Abstract:
A method for forming a semiconductor device includes forming a carbon material on a substrate, forming a gate stack on the carbon material, removing a portion of the substrate to form at least one cavity defined by a portion of the carbon material and the substrate, and forming a conductive contact in the at least one cavity.

Description:
FIELD OF INVENTION 
       [0001]    The present invention relates to semiconductor graphene and carbon nanotube field effect transistor devices and to methods that allow the fabrication of contacts in graphene and carbon nanotube devices. 
       DESCRIPTION OF RELATED ART 
       [0002]    Semiconductor devices formed from silicon often include ion doped source and drain regions. It is desirable to form the source and drain regions proximate to the gate of the device to avoid a non-conductive region that may result in an undesirably high parasitic resistance in the device. It is also desirable to avoid forming source and drain regions under the gate that may result in an undesirably high parasitic capacitance in the device. 
         [0003]    Carbon devices may include a layer of carbon material such as, for example graphene or carbon nanotubes. Though carbon materials are not usually doped with ions, the location of the source and drain regions in carbon devices affect the parasitic resistance and capacitance of such devices. 
       BRIEF SUMMARY 
       [0004]    In one aspect of the present invention, a method for forming a semiconductor device includes forming a carbon material on a substrate, forming a gate stack on the carbon material, forming a spacer over on the gate stack and portions of the carbon material, removing exposed portions of the carbon material, removing exposed portions of the substrate to form cavities defined by the carbon material and the substrate, and forming conductive contacts in the cavities. 
         [0005]    In another aspect of the present invention, a semiconductor device includes a carbon layer disposed on a substrate, a gate stack disposed on a portion of the carbon layer, a first cavity defined by the carbon layer and the substrate, a second cavity defined by the carbon layer and the substrate, a source region including a first conductive contact disposed in the first cavity, a drain region including a second conductive contact disposed in the second cavity. 
         [0006]    In yet another aspect of the present invention, a method for forming a semiconductor device includes forming a carbon material on a substrate, forming a gate stack on the carbon material, removing a portion of the substrate to form at least one cavity defined by a portion of the carbon material and the substrate, and forming a conductive contact in the at least one cavity. 
     
    
     
       BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS 
         [0007]    The subject matter which is regarded as the invention is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The forgoing and other features, and advantages of the invention are apparent from the following detailed description taken in conjunction with the accompanying drawings in which: 
           [0008]      FIGS. 1-7  illustrate a side view of a method for forming a semiconductor device and the resultant semiconductor device. 
       
    
    
