Abstract:
A method includes providing a substrate with a patterned second layer over a first layer. The second layer includes a second layer opening having a first CD equal to the CD produced by a lithographic system (CD L ). CD L  is larger than a desired CD (CD D ). A third layer is formed to fill the opening, leaving a top surface of the second layer exposed. The second layer is removed to produce a mesa formed by the third layer. The CD of the mesa is equal to about the first CD. The mesa is trimmed to produce a mesa with a second CD equal to about CD D . A fourth layer is formed to cover the first layer, leaving a top of the mesa exposed. The substrate is etched to remove the mesa and a portion of the first layer below the mesa to form an opening in the first layer with CD D .

Description:
CROSS-REFERENCE TO RELATED APPLICATION 
       [0001]    This application is a divisional application which claims benefit of copending U.S. patent application Ser. No. 13/655,408, filed Oct. 18, 2012, which is herein incorporated by reference for all purposes. 
     
    
     BACKGROUND OF THE INVENTION 
       [0002]    The fabrication of integrated circuits (ICs) involves the formation of features on a substrate that make up circuit components, such as transistors, resistors and capacitors. The various features of circuit components are formed using optical lithography. Optical lithography involves transferring a pattern of a reticle onto a substrate. For example, an exposure source exposes a photoresist layer through the mask, which is developed to replicate the pattern on the mask. The substrate is then etched to create features on the substrate unprotected by the mask, transferring the pattern of the reticle onto the substrate. 
         [0003]    Due to lithography processing limitations, however, it is sometimes difficult to create openings with the desired dimension or desired critical dimension (CD D ). For example, in the case of forming contact openings in a dielectric layer, the CD of the contact openings may be larger than desired or required by design requirements. 
         [0004]    A conventional technique for forming contact openings having CD D  is to employ a polymerizing etch. For example, a photoresist  397  is patterned with an opening  398  having an initial CD (CD I ), as shown in  FIG. 3 . The initial CD, for example, corresponds to the CD created by the lithographic system (CD L ). The photoresist is used as an etch mask to etch the contact opening in a dielectric layer  360  on a substrate  301 . By employing a polymerizing etch, polymer  392  deposits on sidewall  388  of the opening as the dielectric layer is etched. The polymer acts as an etch mask lining the sidewall. As the etch continues, more and more polymer is deposited, reducing the size of the opening. The polymerizing etch results in an opening with a tapered sidewall. The bottom of the opening has a final CD (CD F ) which is smaller than CD I  or CD L . 
         [0005]    However, such a process is difficult to control and has a narrow process margin. Insufficient polymer deposition results in an opening having a CD F  which is larger than CD D , which can lead to shorting or leakage problems. On the other hand, too much polymer being deposited results in an opening having a CD F  which is smaller than CD D . This may lead to incomplete filling causing high resistance or opens in the contact. In either case, reliability or functionality of the IC is negatively impacted. 
         [0006]    From the foregoing discussion, it is desirable to provide improved CD control of contact openings or other features. 
       SUMMARY OF THE INVENTION 
       [0007]    A method of forming a feature is presented. The method includes providing a substrate with a first layer with a patterned second layer over the first layer. The patterned second layer includes a second layer opening having a first critical dimension (CD) which is equal to the CD produced by a lithographic system (CD L ). CD L  is larger than a desired CD (CD D ). A third layer is formed over the substrate. The third layer fills the opening and leaves a top surface of the second layer exposed. The second layer is removed to produce a mesa formed by the third layer. The CD of the mesa is equal to about the first CD. The mesa is trimmed to produce a mesa with a second CD. The second CD is equal to about CD D . A fourth layer is formed on the substrate to cover the first layer, leaving a top of the mesa exposed. The substrate is etched to remove the mesa and a portion of the first layer below the mesa to form an opening in the first layer with CD D . 
