Abstract:
A method includes generating a plasma plume with a plasma gun, delivering a plurality of coating materials to the plasma plume with a powder feeder assembly to vaporize the coating materials. The delivery includes delivering a first (bond coat) material from a first powder feeder to the plasma gun, ceasing delivery of the first material, increasing a rate of delivery of a second (rare earth stabilized zirconia) material from a second powder feeder to the plasma plume, increasing a rate of delivery of a third material (a rare earth stabilized zirconia material different from the second material) from a third powder feeder to the plasma plume, decreasing a rate of delivery of the second material, and decreasing a rate of delivery of the third material, and depositing the plurality of coating materials on a work piece to produce a layered coating with blended transitions between coating layers.

Description:
CROSS-REFERENCE TO RELATED APPLICATION(S) 
       [0001]    The present application is a divisional of U.S. patent application Ser. No. 13/674,435, filed Nov. 12, 2012, which is a divisional of U.S. patent application Ser. No. 12/781,485, filed May 17, 2010, which are both hereby incorporated by reference in their entireties. 
     
    
     BACKGROUND 
       [0002]    The present invention relates to coating apparatuses and methods of applying coatings. 
         [0003]    Coatings are utilized in a variety of settings to provide a variety of benefits. For example, modern gas turbine engines can include thermal barrier coatings (TBCs), environmental coatings, etc. to help promote efficient and reliable operation. Conventional electron beam physical vapor deposition (EB-PVD) and plasma-based PVD techniques used to create multilayer ceramic coatings are plagued by undesirable transition effects between layers, such as crystallographic defects that occur when coating growth is stopped and re-started and mechanical property discontinuities associated with sharp transitions from one type of ceramic to another (e.g., coefficient of thermal expansion discontinuities). These transition effects can limit a service life of the coating. 
         [0004]    One prior art coating involved plasma spraying to deposit powdered coating material on a blade outer air seal (BOAS). According to that process, the coating material was deposited as a stream of liquid droplets. The coating was deposited on the parent material of the BOAS using continuous plasma spraying (in liquid droplet form) to form a bond coat of Nickel-Chromium/Aluminum, followed by a layer with a gradient of Cobalt-Chromium-Aluminum-Yttrium alloy and Alumina, followed by another layer with a gradient of Alumina and Yttria-stabilized Zirconia, and followed by another layer of either (a) Yttria Zirconia aromatic polyester blend or (b) Yttria-stabilized Zirconia plus Silicon or simply Yttria-stabilized Zirconia blended with an aromatic polyester material. Such a coating and an associated application method are described in U.S. Pat. Nos. 4,481,237, 4,588,607, 4,603,257 and 4,613,259. 
       SUMMARY 
       [0005]    A method includes generating a plasma plume with a plasma gun, delivering a plurality of coating materials to the plasma plume with a powder feeder assembly to vaporize the coating materials. The delivery includes delivering a first (bond coat) material from a first powder feeder to the plasma gun, ceasing delivery of the first material, increasing a rate of delivery of a second (rare earth stabilized zirconia) material from a second powder feeder to the plasma plume, increasing a rate of delivery of a third material (a rare earth stabilized zirconia material different from the second material) from a third powder feeder to the plasma plume, decreasing a rate of delivery of the second material, and decreasing a rate of delivery of the third material, and depositing the plurality of coating materials on a work piece to produce a layered coating with blended transitions between coating layers. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0006]      FIG. 1  is a schematic cross-sectional view of a coating apparatus according to the present invention. 
           [0007]      FIG. 2  is a cross-sectional view of a multilayer coating applied to a work piece according to the present invention. 
       
