Abstract:
An organic light-emitting display device and a method of its manufacture are provided, whereby manufacturing processes are simplified and display quality may be enhanced. The display device includes: an active layer of a thin film transistor (TFT), on a substrate and including a semiconducting material; a lower electrode of a capacitor, on the substrate, doped with ion impurities, and including a semiconducting material; a first insulating layer on the substrate to cover the active layer and the lower electrode; a gate electrode of the TFT, on the first insulating layer; a pixel electrode on the first insulating layer; an upper electrode of the capacitor, on the first insulating layer; source and drain electrodes of the TFT, electrically connected to the active layer; an organic layer on the pixel electrode and including an organic emission layer; and a counter electrode facing the pixel electrode, the organic layer between the counter electrode and the pixel electrode.

Description:
CROSS-REFERENCE TO RELATED APPLICATION 
     This application is a divisional of U.S. patent application Ser. No. 13/069,346, filed Mar. 22, 2011, which claims priority to and the benefit of Korean Patent Application No. 10-2010-0046030, filed on May 17, 2010, the entire content of both of which is incorporated herein by reference. 
    
    
     BACKGROUND 
     1. Field 
     Aspects of embodiments according to the present invention relate to an organic light-emitting display device and a method of manufacturing the same. 
     2. Description of Related Art 
     Organic light-emitting display devices are expected to be the next generation of display devices due to their light weight, narrow profile, wide viewing angle, short response time, and low power consumption. An organic light-emitting display device that implements full-color images may employ an optical resonance structure that has different optical lengths at pixels with different colors (for example, red, green, and blue pixels). 
     SUMMARY 
     One or more embodiments of the present invention provide an organic light-emitting display device that is manufactured in a simple process and has excellent display quality, and a method of manufacturing the same. 
     In an exemplary embodiment according to the present invention, an organic light-emitting display device is disclosed. The organic light-emitting display device includes a substrate, an active layer of a thin film transistor, a lower electrode of a capacitor, a first insulating layer, a gate electrode of the thin film transistor, a pixel electrode, an upper electrode of the capacitor, source and drain electrodes of the thin film transistor, an organic layer, and a counter electrode. The active layer is on the substrate and includes a semiconducting material. The lower electrode is on the substrate, doped with ion impurities, and includes a semiconducting material. The first insulating layer is on the substrate and covers the active layer and the lower electrode. The gate electrode is on the first insulating layer and includes first, second, and third gate electrodes that are sequentially stacked. The first gate electrode includes a metal. The second gate electrode includes a transparent conductive material. The third gate electrode includes a metal. The pixel electrode is on the first insulating layer and includes first and second pixel electrodes that are sequentially stacked. The first pixel electrode includes a metal. The second pixel electrode includes a transparent conductive material. The upper electrode is on the first insulating layer and includes first and second upper electrodes. The first upper electrode includes a metal. The second upper electrode includes a transparent conductive material. The source and drain electrodes are electrically connected to the active layer. The organic layer is on the pixel electrode and includes an organic emission layer. The counter electrode faces the pixel electrode. The organic layer is intervening between the counter electrode and the pixel electrode. 
     The first gate electrode, the first pixel electrode, and the first upper electrode may each include a first metal. The first metal may be an aluminum alloy. 
     The aluminum alloy may further include nickel. 
     The first metal may have a thickness in a range of 50 to 200 Å. 
     The second gate electrode, the second pixel electrode, and the second upper electrode may each include a same transparent conductive material. The same transparent conductive material may include a material selected from the group including indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), indium oxide (In 2 O 3 ), indium gallium oxide (IGO), aluminum zinc oxide (AZO), and combinations thereof. 
     The organic light-emitting display device may further include a third pixel electrode and a second insulating layer. The third pixel electrode is on the second pixel electrode and includes a metal. The second insulating layer is on the first insulating layer, covers the third pixel electrode and the gate electrode, and includes first, second, and third openings. The first opening is for exposing a portion of the second pixel electrode. The second opening is for exposing a portion of the third pixel electrode. The third opening is for exposing the second upper electrode. The source and drain electrodes may be formed on the second insulating layer. One of the source and drain electrodes may contact the third pixel electrode via the second opening. 
