Abstract:
In an embodiment, a polycrystalline diamond compact includes a substrate and a preformed polycrystalline diamond table having an upper surface, an interfacial surface, and at least one side surface extending therebetween. The interfacial surface of the polycrystalline diamond table is bonded to the substrate. The polycrystalline diamond table includes bonded diamond grains defining interstitial regions. The polycrystalline diamond table includes a first region extending inwardly from at least a portion of the upper surface and at least a portion of the at least one side surface. The first region spaced from the interfacial surface. The polycrystalline diamond table includes at least a second region extending inwardly from the interfacial surface to the upper surface. The first region includes at least a first infiltrant disposed interstitially between the bonded diamond grains thereof. The second region includes at least a second infiltrant disposed interstitially between the bonded diamond grains thereof.

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     This application is a continuation of U.S. application Ser. No. 13/230,125 filed on 12 Sep. 2011, which is a continuation of U.S. application Ser. No. 11/983,619 filed on 9 Nov. 2007 (now U.S. Pat. No. 8,034,136 issued on 11 Oct. 2011), which claims the benefit of U.S. Provisional Application No. 60/860,098 filed on 20 Nov. 2006 and U.S. Provisional Application No. 60/876,701 filed on 21 Dec. 2006, the contents of each of the foregoing applications are incorporated herein, in their entirety, by this reference. 
    
    
     BACKGROUND 
     Wear-resistant, superabrasive compacts are utilized for a variety of mechanical applications. For example, polycrystalline diamond compacts (“PDCs”) are used in drilling tools (e.g., cutting elements, gage trimmers, etc.), machining equipment, bearing apparatuses, wire-drawing machinery, and in other mechanical systems. 
     PDCs have found particular utility as superabrasive cutting elements in rotary drill bits, such as roller cone drill bits and fixed cutter drill bits. A PDC cutting element or cutter typically includes a superabrasive diamond layer or table. The diamond table is formed and bonded to a substrate using an ultra-high pressure, ultra-high temperature (“HPHT”) process. The substrate is often brazed or otherwise joined to an attachment member such as a stud or a cylindrical backing. A stud carrying the PDC may be used as a PDC cutting element when mounted to a bit body of a rotary drill bit by press-fitting, brazing, or otherwise securing the stud into a receptacle formed in the bit body. The PDC cutting element may also be brazed directly into a preformed pocket, socket, or other receptacle formed in the bit body. Generally, a rotary drill bit may include a number of PDC cutting elements affixed to the drill bit body. 
     Conventional PDCs are normally fabricated by placing a cemented-carbide substrate into a container or cartridge with a volume of diamond particles positioned on a surface of the cemented-carbide substrate. A number of such cartridges may be typically loaded into an HPHT press. The substrates and volume of diamond particles are then processed under HPHT conditions in the presence of a catalyst material that causes the diamond particles to bond to one another to form a matrix of bonded diamond grains defining a diamond table. The catalyst material is often a solvent catalyst, such as cobalt, nickel, or iron that is used for facilitating the intergrowth of the diamond particles. 
     In one conventional approach, a constituent of the cemented-carbide substrate, such as cobalt from a cobalt-cemented tungsten carbide substrate, liquefies and sweeps from a region adjacent to the volume of diamond particles into interstitial regions between the diamond particles during the HPHT process. The cobalt acts as a catalyst to facilitate intergrowth between the diamond particles, which results in formation of bonded diamond grains. Often, a solvent catalyst may be mixed with the diamond particles prior to subjecting the diamond particles and substrate to the HPHT process. 
     The solvent catalyst dissolves carbon from the diamond particles or portions of the diamond particles that graphitize due to the high temperature being used in the HPHT process. The solubility of the stable diamond phase in the solvent catalyst is lower than that of the metastable graphite under HPHT conditions. As a result of this solubility difference, the undersaturated graphite tends to dissolve into solvent catalyst and the supersaturated diamond tends to deposit onto existing diamond particles to form diamond-to-diamond bonds. Accordingly, diamond grains become mutually bonded to form a matrix of polycrystalline diamond with interstitial regions between the bonded diamond grains being occupied by the solvent catalyst. 
     The presence of the solvent catalyst in the diamond table is believed to reduce the thermal stability of the diamond table at elevated temperatures. For example, the difference in thermal expansion coefficient between the diamond grains and the solvent catalyst is believed to lead to chipping or cracking in the PDC during drilling or cutting operations, which consequently can degrade the mechanical properties of the PDC or cause failure. Additionally, some of the diamond grains can undergo a chemical breakdown or back-conversion with the solvent catalyst. At extremely high temperatures, portions of diamond grains may transform to carbon monoxide, carbon dioxide, graphite, or combinations thereof, thus, degrading the mechanical properties of the PDC. Therefore, manufacturers and users of superabrasive materials continue to seek improved thermally stable, superabrasive materials and processing techniques. 
     SUMMARY 
     In one embodiment of the present invention, a method of fabricating a superabrasive article is disclosed. A mass of un-sintered diamond particles may be infiltrated with metal-solvent catalyst from a metal-solvent-catalyst-containing material to promote formation of a sintered body of diamond grains including interstitial regions. At least a portion of the interstitial regions may also be infiltrated with silicon from a silicon-containing material. The silicon reacts with the sintered body to form silicon carbide within a portion of the interstitial regions. 
     In another embodiment of the present invention, another method of fabricating a superabrasive article is disclosed. At least a portion of interstitial regions of a pre-sintered polycrystalline diamond body may be infiltrated with silicon from a silicon-containing material. At least a portion of metal-solvent catalyst located within the at least a portion of interstitial regions of the pre-sintered polycrystalline diamond body may be displaced into a porous mass. The silicon and the pre-sintered polycrystalline diamond body are reacted to form silicon carbide within the at least a portion of the interstitial regions. A section of the polycrystalline diamond table so-formed may be removed by a suitable material-removal process so that an upper region of the polycrystalline diamond table includes substantially only silicon carbide within the interstitial regions thereof. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       The drawings illustrate several embodiments of the present invention, wherein like reference numerals refer to like or similar elements in different views or embodiments shown in the drawings. 