    
    
     DETAILED DESCRIPTION 
       [0008]    In general, the present invention provides a coating suitable for use as a thermal barrier coating (TBC) for gas turbine engine components, as well as a method of application of the coating. The coating can be a multilayer coating including a bond coat applied to parent material of the work piece and one or more barrier layers having a compositional gradient that produces blended transitions between layers. The barrier layers can each be made of ceramic materials, inert compounds with cubic crystalline structures, or other materials as desired for particular applications. The resultant coating can have a columnar microstructure. Coating materials can be deposited on the work piece in a vapor-based plasma stream using a plasma gun. The work piece can be rotated during the coating deposition process. 
         [0009]      FIG. 1  is a schematic illustration of one embodiment of a coating apparatus  10  that includes a process chamber  12 , a plasma gun  14 , a pumping assembly  16 , a work piece support fixture  18 , and one or more coating material supply assemblies  20 . One or more work pieces  26 A and  26 B (collectively referred to by reference number  26 ) desired to be coated can be secured to the work piece support fixture  18 . In the illustrated embodiment, the work pieces  26  are turbine blades for a gas turbine engine, though it will be understood that the work pieces  26  can be nearly any type of component in further embodiments. 
         [0010]    The process chamber  12  provides a contained environment for application of coating materials to the work pieces  26 . In the illustrated embodiment, the process chamber  12  includes fluid-cooled walls, which can be cooled with water at approximately 15-20° C. (60-70° F.). The process chamber  12  defines an interior space that is held in a vacuum (i.e., a partial vacuum), with the vacuum in the range of approximately 66.66 Pa (0.5 Torr) to approximately 1.33 kPa (10 Torr). Suitable thermal management equipment (not shown), such as passive thermal insulation, thermal reflectors and heater elements, can be provided in the process chamber  12  as desired. For example, some suitable thermal management systems and methods are disclosed in commonly-assigned and co-pending U.S. patent application Ser. Nos. 12/723,405, 12/723,412 and 12/723,436, which are all hereby incorporated by reference in their entireties. 
         [0011]    The plasma gun  14  is typically positioned within the process chamber  12 . The plasma gun  14  can be of a known type that produces a plasma plume (or jet) into which a coating material, such as a coating material powder (which can be a mixture of more than one discrete type of coating material powder), is introduced to produce a stream  30  that includes the coating material in a vapor phase. The stream  30  is directed toward the work pieces  26 A and  26 B and the work piece support fixture  18  to provide plasma-based physical vapor deposition (PVD) coating application. During operation, the plasma gun  14  generates thermal energy within the process chamber  12 , with temperatures typically ranging from approximately 871-1093° C. (1600-2000° F.) near the work pieces  26 A and  26 B, depending on the type of gun, and stand-off distance. Optimal coating process temperatures can vary for different coating materials. Moreover, in alternative embodiments, a different type of coating supply and delivery apparatus can be substituted for the plasma gun  14 , as desired for particular applications. 
         [0012]    Excess coating material, that is, coating material not deposited on the work pieces  26 , can be cooled and collected by the pumping assembly  16 . In the illustrated embodiment, the pumping assembly is of a conventional configuration that allows for extraction and collection of excess coating material from the process chamber  12 , as well as cooling of that excess coating material. The pumping assembly  16  is typically located at an end of the process chamber opposite the plasma gun  14 . 
         [0013]    In the illustrated embodiment, the work pieces  26 A and  26 B desired to be coated are each secured to the work piece support fixture  18  in the path of the stream  30 , downstream from the plasma gun  14 . The work piece support fixture  18  can selectively index the work pieces  26  relative to the stream  30  and the plasma gun  14 , which typically has a fixed orientation, in order to expose different portions of the work pieces  26  to the stream  30  in a uniform manner so that the coating material can cover all sides of the work pieces  26  substantially equally. In one embodiment, the work piece support fixture  18  is configured to rotate the work pieces  26  about a central axis A. In alternative embodiments, more complex movements of the work pieces  26  are possible, such as planetary- or rotisserie-type movement. 
         [0014]    The one or more coating material supply assemblies  20  can supply a plurality of different coating materials to the plasma gun  14  for delivery with the stream  30 . In the illustrated embodiment, two coating material supply assemblies  20  are provided that include a total of four powder feeders  32 A- 32 D each providing separate material feedstock. The powder feeders  32 A- 32 D are configured to supply coating material in powdered form through supply lines  34  to the plasma gun  14  for melting (e.g., vaporization) and delivery by the stream  30 . The powder feeders  32 A- 32 D are independently operable, which allows for one or more of the powder feeders  32 A- 32 D to operate simultaneously and for a supply rate of each of the powder feeders  32 A- 32 D to be independently controlled. This allows the rate of delivery of individual coating materials to be increased and decreased independently through control of the powder feeders  32 A- 32 D. Coating materials from the powder feeders  32 A- 32 D can be mixed prior to vaporization. Mixing can occur in the supply lines  34 , in a mixing manifold (not shown), such as one of a type disclosed in U.S. Pat. No. 4,613,259, or in any other suitable manner. In this way, coating materials can be applied by the apparatus  10  with varying coating material compositions without stopping and re-starting coating deposition. In alternative embodiments, coating materials can be provided in a form other than powdered form with suitable feeder and supply assemblies utilized for the particular form of the coating material to be applied. 
         [0015]    Vapor-phase deposition processes are less prone to variation in makeup of the resultant coating on the work pieces  26  than liquid droplet application processes. This is due at least in part to turbulence in the stream  30 . 
         [0016]      FIG. 2  is a cross-sectional view of a multilayer coating  100  applied to a work piece  26 . The multilayer coating  100  can be applied using the plasma-based PVD method an apparatus described with respect to  FIG. 1 , or other with other suitable processes. The work piece  26  can be made of a metallic parent material (also referred to herein as a substrate), such as a nickel- or cobalt-based superalloy, or any other metallic material desired for a particular application. 
         [0017]    The multilayer coating  100  includes a bond coat layer  102  positioned directly on the parent material of the work piece  26 . A first barrier layer  104  is positioned on the bond coat layer  102 , and a second barrier layer  106  is positioned on the first barrier layer  104 . In the illustrated embodiment, the second barrier layer  106  is the outermost layer of the multilayer coating  100 , and the first barrier layer  104  is located in between the bond coat layer  102  and the second barrier layer  106 . In further embodiments, the bond coat layer  102  and/or the second barrier layer  106  can be omitted. For simplicity of illustration, the coating  100  as shown in  FIG. 2  has clear divisions between the illustrated layers. However, transitions between layers of the coating  100  can be blended such that transitions between layers are less distinct, or even indistinguishable. Moreover, although the layers of the coating  100  illustrated in  FIG. 2  appear homogenous, the illustrated layers can have compositional gradients, as discussed below. 
         [0018]    The bond coat layer  102  will include an adherent layer, typically an alumina layer, and can be made of a MCrAlY material, where M represents a metal such as Ni, Co or Co/Ni, or an aluminide (with or without Pt or other metals) or other suitable material. The first and second barrier layers  104  and  106  can be TBC materials, such as ceramic materials (e.g., rare-earth stabilized zirconia materials), environmental coatings, and/or inert compounds (e.g., compounds with a cubic crystalline structure such as any suitable garnet materials and/or a hexagonal crystalline structure such as an suitable oxyapatite materials, as described in commonly-assigned U.S. Pat. No. 7,622,195). 
         [0019]    Garnet materials generally have the formula 
         [0000]      A 3 B 2 X 3 O 12   (I)
 
