Abstract:
Methods, processes, apparatus, devices, kits and systems for crystallizing liquid to form slush inside of supercooled to below 32 F closed beverage bottles or cans, beverages in fountain dispensers, desserts, and food items by transmitting ultrasonic signals in short time spans, while allowing for optional illuminating the effects when the supercooled liquid is crystallized into slush.

Description:
CROSS REFERENCE TO RELATED APPLICATIONS 
       [0001]    This application is a Continuation-In-Part of U.S. patent application Ser. No. 14/298,117 filed Jun. 6, 2014, which claims the benefit of priority to U.S. Provisional Application Ser. No. 61/966,106 filed Feb. 18, 2014, and this application claims the benefit of priority to U.S. Provisional Patent Application Ser. No. 61/999,812 filed Aug. 7, 2014 and U.S. Provisional Patent Application Ser. No. 62/176,031 filed Feb. 9, 2015. The entire disclosure of each of the applications listed in this paragraph are incorporated herein by specific reference thereto. 
     
    
     FIELD OF INVENTION 
       [0002]    This invention relates to supercooled beverages being instantly transformed into from a liquid state to ice-crystal ‘slush’ beverages inside sealed containers, beverages in fountain dispensers, beverage merchandisers and vending machines, desserts, and food items, and in particular to methods, processes, apparatus, devices, kits and systems for crystallizing supercooled liquid to form slush inside of supercooled to below 32 F, such as between approximately 15 F to approximately 26 F, in beverage bottles or cans, beverages in fountain dispensers, desserts, and foods by transmitting ultrasonic signals in short time spans, with or without illuminating the crystallization effects. 
       BACKGROUND AND PRIOR ART 
       [0003]    Bagged ice has been popular to be used in portable coolers to chill canned and bottled beverages, where the bags generally comprise loose ice cubes, chips, that are frozen fresh water. The user places the bag(s) in coolers and adds canned and/or bottled beverages, to the coolers of packaged-ice. 
         [0004]    Due to the melting properties of fresh-water ice, canned and bottled beverages placed in ice cannot be chilled below 32 degrees Fahrenheit for any significant length of time, which is the known general freezing point. 
         [0005]    Ice-melters such as salt have been known to be used to lower the melting point of fresh-water ice. Sprinkling loose salt on packed-ice in a cooler to produce lower temperatures for canned and bottled beverages placed inside. Sprinkling salt has been tried with beer, since beer will not freeze at 32 degrees due to its alcohol content. However, sprinkling loose salt has problems. 
         [0006]    Due to the uneven spread of salt on ice, it is impossible to know or control the precise resulting temperate below 32 degrees on various ice-cubes in the cooler obtained by sprinkling of salt. Salt sprinkling has resulted in some beverages “freezing hard” while others remain liquid and sometimes at above 32 degrees. The spreading of salt or other ice-melters on packaged-ice in a cooler to obtain temperatures less than 32 degrees is impractical to know and control precisely the resulting temperature of ice-cubes in a cooler environment 
         [0007]    Some devices rely on traditional refrigeration and/or placing ice inside the beverage to obtain cold temperatures. At home devices such as SODASTREAM® by Soda-Club (CO2) Atlantic GmbH, and KEURIG COLD™ by Keurig Green Mountain Inc. rely on basic methods for cooling, and each has drawbacks. 
         [0008]    Traditional refrigeration offers a relatively slow and inefficient method of cooling, requiring hours to obtain approximately 40 F drinking temperatures. 
         [0009]    Ice inside of liquid is also popular to cool beverages. However, placing ice inside a liquid has the drawbacks of: 1) watered-down flavoring, 2) introducing impurities, 3) causing premature de-carbonation of carbonated beverages. 
         [0010]    Non-traditional method of cooling cans/bottles rapidly by spinning on their axis while the can/bottle is in contact with ice or ‘ice-cold’ liquid (usually fresh water at or near approximately 32 deg-F) was also attempted. U.S. Pat. No. 5,505,054 to Loibl et al. describes beverage cooling that attempts to reduce beverage cooling times from hours to close to a minute without putting ice inside. 
         [0011]    SPINCHILL™, www.spinchill.com use portable type drills with a suction cup to attach to a canned beverage with ‘cooling times’ of 60 seconds or less for canned beverages spun at roughly 450 rpm in a standard ice-cooler containing ice and/or iced-water, though the term ‘cooling’ is used loosely and generally describes a beverage temperature between 40-50 F or so. 
         [0012]    Some non-traditional beverage cooling devices generally spin cans/bottles at a constant rpm (revolutions per minute) rate in one-direction only, and expose the can/bottle again and again to ice or cold liquid to rapidly cool the beverage. 
         [0013]    These devices seek to minimize agitation inside the canned or bottled beverage by spinning them at relatively mild rates of 350-500 rpm which, they believe, is optimal for rapid cooling and prevents undesirable foaming of carbonated beverages and beer. 
         [0014]    These devices require up to several minutes of spinning in a cooling medium to obtain Ice-cold′ drinking temperatures, and do not automatically indicate when a beverage has reached optimal or lowest drinking temperature. 
         [0015]    Alcoholic and non-alcoholic bottled and canned beverages of all varieties, including bottled water, has been known to be super cooled below 32 deg-F while remaining liquid for short periods of time. What is not generally known is how to cool these beverages rapidly to precise super cooled temperatures which allow for enjoyable ‘slush-on-demand’ drinking experiences while preventing unwanted or premature freezing which results in undesirable effects such as 1) premature foaming or release of carbonation in an undesirable way, and 2) hard frozen or ‘chunky’ frozen beverages which are difficult to consume. 
         [0016]    Prior art does not describe supercooling beverages below 32-degrees and/or below their freezing point while keeping a liquid state allowing previously impossible beverage options, such as creating instant milkshakes from super cooled milk beverages and creating instant smoothies from super cooled fruit and vegetable juices without the need to blend-in chopped-ice into the smoothie. 
         [0017]    Supercooled beverages are increasingly popular due to the ability to create instant “slushy drinks” by nucleating the supercooled beverage and causing instant soft ice-crystal formation throughout the beverage. Traditional methods for nucleating supercooled liquid beverages involve 1) disturbing the beverage container via shaking, slamming, or hitting the beverage container with enough force to cause ice-crystals to begin forming, or 2) opening the beverage container and exposing the liquid to air and then disturbing the liquid in hopes of creating a nucleation site for ice crystals to being forming. Another method for nucleating supercooled beverages involves opening the beverage and pouring the supercooled liquid into a cup or glass containing seed crystals of ice, which starts the nucleation process and creates an instant slushy drink in a glass. Of all of these methods, none of them can reliably and consistently cause nucleation-on-demand for all varieties of supercooled beverages in sealed containers without the containers being opened. 
         [0018]    For example, if a supercooled carbonated beverage is purchased from a vending machine or merchandiser, there are limited options to start the nucleation process. Shaking or slamming may cause the desired ice-crystal nucleation of the beverage, but can also cause unwanted foaming due to the carbonation within the beverage. So choices are limited to exposing it to air (opening the beverage) which has a high probability of failure in inducing ice-crystal nucleation or pouring the liquid into a glass containing ice crystals which may be undesirable or impractical in many point of purchase situations. 
