Abstract:
Disclosed is an apparatus and method for treating a substrate. The method includes supplying cleaning particles to the substrate to clean the substrate. The cleaning particles are solid particles. The solid particles provide a shock wave to the substrate.

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
       [0001]    A claim for priority under 35 U.S.C. §119 is made to Korean Patent Application No. 10-2014-0154705 filed Nov. 7, 2014, in the Korean Intellectual Property Office, the entire contents of which are hereby incorporated by reference. 
       BACKGROUND 
       [0002]    Embodiments of the inventive concepts described herein relate to an apparatus and a method for treating a substrate, and more particularly, relate to a substrate treating apparatus for cleaning a substrate and a method thereof. 
         [0003]    Various processes such as photolithography, etching, ashing, ion implantation, and film deposition are performed on a substrate so as to manufacture a semiconductor device or a liquid crystal display. A substrate cleaning process for removing various contamination materials and particles attached to a substrate surface may be performed before and after each unit process for fabricating a semiconductor device. 
         [0004]    Various methods such as spraying a chemical, a treating solution including a gas, or a treating solution with a vibration are used as a cleaning process to remove various contamination materials and particles remaining on the substrate surface. 
         [0005]    It is possible to remove remaining contamination materials and particles on the substrate surface by providing a shock wave to a substrate using a liquid of a small size within a range where the substrate is not damaged. However, it may be possible to generate a liquid with a size which is maximally several tens μm. 
       SUMMARY 
       [0006]    Embodiments of the inventive concepts provide a substrate treating apparatus and a method thereof, capable of improving an efficiency of a substrate cleaning process. 
         [0007]    Embodiments of the inventive concepts provide a method of treating a substrate. 
         [0008]    One aspect of embodiments of the inventive concept is directed to provide a method for treating a substrate, the method including supplying cleaning particles to the substrate to clean the substrate. The cleaning particles may be solid particles. The solid particles may provide a shock wave to the substrate. 
         [0009]    Each of the solid particles may have a size of several micrometers. 
         [0010]    Each of the solid particles may have a size of several tens or hundreds nanometers. 
         [0011]    The method may further include supplying a treating solution to the substrate while the solid particles are supplied to the substrate. 
         [0012]    The method may further include supplying a treating solution to the substrate before the solid particles are supplied to the substrate. 
         [0013]    The solid particles may be supplied on the treating solution and may provide the shock wave to the substrate. 
         [0014]    The solid particles may be formed of a material soluble in the treating solution. 
         [0015]    The solid particles may be formed of a material of which the gravity is 1 or less. 
         [0016]    The solid particles may be formed of a plastic powder. 
         [0017]    The solid particles may be supplied to the substrate by a carrier gas. 
         [0018]    The carrier gas may be a helium gas. 
         [0019]    The solid particles may be formed of a material which provides the shock wave to the substrate and of which a state is changed into a liquid state or a gas state at room temperature. 
         [0020]    The solid particles may be formed of dry-ice. 
         [0021]    Embodiments of the inventive concepts provide an apparatus of treating a substrate. 
         [0022]    Another aspect of embodiments of the inventive concept is directed to provide an apparatus for treating a substrate including a container having an inner treating space, a support unit placed in the treating space and supporting the substrate, and a supply unit supplying cleaning particles in the treating space. The supply unit comprises a solid nozzle supplying the cleaning particles having solid particles. 
         [0023]    Each of the solid particles may have a size of several micrometer s. 
         [0024]    Each of the solid particles may have a size of several tens or hundreds nanometers. 
         [0025]    The supply unit may include a treating solution supply nozzle supplying a treating solution. 
         [0026]    The solid nozzle may include a nozzle unit comprising an upper body and a lower body jointed to the upper body, the lower body including a flow pathway therein; and a cleaning particle supply unit connected with the nozzle unit and supplying a gas, the gas being changed into a solid particle passing through a discharge hole connected from the upper body to the lower body and colliding with the substrate. The flow pathway may include an upper flow pathway formed in a length direction of the nozzle unit such that a diameter thereof gradually decreases along the length direction, and a lower flow pathway formed in a second length direction of the nozzle unit such that a diameter thereof gradually increases along the length direction. 
         [0027]    The solid particles may be formed of a material which is sublimated after colliding with the substrate. 
         [0028]    The solid particles may be formed of dry-ice. 
