Power transmission belt

Abstract: An endless power transmission belt comprising (a) a tension section (21); (b) a cushion section (22); (c) a load-carrying section (23) disposed between said tension section and cushion section; (d) at least one drive surface (29)having a fabric layer (25) bonded to an outer surface of the belt; and (e) a layer of thermoplastic (27) located between the fabric layer (25) and the cushion section (22) of the power transmission belt.

Description: Background of the Invention Recent developments in the automotive industry have resulted in an increase in the demands on the properties of power transmission belts. As a result, power transmission belts on these engines have been required to operate under higher loads, at higher speeds and at higher temperatures while reducing belt width and noise. The automotive industry demands a high quality belt capable of withstanding these severe conditions. One method to improve the properties of such belts has been to improve the materials from which the belts are made. For example, conventional polychloroprene rubber has been replaced with hydrogenated nitrile rubber and chlorosulfonated polyethylene. In addition, solid lubricants have been added to the rubber compositions to improve the abrasion properties of the belt by reducing the coefficient of friction. EP-A-0280175 discloses an endless belt comprising a belt main body prepared from a liquid castable elastomeric material, a reinforcing fabric provided over the surface of the main body, and a shock absorbing layer of elastomeric material formed between the main body and the fabric. Summary of the Invention The present invention relates to a power transmission belt that is characterized by a layer of polyvinylidene fluoride located between the fabric layer and the cushion section of the power transmission belt and wherein the cushion section comprises a peroxide-cured rubber composition comprising an elastomer selected from the group consisting of natural rubber, polychloroprene, acrylonitrile-butadiene copolymers polyisoprene, zinc salts of unsaturated carboxylic acid ester grafted hydrogenated artrile butadiene elastomers styrene-butadiene rubbers, polybutadiene, EPDM, hydrogenated acrylonitrile-butadiene copolymers, and ethylene acrylic elastomers. Brief Description of the Figures The accompanying figures show embodiments of this invention in which Figure 1 is a fragmentary perspective view illustrating one embodiment of an endless power transmission belt of this invention. Detailed Description of the Invention There is disclosed an endless power transmission belt comprising (a) a tension section; (b) a cushion section; (c) a load-carrying section disposed between said tension section and cushion section; (d) at least one drive surface having a fabric layer bonded to an outer surface of the belt; and (e) a layer of polyvinylidene fluoride located between the fabric layer and the cushion section of the power transmission belt and wherein the cushion section comprises a peroxide-cured rubber composition comprising an elastomer selected from the group consisting of natural rubber, polychloroprene, acrylonitrile-butadiene copolymers polyisoprene, zinc salts of unsaturated carboxylic acid ester grafted hydrogenated artrile butadiene elastomers styrene-butadiene rubbers, polybutadiene, EPDM, hydrogenated acrylonitrile-butadiene copolymers, and ethylene acrylic elastomers. Reference is now made to Figure 1 of the drawing which illustrates an endless power transmission belt structure or belt of this invention which is designated generally by the reference numeral 20. The belt 20 is particularly adapted to be used in associated sheaves in accordance with techniques known in the art. The belt is particularly suited for use in synchronous drive applications. The belt 20 is adapted to be used in so-called torque sensing drives, application where shock loads of varying belt tension are imposed on the belt, applications where the belt is operated at variable speeds, applications where the belt is spring-loaded to control its tension and the like. The belt 20 comprises a tension section or backing 21, a cushion section 22, a load-carrying section 23 disposed between the tension section 21 and cushion section 22, and a fabric layer 25 adhered to drive surface 29. The belt has a layer of polyvinylidene fluoride 27 which is located between the cushion section 22 and the fabric layer 25 to prevent or decrease the amount of rubber with cushion section 22 permeating through the fabric 25 to the drive surface 29. The cushion section 22 comprises a peroxide-cured rubber composition comprising an elastomer selected from the group consistting of natural rubber, polychloroprene, acrylonitrile-butadiene copolymers, polyisoprene, zinc salts of unsaturated carboxylic acid ester grafted hydrogenated nitrite butadiene elastomer, styrene-butadiene rubbers, polybutadiene, EPDM, hydrogenated