Abstract:
A method for characterizing the knock-resistance of a fuel using a test engine is disclosed, wherein the time versus cylinder pressure curve of the test engine during combustion of the fuel in the test engine is determined. This pressure signal is, in turn, compared with the corresponding pressure signal of at least one standard fuel of known knock-resistance.

Description:
FIELD OF INVENTION 
     The invention relates to a method for characterizing the knock resistance of fuels via the use of a test engine. 
     BACKGROUND 
     Standard DIN EN 228 stipulates the minimum requirements for the characteristic values and properties for non-leaded types of gasoline. Table 1 shows an excerpt of the essential characteristic values for fuel. 
     
       
         
               
               
             
               
               
               
               
               
             
               
               
               
             
           
               
                 TABLE 1 
               
             
             
               
                   
               
               
                   
                 Requirements according 
               
               
                   
                 to DIN EN 228 
               
             
          
           
               
                 Characteristic value 
                 Unit 
                 SuperPlus 
                 Super 
                 Normal 
               
               
                   
               
               
                 Density at 15° C. 
                 Kg/m 3   
                   
                 720-775 
                   
               
               
                 Knock resistance 
                   
                   
                   
                   
               
               
                 R.O.N. 
                   
                 min. 98 
                 min. 95 
                 min. 91   
               
               
                 M.O.N. 
                   
                 min. 88 
                 min. 85 
                 min. 82.5 
               
               
                 Lead content 
                 mg/L 
                   
                 max. 5      
                   
               
             
          
           
               
                 Distillation range* 
                 % (V/V) 
                   
               
               
                 Evaporated quantity 
                   
                   
               
               
                 (Class A) 
                   
                   
               
               
                 at 70° C., E70 
                   
                 20-48 
               
               
                 at 100° C., E100 
                   
                 46-71 
               
               
                 at 150° C., E150 
                   
                     min. 75 
               
               
                 Evaporated quantity 
                   
                   
               
               
                 (Class D/D1) 
                   
                   
               
               
                 at 70° C., E70 
                   
                 22-50 
               
               
                 at 100° C., E100 
                   
                 46-71 
               
               
                 at 150° C., E150 
                   
                     min. 75 
               
               
                 Final boiling point (FBP)  
                 ° C. 
                  max. 210 
               
               
                 (Class A/D/D1) 
                   
                   
               
               
                 Volatility indicator VLI** 
                   
                   
               
               
                 (VLI = 10 × VP + 7/E70) 
                   
                   
               
               
                 Class D1 
                 Index 
                   max. 1150 
               
               
                 Distillation residue 
                 % (V/V) 
                 max. 2 
               
               
                 Vapor pressure (DVPE) 
                 kPa 
                   
               
               
                 Class A 
                   
                 45.0-60.0 
               
               
                 Class D/D1 
                   
                 60.0-90.0 
               
               
                 Evaporation residue 
                 mg/100 mL 
                 max. 5 
               
               
                 Benzene content 
                 % (V/V) 
                 max. 1 
               
               
                 Sulphur content 
                 mg/kg 
                  max. 150 
               
               
                 Oxidation stability 
                 min 
                  max. 360 
               
               
                 Copper corrosion 
                 Extent of 
                 max. 1 
               
               
                   
                 corrosion 
               
               
                   
               
               
                 *Class A: May 1-September 30 (summer) 
               
               
                 Class D: November 16-March 15 (winter) 
               
               
                 Class D1: March 16-April 30 &amp; October 1-November 15 (transition) 
               
               
                 **Vapor Lock Index 
               
             
          
         
       
