Abstract:
There is described the use of substituted N-trichloromethyl thiodicarboximides in combination with N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides in vulcanizable rubber mixtures in order to improve the vulcanization characteristics and such rubber mixtures.

Description:
This is a continuation of application Ser. No. 07/032,683, filed April 1, 1987, now abandoned. 
    
    
     BACKGROUND OF THE INVENTION 
     The invention is directed to the use of substituted N-trichloromethyl thiodicarboximides in combination with N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides in vulcanizable rubber mixtures as antiscorchers with an effect which increases the cross-linking density and is also directed to such rubber mixtures. A series of vulcanization accelerators is available for the cross-linking of elastomers with sulfur, whose vulcanization characteristic is completely insufficient itself. These accelerators, even when added in a small amount, both increase the cross-linking density chemically achievable so strongly and so sharply improve the kinetics of the cross-linking that the vulcanization process can also be performed on a mass-production scale in an economical manner. 
     Even though the cross-linking of rubber mixtures can also be performed without free sulfur, e.g. with the aid of peroxides or thiurams, the invention is directed to the accelerated sulfur vulcanization and the cross-linking with N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides in accordance with formula (II) with n=4 without free sulfur. n=4 stands thereby both for tetrasulfides as well as also for mixtures of compounds according to formula II in which S n  corresponds to an average statistical chain length with n=4. 
     Mercaptans, disulfides and sulphenides based on benzothiazole are the most important accelerators of sulfur vulcanization. Corresponding compounds based on triazine which are similar in their action are described in DE-PS 16 69 954 and DE-PS 12 98 706. The same category also includes the N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)oligosulfides (n=4) according to formula II described in Schwarze U.S. Pat. application Ser. No. 32,817, filed April 1, 1987, now abandoned which, in contrast to the/above-mentioned accelerators, also cross-link without the addition of free sulfur while building up an --S--, --S--S--, --S--S x  --S-- cross-linking structure. The entire disclosure of the Schwarze U.S. application is hereby incorporated by reference. 
     The cross-linking process in accelerated sulfur vulcanization can normally be broken down into 3 phases, namely, into the incubation time of the cross-linking reaction, the cross-linking process itself, characterized by the velocity constant and the cross-linking yield, and into the overheating period. The above-named accelerators differ in their behavior in all 3 phases as a rule. 
     For reasons of processing safety of rubber mixtures, especially when the processing temperature must be raised in order to increase productivity, so-called retarders or &#34;prevulcanization inhibitors&#34; are added in order to extend the incubation time of the vulcanization reaction. In practice, preferably Santoguard® PVI (N-cyclohexylthio-phthalimide; C.D. Trivette et al., Rubber Chem. Technol. 50, 570 (1977), Monsanto, U.S. Pat. Nos. 3,427,319; 3,546,185; 3,752,824; 3,855,262) and for benzothiazolyl disulfide preferably Vulkalent® E (Bayer AG, N-phenyl-N-(trichloromethyl sulfenyl)-benzene sulfonamide, DE-OS 1,957,484) have proven to be effective agents for the delay of sulfur vulcanization with sulfenamides. 
     SUMMARY OF THE INVENTION 
     The invention has the task of improving the vulcanization characteristic of vulcanizable rubber mixtures. 
     The subject matter of the invention is the use of compounds of the general formula ##STR1## in which 
     R 9  is H R 10  is H, C 1  -C 16  alkyl, e.g., methyl, ethyl, propyl, isopropyl, butyl, sec. butyl, hexyl, octyl, decyl, hexadecyl, undecenyl or R 9  and R 10  form, together with the carbon atoms of the dicarboximide in the 3 and 4 position, a six-membered ring, which is saturated or singly or triply unsaturated, which can be substituted once or twice by a methyl group, especially tetrahydrophthalimides of the type ##STR2## with R 7 , R 8  ═H, methyl, R 5  and R 6  an endo-CH 2  bridge or an endo-O-bridge, in vulcanizable rubbers in combination with oligosulfidic compounds of the formula ##STR3## in which R&#39; is hydrogen, R 2  is hydrogen, benzyl or as defined for R 3  and R 4  where R 3 , R 4 ,═C 1  --C 8  -alkyl, e.g., methyl, ethyl, propyl, isopropyl, butyl, amyl, hexyl, preferably C 1  -C 4  -alkyl, branched or unbranched, allyl, C 3  -C 8  -cycloaklyl, e.g., cyclopentyl, cyclohexyl, the latter being unsubstituted or substituted with 1-3 methyl groups, 2-hydroxyethyl, 3-hydroxypropyl, 2-hydroxypropyl or 
     R 3  and R 4  together are C 4  -C 6  -alkylene, --(CH 2  -- CHX) 2  Y where X═CH 3 , H; Y═0 or S. 