         FIG. 1A  is a schematic side cross-sectional view of an assembly including a substrate, a porous polycrystalline diamond body, and a silicon-containing material used to fabricate a PDC according to one embodiment of the present invention. 
         FIG. 1B  is a schematic side cross-sectional view of an assembly including a substrate, a porous polycrystalline diamond body in which a region remote from the substrate contains tungsten carbide, and a silicon-containing material used to fabricate a PDC according to one embodiment of the present invention. 
         FIG. 2A  is a schematic side cross-sectional view of the PDC resulting from HPHT sintering of the assembly shown in  FIG. 1A . 
         FIG. 2B  is a schematic perspective view of the PDC shown in  FIG. 2A . 
         FIG. 3A  is a schematic side cross-sectional view of another assembly that may be used to form a PDC with an annular-shaped cutting region according to another embodiment of the present invention. 
         FIG. 3B  is a schematic side cross-sectional view of another assembly that may be used to form a PDC in which silicon infiltrates into a polycrystalline diamond body through sides thereof according to another embodiment of the present invention. 
         FIG. 4  is a schematic side cross-sectional view of the PDC resulting from HPHT sintering of the assembly shown in  FIG. 3A . 
         FIG. 5  is a schematic side cross-sectional view of another assembly that may be used to form the PDC shown in  FIGS. 2A and 2B  according to another embodiment of the present invention. 
         FIG. 6  is a schematic side cross-sectional view of another assembly that may be used to form the PDC shown in  FIGS. 2A and 2B  according to yet another embodiment of the present invention. 
         FIG. 7  is a schematic side cross-sectional view of an assembly including a substrate, un-sintered diamond particles, a metal-solvent-catalyst material, and a silicon-containing material used to fabricate a PDC according to another embodiment of the present invention. 
         FIG. 8  is a schematic side cross-sectional view of the PDC resulting from HPHT sintering of the assembly shown in  FIG. 7 . 
         FIG. 9  is a schematic side cross-sectional view of an assembly including a substrate, a silicon-containing material, a diamond table, and porous mass used to fabricate a PDC according to another embodiment of the present invention. 
         FIG. 10  is a schematic side cross-sectional view of the resulting structure formed from HPHT sintering of the assembly shown in  FIG. 9 . 
         FIG. 11  is a PDC formed by removing a portion of the multi-region structure shown in  FIG. 10 . 
         FIG. 12  is a schematic cross-sectional view of an assembly including a substrate, a mass of un-sintered diamond particles, and layers of metal-solvent-catalyst-containing material and silicon-containing material disposed between the substrate and the mass of un-sintered diamond particles used to fabricate a PDC according to another embodiment of the present invention. 
         FIG. 13  is a schematic side cross-sectional view of the resulting structure from HPHT sintering of the assembly shown in  FIG. 12 . 
         FIG. 14  is an isometric view of one embodiment of a rotary drill bit including at least one superabrasive cutting element including a PDC configured according to any of the various PDC embodiments of the present invention. 
         FIG. 15  is a top elevation view of the rotary drill bit of  FIG. 14 . 
         FIG. 16  is a graph showing the measured temperature versus linear distance during a vertical turret lathe test on a conventional, leached PDC and a PDC according to working example 2 of the present invention. 
         FIG. 17  is a graph showing the measured normal force versus linear distance during a vertical turret lathe test on a conventional, leached PDC and a PDC according to working example 2 of the present invention. 
         FIG. 18  is a graph illustrating the wear flat volume characteristics of a conventional, leached PDC and a PDC according to working example 2 of the present invention. 
     
    
    
     DETAILED DESCRIPTION 
     Embodiments of the present invention relate to methods of fabricating superabrasive articles, such as PDCs, and intermediate articles formed during fabrication of such PDCs. For example, many different PDC embodiments disclosed herein include a thermally-stable polycrystalline diamond table in which silicon carbide occupies a portion of the interstitial regions formed between bonded diamond grains. The superabrasive articles disclosed herein may be used in a variety of applications, such as drilling tools (e.g., compacts, cutting elements, gage trimmers, etc.), machining equipment, bearing apparatuses, wire-drawing machinery, and other apparatuses. As used herein, the term “superabrasive” means a material that exhibits a hardness exceeding a hardness of tungsten carbide. For example, a superabrasive article is an article of manufacture, at least a portion of which exhibits a hardness exceeding the hardness of tungsten carbide. 
       FIGS. 1A-2B  show an embodiment of a method according to the present invention for fabricating a PDC and the resulting structure of the PDC. As shown in  FIG. 1A , an assembly  10  includes an at least partially porous polycrystalline diamond body  14  (i.e., a pre-sintered polycrystalline diamond body) positioned adjacent to a substrate  12 . The assembly  10  further includes a silicon-containing material  16  positioned adjacent to the polycrystalline diamond body  14  on a side of the polycrystalline diamond body  14  opposite the substrate  12 . In one embodiment of the present invention, the silicon-containing material  16  may comprise a green body of elemental silicon particles (e.g., crystalline or amorphous silicon particles) in the form of a tape-casted tape that is placed adjacent to the polycrystalline diamond body  14 . In another embodiment of the present invention, the silicon-containing material  16  may comprise a disc of silicon. 
     Still referring to  FIG. 1A , the polycrystalline diamond body  14  includes a plurality of interstitial regions that were previously occupied by metal-solvent catalyst. The polycrystalline diamond body  14  may be fabricated by subjecting a plurality of diamond particles (e.g., diamond particles having an average particle size between 0.5 μm to about 150 μm) to an HPHT sintering process in the presence of a metal-solvent catalyst, such as cobalt, or other catalyst to facilitate intergrowth between the diamond particles to form a polycrystalline diamond table of bonded diamond grains. In one embodiment of the present invention, the sintered diamond grains of the polycrystalline diamond body  14  may exhibit an average grain size of about 20 μm or less. The polycrystalline diamond table so-formed may be immersed in an acid, such as aqua-regia, a solution of 90% nitric acid/10% de-ionized water, or subjected to another suitable process to remove at least a portion of the metal-solvent catalyst from the interstitial regions of the polycrystalline diamond table. 
