Judul: Gambaran Hasil Penyembelihan Ayam Pedaging yang Dijual di Pasar Tradisional Kabupaten Jombang
Abstrak: Penelitian ini bertujuan mengetahui ketidaksempurnaan proses penyembelihan ayam pedaging yang dijual di pasar tradisional Kabupaten Jombang. Sebanyak 450 sampel kepala beserta leher ayam pedaging yang dibeli dari 90 pedagang, berasal dari 44 pedagang di pasar 1; 22 pedagang di pasar 2 dan 24 pedagang di pasar 3. Sampel direndam menggunakan larutan formalin 10% dan dipreparir menggunakan alat bedah minor untuk mengidentifikasi saluran trakea, esofagus, dan kedua arteri carotis interna. Penelitian ini menunjukan bahwa sebanyak 168 sampel (37.3%) tidak memenuhi persyaratan penyembelihan secara halal menurut SNI No.99002 tahun 2016 tentang Pemotongan Halal pada Unggas. Ketidaksempurnaan penyembelihan yang terdapat di pasar 1 sebanyak 81 sampel (36.8%), di pasar 2 sebanyak 24 sampel (20%) serta di pasar 3 sebanyak 63 sampel (57.3%). Ketidaksempurnaan penyembelihan yang ditemukan yaitu tidak terpotongnya saluran arteri carotis interna kiri, arteri carotis interna kanan, arteri carotis interna kiri dan kanan, serta trakea dan arteri carotis interna kiri. Kasus ketidaksempurnaan penyembelihan paling banyak ditemukan yaitu tidak terpotongnya saluran arteri carotis interna kiri sebanyak 94 sampel (20.9%). Hasil pengamatan sampel dan pengambilan data kuesioner menunjukkan tingginya ketidaksempurnaan hasil penyembelihan ditemukan pada pasar yang menerapkan metode 1, yaitu metode tangan kiri memegang sayap dan kepala, tangan kanan menyembelih. Selain itu, ukuran ayam dan pelatihan juru sembelih juga mempengaruhi tingginya ketidaksempurnaan hasil penyembelihan, sehingga dapat disimpulkan ketidaksempurnaan proses penyembelihan ayam di Kabupaten Jombang dipengaruhi oleh metode penyembelihan yang digunakan, ukuran ayam dan pelatihan juru sembelih.
Keyword: ayam pedaging, pasar tradisional, penyembelihan

Judul: Overview of Broiler Chicken Slaughtering Result Sold at Tradisional Markets in Jombang.
Abstrak: This study was aimed to determine the misslaughter of the broiler chicken slaughtering process sold at traditional market of Jombang, East Java. 450 samples were obtained from 90 traders; consisting of 44 traders in market 1, 22 traders in market 2 and 24 traders in market 3. The samples fixated with 10% formalin solution and prepared using a minor surgical instruments kit to identify the trachea, esophagus, and two internal carotid artery. This study showed that 168 samples (37.3%) did not meet the requirements for halal slaughter according to SNI N0.99002 2016 about halal slaughtering in poultry. Misslaughter were found on 81 samples (36.8%) from market 1, 24 samples (20%) from market 2, and 63 samples (57.3%) from market 3. Misslaughtered samples shows unfinished cut of the left internal carotid artery, right internal carotid artery, left and right internal carotid artery, and trachea and left internal carotid artery. Most case of misslaughter found was the unfinished cut of the left internal carotid artery by 94 samples (20.9%). The results of sample observations and questionnaire data collection showed that the high imperfections of slaughter results were found on the market applying method 1, namely the method of left hand holding wings and head, right hand slaughtering. In addition, the size of the chicken and the training of the slaughterer also affect the high imperfection of slaughter results. So it can be concluded that the imperfection of the chicken slaughter process in Jombang Regency is influenced by the slaughter method used, the size of the chicken and the training of the slaughterer.
Keyword: roiler chicken, slaughtering, traditional market

Judul: Density funtional theory dalam sintesis, karakterisasi, dan prediksi aplikasi. Kasus: senyawa Zn-dialkylditiokarbamat rantai panjang
Abstrak: Coordination compounds of dialkyldithiocarbamate have broad applications, e.g. automotive lubricant additives. Coordinated long chain dialkyldithiocarbamate was studied to obtain the better anti-friction and anti-wear. Integration of computation chemistry e.g. density functional theory used to identify reaction mechanisms, to optimize geometry of structure, and to estimate properties of compounds. The aim of this study was to obtain long chain complexes Zn-dialkyldithiocarbamate, to examine their structures, and to estimate their applications using Density Functional Theory methods (DFT). Long chain Zn-dialkyldithiocarbamate was synthesized through reaction between ZnCl2, NaOH, CS2 and secondary amine during 24 hours in room condition. Secondary amine was obtained from LiAlH4 reduction of amide 2o during 24 hours in nitrogen atmospheric. Reaction of long chain amine 1o and long chain acylchloride was used to obtain amide 2o. DFT and instrumentation (FTIR and HPLC) was used to study of mechanism, structure elucidation and its application. The results showed the synthesis of Zn-dibutyldithiocarbamate, dipalmitilamide, dipalmitilamine, Zn-dipalmitildithiocarbamate yields are 90.02%, 90.91%, 47.5%, and 66.49% respectively. The ratio of intensity and wave number for Zndibutyldithiocarbamate from FTIR spectra and DFT calculations wasn’t significantly different at 95% confidence level. According to DFT calculation (B3LYP/ 6-31G*), the carbon-sulfur bonds in Zn-dibutyldithiocarbamate have an average length of 0.1683-0.1743 nm and the ligand “bite” angle S-C-S has a mean value of 116.85o. This result indicates a tetrahedral-shaped Zndibutyldithiocarbamate. Lubricant additives (anti-wear and anti-friction) properties of Zn-dialkyldithiocarbamates was estimated by chemical hardness and absolute electronegativity. Lower electronegativity value is better anti-friction, and lower chemical hardness is better anti-wear. Anti-friction ability of Zndialkyldithiocarbamate is better than Mo-dialkyldithiocarbamate, while anti-wear ability is lower than Zn-dialkiydithiophosphates. Based on electronegativity absolute value of DFT calculations, the Zn-dialkyldithiocarbamate is categorized as superlubricity that can perform in the boundary lubricant system.
Keyword: