Abstract:
Benefit agent delivery compositions, compositions, packaged products and displays comprising such benefit agent delivery compositions, and processes for making and using such benefit agent delivery compositions, compositions, packaged products and displays. Such compositions have improved deposition and retention properties that may impart improved benefit characteristics to a composition and/or situs.

Description:
CROSS-REFERENCES TO RELATED APPLICATIONS 
       [0001]    This application claims priority under 35 U.S.C. §119(e) to U.S. Provisional Application Ser. No. 60/901,569 filed Feb. 15, 2007. 
     
    
     FIELD OF INVENTION 
       [0002]    The present application relates to benefit agent delivery compositions, compositions, packaged products and displays comprising such benefit agent delivery compositions, and processes for making and using such benefit agent delivery compositions and compositions, packaged products and displays comprising such benefit agent delivery compositions. 
       BACKGROUND OF THE INVENTION 
       [0003]    Benefit agents, such as perfumes, brighteners, insect repellants, silicones, waxes, flavors, vitamins and fabric softening agents, skin care agents are expensive and may be less effective when employed at high levels in personal care compositions, cleaning compositions, and fabric care compositions. As a result, there is a desire to maximize the effectiveness of such benefit agents. One method of achieving such objective is to improve the delivery efficiencies of such benefit agents. Unfortunately, it is difficult to improve the delivery efficiencies of benefit agents as such agents may be lost do to the agents&#39; physical or chemical characteristics, such agents may be incompatible with other compositional components or the situs that is treated, or such agents may be lost during post application processes such as rinsing or drying. 
         [0004]    Accordingly, there is a need for a benefit agent delivery composition that provides improved benefit agent delivery efficiency. While not being bound by theory, applicants believe that the benefit agent delivery compositions disclosed herein meet such need as such compositions have increased deposition and retention properties which result in the desired increase in benefit agent delivery efficiency. 
       SUMMARY OF THE INVENTION 
       [0005]    Benefit agent delivery compositions, compositions, packaged products and displays comprising such benefit agent delivery compositions, and processes for making and using such benefit agent delivery compositions, and compositions, packaged products and displays comprising such benefit agent delivery compositions. 
     
    
     DETAILED DESCRIPTION OF THE INVENTION 
     Definitions 
       [0006]    As used herein “consumer product” means baby care, beauty care, fabric &amp; home care, family care, feminine care, health care, snack and/or beverage products or devices intended to be used or consumed in the form in which it is sold, and not intended for subsequent commercial manufacture or modification. Such products include but are not limited to diapers, bibs, wipes; products for and/or methods relating to treating hair (human, dog, and/or cat), including, bleaching, coloring, dyeing, conditioning, shampooing, styling; deodorants and antiperspirants; personal cleansing; cosmetics; skin care including application of creams, lotions, and other topically applied products for consumer use; and shaving products, products for and/or methods relating to treating fabrics, hard surfaces and any other surfaces in the area of fabric and home care, including: air care, car care, dishwashing, fabric conditioning (including softening), laundry detergency, laundry and rinse additive and/or care, hard surface cleaning and/or treatment, and other cleaning for consumer or institutional use; products and/or methods relating to bath tissue, facial tissue, paper handkerchiefs, and/or paper towels; tampons, feminine napkins; products and/or methods relating to oral care including toothpastes, tooth gels, tooth rinses, denture adhesives, tooth whitening; over-the-counter health care including cough and cold remedies, pain relievers, RX pharmaceuticals, pet health and nutrition, and water purification; processed food products intended primarily for consumption between customary meals or as a meal accompaniment (non-limiting examples include potato chips, tortilla chips, popcorn, pretzels, corn chips, cereal bars, vegetable chips or crisps, snack mixes, party mixes, multigrain chips, snack crackers, cheese snacks, pork rinds, corn snacks, pellet snacks, extruded snacks and bagel chips); and coffee. 
         [0007]    As used herein, the term “cleaning and/or treatment composition” includes, unless otherwise indicated, granular or powder-form all-purpose or “heavy-duty” washing agents, especially cleaning detergents; liquid, gel or paste-form all-purpose washing agents, especially the so-called heavy-duty liquid types; liquid fine-fabric detergents; hand dishwashing agents or light duty dishwashing agents, especially those of the high-foaming type; machine dishwashing agents, including the various tablet, granular, liquid and rinse-aid types for household and institutional use; liquid cleaning and disinfecting agents, including antibacterial hand-wash types, cleaning bars, mouthwashes, denture cleaners, dentifrice, car or carpet shampoos, bathroom cleaners; hair shampoos and hair-rinses; shower gels and foam baths and metal cleaners; as well as cleaning auxiliaries such as bleach additives and “stain-stick” or pre-treat types, substrate-laden products such as dryer added sheets, dry and wetted wipes and pads, nonwoven substrates, and sponges; as well as sprays and mists. 
         [0008]    As used herein, the term “fabric care composition” includes, unless otherwise indicated, fabric softening compositions, fabric enhancing compositions, fabric freshening compositions and combinations there of. 
         [0009]    As used herein, the term “amine” includes, unless otherwise indicated, primary, secondary, tertiary, and quaternary amines. 
         [0010]    As used herein, the articles such as “a” and “an” when used in a claim, are understood to mean one or more of what is claimed or described. 
         [0011]    As used herein, the terms “include”, “includes” and “including” are meant to be synonymous with the phrase “including but not limited to”. 
         [0012]    As used herein, the term “solid” includes granular, powder, bar and tablet product forms. 
         [0013]    As used herein, the term “situs” includes paper products, fabrics, garments, hard surfaces, hair and skin. 
         [0014]    Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions. 
         [0015]    All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated. 
         [0016]    It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein. 
       Benefit Agent Delivery Compositions 
       [0017]    In one aspect, benefit agent delivery compositions comprising a benefit agent, a polymeric material and an optional cross-linker are disclosed. 
         [0018]    Such benefit agent delivery compositions may comprise from about 54% to about 95%, from about 30% to about 85%, or even from about 40% to about 60% of a benefit agent; from about 5% to about 70%, from about 20 to about 60%, or even from about 30% to about 55% of a polymeric compound containing a carboxylic acid moiety; and from about 0% to about 50%, from about 0% to about 10%, or even from about 1% to about 7% by weight of a cross-linking agent. 
         [0019]    Suitable benefit agents include silicones, enzymes, fragrances, perfumes, perfume raw materials, fragrance raw materials, deodorants, odor counteractants, malodors, essential oils, ethers, esters, ketones, alcohols, glycols, silicone hydrocarbons, cyclic hydrocarbons, aldehydes, terpines, volatile or nonvolatile insecticides, volatile or nonvolatile insect repellants, volatile or nonvolatile pesticides, volatile or nonvolatile antimicrobial agents, volatile or nonvolatile fungicides, volatile or nonvolatile herbicides and mixtures thereof. In one aspect, the inclusion of volatile or nonvolatile acids is avoided to reduce the potential of the cross reaction of the acid with the cross-linker. 
         [0020]    In one aspect, the benefit agent comprises a perfume raw material, a fragrance, a perfume, an essential oil, an insecticide, an insect repellant, a pesticide, a herbicide, an odorant, a malodor counteractant, an odor masking agent, a cooling agent, a vitamin, softening agent, a skin care agent, a silicone, a softening agent, an encapsulated perfume and combinations thereof. 
         [0021]    In one aspect, the benefit agent comprises a fragrance and/or a perfume. Useful perfume materials include materials selected from the group consisting of Table 1 Perfumes, Table 2 Perfumes, Table 3 Perfumes and mixtures thereof. 
         [0000]    
       
         
               
             
               
               
               
             
               
               
               
             
           
               
                 TABLE 1 
               
             
             
               
                   
               
               
                 Perfumes 
               
             
          
           
               
                 Number 
                 Registry Name 
                 Trade Name 
               
               
                   
               
             
          
           
               
                 1 
                 Propanoic acid, ethyl ester 
                 Ethyl Propionate 
               
               
                 2 
                 Acetic acid, 2-methylpropyl ester 
                 Isobutyl Acetate 
               
               
                 3 
                 Butanoic acid, ethyl ester 
                 Ethyl Butyrate 
               
               
                 4 
                 Butanoic acid, 2-methyl-, ethyl ester 
                 Ethyl-2-Methyl Butyrate 
               
               
                 5 
                 2-Hexenal, (E)- 
                 2-Hexenal 
               
               
                 6 
                 1-Butanol, 3-methyl-, acetate 
                 Iso Amyl-Acetate 
               
               
                 7 
                 2-Buten-1-ol, 3-methyl-, acetate 
                 Prenyl Acetate 
               
               
                 8 
                 2-Hexen-1-ol 
                 Beta Gamma Hexenol 
               
               
                 9 
                 3-Hexen-1-ol 
                 Beta Gamma Hexenol 
               
               
                 10 
                 Benzaldehyde 
                 Benzaldehyde 
               
               
                 11 
                 3-Hexen-1-ol, acetate, (Z)- 
                 Cis 3 Hexenyl Acetate 
               
               
                 12 
                 Benzoic acid, methyl ester 
                 Methyl Benzoate 
               
               
                 13 
                 Benzeneacetaldehyde 
                 Phenyl Acetaldehyde 
               
               
                 14 
                 Benzeneacetic acid, methyl ester 
                 Methyl Phenyl Acetate 
               
               
                 15 
                 1,3-Dioxolane-2-acetic acid, 2-methyl-, ethyl 
                 Fructone 
               
               
                   
                 ester 
               
               
                 16 
                 Benzeneacetaldehyde, .alpha.-methyl- 
                 Hydratropic Aldehyde 
               
               
                 17 
                 3-Cyclohexene-1-carboxaldehyde, 3,5- 
                 Cyclal C, 
               
               
                   
                 dimethyl- 
               
               
                 18 
                 Acetic acid, (2-methylbutoxy)-, 2-propenyl 
                 Allyl Amyl Glycolate 
               
               
                   
                 ester 
               
               
                 19 
                 Benzenemethanol, .alpha.-methyl-, acetate 
                 Methyl Phenyl Carbinyl Acetate 
               
               
                 20 
                 Acetic acid, (3-methylbutoxy)-, 2-propenyl 
                 Allyl Amyl Glycolate 
               
               
                   
                 ester 
               
               
                 21 
                 Benzaldehyde, 4-methoxy- 
                 Anisic Aldehyde 
               
               
                 22 
                 Benzeneacetic acid, ethyl ester 
                 Ethyl Phenyl Acetate 
               
               
                 23 
                 2-Cyclohexen-1-one, 2-methyl-5-(1- 
                 Laevo Carvone 
               
               
                   
                 methylethenyl)-, (R)- 
               
               
                 24 
                 Ethanol, 2,2′-oxybis- 
                 Calone 161 
               
               
                 25 
                 Acetic acid, 2-phenylethyl ester 
                 Phenyl Ethyl Acetate 
               
               
                 26 
                 Benzoic acid, 2-amino-, methyl ester 
                 Methyl Anthranilate 
               
               
                 27 
                 4,7-Methano-1H-inden-6-ol, 3a,4,5,6,7,7a- 
                 Flor Acetate 
               
               
                   
                 hexahydro-, acetate 
               
               
                 28 
                 Octanal, 7-hydroxy-3,7-dimethyl- 
                 Hydroxycitronellal 
               
               
                 29 
                 2(3H)-Furanone, 5-ethyldihydro- 
                 Gamma Hexalactone 
               
               
                 30 
                 Phenol, 4-methyl- 
                 Para Cresol 
               
               
                 31 
                 Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, 
                 Camphor Gum 
               
               
                   
                 (1R)- 
               
               
                 32 
                 2H-Pyran, 3,6-dihydro-4-methyl-2-(2-methyl-1- 
                 Nerol Oxide 
               
               
                   
                 propenyl)- 
               
               
                 33 
                 Benzeneethanol, .beta.-methyl- 
                 Hydratropic Alcohol 
               
               
                 34 
                 Benzeneethanol, .alpha.,.alpha.-dimethyl- 
                 Dimethyl Benzyl Carbinol 
               
               
                 35 
                 Benzoic acid, 2-(methylamino)-, methyl ester 
                 Dimethyl Anthranilate 
               
               
                 36 
                 2-Propenal, 3-phenyl- 
                 Cinnamic Aldehyde 
               
               
                 37 
                 2-Propenoic acid, 3-phenyl-, methyl ester 
                 Methyl Cinnamate 
               
               
                 38 
                 4H-Pyran-4-one, 2-ethyl-3-hydroxy- 
                 Ethyl Maltol 
               