         [0019]    Furthermore, due to the temperatures required for nucleation to occur, users have roughly 90-120 seconds to begin the ice-crystal nucleation process once the beverage is removed from the supercooled refrigerated environment of a typical home freezer or that of a specialized merchandiser or vending machine, or the supercooled beverage may become too warm for ice-crystal nucleation to occur. Ideally, the supercooled beverage should either be nucleated before being dispensed by the vending machine, or by the consumer immediately upon removing the beverage from the specialized supercooling merchandiser or vending machine without having to open the bottle/can and with no unwanted foaming occurring when opening the container. 
         [0020]    In addition, the ice-crystal nucleation process can be spectacular and exciting to watch inside of a see-through bottle, and the ability to illuminate or back-light the liquid during ice-crystal nucleation can add significant visual excitement for the consumer at the point of purchase as well as a convenient way to verify that the ice-crystal nucleation or ‘slushing’ process was successful. 
         [0021]    Thus, the need exists for solutions to the above problems with the prior art. 
       SUMMARY OF THE INVENTION 
       [0022]    A primary objective of the present invention is to provide methods, processes, apparatus, devices, kits and systems for crystallizing liquid to form slush inside of supercooled to below 32 F beverage bottles and cans, beverages in fountain dispensers, desserts, and food items by transmitting ultrasonic frequencies with or without illuminating the rapid crystallization effects. 
         [0023]    A secondary objective of the present invention is to provide methods, processes, apparatus, devices, kits and systems for crystallizing liquid to form slush inside of supercooled to below 32 F closed beverage bottles or cans with nucleation-on-demand in without the need to open the beverage bottles or cans. 
         [0024]    A third objective of the present invention is to provide methods, processes, apparatus, devices, kits and systems for crystallizing liquid to form slush inside of supercooled to below 32 F in the closed beverage bottles or cans without causing unwanted foaming of carbonated beverages upon opening the bottles of cans. 
         [0025]    A fourth objective of the present invention is to provide methods, processes, apparatus, devices, kits and systems for crystallizing liquid to form slush inside of supercooled to below 32 F closed beverage bottles or cans, as an integral part of a vending machine or as a stand-alone electric or battery operated nucleation device to allow store clerks, restaurant servers, or consumers to nucleate sealed beverage bottles or cans without opening the bottles or cans. 
         [0026]    A fifth objective of the present invention is to provide methods, processes, apparatus, devices, kits and systems for crystallizing liquid to form slush inside of supercooled to below 32 F sealed or closed beverage bottles, by illuminating the ice-crystal nucleation on-demand in a closed bottle by providing backlighting and/or side-lighting and/or front-lighting and/or top-lighting and/or bottom lighting via LED&#39;s, florescent, neon, or other light sources and types while the beverage is in the bottle. 
         [0027]    The invention can be used with closed beverage bottles, that include glass bottles and plastic bottles, as well as canned beverages, such as those in aluminum cans, and the like. It can also be used with beverages or cold liquids stored in sealed packages of cardboard, waxed paper, or of other construction of sealed and unsealed beverage containers. 
         [0028]    A preferred embodiment uses an ultrasonic transducer (28 khz, 40 khz, 60 khz, or higher or lower khz value) to produce ultrasonic waves though a liquid medium which may be in direct contact with the beverage container or in direct contact with a thin membrane which is subsequently in direct contact with the beverage container. 
         [0029]    An electronic timer allows for short-duration burst(s) of ultrasonic waves produced by the ultrasonic transducer (between approximately one-tenth of a second and approximately two seconds or more or less) when a firing switch is activated. The firing switch can either an automatic detector that senses the presence of a beverage container (and possibly the size and type of beverage) or a manually operated push-button switch to fire the ultrasonic transducer. 
         [0030]    An ultrasonic pulse within the liquid medium that is in direct or indirect contact with the beverage container will cause cavitations within the molecules of the supercooled beverage which result in small areas of ice-crystal nucleation within the beverage which will spread throughout the supercooled beverage due to the properties of molecular structure of supercooled liquids, resulting in the subsequent “slushing” of the entire supercooled beverage within a relatively short period of time of between 2 and 60 seconds depending on the type of beverage and it&#39;s ingredients (non-sugared beverages generally have quicker ‘slushing times’ than heavily sugared beverages). By carefully controlling the timing (and number) of the ultrasonic pulse or pulses, a carbonated beverage can be nucleated for ice-crystal formation without causing unwanted foaming (carbonation nucleation) of the beverage upon opening. 
         [0031]    The invention can also be designed to cause ice-crystal nucleation of supercooled beverages from fountain drink or other free-flowing beverage dispensing mechanisms (not shown) via direct or indirect contact between the ultrasonic transducer and the free-flowing supercooled liquid beverage. 
         [0032]    Additional embodiments allow for enhancing the visible beauty of ice-crystal nucleation-on-demand in a sealed container beverage by providing a backlighting and/or side-lighting and/or front-lighting and/or top-lighting and/or bottom lighting via LEDs (light emitting diodes), florescent, neon, or other light sources and types while the beverage is undergoing ‘slushing’. 
         [0033]    Lights can be switched on manually or automatically with a pressure switch or other switch mounted such to detect the presence of a bottled beverage when placed in contact with the ultrasonic nucleator device. 
         [0034]    An optional rotation device, can rotate the beverage container for a short period of time (from approximately 0.2 sec to approximately 20 seconds, or more or less) prior to the ultrasonic nucleation pulse, which will provide rotational motion of the ice-crystal formation during nucleation. The device can be equipped with multi-color lights, LED&#39;s, or flashing or ‘moving’ LED&#39;s or other light sources. 
         [0035]    Backlighting and/or other lighting can enhance the visibility of ice-crystal formation and subsequent ‘slushing’ of the entire bottled beverage and the reflection and diffraction of light amongst the crystals as they form in the beverage container. Once the beverage container is removed from the nucleation device, the lighting can be switched-off manually or automatically via detection switch(s) or a pressure switch. 
         [0036]    Additionally, a large arcade style button can be optionally incorporated to allow the user to press and begin the rotation process and the ultrasonic pulse for ice-crystal nucleation to occur. 
         [0037]    In another embodiment, Backlighting, side-lighting or other lighting can be part of the nucleation device or separate from the device. Additionally, the optional rotation mechanism can be a part of the nucleation device or separate from it. Additionally, an arcade style activation button can be part of the nucleation device or separate. 
         [0038]    All components of the invention can be constructed as part of the larger assembly of a supercooling beverage merchandiser, supercooling vending machine, or other supercooling capable refrigerated device, or can be made separate and free-standing either individually or collectively. 
         [0039]    Further objects and advantages of this invention will be apparent from the following detailed description of the presently preferred embodiments which are illustrated schematically in the accompanying drawings. 
     
