Abstract:
The present invention is a method of performing processing for a substrate including the step of carrying the substrate, which has been pre-treated, to a heat treatment unit for heating the substrate, prior to supplying a treatment solution to the substrate to perform solution treatment, in which the carrying is performed such as to fix a period after the pretreatment for the substrate is completed and before it is carried to the heat treatment unit. According to the present invention, for example, in a lithography process, the substrate is carried such as to fix the period after exposure processing that is the pretreatment and before the substrate is carried to the heat treatment unit where heat treatment that is the following treatment is performed, whereby the degrees of chemical reaction of coating films by the exposure processing become uniform between the substrates.

Description:
BACKGROUND OF THE INVENTION  
         [0001]    1. Field of the Invention  
           [0002]    The present invention relates to a substrate processing method, a substrate processing apparatus and a substrate carrying method.  
           [0003]    2. Description of the Related Art  
           [0004]    In a photolithography process in fabrication processes for the semiconductor device, for example, resist coating treatment for forming a resist film on a wafer surface, exposure processing in which a pattern is irradiated on the wafer and exposed, post-exposure baking treatment for heating the wafer after the exposure processing, developing treatment for performing development for the heat-treated wafer and the like are performed in sequence. These processing and treatments are sequentially performed in processing and treatment units separately provided in a single coating and developing treatment system and an aligner adjacent to the system. The coating and developing treatment system is structured to process a plurality of wafers concurrently at the same time, in which normally one carrier carries the wafers between the above-mentioned processing and treatment units.  
           [0005]    The carrier is configured to freely access the plurality of processing and treatment units and its operation is controlled to carry the wafers in the processing and treatment units at preferable timing in accordance with the processing steps to the processing and treatment units in which the respective following steps are performed, so that a series of the photolithography processing steps is smoothly performed.  
           [0006]    However, one carrier carries a number of wafers as described above, and thus in the case where, for example, when the carrier is carrying one wafer in one processing or treatment unit, treatment for another wafer is completed in another processing or treatment unit, the carrier can not carry the other wafer before it finishes carrying the one wafer. Meanwhile, when the carrier is not carrying a wafer but in a waiting state, the carrier can immediately carry the other wafer. Accordingly, the period required after the treatment for a wafer finishes and before the carrier goes to receive the wafer depends on the position and the state of the carrier, presenting a fear that the total periods required from the end of one treatment to the start of the following treatment become nonuniform between the wafers.  
           [0007]    When a so-called chemically amplified resist is used as a resist solution for forming the aforementioned resist film, exposure generates acid, and the resist film reacts with the acid and the resist film in the exposed portion changes to be soluble in the developing solution. Therefore, the degree of the developing treatment, that is, the line width of the circuit pattern on the wafer, greatly depends on progress of the chemical reaction by the acid, and the chemical reaction is greatly affected by the period from the exposure to the development.  
           [0008]    Accordingly, the period after the wafer is subjected to the exposure processing and before the developing treatment, especially, the period required from the exposure processing to the post-exposure baking treatment is affected by the position and the state of the carrier to be nonuniform, presenting a fear of adversely affecting the line of the circuit pattern which is finally formed on the wafer.  
           [0009]    Further, the aforementioned carrying of the wafer is conducted as follows, normally a main controller for controlling the carrier receives a processing end signal from each processing or treatment unit and stores it, the carrier recognizes the stored processing end signal every completion of the carrying of one wafer, and the carrier verifies it and then moves to the processing or treatment unit that is the sender to carry the wafer for which predetermined processing has been completed in the processing or treatment unit to the processing or treatment unit where the following step is performed.  
           [0010]    According to the above-described control mechanism for the carrier, however, since the carrier finishes the carrying of the present wafer and verifies processing end signal in the main controller, and then moves to the processing or treatment unit that is the sender, the period after the processing or treatment for the wafer finishes in the processing or treatment unit and before the carrier goes to the processing or treatment unit to receive the wafer differs depending on the state of the carrier at the moment or the number of the processing end signals, and generally tends to be longer. Therefore, it is impossible to carry the wafer between the processing and treatment units speedily and in a fixed period.  
           [0011]    Especially when the chemically amplified resist solution is used as described above, a treatment is performed in which the acid, as a catalyst, generated in the resist film by the exposure is increased in temperature to activate, promoting the chemical reaction for making the resist film soluble in the developing solution in the post-exposure baking treatment. In the following cooling treatment, a treatment of decreasing the acid in temperature to stop the catalysis of the acid is performed. Therefore, unless the wafer is speedily carried between the post-exposure baking unit and the cooling treatment unit, the wafer is overbaked to cause the chemical reaction to excessively proceed by the catalysis of the acid to widen the width of the resist film soluble in the developing solution, resulting in too wide line width of the circuit pattern which is finally formed on the wafer. Furthermore, if the wafer is not carried between the post-exposure baking unit and the cooling treatment unit in a fixed manner, there is a fear that line widths of the circuit patterns formed on wafers will become nonuniform between the wafers.  
         SUMMARY OF THE INVENTION  
         [0012]    The present invention is made in view of the above-described points, and its object is to fix the period required, for example, from exposure processing to post-exposure baking treatment, that is, to heat treatment before developing treatment in a photolithography process, or to make an improvement to make the period close to fixed.  
           [0013]    Further, a second object of the present invention is to shorten the period after the completion of heat treatment and before the substrate is cooled and to fix the period.  
           [0014]    The present invention is a method of performing processing for a substrate including the step of carrying the substrate, which has been pre-treated, to a heat treatment unit for heating the substrate, prior to supplying a treatment solution to the substrate to perform solution treatment, wherein the carrying is performed such as to fix a period after the pretreatment for the substrate is completed and before the substrate is carried to the heat treatment unit.  
           [0015]    According to another aspect, the present invention is a method of performing processing for a substrate including the step of carrying the substrate, which has been exposure-processed, to a heat treatment unit where heat treatment before developing treatment is performed, wherein the carrying is performed such as to fix a period after the exposure processing for the substrate is completed and before the substrate is carried to the heat treatment unit.  
