Abstract:
A contact interface having a substantially annular silicide ring along sides of a depression formed in an active surface of the semiconductor substrate, wherein the depression is formed by an etching process to form a contact opening through a dielectric layer. The contact interface is formed by depositing a layer of conductive material, such as titanium, with a high bias power IMP deposition. The conductive material is turned to a silicide by an annealing process, thereby forming the contact interface.

Description:
BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to a contact interface within a contact opening for a shallow junction device, which contact interface is in electrical communication with an active surface of a semiconductor substrate, and methods of forming the same. More particularly, the present invention relates to altering an Ionized Metal Plasma (“IMP”) process to form a contact interface having a substantially continuous profile along sides of a depression formed in the active surface of the semiconductor substrate, wherein the depression is formed by an etching process to form a contact opening through a dielectric layer. 
     2. State of the Art 
     In the processing of integrated circuits, electrical contact must be made to isolated active-device regions formed within a semiconductor substrate, such a silicon wafer. Such active-device regions may include p-type and n-type source and drain regions used in the production of NMOS, PMOS, and CMOS structures for production of DRAM chips and the like. The active-device regions are connected by conductive paths or lines which are fabricated above an insulative or dielectric material covering a surface of the semiconductor substrate. To provide electrical connection between a conductive path and active-device regions, openings in the insulative material are generally provided to enable a deposited conductive material to contact the desired regions, thereby forming a “contact.” The openings in the insulative material are typically referred to as “contact openings.” 
     Higher performance, lower cost, increased miniaturization of components, and greater packaging density of integrated circuits are goals of the computer industry. However, as components become smaller and smaller, tolerances for all semiconductor structures (such as circuitry traces, contacts, and the like) become more and more stringent. In fact, each new generation of semiconductor device technology has seen a reduction in contact size of, on average, about 0.7 times. Unfortunately, interconnect delays have also increased at a rate of about two times per each new generation. Interconnect delays have a limiting effect on clock speeds which lowers performance. Although the reduction in size creates technical problems, the future advancement of the technology requires the capability for forming sub-0.25 μm contact openings with aspect ratios (height to width) as high as 8 to 1. 
     Moreover, the reduction in contact size (i.e., diameter) has resulted in intolerable increases in resistance between the active-device regions and the conductive material. Various methods have been employed to reduce the contact resistance at the interface between the conductive material and active-device region. One such method includes the formation of a metal silicide contact interface atop the active-device region within the contact opening prior to the application of the conductive material into the contact opening. A common metal silicide material formed is titanium silicide (TiSi X , wherein x is predominately equal to 2) generated from a deposited layer of titanium. 
     FIGS. 7-11 illustrate a conventional method of forming a titanium silicide layer on an active-device region. FIG. 7 illustrates an intermediate structure  300  comprising a semiconductor substrate  302  having an active-device region  304  formed therein with a dielectric layer  306  disposed thereover. A contact opening  308  is formed, by any known technique, such as patterning of a photoresist and subsequent etching, in the dielectric layer  306  to expose a portion of the active-device region  304 , as shown in FIG. 8. A thin layer of titanium  310  is applied over the dielectric layer  306  and the exposed portion of the active-device region  304 , as shown in FIG. 9. A high temperature anneal step is conducted in an inert atmosphere to react the thin titanium layer  310  with the active-device region  304  in contact therewith which forms a titanium silicide layer  312 , as shown in FIG.  10 . The non-reacted titanium layer  310  may then be removed to result in a final structure  314  with a titanium silicide layer  312  formed therein, as shown in FIG.  11 . 
     Naturally, as contact opening aspect ratios increase, thicker conductive material layers must be deposited, usually by DC magnetron sputtering, to obtain the required amount and depth of conductive material on the active-device region at the bottom of the contact opening. However, with contact openings approaching dimensions of 0.25 μm in diameter and aspect ratios of greater than 4 to 1, currently utilized processing techniques, such as physical vapor deposition, do not provide adequate step coverage for depositing conductive materials. Even the use of filtering techniques, such as physical collimated deposition and low-pressure long throw techniques, which are used to increase the number of sputtered particles contacting the bottom of the contact opening, have proven ineffective for contact opening diameters less than about 0.35 μm (for 0.25 μm diameter contact opening, the deposition efficiency is less than about 15%) and as contact opening aspect ratios increase beyond about 3 to 1 (bottom step coverage of less than 20%). Both collimated deposition and low-pressure long throw techniques also tend to create excessive film buildup at the top corner or rim of the contact opening, causing shadowing of bottom corners of the contact openings. The result is little or no deposited film at the bottom corners of the contact opening and consequently poor step coverage. Although increasing collimator aspect ratio results in improved step coverage, it also reduces deposition rate which reduces product throughput and, in turn, increases the cost of the semiconductor device. 
