Abstract:
A device for measuring the quality of an operating substance and/or additive, in particular a reduction agent, stored in a tank, includes a reference container connected to the operating substance and/or the additive via a semi-permeable diaphragm, in which the reference container is filled with a medium which has a known osmotic pressure relative to the used operating substance and/or additive.

Description:
CROSS REFERENCE TO RELATED APPLICATION 
       [0001]    The present application is the national stage entry of International Patent Application No. PCT/EP2012/056186, filed on Apr. 4, 2012, which claims priority to Application No. DE 10 2011 076 496.8, filed in the Federal Republic of Germany on May 26, 2011. 
     
    
     BACKGROUND INFORMATION 
       [0002]    In order to comply with the more stringent exhaust gas legislation, nitrogen oxides contained in the exhaust gas must be reduced in internal combustion engines, in particular in self-igniting internal combustion engines. To carry out the necessary exhaust gas aftertreatment, a method based on selective catalytic reduction (SCR) has become very widely accepted. In the SCR method, the nitrogen oxides are reduced into nitrogen and water with the aid of an operating substance and/or additive, in particular a reduction agent. An aqueous urea solution, which is available, for example, under the trade name AdBlue, is often used as the operating substance and/or additive. Thermal decomposition of the urea produces the actual reduction agent, gaseous ammonia, NH 3 , in the exhaust gas system. The operating substance and/or additive is/are stored in a tank and injected into the exhaust gas system via a delivery or metering module. In this connection, it is always necessary for an adequate amount of reduction agent to be injected by the metering module. To determine the correct amount of the required operating substance and/or additive, the control unit must know the exact properties of the operating substance and/or additive. If the urea content of the frequently used aqueous urea solution is too low, for example, insufficient ammonia is formed in the exhaust gas system and the nitrogen oxides cannot be completely reduced. This has the consequence that the statutory exhaust gas limiting values are exceeded. Causes of an incorrect urea concentration may be, for example, filling an incorrect reduction agent into the tank or deliberately filling the tank with distilled water instead of the operating substance and/or additive due to its significantly lower price. Since the exhaust gas aftertreatment system must ensure compliance with the legal limiting values of nitrogen oxide emissions at all times, it is necessary that the exhaust gas aftertreatment system detects improperly filled operating substances and/or additives, and prevents their use. 
         [0003]    German Application No. DE 10 2007 059 853 describes a tank for storing an operating substance or additive, which is equipped with means for measuring the fill level and quality of the liquid in the tank. The measurement is carried out with the aid of an ultrasonic transducer which transmits ultrasonic signals and receives the signals reflected back. From the received ultrasound echoes, it is possible to calculate, among other things, the density of the liquid and the fill level with the aid of the knowledge of the temperature. By comparing the density with stored values, it is possible to infer the nature or quality of the liquid in the tank. 
         [0004]    Another approach for determining the quality of the operating substance and/or additive in the tank is to measure the efficiency of the SCR catalyst in reducing nitrogen oxides. The disadvantage of this method is that the discovery of a poor quality of the reduction agent is delayed, i.e., only after it is no longer possible to meet the exhaust gas limiting values, as well as the generally low accuracy of this measurement. 
         [0005]    All known methods from the related art for measuring the quality of an operating substance and/or additive in a tank exhibit relatively high complexity and expense. 
       SUMMARY 
       [0006]    According to the present invention, a device is described for measuring the quality of an operating substance and/or additive, in particular a reduction agent, stored in a tank, a reference container being connected to the operating substance and/or additive via a semi-permeable membrane, and the reference container being filled with a medium which has a known osmotic pressure relative to the used operating substance and/or additive. The relationship between the osmotic pressure of the concentration of a substance in a solvent compared to a pure solvent and the temperature is described by Van&#39;t Hoff&#39;s law: 
         [0000]    
       
      
       P 
       osmotic 
       =c·R·T  
      
     
         [0000]    where 
         [0007]    P osmotic  is the osmotic pressure, 
         [0008]    c is the number of all dissolved, dissociated and undissociated particles present, 
         [0009]    R is the universal gas constant, and 
         [0010]    T is the temperature in degrees Kelvin. 
         [0011]    Depending on the reference medium and tank contents, the osmotic pressure between the medium in the reference container and the operating substance and/or additive in the tank is positive, zero or negative. 