           [0016]    According to still another aspect, the present invention is a method of performing processing for a substrate including the steps of carrying the substrate, which has been exposure-processed, temporarily to a delivery unit by a first carrier, and thereafter carrying the substrate staying in the delivery unit to a heat treatment unit where heat treatment before developing treatment is performed, by a second carrier, wherein at least when the exposure for the substrate is completed, the first carrier is waiting at a first position where the first carrier is capable of receiving the exposed substrate to immediately carry the substrate, for which the exposure has been completed, to the delivery unit, and wherein at least when the exposed substrate is carried to the delivery unit, the second carrier is waiting at a second position where the second carrier is capable of receiving the substrate staying in the delivery unit to carry the substrate to the heat treatment unit immediately after the exposed substrate is carried to the delivery unit.  
           [0017]    According to yet another aspect, the present invention is a method of performing processing for a substrate including the steps of carrying the substrate, which has been exposure-processed, temporarily to a delivery unit by a first carrier, and thereafter carrying the substrate staying in the delivery unit to a heat treatment unit where heat treatment before developing treatment is performed, by a second carrier, wherein at least when the exposure processing for the substrate is completed, the first carrier is waiting at a predetermined position where the first carrier is capable of receiving the substrate to carry the substrate to the delivery unit immediately after the exposure processing for the substrate is completed.  
           [0018]    According to further another aspect, the present invention is a method of performing processing for a substrate including the steps of carrying the substrate, which has been exposure-processed, temporarily to a delivery unit by a first carrier, and thereafter carrying the substrate staying in the delivery unit to a heat treatment unit where heat treatment before developing treatment is performed, by a second carrier, wherein at least when the substrate is carried to the delivery unit, the second carrier is waiting at a predetermined position where the second carrier is capable of receiving the substrate to carry the substrate to the heat treatment unit immediately after the substrate is carried to the delivery unit.  
           [0019]    The apparatus of the present invention is a substrate processing apparatus for performing processing for a substrate including a carrier for carrying the substrate, which has been pre-treated, to a heat treatment unit for heating the substrate prior to solution treatment performed by supplying a treatment solution to the substrate, and a controller for controlling the carrier such as to fix a period after the pretreatment for the substrate is completed and before the substrate is carried to the heat treatment unit.  
           [0020]    According to another aspect, the present invention is a substrate processing apparatus for performing processing for a substrate including a carrier for carrying the substrate, which has been exposure-processed, to a heat treatment unit where heat treatment before developing treatment is performed, and a controller for controlling the carrier such as to fix a period after the exposure processing for the substrate is completed and before the substrate is carried to the heat treatment unit.  
           [0021]    According to still another aspect, the present invention is a substrate processing apparatus for performing processing for a substrate including a first carrier for carrying the substrate, which has been exposure-processed, to a delivery unit, a second carrier for carrying the substrate staying in the delivery unit to a heat treatment unit where heat treatment before developing treatment is performed, and a controller for controlling the first carrier and the second carrier, wherein the controller conducts a control so that at least when the exposure processing for the substrate is completed, the first carrier is waiting at a first position where the first carrier is capable of receiving the exposed substrate to immediately carry the substrate, for which the exposure processing has been completed, to the delivery unit, and further at least when the exposure-processed substrate is carried to the delivery unit, the second carrier is waiting at a second position where the second carrier is capable of receiving the substrate staying in the delivery unit to carry the substrate to the heat treatment unit immediately after the exposure-processed substrate is carried to the delivery unit.  
           [0022]    According to yet another aspect, the present invention is a substrate processing apparatus for performing processing for a substrate including a first carrier for carrying the substrate, which has been exposure-processed, to a delivery unit, a second carrier for carrying the substrate staying in the delivery unit to a heat treatment unit where heat treatment before developing treatment is performed, and a controller for controlling the first carrier and the second carrier, wherein the controller conducts a control so that at least when the exposure processing for the substrate is completed, the first carrier is waiting at a predetermined position where the first carrier is capable of receiving the substrate to carry the substrate to the delivery unit immediately after the exposure processing for the substrate is completed.  
           [0023]    According to further another aspect, the present invention is a substrate processing apparatus for performing processing for a substrate including a first carrier for carrying the substrate, which has been exposure-processed, to a delivery unit, a second carrier for carrying the substrate staying in the delivery unit to a heat treatment unit where heat treatment before developing treatment is performed, and a controller for controlling the first carrier and the second carrier, wherein the controller conducts a control so that at least when the substrate is carried to the delivery unit, the second carrier is waiting at a predetermined position where the second carrier is capable of receiving the substrate to carry the substrate to the heat treatment unit immediately after the substrate is carried to the delivery unit.  
           [0024]    Furthermore, in order to attain the second object, according to the present invention, in a substrate carrying method of carrying a substrate, which has been heat-treated in a heat treatment unit, by a carrier to a cooling treatment unit where cooling treatment for the substrate is performed, at least when the heat treatment for the substrate is completed, the carrier is waiting at a predetermined position where the carrier is capable of receiving the substrate in the heat treatment unit.  
           [0025]    The present invention includes the step of carrying the substrate, which has been pre-treated, to a heat treatment unit for heating the substrate, prior to supplying a treatment solution to the substrate to perform solution treatment, wherein the carrying is performed such as to fix a period after the pretreatment for the substrate is completed and before the substrate is carried to the heat treatment unit.  
           [0026]    According to the present invention, since the carrying of the substrate is performed such as to fix the period after the pretreatment for the substrate is completed and before it is carried to the heat treatment unit, for example, the substrate is carried such as to fix the period after the exposure processing that is the pretreatment and before it is carried to the heat treatment unit where heat treatment that is the following treatment, whereby the degrees of the chemical reaction of the coating films by the above-described exposure processing become uniform between substrates. Thus, the developing treatment is performed for the substrates at the same degree, uniformly forming the line widths of the circuit patterns which are finally formed on the substrates between substrates.  