         [0008]    In another embodiment, a device is disclosed. The device includes a substrate and a first layer on the substrate. An opening is in the first layer. The opening has a dimension equal to a desired CD (CD D ) which is smaller than a CD produced by a lithographic system (CD L ) used in forming the device, and a sidewall of the opening is substantially devoid of polymer deposits and is substantially vertical. 
         [0009]    In yet another embodiment, a method of forming a device is presented. The method includes providing a substrate and forming a first layer on the substrate. An opening is formed in the first layer. The opening has a dimension equal to a desired CD (CD D ) which is smaller than a CD produced by a lithographic system (CD L ) used in forming the device, and a sidewall of the opening is substantially devoid of polymer deposits and is substantially vertical. 
         [0010]    These and other objects, along with advantages and features of the present invention herein disclosed, will become apparent through reference to the following description and the accompany drawings. Furthermore, it is to be understood that the features of the various embodiments described herein are not mutually exclusive and can exist in various combinations and permutations. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0011]    In the drawings, like reference characters generally refer to the same parts throughout the different views. Also, the drawings are not necessarily to scale, emphasis instead generally being placed upon illustrating the principles of the invention. In the following description, various embodiments of the present invention are described with reference to the following drawings, in which: 
           [0012]      FIG. 1  shows a cross-sectional view of an embodiment of a portion of a device; 
           [0013]      FIGS. 2   a - 2   j  show a process for forming an embodiment of a portion of a device; and 
           [0014]      FIG. 3  shows a cross-sectional view of a contact opening formed using a polymerizing etch process. 
       
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
       [0015]    Embodiments generally relate to devices, for example, semiconductor devices or integrated circuits (ICs). More particularly, the embodiments relate to features which have a desired CD (CD D ) according to design requirements of the device. The desired or design CD is smaller than the CD provided by the lithographic system (CD L ). In one embodiment, a feature, for example, is an opening. In one embodiment, the feature is a contact or via opening in which a contact is formed. Other types of features having CD D  may also be useful. The ICs can be any type of IC, such as dynamic or static random access memories, signal processors, microcontrollers or system-on-chip (SoC) devices. The devices or ICs can be incorporated into or used with, for example, consumer electronic products, such as computers, cell phones, and personal digital assistants (PDAs). 
         [0016]      FIG. 1  shows a cross-sectional view of a portion of an embodiment of a device  100 . The device, for example, is an IC. Other types of devices may also be useful. As shown, the portion includes a substrate  101 . In one embodiment, the substrate is a semiconductor substrate. For example, the substrate may be a silicon substrate. In some embodiments, the substrate may be a lightly doped substrate, such as a lightly doped p-type substrate. Other types of substrates may also be useful. Such substrates may include silicon germanium, gallium arsenide, germanium or semiconductor-on-insulator, such a silicon-on-insulator (SOI), substrates. The substrate may also be undoped or doped with other types of dopants or dopant concentrations. The substrate may include circuit components such as transistors, capacitors or resistors formed thereon with contact regions. Other types of circuit components are also useful. Generally, the substrate includes numerous circuit components and contact regions. 
         [0017]    The substrate is prepared with one or more contact regions. The contact regions may be source/drain (S/D) regions and gates of transistors. Other types of contact regions, such as junction contact regions, may also be useful. 
         [0018]    As shown, the substrate is prepared with transistors  110   a - b.  A transistor includes a gate  114  with S/D diffusion regions adjacent to first and second sides of the gate. Adjacent transistors may be configured to share an S/D common diffusion region  115 . Other configurations of transistors may also be useful. For example, the transistors may have non-common S/D diffusion regions. The gate can be formed as gate conductors. A gate conductor may serve as a common gate for a plurality of transistors. In some cases, the gate conductor may serve as a wordline of a memory array. Forming individual gates is also useful. Other configurations of gates may also be useful. Dielectric spacers  118  may be provided on the gate sidewalls. The spacers may be used to facilitate forming lightly doped S/D (LDD) regions (not shown). 