               
                 39 
                 Acetic acid ethyl ester 
                 Ethyl Acetate 
               
               
                 40 
                 2-Heptanone 
                 Methyl Amyl Ketone 
               
               
                 41 
                 Acetic acid, pentyl ester 
                 Iso Amyl-Acetate 
               
               
                 42 
                 3-Octanone 
                 Ethyl Amyl Ketone 
               
               
                 43 
                 2-Octanone 
                 Methyl Hexyl Ketone 
               
               
                 44 
                 Heptenone, methyl- 
                 Methyl Heptenone 
               
               
                 45 
                 1-Heptanol 
                 Heptyl Alcohol 
               
               
                 46 
                 5-Hepten-2-one, 6-methyl- 
                 Methyl Heptenone 
               
               
                 47 
                 Butanoic acid, 3-oxo-, ethyl ester 
                 Ethyl Acetoacetate 
               
               
                 48 
                 Ethanol, 2-(2-methoxyethoxy)- 
                 Veramoss Sps 
               
               
                 49 
                 Tricyclo[2.2.1.02,6]heptane, 1-ethyl-3- 
                 Neoproxen 
               
               
                   
                 methoxy- 
               
               
                 50 
                 Benzene, 1,4-dimethoxy- 
                 Hydroquinone Dimethyl Ether 
               
               
                 51 
                 Carbonic acid, 3-hexenyl methyl ester, (Z)- 
                 Liffarome 
               
               
                 52 
                 Oxirane, 2,2-dimethyl-3-(3-methyl-2,4- 
                 Myroxide 
               
               
                   
                 pentadienyl)- 
               
               
                 53 
                 Ethanol, 2-(2-ethoxyethoxy)- 
                 Diethylene Glycol Mono 
               
               
                   
                   
                 Ethylether 
               
               
                 54 
                 Cyclohexaneethanol 
                 Cyclohexyl Ethyl Alcohol 
               
               
                 55 
                 3-Octen-1-ol, (Z)- 
                 Octenol Dix 
               
               
                 56 
                 3-Cyclohexene-1-carboxaldehyde, 3,6- 
                 Cyclovertal 
               
               
                   
                 dimethyl- 
               
               
                 57 
                 1,3-Oxathiane, 2-methyl-4-propyl-, cis- 
                 Oxane 
               
               
                 58 
                 Acetic acid, 4-methylphenyl ester 
                 Para Cresyl Acetate 
               
               
                 59 
                 Benzene, (2,2-dimethoxyethyl)- 
                 Phenyl Acetaldehyde Dimethyl 
               
               
                   
                   
                 Acetal 
               
               
                 60 
                 Ethanone, 1-(4-methylphenyl)- 
                 Para Methyl Acetophenone 
               
               
                 61 
                 Propanoic acid, phenylmethyl ester 
                 Benzyl Propionate 
               
               
                 62 
                 Octanal, 7-methoxy-3,7-dimethyl- 
                 Methoxycitronellal Pq 
               
               
                 63 
                 Linalool oxide 
                 Linalool Oxide 
               
               
                 64 
                 2H-1-Benzopyran-2-one, octahydro- 
                 Octahydro Coumarin 
               
               
                 65 
                 Benzenepropanal, .beta.-methyl- 
                 Trifernal 
               
               
                 66 
                 4,7-Methano-1H-indenecarboxaldehyde, 
                 Formyltricyclodecan 
               
               
                   
                 octahydro- 
               
               
                 67 
                 2-Butanone, 4-phenyl- 
                 Benzyl Acetone 
               
               
                 68 
                 Ethanone, 1-(4-methoxyphenyl)- 
                 Para Methoxy Acetophenone 
               
               
                 69 
                 Benzoic acid, 2-hydroxy-, methyl ester 
                 Methyl Salicylate USP 
               
               
                 70 
                 Propanenitrile, 3-(3-hexenyloxy)-, (Z)- 
                 Parmanyl 
               
               
                 71 
                 1,4-Methanonaphthalen-5(1H)-one, 
                 Tamisone 
               
               
                   
                 4,4a,6,7,8,8a-hexahydro- 
               
               
                 72 
                 Benzene, [2-(2-propenyloxy)ethyl]- 
                 LRA 220 
               
               
                 73 
                 Benzenepropanol 
                 Phenyl Propyl Alcohol 
               
               
                 74 
                 Ethanol, 2-phenoxy- 
                 Phenoxyethanol 
               
               
                 75 
                 1H-Indole 
                 Indole 
               
               
                 76 
                 1,3-Dioxolane, 2-(phenylmethyl)- 
                 Ethylene Glycol Acetal/Phenyl 
               
               
                   
                   
                 Acetaldehy 
               
               
                 77 
                 2H-1-Benzopyran-2-one, 3,4-dihydro- 
                 Dihydrocoumarin 
               
               
                   
               
             
          
         
       
     
         [0022]    In one aspect, suitable Table 1 perfume raw materials include perfume raw materials from number 1 to number 39 and mixtures thereof. 
         [0023]    In one aspect, suitable Table 1 perfume raw materials include perfume raw materials from number 1 to number 29 and mixtures thereof. 
         [0024]    In one aspect, suitable perfume raw materials having boiling point less than or equal to 250° C. and a ClogP greater than 2.5 are those materials listed in Table 2 below and such materials are defined as Table 2 perfume raw materials. 
         [0000]    
       
         
               
             
               
               
               
             
               
               
               
             
           
               
                 TABLE 2 
               
             
             
               
                   
               
               
                 Perfumes 
               
             
          
           
               
                 Number 
                 Registry Name 
                 Trade Name 
               
               
                   
               
             
          
           
               
                 1 
                 Bicyclo[2.2.1]heptane, 2,2-dimethyl-3- 
                 Camphene 
               
               
                   
                 methylene- 
               
               
                 2 
                 Bicyclo[3.1.1]heptane, 6,6-dimethyl-2- 
                 Beta Pinene 
               
               
                   
                 methylene-, (1S)- 
               
               
                 3 
                 Bicyclo[3.1.1]hept-2-ene, 2,6,6- 
                 Alpha Pinene 
               
               
                   
                 trimethyl- 
               
               
                 4 
                 Propanoic acid, pentyl ester 
                 Amyl Propionate 
               
               
                 5 
                 1,6-Octadiene, 7-methyl-3-methylene- 
                 Myrcene 
               
               
                 6 
                 Cyclohexene, 1-methyl-4-(1- 
                 Dipentene 
               
               
                   
                 methylethenyl)- 
               
               
                 7 
                 Cyclohexene, 1-methyl-4-(1- 
                 Terpineolene 
               
               
                   
                 methylethenyl)- 
               
               
                 8 
                 Acetic acid, hexyl ester 
                 Hexyl Acetate 
               
               
                 9 
                 Cyclohexene, 1-methyl-4-(1- 
                 Terpineolene 
               
               
                   
                 methylethylidene)- 
               
               
                 10 
                 Benzene, 1-methoxy-4-methyl- 
                 Para Cresyl Methyl Ether 
               
               
                 11 
                 1-Octen-3-ol, acetate 
                 Amyl Vinyl Carbinyl Acetate 
               
               
                 12 
                 Octanal 
                 Octyl Aldehyde 
               
               
                 13 
                 2-Oxabicyclo[2.2.2]octane, 1,3,3- 
                 Eucalyptol 
               
               
                   
                 trimethyl- 
               
               
                 14 
                 Butanoic acid, pentyl ester 
                 Amyl Butyrate 
               
               
                 15 
                 Heptanoic acid, ethyl ester 
                 Ethyl Oenanthate 
               
               
                 16 
                 5-Heptenal, 2,6-dimethyl- 
                 Melonal 
               
               
                 17 
                 Hexanoic acid, 2-propenyl ester 
                 Allyl Caproate 
               
               
                 18 
                 3-Cyclohexene-1-carboxaldehyde, 
                 Ligustral 
               
               
                   
                 dimethyl- 
               
               
                 19 
                 3-Hexene, 1-(1-ethoxyethoxy)-, (Z)- 
                 Leaf Acetal 
               
               
                 20 
                 Octanal, 3,7-dimethyl- 
                 Dihydrocitronellal 
               
               
                 21 
                 2-Octynoic acid, methyl ester 
                 Methyl Heptine Carbonate 
               
               
                 22 
                 2-Nonenal 
                 2 Nonen-1-al 
               
               
                 23 
                 1,6-Octadien-3-ol, 3,7-dimethyl- 
                 Linalool 
               
               
                 24 
                 Benzoic acid, ethyl ester 
                 Ethyl Benzoate 
               
               
                 25 
                 6-Octenal, 3,7-dimethyl- 
                 Citronellal 
               
               
                 26 
                 Cyclohexanol, 1-methyl-4-(1- 
                 Dihydroterpineol 
               
               
                   
                 methylethyl)- 
               
               
                 27 
                 1-Hexanol, 3,5,5-trimethyl-, acetate 
                 Iso Nonyl Acetate 
               
               
                 28 
                 3,5-Octadien-2-ol, 2,6-dimethyl-, (?,Z)- 
                 Muguol 
               
               
                 29 
                 Cyclohexanone, 5-methyl-2-(1- 
                 Iso Menthone 
               
               
                   
                 methylethyl)-, cis- 
               
               
                 30 
                 Heptanoic acid, 2-propenyl ester 
                 Allyl Heptoate 
               
               
                 31 
                 Butanoic acid, 3-hexenyl ester, (Z)- 
                 Cis 3 Hexenyl Butyrate 
               
               
                 32 
                 1,6-Octadien-3-ol, 3,7-dimethyl-, 
                 Linalyl Formate 
               
               
                   
                 formate 
               
               
                 33 
                 3-Cyclohexen-1-ol, 4-methyl-1-(1- 
                 Terpinenol 
               
               
                   
                 methylethyl)- 
               
               
                 34 
                 Bicyclo[2.2.1]heptan-2-ol, 1,3,3- 
                 Fenchyl Alcohol 
               
               
                   
                 trimethyl- 
               
               
                 35 
                 Cyclohexanol, 2-(1,1-dimethylethyl)-, 
                 Verdol 
               
               
                   
                 cis- 
               
               
                 36 
                 3-Octanol, 3,7-dimethyl-, acetate 
                 Tetrahydro Linayl Acetate 
               
               
                 37 
                 Bicyclo[2.2.1]heptan-2-ol, 1,7,7- 
                 Borneol Crystals 
               
               
                   
                 trimethyl-, (1S-endo)- 
               
               
                 38 
                 Decanal 
                 Decyl Aldehyde 
               
               
                 39 
                 3-Cyclohexene-1-methanol, 
                 Alpha Terpineol 
               
               
                   
                 .alpha.,.alpha.,4-trimethyl- 
               
               
                 40 
                 Cyclohexanol, 5-methyl-2-(1- 
                 Menthol 
               
               
                   
                 methylethyl)- 
               
               
                 41 
                 3-Cyclohexene-1-carboxaldehyde, 
                 Iso Cyclo Citral 
               
               
                   
                 2,4,6-trimethyl- 
               
               
                 42 
                 7-Octen-2-ol, 2,6-dimethyl-, acetate 
                 Dihydro Terpinyl Acetate 
               
               
                 43 
                 2H-Pyran-2-one, 6-butyltetrahydro- 
                 Nonalactone 
               
               
                 44 
                 3-Hepten-2-one, 3,4,5,6,6-pentamethyl- 
                 Koavone 
               
               
                 45 
                 1,6-Nonadien-3-ol, 3,7-dimethyl- 
                 Ethyl Linalool 
               
               
                 46 
                 4-Decenal, (E)- 
                 Decenal (Trans-4) 
               
               
                 47 
                 Terpineol 
                 Terpineol 
               
               
                 48 
                 7-Octen-2-ol, 2-methyl-6-methylene-, 
                 Myrcenyl Acetate 
               
               
                   
                 acetate 
               
               
                 49 
                 2-Butenoic acid, 2-methyl-, 3-hexenyl 
                 Cis-3-Hexenyl Tiglate 
               
               
                   
                 ester, (E,Z)- 
               
               
                 50 
                 1,6-Octadien-3-ol, 3,7-dimethyl-, 
                 Linalyl Acetate 
               
               
                   
                 acetate 
               
               
                 51 
                 Benzene, 1-methoxy-4-(1-propenyl)-, 
                 Anethol Usp 
               
               
                   
                 (E)- 
               
               
                 52 
                 2-Decenal 
                 2 Decene-1-al 
               
               
                 53 
                 2,6-Octadienal, 3,7-dimethyl- 
                 Citral 
               
               
                 54 
                 6-Octen-1-ol, 3,7-dimethyl-, formate 
                 Citronellyl Formate 
               
