Abstract:
A phase change memory may be formed with an insulator made up of two different layers having significantly different thermal conductivities. Pores may be formed within the stack of insulating layers and the pores may be filled with heaters, chalcogenide layers, and electrodes in some embodiments. The use of the two different insulator layers enables embodiments where thermal losses may be reduced and an amorphous region may be maintained along the entire length of the phase change material layer.

Description:
BACKGROUND 
     This invention relates generally to phase change memories. 
     Phase change memory devices use phase change materials, i.e., materials that may be electrically switched between a generally amorphous and a generally crystalline state, for electronic memory application. One type of memory element utilizes a phase change material that may be, in one application, electrically switched between a structural state of generally amorphous and generally crystalline local order or between different detectable states of local order across the entire spectrum between completely amorphous and completely crystalline states. The state of the phase change materials is also non-volatile in that, when set in either a crystalline, semi-crystalline, amorphous, or semi-amorphous state representing a resistance value, that value is retained until changed by another programming event, as that value represents a phase or physical state of the material (e.g., crystalline or amorphous). The state is unaffected by removing electrical power. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a partial, enlarged, cross-sectional view of one embodiment of the present invention; 
         FIG. 2  is an enlarged, cross-sectional view corresponding to  FIG. 1  at an early stage of manufacture in accordance with one embodiment; 
         FIG. 3  is an enlarged, cross-sectional view at a subsequent stage of that shown in  FIG. 2  in accordance with one embodiment; 
         FIG. 4  is an enlarged, cross-sectional view at a subsequent stage of that shown in  FIG. 3  in accordance with one embodiment; 
         FIG. 5  is an enlarged, cross-sectional view at a subsequent stage of that shown in  FIG. 4  in accordance with one embodiment; 
         FIG. 6  is an enlarged, cross-sectional view at a subsequent stage of that shown in  FIG. 5  in accordance with one embodiment; 
         FIG. 7  is a partial, enlarged, cross-sectional view of another embodiment of the present invention; and 
         FIG. 8  is a system depiction for one embodiment. 
     
    
    
     DETAILED DESCRIPTION 
     Referring to  FIG. 1 , a phase change memory cell  10  may be provided within a phase change memory that includes a large number of such cells arranged in rows and columns, in one embodiment. The cell  10  may include a lower electrode  20  coupled to a potential source and an upper electrode  16 , also coupled to that source. 
     A pore, in one embodiment, may receive both of the electrodes  20  and  16 , as well as a phase change material  18  such as, for example, a chalcogenide or pnictide. The pore may be formed in an insulator which includes a first insulator layer  12  and second insulator layers  14   a  and  14   b.    
     In some embodiments, the first insulator layer  12  may have a thermal conductivity that is much smaller than that of the second insulator layers  14   a  and  14   b . In some embodiments, the insulator layers  14   a  and  14   b  may be formed of the same material. For example, the insulator layer  12  may be an air gap or a material such as WSe 2  crystal, ZnS—SiO 2 , silica aerogel, or xerogel. The insulator layers  14   a  and  14   b  may be silicon dioxide or silicon nitride as two examples. 
     In some embodiments, the thermal conductivity of the insulator layers  14   a  and  14   b  may be twice that of the insulator layer  12 . In other embodiments, the insulator layer  12  may have a thermal conductivity that is less than 5% of the thermal conductivity of the phase change material and advantageously less than about one percent of the thermal conductivity of the phase change material  18 . In some embodiments, the insulator layers  14   a  or  14   b  may have a thermal conductivity that is more than five times the thermal conductivity of the phase change material  18  and ten times the thermal conductivity of the phase change material  18 . In some embodiments, the phase change material  18  may be GST, which includes germanium, antimony, and tellurium. 
     In some cases, it may be advantageous to have the insulator layers  14   a  and  14   b  on either side of the insulator layer  12 . However, in some embodiments, the layer  14   a  may be omitted or the layer  14   a  may be the same material as the layer  12  or may be some other insulator. In some cases, the insulator layer  12  may be much thicker than either insulator layer  14   a  or  14   b.    
     It may be advantageous to locate the layer  12  centrally along the vertical extent of the phase change material  18  in some embodiments. The insulator layer  12  may enable the confinement of the molten phase change region away from the electrodes  16  and  20 . The insulator layers  14   a  or  14   b  may be useful for quenching. 
