Abstract:
A process for producing porous polymer masterbatch having anti-bacterial and odor eliminating functions, wherein said fiber contains materials such as porous natural mineral kieselguhr or active carbon, can absorb and eliminate odor such as stink of sweat and the like discharged from the human body, has functions of sterilization, anti-bacterial, anti-mold, and the like. Pores of the natural mineral kieselguhr or active carbon contain organic Chinese herbal medicine and inorganic anti-bacterial minerals, wherein all of such organic Chinese herbal medicine and inorganic anti-bacterial minerals have functions of anti-bacterial, anti-fungal and the like, can eliminate effectively odor or reduce substantially stink, and can be applied extensively on various fabrics, clothes and ornaments or other goods.

Description:
BACKGROUND OF THE INVENTION 
       [0001]    1. Field of the Invention 
         [0002]    The invention relates to a process for producing porous polymer masterbatch and fiber thereof that have anti-bacterial and odor eliminating functions, and in particular, to a process for producing anti-bacterial and odor eliminating polymer masterbatch and fiber thereof containing organic or inorganic materials. 
         [0003]    2. Description of the Prior Art 
         [0004]    As the demand for a modern hygienic life increases, anti-bacterial products have gradually received more welcome from consumers. This trend extends to the textile industry and has resulted into considerable progress in the production of anti-bacterial fibers and clothing and other daily use articles. 
         [0005]    Anti-bacterial agent used in the anti-bacterial fiber can be divided generally into two types, namely, an organic anti-bacterial agent, and an inorganic anti-bacterial agent. One of the organic anti-bacterial agents is quaternary ammonium salt. Unfortunately, quaternary ammonium salt has poor heat resistance and can not be used in the process for making plastics or fiber spinning products. 
         [0006]    On the other hand, an inorganic anti-bacterial agent is a carrier (for example zeolite) containing metal ions (for example Ag + , Zn 2+ , Cu 2+ ), or certain types of nano-scale metal particles (for example nano-scale silver particles), and both are considered as effective particles in the following description. 
         [0007]    Silver has a well-accepted anti-bacterial effect. In general, an antibiotic can kill approximately six different types of bacteria, while silver can kill about 600 types of bacteria. In addition, silver is a non-toxic substance, and therefore silver is used extensively and has a long history. Furthermore, through nanotechnology techniques, silver particles become more active and their anti-bacterial function is enhanced, thereby promoting the quality of the home environment and personal hygiene. Aqueous solutions containing silver ions released from both nano-scale silver granules and nanometer silver has remarkable anti-bacterial effect. Under the circumstance of multiple dilutions, nanometer silver still has an inhibition efficiency of 99.99% against  Escherichia coli, Staphylococcus aureus, Sarmonella, Pseudomonas aeruginosa  and the like. The principal cause of this resides in the biological action that silver has itself. Active silver ions can attract the sulfhydryl group on the enzymatic protein in the bacteria and causes these groups to quickly bind with each other, thereby rendering the enzymes containing sulfhydryl groups to lose activity and hence kill the bacteria. 
         [0008]    A traditional process for using silver ion to produce fiber comprises immersing fiber in an organic anti-bacterial agent so as to adhere a carrier or nanometer silver particle on the surface of the fiber. In such traditional processes, effective particles in the anti-bacterial inorganic solvent may be easily washed off, and at the same time, may easily induce an allergic response in the user. Another process for producing anti-bacterial fiber comprises mixing an inorganic anti-bacterial agent and polyester, and then drawing the mixture thus-obtained into fibers containing effective particles. In such a process for making anti-bacterial fiber, most of the anti-bacterial materials are embedded within the fiber, and hence the anti-bacterial and odor eliminating functions are unable to be exhibited. Furthermore, part of the anti-bacterial material exposed on the outside of the fiber might lose its anti-bacterial and odor eliminating functions after washing or dying and finishing due to binding with chlorine, sulfur and the like. 
         [0009]    In view of the foregoing, conventional techniques mentioned above still have many disadvantages, poorly designed and needs to be improvement. 
         [0010]    The inventor had learned of the various disadvantages and shortcomings derived from such conventional techniques described above, and had thought to improve and innovate, and finally, after studying intensively for many years, has developed a process for producing porous polymer masterbatch and fiber thereof that have anti-bacterial and odor eliminating functions according to the invention. 
       SUMMARY OF THE INVENTION 
       [0011]    One object of the invention is to provide a process for producing porous polymer masterbatch and fiber thereof that have anti-bacterial and odor eliminating functions, for the purpose of reducing lost particles in the anti-bacterial inorganic solvent, which tend to be washed off easily, and hence tend to lower the anti-bacterial effect as well as lead to potential unknown effects on the ecological equilibrium of the environment. 
         [0012]    Another object of the invention is to provide a process for producing porous polymer masterbatch and fiber thereof that have anti-bacterial and odor eliminating functions, characterized in that the inventive process can improve the previous conventional process for making anti-bacterial fiber; where in the conventional process, an inorganic anti-bacterial agent is mixed in a polymer and then the resulted mixture is drawn to form fiber containing fine nanometer particles, and in such conventional process for making anti-bacterial fiber, the nanometer particles are difficult to be dispersed homogeneously in the fiber, and further, most of the nanometer particles are embedded within the fiber, so that its anti-bacterial effect can not function effectively. 
         [0013]    Still another object of the invention is to provide a process for producing porous polymer masterbatch and fiber thereof that have anti-bacterial and odor eliminating functions, characterized in that wide and diverse materials can be used, and has a wide spectrum of anti-bacterial and anti-fungal effects. 
         [0014]    The process for producing porous polymer masterbatch and fiber thereof that have anti-bacterial and odor eliminating functions comprises: step  1 , grinding kieselguhr or active carbon into micro-particles; step  2 , immersing said micro-particles obtained in step  1  in an organic Chinese herbal medicine and inorganic anti-bacterial minerals and polyvinyl alcohol with constant stirring; step  3 , air-drying micro-particles thus-obtained in step  2 , and dry-grinding further the dried micro-particles into finer particles suitable for drawing and to be dispersed homogeneously in a solution; step  4 , carrying out a esterification reaction for binding monomer to form an anti-bacterial polyester masterbatch; and/or step  5 , producing the polyester masterbatch formed in step  4  into anti-bacterial polyester fiber by cold grain spin-drawing technique. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0015]    These features and advantages of the present invention will be fully understood and appreciated from the following detailed description of the accompanying drawings, wherein: 
           [0016]      FIG. 1  shows the flow chart for carrying out the process according to the invention; 
           [0017]      FIG. 2  is a schematic view of porous micro-particles according to the invention; 
           [0018]      FIG. 3  is a schematic view of finer micro-particles obtained after dry-grinding according to the invention; and 
           [0019]      FIG. 4  is a schematic view of anti-bacterial polyester fibers according to the invention. 
       
