Judul: Kinerja Antikorosi Zink Dialkilditiofosfat Berdasarkan Studi Termodinamika dan Kinetika dengan Teknik Polarisasi Potensiodinamik
Abstrak: Zinc Dialkyldithiophosphates (ZDTP) is lubricant additives and has function as anti-friction, anti-wear, antioxidant, and anti-corrosion. ZDTP Performances as anti-corrosion is measured by potentiodynamic polarization technique. Three types of ZDTP were prepared, based on the alkyl chain length. The Measurement shows that ZDTP 8 has the highest corrosion inhibition affectivity as compared to ZDTP 4 and ZDTP 16. The inhibition affectivity of ZDTP 8 to metal Cu reaching 80% in the concentration 2% of inhibitor solution. This research result also explains the influence of alkyl chain length on the performance of ZDTP as anti-corrosion. Thermodynamic parameter verification shows corrosion spontaneity decrease by the present of inhibitor. Corrosion activation energy with present ZDTP 8 is 38.60 kJ mol-1, the value is bigger than blank activation energy namely 31.14 kJ mol-1. This phenomena shows that decreasing corrosion rate relate with increasing minimum energy of reaction.
Keyword: inhibition affectivity, kinetic, polarization, thermodynamic, ZDTP

Judul: Kinetika dan Termodinamika Korosi Logam Cu dan Inhibisinya oleh Zink (Disikloheksilditiofosfat) dengan Teknik Polarisasi Potensiodinamik
Abstrak: Zinc dialkyldithiophosphates (ZDTP) is a lubricant additives which has many functions such as anti-friction, anti-wear, antioxidants, and anti-corrosion. In this research, ZDTP type which was made is ZDTP with alkyl cyclohexyl group (ZDTPS). The yield of ZDTPS were 83.50% and 82.10%. Inhibition effectivity of zinc dicyclohexyldithiophosphate were 94.30% in concentration 3% and increase significantly in concentration 1%. The parameters of thermodynamics was measured to show the easiness of corrosion reaction occur. Themodynamics parameters of blank revealed ΔH∗ was 26.8583 kJ/mol, ΔS∗ was -150.4102 J/molK, and ΔG∗ was 72.4295 kJ/mol. Thermodynamics parameters of ZDTPS revealed ΔH∗ was 50.0563 kJ/mol, ΔS∗ was -79.9807 J/molK, and ΔG∗ was 74.2963 kJ/mol. Activation energy from the corrosion process with ZDTPS presence was 52.6509 kJ/mol. This value is bigger than energy activation of blank with the value was 29.4548 kJ/mol.
Keyword: Bogor Agricultural University (IPB), ZDTP, thermodynamic, polarization, kinetic, inhibition effectivity

Judul: Karakteristik Anatomi Skelet Kepala Buaya senyulong (Tomistoma schlegelii).
Abstrak: Buaya sepit atau senyulong (Tomistoma schlegelii) merupakan jenis buaya asli Indonesia yang berhabitat di sungai-sungai Sumatera, Kalimantan, dan juga pedalaman Sulawesi. Salah satu ciri khas buaya senyulong adalah bentuk moncong yang runcing dan sempit, namun hingga saat ini informasi mengenai struktur skelet kepala buaya senyulong sangat terbatas. Penelitian ini bertujuan untuk mempelajari karakteristik anatomi skelet kepala buaya senyulong yang dikatikan dengan fungsi dan perilakunya. Penelitian dilakukan secara eksploratif dengan melakukan pengamatan, pencatatan, dan pengambilan gambar dari skelet kepala buaya senyulong. Skelet kepala berukuran panjang 70 cm, lebar 29 cm, dan tingggi 17 cm dengan permukaan kasar pada os nasale, os frontale, os maxilla, os mandibula, os lacrimale, os jugale. Jumlah gigi pada buaya ini sebanyak 78 buah, terdiri dari 4 buah gigi premaxila, 16 buah gigi maxila, dan 19 buah gigi mandibula. Pada regio orbitalis ditemukan dua pasang fenestrae temporales yang berkembang baik. Fenestra supratemporale merupakan lubang oval yang membentang di sepanjang os parietale. Fenestra infratemporale berbentuk segitiga dan dibatasi oleh os squamosum, os postorbitale, os jugulare, dan os quadratum. Os mandibula hewan ini mempunyai symphysis mandibularis yang panjang yaitu garis yang melintang di corpus mandibulae. Secara fungsional ukuran symphysis mandibularis berkaitan dengan adaptasi hewan terhadap diet makan.
Keyword: kepala, moncong, Tomistoma schlegelii