Abstract:
Provided is an air injection nozzle, which is used for a heat treatment such as the heating, cooling or thermal insulation of a running sheet (or film) with injected air. In the air injection face, a number of air injection holes are so arrayed at an interval (Py) in first and second rows that the air injection holes of a first row and the air injection holes of a second row are staggered. The first row and the second row are positioned at an interval (Px). The air injection face and the sheet running face confront each other at a distance (L). The air injection holes in the air injection face have a diameter (D). The interval (Px), the interval (Py), the distance (L) and the diameter (D) satisfy Formula (1): 6≦(L/D)/(Px/Py)≦9, and Formula (2): 4≦L/D≦8. This air injection nozzle is employed as a resin film heat treating apparatus in a tenter oven to be used for manufacturing the resin film.

Description:
TECHNICAL FIELD 
       [0001]    The present invention relates to an air ejection nozzle used for heating, cooling or heat-retaining a resin film and a tenter oven using the same. 
       BACKGROUND ART 
       [0002]    Known methods for producing a biaxially oriented resin film such as a biaxially oriented polyester film include a sequential biaxial stretching method comprising the steps of continuously discharging a flowable resin from a die as a sheet, cooling and solidifying the discharged sheet on a casting drum, to form a cast film, stretching the formed cast film in the carrying direction of the film, namely, in the machine direction using a longitudinal stretching machine and subsequently stretching the film stretched in the machine direction (monoaxially oriented film) in the width direction of the film (transverse direction) in a tenter oven, and a simultaneous biaxial stretching method of stretching the cast film in the carrying direction of the film (machine direction) and in the width direction of the film (transverse direction) in a tenter oven. 
         [0003]    In the tenter oven used for these production methods, installed are air ejection nozzles having many air ejection holes formed in the surfaces thereof to face a surface of a resin film passing through the tenter oven. Usually, multiple air ejection nozzles are installed at regular intervals in the resin film carrying direction in such a manner that the longitudinal direction of the air ejection nozzles is kept perpendicular to the resin film carrying direction. 
         [0004]    The air ejection nozzles are provided in a nozzle housing. The nozzle housing has an air supply passage therein and has an air ejection face as one of the surfaces thereof. The ends on one side of the many air ejection holes are opened in the air ejection face, and the ends on the other side are opened into the air supply passage. To another surface or other two surfaces of the nozzle housing, an air supply duct is connected, and one end of the air supply duct communicates with the air supply passage in the nozzle housing while the other end is connected with a heat exchanger and a fan. The air controlled to a desired temperature by the heat exchanger is sent by the fan to the respective air ejection holes through the air supply duct and the air supply passage in the nozzle housing, and is ejected toward the surface of the resin film from the respective air ejection holes open in the air ejection face of the housing. The ejected air is usually collected from suction ports formed in the tenter oven, to be reused. 
         [0005]    In general, the tenter oven has multiple divisional zones such as a preheating zone, stretching zone, heat setting zone and cooling zone in the resin film carrying direction. The tenter oven has such a structure that the temperatures of the air used in the respective zones can be set independently for the respective zones. The tenter oven is provided with numerous clips outside both the edges of the resin film for holding the edges of the resin film moving along rails from the inlet portion toward the outlet portion of the tenter oven. 
         [0006]    In the tenter oven, the resin film held at both the edges thereof and carried by the clips is heated in the preheating zone to a temperature suitable for stretching, and stretched at least in the transverse direction in the stretching zone, then being heat-treated in the heat setting zone, cooling zone, etc. The air ejection nozzles are used to eject the air controlled at a desired temperature toward the surface of the resin film, for promoting the heat exchange between the air and the resin film, to thereby heat, cool or heat-retain the resin film. 
         [0007]    The properties of the resin film produced like this are affected by the heat history which the resin film encounters while it passes through the respective zones of the tenter oven. Therefore, to obtain a resin film having uniform properties in the width direction of the resin film, it is important that the heat exchange between the air ejected from the air ejection nozzles and the resin film takes place uniformly in the width direction of the resin film. For this purpose, the air ejection nozzles are required to assure that the temperature of the air striking the resin film is uniform in the width direction of the resin film and that the heat transfer efficiency of the air ejection nozzles is uniform in the width direction of the resin film. 
         [0008]    An air ejection nozzle having a continuous air ejection hole formed in the width direction of the resin film on the surface thereof facing the surface of the resin film is called a slit nozzle. As a conventional slit nozzle for the purpose of keeping the ejection velocity and temperature of air uniform in the width direction of the resin film, a nozzle having a duct of countercurrent flow design is proposed (see Patent Literature 1). However, a slit nozzle has a problem that the air jet is liable to bend in the progress direction. If the air jet bends in the progress direction, air masses different in temperature are mixed at a portion where zones different in set temperature contact each other, and large temperature irregularity can occur in the width direction of the resin film. In this case, it is difficult to obtain a resin film having uniform properties in the width direction. 
         [0009]    According to the finding by the present inventors, the abovementioned problem that the air jet is liable to bend in the progress direction can be improved by arranging air ejection holes discretely in the width direction of the resin film, that is, by arranging many air ejection holes independent of each other at regular intervals. The reason is considered to be that the air jets finely divided in the width direction of the resin film form air passing portions between the respectively adjacent air jets, such that the air existing in the front and back of the air ejection nozzle can be guided to pass through the air passing portions, to ease the difference of the pressures in the front and back of the air ejection nozzle. As such an air ejection nozzle, there is a hole nozzle having many circular air ejection holes in the face thereof facing the surface of the resin film. However, if many air ejection holes are arranged at regular intervals in the width direction of the resin film, the heat transfer rate of the surface of the resin film becomes uneven in the width direction of the resin film, to raise a problem that the uniformity of heat transfer efficiency declines. 
         [0010]    Proposed is a conventional hole nozzle for the purpose of enhancing the heat transfer rate of the surface of the resin film, in which while the distance between the air ejection holes and the surface of the resin film is set at 4 to 6 times the diameter of the air injection holes, many such air ejection holes are arranged zigzag in six rows in the direction perpendicular to the resin film carrying direction (see Patent Literature 2). However, the magnitude of heat transfer rate and the uniformity of heat transfer efficiency in the width direction of the resin film are different problems, and it is difficult to improve the uniformity of heat transfer efficiency in the width direction of the resin film only by discussing the diameter of air ejection holes and the number of rows of air ejection holes. 
         [0011]    The conventional hole nozzles intended to improve the uniformity of heat transfer efficiency in the width direction of the resin film include a hole nozzle used as a device for cooling the resin film on a casting drum (see Patent Literature 3) and a hole nozzle used as a drying device of a printing machine or coating machine (see Patent Literature 4). However, these hole nozzles are effective in the case where the distance between the air ejection holes and the surface of the resin film is made shorter than 20 mm, and it is not preferred to use such hole nozzles in a tenter oven in which the distance between the air ejection holes and the surface of the resin film is generally 140 to 270 mm, since the heat transfer rate of the surface of the resin film may decline remarkably. 
         [0012]    Patent Literature 1: JP 1634915 B 
         [0013]    Patent Literature 2: JU 2528669 B 
         [0014]    Patent Literature 3 JP 3374527 B 
         [0015]    Patent Literature 4: JU 2008679 B 
       SUMMARY OF INVENTION 
     Technical Problem 
       [0016]    One object of the invention is to solve the problems of the abovementioned prior art by providing an air injection nozzle good in the uniformity of heat transfer efficiency in the width direction of the resin film. Another object of the invention is to provide a tenter oven good in the uniformity of heat transfer efficiency in the width direction of the resin film using the air ejection nozzle of the invention. 
       Solution to Problem 
       [0017]    An air ejection nozzle of the invention comprises: 
         [0018]    (a) an air ejection nozzle which is provided against a passing plane of a resin film carrying one direction with a clearance and used for ejecting air toward a surface of the resin film, wherein 
         [0019]    (b) the air ejection nozzle comprises a nozzle housing, and the nozzle housing has an air supply passage therein, an air ejection face facing the passing plane of the resin film, and many air ejection holes opening to the air supply passage and opening in the air ejection face respectively, 
         [0020]    (c) a figure of each of openings of the many air ejection holes in the air ejection face is circle, 
         [0021]    (d) the many air ejection holes are arranged in the air ejection face in two rows of a first row and a second row in the direction perpendicular to the carrying direction of the resin film, and a state of arrangement between the air ejection holes of the first row and the air ejection holes of the second row is a zigzag arrangement, and 
         [0022]    (e) the distance L (mm) between the air ejection face and the passing plane of the resin film, the diameter D (mm) of the respective air ejection holes in the air ejection face, the interval Px (mm) in the carrying direction of the resin film between a first air ejection holes-aligned straight line passing through the centers of the multiple air ejection holes arranged in the first row and a second air ejection holes-aligned straight line passing through the centers of the multiple air ejection holes arranged in the second row, and each interval Py (mm) between the centers of the respectively adjacent air ejection holes in the first air ejection holes-aligned straight line and between the centers of the respectively adjacent air ejection holes in the second air ejection holes-aligned straight line satisfy the following formulae (1) and (2): 
         [0000]      6≦( L/D )/( Px/Py )≦9  formula (1) 
         [0000]      4≦ L/D≦ 8  formula (2) 
         [0023]    In the air ejection nozzle of the invention, it is preferred that the following formula (3) is satisfied: 
         [0000]      12≦ L/B≦ 30     formula (3) 
         [0024]    where B=2π(D/2) 2 /Py (where π is the ratio of the circumference of a circle to its diameter). 
         [0025]    In the air ejection nozzle of the invention, it is preferred that the distance L is 140 to 270 mm. 
         [0026]    A tenter oven of the invention comprising: 
         [0027]    (a) an oven housing having an inlet of a resin film at one end thereof and an outlet of the resin film at the other end thereof, 
         [0028]    (b) having a stretching zone between the inlet of the resin film and the outlet of the resin film, for stretching the resin film at least in the direction perpendicular to the carrying direction of the resin film while the resin film is carried from the inlet of the resin film toward the outlet of the resin film, and 
         [0029]    (c) having a heat treatment zone between the inlet of the resin film and the outlet of the resin film, for ejecting air toward a surface of the resin film and heat treating the resin film, wherein 
         [0030]    (d) the air ejection face of the air ejection nozzle of the invention is positioned to face a passing plane of the resin film formed between the inlet of the resin film and the outlet of the resin film, and 
         [0031]    (e) the air ejection nozzle is provided in the heat treatment zone in such a manner that the directions of the first row and the second row of the air ejection holes of the air ejection nozzle are kept perpendicular to the carrying direction of the resin film. 
         [0032]    In the tenter oven of the invention, it is preferred that the heat treatment zone includes a preheating zone, a stretching zone, a heat setting zone and a cooling zone in the order from the inlet of the resin film toward the outlet of the resin film, and the air ejection nozzle is provided at least in one of these zones. 
         [0033]    In the tenter oven of the invention, the stretching zone may be a simultaneously biaxial stretching zone in which the resin film is stretched in the direction perpendicular to the carrying direction of the resin film and stretched in the carrying direction of the resin film. 
         [0034]    In the tenter oven of the invention, it is preferred that the air ejection nozzle is provided on both sides of the passing plane of the resin film having a clearance formed against the passing plane of the resin film. 
       ADVANTAGEOUS EFFECTS INVENTION 
       [0035]    The air ejection nozzle of the invention has many air ejection holes having specific forms and arranged in a specific positional relationship. Therefore, if the air ejection nozzle is used for heat-treating a resin film, excellent uniformity of heat transfer efficiency in the width direction of the resin film can be obtained. Therefore, the tenter oven of the invention using the air ejection nozzle of the invention allows a production of a resin film having homogeneous heat-treated properties in the width direction. 
     
