Abstract:
The present invention relates to perfume systems, products comprising such systems and the use of same. Unfortunately current perfume systems do not always provide the desired sensory experience. Thus there is a need for one or more perfume systems that obviate the short comings of the current perfume technologies. The systems of the present invention meet the aforementioned need as they employ symbiotic combinations.

Description:
CROSS-REFERENCES TO RELATED APPLICATIONS 
       [0001]    This application claims priority under 35 U.S.C. §119(e) to U.S. Provisional Application Ser. No. 60/900,591 filed Feb. 9, 2007. 
     
    
     BACKGROUND OF THE INVENTION 
       [0002]    Products such as consumer products are typically designed and/or formulated to include a perfume system. The consumer who selects and uses such a product typically experiences at least three product moments of truth. The first moment of truth is typically at the point of purchase, the second moment of truth typically begins with the product&#39;s application and use, and the third moment of truth typically begins immediately after the product&#39;s application and use. Unfortunately current perfume systems do not provide the desired sensory experience during such moments of truth; as such systems do not provide the perfume level and balance at all three of such moments—especially the first moment of truth—that is desired. Furthermore, current perfume systems do not offer the economics and formulation flexibility that is desired. Thus there is a need for one or more perfume systems that obviate the short comings of the current perfume technologies. The systems of the present invention meet the aforementioned need. 
       SUMMARY OF THE INVENTION 
       [0003]    The present invention relates to perfume systems, products comprising such systems and the use of same. 
     
    
     DETAILED DESCRIPTION OF THE INVENTION 
     Definitions 
       [0004]    As used herein “FMOT” means first moment of truth. 
         [0005]    As used herein “SMOT” means second moment of truth. 
         [0006]    As used herein “TMOT” means third moment of truth. 
         [0007]    As used herein “PRM” means perfume raw material. 
         [0008]    As used herein “perfume system” encompasses a single perfume technology and combinations of perfume technologies. 
         [0009]    As used herein “consumer products” includes, unless otherwise indicated, articles, baby care, beauty care, fabric &amp; home care, family care, feminine care, health care, snack and/or beverage products or devices intended to be used or consumed in the form in which it is sold, and is not intended for subsequent commercial manufacture or modification. Such products include but are not limited to diapers, bibs, wipes; products for and/or methods relating to treating hair (human, dog, and/or cat), including bleaching, coloring, dyeing, conditioning, shampooing, styling; deodorants and antiperspirants; personal cleansing products, including cleansers, moisturizing cleansers, and combinations thereof; cosmetics; skin care including application of creams, lotions, mousses, masks, exfoliating compositions, peels, and combinations thereof; hair removal products, including device-assisted hair removal products; shaving products; and other topically applied products for consumer use; products for and/or methods relating to treating fabrics, hard surfaces and any other surfaces in the area of fabric and home care, including: air care, car care, dishwashing, fabric conditioning (including softening), laundry detergency, laundry and rinse additive and/or care, hard surface cleaning and/or treatment, and other cleaning for consumer or institutional use; products and/or methods relating to bath tissue, facial tissue, paper handkerchiefs, and/or paper towels; tampons, feminine napkins; products and/or methods relating to oral care including toothpastes, tooth gels, tooth rinses, denture adhesives, tooth whitening; over-the-counter health care including cough and cold remedies, pain relievers, pet health and nutrition, and water purification; processed food products intended primarily for consumption between customary meals or as a meal accompaniment (non-limiting examples include potato chips, tortilla chips, popcorn, pretzels, corn chips, cereal bars, vegetable chips or crisps, snack mixes, party mixes, multigrain chips, snack crackers, cheese snacks, pork rinds, corn snacks, pellet snacks, extruded snacks and bagel chips); and coffee and cleaning and/or treatment compositions. 
         [0010]    As used herein, the term “cleaning and/or treatment composition” includes, unless otherwise indicated, tablet, granular or powder-form all-purpose or “heavy-duty” washing agents, especially cleaning detergents; liquid, gel or paste-form all-purpose washing agents, especially the so-called heavy-duty liquid types; liquid fine-fabric detergents; hand dishwashing agents or light duty dishwashing agents, especially those of the high-foaming type; machine dishwashing agents, including the various tablet, granular, liquid and rinse-aid types for household and institutional use; liquid cleaning and disinfecting agents, including antibacterial hand-wash types, cleaning bars, mouthwashes, denture cleaners, car or carpet shampoos, bathroom cleaners; hair shampoos and hair-rinses; shower gels and foam baths and metal cleaners; as well as cleaning auxiliaries such as bleach additives and “stain-stick” or pre-treat types substrate-laden products such as dryer added sheets, dry and wetted wipes and pads, nonwoven substrates, and sponges; as well as sprays and mists. 
         [0011]    As used herein, the term “fabric care composition” includes, unless otherwise indicated, fabric softening compositions, fabric enhancing compositions, fabric freshening compositions and combinations thereof. 
         [0012]    As used herein, the term “solid” includes granular, powder, bar and tablet product forms. 
         [0013]    As used herein, the term “situs” includes paper products, fabrics, garments, hard surfaces, hair and skin. 
         [0014]    As used herein, the articles “a”, “an” and “the” when used in a claim, are understood to mean one or more of what is claimed or described. 
         [0015]    As used herein, the terms “include”, “includes” and “including” are meant to be non-limiting. 
         [0016]    Unless otherwise noted, all component or composition levels are in reference to the active level of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources. 
         [0017]    All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total packaged product, which includes the product and product matrix composition unless otherwise indicated. 
         [0018]    It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein. 
       Consumer Product 
       [0019]    The consumer who selects and uses a perfumed product makes critical decisions as to how satisfied he or she is with the product at multiple touch points in the product usage profile. Although numerous touch points are known, three product moments of truth are typically experienced by the consumer. The FMOT is typically at the point of purchase, the SMOT typically begins with the product&#39;s application and use, and the TMOT typically begins immediately after the product&#39;s application and use. Applicants have recognized that a consumer&#39;s FMOT is negatively impacted because the product packaging inhibits the sensory experience; for example, product packaging may make the product difficult to open or, when open, exposes a product that can spill. In addition, formulation ingredients can suppress and/or distort neat product odor. Furthermore Applicants have recognized that the consumer&#39;s SMOT is negatively impacted as volatile and high impact PRMs are lost during product storage, resulting in lack of bloom during use, where perfume bloom may occur initially upon product use, but does not last throughout the use experience. Compensating for these aforementioned deficiencies by adding high perfume levels for the TMOT can distort in-use scent experience, such that the perfume bloom can be too harsh or strong, and/or the perfume character can become less preferred. Also, Applicants have recognized that a consumer&#39;s FMOT was negatively impacted as perfume release from the treated situs, inter alia a dry fabric, over long period of time requires perfume levels in product that would distort the scent experience during the first and second moments of truth. Furthermore, addition of high perfume levels for SMOT &amp; TMOT can distort neat product odor, and still not result in sufficient perfume deposition through the wash. In addition, perfume evaporation that occurs during drying can result in lower perfume levels on fabric; and/or the perfume remaining on dry fabric may provide initial dry fabric odor benefit but such perfume can dissipate too quickly to provide sufficient scent longevity benefits. Finally, Applicants recognized that solutions to the problems that are associated with one or two moments of truth can be insufficient to resolve the problems associated with the remaining moment(s) of truth or negatively impact the other moment(s) of truth. Thus, what is needed is a consumer product comprising a designed neat perfume and a perfume delivery system. 
         [0020]    In one aspect, a consumer product comprising:
       a.) from about 0.01% to about 20%, from about 0.03% to about 15%, from about 0.05% to about 10%, or from about 0.1% to about 5% of a neat perfume comprising, based on weight of said neat perfume:
           (i) from about 1% to about 30%, from about 2% to about 20%, from about 3% to about 15%, or from about 4% to about 10% of a perfume raw material having a boiling point less than or equal to 250° C. and a ClogP less than or equal to 2.5;   (ii) from about 5% to about 70%, from about 10% to about 60%, from about 15% to about 50%, or from about 20% to about 40% of a perfume raw material having boiling point less than or equal to 250° C. and a ClogP greater than 2.5;   (iii) from about 1% to about 30%, from about 2% to about 20%, from about 3% to about 15%, or from about 4% to about 10% of a perfume raw material having boiling point greater than 250° C. but less than or equal to 280° C.; and   
           b.) from about 0.01% to about 20%, from about 0.03% to about 15%, from about 0.5% to about 10%, or from about 0.1% to about 5% of a perfume delivery system; and   c.) the balance of said consumer product being a consumer product ingredient is disclosed.       
 
         [0027]    In one aspect, when the perfume delivery system comprises a perfume microcapsule such microcapsule may comprise, based on total perfume microcapsule weight, from about 50% to about 95%, from about 60% to about 90%, from about 75% to about 85% perfume, at least 50%, 75%, 85% or even 100% said perfume being a perfume raw material having a ClogP greater than or equal to 1 and a boiling point less than or equal to 350° C.; a ClogP greater than or equal to 1.5 and a boiling point less than or equal to 300° C.; or even a ClogP greater than or equal to 2 and a boiling point less than or equal to 280° C. 
         [0028]    In one aspect, when the perfume delivery system comprises a microcapsule, and an amine assisted delivery system, the neat perfume comprises:
       (i) from about 2% to about 40%, from about 4% to about 30%, or from about 8% to about 20% of a perfume raw material having a boiling point less than or equal to 250° C. and a ClogP less than or equal to 2.5;   (ii) from about 4% to about 60%, from about 7% to about 50%, from about 10% to about 40%, or from about 15% to about 30% of a perfume raw material having boiling point less than or equal to 250° C. and a ClogP greater than 2.5; and   (iii) from about 1% to about 20%, from about 1% to about 15%, from about 2% to about 10%, or from about 3% to about 6% of a perfume raw material having boiling point greater than 250° C. but less than or equal to 280° C.       
 
         [0032]    In one aspect, said amine assisted delivery system comprises a polyalkylamine. 
         [0033]    In one aspect, said polyakylamine comprises a polyethyleneamine. 
         [0034]    In one aspect, said polyethylenamine has a weight average molecular weight in daltons, as determined by dynamic light scattering (DLS) using a Malvern Zetasizer Nano-ZS, supplied by Malvern Instruments Ltd Enigma Business Park, Grovewood Road Malvern Worcestershire WR14 1XZ United Kingdom, of from about 500 to about 5,000,000, from about 1000 to about 1,000,000, or from about 7,000 to about 200,000. 
         [0035]    In one aspect, when the consumer product is a packaged product that comprises a neat perfume, a perfume microcapsule, and a perfume delivery system that comprises a polymer assisted delivery matrix system comprising a perfume comprising:
       (i) from 0% to 100%, from about 1% to about 30%, from about 2% to about 20%, from about 3% to about 15%, or from about 4% to about 10% of a perfume raw material having a boiling point less than or equal to 250° C. and a ClogP less than or equal to 2.5;   (ii) from 0% to 100%, from about 5% to about 70%, from about 10% to about 60%, from about 15% to about 50%, or from about 20% to about 40% of a perfume raw material having boiling point less than or equal to 250° C. and a ClogP greater than 2.5; and   (iii) from about 0% to about 100%, from about 1% to about 30%, from about 2% to about 20%, from about 3% to about 15%, or from about 4% to about 10% of a perfume raw material having boiling point greater than 250° C. but less than or equal to 280° C.;
 
said neat perfume comprises:
   (i) from about 1% to about 30%, from about 2% to about 20%, from about 3% to about 15%, or from about 4% to about 10% of a perfume raw material having a boiling point less than or equal to 250° C. and a ClogP less than or equal to 2.5;   (ii) from about 10% to about 90%, from about 15% to about 80%, from about 20% to about 70%, or from about 25% to about 60% of a perfume raw material having boiling point less than or equal to 250° C. and a ClogP greater than 2.5; and   (iii) from about 1% to about 30%, from about 2% to about 20%, from about 3% to about 15%, or from about 4% to about 10% of a perfume raw material having boiling point greater than 250° C. but less than or equal to 280° C.       
 
         [0042]    In one aspect, said polymer assisted delivery matrix system is in either in whole or in part, (for example, adhered to) in communication with the packaged product&#39;s packaging and/or the exterior of the packaged product&#39;s container, for example any cap that may cap or be attached to said container. In one aspect, said polymer assisted delivery matrix system is either in whole or in part in communication with the underside of the aforementioned cap. 
         [0043]    In one aspect, when the consumer product is a packaged product that comprises a neat perfume, a perfume microcapsule, an amine assisted delivery system and a perfume delivery system that comprises a polymer assisted delivery matrix system said neat perfume comprises:
       (i) from about 2% to about 40%, from about 4% to about 30%, or from about 8% to about 20% of a perfume raw material having a boiling point less than or equal to 250° C. and a ClogP less than or equal to 2.5;   (ii) from about 4% to about 60%, from about 7% to about 50%, from about 10% to about 40%, or from about 15% to about 30% of a perfume raw material having boiling point less than or equal to 250° C. and a ClogP greater than 2.5; and   (iv) from about 1% to about 20%, from about 1% to about 15%, from about 2% to about 10%, or from about 3% to about 6% of a perfume raw material having boiling point greater than 250° C. but less than or equal to 280° C.       
 
         [0047]    In one aspect, suitable perfume raw materials having a boiling point less than or equal to 250° C. and a ClogP less than or equal to 2.5 are those materials listed in Table 1 below and such materials are defined as Table 1 perfume raw materials. 
         [0000]    
       
         
               
               
               
             
               
               
               
             
           
               
                 TABLE 1 
               
               
                   
               
               
                 Number 
                 Registry Name 
                 Trade Name 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 1 
                 Propanoic acid, ethyl ester 
                 Ethyl Propionate 
               
               
                 2 
                 Acetic acid, 2-methylpropyl ester 
                 Isobutyl Acetate 
               
               
                 3 
                 Butanoic acid, ethyl ester 
                 Ethyl Butyrate 
               
               
                 4 
                 Butanoic acid, 2-methyl-, ethyl ester 
                 Ethyl-2-Methyl Butyrate 
               
               
                 5 
                 2-Hexenal, (E)- 
                 2-Hexenal 
               
               
                 6 
                 1-Butanol, 3-methyl-, acetate 
                 Iso Amyl-Acetate 
               
               
                 7 
                 2-Buten-1-ol, 3-methyl-, acetate 
                 Prenyl Acetate 
               
               
                 8 
                 2-Hexen-1-ol 
                 Beta Gamma Hexenol 
               
               
                 9 
                 3-Hexen-1-ol 
                 Beta Gamma Hexenol 
               
               
                 10 
                 Benzaldehyde 
                 Benzaldehyde 
               
               
                 11 
                 3-Hexen-1-ol, acetate, (Z)- 
                 Cis 3 Hexenyl Acetate 
               
               
                 12 
                 Benzoic acid, methyl ester 
                 Methyl Benzoate 
               
               
                 13 
                 Benzeneacetaldehyde 
                 Phenyl Acetaldehyde 
               
               
                 14 
                 Benzeneacetic acid, methyl ester 
                 Methyl Phenyl Acetate 
               
               
                 15 
                 1,3-Dioxolane-2-acetic acid, 2-methyl-, ethyl 
                 Fructone 
               
               
                   
                 ester 
               
               
                 16 
                 Benzeneacetaldehyde, .alpha.-methyl- 
                 Hydratropic Aldehyde 
               
               
                 17 
                 3-Cyclohexene-1-carboxaldehyde, 3,5- 
                 Cyclal C, 
               
               
                   
                 dimethyl- 
               
               
                 18 
                 Acetic acid, (2-methylbutoxy)-, 2-propenyl ester 
                 Allyl Amyl Glycolate 
               
               
                 19 
                 Benzenemethanol, .alpha.-methyl-, acetate 
                 Methyl Phenyl Carbinyl Acetate 
               
               
                 20 
                 Acetic acid, (3-methylbutoxy)-, 2-propenyl ester 
                 Allyl Amyl Glycolate 
               
               
                 21 
                 Benzaldehyde, 4-methoxy- 
                 Anisic Aldehyde 
               
               
                 22 
                 Benzeneacetic acid, ethyl ester 
                 Ethyl Phenyl Acetate 
               
               
                 23 
                 2-Cyclohexen-1-one, 2-methyl-5-(1- 
                 Laevo Carvone 
               
               
                   
                 methylethenyl)-, (R)- 
               
               
                 24 
                 Ethanol, 2,2′-oxybis- 
                 Calone 161 
               
               
                 25 
                 Acetic acid, 2-phenylethyl ester 
                 Phenyl Ethyl Acetate 
               
               
                 26 
                 Benzoic acid, 2-amino-, methyl ester 
                 Methyl Anthranilate 
               
               
                 27 
                 4,7-Methano-1H-inden-6-ol, 3a,4,5,6,7,7a- 
                 Flor Acetate 
               
               
                   
                 hexahydro-, acetate 
               
               
                 28 
                 Octanal, 7-hydroxy-3,7-dimethyl- 
                 Hydroxycitronellal 
               
               
                 29 
                 2(3H)-Furanone, 5-ethyldihydro- 
                 Gamma Hexalactone 
               
               
                 30 
                 Phenol, 4-methyl- 
                 Para Cresol 
               
               
                 31 
                 Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, 
                 Camphor Gum 
               
               
                   
                 (1R)- 
               
               
                 32 
                 2H-Pyran, 3,6-dihydro-4-methyl-2-(2-methyl-1- 
                 Nerol Oxide 
               
               
                   
                 propenyl)- 
               
               
                 33 
                 Benzeneethanol, .beta.-methyl- 
                 Hydratropic Alcohol 
               
               
                 34 
                 Benzeneethanol, .alpha.,.alpha.-dimethyl- 
                 Dimethyl Benzyl Carbinol 
               
               
                 35 
                 Benzoic acid, 2-(methylamino)-, methyl ester 
                 Dimethyl Anthranilate 
               
               
                 36 
                 2-Propenal, 3-phenyl- 
                 Cinnamic Aldehyde 
               
               
                 37 
                 2-Propenoic acid, 3-phenyl-, methyl ester 
                 Methyl Cinnamate 
               