         [0012]    In the case of storing a reduction agent for selective catalytic reduction, the operating substance and/or additive is/are, in particular, an aqueous urea solution. An aqueous urea solution having a known concentration of urea may also be used as a reference medium in the reference container. Water is able to diffuse through the semi-permeable diaphragm back and forth between the reference container and the rest of the tank. Depending on the concentration of urea in the reference container and in the rest of the tank, a negative pressure, equal pressure or a positive pressure occurs in the reference container. If, for example, an aqueous urea solution of known concentration is present in the reference container, and if the tank is filled with water instead of the aqueous urea solution, a positive pressure builds up in the reference container by osmosis. 
         [0013]    This positive pressure may be ascertained using a pressure sensor attached to the reference container. A control unit which evaluates the signal from the pressure sensor may then take appropriate measures such as reducing the power of the drive or preventing the operation of the internal combustion engine. 
         [0014]    In one advantageous exemplary embodiment of the present invention, one or multiple flexible elements are attached to the reference container, which are deformed by the pressure change in the reference container and block the outlet of the tank due to this deformation. This ensures that an improperly filled operating substance and/or additive is/are prevented from entering the exhaust gas system. 
         [0015]    A pressure-related deformation, however, could also be used to activate a mechanical element for sealing the tank and/or activating a mechanical switch. 
         [0016]    If the reference container is intended to seal the tank outlet via a flexible element, it is advantageous to situate the reference container fixedly in the tank using suitable attachment means. However, if only one signal is generated from the reference container, be it via a pressure sensor or via a mechanical switch attached to the reference container, the reference container may also be situated loosely in the tank. 
         [0017]    In another advantageous exemplary embodiment, the reference container is not situated in the tank for storing the operating substance and/or additive itself, but instead in a line leading away from it. In this connection, the reference container is designed to be as small as possible, and is preferably situated at a location that is not readily accessible from the outside. This makes tampering with the reference container difficult. 
         [0018]    As a further protection against tampering from the outside but also to make the reference container frost-proof, the container may be reinforced by incorporated metal plates or fibers. It is particularly preferred that one or multiple displacement bodies are installed in the reference container for frost protection in order to be able to absorb an increase in volume caused by freezing contents of the container. In another advantageous exemplary embodiment, the frost protection is ensured by the fact that a reference medium is used having a freezing point below the lowest expected temperature. 
         [0019]    In another preferred exemplary embodiment, a dye is added to the reference medium in the reference container, which may be used for easily detecting if the container has been pierced. A piercing of the container would make a pressure equalization between the reference container and the tank possible and thus not allow the quality of the operating substance and/or additive in the tank to be measured. If a reference container, the reference medium of which contains a dye, is pierced, the dye enters the tank contents. The staining of the tank contents, which preferably is also evident as a staining of the exhaust gas of the internal combustion engine, makes it possible to easily detect the tampering. In another exemplary embodiment, the semi-permeable diaphragm of the reference container is designed to rupture when a pressure limit is exceeded. An improper filling would result in a rise in pressure in the reference container which is above the set pressure limit of the semi-permeable diaphragm and the dye contained in the reference medium would be released. 
         [0020]    In another preferred exemplary embodiment, measured values from sensors which are usually already present, such as a fill level sensor in the tank or a pressure sensor in the delivery module, are included in the monitoring of the reference container. Sloshing occurring in the tank when the vehicle is moved results in small fluctuations in the fill level of the liquid in the tank, which may also be measured via small pressure fluctuations in the reference container. If these pressure fluctuations are absent in the reference container, this indicates a tampering or a failed sensor. It is further preferred to select the reference medium in the reference container such that a positive or negative pressure permanently occurs in the reference container even when the correct operating substance and/or additive is/are present in the tank. This measured positive or negative pressure in the reference container is used to monitor the operation of the pressure sensor. 
         [0021]    Due to its simple design, the device according to the present invention for measuring the quality of an operating substance and/or additive stored in a tank allows a reliable and cost-effective measurement of the quality of the stored operating substance and/or additive. An improper filling is reliably detected and operation of the internal combustion engine with an incorrect or a low quality operating substance and/or additive may be prevented to ensure compliance with the statutory exhaust gas limiting values at all times. The possibility of sealing the tank outlet in the case of improper filling effectively protects the exhaust gas treatment system from possible damage by an improperly filled operating substance and/or additive. The device according to the present invention may be designed to be frost-proof in a simple way by using a temperature-adjusted reference medium and/or displacement bodies, which makes it possible to use the device in regions having low ambient temperatures without great complexity and additional costs. The possible security against tampering of the system in the other exemplary embodiments contributes to increased security compared to the systems known from the related art. 