    
     
       BRIEF DESCRIPTION OF DRAWINGS 
         [0036]      FIG. 1  is an enlarged plan view showing a portion of the air ejection face of an air ejection nozzle of the invention shown in  FIG. 2 . 
           [0037]      FIG. 2  is a perspective view showing an example of the air ejection nozzle of the invention. 
           [0038]      FIG. 3  is a plan view for explaining an example of the heat transfer rate distribution on a surface of a resin film. 
           [0039]      FIG. 4  is a plan view (top view) for explaining an example of a tenter apparatus. 
           [0040]      FIG. 5  is the C 1 -C 1  sectional view of  FIG. 4  in arrow direction. 
           [0041]      FIG. 6  is the C 2 -C 2  sectional view of  FIG. 5  in arrow direction. 
           [0042]      FIG. 7  is a schematic process chart for explaining an example of a resin film production process using a sequential biaxial stretching method. 
           [0043]      FIG. 8  is a sectional view of an analysis model for explaining an example of the analysis model used for calculating the heat transfer rate distribution on a surface of a resin film. 
           [0044]      FIG. 9  is a chart for explaining the heat transfer efficiency distribution of an air ejection nozzle in the width direction of a resin film. 
           [0045]      FIG. 10  is a graph obtained by plotting the values of (L/D)/(Px/Py) and the values of heat transfer efficiency irregularity Rp obtained in examples and comparative examples of the invention. 
           [0046]      FIG. 11  is a graph obtained by plotting the values of Px/Py and the values of L/D obtained in examples and comparative examples of the invention. 
           [0047]      FIG. 12  is a graph showing the thickness distribution in the width direction of the resin film in Example 16 of the invention. 
           [0048]      FIG. 13  is a graph showing the thickness distribution in the width direction of the resin film in Comparative Example 18 of the invention. 
       
    
    
     REFERENCE SIGNS LIST 
       [0000]    
       
         
           
               1  air ejection nozzle 
               1 A upper air ejection nozzle 
               1 Af,  1 Bf air ejection face 
               1   a  nozzle housing 
               1 B lower air ejection nozzle 
               2 ,  2 A,  2 B air ejection hole 
               2   a  first row in the arrangement of air ejection holes 
               2   b  second row in the arrangement of air ejection holes 
               3   a  straight line passing through the centers of the air ejection holes arranged in first row (first air ejection holes-aligned straight line) 
               3   b  straight line passing through the centers of the air ejection holes arranged in second row (second air ejection holes-aligned straight line) 
               4   a  center line between air ejection nozzle  1  and air ejection nozzle  11   a  adjacent to the air ejection nozzle  1  on the upstream side in the resin film carrying direction 
               4   b  center line between air ejection nozzle  1  and air ejection nozzle  11   b  adjacent to the air ejection nozzle  1  on the downstream side in the resin film carrying direction 
               5   a  straight line passing through the centers of the air ejection holes arranged in the first row  2   a  and drawn in the resin film carrying direction 
               5   b  straight line passing through the center between straight line  5   a  and straight line  5   c    
               5   c  straight line passing through the centers of the air ejection holes arranged in the second row  2   b  and drawn in the resin film carrying direction 
               11   a ,  11   b  air injection nozzle adjacent to air ejection nozzle  1   
               20  air ejection plate 
               21  opening of air ejection hole 
               31  resin film 
               31   a  resin sheet 
               31   b  non-oriented film 
               31   c  monoaxially oriented film 
               31   b  biaxially oriented film 
               31   e  film as a product 
               33  heat transfer rate distribution on a surface of a resin film 
               40 ,  40 A air ejection face 
               41  air supply passage 
               41   a ,  41   b  air introducing port 
               51  tenter oven 
               51 A oven housing 
               51   a  inlet of resin film 
               51   b  outlet of resin film 
               52 A,  52 B heat exchanger 
               53 A,  53 B fan 
               54  suction duct 
               54 A,  54 B suction port 
               61  outside space of tenter oven 
               62  end boundary of analysis space 
               71 A,  71 B rail 
               73 A,  73 B clip 
               91  extruder 
               92  die 
               93  casting drum 
               94  longitudinal stretching machine 
               95  tenter apparatus 
               96  winding roll 
               511  preheating zone 
               512  stretching zone 
               523  heat setting zone 
               514  cooling zone 
             D diameter of air ejection hole (opening of air ejection hole in air ejection face) 
             FTD carrying direction of a resin film 
             FPf passing plane of a resin film 
             HTC magnitude indicator of heat transfer rate 
             HTCL portion of large heat transfer rate 
             HTCS portion of small heat transfer rate 
             L distance between the air ejection face where air ejection holes are arranged and the passing plane of a resin film 
             Pn section between center line  4   a  and center line  4   b    
             Px interval between straight line  3   a  and straight line  3   b    
             Py interval between the centers of respectively adjacent air ejection holes in the respective rows of first row  2   a  and second row  2   b    
             Q heat transfer efficiency of air ejection nozzle 
             Qa average heat transfer efficiency of air ejection nozzle 
             Qmax maximum value of heat transfer efficiency of air ejection nozzle 
             Qmin minimum value of heat transfer efficiency of air ejection nozzle 
             Rq heat transfer efficiency irregularity of air ejection nozzle in the width direction of a resin film 
             Rt thickness irregularity in the width direction of a resin film 
             Ta average value of thickness distributed in the width direction of a resin film 
             Tn minimum value of thickness distributed in the width direction of a resin film 
             Tx maximum value of thickness distributed in the width direction of a resin film 
           
         
       