    
     
       BRIEF DESCRIPTION OF THE FIGURES 
         [0040]      FIG. 1  is an upper front left perspective view of a first embodiment of a device for crystallizing liquid to form slush inside chilled bottles with an illumination source. 
           [0041]      FIG. 2  is another perspective view of the device of  FIG. 1  with a bottle mounted on the device. 
           [0042]      FIG. 3  is an exploded view of the device of  FIG. 1 . 
           [0043]      FIG. 4  is another perspective view of the device of  FIG. 1  with optional rotation capability. 
           [0044]      FIG. 5  is a schematic of the electronic components for the device of  FIG. 1   
           [0045]      FIG. 6  is an upper rear right perspective view of a second embodiment device for crystallizing liquid to form slush inside chilled bottles with no illumination source. 
           [0046]      FIG. 7  is an upper left perspective view of the device of  FIG. 1  attached to the side of refrigerated beverage merchandiser or other cooling device. 
           [0047]      FIG. 8  is an upper front left perspective view of a third embodiment device for crystallizing liquid to form slush inside chilled bottles with an illumination source. 
           [0048]      FIG. 9  is another perspective view of the device for bottles of  FIG. 8  with a bottle mounted on the device. 
           [0049]      FIG. 10  is an exploded view of the device of  FIG. 9 . 
           [0050]      FIG. 11  is another perspective view of the device of  FIG. 9  with bowl assembly removed for cleaning. 
           [0051]      FIG. 12  is another perspective view of another embodiment of a device for crystallizing liquid to form slush inside chilled bottles using a side touch ‘wand’ device attached to an ultrasonic transducer without the need for a bowl or base to set the bottle on. 
           [0052]      FIG. 13  is an exploded view of the device of  FIG. 12 . 
       
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
       [0053]    Before explaining the disclosed embodiments of the present invention in detail it is to be understood that the invention is not limited in its applications to the details of the particular arrangements shown since the invention is capable of other embodiments. Also, the terminology used herein is for the purpose of description and not of limitation. 
         [0054]    In the Summary above and in the Detailed Description of Preferred Embodiments and in the accompanying drawings, reference is made to particular features (including method steps) of the invention. It is to be understood that the disclosure of the invention in this specification does not include all possible combinations of such particular features. For example, where a particular feature is disclosed in the context of a particular aspect or embodiment of the invention, that feature can also be used, to the extent possible, in combination with and/or in the context of other particular aspects and embodiments of the invention, and in the invention generally. 
         [0055]    In this section, some embodiments of the invention will be described more fully with reference to the accompanying drawings, in which preferred embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will convey the scope of the invention to those skilled in the art. Like numbers refer to like elements throughout, and prime notation is used to indicate similar elements in alternative embodiments. 
         [0056]    A list of components will now be described.
     10  device for crystallizing liquid to form slush inside of supercooled to below 32 F closed beverage bottles or cans with illumination source     20  stand (base)     30  ultrasonic transducer     35  Top cover for base     45  neck cover for ultrasonic transducer     50  bowl for bottle     60  thin membrane transmission membrane over transmission medium (liquid, water, gel)     70  fill nozzle     80  power source such as power cord with plug to 120 volt power supply or internal batteries     85  mounting bridge and force sensitive resistor (pressure switch)     90  push button switch     100  schematic of electronic components     101  pressure switch ( 85 )     102  Arduino or IC (integrated circuit) smart board electronics     103  Ready LED to indicate button may be pushed     104  D/C (direct current) relay     105  beverage bottle illumination source ( 220 )     106  push button switch(s) ( 90 )     107  solid state relay     108  40 khz ultrasonic transducer power electronics board ( 40 )     109  ultrasonic transducer ( 30 )     110  sound output electronics and speaker     111  power source     205  closed or sealed beverage bottle or container     210  back wall for illumination source     215  start of nucleation (crystallization) in liquid inside     220  illumination source (LEDs)     240  side mount for refrigerated beverage merchandiser or cooler     250  flanges for attaching device base to side mount     260  refrigerated beverage merchandiser or other cooling device     310  second embodiment device with illuminator source     315  bottled container     320  stand     330  illumination source     340  removable bowl/bowl assembly     345  sealed transmission medium     347  wafer style ultrasonic transducer     348  bowl base     349  contacts for transducer     350  touch sensitive push button to fire ultrasonic transducer     360  ready indicator LED     370  touch sensitive push button to power-on the system     380  power-on indicator LED     400  Wand embodiment     410  ultrasonic transducer     420  ultrasonic power and control electronics board     425  ultrasonic transducer holder and force sensitive resistor (pressure switch)     430  bottle design plate with back lighting LED&#39;s     440  wand attachment     450  watertight transmission medium (water or gel)     460  mounting box   
 
