Abstract:
An herbicidally effective benzoyl derivative having the formula: ##STR1## wherein X 1  is C 1  -C 4  alkoxy or halogen; 
     X 4  is hydrogen, C 1  -C 4  alkyl, C 1  -C 4  alkoxy or halogen; 
     X 5  is hydrogen or fluorine; 
     Y 1 , Y 2 , Y 3 , Y 4  and Y 5  are independently hydrogen or C 1  -C 4  alkyl; 
     R 1  is C 1  -C 4  alkyl; 
     R 4  is C 1  -C 3  alkyl; 
     n is an integer of 0, 1 or 2 is discosed. 
     In addition, the herbicidally effective benzoyl derivative having the formula: ##STR2## wherein: X 1  is C 1  -C 4  alkyl, C 1  -C 4  alkoxy halogen; 
     X 4  is hydrogen, C 1  -C 4  alkyl, C 1  -C 4  alkoxy or halogen; 
     X 5  is hydrogen or fluorine; 
     Y 1 , Y 2 , Y 3 , Y 4  and Y 5  are independently hydrogen or C 1  -C 4  alkyl; 
     R 1  is C 1  -C 4  alkyl; 
     R 4  is C 1  -C 3  alkyl; 
     n is an integer of 0, 1 or 2; 
     L is C 1  -C 4  alkylene is disclosed.

Description:
BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to novel substituted benzoyl derivatives and selective herbicides containing such derivatives as active ingredients. 
     2. Discussion of Background 
     Various herbicides have been developed for practical use from extensive research and development of herbicides for many years, and such herbicides have contributed to a reduction of the labor force required for controlling weeds or to improvement of the productivity of agricultural or horticultural plants. 
     Even now, it is still desired to develop a new herbicide having superior herbicidal properties. In particular, it is desired to develop an agricultural or horticultural herbicide which is capable of selectively controlling weeds without adversely affecting the crop plant and at a low dose. However, conventional herbicides do not necessarily provide such desired herbicidal properties. 
     On the other hand, among substituted benzoyl derivatives, certain compounds of 4-benzoylpyrazole derivatives are known to have herbicidal activities. For example, pyrazolate (common name) and pyrazoxyfen (common name) are practically used as herbicides for paddy fields. While exhibiting excellent herbicidal activities as paddy field herbicides, these compounds are not suitable as upland herbicides since their herbicidal activities are weak against weeds of upland fields. Among substituted benzoyl derivatives, it is desired to develop a superior compound useful as an upland field herbicide. 
     SUMMARY OF THE INVENTION 
     The present invention provides a substituted benzoyl derivative having the formula: ##STR3## wherein X 1  is C 1  -C 4  alkyl, C 2  -C 5  alkoxyalkyl, C 1  -C 4  haloalkyl, C 1  -C 4  alkoxy, C 1  -C 4  haloalkoxy, cyano, nitro or halogen; X 2  is --L--OR 1  (wherein L is C 1  -C 4  alkylene or C 1  -C 4  alkylidene, and R 1  is hydrogen, C 1  -C 4  alkyl, C 1  -C 4  alkenyl or C 1  -C 4  alkynyl), --L--O--L--OR 1  (wherein L and R 1  are as defined above), --L--S(O) n  --R 2  (wherein L is as defined above, R 2  is C 1  -C 4  alkyl, C 1  -C 4  alkenyl or C 1  -C 4  alkynyl, and n is an integer of 0, 1 or 2), --L--O--COR 2  (wherein L and R 2  are as defined above), --L--NR 1  R 3  (wherein L and R 1  are as defined above, and R 3  is hydrogen or C 1  -C 4  alkyl), --COOR 1  (wherein R 1  is as defined above) or --COO--L--O--R 1   (wherein L and R 1  are as defined above), provided that when X 1  is C 1  -C 4  alkyl or C 1  -C 4  haloalkyl, X 2  is not --COOR 1  ; X 3  is trifluoromethyl, C 1  -C 3  alkoxy, halogen, cyano, nitro or --S(O) n  R 4  (wherein n is as defined above, and R 4  is C 1  -C 3  alkyl); X 4  is hydrogen, C 1  -C 4  alkyl, C 1  -C 4  alkoxy or halogen; X 5  is hydrogen or fluorine; and each of Y 1 , Y 2 , Y 3 , Y 4  and Y 5  is hydrogen or C 1  -C 4  alkyl; or a salt thereof. 
     The present invention also provides a selective herbicide comprising a herbicidally effective amount of at least one substituted benzoyl derivative of the formula I as defined above or its salt and an agricultural carrier or diluent. 
     As a result of extensive researches for many years, the present inventors have found that the compounds of the formula I of the present invention have herbicidal activities substantially higher than the conventional herbicides. Further, many compounds of the present invention have superior selectivity for certain crop plants such as corn, wheat, rice and rapeseed, and they are thus practically very useful. The present invention is based on these discoveries. 
     With the compounds of the present invention, the dose of the active ingredient per unit area can be substantially reduced as compared with the conventional compounds, and the phytotoxicity against crop plants is extremely low as compared with the conventional herbicides. The economical merits are thus substantial. Further, with the compounds of the present invention, it is possible to substantially reduce a danger of environmental pollution by the use of a large amount of agricultural drug, and an influence over other crop plants due to the persistent effect in soil is minimum. Therefore, the compounds of the present invention can be regarded as epoch-making herbicides. A feature of the compounds of the present invention is that the benzoyl moiety is substituted by substituents selected from the group consisting of X 1 , X 2 , X 3 , X 4  and X 5  as defined above. 
     Heretofore, it has been known that 2-benzoyl-cyclohexane-1,3-dione derivatives have herbicidal activities, as disclosed, for example, in Japanese Unexamined patent Publications No. 180451/1983, No. 87238/1985 and No. 155347/1986. However, compounds having such a specific combination of substituents as defined in the present invention have not been known. Moreover, the present inventors have found that by introducing such a combination of substituents as defined in the present invention to the benzoyl moiety, the herbicidal effects and the selectivity for crop plants of the substituted benzoyl derivatives can be remarkably improved. 
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     The compounds of the present invention can readily be prepared by using one of the reactions represented by the following reaction schemes. ##STR4## 
     In the above formulas, X 1 , X 2 , X 3 , X 4 , X 5 , Y 1 , Y 2 , Y 3 , Y 4  and Y 5  are as defined above. 
     Further, the compounds of the present invention may be represented by the following four tautomer structures: ##STR5## 
     Reaction scheme (1) represents a reaction wherein a benzoic acid having appropriate substituents and a cyclohexane-1,3-dione are reacted in an inert solvent in the presence of a condensing agent and a base to obtain a 2-benzoylcylohexane derivative. As the condensing agent, for example, N,N&#39;-dicyclohexylcarbodiimide may be mentioned. The condensing agent is used preferably in an amount of from 1.0 to 1.5 mols per mol of the benzoic acid and pyrazole. The solvent may be any solvent so long as it is inert to the reaction. Particularly preferred are tert-butyl alcohol, tert-amyl alcohol, and isopropyl alcohol. The base is not necessarily required. However, the yield is usually improved by using the base. There is no particular restriction as to the base, but potassium carbonate or sodium carbonate is preferred. The reaction temperature may range from room temperature to the boiling point of the solvent, and is preferably within a range of from 50 to 100° C. The reaction time is usually from 0.5 to 20 hours. 
     Reaction scheme (2) represents a reaction wherein a benzoyl chloride having appropriate substituents and a substituted cyclohexane-1,3-dione are reacted to form a benzoyl ester, which is then rearranged to obtain a 2-benzoyl compound. 
     The benzoyl esterification can be conducted in a solvent inert to the reaction (such as an aromatic hydrocarbon, an aliphatic ester, a halogenated hydrocarbon, an ether, acetonitrile, dimethylsulfoxide or N,N&#39;-dimethylformamide) or in a two phase system or mixture thereof with water in the presence of a suitable dehydrochlorinating agent (e.g. an inorganic base such as sodium hydroxide, potassium hydroxide, sodium hydrogencarbonate or sodium phosphate, or an organic base such as pyridine or triethylamine) at a temperature of from 0 to 100° C. usually for 10 minutes to 5 hours. 
     The rearrangement reaction can be conducted by a Lewis acid such as anhydrous aluminum chloride, a base, or a cyano compound such as potassium cyanide. As the base, potassium carbonate, calcium hydroxide and sodium carbonate may be used. The Lewis acid, base or potassium cyanide is used usually within a range of from 0.1 to 10 mol times. 
     No solvent is required. However, in some cases, a solvent inert to the reaction and having a suitable boiling point may improve the operation efficiency or the yield. As a suitable example, the same solvent as used for the benzoyl esterification reaction or dioxane or diglyme may be mentioned. 
     The reaction temperature is usually from 20 to 150° C. The reaction time is usually from 15 minutes to 10 hours. 
     Reaction scheme (3) represents a reaction of cyclohexane-1,3-dione with benzoyl cyanide. For this reaction, at least equimolar amount of zinc chloride and at least equimolar amount of a base such as triethylamine are used. There is no particular restrictions as to the solvent so long as it is inactive. A preferred solvent may be methylene chloride or ethylene dichloride. The reaction temperature is usually from 0 to 40° C., and the reaction time is usually from 1 to 10 hours. The benzoic acid or banzoyl chloride used as the starting material of the compound of the present invention can be readily prepared by a combination of various known preparation methods. For example, in the case of a nd wherein the substituent X 3  on the benzene ring is S(O) n  CH 3 , such a compound can be prepared by the following reaction schemes: ##STR6## 
     In the above formulas, X 1 , X 2  and n are as defined above, and Hal is bromine or iodine. 
     These benzoic acids can readily be led to benzoyl chlorides by means of a chlorinating agent such as phosphorus pentachloride, thionyl chloride or sulfuryl chloride. By using the benzoic acids or benzoyl chlorides thus obtained, the compounds of the present invention can readily be prepared in accordance with the reaction schemes (1) to (3). 
    
    
     The present invention will be described in further detail with reference to Examples. However, it should be understood that the present invention is by no means restricted to such specific Examples. 
     EXAMPLE 1 
     Preparation of 2-(4-methanesulfonyl-3-methoxymethyl-2-methylbenzoyl)cyclohexane-1,3-dione (Compound No. 1) 
     1.3 g of potassium carbonate and 3.0 g of N,N&#39;-dicyclohexylcarbodiimide were added to a solution mixture comprising 2.0 g of 4-methanesulfonyl-3-methoxymethyl-2-methylbenzoic acid, 0.9 g of 1,3-cyclohexanedione and 100 ml of t-amyl alcohol. The mixture was stirred at 80° C. for 11 hours. It was concentrated under reduced pressure, and then an aqueous potassium carbonate solution was added. Then, insoluble substances were removed by filtration. The filtrate was washed with chloroform, then acidified by an addition of concentrated hydrochloric acid and extracted with chloroform. The chloroform layer was washed with water and with a saturated sodium chloride aqueous solution and then dried over anhydrous sodium sulfate. The solvent was distilled off under reduced pressure to obtain 1.1 g of a crude desired product. This crude product was recrystallized from ethanol to obtain 0.2 g of the desired product. Melting point: 192-198° C. 
     EXAMPLE 2 
     Preparation of 2-(2-chloro-4-methanesulfonyl-3-methoxycarbonylbenzoyl)cyclohexane-1,3-dione (Compound No. 2) 
     0.28 g of potassium carbonate and 0.77 g of N,N&#39;-dicyclohexylcarbodiimide were added to a solution mixture comprising 1.0 g of 2-chloro-4-methanesulfonyl-3-methoxycarbonyl benzoic acid, 0.38 g of 1,3-cyclohexane dione and 30 ml of t-amyl alcohol. The mixture was stirred at 80° C. for 3 hours. It was concentrated under reduced pressure, and an aqueous potassium carbonate solution was added thereto. Insoluble substances were removed by filtration. The filtrate was washed with chloroform, then acidified by an addition of concentrated hydrochloric acid and extracted with chloroform. The chloroform layer was washed with water and with a saturated sodium chloride aqueous solution and dried over anhydrous sodium sulfate. Then, the solvent was distilled off under reduced pressure to obtain a crude desired product. This crude product was crystallized from ethanol to obtain 0.3 g of the desired product. Melting point: 160-162° C. 
     Compounds prepared in the same manner as in the preceding Examples will be given in Tables 1 to 6 including the compounds of the preceding Examples. However, the present invention is not limited by such specific Examples. 
     The following abbreviations which are used in the Tables, have the following meanings. 
     Me: methyl, Et: ethyl, Pr-n: n-propyl, 
     Pr-i: isopropyl, Bu-t: tert-butyl, and 
     Ms: methanesulfonyl 
     The reference symbols in Tables 1 to 4 have the following meanings. 
     
         ______________________________________X201    CH.sub.2 OCH.sub.3                   X202    CH(CH.sub.3)OCH.sub.3X203    CH(CH.sub.3)OC.sub.2 H.sub.5                   X204    C(CH.sub.3).sub.2 OCH.sub.3X205    CH.sub.2 CH.sub.2 OCH.sub.3                   X206    CH.sub.2 CH.sub.2 OHX207    CH.sub.2 OH     X208    CH.sub.2 OC.sub.2 H.sub.5X209    CH.sub.2 OCH.sub.2 CH═CH.sub.2                   X210    CH.sub.2 OCH.sub.2 C.tbd.CHX211    CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.3                   X212    C(CH.sub.3).sub.2 OC.sub.2 H.sub.5X213    CH.sub.2 CH.sub.2 OC.sub.2 H.sub.5                   X214    CH(C.sub.2 H.sub.5)OCH.sub.3X215    CH(C.sub.2 H.sub.5)OC.sub.2 H.sub.5                   X216    CH(CH.sub.3)OHX217    C(CH.sub.3).sub.2 OH                   X218    CH(OH)C.sub.2 H.sub.5X219    CH.sub.2 CH.sub.2 OCH(CH.sub.3).sub.2                   X220    CH.sub.2 SCH.sub.3X221    CH.sub.2 SO.sub.2 CH.sub.3                   X222    CH.sub.2 N(CH.sub.3).sub.2X223    CH.sub.2 N(CH.sub.3)C.sub.2 H.sub.5                   X224    CH.sub.2 CH.sub.2 N(CH.sub.3).sub.2X225    CH.sub.2 NHCH.sub.3                   X226    CH.sub.2 OCOCH.sub.3X227    CH.sub.2 OCH(CH.sub.3).sub.2______________________________________ 
    
