Abstract:
A semiconductor light emitting device and a method to form the same are disclosed. The device has at least one porous or low density dielectric region formed in or on top of a bottom electrode, at least one top electrode on the porous or low density dielectric region, and one or more color filters placed above the top electrode, wherein the porous or low density dielectric region contains light emitting nanocrystal materials.

Description:
BACKGROUND 
       [0001]    The present invention relates generally to an integrated circuit (IC) design, and more particularly to light emitting technologies that can be produced in the same substrate along with a control circuit device. 
         [0002]    Light emitting technology has been one of the fastest growing industries in recent years. The improvement in the technology has shrunk the size of many products such as computer displays by providing new generations of products such as the liquid crystal displays (LCD). 
         [0003]    One conventional method for fabricating a light emitting device today is to implant a number of ultra-fine particles, which are also known as nanocrystals, into a thick dielectric layer above the silicon surface. These nanocrystals can be made of materials such as silicon (Si), germanium (Ge), or a combination of the two materials (SiGe). The dielectric layer is made of silicon-oxide (SiO 2 ), and it is a proven combination of materials that provides good control over the fabrication process. 
         [0004]    However, this conventional method suffers from various critically important pitfalls. For example, it provides a poor gate dielectric layer interface, which reduces the ability to optimally form nanocrystals into the dielectric layer above the silicon surface. The CMOS device performance may also be poor due to poor hole mobility. The thick SiO 2  dielectric layer also means a higher material cost during fabrication. It is also difficult to combine the light emitting devices and control circuit devices on the same substrate with this conventional method. This is a major issue since the light emitting devices need to be assembled with many VLSI control circuit devices. 
         [0005]    It is therefore desirable to design methods for a fabricating light emitting device that can be easily integrated with a control circuit without driving up fabrication cost. 
       SUMMARY 
       [0006]    In view of the foregoing, this invention provides light emitting devices and methods for allowing the light emitting devices to be produced in the same substrate along with a control circuit device. In various embodiments of the present invention, methods for creating a light emitting device are shown. The device has at least one porous or low density dielectric region formed in or on top of a bottom electrode, at least one top electrode on the porous or low density dielectric region, and one or more color filters placed above the top electrode, wherein the porous or low density dielectric region contains light emitting nanocrystal materials. As the device is generated using a CMOS process, they can be manufactured along with the control circuit. 
         [0007]    The construction and method of operation of the invention, however, together with additional objectives and advantages thereof will be best understood from the following description of specific embodiments when read in connection with the accompanying drawings. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0008]      FIG. 1  illustrates a conventional semiconductor cross-section of a light emitting device. 
           [0009]      FIG. 2A  illustrates a semiconductor cross-section of a light emitting device with nanocrystals implanted into a dielectric layer comprised of porous or low density oxide in accordance to one embodiment of the present invention. 
           [0010]      FIG. 2B  illustrates a semiconductor cross-section of a light emitting device with nanocrystals implanted into a dielectric layer comprised of porous or low density oxide in accordance to another embodiment of the present invention. 
           [0011]      FIG. 2C  illustrates a semiconductor cross-section of a light emitting device with nanocrystals implanted into a dielectric layer comprised of porous or low density oxide in accordance to another embodiment of the present invention. 
           [0012]      FIG. 3  illustrates a three-pixel circuit in accordance to various embodiments of the present invention. 
       
    
    
     DESCRIPTION 
       [0013]    The present disclosure provides several methods for fabricating light emitting devices such that the light emitting device is produced in the same substrate along with the control circuit device. 
         [0014]      FIG. 1  illustrates a conventional semiconductor cross-section  100  of a light emitting device with nanocrystals implanted into a thick dielectric layer (e.g., comprised of silicon-oxide) that is formed above the silicon substrate. A thick dielectric layer  102  is formed above a silicon substrate  104 . The thickness of the dielectric layer  102  can affect the color generated by the light emitting device. The dielectric layer  102  is typically made of silicon-oxide (SiO 2 ), which provides good control over the fabrication process. A number of nanocrystals  106 , which are ultra-fine particles, are implanted into the thick dielectric layer  102  above the surface of the silicon substrate  104  as a light emitting medium. These nanocrystals  106  can be made of materials such as silicon (Si), germanium (Ge), or a combination thereof. 
