Abstract:
A catalyst for the selective reduction of nitrogen oxides to nitrogen in the presence of ammonia in the form of composite bodies formed from a mixture of anatase (5 to 40% by weight), a zeolite (50 to 90%), a bond material (0 to 30%, and, optionally, promoter selected from oxides of vanadium, molybdenum, and copper, in the amount of at least 0.1% by weight.

Description:
This application is a continuation-in-part of copending application Ser. No. 06/789,690 filed Oct. 22, 1985, now abandoned. 
    
    
     BACKGROUND OF THE INVENTION 
     All fossil fuel combustion processes generate nitrogen oxides (NOx). The probability that these NOx emissions contribute to the &#34;acid rain&#34; problem, coupled with increased public awareness, prompted the search for catalytic materials which reduce NOx atmospheric emissions. 
     Pence U.S. Pat. No. 4,220,632 and Carter U.S. Pat. No. 3,895,094 disclose the use of zeolites in the selective catalytic reduction of oxides of nitrogen (NOx) in the presence of ammonia or other reducing agent. U.S. Pat. No. 4,085,193 to Nakajima et al teaches the use of titania in the presence of vanadia and other metal oxides for the same purpose. Kittrell et al U.S. Pat. No. 4,473,535 teaches copper exchanged zeolite (mordenite) for the same purpose. Many other patents have issued in recent years teaching the reduction of NOx content of exhaust gases. Many NOx containing streams also contain sulfur oxides (SOx) which can adversely affect SCR catalyst performance. It is highly desirable that an SCR catalyst be resistant to poisoning by SOx. The present invention relates to an improved catalyst for the selective catalytic reduction (SCR) of oxides of nitrogen in the presence of a reducing gas such as ammonia in exhaust gas streams, especially those containing SOx. 
     DESCRIPTION OF THE INVENTION 
     We have discovered that an NOx selective catalytic reduction catalyst of improved efficiency and stability to poisoning by SOx can be produced by the combination of high surface area titania in the form of anatase, with a natural or synthetic zeolite. The material are mixed, formed, dried, and fired into a desired shape such as rings or honeycombs, with or without the addition of a ceramic bonding material. The firing takes place at a temperature below the stability limit of the zeolite to form a monolithic body. The anatase starting material should have a surface area (as measured by the B.E.T. method) of at least 100 square meters per gram, and a sulfate content as measured by weight percent of sulfate of at least 0.25. Such anatase is conveniently made from hydrolysis of titanyl sulfate, produced in the sulfate process for the production of TiO2 from titanium bearing ores. Alternatively, sulfate could be added to the hydrolysis product of one or more titanium salts or sulfur can later be absorbed into the titania or into the finished catalyst from a sulfur containing precursor. 
     The preferred amount of titania in the product is 10 to 30% by weight with an optimum at 20% titania content for a mix containing 10% bond material. The operative range of titania is from 5 to 40% depending upon other factors. The zeolite should be present in the amount of 50 to 90%. Bond may be present, 0 to 30%. 
     The catalyst can be further enhanced by the addition of small amounts of promoter in the form of precursors of vanadium oxide, copper oxide, molybdenum oxide or combinations thereof. For the best stability in the presence of SO2, the vanadium and/or molybdenum addition is preferred. 
     A preferred zeolite is natural clinoptilolite which may be mixed with another acid stable zeolite such as chabazite. The zeolite must be either in the acid form or thermally convertible to the acid form in the catalytic product. This form may be produced directly by acid exchange or indirectly by ammonium exchange followed by heating to drive off ammonia and convert the material to the hydrogen form. Zeolites which are useful in this invention are those which can be produced in the hydrogen form by either method and which are stable when in the hydrogen form. Certain zeolites such as zeolite A and sodalite are not stable in the acid form and are not effective in this invention. Examples of zeolites which can be prepared by ammonia and/or acid exchange are mordenite, clinoptilolite, erionite, heulandite, and ferrierite. Zeolites which can be prepared better or only by the ammonium exchange route are natural faujasite and its synthetic counterpart zeolite Y, chabazite and gmelinite. 
     Mixtures of zeolites may also be used. Other hydrogen form zeolites, such as those of the ZSM series, are prepared by the thermal decomposition of organic templates and are also suitable for use in the catalytic compositions of this invention. 
     In use the exhaust gas, containing a suitable reducing gas such as ammonia, is passed over the catalyst. Depending upon the requirements of the particular application, the catalyst may be in the form of honeycombs, stacked and arranged, if plural, to provide a through flow path for the gases. Or it may be in the form of randomly dumped saddles, rings, stars, cross partition rings, pellets, or aggregates. The treated flue gas should be at least 200° C. to prevent deposition of ammonium salts, and may be as high as 650° C. The space velocity is not cititcal. Typically at 10,000 hourly space velocity (gas volume calculated to standard temperature and pressure) a 1600 ppm NOx content can be reduced by over 90% at 350° C. 
    
