Abstract:
This invention provides a method for aqueous multicolor gravure printing which can print at a high speed without color drift, which is formed of plural printing unit processes each of which comprises a printing process, a drying process and a cooling process, wherein quantity of heat supplied in the drying process in each printing unit is removed in the cooling process to render temperature of printed web uniform in front of next printing process, and an apparatus therefor.

Description:
FIELD OF THE INVENTION  
         [0001]    This invention relates to a method for aqueous gravure printing, especially multicolor gravure printing characterized in cooling process, and an apparatus therefor.  
         BACKGROUND OF THE INVENTION  
         [0002]    Printing of packaging materials is carried out by gravure printing, offset printing, flexographic printing or the like and gravure printing is frequently used for packaging materials requiring display effect on goods, because of excellent reproducibility up to fine portions of design and gradation to produce photograph-like printing. The gravure printing comprises placing oil ink on concaves on a drum surface engraved by conventional gravure, intaglio gravure, electronic photoengraving or the like, transferring the ink to raw web, and then, blowing hot wind to evaporate solvent of the ink to dryness. The oil ink is a dispersion of pigment in a vehicle produced by dissolving a resin, such as polyurethane, acrylic resin, nitrocellulose or chlorinated polyolefin, into a solvent.  
           [0003]    Conventional solvent is a mixture of toluene (40%)-ethyl acetate (40%)-isopropyl alcohol (20%), methyl ethyl ketone (40%)-ethyl acetate (40%)-isopropyl alcohol (20%) or the like. The solid content, i.e. resin and pigment, of the oil ink is, in common, 8-10%, and in the case of white solid ink requiring shielding ability, those having a solid content up to 30% are used. In general, the temperature of hot wind is 55-60° C., and blowing volume is 30-70 m 3 /min. Under these conditions, it is possible to set a printing speed at 120-200 m/min. In the multicolor printing, the number of colors employed is 2 to 10, and the greater the number of colors is, the more the print becomes photograph-like decorative.  
           [0004]    Packaging, materials frequently used for printing are films of polyethylene terephthalate (PET), oriented polypropylene (OPP), oriented nylon (O-NY), etc., and other applicable films are single layer films of polyethylene (PE), polypropylene (PP) polystyrene (PS), polyvinyl chloride (PVC), etc., shrinkable films of PET, PP, PS, PE, PVC, etc., and stretched films of PE, PVC, etc.  
           [0005]    Recently, gravure printing is moving to aqueous process using an aqueous ink, due to the problems of the solvent in the oil ink, in noxious odor on printing work, adverse effects on the health in working atmosphere, possibility of explosion, residual solvent odor in prints, contamination of environment around factory, reduction of CO 2 , spending of solvent resources because all the solvent is volatilized in the process of printing (Japanese Patent 3249223, JP 2001-030611A, JP 2002-096448A).  
           [0006]    However, the solvent used in the aqueous ink is e.g. water (70%)-ethanol (30%) having a latent heat of vaporization of 470.7 cal/g which is great compared with the solvent of oil ink, e.g. 101.9 cal/g for toluene (40%)-ethyl acetate (40%)-isopropyl alcohol (20%) or 109.1 cal/g for methyl ethyl ketone (40%)-ethyl acetate (40%)-isopropyl alcohol (20%). That is, calories required for drying is as much as 4.3-4.6 times that of conventional oil inks. Properties of principal solvents used in gravure ink are summarized in Table 1.  
