Abstract:
A polyurethane encapsulated, slow release fertilizer with a coating based upon an isocyanate component and an isocyanate-reactive component comprising a polyether polyol. The process for producing such particles comprises applying an isocyanate-reactive component comprising a polyether polyol onto fertilizer particles to form coated fertilizer particles, applying an isocyanate component onto said coated fertilizer particles; and forming the polyurethane encapsulated fertilizer particles.

Description:
FIELD OF THE INVENTION 
     This invention relates to the art of fertilizer and, more particularly, to a coated granular fertilizer in which the dissolution rates of water-soluble fertilizer components are controlled by coating or encapsulating a granular fertilizer. 
     BACKGROUND OF THE INVENTION 
     Achieving crop fertilization by timing the release or application of fertilizer nutrients is known. Fertilization in the container-grown wholesale plant industry, for example, has been accomplished by methods including:
         Multiple applications of granular fertilizer   Overhead liquid application of soluble fertilizers   Incorporating slow release fertilizers into potting soil   Polymer coated fertilizers.       

     Each of these methods and compositions has associated drawbacks. A description of the drawbacks associated with prior art methods and compositions can be found in U.S. patent application Ser. No. 10/973,732, which is incorporated in its entirety herein. 
     Encapsulating fertilizers to slowly release nutrient to plants is known. Slow release fertilizers delay the dissolution of the fertilizer substrate. Most slow release fertilizers, however, are not dependable in adverse environmental conditions such as high heat and moisture. Hot and wet conditions can cause slow release fertilizers to flash release, causing damage to both the plant material and the environment. 
     Prior art methods include encapsulating a fertilizer having a given chemical composition or compound such that the nutrients are released over a period of time. For example, coated urea has been used as a source of time released nitrogen, which is a nutrient that promotes plant height and leaf formation in a plant. U.S. Pat. Nos. 5,147,442, 5,560,768 and 6,500,223 each of which is incorporated in its entirety, illustrate such coated fertilizers and methods associated with them. 
     Encapsulated slow-release fertilizers may be classified into two major groups according to the fertilizer release mechanism: 
     (i) A first group in which the release is governed by the rate of water permeation through a polymeric or copolymeric membrane of the water-proofing material, and by the rate of fertilizer diffusion away from each coated particle into the surrounding soil. Typical examples of membrane material in slow-release fertilizers of this group are copolymers or glyceryl esters of unsaturated acids with dicyclopentadiene (U.S. Pat. No. 3,223,518), epoxy-polyester resins (U.S. Pat. No. 3,259,482), urethanes (U.S. Pat. No. 3,264,089) and polystyrenes (U.S. Pat. No. 3,158,462). 
     (ii) A second group with relatively thick encapsulating coats, in which release is governed mainly by rupture of the coat, a typical example being particulate fertilizers with sulfur based encapsulation. The rupture occurs upon the permeation of water into the coated particles as a result of the osmotic pressure that builds up within. The sulfur based coating in slow-release fertilizers of this second group are generally produced by spraying onto the particulate fertilizer a molten sulfur based material as disclosed, for example, in U.S. Pat. No. 4,857,098. 
     Inefficient fertilization using past existing polymer coated fertilizers described at (i) and (ii) above increases costs and losses with respect to crops. In order to achieve the safe release of nutrient, current slow-release coated fertilizers must be relatively thickly coated, as measured by percentages of weight. Thicker coatings are necessarily more costly as result of, inter alia, the need for more coating materials. What is needed is an encapsulated slow-release fertilizer that can safely release nutrient to plants using coating that is more efficient. 
