Abstract:
A method of improving lithography resolution on a semiconductor, including the steps of providing a substrate on which a protecting layer, a first etching layer and a photoresist layer are sequentially formed; patterning the photoresist layer to form an opening so as to partially reveal the first etching layer; implanting a first ion into the revealed first etching layer to form a first doped area; and implanting a second ion into the revealed first etching layer to form a second doped area, wherein the first doped area is independent from the second doped area is provided.

Description:
FIELD OF THE INVENTION 
       [0001]    The present invention relates to a method of improving the lithography resolution, in particular, to improve the lithography resolution for a semiconductor fabricating process. 
       BACKGROUND OF THE INVENTION 
       [0002]    At present, with the prosperous growth to the consuming electrical products, the current trend of consumers&#39; demand and need for the dimension of such products is almost towards small size and delicacy design. In order to substantially improve the sophistication during the fabricating process for a semiconductor and to shrink the scale of these products, a lithography process in a semiconductor fabricating process becomes very critical. That is, if the resolution of a lithography process could be further improved to reduce the analytic coefficient k 1 , the critical dimension in the succeeding fabricating steps could correspondingly become smaller so that a finer and more sophisticated semiconductor product is then obtainable. 
         [0003]    Due to the contribution of an excimer laser, the resolution of lithography is propelled to the scale around 100 nm (nanometer) and even the critical dimension of a node is further pushed to the scale around 45 nm. However, once the lithography resolution is reduced to the scale around 0.25 nm or even lower than 0.25 nm, because of the inherent limitation of the optical characteristic, the optical lithography technique at the present state is inapplicable. 
         [0004]    In order to overcome the mentioned defects in the existing lithography technique and to simultaneously improve the resolution of a lithography process, a method of improving the lithography resolution for a semiconductor is provided. 
       SUMMARY OF THE INVENTION 
       [0005]    According to the first aspect of the present invention, a method of improving lithography resolution on a semiconductor, including the steps of providing a substrate on which a protecting layer, a first etching layer and a photoresist layer are sequentially formed; patterning the photoresist layer to form an opening so as to partially reveal the first etching layer; implanting a first ion into the revealed first etching layer to form a first doped area; and implanting a second ion into the revealed first etching layer to form a second doped area, wherein the first doped area is independent from the second doped area is provided. 
         [0006]    Preferably, the substrate is formed by a base and a second etching layer, the second etching layer is formed on the base, and the protecting layer is formed on the second etching layer. 
         [0007]    Preferably, the method further including steps of removing the photoresist layer; and partially removing the first etching layer to reveal the protecting layer. 
         [0008]    Preferably, the method further including steps of forming an insulating layer on the first doped area and the second doped area respectively; and partially removing the protecting layer and the second etching layer. 
         [0009]    Preferably, the insulating layer is formed by an oxidation process. 
         [0010]    Preferably, the first doped area has a first width and the second doped area has a second width which is the same as that of the first width. 
         [0011]    Preferably, the first etching layer has a covered area formed under the patterned photoresist layer and a reserved area formed between the first doped area and the second doped area. 
         [0012]    Preferably, the first doped area, the second doped area, the covered area and the reserved area are formed with an identical width. 
         [0013]    Preferably, the opening has a width three times larger than that of the covered area. 
         [0014]    Preferably, the photoresist layer includes an anti-reflection coating on the first etching layer. 
         [0015]    Preferably, each of the first ion and the second ion is selected from a group consisting of a phosphate ion, an arsenic ion, an inert gas ion and a combination thereof. 
         [0016]    According to the second aspect of the present invention, a method of manufacturing a semiconductor device, including the steps of patterning a photoresist layer to partially reveal an etching layer thereunder; implanting a first ion into the revealed etching layer with a first incidence to form a first doped area; and implanting a second ion into the revealed etching layer with a second incidence to form a second doped area, wherein the first doped area is apart from the second doped area is provided. 
         [0017]    Preferably, the etching layer is formed on a protecting layer disposed on a substrate. 
         [0018]    Preferably, the first incidence is independent from the second incidence. 
         [0019]    According to the third aspect of the present invention, a method of manufacturing a semiconductor device, including the steps of patterning a photoresist layer to partially expose an etching layer thereunder; and performing a plurality of ion implantation processes each with an incidence independent from the others to form a plurality of doped areas in the etching layer independent from one another is provided. 
