METHOD FOR FORMING HIGH QUALITY MULTIPLE THICKNESS OXIDE LAYERS BY REDUCING DESCUM INDUCED DEFECTS

Abstract: A method for forming high quality oxide layers having different thicknesses by eliminating descum induced defects is disclosed. A semiconductor substrate is subjected to reactive ion etching. The semiconductor substrate includes a wafer (4), an oxide layer (2) on the wafer, and a developed photoresist mask (8) on the oxide layer. The oxide layer (2) is then etched, and the remaining photoresist mask (8) is stripped before another layer of oxide (14) is grown on the substrate.

Description: METHOD FOR FORMING HIGH QUALITY MULTIPLE THICKNESS OXIDE LAYERS BY REDUCING DESCUM INDUCED DEFECTS TECHNICAL FIELD The present invention pertains to the field of integrated circuit devices and manufacturing processes for the same More particularly, this invention relates to the formation of high quality multiple thickness oxide layers on a silicon wafer substrate BACKGROUND ART Non-volatile memory devices are currently in widespread use in electronic components that require the retention of information when electrical power is terminated Non-volatile memory devices include read- only-memory (ROM), programmable-read-only memory (PROM), erasable-programmable-read-only memory (EPROM), and electrically-erasable-programmable-read-only-memory (EEPROM) devices EEPROM devices differ from other non-volatile memory devices in that they can be electrically programmed and erased Flash EEPROM devices are similar to EEPROM devices in that memory cells can be programmed and erased electrically However, Flash EEPROM devices enable the erasing of all memory cells in the device using a single electrical current pulse High voltage circuit elements such as program and erase transistors are usually formed on a wafer substrate with a relatively thick gate oxide layer Such relatively thick gate oxide layers are usually required to prevent transistor circuit breakdown in such a high voltage environment On the other hand, it is preferable that the low voltage circuitry is implemented with relatively thin gate oxide layers on the wafer substrate Such thin gate oxide layers typically increase the speed of such circuit elements having relatively short gate lengths and thin oxide layers typically provide increased operation speeds In addition, as process technologies evolve toward shorter and shorter gate lengths it is desirable to reduce the thickness of the gate oxide layer even further in order to achieve greater operating speed However, some circuit elements contained on such integrated circuit devices may not be scalable Non-volatile memory devices, such as flash EEPROMs require the formation of flash memory cells that include tunnel oxide layers on the wafer substrate Such tunnel oxide layers may be thinner than high voltage oxide layers on the wafer substrate However, such tunnel oxide layers usually cannot be scaled down in thickness in the same manner as low voltage oxide layers Such flash memory cells, for example, typically suffer from significant endurance and data retention problems if the tunnel oxide layers are too thin Therefore, non-volatile memory devices can usually benefit from the formation of differing oxide thicknesses on the same wafer substrate Transistors with relatively thick select gate oxide layers can accommodate high voltage program and erase operations while logic transistors with relatively thin gate oxide layers can yield speed advantages as process technologies evolve toward smaller circuit element dimensions In addition, the thickness of tunnel oxide layers for flash memory cells can be scaled for reliability independent of the gate dimensions and oxide thickness of the high and low voltage transistors One method of forming high quality multiple thickness oxide layers involves multiple masking and oxide formation steps For example, a first oxide layer, usually the thickest oxide layer, is initially grown on the wafer substrate Thereafter, a layer of photoresist is formed on the first oxide layer A pattern is formed on the photoresist layer by exposing the photoresist through a mask The photoresist is then developed and removed, leaving a portion of the oxide layer exposed Subsequently, the first oxide layer is etched and the remaining photoresist is stripped A second layer of oxide is then grown on the wafer substrate The second oxide layer forms a thin oxide layer on the wafer substrate while a thicker oxide layer is formed by the combination ot the first and second oxide layers This process can be repeated to form additional oxide layers with various thicknesses throughout the process flow During and after development of the photoresist layer, the unmasked or exposed portion of the oxide layer may become contaminated For example, a thin film, undetectable on visual inspection, may form on the exposed portion of the oxide layer This film may consist of photoresist residue such as dried developer and undissolved pieces of photoresist Thus, it is usually necessary to subject the unmasked portion of the oxide layer to a cleaning or descumming process to remove the resist residue The unmasked or exposed portion of the oxide layer is often descummed or cleaned with 0 2 , OJN 2 or 0 2 /N 2 -H 2 chemistries in a barrel asher or a downstream single wafer asher Although the descum process is relatively short in order to avoid any surface damage to the exposed oxide layer, the descum process itself leaves contaminants on the oxide layer The contaminants appear as dark spots on the oxide layer under a high-resolution scanning electron microscope (SEM) as shown in FIG 1 An analysis of the dark spots shows that they consist of sulfur compounds