     
       DESCRIPTION OF EMBODIMENTS 
       [0118]    Known methods for producing a resin film include a melt film formation method and a solution film formation method. In these film formation methods, a molten resin or a resin solution is continuously extruded from a slit opening of a die, to form a cast sheet-like resin film. The obtained cast resin film is then stretched in the machine direction and/or in the transverse direction. 
         [0119]    Below is explained an example in reference to drawings, in which an air ejection nozzle and a tenter oven of the invention are applied to a process for producing a biaxially oriented resin film to be obtained by stretching a cast resin film formed by the aforementioned melt film formation method in the machine direction and in the transverse direction. 
         [0120]      FIG. 7  is a schematic process chart showing an example of a resin film production process using a sequential biaxial stretching method. In the sequential biaxial stretching method, a cast resin film is stretched at first in the machine direction, to obtain a monoaxially oriented resin film, and the obtained monoaxially oriented resin film is stretched in the transverse direction. 
         [0121]    The resin film production process using a sequential biaxial stretching method is, as shown in  FIG. 7 , provided with an extruder  91 , die  92 , casting drum  93 , longitudinal stretching machine  94 , tenter apparatus  95  and winding roll  96 . 
         [0122]    A resin polymer is melted in the extruder  91  and extruded toward the die  92 , being discharged as a sheet from the die  92 . The resin sheet  31   a  discharged from the die  92  is cooled and solidified by the casting drum  93 , to obtain a cast film  31   b . Then, the cast film  31   b  is stretched by the longitudinal stretching machine  94  in the machine direction, namely, in the carrying direction, to obtain a monoaxially oriented film  31   c . The obtained monoaxially oriented film  31   c  is stretched in the tenter apparatus  95  in the transverse direction, to obtain a biaxially oriented film  31   d . Subsequently, the biaxially oriented film  31   d  is continuously wound around the winding roll  96 , to obtain a film  31   e  as a rolled product. Hereinafter, the cast film  31   b , monoaxially oriented film  31   c  or biaxially stretched film  31   d  may be called simply as a resin film  31 . 
         [0123]    In the case where a surface of the film as a product is required to be modified, the film may be coated on the surface with a desired coating liquid as the case may be. When the film is coated, the monoaxially stretched film  31   c  is coated on the surface immediately before the tenter apparatus  95  in the production process shown in  FIG. 7 . 
         [0124]    A case of using a sequential biaxial stretching method has been explained. In the case where a simultaneous biaxial stretching method is used, the longitudinal stretching machine  94  is not used, and the cast film  31   b  cooled and solidified by the casting drum  93  is stretched in the tenter apparatus  95  simultaneously in the longitudinal direction (carrying direction) of the resin film and the width direction of the resin film, to obtain a biaxially oriented film. 
         [0125]    The carrying direction of the resin film refers to the direction in which the continuous resin film runs continuously, namely, the longitudinal direction of the continuously running resin film, and in the production process of  FIG. 7 , the carrying direction refers to the direction in which the resin film runs from the extruder  91  toward the winding roll  96 . 
         [0126]      FIG. 4  is a plan view (top view) showing an example of the tenter apparatus  95  shown in  FIG. 7 . In  FIG. 4 , the tenter apparatus  95  has rail  71 A and rail  71 B disposed in opposite to each other, numerous clips  73 A and  73 B running along the rails  71 A and  71 B, and a tenter oven  51  for ejecting the air controlled to a desired temperature to a surface of the rein film and collecting the ejected air for recycled use. The direction in which the resin film  31  is carried in the tenter oven  51  is indicated by arrow FTD. The tenter oven  51  comprises an oven housing  51 A, and the oven housing  51 A has a resin film inlet  51   a  at one end thereof and a resin film outlet  51   b  at the other end thereof. 
         [0127]    The clips  73 A and  73 B hold both the edges of the resin film  31  at the resin film inlet  51   a  and pass through the tenter oven  51 , releasing the resin film  31  at the resin film outlet  51   b.    
         [0128]    The tenter oven  51  has at least a stretching zone between the resin film inlet  51   a  and the resin film outlet  51   b  for stretching the resin film  31  in the direction perpendicular to the carrying direction FTD of the resin film  31  while the resin film  31  is carried from the resin film inlet  51   a  to the resin film outlet  51   b . Further, the tenter oven  51  has heat treatment zones between the resin film inlet  51   a  and the resin film outlet  51   b  for ejecting air toward a surface of the resin film  31  for heat-treating the resin film. 
         [0129]    In this example, the tenter oven  51  has four heat treatment zones including a preheating zone  511 , a stretching zone  512 , a heat setting zone  513  and a cooling zone  514  in the order from the upstream side to the downstream side in the carrying direction FTD of the resin film  31 , and desired air temperatures can be set in the respective zones. 
         [0130]    Each of the zones may also be further divided into multiple chambers in the carrying direction FTD of the resin film  31 , so that the temperature of air can be set differently in the respective chambers. That is, the tenter oven  51  can also be constituted, for example, such that the preheating zone  511  has three chambers, that the stretching zone  512  has four chambers, that the heat setting zone  513  has two chambers and that the cooling zone  514  has one chamber. In this case, the temperatures of the respective chambers of each zone can also be independently set. 
         [0131]    With regard to the air temperature ranges of the respective zones, in the case where the resin film  31  is, for example, a polyester film, it is preferred that the temperature of the preheating zone  511  is 80 to 140° C., that the temperature of the stretching zone  512  is 80 to 200° C., that the temperature of the heat setting zone  513  is 150 to 240° C. and that the cooling zone  514  is 50 to 200° C. 
         [0132]    If the rails  71 A and  71 B are installed to be gradually wider in the relative distance between the rail  71 A and the rail  71 B (the gauge between the rail  71 A and the rail  71 B in the direction perpendicular to the carrying direction FTD of the resin film  31 ) in the stretching zone  512 , the resin film  31  can be stretched in the width direction thereof (the direction perpendicular to the carrying direction FTD of the resin film  31 ). As required, if a section in which the relative distance between the rail  71 A and the rail  71 B becomes gradually narrow is established in the heat setting zone  513  or in the cooling zone  514 , the resin film  31  can be treated to be relaxed in the width direction thereof. 
         [0133]    In the case where a simultaneous biaxial stretching method is employed, in the stretching zone  512  of the tenter oven  51 , the intervals between the respective clips  73 A and the intervals between the respective clips  73 B respectively running along the rails  71 A and  71 B are gradually widened. As a result, the resin film  31  can be stretched also in the carrying direction FTD, to allow simultaneous biaxial stretching. 
         [0134]      FIG. 5  is the C 1 -C 1  sectional view of  FIG. 4  in the arrow direction.  FIG. 6  is the C 2 -C 2  sectional view of  FIG. 5  in the arrow direction. The tenter oven  51  shown in  FIG. 4  has multiple upper air ejection nozzles  1 A installed at intervals in the carrying direction FTD of the resin film  31 , to face the upper surface of the resin film  31  as shown in  FIG. 5 , and further has multiple lower air ejection nozzles  1 B installed at intervals in the carrying direction FTD of the resin film  31 , to face the lower surface of the resin film  31 . In the heat setting zone  513  of  FIG. 5 , six upper air ejection nozzles and six lower air ejection nozzles are shown. As shown in  FIG. 6 , the respective upper air ejection nozzles  1 A and the respective lower air ejection nozzles  1 B are installed to extend in the width direction of the resin film  31  (the direction perpendicular to the carrying direction FTD). 
         [0135]    On the top surface of the oven housing  51 A of the tenter oven  51 , heat exchangers  52 A and  52 B are installed. The air controlled to a desired temperature by the heat exchangers  52 A and  52 B is sent by fans  53 A and  53 B into the respective air ejection nozzles  1 A and  1 B, and discharged from the air ejection holes  2 A and  2 B formed in the faces (air ejection faces)  1 Af and  1 Bf of the air ejection nozzles  1 A and  1 B facing the surfaces of the resin film  31 . The discharged air passes through the suction ports  54 A and  54 B in the tenter oven  51  and is collected into the heat exchangers  52 A and  52 B. The collected air is used in recycle in the tenter oven  51 . Meanwhile,  FIG. 5  shows the portion of the heat setting zone  513  in the tenter oven  51  of the tenter apparatus  95 , but the same structure can be used also in other zones of the tenter oven  51  such as the preheating zone  511 , stretching zone  512  and cooling zone  514 . 
         [0136]    The air ejection nozzle ejects air controlled at a desired temperature toward a surface of the resin film carried in one direction, acting to promote heat exchange between the air and the resin film. That is, in the case where the temperature of the resin film is lower than the temperature of the air ejected from the air ejection nozzle toward the surface of the resin film, the resin film is heated, and in the case where the temperature of the resin film is higher than the temperature of the air ejected from the air ejection nozzle toward the surface of the resin film, the resin film is cooled. Further, in the case where the temperature of the resin film is equal to the temperature of the air ejected from the air ejection nozzle toward the surface of the resin film, the resin film is heat-retained. Moreover, in the case where the resin film is coated on the surface with a coating liquid immediately before the tenter apparatus  95 , the formed coating film is dried or cured by the heat exchange with the air ejected from the air ejection nozzle to the surface of the coating film. 
         [0137]    The number of the air ejection nozzles in the resin film carrying direction can also be one in each zone, but considering the efficiency of heat exchange between the air and the resin film, it is preferred that at least three air ejection nozzles are used. Further, the air ejection nozzle can also be installed on one surface side only of the resin film, but considering the efficiency of heat exchange between the air and the resin film, it is preferred that the air ejection nozzles are installed on both the surface sides of the resin film. 
         [0138]      FIG. 2  is a perspective view showing an example of the air ejection nozzle of this invention. In  FIG. 2 , the air ejection nozzle  1  comprises a nozzle housing  1   a . The nozzle housing  1   a  has air introducing ports  41   a  and  41   b  for introducing air having a predetermined temperature into the nozzle housing  1   a  at both the ends thereof in the longitudinal direction, and the inside space between the air introducing port  41   a  and the air introducing port  41   b  forms an air supply passage  41 . 
