Judul: Penentuan Konsentrasi Bahan Penyamak Aldehida dan Minyak Biji Karet untuk Penyamakan Kulit Samoa pada Skala Pilot Plant
Abstrak: Research on chamois tanning using rubber seed oil on a laboratory scale has achieved optimum results. Therefore,further research is directed toward the pilot plant scale before entering mass production for the commercialization. This study aimed to determine the effects of glutaraldehyde concentrations (3% and 5%) and rubber seed oil concentrations (20% and 30%) and also to determine the best combination of treatments. This study shows that the concentration of rubber seed oil significantly affected oil content and tensile strength. The concentration of glutaraldehyde had a significant effect on tear strength and tensile strength. Interaction of these two factors significantly affected the tensile strength of chamois leather. Combination treatment of rubber seed oil concentration of 20% and 3% glutaraldehyde concentration gave the best results. The physical properties were tensile strength of 30.1 N/mm2, elongation of 112.6%, tear strength of 81.57 N/mm, 2 hours water absorption of 345%, 24-hour water absorption of 409.9%. The chemical properties were oil content of 5.9%, ash content of 1.2%, and pH of 6.7. The organoleptic properties were softness 8 (good), colours 8-9 (very good), and odour 8-9 (very good). This best result was similar with or may be as good as the best result on laboratory scale. Therefore, chamois leather production process technology of rubber seed oil is ready to be produced on a larger scale for the purpose of commercialization by considering economic value
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Judul: Pengaruh Jumlah Bahan Pretanning dan Minyak Biji Karet (Hevea brasiliensis) Terhadap Mutu Kulit Samoa. Di
Abstrak: Animal hides or skins are the most valuable by product of the meat industry. Most of those hides are converted into leather by leather tanning process. Chrome based tanning is the most popular tanning process. At the chrome based tanning process, a lot of amount chrome are throw away into the environment that make a significant effect to the biological and ecological environment damaged. Due to concerns over the use and disposal of chromed tanned leather, the leather industry is now facing increasing scrutiny over its use of chrome as tanning agent. The use of non-chrome tannages has gradually become pre-eminent to producing leather, particularly in the European automotive leather markets. Chamois leather is one of leather product. It is produced from animal hides/skins by oil tanning process, usually with fish oil. High price and odour problems to the chamois leather that produced using fish oil motivate to do some research to solve that problems. Rubber seed oil is an oil that predicted can substitute fish oil. Pretanning process is needed to increase the oil penetration and protects the pelt from putrefying during oxidation periods (Khrisnan et al., 2005). Relugan GT 50 is the agent that used on this research. Relugan GT 50 is an aldehyde tanning agent, produced by BASF. This research was aimed to find out the effects of Relugan GT 50 concentration (offer) and rubber seeds (Hevea brasiliensis) oil to the chamois leather’s quality. Beside that, this research is also aimed to decide the best combination of the factors to produce chamois leather also to know the chamois leather characteristics. The preliminary research was carried out by analyzing the rubber seed’s kernel and eggshell as well as physico-chemical properties of the rubber seed oil. The main research was done by tanning the skin with Relugan GT 50 in concentrations of 1.5, 3.0 and 4.5% followed by rubber seed oil concentrations of 10, 20, and 30%. The experimental design used was completely randomize factorial design. The preliminary research shows that rubber seed’s kernel was 49% and rubber seed’s eggshell was 51%. The rubber seed’s oil characterstics were density of 0.94 (g/cm3), viscosity of 48,4 centistokes, colour of 2713 PtCo units, inodine value 113 g iod/ 100 g, peroxide value of 24 miliequivalent/1000 gram oil, acid value of 15 mg KOH/g oil and FFA content of 5.8%. The research shows that Relugan GT 50 concentration significantly affected shrinkage temperature (Ts) and pH; rubber seed oil concentration significantly affect the organoleptic properties of the leather. The optimum conditions for the tanning were Relugan GT of 3.0% concentration and 10% rubber seeds oil. The physical properties of the leather were shrinkage temperature of 75oC, thickness of 0.92 mm, tensile strength of 21.50 N/mm2, elongation at break of 144%, tear strength of 55.77 N/mm, water absorption of 266% (2 hours) and 299% (24 hours). The chemical properties were oil content of 2.5%, ash content of 1.2% and pH of 8. The organoleptic properties were softness of 7–8, colour of 8-9, and odour of 8-9.
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Judul: Metrik Einstein (Anti-) Self-Dual Berdimensi Empat dengan Metode Cartan
Abstrak: Gravitational field equation can be formulated in differential forms (differential geometry), which describes gravity as a manifestation of the curvature of space-time. Curvature of space-time is characterized by a metric that satisfies the gravitational field equation. With differential forms it can be formulated the (anti-) self-dual Einstein equation, which is a modification of the Cartan structure in (anti-) self-dual basis. Calculation of (anti-) self-dual metric with (anti-) self-dual Einstein equation is simpler than the calculation using Christoffel symbols.
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