Abstract:
A structure. The structure may include a layer of cobalt disilicide that is substantially free of cobalt monosilicide and there is substantially no stringer of an oxide of titanium on the layer of cobalt disilicide. The structure may include a substrate that includes: an insulated-gate field effect transistor (FET) that includes a source, a drain, and a gate; a first layer of cobalt disilicide on the source, said first layer having substantially no cobalt monosilicide, and said first layer having substantially no stringer of an oxide of titanium thereon; a second layer of cobalt disilicide on the drain, said second layer having substantially no cobalt monosilicide having substantially no stringer of an oxide of titanium thereon; and a third layer of cobalt disilicide on the gate, said third layer having substantially no cobalt monosilicide and having substantially no stringer of an oxide of titanium thereon.

Description:
[0001]    This application is a divisional application claiming priority to Ser. No. 09/939,895, filed Aug. 27, 2001, which is a divisional of U.S. Pat. No. 6,335,294, issued Jan. 1, 2002. 
     
    
     BACKGROUND OF THE INVENTION 
       [0002]    1. Technical Field 
         [0003]    The present invention relates to a method for removing a formation of an oxide of titanium that is generated as a byproduct of a process that forms cobalt disilicide within an insulated-gate field effect transistor. 
         [0004]    2. Related Art 
         [0005]    Integrated circuits constructed on silicon substrates are limited in performance by the resistance of the source, drain, and gate of a field effect transistor (FET). This difficulty may be addressed by forming cobalt disilicide areas within FETs, since the cobalt disilicide areas have low electrical resistance. For example, cobalt disilicide within the source and drain of an FET lowers the total resistance for current flow from a contact, through the FET source, into the FET channel, and out of the FET drain. 
         [0006]    In the formation of cobalt disilicide, it is well known to utilize a layer of cobalt as a source for the cobalt disilicide and to use a titanium nitride (TiN) capping layer to protect the cobalt from oxidizing during a subsequent annealing step. After a first annealing step, this sacrificial TiN capping layer is chemically removed by a selective etch with a solution such as one comprising hydrogen peroxide. Discrete portions of the TiN cap are not always removed by this process, however, and a residual configuration, or “stringer,” of one or more oxides of titanium, such as titanium dioxide, may remain after the cobalt disilicide is formed in a second annealing step. Unfortunately, the stringer of a titanium oxide is electrically conductive and may cause electrical shorting of adjacent structures. For example, the stringer may cause a short between the gate and the drain of an FET, between the source of a first FET and the drain of a second FET, or between the drain of an FET and external circuitry. The prior art does not disclose a method of removing a stringer of an oxide of titanium that is generated as described above. 
       SUMMARY OF THE INVENTION 
       [0007]    The present invention provides a method of removing an oxide of titanium which is generated as a byproduct of a process that forms cobalt disilicide within a semiconductor device such as an FET. 
         [0008]    The present invention provides an FET within a substrate, wherein the FET is a gate-insulated field effect transistor comprising a source, a drain, a gate, a gate insulator, and a channel. Typically, the substrate is first precleaned with a suitable reagent such as hydrofluoric acid (HF). This precleaning removes a film of silicon dioxide (SiO 2 ) that became deposited on a surface of the layer of silicon as a consequence of prior processing or of prior exposure of the substrate to air at room temperature. Next, a layer of cobalt is formed on a top surface of the substrate by use of a sputtering process such as with argon gas in a low-pressure chamber. The top surface of the substrate comprises a portion of the top surface of each of the source, drain, gate, and insulating structures. Next, a layer of titanium nitride is formed on the layer of cobalt by use of a second sputtering process such as with argon gas and nitrogen gas in a low-pressure chamber. Then a first annealing of the substrate causes portions of the layer of cobalt to react with the source, drain, and gate to transform a top portion of each of the source, drain, and gate into a silicide zone comprising a greater amount of cobalt silicide (CoSi) and a lesser amount of cobalt disilicide (CoSi 2 ). Unreacted cobalt remains after the preceding annealing step, particularly on top of the isolating structures. The layer of titanium nitride and the unreacted cobalt are removed by a first cleaning with a reagent such as one comprising hydrogen peroxide and sulfuric acid. Impurities comprising titanium, cobalt, silicon, oxygen, and/or nitrogen may be present on the substrate after the first cleaning and a second cleaning is performed to remove the impurities. The first and second cleanings in combination may not successfully remove all impurities and impurities comprising titanium may be present on the substrate. Next, a second annealing process transforms cobalt monosilicide to cobalt disilicide in the silicide zone, thereby forming the desired cobalt disilicide within the FET. Nonetheless, a stringer of an oxide of titanium may be present on one or more of the cobalt disilicide areas of the silicide zone following the second annealing, and all such stringers should be removed to prevent shorting of adjacent electrical structures of, within, or coupled to, the FET. The final step removes the stringers by applying a reagent to the substrate at a suitable temperature, and for a period of time, wherein the reagent does not chemically react with the cobalt disilicide. 
