Judul: Exergy Analysis of Membrane Utilization for Solution Separation in LiBr-H2O Absorbtion Refrigeration System
Abstrak: Absorbtion refrigeration system provides prominent advantages in tems of environmental impact and energy consumption. Absorbtion refrigeration system uses natural refrigerant, such as water, which gives no harm to the environment. In terms of energy consumption, it requires heat to regenerate refrigerant from its absorber and provide the refrigeration effect. This form of energy is preferred since heat can be supplied from various sources, including waste heat and renewable energy, and thermodynamically categorized as low quality energy. However, effectiveness of refrigerant regeneration could only be obtained if the temperature is high enough. In this study, the heat utilization in the regeneration process will be eliminated by introducing membranes for separating the refrigerant from the absorber. Specifically, the objectives of this research are to :1) to study the absorbtion mechanism of water vapor by LiBr-H2O solution in a controlled condition, 2) to study the regeneration process of LiBr-H2O using reverse osmosis (RO) membrane and vacuum membrane distillation (VMD) when applied in LiBr-H2O absorbtion refrigeration system, 3) to perform the energy and exergy analysis in LiBr-H2O absorbtion refrigeration system using RO membrane. The membrane was used as a tool to separate the refrigerant from absorbent which performs as regeneration process in conventional absorbtion system. As separation component, RO membrane employs pressure to oppose the osmotic pressure and pass certain component through the pores. While, VMD employs vacuum pressure and thermal, so that the substance to be transported through the membrane is in form of vapor. The result shows that absorbtion rate of water vapor by LiBr-H2O solution was influenced by solution concentration, temperature, humidity and pressure. The highest absorbtion rate was 0.031 g/minute which was occurred at temperature 40°C, RH 70% and solution concentration 60%. Prediction model was developed to calculate the absorbtion parameter inspite of P-T-X diagram.The highest water vapor absorbtion in absorber using spiral wound module-based RO membrane occurred at initial concentration of 30%, wich is the highest concentration used in the experiment. Increasing of operation pressure during separation process will increase permeation flux but decrease rejection factor.Unexpectedly, permeate of the RO membrane still contain LiBr at concentration 7w/w %-9w/w%, which affect the achievable cooling temperature and cooling capacity. Optimization of regeneration using VMD was conducted with response surface methodology (RSM) and the result show that highest permeate flux (0.93 kg.m-2.s-1) can be achived at initial concentration of 47.5%, temperature of 80°C and flow rate of 1.9 L.min-1.COP obtained in absorbtion refrigeration system using RO membran with initial concentration 20% was in the range of 1.147-1.171. Exergy analysis shows that increasing pressure of RO membrane at concentration 20% increased the irreversibity.On the other hand, exergy analysis on VMD shows that higher concentration and temperature will increased irreversibility.
Keyword: refrigeration, absorbtion, reverse osmosis, vacuum membrane distillation, energy, exergy

Judul: Studying rate of absorption steam by solutions Lithium Bromide (LiBr) as absorbant in absorption refrigeration
Abstrak: Absorption is the process of absorbing a fluid by another fluid to form a fluid solution. In absorption refrigeration system, LiBr as absorbent filters on components of the absorber will absorb water vapor with lower pressure than the evaporator pressure. The rate of absorption of water vapor is a function of concentration, temperature, humidity and pressure of water vapor. The goal of this research is to see the effect of concentration, temperature and vapor pressure of water at the rate of absorption of water vapor by aqueous absorbent filters (LiBr-H2O) in relation to the cooling system, to determine the equilibrium concentration absorption solution of LiBr-H2O, and to determine the sorption isotherm model. Equilibrium concentration is a function of temperature and humidity. Ce at 40oC and RH 60% was found 37%; at 40oC and RH 70% was 34%; at 40o and RH 80% was 29%; at 45oC and RH 60% was 37.5%; at 45oC and RH 70% was 36%; and at 45oC and RH 80% was 34.5%. The calculation results of Qe using Qe sorption isotherm model on temperature 40oC and 45oC were not too different. The calculation results of the percentage errors between Qe data and model from each of the humidity, obtained the lowest percentage of errors in model Freundlich was 0.4% in RH 60% and 70%; 0.3% in RH 80%.
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Judul: Closed Knight’s Tour pada Papan Catur Berbentuk Persegi Panjang dengan Ukuran Maksimal 8 × 8
Abstrak: Closed Knight’s Tour merupakan langkah kuda yang mengunjungi setiap kotak pada papan catur tepat satu kali dengan langkah kuda berawal dan berakhir pada kotak yang sama. Graf yang terbentuk dari closed knight’s tour dinotasikan sebagai graf G(m,n), dengan m adalah banyaknya baris dan n adalah banyaknya kolom. Graf tersebut memuat Hamiltonian cycle. Sebuah graf terhubung G adalah graf bipartite jika dan hanya jika graf tersebut tidak memiliki cycle dengan panjang ganjil. Papan catur yang memenuhi syarat cukup untuk memiliki closed knight’s tour adalah papan catur berukuran 5 × 6, 5 × 8, 6 × 6, 6 × 7, 6 × 8, 7 × 8, dan 8 × 8.
Keyword: bipartite, closed knight’s tour, hamiltonian cycle, knight’s tour, teori graf