Abstract:
A waterborne coating composition comprising a waterborne epoxy coating with hydraulic cement, which is capable of a thin initial application. The coating composition may be made, stored and transported as a two-part composition, where each part is a pourable liquid. The waterborne epoxy composition cures under normal conditions and adheres to surfaces including masonry, concrete and metal.

Description:
RELATED APPLICATIONS 
       [0001]    The present application is a continuation and claims priority benefit of an earlier-filed application of the same title, Ser. No. 11/018,644, filed Dec. 20, 2004. The identified earlier-filed application is hereby incorporated by reference into the present application. 
     
    
     FIELD OF THE INVENTION 
       [0002]    This invention relates to coating compositions and, more particularly, to waterborne epoxy coating compositions and methods for using such compositions. 
       BACKGROUND OF THE INVENTION 
       [0003]    Epoxy coating compositions are used to treat surfaces to protect against corrosion and other forms of wear and tear caused by use and the environment. The types of surfaces treated include concrete, metal, and other surfaces. Effective coating compositions are prized not only for the quality of protection, but also for easy and efficient transportation, storage, and application. Thus, a good coating composition will not only protect the surface, but also be easy to apply and quick to cure. 
         [0004]    The use of epoxy compositions containing volatile organic solvents has fallen out of favor even though these compositions provide exceptional anti-corrosion protection. The organic solvent based compositions are environmentally unfriendly and their use has been curtailed. Solvent free epoxy coatings often require sophisticated, non-standard equipment for application. 
         [0005]    Other epoxy coating compositions provide good protection if applied at the recommended thickness. This recommended thickness requires multiple coats and each coat must be cured or set before another coat may be applied. Each additional coat requires additional labor, which increases the cost of application. Other coats may be applied at greater initial thickness, but require more time to set up. Coatings applied at greater initial thicknesses may also introduce flaws caused by voids from evaporation of volatile components during the curing process. 
         [0006]    The combination of an epoxy resin and cement in a coating composition has been used previously to create cement compositions suitable for overlaying concrete. For example, prior products include cement based compositions with an epoxy used as “mortars,” “toppings,” or “overlays” to coat Portland cement concrete or metal surfaces. These compositions use a small portion of epoxy to enhance the cement composition and the final compositions are thick like cement and resembles cement. These are generally two-component compositions having a dry-mix component and a wet-mix component which are combined to form the final composition for application to surfaces in thick films, typically greater than about 20 mils. Other compositions have used an epoxy to bind a cement composition. 
       BRIEF SUMMARY OF THE INVENTION 
       [0007]    There is, therefore, provided in the practice of the invention a novel waterborne fluid coating composition, which is epoxy based and includes hydraulic cement, for reduced initial thickness application, and which provides for a quicker application at a reduced cost. The waterborne epoxy coating composition broadly includes an epoxy resin, a hydraulic cement powder, a curing agent and water. 
         [0008]    In one embodiment, the coating composition is prepared by mixing two pre-blended liquid components; one component containing a liquid epoxy resin and hydraulic cement powder; and the other component containing an amine-based curing agent and water. The first part may also include additives, such as a non-reactive diluent, a reactive diluent, an organosilicon adhesion promoter, a pigment, hollow spheres, or other materials. The second part may also include additives, such as a cement plasticizer, a non-reactive diluent, a water-based latex resin, a defoamer, a corrosion inhibitor, or other materials. 
         [0009]    Accordingly, it is an object of the present invention to provide an improved two-part waterborne epoxy coating providing anti-corrosion protection. 
     