         [0019]    Isolation regions (not shown) can also be provided to isolate transistors for other transistors or circuit components. For example, an isolation device may surround a transistor region on which a transistor is formed. In other cases, multiple transistors, such as those which share a common S/D region, may be surrounded by an isolation region. Other configurations of isolation regions and transistors or circuit components may also be useful. Furthermore, it is understood that transistors are shown for illustrative purposes and that the substrate can also be prepared with other types or arrangements of circuit components. 
         [0020]    A first layer is disposed on the substrate, covering the contact regions. For example, the first layer is disposed on the substrate, covering the transistors as well as other types of contact regions. The first layer  160 , for example, is formed of a dielectric material. The first layer, for example, may serve as a pre-metal dielectric (PMD) layer. Other types of first layers may also be useful. For example, the first lay may be an inter-level dielectric (ILD) layer or an inter-metal dielectric (IMD) layer. The dielectric layer, for example, may be silicon oxide. Other types of dielectric materials including doped silicon oxide such as fluorinated silicon oxide (FSG), undoped or doped silicate glasses such as boron phosphate silicate glass (BPSG) and phosphate silicate glass (PSG), spin-on glass (SOG), undoped or doped thermally grown silicon oxide, undoped or doped TEOS deposited silicon oxide, and other low-k or ultra low-k dielectric materials can also be used to form the PMD layer. In one embodiment, the first layer is about 200 nm thick. Preferably, the thickness of the first layer is in the range of about 100-300 nm. Other thicknesses are also useful, for example, depending on the desired height of the contacts to interconnecting lines. 
         [0021]    Features  185  are formed in the dielectric layer. In one embodiment, the features are contact openings in communication with the contact regions below the dielectric. For example, the contact openings are in communication with S/D regions and gates of the transistors. Conductive contacts  198  are disposed in the contact openings. The contacts, for example, may be formed of tungsten (W). Contacts formed of other conductive materials, such as copper, aluminum, or conductive alloys, may also be useful. The contacts, for example, provide electrical connections between the contact regions below and interconnects disposed over the first layer. 
         [0022]    In one embodiment, a hard mask layer  195  is disposed on the first layer. The hard mask layer, for example, is formed of a material to which the first layer can be etched selectively. In one embodiment, the hard mask layer is formed of a dielectric material. For example, the hard mask layer may be formed of silicon nitride. Other types of hard mask materials may also be useful. As shown, the hard mask layer has a top surface which is coplanar with the top surface of the contacts. In other embodiments, the hard mask layer may be removed. Other configurations of contacts, contact regions and interconnects, may also be useful. 
         [0023]    The CD of the contact openings is equal to about the CD D . In one embodiment, CD I  of the opening at the top is equal to about CD D . In other words, CD I  is smaller than CD L . Since CD I  is equal to about CD D , a polymerizing etch to form the opening is not needed. By avoiding a polymerizing etch, the sidewalls of the contact openings are devoid or substantially devoid of polymer deposits and are vertical or substantially vertical (e.g., the vertical direction is perpendicular to the substrate surface). For example, the sidewalls of the contact openings may form an angle of about 0-0.5° with the vertical direction. In one embodiment, CD I  is equal to or substantially equal to about CD F  at the bottom of the opening and both are equal to about CD D . 
         [0024]    As shown, the hard mask remains on the surface of the dielectric layer. For example, the top of the hard mask and top of the contacts are coplanar. In other embodiments, the hard mask may be removed. For example, the hard mask may be removed by a polishing process, such as chemical mechanical polishing (CMP). The polishing process forms a coplanar surface with the top of the contacts and top of the dielectric layer. 
