Abstract:
Provided are a pressure-sensitive adhesive composition, a pressure-sensitive adhesive film, and a method of manufacturing an organic electronic device using the same. The pressure-sensitive adhesive composition that may effectively block moisture or oxygen penetrated into an organic electronic device from an external environment, and exhibit reliability under harsh conditions such as high temperature and high humidity and excellent optical characteristics, and a pressure-sensitive adhesive film including the same are provided.

Description:
BACKGROUND 
       [0001]    1. Field of the Invention 
         [0002]    The present invention relates to a pressure-sensitive adhesive composition, a pressure-sensitive adhesive film, and a method of manufacturing an organic electronic device using the same. 
         [0003]    2. Discussion of Related Art 
         [0004]    An organic electronic device (OED) refers to a device including an organic material layer generating alternation of charges using holes and electrons, and may include, for example, a photovoltaic device, a rectifier, a transmitter, and an organic light emitting diode (OLED). 
         [0005]    A representative OED, which is an OLED, has less power consumption and a higher response speed, and forms a thinner display device or light than a conventional light source. In addition, the OLED has excellent space utilization, and is expected to be applied in various fields including all kinds of portable devices, monitors, notebook computers, and TVs. 
         [0006]    To extend commercialization and use of the OLED, a major problem is durability. Organic materials and metal electrodes included in the OLED are very easily oxidized by external factors such as water, and a product including the OLED is very sensitive to environmental factors. Therefore, various methods for preventing penetration of oxygen or water from an external environment with respect to an organic electronic device such as the OLED have been suggested. 
         [0007]    In Korean Unexamined Patent No. 2008-0088606, an adhesive capsulating composition and an organic electroluminescence device are provided, and have poor processability as a pressure-sensitive adhesive based on polyisobutylene (PIB) and low reliability at high temperature and high humidity. 
         [0008]    Accordingly, in an organic electronic device, it is required to develop an encapsulant ensuring a required lifetime, excellently preventing penetration of moisture, maintaining reliability at high temperature and high humidity, and having excellent optical characteristics. 
       SUMMARY OF THE INVENTION 
       [0009]    The present invention is directed to providing a pressure-sensitive adhesive composition which can form a structure effectively preventing moisture or oxygen penetrated into an organic electronic device from an external environment, and has excellent mechanical characteristics such as handleability and processability and excellent transparency, a pressure-sensitive adhesive film, and a method of manufacturing an organic electronic device using the same. 
         [0010]    In one aspect, the present invention provides a pressure-sensitive adhesive composition. The pressure-sensitive adhesive composition may be applied to, for example, encapsulation or capsulation of an organic electronic device such as an OLED. 
         [0011]    The term “organic electronic device” used herein refers to a product or device having a structure including an organic material layer generating alternation of charges using holes and electrons between a pair of electrodes facing each other, and may include, but is not limited to, for example, a photovoltaic device, a rectifier, a transmitter, and an organic light emitting diode (OLED). In one example, the organic electronic device may be an OLED. 
         [0012]    In an exemplary embodiment of the present invention, the pressure-sensitive adhesive composition may include an encapsulating resin, a multifunctional active energy ray-polymerizable compound that can be polymerized by irradiation of an active energy ray, and a silane compound satisfying Formula 1: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0013]    In Formula 1, R 1  is hydrogen or an alkyl group. R 1  may be, for example, an alkyl group having 1 to 4 or 1 to 2 carbon atoms. In addition, in Formula 1, R 2  and R 3  are each independently hydrogen, or a linear, branched, or cyclic alkyl group, or R 2  is linked with R 3 , thereby forming a cyclic alkyl group. For example, R 2  and R 3  may be each independently hydrogen, or a linear, branched, or cyclic alkyl group. Here, the linear alkyl group may have 1 to 10, 1 to 6, or 1 to 4 carbon atoms, the branched alkyl group may have 3 to 10, 3 to 6, or 3 to 4 carbon atoms, and the cyclic alkyl group may have 3 to 10, 3 to 8, 3 to 6, or 3 to 4 carbon atoms. In addition, R 2  may be linked with R 3 , thereby forming a cyclic alkyl group having 2 to 10, 3 to 10, 4 to 9, or 4 to 8 carbon atoms. In addition, in Formula 1, R 4 , R 5 , and R 6  are each independently hydrogen, an alkyl group or an alkoxy group, at least one of R 4 , R 5 , and R 6  is an alkoxy group, and n is an integer of 1 or more. Particularly, R 4 , R 5 , and R 6  are each independently an alkyl group having 1 to 10, 1 to 6, 1 to 4, or 1 to 2 carbon atoms; or an alkoxy group having 1 to 10, 1 to 8, 1 to 4 or 1 to 2 carbon atoms. Here, at least one of R 4 , R 5 , and R 6  may be an alkoxy group, and all of R 4 , R 5 , and R 6  may be alkoxy groups, but the present invention is not limited thereto. In one example, the silane compound is not particularly limited, as long as it satisfies Formula 1, and may be, for example, 3-methacryloxypropyl trimethoxysilane, 3-methacryloxy propyl triethoxysilane, 3-acryloxy propyl trimethoxysilane, 3-acryloxy propyl triethoxysilane, 3-methacryloxy methyl triethoxysilane, 3-methacryloxy methyl trimethoxysilane, 3-acryloxy propyl methyldimethoxysilane, methacryloxy methyl methyldimethoxysilane, methacryloxy methyl methyldiethoxysilane, methacryloxy propyl methyldimethoxysilane, methacryloxy propyl methyldiethoxysilane, methacryloxy propyl dimethylmethoxysilane, or methacryloxy propyl dimethylethoxysilane. An acryloyl group of the silane compound may serve to increase an interface pressure-sensitive adhesive strength by being crosslinked with the encapsulating resin or active energy ray-polymerizable compound of the pressure-sensitive adhesive composition. The silane compound may be included at, for example, 0.1 to 10, 0.5 to 8, 0.8 to 5, 1 to 5, 1 to 4.5, or 1 to 4 parts by weight relative to 100 parts by weight of the encapsulating resin. 
         [0014]    In one example, the active energy ray-polymerizable compound may form a crosslinking structure with the silane compound satisfying Formula 1, and the crosslinking structure may form a semi-interpenetrating polymer network (semi-IPN) with the encapsulating resin. That is, the pressure-sensitive adhesive composition may include a semi-IPN. The term “semi-IPN” includes at least one polymer crosslinking structure (polymer network) and at least one linear or branched polymer, and at least a part of the linear or branched polymer has a structure penetrated into the polymer crosslinking structure. The semi-IPN may be distinguished from an IPN structure since the linear or branched polymer can be theoretically separated from the polymer crosslinking structure without loss of a chemical bond. 
         [0015]    In one exemplary embodiment, the crosslinking structure may be a crosslinking structure formed by application of heat, a crosslinking structure formed by irradiation of an active energy ray, or a crosslinking structure formed by aging at room temperature. Here, in the category of the “active energy ray”, a microwave, an infrared (IR) ray, an ultraviolet (UV) ray, an X ray, and a gamma ray, and a particle beam such as an alpha-particle beam, a proton beam, a neutron beam, or an electron beam, and conventionally, an UV ray and an electron beam may be included. As such a semi-IPN structure is introduced, a mechanical property such as processability of the pressure-sensitive adhesive composition may be increased, humidity-resistant adhesive performance is improved, transparency is realized, and high moisture barrier performance that cannot be achieved so far and an excellent panel lifetime may be realized. 
