Abstract:
A spectrometer system includes an optical assembly for collimating light, a micro-ring grating assembly having a plurality of coaxially-aligned ring gratings, an aperture device defining an aperture circumscribing a target focal point, and a photon detector. An electro-optical layer of the grating assembly may be electrically connected to an energy supply to change the refractive index of the electro-optical layer. Alternately, the gratings may be electrically connected to the energy supply and energized, e.g., with alternating voltages, to change the refractive index. A data recorder may record the predetermined spectral characteristic. A method of detecting a spectral characteristic of a predetermined wavelength of source light includes generating collimated light using an optical assembly, directing the collimated light onto the micro-ring grating assembly, and selectively energizing the micro-ring grating assembly to diffract the predetermined wavelength onto the target focal point, and detecting the spectral characteristic using a photon detector.

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
       [0001]    This application claims priority to and the benefit of U.S. Provisional Application 61/089,194 filed on Aug. 15, 2008, which is hereby incorporated by reference in its entirety. 
     
    
     ORIGIN OF THE INVENTION 
       [0002]    The invention described herein was made by employees of the United States Government and may be manufactured and used by or for the Government for governmental purposes without payment of any royalties thereon or therefor. 
       TECHNICAL FIELD 
       [0003]    The present invention relates generally to spectrometers, and in particular to a miniaturized spectrometer system having micro-scale ring gratings and an electro-optically-selectable wavelength. 
       BACKGROUND OF THE INVENTION 
       [0004]    Spectroscopy pertains to the study of the dispersion of light into its component wavelengths. By analyzing the absorption and dispersion of incident source light and other radiation by matter, scientists are able to study various properties of the matter such as temperature, mass, luminosity, composition, etc. Optical instruments known as spectrometers are used to measure and study such light dispersion. Spectrometers therefore play an essential role in the study and design of various scientific monitoring devices, for example multi-spectral imaging (MSI) systems, hyper-spectral imaging (HSI) systems, and the like. 
         [0005]    In a conventional spectrometer, incident light passes through a first linear opening or slit formed in a mirror or an optical lens. A beam of incident light passing through the first slit illuminates a prism or a linear grating device. The grating device may have a series of vertically-aligned gratings which diffract the incident light into its component colors, with each color corresponding to a particular band of wavelengths of the electromagnetic spectrum. 
         [0006]    Spectrometers may include multiple aperture slits, with the first slit positioned in front of the linear grating device to initially select light in a relatively narrow band of wavelengths. The linear grating device spreads this band at different wavelength-dependent angles. A second slit in another mirror or optical lens may be positioned to allow for the selective passage of a narrower band of the light beam from the linear grating device. The second slit may be used to direct selected wavelengths to a measurement device to determine a desired spectral characteristic. In this manner, a specific wavelength or set of wavelengths may be selected for detailed spectral analysis. However, the miniaturization of conventional spectrometers may sacrifice the available optical resolution of such devices, as resolution is largely dependent on the density of the number of gratings and the path length of the incident light. 
       SUMMARY OF THE INVENTION 
       [0007]    Accordingly, a miniature spectrometer system is provided herein that is optimized for spectral data collection from parallel light received from an optical device, e.g., a telescope, an optical fiber waveguide, or microscopic lens optics. The spectrometer uses a micro-ring grating assembly, an optical device for collimating source light, and a photon detector or other suitable spectral sensor. The spectrometer has a sub-millimeter or micro-scale footprint and configuration that may be particularly well suited for use in molecular spectroscopy applications. 
         [0008]    A quartz optical waveguide or other suitable waveguide guides collimated light to the micro-ring grating (μRG) assembly. Light guided into the μRG assembly is differentiated by diffraction through the micro-ring pattern of the μRG, and by an electro-optical layer positioned adjacent thereto. The refractive index of the electro-optical layer may be selectively varied by generating and applying a sufficient electric field thereto to select and diffract only predetermined wavelengths of the parallel light onto a sensory plane. 