         [0139]    Further, the nozzle housing  1   a  is mounted with an air ejection plate  20  on the top surface opening of the housing. The air ejection plate  20  has many air ejection holes  2  open on one side in the outside surface of the air ejection plate  20  and open on the other side in the inside surface of the air ejection plate  20 , namely, open into the air supply passage  41 . Therefore, the outside surface of the air ejection plate  20  forms an air ejection face  40  having many openings  21  of the air ejection holes  2 . The air ejection nozzle  1  is used in such a manner that the air ejection face  40  thereof faces the surface of the resin film to be heat-treated, with a clearance formed between them. 
         [0140]      FIG. 1  is an enlarged plan view showing a portion of the air ejection face  40  of the air ejection nozzle  1  of the invention shown in  FIG. 2 . In  FIG. 1 , the air ejection nozzle  1  has many air ejection holes  2  with openings  21  in the face of the air ejection nozzle  1  facing the surface of the resin film, namely, in the air ejection face  40 . The form of the respective air ejection holes in the air ejection face  40 , namely, the form of the respective openings  21  is circular. The diameter of the respective air ejection holes  2  in the air ejection face  40 , namely, the diameter of the respective openings  21  is D (mm). 
         [0141]    The many air ejection holes  2 , namely, the many openings  21  are arranged in two rows consisting of the first row  2   a  and the second row  2   b  in the air ejection face  40 . The direction of the first row  2   a  and the second row  2   b  is the direction perpendicular to the resin film carrying direction FTD (the width direction of the resin film). The first row  2   a  is positioned on the upstream side in the resin film carrying direction FTD, and the second row  2   b  is positioned on the downstream side in the resin film carrying direction FTD. The air ejection holes  2  arranged in the first row  2   a  and the air ejection holes  2  arranged in the second row  2   b  are arranged zigzag in the plan view. 
         [0142]    In  FIG. 1 , the interval between a straight line  3   a  (a first air ejection holes-aligned straight line) passing through the centers of the air ejection holes  2  arranged in the first row  2   a  and a straight line  3   b  (a second air ejection holes-aligned straight line) passing through the centers of the air ejection holes  2  arranged in the second row  2   b  in the resin film carrying direction FTD is expressed as Px (mm). Further, each interval between the centers of the respectively adjacent air ejection holes  2  in the first row  2   a  and between the centers of the respectively adjacent air ejection holes  2  in the second row  2   b  is expressed as Py (mm). 
         [0143]    In the abovementioned zigzag arrangement, it is preferred that the center of each air ejection hole  2  of the first row  2   a  shifts from the center of the air ejection hole  2  of the second row  2   b  nearest to the air ejection hole of the first row by Py/2 in the width direction of the resin film. However, the interval Py/2 between each air ejection hole of the first row and the air ejection hole of the second row nearest to the air ejection hole of the first row can also be a value within a range of Py/2±10%. 
         [0144]      FIG. 3  is a plan view showing a state of the heat transfer rate distribution  33  on a surface of a resin film obtained by the numerical analysis explained for the examples described later. The heat transfer rate in the heat transfer rate distribution  33  is largest at the central position of each air ejection hole  2  of the air ejection nozzle  1  and becomes smaller at a position farther away from the central position of the air ejection hole  2 . The heat transfer efficiency of one air ejection nozzle  1  is the mean value of the heat transfer rates in the carrying direction FTD of the resin film  31  in a section Pn ranging from the center line  4   a  between the air ejection nozzle  1  and the air ejection nozzle  11   a  adjacent to the air ejection nozzle  1  on the upstream side in the resin film carrying direction to the center line  4   b  between the air ejection nozzle  1  and the air ejection nozzle  11   b  adjacent to the air ejection nozzle  1  on the downstream side in the resin film carrying direction. The center lines  4   a  and  4   b , the straight line  3   a  (the first air ejection holes-aligned straight line) passing through the centers of the air ejection holes  2  of the first row  2   a  and the straight line  3   b  (the second air ejection holes-aligned straight line) passing through the centers of the air ejection holes  2  of the second row  2   b  are parallel to each other. 
         [0145]    Straight lines  5   a ,  5   b  and  5   c  drawn in the resin film carrying direction FTD in  FIG. 3  are explained below. 
         [0146]    The straight line  5   a  is a line passing through the center of an air ejection hole  2  arranged in the first row  2   a  and the straight line  5   c  is a line passing through the center of an air ejection hole  2  arranged in the second row  2   b . The straight line  5   b  is a line passing through the center of the interval between the straight line  5   a  and the straight line  5   c.    
         [0147]    Next, the history of the heat transfer rates occurring on the surface of the carried and moved resin film at the positions corresponding to these lines is explained below. The heat transfer rate on the surface portion of the resin film passing the position corresponding to the straight line  5   a  is large when the surface portion of the film passes over the first row  2   a  but is small when it passes over the second row  2   b . The reason is that the straight line  5   a  passes the center of an air ejection hole  2  on the first row  2   a  but a position apart from the centers of air ejection holes  2  on the second row  2   b , therefore that when the surface portion of the resin film corresponding to the straight line  5   a  passes over the first row  2   a , it passes over the air ejection hole  2 , hence the heat transfer rate being large, and that when the surface portion of the resin film passes over the second row  2   b , it passes over a position apart from air ejection holes  2 , hence the heat transfer rate being small. 
         [0148]    The heat transfer rate on the surface portion of the resin film corresponding to the straight line  5   c  is small when the surface portion of the resin film passes over the first row  2   a , but is large when it passes over the second row  2   b . Likewise, the straight line  5   c  passes a position apart from air ejection holes  2  when it passes the first row  2   a , and therefore when the surface portion of the resin film corresponding to the straight line  5   c  passes over the first row  2   a , the heat transfer rate on the surface portion of the resin film becomes small, and when the surface portion of the resin film passes over the second row  2   b , the heat transfer rate on the surface portion of the resin film becomes large since the surface portion of the resin film passes over the center of an air ejection hole  2  of the second row  2   b.    
         [0149]    The heat transfer rate on the surface portion of the resin film corresponding to the straight line  5   b  becomes medium when the surface portion of the resin film passes over the first row  2   a  and when it passes over the second row  2   b . The reason is that when the straight line  5   b  passes the first row  2   a , it is farther from an air ejection hole  2  than the straight line  5   a  and closer to an air ejection hole  2  than the straight line  5   c , and further that when it passes the second row  2   b , it is closer to an air ejection hole  2  than the straight line  5   a  and is farther away from an air ejection hole than the straight line  5   c . The heat transfer efficiency of the air ejection nozzle  1  is the mean value of these heat transfer rates experienced. 
         [0150]    In  FIG. 3 , the magnitudes in terms of the heat transfer rates of the resin film  31  are expressed by shades on the surface of the resin film  31 .  FIG. 3  shows indicator HTC for expressing the magnitude in terms of heat transfer rate. As the indicator HTC, dark HTCL means a portion having a large heat transfer rate, and light HTCS means a portion having a small heat transfer rate. If the color shades in the indicator HTC are compared with the color shade pattern shown on the surface of the resin film  31 , the portions having high heat transfer rates and the portions having low heat transfer rates on the resin film  31  can be read. 
         [0151]    If the air ejection nozzle  1  in which the air ejection holes  2  are arranged zigzag in two rows in the direction perpendicular to the resin film carrying direction is used, the heat transfer efficiency in the resin film portion corresponding to the straight line  5   a  is almost equal to the heat transfer efficiency in the resin film portion corresponding to the straight line  5   c , needless to say. The air ejection holes arranged like this allow the difference between the heat transfer efficiency in the resin film portions corresponding to the straight lines  5   a  and  5   c , and the heat transfer efficiency in the resin film portion corresponding to the straight line  5   b  to be decreased. Compared with the case where the air ejection holes  2  are arranged in one row only in the resin film carrying direction, the uniformity of heat transfer efficiency in the width direction of the resin film can be improved. 
         [0152]    However, even if the air ejection holes  2  are arranged zigzag in two rows in the direction perpendicular to the resin film carrying direction, the uniformity of heat transfer efficiency is not satisfactorily enough. For further decreasing the difference between the heat transfer efficiency in the portions corresponding to the straight lines  5   a  and  5   c  and the heat transfer efficiency in the portion corresponding to the straight dine  5   b , it is important to select the dimensions of the portions explained below as factors affecting the heat transfer rate distribution  33  in good balance. 
         [0153]    It is necessary that the air ejection nozzle  1  of the invention satisfies the following formulae (1) and (2), where L (mm) is the distance between the air ejection holes  2  and the passing plane of the resin film  31 ; D (mm) is the diameter of the air ejection holes  2  in the air ejection face  40 ; Px (mm) is the interval between the straight line  3   a  (the first air ejection holes-aligned straight line) passing through the centers of the air ejection holes  2  of the first row  2   a  and the straight line  3   b  (the second air ejection holes-aligned straight line)passing through the centers of the air ejection holes  2  of the second row  2   b ; and Py (mm) is each interval between the centers of the respectively adjacent air ejection holes  2  in each row in the width direction of the resin film. 
         [0000]      6≦( L/D )/( Px/Py )≦9  formula (1) 
         [0000]      4≦ L/D≦ 8  formula (2) 
         [0154]    In the above, the passing plane FPf of the resin film  31  refers to the geometrical plane passing through the positions where the respective clips  73 A and  73 B existing in the tenter oven  51  hold the resin film  31 . 
         [0155]    Further, it is preferred that the cross sectional form of the air ejection holes  2  is closer to a geometric circle but is not required to be completely round. Therefore, the diameter D is defined as the diameter of the circle obtained by least square approximation of the air ejection holes  2 . It is preferred that the circularity tolerance of the air ejection holes  2  is within ±5% of diameter D. 