     
                       TABLE 1______________________________________ ##STR7##X.sub.1     X.sub.2        X.sub.3______________________________________Cl          X201           MsCl          X201           ClCl          X202           MsCl          X202           ClCl          X205           MsCl          X205           ClCl          X207           MsCl          X207           ClCl          X208           MsCl          X208           ClCl          X209           MsCl          X209           ClCl          X210           MsCl          X210           ClCl          X201           CF.sub.3Cl          X202           CF.sub.3Cl          X205           CF.sub.3Cl          X207           CF.sub.3Cl          X208           CF.sub.3Cl          X209           CF.sub.3Cl          X210           CF.sub.3Me          X201           MsMe          X201           ClMe          X201           CF.sub.3Me          X202           MsMe          X202           ClMe          X202           CF.sub.3Me          X205           MsMe          X205           ClMe          X205           CF.sub.3Me          X207           MsMe          X207           ClMe          X207           CF.sub.3Me          X208           MsMe          X208           ClMe          X208           CF.sub.3Me          X209           MsMe          X209           ClMe          X209           CF.sub.3Me          X210           MsMe          X210           ClMe          X210           CF.sub.3Cl          X203           MsCl          X203           ClCl          X203           CF.sub.3Cl          X204           MsCl          X204           ClCl          X204           CF.sub.3Cl          X206           MsCl          X206           ClCl          X206           CF.sub.3Cl          X212           MsCl          X212           ClCl          X212           CF.sub.3Cl          X213           MsCl          X213           ClCl          X213           CF.sub.3Cl          X214           MsCl          X214           ClCl          X214           CF.sub.3Cl          X216           MsCl          X216           ClCl          X216           CF.sub.3Cl          X217           MsCl          X217           ClCl          X217           CF.sub.3Cl          X218           MsCl          X218           ClCl          X218           CF.sub.3Cl          X220           MsCl          X220           ClCl          X220           CF.sub.3Cl          X222           MsCl          X222           ClCl          X222           CF.sub.3Cl          X226           MsCl          X226           ClCl          X226           CF.sub.3Cl          X227           MsCl          X227           ClCl          X227           CF.sub.3Me          X203           MsMe          X203           ClMe          X203           CF.sub.3Me          X204           MsMe          X204           ClMe          X204           CF.sub.3Me          X206           MsMe          X206           ClMe          X206           CF.sub.3Me          X212           MsMe          X212           ClMe          X212           CF.sub.3Me          X213           MsMe          X213           ClMe          X213           CF.sub.3Me          X214           MsMe          X214           ClMe          X214           CF.sub.3Me          X216           MsMe          X216           ClMe          X216           CF.sub.3Me          X217           MsMe          X217           ClMe          X217           CF.sub.3Me          X218           MsMe          X218           ClMe          X218           CF.sub.3Me          X220           MsMe          X220           ClMe          X220           CF.sub.3Me          X222           MsMe          X222           ClMe          X222           CF.sub.3Me          X226           MsMe          X226           ClMe          X226           CF.sub.3Me          X227           MsMe          X227           ClMe          X227           CF.sub.3Cl          X211           MsCl          X211           ClCl          X211           CF.sub.3Cl          X215           MsCl          X215           ClCl          X215           CF.sub.3Cl          X219           MsCl          X219           ClCl          X219           CF.sub.3Cl          X221           MsCl          X221           ClCl          X221           CF.sub.3Cl          X223           MsCl          X223           ClCl          X223           CF.sub.3Cl          X224           MsCl          X224           ClCl          X224           CF.sub.3Cl          X225           MsCl          X225           ClCl          X225           CF.sub.3Me          X211           MsMe          X211           ClMe          X211           CF.sub.3Me          X215           MsMe          X215           ClMe          X215           CF.sub.3Me          X219           MsMe          X219           ClMe          X219           CF.sub.3Me          X221           MsMe          X221           ClMe          X221           CF.sub.3Me          X223           MsMe          X223           ClMe          X223           CF.sub.3Me          X224           MsMe          X224           ClMe          X224           CF.sub.3Me          X225           MsMe          X225           ClMe          X225           CF.sub.3NO.sub.2    X201           MsNO.sub.2    X201           ClNO.sub.2    X201           CF.sub.3NO.sub.2    X202           MsNO.sub.2    X202           ClNO.sub.2    X202           CF.sub.3NO.sub.2    X205           MsNO.sub.2    X205           ClNO.sub.2    X205           CF.sub.3NO.sub.2    X207           MsNO.sub.2    X207           ClNO.sub.2    X207           CF.sub.3NO.sub.2    X208           MsNO.sub.2    X208           ClNO.sub.2    X208           CF.sub.3NO.sub.2    X209           MsNO.sub.2    X209           ClNO.sub.2    X209           CF.sub.3NO.sub.2    X210           MsNO.sub.2    X210           ClNO.sub.2    X210           CF.sub.3Et          X201           MsEt          X201           ClEt          X201           CF.sub.3Et          X202           MsEt          X202           ClEt          X202           CF.sub.3Et          X205           MsEt          X205           ClEt          X205           CF.sub.3Et          X207           MsEt          X207           ClEt          X207           CF.sub.3Et          X208           MsEt          X208           ClEt          X208           CF.sub.3Et          X209           MsEt          X209           ClEt          X209           CF.sub.3Et          X210           MsEt          X210           ClEt          X210           CF.sub.3i-Pr        X201           Msi-Pr        X201           Cli-Pr        X201           CF.sub.3i-Pr        X202           Msi-Pr        X202           Cli-Pr        X202           CF.sub.3i-Pr        X205           Msi-Pr        X205           Cli-Pr        X205           CF.sub.3i-Pr        X207           Msi-Pr        X207           Cli-Pr        X207           CF.sub.3i-Pr        X208           Msi-Pr        X208           Cli-Pr        X208           CF.sub.3i-Pr        X209           Msi-Pr        X209           Cli-Pr        X209           CF.sub.3i-Pr        X210           Msi-Pr        X210           Cli-Pr        X210           CF.sub.3n-Pr        X201           Msn-Pr        X201           Cln-Pr        X201           CF.sub.3n-Pr        X202           Msn-Pr        X202           Cln-Pr        X202           CF.sub.3n-Pr        X205           Msn-Pr        X205           Cln-Pr        X205           CF.sub.3n-Pr        X207           Msn-Pr        X207           Cln-Pr        X207           CF.sub.3n-Pr        X208           Msn-Pr        X208           Cln-Pr        X208           CF.sub.3n-Pr        X209           Msn-Pr        X209           Cln-Pr        X209           CF.sub.3n-Pr        X210           Msn-Pr        X210           Cln-Pr        X210           CF.sub.3CN          X201           MsCN          X201           ClCN          X201           CF.sub.3CN          X202           MsCN          X202           ClCN          X202           CF.sub.3CN          X205           MsCN          X205           ClCN          X205           CF.sub.3CN          X207           MsCN          X207           ClCN          X207           CF.sub.3CN          X208           MsCN          X208           ClCN          X208           CF.sub.3CN          X209           MsCN          X209           ClCN          X209           CF.sub.3CN          X210           MsCN          X210           ClCN          X210           CF.sub.3CF.sub.3    X201           MsCF.sub.3    X201           ClCF.sub.3    X201           CF.sub.3CF.sub.3    X202           MsCF.sub.3    X202           ClCF.sub.3    X202           CF.sub.3CF.sub.3    X205           MsCF.sub.3    X205           ClCF.sub.3    X205           CF.sub.3CF.sub.3    X207           MsCF.sub.3    X207           ClCF.sub.3    X207           CF.sub.3CF.sub.3    X208           MsCF.sub.3    X208           ClCF.sub.3    X208           CF.sub.3CF.sub.3    X209           MsCF.sub.3    X209           ClCF.sub.3    X209           CF.sub.3CF.sub.3    X210           MsCF.sub.3    X210           ClCF.sub.3    X210           CF.sub.3F           X201           MsF           X201           ClF           X201           CF.sub.3F           X202           MsF           X202           ClF           X202           CF.sub.3F           X205           MsF           X205           ClF           X205           CF.sub.3F           X207           MsF           X207           ClF           X207           CF.sub.3F           X208           MsF           X208           ClF           X208           CF.sub.3F           X209           MsF           X209           ClF           X209           CF.sub.3F           X210           MsF           X210           ClF           X210           CF.sub.3Br          X201           MsBr          X201           ClBr          X201           CF.sub.3Br          X202           MsBr          X202           ClBr          X202           CF.sub.3Br          X205           MsBr          X205           ClBr          X205           CF.sub.3Br          X207           MsBr          X207           ClBr          X207           CF.sub.3Br          X208           MsBr          X208           ClBr          X208           CF.sub.3Br          X209           MsBr          X209           ClBr          X209           CF.sub.3Br          X210           MsBr          X210           ClBr          X210           CF.sub.3I           X201           MsI           X201           ClI           X201           CF.sub.3I           X202           MsI           X202           ClI           X202           CF.sub.3I           X205           MsI           X205           ClI           X205           CF.sub.3I           X207           MsI           X207           ClI           X207           CF.sub.3I           X208           MsI           X208           ClI           X208           CF.sub.3I           X209           MsI           X209           ClI           X209           CF.sub.3I           X210           MsI           X210           ClI           X210           CF.sub.3MeO         X201           MsMeO         X201           ClMeO         X201           CF.sub.3MeO         X202           MsMeO         X202           ClMeO         X202           CF.sub.3MeO         X205           MsMeO         X205           ClMeO         X205           CF.sub.3MeO         X207           MsMeO         X207           ClMeO         X207           CF.sub.3MeO         X208           MsMeO         X208           ClMeO         X208           CF.sub.3MeO         X209           MsMeO         X209           ClMeO         X209           CF.sub.3MeO         X210           MsMeO         X210           ClMeO         X210           CF.sub.3EtO         X201           MsEtO         X201           ClEtO         X201           CF.sub.3EtO         X202           MsEtO         X202           ClEtO         X202           CF.sub.3EtO         X205           MsEtO         X205           ClEtO         X205           CF.sub.3EtO         X207           MsEtO         X207           ClEtO         X207           CF.sub.3EtO         X208           MsEtO         X208           ClEtO         X208           CF.sub.3EtO         X209           MsEtO         X209           ClEtO         X209           CF.sub.3EtO         X210           MsEtO         X210           ClEtO         X210           CF.sub.3i-PrO       X201           Msi-PrO       X201           Cli-PrO       X201           CF.sub.3i-PrO       X202           Msi-PrO       X202           Cli-PrO       X202           CF.sub.3i-PrO       X205           Msi-PrO       X205           Cli-PrO       X205           CF.sub.3i-PrO       X207           Msi-PrO       X207           Cli-PrO       X207           CF.sub.3i-PrO       X208           Msi-PrO       X208           Cli-PrO       X208           CF.sub.3i-PrO       X209           Msi-PrO       X209           Cli-PrO       X209           CF.sub.3i-PrO       X210           Msi-PrO       X210           Cli-PrO       X210           CF.sub.3n-PrO       X201           Msn-PrO       X201           Cln-PrO       X201           CF.sub.3n-PrO       X202           Msn-PrO       X202           Cln-PrO       X202           CF.sub.3n-PrO       X205           Msn-PrO       X205           Cln-PrO       X205           CF.sub.3n-PrO       X207           Msn-PrO       X207           Cln-PrO       X207           CF.sub.3n-PrO       X208           Msn-PrO       X208           Cln-PrO       X208           CF.sub.3n-PrO       X209           Msn-PrO       X209           Cln-PrO       X209           CF.sub.3n-PrO       X210           Msn-PrO       X210           Cln-PrO       X210           CF.sub.3CHF.sub.2   X201           MsCHF.sub.2   X201           ClCHF.sub.2   X201           CF.sub.3CHF.sub.2   X202           MsCHF.sub.2   X202           ClCHF.sub.2   X202           CF.sub.3CHF.sub.2   X205           MsCHF.sub.2   X205           ClCHF.sub.2   X205           CF.sub.3CHF.sub.2   X207           MsCHF.sub.2   X207           ClCHF.sub.2   X207           CF.sub.3CHF.sub.2   X208           MsCHF.sub.2   X208           ClCHF.sub.2   X208           CF.sub.3CHF.sub.2   X209           MsCHF.sub.2   X209           ClCHF.sub.2   X209           CF.sub.3CHF.sub.2   X210           MsCHF.sub.2   X210           ClCHF.sub.2   X210           CF.sub.3CH.sub.2 CF.sub.3       X201           MsCH.sub.2 CF.sub.3       X201           ClCH.sub.2 CF.sub.3       X201           CF.sub.3CH.sub.2 CF.sub.3       X202           MsCH.sub.2 CF.sub.3       X202           ClCH.sub.2 CF.sub.3       X202           CF.sub.3CH.sub.2 CF.sub.3       X205           MsCH.sub.2 CF.sub.3       X205           ClCH.sub.2 CF.sub.3       X205           CF.sub.3CH.sub.2 CF.sub.3       X207           MsCH.sub.2 CF.sub.3       X207           ClCH.sub.2 CF.sub.3       X207           CF.sub.3CH.sub.2 CF.sub.3       X208           MsCH.sub.2 CF.sub.3       X208           ClCH.sub.2 CF.sub.3       X208           CF.sub.3CH.sub.2 CF.sub.3       X209           MsCH.sub.2 CF.sub.3       X209           ClCH.sub.2 CF.sub.3       X209           CF.sub.3CH.sub.2 CF.sub.3       X210           MsCH.sub.2 CF.sub.3       X210           ClCH.sub.2 CF.sub.3       X210           CF.sub.3X201        X201           MsX201        X201           ClX201        X201           CF.sub.3X201        X202           MsX201        X202           ClX201        X202           CF.sub.3X201        X205           MsX201        X205           ClX201        X205           CF.sub.3X201        X207           MsX201        X207           ClX201        X207           CF.sub.3X201        X208           MsX201        X208           ClX201        X208           CF.sub.3X201        X209           MsX201        X209           ClX201        X209           CF.sub.3X201        X210           MsX201        X210           ClX201        X210           CF.sub.3X201        X203           MsX201        X203           ClX201        X203           CF.sub.3X201        X204           MsX201        X204           ClX201        X204           CF.sub.3X201        X206           MsX201        X206           ClX201        X206           CF.sub.3X201        X212           MsX201        X212           ClX201        X212           CF.sub.3X201        X213           MsX201        X213           ClX201        X213           CF.sub.3X201        X214           MsX201        X214           ClX201        X214           CF.sub.3X201        X216           MsX201        X216           ClX201        X216           CF.sub.3X201        X217           MsX201        X217           ClX201        X217           CF.sub.3X201        X218           MsX201        X218           ClX201        X218           CF.sub.3X201        X220           MsX201        X220           ClX201        X220           CF.sub.3X201        X222           MsX201        X222           ClX201        X222           CF.sub.3X201        X226           MsX201        X226           ClX201        X226           CF.sub.3X201        X227           MsX201        X227           ClX201        X227           CF.sub.3X201        X228           MsX201        X228           ClX201        X228           CF.sub.3X201        X229           MsX201        X229           ClX201        X229           CF.sub.3X201        X230           MsX201        X230           ClX201        X230           CF.sub.3X201        X231           MsX201        X231           ClX201        X231           CF.sub.3X201        X232           MsX201        X232           ClX201        X232           CF.sub.3X201        X233           MsX201        X233           ClX201        X233           CF.sub.3X201        X234           MsX201        X234           ClX201        X234           CF.sub.3X201        X235           MsX201        X235           ClX201        X235           CF.sub.3X202        X201           MsX202        X201           ClX202        X201           CF.sub.3X202        X202           MsX202        X202           ClX202        X202           CF.sub.3X202        X205           MsX202        X205           ClX202        X205           CF.sub.3X202        X207           MsX202        X207           ClX202        X207           CF.sub.3X202        X208           MsX202        X208           ClX202        X208           CF.sub.3X202        X209           MsX202        X209           ClX202        X209           CF.sub.3X202        X210           MsX202        X210           ClX202        X210           CF.sub.3X202        X203           MsX202        X203           ClX202        X203           CF.sub.3X202        X204           MsX202        X204           ClX202        X204           CF.sub.3X202        X206           MsX202        X206           ClX202        X206           CF.sub.3X202        X212           MsX202        X212           ClX202        X212           CF.sub.3X202        X213           MsX202        X213           ClX202        X213           CF.sub.3X202        X214           MsX202        X214           ClX202        X214           CF.sub.3X202        X216           MsX202        X216           ClX202        X216           CF.sub.3X202        X217           MsX202        X217           ClX202        X217           CF.sub.3X202        X218           MsX202        X218           ClX202        X218           CF.sub.3X202        X220           MsX202        X220           ClX202        X220           CF.sub.3X202        X222           MsX202        X222           ClX202        X222           CF.sub.3X202        X226           MsX202        X226           ClX202        X226           CF.sub.3X202        X227           MsX202        X227           ClX202        X227           CF.sub.3X202        X228           MsX202        X228           ClX202        X228           CF.sub.3X202        X229           MsX202        X229           ClX202        X229           CF.sub.3X202        X230           MsX202        X230           ClX202        X230           CF.sub.3X202        X231           MsX202        X231           ClX202        X231           CF.sub.3X202        X232           MsX202        X232           ClX202        X232           CF.sub.3X202        X233           MsX202        X233           ClX202        X233           CF.sub.3X202        X234           MsX202        X234           ClX202        X234           CF.sub.3X202        X235           MsX202        X235           ClX202        X235           CF.sub.3X205        X201           MsX205        X201           ClX205        X201           CF.sub.3X205        X202           MsX205        X202           ClX205        X202           CF.sub.3X205        X205           MsX205        X205           ClX205        X205           CF.sub.3X205        X207           MsX205        X207           ClX205        X207           CF.sub.3X205        X208           MsX205        X208           ClX205        X208           CF.sub.3X205        X209           MsX205        X209           ClX205        X209           CF.sub.3X205        X210           MsX205        X210           ClX205        X210           CF.sub.3X205        X203           MsX205        X203           ClX205        X203           CF.sub.3X205        X204           MsX205        X204           ClX205        X204           CF.sub.3X205        X206           MsX205        X206           ClX205        X206           CF.sub.3X205        X212           MsX205        X212           ClX205        X212           CF.sub.3X205        X213           MsX205        X213           ClX205        X213           CF.sub.3X205        X214           MsX205        X214           ClX205        X214           CF.sub.3X205        X216           MsX205        X216           ClX205        X216           CF.sub.3X205        X217           MsX205        X217           ClX205        X217           CF.sub.3X205        X218           MsX205        X218           ClX205        X218           CF.sub.3X205        X220           MsX205        X220           ClX205        X220           CF.sub.3X205        X222           MsX205        X222           ClX205        X222           CF.sub.3X205        X226           MsX205        X226           ClX205        X226           CF.sub.3X205        X227           MsX205        X227           ClX205        X227           CF.sub.3X205        X228           MsX205        X228           ClX205        X228           CF.sub.3X205        X229           MsX205        X229           ClX205        X229           CF.sub.3X205        X230           MsX205        X230           ClX205        X230           CF.sub.3X205        X231           MsX205        X231           ClX205        X231           CF.sub.3X205        X232           MsX205        X232           ClX205        X232           CF.sub.3X205        X233           MsX205        X233           ClX205        X233           CF.sub.3X205        X234           MsX205        X234           ClX205        X234           CF.sub.3X207        X201           MsX207        X201           ClX207        X201           CF.sub.3X207        X202           MsX207        X202           ClX207        X202           CF.sub.3X207        X205           MsX207        X205           ClX207        X205           CF.sub.3X207        X207           MsX207        X207           ClX207        X207           CF.sub.3X207        X208           MsX207        X208           ClX207        X208           CF.sub.3X207        X209           MsX207        X209           ClX207        X209           CF.sub.3X207        X210           MsX207        X210           ClX207        X210           CF.sub.3X207        X203           MsX207        X203           ClX207        X203           CF.sub.3X207        X204           MsX207        X204           ClX207        X204           CF.sub.3X207        X206           MsX207        X206           ClX207        X206           CF.sub.3X207        X212           MsX207        X212           ClX207        X212           CF.sub.3X207        X213           MsX207        X213           ClX207        X213           CF.sub.3X207        X214           MsX207        X214           ClX207        X214           CF.sub.3X207        X216           MsX207        X216           ClX207        X216           CF.sub.3X207        X217           MsX207        X217           ClX207        X217           CF.sub.3X207        X218           MsX207        X218           ClX207        X218           CF.sub.3X207        X220           MsX207        X220           ClX207        X220           CF.sub.3X207        X222           MsX207        X222           ClX207        X222           CF.sub.3X207        X226           MsX207        X226           ClX207        X226           CF.sub.3X207        X227           MsX207        X227           ClX207        X227           CF.sub.3X208        X201           MsX208        X201           ClX208        X201           CF.sub.3X208        X202           MsX208        X202           ClX208        X202           CF.sub.3X208        X205           MsX208        X205           ClX208        X205           CF.sub.3X208        X207           MsX208        X207           ClX208        X207           CF.sub.3X208        X208           MsX208        X208           ClX208        X208           CF.sub.3X208        X209           MsX208        X209           ClX208        X209           CF.sub.3X208        X210           MsX208        X210           ClX208        X210           CF.sub.3X208        X203           MsX208        X203           ClX208        X203           CF.sub.3X208        X204           MsX208        X204           ClX208        X204           CF.sub.3X208        X206           MsX208        X206           ClX208        X206           CF.sub.3X208        X212           MsX208        X212           ClX208        X212           CF.sub.3X208        X213           MsX208        X213           ClX208        X213           CF.sub.3X208        X214           MsX208        X214           ClX208        X214           CF.sub.3X208        X216           MsX208        X216           ClX208        X216           CF.sub.3X208        X217           MsX208        X217           ClX208        X217           CF.sub.3X208        X218           MsX208        X218           ClX208        X218           CF.sub.3X208        X220           MsX208        X220           ClX208        X220           CF.sub.3X208        X222           MsX208        X222           ClX208        X222           CF.sub.3X208        X226           MsX208        X226           ClX208        X226           CF.sub.3X208        X227           MsX208        X227           ClX208        X227           CF.sub.3X209        X201           MsX209        X201           ClX209        X201           CF.sub.3X209        X202           MsX209        X202           ClX209        X202           CF.sub.3X209        X205           MsX209        X205           ClX209        X205           CF.sub.3X209        X207           MsX209        X207           ClX209        X207           CF.sub.3X209        X208           MsX209        X208           ClX209        X208           CF.sub.3X209        X209           MsX209        X209           ClX209        X209           CF.sub.3X209        X210           MsX209        X210           ClX209        X210           CF.sub.3X209        X203           MsX209        X203           ClX209        X203           CF.sub.3X209        X204           MsX209        X204           ClX209        X204           CF.sub.3X209        X206           MsX209        X206           ClX209        X206           CF.sub.3X209        X212           MsX209        X212           ClX209        X212           CF.sub.3X209        X213           MsX209        X213           ClX209        X213           CF.sub.3X209        X214           MsX209        X214           ClX209        X214           CF.sub.3X209        X216           MsX209        X216           ClX209        X216           CF.sub.3X209        X217           MsX209        X217           ClX209        X217           CF.sub.3X209        X218           MsX209        X218           ClX209        X218           CF.sub.3X209        X220           MsX209        X220           ClX209        X220           CF.sub.3X209        X222           MsX209        X222           ClX209        X222           CF.sub.3X209        X226           MsX209        X226           ClX209        X226           CF.sub.3X209        X227           MsX209        X227           ClX209        X227           CF.sub.3X210        X201           MsX210        X201           ClX210        X201           CF.sub.3X210        X202           MsX210        X202           ClX210        X202           CF.sub.3X210        X205           MsX210        X205           ClX210        X205           CF.sub.3X210        X207           MsX210        X207           ClX210        X207           CF.sub.3X210        X208           MsX210        X208           ClX210        X208           CF.sub.3X210        X209           MsX210        X209           ClX210        X209           CF.sub.3X210        X210           MsX210        X210           ClX210        X210           CF.sub.3X210        X203           MsX210        X203           ClX210        X203           CF.sub.3X210        X204           MsX210        X204           ClX210        X204           CF.sub.3X210        X206           MsX210        X206           ClX210        X206           CF.sub.3X210        X212           MsX210        X212           ClX210        X212           CF.sub.3X210        X213           MsX210        X213           ClX210        X213           CF.sub.3X210        X214           MsX210        X214           ClX210        X214           CF.sub.3X210        X216           MsX210        X216           ClX210        X216           CF.sub.3X210        X217           MsX210        X217           ClX210        X217           CF.sub.3X210        X218           MsX210        X218           ClX210        X218           CF.sub.3X210        X220           MsX210        X220           ClX210        X220           CF.sub.3X210        X222           MsX210        X222           ClX210        X222           CF.sub.3X210        X226           MsX210        X226           ClX210        X226           CF.sub.3X210        X227           MsX210        X227           ClX210        X227           CF.sub.3Cl          X201           NO.sub.2Cl          X201           MeOCl          X201           CNCl          X201           SMeCl          X201           SOMeCl          X201           SO.sub.2 CF.sub.3Cl          X201           BrCl          X201           ICl          X201           EtOCl          X202           NO.sub.2Cl          X202           MeOCl          X202           CNCl          X202           SMeCl          X202           SOMeCl          X202           SO.sub.2 CF.sub.3Cl          X202           BrCl          X202           ICl          X202           EtOCl          X205           NO.sub.2Cl          X205           MeOCl          X205           CNCl          X205           SMeCl          X205           SOMeCl          X205           SO.sub.2 CF.sub.3Cl          X205           BrCl          X205           ICl          X205           EtOCl          X207           NO.sub.2Cl          X207           MeOCl          X207           CNCl          X207           SMeCl          X207           SOMeCl          X207           SO.sub.2 CF.sub.3Cl          X207           BrCl          X207           ICl          X207           EtOCl          X208           NO.sub.2Cl          X208           MeOCl          X208           CNCl          X208           SMeCl          X208           SOMeCl          X208           SO.sub.2 CF.sub.3Cl          X208           BrCl          X208           ICl          X208           EtOCl          X209           NO.sub.2Cl          X209           MeOCl          X209           CNCl          X209           SMeCl          X209           SOMeCl          X209           SO.sub.2 CF.sub.3Cl          X209           BrCl          X209           ICl          X209           EtOCl          X210           NO.sub.2Cl          X210           MeOCl          X210           CNCl          X210           SMeCl          X210           SOMeCl          X210           SO.sub.2 CF.sub.3Cl          X210           BrCl          X210           ICl          X210           EtOMe          X201           NO.sub.2Me          X201           MeOMe          X201           CNMe          X201           SMeMe          X201           SOMeMe          X201           SO.sub.2 CF.sub.3Me          X201           BrMe          X201           IMe          X201           EtOMe          X202           NO.sub.2Me          X202           MeOMe          X202           CNMe          X202           SMeMe          X202           SOMeMe          X202           SO.sub.2 CF.sub.3Me          X202           BrMe          X202           IMe          X202           EtOMe          X205           NO.sub.2Me          X205           MeOMe          X205           CNMe          X205           SMeMe          X205           SOMeMe          X205           SO.sub.2 CF.sub.3Me          X205           BrMe          X205           IMe          X205           EtOMe          X207           NO.sub.2Me          X207           MeOMe          X207           CNMe          X207           SMeMe          X207           SOMeMe          X207           SO.sub.2 CF.sub.3Me          X207           BrMe          X207           IMe          X207           EtOMe          X208           NO.sub.2Me          X208           MeOMe          X208           CNMe          X208           SMeMe          X208           SOMeMe          X208           SO.sub.2 CF.sub.3Me          X208           BrMe          X208           IMe          X208           EtOMe          X209           NO.sub.2Me          X209           MeOMe          X209           CNMe          X209           SMeMe          X209           SOMeMe          X209           SO.sub.2 CF.sub.3Me          X209           BrMe          X209           IMe          X209           EtOMe          X210           NO.sub.2Me          X210           MeOMe          X210           CNMe          X210           SMeMe          X210           SOMeMe          X210           SO.sub.2 CF.sub.3Me          X210           BrMe          X210           IMe          X210           EtO______________________________________ 
    