     In some embodiments, the use of the different insulative layers increases the likelihood of the existence of an amorphous region along the entire phase change material  18 . Therefore, in some embodiments, the cell  10  may have increased resistance in the reset state, increased threshold voltage, and increased resistance dynamic range between set and reset states. The amorphous region in the cell may be fixed near the center of the phase change material  18  in some embodiments. The layers  14   a  and  14   b  may increase the likelihood that the amorphous region remains centered, despite variations in sidewall angle, interface imperfections, or changes in the phase change material itself. Because the thicknesses of the insulator layers  14   a  and  14   b  may be carefully controlled, the size of the amorphous dome may be more regular from bit to bit in the array, providing narrower distributions of characteristics such as threshold voltage and reset resistance that depend on the size of a cell in some cases. In some embodiments, the cell may have reduced distribution of reset state parameters, such as threshold voltage or reset resistance, at the same geometrical variations of cell structure. 
     In some embodiments, because less heat is lost to surrounding insulators and the phase change material  18  is a good insulator, the cell may be more efficient. Because the amorphous region is away from the electrode  16  or  20  interfaces, less resistive electrodes may be utilized to lower the overall cell resistance. 
     Referring to  FIG. 2 , one exemplary fabrication sequence for such a cell may begin by forming a stack of layers including a semiconductor substrate or underlayer  15 , an electrode stack  20 , and insulator layers  12 ,  14   a , and  14   b . Then, the layers may be patterned using any of a variety of techniques. For example, damascene lines may be used for the lower electrode contacts. The insulator stack may be formed of well controlled thicknesses. The stack may be patterned by single or double lithography steps and etched to form an array of cylindrical or rectangular holes. Alternatively, at this stage, lines may be patterned that are then isolated from one another by a later patterning step. 
     Thus, as shown in  FIG. 3 , the etched openings  22  may be formed in the stack of layers down to the electrode stack  20 . 
     Then, referring to  FIG. 4 , the phase change material  18 , such as GST, may be deposited. The deposited phase change material  18  may be polished back, as shown in  FIG. 5 , and then recessed to form recess  26 . This recessing may be achieved by a dip back or an overpolish, to mention two examples. 
     The top electrode contact  16  is then deposited, as shown in  FIG. 6 . The contact  16  may be self-aligned to the phase change material  18  by filling the recess  26  ( FIG. 5 ). The top electrode stack may take a variety of forms and is patterned to form an array. 
     In accordance with another embodiment of the present invention, shown in  FIG. 7 , a bottom electrode or conductive layer  30  may be coupled to a vertically oriented heater  40 . The heater  40  contacts the phase change material  18 , also contacted on its other end by a top electrode  16  or column. The heater  40  may be titanium silicon nitride in one embodiment. 
     A pore may be defined that includes the insulator layer  14   a , the insulator layer  12 , and the insulator layer  14   b  in some embodiments. 
     The heater  40  may be surrounded by a pair of sidewall spacers  34  and  32 . The sidewall spacer  34  may be the same material as the layer  14   a , in one embodiment, and the sidewall spacer  32  may be formed of another material, such as silicon nitride. 
     The insulator layer  12  may conform the molten phase change material region to its boundary with the phase change material  18  and, hence, may protect against creation of the leakage paths or reduced threshold voltage in the reset state. The insulator layer  12  may have a thermal conductivity much smaller than the insulator layers  14   a  or  14   b.    
     To fabricate the embodiment of  FIG. 7 , an array select device (not shown) may be fabricated, and an insulator stack may be formed over the select device. The stack may be patterned by single or double lithography steps and etched to form an array of cylindrical or rectangular holes. 
     A bottom electrode material  30  may be deposited and polished off to contact a select device electrode (not shown). Next, the insulator stack may be formed in which the insulator layers  12 ,  14   a , and  14   b  have well controlled thicknesses. The stack may be patterned by single or double lithography steps and etched to form an array of cylindrical or rectangular holes. 
     Phase change material  18  may be deposited to fill the holes and then polished back. The top electrode contact  16  may be deposited next and may be self-aligned to the phase change material  18  by filling the etched back phase change material. Bit line metal layers (not shown) may then be patterned using subtractive or damascene processes to form an array. 
