Abstract:
Bottle ( 101 ) for a cosmetic product containing a volatile solvent, especially for mascara, comprising an opening ( 106 ) and a rigid side wall ( 103 ) produced as a plastic moulding having an inside lateral surface in contact with said cosmetic product and an outside lateral surface ( 104 ) to which a label ( 100 ) is affixed, said label having barrier properties with regard to the volatile solvent. This label advantageously covers the entire outside lateral surface.

Description:
[0001]    The present application claims the priority of the French application No. 0707537 filed on Oct. 26 2007, the content of which is incorporated by reference into the present application. 
       TECHNICAL FIELD 
       [0002]    The invention relates to a bottle for a cosmetic product containing at least one volatile solvent and more particularly a bottle for mascara. The invention also relates to a distributor/applicator of mascara. 
       STATE OF THE ART 
       [0003]    Such a bottle commonly comprises an aperture and a rigid lateral wall molded in a plastic material or polymer comprising an inside lateral surface in contact with the cosmetic product and an outside lateral surface on which a label is affixed. 
         [0004]    Plastic material is preferred to metal or to glass for making mascara bottles because it is lightweight, does not break, has relatively low cost and is easy to use for industrial manufacturing. Also, the mascara bottles are today molded by injection-blowing or by extrusion-blowing so as to obtain bottles including both a lateral wall, an integrated neck and bottom. With blowing it is possible to obtain a solid bottom and a neck including an aperture with a diameter of less than the diameter of the lateral wall in order to receive a wiper for a mascara applicator. The advantage of such moldings by blowing as compared for example with injection-molding is that it is not necessary to attach a separate end, i.e. a bottom and/or a neck, onto the lateral wall, in order to form the bottle. 
         [0005]    With increasing sophistication of mascara formulas, and in particular the increasing use of so-called “waterproof” mascara based on volatile solvents for example of the type of alcohols or hydrocarbon compounds such as isododecane, there is an increasing need for bottles for mascara having good barrier properties against volatile solvents. In order to limit losses of volatile solvent by migration or evaporation through the walls of the bottle and thereby avoid drying of the mascara, it is presently necessary to wisely select the constitutive plastic material of the bottle depending on its barrier properties with respect to the volatile solvent and on its compatibility with the formulation of the mascara. 
         [0006]    The use of certain grades of polyamides or polyester is thereby known for making mascara bottles because of their barrier properties with respect to non-polar volatile solvents. Such plastic materials are however costly. 
         [0007]    Another known solution consists of co-extruding different layers of plastic material, for example three layers, with an intermediate layer including good barrier properties with respect to the volatile solvent, for example in EVOH, for making the mascara bottle. In addition to inducing a high cost, this multilayer co-extrusion makes the molding method complicated and not very reliable, resulting in general lower bottle quality, notably in terms of tolerance on the dimensioning of the neck or of aesthetics at the joint lines. 
         [0008]    An object of the present invention is therefore to solve the drawbacks mentioned above and to propose another type of bottle having improved barrier properties with respect to the volatile solvent contained in the cosmetic product, while limiting the cost of the bottle thereof. 
         [0009]    Another object of the present invention is to propose a bottle in which the step for checking the compatibility of the bottle with the cosmetic product and for checking the barrier properties may be reduced. 
         [0010]    Another object of the present invention is to propose a bottle having both good barrier properties with respect to the volatile solvents and to water. 
       OBJECT OF THE INVENTION 
       [0011]    For this purpose, the object of the invention is a bottle for cosmetic product containing at least one volatile solvent, notably for mascara, comprising an aperture and a rigid lateral wall molded in plastic material comprising an inside lateral surface in contact with said cosmetic product and an outside lateral surface on which a label is affixed, in which the label has barrier properties with respect to the volatile solvent. 
         [0012]    The label is then used, in addition to its function of information medium or decoration, for ensuring to the lateral wall of the bottle, a good barrier property with respect to the volatile solvent. According to a preferred embodiment of the invention, this label covers the whole of said outside lateral surface so as to maximize the surface area of the lateral wall having a barrier property with respect to the volatile solvent. As mascara bottles generally have a diameter close to 17 mm for a length close to 80 mm, the lateral wall accounts for about 90% of the exchange surface area of the bottle, so that improving the barrier properties of the lateral wall amounts to strongly improving the barrier properties of the bottle on its whole. 
