Abstract:
A device and method for producing a reformate fuel from a hydrocarbon gas source. The invention enables the conversion of a dilute hydrocarbon gas into a more easily consumable reformate fuel. Gases having low concentrations of hydrocarbons are concentrated using a concentrator into a gaseous or liquid concentrated VOC fuel. The concentrated VOC fuel is then converted into a reformate using a reformer. The reformate is more easily consumed by an energy conversion device such as a combustion engine, fuel cell, sterling engine or similar device that converts chemical energy into kinetic or electrical energy. The reformer enables complex hydrocarbon fuels that are not normally suitable for use in an energy conversion device to be converted into a reformate. The reformate may be directly supplied into the energy conversion device.

Description:
RELATED APPLICATIONS 
     This application is a divisional of application Ser. No. 10/543,425, filed May 10, 2006, which is the National Stage of International Application number PCT/US03/019416, filed Jun. 20, 2003, each of the entire contents of which is hereby incorporated by reference. 
    
    
     BACKGROUND 
     Field of the Invention 
     The present invention is directed to a method and device for converting Volatile Organic Compounds (VOC) into energy. More specifically, the invention relates to a method and device that concentrates a dilute hydrocarbon gas using a concentrator into a gaseous or liquid concentrated fuel. The concentrated fuel is then converted into a reformate using a reformer and converted into energy through an energy conversion device. 
     Background of the Invention 
     Various manufacturing, agricultural, contamination remediation and industrial processes produce a waste gas stream having dilute hydrocarbon concentrations. Some applications include those where the VOC is entrained in a solid or liquid media such as contaminated soil or water. The VOC can be converted to gas and separated from the solid or liquid media. Other processes produce or contain gaseous VOC. A number of processes exist to burn or oxidize the VOC, but the present invention is directed to recovering energy. If the concentration or purity of the VOC is sufficiently great and they are suitable to operate an Energy Conversion Device (ECD), they may be directly supplied to the ECD. In other cases, these dilute hydrocarbon concentrations are sometimes insufficient in their energy content to efficiently operate an ECD. ECDs include devices that convert chemical energy into electrical or kinetic energy such as combustion engines (internal or external), Stirling cycle engines, gas turbines, or fuel cells. In other situations, the waste gas stream has sufficient energy content to operate an ECD, but the form of the hydrocarbon is such that the ECD requires extensive modification to operate using the waste gas directly. For example, the waste gas may include complex hydrocarbons of varying concentrations or particulates. These gases may harm the ECD if they are not treated or converted to reformate. 
     Manufacturing processes that produce waste gas streams with a dilute hydrocarbon concentration are currently flared or burned or supplied to an ECD as part of the combustion air. Flaring the waste gas does not return any energy. Burning the waste gas produces heat. Recovering electrical or kinetic energy is generally much more valuable than recovered heat energy. GB patent application 2364257, published Jan. 1, 2002, and incorporated herein by reference, splits a gas stream having VOC into two streams. The first stream is directed to the combustion air intake of an engine and the second stream is directed to a combustion unit. Exhaust heat from the engine mixes with and combusts the second stream. This reference neither teaches concentrating the VOC nor directing the VOC to the fuel intake of the engine. WO9530470, published Nov. 16, 1995, and incorporated herein by reference, teaches a device to burn VOC in an engine by having two adsorption/desorption units so that the waste gas stream and engine may operate independently of one another. The first unit may collect and concentrate VOC as needed and the second unit supplies VOC to the engine as needed. This reference and the GB reference leave the VOC in the combustion air and do not feed the VOC to the fuel intake of the engine. US 2002/0100277 published Aug. 1, 2002, and incorporated herein by reference also teaches directing VOC to an internal combustion engine, but the VOC is not concentrated by a device. Their concentration is based on the vapor pressure of the VOC in the container. VOC not directed to the engine are condensed into a liquid by a chiller, but these liquefied VOC is not supplied to the engine as a fuel. None of these references teach reforming the concentrated VOC. 