         [0156]    The formula (1) is explained below. If the value of Px/Py as the denominator of formula (1) is diminished, a state of arrangement of the air ejection holes  2  approaches to a state of arrangement in one row under at intervals of Py/2 in the width direction of the resin film  31 . Therefore, the heat transfer efficiency of the air ejection nozzle at the position corresponding to the straight line  5   b  declines. On the contrary, if the value of Px/Py is enlarged, the heat transfer efficiency of the air ejection nozzles at the position corresponding to the straight line  5   b  becomes larger than the heat transfer efficiency of the air ejection nozzle at the positions corresponding to the straight line  5   a  and the straight line  5   c . Therefore, among the values of Px/Py, there is a range where the difference between the heat transfer efficiency of the air ejection nozzle at the positions corresponding to the straight line  5   a  and the straight line  5   c  and the heat transfer efficiency of the air ejection nozzle at the position corresponding to the straight line  5   b  becomes small. 
         [0157]    The inventors found that the range where the difference between the heat transfer efficiency at the positions corresponding to the straight lines  5   a  and  5   c  and the heat transfer efficiency at the position corresponding to the straight line  5   b  becomes small depends on the value of L/D. That is, if the value of L/D is diminished, the region where the heat transfer rate is large is widened, and the heat transfer efficiency of the air ejection nozzle at the position corresponding to the straight line  5   b  becomes smaller than the heat transfer efficiency of the air ejection nozzle at the positions corresponding to the straight line  5   a  and the straight line  5   c . Therefore, it is preferred that the value of Px/Py is made smaller. On the contrary, if the value of L/D is enlarged, the region where the heat transfer rate is large is narrowed, and the heat transfer efficiency of the air ejection nozzle at the position corresponding to the straight line  5   b  becomes larger than the heat transfer efficiency of the air ejection nozzle at the positions corresponding to the straight line  5   a  and the straight line  5   c . Therefore, it is preferred that the value of Px/Py is made larger. The preferred relationship between the value of L/D and the value of Px/Py was discussed by the method shown in the examples, and as a result, it was found that in the case where the value of (L/D)/(Px/Py) was in a range from 6 to 9, the uniformity of heat transfer efficiency of the air ejection nozzle in the width direction of the resin film could be greatly improved. 
         [0158]    Further, in the examples, it was found preferred that the value of (L/D)/(Px/Py) was in a range from 6 to 9, but it was found that the uniformity of the heat transfer efficiency of the air ejection nozzle in the width direction of the resin film could be further improved when the value of (L/D)/(Px/Py) was in a range from 7 to 8. 
         [0159]    Also in the case where the air ejection holes are arranged in 4 rows or larger even-numbered rows in the resin film carrying direction, the air ejection nozzle satisfying the formula (1) can be designed, but in this case, since the dimension of the air ejection nozzle in the resin film carrying direction becomes large, the flow of air into the suction ports in the tenter oven is inhibited while the dimension of the tenter oven in the resin film carrying direction becomes large. Therefore, such an air ejection nozzle has problems in view of practicality. 
         [0160]    Next, the formula (2) is explained below. Based on the numerous studies concerning free jet and impact jet, it is well known that the structure of a flow field formed by a jet can be expressed by L/D. According to these studies, when the value of L/D is in a range from 6 to 8, a potential region where the air velocity at the center of a jet maintains an initial air velocity exists, but if the value of L/D is larger than 10, the turbulence of the jet perfectly develops. If the turbulence of a jet develops, velocity variation becomes large to destabilize the jet, and a pressure difference and pressure variation may exist around the jet. In this case, the flow field is likely to be disturbed. The potential core region is strong in the capability to flow rectilinearly and is unlikely to be disturbed by pressure difference or pressure variation. Therefore, it is preferred that the value of L/D is 8 or less, and more preferred is 6 or less. 
         [0161]    Further, it is known that a jet more apart from its air ejection hole entrains the surrounding air more, to spread the mixing region in the radial direction of the air ejection hole. If the value of L/D is too small, the spread of the mixing region is insufficient, and the jet colliding with the surface of the resin film is like a spot, not allowing the effect explained for the formula (1) to be obtained. Therefore, it is preferred that the value of L/D is 4 or more. As a result of discussion performed by using the method shown in the examples, it was confirmed that an L/D value of 5 or more is more preferred. Therefore, it is preferred that the value of L/D is 4 to 8. A range from 5 to 8 is more preferred, and a range from 5 to 6 is further more preferred. 
         [0162]    Further, in the air ejection nozzle of the invention, if B=2π(D/2) 2 /Py (where π is the ratio of the circumference of a circle to its diameter), then it is preferred that the following formula (3) is satisfied. 
         [0000]      12 ≦L/B≦ 30  formula (3) 
         [0163]    The formula (3) is explained below. B is a hole clearance per unit width of the air ejection nozzle. The hole clearance per unit width refers to a clearance of a rectangular air ejection hole (slit) in the case where the air ejection holes  2  circular in cross sectional form are converted into the rectangular air ejection hole (slit) continuous in the width direction of the resin film and having an opening area equal to that of the circular air ejection holes  2 . If the value of B is too small for the value of L, the heat transfer efficiency may decline as the case may be. The air ejection velocity (air velocity) of the air ejection nozzle used in a tenter oven depends on the thickness and carrying speed of the resin film, but it is preferred that the air ejection velocity is set in a range from 5 to 35 m/s. 
         [0164]    The air velocity can be set in a wide range. At an air ejection velocity of 20 m/s, it is preferred that the heat transfer efficiency of the air ejection nozzle is 55 W/(m 2 K) or more. For this purpose, it is preferred that the value of L/B is 30 or less, and 24 or less is more preferred. Further, if the value of B is too large for the value of L, the amount of circulated air increases to require a heat exchanger and a fan respectively larger in capacity, thus raising the equipment cost and the power cost. Therefore, it is preferred that the value of L/B is 12 or more, and 15 or more is more preferred. 
         [0165]    The value of L is not especially limited, but it is preferred that the value of L is in the range of 140 mm to 270 mm. If the value of L is less than 140 mm, it may be difficult to secure the space in which the clips used for carrying the resin film pass. If the value of L is more than 270 mm, a heat exchanger and a fan respectively large in capacity are required for obtaining the necessary heat transfer efficiency, to raise the equipment cost and the power cost. 
         [0166]    The value of D is not especially limited either. However, in view of the abovementioned preferred ranges of L/D and L, it is preferred that the value of D is in the range of L/8 to L/5, and in the range of L/6 to L/5 is more preferred. 
         [0167]    The value of Px is not especially limited, but it is preferred that the value of Px is in the range of 50 mm to 180 mm. In the range of 70 mm to 150 mm is more preferred. If the value of Px is too small, being less than 50 mm, the jets of the air ejection holes adjacent to each other interfere with each other and may be bent or shaken. If the value of Px is too large, being more than 180 mm, the dimension of the air ejection nozzle in the resin film carrying direction becomes large. Therefore, the flow into the suction ports is inhibited, and the dimension of the tenter oven in the resin film carrying direction may become large. It is preferred that the value of Px is in the range of 50 mm to 180 mm. 
         [0168]    The value of Py is not especially limited, but it is preferred that the value of Py is in the range of 50 mm to 200 mm. A more preferred range is 70 mm to 180 mm. If the Py value is too small, being less than 50 mm, the jets of the air ejection holes adjacent to each other may interfere with each other and may be bent or shaken. If the Py value is too large, being more than 200 mm, the jets colliding with the surface of the resin film are like spots, not allowing the effect explained for the formula (1) to be obtained as the case may be. Therefore, it is preferred that the Py value is in the range of 50 mm to 200 mm. 
         [0169]    The resin film to be heat-treated by the air ejection nozzle or the tenter oven of the invention is not especially limited. The resin film can be, for example, a polyester film, polypropylene film, polyamide film, polylactic acid film, polyolefin film or polyphenylene sulfide film. 
         [0170]    The tenter oven of the invention in which the air ejection nozzle of the invention is installed at least in any one of the zones of a preheating zone, stretching zone, heat setting zone and cooling zone preferably allows the production of any of the abovementioned various films uniform in heat treatment effect, especially uniform in the heat treatment effect in the width direction. 
         [0171]    In the tenter oven of the invention, it is preferred that the air ejection nozzle of the invention is installed at least in the preheating zone. Further, it is more preferred that the air ejection nozzle of the invention is installed not only in the preheating zone but also in any one zone of the stretching zone, heat setting zone and cooling zone. It is further more preferred that the air ejection nozzle of the invention is installed in all the zones of the preheating zone, stretching zone, heat setting zone and cooling zone. 
         [0172]    The air ejection nozzle and tenter oven of the invention are explained below on the basis of examples. 
         [0173]    The example of the heat transfer rate distribution  33  on the surface of a resin film  31  shown in  FIG. 3  was obtained by three-dimensional computational fluid analysis.  FIG. 8  is a sectional view of the analysis model of a tenter oven  51  used in the examples of the invention, showing the plane perpendicular to the surface of a resin film  31  including the carrying direction FTD of the resin film  31 . This analysis model drawing shows the upper half of a vertical structure symmetric with respect to the plane of the resin film  31 . 
         [0174]    In  FIG. 8 , with regard to the size of the tenter oven  51 , the length of the tenter oven  51  in the carrying direction FTD of the resin film  31  was 2 m, and the length of the tenter oven  51  in the width direction of the resin film  31  was 2 m, and the height of the tenter oven  51  from the resin film  31  to the upper inner wall face of the tenter oven  51  was (L/1,000+1) m, where L is the distance between the air ejection face and the passing plane of the resin film defined before. 
         [0175]    The outside spaces  61  of the tenter oven  51  were added in order that the end boundaries  62  of the analysis space do not affect the flow field in the tenter oven  51 , and do not affect the constitution of the tenter oven  51 . The end boundaries  62  of the analysis space are pressure boundaries, and as the boundary condition, atmospheric pressure (0.1 MPa) was set. With regard to the size of the outside spaces  61 , the length of the outside spaces  61  in the carrying direction FTD of the resin film  31  was 1 m, and the length of the outside spaces  61  in the width direction of the resin film  31  was 2 m equal to the length (width) 2 m (not shown in the drawing) of the tenter oven  51  in the direction perpendicular to the carrying direction FTD of the resin film  31 , and the height of the outside spaces  61  was (L/1,000+1) m equal to the height of the tenter oven  51 . 