         [0013]    Advantageously, it is no longer necessary to use a plastic material or a multilayer plastic structure having barrier properties with respect to the volatile solvent contained in the cosmetic product in order to form this lateral wall, the barrier with respect to the volatile solvent being ensured by the label, so that it is possible to limit the cost of material for forming the bottle. Therefore it is possible to use any, preferably low cost, plastic material, in order to form the lateral wall of a bottle intended to receive a cosmetic product containing a volatile solvent, regardless of the barrier properties with respect to the volatile solvent of this plastic material, from the moment that this plastic material is compatible with the cosmetic product. 
         [0014]    Therefore it is possible to use high density polyethylene (HDPE) in order to form the lateral wall of a bottle intended to receive a cosmetic product containing a volatile solvent in spite of the generally poor barrier properties of HDPE with respect to volatile solvents. In addition to its reasonable price, HDPE has the advantage of being inert and therefore compatible with the compounds used in the cosmetic product formulations. Many tests of compatibilities of the cosmetic product with the bottle may therefore be avoided or reduced. Thus, HDPE further has good barrier properties with respect to water so that a bottle including an HDPE wall covered with a barrier label with respect to volatile solvents has universal barrier properties, i.e. both with respect to water and with respect to volatile solvents, and may receive any type of cosmetic product without it being necessary to be concerned about the evaporation of the cosmetic product. By good barrier properties with respect to water, is meant in the field of mascara, that water confined for 3 months at 40° C. in the tested plastic material is subject to a weight loss of less than 2%. 
         [0015]    According to a preferred embodiment of the invention, the label includes an external decoration and/or protection layer, an intermediate barrier layer with respect to the volatile solvent and an internal adhesive layer. 
         [0016]    The intermediate barrier layer may comprise a physical barrier such as an aluminium layer, which forms a total barrier with respect to the volatile solvents, but also with respect to water. Such a bottle therefore has universal barrier properties and enables non-evaporation of any mascara formulation stored within it. 
         [0017]    This physical barrier may further be formed by a metallized film, for example a film covered with a coating which is deposited by physically depositing a vapor phase, more known under the name of PVD (Physical Vapor Deposition). A film covered with a fine layer of SiO x  (10-100 nanometers) is perfectly suitable for this application. 
         [0018]    The intermediate barrier layer may otherwise comprise a barrier polymer such as EVOH which forms a known barrier with respect to volatile solvents. This barrier polymer may further be selected from an acetal resin, PET, PVC, a HDPE/EVOH mixture or polyethylene having been subject to fluorination. 
         [0019]    The adhesive layer preferably consists of the same material as the lateral wall or of a material compatible with the material of the lateral wall. 
         [0020]    The external layer may preferably be a layer of polyethylene terephthalate (PET), polyethylene (PE) or polypropylene (PP), bearing an imprint on its face facing the intermediate layer. 
         [0021]    When the adhesive layer consists of a polyolefin, a polyolefin (PE or PP) is advantageously used for forming the external layer so that the adhesive layer properly adheres onto the external layer when there is overlapping of the edges of the label. 
         [0022]    According to a preferred embodiment, the bottle comprises a lateral wall and at least one end, the lateral wall and said end consisting of different plastic materials, the plastic material of said end having greater barrier properties with respect to the volatile solvent than those of the plastic material of the lateral wall. A bottle in addition to its natural wall includes two ends formed by a neck forming an aperture and a bottom opposite to this aperture. As the ends are not covered by the label, it is particularly advantageous to mold one of the two ends—or both ends—separately from the lateral wall by using a plastic material having better barrier properties with respect to the volatile solvent than those of the plastic material of the lateral wall and by bringing together the lateral wall and the end—or the ends—in order to form the bottle. The barrier properties of the bottle are then improved. The material overcost for using plastic materials having suitable barrier properties and/or the molding difficulties with such plastic materials are thus advantageously limited to said end and not to the bottle in its whole. Advantageously, the lateral wall may be injection-molded with one of the ends, while the other end including the better barrier properties is added. The added end is preferably the bottom of the bottle since the bottom of the bottle commonly includes a larger exchange surface area than the neck. 