     In one embodiment of the present invention, the polycrystalline diamond table is not formed by sintering the diamond particles on a cemented-tungsten-carbide substrate or otherwise in the presence of tungsten carbide. In such an embodiment, the interstitial regions of the polycrystalline diamond body  14  may contain no tungsten and/or tungsten carbide or insignificant amounts of tungsten and/or tungsten carbide, which can inhibit removal of the metal-solvent catalyst. 
     In other embodiments of the present invention, a polycrystalline diamond table may be formed by HPHT sintering diamond particles in the presence of tungsten carbide. For example, diamond particles may be placed adjacent to a cemented tungsten carbide substrate and/or tungsten carbide particles may be mixed with the diamond particles prior to HPHT sintering. In such an embodiment, the polycrystalline diamond table so-formed may include tungsten and/or tungsten carbide that is swept in with metal-solvent catalyst from the substrate or intentionally mixed with the diamond particles during HPHT sintering process. For example, some tungsten and/or tungsten carbide from the substrate may be dissolved or otherwise transferred by the liquefied metal-solvent catalyst (e.g., cobalt from a cobalt-cemented tungsten carbide substrate) of the substrate that sweeps into the diamond particles. The polycrystalline diamond table so-formed may be separated from the substrate using a lapping process, a grinding process, wire-electrical-discharge machining (“wire EDM”), or another suitable material-removal process. The separated polycrystalline diamond table may be immersed in a suitable acid (e.g., a hydrochloric acid/hydrogen peroxide solution) to remove substantially all of the metal-solvent catalyst from the interstitial regions and form the polycrystalline diamond body  14 . However, an indeterminate amount of tungsten and/or tungsten carbide may remain distributed throughout the polycrystalline diamond body  14  even after leaching. The presence of the tungsten and/or tungsten carbide within the polycrystalline diamond body  14  is currently believed to significantly improve the abrasion resistance thereof even after infiltration with silicon and HPHT bonding to the substrate  12 , as will discussed in more detail below. 
     In a variation of the above-described embodiment in which the polycrystalline diamond body  14  has tungsten and/or tungsten carbide distributed therein, the polycrystalline diamond body  14  may comprise a first portion including tungsten and/or tungsten carbide and a second portion that is substantially free of tungsten and/or tungsten carbide. For example, a layer of metal-solvent catalyst (e.g., cobalt) may be positioned between diamond particles and a cemented-carbide substrate (e.g., cobalt-cemented tungsten carbide substrate) and subjected to HPHT conditions. During the HPHT sintering process, metal-solvent catalyst from the layer sweeps through the diamond particles to effect intergrowth and bonding. Because the volume of the layer of metal-solvent catalyst is selected so that it is not sufficient to fill the volume of all of the interstitial regions between the diamond particles, metal-solvent catalyst from the substrate also sweeps in, which may carry or transfer tungsten and/or tungsten carbide. Thus, a first region of the polycrystalline diamond table so-formed adjacent to the substrate includes tungsten and/or tungsten carbide and a second region remote from the substrate is substantially free of tungsten and/or tungsten carbide. The volume of the layer of metal-solvent catalyst may be selected so that the second region exhibits a thickness substantially greater than the second region. In this embodiment, the metal-solvent catalyst within the interstitial regions between bonded diamond grains of the polycrystalline diamond table may be removed from the second region more easily. For example, the metal-solvent catalyst may be leached from the first region using a hydrochloric acid/hydrogen peroxide solution and the metal-solvent catalyst in the second region may be leached using a less aggressive nitric acid/hydrofluoric acid solution. As shown in  FIG. 1B , the polycrystalline diamond body  14  so-formed after leaching may be oriented with the second region (shown as  14 A) that is substantially free of tungsten and/or tungsten carbide positioned adjacent to the substrate  12  in the assembly  10  and the first region (shown as  14 B) that includes tungsten and/or tungsten carbide positioned remote from the substrate  12  to form at least part of a working or cutting region of a PDC that is ultimately formed after processing. 
     Referring again to  FIG. 1A , in another embodiment of the present invention, the polycrystalline diamond body  14  may be formed by sintering diamond particles or other particles capable of forming diamond in response to an HPHT sintering process without a catalyst. For example, U.S. patent application Ser. Nos. 11/351,564 and 11/496,905, each of which is incorporated herein, in its entirety, by this reference, disclose that ultra-dispersed diamond particles and fullerenes may be mixed with diamond particles and HPHT sintered to form a polycrystalline diamond body. 
     The substrate  12  may comprise a cemented-carbide material, such as a cobalt-cemented tungsten carbide material or another suitable material. For example, nickel, iron, and alloys thereof are other metal-solvent catalysts that may comprise the substrate  12 . Other materials that may comprise the substrate  12  include, without limitation, cemented carbides including titanium carbide, niobium carbide, tantalum carbide, vanadium carbide, and combinations of any of the preceding carbides cemented with iron, nickel, cobalt, or alloys thereof. A representative thickness for the substrate  12  is a thickness of about 0.100 inches to at least about 0.350 inches, more particularly about 0.150 inches to at least about 0.300 inches, and even more particularly about 0.170 inches to at least about 0.290 inches. 
     The assembly  10  may be placed in a pressure transmitting medium, such as a refractory metal can, graphite structure, pyrophyllite or other pressure transmitting structure, or another suitable container or supporting element. Methods and apparatuses for sealing enclosures suitable for holding the assembly  10  are disclosed in U.S. patent application Ser. No. 11/545,929, which is incorporated herein, in its entirety, by this reference. The pressure transmitting medium, including the assembly  10 , is subjected to an HPHT process using an ultra-high pressure press at a temperature of at least about 1000° Celsius (e.g., about 1300° Celsius to about 1600° Celsius) and a pressure of at least 40 kilobar (e.g., about 50 kilobar to about 70 kilobar) for a time sufficient to sinter the assembly  10  and form a PDC  18  as shown in  FIGS. 2A and 2B . Stated another way, the HPHT bonds the polycrystalline diamond body  14  to the substrate  12  and causes at least partial infiltration of the silicon into the polycrystalline diamond body  14 . The HPHT temperature may be sufficient to melt at least one constituent of the substrate  12  (e.g., cobalt, nickel, iron, or another constituent) and the silicon comprising silicon-containing material  16 . The PDC  18  may exhibit other geometries than the geometry illustrated in  FIGS. 2A and 2B . For example, the PDC  18  may exhibit a non-cylindrical geometry, and the PDC  18  may also include a chamfer along a peripheral region thereof. 