    
     DETAILED DESCRIPTION 
       [0010]    The waterborne epoxy composition broadly includes an epoxy resin, cement powder, an amine-based curing agent, and water. The composition may be enhanced with additives, including a non-reactive diluent, a reactive diluent, an organosilicon adhesion promoter, a pigment, hollow spheres, a cement plasticizer, a water-based latex resin, a defoamer, a corrosion inhibitor, or other materials Each element of the general formula will be discussed in detail below, followed by several embodiments of the composition and the method of production and application. 
         [0011]    In various embodiments of the invention, the epoxy resin is present in the composition in an amount of about 8.0% to about 23.0% by weight, preferably about 10.0% to about 21.0% by weight, and more preferably about 11.0% to about 19.0% by weight. 
         [0012]    The epoxy resin may be liquid, solid or semi-solid. The epoxy resin functions as the curable component of one part of the two-part epoxy coating composition. In one embodiment, the epoxy resin may consist of any one of bisphenol A, bisphenol F, epoxy phenol novolac, epoxy cresol novolac, naphthalene epoxy, or tertiary butyl cathecol epoxy. Another epoxy may be used besides those listed here, although these are preferred. In exemplary embodiments, the epoxy resin is a liquid bisphenol A epoxy resin, including for example, liquid bisphenol A epoxy resin such as Huntsman GY6010, or a water-dispersed bisphenol A epoxy resin such as Resolution EPI-REZ 3510-W-60. 
         [0013]    In various embodiments of the invention, hydraulic cement powder is present in the composition in an amount of about 20.0% to about 72.0% by weight, preferably about 28.0% to about 71.0% by weight, and more preferably about 30.0% to about 70.0% by weight. 
         [0014]    The hydraulic cement powder may be any type of Portland cement and may also be any color. Portland cement comes in Types I, II, III, IV, and V. The possible colors include white, grey, etc. In another embodiment, the hydraulic cement powder is a mixture of 0.50 to 0.95 weight parts of Portland Cement and 0.05 to 0.50 weight parts pozzolan powder derived from a group comprising fly ash, steel slag, silica fume, or calcined kaolin clay. 
         [0015]    In various embodiments of the invention, the curing agent is present in the composition in an amount of about 5.0% to about 21.0% by weight, preferably about 7.0% to about 19.0% by weight, and more preferably about 8.0% to about 18.0% by weight. 
         [0016]    The curing agent may be a substantially solvent free, or a water dilutable polyamine having a plurality of N—H linkages capable of reacting with the epoxy resin. The amine-based curing agent may be a polyoxyalkylene polyamine, arylene polyamine, cyclo-aliphatic polyamine, Mannich base, or a blend of two or more of these polyamines. An example of a solvent free amine curing agent used in an embodiment is a polyoxypropylene polyamine such as Huntsman JEFFAMINE D-400. Examples of commercially available water-based amine curing agents useful in the invention include, for example, Cognis WATERPOXY 751, UCB BECKOPOX 613, Huntsman ARADUR 39, Bakelite RUETADUR VE-51, and Air Products ANQUAMINE 287. Preferably, the curing agent is a water soluble polyamine adduct containing a grafted internal reactive surfactant on the backbone, containing primary, secondary and tertiary amine functionality with some free monomeric polyamine, enabling the emulsification of liquid epoxy resin, without addition of external surfactant, and that is miscible with water in all proportions, such as Cognis WATERPOXY 751, as disclosed in U.S. Pat. No. 6,395,806. 
         [0017]    The coating compositions of the invention are prepared from a desired amount of epoxy resin such that the weight ratio of epoxy resin to hydraulic cement is in the range of about 0.1:1 to about 1.2:1; the compositions further provide a ratio of about 0.8 to 1.3 equivalents of total epoxy groups to 1.0 equivalent of reactive curing agent amine groups; and 0.2 to 0.9 parts water to 1.0 part hydraulic cement. 
         [0018]    A non-reactive diluent may be added to decrease the viscosity of the mixture. Any diluent that does not react with the other elements of the composition and decreases viscosity may be used. In one embodiment, the non-reactive diluent is benzyl alcohol, which not only reduces viscosity, but also speeds the epoxy/amine reaction and helps prevent freezing or crystallization of the coating composition. In another embodiment, the non-reactive diluent is an aromatic hydrocarbon resin, such as Rütgers NOVARES LS 500 for example, which not only reduces viscosity, but also has lower volatility. The non-reactive diluent may be included in either or both components of the composition. 
         [0019]    The composition may further include a reactive diluent. The reactive diluent may be an aliphatic, cycloaliphatic, or aromatic epoxy functional diluent. The reactive diluent may be either monofunctional or multifunctional. In one embodiment, the reactive diluent is a C6 to C18 alkyl mono glycidyl ether, and is included at a ratio of about 8 to 26 parts per 100 parts of epoxy resin. One example of a commercial reactive diluent suitable for this composition is Air Products EPODIL 748. 
         [0020]    The composition may further include an organosilicon adhesion promoter to enhance the adhesion of the cured composition to the surface being coated. The organosilicon adhesion promoter is included in a ratio of about 0.5 to 2 parts to 100 parts of epoxy resin. In one embodiment, the organosilicon adhesion promoter is γ-glycidoxypropyl-trimethoxy silane. 
         [0021]    The composition may further include a water-based latex resin in a ratio of up to about 1.2 parts water-based latex resin to 1.0 part of hydraulic cement. Examples of useful water-based latex resins include, acrylic, styrene-acrylic, styrene butadiene rubber (SBR), polyvinyl acetate (PVA), and ethylene vinyl acetate (EVA) latexes. In one embodiment, the latex resin is an acrylic, styrene-acrylic, or styrene butadiene rubber (SBR) latex. Examples include Rohm &amp; Haas RHOPLEX MC-1834, SYNTHOMER 29Y46 SBR, and Resolution IC-780. 
         [0022]    The composition may further include a desired amount of pigment up to about 24.0% in order to achieve the desired coating color. In one embodiment the pigment is titanium dioxide. The pigment may be dispersed in either component of the two-part composition of the invention. 
         [0023]    The composition may further include up to about 8.0%, preferably about 1.0% to about 8.0%, by weight hollow spheres as an inert filler. In one embodiment the hollow spheres are hollow micro-spheres having a particle diameter in the range of about 5 to 90 microns and are included in the hydraulic cement containing component of the two-part composition in a ratio of about 1 part hollow spheres to about 3 to 50 parts of hydraulic cement. Examples include 3M SCOTCHLITE K37 Glass Bubbles and CHL A-90 Hollow Ceramic Microspheres. 
         [0024]    The composition may further include up to about 0.4% of a cement plasticizer, such as a lignosulfonate salt, for example Lignotech Norlig 24C; up to about 0.55% of a defoamer, such as a non-silicone defoamer, for example BYK-Chemie BYK-011, and/or a silicone defoamer, for example Tego FOAMEX 805; and up to about 2.4% of a corrosion inhibitor, such as Cortec MCI-2000 or W. R. Grace DCI S; all as set forth in the following examples and claims. 
         [0025]    Thus, in various embodiments, the composition of the present invention includes some or all of the following components: about 0.06% to about 0.40% by weight of a concrete plasticizer; about 0.15% to about 0.55% by weight of a defoamer; and, about 0.01% to about 2.4% by weight of a corrosion inhibitor. 
         [0026]    One embodiment of the waterborne epoxy coating composition is divided into two parts for easy storage and transportation. Part A of this formula is non-aqueous and includes liquid Bisphenol A epoxy resin, reactive diluent, organosilicon adhesion promoter, hydraulic cement, and hollow spheres. Part B is aqueous and includes water-based amine curing agent, water-based latex resin, and defoamer. The two parts are combined in a sprayer to mix the two parts together and then apply the coating composition to a surface, wherein the composition has a weight ratio of epoxy resin to hydraulic cement in the range of about 0.19:1 to about 0.6:1; a ratio of about 0.9 to 1.15 equivalents of total epoxy groups to 1.0 equivalent of reactive curing agent amine groups; and 0.3 to 0.6 parts total water to 1.0 part hydraulic cement. 
         [0027]    Another embodiment comprises a non-aqueous Part A including liquid Bisphenol A epoxy resin, reactive diluent, organosilicon adhesion promoter, hydraulic cement, and hollow spheres; and an aqueous Part B including a water-based amine curing agent, water-based latex resin, and defoamer. The two parts are combined in a sprayer to mix the two parts together and then apply the coating composition to a surface, wherein the final composition has a weight ratio of epoxy resin to hydraulic cement is in the range of about 0.25:1 to about 0.5:1; a ratio of about 0.95 to 1.1 equivalents of total epoxy groups to 1.0 equivalent of reactive curing agent amine groups; and 0.4 to 0.6 parts total water to 1.0 part hydraulic cement. Each part is approximately equal in volume and additional water may be added after the two parts are mixed. 
         [0028]    Various embodiments of the non-aqueous Part A of the two part composition of the invention broadly comprise some or all of the following components: epoxy resin in an amount of about 10% to about 42% by weight, preferably about 15% to about 33% by weight, and more preferably about 18% to about 27% by weight of said Part A; hydraulic cement powder in an amount of about 46% to about 90% by weight, preferably about 57% to about 84% by weight, and more preferably about 58% to about 80% by weight of said Part A; hollow spheres in an amount of about 1% to about 13% by weight of said Part A; mono glycidyl ether as reactive diluent in an amount of about 1.1% to about 4.8% by weight of said Part A; and an organosilicon adhesion promoter in an amount of about 0.1% to about 0.5% by weight, preferably about 0.2% to about 0.4% by weight of said Part A. Various embodiments of the aqueous Part B of the two part composition of the invention broadly comprise some or all of the following components: at least one curing agent, comprising a water soluble polyamine, in an amount of about 30% to about 60% by weight, preferably about 34% to about 52% by weight of said Part B; concrete plasticizer in an amount of about 0.2% to about 0.6% by weight of said Part B; water-based latex resin in an amount of about 30% to about 50% by weight of said Part B; defoamer in an amount of about 0.5% to about 1.0% by weight of said Part B; and corrosion inhibitor in an amount of about 0.04% to about 18.5% by weight of said Part B. Further exemplary embodiments are set forth in the following examples. 
         [0029]    In an alternative embodiment the non-aqueous Part A includes a solvent-free amine curing agent, hydraulic cement and hollow spheres. Part B is aqueous and includes a water-dispersed epoxy resin, and may further contain a water-based latex resin, and defoamer. The two parts are combined in a sprayer to mix the two parts together and then apply the coating composition to a surface, wherein the composition has a weight ratio of epoxy resin to hydraulic cement in the range of about 0.1:1 to about 1.2:1; a ratio of about 0.8 to 1.3 equivalents of total epoxy groups to 1.0 equivalent of reactive curing agent amine groups; and 0.2 to 0.9 parts total water to 1.0 part hydraulic cement. 
         [0030]    The embodiments of the waterborne epoxy coating composition may be applied with a brush, roller, or airless sprayer to produce cured coatings with a thickness from about 78% to about 95% of the single coat wet thickness. Exemplary embodiments of the composition applied by airless sprayer produce cured coatings with a thickness from about 90% to about 95% of the single coat wet thickness. Said cured coatings have a thickness of from approximately 2 mils to approximately 15 mils, preferably having a thickness of approximately 4 mils to approximately 12 mils, and more preferably having a thickness of approximately 6 mils to approximately 10 mils. The embodiments of the composition exhibit gel times from about 60 minutes to about 120 minutes and are dry to touch in less than 24 hours. 
         [0031]    The embodiments of the composition are more specifically shown in the following examples, wherein it can be seen that the embodiments of the composition are prepared without the use of a separate emulsifier surfactant to stabilize either part of the two part composition or the final blended composition. It is further apparent from the foregoing detailed description and the component ranges from the following examples of embodiments of the composition of the invention that the composition has low volatile organic compound content, generally not more than about 3.3% by weight of the total composition, preferably not more than about 2.2% by weight of the total composition, and more preferably not more than about 2% by weight of total composition, as indicated by the non-reactive diluent (benzyl alcohol) content. 
         [0000]    
       
