Abstract:
Methods of forming an integrated circuit device can include forming an interlevel dielectric film on an integrated circuit substrate including a conductive portion thereof. The interlevel dielectric film includes a contact hole therein exposing a portion of the conductive portion of the integrated circuit substrate, and the dielectric film includes a trench therein communicating with the contact hole wherein the trench is in a surface of the interlevel dielectric film opposite the integrated circuit substrate. A first metal layer is formed in the contact hole preferentially with respect to formation of the first metal layer on a surface of the interlevel dielectric film opposite the integrated circuit substrate. After preferentially forming the first metal layer in the contact hole, a second metal layer is formed on the surface of the interlevel dielectric film opposite the integrated circuit substrate.

Description:
BACKGROUND OF THE INVENTION 
   This application claims the priority of Korean Patent, Application No. 2002-13264, filed Mar. 12, 2002, which is incorporated herein in its entirety by reference. 
   FIELD OF THE INVENTION 
   The present invention relates to methods of forming integrated circuits, and more particularly to methods for manufacturing semiconductor integrated circuits having a multilayer metal interconnection structure and related structures. 
   DESCRIPTION OF THE RELATED ART 
   As line widths of circuits decrease, there may be technical limitations in adopting a conventional deposition process of forming interconnections when semiconductor devices using interconnection materials such as aluminum, are manufactured. Accordingly, there may be a higher demand for techniques of filling a contact hole, which is a connection part of a lower conductive layer and an upper aluminum interconnection, or a via hole, which is a connection part of a lower aluminum interconnection and an upper aluminum interconnection, with an interconnection material such that electrical connections therebetween are possible. 
   When the contact hole or via hole (hereinafter, is short for “contact hole”) is filled with aluminum, in order to obtain higher electrical characteristics and more perfect filling characteristics, various processing techniques have been developed. When manufacturing memory devices to be used in the next generation, in a deposition process of forming metal interconnections having circuit line widths of less than 0.25 μm, aspect ratios of the contact holes may be high, and, thus, it may be inappropriate to depend only on physical vapor deposition (PVD) such as sputtering. To address this problem, processes of forming aluminum interconnections using chemical vapor deposition (CVD) having higher step coverage than in PVD have been developed. In particular, a preferential metal deposition (PMD) process of selectively forming an aluminum layer only in the contact hole using CVD and depositing the aluminum layer by PVD outside of the contact hole, has been studied. In the PMD process, to selectively form an aluminum thin film only in the contact hole, a metal deposition prevention layer is formed on a top surface of an interlevel dielectric (ILD) film pattern for defining the contact hole, and only the inside of the contact hole is exposed, and then the aluminum thin film is formed in the exposed contact hole by CVD. If the aluminum thin film is formed in the contact hole in this way, there is little consumption of an aluminum precursor outside of the contact hole, and thus the sufficient amount of the aluminum precursor is supplied to the contact hole, and higher step coverage can be obtained than step coverage which can be obtained when aluminum is blanket deposited. Thus, the above-mentioned PMD process can be advantageously adopted in a process of filling a contact hole, which is deep and has a small size, with aluminum. 
   Meanwhile, as semiconductor devices become more highly integrated and the sizes of patterns become finer, a dual damascene process can be adopted to form aluminum interconnections. In order to form aluminum interconnections by adopting the dual damascene process, an ILD film is first patterned, and contact holes, which communicate with one another, and line-shaped trenches are formed, thereby forming a dual damascene structure. As design rules decrease, critical dimensions (CD) of trenches for presenting the dual damascene structure decrease, and aspect ratios of the trenches increase. In order to form metal interconnections using the PMD process in the dual damascene structure, the trenches can be filled with interconnection materials by depositing metal materials in the trenches using a PVD process and reflowing the metal materials. However, in the case of trenches having high aspect ratios, as described above, it may be difficult to fill the trenches using PVD and reflowing metal materials. Thus, it may be desirable to develop a PMD process, which can be adopted when forming metal interconnections of a semiconductor device having a dual damascene structure, which may be required for a highly-integrated semiconductor devices using relatively small design rules. 
