Judul: Dimerisasi eugenol hasil isolasi dari minyak cengkeh menggunakan katalis asam padat
Abstrak: Indonesia merupakan salah satu penghasil minyak cengkeh terbesar di dunia. Pasokan minyak cengkeh Indonesia ke pasar dunia mencapai 60% kebutuhan dunia. Pada tahun 2000, dari 2.080 ton minyak cengkeh yang dipasarkan, Indonesia memasok 1.317 ton (Deptan, 2005). Minyak cengkeh merupakan minyak atsiri dengan komposisi utama golongan fenol yaitu eugenol sebesar 80%. Pemanfaatan minyak cengkeh terutama sebagai campuran dalam fragrant (pengharum) dan dalam produk-produk dan dalam produk konsumsi harian seperti parfum, produk perawatan kulit, deodoran, sabun, shampo, deterjen serta sebagaibahan intermediet dalam produksi vanilin sintetik. Sedangkan pada bidang farmasi pemanfaatannya masih kurang sehingga dilakukan penelitian untuk memberikan nilai tambah dari eugenol dengan proses derivatisasi yang dinamakan dimerisasi eugenol.
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Judul: Mempelajari pembuatan isoeugenol dari minyak daun cengkeh
Abstrak: Indonesia sebagai negara agraris berpotensi menghasilkan minyak atsiri. Ekspor minyak atsiri pada tahun 1985 1989 cenderung meningkat, dan pada tahun 1990 mencapai 2 904 ton dengan nilai USD26.69juta. Dari angka tersebut jumlah ekspor minyak daun cengkeh pada tahun yang sama tercatat 707.35 ton dengan nilaiUSD 1.66 juta (BPS, 1990). Di luar negeri minyak daun cengkeh diisolasi dan disintesis menjadi turunannya yang bernilai lebih tinggi, salah satu di antaranya adalah sintesis isoeugenol dari minyak daun cengkeh. Pengolahan lanjutan tersebut akan meningkatkan nilai tambah, memasok kebutuhan isoeugenol di dalam negeri dan sebagai komoditi ekspor non-migas. Penelitian ini bertujuan untuk mempelajari pembuatan isoeugenol dari minyak daun cengkeh, dalam rangka mendapatkan produk isoeugenol dengan rendemen dan tingkat kemurnian yang tinggi. ...
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Judul: Thermal Characteristics and Dynamics of Tropical Cyclone over Western North Pacific Ocean: A Case Study of Typhoon Songda (Chedeng) 2011
Abstrak: The frequent occasion of Tropical Cyclone (TC) over Western North Pacific (WNP) Ocean lies from 10˚N to 26˚N and 121˚E to 170˚E. Sources of TC development come from warm ocean temperature where latent heat is released during condensation processes and subsequently concentrated in the boundary layer. Relative humidity at 850-700 hPa is responsible to produce the most intense storm. Meanwhile, weak vertical wind shear between 850-200 hPa is one of the dynamical factors that lead to the development of TC. Pressure level of 850-200 hPa is chosen to minimize the thermodynamic effect in the lower troposphere. Typhoon Songda (Chedeng in the Philippines) or TSC lasted from May 18th to 30th, 2011 and strengthened into powerful Super Typhoon stage between May 24th and 27th. Long curving track and the exhibition of all sequences of TC life cycle, TSC is then considered as an ideal case of TC. The objective of the study with case of TSC is to investigate the role of thermal characteristics and dynamics on TC intensity. The research is carried out by using Advanced Research of Weather Research and Forecasting model (WRF ARW model) version 3.3. Two domains are employed in the model. The first domain situate from 02˚N to 40˚N and 118˚E to 149˚E and cover spatial resolution () of 33.1 km. The second domain situate from 09˚N to 27˚N and 119˚E to 132˚E with of 11 km. Timestep of the model () is 120 seconds. The model is supported by the following physical parameterization, i.e., Yonsei University Scheme (YSU) in the boundary layer, Kain-Fritsch scheme (KF) in the cumulus, and WRF Single-Moment 3-class scheme in the microphysics. Initial meteorological condition prior to the formation of the cyclone is generated using WRF ARW standard-release model. Sensitivity of the model output is obtained from a selected single-parameter change scenarios, namely, 10 % to 20 % decrease and increase of wind shear initial data at 850-200 hPa, and by 10 % to 20 % decrease of relative humidity initial data at 850-700 hPa. The result showed that the negative correlations between wind shear and intensity are found in wind shear scenarios. Wind shears of 10 ms-1 which lead to strengthening of the wind intensity in the early period of Typhoon development are found in wind shear scenarios. The effect of wind shear changes on wind intensity is statistically significant in the 20 % wind shear scenarios. During mature stage, weak wind intensity occurred when wind shear increase as given in the WRF standard-release and the 20 % decreasing scenario. Different situation is found in the 20 % increasing scenario where wind shear tend to weak and lead to strong wind intensity at this stage. Meanwhile, the reduction of moisture supply at 850-700 hPa resulting from 20 % decreasing relative humidity play a major role in the weakening of wind intensity and reduces mechanical energy of the cycle process as much as 300 J kg-1.
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