Judul: Optimasi Penumbuhan Apatit pada Mucoza Ampela Ayam : Hamburan Difraksi Sinar-X dan Scanning Electron Microscopy
Abstrak: Senyawa kalsium fosfat karbonat sebagai mineral tulang sintesis yang ditumbuhkan diatas permukaan mucoza ampela ayam sebagai matriks, dibuat dari campuran (NH4)2HPO4 dan (NH4)2CO3 dengan rasio molar CO3 2- : PO4 3- yang bervariasi (0.15:0.3, 0.5:1.02, 0.9:1.8) dan larutan Ca(NO3)2 dengan rasio molar Ca/P sebesar 1.67. Hamburan Difraksi Sinar-X dilakukan untuk mengidentifikasi fase serta ukuran kristal sedangkan SEM (Scanning Electron Microscopy) untuk melihat morfologi apatit karbonat yang ditumbuhkan diatas mucoza ampela ayam. Hasil presipitasi menunjukkan larutan dengan rasio molar CO3 2- dan PO4 3- = 0.15: 0.3 merupakan konsentrasi optimal untuk pertumbuhan apatit pada mucoza, dibuktikan dengan hadirnya puncak mucoza pada sampel ini. Penambahan mucoza pada konsentrasi ini juga mengakibatkan penurunan ukuran kristal. Foto SEM memperlihatkan apatit karbonat yang ditumbuhkan di mucoza ampela ayam secara umum memiliki morfologi yang menyerupai kelompok partikel tidak teratur dan gumpalan bulat-bulat kecil.
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Judul: Apatite Growth Optimation on Chicken Mucouse by Fourier Transform Infrared (FTIR) Characterization
Abstrak: Some experiment had been conducted to grow apatite from supersaturated solution of calcium phosphate ions on chicken mucouse. The calcium and phosphate ions were originated from Ca(NO3)2 and (NH4)2HPO4. Carbonate ions from (NH4)2CO3 was also used as starting solution. Experiment was carried out within about 5 hours at temperature 370 C and pH 7. Value of Ca+ : PO4 3- was 1.67, while molar ratio of CO3 2- : PO4 3- was 0.5 : 1. Molarity of molar ratio CO3 2- : PO4 3- variated approximately 0.15 : 0.30, 0.51 : 1.02, and 0.90 : 1.80. Mass of mucouse powder was constant 0.75 gram. The analysis result of Fourier Transform Infrared (FTIR) showed that the precipitation was apatite carbonate type A and B. In these experiment it was found out that the mucouse reduce the crystallinity of apatite precipitant, and the growth of apatite crystal was optimum at solution with molar ratio CO3 2- : PO4 3- about 0.15 : 0.30.
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Judul: Thermal Characteristics and Dynamics of Tropical Cyclone over Western North Pacific Ocean: A Case Study of Typhoon Songda (Chedeng) 2011
Abstrak: The frequent occasion of Tropical Cyclone (TC) over Western North Pacific (WNP) Ocean lies from 10˚N to 26˚N and 121˚E to 170˚E. Sources of TC development come from warm ocean temperature where latent heat is released during condensation processes and subsequently concentrated in the boundary layer. Relative humidity at 850-700 hPa is responsible to produce the most intense storm. Meanwhile, weak vertical wind shear between 850-200 hPa is one of the dynamical factors that lead to the development of TC. Pressure level of 850-200 hPa is chosen to minimize the thermodynamic effect in the lower troposphere. Typhoon Songda (Chedeng in the Philippines) or TSC lasted from May 18th to 30th, 2011 and strengthened into powerful Super Typhoon stage between May 24th and 27th. Long curving track and the exhibition of all sequences of TC life cycle, TSC is then considered as an ideal case of TC. The objective of the study with case of TSC is to investigate the role of thermal characteristics and dynamics on TC intensity. The research is carried out by using Advanced Research of Weather Research and Forecasting model (WRF ARW model) version 3.3. Two domains are employed in the model. The first domain situate from 02˚N to 40˚N and 118˚E to 149˚E and cover spatial resolution () of 33.1 km. The second domain situate from 09˚N to 27˚N and 119˚E to 132˚E with of 11 km. Timestep of the model () is 120 seconds. The model is supported by the following physical parameterization, i.e., Yonsei University Scheme (YSU) in the boundary layer, Kain-Fritsch scheme (KF) in the cumulus, and WRF Single-Moment 3-class scheme in the microphysics. Initial meteorological condition prior to the formation of the cyclone is generated using WRF ARW standard-release model. Sensitivity of the model output is obtained from a selected single-parameter change scenarios, namely, 10 % to 20 % decrease and increase of wind shear initial data at 850-200 hPa, and by 10 % to 20 % decrease of relative humidity initial data at 850-700 hPa. The result showed that the negative correlations between wind shear and intensity are found in wind shear scenarios. Wind shears of 10 ms-1 which lead to strengthening of the wind intensity in the early period of Typhoon development are found in wind shear scenarios. The effect of wind shear changes on wind intensity is statistically significant in the 20 % wind shear scenarios. During mature stage, weak wind intensity occurred when wind shear increase as given in the WRF standard-release and the 20 % decreasing scenario. Different situation is found in the 20 % increasing scenario where wind shear tend to weak and lead to strong wind intensity at this stage. Meanwhile, the reduction of moisture supply at 850-700 hPa resulting from 20 % decreasing relative humidity play a major role in the weakening of wind intensity and reduces mechanical energy of the cycle process as much as 300 J kg-1.
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