Abstract:
To clean the exhaust gas of internal-combustion engines or other machines which are operated with fossil fuel, it is proposed to firstly pretreat the exhaust gas in a non-thermal normal-pressure gas discharge and subsequently allow a selective catalytic reduction of oxidic noxious substances to take place with the addition of a suitable reduction substance, or to allow a selective catalytic decomposition to take place. The device for removing the oxidic noxious substances is characterized by a series circuit of at least one module with a gas discharge section and at least one module with a catalytic-converter section, and is suitable in particular for use in a diesel engine.

Description:
CROSS-REFERENCE TO RELATED APPLICATION 
     This is a continuation of copending International Application PCT/DE98/01296, filed May 8, 1998, which designated the United States. 
    
    
     BACKGROUND OF THE INVENTION 
     Field of the Invention 
     The invention relates to methods for removing oxidic noxious substances in an oxygen-containing exhaust gas, in particular to clean the exhaust gas of an internal combustion engine or of another machine which is operated with fossil fuel, such as a diesel engine. The invention also relates to a device for carrying out the methods and to an engine that is operated with the specified methods and the associated device. 
     Exhaust gases from combustion processes constitute one of the main sources of atmospheric pollutants. These include, in particular, nitrogen oxides, sulfur dioxides, hydrocarbons, carbon monoxide, soot or the like. The three-way catalytic converter, which effectively eliminates nitrogen oxides, hydrocarbons and carbon monoxide, is the state of the art specifically for a spark-ignition engine which operates with an excess air factor Λ=1. The catalytic converter is suitable for a diesel engine or a lean-mix spark-ignition engine (Λ&gt;1) to only a limited degree because only the hydrocarbons and carbon monoxide are largely decomposed, but the nitrogen oxides cannot be reduced owing to the high oxygen content in the exhaust gas. Until now there has not been any type of catalytic converter with a sufficiently high noxious-substance decomposition rate and service life for these types of engines. 
     Various approaches to eliminating the noxious substances in the exhaust gases of diesel engines or lean-mix.spark-ignition engines are known from the prior art. In this respect, the so-called selective catalytic reduction (SCR=selective catalytic reduction) of nitrogen oxides is becoming increasingly significant. 
     For direct-injecting (DI) spark-ignition engines which are operated with a lean mix under partial load, i.e. with an air excess factor (Λ&gt;1), but with Λ=1 under full load, hydrocarbons (HC=hydrocarbons) are the reduction substances in discussion, which, however, have to be added in excess according to the prior art in order to achieve effective reduction (see for example A. Fritz, V. Pitchon: “The Current State of Research on Automotive Lean NOx Catalysis”, Applied Catalysis B: Environmental, Vol. 13, pages 1-25 (1997)). The reason for this is that the hydrocarbons are also oxidized catalytically by the oxygen contained in the exhaust gas. This process becomes more probable as the temperature rises and thus sets an upper temperature limit of, for example, 550° C. for the use of the HC-SCR catalytic converters. The lower limit is given by the use of No reduction and, depending on the material of the catalytic converter, is 300° C. and above. A further concept for DI spark-ignition engines is associated with the term “NOx Storage Catalytic Converters” (see for example Automotive Engineering, Vol. 105, issue 2, pages 133-135 (1997)). Here, the nitrogen oxides are stored during lean operation and catalytically reduced in cyclically occurring short phases with extremely rich operation, and thus with a high emission of hydrocarbons. The hydrocarbons are not used efficiently according to this prior art either. 
     In diesel vehicles, the principle involved makes rich operation impossible from the outset. For this reason, the reduction substance used here is ammonia that is made available to the SCR process by a urea hydrolysis (ammonia SCR and urea SCR). This avoids a situation in which, in particular for mobile use, it is necessary for the user to carry ammonia directly with him. In practice, in mobile use, reduction rates of nitrogen oxides of more than 70% are achieved. A peculiarity of this method is that urea has to be carried along in a supplementary tank in the vehicle. This method operates at temperature intervals of approximately 200° C. to a maximum of 550° C. 
     Generally, it can therefore be claimed that SCR methods experience problems in the warm-up phase of engines and during low-load operation, for example in the town cycle, but also under full-load conditions with exhaust-gas temperatures of over 600° C. in some cases. 