         [0108]    The invention is to be used with beverage containers, such as bottles or cans whose contents have be supercooled to below at least approximately 32 F, such as to between approximately 15 F to approximately 26 F. Such techniques for reaching these temperatures has been described, and shown in parent patent applications to the same inventor in U.S. patent application Ser. No. 14/298,117 filed Jun. 6, 2014, which claims the benefit of priority to U.S. Provisional Application Ser. No. 61/966,106 filed Feb. 18, 2014, which are incorporated by reference in its&#39; entirety. 
         [0109]    Other techniques for supercooling the beverage containers to these temperatures are also shown and described in additional parent patent applications to the same inventor, which include U.S. patent application Ser. No. 14/163,063 filed Jan. 24, 2014, which claims the benefit of U.S. Provisional Patent Application Ser. No. 61/849,412 filed Jan. 28, 2013, which are also incorporated by reference in their entirety. 
         [0110]    The invention takes these supercooled beverage containers and activates an ice-crystallization of the liquid inside to turn the liquid into a slush with the container remaining sealed if desired. 
         [0111]      FIG. 1  is an upper front left perspective view of a first embodiment of a device  10  for crystallizing liquid to form slush inside chilled bottles with an illumination source  220 .  FIG. 2  is another perspective view of the device  10  of  FIG. 1  with a bottle mounted  205  on the device  10 . 
         [0112]      FIG. 3  is an exploded view of the device  10  of  FIG. 1 . 
         [0113]      FIG. 4  is another perspective view of the device  10  of  FIG. 1  with optional rotation capability. 
         [0114]      FIG. 5  is a schematic of the electronic components  100  for the device  10  of  FIG. 1 . 
         [0115]    Referring to  FIGS. 1 ,  3  and  5 , a device  10  for crystallizing liquid to form slush inside of a supercooled to at least below approximately 30 F closed beverage bottles or cans, can include a stand  20  which is a small base, such as a rectangular box or cube, having a housing formed from plastic or metal, for housing electronic components  100  inside. In front of the base  20  can be an activation switch  90  such as a large push button switch, and the like. 
         [0116]    The stand  20  with base can be of approximate size of approximately 4 inches wide by approximately 4 inches tall by approximately 5 inches deep or bigger or smaller in any dimension but generally of size which can conveniently be moved or placed on a taller stand or apparatus to bring the bottle viewing area and LED&#39;s  220  to eye level for convenient viewing of the ice-crystal nucleation. 
         [0117]    On top of the base  20  can be a removable or non-removable bowl or plate  50 , such as a cylindrical dish made of various materials such as stainless steel, UHMW, plastics or other alloys or materials which holds an amount of water or other liquid or ultrasonic-transmitting gel of volume approximately ½ oz to approximately 4 oz. 
         [0118]    The liquid water, substance or ultrasonic transmitting gel can be in direct or indirect contact with the ultrasonic transducer, bowl, and a beverage bottle which may be placed in the bowl. The purpose of the liquid water, liquid substance or ultrasonic transmitting gel is to uniformly transmit and/or amplify the ultrasonic frequency vibrations from the ultrasonic transducer and/or bowl or plate to the beverage bottle or container placed on the apparatus. 
         [0119]    A water-tight thin membrane or cap  60  that allows for and/or amplifies the transmission of ultrasonic frequencies can be used to prevent the beverage bottles or containers placed in the apparatus from making direct contact with the liquid or gel ultrasonic transmission medium. 
         [0120]    An example of a liquid ultrasonic transmission medium can include a liquid or a gel. The liquid can include but is not limited to be tap water or sterilized water with preservatives to prevent mold or bacterial growth or water with added substances to enhance ultrasonic frequency transmission. An example of a gel medium can include but is not limited to be a pharmaceutical ultrasonic gel pad used widely in the medical industry 
         [0121]    The water-tight thin membrane or cap can be made of flexible plastic, vinyl, or other material generally capable of making adequate surface contact area with the beverage bottle placed on the apparatus to allow for transmission of the ultrasonic frequency vibrations into the liquid beverage. The thin membrane or cap can be puncture resistant. 
         [0122]    If a liquid transmission medium inside the bowl  50  can be used along with a membrane or cap  60 , it can be filled and topped off via a fill nozzle  70 . 
         [0123]    If a gel transmission medium is used along with a membrane or cap  60 , the membrane or cap can be removed in order to insert a gel pad. If a liquid or gel transmission medium is used without a membrane or cap, the liquid or gel can be poured or placed in the bowl or on the plate. 
         [0124]    Beneath the membrane, medium, bowl or plate is an ultrasonic transducer  30 . An example of the ultrasonic transducer can include but is not limited to a 100 W 40 khz Piezoelectric ultrasonic cleaning transducer as used in ultrasonic cleaning tanks. See for example, U.S. Pat. No. 4,979,994 to Dussault et al. and U.S. Patent Application Publications: 2004/0112413 to Brunner et al.; and 2006/0191086 to Mourad et al., which show piezo transducers with or without ultrasonic drivers, which are incorporated by reference in their entirety. 
         [0125]    The base cover  35  and neck  45  provide protection to the ultrasonic transducer and electronics contained in the base. The protection is from dust, debris, and liquid that might be spilled from the bowl or onto the device from the top. The base cover  35  and neck  45  can be angled, ramped or slanted in order to repel liquid in case of beverage spillage, rain, or other liquid spilling on the device. The base cover and neck can also contain grooves or drainage structures to prevent liquid entering the electronics area of the base. A waterproof seal (not shown) can be built-in to the base cover  35  and neck  45  to protect the electronics from moisture. 