     The third pixel electrode and the third gate electrode may each include a second metal. The second metal may include a metal selected from the group including aluminum (Al), platinum (Pt), palladium (Pd), silver (Ag), magnesium (Mg), gold (Au), nickel (Ni), neodymium (Nd), iridium (Ir), chromium (Cr), lithium (Li), calcium (Ca), molybdenum (Mo), titanium (Ti), tungsten (W), copper (Cu), and combinations thereof. 
     The third pixel electrode and the third gate electrode may each include multi-layered metal layers. 
     The first pixel electrode may be a semi-transmissive mirror for partially transmitting and partially reflecting light emitted from the organic emission layer. 
     The counter electrode may be for reflecting light emitted from the organic emission layer. 
     The etched surfaces on both sides of each of the first pixel electrode and the second pixel electrode may be identical to each other. 
     The organic light-emitting display device may further include a third insulating layer on the second insulating layer. The third insulating layer includes a fourth opening exposing a portion of the second pixel electrode exposed via the first opening, and covers the source and drain electrodes and the second upper electrode exposed via the third opening. 
     According to another exemplary embodiment of the present invention, a method of manufacturing an organic light-emitting display device is disclosed. The method includes performing first, second, third, fourth, and fifth mask processes. The first mask process is for forming a semiconductor layer on a substrate and patterning the semiconductor layer as an active layer of a thin film transistor and a lower electrode of a capacitor. The second mask process is for forming a first insulating layer on the substrate to cover the active layer and the lower electrode, sequentially stacking a first metal layer, a first transparent conductive layer, and a second metal layer on the first insulating layer, and then patterning the first metal layer, the first transparent conductive layer, and the second metal layer as a pixel electrode, a gate electrode of a thin film transistor, and an upper electrode of the capacitor. The pixel electrode includes first, second, and third pixel electrodes that are sequentially stacked. The gate electrode includes first, second, and third gate electrodes that are sequentially stacked. The upper electrode includes first, second, and third upper electrodes that are sequentially stacked. The third mask process is for forming a second insulating layer on the first insulating layer to cover the pixel electrode, the gate electrode, and the upper electrode, and patterning the second insulating layer to have first, second, and third openings, and contact holes. The first and second openings expose the third pixel electrode. The contact holes respectively expose source and drain regions of the active layer. The third opening exposes the third upper electrode. The fourth mask process is for forming a third metal layer on the second insulating layer to cover exposed portions via the first, second, and third openings and the contact holes, and patterning the third metal layer as source and drain electrodes. The fifth mask process is for forming a third insulating layer on the second insulating layer to cover the source and drain electrodes, and patterning the third insulating layer to have a fourth opening exposing the pixel electrode. 
     After the performing of the second mask process, the method may further include doping the source and drain regions with ion impurities by using the first, second, and third gate electrodes as masks. 
     The performing of the fourth mask process may include removing a portion of the third pixel electrode exposed via the first opening and the third upper electrode exposed via the third opening. 
     The performing of the fourth mask process may include removing the third upper electrode exposed via the third opening. After the performing of the fourth mask process, the method may further include doping ion impurities into the lower electrode from the second upper electrode exposed via the third opening. 
     The first metal layer may include an aluminum alloy. 
     The aluminum alloy may further include nickel. 
     The first metal layer may have a thickness in a range of 50 to 200 Å. 
     The first transparent conductive layer may include a material selected from the group including indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), indium oxide (In 2 O 3 ), indium gallium oxide (IGO), aluminum zinc oxide (AZO), and combinations thereof. 
     The second metal layer may include a metal selected from the group including aluminum (Al), platinum (Pt), palladium (Pd), silver (Ag), magnesium (Mg), gold (Au), nickel (Ni), neodymium (Nd), iridium (Ir), chromium (Cr), lithium (Li), calcium (Ca), molybdenum (Mo), titanium (Ti), tungsten (W), copper (Cu), and combinations thereof. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       The above and other features and aspects of the present invention will become more apparent by describing in detail exemplary embodiments thereof with reference to the attached drawings in which: 
         FIGS. 1 through 15  are schematic cross-sectional views sequentially illustrating a method of manufacturing an organic light-emitting display device, according to an embodiment of the present invention; and 
         FIG. 16  is a schematic cross-sectional view of an organic light-emitting display device manufactured using the method of  FIGS. 1 through 15 , according to an embodiment of the present invention. 
