Abstract:
A method and apparatus for the electroplating deposition of a metal onto a semiconductor wafer surface ( 29 ), including vibrationally scrubbing the wafer surface ( 29 ) during an electroplating process. At least one transducer ( 32 ) is mounted to a wall ( 33 ) of an electroplating tool chamber ( 22 ). The transducer ( 32 ) intermittently delivers sonic energy pulses lasting for one to two seconds to the electroplating solution during the electroplating process.

Description:
BACKGROUND OF THE INVENTION 
     This invention relates generally to the fabrication step of electroplating in the manufacture of semiconductor wafers and/or integrated circuit devices (IC devices). In addition, the invention relates to the methods of minimizing particulate contamination occurring during the electroplating process commonly used as a fabrication step of semiconductor wafers and/or IC devices. 
     Electroplating is widely used for metal deposition in the manufacture of printed circuit boards, and more recently has become popular in the manufacture of IC devices. A variety of conductor materials are used in the interconnect structure of IC devices including aluminum, aluminum alloys, polysilicon with an overlaid metal silicide layer, and tungsten. More recently, copper has been used in IC device fabrication as an interconnect material. A popular method of depositing copper during IC device fabrication is electroplating. 
     Interconnect structures are those structures on an IC device that connect different levels of a multi-level-interconnect IC device, and include contact holes and/or vias. Contact holes are holes in a PMD (pre-metal dielectric), which is a dielectric layer between a polysilicon gate and a metal layer. Contact holes allow electrical connections between a metal layer and the polysilicon and/or the silicon) wafer substrate. Vias allow the contact between different metal layers on the IC device. 
     These interconnect materials are deposited on the wafer using different techniques including sputtering, chemical vapor deposition and electroplating. In the case of electroplating copper, a wafer or chip first requires an adhesion/barrier layer and a seed layer. The materials used to form the adhesion/barrier layer, and the methods for application of the adhesion/barrier layer, are known to those skilled in art. 
     The copper electroplating process of semiconductor wafers and/or IC devices involves the exposure of a wafer; face down, in an electrolyte bath so that the top patterned surface of the wafer is in contact with, or immersed in the electrolyte bath. The electroplating process is performed in an electroplating tool, which is shown in FIG.  1 . As shown in FIG. 1, the electroplating tool  11  generally includes an electroplating plating chamber  12  in which a semiconductor wafer  13  is disposed “face-down”. Sealing mechanisms, known to those skilled in the art, seal a backside of the wafer  13  from the electroplating process. An electroplating bath (or solution)  15  is supplied to the chamber  12  through a conduit  14 . The conduit  14  directs the solution (or bath) to the chamber, so that the wafer is adequately exposed to the electrolytic solution for deposition of copper on the wafer surface. 
     A commonly used electroplating bath is an electrolyte solution containing copper sulfate, sulfuric acid and water. Moreover, the electrolyte solution includes additives to control the plating process. The additives are organic and inorganic compounds commonly used in the electroplating process that control the rate of copper plating and plating behavior on the wafer surface. The additives are commonly referred to as levelers, brighteners or accelerators. 
     In an electroplating chamber, the wafer  13  acts as a cathode for copper deposition. The tool  11  is also equipped with a solid copper anode, which replaces copper ions removed as a result of electroplating. The entire electroplating process for a semiconductor wafer may take one to three minutes. 
     After electroplating, the wafers are then chemically rinsed and dried. In addition, the wafers are annealed to stabilize the copper microstructure formed on the wafer surface. After the annealing step, the wafers are subjected to a chemical-mechanical planarization (CMP) step in which the copper metal deposited on the wafer, outside a via, trench or contact hole, is polished back to leave the features (holes, vias or trenches) filled with copper. The CMP processes available in the production of semiconductor wafers are well known in the art. The CMP process not only removes any excess copper, but also achieves the required planarization across the wafer surface. 
     Contamination of the wafer may occur in two forms in the electroplating process: particulate contamination and “pits” caused by air/gas bubbles. Since the composition of the electroplating bath is acidic, particles in the bath have a tendency to deposit on the wafer surface during the electroplating process. The presence of particles on the wafer surface leads to enhanced or suppressed copper plating, resulting in the formation of a non-homogenous, defect-ridden copper film across the wafer surface. In addition, as the wafer is placed in the plating cell face down, air bubbles are trapped during the electroplating process against the wafer surface. These air bubbles can lead to “microvoids” or “pits” on the wafer surface. These microvoids or pits compromise the copper film reliability and can lead to device failure. 
     Present methods used to prevent such contamination include minimizing handling and exposure of wafers in clean rooms, or reducing particulate contamination in a previous step of copper seed deposition. In addition, wafers may be introduced into the electroplating chamber at an angle. However, these methods have proven ineffective. Particulate contamination invariably occurs and cannot by completely eliminated. In addition, the angled introduction of the wafer can lead to a copper thickness gradient across the wafer. 