         [0126]    For outdoor use all external surfaces can be treated with waterproof sealant coatings and UV (ultra-violet) protecting coatings to prevent discoloration or damage from exposure to the sun or other sources of UV radiation. 
         [0127]    Stand (base)  20  that houses internal components can be waterproofed or sealed by rubber gaskets and the like to prevent water intrusion or damage from the environment. 
         [0128]    The power supply 80 for the device  10  can be by a cord with plug to a  110 -120 volt power source or a 220 v power source, or by batteries, and the like. Batteries can include, but are not limited to, 9V, AA, AAA, C, D, or Li-ion or Ni-mh rechargeable batteries. Additionally, the device  10  can be powered from a solar power panel. 
         [0129]    The low voltage power can be supplied remotely from an external power converter such as a 12V cigarette lighter power adapter or a 110V/220V AC/DC plug-in power adapter or other low voltage source such that no high voltage AC current is brought to the device  10 . 
         [0130]    The transducer  30  can be activated by switch  90  such as a large push button switch, toggle switch, and the like. 
         [0131]    Alternatively, the transducer  30  can be automatically set off by a pressure sensor  85 , and the like, in the bowl  50  which can be set off by placement of the weight of beverage container  205  placed into the bowl  50 . 
         [0132]    The pressure sensor (such as but not limited to a force sensitive resistor)  85  activates the back-lighting LED  220  and the ready LED (not shown) in the push button to indicate the presence of a bottled beverage or beverage container. The push button switch  90  is pushed to activate the timing electronics  100  which pulse the ultrasonic transducer  30  for a certain period of time creating one or more short pulses (approximately 0.1 s to approximately 2.0 s or more or less) of ultrasonic frequency. 
         [0133]    The pulses immediately transfer through the bowl and transmission medium and start to crystallize the liquid via ice-crystal nucleation inside the closed beverage container  205  starting a slushing effect  215  inside the beverage container which rapidly transfers throughout all the liquid contents, converting them into a soft-slush or “hyperquenched, vitrified-liquid” state. 
         [0134]    For beverage containers that are bottles, such as bottles of carbonated soda, and the like, a novel illumination source  220  mounted to a backwall  210 , which can have a shape of a beverage container, such as the outer shape of a soda bottle, allows for easy placement of the bottled beverage and easy viewing of the ice-crystallization effects to be viewed by the user. 
         [0135]    The backwall  210  and the illumination source  220  can be further treated with waterproofing coatings or covers that are translucent and protect the components from liquid and the environment. 
         [0136]    When the switch  90  is pressed, the timing electronics in the electronic components  100  create a short duration ultrasonic pulse from the transducer  30  which produces ultrasonic waves through the transmission medium (water or gel) and to the thin membrane  60  and into the bottled beverage  205 . Within the bottled beverage  205 , a small amount of supercooled liquid nucleates  215  which will quickly spread and cause the entire beverage liquid to form soft ice-crystals throughout the container  205 . When the beverage container  205  is opened, no unwanted foaming will be present which allows the user to enjoy the supercooled ‘slushed’ beverage without any negative effects. 
         [0137]    Due to the beauty of the ice-crystal nucleation (freezing or slushing) process, it is desirable to enhance the visible aspects of this process while it is in the device  10 , such as backlighting, side-lighting, or bottom lighting of the beverage within the container. The viewer watches the liquid in the bottle turn into a slushy ice-crystal formation over a period of seconds or tens of seconds depending on how much of the nucleation took place during the button press and depending on the type of beverage ingredients that are present—sugared beverages generally taking longer than non-sugared beverages to complete the slushing process. The ice-crystallization can be described as clouds, crystals, glass, or slush and will be different based on supercooled temperature, beverage contents and beverage color. 
         [0138]    Illumination can be designed to light-up automatically upon putting a bottled beverage on the in the bowl  50  via a sensor such as a pressure sensor  85  or via push button switch  90 , or may come-on via an ON/OFF switch. The illumination can be designed to illuminate the beverage from the front, back, sides, top or bottom or from multiple angles in order to see through and into the beverage so that the nucleation or ‘slushing’ of a supercooled beverage can be fully observed. The illumination turn-off automatically when the beverage bottle is removed or via an ON/OFF switch. The device  10  can be designed smaller or larger than illustrated with more or fewer illumination sources (such as more or less LEDs). 
         [0139]    The device  10  can be mounted at eye level with the illumination source next to the bottle container  205 . The device  10  can operate as follows;
       1. The device  10  is normally OFF and will not function until a bottled beverage  205  is placed in the bowl  50  with transmission medium membrane and transmission medium and/or on top of the ultrasonic transducer  30  if no bowl is present. (the invention can be made with or without a bowl, or with a plate or other mechanism for holding a bottled beverage).   2. The illumination sources  220  (LEDs) turn ON when a bottled beverage  205  is placed in the bowl  50  (on the transducer) via a ‘pressure-activated-switch  85     3. The push-button switch  90  becomes ACTIVATED when a bottled beverage  205  is placed in the bowl  50 .       
 