         [0022]    Exemplary embodiments of the present invention are explained in greater detail below with reference to the accompanying drawings. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0023]      FIG. 1  shows a first exemplary embodiment of the device according to the present invention for measuring the quality of an operating substance and/or additive stored in a tank; in this exemplary embodiment, the reference container is situated in the tank. 
           [0024]      FIG. 2   a  shows the reference container of the device according to the present invention having a pressure sensor. 
           [0025]      FIG. 2   b  shows the reference container of the device according to the present invention having a mechanical switch. 
           [0026]      FIG. 3  shows another exemplary embodiment of the device according to the present invention in which the reference container is situated in the tank fixed above the tank outlet using a flexible element. 
           [0027]      FIG. 4  shows another exemplary embodiment of the device according to the present invention in which the reference container is situated on a line exiting the tank. 
       
    
    
     DETAILED DESCRIPTION 
       [0028]    A schematic representation of the device for measuring the quality of an operating substance and/or additive stored in a tank is derived from  FIG. 1 . 
         [0029]      FIG. 1  shows a tank  10  for storing an operating substance and/or additive  12 . In tank  10  are located a fill level sensor  14  and a reference container  20 . The operating substance and/or additive flow(s) via a line  16  to a metering module  40 . The reference container has a semi-permeable diaphragm  24 , through which water is able to diffuse between the tank and the reference container. The reference container is filled with a reference medium  22 . The osmotic pressure occurring between reference container  20  and tank  10  is dependent on operating substance and/or additive  12  in the tank and reference medium  22  used in reference container  20 . The pressure in reference container  20  is measured using a pressure sensor  32  and forwarded to a control unit  38 . If, for example, both tank  10  and reference container  20  are filled with an aqueous urea solution, both having the same urea concentration, the pressure is equalized. If, for example, tank  10  is now only filled with distilled water instead of an aqueous urea solution, water diffuses through semi-permeable diaphragm  24  from tank  10  into reference container  20  and the pressure in reference container  20  rises. If a limiting value is exceeded, control unit  38  may take suitable measures such as preventing the operation of the internal combustion engine or preventing a liquid which was improperly filled into the tank from being injected into the exhaust gas system by shutting down metering module  40 . 
         [0030]      FIG. 2   a  shows a detailed representation of the reference container of the device for measuring the quality of an operating substance and/or additive stored in a tank. 
         [0031]      FIG. 2   a  shows reference container  20 , into the wall  26  of which semi-permeable diaphragm  24  has been introduced. If an aqueous urea solution is used, this diaphragm  24  is, for example, permeable for water but not urea. In the interior of reference container  20  is located reference medium  22 , which, for example, may also be an aqueous urea solution. Since the eutectic aqueous urea solution, which is normally used, freezes at temperatures below −11° C., reference container  20  is preferably designed to be frost-proof. This may, for example, be carried out using reinforcements of walls  26  or by installing metal plates  28 . Walls  26  of reference container  20  may, however, also be reinforced by increasing the wall thickness or by incorporating fibers. The increase in volume occurring when the aqueous urea solution freezes may be compensated for by using a displacement body  30 . Displacement body  30  is designed to be elastic and is compressed by the ice. The pressure in reference container  20  is measured by a pressure sensor  32 , which is separated from reference medium  22  via a diaphragm  34  in the exemplary embodiment shown in  FIG. 2   a . If the pressure in reference container  20  is positive, diaphragm  34  is deflected upwards; if the pressure in reference container  20  is negative, it is deflected downwards. Diaphragm  34  prevents a corrosive reference medium  22 , such as an aqueous urea solution, from corroding sensor  32 . If a sensor  32  which is resistant to reference medium  22  is used, diaphragm  34  may also be omitted. 
         [0032]      FIG. 2   b  shows a detailed representation of the reference container having a mechanical switch. 
         [0033]      FIG. 2   b  shows reference container  20 , into the wall  26  of which semi-permeable diaphragm  24  has been introduced. For the case that an aqueous urea solution is used, this diaphragm  24  is, for example, permeable for water but not urea. Separated by a diaphragm  34  from the interior of reference container  20 , a mechanical switch  33  is situated on reference container  20  such that a deflection of diaphragm  34  activates the switch. In the interior of reference container  20  is located reference medium  22 , which, for example, may also be an aqueous urea solution. In the case of an aqueous urea solution as operating substance and/or additive  12 , the pressure would increase if distilled water was filled into the tank instead of an aqueous urea solution. The positive pressure occurring in the interior of reference container  20  due to filling the improper liquid into the tank deflects diaphragm  34  and hence activates mechanical switch  33 . Its signal may be used to take appropriate measures such as reducing the power of the internal combustion engine or preventing its operation. 
