Abstract:
A method for minimizing formation damage during gravel packing operations in a loosely consolidated hydrocarbonaceous fluid producing formation penetrated by at least one well. Solidifiable chemical blocking agents are used to keep intrusive fluids, e.g. kill fluids, from the hydrocarbonaceous fluid producing interval of said formation during said gravel packing operation. Said blocking agents comprise gels wherein amino resins such as melamine formaldehyde (&#34;MF&#34;) resins co-gel and crosslink with polymers useful for profile control where said polymers have amine, amide, hydroxyl and thiol functionalities.

Description:
Cross-Reference to Related Applications 
     This application is a continuation-in-part of U.S. Ser. No. 769,223, filed on Aug. 26, 1985, now U.S. Pat. No. 4,664,191, and U.S. Ser. No. 917,324, filed on Oct. 9, 1986. 
    
    
     FIELD OF THE INVENTION 
     This invention relates to a method for gravel packing formations using a solidifiable blocking agent in combination with a gravel pack operation to minimize formation damage. 
     BACKGROUND OF THE INVENTION 
     Sand consolidation and gravel packing are two near wellbore techniques widely used for controlling the production of sand from producing wells such as oil wells, gas wells and similar boreholes. In many instances, highly porous and fragmentable sand formations surround a wellbore. Under production conditions, the sand is often displaced from its aggregated structure and carried along by the fluid flood operations to a producing well. If the sand flow is allowed to proceed unchecked, the producing wellbore soon becomes full of sand, thereby clogging the wellbore and impeding oil production. Furthermore, sand arriving at the surface site of the well erodes the production hardware. 
     As more and more sand is displaced from its original formation, a region of wash-out cavities surrounding the wellbore region results. As the wash-out zones become more extensive, the integrity of the wellbore is threatened and a danger of the wellbore collapsing exists. 
     It has therefore been the subject of extensive and intense research by the petroleum industry to develop techniques to minimize or obviate displacement of sand particles into producing well areas and prevent the formation of wash-out cavities surrounding the wellbore. One such general approach suggested by the art is to consolidate the coarse sand structures prior to fluid production. Sand consolidation techniques are aimed at cementing loose sand structures adjacent a wellbore. Such consolidation is effective to prevent breakdown of sand formation and subsequent clogging of producing wells. 
     In many loosely consolidated or unconsolidated formations, it is not economically or practically feasible to consider sand consolidation techniques. Also, there are many instances where substantial wash-out cavities are either initially present naturally near the wellbore or washed-out cavities form around the wellbore after prolonged use despite previous attempts at sand consolidation. 
     For these conditions, gravel packing techniques are often used to prevent formation sand production or further erosion and to reestablish the integrity of the wellbore periphery. Gravel packing is a secondary sand consolidation technique involving the introduction of a fluid suspension of exogenous particulate matter downhole, to fill the wash-out cavities or to &#34;squeeze&#34; to pack into the formation in the vicinity of the well. The term gravel is somewhat loosely applied in the art to encompass hard, rigid particulate matter ranging in size from a coarse sand to pebble size material. 
     Once the placement of sand and gravel has been accomplished, a slotted liner or &#34;screen&#34; placed as part of the production string helps hold the loose filling material and retard the upstream sand flow through the filler material during production conditions. 
     Present gravel pack procedures often require a filling of the casing with weighted completion fluid or drilling mud prior to perforating. Thereafter, the production casing is perforated via a casing gun with shots placed in a helical arrangement. Substantial amounts of wellbore fluid are often lost as in most instances the wellbore is in an overbalanced condition. If the well is not completely dead following the perforation operation, it is generally &#34;killed&#34; so the perforating tool can be pulled from the borehole. After pulling the perforating tool from the borehole, the production tubing along with a slotted liner is directed into the borehole. As a result of these operations, substantial amounts of expensive workover fluid can be lost during these operations. Because of the density, viscosity and chemical makeup of these workover fluids, damage often occurs to the permeability of a formation. Afterwards, in order to stabilize the sand in the formation, an in-casing gravel pack is generally placed within the wellbore along with additional fluids and chemicals. This results often in additional damage to the permeability of the formation. Preventing damage is made more difficult when the formation contains substantially high temperatures and salinities. 