                                                                             TABLE 1                                       Vap. Latent   Vapor   Surface                       Inflammation   Heat   Pressure   Tension                   Point   (b.p.)   (20° C.)   (25° C.)   Solvility               b.p.   (closed)   (KJ/kg)   (Pa)   (mN/m)   Parameter       Solvent   M.W.   (° C.)   (° C.)   (cal/g)   (mmHg)   (dyne/cm)   (Hansen)                                Toluene   92.1   110.6   4.4   363.6   4000   27.9   8.91                       86.9   30.0   27.9       Ethyl Acetate   88.1   76.7   −7.2   369   9706   23.8   9.10                       88.2   72.8   23.8       Methyl Ethyl   72.1   79.6   −4.0   439   9493   24.0   9.27       Ketone               105.2   71.2   24.0       Isopropanol   60.1   82.3   11.7   666   4320   21.7   11.50                       159.2   32.4   21.7*       n-propanol   60.1   97.1   15.0   680   1933   23.8   11.97                       162.6   14.5   23.8*       Ethanol   46.7   78.3   16.0   833   7999   22.1   12.92                       199.2   60.0   22.1       Water   18.0   100.0   —   2456   2333   71.8   23.50                       586.9   17.5   71.8                          
 
           [0007]    A countermeasure is to raise the solid content of the aqueous ink by increasing quantity of pigment within the range where concentration of print is not changed even using a small volume of aqueous ink, this means has a limit up to the increase of 20% in the concentration of oil ink. Thus, even increasing the quantity of pigment, it is still necessary to supply 3.4-3.7 times the heat in the case of oil ink, which requires to lengthen staying time in the drying process, to increase blowing volume of hot wind, to raise the temperature of hot wind, or the like.  
           [0008]    However, to lengthen the staying time is undesirable because of lowering printing speed, and to increase blowing volume degrades energy efficiency and causes flapping of raw web by the wind. In view of heating efficiently, it is the most suitable to raise the temperature of hot wind, but it results in raising the temperature of the raw web that includes slippages between printing pitches of each color caused by elongation of the web.  
           [0009]    Temperature dependencies of the elongation (pitch elongation) of PET film, O-NY film and OPP film are shown in FIG. 3. The elongation of OPP film is the greatest, followed by O-NY film, and then PET film.  
           [0010]    The slippage of printing pitches is rectified by reading color control marks in a form of trapezoid (almost triangular) printed at an edge of raw web by a scanning head, and when the distance (20.0 mm) from the trailing end of the base (10 mm) of the trapezoid mark to the front end of the next mark is slipped with a length of 0.2 mm or more, the length of the passage up to printing is aligned by moving automatically a compensator roll slightly.  
           [0011]    However, when the elongation is great, deformation occurs caused by the elongation of the pattern printed in the previous printing unit (deformation of the pattern printed in the first printing unit is the greatest.). As a result, color drift (slippage of printing) occurs between the previous print pattern and a pattern printed thereon, and it cannot be eliminated by the compensator roll.  
           [0012]    By the way, PET film and O-NY film of which the elongation is small, can be printed at a printing speed of 120 m/min or higher at a temperature of hot wind for drying of 120° C. or higher, but OPP film, of which the elongation is great, cannot be printed due to the deformation of pattern which includes color drift (slippage of printing), although OPP film is cheap and widely used.  
         SUMMARY OF THE INVENTION  
         [0013]    An object of the invention is to provide a method of aqueous multicolor gravure printing capable of printing a film, even which is OPP film or a film having an elongation of more than OPP film, at a printing speed of 120 m/min, or more without color drift (slippage of printing) while temperature of hot wind for drying is 120° C. or higher.  
           [0014]    Another object of the invention is to provide an apparatus therefor.  
           [0015]    The inventors investigated earnestly in order to achieve the above objects, and found that, in the printing-drying-cooling processes of the printing unit for each color of the aqueous multicolor gravure printing, when 3.5 times heat quantity in the case of oil gravure printing is supplied in the drying process by raising hot wind temperature, temperature of the raw web is raised due to insufficient cooling. Accordingly, heat is gradually accumulated toward the second color printing, the third color printing, . . . to elevate temperature of the raw web gradually. As a result, elongation increases along the line (OPP-20 μm) in FIG. 3 (illustrating temperature dependency of elongation) to extend patterns (deformation) up to not allowable level, and color drift (slippage of printing) occurs.  
