Abstract:
A method of operating a heat transfer system includes starting operation of a first heat transfer fluid vapor/compression circulation loop including a fluid pumping mechanism, a heat exchanger for rejecting thermal energy from a first heat transfer fluid, and a heat absorption side of an internal heat exchanger. A first conduit in a closed fluid circulation loop circulates the first heat transfer fluid therethrough. Operation of a second two-phase heat transfer fluid circulation loop is started after starting operation of the first heat transfer fluid circulation loop. The second heat transfer fluid circulation loop transfers heat to the first heat transfer fluid circulation loop through the internal heat exchanger and includes a heat rejection side of the internal heat exchanger, a liquid pump, and a heat exchanger evaporator. A second conduit in a closed fluid circulation loop circulates a second heat transfer fluid therethrough.

Description:
FEDERAL RESEARCH STATEMENT 
       [0001]    This invention was made with government support under contract number DE-EE0003955 awarded by the Department of Energy. The government has certain rights in the invention. 
     
    
     BACKGROUND OF THE INVENTION 
       [0002]    The present disclosure relates to refrigeration systems. More specifically, the present disclosure relates to refrigeration systems with multiple heat transfer fluid circulation loops. 
         [0003]    Refrigerant systems are known in the HVAC&amp;R (heating, ventilation, air conditioning and refrigeration) art, and operate to compress and circulate a heat transfer fluid throughout a closed-loop heat transfer fluid circuit connecting a plurality of components, to transfer heat away from a secondary fluid to be delivered to a climate-controlled space. In a basic refrigerant system, heat transfer fluid is compressed in a compressor from a lower to a higher pressure and delivered to a downstream heat rejection heat exchanger, commonly referred to as a condenser for applications where the fluid is sub-critical and the heat rejection heat exchanger also serves to condense heat transfer fluid from a gas state to a liquid state. From the heat rejection heat exchanger, where heat is typically transferred from the heat transfer fluid to ambient environment, high-pressure heat transfer fluid flows to an expansion device where it is expanded to a lower pressure and temperature and then is routed to an evaporator, where heat transfer fluid cools a secondary heat transfer fluid to be delivered to the conditioned environment. From the evaporator, heat transfer fluid is returned to the compressor. One common example of refrigerant systems is an air conditioning system, which operates to condition (cool and often dehumidify) air to be delivered into a climate-controlled zone or space. Other examples may include refrigeration systems for various applications requiring refrigerated environments. 
         [0004]    However, many proposed systems having two-phase CO 2  as a secondary heat transfer fluid require the CO 2  to be maintained in a supercritical fluid state, which can add to equipment and operating complexity and cost. Further, conventional operation, especially startup, of such a system can result in operational inefficiency and pump cavitation in the secondary heat transfer loop. 
       BRIEF DESCRIPTION OF THE INVENTION 
       [0005]    In one embodiment, a method of operating a heat transfer system includes starting operation of a first heat transfer fluid vapor/compression circulation loop including a fluid pumping mechanism, a heat exchanger for rejecting thermal energy from a first heat transfer fluid, and a heat absorption side of an internal heat exchanger. A first conduit in a closed fluid circulation loop circulates the first heat transfer fluid therethrough. Operation of a second two-phase heat transfer fluid circulation loop is started after starting operation of the first heat transfer fluid circulation loop. The second heat transfer fluid circulation loop transfers heat to the first heat transfer fluid circulation loop through the internal heat exchanger and includes a heat rejection side of the internal heat exchanger, a liquid pump, and a heat exchanger evaporator. A second conduit in a closed fluid circulation loop circulates a second heat transfer fluid therethrough. 
         [0006]    In another embodiment, a heat transfer system includes a first two-phase heat transfer fluid vapor/compression circulation loop including a compressor, a heat exchanger condenser, an expansion device, and a heat absorption side of a heat exchanger evaporator/condenser. A first conduit in a closed fluid circulation loop circulates a first heat transfer fluid therethrough. A second two-phase heat transfer fluid circulation loop that transfers heat to the first heat transfer fluid circulation loop through the heat exchanger evaporator/condenser and includes a heat rejection side of the heat exchanger evaporator/condenser, a liquid pump disposed vertically lower than the heat exchanger evaporator/condenser, and a heat exchanger evaporator. A second conduit in a closed fluid circulation loop circulates a second heat transfer fluid therethrough. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0007]    The subject matter which is regarded as the invention is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other features, and advantages of the invention are apparent from the following detailed description taken in conjunction with the accompanying drawings in which: 
           [0008]      FIG. 1  is a block schematic diagram depicting an embodiment of a heat transfer system having first and second heat transfer fluid circulation loops; 
           [0009]      FIG. 2  is an elevation view of an embodiment of a heat transfer system having first and second heat transfer fluid circulation loops; and 
           [0010]      FIG. 3  is a schematic plot illustrating an embodiment of a startup sequence for a heat transfer system having first and second heat transfer fluid circulation loops. 