         [0143]    When the push-button  90  is pushed, an ultrasonic PULSE is sent from the transducer  30  into the liquid or gel medium and through the transmission medium  60  into the bottle  205 , which nucleates “slushes” the supercooled liquid inside the beverage bottle  205 . The push-button  90  is DE-ACTIVATED for a period of time, such as 2-5 seconds in order to prevent multiple rapid pushes of the button. However, the Illumination source  220  (LEDs) can remain ON as long as the bottle  205  is in the bowl  50  or on the transducer  30  or alternatively for as long as the bottle remains pressed against the wand assembly  440 ,  450  in the side mounted configuration  400  of the apparatus. 
         [0144]    The illumination source  220  can include a plurality of LEDs (Light emitting diodes). A footprint of the illumination source can be for tall bottles (16 ounces to 1 liter), a height of approximately 4½ inches to approximately 7 inches, and a width of approximately 1 inch to approximately 2 inches. A foot print of the illumination source for short bottles (8 ounces to 14 ounces) can have height of approximately 2 inches to approximately 4 inches, and a width of approximately 1 inch to approximately 2 inches. 
         [0145]    The intensity of the LEDs can be adjusted by size, weight, or type of the beverage bottles being used. For example, bright LEDs or superbright LEDS can be used and if a small bottle is detected based on it&#39;s weight against the FSR  85 , only the lower portion of the LEDs can illuminate. 
         [0146]    An optional dimmer switch can be used to control intensity levels. For example a dark soda, such as colas can require maximum intensity of superbright LEDs for proper viewing of the ice-crystal nucleation whereas a clear soda or bottled water may require dimmer LED backlighting when viewing. 
         [0147]    In a preferred embodiment, a pattern of approximately 96 LEDs can be used consisting of two 48 SMD LED 12V Dome Panels stacked vertically with all LED&#39;s backlighting larger bottles and only the lower panel backlighting the smaller bottles. 
         [0148]    An alternative configuration can be used with waterproof strip SMD LEDs such as 50/50 or 35/28 strips of LEDs using horizontal or vertical placements of small strips of LEDs. 
         [0149]    The illumination source  220  can be placed approximately ¼ inch to approximately 1 inch spaced apart from the beverage bottle container  205 . 
         [0150]    The illumination source  220  can be multi-color, flashing, or moving LED&#39;s to enhance the visual effects of the nucleation “slushing” process. 
         [0151]    The Illumination sources  220  can be of any number, shape, size, color, of LED&#39;s and can be made of other light sources than LED&#39;s, for example neon-lights, halogen lights, florescent lights or other lighting mechanisms (not shown in drawings). 
         [0152]    A schematic  100  for running the device  10  is shown in  FIG. 5 . Pressure switch  101  is also the force sensitive resistor (FSR) pressure switch  85  previously described. An example of the FSR used can include but is not limited to be a 0.5 inch diameter round force sensitive resistor able to detect a wide range of pressure applied to the sensitive area with a high degree of precision, allowing the device to detect the difference between sizes and types of bottles placed on the apparatus. 
         [0153]    Arduion or IC (integrated circuit) smart-board electronics  102  can be an Arduino Uno, Mini, or Pro Smart Board or other version of the Arduino platform of smart electronic computer boards, Microchip PIC microcontroller, Raspberry Pi microcontroller, and the like. Various types of micro-electronics can be used, such as but not limited to Arduino boards used with ultrasonic transducers, which are described in U.S. Pat. No. 9,024,168 to Peterson (column 4) and U.S. Patent Application Publication: 2014/0125577 (paragraphs 53-56) to Hoang et al. and 2015/0112451 to Dechev et al. (paragraph 112), which are incorporated by reference in their entirety. 
         [0154]    Ready LED  103  can be an imbedded LED within the push button that illuminates the pushbutton from the inside allowing the user to know it is ready to be pressed. 
         [0155]    D/C Relay  104  can be direct current relay such as a single DC/DC relay or relay board. 
         [0156]    Beverage bottle illumination LEDs  105  is also the illumination source  220  previously described. 
         [0157]    Push button switch  106  is also the push button switch  90  previously described. 
         [0158]    Solid state relay  107  can include but is not limited to be a Berme BEM-14840DA Solid-State Relay. 
         [0159]    Ultrasonic transducer electronics  108  can be an ultrasonic transducer driver board made for 110V, 100 W, 40 khz or similar, with the ultrasonic transducer  109  can be the transducer  30  previously described, such as but not limited to a 100 W, 40 khz piezoelectric ultrasonic cleaning transducer or similar. 
         [0160]    Sound output module  110  can include but is not limited to be a piezo speaker module or similar. 
         [0161]    Power source  111  can include the power source  80  previously described. 
         [0162]    Referring to  FIG. 5  in relation to  FIGS. 1-4 , the components interact as follows: 
       Block Diagram Path A 
       [0163]    Step 1: A supercooled beverage bottle  205  is placed in the bowl  50  which is in contact with the ultrasonic transducer  30  and/or transfer medium (water, liquid or gel) or membrane  60 .
 
