Abstract:
A microchannel contactor and methods of contacting substances in microchannel apparatus are described. Some preferred embodiments are combined with microchannel heat exchange.

Description:
RELATED APPLICATIONS 
     In accordance with 35 U.S.C. sect. 119(e), this application claims priority to U.S. Provisional Application No. 60/363,859 filed Mar. 11, 2002. 
    
    
     This invention was made with Government support under Contract DE-AC0676RLO1830 awarded by the U.S. Department of Energy. The Government has certain rights in the invention. 
    
    
     FIELD OF THE INVENTION 
     The present invention relates to processes and devices that contact a gas phase component with a component in a liquid phase. 
     BACKGROUND OF THE INVENTION 
     Compact systems for capturing and/or separating fluids are desirable in a variety of applications. For example, hydrogen-powered vehicles could utilize fuel cells that recycle water. As another example, efficient and lightweight systems for recovery and reuse of water in spacecraft has long been recognized as a requirement for human space exploration. The present invention provides methods and apparatus for efficient fluid capture and separation. 
     SUMMARY OF THE INVENTION 
     The potential applications of sorption techniques, both absorption and adsorption, for targeted gas separations and purification are essentially unlimited provided sorption media with required specificity and capacity are available. For example, microchannel absorbers can be used in the recovery and recycle of CO 2  and the stripping of CO from RWGS and Sabatier reactor effluent gases. Two types of microchannel absorbers, microwick contactor absorbers and membrane contactor absorbers, are being developed. In absorption, the rate of mass transfer is usually limited by the diffusion time of the gas species into the liquid. The characteristic diffusion time is proportional to the square of the film thickness, so the time to reach a target gas saturation in the liquid is quartered every time the liquid film thickness is halved. Therefore, thin liquid channels defined by microwicks or membrane contactors provide improved mass transport and process intensification as compared to other absorption techniques relying on thicker liquid layers. 
     In wicks wetted by a sorbent, the liquid is preferably confined to the wick volume, and therefore the liquid film thickness is related to the thickness of the wick. In a membrane contactor absorber, a liquid microchannel of defined thickness is separated from a gas microchannel by a porous membrane. In this case it is preferred that the sorbent liquid does not wet the contactor material so it does not weep or break-through the fine pores of the membrane into the gas channel. If the pressure drop across the membrane is relatively high, as occurs when the liquid flow rate is increased sufficiently, break-through is observed. It is difficult to recover from a membrane contactor break-through, because wettability and the pressure driving force do not favor return of the liquid from the gas channel to the liquid channel. The analogous process upset in a microwick absorber is flooding, in which the feed flow rate of liquid exceeds the throughput of the wick. Since the microwick material is wetted, flooding will readily subside into the liquid flow structure when the feed rate is reduced. A challenge for the microwick absorber technology is to create very thin liquid films (e.g., &lt;100 μm) with high throughput. The present invention has overcome these challenges and provide a highly efficient method and apparatus for contacting a gas with a liquid in a microchannel. 
     In a first aspect, the invention provides a process of contacting a substance in a first fluid with a substance in a second fluid. In this process, a gas comprising a first substance passes into a gas channel; and a liquid comprising a second substance passes into a fluid microchannel at a rate such that 1/Pe m  is about 30 or less. The fluid microchannel is adjacent to the gas channel. The dimensions of this fluid microchannel is either defined by a wick (which is adjacent to the fluid microchannel), or a membrane that separates the fluid microchannel from the gas channel. 
     In a second aspect, the invention provides a microchannel contactor, comprising: a gas channel; and a fluid microchannel that is adjacent to the gas channel and wherein the fluid microchannel is defined by a wick, or that is separated from the gas channel by a membrane. The contactor is characterizable (i.e., capable of being characterized) by a CO 2  loading capacity of at least 0.3 CO 2  mol per mol DEA when a 2 M DEA aqueous solution is flowing through the fluid microchannel at a 2 M DEA flow rate set to establish 1/Pe m  to equal 10, and when a 20% CO 2 /80% N 2  mixture is passed into the gas channel at a level sufficient to preclude a gas phase mass transfer limitation. 
     U.S. Pat. No. 6,666,909 and U.S. patent application Ser. No. 10/011,386 filed Dec. 5, 2001 are incorporated herein as if reproduced in full below. These applications provide numerous methods and apparatus for separating fluids and/or heat exchange. One process separates fluids by passing a mixture of at least two fluids, comprising a first fluid and a second fluid, into a device having at least one channel. The channel has an open area and a wicking region. The first fluid is either a liquid (such as a droplet or liquid particle) that is sorbed by the wicking region, or a gas that, under separation conditions, forms a liquid in the wicking region. The first liquid travels through the wicking region to a liquid flow channel and then exits the device through a liquid exit channel. The second fluid is a gas that passes through the gas flow channel to a gas exit, and exits the device through the gas exit. 
