Abstract:
A MISFET device which typically utilizes silicon dioxide as an insulating material and which becomes inoperative under ionizing radiation conditions can be made to significantly enhance its radiation survivability by introducing crystalline zinc sulfide as an insulating material. The invention may be manufactured as one of three variations. Crystalline zinc sulfide may replace silicon dioxide as the gate insulator, the field insulator, or both the gate and field insulators.

Description:
RIGHTS OF THE GOVERNMENT 
     The invention described herein may be manufactured and used by or for the Government of the United States for all governmental purposes without the payment of any royalty. 
    
    
     BACKGROUND OF THE INVENTION 
     This invention generally relates to MIS field effect devices and in particular concerns the insulating material used between discrete transistors found in such devices. 
     A MIS (metal-insulator-semiconductor) device includes a semiconductor substrate, an insulating layer on the substrate, and a gate electrode disposed on the insulating layer. The insulating layer in prior art devices is usually an oxide, and the devices are usually called MOSFETs (metal-oxide-insulator field-effect-transistors). With a MOS field-effect device, additional source and drain electrodes are disposed to either side of the gate electrode and a lateral current may be caused to flow between the source and drain electrodes through application of proper bias potential to the gate electrode. Specifically, in the &#34;enhancement&#34; mode, application of a biased potential to the gate produces a conducting layer beneath the metal oxide allowing lateral current flow between the source and drain electrodes. In the &#34;depletion&#34; mode of operation, application of a bias potential to the gate electrodes produces an insulating region between the source and drain electrodes which serves to decrease current conduction. 
     MOS devices, when exposed to ionizing radiation such as would occur in a space environment, suffer radiation damage in the form of charge trapped in the oxide and/or at the oxidesemiconductor interface and undergo various changes in the electrical characteristics thereof. The circuits in which these MOS devices are found become unstable and in some instances are actually rendered inoperative. A MOSFET device with a substantially improved useful life when subjected to a radiation environment is sorely needed. 
     Prior work in this area includes U.S. Pat. No. 3,799,813 to Danchenko which discloses a technique for radiation hardening of MOS devices by the introduction of boron into the insulating oxide. While this patent is suitable for its intended purpose, it does not provide the simplicity and degree of protection that the present invention provides, nor does it involve the use of the same insulating material. 
     SUMMARY OF THE INVENTION 
     It is therefore an object of the present invention to produce a metal oxide semiconductor device which has improved survivability when exposed in a radiation environment. 
     Another object of the invention is to correct unstable conditions of silicon dioxide when subjected to radiation within a typical MOSFET device. 
     According to the invention, silicon dioxide, the typical MOSFET insulating material, is replaced, in whole or part, with a zinc sulfide compound. Zinc sulfide has the same crystalline structure of silicon but allows greater hole mobility thereby helping to reduce the degradation normally occurring under radiation conditions. The invention may be manufactured as one of three variations. Crystalline zinc sulfide may replace silicon dioxide as the gate insulator, the field insulator, or both the gate insulator and field insulator. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a cross-sectional view of a conventional MOSFET device. 
     FIG. 2 is a cross-sectional view of an embodiment of the present invention in which zinc sulfide has been introduced. 
     FIG. 3 is a cross-sectional view of an alternate embodiment of the present invention in which zinc sulfide has been introduced. 
