Abstract:
A method is disclosed for preparing one of more specific dimethylnaphthalene isomers by the isomerization of one or more other specific dimethylnaphthalene isomers in the liquid phase and in the presence of a solid zeolitic isomerization catalyst.

Description:
BACKGROUND OF THE INVENTION 
     1. Related Application 
     This application is a continuation-in-part of patent application Ser. No. 316,305, filed on Feb. 27, 1989, now abandoned, which in turn is a continuation-in-part of patent application Ser. No. 211,231, filed on June 24, 1988, now abandoned. 
    
    
     2. Field of the Invention 
     This invention relates generally to a method for preparing one or more specific dimethylnaphthalene isomers by isomerizing one or more other specific dimethylnaphthalene isomers. 
     3. Description of the Prior Art 
     Naphthalene dicarboxylic acids are monomers that are known to be useful for the preparation of a variety of polymers. For example, poly(ethylene 2,6-naphthalate) prepared from 2,6-naphthalene dicarboxylic acid and ethylene glycol has better heat resistance and mechanical properties than polyethylene terephthalate and is useful in the manufacture of films and fibers. 
     Dimethylnaphthalenes are desirable feedstocks for oxidation to the corresponding naphthalene dicarboxylic acids. A known conventional process for producing a naphthalene dicarboxylic acid comprises the oxidation of a dimethylnaphthalene with oxygen in the liquid phase in an acetic acid solvent at an elevated temperature and pressure and in the presence of a catalyst comprising cobalt, manganese and bromine components. 
     Typically dimethylnaphthalenes are found in refinery or coal-derived streams as mixtures of all of the ten possible dimethylnaphthalene isomers. However, separation of these isomers is very difficult and expensive. Consequently, methods for producing specific dimethylnaphthalenes or mixtures of two or three specific dimethylnaphthalenes in high purity and quality are highly desirable. One type of such method is a multistep synthesis involving (1) the formation of an alkenylbenzene by the reaction of o-, m- or p-xylene or ethylbenzene with butadiene, (2) the cyclization of the resulting alkenylbenzene to form one or more dimethyltetralins belonging to one or two of three groups of three isomeric dimethyltetralins--that is, either group A containing the 1,5-, 1,6-, 2,5- and 2,6-dimethyltetralins, group B containing the 1,7-, 1,8-, 2,7- and 2,8-dimethyltetralins, or group C containing the 1,3-, 1,4-, 2,3-, 5,7-, 5,8- and 6,7-dimethyltetralins -- (3) the dehydrogenation of the dimethyltetralin(s) to form the corresponding dimethylnaphthalene(s), and (4) the isomerization of the resulting dimethylnaphthalene(s) to the desired specific dimethylnaphthalene. 
     For example, Thompson, U.S Pat. Nos. 3,775,496; 3,775,497; 3,775,498; 3,775,500 disclose processes for the cyclization of specific alkenylbenzenes to one or more specific dimethyltetralins at 200°-450° C. in the presence of any suitable solid acidic cyclization catalyst such as acidic crystalline zeolites as well as silica-alumina, silica-magnesia and silica-alumina-zirconia and phosphoric acid, followed by the dehydrogenation of the resulting dimethyltetralin(s) in the vapor state to the corresponding dimethylnaphthalene(s) in a hydrogen atmosphere at 300°-500° C. and in the presence of a solid dehydrogenation catalyst such as noble metals on carriers and chromia-alumina, and thereafter isomerization of each of the aforesaid dimethylnaphthalene(s) to the desired isomer within the triad of dimethylnaphthalenes to which the isomer being isomerized belongs, at 275°-500° C. in the presence of a solid acidic isomerization catalyst of the same type as described in respect of the cyclization disclosed therein. In the alternative, both the cyclization and isomerization reactions can be performed in the liquid phase, in which case the cyclization is performed at 200°-275° C. with a solid phosphoric acid catalyst, at 70°-140° C. with an acidic ion exchange resin, an acidic crystalline zeolite, hydrofluoric or sulfuric acid as the catalyst or a siliceous cracking catalyst. 
     More specifically, Thompson, U.S. Pat. No. 3,775,496 discloses the cyclization of 5-(m-tolyl) -pent-2-ene to 1,6- and 1,8-dimethyltetralins, which are then dehydrogenated to 1,6- and 1,8-dimethylnaphthalenes, which in turn are isomerized to 2,6- and 2,7-dimethylnaphthalenes, respectively. Thompson, U.S. Pat. No. 3,775,497 discloses the cyclization of 5-phenyl-hex-2-ene to 1,4-dimethyltetralin which is then dehydrogenated to 1,4-dimethylnaphthalene, which is in turn isomerized to 2,3-dimethylnaphthalene. Thompson, U.S. Pat. No. 3,775,498 discloses the cyclization of 5-(o-tolyl)-pent-2-ene to 1,5-dimethyltetralin, which is then dehydrogenated to 1,5-dimethylnaphthalene, which is in turn isomerized to 2,6-dimethylnaphthalene. Thompson, U.S. Pat. No. 3,775,500 discloses the cyclization of 5-(p-tolyl)-pent-2-ene to 1,7-dimethyltetralin, which is then dehydrogenated to 1,7-dimethylnaphthalene, which in turn is isomerized to 2,7-dimethylnaphthalene. 
     Shimada et al., U.S. Pat. No. 3,780,119 disclose a method for the isomerization of dimethylnaphthalene by the use at a temperature above 260° C of a mordenite catalyst in which a metal form of mordenite is in excess of 20 weight percent of the mordenite, with the metal being selected from the group consisting of lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc and aluminum. 
     Suld et al., U.S. Pat. No. 3,803,253 disclose a method for the hydroisomerization of a dimethylnaphthalene by the use of a combination of a hydrogenation catalyst and a calcium-containing zeolite catalyst, such as a calcium-exchanged synthetic faujasite, for example, a Y-type molecular sieve. 
     Shima et al., U.S. Pat. No. 3,806,552 disclose a method for the isomerization of dimethylnaphthalenes in the gas phase by the use of a mixed catalyst consisting of (a) 65-95 weight percent of a hydrogen form of mordenite in which above 80 weight percent of the metal cations are replaced with hydrogen ions, and (b) 5-35 weight percent of catalyst selected from the group consisting of bentonite and fuller&#39;s earth. 
     Hedge, U.S. Pat. No. 3,855,328 discloses a method for the isomerization of dimethylnaphthalenes by the use of a Type Y alumino silicate zeolite at 120°-300° C. in the liquid phase. The catalysts have aluminum-to-silicon atomic ratios of 0.1-1.0. 
     Ogasawara et al., U.S. Pat. No. 3,888,938 disclose a method for the isomerization of dimethylnaphthalenes in the liquid phase by the use of a mixed catalyst consisting of (a) 70-95 weight percent of a hydrogen form of mordenite in which above 80 weight percent of the metal cations are replaced with hydrogen ions, and (b) 5-30 weight percent of a promoter selected from the group consisting of bentonite and fuller&#39;s earth. 
     Hedge et al., U.S. Pat. No. 3,928,482 disclose the isomerization of either dimethyldecalins, dimethyltetralins or dimethylnaphthalenes in the presence of an alumino silicate zeolite containing polyvalent metal cations in exchange positions, such as a rare earth-exchanged Type Y zeolite. 
     Yokayama et al., U.S. Pat. No. 3,957,896 disclose the selective isomerization of dimethylnaphthalenes in the presence of any kind of natural or synthetic, solid acid catalyst, such as Y-type zeolite as well as silica-alumina, silica-magnesia, silica-zirconia, silica-alumina-zirconia, fuller&#39;s earth, natural or synthetic mordenite, X-type zeolite, A-type zeolite and L-type zeolite. These catalysts may be substituted partly or wholly by hydrogen or metal. Furthermore, these catalysts can be unsupported or supported on carriers. 
     Onodera et al., U.S. Pat. No. 4,524,055 discloses a crystalline aluminosilicate zeolite that is useful in the isomerization of dimethylnaphthalenes and has a silica-to-alumina mole ratio of 10 to 100, specific x-ray lattice distances, and a specific cylohexane-to-n-hexane adsorption ratio of at least 0.7. 
     Maki et al., U.S. Pat. No. 4,556,751 disclose the isomerization of dimethylnaphthalenes in the presence of a crystalline aluminosilicate having a pentasil structure and a silica-to-alumina molar structure of 12 or higher. In addition, the aluminosilicate may contain some other metals as non-exchangeable metals. 
     A problem in all such prior art methods is the presence of other dimethylnaphthalene isomers and unconverted dimethyltetralin and alkenylbenzene as impurities and byproducts in the finally obtained, desired specific dimethylnaphthalene isomer. The presence of such impurities and by-products markedly reduces the utility and commercial value of the desired dimethylnaphthalene isomer, especially as a precursor for the formation of a naphthalene dicarboxylic acid for use as a monomer in the manufacture of a polymer. In addition, catalysts tend to deactivate relatively rapidly at the high temperatures employed in vapor phase processes. Therefore, it is highly desirable to employ liquid phase processes and to improve the completeness of each step in the aforesaid multistep synthesis and the selectivity of each step therein for the production of the desired product therefrom. 
     In this regard, it is known that in the presence of an acid catalyst, the dimethylnaphthalene isomers are isomerizable within each triad of dimethylnaphthalene isomers--that is, within the 1,5-, 1,6- and 2,6-dimethylnaphthalenes of triad A, within the 1,7-, 1,8-, and 2,7-dimethylnaphthalenes of triad B, and within the 1,3-, 1,4- and 2,3-dimethylnaphthalenes of triad C. It is also known that the interconversion of a dimethylnaphthalene isomer within one of the aforesaid triads to a dimethylnaphthalene isomer within another of the aforesaid triads occurs to a relatively lesser extent. However, it is highly desired to improve the selectivity and completeness of the isomerization step in the aforesaid multistep synthesis for the formation of the specific dimethylnaphthalene isomer desired. 