     n=2 or 4, or a mixture of compounds according to formula (II) in which S n  corresponds to an average statistical chain length with n=4. 
     The method of preparing the pure tetrasulfides with a linear S 4  chain between the two substituted triazine groups is characterized in that an aqueous alkaline solution of the corresponding N,N&#39;-substituted 2,4-diamino-6-mercaptotriazines in a two-phase system is caused to react with an S 2  Cl 2  -solution in an inert organic solvent in which the reaction product is insoluble or very slightly soluble at temperatures between -5° C. and &lt;+20° C., preferably +10° C. An alkaline aqueous solution of the mercaptotriazine is produced with advantage which contains at least the stoichiometric amount of alkali hydroxide necessary for reaction, preferably an excess of 1-20 molar percent in relation to the mercaptotriazine added. 
     This solution is treated with a solvent in which the final product of the reaction is insoluble or slightly soluble, preferably with C 5  -C 10  alkanes, e.g., pentane, hexane, decane, or C 5  -C 8  cycloalkanes, e.g., cyclohexanes, optionally substituted with 1 to 3 methyl groups, and their mixtures. This mixture is vigorously agitated and cooled, preferably to +10° C. Now, a solution of S 2  Cl 2  in the solvent used is added drop by drop into this mixture under good cooling. S 2  C 12  is used at least in a ratio of 2 moles mercaptotriazine : 1 mole S 2  Cl 2  ; however, this ratio can also be 2 : 1.1 - 1.2, as a function of the alkali excess. 
     Under the given conditions, S 2  Cl 2  exhibits an exclusively condensing action. 
     The product formed is separated with the aid of generally known measures and dried with advantage at temperatures up to +50° C. under a vacuum (10 torr). 
     Mixtures are also used which consist of oligosulfidic compounds of the general formula ##STR4## in which R 1 , R 2 , R 3  and R 4  have the meanings given above and S n  corresponds to an average statistical chain length with n=4. 
     These mixtures of oligosulfides, also designated in the following text as disproportionates, since they are produced by the disproportioning of tetrasulfides in accordance with formula II, can be prepared in several ways. The reaction conditions should be controlled in such a manner thereby that no free sulfur is produced. 
     One method is characterized in that an isolated tetrasulfide according to formula II is heated over its melting point, preferably about 20-50° C. above. 
     In another method the tetrasulfides according to formula II are dissolved in an inert organic solvent and the disproportioning reaction is performed in a temperature range between 20° C. (allowed to stand at room temperature) and the boiling point of the solvent used. 
     A particularly elegant method consists in causing an aqueous alkaline solution of the corresponding N,N&#39;-substituted 2,4-diamino-6-mercaptotriazines in a two-phase system to react with a solution of S 2  Cl 2  in an inert organic solvent which dissolves the tetrasulfide produced. The linear tetrasulfide produced is then disproportionated subsequently at once onto the mixture of the invention. 
     Particularly suitable solvents are chlorinated hydrocarbons, e.g., CH 2  Cl 2  and CHCl 2  ; however, ethers, e.g., diethyl ether, esters, e.g., ethyl acetate, and aromatic hydrocarbons, e.g., acetone, methyl ethyl ketone, are also suitable for the disproportionation reaction in the absence of water. Otherwise, they can be used if they form a two-phase mixture with water. The reaction conditions for producing the disproportionates are otherwise identical to those for producing the pure tetrasulfides. 
     It is of no significance for the suitability of the mixture produced, to what extent the disproportionation reaction has advanced. The only thing to be observed is that no free sulfur is produced during the disproportioning. 
     It turns out that the substituted N-trichloromethyl thiodicarboximides according to formula (I,Ia) used in accordance with the invention in combination with the triazine compounds according to formula II are not only excellent antiscorchers, but also change the vulcanization characteristic at the same time in such a manner that all physical data which react to the cross-linking density, such as the maximum torque (rheometer) or the tensile moduli at 300% elongation, are raised considerably. 
     Preferably, N-trichloromethyl thiophthalimide (VZ a) and 1, 2, 3, 6-tetrahydro-N-(trichloromethyl thio)-phthalimide (VZ b) are used. 
     Other examples for the compounds in accordance with formulas (I, Ia) which can be used in accordance with the invention are: 
     N-trichloromethyl thio-succinimide (VZ c) 
     N-trichloromethyl thio-dodecylsuccinimide 
     N-trichloromethyl thio-7-oxabicyclo-(2.2.1)-hept-5-en-2.3-dicarboximide 
     N-trichloromethyl thio-5-norbornene-1,2-dicarboximide 