       
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
       [0011]    An exemplary heat transfer system with first and second heat transfer fluid circulation loop is shown in block diagram form in  FIG. 1 . As shown in  FIG. 1 , a compressor  110  or other pumping device in first fluid circulation loop  100  pressurizes a first heat transfer fluid in its gaseous state, which both heats the fluid and provides pressure to circulate it throughout the system. The hot pressurized gaseous heat transfer fluid exiting from the compressor  110  flows through conduit  115  to heat exchanger condenser  120 , which functions as a heat exchanger to transfer heat from the heat transfer fluid to the surrounding environment, such as to air blown by fan  122  through conduit  124  across the heat exchanger condenser  120 . The hot heat transfer fluid condenses in the condenser  120  to a pressurized moderate temperature liquid. The liquid heat transfer fluid exiting from the condenser  120  flows through conduit  125  to expansion device  130 , where the pressure is reduced. The reduced pressure liquid heat transfer fluid exiting the expansion device  130  flows through conduit  135  to the heat absorption side of heat exchanger evaporator/condenser  140 , which functions as a heat exchanger to absorb heat from a second heat transfer fluid in secondary fluid circulation loop  200 , and vaporize the first heat transfer fluid to produce heat transfer fluid in its gas state to feed the compressor  110  through conduit  105 , thus completing the first fluid circulation loop. 
         [0012]    A second heat transfer fluid in second fluid circulation loop  200  transfers heat from the heat rejection side of heat exchanger evaporator/condenser  140  to the first heat transfer fluid on the heat absorption side of the heat exchanger  140 , and the second heat transfer fluid vapor is condensed in the process to form second heat transfer fluid in its liquid state. The liquid second heat transfer fluid exits the heat exchanger evaporator/condenser  140  and flows through conduit  205  as a feed stream for liquid pump  210 . The liquid second heat transfer fluid exits pump  210  at a higher pressure than the pump inlet pressure and flows through conduit  215  to heat exchanger evaporator  220 , where heat is transferred to air blown by fan  225  through conduit  230 . Liquid second heat transfer fluid vaporizes in heat exchanger evaporator  220 , and gaseous second heat transfer fluid exits the heat exchanger evaporator  220  and flows through conduit  235  to the heat rejection side of heat exchanger evaporator/condenser  140 , where it condenses and transfers heat to the first heat transfer fluid in the primary fluid circulation loop  100 , thus completing the second fluid circulation loop  200 . 
         [0013]    In an additional exemplary embodiment, the second fluid circulation loop  200  may include multiple heat exchanger evaporators (and accompanying fans) disposed in parallel in the fluid circulation loop. This may be accomplished by including a header (not shown) in conduit  215  to distribute the second heat transfer fluid output from pump  210  in parallel to a plurality of conduits, each leading to a different heat exchanger evaporator (not shown). The output of each heat exchanger evaporator would feed into another header (not shown), which would feed into conduit  235 . Such a system with multiple parallel heat exchanger evaporators can provide heat transfer from a number of locations throughout an indoor environment without requiring a separate outdoor fluid distribution loop for each indoor unit, which cannot be readily achieved using indoor loops based on conventional 2-phase variable refrigerant flow systems that require an expansion device for each evaporator. A similar configuration can optionally be employed in the first fluid circulation loop  100  to include multiple heat exchanger condensers (and accompanying fans and expansion devices) disposed in parallel in the fluid circulation loop, with a header (not shown) in conduit  115  distributing the first heat transfer fluid in parallel to a plurality of conduits each leading to a different heat exchanger condenser and expansion device (not shown), and a header (not shown) in conduit  135  to recombine the parallel fluid flow paths. When multiple heat exchanger condensers are used, the number of heat exchanger condensers and expansion devices would generally be fewer than the number of heat exchanger evaporators. 