and small hydrocarbons, most likely photo active compound, left over from the development of the photoresist These dark spots or defects on the surface of the exposed oxide layer interact with subsequent processing steps, which creates processing problems and degrades reliability and yield For example, when a wet oxide etch is carried out after descum to remove the exposed portion of an oxide layer, the oxide layer under the dark spots cannot be completely removed Thus, the dark spots act as a micromask on the exposed portion of the oxide layer As a result of the dark spots, a subsequently grown oxide layer may not be uniform because the initial oxide layer is not completely removed Therefore, it would be desirable to have a process for removing these dark spots or defects when forming multiple thickness gate and tunnel oxide layers in order to achieve a higher overall yield of acceptable wafers DISCLOSURE OF INVENTION A method of forming uniform oxide layers by reducing descum induced defects is disclosed The method comprises reactive ion etching (RIE) a semiconductor substrate, which includes a wafer, an oxide layer on the wafer and a developed photoresist mask on the oxide layer After reactive ion etching the substrate, the oxide layer is etched Other features and advantages of the present invention will be apparent from the detailed description of the invention BRIEF DESCRIPTION OF SEVERAL VIEWS OF THE DRAWINGS FIG 1 is a photograph of the unwanted dark spots or defects on a wafer substrate after descum, FIG 2 is a partial cross-sectional view of an oxide layer formed on a wafer substrate, FIG is a partial cross-sectional view of the substrate alter the formation of a photoresist layer on the oxide layer FIG 4 is a partial cross sectional view of the wafer substrate after the photoresist has been developed and the substrate has been descummed, FIG 5 is a partial cross-sectional view of the wafer substrate after the oxide layer has been etched, FIG 6 is a partial cross-sectional view of the wafer substrate after the photoresist layer has been stripped, FIG 7 is a partial cross-sectional view of the wafer substrate alter a new layer of oxide has been grown, FIG 8 is a partial cross-sectional view oi a wafer substrate after the formation of a floating gate on the first and second oxide layers, FIG 9 is a partial cioss-sectional view of a wafer substrate after formation and development of a photoresist layer and after the substrate has been descummed, FIG 10 is a partial cross-sectional view of a wafer substrate after the oxide layers have been etched, and FIG 1 1 is a partial cross sectional view of the wafer substrate after a third layer of oxide has been grown It should be appreciated that for simplicity and clarity of illustration, elements shown in the Figures have not necessarily been drawn to scale For example, dimensions of some of the elements are exaggerated relative to each other for clarity MODES FOR CARRYING OUT THE INVENTION Referring to FIG 2, first oxide layer 2, the select gate oxide layer, is formed to overlie the surlace of semiconductor substrate 4 Preferably, semiconductor substrate 4 is a single crystal silicon substrate Semiconductor substrate 4 has an upper surlace 6 previously processed to remove debris and native oxides Preferably, the select gate oxide layer 2 is formed by thermally oxidizing surface 6 at an elevated temperature in the presence of ambient dry oxygen or steam Prelerably the oxidation process is earned out at a temperature of about 700 to about 1400°C The oxidation process forms a silicon oxide layer preferably having a thickness of about 50 to about 1 0 angstroms, and more preferably a thickness of about 90 100 angstroms The oxidation process may be carried out in a batch-type thermal oxidation furnace After forming the first oxide layer 2, the substrate is processed to remove any impurities, and a photoresist layer 8 is formed to overlie the first oxide layer as lllustiated in FIG 3 Preferably, photoresist layer 8 is ultraviolet sensitive and is a positive resist Selected portions of the photoresist layer 8 are then exposed through a mask The exposed photoresist is then developed and removed leaving a portion 10 of the oxide layer exposed The photoresist layer mav be developed by methods generally known in the art including but not limited to immersion, spray and puddle techniques FIG 4 illustrates the exposed portion 10 of the oxide layer 2 After the resist is developed and rcmo\ ed, the exposed portion of the oxide layer 10 is subjected to a low power reactive ion etch to remove any organic lesidue such as dried developer or undissolved photoresist which may appear on the surface of the oxide la\er Preferably the reactive ion etch is with RF bias In order to maintain the integrity of the photoresist layer and ensure pattern quality, the descum process is relatively short and not more than 30 nm of the photoresist layer and 1 nm of the oxide layer are removed The reaction ion etch process variables are as follows ( 1 ) Time duration of RIE 3-25 seconds, (2) OJN,. OJN 2 -H-,. or 0 2 /He/Ar chemistries, (3) RF power level 50 200W, (4) Pressure 25-300mTorr, and (5) Wafer temperature 20-60°C More specific examples of the RIE process conditions are listed in Table 1 below Table 1 It has been discovered that use of a low power reactive ion etch satislactoπly removes any residue left over Irom the development of the photoresist However, unlike a down-stream descum process, which is normally used to remove excess dried developer and/or undissolved photoresist The reactive ion etching process has the advantage of directional etching with the bottom electrode biased, which effectively removes