         [0025]      FIGS. 2   a - j  show cross-sectional views of an embodiment of a process  200  for forming a device. The device, for example, is an IC. Other types of devices may also be useful. Referring to  FIG. 2   a , a portion of the device is shown. The device is formed on a substrate  101 . The substrate  101  may be, for example, a semiconductor substrate. The semiconductor substrate may be a lightly doped p-type silicon substrate. Other types of substrates, such as a germanium-based, gallium arsenide, silicon-on-insulator (SOI), or sapphire substrate, are also useful. 
         [0026]    The substrate, as shown, is prepared with transistors  110   a - b.  A transistor includes a gate  114  disposed on the substrate. A gate, for example, includes an electrode over a gate dielectric layer (not shown). Dielectric spacers  118  may be provided on first and second gate sidewalls. The substrate may include S/D diffusion regions adjacent to the first and second gate sidewalls. The gate and S/D diffusion regions may serve as electrodes for a transistor. The transistors, for example, may share a common S/D region  115 . Other configurations of transistors may also be useful. Isolation regions (not shown) can also be provided to isolate transistors for other circuit components. Other configurations of isolation regions and transistors may also be useful. 
         [0027]    In one embodiment, a first layer  160  is formed on the substrate. In one embodiment, the first layer includes a first material. In one embodiment, the first layer is a dielectric layer. For example, the first material is a dielectric material. Other types of layers may also be useful. The dielectric layer, for example, serves as a PMD layer. In one embodiment, the PMD layer is formed of silicon dioxide. Other types of dielectric materials including doped silicon oxide such as fluorinated silicon oxide (FSG), undoped or doped silicate glasses such as boron phosphate silicate glass (BPSG) and phosphate silicate glass (PSG), spin-on glass (SOG), undoped or doped thermally grown silicon oxide, undoped or doped TEOS deposited silicon oxide, and other low-k or ultra low-k dielectric materials can also be used to form the PMD layer. In one embodiment, the first layer is about 200 nm thick. Preferably, the thickness of the first layer is in the range of about 100-300 nm. Other thicknesses are also useful. 
         [0028]    The first layer can be deposited using various types of processes. For example, the first layer is deposited using chemical vapor deposition (CVD), including plasma enhanced (PECVD), high density (HDCVD), atmospheric pressure (APCVD). Other techniques, such as spin-on processes, depending on the type of material used and application, may also be useful. In one embodiment, the first layer is silicon oxide formed by PECVD using tetraethylorthosilicate (TEOS) as the main precursor gas. A planarization process, such as a chemical mechanical polish (CMP), can be performed, if necessary, to provide a planar top surface. 
         [0029]    In one embodiment, a second layer  168  is disposed over the PMD layer. In one embodiment, the second layer serves as a hard mask layer. The second layer is formed of a second material which the first material can be etched with selectively to it. The second layer may be, for example, silicon nitride (SiN). Other types of materials which the first layer can be etched with selectively to it may also be useful. For example, the first layer may be an advanced patterning film (APF) or a conductive layer. The second layer should be sufficiently thick to process the first layer. In one embodiment, the second layer is about 50 nm thick. Other thicknesses are also useful. In one embodiment, the second layer is formed by CVD. Other forming or deposition techniques may also useful. 
         [0030]    A soft mask layer  170  is formed over the second layer. In one embodiment, the soft mask layer is formed of photoresist. An antireflective coating (not shown) may be formed above the second layer  168  to reduce substrate reflectivity. The antireflective coating (ARC) can be of an organic or inorganic material and formed by appropriate techniques, such as spin-on, sputtering or CVD. Other techniques may also be useful. In one embodiment, the ARC is of an organic material formed by a spin-on process. Alternatively, the ARC can be an inorganic material formed by, for example, CVD or physical vapor deposition (PVD). 
         [0031]    In one embodiment, the soft mask layer  170  is patterned to form openings  173 . The openings, for example, correspond to the contact regions below the first layer. The dimension of the openings is equal to a first dimension. The first dimension, in one embodiment, is equal to CD L . As discussed, CD L  is larger than CD D . Conventional lithographic and patterning processes can be employed to pattern the soft mask. For example, the photoresist is exposed to an exposure source with the desired pattern and developed to remove desired portions to form the openings. 
