Abstract:
Disclosed herein is a polyolefin-based thermoplastic polymer composition, in which an acrylate copolymer phase obtained by absorbing an alkyl acrylate monomer, an alkyl methacrylate monomer, a polar group-containing acrylate monomer and a polymerization initiator into a polyolefin matrix and then polymerizing the monomers is dispersed in a polyolefin phase. The thermoplastic polymer composition has excellent surface polarity leading to excellent paint adhesion.

Description:
BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to a polyolefin-based thermoplastic polymer composition, and more particularly to a polyolefin-based thermoplastic polymer composition having high surface polarity leading to excellent paint adhesion 
     2. Background of the Related Art 
     Generally, plastic parts, which are used as automotive interior and exterior parts, and parts of electric home appliances, are painted for improvements in aesthetic effects and surface properties, and for this, good adhesion between plastic resin and paints are required. Nonpolar polyolefin-based thermoplastic resins, such as polyethylene or polypropylene, are poor in adhesion with paints, and thus, have many difficulties in painting. To overcome such difficulties, various methods of surface pretreatment or methods of using functional additives are developed and being applied. 
     The surface pretreatment methods generally include a flame treatment method, a plasma treatment method, a UV irradiation method, a primer treatment method and a combination of two or more of these methods. However, the surface pretreatment methods have problems, such as additional equipment investment and increases in operation and maintenance costs. Particularly, the primer treatment method which is traditionally mainly used is a method of imparting paint adhesion to the surface of polyolefin-based thermoplastic resin by pre-applying chlorinated polyolefin-based resin to the polyolefin-based thermoplastic resin surface, and has problems in that it causes an increase in costs and uses environment-unfriendly materials. 
     The methods of using functional additives without surface pretreatment include a method of adding a large amount of polypropylene-g-maleic anhydride, a method of adding polyols having special chemical structures, and a method of chemically introducing functional additives into polyolefin. Among these methods, the method of adding a large amount of modified polyolefin, such as polypropylene-g-maleic anhydride, and the method of adding polyols having special chemical structures, have problems in that production cost is increased by the use of a large amount of expensive materials, and the physical properties of the resulting composite material are deteriorated by the addition of a large amount of additives. The method of chemically introducing functional additives into polyolefin (U.S. Pat. No. 6,133,374), which is a preparation method based on chemical decomposition, has a problem in that the control of chemical reaction is not easy, and thus, it is very difficult to obtain a polyolefin composite material with uniform and regular physical properties. 
     Korean patent Nos. 362824 and 395399 disclose methods of preparing polyolefin-based thermoplastic elastomers containing an acrylate-based copolymer. The thermoplastic elastomers prepared by these preparation methods are high in surface polarity and excellent in physical properties and chemical resistance, but very low in flowability. Thus, for the surface modification of the polyolefin-based composite material, a large amount of additives should be added to the polyolefin-based resin, resulting in deterioration in the physical properties and processability of the polyolefin composite material. For this reason, these methods were difficult to apply. 
     SUMMARY OF THE INVENTION 
     Therefore, the present invention has been made to solve the above-described problems occurring in the prior art, and it is an object of the present invention to provide a polyolefin-based thermoplastic polymer composition having high surface polarity leading to excellent paint adhesion. 
     To achieve the above object, the present invention provides a polyolefin-based thermoplastic polymer composition, in which an acrylate copolymer phase obtained by absorbing an alkyl acrylate monomer, an alkyl methacrylate monomer, a polar group-containing acrylate monomer and a polymerization initiator into a polyolefin matrix and then polymerizing the monomers is dispersed in a polyolefin phase. 
