Judul: Sintesis terinisiasi–mikrogelombang dan pencirian kopolimer cangkok pati sagu dengan kopolimer akrilamida dan asam 2-akrilamido-2-metilpropanasulfonat
Abstrak: Sintesis terinisiasi–mikrogelombang dan pencirian kopolimer cangkok pati sagu dengan kopolimer akrilamida dan asam 2-akrilamido-2-metilpropanasulfonat [sagu-g-poli(am-co-amps)] telah berhasil disintesis dengan metode inisiasi menggunakan mikrogelombang. Hasil sintesis berwarna putih, keras, dan higroskopis. Nisbah mol (am-amps) 7:3 memperlihatkan nisbah dan efisiensi pencangkokan tertinggi, yaitu 76% dan 84%. Keberhasilan pencangkokan dicirikan oleh spektrum yang memperlihatkan puncak serapan ulur c=o 1720–1740 cm-1 dan puncak serapan ulur n–h yang kuat dan tajam pada 1545–1560 cm-1. Puncak-puncak serapan tersebut memperlihatkan telah tercangkoknya am pada tulang punggung pati. Keberadaan gugus sulfonat dari amps dibuktikan oleh puncak serapan di 1260–1150 cm-1 untuk ulur s=o simetris dan pada 1080–1010 cm-1 untuk ulur s=o asimetris. Kenaikan kadar nitrogen memperkuat bukti bahwa am dan amps telah berhasil dicangkokkan pada pati
Keyword: akrilamida, asam 2-akrilamido-2-metilpropanasulfonat, kopolimerisasi cangkok, mikrogelombang, sagu

Judul: Modifikasi Sintesis dan Pencirian Fase Diam Kromatografi Kolom Selulosa Berbasis Serabut Ampas Sagu.
Abstrak: Grafting copolymerization of acrylamide (AAm) on cellulose derived from sago fibers (α-cellulose 78.61%) has been performed by using N,N'-methylene-bis-acrylamide (MBA) as cross-linker and ammonium peroxydisulfate as initiator. The cellulose-g-polyacrylamide copolymer products were characterized by their water absorption capacity, grafting ratio, and grafting efficiency as the initial characterizations. Further characterizations was carried out by using infrared spectroscopy, electron microscopy imaging, and X-ray diffraction techniques. The characterization results showed that the copolymers has been formed. Synthesis modification by sequential addition of AAm and MBA, and increased concentration of MBA reduced the water absorption capacity, whereas the grafting ratio and efficiency were increased. Copolymer products could be applied as a stationary phase for normal-phase column chromatography, based on the porous surface morphology as well as good resistance against n-hexane, n-pentane, and cyclohexane solvents.
Keyword: sago fibers, grafting, copolymerization, cellulose, acrylamide

Judul: Thermal Characteristics and Dynamics of Tropical Cyclone over Western North Pacific Ocean: A Case Study of Typhoon Songda (Chedeng) 2011
Abstrak: The frequent occasion of Tropical Cyclone (TC) over Western North Pacific (WNP) Ocean lies from 10˚N to 26˚N and 121˚E to 170˚E. Sources of TC development come from warm ocean temperature where latent heat is released during condensation processes and subsequently concentrated in the boundary layer. Relative humidity at 850-700 hPa is responsible to produce the most intense storm. Meanwhile, weak vertical wind shear between 850-200 hPa is one of the dynamical factors that lead to the development of TC. Pressure level of 850-200 hPa is chosen to minimize the thermodynamic effect in the lower troposphere. Typhoon Songda (Chedeng in the Philippines) or TSC lasted from May 18th to 30th, 2011 and strengthened into powerful Super Typhoon stage between May 24th and 27th. Long curving track and the exhibition of all sequences of TC life cycle, TSC is then considered as an ideal case of TC. The objective of the study with case of TSC is to investigate the role of thermal characteristics and dynamics on TC intensity. The research is carried out by using Advanced Research of Weather Research and Forecasting model (WRF ARW model) version 3.3. Two domains are employed in the model. The first domain situate from 02˚N to 40˚N and 118˚E to 149˚E and cover spatial resolution () of 33.1 km. The second domain situate from 09˚N to 27˚N and 119˚E to 132˚E with of 11 km. Timestep of the model () is 120 seconds. The model is supported by the following physical parameterization, i.e., Yonsei University Scheme (YSU) in the boundary layer, Kain-Fritsch scheme (KF) in the cumulus, and WRF Single-Moment 3-class scheme in the microphysics. Initial meteorological condition prior to the formation of the cyclone is generated using WRF ARW standard-release model. Sensitivity of the model output is obtained from a selected single-parameter change scenarios, namely, 10 % to 20 % decrease and increase of wind shear initial data at 850-200 hPa, and by 10 % to 20 % decrease of relative humidity initial data at 850-700 hPa. The result showed that the negative correlations between wind shear and intensity are found in wind shear scenarios. Wind shears of 10 ms-1 which lead to strengthening of the wind intensity in the early period of Typhoon development are found in wind shear scenarios. The effect of wind shear changes on wind intensity is statistically significant in the 20 % wind shear scenarios. During mature stage, weak wind intensity occurred when wind shear increase as given in the WRF standard-release and the 20 % decreasing scenario. Different situation is found in the 20 % increasing scenario where wind shear tend to weak and lead to strong wind intensity at this stage. Meanwhile, the reduction of moisture supply at 850-700 hPa resulting from 20 % decreasing relative humidity play a major role in the weakening of wind intensity and reduces mechanical energy of the cycle process as much as 300 J kg-1.
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