         [0000]    where A comprises at least one of the elements selected from the group consisting of Ca +2 , Gd +3 , In +3 , Mg +2 , Na + , K + , Fe +2 , La +2 , Ce +2 , Pr +2 , Nd +2 , Pm, Sm +2 , Eu +2 , Gd +2 , Tb +2 , Dy +2 , Ho +2 , Er +2 , Tm +2 , Yb +2 , Lu +2 , Sc +2 , Y +2 , Ti +2 , Zr +2 , Hf +2 , V +2 , Ta +2 , Cr +2 , W +2 , Mn +2 , Tc +2 , Re +2 , Fe +2 , OS +2 , Co +2 , Ir +2 , Ni +2 , Zn +2 , and Cd +2 ; where B comprises at least one of the elements selected from the group consisting of Zr +4 , Hf +4 , Gd +3 , Al +3 , Fe +3 , La +2 , Ce +2 , Pr +2 , Nd +2 , Pm +2 , Sm +2 , Eu +2 , Gd +2 , Tb +2 , Dy +2 , Ho +2 , Er +2 , Tm +2 , Yb +2 , Lu +2 , Ac +2 , Th +2 , Pa +2 , U +2 , Np +2 , Pu +2 , Am +2 , Cm +2 , Bk +2 , Cf +2 , Es +2 , Fm +2 , Md +2 , No +2 , Lr +2 , In +3 , Sc +2 , Y +2 , Cr +3 , Sc +3 , Y +3 , V +3 , Nb +3 , Cr +3 , Mo +3 , W +2 , Mn +3 , Fe +3 , Ru +2 , Co +3 , Rh +3 , Ir +3 , Ni +3 , and Au +3 ; where X comprises at least one of the elements selected from the group consisting of Si +4 , Ti +4 , Al +4 , Fe +3 , Cr +3 , Sc +3 , Y +3 , V +3 , Nb +3 , Cr +3 , Mo +3 , W +3 , Mn +3 , Fe +3 , Ru +3 , Co +3 , Rh +3 , Ir +3 , Ni +3 , and Au +3 ; and where O is oxygen. 
         [0020]    Oxyapatite materials generally have the formula 
         [0000]      A 4 B 6 X 6 O 26   (II)
 