     OBJECTS OF THE INVENTION 
     It is therefore a general object of the present invention to provide an improved method for manufacturing with an improved yield and selectivity a specific dimethylnaphthalene isomer or set of dimethylnaphthalene isomers which meets the aforementioned requirements for selectivity and completeness and catalyst activity. 
     It is a related object of the present invention to provide an improved method for manufacturing with an improved yield and selectivity another specific dimethylnaphthalene isomer or another set of dimethylnaphthalene isomers by the isomerization of a specific dimethylnaphthalene isomer or set of dimethylnaphthalene isomers. 
     Other objects and advantages of the method of the present invention will become apparent upon reading the following detailed description and appended claims. 
     SUMMARY OF THE INVENTION 
     The objects are achieved by an improved method for preparing a dimethylnaphthalene by isomerizing at least 20 weight percent of the total of at least one dimethylnaphthalene isomer to form at least one desired other dimethylnaphthalene isomer in the same triad of dimethylnaphthalene isomers to which the isomer being isomerized belongs comprising: contacting each aforesaid dimethylnaphthalene isomer to be isomerized in liquid form with a solid isomerization catalyst comprising either beta zeolite or an acidic ultrastable Y-type crystalline zeolite having a silica-to-alumina molar ratio of from about 4:1 to about 10:1, and having pore windows provided by twelve-membered rings containing oxygen and a unit cell size of from about 24.2 to about 24.7, and at a temperature in the range of from about at least 200° C. to about 400° C. at a pressure that is sufficiently high to maintain the isomerization feedstock substantially in the liquid phase. 
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     Any dimethylnaphthalene or mixture of dimethylnaphthalenes is suitable for use as a feedstock in the method of this invention. If a particular dimethylnaphthalene or set of dimethylnaphthalenes is desired as the final product, then, as indicated hereinabove, it is preferred to use a dimethylnaphthalene or set of dimethylnaphthalenes that belong to the same triad or triads of dimethylnaphthalene isomers to which the desired dimethylnaphthalene(s) belong. 
     In addition or in the alternative, the specific dimethylnaphthalene or set of specific dimethylnaphthalenes employed in the method of this invention can depend on the manner in which each dimethylnaphthalene employed is obtained. For example, Sikkenga and Lamb, copending U.S. patent application Ser. No. 211,000, filed on June 24, 1988 discloses the formation of one or more dimethyltetralins by the cyclization of 5-(o-, m- or p-tolyl)-pent-1-or -2-ene or 5-phenyl-hex-1- or -2-ene and thereafter the dehydrogenation of the resulting dimethyltetralin(s) to form one or more corresponding dimethylnaphthalenes. 
     When 5-(o-tolyl)-pent-1- or -2-ene is the feedstock to the cyclization step 1,5-, 1,6-, 2,5-, or 2,6-dimethyltetralin or a mixture thereof comprises at least 80, preferably at least 85 weight percent of the dimethyltetralins produced therefrom, which resulting dimethytetralins are in turn the feedstock and are converted in the dehydrogenation step to the corresponding 1,5-, 1,6- and 2,6-dimethylnaphthalenes, which are then the feedstock in the isomerization step of the present invention and are converted therein to 2,6-dimethylnaphthalene. 
     When 5-(m-tolyl)-pent-1- or -2-ene is the feedstock to the cyclization step, 1,5- 1,6- 1,7-, 1,8- 2,5- 2,6-, 2,7- or 2,8-dimethyltetralin or a mixture thereof comprises at least 80, preferably at least 85 weight percent of the dimethyltetralins produced therefrom, which dimethyltetralins are in turn the feedstock and are converted in the dehydrogenation step to the corresponding 1,5-, 1,6-, 1,7-, 1,8- 2,6- and 2,7-dimethylnaphthalenes, which are then the feedstock in the isomerization step of the present invention and are converted to 2,6- and 2,7-dimethylnaphthalenes. 
     When 5-(p-tolyl)-pent-1- or -2-ene is the feedstock to the cyclization step, 1,7-, 1,8-, 2,7- or 2,8-dimethyltetralin or a mixture thereof comprises at least 80, preferably at least 85 weight percent of the dimethyltetralins produced therefrom, which dimethyltetralins are in turn the feedstock and are converted in the dehydrogenation step to the corresponding 1,7-, 1,8- and 2,7-dimethylnaphthalenes which are then the feedstock and are converted in the isomerization step of the present invention to 2,7-dimethylnaphthalene. 
     When 5-phenyl-1- or -2-hexene is the feedstock to the cyclization step, 1,3-, 1,4-, 2,3-, 5,7, 5,8-, or 6,7-dimethyltetralin or a mixture thereof comprises at least 80, preferably at least 85 weight percent of the dimethyltetralins produced therefrom, which dimethyltetralins are in turn the feedstock and are converted in the dehydrogentation step to the corresponding, 1,3-, 1,4- and 2,3-dimethylnaphthalenes, which are then the feedstock in the isomerization step of the present invention and are converted to 2,3-dimethylnaphthalene. 
     In the method of the present invention, the isomerization reaction is performed in the liquid phase at an elevated temperature and at a sufficiently high pressure to ensure that the feedstock is maintained substantially in the liquid phase. The isomerization reaction is performed at a temperature in the range of from about 200° C., preferably from about 240° C., to about 400° C., preferably to about 350° C., and generally at a pressure in the range of from about 0.5, preferably from about 0.8, to about 10, preferably to about 1.3 atmospheres absolute. 
     The isomerization reaction can be performed with or without a solvent for the feedstock. Preferably a solvent is not employed. If employed, a solvent in the isomerization step must be inert under the conditions employed and suitably comprises a paraffin such as a tetradecane, or an aromatic hydrocarbon such as anthracene, or mixtures thereof, which preferably boils above about 270° C. 
     The isomerization step of the method of the present invention can be performed either batchwise or continuously. The reaction apparatus to be used can be of any known type such as a fixed bed, moving bed, fluidized bed, liquid phase suspended bed or a solid-liquid mixture in a stirred tank. Generally, however, the use of a fixed bed is commercially preferred for continuous operation. 
     The improved conversion of the feedstock and selectivity for the production of the desired product or set of products from the isomerization step of the method of this invention are the result of the temperature and pressure conditions employed and the high activity and selectivity of the catalyst employed, which in turn permits the use of less severe conditions--that is, lower temperatures and pressures--such that greater selectivity and reduced catalyst deactivation can be achieved. 
     The catalyst employed in the isomerization step of the method of this invention comprises either beta zeolite or an acidic ultrastable--that is, a thermally stabilized or dealuminated--Y-type crystalline aluminosilicate zeolite having a silica-to-alumina molar ratio of from about 4:1 preferably from about 5:1, to about 10:1, preferably to about 6:1, and having pore windows provided by twelve-membered rings containing oxygen, and a unit cell size of from about 24.2, preferably from about 24.3, to about 24.7, preferably to about 2.6 angstroms. A suitable such zeolite is marketed by Union Carbide under the name LZ-Y72 or LZ-Y20. Water is not detrimental to catalytic activity or selectivity in the isomerization process. 
     The isomerization catalyst preferably comprises beta zeolite. The composition, structure and preparation of beta zeolite are described in Wadlinger et al. U.S. Pat. No. 3,308,069, which in its entirety is specifically incorporated herein by reference. The structure of beta zeolite is also reported in J. Haggin, &#34;Structure of Zeolite Beta Determined,&#34; in Chemical &amp; Engineering News, p. 23 (June 20, 1988). Beta zeolite is also commercially available from P.Q. Corporation. 
     The aforesaid ultrastable Y-type, zeolite which can also be employed in the catalyst for the isomerization step of the method of this invention is in the hydrogen form and contains from about 0.01, preferably from about 1, up to about 5, preferably up to about 3 weight percent of sodium, calculated as elemental sodium and based on the weight of the zeolite. 
     Preferably the isomerization catalyst comprises a hydrogenation component comprising a Group VIII metal, which more preferably is palladium, platinum or nickel. 
     The aforesaid zeolite of the isomerization catalyst can be employed either unsupported or supported on a porous refractory, inorganic oxide that is inert under the conditions employed, such as silica, alumina, silica-alumina, magnesia, bentonite or other such clays. If a support is employed, preferably the support comprises silica, alumina or silica-alumina. When a support is employed, the zeolite comprises from about 10, preferably from about 20, to about 90, preferably to about 80 weight percent based on the weight of the catalyst. 
     If the isomerization is performed on a batch basis, the catalyst is employed at a level .n the range of from about 0.1, preferably from about 1.0, to about 5, preferably to about 3 weight percent of the zeolite component of the catalyst, based on the weight of the dimethylnaphthalene feedstock, and the reaction time is from about 0.5, preferably from about 2, to about 10 preferably to about 6 hours. If the isomerization is performed on a continuous basis, the space velocity is in the range of from about 0.1, preferably from about 0.5 to about 10, preferably to about 5 parts of dimethylnaphthalene feedstock per part of zeolite component of the catalyst by weight per hour. 
    