     Also disclosed is a process of contacting fluids in which at least two fluids are passed into a device having at least one channel. The channel has an open area and a wicking region and an interface between the wicking region and the open area. During operation, at least one fluid flows through the wicking region, and at least one other fluid flows through the open area. At the interface between the wicking region and the open area, one fluid contacts at least one other immiscible fluid, and there is mass transfer occuring through the interface between the at least one fluid flowing through the wicking region, and the at least one other fluid flowing through the open area. 
     The presence of wicks and optional pore throats and capture structures are common to multiple embodiments of the invention. A wick is a material that will preferentially retain a wetting fluid by capillary forces and through which there are multiple continuous channels through which liquids may travel by capillary flow. The channels can be regularly or irregularly shaped. Liquid will migrate through a dry wick, while liquid in a liquid-containing wick can be transported by applying a pressure differential, such as suction, to a part or parts of the wick. The capillary pore size in the wick can be selected based on the contact angle of the liquid and the intended pressure gradient in the device, and the surface tension of the liquid. Preferably, the pressure at which gas will intrude into the wick should be greater than the pressure differential across the wick during operation—this will exclude gas from the wick. 
     The liquid preferentially resides in the wick due to surface forces, i.e. wettability, and is held there by interfacial tension. The liquid prefers the wick to the gas channel and as long as there is capacity in the wick, liquid is removed from the gas stream and does not leave in the gas stream. 
     The wick can be made of different materials depending on the liquid that is intended to be transported through the wick. The wick could be a uniform material, a mixture of materials, a composite material, or a gradient material. For example, the wick could be graded by pore size or wettability to help drain liquid in a desired direction. Examples of wick materials suitable for use in the invention include: sintered metals, metal screens, metal foams, polymer fibers including cellulosic fibers, or other wetting, porous materials. The capillary pore sizes in the wick materials are preferably in the range of 10 nm to 1 mm, more preferably 100 nm to 0.1 mm, where these sizes are the largest pore diameters in the cross-section of a wick observed by scanning electron microscopy (SEM). In a preferred embodiment, the wick is, or includes, a microchannel structure. Liquid in the microchannels migrates by capillary flow. The microchannels can be of any length, preferably the microchannels have a depth of 1 to 1000 micrometers (μm), more preferably 10 to 500 μm. Preferably the microchannels have a width of 1 to 1000 μm, more preferably 10 to 100 μm. In a preferred embodiment, the microchannels are microgrooves, that is, having a constant or decreasing width from the top to the bottom of the groove. In another embodiment, the microchannels form the mouth to a larger diameter pore for liquid transport. 
     The wick is preferably not permitted to dry out during operation since this could result in gas escaping through the wick. One approach for avoiding dryout is to add a flow restrictor in capillary contact with the wick structure, such as a porous structure with a smaller pore size than the wick structure and limiting the magnitude of the suction pressure such that the non-wetting phase(s) cannot displace the wetting phase from the flow restrictor. This type of restrictor is also known as a pore throat. In preferred embodiments, a pore throat is provided between the wick and the liquid flow channel and/or at the liquid outlet. In some embodiments, the wick can have a small pore diameter such that it serves to transport fluids from the gas channel and also prevents gas intrusion, thus serving the dual purpose of a wick and a pore throat. 
     A pore throat has a bubble point that is greater than the maximum pressure difference across the pore throat during operation. This precludes intrusion of gas into the pore throat due to capillary forces (surface tension, wettability, and contact angle dependent). The pore throat should seal the liquid exit, so there should be a seal around the pore throat or the pore throat should cover the exit in order to prevent gas from bypassing the pore throat. The pore throat is preferably very thin to maximize liquid flow through the pore throat at a given pressure drop across the pore throat. Preferably, the pore throat has a pore size that is less than half that of the wick and a thickness of 50% or less than the wick&#39;s thickness; more preferably the pore throat has a pore size that is 20% or less that of the wick. Preferably, the pore throat is in capillary contact with the wicking material to prevent gas from being trapped between the wick and the pore throat and blocking the exit. 
     Flooding can result from exceeding the flow capacity of the device for wetting phase through the wick; the flow capacity is determined by the pore structure of the wick, the cross-sectional area for flow, or the pressure drop in the wick in the direction of flow. 