           [0027]    For example, the carrying such as to fix the period after the completion of the exposure processing for the substrate and before it is carried to the heat treatment unit is realized, for example, by controlling the operation of the carrier for carrying the substrate from the aligner to the heat treatment unit. More specifically, it is suggested that, for example, the carrier is kept waiting in front of the aligner in advance to carry the substrate to the heat treatment unit immediately after the exposure is completed and the substrate comes out of the aligner, the carrying of the substrate is always started after a lapse of a fixed period from the completion of the exposure processing, the carrier holding the substrate is suspended at a predetermined place and the suspension period in the event is adjusted, or the like.  
           [0028]    Furthermore, according to the present invention, when the exposure processing for the substrate is completed, the first carrier is waiting at the first position where it can receive the substrate to carry the substrate to the delivery unit immediately after the completion of exposure for the substrate. Furthermore, when the substrate is carried to the delivery unit, the second carrier is waiting at the second position where it can receive the substrate to carry the substrate to the heat treatment unit immediately after the substrate is carried to the delivery unit. The first and second carriers wait at the respective predetermined positions preceding to the carrying of other substrates, eliminating the fact that the carriers are, for example, carrying the other substrates or have moved to the positions where they can not immediately receive the substrate, with the result that the carrying period for the substrate from the exposure processing to the heat treatment unit is kept fixed. Accordingly, the above-described chemical reaction of the solubilization in the developing solution uniformly proceeds, whereby the developing treatment is uniformly performed for the substrates, reducing nonuniformity in line width of the finally formed pattern between the substrates. It should be noted that the first carrier and the second carrier are preferably waiting at the respective predetermined positions at least when the exposure is completed and at least when the substrate is carried to the delivery unit respectively, and they may be previously waiting from a predetermined period before.  
           [0029]    According to the present invention, the carrier is kept waiting from before the completion of the heat treatment at the predetermined position where it can receive the substrate in the heat treatment unit to receive the substrate immediately after the completion of the heat treatment and carry it to the cooling treatment unit. This shortens the period after the completion of the heat treatment and before the substrate is subjected to the cooling treatment and keeps the period fixed. Therefore, overbaking in the heat treatment and nonuniformity in pattern which is finally formed on the substrate between substrates are reduced.  
           [0030]    The heat treatment unit gives notice of completion of the heat treatment to the carrier controller, and the carrier controller moves the carrier to the waiting position based on the notice, whereby the carrier can recognize at an earlier time that the heat treatment is immediately before completion, and move to the predetermined position before the completion of the heat treatment and wait there. Therefore, when the heat treatment is completed, the carrier can be waiting at the position where it can access the heat treatment unit and immediately carry the substrate, for which the heating has been completed, to the cooling treatment unit.  
           [0031]    By giving discrimination marks to the substrates, when the carrier can not be waiting at the predetermined position at the completion of the heat treatment of the substrate, for example, when the carrier can not be waiting by the completion of the heat treatment because the carrier delays in moving to the predetermined position because of the carrying of another substrate, the substrate, which is presumed to be subjected to the heat treatment at the moment and made stand in a state of a high temperature for a period longer than the other substrates, can be recognized as a substrate needing caution based on its discrimination mark. This makes it possible to recognize the substrate of high possibility of being overbaked and remove the substrate needing caution from the other substrates when necessary. Note that the discrimination mark given to the substrate is not limited to one actually provided on the substrate, but it may be an imaginary discrimination mark, for example, a code which is recognized by a controller or the like to result in discrimination of each substrate.  
       
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
       [0032]    [0032]FIG. 1 is a perspective view showing the appearance of a coating and developing treatment system in which a coating and developing treatment method according to this embodiment is carried out;  
         [0033]    [0033]FIG. 2 is a plane view roughly showing the coating and developing treatment system in FIG. 1;  
         [0034]    [0034]FIG. 3 is an explanatory view showing an arrangement example of processing and treatment units in processing unit groups of the coating and developing treatment system;  
         [0035]    [0035]FIG. 4 is a state view of the coating and developing treatment system showing a state in which a main carrier unit and a carrier are waiting;  
         [0036]    [0036]FIG. 5 is an explanatory view showing the relation between exposure processing period and maximum waiting period;  
         [0037]    [0037]FIG. 6 shows a flowchart of wafer processing in relation to a timer function of the main carrier unit;  
         [0038]    [0038]FIG. 7 is a perspective view showing the appearance of a coating and developing treatment system in which a method of carrying the wafer according to a second embodiment of the present invention is carried out;  
         [0039]    [0039]FIG. 8 is a plane view roughly showing the coating and developing treatment system in FIG. 7;  
         [0040]    [0040]FIG. 9 is an explanatory view showing an arrangement example of processing and treatment units in processing unit groups of the coating and developing treatment system;  
         [0041]    [0041]FIG. 10 is an explanatory view schematically showing the configuration of a control mechanism for controlling a main carrier unit;  
         [0042]    [0042]FIG. 11 shows a flowchart of wafer processing in relation to the main carrier unit;  
         [0043]    [0043]FIG. 12 is a state view of the coating and developing treatment system showing a state in which the main carrier unit is waiting at a predetermined position; and  
         [0044]    [0044]FIG. 13 is a plane view roughly showing the coating and developing treatment system when a cassette for needing caution in a cassette station. 
     
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT  
       [0045]    Hereinafter, preferred embodiments of the present invention are described. FIG. 1 is a perspective view of a coating and developing treatment system  1  as a coating and developing treatment apparatus in which a coating and developing treatment method of the present invention is carried out, and FIG. 2 is a plane view roughly showing the coating and developing treatment system.  
         [0046]    As shown in FIG. 1 and FIG. 2, the coating and developing treatment system  1  has a configuration in which a cassette station  2  for carrying, for example, a plurality of wafers W in a cassette, as a unit, from/to the outside into/out of the coating and developing treatment system  1  and carrying the wafer W into/out of a cassette C, a processing station  3  in which various kinds of processing and treatment units each for performing predetermined processing or treatment for the wafers W one by one in coating and developing treatment steps are arranged side by side in two rows in a Y-direction, and an interface section  6  which is provided adjacent to the processing station  3  and includes a carrier  5  as a first carrier unit for carrying the wafer W between the processing station  3  and an aligner  4  provided outside the coating and developing treatment system  1 , are integrally connected.  