     Therefore, what is needed is a gravel pack method which will minimize the permeability damage to the formation caused by workover fluids and chemicals under substantially high temperature and high salinity conditions. 
     SUMMARY OF THE INVENTION 
     This invention is directed to a method for minimizing formation damage during gravel pack operations in loosely consolidated formations penetrated by at least one well where substantially high temperatures and high salinity conditions are encountered. In the practice of this invention, the casing of said well is filled with an underbalanced completion fluid. Afterwards, a removable packer capable of isolating the space between said casing and which also separates the formation from the downhole well pressure is placed within said well. A first tubing suitable for perforating and stabilizing the flow of fluids into said well is set through said packer. To obtain fluid communication with the formation, said first tubing along with the casing is perforated. 
     In order to isolate the formation, a blocking agent is placed into said formation via said perforations. The blocking agent is then allowed to solidify while forming a solidified plug within the wellbore. 
     Subsequently, the first tubing and retrievable packer is removed from said well. After removing said first tubing from the well, a second tubing having a slotted portion therein which is sufficient to contact said perforation is placed within said well. 
     The solid plug formed by said blocking agent is removed from the wellbore by circulating fluid while running tubing into the well. Thereafter, a gravel pack is placed within said well around said slotted portion of said tubing and within said formation adjacent to said slotted portion of the pipe. Said blocking agent is caused to liquefy in a manner to flow from said formation into said well. The blocking agent comprises an aminoplast resin containing a methyol group and its alkylated varieties which are reactive with a polymer having at least one functional group selected from a member of the group consisting of an amine, an amide, a hydroxyl, or a thiol. Said methyol group and its alkylated varieties contained on said resin can condense to form a cured resin. 
     It is therefore an object of this invention to minimize formation damage using a temporary gel plug to isolate a formation wherein a gravel pack is utilized which plug is formed form economical aminoplast resins which co-gel and crosslink with substantially all polymers. 
     It is another object of this invention to provide a blocking agent which has a gelation reaction which can proceed under all pH conditions encountered in a hydrocarbonaceous reservoir when performing a gravel pack operation. 
     It is a yet further object of this invention to provide for a blocking agent which forms a substantially stable gel when high temperatures are encountered in a reservoir when performing a gravel pack operation. 
     It is a still yet further object of this invention to provide for a blocking agent formed by a gelation reaction which will proceed in a saline hydrocarbonaceous reservoir environment while performing a gravel pack operation. 
     It is a still further object of this invention to protect the integrity of a formation which is sensitive to fluid intrusion from chemicals and workover fluids. 
     It is a yet further object of the present invention to use a temporary gel plug in conjunction with a gravel pack operation in order to prevent sand fines from plugging the pores of a formation and pores near the wellbore where said gel plug is formed from a novel gel composition. 
     It is a still yet further object of this invention to increase the production of hydrocarbonaceous fluids from a hydrocarbonaceous fluid producing formation. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a schematic view of the formation showing an invaded zone where workover and chemical fluids have entered the formation. 
     FIG. 2 is a schematic view of the formation showing an in-casing gravel pack and a gravel pack within the washed out portion of the formation or reservoir. 
    
    
     DESCRIPTION OF PREFERRED EMBODIMENTS 
     It is a purpose of this invention to provide a method for minimizing formation damage caused by the introduction of fluids into an unconsolidated formation or reservoir, particularly hydrocarbonaceous bearing ones. Formation damage is minimized by avoiding the introduction of fluids having high densities, high viscosities and fluid which contain high concentrations of solids. In some formations, these fluids may destroy the salinity balance and cause a dislodgement of fines which can lead to a plugging of the pores within the formation. 