     
    
    
     DETAILED DESCRIPTION 
     Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings. Like reference numerals refer to like elements throughout. 
     An organic light-emitting display device according to an embodiment of the present invention and a method of manufacturing the same will be described with reference to  FIGS. 1 through 16 .  FIGS. 1 through 15  are schematic cross-sectional views sequentially illustrating a method of manufacturing an organic light-emitting display device, according to an embodiment of the present invention.  FIG. 16  is a schematic cross-sectional view of an organic light-emitting display device manufactured using the method of  FIGS. 1 through 15 , according to an embodiment of the present invention. 
     Referring to  FIG. 1 , a buffer layer  11  and a semiconductor layer  12  are sequentially formed on a substrate  10 . The substrate  10  may be formed of a transparent glass material including SiO 2  as a main component. 
     The buffer layer  11  may be formed on the substrate  10  to provide the substrate  10  with a smooth surface and prevent impurity elements from penetrating into the substrate  10 . The buffer layer  11  may include SiO 2  and/or SiN x  (x≧1). The buffer layer  11  and the semiconductor layer  12  each may be deposited using any one of various deposition methods such as plasma enhanced chemical vapor deposition (PECVD), atmospheric pressure CVD (APCVD), low pressure CVD (LPCVD), and the like. 
     The semiconductor layer  12  may be formed on the buffer layer  11 . The semiconductor layer  12  may be formed of amorphous silicon or polysilicon. In this regard, the polysilicon may be formed by crystallizing amorphous silicon by rapid thermal annealing (RTA), solid phase crystallization (SPC), excimer laser annealing (ELA), metal induced crystallization (MIC), metal induced lateral crystallization (MILC), sequential lateral solidification (SLS), or the like. 
     Referring to  FIG. 2 , a first photo-resist (P 1 ) is coated on the semiconductor layer  12 , and a first photomask process is performed thereon using a first photomask M 1  including a light-blocking portion M 11  and a light-transmitting portion M 12 . Although not particularly illustrated in  FIG. 2 , an exposure device is used to perform an exposing process using the first photomask M 1 , followed by a series of processes such as developing, etching, and stripping or ashing. 
     Referring to  FIG. 3 , because of the first photomask process, the semiconductor layer  12  is patterned as an active layer  212  of a thin film transistor and a lower electrode  312  of a capacitor. The lower electrode  312  of the capacitor is formed of the same material as that of the active layer  212  on the same layer on which the active layer  212  is formed. 
     Referring to  FIG. 4 , a first insulating layer  13 , a first metal layer  14 , a first transparent conductive layer  15 , and a second metal layer  16  are sequentially stacked on the resulting structure of  FIG. 3 . The first insulating layer  13  may be formed as a single layer formed of SiO 2  or SiN x , or a plurality of layers formed of SiO 2  and SiN x , and acts as a gate-insulating layer of the thin film transistor and a dielectric layer of the capacitor. 
     The first metal layer  14  may be formed of an aluminum alloy. The aluminum alloy may include aluminum as a main component and may further include nickel (Ni). In addition, the aluminum alloy may further include a small amount of silicon (Si), lanthanum (La), germanium (Ge), and/or cobalt (Co). Since the first metal layer  14  is formed of an aluminum alloy, when the first metal layer  14 , the first transparent conductive layer  15 , and the second metal layer  16  are etched, the second metal layer  16  and/or the first transparent conductive layer  15  may be etched without damage. Thus, the manufacturing process of the organic light-emitting display device may be enhanced. In addition, the first metal layer  14  may further include a small amount of Ni, thereby further enhancing etching properties, which results in further enhancing the manufacturing process of the organic light-emitting display device. Because of the etching process, the first metal layer  14 , the first transparent conductive layer  15 , and the second metal layer  16  have the same (e.g., identical) etched surfaces on their sides (see, for example,  FIG. 6 ). 
