Abstract:
A method for recycling exhaust gas from Fischer-Tropsch synthesis. The method includes: 1) introducing raw gas to a shift reactor to conduct a water-gas shift reaction, and collecting shift gas; 2) introducing the shift gas to a Fischer-Tropsch synthesis device to yield a hydrocarbon fuel and exhaust gas, returning part of the exhaust gas as recycle gas; 3) introducing another part of the exhaust gas to a methanation reactor, allowing a methanation reaction to happen between the part of the exhaust gas and water vapor; 4) introducing a mixed gas product from the methanation reaction to a methane reforming reactor; 5) transporting the hydrogen and carbon monoxide resulting from the methane reforming reaction to a gas separator, separating the hydrogen and obtaining a mixed gas including carbon dioxide; and 6) returning the mixed gas including carbon dioxide to the methane reforming reactor.

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     This application is a continuation-in-part of International Patent Application No. PCT/CN2013/079219 with an international filing date of Jul. 11, 2013, designating the United States, now pending, and further claims priority benefits to Chinese Patent Application No. 201210246633.1 filed Jul. 17, 2012. The contents of all of the aforementioned applications, including any intervening amendments thereto, are incorporated herein by reference. Inquiries from the public to applicants or assignees concerning this document or the related applications should be directed to: Matthias Scholl P. C., Attn.: Dr. Matthias Scholl Esq., 245 First Street, 18th Floor, Cambridge, Mass. 02142. 
    
    
     BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The invention relates to a process for recycling exhaust gases from Fischer-Tropsch synthesis, thereby reducing carbon emissions. 
     2. Description of the Related Art 
     Typically, to improve the efficiency of the Fischer-Tropsch synthesis and to eliminate adverse effects of high CO concentration in the raw gas, incompletely reacted raw gas is returned to the inlet of the reactor to mix with fresh raw gas. However, the inert gas in the raw gas tends to accumulate in the reactor, which adversely affects the production efficiency. 
     The syngas from the gasification of biomass or coal often has a low hydrogen-carbon ratio, which cannot meet the requirement of the Fischer-Tropsch synthesis. In general, the raw gas is treated by water-gas shift reaction and decarbonization processes to regulate the hydrogen-carbon ratio for the Fischer-Tropsch synthesis. However, the gasification, the shift reaction, and the decarbonization are complex and require relatively high investment in the apparatus. In addition, the Fischer-Tropsch synthesis necessitates additional hydrogen for processing the product and reducing the catalyst, which increases the production costs. 
     SUMMARY OF THE INVENTION 
     In view of the above-described problems, it is one objective of the invention to provide a method for recycling exhaust gas from Fischer-Tropsch synthesis. The method can transform part of the exhaust gas into hydrogen, reduce the carbon dioxide emission, and supplies hydrogen source for the Fischer-Tropsch synthesis. The method has high production and economic efficiency. 
     To achieve the above objective, in accordance with one embodiment of the invention, there is provided a method for recycling exhaust gas from Fischer-Tropsch synthesis, the method comprising:
         1) introducing raw gas to a shift reactor to conduct a water-gas shift reaction in the presence of a catalyst, removing carbon dioxide produced from the water-gas shift reaction, and collecting shift gas;   2) introducing the shift gas to a Fischer-Tropsch synthesis device for Fischer-Tropsch synthesis, whereby yielding a hydrocarbon fuel and exhaust gas, returning part of the exhaust gas as recycle gas and mixing the recycle gas with the shift gas, and introducing mixed gas to the Fischer-Tropsch synthesis device;   3) introducing another part of the exhaust gas to a methanation reactor, allowing a methanation reaction to happen between the part of the exhaust gas and water vapor so that hydrocarbons having two or more carbon atoms are transformed into methane;   4) introducing a mixed gas product from the methanation reaction to a methane reforming reactor, allowing a methane reforming reaction to happen between the methane and water vapor in the presence of a reforming catalyst, to yield hydrogen and carbon monoxide;   5) transporting the hydrogen and carbon monoxide resulting from the methane reforming reaction to a gas separator, separating the hydrogen and obtaining a mixed gas comprising carbon dioxide and inert components; and   6) returning the mixed gas comprising the carbon dioxide and the inert components to the methane reforming reactor as a supplementary fuel to supply heat energy.       