         [0009]    Use of an FET in the preceding method is illustrative. The preceding process steps may be applied to any semiconductor structure to form cobalt disilicide volumes that are free of stringers of an oxide of titanium. 
         [0010]    Thus, the invention has the advantage of forming cobalt disilicide by a process that does not leave stringers of one or more oxides of titanium. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0011]      FIG. 1  depicts a side cross-sectional view of an oxide of titanium on the top surface of a layer of material, in accordance with a preferred embodiment of the present invention. 
           [0012]      FIG. 2  depicts  FIG. 1  with the oxide of titanium removed. 
           [0013]      FIG. 3  depicts a side cross-sectional view of a layer of substrate comprising a layer of silicon, in accordance with a preferred embodiment of the present invention. 
           [0014]      FIG. 4  depicts  FIG. 3  with an added layer of cobalt. 
           [0015]      FIG. 5  depicts  FIG. 4  with an added layer of titanium nitride. 
           [0016]      FIG. 6  depicts  FIG. 5  following a first annealing step. 
           [0017]      FIG. 7  depicts  FIG. 6  following a first cleaning step. 
           [0018]      FIG. 8  depicts  FIG. 7  following a second cleaning step. 
           [0019]      FIG. 9  depicts  FIG. 8  following a second annealing step. 
           [0020]      FIG. 10  depicts  FIG. 9  following a third cleaning step. 
           [0021]      FIG. 11  depicts a side cross-sectional view of a substrate comprising an FET, in accordance with a preferred embodiment of the present invention. 
           [0022]      FIG. 12  depicts  FIG. 11  with an added layer of cobalt. 
           [0023]      FIG. 13  depicts  FIG. 12  with an added layer of titanium nitride. 
           [0024]      FIG. 14  depicts  FIG. 13  following a first annealing step. 
           [0025]      FIG. 15  depicts  FIG. 14  following a first cleaning step. 
           [0026]      FIG. 16  depicts  FIG. 15  following a second cleaning step. 
           [0027]      FIG. 17  depicts  FIG. 16  following a second annealing step. 
           [0028]      FIG. 18  depicts  FIG. 17  following a third cleaning step. 
       
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
       [0029]    In a first step of a preferred embodiment of the present invention,  FIG. 1  illustrates a side cross-sectional view of a layer of material  10  having a top surface  12 , and a patch of an oxide of titanium  14 , on the top surface  12 . The patch of oxide of titanium  14  may include titanium dioxide, titanium oxide, etc. The layer of material  10  may be any material that does not chemically react with the reagent to be discussed in connection with  FIG. 2 . More particularly, the layer of material  10  may comprise cobalt disilicide (CoSi 2 ) such as is formed in the fabrication of semiconductor devices. 
         [0030]      FIG. 2  depicts  FIG. 1  with the oxide of titanium removed as a result of applying a reagent under suitable conditions; e.g., by immersing the layer  10  with patch  14  in a chemical reagent at a suitable temperature and period of time, wherein the reagent does not react with the layer of material  10 . A particular reagent that is effective for this removal step comprises water (H 2 O), ammonium hydroxide (NH 4 OH), and hydrogen peroxide (H 2 O 2 ), wherein the NH 4 OH and the H 2 O 2  each comprise approximately 4% of the total reagent volume. This reagent should be applied at a temperature that is approximately in the 45 to 95° C. range for a period of time ranging approximately from 30 seconds to 10 minutes. For example, given a temperature of 65° C., a period of time of approximately 3 minutes is effective. Generally, the minimum required period of time is inversely dependent on the applied temperature. 