     
                       TABLE 2______________________________________ ##STR8##X.sub.1         X.sub.2     X.sub.3______________________________________Cl              X201        MsCl              X201        ClCl              X202        MsCl              X202        ClCl              X205        MsCl              X205        ClCl              X207        MsCl              X207        ClCl              X208        MsCl              X208        ClCl              X209        MsCl              X209        ClCl              X210        MsCl              X210        ClCl              X201        CF.sub.3Cl              X202        CF.sub.3Cl              X205        CF.sub.3Cl              X207        CF.sub.3Cl              X208        CF.sub.3Cl              X209        CF.sub.3Cl              X210        CF.sub.3Me              X201        MsMe              X201        ClMe              X201        CF.sub.3Me              X202        MsMe              X202        ClMe              X202        CF.sub.3Me              X205        MsMe              X205        ClMe              X205        CF.sub.3Me              X207        MsMe              X207        ClMe              X207        CF.sub.3Me              X208        MsMe              X208        ClMe              X208        CF.sub.3Me              X209        MsMe              X209        ClMe              X209        CF.sub.3Me              X210        MsMe              X210        ClMe              X210        CF.sub.3Cl              X203        MsCl              X203        ClCl              X203        CF.sub.3Cl              X204        MsCl              X204        ClCl              X204        CF.sub.3Cl              X206        MsCl              X206        ClCl              X206        CF.sub.3Cl              X212        MsCl              X212        ClCl              X212        CF.sub.3Cl              X213        MsCl              X213        ClCl              X213        CF.sub.3Cl              X214        MsCl              X214        ClCl              X214        CF.sub.3Cl              X216        MsCl              X216        ClCl              X216        CF.sub.3Cl              X217        MsCl              X217        ClCl              X217        CF.sub.3Cl              X218        MsCl              X218        ClCl              X218        CF.sub.3Cl              X220        MsCl              X220        ClCl              X220        CF.sub.3Cl              X222        MsCl              X222        ClCl              X222        CF.sub.3Cl              X226        MsCl              X226        ClCl              X226        CF.sub.3Cl              X227        MsCl              X227        ClCl              X227        CF.sub.3Me              X203        MsMe              X203        ClMe              X203        CF.sub.3Me              X204        MsMe              X204        ClMe              X204        CF.sub.3Me              X206        MsMe              X206        ClMe              X206        CF.sub.3Me              X212        MsMe              X212        ClMe              X212        CF.sub.3Me              X213        MsMe              X213        ClMe              X213        CF.sub.3Me              X214        MsMe              X214        ClMe              X214        CF.sub.3Me              X216        MsMe              X216        ClMe              X216        CF.sub.3Me              X217        MsMe              X217        ClMe              X217        CF.sub.3Me              X218        MsMe              X218        ClMe              X218        CF.sub.3Me              X220        MsMe              X220        ClMe              X220        CF.sub.3Me              X222        MsMe              X222        ClMe              X222        CF.sub.3Me              X226        MsMe              X226        ClMe              X226        CF.sub.3Me              X227        MsMe              X227        ClMe              X227        CF.sub.3Cl              X211        MsCl              X211        ClCl              X211        CF.sub.3Cl              X215        MsCl              X215        ClCl              X215        CF.sub.3Cl              X219        MsCl              X219        ClCl              X219        CF.sub.3Cl              X221        MsCl              X221        ClCl              X221        CF.sub.3Cl              X223        MsCl              X223        ClCl              X223        CF.sub.3Cl              X224        MsCl              X224        ClCl              X224        CF.sub.3Cl              X225        MsCl              X225        ClCl              X225        CF.sub.3Me              X211        MsMe              X211        ClMe              X211        CF.sub.3Me              X215        MsMe              X215        ClMe              X215        CF.sub.3Me              X219        MsMe              X219        ClMe              X219        CF.sub.3Me              X221        MsMe              X221        ClMe              X221        CF.sub.3Me              X223        MsMe              X223        ClMe              X223        CF.sub.3Me              X224        MsMe              X224        ClMe              X224        CF.sub.3Me              X225        MsMe              X225        ClMe              X225        CF.sub.3NO.sub.2        X201        MsNO.sub.2        X201        ClNO.sub.2        X201        CF.sub.3NO.sub.2        X202        MsNO.sub.2        X202        ClNO.sub.2        X202        CF.sub.3NO.sub.2        X205        MsNO.sub.2        X205        ClNO.sub.2        X205        CF.sub.3NO.sub.2        X207        MsNO.sub.2        X207        ClNO.sub.2        X207        CF.sub.3NO.sub.2        X208        MsNO.sub.2        X208        ClNO.sub.2        X208        CF.sub.3NO.sub.2        X209        MsNO.sub.2        X209        ClNO.sub.2        X209        CF.sub.3NO.sub.2        X210        MsNO.sub.2        X210        ClNO.sub.2        X210        CF.sub.3Et              X201        MsEt              X201        ClEt              X201        CF.sub.3Et              X202        MsEt              X202        ClEt              X202        CF.sub.3Et              X205        MsEt              X205        ClEt              X205        CF.sub.3Et              X207        MsEt              X207        ClEt              X207        CF.sub.3Et              X208        MsEt              X208        ClEt              X208        CF.sub.3Et              X209        MsEt              X209        ClEt              X209        CF.sub.3Et              X210        MsEt              X210        ClEt              X210        CF.sub.3i-Pr            X201        Msi-Pr            X201        Cli-Pr            X201        CF.sub.3i-Pr            X202        Msi-Pr            X202        Cli-Pr            X202        CF.sub.3i-Pr            X205        Msi-Pr            X205        Cli-Pr            X205        CF.sub.3i-Pr            X207        Msi-Pr            X207        Cli-Pr            X207        CF.sub.3i-Pr            X208        Msi-Pr            X208        Cli-Pr            X208        CF.sub.3i-Pr            X209        Msi-Pr            X209        Cli-Pr            X209        CF.sub.3i-Pr            X210        Msi-Pr            X210        Cli-Pr            X210        CF.sub.3n-Pr            X201        Msn-Pr            X201        Cln-Pr            X201        CF.sub.3n-Pr            X202        Msn-Pr            X202        Cln-Pr            X202        CF.sub.3n-Pr            X205        Msn-Pr            X205        Cln-Pr            X205        CF.sub.3n-Pr            X207        Msn-Pr            X207        Cln-Pr            X207        CF.sub.3n-Pr            X208        Msn-Pr            X208        Cln-Pr            X208        CF.sub.3n-Pr            X209        Msn-Pr            X209        Cln-Pr            X209        CF.sub.3n-Pr            X210        Msn-Pr            X210        Cln-Pr            X210        CF.sub.3CN              X201        MsCN              X201        ClCN              X201        CF.sub.3CN              X202        MsCN              X202        ClCN              X202        CF.sub.3CN              X205        MsCN              X205        ClCN              X205        CF.sub.3CN              X207        MsCN              X207        ClCN              X207        CF.sub.3CN              X208        MsCN              X208        ClCN              X208        CF.sub.3CN              X209        MsCN              X209        ClCN              X209        CF.sub.3CN              X210        MsCN              X210        ClCN              X210        CF.sub.3CF.sub.3        X201        MsCF.sub.3        X201        ClCF.sub.3        X201        CF.sub.3CF.sub.3        X202        MsCF.sub.3        X202        ClCF.sub.3        X202        CF.sub. 3CF.sub.3        X205        MsCF.sub.3        X205        ClCF.sub.3        X205        CF.sub.3CF.sub.3        X207        MsCF.sub.3        X207        ClCF.sub.3        X207        CF.sub.3CF.sub.3        X208        MsCF.sub.3        X208        ClCF.sub.3        X208        CF.sub.3CF.sub.3        X209        MsCF.sub.3        X209        ClCF.sub.3        X209        CF.sub.3CF.sub.3        X210        MsCF.sub.3        X210        ClCF.sub.3        X210        CF.sub.3F               X201        MsF               X201        ClF               X201        CF.sub.3F               X202        MsF               X202        ClF               X202        CF.sub.3F               X205        MsF               X205        ClF               X205        CF.sub.3F               X207        MsF               X207        ClF               X207        CF.sub.3F               X208        MsF               X208        ClF               X208        CF.sub.3F               X209        MsF               X209        ClF               X209        CF.sub.3F               X210        MsF               X210        ClF               X210        CF.sub.3Br              X201        MsBr              X201        ClBr              X201        CF.sub.3Br              X202        MsBr              X202        ClBr              X202        CF.sub.3Br              X205        MsBr              X205        ClBr              X205        CF.sub.3Br              X207        MsBr              X207        ClBr              X207        CF.sub.3Br              X208        MsBr              X208        ClBr              X208        CF.sub.3Br              X209        MsBr              X209        ClBr              X209        CF.sub.3Br              X210        MsBr              X210        ClBr              X210        CF.sub.3I               X201        MsI               X201        ClI               X201        CF.sub.3I               X202        MsI               X202        ClI               X202        CF.sub.3I               X205        MsI               X205        ClI               X205        CF.sub.3I               X207        MsI               X207        ClI               X207        CF.sub.3I               X208        MsI               X208        ClI               X208        CF.sub.3I               X209        MsI               X209        ClI               X209        CF.sub.3I               X210        MsI               X210        ClI               X210        CF.sub.3MeO             X201        MsMeO             X201        ClMeO             X201        CF.sub.3MeO             X202        MsMeO             X202        ClMeO             X202        CF.sub.3MeO             X205        MsMeO             X205        ClMeO             X205        CF.sub.3MeO             X207        MsMeO             X207        ClMeO             X207        CF.sub.3MeO             X208        MsMeO             X208        ClMeO             X208        CF.sub.3MeO             X209        MsMeO             X209        ClMeO             X209        CF.sub.3MeO             X210        MsMeO             X210        ClMeO             X210        CF.sub.3EtO             X201        MsEtO             X201        ClEtO             X201        CF.sub.3EtO             X202        MsEtO             X202        ClEtO             X202        CF.sub.3EtO             X205        MsEtO             X205        ClEtO             X205        CF.sub.3EtO             X207        MsEtO             X207        ClEtO             X207        CF.sub.3EtO             X208        MsEtO             X208        ClEtO             X208        CF.sub.3EtO             X209        MsEtO             X209        ClEtO             X209        CF.sub.3EtO             X210        MsEtO             X210        ClEtO             X210        CF.sub.3i-PrO           X201        Msi-PrO           X201        Cli-PrO           X201        CF.sub.3i-PrO           X202        Msi-PrO           X202        Cli-PrO           X202        CF.sub.3i-PrO           X205        Msi-PrO           X205        Cli-PrO           X205        CF.sub.3i-PrO           X207        Msi-PrO           X207        Cli-PrO           X207        CF.sub.3i-PrO           X208        Msi-PrO           X208        Cli-PrO           X208        CF.sub.3i-PrO           X209        Msi-PrO           X209        Cli-PrO           X209        CF.sub.3i-PrO           X210        Msi-PrO           X210        Cli-PrO           X210        CF.sub.3n-PrO           X201        Msn-PrO           X201        Cln-PrO           X201        CF.sub.3n-PrO           X202        Msn-PrO           X202        Cln-PrO           X202        CF.sub.3n-PrO           X205        Msn-PrO           X205        Cln-PrO           X205        CF.sub.3n-PrO           X207        Msn-PrO           X207        Cln-PrO           X207        CF.sub.3n-PrO           X208        Msn-PrO           X208        Cln-PrO           X208        CF.sub.3n-PrO           X209        Msn-PrO           X209        Cln-PrO           X209        CF.sub.3n-PrO           X210        Msn-PrO           X210        Cln-PrO           X210        CF.sub.3CHF.sub.2       X201        MsCHF.sub.2       X201        ClCHF.sub.2       X201        CF.sub.3CHF.sub.2       X202        MsCHF.sub.2       X202        ClCHF.sub.2       X202        CF.sub.3CHF.sub.2       X205        MsCHF.sub.2       X205        ClCHF.sub.2       X205        CF.sub.3CHF.sub.2       X207        MsCHF.sub. 2      X207        ClCHF.sub.2       X207        CF.sub.3CHF.sub.2       X208        MsCHF.sub.2       X208        ClCHF.sub.2       X208        CF.sub.3CHF.sub.2       X209        MsCHF.sub.2       X209        ClCHF.sub.2       X209        CF.sub.3CHF.sub.2       X210        MsCHF.sub.2       X210        ClCHF.sub.2       X210        CF.sub.3CH.sub.2 CF.sub.3           X201        MsCH.sub.2 CF.sub.3           X201        ClCH.sub.2 CF.sub.3           X201        CF.sub.3CH.sub.2 CF.sub.3           X202        MsCH.sub.2 CF.sub.3           X202        ClCH.sub.2 CF.sub.3           X202        CF.sub.3CH.sub.2 CF.sub.3           X205        MsCH.sub.2 CF.sub.3           X205        ClCH.sub.2 CF.sub.3           X205        CF.sub.3CH.sub.2 CF.sub.3           X207        MsCH.sub.2 CF.sub.3           X207        ClCH.sub.2 CF.sub.3           X207        CF.sub.3CH.sub.2 CF.sub.3           X208        MsCH.sub.2 CF.sub.3           X208        ClCH.sub.2 CF.sub.3           X208        CF.sub.3CH.sub.2 CF.sub.3           X209        MsCH.sub.2 CF.sub.3           X209        ClCH.sub.2 CF.sub.3           X209        CF.sub.3CH.sub.2 CF.sub.3           X210        MsCH.sub.2 CF.sub.3           X210        ClCH.sub.2 CF.sub.3           X210        CF.sub.3X201            X201        MsX201            X201        ClX201            X201        CF.sub.3X201            X202        MsX201            X202        ClX201            X202        CF.sub.3X201            X205        MsX201            X205        ClX201            X205        CF.sub.3X201            X207        MsX201            X207        ClX201            X207        CF.sub.3X201            X208        MsX201            X208        ClX201            X208        CF.sub.3X201            X209        MsX201            X209        ClX201            X209        CF.sub.3X201            X210        MsX201            X210        ClX201            X210        CF.sub.3X201            X203        MsX201            X203        ClX201            X203        CF.sub.3X201            X204        MsX201            X204        ClX201            X204        CF.sub.3X201            X206        MsX201            X206        ClX201            X206        CF.sub.3X201            X212        MsX201            X212        ClX201            X212        CF.sub.3X201            X213        MsX201            X213        ClX201            X213        CF.sub.3X201            X214        MsX201            X214        ClX201            X214        CF.sub.3X201            X216        MsX201            X216        ClX201            X216        CF.sub.3X201            X217        MsX201            X217        ClX201            X217        CF.sub.3X201            X218        MsX201            X218        ClX201            X218        CF.sub.3X201            X220        MsX201            X220        ClX201            X220        CF.sub.3X201            X222        MsX201            X222        ClX201            X222        CF.sub.3X201            X226        MsX201            X226        ClX201            X226        CF.sub.3X201            X227        MsX201            X227        ClX201            X227        CF.sub.3X201            X228        MsX201            X228        ClX201            X228        CF.sub.3X201            X229        MsX201            X229        ClX201            X229        CF.sub.3X201            X230        MsX201            X230        ClX201            X230        CF.sub.3X201            X231        MsX201            X231        ClX201            X231        CF.sub.3X201            X232        MsX201            X232        ClX201            X232        CF.sub.3X201            X233        MsX201            X233        ClX201            X233        CF.sub.3X201            X234        MsX201            X234        ClX201            X234        CF.sub.3X201            X235        MsX201            X235        ClX201            X235        CF.sub.3X202            X201        MsX202            X201        ClX202            X201        CF.sub.3X202            X202        MsX202            X202        ClX202            X202        CF.sub.3X202            X205        MsX202            X205        ClX202            X205        CF.sub.3X202            X207        MsX202            X207        ClX202            X207        CF.sub.3X202            X208        MsX202            X208        ClX202            X208        CF.sub.3X202            X209        MsX202            X209        ClX202            X209        CF.sub.3X202            X210        MsX202            X210        ClX202            X210        CF.sub.3X202            X203        MsX202            X203        ClX202            X203        CF.sub.3X202            X204        MsX202            X204        ClX202            X204        CF.sub.3X202            X206        MsX202            X206        ClX202            X206        CF.sub.3X202            X212        MsX202            X212        ClX202            X212        CF.sub.3X202            X213        MsX202            X213        ClX202            X213        CF.sub.3X202            X214        MsX202            X214        ClX202            X214        CF.sub.3X202            X216        MsX202            X216        ClX202            X216        CF.sub.3X202            X217        MsX202            X217        ClX202            X217        CF.sub.3X202            X218        MsX202            X218        ClX202            X218        CF.sub.3X202            X220        MsX202            X220        ClX202            X220        CF.sub.3X202            X222        MsX202            X222        ClX202            X222        CF.sub.3X202            X226        MsX202            X226        ClX202            X226        CF.sub.3X202            X227        MsX202            X227        ClX202            X227        CF.sub.3X202            X228        MsX202            X228        ClX202            X228        CF.sub.3X202            X229        MsX202            X229        ClX202            X229        CF.sub.3X202            X230        MsX202            X230        ClX202            X230        CF.sub.3X202            X231        MsX202            X231        ClX202            X231        CF.sub.3X202            X232        MsX202            X232        ClX202            X232        CF.sub.3X202            X233        MsX202            X233        ClX202            X233        CF.sub.3X202            X234        MsX202            X234        ClX202            X234        CF.sub.3X202            X235        MsX202            X235        ClX202            X235        CF.sub.3X205            X201        MsX205            X201        ClX205            X201        CF.sub.3X205            X202        MsX205            X202        ClX205            X202        CF.sub.3X205            X205        MsX205            X205        ClX205            X205        CF.sub.3X205            X207        MsX205            X207        ClX205            X207        CF.sub.3X205            X208        MsX205            X208        ClX205            X208        CF.sub.3X205            X209        MsX205            X209        ClX205            X209        CF.sub.3X205            X210        MsX205            X210        ClX205            X210        CF.sub.3X205            X203        MsX205            X203        ClX205            X203        CF.sub.3X205            X204        MsX205            X204        ClX205            X204        CF.sub.3X205            X206        MsX205            X206        ClX205            X206        CF.sub.3X205            X212        MsX205            X212        ClX205            X212        CF.sub.3X205            X213        MsX205            X213        ClX205            X213        CF.sub.3X205            X214        MsX205            X214        ClX205            X214        CF.sub.3X205            X216        MsX205            X216        ClX205            X216        CF.sub.3X205            X217        MsX205            X217        ClX205            X217        CF.sub.3X205            X218        MsX205            X218        ClX205            X218        CF.sub.3X205            X220        MsX205            X220        ClX205            X220        CF.sub.3X205            X222        MsX205            X222        ClX205            X222        CF.sub.3X205            X226        MsX205            X226        ClX205            X226        CF.sub.3X205            X227        MsX205            X227        ClX205            X227        CF.sub.3X205            X228        MsX205            X228        ClX205            X228        CF.sub.3X205            X229        MsX205            X229        ClX205            X229        CF.sub.3X205            X230        MsX205            X230        ClX205            X230        CF.sub.3X205            X231        MsX205            X231        ClX205            X231        CF.sub.3X205            X232        MsX205            X232        ClX205            X232        CF.sub.3X205            X233        MsX205            X233        ClX205            X233        CF.sub.3X205            X234        MsX205            X234        ClX205            X234        CF.sub.3X207            X201        MsX205            X201        ClX207            X201        CF.sub.3X207            X202        MsX207            X202        ClX207            X202        CF.sub.3X207            X205        MsX207            X205        ClX207            X205        CF.sub.3X207            X207        MsX207            X207        ClX207            X207        CF.sub.3X207            X208        MsX207            X208        ClX207            X208        CF.sub.3X207            X209        MsX207            X209        ClX207            X209        CF.sub.3X207            X210        MsX207            X210        ClX207            X210        CF.sub.3X207            X203        MsX207            X203        ClX207            X203        CF.sub.3X207            X204        MsX207            X204        ClX207            X204        CF.sub.3X207            X206        MsX207            X206        ClX207            X206        CF.sub.3X207            X212        MsX207            X212        ClX207            X212        CF.sub.3X207            X213        MsX207            X213        ClX207            X213        CF.sub.3X207            X214        MsX207            X214        ClX207            X214        CF.sub.3X207            X216        MsX207            X216        ClX207            X216        CF.sub.3X207            X217        MsX207            X217        ClX207            X217        CF.sub.3X207            X218        MsX207            X218        ClX207            X218        CF.sub.3X207            X220        MsX207            X220        ClX207            X220        CF.sub.3X207            X222        MsX207            X222        ClX207            X222        CF.sub.3X207            X226        MsX207            X226        ClX207            X226        CF.sub.3X207            X227        MsX207            X227        ClX207            X227        CF.sub.3X208            X201        MsX208            X201        ClX208            X201        CF.sub.3X208            X202        MsX208            X202        ClX208            X202        CF.sub.3X208            X205        MsX208            X205        ClX208            X205        CF.sub.3X208            X207        MsX208            X207        ClX208            X207        CF.sub.3X208            X208        MsX208            X208        ClX208            X208        CF.sub.3X208            X209        MsX208            X209        ClX208            X209        CF.sub.3X208            X210        MsX208            X210        ClX208            X210        CF.sub.3X208            X203        MsX208            X203        ClX208            X203        CF.sub.3X208            X204        MsX208            X204        ClX208            X204        CF.sub.3X208            X206        MsX208            X206        ClX208            X206        CF.sub.3X208            X212        MsX208            X212        ClX208            X212        CF.sub.3X208            X213        MsX208            X213        ClX208            X213        CF.sub.3X208            X214        MsX208            X214        ClX208            X214        CF.sub.3X208            X216        MsX208            X216        ClX208            X216        CF.sub.3X208            X217        MsX208            X217        ClX208            X217        CF.sub.3X208            X218        MsX208            X218        ClX208            X218        CF.sub.3X208            X220        MsX208            X220        ClX208            X220        CF.sub.3X208            X222        MsX208            X222        ClX208            X222        CF.sub.3X208            X226        MsX208            X226        ClX208            X226        CF.sub.3X208            X227        MsX208            X227        ClX208            X227        CF.sub.3X209            X201        MsX209            X201        ClX209            X201        CF.sub.3X209            X202        MsX209            X202        ClX209            X202        CF.sub.3X209            X205        MsX209            X205        ClX209            X205        CF.sub.3X209            X207        MsX209            X207        ClX209            X207        CF.sub.3X209            X208        MsX209            X208        ClX209            X208        CF.sub.3X209            X209        MsX209            X209        ClX209            X209        CF.sub.3X209            X210        MsX209            X210        ClX209            X210        CF.sub.3X209            X203        MsX209            X203        ClX209            X203        CF.sub.3X209            X204        MsX209            X204        ClX209            X204        CF.sub.3X209            X206        MsX209            X206        ClX209            X206        CF.sub.3X209            X212        MsX209            X212        ClX209            X212        CF.sub.3X209            X213        MsX209            X213        ClX209            X213        CF.sub.3X209            X214        MsX209            X214        ClX209            X214        CF.sub.3X209            X216        MsX209            X216        ClX209            X216        CF.sub.3X209            X217        MsX209            X217        ClX209            X217        CF.sub.3X209            X218        MsX209            X218        ClX209            X218        CF.sub.3X209            X220        MsX209            X220        ClX209            X220        CF.sub.3X209            X222        MsX209            X222        ClX209            X222        CF.sub.3X209            X226        MsX209            X226        ClX209            X226        CF.sub.3X209            X227        MsX209            X227        ClX209            X227        CF.sub.3X210            X201        MsX210            X201        ClX210            X201        CF.sub.3X210            X202        MsX210            X202        ClX210            X202        CF.sub.3X210            X205        MsX210            X205        ClX210            X205        CF.sub.3X210            X207        MsX210            X207        ClX210            X207        CF.sub.3X210            X208        MsX210            X208        ClX210            X208        CF.sub.3X210            X209        MsX210            X209        ClX210            X209        CF.sub.3X210            X210        MsX210            X210        ClX210            X210        CF.sub.3X210            X203        MsX210            X203        ClX210            X203        CF.sub.3X210            X204        MsX210            X204        ClX210            X204        CF.sub.3X210            X206        MsX210            X206        ClX210            X206        CF.sub.3X210            X212        MsX210            X212        ClX210            X212        CF.sub.3X210            X213        MsX210            X213        ClX210            X213        CF.sub.3X210            X214        MsX210            X214        ClX210            X214        CF.sub.3X210            X216        MsX210            X216        ClX210            X216        CF.sub.3X210            X217        MsX210            X217        ClX210            X217        CF.sub.3X210            X218        MsX210            X218        ClX210            X218        CF.sub.3X210            X220        MsX210            X220        ClX210            X220        CF.sub.3X210            X222        MsX210            X222        ClX210            X222        CF.sub.3X210            X226        MsX210            X226        ClX210            X226        CF.sub.3X210            X227        MsX210            X227        ClX210            X227        CF.sub.3Cl              X201        NO.sub.2Cl              X201        MeOCl              X201        CNCl              X201        SMeCl              X201        SOMeCl              X201        SO.sub.2 CF.sub.3Cl              X201        BrCl              X201        ICl              X201        EtOCl              X202        NO.sub.2Cl              X202        MeOCl              X202        CNCl              X202        SMeCl              X202        SOMeCl              X202        SO.sub.2 CF.sub.3Cl              X202        BrCl              X202        ICl              X202        EtOCl              X205        NO.sub.2Cl              X205        MeOCl              X205        CNCl              X205        SMeCl              X205        SOMeCl              X205        SO.sub.2 CF.sub.3Cl              X205        BrCl              X205        ICl              X205        EtOCl              X207        NO.sub.2Cl              X207        MeOCl              X207        CNCl              X207        SMeCl              X207        SOMeCl              X207        SO.sub.2 CF.sub.3Cl              X207        BrCl              X207        ICl              X207        EtOCl              X208        NO.sub.2Cl              X208        MeOCl              X208        CNCl              X208        SMeCl              X208        SOMeCl              X208        SO.sub.2 CF.sub.3Cl              X208        BrCl              X208        ICl              X208        EtOCl              X209        NO.sub.2Cl              X209        MeOCl              X209        CNCl              X209        SMeCl              X209        SOMeCl              X209        SO.sub.2 CF.sub.3Cl              X209        BrCl              X209        ICl              X209        EtOCl              X210        NO.sub.2Cl              X210        MeOCl              X210        CNCl              X210        SMeCl              X210        SOMeCl              X210        SO.sub.2 CF.sub.3Cl              X210        BrCl              X210        ICl              X210        EtOMe              X201        NO.sub.2Me              X201        MeOMe              X201        CNMe              X201        SMeMe              X201        SOMeMe              X201        SO.sub.2 CF.sub.3Me              X201        BrMe              X201        IMe              X201        EtOMe              X202        NO.sub.2Me              X202        MeOMe              X202        CNMe              X202        SMeMe              X202        SOMeMe              X202        SO.sub.2 CF.sub.3Me              X202        BrMe              X202        IMe              X202        EtOMe              X205        NO.sub.2Me              X205        MeOMe              X205        CNMe              X205        SMeMe              X20         SOMeMe              X205        SO.sub.2 CF.sub.3Me              X205        BrMe              X205        IMe              X205        EtOMe              X207        NO.sub.2Me              X207        MeOMe              X207        CNMe              X207        SMeMe              X207        SOMeMe              X207        SO.sub.2 CF.sub.3Me              X207        BrMe              X207        IMe              X207        EtOMe              X208        NO.sub.2Me              X208        MeOMe              X208        CNMe              X208        SMeMe              X208        SOMeMe              X208        SO.sub.2 CF.sub.3Me              X208        BrMe              X208        IMe              X208        EtOMe              X209        NO.sub.2Me              X209        MeOMe              X209        CNMe              X209        SMeMe              X209        SOMeMe              X209        SO.sub.2 CF.sub.3Me              X209        BrMe              X209        IMe              X209        EtOMe              X210        NO.sub.2Me              X210        MeOMe              X210        CNMe              X210        SMeMe              X210        SOMeMe              X210        SO.sub.2 CF.sub.3Me              X210        BrMe              X210        IMe              X210        EtO______________________________________ 
    