     
     Especially important in all of this is knock resistance which is described with two characteristic numbers: the motor octane number (M.O.N.) and the research octane number (R.O.N.). Briefly, knocking can occur during combustion in any gasoline engine and cause extensive engine damage, if intense enough. For this reason, engine developers are required to prevent the non-uniform combustion that occurs during knocking. In other words, they must integrate knock control systems into engine controls and to proactively prepare the engine for the fuel&#39;s knock resistance. High octane numbers permit higher performance with a simultaneously higher degree of efficiency of the engine and, therefore, lower consumption. For these reasons, higher prices can also be fetched with higher-octane fuels, even though they have almost the same energy content (fuel value) as lower-octane fuels. 
     The worldwide determination of octane numbers is nowadays carried out empirically and according to standardized processes in the fuel producers&#39; laboratories. Special one-cylinder test engines with a variable compression ratio that can be adjusted to the respective fuel quality are used for this purpose. The objective is to compare the knock intensity of the fuel being tested with fuels of a known octane number in order to determine its octane number. Interpolation between octane numbers may be necessary. The standard arbitrarily assigned octane number for isooctane is 100 and for n-heptane is 0. By mixing these components, a fuel can be produced that will have the same knock intensity as the fuel being tested. The octane number that is being determined for will then correspond to the volumetric share of isooctane in the fuel mixture. Only testing conditions differentiate between M.O.N. and R.O.N. All other process steps are the same and the same measuring techniques and test engine were used. 
     The degree of knock intensity is measured with an electric sensor (electronic detonation meter) attached to the engine&#39;s combustion chamber ( FIG. 1 ) and an indicator (knock meter) displays the result. The knock intensity and frequency calculations are not performed with the measuring data, however. Research has shown that fuels with equal octane numbers can actually have a different knock behavior regarding intensity and frequency. If this method is professionally applied with the corresponding experience, an accuracy of no more than +0.2 octane numbers can be achieved. The operation is done manually and takes between 20 and 30 minutes per octane number. There have been—and still are—many attempts to determine the octane number with calculations or another instrument—i.e., outside the engine. Unfortunately, so far it has not been possible to achieve this with the desired accuracy. If the fuel composition is known, a gas chromatography analysis or infrared spectroscopy can give reasonably accurate results, but these methods are only used in refineries because they know exactly the composition of their fuel. A fundamental improvement of the device and method has not yet been found. 
     The following problems have been detected in assessing the valid processes for determining the octane number: 
     The accuracy of the process can be improved upon. 
     The process is time-consuming; it cannot be automated and allows no online indication. 
     In the process, the knock intensity is indicated directly after the analog processing of the measuring signal. No exact calculation of the knock intensity and frequency takes place. 
     Whether the determined octane numbers actually reflect the knocking resistance of the fuels that current combustion engines require has been called into question. 
     It is, therefore, an object of the invention to create a process that will provide a fast and reliable characterization of the knock resistance of fuels possible. 
     SUMMARY 
     Objects and advantages of the invention are set forth in part in the following description, or may be obvious from the description, or may be learned through practice of the invention. 
     The objective is solved by determining the chronological sequence of the testing engine&#39;s cylinder pressures during the combustion of the fuel in the test engine so the determined pressure signals can be compared with the corresponding pressure signals of at least one standard fuel of known knock resistance. 
     The utilization of modern measuring and analytical techniques allows the exact characterization of the various parameters of the knocking combustion processes that occur in the test engine, such as knock intensity, knock pressure amplitude of the peak pressure, speed of pressure increase, and the frequency and the frequency distributions of these parameters. The approach taken and the necessary measuring techniques are described in the following exemplary embodiments. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  shows a cross section of a test engine according to the invention; 
         FIG. 2  shows a diagram of an electric knock sensing device according to the invention; 
         FIG. 3  shows an alternative embodiment of the knock sensing device according to the invention; 
         FIG. 4  shows an exemplary graph of crankshaft angle versus cylinder pressure according to the invention; and 
         FIG. 5  shows an exemplary graph of knock intensity distribution according to the Invention. 
     
    
    