     In a class of this embodiment, in step 5), part of the separated hydrogen is introduced as a supplement to the Fischer-Tropsch synthesis device according to one of the following modes: 
     a. the hydrogen is first mixed with the shift gas, and then with the recycle gas, and is introduced to the Fischer-Tropsch synthesis device; 
     b. the hydrogen is mixed with the raw gas to yield the shift gas through the water-gas shift reaction, the shift gas is mixed with the recycle gas, and then is introduced to the Fischer-Tropsch synthesis device; and 
     c. the hydrogen is first mixed with the recycle gas, and then with the shift gas, and is introduced to the Fischer-Tropsch synthesis device. 
     In a class of this embodiment, in step 5), part of the separated hydrogen is utilized according to one or more of the following modes: d) as a material for hydrofining of Fischer-Tropsch reaction products; e) as a material for hydrocracking of Fischer-Tropsch reaction products; and f) as a reducing agent of a catalyst of Fischer-Tropsch synthesis. 
     In a class of this embodiment, in step 1), the raw gas is from gasification of coal or biomass and comprises hydrogen and carbon monoxide with a molar ratio thereof of between 0.1 and 2.2; the shift gas is syngas comprising more than 50% (v/v) of active components comprising hydrogen and carbon monoxide, and a molar ratio of the hydrogen and the carbon monoxide is between 1.6 and 3.0. 
     In a class of this embodiment, in step 1), the molar ratio of the hydrogen and the carbon monoxide in the raw gas is between 0.1 and 1.1; the shift gas comprises more than 80% (v/v) of the active components, and the molar ratio of the hydrogen and the carbon monoxide is between 2.0 and 2.5. 
     In a class of this embodiment, in step 1), the water-gas shift reaction is conducted at a temperature of between 200 and 500° C. under a pressure of between 0 and 4.0 MPa, through which the carbon monoxide and water vapor in the raw gas react to yield hydrogen and carbon dioxide in the presence of the catalyst. 
     In a class of this embodiment, in step 2), the Fischer-Tropsch synthesis is conducted at a temperature of between 160 and 350° C. under a pressure of between 0.1 and 5.0 MPa, through which the shift gas is catalyzed by a Fe- or Co-based catalyst to yield the hydrocarbon fuel. 
     In a class of this embodiment, in step 3), the methanation reaction is conducted at a temperature of between 250 and 450° C. under a pressure of between 0 and 4.0 MPa in the presence of a Ni-based supported catalyst, and a molar ratio of the water vapor to the part of the exhaust gas is between 0.1 and 4. 
     In a class of this embodiment, in step 3), the molar ratio of the water vapor to the part of the exhaust gas is between 0.5 and 1.5. 
     In a class of this embodiment, in step 4), the methane reforming reaction is conducted at a temperature of between 500 and 1300° C. under a pressure of between 0 and 4.0 MPa in the presence of a Ni-based, Mo-based, or Ru-based supported catalyst. 
     In a class of this embodiment, in step 4), water vapor is added to the mixed gas product from the methanation reaction to regulate a molar ratio of the water vapor to the mixed gas product is between 0.1 and 4. 
     In a class of this embodiment, in step 4), the water vapor is added to the mixed gas product from the methanation reaction to regulate the molar ratio of the water vapor to the mixed gas product is between 0.1 and 1. 
     Advantages according to embodiments of the invention are summarized as follows. The method can transform part of the exhaust gas into hydrogen. Conventional reforming devices requires external heat source, but the recycled hydrogen in this invention can be combusted to supply heat energy for methane reforming reactor, thereby improving the energy utilization efficiency. Specifically, the advantages include: 
     1. The exhaust gas of the Fischer-Tropsch synthesis comprises a large amount of alkanes, alkenes, unreacted hydrogen, and carbon monoxide; recycling the exhaust gas can significantly improve the energy utilization efficiency and economic efficiency. 
     2. Inert gas, for example, nitrogen, in the raw gas, tends to accumulate in the Fischer-Tropsch synthesis reactor thereby affecting the reaction efficiency. If the noncyclic exhaust gas comprising inert gas is directly transformed into syngas, it is difficult to separate inert gas from carbon monoxide, however, the separation of hydrogen of the invention can solve the problem. 
     3. The methane reforming reaction is an endothermic reaction; the separated hydrogen can be combusted as heat source, so there is no need to introduce external heat source, thereby saving the energy costs. 
     4. The large amount of hydrogen produced from the methane reforming reaction is an important source for hydrofining and hydrocracking of Fischer-Tropsch reaction products. 
     5. The separated hydrogen from the methane reforming reaction can be added to the raw gas which often has low hydrogen-carbon ratio, which is beneficial to decreasing the transformation depth of the raw gas and lowering the requirements for the shift reactor, thereby improving the production capacity of the Fischer-Tropsch synthesis device and reducing the production costs, and providing hydrogen source for the Fischer-Tropsch synthesis. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a first flow chart of a method for recycling exhaust gas from Fischer-Tropsch synthesis in accordance with one embodiment of the invention; 
         FIG. 2  is a second flow chart of a method for recycling exhaust gas from Fischer-Tropsch synthesis in accordance with one embodiment of the invention; and 
         FIG. 3  is a third flow chart of a method for recycling exhaust gas from Fischer-Tropsch synthesis in accordance with one embodiment of the invention. 
     
    
    
     DETAILED DESCRIPTION OF THE EMBODIMENTS 
     For further illustrating the invention, experiments detailing a method for recycling exhaust gas from Fischer-Tropsch synthesis are described below. It should be noted that the following examples are intended to describe and not to limit the invention. 
     COMPARISON EXAMPLE 
     The example describes conventional Fischer-Tropsch synthesis where the produced noncyclic exhaust gas is not recycled. 
     1) Raw gas with low hydrogen-carbon ratio was introduced to a shift reactor at the flow rate of 5890 NM 3 /h. The molar ratio of hydrogen to carbon monoxide in the raw gas was 0.1. A water-gas shift reaction between the hydrogen and the carbon monoxide was conducted at the temperature of 300° C. and the pressure of 2.0 MPa. After the reaction, 2350 NM 3 /h of carbon monoxide was transformed into carbon dioxide, together with the generation of the same volume of hydrogen. Carbon dioxide and water vapor were removed, and 4480 NM 3 /h of shift gas was obtained. 
     2) The shift gas was transported into a Fischer-Tropsch synthesis device, where 0.65 t/h of hydrocarbon fuel was produced, and 1030 NM 3 /h of exhaust gas was discharged. 
     Table 1 lists the volume percentage of components of different mixed gas 
     