               
                 38 
                 4H-Pyran-4-one, 2-ethyl-3-hydroxy- 
                 Ethyl Maltol 
               
               
                 39 
                 Acetic acid ethyl ester 
                 Ethyl Acetate 
               
               
                 40 
                 2-Heptanone 
                 Methyl Amyl Ketone 
               
               
                 41 
                 Acetic acid, pentyl ester 
                 Iso Amyl-Acetate 
               
               
                 42 
                 3-Octanone 
                 Ethyl Amyl Ketone 
               
               
                 43 
                 2-Octanone 
                 Methyl Hexyl Ketone 
               
               
                 44 
                 Heptenone, methyl- 
                 Methyl Heptenone 
               
               
                 45 
                 1-Heptanol 
                 Heptyl Alcohol 
               
               
                 46 
                 5-Hepten-2-one, 6-methyl- 
                 Methyl Heptenone 
               
               
                 47 
                 Butanoic acid, 3-oxo-, ethyl ester 
                 Ethyl Acetoacetate 
               
               
                 48 
                 Ethanol, 2-(2-methoxyethoxy)- 
                 Veramoss Sps 
               
               
                 49 
                 Tricyclo[2.2.1.02,6]heptane, 1-ethyl-3- 
                 Neoproxen 
               
               
                   
                 methoxy- 
               
               
                 50 
                 Benzene, 1,4-dimethoxy- 
                 Hydroquinone Dimethyl Ether 
               
               
                 51 
                 Carbonic acid, 3-hexenyl methyl ester, (Z)- 
                 Liffarome 
               
               
                 52 
                 Oxirane, 2,2-dimethyl-3-(3-methyl-2,4- 
                 Myroxide 
               
               
                   
                 pentadienyl)- 
               
               
                 53 
                 Ethanol, 2-(2-ethoxyethoxy)- 
                 Diethylene Glycol Mono 
               
               
                   
                   
                 Ethylether 
               
               
                 54 
                 Cyclohexaneethanol 
                 Cyclohexyl Ethyl Alcohol 
               
               
                 55 
                 3-Octen-1-ol, (Z)- 
                 Octenol Dix 
               
               
                 56 
                 3-Cyclohexene-1-carboxaldehyde, 3,6- 
                 Cyclovertal 
               
               
                   
                 dimethyl- 
               
               
                 57 
                 1,3-Oxathiane, 2-methyl-4-propyl-, cis- 
                 Oxane 
               
               
                 58 
                 Acetic acid, 4-methylphenyl ester 
                 Para Cresyl Acetate 
               
               
                 59 
                 Benzene, (2,2-dimethoxyethyl)- 
                 Phenyl Acetaldehyde Dimethyl 
               
               
                   
                   
                 Acetal 
               
               
                 60 
                 Ethanone, 1-(4-methylphenyl)- 
                 Para Methyl Acetophenone 
               
               
                 61 
                 Propanoic acid, phenylmethyl ester 
                 Benzyl Propionate 
               
               
                 62 
                 Octanal, 7-methoxy-3,7-dimethyl- 
                 Methoxycitronellal Pq 
               
               
                 63 
                 Linalool oxide 
                 Linalool Oxide 
               
               
                 64 
                 2H-1-Benzopyran-2-one, octahydro- 
                 Octahydro Coumarin 
               
               
                 65 
                 Benzenepropanal, .beta.-methyl- 
                 Trifernal 
               
               
                 66 
                 4,7-Methano-1H-indenecarboxaldehyde, 
                 Formyltricyclodecan 
               
               
                   
                 octahydro- 
               
               
                 67 
                 2-Butanone, 4-phenyl- 
                 Benzyl Acetone 
               
               
                 68 
                 Ethanone, 1-(4-methoxyphenyl)- 
                 Para Methoxy Acetophenone 
               
               
                 69 
                 Benzoic acid, 2-hydroxy-, methyl ester 
                 Methyl Salicylate USP 
               
               
                 70 
                 Propanenitrile, 3-(3-hexenyloxy)-, (Z)- 
                 Parmanyl 
               
               
                 71 
                 1,4-Methanonaphthalen-5(1H)-one, 
                 Tamisone 
               
               
                   
                 4,4a,6,7,8,8a-hexahydro- 
               
               
                 72 
                 Benzene, [2-(2-propenyloxy)ethyl]- 
                 LRA 220 
               
               
                 73 
                 Benzenepropanol 
                 Phenyl Propyl Alcohol 
               
               
                 74 
                 Ethanol, 2-phenoxy- 
                 Phenoxyethanol 
               
               
                 75 
                 1H-Indole 
                 Indole 
               
               
                 76 
                 1,3-Dioxolane, 2-(phenylmethyl)- 
                 Ethylene Glycol Acetal/Phenyl 
               
               
                   
                   
                 Acetaldehy 
               
               
                 77 
                 2H-1-Benzopyran-2-one, 3,4-dihydro- 
                 Dihydrocoumarin 
               
               
                   
               
             
          
         
       
     
         [0048]    In one aspect, suitable Table 1 perfume raw materials include perfume raw materials from number 1 to number 39 and mixtures thereof. 
         [0049]    In one aspect, suitable Table 1 perfume raw materials include perfume raw materials from number 1 to number 29 and mixtures thereof. 
         [0050]    In one aspect, suitable perfume raw materials having boiling point less than or equal to 250° C. and a ClogP greater than 2.5 are those materials listed in Table 2 below and such materials are defined as Table 2 perfume raw materials. 
         [0000]    
       
         
               
               
               
             
               
               
               
             
           
               
                 TABLE 2 
               
               
                   
               
               
                 Number 
                 Registry Name 
                 Trade Name 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 1 
                 Bicyclo[2.2.1]heptane, 2,2-dimethyl-3- 
                 Camphene 
               
               
                   
                 methylene- 
               
               
                 2 
                 Bicyclo[3.1.1]heptane, 6,6-dimethyl-2- 
                 Beta Pinene 
               
               
                   
                 methylene-, (1S)- 
               
               
                 3 
                 Bicyclo[3.1.1]hept-2-ene, 2,6,6- 
                 Alpha Pinene 
               
               
                   
                 trimethyl- 
               
               
                 4 
                 Propanoic acid, pentyl ester 
                 Amyl Propionate 
               
               
                 5 
                 1,6-Octadiene, 7-methyl-3-methylene- 
                 Myrcene 
               
               
                 6 
                 Cyclohexene, 1-methyl-4-(1- 
                 Dipentene 
               
               
                   
                 methylethenyl)- 
               
               
                 7 
                 Cyclohexene, 1-methyl-4-(1- 
                 Terpineolene 
               
               
                   
                 methylethenyl)- 
               
               
                 8 
                 Acetic acid, hexyl ester 
                 Hexyl Acetate 
               
               
                 9 
                 Cyclohexene, 1-methyl-4-(1- 
                 Terpineolene 
               
               
                   
                 methylethylidene)- 
               
               
                 10 
                 Benzene, 1-methoxy-4-methyl- 
                 Para Cresyl Methyl Ether 
               
               
                 11 
                 1-Octen-3-ol, acetate 
                 Amyl Vinyl Carbinyl Acetate 
               
               
                 12 
                 Octanal 
                 Octyl Aldehyde 
               
               
                 13 
                 2-Oxabicyclo[2.2.2]octane, 1,3,3- 
                 Eucalyptol 
               
               
                   
                 trimethyl- 
               
               
                 14 
                 Butanoic acid, pentyl ester 
                 Amyl Butyrate 
               
               
                 15 
                 Heptanoic acid, ethyl ester 
                 Ethyl Oenanthate 
               
               
                 16 
                 5-Heptenal, 2,6-dimethyl- 
                 Melonal 
               
               
                 17 
                 Hexanoic acid, 2-propenyl ester 
                 Allyl Caproate 
               
               
                 18 
                 3-Cyclohexene-1-carboxaldehyde, 
                 Ligustral 
               
               
                   
                 dimethyl- 
               
               
                 19 
                 3-Hexene, 1-(1-ethoxyethoxy)-, (Z)- 
                 Leaf Acetal 
               
               
                 20 
                 Octanal, 3,7-dimethyl- 
                 Dihydrocitronellal 
               
               
                 21 
                 2-Octynoic acid, methyl ester 
                 Methyl Heptine Carbonate 
               
               
                 22 
                 2-Nonenal 
                 2 Nonen-1-Al 
               
               
                 23 
                 1,6-Octadien-3-ol, 3,7-dimethyl- 
                 Linalool 
               
               
                 24 
                 Benzoic acid, ethyl ester 
                 Ethyl Benzoate 
               
               
                 25 
                 6-Octenal, 3,7-dimethyl- 
                 Citronellal 
               
               
                 26 
                 Cyclohexanol, 1-methyl-4-(1- 
                 Dihydroterpineol 
               
               
                   
                 methylethyl)- 
               
               
                 27 
                 1-Hexanol, 3,5,5-trimethyl-, acetate 
                 Iso Nonyl Acetate 
               
               
                 28 
                 3,5-Octadien-2-ol, 2,6-dimethyl-, (?,Z)- 
                 Muguol 
               
               
                 29 
                 Cyclohexanone, 5-methyl-2-(1- 
                 Iso Menthone 
               
               
                   
                 methylethyl)-, cis- 
               
               
                 30 
                 Heptanoic acid, 2-propenyl ester 
                 Allyl Heptoate 
               
               
                 31 
                 Butanoic acid, 3-hexenyl ester, (Z)- 
                 Cis 3 Hexenyl Butyrate 
               
               
                 32 
                 1,6-Octadien-3-ol, 3,7-dimethyl-, 
                 Linalyl Formate 
               
               
                   
                 formate 
               
               
                 33 
                 3-Cyclohexen-1-ol, 4-methyl-1-(1- 
                 Terpinenol 
               
               
                   
                 methylethyl)- 
               
               
                 34 
                 Bicyclo[2.2.1]heptan-2-ol, 1,3,3- 
                 Fenchyl Alcohol 
               
               
                   
                 trimethyl- 
               
               
                 35 
                 Cyclohexanol, 2-(1,1-dimethylethyl)-, 
                 Verdol 
               
               
                   
                 cis- 
               
               
                 36 
                 3-Octanol, 3,7-dimethyl-, acetate 
                 Tetrahydro Linayl Acetate 
               
               
                 37 
                 Bicyclo[2.2.1]heptan-2-ol, 1,7,7- 
                 Borneol Crystals 
               
               
                   
                 trimethyl-, (1S-endo)- 
               
               
                 38 
                 Decanal 
                 Decyl Aldehyde 
               
               
                 39 
                 3-Cyclohexene-1-methanol, 
                 Alpha Terpineol 
               
               
                   
                 .alpha.,.alpha.,4-trimethyl- 
               
               
                 40 
                 Cyclohexanol, 5-methyl-2-(1- 
                 Menthol 
               
               
                   
                 methylethyl)- 
               
               
                 41 
                 3-Cyclohexene-1-carboxaldehyde, 
                 Iso Cyclo Citral 
               
               
                   
                 2,4,6-trimethyl- 
               
               
                 42 
                 7-Octen-2-ol, 2,6-dimethyl-, acetate 
                 Dihydro Terpinyl Acetate 
               
               
                 43 
                 2H-Pyran-2-one, 6-butyltetrahydro- 
                 Nonalactone 
               
               
                 44 
                 3-Hepten-2-one, 3,4,5,6,6-pentamethyl- 
                 Koavone 
               
               
                 45 
                 1,6-Nonadien-3-ol, 3,7-dimethyl- 
                 Ethyl Linalool 
               
               
                 46 
                 4-Decenal, (E)- 
                 Decenal (Trans-4) 
               
               
                 47 
                 Terpineol 
                 Terpineol 
               
               
                 48 
                 7-Octen-2-ol, 2-methyl-6-methylene-, 
                 Myrcenyl Acetate 
               
               
                   
                 acetate 
               
               
                 49 
                 2-Butenoic acid, 2-methyl-, 3-hexenyl 
                 Cis-3-Hexenyl Tiglate 
               
               
                   
                 ester, (E,Z)- 
               
               
                 50 
                 1,6-Octadien-3-ol, 3,7-dimethyl-, 
                 Linalyl Acetate 
               
               
                   
                 acetate 
               
               
                 51 
                 Benzene, 1-methoxy-4-(1-propenyl)-, 
                 Anethol Usp 
               
               
                   
                 (E)- 
               
               
                 52 
                 2-Decenal 
                 2 Decene-1-Al 
               
               
                 53 
                 2,6-Octadienal, 3,7-dimethyl- 
                 Citral 
               
               
                 54 
                 6-Octen-1-ol, 3,7-dimethyl-, formate 
                 Citronellyl Formate 
               
               
                 55 
                 Cyclopentanone, 3-methyl-2-pentyl- 
                 Jasmylone 
               
               
                 56 
                 Undecenal 
                 Iso C-11 Aldehyde 
               
               
                 57 
                 6-Octen-1-ol, 3,7-dimethyl- 
                 Citronellol 
               
               
                 58 
                 Cyclohexanemethanol, 
                 Dihydro Terpinyl Acetate 
               
               
                   
                 .alpha.,.alpha.,4-trimethyl-, acetate 
               
               
                 59 
                 3-Cyclohexene-1-methanol, 
                 Terpinyl Acetate 
               
               
                   
                 .alpha.,.alpha.,4-trimethyl-, acetate 
               
               
                 60 
                 2,6-Octadien-1-ol, 3,7-dimethyl-, 
                 Geranyl Formate 
               
               
                   
                 formate, (E)- 
               
               
                 61 
                 Bicyclo[2.2.1]heptan-2-ol, 1,3,3- 
                 Fenchyl Acetate 
               
               
                   
                 trimethyl-, acetate 
               
               
                 62 
                 Bicyclo[2.2.1]heptan-2-ol, 1,7,7- 
                 Iso Bornyl Acetate 
               
               
                   
                 trimethyl-, acetate, exo- 
               
               
                 63 
                 2,6-Octadien-1-ol, 3,7-dimethyl-, (E)- 
                 Geraniol 
               
               
                 64 
                 2,6-Octadien-1-ol, 3,7-dimethyl-, (Z)- 
                 Nerol 
               
               
                 65 
                 Cyclohexanol, 2-(1,1-dimethylethyl)-, 
                 Verdox 
               
               
                   
                 acetate 
               
               
                 66 
                 Undecanal, 2-methyl- 
                 Methyl Nonyl Acetaldehyde 
               
               
                 67 
                 Undecanal 
                 Undecyl Aldehyde 
               
               
                 68 
                 2H-Pyran-2-one, tetrahydro-6-pentyl- 
                 Delta Decalactone 
               
               
                 69 
                 6-Octen-1-ol, 3,7-dimethyl-, acetate 
                 Citronellyl Acetate 
               
               
                 70 
                 10-Undecenal 
                 Intreleven Aldehyde Sp 
               
               
                 71 
                 2(3H)-Furanone, 5-hexyldihydro- 
                 Gamma Decalactone 
               
               
                 72 
                 2,6-Octadien-1-ol, 3,7-dimethyl-, 
                 Geranyl Acetate 
               
               
                   
                 acetate, (E)- 
               
               
                 73 
                 2H-Pyran-2-one, tetrahydro-6-(3- 
                 Jasmolactone 
               
               
                   
                 pentenyl)- 
               
               
                 74 
                 Cyclohexanol, 5-methyl-2-(1- 
                 Menthyl Acetate 
               
               
                   
                 methylethyl)-, 
               
               
                   
                 acetate, (1.alpha.,2.beta.,5.alpha.)- 
               
               
                 75 
                 2-Undecenal 
                 2-Undecene-1-Al 
               
               
                 76 
                 2H-Pyran-2-one, tetrahydro-6-(2- 
                 Jasmolactone 
               
               
                   
                 pentenyl)-, (Z)- 
               
               
                 77 
                 2,6-Octadien-1-ol, 3,7-dimethyl-, 
                 Neryl Acetate 
               
               
                   
                 acetate, (Z)- 
               
               
                 78 
                 Benzeneethanol, .alpha.,.alpha.- 
                 Dimethyl Benzyl Carbinyl Acetate 
               
               
                   
                 dimethyl-, acetate 
               
               
                 79 
                 4,9-Decadienal, 4,8-dimethyl- 
                 Floral Super 
               
               
                 80 
                 3-Octanol 
                 Octanol-3 
               
               
                 81 
                 2-Heptanol, 2,6-dimethyl- 
                 Dimethyl-2, 6-Heptan-2-Ol 
               
               
                 82 
                 Propanoic acid, 2-methyl-, 1,3- 
                 Iso Pentyrate 
               
               
                   
                 dimethyl-3-butenyl ester 
               
               
                 83 
                 3-Nonanone 
                 Ethyl Hexyl Ketone 
               
               
                 84 
                 2,4,6-Octatriene, 2,6-dimethyl- 
                 Allo-Ocimene 
               
               
                 85 
                 Bicyclo[2.2.1]heptane, 2-ethyl-5- 
                 Neoproxen 
               
               
                   
                 methoxy- 
               
               
                 86 
                 1-Octanol 
                 Octyl Alcohol 
               
               
                 87 
                 3-Octanol, 3,7-dimethyl- 
                 Linacsol 
               
               
                 88 
                 Propanoic acid, 2-methyl-, 3-hexenyl 
                 Verdural B Extra 
               
               
                   
                 ester, (Z)- 
               
               
                 89 
                 2H-Pyran, tetrahydro-4-methyl-2-(2- 
                 Methyl Iso Butenyl Tetrahydro Pyran 
               
               
                   
                 methyl-1-propenyl)- 
               
               
                 90 
                 Nonanal 
                 Nonyl Aldehyde 
               
               
                 91 
                 Hexanoic acid, 2-methylpropyl ester 
                 Iso Butyl Caproate 
               
               
                 92 
                 Cyclohexane, 3-ethoxy-1,1,5-trimethyl- 
                 Herbavert 
               
               
                 93 
                 7-Octen-2-ol, 2-methyl-6-methylene-, 
                 Dihydro Myrcenol 
               
               
                   
                 dihydro deriv. 
               