     
                       TABLE 3______________________________________ ##STR9##X.sub.1         X.sub.2     X.sub.3______________________________________Cl              X201        MsCl              X201        ClCl              X202        MsCl              X202        ClCl              X205        MsCl              X205        ClCl              X207        MsCl              X207        ClCl              X208        MsCl              X208        ClCl              X209        MsCl              X209        ClCl              X210        MsCl              X210        ClCl              X201        CF.sub.3Cl              X202        CF.sub.3Cl              X205        CF.sub.3Cl              X207        CF.sub.3Cl              X208        CF.sub.3Cl              X209        CF.sub.3Cl              X210        CF.sub.3Me              X201        MsMe              X201        ClMe              X201        CF.sub.3Me              X202        MsMe              X202        ClMe              X202        CF.sub.3Me              X205        MsMe              X205        ClMe              X205        CF.sub.3Me              X207        MsMe              X207        ClMe              X207        CF.sub.3Me              X208        MsMe              X208        ClMe              X208        CF.sub.3Me              X209        MsMe              X209        ClMe              X209        CF.sub.3Me              X210        MsMe              X210        ClMe              X210        CF.sub.3Cl              X203        MsCl              X203        ClCl              X203        CF.sub.3Cl              X204        MsCl              X204        ClCl              X204        CF.sub.3Cl              X206        MsCl              X206        ClCl              X206        CF.sub.3Cl              X212        MsCl              X212        ClCl              X212        CF.sub.3Cl              X213        MsCl              X213        ClCl              X213        CF.sub.3Cl              X214        MsCl              X214        ClCl              X214        CF.sub.3Cl              X216        MsCl              X216        ClCl              X216        CF.sub.3Cl              X217        MsCl              X217        ClCl              X217        CF.sub.3Cl              X218        MsCl              X218        ClCl              X218        CF.sub.3Cl              X220        MsCl              X220        ClCl              X220        CF.sub.3Cl              X222        MsCl              X222        ClCl              X222        CF.sub.3Cl              X226        MsCl              X226        ClCl              X226        CF.sub.3Cl              X227        MsCl              X227        ClCl              X227        CF.sub.3Me              X203        MsMe              X203        ClMe              X203        CF.sub.3Me              X204        MsMe              X204        ClMe              X204        CF.sub.3Me              X206        MsMe              X206        ClMe              X206        CF.sub.3Me              X212        MsMe              X212        ClMe              X212        CF.sub.3Me              X213        MsMe              X213        ClMe              X213        CF.sub.3Me              X214        MsMe              X214        ClMe              X214        CF.sub.3Me              X216        MsMe              X216        ClMe              X216        CF.sub.3Me              X217        MsMe              X217        ClMe              X217        CF.sub.3Me              X218        MsMe              X218        ClMe              X218        CF.sub.3Me              X220        MsMe              X220        ClMe              X220        CF.sub.3Me              X222        MsMe              X222        ClMe              X222        CF.sub.3Me              X226        MsMe              X226        ClMe              X226        CF.sub.3Me              X227        MsMe              X227        ClMe              X227        CF.sub.3Cl              X211        MsCl              X211        ClCl              X211        CF.sub.3Cl              X215        MsCl              X215        ClCl              X215        CF.sub.3Cl              X219        MsCl              X219        ClCl              X219        CF.sub.3Cl              X221        MsCl              X221        ClCl              X221        CF.sub.3Cl              X223        MsCl              X223        ClCl              X223        CF.sub.3Cl              X224        MsCl              X224        ClCl              X224        CF.sub.3Cl              X225        MsCl              X225        ClCl              X225        CF.sub.3Me              X211        MsMe              X211        ClMe              X211        CF.sub.3Me              X215        MsMe              X215        ClMe              X215        CF.sub.3Me              X219        MsMe              X219        ClMe              X219        CF.sub.3Me              X221        MsMe              X221        ClMe              X221        CF.sub.3Me              X223        MsMe              X223        ClMe              X223        CF.sub.3Me              X224        MsMe              X224        ClMe              X224        CF.sub.3Me              X225        MsMe              X225        ClMe              X225        CF.sub.3NO.sub.2        X201        MsNO.sub.2        X201        ClNO.sub.2        X201        CF.sub.3NO.sub.2        X202        MsNO.sub.2        X202        ClNO.sub.2        X202        CF.sub.3NO.sub.2        X205        MsNO.sub.2        X205        ClNO.sub.2        X205        CF.sub.3NO.sub.2        X207        MsNO.sub.2        X207        ClNO.sub.2        X207        CF.sub.3NO.sub.2        X208        MsNO.sub.2        X208        ClNO.sub.2        X208        CF.sub.3NO.sub.2        X209        MsNO.sub.2        X209        ClNO.sub.2        X209        CF.sub.3NO.sub.2        X210        MsNO.sub.2        X210        ClNO.sub.2        X210        CF.sub.3Et              X201        MsEt              X201        ClEt              X201        CF.sub.3Et              X202        MsEt              X202        ClEt              X202        CF.sub.3Et              X205        MsEt              X205        ClEt              X205        CF.sub.3Et              X207        MsEt              X207        ClEt              X207        CF.sub.3Et              X208        MsEt              X208        ClEt              X208        CF.sub.3Et              X209        MsEt              X209        ClEt              X209        CF.sub.3Et              X210        MsEt              X210        ClEt              X210        CF.sub.3i-Pr            X201        Msi-Pr            X201        Cli-Pr            X201        CF.sub.3i-Pr            X202        Msi-Pr            X202        Cli-Pr            X202        CF.sub.3i-Pr            X205        Msi-Pr            X205        Cli-Pr            X205        CF.sub.3i-Pr            X207        Msi-Pr            X207        Cli-Pr            X207        CF.sub.3i-Pr            X208        Msi-Pr            X208        Cli-Pr            X208        CF.sub.3i-Pr            X209        Msi-Pr            X209        Cli-Pr            X209        CF.sub.3i-Pr            X210        Msi-Pr            X210        Cli-Pr            X210        CF.sub.3n-Pr            X201        Msn-Pr            X201        Cln-Pr            X201        CF.sub.3n-Pr            X202        Msn-Pr            X202        Cln-Pr            X202        CF.sub.3n-Pr            X205        Msn-Pr            X205        Cln-Pr            X205        CF.sub.3n-Pr            X207        Msn-Pr            X207        Cln-Pr            X207        CF.sub.3n-Pr            X208        Msn-Pr            X208        Cln-Pr            X208        CF.sub.3n-Pr            X209        Msn-Pr            X209        Cln-Pr            X209        CF.sub.3n-Pr            X210        Msn-Pr            X210        Cln-Pr            X210        CF.sub.3CN              X201        MsCN              X201        ClCN              X201        CF.sub.3CN              X202        MsCN              X202        ClCN              X202        CF.sub.3CN              X205        MsCN              X205        ClCN              X205        CF.sub.3CN              X207        MsCN              X207        ClCN              X207        CF.sub.3CN              X208        MsCN              X208        ClCN              X208        CF.sub.3CN              X209        MsCN              X209        ClCN              X209        CF.sub.3CN              X210        MsCN              X210        ClCN              X210        CF.sub.3CF.sub.3        X201        MsCF.sub.3        X201        ClCF.sub.3        X201        CF.sub.3CF.sub.3        X202        MsCF.sub.3        X202        ClCF.sub.3        X202        CF.sub.3CF.sub.3        X205        MsCF.sub.3        X205        ClCF.sub.3        X205        CF.sub.3CF.sub.3        X207        MsCF.sub.3        X207        ClCF.sub.3        X207        CF.sub.3CF.sub.3        X208        MsCF.sub.3        X208        ClCF.sub.3        X208        CF.sub.3CF.sub.3        X209        MsCF.sub.3        X209        ClCF.sub.3        X209        CF.sub.3CF.sub.3        X210        MsCF.sub.3        X210        ClCF.sub.3        X210        CF.sub.3F               X201        MsF               X201        ClF               X201        CF.sub.3F               X202        MsF               X202        ClF               X202        CF.sub.3F               X205        MsF               X205        ClF               X205        CF.sub.3F               X207        MsF               X207        ClF               X207        CF.sub.3F               X208        MsF               X208        ClF               X208        CF.sub.3F               X209        MsF               X209        ClF               X209        CF.sub.3F               X210        MsF               X210        ClF               X210        CF.sub.3Br              X201        MsBr              X201        ClBr              X201        CF.sub.3Br              X202        MsBr              X202        ClBr              X202        CF.sub.3Br              X205        MsBr              X205        ClBr              X205        CF.sub.3Br              X207        MsBr              X207        ClBr              X207        CF.sub.3Br              X208        MsBr              X208        ClBr              X208        CF.sub.3Br              X209        MsBr              X209        ClBr              X209        CF.sub.3Br              X210        MsBr              X210        ClBr              X210        CF.sub.3I               X201        MsI               X201        ClI               X201        CF.sub.3I               X202        MsI               X202        ClI               X202        CF.sub.3I               X205        MsI               X205        ClI               X205        CF.sub.3I               X207        MsI               X207        ClI               X207        CF.sub.3I               X208        MsI               X208        ClI               X208        CF.sub.3I               X209        MsI               X209        ClI               X209        CF.sub.3I               X210        MsI               X210        ClI               X210        CF.sub.3MeO             X201        MsMeO             X201        ClMeO             X201        CF.sub.3MeO             X202        MsMeO             X202        ClMeO             X202        CF.sub.3MeO             X205        MsMeO             X205        ClMeO             X205        CF.sub.3MeO             X207        MsMeO             X207        ClMeO             X207        CF.sub.3MeO             X208        MsMeO             X208        ClMeO             X208        CF.sub.3MeO             X209        MsMeO             X209        ClMeO             X209        CF.sub.3MeO             X210        MsMeO             X210        ClMeO             X210        CF.sub.3EtO             X201        MsEtO             X201        ClEtO             X201        CF.sub.3EtO             X202        MsEtO             X202        ClEtO             X202        CF.sub.3EtO             X205        MsEtO             X205        ClEtO             X205        CF.sub.3EtO             X207        MsEtO             X207        ClEtO             X207        CF.sub.3EtO             X208        MsEtO             X208        ClEtO             X208        CF.sub.3EtO             X209        MsEtO             X209        ClEtO             X209        CF.sub.3EtO             X210        MsEtO             X210        ClEtO             X210        CF.sub.3i-PrO           X201        Msi-PrO           X201        Cli-PrO           X201        CF.sub.3i-PrO           X202        Msi-PrO           X202        Cli-PrO           X202        CF.sub.3i-PrO           X205        Msi-PrO           X205        Cli-PrO           X205        CF.sub.3i-PrO           X207        Msi-PrO           X207        Cli-PrO           X207        CF.sub.3i-PrO           X208        Msi-PrO           X208        Cli-PrO           X208        CF.sub.3i-PrO           X209        Msi-PrO           X209        Cli-PrO           X209        CF.sub.3i-PrO           X210        Msi-PrO           X210        Cli-PrO           X210        CF.sub.3n-PrO           X201        Msn-PrO           X201        Cln-PrO           X201        CF.sub.3n-PrO           X202        Msn-PrO           X202        Cln-PrO           X202        CF.sub.3n-PrO           X205        Msn-PrO           X205        Cln-PrO           X205        CF.sub.3n-PrO           X207        Msn-PrO           X207        Cln-PrO           X207        CF.sub.3n-PrO           X208        Msn-PrO           X208        Cln-PrO           X208        CF.sub.3n-PrO           X209        Msn-PrO           X209        Cln-PrO           X209        CF.sub.3n-PrO           X210        Msn-PrO           X210        Cln-PrO           X210        CF.sub.3CHF.sub.2       X201        MsCHF.sub.2       X201        ClCHF.sub.2       X201        CF.sub.3CHF.sub.2       X202        MsCHF.sub.2       X202        ClCHF.sub.2       X202        CF.sub.3CHF.sub.2       X205        MsCHF.sub.2       X205        ClCHF.sub.2       X205        CF.sub.3CHF.sub.2       X207        MsCHF.sub.2       X207        ClCHF.sub.2       X207        CF.sub.3CHF.sub.2       X208        MsCHF.sub.2       X208        ClCHF.sub.2       X208        CF.sub.3CHF.sub.2       X209        MsCHF.sub.2       X209        ClCHF.sub.2       X209        CF.sub.3CHF.sub.2       X210        MsCHF.sub.2       X210        ClCHF.sub.2       X210        CF.sub.3CH.sub.2 CF.sub.3           X201        MsCH.sub.2 CF.sub.3           X201        ClCH.sub.2 CF.sub.3           X201        CF.sub.3CH.sub.2 CF.sub.3           X202        MsCH.sub.2 CF.sub.3           X202        ClCH.sub.2 CF.sub.3           X202        CF.sub.3CH.sub.2 CF.sub.3           X205        MsCH.sub.2 CF.sub.3           X205        ClCH.sub.2 CF.sub.3           X205        CF.sub.3CH.sub.2 CF.sub.3           X207        MsCH.sub.2 CF.sub.3           X207        ClCH.sub.2 CF.sub.3           X207        CF.sub.3CH.sub.2 CF.sub.3           X208        MsCH.sub.2 CF.sub.3           X208        ClCH.sub.2 CF.sub.3           X208        CF.sub.3CH.sub.2 CF.sub.3           X209        MsCH.sub.2 CF.sub.3           X209        ClCH.sub.2 CF.sub.3           X209        CF.sub.3CH.sub.2 CF.sub.3           X210        MsCH.sub.2 CF.sub.3           X210        ClCH.sub.2 CF.sub.3           X210        CF.sub.3X201            X201        MsX201            X201        ClX201            X201        CF.sub.3X201            X202        MsX201            X202        ClX201            X202        CF.sub. 3X201            X205        MsX201            X205        ClX201            X205        CF.sub.3X201            X207        MsX201            X207        ClX201            X207        CF.sub.3X201            X208        MsX201            X208        ClX201            X208        CF.sub.3X201            X209        MsX201            X209        ClX201            X209        CF.sub.3X201            X210        MsX201            X210        ClX201            X210        CF.sub.3X201            X203        MsX201            X203        ClX201            X203        CF.sub.3X201            X204        MsX201            X204        ClX201            X204        CF.sub.3X201            X206        MsX201            X206        ClX201            X206        CF.sub.3X201            X212        MsX201            X212        ClX201            X212        CF.sub.3X201            X213        MsX201            X213        ClX201            X213        CF.sub.3X201            X214        MsX201            X214        ClX201            X214        CF.sub.3X201            X216        MsX201            X216        ClX201            X216        CF.sub.3X201            X217        MsX201            X217        ClX201            X217        CF.sub.3X201            X218        MsX201            X218        ClX201            X218        CF.sub.3X201            X220        MsX201            X220        ClX201            X220        CF.sub.3X201            X222        MsX201            X222        ClX201            X222        CF.sub.3X201            X226        MsX201            X226        ClX201            X226        CF.sub.3X201            X227        MsX201            X227        ClX201            X227        CF.sub.3X201            X228        MsX201            X228        ClX201            X228        CF.sub.3X201            X229        MsX201            X229        ClX201            X229        CF.sub. 3X201            X230        MsX201            X230        ClX201            X230        CF.sub.3X201            X231        MsX201            X231        ClX201            X231        CF.sub.3X201            X232        MsX201            X232        ClX201            X232        CF.sub.3X201            X233        MsX201            X233        ClX201            X233        CF.sub.3X201            X234        MsX201            X234        ClX201            X234        CF.sub.3X201            X235        MsX201            X235        ClX201            X235        CF.sub.3X202            X201        MsX202            X201        ClX202            X201        CF.sub.3X202            X202        MsX202            X202        ClX202            X202        CF.sub.3X202            X205        MsX202            X205        ClX202            X205        CF.sub.3X202            X207        MsX202            X207        ClX202            X207        CF.sub.3X202            X208        MsX202            X208        ClX202            X208        CF.sub.3X202            X209        MsX202            X209        ClX202            X209        CF.sub.3X202            X210        MsX202            X210        ClX202            X210        CF.sub.3X202            X203        MsX202            X203        ClX202            X203        CF.sub.3X202            X204        MsX202            X204        ClX202            X204        CF.sub.3X202            X206        MsX202            X206        ClX202            X206        CF.sub.3X202            X212        MsX202            X212        ClX202            X212        CF.sub.3X202            X213        MsX202            X213        ClX202            X213        CF.sub.3X202            X214        MsX202            X214        ClX202            X214        CF.sub.3X202            X216        MsX202            X216        ClX202            X216        CF.sub. 3X202            X217        MsX202            X217        ClX202            X217        CF.sub.3X202            X218        MsX202            X218        ClX202            X218        CF.sub.3X202            X220        MsX202            X220        ClX202            X220        CF.sub.3X202            X222        MsX202            X222        ClX202            X222        CF.sub.3X202            X226        MsX202            X226        ClX202            X226        CF.sub.3X202            X227        MsX202            X227        ClX202            X227        CF.sub.3X202            X228        MsX202            X228        ClX202            X228        CF.sub.3X202            X229        MsX202            X229        ClX202            X229        CF.sub.3X202            X230        MsX202            X230        ClX202            X230        CF.sub.3X202            X231        MsX202            X231        ClX202            X231        CF.sub.3X202            X232        MsX202            X232        ClX202            X232        CF.sub.3X202            X233        MsX202            X233        ClX202            X233        CF.sub.3X202            X234        MsX202            X234        ClX202            X234        CF.sub.3X202            X235        MsX202            X235        ClX202            X235        CF.sub.3X205            X201        MsX205            X201        ClX205            X201        CF.sub.3X205            X202        MsX205            X202        ClX205            X202        CF.sub.3X205            X205        MsX205            X205        ClX205            X205        CF.sub.3X205            X207        MsX205            X207        ClX205            X207        CF.sub.3X205            X208        MsX205            X208        ClX205            X208        CF.sub.3X205            X209        MsX205            X209        ClX205            X209        CF.sub. 3X205            X210        MsX205            X210        ClX205            X210        CF.sub.3X205            X203        MsX205            X203        ClX205            X203        CF.sub.3X205            X204        MsX205            X204        ClX205            X204        CF.sub.3X205            X206        MsX205            X206        ClX205            X206        CF.sub.3X205            X212        MsX205            X212        ClX205            X212        CF.sub.3X205            X213        MsX205            X213        ClX205            X213        CF.sub.3X205            X214        MsX205            X214        ClX205            X214        CF.sub.3X205            X216        MsX205            X216        ClX205            X216        CF.sub.3X205            X217        MsX205            X217        ClX205            X217        CF.sub.3X205            X218        MsX205            X218        ClX205            X218        CF.sub.3X205            X220        MsX205            X220        ClX205            X220        CF.sub.3X205            X222        MsX205            X222        ClX205            X222        CF.sub.3X205            X226        MsX205            X226        ClX205            X226        CF.sub.3X205            X227        MsX205            X227        ClX205            X227        CF.sub.3X205            X228        MsX205            X228        ClX205            X228        CF.sub.3X205            X229        MsX205            X229        ClX205            X229        CF.sub.3X205            X230        MsX205            X230        ClX205            X230        CF.sub.3X205            X231        MsX205            X231        ClX205            X231        CF.sub.3X205            X232        MsX205            X232        ClX205            X232        CF.sub.3X205            X233        MsX205            X233        ClX205            X233        CF.sub. 3X205            X234        MsX205            X234        ClX205            X234        CF.sub.3X207            X201        MsX207            X201        ClX207            X201        CF.sub.3X207            X202        MsX207            X202        ClX207            X202        CF.sub.3X207            X205        MsX207            X205        ClX207            X205        CF.sub.3X207            X207        MsX207            X207        ClX207            X207        CF.sub.3X207            X208        MsX207            X208        ClX207            X208        CF.sub.3X207            X209        MsX207            X209        ClX207            X209        CF.sub.3X207            X210        MsX207            X210        ClX207            X210        CF.sub.3X207            X203        MsX207            X203        ClX207            X203        CF.sub.3X207            X204        MsX207            X204        ClX207            X204        CF.sub.3X207            X206        MsX207            X206        ClX207            X206        CF.sub.3X207            X212        MsX207            X212        ClX207            X212        CF.sub.3X207            X213        MsX207            X213        ClX207            X213        CF.sub.3X207            X214        MsX207            X214        ClX207            X214        CF.sub.3X207            X216        MsX207            X216        ClX207            X216        CF.sub.3X207            X217        MsX207            X217        ClX207            X217        CF.sub.3X207            X218        MsX207            X218        ClX207            X218        CF.sub.3X207            X220        MsX207            X220        ClX207            X220        CF.sub.3X207            X222        MsX207            X222        ClX207            X222        CF.sub.3X207            X226        MsX207            X226        ClX207            X226        CF.sub. 3X207            X227        MsX207            X227        ClX207            X227        CF.sub.3X208            X201        MsX208            X201        ClX208            X201        CF.sub.3X208            X202        MsX208            X202        ClX208            X202        CF.sub.3X208            X205        MsX208            X205        ClX208            X205        CF.sub.3X208            X207        MsX208            X207        ClX208            X207        CF.sub.3X208            X208        MsX208            X208        ClX208            X208        CF.sub.3X208            X209        MsX208            X209        ClX208            X209        CF.sub.3X208            X210        MsX208            X210        ClX208            X210        CF.sub.3X208            X203        MsX208            X203        ClX208            X203        CF.sub.3X208            X204        MsX208            X204        ClX208            X204        CF.sub.3X208            X206        MsX208            X206        ClX208            X206        CF.sub.3X208            X212        MsX208            X212        ClX208            X212        CF.sub.3X208            X213        MsX208            X213        ClX208            X213        CF.sub.3X208            X214        MsX208            X214        ClX208            X214        CF.sub.3X208            X216        MsX208            X216        ClX208            X216        CF.sub.3X208            X217        MsX208            X217        ClX208            X217        CF.sub.3X208            X218        MsX208            X218        ClX208            X218        CF.sub.3X208            X220        MsX208            X220        ClX208            X220        CF.sub.3X208            X222        MsX208            X222        ClX208            X222        CF.sub.3X208            X226        MsX208            X226        ClX208            X226        CF.sub. 3X208            X227        MsX208            X227        ClX208            X227        CF.sub.3X209            X201        MsX209            X201        ClX209            X201        CF.sub.3X209            X202        MsX209            X202        ClX209            X202        CF.sub.3X209            X205        MsX209            X205        ClX209            X205        CF.sub.3X209            X207        MsX209            X207        ClX209            X207        CF.sub.3X209            X208        MsX209            X208        ClX209            X208        CF.sub.3X209            X209        MsX209            X209        ClX209            X209        CF.sub.3X209            X210        MsX209            X210        ClX209            X210        CF.sub.3X209            X203        MsX209            X203        ClX209            X203        CF.sub.3X209            X204        MsX209            X204        ClX209            X204        CF.sub.3X209            X206        MsX209            X206        ClX209            X206        CF.sub.3X209            X212        MsX209            X212        ClX209            X212        CF.sub.3X209            X213        MsX209            X213        ClX209            X213        CF.sub.3X209            X214        MsX209            X214        ClX209            X214        CF.sub.3X209            X216        MsX209            X216        ClX209            X216        CF.sub.3X209            X217        MsX209            X217        ClX209            X217        CF.sub.3X209            X218        MsX209            X218        ClX209            X218        CF.sub.3X209            X220        MsX209            X220        ClX209            X220        CF.sub.3X209            X222        MsX209            X222        ClX209            X222        CF.sub.3X209            X226        MsX209            X226        ClX209            X226        CF.sub. 3X209            X227        MsX209            X227        ClX209            X227        CF.sub.3X210            X201        MsX210            X201        ClX210            X201        CF.sub.3X210            X202        MsX210            X202        ClX210            X202        CF.sub.3X210            X205        MsX210            X205        ClX210            X205        CF.sub.3X210            X207        MsX210            X207        ClX210            X207        CF.sub.3X210            X208        MsX210            X208        ClX210            X208        CF.sub.3X210            X209        MsX210            X209        ClX210            X209        CF.sub.3X210            X210        MsX210            X210        ClX210            X210        CF.sub.3X210            X203        MsX210            X203        ClX210            X203        CF.sub.3X210            X204        MsX210            X204        ClX210            X204        CF.sub.3X210            X206        MsX210            X206        ClX210            X206        CF.sub.3X210            X212        MsX210            X212        ClX210            X212        CF.sub.3X210            X213        MsX210            X213        ClX210            X213        CF.sub.3X210            X214        MsX210            X214        ClX210            X214        CF.sub.3X210            X216        MsX210            X216        ClX210            X216        CF.sub.3X210            X217        MsX210            X217        ClX210            X217        CF.sub.3X210            X218        MsX210            X218        ClX210            X218        CF.sub.3X210            X220        MsX210            X220        ClX210            X220        CF.sub.3X210            X222        MsX210            X222        ClX210            X222        CF.sub.3X210            X226        MsX210            X226        ClX210            X226        CF.sub. 3X210            X227        MsX210            X227        ClX210            X227        CF.sub.3Cl              X201        NO.sub.2Cl              X201        MeOCl              X201        CNCl              X201        SMeCl              X201        SOMeCl              X201        SO.sub.2 CF.sub.3Cl              X201        BrCl              X201        ICl              X201        EtOCl              X202        NO.sub.2Cl              X202        MeOCl              X202        CNCl              X202        SMeCl              X202        SOMeCl              X202        SO.sub.2 CF.sub.3Cl              X202        BrCl              X202        ICl              X202        EtOCl              X205        NO.sub.2Cl              X205        MeOCl              X205        CNCl              X205        SMeCl              X205        SOMeCl              X205        SO.sub.2 CF.sub.3Cl              X205        BrCl              X205        ICl              X205        EtOCl              X207        NO.sub.2Cl              X207        MeOCl              X207        CNCl              X207        SMeCl              X207        SOMeCl              X207        SO.sub.2 CF.sub.3Cl              X207        BrCl              X207        ICl              X207        EtOCl              X208        NO.sub.2Cl              X208        MeOCl              X208        CNCl              X208        SMeCl              X208        SOMeCl              X208        SO.sub.2 CF.sub.3Cl              X208        BrCl              X208        ICl              X208        EtOCl              X209        NO.sub.2Cl              X209        MeOCl              X209        CNCl              X209        SMeCl              X209        SOMeCl              X209        SO.sub.2 CF.sub.3Cl              X209        BrCl              X209        ICl              X209        EtOCl              X210        NO2Cl              X210        MeOCl              X210        CNCl              X210        SMeCl              X210        SOMeCl              X210        SO.sub.2 CF.sub.3Cl              X210        BrCl              X210        ICl              X210        EtOMe              X201        NO.sub.2Me              X201        MeOMe              X201        CNMe              X201        SMeMe              X201        SOMeMe              X201        SO.sub.2 CF.sub.3Me              X201        BrMe              X201        IMe              X201        EtOMe              X202        NO.sub.2Me              X202        MeOMe              X202        CNMe              X202        SMeMe              X202        SOMeMe              X202        SO.sub.2 CF.sub.3Me              X202        BrMe              X202        IMe              X202        EtOMe              X205        NO.sub.2Me              X205        MeOMe              X205        CNMe              X205        SMeMe              X205        SOMeMe              X205        SO.sub.2 CF.sub.3Me              X205        BrMe              X205        IMe              X205        EtOMe              X207        NO.sub.2Me              X207        MeOMe              X207        CNMe              X207        SMeMe              X207        SOMeMe              X207        SO.sub.2 CF.sub.3Me              X207        BrMe              X207        IMe              X207        EtOMe              X208        NO.sub.2Me              X208        MeOMe              X208        CNMe              X208        SMeMe              X208        SOMeMe              X208        SO.sub.2 CF.sub.3Me              X208        BrMe              X208        IMe              X208        EtOMe              X209        NO.sub.2Me              X209        MeOMe              X209        CNMe              X209        SMeMe              X209        SOMeMe              X209        SO.sub.2 CF.sub.3Me              X209        BrMe              X209        IMe              X209        EtOMe              X210        NO.sub.2Me              X210        MeOMe              X210        CNMe              X210        SMeMe              X210        SOMeMe              X210        SO.sub.2 CF.sub.3Me              X210        BrMe              X210        IMe              X210        EtO______________________________________ 
    
