Abstract:
The composition of and method of manufacturing and using a composite absorption material for solidifying a waste stream from oil and gas industry drilling operations. The waste stream has a liquid component and is solidified prior to transportation to a landfill. The absorption material is a pelletized composite blend of agricultural fibers and a superabsorbent polymer that has been specifically proportioned to solidify liquids in the waste stream for transport and disposal.

Description:
CROSS-REFERENCE TO RELATED APPLICATION 
       [0001]    This application claims the benefit under 35 U.S.C. 119 §(e) of the earlier filing date of U.S. Provisional Patent Application No. 62/037,314, filed on Jul. 22, 2014, the entire contents of which are incorporated herein by reference. 
     
    
     BACKGROUND 
       [0002]    The present disclosure relates to the composition of and method of manufacturing, a composite absorption material comprising a blend of organic, repurposed and agricultural fibers that have been specifically proportioned and blended to quickly solidify liquids in waste streams for transport and disposal. 
         [0003]    The absorption material disclosed herein was specifically developed for the purpose of waste stream solidification resulting from drill cuttings from oil and gas industry drilling operations. Waste streams from such operations contain liquids at a level unacceptable fix disposal at landfill sites so there exists a need for a material or method of solidifying the liquid in the waste streams so that landfills will accept the waste. There is a need to have the liquid in the waste remain solidified as the waste is being transported to the landfill. The vibration during transport can cause drill cutting waste that has been treated with other materials or methods to partially desolidify so that the waste is not accepted by landfills when it reaches the site and must he resolidified. The absorption material disclosed herein fulfill these needs. The absorption material can also be used for applications other than oil and gas production  industry, including dredging operations, land fill operations, pipeline and road boring operations and other operations, where liquids need to be solidified in the waste stream or by products of such operations. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0004]    Various embodiments of the invention are described herein in by was of example in conjunction with the following figures, wherein like reference characters designate the same or similar elements. 
           [0005]      FIG. 1 a    shows the pellets prior to being run through a crumbling process. 
           [0006]      FIG. 1 b    shows the crumbles or crumbled pelletized absorption material resulting from running the pellets through a crumbling process that breaks the pellets into a variety of sizes of crumbles. 
           [0007]      FIG. 2  shows a comparison of the crumbled pellets in a container (on the left) to the crumbled pellets after liquid is added to the container and then solidified due to the action of the crumbled pellets (on the right). 
           [0008]      FIG. 3  shows the crumbled pellets mixed with drill cuttings 
           [0009]      FIG. 4  shows the crumbled pellets being mixed with a waste stream of drill cuttings at a well site. 
           [0010]      FIG. 5  shows the crumbled pellets in sacks ready for shipment. 
       
    
    
