Abstract:
The present invention relates to liquid, lotion-like aqueous oil-in-water dispersion compositons including emulsions containing large amounts of oil or oil/wax mixtures, a volatile organic foam-producing liquid, alone or in combination with foam suppressing agents, if necessary, to and surface active agent or agents which increase the solubility of the foam-producing liquid in the oil or oil/wax mixture. The present compositions are dispersions including mixtures which do not foam or self-dispense from a non-pressurized container at temperatures from RT to 120° F., then can be poured onto a wet surface at room temperatures and spread to form a thin cleansing coating which will foam under ambient conditions to leave a residue of the oil or oil/wax mixture for cosmetic, medicinal, aesthetic, protection or other purposes.

Description:
This is a continuation-in-part of our earlier co-pending U.S. application, Ser. No. 270,263, filed Nov. 14, 1988 now U.S. Pat. No. 4,931,204. 
    
    
     BACKGROUND OF THE INVENTION 
     Liquid compositions containing oils and/or soluble waxes are well known for a variety of uses, such as cosmetic lotions, medicinal lotions, furniture polishes, cleansers for tile, glass, metal, etc. Some such compositions contain soaps and/or detergents to enable them to entrap air and produce a foam or lather during use. However if high levels of oil or oil/wax mixture are added to such aqueous compositions, the foam- or lather-producing properties of the compositions are substantially reduced. Therefore aqueous liquid compositions, capable of being poured from a non-pressurized container to form a foam-producing coating, have not been available with oil or oil/wax contents greater than about 4% or 5% by weight. Such low contents are not satisfactory where the purpose of the product is to apply coatings which are high in oil or oil/wax content. 
     Aerosol compositions containing oil and/or oil/wax ingredients and water are also well known but such compositions must be dispensed as a foam from a pressurized container and cannot be contained as a self-foaming lotion-like liquid in a non-pressurized container. Reference is made to U.S. Pat. Nos. 2,655,480 and 3,705,855 for their disclosure of such aerosol compositions. 
     It is also known to provide aerosol soap and detergent compositions which dispense as a single phase gel capable of being spread over the skin as a self-foaming coating, and reference is made to U.S. Pat. Nos. 3,541,581, 4,505,489 and 4,772,427 for their disclosure of such compositions. 
     Finally, it is known from U.S. Pat. No. 4,726,944 to provide self-foaming or post foaming aqueous liquid detergent compositions which are capable of being poured from a non-pressurized container and rubbed into the hair as a post-foaming shampoo. Such compositions contain mixtures of anionic, amphoteric and non-ionic surfactants, water-soluble gum and a volatile hydrocarbon, and foaming occurs by evaporation of the latter as the composition is applied to the hair. U.S. Pat. No. 4,744,979 relates to similar post-foaming shaving gel compositions containing an aqueous soap solution and a mixture of surface active agents comprising amine oxides and alkanolamides. 
     While self-foaming or post-foaming compositions of the aforementioned types intended for the cleansing of wet or dry surfaces that contain no oil or small amounts thereof are capable of being poured as clear liquid solutions from a non-pressurized container, they function well for their intended purposes only at temperatures close to room temperature, 70°-80° F. It has not been possible heretofore to produce lotion-like post-foaming compositions of these types which are detergent-based and are used for cleansing which contain large amounts of oil or oil/wax mixture for purposes of applying oil or oil/wax coatings to the skin or other wet or dry surfaces for cosmetic, medicinal, aesthetic, protective, household, automotive or other purposes. In addition, such lotion-like post-foaming compositions show a markedly increased solubility of the volatile hydrocarbon component. This property allows the non-pressurized containers to be opened at much higher temperatures, i.e., 110°-120° F. 
     SUMMARY OF THE INVENTION 
     The present invention relates to the discovery of formulations for aqueous, lotion-like compositions which contain large amounts of dispersed oil or oil/wax mixture, greater than about 5% by weight, a volatile organic foam-producing liquid and a surfactant or detergent which increases the solubility of the foam-producing liquid in the oil or oil/wax mixture, optional additional foam suppressing agents depending on the surfactant or surfactants used, the surfactant or detergent comprising the discontinuous phase of the composition, the continuous phase comprising water. This allows the presence of large amounts of the oil or oil/wax mixture without any interference with the foam-forming ability of the foam-producing liquid, whereby the composition can be poured onto a preferably wet surface and spread as a creamy lotion coating which forms a uniform fine foam within a few seconds under ambient exposure, due to the evaporation of the volatile organic foam-producing liquid, to leave an oil or oil/wax foam residue which can be rubbed over the skin or other surface for cosmetic, medicinal, aesthetic, protective, cleansing or other purposes. The presence of the oil or oil/wax on the skin during the foaming action permits the oil or oil/wax mixture, and any medicaments, emollients or other additives dissolved therein or present in the water phase to penetrate the skin and displace moisture, moisture-soluble dirt skin oils or infected matter which may be withdrawn from the skin during the foaming process, for increased effectiveness in softening and treating the skin. 
     The preferred compositions of the present invention are aqueous emulsions including pseudo emulsions and other aqueous dispersions which can be agitated within the container, prior to use, to form lotion-like liquids containing oil or oil/wax mixture dispersed within the continuous water phase. 
    