               
                 94 
                 Ethanone, 1-(3,3-dimethylcyclohexyl)- 
                 Herbac 
               
               
                 95 
                 Propanoic acid, 2,2-dimethyl-, hexyl 
                 Hexyl Neo Pentanoate 
               
               
                   
                 ester 
               
               
                 96 
                 3-Heptanone, 5-methyl-, oxime 
                 Stemone 
               
               
                 97 
                 Isononanol 
                 Iso Nonyl Alcohol 
               
               
                 98 
                 Cyclohexanone, 2-(1-methylpropyl)- 
                 2-Sec-Butyl Cyclo Hexanone 
               
               
                 99 
                 Butanoic acid, 2-methyl-, hexyl ester 
                 Hexyl-2-Methyl Butyrate 
               
               
                 100 
                 1-Nonanol 
                 Nonyl Alcohol 
               
               
                 101 
                 Cyclohexaneethanol, acetate 
                 Cyclohexyl Ethyl Acetate 
               
               
                 102 
                 1-Octanol, 3,7-dimethyl- 
                 Dimethyl Octanol 
               
               
                 103 
                 Cyclopentanone, 2-pentyl- 
                 Delphone 
               
               
                 104 
                 Cyclohexanemethanol, 4-(1- 
                 Mayol 
               
               
                   
                 methylethyl)-, cis- 
               
               
                 105 
                 6-Octen-1-ol, 3,7-dimethyl-, (S)- 
                 Baranol 
               
               
                 106 
                 Benzaldehyde, 4-(1-methylethyl)- 
                 Cuminic Aldehyde 
               
               
                 107 
                 Propanoic acid, 2-methyl-, 
                 Benzyl Iso Butyrate 
               
               
                   
                 phenylmethyl ester 
               
               
                 108 
                 Propanoic acid, 2-methyl-, 4- 
                 Para Cresyl Iso Butyrate 
               
               
                   
                 methylphenyl ester 
               
               
                 109 
                 Carbonic acid, 4-cycloocten-1-yl 
                 Violiff 
               
               
                   
                 methyl ester 
               
               
                 110 
                 1,6-Octadien-3-ol, 3,7-dimethyl-, 
                 Linalyl Propionate 
               
               
                   
                 propanoate 
               
               
                 111 
                 Cyclohexanemethanol, .alpha.-methyl- 
                 Mugetanol 
               
               
                   
                 4-(1-methylethyl)- 
               
               
                 112 
                 Butanoic acid, phenylmethyl ester 
                 Benzyl Butyrate 
               
               
                 113 
                 4,7-Methano-1H-inden-5-ol, octahydro-, 
                 Dihydro Cyclacet 
               
               
                   
                 acetate 
               
               
                 114 
                 2-Cyclopenten-1-one, 3-methyl-2- 
                 Dihydrojasmone 
               
               
                   
                 pentyl- 
               
               
                 115 
                 Bicyclo[2.2.1]heptan-2-ol, 1,7,7- 
                 Iso Bornyl Propionate 
               
               
                   
                 trimethyl-, propanoate, exo- 
               
               
                 116 
                 2,6-Octadienenitrile, 3,7-dimethyl- 
                 Geranyl Nitrile 
               
               
                 117 
                 Benzene, ethenyl- 
                 Styrene 
               
               
                 118 
                 Benzene, methyl(1-methylethyl)- 
                 Cymene Coeur 
               
               
                 119 
                 Cyclohexanol, 3,3,5-trimethyl-, cis- 
                 Trimethylcyclohexanol 
               
               
                 120 
                 1-Hexanol, 5-methyl-2-(1- 
                 Tetrahydro Lavandulol 
               
               
                   
                 methylethyl)-, (R)- 
               
               
                 121 
                 Cyclohexanol, 4-(1-methylethyl)- 
                 Roselea 
               
               
                 122 
                 7-Octen-2-ol, 2,6-dimethyl-, formate 
                 Dimyrcetol 
               
               
                 123 
                 Cyclohexanone, 5-methyl-2-(1- 
                 Menthone Racemic 
               
               
                   
                 methylethyl)-, trans- 
               
               
                 124 
                 1,3,5-Undecatriene 
                 Galbanolene Super 
               
               
                 125 
                 5,7-Octadien-2-ol, 2,6-dimethyl- 
                 Ocimenol 
               
               
                 126 
                 2-Cyclohexene-1-carboxylic acid, 
                 Methyl Cyclogeranate 
               
               
                   
                 2,6,6-trimethyl-, methyl ester 
               
               
                 127 
                 Benzene, (2-bromoethenyl)- 
                 Brom Styrol 
               
               
                 128 
                 Benzene, 1-methoxy-4-(2-propenyl)- 
                 Methyl Chavicol 
               
               
                 129 
                 2H-Pyran, 6-butyl-3,6-dihydro-2,4- 
                 Gyrane 
               
               
                   
                 dimethyl- 
               
               
                 130 
                 Cyclohexanemethanol, .alpha.,3,3- 
                 Aphermate 
               
               
                   
                 trimethyl-, formate 
               
               
                 131 
                 Cyclohexanol, 4-(1,1-dimethylethyl)- 
                 Patchon 
               
               
                 132 
                 Cyclohexanol, 5-methyl-2-(1- 
                 Menthol Natural 
               
               
                   
                 methylethyl)-, [1R- 
               
               
                   
                 (1.alpha.,2.beta.,5.alpha.)]- 
               
               
                 133 
                 1,3-Dioxane, 2-butyl-4,4,6-trimethyl- 
                 Herboxane 
               
               
                 134 
                 2-Nonynoic acid, methyl ester 
                 Methyl Octine Carbonate 
               
               
                 135 
                 6-Octenenitrile, 3,7-dimethyl- 
                 Baranyl Nitrile 
               
               
                 136 
                 Decanal, 2-methyl- 
                 Methyl Octyl Acetaldehyde 
               
               
                 137 
                 2-Nonanol, 6,8-dimethyl- 
                 Nonadyl 
               
               
                 138 
                 Phenol, 4-(1,1-dimethylethyl)- 
                 Para Tertiary Butyl Phenol 
               
               
                 139 
                 1-Hexanol, 5-methyl-2-(1- 
                 Tetrahydro Lavandulyl Acetate 
               
               
                   
                 methylethyl)-, acetate 
               
               
                 140 
                 Cyclohexanol, 5-methyl-2-(1- 
                 Iso Pulegol 
               
               
                   
                 methylethenyl)-, [1R- 
               
               
                   
                 (1.alpha.,2.beta.,5.alpha.)]- 
               
               
                 141 
                 Cyclohexanone, 4-(1,1- 
                 Orivone 
               
               
                   
                 dimethylpropyl)- 
               
               
                 142 
                 2-Undecanone 
                 Methyl Nonyl Ketone 
               
               
                 143 
                 Cyclohexanemethanol, .alpha.,3,3- 
                 Rosamusk 
               
               
                   
                 trimethyl-, acetate 
               
               
                 144 
                 3-Cyclohexene-1-methanol, 2,4,6- 
                 Isocyclogeraniol 
               
               
                   
                 trimethyl- 
               
               
                 145 
                 2,6-Octadiene, 1,1-dimethoxy-3,7- 
                 Citral Dimethyl Acetal 
               
               
                   
                 dimethyl- 
               
               
                 146 
                 1-Decanol 
                 Rhodalione 
               
               
                 147 
                 2-Cyclohexen-1-one, 3-methyl-5- 
                 Livescone 
               
               
                   
                 propyl- 
               
               
                 148 
                 Phenol, 2-methyl-5-(1-methylethyl)- 
                 Carvacrol 
               
               
                 149 
                 2-Naphthalenol, decahydro- 
                 Trans Deca Hydro Beta Naphthol 
               
               
                 150 
                 Cyclohexanol, 4-(1,1-dimethylethyl)-, 
                 Tertiary Butyl Cyclohexyl Acetate 
               
               
                   
                 acetate 
               
               
                 151 
                 9-Decen-1-ol 
                 Rosalva 
               
               
                 152 
                 Phenol, 5-methyl-2-(1-methylethyl)- 
                 Thymol Nf 
               
               
                 153 
                 Cyclohexanol, 5-methyl-2-(1- 
                 Iso Pulegol Acetate 
               
               
                   
                 methylethenyl)-, acetate, [1R- 
               
               
                   
                 (1.alpha.,2.beta.,5.alpha.)]- 
               
               
                 154 
                 Benzene, [(3-methylbutoxy)methyl]- 
                 Iso Amyl Benzyl Ether 
               
               
                 155 
                 2(3H)-Furanone, 5-hexyldihydro-5- 
                 Lactojasmon 
               
               
                   
                 methyl- 
               
               
                 156 
                 Benzoic acid, butyl ester 
                 Butyl Benzoate 
               
               
                 157 
                 Bicyclo[3.2.1]octan-8-one, 1,5- 
                 Buccoxime 
               
               
                   
                 dimethyl-, oxime 
               
               
                 158 
                 2-Cyclopenten-1-one, 2-methyl-3-(2- 
                 Iso Jasmone 
               
               
                   
                 pentenyl)- 
               
               
                   
               
             
          
         
       
     
         [0051]    In one aspect, suitable Table 2 perfume raw materials include perfume raw materials from number 1 to number 116 and mixtures thereof. 
         [0052]    In one aspect, suitable Table 2 perfume raw materials include perfume raw materials from number 1 to number 79 and mixtures thereof. 
         [0053]    In one aspect, suitable perfume raw materials having boiling point greater than 250° C. but less than or equal to 280° C. are those materials listed in Table 3 below and such materials are defined as Table 3 perfume raw materials. 
         [0000]    
       
         
               
               
               
             
               
               
               
             
           
               
                 TABLE 3 
               
               
                   
               
               
                 Number 
                 Registry Name 
                 Trade Name 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 1 
                 Dodecanenitrile 
                 Clonal 
               
               
                 2 
                 Cyclohexanepropanoic acid, 2-propenyl ester 
                 Allyl Cyclohexane Propionate 
               
               
                 3 
                 2-Buten-1-one, 1-(2,6,6-trimethyl-2- 
                 Alpha Damascone 
               
               
                   
                 cyclohexen-1-yl)- 
               
               
                 4 
                 1,4-Cyclohexanedicarboxylic acid, diethyl 
                 Fructalate 
               
               
                   
                 ester 
               
               
                 5 
                 2(3H)-Furanone, 5-heptyldihydro- 
                 Undecalactone 
               
               
                 6 
                 Naphthalene, 2-methoxy- 
                 Beta Naphthol Methyl Ether 
               
               
                 7 
                 Benzenepropanal, 4-(1,1-dimethylethyl)- 
                 Bourgeonal 
               
               
                 8 
                 3-Cyclopentene-1-butanol, .beta.,2,2,3- 
                 Brahmanol 
               
               
                   
                 tetramethyl- 
               
               
                 9 
                 1H-3a,7-Methanoazulen-6-ol, octahydro- 
                 Cedrol 
               
               
                   
                 3,6,8,8-tetramethyl-,[3R- 
               
               
                   
                 (3.alpha.,3a.beta.,6.alpha.,7.beta.,8a.alpha.)]- 
               
               
                 10 
                 2-Propen-1-ol, 3-phenyl-, acetate 
                 Cinnamyl Acetate 
               
               
                 11 
                 Benzenepropanal, .alpha.-methyl-4-(1- 
                 Cymal 
               
               
                   
                 methylethyl)- 
               
               
                 12 
                 2-Buten-1-one, 1-(2,6,6-trimethyl-1- 
                 Damascone Beta 
               
               
                   
                 cyclohexen-1-yl)-, (Z)- 
               
               
                 13 
                 2-Buten-1-one, 1-(2,6,6-trimethyl-1,3- 
                 Damascenone 
               
               
                   
                 cyclohexadien-1-yl)- 
               
               
                 14 
                 2-Buten-1-one, 1-(2,6,6-trimethyl-3- 
                 Delta Damascone 
               
               
                   
                 cyclohexen-1-yl)- 
               
               
                 15 
                 Butanoic acid, 1,1-dimethyl-2-phenylethyl 
                 Dimethyl Benzyl Carbinyl 
               
               
                   
                 ester 
                 Butyrate 
               
               
                 16 
                 2-Dodecenal 
                 2 Dodecene-1-Al 
               
               
                 17 
                 2H-Pyran-2-one, 6-heptyltetrahydro- 
                 Dodecalactone 
               
               
                 18 
                 Oxiranecarboxylic acid, 3-methyl-3-phenyl-, 
                 Ethyl Methyl Phenyl Glycidate 
               
               
                   
                 ethyl ester 
               
               
                 19 
                 Oxiranecarboxylic acid, 3-phenyl-, ethyl 
                 Ethyl Phenyl Glycidate 
               
               
                   
                 ester 
               
               
                 20 
                 Phenol, 2-methoxy-4-(2-propenyl)- 
                 Eugenol 
               
               
                 21 
                 Benzenepropanal, .beta.-methyl-3-(1- 
                 Florhydral 
               
               
                   
                 methylethyl)- 
               
               
                 22 
                 Benzenepropanal, 2-ethyl-.alpha.,.alpha.- 
                 Floralozone 
               
               
                   
                 dimethyl- 
               
               
                 23 
                 4,7-Methano-1H-inden-6-ol, 3a,4,5,6,7,7a- 
                 Frutene 
               
               
                   
                 hexahydro-, propanoate 
               
               
                 24 
                 2,6-Octadienenitrile, 3,7-dimethyl-, (E)- 
                 Geranyl Nitrile 
               
               
                 25 
                 1,3-Benzodioxole-5-carboxaldehyde 
                 Heliotropin 
               
               
                 26 
                 Ionone 
                 Ionone Ab 
               
               
                 27 
                 3-Buten-2-one, 4-(2,6,6-trimethyl-2- 
                 Onone Alpha 
               
               
                   
                 cyclohexen-1-yl)-, (E)- 
               
               
                 28 
                 3-Buten-2-one, 4-(2,6,6-trimethyl-1- 
                 Ionone Beta 
               
               
                   
                 cyclohexen-1-yl)- 
               
               
                 29 
                 3-Buten-2-one, 4-(2,6,6-trimethyl-1- 
                 Ionone Beta 
               
               
                   
                 cyclohexen-1-yl)-, (E)- 
               
               
                 30 
                 3-Buten-2-one, 3-methyl-4-(2,6,6-trimethyl- 
                 Ionone Gamma Methyl 
               
               
                   
                 2-cyclohexen-1-yl)- 
               
               
                 31 
                 2-Buten-1-one, 1-(2,4,4-trimethyl-2- 
                 Isodamascone N 
               
               
                   
                 cyclohexen-1-yl)-, (E)- 
               
               
                 32 
                 Phenol, 2-methoxy-4-(1-propenyl)- 
                 Iso Eugenol 
               
               
                 33 
                 2H-Pyran-4-ol, tetrahydro-3-pentyl-, acetate 
                 Jasmal 
               
               
                 34 
                 Bicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6- 
                 Nopyl Acetate 
               
               
                   
                 dimethyl-, acetate 
               
               
                 35 
                 Benzenepropanol, .alpha.,.alpha.-dimethyl-, 
                 Phenyl Ethyl Dimethyl 
               
               
                   
                 acetate 
                 Carbinyl Acetate 
               
               
                 36 
                 Propanoic acid, 2-methyl-, 3a,4,5,6,7,7a- 
                 Cyclabute 
               
               
                   
                 hexahydro-4,7-methano-1H- 
               
               
                 37 
                 Benzaldehyde, 4-hydroxy-3-methoxy- 
                 Vanillin 
               
               
                 38 
                 3-Cyclohexene-1-carboxaldehyde, 1-methyl- 
                 Vernaldehyde 
               
               
                   
                 4-(4-methylpentyl)- 
               
               
                 39 
                 Benzenemethanol, ar-methoxy-, acetate 
                 Anisyl Acetate 
               
               
                 40 
                 Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 
                 Herbanate Ci 
               
               
                   
                 3-(1-methylethyl)-,ethyl ester, (2-endo,3- 
               
               
                   
                 exo)- 
               
               
                 41 
                 Butanoic acid, 3-methyl-, 2-phenylethyl ester 
                 Beta Phenyl Ethyl Isovalerate 
               
               
                 42 
                 Benzenepropanal, 4-methoxy-.alpha.-methyl- 
                 Canthoxal 
               
               
                 43 
                 Bicyclo[7.2.0]undec-4-ene, 4,11,11- 
                 Caryophyllene Extra 
               
               
                   
                 trimethyl-8-methylene-,[1R-(1R*,4E,9S*)]- 
               
               
                 44 
                 Cyclohexenebutanal, .alpha.,2,2,6- 
                 Cetonal 
               
               
                   
                 tetramethyl- 
               
               
                 45 
                 2-Propen-1-ol, 3-phenyl- 
                 Cinnamic Alcohol 
               
               
                 46 
                 6-Octen-1-ol, 3,7-dimethyl-, propanoate 
                 Citronellyl Propionate 
               
               
                 47 
                 Propanoic acid, decyl ester 
                 N-Decyl Propionate 
               
               
                 48 
                 Phenol, 2-methoxy-4-propyl- 
                 Dihydro Eugenol 
               
               
                 49 
                 Cyclohexanol, 1-ethenyl-2-(1-methylpropyl)-, 
                 Dihydro Ambrate 
               
               
                   
                 acetate 
               
               
                 50 
                 2-Propenoic acid, 3-phenyl-, ethyl ester 
                 Ethyl Cinnamate 
               
               
                 51 
                 Butanoic acid, 3,7-dimethyl-2,6-octadienyl 
                 Geranyl Butyrate 
               
               
                   
                 ester, (E)- 
               
               
                 52 
                 2-Octanol, 8,8-dimethoxy-2,6-dimethyl- 
                 Hydroxycitronellal Dimethyl 
               
               
                   