         [0029]    The solid nozzle may include a nozzle unit having an inner flow pathway, a cleaning particle supply unit connected to the nozzle unit and supplying the cleaning particles, and a carrier gas supply unit connected to the nozzle unit and supplying high-pressure carrier gas to the nozzle unit. The nozzle unit may include an upper body formed along its length direction such that its diameter gradually decreases along the length direction, and a lower body connected to the upper body, and formed in its length direction such that its diameter gradually increases along the length direction. 
         [0030]    The solid particles may be a material of which gravity is 1 or less. 
         [0031]    The solid particles may be a plastic powder. 
         [0032]    The carrier gas may be a helium gas. 
     
    
     
       BRIEF DESCRIPTION OF THE FIGURES 
         [0033]    The above and other objects and features will become apparent from the following description with reference to the following figures, wherein like reference numerals refer to like parts throughout the various figures unless otherwise specified, and wherein: 
           [0034]      FIG. 1  is a top plan view schematically illustrating a substrate treating apparatus; 
           [0035]      FIG. 2  is a cross-sectional view illustrating a substrate treating apparatus of  FIG. 1 ; 
           [0036]      FIG. 3  is a diagram schematically illustrating a solid nozzle of  FIG. 2 ; 
           [0037]      FIG. 4  is a diagram illustrating other embodiment of a solid nozzle of  FIG. 2 ; and 
           [0038]      FIGS. 5 to 10  are diagrams sequentially illustrating a process for generating a shock wave on a substrate using solid particles. 
       
    
    
     DETAILED DESCRIPTION 
       [0039]    Below, Embodiments will be described in detail with reference to the accompanying drawings. The inventive concept, however, may be embodied in various different forms, and should not be construed as being limited only to the illustrated embodiments. Embodiments of the inventive concept are provided to illustrate more fully the scope of the inventive concept to those skilled in the art. Therefore, the shapes of the components in the drawings may be exaggerated to emphasize a more clear description. 
         [0040]      FIG. 1  is a top plan view schematically illustrating a substrate treating apparatus according to an embodiment of the inventive concept. 
         [0041]    Referring to  FIG. 1 , a substrate treating apparatus  1  may have an index module  10  and a process treating module  20 . The index module  100  may contain a load port  120  and a transfer frame  140 . The load port  120 , the transfer frame  140 , and the process treating module  20  may be arranged in a line. Below, a direction where the load port  120 , the transfer frame  140 , and the process treating module  20  are arranged may be referred to as “first direction”  12 . When viewed from the top, a direction perpendicular to the first direction  12  may be referred to as “second direction”  14 , and a direction perpendicular to a plane defined by the first direction  12  and the second direction  14  may be referred to as “third direction”  16 . 
         [0042]    A carrier  130  where a substrate W is received may be safely put on the load port  120 . The load port  120  may be in plurality, and the plurality of load ports  120  may be arranged in a line along the second direction  14 . The number of load ports  120  may increase or decrease according to conditions such as process efficiency, footprint, and the like in the process treating module  20 . A plurality of slots (not illustrated) may be formed in the carrier  130  so as to receive the substrates W in a state where they are placed in a horizontal position on the ground surface. A Front Opening Unified Pod (FOUP) may be used as the carrier  130 . 
         [0043]    The process treating module  20  may contain a buffer unit  220 , a transfer chamber  240 , and process chambers  260 . The transfer chamber  240  may be arranged such that its length direction is parallel with the first direction  12 . The process chambers  260  may be arranged at opposite sides of the transfer chamber  240  along the second direction  14 . The process chambers  260  may be arranged at one side and the other side of the transfer chamber  240  so as to be arranged symmetrically with respect to the transfer chamber  240 . The plurality of process chambers  260  may be provided at one side of the transfer chamber  240 . A portion of the process chambers  260  may be arranged along a length direction of the transfer chamber  240 . Furthermore, a portion of the process chambers  260  may be arranged to be stacked on. That is, the process chambers  260  may be arranged in an A-by-B matrix at the one side of the transfer chamber  240 . In this case, “A” may indicate the number of process chambers  260  arranged in a line along the first direction  12 , and “B” may indicate the number of process chambers  260  arranged in line along the third direction  16 . When four or six process chambers  260  are arranged at the one side of the transfer chamber  240 , the process chambers  260  may be arranged in a 2-by-2 or 3-by-2 matrix. The number of process chambers  260  may increase or decrease. Unlikely, the process chambers  260  may be provided at any one side of the transfer chamber  240 . In addition, the process chambers  260  may be arranged at one side and opposite sides of the transfer chamber  240  to form a single layer. 