               
                 55 
                 Cyclopentanone, 3-methyl-2-pentyl- 
                 Jasmylone 
               
               
                 56 
                 Undecenal 
                 Iso C-11 Aldehyde 
               
               
                 57 
                 6-Octen-1-ol, 3,7-dimethyl- 
                 Citronellol 
               
               
                 58 
                 Cyclohexanemethanol, 
                 Dihydro Terpinyl Acetate 
               
               
                   
                 .alpha.,.alpha.,4-trimethyl-, acetate 
               
               
                 59 
                 3-Cyclohexene-1-methanol, 
                 Terpinyl Acetate 
               
               
                   
                 .alpha.,.alpha.,4-trimethyl-, acetate 
               
               
                 60 
                 2,6-Octadien-1-ol, 3,7-dimethyl-, 
                 Geranyl Formate 
               
               
                   
                 formate, (E)- 
               
               
                 61 
                 Bicyclo[2.2.1]heptan-2-ol, 1,3,3- 
                 Fenchyl Acetate 
               
               
                   
                 trimethyl-, acetate 
               
               
                 62 
                 Bicyclo[2.2.1]heptan-2-ol, 1,7,7- 
                 Iso Bornyl Acetate 
               
               
                   
                 trimethyl-, acetate, exo- 
               
               
                 63 
                 2,6-Octadien-1-ol, 3,7-dimethyl-, (E)- 
                 Geraniol 
               
               
                 64 
                 2,6-Octadien-1-ol, 3,7-dimethyl-, (Z)- 
                 Nerol 
               
               
                 65 
                 Cyclohexanol, 2-(1,1-dimethylethyl)-, 
                 Verdox 
               
               
                   
                 acetate 
               
               
                 66 
                 Undecanal, 2-methyl- 
                 Methyl Nonyl Acetaldehyde 
               
               
                 67 
                 Undecanal 
                 Undecyl Aldehyde 
               
               
                 68 
                 2H-Pyran-2-one, tetrahydro-6-pentyl- 
                 Delta Decalactone 
               
               
                 69 
                 6-Octen-1-ol, 3,7-dimethyl-, acetate 
                 Citronellyl Acetate 
               
               
                 70 
                 10-Undecenal 
                 Intreleven Aldehyde Sp 
               
               
                 71 
                 2(3H)-Furanone, 5-hexyldihydro- 
                 Gamma Decalactone 
               
               
                 72 
                 2,6-Octadien-1-ol, 3,7-dimethyl-, 
                 Geranyl Acetate 
               
               
                   
                 acetate, (E)- 
               
               
                 73 
                 2H-Pyran-2-one, tetrahydro-6-(3- 
                 Jasmolactone 
               
               
                   
                 pentenyl)- 
               
               
                 74 
                 Cyclohexanol, 5-methyl-2-(1- 
                 Menthyl Acetate 
               
               
                   
                 methylethyl)-, 
               
               
                   
                 acetate, (1.alpha.,2.beta.,5.alpha.)- 
               
               
                 75 
                 2-Undecenal 
                 2-Undecene-1-Al 
               
               
                 76 
                 2H-Pyran-2-one, tetrahydro-6-(2- 
                 Jasmolactone 
               
               
                   
                 pentenyl)-, (Z)- 
               
               
                 77 
                 2,6-Octadien-1-ol, 3,7-dimethyl-, 
                 Neryl Acetate 
               
               
                   
                 acetate, (Z)- 
               
               
                 78 
                 Benzeneethanol, .alpha.,.alpha.- 
                 Dimethyl Benzyl Carbinyl Acetate 
               
               
                   
                 dimethyl-, acetate 
               
               
                 79 
                 4,9-Decadienal, 4,8-dimethyl- 
                 Floral Super 
               
               
                 80 
                 3-Octanol 
                 Octanol-3 
               
               
                 81 
                 2-Heptanol, 2,6-dimethyl- 
                 Dimethyl-2,6-Heptan-2-ol 
               
               
                 82 
                 Propanoic acid, 2-methyl-, 1,3- 
                 Iso Pentyrate 
               
               
                   
                 dimethyl-3-butenyl ester 
               
               
                 83 
                 3-Nonanone 
                 Ethyl Hexyl Ketone 
               
               
                 84 
                 2,4,6-Octatriene, 2,6-dimethyl- 
                 Allo-Ocimene 
               
               
                 85 
                 Bicyclo[2.2.1]heptane, 2-ethyl-5- 
                 Neoproxen 
               
               
                   
                 methoxy- 
               
               
                 86 
                 1-Octanol 
                 Octyl Alcohol 
               
               
                 87 
                 3-Octanol, 3,7-dimethyl- 
                 Linacsol 
               
               
                 88 
                 Propanoic acid, 2-methyl-, 3-hexenyl 
                 Verdural B Extra 
               
               
                   
                 ester, (Z)- 
               
               
                 89 
                 2H-Pyran, tetrahydro-4-methyl-2-(2- 
                 Methyl Iso Butenyl Tetrahydro Pyran 
               
               
                   
                 methyl-1-propenyl)- 
               
               
                 90 
                 Nonanal 
                 Nonyl Aldehyde 
               
               
                 91 
                 Hexanoic acid, 2-methylpropyl ester 
                 Iso Butyl Caproate 
               
               
                 92 
                 Cyclohexane, 3-ethoxy-1,1,5-trimethyl- 
                 Herbavert 
               
               
                 93 
                 7-Octen-2-ol, 2-methyl-6-methylene-, 
                 Dihydro Myrcenol 
               
               
                   
                 dihydro deriv. 
               
               
                 94 
                 Ethanone, 1-(3,3-dimethylcyclohexyl)- 
                 Herbac 
               
               
                 95 
                 Propanoic acid, 2,2-dimethyl-, hexyl 
                 Hexyl Neo Pentanoate 
               
               
                   
                 ester 
               
               
                 96 
                 3-Heptanone, 5-methyl-, oxime 
                 Stemone 
               
               
                 97 
                 Isononanol 
                 Iso Nonyl Alcohol 
               
               
                 98 
                 Cyclohexanone, 2-(1-methylpropyl)- 
                 2-Sec-Butyl Cyclo Hexanone 
               
               
                 99 
                 Butanoic acid, 2-methyl-, hexyl ester 
                 Hexyl-2-Methyl Butyrate 
               
               
                 100 
                 1-Nonanol 
                 Nonyl Alcohol 
               
               
                 101 
                 Cyclohexaneethanol, acetate 
                 Cyclohexyl Ethyl Acetate 
               
               
                 102 
                 1-Octanol, 3,7-dimethyl- 
                 Dimethyl Octanol 
               
               
                 103 
                 Cyclopentanone, 2-pentyl- 
                 Delphone 
               
               
                 104 
                 Cyclohexanemethanol, 4-(1- 
                 Mayol 
               
               
                   
                 methylethyl)-, cis- 
               
               
                 105 
                 6-Octen-1-ol, 3,7-dimethyl-, (S)- 
                 Baranol 
               
               
                 106 
                 Benzaldehyde, 4-(1-methylethyl)- 
                 Cuminic Aldehyde 
               
               
                 107 
                 Propanoic acid, 2-methyl-, 
                 Benzyl Iso Butyrate 
               
               
                   
                 phenylmethyl ester 
               
               
                 108 
                 Propanoic acid, 2-methyl-, 4- 
                 Para Cresyl Iso Butyrate 
               
               
                   
                 methylphenyl ester 
               
               
                 109 
                 Carbonic acid, 4-cycloocten-1-yl 
                 Violiff 
               
               
                   
                 methyl ester 
               
               
                 110 
                 1,6-Octadien-3-ol, 3,7-dimethyl-, 
                 Linalyl Propionate 
               
               
                   
                 propanoate 
               
               
                 111 
                 Cyclohexanemethanol, .alpha.-methyl- 
                 Mugetanol 
               
               
                   
                 4-(1-methylethyl)- 
               
               
                 112 
                 Butanoic acid, phenylmethyl ester 
                 Benzyl Butyrate 
               
               
                 113 
                 4,7-Methano-1H-inden-5-ol, octahydro-, 
                 Dihydro Cyclacet 
               
               
                   
                 acetate 
               
               
                 114 
                 2-Cyclopenten-1-one, 3-methyl-2- 
                 Dihydrojasmone 
               
               
                   
                 pentyl- 
               
               
                 115 
                 Bicyclo[2.2.1]heptan-2-ol, 1,7,7- 
                 Iso Bornyl Propionate 
               
               
                   
                 trimethyl-, propanoate, exo- 
               
               
                 116 
                 2,6-Octadienenitrile, 3,7-dimethyl- 
                 Geranyl Nitrile 
               
               
                 117 
                 Benzene, ethenyl- 
                 Styrene 
               
               
                 118 
                 Benzene, methyl(1-methylethyl)- 
                 Cymene Coeur 
               
               
                 119 
                 Cyclohexanol, 3,3,5-trimethyl-, cis- 
                 Trimethylcyclohexanol 
               
               
                 120 
                 1-Hexanol, 5-methyl-2-(1- 
                 Tetrahydro Lavandulol 
               
               
                   
                 methylethyl)-, (R)- 
               
               
                 121 
                 Cyclohexanol, 4-(1-methylethyl)- 
                 Roselea 
               
               
                 122 
                 7-Octen-2-ol, 2,6-dimethyl-, formate 
                 Dimyrcetol 
               
               
                 123 
                 Cyclohexanone, 5-methyl-2-(1- 
                 Menthone Racemic 
               
               
                   
                 methylethyl)-, trans- 
               
               
                 124 
                 1,3,5-Undecatriene 
                 Galbanolene Super 
               
               
                 125 
                 5,7-Octadien-2-ol, 2,6-dimethyl- 
                 Ocimenol 
               
               
                 126 
                 2-Cyclohexene-1-carboxylic acid, 
                 Methyl Cyclogeranate 
               
               
                   
                 2,6,6-trimethyl-, methyl ester 
               
               
                 127 
                 Benzene, (2-bromoethenyl)- 
                 Brom Styrol 
               
               
                 128 
                 Benzene, 1-methoxy-4-(2-propenyl)- 
                 Methyl Chavicol 
               
               
                 129 
                 2H-Pyran, 6-butyl-3,6-dihydro-2,4- 
                 Gyrane 
               
               
                   
                 dimethyl- 
               
               
                 130 
                 Cyclohexanemethanol, .alpha.,3,3- 
                 Aphermate 
               
               
                   
                 trimethyl-, formate 
               
               
                 131 
                 Cyclohexanol, 4-(1,1-dimethylethyl)- 
                 Patchon 
               
               
                 132 
                 Cyclohexanol, 5-methyl-2-(1- 
                 Menthol Natural 
               
               
                   
                 methylethyl)-, [1R- 
               
               
                   
                 (1.alpha.,2.beta.,5.alpha.)]- 
               
               
                 133 
                 1,3-Dioxane, 2-butyl-4,4,6-trimethyl- 
                 Herboxane 
               
               
                 134 
                 2-Nonynoic acid, methyl ester 
                 Methyl Octine Carbonate 
               
               
                 135 
                 6-Octenenitrile, 3,7-dimethyl- 
                 Baranyl Nitrile 
               
               
                 136 
                 Decanal, 2-methyl- 
                 Methyl Octyl Acetaldehyde 
               
               
                 137 
                 2-Nonanol, 6,8-dimethyl- 
                 Nonadyl 
               
               
                 138 
                 Phenol, 4-(1,1-dimethylethyl)- 
                 Para Tertiary Butyl Phenol 
               
               
                 139 
                 1-Hexanol, 5-methyl-2-(1- 
                 Tetrahydro Lavandulyl Acetate 
               
               
                   
                 methylethyl)-, acetate 
               
               
                 140 
                 Cyclohexanol, 5-methyl-2-(1- 
                 Iso Pulegol 
               
               
                   
                 methylethenyl)-, [1R- 
               
               
                   
                 (1.alpha.,2.beta.,5.alpha.)]- 
               
               
                 141 
                 Cyclohexanone, 4-(1,1- 
                 Orivone 
               
               
                   
                 dimethylpropyl)- 
               
               
                 142 
                 2-Undecanone 
                 Methyl Nonyl Ketone 
               
               
                 143 
                 Cyclohexanemethanol, .alpha.,3,3- 
                 Rosamusk 
               
               
                   
                 trimethyl-, acetate 
               
               
                 144 
                 3-Cyclohexene-1-methanol, 2,4,6- 
                 Isocyclogeraniol 
               
               
                   
                 trimethyl- 
               
               
                 145 
                 2,6-Octadiene, 1,1-dimethoxy-3,7- 
                 Citral Dimethyl Acetal 
               
               
                   
                 dimethyl- 
               
               
                 146 
                 1-Decanol 
                 Rhodalione 
               
               
                 147 
                 2-Cyclohexen-1-one, 3-methyl-5- 
                 Livescone 
               
