Abstract:
This invention relates to semiconductor circuit memory storage devices and more particularly to a process to develop three-dimensional stacked capacitor cells using a high dielectric constant material as a storage cell dielectric and a combination of conductively doped polysilicon and metal silicide as the capacitor plates of a storage cell for use in high-density dynamic random access memory (DRAM) arrays. The present invention teaches how to fabricate three-dimensional stacked capacitors by modifying an existing stacked capacitor fabrication process to construct the three-dimensional stacked capacitor cell incorporating a high dielectric constant material as the cell dielectric that will allow denser storage cell fabrication with minimal increases of overall memory array dimensions. A capacitance gain of 3 to 10× or more over that of a conventional 3-dimensional storage cell is gained by using a high dielectric constant material as the storage cell dielectric.

Description:
This application is a continuation of application Ser. No. 684,420 filed Apr. 12, 1991 now abandoned. 
    
    
     FIELD OF THE INVENTION 
     This invention relates to semiconductor circuit memory storage devices and more particularly to a process to develop three-dimensional stacked cell capacitors incorporating a material having a high dielectric constant for use as a storage cell dielectric with self-aligned top and bottom metal storage capacitor electrodes for use in high-density dynamic random access memory (DRAM) arrays. 
     BACKGROUND OF THE INVENTION 
     In dynamic semiconductor memory storage devices it is essential that the storage node capacitor retain an adequate charge or capacitance in spite of parasitic capacitances and noise that may be present during circuit operation. As is the case for most semiconductor integrated circuitry, circuit density is continuing to increase at a fairly constant rate. The issue of maintaining storage node capacitance is particularly important as the density of DRAM arrays continue to increase for future generations of memory devices. 
     The ability to densely pack storage cells while maintaining required storage capabilities is a crucial requirement of semiconductor manufacturing technologies if future generations of expanded memory array devices are to be successfully manufactured. 
     One method of maintaining, as well as increasing, storage node capacitance in densely packed memory devices is through the use of &#34;stacked storage cell&#34; design. With this technology, two layers of conductive material, such as polycrystalline silicon (polysilicon or poly) are deposited over an access device on a silicon wafer with a dielectric layer sandwiched between each poly layer. A cell constructed in this manner is known as a stacked capacitor cell (STC). Such a cell utilizes the space over the access device for capacitor plates, has a low soft error rate (SER) and may be used in conjunction with inter-plate insulative layers having a high dielectric constant. 
     However, it is difficult to obtain sufficient storage capacitance with a conventional STC capacitor as the storage electrode area is confined within the limits of its own cell area. Also, maintaining high dielectric breakdown characteristics between poly layers in the STC capacitor becomes a major concern once insulator thickness is appropriately scaled. 
     A paper submitted by Reza Moazzami et al., entitled &#34;A Ferroelectric DRAM Cell for High-Density NVRAM&#39;s,&#34; IEEE ELECTRONIC DEVICE LETTERS, VOL. 11, NO. 10, OCTOBER 1990, pp. 454-456, herein incorporated by reference, discusses the use of a PZT ferroelectric material as a cell dielectric in a planar capacitor. 
     As discussed on pp. 455 in section B. DRAM Mode, a PZT ferroelectric material has been used as the storage cell&#39;s dielectric film. As stated and shown in FIG. 3a, pp. 455, very little degradation was observed in the small-signal capacitance after 10 10  read/write cycles. 
     The PZT ferroelectric material has a high dielectric constant very favorable for use as a storage cell dielectric, but as discussed in this article PZT has only been used experimentally in planar storage capacitors. It is also a much electrically leakier film than nitride films that are in current use and must be deposited much thicker to reduce this undesirable current leakage. The selection of electrode materials now becomes critical when using a PZT cell dielectric. Reza et al. reports the use of platinum metal electrodes which are incompatible with silicon device manufacturing. 