           [0016]    Then, the inventors further investigated in order to remove the above cause for color drift, and found that, even when hot wind temperature is raised to generate elongation, color drift problem can be solved by cooling it sufficiently in the cooling process to remove the heat quantity supplied in the printing unit. That is, when cooling web so that temperature of the web or printing of each color is almost uniformed, elongation of the web becomes almost the same on printing. Accordingly, patterns are not deformed, and color drift does not occur.  
           [0017]    The increase of the elongation with elevating temperature is due to decreasing of elastic modulus in tension with elevating temperature, and accordingly, elongation of film and elastic modulus in tension are in a relationship opposite to each other.  
           [0018]    Temperature dependencies of elastic modulus in tension are shown in FIG. 4. As to the relationship between the elongation (tension: 8 kg/800 mm width) and elastic modulus in tension at 30° C. of PET and OPP, as shown in FIGS. 3 and 4, the elongation of PET is about 0.15%, the elongation of OPP is about 0.45%, the elastic modulus in tension of PET is about 440 kgf/mm 2 , and the elastic modulus in tension of OPP is about 150 kg/f/mm 2 . Thus, the elongation ratio of OPP/PET is 0.45%/0.15%=3.0, and the elastic modulus in tension ratio of OPP/PET is 150 kgf/mm 2 /440 kgf/mm 2 =⅓, and accordingly, these factors are in a relationship opposite to each other.  
           [0019]    As explained above, even a film elongated caused by the decrease of elastic modulus in tension with elevating temperature, when the film is cooled to the original temperature in a cooling process, the elastic modulus in tension returns to original value, and the elongated film returns to the original state.  
           [0020]    In the case of OPP film (20 μm), when a pattern having a size of 5 cm is slipped by 0.2 mm or more, color drift can be recognized. Thus, the difference of elongation on printing each color can be allowed up to 0.4% (0.2/50×100). When the printing temperature of the first color (temperature of raw web on printing) is 25° C., since the elongation at 25° C. can be found about 0.3% from the full line (OPP-20 μm) in FIG. 3, the elongation allowance for not recognizing color drift can be estimated to be up to 0.7% which is obtained by adding the above 0.4% to 0.3%. The elongation of 0.7% occurs at about 43° C. which can be found in FIG. 3. Thus, it can be seen that color drift to be recognized does not occur by cooling the raw web to 43° C. or lower on each printing.  
           [0021]    Moreover, the inventors also found that, since conventional cooling is conducted to the surface to be printed, i.e. to one side, of the raw web by cooling wind and chilling roll in a moment, the cooling is insufficient due to residual heat remaining on the opposite side which spreads over by heat transfer after that. Then, they devised to apply a liquid to the opposite surface in addition to the cooling by means of cooling wind and chilling roll, and cooling by latent heat of vaporization by blowing cooling wind. They found this means is very effective.  
           [0022]    The present invention has been completed based on these findings, and provides;  
           [0023]    A method for aqueous multicolor gravure printing which is formed of plural printing unit processes each of which comprises a printing process, a drying process and a cooling process, wherein quantity of heat supplied in the drying process in each printing unit is removed in the cooling process to render temperature of printed web uniform in front of next printing process.  
           [0024]    In the method for aqueous gravure printing of the invention, since raw web is cooled so that the temperature of the raw web becomes almost the same on the printing in each printing unit, the elongation of the raw web also becomes almost the same on the printing of each color, and the differences in the elongations are almost none. Accordingly, slippage of printing do not occur. Moreover, the rate of the elongation is made small by the cooling.  
           [0025]    The apparatus for aqueous multicolor gravure printing of the invention is having plural printing units each of which comprises a printing portion, a drying portion and a cooling portion, where in the cooling portion comprises a cooling roll around which a raw web is wound with facing printed surface toward the surface of the roll, a blower blowing cooling wind on the printed surface, an applicator applying a liquid for cooling to the surface opposite to the printed surface, and another blower blowing wind on the opposite surface for accelerating vaporization of the liquid for cooling from the opposite surface.  