         [0032]    In  FIG. 2   b , the second layer  168  is patterned using the soft mask as the etch mask. The ARC layer may also be patterned. Openings  175  are formed in the second layer by removing the exposed portions not covered by the soft mask. The second layer can be patterned using an anisotropic etch, such as reactive ion etch (RIE) or dry etch. In one embodiment, the second layer, which is formed of SiN, is etched using a high silicon nitride etch rate recipe, such as SF 6 /HBr/He or CF 4 /Ar chemistry. These etch recipes include high fluorine atom plasma which maintains a near vertical silicon nitride profile and excellent critical dimension control. For example, using CF4/Ar chemistry, the gases are flowed at the rate of about 50 sccm for CF4 and 500 sccm for Ar. The soft mask is removed after patterning. Other chemistries for patterning the second layer may also be useful. The CD of the openings in the second layer is equal to about CD L . 
         [0033]    Referring to  FIG. 2   c , a third layer  162  is deposited on the substrate, covering the first layer  160  and the second layer  168 . In one embodiment, the third layer  162  is deposited conformally over the substrate. Non-conformal deposition may also be useful. In one embodiment, the third layer includes a third material. The third layer, in one embodiment, is formed of a dielectric material. For example, the third layer is formed of silicon oxide. Other types of dielectric materials, such as fluorinated silicon oxide (FSG), silicate glasses such as boron phosphate silicate glass (BPSG) and phosphate silicate glass (PSG), spin-on glass (SOG), undoped or doped thermally grown silicon oxide, undoped or doped TEOS deposited silicon oxide, and other low-k or ultra low-k dielectric materials, may also be useful. The third layer may include other types of material. For example, the third layer may be formed of any type of material which can be removed selectively to the second layer. In one embodiment, the third layer is formed by CVD or PVD. Other techniques may also be employed to form the third layer. In a preferred embodiment, the third and first materials are the same. For example, the third layer is formed of the same material as the first layer. Providing first and third layers which are different may also be useful. 
         [0034]    In  FIG. 2   d , a planarization process is performed on the substrate. The planarization process removes a portion of the third layer above the second layer. This, for example, produces a planar surface between the second and third layers  168  and  162 . The planarization process, in one embodiment, includes CMP. Other types of planarization processes may also be useful. 
         [0035]    Referring to  FIG. 2   e , the second layer is removed. The removal of the second layer results in a topology on the substrate. For example, the topology includes mesas formed of the remaining portions of the third layer  162  which protrude above the surface of the first layer. The removal of the second layer, in one embodiment, is achieved by a wet etch employing, for example, a HF solution. Other techniques of removing the second layer may also be useful. 
         [0036]    In  FIG. 2   f , a trimming process is performed to partially remove at least a portion of the third layer. The trimming process, in one embodiment, is an isotropic etch, such as a wet etch. Other types of trimming processes may also be useful. The trimming process at least partially reduces the width of the mesas formed by the third layer. If the third and first layers are of the same or similar materials, a height of the first layer may also be reduced. For example, the trimming process reduces the dimension of the mesas from the first dimension to a second dimension. In one embodiment, the second dimension of the mesas is equal to about CD D  of openings formed in the first layer. 
         [0037]    As illustrated by  FIG. 2   g , a fourth layer  195  is formed over the substrate. The fourth layer at least covers the mesas of the third layer. The fourth layer serves as an etch mask for subsequently forming openings in the first layer. The openings, for example, are contact openings which correspond to contact regions below the first layer. The CD of the contact openings is equal to about CD D . In one embodiment, the fourth layer is formed of a dielectric layer which the first layer can be etched with selectively to it. For example, the fourth layer is formed of SiN. Other types of hard mask materials, such as conductive materials, may also be useful. In one embodiment, the fourth layer is preferably the same material as the removed second layer. Providing second and fourth layers formed of different materials may also be useful. 