    
     The present invention will be more clearly understood from the following specific examples. 
     EXAMPLES 1-18 
     In each of Examples 1-18, the particular isomer of dimethylnaphthalene employed as the feed was mixed in liquid form with unsupported catalyst in a stirred reaction vessel with a continuous nitrogen purge to preclude oxygen from the system. The temperature of the reaction vessel was raised to the reaction temperature and samples were withdrawn at various times after commencement of the reaction and analyzed. The conditions employed, the compositions of the feedstock employed and of the resulting products containing up to 13 carbon atoms, the percent conversion of the feedstock, and the percent selectivity of the formation of desired product from the total amount of feedstock converted in each of Examples 1-18 are presented in Table 1. 
     The catalyst employed in Example 1 was a crystalline borosilicate molecular sieve (HAMS-1B from Amoco Chemical). The catalyst employed in Example 2 was Union Carbide&#39;s LZ-Y20 ultrastable Y-type sieve, containing 2 weight percent of copper, calculated as elemental copper. The catalyst employed in Example 3 was Union Carbide&#39;s LZ-Y62, a non-ultrastable, Y-type sieve in the ammonia exchanged form and having a unit cell size of 24.73Å. The catalyst employed in Example 4 and 5 was commercially available Union Carbide&#39;s LZ-Y82, an ultra-stable-molecular sieve having a unit cell size of 24.56Å and a sodium content of less than 0.2 weight percent. In Example 4, the sieve was in the ammonia form and had not been calcined. In Example 5, the sieve had been calcined to form the hydrogen form. The catalyst employed in Example 6 was a commercially available amorphous silica-alumina containing 13 weight percent of alumina. The catalyst employed in Example 7 was commercially available mordenite in the acid form. The catalyst employed in Examples 8, 9, 11-16 was commercially available Union Carbide&#39;s LZ-Y72 in the hydrogen form as received from the manufacturer. The catalyst employed in Example 10 was commercially available Grace USY sieve containing 2.6 weight percent of sodium and has chemical and physical properties that are very similar to those of Union Carbide&#39;s LZ-Y72, and is also suitable for use as a catalyst in either the cyclization or isomerization step in the method of this invention. 1,5-dimethylnaphthalene was the feed in Examples 1-15. The feed was 1,7-dimethylnaphthalene in Example 16 and 1,4-dimethylnaphthalene in Examples 17 and 18. For the purposes of Table 1, the concentration of 2,7-DMN in the product is taken to be approximately equal to the concentration of 1,7-DMN and is subtracted from the sum of 2,6-DMN and 2,7-DMN (which are determined together) for the purpose of determining the concentration of 2,6-DMN alone. The effective maximum concentrations of a particular desired DMN in its triad is its equilibrium concentration in the triad, which generally is 40-45 weight percent. 
     