     SUMMARY OF THE INVENTION 
     The present invention provides a process for producing polyurethane encapsulated, slow-release fertilizer particles. The process comprises applying an isocyanate-reactive component that includes a polyether polyol onto fertilizer particles to form a coating on the fertilizer particles, and applying an isocyanate component onto said fertilizer particles. The applications of each component may be repeated so as to form the polyurethane encapsulated fertilizer particles comprising up to about nine percent of said coating by weight. 
     Another embodiment provides coated granular fertilizer comprising polyurethane encapsulated, slow release fertilizer particles comprising a coating of up to about six percent of said coating by weight, said wherein the coating releases nutrient from a nutrient substrate. The conditions for each of the nutrient release rates below are at 100 degrees Fahrenheit—(e.g.: nitrogen release at about 1,120 ppm at 100 degrees Fahrenheit). The nutrient substrate can include potassium nitrate in the percentages of 12-0-43 (N-P-K) at release rates comprising from about 1,120 ppm to about 35,000 ppm of nitrogen in about one day, from about 5,200 ppm to about 74,000 ppm of nitrogen in about three days, and from about 10,500 ppm to about 104,000 ppm of nitrogen in about seven days. The coated fertilizer also can release from about 1,000 ppm to about 15,000 ppm of potassium in about one day, from about 3,000 ppm to about 170,000 ppm of potassium in about three days, and from about 19,000 ppm to about 212,000 ppm of potassium in about seven days. 
     The nitrogen release of this coated fertilizer at about four percent of the coating is about 17,200 ppm of nitrogen in about one day, about 74,000 ppm of nitrogen in about three days, and about 104,000 ppm of nitrogen in about seven days. At about five percent of the coating by weight the coating releases nutrient at rates comprising about from about 14,600 ppm to about 35,000 ppm of nitrogen in about one day, from about 41,500 to about 58,000 ppm of nitrogen in about three days, and from about 58,000 to about 94,000 ppm of nitrogen at 100 degrees Fahrenheit in about seven days. Nitrogen release at about six percent of said coating by weight is from about 1,120 ppm to 12,400 ppm of nitrogen in about one day, from about 8,600 ppm to about 36,000 ppm of nitrogen in about three days, and from about 16,500 ppm to about 54,200 ppm of nitrogen in about seven days. When the coating is about eight percent by weight, nitrogen release rates comprise about 2,300 ppm in about one day; about 5,200 ppm in about three days; and about 10,500 ppm in about seven days. 
     As regards potassium release, when the coating of the granular fertilizer is about four percent of the coating by weight the coating releases potassium at rates comprising about 12,000 ppm of potassium in about one day, about 170,000 ppm of potassium in about three days, and from about 212,000 ppm of potassium in about seven days. At about five percent of the coating by weight, the release rates comprise from about 12,000 ppm to about 15,000 ppm of potassium in about one day, from about 45,000 ppm to about 120,000 ppm of potassium in about three days, and from about 110,000 ppm to about 184,000 ppm of potassium in about seven days. Potassium release rates at about six percent of the coating by weight comprise: from about 1,000 ppm to about 10,000 ppm of potassium in about one day, from about 3,000 ppm to about 90,000 ppm of potassium in about three days, and from about 19,000 ppm to about 105,000 ppm of potassium in about seven days. When the coating is about eight percent by weight, potassium release rates comprise about 1,000 ppm in about one day; about 4,000 ppm in about three days; and about 19,000 ppm in about seven days. 
     The polyurethane encapsulated, slow release fertilizer&#39;s coating can be based upon an isocyanate component and an isocyanate-reactive component comprising a polyether polyol. 
    
