Abstract:
A magnetic recording medium is described, comprising a non-magnetic support base having positioned thereon a magnetic layer and optionally a non-magnetic layer, wherein at least one layer of the magnetic and non-magnetic layers contains an oxyfatty acid ester. This recording medium has superior surface properties and thus superior running properties, and can be satisfactorily used in tape decks.

Description:
FIELD OF THE INVENTION 
     The present invention relates to magnetic recording media, and more particularly, to magnetic recording media with a magnetic layer having superior surface characteristics, which are superior in lubricity because of low coefficients of friction of the magnetic layer with various materials when passed in contact therewith through magnetic recording/reproducing decks. 
     BACKGROUND OF THE INVENTION 
     With magnetic recording media having insufficient lubricity, the surface of a magnetic layer is smoothed by contact with contacting parts of magnetic recording/reproducing decks, resulting in an increase in the coefficient of friction of the magnetic layer. When magnetic recording media with such a magnetic layer having an increased coefficient of friction are passed through magnetic recording/reproducing decks, in particular, under high humidity conditions (relative humidity: at least 60%), cohesion occurs between the magnetic recording media and the contacting parts of the magnetic recording/reproducing decks due to the presence of fine water droplets. When the cohesion phenomenon occurs, if the running tension is greater than the cohesive strength, stick-slip running is caused, producing running noises comprising an audible sound. In recording of magnetic recording media under the stick-slip running, signals recorded are modulated in frequency in the running direction, and normal reproduction becomes difficult. When the stick-slip running occurs during the reproduction of recorded signals, phenomena such as wow, flutter and jitter are caused, and normal reproduction cannot be achieved. On the other hand, when the cohesion phenomenon occurs, if the cohesive strength is greater than the running tension, running is stopped and reproduction becomes impossible. These phenomena are called &#34;tape signal&#34; in the art, the magnetic recording media and magnetic recording/reproducing decks causing such tape squeal are seriously low in product value. 
     In the case of magnetic recording/reproducing decks, the tape squeal is caused by the material, running tension, running speed, etc. of the magnetic recording medium running system. In the magnetic recording media, smoothing of the surface, an increase in the coefficient of friction, etc. are responsible for tape squeal. 
     A number of lubricants, solid or liquid, are used to improve the surface lubricity of magnetic recording media, as described in U.S. Pat. Nos. 3,470,021, 3,525,694, 3,630,772, 3,387,993, 3,542,589, 4,018,968, 3,476,596, 3,547,693, 3,471,415, 2,654,681, 3,781,206, 3,625,760, 3,634,253, 3,274,111, 3,492,235, 4,007,314 and 3,476,596. Examples of such lubricants include inorganic or organic fine powders (e.g., Al 2  O 3 , graphite, silica, Cr 2  O 3 , ZnO, and carbon black) and organic surface active agent (e.g., higher hydrocarbon compounds, aliphatic alcohols, aliphatic acids, aliphatic acid esters, aliphatic acid amides, aliphatic acid salts, and aliphatic acid quaternary salts). There is no limitation on the number of carbon atoms contained in the foregoing compounds, of which are preferred those compounds having a boiling point of at least about 100° C. and a melting point of not higher than about 150° C. The amount of the lubricant added is from 0.1 to 20 parts by weight per 100 parts by weight of the binder. 
     Addition of such additives does not always succeed in producing a magnetic recording layer having desirable characteristics. For example, the use of large amounts of additives may decrease the mechanical strength of the resulting recording layer and may give rise to the phenomenon that after the formation of the recording layer the additives gradually come out to the surface of the recording layer. Furthermore, dispersion of magnetic substances is not always satisfactory. 
     For example, the addition of glycerol tristearate as a lubricant to the magnetic layer in an effective amount to inhibit the tape squeal exerts adverse influences on electromagnetic properties, lowering the S/N ratio. When butyl palmitate, which is another example of lubricants, is added to the magnetic recording layer in an effective amount to improve the running properties on guide roles made of stainless steel in the deck running system for magnetic materials, the tape squeal is caused at the deck head portion. 
     SUMMARY OF THE INVENTION 
     An object of the invention is to provide novel additives for use in a magnetic recording layer, which make it possible to produce magnetic recording media having superior running properties. 
     Another object of the invention is to provide magnetic recording media with a magnetic layer having improved surface characteristics. 
