Abstract:
The present invention relates to a method for refining polyoxymethylene dialkyl ethers by catalytic hydrogenation using a slurry bed, wherein, using a slurry bed reactor of refining by hydrogenation, an equilibrium system of products containing polyoxymethylene dialkyl ethers is refined by catalytic hydrogenation, so as to remove formaldehyde contained therein. The refining method by hydrogenation described in the present invention is able to remarkably increase the extracting rate of polyoxymethylene dialkyl ethers, and the polyoxymethylene dialkyl ethers obtained after subsequent rectification have purity greater than 99.5%, yield greater than 97% and atom utilization ratio close to 100%.

Description:
TECHNICAL FIELD 
       [0001]    The present invention relates to a method for refining polyoxymethylene dialkyl ethers by catalytic hydrogenation using a slurry bed, which belongs to the field of coal-based energy chemical industry, clean energy and refining by chemical process. 
       BACKGROUND OF THE INVENTION 
       [0002]    Recent investigation shows that, the apparent consumption of diesel fuel in China has already mounted up to 167 million tons, which leads to frequent occurrence of short supply of diesel fuel (the domestic demand ratio of diesel fuel to petrol is about 2.5:1, but the production ratio is about 2.3:1). Besides the reasons of unreasonable pricing of different types of oil products, and slow price linkage mechanism of domestic petroleum products with international crude oil, the fundamental reason is the restriction of resource shortage. Traditionally, diesel fuel is made from feedstock of petroleum, and the resource endowment of China characterized in relatively “rich in coal, poor in oil, and lack in gas” leads to increasingly prominent contradiction between petroleum supply and relatively fast sustainable development of economic society. Since China became a net importer of petroleum in 1993, the import quantum increases fast and constantly, and the foreign-trade dependence already surpassed 56% after 2011, which has a severe impact on national strategic security of energy. 
         [0003]    Furthermore, the day-by-day deterioration of crude oil quality leads to continuous scale expansion of domestic catalytic processing of heavy oil and increasing percentage of diesel fuel produced by catalytic processing, which results in gradual decrease of the cetane number (CN value) of diesel fuel products and significant increase of noxious substance discharged after combustion, therefore, the urgent problem to be solved is to improve the CN value of diesel fuel. 
         [0004]    The tail gas discharged by diesel engine contains a large amount of noxious substance such as unburned hydrocarbon compounds and particulate matter (PM), as well as CO, CO 2  and NO R , which are one of the main sources of PM2.5 contamination in urban air. International Agency for Research on Cancer (IARC) affiliated to World Health Organization (WHO) declared in June, 2012 the decision to promote the cancer hazard ranking of diesel engine tail gas, from “possibly carcinogenic” classified in 1988 to “definitely carcinogenic”. As scientific research advances, now there is enough evidence to prove that diesel engine tail gas is one of the reasons that cause people to suffer from lung cancer. Furthermore, there is also limited evidence indicating that, inhaling diesel engine tail gas is relevant to suffering from bladder cancer. People come into contact with diesel engine tail gas through various channels in daily life and work. IARC hopes that this reclassification can provide reference for national governments and other decision makers, so as to actuate them to establish more strict discharge standards of diesel engine tail gas. This significant decision undoubtedly puts forward harsher requirements of diesel fuel quality. 
         [0005]    Reducing the content of noxious substance such as sulfur, nitrogen and aromatic hydrocarbon in fuels by petroleum refining process such as hydrogenation is an effective technical route to improve fuel quality, but has very demanding requirements of hydrogenation catalyst and reaction process, with relatively high processing cost. Internationally, many scientific research institutes are carrying out research and development on production technologies of oxygen-containing blending components of petrol and diesel fuel, especially those diesel fuel blending components with high oxygen content and high cetane number, and this has recently become a research hotspot in the technical field of new energy. 
         [0006]    Research has indicated that, in consideration of oxygen-containing fuel&#39;s own characteristic, when coal-based or methanol-based substance with a high oxygen content and a high cetane number is added into the fuel as a fuel additive, the discharge of hydrocarbon and CO, especially soot, can be effectively reduced, without changing the original parameters of the engine or increasing the discharge of NO x . 
         [0007]    So far, there is plenty of research indicating that, polyoxymethylene dimethyl ethers (abbreviated as POMDME n , n=2-8), which has a general formula of CH 3 (OCH 2 ) n OCH 3  and is a yellow liquid with a high boiling point, an average cetane number reaching above 63 and increasing dramatically as its degree of polymerization increases, an average oxygen content of 47%-50%, a flash point of about 65.5° C., and a boiling point of about 160-280° C., is a type of clean diesel fuel blending component with a high cetane number, and also a world-recognized environmental friendly fuel component. Polyoxymethylene dimethyl ethers can be blended into diesel fuel, and can significantly improve the performance of diesel fuel without the need to modify the engine oil feeding system of the in-use vehicle. However, it is discovered in practical usage that, the cetane number of polyoxymethylene dimethyl ethers is largely influenced by its degree of polymerization, and polyoxymethylene dimethyl ethers with a relatively high degree of polymerization is required to achieve better effectiveness. But, in consideration of the difficulty of polymerization reaction in its own, relatively demanding requirements are put forward not only for equipment but also for process conditions, with increased difficulty of processing and extracting. Therefore, people gradually move their focus onto characteristic of polyoxymethylene dialkyl ethers. Polyoxymethylene dialkyl ethers (PODE n ) are a series of acetal polymers with low relative molecular weights, which comprise oxymethylene groups as main chain and low carbon alkyl groups as terminal groups, with a general formula of R(OCH 2 ) n OR where R is an alkyl chain of C n H 2n+1 . 