         [0020]    The foregoing and other features and advantages of the present invention will be more clearly understood through the following descriptions with reference to the drawings: 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0021]      FIG. 1  is a diagram illustrating a lateral profile for the initial semiconductor structure according to the present invention; 
           [0022]      FIG. 2  is a diagram illustrating a lateral profile for the patterned semiconductor structure made by a lithography process according to the present invention; 
           [0023]      FIG. 3  is a diagram illustrating a lateral profile for the doped semiconductor structure made by an ion implantation process according to the present invention; 
           [0024]      FIG. 4  is a diagram illustrating a lateral profile for the first etched semiconductor structure made by a first etching process according to the present invention; 
           [0025]      FIG. 5  is a diagram illustrating a lateral profile for the oxidized semiconductor structure made by an oxidation process according to the present invention; 
           [0026]      FIG. 6  is a diagram illustrating a lateral profile for the second etched semiconductor structure made by a second etching process according to the present invention; and 
           [0027]      FIG. 7  is a flow chart illustrating the method for improving a lithography resolution according to the present invention. 
       
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 
       [0028]    The present invention will now be described more specifically with reference to the following embodiments. It is to be noted that the following descriptions of preferred embodiments of this invention are presented herein for the aspect of illustration and description only, it is not intended to be exhaustive or to be limited to the precise form disclosed. 
         [0029]    Please refer to  FIG. 1 , which is a diagram illustrating a lateral profile for the initial semiconductor structure according to the present invention. From the bottom to the top, the initial semiconductor structure  10  disclosed in  FIG. 1  includes a base  111 , a second etching layer  112 , a protecting layer  13 , a first etching layer  14 , a bottom anti-reflective coating (BARC) layer  162  and a photoresist layer  161 . In the present semiconductor field, the base  111  is usually a silicon layer; the first etching layer  14  and the second etching layer  112  are usually polysilicon; the protecting layer  13  used for the purpose of preventing that the doped ions infiltrate into the second etching layer is usually the silicon nitride (SiN). A substrate includes the base  111  and the second etching layer  112 . 
         [0030]    Subsequently, please refer to  FIG. 2 , which is a diagram illustrating a lateral profile for the patterned semiconductor structure made by a lithography process according to the present invention. A lithography process is performed to remove parts of the BARC layer  162  and the photoresist layer  161  as shown in  FIG. 2  by etching. The patterned semiconductor structure  20  shown in  FIG. 2  includes a photoresist wall  165  consisted of the BARC layer  162  and the photoresist layer  161  and an opening  21 . The BARC layer  162  and the photoresist layer  161  are remainings after etching. The first etching layer  14  at the opening  21  is a bottom area  141  and the first etching layer  14  under the photoresist wall  165  is a covered area  142 . 
         [0031]    Subsequently, please refer to  FIG. 3 , which is a diagram illustrating a lateral profile for the doped semiconductor structure made by an ion implantation process according to the present invention. At least twice the ion implantation processes are preformed at this stage. First, a first ion implantation process is performed so as to implant a first group of ions  31  into the bottom area  141  with a first incidence a to form a first doped area  1411 , wherein the first incidence a is an angle between the incident path of the first group of ions  31  and the normal line n on the surface of the first etching layer  14 . The entry of the first group of ions  31  into the first doped area  1411  is with a certain incidence, so that some of the ions would be hampered by the photoresist wall  165  and could not be implanted into the bottom area  141  of the first etching layer  14 . Through well controlling the height of the photoresist wall  165  and the first incidence a, the first group of ions  31  could be merely implanted into a part of the first etching layer  14  for forming the first doped  1411 . Equally, a second ion implantation process is then performed so as to implant a second group of ions  32  into the bottom area  141  with a second incidence b to form a second doped area  1412 , wherein the second incidence b is an angle between the incident path of the second group of ions  32  and the normal line n on the surface of the first etching layer  14 . Each of the first and the second group of ions is one selected from a group consisting of a phosphate ion, an arsenic ion, an inert gas ion and a combination thereof. Typically, the first group of ions  31  and the second group of ions  32  could be the same kind or the different kind and the first doped area  1411  and the second doped area  1412  are not adjacent to each other and a reserved area  1413  is formed therebetween. The first doped area  1411  is independent from or apart from the second doped area  1412  and the first incidence a is independent from the second incidence b. None of the ions implanted is in the reserved area  1413 . Therefore, the doped semiconductor structure  30  in  FIG. 3  is thus formed. It is noted that a plurality of ion implantation processes, each of which has an incidence independent from the others, could be performed at this stage, so as to form a plurality of doped areas in the first etching layer  14  independent from one another. 
         [0032]    Subsequently, please refer to  FIG. 4 , which is a diagram illustrating a lateral profile for the first etched semiconductor structure made by a first etching process according to the present invention. In  FIG. 4 , the photoresist wall  165 , the covered area  142  and the reserved area  1413  of the first etching layer  14  included in the first etched semiconductor structure  40  are removed so that the first doped area  1411  and second doped area  1412  are left behind and a surface of the protecting layer  13  are thus revealed. The photoresist wall  165 , the covered area  142  and the reserved area  1413  could be removed by the conventional etching scheme or the chemical mechanical polishing (CMP) scheme. 