     Still another object of the invention is to provide magnetic recording media which provide a good S/N ratio. 
     A further object of the invention is to provide magnetic recording media having good sensitivity. 
     A still further object of the invention is to provide magnetic recording media having good storage stability, in which no additives come out to the surface thereof. 
     The present invention relates to magnetic recording media comprising a non-magnetic support base having positioned thereon a magnetic layer and optionally a non-magnetic layer, wherein at least one layer of the magnetic and non-magnetic layers contains an oxyfatty acid ester. 
     DETAILED DESCRIPTION OF THE INVENTION 
     The term &#34;oxyfatty acid&#34; as used herein means an aliphatic monocarboxylic acid containing an hydroxyl group in the molecule, preferably containing from 10 to 24 carbon atoms, more preferably from 12 to 18 carbon atoms. The melting point of the oxyfatty acid is preferably from -20° C. to 200° C. and more preferably from 0° C. to 150° C. Typical examples include ricinoleic acid, oxystearic acid, lanopalmitic acid, oxylauric acid and oxymyristic acid, with oxystearic acid being particularly preferred. 
     The oxyfatty acid ester used herein include esters obtained by the reaction of oxyfatty acids as an alcohol component and acids, and esters obtained by the reaction of oxyfatty acids as an acid component and mono or polyhydric alcohols. 
     Acids which may be reacted with the oxyfatty acid include mono, di or tricarboxylic acids, and aliphatic acids are preferably used. Of these acids, aliphatic acids having 8 to 24 carbon atoms, such as caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid, behenic acid, oleic acid, oleic acid, eladic acid, linoleic acid, linolenic acid, stearolic acid and erucic acid, are particularly preferred. 
     Monohydric alcohols which can be used include methyl alcohol, ethyl alcohol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, sec-butyl alcohol, tert-butyl alcohol, n-amyl alcohol, isoamyl alcohol, active amyl alcohol, sec-amyl alcohol, diethylcarbinol, tert-amyl alcohol, fusel oil, pentazole, n-hexyl alcohol, methylamyl alcohol, ethylbutyl alcohol, heptyl alcohol, methylamyl carbinol, 3-heptanol, dimethylpentanol, n-octyl alcohol, sec-octyl alcohol, ethylhexyl alcohol, isooctyl alcohol, n-nonyl alcohol, diisobutyl carbinol, n-decyl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, isocetyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, eicosenol, and behenyl alcohol. There is no particular limitation on the number of carbon atoms contained in the monohydric alcohol, but those having 6 to 20 carbon atoms are preferably used. 
     There is no limitation on the type of polyhydric alcohol to be used in the preparation of the desired esters. For example, dihydric alcohols such as ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, dipropylene glycol, trimethylene glycol, butanediol, 1,5-pentanediol, hexylene glycol, octylene glycol, polyethylene glycol, polypropylene glycol and polybutylene glycol; trihydric alcohols such as glycerin, trimethylolpropane and 1,2,6-hexanetriol; tetrahydric alcohols such as pentaerythritol and sorbitan; pentahydric alcohols such as pentitol; hexahydric alcohols such as hexitol; and polycondensates of one or more of the foregoing polyhydric alcohols, such as diglycerin, polyglycerin, ditrimethylolpropane and dipentaerithritol. Of these, pentaerythritol and its condensate are preferably used. These alcohols may be used in combination with each other. In the esterification of the polyhydric alcohols, carboxylic acids may be added in combination with the oxyfatty acid to control the melting point of the oxyfatty acid ester. Such carboxylic acids include mono, di or tricarboxylic acids (e.g., aliphatic monocarboxylic acids). For the purpose, the carboxylic acids may be added in an amount of 30 mol% or less based on the total amount of the oxyfatty acids used in combination. 
     The oxyfatty acid esters used in the present invention preferably have a melting point of -30° C. to 150° C. and more preferably -20° C. to 80° C. 
     Representative examples of oxyfatty acid esters are shown below: 
     A-1: ester of 12-oxystearic acid with lauryl alcohol, (m.p., 25°-30° C.) 
     A-2: ester of 12-oxystearic acid with n-octanol, (m.p., 30°-35°C.) 
     A-3: diester of 12-oxystearic acid with neopentyl glycol, (paste-like at ordinary temperature) 
     A-4: triester of 12-oxystearic acid with trimethylolpropane (m.p., 31° C.) 