           [0026]    In the apparatus of the invention, the opposite surface of the raw web is cooled by the wind blown from another blower to evaporate the liquid for cooling applied by the applicator, as well as the printed surface is cooled by the cooling roll and a blower. Accordingly, the raw web is cooled efficiently. Moreover, since the liquid for cooling applied by the applicator evaporates gradually, cooling continues for a considerable period. 
       
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
       [0027]    [0027]FIG. 1 is a diagrammatic illustration of an apparatus embodying the invention, and FIG. 2 is an enlarged partial view thereof.  
         [0028]    [0028]FIG. 3 is a graph showing temperature dependency of elongation (pitch elongation) of various films.  
         [0029]    [0029]FIG. 4 is a graph showing temperature dependency of elastic modulus in tension of various films. 
     
    
       [0030]    [0030] 1  . . . Raw web  
         [0031]    [0031] 11  . . . Printed surface  
         [0032]    [0032] 12  . . . Liquid-applied surface  
         [0033]    [0033] 100  . . . Feeder  
         [0034]    [0034] 200  . . . First printing unit  
         [0035]    [0035] 210  . . . Printing portion  
         [0036]    [0036] 211  . . . Plate cylinder  
         [0037]    [0037] 212  . . . Impression cylinder  
         [0038]    [0038] 213  . . . Furnisher roll  
         [0039]    [0039] 220  . . . Drying portion  
         [0040]    [0040] 221  . . . Roller  
         [0041]    [0041] 230  . . . Cooling portion  
         [0042]    [0042] 231  . . . Cooling roll  
         [0043]    [0043] 232  . . . Cooling wind blower  
         [0044]    [0044] 233  . . . Molleton roll  
         [0045]    [0045] 234  . . . Cooling wind nozzle  
         [0046]    [0046] 300  . . . Second printing unit  
         [0047]    [0047] 400  . . . Third printing unit  
         [0048]    [0048] 500  . . . Fourth printing unit  
         [0049]    [0049] 600  . . . Fifth printing unit  
       DETAILED DESCRIPTION OF THE INVENTION  
       [0050]    In the method for aqueous multicolor gravure printing of the invention, the raw web is cooled in the cooling process so that the temperature of the web becomes uniform on printing in each printing unit process. The means for cooling the web is not especially restricted so far as the temperature of the web can be made almost the same as that in the previous printing process.  
         [0051]    The web may be cooled only from the printed surface side, but it is preferable to be cooled also from the opposite surface. By cooling the web from both sides, cooling can be conducted efficiently, and the temperature of the web can be lowered to a prescribed value without lowering printing speed in the next printing process.  
         [0052]    A cooling means of both sides of the web is to cool the printed surface by cooling wind and a cooling roll, and to cool the opposite surface by applying a liquid for cooling followed by blowing cooling wind to utilize latent heat of vaporization. By utilizing the vaporization of the liquid for cooling, cooling can be conducted efficiently through a simple structure. The cooling roll and blowing means of the cooling wind may be conventional.  
         [0053]    The liquid for cooling removes heat by the latent heat of vaporization, and is required to have a great latent heat of vaporization, to have a low boiling point and a high vapor pressure to be easily vaporized, and to have a small surface tension in order to apply it uniformly. The liquid for cooling may be a single liquid or a mixture of two or more types. For example, it may be a lower alcohol having 1 to 4 carbon atoms, such as methanol or ethanol. However, in the case of increasing latent heat of vaporization, a liquid mixture containing water as principal component is preferable, because water has a great latent heat of vaporization. A preferable liquid to be mixed with water is water-miscible and compensates vaporization ability and low surface tension which are deficient in water.  
         [0054]    Examples of the preferable liquid to be mixed with water are lower alcohols having 1 to 4 carbon atoms, esters, such as ethyl acetate, and ketones such as acetone, preferably, lower alcohols because of having great latent heat of vaporization and vapor pressure, and methanol and ethanol, especially methanol in the most preferred. Boiling point, latent heat of vaporization (evaporation), vapor pressure and surface tension of water, methanol, ethanol and ethyl acetate are summarized in Table 2.  