               
                   
                 propyl- 
               
               
                 148 
                 Phenol, 2-methyl-5-(1-methylethyl)- 
                 Carvacrol 
               
               
                 149 
                 2-Naphthalenol, decahydro- 
                 Trans Deca Hydro Beta Naphthol 
               
               
                 150 
                 Cyclohexanol, 4-(1,1-dimethylethyl)-, 
                 Tertiary Butyl Cyclohexyl Acetate 
               
               
                   
                 acetate 
               
               
                 151 
                 9-Decen-1-ol 
                 Rosalva 
               
               
                 152 
                 Phenol, 5-methyl-2-(1-methylethyl)- 
                 Thymol Nf 
               
               
                 153 
                 Cyclohexanol, 5-methyl-2-(1- 
                 Iso Pulegol Acetate 
               
               
                   
                 methylethenyl)-, acetate, [1R- 
               
               
                   
                 (1.alpha.,2.beta.,5.alpha.)]- 
               
               
                 154 
                 Benzene, [(3-methylbutoxy)methyl]- 
                 Iso Amyl Benzyl Ether 
               
               
                 155 
                 2(3H)-Furanone, 5-hexyldihydro-5- 
                 Lactojasmon 
               
               
                   
                 methyl- 
               
               
                 156 
                 Benzoic acid, butyl ester 
                 Butyl Benzoate 
               
               
                 157 
                 Bicyclo[3.2.1]octan-8-one, 1,5- 
                 Buccoxime 
               
               
                   
                 dimethyl-, oxime 
               
               
                 158 
                 2-Cyclopenten-1-one, 2-methyl-3-(2- 
                 Iso Jasmone 
               
               
                   
                 pentenyl)- 
               
               
                   
               
             
          
         
       
     
         [0025]    In one aspect, suitable Table 2 perfume raw materials include perfume raw materials from number 1 to number 116 and mixtures thereof. 
         [0026]    In one aspect, suitable Table 2 perfume raw materials include perfume raw materials from number 1 to number 79 and mixtures thereof. 
         [0027]    In one aspect, suitable perfume raw materials having boiling point greater than 250° C. but less than or equal to 280° C. are those materials listed in Table 3 below and such materials are defined as Table 3 perfume raw materials. 
         [0000]    
       
         
               
             
               
               
               
             
               
               
               
             
           
               
                 TABLE 3 
               
             
             
               
                   
               
               
                 Perfumes 
               
             
          
           
               
                 Number 
                 Registry Name 
                 Trade Name 
               
               
                   
               
             
          
           
               
                 1 
                 Dodecanenitrile 
                 Clonal 
               
               
                 2 
                 Cyclohexanepropanoic acid, 2-propenyl ester 
                 Allyl Cyclohexane Propionate 
               
               
                 3 
                 2-Buten-1-one, 1-(2,6,6-trimethyl-2- 
                 Alpha Damascone 
               
               
                   
                 cyclohexen-1-yl)- 
               
               
                 4 
                 1,4-Cyclohexanedicarboxylic acid, diethyl 
                 Fructalate 
               
               
                   
                 ester 
               
               
                 5 
                 2(3H)-Furanone, 5-heptyldihydro- 
                 Undecalactone 
               
               
                 6 
                 Naphthalene, 2-methoxy- 
                 Beta Naphthol Methyl Ether 
               
               
                 7 
                 Benzenepropanal, 4-(1,1-dimethylethyl)- 
                 Bourgeonal 
               
               
                 8 
                 3-Cyclopentene-1-butanol, .beta.,2,2,3- 
                 Brahmanol 
               
               
                   
                 tetramethyl- 
               
               
                 9 
                 1H-3a,7-Methanoazulen-6-ol, octahydro- 
                 Cedrol 
               
               
                   
                 3,6,8,8-tetramethyl-,[3R- 
               
               
                   
                 (3.alpha.,3a.beta.,6.alpha.,7.beta.,8a.alpha.)]- 
               
               
                 10 
                 2-Propen-1-ol, 3-phenyl-, acetate 
                 Cinnamyl Acetate 
               
               
                 11 
                 Benzenepropanal, .alpha.-methyl-4-(1- 
                 Cymal 
               
               
                   
                 methylethyl)- 
               
               
                 12 
                 2-Buten-1-one, 1-(2,6,6-trimethyl-1- 
                 Damascone Beta 
               
               
                   
                 cyclohexen-1-yl)-, (Z)- 
               
               
                 13 
                 2-Buten-1-one, 1-(2,6,6-trimethyl-1,3- 
                 Damascenone 
               
               
                   
                 cyclohexadien-1-yl)- 
               
               
                 14 
                 2-Buten-1-one, 1-(2,6,6-trimethyl-3- 
                 Delta Damascone 
               
               
                   
                 cyclohexen-1-yl)- 
               
               
                 15 
                 Butanoic acid, 1,1-dimethyl-2-phenylethyl 
                 Dimethyl Benzyl Carbinyl 
               
               
                   
                 ester 
                 Butyrate 
               
               
                 16 
                 2-Dodecenal 
                 2 Dodecene-1-al 
               
               
                 17 
                 2H-Pyran-2-one, 6-heptyltetrahydro- 
                 Dodecalactone 
               
               
                 18 
                 Oxiranecarboxylic acid, 3-methyl-3-phenyl-, 
                 Ethyl Methyl Phenyl Glycidate 
               
               
                   
                 ethyl ester 
               
               
                 19 
                 Oxiranecarboxylic acid, 3-phenyl-, ethyl 
                 Ethyl Phenyl Glycidate 
               
               
                   
                 ester 
               
               
                 20 
                 Phenol, 2-methoxy-4-(2-propenyl)- 
                 Eugenol 
               
               
                 21 
                 Benzenepropanal, .beta.-methyl-3-(1- 
                 Florhydral 
               
               
                   
                 methylethyl)- 
               
               
                 22 
                 Benzenepropanal, 2-ethyl-.alpha.,.alpha.- 
                 Floralozone 
               
               
                   
                 dimethyl- 
               
               
                 23 
                 4,7-Methano-1H-inden-6-ol, 3a,4,5,6,7,7a- 
                 Frutene 
               
               
                   
                 hexahydro-, propanoate 
               
               
                 24 
                 2,6-Octadienenitrile, 3,7-dimethyl-, (E)- 
                 Geranyl Nitrile 
               
               
                 25 
                 1,3-Benzodioxole-5-carboxaldehyde 
                 Heliotropin 
               
               
                 26 
                 Ionone 
                 Ionone Ab 
               
               
                 27 
                 3-Buten-2-one, 4-(2,6,6-trimethyl-2- 
                 Ionone Alpha 
               
               
                   
                 cyclohexen-1-yl)-, (E)- 
               
               
                 28 
                 3-Buten-2-one, 4-(2,6,6-trimethyl-1- 
                 Ionone Beta 
               
               
                   
                 cyclohexen-1-yl)- 
               
               
                 29 
                 3-Buten-2-one, 4-(2,6,6-trimethyl-1- 
                 Ionone Beta 
               
               
                   
                 cyclohexen-1-yl)-, (E)- 
               
               
                 30 
                 3-Buten-2-one, 3-methyl-4-(2,6,6-trimethyl- 
                 Ionone Gamma Methyl 
               
               
                   
                 2-cyclohexen-1-yl)- 
               
               
                 31 
                 2-Buten-1-one, 1-(2,4,4-trimethyl-2- 
                 Isodamascone N 
               
               
                   
                 cyclohexen-1-yl)-, (E)- 
               
               
                 32 
                 Phenol, 2-methoxy-4-(1-propenyl)- 
                 Iso Eugenol 
               
               
                 33 
                 2H-Pyran-4-ol, tetrahydro-3-pentyl-, acetate 
                 Jasmal 
               
               
                 34 
                 Bicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6- 
                 Nopyl Acetate 
               
               
                   
                 dimethyl-, acetate 
               
               
                 35 
                 Benzenepropanol, .alpha.,.alpha.-dimethyl-, 
                 Phenyl Ethyl Dimethyl 
               
               
                   
                 acetate 
                 Carbinyl Acetate 
               
               
                 36 
                 Propanoic acid, 2-methyl-, 3a,4,5,6,7,7a- 
                 Cyclabute 
               
               
                   
                 hexahydro-4,7-methano-1H- 
               
               
                 37 
                 Benzaldehyde, 4-hydroxy-3-methoxy- 
                 Vanillin 
               
               
                 38 
                 3-Cyclohexene-1-carboxaldehyde, 1-methyl- 
                 Vernaldehyde 
               
               
                   
                 4-(4-methylpentyl)- 
               
               
                 39 
                 Benzenemethanol, ar-methoxy-, acetate 
                 Anisyl Acetate 
               
               
                 40 
                 Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 
                 Herbanate Ci 
               
               
                   
                 3-(1-methylethyl)-,ethyl ester, (2-endo,3- 
               
               
                   
                 exo)- 
               
               
                 41 
                 Butanoic acid, 3-methyl-, 2-phenylethyl ester 
                 Beta Phenyl Ethyl Isovalerate 
               
               
                 42 
                 Benzenepropanal, 4-methoxy-.alpha.-methyl- 
                 Canthoxal 
               
               
                 43 
                 Bicyclo[7.2.0]undec-4-ene, 4,11,11- 
                 Caryophyllene Extra 
               
               
                   
                 trimethyl-8-methylene-,[1R-(1R*,4E,9S*)]- 
               
               
                 44 
                 Cyclohexenebutanal, .alpha.,2,2,6- 
                 Cetonal 
               
               
                   
                 tetramethyl- 
               
               
                 45 
                 2-Propen-1-ol, 3-phenyl- 
                 Cinnamic Alcohol 
               
               
                 46 
                 6-Octen-1-ol, 3,7-dimethyl-, propanoate 
                 Citronellyl Propionate 
               
               
                 47 
                 Propanoic acid, decyl ester 
                 N-Decyl Propionate 
               
               
                 48 
                 Phenol, 2-methoxy-4-propyl- 
                 Dihydro Eugenol 
               
               
                 49 
                 Cyclohexanol, 1-ethenyl-2-(1-methylpropyl)-, 
                 Dihydro Ambrate 
               
               
                   
                 acetate 
               
               
                 50 
                 2-Propenoic acid, 3-phenyl-, ethyl ester 
                 Ethyl Cinnamate 
               
               
                 51 
                 Butanoic acid, 3,7-dimethyl-2,6-octadienyl 
                 Geranyl Butyrate 
               
               
                   
                 ester, (E)- 
               
               
                 52 
                 2-Octanol, 8,8-dimethoxy-2,6-dimethyl- 
                 Hydroxycitronellal Dimethyl 
               
               
                   
                   
                 Acetal 
               
               
                 53 
                 Cyclohexadieneethanol, 4-(1-methylethyl)-, 
                 Iso Bergamate 
               
               
                   
                 formate 
               
               
                 54 
                 Dodecanal 
                 Lauric Aldehyde 
               
               
                 55 
                 Propanoic acid, 2-methyl-, 1-ethenyl-1,5- 
                 Linalyl Iso Butyrate 
               
               
                   
                 dimethyl-4-hexenyl ester 
               
               
                 56 
                 Benzenepropanol, .beta.,.beta.,3-trimethyl- 
                 Majantol 
               
               
                 57 
                 Benzene, 1,2-dimethoxy-4-(2-propenyl)- 
                 Methyl Eugenol 
               
               
                 58 
                 Propanoic acid, 2-methyl-, 2-phenylethyl 
                 Phenyl Ethyl Iso Butyrate 
               
               
                   
                 ester 
               
               
                 59 
                 2-Propenenitrile, 3-phenyl- 
                 Cinnamalva 
               
               
                 60 
                 Benzene, [2-(1-propoxyethoxy)ethyl]- 
                 Acetal R 
               
               
                 61 
                 9-Undecenal, 2,6,10-trimethyl- 
                 Adoxal 
               
               
                 62 
                 2-Naphthalenol, 1,2,3,4,4a,5,6,7-octahydro- 
                 Ambrinol 20t 
               
               
                   
                 2,5,5-trimethyl- 
               
               
                 63 
                 2-Naphthalenol, octahydro-2,5,5-trimethyl- 
                 Ambrinol 20t 
               
               
                 64 
                 Ethanol, 2-[(1,7,7- 
                 Arbanol 
               
               
                   
                 trimethylbicyclo[2.2.1]hept-2-yl)oxy]-, exo- 
               
               
                 65 
                 1H-2-Benzopyran, 3,4,4a,5,8,8a(or 
                 Bigarade Oxide 
               
               
                   