         [0031]    In a first step of a preferred embodiment of the present invention for forming a clean layer of cobalt disilicide,  FIG. 3  illustrates a side cross-sectional view of a provided substrate  20  comprising a layer of silicon  22 . A precleaning with a chemical solution, such as hydrofluoric acid (HF), is typically performed prior to the first step of  FIG. 3  in order to remove from the layer of silicon  22  a film of silicon dioxide (SiO 2 ) that results from prior processing or from exposure of silicon to air at room temperature. The film of silicon dioxide has a thickness typically in the range of 20 to 50 angstroms. 
         [0032]      FIG. 4  depicts  FIG. 3  with an added layer of cobalt  24 . The layer of cobalt  24  may be formed on the layer of silicon  22  by any suitable technique known to those skilled in the art. For example, a cobalt sputtering process may be employed, wherein the substrate  20  is placed in a depressurized chamber containing argon (Ar) gas and a region of cobalt. A voltage applied to the chamber first causes the argon atoms to be ionized into Ar+ ions and next accelerates the Ar+ ions to move within the chamber. A percentage of the accelerated Ar+ ions strikes the region of cobalt, resulting in formation of gaseous cobalt with moving cobalt atoms, wherein a share of the moving cobalt atoms adheres to the layer of silicon  22  to form the layer of cobalt  24 , as shown in  FIG. 4 . While a range of thicknesses may characterize the layer of cobalt  24 , as is known to those of ordinary skill in the art, a thickness of approximately 80 angstroms is representative. The layer of cobalt  24  should be formed within approximately 2 hours after the precleaning removal of the silicon dioxide film (see discussion of  FIG. 3 ) in order to avoid reforming a silicon dioxide film on the layer of silicon  22 . 
         [0033]      FIG. 5  depicts  FIG. 4  with an added layer of titanium nitride  26 . The layer of titanium nitride  26  may be formed on the layer of cobalt  24  by any suitable technique known to those skilled in the art. For example, a sputtering process may be employed, wherein the substrate  20  is placed in a depressurized chamber containing argon (Ar) gas, nitrogen gas, and a region of titanium. A voltage is applied to the chamber, which first causes the argon atoms to be ionized into Ar+ ions and next accelerates the Ar+ ions to move within the chamber. A percentage of the accelerated Ar+ ions strikes the region of titanium resulting in formation of gaseous titanium with moving titanium particles, wherein a share of the moving titanium particles strikes and combines with the nitrogen gas to form titanium nitride particles, and wherein a share of the titanium nitride particles adheres to the layer of cobalt  24  to form the layer of titanium nitride  26 , as shown in  FIG. 5 . While a range of thicknesses may characterize the layer of titanium nitride  26 , as is known to those of ordinary skill in the art, a thickness of approximately 200 angstroms is representative. 
         [0034]      FIG. 6  depicts  FIG. 5  following a first annealing step, wherein the layer of cobalt  24  and a top portion of the layer of silicon  22  (see  FIG. 5 ) react and are transformed into a layer of silicides of cobalt  34  and a thinner layer of silicon  32  (see  FIG. 6 ), and wherein the layer of silicides of cobalt  34  comprises a greater amount of cobalt monosilicide (CoSi) and a lesser amount of cobalt disilicide (CoSi 2 ). The mixture of cobalt monosilicide and cobalt disilicide is generally inhomogeneously distributed within the layer of suicides of cobalt  34 . While the time and temperature of the first annealing step may vary within limits known to those ordinarily skilled in the art, a temperature range of approximately 540° C. to approximately 600° C. for a time period of approximately 5 seconds to approximately 2 minutes are representative. The preceding first annealing step causes the combined thickness of the layer of silicides of cobalt  34  and the thinner layer of silicon  32  (see  FIG. 6 ) to be less than the combined thickness of the layer of cobalt  24  and the layer of silicon  22  (see  FIG. 5 ). While a range of thicknesses may characterize the layer of suicides of cobalt  34 , as is known to those ordinarily skilled in the art, a thickness of approximately 160 angstroms is representative. 
         [0035]      FIG. 7  depicts  FIG. 6  following a first cleaning step, which has the purpose of removing the reconfigured layer of titanium nitride  36  (see  FIG. 6 ) and also to remove any unreacted cobalt from the preceding first annealing step. The first cleaning step may be accomplished by use of a chemical reagent, such as one comprising hydrogen peroxide and sulfuric acid. As shown in  FIG. 7 , an impurity  38  comprising titanium, cobalt, and/or silicon, may be present on the layer of silicides of cobalt  34  after the first cleaning step. 