                   
                 Acetal 
               
               
                 53 
                 Cyclohexadieneethanol, 4-(1-methylethyl)-, 
                 Iso Bergamate 
               
               
                   
                 formate 
               
               
                 54 
                 Dodecanal 
                 Lauric Aldehyde 
               
               
                 55 
                 Propanoic acid, 2-methyl-, 1-ethenyl-1,5- 
                 Linalyl Iso Butyrate 
               
               
                   
                 dimethyl-4-hexenyl ester 
               
               
                 56 
                 Benzenepropanol, .beta.,.beta.,3-trimethyl- 
                 Majantol 
               
               
                 57 
                 Benzene, 1,2-dimethoxy-4-(2-propenyl)- 
                 Methyl Eugenol 
               
               
                 58 
                 Propanoic acid, 2-methyl-, 2-phenylethyl 
                 Phenyl Ethyl Iso Butyrate 
               
               
                   
                 ester 
               
               
                 59 
                 2-Propenenitrile, 3-phenyl- 
                 Cinnamalva 
               
               
                 60 
                 Benzene, [2-(1-propoxyethoxy)ethyl]- 
                 Acetal R 
               
               
                 61 
                 9-Undecenal, 2,6,10-trimethyl- 
                 Adoxal 
               
               
                 62 
                 2-Naphthalenol, 1,2,3,4,4a,5,6,7-octahydro- 
                 Ambrinol 20t 
               
               
                   
                 2,5,5-trimethyl- 
               
               
                 63 
                 2-Naphthalenol, octahydro-2,5,5-trimethyl- 
                 Ambrinol 20t 
               
               
                 64 
                 Ethanol, 2-[(1,7,7- 
                 Arbanol 
               
               
                   
                 trimethylbicyclo[2.2.1]hept-2-yl)oxy]-, exo- 
               
               
                 65 
                 1H-2-Benzopyran, 3,4,4a,5,8,8a(or 
                 Bigarade Oxide 
               
               
                   
                 3,4,4a,7,8,8a)-hexahydro-3,3,6,7- 
               
               
                 66 
                 Cyclohexene, 4-(1,5-dimethyl-4- 
                 Bisabolene 
               
               
                   
                 hexenylidene)-1-methyl- 
               
               
                 67 
                 1H-3a,7-Methanoazulene, octahydro-6- 
                 Cedramber 
               
               
                   
                 methoxy-3,6,8,8-tetramethyl-,[3R- 
               
               
                   
                 (3.alpha.,3a.beta.,6.alpha.,7.beta.,8a.alpha.)]- 
               
               
                 68 
                 Phenol, 4-chloro-3,5-dimethyl- 
                 4-Chloro 3,5 Xylenol 
               
               
                 69 
                 2,6-Octadiene, 1,1-diethoxy-3,7-dimethyl- 
                 Citrathal 
               
               
                 70 
                 Acetaldehyde, [(3,7-dimethyl-6- 
                 Citronellyl Oxyacetaldehyde 
               
               
                   
                 octenyl)oxy]- 
               
               
                 71 
                 Benzenepropanenitrile, .alpha.-ethenyl- 
                 Citrowanil B 
               
               
                   
                 .alpha.-methyl- 
               
               
                 72 
                 Cyclohexanol, 2-(1,1-dimethylpropyl)-, 
                 Coniferan 
               
               
                   
                 acetate 
               
               
                 73 
                 2H-1-Benzopyran-2-one 
                 Coumarin 
               
               
                 74 
                 1,3-Nonanediol, monoacetate 
                 Diasmol 
               
               
                 75 
                 Benzene, 1,1′-methylenebis- 
                 Diphenyl Methane 
               
               
                 76 
                 Benzene, 1,1′-oxybis- 
                 Diphenyl Oxide 
               
               
                 77 
                 1,6-Octadiene, 3-(1-ethoxyethoxy)-3,7- 
                 Elinthal 
               
               
                   
                 dimethyl- 
               
               
                 78 
                 Cyclopentanone, 2-heptyl- 
                 Fleuramone 
               
               
                 79 
                 5,8-Methano-2H-1-benzopyran-2-one, 6- 
                 Florex 
               
               
                   
                 ethylideneoctahydro- 
               
               
                 80 
                 Octanoic acid, 2-acetyl-, ethyl ester 
                 Gelsone 
               
               
                 81 
                 Indeno[1,2-d]-1,3-dioxin, 4,4a,5,9b- 
                 Indoflor Crist. 
               
               
                   
                 tetrahydro- 
               
               
                 82 
                 Benzeneacetic acid, 2-methylpropyl ester 
                 Iso Butyl Phenylacetate 
               
               
                 83 
                 2,6-Nonadienenitrile, 3,7-dimethyl- 
                 Lemonile 
               
               
                 84 
                 3-Decanone, 1-hydroxy- 
                 Methyl Lavender Ketone 
               
               
                 85 
                 Undecane, 1,1-dimethoxy-2-methyl- 
                 Methyl Nonyl Acetaldehyde 
               
               
                   
                   
                 Dimethyl Aceta 
               
               
                 86 
                 1-Propanone, 1-[2-methyl-5-(1-methylethyl)- 
                 Nerone 
               
               
                   
                 2-cyclohexen-1-yl]- 
               
               
                 87 
                 5,9-Undecadienal, 2,6,10-trimethyl- 
                 Oncidal 
               
               
                 88 
                 Quinoline, 6-methyl- 
                 Para Methyl Quinoline 
               
               
                 89 
                 Propanoic acid, 2-methyl-, 2-phenoxyethyl 
                 Phenoxy Ethyl Iso Butyrate 
               
               
                   
                 ester 
               
               
                 90 
                 Ethanol, 2-phenoxy-, propanoate 
                 Phenoxy Ethyl Propionate 
               
               
                   
                   
                 Formerly N-225 
               
               
                 91 
                 4,7-Methano-1H-indene-2-carboxaldehyde, 
                 Scentenal 
               
               
                   
                 octahydro-5-methoxy- 
               
               
                 92 
                 9-Undecen-2-one, 6,10-dimethyl- 
                 Tetra Hydro Psuedo Ionone 
               
               
                 93 
                 Benzenemethanol, .alpha.-(trichloromethyl)-, 
                 Trichloromethyl Phenyl 
               
               
                   
                 acetate 
                 Carbinyl Acetate 
               
               
                 94 
                 Phenol, 2-methoxy-4-(methoxymethyl)- 
                 Vaniwhite 
               
               
                 95 
                 Bicyclo[2.2.2]oct-5-ene-2-carboxaldehyde, 
                 Maceal 
               
               
                   
                 6-methyl-8-(1-methylethyl)- 
               
               
                 96 
                 Benzene, [2-(3-methylbutoxy)ethyl]- 
                 Phenyl Ether Isamyl Ether (Aka 
               
               
                   
                   
                 Anther) 
               
               
                 97 
                 2-Cyclohexene-1-carboxylic acid, 2,3,6,6- 
                 Givescone 
               
               
                   
                 tetramethyl-, ethyl ester 
               
               
                   
               
             
          
         
       
     
         [0054]    In one aspect, suitable Table 3 perfume raw materials include perfume raw materials from number 1 to number 58 and mixtures thereof. 
         [0055]    In one aspect, suitable Table 3 perfume raw materials include perfume raw materials from number 1 to number 39 and mixtures thereof. 
         [0056]    Suitable perfume raw materials and accords may be obtained from one or more of the following companies Firmenich (Geneva, Switzerland), Givaudan (Argenteuil, France), IFF (Hazlet, N.J. U.S.A.), Quest (Mount Olive, N.J. U.S.A), Bedoukian (Danbury, Conn.), Sigma Aldrich (St. Louis, Mo. U.S.A), Millennium Specialty Chemicals (Olympia Fields, Ill. U.S.A), Polarone International (Jersey City, N.J. U.S.A), Fragrance Resources (Keyport, N.J. U.S.A), and Aroma &amp; Flavor Specialties (Danbury, Conn. U.S.A). 
         [0057]    Non-limiting examples of suitable perfume delivery systems that may be used in any combination, including mixtures thereof, in the consumer product disclosed herein are:
   Polymer Assisted Delivery (PAD): This technology uses polymeric materials to deliver perfume materials. Classical coacervation, water soluble or partly soluble charged polymers, liquid crystals, hot melts, hydrogels, perfumed plastics, microcapsules, nano- and micro-latexes, etc. are examples. PAD includes but is not limited to:
       Matrix Systems: The fragrance is dissolved or dispersed in a polymer matrix or particle. Perfumes can be 1) dispersed into the polymer prior to formulating into the product or 2) added separately from the polymer during or after formulation of the product. Diffusion of perfume is a common trigger that allows or increases the rate of perfume release from a matrix system that has been deposited or applied to the desired surface (situs), although many other triggers are know that can control perfume release. Absorption into or onto polymeric particles also describes this technology. Nano- or micro-particles composed of organic materials (e.g., latexes) are examples. Suitable particles include a wide range of materials including, but not limited to styrene-butadiene copolymers (SBR), acrylonitrile-butadiene copolymers, polychloroprene, acrylic polymers, vinyl acetate polymers, vinyl acetate-ethylene polymers, vinyl chloride polymers and copolymers, polybutadiene and polyisoprene. “Standard” systems refer to those that are “pre-loaded” with the intent of keeping the pre-loaded perfume associated with the polymer until the moment or moments of perfume release. Such polymers can also suppress the neat product odor and provide a bloom and/or longevity benefit depending on the rate of perfume release. One challenge with such systems is to achieve the ideal balance between 1) in-product stability (keeping perfume inside carrier until you need it) and 2) timely release (during use or from dry situs). Achieving such stability is particularly important during in-product storage and product aging. This challenge is particularly apparent for aqueous-based, surfactant-containing products, such as heavy duty liquid laundry detergents. Many “Standard” matrix systems available effectively become “Equilibrium” systems when formulated into aqueous-based products. One can select an “Equilibrium” system or a Reservoir system, which can have acceptable in-product diffusion stability and have available triggers for release (e.g., friction). “Equilibrium” systems are those in which the perfume and polymer can be added separately to the product, and the equilibrium interaction between perfume and polymer leads to a benefit at one or more consumer touch points (versus a free perfume control that has no polymer-assisted delivery technology). The polymer can also be pre-loaded with perfume; however, part or all of the perfume can diffuse during in-product storage reaching an equilibrium that includes having desired perfume raw materials (PRMs) associated with the polymer. The polymer then carries the perfume to the surface, and release is typically via simple perfume diffusion. The use of such equilibrium system polymers has the potential to decrease the neat product odor intensity of the neat product (more so in the case of pre-loaded standard system). Deposition of such polymers can serve to “flatten” the release profile and provide increased longevity. As indicated above, such longevity would be achieved by suppressing the initial intensity and can enable the formulator to use more high impact PRMs to achieve FMOT benefits without causing initial intensity to be too strong or to be distorted. It is important that perfume release occurs within the time frame of the application to impact the desired consumer touch point or touch points. Suitable micro-particles and micro-latexes as well as making same can be found in USPA 2005/0003980 A1. Matrix systems also include hot melt adhesives and perfume plastics. Suitable hot melt adhesives and perfume plastics include those described in USPAs 2003/0109628 A1; 2004/0018950 A1; 2004/0063865 A1; 2004/0059310 A1; 2004/0059018 A1; 2005/0026801 A1; 2005/0106200 A1; 2005/0272878 A1; 2005/0147523 A1; 2006/0029564 A1; 2006/0099168 A1 and U.S. Pat. Nos. 6,498,201 B1 and 6,534,561 B1. In addition, hydrophobically modified polysaccharides can be formulated into the perfumed product to increase perfume deposition and/or modify perfume release. All such matrix systems, including for example polysaccarides and nanolatexes can be combined with other PDTs such as perfume microcapsules.   Silicones are also examples of polymers that may be used as PDT, and can provide perfume benefits in a manner similar to the polymer-assisted delivery “matrix system”. Such a PDT is referred to as silicone-assisted delivery (SAD). One can pre-load silicones, or use them as an equilibrium system as described for PAD. Suitable silicones as well as making same can be found in WO 2005/102261; USPA 20050124530A1; USPA 20050143282A1; WO 2003/015736. Functionalized silicones may also be used as described in USPA 2006/003913 A1. Examples of silicones include polydimethylsiloxane and polyalkyldimethylsiloxanes. Other examples include those with amine functionality, which can be used to provide benefits associated with amine-assisted delivery (AAD) and/or polymer-assisted delivery (PAD) and/or amine-reaction products (ARP). Other examples include, such as U.S. Pat. No. 4,911,852, USPA 2004/0058845 A1, and USPA 2004/0092425 A1.   Reservoir Systems: Reservoir systems can be described as a core-shell type technology, or one in which the fragrance is surrounded by a perfume release controlling membrane (protective shell). Microparticles or pressure sensitive capsules are examples of this technology. The possible shell materials vary widely in their stability toward water. Among the most stable are polyoxymethyleneurea (PMU)-based materials, which can hold certain PRMs for even long periods of time in aqueous solution (or product). Such systems include but are not limited to urea-formaldehyde and/or melamine-formaldehyde. Gelatin-based microcapsules can be prepared to dissolve quickly or slowly in water, depending for example on the degree of cross-linking. Many other capsule wall materials are available and vary in the degree of perfume diffusion stability observed. The rate of release of perfume from a capsule, for example, once deposited on a surface is typically in reverse order of in-product stability. As such, urea-formaldehyde and melamine-formaldehyde microcapsules for example, typically require a release mechanism other than, or in addition to, diffusion for release, such as mechanical force (e.g., friction) that serves to break the capsule and increase the rate of perfume (fragrance) release. The use of pre-loaded microcapsules requires the proper ratio of in-product stability and in-use and/or on-surface (on-situs) release, as well as proper selection of PRMs. Microcapsules that are based on urea-formaldehyde and/or melamine-formaldehyde are relatively stable, especially in near neutral aqueous-based solutions. These materials can require a friction trigger which may not be suitable to all product applications. Other microcapsule materials (e.g., gelatin) can be unstable in water and can even provide reduced benefit (versus free perfume control) when in-product aged. Perfume microcapsules (PMC) may include those described in the following references: US Patent Applications: 2003/0125222 A1; 2003/215417 A1; 2003/216488 A1; 2003/158344 A1; 2003/165692 A1; 2004/071742 A1; 2004/071746 A1; 2004/072719 A1; 2004/072720 A1; 2006/0039934A1; 2003/203829 A1; 2003/195133 A1; 2004/087477 Al; 2004/0106536 A1; and U.S. Pat. Nos. 6,645,479 B1; 6,200,949 B1; 4,882,220; 4,917,920; 4,514,461; and 4,234,627, and US RE 32713. In one aspect, said perfume microcapsule comprises, based on total perfume microcapsule weight, from about 50% to about 95%, from about 60% to about 90%, from about 75% to about 85% perfume, at least 50%, 75%, 85% or even 100% said perfume being a perfume raw material having a ClogP great than or equal to 1 and a boiling point less than or equal to 350° C.; a ClogP great than or equal to 1.5 and a boiling point less than or equal to 300° C.; or even a ClogP great than or equal to 2 and a boiling point less than or equal to 280° C. For purposes of the present invention, and unless indicated otherwise, the terms “perfume nanocapsule” and “microcapsule” is within the scope of the term “perfume microcapsule.”   
       Monomer-Assisted Delivery (MAD): Non-polymer materials or molecules can also serve to improve the delivery of perfume. Without wishing to be bound by theory, perfume can non-covalently interact with organic materials, resulting in altered deposition and/or release. Non-limiting examples of such organic materials include but are not limited to hydrophobic materials such as organic oils, mineral oils, petrolatum, fatty acids or esters, sugars, surfactants, and even other perfume raw material (perfume oils). Useful non-polymeric materials or molecules include those with a CLogP greater than about 2.   Amine Assisted Delivery (AAD): The amine-assisted delivery technology approach utilizes materials that contain an amine group to increase perfume deposition or modify perfume release during product use. There is no requirement in this approach to pre-complex or pre-react the perfume raw material(s) and amine prior to addition to the product. Materials that can contain an amine group and be suitable for use herein may be non-aromatic, for example, polyalkylimine, such as polyethyleneimine (PEI), or polyvinylamine (PVAm), or aromatic, for example, anthranilates. Such materials may also be polymeric or non-polymeric. In one aspect, such materials contain at least one primary amine. This technology will allow increased longevity and controlled release also of low ODT perfume notes (e.g., aldehydes, ketones, enones) via amine functionality, and delivery of other PRMs, without being bound by theory, via polymer-assisted delivery for polymeric amines. Without technology, volatile top notes can be lost too quickly, leaving a higher ratio of middle and base notes to top notes. The use of a polymeric amine allows higher levels of top notes and other PRMS to be used to obtain freshness longevity without causing neat product odor to be more intense than desired, or allows top notes and other PRMs to be used more efficiently. Suitable AAD systems as well as methods of making same can be found in US Patent Applications 2005/0003980 A1; 2003/0199422 A1; 2003/0036489 A1 and U.S. Pat. No. 6,103,678.   Cyclodextrins (CD): This technology approach uses cyclodextrin to improve the delivery of perfume. Typically a perfume and cyclodextrin (CD) complex is formed. Such complexes can be preformed, formed in-situ, or even formed upon the situs. Without wishing to be bound by theory, loss of water can serve to shift the equilibrium toward the CD-Perfume complex, especially if other adjunct ingredients (e.g., surfactant) are not present at high concentration to compete with the perfume for the cyclodextrin cavity. A bloom benefit can be achieved if water exposure occurs at a later time point. In addition, cyclodextrin allows the perfume formulator increased flexibility in selection of PRMs. Cyclodextrin can be preloaded with perfume or added separately from perfume to obtain the desired perfume stability, deposition or release benefit. Suitable CDs as well as methods of making same can be found in USPA 2005/0003980 A1 and U.S. Pat. Nos. 5,552,378; 3,812,011; 4,317,881; 4,418,144; and 4,378,923.   Starch Encapsulated Accords (SEA): The use of a starch encapsulated accord (SEA) technology allows one to modify the properties of the perfume, for example, by converting a liquid perfume into a solid by adding ingredients such as starch. The benefit includes increased perfume retention during product storage, especially under non-aqueous conditions. Upon exposure to moisture, a perfume bloom can be triggered. Benefits at other moments of truth can also be achieved because the starch allows the product formulator to select PRMs or PRM concentrations that normally cannot be used without the presence of SEA. Another technology example includes the use of other organic and inorganic materials, such as silica to convert perfume from liquid to solid. Suitable SEAs as well as methods of making same can be found in USPA 2005/0003980 A1 and U.S. Pat. No. 6,458,754 B1.   Inorganic Carriers (IC): This technology relates to the use of porous zeolites or other inorganic materials to deliver perfumes. Perfume-loaded zeolite can be used with or without adjunct ingredients used for example to coat the perfume-loaded zeolite (PLZ) to change its perfume release properties during product storage or during use or from the dry situs. Suitable zeolite and inorganic carriers as well as methods of making same can be found in USPA 2005/0003980 A1 and U.S. Pat. Nos. 5,858,959, 6,245,732 B1 and 6,048,830. Another example of a suitable inorganic carrier includes inorganic tubules, where the perfume or other active material is contained within the lumen of the nano- or micro-tubules. In one aspect, the perfume-loaded inorganic tubule (or Perfume-Loaded Tubule or PLT) is a mineral nano- or micro-tubule, such as halloysite or mixtures of halloysite with other inorganic materials, including other clays. The PLT technology can also comprise additional ingredients on the inside and/or outside of the tubule for the purpose of improving in-product diffusion stability, deposition on the desired situs or for controlling the release rate of the loaded perfume. Monomeric and/or polymeric materials, including starch encapsulation, can be used to coat, plug, cap, or otherwise encapsulate the PLT. Suitable PLTs as well as methods of making same can be found in U.S. Pat. No. 5,651,976.   Pro-Perfumes (PP): This technology refers to perfume technologies that result from the reaction of perfume materials with other substrates or chemicals to form materials that have a covalent bond between PRM and carrier. The PRM is converted into a new material called a pro-PRM (i.e., pro-perfume), which then releases the original PRM upon exposure to a trigger such as water or light. Pro-perfumes can provide enhanced perfume delivery properties such as increased deposition, longevity, stability, retention, and the like. Pro-perfumes include those that are monomeric or polymeric, and can be pre-formed or can be formed in-situ under equilibrium conditions, such as those present during in-product storage or on the wet or dry situs. Nonlimiting examples of pro-perfumes include Michael adducts (e.g., beta-amino ketones), aromatic or non-aromatic imines (Schiff bases), oxazolidines, beta-keto esters, and orthoesters, The typical trigger for perfume release is exposure to water; although other triggers may include enzymes, heat, light, pH change, autoxidation, shift of equilibrium, change in concentration and others. For aqueous-based products, light triggered pro-perfumes are particularly suited. Such photo-pro-perfumes (PPPs) include but are not limited to those that release coumarin derivatives and pro-perfumes upon being triggered. The released pro-perfume can release PRM(s) by means of any of the above mentioned triggers. Suitable pro-perfumes and methods of making same can be found in U.S. Pat. Nos. 7,018,978 B2; 6,987,084 B2; 6,956,013 B2; 6,861,402 B1; 6,544,945 B1; 6,093,691; 6,277,796 B1; 6,165,953; 6,316,397 B1; 6,437,150 B1; 6,479,682 B1; 6,096,918; 6,218,355 B1; 6,133,228; 6,147,037; and 5,958,870.   Amine Reaction Products (ARP): One can also use “reactive” polymeric amines in which the amine functionality is pre-reacted with PRMs to form an amine reaction product (ARP). Typically the reactive amines are primary and/or secondary amines, and can be part of a polymer or a monomer. Such ARPs can also be mixed with additional PRMs to provide benefits of polymer-assisted delivery and/or amine-assisted delivery. Nonlimiting examples of monomeric amines include hydroxyl amines and aromatic amines such as anthranilates. The ARPs can be premixed with perfume or added separately in leave-on or rinse-off applications. The benefit can include improved delivery of perfume as well as controlled release. Suitable ARPs as well as methods of making same can be found in USPA 2005/0003980 A1 and U.S. Pat. No. 6,413,920 B1.   
 