     In the inventive polyolefin-based thermoplastic composition, the content of the acrylate copolymer phase is 95-995 parts by weight based on 100 parts by weight of the polyolefin phase. 
     Also, the polyolefin comprises either an unblended polyolefin or a blend of two or more polyolefins. 
     The polyolefin blend comprises a blend of polyolefin and one or more polyethylene copolymer. 
     The polyethylene copolymer comprises at least one selected from the group consisting of poly(ethylene-co-methylacrylate), poly(ethylene-co-ethylacrylate), poly(ethylene-co-butylacrylate), poly(ethylene-co-acrylic acid), poly(ethylene-co-methacrylic acid), poly(ethylene-co-glycidyl methacrylate), poly(ethylene-co-maleic acid), poly(ethylene-co-vinyl acetate), poly(ethylene-co-acrylamide), and poly(ethylene-co-acrylonitrile). 
     The amount of the alkyl acrylate monomer used is 65-455 parts by weight based on 100 parts by weight of the polyolefin phase. 
     Preferably, the amount of the alkyl acrylate monomer used is 90-350 parts by weight based on 100 parts by weight of the polyolefin phase. 
     The amount of the alkyl methacrylate monomer used is 15-240 parts by weight based on 100 parts by weight of the polyolefin phase. 
     Preferably, the amount of the alkyl methacrylate monomer used is 45-150 parts by weight based on 100 parts by weight of the polyolefin phase. 
     The amount of the polar group-containing acrylate monomer used is 15-300 parts by weight based on 100 parts by weight of the polyolefin phase. 
     Preferably, the amount of the polar group-containing acrylate monomer used is 50-180 parts by weight based on 100 parts by weight of the polyolefin phase. 
     In the inventive polyolefin-based thermoplastic polymer composition, the polymerization initiator is used in an amount of 0.5-2.0 mole % based on the sum of the mole of the monomers and the mole of the polymerization initiator. 
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 
     Hereinafter, the present invention will be described in detail. 
     (First Polymerization Step) 
     Into a reactor equipped with a stirrer, a heater and a cooler, 50-200 parts by weight, based on 100 parts by weight of polyolefin, of an alkyl acrylate monomer and 500-1,000 parts by weight of water are charged. Also, a polymerization initiator is charged into the reactor in an amount of 0.5-2.0 mol % based on the sum of the mole of the acrylate monomer and the mole of the polymerization initiator, and the reactor is then closed. If the content of the alkyl acrylate monomer is less than 50 parts by weight, the impregnation of monomers for second polymerization will be poor, and if the content is more than 200 parts by weight, the monomer content which is not absorbed into the polyolefin matrix will be increased, thus causing a reduction in yield and a problem in waste water treatment. If the polymerization initiator is used in an amount of less than 0.5 mole % based on the sum of the mole of the acrylate monomer and the mole of the polymerization initiator, a high-molecular weight polyacrylate polymer will be produced which does not meet the object of the present invention, and if the polymerization initiator is used in an amount of more than 2.0 mole %, a ultra-low-molecular weight polyacrylate polymer will be produced which causes a reduction in the physical properties of the resulting product and makes process control difficult. 
     The closed reactor is purged with high-pressure nitrogen gas with stirring to remove oxygen. Then, the temperature within the reactor is elevated to an absorption temperature of 45-120° C. depending on the kind of the selected polymerization initiator to absorb the alkyl acrylate monomer into the polyolefin pellets. The absorption time is 1-5 hours depending on the kinds of the polyolefin and the alkyl acrylate monomer. 
     In the prior art, the pellets and the monomer are placed in the reactor and stirred to absorb the monomer, and then, water is added to the stirred material before polymerization. In this case, however, there is a problem in that if the control of the reactor temperature is failed, rapid polymerization can occur, thus making the use of the entire reactor impossible. On the other hand, in the present invention, water is used in the monomer absorption process, and thus, temperature is easily controlled without significantly influencing the absorption time of the monomer, and heating and cooling effects are excellent. 