         
               
               
             
               
               
               
               
             
               
               
               
             
               
               
               
               
               
               
             
               
               
               
             
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
           
               
                   
                   
               
             
             
               
                   
                 Examples 
               
             
          
           
               
                   
                 1 
                 2 
                 3 
               
               
                   
                 Weight % 
                 Weight % 
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                   
                 Part A Components 
                   
               
             
          
           
               
                   
                 Epoxy Resin 
                 Huntsman GY6010 
                 22.29 
                 20.35 
                 23.26 
               
               
                   
                 Reactive Diluent 
                 Air Products Epodil 748 
                 2.50 
                 2.29 
                 2.61 
               
               
                   
                 Adhesion Promoter 
                 OSi Silquest A-187 
                 0.25 
                 0.23 
                 0.26 
               
               
                   
                 Portland Cement 
                 Lehigh Type I 
                 59.43 
                 0 
                 0 
               
               
                   
                   
                 Lefarge Fondu Type V 
                 0 
                 66.43 
                 50.32 
               
               
                   
                 Pozzolan 
                 Lefarge NewChem Slag 
                 0 
                 0 
                 16.70 
               
               
                   
                 Titanium Dioxide 
                 Huntsman TR-60 
                 9.60 
                 0 
                 0 
               
               
                   
                 Hollow Spheres 
                   
                 2.50 
                 7.59 
                 3.27 
               
               
                   
                 Non-reactive Diluent 
                 Benzyl Alcohol 
                 3.42 
                 3.12 
                 3.57 
               
               
                   
                 Total Part A 
                   
                 100.00 
                 100.00 
                 100.00 
               
             
          
           
               
                   
                 Part B Components 
                   
               
             
          
           
               
                   
                 Water-based amine curing 
                 Cognis Waterpoxy 751 
                 14.95 
                 25.64 
                 51.87 
               
               
                   
                 agent 
                 Anquamine 287 
                 35.33 
                 10.85 
                 0 
               
               
                   
                 Titanium Dioxide 
                 Huntsman TR-60 
                   
                 27.82 
                 0 
               
               
                   
                 Concrete Super Plasticizer 
                 Lignotech Norlig 24C 
                 0.57 
                 0 
                 0 
               
               
                   
                 Latex Emulsion 
                 Synthomer 29Y46 SBR 
                 48.61 
                 0 
                 0 
               
               
                   
                   
                 Rohm &amp; Haas Rhoplex MC- 
                 0 
                 35.28 
                 0 
               
               
                   
                   
                 1834 
               
               
                   
                 Non-reactive Diluent 
                 Benzyl Alcohol 
                 0.55 
                 0.40 
                 0 
               
               
                   
                 Deionized Water 
                   
                 0 
                 0 
                 29.95 
               
               
                   
                 Corrosion Inhibitor 
                 W. R. Grace DCI S 
                 0 
                 0 
                 18.18 
               
               
                   
                 Total Part B 
                   
                 100.00 
                 100.00 
                 100.00 
               
               
                   
                   
               
             
          
           
               
                   
                 Examples 
               
             
          
           
               
                   
                 4 
                 5 
                 6 
                 7 
                 8 
                 9 
                 10 
               
               
                   
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                 Part A Components 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Epoxy Resin: 
                 13.04 
                 13.45 
                 12.20 
                 14.44 
                 10.55 
                 16.47 
                 8.23 
               
               
                 Huntsman GY6010 
               
               
                 Reactive Diluent: Air 
                 1.46 
                 1.51 
                 1.37 
                 1.62 
                 1.19 
                 1.85 
                 0.92 
               
               
                 Products Epodil 748 
               
               
                 Adhesion Promoter: 
                 0.15 
                 0.15 
                 0.14 
                 0.16 
                 0.12 
                 0.19 
                 0.09 
               
               
                 OSi Silquest A-187 
               
               
                 Portland Cement: 
                 35.82 
                 37.44 
                 38.90 
                 34.12 
                 43.08 
                 26.68 
                 42.67 
               