         [0036]      FIG. 8  depicts  FIG. 7  following a second cleaning step, whose purpose is to remove the impurity  38  (see  FIG. 7 ). The second cleaning step may be accomplished in the following two sub-steps. First, the substrate  20  is sprayed with a first reagent at a temperature of approximately 40° C., wherein the first reagent comprises water, ammonium hydroxide, and hydrogen peroxide, wherein the ammonium hydroxide and the hydrogen peroxide each comprises approximately 4% of a total first reagent volume. Second, the substrate  20  is sprayed with a second reagent at a temperature of approximately 65° C., wherein the second reagent comprises water, hydrochloric acid, and hydrogen peroxide, wherein the hydrochloric acid comprises approximately 5% of a total second reagent volume, and wherein the hydrogen peroxide comprises approximately 4% of the total second reagent volume. The second cleaning step may not successfully remove all impurities and an impurity  40  comprising titanium may be present on the layer of silicides of cobalt  34  after the second cleaning step, as shown in  FIG. 8 . 
         [0037]      FIG. 9  depicts  FIG. 8  following a second annealing step, wherein the cobalt silicide in the layer of silicides of cobalt  34  is transformed into cobalt disilicide, resulting in the layer of silicides of cobalt  34  ( FIG. 8 ) being replaced by a layer of cobalt disilicide  44 , as shown in  FIG. 9 . Since the second annealing step involves chemical reactions involving silicon, part of the layer of silicon  32  ( FIG. 8 ) is incorporated within the layer of cobalt disilicide  44  ( FIG. 9 ), which reflects a possible change in the thickness of the layer of silicon  32  ( FIG. 8 ) to form a modified layer of silicon  33  ( FIG. 9 ). While the time and temperature of the second annealing step may vary within limits known to those ordinarily skilled in the art, a temperature range of approximately 700° C. to approximately 850° C. for a time period of approximately 1 second to approximately 1 minute are representative. Generally, the minimum required period of time is inversely dependent on the temperature. Although the second annealing step forms the desired layer of cobalt disilicide  44 , an undesired stringer of an oxide of titanium  42  may be nonetheless be present on the layer of the cobalt disilicide  44  following completion of the second annealing step, as shown in  FIG. 9 . 
         [0038]      FIG. 10  depicts  FIG. 9  following a third cleaning step, which has the purpose of removing the stringer of an oxide of titanium  42  (see  FIG. 9 ) in order to prevent shorting of adjacent electrical structures within, or coupled to, the substrate  20 . The third cleaning step removes the stringer  42  by applying a reagent under suitable conditions; e.g., by immersing the substrate  20  in a chemical reagent at a suitable temperature and period of time, wherein the reagent does not chemically react with the layer of cobalt disilicide  42 . A particular reagent that is effective for this removal step comprises water (H 2 O), ammonium hydroxide (NH 4 OH), and hydrogen peroxide (H 2 O 2 ), wherein the NH 4 OH and the H 2 O 2  each comprises approximately 4% of the total reagent volume. This reagent should be applied at a temperature that is approximately in the 45 to 95° C. range for a period of time ranging approximately from 30 seconds to 10 minutes. For example, given a temperature of 65° C., a period of time of approximately 3 minutes is effective. Generally, the minimum required period of time is inversely dependent on the applied temperature. The effect of the third cleaning step is to achieve the goal of removing the stringer of an oxide of titanium  42 , as shown in  FIG. 10 . 
         [0039]    In a first step of a preferred embodiment of the present invention for forming a clean layer of cobalt disilicide,  FIG. 11  illustrates a side cross-sectional view of a provided substrate  50 , comprising an insulated-gate field effect transistor (FET)  49  and isolating structures  56  and  58 . The FET  49  comprises a source  52 , drain  54 , channel  51 , gate  142 , gate insulator  140 , and insulating spacers  144  and  146 . While the source  52 , drain  54 , and channel  51  are shown to comprise N+, N+, and P− material, respectively, the source  52 , drain  54 , and channel  51  may alternatively comprise P+, P+, and N− material, respectively. The insulating spacers  144  and  146  comprise any suitable electrically insulating material such as an oxide or nitride of silicon. The isolating structures  56  and  58  are any structures that electrically isolate the FET  49  such as trench isolation structures or grown oxide structures. 