         [0008]    Since the terminal groups of polyoxymethylene dialkyl ethers has relatively high molecular weights in its own, only relatively low degree of polymerization is required to achieve a cetane number performance similar to that of polyoxymethylene dimethyl ethers, and the difficulty during the preparation process is relatively low. Polyoxymethylene dialkyl ethers have good performance of environmental protection, and when blended into diesel fuel at a certain percentage, they can increase oxygen content of the oil product, and greatly reduce the discharge of contaminants such as SO x , unburned hydrocarbon compounds, PM particulate black smoke and CO from vehicle tail gas. Because polyoxymethylene dialkyl ethers have a high cetane number and physical property similar to that of diesel fuel, they are also a type of diesel fuel additive with very high application value. 
         [0009]    Synthesis of polyoxymethylene dialkyl ethers (including polyoxymethylene dimethyl ethers) may be carried out by processing synthesis gas through a series of steps of methanol, formaldehyde, methylal, polyformaldehyde and dimethyl ether etc. China is a famous huge country of coal storage, and Chinese technologies of producing methanol from coal, producing methanol from natural gas and producing methanol from coke-oven gas are increasingly mature, and the production capacity of methanol broke through 50 million tons in 2012, but the rate of equipment operation is merely about 50%, thus the problem of methanol surplus has already become very prominent, and the industrial chain of coal chemical industry is in an urgent need to be further extended. Therefore, developing the technology of producing polyoxymethylene dialkyl ethers from coal-based methanol can not only provide a new technology to significantly improve diesel fuel product quality, but also improve the feedstock structure of diesel fuel production, so as to make it more suitable for the resource endowment of domestic fossil energy and enhance the strategic security of domestic supply of liquid fuel for engines. 
         [0010]    The preparation process of polyoxymethylene dialkyl ethers should comprise three major process units, wherein, the first unit is a synthesis unit where cascade polymerization reactions and thermodynamic equilibrium reactions catalyzed by acidic catalysts take place; the second unit is a pretreatment unit where processing steps such as deacidifying by neutralization and dehydration by drying take place; and the third unit is a unit for rectification and separation of the downstream products, and this unit attempts to separate polyoxymethylene dialkyl ethers by simple rectification or complicated rectification such as extractive rectification, azeotropic rectification, etc. 
         [0011]    So far, domestic and foreign research on preparation process of polyoxymethylene dialkyl ethers (including polyoxymethylene dimethyl ethers) mainly focuses on the aspects of feedstock choice, condition optimization and catalyst system optimization of the synthesis unit, as well as the process technology to improve the distribution of target products and increase product yield. As for optimization of feedstock of synthesis, there are mainly the following five techniques: the first technique is synthesizing polyoxymethylene dimethyl ethers from the feedstock of methanol, formaldehyde or aqueous formaldehyde solution or paraformaldehyde, with details described in patent literatures such as U.S. Pat. No. 6,437,195B2, US2008/0207954A1 and EP1070755A1; the second technique is synthesizing polyoxymethylene dimethyl ethers from the feedstock of methylal, trioxane or paraformaldehyde, with details described in patent literatures such as US2007/0260094A1 and US2449469A; the third technique is synthesizing polyoxymethylene dimethyl ethers from the feedstock of methanol and dimethyl ether, with details described in patent literatures such as U.S. Pat. No. 6,265,528B1; the fourth technique is developed on the basis of the foregoing three techniques, and this technique uses alcohol-containing by-products of other chemical processes in the prior art to synthesize mixture of polyoxymethylene dialkyl ethers with various degrees of polymerization and various terminal groups, and the major representative techniques are synthesis of polyoxymethylene dialkyl ethers with various degrees of polymerization and various terminal groups from the feedstock of industrial alcohol brewing by-products or Fischer-Tropsch synthesis by-products or C4, C5 fractions of petroleum, which are disclosed in Chinese patent literatures CN102173984A and CN102180778A. 
         [0012]    In the above-mentioned technical solutions of synthesis of polyoxymethylene dialkyl ethers, the separation and extraction of synthesized products is carried out without exception by conventional ordinary rectification, extractive rectification or azeotropic rectification of the prior art, and no further in-depth research is done in respect of the extraction unit of target products. However, it is discovered in practical research that, when extracting target products by using the foregoing conventional seemingly viable means, it always leads to that the extracting rate of products is not high, and the purity of the extracted products is not satisfactory, which is not enough to meet the technical standard for blending with fossil diesel fuel and requires subsequent additional purification operations to meet the needs, and no matter how the parameters and conditions of the entire operating process of the extraction unit are optimized, the difficult problem about extracting rate always cannot be solved, and no significant increase in extracting rate or product purity can be achieved. In practical production, in consideration of economical and various other aspects, no matter how great the efficiency of the synthesis unit at the front is, the incapability of obtaining required products by effective extracting means is always a difficult problem and bottleneck that restrains the development of this technology, which is an urgent matter to be solved in this field. 
       SUMMARY OF THE INVENTION 
       [0013]    The technical problem to be solved in the present invention is, by in-depth research on the process of the unit for extracting polyoxymethylene dialkyl ethers in prior art, to find out the influence reasons of inferior extracting rate of the extraction unit and inferior purity of the extracted products, so as to provide a method for refining polyoxymethylene dialkyl ethers by catalytic hydrogenation using a slurry bed, which is able to significantly increase the extracting rate and the product purity. 
         [0014]    To solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions: 
         [0015]    A method for refining polyoxymethylene dialkyl ethers by catalytic hydrogenation using a slurry bed is provided, wherein, using a slurry bed reactor of refining by hydrogenation and in the presence of catalyst, an equilibrium system of products containing polyoxymethylene dialkyl ethers is refined by catalytic hydrogenation, so as to remove formaldehyde contained therein, and subsequent rectification operations are performed on the products after formaldehyde removal. 
         [0016]    Preferably, the catalyst is skeletal metal catalyst. 
         [0017]    The catalyst is preferably Raney-Co, Raney-Fe, Raney-Ru, Raney-Ni catalyst, Raney-Cu catalyst or combinations thereof. 
         [0018]    The catalyst is most preferably Raney-Ni catalyst or Raney-Cu catalyst. 
