Abstract:
An etch barrier to be used in a photolithograph process is disclosed. A silicon rich etch barrier is deposited on a substrate using a low energy deposition technique. A diamond like carbon layer is deposited on the silicon rich etch barrier. Photoresist is then placed on this etch barrier DLC combination. To form photolithographic features, successive steps of oxygen and flourine reactive ion etching is used.

Description:
BACKGROUND OF THE INVENTION  
         [0001]    1. Field of the Invention  
           [0002]    This invention relates to a method of manufacturing photolithographic features which have high aspect ratios. This method is applicable to manufacturing devices such as recording heads for disk drives and semiconductor integrated circuits.  
           [0003]    2. Description of the Background Art  
           [0004]    Devices which are made with photolithographic processes include articles such as recording heads for disk drives and integrated circuits for a variety of applications. In general there is a trend to make such devices smaller and smaller. The important dimensions of such devices can include for example the track widths of recording heads and conductor widths for integrated circuits.  
           [0005]    The conventional photolithographic processes of manufacturing these small features involve first forming a layer of photo resist on a substrate such as metal or silicon. Then a pattern is created in the resist layer by first exposing through a patterned mask with the proper light for that particular resist and then chemically dissolving away the exposed portions of the resist to expose the underlying substrate. The actual structure in the final device is then usually constructed by plating or otherwise building the features onto the substrate. After the feature has been built, the remaining resist layer is removed. This conventional approach is appropriate when the width of the desired features is relatively large compared to the depth or thickness of the resist; or correspondingly, when the width of the features is large relative to the height of the feature. The aspect ratio of a feature is defined as the height of a feature divided by the width. For example, a recording head for very high density applications would have a very narrow track width and the height of the write pole would be large compared to the track width.  
           [0006]    When manufacturing high aspect features conventional photolithographic processes have serious shortcomings. Among these shortcomings are lack of precise definition of the desired template in the resist and undercutting when the resist is chemically treated. Both of these shortcomings limit the ability of conventional methods to achieve high aspect ratio features.  
           [0007]    An improvement in the conventional processes of achieving high aspect ratio features has been the use of an image transfer process. In this process a thin adhesion layer, typically containing a tantalum rich material is placed on the substrate to provide improved adhesion for the resist layer. A thin top layer of a silicon rich or tantalum rich material is placed on top of the resist layer, and a pattern is created in this top layer. Then, instead of using photolithography with a wet chemical process to dissolve the underlying resist layer, an oxygen based reactive ion etch (RIE) is used to create the template in the resist layer. This method has the advantage of creating more sharply defined walls in the resist template (e.g. little undercutting). However, this approach has at least two noteworthy shortcomings. One, the adhesion layer material which is removed during the RIE process tends to deposit on the walls of the photoresist template. Furthermore, it is difficult to completely remove the remaining adhesion layer without damaging or undesirably altering the patterned substrate.  
           [0008]    There is a need for a process which has an effective adhesion layer between the substrate and resist which protects the substrate and is subsequently easy to remove.  
         SUMMARY OF THE INVENTION  
         [0009]    The present invention is a photolithographic process which includes a step of forming an effective etch barrier for an oxygen RIE process. The process results in improved protection of the substrate and more sharply defined goemetrical features. The steps of the process of the present invention include first placing a silicon rich thin layer on the substrate using a low energy deposition. A thin diamond like carbon (DLC) layer is then placed on the silicon rich layer. Relatively thick resist is then placed on the DLC. Finally the image transfer layers comprising a silicon rich or tantalum rich layer and an additional resist layer which is relatively thin are placed on the thicker resist. The DLC layer provides good adhesion with the resist. The silicon rich material on the substrate is the etch barrier which protects the substrate during the oxygen RIE. The silicon rich material is subsequently removed with a fluorine based RIE without damage to the substrate and with minimal redeposition on the walls of the features in the resist layer. These steps allow high aspect ratio photolithographic features to be constructed. 
       
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
       [0010]    [0010]FIG. 1 a  shows the sequence of layers before the process steps resulting in a resist template.  
         [0011]    [0011]FIG. 1 b  shows the first step of exposing a portion of the upper, then resist layer  106 .  
         [0012]    [0012]FIG. 1 c  shows the result of removing the exposed sections of the thin resist layer  106 .  
         [0013]    [0013]FIG. 1 d  shows the step of using a fluorine based RIE to transfer the pattern through the etch barrier  105 .  
         [0014]    [0014]FIG. 1 e  shows the step of using an oxygen based RIE to transfer the pattern through the resits layer  104  and the DLC layer.  
         [0015]    [0015]FIG. 1 f  shows using a flourine based RIE to remove the silicon rich layer  102 .  
         [0016]    [0016]FIG. 2 shows a coil structure of a magnetic recording write head made with the present invention. 
     