     A-5: tetraester of 12-oxystearic acid with pentaerythritol, (m.p., 25°-26° C.) 
     A-6: hexaester of 12-oxystearic acid with dipentaerythritol, (m.p., 30°-35° C.) 
     A-7: tetraester of 12-oxystearic acid/rosin/stearic acid (molar ratio: 4/0.5/1.5) mixture with dipentaerythritol, (m.p., 30°-45° C.) 
     A-8: ester of ricinoleic acid with stearic acid, (m.p., 30°-35° C.) 
     A-9: diester of 3-oxylauric acid with polyethylene glycol (average molecular weight: 600), (m.p., 25°-35° C.) 
     A-10: tetraester of 12-oxystearic acid/isostearic acid (molar ratio: 3/1) mixture with dipentaerythritol, (m.p., 30°-40° C.) 
     Of these, 12-oxyfatty acid esters are particularly preferably used in the invention. 
     Known ferromagnetic fine powders can be used in the invention, including γ-Fe 2  O 3 , Co-containing γ-Fe 2  O 3 , Fe 3  O 4 , Co-containing Fe 3  O 4 , CrO 2 , Co-Ni-P alloy, and Co-Ni-Fe alloy. Specific examples are described in Japanese Patent Publication Nos. 14090/69, 18372/70, 22062/72, 22513/72, 28466/71, 38755/71, 4286/72, 12422/72, 17284/72 18509/72, and 18573/72. 
     The amount of the magnetic powder used is from 50 to 2,000 parts by weight per 100 parts by weight of the binder. Hereinafter, unless otherwise specified, all parts are by weight. 
     The amount of the ester compound to be added is from 0.01 to 20 parts, preferably from 0.1 to 10 parts, preferably from 0.5 to 5 parts, per 100 parts of the magnetic powder. 
     The oxyfatty acid esters can be added in various manners. For example, the ferromagnetic fine powder is impregnated with the oxyfatty acid ester, the ester is added before or after the dispersion of the ferromagnetic fine powder in the binder, or the ester is coated on the magnetic layer which has been coated on a support base. Furthermore, the ester may be coated on the surface of a support base on which no magnetic layer has been provided and, thereafter, transferred to a magnetic layer on the other surface of the support base, or may be sprayed by means of, e.g., a spray. The ester may be coated in a discontinous condition. When the magnetic recording medium has non-magnetic layers such as a back layers and a protective layer, the ester may be incorporated in both the magnetic layer and the non-magnetic layer(s), or may be incorporated in the non-magnetic layer(s). 
     Useful binders include conventionally known thermoplastic resins, thermosetting or reactive resins, and their mixtures. 
     Thermoplastic resins which can be used are those resins having a softening point of 150° C. or lower, an average molecular weight of from 10,000 to 200,000, and a degree of polymerization of about 200 to about 500, and mixtures thereof. Examples are a vinyl chloride-vinyl acetate copolymer, a vinyl chloride-vinylidene chloride copolymer, a vinyl chloride-acrylonitrile copolymer, an acrylic acid ester-acrylonitrile copolymer, an acrylic acid ester-vinylidene chloride copolymer, an acrylic acid ester-styrene copolymer, a methacrylic acid ester-acrylonitrile copolymer, a methacrylic acid ester-vinylidene chloride copolymer, a methacrylic acid ester-styrene copolymer, a urethane elastomer, a nylon-silicone resin, a nitrocellulose-polyamide resin, polyvinyl fluoride, a vinylidene chloride-acrylonitrile copolymer, a butadiene-acrylonitrile copolymer, a polyamide resin, polyvinyl butyral, cellulose derivatives (e.g., cellulose acetate butyrate, cellulose diacetate, cellulose triacetate, cellulose propionate, and cellulose nitrate), a styrene-butadiene copolymer, a polyester resin, a chloro vinyl ether-acrylic acid ester copolymer, an amino resin, and various synthetic rubbers. 
     Specific examples of these resins are described in, for example, Japanese Patent Publication Nos. 6877/62, 12528/64, 19282/64, 5349/65, 20907/65, 9463/66, 14059/66, 16985/66, 6428/67, 11621/67, 4623/68, 15206/68, 2889/69, 17947/69, 18232/69, 14020/70, 14500/70, 18573/72, 22063/72, 22064/72, 22068/72, 22069/72, 22070/72, and 27886/72. 