    
     
       DETAILED DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is an overall block flow diagram of the method of the invention. 
     
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     The coated granular fertilizer according to the invention can comprise a particulate fertilizer to be covered with a resin composition. The particulate fertilizer used in the present invention is not critical with respect to the type and may be any known chemical fertilizer. Examples of the fertilizer include ammonium sulfate, ammonium chloride, ammonium nitrate, urea, potassium chloride, potassium sulfate, potassium nitrate, sodium nitrate, ammonium phosphate, potassium phosphate, calcium phosphate, and composite fertilizers thereof. 
     The granular fertilizer is coated with a water-resistant film-forming polyurethane composition. The composition should comprise a isocyanate-reactive polyether polyol and an isocyanate component, and optionally, other polymers, waxes, inorganic and organic powders and surface active agents. The waxes used in the present invention may be any waxes provided that they are soluble in solvents for the essential polymers. Examples of such waxes include paraffin wax, hardened oils, bee wax, Japan wax, rosin, petroleum resins and the like. 
     The invention provides compositions and methods for delivering the proper nutrition to plants by the encapsulation of fertilizer particles. The term “fertilizer” as used herein denotes an at least moderately water-soluble chemical substance or mixture of such substances, and the term “particulate fertilizer” used herein denotes any type of comminuted fertilizer such as granulated, pelleted, or microgranulated and the like. Nutrient releases is described in terms of parts per million (ppm) at about plus (+) or minus 20% (−) of the ppm given (i.e. + or−1,000 ppm of potassium release).The following examples further illustrate details for the process of the present invention, and the preparation of the compositions of this invention. The invention, which is set forth in this disclosure, is not to be limited either in spirit or scope by these examples. Those skilled in the art will readily understand that known variations of the conditions and processes of the following preparative procedures can be used to prepare these compositions. Unless otherwise noted, all temperatures are degrees Celsius and all parts and percentages are parts by weight and percentages by weight, respectively. 
     EXAMPLES 
     Polyol: a polyether polyol obtained by adding propylene oxide to a glycerine nucleus. The polyol has a hydroxyl number of from about 388 to about 408, a nominal functionality of about 3; and a nominal molecular weight of about 400. Its density in lbs/gallon at 77 degrees Fahrenheit is about 8.75; at 100 degrees Fahrenheit is about 8.68 and at 120 degrees Fahrenheit is about 8.61. The polyol&#39;s viscosity is about 360 cps at 77 degrees Fahrenheit, about 160 cps at 100 degrees Fahrenheit, and about 78 cps at 120 degrees Fahrenheit. It has a specific heat of 0.5 BTU/lb Fahrenheit, and a thermal conductivity of 0.087 BTU/lb ft 2  Fahrenheit/in. An exemplary polyol is commercially available as BASF Plurocol GP430. 
     Isocyanate: A polymethylene polyphenylpolyisocyanate having a NCO content of about 31.5% by weight, a viscosity of about 200 cps, at about 25 degrees, a hydrolyzable chlorine of about 0.035% by weight, a flash point of about 200 degrees, density of about 1.23 g/cm 3  at about 25 degrees, an initial boiling point of about 190 mm Hg at about 25 degrees; and vapor pressure of about 0.0002 mm Hg at about 25 degrees. The isocyanate is a polymeric MDI with a functionality of about 2.7 An example is commercially available as BASF Lupranate M20S 
     Encapsulation of Fertilizer Pellets: 
     Among other things, compositions and methods of the present invention can provide proper nutrition to plants in the differing stages of plant growth. In a non-limiting example, semi-permeable resin membranes encapsulate particulate fertilizers. The membranes differ in porosity. The porosities are matched to the solubility of each specific nutrient to control the speed of release. During manufacturing, the thickness of the resin coating together with the choice of resin type coating membrane, creates the release criteria. The fertilizer substrate releases by timed osmosis back through release channels of the semi-permeable membrane, providing the corresponding nutrient to the crop. By matching each nutrient to a given porosity of the membranes, as well as adjusting resin thickness, the process individually controls the time release of each nutrient such at least one plant receives the appropriate fertilizer nutrient at the differing stages of the a plant&#39;s growth. A description of proper nutrition in a plant in the differing stages of plant growth as well as exemplary methods and compositions for providing such nutrition can be found in U.S. patent application Ser. No. 10/973,732, incorporated herein. 
       FIG. 1  is an overall block flow diagram of the method of the invention. The method begins by introducing the fertilizer particles into a rotary blender  100 . In one example, 50 lbs of substrate potassium nitrate is introduced into the blender. The substrate is then heated 110 to approximately 60 degrees for time sufficient to drive all moisture out of the material. 