     DETAILED DESCRIPTION 
       [0009]      FIGS. 1-7  illustrate a side view of a method for forming a semiconductor device with graphene having source and drain regions that avoid undesirable parasitic resistance and capacitance in the device. 
         [0010]    Referring to  FIG. 1 , a carbon material  102  such as, for example, two-dimensional graphene material, graphene nanotube(s) material, or carbon nanotube(s) material is formed on a substrate  100 . The substrate  100  may include, for example, a silicon dioxide material or a silicon carbide material. 
         [0011]    The carbon material  102  may include a layer of graphene that may be formed by, for example, epitaxially forming a layer of graphene on a metallic foil such as, for example, copper (not shown) using a chemical vapor deposition process using methane and transferring the carbon material  102  to the substrate  100 . The carbon material  102  may also be formed by epitaxially forming graphene on a silicon carbide substrate using an annealing process that removes Si from the silicon carbide substrate resulting in a graphene monolayer. Alternatively, the carbon material  102  may include nanotubes that may be formed by, for example, a spincoating method or a chemical vapor deposition process. 
         [0012]    The following references include examples of methods that may be used for forming the carbon material  102 : X. Li et al. “Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils”, Science (2009), 324, 1312-1314; K. V. Emtsev et al., “Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide”, Nature Materials, (2009), 8, 203-207; Dai, H., “Carbon Nanotubes: Synthesis, Integration, and Properties”,  Acc. Chem. Res.,  35, 1035-1044, 2002; LeMieux, M., et al., “Self-Sorted, Aligned Nanotube Networks for Thin-Film Transistors”,  Science , vol. 321, pp. 101-104, 2008. 
         [0013]    Referring to  FIG. 2 , a dielectric layer  202  such as, for example a high-k dielectric material (e.g., hafnium silicate, zirconium silicate, hafnium dioxide, or zirconium dioxide) is formed on the carbon material  102  by, for example, an atomic layer deposition process. A metallic layer  204  is formed on the dielectric layer  202 . The metallic layer  204  may be formed from, for example, tantalum, tungsten, tantalum nitride, palladium, aluminum, or titanium nitride. 
         [0014]      FIG. 3  illustrates the resultant structure following the removal of portions of the metallic layer  204  and dielectric layer  202  that exposes portions of the carbon material  102  and forms a gate stack  302 . The gate stack  302  includes a portion of the dielectric layer  202  and the metallic layer  204 . The portions of the metallic layer  204  and the dielectric layer  202  may be removed by a suitable etching process such as for example, a reactive ion etching (RIE) and wet etch process. For example, a RIE process may be used to remove portions of the metallic layer  204 , and a wet etching process may be used to remove portions of the dielectric layer  202 . 
         [0015]      FIG. 4  illustrates the resultant structure following the formation of an encapsulating spacer  402  over the gate stack  302  and portions of the graphene layer  102 . The spacer  402  may be formed from, for example a nitride material or an oxide material such as hafnium oxide. 
         [0016]    Referring to  FIG. 5 , exposed portions of the carbon material  102  are removed by, for example, an oxygen plasma etching process that selectively removes the exposed carbon material  102  and exposes portions of the substrate  100 , but does not appreciably remove the spacer  402  material or the substrate  100  material. 
         [0017]      FIG. 6  illustrates the resultant structure following an isotropic etching of the substrate  100  that removes exposed portions of the substrate  100 . The etching process may include for example, an isotropic wet etching process. The etching forms cavities  602  defined by the carbon material  102  and the substrate  100 . The etching process is controlled to form the cavities  602  under the spacer  402 . 
         [0018]      FIG. 7  illustrates a device  700  that is formed following the formation of conductive contacts  702 . The conductive contacts form a source region (S)  703  and a drain region (D)  705  in the cavities  602  (of  FIG. 6 ). The conductive contacts  702  may be formed by, for example, an atomic layer deposition process followed by a chemical vapor deposition process of a conductive metal such as, copper, aluminum, palladium, or silver. 
         [0019]    The device  700  includes the carbon material  102  disposed on the substrate  100 , the gate stack  302  including the dielectric layer  202  disposed on the carbon material  102 , the metallic gate material  204  that forms a gate (G)  706  disposed on the dielectric layer  202 , and the conductive contacts  702  that form the source and drain regions  703  and  705 . 
         [0020]    The isotropic etching of the substrate  100  discussed above in  FIG. 6 , may be controlled to effect the geometry of the cavities  602 . Though the illustrated embodiment includes cavities  602  that are aligned with the longitudinal edges  704  of the gate stack  302 , it may be desirable to “overlap” the device  700  by controlling the isotropic etching process to extend the cavities  602  under the gate stack  302 , or “underlap” the device  700  by forming smaller cavities  602  that do not extend to the longitudinal edges  702  of the gate stack  302   
         [0021]    The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, element components, and/or groups thereof. 
         [0022]    The corresponding structures, materials, acts, and equivalents of all means or step plus function elements in the claims below are intended to include any structure, material, or act for performing the function in combination with other claimed elements as specifically claimed. The description of the present invention has been presented for purposes of illustration and description, but is not intended to be exhaustive or limited to the invention in the form disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the invention. The embodiment was chosen and described in order to best explain the principles of the invention and the practical application, and to enable others of ordinary skill in the art to understand the invention for various embodiments with various modifications as are suited to the particular use contemplated 
         [0023]    The flows depicted herein are just one example. There may be many variations to this diagram or the steps (or operations) described therein without departing from the spirit of the invention. For instance, the steps may be performed in a differing order or steps may be added, deleted or modified. All of these variations are considered a part of the claimed invention. 
         [0024]    While the preferred embodiment to the invention had been described, it will be understood that those skilled in the art, both now and in the future, may make various improvements and enhancements which fall within the scope of the claims which follow. These claims should be construed to maintain the proper protection for the invention first described.