         [0044]    The buffer unit  220  may be disposed between the transfer frame  140  and the transfer chamber  240 . The buffer unit  220  may provide a space where a substrate W stays before transferred between the transfer chamber  240  and the transfer frame  140 . A slot(s) (not illustrated) where a substrate W is placed may be provided in the buffer unit  220 . A plurality of slots may be provided to be spaced apart from each other along the third direction  16 . The buffer unit  220  may have an opened surface that faces the transfer frame  140  and an opened surface that faces the transfer chamber  240 . 
         [0045]    The transfer frame  140  may transfer a wafer W between the buffer unit  220  and the carrier  130  safely put on the load port  120 . An index rail  142  and an index robot  144  may be provided at the transfer frame  140 . The index rail  142  may be provided such that its length direction is parallel with the second direction  14 . The index robot  144  may be mounted on the index rail  142  and may move in a straight line toward the second direction  14  along the index rail  142 . The index robot  144  may contain a base  144   a , a body  144   b , and an index arm  144   c . The base  144   a  may be installed to be movable along the index rail  142 . The body  144   b  may be joined to the base  144   a . The body  144   b  may be provided to be movable on the base  144   a  along the third direction  16 . Furthermore, the body  144   b  may be provided to be rotatable on the base  144   a . The index arm  144   c  may be joined to the body  144   b  such that it is forward and backward movable with respect to the body  144   b . The index arm  144   c  may be in plurality, and the plurality of index arms  144   c  may be driven independently of each other. The index arms  144   c  may be arranged to be stacked on each other under the condition that index arms  144   c  are spaced apart from each other along the third direction  16 . A portion of the index arms  144   c  may be used to transfer a substrate W from the process treating module  20  to the carrier  130 , and a portion of remaining index arms  144   c  may be used to transfer the substrate W from the process treating module  20  to the carrier  130 , thereby preventing particles, generated from a substrate W not experiencing process treating when the substrate W is carried into or taken out of by the index robot  144 , from being attached to the substrate W. 
         [0046]    The transfer chamber  240  may transfer a substrate W between the buffer unit  220  and the process chamber  260  and between the process chambers  260 . A guide rail  242  and a main robot  244  may be provided at the transfer chamber  240 . The guide rail  242  may be arranged such that its length direction is parallel with the first direction  12 . The main robot  244  may be installed on the guide rail  242  and may move in a straight line along the first direction  12  on the guide rail  242 . The main robot  244  may contain a base  244   a , a body  244   b , and a main arm  244   c . The base  244   a  may be installed to be movable along the guide rail  242 . The body  244   b  may be joined to the base  244   a . The body  244   b  may be provided to be movable on the base  244   a  along the third direction  16 . Furthermore, the body  244   b  may be provided to be rotatable on the base  244   a . The main arm  244   c  may be joined to the body  244   b  such that it is forward and backward movable with respect to the body  144   b . The main arm  244   c  may be in plurality, and the plurality of main arms  244   c  may be driven independently of each other. The main arms  244   c  may be arranged to be stacked on each other in a state where the main arms  244   c  are spaced apart from each other along the third direction  16 . 
         [0047]    A substrate treating apparatus  300  performing a cleaning process for cleaning a substrate W may be provided in the process chamber  260 . The substrate treating apparatus  300  may have different structures varied according to types of cleaning processes. In contrast, the substrate treating apparatuses  300  of the process chambers  260  may have the same structure. Selectively, the process chambers  260  may be divided into a plurality of groups. The substrate treating apparatuses  300  in the same groups may have the same structure and the substrate treating apparatuses  300  in different groups may have different structures. 
         [0048]      FIG. 2  is a cross-sectional view illustrating a substrate treating apparatus of  FIG. 1 . Referring to  FIG. 2 , the substrate treating apparatus  300  may include a container  320 , a support unit  340 , an elevation unit  360 , and a supply unit  380 . The container  320  may contain a space where the substrate treating process is performed and an upper portion of the container  320  may be opened. The container  320  may contain an internal collection barrel  322 , a middle collection barrel  324 , and an external collection barrel  326 . Each of the internal, middle, and external collection barrels  322 ,  324  and  326  may collect different treating solutions from each other among treating solutions used in a process. 