                                             TABLE 2                                       Item                    Latent Heat   Vap. Pressure   Surface Tension       Liquid   b.p   of Vap.   (at 20° C.)   (at 25° C.)               Water   100° C.   2456 KJ/kg   2333 Pa   71.8 mN/m               587 cal/g   17.5 mmHg   71.8 dyne/cm       Methanol   64.6   1087   13332               260   100       Ethanol   78.3   832   7999   22.1               199   60   22.1       Ethyl   76.7   368   9732   23.8       Acetate       88   73   23.8                  
 
         [0055]    Properties of the liquid mixture fall between those of water and methanol, ethanol or ethyl acetate, except for vapor pressure. Since each component evaporates separately, the vapor pressure is the sum of both components. With respect to the mixing ratio, to increase water ratio increases latent heat of vaporization but degrades vaporizability. On the other hand, when the ration of methanol, ethanol or ethyl acetate increases, although vaporizability is improved, latent heat of vaporizaation becomes small. A suitable mixing ration can be selected from the range of 10:90 to 90:10 by water:organic solvent ratio by volume, particularly 30:70 to 90:10 by considering vaporization rate and required latent heat of vaporization.  
         [0056]    The application of the liquid for cooling may be conducted by any means capable of applying it almost uniformly, such as spraying or roll coater. A preferable means is to use a molleton roll (a metal roll around which a raised cloth, such as flannel cloth, is wound), in the cloth of which the liquid for cooling immersed and is then contacted with the raw web on the cooling roll, because it can be applied uniformly with a simple apparatus.  
         [0057]    To the surface applied with the liquid for cooling, cooling wind blows to accelerate the evaporation of the liquid. That is, since vapor of the liquid for cooling is removed from the vapor phase around the surface applied with the liquid, the evaporation is accelerated. Even if the applied liquid for cooling remains in a certain degree, the remaining liquid evaporates on the subsequent traveling line to cool the web, and the evaporation is finished prior to the next printing. As a result, temperature of the web is lowered to that of the printing on the previous printing process.  
         [0058]    The more the web is cooled, the smaller the elongation is. Accordingly, the more cooling is more effective. However, in the invention, it is important to uniform the temperature of the web on printing of each color from the first color to the last color.  
         [0059]    The degree of uniformity of the temperature required in the invention is set in the range of not recognizing color drift. The inventors confirmed that when slippage between each prints becomes 0.2 mm or more, color drift is recognized. Accordingly, the degree of uniformity of the temperature (allowable temperature variation) of the web on entering each printing is decided so that elongation difference of the web between each printing becomes within 0.2 mm. Preferable slippage of printing is less than 0.15 mm, more preferably less than 0.1 mm. The slippage is the distance between the center or the same edge of a figure, such as a line. The allowable temperature variation can be set by measuring the relationship between elongation and temperature, as shown in FIG. 3, for each web.  
         [0060]    The webs applicable to the invention are OPP film, films having an elongation smaller than OPP film, such as PET film and O-NY film, of which the printing speed can be raised, films liable to be elongated more than OPP film, such as single layer films of PE, PP, PS and PVC, shrinkable films of PET, PE, PS and PVC, and stretched films of PE and PVC. The invention is particularly effective against the films liable to be elongated more than OPP film, such as single layer films of PE, PP, PS and PVC, shrinkable films of PET, PE, PS and PVC, and stretched films of PE and PVC. The thickness of the films are, in general, in the range of 5 to 100 μm, particularly 7 to 50 μm.  
         [0061]    An embodiment of the apparatus of the invention will be explained with reference to drawings.  
         [0062]    [0062]FIG. 1 is a general view illustrating diagrammatic configulation of the apparatus for aqueous multicolor gravure printing, and FIG. 2 is an enlarged partial view at the first printing unit portion.  