     It is known that waste gases can be directly supplied to the combustion or exhaust air of an engine. One commercially available system supplies waste gases from an industrial operation to a turbine engine. In a paper by Neill and Gunter, VOC Destruction using Combustion Turbines, published September 2002, and incorporated herein by reference, describes a device that combines waste VOC with natural gas to operate a gas turbine. The gas turbine produces electricity for the facility. The waste gases come directly from the exhaust air of the industrial operation and are supplied to the engine as part of the combustion air. The turbine engine has a separate fuel source to supply the majority of the fuel. The exhaust air provides a relatively low (200 to 5000 ppm of unburned hydrocarbons and VOC) percentage of the energy content needed to operate the engine. Devices like this require an external fuel supply as part of the normal operation of the device. The external fuel supply is not merely a part of start-up or load leveling operation. These references teach directly supplying VOC to the engine without filtering or reforming and require an engine capable of consuming the VOC. By directing the VOC to the combustion air, a very large engine/generator is needed. The example given in Neill and Gunter is a 20 MW turbine to abate 150,000 Standard Cubic Feet per Minute (scfm) of air. 
     U.S. Pat. No. 5,451,249, issued Sep. 19, 1995, and incorporated herein by reference, teaches a device and method to supply a gas stream from a landfill to be used as the fuel source of a fuel cell. The natural gas component of the landfill gas is desirable and the VOC contained in the landfill gas is removed and is not used to supply fuel to the fuel cell. The U.S. Pat. No. 5,451,249, describes heavy hydrocarbons as contaminant fractions that must be removed from the gas stream prior to reforming. Rather than teaching that the VOC is a contaminant, the present invention utilizes these hydrocarbons as the feedstock for the reformer. 
     The present invention is directed to a device and method to utilize the energy from waste VOC by converting the VOC into reformate for easier processing by the ECD. The present invention is capable of producing higher value kinetic or electrical energy from waste gases. The dilute VOC gas stream are organic compounds that evaporate readily into air may contain straight chain, branched, aromatic, or oxygenated hydrocarbons. The invention has the dual advantage of abating the hydrocarbons while producing electricity. More specifically, the dilute VOC presently considered waste products are reclaimed from the gas stream and used to generate electricity in a fuel cell, or via an internal or external combustion engine, a Stirling cycle engine, a gas turbine or another ECD that can produce electricity or kinetic energy. The invention is an energy efficient method to utilize the hydrocarbons entrained in the gas stream present in, or exhausted from, manufacturing, industrial, agricultural, environmental, or refinery processes. 
     SUMMARY OF THE INVENTION 
     The present invention provides for a device and method for producing a reformate. The device includes a concentrator that concentrates a dilute VOC gas stream. The concentrated VOC is then processed by a reformer into a reformate that is suitable to operate an ECD. The device is operated by adsorbing the dilute VOC onto an adsorbent media within a concentrator. The concentrator increases the concentration of VOC per unit volume. The adsorbed VOC is then desorbed to form a concentrated VOC fuel. The concentrated VOC fuel may be either liquefied VOC or a gaseous concentrated VOC fuel. The concentrated VOC fuel is then directed to a reformer to be converted into reformate. The procedure provides a process that efficiently utilizes the energy capacity within the dilute VOC gas stream. 