         [0009]    In particular, the spectrometer system includes an optical assembly adapted for collimating light from a light source, a μRG assembly having a plurality of coaxially-aligned micro-ring gratings configured for diffracting a predetermined wavelength of the collimated light onto a target focal point, an aperture device, and a photon detector. The aperture device defines an aperture circumscribing the target focal point, and the photon detector detects intensity or another spectral characteristic of the predetermined wavelength. The μRG assembly may be selectively energized to select the predetermined wavelength(s). 
         [0010]    The μRG assembly may include the electro-optical layer noted above, with the electro-optical layer electrically connected to an energy supply and selectively energized thereby to change or “tune” the refractive index of the electro-optical layer as needed. Alternately, the coaxially-aligned ring gratings may be electrically connected to the energy supply and energized, e.g., with alternating or equal/opposite voltages, in order to tune the refractive index in a different manner. A data recorder in communication with the photon detector may be used for recording the intensity or other desired spectral characteristic. 
         [0011]    A method of detecting a spectral characteristic of a predetermined wavelength of source light includes generating collimated light using the optical assembly, directing the collimated light onto the μRG assembly, and selectively energizing the μRG assembly using an energy supply to thereby diffract the predetermined wavelength onto the target focal point. The method includes detecting the spectral characteristic using a photon detector or other suitable spectral detection device. 
         [0012]    The above features and advantages and other features and advantages of the present invention are readily apparent from the following detailed description of the best modes for carrying out the invention when taken in connection with the accompanying drawings. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0013]      FIG. 1A  is a schematic illustration of a positive micro-zone plate (MZP) having micro-ring gratings usable within a spectrometer system in accordance with the present invention; 
           [0014]      FIG. 1B  is a schematic illustration of an alternate negative MZP also usable with the spectrometer system of the present invention; 
           [0015]      FIG. 2  is schematic illustration of the micro-ring spectrometer system of the present invention; 
           [0016]      FIG. 3A  is a schematic illustration of a micro-ring grating assembly portion of the micro-ring spectrometer system of  FIG. 2 ; and 
           [0017]      FIG. 3B  is a schematic illustration of the micro-ring grating assembly of  FIG. 3A  according to another embodiment. 
       
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
       [0018]    Referring to the drawings wherein like reference numbers represent like components throughout the several figures, and beginning with  FIG. 1A , a positive micro-zone plate (MZP)  10  is provided that can be used within a parallel light micro spectrometer system  50  of the present invention, as shown in  FIG. 2  and discussed in detail hereinbelow. The structure of the MZP  10  may be fabricated as a series of concentric micro-ring gratings on a thin-film of glass or other suitable material. As will be understood by those of ordinary skill in the optical arts, the term “grating” refers to an optical element configured for diffracting incident light in a particular manner. Gratings have a regular pattern which splits and diffracts incident light into several beams of light each travelling in directions that depend upon the spacing or gap between adjacent gratings and the wavelength(s) of the incident light. 
         [0019]    The MZP  10  shown in  FIG. 1  includes a transparent center  12  that is circumscribed by a series of transparent rings  14 . The transparent rings  14  are separated by an interposed series of opaque rings  16 , with the transparent center  12  and each of the rings  14 ,  16  being coaxially-aligned and centered on an optical axis  11 . For clarity of illustration, the number of rings  14 ,  16  is kept at a minimum in  FIGS. 1A and 1B , with the actual number of rings used in the construction of the MZP  10  being dependent upon the particular design and intended use of the MZP  10 . 
         [0020]    Source light (arrows  13 ) is directed toward the micro-ring gratings of the MZP  10  from a light source  22  (see  FIG. 2 ), e.g., a naturally-existing light emitter, fluorescence, or emission spectra from excited molecules of target materials by an accompanying light-emitting diode (LED) or a diode laser. The source light (arrows  13 ) is then diffracted by the various rings  14 ,  16  of the MZP  10  into different wavelengths, with each wavelength directed toward a particular focal point P 1 , P 2 , P 3 , P 4 , or P 5 . That is, the particular focal point corresponds to particular wavelengths or frequencies of the source light (arrows  13 ). The transparent center  12  allows a constructive interference point at the farthest focal point, i.e., focal point P 1 . Additional constructive interference points are provided at focal points P 3  and P 5 . 