         [0033]    In one of the preferred embodiments to improve the lithography resolution according to the present invention, the opening  21  has a width L three times larger than the width S of the photoresist wall  165  (of the covered area  142 ). In the first ion implantation process and the second ion implantation process, Through well controlling the height H of the photoresist wall  165 , the first incidence a and the second incidence b, the dimensions of the surface width L 1  of the first doped area  1411 , the surface width L 2  of the second doped area  1412  and the surface width L 3  of the reserved area  1413  could become all the same, which is also simultaneously the same with the width S of the photoresist wall  165 . That is, after the first etching process is performed, the first doped area  1411  and the second doped area  1412  are distributed very regularly, which could substantially improve the lithography resolution for the succeeding process and broadens the applicable field thereof. 
         [0034]    Subsequently, please refer to  FIG. 5 , which is a diagram illustrating a lateral profile for the oxidized semiconductor structure made by an oxidation process according to the present invention. In  FIG. 5 , for the oxidized semiconductor structure  50 , an insulating layer  1418  is formed on the first doped area  1411  and the second doped area  1412  by a conventional oxidation process, wherein the material of the insulating layer  1418  is, for example, silicon dioxide. 
         [0035]    Subsequently, please refer to  FIG. 6 , which is a diagram illustrating a lateral profile for the second etched semiconductor structure made by a second etching process according to the present invention. A part of the protecting layer  13  and a part of the second etching layer  112  are removed via a dry etching scheme in which the insulating layer  1418  is deemed as a hard mask therein. Therefore, the second etched semiconductor structure  60  in  FIG. 6  is thus formed. 
         [0036]    Through performing the preceding processes, a pattern formed on the base  111  in  FIG. 6  finer than that original formed on the first etching layer  14  that is above the base  111  in  FIG. 2  could be available. 
         [0037]    It is unnecessary to use the same material for the first etching layer  14  and the second etching layer  112 , as long as the material adopted respectively in the doped area (the first doped area  1411  and the second doped area  1412 ) and the non-doped area (the reserved area  1413 ) have the different etching selective ratio, the material could be used in the first etching layer  14 , and as long as the material adopted respectively in the first etching layer  14  on the insulating layer  1418  and the second etching layer  112  have the different etching selective ratio, the material could be used in the second etching layer  112 . 
         [0038]    In one of the preferred embodiments to improve the lithography resolution according to the present invention, the thickness of the photoresist layer  16  is approximately 154 nm, which includes the thickness of the BARC layer  162  thereunder is approximately 44 mm, the thickness of the first etching layer  14  is approximately 15 nm, the thickness of the protecting layer  13  is approximately 3 nm and the thickness of the second etching layer  112  is approximately 95 nm. 
         [0039]    Please refer to  FIG. 7 , which is a flow chart illustrating the method for improving a lithography resolution according to the present invention. The above-mentioned processes could be summed up as follows. In  FIG. 7 , as described in the step  71 , the lithography process is first performed so as to form the patterned semiconductor structure  20  with a photoresist pattern on the first etching layer  14  wherein the photoresist pattern includes the opening  21  and the photoresist wall  165 ; subsequently, as described in step  72 , at least twice the ion implantation processes (the first and the second ion implantation processes) with a certain incidence are performed so as to form the first doped area  1411  and the second doped areas  1412  that are not adjacent to each other at the bottom of the opening  21  on the first etching layer  14  to form the doped semiconductor structure  30 ; subsequently, as described in step  73 , the first etching process is performed so as to remove the photoresist wall  165  and to partially remove the first etching layer  14 , that is to remove the first etching layer  14  except parts covered by the first and the second doped areas to form the first etched semiconductor structure  40 ; subsequently, as described in step  74 , the oxidation process is performed so as to form an insulating layer  1418  on the first doped area  1411  and the second doped areas  1412  to form the oxidized semiconductor structure  50 ; subsequently, as described in step  75 , the second etching process for which the insulating layer  1418  is used as a hard mask is performed so as to remove the parts of the protecting layer  13  and the parts of the second etching layer  112  to form the second etched semiconductor structure  60 . Finally, a finer pattern with high resolution is formed on the base  111 . 
         [0040]    While the invention has been described in terms of what are presently considered to be the most practical and preferred embodiments, it is to be understood that the invention need not to be limited to the disclosed embodiment. On the contrary, it is intended to cover various modifications and similar arrangements included within the spirit and scope of the appended claims that are to be accorded with the broadest interpretation, so as to encompass all such modifications and similar structures. According, the invention is not limited by the disclosure, but instead its scope is to be determined entirely by reference to the following claims.