     
                       TABLE 4______________________________________ ##STR10##X.sub.1         X.sub.2     X.sub.3______________________________________Cl              X201        MsCl              X201        ClCl              X202        MsCl              X202        ClCl              X205        MsCl              X205        ClCl              X207        MsCl              X207        ClCl              X208        MsCl              X208        ClCl              X209        MsCl              X209        ClCl              X210        MsCl              X210        ClCl              X201        CF.sub.3Cl              X202        CF.sub.3Cl              X205        CF.sub.3Cl              X207        CF.sub.3Cl              X208        CF.sub.3Cl              X209        CF.sub.3Cl              X210        CF.sub.3Me              X201        MsMe              X201        ClMe              X201        CF.sub.3Me              X202        MsMe              X202        ClMe              X202        CF.sub.3Me              X205        MsMe              X205        ClMe              X205        CF.sub.3Me              X207        MsMe              X207        ClMe              X207        CF.sub.3Me              X208        MsMe              X208        ClMe              X208        CF.sub.3Me              X209        MsMe              X209        ClMe              X209        CF.sub.3Me              X210        MsMe              X210        ClMe              X210        CF.sub.3Cl              X203        MsCl              X203        ClCl              X203        CF.sub.3Cl              X204        MsCl              X204        ClCl              X204        CF.sub.3Cl              X206        MsCl              X206        ClCl              X206        CF.sub.3Cl              X212        MsCl              X212        ClCl              X212        CF.sub.3Cl              X213        MsCl              X213        ClCl              X213        CF.sub.3Cl              X214        MsCl              X214        ClCl              X214        CF.sub.3Cl              X216        MsCl              X216        ClCl              X216        CF.sub.3Cl              X217        MsCl              X217        ClCl              X217        CF.sub.3Cl              X218        MsCl              X218        ClCl              X218        CF.sub.3Cl              X220        MsCl              X220        ClCl              X220        CF.sub.3Cl              X222        MsCl              X222        ClCl              X222        CF.sub.3Cl              X226        MsCl              X226        ClCl              X226        CF.sub.3Cl              X227        MsCl              X227        ClCl              X227        CF.sub.3Me              X203        MsMe              X203        ClMe              X203        CF.sub.3Me              X204        MsMe              X204        ClMe              X204        CF.sub.3Me              X206        MsMe              X206        ClMe              X206        CF.sub.3Me              X212        MsMe              X212        ClMe              X212        CF.sub.3Me              X213        MsMe              X213        ClMe              X213        CF.sub.3Me              X214        MsMe              X214        ClMe              X214        CF.sub.3Me              X216        MsMe              X216        ClMe              X216        CF.sub.3Me              X217        MsMe              X217        ClMe              X217        CF.sub.3Me              X218        MsMe              X218        ClMe              X218        CF.sub.3Me              X220        MsMe              X220        ClMe              X220        CF.sub.3Me              X222        MsMe              X222        ClMe              X222        CF.sub.3Me              X226        MsMe              X226        ClMe              X226        CF.sub.3Me              X227        MsMe              X227        ClMe              X227        CF.sub.3Cl              X211        MsCl              X211        ClCl              X211        CF.sub.3Cl              X215        MsCl              X215        ClCl              X215        CF.sub.3Cl              X219        MsCl              X219        ClCl              X219        CF.sub.3Cl              X221        MsCl              X221        ClCl              X221        CF.sub.3Cl              X223        MsCl              X223        ClCl              X223        CF.sub.3Cl              X224        MsCl              X224        ClCl              X224        CF.sub.3Cl              X225        MsCl              X225        ClCl              X225        CF.sub.3Me              X211        MsMe              X211        ClMe              X211        CF.sub.3Me              X215        MsMe              X215        ClMe              X215        CF.sub.3Me              X219        MsMe              X219        ClMe              X219        CF.sub.3Me              X221        MsMe              X221        ClMe              X221        CF.sub.3Me              X223        MsMe              X223        ClMe              X223        CF.sub.3Me              X224        MsMe              X224        ClMe              X224        CF.sub.3Me              X225        MsMe              X225        ClMe              X225        CF.sub.3NO.sub.2        X201        MsNO.sub.2        X201        ClNO.sub.2        X201        CF.sub.3NO.sub.2        X202        MsNO.sub.2        X202        ClNO.sub.2        X202        CF.sub.3NO.sub.2        X205        MsNO.sub.2        X205        ClNO.sub.2        X205        CF.sub.3NO.sub.2        X207        MsNO.sub.2        X207        ClNO.sub.2        X207        CF.sub.3NO.sub.2        X208        MsNO.sub.2        X208        ClNO.sub.2        X208        CF.sub.3NO.sub.2        X209        MsNO.sub.2        X209        ClNO.sub.2        X209        CF.sub.3NO.sub.2        X210        MsNO.sub.2        X210        ClNO.sub.2        X210        CF.sub.3Et              X201        MsEt              X201        ClEt              X201        CF.sub.3Et              X202        MsEt              X202        ClEt              X202        CF.sub.3Et              X205        MsEt              X205        ClEt              X205        CF.sub.3Et              X207        MsEt              X207        ClEt              X207        CF.sub.3Et              X208        MsEt              X208        ClEt              X208        CF.sub.3Et              X209        MsEt              X209        ClEt              X209        CF.sub.3Et              X210        MsEt              X210        ClEt              X210        CF.sub.3i-Pr            X201        Msi-Pr            X201        Cli-Pr            X201        CF.sub.3i-Pr            X202        Msi-Pr            X202        Cli-Pr            X202        CF.sub.3i-Pr            X205        Msi-Pr            X205        Cli-Pr            X205        CF.sub.3i-Pr            X207        Msi-Pr            X207        Cli-Pr            X207        CF.sub.3i-Pr            X208        Msi-Pr            X208        Cli-Pr            X208        CF.sub.3i-Pr            X209        Msi-Pr            X209        Cli-Pr            X209        CF.sub.3i-Pr            X210        Msi-Pr            X210        Cli-Pr            X210        CF.sub.3n-Pr            X201        Msn-Pr            X201        Cln-Pr            X201        CF.sub.3n-Pr            X202        Msn-Pr            X202        Cln-Pr            X202        CF.sub.3n-Pr            X205        Msn-Pr            X205        Cln-Pr            X205        CF.sub.3n-Pr            X207        Msn-Pr            X207        Cln-Pr            X207        CF.sub.3n-Pr            X208        Msn-Pr            X208        Cln-Pr            X208        CF.sub.3n-Pr            X209        Msn-Pr            X209        Cln-Pr            X209        CF.sub.3n-Pr            X210        Msn-Pr            X210        Cln-Pr            X210        CF.sub.3CN              X201        MsCN              X201        ClCN              X201        CF.sub.3CN              X202        MsCN              X202        ClCN              X202        CF.sub.3CN              X205        MsCN              X205        ClCN              X205        CF.sub.3CN              X207        MsCN              X207        ClCN              X207        CF.sub.3CN              X208        MsCN              X208        ClCN              X208        CF.sub.3CN              X209        MsCN              X209        ClCN              X209        CF.sub.3CN              X210        MsCN              X210        ClCN              X210        CF.sub.3CF.sub.3        X201        MsCF.sub.3        X201        ClCF.sub.3        X201        CF.sub.3CF.sub.3        X202        MsCF.sub.3        X202        ClCF.sub.3        X202        CF.sub.3CF.sub.3        X205        MsCF.sub.3        X205        ClCF.sub.3        X205        CF.sub.3CF.sub.3        X207        MsCF.sub.3        X207        ClCF.sub.3        X207        CF.sub.3CF.sub.3        X208        MsCF.sub.3        X208        ClCF.sub.3        X208        CF.sub.3CF.sub.3        X209        MsCF.sub.3        X209        ClCF.sub.3        X209        CF.sub.3CF.sub.3        X210        MsCF.sub.3        X210        ClCF.sub.3        X210        CF.sub.3F               X201        MsF               X201        ClF               X201        CF.sub.3F               X202        MsF               X202        ClF               X202        CF.sub.3F               X205        MsF               X205        ClF               X205        CF.sub.3F               X207        MsF               X207        ClF               X207        CF.sub.3F               X208        MsF               X208        ClF               X208        CF.sub.3F               X209        MsF               X209        ClF               X209        CF.sub.3F               X210        MsF               X210        ClF               X210        CF.sub.3Br              X201        MsBr              X201        ClBr              X201        CF.sub.3Br              X202        MsBr              X202        ClBr              X202        CF.sub.3Br              X205        MsBr              X205        ClBr              X205        CF.sub.3Br              X207        MsBr              X207        ClBr              X207        CF.sub.3Br              X208        MsBr              X208        ClBr              X208        CF.sub.3Br              X209        MsBr              X209        ClBr              X209        CF.sub. 3Br              X210        MsBr              X210        ClBr              X210        CF.sub.3I               X201        MsI               X201        ClI               X201        CF.sub.3I               X202        MsI               X202        ClI               X202        CF.sub.3I               X205        MsI               X205        ClI               X205        CF.sub.3I               X207        MsI               X207        ClI               X207        CF.sub.3I               X208        MsI               X208        ClI               X208        CF.sub.3I               X209        MsI               X209        ClI               X209        CF.sub.3I               X210        MsI               X210        ClI               X210        CF.sub.3MeO             X201        MsMeO             X201        ClMeO             X201        CF.sub.3MeO             X202        MsMeO             X202        ClMeO             X202        CF.sub.3MeO             X205        MsMeO             X205        ClMeO             X205        CF.sub.3MeO             X207        MsMeO             X207        ClMeO             X207        CF.sub.3MeO             X208        MsMeO             X208        ClMeO             X208        CF.sub.3MeO             X209        MsMeO             X209        ClMeO             X209        CF.sub.3MeO             X210        MsMeO             X210        ClMeO             X210        CF.sub.3EtO             X201        MsEtO             X201        ClEtO             X201        CF.sub.3EtO             X202        MsEtO             X202        ClEtO             X202        CF.sub.3EtO             X205        MsEtO             X205        ClEtO             X205        CF.sub.3EtO             X207        MsEtO             X207        ClEtO             X207        CF.sub.3EtO             X208        MsEtO             X208        ClEtO             X208        CF.sub. 3EtO             X209        MsEtO             X209        ClEtO             X209        CF.sub.3EtO             X210        MsEtO             X210        ClEtO             X210        CF.sub.3i-PrO           X201        Msi-PrO           X201        Cli-PrO           X201        CF.sub.3i-PrO           X202        Msi-PrO           X202        Cli-PrO           X202        CF.sub.3i-PrO           X205        Msi-PrO           X205        Cli-PrO           X205        CF.sub.3i-PrO           X207        Msi-PrO           X207        Cli-PrO           X207        CF.sub.3i-PrO           X208        Msi-PrO           X208        Cli-PrO           X208        CF.sub.3i-PrO           X209        Msi-PrO           X209        Cli-PrO           X209        CF.sub.3i-PrO           X210        Msi-PrO           X210        Cli-PrO           X210        CF.sub.3n-PrO           X201        Msn-PrO           X201        Cln-PrO           X201        CF.sub.3n-PrO           X202        Msn-PrO           X202        Cln-PrO           X202        CF.sub.3n-PrO           X205        Msn-PrO           X205        Cln-PrO           X205        CF.sub.3n-PrO           X207        Msn-PrO           X207        Cln-PrO           X207        CF.sub.3n-PrO           X208        Msn-PrO           X208        Cln-PrO           X208        CF.sub.3n-PrO           X209        Msn-PrO           X209        Cln-PrO           X209        CF.sub.3n-PrO           X210        Msn-PrO           X210        Cln-PrO           X210        CF.sub.3CHF.sub.2       X201        MsCHF.sub.2       X201        ClCHF.sub.2       X201        CF.sub.3CHF.sub.2       X202        MsCHF.sub.2       X202        ClCHF.sub.2       X202        CF.sub.3CHF.sub.2       X205        MsCHF.sub.2       X205        ClCHF.sub.2       X205        CF.sub.3CHF.sub.2       X207        MsCHF.sub.2       X207        ClCHF.sub.2       X207        CF.sub.3CHF.sub.2       X208        MsCHF.sub.2       X208        ClCHF.sub.2       X208        CF.sub.3CHF.sub.2       X209        MsCHF.sub.2       X209        ClCHF.sub.2       X209        CF.sub.3CHF.sub.2       X210        MsCHF.sub.2       X210        ClCHF.sub.2       X210        CF.sub.3CH.sub.2 CF.sub.3           X201        MsCH.sub.2 CF.sub.3           X201        ClCH.sub.2 CF.sub.3           X201        CF.sub.3CH.sub.2 CF.sub.3           X202        MsCH.sub.2 CF.sub.3           X202        ClCH.sub.2 CF.sub.3           X202        CF.sub.3CH.sub.2 CF.sub.3           X205        MsCH.sub.2 CF.sub.3           X205        ClCH.sub.2 CF.sub.3           X205        CF.sub.3CH.sub.2 CF.sub.3           X207        MsCH.sub.2 CF.sub.3           X207        ClCH.sub.2 CF.sub.3           X207        CF.sub.3CH.sub.2 CF.sub.3           X208        MsCH.sub.2 CF.sub.3           X208        ClCH.sub.2 CF.sub.3           X208        CF.sub.3CH.sub.2 CF.sub.3           X209        MsCH.sub.2 CF.sub.3           X209        ClCH.sub.2 CF.sub.3           X209        CF.sub.3CH.sub.2 CF.sub.3           X210        MsCH.sub.2 CF.sub.3           X210        ClCH.sub.2 CF.sub.3           X210        CF.sub.3X201            X201        MsX201            X201        ClX201            X201        CF.sub.3X201            X202        MsX201            X202        ClX201            X202        CF.sub.3X201            X205        MsX201            X205        ClX201            X205        CF.sub.3X201            X207        MsX201            X207        ClX201            X207        CF.sub.3X201            X208        MsX201            X208        ClX201            X208        CF.sub.3X201            X209        MsX201            X209        ClX201            X209        CF.sub.3X201            X210        MsX201            X210        ClX201            X210        CF.sub.3X201            X203        MsX201            X203        ClX201            X203        CF.sub.3X201            X204        MsX201            X204        ClX201            X204        CF.sub.3X201            X206        MsX201            X206        ClX201            X206        CF.sub.3X201            X212        MsX201            X212        ClX201            X212        CF.sub.3X201            X213        MsX201            X213        ClX201            X213        CF.sub.3X201            X214        MsX201            X214        ClX201            X214        CF.sub.3X201            X216        MsX201            X216        ClX201            X216        CF.sub.3X201            X217        MsX201            X217        ClX201            X217        CF.sub.3X201            X218        MsX201            X218        ClX201            X218        CF.sub.3X201            X220        MsX201            X220        ClX201            X220        CF.sub.3X201            X222        MsX201            X222        ClX201            X222        CF.sub.3X201            X226        MsX201            X226        ClX201            X226        CF.sub.3X201            X227        MsX201            X227        ClX201            X227        CF.sub.3X201            X228        MsX201            X228        ClX201            X228        CF.sub.3X201            X229        MsX201            X229        ClX201            X229        CF.sub.3X201            X230        MsX201            X230        ClX201            X230        CF.sub.3X201            X231        MsX201            X231        ClX201            X231        CF.sub.3X201            X232        MsX201            X232        ClX201            X232        CF.sub.3X201            X233        MsX201            X233        ClX201            X233        CF.sub.3X201            X234        MsX201            X234        ClX201            X234        CF.sub.3X201            X235        MsX201            X235        ClX201            X235        CF.sub.3X202            X201        MsX202            X201        ClX202            X201        CF.sub.3X202            X202        MsX202            X202        ClX202            X202        CF.sub.3X202            X205        MsX202            X205        ClX202            X205        CF.sub.3X202            X207        MsX202            X207        ClX202            X207        CF.sub.3X202            X208        MsX202            X208        ClX202            X208        CF.sub.3X202            X209        MsX202            X209        ClX202            X209        CF.sub.3X202            X210        MsX202            X210        ClX202            X210        CF.sub.3X202            X203        MsX202            X203        ClX202            X203        CF.sub.3X202            X204        MsX202            X204        ClX202            X204        CF.sub.3X202            X206        MsX202            X206        ClX202            X206        CF.sub.3X202            X212        MsX202            X212        ClX202            X212        CF.sub.3X202            X213        MsX202            X213        ClX202            X213        CF.sub.3X202            X214        MsX202            X214        ClX202            X214        CF.sub.3X202            X216        MsX202            X216        ClX202            X216        CF.sub.3X202            X217        MsX202            X217        ClX202            X217        CF.sub.3X202            X218        MsX202            X218        ClX202            X218        CF.sub.3X202            X220        MsX202            X220        ClX202            X220        CF.sub.3X202            X222        MsX202            X222        ClX202            X222        CF.sub.3X202            X226        MsX202            X226        ClX202            X226        CF.sub.3X202            X227        MsX202            X227        ClX202            X227        CF.sub.3X202            X228        MsX202            X228        ClX202            X228        CF.sub.3X202            X229        MsX202            X229        ClX202            X229        CF.sub.3X202            X230        MsX202            X230        ClX202            X230        CF.sub.3X202            X231        MsX202            X231        ClX202            X231        CF.sub.3X202            X232        MsX202            X232        ClX202            X232        CF.sub.3X202            X233        MsX202            X233        ClX202            X233        CF.sub.3X202            X234        MsX202            X234        ClX202            X234        CF.sub.3X202            X235        MsX202            X235        ClX202            X235        CF.sub.3X205            X201        MsX205            X201        ClX205            X201        CF.sub.3X205            X202        MsX205            X202        ClX205            X202        CF.sub.3X205            X205        MsX205            X205        ClX205            X205        CF.sub.3X205            X207        MsX205            X207        ClX205            X207        CF.sub.3X205            X208        MsX205            X208        ClX205            X208        CF.sub.3X205            X209        MsX205            X209        ClX205            X209        CF.sub.3X205            X210        MsX205            X210        ClX205            X210        CF.sub.3X205            X203        MsX205            X203        ClX205            X203        CF.sub.3X205            X204        MsX205            X204        ClX205            X204        CF.sub.3X205            X206        MsX205            X206        ClX205            X206        CF.sub.3X205            X212        MsX205            X212        ClX205            X212        CF.sub.3X205            X213        MsX205            X213        ClX205            X213        CF.sub.3X205            X214        MsX205            X214        ClX205            X214        CF.sub.3X205            X216        MsX205            X216        ClX205            X216        CF.sub.3X205            X217        MsX205            X217        ClX205            X217        CF.sub.3X205            X218        MsX205            X218        ClX205            X218        CF.sub.3X205            X220        MsX205            X220        ClX205            X220        CF.sub.3X205            X222        MsX205            X222        ClX205            X222        CF.sub.3X205            X226        MsX205            X226        ClX205            X226        CF.sub.3X205            X227        MsX205            X227        ClX205            X227        CF.sub.3X205            X228        MsX205            X228        ClX205            X228        CF.sub.3X205            X229        MsX205            X229        ClX205            X229        CF.sub.3X205            X230        MsX205            X230        ClX205            X230        CF.sub.3X205            X231        MsX205            X231        ClX205            X231        CF.sub.3X205            X232        MsX205            X232        ClX205            X232        CF.sub.3X205            X233        MsX205            X233        ClX205            X233        CF.sub.3X205            X234        MsX205            X234        ClX205            X234        CF.sub.3X207            X201        MsX207            X201        ClX207            X201        CF.sub.3X207            X202        MsX207            X202        ClX207            X202        CF.sub.3X207            X205        MsX207            X205        ClX207            X205        CF.sub.3X207            X207        MsX207            X207        ClX207            X207        CF.sub.3X207            X208        MsX207            X208        ClX207            X208        CF.sub.3X207            X209        MsX207            X209        ClX207            X209        CF.sub.3X207            X210        MsX207            X210        ClX207            X210        CF.sub.3X207            X203        MsX207            X203        ClX207            X203        CF.sub.3X207            X204        MsX207            X204        ClX207            X204        CF.sub.3X207            X206        MsX207            X206        ClX207            X206        CF.sub.3X207            X212        MsX207            X212        ClX207            X212        CF.sub.3X207            X213        MsX207            X213        ClX207            X213        CF.sub.3X207            X214        MsX207            X214        ClX207            X214        CF.sub.3X207            X216        MsX207            X216        ClX207            X216        CF.sub.3X207            X217        MsX207            X217        ClX207            X217        CF.sub.3X207            X218        MsX207            X218        ClX207            X218        CF.sub.3X207            X220        MsX207            X220        ClX207            X220        CF.sub.3X207            X222        MsX207            X222        ClX207            X222        CF.sub.3X207            X226        MsX207            X226        ClX207            X226        CF.sub.3X207            X227        MsX207            X227        ClX207            X227        CF.sub.3X208            X201        MsX208            X201        ClX208            X201        CF.sub.3X208            X202        MsX208            X202        ClX208            X202        CF.sub.3X208            X205        MsX208            X205        ClX208            X205        CF.sub.3X208            X207        MsX208            X207        ClX208            X207        CF.sub.3X208            X208        MsX208            X208        ClX208            X208        CF.sub.3X208            X209        MsX208            X209        ClX208            X209        CF.sub.3X208            X210        MsX208            X210        ClX208            X210        CF.sub.3X208            X203        MsX208            X203        ClX208            X203        CF.sub.3X208            X204        MsX208            X204        ClX208            X204        CF.sub.3X208            X206        MsX208            X206        ClX208            X206        CF.sub.3X208            X212        MsX208            X212        ClX208            X212        CF.sub.3X208            X213        MsX208            X213        ClX208            X213        CF.sub.3X208            X214        MsX208            X214        ClX208            X214        CF.sub.3X208            X216        MsX208            X216        ClX208            X216        CF.sub.3X208            X217        MsX208            X217        ClX208            X217        CF.sub.3X208            X218        MsX208            X218        ClX208            X218        CF.sub.3X208            X220        MsX208            X220        ClX208            X220        CF.sub.3X208            X222        MsX208            X222        ClX208            X222        CF.sub.3X208            X226        MsX208            X226        ClX208            X226        CF.sub.3X208            X227        MsX208            X227        ClX208            X227        CF.sub.3X209            X201        MsX209            X201        ClX209            X201        CF.sub.3X209            X202        MsX209            X202        ClX209            X202        CF.sub.3X209            X205        MsX209            X205        ClX209            X205        CF.sub.3X209            X207        MsX209            X207        ClX209            X207        CF.sub.3X209            X208        MsX209            X208        ClX209            X208        CF.sub.3X209            X209        MsX209            X209        ClX209            X209        CF.sub.3X209            X210        MsX209            X210        ClX209            X210        CF.sub.3X209            X203        MsX209            X203        ClX209            X203        CF.sub.3X209            X204        MsX209            X204        ClX209            X204        CF.sub.3X209            X206        MsX209            X206        ClX209            X206        CF.sub.3X209            X212        MsX209            X212        ClX209            X212        CF.sub.3X209            X213        MsX209            X213        ClX209            X213        CF.sub.3X209            X214        MsX209            X214        ClX209            X214        CF.sub.3X209            X216        MsX209            X216        ClX209            X216        CF.sub.3X209            X217        MsX209            X217        ClX209            X217        CF.sub.3X209            X218        MsX209            X218        ClX209            X218        CF.sub.3X209            X220        MsX209            X220        ClX209            X220        CF.sub.3X209            X222        MsX209            X222        ClX209            X222        CF.sub.3X209            X226        MsX209            X226        ClX209            X226        CF.sub.3X209            X227        MsX209            X227        ClX209            X227        CF.sub.3X210            X201        MsX210            X201        ClX210            X201        CF.sub.3X210            X202        MsX210            X202        ClX210            X202        CF.sub.3X210            X205        MsX210            X205        ClX210            X205        CF.sub.3X210            X207        MsX210            X207        ClX210            X207        CF.sub.3X210            X208        MsX210            X208        ClX210            X208        CF.sub.3X210            X209        MsX210            X209        ClX210            X209        CF.sub.3X210            X210        MsX210            X210        ClX210            X210        CF.sub.3X210            X203        MsX210            X203        ClX210            X203        CF.sub.3X210            X204        MsX210            X204        ClX210            X204        CF.sub.3X210            X206        MsX210            X206        ClX210            X206        CF.sub.3X210            X212        MsX210            X212        ClX210            X212        CF.sub.3X210            X213        MsX210            X213        ClX210            X213        CF.sub.3X210            X214        MsX210            X214        ClX210            X214        CF.sub.3X210            X216        MsX210            X216        ClX210            X216        CF.sub.3X210            X217        MsX210            X217        ClX210            X217        CF.sub.3X210            X218        MsX210            X218        ClX210            X218        CF.sub.3X210            X220        MsX210            X220        ClX210            X220        CF.sub.3X210            X222        MsX210            X222        ClX210            X222        CF.sub.3X210            X226        MsX210            X226        ClX210            X226        CF.sub.3X210            X227        MsX210            X227        ClX210            X227        CF.sub.3Cl              X201        NO.sub.2Cl              X201        MeOCl              X201        CNCl              X201        SMeCl              X201        SOMeCl              X201        SO.sub.2 CF.sub.3Cl              X201        BrCl              X201        ICl              X201        EtOCl              X202        NO.sub.2Cl              X202        MeOCl              X202        CNCl              X202        SMeCl              X202        SOMeCl              X202        SO.sub.2 CF.sub.3Cl              X202        BrCl              X202        ICl              X202        EtOCl              X205        NO.sub.2Cl              X205        MeOCl              X205        CNCl              X205        SMeCl              X205        SOMeCl              X205        SO.sub.2 CF.sub.3Cl              X205        BrCl              X205        ICl              X205        EtOCl              X207        NO.sub.2Cl              X207        MeOCl              X207        CNCl              X207        SMeCl              X207        SOMeCl              X207        SO.sub.2 CF.sub.3Cl              X207        BrCl              X207        ICl              X207        EtOCl              X208        NO.sub.2Cl              X208        MeOCl              X208        CNCl              X208        SMeCl              X208        SOMeCl              X208        SO.sub.2 CF.sub.3Cl              X208        BrCl              X208        ICl              X208        EtOCl              X209        NO.sub.2Cl              X209        MeOCl              X209        CNCl              X209        SMeCl              X209        SOMeCl              X209        SO.sub.2 CF.sub.3Cl              X209        BrCl              X209        ICl              X209        EtOCl              X210        NO.sub.2Cl              X210        MeOCl              X210        CNCl              X210        SMeCl              X210        SOMeCl              X210        SO.sub.2 CF.sub.3Cl              X210        BrCl              X210        ICl              X210        EtOMe              X201        NO.sub.2Me              X201        MeOMe              X201        CNMe              X201        SMeMe              X201        SOMeMe              X201        SO.sub.2 CF.sub.3Me              X201        BrMe              X201        IMe              X201        EtOMe              X202        NO.sub.2Me              X202        MeOMe              X202        CNMe              X202        SMeMe              X202        SOMeMe              X202        SO.sub.2 CF.sub.3Me              X202        BrMe              X202        IMe              X202        EtOMe              X205        NO.sub.2Me              X205        MeOMe              X205        CNMe              X205        SMeMe              X205        SOMeMe              X205        SO.sub.2 CF.sub.3Me              X205        BrMe              X205        IMe              X205        EtOMe              X207        NO.sub.2Me              X207        MeOMe              X207        CNMe              X207        SMeMe              X207        SOMeMe              X207        SO.sub.2 CF.sub.3Me              X207        BrMe              X207        IMe              X207        EtOMe              X208        NO.sub.2Me              X208        MeOMe              X208        CNMe              X208        SMeMe              X208        SOMeMe              X208        SO.sub.2 CF.sub.3Me              X208        BrMe              X208        IMe              X208        EtOMe              X209        NO.sub.2Me              X209        MeOMe              X209        CNMe              X209        SMeMe              X209        SOMeMe              X209        SO.sub.2 CF.sub.3Me              X209        BrMe              X209        IMe              X209        EtOMe              X210        NO.sub.2Me              X210        MeOMe              X210        CNMe              X210        SMeMe              X210        SOMeMe              X210        SO.sub.2 CF.sub.3Me              X210        BrMe              X210        IMe              X210        EtO______________________________________ 
    
