DENDRIMERS

Abstract: A compound of formula (I), where x is 3, 2 or 1, y is 0 or 1, n<1> and n<2>, which may be the same or different, are 0 or 1 to 3, X represents a divalent mono- or poly-aromatic and/or heteroaromatic moiety, the or each Y, which may be the same or different if x is 1, represents hydrogen or an optionally substituted hydrocarbon group, Z represents an aromatic group, or an inherently at least partly conjugated dendritic molecular structure comprising one or more aromatic and/or heteroaromatic groups and, optionally, alkenylene groups, connected to each other either directly or via a carbon atom of an alkenylene group, if present, to a ring carbon atom of an (hetero) aromatic group to which more than one at least partly conjugated dendritic chain is attached, said molecular structure being connected to the remainder of the molecule via a ring carbon atom, one or more of the (hetero) aromatic rings of the dendrimers optionally being substituted, Z and/or the remainder of the molecule, excluding any groups Y, being luminescent, with the proviso that when Z represents an aromatic group y must be 1.

Description: DENDRIMERS This invention relates to improved dendrimers which are light-emitting, to a novel process for making dendrimers and to devices using them. Organic and polymer light emitting diodes (LEDs) have been the focus of intensive research for the past decade. Whereas small organic molecules are processed by thermal evaporation under high vacuum, polymers may be deposited directly from solution. Both classes of materials have their merits, with small organic molecules allowing greater chemical and colour purity and polymers greatly simplifying the manufacturing process which has led, for example, to displays produced by inkjet printing. An alternative approach is conjugated dendrimers which have been used successfully both as charge transporting and light-emitting materials. This class of materials combines a well defined chromophore and molecular mass with advantageous solution processing properties. With dendrimers it is possible to tune the emission colour independently of the processing properties. The role of the degree of intermolecular interactions in conjugated polymers and their effect on optical and transport properties has been a topic of intense debate over the past few years. In the context of organic LEDs it is particularly important to understand the relationship between good transport properties and efficient luminescence. It is known that intermolecular interactions can quench the luminescence, but would increase wave function overlap of the π-electrons and so be beneficial to charge transport. The present invention relates to a class of dendrimers which allows a direct control of the microscopic packing through chemical modification and this provides a unique correlation between chemical structure of the molecules and macroscopic device properties. The degree of interaction between molecules as well as the film morphology and microscopic packing can be controlled by the dendrimer generation. Electrochemical studies on conjugated dendrimers have shown that charge injection takes place into the core and not into dendrons which have a wider energy gap. The dendrons act as spatial separators and insulate the cores. We have found that the electronic properties, such as barrier to charge injection in dendrimer-based LEDs, can remain unaffected by generation but that the change in chromophore separation directly affects the charge transport properties. According to the present invention there is provided a compound of the formula: where x is 3, 2 or 1 , y is 0 or 1 , n 1 and n 2 , which may be the same or different, are 0 or 1 to 3, X represents a divalent mono- or poly-(i.e. 2 or more) aromatic and/or heteroaromatic moiety, the or each Y, which may be the same or different if x is 1 , represents hydrogen or an optionally substituted hydrocarbon group, Z represents an aromatic group, or an inherently at least partly conjugated dendritic molecular structure comprising one or more aromatic and/or heteroaromatic groups and, optionally, alkenylene groups, connected to each other either directly or via a carbon atom of an alkenylene group, if present, to a ring carbon atom of an (hetero) aromatic group to which more than one at least partly conjugated dendritic chain is attached, said molecular structure being connected to the remainder of the molecule via a ring carbon atom, one or more of the (hetero) aromatic rings of the dendrimers optionally being substituted, Z and/or the remainder of the molecule, excluding any groups Y, being luminescent with the proviso that when Z represents an aromatic group y must be 1. It will be appreciated that the compounds of the present invention contain 1 to 3 dendritic molecular structures attached to the central nitrogen atom via the grouping. It is preferred that x is 3 in which case Y is absent. As indicated, Y can represent hydrogen or an optionally substituted hydrocarbon group. The nature of the hydrocarbon group is not particularly critical although, typically, it is an alkyl or aryl group such as an alkyl group of 1 to 6 carbon atoms, for example methyl or a phenyl group, an alkylaryl or arylalkyl group, or an arylvinylaryl group such as a stilbene group. When x is 1, each Y can be the same or different. It will be noted that the dendritic structures Z are connected, directly or indirectly, to the central nitrogen atom via a benzene ring. The nature of X can be broad and can represent a mono or poly-aromatic and/or hetero aromatic moiety such as a moiety of pyridine (as in divinyl pyridine), pyrimidine, triazine, thiophene, (as in divinylthiophene), oxadiazole and coronene as well as benzene (as in divinylbenzene and distyrylethylene) and anthracene or can represent linked phenylene units. It can also represent a polyaromatic moiety wherein the aromatic rings are connected by a conjugated grouping such as a vinyl grouping. A typical example is Preferably X represents a moiety of benzene. The group X is preferably linked to the vinyl groups in the para position although it can also be linked in the ortho or meta position. For anthracene the links are preferably para in the central ring. n 1 and n 2 independently represent 0, 1, 2 or 3. Thus, the length of the conjugated structure can vary although it is preferred that n 1 and n 2 are both equal to 1. Thus the preferred unit incorporating the vinyl groups is distyryl benzene. A preferred grouping with n 1 = n 2 = 1 is trans, tπ y-distyryl benzene. The various aromatic and heteroaromatic rings present in the compound may be substituted, for example by C, to C 15 alkyl or alkoxy groups, preferably alkyl or alkoxy of 1 to 8, for example 1 to 6, carbon atoms such as t-butyl or 2-ethyl hexyl. It will be appreciated, in this connection, that the benzene ring which is adjacent to the nitrogen atom can likewise be substituted. In Z, the aromatic groups are preferably benzene rings, preferably substituted at 3 and 5 positions, pyridine or triazine rings or linked phenylene units. These rings may optionally be substituted in the same manner as the other rings present in the molecule. Z incorporates conjugated units which are preferably based on arylenes and heteroarylenes optionally linked by alkenyl (preferably vinyl) groups. The conjugation of the core may be varied both in length, with the aim to have the HOMO-LUMO energy gap lower than that of the branches as aforesaid, and in substituent pattern. This allows control of the colour of emission, from blue to red. Electron affinity can be controlled by the choice of core. When Z is an aromatic group by itself, this group is typically a benzene group other than unsubstituted benzene and preferably 3,5-disubstituted benzene , or a heteroaromatic group such as pyridine or triazine, or linked phenylene units. These rings may be substituted in the same manner as the other rings. The compounds typically have one or more end or surface groups which will be attached to the terminal ring or rings of Z. With higher-generation dendrimers (see hereinafter), the surface groups may tend to assume a majority or substantially all fo the molecular contact with