         [0000]    where A comprises at least one of the elements selected from the group consisting of is Ca +2 , Mg +2 , Fe +2 , Na + , K + , Gd +3 , Zr +4 , Hf +4 , Y +2 , Sc +2 , Sc +3 , In +3 , La +2 , Ce +2 , Pr +2 , Nd +2 , Pm +2 , Sm +2 , Eu +2 , Gd +2 , Tb +2 , Dy +2 , Ho +2 , Er +2 , Tm +2 , Yb +2 , Lu +2 , Sc +2 , Y +2 , Ti +2 , Zr +2 , Hf +2 , V +2 , Ta +2 , Cr +2 , W +2 , Mn +2 , Tc +2 , Re +2 , Fe +2 , Os +2 , Co +2 , Ir +2 , Ni +2 , Zn +2 , and Cd +2 ; where B comprises at least one of the elements selected from the group consisting of Gd +3 , Y +2 , Sc +2 , In +3 , Zr +4 , Hf +4 , Cr +3 , Sc +3 , Y +3 , V +3 , Nb +3 , Cr +3 , Mo +3 , W +3 , Mn +3 , Fe +3 , Ru +3 , Co +3 , Rh +3 , Ir +3 , Ni +3 , and Au +3 ; where X comprises at least one of the elements selected from the group consisting of Si +4 , Ti +4 , Al +4 , Cr +3 , Sc +3 , Y +3 , V +3 , Nb +3 , Cr +3 , Mo +3 , W +3 , Mn +3 , Fe +3 , Ru +3 , Co +3 , Rh +3 , Ir +3 , Ni +3 , and Au +3 ; and where O is oxygen. 
         [0021]    The use of optional inert compounds can help make the resultant multilayer coating more resistant to undesirable penetration and/or reaction with materials that are present near the coating, such as molten sand, etc. Each of the first and second barrier layers  104  and  106  can have a compositional gradient such that the makeup of each coating layer  104  and  106  varies across its thickness from an inner dimension to an outer dimension. For example, the first barrier layer  104  can have a compositional gradient comprising a majority of a first rare earth stabilized zirconia material proximate the bond coat layer  102  to a majority of a second rare earth stabilized zirconia material away from the bond coat layer, with the first and second rare earth stabilized zirconia materials being different. A number of possible embodiments of the multilayer coating  100  are detailed below; however, those embodiments are provided merely by way of example and not limitation. 
       EXAMPLES 
       [0022]    Tables 1-7 describe prophetic examples of coating compositions that can be made according to the present invention for application to a work piece. In each example, a gradient of coating materials within a given layer can be substantially linear. Moreover, each coating layer for each example can be applied using a plasma-based PVD process that can produce a columnar microstructure in layers of the coating as applied. In each of the Tables 1-7, the “Beginning wt %” designates weight percent of a given material at the beginning of application (i.e., at a location in a given coating layer closest to the parent material of the work piece), and “Ending wt %” designates weight percent of a given material at the end of application (i.e., at a location in the given coating layer further from the parent material of the work piece and from any previously-applied layer). Moreover, in the given examples, the bond layer, the first barrier layer and the second barrier layer can correspond to the layers  102 ,  104  and  106  described above with respect to  FIG. 2 . All given values are approximate, and specified materials can include incidental impurities. 
         [0000]    
       