     Most industrial concentrators desorb with hot air. Because of the risk associated with allowing the concentration of hydrocarbons to approach the Lower Explosion Limit (about 1½% hydrocarbon by volume), the concentrations associated with gases in these devices never become sufficiently fuel rich for the desorbate to act as the primary fuel for an ECD. As described in the Background of the Invention, the dilute hydrocarbons are merely supplied to an engine as part of the combustion air. The engine requires a separate fuel supply to operate. Further, many waste gases are not suitable to be used as fuel in the ECD. By reforming these gases, they can be converted into a reformate which is more easily consumed by the ECD. 
     The device receives waste gas from a manufacturing or other process. If the gas is prone to contain particulates, it is filtered through a multiple stage filtration device prior to being concentrated. Then, the gas is directed into an adsorption chamber where the VOC is removed from the waste stream onto an adsorbent material. The adsorbent material is isolated from the VOC laden gas source and heated to release, or desorb, the VOC at regular intervals. The timing of the desorb cycle is such that the level of VOC saturation on the adsorbent material does not exceed a predetermined level. Heating the VOC laden adsorbent material causes the VOC to flash to high temperature vapor, which is then converted to reformate and directed to a fuel cell, engine or other type of ECD. A fuel cooler or condenser may be used to further process the fuel stream as necessary to prepare the fuel for introduction into the ECD. The water and CO 2  gases resulting from oxidation in the ECD are exhausted to the atmosphere. A control system is used to monitor and control the sequence. 
     A variety of ECDs may be utilized to convert the reformate into energy. Generators may be used to convert kinetic energy into electricity. In one embodiment, the dilute VOC laden gas stream passes through optional multiple stage particulate filters and an adsorption/desorption concentrator. VOC is stripped from the gas and adheres to the adsorbent media. The clean gas is vented to atmosphere or used elsewhere in the process, and inert gas passes over the adsorbent material to desorb the VOC. The inert gas-VOC mixture is routed to a condenser where it is cooled to condense the VOC. The inert gas is then recycled back to the desorption chamber. The cooled VOC, now condensed into a liquid, is directed to a reformer to convert the VOC to H 2  gas and oxides of carbon. The gaseous fuel is then directed to the ECD. 
     In an alternative embodiment, the VOC laden gas stream passes through optional multiple stage particulate filters and an adsorption/desorption concentrator. VOC is stripped from the gas and adhere to the adsorbent media. The clean gas is vented to atmosphere or used elsewhere in the process and a sweep gas passes over the adsorbent material to desorb the adhered VOC. The sweep gas may be gases that do not react with or oxidize the adsorbed VOC or the adsorption/desorption concentrator and include steam, inert gas, combustion products, or a fuel such as methane or another alkane. The concentrated sweep gas-VOC mixture then passes into a reformer to convert the hydrocarbons into H 2  gas and oxides of carbon. The reformate is directed to the ECD. 
     In another embodiment, the VOC laden gas stream passes through optional multiple stage particulate filters and an adsorption/desorption concentrator. VOC is stripped from the gas and adhere to the adsorbent media. The clean gas is vented to atmosphere or used elsewhere in the process and a sweep gas passes over the adsorbent material to desorb the adhered VOC. The concentrated sweep gas-VOC mixture then passes into a reformer to convert the hydrocarbons into H 2  gas and oxides of carbon. The reformate is then cooled in a fuel cooler. The cooled gaseous fuel is directed to the ECD. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  illustrates a device for removing dilute VOC from a gas stream and concentrating them into a high temperature gaseous fuel consisting of H 2 , CO, and various inert gases such as CO 2 , nitrogen, and water. 
         FIG. 2  illustrates an alternative device for removing dilute VOC from a gas stream and concentrating them into a high temperature gaseous fuel consisting of H 2 , CO, and various inert gases such as CO 2 , nitrogen, and water. 
         FIG. 3  illustrates a device for removing dilute VOC from a gas stream and concentrating them into a low temperature gaseous fuel consisting of H 2 , CO, and various inert gases such as CO 2 , nitrogen, and water. 
     
