Abstract:
A memory cell container of a DRAM semiconductor memory device and method for manufacturing the cell container. The cell includes a container formed in a structural layer such as borophosphosilicate glass. The container is then lined with a polysilicon such as hemispherical grained polysilicon. A dielectric layer is deposited over the polysilicon layer. A barrier layer is deposited over the dielectric layer such that the opening of the container is covered by not the sidewalls or the bottom of the container. The cell is then oxidize and the barrier layer provides protection as an oxygen barrier during the oxidation or any followed re-oxidation process.

Description:
BACKGROUND OF THE INVENTION  
         [0001]    1. Field of the Invention  
           [0002]    The present invention relates generally to computer memory devices and more specifically to capacitor cell containers formed in such semiconductor memory devices.  
           [0003]    2. State of the Art  
           [0004]    Computer memory devices, such as for example DRAM (dynamic random access memory) semiconductor device modules, utilize a series or an array of capacitors to store charge in retaining digital data for subsequent recall. Each capacitor is coupled to a transistor and includes a cell which holds a charge representative of a bit of data ( i.e., a “1” or a “0”) depending on the charge of the cell. An array of capacitors, with a plurality of them holding a charge, allows for digital information to be stored in compact and efficient manner which may be recalled by examining the charge on each capacitor. However, DRAM type memory requires constant refreshing at a rapid rate due to leakage from the capacitors. Thus, one of the inherent inefficiencies of DRAM type semiconductor device memory is the time and power utilized in the continual refreshing of the array of capacitors.  
           [0005]    With the rapid advance in computer technology, DRAM semiconductor device memory modules have been designed with a higher density of memory cells. While such density of memory cells has led to expanded capacity in a smaller package, it has also produced new design challenges. For example, regardless of how small or how dense a storage cell array is packaged, each cell must hold a minimum amount of charge. Thus, in a high density memory cell array, the ability to retain the minimum level of charge in a smaller volume memory needs to be addressed. One method of addressing such an issue has been to increase the effective surface area of the memory cell, and thus the electrode associated with the memory cell.  
           [0006]    An example of increasing the surface area of a capacitor memory cell container may be seen in drawing FIG. 1 which shows a prior art partially fabricated memory cell within an integrated circuit such as a DRAM semiconductor memory device or chip. A conductive plug  10  located between neighboring word lines  12 , usually comprising polysilicon, forms electrical contact with an active area  14  of a semiconductor substrate  16 . A planarized insulating layer  18 , such as borophosphosilicate glass (BPSG) surrounds the word lines  12 . The plug  10  is formed within an opening through the insulating layer  18 . A structural layer  20  overlies the insulating layer and may also be composed of BPSG or similar material. A container  22  is formed in the structural layer, generally by anisotropically etching the structural layer  20  through a mask. The container  22  is generally a cylindrical cavity formed contiguous with the conductive plug  10  and includes sidewalls  24  which extend to an opening in the structural layer  20 . A layer  26  of hemispherical grained (HSG) silicon covers the interior surface of the container  22 . The HSG layer  26  increases the surface area of the cell container due to the hemispherical arrangement and patterning of the silicon. By increasing the surface area of the memory cell container, and thus an associated electrode, capacitance charge may be increased for a generally smaller cell container.  
           [0007]    A thin layer of nitride  28  is deposited over the HSG layer  26  as well as the surface of the structural layer  20 . It is noted that the nitride layer  28  grows much thinner over the surface of the BPSG structural layer  20  than on the HSG layer  26  due to the large nucleation incubation time of silicon nitride on BPSG. The slower growth of cell nitride on the BPSG layer  20  results in various problems. One problem is that the thin layer of cell nitride  28  on the structural layer  20  fails to effectively block oxygen during processes such as oxidation or followed oxidation (reox). The inefficiency of the thin cell nitride layer  28  allows oxygen to pass through the structural layer  20  resulting in the oxidation of the HSG polysilicon layer. Of course, the amount of oxidation depends on the actual thickness of the nitride layer  26  above the structural layer  20 . Additionally, the thin nitride layer allows for current leakage at the edge of the container  22  thus creating an additional inefficiency with regard to the operation of the capacitor cell structure.  
           [0008]    In view of the shortcomings in the art, it would be advantageous to provide a memory cell structure and a method for forming such a structure that assists in preventing oxidation of the cell plate. Further it would be advantageous to provide a structure which is simple to manufacture and a method which did not significantly interfere with existing manufacturing processes. It would also be advantageous to provide a memory cell structure and method for manufacturing the structure to which reduced current leakage at the edge of the cell container thus improving the overall efficiency of the memory cell.  