     The first metal layer  14  is formed as a semi-transmissive reflective film, e.g., as a semi-transmissive mirror, and has a thickness of 50 to 200 Å. In one embodiment, when the thickness of the first metal layer  14  is less than 50 Å, the reflectance of the first metal layer  14  decreases significantly and thus, it is difficult to form optical resonance between the first metal layer  14  and a counter electrode, which will be described later. In another embodiment, when the thickness of the first metal layer  14  is greater than 200 Å, the transmissivity of the first metal layer  14  decreases significantly and thus, the luminous efficiency of an organic light-emitting display device decreases. 
     The first transparent conductive layer  15  may include indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), indium oxide (In 2 O 3 ), indium gallium oxide (IGO), and/or aluminum zinc oxide (AZO). The second metal layer  16  may include aluminum (Al), platinum (Pt), palladium (Pd), silver (Ag), magnesium (Mg), gold (Au), nickel (Ni), neodymium (Nd), iridium (Ir), chromium (Cr), lithium (Li), calcium (Ca), molybdenum (Mo), titanium (Ti), tungsten (W), and/or copper (Cu). 
     In the present embodiment, the second metal layer  16  includes Al. In addition, the second metal layer  16  may include a plurality of metal layers, for example, fourth, fifth, and sixth metal layers  16   a ,  16   b , and  16   c . In the present embodiment, the second metal layer  16  may have a three-layer structure (Mo/Al/Mo) in which the sixth metal layer  16   c  is formed on a top surface of the fifth metal layer  16   b  and the fourth metal layer  16   a  is formed on a bottom surface of the fifth metal layer  16   b , wherein the fifth metal layer  16   b  is formed of Al or Al alloy and the fourth and sixth metal layers  16   a  and  16   c  are each formed of Mo or Mo alloy. However, the second metal layer  16  is not limited to the example described above, and may be formed of various suitable materials and to have various suitable layers. 
     As described above, since the first metal layer  14  is formed of an aluminum alloy, the stacked structure of the first metal layer  14 , the first transparent conductive layer  15 , and the second metal layer  16  may be simply patterned. As a result, etched surfaces on all sides of each of the first metal layer  14 , the first transparent conductive layer  15 , and the second metal layer  16  are the same as one another. 
     The stacked structure of the first metal layer  14 , the first transparent conductive layer  15 , and the second metal layer  16  may be patterned by being simultaneously or commonly or concurrently etched using a single etchant. Alternatively, the second metal layer  16  may be first wet etched, the first transparent conductive layer  15  may be wet etched or dry etched, and the second metal layer  16  may be then dry etched. 
     As described above, the first metal layer  14  formed as a semi-transmissive reflective layer may be simply patterned. Thus, the manufacturing process of the organic light-emitting display device may be enhanced. 
     Referring to  FIG. 5 , a second photo-resist P 2  is coated on the second metal layer  16 , and a second mask process is performed using a second photomask M 2  including a light-blocking portion M 21  and a light-transmitting portion M 22 . Referring to  FIG. 6 , as a result of the second mask process, the first metal layer  14 , the first transparent conductive layer  15 , and the second metal layer  16  are patterned as first, second, and third pixel electrodes  114 ,  115 , and  116 , respectively, first, second, and third gate electrodes  214 ,  215 , and  216 , respectively, of the thin film transistor, and first, second, and third upper electrodes  314 ,  315 , and  316 , respectively, of the capacitor. 
     Referring to  FIG. 7 , the active layer  212  is doped with ion impurities by using the first, second, and third gate electrodes  214 ,  215 , and  216  formed as a result of the second mask process as self-aligned masks. As a result, the active layer  212  includes source and drain regions  212   a  and  212   b  that are doped with the ion impurities and a channel region  212   c  disposed therebetween. That is, by using the first, second, and third gate electrodes  214 ,  215 , and  216  as self-aligned masks, the source and drain regions  212   a  and  212   b  may be formed without using a separate photomask. 