         [0049]    The internal collection barrel  322  may be provided in the form of a ring surrounding the support unit  340 . The middle collection barrel  324  may be provided in the form of a ring surrounding the internal collection barrel  322  and the external collection barrel  326  may be provided in the form of a ring surrounding the middle collection barrel  322 . An internal space  322   a  of the internal collection barrel  322 , a space  324   a  between the internal collection barrel  322  and the middle collection barrel  324 , and a space  326   a  between the middle collection barrel  324  and the external collection barrel  326  may serve as inlets that allow the treating solutions to flow into the internal collection barrel  322 , the middle collection barrel  324 , and the external collection barrel  326 , respectively. Collection lines  322   b ,  324   b  and  326   b  which extend vertically and downwardly toward the bottom may be connected to the respective collection barrels  322 ,  324  and  326 . The collection lines  322   b ,  324   b  and  326   b  may discharge treating solutions collected by the collection barrels  322 ,  324  and  326 . The discharged treating solutions may be recycled through an external treating solution recycling system (not illustrated). 
         [0050]    The support unit  340  may support and rotate a substrate W during a process. The support unit  340  may include a body  342 , a support pin  344 , a chuck pin  346 , and a support shaft  348 . The body  342  may have an upper surface provided in the form of a circle when viewed from the top. The support shaft  348  rotated by a motor  349  may be fixedly jointed on a lower surface of the body  342 . 
         [0051]    The support pin  344  may be provided in plurality. The support pins  344  may be disposed to be spaced apart by a predetermined gap from an edge of the upper surface of the body  342  and may protrude upwardly from the body  342 . The support pins  344  may be disposed to have the form of a ring as a whole through a combination thereof. The support pins  344  may support an edge of a rear surface of the substrate W to allow the substrate W to be spaced apart by a predetermined distance from the upper surface of the body  342 . 
         [0052]    The chunk pin  346  may be provided in plurality. The chuck pins  346  may be disposed such that it is further away from the center of the body  342  than the support pin  344 . The chuck pins  346  may be provided to protrude upwardly from the body  342 . The chuck pins  346  may support a side portion of the substrate W to prevent the substrate W from deviating from a given position to a lateral direction when the support unit  340  rotates. The chuck pins  346  may be provided to move in a straight line between a waiting position and a support position along a radius direction of the body  342 . The waiting position may be a position such that it is further away from the center of the body  342  than the support position. When the substrate W is loaded on or unloaded from the body  342 , the chuck pins  346  may be placed at the waiting position; when a substrate treating process is performed, the chuck pin  346  may be placed at the support position. The chuck pin  346  may be contacted with a side portion of the substrate W at the support position. 
         [0053]    The elevation unit  360  may upwardly or downwardly move the container  320  in a straight line. A height of the container  320  relative to the support unit  340  may be changed as the container  320  moves upwardly or downwardly. The elevation unit  360  may include a bracket  362 , a moving shaft  364 , and a driver  366 . The bracket  362  may be fixedly installed to an outer wall of the container  320  and the moving shaft  364  which is moved upwardly or downwardly by the driver  366  may be fixedly jointed to the bracket  362 . When the substrate W is loaded on or lifted from the support unit  340 , the container  320  may descend such that the support unit  340  protrudes upwardly from an upper portion of the container  320 . Furthermore, when the process is performed, a height of the container  320  may be adjusted such that the treating solution flows into a predetermined collection barrel  360  depending on a type of the treating solution supplied to the substrate W. Selectively, the elevation unit  360  may move the support unit  340  upwardly or downwardly. 
         [0054]    The supply unit  380  may supply the treating solution and cleaning particles on the substrate W. 
         [0055]    The supply unit  380  may include a solid supply unit  380   a  and a treating solution supply unit  380   b . The solid supply unit  380   a  may supply the cleaning particles on a top surface of the substrate W. The solid supply unit  380   a  may include a support shaft  384 , a nozzle arm  383 , a driving member  381 , and a solid nozzle  385 . 