     Programming of the phase change material  18  to alter the state or phase of the material may be accomplished by applying voltage potentials to the lower electrode  20  and upper electrode  16 , thereby generating a voltage potential across the select device and memory element. When the voltage potential is greater than the threshold voltages of select device and memory element, then an electrical current may flow through the phase change material  18  in response to the applied voltage potentials, and may result in heating of the phase change material  18 . 
     This heating may alter the memory state or phase of the material  18 . Altering the phase or state of the phase change material  18  may alter the electrical characteristic of memory material, e.g., the resistance of the material may be altered by altering the phase of the memory material. Memory material may also be referred to as a programmable resistive material. 
     In the “reset” state, memory material may be in an amorphous or semi-amorphous state and in the “set” state, memory material may be in an a crystalline or semi-crystalline state. The resistance of memory material in the amorphous or semi-amorphous state may be greater than the resistance of memory material in the crystalline or semi-crystalline state. It is to be appreciated that the association of reset and set with amorphous and crystalline states, respectively, is a convention and that at least an opposite convention may be adopted. 
     Using electrical current, memory material may be heated to a relatively higher temperature to amorphosize memory material and “reset” memory material (e.g., program memory material to a logic “0” value). Heating the volume of memory material to a relatively lower crystallization temperature may crystallize memory material and “set” memory material (e.g., program memory material to a logic “1” value). Various resistances of memory material may be achieved to store information by varying the amount of current flow and duration through the volume of memory material. 
     One or more MOS or bipolar transistors or one or more diodes (either MOS or bipolar) may be used as the select device. Also, an ovonic threshold switch may be used as a select device. If a diode is used, the bit may be selected by lowering the row line from a higher deselect level. As a further non-limiting example, if an n-channel MOS transistor is used as a select device with its source, for example, at ground, the row line may be raised to select the memory element connected between the drain of the MOS transistor and the column line. When a single MOS or single bipolar transistor is used as the select device, a control voltage level may be used on a “row line” to turn the select device on and off to access the memory element. 
     Turning to  FIG. 8 , a portion of a system  500  in accordance with an embodiment of the present invention is described. System  500  may be used in wireless devices such as, for example, a personal digital assistant (PDA), a laptop or portable computer with wireless capability, a web tablet, a wireless telephone, a pager, an instant messaging device, a digital music player, a digital camera, or other devices that may be adapted to transmit and/or receive information wirelessly. System  500  may be used in any of the following systems: a wireless local area network (WLAN) system, a wireless personal area network (WPAN) system, a cellular network, although the scope of the present invention is not limited in this respect. 
     System  500  may include a controller  510 , an input/output (I/O) device  520  (e.g. a keypad, display), static random access memory (SRAM)  560 , a memory  530 , and a wireless interface  540  coupled to each other via a bus  550 . A battery  580  may be used in some embodiments. It should be noted that the scope of the present invention is not limited to embodiments having any or all of these components. 
     Controller  510  may comprise, for example, one or more microprocessors, digital signal processors, microcontrollers, or the like. Memory  530  may be used to store messages transmitted to or by system  500 . Memory  530  may also optionally be used to store instructions that are executed by controller  510  during the operation of system  500 , and may be used to store user data. Memory  530  may be provided by one or more different types of memory. For example, memory  530  may comprise any type of random access memory, a volatile memory, a non-volatile memory such as a flash memory and/or a memory such as memory discussed herein. 
     I/O device  520  may be used by a user to generate a message. System  500  may use wireless interface  540  to transmit and receive messages to and from a wireless communication network with a radio frequency (RF) signal. Examples of wireless interface  540  may include an antenna or a wireless transceiver, although the scope of the present invention is not limited in this respect. 
     References throughout this specification to “one embodiment” or “an embodiment” mean that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one implementation encompassed within the present invention. Thus, appearances of the phrase “one embodiment” or “in an embodiment” are not necessarily referring to the same embodiment. Furthermore, the particular features, structures, or characteristics may be instituted in other suitable forms other than the particular embodiment illustrated and all such forms may be encompassed within the claims of the present application. 
     While the present invention has been described with respect to a limited number of embodiments, those skilled in the art will appreciate numerous modifications and variations therefrom. It is intended that the appended claims cover all such modifications and variations as fall within the true spirit and scope of this present invention.