         [0040]    A precleaning of the substrate  50  with a chemical solution, such as hydrofluoric acid (HF), is typically performed prior to the first step of  FIG. 11  in order to remove from a surface of the substrate  50  a film of silicon dioxide (SiO 2 ) that results from exposure of silicon to air at room temperature. The film of silicon dioxide has a thickness typically in the range of 20 to 50 angstroms. 
         [0041]      FIG. 12  depicts  FIG. 11  with an added layer of cobalt  60 . The layer of cobalt  60  may be formed on a top surface  61  of the FET  49  and isolating structures  56  and  58  by any suitable technique known to those skilled in the art. For example, a cobalt sputtering process may be employed, wherein the substrate  50  is placed in a depressurized chamber containing argon (Ar) gas and a region of cobalt. A voltage applied to the chamber first causes the argon atoms to be ionized into Ar+ ions and next accelerates the Ar+ ions to move within the chamber. A percentage of the accelerated Ar+ ions strikes the region of cobalt, resulting in formation of gaseous cobalt with moving cobalt particles, wherein a share of the moving cobalt particles adheres to the top surface  61  to form the layer of cobalt  60 , as shown in  FIG. 12 . While a range of thicknesses may characterize the layer of cobalt  60 , as is known to those of ordinary skill in the art, a thickness of approximately 80 angstroms is representative. The layer of cobalt  60  should be formed within approximately 2 hours after the precleaning removal of the silicon dioxide film (see discussion of  FIG. 11 ) in order to avoid reforming a silicon dioxide film on the top surface  61 . 
         [0042]      FIG. 13  depicts  FIG. 12  with an added layer of titanium nitride  62 . The layer of titanium nitride  62  may be formed on the layer of cobalt  60  by any suitable technique known to those ordinarily skilled in the art. For example, a sputtering process may be employed, wherein the substrate  50  is placed in a depressurized chamber containing argon (Ar) gas, nitrogen gas, and a region of titanium. A voltage is applied to the chamber, which first causes the argon atoms to be ionized into Ar+ ions and next accelerates the Ar+ ions to move within the chamber. A percentage of the accelerated Ar+ ions strikes the region of titanium resulting in formation of gaseous titanium with moving titanium particles, wherein a share of the moving titanium particles strikes and combines with the nitrogen gas to form titanium nitride particles, and wherein a share of the titanium nitride particles adheres to the layer of cobalt  60  to form the layer of titanium nitride  62 , as shown in  FIG. 13 . While a range of thicknesses may characterize the layer of titanium nitride  62 , as is known to those of ordinary skill in the art, a thickness of approximately 200 angstroms is representative. 
         [0043]      FIG. 14  depicts  FIG. 13  following a first annealing step, wherein the layer of cobalt  60  reacts with a top portion of the source  52 , drain  54 , and gate  142  (see  FIG. 13 ) to form layers of silicides of cobalt  82 ,  84 , and  90 , respectively (see  FIG. 14 ), comprising a greater amount of cobalt silicide (CoSi) and a lesser amount of cobalt disilicide (CoSi 2 ). The mixture of cobalt silicide and cobalt disilicide is generally inhomogeneously distributed within the layers of silicides of cobalt  82 ,  84 , and  90 . Also, the source  52 , drain  54 , and gate  142  (see  FIG. 13 ) are geometrically transformed into source  72 , drain  74 , and gate  92 , respectively (see  FIG. 14 ). Non-reacting cobalt remain in cobalt layers  86  and  88 . The first annealing step also reconfigures the layer of titanium nitride  62  (see  FIG. 13 ), into the layer of titanium nitride  63  (see  FIG. 14 ). While the time and temperature of the first annealing step may vary within limits known to those ordinarily skilled in the art, a temperature range of approximately 540° C. to approximately 600° C. for a time period of approximately 5 seconds to approximately 2 minutes are representative While a range of thicknesses may characterize the layers of silicides of cobalt  82 ,  84 , and  90 , as is known to those ordinarily skilled in the art, a thickness of approximately 160 angstroms is representative. 