Step 2: The pressure switch  70  is activated by the weight of the bottle  205 , which sends a signal to the Arduino or IC Smart-board electronics  102  that a bottle  205  is present. (In one embodiment, the pressure switch  85  and smart-board electronics  102  can determine the size and type of beverage by weight.)
 
Step 3: The Ready LED  103  is activated
 
Step 4: The D/C Relay  104  is activated providing power to the Illumination LEDs  105 / 220 .
 
Step 5: The Illumination LED  105 / 220  are powered ON to shine through the bottle  205  for the viewer.
 
       Block Diagram Path B 
       [0164]    Step 6: The Push Button Switch  90  is pressed by the user sending a signal to the Arduino or smart-board electronics  102 .
 
Step 7: The Arduino or smart-board electronics  102  activates the solid-state relay  107  to energize the ultrasonic transducer electronics  108  for a short-duration pulse (approximately 0.1 to approximately 2.0 seconds). (note: if a bottle  205  is not present on the pressure switch  85 , the Arduino or smart-board electronics  102  will not activate the solid-state relay  107  when the push-button switch  90  is pressed.)
 
Step 8: The ultrasonic transducer electronics  108  energizes the ultrasonic transducer  109 / 30  for the short duration pulse which nucleates the supercooled beverage inside the bottle  205  and begins to create a slush. In addition, the optional sound output module  110  creates a sound effect while the slush is forming in the bottle  205 , which may take between approximately 1 and approximately 30 seconds.
 
         [0165]    The Illumination LEDs  220 / 105  remain ON while the bottle  205  is detected in the bowl  50  for a duration of time (between approximately 30 seconds up to several minutes). The Illumination LEDs  105 / 220  will switch OFF when the bottle  205  is removed or the time setting expires. 
       Automated Delay 
       [0166]    The Arduino or smart-board electronics  102  will force a delay (of approximately 1 to approximately 5 seconds) before allowing a subsequent pressing of the push-button  90  to cause a subsequent ultrasonic pulse to be sent. This feature will prevent repeated, rapid ultrasonic pulses being sent to the ultrasonic transducer  109 / 30  which can cause undesirable results such as foaming overflow of sodas. Additionally, a longer automated delay (of approximately 30 to approximately 60 seconds) will take place if a certain number of ultrasonic pulses are sent to the same bottle  205  (between approximately 3 and approximately 5) in a short period of time (approximately 10 to approximately 15 seconds) in order to prevent undesirable overflow or pressure due to possible CO2 (carbon dioxide) expansion inside a bottled beverage  205  caused by the repeated ultrasonic pulsing. 
         [0167]    The wattage (W) and time duration of the ultrasonic signals can be adjusted based on having different transmission mediums (water, gel), as well as different types of beverages, such as soda/juice and diet soda. The sugar in soda/juice and non-sweeteners in diet soda can have different transducer emitter times as shown in Tables 1 and 2. The ranges of seconds can include the term “approximately” before each of the numerical values. 
         [0168]    Table 1 shows a timing matrix for the nucleator (crystallization) pulse power (wattage (W) in range of seconds for a water based transmission medium. 
         [0000]    
       
         
               
               
               
               
               
               
               
             
           
               
                 TABLE 1 
               
               
                   
               
               
                 Beverage 
                 15 W 
                 25 W 
                 35 W 
                 60 W 
                 100 W 
                 150 W 
               
               
                   
               
             
             
               
                 Soda/ 
                 0.3-1.5  
                 0.3-1.0 
                 0.2-0.9 
                 0.2-0.8 
                 0.1-0.6 
                 0.1-0.4 
               
               
                 Juice 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
               
               
                 Diet soda/  
                 0.2-1.0 
                 0.3-0.8 
                 0.1-0.7  
                 0.1-0.6  
                 0.1-0.4 
                 0.05-0.3 
               
               
                 Bottle 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
               
               
                 Water 
               
               
                   
               
             
          
         
       
     
         [0169]    Table 2 shows a timing matrix for the nucleator (crystallization) pulse power in range of seconds for a gel based transmission medium. 
         [0000]    
       
         
               
               
               
               
               
               
               
             
           
               
                 TABLE 2 
               
               
                   
               
               
                 Beverage 
                 15 W 
                 25 W 
                 35 W 
                 60 W 
                 100 W 
                 150 W 
               
               
                   
               
             
             
               
                 Soda/ 
                 0.5-2.0  
                 0.5-1.8 
                 0.3-1.7 
                 0.3-1.5 
                 0.3-1.2 
                 0.2-1.0 
               
               
                 Juice 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
               
               
                 Diet soda/  
                 0.3-1.8 
                 0.3-1.7 
                 0.2-1.4  
                 0.2-1.2 
                 0.2-1.0  
                 0.1-0.8 
               
               
                 Bottle 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
                 seconds 
               
               
                 Water 
               
               
                   
               
             
          
         
       
     