the surrounding environment. Therefore, the outer surface controls the solubility and processability of the molecule in common solvents and thus changes to the internal electronic structure of the chromophore(s) can be possible • without unacceptably affecting the processing properties and vice versa. If the need arises for multilayer LEDs to be prepared, then the surface groups may be selected to allow crosslinking or appropriate solubility. The dendrimers of this invention provide an opportunity of optimising the electronic and processing properties independently which should give improved manufacturability of electronically optimised materials. Some examples of the surface groups which would be suitable to incorporate onto the dendrimers include branched and unbranched alkyl, especially t-butyl, branched and unbranched alkoxy, for example 2-ethyl-n-hexyloxy, hydroxy, alkylsilane, carboxy, carbalkoxy, and vinyl. A more comprehensive list include a further-reac table alkene, (meth)acrylate, sulphur- containing or silicon-containing group; sulphonyl group; polyether group; C,- to C 15 alkyl or alkoxy (preferably t-butyl) group; amine group; mono-, di- or tri C r to C 15 alkylamine group; -COOR group wherein R is hydrogen or C r to C 15 alkyl or alkenyl; - 0 2 SR group wherein R is C t - to -C 15 alkyl or alkenyl; -SR group wherein R is aryl, or C to -C 15 alkyl or alkenyl; -SiR 3 groups wherein the R groups are the same or different and are hydrogen C r to -C 15 alkyl or alkenyl, or -SR' group (R' is aryl or C r to -C 15 alkyl or alkenyl), aryl or heteroaryl. The most preferred surface group is t-butyl. Thus particularly preferred groups Z have the formulae shown in Figures I to 4 and 24 of the accompanying drawings. Z can also represent an aromatic group, preferably a phenyl group which can also be substituted with one or more surface groups as discussed above, Preferably, therefore, in this embodiment Z represents a 3,5-di(t-butyl) phenyl group. When Z represents an aromatic group in this way, the dendrimer will be the 0-generation dendrimer while when Z represents the value shown in Figure 1 this corresponds to generation 1 of the dendrimer. Preferred compounds of the present invention include those shown in Figures 2, 3 and 4, these being the 0- and 1 -generation, 2-generation and 3 -generation, respectively. The radii of these molecules are 10.3A, 14.6A, 19.4A and 24.0A, respectively, as estimated from gel permeation chromatography. The compound may have more than one luminescent moiety and the energy ' resulting from electrical or optical excitation is transferred to one of them for light emission. In a preferred embodiment the dendrimer incorporates at least one inherently at-least-partly-conjugated luminescent moieties which moieties may or may not be conjugated with each other, wherein the or each said dendritic structure(s) include(s) at least one of the said luminescent moieties, the luminescent moiety or moieties further from the core of the dendrimer being of larger HOMO- LUMO energy gap than the luminescent moiety or moieties closer to or partly or wholly within the core of the dendrimer. In another embodiment the HOMO-LUMO energy gap is the same. The relative HOMO-LUMO energy gaps of the moieties can be measured by methods known per se using a UV-visible spectrophotometer. One of the luminescent moieties may be, or (partly or wholly) within, the core itself i.e. the part of the molecule excluding Z, which will thus preferably have a smaller inherent HOMO- LUMO gap energy than the other luminescent moiety or moieties in the dendritic structures. Alternatively, or in addition, the dendritic structures themselves may each contain more than one luminescent moiety, in which case those further from the core will again preferably have larger inherent HOMO-LUMO gap energies than those closer to the core. In this case, the core itself need not be luminescent, although luminescent cores are generally preferred. Again any groups Y can also be luminescent. It is furthermore possible to control the electron affinity of the dendrimers by the addition to the chromophores of electron- withdrawing groups, for example cyano and sulfone which are strongly electron-withdrawing and optically transparent in the spectral region we are interested in. Alternatively the branches and/or core may contain heteroaromatic units such as pyridine, pynmidine, thiazole, triazine or fluorinated aryl or heteroaryl units to increase the electron affinity of the dendrimer. Intermolecular interactions have a strong effect on the photophysics of conjugated molecules, and the flexibility of synthesis (generation number, surface groups, linkers, etc.) will allow them to be controlled. This is believed to be a particular advantage for the efficiency of blue emission, because it will tend to prevent the blue luminescence from being quenched by excimer formation, which may render the emission yellow instead. In addition, luminescence in dyes and the like is often quenched at high concentrations, as encountered in the film. By incorporating these molecules into a dendrimer we can avoid this, for example, by avoiding processes such as pi-stacking. With dendrimers exciton migration to quenching sites can be inhibited, optimised chromophores can be used, and intermolecular interactions controlled to avoid undesirable processes such as excimer formation. In linear conjugated polymers the exciton migrates through the sample to regions of low HOMO-LUMO gap energy and can often encounter defects which quench the luminescence. Dendrimers can be designed according to the present invention so that the innermost or central chromophore has a lower HOMO-LUMO energy gap than chromophores closer to the surface. The excitations are localised on the core and migration to quenching sites is impeded. In addition, this process will tend to give rise to a space charge build-up similar to that obtained in organic light emitting devices incorporating a hole-blocking electron transporting layer. Dendrimers with electron- withdrawing groups attached to the chromophores and/or high electron affinity chromophores will be easier to prepare as the routes involve "small molecule" reactions, which do not have the same stringent requirements, for example, yield, of those for forming high polymers. The compounds of the present invention possess particular advantages over other dendrimers. In particular, they possess enhanced stability which results in devices using them to have an increased life. The compounds of the present invention can be processed in solution i.e. a solution of the compound can be applied as a layer of a display device and then the solvent evaporated. This is a much simpler procedure than vacuum deposition which is currently generally needed because individual molecular chromophores such as those included within dendrimers are not often solution processable. It has also been found that the compounds of the present invention can act both as a hole transport layer and/or as a light emitting layer, with appropriate other layers, in a display device. This naturally gives rise to increased versatility of the compounds. It has surprisingly been found that charge mobility can be controlled by altering the generation of the dendrimer. In other words by measuring the mobility of successive generations it can be readily established what generation is needed to give the desired degree of mobility. This provides a way of controlling the operating bias and current of an organic LED. The low charge mobility of some of the compounds of the present invention gives rise to increased efficiency. The dendrimers of this invention may appear fully conjugated. However, as the branch linkages are typically all meta in arrangement, the pi-electron system is not fully delocalised over the whole molecule (R.S. Kang et al, J Chem. Soc., Chem. Comm. 1996, 1167). This means that in a simple analysis the central core can be considered independently from the branches when determining the required colour of light emission and the relative energy gaps or conjugation lengths. The present invention also provides a process for preparing the compounds of the present invention which comprises reacting an aldehyde of the formula: with a Z-containing compound of the formula: TCH.