       
         
               
               
               
             
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 1 
               
             
             
               
                   
               
               
                   
                 Flow rate 
                 Components (% v/v) 
               
             
          
           
               
                   
                 (NM 3 /h)  
                 CO 
                 H 2   
                 CH 4   
                 C2+ 
                 CO 2   
                 N 2   
                 H 2 O 
               
               
                   
               
             
          
           
               
                 Raw gas 
                 5890 
                 61.2 
                 6.1 
                 2.2 
                   
                 23.9 
                 6.5 
                   
               
               
                 Shift gas 
                 4480 
                 28.1 
                 60.4 
                 2.9 
                   
                   
                 8.6 
                   
               
               
                 Noncyclic 
                 1030 
                 10.1 
                 21.0 
                 17.0 
                 2.5 
                 11.9 
                 37.5 
                   
               
               
                 exhaust gas 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                   
               
             
          
         
       
     
     Example 1 
     Raw gas involved in this example is the same as that in Comparison example, and the produced hydrogen is transported back to the shift reactor according to the flow chart in  FIG. 1 . 
     1) The raw gas was from the gasification of coal or biomass and comprised hydrogen and carbon monoxide with a molar ratio thereof of 0.1. The raw gas was introduced to a shift reactor at the flow rate of 5890 NM 3 /h. A water-gas shift reaction between the hydrogen and the carbon monoxide was conducted at the temperature of 300° C. and the pressure of 2.0 MPa to yield hydrogen and carbon dioxide. After the reaction, 2120 NM 3 /h of carbon monoxide was transformed into carbon dioxide, together with the generation of the same volume of hydrogen. Carbon dioxide was removed, and 4480 NM 3 /h of shift gas was obtained. The molar ratio of hydrogen to carbon monoxide in the shift gas was 1.7, and the shift gas comprises more than 88% (v/v) of active components. 
     2) The shift gas was mixed with 715 NM 3 /h of hydrogen resulting from a methane reforming reactor, and transported to a Fischer-Tropsch synthesis device for Fischer-Tropsch synthesis. The Fischer-Tropsch synthesis was conducted at the temperature of 300° C. under the pressure of 2.5 MPa in the presence of a Fe-based catalyst. Thereafter, 0.75 t/h of hydrocarbon fuel was produced, and 1150 NM 3 /h of noncyclic exhaust gas was discharged. Part of the exhaust gas was pumped as recycle gas, which was mixed with the shift gas and then introduced to the Fischer-Tropsch synthesis device. 
     3) The noncyclic exhaust gas with a flow rate of 1150 NM 3 /h was mixed with water vapor with a flow rate of 345 NM 3 /h. The resulting mixed gas was cooled to 300° C. and introduced to a methanation reactor for methanation reaction. The methanation reaction was conducted at the temperature of 300° C. under the pressure of 2.0 MPa in the presence of a Ni-based supported catalyst, and the molar ratio of the water vapor to the noncyclic exhaust gas was 0.3. After the reaction, hydrocarbons having two or more carbon atoms were transformed into methane, and the mixed gas product (outlet gas) of the methanation reactor had a flow rate of 1330 NM 3 /h. 
     4) The outlet gas of the methanation reactor was transported to a subsequent dividing wall type methane reforming reactor. Water vapor was added to the mixed gas product from the methanation reaction to regulate the molar ratio of the water vapor to the mixed gas product was 2. The methane reforming reaction between the methane and water vapor was conducted at the temperature of 800° C. under the pressure of 2.0 MPa in the presence of a Ni-based supported catalyst, to yield hydrogen and carbon monoxide. The gas product from the methane reforming reactor was cooled to 45° C. and dehydrated, and had a flow rate of 1830 NM 3 /h. 
     5) The gas product from the methane reforming reactor was introduced to a pressure swing adsorption separation device, and 735 NM 3 /h of high purity hydrogen and 10807 NM 3 /h of a mixed gas comprising carbon dioxide and inert components were separated. 715 NM 3 /h of the high purity hydrogen was mixed with the raw gas and transformed into the shift gas through the water-gas shift reaction. The shift gas was mixed with recycle gas and then introduced to the Fischer-Tropsch synthesis device. The remaining 20 NM 3 /h of high purity hydrogen was utilized as a reducing agent of the catalyst of Fischer-Tropsch synthesis. 
     6) The mixed gas comprising carbon dioxide and inert components from the pressure swing adsorption separation device was mixed with 450 NM 3 /h of 93% v/v oxygen. The mixed gas was sprayed via a nozzle into a dividing wall of the methane reforming reactor and combusted to heat the methane reforming reactor. 
     In this example, due to the supplementation of hydrogen to the raw gas, the carbon dioxide emission from the water-gas shift reaction was decreased by 230 NM 3 /h, and the yield of the hydrocarbon fuel from the Fischer-Tropsch synthesis was increased from 0.65 t/h to 0.75 t/h, which was increased by 16%. 
     Table 2 lists the volume percentage of components of different mixed gas in Example 1. 
     