acrylonitrile-butadiene copolymers, and ethylene-acrylic elastomers. In the belts of the present invention, there is at least one drive surface 29 having a fabric layer 25 bonded to the outer surface. In the embodiment shown in Figure 1, there is one drive surface 29 having a fabric layer 25. In accordance with other embodiments, the belt 20 may have multiple drive surfaces of two or more. The fabric layer may also be on the outer surface of the belt which is not a drive surface. The fabric layer 25 may be made from a woven, non-woven or knitted fabric. The fabrics for use in the present invention are made of conventional materials including nylon (such as nylon 4,6, nylon 6,6 and nylon 6), cotton, polyester, cotton/polyester, nylon/polyester, cotton/nylon, Lycra™ (segmented polyurethane), aramid, rayon and the like. Preferably, the fabric is made of nylon 6,6. The load-carrying section 23 has load-carrying means in the form of load-carrying cords 32 or filaments which are suitably embedded in an elastomeric load-carrying section 23 in accordance with techniques which are well known in the art. The cords may be transverse or parallel to the length of the belt. The cords 32 or filaments may be made of any suitable material known and used in the art. Representative examples of such materials include aramids, fiberglass, nylon, polyester, cotton, steel, carbon fiber and polybenzoxazole. The drive surface 29 of the belt 20 of Figure 1 is synchronous. In accordance with other embodiments and as discussed later, it is contemplated herein the belts of the present invention also include those belts where the drive surface of the belt may be smooth, single V-grooved, and multi-V-grooved. Representative examples of synchronous include belts having trapezoidal or curvilinear teeth. The tooth design may have a helical offset tooth design such as shown in US-A- 5,209,705 and 5,421,789. The rubber compositions for use in the tension section 21, cushion section 22 and load-carrying section 23 may be the same or different. Conventional elastomers which may be used in the tension section or the load carrying section include natural rubber, polychloroprene, acrylonitrile-butadiene copolymers (NBR), polyisoprene, zinc salts of unsaturated carboxylic acid ester grafted hydrogenated nitrile butadiene elastomers, styrene-butadiene rubbers, polybutadiene, EPDM, hydrogenated acrylonitrile-butadiene copolymers (HNBR), polyurethane, elastomers marketed under the Viton™ designation and ethylene-acrylic elastomers sold under the name VAMAC and blends thereof. The elastomers for use in the tension section 21, and load carrying section 23 may be crosslinked by various peroxide containing curing agents. Curing agents which may be employed in the compositions of the invention include, for example, di-tertbutyl peroxide, dicumyl peroxide, benzoyl peroxide, 2,4-dichlorobenzol peroxide, t-butyl-cumyl peroxide, t-butyl perbenzoate, t-butyl peroxide, t-butylperoxy (2-ethyl hexanoate), 2,5-dimethyl-2,5-di(benzoylperoxy)-hexane, benzoyl peroxide, 2,5-dimethyl-2,5-(t-butyl peroxy)-hexane, 1,1-ditert-butyl peroxy-3,3,5-trimethyl cyclohexane, 4,4-ditert-butyl peroxy n-butyl valerate and n-butyl-4,4-bis(t-butyl peroxy) valerate. Additional curing agents which may be employed include diacyl or dialkyl peroxides such as α,α'-bis(t-butylperoxy)-isopropylbenzene, 2,5-dimethyl-2,5-di(t-butylperoxy) hexane, di-t-butyl peroxide, 2,5-dimethyl-2,5-di-(t-butylperoxy)hexyne-3, lauroyl peroxide, t-butyl hydroperoxide, t-amyl hydroperoxide, cumene hydroperoxide, t-butyl perbenzoate, t-butyl peroxide, t-butylperoxy (2-ethyl hexanoate), 2,5-dimethyl-2,5-di (benzoylperoxy)-hexane and benzoyl peroxide. All of the above curing agents are commercially available. The amount of curing agent that is used may vary. Generally speaking, the level will range of from 0.1 to 10 phr (based on active parts of peroxide). Preferably, the level ranges from 1.8 to 3.0 phr. In the belt of Figure 1, there is one drive surface 29 having a fabric layer 25 bonded to the outer surface. Between the fabric layer 25 and the cushion section is the layer of polyvinylidene fluoride 27. Polyvinylidene fluoride has a melting point of from 82°C to 265°C. The polyvinylidene fluoride layer may be the homopolymer of vinylidene fluoride or a copolymer of vinylidene fluoride and another monomer. One or more monomers selected from the group consisting of tetrafluoroethylene, hexafluoropropylene, monochlorotrifluoroethylene, vinyl fluoride, perfluorovinylalkyl ethers, vinyl acetate and ethylene can be used for copolymerization with vinylidene fluoride. The polyvinylidene fluoride layer is preferably applied in the form of a film. The film is generally transparent and may be an unoriented film produced by the techniques of extrusion or casting or an oriented film obtained by stretching the unoriented film. Commercially available films of polyvinylidene fluoride may be