         [0176]    The resin film  31  was modeled as a wall boundary moving at a speed of 1 m/s. The length of the resin film  31  in the width direction was 1 m, and the center of the resin film  31  in the width direction was positioned at the center of the tenter oven  51  in the width direction. That is, the center of the tenter oven  51  in the width direction of the resin film  31  is made to agree with the center of the resin film  31  in the width direction. Further, since the resin film  31  was carried continuously in the carrying direction FTD, the resin film  31  was positioned to be continuous from one end to the other end of the analysis model. 
         [0177]    The tenter oven  51  was constituted such that five air ejection nozzles  1  were disposed on the side above the resin film  31 . 
         [0178]    With regard to the size of the air ejection nozzles  1 , the length of each air ejection nozzle  1  in the carrying direction of the resin film  31  was 200 mm, and the length of each air ejection nozzle  1  in the width direction of the resin film was 1,400 mm, and the height of each air ejection nozzle  1  was 600 mm, and the center of each air ejection nozzle  1  in the direction perpendicular to the carrying direction FTD of the resin film  31  was positioned at the center of the tenter oven  51  in the width direction. That is, the center of the tenter oven  51  in the width direction of the resin film  31  is made to agree with the center of each air ejection nozzle  1  in the width direction of the resin film  31 . 
         [0179]    Further, among the five air ejection nozzles  1 , the air ejection nozzle  1  positioned at the center (the third air ejection nozzle  1  on the upstream side in the carrying direction of the resin film  31 ) was positioned at the center of the tenter oven  51  in the carrying direction. That is, the center of the air ejection nozzle  1  positioned at the center in the carrying direction FTD of the resin film  31  is made to agree with the center of the tenter oven  51  in the carrying direction FTD of the resin film  31 . Further, each interval Pn between the center lines between the air ejection nozzles  1  adjacent to each other in the carrying direction of the resin film  31  was 300 mm. Therefore, every interval between the respectively adjacent air ejection nozzles  1  is 100 mm. 
         [0180]    In the faces of the air ejection nozzles  1  facing the resin film  31  (air ejection faces  40 A), many circular air ejection holes  2  having diameter D (mm) were provided. The distance between the passing plane FPf of the resin film  31  and the air ejection faces  40 A was L (mm). The air ejection holes  2  were modeled as an inflow boundary, and as the boundary condition, an air flow velocity of 20 m/s was set. 
         [0181]    The air ejection holes  2  were arranged, as shown in  FIG. 1 , in two rows of first row  2   a  and second row  2   b  in the direction perpendicular to the carrying direction FTD of the resin film  31 , and the air ejection holes  2  of the first row  2   a  and the air ejection holes  2  of the second row  2   b  were arranged zigzag in the plan view. The interval between the straight line  3   a  (the first air ejection holes-aligned straight line) passing through the centers of the air ejection holes  2  arranged in the first row  2   a  extending in the width direction of the resin film  31  and the straight line  3   b  (the second air ejection holes-aligned straight line) passing through the centers of the air ejection holes  2  arranged in the second row  2   b  extending in the width direction of the resin film  31  was expressed as Px (mm), and each interval between the centers of the air ejection holes  2  adjacent to each other in each row in the width direction of the resin film  31  was expressed as Py (mm). 
         [0182]    The suction port  54 A was modeled as an outflow boundary, and as the boundary condition, an outflow amount equal to the inflow amount from all the air ejection holes  2  was set. With regard to the size of the suction port  54 A, the length of the suction port  54 A in the carrying direction FTD of the resin film  31  was 1,400 mm, and the length of the suction port  54 A in the width direction of the resin film  31  was 1,400 mm, and the suction port  54 A was disposed above the air ejection nozzles  1 . The distance between the suction port  54 A and the faces (top faces) of the air ejection nozzles  1  opposite to the air ejection faces  40 A was 100 mm. The height of the suction duct  54  provided with the suction port  54 A was 200 mm, and the face as a whole of the suction duct  54  facing the air ejection nozzles  1  was formed as the suction port  54 A. Further, the suction port  54 A was disposed at the center in the width direction of the tenter oven  51  and the center in the carrying direction FTD of the resin film  31 . That is, the center of the suction port  54 A in the width direction of the resin film  31  is made to agree with the center of the tenter oven  51  in the width direction of the resin film  31 , and the center of the suction port  54 A in the carrying direction FTD of the resin film  31  is made to agree with the center of the tenter oven  51  in the carrying direction FTD of the resin film  31 . 
         [0183]    With regard to the physical properties of the fluid, dry air of atmospheric pressure at a temperature of 100° C. was assumed to have a density of 0.93 kg/m 3 , a viscosity of 2.2×10 −5  Pa&#39;s, a specific heat of 1,012 J/(kg·K) and a heat conductivity of 0.031 W/(m·K). 
         [0184]    For analysis, commercially available general purpose hot fluid analysis software, “STAR-CD (produced by CD-adapco Japan Co., Ltd.) was used to perform steady calculation. For handling turbulent flow, a k-ε turbulent flow model was used, and for handling a turbulent flow boundary layer near a wall, a wall law was used. 
         [0185]    The abovementioned software is intended to analyze the Navier-Stokes Equation as a fluid motion equation by a finite volume method. Of course, any other hot fluid analysis software can also be used if similar analysis can be performed. 
         [0186]    The heat transfer efficiency refers to the mean value of the heat transfer rates which the resin film  31  receives when it passes the air ejection nozzles  1 . That is, the heat transfer efficiency of one air ejection nozzle  1  is the mean value in the carrying direction FTD of the resin film  31 , of the heat transfer rates of the surface of the resin film  31  in the section Pn between the center line  4   a  with the adjacent air ejection nozzle  11   a  and the center line  4   b  with the adjacent air ejection nozzle  11   b . Since the five air ejection nozzles installed side by side in the carrying direction FTD of the resin film  31  were identical in the arrangement of the air ejection holes  2 , the heat transfer efficiency was calculated with the central one air ejection nozzle  1  as a representative of the respective air ejection nozzles. 
       Example 1 
       [0187]    With L=150 mm, D=25 mm, Px=100 mm and Py=122 mm, the abovementioned analysis was performed.  FIG. 9  is a chart showing the state of the heat transfer efficiency distribution of the air ejection nozzle  1  in the width direction of the film  31 . In the chart, the position P (in mm) in the width direction of the resin film  31  is chosen as the abscissa, and the heat transfer efficiency Q (in W/m 2 K) of the air ejection nozzle  1 , as the ordinate. This chart was used to evaluate the following two items. 
         [0188]    (1) Average heat transfer efficiency Qa of air ejection nozzle  1 : 
         [0189]    The mean value of the heat transfer efficiency values of the air ejection nozzle  1  distributed in the width direction of the resin film  31  is defined as the average heat transfer efficiency Qa (in W/m 2 K) of the air ejection nozzle  1 . It is preferred that the average heat transfer efficiency Qa is larger. In the invention, like the indicator of a general tenter oven, it was evaluated that the object of the invention was achieved and that the air ejection nozzle was acceptable in the case where the value of the average heat transfer efficiency Qa was 55 W/m 2 K or more. 
         [0190]    (2) Heat transfer efficiency irregularity Rq of air ejection nozzle  1  in the width direction of resin film  31 : 
         [0191]    The value obtained by dividing the difference between the maximum value Qmax and the minimum value Qmin of the heat transfer efficiency Q of the air injection nozzle  1  in the width direction of the resin film  31  by the average heat transfer efficiency Qa and multiplying the quotient by 100 was defined as the heat transfer efficiency irregularity Rq (in %) of the air ejection nozzle  1  in the width direction of the resin film  31 . In  FIG. 9 , the maximum value of heat transfer efficiency Q is indicated by dotted line Qmax, the minimum value of heat transfer efficiency Q, by dotted line Qmin, and the mean value of heat transfer efficiency Q (average heat transfer efficiency Qa), by solid line Qa. It is preferred that the heat transfer efficiency irregularity Rq is smaller. In the invention, since the heat transfer efficiency irregularity Rq of a general slit nozzle is 5 to 15%, it was evaluated that the object of the invention was achieved and that the air ejection nozzle was acceptable in the case where the value of the heat transfer efficiency irregularity Rq was 15% or less. 
         [0192]    The evaluation results of Example 1 were Qa=72.0 W/m 2 K and Rq=10.9%, showing that both the average heat transfer efficiency Qa and the heat transfer efficiency irregularity Rq were acceptable. 
       Examples 2 to 15 and Comparative Examples 1 to 13 
       [0193]    L, D, Px and Py were changed with the value of L/D kept in a range from 5 to 8, to perform the abovementioned analysis as described for Example 1. The values of L, D, Px and Py used for analysis and the values of average heat transfer efficiency Qa and the values of heat transfer efficiency irregularity Rq evaluated are shown in Table 1. 
         [0194]    In Examples 2 to 15 in which the value of (L/D)/(Px/Py) was kept in a range from 6 to  9 , the values of average heat transfer efficiency Qa were 55 W/m 2 K or more and the values of heat transfer efficiency irregularity Rq were 15% or less, showing that the results of the respective examples were acceptable. 
         [0195]    In Comparative Examples 1 to 13 in which the value of (L/D)/(Px/Py) was smaller than 6 or larger than 9, the values of average heat transfer efficiency Qa were 55 W/m 2 K or more, but the values of heat transfer efficiency irregularity Rq were larger than 15%, showing that the results of the respective comparative examples were not acceptable, namely, were rejected. 
       Comparative Examples 14 to 17 
       [0196]    With L=270 mm, D=30 mm and Py=88 mm, the value of Px was changed in a range from 80 to 140 mm, to perform the abovementioned analysis as described for Example 1. The values of L, D, Px and Py used for analysis, and the values of average heat transfer efficiency Qa and the values of heat transfer efficiency irregularity Rq evaluated are shown in Table 1. 
         [0197]    In Comparative Examples 14 to 17 in which the value of L/D was 9, the values of average heat transfer efficiency Qa were 55 W/m 2 K or more, but the values of heat transfer efficiency irregularity Rq were larger than 15%, showing that the respective comparative examples were not acceptable, namely, were rejected. 
         [0000]    
       
