Abstract:
A process for the production of ethanol utilizes a vacuum process and selectively permeable membranes to increase ethanol production efficiency. Yeast converts sugars to ethanol in an anaerobic condition within process chamber void of oxygen and filled with a Nitrogen gas (N2) or any non-oxygen containing gas. A glucose solution is fed into the process chamber to a yeast solution to ferment. A selectively permeable membrane filters ethanol away from the yeast and out of the process chamber. The removal of ethanol from the process chamber keeps the yeast alive to constantly produce ethanol.

Description:
CROSS REFERENCE TO RELATED APPLICATION 
     This application is a continuation in part of U.S. patent application Ser. No 11/099,404 which was filed on Apr. 5, 2005, now abandoned. 
    
    
     BACKGROUND OF THE INVENTION 
     This invention relates generally to the field of renewable fuel productions and more specifically to a process for the production of ethanol by use of a vacuum process and selectively permeable membranes to increase ethanol production efficiency. 
     Production of ethanol is an age old technology that has lacked development throughout the centuries. In both traditional ethanol production (wine making, etc) and commercial ethanol production yeast, a facultative anaerobe, is placed in a solution of sugar or fermenting mash that is open in some way to oxygen. The yeast is allowed to ferment the sugars (glucose) into ethanol until the concentration of ethanol to fermenting mash reaches approximately 15%, at which, the enzyme in the yeast that converts sugar to ethanol is destroyed or denatured due to the high concentration of ethanol and hence ceasing ethanol production. Ethanol production is both more time consuming and only partially efficient. 
     To overcome some obstacles in ethanol production, such as random strains of bacteria ruining the ethanol production process, traditional and commercial ethanol producers sanitize all the equipment used in ethanol production in some way (usually through the use of an iodine solution) to ensure that ethanol and not vinegar will be produced. This has helped to improve the efficiency of ethanol production. Ethanol production ceases once the concentration of ethanol to fermenting mash reaches approximately 15%. To overcome this barrier, some producers have experimented with different strains of yeast or genetically altered yeast to produce high tolerance yeast that can continue to produce ethanol until the concentration of ethanol to fermenting mash reaches approximately 18% to 20%. Basically, the yeast that produces ethanol has a higher tolerance to ethanol concentrations and will not denature until a concentration of approximately 18% to 20% has been reached but this form of improvement (yeast being tolerant to ethanol) is limited. 
     Deficiencies in prior technology include the presence of oxygen in the fermenting mash, either at the surface of the mash or dissolved within the mash, and the fact that the yeast is directly exposed to the fermenting mash. When yeast has oxygen available to it, it will go through cellular respiration rather than alcoholic fermentation, hence making ATP (adenosine triphosphate) instead of ethanol. 
     Accordingly, it is desirable to design and develop new methods and systems for increasing the efficiency in the ethanol producing process. 
     SUMMARY OF THE INVENTION 
     An example method and system increases the efficiency of ethanol production by removing oxygen from contact with ethanol producing yeast, and by continuously removing ethanol through a selectively permeable membrane. 
     An example system utilizes a vacuum process to eliminate oxygen in the fermenting mash to ensure that fermenting mash is not exposed to oxygen during fermentation. This provides for the constant production of ethanol because the yeast is a facultative anaerobe. 
     By eliminating all forms of oxygen, the yeast is forced to constantly go through alcoholic fermentation, hence constantly producing ethanol. This allows the efficiency rate of ethanol production to be greatly improved. A selectively permeable membrane is utilized to maintain a maximum concentration of ethanol with basic yeast of approximately 15% and with genetically engineered yeast of approximately 18-20%. The yeast is suspended within the selectively permeable membrane such that the ethanol and perhaps small amounts of the fermenting yeast pass through the membrane while keeping the yeast inside the membrane with a fresh supply of fermenting mash (glucose solution). This allows the concentration of ethanol to fermenting mash to stay below 15% and allow for constant ethanol production without denaturing the yeast. 
     Accordingly, an example system and method provides for improved efficiency in the production of ethanol. 
     These and other features of the present invention can be best understood from the following specification and drawings, the following of which is a brief description. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a schematic view of an example device for producing ethanol. 
         FIG. 2  is an enlarged schematic view of an example tube of the example device. 
         FIG. 3  is another enlarged schematic view of an example tube of the example device. 
     