     As shown in  FIGS. 2A and 2B , the HPHT sintered PDC  18  comprises a polycrystalline diamond table  15  that may include three regions: a first region  20 , a second-intermediate region  22 , and a third region  24 . The first region  20  includes polycrystalline diamond with substantially only silicon carbide formed within the interstitial regions between the bonded diamond grains of the first region  20 . It is noted that the interstitial regions of at least the first region  20  may also include tungsten carbide when tungsten carbide is present in the polycrystalline diamond body  14 , such as in the embodiment shown in  FIG. 1B . During the HPHT process, silicon from the silicon-containing material  16  liquefies and at least partially infiltrates the interstitial regions of the polycrystalline diamond body  14 . The silicon reacts with the diamond grains of the polycrystalline diamond body  14  to form silicon carbide, which occupies the interstitial regions between the diamond grains and bonds to the diamond grains. Further, the amount of the silicon-containing material  16  may be selected so that the silicon of the silicon-containing material  16  fills a selected portion of the interstitial regions of the polycrystalline diamond body  14 . 
     During the HPHT sintering process, metal-solvent catalyst from the substrate  12  or another source also sweeps into the interstitial regions of the polycrystalline diamond body  14  and fills some of the interstitial regions thereof, in addition to silicon carbide filling other interstitial regions as previously described with respect to the first region  20 . In one embodiment of the present invention, the second-intermediate region  22  of the polycrystalline diamond table  15  may include polycrystalline diamond with silicon carbide formed within a portion of the interstitial regions between the bonded diamond grains of the second-intermediate region  22  and metal-solvent catalyst (e.g., cobalt) occupying another portion of the interstitial regions between the bonded diamond grains of the second-intermediate region  22 . In another embodiment of the present invention, substantially all of or only a portion of the interstitial regions of the second-intermediate region  22  may include an alloy of silicon and the metal-solvent catalyst, such as a silicon-cobalt solid solution alloy or an intermetallic compound of cobalt and silicon. In yet another embodiment of the present invention, each interstitial region of the second-intermediate region  22  of the polycrystalline diamond table  15  may include one or more of the following materials: silicon carbide, metal-solvent catalyst, silicon, and an alloy of silicon and metal-solvent catalyst. The third region  24  includes polycrystalline diamond with substantially only metal-solvent catalyst (e.g., cobalt) occupying the interstitial regions between the bonded diamond grains. The metal-solvent catalyst occupying the interstitial regions of the third region  24  is liquefied and swept into the polycrystalline diamond body  14  from the substrate  12  or another source (e.g., a metal disk, particles, etc.) during the HPHT sintering process. The third region  24  provides a strong, metallurgical bond between the substrate  12  and the polycrystalline diamond table  15 . It is noted that at least the first region  20  of the polycrystalline diamond table  15  may be substantially free of non-silicon carbide type carbides, such as tungsten carbide, when the polycrystalline diamond body  14  is not formed in the presence of tungsten carbide. 
     The PDC  18  shown in  FIGS. 2A and 2B  exhibits an improved thermal stability relative to a conventional PDC in which the interstitial regions of the diamond table are occupied with only cobalt or another metal-solvent catalyst. Additionally, the wear resistance of the PDC  18  may be improved relative to a conventional PDC because the silicon carbide phase occupying the interstitial regions of the first region  20  exhibits a hardness greater than a hardness of cobalt or other metal-solvent catalysts. 
     Although the assembly  10  shown in  FIGS. 1A and 1B  includes the substrate  12 , in another embodiment of the present invention, the substrate  12  may be omitted. In such an embodiment of the present invention, an assembly of the polycrystalline diamond body  14  and the silicon-containing material  16  may be subjected to an HPHT process to form a polycrystalline diamond table. After the HPHT process, a carbide layer (e.g., a tungsten carbide layer) may be deposited on the polycrystalline diamond table, as disclosed in U.S. Patent Application No. 60/850,969, to form a PDC and enable attaching the PDC to a bit body of a rotary drill bit. U.S. Patent Application No. 60/850,969 is incorporated herein, in its entirety, by this reference. In another embodiment of the present invention, the polycrystalline diamond table may be brazed or otherwise secured to a bit body of a rotary drill bit. 
     One of ordinary skill in the art will recognize that many variations for selectively forming silicon carbide regions within a pre-sintered polycrystalline diamond body may be employed. For example, in another embodiment of the present invention, a PDC may be formed with a polycrystalline diamond table including a cutting region exhibiting a selected configuration. The cutting region may comprise bonded diamond grains with silicon carbide within the interstitial regions between the bonded diamond grains. As shown in  FIG. 3A , a silicon-containing material  16 ′ in the form of an annular disc of silicon or amorphous silicon, or an annular, green body of silicon particles in the form of a tape-casted tape may be placed adjacent to the polycrystalline diamond body  14 . 
     As shown in  FIG. 4 , upon subjecting assembly  10 ′ to HPHT sintering conditions as described generally hereinabove with respect to the assembly  10 , a PDC  18 ′ is formed with a polycrystalline diamond table  15 ′ including an annular, cutting region  20 ′ formed peripherally about an annular, intermediate region  22 ′ and a third region  24 ′. The cutting region  20 ′ comprises bonded diamond grains with substantially only silicon carbide within the interstitial regions between the bonded diamond grains. In one embodiment of the present invention, the intermediate region  22 ′ comprises bonded diamond grains with silicon carbide within a portion of the interstitial regions and metal-solvent catalyst from the substrate  12  or another source within another portion of the interstitial regions. In another embodiment of the present invention, substantially all of or only a portion of the interstitial regions of the second-intermediate region  22 ′ includes an alloy of silicon and metal-solvent catalyst, such as a silicon-cobalt solid solution alloy or an intermetallic compound of cobalt and silicon. In yet another embodiment of the present invention, each interstitial region of the second-intermediate region  22 ′ of the polycrystalline diamond table  15  may include one or more of the following materials: silicon carbide, metal-solvent catalyst, silicon, and an alloy of silicon and metal-solvent catalyst. The third region  24 ′ is formed adjacent to the substrate  12  and provides a strong, metallurgical bond between the polycrystalline diamond table  15 ′ and the substrate  12 . The third region  24 ′ comprises bonded diamond grains with substantially only the metal-solvent catalyst from the substrate  12  or another source within the interstitial regions between the bonded diamond grains. Depending upon the geometry of the silicon-containing material  16 ′, the geometry of the cutting region  20 ′ of the polycrystalline diamond table  15 ′ may also be formed to exhibit other selected geometries. 