         [0047]    In the cassette station  2 , a plurality of cassettes C can be mounted in a line in an X-direction. A wafer carrier  8  transportable in the direction of arrangement of the cassettes (the X-direction) and in the direction of arrangement of the wafers W housed in the cassette C (a Z-direction; a vertical direction) is provided to freely move along a carrier guide  9  to be able to selectively access each cassette C.  
         [0048]    In the processing station  3 , a carrier rail  10  extending in the Y-direction is provided at the center, and a main carrier unit  11  is provided as a second carrier unit movable on the carrier rail  10 . Across the carrier rail  10 , various kinds of processing and treatment units are arranged on both sides in the Y-direction. More specifically, a brush scrubber  12  for cleaning the wafer W taken out of the cassette C, a wet cleaner  13  for performing high pressure jet cleaning for the wafer W, and treatment unit groups  14 ,  15  and  16  in each of which a plurality of thermal treatment units each for performing predetermined thermal treatment for the wafer W are multi-tiered, are arranged side by side, in order from the cassette station  2  side, on the front side of the carrier rail  10  in the X-direction. Meanwhile, resist coating units  17  and  18  each for applying a resist solution to the wafer W and developing treatment units  19  and  20  each for performing developing treatment for the exposure-processed wafer W are arranged side by side, in order from the cassette station  2  side, on the rear side of the carrier rail  10  in the X-direction.  
         [0049]    In the processing unit group  14 , as shown in FIG. 3, for example, a cooling unit  21  for performing cooling treatment for the wafer W, an adhesion unit  22  for enhancing adhesion of the resist solution to the wafer W, pre-baking units  23  and  24  each for evaporating a solvent in the resist solution are tiered in order from the bottom. In the processing unit group  15 , cooling units  26  and  27  and post-baking units  28  and  29  each for performing heat treatment for the developing-treated wafer W tiered in order from the bottom.  
         [0050]    In the processing unit group  16 , cooling units  30  and  31  and post-exposure baking units (hereinafter, referred to as “PEB units”)  32  and  33  as heat treatment units each for performing heat treatment for the wafer W after exposure processing and before developing treatment, are tiered in order from the bottom.  
         [0051]    The main carrier unit  11  is configured to be movable in a direction of rotation (a θ-direction) and in the Z-direction, as shown in FIG. 1 and FIG. 2, in addition to the above-described Y-direction so as to access and carry the wafer W to the processing and treatment units in the processing station  3 , the wafer carrier  8  in the cassette station  2 , and extension units  35  and  36  as delivery units in the interface section  6 .  
         [0052]    The main carrier unit  11  is controlled by a main controller  37  having a carrying algorithm as a program. More specifically, the main carrier unit  11  is controlled to carry in sequence each wafer W under processing in the processing station  3  to a processing unit where the following processing is performed in accordance with a predetermined processing flow for the wafer W. The main controller  37  controls the main carrier unit  11  so that when the wafer W for which at least exposure processing has been finished is carried to the above-described extension unit  36 , the main carrier unit  11  is waiting at a waiting position P, as shown in FIG. 4, as a second position where the main carrier unit  11  can access the extension unit  36 , that is a position where the main carrier unit  11  approaches closest to the extension unit  36  on the carrier rail  10 .  
         [0053]    The main controller  37  is provided with a timer function for counting a maximum waiting period M, which is a maximum period during which the main carrier unit  11  is waiting at the waiting position P. This timer function is for releasing the waiting by the main carrier unit  11  when some trouble occurs in the aligner  4  and thus the wafer W is not sent out of the aligner  4 .  
         [0054]    The timer function is configured to start counting when the wafer W is carried into the aligner  4  and stop the counting when the wafer W is carried out of the aligner  4 . Accordingly, the main carrier unit  11  is configured to be usually waiting at the waiting position P until it receives at the extension unit  36  the wafer W from the aligner  4 , but if the wafer W is not sent out of the aligner  4  by the time when the maximum waiting period M which the timer function counts elapses, the waiting by the main carrier unit  11  is released.  
         [0055]    As shown in FIG. 5, when it is assumed that a period usually required for an exposure processing step after the wafer W is carried into the aligner  4  until it is carried out of the aligner  4  is an exposure processing period T as a predetermined period T, the maximum waiting period M is previously set to be, for example, M=2T, which is sufficiently longer than the exposure processing period T.  
         [0056]    As shown in FIG. 1 and FIG. 2, the extension units  35  and  36  each for delivering the wafer W between the main carrier unit  11  and the carrier  5  are arranged tiered in order from the bottom on the processing station  3  side of the interface section  6  and on the extension line of the carrier rail  10 . Each of the extension units  35  and  36  includes a mounting table (not shown) for mounting the wafer W thereon and raising and lowering pins (not shown) for raising and lowering the wafer W The extension unit  35  is used when the wafer W is carried from the main carrier unit  11  to the carrier  5  side, and the extension unit  36  is used when the wafer W is carried from the carrier  5  to the main carrier unit  11  side. On the aligner  4  side of the interface section  6 , a carrying-in mounting table  38  on which the wafer W is temporarily mounted when the wafer W is carried into the aligner  4 , and a carrying-out mounting table  39  on which the wafer W is mounted when the wafer W is carried out of the aligner  4 , are arranged side by side in the X-direction.  
         [0057]    At the center of the interface section  6 , a rail  6   a  extending in the X-direction is provided, on which the above-described carrier  5  is provided to freely move. The carrier  5  is configured to freely move in the X-direction, the Z-direction, and freely rotate in the θ-direction (a direction of rotation around the Z-axis) so as to access the extension units  35  and  36 , the carrying-in mounting table  38  and the carrying-out mounting table  39  and carry the wafer W to them. The carrier  5  is controlled by the main controller  37  similarly to the main carrier unit  11  so that at least when the wafer W, for which exposure processing has been completed, is mounted on the carrying-out mounting table  39 , the carrier  5  is waiting at a waiting position Q, as shown in FIG. 4, as a first position where the carrier  5  can receive the wafer W on the carrying-out mounting table  39 .  