     
                       TABLE 5______________________________________ ##STR11##X.sub.1   X.sub.3    X.sub.4   R.sub.1______________________________________Cl        SO.sub.2 Me                H         HCl        SO.sub.2 Me                H         MeCl        SO.sub.2 Me                H         EtCl        SO.sub.2 Me                H         Pr-iCl        SO.sub.2 Me                H         Pr-nCl        SO.sub.2 Me                H         Bu-tCl        SO.sub.2 Me                H         CH.sub.2 CCHCl        SO.sub.2 Me                H         CH.sub.2 CCH.sub.2Cl        SO.sub.2 Me                H         CH.sub.2 CH.sub.2 OMeCl        SO.sub.2 Me                H         CH.sub.2 CH.sub.2 ClCl        SO.sub.2 Me                H         CH.sub.2 CF.sub.3Cl        SO.sub.2 Me                H         CH.sub.2 CH.sub.2 CNCl        SO.sub.2 Me                F         MeCl        SO.sub.2 Me                F         EtCl        SO.sub.2 Me                F         Pr-iCl        SO.sub.2 Me                Cl        MeCl        SO.sub.2 Me                Cl        EtCl        SO.sub.2 Me                Cl        Pr-iCl        SO.sub.2 Me                Me        MeCl        SO.sub.2 Me                Me        EtCl        SO.sub.2 Me                OMe       MeCl        SO.sub.2 Me                OMe       EtCl        SO.sub.2 Me                OMe       Pr-iCl        SOMe       H         MeCl        SOMe       H         EtCl        SOMe       H         Pr-iCl        SMe        H         MeCl        SMe        H         EtCl        SMe        H         Pr-iCl        SO.sub.2 CF.sub.3                H         MeCl        SO.sub.2 CF.sub.3                H         EtCl        SO.sub.2 CF.sub.3                H         Pr-iCl        SO.sub.2 CF.sub.3                H         Pr-nCl        SOCF.sub.3 H         MeCl        SOCF.sub.3 H         EtCl        SOCF.sub.3 H         Pr-iCl        SCF.sub.3  H         MeCl        SCF.sub.3  H         EtCl        SCF.sub.3  H         Pr-iCl        Cl         H         MeCl        Cl         H         EtCl        Cl         H         Pr-iCl        Cl         H         Pr-nCl        Br         H         MeCl        Br         H         EtCl        Br         H         Pr-iCl        NO.sub.2   H         MeCl        NO.sub.2   H         EtCl        NO.sub.2   H         Pr-iCl        CF.sub.3   H         MeCl        CF.sub.3   H         EtCl        CF.sub.3   H         Pr-iCl        CN         H         MeCl        CN         H         EtCl        OMe        H         MeCl        OMe        H         EtOMe       SO.sub.2 Me                H         HOMe       SO.sub.2 Me                H         MeOMe       SO.sub.2 Me                H         EtOMe       SO.sub.2 Me                H         Pr-iOMe       SO.sub.2 Me                H         Pr-nOMe       SO.sub.2 Me                H         Bu-tOMe       SO.sub.2 Me                H         CH.sub.2 CCHOMe       SO.sub.2 Me                H         CH.sub.2 CCH.sub.2OMe       SO.sub.2 Me                H         CH.sub.2 CH.sub.2 OMeOMe       SO.sub.2 Me                H         CH.sub.2 CH.sub.2 ClOMe       SO.sub.2 Me                H         CH.sub.2 CF.sub.3OMe       SO.sub.2 Me                H         CH.sub.2 CH.sub.2 CNOMe       SO.sub.2 Me                F         MeOMe       SO.sub.2 Me                F         EtOMe       SO.sub.2 Me                F         Pr-iOMe       SO.sub.2 Me                F         Pr-nOMe       SO.sub.2 Me                Cl        MeOMe       SO.sub.2 Me                Cl        EtOMe       SO.sub.2 Me                Cl        Pr-iOMe       SO.sub.2 Me                Cl        Pr-nOMe       SO.sub.2 Me                Me        MeOMe       SO.sub.2 Me                Me        EtOMe       SO.sub.2 Me                Me        Pr-iOMe       SO.sub.2 Me                Me        Pr-nOMe       SO.sub.2 Me                OMe       MeOMe       SO.sub.2 Me                OMe       EtOMe       SO.sub.2 Me                OMe       Pr-iOMe       SO.sub.2 Me                OMe       Pr-nOMe       SOMe       H         MeOMe       SOMe       H         EtOMe       SOMe       H         Pr-iOMe       SMe        H         MeOMe       SMe        H         EtOMe       SMe        H         Pr-iOMe       SO.sub.2 CF.sub.3                H         MeOMe       SO.sub.2 CF.sub.3                H         EtOMe       SO.sub.2 CF.sub.3                H         Pr-iOMe       SO.sub.2 CF.sub.3                H         Pr-nOMe       SOCF.sub.3 H         MeOMe       SOCF.sub.3 H         EtOMe       SOCF.sub.3 H         Pr-iOMe       SCF.sub.3  H         MeOMe       SCF.sub.3  H         EtOMe       SCF.sub.3  H         Pr-iOMe       Cl         H         MeOMe       Cl         H         EtOMe       Cl         H         Pr-iOMe       Cl         H         Pr-nOMe       Br         H         MeOMe       Br         H         EtOMe       Br         H         Pr-iOMe       NO.sub.2   H         MeOMe       NO.sub.2   H         EtOMe       NO.sub.2   H         Pr-iOMe       CF.sub.3   H         MeOMe       CF.sub.3   H         EtOMe       CF.sub.3   H         Pr-iOMe       CN         H         MeOMe       CN         H         EtOMe       OMe        H         MeOMe       OMe        H         EtBr        SO.sub.2 Me                H         MeBr        SO.sub.2 Me                H         EtBr        SO.sub.2 Me                H         Pr-iBr        SO.sub.2 Me                H         Pr-nBr        SOMe       H         MeBr        SOMe       H         EtBr        SMe        H         MeBr        SMe        H         EtBr        SO.sub.2 CF.sub.3                H         MeBr        SO.sub.2 CF.sub.3                H         EtBr        SOCF.sub.3 H         MeBr        SOCF.sub.3 H         EtBr        SCF.sub.3  H         MeBr        SCF.sub.3  H         EtBr        Cl         H         MeBr        Cl         H         EtBr        Cl         H         Pr-iBr        Cl         H         Pr-nBr        Br         H         MeBr        Br         H         EtBr        NO.sub.2   H         MeBr        NO.sub.2   H         EtBr        CF.sub.3   H         MeBr        CF.sub.3   H         EtI         SO.sub.2 Me                H         MeI         SO.sub.2 Me                H         EtI         SO.sub.2 Me                H         Pr-iI         SO.sub.2 Me                H         Pr-nI         SO.sub.2 Me                H         Bu-tI         SOMe       H         MeI         SOMe       H         EtI         SMe        H         MeI         SMe        H         EtI         SO.sub.2 CF.sub.3                H         MeI         SO.sub.2 CF.sub.3                H         EtI         SOCF.sub.3 H         MeI         SOCF.sub.3 H         EtI         SCF.sub.3  H         MeI         SCF.sub.3  H         EtI         Cl         H         MeI         Cl         H         EtI         Cl         H         Pr-iI         Cl         H         Pr-nI         Br         H         MeI         Br         H         EtI         NO.sub.2   H         MeI         NO.sub.2   H         EtI         CF.sub.3   H         MeI         CF.sub.3   H         EtCH.sub.2 OMe     SO.sub.2 Me                H         MeCH.sub.2 OMe     SO.sub.2 Me                H         EtCH.sub.2 OMe     SO.sub.2 Me                H         Pr-iCH.sub.2 OMe     SO.sub.2 Me                H         Pr-nCH.sub.2 OMe     SO.sub.2 Me                H         Bu-tCH.sub.2 OMe     SOMe       H         MeCH.sub.2 OMe     SOMe       H         EtCH.sub.2 OMe     SMe        H         MeCH.sub.2 OMe     SMe        H         EtCH.sub.2 OMe     SO.sub.2 CF.sub.3                H         MeCH.sub.2 OMe     SO.sub.2 CF.sub.3                H         EtCH.sub.2 OMe     SOCF.sub.3 H         MeCH.sub.2 OMe     SOCF.sub.3 H         EtCH.sub.2 OMe     SCF.sub.3  H         MeCH.sub.2 OMe     SCF.sub.3  H         EtCH.sub.2 OMe     Cl         H         MeCH.sub.2 OMe     Cl         H         EtCH.sub.2 OMe     Cl         H         Pr-iCH.sub.2 OMe     Cl         H         Pr-nCH.sub.2 OMe     Br         H         MeCH.sub.2 OMe     Br         H         EtCH.sub.2 OMe     NO.sub.2   H         MeCH.sub.2 OMe     NO.sub.2   H         EtCH.sub.2 OMe     CF.sub.3   H         MeCH.sub.2 OMe     CF.sub.3   H         EtF         SO.sub.2 Me                H         MeF         SO.sub.2 ME                H         EtF         SO.sub.2 CF.sub.3                H         MeF         SO.sub.2 CF.sub.3                H         EtF         Cl         H         MeF         Cl         H         EtOEt       SO.sub.2 Me                H         MeOEt       SO.sub. 2 Me                H         EtOEt       SO.sub.2 CF.sub.3                H         MeOEt       SO.sub.2 CF.sub.3                H         EtOEt       Cl         H         MeOEt       Cl         H         EtOPr-i     SO.sub.2 Me                H         MeOPr-i     SO.sub.2 Me                H         EtOPr-i     SO.sub.2 CF.sub.3                H         MeOPr-i     SO.sub.2 CF.sub.3                H         EtOPr-i     Cl         H         MeOPr-i     Cl         H         EtOCHF.sub.2     SO.sub.2 Me                H         MeOCHF.sub.2     SO.sub.2 Me                H         EtOCHF.sub.2     SO.sub.2 CF.sub.3                H         MeOCHF.sub.2     SO.sub.2 CF.sub.3                H         EtOCHF.sub.2     Cl         H         MeOCHF.sub.2     Cl         H         EtOCF.sub.3 SO.sub.2 Me                H         MeOCF.sub.3 SO.sub.2 Me                H         EtOCF.sub.3 SO.sub.2 CF.sub.3                H         MeOCF.sub.3 SO.sub.2 CF.sub.3                H         EtOCF.sub.3 Cl         H         MeOCF.sub.3 Cl         H         EtOCH.sub.2 CF.sub.3     SO.sub.2 Me                H         MeOCH.sub.2 CF.sub.3     SO.sub.2 Me                H         EtOCH.sub.2 CF.sub.3     SO.sub.2 CF.sub.3                H         MeOCH.sub.2 CF.sub.3     SO.sub.2 CF.sub.3                H         EtOCH.sub.2 CF.sub.3     Cl         H         MeOCH.sub.2 CF.sub.3     Cl         H         EtCH.sub.2 OEt     SO.sub.2 Me                H         MeCH.sub.2 OEt     SO.sub.2 Me                H         EtCH.sub.2 OEt     SO.sub.2 CF.sub.3                H         MeCH.sub.2 OEt     SO.sub.2 CF.sub.3                H         EtCH.sub.2 OEt     Cl         H         MeCH.sub.2 OEt     Cl         H         EtCH.sub.2 SMe     SO.sub.2 Me                H         MeCH.sub.2 SMe     SO.sub.2 Me                H         EtCH.sub.2 SMe     SO.sub.2 CF.sub.3                H         MeCH.sub.2 SMe     SO.sub.2 CF.sub.3                H         EtCH.sub.2 SMe     Cl         H         MeCH.sub.2 SMe     Cl         H         Et______________________________________ 
    