     These materials are known, a few of them are produced on a large scale and are used as fungicides in agriculture (Captan® and Folpet®). They are produced from the corresponding dicarboximides and perchloromethyl mercaptan=trichlorosulfenyl chloride in the presence of an acid acceptor (Chevron, U.S. Pat. Nos. 2,553,770; 2,553,771; 2,553,776; Bayer, U.S. Pat. No. 2,846,442; Zefirov and Yuref, C.A. 55,page 504). Previously, only the use of N-trichloromethyl thio-phthalimide was described in rubber mixtures in combination with sulfenamides of benzothiazole, e.g. of benzothiazolyl-cyclohexyl-sulfenamide or of benzothiazolyl-2sulfenmorpholide (SU-PS 164,670, J.J. Eitington et al.) with only a weak retarding action. 
     The N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-disulfides according to formula II are described in DE-PS 16 69 954, e.g. 
     Bis-(2-ethylamino-4-diethylamino-s-triazin-6-yl)disulfide 
     Bis-(2-ethylamino-4-di-isopropylamino-s-triazin-6-yl)-disulfide 
     Bis-(2-n-propylamino-4-diethylamino-s-triazin-6-yl)-disulfide 
     Bis-(2-ethylamino-4-di-n-butylamino-s-triazin-6-yl)-disulfide 
     Examples of N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-tetrasulfides and their disproportionates are: 
     A: Bis-(2-ethylamino-4-di-isopropylamino-s-triazin-6-yl)-tetrasulfide 
     B: Bis-2-n-butylamino-4-diethylamino-s-triazin-6-yl)-tetrasulfide 
     C: Bis-(2-isopropylamino-4-di-isopropylamino-s-triazin-6-yl)-tetrasulfide 
     D: Bis-(2-ethylamino-4-di-isobutylamino-s-triazin-6-yl)-tetrasulfide 
     E: Bis-(2-ethylamino-4-di-n-propylamino-s-triazin-6-yl)-tetrasulfide 
     F: Bis-(2-n-propylamino-4-diethylamino-s-triazin-o-yl)-tetrasulfide 
     G: Bis-(2-n-propylamino-4-di-n-propylamino-s-triazin-6-yl)-tetrasulfide 
     H: Bis-(2-n-butylamino-4-di-n-propylamino-s-triazin-6-yl)-tetrasulfide 
     I: Bis-(2-ethylamino-4-di-n-butylamino-s-triazin-6-yl)-tetrasulfide 
     K: Bis-(2-isopropylamino-4-di-isopropylamino-s-triazin-6-yl)-oligosulfide mixture 
     L: Bis-(2-cyclohexylamino-4-diethylamino-s-triazin-6-yl)-oligosulfide mixture 
     M: Bis-(2-ethylamino-4-diethylamino-s-triazin-6-yl)-oligosulfide mixture 
     N: bis-(2-ethylamino-4-diethylamino-triazin-6-yl)tetrasulfide 
     O: Bis-(2-amino-4-diethylamino-s-triazin-6-yl)-oligosulfide mixture 
     The substituted N-tricloromethyl thiodicarboximides to be used in accordance with the invention as antiscorchers with an effect which increases the cross-linking density in combination with N,N&#39;-substituted bis(2,4-diamino-s-triazin-6-yl)-sulfides according to formula (II) are suitable for the rubber mixtures known in the state of the art including natural rubber (NR), isoprene rubbers (IR), butadiene rubbers (BR), styrol-butadiene rubbers (SBR), isobutylene-isoprene rubbers (IIR), ethylene-propyleneter-polymers (EPDM), nitrile rubbers (NBR), halogen-containing rubbers and also epoxidized natural rubbers (ENR) as well as their blends. 
     According to the invention, compounds according to formula (I,Ia) are added in an amount of 0.1-5 parts and the N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-sulfides (n=4) according to formula II are added in an amount of 0.1-10 parts per 100 parts rubber. The molar ratio of triazine cross-linking agent to antiscorcher is preferably from 1 : 0.3 - 1.5, preferably 1 : 0.3 - 1.2. In this instance the mixture does not contain any free sulfur. 
     In accelerated sulfur vulcanization, the substituted N-trichloromethyl thiocarboximides according to formulas (I,Ia) are added in amounts of 0.1-5 parts, preferably 0.1-2 parts per 100 parts rubber at sulfur amounts of 0.1-10 parts, preferably 0.1-8 parts per 100 parts rubber. Molar ratios of accelerator, antiscorcher, sulfur of 1 : 0.3-1.5 : 0.5-1.5, preferably 1 : 0.3-1.2 : 0.5-1.5 are preferred. Oligosulfides according to formula II are then used in amounts of 0.1-10 parts. In order to achieve a broader range of variation of the vulcanization kinetics, it can be advantageous to add the triazine accelerators according to formula II in the form of mixtures of two or several individuals, whereby the substitution is to be performed on a molar basis in order to maintain the amounts to be used indicated above, especially the preferred molar ratios. 
     The substitution when using the triazine compounds according to formula (II) is to be performed in the same manner if the work is performed without sulfur. 
     It can be advantageous, also for kinetic reasons, to use the N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides according to formula II in admixture with conventional accelerators of the benzothiazole series and/or thiurams, e.g. N-cyclohexyl benzothiazole sulfenamide, 2-mercaptobenzothiazole, benzothiazolyl disulfide and their zinc salts and tetramethyl thiuram disulfide (see also J. van Alphen, Rubber Chemicals, 1977, pp. 1-46), the entire disclosure of which is hereby incorporated by reference and relied upon. 
     Significant vulcanization problems can be solved with these dosing guidelines without a loss of vulcanizate properties occurring. 
     N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides according to formula II can be used with advantage together with organosilanes, e.g. 
     