     In the practice of this invention, as shown in FIG. 2, a well 4 has penetrated the subterranean formation 2. A cement sheath 8 surrounds casing 6. A packer 16 is run in on tubing and set in the well 4 to isolate that portion of the well penetrating the formation 2 from the portion of the well there above. Said tubing is filled with an underbalanced completion fluid. Afterwards, a &#34;through tubing&#34; perforating gun is used to perforate the casing. A reliable gun such as Schlumberger&#39;s 25/8 inch Enerjet can be used. A high pressure lubricator can also be used to allow perforating under pressure. Other methods of perforating the casing are discussed in U.S. Pat. No. 3,983,941 issued to Fitch on Oct. 5, 1976, and which is hereby incorporated by reference. The perforating gun is then removed from the tubing. If a lubricator has been used, the perforating gun can be removed through the lubricator. Afterwards, approximately 50 barrels of a fluid compatible with the formation such as KCl or NaCl brine, which is obtainable from various service companies is placed through the tubing. The purpose of this fluid is to condition the formation so as to be receptive to a chemical blocking agent. 
     Thereafter, a chemical blocking agent is introduced into the formation by said first tubing. The volume of said chemical blocking agent is determined based upon the extent of the perforated interval and the capacity of the formation area desired to be blocked. A chemical blocking agent which can be used is a novel gel. These gels are formed from polymers having functional groups such as NH 2 , --CONH 2 , --OH, and --SH. Said polymers can be gelled with methylated, MF resins. A melamine formaldehyde (&#34;MF&#34;) resin which can be used is formed as a reaction product of melamine and formaldehyde. Said resin is known as an aminoplast or amino resin which comprises a class of thermo-setting resins made by the reaction of an amine with an aldehyde. The resultant resin is reacted with a crosslinkable polymer in an aqueous medium under all pH conditions and needs no catalyst. Said polymer has at least one functional group selected from a member of the group consisting of an amine, an amide, a hydroxyl, or a thiol group. This reaction can be carried out at ambient conditions, and also under conditions occurring in a subterranean hydrocarbonaceous formation. 
     These gels are novel in that they are unaffected by high saline concentrations often encountered in oil reservoirs. High temperatures encountered in said reservoirs do not adversely affect said gels. Carbonate, bicarbonate, and sulfate anions encountered in oil reservoirs which are known to affect certain metal crosslinked gels, but do not affect these novel gels. These novel gels can be formed under all pH conditions and are particularly useful in pH conditions of 10 or less. A method for making a kindred gel is discussed in U.S. Pat. No. 4,157,322 which issued to Colegrove on June 5, 1979. Unlike Colegrove, the instant gelation reaction is not catalyzed by a salt which is acid generating upon the application of heat. This patent is hereby incorporated by reference. 
     Gels utilized as chemical blocking agents herein can be made from various related materials. These materials will be discussed later. 
     If the formation is over-pressured, which means the reservoir pressure is greater than the hydrostatic pressure of water (0.433 psi/ft) standing in the wellbore, the volume of chemical blocking agent should be prepared from the high density brine. As is anticipated, a relatively small amount, usually less than about 50 barrels, of the liquefied chemical blocking agent is required to isolate the perforated interval and the washed out portion of the formation surrounding well 4 as shown in FIG. 2. After about 2 to about 4 hours, the chemical blocking agent sets up and solidifies. Subsequently, a high density brine of about 10 weight percent sodium chloride to about 28 weight percent sodium chloride is injected into said first tubing on top of the solidified chemical blocking agent. Placement of the high density brine solution on top of the solidified chemical blocking agent allows the first tubing or &#34;work string&#34; to be removed from the well 4. Upon solidification, the chemical blocking agent also protects the formation 2, as shown in FIG. 2, and the washed out area surrounding the wellbore 4, while forming a solidified plug within well 4. 