     A capture structure can be inserted (at least partly) within the gas flow channel, and in liquid contact with the wick. The capture structure assists in removing (capturing) a liquid from the gas stream. One example of a capture structure are cones that protrude from the wick; liquid can condense on the cones and migrate into the wick—an example of this capture structure is shown in U.S. Pat. No. 3,289,752, incorporated herein by reference. Other capture structures include inverted cones, a liquid-nonwetting porous structure having a pore size gradient with pore sizes getting larger toward the wick, a liquid-wetting porous structure having a pore size gradient with pore sizes getting smaller toward the wick and fibers such as found in commercial demisters or filter media. Mechanisms for capturing dispersed liquid particles include impingement (due to flow around obstructions), Brownian capture (long residence time in high surface area structure), gravity, centrifugal forces (high curvature in flow), or incorporating fields, such as electrical or sonic fields, to induce aerosol particle motion relative to the flow field. 
     Nonwetting surfaces can be disposed on the gas flow channel walls. These non-wetting surfaces can help prevent formation of a liquid film on the surface and, in combination with a wick or a wick and capture structure the liquid present in a fluid mixture can be siphoned away from the condensing surface by capillary flow, thereby avoiding problems associated with dropwise condensation, such as cold spots or re-entrainment. 
     The invention, in various aspects and embodiments can provide numerous advantages including: rapid mass transport, high rates of heat transfer, low cost, durability, and highly efficient liquid separations in a compact space. 
     Devices and processes of the present invention are capable of integrating high efficiency, high power density heat exchange. Heat exchange can facilitate phase changes within the separation device, such as condensation and evaporation. One example is partial condensation of a gas stream to recover condensable components, such as water from the cathode waste gas stream from a fuel cell. Another optional feature is reduced or non-wettability of the wall adjacent to a heat exchange surface to preclude formation of a liquid film. The heat transfer coefficient would increase substantially by avoiding the resistance of a liquid film. 
     The embodiments show preferred embodiments in which there are multiple gas flow channels operating in parallel. This configuration allows high throughput and provides a large surface area to volume ratio for high efficiency. In some preferred embodiments, layers are stacked to have between 2 and 600 separate gas flow channels, more preferably between 4 and 40 gas flow channels. As an alternative to the parallel arrangement, the channels could be connected in series to create a longer flow path. 
     Another advantageous feature of some preferred embodiments of the invention is that the gas flow channels and/or liquid flow channels are essentially planar in the fluid separation regions. This configuration enables highly rapid and uniform rates of mass and heat transport. In some preferred embodiments, the gas flow channels and/or liquid flow channels have dimensions of width and length that are at least 10 times larger than the dimension of height (which is perpendicular to net gas flow). 
     The subject matter of the present invention is distinctly claimed in the concluding portion of this specification. However, both the organization and method of operation, together with further advantages and objects thereof, may further be understood by reference to the following description taken in connection with accompanying drawings wherein like reference characters refer to like elements. 
     GLOSSARY OF TERMS 
     A “capture structure” is a structure disposed (at least partly) within a gas flow channel that assists movement of a liquid into the wick. 
     A “cell” refers to a separate component, or an area within an integrated device, in which at least one unit operation is performed. In preferred embodiments, the cell has a width less than about 20 cm, length less than about 20 cm, and height less than about 3 cm. 
     “Device volume” refers to the entire volume of the device, including channels, headers, and shims. 
     “Entrainment” refers to transport of liquid into the gas exit 
     “Flow microchannel” refers to a microchannel through which a fluid flows during normal operation of an apparatus. 
     A “laminated device” is a device having at least two nonidentical layers, wherein these at least two nonidentical layers can perform a unit operation, such as heat transfer, condensation, etc., and where each of the two nonidentical layers are capable of having a fluid flow through the layer. In the present invention, a laminated device is not a bundle of fibers in a fluid medium. 
     A “liquid” is a substance that is in the liquid phase within the wick under the relevant operating conditions. 
     “Microchannel” refers to a channel having at least one dimension of 5 mm or less. The length of a microchannel is defined as the furthest direction a fluid could flow, during normal operation, before hitting a wall. The width and depth are perpendicular to length, and to each other, and, in the illustrated embodiments, width is measured in the plane of a shim or layer. 
     “Microcomponent” is a component that, during operation, is part of a unit process operation and has a dimension that is 1 mm or less. 
     “Microcomponent cell” is a cell within a device wherein the cell contains microcomponents. 
     “Pore throat” refers to a porous structure having a maximum pore dimension such that a non-wetting fluid is restricted from displacing a wetting fluid contained with the pore throat under normal operating conditions. 
     “Residence time” refers to the time that a fluid occupies a given working volume. 