    
     DETAILED DESCRIPTION 
     The present compositions contain at least about 5% by weight of one or more oils, alone or in combination with one or more waxes soluble in or compatible with said oil(s), at least about 5% by weight of at least one suitable surface active agent or detergent, at least about 5% by weight of at least one volatile organic foam-producing liquid, optionally one or more foam-suppressing compounds in the amount of 2-15% by weight, and the remainder, generally less than about 60%, water. 
     The ingredient of the present compositions that enables the presence of large amounts of oil or oil/wax mixtures, is the surface active agent or detergent. This material preferably is present in an amount within the range of from about 5% to about 20% by weight, and preferably from 10% to about 15% by weight, to enable the incorporation of from about 5% to about 60% by weight of the oil or oil/wax mixture, preferably from 20% to about 35% by weight of said oil or oil/wax mixture. 
     The most critical ingredients of the present compositions from the standpoint of increasing the solubility of the volatile hydrocarbon are both the oil and surface active agent. Their combination enables the incorporation of about 15% volatile hydrocarbons, increasing their solubility to the point that the compositions of the invention can be opened to the atmosphere at temperatures much higher than room temperature. 
     The addition of foam-suppressing compounds also increases the solubility of the volatile hydrocarbon component. Some surfactants by their nature do not need the addition of foam-suppressing agents, while other surfactants are not suitable for commercial utilization without them. 
     The most preferred mild surfactants that do not need foam suppressing agents are anionic materials such as sodium methyl cocoyl taurate (sodium salts of N-methyl taurine-coconut oil amides, referred to herein as SMCT); disodium cocamido monoisopropanol amide sulfosuccinate (disodium salts of sulfo-2-cocamide-1-methyl ethyl esters of butanedioic acid, referred to herein as DCMS); sodium lauryl sulfoacetate (sodium salt of sulfo-1-dodecyl ester of acetic acid, referred to herein as SLSA); dioctyl sodium sulfosuccinate (sodium salt of the diester of 2-ethylhexyl alcohol and sulfosuccinic acid, referred to herein as DSS), and amphoteric materials such as cocamidopropyl hydroxy sultaine, referred to herein as CHS, and combinations of such detergents with each other or with small amounts of other foam-boosting surfactants. 
     The inclusion of foam-suppressing compounds, preferably in amounts between about 3% and 7% by weight where necessary, in combination with highly foaming surfactants allows the use of a greater variety of surfactants which, per se, are not useful for the preparation of suitable commercial products. Combinations of this type can be obtained by adding alcohols, alkoxy alcohols, etc. to surfactants like sodium lauryl sulfate, referred to herein as SLS, ammonium lauryl ether sulfate, referred to herein as ALS, and many other surfactants generally of the anionic type. A similar foam-controlling effect can be obtained by blending high foaming surfactants, generally of the anionic type, with low foaming surfactants. The preferred low foaming surfactants used for this foam controlling effect are generally of the non-ionic and the amphoteric type. Typical of these are nonoxinol-9 (nonionic) and cocampho-carboxyl glycinate (amphoteric), referred to herein as CCG. 