         [0063]    The apparatus has a feeder  100  and five printing units, i.e. the first printing unit  200  printing a first color, the second printing unit  300  printing a second color, the third printing unit  400  printing a third color, the fourth printing unit  500  printing a fourth color, and the fifth printing unit  600  printing a fifth color.  
         [0064]    The first printing unit  200  comprises a printing portion  210  where the first color is printed on the raw web  1 , a drying portion  220  where the printing web  1  is dried, and a cooling portion  230  where the dried web  1  is cooled.  
         [0065]    The printing portion  210  is provided with a plate cylinder  211 , an impression cylinder  212  and a furnisher roll  213 . The drying portion  220  is provided with many rollers  221 , . . . ,  221 .  
         [0066]    The cooling portion  230  is provided with a cooling roll  231  which contacts to cool the printed surface of the web  1 , and cooling wind blowers  232  which blow cooling wind on the printed surface  11  of the web  1  on the upstream side in the vicinity of the cooling roll  231 . A molleton roll  223  is provided in contact with the cooling roll  231 , and a liquid for cooling is incorporated into the cloth material provided on the surface of the molleton roll  233 . Further, cooling wind nozzles  234  are arranged on the exit side of the cooling roll  231  as the blower for accelerating vaporization of the liquid for cooling. The cooling wind nozzles  234  and the cooling wind blowers  232  are connected to a supply source (not illustrated), and blows cooling wind on the printed surface and the applied surface of the web  1 , respectively.  
         [0067]    The constructions of the downstream side printing units, i.e. the second printing unit  300  for the second color, the third printing unit  400  for the third color, the fourth printing unit  500  for the fourth color and the fifth printing unit  600  for the fifth color are similar to the first printing unit  200 , and each having a plate cylinder  311 ,  411 ,  511 ,  611 , an impression cylinder  312 ,  412 ,  512 ,  612 , a furnisher roll  313 ,  413 ,  513 ,  613 , a roller  321 ,  421 ,  521 ,  621 , a cooling roll  331 ,  431 ,  531 ,  631 , cooling wind blowers  332 ,  432 ,  532 ,  632 , a molleton roll  333 ,  433 ,  533 ,  633  and cooling wind nozzles  334 ,  434 ,  534 ,  634 .  
         [0068]    Using the above apparatus for aqueous multicolor gravure printing, the gravure printing is carried out by delivering the raw web  1  from the feeder  100  to the first printing unit  200 . In the first printing unit  200 , a first color (e.g. white solid) is printed on the web  1  at the printing portion  210  while pressing between the plate cylinder  211  and the compression cylinder  212 . Then, the web  1  is dried by hot air at the drying portion  220 , and delivered to the cooling portion  230 .  
         [0069]    At the cooling portion  230 , the web  1  is cooled by blowing cooling air from the cooling wind blowers  232  toward the printed surface  11 , and then, cooled from the printed surface by passing the cooling roll  231 . While passing the cooling roll  231 , since the molleton roll  233  is contacted with the web  1  with pressure, the liquid for cooling impregnated into the molleton roll  233  is applied to the opposite surface of the web  1 . Further, cooling air is blown from the cooling wind nozzles  234  to the liquid-applied surface  12  on the exit side of the cooling roll  231 . The liquid for cooling which vaporizes easily evaporates to remove heat from the web  1  by the latent heat of vaporization. By the cooling air blown from the cooling wind nozzles  234 , evaporated liquid for cooling is removed from surrounding of the web  1 , and accordingly, evaporation of the liquid cooling is accelerated.  
         [0070]    Thus, the printed surface  11  side of the web  1  is cooled mainly by the cooling wind from the cooling wind blower  232  and the cooling roll  231 , and the liquid-applied surface  12  side of the web  1  is cooled mainly by the latent heat of vaporization of the liquid for cooling, resulting in cooling the web efficiently as a whole. By the cooling, the temperature of the web  1  printed at the printing portion  210  is returned to almost the same temperature as entered therein.  