       FIG. 3B  shows another embodiment of the present invention in which a silicon-containing material  16 ″ may be positioned adjacent to at least one peripheral surface  17  of the polycrystalline diamond body  14 . HPHT processing causes silicon from the silicon-containing material  16 ″ to at least partially or substantially infiltrate the polycrystalline diamond body  14 . For example, the silicon from the silicon-containing material  16 ″ may partially infiltrate the polycrystalline diamond body  14  to form a PDC including a multi-region polycrystalline diamond table. 
     As shown in  FIG. 5 , in another embodiment of the present invention, the PDC  18  may be formed by subjecting an assembly  21  to HPHT sintering process conditions similar to that employed on the assembly  10 . The assembly  21  includes a silicon-containing material  16  positioned adjacent to a substrate  12 , and between the substrate  12  and a polycrystalline diamond body  14 . During HPHT sintering, the assembly  21  is heated at a sufficient rate so that the metal-solvent catalyst (e.g., cobalt) and the silicon in the silicon-containing material  16  are in a liquid state at substantially the same time. Such heating may cause the molten, metal-solvent catalyst (e.g., from the substrate  12 , metal-solvent catalyst mixed with the silicon-containing material  16 , or another source) to occupy a portion of the interstitial regions of the polycrystalline diamond body  14  and may cause the molten silicon to occupy other portions of the interstitial regions of the polycrystalline diamond body  14 . Upon cooling, the resultant, as-sintered PDC may exhibit a similar multi-region diamond table as the polycrystalline diamond table  15  shown in  FIGS. 2A and 2B . 
       FIG. 6  shows another embodiment of the present invention in which a PDC  13  including a leached polycrystalline diamond table  19  and a silicon-containing material  16  are assembled and HPHT sintered using HPHT sintering conditions as described generally hereinabove with respect to the assembly  10 . In this embodiment, the PDC  13  may be formed from a conventional PDC with a polycrystalline diamond table that comprises bonded diamond grains with cobalt or another metal-solvent catalyst occupying the interstitial regions between the bonded diamond grains. The metal-solvent catalyst may be substantially removed from the polycrystalline diamond table by leaching using an acid, such as aqua-regia, a solution of 90% nitric acid/10% de-ionized water, or another suitable process to remove at least a portion of the metal-solvent catalyst from the interstitial regions of the polycrystalline diamond table. After removal of the metal-solvent catalyst from the PDC  13 , a silicon-containing material  16  may be positioned adjacent to the leached polycrystalline diamond table  19  on a side thereof opposite the substrate  12 . The leached polycrystalline diamond table  19  and the silicon-containing material  16  are subjected to an HPHT process to infiltrate the leached polycrystalline diamond table  19  with silicon from the silicon-containing material  16  to form a PDC having a polycrystalline diamond table with the same or similar construction as the polycrystalline diamond table  15  shown in  FIGS. 2A and 2B . 
       FIGS. 7 and 8  show another embodiment of a method according to the present invention for forming a PDC. As shown in  FIG. 7 , an assembly  24  includes a mass of un-sintered diamond particles  28  positioned adjacent to the substrate  12 . The mass of un-sintered diamond particles  28  may be a green body of diamond particles  28  in the form of a tape-casted tape. In one embodiment of the present invention, the diamond particles  28  may exhibit an average particle size of about 20 μm or less. In another embodiment of the present invention, the diamond particles  28  may exhibit an average particle size of about 5 μm to about 50 μm. The mass of un-sintered diamond particles  28  may exhibit a thickness, for example, of about 0.150 inches to about 0.200 inches. The assembly  24  further includes a metal-solvent-catalyst-containing material  26  positioned adjacent to the mass of diamond particles  28 , and a silicon-containing material  16  positioned adjacent to the metal-solvent-catalyst-containing material  26 . The metal-solvent-catalyst-containing material  26  may include or may be formed from a material, such as cobalt, nickel, iron, or alloys thereof. The metal-solvent-catalyst-containing material  26  may also be a green body of metal-solvent-catalyst particles in the form of a tape-casted tape, a thin disc of metal-solvent-catalyst material, or any other suitable metal-solvent-catalyst material or structure, without limitation. 
     The assembly  24  may be subjected to an HPHT sintering process using HPHT sintering conditions similar to those previously discussed to form a PDC  42  shown in  FIG. 8 . During HPHT sintering, the metal-solvent catalyst of the metal-solvent-catalyst-containing material  26  melts and infiltrates the diamond particles  28  to effect intergrowth between the diamond particles  28 . Molten silicon from the silicon-containing material  16  also infiltrates the diamond particles  28  and the infiltration by the molten silicon follows the infiltration of the metal-solvent catalyst. Thus, the metal-solvent catalyst from the metal-solvent-catalyst-containing material  26  promotes bonding of the diamond particles  28  to form polycrystalline diamond and the silicon infiltrates the polycrystalline diamond so-formed. The silicon reacts with the diamond grains of the polycrystalline diamond to form silicon carbide within some of the interstitial regions between the bonded diamond grains. The amount of the silicon-containing material  16  metal-solvent-catalyst-containing material  26  may be selected so that the silicon of the silicon-containing material  16  and the metal-solvent catalyst from the metal-solvent-catalyst-containing material  26 , respectively, only fill a portion of the interstitial regions of the polycrystalline-diamond formed during the HPHT process. 