         [0170]    Referring to  FIG. 4 , optional rotation of the beverage container can also be used. Adding rotation or spinning to the base of the device  10  in order to rotate beverage bottles  2015  just prior or during the process of nucleating the beverage can further add additional excitement and visual enhancement to the visible beauty of the nucleation (freezing/slushing) process. 
         [0171]    The rotation can be of slow RPM such as approximately 60 to approximately 100 RPM of duration of a few seconds to a few tens of seconds in order to move the liquid inside the beverage bottle in a circular motion just prior to—and during—ice-crystal nucleation. The benefit of the rotation is that the small ice-crystals that form at the beginning of ice-crystal nucleation are in motion as they expand within the beverage to create the slushing effect. The motion adds fascination and visual excitement to the process for the end user. 
         [0172]      FIG. 6  is an upper rear right perspective view of a second embodiment device  10  for crystallizing liquid to form slush inside chilled bottles with no illumination source. This embodiment works the same as the previous embodiment with the exception of not having the illumination sources  220 . This embodiment can be used with beverages that are opaque such as milkshakes or with canned beverages, and the like. 
         [0173]    Device  10  can be stand-alone, on a pedestal, or mounted to a supercooling refrigeration system, portable cooler, or other secondary device. 
         [0174]      FIG. 7  is an upper left perspective view of the device  10  of  FIG. 1  attached to the side of refrigerated beverage merchandiser or other cooling device  260 . Commercial devices  260  can be a refrigerant display case in a retail store that supercools beverage containers such as bottles to less than approximately 30 F. 
         [0175]    A side mount  240  can be attached to the sides of merchandiser or cooling device  260  by magnets or fasteners, such as screws and bolts. Flanges  250  extending from the sides of the base of device  10  can fasten the device  10  to the mount  240 . The mount can be hollow with an access door (not shown) such that it can contain items such as ultrasonic gel pads, membranes, or liquid transmission medium fluid. 
         [0176]      FIG. 8  is an upper front left perspective view of a third embodiment device  310  for crystallizing liquid to form slush inside supercooled bottles with an illumination source  330 .  FIG. 9  is another perspective view of the device  310  for bottles of  FIG. 8  with a bottle  315  mounted on the device  310 .  FIG. 10  is an exploded view of the device  310  of  FIG. 9 .  FIG. 11  is another perspective view of the device  310  of  FIG. 9  with bowl assembly  340  removed for cleaning. 
         [0177]    Referring to  FIGS. 8-11 , the device  310  works similar to device  10  with an illumination source previously described. Here device  310  can include a sleeker stand  320  being more aesthetically useful for home and/or private use and resembles a cordless handheld phone. An illumination source  330  such as LEDs (light emitting diodes), can operate similar to the previous embodiment device  10 . Power and operation can function similar to previous embodiment  10 . 
         [0178]    Component  340  refers to removable bowl assembly similar to bowl  50  previously described but containing a wafer-type ultrasonic transducer attached to the underside of a metal alloy or plastic plate or bowl. 
         [0179]    Component  347  refers to wafer style piezoelectric ultrasonic of 15 W, 25 W, 35 W or 50 W power or similar. 
         [0180]    Component  348  refers to a plastic bowl or plate that contains electrical contacts to allow electrical transmission from the base connector  349  to the piezoelectric ultrasonic transducer  347 . 
         [0181]    Component  349  refers to base electrical connector for allowing the bowl  348  to be removed from the apparatus for cleaning or filling with water or ultrasonic transmission fluid. 
         [0182]    Component  350  refers to a touch sensitive button to fire the ultrasonic transducer pulse. 
         [0183]    Component  360  refers to a ready indicator LED to indicate the unit is ready for button push. 
         [0184]    Component  370  refers to a touch sensitive power-on button to turn the device on and off. 
         [0185]    Component  380  refers to a power-on indicator LED to show the unit is on or off. 
         [0186]    For operating the device, a beverage bottle or container is placed on the bowl assembly  340 , in contact with the liquid medium and the plate  345 . The power button  370  is pressed and the device is turned ON as indicated by the power LED  380 . The backlighting LED&#39;s  330  illuminate the beverage bottle. The ready LED  360  turns on and the firing button  350  is pressed by the user. The ultrasonic transducer  347  sends a short duration pulse through the plate and transmission medium into the beverage container. The supercooled beverage inside the container will begin ice-crystal nucleation and the slushing process will begin as the user watches from the vantage point shown in  FIG. 9 . 
         [0187]    The embodiment of  FIGS. 8-11  can also have optional rotation or spinning of the beverage bottle similar to the rotating and spinning capability described in the previous embodiment. 
         [0188]      FIG. 12  is another perspective view of another embodiment of a device  400  for crystallizing liquid to form slush inside chilled bottles using a contact membrane  450  with liquid or gel transmission medium inside. The bottle backlighting assembly  430  indicates where the bottle should be held and pressed against by the user. 
         [0189]      FIG. 13  is an exploded view of the side pressed embodiment. This embodiment can use a wand  440  which includes an extension arm  440  connected securely to the ultrasonic transducer  410 . A water-tight membrane  450  similar to the previous embodiments can be attached to the end of the wand  440  and is filled with liquid (such as water) or a gel. Timing electronics  420  such as electronics  100  previously described can produce the ultrasonic pulse when a switch and/or a pressure sensor is activated. A pressure switch force sensitive resistor and support  425  is used to detect the presence of a bottle on the device. 
         [0190]    The wand end  450  can be placed in physical contact with a supercooled beverage bottle (not shown) and will cause nucleation within the beverage when the pulse is generated. 
         [0191]    Component  430  refers to a bottle design back plate and LED housing. 
         [0192]    Component  440  refers to a wand attachment to the ultrasonic transducer and a liquid or gel medium and membrane. 
         [0193]    A mounting box  460  can attach the wand embodiment  400  to a wall or cabinet or merchandiser, and the like, by using conventional fasteners, such as screws or bolts through box flanges to the underlying vertical support. 
         [0194]    In operation, the wand  440  is directly attached to the ultrasonic transducer  410  such that the ultrasonic frequency vibrations are transmitted to the end of the wand and through the liquid or gel medium and membrane  450  into the beverage container that is in contact with the membrane. The nucleation effect is similar to that of the previously described embodiments. 
         [0195]    The term “approximately” throughout the application can be +/−10% of the amount referenced. Additionally, preferred amounts and ranges can include the amounts and ranges referenced without the prefix of being approximately. 
         [0196]    The devices referenced above can be designed as a counter-top display in TWO-PARTS, with the ultrasonic Nucleator being separate from the Illumination LED&#39;s—or even MULTIPLE-PARTS with multiple lighting sources separate from the Nucleation device. 
         [0197]    Although the drawings show devices, All components of the present invention can be constructed as part of the larger assembly of a beverage merchandiser, vending machine, or other supercooling capable refrigerated device or they may be made separate and free-standing either individually or collectively. 
         [0198]    The invention can be used with beverage bottles that are sealed and not opened, as well as can be with beverage bottles that are opened and closed again. 
         [0199]    The invention can be used with closed beverage bottles, that include glass bottles and plastic bottles, as well as canned beverages, such as those in aluminum cans, and the like. 
         [0200]    The invention can be used with sealed beverage containers made of cardboard, wax paper, plastic or multi-layer constructions. The invention can also be used with re-usable containers with removable lids or caps. 
         [0201]    The invention can be used with open beverage containers such as glass, plastic or metal cups or containers. 
         [0202]    The invention can be used with containers of liquids, gelatins, or combinations of cold food ingredients such as ice-creams to create unique ice-crystal nucleations or emulsions. 
         [0203]    While the invention has been described, disclosed, illustrated and shown in various terms of certain embodiments or modifications which it has presumed in practice, the scope of the invention is not intended to be, nor should it be deemed to be, limited thereby and such other modifications or embodiments as may be suggested by the teachings herein are particularly reserved especially as they fall within the breadth and scope of the claims here appended.