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     The present invention is illustrated in a series of drawings where like elements have the same suffix, but the initial number matches the figure reference. A table of the various elements and reference numbers is reproduced below to aid in understanding the invention: 
     
       
         
               
               
               
               
               
             
           
               
                   
                   
               
               
                   
                 ELEMENT 
                 FIG. 1 
                 FIG. 2 
                 FIG. 3 
               
               
                   
                   
               
             
             
               
                   
                 DEVICE 
                 100 
                 200 
                 300 
               
               
                   
                 SOURCE 
                 101 
                 201 
                 301 
               
               
                   
                 DAMPER 
                 102 
                 202 
                 302 
               
               
                   
                 DAMPER 
                 103 
                 203 
                 303 
               
               
                   
                 FILTERS 
                 110 
                 210 
                 310 
               
               
                   
                 FAN 
                 115 
                 215 
                 315 
               
               
                   
                 CONCENTRATOR 
                 120 
                 220 
                 320 
               
               
                   
                 LINE 
                 121 
                 221 
                 321 
               
               
                   
                 VENT 
                 122 
                 222 
                 322 
               
               
                   
                 OUTLET 
                 123 
                 223 
                 323 
               
               
                   
                 FAN 
                 125 
               
               
                   
                 LINE 
                 129 
               
               
                   
                 CONDENSER 
                 130 
               
               
                   
                 LINE 
                 131 
               
               
                   
                 REFORMER 
                 140 
                 240 
                 340 
               
               
                   
                 LINE 
                 141 
                 241 
                 341 
               
               
                   
                 INLET 
                 142 
                 242 
                 342 
               
               
                   
                 LINE 
                 143 
                 243 
                 343 
               
               
                   
                 INLET 
                 144 
                 244 
                 344 
               
               
                   
                 LINE 
                 145 
                 245 
                 345 
               
               
                   
                 FUEL COOLER 
                   
                   
                 350 
               
               
                   
                 LINE 
                   
                   
                 351 
               
               
                   
                 ECD 
                 160 
                 260 
                 360 
               
               
                   
                 INLET 
                 161 
                 261 
                 361 
               
               
                   
                 OUTLET 
                 162 
                 262 
                 362 
               
               
                   
                 OUTPUT 
                 163 
                 263 
                 363 
               
               
                   
                 SWITCHGEAR 
                 170 
                 270 
                 370 
               
               
                   
                 CONNECTOR 
                 171 
                 271 
                 371 
               
               
                   
                   
               
             
          
         
       