         [0069]    Suitable laundry care ingredients include, but are not limited to, those materials described in the present specification as useful aspects of the present invention, including adjunct materials as described in the present specification. 
       Liquid, Laundry Detergent Compositions 
       [0070]    In one aspect, the laundry care compositions disclosed herein, may take the form of liquid, laundry detergent compositions. In one aspect, such compositions may be a heavy duty liquid composition. Such compositions may comprise a sufficient amount of a surfactant to provide the desired level of one or more cleaning properties, typically by weight of the total composition, from about 5% to about 90%, from about 5% to about 70% or even from about 5% to about 40%. The liquid detergent compositions comprise an aqueous, non-surface active liquid carrier. Generally, the amount of the aqueous, non-surface active liquid carrier employed in the compositions herein will be effective to solubilize, suspend or disperse the composition components. For example, the compositions may comprise, by weight, from about 5% to about 90%, from about 10% to about 70%, or even from about 20% to about 70% of an aqueous, non-surface active liquid carrier. 
         [0071]    The most cost effective type of aqueous, non-surface active liquid carrier may be water. Accordingly, the aqueous, non-surface active liquid carrier component may be generally mostly, if not completely, water. While other types of water-miscible liquids, such alkanols, diols, other polyols, ethers, amines, and the like, have been conventionally been added to liquid detergent compositions as co-solvents or stabilizers, for purposes of the present invention, the utilization of such water-miscible liquids may be minimized to hold down composition cost. Accordingly, the aqueous liquid carrier component of the liquid detergent products herein will generally comprise water present in concentrations ranging from about 5% to about 90%, or even from about 20% to about 70%, by weight of the composition. 
         [0072]    The liquid detergent compositions herein may take the form of an aqueous solution or uniform dispersion or suspension of surfactant, and certain optional other ingredients, some of which may normally be in solid form, that have been combined with the normally liquid components of the composition, such as the liquid alcohol ethoxylate nonionic, the aqueous liquid carrier, and any other normally liquid optional ingredients. Such a solution, dispersion or suspension will be acceptably phase stable and will typically have a viscosity which ranges from about 100 to 600 cps, or even from about 150 to 400 cps. For purposes of this invention, viscosity is measured with a Brookfield LVDV-II+ viscometer apparatus using a #21 spindle. 
         [0073]    Suitable surfactants may be anionic, nonionic, cationic, zwitterionic and/or amphoteric surfactants. In one aspect, the detergent composition comprises anionic surfactant, nonionic surfactant, or mixtures thereof. 
         [0074]    Suitable anionic surfactants may be any of the conventional anionic surfactant types typically used in liquid detergent products. Such surfactants include the alkyl benzene sulfonic acids and their salts as well as alkoxylated or non-alkoxylated alkyl sulfate materials. Exemplary anionic surfactants are the alkali metal salts of C 10 -C 16  alkyl benzene sulfonic acids, including C 11 -C 14  alkyl benzene sulfonic acids. In one aspect, the alkyl group is linear. Such linear alkyl benzene sulfonates are known as “LAS”. Such surfactants and their preparation are described for example in U.S. Pat. Nos. 2,220,099 and 2,477,383. In one aspect, sodium and potassium linear straight chain alkylbenzene sulfonates in which the average number of carbon atoms in the alkyl group is from about 11 to 14 may be used. Sodium C 11 -C 14 , e.g., C 12 , LAS is a specific example of such surfactants. 
         [0075]    Another exemplary type of anionic surfactant comprises ethoxylated alkyl sulfate surfactants. Such materials, also known as alkyl ether sulfates or alkyl polyethoxylate sulfates, are those which correspond to the formula: R′—O—(C 2 H4O)n-SO 3 M wherein R′ is a C 8 -C 20  alkyl group, n is from about 1 to 20, and M is a salt-forming cation. In a specific embodiment, R′ is C 10 -C 18  alkyl, n is from about 1 to 15, and M is sodium, potassium, ammonium, alkylammonium, or alkanolammonium. In more specific embodiments, R′ is a C 12 -C 16 , n is from about 1 to 6 and M is sodium. 
         [0076]    The alkyl ether sulfates will generally be used in the form of mixtures comprising varying R′ chain lengths and varying degrees of ethoxylation. Frequently such mixtures will inevitably also contain some non-ethoxylated alkyl sulfate materials, i.e., surfactants of the above ethoxylated alkyl sulfate formula wherein n=0. Non-ethoxylated alkyl sulfates may also be added separately to the compositions of this invention and used as or in any anionic surfactant component which may be present. Specific examples of non-alkoyxylated, e.g., non-ethoxylated, alkyl ether sulfate surfactants are those produced by the sulfation of higher C 8 -C 20  fatty alcohols. Conventional primary alkyl sulfate surfactants have the general formula: ROSO 3 -M+ wherein R is typically a linear C 8 -C 20  hydrocarbyl group, which may be straight chain or branched chain, and M is a water-solubilizing cation. In specific embodiments, R is a C 10 -C 15  alkyl, and M is alkali metal, more specifically R is C 12 -C 14  and M is sodium. 
         [0077]    Specific, nonlimiting examples of anionic surfactants useful herein include: a) C 11 -C 18  alkyl benzene sulfonates (LAS); b) C 10 -C 20  primary, branched-chain and random alkyl sulfates (AS); c) C 10 -C 18  secondary (2,3) alkyl sulfates having formulae (I) and (II): 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    wherein M in Formulae (I) and (II) is hydrogen or a cation which provides charge neutrality, and all M units, whether associated with a surfactant or adjunct ingredient, can either be a hydrogen atom or a cation depending upon the form isolated by the artisan or the relative pH of the system wherein the compound is used, with non-limiting examples of cations including sodium, potassium, ammonium, and mixtures thereof, and x is an integer of at least about 7, or even at least about 9, and y is an integer of at least 8, or even at least about 9; d) C 10 -C 18  alkyl alkoxy sulfates (AExS) wherein x may be from 1-30; e) C 10 -C 18  alkyl alkoxy carboxylates or even comprising 1-5 ethoxy units; f) mid-chain branched alkyl sulfates as discussed in U.S. Pat. No. 6,020,303 and U.S. Pat. No. 6,060,443; g) mid-chain branched alkyl alkoxy sulfates as discussed in U.S. Pat. No. 6,008,181 and U.S. Pat. No. 6,020,303; h) modified alkylbenzene sulfonate (MLAS) as discussed in WO 99/05243, WO 99/05242, WO 99/05244, WO 99/05082, WO 99/05084, WO 99/05241, WO 99/07656, WO 00/23549, and WO 00/23548.; i) methyl ester sulfonate (MES); and j) alpha-olefin sulfonate (AOS). 
         [0078]    Suitable nonionic surfactants useful herein can comprise any of the conventional nonionic surfactant types typically used in liquid detergent products. These include alkoxylated fatty alcohols and amine oxide surfactants. In one aspect, those nonionic surfactants which are normally liquid are used. 
         [0079]    Suitable nonionic surfactants for use herein include the alcohol alkoxylate nonionic surfactants. Alcohol alkoxylates are materials which correspond to the general formula: R1(CmH 2 mO)nOH wherein R1 is a C 8 -C 16  alkyl group, m is from 2 to 4, and n ranges from about 2 to 12. In one aspect, R1 is an alkyl group, which may be primary or secondary, that contains from about 9 to 15 carbon atoms, or even from about 10 to 14 carbon atoms. In one embodiment, the alkoxylated fatty alcohols will also be ethoxylated materials that contain from about 2 to 12 ethylene oxide moieties per molecule, or even from about 3 to 10 ethylene oxide moieties per molecule. 
         [0080]    The alkoxylated fatty alcohol materials useful in the liquid detergent compositions herein will frequently have a hydrophilic-lipophilic balance (HLB) which ranges from about 3 to 17. In one aspect, the HLB of this material will range from about 6 to 15, or even from about 8 to 15. Alkoxylated fatty alcohol nonionic surfactants have been marketed under the tradename Neodol® by the Shell Chemical Company. 
         [0081]    Another suitable type of nonionic surfactant useful herein comprises the amine oxide surfactants. Amine oxides are materials which are often referred to in the art as “semi-polar” nonionics. Amine oxides have the formula: R(EO)x(PO)y(BO)zN(O)(CH2R′) 2 .qH 2 O. In this formula, R is a relatively long-chain hydrocarbyl moiety which can be saturated or unsaturated, linear or branched, and can contain from 8 to 20, from 10 to 16 carbon atoms, or even C 12 -C 16  primary alkyl. R′ is a short-chain moiety, that, in one aspect, is selected from hydrogen, methyl and —CH 2 OH. When x+y+z is different from 0, EO is ethyleneoxy, PO is propyleneneoxy and BO is butyleneoxy. Amine oxide surfactants are illustrated by C 12 -C 14  alkyldimethyl amine oxide. Non-limiting examples of nonionic surfactants include: a) C 12 -C 18  alkyl ethoxylates, such as, NEODOL® nonionic surfactants from Shell; b) C 6 -C 12  alkyl phenol alkoxylates wherein the alkoxylate units are a mixture of ethyleneoxy and propyleneoxy units; c) C 12 -C 18  alcohol and C 6 -C 12  alkyl phenol condensates with ethylene oxide/propylene oxide block polymers such as Pluronic® from BASF; d) C 14 -C 22  mid-chain branched alcohols, BA, as discussed in U.S. Pat. No. 6,150,322; e) C 14 -C 22  mid-chain branched alkyl alkoxylates, BAEx, wherein x 1-30, as discussed in U.S. Pat. No. 6,153,577, U.S. Pat. No. 6,020,303 and U.S. Pat. No. 6,093,856; f) Alkylpolysaccharides as discussed in U.S. Pat. No. 4,565,647 Llenado, issued Jan. 26, 1986; specifically alkylpolyglycosides as discussed in U.S. Pat. No. 4,483,780 and U.S. Pat. No. 4,483,779; g) Polyhydroxy fatty acid amides as discussed in U.S. Pat. No. 5,332,528, WO 92/06162, WO 93/19146, WO 93/19038, and WO 94/09099; and h) ether capped poly(oxyalkylated) alcohol surfactants as discussed in U.S. Pat. No. 6,482,994 and WO 01/42408. 
         [0082]    In the laundry detergent compositions herein, the detersive surfactant component may comprise combinations of anionic and nonionic surfactant materials. When this is the case, the weight ratio of anionic to nonionic will typically range from 10:90 to 90:10, more typically from 30:70 to 70:30. 
         [0083]    Cationic surfactants are well known in the art and non-limiting examples of these include quaternary ammonium surfactants, which can have up to 26 carbon atoms. Additional examples include a) alkoxylate quaternary ammonium (AQA) surfactants as discussed in U.S. Pat. No. 6,136,769; b) dimethyl hydroxyethyl quaternary ammonium as discussed in U.S. Pat. No. 6,004,922; c) polyamine cationic surfactants as discussed in WO 98/35002, WO 98/35003, WO 98/35004, WO 98/35005, and WO 98/35006; d) cationic ester surfactants as discussed in U.S. Pat. Nos. 4,228,042, 4,239,660 4,260,529 and U.S. Pat. No. 6,022,844; and e) amino surfactants as discussed in U.S. Pat. No. 6,221,825 and WO 00/47708, specifically amido propyldimethyl amine (APA). 
         [0084]    Non-limiting examples of zwitterionic surfactants include: derivatives of secondary and tertiary amines, derivatives of heterocyclic secondary and tertiary amines, or derivatives of quaternary ammonium, quaternary phosphonium or tertiary sulfonium compounds. See U.S. Pat. No. 3,929,678 to Laughlin et al., issued Dec. 30, 1975, at column 19, line 38 through column 22, line 48, for examples of zwitterionic surfactants; betaine, including alkyl dimethyl betaine and cocodimethyl amidopropyl betaine, C 8  to C 18  (in one aspect C 12  to C 18 ) amine oxides and sulfo and hydroxy betaines, such as N-alkyl-N,N-dimethylammino-1-propane sulfonate where the alkyl group can be C 8  to C 18 , or even C 10  to C 14 . 
         [0085]    Non-limiting examples of ampholytic surfactants include: aliphatic derivatives of secondary or tertiary amines, or aliphatic derivatives of heterocyclic secondary and tertiary amines in which the aliphatic radical can be straight- or branched-chain. One of the aliphatic substituents contains at least about 8 carbon atoms, typically from about 8 to about 18 carbon atoms, and at least one contains an anionic water-solubilizing group, e.g. carboxy, sulfonate, sulfate. See U.S. Pat. No. 3,929,678 to Laughlin et al., issued Dec. 30, 1975, at column 19, lines 18-35, for examples of ampholytic surfactants. 
       Granular Laundry Detergent Compositions 
       [0086]    In one aspect, the laundry care compositions disclosed herein, may take the form of granular, laundry detergent compositions. Granular detergent compositions of the present invention may include any number of conventional detergent ingredients. For example, the surfactant system of the detergent composition may include anionic, nonionic, zwitterionic, ampholytic and cationic classes and compatible mixtures thereof. Detergent surfactants for granular compositions are described in U.S. Pat. No. 3,664,961, Norris, issued May 23, 1972, and in U.S. Pat. No. 3,919,678, Laughlin et al., issued Dec. 30, 1975. Cationic surfactants include those described in U.S. Pat. No. 4,222,905, Cockrell, issued Sep. 16, 1980, and in U.S. Pat. No. 4,239,659, Murphy, issued Dec. 16, 1980. 
         [0087]    Nonlimiting examples of surfactant systems include the conventional C 11 -C 18  alkyl benzene sulfonates (“LAS”) and primary, branched-chain and random C 10 -C 20  alkyl sulfates (“AS”), the C 10 -C 18  secondary (2,3) alkyl sulfates of the formula CH 3 (CH 2 )x(CHOSO 3 —M+) CH 3  and CH 3  (CH 2 )y(CHOSO 3 M+) CH 2 CH 3  where x and (y+1) are integers of at least about 7, or even at least about 9, and M is a water-solubilizing cation, especially sodium, unsaturated sulfates such as oleyl sulfate, the C 10 -C 18  alkyl alkoxy sulfates (“AExS”; especially EO 1-7 ethoxy sulfates), C 10 -C 18  alkyl alkoxy carboxylates (especially the EO 1-5 ethoxycarboxylates), the C 10 -C 18  glycerol ethers, the C 10 -C 18  alkyl polyglycosides and their corresponding sulfated polyglycosides, and C 12 -C 18  alpha-sulfonated fatty acid esters. If desired, the conventional nonionic and amphoteric surfactants such as the C 12 -C 18  alkyl ethoxylates (“AE”) including the so-called narrow peaked alkyl ethoxylates and C 6 -C 12  alkyl phenol alkoxylates (especially ethoxylates and mixed ethoxy/propoxy), C 12 -C 18  betaines and sulfobetaines (“sultaines”), C 10 -C 18  amine oxides, and the like, can also be included in the surfactant system. The C 10 -C 18  N-alkyl polyhydroxy fatty acid amides can also be used. Other sugar-derived surfactants include the N-alkoxy polyhydroxy fatty acid amides, such as C 10 -C 18  N-(3-methoxypropyl) glucamide. The N-propyl through N-hexyl C 12 -C 18  glucamides can be used for low sudsing. C 10 -C 20  conventional soaps may also be used. If high sudsing is desired, the branched-chain C 10 -C 16  soaps may be used. Mixtures of anionic and nonionic surfactants are especially useful. Other conventional useful surfactants are listed in standard texts. 
         [0088]    The detergent composition can, and, in one or more aspects does, include a detergent builder. Builders are generally selected from the various water-soluble, alkali metal, ammonium or substituted ammonium phosphates, polyphosphates, phosphonates, polyphosphonates, carbonates, silicates, borates, polyhydroxy sulfonates, polyacetates, carboxylates, and polycarboxylates. In one aspect, suitable builders include alkali metals, especially sodium, salts of the above. In one aspect, phosphates, carbonates, silicates, C 10 -C 18  fatty acids, polycarboxylates, and mixtures thereof may be used. In another aspect, sodium tripolyphosphate, tetrasodium pyrophosphate, citrate, tartrate mono and di succinates, sodium silicate, and mixtures thereof may be used. 
         [0089]    Specific examples of inorganic phosphate builders are sodium and potassium tripolyphosphate, pyrophosphate, polymeric metaphosphate having a degree of polymerization of from about 6 to 21, and orthophosphates. Examples of polyphosphonate builders are the sodium and potassium salts of ethylene diphosphonic acid, the sodium and potassium salts of ethane 1-hydroxy-1, 1-diphosphonic acid and the sodium and potassium salts of ethane, 1,1,2-triphosphonic acid. Other phosphorus builder compounds are disclosed in U.S. Pat. Nos. 3,159,581; 3,213,030; 3,422,021; 3,422,137; 3,400,176 and 3,400,148. Examples of nonphosphorus, inorganic builders are sodium and potassium carbonate, bicarbonate, sesquicarbonate, tetraborate decahydrate, and silicates having a weight ratio of SiO 2  to alkali metal oxide of from about 0.5 to about 4.0, or even from about 1.0 to about 2.4. Water-soluble, nonphosphorus organic builders useful herein include the various alkali metal, ammonium and substituted ammonium polyacetates, carboxylates, polycarboxylates and polyhydroxy sulfonates. Examples of polyacetate and polycarboxylate builders are the sodium, potassium, lithium, ammonium and substituted ammonium salts of ethylene diamine tetraacetic acid, nitrilotriacetic acid, oxydisuccinic acid, mellitic acid, benzene polycarboxylic acids, and citric acid. 
         [0090]    Polymeric polycarboxylate builders are set forth in U.S. Pat. No. 3,308,067, Diehl, issued Mar. 7, 1967. Such materials include the water-soluble salts of homo- and copolymers of aliphatic carboxylic acids such as maleic acid, itaconic acid, mesaconic acid, fumaric acid, aconitic acid, citraconic acid and methylenemalonic acid. Some of these materials are useful as the water-soluble anionic polymer as hereinafter described, but only if in intimate admixture with the nonsoap anionic surfactant. Other suitable polycarboxylates for use herein are the polyacetal carboxylates described in U.S. Pat. No. 4,144,226, issued Mar. 13, 1979, to Crutchfield et al., and U.S. Pat. No. 4,246,495, issued Mar. 27, 1979, to Crutchfield et al. 
         [0091]    Water-soluble silicate solids represented by the formula SiO 2 .M 2 O, M being an alkali metal, and having a SiO 2 :M 2 O weight ratio of from about 0.5 to about 4.0, are useful salts in the detergent granules of the invention at levels of from about 2% to about 15% on an anhydrous weight basis. Anhydrous or hydrated particulate silicate can be utilized, as well. 
         [0092]    Any number of additional ingredients can also be included as components in the granular detergent composition. These include other detergency builders, bleaches, bleach activators, suds boosters or suds suppressors, anti tarnish and anti-corrosion agents, soil suspending agents, soil release agents, germicides, pH adjusting agents, nonbuilder alkalinity sources, chelating agents, smectite clays, enzymes, enzyme stabilizing agents and perfumes. See U.S. Pat. No. 3,936,537, issued Feb. 3, 1976, to Baskerville, Jr. et al. 
         [0093]    Bleaching agents and activators are described in U.S. Pat. No. 4,412,934, Chung et al., issued Nov. 1, 1983, and in U.S. Pat. No. 4,483,781, Hartman, issued Nov. 20, 1984. Chelating agents are also described in U.S. Pat. No. 4,663,071, Bush et al., from Column 17, line 54 through Column 18, line 68. Suds modifiers are also optional ingredients and are described in U.S. Pat. No. 3,933,672, issued Jan. 20, 1976, to Bartoletta et al., and U.S. Pat. No. 4,136,045, issued Jan. 23, 1979, to Gault et al. Suitable smectite clays for use herein are described in U.S. Pat. No. 4,762,645, Tucker et al., issued Aug. 9, 1988, Column 6, line 3 through Column 7, line 24. Suitable additional detergency builders for use herein are enumerated in the Baskerville patent, Column 13, line 54 through Column 16, line 16, and in U.S. Pat. No. 4,663,071, Bush et al., issued May 5, 1987. 