         [0019]    Specifically, the amount of Raney-Ni catalyst used is equal to 0.2-10 wt % of the products to be refined by hydrogenation. 
         [0020]    Preferably, the amount of Raney-Ni catalyst used is equal to 3-8 wt % of the products to be refined by hydrogenation. 
         [0021]    Specifically, the amount of Raney-Cu catalyst used is equal to 0.2-10 wt % of the products to be refined by hydrogenation. 
         [0022]    Preferably, the amount of Raney-Cu catalyst used is equal to 3-8 wt % of the products to be refined by hydrogenation. 
         [0023]    Preferably, the amount of formaldehyde contained in the equilibrium system of products containing polyoxymethylene dialkyl ethers is 0.5-20 wt %. 
         [0024]    Preferably, the process conditions of refining by catalytic hydrogenation are that: the hydrogen pressure is 1-10 Mpa, the reaction temperature of catalytic hydrogenation is 60-150° C., and the reaction time is 2-8 hours. 
         [0025]    Most preferably, the process conditions of refining by catalytic hydrogenation are that: the hydrogen pressure is 2-6 Mpa, the reaction temperature of catalytic hydrogenation is 70-120° C., and the reaction time is 3-6 hours. 
         [0026]    Specifically, the extracting step comprises one or more operations selected from atmospheric distillation, reduced pressure distillation, flash evaporation, rectification, phase separation and filtration. 
         [0027]    The aforementioned technical solutions of the present invention have the following advantages, as compared to the prior art: 
         [0028]    (1) By in-depth research on the synthesis process of polyoxymethylene dialkyl ethers, the applicant has discovered that, no matter which of formaldehyde, paraformaldehyde or methylal is used as feedstock for the reaction, the entire reaction system is equilibrium and reversible, thus the problem of incomplete reaction with low carbon alcohol (or methanol) always exists, therefore, regardless of how the reaction conditions are improved, there is always 3.5 wt % of formaldehyde (or monomer of depolymerized paraformaldehyde or methylal) unable to completely react in the product system, and the reason that leads to the difficulty of extraction of polyoxymethylene dialkyl ether products and the low product purity is mainly that the formaldehyde in the system gives rise to unexpected negative effect, that is, complexation reaction happens between formaldehyde and polyoxymethylene dialkyl ethers with various degrees of polymerization, and the products with various degrees of polymerization are chained together by formaldehyde to form enormous complexation system, which causes the entire product system unable to be extracted or refined by ordinary processes such as distillation, not only bringing about great difficulty of separation process, but also severely affecting product yield and economic efficiency; furthermore, in the rectification process oxidization and dismutation of formaldehyde into formic acid takes place to form an acidic environment, and formic acid is a catalyst for reverse decomposition of polyoxymethylene dialkyl ethers, which causes the technical problem that the target products of polyoxymethylene dialkyl ethers are decomposed reversely and new formaldehyde is released; therefore, before extracting the target products, it is necessary to specifically eliminate the small amount of formaldehyde contained in the equilibrium system, in order to release the respective products required and to obtain satisfactory products by other feasible means; 
         [0029]    (2) At the same time of research on factors that influence the extraction efficiency, it is surprisingly discovered by the applicant that, in the entire equilibrium system after synthesis of products, the water content has a great influence on extraction efficiency and purity of the products, therefore, when choosing the process of refining by eliminating formaldehyde, it is necessary to carefully select a reasonable method in order to maximally ensure the extraction efficiency and purity of the products; 
         [0030]    (3) In the extraction process described in the present invention, after careful research, the applicant has inventively discovered the key factors that influence the extraction efficiency of polyoxymethylene dialkyl ethers in the prior art, and has achieved high-efficiency, high-purity extraction of polyoxymethylene dialkyl ethers with various degrees of polymerization by specific modification of the above-mentioned factors which have not been cared or considered by those skilled in the art; 
         [0031]    (4) In the method of the present invention for refining polyoxymethylene dialkyl ethers by catalytic hydrogenation using a slurry bed, the unreacted formaldehyde contained in the equilibrium system of products containing polyoxymethylene dialkyl ethers is transformed into methanol by reduction reaction, so as to break the complicated azeotropic system between formaldehyde and methanol, as well as between formaldehyde and the products, so that polyoxymethylene dialkyl ethers with purity greater than 99.5% can be produced by atmospheric rectification and/or reduced pressure rectification of the products, and the yield of polyoxymethylene dialkyl ethers is greater than 97%, the atom utilization ratio is close to 100%. The technological process has no discharge of waste water or waste residue, thus is an innovative green process and technology to separate and refine polyoxymethylene dialkyl ethers; 
         [0032]    (5) The method of the present invention for refining polyoxymethylene dialkyl ethers by catalytic hydrogenation using a slurry bed utilizes a slurry bed reactor of refining by hydrogenation together with skeletal metal catalyst which consists of Raney-Co, Raney-Fe, Raney-Ru, Raney-Ni catalyst, Raney-Cu catalyst or combinations thereof, preferably Raney-Ni catalyst and/or Raney-Cu catalyst, to specifically and high selectively refine the equilibrium products by hydrogenation of formaldehyde, so as to specifically separate and purify the products with various degrees of polymerization, and the aforementioned selected catalyst has high activity and high efficiency; 
         [0033]    (6) As for the equilibrium system after processing by the refining method of the present invention, subsequent separating operations may be performed by ordinary processing means such as atmospheric rectification and reduced pressure rectification, and the products with various degrees of polymerization that have been separated have high purity and high yield. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0034]    In order to make the present invention more easily and clearly understood, detailed description is further presented below, with reference of accompanying drawings, wherein, 
           [0035]      FIG. 1  is a process flow diagram showing the method of producing polyoxymethylene dialkyl ethers described in the present invention; 
           [0036]      FIG. 2  is a process flow diagram showing the step of refining by hydrogenation using a slurry bed described in the present invention; 
       