                                           TABLE 1__________________________________________________________________________             Feed                 Ex. 1  Feed  Ex. 2__________________________________________________________________________ConditionsTemperature (°C.)                 249          243Pressure (psig)       1            1Catalyst              Amsac-3400   LZ-Y20Feed/catalyst wt ratio                 10           10Hours on stream       7.3          13Product Composition (wt %)1,2-DMN           0.0 0.0    0.0   0.11,3-DMN           0.0 0.0    0.0   0.01,4-DMN           0.0 0.0    0.0   0.01,5-DMN           93.4                 69.3   82.6  8.71,6-DMN           0.0 20.1   11.8  37.81,7-DMN           0.0 0.0    1.2   1.52,3-DMN           0.0 0.0    0.0   0.02,6- + 2,7-DMNs   0.0 5.4    1.8   36.3Lights            6.3 2.6    1.7   1.4Heavies           0.0 1.9    0.2   5.8Naphthalene       0.0 0.0    0.0   0.1Methylnaphthalenes             0.0 0.2    0.6   6.5Other             0.2 0.5    0.0   1.9Total             99.9                 100.0  99.9  100.1Total DMNs        93.4                 94.8   97.3  84.42,7-DMN %2,6-DMN % in      0.0 5.7    0.6   42.8the 1,5-, 1,6- and 2,6-DMN triad2,6-DMN selectivity   100          71.7__________________________________________________________________________             Feed                 Ex. 3  Ex. 4 Ex. 5__________________________________________________________________________ConditionsTemperature (°C.)                 248    249   240Pressure (psig)       1      1     1Catalyst              LZ-Y62 LZ-Y82.sup.1                              LZ-Y82.sup.2Feed/catalyst wt ratio                 10.0   9.9   9.8Hours on stream       12     11.8  5.5Product Composition (wt %)1,2-DMN           0.0 0.0    0.0   0.41,3-DMN           0.0 0.0    0.0   0.01,4-DMN           0.0 0.0    0.0   0.01,5-DMN           82.6                 82.3   75.6  4.11,6-DMN           11.8                 12.1   18.3  25.41,7-DMN           1.2 1.3    1.2   3.62,3-DMN           0.0 0.0    0.0   1.22,6- + 2,7-DMNs   1.8 2.1    3.2   30.4Lights            1.7 1.8    1.2   1.3Heavies           0.2 0.1    0.1   16.2Naphthalene       0.0 0.0    0.0   0.7Methylnaphthalenes             0.6 0.3    0.2   12.7Other             0.0 0.0    0.0   3.9Total             99.6                 100.1  99.8  100.1Total DMNs        97.3                 97.8   98.3  65.12,7-DMN %2,6-DMN % in the  0.6 0.9    2.1   47.71,5-, 1,6- and 2,6- DMN triad2,6-DMN selectivity                40.5__________________________________________________________________________ .sup.1 not calcined .sup.2 calcined 
    