         [0023]    According to a preferred embodiment, the plastic material of the end has high barrier properties, so that the volatile solvent confined in this plastic material for 3 months at 40° C. undergoes a weight loss of less than 3%. Such a seal level is suitable for mascara applications. 
         [0024]    Also, the basis of the plastic material of said end may be selected from acetal resin, PET, HDPE/EVOH mixture, polyethylene having been subject to fluorination or PVC. The HDPE/EVOH mixture is particularly appreciated for its joint barrier properties with respect to water and with respect to volatile solvents. 
         [0025]    According to different preferred embodiments:
       the plastic material of the lateral wall may further advantageously have high barrier properties with respect to water, so that the water confined in this plastic material for 3 months at 40° C. undergoes a weight loss of less than 2%; there actually exists a need for a bottle having good barrier properties both with respect to water and with respect to solvents. In order to be used as a bottle of universal use or for containing mascaras containing both volatile solvents and water;   the basis of the plastic material of the lateral wall is selected from HDPE or from polylactic acid (PLA);   the plastic material of the lateral wall is a plastic material inert with the cosmetic product, selected from PP, PE, biodegradable materials, or a mixture of PP/biodegradable material or PE/biodegradable material;   the lateral wall consists of HDPE and the bottom consists of HDPE/EVOH;   the lateral wall is injection-molded and the label is affixed on said outside lateral surface during the injection-molding of the lateral wall by a label molding technique in the mold; the fact that the label covers the surface of the lateral wall and is laid by injection-molding allows a reduction in the thickness of the lateral walls while having the same rigidity and strength characteristics as earlier; the thickness of the lateral wall, commonly comprised between 0.8 and 1 mm may then be reduced to a thickness of less than 0.8 mm, which allows reduction in the raw material cost; with label molding in the mold, it is moreover possible to obtain higher adhesion and aesthetical quality than what may be obtained with simple sizing.       
 
         [0031]    Still according to another embodiment of the invention, the bottle further includes a bottom covered with a second label having barrier properties with respect to the volatile solvent. The evaporation of the volatile solvents contained in the bottle is then advantageously prevented at the lateral wall by the label covering the outside lateral surface and by the bottom by this second label. 
         [0032]    The invention also extends to a mascara distributor, comprising:
       a bottle as defined above intended for receiving mascara;   a wiper positioned in the aperture of the bottle; and   a means for closing said aperture comprising a gripping means, a rod and a means for applying mascara.       
 
         [0036]    Finally, the invention also extends to a method for making a bottle for a cosmetic product including volatile solvents, notably for mascara, having at least one lateral wall portion in molded plastic material covered by a label and comprising the steps of:
       providing a label having barrier properties with respect to the volatile solvents and including an outside decoration or protection layer, an intermediate barrier layer with respect to the volatile solvents and an adhesive internal layer;   inserting said label in a mold;   injecting said plastic material in the mold so as to achieve label molding in the mold.       
 
         [0040]    Such manufacturing by label molding in the mold allows limitation of the number of successive operations to be carried out in order to obtain the bottle and notably the adhesive bonding of the label on the lateral wall as this is commonly carried out. 
         [0041]    In order that such a method be economically viable, the manufacturing by label molding in the mold has however to be carried out at a high rate. 
         [0042]    The invention will be better understood by means of the following description and of the appended figures given as a non-limiting example. 
     
    
     
       SHORT DESCRIPTION OF THE DRAWINGS 
         [0043]      FIG. 1  illustrates in a perspective top view a bottle and a label intended to be put on the lateral surface of the bottle. 
           [0044]      FIG. 2  is a sectional view of a mascara distributor according to the invention. 
           [0045]      FIG. 3  schematically illustrates a label according to the invention. 
           [0046]      FIG. 4  illustrates in a top perspective view, a bottle including a bottom added onto the lateral wall. 