         [0016]    In one example, the active energy ray-polymerizable compound may form a crosslinking structure with the silane compound satisfying Formula 1, and the encapsulating resin may form a crosslinking structure with the active energy ray-polymerizable compound or the silane compound satisfying Formula 1, thereby forming an interpenetrating polymer network (IPN) structure. In addition, the term “IPN structure” refers to a state in which at least two crosslinking structures are present in a pressure-sensitive adhesive. In one example, the IPN structure may refer to a structure including at least two crosslinking structures in an intertwining, entanglement, or penetrating state. For example, the composition of the present invention may include a crosslinking structure by an encapsulating resin (hereinafter, referred to as a “first crosslinking structure”) and a crosslinking structure formed by a reaction of an active energy ray-polymerizable compound and the silane compound satisfying Formula 1 (hereinafter, referred to as a “second crosslinking structure”), and the first and second crosslinking structures may be in an interwinding state or an entanglement state. That is, as the pressure-sensitive adhesive composition includes a semi-IPN or IPN structure in a crosslinked state, excellent durability and reliability of a pressure-sensitive adhesive may be realized under harsh conditions such as high temperature and high humidity by increasing a pressure-sensitive adhesive strength of the pressure-sensitive adhesive and preventing a decrease in an interface pressure-sensitive adhesive strength due to moisture penetration. 
         [0017]    In an exemplary embodiment of the present invention, the encapsulating resin may have a glass transition temperature of less than 0, −10, −30, −50, or −60° C. Here, the glass transition temperature may refer to a glass transition temperature after a UV ray is irradiated at a dose of approximately 1 J/cm 2  or more, or a glass transition temperature after thermal curing is additionally performed after UV irradiation. 
         [0018]    In one example, the encapsulating resin may include a styrene-based resin or an elastomer, a polyolefin-based resin or an elastomer, other elastomers, a polyoxyalkylene-based resin or an elastomer, a polyester-based resin or an elastomer, a polyvinylchloride-based resin or an elastomer, a polycarbonate-based resin or an elastomer, a polyphenylenesulfide-based resin or an elastomer, a polyamide-based resin or an elastomer, an acrylate-based resin or an elastomer, an epoxy-based resin or an elastomer, a silicone-based resin or an elastomer, a fluorine-based resin or an elastomer, or a mixture thereof. 
         [0019]    Here, the styrene-based resin or an elastomer may be, for example, a a styrene-ethylene-butadiene-styrene (SEBS) block copolymer, a styrene-isoprene-styrene (SIS) block copolymer, an acrylonitrile-butadiene-styrene (ABS) block copolymer, an acrylonitrile-styrene-acrylate (ASA) block copolymer, a styrene-butadiene-styrene (SBS) block copolymer, a styrene-based homocopolymer, or a mixture thereof. The olefin-based resin or an elastomer may be, for example, a high density polyethylene-based resin or an elastomer, a low density polyethylene-based resin or an elastomer, a polypropylene-based resin or an elastomer, or a mixture thereof. The elastomer may be, for example, an ester-based thermoplastic elastomer, an olefin-based elastomer, a silicone-based elastomer, an acrylic elastomer, or a mixture thereof. Among these, the olefin-based thermoplastic elastomer may be a polybutadiene resin or an elastomer or a polyisobutylene resin or an elastomer. The polyoxyalkylene-based resin or an elastomer may be, for example, a polyoxymethylene-based resin or an elastomer, a polyoxyethylene-based resin or an elastomer, or a mixture thereof. The polyester-based resin or an elastomer may be, for example, a polyethylene terephthalate-based resin or an elastomer, a polybutylene terephthalate-based resin or an elastomer, or a mixture thereof. The polyvinylchloride-based resin or an elastomer may be, for example, polyvinylidene chloride. The encapsulating resin may include a mixture resin of hydrocarbon, for example, hexatriacontane or paraffin. The polyamide-based resin or an elastomer may be, for example, nylon. The acrylate-based resin or an elastomer may be, for example, polybutyl(meth)acrylate. The epoxy-based resin or an elastomer may be, for example, a bisphenol-type such as a bisphenol A-type, a bisphenol F-type, a bisphenol S-type, and a hydrogenated product thereof; a novolac-type such as a phenolnovolac-type or a cresolnovolac-type; a nitrogen-containing ring-type such as a triglycidylisocyanurate-type or a hydantoin-type; an alicyclic-type; an aliphatic-type; an aromatic-type such as a naphthalene-type or a biphenyl-type; a glycidyl-type such as a glycidylether-type, a glycidylamine-type, or a glycidylester-type; a dicyclo-type such as dicyclopentadiene-type; an ester-type; an etherester-type; or a mixture thereof. The silicone-based resin or an elastomer may be, for example, polydimethylsiloxane. In addition, the fluorine-based resin or an elastomer may be a polytrifluoroethylene resin or an elastomer, a polytetrafluoroethylene resin or an elastomer, a polychlorotrifluoroethylene resin or an elastomer, a polyhexafluoropropylene resin or an elastomer, polyvinylidene fluoride, polyvinyl fluoride, polyethylenepropylene fluoride, or a mixture thereof. 
         [0020]    One of the above-listed resins or elastomers may be grafted to, for example, maleic anhydride, copolymerized with another one of the listed resins or elastomers or a monomer for preparing the resin or elastomer, or modified by a compound, other than the above-used resins or elastomers. The compound may be a carboxyl-terminated butadiene-acrylonitrile copolymer. 
         [0021]    In one example, the pressure-sensitive adhesive composition is an encapsulating resin, which may include an olefin-based elastomer, a silicone-based elastomer, or an acrylic elastomer of the above-described types, but the present invention is not limited thereto. 
         [0022]    Specifically, the encapsulating resin may be a copolymer of a diene and an olefin-based compound having one carbon-carbon double bond. Here, the olefin-based compound may include isobutylene, propylene, or ethylene, and the diene may be a monomer capable of being polymerized with the olefin-based compound, for example, 1-butene, 2-butene, isoprene, or butadiene. That is, the encapsulating resin of the present invention may be, for example, a homopolymer of an isobutylene monomer; a copolymer prepared by copolymerizing an isobutylene monomer with a monomer capable of being polymerized therewith; or a mixture thereof. In one example, the copolymer of the olefin-based compound having one carbon-carbon double bond and the diene may be a butyl rubber. When a specific resin is used as described above, moisture barrierability that would be achieved in the present invention may be satisfied. In addition, the present invention may improve humidity resistance and heat resistance by introducing various crosslinking systems described above since a conventional isobutylene polymer has a low moisture permeability but has low heat resistance. 
         [0023]    In the pressure-sensitive adhesive composition, the resin or elastomer component may have a weight average molecular weight (Mw) to an extent that the pressure-sensitive adhesive composition can be plasticized in a film type. For example, the resin or elastomer may have a weight average molecular weight (Mw) of approximately 100,000 to 2,000,000, 100,000 to 1,500,000, or 100,000 to 1,000,000. The term “weight average molecular weight” used herein refers to a converted value with respect to standard polystyrene measured by gel penetration chromatography (GPC). However, the resin or elastomer component does not necessarily have the above-mentioned weight average molecular weight. For example, when a molecular weight of the resin or elastomer component is not sufficient for forming a film, a separate binder resin may be blended in the pressure-sensitive adhesive composition. 
         [0024]    The pressure-sensitive adhesive composition of the present invention may include, as described above, an active energy ray-polymerizable compound having high compatibility with the encapsulating resin and capable of forming a specific crosslinking structure with the encapsulating resin. 
         [0025]    For example, the pressure-sensitive adhesive composition of the present invention may include a multifunctional active energy ray-polymerizable compound that can be polymerized by irradiation of an active energy ray with the encapsulating resin. The active energy ray-polymerizable compound may refer to, for example, a compound including at least two of functional groups that can participate in a polymerization reaction by irradiation of an active energy ray, for example, a functional group including an ethylene-like unsaturated double bond such as an acryloyl group or a methacryloyl group, and a functional group such as an epoxy group or an oxetane group. 
         [0026]    As the multifunctional active energy ray-polymerizable compound, for example, a multifunctional acrylate (MFA) may be used. 
         [0027]    In addition, the multifunctional active energy ray-polymerizable compound that can be polymerized by the irradiation of an active energy ray may satisfy Formula 2. In addition, the active energy ray-polymerizable compound may be included at 5 to 30, 5 to 25, 8 to 20, 10 to 18, or 12 to 18 parts by weight relative to 100 parts by weight of the encapsulating resin. 
         [0000]    
       