       
         
               
               
               
             
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 2 
               
             
             
               
                   
               
               
                   
                 Flow rate 
                 Components (% v/v) 
               
             
          
           
               
                   
                 (NM 3 /h) 
                 CO 
                 H 2   
                 CH 4   
                 C2+ 
                 CO 2   
                 N 2   
                 H 2 O 
               
               
                   
               
             
          
           
               
                 Raw gas 
                 5890 
                 61.2 
                 6.1 
                 2.2 
                   
                 23.9 
                 6.5 
                   
               
               
                 Shift gas 
                 4480 
                 33.2 
                 55.4 
                 2.9 
                   
                   
                 8.6 
                   
               
               
                 Noncyclic  
                 1150 
                 10.1 
                 21.0 
                 17.0 
                 2.5 
                 11.9 
                 37.5 
                   
               
               
                 exhaust gas 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Mixed  
                 1330 
                 8.5 
                 12.6 
                 21.9 
                   
                 10.2 
                 31.9 
                 14.9 
               
               
                 gas product 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 from  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 methanation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reactor 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Gas product  
                 1830 
                 27.1 
                 47.6 
                 1 
                   
                 1.3 
                 23.1 
                   
               
               
                 from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 methane  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reforming 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reactor 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Hydrogen  
                 735 
                   
                 99.9 
                   
                   
                   
                   
                   
               
               
                 from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 pressure  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 swing 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 adsorption  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 separation  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 device 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Mixed gas  
                 1080 
                 45.5 
                 12 
                 1.7 
                   
                 2.2 
                 38.7 
                   
               
               
                 from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 pressure  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 swing 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 adsorption 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 separation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 device 
               
               
                   
               
             
          
         
       
     
     Example 2 
     The treatment method of the exhaust gas in this example is the same as that in Example 1, and the produced hydrogen is transported back to the shift reactor according to the flow chart in  FIG. 1 . 
     1) The raw gas was from the gasification of coal or biomass and comprised hydrogen and carbon monoxide with a molar ratio thereof of 1.1. The raw gas was introduced to a shift reactor at the flow rate of 5950 NM 3 /h. A water-gas shift reaction between the hydrogen and the carbon monoxide was conducted at the temperature of 200° C. and the pressure of 1.0 MPa to yield hydrogen and carbon dioxide. After the reaction, 256 NM 3 /h of carbon monoxide was transformed into carbon dioxide, together with the generation of the same volume of hydrogen. Carbon dioxide was removed, and 4530 NM 3 /h of shift gas was obtained. The molar ratio of hydrogen to carbon monoxide in the shift gas was 1.43, and the shift gas comprises more than 88% (v/v) of active components. 
     2) The shift gas was mixed with 1150 NM 3 /h of hydrogen resulting from a methane reforming reactor, and transported to a Fischer-Tropsch synthesis device for Fischer-Tropsch synthesis. The Fischer-Tropsch synthesis was conducted at the temperature of 160° C. under the pressure of 0.1 MPa in the presence of a Co-based catalyst. Thereafter, 0.27 t/h of hydrocarbon fuel was produced, and 2420 NM 3 /h of noncyclic exhaust gas was discharged. Part of the exhaust gas was pumped as recycle gas, which was mixed with the shift gas and then introduced to the Fischer-Tropsch synthesis device. 
     3) The noncyclic exhaust gas with a flow rate of 2420 NM 3 /h was mixed with water vapor with a flow rate of 240 NM 3 /h. The resulting mixed gas was cooled to 250° C. and introduced to a methanation reactor for methanation reaction. The methanation reaction was conducted at the temperature of 250° C. under the pressure of 1.0 MPa in the presence of a Ni-based supported catalyst, and the molar ratio of the water vapor to the noncyclic exhaust gas was 0.1. After the reaction, hydrocarbons having two or more carbon atoms were transformed into methane, and the mixed gas product (outlet gas) of the methanation reactor had a flow rate of 2660 NM 3 /h. 
     4) The outlet gas of the methanation reactor was transported to a subsequent dividing wall type methane reforming reactor. Water vapor was added to the mixed gas product from the methanation reaction to regulate the molar ratio of the water vapor to the mixed gas product was 4. The methane reforming reaction between the methane and water vapor was conducted at the temperature of 500° C. under the pressure of 1.0 MPa in the presence of a Ni-based supported catalyst, to yield hydrogen and carbon monoxide. The gas product from the methane reforming reactor had a flow rate of 12400 NM 3 /h. 
     5) The gas product from the methane reforming reactor was cooled to 45° C. and dehydrated, and introduced to a pressure swing adsorption separation device. 1180 NM 3 /h of high purity hydrogen and 1780 NM 3 /h of a mixed gas comprising carbon dioxide and inert components were separated. 540 NM 3 /h of the high purity hydrogen was mixed with the raw gas and transformed into the shift gas through the water-gas shift reaction. The shift gas was mixed with recycle gas and then introduced to the Fischer-Tropsch synthesis device. 400 NM 3 /h of the high purity hydrogen was utilized for hydrofining and hydrocracking of Fischer-Tropsch reaction products. The remaining 240 NM 3 /h of high purity hydrogen was utilized as a reducing agent of the catalyst of Fischer-Tropsch synthesis. 
     6) The mixed gas comprising carbon dioxide and inert components from the pressure swing adsorption separation device was mixed with 950 NM 3 /h of 93% v/v oxygen. The mixed gas was sprayed via a nozzle into a dividing wall of the methane reforming reactor and combusted to heat the methane reforming reactor. 
     Table 3 lists the volume percentage of components of different mixed gas in Example 2. 
     