         
               
               
               
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
               
               
             
           
               
                   
                 TABLE 1 
               
               
                   
                   
               
               
                   
                 L 
                 D 
                 Px 
                 Py 
                 B 
                   
                   
                   
                 (L/D)/ 
                 Qa 
                 Rq 
               
               
                   
                 [mm] 
                 [mm] 
                 [mm] 
                 [mm] 
                 [mm] 
                 L/B 
                 L/D 
                 Px/Py 
                 (Px/Py) 
                 [W/m 2 K] 
                 [%] 
               
               
                   
                   
               
             
             
               
                   
               
             
          
           
               
                 Comparative 
                 150 
                 25 
                 80 
                 122 
                 8.0 
                 18.6 
                 6.0 
                 0.7 
                 9.2 
                 69.6 
                 18.3 
               
               
                 example 1 
               
               
                 Example 1 
                 150 
                 25 
                 100 
                 122 
                 8.0 
                 18.6 
                 6.0 
                 0.8 
                 7.3 
                 72.0 
                 10.9 
               
               
                 Example 2 
                 150 
                 25 
                 120 
                 122 
                 8.0 
                 18.6 
                 6.0 
                 1.0 
                 6.1 
                 71.3 
                 13.3 
               
               
                 Comparative 
                 150 
                 25 
                 140 
                 122 
                 8.0 
                 18.6 
                 6.0 
                 1.1 
                 5.2 
                 69.0 
                 23.1 
               
               
                 example 2 
               
               
                 Comparative 
                 150 
                 30 
                 80 
                 176 
                 8.0 
                 18.7 
                 5.0 
                 0.5 
                 11.0 
                 69.8 
                 22.2 
               
               
                 example 3 
               
               
                 Example 3 
                 150 
                 30 
                 100 
                 176 
                 8.0 
                 18.7 
                 5.0 
                 0.6 
                 8.8 
                 72.9 
                 9.5 
               
               
                 Example 4 
                 150 
                 30 
                 120 
                 176 
                 8.0 
                 18.7 
                 5.0 
                 0.7 
                 7.3 
                 74.3 
                 7.1 
               
               
                 Example 5 
                 150 
                 30 
                 140 
                 176 
                 8.0 
                 18.7 
                 5.0 
                 0.8 
                 6.3 
                 73.5 
                 10.0 
               
               
                 Comparative 
                 180 
                 25 
                 80 
                 108 
                 9.1 
                 19.8 
                 7.2 
                 0.7 
                 9.7 
                 66.7 
                 20.7 
               
               
                 example 4 
               
               
                 Example 6 
                 180 
                 25 
                 100 
                 108 
                 9.1 
                 19.8 
                 7.2 
                 0.9 
                 7.8 
                 69.6 
                 12.4 
               
               
                 Example 7 
                 180 
                 25 
                 120 
                 108 
                 9.1 
                 19.8 
                 7.2 
                 1.1 
                 6.5 
                 69.1 
                 14.1 
               
               
                 Comparative 
                 180 
                 25 
                 140 
                 108 
                 9.1 
                 19.8 
                 7.2 
                 1.3 
                 5.6 
                 66.5 
                 17.6 
               
               
                 example 5 
               
               
                 Comparative 
                 180 
                 30 
                 80 
                 156 
                 9.1 
                 19.9 
                 6.0 
                 0.5 
                 11.7 
                 65.9 
                 23.6 
               
               
                 example 6 
               
               
                 Comparative 
                 180 
                 30 
                 100 
                 156 
                 9.1 
                 19.9 
                 6.0 
                 0.6 
                 9.4 
                 69.8 
                 16.8 
               
               
                 example 7 
               
               
                 Example 8 
                 180 
                 30 
                 120 
                 156 
                 9.1 
                 19.9 
                 6.0 
                 0.8 
                 7.8 
                 71.4 
                 9.4 
               
               
                 Example 9 
                 180 
                 30 
                 140 
                 156 
                 9.1 
                 19.9 
                 6.0 
                 0.9 
                 6.7 
                 71.0 
                 10.0 
               
               
                 Comparative 
                 240 
                 30 
                 80 
                 100 
                 14.1 
                 17.0 
                 8.0 
                 0.8 
                 10.0 
                 65.1 
                 24.8 
               
               
                 example 8 
               
               
                 Example 10 
                 240 
                 30 
                 100 
                 100 
                 14.1 
                 17.0 
                 8.0 
                 1.0 
                 8.0 
                 69.2 
                 11.3 
               
               
                 Example 11 
                 240 
                 30 
                 120 
                 100 
                 14.1 
                 17.0 
                 8.0 
                 1.2 
                 6.7 
                 69.4 
                 11.9 
               
               
                 Comparative 
                 240 
                 30 
                 140 
                 100 
                 14.1 
                 17.0 
                 8.0 
                 1.4 
                 5.7 
                 67.6 
                 21.0 
               
               
                 example 9 
               
               
                 Comparative 
                 240 
                 35 
                 80 
                 136 
                 14.1 
                 17.0 
                 6.9 
                 0.6 
                 11.7 
                 66.9 
                 26.3 
               
               
                 example 10 
               
               
                 Comparative 
                 240 
                 35 
                 100 
                 136 
                 14.1 
                 17.0 
                 6.9 
                 0.7 
                 9.3 
                 67.5 
                 17.7 
               