         [0071]    In the second and thereafter printing units, similar motions are repeated to add an aqueous gravure printing composed of 5 colors to the web  1  to complete gravure printing.  
         [0072]    In each printing unit of the invention, heat quantity supplied in the drying process is removed rapidly by cooling in the subsequent cooling process, and in the cooling process, the web is cooled so that the temperature of the web becomes almost the same as that on printing each color. Accordingly, even when the temperature of the web is elevated in the drying process, the temperature of the web is lowered on the next printing, difference in the elongation of the web can be made small in each printing process. Moreover, elongation itself of the web is also made small. Accordingly, even when the drying temperature is made high, slippage of printing between each color does not occur. It is particularly effective for OPP film which is liable to be elongated by heat, and films which are liable to be elongated more than OPP film, such as single layer films of PE, PP, PS and PVC, shrinkable films of PET, PE, PP, PS and PVC, and stretched films of PE and PVC.  
         [0073]    Moreover, in the invention, since the cooling portion is provided with a liquid for cooling application means for applying a liquid for cooling on the surface opposite to the printed surface and a cooling wind blowing means for blowing cooling wind on the surface to which the liquid for cooling is applied, the web can be cooled efficiently by the latent heat of vaporization of the liquid for cooling. Thus, the heat supplied at the heating portion can be removed in the printing unit, and the temperature of the web in the next printing unit can be made close to that of the previous printing process.  
       EXAMPLE  
       [0074]    Gravure rolls were used each having a 1.0 mm square-lattice-shaped pattern carved on a plate cylinder by the electroengraving of helio-gravure (200 lines, 130°), and set in a five color gravure printing machine (“FM-5S type”, Fuji Kikai Kabushiki Kaisha). Five type inks of white solid (solid content: 30% by weight), yellow (solid content: 12%), red (solid content: 12%), blue (solid content: 12%) and black (solid content: 12%) were prepared using aqueous inks (“Hydric PRP-401, Dainichi Seika Color &amp; Chemicals Manufacturing Co., Ltd., which are dispersions of pigment in an acrylic resin vehicle) by diluting with water (70% by volume) and ethanol (30%).  
         [0075]    A roll of OPP film (thickness: 20 μm, width: 1000 mm, length: 2000 m, corona treatment on one side, manufactured by Tocello Kabushiki Kaisha) was attached to the feeder  100  of the five color gravure printing machine as the raw web  1 , and layer printing of the square lattice-shaped pattern was conducted on the corona-treated surface at a printing speed of 120 m/min with a tension of 8.0 Kg/1000 mm width in the order of white solid (the first printing unit  200 ), yellow (the second printing unit  300 ), red (the third printing unit  400 ), blue (the fourth printing unit  500 ) and black (the fifth printing unit  600 ), successively.  
         [0076]    The hot wind used in the drying portion  220 ,  320 ,  420 ,  520 ,  620  was at 120° C. at 60 m 3 /min for the first printing unit  200  and at 100° C. at 60 m 3 /min for the second and later printing units  300 ,  400 ,  500 ,  600 .  
         [0077]    At the cooling portion  230 ,  330 ,  430 ,  530 ,  630 , cooling wind at 30° C. was blown from the blowers already mounted  232 ,  332 ,  432 ,  532 ,  632  toward the printed surface  11  side, and then, the web was passed the cooling roll  231 ,  331 ,  431 ,  531 ,  631  which had been also already mounted and cooled by passing cooling water at 30° C., to cool the printed surface  11 .  
         [0078]    Simultaneously, the opposite surface of the web was contacted with the molleton roll  233 ,  333 ,  433 ,  533 ,  633  of which the cloth had been impregnated with the liquid for cooling which was a mixture of water (70% by volume) and methanol (30%) to apply the liquid to the opposite surface. Subsequently, the cooling wind at 30° C. was blown from the cooling wind nozzles  234 ,  334 ,  434 ,  534 ,  634  at a blowing volume of 0.8 m 3 /min on the liquid-applied surface  12  to cool it with evaporation of the liquid.  