     
                         Ex. 6                Ex. 7                     Ex. 8                          Ex. 9                               Ex. 10__________________________________________________________________________ConditionsTemperature (°C.)           233  248  226  227  252Pressure (psig) 1    1    1    1    1Catalyst        SiO.sub.2 /                Morde-                     LZY-72                          LZY-72                               US-Y.sup.5           Al.sub.2 O.sub.3                nite.sup.4Feed/catalyst wt ratio           10.1 9.8  50.4 50.4 50.8Hours on stream 13   11.5 19.5 23.3 11.5Product Composition (wt %)1,2-DMN         0.0  0.0  0.0  0.0  0.01,3-DMN         0.0  0.0  0.0  0.0  0.01,4-DMN         0.0  0.0  0.0  0.0  0.01,5-DMN         21.9 41.2 24.0 21.3 17.51,6-DMN         42.8 29.4 39.9 40.3 41.51,7-DMN         1.2  0.7  1.0  0.9  1.02,3-DMN         0.0  0.0  0.0  0.0  0.02,6- + 2,7-DMNs 29.3 27.6 31.8 34.2 35.9Lights          1.2  1.0  1.9  0.9  1.2Heavies         1.2  0.0  0.9  1.1  1.0Naphthalene     0.0  0.0  0.0  0.0  0.0Methylnaphthalenes           2.0  0.1  1.0  1.1  1.3Other           0.5  0.0  0.4  0.2  0.5Total           100.1                100.0                     100.9                          100.0                               99.9Total DMNs      95.2 98.9 96.7 96.7 95.92,7-DMN %                 1.1       1.12,6-DMN % in the           30.3 27.6 32.5 35.1 37.21,5-, 1,6- and 2,6-DMN triad2,6-DMN selectivity           93.1 &gt;100 99.5 99.9 97.3__________________________________________________________________________ .sup.3 13% Al.sub.2 O.sub.3 .sup.4 in H form .sup.5 ultrastable sieve containing 2.6% Na 
    
     
                         Ex. 11                Ex. 12                     Ex. 13                          Ex. 14                               Ex. 15__________________________________________________________________________ConditionsTemperature (°C.)           251  248  248  249  248Pressure (psig) 1    1    1    1    1Catalyst        LZY-72                LZY-72                     LZY-72                          LZY-72                               LZY-72Feed/catalyst wt ratio           50.6 50.6 50.6 50.6 50.6Hours on stream 3.0  4.8  6.8  8.5  10.5Product Composition (wt %)1,2-DMN         0.0  0.0  0.0  0.0  0.01,3-DMN         0.0  0.0  0.0  0.0  0.01,4-DMN         0.0  0.0  0.0  0.0  0.01,5-DMN         20.9 15.1 12.2 9.6  8.71,6-DMN         41.6 41.6 41.6 40.0 39.71,7-DMN         0.9  1.0  1.0  1.2  1.22,3-DMN         0.0  0.0  0.0  0.0  0.02,6- + 2,7-DMNs 32.9 37.6 40.0 43.0 43.3Lights          1.6  1.6  1.2  1.0  1.1Heavies         0.8  1.1  1.6  2.1  2.2Naphthalene     0.0  0.0  0.0  0.0  0.0Methylnaphthalenes           1.1  1.5  1.7  2.6  2.8Other           0.3  0.5  0.7  0.5  0.9Total           100.1                100.0                     100.0                          100.0                               99.9Total DMNs      96.3 95.2 94.8 93.9 93.02,7-DMN %                           1.62,6-DMN %       33.8 39.2 42.0 45.7 46.5the 1,5-, 1,6- and 2,6-DMN triad2,6-DMN selectivity           98.4 95.6 94.6 92.3 90.5__________________________________________________________________________           Feed Ex. 16                     Feed Ex. 17                               Ex. 18__________________________________________________________________________ConditionsTemperature (°C.)                251       247  252Pressure (psig)      1         1    1Catalyst        LZY-72                LZY-72                     LZY-72                          LZY-72                               LZY-72Feed/catalyst wt ratio                50.0      44.0 44.0Hours on stream      4.0       2.0  6.5Product Composition (wt %)1,2-DMN         0.0  0.0  0.0  0.1  0.41,3-DMN         0.0  0.0  0.6  50.8 51.01,4-DMN         0.0  0.0  90.6 15.1 9.01,5-DMN         0.5  0.2  0.0  0.0  0.01,6-DMN         0.7  1.4  0.0  0.0  0.01,7-DMN         90.4 40.5 0.0  0.0  0.12,3-DMN         0.0  0.0  0.0  22.1 23.32,6-DMN         0.0  1.3  0.0  0.0  0.32,7-DMN         0.3  44.7 0.0  0.0  0.1Lights          6.6  6.3  5.2  4.3  3.6Heavies         0.0  0.7  0.0  1.8  3.8Naphthalene               0.0  2.0  3.3Methylnaphthalenes           0.2  1.7  3.6  3.9  4.8Other           1.3  2.8  0.0  0.0  0.3Total           100.0                99.6 100.0                          100.1                               100.0Total DMNs      92.0 88.4 91.1 88.1 84.2% desired DMN.sup.1 in its           0.3  52.2 0.6  25.1 28.0triadSelectivity          89.0      87.5 74.8__________________________________________________________________________ .sup.1 2,7DMN in Example 16 and 2,3DMN in Examples 17-18. 
    