         BRIEF SUMMARY OF THE INVENTION  
         [0009]    In accordance with one aspect of the invention a method of forming a cell container for the capacitor of a memory device, such as a DRAM semiconductor memory device or chip or module, is provided. The method includes forming a structural layer above a conductive plug. A cavity is formed in the structural layer, such as by etching. The cavity includes at least one sidewall, such as a continual sidewall in a cylinder, a bottom surface which is contiguous with the conductive plug, and an opening at the upper surface of the structural layer. A layer of polysilicon is deposited over the bottom and sidewall of the cavity. A dielectric, such as a nitride layer, is formed over the polysilicon layer and at least a portion of the upper surface of the structural layer including the area surrounding the opening of the cavity at the opening thereof. A barrier layer is deposited over at least a portion of the dielectric layer including the area surrounding the opening of the cavity and a portion of the sidewall adjacent the opening. The barrier layer is deposited such that the majority of the sidewall as well as the bottom surface are not covered with the barrier layer. The container may then be subjected to an oxidation process wherein the barrier layer is oxidized and acts as an oxygen barrier for the structural layer.  
           [0010]    The structural layer may be formed of BPSG with the polysilicon layer being formed of a hemispherical grained polysilicon to improve the surface area of the cell container. The dielectric layer may be formed of silicon nitride. Aluminum is a suitable material for the barrier layer and may be deposited by sputtering the aluminum on to help keep the aluminum layer from substantially covering the interior cell surface. Other metallic materials are also suitable such as, for example, tantalum, zirconium, hafnium, tungsten, titanium or aluminum nitride. The formation of the metallic layer provides both, an oxygen barrier for the cell structure during oxidation processes, as well as leakage protection for the cell at the opening edge.  
           [0011]    In accordance with another aspect of the invention, a memory cell container is provided. The memory cell includes a cavity formed in a structural layer such as BPSG. The cavity is formed to have a bottom, which is contiguous with a conductive plug, and a sidewall extending from the bottom of the cavity to an opening at the upper surface of the structural layer. A polysilicon layer, such as HSG polysilicon, is deposited in the cavity on the bottom and along the sidewall. A nitride layer, such as silicon nitride, is formed over the polysilicon layer and at least a portion of the upper surface of the structural layer. A barrier layer, such as aluminum, covers at least a portion of the nitride above the structural layer and a small portion of the nitride along the sidewall of the cavity adjacent the opening. The barrier layer forms an oxygen barrier for the cell container and also protects against edge leakage during operation. As with the method, various materials may be utilized to form the cell container, including various materials cited for the barrier layer.  
           [0012]    In accordance with another aspect of the invention, a memory device is provided which includes a substrate having an array of capacitors formed therein. At least one of the capacitors includes a cell container similar to that described above including the metallic layer formed as an oxygen barrier. 
       
    
    
     BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS  
       [0013]    The foregoing and other advantages of the invention will become apparent upon reading the following detailed description and upon reference to the drawings in which:  
         [0014]    [0014]FIG. 1 is a partial sectional view of a prior art cell container of DRAM module; and  
         [0015]    FIGS.  2 A- 2 E show partial sectional views of a cell container for a DRAM module and a method of making such according to one aspect of the present invention. 
     
    
     DETAILED DESCRIPTION OF THE INVENTION  
       [0016]    Referring first to drawing FIG. 2A a cell container  40  is shown at an early stage of manufacturing. It is noted that manufacture of such cells is carried out with respect to multiple cells and cell containers  40  substantially simultaneously, however, for sake of clarity only one such cell container is depicted in the drawings. The cell container  40  is formed above a conductive plug  10  and a planarized insulating layer  18  similar to that previously discussed. However, for sake of convenience, various other components associated with the memory cell such as the word lines, active areas, or the semiconductor substrate are not shown in drawing FIGS. 2A through 2E. To form the cell container  40 , a structural layer  20 , such as BPSG, is deposited above the planarized insulating layer  18  utilizing techniques and processes known by those of skill in the art. A masked etching process then forms several openings, typically cylindrical in geometry, contiguous with the conductive plug  10  and having sidewalls  24  which extend upwards therefrom.  
         [0017]    As shown in drawing FIG. 2B, a layer of HSG polysilicon  26  is deposited over the structural layer  20 . The HSG layer  26  may be formed by various methods known in the art, including low pressure CVD (LPCVD) and silicon deposition followed by vacuum anneal under specified temperature and pressure conditions. The HSG layer  26  may also be doped for greater conductivity. The formation of an HSG layer  26  is discussed in greater detail in U.S. Pat. No. 6,090,655 issued to Zahurak et al., assigned to the assignee of the present invention and incorporated by reference herein. As discussed above, the HSG layer  26  provides a rough or textured surface thus increasing the surface area, as well as the capacitance of the container  40 . Grain size of the HSG layer may vary depending on the volume of the cell container  40  and the desired surface area of the container.  
         [0018]    Subsequent the formation of the HSG layer  26 , the structure may be planarized for isolation of the memory cells on the array as shown in drawing FIG. 2C and thus again exposing the upper surface  42  of the structural layer  20  in preparation for further processing. A dielectric  28  is then deposited over the HSG layer  26  as well as the planarized structural layer  20  as seen in drawing FIG. 2D. The dielectric layer  28  is conformally deposited according the methods and processes known to those of skill in the art. It is contemplated that the dielectric layer  28  is formed silicon nitride, such as Si 3 N 4 , however, it is noted that other suitable dielectric materials may be utilized in conjunction with the present invention such as, for example, oxynitride.  