     After the alkyl acrylate monomer is absorbed into polyolefin pellets, the pellets and water within the reactor are heated with stirring to induce the decomposition of the polymerization initiator and the polymerization of the acrylate monomer. The alkyl acrylate monomer and polymerization initiator absorbed into the polyolefin pellets are polymerized in the pellets to form polyacrylate. The polymerization time is 3-10 hours depending on the kinds of the polyolefin, the alkyl acrylate monomer and the polymerization initiator. 
     (Second Polymerization Step) 
     After completion of the first polymerization step, the temperature within the reactor is lowered to room temperature, and 10-85 parts by weight, based on 100 parts by weight of the product obtained in the first polymerization step, of an alkyl acrylate monomer, 10-100 parts by weight of a polar group-containing acrylate monomer, and 10-80 parts by weight of an alkyl methacrylate monomer are charged into the reactor. Also, a polymerization initiator is charged into the reactor in an amount of 0.5-2.0 mole % based on the sum of the mole of the acrylate monomers and the mole of the polymerization initiator. Then, a second polymerization step is carried out in the same manner as in the first polymerization step. If the alkyl acrylate monomer is used in an amount of less than 10 parts by weight, processability will be poor, thus making it impossible to achieve the object of the present invention, and if it is used in an amount of more than 85 parts by weight, the effect of improving paint adhesion, the object of the present invention, will be reduced. If the polar group-containing acrylate monomer is used in an amount of less than 10 parts by weight, the effect of improving paint adhesion will be reduced, and if it is used in an amount of more than 100 parts by weight, undesired side-reactions, such as intramolecular crosslinking or chemical reactions, will occur during processing steps, thus making it impossible to achieve the object of the present invention. If the alkyl methacrylate monomer is used in an amount of less than 10 parts by weight, the processabilty of the resulting product will be poor, thus making it impossible to achieve the object of the present invention, and if it is used in an amount of more than 80 parts by weight, the effect of improving paint adhesion will be reduced. If the polymerization initiator is used in an amount of less than 0.5 mole % based on the sum of the mole of the acrylate monomers and the mole of the polymerization initiator, the resulting product will be poor in processability, and if it is used in an amount of more than 2.0 mole %, the physical properties of the resulting product will be deteriorated and a difficulty in process control will be caused. 
     After completion of the polymerization, the reactor is sufficiently cooled and the reaction solution within the reactor is filtered to obtain pellets. The obtained pellets are in a swollen state as a result of the copolymerization of the absorbed acrylate monomers in the pellets. The obtained pellets are dried in a hot-air oven. 
     Hereinafter, each of the components used in the above reactions will be described in more detail. 
     (A) Polyolefin 
     Examples of polyolefin used in the present invention include high-density polyethylene, low-density polyethylene, linear low-density polyethylene, polyethylene copolymers, polyethylene having a functional group chemically bound to the main chain, and polyethylene having a functional group chemically bound to the branched chain. 
     Examples of a comonomer contained in the polyethylene copolymer include, but are not limited to, propylene, butene, pentene, octene, butadiene, ethylidene norbornene, 1,4-hexadiene, dicyclopentadiene, methyl acrylate, ethyl acrylate, butyl acrylate, glycidyl methacrylate, acrylic acid, methacrylic acid, vinyl acetate, maleic anhydride, itaconic anhydride, acrylonitrile, and acrylamide. 
     Examples of the functional group include, but are not limited to, maleic anhydride, itaconic anhydride, acrylic acid, methacrylic acid, acrylonitrile, acrylamide, vinyl pyrrolidone, and styrene. 