     Using a high dielectric constant material as the cell dielectric presents a cell leakage problem that must be taken into consideration that is different from a conventional storage capacitor. As illustrated in FIG. 1a, a conventional storage cell using a thin dielectric, such as nitride, is depicted. I 1  represents leakage current between a capacitor&#39;s top and bottom cell plates (or top cell plate and storage node cell plate). I 2  represents leakage current between adjacent storage node cell plates. A worst case scenario for cell to cell leakage would be 0 volts on storage node 1 and Vcc volts on adjacent storage node 2 with Vcc/2 on common top plate 3. A typical planar cell dielectric is 0.01 microns thick while the storage node to storage node spacing is 1.0 microns. The conventional storage cell present leakage current I 1  as the dominant leakage that one must be concerned with as I 1  &gt;&gt;I 2  as the capacitor&#39;s top and bottom cell plates are closer to one another than are adjacent storage node cell plates. 
     Referring now to FIG. 1b, a cell (later to be developed in the present invention) using a high dielectric constant material for its cell dielectric must contain a much thicker layer of dielectric than one having a nitride cell dielectric, but due to its high dielectric breakdown characteristics at this increased thickness, leakage current I 1  becomes very small. At the same time however, if the surface area of the storage node cell plate is to be maximized, the spacing of adjacent storage node cell plates becomes less than the spacing between the two cell plates of the capacitor. However, even if the storage node to storage node distance remains fixed at 1.0 microns, there is 2× greater potential difference between adjacent storage nodes as compared to storage node to top plate. So in the case of the present invention represented in FIG. 1b, I 2  &gt;&gt;I 1  and a process must be developed (which is described in the following text) to eliminate this cell to cell leakage, I 2  while maintaining high cell capacitance and close cell to cell spacing. 
     The present invention addresses both leakage current issues by fabricating a storage cell using a high dielectric constant material combined with a conventional dielectric in a preferred embodiment or alternatively, a storage cell using only a high dielectric constant material in a second embodiment. Both embodiments modify an existing stacked capacitor fabrication process to construct a three-dimensional stacked capacitor cell that will allow denser storage cell fabrication with minimal increases of overall memory array dimensions. 
     SUMMARY OF THE INVENTION 
     The invention is directed to maximizing storage cell surface area while minimizing both a capacitor&#39;s plate to plate leakage current as well as adjacent storage node cell to cell leakage current in a high density/high volume DRAM (dynamic random access memory) fabrication process. An existing stacked capacitor fabrication process is modified to construct a three-dimensional stacked capacitor utilizing a material, possessing a high dielectric constant, as the cell dielectric and a combination of conductively doped polysilicon and metal silicide as the storage capacitor plates. Three key elements of the present invention include: 1) a polysilicon etch-back of the storage node to maximize cell capacitance, 2) the use of silicides for both cell electrodes (polysilicon is currently used with a nitride cell dielectric and platinum metal is used with a high dielectric constant cell dielectric), and 3) I 2  elimination by use of a dielectric fill process. The present invention defines a capacitor storage cell only for a DRAM process, however it will be evident to one skilled in the art to incorporate these steps into other processes requiring memory cells such as VRAMs, EPROMs or the like. 