-Z wherein Y, n 1 , X, x and Z are as defined above, n 3 is 0, 1 or 2, and T represents a functional group which allows the adjacent methylene group to react with an aldehyde group to form an alkene. One of skill in the art will be well aware of the functional groups which will cause the adjacent methylene group to react with the aldehyde group to form an _ alkene. Examples include phosphonium and phosphonate which is preferred i.e. the compound is (RO) 2 P(0)CH 2 Z where each R, which may be the same or different, represents an alkyl or aryl group. The precise nature of the groups R is relatively unimportant although economic considerations will affect the choice. Typically R represents an alkyl group of 1 to 6 carbon atoms such as methyl. The aldehyde starting material is typically obtained by reacting a bromide of the formula: (-Y)3 with a vinyl compound of the formula: (CH 2 =CH) n 3 -X-CHO In order to obtain the phosphonate it is possible to react the corresponding aryl methyl bromide with the corresponding phosphate. The aryl methyl bromide itself can conveniently be obtained by reducing an aldehyde of formula OCH-Z, for example with a borohydride and then brominating the corresponding alcohol. It will be appreciated that in order to obtain the 0 generation compound Z will represent an aromatic group; to obtain a generation 1 and successive generations Z represents the dendritic molecular structure. This is generally obtainable from the corresponding aldehyde. Successive generations can therefore readily be obtained. It will be appreciated that this process differs from the process disclosed in our earlier W099/21935 where the aldehyde of the dendron moiety is reacted with a functional group. In contrast, in the process of the present invention a functional group of the dendron moiety is reacted with an aldehyde moiety containing the central nitrogen atom. A particular advantage of this procedure is that, as will be appreciated, it is difficult to form the core material with, say, three phosphonate groups, let alone purify it. This applies equally to the preparation of other dendrimers which require more than 2 phosphonate groups to form a core of the type disclosed in our earlier W099/21935 i.e. it is generally much easier to prepare an aldehyde of the core moiety, especially where more than 2 dendritic structures are to be attached to it. Accordingly, the present invention also provides a process for preparing a compound of the formula: CORE - [DENDRITE] π in which CORE represents an atom or group, n represents an integer of at least 1 and DEND RITE, which may be the same or different if n is greater than 1, represents an inherently at least partly conjugated dendritic molecular structure comprising aryl and/or heteroaryl groups and alkenyl groups connected to each other via a carbon atom of an alkenyl group to a ring carbon atom of an aryl or heteroaryl group, CORE terminating in the first single bond which is connected to a ring carbon atom of an (hetero) aryl group to which more than one at least partly conjugated dendritic chain is attached, said ring carbon atom forming part of DENDRITE, the CORE and/or DENDRITE being luminescent, which comprises reacting an aldehyde of the central atom or group with an aryl or heteroaryl compound bearing a functional group which allows the adjacent methylene group to react with an aldehyde to form an alkene thus resulting in the formation of CORE-DENDRITE. CORE-DENDRITE can have any of the values disclosed in W099/21935, to which reference should be made for further details. It is particularly useful where the CORE is centered on a 1,3,5-substituted benzene ring. The dendrimers of the present invention find utility in light emitting devices (LED). Accordingly, the present invention also provides a light emitting device comprising at least one compound of the present invention. Typically the LED comprises two electrodes with 1 or more layers therebetween, at least one of said layers is, or contains, a compound of the present invention. As indicated above, a particular feature of the compounds of the present invention is that they can act both _ as light emitters and/or charge transporting layers, depending on the other materials present. Thus in a "single layer" device the compound acts as a light emitter. On the other hand, in a "bi-layer device" the compound can form a hole transporting layer together with a light emitter such as an aluminium quinolinate. Alternatively, bi- layers formed with an electron transport layer such as PBD (2-phenyl-5-biphenyl- 1,3,4-oxadiazole) which has a wide gap cause the dendrimer to act as a light emitter. On the other hand, with an organolanthanide layer emission can come from the organolanthanide and/or from the dendrimer. The general construction of the light emitting devices can be conventional although it is a particular feature of the present invention that the compounds of the present invention are solution processable such that they can be applied to the device in the form of a solution in a common solvent such as tetrahydrofuran, for example by spin coating, and then the solvent evaporated. In general the dendrimer layer will be adjacent to one electrode, typically an indium tin oxide layer, with the extra layer over it before the cathode, typically of aluminium or MgAl, layer. If desired a buffer layer, for example of poly(3,4-ethylenedioxythiophene) and polystyrene sulphonate^ can be placed between the dendrimer layer and the indium tin oxide layer. The light emitting devices of the present invention can form part of a colour display device including pixels. Indeed the compounds can be used in any semi- conductor device, for example a photodiode, solar cell, FET or solid state triode. The following Examples further illustrate the present invention. In these Examples G-O, G-l etc, indicates zero generation, 1 st generation etc. while the compounds prepared are as shown in Figures 2 to 4. Example 1 - [G-0] 3 N A mixture of l-(methylenedimethylphosphonate)-3,5-di-tert-butylbenzene (986 mg, 3.16 mmol), tris[4-(4'-formylstyryl)phenyl]amine (498 mg, 0.78 mmol) and potassium tert-butoxide (353 mg, 3.15 mmol) in tetrahydrofuran (80 cm 3 ) was stirred at room temperature under argon for approximately 16 h, giving a fluorescent yellow solution. Figure 18 shows the reaction scheme. Water (25 cm 3 ) and dichloromethane (175 cm 3 ) were added, the organic layer separated, dried over sodium sulphate, filtered, and the solvent removed to give a yellow solid residue. Purification by column chromatography, gradient eluting from dichloromethane-light petroleum (1 :4) to dichloromethane, gave [G-0] 3 N (804 mg, 86 %) as a bright yellow solid, mp 182 °C (Found: C, 90.15; H, 8.17; N, 1.20. C 90 H 99 N requires C, 90.48; H, 8.35; N, 1.17 %); λ max (CH 2 Cl 2 )/nm (logs) 241 (4.72), 341 (4.91) and 421 (5.13); δ H (400MHz, CDC1 3 ) 1.38 (54 H, s, t-Bu), 7.05 and 7.19 (6 H, ABq, J 16.5, 7',8'-H), 7.09 and 7.14 (6 H, ABq, J6, 7",8"-H), 7.14 and 7.45 (12 H, AA'BB', 2,3,5,6-H), 7.37 (3 H, dd, J 1.5, 4"-H), 7.39 (6 H, d, J 1.5, 2", 6"-H), 7.53 (12 H, AA'BB', 2'3'5'6'-H); m/z (FAB) 1194.8 (M + , 100 %). Example 2 - [G-1] 3 N A mixture of l-(methylenedimethylphosphonate)-3,5-bis(3',5'-di-tert- butylstyryl)benzene (1.19 g, 1.89 mmol), tris[4-(4'-formyl)styrylphenyl]amine (302_ mg, 0.475 mmol) and potassium tert-butoxide (212 mg, 1.89 mmol) in tetrahydrofuran (60 cm 3 ) was stirred at room temperature under argon for 14 h. The solvent was removed. Water (25 cm 3 ) and dichloromethane (50 cm 3 ) were added. The organic layer was separated, washed with brine (100 cm 3 ), dried over sodium sulphate, filtered and the solvent removed to give a yellow solid residue. Purification by column chromatography over silica, gradient eluting from dichloromethane-light petroleum (1 :4) to dichloromethane - light petroleum (1 :2) gave [G-1] 3 N (817 mg, 81 %) as a bright yellow solid, mp 238-239 °C (Found: C, 90.54; H, 8.80; N, 0.63. C 162 H I83 N requires C, 90.74; H, 8.60; N, 0.65 %); λ max (CH 2 Cl 2 )/nm (logs) 239 (4.99), 323 (5.31), 334sh (5.29) and 4.23 (5.17); δ H (400MHz, CDC1 3 ) 1.40 (108 H, s, t-Bu), 7.05-7.31 (30 H, m, vinylic-H and 2,6-H), 7.40 (6 H, dd, J 1.5,4"'-H), 7.44 (12 H, d, J 1.5, 2"', 6"'-H), 7.47 (6 H, 'ΛAA'BB', 3,5-H), 7.56 (12 H, AA'BB', 2', 3', 5', 6'-H), 7.61 (6 H, br s, 2",6"-H) and 7.64 (3 H, br s, 4"-H); m/z (MALDI) 2143.5 (M + , 100 _ %). Example 3 - [G-2] 3 N A mixture of l-(methylenedimethylphosphonate)-3,5-bis[3',5'-bis(3",5"-di-tert- butylstyryl)styryl]benzene (1.01 g, 0.80 mmol), tris[4-(4'-formyl)styrylphenyl]amine (129 mg, 0.203 mmol) and potassium tert-butoxide (93 mg, 0.829 mmol) in tetrahydrofuran (40 cm 3 ) was stirred at room temperature under argon for approximately 14 h. The solvent was removed by rotary evaporation. Water (25 cm 3 ) and dichloromethane (50 cm 3 ) were added. The organic layer was separated, washed with brine (100 cm 3 ), dried over sodium sulphate, filtered and the solvent removed to give a yellow solid residue. Purification by column chromatography over silica, gradient eluting from dichloromethane - light petroleum (1 :4) to dichloromethane - light petroleum (1 :2) gave [G-2] 3 N (611 mg, 76 %) as a bright yellow solid, mp 268 °C (Found: C, 90.58; H, 9.18; N, 0.35.