     Also, examples of the polyolefin used in the present invention include polypropylene, polypropylene copolymers, polypropylene having a functional group chemically bound to the main chain, and polypropylene having a functional group chemically bound to the branched chain. Examples of a copolymer used in the polypropylene copolymers include, but are not limited to, ethylene and butylene. Examples of the functional group include, but are not limited to, maleic anhydride, itaconic anhydride, acrylic acid, methacrylic acid, acrylonitrile, acrylamide, vinyl pyrrolidone, and styrene. 
     Furthermore, polyolefin used in the present invention may be a polyolefin alone or a blend of two or more polyolefins. If the blend of two or more polyolefins is used, it is preferably a blend of polyolefin and polyethylene copolymer. The polyethylene copolymer used in the polyolefin blend include, but are not limited to, poly(ethylene-co-methylacrylate), poly(ethylene-co-ethylacrylate), poly(ethylene-co-butylacrylate), poly(ethylene-co-acrylic acid), poly(ethylene-co-methacrylic acid), poly(ethylene-co-glycidyl methacrylate), poly(ethylene-co-maleic acid), poly(ethylene-co-vinyl acetate), poly(ethylene-co-acrylamide) and poly(ethylene-co-acrylonitrile). 
     (B) Acrylate Monomers 
     The acrylate monomers used in the present invention include: 1) alkyl acrylate; 2) alkyl methacrylate; and 3) a polar group-containing acrylate monomer. 
     The alkyl acrylate is an alkyl acrylate having at least one carbon atom, and preferably at least two carbon atoms, in the alkyl chain. Examples of the alkyl acrylate used in the present invention include, but are not limited to, methyl acrylate, ethyl acrylate, and butyl acrylate. 
     The alkyl methacrylate preferably has 1-18 carbon atoms in the alkyl chain. Particularly, since the alkyl methacrylate act to improve the flowability of the thermoplastic polymer and inhibit side-reactions, such as intramolecular crosslinking reaction, it is more preferably for the display of this action that the alkyl methacrylate has 1-4 carbon atoms. 
     Examples of the alkyl methacrylate used in the present invention include, but are not limited to, methyl methacrylate, ethyl methacrylate, and butyl methacrylate. 
     Examples of the polar group-containing acrylate include, but are not limited to, hydroxyalkyl acrylate, hydroxyalkyl methacrylate, acrylamide, aminoalkyl acrylate, aminoalkyl methacrylate, acrylic acid, and methacrylic acid. The polar group-containing acrylate preferably has 1-18 carbon atoms in the alkyl chain. More preferably, it has 1-4 carbon atoms so that it acts to improve the flowability of the thermoplastic polymer and to inhibit side reactions, such as intramolecular crosslinking reaction. 
     (C) Polymerization Initiator 
     As a polymerization initiator for the polymerization of the acrylate monomers, a polymerization initiator which has been used in the prior art to induce the free radical reaction of the acrylate monomers to form a polymer is used, and examples thereof include azobisisobutyronitrile, benzoyl peroxide, lauroyl peroxide, t-butyl peroxide, dicumyl peroxide, t-butyl peracetate, 2,2-bis(t-butylperoxy)butane, 2,5-bis(t-butylperoxy)-2,5-dimethyl-3-hexyne, and 2,5-bis(t-butylperoxy)-2,5-dimethylhexane. 
     The polymerization initiator can be selected from the above exemplified polymerization initiators depending on the kinds of the selected polyolefin and acrylate monomer. 
     Hereinafter, the present invention will be described in more detail by the following examples. It is to be understood, however, that these examples are not construed to limit the scope of the present invention. 
     Example 1 
     First Polymerization Step 
     As polyolefin, a polyolefin blend was used. The polyolefin blend was prepared by blending 50 Parts by weight of polypropylene (melt index: 60 g/10 min) and 100 parts by weight of poly(ethylene-co-butyl acrylate) (manufactured by DuPont; melt index: 4 g/10 min) in a co-rotating twin-screw extruder (D=20 mm, L/D=40) at a melting temperature of 170-190° C. The polyolefin blend was cooled in a cooling water bath and palletized with a pelletizer. Then, the pellets were dried in a hot-air oven at 80° C. for 3 hours. 