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 
       [0020]    For understanding further the objects, characteristics and effects of the invention, the following non-limiting examples will be illustrated in conjunction with the accompanied drawings below. 
         [0021]    Referring to  FIG. 1 , the process for producing porous polymer masterbatch and fiber thereof having anti-bacterial and odor eliminating functions provided according to the invention comprises following steps: 
         [0022]    step  1 : grinding kieselguhr or active carbon into micro-particles of 1˜1000 micron ( 111 );
       Referring to  FIG. 2 , a schematic view of kieselguhr or active carbon micro-particles. In the step  1 , kieselguhr or active carbon is ground at first into micro-particles  1 . In the case of active carbon, the principal component of active carbon is carbon, combined with minor amount of hydrogen, oxygen, nitrogen, sulfur and the like, and is a black porous material  2  with complex surface. It has a six ring structure formed from carbon and its shape may range from a cylindrical coarse granule to a fine powder particle, and hence it has two type of morphology of granule and powder. The granule has generally a diameter of 1˜6 mm, and its length is 0.7˜4 times of its diameter. Alternatively, it may be present as a granule of irregular shape with 6˜120 particle mesh. The active carbon is odorless, and tasteless, and is insoluble in water and organic solvent. Active carbon has a packing density of about 0.3˜0.6 g/ml, a volume of the very large micro-pore of about 0.6˜0.8 ml/g, and a specific surface of about 500˜1,500 m 2 /g, and therefore, exhibits a very strong adhesive force to an organic macromolecular material;   In addition, kieselguhr can be used in the process of the invention. Kieselguhr is mined from fossil lake beds. Such kieselguhr is formed from the deposition of large amounts of dead micro-diatoms on the ancient lake or sea bed. Diatom is classified into two morphologies of salt water diatom and fresh water diatom. Accordingly, the thus-mined kieselguhr is classified also into two types; salt water kieselguhr and fresh water kieselguhr. After mining, it can be washed, processed and ground into micro-powder of various specific sizes;       
 