                 3,4,4a,7,8,8a)-hexahydro-3,3,6,7- 
               
               
                 66 
                 Cyclohexene, 4-(1,5-dimethyl-4- 
                 Bisabolene 
               
               
                   
                 hexenylidene)-1-methyl- 
               
               
                 67 
                 1H-3a,7-Methanoazulene, octahydro-6- 
                 Cedramber 
               
               
                   
                 methoxy-3,6,8,8-tetramethyl-,[3R- 
               
               
                   
                 (3.alpha.,3a.beta.,6.alpha.,7.beta.,8a.alpha.)]- 
               
               
                 68 
                 Phenol, 4-chloro-3,5-dimethyl- 
                 4-Chloro 3,5 Xylenol 
               
               
                 69 
                 2,6-Octadiene, 1,1-diethoxy-3,7-dimethyl- 
                 Citrathal 
               
               
                 70 
                 Acetaldehyde, [(3,7-dimethyl-6- 
                 Citronellyl Oxyacetaldehyde 
               
               
                   
                 octenyl)oxy]- 
               
               
                 71 
                 Benzenepropanenitrile, .alpha.-ethenyl- 
                 Citrowanil B 
               
               
                   
                 .alpha.-methyl- 
               
               
                 72 
                 Cyclohexanol, 2-(1,1-dimethylpropyl)-, 
                 Coniferan 
               
               
                   
                 acetate 
               
               
                 73 
                 2H-1-Benzopyran-2-one 
                 Coumarin 
               
               
                 74 
                 1,3-Nonanediol, monoacetate 
                 Diasmol 
               
               
                 75 
                 Benzene, 1,1′-methylenebis- 
                 Diphenyl Methane 
               
               
                 76 
                 Benzene, 1,1′-oxybis- 
                 Diphenyl Oxide 
               
               
                 77 
                 1,6-Octadiene, 3-(1-ethoxyethoxy)-3,7- 
                 Elinthal 
               
               
                   
                 dimethyl- 
               
               
                 78 
                 Cyclopentanone, 2-heptyl- 
                 Fleuramone 
               
               
                 79 
                 5,8-Methano-2H-1-benzopyran-2-one, 6- 
                 Florex 
               
               
                   
                 ethylideneoctahydro- 
               
               
                 80 
                 Octanoic acid, 2-acetyl-, ethyl ester 
                 Gelsone 
               
               
                 81 
                 Indeno[1,2-d]-1,3-dioxin, 4,4a,5,9b- 
                 Indoflor Crist. 
               
               
                   
                 tetrahydro- 
               
               
                 82 
                 Benzeneacetic acid, 2-methylpropyl ester 
                 Iso Butyl Phenylacetate 
               
               
                 83 
                 2,6-Nonadienenitrile, 3,7-dimethyl- 
                 Lemonile 
               
               
                 84 
                 3-Decanone, 1-hydroxy- 
                 Methyl Lavender Ketone 
               
               
                 85 
                 Undecane, 1,1-dimethoxy-2-methyl- 
                 Methyl Nonyl Acetaldehyde 
               
               
                   
                   
                 Dimethyl Aceta 
               
               
                 86 
                 1-Propanone, 1-[2-methyl-5-(1-methylethyl)- 
                 Nerone 
               
               
                   
                 2-cyclohexen-1-yl]- 
               
               
                 87 
                 5,9-Undecadienal, 2,6,10-trimethyl- 
                 Oncidal 
               
               
                 88 
                 Quinoline, 6-methyl- 
                 Para Methyl Quinoline 
               
               
                 89 
                 Propanoic acid, 2-methyl-, 2-phenoxyethyl 
                 Phenoxy Ethyl Iso Butyrate 
               
               
                   
                 ester 
               
               
                 90 
                 Ethanol, 2-phenoxy-, propanoate 
                 Phenoxy Ethyl Propionate 
               
               
                   
                   
                 Formerly N-225 
               
               
                 91 
                 4,7-Methano-1H-indene-2-carboxaldehyde, 
                 Scentenal 
               
               
                   
                 octahydro-5-methoxy- 
               
               
                 92 
                 9-Undecen-2-one, 6,10-dimethyl- 
                 Tetra Hydro Psuedo Ionone 
               
               
                 93 
                 Benzenemethanol, .alpha.-(trichloromethyl)-, 
                 Trichloromethyl Phenyl 
               
               
                   
                 acetate 
                 Carbinyl Acetate 
               
               
                 94 
                 Phenol, 2-methoxy-4-(methoxymethyl)- 
                 Vaniwhite 
               
               
                 95 
                 Bicyclo[2.2.2]oct-5-ene-2-carboxaldehyde, 
                 Maceal 
               
               
                   
                 6-methyl-8-(1-methylethyl)- 
               
               
                 96 
                 Benzene, [2-(3-methylbutoxy)ethyl]- 
                 Phenyl Ether Isamyl Ether (Aka 
               
               
                   
                   
                 Anther) 
               
               
                 97 
                 2-Cyclohexene-1-carboxylic acid, 2,3,6,6- 
                 Givescone 
               
               
                   
                 tetramethyl-, ethyl ester 
               
               
                   
               
             
          
         
       
     
         [0028]    In one aspect, suitable Table 3 perfume raw materials include perfume raw materials from number 1 to number 58 and mixtures thereof. 
         [0029]    In one aspect, suitable Table 3 perfume raw materials include perfume raw materials from number 1 to number 39 and mixtures thereof. 
         [0030]    In one aspect, suitable perfume raw materials may be selected from the group consisting of 4-methoxybenzaldehyde; 4-phenylbutan-2-one; 3,7-dimethyl-2-methylene-6-octenal; 4-(2,6,6-trimethyl cyclohex-1-ene-1-yl) but-3-ene-2-one; 2,4-dimethylcyclohex-3-ene-1-carbaldehyde; 2-methyl-3-(para iso propylphenyl)propionaldehyde; 2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-; 1-cyclohexyl-ethylene-crotonate; 1-(2,6,6-trimethyl-3-cyclohexen-1-yl)-2-buten-1-one; 3-methyl cyclopentadecenone; 4-(2,6,6-trimethyl-1-cyclohexenyl)butan-2-one; 2,5-Dimethyl-2-octen-6-one; dihydro-nor-cyclopentadienyl acetate; 3-(o-(and p-)ethylphenyl)-2,2-dimethylpropionaldehyde; 3-(3-isopropylphenyl)butanal; 3-Buten-2-one, 3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-; alpha-methyl-3,4(methylenedioxy)hydrocinnamaldehyde; n-hexyl ortho hydroxy benzoate;  7 -acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7,tetramethyl naphthalene; 4-(1-Ethoxyvinyl)-3,3,5,5-tetramethyl-cyclohexan-1-one; 2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-, (R)-; 2,4-Dimethyl-3-cyclohexene-1-carboxaldehyde; 3,7-dimethyl-1,6-octadien-3-ol; 2,6-Dimethyl-5-Heptenal; Methyl Dihydro Jasmonate; Methyl Nonyl Acetaldehyde; 6,6-dimethoxy-2,5,5-trimethylhex-2-ene; 2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-, (R)-; Octaldehyde; 2-Cyclohexyl-1,6-heptadien-3-one and mixtures thereof. 
         [0031]    Suitable polymeric materials may comprise at least two moieties each of which may be independently selected from the group consisting of carboxylic acid, hydroxyl, ester, amide, amine, nitrile and thiol moieties. 
         [0032]    In one aspect, said polymeric compound comprises, per polymeric compound, at least two moieties selected from the moieties consisting of a carboxylic acid moiety, an amine moiety, a hydroxyl moiety, and a nitrile moiety. In one aspect, the polymeric material contains two or more carboxylic acid moieties on each polymeric molecule. In one aspect, polymeric materials may contain a backbone of polybutadiene, polyisoprene, polybutadiene/styrene, polybutadiene/acrylonitrile, carboxyl-terminated polybutadiene/acrylonitrile or combinations thereof. In another aspect, suitable polymeric materials encompass amine terminated, epoxy terminated, or vinyl terminated polymers. Suitable molecular weights for these polymers range from about 1,000 to about 10,000,000. In one aspect, the suitable polymers may have molecular weights that range from about 1,000 to about 10,000,000 or from about 2,000 to about 50,000. Suitable polymeric materials are available from NOVEON (Cleveland, Ohio U.S.A) and SARTOMER (Philadelphia, Pa. U.S.A.). Such materials include HYCAR® materials CTB 2000x162, CTBNX 1300x18, CTBNX 1300x9, CTBN 1300x8, CTBN 1300x31, ATB 2000x173, ATBN 1300x21, ATBN 1300x16, ATBN 1300x45, ATBN 1300x35, ATBN 1300x42, VTB 2000x168, VTBNX1300x33, VTBNX1300x43, ETBN 1300x40, and ETBN 1300x44 from NOVEON or Emerald Performance Materials of Cuyahoga Falls, Ohio U.S.A. and Krasol® LBH 5000 from SARTOMER. 
         [0033]    In one aspect, the benefit delivery composition may comprise a cross-linker. In any aspect, such cross-linker may provide covalent cross-linking and/or ionic cross-linking. In one aspect, the benefit agent delivery composition comprises a cross-linker at a concentration similar to the equivalence of the polymeric material. In one aspect, the equivalence ratio of cross-linker equivalence to the carboxylic acid equivalence within the composition is from about 0.5 to about 2.0. In one aspect, the equivalence ratio is from about 0.8 to about 1.2. The cross-linker can be any material that provides cross-linking when placed in the presence of the carboxylic acid containing polymer. Suitable cross-linkers include polyamines, expoxides and polycarbodiimides. In one aspect, the polycarbodiimide cross-linker compound may be ZOLDINE™ XL-29SE manufactured by Angus Chemical Company, a subsidiary of the Dow Chemical Company of Midland, Mich. U.S.A. In one aspect, polyamines may comprise diethylenetriamine, polyethyleneimines, polyvinylamines, and/or ethylene diamine moieties. 
         [0034]    In one aspect, the crosslinker comprises a polyamine that may comprise diethylenetriamine, ethylene diamine, polyethyleneimine, polyvinylamine, bis(3-aminopropyl)piperazine, N,N-Bis-(3-aminopropyl)methylamine, tris(2-aminoethyl)amine or mixtures thereof. 
         [0035]    Suitable polyamines include Lupasolg WF, SK, PS, PO100, P, HF, G500, G35, G20 water free, G20, G100, FG, FC, and PR8515 products supplied by BASF of Ludwigshaven, Germany. 
         [0036]    Other materials may be added to the benefit agent delivery compositions disclosed herein. For example, colorants can be added to such benefit agent delivery compositions including dyes and pigments. The colorant may be one or more oil soluble dyes. Such dyes may be added to the benefit agent prior to the formation of the benefit agent delivery compositions disclosed herein. Antioxidants may be added to benefit agent delivery compositions disclosed herein. Such antioxidants may protect benefit agents, including fragrances from oxidation. Suitable antioxidants include BHA supplied by Eastman Chemical Company of Kingsport Tenn. U.S.A. UV inhibitors can be added to benefit agent delivery compositions disclosed herein and may prevent discoloration. Suitable UV inhibitors include TINUVIN® commercial products supplied by Ciba® of Basel, Switzerland. 
         [0037]    Other materials maybe added to the benefit agent delivery compositions disclosed herein are materials that will help to process the benefit agent delivery compositions like solvents, diluents, surfactants, fatty acids, polymers, suitable materials are diluents like benzylbenzoate, nonionic surfactants like TAE80, fatty acids like coconut oil, polymers like PEG4000. 
         [0038]    In one aspect, the benefit agent delivery compositions of the present invention may be clear. However, such compositions may also be opaque. Such compositions can be made opaque by the addition of opacifying agents. Suitable opacifying agents include titanium dioxide, zinc oxide, inorganic salts, waxes, water, and other organic opacifiers that are well known to those of skilled in the art. 
         [0039]    Additional materials may be added to the benefit agent delivery compositions disclosed herein. Such materials may or may not be volatile. Such materials include solvents, oils, esters, phthalates, fatty acids, triglycerides, ethers, oils, aliphatic materials, hydrocarbons, plasticizers, and alcohols. Such materials may or may not be hydrophilic. Suitable hydrophilic materials include water, glycols, and alcohols. In one aspect, surfactants may be added to the benefit agent delivery compositions disclosed herein. Suitable surfactants include nonionic, anionic, cationic, and amphoteric surfactants--examples of which will be well known to those of skill in the art. The inclusion of surfactants may facilitate the inclusion of hydrophilic materials into the benefit agent delivery compositions disclosed herein. 
       Process of Making Benefit Agent Delivery Compositions 
       [0040]    The benefit agent delivery compositions disclosed in the present application may be made via the teachings of USPA 2006/0067963 A1, and the examples disclosed herein. 
         [0041]    The benefit agent containing compositions disclosed in the present application may be processed in accordance with the teachings of U.S. Pat. Nos. 6,451,751 B1, 6,972,276 B1, 6,764,986 B1, 6,740,713 B1 and the examples disclosed herein. Suitable forms for such benefit agent delivery compositions include, solids and fluids including agglomerates, emulsions, solutions, prills, beads and encapsulates. When employed to product a benefit agent delivery composition the particle size of the benefit agent delivery composition in said agglomerates, emulsions, solutions, prills, beads and encapsulates may be from about 0.1 microns to about 100 microns, from about 1 micron to about 60 microns or even from about 5 to about 40 microns. In addition to the foregoing, the benefit agent delivery compositions of the present invention may be further processed in accordance with the teachings of published US Patent Application No. 2007/0196502 A1 to yield a particle wherein the benefit agent delivery composition comprises at least a portion or even all of one or more layers of the resulting particle. 
         [0042]    In one aspect, a method for making a benefit agent delivery composition comprising:
       a.) mixing a first mixture, wherein said first mixture comprises: from about 15% to about 95% by weight of a volatile hydrophobic liquid; and from about 3% to about 40% by weight of a polymeric compound containing a carboxylic acid, until said first mixture is completely mixed; and mixing into said first mixture, from about 1.5% to about 40% by weight of a cross-linking agent; or   b.) mixing a first mixture, wherein said first mixture comprises: from about 15% to about 95% by weight of a volatile hydrophobic liquid; and from about 3% to about 40% by weight of a polymeric compound containing a carboxylic acid, until said first mixture is completely mixed; and mixing into said first mixture, from about 0% to about 40% by weight of a cross-linking agent; or   c.) mixing a first mixture, wherein said first mixture comprises: from about 15% to about 95% by weight of a volatile hydrophobic liquid; and from about 3% to about 40% by weight of a polymeric compound containing a carboxylic acid, until said first mixture is completely mixed; and mixing into said first mixture a second mixture, wherein said second mixture comprises: from 15% to about 95% by weight volatile hydrophobic liquid; and from about 1.5% to about 40% by weight of a cross-linking agent; or   d.) combining from about 15% to about 95% by weight of a volatile hydrophobic liquid; and from about 3% to about 40% by weight of a polymeric compound containing a carboxylic acid, until said first mixture is completely mixed; and mixing into said first mixture, from about 0% to about 40% by weight of a cross-linking agent;   e.) optionally combining the mixtures produced in a.), b.), c.) and/or d.) with a diluent and/or a surfactant; and/or further processing the mixtures produced in a.), b.), c.) and/or d.) to form a particle, bead and/or agglomerate is disclosed.       
 