       
         
               
               
               
             
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 3 
               
             
             
               
                   
               
               
                   
                 Flow rate 
                 Components (% v/v) 
               
             
          
           
               
                   
                 (NM 3 /h) 
                 CO 
                 H 2    
                 CH 4   
                 C2+ 
                 CO 2   
                 N 2   
                 H 2 O 
               
               
                   
               
             
          
           
               
                 Raw gas 
                 5950 
                 32 
                 35.4 
                 2.2 
                   
                 23.9 
                 6.5 
                   
               
               
                 Shift gas 
                 4530 
                 36.4 
                 52.2 
                 2.9 
                 0.0 
                 0.0 
                 8.5 
                   
               
               
                 Noncyclic 
                 2420 
                 19.5 
                 37.3 
                 14.7 
                 1.2 
                 11.4 
                 15.9 
                   
               
               
                 exhaust gas 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Mixed gas 
                 2660 
                 17.7 
                 31.8 
                 16.6 
                   
                 10.4 
                 14.5 
                 0.9 
               
               
                 product  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 methanation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reactor 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Gas product 
                 12400 
                 0.2 
                 11.2 
                 3.4 
                   
                 6 
                 3.1 
                 76.1 
               
               
                 from methane 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reforming  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reactor 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Hydrogen  
                 1180 
                   
                 99.9 
                   
                   
                   
                   
                   
               
               
                 from pressure 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 swing 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 adsorption 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 separation  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 device 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Mixed gas  
                 1780 
                 1.4 
                 11.7 
                 23.7 
                   
                 41.8 
                 21.6 
                   
               
               
                 from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 pressure  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 swing 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 adsorption 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 separation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 device 
               
               
                   
               
             
          
         
       
     
     In this example, due to the supplementation of hydrogen to the raw gas, the carbon dioxide emission from the water-gas shift reaction was decreased by 375 NM 3 /h, the yield of the hydrocarbon fuel from the Fischer-Tropsch synthesis was increased from 0.21 t/h to 0.27 t/h, which was increased by 29%. 
     Example 3 
     Raw gas involved in this example is listed in Table 4, and the produced hydrogen is transported back to the Fischer-Tropsch synthesis device according to the flow chart in  FIG. 2 . 
     1) The raw gas was from the gasification of coal or biomass and comprised hydrogen and carbon monoxide with a molar ratio thereof of 2.2. The raw gas was introduced to a shift reactor at the flow rate of 5900 NM 3 /h. A water-gas shift reaction between the hydrogen and the carbon monoxide was conducted at the temperature of 500° C. and the pressure of 4.0 MPa to yield hydrogen and carbon dioxide. After the reaction, 300 NM 3 /h of carbon monoxide was transformed into carbon dioxide, together with the generation of the same volume of hydrogen. Carbon dioxide was removed, and 5090 NM 3 /h of shift gas was obtained. The molar ratio of hydrogen to carbon monoxide in the shift gas was 3.0, and the shift gas comprises more than 95% (v/v) of active components. 
     2) The shift gas was mixed with 100 NM 3 /h of hydrogen resulting from a methane reforming reactor, and transported to a Fischer-Tropsch synthesis device for Fischer-Tropsch synthesis. The Fischer-Tropsch synthesis was conducted at the temperature of 350° C. under the pressure of 5 MPa in the presence of a Co-based catalyst. Thereafter, 0.72 t/h of hydrocarbon fuel was produced, and 350 NM 3 /h of noncyclic exhaust gas was discharged. Part of the exhaust gas was pumped as recycle gas, which was mixed with the shift gas and then introduced to the Fischer-Tropsch synthesis device. 
     3) The noncyclic exhaust gas with a flow rate of 350 NM 3 /h was mixed with water vapor with a flow rate of 35 NM 3 /h. The resulting mixed gas was cooled to 450° C. and introduced to a methanation reactor for methanation reaction. The methanation reaction was conducted at the temperature of 450° C. under the pressure of 4.0 MPa in the presence of a Ni-based supported catalyst, and the molar ratio of the water vapor to the noncyclic exhaust gas was 0.1. After the reaction, hydrocarbons having two or more carbon atoms were transformed into methane, and the mixed gas product (outlet gas) of the methanation reactor had a flow rate of 384 NM 3 /h. 
     4) The outlet gas of the methanation reactor was transported to a subsequent dividing wall type methane reforming reactor. Water vapor was added to the mixed gas product from the methanation reaction to regulate the molar ratio of the water vapor to the mixed gas product was 0.1. The methane reforming reaction between the methane and water vapor was conducted at the temperature of 1300° C. under the pressure of 4.0 MPa in the presence of a Ru-based supported catalyst, to yield hydrogen and carbon monoxide. The gas product from the methane reforming reactor had a flow rate of 486 NM 3 /h. 
     5) The gas product from the methane reforming reactor was cooled to 45° C. and dehydrated, and introduced to a pressure swing adsorption separation device. 189 NM 3 /h of high purity hydrogen and 297 NM 3 /h of a mixed gas comprising carbon dioxide and inert components were separated. 124 NM 3 /h of the high purity hydrogen was first mixed with the shift gas, and then mixed with recycle gas, and introduced to the Fischer-Tropsch synthesis device. 50 NM 3 /h of the high purity hydrogen was utilized for hydrofining and hydrocracking of Fischer-Tropsch reaction products. The remaining 15 NM 3 /h of high purity hydrogen was utilized as a reducing agent of the catalyst of Fischer-Tropsch synthesis. 
     6) The mixed gas comprising carbon dioxide and inert components from the pressure swing adsorption separation device was mixed with 150 NM 3 /h of 93% v/v oxygen. The mixed gas was sprayed via a nozzle into a dividing wall of the methane reforming reactor and combusted to heat the methane reforming reactor. 
     Table 4 lists the volume percentage of components of different mixed gas in Example 3. 
     