         [0025]    step  2 : impregnating micro-particles obtained in step  1  in an organic Chinese herbal medicine and a water-soluble cementing agent, adding inorganic anti-bacterial minerals of 1˜100 nm in size, and then stirring continuously for more than 24 hours, thereby enabling the organic Chinese herbal medicine and inorganic anti-bacterial minerals to be impregnated, bound and adhered sufficiently in the pores of the micro-particle ( 112 );
       Referring to Table 1, each of the inorganic anti-bacterial minerals mentioned above has its own special effect. Inorganic anti-bacterial minerals used in the process of the invention may be selected from the group consisting of realgar, calamine, melanterite, talc, alum, sulfur, borax, nanometer silver (Ag), nanometer zinc (Zn), nanometer copper (Cu), titanium dioxide (TiO 2 ) and any combination thereof;       
 
         [0000]    
       
         
               
             
               
               
               
             
               
               
               
             
           
               
                 TABLE 1 
               
             
             
               
                   
               
               
                 The pharmacological effect, function and chemical component of 
               
               
                 inorganic anti-bacterial minerals. 
               
             
          
           
               
                 Item 
                 Name 
                 Pharmacological effect 
               
               
                   
               
             
          
           
               
                 1. 
                 Realgar 
                 Detoxification, removing moisture, killing insects, 
               
               
                   
                   
                 anti-bacterial 
               
               
                 2. 
                 Calamine 
                 Absorbing moisture, stopping itch, controlling 
               
               
                   
                   
                 sores, antiseptic, anti-bacterial 
               
               
                 3. 
                 Melanterite 
                 Treating eczema, killing insects, anti-bacterial 
               
               
                 4. 
                 Talc 
                 Treating eczema, wet sore, scabies, anti-bacterial 
               
               
                 5. 
                 Alum 
                 Detoxification, killing insects, drying moisture, 
               
               
                   
                   
                 stopping itch, wide spectrum anti-bacterial 
               
               
                 6. 
                 Sulfur 
                 Killing insects, stopping itch, scabies, eczema, 
               
               
                   
                   
                 killing insects, anti-bacterial 
               
               
                 7. 
                 Borax 
                 Detumescence, antiseptic, anti-bacterial, treating 
               
               
                   
                   
                 scabies and itch 
               
               
                 8. 
                 Nanometer 
                 Anti-bacterial, anti-fungal 
               
               
                   
                 silver (Ag) 
               
               
                 9. 
                 Nanometer 
                 Anti-bacterial, anti-fungal 
               
               
                   
                 zinc (Zn) 
               
               
                 10. 
                 Nanometer 
                 Anti-bacterial, anti-fungal 
               
               
                   
                 copper (Cu) 
               
               
                 11. 
                 Titanium 
                 Anti-bacterial, anti-fungal 
               
               
                   
                 dioxide (TiO 2 ) 
               
               
                   
               
             
          
         
       
       
         
           
             The water-soluble cementing agent  3  may be selected from polyvinyl alcohol (PVA) or the like. PVA is an extensively used water-soluble macromolecular polymer, with a property between those of plastic and rubber. Since PVA possesses a strong bonding property, flexibility, smoothness of the surface texture, oil resistance, solvent resistance, protective gel property, gas insulating property, wear resistance and after special treatment, water resistance, it is used very often in raw materials for fiber; 
             The binding property of PVA is utilized to adhere the extract essence fluid of herbal plants on the surface of the outer and inner holes of micro-particles so as to increase the amount and surface area of the organic Chinese herbal medicine and inorganic anti-bacterial minerals thus-adhered. The herbal plants useful in the process according to the invention may be selected from the group consisting of Radix et RhizomanNotopterygii, Black false hellebore, Hibiscus syriacus skin, Cinnamomum cassia Presl, camphor, Cnidium monnieri (L) Cuss, Hydnocarpus anthelmintica Pier., rosin and any combination thereof. Each of the herbal plants mentioned above has its own specific effect as shown in Table 2; 
           