     Suitable oils for use in the compositions of the present invention include all of the conventional water-insoluble liquid or semi-solid mineral (including mixtures of petroleum derived hydrocarbons containing 10 or more carbon atoms), vegetable, synthetic and animal oils, including fatty acid esters, lanolin, etc. The particular oils selected for a particular composition will depend upon its desired function and/or its ability to dissolve additives such as fragrances, waxes, medicaments, etc. 
     Suitable waxes include semi-solid and solid vegetable, mineral, animal and synthetic waxes, present in amounts which are soluble in the oils present to form liquid oil/wax mixtures. 
     The preferred volatile organic foam-producing liquids are those having a vapor pressure from about 4 to 14 p.s.i.g. at temperatures between about 90°-100° F., most preferably hydrocarbons having 5 or 6 carbon atoms such as isopentane, pentane and hexane. The volatile organic liquid is present in an amount between about 5% and 15% by weight, preferably between 7% and 12% by weight. 
     The preferred foam suppressing agents are alcohols, alkoxy alcohols, low foaming surfactants and any other suitable compounds that help prevent the compositions of the invention from self-dispensing at temperatures well in excess of room temperature. 
     The final essential ingredient of the present compositions is water, which is present as an oil-in-water emulsion or dispersion to form the continuous phase of the self-foaming composition. Generally the water is present in an amount between about 25% and 60% by weight of the composition, most preferably between about 35% and 45% by weight. 
     Other ingredients generally are present in minor amounts, less than 10% by weight and usually less than about 2% by weight. Such additives should be soluble in or miscible with either the oils or oil/wax mixtures or in the water and include perfumes or fragrances, emollients, humectants, medicaments, colorants, etc. 
     The following examples are illustrative of several compositions within the scope of the present invention and should not be considered limitative. The compositions thereof are produced by adding the oils or oil/wax mixtures to a suitable container, adding the surface active agents or detergents thereto and homogenizing at a suitable elevated temperature until the detergents are thoroughly dispersed in the oil or oil/wax phase, water being added while homogenizing. Finally the mixture is cooled to room temperature or lower and the volatile organic foam-producing liquid, cooled below its boiling point, is added while the composition is stirred with a mixer. Generally any additives are initially incorporated with the oils or oil/wax mixtures in the first step. 
     EXAMPLE 1 
     