     Thermosetting or reactive resins have a molecular weight of 200,000 or less in the state of coating solution and, when heated after coating and drying, undergo reactions such as condensation and addition, having an infinite molecular weight. Of these resins, those resins are preferred that do not soften or melt before heat-decomposition occurs. Typical examples are a phenol resin, an epoxy resin, a polyurethane curing type resin, a urea resin, a melamine resin, an alkyd resin, a silicone resin, an acryl-based reactive resin, an epoxy-polyamide resin, a cellulose nitrate-melamine resin, a mixture of a high molecular weight polyester resin and an isocyanate prepolymer, a mixture of a methacrylate copolymer and a diisocyanate prepolymer, a mixture of polyester polyol and polyisocyanate, a urea-formaldehyde resin, a mixture of low molecular weight glycol/high molecular weight diol/triphenylmethane triisocyanate, a polyamine resin, and their mixtures. 
     These compounds are described in Japanese Patent Publication Nos. 8103/64, 9779/65, 7192/66, 8016/66, 14275/66, 18179/67, 12081/68, 28023/69, 14501/70, 24902/70, 13103/71, 22065/72, 22056/72, 22067/72, 22072/72, 22073/72, 28045/72, 28048/72, 28922/72, etc. 
     These binders are used alone or in combination with each other. Other additives such as dispersants, lubricants and abrasives may be added thereto. 
     Various lubricants can be used in combination with the oxyfatty acid esters of the invention. Examples of such lubricants include carbon black of various sizes (mean grain size: 10 to 1,000 mμ), silicon oil, graphite, molybdenum disulfide, tungsten disulfide, fatty acid esters derived from monobasic fatty acids containing from 12 to 16 carbon atoms and monohydric alcohols containing from 3 to 12 carbon atoms, fatty acid esters derived from monobasic fatty acids containing at least 17 carbon atoms and monohydric alcohols (wherein total number of carbon atoms in the fatty acid and alcohol being from 21 to 23) and their mixtures. These lubricatns can be added in an amount of 0.2 to 20 parts per 100 parts of the binder. Specific examples of such lubricants are described in Japanese Patent Publication No. 23889/68, U.S. Pat. No. 3,423,233, and Japanese Patent Publication No. 28043/72. 
     Dispersants which can be used include fatty acids containing from 12 to 18 carbon atoms: R 1  COOH (wherein R 1  is an alkyl group containing from 11 to 17); for example, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, elaidic acid, linoleic acid, linolenic acid, and stearolic acid; metallic soaps comprising the alkali mtal (e.g., Li, Na, and K) or alkaline earth metal (e.g., Mg, Ca, and Ba) salts of the foregoing fatty acids; and lecithin. In addition, higher alcohols containing at least 12 carbon atoms and their sulfuric acid esters, etc. can be used. The amount of the dispersant added is from 1 to 20 parts per 100 parts of the binder. Specific examples of such dispersants are described in, for example, Japanese Patent Publication Nos. 28369/64, 17945/69, 15001/73, U.S. Pat. Nos. 3,387,993, and 3,470,021. 
     Commonly used abrasives can be used, including fused alumina, silicon carbide, chromium oxide, corundum, synthetic corundum, diamond, synthetic diamond, garnet, and emery (main components: corundum and magnetite). The mean grain diameter of the abrasives is from 0.05 to 5 μm and preferably from 0.1 to 2 μm. The amount of the abrasive added is from 2 to 20 parts per 100 parts of the binder. Specific examples of the abrasives are described in, for example, U.S. Pat. No. 3,687,725. 
     Organic solvents which can be used in kneading and coating include ketones such as acetone, methyl ethyl ketone, methyl butyl ketone, and cyclohexanone; alcohols such as methanol, ethanol, propanol, and butanol; esters such as methyl acetate, ethyl acetate, butyl acetate, ethyl lactate, and glycol acetate monoethyl ether; ethers and glycol ethers such as glycol dimethyl ether, glycol monoethyl ether, and dioxane; tars (aromatic hydrocarbons) such as benzene, toluene, and xylene; and chlorinated hydrocarbons such as methylene chloride, ethylene chloride, carbon tetrachloride, chloroform, ethylenechlorohydrin, and dichlorobenzene. 