         
       
     
         [0000]    
       
         
               
             
               
               
               
               
               
             
           
               
                 TABLE 2 
               
             
             
               
                   
               
               
                 Pharmacological effect, functions and chemical components of 
               
               
                 Chinese herbs 
               
             
          
           
               
                   
                   
                 Pharmacological 
                   
                   
               
               
                 Item 
                 Name 
                 effect 
                 Function 
                 Chemical components 
               
               
                   
               
               
                 1. 
                 Radix et Rhizoma 
                 Anti-bacterial, 
                   
                   
               
               
                   
                 notopterygii 
                 anti-fungal 
               
               
                 2. 
                 Black false hellebore 
                 Anti-bacterial, 
               
               
                   
                   
                 anti-fungal, killing 
               
               
                   
                   
                 insects 
               
               
                 3. 
                 Hibiscus syriacus 
                 Killing insects, 
               
               
                   
                 skin 
                 stopping itch, 
               
               
                   
                   
                 anti-bacterial 
               
               
                 4. 
                 Cinnamomum cassia 
                 Anti-bacterial, 
                 Sedation, 
                 Cinnamic aldehyde, 
               
               
                   
                 Presl 
                 anti-bacterial 
                 Analgesia, 
                 Cinnamic acid, 
               
               
                   
                   
                 anti-tinea, 
                 Allaying fever 
                 Cinnamyl acetate, 
               
               
                   
                   
                 anti-fungal 
                   
                 Phenylpropyl acetate 
               
               
                 5. 
                 Camphor 
                 Removing 
               
               
                   
                   
                 moisture, killing 
               
               
                   
                   
                 insects, 
               
               
                   
                   
                 anti-bacterial, 
               
               
                   
                   
                 anti-fungal 
               
               
                 6. 
                 Cnidium monnieri 
                 Anti-fungal, 
                 Removing 
                 L-Piuene, 
               
               
                   
                 (L) Cuss 
                 anti-Gram negative 
                 rheumatism, 
                 L-Camphene, 
               
               
                   
                   
                 bacteria, anti-mold 
                 drying 
                 Bornyl isovalerate, 
               
               
                   
                   
                 Anti-Ringworm 
                 moisture, 
                 Isoborneol, Edultim, 
               
               
                   
                   
                 fungus 
                 killing insects, 
                 Cnidimine, 
               
               
                   
                   
                   
                 stopping itch 
                 Xanthotoxin 
               
               
                 7. 
                 Hydnocarpus 
                 Anti-bacterial, 
                 Detoxification, 
                 Chaulmoogric Acid, 
               
               
                   
                 anthelmintica Pier. 
                 treating tinea 
                 killing insects, 
                 Hydnocarpic Acid, 
               
               
                   
                   
                 manus and tinea 
                 removing tinea 
                 Gorlic Acid 
               
               
                   
                   
                 pedis 
                 cruris 
               
               
                 8. 
                 Rosin 
                 Anti-bacterial, 
               
               
                   
                   
                 anti-mold, treating 
               
               
                   
                   
                 scabies, wet itch 
               
               
                   
               
             
          
         
       
       
         
           
             The organic Chinese herbal medicine and inorganic anti-bacterial minerals mentioned in step  2  may be used in combination with one another to achieve the desired pharmacological effect and function; 
           
         
       
     
         [0030]    step  3 : air drying the micro-particle impregnated in step  2 , and dry grinding them further into finer micro-particle of 1˜50 micron in size suitable for drawing, and dispersing them homogeneously in a solution ( 113 );
       Referring to  FIG. 2 , the surface and the outside and inside of the holes in the thus-impregnated micro-particles had been adhered with extract essence fluid of the herbal plants. Thereafter, the impregnated micro-particles thus air dried were dry ground further into finer micro-particles. The surface  6  and the outside and inside of holes  4  in the thus-obtained finer micro-particles  7  had been adhered with the organic Chinese herbal medicine and inorganic anti-bacterial minerals  5 . The air-dried finer micro-particle  7  had a size of 1˜50 micron and became a finer micro-particle suitable for drawing as well as could be dispersed homogeneously in a solution.   The solution mentioned in the step  3  of the inventive process may be ethylene glycol solution. Ethylene glycol is a catalyst used in the condensation polymerization of polyester, and has the following advantages: 1. It has greater solubility and better dispersability in ethylene glycol solution; 2. It has good activity, and can enhance productivity of the apparatus; 3. This catalyst itself will not introduce new contaminants, can increase the intrinsic mass and improve post-processing spinning ability; 4. It can improve hues and heat stability of the slice.       
 