       Rinse Added Fabric Conditioning Compositions 
       [0094]    In one aspect, the laundry care compositions disclosed herein, may take the form of rinse added fabric conditioning compositions. Such compositions comprise a fabric softening active. In another embodiment, the compositions are rinse added fabric conditioning compositions. Examples of typical rinse added conditioning composition can be found in U.S. Provisional Patent Application Ser. No. 60/687582 filed on Oct. 8, 2004. 
         [0095]    In one embodiment of the invention, the fabric softening active (hereinafter “FSA”) is a quaternary ammonium compound suitable for softening fabric in a rinse step. In one embodiment, the FSA is formed from a reaction product of a fatty acid and an aminoalcohol obtaining mixtures of mono-, di-, and, in one embodiment, triester compounds. In another embodiment, the FSA comprises one or more softener quaternary ammonium compounds such, but not limited to, as a monoalkyquaternary ammonium compound, a diamido quaternary compound and a diester quaternary ammonium compound, or a combination thereof. 
         [0096]    In one aspect of the invention, the FSA comprises a diester quaternary ammonium (hereinafter “DQA”) compound composition. In certain embodiments of the present invention, the DQA compounds compositions also encompasses a description of diamido FSAs and FSAs with mixed amido and ester linkages as well as the aforementioned diester linkages, all herein referred to as DQA. 
         [0097]    A first type of DQA (“DQA (1)”) suitable as a FSA in the present CFSC includes a compound comprising the formula: 
         [0000]      {R4-m-N+-[(CH2)n-Y—R1]m}X— 
         [0000]    wherein each R substituent is either hydrogen, a short chain C 1 -C 6 , or even C 1 -C 3  alkyl or hydroxyalkyl group, e.g., methyl, ethyl, propyl, hydroxyethyl, and the like, poly (C 2 -C 3           alkoxy), polyethoxy, group, benzyl, or mixtures thereof; each m is 2 or 3; each n is from 1 to about 4, or 2; each Y is —O—(O)C—, —C(O)—O—, —NR—C(O)—, or —C(O)—NR— and it is acceptable for each Y to be the same or different; the sum of carbons in each R1, plus one when Y is —O—(O)C— or —NR—C(O)—, is C 12 -C 22 , or C 14 -C 20 , with each R1 being a hydrocarbyl, or substituted hydrocarbyl group; it is acceptable for R1 to be unsaturated or saturated and branched or linear and in one aspect it is linear; it is acceptable for each R1 to be the same or different and in one aspect these are the same; and X— can be any softener-compatible anion, in one aspect, chloride, bromide, methylsulfate, ethylsulfate, sulfate, phosphate, and nitrate, or chloride or methyl sulfate. Suitable DQA compounds can be made by reacting alkanolamines such as MDEA (methyldiethanolamine) and TEA (triethanolamine) with fatty acids. Some materials that typically result from such reactions include N,N-di(acyl-oxyethyl)-N,N-dimethylammonium chloride or N,N-di(acyl-oxyethyl)-N,N-methylhydroxyethylammonium methylsulfate wherein the acyl group is derived from animal fats, unsaturated, and polyunsaturated, fatty acids, e.g., tallow, hardended tallow, oleic acid, and/or partially hydrogenated fatty acids, derived from vegetable oils and/or partially hydrogenated vegetable oils, such as, canola oil, safflower oil, peanut oil, sunflower oil, corn oil, soybean oil, tall oil, rice bran oil, palm oil, etc. Non-limiting examples of suitable fatty acids are listed in U.S. Pat. No. 5,759,990 at column 4, lines 45-66. In one embodiment the FSA comprises other actives in addition to DQA (1) or DQA. In yet another embodiment, the FSA comprises only DQA (1) or DQA and is free or essentially free of any other quaternary ammonium compounds or other actives. In yet another embodiment, the FSA comprises the precursor amine that is used to produce the DQA. 
         [0098]    In another aspect of the invention, the FSA comprises a compound, identified as DTTMAC comprising the formula: 
         [0000]      [R4-m-N(+)-R1m]A- 
         [0000]    wherein each m is 2 or 3, each R1 is a C 6 -C 22 , or C 14 -C 20 , but no more than one being less than about C 12  and then the other is at least about 16, hydrocarbyl, or substituted hydrocarbyl substituent, such as C10-C 20  alkyl or alkenyl (unsaturated alkyl, including polyunsaturated alkyl, also referred to sometimes as “alkylene”), in one aspect, C 12 -C 18  alkyl or alkenyl, and branch or unbranched. In one embodiment, the Iodine Value (IV) of the FSA is from about 1 to 70; each R is H or a short chain C 1 -C 6 , such as C 1 -C 3  alkyl or hydroxyalkyl group, e.g., methyl, ethyl, propyl, hydroxyethyl, and the like, benzyl, or (R2 O) 2 -4H where each R2 is a C 1 -C 6  alkylene group; and A- is a softener compatible anion, in one aspect, chloride, bromide, methylsulfate, ethylsulfate, sulfate, phosphate, or nitrate; in another aspect chloride or methyl sulfate. Examples of these FSAs include dialkydimethylammonium salts and dialkylenedimethylammonium salts such as ditallowdimethylammonium and ditallowdimethylammonium methylsulfate. Examples of commercially available dialkylenedimethylammonium salts usable in the present invention are di-hydrogenated tallow dimethyl ammonium chloride and ditallowdimethyl ammonium chloride available from Degussa under the trade names Adogen® 442 and Adogen® 470 respectively. In one embodiment the FSA comprises other actives in addition to DTTMAC. In yet another embodiment, the FSA comprises only compounds of the DTTMAC and is free or essentially free of any other quaternary ammonium compounds or other actives. 
         [0099]    In one embodiment, the FSA comprises an FSA described in U.S. Pat. Pub. No. 2004/0204337 A1, published Oct. 14, 2004, to Corona et al., from paragraphs 30-79. 
         [0100]    In another embodiment, the FSA is one described in U.S. Pat. Pub. No. 2004/0229769 A1, published Nov. 18, 2005, to Smith et al., on paragraphs 26-31; or U.S. Pat. No. 6,494,920, at column 1, line 51 et seq. detailing an “esterquat” or a quaternized fatty acid triethanolamine ester salt. 
         [0101]    In one embodiment, the FSA is chosen from at least one of the following: ditallowoyloxyethyl dimethyl ammonium chloride, dihydrogenated-tallowoyloxyethyl dimethyl ammonium chloride, ditallow dimethyl ammonium chloride, ditallowoyloxyethyl dimethyl ammonium methyl sulfate, dihydrogenated-tallowoyloxyethyl dimethyl ammonium chloride, dihydrogenated-tallowoyloxyethyl dimethyl ammonium chloride, or combinations thereof. 
         [0102]    In one embodiment, the FSA may also include amide containing compound compositions. Examples of diamide comprising compounds may include but not limited to methyl-bis(tallowamidoethyl)-2-hydroxyethylammonium methyl sulfate (available from Degussa under the trade names Varisoft 110 and Varisoft 222). An example of an amide-ester containing compound is N-[3-(stearoylamino)propyl]-N-[2-(stearoyloxy)ethoxy)ethyl)]-N-methylamine. 
         [0103]    Another specific embodiment of the invention provides for a rinse added fabric care composition further comprising a cationic starch. Cationic starches are disclosed in US 2004/0204337 A1. In one embodiment, the fabric care composition comprises from about 0.1% to about 7% of cationic starch by weight of the laundry care composition. In one embodiment, the cationic starch is HCP401 from National Starch. 
       Adjunct Materials 
       [0104]    While not essential for the purposes of the present invention, the non-limiting list of adjuncts illustrated hereinafter are suitable for use in the consumer products disclosed herein and may be desirably incorporated in certain embodiments of such products, for example to assist or enhance performance, for treatment of the substrate to be cleaned, or to modify the aesthetics of the composition as is the case with perfumes, colorants, dyes or the like. It is understood that when a previous component, other than a perfume raw material or a perfume delivery system, is listed for an embodiment such adjuncts are in addition to the components that were previously listed for any particular embodiment. The total amount of such adjuncts may range from about 0.1% to about 50%, or even from about 1% to about 30%, by weight of the consumer product. 
         [0105]    The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the composition and the nature of the operation for which it is to be used. Suitable adjunct materials include, but are not limited to, polymers, for example cationic polymers, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, additional perfume and perfume delivery systems, structure elasticizing agents, fabric softeners, carriers, hydrotropes, processing aids and/or pigments. In addition to the disclosure below, suitable examples of such other adjuncts and levels of use are found in U.S. Pat. Nos. 5,576,282, 6,306,812 B1 and 6,326,348 B1 that are incorporated by reference. 
         [0106]    As stated, the adjunct ingredients are not essential to Applicants&#39; cleaning and laundry care compositions. Thus, certain embodiments of Applicants&#39; compositions do not contain one or more of the following adjuncts materials: bleach activators, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, additional perfumes and perfume delivery systems, structure elasticizing agents, fabric softeners, carriers, hydrotropes, processing aids and/or pigments. However, when one or more adjuncts are present, such one or more adjuncts may be present as detailed below: 
         [0107]    Surfactants—The compositions according to the present invention can comprise a surfactant or surfactant system wherein the surfactant can be selected from nonionic and/or anionic and/or cationic surfactants and/or ampholytic and/or zwitterionic and/or semi-polar nonionic surfactants. The surfactant is typically present at a level of from about 0.1%, from about 1%, or even from about 5% by weight of the cleaning compositions to about 99.9%, to about 80%, to about 35%, or even to about 30% by weight of the cleaning compositions. 
         [0108]    Builders—The compositions of the present invention can comprise one or more detergent builders or builder systems. When present, the compositions will typically comprise at least about 1% builder, or from about 5% or 10% to about 80%, 50%, or even 30% by weight, of said builder. Builders include, but are not limited to, the alkali metal, ammonium and alkanolammonium salts of polyphosphates, alkali metal silicates, alkaline earth and alkali metal carbonates, aluminosilicate builders polycarboxylate compounds. ether hydroxypolycarboxylates, copolymers of maleic anhydride with ethylene or vinyl methyl ether, 1,3,5-trihydroxybenzene-2,4,6-trisulphonic acid, and carboxymethyl-oxysuccinic acid, the various alkali metal, ammonium and substituted ammonium salts of polyacetic acids such as ethylenediamine tetraacetic acid and nitrilotriacetic acid, as well as polycarboxylates such as mellitic acid, succinic acid, oxydisuccinic acid, polymaleic acid, benzene 1,3,5-tricarboxylic acid, carboxymethyloxysuccinic acid, and soluble salts thereof. 
         [0109]    Chelating Agents—The compositions herein may also optionally contain one or more copper, iron and/or manganese chelating agents. If utilized, chelating agents will generally comprise from about 0.1% by weight of the compositions herein to about 15%, or even from about 3.0% to about 15% by weight of the compositions herein. 
         [0110]    Dye Transfer Inhibiting Agents—The compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof. When present in the compositions herein, the dye transfer inhibiting agents are present at levels from about 0.0001%, from about 0.01%, from about 0.05% by weight of the cleaning compositions to about 10%, about 2%, or even about 1% by weight of the cleaning compositions. 
         [0111]    Dispersants—The compositions of the present invention can also contain dispersants. Suitable water-soluble organic materials are the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid may comprise at least two carboxyl radicals separated from each other by not more than two carbon atoms. 
         [0112]    Enzymes—The compositions can comprise one or more detergent enzymes which provide cleaning performance and/or fabric care benefits. Examples of suitable enzymes include, but are not limited to, hemicellulases, peroxidases, proteases, cellulases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, keratanases, reductases, oxidases, phenoloxidases, lipoxygenases, ligninases, pullulanases, tannases, pentosanases, malanases, β-glucanases, arabinosidases, hyaluronidase, chondroitinase, laccase, and amylases, or mixtures thereof. A typical combination is a cocktail of conventional applicable enzymes like protease, lipase, cutinase and/or cellulase in conjunction with amylase. 
         [0113]    Enzyme Stabilizers—Enzymes for use in compositions, for example, detergents can be stabilized by various techniques. The enzymes employed herein can be stabilized by the presence of water-soluble sources of calcium and/or magnesium ions in the finished compositions that provide such ions to the enzymes. 
         [0114]    Catalytic Metal Complexes—Applicants&#39; compositions may include catalytic metal complexes. One type of metal-containing bleach catalyst is a catalyst system comprising a transition metal cation of defined bleach catalytic activity, such as copper, iron, titanium, ruthenium, tungsten, molybdenum, or manganese cations, an auxiliary metal cation having little or no bleach catalytic activity, such as zinc or aluminum cations, and a sequestrate having defined stability constants for the catalytic and auxiliary metal cations, particularly ethylenediaminetetraacetic acid, ethylenediaminetetra (methyl-enephos         phonic acid) and water-soluble salts thereof. Such catalysts are disclosed in U.S. Pat. No. 4,430,243. 
         [0115]    If desired, the compositions herein can be catalyzed by means of a manganese compound. Such compounds and levels of use are well known in the art and include, for example, the manganese-based catalysts disclosed in U.S. Pat. No. 5,576,282. 
         [0116]    Cobalt bleach catalysts useful herein are known, and are described, for example, in U.S. Pat. Nos. 5,597,936 and 5,595,967. Such cobalt catalysts are readily prepared by known procedures, such as taught for example in U.S. Pat. Nos. 5,597,936, and 5,595,967. 
         [0117]    Compositions herein may also suitably include a transition metal complex of a macropolycyclic rigid ligand—abbreviated as “MRL”. As a practical matter, and not by way of limitation, the compositions and cleaning processes herein can be adjusted to provide on the order of at least one part per hundred million of the benefit agent MRL species in the aqueous washing medium, and may provide from about 0.005 ppm to about 25 ppm, from about 0.05 ppm to about 10 ppm, or even from about 0.1 ppm to about 5 ppm, of the MRL in the wash liquor. 
         [0118]    Suitable transition-metals in the instant transition-metal bleach catalyst include manganese, iron and chromium. In one aspect, suitable MRL&#39;s herein are a special type of ultra-rigid ligand that is cross-bridged such as 5,12-diethyl-1,5,8,12-tetraazabicyclo[6.6.2]hexa-decane. Suitable transition metal MRLs are readily prepared by known procedures, such as taught for example in WO 00/32601, and U.S. Pat. No. 6,225,464. 
       Processes of Making Laundry Care Compositions 
       [0119]    The laundry care compositions of the present invention can be formulated into any suitable form and prepared by any process chosen by the formulator, non-limiting examples of which are described in U.S. Pat. No. 5,879,584; U.S. Pat. No. 5,691,297; U.S. Pat. No. 5,574,005; U.S. Pat. No. 5,569,645; U.S. Pat. No. 5,565,422; U.S. Pat. No. 5,516,448; U.S. Pat. No. 5,489,392; and U.S. Pat. No. 5,486,303. 
         [0120]    In one aspect, the liquid detergent compositions disclosed herein may be prepared by combining the components thereof in any convenient order and by mixing, e.g., agitating, the resulting component combination to form a phase stable liquid detergent composition. In one aspect, a liquid matrix is formed containing at least a major proportion, or even substantially all, of the liquid components, e.g., nonionic surfactant, the non-surface active liquid carriers and other optional liquid components, with the liquid components being thoroughly admixed by imparting shear agitation to this liquid combination. For example, rapid stirring with a mechanical stirrer may usefully be employed. While shear agitation is maintained, substantially all of any anionic surfactant and the solid ingredients can be added. Agitation of the mixture is continued, and if necessary, can be increased at this point to form a solution or a uniform dispersion of insoluble solid phase particulates within the liquid phase. After some or all of the solid-form materials have been added to this agitated mixture, particles of any enzyme material to be included, e.g., enzyme prills, are incorporated. As a variation of the composition preparation procedure described above, one or more of the solid components may be added to the agitated mixture as a solution or slurry of particles premixed with a minor portion of one or more of the liquid components. After addition of all of the composition components, agitation of the mixture is continued for a period of time sufficient to form compositions having the requisite viscosity and phase stability characteristics. Frequently this will involve agitation for a period of from about 30 to 60 minutes. 
         [0121]    Various techniques for forming detergent compositions in such solid forms are well known in the art and may be used herein. In one aspect, when the laundry care composition is in the form of a granular particle, optionally including additional but not all components of the laundry detergent composition. 
       Methods of Using Laundry Care Compositions 
       [0122]    The laundry care compositions disclosed in the present specification may be used to clean or treat a fabric. Typically at least a portion of the fabric is contacted with an embodiment of the aforementioned laundry care compositions, in neat form or diluted in a liquor, for example, a wash liquor and then the fabric may be optionally washed and/or rinsed. In one aspect, a fabric is optionally washed and/or rinsed, contacted with a an embodiment of the aforementioned laundry care compositions and then optionally washed and/or rinsed. For purposes of the present invention, washing includes but is not limited to, scrubbing, and mechanical agitation. The fabric may comprise most any fabric capable of being laundered or treated. 
         [0123]    The laundry care compositions disclosed in the present specification can be used to form aqueous washing solutions for use in the laundering of fabrics. Generally, an effective amount of such compositions is added to water, for example, in a conventional fabric laundering automatic washing machine, to form such aqueous laundering solutions. The aqueous washing solution so formed is then contacted, in one aspect, under agitation, with the fabrics to be laundered therewith. An effective amount of the laundry care composition, such as the liquid detergent compositions disclosed in the present specification, may be added to water to form aqueous laundering solutions that may comprise from about 500 to about 7,000 ppm or even from about 1,000 to about 3,000 pm of laundry care composition. 
         [0124]    In one aspect, the laundry care compositions may be employed as a laundry additive, a pre-treatment composition and/or a post-treatment composition. 
       Test Methods 
       [0000]    
       