   SUMMARY OF THE INVENTION 
   According to embodiments of the present invention, methods of forming an integrated circuit device can include forming an interlevel dielectric film on an integrated circuit substrate including a conductive portion thereof. More particularly, the interlevel dielectric film can include a contact hole therein exposing a portion of the conductive portion of the integrated circuit substrate and the interlevel dielectric film can also include a trench therein communicating with the contact hole wherein the trench is in a surface of the interlevel dielectric film opposite the integrated circuit substrate. A first metal layer can be formed in the contact hole preferentially with respect to formation of the first metal layer on a surface of the interlevel dielectric film opposite the integrated circuit substrate. After preferentially forming the first metal layer in the contact hole, a second metal layer is formed on the surface of the interlevel dielectric film opposite the integrated circuit substrate. 
   A metal inhibiting layer can be formed on the surface of the interlevel dielectric film and on sidewalls of the trench preferentially with respect to formation of the metal inhibiting layer in the contact hole before preferentially forming the first metal layer. The metal inhibiting layer may comprise a metal oxide such as an oxide of Al, Zr, Ti, Ta, Sr, Mg, Ba, Ca, Ce, and/or Y. Alternatively or in addition to, the metal inhibiting layer may comprise metal nitride and/or silicon carbide. 
   In addition, the metal inhibiting layer may be treated after forming the first metal layer and before forming the second metal layer to facilitate forming the second metal layer thereon. More particularly, treating the metal inhibiting layer may include forming a wetting layer on the metal inhibiting layer opposite the interlevel dielectric film, and the wetting layer may be selected from at least one of Ti, TiN, Ta, and/or TaN. A barrier metal layer can also be formed on sidewalls of the contact hose and the trench before forming the metal inhibiting layer, and the barrier metal layer can include at least one of TiN, TaN, TiAlN, TiSiN, TaAlN, TaSiN, and/or WN. 
   According to additional embodiments of the present invention, methods of forming integrated circuit devices can include forming an interlevel dielectric film on an integrated circuit substrate including a conductive portion thereof. Moreover, the interlevel dielectric film can include a contact hole therein exposing a portion of the conductive portion of the integrated circuit substrate. A metal inhibiting layer can be formed on a surface of the interlevel dielectric film opposite the integrated circuit substrate preferentially with respect to formation of the metal inhibiting layer in the contact hole, and a first metal layer can be formed in the contact hole preferentially with respect to formation of the first metal layer on the metal inhibiting layer. After preferentially forming the first metal layer in the contact hole, a second metal layer can be formed on the interlevel dielectric film opposite the integrated circuit substrate. 
   The dielectric film can include a trench therein communicating with the contact hole wherein the trench is in a surface of the interlevel dielectric film opposite the integrated circuit substrate. Moreover, the metal inhibiting layer can be formed on sidewalls of the trench, and the second metal layer can be formed in the trench. The metal inhibiting layer can include a metal oxide such as an oxide of Al, Zr, Ti, Ta, Sr, Mg, Ba, Ca, Ce, and/or Y. Alternatively or in addition, the metal inhibiting layer can include a metal nitride layer and/or a silicon carbide layer. In addition, the metal inhibiting layer can be treated after forming the first metal layer and before forming the second metal layer to facilitate forming the second metal layer thereon. More particularly, treating the metal inhibiting layer can include forming a wetting layer on the metal inhibiting layer opposite the interlevel dielectric film, and the wetting layer can be selected from at least one of Ti, TiN, Ta, and/or TaN. 
   A barrier metal layer can also be formed on sidewalls of the contact hose and the trench before forming the metal inhibiting layer, and the barrier metal layer can be selected from at least one of TiN, TaN, TiAlN, TiSiN, TaAlN, TaSiN, and/or WN. A third metal layer can also be formed on the second metal layer after forming the second metal layer, and the third metal layer can be reflowed. In addition, selectively forming the first metal layer can include forming the first metal layer using chemical vapor deposition, and forming the second metal layer can include forming the second metal layer using chemical vapor deposition. 