     DETAILED DESCRIPTION 
       [0011]    It is to be understood that at least some of the figures and descriptions of the invention have been simplified to illustrate elements that are relevant for a clear understanding of the invention, while eliminating, for purposes of clarity, other elements that those of ordinary skill in the art will appreciate may also comprise a portion of the invention. However, because such elements are well known in the art, and because they do not facilitate a better understanding of the invention, a description of such elements is not provided herein. 
         [0012]    The composite absorption material  10  disclosed herein is composed of any form of agricultural fibers, including agricultural fibers such as hard wood, soft wood, oat hulls, corn cob, peanut hulls, and grasses, blended with superabsorbent polymers. The superabsorbent polymers can be composed of sodium polyacrylate. The superabsorbent polymers can also be composed of sodium polyacrylamide. The blended ratio used in the absorption material described herein can be between approximately 80% and 98% agriculture fibers by weight and 20% and 2% superabsorbent polymers by weight, respectively. For example, the absorption material  10  disclosed herein can be composed of about 95% by weight hard wood agricultural fiber and 5% by weight sodium polyacrylate superabsorbent polymer. 
         [0013]    The absorption material  10  described herein is made into pellets  12  using a large scale, commercial pellet mill where superabsorbent polymer is introduced to the fibers prior to pelletizing by the pellet mill. The superabsorbent polymer is therefore integrated into the fibers as the fibers are compressed into pellets  12 . In one embodiment ( FIG. 1 a   ), the pellets  12  are approximately 0.25 inch diameter by 1 inch long (6 mm by 25 mm) although larger or smaller pellets can be used. Due to the intense compression of pellets  12  leaving the mill, and customers desiring a product that performs immediately, the pellets are run through a crumbling process that breaks the pellets  12  into a variety of sizes of crumbles  14  ( FIG. 1 b   ), the smaller of which work immediately once introduced to a liquid, and the larger crumbles working somewhat slower as the liquid causes them to lose compression and unravel into smaller crumbles. The crumbles or crumbled pellets  14  formed from running pellets  12  through the crumbling process can range in size from a powder consistency to approximately 0.25 inch diameter by 0.75 inch long (6 mm by 18 mm) although larger size crumbles  14  are possible and can be acceptable. 
         [0014]    The pellets  12 , preferably in the form of crumbles  14 , are mixed in with the waste stream  18  containing liquids. Typically, the crumbled pellets  14  are mixed into the waste stream at approximately 5% to 20% of the weight of the waste stream  18 , depending on the make-up of the waste stream  18 . Typically, the absorption material is added to the waste stream in an amount not exceeding approximately 20% of the weight of the waste stream  18 . The crumbled pellets  14  are typically mixed with the waste stream  18  in a contained area or container  20  such as the hopper or a transportable container or mixing bin then loaded onto a truck in which the waste is being transported in to a disposal site. The crumbled pellets  14  act to solidify the liquid in the waste stream  18  as it is being transported such that the dump site will accept the solidified waste stream if it passes the paint filter test. 
         [0015]    Referring to the figures,  FIG. 1 a    shows the pellets  12  prior to being crumbled and  FIG. 1 b    shows the crumbled pellets  14  resulting from running the pellets  12  through the crumbling process that breaks the pellets  12  into a variety of sizes of crumbles  14 .  FIG. 2  shows a comparison of crumbled pellets  14  in a container (on the left) to crumbled pellets that have absorbed liquid  16  after liquid is added to the container and then solidified due to the action of the crumbled pellets on the right).  FIG. 3  shows drill cuttings  22  that may contain liquid waste  18  (on the left) and the mixture  24  of crumbled pellets  14  and drill cuttings  20  that may contain liquid waste  18  after any liquid waste  18  has been absorbed by the crumbled pellets  14  (on the right).  FIG. 4  shows the resulting mixture  24  of crumbled pellets  14  mixed with a waste stream comprising liquid waste  18  and solid drill cuttings  22  in a container  20  at a well site on the right a waste stream comprising liquid waste  18  and drill cuttings  22  in a container  20  at a well site on the left prior to introduction of the crumbled pellets  14 .  FIG. 5  shows crumbled pellets  14  are stored in large sacks  16  for shipment. 
         [0016]    The pellets  12  disclosed herein enjoy a substantial advantage over other liquid absorbing pellets and products in terms of performance as measured by a percentage of such pellets and products and by permanent solidification of the liquids in the waste stream. These other pellets and products typically consist of fly ash, sawdust, kiln dust, quick-time, corn cobs and wood pellets, and require, at minimum, a 50% ratio of pellets to waste stream by weight. The pellets described herein are capable of absorbing up to approximately 5 times their weight of liquid, typically within minutes, and are non-selective in performance as to the liquids and waste products on which they are used. Moreover, waste that is solidified using the pellets  12  disclosed herein remains solidified whereas the solidification of waste solidified with other available agents breaks down during transport, under pressure and over time, releasing the liquids that were to have remained solidified. 
         [0017]    The above description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles described herein can be applied to other embodiments without departing from the spirit or scope of the invention. Thus, it is to be understood that the description and drawings presented herein represent a presently preferred embodiment of the invention and are therefore representative of the subject matter which is broadly contemplated by the present invention. It is further understood that the scope of the present invention fully encompasses other embodiments that may become obvious to those skilled in the art and that the scope of the present invention is accordingly limited by nothing other than the appended claims.