         1.) ClogP values: For purposes of the present invention ClogP values are calculated ClogP values. Such values may be obtained from the SciFiner database by American Chemical Society through Chemical Abstract Services (CAS), P.O. Box 3102, Columbus, Ohio 43210. If a ClogP value is not available from SciFiner, the value is calculated in accordance with the fragment approach in Hansch and Leo (cf., A. Leo, in comprehensive medicinal chemistry, Vol.4, C. Hansch, P. G. Sammens, J. B. Taylor and C. A. Ransden, Eds., P. 295, Pergamon Press, 1990, 
         2.) Boiling Point: For purposes of the present invention the boiling points of perfume materials may be obtained from the SciFiner database by American Chemical Society through Chemical Abstract Services (CAS), P.O. Box 3102, Columbus, Ohio 43210. If a ClogP value is not available from SciFiner, the value is calculated in accordance with the protocol found in “Computer-Assisted Prediction of Normal Boiling Points of Furans, Tetrahydrofurans, and Thiophenes,” D. T. Stanton et al, J. Chem. Inf. Comput. Sci., 31 (1992), pp. 301-310. 
       
     
       EXAMPLES 
       [0127]    The following examples illustrate the compositions of the present invention but are not necessarily meant to limit or otherwise define the scope of the invention herein. 
       Example 1  
       [0128]    The following neat perfume compositions are made 
         [0000]    
       
         
               
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                   
               
               
                   
                   
                   
                   
                   
                 PRM 
               
               
                 Perfume Materials 
                 Example A 
                 Example B 
                 Example C 
                 Example F 
                 Type 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Ethyl-2-methyl butyrate 
                 5.0 
                 10.0 
                 0.5 
                 1.0 
                 Table 1 
               
               
                 Anisic Aldehyde 
                 5.0 
                 10.0 
                 0.0 
                 0.5 
                 Table 1 
               
               
                 Benzyl acetate 
                 11.0 
                 10.0 
                 0.5 
                 10.0 
                 Table 1 
               
               
                 Hexyl Acetate 
                 0.0 
                 2.0 
                 1.0 
                 5.0 
                 Table 2 
               
               
                 Myrcene 
                 2.0 
                 2.5 
                 1.0 
                 5.0 
                 Table 2 
               
               
                 Linalyl Acetate 
                 0.5 
                 20.0 
                 10.0 
                 20.0 
                 Table 2 
               
               
                 Citronellol 
                 2.0 
                 1.0 
                 10.0 
                 15.0 
                 Table 2 
               
               
                 Vertenex 
                 0.5 
                 5.0 
                 15.0 
                 20.0 
                 Table 2 
               
               
                 Geranyl Nitrile 
                 0.0 
                 1.0 
                 4.0 
                 5.0 
                 Table 2 
               
               
                 Cedrol 
                 10.0 
                 5.0 
                 3.5 
                 0.5 
                 Table 3 
               
               
                 Cymal 
                 10.0 
                 5.0 
                 10.5 
                 0.0 
                 Table 3 
               
               
                 Gamma Methyl Ionone 
                 10.0 
                 5.0 
                 10.0 
                 0.5 
                 Table 3 
               
               
                 Hexyl Cinnamic 
                 24.0 
                 15.0 
                 15.0 
                 7.5 
                 Other 
               
               
                 Aldehyde 
               
               
                 Methyl 
                 20.0 
                 8.5 
                 19.0 
                 10.0 
                 Other 
               
               
                 dihydrojasmonate 
                   
                   
                   
                   
               
               
                 Sum 
                 100.0 
                 100.0 
                 100.0 
                 100.0 
               
               
                   
               
             
          
         
       
     
       Example 2  
       [0129]    The following perfume compositions are made and are used as a core in the perfume microcapsules. 
         [0000]    
       
         
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                   
               
               
                   
                 Example 
                 Example 
                 Example 
                   
               
               
                 Perfume Materials 
                 A 
                 B 
                 C 
                 Example D 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Ethyl Vanillin 
                 0.5 
                 — 
                 1 
                 2 
               
               
                 Phenyl Ethyl Alcohol 
                 5 
                 — 
                 15 
                 25 
               
               
                 Benzyl Acetate 
                 1 
                 — 
                 15 
                 2 
               
               
                 Linalool 
                 10 
                 10 
                 20 
                 25 
               
               
                 Linaly Acetate 
                 11.5 
                 15 
                 25 
                 5 
               
               
                 Flor Acetate 
                 12 
                 15 
                 1 
                 25 
               
               
                 Hexyl Cinnamic 
                 15 
                 20 
                 5 
                 5 
               
               
                 Aldehyde 
               
               
                 Benzyl Salicylate 
                 10 
                 5 
                 1 
               
               
                 Methyl 
                 20 
                 10 
                 10 
                 5 
               
               
                 Dihydrojasmonate 
               
               
                 Gamma Methyl Ionone 
                 10 
                 20 
                 5 
                 5 
               
               
                 Delta Damascone 
                 5 
                 5 
                 2 
                 1 
               
               
                 Sum 
                 100 
                 100 
                 100 
                 100 
               
               
                   
               
             
          
         
       
     
       Example 3  
       [0130]    The following perfume compositions are made and are used as the perfume associated or loaded into or absorbed into the polymer assisted delivery matrix system. 
         [0000]    
       
         
               
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                   
               
               
                   
                   
                   
                   
                   
                 PRM 
               
               
                 Perfume Materials 
                 Example A 
                 Example B 
                 Example C 
                 Example D 
                 Type 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Ethyl-2-methyl butyrate 
                 5.0 
                 10.0 
                 0.5 
                 13.0 
                 Table 1 
               
               
                 Anisic Aldehyde 
                 5.0 
                 10.0 
                 0.0 
                 3.0 
                 Table 1 
               
               
                 Benzyl acetate 
                 11.0 
                 10.0 
                 0.5 
                 2.0 
                 Table 1 
               
               
                 Hexyl Acetate 
                 0.0 
                 2.0 
                 1.0 
                 9.0 
                 Table 2 
               
               
                 Myrcene 
                 2.0 
                 2.5 
                 1.0 
                 8.0 
                 Table 2 
               
               
                 Linalyl Acetate 
                 0.5 
                 20.0 
                 10.0 
                 3.0 
                 Table 2 
               
               
                 Citronellol 
                 2.0 
                 1.0 
                 10.0 
                 5.0 
                 Table 2 
               
               
                 Vertenex 
                 0.5 
                 5.0 
                 15.0 
                 3.0 
                 Table 2 
               
               
                 Geranyl Nitrile 
                 0.0 
                 1.0 
                 4.0 
                 2.0 
                 Table 2 
               
               
                 Cedrol 
                 10.0 
                 5.0 
                 3.5 
                 0.4 
                 Table 3 
               
               
                 Cymal 
                 10.0 
                 5.0 
                 10.5 
                 0.2 
                 Table 3 
               
               
                 Gamma Methyl Ionone 
                 10.0 
                 5.0 
                 10.0 
                 0.1 
                 Table 3 
               
               
                 Hexyl Cinnamic 
                 24.0 
                 15.0 
                 15.0 
                 0.2 
                 Other 
               
               
                 Aldehyde 
               
               
                 Methyl 
                 20.0 
                 8.5 
                 19.0 
                 0.3 
                 Other 
               
               
                 dihydrojasmonate 
               
               
                 Other 
                 Balance 
                 Balance 
                 Balance 
                 Balance 
                 Tables 
               
               
                   
                   
                   
                   
                   
                 1-3 
               
               
                   
               
             
          
         
       
     
       Example 4 
     Melamine Based Polyurea Capsule (85% core/15% wall) 
       [0131]    A first mixture is prepared by combining 208 grams of water and 5 grams of alkyl acrylate-acrylic acid copolymer (Polysciences, Inc. of Warrington, Pa., USA). This first mixture is adjusted to pH 5.0 using sodium hydroxide. 
         [0132]    178 grams of the capsule core material which comprise a fragrance oil of Example 2 A, B, C or D is added to the first mixture at a temperature of 65° C. to form an emulsion. High speed blending is used to achieve a volume-mean particle size of 15 microns. The ingredients to form the capsule wall material are prepared as follows: 9 grams of a corresponding capsule wall material copolymer pre-polymer (butylacrylate-acrylic acid copolymer) and 90 grams of water are combined and adjusted to pH 5.0. To this mixture is added 28 grams of a partially methylated methylol melamine resin solution (“Cymel 385”, 80% solids, Cytec). This mixture is added to the above described fragrance oil-in-water emulsion with stirring at a temperature of 65 degrees Centigrade. The temperature of the mixture is maintained at this temperature for 8 hours with continuous stirring to initiate and complete encapsulation. 
         [0133]    To form the acrylic acid-alkyl acrylate copolymer capsule wall, the alkyl group can be selected from ethyl, propyl, butyl, amyl, hexyl, cyclohexyl, 2-ethylhexyl, or other alkyl groups having from one to about sixteen carbons, or even one to eight carbons. 
       Example 5  
     Fabric Conditioning Compositions 
       [0134]    The following are non-limiting examples of the fabric conditioning compositions of the present invention. 
         [0000]    
       
         
               
               
               
               
               
             
           
               
                   
               
               
                 Ingredients 
                 Example A 
                 Example B 
                 Example C 
                 Example D 
               
               
                   
               
             
             
               
                 FSA a   
                   14-16.5 
                   14-16.5 
                   14-16.5 
                   14-16.5 
               
               
                 Ethanol 
                 2.2-2.6 
                 2.2-2.6 
                 2.2-2.6 
                 2.2-2.6 
               
               
                 Starch b   
                 1.25-1.5  
                 1.25-1.5  
                 1.25-1.5  
                 1.25-1.5  
               
               
                 Neat Perfume 
                 0.4-1.5 A 
                 0.4-1.5 B 
                 0.4-1.5 C 
                 0.4-1.5 D 
               
               
                 From Example 1 
               
               
                 Encapsulated Perfume from 
                    0.6 A 
                    0.6 B 
                    0.6 C 
                    0.6 D 
               
               
                 Example 2 
               
               
                 Phase Stabilizing Polymer c   
                 0.14-0.21 
                 0.14-0.21 
                 0.14-0.21 
                 0.14-0.21 
               
               
                 Calcium Chloride 
                 0.1-0.3 
                 0.1-0.3 
                 0.1-0.3 
                 0.1-0.3 
               
               
                 DTPA d   
                 0.017 
                 0.017 
                 0.017 
                 0.017 
               
               
                 Preservative (ppm) e   
                 5 
                 5 
                 5 
                 5 
               
               
                 Antifoam f   
                 0.015 
                 0.018 
                 0.015 
                 0.015 
               
               
                 Dye (ppm) 
                  30-300 
                  30-300 
                  30-300 
                  30-300 
               
               
                 Ammonium Chloride 
                 0.02-0.12 
                 0.02-0.12 
                 0.02-0.12 
                 0.02-0.12 
               
               
                 HCl 
                 0.012 
                 0.014 
                 0.012 
                 0.012 
               
               
                 Structurant g   
                 0.01 
                 0.01 
                 0.01 
                 0.01 
               
               
                 Deionized Water 
                 Balance 
                 Balance 
                 Balance 
                 Balance 
               
               
                   
               
               
                   a N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride. 
               
               
                   b Cationic high amylose maize starch available from National Starch under the trade name CATO ®. 
               
               
                   c Copolymer of ethylene oxide and terephthalate having the formula described in U.S. Pat. No. 5,574,179 at col.15, lines 1-5, wherein each X is methyl, each n is 40, u is 4, each R1 is essentially 1,4-phenylene moieties, each R2 is essentially ethylene, 1,2-propylene moieties, or mixtures thereof. 
               
               
                   d Diethylenetriaminepentaacetic acid. 
               
               
                   e KATHON ® CG available from Rohm and Haas Co. “PPM” is “parts per million.” 
               
               
                   f Silicone antifoam agent available from Dow Corning Corp. under the trade name DC2310. 
               
               
                   g Hydrophobically-modified ethoxylated urethane available from Rohm and Haas under the tradename Aculan 44. 
               