         ______________________________________  Ingredients          Wt %______________________________________  Mineral Oil          35.0  DCMS    15.0  Water   40.0  Pentane 10.0______________________________________ 
    
     EXAMPLE 2 
     
         ______________________________________Ingredients       Wt %______________________________________Mineral Oil       35.0DCMS              13.0Sodium Lauryl Sulfate              2.0Fragrance          0.5Water             39.5Isopentane        10.0______________________________________ 
    
     EXAMPLE 3 
     
         ______________________________________  Ingredients          Wt %______________________________________  Mineral Oil          35.0  SMCT    15.0  Water   40.0  Pentane 10.0______________________________________ 
    
     EXAMPLE 4 
     
         ______________________________________  Ingredients          Wt %______________________________________  Mineral Oil          35.0  DCMS    20.0  Water   35.0  Pentane 10.0______________________________________ 
    
     EXAMPLE 5 
     
         ______________________________________  Ingredients          Wt %______________________________________  Mineral Oil          35.0  DCMS     5.0  Water   50.0  Pentane 10.0______________________________________ 
    
     EXAMPLE 6 
     
         ______________________________________Ingredients       Wt %______________________________________Petroleum Jelly   15.0Mineral Oil       10.0Isopropyl Palmitate             10.0DCMS              12.0SLS                3.0Water             39.5Fragrance          0.5Isopentane        10.0______________________________________ 
    
     EXAMPLE 7 
     
         ______________________________________  Ingredients          Wt %______________________________________  Mineral Oil          35.0  SLSA     5.0  Water   50.0  Isopentane          10.0______________________________________ 
    
     EXAMPLE 8 (SHAVING PREPARATION) 
     
         ______________________________________Ingredients         Wt %______________________________________Mineral Oil         15Isopropyl Palmitate  8Glycerine           10DCMS                13SLS                  2Palmitic Acid        2Water               40Isopentane          10NaOH to adjust to pH 8.5______________________________________ 
    
     EXAMPLE 9 (ANTIDUNDRUFF CLEANSER) 
     
         ______________________________________Ingredient            Wt %______________________________________Mineral Oil           35.0DCMS                  15.0Omadine MDS (MgSO.sub.4 adduct)                  1.0Water                 39.0Isopentane            10.0______________________________________ 
    
     EXAMPLE 10 (PSORIATIC SKIN CLEANSER) 
     
         ______________________________________Ingredient         Wt %______________________________________Petroleum Jelly    10.0Mineral Oil        20.0DCMS               15.0Coal Tar Aqueous Soln.               5.0Water              40.0Isopentane         10.0______________________________________ 
    
     EXAMPLE 11 (AUTO CLEANER/POLISH) 
     
         ______________________________________Ingredient      Wt %______________________________________Carnauba Wax    17.5Mineral Oil     17.5DCMS             9.0SLS              1.0Water           45.0Isopentane      10.0______________________________________ 
    
     EXAMPLE 12 (FABRIC CLEANER) 
     
         ______________________________________Ingredient        Wt %______________________________________Deodorized Kerosene             35.0DCMS              15.0Water             45.0Pentane            5.0______________________________________ 
    
     EXAMPLE 13 (COSMETIC CLEANSER) 
     
         ______________________________________Ingredient          Wt %______________________________________Lanolin             10.0Acetulan (acetylated lanolin)               25.0DCMS                13.0SLS                  2.0Water               40.0Isopentane          10.0______________________________________ 
    
     EXAMPLE 14 
     
         ______________________________________  Ingredients          Wt %______________________________________  DCMS    15.0  Mineral Oil          60.0  Water   15.0  Isopentane          10.0______________________________________ 
    
     EXAMPLE 15 
     
         ______________________________________  Ingredients          Wt %______________________________________  DCMS     5.0  Mineral Oil          35.0  Water   50.0  Isopentane          10.0______________________________________ 
    
     EXAMPLE 16 
     
         ______________________________________  Ingredients          Wt %______________________________________  SCT     15.0  Mineral Oil          10.0  Water   65.0  Isopentane          10.0______________________________________ 
    
     EXAMPLE 17 
     
         ______________________________________  Ingredients          Wt %______________________________________  DSS     15.0  Mineral Oil          35.0  Water   40.0  Isopentane          10.0______________________________________ 
    
     EXAMPLE 18 
     
         ______________________________________Ingredients       Wt %______________________________________DCMS              12.0SLS                3.0Mineral Oil       20.0Petroleum Jelly   12.5Polyethyleneglycol-8              2.5DilaurateWater             39.5Fragrance          0.5Hexane            10.0______________________________________ 
    
     EXAMPLE 19 (DEPILATORY LOTION) 
     
         ______________________________________Ingredients       Wt %______________________________________DCMS              15.0Mineral Oil       35.0Water             34.0Calcium Thioglycolate              6.0Isopentane        10.0______________________________________ 
    