               
                 Lefarge Secar 71 Type V 
               
               
                 Pozzolan: Calcined 
                 7.18 
                 3.74 
                 7.78 
                 2.73 
                 10.77 
                 1.33 
                 21.34 
               
               
                 Kaolin Imerys 
               
               
                 Metastar 450 
               
               
                 Hollow Spheres: 3M 
                 2.34 
                 2.42 
                 2.19 
                 2.60 
                 1.90 
                 2.96 
                 1.48 
               
               
                 Scotchlite K37 
               
               
                 Non-reactive Diluent: 
                 2.00 
                 2.07 
                 1.87 
                 2.22 
                 1.62 
                 2.53 
                 1.26 
               
               
                 Benzyl Alcohol 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 61.99 
                 60.78 
                 64.45 
                 57.9057.89 
                 69.23 
                 52.01 
                 75.99 
               
               
                 Part B Components 
               
               
                 Water-based amine 
                 16.49 
                 17.01 
                 15.42 
                 18.26 
                 13.35 
                 20.82 
                 10.41 
               
               
                 curing agent: Cognis 
               
               
                 Waterpoxy 751 
               
               
                 Deionized Water 
                 4.74 
                 4.90 
                 4.44 
                 5.26 
                 3.84 
                 5.99 
                 3.00 
               
               
                 Latex Emulsion: 
                 16.27 
                 16.78 
                 15.22 
                 18.02 
                 13.17 
                 20.54 
                 10.27 
               
               
                 Rohm &amp; Haas 
               
               
                 Rhoplex MC-1834 
               
               
                 Non-reactive Diluent: 
                 0.18 
                 0.19 
                 0.17 
                 0.20 
                 0.15 
                 0.23 
                 0.12 
               
               
                 Benzyl Alcohol 
               
               
                 Defoamer: BYK- 
                 0.33 
                 0.34 
                 0.31 
                 0.36 
                 0.26 
                 0.41 
                 0.21 
               
               
                 Chemie BYK-011 
               
               
                 (non-silicone) 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 38.01 
                 39.22 
                 35.56 
                 42.10 
                 30.77 
                 47.99 
                 24.01 
               
               
                   
               
             
          
           
               
                   
                 Examples 
               
             
          
           
               
                   
                 11 
                 12 
                 13 
                 14 
                 15 
                 16 
                 17 
               
               
                   
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                 Part A Components 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Epoxy Resin: Huntsman 
                 11.48 
                 13.16 
                 11.74 
                 12.82 
                 10.43 
                 14.86 
                 8.53 
               
               
                 GY6010 
               
               
                 Reactive Diluent: Air 
                 1.29 
                 1.48 
                 1.32 
                 1.44 
                 1.17 
                 1.67 
                 0.96 
               
               
                 Products Epodil 748 
               
               
                 Adhesion Promoter: OSi 
                 0.13 
                 0.15 
                 0.13 
                 0.14 
                 0.12 
                 0.17 
                 0.10 
               
               
                 Silquest A-187 
               
               
                 Portland Cement: 
                 32.41 
                 27.48 
                 31.44 
                 29.65 
                 35.75 
                 20.20 
                 36.52 
               
               
                 Lefarge Secar 71 Type V 
               
               
                 Pozzolan: Fly Ash 
                 6.71 
                 2.75 
                 6.29 
                 2.37 
                 8.94 
                 1.01 
                 18.26 
               
               
                 Hollow Spheres: 3M 
                 4.27 
                 4.90 
                 4.37 
                 4.77 
                 3.88 
                 5.53 
                 3.17 
               
               
                 Scotchlite K37 
               
               
                 Non-reactive Diluent: 
                 1.76 
                 2.02 
                 1.80 
                 1.97 
                 1.60 
                 2.28 
                 1.31 
               
               
                 Benzyl Alcohol 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 58.05 
                 51.93 
                 57.10 
                 53.17 
                 61.89 
                 45.72 
                 68.85 
               
               
                 Part B Components 
               
               
                 Water-based amine 
                 14.52 
                 16.64 
                 14.85 
                 16.21 
                 13.19 
                 18.79 
                 10.78 
               
               
                 curing agent: Cognis 
               
               
                 Waterpoxy 751 
               
               
                 Deionized Water 
                 1.35 
                 1.55 
                 1.38 
                 1.51 
                 1.23 
                 1.75 
                 1.00 
               
               
                 Titanium Dioxide: 
                 11.3 
                 12.95 
                 11.55 
                 12.61 
                 10.26 
                 14.62 
                 8.39 
               
               
                 Huntsman TR-60 
               
               
                 Latex Emulsion: Rohm 
                 14.33 
                 16.42 
                 14.65 
                 16.00 
                 13.02 
                 18.54 
                 10.64 
               
               
                 &amp; Haas Rhoplex MC- 
               
               
                 1834 
               
               
                 Non-reactive Diluent: 
                 0.16 
                 0.19 
                 0.17 
                 0.18 
                 0.15 
                 0.21 
                 0.12 
               
               
                 Benzyl Alcohol 
               
               
                 Defoamer: BYK- 
                 0.29 
                 0.33 
                 0.29 
                 0.32 
                 0.26 
                 0.37 
                 0.21 
               
               
                 Chemie BYK-011 (non- 
               
               
                 silicone) 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 41.95 
                 48.07 
                 42.90 
                 46.83 
                 38.11 
                 54.28 
                 31.15 
               
               
                   
               
             
          
           
               
                   
                 Examples 
               
             
          
           
               
                   
                 18 
                 19 
                 20 
                 21 
                 22 
                 23 
                 24 
               
               
                   
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                 Part A Components 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Epoxy Resin: Huntsman 
                 13.20 
                 13.85 
                 12.62 
                 14.81 
                 10.99 
                 16.76 
                 8.73 
               
               
                 GY6010 
               
               
                 Reactive Diluent: Air 
                 1.48 
                 1.56 
                 1.42 
                 1.66 
                 1.23 
                 1.88 
                 0.98 
               
               
                 Products Epodil 748 
               
               
                 Adhesion Promoter: OSi 
                 0.15 
                 0.16 
                 0.14 
                 0.17 
                 0.12 
                 0.19 
                 0.10 
               
               
                 Silquest A-187 
               
               
                 Portland Cement: 
                 34.91 
                 35.51 
                 37.07 
                 32.24 
                 41.32 
                 25.01 
                 41.05 
               