used to construct the belts of the present invention. Such films include those that are commercially available from Westlake Plastics Company of Lenni, Pennsylvania. The thickness of the polyvinylidene fluoride layer may vary. Generally speaking, the thickness may range from 0.0125 mm (0.5 mil) to 1.25 mm (50 mils). Preferably, the thickness ranges from 0.05 mm (2 mils) to 0.20 mm (8 mils). The polyvinylidene fluoride layer 27 may be applied to the fabric and heated to adhere the polyvinylidene fluoride to the fabric. Preferably, this is done prior to application of the fabric to the cushion section 22 during construction of the belt 20. The power transmission belts may be built on a drum device. First, the fabric and polyvinylidene fluoride layer are applied to the drum. Next, the cord or tensile member (load carrying section) is spiraled onto the drum. Thereafter, the cushion section is applied onto the tension section. The polyvinylidene fluoride layer or film may be heat bonded to the facing fabric and thereafter laminated onto the cushion section. Another alternative is to apply the polyvinyliden fluoride layer film and fabric separately relying on the heat during cure to mechanically bond the two layers. The assembled laminate or slab is then placed in a mold, cured and cut into the belts in a manner known to those skilled in the art. Example The belts of the present invention were prepared in the following manner. A resorcinol formaldehyde latex dipped nylon 6,6 knit fabric was laminated with 0.1 mm of a polyvinylidene fluoride film obtained from Westlake Plastic Company. The filler was laminated to the fabric in a flat platen press at 191°C. This fabric laminate was placed on the drum with the polyvinylidene fluoride layer out. Fiberglass cord dipped in an adhesive was spiraled onto the drum. A rubber sheet of peroxide-cured hydrogenated NBR was applied onto the cord to form the cushion section. Finally, a cotton/polyester fabric backing was applied to the drum device. The belts were cured at 176°C and cut in widths of 32 mm (1.25 inches).

Claims: An endless power transmission belt comprising (a) a tension section (21); (b) a cushion section (22); (c) a load-carrying section (23) disposed between said tension section and cushion section; (d) at least one drive surface (29) having a fabric layer (25) bonded to an outer surface of the belt; characterized in that the belt further comprises (e) a layer (27) of polyvinylidene fluoride located between the fabric layer (25) and the cushion section (22) of the power transmission belt; and wherein the cushion section (22) comprises a peroxide-cured rubber composition comprising an elastomer selected from the group consisting of natural rubber, polychloroprene, acrylonitrile-butadiene copolymers polyisoprene, zinc salts of unsaturated carboxylic acid ester grafted hydrogenated nitrile butadiene elastomers, styrene-butadiene rubbers, polybutadiene, EPDM, hydrogenated acrylonitrile-butadiene copolymers and ethylene-acrylic elastomers. The power transmission belt of claim 1, characterized in that the layer (27) of polyvinylidene fluoride ranges from 0.0125 mm to 1.25 mm thick. The power transmission belt of claim 1, characterized in that the fabric layer (25) is selected from the group consisting of woven, non-woven and knitted fabrics. The power transmission belt of claim 1, characterized in that said peroxide is selected from the group consisting of di-tertbutyl peroxide, dicumyl peroxide, benzoyl peroxide, 2,4-dichlorobenzol peroxide, t-butyl-cumyl peroxide, t-butyl perbenzoate, t-butyl peroxide, t-butylperoxy (2-ethyl hexanoate), 2,5-dimethyl-2,5-di (benzoylperoxy)-hexane, benzoyl peroxide, 2,5-dimethyl-2,5-(t-butyl peroxy)-hexane, 1,1-ditert-butyl peroxy-3,3,5-trimethyl cyclohexane, 4,4-ditert-butyl peroxy n-butyl valerate, n-butyl-4,4-bis (t-butyl peroxy) valerate, α,α-bis(t-butylperoxy)-isopropylbenzene, 2,5-dimethyl-2,5-di(5-butylperoxy) hexane, di-t-butyl peroxide, 2,5-dimethyl-2,5-di-(t-butylperoxy)hexyne-3, lauroyl peroxide, t-butyl hydroperoxide, t-amyl hydroperoxide, cumene hydroperoxide, t-butyl perbenzoate, t-butyl peroxide, t-butylperoxy (2-ethyl hexanoate), 2,5-dimethyl-2,5-di(benzoylperoxy)-hexane, benzoyl peroxide and mixtures thereof. The power transmission belt of claim 1, characterized in that said polyvinylidene fluoride is selected from the group consisting of a homopolymer of vinylidene fluoride and copolymers of vinylidene fluoride and another monomer. The power transmission belt of claim 5, characterized in that said additional monomer is selected from the group consisting of tetrafluoroethylene, hexafluoropropylene, monochlorotrifluoroethylene, vinyl fluoride, perfluorovinylalkyl ethers, vinyl acetate and ethylene.

Inventors: BILLUPS WESLEY JAMES, BILLUPS, WESLEY JAMES
Applicants: GOODYEAR TIRE & RUBBER, THE GOODYEAR TIRE & RUBBER COMPANY
Application year: 2001
Main classification: F16G1
IPC codes: F16G1