         [0015]    However, this conventional design presents several issues. For example, a relatively poor gate dielectric layer interface prevents an optimum formation of the nanocrystals. The CMOS device performance may also be poor due to poor hole mobility. A high material cost is inevitable due to the thick dielectric layer  102 . 
         [0016]      FIG. 2A  illustrates a cross-section  200  of a light emitting device with nanocrystals implanted into a dielectric layer comprising porous or low density oxide in accordance to one embodiment of the present invention. In this embodiment, the porous or low density oxide is formed within a shallow trench isolation created within the silicon substrate. 
         [0017]    In the cross-section  200 , a shallow trench isolation (STI)  202  is created within a silicon substrate  204 . The STI  202 , used as a dielectric layer, is filled with a type of porous or low density oxide. This porous or low density oxide is preferably a low-K material; sub-atmospheric chemical vapor deposition (SACVD) oxide or plasma enhanced chemical vapor deposition (PECVD) oxide, and increases its formation efficiency by having a plurality of nanocrystals  206 . The porous size of porous materials is at least larger than 2 nm. The low density oxide has a wet etching rate greater than 200A/min in 50:1 HF solution. As an example, the porous or low density oxide can be placed through an SACVD or PECVD. The porous or low density oxide can help improve the hole mobility and gate dielectric layer interface. The nanocrystals  206  are implanted into the porous or low density oxide within the STI  202  as a light emitting medium, and the implantation methods are well-known by those skilled in the art. Note that the nanocrystals  206  can be made of Si, Ge, or a combination thereof. In order for the nanocrystals  206  to emit light, a top electrode  208  is implemented above the STI  202  while the silicon substrate  204  is used as a bottom electrode. The STI  202  can have a thickness of more than 3000 Å. 
         [0018]    In this design, light emitted from the nanocrystals  206  can be visible above the top electrode  208 . An optional color filter film  210  can also be implemented on a higher level above the top electrode  208  to provide the color desired. The thickness of the dielectric layer can also affect the color generated. Also note that the processing steps and materials used for creating the components of this design such as the STI  202  and the top electrode  208  are all compatible with the current standard CMOS process. This allows further circuit integration for this design such as implementation of VLSI memory. 
         [0019]      FIG. 2B  illustrates a semiconductor cross-section  212  of a light emitting device with nanocrystals implanted into a dielectric layer comprising porous or low density particles in accordance to another embodiment of the present invention. In this embodiment, the dielectric layer comprises a porous or low density oxide that is formed above the silicon substrate. A dielectric layer  214  has the same porous or low density oxide used in  FIG. 2A  which is formed above a silicon substrate  216 . The thickness of which can be larger than 3000 Å. A plurality of nanocrystals  218  are implanted into the dielectric layer  214  above the surface of the silicon substrate  216  as a light emitting medium. These nanocrystals  218  can be made of materials such as silicon (Si), germanium (Ge), or a combination thereof. 
         [0020]    Like in  FIG. 2A , the porous or low density oxide used for the dielectric layer  214  is a low-K material, which can increase the formation efficiency of the nanocrystals  218 . In order for the nanocrystals  218  to emit light, a top electrode  220  is implemented above the dielectric layer  214  while the silicon substrate  216  is used as a bottom electrode. 
         [0021]    In this design, light emitted from the nanocrystals  218  can be visible above the top electrode  220 . An optional color filter film  222  can also be implemented on a higher level above the top electrode  220  to provide the color desired. The thickness of the dielectric layer  214  can also affect the color generated. Also note that the processing steps and materials used for creating the components of this design such as the dielectric layer  214  and the top electrode  220  are all compatible with the current standard CMOS process. This allows further circuit integration for this design such as implementation of VLSI memory. 
         [0022]      FIG. 2C  illustrates a semiconductor cross-section  224  of a light emitting device with nanocrystals implanted into a dielectric layer comprising porous or low density oxide in accordance to another embodiment of the present invention. In this embodiment, the dielectric layer comprises a porous or low density oxide above a metal layer that acts as a bottom electrode. 