     By use of plasma-chemical methods and associated devices, as are described in Published, Non-Prosecuted German Patent Applications DE 42 31 581 and DE 44 16 676 A, International Patent Disclosure WO 97/03746 A and U.S. Pat. No. 5,476,539, it is also possible to reduce the nitrogen oxides from engine exhaust gases. Here, so-called non-thermal normal-pressure gas discharges are used to initiate chemical reactions in a plasma which can lead to decomposition of the nitrogen oxides. 
     “Non-thermal normal-pressure gas discharges” are generally understood as gas discharges that burn under normal pressure and in which high-energy electrons initiate plasma processes without the gas being significantly heated in the process. These include dielectrically impeded (“silent”) discharges, corona discharges and pulsed glow discharges (see for example B. Eliasson, U. Kogelschatz: “Nonequilibrium Volume Plasma Chemical Processing”, IEEE Trans. Plasma Sci. Vol. 19, No. 6, pages 1063-1077 (1991)). A peculiarity of these plasma-chemical methods is that they oxidize the nitrogen oxides mainly to form NO 2  and HNO 3  and only reduce them to the desired products N 2  and O 2  to a small degree and with comparatively high expenditure of energy. The combination, proposed in U.S. Pat. No. 3,983,021 and in Published, European Patent Application EP 0 659 465 A2, of a gas discharge and a catalytic converter in direct contact has also previously not been successful. This is due, inter alia, to the fact that a series of catalytic converters cannot be used as the dielectric because in the presence of certain exhaust-gas components, for example heavy hydrocarbons, they form a weak electrical conductivity which, in particular, impedes or entirely prevents the operation of the silent discharges. Furthermore, the document does not provide for the addition of a reduction substance or even excludes it as unsuitable for cleaning the exhaust gases of motor vehicles. A concrete approach for effective cleaning of exhaust gas specifically at low exhaust-gas temperatures is not given in the publication. 
     In addition, Published, Non-Prosecuted German Patent Application DE 195 10 804 A describes a method for reducing the nitrogen oxide in exhaust gases of internal combustion engines, in which the exhaust gases having excess oxygen are placed in contact with a catalyst while a selectively acting gaseous reduction substance is added. In the associated device, before entering into contact with the catalyst the reduction substance is converted into the high-pressure plasma state with an overwhelming formation of radicals. In contrast, in Published, European Patent Application EP 0 585 047 A, in order to clean the exhaust gases of internal combustion engines, the exhaust gas firstly passes through an electrical low-temperature discharge before it arrives at a converter with a catalyst for converting the noxious substances. Reduction is not mentioned in this reference. 
     Furthermore, in Published, Non-Prosecuted German Patent Application DE 21 26 228 A a method and a device for cleaning exhaust gas in motor vehicles is described, in which the exhaust gas is firstly fed to an electrostatic filter before it is conducted through a catalytic exhaust-gas reactor. The filter is intended to charge particles floating in the spatial discharge field of a corona discharge. A gas discharge is not realized here. Finally, in order to remove NOx from an exhaust gas, Published Japanese Abstract JP 63-242323 A proposes treatment using a discharge plasma before the exhaust gas is conducted with reducing effect through a catalyst bed based on platinum rhodium (PtRh). 
     SUMMARY OF THE INVENTION 
     It is accordingly an object of the invention to provide a method and a device for removing oxidic noxious substances in an oxygen-containing exhaust gas and an engine which is operated therewith which overcomes the above-mentioned disadvantages of the prior art methods and devices of this general type. 
     With the foregoing and other objects in view there is provided, in accordance with the invention, a method for removing oxidic noxious substances in an exhaust gas containing oxygen, which includes: 
     pretreating, initially, the exhaust gas containing the oxidic noxious substances including nitrogen monoxide in a non-thermal normal-pressure gas discharge in which the nitrogen monoxide is oxidized forming nitrogen dioxide and a degree of oxidation of the nitrogen monoxide to form the nitrogen dioxide being held below 50%; and 
     performing, subsequently, a selective catalytic reduction of the oxidic noxious substances with an addition of ammonia functioning as a reduction substance and resulting in water and nitrogen as reaction by-products. 
     Taking the prior art as a point of departure, the object of the invention is to specify methods for removing oxidic noxious substances in an oxygen-containing exhaust gas and to provide associated devices in which, in particular, the respective disadvantages of the plasma-chemical methods and of the catalytic methods for the treatment of exhaust gas are avoided. The intention is instead to utilize the strengths of both methods. 