     A “substance” is a chemical compound or molecule. 
     “Unit process operation” refers to an operation in which the chemical or physical properties of a fluid stream are modified. Unit process operations (also called unit operations) may include modifications in a fluid stream&#39;s temperature, pressure or composition. 
     A “wicking region” is the volume occupied by a wick, or, a wicking surface such as a grooved microchannel surface. 
     “Working volume” refers to the total channel volume of the device, and excludes the headers and solid shim and end plate materials. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a cross-sectional view of a gas/liquid separator. 
         FIG. 2  is a top-down view of a gas flow channel layer of the gas/liquid separator. 
         FIG. 3  is a bottom-up view of a liquid flow channel layer of the gas/liquid separator. 
         FIG. 4  is a top-down view of an end plate of the gas/liquid separator. 
         FIG. 5  illustrates the other end plate of the gas/liquid separator. 
         FIG. 6  is a cross-sectional view of a gas/liquid contactor. 
         FIG. 7  is a top-down view of a gas flow channel layer of the gas/liquid contactor. 
         FIG. 8  is a bottom-up view of a liquid flow channel layer of the gas/liquid contactor. 
         FIG. 9  illustrates a wick insert. 
         FIG. 10  is a cross-sectional view of a counter-current heat exchange condenser assembly. 
         FIG. 11  is a top-down view of a gas flow channel layer of the counter-current heat exchange condensor assembly. 
         FIG. 12  is a bottom-up view of a liquid flow channel layer of the counter-current heat exchange condensor assembly. 
         FIG. 13  is a top-down view of a heat exchange layer of the counter-current heat exchange condenser assembly. 
         FIG. 14  is a cross-sectional view of a cross-current heat exchange condenser assembly. 
         FIG. 15  is a top-down view of a gas flow channel layer of the cross-current heat exchange condensor assembly. 
         FIG. 16  is a bottom-up view of a liquid flow channel layer of the cross-current heat exchange condensor assembly. 
         FIG. 17  is a top-down view of a heat exchange layer of the cross-current heat exchange condenser assembly. 
         FIG. 18  is a data plot from the Examples showing maximum water flow rate with no entrainment as a function of gas flow rate. 
         FIG. 19  is a plot of carbon dioxide loading in 2M DEA/water as a function of the inverse Peclet number for varying liquid film thickness in three microwick contactors and one membrane contactor. 
         FIG. 20  is a plot of carbon dioxide flux into a 2M DEA/PEG solution in a microchannel membrane contactor at three liquid flow rates. 
     
    
    
     DETAILED DESCRIPTION 
     In a first aspect, the invention provides a gas/liquid separator. An embodiment of one such device is illustrated in FIG.  1 . The illustrated device is made up of end plates  6 ,  8  and alternating central shims  1  and  2 . A fluid inlet  9  is connected to open channel  12 . Shim  1  has open gas flow channels  14 . The surface  18  of solid section  16  forms the bottom of the gas flow channel. The top of the gas flow channel is formed by wick  22  of shim  2 . As the gas/liquid mixture flows through channel  14 , the liquid component is absorbed by the wick  22 . The liquid in the wick travels to a wick exit channel and flows out through liquid outlet  29 . To remove liquid suction can be applied through a pump (not shown). Gas flows out through a separate channel and out through gas outlet  19 . 
     A top down view of shim  1  is illustrated in FIG.  2 . Channels  14  are separated by lands  32 . The lands can support a wick insert and prevent channel collapse during fabrication. Gas flows through channels  14  and into gas exit holes  34 . Lands  32  are preferably the same height as edges  36 . The height of the gas flow channels  14 , from surface  18  to wick surface  24  is preferably about 10 μm to 5 mm, more preferably 100 μm to 1 mm. The height of the channels is preferably small for good heat and mass transfer and overall device size, balanced against potentially slower flow rates. The path to exit wicks  42  can be blocked by lands  38 . A high ratio of surface area of exposed wick to volume of gas flow channel is desirable for efficient phase separations. Preferably this ratio is from 1 to 1000 cm 2 :cm 3 , more preferably from 5 to 100. 
     A bottom up view of shim  2  (without wick) is illustrated in FIG.  3 . It includes gas exit holes  34  (open space) and exit wicks  42 . A wick (not shown) may be inserted open space  42  (preferably without blocking hole  12 ). Alternatively, surface of the shim can be a wick structure such as microchannels. In any event, the wick structure should create a continuous liquid flow path with exit wick  42 , but should not block gas exit holes  34 . 