           [0047]      FIG. 5  is a sectional view of a portion of the bottle of  FIG. 4  and schematically illustrates a means for assembling the bottom on the lateral wall. 
           [0048]      FIG. 6  illustrates in a top perspective view, a bottle including a neck added onto the lateral wall. 
           [0049]      FIG. 7  is a sectional view of a portion of the bottle of  FIG. 6  and schematically illustrates a means for assembling the neck on the lateral wall. 
           [0050]      FIG. 8  schematically illustrates a machine by means of which the bottle according to the invention may be manufactured. 
           [0051]      FIG. 9  illustrates in a front view the devices placed at a station for affixing labels of a particular machine. 
           [0052]      FIG. 10  illustrates in a perspective view, the device of  FIG. 8 , the transfer means this time being in a position for introducing the labels into imprints of matrices. 
           [0053]      FIG. 11  schematically illustrates the vicinity of a mandrel used for transferring the label from a storage area towards the molding cavity, very shortly before the label is conformed around the mandrel. 
           [0054]      FIG. 12   a  schematically illustrates a molding assembly intended for making a substantially flat bottom and a lateral wall after depositing a label in the imprint of the matrix. 
           [0055]      FIG. 12   b  details the diagram of  FIG. 12   a  in the peripheral portion of the imprint which is found in the vicinity of the connection between said bottom and said lateral wall. 
       
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
       [0056]    A label  100  rolled around a bottle  101  intended to receive a cosmetic product and visible by transparence through the label  100  is illustrated in  FIG. 1 . The bottle includes a bottom  102 , a lateral wall  103 , the outside lateral surface of which  104  is visible, and a neck  105  including an aperture  106 . The cosmetic products, and notably the mascara, increasingly include non-polar volatile solvents, notably of the alcohol or hydrocarbon type, such as isododecane. The label is further selected for its barrier properties with respect to volatile solvent(s) contained in the cosmetic products and is intended to be adhesively bonded on the outside lateral surface of bottle  101  in order to form the bottle according to the invention. 
         [0057]    As mascara bottles generally have a diameter close to 17 mm for a length close to 80 mm, the lateral wall accounts for about 90% of the exchange surface area of the bottle, so that preventing the evaporation of the volatile solvents through this lateral wall by means of the label amounts to limiting 90% of the evaporation of the volatile solvent relatively to a standard bottle. 
         [0058]    With the bottles according to the invention, it is possible to observe at lesser costs the requirements as regards preserving the mascara in its package, regularly set to a maximum weight loss of 3% of the volatile solvent after storage for 3 months at 40° C. 
         [0059]    A mascara distributor according to the invention including the bottle  101  with its lateral wall  103  covered with the label  100  and a mascara applicator  107  which will be screwed onto the neck  105  for closing the aperture  106  and consisting of a gripping means  108 , of a rod  109  and a means for applying the mascara  110  are illustrated in  FIG. 2 . A wiper  111  is further inserted into the aperture  106  of the neck  105 . The label  100  advantageously covers the whole outside lateral surface  104  of the bottle  101 . 
         [0060]    As visible in  FIG. 3 , the label includes an external decoration and/or protection layer  112 , an intermediate barrier layer  113  with respect to the volatile solvent and an internal adhesive layer  114 . The intermediate barrier layer  113  is preferably a layer of aluminium which forms a total barrier with respect to volatile solvents, but also with respect to water, this aluminium layer for example having a thickness from 6.5 to 65 μm and preferably from 8 to 12 μm. 
         [0061]    The intermediate barrier layer may further be formed by a metallized film, for example a film covered with a SiO x  coating with a thickness from 10 to 100 nanometers, deposited by physical vapor phase deposition. 
         [0062]    The intermediate barrier layer may however also be formed by a known polymeric material for its barrier properties with respect to volatile solvents such as an EVOH layer. 
         [0063]    The internal adhesive layer  114  is made up in the same way as the lateral wall and with a material compatible with the material of the lateral wall. A PE adhesive layer  114  is for example used when the lateral wall  103  is in HDPE. The adhesion between the label and the lateral wall is therefore very strong and there is no risk of delamination or detachment of the label, even after a long period. 