         [0058]    The timer function of the main controller  37  is used also for the carrier  5 , so that the carrier  5  is configured to wait at the waiting position Q until a period not longer than a maximum waiting period I elapses, but if the wafer W is not sent out of the aligner  4  by the time the maximum waiting period I elapses, the waiting by the carrier  5  is released. The main controller  37  also controls the carrier  5  as a carrier unit.  
         [0059]    In this embodiment, the maximum waiting period I of the carrier  5  is set at the same value as the maximum waiting period M of the main carrier unit  11  as shown in FIG. 5. Sometimes the exposure processing is not performed in the period as usual because of alignment operation or the like in the aligner  4 , and thus the maximum waiting period I is preferably set at the longest period possible keeping in a consideration nonuniformity in period of the exposure processing step.  
         [0060]    The aligner  4  is provided adjacent to the interface section  5  as shown in FIG. 1. The aligner  4  is provided with a carrier opening  40  through which the wafer W passes when carried into/out of the aligner  4 . In the aligner  4 , a carrier means not shown is provided to carry in the wafer W from the aforesaid carrying-in mounting table  38  and carry out the wafer W to the aforesaid carrying-out mounting table  39 . The carrier opening  40  is provided with a sensor  41  for detecting the wafer W being carried into/out of the aligner  4  and sending the signal to the main controller  37 , so that with the signal as a trigger the counting of the timer function in the main controller  37  is started or stopped.  
         [0061]    Next, the coating and developing treatment method which is carried out in the coating and developing treatment system  1  structured as described above is explained along the process of the photolithography processing steps.  
         [0062]    Initially, in the cassette station  2 , the wafer carrier  8  takes one unprocessed wafer W out of the cassette C, and then the main carrier unit  11  receives the wafer W direct from the wafer carrier  8 . Subsequently, the main carrier unit  11  carries the wafer W in sequence to the brush scrubber  12  and the wet cleaner  13 , where the wafer W is subjected to predetermined cleaning treatment.  
         [0063]    Thereafter, the wafer W is carried again by the main carrier unit  11  to the adhesion unit  22  included in the processing unit group  14  and coated with an adhesion promoter such as HMDS for enhancing adhesion to the resist solution. Then, the wafer W is carried in sequence by the main carrier unit  11  to the cooling unit  21 , the resist coating unit  17  or  18 , the pre-baking unit  23  or  24 , and the cooling unit  26  or  27  to be subjected to predetermined processing.  
         [0064]    The wafer W which has been cooled to a predetermined temperature in the cooling unit  26  or  27  is carried by the main carrier unit  11  into the extension unit  35  and mounted on a mounting table not shown.  
         [0065]    Then, the wafer W is carried by the carrier  5  to the carrying-in mounting table  38  near the aligner  4 , while the main carrier unit  11  carries other wafers in the treatment units in the processing station  3  to the treatment units where the respective next steps are performed while moving on the carrier rail  10  in accordance with the carrying program of the main controller  37  during a predetermined period E. The predetermined period E here is a period during which the main carrier unit  11  may carry the other wafers, that is, a predetermined set period shorter than a period which is usually required after the wafer W is mounted on the extension unit  35  and before the wafer W is sent out of the aligner  4  as shown in FIG. 5.  
         [0066]    After the predetermined period E elapses, the main carrier unit  11  moves to the waiting position P where it is accessible to the extension unit  36 , and waits there until the wafer W which has been carried into the aligner  4  is returned to the extension unit  36 . It should be noted that the predetermined period E is set, for example, to be the same period as the exposure processing period T so that the main carrier unit  11  is waiting without fail at the waiting position P when the wafer W for which exposure processing is finished and mounted on the extension unit  36 .  
         [0067]    The wafer W mounted on the carrying-in mounting table  38  by the carrier  5  is carried through the carrier opening  40  of the aligner  4  into the aligner  4  by the carrier means not shown in the aligner  4 . Hereinafter, the processing for the wafer W relating to the timer function is shown in the flowchart in FIG. 6. In this event, the sensor  41  at the carrier opening  40  detects the carrying-in of the wafer W, and sends the signal to the main controller  37 . In the main controller  37  which has received the signal, the counting by the aforesaid timer function is started taking the signal as a trigger. The carrier  5  moves to the waiting position Q where it is accessible to the carrying-out mounting table  39 , and waits there until exposure processing for the wafer W is completed.  
         [0068]    Thereafter, a predetermined pattern is exposed on the wafer W in the aligner  4 . While this exposure processing is performed, the aforesaid predetermined period E of the main carrier unit  11  elapses, and the main carrier unit  11  thus moves to the waiting position P and waits there (becomes the state in FIG. 4). Normally, after a lapse of the aforesaid exposure processing period T, the wafer W is sent out from the carrier opening  40  of the aligner  4  and mounted on the carrying-out mounting table  39 . In this event, the sensor  41  detects the carrying-out of the wafer W, and sends the signal to the main controller  37 , whereby the counting by the timer function of the main controller  37  is stopped and reset.  
         [0069]    The wafer W mounted on the carrying-out mounting table  39  is immediately delivered to the carrier  5  waiting at the waiting position Q, and the carrier  5  carries the wafer W to the extension unit  36 . The wafer W carried to the extension unit  36  is immediately delivered to the main carrier unit  11  waiting at the waiting position P, and carried to the PEB unit  32  or  33  by the main carrier unit  11 .  
         [0070]    When some trouble happens in the aligner  4  and the wafer W is not sent out of the aligner  4  even when the maximum waiting period I or M elapses, the timer function is stopped to release the waiting instruction to the carrier  5  and the main carrier unit  11 . Then, the carrier  5  stops, for example, its operation, and the main carrier unit  11  carries the other wafers W remaining in the processing station  3 , for which exposure processing has been properly performed, along the predetermined processing steps described below and stops its operation after the wafers W are carried out of the processing station  3  to the cassette station  2 .  