     EXAMPLE 20 
     
         ______________________________________Ingredients     Wt %______________________________________SLS             15.0Mineral Oil     30.0Water           40.0Ethyleneglycol   5.0n-Butyl etherPentane         10.0______________________________________ 
    
     EXAMPLE 21 
     
         ______________________________________  Ingredients          Wt %______________________________________  SLS     15.0  Mineral Oil          35.0  Water   32.5  Ethanol  7.5  Pentane 10.0______________________________________ 
    
     EXAMPLE 22 
     
         ______________________________________Ingredients       Wt %______________________________________SLS                7.5Cocampho-carboxyl  7.5glycinate (CCG)Mineral Oil       35.0Water             40.0Pentane           10.0______________________________________ 
    
     EXAMPLE 23 
     
         ______________________________________  Ingredients          Wt %______________________________________  SLS      7.5  Nonoxinol-9           7.5  Mineral Oil          35.0  Water   40.0  Pentane 10.0______________________________________ 
    
     EXAMPLE 24 
     
         ______________________________________  Ingredients          Wt %______________________________________  CHS     15.0  Mineral Oil          35.0  Water   40.0  Pentane 10.0______________________________________ 
    
     EXAMPLE 25 (SURGICAL SCRUB) 
     
         ______________________________________Ingredients        Wt %______________________________________CHS                15.0Chlorhexidine gluconate               4.0Capramide DEA       2.0Polyquaternium-7    0.2Mineral Oil        18.0Petroleum Jelly    12.0Fragrance           0.3Water              38.5Pentane            10.0______________________________________ 
    
     EXAMPLE 26 (ACNE CLEANSER) 
     
         ______________________________________Ingredients      Wt %______________________________________DCMS             12.0ALS               3.0Polyquaternium-7  0.2Mineral Oil      30.0Benzoyl Peroxide  5.0Glycerine         5.0Water            34.5Fragrance         0.3Pentane          10.0______________________________________ 
    
     The following Examples 27 to 31 illustrate non-functional comparative compositions: 
     EXAMPLE 27 
     
         ______________________________________Ingredients     Wt %______________________________________Sodium Lauryl   15.0Sulfate (SLS)Mineral Oil     35.0Water           40.0Pentane         10.0______________________________________ 
    
     EXAMPLE 28 
     
         ______________________________________Ingredients         Wt %______________________________________Ammonium Lauryl Ether               15.0Sulfate (ALS)Mineral Oil         35.0Water               40.0Pentane             10.0______________________________________ 
    
     EXAMPLE 29 
     
         ______________________________________  Ingredients          Wt %______________________________________  Nonoxinol-9          15.0  Mineral Oil          35.0  Water   40.0  Pentane 10.0______________________________________ 
    
     EXAMPLE + 
     
         ______________________________________Ingredients       Wt %______________________________________Dimethyl-1-Naphthyl             15.0Methyl AmmoniumChlorideMineral Oil       35.0Water             40.0Pentane           10.0______________________________________ 
    
     EXAMPLE 31 
     
         ______________________________________  Ingredients          Wt %______________________________________  CCG     15.0  Mineral Oil          35.0  Water   40.0  Pentane 10.0______________________________________ 
    