         [0033]    step  4 : binding the finer micro-particle dispersed homogeneously in the solution to a monomer through esterification reaction to form anti-bacterial polyester masterbatch, wherein such finer micro-particle in each of the polyester masterbatch comprises about 10-25% of the total weight of each masterbatch ( 114 ); 
         [0034]    step  5 : Using low temperature batch processing chip spinning technique to produce the anti-bacterial polyester masterbatch to produce anti-bacterial polyester fiber  8 , wherein the ratio of the anti-bacterial polyester masterbatch added is about 5-10% ( 115 ). 
         [0035]    In summary, the process for producing porous polymer masterbatch and fiber thereof having anti-bacterial and odor eliminating functions provided by the invention comprises following steps: 
         [0036]    step  1 : grinding kieselguhr or active carbon into micro-particles of 1˜1000 micron in size ( 111 ); 
         [0037]    step  2 : impregnating micro-particles obtained in step  1  with organic Chinese herbal medicine and water-soluble cementing agent and inorganic anti-bacterial minerals of 1˜100 micron in size, and stirring continuously for more than 24 hours, thereby enabling sufficient penetration, binding and adsorption of the organic Chinese herbal medicine and inorganic anti-bacterial minerals in pores of micro-particles ( 112 ); 
         [0038]    step  3 : air drying micro-particles impregnated in step  2 , and then dry grinding said dried micro-particles into finer micro-particle of 1˜50 micron in size suitable for drawing and dispersing homogeneously in a solution ( 113 ); 
         [0039]    step  4 : binding said finer micro-particles dispersed homogeneously in a solution with monomer through esterification reaction to form said anti-bacterial polyester masterbatch, wherein such finer micro-particle in each of the polyester masterbatch comprises about 10-25% of the total weight of each masterbatch ( 114 ); 
         [0040]    step  5 : producing anti-bacterial polyester fiber from said anti-bacterial polyester masterbatch by low temperature batch processing chip spinning technique, wherein the ratio of the anti-bacterial polyester masterbatch added is about 5-10% ( 115 ). 
         [0041]    Accordingly, the process for producing porous polymer masterbatch and fiber thereof having anti-bacterial and odor eliminating functions provided by the invention has following advantages over other conventional techniques: 
         [0042]    1. The inventive process for producing porous polymer masterbatch and fiber thereof having anti-bacterial and odor eliminating functions can reduce the lost amount of particles originally present in the anti-bacterial inorganic solvent, wherein said particles is susceptible to be washed off, and thus, may lower its anti-bacterial effect as well as may cause an unexpected influence on the ecological equilibrium of the environment. 
         [0043]    2. The inventive process for producing porous polymer masterbatch and fiber thereof having anti-bacterial and odor eliminating functions can enable these odor eliminating anti-bacterial materials to penetrate and adhere into tremendous micro-pores of these porous particles, and further, since they can bind in these micro-pores by means of water-soluble cementing agent, thereby these materials tend not to lose and hence can achieve the purpose of increasing its anti-bacterial and odor eliminating functions. 
         [0044]    3. The inventive process for producing porous polymer masterbatch and fiber thereof having anti-bacterial and odor eliminating functions can be extended to make various related products having anti-bacterial and odor eliminating functions, such as shoes, bags, socks, clothes. 
         [0045]    4. The inventive process for producing porous polymer masterbatch and fiber thereof having anti-bacterial and odor eliminating functions can adopt wide and diverse materials, and hence can retain wide spectrum anti-bacterial and anti-fungal effects, without loses its anti-bacterial function during dying and finishing process due to bind with chlorine and sulfur like, for example, using nanometer silver alone. 
         [0046]    Many changes and modifications in the above-described embodiment of the invention can, of course, be carried out without departing from the scope thereof. Accordingly, to promote the progress in science and useful arts, the invention is disclosed and is intended to be limited only by the scope of the appended claims.