    
    
       [0037]    Wherein, the markings in the accompanying drawings are explained as follows: 1-slurry bed synthesis reactor, 2-buffer tank, 3-drying tower, 4-slurry bed reactor of refining by hydrogenation, 5-buffer tank, 6-atmospheric rectification tower, 7-reduced pressure rectification tower. 
       DETAILED DESCRIPTION OF EMBODIMENTS 
       [0038]    As shown in  FIG. 1 , the process of the present invention for preparation of polyoxymethylene dialkyl ethers comprises three major process units, the first unit is a synthesis unit, and its structure includes a slurry bed synthesis reactor  1 , a buffer tank  2 , and a drying tower  3 , wherein, the equilibrium system obtained by synthesis reaction in the slurry bed synthesis reactor  1  is successively deacidified in the buffer tank  2  and dehydrated in the drying tower  3 ; the feedstock of synthesis of polyoxymethylene dimethyl ethers mainly consists of two parts: one part is compounds that provide low polyformaldehyde, including aqueous formaldehyde solution, trioxane, paraformaldehyde, etc., and the other part is compounds that provide terminal groups, including methanol, dimethyl ether, methylal, etc., and the synthesis reaction is a cascade polymerization reaction and a thermodynamic equilibrium reaction catalyzed by acidic catalyst; the second unit is a unit for pretreatment and catalytic refining, and its structure includes a slurry bed reactor of refining by hydrogenation  4  and a buffer tank  5 , wherein, the equilibrium system is successively processed in the slurry bed reactor of refining by hydrogenation  4  and the buffer tank  5 , thereby the unreacted formaldehyde is removed; the third unit is a unit for extraction by rectification and separation, its structure includes an atmospheric rectification tower  6  and a reduced pressure rectification tower  7 , wherein, high purity polyoxymethylene dialkyl ethers are finally obtained after the equilibrium system has passed through the atmospheric rectification tower  6  and the reduced pressure rectification tower  7 . The unreacted light components such as methylal and methanol as well as the polyoxymethylene dialkyl ethers with boiling points lower than 150° C. are returned as recycle stream to the slurry bed synthesis reactor  1 ; the heavy components of polyoxymethylene dialkyl ethers with boiling points higher than 320° C. are also returned as recycle stream to the slurry bed synthesis reactor  1 . 
         [0039]      FIG. 2  illustrates a flow diagram of the slurry bed reactor apparatus of refining by hydrogenation, wherein, the products before refining (the equilibrium system) and hydrogen are mixed at a selected hydrogen-to-oil ratio in a mixer and enter the slurry bed reactor (of refining by hydrogenation), and refined products of the equilibrium system are obtained after refining by hydrogenation, and subsequent extracting operations are then performed. 
         [0040]    In Embodiment 1 and Embodiment 2 of the present invention, as well as in Comparison Example 1, the equilibrium systems of products containing polyoxymethylene dimethyl ethers are the same, the preparation method of which is that: 
         [0041]    In a 2 L slurry bed synthesis reactor  1 , 60˜80 g strongly acidic catalyst of Amberlyst15 cation exchange resin is added, and then 1200 g in total of paraformaldehyde (or trioxane) and acetal (or methanol, ethanol, propanol, butanol, pentanol) at various molar ratios are added, wherein the molar ratios are within 1:1˜2:1. First the air in the reactor is replaced by nitrogen, then 1.5 MPa of initial nitrogen is filled in, the reaction mixture is heated up to the reaction temperature of 70-130° C. and reacts under stirring for 0.5˜6 hours, thereby the equilibrium system of products containing polyoxymethylene dimethyl ethers are obtained, wherein the product distribution and yield of the target product POMDME n  are shown in Table 1. 
         [0000]    
       
         
               
             
               
               
               
               
             
               
               
               
               
             
           
               
                 TABLE 1 
               
             
             
               
                   
               
               
                 product distribution and yield of the target product 
               
               
                 POMDME n  of the equilibrium system of products containing 
               
               
                 polyoxymethylene dimethyl ethers 
               
             
          
           
               
                   
                 Products 
                 Boiling Point/° C. 
                 Content/wt. % 
               
               
                   
                   
               
             
          
           
               
                   
                 Formaldehyde 
                 −19.5 
                  3.0~10.0 
               
               
                   
                 Methanol 
                 64.7 
                 2.0~5.0 
               
               
                   
                 Methylal 
                 42.3 
                 28.0~30.0 
               
               
                   
                 POMDME 2   
                 105 
                 25.0~26.0 
               
               
                   
                 POMDME 3   
                 156 
                 10.0~13.0 
               
               
                   
                 POMDME 4   
                 202 
                 5.0~6.0 
               
               
                   
                 POMDME 5   
                 242 
                 3.0~3.5 
               
               
                   
                 POMDME 6   
                 280 
                 2.0~2.5 
               
               
                   
                 POMDME 7   
                 313 
                 0.5~1.0 
               
               
                   
                 POMDME 8   
                 320 
                 0.2-0.5 
               
               
                   
                 ΣPOMDME 2-8  wt % 
                   
                 ~50.0 
               
               
                   
                   
               
             
          
         
       