     In the invention, a reactor for operating non-thermal normal-pressure gas discharges, also referred to below for short as “gas discharge”, such as dielectrically impeded discharges, pulsed discharges or D.C. corona discharges or pulsed glow discharges, and a catalytic converter are connected in series in the direction of flow of the exhaust gas. In contrast to Published, European Patent Application EP 659 465 A2, there is no direct contact here between the plasma and the catalyst. Likewise in contrast to the European Patent Application EP 0 659 465 A2, there is provision for the reduction substance to be added either upstream of the gas discharge or upstream of the catalytic converter because of the preferred use of the invention for the reduction of NO in an oxidizing atmosphere, such as in diesel exhaust gas, for example. However, the use of the invention is not restricted by this to diesel exhaust gases but rather permits the efficient reduction of oxidic noxious substances, such as nitrogen oxide (NO) or nitrogen dioxide (NO 2 ), i.e. generally nitrogen oxides (NOx), in all oxidizing atmospheres. 
     In the case of the invention, the pretreatment of the exhaust gas in the gas discharge serves to “activates” the selective catalytic reduction. The latter has been used successfully for years for cleaning the smoke emissions from power plants. Within the scope of the invention, it is possible, for example, firstly to oxidize, induced by the gas discharge, some of the NO to form NO 2 , which is possible by a suitable reactor configuration and reactor operation, for example in accordance with Published, Non-Prosecuted German Patent Applications DE 195 25 749 A1 or DE 195 25 754 A1, with a low expenditure of energy, the remaining NO being subsequently reduced together with the nitrogen dioxide. 
     The invention has been based on the surprising finding that the NO oxidation product NO 2 , which is actually undesired, is actually decomposed in the selective catalytic reduction not only very much quicker, and particularly at lower temperatures than NO, but that it also makes possible the decomposition of NO at temperatures below the temperatures which are otherwise necessary for it. H 2 O and N 2  are to be expected as reaction products of the selective catalytic reduction of NO and NO 2  with NH 3  as the reduction substance. In order to promote the common reduction of NO and NO 2  and to avoid the formation of ammonium nitrate, which takes place in a reaction of NO 2  with NH 3  which is shorter in comparison, the conversion degree here will advantageously always lie below 50% of the initial NO content. 
     The expenditure of energy for the oxidation of NO to form NO 2  by the gas discharge can be reduced not only by reactor measures but also by providing in the exhaust gas hydrocarbons in a concentration which corresponds approximately to that of NO. This can be carried out by controlling the combustion process or by subsequent injection into the hot exhaust gas. The hydrocarbon in this case can be an individual hydrocarbon that preferably contains double bonds or oxygen, or there may be a mixture of different hydrocarbons, such as gasoline or diesel fuel. 
     The average energy consumption can be kept low within the scope of the invention by virtue of the fact that the gas discharge is controlled by a characteristic diagram as a function of the engine load and rotational speed as well as of the mean temperature of the catalytic converter. Discharge operation is not necessary above the threshold temperature for the selective catalytic reduction of NO, and below this temperature the use of energy per mass unit NOx in the exhaust gas rises as the temperature drops because more NO has to be converted to NO 2  at a constant degree of reduction. 
     In the event that the reduction substance is added before the gas discharge, it is to be noted during the gas discharge operation that the reduction substance is not decomposed by the gas discharge but instead is only activated. If this is ensured, within the scope of the invention advantages can be obtained in comparison with other proposals. An oxidation catalytic converter would indeed be capable of oxidizing, to a limited degree, NO to form NO 2 , particularly at relatively high temperatures, but the reduction substances which are necessary in a downstream SCR catalytic converter, for example the hydrocarbons and CO contained in the exhaust gas, are virtually completely removed from the exhaust gas in the process, and the degree of conversion of NO to NO 2  disadvantageously rises as the temperature increases. Therefore, particularly for the activation of the reduction substance, gas discharge in particular provides possibilities which it has not been possible to realize until now using catalytic measures alone. 