     Recently, physical vapor deposition (“PVD”) has been revived with the introduction of the Ionized Metal Plasma (“IMP”) process. Ionizing sputtered metal particles allows for highly directional PVD for depositing material in contact openings with up to about 6 to 1 aspect ratios and having 0.25 μm diameter openings. The IMP process can result in up to about 70% bottom coverage and up to about 10% sidewall coverage, even with such high aspect ratios and small diameter contact openings. 
     As illustrated in FIG. 12, an apparatus  320  used in the IMP process consists of a deposition chamber  322  having a pedestal  324  to support a semiconductor substrate  326  to be coated and a target  328 , such as a titanium plate. The pedestal  324  has an RF bias power source  330 , the deposition chamber  322  includes an RF power source  332 , and the target  328  has an RF or a DC power source  334 . 
     In the IMP process, metal particles (atoms, ions, etc.) (not shown) are sputtered from the target  328 . These metal particles pass through a high-density plasma  336  (e.g., usually between about 10 11 /[cm 3 ] and 10 12 /[cm 3 ]) formed between the target  328  and semiconductor substrate  326  where they become ionized. The ionization of the material particles enables a user to control the angular distribution of material arriving at the substrate for maximum bottom coverage in the bottom of the contact openings (not shown) by the manipulation of the electric field at the substrate. 
     In the deposition chamber  322 , the plasma  336  is maintained by inductively coupling RF energy from the RF power source  332  into the plasma  336 . An electric field, or bias voltage, develops in a sheath layer  338  around the plasma  336 , accelerating the metal ions (not shown) in a vector substantially perpendicular to the semiconductor substrate  326  by electrostatic coupling. The potential difference between the plasma  336  and the semiconductor substrate  326  can be optionally modulated by applying independent bias power from RF pedestal power bias source  330  to the semiconductor substrate  326 . 
     The degree of ionization of sputtered metal particles depends on their residence time in the plasma  336  (i.e., the longer the residence time, the greater the ionization). The sputtered atoms are ejected from the target  328  with relatively high energies (1 eV to 10 eV), leading to very short residence times. In order to slow down the metal particles for higher ionization, the process is usually operated at relatively high pressure (greater than about 10 mtorr). Such a pressure regime is higher than the 0.5-10 mtorr normally encountered in traditional PVD processes. 
     One drawback of the IMP process is the uniformity of the thickness of material deposited in the contact opening. When a contact opening is formed, a portion of the active material is also removed, as shown in FIG.  13 . Elements common between FIGS. 7-11 and FIGS. 13 and 14 retain the same numeric designation. The uniformity of the IMP process results in a substantially level layer of conductive material  342  at the bottom  344  of the contact opening  308  with very little or no sidewall coverage at the active-device region  304 . Thus, when a titanium silicide layer  346  is formed by a high temperature anneal, the titanium silicide layer  346  formed does not effectively take advantage of the sidewall portions  348  which had little or no conductive material  342  thereon (see FIG.  13 ). 
     This uniformity is particularly troublesome with shallow junction devices. As semiconductor devices become smaller in lateral dimension, they also become smaller in vertical dimension. Thus, shallow junction formation techniques are used to reduce the depth of the active-device regions of the semiconductor devices. However, for active-device regions having a depth of less than 0.15 microns, a contact depth into the active-device region without current leakage into the underlying substrate requires less than 600  521   of junction penetration for n-type active-device regions and less than about 800 Å for p-type active-device regions. Junction penetration includes both the penetration of the silicide and the depth of active-device region removed during the etching of the contact opening. 
     FIG. 15 illustrates a contact opening  308  formed to contact a shallow active-device  350 . Elements common between FIGS. 13 and 14 and FIGS. 15 and 16 retain the same numeric designation. Again, when a contact opening  308  is formed, a portion of the active material is also removed, as shown in FIG.  15 . The uniformity of the IMP process results in a substantially level layer of conductive material  342  at the bottom  352  of the contact opening  308  with very little or no sidewall coverage at the shallow active-device region  350 . Thus, when a titanium silicide layer  346  is formed by a high temperature anneal, the titanium silicide layer  346  formed does not form on the sidewall portions  348  of the contact opening, which had little or no conductive material  342  thereon (see FIG.  15 ), and the titanium silicide layer  346  can extend past the shallow active-device region  350  which causes junction leakage (escape of current from the shallow active-device region) into the underlying substrate material. 
     Thus, it can be appreciated that it would be advantageous to develop a technique and a contact interface to maximize sidewall coverage of the exposed active-device region while minimizing bottom coverage of the exposed active-device region in a contact opening to form a contact interface for a shallow junction device. 