       FIG. 4  illustrates a top down view of end plate  6  showing spaces for gas/liquid entry  12  and gas exit holes  34 .  FIG. 5  illustrates end plate  8  with exit wicks  42 . Of course, the device could be plumbed to have gas and liquid exit from the same side or the gas/liq entry could be moved to the opposite end plate  8  to have liquid exit and gas/liq entry on the same side of the device. 
     In operation of a device with a wick, the wick should not be flooded, and it is preferably not dry. A wet or saturated wick will effectively transport liquid through capillary to a low pressure zone, such as low pressure created by suction. A pore throat may be added to liquid outlet  29  to prevent gas flow out of the liquid exit. 
     A cross-sectional view of a gas/liquid contactor is illustrated in FIG.  6 . This contactor has end plates  54  and  56  and alternating shims  51  and  52 . T-joint inlets  60  and  62  are for the passage of gas and liquid respectively. T-joint outlets  64  and  66  are for the passage of gas and liquid respectively. A top-down view of shim  51  is illustrated in FIG.  7 . Gas flows in through gas inlet holes  76  and out through outlet holes  72 . A bottom-up view of shim  52  is illustrated in FIG.  8 . Liquid flows in through wick channels  82  through the wick and out through wick channels  84 . A wick insert is illustrated in FIG.  9 . The wick insert has through holes  92  for gas flow through the wick. Regions  94  of the insert can be continuous wick or can be holes that are filled with a continuous wick through the wick channels. Where the wick insert covers regions  94 , disks or other inserts of a wicking material should be disposed in channels  78 ,  79 ,  82  and  84  to provide a continuous capillary liquid flow path. Use of microchannels in shim  52  can obviate the need for a wick insert. Endplate  54  has wick channels (not shown) corresponding to the wick channels in shim  52 . Endplate  56  has gas inlet and outlet holes (not shown) corresponding to inlet and outlet holes  72  and  76 . This device illustrates a preferred counterflow of liquid and gas phases. Where the liquid is used to selectively absorb components from the gas phase, the counterflow construction contacts the gas with the lowest concentration of extractable components with the purest liquid and thus provides for maximal absorbtion of the gas components. 
     A cross-sectional view of a counter flow heat exchange condenser assembly  100  is illustrated in FIG.  10 . The assembly includes shims  101 ,  102 , and  103 , inlets  104  and  105 , and outlets  106 ,  108 , and  110 . Shim  102  includes wick  112  and wall  124 . Shim  101  has gas flow channels  114  and walls  126 . Heat exchanger shim  103  contains microchannels  183  and wall  122 . 
     A top down view of shim  101  is illustrated in FIG.  11 . The illustrated shim contains gas flow channels  118 , fluid flow inlets  113 , lands  116 , gas exit holes  117 , heat exchange fluid holes  115 , and liquid exit hole  119 . 
       FIG. 12  illustrates a bottom up view of shim  102 . The illustrated shim includes liquid flow channel  128 , fluid flow inlets  123 , gas exit holes  127 , heat exchange fluid holes  125 , and liquid exit hole  129 . 
     A top down view of a heat exchange shim is illustrated in FIG.  13 . The heat exchange fluid enters through holes  132 , travels through microchannels  134  and exits through holes  136 . Passageways  137 ,  138 , and  139  are provided for fluid mixture, gas and liquid to flow through the heat exchange shim. 
     Endplate  190  has inlet and outlet holes for the heat exchange fluids. End plate  111  has fluid inlet holes, gas outlet holes, and liquid exit holes. 
     During operation, a fluid mixture can enter through inlet  105  and pass through gas flow channels  114 . A heat exchange fluid enters through inlet  104  and passes through microchannel layer  116 . In a preferred embodiment, one component of the fluid mixture condenses in wick  112 . Heat can be removed from (or added to) the system by the heat exchange fluid. Depending on system requirements, either wall  101  or walls  122 ,  124  can be insulating. In a preferred embodiment, the layers (shims) are arranged to have the repeating sequence: wick, gas flow channel, wall, microchannel layer, wall, gas flow channel, and wick. 
     A cross-current heat exchange assembly is illustrated in  FIGS. 14-17 . The gas and liquid inlets and outlets and the lands are indicated using the same shadings as above. The assembly includes shims  101 ,  102 , and  103 , inlets  144  and  146 , and outlets  142 ,  148 , and  149 . A top down view of shim  101  is illustrated in FIG.  15 . The illustrated shim contains fluid flow inlet  154 , lands  155 , gas exit holes  158 , heat exchange fluid holes  151 ,  152  and liquid exit hole  156 .  FIG. 16  illustrates a bottom up view of shim  102 . The illustrated shim includes fluid flow inlet  154 , gas exit holes  158 , heat exchange fluid holes  151 ,  152  and liquid exit holes  158 . A top down view of a heat exchange shim is illustrated in FIG.  17 . The heat exchange fluid enters through hole  171  and exits through hole  172 . Passageways  154 ,  158 , and  156  are provided for fluid mixture, gas and liquid to flow through the heat exchange shim. In this embodiment, the heat exchange fluid runs cross-current (at a right angle) to the flow of fluid through the gas flow channel. 