         [0019]    After the dielectric layer  28  has been deposited, a thin barrier layer  44 , such as aluminum, is deposited such that it covers the dielectric layer  28  above the upper surface  42  of the structural layer  20  as well as partially into the cell container  40  about the rim  46  of the container  40 . Such deposition may be accomplished by a low step coverage sputtering process after the dielectric layer  28  has been deposited. Techniques such as low angle or high vacuum application may be used in the sputtering process to ensure that the metallic layer is deposited on the top part or rim area  46  of the container  40  without significantly depositing metal along the sidewalls or bottom surface of the container  40 . While aluminum is contemplated for use as the metallic layer, other metals may properly be utilized in conjunction with the present invention. For example, tantalum, zirconium, hafnium, tungsten, titanium, aluminum nitride, and their oxides may be used for the barrier layer  44 . It should be understood that the barrier layer  44  will form an oxygen barrier for those areas that it covers. To form the desired oxygen barrier, the barrier layer can be formed by one of at least two methods. The barrier layer  44  may be formed by directly sputtering a metallic layer to cover the dielectric layer  28  above the upper surface  42  of the structural layer  20  as well as partially into the cell container  40  about the rim  46  of the container  40  and then converting the metallic layer to a metallic oxide layer  44  by an oxidation process. When the metallic layer  44 , a conductive layer, is converted by oxidation from a metallic layer  44  to a metallic oxide layer  44 , the metallic oxide layer  44  becomes an insulation layer and is no longer conductive. If the barrier layer  44  is to be formed as a metallic oxide layer in-situ, such a metallic oxide layer  44  may be formed by the reactive sputtering of metal in an oxidizing ambient atmosphere. In either event, whether the layer  44  is either sputtered and then converted to a metallic oxide layer by an external oxidation process or is formed in-situ by the reactive sputtering of a metal in an oxidizing ambient atmosphere, the resulting metallic oxide layer  44  has a higher dielectric constant than that of silicon nitride. Therefore, the formation of the metallic oxide layer  44  does not affect the electrical performance of the capacitor cell container  40  but, rather, functions as an oxygen diffusion barrier regarding the surrounding areas that the metallic oxide layer  44  covers after formation to prevent the diffusion of oxygen thereinto. When the metallic layer  44  is deposited as a metal and subjected to an external oxidation process, the metallic layer  44  the cell container  40  is oxidized at relatively low temperatures in an oxidizing ambient, such as O 2 , O 3 , N 2 O or H 2 O with or without the aid of plasma enhancement. Thus, for example, deposited aluminum  44  would be oxidized to form aluminum oxide (Al 2 O 3 ). The aluminum oxide may also be formed after the aluminum layer  44  is deposited during a followed cell nitride re-oxidation step thus eliminating the need for an extra oxidation step. Subsequent oxidation of the metallic layer  44  converts the metallic layer  44  to a metallic oxide layer which has a high dielectric constant and preferably higher than the nitride layer  28  upon which it is deposited. Additionally, it is expected that the resulting thickness of oxidized metallic layer  44  be in the range of approximately 20-200 Å.  
         [0020]    The existence of the barrier layer  44  allows for oxidation of the cell container  40 , including the nitride layer  28 , to take place without oxygen leaking through the structural layer  20 . As noted previously, oxygen leaking through the structural layer  20  would result in damage of the bottom cell layer such as the HSG layer  26 . Furthermore, the barrier layer  46  serves as a barrier of current leakage through the edge or rim area  46  of the container  40  thus improving the efficiency of the cell container in operation.  
         [0021]    It is noted that while sputtering of the barrier layer  44  allows for deposition of the material in a manner which does not sufficiently form an extraneous layer within the cell container itself (i.e., the cell walls and floor) formation of such would not be detrimental to the operative capacity or does not affect the operative characteristics of the memory cell using cell container  40 . The barrier layer  44  has no discernable or minimum impact, in any at all, upon cell capacitance in the case that limited material is formed within the cell container  40  itself. Further, the limited material falling into the cell container will be converted into a metallic oxide in the oxidation step or process. As such, the metallic oxide layer of material for the metals described herein will have a higher dielectric constant than the silicon nitride and, therefore, will have little effect on the capacitor electrical performance.  
         [0022]    A conductive top electrode layer  48  is deposited in the container  40  and above the metallic layer  44  to form the resulting capacitive memory cell  50 . The top electrode layer  48  may be formed, for example, of polysilicon, titanium nitride or even a silicide according to processes understood by those of skill in the art.  
         [0023]    While the invention may be susceptible to various modifications and alternative forms, specific embodiments have been shown by way of example in the drawings and have been described in detail herein. However, it should be understood that the invention is not intended to be limited to the particular forms disclosed. Rather, the invention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the following appended claims.