         [(R--O).sub.3 Si--(CH.sub.2).sub.n ]2 --S.sub.x            (III) or 
    
     
         (RO).sub.3 --Si(CH.sub.2).sub.n --SH                       (IV) 
    
     where 
     n=2,3; 
     x=2-6; 
     R=C 1  -C 6  -alkyl or cyclohexyl ##STR5## where x=2-6, preferably 3, preferably bis-(3-triethoxysilylpropyl)-tetrasulfide (Si 69, Degussa AG), namely in sulfur-free Si 69 cross-linking (DE-PS 25 36 674 and related Wolff U.S. Pat. No. 4,229,333), in sulfur vulcanization with Si 69 (DE-PS 22 55 577 and related Thurn U.S. Pat. No. 3,873,489) and likewise in the production of reversion-stable vulcanizates by means of the construction of equilibrium cure systems according to DE-PS 28 48 559 and related Wolff U.S. Pat. No. 4,517,336. The entire disclosures of the Thurn U.S. Pat. and the two Wolff U.S. Pats. are hereby incorporated by reference and relied upon. In all the instances cited, substituted N-trichloromethyl thiodicarboximides according to formula (I,Ia) function as suitable antiscorchers with an effect which increases the cross-linking density. 
     The vulcanization-retarding action of substituted N-trichloromethyl thiodicarboximides according to formula (I, Ia) also occurs when N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides according to formula (II) are used alone or in a mixture together with conventional accelerators and/or with customary sulfur donors such as, e.g., Sulfasan® (morpholine disulfide). 
     The use of substituted N-trichloromethyl thiodicarboximides as antiscorchers with an effect which increases the cross-linking density in combination with N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides according to formula (II) occurs in rubber mixtures which can contain the following as other customary mixture components: 
     Reinforcing systems, i.e. furnace blacks, channel blacks, flame blacks, thermal blacks, acetylene blacks, arc carbon blacks, CK carbon blacks etc. as well as synthetic fillers such as silicas, silicates, aluminum oxide hydrates, calcium carbonates and natural fillers like clays, chalk flints, chalks, talcs, etc., as well as silane-modified fillers and their blends in amounts of 5-300 parts per 100 parts rubber, 
     zinc oxide and stearic acid as vulcanization promoters in amounts of 0.5-10 parts per 100 parts rubber, 
     customarily used antiageing, antiozone and antifatigue agents such as, e.g., IPPD, TMQ, etc. and also waxes as antilight protective agents and their blends, 
     any softeners such as, e.g., aromatic, naphthenic, paraffinic, synthetic softeners and their blends, 
     organosilanes optionally used in the rubber industry in accordance with the state of the art, e.g., -chloropropyltrialkoxysilanes, e.g., chloropropyldiethoxysilane, vinyl trialkoxysilanes,e.g., vinyl triethoxysilane, -mercaptoalkyl trialkoxysilanes and amino alkyl trialkoxysilanes as well as their blends in an amount of 0.1-25, preferably 1-10- parts per 100 parts fillers carrying silanol groups such as silicas, silicates, clays, etc. 
     optionally dyes and processing adjuvants in a customary dose. 
     Production and vulcanization of the rubber mixtures are performed according to the known methods and under the customary conditions. 
     The area of application of the N-(trichloromethyl thio)-dicarboximides in combination with N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)sulfides in accordance with formula (I), (Ia) and (II) extends to rubber mixtures like those customarily used in tire construction, to industrial articles such as, e.g., mixtures for conveyor belts, V-belts, formed articles, hoses with and without inserts, rubber coatings for rollers, jacketings, spray profiles, freehand articles, foils, shoe soles and upper parts, cables, solid-rubber tires and their vulcanizates. 
     The production and vulcanization of the rubber mixtures are performed according to the known methods and under the customary conditions. 
     The composition can comprise, consist essentially of or consist of the stated materials and the process can comprise, consist essentially of or consist of the recited steps with such materials. 
    