     The activation therefore advantageously leads to a lower threshold temperature for the catalytic process than is usually necessary without gas discharge. The essential factor in this context is that the activation of the noxious substances, of the reduction substance or of other components of the exhaust gas in the gas discharge is possible in a temperature range which goes far beyond that for selective catalytic reduction. This provides the possibility of allowing the exhaust gas to cool before the catalytic treatment, that is to say, for example, in the gas discharge, and thus to extend additionally the range of application for catalytic reduction. Because the heat loss at high temperatures is significantly greater than at low temperatures, hot exhaust gas, which could damage the catalytic converter, or in which reduction is no longer possible because of catalytic oxidation of the reduction substance, is cooled more strongly than exhaust gas whose temperature is only a little above the threshold temperature for the catalytic process. 
     A further advantage of the invention lies in the fact that the provision of additional reaction ducts such as those mentioned above brings about increased reduction rates even in the temperature interval of a normal catalytic activity. These increased reduction rates do not become apparent with normal configuration for a maximum degree of reduction in the active temperature interval, but they permit the volume of the catalytic converter to be reduced for the same mass flow of exhaust gas or for a larger mass flow of exhaust gas to be treated with the same volume of catalytic converter. 
     Other features which are considered as characteristic for the invention are set forth in the appended claims. 
     Although the invention is illustrated and described herein as embodied in a method and a device for removing oxidic noxious substances in an oxygen-containing exhaust gas and an engine which is operated therewith, it is nevertheless not intended to be limited to the details shown, since various modifications and structural changes may be made therein without departing from the spirit of the invention and within the scope and range of equivalents of the claims. 
     The construction and method of operation of the invention, however, together with additional objects and advantages thereof will be best understood from the following description of specific embodiments when read in connection with the accompanying drawings. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a diagrammatic, block diagram of a principle of a method for removing oxidic noxious substances in an oxygen-containing exhaust gas according to the invention; 
     FIG. 2 is a block diagram of a modification of FIG. 1; 
     FIGS. 3 and 4 are block diagrams of possible ways of preparing the exhaust gas; 
     FIGS. 5,  5   a ,  5   b  and  6  are block diagrams for preparing a reduction substance; 
     FIGS. 7 to  10  are graphs illustrating trial results for clarifying the invention; and 
     FIG. 11 is a block diagram of an engine operated with the method described. 
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     In all the figures of the drawing, sub-features and integral parts that correspond to one another bear the same reference symbol in each case. Referring now to the figures of the drawing in detail and first, particularly, to FIG. 1 thereof, there is shown a simple series circuit of individual functional modules for cleaning an exhaust gas A. The exhaust gas A is conducted through a feed line  3  into a module  1  which contains a gas discharge section and ports  11  and  12  for supplying the gas discharge section  1  with electricity. After an activation, the exhaust gas A is passed through a connection line  4  into a module  2  that contains an SCR catalytic converter  2 . After catalytic cleaning, the exhaust gas A is released through a line  5 , or an exhaust system of a vehicle, leading into the open air. 
     In FIG. 2, a plurality of the individual modules  1 ,  2  each having one of the gas discharge sections and a catalytic converter section alternately one behind the other are provided to increase the efficiency. In this way, a plurality of units  6  each made of the gas discharge module  1  and of the catalytic converter module  2  with the necessary connecting lines  4  are provided in a series circuit. 
     A first possible way of preparing the exhaust gas A is provided in FIG.  3 . The efficiency of the method, whose principle is clarified with reference to FIGS. 1 and 2, is improved in a way which is compatible with practical conditions, by adding in a metered fashion a reduction substance R from a supply tank  31 , a metering valve  32 , feed lines  33  and a suitably configured probe  34  disposed upstream of the gas discharge module  1 . The type of the probe  34  for conduction into the stream of the exhaust gas A depends on the method of preparation of the reduction substance R, which may be liquid or gaseous. In the configuration according to FIG. 2, the addition of the reduction substance R upstream of each gas discharge module  1  may be controlled separately. 
     In FIG. 4, an alternative possible way of preparing the exhaust gas is provided. Here, the reduction substance R is added between the gas discharge module  1  and the catalytic converter module  2 . When it is implemented in the configuration according to FIG. 2 with a series circuit of a plurality of units which are respectively composed of the gas discharge section and the catalytic converter section, the addition of the reduction substance R can be carried out in each unit  6  in a separately controlled way. 
     FIGS. 5,  5   a ,  5   b  and  6  show possible ways of preparing the reduction substance R, a preparation module  7  being provided for this in each case. Specifically in FIG. 5, the preparation takes place in the feed line  3  for the exhaust gas A. In FIG. 5 a , a further catalytic converter is disposed downstream while in FIG. 5 b  a further catalytic converter is disposed upstream. The preparation module  7  may contain a catalytic converter section or a gas discharge section in this case. On the other hand, in FIG. 6 the preparation takes place in the exhaust-gas line  4 . 