                 
         
             
             
         
       
     
         [0028]    In Formula 2, R 1  is hydrogen or an alkyl group having 1 to 4 carbon atoms, n is an integer of 2 or more, and X is a residue induced from a linear, branched, or cyclic alkyl group having 3 to 30 carbon atoms. Here, when X is a residue induced from a cyclic alkyl group, X may be, for example, a residue induced from a cyclic alkyl group having 3 to 30, 6 to 28, 8 to 22, or 12 to 20 carbon atoms. In addition, when X is a residue induced from a linear alkyl group, X may be a residue induced from a linear alkyl group having 3 to 30, 6 to 25, or 8 to 20 carbon atoms. In addition, when X is a residue induced from a branched alkyl group, X may be a residue induced from a branched alkyl group having 3 to 30, 5 to 25, or 6 to 20 carbon atoms. 
         [0029]    The term “residue induced from an alkyl group” used herein may refer to a residue of a specific compound composed of an alkyl group. In one example, in Formula 2, when n is 2, X may be an alkylene group. In addition, when n is 3 or more, at least two hydrogens of the alkyl group may be released from X, and then bind to a (meth)acryloyl group of Formula 2. 
         [0030]    The term “alkyl group” used herein may refer to, unless particularly defined otherwise, an alkyl group having 1 to 30, 1 to 25, 1 to 20, 1 to 16, 1 to 12, 1 to 8, or 1 to 4 carbon atoms. The alkyl group may have a linear, branched, or cyclic structure, and may be optionally substituted by at least one substituent. 
         [0031]    The term “alkylene group” used herein may be, unless particularly defined otherwise, an alkylene group having 2 to 30, 2 to 25, 2 to 20, 2 to 16, 2 to 12, 2 to 10, or 2 to 8 carbon atoms. The alkylene group may have a linear, branched, or cyclic structure, and may be optionally substituted by at least one substituent. 
         [0032]    The term “alkoxy group” used herein may be, unless particularly defined otherwise, an alkoxy group having 1 to 20, 1 to 16, 1 to 12, 1 to 8, or 1 to 4 carbon atoms. The alkoxy group may be a linear, branched, or cyclic type. In addition, the alkoxy group may be optionally substituted by at least one substituent. 
         [0033]    The multifunctional active energy ray-polymerizable compound that can be polymerized by the irradiation of an active energy ray may be any one satisfying Formula 2 without limitation. For example, the compound may be 1,4-butanediol di(meth)acrylate, 1,3-butylene glycol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, 1,8-octanediol di(meth)acrylate, 1,12-dodecanediol di(meth)acrylate, neopentylglycol di(meth)acrylate, dicyclopentanyl di(meth)acrylate, cyclohexane-1,4-dimethanol di(meth)acrylate, tricyclodecanedimethanol (meth)diacrylate, dimethylol dicyclopentane di(meth)acrylate, neopentyl glycol modified trimethylpropane di(meth)acrylate, adamantane di(meth)acrylate, trimethylolpropane tri(meth)acrylate, or a mixture thereof. 
         [0034]    As the multifunctional active energy ray-polymerizable compound, for example, a compound having a molecular weight of less than 1,000 and including at least two functional groups may be used. In this case, the molecular weight may refer to a weight average molecular weight or a conventional molecular weight. A cyclic structure included in the multifunctional active energy ray-polymerizable compound may be any one of a carbocyclic structure, a heterocyclic structure, a monocyclic structure, and a polycyclic structure. 
         [0035]    In an exemplary embodiment of the present invention, the pres sure-sensitive adhesive composition may further include a radical initiator that can induce a polymerization reaction of the above-described active energy ray-polymerizable compound. The radical initiator may be a photoinitiator or a thermal initiator. A specific type of the photoinitiator may be suitably selected in consideration of a curing rate and possibility of yellowing. For example, as the photoinitiator, a benzoin-, hydroxy ketone-, amino ketone-, or phosphine oxide-based photoinitiator, and specifically, benzoin, benzoin methylether, benzoin ethylether, benzoin isopropylether, benzoin n-butylether, benzoin isobutylether, acetophenone, dimethylamino acetophenone, 2,2-dimethoxy-2-phenylacetophenone, 2,2-diethoxy-2-phenylacetophenone, 2-hydroxy-2-methyl-1-phenylpropanelone, 1-hydroxycyclohexylphenylketone, 2-methyl-1-[4-(methylthio)phenyl]-2-morpholino-propane-1-one, 4-(2-hydroxyethoxy)phenyl-2-(hydroxy-2-propyl)ketone, benzophenone, p-phenylbenzophenone, 4,4′-diethylaminobenzophenone, dichlorobenzophenone, 2-methylanthraquinone, 2-ethylanthraquinone, 2-t-butylanthraquinone, 2-amino anthraquinone, 2-methylthioxanthone, 2-ethylthioxanthone, 2-chlorothioxanthone, 2,4-dimethylthioxanthone, 2,4-diethylthioxanthone, benzyldimethylketal, acetophenone dimethylketal, p-dimethylamino benzoic acid ester, oligo[2-hydroxy-2-methyl-1-[4-(1-methylvinyl)phenyl]propanone], or 2,4,6-trimethylbenzoyl-diphenyl-phosphineoxide may be used. 
         [0036]    The radical initiator may be included at 0.2 to 20, 0.5 to 18, 1 to 15, or 2 to 13 parts by weight relative to 100 parts by weight of the active energy ray-polymerizable compound. Accordingly, the reaction of the active energy ray-polymerizable compound is effectively induced, and degradation of physical properties of the pressure-sensitive adhesive composition due to remaining components after curing may be prevented. 
         [0037]    In one example, the pressure-sensitive adhesive composition may further include a tackifier. The tackifier may be a hydrogenated cyclic olefin-based polymer. As the tackifier, for example, a hydrogenated petroleum resin obtained by hydrogenating a petroleum resin may be used. The hydrogenated petroleum resin may be partially or completely hydrogenated, and may be a mixture of such resins. Such a tackifier may have a high compatibility with the pressure-sensitive adhesive composition, excellent moisture barrierability, and a small content of an organic volatile component. A specific example of the hydrogenated petroleum resin may be a hydrogenated terpene-based resin, a hydrogenated ester-based resin, or a hydrogenated dicyclopentadiene-based resin. The tackifier may have a weight average molecular weight of approximately 200 to 5,000. A content of the tackifier may be suitably controlled as needed. For example, the content of the tackifier may be selected in consideration of a degree of crosslinking of the pressure-sensitive adhesive composition. According to one example, the tackifier may be included at 5 to 100, 8 to 95, 10 to 93, or 15 to 90 parts by weight relative to 100 parts by weight of a solid content of the pressure-sensitive adhesive composition. 