     
       Embodiment 1 
       [0042]    First, 63 g Raney-Ni catalyst is loaded into a 2 L pressurized slurry bed reactor of refining by hydrogenation  4 ; 
         [0043]    Then, an equilibrium system of 1260 g products containing polyoxymethylene dimethyl ethers is refined by catalytic hydrogenation, the amount of Raney-Ni catalyst used is equal to 5 wt % of the overall reaction products to be refined, and the process conditions are: the hydrogen pressure is 6 Mpa, the reaction temperature of refining by the slurry bed (i.e. the reaction temperature of catalytic hydrogenation) is 70° C., and the reaction time is 4 hours; 
         [0044]    Finally, the formaldehyde contained is hydrogenated into methanol by the catalytic function of Raney-Ni, and the methanol generated constitutes a component of the equilibrium products, thereby no other foreign component is generated while removing formaldehyde. The constituents and distribution of the main products before and after refining by catalytic hydrogenation are shown in Table 2. 
         [0045]    The equilibrium system after refining by catalytic hydrogenation is extracted, and the extraction process utilizes the atmospheric rectification technology, with tower plate number of 10˜40, gas temperature of 48˜58.0° C. at tower top, temperature of 100˜120° C. at tower bottom, feedstock temperature of 60˜90° C., and reflux ratio of 1.0˜3.0. After the extraction is finished, the testing result of extraction rate of the products is shown in Table 3. 
       Embodiment 2 
       [0046]    First, 37.8 g Raney-Cu catalyst is loaded into a 2 L pressurized slurry bed reactor of refining by hydrogenation; 
         [0047]    Then, an equilibrium system of 1260 g products containing polyoxymethylene dimethyl ethers is refined by catalytic hydrogenation, the amount of Raney-Cu catalyst used is equal to 3 wt % of the overall reaction products to be refined, and the process conditions are: the hydrogen pressure is 2 Mpa, the reaction temperature of refining by the slurry bed (i.e. the reaction temperature of catalytic hydrogenation) is 110° C., and the reaction time is 4.5 hours; 
         [0048]    Finally, the formaldehyde contained is hydrogenated into methanol by the catalytic function of Raney-Cu, and the methanol generated constitutes a component of the equilibrium products, thereby no other foreign component is generated while removing formaldehyde. The constituents and distribution of the main products before and after refining by catalytic hydrogenation are shown in Table 2. 
         [0049]    This embodiment utilizes the same extraction process as in Embodiment 1 to perform the extraction operations. 
         [0050]    In Embodiment 1 and Embodiment 2, the constituents and distribution of the main products before and after refining by catalytic hydrogenation are shown in Table 2 (Note: the symbol “˜” therein means being close to). 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 2 
               
             
             
               
                   
               
               
                 constituents and distribution of the main products before 
               
               
                 and after refining by hydrogenation catalyzed by Raney-Cu catalyst 
               
               
                 (or Raney-Ni catalyst) 
               
             
          
           
               
                   
                 Constituents 
               
             
          
           
               
                   
                   
                   
                   
                   
                   
                 Conversion 
                   
               
               
                   
                 Methanol 
                 Formaldehyde 
                 Methylal 
                 ΣPODE 2-8   
                 ΣPODE n&gt;8   
                 rate of 
                 Selectivity 
               
               
                 System 
                 wt % 
                 wt % 
                 wt % 
                 wt % 
                 wt % 
                 formaldehyde/% 
                 of catalyst/% 
               
               
                   
               
             
          
           
               
                 Before refining 
                 3.7 
                 7.8 
                 34.0 
                 54.0 
                 0.5 
                 — 
                 — 
               
               
                 by 
               
               
                 hydrogenation 
               
               
                 After refining 
                 11.5 
                 0.01 
                 34.0 
                 54.0 
                 0.5 
                 ~100 
                 ~100 
               
               
                 by 
               
               
                 hydrogenation 
               
               
                 in Embodiment 1 
               
               
                 After refining 
                 11.48 
                 0.02 
                 34.5 
                 53.5 
                 0.5 
                 ~99.7 
                 ~100 
               
               
                 by 
               
               
                 hydrogenation 
               
               
                 in Embodiment 2 
               
               
                   
               
             
          
         
       
     
         [0051]    Thus it can be seen that, the catalyst used in the present invention can effectively solve the problem of eliminating formaldehyde contained in the product system, and meanwhile does not affect other required products in the system, with very high selectivity and efficiency of catalyst. 
       Comparative Example 1 
       [0052]    This comparative example is based on the same equilibrium system of products containing polyoxymethylene dimethyl ethers as in Embodiment 1, but the refining step as in Embodiment 1 is omitted, instead the overall equilibrium system after synthesis directly enters the extraction unit, and Comparative Example 1 utilizes the same extraction means as in Embodiment 1 to extract the products with various degrees of polymerization. After the extraction is finished, the testing result of extraction rate of the products is shown in Table 3. 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                 TABLE 3 
               
             
             
               
                   
               
               
                 extraction rate of the products 
               
             
          
           
               
                   
                 Constituents 
               
             
          
           
               
                   
                   
                 Formaldehyde 
                   
                   
               
               
                   
                 Content of 
                 content after 
                 Recovery ratio 
               
               
                   
                 ΣPODE 2-8  in 
                 atmospheric 
                 of the target 
                 Purity of the 
               
               
                   
                 the equilibrium 
                 rectification/ 
                 product 
                 target product 
               
               
                 Number 
                 products/wt % 
                 wt % 
                 ΣPODE 2-8 /% 
                 ΣPODE 2-8 /% 
               
               
                   
               
             
          
           
               
                 Embodiment 1 
                 54.0 
                 0.01 
                 ~100 
                 99.9 
               
               
                 Comparative example 1 
                 54.0 
                 7.4 
                 ~32.0 
                 ~92.6 
               
               
                   
               
             
          
         
       
     