     The figures illustrate preferred embodiments in which liquid flows by direct contact of the wick in the liquid flow channels to a wick in the liquid exit channels. In other embodiments, however, the liquid, after having been sorbed into the wick, can flow into a liquid flow channel that does not contain a wick. The liquid can then flow out through wicks or by fluid flow without wicks. 
     The shims can be made of metals, plastics, ceramic or composite materials. Metal shims can be made by etching, conventional cutting and machining, electrical discharge machining (EDM), laser machining, stamping, or molding techniques. Plastic shims can be made using the same techniques or by conventional plastic forming techniques, including injection molding, hot embossing, stamping, casting, and other molding techniques. Ceramic shims could be made using techniques well known for fabricating ceramic parts, including those used in fabricating solid oxide fuel cell elements. The shim material facing the gas channel can be made hydrophobic through coatings, treatment or by the choice of material. The end plates are preferably made of a similar material as the shims and made using similar techniques. The shims are stacked with wicks installed within the liquid flow channel, either held in loosely by the lands and channel walls or by adhering the wicks to the liquid channel wall. The wick or pore throat must prevent an open path for the gas to flow to the liquid exit. This is accomplished either by close tolerances between the wick or pore throat structure and the walls, by using a sealant, such as epoxy to install the wick or pore throat, or through the use of gaskets or o-rings. End plates are then placed on the top and bottom of the shim stack. The seams between shims and between end plates and shims are either sealed by bonding or by a compression seal. Bonding can be accomplished by diffusion bonding, by chemical reaction, such as using an epoxy resin, or by gluing with an adhesive material. A compression seal can be accomplished using gaskets, O-rings, or by surface to surface contact and bolting the device together. Inlets and outlets can be connected by the same methods, by welding, by screws or bolts, or by other known connection techniques. 
     When making low volumes of a given device or when the device needs to be disassembled for cleaning or modifications, the preferred fabrication technique is to fabricate the shims and end plates by conventional machining, such as by milling. Seals between the shims and end plates are preferably accomplished by compression seals using either O-rings placed in grooves machined into one of the sealing surfaces or by using a gasket material cut to match the profile of the sealing surface. The device is then held together in compression using bolts. The liquid exit is isolated from the gas flow channel using gaskets or sealant, such as epoxy, between the wick or pore throat and the wall. Inlets and outlets can be installed using standard threaded fittings or other known connection techniques. 
     The devices and processes described herein are especially desirable for integration in a system. These systems can accomplish desired functions such as heat transfer, mass transfer, heterogeneous reaction, electrochemical reactions, or electric field enhancements. When integrated as an element in a chemical reactor, the inventive devices can result in process intensification (e.g., reduced mass transport residence times) and/or greater than equilbrium conversion and selectivity for chemical reactions. Combination with a heat exchanger can facilitate multi-phase endothermic or exothermic chemical reactions. 
     Heterogeneous catalytic reactions can also be accomplished within the proposed architecture by impregnating active catalyst materials in the wicking structure for liquid phase reactions and/or in the capture structure for gas phase reaction. One example is Fischer-Tropsch synthesis, where condensable hydrocarbons are produced. Reactor residence time can be reduced by the incorporation of structures that remove liquid hydrocarbon products in contact with the catalyst structure. The devices can also be used in an integral reactor-chemical separator. For example, the wick or an absorbent material within the wick can selectively remove one of the products. This causes a shift in the equilbrium conversion as well as improved selectivity. Other, nonlimiting, examples include low temperature water gas shift reaction, where we believe that selectively removing CO could lower the operating temperature for achieving adequate conversion. This effect could be enhanced by flowing an absorbent liquid countercurrent to a flowing gas stream. 
     EXAMPLES 
     Example 1 
     Half inch polycarbonate was machined to create a 3000 μm deep×2 cm wide×8 cm long channel. An ⅛″ NPT barbed fitting placed 1 cm from the end of the channel served as the liquid outlet. A 2 cm×8 cm piece of 70×70 stainless steel mesh available from McMaster Carr was placed in the channel beneath a {fraction (1/16)}″×2 cm×8 cm piece of sintered nickel with 5 □m pores (Mott Corporation). The sintered nickel was sealed into place using Loctite® RTV silicone adhesive. 