         [0038]    The pressure-sensitive adhesive composition may further include a moisture absorbent when needed. The term “moisture absorbent” may refer to a material that can remove moisture or vapor penetrated into a pressure-sensitive adhesive film to be described below through a chemical reaction. When the pressure-sensitive adhesive composition of the present invention includes a moisture absorbent, light transmittance to be described below may not be satisfied in the formation in a film, but instead, excellent moisture barrierability may be realized. Specifically, the pressure-sensitive adhesive composition may be formed in a film to be applied to encapsulation of an organic electronic device. In this case, when the pressure-sensitive adhesive composition does not include a moisture absorbent and exhibits excellent transparency, it may be applied to encapsulation of a top-emissive organic electronic device, or when the pressure-sensitive adhesive composition includes a moisture absorbent and exhibits excellent moisture barrierability, it may be applied to encapsulation of a bottom-emissive organic electronic device. However, the present invention is not limited thereto. That is, when the pressure-sensitive adhesive composition does not include a moisture absorbent and exhibits excellent transparency, it may be applied to encapsulation of a bottom-emissive organic electronic device. 
         [0039]    For example, the moisture absorbent may be present while being uniformly dispersed in the pressure-sensitive adhesive composition or a pressure-sensitive adhesive layer to be described below. Here, the uniformly dispersed state may mean that the state in which the moisture absorbent is present even in any part of the pressure-sensitive adhesive composition or the pressure-sensitive adhesive layer at the same or substantially the same density. As the moisture absorbent used herein, for example, a metal oxide, a sulfate, or an organic metal oxide may be used. Specifically, the sulfate may be magnesium sulfate, sodium sulfate, or nickel sulfate, and the organic metal oxide may be aluminum oxide octylate. Here, the metal oxide may be phosphorus pentoxide (P 2 O 5 ), lithium oxide (Li 2 O), sodium oxide (Na 2 O), barium oxide (BaO), calcium oxide (CaO), or magnesium oxide (MgO), and the metal salt may be a sulfate such as lithium sulfate (Li 2 SO 4 ), sodium sulfate (Na 2 SO 4 ), calcium sulfate (CaSO 4 ), magnesium sulfate (MgSO 4 ), cobalt sulfate (CoSO 4 ), gallium sulfate (Ga 2 (SO 4 ) 3 ), titanium sulfate (Ti(SO 4 ) 2 ), or nickel sulfate (NiSO 4 ); a metal halide such as calcium chloride (CaCl 2 ), magnesium chloride (MgCl 2 ), strontium chloride (SrCl 2 ), yttrium chloride (YCl 3 ), copper chloride (CuCl 2 ), cesium fluoride (CsF), tantalum fluoride (TaF 5 ), niobium fluoride (NbF 5 ), lithium bromide (LiBr), calcium bromide (CaBr 2 ), cesium bromide (CeBr 3 ), selenium bromide (SeBr 4 ), vanadium bromide (VBr 3 ), magnesium bromide (MgBr 2 ), barium iodide (BaI 2 ), or magnesium iodide (MgI 2 ); or a metal chlorate such as barium perchlorate (Ba(ClO 4 ) 2 ) or magnesium perchlorate (Mg(ClO 4 ) 2 ), but the present invention is not limited thereto. As the moisture absorbent that can be included in the pressure-sensitive adhesive composition, one or at least two of the above-described materials may be used. In one example, when at least two of the above materials are used, the moisture absorbent may be calcined dolomite. 
         [0040]    Such a moisture absorbent may be controlled in a suitable size according to its use. In one example, an average diameter of the moisture absorbent may be controlled to approximately 10 to 15000 nm. A moisture absorbent having the above range of the average diameter may be easily stored due to a not too high reaction speed with moisture, and may effectively remove moisture without damage to an element to be encapsulated. 
         [0041]    A content of the moisture absorbent may be suitably selected without particular limitation in consideration of a desired barrier characteristic. 
         [0042]    The pressure-sensitive adhesive composition may further include a moisture blocker when needed. The term “moisture blocker” used herein may refer to a material that can block or prevent migration of moisture or vapor in the film while having no or low reactivity with moisture. As the moisture blocker, one or at least two of clay, talc, needle-like silica, planar silica, porous silica, zeolite, titania, and zirconia may be used. In addition, a surface of the water blocker may be treated with an organic modifier to facilitate penetration of an organic material. As such an organic modifier, dimethyl benzyl hydrogenated tallow quaternary ammonium, dimethyl hydrogenated tallow quaternary ammonium, methyl tallow bis-2-hydroxyethyl quaternary ammonium, dimethyl hydrogenated tallow 2-ethylhexyl quaternary ammonium, dimethyl dehydrogenated tallow quaternary ammonium, or a mixture thereof may be used. 
         [0043]    A content of the moisture blocker may be suitably selected without particular limitation in consideration of a desired blocking characteristic. 
         [0044]    In addition to the above-described components, various additives may be included in the pressure-sensitive adhesive composition according to its use and a process of manufacturing a pressure-sensitive adhesive film that will be described below. For example, the pressure-sensitive adhesive composition may include a curable material, a crosslinking agent, or a filler at a suitable range of content according to a desired physical property. 
         [0045]    In one example, the pressure-sensitive adhesive composition of the present invention may have a gel content represented by Equation 1 of 50% or more. 
         [0000]      Gel content(wt %)= B/A× 100  [Equation 1]
 