   
     BRIEF DESCRIPTION OF THE DRAWINGS 
     The above objective and advantages of the present invention will become more apparent by describing in detail a preferred embodiment thereof with reference to the attached drawings in which: 
       FIGS. 1A through 1H  are cross-sectional views illustrating methods for forming metal interconnections of semiconductor devices according to first embodiments of the present invention; 
       FIGS. 2A and 2B  are cross-sectional views illustrating methods of forming metal interconnections of a semiconductor device according to second embodiments of the present invention; 
       FIG. 3  is a cross-sectional view illustrating methods for forming metal interconnections of a semiconductor device according to third embodiments of the present invention; and 
       FIGS. 4A and 4B  are cross-sectional views illustrating methods for forming metal interconnections of a semiconductor device according to fourth embodiments of the present invention. 
   

   DETAILED DESCRIPTION OF THE INVENTION 
   The present invention will be descried more fully hereinafter with reference to the accompanying drawings in which preferred embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be through and complete, and will fully convey the scope of the invention to those skilled in the art. In the drawings, the forms of elements are exaggerated for clarity. Like reference numerals refer to like elements throughout the drawings. It will be understood that when a layer is referred to as being on another layer or “on” a semiconductor substrate, it can be directly on the other layer or on the semiconductor substrate, or intervening layers may also be present. 
     FIGS. 1A through 1H  are cross-sectional views illustrating methods for forming metal interconnections of a semiconductor device according to first embodiments of the present invention. 
   Referring to  FIG. 1A , an interlevel dielectric (ILD) film  20  is formed on a semiconductor substrate  10  on which a conductive region  12  is exposed. The ILD film  20  is patterned to define a contact hole  22  by which the conductive region  12  is exposed, and a line-shaped trench  24  which communicates with the upper portion of the contact hole  22 . The trench  24  is provided to form metal interconnections of a semiconductor device having a dual damascene structure, which may be required for a highly-integrated semiconductor device with a relatively small design rule and having a relatively high aspect ratio of more than 1. 
   The conductive region  12  may include source and drain regions, or an N+ or P+ conductive layer comprising a transistor disposed on the semiconductor substrate  10 . Alternatively, the conductive region  12  may include a metal interconnection on an insulating layer formed on the semiconductor substrate  10  that is connected to the source and drain regions of the transistor. In this case, the contact hole  22  constitutes a via hole. The trench  24  can be a region in which a line type interconnection is to be formed. For example, the ILD film  20  may be formed of a borophosphosilicate glass (BPSG) layer and/or an undoped silicon oxide layer. 
   Referring to  FIG. 1B , a resistive metal layer  32  and a barrier metal layer  34  are sequentially formed on the entire surface of a resulting structure including the patterned ILD film  20 . The resistive metal layer  32  can be formed of Ti or Ta, preferably, Ti. Also, the barrier metal layer  34  can be formed of TiN, TaN, TiAlN, TiSiN, TaAlN, TaSiN and/or WN, preferably, TiN. 
   Subsequently, the barrier metal layer  34  can be heat-treated. In the case of source and drain regions including an impurity layer, a metal silicide layer can be formed by the reaction of metal atoms in the resistive metal layer  32  with silicon atoms in the impurity layer by heat treatment, and simultaneously an oxygen stuffing effect in which a grain boundary region of the barrier metal layer  34  is filled with oxygen atoms, can be obtained. Likewise, if the barrier metal layer  34  is heat-treated, contact resistance can be improved by the metal silicide layer formed between the conductive region  12  and the barrier metal layer  34 , and a phenomenon in which silicon atoms in the conductive region  12  and aluminum atoms in the metal layer formed in a subsequent process are dispersed through the barrier metal layer  34  can be suppressed. When the conductive region  12  constitutes a metal interconnection, that is, when the contact hole  22  is a via hole by which the metal interconnection is exposed, a step of forming the barrier metal layer  34  and a heat-treatment step may be omitted. 
   Referring to  FIG. 1C , a metal deposition prevention layer  40  is formed on the top surface of the ILD film pattern  20  and a bottom surface and sidewalls of the trench  24  such that the inside wall of the contact hole  22  defined by the barrier metal layer  34  is exposed. For example, the metal deposition prevention layer  40  may be formed of an insulating layer such as an aluminum oxide layer, an aluminum nitride layer, a tantalum oxide layer, a titanium oxide layer, and/or a silicon carbide (SiC) layer. 