     
     In each embodiment of the invention, VOC is reduced into hydrogen and oxides of carbon. The procedure provides a process that ultimately utilizes the hydrocarbons contained in the VOC to extract energy. The device reduces air emissions while using the multi-component solvents separated from the dilute VOC gas stream as fuel to produce electricity or kinetic energy. 
     In one embodiment, a dilute VOC gas stream from a manufacturing process is filtered through a multiple stage filtration system if particulate material is entrained within the gas stream. Then, the gas is directed into an adsorption chamber where the VOC is removed from the waste stream onto an adsorbent media. The adsorbent media is isolated from the VOC laden gas source and heated to release, or desorb, the VOC at regular intervals. The timing of the desorb cycle is such that the level of VOC saturation on the adsorbent media does not exceed a predetermined level. Heating the VOC laden adsorbent media causes the VOC to flash to high temperature vapor, which is then directed to a reformer, and then to an ECD that can be either an engine or fuel cell. Engines may be used to power equipment or to operate generators to produce electricity. In an alternative embodiment, a sweep gas passes over the adsorbent media to desorb the adhered VOC. The sweep gas may be steam, inert gas, combustion products, or another fuel such as methane or another alkane. The concentrated sweep gas-VOC mixture then passes into a reformer. In another embodiment, the reformate is cooled before introduction into the ECD. The water and CO 2  gases resulting from oxidation in the ECD are exhausted to the atmosphere. A control system is used to monitor and control the sequence. 
       FIG. 1  illustrates a first embodiment of a device  100  to remove VOC from the effluent gas stream of a manufacturing process and convert the VOC into a fuel that can be used to generate electricity. The VOC treatment begins at the VOC laden gas source  101 , which allows VOC laden gas to pass through normally open damper  102  to the inlet of optional multiple stage particulate filters  110 . The damper  102  directs the dilute VOC gas stream to be processed by the device  100 . Normally closed bypass damper  103  allows temporary exhaustion to the atmosphere when the exhaust gas treatment device  100  is not operating. A booster fan  115  directs the filtered gas stream to the inlet of the adsorption/desorption concentrator  120 . The dilute VOC gas stream enters an adsorption portion of the concentrator  120  where the VOC adheres to the adsorbent media as the gas passes through the concentrator  120 . Exhaust vent  122  allows the process gas, now cleaned of VOC, to vent to the atmosphere or be redirected for use within the process or into another manufacturing process. The adsorbent media can be any commercially available adsorbent, such as activated carbon, zeolite, synthetic resin or mixtures thereof. The VOC laden adsorbent media, in a continuous loop, are directed to the desorption portion of the concentrator  120  where the entrained VOC is desorbed by heating the adsorbent media and passing an inert sweep gas, such as nitrogen, through the concentrator  120 . The VOC is entrained in the sweep gas and proceeds out of the concentrator  120  via outlet  123  to a condenser  130 . The condenser  130  cools the inert gas to a temperature, which is below the flash temperature of the VOC but above the condensation temperature of the inert gas, thereby separating the VOC (liquid) from the inert gas (gaseous) in the condenser  130 . The inert gas is recycled through line  129  to fan  125  and through inlet line  121  into the desorption portion of the condenser  130 . Nitrogen or another inert gas, with a condensing temperature significantly below the condensing temperature of the VOC, will be used to ensure adequate separation. The VOC, now in liquid form, exits the condenser through outlet line  131 , and flow to reformer  140 . 
     The reformer  140  breaks down the VOC into H 2 , CO, CO 2 , and water through a partial oxidation process such as Auto Thermal Reforming (ATR). Process water for the fuel processor enters through water inlet  142 . Air is added through inlet line  141 . Supplemental fuel, such as natural gas, is available through inlet line  144 . Controls for the reformer  140  regulate the airflow in such a way as to maximize the production of H 2  and CO, and minimize the production of completely oxidized byproducts while maintaining thermal equilibrium. Water is condensed from the fuel stream after partial oxidation, and exits the fuel processor through drain line  143 . The processed fuel, H 2  and CO, exits the fuel processor through line  145  to the inlet of the ECD  160 , in this case, either a fuel cell or an engine. Additional air for oxidation within the ECD  160  is provided through inlet  161 , which may be the redirected clean air from the vent  122 . Air, CO 2 , and water vapor exit the ECD  160  through outlet  162 . The power output  163  connects to electrical switchgear  170 . If the electrical power is produced by a fuel cell, the DC power is converted to AC power and stepped up to make it compatible with the facility&#39;s internal power grid. If the ECD  160  is a Stirling cycle engine, the AC power produced is stepped up via the switchgear. The connection to the facility&#39;s power grid, a protected bus that enables the device  100  to be self-supporting for emergency shutdown, is through connector  171 . 
     While the device  100  is capable of operating on supplemental fuel, the amount of supplemental fuel added through valve  164  will be substantially below 90% and preferably near 0%. The device  100  is designed to operate completely on the energy content of the VOC fuel. Supplemental fuel is generally used in the initial device  100  start-up or when the output of the dilute VOC gas source falls below the efficient operation of device  100 . Enabling the operation of device  100  exclusively on supplemental fuel provides redundant back-up power for the facility employing the device and is helpful in justifying the installation cost of the device. 