               
                 Lefarge Fondu Type V 
               
               
                 Pozzolan: Lefarge 
                 7.00 
                 3.55 
                 7.41 
                 2.58 
                 10.33 
                 1.25 
                 20.53 
               
               
                 NewChem Slag 
               
               
                 Hollow Spheres: 3M 
                 5.06 
                 5.31 
                 4.83 
                 5.67 
                 4.21 
                 6.42 
                 3.35 
               
               
                 Scotchlite K37 
               
               
                 Non-reactive Diluent: 
                 2.03 
                 2.13 
                 1.94 
                 2.27 
                 1.69 
                 2.57 
                 1.34 
               
               
                 Benzyl Alcohol 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 63.83 
                 62.05 
                 65.43 
                 59.41 
                 69.89 
                 54.08 
                 76.07 
               
               
                 Part B Components 
               
               
                 Water-based amine 
                 16.07 
                 16.86 
                 15.36 
                 18.03 
                 13.38 
                 20.40 
                 10.63 
               
               
                 curing agent: Cognis 
               
               
                 Waterpoxy 751 
               
               
                 Deionized Water 
                 3.83 
                 4.02 
                 3.66 
                 4.30 
                 3.19 
                 4.86 
                 2.53 
               
               
                 Latex Emulsion: 
                 15.77 
                 16.55 
                 15.08 
                 17.70 
                 13.13 
                 20.02 
                 10.43 
               
               
                 Synthomer 29Y46 SBR 
               
               
                 Non-reactive Diluent: 
                 0.18 
                 0.19 
                 0.17 
                 0.20 
                 0.15 
                 0.23 
                 0.12 
               
               
                 Benzyl Alcohol 
               
               
                 Defoamer: BYK- 
                 0.32 
                 0.33 
                 0.30 
                 0.36 
                 0.27 
                 0.40 
                 0.21 
               
               
                 Chemie BYK-011 (non- 
               
               
                 silicone) 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 36.17 
                 37.95 
                 34.57 
                 40.59 
                 30.11 
                 45.92 
                 23.93 
               
               
                   
               
             
          
           
               
                   
                 Examples 
               
             
          
           
               
                   
                 25 
                 26 
                 27 
                 28 
                 29 
                 30 
                 31 
               
               
                   
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                 Part A Components 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Epoxy Resin: Huntsman 
                 11.81 
                 13.16 
                 12.16 
                 13.92 
                 10.80 
                 15.40 
                 8.82 
               
               
                 GY6010 
               
               
                 Reactive Diluent: Air 
                 1.33 
                 1.48 
                 1.37 
                 1.56 
                 1.21 
                 1.73 
                 0.99 
               
               
                 Products Epodil 748 
               
               
                 Adhesion Promoter: OSi 
                 0.13 
                 0.15 
                 0.14 
                 0.16 
                 0.12 
                 0.17 
                 0.10 
               
               
                 Silquest A-187 
               
               
                 Portland Cement: 
                 33.32 
                 29.83 
                 31.59 
                 26.78 
                 35.90 
                 20.33 
                 36.65 
               
               
                 Lefarge Secar 71 White 
               
               
                 Type V (Calcium 
               
               
                 Aluminate) 
               
               
                 Pozzolan: Silica Fume 
                 6.66 
                 2.98 
                 6.32 
                 2.14 
                 8.97 
                 1.02 
                 18.32 
               
               
                 Hollow Spheres: 3M 
                 1.81 
                 2.01 
                 1.86 
                 2.13 
                 1.65 
                 2.36 
                 1.35 
               
               
                 Scotchlite K37 
               
               
                 Non-reactive Diluent: 
                 1.81 
                 2.02 
                 1.87 
                 2.14 
                 1.66 
                 2.37 
                 1.35 
               
               
                 Benzyl Alcohol 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 56.87 
                 51.63 
                 55.30 
                 48.83 
                 60.31 
                 43.37 
                 67.58 
               
               
                 Part B Components 
               
               
                 Water-based amine 
                 14.93 
                 17.07 
                 15.77 
                 18.05 
                 14.00 
                 19.98 
                 11.44 
               
               
                 curing agent: Cognis 
               
               
                 Waterpoxy 751 
               
               
                 Deionized Water 
                 1.39 
                 0.65 
                 0.61 
                 0.69 
                 0.54 
                 0.77 
                 0.44 
               
               
                 Titanium Dioxide: 
                 11.62 
                 13.28 
                 12.27 
                 14.05 
                 10.90 
                 15.55 
                 8.90 
               
               
                 Huntsman TR-60 
               
               
                 Latex Emulsion: Rohm 
                 14.73 
                 16.84 
                 15.56 
                 17.81 
                 13.82 
                 19.72 
                 11.29 
               
               
                 &amp; Haas Rhoplex MC- 
               
               
                 1834 
               
               
                 Non-reactive Diluent: 
                 0.17 
                 0.19 
                 0.18 
                 0.20 
                 0.16 
                 0.22 
                 0.13 
               
               
                 Benzyl Alcohol 
               
               
                 Defoamer: BYK-Chemie 
                 0.30 
                 0.34 
                 0.31 
                 0.36 
                 0.28 
                 0.40 
                 0.23 
               
               
                 BYK-011 (non-silicone) 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 43.13 
                 48.37 
                 44.70 
                 51.17 
                 39.69 
                 56.63 
                 32.42 
               
               
                   
               
             
          
           
               
                   
                 Examples 
               
             
          
           
               
                   
                 32 
                 33 
                 34 
                 35 
                 36 
                 37 
                 38 
               
               
                   
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                 Part A Components 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Epoxy Resin: Huntsman 
                 13.23 
                 13.65 
                 12.37 
                 14.66 
                 10.70 
                 16.72 
                 8.43 
               
               
                 GY6010 
               
               
                 Reactive Diluent: Air 
                 1.49 
                 1.53 
                 1.39 
                 1.65 
                 1.20 
                 1.88 
                 0.95 
               
               
                 Products Epodil 748 
               
               
                 Adhesion Promoter: OSi 
                 0.15 
                 0.15 
                 0.14 
                 0.16 
                 0.12 
                 0.19 
                 0.09 
               
               
                 Silquest A-187 
               
               
                 Portland Cement: 
                 35.89 
                 37.53 
                 38.98 
                 34.20 
                 43.16 
                 26.75 
                 42.49 
               
               
                 Federal Type I 
               
               
                 Pozzolan: Calcined 
                 7.20 
                 3.75 
                 7.80 
                 2.74 
                 10.79 
                 1.34 
                 21.25 
               