     As shown in  FIG. 8 , the PDC  42  formed by HPHT sintering the assembly  24  includes a multi-region polycrystalline diamond table  35  similar in configuration to the polycrystalline diamond table  15  shown in  FIGS. 2A and 2B . The polycrystalline diamond table  35  includes: a first region  36 , a second-intermediate region  38 , and a third region  40 . The first region  36  includes substantially only silicon carbide within the interstitial regions between the bonded diamond grains. In one embodiment of the present invention, the second-intermediate region  38  may include silicon carbide within a portion of the interstitial regions between the bonded diamond grains, along with metal-solvent catalyst from the metal-solvent-catalyst-containing material  26  and/or the substrate  12  within other portions of the interstitial regions of the second-intermediate region  38 . In another embodiment of the present invention, substantially all of or only a portion of the interstitial regions of the second-intermediate region  38  may include an alloy of silicon and metal-solvent catalyst, such as a silicon-cobalt solid solution alloy or an intermetallic compound of cobalt and silicon. In yet another embodiment of the present invention, each interstitial region of the second-intermediate region  38  may include one or more of the following materials: silicon carbide, metal-solvent catalyst, silicon, and an alloy of silicon and metal-solvent catalyst. The third region  40 , adjacent to the substrate  12 , includes substantially only metal-solvent catalyst from the substrate  12  or another source within the interstitial regions thereof for forming a strong, metallurgical bond between the polycrystalline diamond table  35  and the substrate  12 . 
       FIGS. 9-11  show yet another embodiment of a method according to the present invention for forming a PDC. As shown in  FIG. 9 , an assembly  44  is formed by positioning a silicon-containing material  16  between a substrate  12  and a pre-sintered-polycrystalline diamond table  46 . The polycrystalline diamond table  46  may exhibit a thickness of, for example, about 0.090 inches and an average grain size of about 20 μm or less. The polycrystalline diamond table  46  comprises bonded diamond grains sintered using a metal-solvent catalyst, such as cobalt, nickel, iron, or alloys thereof. Accordingly, the polycrystalline diamond table  46  includes bonded diamond grains with the metal-solvent catalyst occupying interstitial regions between the bonded diamond grains. In one embodiment of the present invention, the polycrystalline diamond table  46  may not be formed by sintering diamond particles in the presence of tungsten carbide so that the interstitial regions of the polycrystalline diamond table  46  contain no tungsten and/or tungsten carbide or insignificant amounts of tungsten and/or tungsten carbide. In other embodiments of the present invention, a portion or substantially the entire polycrystalline diamond table  46  may be formed to include tungsten and/or tungsten carbide distributed therethrough, as previously described with respect to the polycrystalline diamond body  14  shown in  FIGS. 1A and 1B . For example, a first region of the polycrystalline diamond table  46  that is substantially free of tungsten and/or tungsten carbide may be positioned adjacent to the silicon-containing material  16 , while a second region of the polycrystalline diamond table  46  that includes tungsten and/or tungsten carbide may be positioned remote from the silicon-containing material  16 . The assembly  44  further includes a porous mass  48  positioned adjacent to the polycrystalline diamond table  46  on a side of the polycrystalline diamond table  46  opposite the silicon-containing material  16 . The porous mass  48  may be un-sintered diamond particles, un-sintered aluminum oxide particles, un-sintered aluminum particles, un-sintered silicon carbide particles, or another suitable porous mass. The porous mass  48  may also be a green body of diamond particles in the form of a tape-casted tape, or any other form, without limitation. 
     The assembly  44  may be subjected to an HPHT sintering process using sintering conditions similar to the sintering conditions employed on the assembly  10  to bond the various components of the assembly  44  together and to form a polycrystalline diamond structure  50  shown in  FIG. 10 . During sintering, silicon from the silicon-containing material  16  melts and displaces all or a portion of the metal-solvent catalyst of the polycrystalline diamond table  46  into the porous mass  48 . Depending on the sintering temperature, the metal-solvent catalyst of the polycrystalline diamond table  46  may also be partially or completed molten at the same time as the silicon from the silicon-containing material  16 . In one embodiment of the present invention, the amount of silicon-containing material  16  is selected so that substantially all of the metal-solvent catalyst of the polycrystalline diamond table  46  is displaced into the porous mass  48 . In another embodiment of the present invention, the amount of the silicon-containing material  16  may be selected so that the silicon from the silicon-containing material  16  displaces only a portion of the metal-solvent catalyst of the polycrystalline diamond table  46 . The silicon reacts with the diamond grains of the polycrystalline diamond table  46  or another carbon source to form silicon carbide within interstitial regions between the bonded diamond grains of the polycrystalline diamond table  46 . Additionally, metal-solvent catalyst from the substrate  12  or another source also melts and infiltrates into a region of the polycrystalline diamond table  46  adjacent the substrate  12 . 
     As shown in  FIG. 10 , the polycrystalline diamond structure  50  formed by HPHT sintering of the assembly  44  comprises a multi-region polycrystalline diamond table  55  that may include: a first region  52 , a second region  54 , a third region  56 , a fourth region  58 , and a fifth region  60 . The first region  52  includes the particles from the porous mass  48  with the interstitial regions thereof occupied by substantially only the metal-solvent catalyst displaced from the polycrystalline diamond table  46 . The second region  54  includes the particles from the porous mass  48  with the interstitial regions thereof occupied by an alloy of silicon and metal-solvent catalyst, such as a silicon-cobalt solid solution alloy or an intermetallic compound of cobalt and silicon. Depending upon the amount of the silicon-containing material  16  employed, the second region  54  may also extend into the HPHT processed polycrystalline diamond table  46 . The third region  56 , fourth region  58 , and fifth region  60  may be formed from the HPHT processed polycrystalline diamond table  46 , which exhibits a reduced thickness due to the HPHT processing. The third region  56  includes polycrystalline diamond with substantially only silicon carbide within the interstitial regions between the bonded diamond grains. In one embodiment of the present invention, the fourth region  58  includes polycrystalline diamond with the interstitial regions thereof occupied by an alloy of silicon and metal-solvent catalyst, such as a silicon-cobalt solid solution alloy or an intermetallic compound of cobalt and silicon. In another embodiment of the present invention, the fourth region  58  may include polycrystalline diamond with silicon carbide formed within a portion of the interstitial regions between the bonded diamond grains of the fourth region  58  and metal-solvent catalyst (e.g., cobalt) occupying another portion of the interstitial regions between the bonded diamond grains of the fourth region  58 . In yet another embodiment of the present invention, each interstitial region of the fourth region  58  may include one or more of the following materials: silicon carbide, metal-solvent catalyst, silicon, and an alloy of silicon and metal-solvent catalyst. The fifth region  60 , adjacent to the substrate  12 , includes substantially only metal-solvent catalyst from the substrate  12  within the interstitial regions between bonded diamond grains for forming a strong, metallurgical bond between the multi-region polycrystalline diamond table  55  and the substrate  12 . 