         [0014]    The first heat transfer fluid circulation loop utilizes heat transfer fluids that are not restricted in terms of flammability and/or toxicity, and this loop is a substantially outdoor loop. The second heat transfer fluid circulation loop utilizes heat transfer fluids that meet certain flammability and toxicity requirements, and this loop is substantially an indoor loop. By substantially outdoor, it is understood that a majority if not the entire loop is outdoors, but that portions of the substantially outdoor first loop may be indoors and that portions of the substantially indoor second loop may be outdoors. In an exemplary embodiment, any indoor portion of the outdoor loop is isolated in a sealed fashion from other protected portions of the indoors so that any leak of the first heat transfer fluid will not escape to protected portions of the indoor structure. In another exemplary embodiment, all of the substantially outdoor loop and components thereof is located outdoors. By at least partially indoor, it is understood that at least a portion of the loop and components thereof is indoors, although some components such as the liquid pump  210  and/or the heat exchanger evaporator condenser  140  may be located outdoors. The at least partially indoor loop can be used to transfer heat from an indoor location that is remote from exterior walls of a building and has more stringent requirements for flammability and toxicity of the heat transfer fluid. The substantially outdoor loop can be used to transfer heat from the indoor loop to the outside environment, and can utilize a heat transfer fluid chosen to provide the outdoor loop with thermodynamic that work efficiently while meeting targets for global warming potential and ozone depleting potential. The placement of portions of the substantially outdoor loop indoors, or portions of the indoor loop outdoors will depend in part on the placement and configuration of the heat exchanger evaporator/condenser, where the two loops come into thermal contact. In an exemplary embodiment where the heat exchanger evaporator/condenser is outdoors, then portions of conduits  205  and/or  235  of the second loop will extend through an exterior building wall to connect with the outdoor heat exchanger evaporator/condenser  140 . In an exemplary embodiment where the heat exchanger evaporator/condenser  140  is indoors, then portions of conduits  105  and/or  135  of the first substantially outdoor loop will extend through an exterior building wall to connect with the indoor heat exchanger evaporator/condenser  140 . In such an embodiment where portions of the first loop extend indoors, then an enclosure vented to the outside may be provided for the heat exchanger evaporator/condenser  140  and the indoor-extending portions of conduits  105  and/or  135 . In another exemplary embodiment, the heat exchanger evaporator/condenser  140  may be integrated with an exterior wall so that neither of the fluid circulation loops will cross outside of their primary (indoor or outdoor) areas. 
         [0015]    Referring now to  FIG. 2 , in some embodiments, the liquid pump  210  is located at a position vertically lower than the heat exchanger evaporator/condenser  140 , with conduit  205  extending downwardly from the heat exchanger evaporator/condenser  140  to ensure sufficient column height of the second heat transfer fluid at the inlet of the liquid pump  210  to avoid cavitation of the liquid pump  210 . Further, internal volumes of the heat exchanger evaporator/condenser  140  and the heat exchanger evaporator  220  are matched to ensure charge balance of the system during a wide range of expected operating conditions. Still further, in some embodiments, the amount of liquid charge in the system, as a percentage of total heat exchanger volume in the system, is about 50% liquid to ensure proper startup of the system, especially the second fluid circulation loop  200 . 
         [0016]    Starting operation of the first fluid circulation loop  100  and the second fluid circulation loop  200  requires coordination of various components in the first fluid circulation loop  100  and the second fluid circulation loop  200  via a plurality of actuators controlling components thereof. Initializing operation of the entire loops  100  and  200  simultaneously reduces system efficiency and may result in system stoppage or breakdown. To maximize system efficiency at startup, the first fluid circulation loop  100  is initialized before startup of the second fluid circulation loop  200 , typically in a range between 0.1 second and 10 minutes prior to second fluid circulation loop  200  startup. In other embodiments, startup of the second fluid circulation loop  200  is started between 0.1 second and 5 minutes or between 0.1 second and 1 minute after startup of the first fluid circulation loop  100 . This ensures a flow of cooled first heat transfer fluid through the heat exchanger evaporator/condenser  140  for thermal exchange with the second heat transfer fluid. 
         [0017]    More particularly, as shown in  FIG. 3 , startup of the system begins with opening of the expansion device  130 , followed by startup of the fan  122  to flow air across the condenser  120 . The compressor  110  is then started. After compressor  110  startup and flow of the first heat transfer fluid through the heat exchanger evaporator/condenser  140  begins, after a delay of between 0.1 second and 10 minutes, the liquid pump  210  is then started to draw the second heat transfer fluid through the heat exchanger evaporator/condenser  140  and toward the heat exchanger evaporator  220 . Once flow of cooled second heat transfer fluid through the heat exchanger evaporator  220  is achieved, fan  225  is started to flow air across the heat exchanger evaporator  220 . 
         [0018]    Similarly, when stopping operation of the system, operation of the first fluid circulation loop  100  is stopped before operation of the second fluid circulation loop  200  is stopped. The time delay between shutdown of the first fluid circulation loop  100  and shutdown of the second fluid transfer loop  200  is in a range of between 0.1 second and 10 minutes. In other embodiments, the time delay is between 0.1 second and 5 minutes or between 0.1 second and 1 minute. 