     FIG. 7 shows the degree p of NO reduction in % as a function of the exhaust-gas temperature T in ° C., ammonia being used as the reduction substance and a simple combination of the gas discharge module  1  and the SCR catalytic converter module  2  according to FIG. 1 having been used. The gas mixture which is treated as exhaust gas A was composed of 82% N 2 , 13% O 2 , 5% H 2 O, 500 ppm NO and 500 ppm NH 3 . The space velocity in the catalytic converter module  2  was 11,000 h −1 . The reduction substance R was added upstream of the gas discharge module  1 . The curve  71  represents a trial result with a catalytic converter, and the curve  72  represents the trial result of a combination of the gas discharge section  1  and the catalytic converter  2  section. 
     FIG. 8 shows an ammonia slips occurring during the processes according to FIG. 7, in ppm as a function of temperature T in ° C. The “slip” s is understood here to be the proportion of reduction substance that is not consumed, which provides a measure of the efficiency. Since the quantity of reduction substance is generally adapted to consumption, in practice the objective is to have a low slip. The curve  81  represents the trial result with only the catalytic converter, the curve  82  the trial result of a combination of the gas discharge and the catalytic converter. 
     In a corresponding way, FIG. 9 illustrates the NOx reduction degree p and FIG. 10 illustrates the NH 3  concentration c in ppm as a function of the exhaust-gas temperature T in ° C. under the same peripheral conditions as in FIG. 7, but with a further addition of 500 ppm of the hydrocarbon ethene. Here, the curves  91  and  92  represent the results with the catalytic converter and the discharge section, respectively, while curve  93  shows their sum and curve  94  finally shows the combination of the gas discharge section  1  and the catalytic converter  2  for the proposed method of operation. 
     With the configuration described with reference to FIGS. 1 to  6 , a catalytic converter from the field of power plant nitrogen removal, which uses NH 3  as the reduction substance, can be utilized. Furthermore, it is possible to use catalytic converters that reduce nitrogen oxides on the basis of selective catalytic reduction (SCR) with any desired reduction substance. In almost all cases, this process will run more efficiently and at relatively low temperatures if the exhaust gas is firstly activated by an energy-efficient gas-discharge process for catalytic cleaning. 
     The reduction substance used is specifically ammonia (NH 3 ). If appropriate, such substances which have previously not been used for NO reduction, but which are suitable for NO 2  reduction or for NO reduction in the presence of NO 2 , are possible. The reduction substance R can be introduced either upstream of the gas discharge or else downstream of the gas discharge. Introduction upstream of the gas discharge module  1  leads not only to the formation of NO 2  but also to activation of the reduction substance by the gas discharge. It is also possible to pretreat the reduction substance R in a catalytic converter connected upstream of the gas discharge module, either in the feed line of the reduction substance or after the addition of the reduction substance R in the exhaust-gas line, as takes place, for example, in urea hydrolysis. 
     The presently mentioned aspects are covered by experimental results which have been carried out with a simple series connection of dielectrically impeded discharge and SCR catalytic converter: with these measurements, a catalytic converter from the field of power plant nitrogen removal was utilized and the reduction substance used was ammonia. 
     The measurement curves of the method according to the invention are plotted in FIGS. 7 to  10  as a function of the temperature T in comparison with known curves of catalytic converters and a separate normal-pressure discharge. In all cases there is a significant improvement. 
     In particular, it emerges from FIG. 7, through the comparison of curve  72  and curve  71 , that at the predefined space velocity of approximately 11,000 h −1  the degree p of reduction of the nitrogen oxides at a temperature T of 200° C. is increased from 70% to 92%, and at a temperature T of 180° C. from 50% to 88%. Even at 140° C. and 160° C., i.e. outside the known active temperature window (170° C.-430° C.) of the catalyst, the gas discharge module  1  which is connected upstream brings about a degree p of reduction of 72% or 81%. When the temperature is raised to 250° C., 90% of the nitrogen oxides are reduced even without the discharge module. By connecting the discharge module  1 , the degree of reduction is increased to 95%. 