         [0064]    The external layer is preferably a layer of polyethylene terephthalate (PET), polyethylene (PE) or polypropylene (PP), bearing an imprint on its face facing the intermediate layer. Such external layers are commonly used for decorating and protecting flexible packages. Quality decorations may be obtained on such external layers by flexography or photogravure which provides vast opportunities in terms of coloration or fineness. 
         [0065]    The bottle  101  is advantageously molded in HDPE because HDPE has a reasonable price and is inert and therefore compatible with the compounds used in cosmetic product formulations. HDPE further has good barrier properties with respect to water so that a bottle including a HDPE wall covered with a barrier label with respect to volatile solvents has universal barrier properties, i.e. both with respect to water and with respect to volatile solvents, and may receive any type of cosmetic products without it being necessary to be concerned about the evaporation of the cosmetic product. By good barrier properties with respect to water, is meant in the field of mascara, that water confined for 3 months at 40° C. in the tested plastic material undergoes a maximum weight loss of 2%. 
         [0066]    The bottle  101  may also be molded in polylactic acid (PLA) appreciable for its biodegradability properties and for its compatibility with volatile solvents. 
         [0067]    Other plastic materials may also be used in cosmetics for molding the bottle  101  after determining their compatibility with the cosmetic product such as for example PP, PE, biodegradable materials such as for example polyhydroxyalkanoate (PHA), polyhydroxybutyrate (PHB), polyhydroxyvalerate (PHV), starch derivatives, succinic acid derivatives, PP/biodegradable material mixtures and PE/biodegradable material mixtures. 
         [0068]    Tests were conducted in order to demonstrate the seal of the bottle  101  according to the invention. Cylindrical HDPE bottles (product reference MG9601 of Borealis) with a height of 77 mm for a diameter of 15 mm were filled with 5 ml of water or 5 mL of isododecane, sealed hermetically, and then subject to a temperature of 40° C. for 3 months. The water and isododecane weight losses were 0.8% and 9.9%, respectively. The same bottles with the outside lateral surface covered by a label including an aluminium layer were subject to the same experiment and the water and isododecane weight losses were 0.1% and 1.9%, respectively. Water and isododecane evaporation was strongly reduced with this bottle according to the invention. Such a bottle according to the invention may therefore be used without any modification in order to receive as required, a mascara based on water or a mascara based on isododecane. 
         [0069]    In order to further improve the barrier properties of the bottle with respect to a volatile solvent without modifying the advantageously economical and practical constitution of the lateral wall  103 , it is contemplated to additionally act on the barrier properties of the sole portions of the bottle  101  not covered by the label  100 , i.e. the neck  105  and/or on the bottom  102 , further defined by the term of ends. 
         [0070]    Thus, two other advantageous embodiments according to the invention are shown in  FIGS. 4 ,  5  and in  FIGS. 6 ,  7 , respectively. 
         [0071]    As visible in  FIGS. 4 and 5  which show the bottle  101  without the label  100  for the sake of clarity, the bottle  101  includes a bottom  102 ′ added on an aperture at the base of the lateral wall  103 ; i.e. the bottom of the bottle is formed by a distinct element  102 ′ which has not been molded with the lateral wall  103 . The bottom  102 ′ is attached to the base of the lateral wall  103  for example by snapping a ridge  115  formed on the lateral wall  103  onto a groove  116  formed on a tab of the bottom  102 ′. The attachment should provide a perfect seal. Other attachment means may of course be used, such as adhesive bonding, welding, screwing . . . . 
         [0072]    The bottom  102 ′ was molded in a plastic material having good barrier properties with respect to the volatile solvent of the cosmetic product and more particularly in a plastic material different from the plastic material of the lateral wall and having higher barrier properties with respect to the volatile solvent than those of the plastic material of the lateral wall. 
         [0073]    The plastic material of the bottom  102 ′ has high barrier properties, so that the volatile solvent confined in this plastic material for 3 months at 40° C. undergoes a weight loss of less than 3%. 