         [0023]    The cross-section  224  is similar to the cross-section  212  of  FIG. 2B . A dielectric layer  226  is filled with the same porous or low density oxide used in the  FIG. 2A  and  FIG. 2B . However, in this example, the dielectric layer  226  is formed on a metal layer  228  instead of the silicon substrate. The metal layer  228  is also designed to be the bottom electrode. A plurality of nanocrystals  230  are also implanted into the dielectric layer  226  as a light emitting medium. These nanocrystals  230  can be made of materials such as silicon (Si), germanium (Ge), or a combination thereof. 
         [0024]    The porous or low density oxide used for the dielectric layer  226  is a low-K material, which can increase the formation efficiency of the nanocrystals  230 . In order for the nanocrystals  230  to emit light, a top electrode  232  is also implemented on the dielectric layer  226  while the metal layer  228  is used as the bottom electrode. 
         [0025]    In this design, light emitted from the nanocrystals  230  can be visible above the top electrode  232 . An optional color filter film  234  can also be implemented on a higher level above the top electrode  232  to provide the color desired. The thickness of the dielectric layer  226  can also affect the color generated. Also note that the processing steps and materials used for creating the components of this design such as the dielectric layer  226 , the metal layer  228 , and the top electrode  232  are all compatible with the current standard CMOS process. This allows further circuit integration for this design such as implementation of VLSI memory. 
         [0026]      FIG. 3  illustrates a three-pixel circuit  300  in accordance to various embodiments of the present invention. The circuit  300 , which is fabricated with standard CMOS processes, can be integrated with the cross-sectional designs shown in  FIGS. 2A ,  2 B, and  2 C, since they are designed to be compatible with current standard CMOS processes. 
         [0027]    Each pixel comprises three NMOS transistors that are lined up in the same row. Each of the three NMOS transistors is designed to control a certain color of the pixel: red, green, or blue. For example, a pixel comprised of three NMOS transistors  302 ,  304 , and  306  is used to display an RGB color, with the transistor controlling red output, the transistor  304  controlling green output, and the transistor  306  controlling blue output. The color output corresponding to a transistor can be determined by a color filter that is placed above the light emitting device corresponding to that transistor. Since there are three columns and three rows of transistors in the circuit diagram  300 , a total of three pixels are shown. 
         [0028]    The gates of all NMOS transistors are tied to a corresponding variable voltage generator circuit, which is not shown in this figure, through a signal line. By adjusting the voltage applied to the gate of the NMOS transistors, the intensity of the light emitted for the certain color can be controlled. For example, the gate of the NMOS transistor  302  is coupled to a variable voltage generator circuit that controls the intensity of the color red through a signal line  308 . The gate of the NMOS transistor  304  is coupled to a variable voltage generator circuit that controls the intensity of the color green through a signal line  310 , and the gate of the NMOS transistor  306  is coupled to a variable voltage generator circuit that controls the intensity of the color blue through another signal line  312 . With this pixel concept, different color light can be generated and adjusted with three optical devices. 
         [0029]    By using plasma doping methods or other implantation methods to implant nanocrystals made of silicon (Si), germanium (Ge), or a combination thereof into a more porous or low density dielectric layer with a lower dielectric constant (such as the SACVD oxide or porous or low density low-K materials), the formation efficiency of the nanocrystals can be increased, thereby improving the hole mobility and gate dielectric layer interface of the light emitting device. In addition, the control electrode on top of the porous or low density dielectric layer such as layers  208 ,  220 , and  232  can be formed by non-poly semiconductor materials such as Indium Tin oxide as long as such materials can handle the voltage applied thereon. The proposed method also allows the light emitting device to be created within the same substrate with the VLSI circuit, because all process steps and materials are compatible with the current CMOS fabrication process. 
         [0030]    The above illustration provides many different embodiments or embodiments for implementing different features of the invention. Specific embodiments of components and processes are described to help clarify the invention. These are, of course, merely embodiments and are not intended to limit the invention from that described in the claims. 
         [0031]    Although the invention is illustrated and described herein as embodied in one or more specific examples, it is nevertheless not intended to be limited to the details shown, since various modifications and structural changes may be made therein without departing from the spirit of the invention and within the scope and range of equivalents of the claims. Accordingly, it is appropriate that the appended claims be construed broadly and in a manner consistent with the scope of the invention, as set forth in the following claims.