         [0038]    In  FIG. 2   h , a planarization process is performed to remove excess materials of the fourth layer such that it is coplanar with the top of the mesas. In one embodiment, the planarization process includes a CMP or an etch back. Other types of planarization processes may also be useful. 
         [0039]    Referring to  FIG. 2   i , the mesas of the third layer and portions of the first layer under them are removed by an anisotropic etch to form openings in the first layer using the fourth layer as an etch mask. The openings, for example, correspond to contact regions below the first layer, such as gates and S/D regions. The CD of the openings in the first layer, in one embodiment, is equal to CD D , which is less than CD L . 
         [0040]    In one embodiment, the first material of the first layer and the mesas of the third layer are removed by an anisotropic etch, such as an RIE. The RIE may remove both the mesas and portions of the first layer using the same chemistry. For example, a single anisotropic etching process can be performed to remove the mesas and portions of the first layer. This may be possible when the first and third layers are of the same or similar materials which can be etched non-selectively. In other embodiments, different chemistries may be used to separately remove the mesas and the portions of the first layer. 
         [0041]    In one embodiment, the first layer is etched using a clean chemistry. The use of a clean chemistry advantageously avoids or reduces polymer buildup in the openings during etching. This facilitates forming openings with vertical or substantially vertical sidewalls. In one embodiment, the first layer is patterned using a fluorocarbon chemistry (e.g., C 4 F 6 ). The process, for example, is performed at a pressure of about 30 to 200 mT and a temperature of less than about 200° C. Other etch chemistries or parameters to reduce polymer buildup are also useful. 
         [0042]    Referring to  FIG. 2   j , a conductive layer is deposited on the substrate, filling the openings and covering the substrate. For example, the conductive layer fills the openings and covers the fourth layer. In one embodiment, the conductive materials include tungsten (W). Other types of conductive materials, such as copper and aluminum, are also useful. The conductive material, for example, may be formed by sputtering. Other techniques may also be useful to form the conductive layer. Excess conductive materials over the substrate are removed to form contacts  198  in the openings. In one embodiment, CMP is used to remove the excess conductive materials, using the fourth layer as a CMP stop. This produces a planar top surface. For example, the top of the contacts and fourth layer is coplanar. The contacts, for example, connect the contact regions, such as gates and S/D regions of transistors to conductive interconnects (not shown) of an interconnect or metal level. 
         [0043]    As described, the hard mask remains over the dielectric layer, forming coplanar top surface with the top of the contacts. In some, embodiments, the hard mask is removed. In one embodiment, the hard mask may be removed by the CMP process to form the contacts. For example, excess conductive material along with the hard mask is removed by CMP. This leaves a coplanar surface between the top of the dielectric layer and contacts. 
         [0044]    In other embodiments, the hard mask is removed after forming the openings, as shown in  FIG. 2   i . The hard mask may be removed, for example, by a wet etch. After removal, the contact openings are filled with conductive material. The process continues as described in  FIG. 2   j.    
         [0045]    The process continues to complete fabricating the IC. For example, the process continues to form interconnects, additional interconnect levels, passivation layer, dicing, assembly and packaging. In alternative embodiments, interconnects and contacts can be formed using dual damascene techniques. With the use of a composite etch stop layer according to the invention, polymerization in the contact opening can be avoided. Additionally, the contacts can be formed with minimal erosion of silicide contact and isolation material, increasing process window and yields. 
         [0046]    The invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. The foregoing embodiments, therefore, are to be considered in all respects illustrative rather than limiting the invention described herein. Scope of the invention is thus indicated by the appended claims, rather than by the foregoing description, and all changes that come within the meaning and range of equivalency of the claims are intended to be embraced therein.