     EXAMPLE 19 
     7.5 kilograms of distilled water, 7.5 kilograms of an aqueous solution containing 40 weight percent of tetraethylamine hydroxide, 50 grams of sodium hydroxide and 300 grams of sodium aluminate were stirred and dissolved in a 25-gallon stainless steel tank. The resulting solution and 12.2 kilograms of a silica sol containing 40 weight percent of silica were mixed and stirred in a 10-gallon autoclave at 150° C. for 72 hours. The resulting mixture was filtered, and the separated solids were washed three times with distilled water, dried at 120° C. and then calcined at 538° C. for 4 hours. 
     The resulting dried powder contained 0.37 weight percent of sodium, calculated as elemental sodium, and x-ray diffraction analysis indicated that the powder had the x-ray diffraction pattern of beta zeolite. The following is the x-ray diffraction pattern of the powder product, showing only the lines that are common to all 4 sources of beta zeolite in U.S. Pat. No. 3,308,069. 
     
         ______________________________________   Line Relative   d(A) Intensity______________________________________   4.18 16.2   3.99 100.0   3.54 6.1   3.35 12.6   3.11 3.0   3.05 14.6   2.94 5.3   2.69 4.1   2.54 1.5   2.08 11.5______________________________________ 
    
     The powder was employed as the catalyst without being ion-exchanged. Some powder was ion-exchanged using the ion-exchange procedure of Example 21 to reduce the sodium content, and after being ion-exchanged, the powder&#39;s aluminum content, the powder&#39;s silica-to-alumina mole ratio, and the silicon-to-aluminum atom ratio were measured as 1.14 weight percent, 68:1, and 34:1, respectively. 
     EXAMPLE 20 
     8 kilograms of distilled water, 8 kilograms of an aqueous solution containing 40 weight percent of tetraethylamine hydroxide, 3.81 kilograms of an aqueous solution containing 20 weight percent of tetraethylamine hydroxide, 0.6 kilogram of sodium aluminate, and 12.2 kilograms of a silica sol containing 40 weight percent of silica were mixed and stirred in a 10 gallon autoclave at 150° C. for 72 hours. The resulting mixture was filtered, and the separated solids were washed three times with distilled water, dried at 120° C. for about 16 hours and then calcined at 538° C. for 6 hours. 
     The resulting dried powder contained 0.17 weight percent of sodium, calculated as elemental sodium. X-ray diffraction analysis indicated that the powder had the x-ray diffraction pattern of beta zeolite. The following is the x-ray diffraction pattern of the powder product, showing only the lines that are common to all 4 sources of beta zeolite in U.S. Pat. No. 3,308,069. 
     
         ______________________________________   Line Relative   d(A) Intensity______________________________________   4.19 17.7   4.01 100.0   3.54 Weak   3.35 13.8   3.11 Weak   3.05 13.4   2.95  2.8   2.67 Weak   2.49  0.6   2.09  7.6______________________________________ 
    