     From FIG. 8 it is apparent that the combination of the discharge section  1  and the catalytic converter section  2  according to curve  82  significantly reduces the ammonia slip in comparison with the exclusive treatment by the catalytic converter module according to curve  81 . An increase in the degree of efficiency of the SCR method is therefore obtained. 
     The admixture of the hydrocarbon ethene, which in terms of its plasma-chemical behavior has a model character for the hydrocarbons present, for example, in diesel exhaust gases, to the existing mixture of exhaust gases produces a further increase in the degree p of reduction in the combination of discharge plasma and catalytic converter module so that the oxidation of NO to form NO 2  in the gas discharge runs more efficiently. In this regard, FIG. 9 shows the curve  91  for a catalytic converter and the curve  92  for the decomposition reaction of a discharge. The degree p of reduction of the catalytic converter rises from 1% to 63% as the working temperature is increased from 100° C. to 200° C. Without a downstream catalytic converter, i.e. with the gas discharge section alone, the degree p of reduction is low and is approximately 25% irrespective of the temperature T. 
     It is apparent from curve  94  that here with a low expenditure of energy for the temperatures 100° C. and 130° C. the degree of reduction for NO of 1% and 11% for the catalytic converter can be increased to 69% and 83%, solely by the combination of the gas discharge module  1  and the catalytic converter  2 . At the given temperatures T of 160° C., 180° C. and 200° C., it is possible to discern an improvement in the degree p of reduction from 27%, 47% and 63%, respectively, to 95% in each case. Here, the ammonia slip s is also reduced, which is clear in particular from FIG.  10 . The NH 3  concentration p, illustrated in FIG. 10 on the ordinate, in ppm corresponds to the slip according to FIG. 7, the curve  101  representing the trial results with a catalytic converter, and the curve  102  representing the trial results of a combination of discharge module and catalytic converter. 
     As in the case of the experiments without the model hydrocarbon ethene, it is also clear from FIG. 10 that the combination of the discharge module  1  and the catalytic converter  2  according to curve  102  significantly reduces the ammonia slip s in comparison with an exclusive treatment by the catalytic converter according to curve  101 . This also shows the increase in the degree of efficiency with the proposed method in comparison with the prior art. 
     The compositions selected for the investigations described above using model exhaust gases correspond to the basic composition of diesel exhaust gas when a diesel engine is operating with an average load. In this respect the results can be transferred, the application of the method described and of the associated device for diesel engines producing a considerable improvement in comparison with the relevant prior art. The expenditure which it requires stays within reasonable limits. 
     FIG. 11 illustrates the specific implementation of the method described and of the associated device specifically in the case of a diesel engine. 
     An engine  8  with a device according to FIG. 1 formed of the combination of the modules  1  and  2  having the gas discharge section  1  and the catalytic converter section  2 , respectfully, are assigned an electronic control unit  13  with an associated switched-mode power supply for operating the gas discharge, and a unit  14  for controlling the engine  8 . An electronic controller  15  for controlling an injection of the reduction substance R, for example urea, is provided along with data lines  16 ,  16 ′,  16 ″ for digital and/or analog signals for the control functions. Reference numerals  17 ,  17 ′ and  17 ″ designate signal lines for measurement signals. 
     The gas discharge in the exhaust gas A and the feeding in of the reduction substance R are controlled as a function of the state of the engine B. A permanent data memory  20 , for example an EEPROM, in which known characteristic diagrams KF of the engine  8  are stored is connected upstream of the motor control unit  14 . Furthermore, there are measurement devices for characteristic variables. These include a sensor  21  for an electrical temperature measurement which is necessary for the controller  14 ; a sensor  22 , advantageously an electrochemical or optical sensor, for determining the concentration of the reduction substance R an d furthermore sensors  23 , advantageously electrochemical or optical sensors, for determining the concentration of NOx and HC are optionally present. 
     The combination of the non-thermal normal-pressure gas discharge with the selective catalytic reduction (SCR) therefore proves a considerable improvement for the practice of exhaust-gas cleaning, for which purpose in summary reference is again made to FIG.  9 . From the sum of the results for SCR without plasma activation according to curve  91  and the results for plasma treatment alone according to curve  92  it follows that the successful treatment which was achieved in combination according to curve  94  is not due to the simple additive superimposition of two No decomposition measures according to curve  93 . In fact, only the process which is described above in particular, with plasma activation which takes place with separation in terms of spatial and chronological terms, leads to a strengthening of the catalytic decomposition.