     
                       TABLE 6______________________________________ ##STR12##X.sub.1   X.sub.3    X.sub.4   R.sub.1______________________________________Cl        SO.sub.2 Me                H         HCl        SO.sub.2 Me                H         MeCl        SO.sub.2 Me                H         EtCl        SO.sub.2 Me                H         Pr-iCl        SO.sub.2 Me                H         Pr-nCl        SO.sub.2 Me                H         Bu-tCl        SO.sub.2 Me                H         CH.sub.2 CCHCl        SO.sub.2 Me                H         CH.sub.2 CCH.sub.2Cl        SO.sub.2 Me                H         CH.sub.2 CH.sub.2 OMeCl        SO.sub.2 Me                H         CH.sub.2 CH.sub.2 ClCl        SO.sub.2 Me                H         CH.sub.2 CF.sub.3Cl        SO.sub.2 Me                H         CH.sub.2 CH.sub.2 CNCl        SO.sub.2 Me                F         MeCl        SO.sub.2 Me                F         EtCl        SO.sub.2 Me                F         Pr-iCl        SO.sub.2 Me                Cl        MeCl        SO.sub. 2 Me                Cl        EtCl        SO.sub.2 Me                Cl        Pr-iCl        SO.sub.2 Me                Me        MeCl        SO.sub.2 Me                Me        EtCl        SO.sub.2 Me                OMe       MeCl        SO.sub.2 Me                OMe       EtCL        SO.sub.2 Me                OMe       Pr-iCl        SOMe       H         MeCl        SOMe       H         EtCl        SOMe       H         Pr-iCl        SMe        H         MeCl        SMe        H         EtCl        SMe        H         Pr-iCl        SO.sub.2 CF.sub.3                H         MeCl        SO.sub.2 CF.sub.3                H         EtCl        SO.sub.2 CF.sub.3                H         Pr-iCl        SO.sub.2 CF.sub.3                H         Pr-nCl        SOCF.sub.3 H         MeCl        SOCF.sub.3 H         EtCl        SOCF.sub.3 H         Pr-iCl        SCF.sub.3  H         MeCl        SCF.sub.3  H         EtCl        SCF.sub.3  H         Pr-iCl        Cl         H         MeCl        Cl         H         EtCl        Cl         H         Pr-iCl        Cl         H         Pr-nCl        Br         H         MeCl        Br         H         MeCl        Br         H         Pr-iCl        NO.sub.2   H         MeCl        NO.sub.2   H         EtCl        NO.sub.2   H         Pr-iCl        CF.sub.3   H         MeCl        CF.sub.3   H         EtCl        CF.sub.3   H         Pr-iCl        CN         H         MeCl        CN         H         EtCl        OMe        H         MeCl        OMe        H         EtOMe       SO.sub.2 Me                H         HOMe       SO.sub.2 Me                H         MeOMe       SO.sub.2 Me                H         EtOMe       SO.sub.2 Me                H         Pr-iOMe       SO.sub.2 Me                H         Pr-nOMe       SO.sub.2 Me                H         Bu-tOMe       SO.sub.2 Me                H         CH.sub.2 CCHOMe       SO.sub.2 Me                H         CH.sub.2 CCH.sub.2OMe       SO.sub.2 Me                H         CH.sub.2 CH.sub.2 OMeOMe       SO.sub.2 Me                H         CH.sub.2 CH.sub.2 ClOMe       SO.sub.2 Me                H         CH.sub.2 CF.sub.3OMe       SO.sub.2 Me                H         CH.sub.2 CH.sub.2 CNOMe       SO.sub.2 Me                F         MeOMe       SO.sub.2 Me                F         EtOMe       SO.sub.2 Me                F         Pr-iOMe       SO.sub.2 Me                F         Pr-nOMe       SO.sub.2 Me                Cl        MeOMe       SO.sub.2 Me                Cl        EtOMe       SO.sub.2 Me                Cl        Pr-iOMe       SO.sub.2 Me                Cl        Pr-nOMe       SO.sub.2 Me                Me        MeOMe       SO.sub.2 Me                Me        EtOMe       SO.sub.2 Me                Me        Pr-iOMe       SO.sub.2 Me                Me        Pr-nOMe       SO.sub.2 Me                OMe       MeOMe       SO.sub.2 Me                OMe       EtOMe       SO.sub.2 Me                OMe       Pr-iOMe       SO.sub.2 Me                OMe       Pr-nOMe       SOMe       H         MeOMe       SOMe       H         EtOMe       SOMe       H         Pr-iOMe       SMe        H         MeOMe       SMe        H         EtOMe       SMe        H         Pr-iOMe       SO.sub.2 CF.sub.3                H         MeOMe       SO.sub.2 CF.sub.3                H         EtOMe       SO.sub.2 CF.sub.3                H         Pr-iOMe       SO.sub.2 CF.sub.3                H         Pr-nOMe       SOCF.sub.3 H         MeOMe       SOCF.sub.3 H         EtOMe       SOCF.sub.3 H         Pr-iOMe       SCF.sub.3  H         MeOMe       SCF.sub.3  H         EtOMe       SCF.sub.3  H         Pr-iOMe       Cl         H         MeOMe       Cl         H         EtOMe       Cl         H         Pr-iOMe       Cl         H         Pr-nOMe       Br         H         MeOMe       Br         H         EtOMe       Br         H         Pr-iOMe       NO.sub.2   H         MeOMe       NO.sub.2   H         EtOMe       NO.sub.2   H         Pr-iOMe       CF.sub.3   H         MeOMe       CF.sub.3   H         EtOMe       CF.sub.3   H         Pr-iOMe       CN         H         MeOMe       CN         H         EtOMe       OMe        H         MeOMe       OMe        H         EtBr        SO.sub.2 Me                H         MeBr        SO.sub.2 Me                H         EtBr        SO.sub.2 Me                H         Pr-iBr        SO.sub.2 Me                H         Pr-nBr        SOMe       H         MeBr        SOMe       H         EtBr        SMe        H         MeBr        SMe        H         EtBr        SO.sub.2 CF.sub.3                H         MeBr        SO.sub.2 CF.sub. 3                H         EtBr        SOCF.sub.3 H         MeBr        SOCF.sub.3 H         EtBr        SCF.sub.3  H         MeBr        SCF.sub.3  H         EtBr        Cl         H         MeBr        Cl         H         EtBr        Cl         H         Pr-iBr        Cl         H         Pr-nBr        Br         H         MeBr        Br         H         EtBr        NO.sub.2   H         MeBr        NO.sub.2   H         EtBr        CF.sub.3   H         MeBr        CF.sub.3   H         EtI         SO.sub.2 Me                H         MeI         SO.sub.2 Me                H         EtI         SO.sub.2 Me                H         Pr-iI         SO.sub.2 Me                H         Pr-nI         SO.sub.2 Me                H         Bu-tI         SOMe       H         MeI         SOMe       H         EtI         SMe        H         MeI         SMe        H         EtI         SO.sub.2 CF.sub.3                H         MeI         SO.sub.2 CF.sub.3                H         EtI         SOCF.sub.3 H         MeI         SOCF.sub.3 H         EtI         SCF.sub.3  H         MeI         SCF.sub.3  H         EtI         Cl         H         MeI         Cl         H         EtI         Cl         H         Pr-iI         Cl         H         Pr-nI         Br         H         MeI         Br         H         EtI         NO.sub.2   H         MeI         NO.sub.2   H         EtI         CF.sub.3   H         MeI         CF.sub.3   H         EtCH.sub.2 OMe     SO.sub.2 Me                H         MeCH.sub. 2 OMe     SO.sub.2 Me                H         EtCH.sub.2 OMe     SO.sub.2 Me                H         Pr-iCH.sub.2 OMe     SO.sub.2 Me                H         Pr-nCH.sub.2 OMe     SO.sub.2 Me                H         Bu-tCH.sub.2 OMe     SOMe       H         MeCH.sub.2 OMe     SOMe       H         EtCH.sub.2 OMe     SMe        H         MeCH.sub.2 OMe     SMe        H         EtCH.sub.2 OMe     SO.sub.2 CF.sub.3                H         MeCH.sub.2 OMe     SO.sub.2 CF.sub.3                H         EtCH.sub.2 OMe     SOCF.sub.3 H         MeCH.sub.2 OMe     SOCF.sub.3 H         EtCH.sub.2 OMe     SCF.sub.3  H         MeCH.sub.2 OMe     SCF.sub.3  H         EtCH.sub.2 OMe     Cl         H         MeCH.sub.2 OMe     Cl         H         EtCH.sub.2 OMe     Cl         H         Pr-iCH.sub.2 OMe     Cl         H         Pr-nCH.sub.2 OMe     Br         H         MeCH.sub.2 OMe     Br         H         EtCH.sub.2 OMe     NO.sub.2   H         MeCH.sub.2 OMe     NO.sub.2   H         EtCH.sub.2 OMe     CF.sub.3   H         MeCH.sub.2 OMe     CF.sub.3   H         EtF         SO.sub.2 Me                H         MeF         SO.sub.2 Me                H         EtF         SO.sub.2 CF.sub.3                H         MeF         SO.sub.2 CF.sub.3                H         EtF         Cl         H         MeF         Cl         H         EtOEt       SO.sub.2 Me                H         MeOEt       SO.sub.2 Me                H         EtOEt       SO.sub.2 CF.sub.3                H         MeOEt       SO.sub.2 CF.sub.3                H         EtOEt       Cl         H         MeOEt       Cl         H         EtOPr-i     SO.sub.2 Me                H         MeOPr-i     SO.sub.2 Me                H         EtOPr-i     SO.sub.2 CF.sub.3                H         MeOPr-i     SO.sub.2 CF.sub.3                H         EtOPr-i     Cl         H         MeOPr-i     Cl         H         EtOCHF.sub.2     SO.sub.2 Me                H         MeOCHF.sub.2     SO.sub.2 Me                H         EtOCHF.sub.2     SO.sub.2 CF.sub.3                H         MeOCHF.sub.2     SO.sub.2 CF.sub.3                H         EtOCHF.sub.2     Cl         H         MeOCHF.sub.2     Cl         H         EtOCF.sub.3 SO.sub.2 Me                H         MeOCF.sub.3 SO.sub.2 Me                H         EtOCF.sub.3 SO.sub.2 CF.sub.3                H         MeOCF.sub.3 SO.sub.2 CF.sub.3                H         EtOCF.sub.3 Cl         H         MeOCF.sub.3 Cl         H         EtOCH.sub.2 CF.sub.3     SO.sub.2 Me                H         MeOCH.sub.2 CF.sub.3     SO.sub.2 Me                H         EtOCH.sub.2 CF.sub.3     SO.sub.2 CF.sub.3                H         MeOCH.sub.2 CF.sub.3     SO.sub.2 CF.sub.3                H         EtOCH.sub.2 CF.sub.3     Cl         H         MeOCH.sub.2 CF.sub.3     Cl         H         EtCH.sub. 2 OEt     SO.sub.2 Me                H         MeCH.sub.2 OEt     SO.sub.2 Me                H         EtCH.sub.2 OEt     SO.sub.2 CF.sub.3                H         MeCH.sub.2 OEt     SO.sub.2 CF.sub.3                H         EtCH.sub.2 OEt     Cl         H         MeCH.sub.2 OEt     Cl         H         EtCH.sub.2 SMe     SO.sub.2 Me                H         MeCH.sub.2 SMe     SO.sub.2 Me                H         EtCH.sub.2 SMe     SO.sub.2 CF.sub.3                H         MeCH.sub.2 SMe     SO.sub.2 CF.sub.3                H         EtCH.sub.2 SMe     Cl         H         MeCH.sub.2 SMe     Cl         H         Et______________________________________ 
    
     
                       TABLE 7______________________________________ ##STR13##X.sub.1     X.sub.3    X.sub.4  R.sub.1______________________________________Cl          SO.sub.2 Me                  H        HCl          SO.sub.2 Me                  H        MeCl          SO.sub.2 Me                  H        EtCl          SO.sub.2 Me                  H        Pr-iCl          SO.sub.2 Me                  H        Pr-nCl          SO.sub.2 Me                  H        Bu-tCl          SO.sub.2 Me                  H        CH.sub.2 CCHCl          SO.sub.2 Me                  H        CH.sub.2 CCH.sub.2Cl          SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 OMeCl          SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 ClCl          SO.sub.2 Me                  H        CH.sub.2 CF.sub.3Cl          SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 CNCl          SO.sub.2 Me                  F        MeCl          SO.sub.2 Me                  F        EtCl          SO.sub.2 Me                  F        Pr-iCl          SO.sub.2 Me                  Cl       MeCl          SO.sub.2 Me                  Cl       EtCl          SO.sub.2 Me                  Cl       Pr-iCl          SO.sub.2 Me                  Me       MeCl          SO.sub.2 Me                  Me       EtCl          SO.sub.2 Me                  OMe      MeCl          SO.sub.2 Me                  OMe      EtCl          SO.sub.2 Me                  OMe      Pr-iCl          SOMe       H        MeCl          SOMe       H        EtCl          SOMe       H        Pr-iCl          SMe        H        MeCl          SMe        H        EtCl          SMe        H        Pr-iCl          SO.sub.2 CF.sub.3                  H        MeCl          SO.sub.2 CF.sub.3                  H        EtCl          SO.sub.2 CF.sub.3                  H        Pr-iCl          SO.sub.2 CF.sub.3                  H        Pr-nCl          SOCF.sub.3 H        MeCl          SOCF.sub.3 H        EtCl          SOCF.sub.3 H        Pr-iCl          SCF.sub.3  H        MeCl          SCF.sub.3  H        EtCl          SCF.sub.3  H        Pr-iCl          Cl         H        MeCl          Cl         H        EtCl          Cl         H        Pr-iCl          Cl         H        Pr-nCl          Br         H        MeCl          Br         H        EtCl          Br         H        Pr-iCl          NO.sub.2   H        MeCl          NO.sub.2   H        EtCl          NO.sub.2   H        Pr-iCl          CF.sub.3   H        MeCl          CF.sub.3   H        EtCl          CF.sub.3   H        Pr-iCl          CN         H        MeCl          CN         H        EtCl          OMe        H        MeCl          OMe        H        EtOMe         SO.sub.2 Me                  H        HOMe         SO.sub.2 Me                  H        MeOMe         SO.sub.2 Me                  H        EtOMe         SO.sub.2 Me                  H        Pr-iOMe         SO.sub.2 Me                  H        Pr-nOMe         SO.sub.2 Me                  H        Bu-tOMe         SO.sub.2 Me                  H        CH.sub.2 CCHOMe         SO.sub.2 Me                  H        CH.sub.2 CCH.sub.2OMe         SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 OMeOMe         SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 ClOMe         SO.sub.2 Me                  H        CH.sub.2 CF.sub.3OMe         SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 CNOMe         SO.sub.2 Me                  F        MeOMe         SO.sub.2 Me                  F        EtOMe         SO.sub.2 Me                  F        Pr-iOMe         SO.sub.2 Me                  F        Pr-nOMe         SO.sub.2 Me                  Cl       MeOMe         SO.sub.2 Me                  Cl       EtOMe         SO.sub.2 Me                  Cl       Pr-iOMe         SO.sub.2 Me                  Cl       Pr-nOMe         SO.sub.2 Me                  Me       MeOMe         SO.sub.2 Me                  Me       EtOMe         SO.sub.2 Me                  Me       Pr-iOMe         SO.sub.2 Me                  Me       Pr-nOMe         SO.sub.2 Me                  OMe      MeOMe         SO.sub.2 Me                  OMe      EtOMe         SO.sub.2 Me                  OMe      Pr-iOMe         SO.sub.2 Me                  OMe      Pr-nOMe         SOMe       H        MeOMe         SOMe       H        EtOMe         SOMe       H        Pr-iOMe         SMe        H        MeOMe         SMe        H        EtOMe         SMe        H        Pr-iOMe         SO.sub.2 CF.sub.3                  H        MeOMe         SO.sub.2 CF.sub.3                  H        EtOMe         SO.sub.2 CF.sub.3                  H        Pr-iOMe         SO.sub.2 CF.sub.3                  H        Pr-nOMe         SOCF.sub.3 H        MeOMe         SOCF.sub.3 H        EtOMe         SOCF.sub.3 H        Pr-iOMe         SCF.sub.3  H        MeOMe         SCF.sub.3  H        EtOMe         SCF.sub.3  H        Pr-iOMe         Cl         H        MeOMe         Cl         H        EtOMe         Cl         H        Pr-iOMe         Cl         H        Pr-nOMe         Br         H        MeOMe         Br         H        EtOMe         Br         H        Pr-iOMe         NO.sub.2   H        MeOMe         NO.sub.2   H        EtOMe         NO.sub.2   H        Pr-iOMe         CF.sub.3   H        MeOMe         CF.sub.3   H        EtOMe         CF.sub.3   H        Pr-iOMe         CN         H        MeOMe         CN         H        EtOMe         OMe        H        MeOMe         OMe        H        EtBr          SO.sub.2 Me                  H        MeBr          SO.sub.2 Me                  H        EtBr          SO.sub.2 Me                  H        Pr-iBr          SO.sub.2 Me                  H        Pr-nBr          SOMe       H        MeBr          SOMe       H        EtBr          SMe        H        MeBr          SMe        H        EtBr          SO.sub.2 CF.sub.3                  H        MeBr          SO.sub.2 CF.sub.3                  H        EtBr          SOCF.sub.3 H        MeBr          SOCF.sub.3 H        EtBr          SCF.sub.3  H        MeBr          SCF.sub.3  H        EtBr          Cl         H        MeBr          Cl         H        EtBr          Cl         H        Pr-iBr          Cl         H        Pr-nBr          Br         H        MeBr          Br         H        EtBr          NO.sub.2   H        MeBr          NO.sub.2   H        EtBr          CF.sub.3   H        MeBr          CF.sub.3   H        EtI           SO.sub.2 Me                  H        MeI           SO.sub.2 Me                  H        EtI           SO.sub.2 Me                  H        Pr-iI           SO.sub.2 Me                  H        Pr-nI           SO.sub.2 Me                  H        Bu-tI           SOMe       H        MeI           SOMe       H        EtI           SMe        H        MeI           SMe        H        EtI           SO.sub.2 CF.sub.3                  H        MeI           SO.sub.2 CF.sub.3                  H        EtI           SOCF.sub.3 H        MeI           SOCF.sub.3 H        EtI           SCF.sub.3  H        MeI           SCF.sub.3  H        EtI           Cl         H        MeI           Cl         H        EtI           Cl         H        Pr-iI           Cl         H        Pr-nI           Br         H        MeI           Br         H        EtI           NO.sub.2   H        MeI           NO.sub.2   H        EtI           CF.sub.3   H        MeI           CF.sub.3   H        EtCH.sub.2 OMe       SO.sub.2 Me                  H        MeCH.sub.2 OMe       SO.sub.2 Me                  H        EtCH.sub.2 OMe       SO.sub.2 Me                  H        Pr-iCH.sub.2 OMe       SO.sub.2 Me                  H        Pr-nCH.sub.2 OMe       SO.sub.2 Me                  H        Bu-tCH.sub.2 OMe       SOMe       H        MeCH.sub.2 OMe       SOMe       H        EtCH.sub.2 OMe       SMe        H        MeCH.sub.2 OMe       SMe        H        EtCH.sub.2 OMe       SO.sub.2 CF.sub.3                  H        MeCH.sub.2 OMe       SO.sub.2 CF.sub.3                  H        EtCH.sub.2 OMe       SOCF.sub.3 H        MeCH.sub.2 OMe       SOCF.sub.3 H        EtCH.sub.2 OMe       SCF.sub.3  H        MeCH.sub.2 OMe       SCF.sub.3  H        EtCH.sub.2 OMe       Cl         H        MeCH.sub.2 OMe       Cl         H        EtCH.sub.2 OMe       Cl         H        Pr-iCH.sub.2 OMe       Cl         H        Pr-nCH.sub.2 OMe       Br         H        MeCH.sub.2 OMe       Br         H        EtCH.sub.2 OMe       NO.sub.2   H        MeCH.sub.2 OMe       NO.sub.2   H        EtCH.sub.2 OMe       CF.sub.3   H        MeCH.sub.2 OMe       CF.sub.3   H        EtF           SO.sub.2 Me                  H        MeF           SO.sub.2 Me                  H        EtF           SO.sub.2 CF.sub.3                  H        MeF           SO.sub.2 CF.sub.3                  H        EtF           Cl         H        MeF           Cl         H        EtOEt         SO.sub.2 Me                  H        MeOEt         SO.sub.2 Me                  H        EtOEt         SO.sub.2 CF.sub.3                  H        MeOEt         SO.sub.2 CF.sub.3                  H        EtOEt         Cl         H        MeOEt         Cl         H        EtOPr-i       SO.sub.2 Me                  H        MeOPr-i       SO.sub.2 Me                  H        EtOPr-i       SO.sub.2 CF.sub.3                  H        MeOPr-i       SO.sub.2 CF.sub.3                  H        EtOPr-i       Cl         H        MeOPr-i       Cl         H        EtOCHF.sub.2  SO.sub.2 Me                  H        MeOCHF.sub.2  SO.sub.2 Me                  H        EtOCHF.sub.2  SO.sub.2 CF.sub.3                  H        MeOCHF.sub.2  SO.sub.2 CF.sub.3                  H        EtOCHF.sub.2  Cl         H        MeOCHF.sub.2  Cl         H        EtOCF.sub.3   SO.sub.2 Me                  H        MeOCF.sub.3   SO.sub.2 Me                  H        EtOCF.sub.3   SO.sub.2 CF.sub.3                  H        MeOCF.sub.3   SO.sub.2 CF.sub.3                  H        EtOCF.sub.3   Cl         H        MeOCF.sub.3   Cl         H        EtOCH.sub.2 CF.sub.3       SO.sub.2 Me                  H        MeOCH.sub.2 CF.sub.3       SO.sub.2 Me                  H        EtOCH.sub.2 CF.sub.3       SO.sub.2 CF.sub.3                  H        MeOCH.sub.2 CF.sub.3       SO.sub.2 CF.sub.3                  H        EtOCH.sub.2 CF.sub.3       Cl         H        MeOCH.sub.2 CF.sub.3       Cl         H        EtCH.sub.2 OEt       SO.sub.2 Me                  H        MeCH.sub.2 OEt       SO.sub.2 Me                  H        EtCH.sub.2 OEt       SO.sub.2 CF.sub.3                  H        MeCH.sub.2 OEt       SO.sub.2 CF.sub.3                  H        EtCH.sub.2 OEt       Cl         H        MeCH.sub.2 OEt       Cl         H        EtCH.sub.2 SMe       SO.sub.2 Me                  H        MeCH.sub.2 SMe       SO.sub.2 Me                  H        EtCH.sub.2 SMe       SO.sub.2 CF.sub.3                  H        MeCH.sub.2 SMe       SO.sub.2 CF.sub.3                  H        EtCH.sub.2 SMe       Cl         H        MeCH.sub.2 SMe       Cl         H        Et______________________________________ 
    