             
          
         
       
     
       Example 6  
     Fabric Conditioning Compositions 
       [0135]    The following are non-limiting examples of the fabric conditioning compositions of the present invention. 
         [0000]    
       
         
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
           
               
                   
               
               
                 Ingredients 
                 A 
                 B 
                 C 
                 D 
                 E 
                 F 
                 G 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 FSA a   
                 14 
                 16 
                 14 
                 18 
                 16 
                 14 
                 14 
               
               
                 Ethanol 
                 2 
                 3 
                 2 
                 4 
                 3 
                 2 
                 2 
               
               
                 Starch b   
                 1.2 
                 2.0 
                 1.7 
                 2.4 
                 2.0 
                 1.7 
                 1.2 
               
               
                 Neat Perfume From Example 1A 
                 0.4 
                 0.5 
                 0.65 
                 1.0 
                 0.5 
                 0.65 
                 0.4 
               
               
                 Encapsulated Perfume from Example 2B 
                 0.6 
                 0.5 
                 0.7 
                 0.8 
                 0.5 
                 0.7 
                 0.6 
               
               
                 Phase Stabilizing Polymer c   
                 0.20 
                 0.14 
                 0.17 
                 0.21 
                 0.14 
                 0.17 
                 0.20 
               
               
                 Calcium Chloride 
                 0.11 
                 0.15 
                 0.17 
                 0.31 
                 0.15 
                 0.17 
                 0.11 
               
               
                 DTPA d   
                 0.017 
                 0.015 
                 0.019 
                 0.019 
                 0.015 
                 0.019 
                 0.017 
               
               
                 Preservative (ppm) e   
                 5 
                 5 
                 5 
                 5 
                 5 
                 5 
                 5 
               
               
                 Antifoam f   
                 0.015 
                 0.018 
                 0.015 
                 0.015 
                 0.018 
                 0.015 
                 0.015 
               
               
                 Dye (ppm) 
                 30 
                 80 
                 150 
                 300 
                 80 
                 150 
                 30 
               
               
                 Ammonium Chloride 
                 0.02 
                 0.07 
                 0.10 
                 0.12 
                 0.07 
                 0.10 
                 0.02 
               
               
                 HCl 
                 0.012 
                 0.014 
                 0.012 
                 0.012 
                 0.014 
                 0.012 
                 0.012 
               
               
                 Structurant g   
                 0.01 
                 0.01 
                 0.01 
                 0.01 
                 0.01 
                 0.01 
                 0.01 
               
               
                 Polyethyleneimine (25,000 MW average) 
                 0.20 
                 0.25 
                 0.28 
                 0.17 
                 — 
                 — 
                 — 
               
               
                 Additional Neat Perfume 
                   
                   
                   
                   
                   
                 0.05 
                 0.08 
               
               
                 Deionized Water* 
               
               
                 PAD matrix in the form of a Hot Melt** 
                 — 
                 Yes 
                 — 
                 Yes 
                 — 
                 Yes 
                 — 
               
               
                 with Loaded Perfume from Example 3A 
               
               
                   
               
               
                 *Balance 
               
               
                 **The products above are packaged in a package comprising a container comprising a cap. The packaging in one aspect comprises the aforementioned PAD matrix system in the form of a Hot Melt adhesive. The PAD in form of hot melt adhesive in above examples is placed under or in close proximity to said cap. 
               
             
          
         
       
     
         [0136]    In the detergent compositions, the abbreviated component identifications have the following meanings:
   LAS: Sodium linear C 11 -C 13  alkyl benzene sulfonate   TAS: Sodium tallow alkyl sulfate   CxyAS: Sodium C 1x -C 1y  alkyl sulfate   C46SAS: Sodium C 14 -C16 secondary (2,3) alkyl sulfate   CxyEzS: Sodium C1x-C1y alkyl sulfate condensed with z moles of ethylene oxide   CxyEz: C1x-C1y predominantly linear primary alcohol condensed with an average of z moles of ethylene oxide   QAS: R2.N+(CH 3 ) 2 (C 2 H 4 OH) with R2=C 12 -C 14      QAS 1: R2.N+(CH 3 ) 2 (C 2 H 4 OH) with R2=C 8 -C 11      APA: C 8 -C 10  amido propyl dimethyl amine   Soap: Sodium linear alkyl carboxylate derived from an 80/20 mixture of tallow and coconut fatty acids   STS: Sodium toluene sulphonate   CFAA: C 12 -C 14  (coco) alkyl N-methyl glucamide   TFAA: C 16 -C 18  alkyl N-methyl glucamide   TPKFA: C 12 -C 14  topped whole cut fatty acids   STPP: Anhydrous sodium tripolyphosphate   TSPP: Tetrasodium pyrophosphate   Zeolite A: Hydrated sodium aluminosilicate of formula Na 12 (AlO 2 SiO 2 ) 12 .27H 2 O having a primary particle size in the range from 0.1 to 10 micrometers (weight expressed on an anhydrous basis)   NaSKS-6: Crystalline layered silicate of formula δ-Na 2 Si 2 O 5      Citric acid: Anhydrous citric acid   Borate: Sodium borate   Carbonate: Anhydrous sodium carbonate with a particle size between 200 μm and 900 μm   Bicarbonate: Anhydrous sodium bicarbonate with a particle size distribution between 400 μm and 1200 μm   Silicate: Amorphous sodium silicate (SiO 2 :Na 2 O=2.0:1)   Sulfate: Anhydrous sodium sulfate   Mg sulfate: Anhydrous magnesium sulfate   Citrate Tri-sodium citrate dihydrate of activity 86.4% with a particle size distribution between 425 μm and 850 μm   MA/AA: Copolymer of 1:4 maleic/acrylic acid, average molecular weight about 70,000   MA/AA (1): Copolymer of 4:6 maleic/acrylic acid, average molecular weight about 10,000   AA: Sodium polyacrylate polymer of average molecular weight 4,500   CMC: Sodium carboxymethyl cellulose   Cellulose ether: Methyl cellulose ether with a degree of polymerization of 650 available from Shin Etsu Chemicals   Protease: Proteolytic enzyme, having 3.3% by weight of active enzyme, sold by NOVO Industries A/S under the tradename Savinase   Protease I: Proteolytic enzyme, having 4% by weight of active enzyme, as described in WO 95/10591, sold by Genencor Int. Inc.   Alcalase: Proteolytic enzyme, having 5.3% by weight of active enzyme, sold by NOVO Industries A/S   Cellulase: Cellulytic enzyme, having 0.23% by weight of active enzyme, sold by NOVO Industries A/S under the tradename Carezyme   Amylase: Amylolytic enzyme, having 1.6% by weight of active enzyme, sold by NOVO Industries A/S under the tradename Termamyl 120T   Lipase: Lipolytic enzyme, having 2.0% by weight of active enzyme, sold by NOVO Industries A/S under the tradename Lipolase   Lipase (1) Lipolytic enzyme, having 2.0% by weight of active enzyme, sold by NOVO Industries A/S under the tradename Lipolase Ultra   Endolase: Endoglucanase enzyme, having 1.5% by weight of active enzyme, sold by NOVO Industries A/S   PB4: Sodium perborate tetrahydrate of nominal formula NaBO 2 .3H 2 O.H 2 O 2      PB1: Anhydrous sodium perborate bleach of nominal formula NaBO 2 .H 2 O 2      Percarbonate: Sodium percarbonate of nominal formula 2Na 2 CO 3 .3H 2 O 2      NOBS: Nonanoyloxybenzene sulfonate in the form of the sodium salt   NAC-OBS: (6-nonamidocaproyl) oxybenzene sulfonate   TAED: Tetraacetylethylenediamine   DTPA: Diethylene triamine pentaacetic acid   DTPMP: Diethylene triamine penta (methylene phosphonate), marketed by Monsanto under the Tradename Dequest 2060   EDDS: Ethylenediamine-N,N′-disuccinic acid, (S,S) isomer in the form of its sodium salt.   Photoactivated: Sulfonated zinc phthlocyanine encapsulated in   bleach (1) dextrin soluble polymer   Photoactivated: Sulfonated alumino phthlocyanine encapsulated in   bleach (2) dextrin soluble polymer   Brightener 1: Disodium 4,4′-bis(2-sulphostyryl)biphenyl   Brightener 2: Disodium 4,4′-bis(4-anilino-6-morpholino-1.3.5-triazin-2-yl)amino)stilbene-2:2′-disulfonate   HEDP: 1,1-hydroxyethane diphosphonic acid   PEGx: Polyethylene glycol, with a molecular weight of x (typically 4,000)   PEO: Polyethylene oxide, with an average molecular weight of 50,000   TEPAE: Tetraethylenepentaamine ethoxylate   PVI: Polyvinyl imidosole, with an average molecular weight of 20,000   PVP: Polyvinylpyrolidone polymer, with an average molecular weight of 60,000   PVNO: Polyvinylpyridine N-oxide polymer, with an average molecular weight of 50,000   PVPVI: Copolymer of polyvinylpyrolidone and vinylimidazole, with an average molecular weight of 20,000   QEA: bis((C 2 H 5 O)(C 2 H4O)n)(CH 3 ) —N+-C 6 H 12 —N+-(CH 3 ) bis((C 2 H 5 O)—(C 2 H4O))n, wherein n =from 20 to 30   SRP 1: Anionically end capped poly esters   SRP 2: Diethoxylated poly (1, 2 propylene terephtalate) short block polymer   PEI: Polyethyleneimine   Silicone antifoam: Polydimethylsiloxane foam controller with siloxane-oxyalkylene copolymer as dispersing agent with a ratio of said foam controller to said dispersing agent of 10:1 to 100:1   Opacifier: Water based monostyrene latex mixture, sold by BASF Aktiengesellschaft under the tradename Lytron 621   Wax: Paraffin wax   DEQA: Di-(tallow-oxy-ethyl) dimethyl ammonium chloride.   DEQA (2): Di-(soft-tallowyloxyethyl) hydroxyethyl methyl ammonium methylsulfate.   DTDMAMS: Ditallow dimethyl ammonium methylsulfate.   SDASA: 1:2 ratio of stearyldimethyl amine:triple-pressed stearic acid.   PA30: Polyacrylic acid of average molecular weight of between about 4,500-8,000.   480N: Random copolymer of 7:3 acrylate/methacrylate, average molecular weight about 3,500.   Polygel/carbopol: High molecular weight crosslinked polyacrylates.   Metasilicate: Sodium metasilicate (SiO 2 :Na 2 O ratio=1.0).   Nonionic: C 13 -C 15  mixed ethoxylated/propoxylated fatty alcohol with an average degree of ethoxylation of 3.8 and an average degree of propoxylation of 4.5.   Neodol 45-13: C 14 -C 15  linear primary alcohol ethoxylate, sold by Shell Chemical CO.   MnTACN: Manganese 1,4,7-trimethyl-1,4,7-triazacyclononane.   PAAC: Pentaamine acetate cobalt(III) salt.   Paraffin: Paraffin oil sold under the tradename Winog 70 by Wintershall.   NaBz: Sodium benzoate.   BzP: Benzoyl Peroxide.   SCS: Sodium cumene sulphonate.   BTA: Benzotriazole.   pH: Measured as a 1% solution in distilled water at 20° C.   
 
       Example 7  
       [0224]    The following high density granular laundry detergent compositions A to F are prepared in accord with the invention: 
         [0000]    
       
         
               
               
               
               
               
             
           
               
                   
               
               
                 Ingredients 
                 Example A 
                 Example B 
                 Example C 
                 Example D 
               
               
                   
               
             
             
               
                 Blown powder 
                   
                   
                   
                   
               
               
                 LAS 
                 6.0 
                 5.0 
                 11.0  
                 6.0 
               
               
                 TAS 
                 2.0 
                 — 
                 — 
                 2.0 
               
               
                 Zeolite A 
                 24.0  
                 — 
                 — 
                 20.0  
               
               
                 STPP 
                 — 
                 27.0  
                 24.0  
                 — 
               
               
                 Sulfate 
                 4.0 
                 6.0 
                 13.0  
                 — 
               
               
                 MA/AA 
                 1.0 
                 4.0 
                 6.0 
                 2.0 
               
               
                 Silicate 
                 1.0 
                 7.0 
                 3.0 
                 3.0 
               
               
                 CMC 
                 1.0 
                 1.0 
                 0.5 
                 0.6 
               
               
                 Brightener 1 
                 0.2 
                 0.2 
                 0.2 
                 0.2 
               
               
                 Silicone 
                 1.0 
                 1.0 
                 1.0 
                 0.3 
               
               
                 antifoam 
               
               
                 DTPMP 
                 0.4 
                 0.4 
                 0.2 
                 0.4 
               
               
                 Spray on 
               
               
                 Brightener 
                  0.02 
                 — 
                 — 
                  0.02 
               
               
                 C45E7 
                 — 
                 — 
                 — 
                 5.0 
               
               
                 C45E2 
                 2.5 
                 2.5 
                 2.0 
                 — 
               
               
                 C45E3 
                 2.6 
                 2.5 
                 2.0 
                 — 
               
               
                 Neat Perfume 
                 0.5 A 
                 0.3 B 
                 0.5 C 
                 0.2 D 
               
               
                 From 
               
               
                 Example 1 
               
               
                 Silicone 
                 0.3 
                 0.3 
                 0.3 
                 — 
               
               
                 antifoam 
               
               
                 Dry additives 
               
               
                 QEA 
                 — 
                 — 
                 — 
                 1.0 
               
               
                 EDDS 
                 0.3 
                 — 
                 — 
                 — 
               
               
                 Sulfate 
                 2.0 
                 3.0 
                 5.0 
                 10.0  
               
               
                 Carbonate 
                 6.0 
                 13.0  
                 15.0  
                 14.0  
               
               
                 Citric acid 
                 2.5 
                 — 
                 — 
                 2.0 
               
               
                 QAS II 
                 0.5 
                 — 
                 — 
                 0.5 
               
               
                 SKS-6 
                 10.0  
                 — 
                 — 
                 — 
               
               
                 Percarbonate 
                 18.5  
                 — 
                 — 
                 — 
               
               
                 PB4 
                 — 
                 18.0  
                 10.0  
                 21.5  
               
               
                 TAED 
                 2.0 
                 2.0 
                 — 
                 2.0 
               
               
                 NAC-OBS 
                 3.0 
                 2.0 
                 4.0 
                 — 
               
               
                 Protease 
                 1.0 
                 1.0 
                 1.0 
                 1.0 
               
               
                 Lipase 
                 — 
                 0.4 
                 — 
                 0.2 
               
               
                 Lipase (1) 
                 0.4 
                 — 
                 0.4 
                 — 
               
               
                 Amylase 
                 0.2 
                 0.2 
                 0.2 
                 0.4 
               
               
                 Brightener 1 
                  0.05 
                 — 
                 — 
                  0.05 
               
               
                 Encapsulated 
                 0.1 A 
                 0.3 B 
                 0.15 C  
                 0.4 D 
               
               
                 Perfume of 
               
               
                 Example 2 
               
               
                 Misc/minor to 
               
               
                 100% 
               
               
                   
               
             
          
         
       
     
       Example 8 
     Heavy Duty Liquid Detergent Composition 
       [0225]    The following liquid detergent formulations are prepared in accord with the invention (levels are given as parts per weight). 
         [0000]    
       
         
               
               
               
               
               
             
           
               
                   
               
               
                   
                   
                 Example 
                 Example 
                 Example 
               
               
                 Ingredients 
                 Example A 
                 B 
                 C 
                 D 
               
               
                   
               
             
             
               
                 LAS 
                 11.5  
                 8.8 
                 — 
                 3.9 
               
               
                 C25E2.5S 
                 — 
                 3.0 
                 18.0  
                 — 
               
               
                 C45E2.25S 
                 11.5  
                 3.0 
                 — 
                 15.7  
               
               
                 C23E9 
                 — 
                 2.7 
                 1.8 
                 2.0 
               
               
                 C23E7 
                 3.2 
                 — 
                 — 
                 — 
               
               
                 CFAA 
                 — 
                 — 
                 5.2 
                 — 
               
               
                 TPKFA 
                 1.6 
                 — 
                 2.0 
                 0.5 
               
               
                 Citric acid (50%) 
                 6.5 
                 1.2 
                 2.5 
                 4.4 
               
               
                 Calcium formate 
                 0.1 
                  0.06 
                 0.1 
                 — 
               
               
                 Sodium formate 
                 0.5 
                  0.06 
                 0.1 
                  0.05 
               
               
                 Sodium cumene 
                 4.0 
                 1.0 
                 3.0 
                  1.18 
               
               
                 sulfonate 
               
               
                 Borate 
                 0.6 
                 — 
                 3.0 
                 2.0 
               
               
                 Sodium hydroxide 
                 5.8 
                 2.0 
                 3.5 
                 3.7 
               
               
                 Ethanol 
                  1.75 
                 1.0 
                 3.6 
                 4.2 
               
               
                 1,2 propanediol 
                 3.3 
                 2.0 
                 8.0 
                 7.9 
               
               
                 Monoethanolamine 
                 3.0 
                 1.5 
                 1.3 
                 2.5 
               
               
                 TEPAE 
                 1.6 
                 — 
                 1.3 
                 1.2 
               
               
                 Protease 
                 1.0 
                 0.3 
                 1.0 
                 0.5 
               
               
                 Lipase 
                 — 
                 — 
                 0.1 
                 — 
               
               
                 Cellulase 
                 — 
                 — 
                 0.1 
                 0.2 
               
               
                 Amylase 
                 — 
                 — 
                 — 
                 0.1 
               
               
                 SRP1 
                 0.2 
                 — 
                 0.1 
                 — 
               
               
                 DTPA 
                 — 
                 — 
                 0.3 
                 — 
               
               
                 PVNO 
                 — 
                 — 
                 0.3 
                 — 
               
               
                 Neat Perfume 
                 0.4 
                 0.4 
                 0.4 
                 0.4 
               
               
                 Encapsulated 
                 0.2 A 
                 0.5 B 
                 0.1 C 
                 0.3 D 
               
               
                 Perfume of 
               
               
                 Example 2 
               
               
                 Brightener 1 
                 0.2 
                  0.07 
                 0.1 
                 — 
               
               
                 Silicone antifoam 
                  0.04 
                  0.02 
                 0.1 
                 0.1 
               
               
                 Water/minors 
               
               
                 PAD matrix Hot Melt 
                 — 
                 — 
                 Yes 
                 — 
               
               
                 perfume delivery 
               
               
                 system 
               
               
                   
               
             
          
         
       
     
         [0226]    The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm”. 
         [0227]    All documents cited in the Detailed Description of the Invention are, in relevant part, incorporated herein by reference; the citation of any document is not to be construed as an admission that it is prior art with respect to the present invention. To the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern. 
         [0228]    While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.