£ 3 o 6 H 35. N requires C, 90.90; H, 8.75; N, 0.35 %); λ max (CH 2 Cl 2 )/nm (logε) 239 (5.25), 323 (5.73), 334sh (5.70) and 423 (5.18); δ H (400MHz, CDC1 3 ) 1.41 (216 H, s, t-Bu), 7.06-7.34 (54 H, m, vinylic-H and 2,6-H), 7.41 (12 H, dd, J 1.5, 4""-H), 7.45 (24 H, d, J 1.5, 2"", 6""-H), 7.48 (6 H, 'ΛAA'BB', 3,5-H), 7.58 (12 H, AA'BB', 2'3'5'6'-H), 7.67 (24 H, m, 2",6",2"',4'",6'"-H) and 7.71 (3 H, br s, 4"); m/z (MALDI) 4042.8 (M + , 100%). Example 4 - [G-3] 3 N Potassium tert-butoxide (171 mg, 1.52 mmol) was added to a solution of tris[4-(4'- fo__ny_)sty_ylphenyl]amine (51.5 mg, 0.074 mmol) and 1- (methylenedimethylphosphonate)-3,5-bis{3',5'-bis[3",5"-bis(3'",5"'-di-tert- butylstyιyl)styryl]styryl} benzene (759 mg, 0.30 mmol) heated at reflux. Figure 19 shows the reaction scheme. The solution immediately turned a dark red-brown colour. The mixture was heated at reflux for approximately 18 h and allowed to cool. Water (50 cm 3 ) and dichloromethane (50 cm 3 ) were added. The aqueous layer was separated and extracted with dichloromethane (2 x 50 cm 3 ). The combined organic layers were washed with brine (50 cm 3 ), dried over sodium sulphate, filtered, and the • solvent removed to leave a yellow solid. Purification by column chromatography using dichloromethane - light petroleum (2:3) as eluent, then recrystallisation from a dichloromethane-methanol mixture gave [G-3] 3 N (349 mg, 60 %) as a yellow powder, mp 266-267 °C (Found: C, 90.56; H, 9.29; N, 0.0. C 594 H 687 N requires C, 90.99, H, 8.83; N, 0.18 %); λ max (CH 2 Cl 2 )/nm (logs) 239 (5.52), 323 (6.08), 334sh (6.04) and 423.69 (5.16); δ H (400MHz, CDC1 3 ) 1.40 (432 H, s, t-Bu), 7.08-7.36 (102 H, m, vinylic-H and 2,6-H), 7.39 (24 H, dd, J 1.5, 4""'-H), 7.45 (48 H, d, J 1.5, 2"'",6'""-H), 7.50 (6 H, ' AA'BB', 3,5-H), 7.61 (12 H, AA'BB', 2',3',5',6'-H), 7.68- 7.76 (63 H, m, 2", 6", 4", 2'", 4'", 6"', 2"", 4"", 6""-H); m/z (MALDI) 7839.1 (M + , 100%). Example 1A [G-0]Phosphonate l-(methylenedimethylphosphonate)-3,5-di-tert-butylbenzene A mixture of 3,5-di-tert-butylbenzyl bromide (1.86 g, 6.57mol) and trimethylphosphite (7.6 cm 3 , 64 mmol) were stirred at 95 °C for approximately 3 h, then allowed to cool. Figure 20 gives the reaction scheme and the route to the starting material for Example 2C. The solution was diluted with ether (25 cm 3 ) and washed with water (6 x 25 cm 3 ), dried over sodium sulphate, filtered and the solvent removed to give a colourless oil which was dried under vacuum giving 1 - (methylenedimethylphosphonate)-3,5-di-tert-butylbenzene (1.82 g, 89 %) as a white crystalline solid, mp 56 °C; δ H (200MHz, CDC1 3 ) 1.33 (18 H, s, t-Bu), 3.18 (2H, d, J 21.5, 7-H), 3.66 (6 H, d, J 11, OCH 3 ), 7.15 (2 Η, br s, 2,6-Η) and 7.32 (1 H, br s, 4- H); m/z (APCI+) 313.2 (MH + , 100%) and 335.2 (MNa + , 15 %). Example 2A [G-l]Phosphonate 1 -(methylenedimethylphosphonate)-3 ,5-bis(3',5'-di-tert- butylstyιyl)benzene A mixture of 3,5-bis(3',5'-di-tert-butylstyryl)styryl]benzyl bromide (500 mg, 0.52 mmol) and trimethylphosphite (5.0 cm 3 , 38 mmol) was heated at 110 °C for 3 h. ' Methanol (100 cm 3 ) was added and water was added slowly until a precipitate was formed. The precipitate was filtered and dried under vacuum to give 1- (methylenedimethylphosphonate)-3,5-bis(3',5'-di-tert-butylstyryl)benzene (477 mg, 91 %). A sample for analysis was recrystallised from a dichlorome hane-methanol- water mixture, mp 207-208°C (Found: C, 78.24; H, 9.44. C 41 H 57 0 3 P requires C, 78.31; H, 9.14 %); v max (CHCl 3 )/cm-' 1596s (C=C), 1062 (P-O-C), 1038s (P-O-C) and 964s (C=C-H trans); λ max (CHCl 3 )/nm (logs) 308 (4.75), 3.16 (4.75) and 331sh (4.60); δ H (500MHz, CDC1 3 ); 1.38 (36 H, s, t-Bu), 1.23 (2 H, d, J22, CH 2 ), 3.72 (6 Η, d, J 1 1, OCH 3 ), 7.12 and 7.23 (4 Η, d, J 16, 7',8'-Η), 7.38 (4 H, m, 2, 6, 4'-H), 7.40 (4 H, d, J 1.5, 2',6'-H), 7.62 (1 H, m, 4-H); m/z (APCI+) 630 (MH + , 100%). Example 3A [G-2]Phosphonate l-(methylenedimethylphosphonate)-3,5-bis[3',5'-bis(3",5"-di- tert-butylstyryl)styryl]benzene A mixture of 3,5-bis[3',5"-bis(3",5"-di-tert-butylstyryl)styryl]styryl}benzyl bromide (1.24 g, 1.00 mmol) and trimethylphosphite (10 cm 3 ) was heated at 100 °C under argon for 18 h. Excess trimethylphosphite was removed by distillation under reduced pressure and the white solid residue was recrystallised from a dichloromethane- methanol mixture. Column chromatography, eluting with dichloromethane, gave 1- (methylenedimethylphosphonate)-3,5-bis[3',5'-bis(3",5"-di-tert-butylstyryl)styryl] benzene (983 mg, 78 %) as a white solid, mp >220 °C (decomp) (Found: C, 84.63; H, 9.03. C 89 H 113 P0 3 requires C, 84.72; H, 9.03 %); v^KBrycm "1 1595 (C=C), 1056 and 1028 (P-O-C) and 958 (C=C-H trans); λ max (CH 2 Cl 2 )/nm (logε) 230 (4.69) and 321 (5.24); δ H (400MHz, CDC1 3 ) 1.40 (72 H, s, t-Bu), 3.26 (2 H, d, J21.5, CH 2 P), 3.76 (6 Η, d, J 11, OCH 3 ), 7.19 and 7.30 (8 Η, ABq, J 16, 7",8"-Η), 7.27 (4 H, s, 7',8'-H), 7.40 (4 H, br s, 4"-H), 7.44 (10 H, br s, 4',2",6"-H), 7.64 (6 H, br s, 2,6,2', 6'- H) and 7.70 (1 H, br s, 4-H); m/z (CI+) 1261.8 (MH + , 100%). • Example 4A [G-3]Phosphonate l-(methylenedimethylphosphonate)-3,5-bis{3',5'-bis[3",5"- bis(3'",5"'-di-tert-butylstyryl)styryl]styryl}benzene Trimethylphosphite (5.4 cm 3 , 46 mmol) was added to 3,5-bis{3',5'-bis[3",5"- bis(3'",5'"-di-tert-butylstyryl)styryl]styryl} benzyl bromide (1.14 g, 0.455 mmol) and the suspension heated at 100 °C under argon for 2 h. Excess trimethylphosphite was removed by distillation under reduced pressure. The residue was recrystallised from a dichloromethane-methanol mixture, then further purified by column chromatography over silica using dichloromethane as eluent, giving 1 - (methylenedimethylphosphonate)-3,5-bis{3',5'-bis[3",5"-bis(3'",5'"-di-tert- butylstyryl)styryl]styryl} benzene (853 mg, 74 %) as a white solid, mp 232 °C (Found: C, 87.30; H, 9.18. C 185 H 225 P0 3 requires C, 87.90; H, 8.97); v max (KBr)/cm-' 1594 (C=C), 1059 and 1033 (P-O-C) and 960 (C=C-H trans); λ max (CH 2 Cl 2 )/nm (logs) 322 (5.59) and 334sh (5.50); δ H (400MHz, CDC1 3 ) 1.39 (144 H, s, t-Bu), 3.38 (2 H, d, J21, CH 2 P), 3.79 (6 Η, d, J 11, OCH 3 ), 7.19 and 7.32 (16 Η, ABq, J 16, 7"',8'"-Η), ~ 7.30 (4 H, s, 7, 8'-H), 7.33 (8 H, s, 7",8"-H), 7.38 (8 H, dd, J 1.5, 4"'-H), 7.44 (16 H, d, J 1.5, 2"',6'"-H), 7.48 (2 H, br s, 4'-H), 7.66 (4 H, s, 4"-H), 7.67 (8 H, s, 2",6"-FI), 7.67 (5 H, br s, 4,2',6'-H), 7.73 (2H, s, 2,6-H); m/z (MALDI) 2527.8 (M + , 100%) and 2590.7 (MCu + , 97 %). Example 2B [G-l]CH 2 Br 3,5 -bis(3',5'-di-tert-butylstyryl)benzyl bromide Phosphorus tribromide (2.8 cm 3 , 30 mmol) was added to a solution of 3,5-bis(3',5'- di-tert-butylstyryl)benzyl alcohol (1.60 g, 3.0 mmol) in dichloromethane (50 cm 3 ) and the mixture stirred at room temperature for 3 h. Propan-2-ol (14 cm 3 ) was added slowly and the solvent was completely removed. The residue was purified by column chromatography over silica, eluting with dichloromethane-light petroleum (40-60) • (1 :9), giving 3,5-bis(3',5'-di-tert-butylstyryl)benzyl bromide (1.52 g, 85 %). A