     The device may be scaled to accommodate large or small gas streams. In one application an automotive paint booth was ducted to device  100 . The booth provided between 2000 and 6500 scfm of diluted VOC gas in air when it was fully operational. This dilute VOC gas stream was between 10 and 1000 ppm of aromatics such as xylene, straight chains such as heptane, and oxygenated hydrocarbons such as butyl acetate. At this concentration, the dilute VOC is below the Lower Explosion Limit of VOC in air. 
     Concentrator  120  increases the concentration of VOC to greater than 15,000 PPM and preferably to more then 200,000 PPM. Because the concentrated VOC is entrained in inert gas and not air, the risk of explosion is no greater than that of a pressurized fuel line. Other applications for the present invention include the capture of formaldehyde and acetic acid released during the manufacture of ethanol or the VOC emitted in baking. VOC that are entrained in soil or water can be evolved into a dilute VOC gas stream that is then supplied to device  100  for processing. In another application, the device could be used to capture gasoline vapors vented from underground or above ground tanks, tanker trucks or ships or other vessels during filling or servicing. Many other applications that involve dilute VOC will be readily apparent to those skilled in the art and are contemplated by this invention. 
       FIG. 2  illustrates another embodiment of a device  200  to remove VOC from the effluent gas stream of a manufacturing process and convert the VOC into a fuel that can be used to generate electricity. The VOC treatment begins at the VOC laden gas source  201 , which allows the VOC laden gas stream to pass through normally open damper  202  to the inlet of an optional multiple stage particulate filters  210 . Normally closed bypass damper  203  allows temporary exhaustion to the atmosphere when the exhaust gas treatment device is not operating. A booster fan  215  directs the filtered gas stream to the inlet of the concentrator  220 . The gas stream first enters an adsorption portion of concentrator  220  where the VOC adheres to the adsorbent media as the gas passes through the concentrator  220 . The adsorbent media can be any commercially available adsorbent, such as activated carbon, zeolite, synthetic resin or mixtures thereof. The VOC laden adsorbent media, in a continuous loop, are directed to a desorption portion of concentrator  220  where 200-600° F. steam from an external steam generator or boiler device enters the concentrator  220  through inlet line  221  to heat the adsorbent media and vaporize the VOC to remove them (desorb) from the adsorbent media. Alternatively, a sweep gas composed of inert combustion products or a gaseous fuel such as methane or another alkane may be used as a carrier of the desorbed VOC. An additional heat source (not shown) may be required for the desorption portion of the concentrator  220 . Exhaust vent  222  allows the process gas, now cleaned of VOC, to vent to the atmosphere or be redirected for use within the process or into another manufacturing process. The VOC, now in a gaseous form and entrained in a sweep gas, exit the concentrator  220  as a concentrated fuel via outlet  223  that directs it to a reformer  240 . 
     The reformer  240  breaks down the VOC into H 2 , CO, CO 2 , and water through a partial oxidation process such as Auto Thermal Reforming (ATR). If necessary, additional process water for the fuel processor enters through water inlet  242 . Air is added through inlet line  241 . Supplemental fuel, such as natural gas, is available through inlet line  244 . Controls for the reformer  240  regulate the airflow in such a way as to maximize the production of H 2  and CO, and minimize the production of completely oxidized byproducts while maintaining thermal equilibrium. Water is condensed from the fuel stream after partial oxidation, and exits the fuel processor through drain line  243 . The processed fuel, H 2  and CO, exits the fuel processor through line  245  to the inlet of the ECD  260 , in this case, either a fuel cell or an engine. Additional air for oxidation within the ECD is provided through inlet  261 , which may be the redirected clean air from the vent  222 . Excess air, CO 2 , and water vapor exit the ECD through outlet  262 . The power output  263  connects to electrical switchgear  270 . If the electrical power is produced by a fuel cell, the DC power is converted to AC power and stepped up to make it compatible with the facility&#39;s internal power grid. If the ECD  260  is a Stirling cycle engine, the AC power produced is stepped up via the switchgear. The connection to the facility&#39;s power grid, a protected bus that enables the device  200  to be self-supporting for emergency shutdown, is through connector  271 . 
       FIG. 3  illustrates another embodiment of a device  300  to remove VOC from the effluent gas stream of a manufacturing process and convert the VOC into a fuel that can be used to generate electricity. The VOC treatment begins at the VOC laden gas source  301 , which allows the VOC laden gas stream to pass through normally open damper  302  to the inlet of an optional multiple stage particulate filters  310 . Normally closed bypass damper  303  allows temporary exhaustion to the atmosphere when the exhaust gas treatment device is not operating. A booster fan  315  directs the filtered gas stream to the inlet of the adsorption/desorption concentrator  320 . The gas stream first enters an adsorption portion of the concentrator  320  where the VOC adheres to the adsorbent media as the gas passes through the concentrator  320 . The adsorbent media can be any commercially available adsorbent, such as activated carbon, zeolite, or synthetic resin. The VOC laden adsorbent media, in a continuous loop, are directed to the desorption