         [0074]    The plastic material of the bottom  102 ′ is more particularly selected from acetal resin, PET, a HDPE/EVOH mixture or polyethylene having undergone fluorination and PVC. 
         [0075]    By preventing the evaporation of the volatile solvent through the lateral wall  103  by means of the label  100  and through the bottom  102 ′ by selecting a suitable material, a bottle is obtained which is perfectly adapted to the requirements in the field of cosmetic products and more particularly in the field of mascara. 
         [0076]    According to a preferred embodiment of the invention, the bottom  102 ′ consists of a HDPE/EVOH mixture, the lateral wall  103  consists of HDPE and the label  100  includes an aluminium layer. 
         [0077]    As visible in  FIGS. 6 and 7  which show the bottle  101  without a label  100  for the sake of clarity, the bottle  101  includes a neck  105 ′ added onto an aperture at the top of the lateral wall  103 ; i.e. the neck of the bottle is formed by a distinct element  105 ′ which has not been molded with the lateral wall  103 . The neck  105 ′ is attached to the lateral wall  103 , for example by snapping a ridge  117  formed on the lateral wall  103  onto a groove  118  formed on the neck  105 ′. The attachment should provide a perfect seal. Other attachment means may of course be used, such as adhesive bonding, welding, screwing . . . . 
         [0078]    The neck  105 ′ was molded in a plastic material having good barrier properties with respect to the volatile solvent of the cosmetic product and more particularly in a plastic material different from the plastic material of the lateral wall  103  and having higher barrier properties with respect to the volatile solvent than those of the plastic material of the lateral wall  103 . 
         [0079]    The plastic material of the neck  105 ′ has high barrier properties, so that the volatile solvent confined in this plastic material for 3 months at 40° C., undergoes a weight loss of less than 3%. 
         [0080]    The plastic material of the neck  105 ′ is more particularly selected from acetal resin, PET, HDPE/EVOH mixture or polyethylene having undergone fluorination and PVC. 
         [0081]    By preventing the evaporation of the volatile solvent through the lateral wall  103  by means of the label  100  and through the neck  105 ′ by selecting a suitable material, a bottle is obtained which is perfectly adapted to the requirements in the field of cosmetic products and more particularly in the field of mascara. 
         [0082]    According to a preferred embodiment of the invention, the neck  105 ′ consists of a HDPE/EVOH mixture, the lateral wall  103  consists of HDPE and the label  100  includes an aluminium layer. 
         [0083]    Of course, for greater efficiency, it is also possible to add both a neck  105 ′ and a bottom  102 ′ on a lateral wall  103  covered with a label  100 . 
         [0084]    We shall discuss hereafter as an example a particularly advantageous method for making the product according to the invention, and more particularly the bottle  101  illustrated by  FIGS. 6 and 7 . 
         [0085]    In fields other than that of mascara bottles, bodies in plastic material are known for which the outer surface is provided with a label. These labels may be applied on the outer surface by means of so-called “in-mold labeling” (IML) method but which we shall prefer to subsequently designate by label molding in the mold. It is particularly interesting for making bottles in plastic material, having a lateral wall covered by a label, said lateral wall extending along an axisymmetrical surface with a perpendicular axis, such as cylinder or a frustum, to the plane of the bottom. It is intended even more particularly for containers or bottles, the dimensions of which are relatively small, i.e. with a diameter comprised between 13 and 60 mm and a height comprised between 40 and 200 mm and the lateral wall of which is entirely covered or almost entirely covered by said label. 
         [0086]    The molding is carried out by injecting plastic material into a mold including at least two portions movable relatively to each other, which, by bringing them closer to each other, allows a molding cavity to be made and which by moving them away from each other allows the molded part to be ejected. For more specifically targeted axisymmetrical bottles, the mold comprises a female portion or die, including at least one hollow imprint corresponding to the external shape of the bottle, and a male portion or punch, including at least one raised imprint corresponding to the internal face of said bottle. 
         [0087]    In order to make the present invention economically viable by using a label molding technique in the mold, it is possible to use a manufacturing method with which a manufacturing cycle time for such bottles, as short as possible, may be ensured. Moreover it is interesting that this method may repeatedly ensure accurate positioning of the label, in particular when the latter has to entirely cover the lateral wall of the bottle. 