         [0071]    The wafer W which has been properly exposed to light and carried to the PEB unit  32  or  33  is subjected to heat treatment for promoting solubilization reaction of the resist film in the developing solution. Then, the wafer W is immediately carried to the cooling unit  30  or  31  by the main carrier unit  11  and cooled to a predetermined temperature. Subsequently, the wafer W is carried to the developing treatment unit  19  or  20  and subjected to developing treatment.  
         [0072]    The wafer W for which the developing treatment has been completed is delivered again to the main carrier unit  11 , and carried backward in the Y-direction on the carrier rail  10  by the main carrier unit  11  to be delivered to the wafer carrier  8  in the cassette station  2 . The wafer W is returned to the cassette C by the wafer carrier  8 , and a series of photolithography processing steps is thus completed.  
         [0073]    According to the above-described embodiment, the carrier  5  and the main carrier unit  11  are waiting at the predetermined waiting positions Q and P respectively for the wafer W to come, quickly carrying the wafer W from the exposure processing to the PEB treatment in a fixed period. This equalizes periods required from the exposure processing to the PEB treatment between the wafers W, whereby the solubilization reaction of the resist film to the developing solution uniformly proceeds, and the developing treatment is uniformly performed, resulting in line widths formed on the wafers W uniform between the wafers W.  
         [0074]    By providing the timer function in the main controller  37  to set the maximum waiting periods I and M of the carrier  5  and the main carrier unit  11 , when the wafer W is not sent out of the exposure processing because of some reason, the carrying by the carrier  5  may be stopped for a check of the aligner  4 , and the main carrier unit  11  may carry the other wafers W remaining in the processing station  3 , for which exposure has been properly performed, to allow them to be subjected to the end of processing.  
         [0075]    In the above-described embodiment, both of the main carrier unit  11  and the carrier  5  are configured to keep waiting, but it is also preferable that when there occurs no nonuniformity between the wafers W in period required before the carrier or carrier unit receives the wafer W by virtue of the structure of the coating and developing treatment system  1  and the carrying algorithm for the carrier or carrier unit, the carrier or carrier unit without nonuniformity is not kept waiting but the other carrier or carrier unit is kept waiting. More specifically, it is preferable to keep only the main carrier unit  11  or only the carrier  5  waiting. Also in this case, it is preferable that the timer function is naturally provided ready for the case in which the exposure processing is not performed in the predetermined period.  
         [0076]    The embodiment explained hereinbefore is for the coating and developing treatment method for the wafer W in the photolithography process in the semiconductor wafer device fabrication processes, and the present invention is applicable to a coating and developing treatment method for a substrate other than the semiconductor wafer, for example, an LCD substrate.  
         [0077]    According to the present invention, it is possible to fix the period from the completion of the exposure processing for the substrate to the start of the heat treatment before the developing treatment, whereby chemical reaction by the exposure to the coating film proceeds to a fixed degree and thus the wafers W are subjected to the developing treatment to a fixed degree, resulting in uniform line width which is finally formed on the substrate between the substrates.  
         [0078]    The carrier and carrier unit previously keep waiting to receive the substrate and immediately carry it, thereby also reducing the period required from the completion of the exposure processing to the performance of the heat treatment before the developing treatment.  
         [0079]    The maximum waiting periods of the carrier and carrier unit are provided, thereby making it possible to cope also with the case in which the exposure processing is not properly performed.  
         [0080]    Next, a second embodiment of the present invention is explained. FIG. 7 is a perspective view of a coating and developing treatment system  101  in which a method of carrying the substrate of the present invention is carried out, and FIG. 8 is a plane view roughly showing the coating and developing treatment system.  
         [0081]    As shown in FIG. 7 and FIG. 8, the coating and developing treatment system  101  has a configuration in which a cassette station  102  for carrying, for example, a plurality of wafers W in a cassette, as a unit, from/to the outside into/out of the coating and developing treatment system  101  and carrying the wafer W into/out of a cassette C, a processing station  103  in which various kinds of processing and treatment units each for performing predetermined processing or treatment for the wafers W one by one in coating and developing treatment steps are arranged side by side in two rows in a Y-direction, and an interface section  104  for delivering the wafer W to/from an aligner not shown which is provided adjacent to the processing station  103 , are integrally connected.  
         [0082]    In the cassette station  102 , a plurality of cassettes C can be mounted in a line in an X-direction. A wafer carrier  108  transportable in the direction of arrangement of the cassettes (the X-direction) and in the direction of arrangement of the wafers W housed in the cassette C (a Z-direction; a vertical direction) is provided to freely move along a carrier guide  109  to be able to selectively access each cassette C.  
         [0083]    In the processing station  103 , a carrier rail  110  extending in the Y-direction is provided at the center, on which a main carrier unit  111  is provided as a carrier unit freely moving on the carrier rail  110 . Across the carrier rail  110 , various kinds of processing and treatment units are arranged side by side on both sides in the Y-direction. More specifically, a brush scrubber  112  for cleaning the wafer W taken out of the cassette C, a wet cleaner  113  for performing high pressure jet cleaning for the wafer W, and treatment unit groups  114 ,  115  and  116  in each of which a plurality of thermal treatment units each for performing predetermined thermal treatment for the wafer W are multi-tiered, are arranged side by side, in order from the cassette station  102  side, on the front side of the carrier rail  110  in the X-direction. Meanwhile, resist coating units  117  and  118  each for applying a resist solution to the wafer W and developing treatment units  119  and  120  each for performing developing treatment for the exposure-processed wafer W are arranged side by side, in order from the cassette station  102  side, on the rear side of the carrier rail  110  in the X-direction.  
         [0084]    The main carrier unit  111  is configured to freely move in a direction of rotation (a θ-direction) and in the Z-direction, as shown in FIG. 7 and FIG. 8, in addition to the above-described Y-direction so as to access the processing and treatment units in the processing station  103 , the wafer carrier  108  in the cassette station  102 , and extension units  135  and  136  as delivery units in the interface section  104  described below to carry the wafer W to them.  