         
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                 TABLE 1 
               
               
                   
               
               
                   
                   
                   
                   
                 Approximate 
               
               
                   
                 Material 
                   
                   
                 Thickness 
               
               
                   
                 (all mol % values 
                 Beginning 
                 Ending 
                 Range in mm 
               
               
                 Layer 
                 are approximate) 
                 wt % 
                 wt % 
                 (in.) 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Bond 
                 MCrAlY 
                 100 
                 100 
                 0.0254-0.381 
               
               
                   
                   
                   
                   
                  (0.001-0.015) 
               
               
                 1st 
                 4-10 mol % 
                 100 
                 0 
                 0.0127-0.254 
               
               
                 Barrier 
                 Yttria-Stabilized 
                   
                   
                 (0.0005-0.010) 
               
               
                   
                 Zirconia 
               
               
                   
                 25-40 mol % 
                 0 
                 100 
               
               
                   
                 Lanthana-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 or 5-60 mol % 
               
               
                   
                 Gadolinia-Stabilized 
               
               
                   
                 Zirconia 
               
               
                 2nd 
                 4-10 mol % 
                 0 
                 100 
                 0.0508-0.762 
               
               
                 Barrier 
                 Yttria-Stabilized 
                   
                   
                  (0.002-0.030) 
               
               
                   
                 Zirconia 
               
               
                   
                 25-40 mol % 
                 100 
                 0 
               
               
                   
                 Lanthana-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
               
             
          
         
       
     
         [0000]    
       
         
               
               
               
               
               
             
               
               
               
               
               
             
               
               
             
           
               
                 TABLE 2 
               
               
                   
               
               
                   
                   
                   
                   
                 Approximate 
               
               
                   
                 Material 
                   
                   
                 Thickness 
               
               
                   
                 (all mol % values 
                 Beginning 
                 Ending 
                 Range in mm 
               
               
                 Layer 
                 are approximate) 
                 wt % 
                 wt % 
                 (in.) 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Bond 
                 MCrAlY 
                 100 
                 100 
                 0.0254-0.381 
               
               
                   
                   
                   
                   
                  (0.001-0.015) 
               
               
                 1st 
                 4-10 mol % 
                 100 
                 0 
                 0.0127-0.762 
               
               
                 Barrier 
                 Yttria-Stabilized 
                   
                   
                 (0.0005-0.030) 
               
               
                   
                 Zirconia 
               
               
                   
                 25-40 mol % 
                 0 
                 100 
               
               
                   
                 Lanthana-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 or 5-60 mol % 
               
               
                   
                 Gadolinia-Stabilized 
               
               
                   
                 Zirconia 
               
             
          
           
               
                 2nd 
                 None 
               
               
                 Barrier 
               
               
                   
               
             
          
         
       
     
         [0000]    
       
         
               
               
               
               
               
             
               
               
               
               
               
             
               
               
             
           
               
                 TABLE 3 
               
               
                   
               
               
                   
                   
                   
                   
                 Approximate 
               
               
                   
                 Material 
                   
                   
                 Thickness 
               
               
                   