         [0088]    For this, it is possible to use, as a non-limiting example, the manufacturing method described below and illustrated by  FIGS. 7-12   b.    
         [0089]    In order to mold mascara bottles having a substantially flat bottom and an asymmetrical or quasi-cylindrical lateral wall entirely covered with a label, a machine is used which comprises:
       an indexed rotary plate  60  operating stepwise and subdivided into six sectors for serving six work stations. On this plate are mounted in each of the six sectors, six molding assemblies  50 , each comprising six dies  31 , grouped in a die-holder assembly  30  and six punches  41  grouped in a punch-holder assembly  40 ; the punches and the dies appear here as a rake, aligned so that their axes are parallel to each other and equidistant;   an injection press (not shown), placed on one of the work stations of the rotary plate,   a device for affixing labels located upstream from the injection press, schematized in  FIG. 1  and detailed in  FIGS. 2 and 3 , comprising six interdependent mandrels  21  and placed as a rake with a distance between their axes identical to that of the dies and of the punches, each acting as a means  20  for transferring the labels, driven by a first actuator  90 , which in fact is an assembly of actuator cylinders and rotary motors allowing the mandrels  21  to be presented substantially horizontally so that they receive the labels  5  and the latter to be presented substantially vertically so that they may be introduced, provided with their labels, inside the imprints  32  of the dies  31 , the molding assembly  50  being opened at said station for affixing the labels, so that said labels may be deposited in said imprints.       
 
         [0093]    Supply of labels is ensured by a rotary table  71  comprising two diametrically opposite magazines  72  and  73 , one ( 72 ) ready to be filled, the other one ( 73 ) comprising six stacks of labels is placed under six cylinders with suction cups  11 , each acting as a means  10  for picking up labels. The whole of the suction cup cylinders  11  may be displaced above an area where the mandrels  21  actuated by the actuator  90 , are placed horizontally so as to each receive a label  5 ′. 
         [0094]    The labels  5 ′ have been cut out in a multilayer flexible sheet in plastic material, comprising an external layer printed in four colors by flexography and an aluminium layer forming a barrier with respect to diffusion of gases. They have larger width, of the order of 1 mm at the circumference of the lateral wall of the bottle to be made. They have greater length of the order of 1 mm, at the height of the lateral wall of the bottle to be made. 
         [0095]    The labels  5 ′ are presented in such a way that they arrive slightly unbalanced on their mandrels  21 : their middle axis  7  forms with the upper generatrix  24  of the associated mandrel an angle close to 10° (measured in a plane perpendicular to the axis of the mandrel). 
         [0096]    The mandrels  21  are cylindrical with sections of 0.5 mm smaller diameters than those of the dies. Each mandrel  21  is provided with channels  22  opening onto its surface and in which air may be sucked up or blown. 
         [0097]    While sucking up air through the channels  22  of the mandrels  21 , the labels  5 ′ are released from the suction cups  11  and the latter will rest on the upper generatrix  24  of the mandrels  21  placed horizontally. In order to conform the labels  5 ′ on the mandrels  21 , 6 upper half-shells  83  also arranged as a rake, which apply the labels against the upper portion of the mandrels, are moved down. The shaping of the label is continued by moving up the 6 lower half-shells  83 . During this upward movement, for each label, the edges follow the wall of the hollow surface  84  of the lower half-shells  83  until they overlap by over about 1 mm. The final geometrical configuration of the thereby conformed label is such that the edges or any other portion of the label do not touch the wall of the imprint of the die, during the introduction of the mandrel into the imprint of the die. 
         [0098]    The half-shells are removed while maintaining suction of air through the mandrels  21 . By means of the first actuator  90 , the mandrels  21  are displaced towards the rotary plate and the 6 molding assemblies  50  maintained in the open position. The six mandrels  31  are introduced into the six imprints  32  of the dies  31  while maintaining sufficient suction power so that the labels are maintained conformed in this way. 