sample for analysis was recrystallised from a dichloromethane-light petroleum (60- 80) mixture, mp 222-223°C (Found: C, 77.75; H, 8.72. C 39 H 5 ,Br requires C, 78.11; H, 8.57 %); v max (CHCl 3 )/cm-' 1596s (C=C) and 964s (C=C-H trans); λ max (CHCl 3 )/nm (logε) 315 (4.82); δ H (400MHz, CDC1 3 ) 1.38 (36 H, s, t-Bu), 4.55 (2 H, s, CH 2 ), 7.12 and 7.24 (4 Η, d, J 16, T, 8'-Η), 7.39 (2 H, dd, J 1.5, 4'-H), 7.41 (4 H, d, J 1.5, 2',6'- H), 7.47 (2 H, d, J 1, 2,6-H) and 7.63 (1 H, m, 4-H); m/z (APCI+) 521 ((M-Br) + , 100 %) and 599 (M + , 40 %). Example 3B [G-2]CH 2 Br 3,5-bis[3'5'-bis(3",5"-di-tβrt-butyl)styryl)styryl]benzyl bromide A solution of 3,5-bis[3'5'-bis(3",5"-di-t_rt-butyl)styryl)styryl]benzyl alcohol (2.43 g, 2.08 mmol) and phosphorus tribromide (2.0 cm 3 ) in dichloromethane (50 cm 3 ) was stirred at room temperature under argon for 46 h. Water (100 cm 3 ) was added carefully and dichloromethane (150 cm 3 ) was added. The organic layer was separated and washed with aqueous sodium bicarbonate solution (5 %, 100 cm 3 ), water (100 cm 3 ) and brine (2 x 100 cm 3 ), dried over sodium sulphate, filtered and the solvent removed. Purification by column chromatography over silica, eluting with dichloromethane, gave 3,5-bis[3'5'-bis(3",5"-di-tert-butyl)styryl)styryl]ben__yl bromide (1.43 g, 56 %) as a white solid, δ H (500MHz, CDC1 3 ) 1.41 (72 H, s, t-Bu), 4.60 (2 H, s, CHBr), 7.19 and 7.30 (8 H, ABq, J 16.5, 7", 8"-H), 7.28 (4 H, s, 7,8'- H), 7.40 (4 H, dd, J 1.5, 4"-H), 7.44 (8 H, d, J 1.5, 2",6"-H), 7.52 (2 H, d, J 1, 2,6-H), 7.64 (4 H, br s, 2',6'-H) 7.65 (2 H, br s, 4'-H) and 7.71 (1 H, br s, 4-H); m/z (FAB) 1232.5 (M + , 100%). Example 4B [G-3]CH 2 Br 5-bis{3',5'-bis[3",5"-bis(3'",5'"-di-tert-butylstyryl)styryl]styryl}benzyl bromide Phosphorus tribromide (1.2 cm 3 , 12.4 mmol) was added to a solution of 3,5- bis{3',5'-bis[3",5"-bis(3'",5" , -di-tert-butylstyryl)styryl]styryl}benzyl alcohol (3.009 g, 1.235 mmol) in dichloromethane (120 cm 3 ) and the yellow mixture stirred in the dark under argon for approximately 6 days. Water (50 cm 3 ) was added carefully, then ether (300 cm 3 ). The organic layer was washed with water (100 cm 3 ) and brine (70 cm 3 ), dried over sodium sulphate, filtered and the solvent removed. The residue was passed through a plug of silica, eluting with dichloromethane-light petroleum (2:3), giving 5-bis{3',5'-bis[3",5"-bis(3'",5'"-di-tert-butylstyryl)styryl]styryl}benzyl bromide (1.45 g, 47 %) as a white solid. A sample for analysis was recrystallised from a dichloromethane-methanol mixture, mp 256-258 °C (Found: C, 87.74; H 8.46, C 183 H 219 Br requires C, 87.97; H, 8.83); v^KBr . /cm- 1 1594 (C=C) and 960 (C=C-H trans); λ max (CH 2 Cl 2 )/nm (logε) 323 (5.54) and 334sh (5.46); δ H (400MHz, CDC1 3 ) 1.39 (144 H, s, t-Bu), 4.62 (2 H, s, CH 2 Br), 7.19 and 7.31 (16 Η, ABq, J 16, 7"',8'"- Η), 7.30 (4 Η, s, 7,8'-Η), 7.33 (8 H, s, 7",8"-H), 7.39 (8 H, dd, J 1.5, 4"'-H), 7.44 (16 H, d, J 1.5, 2"',6'"-H), 7.57 (2 H, br s, 4'-H), 7.66 (12 H, br s, 2",4",6"-H), 7.68 (4 H. br s, 2',6'-H), 7.70 (1 H, br s, 4-H) and 7.74 (2 H, br s, 2,6-H); m/z (MALDI) 2498.74 (M + , 100%). Example 2C [G-l]CH 2 OH 3,5-bis(3',5'-di-tert-butylstyryl)benzyl alcohol A mixture of 3,5-bis(3',5'-di-tert-butylstyryl)benzaldehyde (3.00 g, 6.61 mmol) and sodium borohydride (840 mg, 22.2 mmol) in tetrahydrofuran (150 cm 3 ) was heated at reflux for 110 min. The solvent was then completely removed and light petroleum (30-40) and aqueous hydrochloric acid (3 M, 30 cm 3 ) were added and stirred until effervescence had ceased. The white precipitate was then filtered and dried under vacuum to give 3,5-bis(3',5'-di-tert-butylstyryl)benzyl alcohol (2.63 g, 87 %). A sample for analysis was recrystallised from a dichloromethane-light petroleum (60- 80) mixture, mp 226-228 °C (Found: C, 87.28; H, 9.47. C 39 H 52 0 requires C, 87.26; H, 9.76 %); v^CHCy/cπr 1 3608w (OH), 1596 (C=C) and 964 (C-C-H trans); • λ max (CH 2 Cl 2 )/__m (logε) 230 (4.42), 307 (4.80), 312 (4.80), 315 (4.80) and 330sh (4.66); δ H (500MHz, CDC1 3 ) 1.41 (36 H, s, t-Bu), 1.81 (1 H, t, J6, OH), 4.79 (2 Η, d, J 6, CH 2 ), 7.16 and 7.27 (4Η, d, J 16, 7,8'-H), 7.40 (2 H, dd, J 1.5, 4'-H), 7.43 (4 H, d, J 1.5, 2',6'-H), 7.49 (2 H, s, 2,6-H) and 7.66 (1 H, s, 4-H); m/z (APCI+) 519 ((M- OH) + , 100%). Figure 21 gives the reaction scheme to produce the [G-l] phosphonate and also to the aldehyde starting material for Example 3C leading to the [G-2] phosphonate. Example 3C [G-2]CH 2 OH 3, 5-bis[3'5'-bis(3",5"-di-tert-butyl)styryl)styryl]benzyl alcohol A mixture of 3,5-bis[3'5'-bis(3",5"-di-tert-butyl)styryl)styryl]benzaldehyde (2.52 g, 2.16 mmol) and sodium borohydride (164 mg, 4.34 mmol) in tetrahydrofuran (75 cm 3 ) was heated at reflux for 40 min. Water (50 cm 3 ) and dichloromethane (100 cm 3 ) were added. The aqueous layer was separated and extracted with dichloromethane (2 x 30 cm 3 ). The combined organic layers were washed with water (100 cm 3 ) and brine (100 cm 3 ), dried over sodium sulphate, filtered and the solvent removed to leave a white solid. The residue was purified by column chromatography over silica eluting with dichloromethane, giving 3,5-bis[3'5'-bis(3",5"-di-tert-butyl)styryl)styryl]benzyl alcohol (2.43 g, 97 %) as a white solid, mp 310 °C (Found: C, 89.38; H, 9.29. C 87 H 108 O requires C, 89.33; H, 9.31); v-. KBr . /cm- 1 3567 (OH), 1595 (C=C) and 961 (C=C-H trans); λ max (CH 2 Cl 2 )/nm (logε) 230 (4.86), 322 (5.43) and 330sh (5.34); δ H (400MHz, CDC1 3 ) 1.41 (72 H, s, t-Bu), 1.78 (1 H, t, J6, OH), 4.82 (2 Η, d, J 6, 7- H), 7.19 and 7.30 (8 H, ABq, J 16.5, 7",8"-H), 7.30 (4 H, s, 7,8'-H), 7.40 (4 H, dd, J 1.5, 4"-H), 7.45 (8 H, d, J 1.5, 2",6"-H), 7.53 (2 H, br s, 4'-H), 7.65 (6 H, br s, 2,6,2',6'-H) and 7.71 (1 H, br s, 4-H); m/z (FAB) 1 169.6 (M + , 100%). Example 4C • [G-3]CH 2 OH 3,5-bis{3',5'-bis[3",5"-bis(3'",5'"-di-tert- butylstyryl)styryl]styryl}benzyl alcohol A solution of 3,5-bis{3',5'-bis[3",5"-bis(3'",5'"-di-tert- butylstyryl)styryl]sty_yl}benzaldehyde (3.853 g, 1.585 mmol) in tetrahydrofuran (50 cm 3 ) was treated with sodium borohydride (121 mg, 3.20 mmol) and heated at reflux for 135 min. The solvent was removed. Dichloromethane (50 cm 3 ) was added and the solution washed with water (50 cm 3 ) and brine (50 cm 3 ), dried over sodium sulphate, filtered and the solvent removed to leave a yellow foam. The product was purified by column chromatography over silica, eluting with dichloromethane-light petroleum (2:3). Recrystallisation from a dichloromethane-methanol mixture gave 3, 5-bis{3',5'-bis[3",5"-bis(3'",5'"-di-tert-butylstyryl)styryl]styryl}benzyl alcohol (3.07 g, 80 %) as a yellow powder, mp 248 °C (Found: C, 89.89; H, 8.89. C, 83 H 220 O requires C, 90.24; H, 9.10 %); v max (KBr)/cm- 1 3568 (OH), 1594 (C=C) and 959 (C=C-H trans); λ max (CH 2 Cl 2 )/nm (logε) 323 (5.59) and 334sh (5.52); δ H (400MHz, CDC1 3 ) 1.39 (144 H, s, t-Bu), 1.80 (1H, t, OH), 4.85 (2 Η, d, CH,OΗ), 7.19 and 7.31 (16 H, ABq, J 16, 7"',8"'-H), 7.32 (4 H, s, 7,8'-H), 7.34 (8 H, s, 7",8"-H), 7.38 (8 H, dd, J 1.5, 4"'-H), 7.44 (16 H, d, J 1.5, 2"',6'"-H), 7.57 (2 H, br s, 4'-H), 7.67 (12 H, br s, 2",4",6"-H), 7.67 (4 H, br s, 2',6'-H), 7.70 (1 H, br s, 4-H) and 7.74 (2 H, br s, 2,6- H); m/z (MALDI) 2434.94 (M + , 100%). Example ID Amine trial dehyde core tris[4-(4'-formylstyryl)phenyl]amine A mixture of tris(4-bromophenyl)amine (6.34 g, 13.1 mmol), 4-vinylbenzaldehyde (6.95 g, 53 mmol), 2,6-di-tert-butyl-p-cresol (11.57 g, 0.053 mmol), sodium carbonate (5.57 g, 53 mmol), tr rz_ , -di(μ : aceto)-bis[o-(di-_)-tolylphosphino)beι_zyl] dipalladium (II) (37 mg, 39 μmol) and N,N-dimethylacetamide (70 cm 3 ) was degassed by alternate exposure to high vacuum and purging with argon over 30 min. The mixture was heated at 130 °C under argon for 47 h, then allowed to cool. • Aqueous hydrochloric acid (3 M, 10 cm 3 ) and chloroform (150 cm 3 ) were added. The organic layer was separated and washed with water (2 x 100 cm 3 ) and brine (100 cm 3 ), dried over sodium sulphate, filtered and the solvent removed to leave an orange residue which crystallised overnight with refrigeration. The residue was recrystallised from a dichloromethane-light petroleum mixture, leaving an