   As an example of forming the metal deposition prevention layer  40 , a metal thin film having the thickness between about 20 and 300 Å can be formed on the top surface of the ILD film pattern  20  and the bottom surface and sidewalls of the trench  24  by PVD such as sputtering, and the metal thin film can be oxidized. The metal thin film can be formed of a material having a larger oxidizing property than Si. For example, the metal thin film may be formed of Al, Zr, Ti, Ta, Sr, Mg, Ba, Ca, Ce, and/or Y. Here, it is preferable that a direct current (DC) magnetron sputter in which a collimator is not mounted is used when the metal thin film is formed. A DC magnetron sputtering process of forming the metal thin film may be performed at a relatively low temperature between about 10 and 30° C. under a pressure between about 3 and 10 mTorr, preferably, between about 5 and 10 m Torr. If the metal thin film is formed under the above conditions using a DC magnetron sputter in which the collimator is not mounted, a straight advancing property of the sputtered metal atoms can be reduced so that the metal thin film is not significantly formed in the contact hole  22 . Thus, the metal thin film can be formed on the top surface of the ILD film  20  and the bottom surface and sidewalls of the trench  24 , and the barrier metal layer  34  can be exposed in the contact hole  22 . 
   There are various methods for oxidizing the metal thin film to form the metal deposition prevention layer  40 . For example, a method for oxidizing the metal thin film to form the metal deposition prevention layer  40  can include providing an O 2  gas atmosphere in a closed space maintained at a pressure lower than atmospheric pressure. Alternatively, a method for oxidizing the metal thin film at a mixed gas atmosphere of an oxygen-containing gas and an inert gas in a closed space maintained at a pressure lower than atmospheric pressure may be used to form the metal deposition prevention layer  40 . The oxygen-containing gas may comprise O 2 , O 3 , and/or N 2 O. Alternatively, the metal thin film may be exposed in air or exposed to oxygen plasma. 
   As another example of forming the metal deposition prevention layer  40 , the metal thin film can be nitrided after a metal thin film is formed as discussed above. For example, when the metal thin film is an Al thin film, the Al thin film can be nitrided by exposing a resulting structure including the Al thin film, or by rapidly heat-treating the resulting structure in an ammonia gas atmosphere. 
   Referring to  FIG. 1D , a first metal layer  42  can be formed only on the barrier metal layer  34  in the contact hole  22  exposed through the metal deposition prevention layer  40 , using selective chemical vapor deposition. For example, the first metal layer  42  can be formed of Al. A selective metal organic CVD (MOCVD) process may be adopted to form the first metal layer  42 . The selective MOCVD process of forming the first metal layer  42  of Al can be performed using a precursor formed of an organometallic compound such as dimethylaluminum hydride (DMAH), dimethylethylamine alane (DMEAA), and/or methylpyrrolidine alane (MPA), as an aluminum source, at a temperature between about 100 and 150° C., preferably, at a deposition temperature of about 120° C., and at a pressure between 0.5 and 5 torr, preferably, at a pressure of about 1 torr. In this case, a raw material conveyor such as a bubbler, a vapor flow controller, or a liquid delivery system, may be used to supply the precursor to a CVD chamber. An inert gas formed of Ar and/or Ne can be used for a carrier gas. 
   Referring to  FIG. 1E , a wetting layer  46  can be formed on the metal deposition prevention layer  40 . The wetting layer  46  can be a conductive layer formed such that a conductive metal layer is fully deposited on the metal deposition prevention layer  40 . The wetting layer  46  may be formed of a conductive layer, for example, Ti, TiN, Ta, TaN, or combinations thereof such as Ti/TiN. The wetting layer  46  may be formed by CVD and/or PVD. A deposition process of forming the wetting layer  46  can be performed in a separate reactive chamber other than a reactor used in forming the first metal layer  42 . 