     In order to establish the critical nature of the components of the present compositions we have compared examples of the preferred surfactants with other surfactants considered non-functional by themselves for the purpose of this invention. The compositions of Examples 1, 3 and 24 being compared are identical in every respect to the compositions of Examples 27, 28 and 31, respectively, except by substitution of identical amounts of total surfactant. The compositions of Example 1, 3, 7, 17, and 24 were compared with the non-functional compositions of examples 27, 28, 29, 30 and 31. Each of the compositions was placed in an individual 100 ml graduated cylinder, 10 ml of water was added to 10 g of each composition, and the cylinder was closed and shaken vigorously ten times. The initial and final volumes of the foam were recorded as 1 (0 ml increase), 3 (27 ml increase), 7 (0 ml increase), 17 (0 ml increase), 24 (24 ml increase),  27 (55 ml increase), 28 (59 ml increase), 29 (8 ml increase), 30 (5 ml increase) and 31 (28 ml increase). The preferred compositions, Examples 1, 7 and 17, showed no tendency to foam in the sealed container under agitation, establishing the solubilizing effect on the volatile organic liquid and its suppression against escape and foaming within the container, whereby the compositions have excellent post-foaming properties after being poured onto the wet skin and scrubbed for cleansing action. The compositions of Example 3 an 24 foamed somewhat but still solublized the volatile organic liquid within the oil to a sufficient extent that the composition has excellent post-foaming properties similar to those of Examples 1, 7 and 17. 
     The compositions of examples 1, 3, 7, 17 and 24 when opened at temperatures much higher than room temperature, e.g. from 110° to 120° F., will not self-dispense. The compositions of Examples 27 and 28 foamed excessively and self-dispensed from the container even at room temperature, although they do post-foam because the volatile liquid hydrocarbon is solublized somewhat in the oil phase but only to an unsatisfactory extent. 
     The compositions of Examples 29, 30 and 31 while they showed little or no tendency to foam when agitated in the sealed container, they were non-functional when poured onto the skin and spread in the same manner as the other compositions since they do not self-foam or post-foam to any useful extent. 
     The inclusion of foam suppressing components in combination with highly foaming surfactants allows the preparation of suitable commercial products. Preparations of this type can be obtained by adding alcohols, alkoxy alcohols, etc. to the highly foaming surfactant of Examples 27. For example, the compositions of Examples 20 and 21 show limited foam increase in the sealed container under agitation, i.e., composition 20 (23 ml increase) and composition 21 (15 ml increase). This establishes the solubilizing effect on the volatile organic liquid and its suppression against escape and foaming within the container. 
     A similar foam-controlling effect can be obtained by blending high foaming surfactants generally of the anionic type with low foaming surfactants generally the non-ionic and amphoteric types. Thus, in Examples 22 and 23 the surfactants of the unsatisfactory compositions of Examples 29 and 31 are modified to prepare suitable commercial products by adding the low foaming surfactants of the compositions to provide additional foam-controlling effect. The foaming values of composition 22 (23 ml increase) and compositions 23 (25 ml increase) illustrate the effect of the low foaming surfactants on compositions containing SLS which, by its chemical nature, will foam uncontrollably when used alone and will produce compositions which self-dispense at room temperature. The compositions of Examples 20, 21, 22 and 23 contain foam suppressants and demonstrate controlled foaming and will not self-dispense at temperatures from 110°-120° F. All these compositions are functional when poured onto the skin and spread in the same manner as the compositions of examples 1, 3, 7, 17 and 24 since they do foam and post-foam to a useful extent. 
     Therefore it will be apparent to those skilled in the art that the various classes of oils or oil/wax mixtures, specific ones of which are illustrated by the various examples set forth herein, can be incorporated in large amounts in self-foaming compositions capable of being contained within non-aerosol, non-pressurized containers, preferably small-mouth rigid containers, which compositions can be poured onto the skin or other surface and rubbed or spread in the same manner as a conventional lotion and will self-generate a copious foam on the wet skin or other wet surfaces in a few seconds time. The foaming operation results from the evaporation of the organic foam-producing liquid to leave an oily foam residue which can be rubbed into the skin or over a wooden, metallic, plastic or other surface for cleaning, medication, polishing, waxing or other purposes. 
     It is to be understood that the above described embodiments of the invention are illustrative only and that modifications throughout may occur to those skilled in the art. Accordingly, this invention is not to be regarded as limited to the embodiments disclosed herein but is to be limited as defined by the appended claims.