    
     DETAILED DESCRIPTION 
     EXAMPLE 1 
     454 g 2-ethylamino-4-diethylamino-6-mercaptotriazine are dissolved in sodium hydroxide solution produced from 84 g NaOH+1.5 liters H 2  O. 
     The solution is put into a 4-liter 3-tube flask, then 1.5 liters light gasoline (boiling pt. 80-110° C.) are added and the mixture is cooled to 0° C. under vigorous agitation. 
     Now, a solution of 137 g S 2  Cl 2  is allowed to run for 20 min. into 100 ml gasoline, whereby care is taken that the temperature does not exceed +5° C. 
     The tetrasulfide precipitates immediately. At the end of the reaction, the matter is subsequently agitated 5 min., then filtered off by suction and washed. 
     The snow-white fine powder is dried in a vacuum/12 torr at 40-45° C. 
     Amount: 499.5 g, corresponding to 97.1% of theory, M.P. 149-150° C. 
     Analysis: bis-(2-ethylamino-4-diethylamino-s-triazin-6-yl)-tetrasulfide, gram-molecular weight 516, C 18  H 32  N 10  S 4  Calculated: C 41.9; H 6.2; N 27.1; S 24.8; Found: 41.8; 6.5; 26.8; 24.8 
     TLC and HPLC analysis show that the product contains 97.1% linear tetrasulfide. 
     EXAMPLE 2 
     56.6 g 2-ethylamino-4-di-n-butylamino-6-mercaptotriazine are dissolved in a solution of 8.8 NaOH in 250 ml water. 250 ml gasoline is added thereto. After being well-agitated, the mixture is cooled off to +5° C. Now a solution of 13.5% S 2  Cl 2  in 30 ml gasoline is allowed to run in. A white precipitate forms immediately. At the end of the reaction, a work-up in accordance with Example 1 is performed. 
     Amount: 56 g, corresponding to 89.2% of theory. 
     Analysis: C 26  H 45  N 10  S 4  (gram-molecular wt. 628) Calculated: C 49.68; H 7.64; N 22.29; S 20.38; Found: 49.59; 7.59; 22.18; 20.40 
     HPLC analysis: degree of purity &gt;96%. 
     EXAMPLE 3 
     107.6 g 2-i-propylamino-4-diisopropylamino-6-mercaptotriazine are dissolved in sodium hydroxide solution produced from 17.6 g NaOH in 600 ml H 2  O. 600 ml methylene chloride are added thereto. 
     A solution of 27 g S 2  Cl 2  is allowed to run at 0-5° C. into 50 ml CH 2  Cl 2 . At the end of the reaction, the organic phase is separated is a separatory funnel, dried and concentrated by evaporation in a vacuum. An amorphous powder is obtained; softening point: 90C. 
     Yield: 112.5 g, corresponding to 94% of theory. 
     Analysis: C 24  H 44  N 10  S 4  (gram-molecular wt. 600) Calculated: C 48; H 7.33; N 23.3; S 21.3; Found: 48.2; 7.36; 23.01; 20.95 
     EXAMPLE 4 
     45.4 g 2-ethylamino-4-diethylamino-6-mercaptotriazine is dissolved in sodium hydroxide solution prepared from 8.8 g NaOH and 200 ml water. 200 ml methylene chloride is added thereto. The mixture is stirred vigorously and cooled down to 0° C. Now, 14 g S 2  Cl 2  is dissolved in 50 ml CH 2  Cl 2  and this solution is allowed to run into the mercaptide solution. 
     The reaction product dissolves in CH 2  Cl 2 . At the end of the reaction, the phases are separated and the CH 2  Cl 2  solution is worked up. This yields an amorphous powder with a softening point of approximately 110° C. 
     Amount: 46.7 g, corresponding to 90.5% of theory. 
     Analysis: C 18  H 32  N 10  S 4  (gram-molecular wt. 516) Calculated: N 27.1; S 24.8; Found: 26.8; 24.4 
     According to TLC analysis, a mixture of 4 oligosulfides but no free sulfur is obtained. 
     EXAMPLE 5 
     50 g bis-(2-ethylamino-4-diethylamino-s-triazin-6-yl)-tetrasulfide with a degree of purity of 97.1% are placed in a round flask and heated in an oil bath for 1 hour at 60° C. When cold, the melt solidifies amorphously. According to TLC analysis, the product contains in addition to approximately 50% initial product 3 other oligosulfides. 
     EXAMPLE 6 
     70.25 g 2-cyclohexylamino-4-diethylamino-6-mercaptotriazine are dissolved in 11 g NaOH and 250 ml water. 250 ml chloroform are added thereto. A solution of 18.8 g S 2  Cl 2  is allowed to run into 30 ml CHCl 2  under vigorous agitation. At the end of the reaction, the phase is separated and the chloroform layer is worked up. 71.9 g of a white amorphous powder are obtained, corresponding to 92% of the theory. 
     Analysis: C 26  H 44  N 10  S 4  (gram-mol. wt. 624) Calculated: C 50; H 7.05; N 22.4; S 20.51; Found: 49.1; 6.90; 21.8; 20 
     According to TLC analysis, the product is composed of approximately 30% linear S 4  product and 70% oligosulfides but contains no free sulfur. 
     TEST STANDARDS 
     The physical tests were performed at room temperature according to the following standard specifications: 
     
         ______________________________________(DIN = GERMAN INDUSTRIAL STANDARD) Measured in______________________________________Tensile Moduli 300%             DIN 53504     MPaIncubation Time t DIN 53529     minScorch Time       ASTM 2084     minShore-A-Hardness  DIN 53505     Nm______________________________________ 
    
     The following names and abbreviations are used in the examples of use, the meanings of which are indicated in the following table. 
     