     Once said first tubing or &#34;work string&#34; has been removed from well 4, a production string having a slotted liner assembly 12 is placed into well 4 and penetrates the solidified chemical blocking agent. The slotted liner portion of production string 12 allows contact to be made through the perforations and into the washed out areas surrounding the wellbore for placement of a gravel pack. Thereafter, depending upon the composition of the solidified chemical blocking agent, said solidified blocking agent can be removed by either chemical or physical means. 
     In order to establish a gravel pack 10 as shown in FIG. 2, it is necessary to remove the solified chemical blocking agent as discussed above, either by chemical or mechanical means. Upon removal of the solidified chemical blocking agent from the well 4, a gravel pack placement operation can begin. Gravel packing methods are known to those skilled in the art. A preferred consolidatable gravel pack method is disclosed by Friedman in U.S. Pat. No. 4,428,427 which issued on Jan. 31, 1984 and which is hereby incorporated by reference. This gravel packing operation immediately follows the removal of the solidified chemical blocking agent from said washed out portion of the formation surrounding the well and also removal of said chemical blocking agent from the core of well 4. A preferred method for the removal of the solidified chemical blocking agent from the formation, the washed out area surrounding the well 4, and within the well is to have a gel composition which liquefies within a specified period of time. In this manner, the chemical blocking agent is allowed to flow from the formation 2 into wellbore 4. Gel compositions which are suitable for use in this preferred embodiment will be discussed later. 
     After removing the solidified blocking agent from the washed out portion of said formation and the wellbore, a gravel pack 10 is placed within the well 4 and the washed out portion of the formation surrounding the well 4. The gravel pack which is placed into the washed out area and in the well around the slotted portion of tubing 12 is sufficient to prevent fines migration from the formation into the well. Placement of said gravel pack consolidates the sand within the formation and allows fluid communication between the formation and said wellbore for the production of hydrocarbonaceous fluids. 
     FIG. 1 shows damage resultant from placement of a gravel pack without benefit of this invention. As shown in FIG. 1, the &#34;invaded&#34; zone 18 has resulted because of the placement or injection of consolidation fluids, workover fluids and chemicals (&#34;intrusive fluids&#34;) which have penetrated the formation zone in a manner to cause a blocking of the pores within the formation. In the practice of the method disclosed above, and as is shown in FIG. 2, said &#34;invaded&#34; zone is reduced thereby minimizing damage to the formation by said fluids. 
     Chemical blocking agents which are preferred for utilization in the practice of the invention include solidifiable gel mixtures. Solidifiable gel mixtures which can work in the present invention are selected to withstand conditions encountered in the formation. As will be understood by those skilled in the art, the composition of the mixture can be varied to obtain the desired rigidity in the gel composition. The stability and rigidity of the selected gel will depend upon the physical and chemical characteristics of the gel which are dictated by conditions in the formation. As is known to those skilled in the art, the solidified gel should be generally of a stability and rigidity which will absorb the heat and pressures encountered in a formation. Generally, the pressures encountered in a formation will vary from about 1,000 psig to about 20,000 psig. Heat encountered in a formation will generally vary from about 60° to about 450° F. 
     Often, it will be necessary to increase the density of the pumpable solidifiable gel to obtain the desired stability and rigidity. To accomplish this, a solid non-reactant material can be added to the pumpable gel mixture. Calcium carbonate is a preferred non-reacting solid material. 
     A pumpable solidifiable gel which can be utilized herein is made from polymers having functional groups such as NH 2 , --CONH 2 , --OH, --SH can be gelled with methylated, MF resins. Some acceptable polymers include polyacrylamide, Kelco&#39;s S-130 biopolymer, acrylamide modified polyvinyl alcohol (&#34;AMPVA&#34;), Xanthan biopolymers, poly (acrylamide-co-acryl-amide-2-methyl-propanesulfonate) &#34;AM-AMPS&#34;, &#34;Phillips HE&#34; polymers (a family of acrylamide containing copolymers), and polyvinyl alcohol. Polymers mentioned in U.S. Pat. No. 4,157,322, supra, may be utilized as long as those polymers contain the functional groups above mentioned. Polymer concentration in said gels range from about 0.1 to about 5.0 wt. percent. These polymer concentrations vary depending upon the molecular weight of polymer used. Lower molecular weight polymers require a higher polymer concentration to gel. A polymer concentration of about 0.2-5.0 wt. Percent is preferred. This crosslinking/co-gelation method produces high integrity polymer gels able to withstand high temperatures and high salinity conditions often found in subterranean hydrocarbonaceous formations. 