     An isocyanate-reactive polyether polyol is applied onto the fertilizer particles to form a coating on said fertilizer particles  120 . For example, two ounces of the polyol component (Plurocol) can be added to the substrate. No pressure is used, and the material is slowly poured onto the substrate while the rotary blender is in operation. The relatively low viscosity of the polyol allows rapid and even coverage of all the substrate particles. Next, the isocyanate component is applied to the fertilizer  130 . In the example, after 2 minutes of blending, the isocyanate (Lupranate) binder is introduced, again by simply pouring it into the agitating material. Complete reaction can occur within about 6 to 7 minutes without any clumping of the processed substrate at any time during the reaction. This process can then be repeated  140 , without increasing the rate of application. Modifications may include pre-sealing the substrate material with vegetable oil or polyethylene, and/or using an outer layer of wax or polyethylene to extend release time. Analysis of these examples made via the method are shown in Table 1. 
     In another example, five (5) batches of polyurethane encapsulated fertilizer are made using following procedure. A potassium nitrate substrate of 13.5-0-45 (N-P-K) is heated about 225 degrees F., with the temperature kept constant a plus or minus 15 degrees throughout process. A fine granular matter, such as ionized iron oxide pigment, may then be added at 0.5% to the heated substrate. Then 0.5% canola oil may be added. This seals imperfections in the individual prills, allowing the polymers to form completely around each prill. The use of the vegetable oil (e.g. canola) in this process eliminates premature or “flash release” of nutrients, which can cause burn to plants. The addition of iron oxide is also coloring process, giving the prills a brownish red color. Pluracol is then added at 0.75% and allowed to mix thoroughly. Then 0.75% of the lupranate is added. Reaction time is complete in 7-8 minutes at the heated temperature, and the momentary clumping does not occur at this temperature. This process may then be repeated 3 more times, with each addition of polymer weighed carefully, so the final product has 6 lbs of polymer reacted. By calculated weight, the polymer coating is 6/107lbs., or 5.6%. (With respect to the polymer coated potassium nitrate, the percentages of 12-0-43, as used herein, are shown using this example. Beginning with 100 lbs of 13.5-0-45, then the final analysis would be 100/107 ×13.5-0-45, which is 12.6-0-42.05. Primary nutrients (N-P-K) are expressed as whole numbers, so the percentages are expressed as 12-0-42.) Analysis of these examples is shown in Table 3. Analysis: 
     Using this process, one set of samples of the polyurethane encapsulated fertilizer particles beginning with the initial coating of about 0.5% up to about 6% coating by weight were retained. Beginning with the coating at about the 3% level, after 12 days in room temperature water, prill failure rate was less than 3% of the prills, going down to the 6% coating, which exhibited two (2) prills which became soft and floated up after stirring the sample of 2 tbsp in 6 oz of water. The samples&#39; demonstrated resistance to prill failure shows that the coated fertilizer is not subject to unsafe flash release. 
     Samples of polyurethane encapsulated fertilizer particles with the 3%, 4%, 5% and 6% coatings were compared to 2 month (H 2 ), 4 month (H 4 ), and 8 to 9 (P 8 ) month coated time released potassium nitrate commercially available from Haifa and Pursell. All of the compared coated fertilizers included time released potassium nitrate at the percentages of 12-0-43 (N-P-K) as the fertilizer substrate. The results of the comparison of the exemplary polyurethane encapsulated fertilizer particles of the present invention at 4% (A 4 ), 5% (A 5 ) and 6% (A 6 ) levels of coating are shown below in Table 1. 
     With respect to the 2 to 3 month Haifa product (H 2 ) vs. the A 4  sample, the A 4  demonstrated tighter release at day one. All nutrient release was trialed at 100 degrees Fahrenheit. As shown in Table 1 below, A 4  released Nitrogen at 17,200 parts per million (ppm) versus H 2 &#39;s Nitrogen release at 36,200 ppm; A 4 &#39;s potassium release was 12,000 ppm versus H 2 &#39;s 90,000 ppm. This indicates that the A 4  can perform very well even at about a 3.5% level of coating. A 4  showed to be still tighter than H 2  at the 7 day level, since A 4  released Nitrogen at 104,000 ppm versus H 2 &#39;s Nitrogen release at 111,600 ppm and A 4 &#39;s potassium release of 212,000 ppm versus H 2 &#39;s 224,000 ppm. 
     When compared to the 4 to 5 month Haifa product (H 4 ), the A 5  sample was so much tighter that a coating of up to from about 4% to about 4.5% could safely be used over the same time period as the H 4  product. 
     As regards the A 6  sample when compared to the 8 to 9 month Polyon (P 8 ), the A 6  sample demonstrated comparable results through the 3 and 7 day results, although the A 6  more slowly released nutrient. The slower release of nutrient indicates that there may be up to thirty days longevity in field performance. 
     The results in Table 1 below show that the encapsulated fertilizer particles of the present invention have tighter upfront release of nutrient, which demonstrates complete safety to plants. The comparative results are set forth in Table 1 below. It is seen that the conductivity values, the measurement of low soluble salts, go down with each additional layer of polymer, indicating that release longevity can be controlled by amount of polymer added. Also, the encapsulated fertilizer particles when placed in water for 3 weeks showed no susceptibility to flash release. 
     