         ______________________________________RSS:              ribbed smoked sheet             (natural rubber)CORAX ® N 220:             carbon black, surface area             (BET) 120 m.sup.2 /g (Degussa)Naftolen ® ZD:             softener made of             hydrocarbonsVulkanox ® 4010 NA:             N-isopropyl-N&#39;-phenyl-p-             phenylene diamineVulkanox ® HS:             poly-2,2,4-trimethyl-1-2-             dihydroquinolineMesamoll ®    alkyl sulfonic acid ester             from phenol and cresolProtektor ® G 35:             antiozonant waxVulkacit ® MOZ:             benzothiazole-2-             morpholinosulfenamideVulkalent ® E N-phenyl-N-             (trichloromethyl             sulfenyl)-             benzenesulfonamidePVI:              N-cyclohexyl             thiophthalimideUltrasil ® VN 3:             preciptitated silica acid             (Degussa)Gran.             granulateV 143:            bis-(2-ethylamino-4-di-             ethylamino-s-triazin-6-             yl)-disulfideV 225:            bis-(2-isopropylamino-4-             diisopropylamino-s-             triazin-6-yl)-disulfideSulfasan ®    morpholine disulfide______________________________________ 
    
     EXAMPLE 7 
     Action of VZ materials in combination with N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides as accelerator in N 220-filled NR mixtures 
     
         __________________________________________________________________________          1   2   3   4   5   6   7__________________________________________________________________________RSS 1, ML (1 + 4) = 70 - 80          100 100 100 100 100 100 100CORAX N 220    50  50  50  50  50  50  50ZnO RS         5   5   5   5   5   5   5Stearic Acid   2   2   2   2   2   2   2Naftolen ZD    3   3   3   3   3   3   3Protektor G 35 1   1   1   1   1   1   1Vulkanox HS    1.5 1.5 1.5 1.5 1.5 1.5 1.5Vulkanox 4010 NA          2.5 2.5 2.5 2.5 2.5 2.5 2.5Vulkacit MOZ   1.43              --  --  --  --  --  --V 143          --  1.29                  1.29                      1.29                          --  --  --D              --  --  --  --  1.5 1.5 1.5VZ a           --  --  0.4 --  --  0.8 --VZ b           --  --  --  0.4 --  --  0.8Sulfur         1.5 1.5 1.5 1.5 1.5 1.5 1.5D.sub.max -D.sub.min(170° C.), Nm          8.56              8.04                  9.58                      9.62                          7.28                              8.45                                  8.53t.sub.I (170° C.), min.          4.5 3.7 4.8 4.9 2.9 4.3 4.2Cross-linking velocity          2.5 2.3 2.5 2.5 3.4 3.1 3.1(t 90%-t 10%), mint.sub.1 (130° C.), min          22.5              15.0                  24.5                      24.0                          9.5 22.0                                  21.5Vulcanizate data at 170° C.Tensile Modulus 300%          10.2              10.3                  11.5                      11.6                          10.6                              11.3                                  11.3__________________________________________________________________________ 
    
     Example 7 demonstrates that the addition of N-trichloromethyl thiophthalimides for di- and tetrasulfidic triazines results in a scorch retardation (Mixtures 2-7) which raises the scorch time to the level of sulfenamide acceleration (Mixture 1). In addition, in NR filled with carbon black, no change of the cross-linking speed can be determined, but there is an improvement of the 300% tensile moduli. 
     EXAMPLE 8 
     Comparison of VZ materials to Vulkalent E in N 220-filled NR in combination with N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides as accelerators. 
     
         __________________________________________________________________________          8   9   10  11  12  13__________________________________________________________________________RSS 1, ML (1 + 4) = 70 - 80          100 100 100 100 100 100CORAX N 220    50  50  50  50  50  50ZnO RS         5   5   5   5   5   5Stearic Acid   2   2   2   2   2   2Naftolen ZD    3   3   3   3   3   3Protektor G35  1   1   1   1   1   1Vulkanox HS    1.5 1.5 1.5 1.5 1.5 1.5Vulkanox 4010 NA          2.5 2.5 2.5 2.5 2.5 2.5Vulkacit MOZ   1.43              --  --  --  --  --N              --  1.5 1.5 1.5 1.5 1.5Vulkalent E    --  --  0.8 --  --  --VZ a           --  --  --  0.8 --  --VZ b           --  --  --  --  0.8 --VZ c           --  --  --  --  --  0.8Sulfur         1.5 0.8  0.8                      0.8 0.8 0.8t.sub.I (170° C.), min.          4.5 2.9 3.8 4.3 4.2 4.3t.sub.1 (130° C.), min          22.5              9.5 14.0                      22.0                          21.5                              20.5Vulcanizate data at 170° C.Tensile Modulus 300%          10.2              10.6                  10.7                      10.2                          10.6                              10.7__________________________________________________________________________ 
    
     The comparison of Vulkalent E (Mixture 10) to VZ materials (Mixtures 11-13) shows that the VZ materials result in a longer incubation time and a higher tensile modulus at 300% expansion. 
     EXAMPLE 9: 
     Temperature dependency of the mode of action of VZ materials in acceleration of the vulcanization with bis-(2-ethylamino-4-diethylamino-s-triazin-6-yl)-disulfide in N 220-filled NR. 
     