         [0044]      FIG. 15  depicts  FIG. 14  following a first cleaning step, whose purpose is to remove the layer of titanium nitride  63  (see  FIG. 14 ) and also to remove cobalt layers  86  and  88  as well as any additional unreacted cobalt from the preceding first annealing step. The first cleaning step may be accomplished by use of a chemical reagent, such as one comprising hydrogen peroxide and sulfuric acid. As shown in  FIG. 15 , impurities  100  and  102 , comprising titanium, cobalt, and/or silicon, may be present after the first cleaning step. 
         [0045]      FIG. 16  depicts  FIG. 15  following a second cleaning step, which has the purpose of removing the impurities  100  and  102  (see  FIG. 15 ). The second cleaning step may be accomplished in the following two sub-steps. First, the substrate  50  is sprayed with a first reagent at a temperature of approximately 40° C., wherein the first reagent comprises water, ammonium hydroxide, and hydrogen peroxide, wherein the ammonium hydroxide and the hydrogen peroxide each comprises approximately 4% of a total first reagent volume. Second, the substrate  50  is sprayed with a second reagent at a temperature of approximately 65° C., wherein the second reagent comprises water, hydrochloric acid, and hydrogen peroxide, wherein the hydrochloric acid comprises approximately 5% of a total second reagent volume, and wherein the hydrogen peroxide comprises approximately 4% of the total second reagent volume. The second cleaning step may not successfully remove all impurities and the impurities  110  and  112  comprising titanium may be present after the second cleaning step, as shown in  FIG. 16 . 
         [0046]      FIG. 17  depicts  FIG. 16  following a second annealing step, wherein the cobalt silicide in the layers of silicides of cobalt  82 ,  84 , and  90  is transformed into cobalt disilicide, resulting in the layers of silicides of cobalt  82 ,  84 , and  90  ( FIG. 16 ) being replaced by a layers of cobalt disilicide  83 ,  85 , and  91 , respectively ( FIG. 17 ). Since the second annealing step relates to chemical reactions involving silicon, the source  72 , drain  74 , and gate  92  ( FIG. 16 ) are geometrically changed into source  73 , drain  75 , and gate  93 , respectively ( FIG. 17 ). Gate  92  ( FIG. 16 ) is changed to gate  93  ( FIG. 17 ), which reflects a possible repositioning of gate  92 . While the time and temperature of the second annealing step may vary within limits known to those ordinarily skilled in the art, a temperature range of approximately 700° C. to approximately 850° C. for a time period of approximately 1 second to approximately 1 minute are representative. Generally, the minimum required period of time is inversely dependent on the temperature. Although the second annealing step forms the desired layers of cobalt disilicide  83 ,  85 , and  91 , undesired stringers of an oxide of titanium  120  and  122  may be nonetheless be present following completion of the second annealing step, as shown in  FIG. 17 . 
         [0047]      FIG. 18  depicts  FIG. 17  following a third cleaning step, which ha the purpose of removing the stringers of an oxide of titanium  120  and  122  (see  FIG. 17 ) in order to prevent shorting of adjacent electrical structures within, or coupled to, the FET  49 . The third cleaning step removes the stringers  120  and  122  by applying a reagent under suitable conditions; e.g., by immersing the substrate  50  in a chemical reagent at a suitable temperature and period of time, wherein the reagent does not chemically react with the layers of cobalt disilicide  83 ,  85 , and  91 . A particular reagent that is effective for this removal step comprises water (H 2 O), ammonium hydroxide (NH 4 OH), and hydrogen peroxide (H 2 O 2 ), wherein the NH 4 OH and the H 2 O 2  each comprises approximately 4% of the total reagent volume. This reagent should be applied at a temperature that is approximately in the 45 to 95° C. range for a period of time ranging approximately from 30 seconds to 10 minutes. For example, given a temperature of 65° C., a period of time of approximately 3 minutes is effective. Generally, the minimum required period of time is inversely dependent on the applied temperature. The effect of the third cleaning step is to achieve the goal of removing the stringers  120  and  122 , as shown in  FIG. 18 . 
         [0048]    While preferred and particular embodiments of the present invention have been described herein for purposes of illustration, many modifications and changes will become apparent to those ordinarily skilled in the art. Accordingly, the appended claims are intended to encompass all such modifications and changes as fall within the true spirit and scope of this invention.