               
                 example 11 
               
               
                 Example 12 
                 240 
                 35 
                 120 
                 136 
                 14.1 
                 17.0 
                 6.9 
                 0.9 
                 7.8 
                 71.9 
                 7.4 
               
               
                 Example 13 
                 240 
                 35 
                 140 
                 136 
                 14.1 
                 17.0 
                 6.9 
                 1.0 
                 6.7 
                 71.8 
                 8.2 
               
               
                 Comparative 
                 270 
                 30 
                 80 
                 88 
                 16.1 
                 16.8 
                 9.0 
                 0.9 
                 9.9 
                 61.5 
                 19.5 
               
               
                 example 14 
               
               
                 Comparative 
                 270 
                 30 
                 100 
                 88 
                 16.1 
                 16.8 
                 9.0 
                 1.1 
                 7.9 
                 59.7 
                 21.1 
               
               
                 example 15 
               
               
                 Comparative 
                 270 
                 30 
                 120 
                 88 
                 16.1 
                 16.8 
                 9.0 
                 1.4 
                 6.6 
                 61.8 
                 19.1 
               
               
                 example 16 
               
               
                 Comparative 
                 270 
                 30 
                 140 
                 88 
                 16.1 
                 16.8 
                 9.0 
                 1.6 
                 5.7 
                 59.7 
                 22.1 
               
               
                 example 17 
               
               
                 Comparative 
                 270 
                 35 
                 80 
                 120 
                 16.0 
                 16.8 
                 7.7 
                 0.7 
                 11.6 
                 65.8 
                 25.2 
               
               
                 example 12 
               
               
                 Comparative 
                 270 
                 35 
                 100 
                 120 
                 16.0 
                 16.8 
                 7.7 
                 0.8 
                 9.3 
                 66.9 
                 15.6 
               
               
                 example 13 
               
               
                 Example 14 
                 270 
                 35 
                 120 
                 120 
                 16.0 
                 16.8 
                 7.7 
                 1.0 
                 7.7 
                 70.2 
                 11.7 
               
               
                 Example 15 
                 270 
                 35 
                 140 
                 120 
                 16.0 
                 16.8 
                 7.7 
                 1.2 
                 6.6 
                 69.9 
                 12.5 
               
               
                   
               
             
          
         
       
     
         [0198]      FIG. 10  is a graph in which the values of (L/D)/(Px/Py) used and the values of heat transfer efficiency irregularity Rq obtained in Examples 1 to 15 and Comparative Examples 1 to 17 are plotted. In the graph of  FIG. 10 , the value of (L/D)/(Px/Py) is chosen as the abscissa, and the value of heat transfer efficiency irregularity Rq (%), as the ordinate. Circles indicate the values of Examples 1 to 15, triangles, the values of Comparative Examples 1 to 13, and crosses, the values of Comparative Examples 14 to 17. 
         [0199]    From the graph of  FIG. 10 , it can be seen that as the value of (L/D)/(Px/Py) becomes smaller than 6, the value of heat transfer efficiency irregularity Rq becomes suddenly large. Further, it can be seen that as the value of (L/D)/(Px/Py) becomes larger than 9, the value of heat transfer efficiency irregularity Rq becomes suddenly large. Furthermore in Comparative Examples 14 to 17 where the value of L/D is 9, it can be seen that even though the value of (L/D)/(Px/Py) is kept in a range from 6 to 9, the value of heat transfer efficiency irregularity Rq does not become small. 
         [0200]      FIG. 11  is a graph in which the values of Px/Py and the values of L/D in Examples 1 to 15 and Comparative Examples 1 to 17 are plotted. In the graph of  FIG. 11 , the value of Px/Py is chosen as the abscissa, and the value of L/D, as the ordinate. Circles indicate the values of Examples 1 to 15, triangles, the values of Comparative Examples 1 to 13, and crosses, the values of Comparative Examples 14 to 17. Further, dotted line L 6  indicates the line of (L/D)/(Px/Py)=6, dotted line L 9 , line of (L/D)/(Px/Py)=9, and dotted line L 8 , line of L/D=8. 
         [0201]    From the graph of  FIG. 11 , it can be seen that in Examples 1 to 15 in which the values of heat transfer efficiency irregularity Rq are small, the values of (L/D)/(Px/Py) are kept in a range from 6 to 9 while the values of L/D are kept in a range from 5 to 8. 
       Example 16 
       [0202]    An air ejection nozzle  1  having the same dimensions as those of Example 1 was installed in the preheating zone of the tenter apparatus  95  shown in  FIG. 4 , and the production process shown in  FIG. 7  was used to produce a biaxially oriented polyethylene terephthalate resin film  31   d.    
       Production Conditions: 
       [0203]    Chips of polyethylene terephthalate dried in vacuum at a temperature of 180° C. were supplied into the extruder  91 , and the resin melted at a temperature of 280° C. was extruded, being discharged as a sheet from the die  92 , to obtain a resin sheet  31   a . The resin sheet  31   a  was wound around the casting drum  93  with a surface temperature of 20° C., to be cooled and solidified, for obtaining a cast film  31   b . In succession, the cast film  31   b  was introduced into the longitudinal stretching machine  94 , heated by rolls heated to a temperature of 80° C., further stretched to 3.2 times in the carrying direction while being heated by an infrared heater, and cooled by a cooling roll with a temperature of 40° C., to obtain a monoaxially oriented film  31   c . In succession, the monoaxially oriented film  31   c  was introduced into the tenter apparatus  95 , heated to a temperature of 100° C. in the preheating zone, stretched to 3.5 times in the width direction while being heated to a temperature of 110° C. in the stretching zone, heated to a temperature of 220° C. in the heat setting zone, and cooled to a temperature of 90° C. in the cooling zone while being treated for relaxation by 5% in the width direction, to obtain a biaxially oriented film  31   d . Then, both the edges of the biaxially stretched film  31   d  were off, and the film was wound around the winding roll  96 , to obtain a film  31   e  having a width of 3,400 mm as a product. 
         [0204]    Thickness Measuring Method: 
         [0205]    From the film  31   e  wound as a product around the winding roll  96 , a sample having a size of 3,400 nm in the width direction and 30 mm in the carrying direction was obtained by cutting, and the thickness values of the sample film distributed in the width direction were measured using Film Thickness Tester “KG601A” and Electronic Micrometer “K306C” respectively produced by Anritsu K.K. The thickness irregularity Rt (in %) in the width direction was obtained from relational expression Rt=(Tx−Tn)/Ta×100 [%], wherein Ta is the mean thickness value (in μm); Tn, the minimum thickness value (in μm); and Tx, the maximum thickness value (in μm). 
         [0206]    The thickness values distributed in the width direction of the film  31   e  as a product of Example 16 are shown in the graph of  FIG. 12 . In the graph of  FIG. 12 , the position (mm) in the width direction is chosen as the abscissa, and the thickness value, as the ordinate. Solid line Ta indicates the mean thickness value, dotted line Tx, the maximum thickness value, and dotted line Tn, the minimum thickness value. The results of Example 16 were Ta=74.9 μm, Tn=74.3 μm, Tx=75.5 μm and Rt=1.6%. 
       Comparative Example 18 
       [0207]    An air ejection nozzle  1  having the same dimensions as those of Comparative Example 1 was installed in the preheating zone of the tenter apparatus  95  shown in  FIG. 4 , and a biaxially stretched polyethylene terephthalate resin film  31   d  (film  31   e  as a product) was produced under the same conditions as described for Example 16. The thickness values were measured according to the same method as that of Example 16. 
         [0208]    The thickness values distributed in the width direction of the film  31   e  as the product of Comparative Example 18 are shown in the graph of  FIG. 13 . In the graph of  FIG. 13 , the position (mm) in the width direction is chosen as the abscissa, and the thickness value, as the ordinate. Solid line Ta indicates the mean thickness value, dotted line Tx, the maximum thickness value, and dotted line Tn, the minimum thickness value. The results of Comparative Example 18 were Ta=75.1 μm. Tn=74.1 μm, Tx=76.0 μm and Rt=2.5%. 
         [0209]    If the heat transfer efficiency irregularity Rq of the air ejection nozzle  1  is large, the temperature irregularity of the resin film  31  after passing through the preheating zone becomes large, to cause stretching irregularity in the stretching zone, thus enlarging the thickness irregularity Rt in the width direction. Since the value of heat transfer efficiency irregularity Rq in Example 16 is very smaller than the value of the heat transfer efficiency irregularity Rq in Comparative Example 18, the air ejection nozzle  1  of Example 16 is good in the uniformity of heat transfer efficiency in the width direction of the resin film. 
       INDUSTRIAL APPLICABILITY 
       [0210]    Since the air ejection nozzle of the invention has specifically formed many air ejection holes arranged in a specific relationship, the resin film heat-treated using the air ejection nozzle is excellently uniform in the heat transfer efficiency in the width direction of the resin film. Therefore, the tenter oven of the invention using the air ejection nozzle of the invention allows the production of a resin film having homogeneous heat-treated properties in the width direction. The air ejection nozzle of the invention can be used not only for a tenter oven but also as a drying device used in a printing machine or coating machine, etc.