         ______________________________________          14      15      16______________________________________RSS 1, ML (1 + 4) = 70 - 80            100       100     100CORAX N 220      50        50      50ZnO RS           5         5       5Stearic Acid     2         2       2Naftolen ZD      3         3       3Vulkanox 4010 NA 2.5       2.5     2.5Vulkanox HS      1.5       1.5     1.5Protektor G 35   1         1       1V 143            1.29      1.29    1.29VZ a             --        0.8     --VZ b             --        --      0.8Sulfur           1.5       1.5     1.5t.sub.I min.145° C.   9.2       17.0    17.5160° C.   5.2       8.2     8.2170° C.   4.0       5.2     5.7180° C.   2.8       4.0     4.0Vulcanization velocity, min:(5 90%-t 10%)145° C.   15.9      18.9    18.2160° C.   4.1       5.4     5.2170° C.   2.0       3.0     2.6180° C.   1.3       1.6     1.6Vulcanizate data:Tensile modulus 300%, MPa145° C.   10.6      12.3    13.1170° C.   9.5       12.0    12.5Shore-A-Hardness145° C.   65        69      69170° C.   63        68      68______________________________________ 
    
     The addition of VZ materials brings about a considerable prolongation of the incubation time at processing temperatures (&lt;145° C.) without any essential decrease in the vulcanization time at higher temperatures and in each case an effective increase of the 300% tensile strength. 
     EXAMPLE 10 
     Action of VZ material on the acceleration with bis-(2-ethylamino-4-diethyl amino-s-triazin-6yl)-tetrasulfide (N) in NR filled with carbon black/silica acid. 
     
         ______________________________________          17      18      19______________________________________RSS 1, ML (1 + 4) = 70 - 80            100       100     100CORAX N 220      25        25      25Ultrasil VN 3 Gran.            25        25      25ZnO RS           5         5       5Stearic Acid     2         2       2Naftolen ZD      3         3       3Protektor G35    1         1       1Vulkanox 4010 NA 2.5       2.5     2.5Vulkanox HS      1.5       1.5     1.5Vulkacit MOZ     1.43      --      --N                --        3       3VZ a             --        --      0.8Sulfur           1.5       0.8     0.8t.sub.I (170° C.), min.            4.6       3.8     4.7t.sub.1 (130° C.), min            3.6       5.9     8.6Vulcanizate data at 170° C.Tensile Modulus 300%            3.6       5.9     8.6______________________________________ 
    
     The addition of VZ a (Mixture 19) in NR mixtures filled with N 220/silica shows a prolongation of the incubation time to the reference level (Mixture 17) and at the same time an increase of the tensile modulus 300% in comparison to Mixtures 17 and 18. 
     EXAMPLE 11 
     Action of VZ a in carbon black-filled NR accelerated with a V 143/MOZ blend. 
     
         ______________________________________          20      21      22______________________________________RSS 1, ML (1 + 4) = 70 - 80            100       100     100CORAX N 220      50        50      50ZnO RS           5         5       5Stearic Acid     2         2       2Naftolen ZD      3         3       3Protektor G35    1         1       1Vulkanox 4010 NA 2.5       2.5     2.5Vulkanox HS      1.5       1.5     1.5Vulkacit MOZ     1.43      0.72    0.72V 143                      0.75    0.75VZ a             --        --      0.4Sulfur           1.5       1.5     1.5D.sub.Max -D.sub.min,(170° C.) Nm            8.56      8.24    8.87t.sub.I (170° C.), min.            4.5       4.1     4.7t.sub.1 (130° C.), min            22.5      15.0    19.3______________________________________ 
    
     The incubation time is likewise prolonged by the addition of VZ a (Mixture 22) with the mutual usage of N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6yl)-sulfides with commercial sulfenamide accelerators (Mixture 21). 
     EXAMPLE 12 
     Action of VZ b in combination with N,N&#39;-substituted bis-(24-diamino-s-triazin-6yl)-oligosulfide/Si 69 in NR mixtures filled with carbon black/silica. 
     
         ______________________________________          23      24      25______________________________________RSS 1, ML (1 + 4) = 70 - 80            100       100     100CORAX N 220      25        25      25Ultrasil VN 3 Gran.            25        25      25Si 69            3.75      3.75    3.75ZnO RS           5         5       5Stearic Acid     2         2       2Naftolen ZD      3         3       3Protektor G35    1         1       1Vulkanox 4010 NA 2.5       2.5     2.5Vulkanox HS      1.5       1.5     1.5Vulkacit MOZ     1.43      --      --B                --        1.66    1.66VZ b             --        --      0.8Sulfur           1.5       1.5     1.5t.sub.I (170° C.), min.            4.9       4.2     5.2t.sub.I (130° C.), min.            37.5      25.4    36.6______________________________________ 
    
     As can be seen in Example 12, a scorch delay is achieved even in the presence of Si 69 in NR filled with carbon black/silica. 
     EXAMPLE 13 
     Action of VZ b in an NR mixture with sulfur donor filled with N 220 and cross-linked using D. 
     