     After a silicon wafer is prepared using conventional process steps, the present invention creates a conductive storage node structure conforming to the wafer&#39;s topology formed by two adjacent digit lines running perpendicular to and over the top of three adjacent word lines. A high dielectric constant material is used as the storage cell dielectric allowing for increased capacitance and minimal leakage current while maintaining the surface area required for a conventional 3-dimensional storage cell. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1a depicts a conventional stacked capacitor using a thin cell dielectric showing plate to plate leakage current I 1  and cell to cell leakage current I 2  ; 
     FIG. 1b depicts a stacked capacitor using a thick high dielectric constant cell dielectric showing plate to plate leakage current I 1  and cell to cell leakage current I 2  ; 
     FIG. 2 is a cross-sectional view on an in-process wafer portion taken perpendicular to word lines; 
     FIG. 3 is a cross-sectional view on an in-process wafer portion taken perpendicular to digit lines; 
     FIG. 4 is a cross-sectional view of the in-process wafer portion of FIG. 2 following a conformal oxide deposition and patterning of a storage node buried contact; 
     FIG. 5 is a cross-sectional view of the in-process wafer portion of FIG. 4 following a blanket deposition of polysilicon, polysilicon etch-back and doping; 
     FIG. 6 is a cross-sectional view of the in-process wafer portion of FIG. 5 after patterning and etching of a storage node plate; 
     FIG. 7 is a cross-sectional view of the in-process wafer portion of FIG. 6 following a photoresist strip; 
     FIG. 8 is a cross-sectional view of the in-process wafer portion of FIG. 7, following a conformal deposition of a low leakage dielectric; 
     FIG. 9 is a cross-sectional view of the in-process wafer portion of FIG. 8, following an etch-back of the conformal dielectric; 
     FIG. 10 is a cross-sectional view of the in-process wafer portion of FIG. 9, following formation of a first conformal layer of metal silicide and a selective wet chemical etch; 
     FIG. 11 is a cross-sectional view of the in-process wafer portion of FIG. 10, following depositions of a high dielectric constant material, formation of a second conformal layer of metal silicide, and a layer of conformal polysilicon, respectively; 
     FIG. 12 is a cross-sectional view of the in-process wafer portion of FIG. 5 after patterning and etching a storage node plate; 
     FIG. 13 is a cross-sectional view of the in-process wafer portion of FIG. 12 following a -photoresist strip and formation of a first conformal layer of metal silicide; 
     FIG. 14 is a cross-sectional view of the in-process wafer portion of FIG. 13, following a selective etching of the first metal silicide layer; and 
     FIG. 15 is a cross-sectional view of the in-process wafer portion of FIG. 14, following depositions of a high dielectric constant material, formation of a second conformal layer of metal silicide, and a layer of conformal polysilicon, respectively. 
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 
     A preferred embodiment of the present invention is directed to maximizing storage cell capacitance in a high density/high volume DRAM fabrication process, in a sequence shown in FIGS. 2-11. 
     A silicon wafer is prepared using conventional process steps up to the point of defining a cell array. Capacitor fabrication will now follow. 
     The capacitor of each cell will make contact with a buried contact within the cell. Each active area within the array is isolated from one another by a thick field oxide and can be arranged in interdigitated columns and non-interdigitated rows. The active areas are used to form active MOS transistors that can be doped as NMOS or PMOS type FETs depending on the desired use. 
     As shown in FIG. 2, poly 22, covered with metal silicide 23 (such as tungsten silicide) and dielectric 24 (either oxide or nitride) are patterned to serve as word lines 25. Word lines 25 are further isolated from one another as well as subsequent conductive layers by dielectric spacers 26 (also either oxide or nitride). Word lines 25 have been previously deposited over a thick layer of field oxide 27. Dielectrics 24 and 26 may be deposited by chemical vapor deposition (CVD). Active areas 21 have been appropriately doped to a desired conductivity type which penetrates into the bulk silicon wafer 20, by conventional process steps. Now the wafer is ready for digit line-formation that will run perpendicular to and over word lines 25. 
     As shown in FIG. 3, an oxide layer 31 is deposited over the entire wafer array surface followed by self aligned, buried digit line contacts patterning and etch (The buried digit line contacts cannot be seen, as this cross-sectional view does not pass through the buried contacts). Following the etching of the digit line buried contacts, polysilicon 32, covered with metal silicide 33 (such as tungsten silicide) and dielectric 34 are placed, respectively. Dielectric 34 can be either nitride or oxide and is deposited by chemical vapor deposition (CVD) which is preferred for its excellent conformity. The layers of polysilicon 32, silicide 33 and dielectric 34 are patterned and etched to serve as parallel digit lines 35. Polysilicon 32 has previously been conductively doped to electrically couple with silicide 33 to serve as the conductor for digit lines 35. Digit lines 35 run perpendicular to and over the top of word lines 25 (shown in FIG. 2) and conform to the wafer surface resulting in a waveform-like topology running in both the digit line and word line directions. A second dielectric, such as nitride or oxide is now deposited (preferably by CVD), followed by an anisotropic etch to form vertical dielectric spacers 36. 