     Into a 50-liter reactor equipped with a stirrer, a heater and a cooler, 6.0 kg of the polyolefin blend pellets, 6.0 kg of n-butyl acrylate, 233 g of lauroyl peroxide and 27.5 kg of water were charged, and the reactor was closed. The closed reactor was purged with high-pressure nitrogen gas with stirring to remove oxygen. To lower the oxygen concentration, the purge operation was repeated three times. Then, the temperature within the reactor was elevated to 55° C. so that the n-butyl acrylate was absorbed into the polyolefin blend pellets for 2 hours. For the complete absorption of the introduced monomer, the temperature within the reactor was elevated to 65° C., followed by stirring for 1 hour. For the polymerization of the n-butyl acrylate monomer, the temperature within the reactor was elevated to 70° C., followed by stirring for 2 hours. Then, the temperature within the reactor was elevated to 75° C., with attention to heat generation caused by the polymerization, and maintained at this temperature for 1 hour. After completion of the reaction, the obtained pellets were dried in a hot-air oven at 85° C. for 6 hours. 
     Second Polymerization Step 
     The pellets obtained in the first polymerization step were subjected to a second polymerization step. 
     6.0 kg of the pellets obtained in the first polymerization step, 3.1 kg of n-butyl acrylate, 3.1 kg of methyl methacrylate, 1.6 kg of hydroxypropyl methacrylate and 317 g of lauroyl peroxide were charged into a reactor, and subjected to the second polymerization step in the same manner as in the first polymerization step. 
     After completion of the polymerization, the reactor was sufficiently cooled, and the reaction solution within the reactor was filtered to obtain pellets. The obtained pellets were in a swollen state as a result of the copolymerization of the absorbed acrylate monomer in the pellets. The obtained pellets were dried in a hot-air oven at 85° C. for 6 hours. The yield of the final product was 98.4%. 
     (Preparation of Polyolefin Compound and Paint Adhesion Test) 
     15% by weight of the completely dried pellets obtained in the second polymerization step and 85% by weight of polypropylene (melt index=60 g/10 min, 230° C., 2.16 kg) were blended with each other in a co-rotating twin-screw extruder to prepare a compound, and the compound was passed through an injection molding machine to prepare a plaque test sample. The obtained plaque test sample was applied with a suitable amount of a spray-type paint, followed by drying for 24 hours. 
     To evaluate paint adhesion, the sample was tested according to a 2 mm×2 mm block peel-off test method, and the paint adhesion of the sample was evaluated by the number of remaining paint lattice blocks. 
     Examples 2-8 
     Thermoplastic polymers were prepared in the same manner as in Example 1 except that the contents of the acrylate monomers in the second polymerization step varied as shown in Table 1 below. 
     Also, a polypropylene compound was prepared in the same manner as in Example 1, and a plaque test sample prepared from the compound was evaluated for paint adhesion. 
     Examples 9-10 
     Test samples were prepared and evaluated in the same manner as in Example 1 except that ethyl acrylate was used as alkyl acrylate. However, the prepared thermoplastic polymers were used in amounts of 15% by weight and 20% by weight, respectively, to prepare polypropylene compounds, and evaluated for paint adhesion. 
     Example 11 
     A test sample was prepared and evaluated in the same manner as in Example 1 except that methyl acrylate was used as alkyl acrylate. However, the prepared thermoplastic polymer was used in an amount of 15% by weight to prepare polypropylene compounds, and evaluated for paint adhesion. 
     Example 12 
     A test sample was prepared and evaluated in the same manner as in Example 1 except that hydroxybutyl methacrylate was used as the polar group-containing acrylate monomer. 
     Example 13 
     A test sample was prepared and evaluated in the same manner as in Example 1 except that butyl methacrylate was used as the alkyl methacrylate. 
     Examples 14-15 
     Test samples were prepared and evaluated in the same manner as in Example 1. However, the prepared thermoplastic polymers were used in amounts of 15% by weight and 20% by weight, respectively, to prepare polypropylene compounds, and evaluated for paint adhesion. 
     