       
         
               
               
             
               
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                   
                 TABLE 1 
               
             
             
               
                   
                   
               
               
                   
                 NUTRIENT RELEASE AT 100° F. 
               
             
          
           
               
                 SAMPLE ID 
                 PARAMETER 
                 UNIT 
                 DAY 1 
                 DAY 3 
                 DAY 7 
               
               
                   
               
             
          
           
               
                 A4 12-0-43 
                 Nitrogen 
                 ppm 
                 17,200 
                 74,000 
                 104,000 
               
               
                   
                 Potassium 
                 ppm 
                 12,000 
                 170,000 
                 212,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 92.00 
                 658.00 
                 900.00 
               
               
                 A5 12-0-43 
                 Nitrogen 
                 ppm 
                 14,600 
                 58,000 
                 94,400 
               
               
                   
                 Potassium 
                 ppm 
                 12,000 
                 120,000 
                 184,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 102.00 
                 520.00 
                 740.00 
               
               
                 A6 12-0-43 
                 Nitrogen 
                 ppm 
                 12,400 
                 36,000 
                 54,200 
               
               
                   
                 Potassium 
                 ppm 
                 10,000 
                 90,000 
                 114,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 60.00 
                 248.00 
                 452.00 
               
               
                 H2 12-0-43 
                 Nitrogen 
                 ppm 
                 36,200 
                 98,000 
                 111,600 
               
               
                   
                 Potassium 
                 ppm 
                 90,000 
                 206,000 
                 224,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 682.00 
                 874.00 
                 960.00 
               
               
                 H4 12-0-43 
                 Nitrogen 
                 ppm 
                 34,000 
                 74,000 
                 84,600 
               
               
                   
                 Potassium 
                 ppm 
                 70,000 
                 176,000 
                 192,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 504.00 
                 700.00 
                 818.00 
               
               
                 P8 12-0-43 
                 Nitrogen 
                 ppm 
                 13,800 
                 38,000 
                 56,800 
               
               
                   
                 Potassium 
                 ppm 
                 20,000 
                 82,000 
                 118,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 148.00 
                 342.00 
                 486.00 
               
               
                   
               
             
          
         
       
     
     The results in Table 2 below show that the encapsulated fertilizer particles of the present invention have tighter upfront release of nutrient, which demonstrates complete safety to plants. In the examples set forth, the coating was up to about eight to nine percent. The coating percentages are listed in the table. Among other things, these exemplary results indicate that a coating of 6% can be designed to release over 9 months. 
     
       
         
               
               
             
               
               
             
               
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                   
                 TABLE 2 
               
               
                   
                   
               
             
             
               
                   
                 NUTRIENT RELEASE AT 
               
             
          
           
               
                 SAMPLE 
                 100° F. 
               
             
          
           
               
                 ID 
                 PARAMETER 
                 UNIT 
                 DAY 1 
                 DAY 3 
                 DAY 7 
               
               
                   
               
               
                 Fertilizer A - 11-8 
                 Nitrogen 
                 ppm 
                 5,600 
                 7,400 
                 11,600 
               
               
                 (At about 8%) 
                 Potassium 
                 ppm 
                 2,000 
                 3,000 
                 23,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 14.00 
                 20.00 
                 120.00 
               
               
                 Fertilizer A - 11-9 
                 Nitrogen 
                 ppm 
                 6,600 
                 7,600 
                 12,000 
               
               
                 (At about 9%) 
                 Potassium 
                 ppm 
                 3,000 
                 4,000 
                 184,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 19.00 
                 27.00 
                 110.00 
               
               
                 Fertilizer A - 15-4 
                 Nitrogen 
                 ppm 
                 35,000 
                 41,500 
                 58,000 
               
               
                 (At about 5%) 
                 Potassium 
                 ppm 
                 15,000 
                 45,000 
                 110,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 96.00 
                 226.00 
                 596.00 
               
               
                 Fertilizer A - 15-6 
                 Nitrogen 
                 ppm 
                 5,600 
                 8,600 
                 16,500 
               
               
                 About 6%) 
                 Potassium 
                 ppm 
                 1,000 
                 3,000 
                 56,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 4.00 
                 23.00 
                 232.00 
               
               
                 Fertilizer A - 15-8 
                 Nitrogen 
                 ppm 
                 2,300 
                 5,200 
                 10,500 
               
               
                 (About 8%) 
                 Potassium 
                 ppm 
                 1,000 
                 4,000 
                 19,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 10.00 
                 30.00 
                 111.00 
               
               
                   
               
             
          
           
               
                   
                 SAMPLE 
                   
                   
                   
                   
               
               
                   
                 ID 
                 PARAMETER 
                 UNIT 
                 Result 
                 Detection Limit 
               
               
                   
                   
               