         [0053]    The equilibrium systems of products containing polyoxymethylene dialkyl ethers in Embodiment 3-1 to Embodiment 6-2 of the present invention are the same, the preparation method of which is that: 
         [0054]    In a 2 L pressurized slurry bed reactor, 60˜80 g strongly acidic catalyst of Amberlyst15 cation exchange resin is added, and then 1200 g in total of paraformaldehyde (or trioxane) and ethanol (or propanol, butanol, pentanol) at various molar ratios are added, wherein the molar ratios are within 1:1˜2:1. First the air in the reactor is replaced by nitrogen, then 1.5 MPa of initial nitrogen is filled in. The reaction mixture is heated up to the reaction temperature of 70-130° C. and reacts under stirring for 0.5˜6 hours, thereby the equilibrium systems of products respectively containing polyoxymethylene diethyl ether, polyoxymethylene dipropyl ether, polyoxymethylene dibutyl ether and polyoxymethylene dipentyl ether are obtained. 
       Embodiment 3-1 
       [0055]    First, 63 g Raney-Cu catalyst is loaded into a 2 L pressurized slurry bed reactor of refining by hydrogenation; 
         [0056]    Then, an equilibrium system of 1260 g products containing polyoxymethylene diethyl ethers is refined by catalytic hydrogenation, the amount of Raney-Cu catalyst used is equal to 5 wt % of the overall reaction products to be refined, and the process conditions are: the hydrogen pressure is 3 Mpa, the reaction temperature of refining by the slurry bed (i.e. the reaction temperature of catalytic hydrogenation) is 100° C., and the reaction time is 5 hours; 
         [0057]    Finally, the formaldehyde contained is hydrogenated into methanol by the catalytic function of Raney-Cu, and the methanol generated constitutes a component of the equilibrium products, thereby no other foreign component is generated while removing formaldehyde. The constituents and distribution of the main products before and after refining by catalytic hydrogenation are shown in Table 4-1. 
         [0058]    The equilibrium system after refining is extracted, and the extraction process utilizes the atmospheric rectification technology, with tower plate number of 20˜50, gas temperature of 45˜65.0° C. at tower top, temperature of 110˜130° C. at tower bottom, feedstock temperature of 60˜90° C., and reflux ratio of 1.0˜3.0. After the extraction is finished, the testing result of extraction rate of the products is shown in Table 4-2. 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 4-1 
               
             
             
               
                   
               
               
                 constituents and distribution of the main products before 
               
               
                 and after refining by hydrogenation catalyzed by Raney-Cu catalyst 
               
             
          
           
               
                   
                 Constituents 
               
             
          
           
               
                   
                   
                   
                   
                   
                   
                 Conversion 
                   
               
               
                   
                 Ethanol 
                 Formaldehyde 
                 Methanol 
                 PODE 1   
                 ΣPODE 2-6   
                 rate of 
                 Selectivity 
               
               
                 System 
                 wt % 
                 wt % 
                 wt % 
                 wt % 
                 wt % 
                 formaldehyde/% 
                 of catalyst/% 
               
               
                   
               
             
          
           
               
                 Before refining 
                 5.1 
                 4.7 
                 0 
                 38.0 
                 52.2 
                 — 
                 — 
               
               
                 by hydrogenation 
               
               
                 After refining 
                 5.1 
                 0.00 
                 4.7 
                 38.0 
                 52.2 
                 ~100 
                 ~100 
               
               
                 by hydrogenation 
               
               
                   
               
             
          
         
       
     
       Embodiment 3-2 
       [0059]    This embodiment is based on the same synthesis product system as in Embodiment 3-1, but the refining step as in Embodiment 3-1 is omitted, instead the overall equilibrium system after synthesis directly enters the extraction unit, and Embodiment 3-1 and Embodiment 3-2 utilize the same extraction means to extract the products with various degrees of polymerization. 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                 TABLE 4-2 
               
             
             
               
                   
               
               
                 extraction rate of the products 
               
             
          
           
               
                   
                 Constituents 
               
             
          
           
               
                   
                   
                 Formaldehyde 
                   
                   
               
               
                   
                 Content 
                 content after 
                 Recovery 
               
               
                   
                 of ΣPODE 2-6   
                 atmospheric 
                 ratio of the 
                 Purity of the 
               
               
                   
                 in the equilibrium 
                 rectification/ 
                 target product 
                 target product 
               
               
                 Number 
                 products/wt % 
                 wt % 
                 ΣPODE 2-6 /% 
                 ΣPODE 2-6 /% 
               
               
                   
               
             
          
           
               
                 Embodiment 3-1 
                 52.2 
                 ~0.0 
                 ~99.9 
                 99.9 
               
               
                 Embodiment 3-2 
                 52.2 
                 8.6 
                 ~36.5 
                 ~91.4 
               
               
                   
               
             
          
         
       
     
       Embodiment 4-1 
       [0060]    First, 88.2 g Raney-Ni catalyst is loaded into a 2 L pressurized slurry bed reactor of refining by hydrogenation; 
         [0061]    Then, an equilibrium system of 1260 g products containing polyoxymethylene diethyl ethers is refined by catalytic hydrogenation, the amount of Raney-Ni catalyst used is equal to 7 wt % of the overall reaction products to be refined, and the process conditions are: the hydrogen pressure is 4 Mpa, the reaction temperature of refining by the slurry bed (i.e. the reaction temperature of catalytic hydrogenation) is 80° C., and the reaction time is 3.5 hours; 
         [0062]    Finally, the formaldehyde contained is hydrogenated into methanol by the catalytic function of Raney-Ni, and the methanol generated constitutes a component of the equilibrium products, thereby no other foreign component is generated while removing formaldehyde. The constituents and distribution of the main products before and after refining by catalytic hydrogenation are shown in Table 5-1. 
         [0063]    The equilibrium system after refining is extracted, and the extraction process utilizes the atmospheric rectification technology, with tower plate number of 20˜50, gas temperature of 45˜65.0° C. at tower top, temperature of 110˜130° C. at tower bottom, feedstock temperature of 60˜90° C., and reflux ratio of 1.0˜3.0. After the extraction is finished, the testing result of extraction rate of the products is shown in Table 5-2. 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 5-1 
               