         [0046]    In Equation 1, A is a mass of the pressure-sensitive adhesive composition, and B is a dry mass of an insoluble content of the pressure-sensitive adhesive composition remaining after being dipped in toluene at 60° C. for 24 hours and filtered through a 200-mesh filter (pore size of 200 μm). 
         [0047]    The gel content represented by Equation 1 may be 50 to 99%, 50 to 90%, 50 to 80%, or 50 to 70%. That is, in the present invention, a pressure-sensitive adhesive composition having an excellent moisture blocking characteristic, reliability, and an optical characteristic may be realized by determining suitable ranges of a crosslinking structure and a degree of crosslinking of the pressure-sensitive adhesive composition from the gel content. 
         [0048]    In another aspect, the present invention provides a pressure-sensitive adhesive film. The pressure-sensitive adhesive film may include the pressure-sensitive adhesive layer. In addition, the pressure-sensitive adhesive film may satisfy Equation 2 when a peeling strength (peeling rate: 5 mm/sec, peeling angle: 180 degrees) to a substrate of the pressure-sensitive adhesive layer after being stored at 25° C. and a relative humidity of 50% for 1 hour is P gf/25 mm, and a peeling strength (peeling rate: 5 mm/sec, peeling angle: 180 degrees) to a substrate of the pressure-sensitive adhesive layer after being stored at 85° C. and a relative humidity of 85% for 1 hour is Q gf/25 mm. The temperature and humidity conditions may be a constant temperature and a constant humidity. 
         [0000]        Q≧ 1.3  P   [Equation 2]
 