         [0079]    During printing, temperatures at the positions of a-g indicated in FIG. 2 were measured after 10 minutes from the start of printing to grasp the temperature behavior and to check that the temperature of the web became almost the same on printing of each color from the first color to the fifth color. The temperature was measured by using a radiation thermometer.  
         [0080]    The results are summarized in Table 3.  
                                                         TABLE 3                                       Measured Position            Printing Unit   a   b   c   d   e   f   g               1st Printing Unit    25° C.*   40° C.   34° C.   35° C.   29° C.   34° C.   43° C.       2nd Printing Unit   33° C.   47° C.   42° C.   34° C.   26° C.   35° C.   42° C.       3rd Printing Unit   34° C.   46° C.   38° C.   34° C.   25° C.   39° C.   39° C.       4th Printing Unit   33° C.   46° C.   44° C.   34° C.   25° C.   35° C.   40° C.       5th Printing Unit   33° C.   50° C.   39° C.   33° C.   24° C.   33° C.   37° C.                  
 
         [0081]    The measuring positions a through g are as indicated in FIG. 2, and details are as follows:  
         [0082]    a: Temperature of the printed surface  11  of the web on entering a next printing unit, after finishing the cooling portion of the previous printing unit (the temperature of the raw web on printing in each unit)  
         [0083]    b: Temperature of the printed surface  11  immediately after drying  
         [0084]    c: Temperature of the printed surface  11  after passing the cooling wind blower  
         [0085]    d: Surface temperature of the cooling roll  
         [0086]    e: Surface temperature of the molleton roll  
         [0087]    f: Temperature of the liquid-applied surface immediately after passing the cooling nozzles  
         [0088]    g: Temperature of the printed surface  11  after passing the cooling nozzles  
         [0089]    *: Storing temperature of the raw web (room temperature)  
         [0090]    Subsequently, the temperature behavier is explained with respect to the second printing unit as an example.  
         [0091]    After finishing the cooling portion of the first printing unit  200 , the web  1  was entered in the second printing unit  300 . At that time, the web  1  had been cooled to 33° C. at position a, and was printed at this temperature. Then, the web  1  was dried, and the temperature of the web  1  immediately after the drying portion was raised to 47° C. at the position b. At the cooling portion, the temperature of the printed surface  11  was lowered to 42° C. by blowing the cooling wind (30° C.) at the position c. The printed surface  11  was further cooled by the cooling roll  331  at 34° C., and while the liquid-applied surface  12  applied with the liquid for cooling by the molleton roll  333 , followed by blowing the cooling wind at 30° C. at 0.8 m 3 /min from the cooling wind nozzles  334 . Then, heat of the web  1  was removed by the latent heat of vaporization, and the temperature of the liquid-applied surface  12  was lowered to 35° C. at the position f. On the other hand, the temperature of the printed surface was still 42° C. at the position g, which indicates the presence of temperature gradient. However, after finishing the cooling portion, the web was entered in the third printing unit. At that time, the temperature of the printed surface  11  was lowered to 34° C. at the position a. Accordingly, it is considered that cooling further proceeded by the latent heat of vaporization of the applied liquid for cooling. Like this, it is effective to cool the printed surface  11  by the cooling wind and the cooling roll and to cool the opposite surface by applying the liquid for cooling and utilizing the latent heat of vaporization thereof, and particularly, the liquid for cooling exhibits to continue cooling by evaporation during traveling the web.  
         [0092]    The temperatures of the web on printing were almost the same from the first color to the fifth color as shown in the column a of Table 3.  
         [0093]    The layer prints of square lattice-shaped pattern printed in the order of white solid-yellow-red-blue-black were observed for a length of 2000 m by naked eyes to search the squeeze-out of color. The squeeze-out of color occurs caused by slippage of printing. As a result, it was found that the square lattice-shaped pattern was printed black in fine through the whole length, and the squeeze-out of color did not find, i.e. slippage of printing did not occur at all.