         [0019]    The heat transfer fluid used in the first fluid circulation loop has a critical temperature of greater than or equal to 31.2° C., more specifically greater than or equal to 35° C., which helps enable it to maintain two phases under normal operating conditions. Exemplary heat transfer fluids for use in the first fluid circulation loop include but are not limited to saturated hydrocarbons (e.g., propane, isobutane), unsaturated hydrocarbons (e.g., propene), R32, R152a, ammonia, an R1234 isomer (e.g., R1234yf, R1234ze, R1234zf), R410a, and mixtures comprising one or more of the foregoing. 
         [0020]    The heat transfer fluid used in the second fluid circulation loop has an ASHRAE Class A toxicity rating and an ASHRAE Class 1 or 2L flammability rating. Exemplary heat transfer fluids for use in the second fluid circulation loop include but are not limited to sub-critical fluid CO 2 , a mixture comprising an R1234 isomer (e.g., R1234yf, R1234ze) and an R134 isomer (e.g., R134a, R134) or R32, 2-phase water, or mixtures comprising one or more of the foregoing. In another exemplary embodiment, the second heat transfer fluid comprises at least 25 wt %, and more specifically at least 50 wt % sub-critical fluid CO 2 . In yet another exemplary embodiment, the second heat transfer fluid comprises nanoparticles to provide enhanced thermal conductivity. Exemplary nanoparticles include, but are not limited to, particles having a particle size less than 500 nm (more specifically less than 200 nm). In an exemplary embodiment, the nanoparticles have a specific heat greater than that of the second fluid. In yet another exemplary embodiment, the nanoparticles have a thermal conductivity greater than that of the second fluid. In further exemplary embodiments, the nanoparticles have a specific heat greater than at least 5 J/mol·K (more specifically at least 20 J/mol·K), and/or a thermal conductivity of at least 0.5 W/m·K (more specifically at least 1 W/m·K). In another exemplary embodiment, the second heat transfer fluid comprises greater than 0 wt % and less than or equal to 10 wt % nanoparticles, more specifically from 0.01 to 5 wt % nanoparticles. Exemplary nanoparticles include but are not limited to carbon nanotubes and metal or metalloid oxides such as Si 2 O 3 , CuO, or Al 2 O 3 . 
         [0021]    The expansion device used in the first heat transfer fluid circulation loop may be any sort of known thermal expansion device, including a simple orifice or a thermal expansion valve (TXV) or an electronically controllable expansion valve (EXV). Expansion valves can be controlled to control superheating at the outlet of the heat absorption side of the heat exchanger evaporator/condenser and optimize system performance. Such devices and their operation are well-known in the art and do not require additional detailed explanation herein. 
         [0022]    In another exemplary embodiment, one or more of the compressor  110 , fan  122 , fan  225 , and/or pump  210  utilizes a variable speed drive (VSD). Control of VSD&#39;s can be implemented utilizing known power control technologies, such as an integrated power electronic system incorporating an input power factor correction (PFC) rectifier and one or more inverters (e.g., an inverter for each separate VSD). The input PFC rectifier converts single-phase AC input voltage into a regulated DC common bus voltage in order to provide a near unity power factor with low harmonic current from the AC supply. The motor inverters can be connected in parallel with input drawn from the common DC bus. Motors with higher power requirements (e.g., &gt;1 kW such as for compressors) can use insulated gate bipolar transistors (IGBT&#39;s) as power switches whereas motors with lower power requirements (e.g., &lt;1 kW such as for fan blowers) can use lower-cost metal oxide semiconductor field effect transistors (MOSFET&#39;s). Any type of electric motor can be used in the VSD&#39;s, including induction motors or permanent magnet (PM) motors. In an exemplary embodiment, the compressor  110  utilizes a PM motor, optionally in conjunction with electronic circuitry and/or a microprocessor that adaptively estimates the rotor magnet position using only the winding current signals, thus eliminating the need for expensive Hall effect sensors typically used in PM motors. The precise speed settings of the VSD&#39;s will vary depending on the demands placed on the system, but can be set by system control algorithms to maximize system operating efficiency and/or meet system demand as is known in the art. Typically, compressor and pump speed can be varied to control system capacity based on user demand, while the speed of the indoor and outdoor fan blowers can be controlled to optimize system efficiency. 
         [0023]    While the invention has been described in detail in connection with only a limited number of embodiments, it should be readily understood that the invention is not limited to such disclosed embodiments. Rather, the invention can be modified to incorporate any number of variations, alterations, substitutions or equivalent arrangements not heretofore described, but which are commensurate with the spirit and scope of the invention. Additionally, while various embodiments of the invention have been described, it is to be understood that aspects of the invention may include only some of the described embodiments. Accordingly, the invention is not to be seen as limited by the foregoing description, but is only limited by the scope of the appended claims.