         [0056]    The support shaft  384  may be disposed at one side of the container  320 . The support shaft  384  may have a rod form provided in its length direction which is a vertical direction. The support shaft  384  may be rotated, ascended and descended by a driving member  381 . In contrast, the support shaft  384  may be moved in a straight line along a horizontal direction, ascended and descended by the driving member  381 . The nozzle arm  383  may be fixedly jointed to a top end of the support shaft  384 . The nozzle arm  383  may support a solid nozzle  385 . A solid nozzle  385  may be placed at the end of the nozzle arm  383 . 
         [0057]    The solid nozzle  385  may supply cleaning particles provided from an outside to the substrate W. The cleaning particles may contain solid particles. Each of the solid particles may have a size of several micrometers, or a size of several tens or hundreds nanometers. 
         [0058]      FIG. 3  is a diagram schematically illustrating a solid nozzle of  FIG. 2 . Referring to  FIG. 3 , the solid nozzle  385  may supply the solid particles on the treating solution and may provide a shock wave to the substrate W. The solid nozzle  385  may include a nozzle unit  385   a  and a cleaning particle supply unit  385   b . The nozzle unit  385   a  may include an upper body  385   c  and a lower body  385   h . The upper body  385   c  may be provided in a cylinder form. A space may be defined in the upper body  385   c . The upper body  385   c  may be formed of a material capable of enduring the cleaning particles of the high pressure. The upper body  385   c  may be connected to the cleaning particle supply unit  385   b . The cleaning particles may be provided into the space of the upper body  385   c  via the cleaning particle supply unit  385   b.    
         [0059]    A discharge hole  385   d  may be formed at the upper body  385   c . The discharge hole  385   d  may be connected to the lower body  385   h . For example, the phase of the cleaning particles supplied in a high-pressure gas phase may be changed when passing through the discharge hole  385   d  and may be changed into fine solid particles. For example, the gas supplied to the discharge hole  385   d  may be a carbon dioxide gas and the solid particles may be formed of dry-ice. 
         [0060]    The lower body  385   h  may be connected to the upper body  385   c . A flow pathway  385   e  may be formed in the lower body  385   h . The flow pathway  385   e  may include an upper flow pathway  385   f  and a lower flow pathway  385   g . The upper flow pathway  385   f  may be formed to extend along a longitudinal direction of the nozzle unit  385   a . The upper flow pathway  385   f  may be provided such that its diameter is gradually decreased along the longitudinal direction. The lower flow pathway  385   g  may be connected to the upper flow pathway  385   f . The lower flow pathway  385   g  may be formed to extend along the longitudinal direction of the nozzle unit  385   a . The lower flow pathway  385   g  may be provided such that its diameter is gradually increased along the longitudinal direction. 
         [0061]    The cleaning particle supply unit  385   b  may be connected to a nozzle unit  385   a  and may supply the cleaning particles. For example, the cleaning particles may be supplied in a gas state when supplied to the nozzle unit  385   a . The supplied cleaning particles may be supplied to the nozzle unit  385   a  in a high-pressure state. When passing through the discharge hole  385   d , the cleaning particles supplied to the nozzle unit  385   a  may be changed from a gas phase to a solid phase. That is, the cleaning particles may be changed into the solid particles. For example, the supplied cleaning particles may be the carbon dioxide gas. After the carbon dioxide gas passes through the discharge holes  385   d  and is then changed into a dry-ice phase, the changed carbon dioxide ice may be collided to the substrate W. In contrast, the supplied cleaning particles may be an argon gas. 
         [0062]    The treating solution supply unit  380  may include a support shaft  386 , a nozzle arm  382 , and a treating solution nozzle  400 . The support shaft  386  may be disposed at one side of the container  320 . The support shaft  386  may have a rod form in which its length direction is an up-and-down direction. The support shaft  386  may be rotated, ascended and descended by a driving member  388 . In contrast, the support shaft  386  may be moved, ascended and descended in a straight line along a horizontal direction by the driving member  388 . The nozzle arm  382  may be fixedly jointed to a top end of the support shaft  386 . The nozzle arm  382  may support a treating solution nozzle  400 . The treating solution nozzle  400  may be placed at an end portion of the nozzle arm  382 . The treating solution nozzle  400  may supply the treating solution on an upper surface of the substrate W. For example, the supplied treating solutions may include, but not limited to, an organic solvent, chemical solution, rinsing solution, and the like. 