     The powder was employed as the catalyst without being ion-exchanged. After being ion-exchanged using the procedure of Example 21 in order to reduce the sodium content, the powder&#39;s silica-to-alumina mole ratio and silicon-to-aluminum atom ratio were measured as 30:1 and 14.8:1, respectively. 
     EXAMPLE 21 
     2.3 kilograms of the un-ion-exchanged catalyst powder produced in Example 20, 4 kilograms of distilled water, and 12 kilograms of an aqueous solution containing 19 weight percent of ammonium nitrate were stirred in a 22-liter flask at 72° C. for 4 hours. The mixture was then cooled; the liquid was removed by decantation, and the resulting ion-exchanged catalyst was then washed with water. The catalyst was then dried at 120° C. and calcined at 538° C. for 3 hours. The ion-exchanged catalyst contained 0.01 weight percent of sodium (calculated as elemental sodium), 2.43 weight percent of aluminum (calculated as elemental aluminum), and a silica-to-alumina mole ratio and a silicon-to-aluminum atomic ratio of 30:1 and 14.8:1, respectively. 
     163 grams of this dry, ion-exchanged beta zeolite powder, 454 grams of an alumina sol containing 8.8 weight percent of solids, and 123 grams of distilled water were blended to obtain a smooth, uniform slurry. The slurry was maintained at 23° C. for 5 hours to permit liquid to evaporate from the slurry. The slurry was then dried at 120° C. for about 16 hours and calcined at 538° C. for 2 hours, to afford solids containing 80 weight percent of beta zeolite and 20 weight percent of alumina, which were then ground and sieved to form particles having a 20-40 mesh size. 
     EXAMPLES 22-40 
     In each of Examples 22-40, the particular feedstock employed was mixed in liquid form with a catalyst in a stirred reaction vessel with a continuous nitrogen purge to preclude oxygen from the system. The weight ratio of the feedstock-to-zeolite component of the catalyst was 49:1 in each case. The pressure of the contents of the reaction vessel was maintained at about 1 pound per square inch gauge. The temperature of the reaction vessel was raised to the reaction temperature and samples were withdrawn at various times after commencement of the reaction and analyzed. The conditions employed, the compositions of the feedstock employed and of the resulting products, the percent of the 1,5-, 1,6- and 2,6-DMN triad in each thereof, the percent of 2,6-DMN in each such 1,5-, 1,6-and 2,6-DMN triad, the percent decreases in each 1,5-, 1,6- and 2,6-DMN triad, the percent gains in each 1,7-, 1,8- and 2,7-DMN triad and the percent gain in total methylnaphthalene and trimethylnaphthalene content in each of Examples 22- 40 are presented in Tables 2-6. 
     The catalyst employed in Examples 22-24 was commercially available Union Carbide&#39;s unsupported LZ-Y72 in the hydrogen form as received from the manufacturer. The catalyst employed in Examples 25-28 was an unsupported beta zeolite having a relatively high silicon-to-aluminum ratio and prepared by the procedure of Example 19. The catalyst employed in Examples 29-37 was an unsupported beta zeolite having a relatively low silicon-to-aluminum ratio and prepared by the procedure of Example 20. A single sample of this catalyst was used for four cycles in Examples 32-37. The catalyst employed in Examples 38-40 was also the beta zeolite having the relatively low silicon-to-aluminum ratio and prepared by the procedure of Example 20, but in this instance ion-exchanged to reduce the sodium content and supported on an alumina matrix by the procedure of Example 21. 
     
                                           TABLE 2__________________________________________________________________________         Feed Ex. 22                    Ex. 23                          Ex. 24__________________________________________________________________________ConditionsCatalyst           LZ-Y72                    LZ-Y72                          LZ-Y72Temperature (°C.)              250   250   250Hours on Stream    1     3     4.75Product Composition (wt %)1,5-DMN       91.03              38.70 18.30 12.841,6-DMN       3.73 36.92 40.67 40.352,6-DMN       0    18.42 32.40 36.181,7-DMN       0.74 0.81  0.93  1.082,7-DMN       0    0.73  1.37  1.81Methylnaphthalenes         0.06 0.62  1.43  2.03Trimethylnaphthalenes         0.44 0.53  1.33  2.02Other         4.00 3.27  3.57  3.69Total         100.00              100.00                    100.00                          100.001,5-, 1,6- and         94.76              94.04 91.37 89.372,6-DMN triad content2,6-DMN percent in 1,5-, 1,6-         0    19.59 35.46 40.49and 2,6-DMN triad1,5-, 1,6- and 2,6-DMN         0    0.72  3.39  5.39triad percent loss1,7-, 1,8- and 2,7-DMN         0    0.80  1.56  2.15triad percent gainMethylnaphthalene and         0    0.71  2.32  3.61trimethylnaphthalenepercent gain__________________________________________________________________________ 
    
     
                                           TABLE 3__________________________________________________________________________         Feed Ex. 25                  Ex. 26                       Ex. 27                           Ex. 28__________________________________________________________________________ConditionsCatalyst from Example              19  19   19  19Temperature (°C.)              250 250  250 250Hours on Stream    1   3    5   7Product Composition (wt %)1,5-DMN       91.03              54.00                  28.93                       18.94                           14.091,6-DMN       3.73 28.76                  37.62                       39.70                           40.412,6-DMN       0    12.91                  28.63                       35.96                           39.551,7-DMN       0.74 0.61                  0.58 0.60                           0.672,7-DMN       0    0.67                  1.09 1.13                           1.28Methylnaphthalenes         0    0.12                  0.29 0.41                           0.57Trimethylnaphthalenes         0.44 0.10                  0.19 0.34                           0.46Other         4.06 2.83                  2.67 2.92                           2.97Total         100.00              100.00                  100.00                       100.00                           100.001,5-, 1,6- and         94.76              95.67                  95.18                       94.60                           94.052,6-DMN triad content2,6-DMN percent in 1,5-, 1,6-         0    13.49                  30.08                       38.01                           42.05and 2,6-DMN triad1,5-, 1,6- and 2,6-DMN         0    -0.91                  -0.42                       0.16                           0.71triad percent loss1,7-, 1,8- and 2,7-DMN         0    0.54                  0.93 0.99                           1.21triad percent gainMethylnaphthalene and         0    -0.23                  0.04 0.31                           0.59trimethylnaphthalenepercent gain__________________________________________________________________________ 
    