         [0049]    In addition, in an exemplary embodiment of the present invention, the pressure-sensitive adhesive film may have a peeling strength (peeling rate: 5 mm/sec, peeling angle: 180 degrees) of 1,000 gf/inch or more with respect to a glass substrate after being stored for 1 hour at 25° C. and a relative humidity of 50% before or after a crosslinking structure is realized. The peeling strength may be measured using a texture analyzer according to ASTM3330. When a composition or crosslinking condition of the pressure-sensitive adhesive composition is controlled to have such a peeling strength, a pressure-sensitive adhesive film that can realize an encapsulation or capsulation structure having excellent durability with respect to an electronic device may be provided. 
         [0050]    The pressure-sensitive adhesive layer of the pressure-sensitive adhesive film may further include the above-described pressure-sensitive adhesive composition or a crosslinked product thereof. The pressure-sensitive adhesive layer may also have a film or sheet shape. Such a pressure-sensitive adhesive layer may be used to encapsulate an organic electronic element. 
         [0051]    In an exemplary embodiment of the present invention, the pres sure-sensitive adhesive layer may be formed in a monolayer structure as described above, or may be formed of at least two layers that will be described below. For example, the pressure-sensitive adhesive layer may include a first layer containing the above-described pressure-sensitive adhesive composition or a crosslinked product thereof and a second layer including a pressure-sensitive adhesive resin or an adhesive resin. The pressure-sensitive adhesive resin or adhesive resin included in the second layer may be the same as or different from the above-described encapsulating resin, and may be suitably selected by a conventional technician according to a purpose. When the pressure-sensitive adhesive layer is fomed of at least two layers, the above-described pressure-sensitive adhesive strength or peeling strength may correspond to a first layer or a second layer. In addition, the first and second layers may or may not include a moisture absorbent. 
         [0052]    In one example, the pressure-sensitive adhesive resin included in the second layer may include a curable resin including at least one heat-curable functional group such as a glycidyl group, an isocyanate group, a hydroxyl group, a carboxyl group, or an amide group, or at least one electromagnetic wave-curable functional group such as an epoxide group, a cyclic ether group, a sulfide group, an acetal group, or a lactone group, which may be cured to exhibit an adhesive characteristic. In addition, a specific type of such a resin may be, but is not limited to, an acryl resin, a polyester resin, an isocyanate resin, or an epoxy resin. 
         [0053]    In the present invention, as the curable resin, an aromatic or aliphatic, or linear or branched epoxy resin may be used. In one exemplary embodiment of the present invention, an epoxy resin containing at least two functional groups and having an epoxy equivalent of 180 to 1,000 g/eq may be used. When the epoxy resin having the above range of epoxy equivalent is used, characteristics of the cured product such as adhesive performance and a glass transition temperature may be effectively maintained. Such an epoxy resin may be one or a mixture of at least two of a cresol novolac epoxy resin, a bisphenol A-type epoxy resin, a bisphenol A-type novolac epoxy resin, a phenol novolac epoxy resin, a tetrafunctional epoxy resin, a biphenyl-type epoxy resin, a triphenol methane-type epoxy resin, an alkyl-modified triphenol methane epoxy resin, a naphthalene-type epoxy resin, a dicyclopentadiene-type epoxy resin, and a dicyclopentadiene modified phenol-type epoxy resin. 
         [0054]    In an exemplary embodiment of the present invention, the second layer may include another component such as the above-described active energy ray-polymerizable compound, a radical initiator, a tackifier, a moisture absorbent, a moisture blocker, a dispersing agent, or a silane compound, which may be the same as or different from that of the first layer, in addition to the above-described resin. In addition, the second layer may include a curable material, a curing agent, or a filler at a suitable range of content according to a desired physical property. 
         [0055]    A sequence of laminating the first and second layers is not particularly limited, and thus the second layer may be formed on the first layer, or the first layer may be formed on the second layer. 
         [0056]    In one example, the pressure-sensitive adhesive film may include a barrier film on one surface of the pressure-sensitive adhesive layer. The barrier film may be formed of any material generally used in the art without limitation. For example, here, the barrier film may include a base layer, an organic undercoating layer, an inorganic deposition layer, and an organic top-coating layer, and the organic top-coating layer may be in contact with the pressure-sensitive adhesive layer. 
         [0057]    The pressure-sensitive adhesive film may have a water vapor transmission rate (WVTR) measured with respect to a thickness direction of the film while being manufactured in a film having a thickness of 10 μm of 50, 40, 30, 20, or 10 g/m 2 ·day or less at 100° F. and a relative humidity of 100%. By controlling a composition or crosslinking condition of a pressure-sensitive adhesive layer including a pressure-sensitive adhesive composition to have such a WVTR, an encapsulation or capsulation structure which can stably protect an element by effectively blocking moisture or oxygen penetrated from an external environment when being applied to the encapsulation or capsulation structure of an organic electronic device may be realized. The lower WVTR, the better moisture barrierability, and therefore the lower limit of the WVTR may be, but is not particularly limited to, 0 g/m 2 ·day. 
         [0058]    In addition, the pressure-sensitive adhesive film may have an excellent light transmittance with respect to a visible-ray region. In one example, the pressure-sensitive adhesive film of the present invention may have a light transmittance of 85% or more with respect to the visible-ray region. For example, the pressure-sensitive adhesive film may have a light transmittance of 85%, 87%, or 90% or more with respect to the visible-ray region. In addition, the pressure-sensitive adhesive film of the present invention may have a low haze with the excellent light transmittance. In one example, the pressure-sensitive adhesive film may have a haze of 3%, 2%, 1%, 0.8%, 0.5%, or 0.3% or less. That is, the pressure-sensitive adhesive composition according to the present invention may realize excellent optical characteristics as well as reliability at high temperature and high humidity by introducing a particular crosslinking system. 
         [0059]    The pressure-sensitive adhesive film may further include a base film or release film (hereinafter, can be referred to as a “first film”), and the pressure-sensitive adhesive layer may be formed on the base or release film. The structure may further include a base or release film formed on the pressure-sensitive adhesive layer (hereinafter, can be referred to as a “second film”). 
         [0060]      FIGS. 1 and 2  are cross-sectional views of exemplary pressure-sensitive adhesive films. 
         [0061]    A pressure-sensitive adhesive film  1 , as shown in  FIG. 1 , may include a pressure-sensitive adhesive layer  11  formed on a base or release film  12 . Another exemplary pressure-sensitive adhesive film  2 , as shown in  FIG. 2 , may further include a base or release film  21  formed on the pressure-sensitive adhesive layer  11 . Although not shown in  FIGS. 1 and 2 , the pressure-sensitive adhesive film may also have the pressure-sensitive adhesive composition without a supporting base such as a base or release film, and therefore have a structure only including a pressure-sensitive adhesive layer formed in a film or sheet maintaining a solid phase or a semi-solid phase at room temperature, or a structure in which a pressure-sensitive adhesive layer is formed on both surfaces of one base or release film. 
         [0062]    A specific type of the first film is not particularly limited. As the first film, for example, a plastic film may be used. The first film may be a polyethyleneterephthalate film, a polytetrafluoroethylene film, a polyethylene film, a polypropylene film, a polybutene film, a polybutadiene film, a vinyl chloride copolymer film, a polyurethane film, an ethylene-vinyl acetate film, an ethylene-propylene copolymer film, an ethylene-ethyl acrylate copolymer film, an ethylene-methyl acrylate copolymer film, or a polyimide film. 
         [0063]    When the first film is a release film, suitable release treatment may be performed on one or both surfaces of such a plastic film. As a releasing agent used for release treatment, an alkyd-based releasing agent, a silicone-based releasing agent, a fluorine-based releasing agent, an fluorinated ester-based releasing agent, a polyolefin-based releasing agent, or a wax-based releasing agent may be used. In consideration of heat resistance, an alkyd-based releasing agent, a silicone-based releasing agent, or a fluorine-based releasing agent among the above examples may be conventionally used, but the present invention is not limited thereto. 
         [0064]    As the first film, for example, a plastic film in which a gas barrier layer is formed on a top or side surface of a base may be used. Such a film may directly constitute, for example, a substrate of an organic electronic device to be used for realizing a flexible element. 
         [0065]    A type of the second film is not particularly limited, either. For example, as the second film, within the category of the first film listed above, one that is the same as or different from the first film may be used. 
         [0066]    A thickness of the first or second film is not particularly limited. In one example, the thickness of the first film may be approximately 50 to 500 or 100 to 200 μm. In such a range, a process of preparing or manufacturing a pressure-sensitive adhesive or an organic electronic device may be effectively automated, and advantageous effects in economic feasibility may be achieved. 
         [0067]    The thickness of the second film is not particularly limited, either. For example, the thickness of the second film may be the same as, or relatively smaller or larger than that of the first film. 