     As shown in  FIG. 11 , after forming the polycrystalline diamond structure  50 , a PDC  63  including a multi-region structure  65  similar in configuration to the polycrystalline diamond table  15  shown in  FIGS. 2A and 2B  may be formed by removing the first region  52  and the second region  54  of the multi-region structure  65  using a lapping process, a grinding process, wire EDM, or another suitable material-removal process. 
       FIGS. 12 and 13  show yet another embodiment of a method according to the present invention for forming a PDC. As shown in  FIG. 12 , an assembly  59  includes a mass of un-sintered diamond particles  62  with a silicon-containing material  16  and a metal-solvent catalyst-containing material  26  positioned between the mass of un-sintered diamond particles  62  and a substrate  12 . The metal-solvent-catalyst-containing material  26  is positioned adjacent to the mass of un-sintered diamond particles  62  and the silicon-containing material  16  is positioned adjacent to the substrate  12 . The assembly  59  may be subjected to an HPHT sintering process using sintering conditions similar to the sintering conditions employed on the assembly  10  to form a polycrystalline diamond structure  61  shown in  FIG. 13 . During HPHT sintering, the silicon-containing material  16  and the metal-solvent catalyst-containing material  26  are melted, and metal-solvent catalyst from the metal-solvent-catalyst-containing material  26  infiltrates the mass of un-sintered diamond particles  62  to promote bonding between the diamond particles, thus, forming polycrystalline diamond that comprises bonded diamond grains with interstitial regions between the bonded diamond grains. The silicon from the silicon-containing material  16  follows the infiltration of the mass  62  by the metal-solvent-catalyst-containing material  26  and infiltrates the polycrystalline diamond so-formed. The silicon reacts with the diamond grains to form silicon carbide within some of the interstitial regions. 
     As shown in  FIG. 13 , the polycrystalline diamond structure  61  formed by HPHT sintering of the assembly  59  comprises a multi-region polycrystalline diamond table  69  that may include: a first region  64 , a second region  65 , a third region  66 , a fourth region  67 , and a fifth region  68 . The first region  64  includes polycrystalline diamond with the interstitial regions thereof occupied by substantially only the metal-solvent catalyst from the metal-solvent-catalyst-containing material  26 . In one embodiment of the present invention, the second region  65  includes polycrystalline diamond with the interstitial regions thereof occupied by an alloy of silicon and metal-solvent catalyst, such as a silicon-cobalt solid solution alloy or an intermetallic compound of cobalt and silicon. In another embodiment of the present invention, the second region  65  may include polycrystalline diamond with silicon carbide formed within a portion of the interstitial regions between the bonded diamond grains of the second region  65  and metal-solvent catalyst (e.g., cobalt) occupying another portion of the interstitial regions between the bonded diamond grains of the second region  65 . In yet another embodiment of the present invention, each interstitial region of the second region  65  may include one or more of the following materials: silicon carbide, metal-solvent catalyst, silicon, and an alloy of silicon and metal-solvent catalyst. The third region  66  includes polycrystalline diamond with substantially only silicon carbide within the interstitial regions thereof. The fourth region  67  may include a composition and microstructure that is the same or similar to the second region  65 . The fifth region  68  adjacent to the substrate  12  includes substantially only metal-solvent catalyst from the substrate  12  or another source within the interstitial regions thereof for forming a strong, metallurgical bond between the multi-region polycrystalline diamond table  69  and the substrate  12 . After forming the multi-region polycrystalline diamond table  69 , a PDC including a polycrystalline diamond table similar in configuration to the polycrystalline diamond table  15  shown in  FIGS. 2A and 2B  may be formed by removing the first region  64  and the second region  65  using a lapping process, a grinding process, wire EDM, or another suitable material-removal process. 
       FIGS. 14 and 15  show an isometric view and a top elevation view, respectively, of a rotary drill bit  70  according to one embodiment of the present invention. The rotary drill bit  70  includes at least one PDC configured according to any of the previously described PDC embodiments. The rotary drill bit  70  comprises a bit body  72  that includes radially and longitudinally extending blades  74  with leading faces  76 , and a threaded pin connection  78  for connecting the bit body  72  to a drilling string. The bit body  72  defines a leading end structure for drilling into a subterranean formation by rotation about a longitudinal axis  80  and application of weight-on-bit. At least one PDC, fabricated according to any of the previously described PDC embodiments, may be affixed to rotary drill bit  70 . As best shown in  FIG. 15 , a plurality of PDCs  86  are secured to the blades  74 . For example, each PDC  86  may include a polycrystalline diamond table  88  bonded to a substrate  90 . More generally, the PDCs  86  may comprise any PDC disclosed herein, without limitation. In addition, if desired, in some embodiments of the present invention, a number of the PDCs  86  may be conventional in construction. Also, circumferentially adjacent blades  74  define so-called junk slots  82  therebetween, as known in the art. Additionally, the rotary drill bit  70  includes a plurality of nozzle cavities  84  for communicating drilling fluid from the interior of the rotary drill bit  70  to the PDCs  86 . 
       FIGS. 14 and 15  merely depict one embodiment of a rotary drill bit that employs at least one cutting element that comprises a PDC fabricated and structured in accordance with the disclosed embodiments, without limitation. The rotary drill bit  70  is used to represent any number of earth-boring tools or drilling tools, including, for example, core bits, roller-cone bits, fixed-cutter bits, eccentric bits, bicenter bits, reamers, reamer wings, or any other downhole tool including PDCs, without limitation. 