     Methylated MF derived as a reaction product of melamine and formaldehyde has a molar ratio of between 1-6. A ratio of 3-6 is commonly found in commercial resins. The methyol group, --CH 2  OH and its methylated varieties are reactive to various functional groups such as NH 2 , --CONH 2 , --OH, --SH and can also self-condense to form cured resins. Its preparation is convenient and well documented in preparative polymer manuals. 
     The melamine resin that is utilized in this invention can be a commercial product such as Cyanamid&#39;s Parez resins. Included among these melamine-formaldehyde (melamine) resins which are useful is this invention are the partially methylated resins and the hexamethoxymethyl resins (i.e. American Cyanamid&#39;s Parez, Cymel™373, Cymel 370, Cymel 303, and Cymel 380). The resin, however, has to be one that is soluble or dispersible in an aqueous medium. Other amino resins can also be used. Non-limiting examples are urea-formaldehyde, ethylene and propylene urea formaldehyde, triazone, uran, and glyoxal resins. The amount of MF resins required for adequate gel formation is in the ratio of 10:1-1:10 polymer to amino resins. Preferred polymer concentrations are from about 0.2 to about 5.0 wt. percent. Amino resins are preferred crosslinkers because they (1) are economical to use; (2) can be applied to a wide variety of polymers; (3) form thermally stable, brine tolerant gels; and (4) do not need an acid or base catalyst. 
     The gelation rate of the composition depends on the amount of each of the components and the temperature at which the reaction is conducted. Thus, one can tailor the gel rate and gel strength of the composition by adjusting the amount of the polymer, the resin amount and the temperature. The higher the temperature at given concentrations of resin and polymer will result in a faster gelation time. If a thicker gelled composition is desired, the polymer and resin concentrations may be increased for a given temperature. 
     Gels resultant from the gelation reaction were formed in about a 15 to 30 wt. % brine solution containing at least about 1500 ppm Ca(II) and at least about 500 ppm Mg(II). Said formed gels were stable as determined by sustained gel integrity and low gel shrinkage at least about 195° F. for at least three months. Examples of preferred gel compositions are set forth below. 
     
         ______________________________________Gelation of Melamine- Formaldehyde Crosslinker                 30%      Deionized                                  ParezExample  Polymer        Brine.sup.8                          Water   613.sup.1______________________________________  10% AMPVA.sup.2 #1      5 g          5 g      0 .sup. 0.4 g #2    2.5 g          5 g      2.5 g   0.4 g  AMPS-AMPVA.sup.3 10% #3    2.5 g          5 g      2.5 g   0.4 g #4      5 g          5 g      0 .sup. 0.4 g  PVA.sup.4 5% #5      5 g          2.5 g    2.5 g   0.4 g  AMPS-PVA.sup.5 10% #6      5 g          2.5 g    2.5 g   0.4 g  Magnifloc.sup.6 1% #7      5 g          5 g      0 .sup. 0.4 g #8      5 g          2.5 g    2.5 g   0.4 g  AM-AMPS.sup.7 1% #9      5 g          5 g      0 .sup. 0.4 g#10    2.5 g          5 g      2.5 g   0.4 g______________________________________Gelation with Trimethylolmelamine (TM)                 30%      DeionizedExample  Polymer        Brine.sup.8                          Water   TM______________________________________  S-130 1%.sup.9#11      5 g          5 g      --      0.4 g#12      5 g          5 g              0.2 g  HE B 2%.sup.10#13    2.5 g          5 g      2.5 g   0.4 g#14    2.5 g          5 g      2.5 g   0.4 g  He E 2%#15    2.5 g          5 g      2.5 g   0.4 g#16    2.5 g          5 g      2.5 g   0.2 g  Xanthan.sup.11 2%#17    2.5 g          5 g      2.5 g   0.4 g#18    2.5 g          5 g      2.5 g   0.2 g______________________________________ .sup.1 A commercial 80% active amino resin obtainable from American Cyanamid .sup.2 Acrylamide modified polyvinyl alcohol .sup.3 Acrylamido-2-methyl-propanesulfonate/acrylamide modified polyvinyl alcohol .sup.4 Polyvinyl alcohol .sup.5 Acrylamido-2-methyl-propanesulfonate/polyvinyl alcohol .sup.6 Polyacrylamide obtained from American Cyanamid .sup.7 Poly (acrylamideco-acrylamido-2-methyl-propanesulfonate) .sup.8 30% NaCl, 2000 ppm Ca, 1000 ppm Mg .sup.9 Kelco &#34;S130&#34; biopolymer .sup.10 Phillips HE .sup.11 Pfizer Flocon biopolymer 
    