         [0048]    In one aspect, the benefit agent delivery composition is pre-made and added to a consumer. 
         [0049]    In one aspect the components of the benefit agent delivery composition are added separately to a consumer product and the benefit agent delivery composition may form in the consumer before, during and/or after use by the consumer. 
         [0050]    In one aspect, when additional benefit agent(s) and/or benefit agent delivery system(s), for example perfume and/or encapsulated perfume, are employed to form a particle, bead and/or agglomerate, the benefit agent delivery composition of the present invention may be added before, during or after said additional benefit agent(s) and/or benefit agent delivery system(s) are added to said a particle, bead and/or agglomerate. 
         [0051]    In one aspect, when additional benefit agent(s) and/or benefit agent delivery system(s), for example perfume and/or encapsulated perfume, are employed, the benefit agent delivery composition of the present invention may be added before, during or after said additional benefit agent(s) and/or benefit agent delivery system(s) are added to a consumer. 
         [0052]    Suitable equipment for use in the processes disclosed herein may include continuous stirred tank reactors, homogenizers, turbine agitators, recirculating pumps, paddle mixers, ploughshear mixers, ribbon blenders, vertical axis granulators, twin screw extruders and drum mixers, both in batch and, where available, in continuous process configurations, spray dryers, and extruders. Such equipment can be obtained from Lodige GmbH (Paderbom, Germany), Littleford Day, Inc. (Florence, Ky., U.S.A.), Forberg A S (Larvik, Norway), Glatt Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark), Hosokawa Bepex Corp. (Minneapolis, Minn., USA), Arde Barinco (New Jersey, USA), Wenger (Sabetha, Kans. USA). 
       Compositions Comprising Benefit Agent Delivery Compositions 
       [0053]    Applicants&#39; compositions comprise an embodiment of the benefit agent delivery compositions disclosed in the present application. In one aspect, such compositions may be a consumer product. While the precise level of benefit agent delivery composition that is employed depends on the type and end use of the product comprising such composition, a products, including cleaning and/or fabric treatment products, may comprise, based on total product weight, from about 0.001% to about 25%, from about 0.01% to about 5%, or even from about 0.05% to about 3% benefit agent delivery composition. 
         [0054]    In one aspect, a consumer product comprising at least one embodiment of a benefit agent delivery composition disclosed herein and a material selected from the group consisting of a surfactant, an enzyme, a polymer, a dye, a neat perfume, a perfume delivery system in addition to Applicants&#39; benefit agent delivery system and mixtures thereof is disclosed. Suitable perfume delivery systems are described in published U.S. Patent Application No. 2007/0275866 A1 
         [0055]    Aspects of the invention include the use of the benefit agent delivery compositions of the present invention in laundry detergent compositions (e.g., TIDE™), hard surface cleaners (e.g., MR CLEAN™), automatic dishwashing liquids (e.g., CASCADE™), dishwashing liquids (e.g., DAWN™), and floor cleaners (e.g., SWIFFER™). Non-limiting examples of cleaning compositions may include those described in U.S. Pat. Nos. 4,515,705; 4,537,706; 4,537,707; 4,550,862; 4,561,998; 4,597,898; 4,968,451; 5,565,145; 5,929,022; 6,294,514; 6,376,445, 7,169,741 B2 and U.S. Pat. No. 7,297,674 B2 as well as in U.S. Patent Application Publication No. 2005/0130864 A1. The cleaning compositions disclosed herein may be formulated such that, during use in aqueous cleaning operations, the wash water will have a pH of between about 5 and about 12, or between about 7.5 and 10.5. Liquid dishwashing product formulations typically have a pH between about 6.8 and about 9.0. Cleaning products are typically formulated to have a pH of from about 7 to about 12. Techniques for controlling pH at recommended usage levels include the use of buffers, alkalis, acids, etc., and are well known to those skilled in the art. 
         [0056]    Fabric treatment compositions disclosed herein typically comprise a fabric softening active (“FSA”). Suitable fabric softening actives, include, but are not limited to, materials selected from the group consisting of quats, amines, fatty esters, sucrose esters, silicones, dispersible polyolefins, clays, polysaccharides, fatty oils, polymer latexes and mixtures thereof. 
       Adjunct Materials 
       [0057]    While not essential for the purposes of the present invention, the non-limiting list of adjuncts illustrated hereinafter are suitable for use in the instant compositions and may be desirably incorporated in certain embodiments of the invention, for example to assist or enhance performance, for treatment of the substrate to be cleaned, or to modify the aesthetics of the composition as is the case with perfumes, colorants, dyes or the like. It is understood that such adjuncts are in addition to the components that are supplied via Applicants&#39; delivery particles and FSAs. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the composition and the nature of the operation for which it is to be used. Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, additional perfume and perfume delivery systems, structure elasticizing agents, thickeners/structurants, fabric softeners, carriers, hydrotropes, processing aids and/or pigments. In addition to the disclosure below, suitable examples of such other adjuncts and levels of use are found in U.S. Pat. Nos. 5,576,282, 6,306,812 B1 and 6,326,348 B1 that are incorporated by reference. 
         [0058]    As stated, the adjunct ingredients are not essential to Applicants&#39; cleaning and fabric care compositions. Thus, certain embodiments of Applicants&#39; compositions do not contain one or more of the following adjuncts materials: bleach activators, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, additional perfumes and perfume delivery systems, structure elasticizing agents, thickeners/structurants, fabric softeners, carriers, hydrotropes, processing aids and/or pigments. However, when one or more adjuncts is present, such one or more adjuncts may be present as detailed below: 
         [0059]    Surfactants—The compositions according to the present invention can comprise a surfactant or surfactant system wherein the surfactant can be selected from nonionic and/or anionic and/or cationic surfactants and/or ampholytic and/or zwitterionic and/or semi-polar nonionic surfactants. The surfactant is typically present at a level of from about 0.1%, from about 1%, or even from about 5% by weight of the cleaning compositions to about 99.9%, to about 80%, to about 35%, or even to about 30% by weight of the cleaning compositions. 
         [0060]    Builders—The compositions of the present invention can comprise one or more detergent builders or builder systems. When present, the compositions will typically comprise at least about 1% builder, or from about 5% or 10% to about 80%, 50%, or even 30% by weight, of said builder. Builders include, but are not limited to, the alkali metal, ammonium and alkanolammonium salts of polyphosphates, alkali metal silicates, alkaline earth and alkali metal carbonates, aluminosilicate builders polycarboxylate compounds. ether hydroxypolycarboxylates, copolymers of maleic anhydride with ethylene or vinyl methyl ether, 1,3,5-trihydroxybenzene-2,4,6-trisulphonic acid, and carboxymethyl-oxysuccinic acid, the various alkali metal, ammonium and substituted ammonium salts of polyacetic acids such as ethylenediamine tetraacetic acid and nitrilotriacetic acid, as well as polycarboxylates such as mellitic acid, succinic acid, oxydisuccinic acid, polymaleic acid, benzene 1,3,5-tricarboxylic acid, carboxymethyloxysuccinic acid, and soluble salts thereof. 
         [0061]    Chelating Agents—The compositions herein may also optionally contain one or more copper, iron and/or manganese chelating agents. If utilized, chelating agents will generally comprise from about 0.1% by weight of the compositions herein to about 15%, or even from about 3.0% to about 15% by weight of the compositions herein. 
         [0062]    Dye Transfer Inhibiting Agents—The compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof. When present in the compositions herein, the dye transfer inhibiting agents are present at levels from about 0.0001%, from about 0.01%, from about 0.05% by weight of the cleaning compositions to about 10%, about 2%, or even about 1% by weight of the cleaning compositions. 
         [0063]    Dispersants—The compositions of the present invention can also contain dispersants. Suitable water-soluble organic materials are the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid may comprise at least two carboxyl radicals separated from each other by not more than two carbon atoms. 
         [0064]    Enzymes—The compositions can comprise one or more detergent enzymes which provide cleaning performance and/or fabric care benefits. Examples of suitable enzymes include, but are not limited to, hemicellulases, peroxidases, proteases, cellulases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, keratanases, reductases, oxidases, phenoloxidases, lipoxygenases, ligninases, pullulanases, tannases, pentosanases, malanases, B-glucanases, arabinosidases, hyaluronidase, chondroitinase, laccase, and amylases, or mixtures thereof. A typical combination is a cocktail of conventional applicable enzymes like protease, lipase, cutinase and/or cellulase in conjunction with amylase. 
         [0065]    Enzyme Stabilizers—Enzymes for use in compositions, for example, detergents can be stabilized by various techniques. The enzymes employed herein can be stabilized by the presence of water-soluble sources of calcium and/or magnesium ions in the finished compositions that provide such ions to the enzymes. 
         [0066]    Catalytic Metal Complexes—Applicants&#39; compositions may include catalytic metal complexes. One type of metal-containing bleach catalyst is a catalyst system comprising a transition metal cation of defined bleach catalytic activity, such as copper, iron, titanium, ruthenium, tungsten, molybdenum, or manganese cations, an auxiliary metal cation having little or no bleach catalytic activity, such as zinc or aluminum cations, and a sequestrate having defined stability constants for the catalytic and auxiliary metal cations, particularly ethylenediaminetetraacetic acid, ethylenediaminetetra (methyl-enephosphonic acid) and water-soluble salts thereof. Such catalysts are disclosed in U.S. Pat. No. 4,430,243. 
         [0067]    If desired, the compositions herein can be catalyzed by means of a manganese compound. Such compounds and levels of use are well known in the art and include, for example, the manganese-based catalysts disclosed in U.S. Pat. No. 5,576,282. 
         [0068]    Cobalt bleach catalysts useful herein are known, and are described, for example, in U.S. Pat. Nos. 5,597,936 and 5,595,967. Such cobalt catalysts are readily prepared by known procedures, such as taught for example in U.S. Pat. Nos. 5,597,936, and 5,595,967. 
         [0069]    Compositions herein may also suitably include a transition metal complex of a macropolycyclic rigid ligand—abreviated as “MRL”. As a practical matter, and not by way of limitation, the compositions and cleaning processes herein can be adjusted to provide on the order of at least one part per hundred million of the benefit agent MRL species in the aqueous washing medium, and may provide from about 0.005 ppm to about 25 ppm, from about 0.05 ppm to about 10 ppm, or even from about 0.1 ppm to about 5 ppm, of the MRL in the wash liquor. 
         [0070]    Suitable transition-metals in the instant transition-metal bleach catalyst include manganese, iron and chromium. Suitable MRL&#39;s herein are a special type of ultra-rigid ligand that is cross-bridged such as 5,12-diethyl-1,5,8,12-tetraazabicyclo[6.6.2]hexa-decane. 
         [0071]    Suitable transition metal MRLs are readily prepared by known procedures, such as taught for example in WO 00/32601, and U.S. Pat. No. 6,225,464. 
         [0072]    Suitable thickeners/structurants and useful levels of same are described in U.S. Patent Application Publication No. 2005/0130864 A1 and U.S. Pat. Nos. 7,169,741 B2 and 7,297,674 B2. 
       Processes of Making and Using Compositions 
       [0073]    The compositions of the present invention can be formulated into any suitable form and prepared by any process chosen by the formulator, non-limiting examples of which are described in U.S. Pat. No. 5,879,584; U.S. Pat. No. 5,691,297; U.S. Pat. No. 5,574,005; U.S. Pat. No. 5,569,645; U.S. Pat. No. 5,565,422; U.S. Pat. No. 5,516,448; U.S. Pat. No. 5,489,392; U.S. Pat. No. 5,486,303 all of which are incorporated herein by reference. 
       Method of Use 
       [0074]    Compositions containing the benefit agent delivery composition disclosed herein can be used to clean or treat a situs inter alia a surface or fabric. Typically at least a portion of the situs is contacted with an embodiment of Applicants&#39; composition, in neat form or diluted in a liquor, for example, a wash liquor and then the situs may be optionally washed and/or rinsed. In one aspect, a situs is optionally washed and/or rinsed, contacted with a particle according to the present invention or composition comprising said particle and then optionally washed and/or rinsed. For purposes of the present invention, washing includes but is not limited to, scrubbing, and mechanical agitation. The fabric may comprise most any fabric capable of being laundered or treated in normal consumer use conditions. Liquors that may comprise the disclosed compositions may have a pH of from about 3 to about 11.5. Such compositions are typically employed at concentrations of from about 500 ppm to about 15,000 ppm in solution. When the wash solvent is water, the water temperature typically ranges from about 5° C. to about 90° C. and, when the situs comprises a fabric, the water to fabric ratio is typically from about 1:1 to about 30:1. 
       Packaging Comprising Benefit Agent Delivery Compositions 
       [0075]    In one aspect, packaging comprising the benefit agent delivery compositions is disclosed. Such packaging may be used to package a product such as a consumer product. The benefit delivery compositions of the present invention may be adhered or attached any where on such packaging. Such packing may take any form including wrapping, or a container. In one aspect, a benefit agent delivery composition disclosed herein may be adhered or attached to the exterior and/or the interior surface of such packaging. In one aspect, said packaging may comprise a container comprising a cap and said benefit agent delivery composition disclosed herein is adhered or attached to the exterior or interior surface of said cap. 
       Displays Comprising Benefit Agent Delivery Compositions 
       [0076]    In one aspect, a display comprising the benefit agent delivery compositions is disclosed. Such display may be used to attract attention to, market and/or assist in whole or in part the sale of a product such as a consumer product. The benefit delivery compositions of the present invention may be adhered or attached any where on such display. Such display may take any form including posters, sales and/or marketing literature, or a container. In one aspect, a benefit agent delivery composition disclosed herein is adhered or attached to the exterior and/or the interior surface of such display. 
       EXAMPLES 
       [0077]    While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention. 
       Example 1 
       [0078]    Equal amounts a perfume composition and amine-terminated Hycar® ATBN1300X42 from Noveon are weighted and mixed for five minutes using a Ultra-Turrax as needed. The ingredients are put at 60° C. in warm water bath for 1 hour before use/mixing. After mixing the mixture is put in a warm water bath at 60° C. for ±12 hours. A homogenous, viscous and sticky material is obtained. 
         [0079]    In the same way as described above different ratios between the components can be used: 
         [0000]    
       