             
             
               
                   
               
               
                 constituents and distribution of the main products before 
               
               
                 and after refining by hydrogenation catalyzed by Raney-Ni catalyst 
               
             
          
           
               
                   
                 Constituents 
               
             
          
           
               
                   
                   
                   
                   
                   
                   
                 Conversion 
                   
               
               
                   
                 Propanol 
                 Formaldehyde 
                 Methanol 
                 PODE 1   
                 ΣPODE 2-6   
                 rate of 
                 Selectivity 
               
               
                 System 
                 wt % 
                 wt % 
                 wt % 
                 wt % 
                 wt % 
                 formaldehyde/% 
                 of catalyst/% 
               
               
                   
               
             
          
           
               
                 Before refining 
                 4.5 
                 3.8 
                 0 
                 31.6 
                 60.1 
                 — 
                 — 
               
               
                 by hydrogenation 
               
               
                 After refining 
                 4.5 
                 0.01 
                 3.8 
                 31.6 
                 60.1 
                 ~99.7 
                 ~100 
               
               
                 by hydrogenation 
               
               
                   
               
             
          
         
       
     
       Embodiment 4-2 
       [0064]    This embodiment is based on the same synthesis product system as in Embodiment 4-1, but the refining step as in Embodiment 4-1 is omitted, instead the overall equilibrium system after synthesis directly enters the extraction unit, and Embodiment 4-1 and Embodiment 4-2 utilize the same extraction means to extract the products with various degrees of polymerization. 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                 TABLE 5-2 
               
             
             
               
                   
               
               
                 extraction rate of the products 
               
             
          
           
               
                   
                 Constituents 
               
             
          
           
               
                   
                   
                 Formaldehyde 
                   
                   
               
               
                   
                 Content of 
                 content after 
                 Recovery ratio 
               
               
                   
                 ΣPODE 2-6  in the 
                 atmospheric 
                 of the target 
                 Purity of the 
               
               
                   
                 equilibrium 
                 rectification/ 
                 product 
                 target product 
               
               
                 Number 
                 products/wt % 
                 wt % 
                 ΣPODE 2-6 /% 
                 ΣPODE 2-6 /% 
               
               
                   
               
             
          
           
               
                 Embodiment 4-1 
                 60.1 
                 0.01 
                 99.9 
                 99.8 
               
               
                 Embodiment 4-2 
                 60.1 
                 9.3 
                 ~46.0 
                 ~90.7 
               
               
                   
               
             
          
         
       
     
       Embodiment 5-1 
       [0065]    First, 50.4 g Raney-Cu catalyst is loaded into a 2 L pressurized slurry bed reactor of refining by hydrogenation; 
         [0066]    Then, an equilibrium system of 1260 g products containing polyoxymethylene diethyl ethers is refined by catalytic hydrogenation, the amount of Raney-Cu catalyst used is equal to 4 wt % of the overall reaction products to be refined, and the process conditions are: the hydrogen pressure is 4 Mpa, the reaction temperature of refining by the slurry bed (i.e. the reaction temperature of catalytic hydrogenation) is 100° C., and the reaction time is 4 hours; 
         [0067]    Finally, the formaldehyde contained is hydrogenated into methanol by the catalytic function of Raney-Cu, and the methanol generated constitutes a component of the equilibrium products, thereby no other foreign component is generated while removing formaldehyde. The constituents and distribution of the main products before and after refining by catalytic hydrogenation are shown in Table 6-1. 
         [0068]    The equilibrium system after refining is extracted, and the extraction process utilizes the atmospheric rectification technology, with tower plate number of 20˜50, gas temperature of 45˜65.0° C. at tower top, temperature of 110˜130° C. at tower bottom, feedstock temperature of 60˜90° C., and reflux ratio of 1.0˜3.0. After the extraction is finished, the testing result of extraction rate of the products is shown in Table 6-2. 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 6-1 
               
             
             
               
                   
               
               
                 constituents and distribution of the main products before 
               
               
                 and after refining by hydrogenation catalyzed by Raney-Cu catalyst 
               
             
          
           
               
                   
                 Constituents 
               
             
          
           
               
                   
                   
                   
                   
                   
                   
                 Conversion 
                   
               
               
                   
                 Butanol 
                 Formaldehyde 
                 Methanol 
                 PODE 1   
                 ΣPODE 2-6   
                 rate of 
                 Selectivity 
               
               
                 System 
                 wt % 
                 wt % 
                 wt % 
                 wt % 
                 wt % 
                 formaldehyde/% 
                 of catalyst/% 
               
               
                   
               
             
          
           
               
                 Before refining 
                 11.3 
                 4.5 
                 0 
                 27.6 
                 56.6 
                 — 
                 — 
               
               
                 by hydrogenation 
               
               
                 After refining 
                 11.3 
                 0.00 
                 4.5 
                 27.6 
                 56.6 
                 ~100 
                 ~100 
               
               
                 by hydrogenation 
               
               
                   
               
             
          
         
       
     
       Embodiment 5-2 
       [0069]    This embodiment is based on the same synthesis product system as in Embodiment 5-1, but the refining step as in Embodiment 5-1 is omitted, instead the overall equilibrium system after synthesis directly enters the extraction unit, and Embodiment 5-1 and Embodiment 5-2 utilize the same extraction means to extract the products with various degrees of polymerization. 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                 TABLE 6-2 
               
             
             
               
                   
               
               
                 extraction rate of the products 
               
             
          
           
               
                   
                 Constituents 
               
             
          
           
               
                   
                   
                 Formaldehyde 
                   
                   
               
               
                   