       
         
               
               
               
             
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 4 
               
             
             
               
                   
               
               
                   
                 Flow rate 
                 Components (% v/v) 
               
             
          
           
               
                   
                 (NM 3 /h) 
                 CO 
                 H 2   
                 CH 4   
                 C2+ 
                 CO 2   
                 N 2   
                 H 2 O 
               
               
                   
               
             
          
           
               
                 Raw gas 
                 5900 
                 25.8 
                 56.9 
                 1.3 
                   
                 13.8 
                 2.2 
                   
               
               
                 Shift gas 
                 5090 
                 24.0 
                 71.9 
                 1.5 
                 0.0 
                 0.0 
                 2.6 
                   
               
               
                 Noncyclic 
                 350 
                 7.2 
                 24.3 
                 25.8 
                 1.7 
                 3.2 
                 37.8 
                   
               
               
                 exhaust gas 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Mixed gas 
                 384 
                 6.5 
                 19.0 
                 28.1 
                   
                 2.9 
                 34.4 
                 9.1 
               
               
                 product from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 methanation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reactor 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Gas product 
                 486 
                 17.6 
                 43.1 
                 12.1 
                   
                   
                 27.2 
                   
               
               
                 from methane 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reforming  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reactor 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Hydrogen  
                 189 
                   
                 99.9 
                   
                   
                   
                   
                   
               
               
                 from pressure  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 swing 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 adsorption 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 separation  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 device 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Mixed gas  
                 297 
                 28.8 
                 6.9 
                 19.8 
                 0.0 
                 0.0 
                 44.5 
                   
               
               
                 from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 pressure  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 swing 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 adsorption 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 separation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 device 
               
               
                   
               
             
          
         
       
     
     In this example, due to the supplementation of hydrogen to the raw gas, the yield of the hydrocarbon fuel from the Fischer-Tropsch synthesis was increased from 0.72 t/h to 0.73 t/h, which was increased by 2%. 
     Example 4 
     The treatment method of the exhaust gas in this example is the same as that in Example 3, and the produced hydrogen is transported back to the Fischer-Tropsch synthesis device according to the flow chart in  FIG. 2 . 
     1) The raw gas was from the gasification of coal or biomass and comprised hydrogen and carbon monoxide with a molar ratio thereof of 1. The raw gas was introduced to a shift reactor at the flow rate of 6000 NM 3 /h. A water-gas shift reaction between the hydrogen and the carbon monoxide was conducted at the temperature of 400° C. and the pressure of 3.0 MPa to yield hydrogen and carbon dioxide. After the reaction, 1010 NM 3 /h of carbon monoxide was transformed into carbon dioxide, together with the generation of the same volume of hydrogen. Carbon dioxide was removed, and 5874 NM 3 /h of shift gas was obtained. The molar ratio of hydrogen to carbon monoxide in the shift gas was 2.5, and the shift gas comprises more than 80% (v/v) of active components. 
     2) The shift gas was mixed with 1300 NM 3 /h of hydrogen resulting from a methane reforming reactor, and transported to a Fischer-Tropsch synthesis device for Fischer-Tropsch synthesis. The Fischer-Tropsch synthesis was conducted at the temperature of 250° C. under the pressure of 3.5 MPa in the presence of a Co-based catalyst. Thereafter, 0.69 t/h of hydrocarbon fuel was produced, and 2120 NM 3 /h of noncyclic exhaust gas was discharged. Part of the exhaust gas was pumped as recycle gas, which was mixed with the shift gas and then introduced to the Fischer-Tropsch synthesis device. 
     3) The noncyclic exhaust gas with a flow rate of 2120 NM 3 /h was mixed with water vapor with a flow rate of 3180 NM 3 /h. The resulting mixed gas was cooled to 400° C. and introduced to a methanation reactor for methanation reaction. The methanation reaction was conducted at the temperature of 400° C. under the pressure of 3.0 MPa in the presence of a Ni-based supported catalyst, and the molar ratio of the water vapor to the noncyclic exhaust gas was 1.5. After the reaction, hydrocarbons having two or more carbon atoms were transformed into methane, and the mixed gas product (outlet gas) of the methanation reactor had a flow rate of 5300 NM 3 /h. 
     4) The outlet gas of the methanation reactor was transported to a subsequent dividing wall type methane reforming reactor. Water vapor was added to the mixed gas product from the methanation reaction to regulate the molar ratio of the water vapor to the mixed gas product was 3. The methane reforming reaction between the methane and water vapor was conducted at the temperature of 900° C. under the pressure of 2.5 MPa in the presence of a Mo-based supported catalyst, to yield hydrogen and carbon monoxide. The gas product from the methane reforming reactor had a flow rate of 9005 NM 3 /h. 
     5) The gas product from the methane reforming reactor was cooled to 45° C. and dehydrated, and introduced to a pressure swing adsorption separation device. 1450 NM 3 /h of high purity hydrogen and 1780 NM 3 /h of a mixed gas comprising carbon dioxide and inert components were separated. 1050 NM 3 /h of the high purity hydrogen was first mixed with the shift gas, and then mixed with recycle gas, and introduced to the Fischer-Tropsch synthesis device. 325 NM 3 /h of the high purity hydrogen was utilized for hydrofining and hydrocracking of Fischer-Tropsch reaction products. The remaining 75 NM 3 /h of high purity hydrogen was utilized as a reducing agent of the catalyst of Fischer-Tropsch synthesis. 
     6) The mixed gas comprising carbon dioxide and inert components from the pressure swing adsorption separation device was mixed with 200 NM 3 /h of 93% v/v oxygen. The mixed gas was sprayed via a nozzle into a dividing wall of the methane reforming reactor and combusted to heat the methane reforming reactor. 
     Table 5 lists the volume percentage of components of different mixed gas in Example 4. 
     