     SUMMARY OF THE INVENTION 
     The present invention relates to altering an IMP process to form a contact interface within a contact opening for a shallow junction device, wherein the contact interface has a substantially continuous profile (substantially annular) along sides of a depression formed in the active surface of the semiconductor substrate, wherein the depression is formed by an etching process to form a contact opening through a dielectric layer. The contact interface is formed by depositing a layer of conductive material, such as titanium, with a high bias power deposition. The conductive material is preferably turned to a silicide by an annealing process, thereby forming the contact interface. 
     The annular contact interface profile flows current through the contact corners, while the vast majority of the contact will possess a higher resistance. This is advantageous for shallow active-device regions as the silicide will have effective contact with the shallow active-device region, while at the same time there is very little penetration of the silicide downward into the active-device region, thus assisting in reducing or eliminating junction leakage. 
     In an exemplary method of the present invention, a semiconductor substrate having a contact opening through a dielectric layer to contact an active-device region on the semiconductor substrate, is placed on a pedestal within an IMP deposition chamber. A DC power source, coupled to a conductive material target such as titanium, is preferably set between about 1 and 9 kilowatts and an RF power source is preferably set between about 2 and 3 kilowatts. A pedestal bias power source is set to deliver a relatively high pedestal bias power of greater than about 300 watts which results in a build-up of titanium at corners and lower sidewall portions of the contact opening. 
     After deposition, the semiconductor substrate is subjected to a high temperature anneal to form a titanium silicide layer. The unreacted titanium layer may be removed (optional) and a contact is completed by depositing a metal or other such conductive material in the contact opening. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     While the specification concludes with claims particularly pointing out and distinctly claiming that which is regarded as the present invention, the advantages of this invention can be more readily ascertained from the following description of the invention when read in conjunction with the accompanying drawings in which: 
     FIG. 1 is a cross-sectional view of a semiconductor substrate having an active-device region implanted therein and a dielectric layer disposed thereover with a contact opening therethrough; 
     FIG. 2 is a schematic of an IMP system; 
     FIG. 3 is a cross-sectional view of a titanium layer formed in an IMP system with a high pedestal bias power; 
     FIG. 4 is a cross-sectional view of a titanium silicide layer formed from the titanium layer of FIG. 3; 
     FIG. 5 is a cross-sectional view of a contact formed over the contact interface formed in the method illustrated in FIGS. 3-4; 
     FIG. 6 is a cross-sectional view of a memory array of a DRAM chip utilizing the contact interfaces of the present invention; 
     FIGS. 7-11 are cross-sectional views of a prior art method of forming a titanium silicide layer in a contact opening; 
     FIG. 12 is a schematic of an IMP system; 
     FIG. 13 is a cross-sectional view of a titanium layer formed by an IMP system; 
     FIG. 14 is a cross-sectional view of the titanium layer having been formed into a titanium silicide layer by an annealing process; 
     FIG. 15 is a cross-sectional view of a titanium layer formed by an IMP system in a shallow active-device region; and 
     FIG. 16 is a cross-sectional view of the titanium layer having been formed into a titanium silicide layer by an annealing process in a shallow active-device region. 
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     FIGS. 1-6 illustrate various structures and contact interface formations of the present invention. It should be understood that the illustrations are not meant to be actual views of any particular semiconductor device, but are merely idealized representations which are employed to more clearly and fully depict the formation of contact interfaces in the present invention than would otherwise be possible. Additionally, elements common between FIGS. 1-6 retain the same numerical designation. 
     Although the examples presented are directed to the formation of titanium silicide contact interfaces, any metal or metal alloy which is capable of forming a silicide may be employed. 
     EXAMPLE 
     Referring to FIG. 1, a test semiconductor substrate  102  (i.e., a silicon wafer) was formed with an active-device region  104  implanted therein and at least one dielectric layer  106  disposed thereover. At least one contact opening  108  (having a diameter of 0.35 μm and an aspect ratio greater than 4 to 1) was formed through the dielectric layer  106 , by a known patterning and etching technique, to expose the active-device region  104 , which also results in a recess  110  into the active-device region  104  caused by the etching technique. 
     As shown in FIG. 2, the test semiconductor substrate  102  was placed on a pedestal  112  within an IMP deposition chamber  114  (as also illustrated in FIG.  12 ). Preferably, the test semiconductor substrate  102  was placed in a hydrofluoric acid dip (prior to placement in the IMP deposition chamber  114 ) in order to remove native oxides from the contact opening  108 . It is known that thin layers of native oxide will grow immediately after the removal of the test semiconductor substrate  102 ; however, the hydrofluoric acid dip will remove any previously formed native oxides or build-up thereof. 