     DESCRIPTION 
     Reference is now made to particular embodiments of the invention, one or more examples of which are illustrated in the drawings. Each embodiment is provided by way of explanation of the invention, and not as a limitation of the invention. For example, features illustrated as described as part of one embodiment may be used with another embodiment to yield still a further embodiment. It is intended that the present invention include these and other modifications and variations. 
     In one embodiment, a piezoelectric pressure sensor (as typically used by engine developers in their R&amp;D tasks) is advantageously coupled with the combustion chamber, instead of the electronic detonation meter. Thus, the pressure signal is amplified and converted to a charge signal proportional to the cylinder pressure (p) (see  FIG. 3 ). The charge signal is fed to a fast data capture unit, where it is digitalized, processed further, and then saved. 
     In this context, it can be advantageous if the pressure signals are filtered via a band pass filter (especially within the 3 to 15 kHz range and/or with high pass from 3 kHz) before comparing them to the corresponding signals of one or several standard fuels. 
     At the same time, it is also advantageous if the chronological sequence of the crankshaft angles (α in  FIG. 3 ) of the test engine is determined during combustion via a crankshaft angle sensor. Using this information, the determined pressure signals can be analyzed either as a function of time, crankshaft angle, or ignition timing.  FIG. 4  shows a representation of the cylinder pressure and the respective, time-dependent knock pressure amplitudes as a function of crankshaft angle. 
     Knock intensity or the other parameters mentioned above that can be derived from the cylinder pressure sequence and their distribution as a histogram, cumulative frequency or individual characteristic number can be displayed for describing the knocking ( FIG. 5 ). Even a comparison of the individual parameters is possible, as important knowledge about the knock behavior of the examined fuel can be gained. In this respect, it must be pointed out that the respective operating conditions of the tested engine must be considered when interpreting the captured data to prevent false results. 
     A comparison of the corresponding results with those from typical standard fuels such as isooctane and/or n-heptane obtained in an analogous way leads to one or several characteristic numbers that describe the exact knocking resistance of the fuel to be tested. 
     In this case, the respective characteristic numbers based on the chronological sequence of the test engine&#39;s cylinder pressure signal that are obtained can be measured either during the individual test engine cycle or obtained from the statistical evaluation of the pressure signals of several cycles. 
     In addition, it is also advantageous if the compression ratio of the test engine is calculated based on the cylinder pressure at a defined crankshaft angle, whereby the crankshaft angle serves as a measure of the ignition timing. Since the knock behavior of a fuel depends, among other things, from the test engine&#39;s compression ratio, it is advantageous to take this parameter into account when comparing the pressure signals of the fuel tested with those of the standard fuel of known knock resistance. 
     Furthermore, it is also extremely advantageous if the measured cylinder pressure signals and the corresponding additional known data from the tested fuel—such as, for example, its exact chemical composition—can be stored in a database. After all, these measured values are the basis for future evaluations of new or not yet analyzed fuels. In this case (and especially while complying with standardized process steps), fast and reliable conclusions about the knock behavior of a fuel to be tested can be obtained. With the corresponding data stock, an analysis of standard fuels is therefore no longer necessary in every case. 
     Examples of the process steps are listed below: 
     Time-based measurement of the cylinder pressure signal (scanning frequency: 100 kHz). 
     Band pass filtration of the measured pressure signal (3 to 15 kHz). 
     Determination of the maximum amplitude height of the filtered pressure signal per cycle (best results with a signal processor). 
     Evaluation of the amplitude height and its frequency in an adjustable time window (300 cycles, intensity distribution, or cumulative frequency). 
     Correlation of results with the known standard fuels or their mixtures. 
     Display and storage of the correlation indices as a measure for knock resistance. 
     The important advantages of the device and the process include: 
     Higher accuracy, especially through the use of precision technology and statistical analysis. 
     More exact evaluation of the knock processes through the analysis of knock intensity and frequency. 
     Possibility of automation. 
     Online display of the characteristic number of the knock resistance. 
     Automatic or partially-automatic process. 
     Measurement with standard fuels no longer needed as soon as the results have been made available in a database. 
     The compression ratio can be exactly calculated from the pressure sequence occurring before the time of ignition. 
     Modifications of the invention are easily possible within the framework of the patent claims, in which case, it is expressly mentioned that all individual characteristics in the patent claims, in the description, and in the figures can be used in any combination thereof, as long as it is possible and makes sense. For example, it can be quite advantageous if the pressure and/or temperature of the combustion mixture and its dwelling time (especially in form of a characteristic number calculated therefrom) can be taken into account. It is advantageous if the ignition timing and the start of knocking of the combustion mixture can be recorded (especially via a sensor) and the intermediate time difference and/or the difference of the respective crankshaft angles of the test engine are considered. In this way, it is possible to very accurately determine the time period to be analyzed, which results in an especially reliable implementation of the test. In addition, it is also possible to determine the combustion period (heat input through combustion) of an individual or several test engine cycles for obtaining, therefrom, the ignition delay, the preliminary ignition, the maximum combustion speed and/or the residual amount of the combustion mixture from fuel and combustion gas, especially combustion air, when the knocking starts. The combustion period of an individual or several cycles of the test engine can also be determined (and at least a pre-defined value of the combustion period such as the start of combustion) via at least one sensor, especially one for measuring the ionic current inside the test engine, a sensor for measuring the structure-borne noise of the test engine, and/or an optical sensor. This method allows the very precise determination of the start of the combustion so that the period for the corresponding cylinder pressure measurement can be determined with exemplary reliability. It is, likewise, extremely advantageous for the characterization of knock resistance to include a statistical analysis of the measured parameters (especially those of the pressure signals), in which case this statistical analysis should encompass the recording of the measured parameters (especially of the pressure signals) of one or several cycles (between 200 and 500, for example), of the test engine, particularly in a defined operating point of the test engine. It would also be advantageous for the statistical analysis to encompass the calculation of the mean values of the measured parameters, so that possible measurement fluctuations should only have a minimal effect on the characterization of knock resistance. 
     Modifications and variations can be made to the embodiments illustrated or described herein without departing from the scope and spirit of the invention as set forth in the appended claims.