     Referring to  FIG. 8 , a second insulating layer  17  and a third photo-resist P 3  are coated on the structure obtained as a result of the second mask process, and a third mask process is performed using a third photomask M 3  including a light-blocking portion M 31  and a light-transmitting portion M 32 . Referring to  FIG. 9 , as a result of the third mask process, a first opening  117   a  and a second opening  117   b  for exposing portions of the third pixel electrode  116 , contact holes  217   a  and  217   b  that respectively expose the source and drain regions  212   a  and  212   b  of the thin film transistor, and a third opening  317  for exposing portions of the third upper electrode  316  of the capacitor are formed in the second insulating layer  17 . 
     Referring to  FIG. 10 , a third metal layer  18  is formed on the resulting structure of  FIG. 9 . The third metal layer  18  may include Al, Pt, Pd, Ag, Mg, Au, Ni, Nd, Ir, chromium (Cr), Li, Ca, Mo, Ti, W, and/or Cu. In the present embodiment, the third metal layer  18  includes Al. 
     In addition, the third metal layer  18  may include a plurality of metal layers, for example, seventh, eighth, and ninth metal layers  18   a ,  18   b , and  18   c . In the present embodiment, like the second metal layer  16 , the third metal layer  18  may have a three-layer structure (Mo/Al/Mo) in which the ninth metal layer  18   c  is formed on a top surface of the eighth metal layer  18   b  and the seventh metal layer  18   a  is formed on a bottom surface of the eighth metal layer  18   b , wherein the eighth metal layer  18   b  is formed of Al or Al alloy and the seventh and ninth metal layers  18   a  and  18   c  are each formed of Mo or Mo alloy. However, the third metal layer  18  is not limited to the example described above, and may be formed of various suitable materials and formed to have various suitable layers. For example, the third metal layer  18  may have a three-layer structure including a Ti layer, an Al layer, and a Ti layer. 
     Referring to  FIG. 11 , a fourth photo-resist P 4  is coated on the third metal layer  18 , and a fourth mask process is performed using a fourth photomask M 4  including a light-blocking portion M 41  and a light-transmitting portion M 42 . The third metal layer  18  is patterned in the fourth mask process. In this regard, when the third metal layer  18  is etched, portions of the second metal layer  16  formed below the third metal layer  18  may also be patterned. 
     That is, referring to  FIG. 12 , the third metal layer  18  is patterned to form source and drain electrodes  218   a  and  218   b  that are respectively electrically connected to the source and drain regions  212   a  and  212   b . In this patterning process, a portion of the third pixel electrode  116  exposed via the first opening  117   a  and the third upper electrode  316  exposed via the third opening  317  are simultaneously or commonly or concurrently etched and removed. As a result, the second pixel electrode  115  and the second upper electrode  315  are respectively exposed via the first opening  117   a  and the third opening  317 . 
     Referring to  FIG. 13 , the structure obtained as a result of the fourth mask process is doped with ion impurities. The doped ion impurities are B ions and/or P ions, and the doping concentration of the ion impurities is 1×10 15  atoms/cm 2  or greater, and the doping process is performed, targeting the lower electrode  312  of the capacitor, which is formed by patterning the semiconductor layer  12 . Accordingly, the lower electrode  312  of the capacitor becomes highly conductive, thereby forming a metal-insulator-metal (MIM) capacitor together with the first upper electrode  314  and the second upper electrode  315 , which may result in increasing the capacitance of the capacitor. 
     Referring to  FIG. 14 , a fifth photo-resist P 5  is coated on the resulting structure of  FIG. 13 , and a fifth mask process is performed using a fifth photomask M 5  including a light-blocking portion M 51  and a light-transmitting portion M 52 . In this regard, the exposure device is used to perform an exposing process using the fifth photomask M 5 , followed by developing and ashing processes. As illustrated in  FIG. 15 , a fourth opening  119  for exposing the second pixel electrode  115  is formed in the fifth photo-resist P 5 , and the remaining portion of the fifth photo-resist P 5  is then sintered and formed as a third insulating layer  19 . The fifth mask process is not limited to the example described above, and may be performed by forming the third insulating layer  19  using an organic material and/or an inorganic material, coating the fifth photo-resist P 5  on the third insulating layer  19 , and performing a general mask process thereon to form the fourth opening  119 . 