impure orange solid. Purification by column chromatography, eluting with dichloromethane-ethyl acetate (19:1) gave tris[4-(4'-formylstyryl)phenyl]amine (4.47 g, 53 %), mp 256-258 °C (Found: C, 84.81; H, 5.24; Ν, 2.21. C 45 H 33 Ν0 3 requires C, 85.02; H, 5.23; N, 2.20 %); v max (KBr)/cm-' 1691 (C=0); λ max (CH 2 Cl 2 )/nm (logε) 432 (4.99) and 316 (4.76); δ H (500MHz, CDC1 3 ) 7.07 and 7.24 (6 H, ABq, J 16.5, vinylic- H), 7.15 and 7.48 (12 H, AA'BB', 2,3,5,6-H), 7.64 and 7.87 (12 H, AA'BB', 2',3',5',6'-H) and 9.99 3 H, s, CHO); m/z (FAB) 635.2 (M + , 100%). The reaction scheme is shown in Figure 22. Example 5 Device fabrication Light emitting diodes (LEDs) were fabricated on indium tin oxide (ITO) substrates, which had previously been cleaned chemically (either ultrasonication in acetone and isopropanol (set A) or ultrasonication in ammonia and peroxide, subsequent baking (set B)). In all cases the dendrimers were spin-coated from tetrahydrofuran solutions of concentration 10 mg/ml. For set A a PEDOT (poly(3,4- ethylenedioxythiophene))/PSS (polystyrene sulphonate) layer was deposited onto the ITO; the dendrimer was subsequently spin coated on top of the PEDOT/PSS layer. Metal electrodes were subsequently thermally evaporated on top of the dendrimer layer. For set B the dendrimer was spin-coated onto the ITO and, if appropriate, the molecular materials were subsequently evaporated onto the dendrimer layer. For both sets, in the final step patterned metal electrodes (Al or MgAl) were evaporated onto the topmost layer. Measurements were performed in vacuum for set A and in air for set B. Single layer devices Aluminium Contacts (set A) Single layer diodes were fabricated from the compounds of Examples 1 to 4 (refened to as 0 to 3 (conesponding to [G-0] to [G-3] respectively). The electroluminescence (EL) spectra are shown in Figure 5, which show that the core of the material is a green emitter. The red tail is reduced as the generation increases. This may be due to a decrease in excimer formation or aggregation as the intermolecular interactions between chromophores are reduced with increasing generation. The current-field characteristics of the family of dendrimers are shown in Figure 6. It is seen that the operating field increases with increasing generation and increasing chromophore spacing. This suggests that the transport capabilities of the material are reduced with increasing generation, which is a useful tool for tuning mobilities and can be exploited for balancing electron and hole currents in bilayer devices. In single layer configuration, the change in device characteristics, which reflects the majority carrier properties (i.e. the hole transport properties), gives rise to a marked increase in device external quantum efficiency as measured in the forward direction, corresponding to the ratio of photons emitted to carriers injected. Figure 7 shows the increase in efficiency with generation. The device properties (maximum brightness and external quantum efficiency) are summarised in Table 1 for materials 0 and 3. Metal cathode 0 3 Al Efficiency (%) 0.00025 0.01 Brightness (Cd/m 2 ) 1 set A 16 set B MgAl Efficiency (%) 0.02 0.2 Brightness (Cd/m 2 ) 24 set B 100 set B Table 1. Comparison of single layer efficiency and brightness data. Efficiencies are given in percent photons/electrons. With the given spectral distribution of emission of these materials, efficiencies may also be quoted in Cd/A with 1 Cd/A equivalent to an efficiency of 0.4 %. It can be seen from Table 1 that not only the efficiency but also the maximum brightness depends on dendrimer generation. This is due to the large currents which are supported by the low generation materials due to extensive overlap of adjacent p orbitals and ease of current flow. However, large currents lead to ohmic heating of the material which in turn gives rise to degradation and limits the maximum achievable brightness. It is shown below that in the case of bilayer devices the improved transport properties of low generation materials can be put to use when a sufficiently high electron current is supported. Control of mobility - mobility measurements In the following the direct control of mobility through dendrimer generation is demonstrated. The mobility is measured directly by the time of flight (TOF) technique in thin layers of the film (typically 200 nm) in conjunction with a rhodamine charge generation layer. Dendrimer films are spin-coated onto ITO substrates. Subsequently a 15 nm rhodamine film (R6G) is evaporated onto the dendrimer film, followed by patterned aluminium electrodes. Charges are generated within the rhodamine layer by a 550 nm 10 ns light pulse from an optical parametric oscillator pumped by a Q-switched Nd:YAG laser and swept across the dendrimer film by the application of a DC field. The transient current is measured using a digital oscilloscope and gives information about the carrier transit times as a function of applied field. A further indirect way of estimating the mobility comes from the change of the current-field characteristics with generation. Current-field characteristics can be fitted using the barrier height to injection in a Schottky model and a field dependent mobility of the form m 0 *exp((E/E 0 ) 05 ). Values obtained by this method agree quantitatively with mobility values obtained by the TOF method as shown in Figure 8. These measurements demonstrate that it is possible to tune majority carrier (hole) mobility by up to two orders of magnitude by changing the separation between adjacent chromophores through dendron branching. The dendrimer concept hence allows independent tuning of colour and transport, where the colour is governed by the chromophore photophysical properties and the transport is controlled by the spatial separation introduced by the dendrons. In the following section the benefits of controlling mobility are demonstrated in the context of bilayer LEDs, where, depending on the desired application, either high or low mobility materials may be required. Bi-layer devices (set B) In the following the use of the family of dendrimers as hole transport layers in bilayer devices with vacuum deposited molecular materials is demonstrated. The device structure used was ITO/dendrimer/Alq3/metal. Devices were prepared as described above with vacuum deposited layers of the organic electron transporter (typically 50 nm, with dendrimer film thicknesses ~80 nm, spun at 1600 rpm). Patterned cathodes were evaporated either from aluminium or from a mixture of aluminium and magnesium. Device areas were 4 mm 2 . The chemical structure of Alq3 is shown in Figure 9. Devices with an Alq3 layer The dendrimer performed as a hole transporter in bilayers with Alq3. Emission was observed purely from the Alq layer. Table 2 summarises the results obtained for Alq3 bilayer devices. Table 2. Comparison of dendrimer/ Alq3 bilayer efficiency and brightness data. It can be seen that the efficiency is virtually independent of the metal electrode used. The lower mobility 3 gives a larger efficiency but limits the overall device current. The overall device current is also limited by the cathode, as the greatest brightness is achieved for the MgAl cathode with 0 as hole transporter. This brightness is comparable to values reported in hybrid systems with PVK (poly(vinyl carbazole)) as a hole transporting layer (Synthetic Metals 87, 175 (1997)). Figure 10 shows the current-voltage characteristics for different device configurations. It is seen that devices with 0 can support larger currents and also show lower operating biases, which is a direct result of the larger mobility of the dendrimer. A further reduction in operating bias is achieved through the change of electrode material. The corresponding voltage-brightness characteristics are shown in Figure 11 , which follow a similar pattern. The trend to higher biases with higher dendrimer generation is also observed here. The barrier for electron injection from aluminium into Alq3 appears to be a current limiting factor at lower biases. At higher biases the hole current supported by the high generation dendrimer material is current and brightness limiting, as the maximum currents and brightnesses