         ______________________________________          23      24      25______________________________________RSS 1, ML (1 + 4) = 70 - 80            100       100     100CORAX N 220      50        50      50ZnO RS           5         5       5Stearic Acid     2         2       2Naftolen ZD      3         3       3Protektor G35    1         1       1Vulkanox 4010 NA 2.5       2.5     2.5Vulkanox HS      1.5       1.5     1.5Vulkacit MOZ     1.43      --      --D                --        1.76    1.76VZ b             --        --      --Sulfur           1.5       --      --Sulfasan R       --        0.7     0.7t.sub.I (170° C.), min.            4.5       3.2     4.8t.sub.I (130° C.), min.            22.5      11.5    21.0______________________________________ 
    
     Even when used in NR mixtures with sulfur donor together with N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides, the addition of VZ b results, as Mixture 28 shows, in a distinct scorch retardation to the level of the reference mixture with sulfenamide acceleration and sulfur (Mixture 26). 
     EXAMPLE 14 
     Influence of VZ a in combination with N,N&#39;substituted bis-(2,4-diamino-s-triazin-6yl)-oligosulfides in BR filled with N 330. 
     
         ______________________________________         29    30      31      32______________________________________Buna CB 10      100     100     100   100CORAX N 330     60      60      60    60Stearic Acid    2       2       2     2Naftolen ZD     15      15      15    15Protektor G 35  1       1       1     1Vulkanox 4010 NA           1.5     1.5     1.5   1.5D               1.76    1.76    --    --V 225           --      --      1.5   1.5VZ a            --      0.8     --    0.8Sulfur          1.5     1.5     1.5   1.5t.sub.I (165° C.), min.           4.3     5.7     6.8   9.7Vulcanizate data at 165° C.Tensile Modulus 300%           7.1     9.8     6.0   8.8______________________________________ 
    
     Example 14 shows the incubation time prolongation of N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6yl)-di- and tetrasulfide-accelerated, N 330-filled polybutadiene and at the same time the considerable increase in tensile modulus 300%. 
     EXAMPLE 15 
     Action of VZ a in combination with N,N&#39;substituted bis-(24,-diamino-s-triazin-6yl)-oligosulfides as accelerators in NR/BR blend. 
     
         ______________________________________          37    38     39     40   41______________________________________RSS 1, ML (1 + 4) = 70 - 80            70      70     70   70   70Buna CB 10       30      30     30   30   30CORAX N 220      50      50     50   50   50ZnO Active       5       5      5    5    5Stearic Acid     2       2      2    2    2Naftolen ZD      3       3      3    3    3Protektor G 35   1       1      1    1    1Vulkanox HS      1.5     1.5    1.5  1.5  1.5Vulkanox 4010 NA 2.5     2.5    2.5  2.5  2.5Vulkacit MOZ     1.43    --     --   --   --D                --      1.76   1.76 --   --V 225            --      --     --   1.5  1.5VZ a             --      --     0.8  --   0.8VZ b             --      --     --   0.4  --Sulfur           1.5     0.8    0.8  0.8  0.8t.sub.I (170° C.), min.            3.7     2.7    4.2  4.7  7.1t.sub.I (130° C.), min.            12.9    6.6    14.0 22.3 45.0______________________________________ 
    
     Example 15 shows that even in a blend of NR with synthetic rubber, a clear gain in scorch safety can be achieved by the addition of VZ materials. 
     EXAMPLE 16 
     Action of VZ b in combination with N,N&#39;substituted bis-(24,-diamino-s-triazin-6yl)-oligosulfides as accelerators in NBR mixtures filled with N 330. 
     
         ______________________________________        33    34       35      36______________________________________Perbunan N 3307 NS          100     100      100   100CORAX N 330    60      60       60    60ZnO Active     5       5        5     5Stearic Acid   1       1        1     1Mesamoll       10      10       10    10Paraffin solid 1       1        1     1Vulkanox HS    1.5     1.5      1.5   1.5D              1.76    1.76     --    --V 225          --      --       1.5   1.5VZ b           --      0.8      --    0.8Sulfur         1.2     1.2      1.2   1.2D.sub.max -D.sub.min,(170° C.) Nm          9.23    12.95    8.18  12.59t.sub.I (170° C.), min.          3.5     4.9      4.8   8.4Vulcanization Velocityt 90-t 10%, min.          8.2     2.7      9.4   3.1Vulcanizate dataat 170° C.Tensile Modulus 300%          14.0    17.1     11.6  15.5______________________________________ 
    
     The addition of VZ b to NBR mixtures in the presence of N,N&#39;-substituted bis-(2,4-diamino-s-triazin-6-yl)-oligosulfides makes possible an improvement of the scorch safety while increasing the vulcanization speed at the same time. A considerable increase of the tensile modulus 300% also occurs in spite of the already very high initial level. 
     The entire disclosure of German priority application P 3610811.1 is hereby incorporated by reference.