Judul: Kajian Proses Produksi Biodiesel Melalui Transesterifikasi in situ Biji Jarak Pagar (Jatropha curcas L.) Pada Berbagai Kondisi Operasi
Abstrak: Biodiesel production is generally carried out through several stages of process. They are oil extraction, oil purification, and oil transesterification. Several steps that must be passed in the biodiesel production causing low efficiency and high energy consumption, resulting in high cost of biodiesel production. Therefore, it is necessary to develop a process that simplify the steps in biodiesel production, more efficient, low cost and low energy consumption, also be able to produce high quality of biodiesel through in situ transesterification. This study purposes to investigate on in situ transesterification of Jatropha curcas L. under various operating condition by studying the influence of temperature, stirring speed, and reaction time on the yield and quality of biodiesel. In situ transesterification of Jatropha seeds was carried out under the following process conditions : the moisture content of Jatropha seeds less than 1%, the particle size of 35 mesh, the methanol to hexane to seeds ratio of 6:1:1 (v/v/w), and the KOH concentration of 0.075 mol/L methanol. Operating conditions of in situ transesterification was varied at temperature of 40, 50, and 60ºC, reaction time of 3, 4, and 5 hours, and mechanical stirring of 700, 800, and 900 rpm. Analysis of variance showed that temperature, stirring speed, and reaction time did not significantly affected the yield and viscosity of biodiesel. Temperature, reaction time, and interactions between temperature, stirring speed, and reaction time significantly affected acid value of biodiesel. Temperature and interaction between temperature and stirring speed significantly affected saponification value and ester value of biodiesel. The experimental results showed that in situ transesterification conditions which recommended for commercial scale was at temperature of 40ºC, mechanical stirring of 700 rpm, and reaction time of 3 hours (A1B1C1). That condition was choosen because this condition used low energy than other operating condition. This was also supported by the results of statistical analysis showed that the yield and viscosity of biodiesel were not significantly different at all operating conditions, and biodiesel’s characteristics meets Indonesian Biodiesel Standard. The value of acid value, saponification value, ester value, and viscosity at A1B1C1 are 0.49 mg KOH/g, 201.36 mg KOH/g, 200.87 mg KOH/g, and 3.49 cSt.
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Judul: Transformation of jatropha seeds (Jatropha curcas L.)  into biodiesel by in situ transesterification
Abstrak: Biodiesel is defined as mono-alkyl esters from transesterification reaction of triglycerides with alkyl alcohol. In situ transesterification is a method to produce biodiesel from oil sources of material by eliminating process steps of oil extraction and refining. The purpose of this research is to study the transformation process of Jatropha seeds into biodiesel by in situ transesterification on the 10 liters scale by studying the influence of reaction time, stirring speed and ratio methanol/hexane/material on the yield and quality of biodiesel. In situ transesterification of Jatropha seeds was carried out under the following process condition: the moisture content of Jatropha seeds were less than 2%, the particles size were ± 20 mesh and KOH concentration was 0.075 mol/L methanol. Operating condition of in situ transesterification was varied at 4 and 6 hours reaction time, 200 and 600 rpm stirring speed and ratio methanol/hexane/material (v/v/w) were 3:3:1, 4:2:1 and 5:1:1. Analysis of variance showed that reaction time, stirring speed and ratio methanol/hexane/material did not significantly affected the yield, acid value, saponification value, ester value, viscosity and ash content of biodiesel. The biodiesel yield was produced between 82.54-87.57%. The best biodiesel yield on all of treatments was 87.57% with condition treatment were reaction time of 6 hours, stirring speed 600 rpm and ratio methanol/hexane/material (v/v/w) of 4:2:1. Acid value, saponification value and ester value of biodiesel were 0.20-0.26 mg KOH/g, 185.49-194.30 mg KOH/g and 185.29-194.10 mg KOH/g respectively. Viscosity of biodiesel was 3.49-6.36 cSt. The ash content of biodiesel was 0%, but the condition treatment, were reaction time of 4 hours, stirring speed of 600 rpm and ratio methanol/hexane/material (v/v/w) of 5:1:1, had ash content of 0.007%. Jatropha cakes had total volatile matter content 1.80-3.64% and extracted material content 3.94-11.42%.
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Judul: Psittacosis Sebagai Zoonosis Penting Yang Berasal Dari Burung
Abstrak: Psittacosis atau ornithosis adalah penyakit menular dari burung kepada manusia. Agens penyebab psittacosis termasuk ke dalam virus psittacosis-lymphogranuloma venereum group yang disebut Chlamydia psittaci. C. psittaci hanya dapat berkembang biak di dalam jaringan hidup tetapi peka terhadap antibiotik. Penyebaran penyakit ini sangat luas, terdapat hampir di seluruh dunia. Di Indonesia penyakit ini belum pernah di diagnosa, tetapi mengingat terdapat demikian banyaknya jenis burung maka diperkirakan psittacosis ini sudah ada. Kasus pada manusia pertamakali ditemukan oleh Ritter pada tahun 1879, di Eropa. Waktu itu dikenal sebagai pneumotyphus. Chlamydia psittaci tidak hanya sebagai penyebab infeksi pada burung, juga bisa menyebabkan infeksi pada mamalia diantaranya sapi, kerbau, kambing, domba, babi dan kucing. Pada kucing dikenal sebagai feline pneumonitis. Pada domba atau kambing mengakibatkan enzootic abortion. Pada burung, kalkun merupakan unggas paling rentan diikuti oleh burung psittacine dan burung lain di luar famili psittacidae. Virulensinyapun berbeda-beda. Yang berasal dari kalkun bervirulensi tinggi, sedangkan yang berasal dari burung merpati bisa bervirulensi tinggi bisa juga bervirulensi rendah. Penularan terjadi melalui kontak langsung maupun ti- dak langsung. Penularan melalui telur tidak terjadi. Umumnya penyakit ini memperlihatkan gejala klinis berupa deman, lesu, lemah, anorexia, kurus, diarrhea ber- warna kekuningan, discharge dari mata dan hidung, conjunc- tivitis. Gejala khas pada kalkun adalah istirahat dengan sternum sebagai dasarnya, karena adanya tekanan dari bagian perut yang sakit. Sedangkan pada manusia memperlihatkan adanya demam, kadang-kadang merasa dingin, lesu, sakit kepala yang hebat, sakit pada bagian belakang badan dan photophobia…dst
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