Judul: Linearitas dan Limit Deteksi Pasta Karbon Biosensor Arsen dengan Elektrode Pasta Karbon Termodifikasi Zeolit-Fe
Abstrak: Detection of arsenic using biosensor based on enzyme inhibition could be a routine alternative analysis method of aquatic environmental quality. Biosensors were fabricated from carbon paste electrode modified by zeolite-Fe with pyruvate dehydrogenase (PDH) enzyme as bioreceptor which was inhibited its activity by arsenic. Measurement results were compared to atomic absorption spectroscopy (AAS) measurement. Linearity and LOD value of both methods were compared. The results showed optimum performance of biosensor was at pH 7.00, 33 °C, and at PDH concentration of 0.0142 U/mL. The best linearity was around 97.70% in range of 2.50-20 ppb, meanwhile the best LOD achieved as low as 3.78 ppb. Biosensor’s LOD was lower compared to AAS value of LOD measured as low as 6.52 ppb. Paired data test showed that there was no significant difference between the two methods at 95% confidence level. Reproducibility of fabricated biosensor was still low, hence it needs to enhance the biosensor performance
Keyword: limit of detection, linearity, arsenic, biosensor, zeolite-Fe, carbon paste electrode

Judul: Studi Literatur Biosensor Fenol dengan Biofilm Pseudomonas fluorescens Termodifikasi pada Permukaan Screen Printed Carbon Electrode.
Abstrak: Sampel air limbah mengandung senyawa organik aromatik seperti fenol. Fenol merupakan zat polutan prioritas dan berbahaya. Metode deteksi fenol secara konvensional menggunakan alat deteksi seperti kromatografi dan spektrofotometri tidak efektif. Alternatif deteksi fenol yakni menggunakan biosensor fenol dengan metode voltametri siklik. Studi literatur ini bertujuan mengkaji mekanisme tirosinase yang tepat, mengkaji optimasi pengukuran biosensor senyawa fenol dengan biofilm P. fluorescens, mengkaji modifikasi elektrode kerja dengan penambahan supporting material, dan mengkaji hasil kinerja analitik biosensor fenol. Pembentukan biofilm P.fluorescens di permukaan SPCE akan mempermudah imobilisasi enzim tirosinase. Keberhasilan imobilisasi ditandai dengan munculnya arus reduksi dan oksidasi. Penambahan magnetit-PEG akan meningkatkan deteksi biosensor fenol sehingga menghasilkan linearitas sebesar 0,9925 dan 0,9989., Wastewater samples contain aromatic organic compounds such as phenol. Phenols are the priority and harmful pollutant substances. Conventional phenol detection methods using detection tools such as chromatography and spectrophotometry are ineffective. An alternative to phenol detection is to use phenol biosensors with the cyclic voltammetry method. This literature study aims to examine the proper mechanism of tyrosinase, review the optimization of biosensor measurements of phenol compounds with biofilm P. fluorescens, review the modification of working electrodes with the addition of supporting materials, and review the analytical performance results of phenol biosensors. The formation of P.fluorescens biofilms on the surface of the SPCE will facilitate the immobilization of the enzyme tyrosinase. The success of immobilization is characterized by the emergence of reduction and oxidation currents. The addition of magnetite-PEG will improve the detection of phenol biosensors resulting in the linearity of 0,9925 and 0,9989.
Keyword: biofilm, biosensor, phenol, Pseudomonas fluorescens, tyrosinase

Judul: Penggunaan Teorema Homeomorphy 2-Manifold dan Teorema Euler Poincare pada Torus 𝑇�� dan Simplicial Complex 𝐾��
Abstrak: Two dimensional topological spaces are said to be homeomorphic if they have the same topological invariant, where one of topological invariant used is an Euler characteristic. Homeomorphy 2-Manifold’s Theorem and Euler Poincare’s Theorem are used to distinguish two topological spaces. Homeomorphy 2-Manifold’s Theorem uses Euler characteristic to identify two dimensional topological spaces. Euler Poincare’s Theorem is an alternative way to find Euler characteristic with Betti number, which is topological invariant as well. The objective of this paper is to investigate the homeomorphism of torus 𝑇����� and simplicial complex 𝐾�����. Topological space torus and simplicial complex 𝐾����� have the same Euler characteristic, which is two. Based on Homeomorphy 2-Manifold’s Theorem topological space torus 𝑇����� and simplicial complex 𝐾����� is homeomorphic.
Keyword: simplicial, torus, Euler, homeomorphism, topology