   Referring to  FIG. 1F , a second metal layer  48  is formed to the thickness of about 300 Å or more than on the wetting layer  46  using CVD. A metal organic CVD (MOCVD) process may be adopted to form the second metal layer  48 . The MOCVD process of forming the second metal layer  48  of Al can be performed using a precursor including an organometallic compound such as DMAH, DMEAA, and/or MPA, as an aluminum source, at a temperature between about 100 and 200° C., preferably, at a deposition temperature of about 150° C., and at a pressure between about 0.5 and 5 torr, preferably, at a pressure of about 1 torr. In this case, an inert gas formed of Ar and/or Ne can be used for a carrier gas. 
   Referring to  FIG. 1G , a third metal layer  50  can be formed so as to fill the remaining space of the trench  24  whose part is filled with the second metal layer  48 . The third metal layer  50  can be formed by physical vapor deposition (PVD). Preferably, the third metal layer  50  can be formed of Al or Al alloy. 
   Methods such as DC sputtering, DC magnetron sputtering, AC sputtering, or AC magnetron sputtering, may be used to form the third metal layer  50  by PVD. Preferably, the third metal layer  50  can be formed by DC magnetron sputtering. A step of forming the third metal layer  50  may be performed using monolithic cluster tool type equipment without breaking a vacuum atmosphere after forming the second metal layer  48 . 
   Referring to  FIG. 1H , a structure including the third metal layer  50  can be heat-treated and reflowed. For example, the structure including the third metal layer  50  can be heat-treated in a vacuum atmosphere and/or in an inert gas atmosphere such as argon (Ar), for several seconds to several minutes, preferably, for about 30 to 180 seconds, at a temperature between about 350 and 600° C. The heat-treatment process for reflow can preferably be performed when surface oxidization of the third metal layer  50  is suppressed. Thus, the heat-treatment process can be performed at a pressure less than about 1 torr, preferably, at a high vacuum state of less than about 10 −6  torr. 
   When the structure including the third metal layer  50  is heat-treated under the above conditions, metal layers may move due to reflow such that the contact hole  22  can be completely filled with metal, and a metal layer  50   a  having a planarized top surface can be formed. 
   As described above, in a step where metal interconnections of a semiconductor device having a dual damascene structure are formed using a PMD process, the first metal layer can first be formed in the contact hole using selective CVD when the metal deposition prevention layer is formed on the top surface of patterned the ILD film and in the trench. Then, a deposition process comprising two steps, that is, a step of forming the second metal layer filling only part of the trench using CVD and a step of forming the third metal layer filling the reminder of the trench, can be used to fill the trench with the metal layer. Subsequently, before the second metal layer is formed, the wetting layer can be formed on the metal deposition prevention layer such that the trench is effectively filled with the metal layer. If metal interconnections of a semiconductor device having a dual damascene structure are formed as discussed above, metal interconnections formed in trenches having a high aspect ratio used in highly-integrated semiconductor devices with relatively small design rules, can be formed relatively easily. 
     FIGS. 2A and 2B  are cross-sectional views for explaining a method for forming metal interconnections of a semiconductor device according to second embodiments of the present invention. Unlike the first embodiments in which the wetting layer  46  is formed on the metal deposition prevention layer  40  before the second metal layer  48  is formed in the trench  24 , the surface of the metal deposition prevention layer  40  is treated with a SiH 4  gas so as to control the selective deposition characteristics of the second metal layer  148  formed in the trench  24 . More detailed descriptions thereof will be as follows. 
   Referring to  FIG. 2A , as described with reference to  FIGS. 1A through 1D , the patterned ILD film  20  includes contact hole  22  (by which the conductive region  12  is exposed), and trench  24 . The ILD film  20  is formed on the semiconductor substrate  10 , and resistive metal layer  32  and barrier metal layer  34  are sequentially formed on the entire surface of the structure including the ILD film  20 . The metal deposition prevention layer  40  is then formed in the trench  24 , and the first metal layer  42  is formed only in the contact hole  22 . After that, a SiH 4  gas is supplied to the surface of the metal deposition prevention layer  40  such that the SiH 4  gas is adsorbed to the surface of the metal deposition prevention layer  40 . As a result, a thin SiH 4  adsorption layer  143  is formed on the metal deposition prevention layer  40 . The SiH 4  gas may be supplied to the surface of the metal deposition prevention layer  40  for about 20 seconds at the flow rate of about 100 sccm. In this case, a process temperature can be about between about 100 and 200° C. Argon (Ar) supplied at the flow rate of about 100 sccm may be used for a carrier gas when the SiH 4  gas is supplied to the surface of the metal deposition prevention layer  40 . 