         
               
             
               
               
               
               
               
               
               
             
           
               
                   
               
               
                 Weight % 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                   
                 Perfume composition 
                 40 
                 50 
                 60 
                 70 
                 80 
               
               
                   
                 Hycar ® 1300X42 
                 60 
                 50 
                 40 
                 30 
                 20 
               
               
                   
                   
               
             
          
         
       
     
       Example 2 
       [0080]    A mixture comprising 50% of a perfume composition, 40% of carboxyl-terminated Hycar ® 1300X18 (CAS#0068891-50-9) from Noveon, (put at 60° C. in warm water bath for 1 hour before mixing) and 10% of Lupasol® WF(CAS#09002-98-6) from BASF (put at 60° C. in warm water bath for 1 hour before mixing). Mixing is achieved by mixing for five minutes using a Ultra-Turrax T25 Basic equipment (from IKA). After mixing, the mixture is put in a warm water bath at 60° C. for ±12 hours. A homogenous, viscous and sticky material is obtained. In the same way as described above different ratios between the components can be used: 
         [0000]    
       
         
               
             
               
               
               
               
               
               
               
             
           
               
                   
               
               
                 Weight % 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                   
                 Perfume composition 
                 40 
                 50 
                 60 
                 70 
                 80 
               
               
                   
                 Lupasol ® WF 
                 12 
                 10 
                 8 
                 6 
                 4 
               
               
                   
                 Hycar ® 
                 48 
                 40 
                 32 
                 24 
                 16 
               
               
                   
                 CTBN1300X18 
               
               
                   
                   
               
             
          
         
       
     
         [0000]    
       
         
               
             
               
               
               
               
               
               
               
               
               
             
           
               
                   
               
               
                 Weight % 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Perfume composition 
                 50 
                 50 
                 50 
                 50 
                 50 
                 50 
                 50 
                 50 
               
               
                 Lupasol ® WF 
                 2.5 
                 5 
                 7.5 
                 10 
                 12.5 
                 15 
                 17.5 
                 20 
               
               
                 Hycar ® CTBN 
                 47.5 
                 45 
                 42.5 
                 40 
                 37.5 
                 35 
                 32.5 
                 30 
               
               
                 1300X18 
               
               
                   
               
             
          
         
       
     
       Example 3 
       [0081]    A mixture comprising 50% of a perfume composition, 40% of carboxyl-terminated Hycar® CTBN 1300X18 from Noveon (put at 60° C. in warm water bath for 1 hour before mixing) and 10% of Lupasol® WF (CAS#09002-98-6) from BASF (put at 60° C. in warm water bath for 1 hour before use) is formed. 
         [0082]    Mixing is achieved by mixing for five minutes using a Ultra-Turrax T25 Basic equipment (from IKA). After mixing, the mixture is put in a warm water bath at 60° C. for ±12 hours. A homogenous, viscous and sticky material is obtained. 
       Example 4 
       [0083]    In a first step of the preparation the Lupasol® WF (CAS#09002-98-6) from BASF 15% is used in combination with 35% of carboxyl-terminated Hycar® CTBN1300X18 and 17% of this polymer mix is diluted with 83% of Benzyl Benzoate to make a workable solution. The materials described above are put together, in the ratio&#39;s described above, in a glass jar at 80° C. on a hot plate with stirring using a magnetic stirrer. Next the polymer premix is mixed with a perfume composition in a 1:1 ratio. This polymer—perfume mix is than added to a fabric enhancer composition. 
       Example 5 
     Agglomeration of Benefit Agent Delivery Composition—Perfume System for use in Powder Detergents 
       [0084]    Starting from any of Examples 1 to 3 as described above: 
         [0085]    The resulting homogenous, viscous and sticky material is held at 60° for ±2 hours before starting the agglomeration process. Next, a mixture comprising 40% of the viscous, sticky sample and 60% of melted TAE80 is formed by combining and mixing with an Ultra-Turrax T25 Basic equipment (from IKA) for 5 to 10 minutes. Then, 1 part of the TAE80/sticky sample is very slowly added to 0.6 parts of light soda ash using a Braun kitchen robot to form agglomerates. The resulting agglomerates are then used in a powder detergent. 
       Example 6 
     Liquid Application 
       [0086]    Starting from any of Examples 1 to 3 as described above: 
         [0087]    The resulting homogenous, viscous and sticky material is held at 60° for ±2 hours before starting the dilution process. 
         [0000]    
       
         
               
             
               
               
               
               
               
               
               
             
           
               
                   
               
               
                 Weight % 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                   
                 Sticky sample 
                 20 
                 30 
                 40 
                 50 
                 60 
               
               
                   
                 Benzyl benzoate or 
                 80 
                 70 
                 60 
                 50 
                 40 
               
               
                   
                 fatty acid 
               
               
                   
                   
               
             
          
         
       
     
         [0088]    The viscous sticky material obtained as described in any of Examples 1-3 above are mixed at different ratios for five minutes using an Ultra-Turrax T25 Basic equipment (from IKA), at the levels listed in the table above, with benzyl benzoate before the resulting mixture is a added to a liquid detergent. 
       Example 7  
       [0089]    Different process manner of obtaining the consumer benefit delivery agent system. Addition of the different ingredients without premixing of the materials: The following are mixed without premixing/premixtures being formed. 
         [0000]    
       
         
               
             
               
               
               
               
               
               
             
           
               
                   
               
               
                 Weight % 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                   
                 Perfume composition 
                 40 
                 50 
                 60 
                 70 
               
               
                   
                 Lupasol ® wf 
                 12 
                 10 
                 8 
                 6 
               
               
                   
                 Via premix in H 2 O (50%/50%) 
               
               
                   
                 Hycar ® CTBN 1300X18 
                 48 
                 40 
                 32 
                 24 
               
               
                   
                 Via premix in Benzyl Benzoate 
               
               
                   
                 (20%/80% Benzyl Benzoate) 
               
               
                   
                   
               
             
          
         
       
     
       Example 8 
       [0090]    Non-limiting examples of product formulations containing a benefit agent delivery composition are summarized in the following table. 
         [0000]    
       
         
               
               
             
               
               
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
               
             
           
               
                   
                   
               
               
                   
                 EXAMPLES 
               
             
          
           
               
                 (% wt) 
                 XI 
                 XII 
                 XIII 
                 XIV 
                 XV 
                 XVI 
                 XVII 
                 XVIII 
                 XIX 
                 XX 
               
               
                   
               
             
          
           
               
                 FSA a   
                 14 
                 16.47 
                 14 
                 12 
                 12 
                 16.47 
                 — 
                 — 
                 5 
                 5 
               
               
                 FSA b   
                   
                   
                   
                   
                 — 
                   
                 3.00 
                 — 
                 — 
                 — 
               
               
                 FSA c   
                   
                   
                   
                   
                 — 
                   
                 — 
                 6.5 
                 — 
                 — 
               
               
                 Ethanol 
                 2.18 
                 2.57 
                 2.18 
                 1.95 
                 1.95 
                 2.57 
                 — 
                 — 
                 0.81 
                 0.81 
               
               
                 Isopropyl 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 0.33 
                  1.22 
                 — 
                 — 
               
               
                 Alcohol 
               
               
                 Starch d   
                 1.25 
                 1.47 
                 2.00 
                 1.25 
                 — 
                 2.30 
                 0.5 
                  0.70 
                 0.71 
                 0.42 
               
               
                 Benefit agent 
                 0.6 
                 0.75 
                 0.6 
                 0.75 
                 0.37 
                 0.60 
                 0.37 
                 0.6 
                 0.37 
                 0.37 
               
               
                 delivery 
               
               
                 composition 
               
               
                 Phase 
                 0.21 
                 0.25 
                 0.21 
                 0.21 
                 0.14 
                 — 
                 — 
                  0.14 
                 — 
                 — 
               
               
                 Stabilizing 
               
               
                 Polymer f   
               
               
                 Suds 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 0.1 
                 — 
                 — 
               
               
                 Suppressor g   
               
               
                 Calcium 
                 0.15 
                 0.176 
                 0.15 
                 0.15 
                 0.30 
                 0.176 
                 — 
                 0.1-0.15 
                 — 
                 — 
               
               
                 Chloride 
               
               
                 DTPA h   
                 0.017 
                 0.017 
                 0.017 
                 0.017 
                 0.007 
                 0.007 
                 0.20 
                 — 
                 0.002 
                 0.002 
               
               
                 Preservative 
                 5 
                 5 
                 5 
                 5 
                 5 
                 5 
                 — 
                 250 j    
                 5 
                 5 
               
               
                 (ppm) i, j   
               
               
                 Antifoam k   
                 0.015 
                 0.018 
                 0.015 
                 0.015 
                 0.015 
                 0.015 
                 — 
                 — 
                 0.015 
                 0.015 
               
               
                 Dye 
                 40 
                 40 
                 40 
                 40 
                 40 
                 40 
                 11 
                 30-300 
                 30 
                 30 
               
               
                 (ppm) 
               
               
                 Ammonium 
                 0.100 
                 0.118 
                 0.100 
                 0.100 
                 0.115 
                 0.115 
                 — 
                 — 
                 — 
                 — 
               
               
                 Chloride 
               
               
                 HCl 
                 0.012 
                 0.014 
                 0.012 
                 0.012 
                 0.028 
                 0.028 
                 0.016 
                  0.025 
                 0.011 
                 0.011 
               
               
                 Structurant l   
                 0.01 
                 0.01 
                 0.01 
                 0.01 
                 0.01 
                 0.01 
                 0.01 
                  0.01 
                 0.01 
                 0.01 
               
               
                 Neat 
                 0.8 
                 0.7 
                 0.9 
                 0.5 
                 1.2 
                 0.5 
                 1.1 
                 0.6 
                 1.0 
                 0.9 
               
               
                 Perfume 
               
               
                 Deionized 
                 * 
                 * 
                 * 
                 * 
                 * 
                 * 
                 * 
                 * 
                 * 
                 * 
               
               
                 Water 
               
               
                   
               
               
                 *Balance 
               
               
                   a N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride. 
               
