Judul: Dekolorasi Limbah Cair Berwarna Mengandung Orange II Oleh Penicillium sp. L2
Abstrak: Setengah dari zat warna komersial yang ada di pasaran termasuk ke dalam kelompok senyawa azo (Weber dan Adams, 1995). Kelompok pewarna ini paling banyak digunakan di industri tekstil dan kertas. Secara umum zat warna azo termasuk kedalam kelompok bah an aromatik yang sukar terdegradasi secara biologi karena adanya ikatan azo dan pada beberapa senyawa tertentu disebabkan adanya gugus sui fat pada cincin aromatiknya. Renclahnya tingkat degradabilitas ini juga disebabkan oleh sifat penguraian bakteri aerob yang sangat spesifik, yang hanya mampu menclegradasi satu senyawa azo tertentu dan kurang efisien untuk mengolah campuran warna yang umumnya dijumpai dalam air limbah industri (Cripps et aI., 1990). Sementara itu, pacla kondisi anaerobik, senyawa azo akan tereduksi menjadi aromatik amina yang bersifat toksik atau karsinogenik. Penelitian ini bertujuan untuk mengkaji kemaillpuan isolat jamul' Penicillium sp. L2 dalam mendekolorisasi dan mendegradasi Orange II pada kondisi aerobik.
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Judul: Uji Keberadaan Amina Aromatik Hasil Biodegradasi Zat Warna Azo
Abstrak: Masuknya zat warna azo ke dalam lingkungan menjadi masalah yang serius. Dalam lingkungan, zat warna azo dapat mengalami biodegradasi mengbasilkan amina aromatik. Senyawa yang tidak berwarna ini bersifat toksik, mutagenik, dan karsindgenik terhadap hewan dan man usia. Selain itu polaritas amina aromatik menyebabkan amina aromatik banyak dijumpai di perairan. Dalam penelitian dilakukan analisis amina aromatik dalam sampel Orange II yang didegradasi oleh jamur Penicillium sp L2A dan dari air limbah pabrik tekstil. Sebagai standar am ina aromatik digunakan 1- naftilamina. Amina aromatik diderivatisasi menjadi senyawa iodo turunannya melalui reaksi azotasi yang diikuti dengan reaksi substitusi. Senyawa hasil derivatisasi yang diperoleh kemudian dianalisis menggunakan kromatografi gas dengan detektor ionisasi nyala.
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Judul: Thermal Characteristics and Dynamics of Tropical Cyclone over Western North Pacific Ocean: A Case Study of Typhoon Songda (Chedeng) 2011
Abstrak: The frequent occasion of Tropical Cyclone (TC) over Western North Pacific (WNP) Ocean lies from 10˚N to 26˚N and 121˚E to 170˚E. Sources of TC development come from warm ocean temperature where latent heat is released during condensation processes and subsequently concentrated in the boundary layer. Relative humidity at 850-700 hPa is responsible to produce the most intense storm. Meanwhile, weak vertical wind shear between 850-200 hPa is one of the dynamical factors that lead to the development of TC. Pressure level of 850-200 hPa is chosen to minimize the thermodynamic effect in the lower troposphere. Typhoon Songda (Chedeng in the Philippines) or TSC lasted from May 18th to 30th, 2011 and strengthened into powerful Super Typhoon stage between May 24th and 27th. Long curving track and the exhibition of all sequences of TC life cycle, TSC is then considered as an ideal case of TC. The objective of the study with case of TSC is to investigate the role of thermal characteristics and dynamics on TC intensity. The research is carried out by using Advanced Research of Weather Research and Forecasting model (WRF ARW model) version 3.3. Two domains are employed in the model. The first domain situate from 02˚N to 40˚N and 118˚E to 149˚E and cover spatial resolution () of 33.1 km. The second domain situate from 09˚N to 27˚N and 119˚E to 132˚E with of 11 km. Timestep of the model () is 120 seconds. The model is supported by the following physical parameterization, i.e., Yonsei University Scheme (YSU) in the boundary layer, Kain-Fritsch scheme (KF) in the cumulus, and WRF Single-Moment 3-class scheme in the microphysics. Initial meteorological condition prior to the formation of the cyclone is generated using WRF ARW standard-release model. Sensitivity of the model output is obtained from a selected single-parameter change scenarios, namely, 10 % to 20 % decrease and increase of wind shear initial data at 850-200 hPa, and by 10 % to 20 % decrease of relative humidity initial data at 850-700 hPa. The result showed that the negative correlations between wind shear and intensity are found in wind shear scenarios. Wind shears of 10 ms-1 which lead to strengthening of the wind intensity in the early period of Typhoon development are found in wind shear scenarios. The effect of wind shear changes on wind intensity is statistically significant in the 20 % wind shear scenarios. During mature stage, weak wind intensity occurred when wind shear increase as given in the WRF standard-release and the 20 % decreasing scenario. Different situation is found in the 20 % increasing scenario where wind shear tend to weak and lead to strong wind intensity at this stage. Meanwhile, the reduction of moisture supply at 850-700 hPa resulting from 20 % decreasing relative humidity play a major role in the weakening of wind intensity and reduces mechanical energy of the cycle process as much as 300 J kg-1.
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