   Referring to  FIG. 2B , as described with reference to  FIG. 1F , a second metal layer  148  is formed on the SiH 4  adsorption layer  143  thereby filling part of the trench  24 . In this case, the SiH 4  adsorption layer  143  is formed on the metal deposition prevention layer  40 , and thus the selective deposition characteristics of the second metal layer  148  may be reduced and/or eliminated. Thus, the second metal layer  148  can be formed to an approximately uniform thickness on the entire surface of the SiH 4  adsorption layer  143 . Here, a step of forming the first metal layer  42 , a step of forming the SiH 4  adsorption layer  143 , and a step of forming the second metal layer  148  may be consecutively performed in an identical reaction chamber. After the second metal layer  148  is formed, metal interconnections of a semiconductor device having a dual damascene structure can be completed as described with reference to  FIGS. 1G and 1H . 
     FIG. 3  is a cross-sectional view illustrating methods for forming metal interconnections of a semiconductor device according to third embodiments of the present invention. 
   Referring to  FIG. 3 , as described with reference to  FIGS. 1A through 1D , the patterned ILD film  20 , including contact hole  22  (by which the conductive region  12  is exposed) and trench  24 , is formed on the semiconductor substrate  10 . Resistive metal layer  32  and barrier metal layer  34  are sequentially formed on the entire surface of the structure including the ILD film  20 . Then the metal deposition prevention layer  40  is formed in the trench  24 , and the first metal layer  42  is formed only in the contact hole  22 . After that, a second metal layer  248  is formed directly on the metal deposition prevention layer  40  using nonselective CVD, thereby filling part of the trench  24 . In this case, conditions of forming the second metal layer  248  formed of Al may be identical with those of the step of forming the second metal layer  48  described with reference to  FIG. 1F , except that a reactive gas such as H 2 , is used for a carrier gas so as to reduce and/or eliminate the selective deposition characteristics of the second metal layer  248 . The H 2  gas contributes to promote the decomposition of the precursor used for an Al source such that the Al layer is fully deposited on the metal deposition prevention layer  40 . According to some embodiments, only an H 2  gas or a mixed gas of H 2  and Ar may be used as a carrier gas to form the second metal layer  248 . 
   After the second metal layer  248  is formed, metal interconnections of a semiconductor device having a dual damascene structure can be completed as described with reference to  FIGS. 1G and 1H . 
     FIGS. 4A and 4B  are cross-sectional views illustrating methods for forming metal interconnections of a semiconductor device according to fourth embodiments of the present invention. According to fourth embodiments, a deposition temperature can be varied so as to control the selective deposition characteristics of the second metal layer  348 . 
   Referring to  FIG. 4A , as described with reference to  FIGS. 1A through 1D , the patterned ILD film  20  (including contact hole  22  by which the conductive region  12  is exposed and trench  24 ) is formed on the semiconductor substrate  10 . Resistive metal layer  32  and barrier metal layer  34  are sequentially formed on the entire surface of the ILD film  20 , and then the metal deposition prevention layer  40  is formed in the trench  24 , and the first metal layer  342  is formed only in the contact hole  22  using selective CVD. As described with reference to  FIG. 1D , to obtain the selective deposition characteristics when the first metal layer  342  is formed, the first metal layer  342  can be formed by MOCVD at a first deposition temperature T 1  between about 100 and 200° C. 
   Referring to  FIG. 4B , a second metal layer  348  is formed on the structure including the first metal layer  342  using nonselective MOCVD. In order to reduce and/or eliminate the selective deposition characteristics when forming the second metal layer  348 , a higher temperature between 200 and 350° C. is set to a second deposition temperature T 2 . A nonselective MOCVD process of forming the second metal layer  348  of Al can be performed using a precursor comprising of an organometallic compound such as DMAH (Dimethylaluminum Hydride), DMEAA (Dimethylethylaminealane), and/or MPA (mercaptopropionic acid), as an aluminum source, at the second deposition temperature T 2  under the pressure between about 0.5 and 5 torr. Preferably, a step of stabilizing temperature can be performed to increase the first deposition temperature T 1  to the second deposition temperature T 2  before the second metal layer  348  is formed after the first metal layer  342  is formed. After the second metal layer  348  is formed, metal interconnections of a semiconductor device having a dual damascene structure can be completed as described with reference to  FIGS. 1G and 1H . 