     A DC power source  116 , coupled to a titanium target  118 , was set at approximately 2.0 kilowatts and an RF power source  124  was set at approximately 2.1 kilowatts. A pedestal bias power generated from a pedestal bias power source  122 , coupled to the pedestal  112 , was varied from about 150 watts to about 500 watts, as will be discussed. The IMP deposition chamber  114  was maintained at temperature of about 200° C. 
     As particles of titanium (not shown) are sputtered from the titanium target  118 , they are ionized to a positive charge while residing in a plasma  126  formed between the titanium target  118  and the semiconductor substrate  102 . Thus, any negative voltage on the pedestal  112  will accelerate the titanium ions toward the pedestal  112 . These titanium ions strike the semiconductor substrate  102  atop the pedestal  112 , forming a titanium layer. A self-bias voltage of approximately−20 volts will be inherently present on the pedestal  112  at these operating parameters, even with no pedestal bias power applied. As the pedestal bias power is increased, an increasing pedestal bias voltage will be present, reaching a potential of approximately−80 volts for an applied pedestal bias power of about 300 watts. 
     FIG. 3 illustrates a titanium layer formed with a high bias power. It has been found that with a relatively high pedestal bias power of greater than about 300 watts, there is a high acceleration of the ionized titanium particles from the sheath  128  of the plasma  126  (see FIG.  2 ). The high acceleration causes resputtering of a previously deposited titanium layer. This results in a build-up of titanium  152  at corners  154  and a lower sidewall portion  156  of the contact opening  108 . For example in a circular contact opening, the titanium build-up  152  would be annular in shape, having an inclined, concave, and inwardly facing upper suface  155 . This deposition is preferably perform at a temperature of between 0 ° and 300° C., a pressure of about 15 μTorr and 30 μTorr, and a duration between about 35 and 70 seconds. 
     When a titanium silicide layer  158  is formed by heating the semiconductor substrate  102 , such as by rapid thermal processing (RTP), as shown in FIG. 4, the titanium silicide layer  158  allows a very limited contact area. For devices which do not have shallow junctions, such a limited contact area is detrimental because high contact resistance would result as the majority of the current follows the path of least resistance through the titanium silicide layer  158 . However, for a shallow junction device, such an annular titanium silicide layer  158  forms an effective contact with the shallow active-device region  104 , while at the same time there is no penetration of the titanium silicide layer  158  downward past the active-device region  104 , thus assisting in reducing or eliminating junction leakage of current into the underlying semiconductor substrate  102 . 
     Additionally, to complete the fabrication of a contact, as shown in FIG. 5, a layer of titanium nitride  172  is deposited over the dielectric layer  106  and into the contact opening  108 . The contact opening  108  is then filled with a conductive material  174 , such as tungsten. 
     Furthermore, it is contemplated that the process of the present invention is useful for production of DRAM chips, wherein the contact interfaces are used in the CMOS structures within a memory array of a DRAM chip. Such a CMOS structure  200  is illustrated in FIG. 6, as a portion of a memory array in a DRAM chip. The CMOS structure  200  comprises a semiconductor substrate  202 , such as a lightly doped P-type crystal silicon substrate, which has been oxidized to form thick field oxide areas  204  and exposed to implantation processes to form drain regions  206  and source regions  208 . Transistor gate members  212 , including a word line  214  bounded by insulative material  216 , are formed on the surface of the semiconductor substrate  202 . A barrier layer  218  is disposed over the semiconductor substrate  202 , the thick field oxide areas  204 , and the transistor gate members  212 . The barrier layer  218  has bitline contacts  222  contacting the source regions  208  for electrical communication with a bitline  224 , and, further, has capacitor contacts  226  contacting the drain regions  206  for electrical communication with capacitors  228 . Each of the bitline contacts  222  and capacitor contacts  226  may have silicide layer interfaces  232  formed as described above for reducing resistance between the bitline contacts  222  and the source regions  208 , and between the capacitor contacts  226  and the drain regions  206 . 
     An additional advantage of the present invention is an enhanced protection against defects associated with WF 6 . When WF 6  is deposited in a contact opening, it migrates into the silicon, creating long voids or “wormholes” in the substrate through the junction. This occurs particularly at the corners of the contact opening. The presence of the silicide in the corners of the contact opening, as taught by the present application, minimizes or prevents this from happening. 
     A further advantage of the present invention is that it can also be used for making electrical contact with unlanded structures and can be used for forming a contact through the conductive layer, such as conductive polysilicon layers. 
     Having thus described in detail preferred embodiments of the present invention, it is to be understood that the invention defined by the appended claims is not to be limited by particular details set forth in the above description as many apparent variations thereof are possible without departing from the spirit or scope thereof.