     Since the first pixel electrode  114 , including a semi-transmissive mirror, is disposed below the second pixel electrode  115  exposed via the fourth opening  119 , the first pixel electrode  114  may partially transmit light and partially reflect light. By using the first pixel electrode  114 , which is a semi-transmissive mirror capable of partially transmitting and reflecting light, an organic light-emitting display device employing an optical resonance structure may be manufactured. In the present embodiment, since the first pixel electrode  114 , which acts as a semi-transmissive mirror, is formed of an aluminum alloy, the first pixel electrode  114  and the second pixel electrode  115  may be simultaneously or commonly or concurrently patterned and thus, the manufacturing process of the organic light-emitting display device may be enhanced. 
     Referring to  FIG. 16 , an organic layer  21 , including an organic emission layer  21   a , and a counter electrode  22  are formed on the second pixel electrode  115 . The organic emission layer  21   a  may be formed of a low molecular weight or high molecular weight organic material. 
     The organic layer  21  includes a hole transport layer (HTL) and a hole injection layer (HIL) that are sequentially stacked on the organic emission layer  21   a  towards the second pixel electrode  115 , and includes an electron transport layer (ETL) and an electron injection layer (EIL) that are sequentially stacked on the organic emission layer  21   a  towards the counter electrode  22 . The organic layer  21  may further include various other suitable layers, if necessary. The organic layer  21 , including the organic emission layer  21   a , may realize the optical resonance structure by suitably varying the thicknesses of the organic emission layer  21   a  for each pixel or the thicknesses of the other layers included in the organic layer  21  except for the organic emission layer  21   a.    
     The counter electrode  22  is formed on the organic layer  21  as a common electrode. In the organic light-emitting display device according to the present embodiment, the first pixel electrode  114  and the second pixel electrode  115  are used as an anode, and the counter electrode  22  is used as a cathode; however, the opposite case is also possible. 
     In addition, the counter electrode  22  may be formed as a reflective electrode including a reflective material in order to form an optical resonance structure. In this regard, the counter electrode  22  may be formed of Al, Ag, Mg, Li, Ca, LiF/Ca, or LiF/Al. Also, a sealing element and an absorbent element may be further formed on the counter electrode  22  to protect the organic emission layer  21   a  from external moisture or oxygen. 
     Embodiments of the present invention may be directed to a bottom-emission type organic light-emitting display device, in which the displayed image is realized towards the substrate  10 . By having a distance between the counter electrode  22  and the first pixel electrode  114  be a resonance thickness, such embodiments may also have enhanced luminous efficiency by using the optical resonance. 
     In addition, the lower electrode  312  of the capacitor is formed using N+- or P+-doped polysilicon, and the first upper electrode  314  and the second upper electrode  315  are respectively formed using a conductive metal and a transparent conductive material, e.g., a metal oxide, thereby forming an MIM capacitor. In contrast, when a metal-oxide-silicon (MOS) capacitor is used, a high voltage needs to be continuously applied to a specific wiring of a panel, and thus there is a large risk of electrical shortage. However, as described above, the organic light-emitting display device includes the MIM capacitor and thus, these problems may be prevented or reduced, and limitations on the design of the organic light-emitting display device are decreased. 
     The organic light-emitting display device and the method of manufacturing the same as described above provide the following effects. First, a pixel electrode employs a semi-transmissive mirror, thereby forming optical resonance in a bottom-emission type organic light-emitting display device in which the displayed image is realized towards a pixel electrode. Thus, the luminous efficiency of the organic light-emitting display device may be enhanced. 
     Second, the semi-transmissive mirror is formed of an aluminum alloy, thereby reducing or preventing the damage of a transparent conductive layer or a gate electrode in a patterning process of the pixel electrode. In addition, this allows patterning a plurality of stacked structures of the pixel electrode in a single process. Thus, the manufacturing process of the organic light-emitting display device may be enhanced. 
     Third, the organic light-emitting display device including the semi-transmissive mirror may be manufactured by five mask processes. Fourth, an MIM capacitor structure may be formed in a simple process and thus, the manufacturing process and circuit characteristics thereof may be enhanced. 
     While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present invention as defined by the following claims, and equivalents thereof.