achieved for this case are independent of the electrode. It should be noted that the barrier to hole injection remains unchanged with generation, as electrochemical studies of the dendrimers revealed no change in oxidation potential with generation. The devices are relatively stable in air, which is surprising considering the inherent instability to oxidation of many phenylene-vinylene compounds. The development of the brightness over 60 seconds is displayed in Figure 12. Commercial use of this material would involve encapsulation to extend this lifetime greatly. Bilayers with PBD as an electron transporter Devices were fabricated in the configuration ITO/dendrimer/PBD/metal. The chemical structure of PBD is given in Figure 13. In the case of bilayers with wide gap PBD, emission was observed purely from the dendrimer. The results are summarised in Table 3. Table 3. Comparison of dendrimer /Alq3 bilayer efficiency and brightness data. In comparison to single layer dendrimer emitters, the efficiency increases by a factor of 300 for 0 and a factor of 40 for 3. The maximum brightness is increased dramatically for 0 and by at least a factor of 5 for 3. It is seen that the efficiency more than doubles as the mobility of the hole transporter is decreased, but remains virtually independent of the cathode material. Also, in contrast to the devices with Alq3, the maximum brightness and current do not show a strong dependence on either generation or on cathode material. It is to be expected that the barrier for electron injection from PBD to the dendrimer is considerably larger than for Alq3, which may be a further reason for the relatively low currents and high operating fields in comparison to the Alq3 devices (see below). Devices with an organolanthanide layer Bilayer devices were also prepared with an organolanthanide layer of MeTbl3, which is a green phosphor, in the configuration ITO/dendrimer/MeTbl3/MgAl. The emission was found to come from both the organolanthanide and the dendrimer, although at high currents the dendrimer emission dominated. The EL spectrum is given in Figure 14 for a 3/MeTbl3/MgAl device at 11 V and 17 V, corresponding to currents of 75 mA and 1.4 mA. The chemical structure of MeTbl3 is shown in Figure 23. The brightnesses and efficiencies are summarised in Table 4 Table 4. Comparison of bilayer efficiency and brightness data. It is seen that the efficiency increases significantly with generation, which suggests that limiting the hole current raises the efficiency and also leads to much improved carrier confinement at the interface. Comparison of device characteristics A comparison of devices made with different electron transport layers with single layer devices as shown in Figure 15 yields valuable information on the charge carrier blocking nature or current enhancing effect of the different layers. The largest current in 3 is supported by the single layer device, which exhibits characteristics similar to the device incorporating an organolanthanide layer. The electron current supported by Alq3 clearly increases the overall device current, which leads to a significant reduction in operating bias. In contrast, the larger band gap PBD shows much poorer electron transport properties than Alq, which gives rise to overall extremely low currents, particularly at biases below 10 V. Thus PBD acts as a very efficient hole blocker which helps to accumulate holes in the dendrimer at the dendrimer/PBD interface and likewise 3 efficiently blocks electrons. The corresponding brightness-voltage characteristics are shown in Fig. 16. It is clear ' that the bilayer device using PBD is the most efficient configuration, certainly at low biases, as the light output closely follows the single layer emission, yet the current is much reduced. In the Alq3 device, the turn-on field for light emission is halved with respect to the single layer, whereas it is increased with the organolanthanide. The maximum brightnesses are all comparable, which suggests that this is a drawback of increasing efficiency through decreasing mobility. However, for many applications such as backlights, efficiency is more important than brightness, and brightnesses of 100 Cd/m 2 with good efficiencies are entirely acceptable. Extreme carrier confinement The low hole mobility of 3 and the even lower electron mobility allow for extreme carrier confinement at the interface to the larger bandgap PBD. This is demonstrated by the current- voltage characteristics of a ITO/3/PBD/MgAl bilayer device as seen in Figure 17. Currents down to 10 " " A are measured at low biases and light emission is observed for currents between 10 nA and 100 nA. This gives rise to extremely large- efficiencies, which are estimated to be up to 60 Cd/A, although this may be an overestimate due to a non-linearity of the detector at low intensities. At higher currents the device efficiency decreases steadily, but at a brightness of 55 Cd/m 2 an efficiency of 0.4 % is measured. Example 6 1 ,3,5-Tris(4-bromophenyl)benzene Silicon tetrachloride (9.7 ml, 85 mmol) was added dropwise over 15 min. to a mixture of the (partially dissolved) 4-bromophenylmethylketone (5.61 g, 28.2 mmol) in ethanol (22 ml) cooled in an ice bath. The temperature rose to 20 °C and the mixture darkened and thickened. The mixture was stirred at room temperature for 53 h (after 3 h dry THF (15 ml) was added). Water (50 ml) was then added carefully and dichloromethane (250 ml). The organic layer was separated, dried over sodium sulphate, filtered, and the solvent removed to leave a yellow solid. Recrystallisation ' from dichloromethane gave l,3,5-tris(4-bromophenyl)benzene (2.85 g, 56%) as a white crystalline solid, mp 254-255°C; 5H(200 MHz, CDC13) 7.54 and 7.62 (12H, AA'BB', 2',3',5',6'-H), 7.70 (3H, s, 2,4,6-H); m/z (CI) 541.9 (M+, 100%) - isotopic cluster of molecular ions. Tris-aldehyde benzene core l,3,5-Tris(4"-formylstilbene)benzene A mixture of 4-vinylbenzaldehyde (1.95 g, 14.7 mmol), dimethylacetamide (40 ml), l,3,5-tris(4'-bromophenyl)benzene (2.00 g, 3.68 mmol), trans-di((-aceto)-bis[o-(di-o- tolylphosphino)benzyl] dipalladium (II) (10 mg, 11m (mol), 2,6-di-tert-butyl-p-cresol (646 mg, 29.3 mmol), and sodium carbonate (1.56 g, 14.7 mmol) was degassed by sequential evacuation and purging with argon over 35 min. The mixture was then stirred at 130°C for 50.5 h. Water (100 ml) and dichloromethane (100 ml) were added. The aqueous layer was separated and extracted with dichloromethane (3 x 100 ml, 2 x 50 ml, 2 x 100 ml). The combined organic layers were washed with water (3 x 500 ml) and brine (250 ml), dried over sodium sulphate, filtered and the ~ solvent completely removed to leave a yellow/brown solid. Trituration from dichloromethane followed by recrystallisation from dichloromethane gave 1,3,5- tris(4"-formylstilbene)benzene (1.24 g, 48%) as a yellow powder, mp 163 °C (Found: C, 87.43; H, 5.36. C 51 H 36 0 requires C, 87.91 ; H, 5.21 %); vmax(KBr)/cm-l 1690 (C=0); λmax(CH2C12)/nm (logε 237 (4.46), 358 (5.10); δH(500 MHz, CDC13) 7.24 and 7.35 (6H, ABq, JAB = 16.5 Hz, vinylic H), 7.69 and 7.77 (12 H, AA'BB', 2',3',5',6'-H), 7.71 and 7.91 (12H, AA'BB', 2",3",5",6"-H), 7.86 (3H, s, 2,4,6-H), 10.07 (3H, s, CHO); m/z (CI) 697.0 (MH+, 100%). G0 Benzene- centred dendrimer. A solution of l,3,5-tris(4"-fo_τnylstilbene)benzene (350 mg, 0.50 mmol), 1- (methylenedimethylphosphonate)-3,5-di-tert-butylbenzene (628 mg, 2.01 mmol), and potassium-tert-butoxide (225 mg, 2.01 mmol) in dry tetrahydrofuran (80 ml) was stirred in the dark under argon at room temperature for 17 h. A blue fluorescent tinge appeared in the solution. The solvent was removed and dichloromethane (150 ml) and water (100 ml) were added. The organic layer was separated and washed with brine (100 ml), dried over sodium sulphate, filtered, and the solvent removed. The residue was purified by column chromatography over silica using dichloromethane/light petroleum (1.5 : 3.5) as eluent to give the GO dendrimer (520 mg, 82%) as a pale yellow powder. A sample for analysis was recrystallised from dichloromethane/methanol, mp 209 - 211 °C (Found C, 91.57; H, 8.41%. C 96 H 102 requires C, 91.81; H, 8.19%); λmax(CH2C12)/nm (logε 246 (4.81), 375 (5.39), 