     A 0.25″ piece of polycarbonate was machined so that two ⅛″ NPT barbed fittings could be threaded into holes 6 cm apart. This piece of polycarbonate had been made hydrophobic by treatment in a capacitively coupled RF (13.56 MHz) plasma reactor (66×66×91 cm 3 ) using two stainless steel parallel electrodes (25 cm in diam.). The electrodes were separated by a distance of 10 cm, and were both water-cooled. The RF power was applied to the upper electrode, and the sample was placed on the lower, grounded electrode. An automatic L-type matching network with two air variable capacitors converted the complex impedance of plasmas to 50 resistivity. A dc self-bias meter with selectable scaling allowed precise control over the matching/chamber environment. The system was first evacuated to a base pressure of 10 −5  Torr using a diffusion pump. The CF 4  gas was then introduced to the system and a pressure of 100 mTorr was established by adjusting the opening of a throttle valve placed between the diffusion pump and the chamber. After a stabilization period of several minutes, the plasma was initiated. The treatment was performed at a power of 100W, a pressure of 100 mTorr, and a gas flow rate of 50 sccm for 5 minutes. (See “In-situ and real-time monitoring of plasma-induced etching of PET and acrylic films”, M. K. Shi, G. L. Graff, M. E. Gross, and P. M. Martin, Plasmas and Polymers, in press). The advancing contact angle of water on the plasma treated substrate was greater than 110°. 
     The half inch and quarter inch polycarbonate pieces were bolted together and sealed with an o-ring such that the 3000 μm channel and hydrophobic surface faced each other. The device volume was 90 cm 3 . The device was situated so that the liquid outlet faced downwards. A 3″ piece of ⅛″ tubing was attached to the liquid outlet to provide suction by siphoning. The fitting in the ½″ polycarbonate piece above the liquid outlet served as the gas outlet, while the other fitting in the ½″ polycarbonate served as the inlet to a mixture of air and water. Various flows of air were fed to the device. The water flow rate was adjusted to the maximum flow that allowed no entrainment of water in the gas exit line. This maximum flow is plotted as a function of gas flow rate (indicated as Mott in FIG.  18 ). As can be seen, the maximum water flow rate was constant at roughly 6.5 milliters/min (mL/min) between the air flow rates of 500 and 1250 mL/min. Significant entrainment of the liquid occurred at 1500 mL/min air flow rate, until the liquid flow rate was decreased to 2.6 mL/min. No gas was observed to exit the liquid channel. Given that the working volume of the channels is 4.8 cm 3 , the residence time is 0.2 seconds at the highest flow rate. 
     Example 2 
     The device was the same as above, except a 1400 μm channel replaced the 3000 μm channel. This channel had a 8 cm×2 cm piece of 0.0011″ Supramesh from Pall Corporation placed in the bottom. This material consists of sintered stainless steel overlying a fine stainless mesh. Flat gasket material with a 1.5 cm×7.5 cm hole placed inside the channel served to seal both pieces of polycarbonate together as well as preventing gas intrusion into the porous material. 
     Again, the gas flow rate was plotted against the maximum liquid flow rate that allowed no entrainment of water in the gas exit line. These data are indicated as Pall in FIG.  18 . As can be seen, the water flow rate was close to 10 mL/min between the air flow rates of 200 and 1500 mL/min. At a gas flow rate of 1750 mL/min, entrainment occurred in the air exit until the liquid flow was decreased to 5 mL/min. 
     A comparison of the efficiency of this device with a typical centrifugal separator demonstrates the economy of size and weight of this invention. A known fuel processing stream contains 355 L/min of gas with 300 mL/min water. The size of a type T cast iron gas/liquid separator from Wright-Austin to treat this stream would be approximately 2100 cm 3  and weigh 14 pounds. The residence time within the device is 0.35 seconds. In contrast, the invention would have a working volume of approximately 450 cm 3  giving a residence time of 0.08 seconds. The pressure drop across the Wright-Austin system is estimated to be 1.38 inches of water, while the pressure drop across the invention is estimated to be 0.075 inches of water. 
     Example 3 
     The effectiveness of membrane and wick microchannel contactors has been demonstrated experimentally. CO 2  was absorbed from a 20%-CO 2 :80%-N 2  mixture into a 2-M diethanolamine/water (DEA) solution. For these wick tests, a single-gas-channel, plate-type contactor was used (similar to that shown in  FIG. 1  but with only 1 gas channel and one wick layer). The membrane contactor absorber was similarly configured except for: the use of a membrane contactor instead of a microwick; heat exchange channels sandwiching the gas channel and liquid channel; and different microchannel dimensions. In each device, the CO 2 -laden gas was delivered via a gas inlet counter-current to the liquid stream. Gas flow was maintained at a sufficient level to preclude gas phase mass-transfer limitations. The composition of the effluent gas stream was determined with a residual gas analyzer, and the change in composition was used to evaluate CO 2  mass transfer into the flowing DEA solution. 