         [0085]    The main carrier unit  111  is configured to be controllable by a main controller  121  as a carrier controller as shown in FIG. 8, so that the main carrier unit  111  is controlled by the main controller  121  to carry the wafer W in accordance with a processing flow for the wafer W.  
         [0086]    In the processing unit group  114 , as shown in FIG. 9, for example, a cooling unit  122  for performing cooling treatment for the wafer W, an adhesion unit  123  for enhancing adhesion of the resist solution to the wafer W, pre-baking units  124  and  125  each for evaporating a solvent in the resist solution are tiered in order from the bottom. In the processing unit group  20   115 , cooling units  126  and  127  and post-baking units  128  and  129  each for performing heat treatment for the developing-treated wafer W tiered in order from the bottom.  
         [0087]    In the processing unit group  116 , cooling units  130  and  131  and post-exposure baking units (hereinafter, referred to as “PEB units”)  132  and  133  as heat treatment units each for performing heat treatment for the wafer W after exposure processing and before developing treatment, are tiered in order from the bottom. Casings of the PEB units  132  and  133  are provided with carrier openings  132   a  and  133   a  facing the carrier rail  110 , as shown in FIG. 7, through which the wafer W is carried in/out. These carrier openings  132   a  and  133   a  are respectively provided with shutters  132   b  and  133   b  for preventing heat in the PEB units  132  and  133  from diffusing and adapted to open only when the wafer W is carried in/out.  
         [0088]    In the PEB units  132  and  133  are provided with controllers  132   c  and  133   c  for controlling the operation of the PEB units  132  and  133  in the PEB treatment for the wafer W as shown in FIG. 10. Each of the controllers  132   c  and  133   c  is configured to be able to send a dummy end signal as an end notice signal for giving the main controller  121  notice of a predetermined period T before the completion of the PEB treatment. Note that the predetermined period T is previously set in the controllers  132   c  and  133   c  and may be changed.  
         [0089]    The main controller  121  is configured to be able to receive the signals from the above-described controllers  132   c  and  133   c  of the PEB units  132  and  133  so as to receive the dummy end signals. The main controller  121  is configured to be able to send and receive the signal to/from the main carrier unit  111  to control it as described above, so that a controlling instruction can be sent and their states can be recognized each other by sending and receiving the signal. The main controller  121  is provided with a storage function for storing received data, in which the signal received by the main controller  121  can be stored when necessary.  
         [0090]    The main controller  121  is configured to be able to send and receive signals also to/from the processing and treatment units other than the PEB units  132  and  133  in the processing station  103  so as to receive end signals of wafer processing sent from the processing and treatment units and store them by the aforesaid storing function. The main carrier unit  111  is configured to recognize and verify the wafer processing end signal stored in the main controller  121  and then move to the processing unit, the sender of the end signal, to carry the wafer W to the processing unit where the following processing is performed.  
         [0091]    In the interface section  104 , as shown in FIG. 7 and FIG. 8, a carrier  140  for carrying the wafer W between the processing station  103  and the aligner not shown is provided to freely move in the X-direction, the Z-direction, and in the θ-direction. The extension units  135  and  136  each for delivering the wafer W between the main carrier unit  111  and the carrier  140  are arranged tiered in order from the bottom on the processing station  103  side of the interface section  104  and on the extension line of the carrier rail  110 . Each of the extension units  135  and  136  includes a mounting table not shown for mounting the wafer W thereon and raising and lowering pins not shown for raising and lowering the wafer W The extension unit  135  is used when the wafer W is carried from the main carrier unit  111  to the carrier  140 , and the extension unit  136  is used when the wafer W is carried from the carrier  140  to the main carrier unit  111 .  
         [0092]    Next, the method of carrying the wafer W which is carried out in the coating and developing treatment system  101  structured as described above is explained with the process of the photolithography processing steps.  
         [0093]    Initially, in the cassette station  102 , the wafer carrier  108  takes one unprocessed wafer W out of the cassette C, and then the main carrier unit  111  receives the wafer W direct from the wafer carrier  108 . Subsequently, the main carrier unit  111  carries the wafer W in sequence to the brush scrubber  112  and the wet cleaner  113 , and further in sequence to the adhesion unit  123  and the cooling unit  122  which are included in the processing unit group  114 , whereby the wafer W is subjected to predetermined processing in the processing and treatment units. Then the wafer W is carried by the main carrier unit  111  to the resist coating unit  117  or  118  to be coated thereon with a chemically amplified resist solution, whereby a resist film is formed on the wafer W. The wafer W on which the resist film formed is then carried again by the main carrier unit  111  in sequence to the pre-baking unit  124  or  125  and the cooling unit  126  to be subjected to predetermined processing there.  
         [0094]    The wafer W which has been cooled to a predetermined temperature in the cooling unit  126  or  127  is carried by the main carrier unit  111  into the extension unit  135  of the interface section  104  and mounted on the mounting table not shown. Subsequently, the wafer W is carried by the carrier  140  to the aligner not shown, where a predetermined pattern is exposed on the wafer W. In this event, acid, which acts as a catalyst for solubilization reaction of the resist film in the developing solution, generates in the resist film in the exposed portion. The wafer W for which exposure processing has been completed is carried again by the main carrier  140  to the extension unit  136 , and then carried by the main carrier unit  111  into the PEB unit  133  through the carrier opening  133   a  of the PEB unit  133 .  
         [0095]    The following wafer processing is explained along the flow chart in FIG. 11. The wafer W is initially heated at a predetermine temperature in the PEB unit  133 , whereby the acid in the resist film is activated to proceed the solubilization reaction of the resist film in the exposed part to the developing solution. Then, when it is a predetermined period T before the completion of the heat treatment, the controller  133   c  sends a dummy end signal of giving notice that it is immediately before the completion of the heat treatment, to the main controller  121 .  