     In preparing a magnetic layer, a desired combination of the above-described components is dissolved in an organic solvent, and the resulting coating solution is then coated on a non-magnetic support base. The thickness of the magnetic layer is generally from 0.01 to 50 μm, preferably from 0.05 to 30 μm and more preferably from 0.1 to 20 μm. When a tape is to be produced, the thickness of the support base is from about 2.5 to about 100 μm and preferably from about 3 to about 40 μm. Materials which can be used in preparing such supports include polyesters such as polyethylene terephthalate and polyethylene naphthalate; polyolefins such as polypropylene; cellulose derivatives such as cellulose triacetate and cellulose diacetate; vinyl-based resins such as polyvinyl chloride; polycarbonate; and like plastics; metals such as aluminum; and ceramics such as glass. 
     The foregoing magnetic recording layer can be provided on the support base by techniques such as air doctor coating, blade coating, air knife coating, squeese coating, dip coating, reverse roll coating, transfer roll coating, gravure coating, kiss coating, cast coating, and spray coating. Other coating methods can be used. These coating techniques are described in detail in Coating Kogaku (Coating Engineering), published by Asakura Shoten (Tokyo), pp. 253-277 (Mar. 20, 1971). 
     The magnetic layer thus coated on the support is, if necessary, subjected to a treatment to orientate the magnetic powder therein and then dried. Further, if necessary, a surface smoothning processing is applied, or the magnetic material is cut to the desired size to produce the magnetic recording medium of the invention. These procedures are described in, for example, Japanese Patent Publication Nos. 23625/65, 28368/64, and U.S. Pat. No. 3,473,960. In addition, the methods described in Japanese Patent Publication No. 13181/66 are believed to be basic and important techniques in this field. 
    
    
     The present invention is hereinafter described in greater detail by reference to the following examples. It will be understood that the components, the compounding ratio, the order of operations, etc. can be changed or modified without departing from the spirit of the invention. Thus the present invention is not limited to the examples. 
     EXAMPLE 1 
     
         ______________________________________Fe.sub.2 O.sub.3 powder  300    partsVinyl chloride-vinyl acetate                    30     parts(87/13) copolymer (degree ofpolymerization: about 400)Epoxy resin (epoxy group 30     partscontent: 0.56)Carbon black mean grain size: 80 mμ)                    5      partsEthyl acetate            250    partsCyclohexanone            250    partsCompound to be tested    x      parts______________________________________ 
    
     These ingredients were placed in a ball mill and fully kneaded, and 35 parts of Desmodule L-75 (trade name for a polyisocyanate compound produced by Bayer Co.) was added thereto. The resulting mixture was uniformly mixed and dispersed to prepare a magnetic coating composition. 
     This composition was coated on a polyester film support and dried to produce a magnetic tape. 
     Run No. 1 is a comparative example in which no lubricant was added, Run Nos. 2 to 7 are examples in which oxyfatty acid esters of the invention were added, and Run Nos. 8 to 13 are comparative examples in which conventionally known lubricants were each added. The results are shown in Table 1 below. 
     
                                           TABLE 1__________________________________________________________________________               Amount                    Number of                           RF   SurfaceRun No.Compound       (x parts)                    Runnings                           Output                                Properties__________________________________________________________________________1    None           --   16        0 dB                                A2    Ester of 12-oxystearic acid                1   more than 60                           +1.2 dB                                Awith n-octanol (A-2)3    Ester of 12-oxystearic acid               10   more than 60                           +1.3 dB                                Awith n-octanol (A-2)4    Hexaester of 12-oxystearic                1   more than 60                           +1.0 dB                                Aacid with dipentaerythritol(A-6)5    Hexaester of 12-oxystearic               10   more than 60                           +1.0 dB                                Aacid with dipentaerythritol(A-6)6    Ester of 12-oxystearic acid                1   more than 60                           +1.0 dB                                Awith lauryl alcohol (A-1)7    Ester of 12-oxystearic acid               10   more than 60                           +0.9 dB                                Awith lauryl alcohol (A-1)8    Butyl stearate  1   13     +1.1 dB                                A9    Butyl stearate 10   10     +1.2 dB                                A10   Glycerol tristearate                1   more than 60                           *    B11   Glycerol tristearate               10   more than 60                           *    B12   Silicone (viscosity: 1,000 C.S.)                1   17     -0.5 dB                                A13   Silicone (viscosity: 1,000 C.S.)               10   20     *    A__________________________________________________________________________ Note: *Not measured because of many dropouts. 