         [0063]    As described above, an embodiment of the inventive concept is exemplified as each of the solid supply unit  380   a  and the treating solution supply unit  380   b  includes a support shaft and a nozzle arm, independently. In contrast, a solid nozzle and a treating solution nozzle may be included in one nozzle arm. 
         [0064]      FIG. 4  is a diagram illustrating a solid nozzle according to another exemplary embodiment of the inventive concept. Referring to  FIG. 4 , a solid nozzle  585  may supply solid particles on the treating solution and may provide a shock wave to the substrate W. The solid nozzle  585  may include a nozzle unit  585   a , a cleaning particle supply unit  585   b , and a carrier gas supply unit  585   d . The nozzle unit  585   a  may include an upper body  585   e  and a lower body  585   f . The upper body  585   e  may be connected to the cleaning particle supply unit  585   b  and the carrier gas supply unit  585   d . The upper body  585   e  may be formed to extend in a length direction thereof. The upper body  585   e  may be formed such that a diameter thereof is gradually decreased along a length direction thereof. The lower body  585   f  may be connected to the upper body  585   e . The lower body  585   f  may be formed to extend in a length direction thereof. The lower body  585   f  may be formed such that a diameter thereof is gradually increased along a length direction thereof. 
         [0065]    The cleaning particle supply unit  585   b  may supply the cleaning particles to the nozzle unit. For example, the cleaning particles to be supplied may be supplied in a solid particle state. A size of the solid particles may be several micrometers or several or hundreds nanometers. The solid particles may be formed of a material soluble in the treating solution. The solid particles may be materials of which the gravity is 1 or less. For example, the solid particles may be plastic powder. 
         [0066]    The carrier gas supply unit  585   d  may supply a carrier gas to the nozzle unit  585   a . The carrier gas may be supplied in a high-pressure state. The high-pressure carrier gas may be mixed with the solid particles at the nozzle unit  585   a . Furthermore, the solid particles may pass through the lower body  585   f  together with the carrier gas and may be supplied on the treating solution. For example, the carrier gas to be supplied may be a helium gas. 
         [0067]      FIGS. 5 to 10  are diagrams sequentially illustrating a process for generating a shock wave on a substrate using solid particles. A process for generating a shock wave on a substrate W will be described with reference to  FIGS. 5 to 10 . 
         [0068]    The substrate treating apparatus  300  may supply a treating solution F to the substrate W while the solid particles S are supplied to the substrate W. In contrast, the substrate treating apparatus  300  may supply the treating solution to the substrate W before the solid particles S are supplied to the substrate W. When the treating solution F is supplied, a layer of the treating solution F may be formed on the substrate W. The solid particles S may be rapidly supplied to the substrate W. The solid particles S may collide with the layer of the treating solution F on the substrate W and may generate the shock wave at the treating solution F. The shock wave may be transmitted to the substrate W. Due to the generated shock wave, contamination materials and particles of the substrate W may be easily removed as illustrated in  FIG. 7 . After the solid particles S collide with the treating solution F, the solid particles S may be vaporized or liquefied as illustrated in  FIG. 8 . For example, the solid particle may be formed of dry-ice. Furthermore, in the case that the solid particles S are formed of a material soluble in the treating solution, the solid particle S may melt in the treating solution as illustrated in  FIG. 9 . Selectively, in the case that the solid particles S are materials of which the gravity is 1 or less, the solid particles S may remain at a floated state on the layer of the treating solution F as illustrated in  FIG. 10 . For example, the solid particles may be plastic powder. Remaining solid particles S may be removed together with the contamination materials and particles of the substrate W in a cleaning process afterward. 
         [0069]    According to an embodiment of the inventive concept, a substrate cleaning process may be performed using solid particles where a size thereof is several micrometers, several tens or hundreds nanometers, thereby improving an efficiency of the substrate cleaning process. 
         [0070]    Furthermore, According to an embodiment of the inventive concept, a substrate cleaning process may be performed by producing a shock wave using solid particles on a substrate, thereby improving an efficiency of the substrate cleaning process. 
         [0071]    While the inventive concepts have been described with reference to example embodiments, it will be apparent to those skilled in the art that various changes and modifications may be made without departing from the spirits and scopes of the inventive concepts. Therefore, it should be understood that the above embodiments are not limiting, but illustrative. Thus, the scopes of the inventive concepts are to be determined by the broadest permissible interpretation of the following claims and their equivalents, and shall not be restricted or limited by the foregoing description.