    
     DESCRIPTION OF SPECIFIC EMBODIMENTS 
     Example 
     Catalyst Preparation 
     A composition for making nominal 1/4 inch rings with 1/8 inch holes was prepared by mixing dry powders consisting of 4,000 grams of a powdered ammonium form of clinoptilolite with 500 g of microcrystalline boehmite powder (bond), and 577 g parts of hydrous titanium oxide powder (hydrolysate from the sulfate process, dried at low temperature). Water was added in the amount of 800 ml. and mixing was continued for 10 minutes. 
     Concentrated nitric acid, 106 ml, is added and the mixing continued for another ten minutes. Additional water may be added to adjust the consistency of the mix. When the mix is to be extruded 0.2% of an organic cationic polymer extrusion aid may be added after the mix is wet. 
     After extrusion the rings are dried in an air atmosphere for one to two hours ato 200 F. The final firing takes place at 1,000 F. for five hours. 
     When it is desired to incorporate promoter or promoters into the composition the promoter precursor may be added during the mixing operation, or may be impregnated into the formed product after firing. The added promoter or promoters should be present in an amount of at least 0.1% by elemental weight, as the oxide or oxides. 
     Various products were made according to the methods of the Example. 
     Table I shows the composition of a variety of catalysts made as described above, with varying amounts of zeolite, TiO 2  (anatase), binder, and promoter. 
     Table I shows the composition of a variety of catalysts made as described above, with varying amounts of zeolite, TiO 2  (anatase), binder, and promoter. 
     
                       TABLE I______________________________________SELECTIVE CATALYTIC REDUCTIONCATALYST COMPOSITIONS     Weight %Sample No.  Zeolite.sup.(1)                TiO.sub.2                         Binder                               Promoter______________________________________65233 (Control)       90        0       1065309       80       10       1065379       80       10       1065390       70       20       1065389       60       30       1065377       45       45       1065383       80       20        065393*      70       20       1036316       70       20       10    0.1 V65385       80       10       10    0.4 V65308       80       10       10    1.6 V36309       80       10       10     0.2 Cu65284       80       10       10    0.4 V65284**     80       10       10    0.4 V______________________________________ .sup.(1) Except for Sample No. 65393 the zeolite was a blend of clinoptilolite and chabazite in the ammonium form. *100% Clinoptilolite  NH4 + exchanged form. **Sample 65284 contained a TiO.sub.2 of lower surface area than the other catalysts. 
    
     The SO 2  concentrations were varied with time. The catalysts initial NOx reduction activity without SO 2  in the stream was measured over a 24 hour period and is listed in Table II, column 2. Then, 50 ppm SO 2  was added to the stream and the NOx reduction efficiency measured after an additional 24 hours with the results shown in column 3. Then, this SO 2  concentration was increased to 1600 ppm and the NOx reduction efficiency measured at 24 and 48 hours and shown in columns 4 and 5 respectively. 
     The test conditions were: 
     
         ______________________________________Temperature, C.          350Oxygen concentration, Vol. %                     5NOx concentration, volume parts per million                    500NH.sub.3 /NOx (vol)       1H.sub.2 O %              15N.sub.2                  BalanceSO.sub.2                 As Indicated______________________________________ 
    
     
                       TABLE II______________________________________NOx Removal EfficienciesOf Selective Catalytic Reduction CatalystsBefore And After Exposure to SO.sub.2           % NOx           Removal           After      % NOx Removal    Initial           50 ppm SO.sub.2                      After 1600 ppm    % NOx  Exposure   SO.sub.2 ExposureSample No. Removal  24 Hours   24 Hours                                 48 Hours______________________________________65233 (Control)      72.1     63.9       57.4   57.465309      71.7     72.3       69.8   70.865379      80.2     79.5       75.4   75.065390      85.5     82.7       82.7   82.765389      78.1     80.0       80.0   --65377      66.1     62.5       58.6   --65383      93.5     93.1       96.7   --65393*     86.4     89.0       89.0   87.736316 (0.1% V)      93.7     99.3       97.9   97.465385 (0.4% V)      93.2     94.6       90.7   87.365308 (1.6% V)      87.3     96.2       91.6   95.536309 (0.2% Cu)      92.7     85.2       77.5   73.965284 (0.4% V)**      64.6     59.3       46.9   --______________________________________ *100% Clinoptilolite  NH4 + Exchanged **Sample 65284 contained a TiO.sub.2 of lower surface area than the other catalysts.