                 (all mol % values 
                 Beginning 
                 Ending 
                 Range in mm 
               
               
                 Layer 
                 are approximate) 
                 wt % 
                 wt % 
                 (in.) 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Bond 
                 MCrAlY 
                 100 
                 100 
                 0.0254-0.381 
               
               
                   
                   
                   
                   
                  (0.001-0.015) 
               
               
                 1st 
                 4-10 mol % 
                 0 
                 100 
                 0.0127-0.762 
               
               
                 Barrier 
                 Yttria-Stabilized 
                   
                   
                 (0.0005-0.030) 
               
               
                   
                 Zirconia 
               
               
                   
                 25-40 mol % 
                 100 
                 0 
               
               
                   
                 Lanthana-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 or 5-60 mol % 
               
               
                   
                 Gadolinia-Stabilized 
               
               
                   
                 Zirconia 
               
             
          
           
               
                 2nd 
                 None 
               
               
                 Barrier 
               
               
                   
               
             
          
         
       
     
         [0000]    
       
         
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                 TABLE 4 
               
               
                   
               
               
                   
                   
                   
                   
                 Approximate 
               
               
                   
                 Material 
                   
                   
                 Thickness 
               
               
                   
                 (all mol % values 
                 Beginning 
                 Ending 
                 Range in mm 
               
               
                 Layer 
                 are approximate) 
                 wt % 
                 wt % 
                 (in.) 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Bond 
                 MCrAlY 
                 100 
                 100 
                 0.0254-0.381 
               
               
                   
                   
                   
                   
                  (0.001-0.015) 
               
               
                 1st 
                 4-10 mol % 
                 100 
                 0 
                 0.0127-0.254 
               
               
                 Barrier 
                 Yttria-Stabilized 
                   
                   
                 (0.0005-0.010) 
               
               
                   
                 Zirconia 
               
               
                   
                 25-40 mol % 
                 0 
                 100 
               
               
                   
                 Lanthana-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 or 5-60 mol % 
               
               
                   
                 Gadolinia-Stabilized 
               
               
                   
                 Zirconia 
               
               
                 2nd 
                 25-40 mol % 
                 100 
                 0 
                 0.0508-0.762 
               
               
                 Barrier 
                 Lanthana-Stabilized 
                   
                   
                  (0.002-0.030) 
               
               
                   
                 Zirconia 
               
               
                   
                 or 5-60 mol % 
               
               
                   
                 Gadolinia-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 10-50 mol % 
                 0 
                 100 
               
               
                   
                 Hafnia-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
               
             
          
         
       
     
         [0000]    
       
         
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                 TABLE 5 
               
               
                   
               
               
                   
                   
                   
                   
                 Approximate 
               
               
                   
                 Material 
                   
                   
                 Thickness 
               
               
                   
                 (all mol % values 
                 Beginning 
                 Ending 
                 Range in mm 
               
               
                 Layer 
                 are approximate) 
                 wt % 
                 wt % 
                 (in.) 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Bond 
                 MCrAlY 
                 100 
                 100 
                 0.0254-0.381 
               
               
                   
                   
                   
                   
                  (0.001-0.015) 
               
               
                 1st 
                 4-10 mol % 
                 100 
                 0 
                 0.0127-0.254 
               
               
                 Barrier 
                 Yttria-Stabilized 
                   
                   
                 (0.0005-0.010) 
               
               
                   
                 Zirconia 
               
               
                   
                 25-40 mol % 
                 0 
                 80 
               
               
                   
                 Lanthana-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 or 5-60 mol % 
               
               
                   
                 Gadolinia-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 Garnet (e.g., 
                 0 
                 20 
               
               
                   
                 Ca 3 Gd 2 Si 3 O 12 ) 
               
               
                 2nd 
                 4-10 mol % 
                 0 
                 0 
                 0.0508-0.762 
               
               
                 Barrier 
                 Yttria-Stabilized 
                   
                   
                  (0.002-0.030) 
               
               
                   
                 Zirconia 
               
               
                   