    
     DETAILED DESCRIPTION OF THE INVENTION  
       [0017]    [0017]FIG. 1 shows a series of process steps illustrating the present invention. In FIG. 1 a  there is shown a sequence of layers formed on the substrate  101 . Depending on the device, the substrate could be a substantially pure metal such as Cu or an alloy such as NiFe or CoNiFe. Additionally the substrate could be an amorphous crystalline material used in integrated circuit construction. A first etch barrier layer  102  of Si rich material is then placed on the substrate. This material could be relatively pure Si, but more commonly the material is silicon oxide, silicon nitride, or a combination thereof. This layer is typically in the thickness range of 10 to 40 Angstroms but is not limited to this range. The Si rich etch barrier layer  102  prevents oxygen RIE damage to the substrate. The next layer  103  is composed of diamond like carbon (DLC). This material is hydrogenated carbon which is relatively hard and durable. Typical thickness values for the DLC layer range from 20 to 60 Angstroms. The DLC layer  103  also functions as a very good adhesion layer with the first resist layer  104 . The resist layer material is conventional has no special requirements beyond conventional use. The thickness of the first resist layer  104  depends on the desired vertical dimension of the final feature. For example the pole of a magnet recording write head is typically from 1 to 4 um tall. If the desired pole height was 3 um, then the resist thickness would be about 3 um. The relatively thick resist layer  104  is placed on the DLC layer  103 . A relatively thin second etch barrier layer  105  is placed on the thick resist layer  104 . One of the purposes of this thin layer  105  is to provide an protecting etch barrier to the resist layer  104  during the subsequent oxygen RIE process. Accordingly the material for this layer  105  is typically silicon oxide, silicon nitride, or tantalum oxide. The thickness of this layer  105  is not especially critical and is typically a few hundred Angstroms. Finally a thin layer of conventional resist  106  is placed on the etch barrier layer  105 . The thickness of this layer is usually substantially less than one micron.  
         [0018]    All of the layers are deposited using well known processes including spin coat, chemical solution deposition, or low energy chemical vapor deposition. It is usually important to form well defined, distinct interfaces between the substrate  101  and the Si rich layer  102  and also between the Si rich layer  102  and the DLC layer  103 . Accordingly it is preferable to use lower energy deposition techniques such as chemical vapor deposition rather than a higher energy technique such as ion beam deposition. A technique such as routine ion beam deposition tends to damage the substrate surface and to make the interfaces less distinct. However a lower energy ion beam deposition, where substrate damage is minimal is also acceptable. The subsequent RIE steps leave a cleaner, better defined surface if a low energy process is used for deposition.  
         [0019]    After all the layers have been deposited subsequent processing must be carried out to create the desired pattern or template in the resist. FIG. 1 b  shows the first step of exposing a portion of the upper, thin resist layer  106  to light  107  through a mask to expose some areas of resist  108 . This light exposure step is typically done with an optical mask (not shown) which has the desired pattern or image. In FIG. 1 c  the exposed sections  108  of the thin resist  106  have been removed by developing the resist to leave a pattern  109 . FIG. 1 d  shows the next step of using a fluorine based RIE  110  to transfer the pattern through the etch barrier  105 . The pattern  111  is then transfered to the top of the thick resist layer  104 . Fluorine based RIE is effective in removing Si materials whereas oxygen based RIE is effective in removing organic material.  
         [0020]    The next step, illustrated in FIG. 1 e , is to use an oxygen based RIE  112  to transfer the pattern through the resist layer  104  and the DLC layer  103  in the patterned area  113 . This RIE step leaves walls  114  which are much more straight and well defined than by using the conventional chemical processes. The junction between the walls and the bottom layer  115  is also more sharply defined. This enables the construction of a more narrow feature and therefore a feature with a higher aspect ratio. The final step, illustrated in FIG. 1 f , is to use a Fluorine based RIE  116  to remove the Si material under the pattern  117  in the silicon rich layer  102 . The well defined trenches which form the desired pattern or template are now ready to be filled with the desired material using any of the conventional processes.  
         [0021]    [0021]FIG. 2 shows an example of a structure made with the invented process. The structure in FIG. 2 is a coil winding for a write head used in magnetic recording. In this case the coil height was about 3 um and was approximately determined by the thickness of the thicker resist  104 . The coil width was approximately 0.5 um resulting in an aspect ratio of about 6. This structure demonstrates that the well defined wall geometry and the sharp intersection of the wall and the substrate result in well defined final geometry of the constructed device.