portion of the concentrator  320  where 200-600° F. steam from an external steam generator or boiler system enters the concentrator  320  through inlet line  321  to heat the adsorbent media and vaporize the VOC to remove them (desorb) from the adsorbent media. Alternatively, a sweep gas composed of inert combustion products or a gaseous fuel such as methane or another alkane may be used as a carrier of the desorbed VOC. If natural gas is used, sulfur scrubbers may be needed to remove sulfur and other materials that may contaminate the adsorbent media. An additional heat source (not shown) may be required for the desorption portion of the concentrator  320 . Exhaust vent  322  allows the process gas, now cleaned of VOC, to vent to the atmosphere or be redirected for use within the process or into another manufacturing process. The VOC, now in a gaseous form and entrained in the sweep gas, exit the adsorption/desorption concentrator  320  via outlet  323  and are directed to a reformer  340 . 
     The reformer  340  breaks down the VOC into H 2 , CO, CO 2 , and water through a partial oxidation process such as Auto Thermal Reforming (ATR). If necessary, additional process water for the fuel processor enters through water inlet  342 . Air is added through inlet line  341 . Supplemental fuel, such as natural gas, is available through inlet line  344 . Controls for the reformer  340  regulate the airflow in such a way as to maximize the production of H 2  and CO, and minimize the production of completely oxidized byproducts while maintaining thermal equilibrium. Water is condensed from the fuel stream after partial oxidation, and exits the fuel processor through drain line  343 . The processed fuel, H 2  and CO, exits the fuel processor through line  345  to the inlet of a fuel cooler  350 , where it is cooled to a useable temperature. The fuel exits the cooler via valve  351  and is directed to the inlet of the ECD  360 , in this case, either a fuel cell or an engine. Additional air for oxidation within the ECD is provided through inlet  361 , which may be the redirected clean air from the vent  322 . Excess air, CO 2 , and water vapor exit the ECD through outlet  362 . The power output  363  connects to electrical switchgear  370 . If the electrical power is produced by a fuel cell, the DC power is converted to AC power and stepped up to make it compatible with the facility&#39;s internal power grid. If the ECD  360  is an engine, the AC power produced is stepped up via the switchgear. The connection to the facility&#39;s power grid, a protected bus that enables the device  300  to be self-supporting for emergency shutdown, is through connector  371 . 
     The above descriptions of the process identify certain preferred embodiments, which are not meant to be limiting in the application of the devices described. 
     Each embodiment references an optional multiple stage filtration system. This filter is intended to remove any organic and inorganic particulates that may contaminate the ECD or the reformer. Some VOC sources may not contain particulates, and some ECDs may have tolerance for some particulates, therefore, the filtration system may not be needed in some applications of the process. 
     The concentrator is described as a moving system in which the adsorbent material is transported from adsorption portions to desorption portions. It is recognized that this can be accomplished by a fluidized bed system or a system of adsorbent material attached to a rotating wheel. Also, the concentrator could be configured such that the adsorbent material is arranged in fixed beds and adsorption and desorption are variously alternated by controlling valves that direct the source gas flow and effluent fuel flow. The concentrator should be capable of desorbing VOC in a non-oxidizing environment, of separating the desorbed effluent from the clean gas leaving the adsorber, and be capable of concentrating the VOC such that the desorbed effluent has a hydrocarbon concentration above 15,000 PPM VOC. The sweep gases can be inert gases, steam, or fuel such as methane or another alkane, such that the sweep gas does not contain free oxygen, which could react in the desorption step with the hydrocarbons present in the device. 
     The ATR Reformer also may contain various alternatives. Auto Thermal reforming is made up of two process steps: partial oxidation and steam reforming. A simple steam reformer may be used for simple VOC fueling some ECDs, but more complex reforming, utilizing water-gas shift reactions and/or preferential oxidation, may be necessary for certain generators such as Proton Exchange Membrane fuel cells. Also, plasma arc decomposition may be suitable for some fuels. 
     It will be apparent that the device described in this invention is constructed from commercially available components, which when operated in the particular combinations described above, form a device that generates electricity from the waste gas stream of certain manufacturing processes. The embodiments described above result in a variety of fuel types to be used in fuel cells, engines, turbines, or other ECDs including: reformed hot gaseous fuel, and reformed cold gaseous fuel. The fuel desired will direct the choice of components in the device. 
     The embodiments of the invention and the types of fuel described above are not intended to limit the application of the invention. The components of the device can be recombined in other variations without departing from the concept of this invention. It is not intended to limit the application of the invention except as required by the following claims. 
     Various preferred embodiments of the invention have been described in fulfillment of the various objects of the invention. It should be recognized that these embodiments are merely illustrative of the principles of the invention. Numerous modifications and adaptations thereof will be readily apparent to those skilled in the art without departing from the spirit and scope of the present invention.