               
                 Kaolin Imerys Metastar 
               
               
                 450 
               
               
                 Hollow Spheres: 3M 
                 1.93 
                 1.99 
                 1.80 
                 2.13 
                 1.56 
                 2.43 
                 1.23 
               
               
                 Scotchlite K37 
               
               
                 Non-reactive Diluent: 
                 2.03 
                 2.10 
                 1.90 
                 2.25 
                 1.64 
                 2.57 
                 1.29 
               
               
                 Benzyl Alcohol 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 61.921 
                 60.70 
                 64.38 
                 57.79 
                 69.18 
                 51.87 
                 75.73 
               
               
                 Part B Components 
               
               
                 Water-based amine 
                 16.52 
                 17.05 
                 15.45 
                 18.31 
                 13.37 
                 20.88 
                 10.53 
               
               
                 curing agent: Cognis 
               
               
                 Waterpoxy 751 
               
               
                 Deionized Water 
                 4.76 
                 4.91 
                 4.45 
                 5.27 
                 3.85 
                 6.01 
                 3.03 
               
               
                 Latex Emulsion: Rohm 
                 16.30 
                 16.82 
                 15.25 
                 18.06 
                 13.19 
                 20.60 
                 10.39 
               
               
                 &amp; Haas Rhoplex MC- 
               
               
                 1834 
               
               
                 Non-reactive Diluent: 
                 0.18 
                 0.19 
                 0.17 
                 0.20 
                 0.15 
                 0.23 
                 0.12 
               
               
                 Benzyl Alcohol 
               
               
                 Defoamer: BYK- 
                 0.33 
                 0.34 
                 0.31 
                 0.36 
                 0.27 
                 0.41 
                 0.21 
               
               
                 Chemie BYK-011 (non- 
               
               
                 silicone) 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 38.09 
                 39.30 
                 35.62 
                 42.21 
                 30.82 
                 48.13 
                 24.27 
               
               
                   
               
             
          
           
               
                   
                 Examples 
               
             
          
           
               
                   
                 39 
                 40 
                 41 
                 42 
                 43 
                 44 
                 45 
               
               
                   
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                 Part A Components 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Epoxy Resin: Huntsman 
                 13.07 
                 13.49 
                 12.23 
                 14.49 
                 10.58 
                 16.52 
                 8.33 
               
               
                 GY6010 
               
               
                 Reactive Diluent: Air 
                 1.47 
                 1.52 
                 1.37 
                 1.63 
                 1.19 
                 1.86 
                 0.94 
               
               
                 Products Epodil 748 
               
               
                 Adhesion Promoter: OSi 
                 0.15 
                 0.15 
                 0.14 
                 0.16 
                 0.12 
                 0.19 
                 0.09 
               
               
                 Silquest A-187 
               
               
                 Portland Cement: 
                 35.91 
                 37.55 
                 39.00 
                 34.23 
                 43.18 
                 26.77 
                 42.51 
               
               
                 Federal Type I 
               
               
                 Pozzolan: Lefarge 
                 7.20 
                 3.75 
                 7.80 
                 2.74 
                 10.79 
                 1.34 
                 21.25 
               
               
                 NewChem Slag 
               
               
                 Hollow Spheres: 3M 
                 2.08 
                 2.14 
                 1.94 
                 2.30 
                 1.68 
                 2.63 
                 1.32 
               
               
                 Scotchlite K37 
               
               
                 Non-reactive Diluent: 
                 2.01 
                 2.07 
                 1.88 
                 2.22 
                 1.62 
                 2.54 
                 1.28 
               
               
                 Benzyl Alcohol 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 61.89 
                 60.68 
                 64.36 
                 57.77 
                 69.16 
                 51.83 
                 75.72 
               
               
                 Part B Components 
               
               
                 Water-based amine 
                 16.53 
                 17.06 
                 15.46 
                 18.32 
                 13.37 
                 20.89 
                 10.53 
               
               
                 curing agent: Cognis 
               
               
                 Waterpoxy 751 
               
               
                 Deionized Water 
                 4.76 
                 4.91 
                 4.45 
                 5.27 
                 3.85 
                 6.01 
                 3.03 
               
               
                 Latex Emulsion: Rohm 
                 16.31 
                 16.83 
                 15.25 
                 18.07 
                 13.20 
                 20.61 
                 10.39 
               
               
                 &amp; Haas Rhoplex MC- 
               
               
                 1834 
               
               
                 Non-reactive Diluent: 
                 0.18 
                 0.19 
                 0.17 
                 0.20 
                 0.15 
                 0.23 
                 0.12 
               
               
                 Benzyl Alcohol 
               
               
                 Defoamer: BYK- 
                 0.33 
                 0.34 
                 0.31 
                 0.36 
                 0.27 
                 0.41 
                 0.21 
               
               
                 Chemie BYK-011 (non- 
               
               
                 silicone) 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 38.11 
                 39.32 
                 35.64 
                 42.23 
                 30.84 
                 48.17 
                 24.28 
               
               
                   
               
             
          
           
               
                   
                 Examples 
               
             
          
           
               
                   
                 46 
                 47 
                 48 
                 49 
                 50 
                 51 
                 52 
               
               
                   
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                 Part A Components 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Epoxy Resin: Huntsman 
                 13.11 
                 13.53 
                 12.26 
                 14.53 
                 10.60 
                 16.58 
                 8.34 
               
               
                 GY6010 
               
               
                 Reactive Diluent: Air 
                 1.47 
                 1.52 
                 1.38 
                 1.63 
                 1.19 
                 1.86 
                 0.94 
               
               
                 Products Epodil 748 
               
               
                 Adhesion Promoter: OSi 
                 0.15 
                 0.15 
                 0.14 
                 0.16 
                 0.12 
                 0.19 
                 0.09 
               
               
                 Silquest A-187 
               
               
                 Portland Cement: 
                 36.02 
                 37.66 
                 39.10 
                 34.33 
                 43.28 
                 26.86 
                 42.58 
               
               
                 Federal Type I 
               
               
                 Pozzolan: Silica Fume 
                 7.22 
                 3.77 
                 7.82 
                 2.75 
                 10.82 
                 1.34 
                 21.29 
               
               
                 Hollow Spheres: 3M 
                 1.80 
                 1.86 
                 1.68 
                 2.00 
                 1.46 
                 2.28 
                 1.15 
               
               
                 Scotchlite K37 
               
               
                 Non-reactive Diluent: 
                 2.01 
                 2.08 
                 1.88 
                 2.23 
                 1.63 
                 2.55 
                 1.28 
               