               
                   b Methyl bis(tallow amidoethyl)2-hydroxyethyl ammonium methyl sulfate. 
               
               
                   c Reaction product of Fatty acid with Methyldiethanolamine in a molar ratio 1.5:1, quaternized with Methylchloride, resulting in a 1:1 molar mixture of N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride and N-(stearoyl-oxy-ethyl) N,-hydroxyethyl N,N dimethyl ammonium chloride. 
               
               
                   d Cationic high amylose maize starch available from National Starch under the trade name CATO ®. 
               
               
                   f Copolymer of ethylene oxide and terephthalate having the formula described in U.S. Pat. No. 5,574,179 at col.15, lines 1-5, wherein each X is methyl, each n is 40, u is 4, each R1 is essentially 1,4-phenylene moieties, each R2 is essentially ethylene, 1,2-propylene moieties, or mixtures thereof. 
               
               
                   g SE39 from Wacker 
               
               
                   h Diethylenetriaminepentaacetic acid. 
               
               
                   i KATHON ® CG available from Rohm and Haas Co. “PPM” is “parts per million.” 
               
               
                   j Gluteraldehyde 
               
               
                   k Silicone antifoam agent available from Dow Corning Corp. under the trade name DC2310. 
               
               
                   l Hydrophobically-modified ethoxylated urethane available from Rohm and Haas under the tradename Aculan 44. 
               
             
          
         
       
     
       Example 9  
     Benefit Agent Delivery Composition in Dry Laundry Formulations 
       [0091]      
         [0000]    
       
         
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
           
               
                   
                   
               
               
                   
                 % w/w granular laundry detergent composition 
               
             
          
           
               
                 Component 
                 A 
                 B 
                 C 
                 D 
                 E 
                 F 
                 G 
               
               
                   
               
             
          
           
               
                 Brightener 
                 0.1 
                 0.1 
                 0.1 
                 0.2 
                 0.1 
                 0.2 
                 0.1 
               
               
                 Soap 
                 0.6 
                 0.6 
                 0.6 
                 0.6 
                 0.6 
                 0.6 
                 0.6 
               
               
                 Ethylenediamine disuccinic acid 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
               
               
                 Acrylate/maleate copolymer 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 Hydroxyethane di(methylene 
                 0.4 
                 0.4 
                 0.4 
                 0.4 
                 0.4 
                 0.4 
                 0.4 
               
               
                 phosphonic acid) 
               
               
                 Mono-C 12-14  alkyl, di-methyl, 
                 0.5 
                 0.5 
                 0.5 
                 0.5 
                 0.5 
                 0.5 
                 0.5 
               
               
                 mono-hydroxyethyl quaternary 
               
               
                 ammonium chloride 
               
               
                 Linear alkyl benzene 
                 0.1 
                 0.1 
                 0.2 
                 0.1 
                 0.1 
                 0.2 
                 0.1 
               
               
                 Linear alkyl benzene sulphonate 
                 10.3 
                 10.1 
                 19.9 
                 14.7 
                 10.3 
                 17 
                 10.5 
               
               
                 Magnesium sulphate 
                 0.4 
                 0.4 
                 0.4 
                 0.4 
                 0.4 
                 0.4 
                 0.4 
               
               
                 Sodium carbonate 
                 19.5 
                 19.2 
                 10.1 
                 18.5 
                 29.9 
                 10.1 
                 16.8 
               
               
                 Sodium sulphate 
                 29.6 
                 29.8 
                 38.8 
                 15.1 
                 24.4 
                 19.7 
                 19.1 
               
               
                 Sodium Chloride 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
               
               
                 Zeolite 
                 9.6 
                 9.4 
                 8.1 
                 18 
                 10 
                 13.2 
                 17.3 
               
               
                 Photobleach particle 
                 0.1 
                 0.1 
                 0.2 
                 0.1 
                 0.2 
                 0.1 
                 0.2 
               
               
                 Blue and red carbonate speckles 
                 1.8 
                 1.8 
                 1.8 
                 1.8 
                 1.8 
                 1.8 
                 1.8 
               
               
                 Ethoxylated Alcohol AE7 
                 1 
                 1 
                 1 
                 1 
                 1 
                 1 
                 1 
               
               
                 Tetraacetyl ethylene diamine 
                 0.9 
                 0.9 
                 0.9 
                 0.9 
                 0.9 
                 0.9 
                 0.9 
               
               
                 agglomerate (92 wt % active) 
               
               
                 Citric acid 
                 1.4 
                 1.4 
                 1.4 
                 1.4 
                 1.4 
                 1.4 
                 1.4 
               
               
                 PDMS/clay agglomerates (9.5% wt % 
                 10.5 
                 10.3 
                 5 
                 15 
                 5.1 
                 7.3 
                 10.2 
               
               
                 active PDMS) 
               
               
                 Polyethylene oxide 
                 0.2 
                 0.2 
                 0.2 
                 0.2 
                 0.2 
                 0.2 
                 0.2 
               
               
                 Enzymes e.g. Protease (84 mg/g active), 
                 0.2 
                 0.3 
                 0.2 
                 0.1 
                 0.2 
                 0.1 
                 0.2 
               
               
                 Amylase (22 mg/g active) 
               
               
                 Suds suppressor agglomerate 
                 0.2 
                 0.2 
                 0.2 
                 0.2 
                 0.2 
                 0.2 
                 0.2 
               
               
                 (12.4 wt % active) 
               
               
                 Sodium percarbonate (having 
                 7.2 
                 7.1 
                 4.9 
                 5.4 
                 6.9 
                 19.3 
                 13.1 
               
               
                 from 12% to 15% active AvOx) 
               
               
                 Perfume oil 
                 0.5 
                 0.5 
                 0.5 
                 0.5 
                 0.5 
                 0.5 
                 0.5 
               
               
                 Solid perfume particles 
                 0.4 
                 0 
                 0.4 
                 0.4 
                 0.4 
                 0.4 
                 0.6 
               
               
                 Benefit agent delivery composition 
                 1.3 
                 2.4 
                 1 
                 1.3 
                 1.3 
                 1.3 
                 0.7 
               
               
                 Water 
                 1.4 
                 1.4 
                 1.4 
                 1.4 
                 1.4 
                 1.4 
                 1.4 
               
               
                 Misc. 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
                 0.1 
               
               
                 Total Parts 
                 100 
                 100 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                   
               
             
          
         
       
     
       Example 10  
     Liquid Laundry Formulations (HDLs) 
       [0092]      
         [0000]    
       
         
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
             
           
               
                   
               
               
                 Ingredient 
                 HDL 1 
                 HDL 2 
                 HDL3 
                 HDL4 
                 HDL 5 
                 HDL 6 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Alkyl Ether Sulphate 
                 0.00 
                 0.50 
                 12.0 
                 12.0 
                 6.0 
                 7.0 
               
               
                 Dodecyl Benzene 
                 8.0 
                 8.0 
                 1.0 
                 1.0 
                 2.0 
                 3.0 
               
               
                 Sulphonic Acid 
               
               
                 Ethoxylated Alcohol 
                 8.0 
                 6.0 
                 5.0 
                 7.0 
                 5.0 
                 3.0 
               
               
                 Citric Acid 
                 5.0 
                 3.0 
                 3.0 
                 5.0 
                 2.0 
                 3.0 
               
               
                 Fatty Acid 
                 3.0 
                 5.0 
                 5.0 
                 3.0 
                 6.0 
                 5.0 
               
               
                 Ethoxysulfated 
                 1.9 
                 1.2 
                 1.5 
                 2.0 
                 1.0 
                 1.0 
               
               
                 hexamethylene diamine 
               
               
                 quaternized 
               
               
                 Diethylene triamine penta 
                 0.3 
                 0.2 
                 0.2 
                 0.3 
                 0.1 
                 0.2 
               
               
                 methylene phosphonic acid 
               
               
                 Enzymes 
                 1.20 
                 0.80 
                 0 
                 1.2 
                 0 
                 0.8 
               
               
                 Brightener (disulphonated 
                 0.14 
                 0.09 
                 0 
                 0.14 
                 0.01 
                 0.09 
               
               
                 diamino stilbene based FWA) 
               
               
                 Cationic hydroxyethyl cellulose 
                 0 
                 0 
                 0.10 
                 0 
                 0.200 
                 0.30 
               
               
                 Poly(acrylamide-co- 
                 0 
                 0 
                 0 
                 0.50 
                 0.10 
                 0 
               
               
                 diallyldimethylammonium chloride) 
               
               
                 Hydrogenated Castor Oil 
                 0.50 
                 0.44 
                 0.2 
                 0.2 
                 0.3 
                 0.3 
               
               
                 Structurant 
               
               
                 Boric acid 
                 2.4 
                 1.5 
                 1.0 
                 2.4 
                 1.0 
                 1.5 
               
               
                 Ethanol 
                 0.50 
                 1.0 
                 2.0 
                 2.0 
                 1.0 
                 1.0 
               
               
                 1,2 propanediol 
                 2.0 
                 3.0 
                 1.0 
                 1.0 
                 0.01 
                 0.01 
               
               
                 Glutaraldehyde 
                 0 
                 0 
                 19 ppm 
                 0 
                 13 ppm 
                 0 
               
               
                 Diethyleneglycol (DEG) 
                 1.6 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 2,3-Methyl-1,3- 
                 1.0 
                 1.0 
                 0 
                 0 
                 0 
                 0 
               
               
                 propanediol (M pdiol) 
               
               
                 Mono Ethanol Amine 
                 1.0 
                 0.5 
                 0 
                 0 
                 0 
                 0 
               
               
                 NaOH Sufficient To 
                 pH 8 
                 pH 8 
                 pH 8 
                 pH 8 
                 pH 8 
                 pH 8 
               
               
                 Provide Formulation pH of: 
               
               
                 Sodium Cumene 
                 2.00 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 Sulphonate (NaCS) 
               
               
                 Silicone (PDMS) emulsion 
                 0.003 
                 0.003 
                 0.003 
                 0.003 
                 0.003 
                 0.003 
               
               
                 Perfume 
                 0.7 
                 0.5 
                 0.8 
                 0.8 
                 0.6 
                 0.6 
               
               
                 Polyethyleneimine 
                 0.01 
                 0.10 
                 0.00 
                 0.10 
                 0.20 
                 0.05 
               
               
                 Benefit Agent Delivery 
                 1.00 
                 5.00 
                 1.00 
                 2.00 
                 0.10 
                 0.80 
               
               
                 Composition 
               
               
                 Water 
                 Balance 
                 Balance 
                 Balance 
                 Balance 
                 Balance 
                 Balance 
               
               
                   
                 to 
                 to 
                 to 
                 to 
                 to 
                 to 
               
               
                   
                 100% 
                 100% 
                 100% 
                 100% 
                 100% 
                 100% 
               
               
                   
               
             
          
         
       
     
         [0093]    The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm”. 
         [0094]    All documents cited in the Detailed Description of the Invention are, in relevant part, incorporated herein by reference; the citation of any document is not to be construed as an admission that it is prior art with respect to the present invention. To the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern. 
         [0095]    While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.