     
                       TABLE 8______________________________________ ##STR14##X.sub.1     X.sub.3    X.sub.4  R.sub.1______________________________________Cl          SO.sub.2 Me                  H        HCl          SO.sub.2 Me                  H        MeCl          SO.sub.2 Me                  H        EtCl          SO.sub.2 Me                  H        Pr-iCl          SO.sub.2 Me                  H        Pr-nCl          SO.sub.2 Me                  H        Bu-tCl          SO.sub.2 Me                  H        CH.sub.2 CCHCl          SO.sub.2 Me                  H        CH.sub.2 CCH.sub.2Cl          SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 OMeCl          SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 ClCl          SO.sub.2 Me                  H        CH.sub.2 CF.sub.3Cl          SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 CNCl          SO.sub.2 Me                  F        MeCl          SO.sub.2 Me                  F        EtCl          SO.sub.2 Me                  F        Pr-iCl          SO.sub.2 Me                  Cl       MeCl          SO.sub.2 Me                  Cl       EtCl          SO.sub.2 Me                  Cl       Pr-iCl          SO.sub.2 Me                  Me       MeCl          SO.sub.2 Me                  Me       EtCl          SO.sub.2 Me                  OMe      MeCl          SO.sub.2 Me                  OMe      EtCl          SO.sub.2 Me                  OMe      Pr-iCl          SOMe       H        MeCl          SOMe       H        EtCl          SOMe       H        Pr-iCl          SMe        H        MeCl          SMe        H        EtCl          SMe        H        Pr-iCl          SO.sub.2 CF.sub.3                  H        MeCl          SO.sub.2 CF.sub.3                  H        EtCl          SO.sub.2 CF.sub.3                  H        Pr-iCl          SO.sub.2 CF.sub.3                  H        Pr-nCl          SOCF.sub.3 H        MeCl          SOCF.sub.3 H        EtCl          SOCF.sub.3 H        Pr-iCl          SCF.sub.3  H        MeCl          SCF.sub.3  H        EtCl          SCF.sub.3  H        Pr-iCl          Cl         H        MeCl          Cl         H        EtCl          Cl         H        Pr-iCl          Cl         H        Pr-nCl          Br         H        MeCl          Br         H        EtCl          Br         H        Pr-iCl          NO.sub.2   H        MeCl          NO.sub.2   H        EtCl          NO.sub.2   H        Pr-iCl          CF.sub.3   H        MeCl          CF.sub.3   H        EtCl          CF.sub.3   H        Pr-iCl          CN         H        MeCl          CN         H        EtCl          OMe        H        MeCl          OMe        H        EtOMe         SO.sub.2 Me                  H        HOMe         SO.sub.2 Me                  H        MeOMe         SO.sub.2 Me                  H        EtOMe         SO.sub.2 Me                  H        Pr-iOMe         SO.sub.2 Me                  H        Pr-nOMe         SO.sub.2 Me                  H        Bu-tOMe         SO.sub.2 Me                  H        CH.sub.2 CCHOMe         SO.sub.2 Me                  H        CH.sub.2 CCH.sub.2OMe         SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 OMeOMe         SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 ClOMe         SO.sub.2 Me                  H        CH.sub.2 CF.sub.3OMe         SO.sub.2 Me                  H        CH.sub.2 CH.sub.2 CNOMe         SO.sub.2 Me                  F        MeOMe         SO.sub.2 Me                  F        EtOMe         SO.sub.2 Me                  F        Pr-iOMe         SO.sub.2 Me                  F        Pr-nOMe         SO.sub.2 Me                  Cl       MeOMe         SO.sub.2 Me                  Cl       EtOMe         SO.sub.2 Me                  Cl       Pr-iOMe         SO.sub.2 Me                  Cl       Pr-nOMe         SO.sub.2 Me                  Me       MeOMe         SO.sub.2 Me                  Me       EtOMe         SO.sub.2 Me                  Me       Pr-iOMe         SO.sub.2 Me                  Me       Pr-nOMe         SO.sub.2 Me                  OMe      MeOMe         SO.sub.2 Me                  OMe      EtOMe         SO.sub.2 Me                  OMe      Pr-iOMe         SO.sub.2 Me                  OMe      Pr-nOMe         SOMe       H        MeOMe         SOMe       H        EtOMe         SOMe       H        Pr-iOMe         SMe        H        MeOMe         SMe        H        EtOMe         SMe        H        Pr-iOMe         SO.sub.2 CF.sub.3                  H        MeOMe         SO.sub.2 CF.sub.3                  H        EtOMe         SO.sub.2 CF.sub.3                  H        Pr-iOMe         SO.sub.2 CF.sub.3                  H        Pr-nOMe         SOCF.sub.3 H        MeOMe         SOCF.sub.3 H        EtOMe         SOCF.sub.3 H        Pr-iOMe         SCF.sub.3  H        MeOMe         SCF.sub.3  H        EtOMe         SCF.sub.3  H        Pr-iOMe         Cl         H        MeOMe         Cl         H        EtOMe         Cl         H        Pr-iOMe         Cl         H        Pr-nOMe         Br         H        MeOMe         Br         H        EtOMe         Br         H        Pr-iOMe         NO.sub.2   H        MeOMe         NO.sub.2   H        EtOMe         NO.sub.2   H        Pr-iOMe         CF.sub.3   H        MeOMe         CF.sub.3   H        EtOMe         CF.sub.3   H        Pr-iOMe         CN         H        MeOMe         CN         H        EtOMe         OMe        H        MeOMe         OMe        H        EtBr          SO.sub.2 Me                  H        MeBr          SO.sub.2 Me                  H        EtBr          SO.sub.2 Me                  H        Pr-iBr          SO.sub.2 Me                  H        Pr-nBr          SOMe       H        MeBr          SOMe       H        EtBr          SMe        H        MeBr          SMe        H        EtBr          SO.sub. 2 CF.sub.3                  H        MeBr          SO.sub.2 CF.sub.3                  H        EtBr          SOCF.sub.3 H        MeBr          SOCF.sub.3 H        EtBr          SCF.sub.3  H        MeBr          SCF.sub.3  H        EtBr          Cl         H        MeBr          Cl         H        EtBr          Cl         H        Pr-iBr          Cl         H        Pr-nBr          Br         H        MeBr          Br         H        EtBr          NO.sub.2   H        MeBr          NO.sub.2   H        EtBr          CF.sub.3   H        MeBr          CF.sub.3   H        EtI           SO.sub.2 Me                  H        MeI           SO.sub.2 Me                  H        EtI           SO.sub.2 Me                  H        Pr-iI           SO.sub.2 Me                  H        Pr-nI           SO.sub.2 Me                  H        Bu-tI           SOMe       H        MeI           SOMe       H        EtI           SMe        H        MeI           SMe        H        EtI           SO.sub.2 CF.sub.3                  H        MeI           SO.sub.2 CF.sub.3                  H        EtI           SOCF.sub.3 H        MeI           SOCF.sub.3 H        EtI           SCF.sub.3  H        MeI           SCF.sub.3  H        EtI           Cl         H        MeI           Cl         H        EtI           Cl         H        Pr-iI           Cl         H        Pr-nI           Br         H        MeI           Br         H        EtI           NO.sub.2   H        MeI           NO.sub.2   H        EtI           CF.sub.3   H        MeI           CF.sub.3   H        EtCH.sub.2 OMe       SO.sub.2 Me                  H        MeCH.sub.2 OMe       SO.sub.2 Me                  H        EtCH.sub.2 OMe       SO.sub.2 Me                  H        Pr-iCH.sub.2 OMe       SO.sub.2 Me                  H        Pr-nCH.sub.2 OMe       SO.sub.2 Me                  H        Bu-tCH.sub.2 OMe       SOMe       H        MeCH.sub.2 OMe       SOMe       H        EtCH.sub.2 OMe       SMe        H        MeCH.sub.2 OMe       SMe        H        EtCH.sub.2 OMe       SO.sub.2 CF.sub.3                  H        MeCH.sub.2 OMe       SO.sub.2 CF.sub.3                  H        EtCH.sub.2 OMe       SOCF.sub.3 H        MeCH.sub.2 OMe       SOCF.sub.3 H        EtCH.sub.2 OMe       SCF.sub.3  H        MeCH.sub.2 OMe       SCF.sub.3  H        EtCH.sub.2 OMe       Cl         H        MeCH.sub.2 OMe       Cl         H        EtCH.sub.2 OMe       Cl         H        Pr-iCH.sub.2 OMe       Cl         H        Pr-nCH.sub.2 OMe       Br         H        MeCH.sub.2 OMe       Br         H        EtCH.sub.2 OMe       NO.sub.2   H        MeCH.sub.2 OMe       NO.sub.2   H        EtCH.sub.2 OMe       CF.sub.3   H        MeCH.sub.2 OMe       CF.sub.3   H        EtF           SO.sub.2 Me                  H        MeF           SO.sub.2 Me                  H        EtF           SO.sub.2 CF.sub.3                  H        MeF           SO.sub.2 CF.sub.3                  H        EtF           Cl         H        MeF           Cl         H        EtOEt         SO.sub.2 Me                  H        MeOEt         SO.sub.2 Me                  H        EtOEt         SO.sub.2 CF.sub.3                  H        MeOEt         SO.sub.2 CF.sub.3                  H        EtOEt         Cl         H        MeOEt         Cl         H        EtOPr-i       SO.sub.2 Me                  H        MeOPr-i       SO.sub.2 Me                  H        EtOPr-i       SO.sub.2 CF.sub.3                  H        MeOPr-i       SO.sub.2 CF.sub.3                  H        EtOPr-i       Cl         H        MeOPr-i       Cl         H        EtOCHF.sub.2  SO.sub.2 Me                  H        MeOCHF.sub.2  SO.sub.2 Me                  H        EtOCHF.sub.2  SO.sub.2 CF.sub.3                  H        MeOCHF.sub.2  SO.sub.2 CF.sub.3                  H        EtOCHF.sub.2  Cl         H        MeOCHF.sub.2  Cl         H        EtOCF.sub.3   SO.sub.2 Me                  H        MeOCF.sub.3   SO.sub.2 Me                  H        EtOCF.sub.3   SO.sub.2 CF.sub.3                  H        MeOCF.sub.3   SO.sub.2 CF.sub.3                  H        EtOCF.sub.3   Cl         H        MeOCF.sub.3   Cl         H        EtOCH.sub.2 CF.sub.3       SO.sub.2 Me                  H        MeOCH.sub.2 CF.sub.3       SO.sub.2 Me                  H        EtOCH.sub.2 CF.sub.3       SO.sub.2 CF.sub.3                  H        MeOCH.sub.2 CF.sub.3       SO.sub.2 CF.sub.3                  H        EtOCH.sub.2 CF.sub.3       Cl         H        MeOCH.sub.2 CF.sub.3       Cl         H        EtCH.sub.2 OEt       SO.sub.2 Me                  H        MeCH.sub.2 OEt       SO.sub.2 Me                  H        EtCH.sub.2 OEt       SO.sub.2 CF.sub.3                  H        MeCH.sub.2 OEt       SO.sub.2 CF.sub.3                  H        EtCH.sub.2 OEt       Cl         H        MeCH.sub.2 OEt       Cl         H        EtCH.sub.2 SMe       SO.sub.2 Me                  H        MeCH.sub.2 SMe       SO.sub.2 Me                  H        EtCH.sub.2 SMe       SO.sub.2 CF.sub.3                  H        MeCH.sub.2 SMe       SO.sub.2 CF.sub.3                  H        EtCH.sub.2 SMe       Cl         H        MeCH.sub.2 SMe       Cl         H        Et______________________________________ 
    
     When the compound of the present invention is to be used as an agricultural or horticultural herbicide, it is usually mixed with a suitable carrier, for instance, a solid carrier such as clay, talc, bentonite or diatomaceous earth, or a liquid carrier such as water, an alcohol (such as methanol or ethanol), an aromatic hydrocarbon (such as benzene, toluene or xylene), a chlorinated hydrocarbon, an ether, a ketone, an ester (such as ethyl acetate) or an acid amide (such as dimethylformamide). If desired, an emulsifier, a dispersing agent, a suspending agent, a penetrating agent, a spreader or a stabilizer may be added to prepare an optional formulation such as a liquid formulation, an emulsifiable concentrate, a wettable powder, a dust, a granule or a flowable. 
     Further, if desired, other herbicides, various insecticides, bacteriocides, plant regulating agents or synergism agents may be combined at the time of the preparation of the formulations or at the time of the application of the herbicides. 
     As other herbicides to be combined with the herbicide of the present invention, there may be mentioned, for instance, compounds disclosed in Farm Chemicals Handbook, the 73rd Edition (1987). Among them, there may be mentioned, for example, atrazine, cyanazine, alachlor, metolachlor, EPTC, 2,4-D, butylate, dicamba, bromoxynil and tridiphane. Further, N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-3-chloro-4-methoxycarbonyl-1-methylpyrazole-5-sulfonamide or N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-3-bromo-4-methoxycarbonyl-1-methylpyrazole-5-sulfonamide as disclosed in U.S. Pat. No. 4,668,277 may also be combined with the herbicide of the present invention. 
     The dose varies depending upon the application site, the season for application, the method for application, the type of the crop plant, etc. In general, however, the dose is usually within a range of from 0.001 to 10 kg per hectare as the amount of the active ingredient. 
     Now, Formulation Examples of the herbicides containing the compounds of the present invention as active ingredients, will be given. However, it should be understood that the present invention is by no means restricted to such specific Examples. In the following Formulation Examples, &#34;parts&#34; means &#34;parts by weight&#34;. 
     FORMULATION EXAMPLE 1: Wettable powder 
     
         ______________________________________Compound No. 1 of the present invention                    60 partsZeeklite PFP (tradename for a kaolin-type                    33 partsclay, manufactured by Zeeklite Industries,Co., Ltd.)Sorpol 5039 (tradename for a mixture of a                     5 partsnonionic surfactant and an anionicsurfactant, manufactured by Toho ChemicalCo., Ltd.)Carplex (tradename for a coagulation-                     2 partspreventing agent composed of a mixture ofa surfactant and fine silica powder,manufactured by Shionogi PharmaceuticalCo., Ltd.)______________________________________ 
    
     The above ingredients are homogeneously pulverized and mixed to form a wettable powder. 
     
         ______________________________________Compound No. 1 of the present invention                     l.5 partsXylene                    78.5 partsN,N-dimethylformamide     l5 partsSorpol 2680 (tradename for a mixture of                     5 partsa nonionic surfactant and an anionicsurfactant, manufactured by Toho ChemicalCo., Ltd.)______________________________________ 
    
     The above ingredients are homogeneously mixed to obtain an emulsifiable concentrate. 
     FORMULATION EXAMPLE 3: Flowable 
     
         ______________________________________Compound No. 1 of the present invention                      40 partsAgrizole B-710 (tradename for a nonionic                      10 partssurfactant, manufactured by Kao Corporation)Runox 1000C (tradename for an anionic                      0.5 partssurfactant, manufactured by Toho ChemicalCo., Ltd.)l% Rodopol water (tradename for a                      20 partsthickener, manufactured by Rhone-Poulenc)Water                      29.5 parts______________________________________ 
    
     The above ingredients are homogeneously mixed to form a flowable. 
     FORMULATION EXAMPLE 4: Wettable powder 
     
         ______________________________________Compound No. 2 of the present invention                    60 partsZeeklite PFP (tradename for a kaolin-type                    33 partsclay, manufactured by Zeeklite Industries,Co., Ltd.)Sorpol 5039 (tradename for a mixture of a                     5 partsnonionic surfactant and an anionicsurfactant, manufactured by Toho ChemicalCo., Ltd.)Carplex (tradename for a coagulation-                     2 partspreventing agent composed of a mixture ofa surfactant and fine silica powder,manuactured by Shionogi PharmaceuticalCo., Ltd.)______________________________________ 
    
     The above ingredients are homogeneously pulverized and mixed to form a wettable powder. 
     FORMULATION EXAMPLE 5: Emulsifiable concentrate 
     
         ______________________________________Compound No. 2 of the present invention                     1.5 partsXylene                    78.5 partsN,N-dimethylformamide     15 partsSorpol 2680 (tradename for a mixture of                     5 partsa nonionic surfactant and an anionicsurfactant, manufactured by Toho ChemicalCo., Ltd.)______________________________________ 
    
     The above ingredients are homogeneously mixed to obtain an emulsifiable concentrate. 
     FORMULATION EXAMPLE 6: Flowable 
     
         ______________________________________Compound No. 2 of the present invention                      40 partsAgrizole B-710 (tradename for a nonionic                      10 partssurfactant, manufactured by Kao Corporation)Runox 1000C (tradename for an anionic                      0.5 partssurfactant, manufactured by Toho ChemicalCo., Ltd.)1% Rodopol water (tradename for a                      20 partsthickener, manufactured by Rhone-Poulenc)Water                      29.5 parts______________________________________ 
    
     The above ingredients are homogeneously mixed to form a flowable. 
     The compounds of the present invention are applicable not only to agricultural and horticultural fields such as upland fields, paddy fields and orchards, but also to non-agricultural fields such as athletic fields, vacant fields and railway sides for the control of various weeds. The dose in their application varies depending upon the application site, the season for application, the type of crop plants, etc. However, it is usually within a range of from 0.001 to 5 kg per hectare. 
     Now, the herbicidal activities of the compounds of the present invention will be described with respect to specific Test Examples. 
     TEST EXAMPLE 1: Test on the herbicidal effects in soil treatment 
     A plastic box having a length of 15 cm, a width of 22 cm and a depth of 6 cm was filled with a sterilized diluvium soil, and seeds Echinochloa crus-galli, Eleusine indica, Digitaria adscendens, Panicum dichotomiflorum, Abutilon theophrasti, Amaranthus lividus, Polygonum longisetum and Zea mays were sown, and tubers of Cyperus esculentus were further planted. The soil was covered thereon in the thickness of about 1.5 cm, and then a herbicide solution was applied onto the surface of the soil uniformly so that the active ingredient is distributed at a predetermined concentration. The herbicide solution was prepared by diluting the wettable powder, the emulsifiable concentrate, the liquid formulation or the flowable as described in the foregoing Formulation Examples with water and applied onto the entire soil surface by means of a small spray. Three weeks after the application of the herbicidal solution, the herbicidal effects against each weed were determined on the basis of the following standard ratings. The results thereby obtained are shown in Table 9. 
     Standard ratings 
     5: Growth control rate of more than 90% (almost completely withered) 
     4: Growth control rate of from 70 to 90% 
     3: Growth control rate of from 40 to 70% 
     2: Growth control rate of from 20 to 40% 
     1: Growth control rate of from 5 to 20% 
     0: Growth control rate of less than 5% (almost non-effective) 
     The above growth control rates were calculated by the following equation: 
     
         Growth control rate (%)=(1-T/N)×100 
    
     where 
     T: Weight of the weed grown above the soil surface of the treated area 
     N: Weight of the weed grown above the soil surface of the non-treated area 
     TEST EXAMPLE 2: Test on the herbicidal effects in foliage treatment 
     A plastic box having a length of 15 cm, a width of 22 cm and a depth of 6 cm was filled with a sterilized diluvium soil, and seeds of Echinochloa crus-galli, Eleusine indica, Digitaria adscendens, Panicum dichotomiflorum, Xanthium strumarium, Abutilon theophrasti, Amaranthus lividus, Polygonum longisetum and Zea mays were spot-wisely sown, and tubers of Cyperus esculentus were further planted. Then, the soil was covered thereon in a thickness of about 1.5 cm. When the various weeds and crops grew to the 2 or 3 leaf stage, a herbicidal solution was uniformly sprayed on the foliages so that the active ingredient is applied in a predetermined concentration. 
     The herbicidal solution was prepared by diluting the wettable powder, the emulsifiable concentrate, the liquid formulation or the flowable as described in the above Formulation Examples with water and applied onto the entire surface of the foliages of the weeds and the crop plants by a small spray. Two weeks after the application of the herbicide solution, the herbicidal effects against each weed were determined on the basis of the standard ratings described in Test Example 1, and the phytotoxicity against each crop plant was determined on the basis of the standard ratings in Test Example 1. The results are shown in Table 10. 
     In Tables 9 and 10, the following abbreviations are used: 
     Dose: Dose of active ingredient (g/are) 
     EC: Echinochloa crus-galli (barnyardgrass) 
     EL: Eleusine indica (goosegrass) 
     DI: Digitaria adscendens (large crabgrass) 
     PA: Panicum dichotomiflorum (fall panicum) 
     AB: Abutilon theophrasti (velvet leaf) 
     AM: Amaranthus lividus (livid amaranth) 
     PO: Polygonum longisetum (persicaria blumei gross) 
     XA: Xanthium strumarium (cocklebur) 
     CY: Cyperus esculentus (yellow nutsedge) 
     ZE: Zea mays (corn) 
     
                                           TABLE 9__________________________________________________________________________CompoundNo.    Dose     EC EL DI PA AB AM PO CY ZE__________________________________________________________________________1      0.5     5  5  5  5  5  5  5  5  0  1  5  5  5  5  5  5  5  5  0  2  5  5  5  5  5  5  5  5  02      0.5     5  5  5  5  5  5  5  5  0  1  5  5  5  5  5  5  5  5  0  2  5  5  5  5  5  5  5  5  0Reference  4  3  3  3  1  4  5  5  0  0Compound  8  4  4  4  2  5  5  5  0  0A      16 5  5  5  3  5  5  5  1  1Reference  4  5  5  5  5  1  1  1  2  0Compound  8  5  5  5  5  2  2  2  3  0B      16 5  5  5  5  3  3  3  4  1Reference  0.5     3  3  3  2  4  1  1  3  0Compound  1  4  4  4  3  5  2  2  4  0C      2  5  5  5  4  5  3  3  5  0__________________________________________________________________________ 
    
     
                                           TABLE 10__________________________________________________________________________CompoundNo.   Dose    EC EL DI            PA AB AM PO XA CY ZE__________________________________________________________________________1     0.5    5  5  5 5  5  5  5  5  5  0 1  5  5  5 5  5  5  5  5  5  0 2  5  5  5 5  5  5  5  5  5  02     0.5    5  5  5 5  5  5  5  5  5  0 1  5  5  5 5  5  5  5  5  5  0 2  5  5  5 5  5  5  5  5  5  0Reference 4  3  2  3 0  3  5  5  4  0  0Compound 8  4  3  4 1  5  5  5  5  0  1A     16 5  4  5 2  5  5  5  5  1  2Reference 4  4  3  4 3  0  2  2  0  1  0Compound 8  4  4  4 4  1  3  3  1  2  1B     16 5  5  5 5  2  4  4  2  3  2Reference 0.5    4  3  3 2  4  0  1  2  3  0Compound 1  5  4  4 3  5  1  2  3  4  0C     2  5  5  5 4  5  2  3  4  5  1__________________________________________________________________________ 
    
     In Tables 9 and 10, the Comparative Compounds are as follows: ##STR15##