                 Content of 
                 content after 
                 Recovery ratio 
               
               
                   
                 ΣPODE 2-6  in the 
                 atmospheric 
                 of the target 
                 Purity of the 
               
               
                   
                 equilibrium 
                 rectification/ 
                 product 
                 target product 
               
               
                 Number 
                 products/wt % 
                 wt % 
                 ΣPODE 2-6 /% 
                 ΣPODE 2-6 /% 
               
               
                   
               
             
          
           
               
                 Embodiment 5-1 
                 56.6 
                 0.01 
                 ~99.9 
                 99.8 
               
               
                 Embodiment 5-2 
                 56.6 
                 7.8 
                 ~48.5 
                 ~92.2 
               
               
                   
               
             
          
         
       
     
       Embodiment 6-1 
       [0070]    First, 37.8 g Raney-Ni catalyst is loaded into a 2 L pressurized slurry bed reactor of refining by hydrogenation; 
         [0071]    Then, an equilibrium system of 1260 g products containing polyoxymethylene diethyl ethers is refined by catalytic hydrogenation, the amount of Raney-Ni catalyst used is equal to 3 wt % of the overall reaction products to be refined, and the process conditions are: the hydrogen pressure is 4 Mpa, the reaction temperature of refining by the slurry bed (i.e. the reaction temperature of catalytic hydrogenation) is 90° C., and the reaction time is 4.5 hours; 
         [0072]    Finally, the formaldehyde contained is hydrogenated into methanol by the catalytic function of Raney-Ni, and the methanol generated constitutes a component of the equilibrium products, thereby no other foreign component is generated while removing formaldehyde. The constituents and distribution of the main products before and after refining by catalytic hydrogenation are shown in Table 7-1. 
         [0073]    The equilibrium system after refining is extracted, and the extraction process utilizes the atmospheric rectification technology, with tower plate number of 20˜50, gas temperature of 45˜65.0° C. at tower top, temperature of 110˜130° C. at tower bottom, feedstock temperature of 60˜90° C., and reflux ratio of 1.0˜3.0. After the extraction is finished, the testing result of extraction rate of the products is shown in Table 7-2. 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 7-1 
               
             
             
               
                   
               
               
                 constituents and distribution of the main products before 
               
               
                 and after refining by hydrogenation catalyzed by Raney-Ni catalyst 
               
             
          
           
               
                   
                 Constituents 
               
             
          
           
               
                   
                   
                   
                   
                   
                   
                 Conversion 
                   
               
               
                   
                 Pentanol 
                 Formaldehyde 
                 Methanol 
                 PODE 1   
                 ΣPODE 2-6   
                 rate of 
                 Selectivity 
               
               
                 System 
                 wt % 
                 wt % 
                 wt % 
                 wt % 
                 wt % 
                 formaldehyde/% 
                 of catalyst/% 
               
               
                   
               
             
          
           
               
                 Before refining 
                 12.4 
                 7.2 
                 0 
                 34.1 
                 46.3 
                 — 
                 — 
               
               
                 by hydrogenation 
               
               
                 After refining 
                 12.4 
                 0.00 
                 7.19 
                 34.1 
                 46.3 
                 ~99.8 
                 ~100 
               
               
                 by hydrogenation 
               
               
                   
               
             
          
         
       
     
       Embodiment 6-2 
       [0074]    This embodiment is based on the same synthesis product system as in Embodiment 6-1, but the refining step as in Embodiment 6-1 is omitted, instead the overall equilibrium system after synthesis directly enters the extraction unit, and Embodiment 6-1 and Embodiment 6-2 utilize the same extraction means to extract the products with various degrees of polymerization. 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                 TABLE 7-2 
               
             
             
               
                   
               
               
                 extraction rate of the products 
               
             
          
           
               
                   
                 Constituents 
               
             
          
           
               
                   
                   
                 Formaldehyde 
                   
                   
               
               
                   
                 Content of 
                 content after 
                 Recovery 
               
               
                   
                 ΣPODE 2-6  in the 
                 atmospheric 
                 ratio of the 
                 Purity of the 
               
               
                   
                 equilibrium 
                 rectification/ 
                 target product 
                 target product 
               
               
                 Number 
                 products/wt % 
                 wt % 
                 ΣPODE 2-6 /% 
                 ΣPODE 2-6 /% 
               
               
                   
               
             
          
           
               
                 Embodiment 6-1 
                 46.3 
                 0.02 
                 99.9 
                 99.8 
               
               
                 Embodiment 6-2 
                 46.3 
                 6.2 
                 ~39.5 
                 ~93.8 
               
               
                   
               
             
          
         
       
     
         [0075]    It can be seen from the data of extraction in the foregoing embodiments that, in the equilibrium system obtained by the synthesis unit, if the formaldehyde contained is not specifically removed, then no matter how ideal the product distribution of the synthesis part is, it is always unable to obtain satisfactory products. However, the system that has been through the refining process by hydrogenation of the present invention only requires simple ordinary extraction operations to achieve extraction of products with various degrees of polymerization and to obtain the effects of satisfactory product yield and product purity. Therefore, as a step of the entire production process, the refining unit plays a crucial role in obtaining of the target products. More importantly, the technological process of the present invention for refining by catalytic hydrogenation using a slurry bed achieves an atom utilization ratio close to 100%, does not discharge any waste water or waste residue during the entire process, not only has satisfactory extraction results, but also is green and environmental as a whole, which has great practical significance. 
         [0076]    Obviously, the aforementioned embodiments are merely intended for clearly describing the examples, rather than limiting the implementation scope of the invention. For those skilled in the art, various changes and modifications in other different forms can be made on the basis of the aforementioned description. It is unnecessary and impossible to exhaustively list all the implementation ways herein. However, any obvious changes or modifications derived from the aforementioned description are intended to be embraced within the protection scope of the present invention.