       
         
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
             
           
               
                   
                 TABLE 1 
               
             
             
               
                   
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 Paint 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 adhesion 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 test result 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 (number 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 of 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 remaining 
               
               
                   
                   
                   
                   
                 Polar 
                   
                   
                   
                 paint 
               
               
                   
                   
                   
                   
                 group- 
                   
                   
                   
                 lattice 
               
               
                   
                 Pellets (kg) 
                   
                   
                 containing 
                   
                   
                   
                 blocks 
               
               
                   
                 obtained in 
                 Alkyl 
                   
                 acrylate 
                   
                 Final 
                 Polyolefin compound 
                 among 
               
             
          
           
               
                   
                 the first 
                 acrylate 
                 Alkyl 
                 monomer 
                 Polymerization 
                 product 
                   
                 Thermoplastic 
                 100 paint 
               
               
                   
                 polymerization 
                 content 
                 methacrylate 
                 content 
                 initiator 
                 yield 
                 Polyolefin 
                 polymer 
                 lattice 
               
               
                 Example 
                 step 
                 (kg) 
                 content (kg) 
                 (kg) 
                 content (g) 
                 (%) 
                 (wt %) 
                 (wt %) 
                 blocks) 
               
               
                   
               
             
          
           
               
                 1 
                 6.0 
                 3.1 
                 3.1 
                 1.6 
                 317 
                 98.4 
                 85 
                 15 
                 100 
               
               
                 2 
                 6.0 
                 3.7 
                 2.5 
                 1.5 
                 311 
                 98.7 
                 85 
                 15 
                 100 
               
               
                 3 
                 6.0 
                 3.1 
                 2.1 
                 2.1 
                 303 
                 98.1 
                 85 
                 15 
                 100 
               
               
                 4 
                 6.0 
                 3.0 
                 2.4 
                 2.1 
                 309 
                 98.2 
                 85 
                 15 
                 100 
               
               
                 5 
                 6.0 
                 3.2 
                 2.3 
                 2.1 
                 304 
                 98.0 
                 85 
                 15 
                 100 
               
               
                 6 
                 6.0 
                 3.2 
                 2.0 
                 2.3 
                 304 
                 98.3 
                 85 
                 15 
                 100 
               
               
                 7 
                 6.0 
                 1.5 
                 1.6 
                 4.5 
                 185 
                 96.4 
                 85 
                 15 
                 100 
               
               
                 8 
                 6.0 
                 2.9 
                 0.4 
                 4.2 
                 223 
                 94.2 
                 85 
                 15 
                 95 
               
               
                 9 
                 6.0 
                 1.0 
                 1.0 
                 5.6 
                 278 
                 96.3 
                 85 
                 15 
                 94 
               
               
                 10 
                 6.0 
                 1.0 
                 1.0 
                 5.6 
                 278 
                 96.3 
                 80 
                 20 
                 100 
               
               
                 11 
                 6.0 
                 1.4 
                 1.6 
                 4.5 
                 316 
                 98.3 
                 85 
                 15 
                 100 
               
               
                 12 
                 6.0 
                 3.1 
                 2.1 
                 2.1 
                 291 
                 97.9 
                 85 
                 15 
                 100 
               
               
                 13 
                 6.0 
                 3.7 
                 2.5 
                 1.5 
                 260 
                 98.2 
                 85 
                 15 
                 100 
               
               
                 14 
                 6.0 
                 1.1 
                 1.1 
                 5.5 
                 357 
                 97.9 
                 85 
                 15 
                 96 
               
               
                 15 
                 6.0 
                 1.1 
                 1.1 
                 5.5 
                 357 
                 97.9 
                 80 
                 20 
                 100 
               
               
                   
               
             
          
         
       
     
     Hereinafter, the effect of the acrylate monomers on the mechanical properties such as flexural modulus and Izod impact strength will be described by more examples. 
     Example 16 
     A test sample was prepared and evaluated in the same manner as in Example 1 except that in the second polymerization step, ethyl acrylate was used as alkyl acrylate and except that the contents of the acrylate monomers and initiator were different from the ones in example 1 as shown in Table 2 below. 
     Example 17 
     A test sample was prepared and evaluated in the same manner as in Example 1 except that in the second polymerization step, ethyl acrylate was used as alkyl acrylate, hydroxyethyl methacrylate was used as polar group-containing acrylate and except that the contents of the acrylate monomers and initiator were different from the ones in Example 1 as shown in Table 2 below. 
     Example 18 
     A test sample was prepared and evaluated in the same manner as in Example 17 except that in the second polymerization step, the contents of alkyl acrylate, polar group-containing acrylate and initiator were different from the ones in Example 17 as shown in Table 2 below. 
     Example 19 
     A test sample was prepared and evaluated in the same manner as in Example 1 except that in the second polymerization step, the contents of acrylate monomers and initiator were different from the ones in Example 1 as shown in Table 2 below. 
     