                 25-40 mol % 
                 80 
                 0 
               
               
                   
                 Lanthana-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 or 5-60 mol % 
               
               
                   
                 Gadolinia-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 Garnet (e.g., 
                 20 
                 100 
               
               
                   
                 Ca 3 Gd 2 Si 3 O 12 ) 
               
               
                   
               
             
          
         
       
     
         [0000]    
       
         
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                 TABLE 6 
               
               
                   
               
               
                   
                   
                   
                   
                 Approximate 
               
               
                   
                 Material 
                   
                   
                 Thickness 
               
               
                   
                 (all mol % values 
                 Beginning 
                 Ending 
                 Range in mm 
               
               
                 Layer 
                 are approximate) 
                 wt % 
                 wt % 
                 (in.) 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Bond 
                 MCrAlY 
                 100 
                 100 
                 0.0254-0.381 
               
               
                   
                   
                   
                   
                  (0.001-0.015) 
               
               
                 1st 
                 4-10 mol % 
                 100 
                 0 
                 0.0127-0.254 
               
               
                 Barrier 
                 Yttria-Stabilized 
                   
                   
                 (0.0005-0.010) 
               
               
                   
                 Zirconia 
               
               
                   
                 25-40 mol % 
                 0 
                 80 
               
               
                   
                 Lanthana-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 or 5-60 mol % 
               
               
                   
                 Gadolinia-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 Oxyapatite (e.g., 
                 0 
                 20 
               
               
                   
                 Ca 2 Gd 8 Si 6 O 26 ) 
               
               
                 2nd 
                 4-10 mol % 
                 0 
                 0 
                 0.0508-0.762 
               
               
                 Barrier 
                 Yttria-Stabilized 
                   
                   
                  (0.002-0.030) 
               
               
                   
                 Zirconia 
               
               
                   
                 25-40 mol % 
                 80 
                 0 
               
               
                   
                 Lanthana-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 or 5-60 mol % 
               
               
                   
                 Gadolinia-Stabilized 
               
               
                   
                 Zirconia 
               
               
                   
                 Oxyapatite (e.g., 
                 20 
                 100 
               
               
                   
                 Ca 2 Gd 8 Si 6 O 26 ) 
               
               
                   
               
             
          
         
       
     
         [0000]    
       
         
               
               
               
               
               
             
               
               
               
               
               
             
               
               
             
           
               
                 TABLE 7 
               
               
                   
               
               
                   
                   
                   
                   
                 Approximate 
               
               
                   
                 Material 
                   
                   
                 Thickness 
               
               
                   
                 (all mol % values 
                 Beginning 
                 Ending 
                 Range in mm 
               
               
                 Layer 
                 are approximate) 
                 wt % 
                 wt % 
                 (in.) 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Bond 
                 MCrAlY 
                 100 
                 100 
                 0.0254-0.381 
               
               
                   
                   
                   
                   
                  (0.001-0.015) 
               
               
                 1st 
                 5-60 mol % 
                 100 
                 0 
                 0.0127-0.762 
               
               
                 Barrier 
                 Gadolinia-Stabilized 
                   
                   
                 (0.0005-0.030) 
               
               
                   
                 Zirconia 
               
               
                   
                 Garnet (e.g., 
                 0 
                 100 
               
               
                   
                 Ca 3 Gd 2 Si 3 O 12 ) or 
               
               
                   
                 Oxyapatite (e.g., 
               
               
                   
                 Ca 2 Gd 8 Si 6 O 26 ) 
               
             
          
           
               
                 2nd 
                 None 
               
               
                 Barrier 
               
               
                   
               
             
          
         
       
     
         [0023]    While the invention has been described with reference to an exemplary embodiment(s), it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiment(s) disclosed, but that the invention will include all embodiments falling within the scope of the appended claims. For example, coatings according to the present invention can include additional layers or materials not specifically discussed above. Moreover, thicknesses of coating layers can vary as desired for particular applications, and can be greater or lesser than those indicated in the foregoing examples.