Judul: Sintesis nanopartikel Cu2ZnSnS4 menggunakan teknik hidrotermal
Abstrak: Nanopartikel Cu2ZnSnS4 (CZTS) merupakan semikonduktor yang berpotensi sebagai fotokatalis untuk reaksi fotodegradasi zat pewarna. Semikonduktor ini memiliki sela pita yang jauh lebih kecil dibandingkan dengan semikonduktor TiO2, sehingga memungkinkan dapat berkerja hanya dengan paparan sinar matahari. Nanopartikel Cu2ZnSnS4 telah berhasil disintesis menggunakan teknik hidrotermal dengan suhu 200 oC selama 24 jam. Larutan Cu2ZnSnS4 dinetralkan menggunakan amonium hidroksida dan dialiri gas N2 sebelum proses hidrotermal. Hasil analisis mikroskop elektron pemayaran menunjukkan nanopartikel Cu2ZnSnS4 mengalami aglomerasi karena memiliki ukuran partikel yang besar. Hasil analisis difraktogram sinar-X menunjukkan bahwa Cu2ZnSnS4 yang dihasilkan memiliki struktur kesterit dengan senyawa fase sekunder yang terbentuk adalah CuS, ZnS, dan Cu2SnS3. Hasil uji fotodegradasi menunjukkan bahwa senyawa hasil sintesis memiliki kemampuan degradasi dibawah sinar matahari lebih baik dibandingkan dengan TiO2. Namun, pada paparan sinar UV, TiO2 mendegradasi biru metilena lebih baik daripada senyawa hasil sintesis. Kapasitas adsorbsi terhadap biru metilena sebesar 2.6780 mg/g menunjukkan bahwa senyawa hasil sintesis tidak mampu mengadsorpsi dengan baik, sehingga disimpulkan bahwa hilangnya biru metilena dari larutan disebabkan oleh fotodegradasi, bukan oleh adsorpsi
Keyword: band gap, Cu2ZnSnS4, kesterite, photocatalyst, semiconductor

Judul: Sintesis Hidrotermal Nanopartikel ZnO Berbantuan Pektin dan Aplikasinya sebagai Fotokatalis Penguraian Biru Metilena.
Abstrak: Seiring berkembangnya dunia industri, khususnya industri tekstil yang tidak diimbangi dengan teknologi pengolahan limbah secara tepat, dapat menurunkan kualitas lingkungan. Penggunaan pewarna tekstil sintetik menimbulkan masalah, yakni limbah yang dihasilkan masih berwarna dan sulit terdegradasi. Limbah pewarna tekstil harus diolah terlebih dahulu sebelum dibuang ke perairan umum. Lewat fotokatalis ZnO, model polutan biru metilena didegradasi dengan meningkatkan aktivitas fotokatalitik; berbagai metode sudah dikembangkan untuk memodifikasi morfologi, ukuran, dan pertumbuhan kristal ZnO. Sifat nanopartikel seperti morfologi dan ukuran dapat dikendalikan dengan menyesuaikan pH reaksi, kecepatan penambahan NaOH, penambahan capping agent, dan kalsinasi. Semakin tinggi kekuatan pH dan kalsinasi, aktivitas fotokatalisnya semakin baik. Perbandingan ukuran partikel NP-ZnO dapat dilihat pada aktivitas fotokatalis. Ukuran NP-ZnO yang semakin kecil menghasilkan aktivitas fotokatalis yang semakin besar. Urutan aktivitas fotokatalis tertinggi sampai terendah ialah ZnO pH 13 kalsinasi, ZnO pH 13, ZnO pH 10 kalsinasi, dan ZnO pH 10.
Keyword: capping agent, fotokatalis, kalsinasi, nanopartikel ZnO, pH

Judul: Morphofunctional Characteristic of the Shoulder and Upper Arm Muscles of The Bornean Orangutan (Pongo pygmaeus)
Abstrak: Orangutans are arboreal primates that have similarities to gorillas and chimpanzees from both anatomical and physiological aspects, although there are distinct behaviors that allow for differentiation in the structure of the locomotor apparatus. This research aims to study the anatomy of the muscles of the shoulders and upper-arm of the Bornean orangutan associated with the type of locomotion and daily behavior. This study was conducted by observing the morphology of the shoulders and upper-arms muscles and watching their behaviors through video observations. The results showed that the rotator cuff muscles in orangutans were relatively thick resulted in well-fixed shoulders. Musculus rhomboideus occipitalis is only observed in orangutans to facilitate them during arboreal activities such as brachiation. The external trunk muscle in orangutans is found to be relatively large compared to chimpanzees and gorillas, due to the lifting of the upper arms while in trees and on the ground. Musculus brachioradialis and musculus biceps brachii were well developed as flexors of the elbow joint and hold the body mass while climbing up the tree. The Bornean orangutans' activities are more arboreal than those in gorillas and chimpanzees, thus their shoulder and upper arm muscles were more developed to support brachiation activities., Orangutans are arboreal primates that have similarities to gorillas and chimpanzees from both anatomical and physiological aspects, although there are distinct behaviors that allow for differentiation in the structure of the locomotor apparatus. This research aims to study the anatomy of the muscles of the shoulders and upper-arm of the Bornean orangutan associated with the type of locomotion and daily behavior. This study was conducted by observing the morphology of the shoulders and upper-arms muscles and watching their behaviors through video observations. The results showed that the rotator cuff muscles in orangutans were relatively thick resulted in well-fixed shoulders. Musculus rhomboideus occipitalis is only observed in orangutans to facilitate them during arboreal activities such as brachiation. The external trunk muscle in orangutans is found to be relatively large compared to chimpanzees and gorillas, due to the lifting of the upper arms while in trees and on the ground. Musculus brachioradialis and musculus biceps brachii were well developed as flexors of the elbow joint and hold the body mass while climbing up the tree. The Bornean orangutans' activities are more arboreal than those in gorillas and chimpanzees, thus their shoulder and upper arm muscles were more developed to support brachiation activities.
Keyword: arboreal, Bornean orangutans, shoulders and upper-arm muscles, terrestrial