       
         
               
               
               
             
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 5 
               
             
             
               
                   
               
               
                   
                 Flow rate 
                 Components (% v/v) 
               
             
          
           
               
                   
                 (NM 3 /h) 
                 CO 
                 H 2   
                 CH 4   
                 C2+ 
                 CO 2   
                 N 2   
                 H 2 O 
               
               
                   
               
             
          
           
               
                 Raw gas 
                 6000 
                 39.3  
                 39.2 
                 1.7 
                   
                 2.1 
                 17.7 
                   
               
               
                 Shift gas 
                 5874.0 
                 22.9 
                 57.3 
                 1.7 
                 0.0 
                 0.0 
                 18.1 
                 0.0 
               
               
                 Noncyclic 
                 2120.0 
                 9.9 
                 23.4 
                 11.5 
                 0.3 
                 4.8 
                 50.1 
                   
               
               
                 exhaust gas 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Mixed gas 
                 5300 
                 4.0 
                 9.1 
                 5.0 
                   
                 1.9  
                 20.0 
                 60.0 
               
               
                 product from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 methanation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reactor 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Gas product 
                 9005 
                 1.7 
                 17.7 
                   
                   
                 4.7 
                 11.8 
                 64.2 
               
               
                 from methane 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reforming  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reactor 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Hydrogen  
                 1450 
                   
                 99.9 
                   
                   
                   
                   
                   
               
               
                 from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 pressure  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 swing 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 adsorption 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 separation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 device 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Mixed gas 
                 1780 
                 8.6 
                 8.0 
                 0.0 
                 0.0 
                 23.8 
                 59.6 
                   
               
               
                 from pressure 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 swing 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 adsorption 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 separation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 device 
               
               
                   
               
             
          
         
       
     
     In this example, due to the supplementation of hydrogen to the raw gas, the yield of the hydrocarbon fuel from the Fischer-Tropsch synthesis was increased from 0.56 t/h to 0.69 t/h, which was increased by 24%. 
     Example 5 
     Raw gas involved in this example is listed in Table 6, and the produced hydrogen is first mixed with cycle gas and then transported back to the Fischer-Tropsch synthesis device according to the flow chart in  FIG. 3 . 
     1) The raw gas was from the gasification of coal or biomass and comprised hydrogen and carbon monoxide with a molar ratio thereof of 2.2. The raw gas was introduced to a shift reactor at the flow rate of 5500 NM 3 /h. A water-gas shift reaction between the hydrogen and the carbon monoxide was conducted at the temperature of 500° C. and the pressure of 4.0 MPa to yield hydrogen and carbon dioxide. After the reaction, 164 NM 3 /h of carbon monoxide was transformed into carbon dioxide, together with the generation of the same volume of hydrogen. Carbon dioxide was removed, and 4970 NM 3 /h of shift gas was obtained. The molar ratio of hydrogen to carbon monoxide in the shift gas was 3.0, and the shift gas comprises more than 50% (v/v) of active components. 
     2) The shift gas was mixed with hydrogen resulting from a methane reforming reactor with a flow rate of 715 NM 3 /h, and transported to a Fischer-Tropsch synthesis device for Fischer-Tropsch synthesis. The Fischer-Tropsch synthesis was conducted at the temperature of 350° C. under the pressure of 5 MPa in the presence of a Fe-based catalyst. Thereafter, 0.18 t/h of hydrocarbon fuel was produced, and 3100 NM 3 /h of noncyclic exhaust gas was discharged. Part of the exhaust gas was pumped as recycle gas, which was mixed with the shift gas and then introduced to the Fischer-Tropsch synthesis device. 
     3) The noncyclic exhaust gas with a flow rate of 3100 NM 3 /h was mixed with water vapor with a flow rate of 9300 NM 3 /h. The resulting mixed gas was cooled to 450° C. and introduced to a methanation reactor for methanation reaction. The methanation reaction was conducted at the temperature of 450° C. under the pressure of 4.0 MPa in the presence of a Ni-based supported catalyst, and the molar ratio of the water vapor to the noncyclic exhaust gas was 4. After the reaction, hydrocarbons having two or more carbon atoms were transformed into methane, and the mixed gas product (outlet gas) of the methanation reactor had a flow rate of 12400 NM 3 /h. 
     4) The outlet gas of the methanation reactor was transported to a subsequent dividing wall type methane reforming reactor. Water vapor was added to the mixed gas product from the methanation reaction to regulate the molar ratio of the water vapor to the mixed gas product was 4. The methane reforming reaction between the methane and water vapor was conducted at the temperature of 1300° C. under the pressure of 4.0 MPa in the presence of a Ni-based supported catalyst, to yield hydrogen and carbon monoxide. The gas product from the methane reforming reactor had a flow rate of 12700 NM 3 /h. 
     5) The gas product from the methane reforming reactor was cooled to 45° C. and dehydrated, and introduced to a pressure swing adsorption separation device. 630 NM 3 /h of high purity hydrogen and 2025 NM 3 /h of a mixed gas comprising carbon dioxide and inert components were separated. 440 NM 3 /h of the high purity hydrogen was first mixed with the cycle gas, and then mixed with the shift gas, and introduced to the Fischer-Tropsch synthesis device. 150 NM 3 /h of the high purity hydrogen was utilized for hydrofining and hydrocracking of Fischer-Tropsch reaction products. The remaining 40 NM 3 /h of high purity hydrogen was utilized as a reducing agent of the catalyst of Fischer-Tropsch synthesis. 
     6) The mixed gas comprising carbon dioxide and inert components from the pressure swing adsorption separation device was mixed with 150 NM 3 /h of 93% v/v oxygen. The mixed gas was sprayed via a nozzle into a dividing wall of the methane reforming reactor and combusted to heat the methane reforming reactor. 
     Table 6 lists the volume percentage of components of different mixed gas in Example 5. 
     