               
                   
                 Fertilizer A - 15-8 
                 Total Nitrogen 
                 % 
                 13.06 
                 0.10 
               
               
                   
                   
                 (N) 
               
               
                   
                   
                 Soluble Potash 
                 % 
                 40.01 
                 0.01 
               
               
                   
                   
                 (K2O) 
               
               
                   
                   
                 Iron (Fe) 
                 % 
                 0.16 
                 0.01 
               
               
                   
                   
               
             
          
         
       
     
     The following results shown in Table 3, which all include example of 12-0-43 potassium nitrate at 6% coating by weight, also demonstrate examples of the consistency of fertilizer release at 100 degrees in water bath for and through 7 days. When placed in water at room temperature for 6 days, there was no prill failure. Samples of the products were sent to lab for accelerated release tests on 6 pound polymer levels. Tests done on products when the isocyanate-reactive polyether polyol and isocyanate component were added at 2% per layer showed tendency to agglomerate and lose coating to blender surface, so 1.5% maximum has been adopted. The results in Table 3 below also show that the encapsulated fertilizer particles of the present invention have tighter upfront release of nutrient, which demonstrates complete safety to plants. The measurement of low soluble salts in these results confirm the stability of coating at accelerated temperatures. 
     
       
         
               
               
             
               
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                 TABLE 3 
               
             
             
               
                   
               
               
                   
                 NUTRIENT RELEASE AT 
               
               
                 SAMPLE 
                 100° F. 
               
             
          
           
               
                 ID 
                 PARAMETER 
                 UNIT 
                 DAY 1 
                 DAY 3 
                 DAY 7 
               
               
                   
               
             
          
           
               
                 05001 - Fertilizer 
                 Nitrogen 
                 ppm 
                 1,490 
                 10,000 
                 27,700 
               
               
                 12-0-43 
                 Potassium 
                 ppm 
                 1,300 
                 12,000 
                 71,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 18.00 
                 134.00 
                 388.00 
               
               
                 05002 - Fertilizer 
                 Nitrogen 
                 ppm 
                 1,760 
                 11,000 
                 23,700 
               
               
                 12-0-43 
                 Potassium 
                 ppm 
                 2,200 
                 16,000 
                 79,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 23.00 
                 148.00 
                 413.00 
               
               
                 05003 - Fertilizer 
                 Nitrogen 
                 ppm 
                 1,480 
                 10,200 
                 26,900 
               
               
                 12-0-43 
                 Potassium 
                 ppm 
                 1,200 
                 13,000 
                 96,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 15.00 
                 130.00 
                 420.00 
               
               
                 05004 - Fertilizer 
                 Nitrogen 
                 ppm 
                 1,260 
                 11,600 
                 27,700 
               
               
                 12-0-43 
                 Potassium 
                 ppm 
                 1,000 
                 14,000 
                 93,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 13.00 
                 136.00 
                 430.00 
               
               
                 05005 - Fertilizer 
                 Nitrogen 
                 ppm 
                 1,120 
                 10,600 
                 28,200 
               
               
                 12-0-43 
                 Potassium 
                 ppm 
                 900 
                 19,000 
                 104,000 
               
               
                   
                 Conductivity 
                 mmhos/cm 
                 12.00 
                 151.00 
                 454.00 
               
               
                 05006 - Fertilizer 
                 Nitrogen 
                 ppm 
                 1,380 
                 11,300 
                 25,900 
               
               
                 12-0-43 
                 Potassium 
                 ppm 
                 1,300 
                 21,000 
                 105,000 
               
               
                 Polymer Coated 
                 Conductivity 
                 mmhos/cm 
                 15.00 
                 153.00 
                 448.00 
               
               
                   
               
             
          
         
       
     
     It should be understood that the above description is only representative of illustrative embodiments and examples. For the convenience of the reader, the above description has focused on a limited number of representative examples of all possible embodiments, examples that teach the principles of the invention. The description has not attempted to exhaustively enumerate all possible variations or even combinations of those variations described. That alternate embodiments may not have been presented for a specific portion of the invention, or that further undescribed alternate embodiments may be available for a portion, is not to be considered a disclaimer of those alternate embodiments. One of ordinary skill will appreciate that many of those undescribed embodiments, involve differences in technology and materials rather than differences in the application of the principles of the invention. Accordingly, the invention is not intended to be limited to less than the scope set forth in the following claims and equivalents.