               
                 Benzyl Alcohol 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 61.78 
                 60.56 
                 64.26 
                 57.64 
                 69.09 
                 51.66 
                 75.68 
               
               
                 Part B Components 
               
               
                 Water-based amine 
                 16.58 
                 17.11 
                 15.50 
                 18.38 
                 13.41 
                 20.97 
                 10.55 
               
               
                 curing agent: Cognis 
               
               
                 Waterpoxy 751 
               
               
                 Deionized Water 
                 4.77 
                 4.92 
                 4.46 
                 5.29 
                 3.86 
                 6.03 
                 3.04 
               
               
                 Latex Emulsion: Rohm 
                 16.36 
                 16.88 
                 15.29 
                 18.13 
                 13.23 
                 20.69 
                 10.41 
               
               
                 &amp; Haas Rhoplex MC- 
               
               
                 1834 
               
               
                 Non-reactive Diluent: 
                 0.18 
                 0.19 
                 0.17 
                 0.20 
                 0.15 
                 0.23 
                 0.12 
               
               
                 Benzyl Alcohol 
               
               
                 Defoamer: BYK- 
                 0.33 
                 0.34 
                 0.31 
                 0.36 
                 0.27 
                 0.42 
                 0.21 
               
               
                 Chemie BYK-011 (non- 
               
               
                 silicone) 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 38.22 
                 39.44 
                 35.74 
                 42.36 
                 30.91 
                 48.34 
                 24.32 
               
               
                   
               
             
          
           
               
                   
                 Examples 
               
             
          
           
               
                   
                 53 
                 54 
                 55 
                 56 
                 57 
                 58 
                 59 
               
               
                   
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                 Part A Components 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Epoxy Resin: 
                 12.12 
                 13.51 
                 12.49 
                 14.29 
                 11.09 
                 15.81 
                 9.62 
               
               
                 Huntsman GY6010 
               
               
                 Reactive Diluent: Air 
                 1.36 
                 1.52 
                 1.40 
                 1.61 
                 1.25 
                 1.73 
                 1.08 
               
               
                 Products Epodil 748 
               
               
                 Adhesion Promoter: 
                 0.14 
                 0.15 
                 0.14 
                 0.16 
                 0.12 
                 0.18 
                 0.11 
               
               
                 OSi Silquest A-187 
               
               
                 Portland Cement: Type I 
                 39.58 
                 32.67 
                 37.76 
                 28.80 
                 44.72 
                 21.23 
                 58.20 
               
               
                 Hollow Spheres: 3M 
                 2.28 
                 2.54 
                 2.35 
                 2.68 
                 2.08 
                 2.97 
                 1.81 
               
               
                 Scotchlite K37 
               
               
                 Non-reactive Diluent: 
                 1.86 
                 2.07 
                 1.92 
                 2.19 
                 1.70 
                 2.43 
                 1.48 
               
               
                 Benzyl Alcohol 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 57.34 
                 52.46 
                 56.06 
                 49.73 
                 60.97 
                 44.39 
                 72.29 
               
               
                 Part B Components 
               
               
                 Water-based amine 
                 4.63 
                 5.16 
                 4.77 
                 5.45 
                 4.23 
                 6.03 
                 3.01 
               
               
                 curing agent: 
               
               
                 Anquamine 287 
               
               
                 Water-based amine 
                 10.93 
                 12.18 
                 11.26 
                 12.89 
                 10.00 
                 14.26 
                 7.10 
               
               
                 curing agent: 
               
               
                 Waterpoxy 751 
               
               
                 Titanium Dioxide: 
                 11.86 
                 13.22 
                 12.22 
                 13.98 
                 10.85 
                 15.47 
                 7.71 
               
               
                 Huntsman TR-60 
               
               
                 Latex Emulsion: 
                 15.05 
                 16.77 
                 15.50 
                 17.73 
                 13.77 
                 19.61 
                 9.77 
               
               
                 Synthomer 29Y46 SBR 
               
               
                 Non-reactive Diluent: 
                 0.17 
                 0.19 
                 0.18 
                 0.20 
                 0.16 
                 0.22 
                 0.11 
               
               
                 Benzyl Alcohol 
               
               
                 Corrosion Inhibitor: 
                 0.02 
                 0.02 
                 0.02 
                 0.02 
                 0.02 
                 0.02 
                 0.01 
               
               
                 Cortec MCI-2000 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                 42.66 
                 47.54 
                 43.94 
                 50.27 
                 39.03 
                 55.61 
                 27.71 
               
               
                   
               
             
          
         
       
     
         [0032]    Further embodiments of the composition are described by the following untested examples. The following examples are provide by way of illustration not limitation, and the changes reflected are equally applicable to each of the compositions specifically described in Examples 1 through 59. 
         [0000]    
       
         
               
               
             
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
               
             
               
               
             
               
               
               
             
               
               
               
               
             
               
               
               
             
               
               
               
               
             
           
               
                   
                   
               
             
             
               
                   
                 Untested Examples 
               
             
          
           
               
                   
                 60 
                 61 
                 62 
                 63 
                 64 
               
               
                   
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                 Part A Components 
                   
               
             
          
           
               
                 Epoxy Resin 
                 Huntsman GY6010 
                 14.31 
                 13.04 
                 13.04 
                 11.48 
                 12.12 
               
               
                 Reactive Diluent 
                 Air Products Epodil 
                 1.61 
                 1.46 
                 1.46 
                 1.29 
                 1.36 
               
               
                   
                 748 
               
               
                 Adhesion 
                 OSi Silquest A-187 
                 0.16 
                 0.15 
                 0.15 
                 0.13 
                 0.14 
               
               
                 Promoter 
               
               
                 Portland Cement 
                 Type I 
                 38.15 
                 0 
                 0 
                 0 
                 39.58 
               
               
                   
                 Type V 
                 0 
                 35.82 
                 35.82 
                 32.41 
                 0 
               
               
                 Pozzolan 
                 Calcined Kaolin 
                 0 
                 7.18 
                 7.18 
                 0 
                 0 
               
               
                   
                 Fly Ash 
                 0 
                 0 
                 0 
                 6.71 
                 0 
               
               
                 Titanium Dioxide 
                 Huntsman TR-60 
                 6.16 
                 0 
                 0 
                 0 
                 0 
               
               
                 Hollow Spheres 
                   
                 1.61 
                 2.34 
                 2.34 
                 4.27 
                 2.28 
               
               
                 Non-reactive 
                 Rutgers Novares LS 
                 2.20 
                 2.00 
                 2.00 
                 1.76 
                 1.86 
               
               
                 Diluent 
                 500 
                   
                   
                   