     FIGS. 4-11 show the process steps of the preferred embodiment as seen from the cross-sectional view of FIG. 2, showing a cross-section of parallel word lines 25 to present clearer views of the present invention. Therefore, the preferred embodiment will be described from here on as seen from the word line cross-section. 
     As shown in FIG. 4, word lines 25 and their subsequent isolation layers are then covered with dielectric 41 to a preferred thickness of 500 to 2000 angstroms preferably by CVD. Dielectric 41 may be either a layer of oxide or nitride depending on the process. Following dielectric 41 deposition, a self aligned buried contact to active area 21 is located by coating the wafer surface with a photoresist. Then after applying the appropriate photomask, an anisotropic etch provides an opening for buried contact 42 thus allowing access to active area 21. 
     Up to this point, process flow has followed that of an array comprising conventional stacked capacitor cells. From this point forward, the process is unique to an array having storage capacitors developed by the present invention. 
     As shown in FIG. 5, once buried contact 42 is established a conformal polysilicon layer 51 is deposited thus making contact to active area 21. Polysilicon layer 51 is etched back to form a semi-planar layer of poly that is conductively doped by conventional methods to serve as a poly storage node cell plate which is to be patterned later in the process. Although it is preferred to deposit a thick layer of polysilicon 51, a conventional thin layer of polysilicon could be deposited to avoid the need to semi-planarize the polysilicon layer. However, a thin layer of polysilicon will create valleys in areas such as at a buried contact or between adjacent word lines. By using a thick cell dielectric (as taught later on in the preferred embodiment) placed over the thin polysilicon, the capacitance will be reduced at these valley areas, thus reducing the overall capacitance of a storage node cell. 
     As shown in FIG. 6, photoresist 61 is patterned to allow a subsequent poly etch to form a poly storage node plate 62. Edges of two adjacent storage node plates 63 and 64 (also seen in FIG. 6) result from the storage node poly etch. 
     As shown in FIG. 7, photoresist 61 (seen in FIG. 6) has been stripped leaving the surfaces of poly storage node plates 62, 63 and 64 exposed. 
     As shown in FIG. 8, a conformal dielectric layer 81 is deposited, followed by a dielectric etch leaving remnant dielectric 91 residing between poly storage node plates 62, 63 and 64, as seen in FIG. 9. Remnant dielectric 91 has added benefit of reducing storage node leakage current between neighboring storage node plates. Only storage node plate 62 is discussed from hereon as its cross-section is resembles all storage capacitors fabricated in a memory array. 