         [0021]    As is well understood in the art, wave propagation of light gives rise to the principals of constructive and destructive wave interference. The shape of the medium is determined during interference by the sum of the separate amplitudes of each wave as one wave passes through another. When the crest of one wave is superpositioned upon the crest of another, the waves constructively interfere. Constructive interference also occurs when the trough of one wave is superpositioned upon the trough of another. Conversely, destructive interference occurs when the crest of one wave is superpositioned upon the trough of another. During destructive interference, the positive amplitudes from one crest are added to the negative amplitudes from the other trough, with the result being a reduced amplitude or destructive wave interference. Such principles give rise to the different constructive/destructive focal points discussed above. 
         [0022]    Referring to  FIG. 1B , another type of MZP is the negative MZP  10 A, which has an opaque center  12 A at its optical center that is circumscribed by a series of opaque rings  16 A. The opaque rings  16 A are separated by a corresponding series of transparent rings  14 A, with the opaque center  12 A and each of the rings  14 A,  16 A being coaxially-aligned and centered on optical axis  11 . The gratings of MZP  10 A provide a destructive interference point at P 1 ′. The source light (arrows  13 ) is diffracted by the various gratings of the MZP  10 A, and is thereafter directed through an aperture  38  (see  FIG. 2 ) toward a focal point P 1 ′, P 2 ′, P 3 ′, P 4 ′, and P 5 ′, with the particular focal point corresponding to a band of wavelengths of the source light (arrows  13 ). The opaque center  12 A allows a constructive interference point at the farthest focal point, i.e., focal point P 1 ′. The focused photons are 180 degree out of phase with respect to the photons in  FIG. 1A . Additional destructive interference points are provided at focal points P 2 ′ and P 4 ′. 
         [0023]    As noted above, the MZP  10 ,  10 A may include micro-ring gratings that focus parallel photons of the source light (arrows  13 ) as shown in  FIGS. 2 ,  3 A, and  3 B into the different radial points according to their wavelengths. A photon detector (D)  18  may be placed at any of the focal points P 1 -P 5  or P 1 ′-P 5 ′, and may relay or transmit detected spectral information (arrow i s ) to a data recorder (R)  20  to provide a historical record facilitating spectral analysis. 
         [0024]    Zero-order direct photons from the source light (arrows  13 ) through the transparent center disk  12  of  FIG. 1A  may cause bright irregular spots at the concentric center of any image produced using a Secondary Electron Microscope (SEM). It takes an infinite number of micro-ring gratings to completely compensate for 0 th  order constant photons through the transparent center  12  of the positive MZP  10  shown in  FIG. 1A . This result is similar to the Fourier transform in which y=c (a constant) is approximated by the sum of infinite sine and cosine waves. However, a negative grating such as the MZP  10 A of  FIG. 1B  does not have a direct line-of-sight between the focal point and the light source, and therefore all converging light is from higher order photons without a 0 th  order photon. Therefore, the MZP  10 A of  FIG. 1B  may be particularly well suited for use as a micro-ring grating due to the opacity of its opaque center  12 A. 
         [0025]    Referring to  FIG. 2 , the parallel light micro spectrometer system  50  of the present invention includes an optical assembly  24 , a micro-ring grating (μRG) assembly  40 , a light-blocking aperture device  36 , and the photon detector (D)  18 . The aperture device  36  defines an aperture  38 , which may be circular in shape according to one embodiment, and which circumscribes a focal point P, i.e., one of the focal points P 1 -P 5  of  FIG. 1A  or P 1 ′-P 5 ′ of  FIG. 1B  as described above. The spectrometer system  50  may be placed in communication with data recorder  20 , which may be any device configured for recording the desired spectral information (arrow i s ) detected, measured, or otherwise determined by the photon detector  18 . 