       
         
               
               
               
             
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 6 
               
             
             
               
                   
               
               
                   
                 Flow rate 
                 Components (% v/v) 
               
             
          
           
               
                   
                 (NM 3 /h) 
                 CO 
                 H 2   
                 CH 4   
                 C2+ 
                 CO 2   
                 N 2   
                 H 2 O 
               
               
                   
               
             
          
           
               
                 Raw gas 
                 5500 
                 14.7 
                 32.2 
                 0.3 
                   
                 9.7 
                 43.1 
                   
               
               
                 Shift gas 
                 4966.5 
                 13.0 
                 39.0 
                 0.3 
                 0.0 
                 0.0 
                 47.7 
                   
               
               
                 Noncyclic 
                 3100.0 
                 4.1 
                 11.3 
                 4.1 
                 0.3 
                 3.8 
                 76.4 
                   
               
               
                 exhaust gas 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Mixed gas 
                 12400 
                 1.0 
                 2.8 
                 1.0 
                   
                 1.0 
                 19.1 
                 75.0 
               
               
                 product from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 methanation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reactor 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Gas product 
                 12700 
                 0.8 
                 7.7 
                   
                   
                 2.4 
                 18.6 
                 70.5 
               
               
                 from methane 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reforming  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 reactor 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Hydrogen  
                 630 
                   
                 99.9 
                   
                   
                   
                   
                   
               
               
                 from 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 pressure  
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 swing 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 adsorption 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 separation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 device 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Mixed gas 
                 2025 
                 3.6 
                 3.1 
                 0.0 
                 0.0 
                 10.7 
                 82.7 
                   
               
               
                 from pressure 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 swing 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 adsorption 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 separation 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 device 
               
               
                   
               
             
          
         
       
     
     In this example, due to the supplementation of hydrogen to the raw gas, the yield of the hydrocarbon fuel from the Fischer-Tropsch synthesis was increased from 0.16 t/h to 0.18 t/h, which was increased by 13%. 
     The working principle and working process of the invention are summarized as follows. The raw gas is transformed in the shift reactor and then introduced to a Fischer-Tropsch synthesis device for reaction to yield hydrocarbon fuel and exhaust gas. Part of the exhaust gas is used as recycle gas and transported back to the outlet of the Fischer-Tropsch synthesis device. The other part of the exhaust gas is mixed and reacts with water vapor in a methanation reactor. The produced mixed gas is introduced to a methane reforming reactor where methane and water vapor react to produce a first mixed gas comprising carbon monoxide and hydrogen. The first mixed gas comprising carbon monoxide and hydrogen is introduced to a separation device and thus high purity hydrogen and a second mixed gas comprising carbon monoxide. The second mixed gas comprising carbon monoxide is combusted to supply heat energy for the methane reforming reactor. The high purity hydrogen can be utilized for the deep processing or deacidification of Fischer-Tropsch synthesis products, and part of the hydrogen is mixed with the raw gas to participate in the Fischer-Tropsch synthesis. The method employs syngas as the raw gas in the Fischer-Tropsch synthesis and recycles the exhaust gas, specifically, to separate hydrogen from the exhaust gas, thereby reducing the carbon dioxide emission and providing new hydrogen source for the Fischer-Tropsch synthesis, with high production and economic efficiency. The invention involves a Fischer-Tropsch synthesis and methane reforming device, which can transform light hydrocarbon-rich exhaust gas into hydrogen which is separated and purified for the Fischer-Tropsch synthesis. 
     While particular embodiments of the invention have been shown and described, it will be obvious to those skilled in the art that changes and modifications may be made without departing from the invention in its broader aspects, and therefore, the aim in the appended claims is to cover all such changes and modifications as fall within the true spirit and scope of the invention.