     SUMMARY OF THE INVENTION 
     In order to minimize contamination or prevent defects on semiconductor wafer surfaces or IC devices, an electroplating process is adapted to perform vibrational scrubbing during the electroplating process. An electroplating tool is equipped with a transducer for generating energy waves within an electroplating solution. A top surface of the semiconductor wafer is exposed to the electroplating solution containing those components known in the art such as Cu 2 SO 4 , H 2 SO 4 , water and various organic and inorganic additives to control variables of the electroplating process. During the electroplating process the transducer intermittently generates sonic energy waves at selected frequencies and wavelengths, for a timed duration. The sonic waves agitate and remove particulate contamination and trapped air bubbles. The transducer preferably generates the sonic energy waves for pulses up to 1 to 2 seconds in length. Once the electroplating process is complete, the semiconductor wafers are removed free of contaminants and potential defects that may normally occur in the electroplating process. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a front sectional view of a semiconductor wafers immersed in a electrolyte solution. 
     FIG. 2 is a front sectional view of a semiconductor wafer immersed in electroplating tool of the present invention. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     The present invention combines the fabrication step of electroplating on a semiconductor wafer surface with a vibrational scrubbing process in order to minimize or eliminate wafer surface contamination that may take place during electroplating. The invention is described in the context of copper electroplating, but the invention is not intended to be limited to copper electroplating but includes the electroplating deposition of other metals as can be appreciated by those skilled in the art. With respect to FIG. 2, an electroplating tool  20  is shown with a semiconductor wafer  21  exposed to a copper-electroplating solution  25  (also referred to as an electrolyte bath or solution). The electroplating solution  25  is held in a chamber  22 , which is defined by walls  33 . The electrolyte solution  25  consists of an acidic solution of CuSO 4  (copper sulfate), H 2 SO 4  (sulfuric acid), water and organic additives, all of which are known by those skilled in the art. The present invention is not limited by the different components of the bath or the component concentrations. 
     The semiconductor wafer  21  is secured to a cradle  24  with the top surface of the wafer  21  facing downward toward an electroplating chamber  22  filled with an electrolyte solution  25 . The cradle  24  may take different forms as known in the art, but in most cases the cradle  24  is equipped with probe clamps  28  which apply a voltage bias to the wafer surface  29 . The voltage bias creates a negative charge along the wafer surface  29  for attraction of positively charged cupric ions in the electrolyte solution  25 . The electrolyte solution  25  is supplied from a reservoir  23  to the chamber  22  through a conduit  27 . 
     The cradle  24  immerses the top surface  29  of the wafer  21  in the electrolyte solution  25 . The cradle  24  preferably has a sealing mechanism, as an o-ring  31 , disposed along a backsurface  34  of the wafer  21 , to seal the backsurface  34  from the electroplating process. Copper anodes  30  disposed within the electroplating solution  25  and chamber  22  generate cupric ions replacing those ions removed from the solution by the plating taking place on the wafer surface  29 . 
     A sonic energy source is provided in communication with the electroplating solution. In an exemplary embodiment, at least one transducer  32  is mounted to a wall  33  of the chamber  22 . The transducer  32  generates sonic energy in short bursts (sonic energy pulses) of one to two seconds. The sonic energy generated can range from 300 watts to 1200 watts, at frequencies of 800 kHz to 900 kHz of sonic waves to efficiently remove particulate and release trapped air bubbles. 
     The device may also include means for activating the sonic energy source to supply intermittent bursts of sonic energy to the electroplating solution. In an exemplary embodiment, a variable timing circuit controls the activation and deactivation of the transducer to deliver bursts of sonic energy to the electrolyte solution for preselected time durations. The timer is preferably interconnected with the probes  28  and transducer such that the probe  28  and transducer  32  are simultaneously activated. Alternatively, the timer may delay activation of the transducer  32  for a preselected period of time. In addition, a controller may be incorporated with a timer to program the activation and deactivation of the transducer. The controller is programmed so the transducer  32  is activated intermittently during the electroplating process. The electroplating process takes approximately one to three minutes. Preferably six to eight sonic bursts are generated during the electroplating process so the sonic energy pulses in total last a maximum of twelve to sixteen seconds. Fewer and longer bursts may be generated that are separated by longer periods, e.g., up to eight seconds. 
     The present invention improves on the prior art of a continuous ultrasonic or megasonic vibration which may cause removal of the additives from the wafer surface  29 , which additives are required for effective slope, step and trench coverage. The periodic bursts of sonic energy agitate localized agglomerations, which allows the additives to migrate to and adsorption on the wafer surface  29 , and removes contaminants and air/gas bubbles. The pulsing of the transducers may be coupled with a physical movement of the semiconductor wafer in and out of the electrolyte such that the energy is not coupled to the wafer at all times. 
     While the preferred embodiments of the present invention have been shown and described herein, it will be obvious that such embodiments are provided by way of example only. Numerous variations, changes and substitutions will occur to those of skill in the art without departing from the invention herein. Accordingly, it is intended that the invention be limited only by the spirit and scope of the appended claims.