         [0099]    Each mandrel  21  is provided with three rows of opening channels  22 , one row aligned on the upper generatrix  24  of the mandrel and two rows aligned along the symmetrical generatrices relatively to the vertical diametrical plane of said mandrel, the closest edge of the orifices being located at a distance close to 3 mm from the lower generatrix  25 . The orifices are regularly positioned on said generatrices, at a distance close to 3 mm from each other. By sucking up air with a negative pressure of the order of 4-5 bars, one manages to maintain said flattened labels on their mandrels and to introduce the latter inside the imprints of the dies without there being any collision. 
         [0100]    When the mandrels  21  have penetrated into the imprints  32  to a predetermined depth, the airflow direction is reversed in the channels  22  of the mandrels  21  so that the labels unroll and their edges come into contact with the lateral walls of imprints  32 . 
         [0101]    The predetermined penetration depth of the mandrels into the imprints is defined so that, when the latter is reached, the ends of the labels extend beyond the imprints of the dies by a distance close to 1 mm. 
         [0102]    The punches  41  have a lateral surface which is provided at the base of a shoulder  42  forming a joint plane with the associated die  31 . The shoulder is placed at a distance such that when the punch  41  and the matrix  31  are brought closer together, the jutting-out end  6  of the label  5 ′ comes into abutment against said shoulder  42  and is driven by the latter towards the bottom  33  of the die  31  until it occupies it final position. 
         [0103]    When the punch  41  and the die  31  are side-by-side in order to form the molding cavity, the second end  8  of the label juts out from the punch  41  into the molding cavity. The peripheral portion  34  of the imprint has the following shape:
       at the periphery, the lateral wall  35  of the imprint facing the punch  41  remains substantially axial;   when the die  31  and the punch  41  are in contact with each other, the bottom  33  of the imprint  32  of the die  31  being at right angles to the lateral wall is at a greater depth than the jutting-out height of the second end  8  of the label, so that said end does not come into abutment on the bottom of said die imprint and that, during the injection, the plastic material injected in a point located close to the axis, has to flow radially in an annular peripheral area  36  located above the apical slice of said end portion;   the bottom of the die has an annular boss  37  which is an obstacle to the flow of the plastic material towards said annular peripheral area  36 , the outside edge  38  of said annular boss  37  and the inside edge of the second end being distant from each other by a value smaller than the average thickness of said bottom.       
 
         [0107]    The molding assemblies are then closed and locked and the rotary plate rotates so that the molding assemblies arrive at the molding station. Downstream, two stations are dedicated to cooling the thereby molded elements and a station is dedicated to ejecting the molded elements after the molding devices have been opened. A maneuvering device ensuring the opening, closing and locking of the mobile portions of the molding assemblies is placed in each sector of the rotary plate, associated with six punches and with six dies. Thus, this operation may be performed concurrently independently of the immobilization time at each station. 
         [0108]    With such a machine, mascara containers for which the lateral wall comprised between 0.6 and 1.5 mm is entirely covered with a label are easily made at a clearly higher rate relative to standard injection. 
         [0109]    Still according to another advantageous embodiment of the bottle, the bottom  102  of the bottle  101  of  FIG. 1  may further be covered with a second label having barrier properties with respect to the volatile solvent. The bottom generally forming an outside planar surface, the attachment of the second label onto the bottom may be carried out in a simple way. The evaporation of the volatile solvents contained in the bottle  101  is then advantageously prevented at the lateral wall  103  by the label  100  covering the outside lateral surface  104  and through the bottom  102  by this second label. This second label for example has physical characteristics and properties identical with those of the label  100 . The bottom  102  as for it, may have physical characteristics identical with those of the lateral wall. 
         [0110]    The bottom  102  and the lateral wall  103  may for example have been molded together with the label  100  as the second label. The label  100  and the second label may form a single label or two distinct labels. 
         [0111]    The label  102  and the lateral wall  103  may further have been molded together only with the label  100 . The second label may then be adhesively bonded subsequently, for example during the filling of the bottle in order to reference the bottle. 
         [0112]    The lateral wall  103  may further be molded with the label  100  separately from the bottom which is molded with the second label, and then the bottom  102  added onto the lateral wall  103 .