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 
     Referring to  FIG. 1 , an example ethanol producing device  10  includes a fermenting chamber  12  that is void of oxygen and filled with a non-oxygen containing gas. Air within the fermenting chamber  12  is removed through a vacuum line  16  and Nitrogen gas (N2)  30  is fed into the fermenting chamber  12  through a hose  20 . 
     A bundle  14  of tubes  32  is disposed within the fermenting chamber  12 . Each of the tubes  32  are fabricated from a selectively permeable membrane that allows ethanol  24  to migrate through the tubes  14  and into the fermenting chamber  12  where it is exhausted through the outlet  22 . 
     The example process for the production of ethanol utilizes a pressure differential between a pressure P 1  within the tubes  32 , and a pressure P 2  within the fermentation chamber  12  to draw ethanol  24  through the selectively permeable membrane of the tubes  32  and into the fermentation chamber  12 . 
     The example process includes the initial step of introducing a biologically pure yeast culture into each of the tubes  14 . The fermentation chamber  12  is sealed from ambient air and oxygen and is filled with a non-oxygen containing gas such as for example Nitrogen  30 . Because the fermentation chamber  12  is substantially void of oxygen, the yeast culture maintains alcoholic fermentation of the glucose solution  28 . In the presence of oxygen, the yeast culture will undergo a cellular respiration and produces ATP (adenosine triphosphate) instead of the desired ethanol. 
     The fermentation chamber can begin with a non-oxygen containing gas such as Nitrogen  30 . Alternatively, a vacuum applied through the vacuum hose  16  can first remove any oxygen or air to provide for replacement with the desired non-oxygen containing gas. Oxygen removal is accomplished with a vacuum pumping system as is known. Other methods of removing oxygen from the fermentation chamber  12  in preparation for filling with a non-oxygen containing gas are also within the contemplation of this invention. 
     Once the fermentation chamber  12  is devoid of substantially all oxygen, the glucose solution  28  is fed into the bundle  14  of tubes  32 . Each of the tubes  32  includes a desired amount of yeast that goes through an alcoholic fermentation in combination with the introduced glucose solution  28 . The non-oxygen atmosphere within the fermentation chamber  12  ensures that the yeast and glucose solution will undergo alcoholic fermentation to produce ethanol. 
     The glucose solution  28  is fed into the tubes  32  within the fermentation chamber  12  at a rate determined to provide a desired production of ethanol. The fermentation chamber  12  includes the inlet  18  for the glucose solution  28  and the outlet  22  for the ethanol  24  produced. The tubes  32  are made from a selectively permeable membrane that provides for the evacuation of ethanol, while maintaining the yeast and glucose solution within the tubes  14 . 
     Referring to  FIGS. 2 and 3 , the tube  32  includes a wall fabricated of a selectively permeable membrane  34 . The selectively permeable membrane  34  if of material compatible with the environment within the fabrication chamber  12 . Further, the selectively permeable membrane  34  is of a defined porosity that allows Ethanol to pass through, but that does not allow other elements such as the yeast  40  to pass through. The porosity is a function of the open area that allows ethanol evacuation for a give area. The example tube  32  includes a number of pores  35  ( FIG. 3 ) disposed over the surface area of the tube  32 . The number and size of pores  35  are determined based on the size of the specific yeast utilized in fermentation process. The permeable membrane  34  prevents the evacuation of the yeasts  40  and glucose solutions  28  to maintain the desired production of ethanol  24 . Selectively permeable membranes are known devices and are available for allowing desired content and elements through while retaining the desired elements and compounds within the chamber. 
     Referring back to  FIG. 1 , with continued reference to  FIGS. 2 and 3 , during the alcoholic fermentation process, the inside of the tube  32  begins to become filled with ethanol  24 . A desired percentage of ethanol  24  within the tube relative to the amount of yeast  40  is controlled by controlling the flow of ethanol  24  through the selectively permeable membrane  34 . The flow of ethanol through the selectively permeable membrane  34  is controlled by controlling a pressure differential between P 1  and P 2  across the permeable membrane  34 . Control of the pressure differential across the permeable membrane  34  along with the specific porosity of the permeable membrane  34  relative to the yeast  40  and glucose solution  28  utilized for the example process provide for a substantially continuous process where glucose  28  is fed in and ethanol  24  is forced through the selectively permeable membrane  34 . Accordingly, the desired flow of ethanol from the plurality of tubes  14  is controlled and continuous. 
     The percent of ethanol  24  to yeast  40  is maintained at a rate determined to not cause the denaturing of the yeast  40 . As appreciated, yeasts of different purities perform most efficiently ad different ethanol concentrations. For example, alcoholic fermentation for normal yeasts begins to degrade as the ethanol concentration approaches 15% relative to the amount of yeasts. Some genetically engineered yeast provides efficient ethanol production up approaching 18-20% ethanol relative to the amount of yeast contained within the process chamber. The system and method of this invention maintains the desired ratio of yeast to ethanol by evacuating ethanol through the selectively permeable membrane  34 . Accordingly, the process can continue for as long as glucose solution is fed into the bundle of tubes  14 . 
     The yeast  40  is suspended within the tubes  14  of the fermentation chamber  12  and does not move through the selectively permeable membrane  34 . The selectively permeable membrane  34  is selected from commercially available devices according to the specific yeast and glucose utilized for the fermentation process. A worked skilled in the art would understand that selectively permeable membranes of differing capabilities can be utilized for different conditions created by different yeast types and glucose types. Further, as the selectively permeable membrane  34  allows ethanol  24  to pass therethrough, and not a substantial portion of the other contents within the tube  32 , the selectively permeable membrane  34  selected will always provide for a desired amount of ethanol  24  to diffuse therethrough responsive to a pressure differential determined to provide the driving force for exhausting a desired amount of ethanol from the tube  32  that would provide a desired balance within each of the tubes  32 . 
     A fresh supply of glucose solution  28 , also known in the art as “fermenting mash” is continually introduced into the tubes  32  as required to maintain the desired rate of ethanol production that corresponds to the desired concentration of ethanol within the fermentation chamber  12 . 
     The glucose solution  28  flows through the tube  32  in contact with the yeast  40 . Circulation of the glucose solution  28  provides for reuse of the solution to efficiently utilize any glucose that did not undergo the fermentation process. 
     While the invention has been described in connection with a preferred embodiment, it is not intended to limit the scope of the invention to the particular form set forth, but on the contrary, it is intended to cover such alternatives, modification, and equivalents as may be included within the spirit and scope of the invention as defined by the appended claims. 
     Although a preferred embodiment of this invention has been disclosed, a worker of ordinary skill in this art would recognize that certain modifications would come within the scope of this invention. For that reason, the following claims should be studied to determine the true scope and content of this invention.