                   
                   
               
               
                 Sub-total 
                   
                 64.19 
                 61.99 
                 61.99 
                 58.06 
                 57.34 
               
             
          
           
               
                 Part B Components 
                   
               
             
          
           
               
                 Water-based amine 
                 Cognis Waterpoxy 
                 5.35 
                 16.49 
                 16.49 
                 14.52 
                 10.93 
               
               
                 curing agent 
                 751 
               
               
                   
                 Anquamine 287 
                 12.65 
                 0 
                 0 
                 0 
                 4.63 
               
               
                 Deionized Water 
                   
                   
                 4.74 
                 4.74 
                 1.35 
                 0 
               
               
                 Titanium Dioxide 
                 Huntsman TR-60 
                 0 
                 0 
                 0 
                 11.30 
                 11.86 
               
               
                 Concrete Super 
                 Lignotech Norlig 24C 
                 0.20 
                 0 
                 0 
                 0 
                 0 
               
               
                 Plasticizer 
               
               
                 Latex Emulsion 
                 Synthomer 29Y46 
                 17.41 
                 0 
                 0 
                 0 
                 15.05 
               
               
                   
                 SBR 
               
               
                   
                 Rohm &amp; Haas 
                 0 
                 16.27 
                 16.27 
                 14.33 
                 0 
               
               
                   
                 Rhoplex MC-1834 
               
               
                 Non-reactive 
                 Benzyl Alcohol 
                 0 
                 0.18 
                 0 
                 0 
                 0 
               
               
                 Diluent 
                 Rutgers Novares LS 
                 0.2 
                 0 
                 0.18 
                 0.16 
                 0.17 
               
               
                   
                 500 
               
               
                 Defoamer 
                 BYK-Chemie BYK- 
                 0 
                 0 
                 0.16 
                 0 
                 0 
               
               
                   
                 011 (non-silicone) 
               
               
                   
                 Tego Foamex 805 
                 0 
                 0.33 
                 0.17 
                 0.29 
                 0 
               
               
                   
                 (silicone) 
               
               
                 Corrosion Inhibitor 
                 Cortec MCI-2000 
                 0 
                 0 
                 0 
                 0 
                 0.02 
               
               
                 Sub-total 
                   
                 35.81 
                 38.01 
                 38.01 
                 41.94 
                 42.66 
               
               
                   
               
             
          
           
               
                   
                 Untested Examples 
               
               
                   
                 65 
               
               
                   
                 Weight % 
               
               
                   
                   
               
             
          
           
               
                   
                 Part A Components 
                   
               
             
          
           
               
                   
                 Liquid Amine Resin 
                 Huntsman Jeffamine D-400 
                 14.45 
               
               
                   
                 Portland Cement 
                 Lehigh Type I 
                 42.01 
               
               
                   
                 Hollow Spheres 
                 Scotchlite K-37 Glass Bubbles 
                 2.41 
               
               
                   
                 Sub-total 
                   
                 58.86 
               
             
          
           
               
                   
                 Part B Components 
                   
               
             
          
           
               
                   
                 Water-dispersed Epoxy Resin 
                 Resolution Epi-Rez 3510-W-60 
                 41.14 
               
               
                   
                 Sub-total 
                   
                 41.14 
               
               
                   
                   
               
             
          
         
       
     
         [0033]    Thus, in various embodiments, the composition of the present invention broadly comprises some or all of the following components: an epoxy resin of, in one embodiment, between 8.0% to 23.0% by weight, and, in another embodiment, between 10% to 42% by weight; a powdered hydraulic cement of, in one embodiment, between 20.0% to 72.0% by weight and, in another embodiment, between 46% to 90% by weight; water in an amount at least sufficient to react with the cement; a curing agent of, in one embodiment, between 5.0% to 21.0% by weight, and, in another embodiment, between 30% to 60%; a non-reactive diluent of between 0.1% to 3.3% by weight; a reactive diluent of, in one embodiment, between 0.8% to 2.6% by weight, and, in another embodiment, between 1.1% to 4.8% by weight; a pigment of between 6.0% to 24.0% by weight; an organosilicon adhesion promoter of, in one embodiment, between 0.08% to 0.26% by weight, and, in another embodiment, between 0.1% to 0.5%; a water-based latex resin of between 4.0% to 31.0% by weight; a plurality of hollow spheres of, in one embodiment, between 1.0% to 8.0% by weight, and, in another embodiment, between 1% to 13% by weight; a defoamer of between 0.5% to 1.0% by weight; a non-silicon defoamer of between 0.15% to 0.55% by weight; a silicone defoamer of between 0.15% to 0.55% by weight; a corrosion inhibitor of, in one embodiment, between 0.01% to 2.4% by weight, and, in another embodiment, of between 0.04% to 18.5% by weight; a concrete plasticizer of between 0.2% to 0.6% by weight; and/or a latex resin of between 30% to 50% by weight. Characterized another way, one embodiment of the composition of the present invention broadly comprises approximately 90 parts epoxy resin mixed with approximately 10 parts reactive diluent to produce a mixture, and approximately 1 part hydraulic cement powder mixed with approximately 0.11 to 1.5 parts of the aforementioned mixture, to ultimately produce the coating composition having between 0.80 to 1.30 equivalents of total epoxy groups to 1.00 equivalent of reactive amine groups. In various embodiments, the composition forms a coat having a thickness of approximately between 2 mils to 15 mils. 
         [0034]    Any of the disclosed embodiments of the claimed composition may be used in a process to protectively coat a surface. The process involves preparing the composition according to the present invention, mixing the two parts with an appropriate amount of water, and applying the coating to the surface. The formula may be applied with a brush, roller or airless sprayer and will achieve a high build film in a single application, although multiple coats may be applied at the discretion of the user. 
         [0035]    Thus, a waterborne epoxy composition is disclosed which utilizes hydraulic cement powder as an element of the epoxy composition to provide a desired initial application coat thickness with good fluidity and enhanced cure time while still providing protection against corrosion and other environmental threats. The coating composition also provides corrosion resistance equal to organic solvent based and solvent free coatings. 
         [0036]    While preferred embodiments and particular applications of this invention have been shown and described, it is apparent to those skilled in the art that many other modifications and applications of this invention are possible, including using the teaching to develop coating compositions having three or more components, without departing from the inventive concepts herein. It is, therefore, to be understood that, within the scope of the appended claims, this invention may be practiced otherwise than as specifically described, and the invention is not to be restricted except in the spirit of the appended claims. Though some of the features of the invention may be claimed in dependency, each feature has merit if used independently.