         [0034]      FIG. 3  shows another exemplary embodiment of the device according to the present invention in which the reference container is equipped with a flexible element. 
         [0035]    In the exemplary embodiment of the device according to the present invention shown in  FIG. 3  for measuring the quality of an operating substance and/or additive  12  stored in a tank, reference container  20  is fixedly situated in tank  10  above outlet  18  of the tank, via which operating substance and/or additive  12  exit(s) tank  10  and enter(s) line  16 . In housing wall  26 , reference container  20  has a semi-permeable diaphragm  24 , which is designed to be water-permeable if, for example, an aqueous urea solution is used as an operating substance and/or additive  12 . An aqueous urea solution may also be used as reference medium  22  in reference container  20 . Reference container  20  has at a position located directly above tank outlet  18  a flexible element  36  which may be deformed under pressure. In this example, if only distilled water is filled into the tank instead of an aqueous urea solution as an operating substance and/or additive  12 , the pressure increases in reference tank  20  due to osmosis. Due to the increased pressure, flexible element  36  is deformed and assumes the shape indicated in  FIG. 3  by reference numeral  37 . In this case, tank outlet  18  is blocked by flexible element  36 . This prevents an operating substance and/or additive  12  which has/have been improperly pumped into the tank from entering the exhaust gas system via line  16  and metering module  40 . Furthermore, control unit  38  is able to detect this error state via sensors already present in metering module  40 . Instead of flexible element  36  or  37 , tank outlet  18  may also be blocked by a flexible spring element or another mechanical means which is activated by a pressure difference in the reference container. 
         [0036]      FIG. 4  depicts another exemplary embodiment of the device according to the present invention in which the reference container is situated on a line  16  exiting tank  10 . 
         [0037]      FIG. 4  shows a tank  10  for storing an operating substance and/or additive  12  which flow(s) through tank outlet  18  and line  16  into delivery module  40 . A fill level sensor  14  and reference container  20  are situated on line  16 . Reference container  20  has a semi-permeable diaphragm  24 , which is in direct connection with operating substance and/or additive  12  in line  16 . Reference medium  22  is located in the interior of reference container  20 . The pressure in the interior of reference container  20  is ascertained by a pressure sensor  32  which, as well as fill level sensor  14 , transmits its measured value to a control unit  38 . When used in an SCR system, an aqueous urea solution is used, for example, both as operating substance and/or additive  12  as well as reference medium  22 . If, for example, tank  10  is improperly filled with distilled water, water diffuses from line  16  into the interior of reference container  20  and causes the pressure in the interior to increase. If the increase in pressure measured by sensor  32  exceeds a critical limiting value, control unit  38  may take suitable measures such as preventing the injection of an improperly filled operating substance and/or additive  12  into the exhaust gas treatment system by shutting down delivery module  40 . In order to verify the plausibility of the pressure values delivered by pressure sensor  32 , i.e., securing against tampering and/or failure of one or multiple sensors, control unit  38  may use additional data sources, such as fill level sensor  14  or sensors built into delivery module  40 . For example, movements of operating substance and/or additive  12  in tank  10 , which are detected by fill level sensor  14 , also result in minor pressure fluctuations which are detected by sensor  32 . Control unit  38  may combine the measured values from both sensors and infer the failure of and/or tampering with one of the sensors from the absence of pressure fluctuations or fill level fluctuations. Another possibility for verifying the sensor data in an SCR system using an aqueous urea solution is to use as reference medium  22  an aqueous urea solution having a changed urea concentration compared to the solution present in tank  10 . In the case of a proper filling of tank  10 , this also results in a positive pressure or negative pressure in reference container  20  which must be detected by the sensor  32 . A failure of detection of the positive pressure or negative pressure indicates a tampering with sensor  32  or reference container  20 . For example, a pierced reference container  20  would allow an unimpeded exchange of liquid between the interior of reference container  20  and tank  10 , making it impossible for a pressure difference to occur in any case. To prevent tampering with reference container  20 , it is advantageous to reinforce container walls  26 , for example by incorporating metal plates  28 , and/or to place reference container  20  at a position where access from the outside is very difficult. It is also advantageous to design reference container  20  to be as small as possible, since this makes it very difficult to access from the outside. A piercing of reference container  20  may be verified in one exemplary embodiment, for example, by adding a dye to reference medium  22 . If reference container  20  was pierced, dye would pass from the interior of reference container  20  into tank  10  or line  16  and stain tank contents  12 . This staining is preferably also detectable in the exhaust gas.