resist residue, but does not leave any dark spots on the exposed portion 10 of the oxide layer Thus, use of a reactive ion etch eliminates any potential micromasking which occurs when a conventional Oi descum process After the reactive ion etching has been completed, the exposed portion of oxide layer 10 is etched 01 stripped away as illustrated in FIG 5 The oxide layer may be etched by conventional dry and wet methods that are well known in the art lor etching oxide layers Dry etch methods that can be used to etch the exposed portion of the oxide layer include plasma etching ion milling etching, and reactive ion etching Wet etch methods include using hydrofluoric acid Preferably, a standard bulfered oxide etch of hydrofluoric acid ammonium fluoride and water is used to etch the exposed portion of the oxide layer After the exposed portion 10 of the oxide layer 2 is etched, the remaining photoresist 8 is stripped as shown in FIG 6 Both wet and dry methods that are well known in the art oi semiconductor fabrication can be used to strip the remaining photoresist layer 8 Such methods include but are not limited to use of sulfuπc acid and oxidant solutions and conventional Oτ plasma stripping A new oxide layer 14 is then grown on the wafer substrate 4 as shown in FIG 7 to produce two oxide layers having different thicknesses The tunnel oxide layer forms a thin oxide layer while the combination ol the select gate oxide layer and the tunnel gate oxide layer form a thicker oxide layer The process described above may be repeated to create additional oxide layers with various thicknesses For example after growing the tunnel oxide layer 14 a floating gate 16 is formed over oxide layers 2 and 14 as shown in FIG 8 A photoresist layer 18 is then formed to overlie oxide layei s 2 and 14 and gate structure 16 As shown in FIG 9 the photoresist layer 18 is exposed through a mask and the exposed photoresist is then developed and removed leaving a portion 15 of oxide layers 2 and 14 exposed. After the resist is developed and removed, the substrate is descummed using reactive ion etching at low power Then, the exposed portion 15 of oxide layers 2 and 14 is etched away and the remaining photoresist is stripped away as shown in FIG 10. As illustrated in Figure 1 1 , a third oxide layer 20, the peripheral gate oxide layer, having a thickness different than oxide layers 2 and 14 is grown on the surface of wafer substrate 4 Thus, there has been disclosed in accordance with the invention a process for fabricating multiple thickness uniform oxide layers in a semiconductor device that fully provides the advantages set forth above The disclosed method can double the yield of acceptable wafers for further processing Although the invention has been described and illustrated with reference to specific illustrative embodiments thereof, it is not intended that the invention be limited to those illustrative embodiments Those skilled in the art will recognize that variations and modifications can be made without departing from the spirit of the invention. It is therefore intended to include within the invention all such variations and modifications that fall within the scope of the appended claims and equivalents thereof

Claims: CLAIMS 1 A method for forming a semiconductor structure, the method characterized by reactive ion etching a substrate at low power, said substrate characterized by (a) a wafer (4), (b) a first oxide layer (2) on the wafer, and (c) a developed photoresist mask (8) on said first oxide layer, and etching the first oxide layer 2 The method of Claim 1 , further characterized by stripping the photoresist mask (8) 3 The method of Claim 2 further characterized by growing a second layer of oxide (14) on the wafer 4 The method of Claim 1 , wherein the reactive ion etching is carried out with an RF bias for between 3 to 25 seconds 5 A method of making a semiconductor device characterized by forming a semiconductor structure by the method of Claim 4, and fabricating a semiconductor device from said semiconductor structure 6 In a method of fabricating a semiconductor device, including growing an oxide layer (2) over a semiconductor substrate, depositing a layer of photoresist (8) over the oxide layer, exposing and developing the photoresist layer, ashing the substrate to remove any photoresist residue, etching the oxide layer (8), stripping the remaining photoresist and growing a new oxide layer (14), the improvement characterized by reactive ion etching the substrate at low power instead of ashing the substrate 7 The method of Claim 6, wherein the reactive ion etching is carried out with an RF bias for between 3 to 25 seconds 8 A method for forming a semiconductor structure, the method characterized by reactive ion etching a substrate at low power, said substrate characterized by (a) a wafer (4), (b) a first patterned oxide layer (2) on the wafer, (c) a second oxide layer on the first oxide layer(14), and (d) a developed photoresist mask ( 18) on the second oxide layer, etching the second oxide layer (14), stripping the photoresist mask ( 18), and growing a third layer of oxide (20) on the substrate 9 The method of Claim 8, wherein the reactive ion etching is carried out with an RF bias for between 3 to 25 seconds 0. A method of making a semiconductor device characterized by. forming a semiconductor structure by the method of Claim 9; and fabricating a semiconductor device from said semiconductor structure.

Inventors: HUI ANGELA T, OGURA JUSUKE, HUI, ANGELA, T., OGURA, JUSUKE
Applicants: ADVANCED MICRO DEVICES INC, FUJITSU LTD, ADVANCED MICRO DEVICES, INC., FUJITSU LIMITED
Application year: 2001
Main classification: H01L21
IPC codes: H01L21, H01L27, H01L29