       
         
               
               
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
               
               
             
           
               
                   
                 TABLE 2 
               
             
             
               
                   
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 Paint 
                   
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 adhesion 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 test result 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 (number 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 of 
                   
                 Izod 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 remaining 
                   
                 Impact 
               
               
                   
                   
                   
                   
                 Polar 
                   
                   
                   
                 paint 
                   
                 Stremgth 
               
               
                   
                   
                   
                   
                 group- 
                   
                   
                   
                 lattice 
                   
                 (kg- 
               
               
                   
                 Pellets (kg) 
                   
                   
                 containing 
                   
                   
                   
                 blocks 
                   
                 cm/cm, 
               
               
                   
                 obtained in 
                 Alkyl 
                   
                 acrylate 
                   
                 Final 
                 Polyolefin compound 
                 among 
                 Flexural 
                 23°, 
               
             
          
           
               
                 Ex- 
                 the first 
                 acrylate 
                 Alkyl 
                 monomer 
                 Polymerization 
                 product 
                   
                 Thermoplastic 
                 100 paint 
                 Modulus 
                 notched. 
               
               
                 am- 
                 polymerization 
                 content 
                 methacrylate 
                 content 
                 initiator 
                 yield 
                 Polyolefin 
                 polymer 
                 lattice 
                 (23°, 
                 Thickness: 
               
               
                 ple 
                 step 
                 (kg) 
                 content (kg) 
                 (kg) 
                 content (g) 
                 (%) 
                 (wt %) 
                 (wt %) 
                 blocks) 
                 Kgf/Cm 2   
                 6.4 mm) 
               
               
                   
               
             
          
           
               
                 1 
                 6.0 
                 3.1 
                 3.1 
                 1.6 
                 317 
                 98.4 
                 85 
                 15 
                 100 
                 1,285 
                 30.4 
               
               
                 16 
                 6.0 
                 3.0 
                 2.4 
                 2.1 
                 341 
                 98.2 
                 85 
                 15 
                 100 
                 1,396 
                 30.4 
               
               
                 17 
                 6.0 
                 1.5 
                 3.0 
                 3.0 
                 339 
                 98.0 
                 85 
                 15 
                 100 
                 1,323 
                 35.2 
               
               
                 18 
                 6.0 
                 1.8 
                 3.0 
                 2.7 
                 342 
                 97.9 
                 85 
                 15 
                 100 
                 1,370 
                 32.9 
               
               
                 19 
                 6.0 
                 1.8 
                 3.0 
                 2.7 
                 313 
                 97.2 
                 85 
                 15 
                 100 
                 1,347 
                 33.9 
               
               
                   
               
             
          
         
       
     