         [0026]    Light source  22  may be a naturally-existing light emitter, fluorescence, or emission spectra from excited molecules of target materials by an accompanying light-emitting diode (LED) or diode laser. The light source  22  generates raw source light (arrows  13 A), which is transmitted to the optical assembly  24 . The optical assembly  24  includes front-end optics  26 , e.g., a series of collimating lenses or another suitable collimating device, and an optical waveguide  28 , e.g., a quartz element or other suitable waveguide. The optics  26  collimate the raw source light (arrows  13 A) into parallel photons of source light (arrows  13 ), and the waveguide  28  directs the collimated source light (arrows  13 ) to the various micro-ring gratings of the MZP  10 . 
         [0027]    Another possibility for distinguishing and identifying the target material is to use a sensing medium, e.g., nanocrystals or quantum dots undergoing quantum-confined discrete transition by excitation. The level of transition of quantum-dots is heavily influenced by the contact of surrounding materials. The light-emission pattern from quantum dots after contact with an unknown material is different from the emission pattern of uncontacted cases. The difference in emission spectra is the indication of foreign materials adhering to the quantum dots. 
         [0028]    The source light (arrows  13 ) is guided to the micro-ring gratings of the MZP  10  through a transparent substrate  30 . The light is then differentiated by diffraction through the micro-ring pattern of the gratings of MZP  10  and an electro-optical (E/O) medium or layer  32  positioned adjacent thereto, and/or at least partially between rings of the MZP  10 , with diffracted light (arrows  17 ) passing from the micro-ring gratings of the MZP  10  through a transparent electrode layer  33 , and to the aperture device  36 . 
         [0029]    Diffracted light (arrows  17 ) of a predetermined wavelength(s) is allowed to enter the aperture  38 , while the non-selected wavelength(s)(arrows  19 ) is reflected away by a light-blocking surface  42  of the aperture device  36 . The electrode layer  33  may be constructed of Indium Tin Oxide (ITO) or another suitable material providing a bias voltage for the E/O layer  32 . The E/O layer  32  in turn may be constructed of a material having a refractive index that is varied by application of an electrical field, e.g., liquid crystal, non-linear optical crystal, or electro-optical polymer to name just a few. 
         [0030]    Referring to  FIGS. 3A and 3B , an energy source  34  may be selectively connected to the μRG assembly  40  to select and diffract only certain wavelengths of light. In the configuration shown in  FIG. 3A , the energy source  34  may be electrically-connected to the E/O layer  32 . The E/O layer  32  may be selectively energized to vary its refractive index, as represented in  FIG. 3A  by the various refractive zones  35 . Calibrated wavelengths of light may be selected and diffracted onto a sensory plane, i.e., a plane containing the photon detector  18 , by changing the level of the voltage supplied by the energy supply  34 . 
         [0031]    Particularly, when the optical assembly  24  blocks zero-order direct light, the concentric micro-rings of the MZP  10  provide a better grating effect without background noise. Because the phase of the propagating light is changed by the refractive index of the E/O layer  32 , selected photons of a specific wavelength may be focused on an aperture  38  formed in or defined by the aperture device  36 . The aperture  38  directs light of a selected wavelength of diffracted light (arrows  17 ) to the photon detector  18 , e.g., a photo-diode or other suitable device, while as noted above with reference to  FIG. 2  photons having different or non-selected wavelengths are absorbed or scattered by the light-blocking surface  42  of the aperture device  36 . 
         [0032]    Referring to  FIG. 3B , in an alternate embodiment the energy source  34  may be used to apply different voltages to the micro-ring gratings of the MZP  10  to create different refractive zones  135  in the E/O layer  32 . For example, alternating voltages may be applied such that a strong electric field is confined between adjacent rings, e.g., one ring of the MZP  10  may be energized at a level of 5V, while the adjacent ring is energized at −5V, and so on. Different voltages on the ring gratings of the MZP  10  select the wavelengths of the photons that will be focused on aperture  38  (see  FIG. 2 ). 
         [0033]    While the best modes for carrying out the invention have been described in detail, those familiar with the art to which this invention relates will recognize various alternative designs and embodiments for practicing the invention within the scope of the appended claims.