     As seen in FIG. 10, metal silicide 101 is formed by depositing and annealing a metal, such as platinum, cobalt, chromium, or titanium on top of poly storage node plate 62. Metal silicide 101 connects to poly storage node plate 62 to form a completed conductive storage node plate 102 (also a polycide storage electrode). This constitutes the present invention&#39;s first use of a polycide storage electrode. A wet chemical metal etch is performed to remove unreacted metal over the isolation regions 91 and thereby isolate adjacent storage node cell plates 
     As shown in FIG. 11, a dielectric material presenting a very high dielectric constant such as Ta 2  O 5 , Y 2  O 3 , ZrO 2  a PZT ferroelectric material (lead zirconate titanate or PbZr 0 .5 Ti 0 .5 O 3 ) is then deposited to cover conductive storage node plate 102. If PZT is selected it can be applied preferentially by a sol-gel technique known by one skilled in the art. The high dielectric constant materials mentioned (particularly PZT) are known to present dielectric constant values 100 to 300 times higher than that of generally used cell dielectrics such as Si 3  N 4 . The high dielectric material will serve as cell dielectric 111 thereby isolating storage node plate 102 from a top cell plate to be formed next. Because of the etch-back of the storage node poly 62, the cell dielectric 111 is deposited over a semi-planar storage node cell plate 102. This advantageously creates a uniform thickness of cell dielectric 111 where all regions contribute to cell capacitance thereby maximizing cell capacitance. A second metal layer 112 (such as, platinum, chromium, cobalt, chromium, or titanium) is deposited followed by deposition of another polysilicon layer 113. Metal layer 112 is then annealed and becomes metal silicide 112 that combines with polysilicon 113 and now serves as capacitor cell plate 114 which then becomes a common cell plate (or top polycide electrode) to all storage capacitors in the array. This constitutes the present invention&#39;s first use of an inverse polycide process. Conventionally the metal is deposited over the poly, but in the present invention the poly is deposited over the metal. 
     A second embodiment of the present invention is directed to maximizing storage cell capacitance in a high density/high volume DRAM fabrication process, in a sequence shown in FIGS. 12-15 in conjunction with FIGS. 1-5 that have been described previously. FIGS. 12-15 show the process steps of the second embodiment as seen from the cross-sectional view of FIG. 2, showing a cross-section of parallel word lines 25 to present clearer views of the present invention. Therefore, the preferred embodiment will be described from here on as seen from the word line cross-section. 
     Referring now to FIG. 12, photoresist 121 is patterned to allow a subsequent poly etch to form a poly storage node plate 122. 
     As shown in FIG. 13, photoresist 121 (seen in FIG. 12) has been stripped leaving the surfaces of poly storage node plate 122 exposed. Following photoresist 121 strip, metal silicide 131 is formed by depositing and then annealing a metal, such as platinum, chromium, cobalt, chromium, or titanium on top of poly storage node plate 122. A wet chemical metal etch is performed to remove unreacted metal 131 over oxide regions 41, thereby isolating adjacent storage node cell plates. 
     As shown in FIG. 14, metal silicide 131 is etched and connects to poly storage node plate 122 to form a completed conductive storage node plate 141. 
     As shown in FIG. 15, a dielectric material presenting a very high dielectric constant such as Ta 2  O 5 , Y 2  O 3 , ZrO 2  or a PZT ferroelectric material (lead zirconate titanate or PbZr 0 .5 Ti 0 .5 O 3 ) is then deposited to cover conductive storage node plate 141. If PZT is selected at can be applied preferentially by a sol-gel technique known by one skilled in the art. The high dielectric constant materials mentioned (particularly PZT) are known to present dielectric constant values 100 to 300 times higher than that of generally used cell dielectrics such as Si 3  N 4 . The high dielectric material will serve as cell dielectric 151 thereby isolating storage node plate 141 from a top cell plate to be formed next. A second metal layer 152 (such as, platinum, chromium, cobalt, chromium, or titanium) is deposited followed by deposition of another polysilicon layer 153. Metal layer 152 is then annealed and becomes metal silicide 152 that combines with polysilicon 153 and now serves as capacitor cell plate 154 which then becomes a common cell plate to all storage capacitors in the array. 
     Using a very high dielectric constant material for the cell dielectric increases the storage capability of the storage node cell without increasing the area required for cell construction. Also, by forming a metal silicide on the outer surface of the poly capacitor plates, the storage capabilities of the storage capacitor is enhanced. These important features will allow fabrication of similar cell structures for future generations of memory devices such as 64M and 256M DRAMs. 
     It is to be understood that although the present invention has been described with reference to a preferred embodiment, various modifications, known to those skilled in the art, may be made to the structures and process steps presented herein without departing from the invention as recited in the claims appended hereto.