     As can be seen from Table 2, the polyolefin compound according to Example 1 possesses excellent mechanical and paint adhesion properties. However, the polyolefin compound according to Example 16˜19 has excellent paint adhesion properties and possesses excellent mechanical properties that are superior to the polyolefin compound according to Example 1. 
     Comparative Example 1 
     Only polyolefin prepared in Example 1 was injection molded into a plaque test sample, and the sample was tested for paint adhesion. The results are shown in Table 3. 
     As can be seen from the test results, the polyolefin containing no thermoplastic polymer prepared by the present invention had no paint adhesion. 
     Comparative Examples 2 to 3 
     Into a 50-liter reactor equipped with a stirrer, a heater and a cooler, 6.0 kg of a blend of ethylene-butyl acrylate copolymer (melt index=4; manufactured by Borealis) and polypropylene, 12.37 kg of n-butyl acrylate, 0.15 kg of glycidyl methacrylate, 0.015 kg of 1,6-hexanedioldiacrylate, 194.60 g of lauroyl peroxide and 25 kg of water were charged, and the reactor was closed. The closed reactor was purged with high-pressure nitrogen gas with stirring to remove oxygen. To lower the oxygen concentration, the purge operation was repeated three times. The temperature within the reactor was elevated to 55° C. so that the acrylate monomers were absorbed into the polyolefin blend pellets for 1 hour. To absorb acrylate monomers which could remain in water, the temperature within the reactor was elevated to 65° C., followed by stirring for 1 hour. For the polymerization of the acrylate monomers, the temperature within the reactor was elevated to 70° C., followed by stirring for 2 hours. Then, the temperature within the reactor was elevated to 75° C., with attention to heat generation caused by the polymerization, and maintained at this temperature for 1 hour. After completion of the reaction, the obtained pellets were dried in a hot-air oven at 75° C. for 8 hours. 
     The completely dried pellets and polypropylene (melt index=60 g/10 min, 230° C., 2.16 kg) were blended with each other in a co-rotating twin-screw extruder to prepare compounds, and the prepared compounds were injection molded to prepare plaque test samples. In this regard, the contents of the pellets in the compounds were 15% by weight and 50% by weight, respectively. The obtained flat test samples were applied with a suitable amount of a spray-type paint, dried for 24 hours, and evaluated for paint adhesion by a peel-off test in the same manner as in Example 1. The results are shown in Table 3. 
     As can be seen from the test results, the thermoplastic polymer with crosslinking bonds, prepared using the multifunctional acrylate monomer, such as 1,6-hexanedioldiacrylate, had little or no effect of imparting paint adhesion when it was added to the polyolefin-based composite material. 
     Comparative Example 4 
     A test sample was prepared and evaluated in the same manner as in Example 1 except that 6.0 kg of pellets (polyolefin blend) obtained in the first polymerization step in the same manner as in Example 1, 4.3 kg of n-butyl acrylate, 3.2 kg of methyl methacrylate, and 134 g of azobisisobutyronitrile, a polymerization initiator, were charged into a reactor, and hydroxypropyl methacrylate as the polar group-containing acrylate monomer was not used. The result is shown in Table 3 below. As can be seen from the test results, the polymer containing no polar group-containing acrylate monomer, such as hydroxypropyl methacrylate, had no effect of imparting paint adhesion even when it was added to the polyolefin compound. 
     Comparative Example 5 
     A test sample was prepared and evaluated in the same manner as in Example except that 6.0 kg of pellets (polyolefin blend) prepared in the first polymerization step in the same manner as in Example 1, 2.2 kg of methyl methacrylate, 5.4 kg of hydroxypropyl methacrylate, and 189.5 g of lauroyl peroxide, a polymerization initiator were charged into a reactor, and n-butyl acrylate was not used. The result is shown in Table 3. 
     As can be seen from the test result, the polymer containing no alkyl acrylate, such as n-butyl acrylate, had no effect of imparting paint adhesion when it was added to the polyolefin compound. 
     
       
         
               
               
               
             
               
               
               
               
             
               
               
               
               
             
           
               
                   
                 TABLE 3 
               
             
             
               
                   
                   
               
               
                   
                   
                 Paint adhesion test results 
               
               
                   
                 Polyolefin compound 
                 (number of remaining paint 
               
             
          
           
               
                 Comparative 
                 Polyolefin 
                 Thermoplastic 
                 lattice) blocks among 100 
               
               
                 Example 
                 (wt %) 
                 polymer (wt %) 
                 paint lattice blocks) 
               
               
                   
               
             
          
           
               
                 1 
                 100 
                 0 
                 0 
               
               
                 2 
                 85 
                 15 
                 0 
               
               
                 3 
                 50 
                 50 
                 20 
               
               
                 4 
                 80 
                 20 
                 0 
               
               
                 5 
                 80 
                 20 
                 0 
               
               
                   
               
             
          
         
       
     
     As can be seen from the foregoing, the polyolefin-based thermoplastic polymer composition according to the present invention is very excellent in paint adhesion because it is excellent in surface polarity so that it can be applied directly with paints without a need for primer treatment.