     Results for three microwick contactor experiments using wicks of various materials and thicknesses (150 μm, 250 μm, and 380 μm) and a membrane contactor test using a 100-μm liquid microchannel are presented in FIG.  19 . The results of all the experiments are correlated in terms of the inverse mass-transfer Peclet number (Pe m   −1 ), which is defined as the solute diffusivity (DEA diffusion, in this case) multiplied by the liquid residence time divided by the thickness of the liquid channel (which, in the case of the wick, is the wick channel) squared. Equilibrium uptake of CO 2  is sensitive to temperature and CO 2  partial pressure and is 0.5-0.65 moles CO 2  per mole of DEA at the conditions tested (room temperature, 20-25° C.). The objective was to achieve high solvent loading with a minimum residence time, as this would lead to reduced sorbent mass in a separation/purification system. Near equilibrium loading of CO 2  is achieved at Pe m   −1  above 10, where performance is limited by solvent capacity for the solute. Thus, it was surprisingly discovered that superior results could be obtained by controlling residence time of the liquid as a function of liquid layer thickness so that 1/Pe m  is short. 1/Pe m  should be about 30 or less, preferably about 20 or less, and more preferably about 10 or less, and in some embodiments about 5 to about 15. 
     Overall mass-transfer coefficients were also determined from the data shown in FIG.  19  and were compared to those typical of conventional packed towers using 2-M monoethanolamine/water solutions (Kohl, A. L. and R. B. Nielsen, Gas Purification, 4 th  Ed., Gulf Publishing Company, Houston, Tex., 1985). The overall mass transfer coefficients were as much as 2.6 times greater for the thinnest microwick and about 7.1 times greater for the membrane system. 
     For space applications, water is not likely the preferred solvent for absorption systems because of its relatively high vapor pressure. Using the membrane contactor absorber described above, we completed a series of experiments in which the solvent water was replaced with much less volatile polyethylene glycol (PEG). The microchannel absorber incorporated heat exchangers on both the liquid and gas sides, and this feature was used in several experiments to evaluate mass transfer rates as a function of temperature in the range ˜25 to ˜80 C. Results are shown in FIG.  20 . Reduced liquid viscosity with increasing temperature had a two-fold benefit: first, the mass transfer rate increased, most likely due to increased mass diffusivity in the liquid; and second, the liquid pressure drop across the device was reduced. This allowed higher liquid flow rates to be evaluated without liquid breakthrough across the contactor membrane. At a given sorbent flow rate (residence time), increasing the temperature of absorption above ambient also resulted in an increased conversion of DEA to amine-CO 2  product (FIG.  20 ). Thus, it was unexpectedly discovered that improved results could be obtained by increasing temperature above ambient. For example, improved CO 2  scrubbing efficiency was observed at a temperature in the range of about 40 to about 60° C. The decrease in CO 2  sorption at higher temperatures is expected, as the reverse reaction leading to desorption (or less absorption) of CO 2  from the amine is favored. This is the basis of a continuously regenerated thermal swing absorption process. Also note in  FIG. 20  that the CO 2  flux increases as the absorbent residence time decreases. The flux is higher when the CO 2  loading of the sorbent is low and Pe m   −1  is small (FIG.  19 ). 
     Because of the relatively high viscosity of PEG and a corresponding reduction in DEA diffusivity compared to that in water, mass transfer rates were lower for DEA/PEG. At room temperature, the CO 2  mass flux to a 2-M DEA/water solution was 5 to 10 times greater than that for comparably configured devices using a 2-M DEA/PEG sorbent. Since water may not be an acceptable solvent for space applications, this is further indication of the need for microchannel liquid absorbers (microwick or membrane contactor) integrated with heat exchange. Advancements in wicking microtechnology will result from thinner, higher permeability, and lower pore size wicks. Membrane contactor absorbers will benefit from robust membranes that are less susceptible to break-through. Both microwick and membrane contactor absorption approaches are amenable to scale up in multi-channel systems. 
     CLOSURE 
     While preferred embodiments of the present invention have been shown and described, it will be apparent to those skilled in the art that many changes and modifications may be made without departing from the invention in its broader aspects. The appended claims are therefore intended to cover all such changes and modifications as fall within the true spirit and scope of the invention.