         [0068]    The pressure-sensitive adhesive layer of the pressure-sensitive adhesive film includes the pressure-sensitive adhesive composition, and is formed in a film or sheet. In the pressure-sensitive adhesive layer, the pressure-sensitive adhesive composition may be in a crosslinked or non-crosslinked state. The pressure-sensitive adhesive layer may be in a solid or semi-solid phase at room temperature. Such a pressure-sensitive adhesive resin may form a crosslinked structure in an encapsulation structure of an organic electronic device, which will be described below. 
         [0069]    A thickness of the pressure-sensitive adhesive layer is not particularly limited, and in consideration of its uses, may be suitably selected. For example, the pressure-sensitive adhesive layer may have a thickness of approximately 5 to 200 μm. The thickness of the pressure-sensitive adhesive layer may be controlled in consideration of, for example, embeddability when being used as an encapsulant of an organic electronic element and processability or economic feasibility. 
         [0070]    In still another aspect, the present invention provides a method of manufacturing a pressure-sensitive adhesive film. The exemplary pressure-sensitive adhesive film may be manufactured by plasticizing the pressure-sensitive adhesive composition in a film or sheet. 
         [0071]    In one example, the method may include applying a coating solution including the pressure-sensitive adhesive composition on a base or release film in a sheet or film, and drying the applied coating solution. The method may further include adhering an additional base or release film to the dried coating solution. 
         [0072]    The coating solution including the pressure-sensitive adhesive composition may be prepared by, for example, dissolving or dispersing components of each pressure-sensitive adhesive composition described above in a suitable solvent. In one example, the pressure-sensitive adhesive composition may be prepared by dissolving or dispersing the moisture absorbent, blocker, or filler in a solvent when needed, grinding the resulting product, and mixing the moisture absorbent, blocker, or filler with an encapsulating resin. 
         [0073]    A type of a solvent used in preparation of the coating solution is not particularly limited. However, when time to dry the solvent is too long, or it is necessary to dry the solvent at a high temperature, there may have some problems in workability or durability of a pressure-sensitive adhesive film. For this reason, a solvent having a volatile temperature of 150° C. or less may be used. In consideration of film moldability, a small amount of the solvent having the above range or more of the volatile temperature may be mixed to be used. The solvent may be, but is not limited to, one or at least two of methylethylketone (MEK), acetone, toluene, dimethyl formamide (DMF), methyl cellosolve (MCS), tetrahydrofuran (THF), xylene, and N-methylpyrrolidone (NMP). 
         [0074]    A method of applying the coating solution to the base or release film may be, but is not particularly limited to, a known coating method such as knife coating, roll coating, spray coating, gravure coating, curtain coating, comma coating, or lip coating. 
         [0075]    The applied coating solution may be dried to volatilize the solvent, thereby forming a pressure-sensitive adhesive layer. The drying may be performed, for example, at 70 to 150° C. for 1 to 10 minutes. The drying condition may be changed in consideration of a type of the used solvent. 
         [0076]    After drying, an additional base or release film may be formed on the pressure-sensitive adhesive layer. 
         [0077]    In yet another aspect, the present invention provides a product for encapsulating an organic electronic device. The product for encapsulating an organic electronic device may include a substrate; an organic electronic element formed on the substrate; and a pressure-sensitive adhesive film encapsulating an entire surface, for example, both top and side surfaces of the organic electronic element. The pressure-sensitive adhesive film may include a pressure-sensitive adhesive layer containing a pressure-sensitive adhesive composition in a crosslinked state. The product for encapsulating an organic electronic device may further include a cover substrate formed on a top surface of the pressure-sensitive adhesive layer. 
         [0078]    Here, the organic electronic element may be, for example, an organic light emitting element. 
         [0079]    In yet another aspect, the present invention provides a method of manufacturing an organic electronic device. The product for encapsulating an organic electronic device may be manufactured using, for example, the pressure-sensitive adhesive film. 
         [0080]    The pressure-sensitive adhesive layer may be formed as an encapsulating layer for a structure exhibiting excellent moisture barrier property and optical property in the organic electronic device, efficiently fixing and supporting the substrate and a cover substrate. 
         [0081]    In addition, the pressure-sensitive adhesive layer may exhibit excellent transparency, and may be stable regardless of a type of the organic electronic device, for example, a top-emissive or bottom-emissive organic electronic device. 
         [0082]    The term “encapsulating layer” used herein may refer to a pressure-sensitive adhesive layer covering both top and side surfaces of the organic electronic element. 
         [0083]      FIG. 3  is a schematic diagram of an exemplary organic electronic device in which an organic electronic element is an organic light emitting element. 
         [0084]    To manufacture the organic electronic device, for example, applying the above-described pressure-sensitive adhesive film to the substrate on which the organic electronic element is formed in order to cover the organic electronic element; and curing the pressure-sensitive adhesive film may be included. 
         [0085]    The term “curing” used herein may refer to preparing a pressure-sensitive adhesive by forming the pressure-sensitive adhesive composition of the present invention to have a crosslinking structure through heating or UV irradiation. 
         [0086]    Particularly, an organic electronic element  32  may be formed by forming a transparent electrode on a glass or polymer film  31  used as a substrate by a method such as vacuum deposition or sputtering, forming layers of emissive organic materials, composed of, for example, a hole transport layer, an emitting layer, and an electron transport layer on the transparent electrode, and further forming an electrode layer thereon. Subsequently, a pressure-sensitive adhesive layer of the pressure-sensitive adhesive film is disposed to cover an entire surface of the organic electronic element  32  of the substrate  31  which has gone through the above-described process. 
         [0087]    Subsequently, an encapsulating layer may be formed by compressing the pressure-sensitive adhesive layer on the organic electronic element using a laminator while being heated to provide mobility, and crosslinking a resin in the pressure-sensitive adhesive layer. 
         [0088]    In one example, a pressure-sensitive adhesive layer  33  disposed to cover an entire surface of the organic electronic element  32  may be previously transferred to a cover substrate  34  such as a glass or a polymer film. The transfer of the pressure-sensitive adhesive layer to the cover substrate  34  may be performed using a vacuum press or vacuum laminator while being heated after a first or second film is peeled off from the pressure-sensitive adhesive film and the pressure-sensitive adhesive layer is in contact with the cover substrate  34 . When a pressure-sensitive adhesive includes a heat-curable pressure-sensitive adhesive resin and a curing reaction is excessively performed during the process, a cohesive strength or pressure-sensitive adhesive strength of the encapsulating layer is probably reduced. Therefore, a process temperature may be controlled to approximately 100° C. or less, and a process time may be controlled within 5 minutes. 
         [0089]    An encapsulating layer may be formed by disposing the cover substrate  34  to which the pressure-sensitive adhesive layer is transferred on the organic electronic element  32 , and performing the heat compression process. 
         [0090]    An encapsulating layer may be formed by curing the pressure-sensitive adhesive layer  33 . The curing process may be performed in a suitable heating chamber or UV chamber, for example, according to a method of curing a curable pressure-sensitive adhesive resin. A heating condition or a condition of irradiating an active energy ray may be suitably selected in consideration of stability of the organic electronic element and curability of the pressure-sensitive adhesive resin, and to increase compression efficiency, autoclaving may also be performed with application of heat and pressure. 
         [0091]    Here, one example of the method of manufacturing an organic electronic device is described, but the organic electronic device may be manufactured by a different method. For example, the manufacture of the device is performed by the above-described method, but a sequence or condition of the process may be changed. For example, the encapsulating layer may be formed by previously transferring the pressure-sensitive adhesive layer to an orgnaic electronic element on the substrate  31 , not to the cover substrate  34 , and performing a curing process after the cover substrate  34  is laminated. 
       Effects 
       [0092]    The present invention can provide a pressure-sensitive adhesive composition that can effectively block moisture or oxygen penetrated into an organic electronic device from an external environment, and exhibit reliability under harsh conditions such as high temperature and high humidity and excellent optical characteristics, and a pressure-sensitive adhesive film including the same. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0093]      FIGS. 1 and 2  are cross-sectional views of pressure-sensitive adhesive films according to exemplary embodiments of the present invention; and 
           [0094]      FIG. 3  is a cross-sectional view of a product for encapsulating an organic electronic device according to an exemplary embodiment of the present invention. 
       