   In methods for forming metal interconnections of a semiconductor device according to embodiments of the present invention, the metal deposition prevention layer can be formed in the line-shaped trench used for exposed surfaces excluding the inside of the contact hole, that is, a dual damascene structure. Further, after the first metal layer is filled only in the contact hole using selective CVD, to effectively fill the trench having a high aspect ratio with the metal interconnection, the surface of the metal deposition prevention layer can be processed properly, and a deposition process including two steps (that is, a step of forming the second metal layer filling only part of the trench using CVD and a step of forming the third metal layer filling the reminder of the trench) can be performed. The selective deposition characteristics of the second metal layer can be controlled by varying conditions such as kinds of gas or deposition temperature used in the deposition process of forming the second metal layer. 
   By forming metal interconnections of a semiconductor device having a dual damascene structure as discussed above, metal interconnections of a semiconductor device having a dual damascene structure (which includes forming the trench having a high aspect ratio used for highly-integrated semiconductor devices with a small design rule) can be formed relatively easily. 
   According to embodiments of the present invention, methods can be provided that effectively form metal interconnections of a semiconductor device having a dual damascene structure, which may be required for a highly-integrated semiconductor device with a small design rule, adopting a preferential metal deposition (PMD) process. 
   According to embodiments of the present invention, methods are provided for manufacturing metal interconnections of a semiconductor device. An interlevel dielectric (ILD) film pattern (including a contact hole by which a conductive region is exposed and including a trench which communicates with the upper portion of the contact hole) is formed on a semiconductor substrate on which the conductive region is formed. A metal deposition prevention layer is formed on the top surface of the ILD film and the bottom surface and sidewalls of the trench such that the contact hole is exposed. A first metal layer is formed in the contact hole using chemical vapor deposition (CVD). A second metal layer is formed in the trench and on the upper portion of the ILD film using CVD. A third metal layer is formed on the second metal layer using physical vapor deposition (PVD). A resulting structure in which the third metal layer is formed is heat-treated and reflowed. The trench may constitute a line type interconnection region having an aspect ratio of more than 1. 
   Before forming the metal deposition prevention layer, the method may further include the steps of forming a resistive metal layer on the entire surface of the resulting structure in which the ILD film is formed and forming a barrier metal layer on the resistive metal layer. The resistive metal layer can be formed of Ti and/or Ta, and the barrier metal layer can be formed of TiN, TaN, TiAlN, TiSiN, TaAlN, TaSiN, and/or WN. 
   The metal deposition prevention layer can be formed of an aluminum oxide layer, an aluminum nitride layer, a tantalum oxide layer, a titanium oxide layer, and/or a silicon carbide (SiC) layer. To form the metal deposition prevention layer, a metal thin film can be formed on the top surface of the ILD film and the bottom surface and sidewalls of the trench. After that, the metal thin film can be oxidized. The metal thin film can be formed of Al, Zr, Ti, Ta, Sr, Mg, Ba, Ca, Ce, and/or Y. The metal thin film can be formed by direct current (DC) magnetron sputtering. 
   The step of oxidizing the metal thin film can be performed in an O 2  gas atmosphere. As another method, a mixed gas atmosphere of an oxygen-containing gas and an inert gas can be used to oxidize the metal thin film. The oxygen-containing gas can include O 2 , O 3 , and or N 2 O. As still another method of oxidizing the metal thin film, the metal thin film can be exposed in air or to oxygen plasma. 
   To form the metal deposition prevention layer, a metal thin film can be formed on the top surface of the ILD film and the bottom surface and sidewalls of the trench. Subsequently, the metal thin film can be nitrided. To nitride the metal thin film, the metal thin film can be exposed to nitrogen plasma or can be rapidly heat-treated at an ammonia gas atmosphere. 