         [0096]    The main controller  121  which has received the aforesaid dummy end signal immediately verifies whether or not the main carrier unit  111  is keeping another wafer W. When the main carrier unit  111  is not keeping another wafer W, the main controller  121  instructs the main carrier unit  111  to move to the predetermined position P where it can receive the wafer W in the PEB unit  133 , that is, a position in front of the shutter  133   b  of the PEB unit  133 . The main carrier unit  111  which has received the instruction moves on the carrier rail  110  to the predetermined position P as shown in FIG. 12 and waits there until the shutter  133   b  at the carrier opening  133   a  is opened.  
         [0097]    Meanwhile, when the main carrier unit  111  is keeping another wafer W, the main controller  121  stores therein the dummy end signal and always verifies whether or not the main carrier unit  111  is keeping the other wafer W, and gives a moving instruction to the main carrier unit  111  to move to the predetermined position P when the main carrier unit  111  completes the carrying operation of the other wafer W and becomes a so-called free state.  
         [0098]    Thereafter, when the heat treatment in the PEB unit  133  is completed and the shutter  133   b  is opened, the waiting main carrier unit  111  immediately carries the wafer W out of the PEB unit  133  to the cooling unit  131 .  
         [0099]    The wafer W which has been carried to the cooling unit  131  is cooled to a predetermined temperature, whereby the catalysis of the acid then stops.  
         [0100]    Thereafter, the wafer W is carried by the main carrier unit  111  to the developing treatment unit  119  or  120  to be subjected to developing treatment. The wafer W for which the developing treatment has been completed is carried again by the main carrier unit  111  in sequence to post-baking unit  128  or  129  and the cooling unit  127 . The wafer W for which the cooling treatment has been completed is carried backward in the Y-direction on the carrier rail  110  and delivered to the wafer carrier  108  in the cassette station  102 . The wafer W is returned to the cassette C by the wafer carrier  108 , and a series of photolithography processing steps is thus completed.  
         [0101]    In the above-described second embodiment, the PEB unit  133  previously sends the dummy end signal to the main controller  121 , and the main carrier unit  111  moves by the instruction from the main controller  121 , which has received the dummy end signal, to the predetermined position P in front of the PEB unit  133  and waits there until the PEB treatment is completed, so that the main carrier unit  111  can receive the wafer W immediately after the PEB treatment for the wafer W is completed and the shutter  133  is opened, and carry it to the cooling unit  131 . This avoids the wafer W, for which the PEB treatment has completed, from being waiting in the PEB unit  133  for the main carrier unit  111  to come to receive it, whereby the period required from the PEB treatment to the cooling treatment is reduced and kept fixed.  
         [0102]    Further, before the main controller  121  which has received the dummy end signal gives a moving instruction to the main carrier unit  111 , the main controller  121  verifies whether or not the main carrier unit  111  is carrying another wafer W, and when it is carrying, the main controller  121  gives the moving instruction immediately after the completion of the carrying, thereby making it possible to properly cope with the case where the main carrier unit  111  can not move to the predetermined position P because of the carrying of the other wafer W. Furthermore, as compared with the conventional case in which after the PEB treatment for the wafer W is completed, the end signal is sent to the main controller  121 , and thereafter the main carrier unit  111  verifies the end signal and then moves to the predetermined position P, the main carrier unit  111  can move earlier to the predetermined position P where it can receive the wafer W, and thus the period required from the PEB treatment to the cooling treatment is reduced and kept fixed also in this case.  
         [0103]    The above-described embodiment is the case in which the main carrier unit  111  has moved to the predetermine position P where it can access the PEB unit  133  without fail before the completion of the PEB treatment. However, it is predictable that it takes a long time for the main carrier unit  111  to carry another wafer W to be late for the time at the completion of the PEB treatment. As measures in this case, it is suggested that the overbaked wafer W is separated from the properly processed wafers W.  
         [0104]    For example, imaginary numbers are previously given as discrimination marks to the wafers W, and previously recognized by, for example, the main controller  121 . When the main carrier unit  111  is late for the time at the completion of the PEB treatment, the main controller  121  recognizes the number of the wafer under processing at that time as a wafer needing caution. Thereafter, the wafer needing caution is processed in accordance with the predetermined processing flow, and when it is carried to the cassette C in the cassette station  102 , it is separated and mounted, for example, in a cassette C 1  which is previously provided for a wafer needing caution as shown in FIG. 13. This makes it possible to separate the overbaked wafer W and the normally PEB-processed wafers W, thereby removing a wafer W of a poor quality from products.  
         [0105]    Alternatively, the wafer W overbaked in the PEB unit  133  may be carried, not subjected to the following processing, immediately to the cassette station  102  to be carried into the cassette C 1  for the wafer W needing caution. In this case, the developing treatment and the like are not performed yet, making it possible to use again the wafer W by removing the resist film thereon.  
         [0106]    Note that the predetermined period T of the controller  133   c  is preferably set to be somewhat long enough to prevent the main carrier unit  111  from not usually being late for the completion of the PEB treatment.  
         [0107]    The method of carrying the wafer W according to the above-described embodiment is for the carrying from the PEB unit  133  to the cooling unit  131 , and it is also applicable to the carrying between another heat treatment unit and cooling treatment unit, for example, between the pre-baking unit  124  or  125  and the cooling unit  126 , and between the post-baking unit  128  or  129  and the cooling unit  127 .  
         [0108]    Furthermore, the above-described embodiment is for the method of carrying the wafer W in the photolithography process in the semiconductor wafer device fabrication processes, and the present invention is applicable to a method of carrying a substrate other than the semiconductor wafer, for example, an LCD substrate.  
         [0109]    According to the present invention, the carrier unit for the substrate keeps waiting from before the completion of the heat treatment for the substrate at the position where it can receive the substrate in the heat treatment unit in which the heat treatment is performing, to immediately carry the substrate, for which the heat treatment has been completed, to the cooling treatment unit, whereby the period required from the heat treatment to the cooling treatment is reduced and kept fixed. Consequently, overbaking or difference in thermal history between substrates is reduced to form a predetermined pattern on the substrate, resulting in improved yields.