    
    
     DESCRIPTION OF REFERENCE NUMERALS 
       [0000]    
       
         
           
               1 ,  2 : pressure-sensitive adhesive film 
               11 : pressure-sensitive adhesive layer 
               12 : first film 
               21 : second film 
               3 : organic electronic device 
               31 : substrate 
               32 : organic electronic element 
               33 : pressure-sensitive adhesive layer or encapsulating layer 
               34 : cover substrate 
           
         
       
     
       DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENTS 
       [0104]    Hereinafter, the present invention will be described in detail with reference to Examples and Comparative Examples, but the scope of the present invention is not limited to the following examples. 
       Example 1 
       [0105]    A coating solution was prepared by adding 90 g of a butyl rubber (Br268, EXXON) as an encapsulating resin, 10 g of a hydrogenated DCPD-based tackifier (SU-90, Kolon) as a tackifier, 15 g of tricyclodecane dimethanol diacrylate (M262, Miwon) as an active energy ray-polymerizable compound, 3 g of 3-methacryloxypropyl trimethoxysilane (Sigma Aldrich) as a silane compound, and 0.5 g of 2,2-dimethoxy-1,2-diphenylethane-1-one (Irgacure651, Ciba) as a radical initiator, and diluting the mixture in toluene to have a solid content of approximately 20 wt %. 
         [0106]    The prepared solution was coated on a released surface of release PET, and dried in an oven at 100° C. for 15 minutes, thereby manufacturing a pressure-sensitive adhesive film including a pressure-sensitive adhesive layer having a thickness of 20 μm. Physical properties of the sample were measured after a UV ray was irradiated at 2 J/cm 2  on the manufactured film. 
       Example 2 
       [0107]    A pressure-sensitive adhesive film was manufactured by the same method as described in Example 1, except that 10 g of 3-methacryloxypropyl trimethoxysilane (Sigma Aldrich) was used. 
       Comparative Example 1 
       [0108]    A pressure-sensitive adhesive film was manufactured by the same method as described in Example 1, except that 3-methacryloxypropyl trimethoxysilane (0 g) was not used. 
       Comparative Example 2 
       [0109]    A pressure-sensitive adhesive film was manufactured by the same method as described in Example 1, except that 90 g of butyl acrylate and 10 g of acrylic acid were used instead of the butyl rubber and hydrogenated DCPD-based tackifier used in Example 1. 
         [0110]    Hereinafter, physical properties were evaluated by the following methods in the Examples and Comparative Examples. 
         [0111]    1. Measurement of Pressure-Sensitive Adhesive Strength 
         [0112]    A width of the pressure-sensitive adhesive film manufactured in Example or Comparative Example was set to 1 inch, and the film was maintained at 25° C. and a relative humidity of 50% for 1 hour, and then a peeling strength (peeling rate: 5 mm/sec, peeling angle: 180 degrees) of a pressure-sensitive adhesive layer of the pressure-sensitive adhesive film with respect to an OLED panel (a glass on which silicon nitride is inorganic-deposited) was measured. 
         [0113]    A width of the pressure-sensitive adhesive film manufactured in Example or Comparative Example was set to 1 inch, and the film was maintained at 85° C. and a relative humidity of 85% for 1 hour, and then a peeling strength (peeling rate: 5 mm/sec, peeling angle: 180 degrees) of a pressure-sensitive adhesive layer of the pressure-sensitive adhesive film with respect to an OLED panel (a glass on which silicon nitride is inorganic-deposited) was measured. 
         [0114]    The measurement was performed at constant temperature and constant humidity, and the peeling strength was measured using a texture analyzer according to ASTM3330. 
         [0115]    2. Water Vapor Transmission Rate (WVTR) 
         [0116]    A resin composition was prepared by dissolving the resin used in Example or Comparative Example in a solvent. The resin composition was applied to a base film having a thickness of 38 μm (release polyester film, RS-21G, SKC). Subsequently, the composition was dried at 110° C. for 10 minutes, thereby forming a film-type layer having a thickness of 100 μm. Afterward, the base film was peeled, and then a WVTR of the film-type layer was measured in a thickness direction, while the layer was maintained at 100° F. and a relative humidity of 100%. The WVTR was measured according to a specification of ASTM F1249. 
         [0117]    3. Measurement of Haze 
         [0118]    A haze of the pressure-sensitive adhesive film manufactured as described above was measured using a haze meter according to JIS K7105 standard test method. 
         [0119]    4. Measurement of Release Peeling Strength 
         [0120]    A width of the pressure-sensitive adhesive film manufactured in Example or Comparative Example was set to 1 inch, and the film was maintained at 25° C. and a relative humidity of 50% for 1 week, and then a peeling strength (peeling rate: 5 mm/sec, peeling angle: 180 degrees) of the pressure-sensitive adhesive film with respect to release PET was measured. 
         [0121]    The measurement was performed at constant temperature and constant humidity, and the peeling strength was measured using a texture analyzer according to ASTM3330. 
         [0000]    
       
         
               
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                 TABLE 1 
               
               
                   
               
               
                   
                 25° C.  
                 85° C.  
                   
                   
                   
               
               
                   
                 Pressure- 
                 Pressure- 
                   
                   
                   
               
               
                   
                 sensitive 
                 sensitive 
                   
                 Release 
                   
               
               
                   
                 adhesive 
                 adhesive  
                   
                 peeling 
                   
               
               
                   
                 strength 
                 strength 
                 WVTR 
                 strength  
                 Haze 
               
               
                   
                 (gf/inch) 
                 (gf/inch) 
                 (g/m 2  · day) 
                 (gf/inch) 
                 (%) 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Example 1 
                 2108.6 
                 3021.0 
                 3 
                 12 
                 1.2 
               
               
                 Example 2 
                 2200 
                 3021.0 
                 3 
                 55 
                 3.2 
               
               
                 Comparative 
                 1816 
                 1075 
                 3 
                 7 
                 1.2 
               
               
                 Example 1 
                   
                   
                   
                   
                   
               
               
                 Comparative 
                 1980 
                 500 
                 1200 
                 10 
                 1.0 
               
               
                 Example 2 
                   
                   
                   
                   
                   
               
               
                   
               
             
          
         
       
     
         [0122]    As shown in Table 1, Example 1 according to the present invention can realize excellent durability and reliability under harsh conditions such as high temperature and high humidity by preventing a decrease in an interface pres sure-sensitive adhesive strength due to moisture penetration at high temperature and high humidity. On the other hand, Comparative Example 1 showed a decrease in a pressure-sensitive adhesive strength at a high temperature, and Comparative Example 3 showed a decrease in an interface pressure-sensitive adhesive strength due to moisture penetration.