     FIG. 4 is a cross-sectional view of another alternate embodiment of the present invention in which zinc sulfide has been introduced. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     Referring to FIG. 1 of the appended drawing, a conventional N-channel MOSFET is shown which utilizes silicon dioxide as an insulating material. Typically, such a MOSFET device comprises a substrate 12 of semiconductor material such as silicon, a p-type silicon epitaxial layer 14 disposed on the semiconductor substrate into which n-type silicon 16 is implanted to form p-n transistor junctions. Drain and source regions, 18 and 20, respectively, are provided and affixed to the n-type silicon implant. A layer 22 of silicon dioxide (SiO 2 ) is placed over large areas of crystalline silicon between discrete transistors for use as a field insulator to insulate interconnecting metallization runs from the crystalline silicon. A layer 24 of silicon dioxide is also placed between a gate contact 26 for the transistor and a channel formed by the n-type silicon implants. This layer insulates the gate from the channel, yet allows the applied charge to form an electric field which enhances or depletes the channel as necessary. The SiO 2  gate insulator is usually much thinner than the field oxide. The problem with the use of SiO 2  for gate and field oxides is that SiO 2  is an insulator and forms an amorphous layer on top of the crystalline silicon. Ionizing radiation causes electron-hole pairs to form in the SiO 2 . The electrons are much more mobile than the holes and diffuse away rapidly. The holes move very slowly through the SiO 2  and appear as a layer of trapped charge. The trapped holes produce an electric field which alters other electric fields and changes the electrical operating characteristics of the FET. Prolonged exposure to ionizing radiation destroys the device. As the holes begin to diffuse, some of them cross the SiO 2  -Si interface and produce the little understood interface states. Interface states also cause a change in device performance and may destroy the device. One theory is that interface states are dangling bonds from the silicon into the SiO 2  caused by a hole passing across the interface. 
     Interface states and trapped charge in field oxides eventually lead to the electrical connection of adjacent devices or transistors which may adversely affect the function of the intergrated circuit. In gate oxides, trapped charge and interface states will cause shifts in the transistor threshold voltage and will eventually force it to cease normal operation. 
     Replacing the amorphous SiO 2  with crystalline material zinc sulfide allows greater hole mobility thereby helping to reduce the number of trapped holes, i.e., the quantity of trapped charge. Secondly, since the crystalline material has the same crystal structure as silicon, the problem with dangling bonds is eliminated thereby reducing the production of interface states. Therefore, zinc sulfide on silicon field effect transistors has greater radiation survivability than conventional MOSFETs. 
     Referring to FIGS. 2, 3, and 4, the embodiments of the invention are shown which are substantially similar to the conventional MOSFET of FIG. 1 but zinc sulfide has been introduced as an insulating material replacing silicon dioxide. As in FIG. 1, FIGS. 2, 3, and 4 show an N-channel MOSFET, each of which is comprised of the same basic elements as FIG. 1. Namely, the MOSFET comprises a substrate 12 of semiconductor material such as silicon, a p-type silicon epitaxial layer 14 disposed on the semiconductor substrate into which n-type silicon 16 is implanted to form p-n transistor junctions. Drain and source regions, 18 and 20, respectively, are provided and affixed to the n-type silicon implant. However, the use of SiO 2  as the insulating material has been curtailed or abandoned according to the embodiments presented in FIGS. 2, 3, and 4. The zinc sulfide on silicon MISFET devices may be manufactured as one of three variations, FIG. 2, 3, or 4, respectively. 
     FIG. 2 shows a layer of zinc sulfide 30 placed over the large areas of crystalline silicon for use as a field insulator. The conventional SiO 2  gate insulator 24 is retained according to this embodiment. 
     FIG. 3 shows a layer of zinc sulfide 32 placed between the gate contact 26 and the channel formed by the n-type silicon implants 16. The conventional SiO 2  field insulator is retained according to this embodiment. 
     FIG. 4 shows a layer of zinc sulfide 32 placed between the gate contact and the channel for use as the gate insulator and also a second layer of zinc sulfide 30 placed over the large area of crystalline silicon for use as a field insulator. With this embodiment, all of the conventional SiO 2  insulating material has been replaced with zinc sulfide material. 
     Zinc sulfide (ZnS) has a zincblende crystal structure with a lattice constant of 5.42 Angstroms. Crystalline silicon has a diamond structure with a lattice constant of 5.43086 Angstroms. There is only a 0.2% variation in the lattice spacing and crystalline ZnS will continue from crystalline silicon. 
     Silicon has a bandgap energy of 1.12 eV. ZnS has a bandgap of 3.6 eV. The ZnS acts as a semiinsulator atop the silicon and can effectively replace SiO 2  as the insulator for a properly designed transistor. The advantage of crystalline ZnS atop crystalline Si is the total dose radiation survivability. 
     The use of zinc sulfide for gate and field insulating materials should also greatly reduce the need for costly research and development of radiation hardened field oxide processes. 
     Thus, while preferred constructional features are embodied in the structure illustrated herein, it is to be understood that changes and variations may be made by the skilled in the art without departing from the spirit and scope of the invention.