   Preferably, the metal thin film can be formed of Al. In this case, the first metal layer can be formed by selective metal organic CVD (MOCVD) using a precursor selected from dimethylaluminum hydride (DMAH), dimethylethylamine alane (DMEAA), and/or methylpyrrolidine alane (MPA). Preferably, the second metal layer can be formed of Al. The second metal layer can be formed by nonselective MOCVD using a precursor selected from DMAH, DMEAA, and/or MPA. 
   Before forming the second metal layer and after forming the first metal layer, the method may further include forming a wetting layer on the metal deposition prevention layer. In this case, the wetting layer can be formed of a conductive layer such as Ti, TiN, Ta, TaN, or a combination thereof. The wetting layer can be formed by CVD and/or PVD techniques. Before forming the second metal layer and after forming the first metal layer, the method may further include adsorbing SiH 4  to the surface of the metal deposition prevention layer. In this case, the steps of forming the first metal layer and adsorbing SiH 4  can be consecutively performed in an identical chamber. 
   In order to nonselectively form the second metal layer on the metal deposition prevention layer, the step of forming the first metal layer can be performed by selective MOCVD using a precursor selected from DMAH, DMEAA, and/or MPA, and a carrier gas formed of an inert gas, and the step of forming the second metal layer can be performed by nonselective MOCVD using a precursor selected from DMAH, DMEAA, and/or MPA, and a carrier gas including a reactive gas. For example, a carrier gas formed of Ar or Ne can be used in the step of forming the first metal layer, and a carrier gas including H 2  can be used in the step of forming the second metal layer. In this case, the steps of forming the first metal layer and forming the second metal layer, respectively, can be performed at deposition temperatures between about 100 and 150° C. 
   In addition, to nonselectively form the second metal layer on the metal deposition prevention layer, the step of forming the first metal layer can include forming a first Al layer by selective MOCVD at a first deposition temperature between about 100 and 200° C. In addition, the step of forming the second metal layer can include forming a second Al layer by nonselective MOCVD at a second deposition temperature between about 200 and 350° C. The third metal layer can be formed of Al and/or an Al alloy formed by DC magnetron sputtering. The step of heat-treating the resulting structure in which the third metal layer is formed can be performed at a temperature between about 350 and 500° C. 
   According to additional embodiments of the present invention, methods of manufacturing metal interconnections of a semiconductor device are provided. An insulating metal deposition prevention layer can be formed on an exposed surface (excluding a via hole) of a semiconductor substrate. A first metal layer is formed in the via hole. The surface of the insulating metal deposition prevention layer is treated such that metal can be deposited on the insulating metal deposition layer. A second metal layer is formed on the insulating metal deposition prevention layer having the treated surface and on the first metal layer. The exposed surface includes a line-shaped trench which communicates with the via hole in an upper portion of the via hole. 
   In the step of treating the surface of the insulating metal deposition prevention layer, a conductive wetting layer can be formed on the surface of the insulating metal deposition prevention layer, or SiH 4  can be adsorbed to the surface of the insulating metal deposition prevention layer. 
   According to still additional embodiments of the present invention, methods for manufacturing metal interconnections of a semiconductor device can be provided. An interlevel dielectric (ILD) film which defines a hole region for a via contact and a trench for an interconnection line that communicate with each other, can be formed on a semiconductor substrate. A barrier metal layer can be formed in the inner wall of the hole region and the. inner wall of the trench. An insulating metal deposition prevention layer can be formed on the barrier metal layer in a region excluding the hole region. A first metal layer can be formed only in the hole region using selective chemical vapor deposition (CVD). A second metal layer can be formed on the insulating metal deposition prevention layer and the first metal layer using nonselective CVD. A third metal layer can be formed on the second metal layer using physical vapor deposition (PVD). A resulting structure in which the third metal layer is formed can be heat-treated and reflowed. 
   According to embodiments of the present invention, metal interconnections of a semiconductor device having a dual damascene structure, (which is constituted by forming the trench having a high aspect ratio as may be required for a highly-integrated semiconductor device with a small design rule), may be formed relatively easily. 
   While this invention has been particularly shown and described with reference to preferred embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.