    
     The methods of measurement and the criterion are as follows: 
     Number of Runnings 
     A test tape was mounted on a tape deck and repeatedly run under the conditions of 30° C. and 80% RH. The number of runnings until &#34;tape squeal&#34; occurred was measured twice, and the average value of two measurements was indicated. 
     RH Output 
     With regard to the RH output, an output when 4 MHz was recorded and reproduced was indicated in relative dB. 
     Surface properties 
     The surface properties were determined with a microscope and the eye. A test tape, when no contaminants were observed on the magnetic surface thereof, was given the symbol (A) and when some contaminants were observed, the symbol (B) was given. 
     In Run Nos. 8 to 13, i.e., comparative examples in which the conventionally known compounds were used, the number of runnings and S/N surface properties were not satisfactory. On the other hand, in Run Nos. 2 to 7, i.e., examples of the invention, the addition of oxyfatty acid esters brought about very satisfactory tape characteristics. 
     EXAMPLE 2 
     
         ______________________________________Fe.sub.2 O.sub.3 powder 300    partsVinyl chloride-vinyl acetate-                   10     partsvinyl alcohol (90/3/7) copolymerCellulose nitrate (molecular weight:                   20     partsabout 10,000)Epoxy resin             30     partsCarbon black (mean grain size:                   10     parts35 mμ)Lecithin                2      partsOleic acid              3      partsEthyl acetate           250    partsCyclohexanone           250    partsCompound to be tested   x      parts______________________________________ 
    
     These ingredients were placed in a ball mill and fully mixed, and 40 parts of Desmodule L-75 (trade name for a polyisocyanate compound produced by Bayer Co.) was added thereto. The resulting mixture was uniformly mixed and dispersed to prepare a magnetic coating composition. 
     This composition was coated on a polyester film support and dried to produce a magnetic tape. This magnetic tape was evaluated, and the results are shown in Table 2 below. 
     
                                           TABLE 2__________________________________________________________________________                   Amount                        Number ofRun No.Compound           (parts)                        Runnings                               RF Output__________________________________________________________________________14   None               --   22        0 dB15   Hexaester of 12-oxystearic acid with                    1   more than 60                               -0.3 dBdipentaerythritol (A-6)16   Hexaester of 12-oxystearic acid with                   10   more than 60                                  0 dBdipentaerythritol (A-6)17   Ester of 12-oxystearic acid with lauryl                   10   more than 60                                  0 dBalcohol (A-1)18   Ester of 12-oxystearic acid with lauryl                   70   17     +0.1 dBalcohol (A-1)19   Tetraester of 12-oxystearic acid/rosin/                    1   more than 60                                  0 dBstearic acid (molar ratio: 4/0.5/1.5)mixture with dipentaerythritol (A-7)20   Tetraester of 12-oxystearic acid/rosin/                   10   42     +0.2 dBstearic acid (molar ratio: 4/0.5/1.5)mixture with dipentaerythritol (A-7)21   Ester of ricinoleic acid with stearic                    1   more than 60                                  0 dBacid (A-8)22   Ester of ricinoleic acid with stearic                   10   51     -0.2 dBacid (A-8)23   Diester of 3-oxylauric acid with poly-                    1   more than 60                               +0.1 dBethylene glycol (average molecularweight: 600) (A-9)24   Diester of 3-oxylauric acid with poly-                   10   48     +0.3 dBethylene glycol (average molecularweight: 600) (A-9)25   Tetraester of 12-oxystearic acid/                    1   more than 60                                  0 dBisostearic acid (molar ratio: 3/1)mixture with dipentaerythritol (A-10)26   Tetraester of 12-oxystearic acid/                   10   50     +0.3 dBisostearic acid (molar ratio: 3/1)mixture with dipentaerythritol (A-10)27   Anhydrosorbitol monolaurate                   10   25     +0.2 dB__________________________________________________________________________ 
    
     The characteristics of Table 2 were measured in the same manner as in Example 1. 
     As can be seen from Tables 1 and 2, compared with the conventionally known esters, the oxyfatty acid esters bring about great effects in connection with running, particularly under high humidity conditions. 
     While the invention has been described in detail and with reference to specific embodiment thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.