     
                       TABLE 4______________________________________          Feed  Ex. 29  Ex. 30  Ex. 31______________________________________ConditionsCatalyst from Example    20      20    20Temperature (°C.) 250     250   250Hours on Stream          1.25    3     5Product Composition (wt %)1,5-DMN          91.03   21.94   10.79 8.201,6-DMN          3.73    38.62   40.89 41.202,6-DMN          0       35.59   43.28 44.941,7-DMN          0.74    0.52    0.60  0.642,7-DMN          0       0.30    0.53  0.47Methylnaphthalenes            0       0.33    0.59  0.84Trimethylnaphthalenes            0.44    0.16    0.46  0.78Other            4.06    2.54    2.86  2.93Total            100.00  100.00  100.00                                  100.001,5-, 1,6- and   94.76   96.15   94.96 94.342,6-DMN triad content2,6-DMN percent in 1,5-, 1,6-            0       37.02   45.58 47.63and 2,6-DMN triad1,5-, 1,6- and 2,6-DMN            0       -1.39   -0.20 0.42triad percent loss1,7-, 1,8- and 2,7-DMN            0       0.08    0.39  0.37triad percent gainMethylnaphthalene and            0       0.05    0.61  1.18trimethylnaphthalenepercent gain______________________________________ 
    
     
                       TABLE 5______________________________________            Feed    Ex. 32  Ex. 33                                  Ex. 34______________________________________ConditionsCatalyst from Example    20      20    20Temperature (°C.) 240     240   240Hours on Stream          3       3.9   3Catalyst Cycle           1st     1st   3rdProduct Composition (wt %)1,5-DMN          88.14   9.63    7.99  26.621,6-DMN          3.66    39.45   39.53 35.392,6-DMN          0       41.50   42.34 29.831,7-DMN          0.74    0.66    0.69  0.572,7-DMN          0       1.26    1.50  1.02Methylnaphthalenes            0.13    0.99    1.17  0.26Trimethylnaphthalenes            0.54    0.53    0.70  0.17Other            6.79    5.98    6.08  6.14Total            100.00  100.00  100.00                                  100.001,5-, 1,6- and   91.80   90.58   89.86 91.842,6-DMN triad content2,6-DMN percent in 1,5-, 1,6-            0       45.82   47.12 32.48and 2,6-DMN triad1,5-, 1,6- and 2,6-DMN            0       1.22    1.94  -0.04triad percent loss1,7-, 1,8- and 2,7-DMN            0       1.18    1.45  0.85triad percent gainMethylnaphthalene and            0       0.85    1.20  -0.24trimethylnaphthalenepercent gain______________________________________            Feed    Ex. 35  Ex. 36                                  Ex. 37______________________________________ConditionsCatalyst from Example    20      20    20Temperature (°C.) 240     265   265Hours on Stream          4.5     3     4.5Catalyst Cycle           3rd     4th   4thProduct Composition (wt %)1,5-DMN          88.14   17.73   11.47 8.161,6-DMN          3.66    38.10   39.23 39.732,6-DMN          0       36.25   40.02 42.311,7-DMN          0.74    0.59    0.66  0.722,7-DMN          0       0.97    1.20  1.13Methylnaphthalenes            0.13    0.33    0.48  0.70Trimethylnaphthalenes            0.54    0.29    0.37  0.52Other            6.79    5.74    6.57  6.73Total            100.00  100.00  100.00                                  100.001,5-, 1,6- and   91.80   92.08   90.72 90.202,6-DMN triad content2,6-DMN percent in 1,5-, 1,6-            0       39.37   44.11 46.91and 2,6-DMN triad1,5-, 1,6- and 2,6-DMN            0       -0.28   1.08  1.60triad percent loss1,7-, 1,8- and 2,7-DMN            0       0.82    1.12  1.11triad percent gainMethylnaphthalene and            0       -0.05   0.18  0.55trimethylnaphthalenepercent gain______________________________________ 
    
     
                       TABLE 6______________________________________          Feed  Ex. 38  Ex. 39  Ex. 40______________________________________ConditionsCatalyst from Example    21      21    21Temperature (°C.) 250     250   250Hours on Stream          1       2     3Product Composition (wt %)1,5-DMN          88.14   16.50   11.20 9.231,6-DMN          3.66    38.10   39.30 39.702,6-DMN          0       37.42   41.07 42.151,7-DMN          0.74    0.53    0.55  0.582,7-DMN          0       0.97    0.84  1.00Methylnaphthalenes            0.13    0.52    0.69  0.83Trimethylnaphthalenes            0.54    0.32    0.62  0.75Other            6.79    5.64    5.73  5.76Total            100.00  100.00  100.00                                  100.001,5-, 1,6- and   91.80   92.02   91.57 91.082,6-DMN triad content2,6-DMN percent in 1,5-, 1,6-            0       40.67   44.85 46.28and 2,6-DMN triad1,5-, 1,6- and 2,6-DMN            0       -0.22   0.23  0.72triad percent loss1,7-, 1,8- and 2,7-DMN            0       0.76    0.65  0.84triad percent gainMethylnaphthalene and            0       0.17    0.64  0.91trimethylnaphthalenepercent gain______________________________________ 
    
     Comparison of the results in Tables 2-6 illustrates clearly that (1) the use of a beta zeolite catalyst affords reduced losses of the 1,5-, 1,6- and 2,6-dimethylnaphthalene triad, reduced formation of methylnaphthalenes, trimethylnaphthalenes and the 1,7-, 1,8- and 2,7-dimethylnaphthalene triad relative to the use of the LZ-Y72 zeolite catalyst; and (2) the use of a beta zeolite catalyst either unsupported or supported on a base material and having a relatively lower silicon-to-aluminum ratio affords greater formation of 2,6-dimethylnaphthalene and reduced losses of the 1,5-, 1,6- and 2,6-dimethylnaphthalene triad relative to the use of a beta zeolite catalyst having a relatively higher silicon-to-aluminum ratio and permits the use of lower reaction temperatures or the use at a higher temperature of even a partially deactivated catalyst relative to the use of a LZ-Y72 zeolite catalyst. 
     From the above description, it is apparent that the objects of the present invention have been achieved. While only certain embodiments have been set forth, alternative embodiments and various modifications will be apparent from the above description to those skilled in the art. These alternatives are considered equivalents and are within the spirit and scope of the present invention.