     It is often desirable to have a solidified gel which will withstand a formation temperature range from about 300° F. to about 450° F. for from about 0.5 of a day to about 4 days. These solidified gels will be self destructive after about 0.5 of a day to about 4 days. While the gel is solidifying, preparation can be taken for the gravel packing step. A thermally stable gel can be obtained by mixing into the pumpable gel mixture a chemical known as an oxygen scavenger (such as sodium thiosulfate or short chain alcohols such as methanol, ethanol, and isopropanol), preferably sodium thiosulfate. The concentration of the oxygen scavenger utilized, of course, will depend upon the thermal stability desired to be obtained for the solidified gel in the formation. However, as preferred, it is anticipated that the concentration of the oxygen scavenger in the pumpable gel mixture will be from about 0.10 percent by weight to about 0.75 percent by weight, preferably 0.50 percent by weight. 
     In formations where temperatures are lower, a gel breaker can be placed in the solidifiable gel prior to injecting the gel into the formation. This gel breaker, included in the gel mixture, is selected from a group of chemicals which can break down the solid gel at temperatures of less than from about 60° F. to about 250° F. Generally this breakdown will occur within from about 2 hours to about 24 hours depending upon type and concentration of breaker added. Chemicals satisfactory for use as gel breakers, and which are incorporated into the gel mixture, include enzymes and oxidizing agents, suitable for breaking down the solid gel (such as sodium persulfate). Other gel breakers sufficient for this purpose are discussed in U.S. Pat. No. 4,265,311 issued to Ely on May 5, 1981, which is hereby incorporated by reference. These chemicals are readily available from chemical suppliers and with the exception of enzyme breakers are sold under their chemical names. Enzyme breakers can be obtained from oil field service companies. The concentration of the gel breaker incorporated into the gel mixture will vary from about 0.01 weight percent to about 0.10 weight percent, preferably about 0.05 weight percent of the gel mixture. Upon cooling to a temperature of from about 60° F. to about 150° F., the gel breaker will breakdown the solid gel causing it to liquefy and flow from the formation. This gel mixture is pumped into the casing of well 4 as shown in FIG. 2 and also into the washed out portion of the formation. After solidification of the mixture, any undesired solidified gel in the wellbore 12 can be removed by contacting it with 15 volume percent of hydrochloric acid in the amount sufficient to solubilize said gel. 
     As is understood by those skilled in the art, the composition of a selected gel will depend upon many variables including formation conditions. The above example is mentioned as one possible variation among many others. 
     Although the present invention has been described with preferred embodiments, it is to be understood that modifications and variations may be resorted to without departing from the spirit and scope of this invention, as those skilled in the art will readily understand. Such modifications and variations are considered to be within the purview and scope of the appended claims.