     The PDCs disclosed herein may also be utilized in applications other than cutting technology. The disclosed PDC embodiments may be used in wire dies, bearings, artificial joints, inserts, cutting elements, and heat sinks Thus, any of the PDCs disclosed herein may be employed in an article of manufacture including at least one superabrasive element or compact. 
     Thus, the embodiments of PDCs disclosed herein may be used on any apparatus or structure in which at least one conventional PDC is typically used. For example, in one embodiment of the present invention, a rotor and a stator (i.e., a thrust bearing apparatus) may each include a PDC according to any of the embodiments disclosed herein and may be operably assembled to a downhole drilling assembly. U.S. Pat. Nos. 4,410,054; 4,560,014; 5,364,192; 5,368,398; and 5,480,233, the disclosure of each of which is incorporated herein, in its entirety, by this reference, disclose subterranean drilling systems within which bearing apparatuses utilizing PDCs disclosed herein may be incorporated. The embodiments of PDCs disclosed herein may also form all or part of heat sinks, wire dies, bearing elements, cutting elements, cutting inserts (e.g., on a roller cone type drill bit), machining inserts, or any other article of manufacture as known in the art. Other examples of articles of manufacture that may use any of the PDCs disclosed herein are disclosed in U.S. Pat. Nos. 4,811,801; 4,268,276; 4,468,138; 4,738,322; 4,913,247; 5,016,718; 5,092,687; 5,120,327; 5,135,061; 5,154,245; 5,460,233; 5,544,713; and 6,793,681, the disclosure of each of which is incorporated herein, in its entirety, by this reference. 
     The following working examples of the present invention set forth various formulations for forming PDCs. The following working examples provide further detail in connection with the specific embodiments described above. 
     COMPARATIVE WORKING EXAMPLE 1 
     A conventional PDC was formed from a mixture of diamond particles having an average grain size of about 18 μm. The mixture was placed adjacent to a cobalt-cemented tungsten carbide substrate. The mixture and substrate were placed in a niobium can and HPHT sintered at a temperature of about 1400° Celsius and a pressure of about 5 GPa to about 8 GPa for about 90 seconds to form the conventional PDC. The conventional PDC was acid-leached to a depth of about 70 μm to remove substantially all of the cobalt from a region of the polycrystalline diamond table. The thickness of the polycrystalline diamond table of the PDC was 0.090 inches and a 0.012 inch chamfer was machined in the polycrystalline diamond table. The thermal stability of the conventional PDC so-formed was evaluated by measuring the distance cut in a Sierra White granite workpiece prior to failure without using coolant in a vertical turret lathe test. The distance cut is considered representative of the thermal stability of the PDC. The conventional PDC was able to cut a distance of about only 2000 linear feet in the workpiece prior to failure. Evidence of failure of the conventional PDC is best shown in  FIG. 16  where the measured temperature of the conventional PDC during cutting increased dramatically at around about 2000 linear feet and in  FIG. 17  where the normal force required to continue cutting also increased dramatically at around about 2000 linear feet. 
     WORKING EXAMPLE 2 
     A PDC was formed by first fabricating a leached-polycrystalline diamond body. The leached-polycrystalline diamond body was formed by HPHT sintering diamond particles having an average grain size of about 18 μm in the presence of cobalt. The sintered-polycrystalline diamond body included cobalt within the interstitial regions between bonded diamond grains. The sintered-polycrystalline diamond body was leached using a solution of 90% nitric acid/10% de-ionized water for a time sufficient to remove substantially all of the cobalt from the interstitial regions to form the leached-polycrystalline diamond body. The leached-polycrystalline diamond body was placed adjacent to a cobalt-cemented tungsten carbide substrate. A green layer of silicon particles was placed adjacent to the leached-polycrystalline diamond body on a side thereof opposite the cobalt-cemented tungsten carbide substrate. The leached-polycrystalline diamond body, cobalt-cemented tungsten carbide substrate, and green layer of silicon particles were placed within a niobium can, and HPHT sintered at a temperature of about 1400° Celsius and a pressure of about 5 GPa to about 7 GPa for about 60 seconds to form a PDC that exhibited a similar multi-region diamond table as the polycrystalline diamond table  15  shown in  FIGS. 2A and 2B , with silicon carbide formed in a portion of the interstitial regions between the bonded diamond grains. The thickness of the polycrystalline diamond table was about 0.090 inches and a chamfer of about 0.01065 inch was machined in the polycrystalline diamond table. 
     The thermal stability of the PDC of example 2 was evaluated by measuring the distance cut in a Sierra White granite workpiece without using coolant in a vertical turret lathe test. The PDC of example 2 was able to cut a distance of over 14000 linear feet in a granite workpiece without failing and without using coolant. This is best shown in  FIGS. 16 and 17  where the measured temperature ( FIG. 16 ) of the PDC of example 2 during cutting of the workpiece and the normal force required to continue cutting the workpiece ( FIG. 17 ) does not increase dramatically as occurred with the conventional PDC of comparative example 1 during cutting. Therefore, thermal stability tests indicate that the PDC of example 2 exhibited a significantly improved thermal stability compared to the conventional PDC of comparative example 1. 
     The wear resistance of the PDCs of comparative example 1 and example 2 were evaluated by measuring the volume of the PDC removed versus the volume of a Sierra White granite workpiece removed in a vertical turret lathe with water used as a coolant. As shown in  FIG. 18 , the wearflat volume tests indicated that the PDC of example 2 exhibited a slightly decreased wear resistance compared to the wear resistance of the PDC of comparative example 1. However, the wear resistance of the PDC of example 2 is still more than sufficient to function as a PDC for subterranean drilling applications. Drop-weight tests also indicated that a PDC fabricated according to example 2 exhibits an impact resistance similar to a conventionally fabricated PDC, such as the comparative example 1. Therefore, the PDC of example 2 exhibited a significantly superior thermal stability compared to the conventional PDC of comparative example 1 without significantly compromising wear resistance and impact resistance. 
     Although the present invention has been disclosed and described by way of some embodiments, it is apparent to those skilled in the art that several modifications to the described embodiments, as well as other embodiments of the present invention are possible without departing from the spirit and scope of the present invention. Additionally, the words “including” and “having,” as used herein, including the claims, shall be open ended and have the same meaning as the word “comprising.”