390sh (5.29); δH(400 MHz, CDC13) 1.39 (54 H, s, t-butyl H), 7.12 and 7.21 (6 H, ABq, 7" and 8" H), 7.22 (6 H, s, 7 and 8' H), 7.38 (3 H, m, 4" H), 7.40 (6 H, d, J=l .5 Hz, 2"' arid 6"' H), 7.57 (12 H, s, 2",3",5",6" H), 7.67 and 7.75 (12 H, AA'BB',2',3 , ,5 • ,6 , H) and 7.86 (3H, s, 2,4,6 H); m/z (MALDI) 1255.9 (MH+, 100%). Example 7 The novel dendrimer 8 and reaction scheme are shown in Figure 24. Compound 5 Gl-CH.OH 3.5-Di,4'-2"-efhylhexyloxy.phenyl ~ |benzyl alcohol A mixture of the aryl benzaldehyde (Ar-Ar Patent: Example 3: Gl-CHO: 3,5- di r4'(2 "-ethylhexyloxy .phenyll benzaldehvde (610 mg, 1.19 mmol), NaBH 4 (90 mg, 2.37 mmol), and 12.5 cm 3 of anhydrous THF was heated at reflux under argon for 5.3 h before being cooled and quenched with 5 cm 3 of H 2 0. The two layers were separated. The aqueous layer was extracted with DCM (2x4 cm 3 ). The combined DCM extracts and the organic portion were dried (MgS0 4 ). The solvents were completely removed to leave a colourless oil. The oil was purified by column chromatography using silica gel with DCM-light petroleum (1 :3 to 1:2) as eluent to give 501 mg (82%) of colourless oil of the desired alcohol (5); (Found: C, 81.4; H, 9.4 C 35 H 48 0 3 requires C, 81.4; H, 9.4%); v cm "1 (neat) 3325 (OH); λ^CH.Cy/nm 269 (ε/dn^mol-'cm- 1 65455); δ H (400 MHz; CDC1 3 ) 0.88-1.00 (12 H, m, Me), 1.29-1.62 (16 H, m, CH 2 ), 1.68-1.84 (2 H, m, 2xCH), 3.90 (4 H, m, ArOCH 2 ), 4.82 (2 H, s, ArCH 2 ), 7.00 (4 H, m, ArH), 7.50 (2 H, s, ArH), 7.58 (4 H m, ArH), and 7.66 (1 H s, ArH), NB: the OH is not easily observed; δ c (100 MHz; CDC1 3 ) 1 1.1, 14.1, 23.1, 23.9, 29.1, 30.5, 39.4, 65.5, 70.6, 114.8, 123.6, 124.6, 128.2, 133.2, 141.7, 141.8, and 159.1; m/z[MALDI] 516(M + ). Compound 6 Gl-CH 7 Br 3.5-Dir4'-f2"-ethylhexyloxy,phenyllbenzyl bromide Phosphorus tribromide (0.7 cm 3 , 7.37 mmol) was added slowly to a solution of the benzyl alcohol 5 (890 mg, 1.72 mmol) in dry DCM (37 cm 3 ) at room temperature under argon for 18 h. The mixture was diluted with water (10 cm 3 ). The organic layer was separated, washed with water (2x20 cm 3 ), brine (1x20 cm), dried over anhydrous magnesium sulfate, and the solvent completely removed to give yellowish oil. The residue was purified by column chromatography over silica with ethyl acetate-light petroleum (1 :0 to 1 :10) as eluent to give a white solid of 6 (805 mg, 81%); mp 79-79.5 °C; (Found: C, 72.6; H, 8.2 C 35 H 47 Br0 2 requires C, 72.5; H, 8.2%); λ^CH.Cy/nm 272 (ε/dm 3 mol-'cm- 1 41332); δ H (400 MHz; CDC1 3 ) 0.91- 1.02 (12 H, m, Me), 1.31-1.68 (16 H, m, CH 2 ), 1.74-1.87 (2 H, m, CH), 3.93 (4 H, m, ArOCH 2 ), 4.62 (2 H, s, ArCH 2 ), 7.03 (4 H, m, ArH), 7.53 (2 H, m, ArH), 7.59 (4 H, m, ArH), and 7.68 (1 H, m, ArH); δ c (100 MHz; CDC1 3 ) 11.1, 14.1, 23.1, 23.9, 29.1, 30.5, 33.7, 39.4, 70.6, 114.8, 125.4, 125.7, 128.2, 132.8, 138.6, 142.0 and 159.3; m/z [MALDI] 500 (M + -Br). Compound 7 Gl-Phosphonate l-(MethylenedimethylphosphonateV3.5-di 4'(2"-ethylhexyloxy)phenyl]benzene A mixture of the benzyl bromide 6 (800 mg, 1.38 mmol), and trimethyl phosphite (3.6 cm 3 , 30.5 mmol) was heated at 110°C under argon for 14 h. The mixture was allowed to cool and the excess of trimethyl phosphite was removed under vacuum. The light yellow residue was purified by column chromatography over silica gel with ethyl acetate-light petroleum (1 : 10) and then MeOH-DCM (0: 1 to 1 : 10) as eluent to give 840 mg (100%) of the Gl-Phosphonate 7 as a colourless oil; (Found: C, 72.8; H, 8.7. C 37 H 53 0 5 P requires C, 73.0; H, 8.8%); 271 (ε/dπAnol-'cm- 1 16234); δ H (200 MHz; CDC1 3 ) 0.84-1.02 (12 H, m, Me), 1.26-1.60 (16 H, m, CH 2 ), 1.68-1.85 (2 H, m, CH), 3.28 (2 H, d, 21.8 Hz, ArCH 2 P), 3.72 (6 H, d, J10.8 Hz, OMe), 3.90 (4 H, m, ArOCH 2 ), 6.99 (4 H, m, ArH), 7.42 (2 H, m, ArH), and 7.51- 7.68 (5 H, m, ArH); m/z [MALDI] 609 (MH + ). Compound 8 Gl Amine 3 Core Dendrimer A solution of Gl -phosphonate (7) (500 mg, 0.821 mmol), tris[4- (4'formyl)styrylphenyl]amine (Example ID) (131 mg, 0.205 mmol), potassium tert- butoxide (92 mg, 0.821 mmol) and anhydrous THF (22 cm 3 ) was stirred at room temperature for 14 h before being quenched with 3 cm 3 of water. The aqueous portion was separated and the organic layer was washed with brine (1 x 10 cm 3 ), dried (MgS0 4 ) and the solvent was completely removed to leave a yellow oil. The oil was purified over silica gel using ethyl acetate-light petroleum (1 : 10) as eluent to give 8 (406 mg, 95%) as a bright yellow solid; (Found: C, 86.3; H, 8.3; N, 0.8. C 150 H 171 NO 6 requires C, 86.5; H, 8.3; N, 0.7%); λ^CH^y /nm 264 (ε/dm 3 mol " 'cm- 1 150046), 287sh (133375), 345 (120870) and 424 (183389); δ H (400 MHz; CD 2 C1 2 ), 0.91-1.07 (36 H, m, 12xMe), 1.34-1.67 (48 H, m, 24xCH 2 ), 1.74-1.87 (6 H, m, 6CH), 3.96 (12 H, m, 6xAr0CH 2 ), 7.04-7.70 (69 H, ArH & vinyl H); m/z [MALDI] 2083 (M + ). Device Preparation & Results Device fabrication & measurement was carried out as for the preceding set A devices. However, in addition to single layer devices several heterolayer devices were prepared. The heterolayer devices were prepared by sequentially depositing a PEDOT/PSS film, a layer of dendrimer, a layer of dendrimer blended with PBD and then an Al cathode onto the cleaned ITO substrate. The neat dendrimer layer was spin-coated at a spin speed of 1000 m and then the blended dendrimer:PBD layer was spin-coated onto the neat dendrimer layer at a spin speed of 2000 φm. The dendrimer and dendrimer:PBD mixture were both dissolved in THF at a dendrimer concentration of 10 mg/ml. The absoφtion spectrum and PL emission spectrum of 8 are shown in Figure 25. The performance of several devices containing 8 are summarised in the table below: Spectra for the heterolayer device ITO / PEDOT / 8 / 8: PBD (1 :0.8) / Al are shown in Figures 26-28. Figure 26, shows the electroluminescent emission spectrum at different voltages of the device ITO / PEDOT / 8 / 8: PBD (1 :0.8) / Al. Figure 27 shows the current -voltage-luminescent characteristics. Figure 28 shows the current-luminance-efficiency characteristics. Spectra for the heterolayer device ITO / PEDOT / 8 / 8: PBD (1 : 1) / Al are shown in figures 29-31. Changing the concentration of PBD in the blend has increased the maximum efficiency, although decreased the maximum brightness. Figure 29 shows the electroluminescent emission spectrum at different voltages. Figure 30 shows the current -voltage-luminescent characteristics. Figure 31 shows the current-luminance-efficiency characteristics.

Claims: CLAIMS 1. A compound of the formula: where x is 3, 2 or 1 , y is 0 or 1 , n 1 and n 2 , which may be the same or different, are 0 or 1 to 3, X represents a divalent mono- or poly-aromatic and/or heteroaromatic moiety, the or each Y, which may be the same or different if x is 1, represents hydrogen or an optionally substituted hydrocarbon group, Z represents an aromatic group, or an inherently at least partly conjugated dendritic molecular structure comprising one or more aromatic and/or heteroaromatic groups and, optionally, alkenylene groups, connected to each other either directly or via a carbon atom of an alkenylene group, if present, to a ring carbon atom of an (hetero) aromatic group to which more than one at least partly conjugated dendritic chain is attached, said molecular structure being connected to the remainder of the molecule via a ring carbon atom, one or more of the (hetero) aromatic rings of the dendrimers optionally being substituted, Z and/or the remainder of the molecule, excluding any groups Y, being luminescent, with the proviso that when Z represents an aromatic group y must be 1. 2. A compound according to claim 1 which is luminescent in the solid state. 3. A compound according to claim 2 which emits light in the visible region under electrical or optical excitation. 4. A compound according to any one of claims 1 to 3 which has more than one luminescent moiety and the energy resulting from electrical or optical excitation is transferred to one of them for light emission. 5. A compound according to any one of claims 1 to 4 which has at least two inherently at-least-partly-conjugated luminescent moieties, the luminescent moiety or moieties further from the core being of larger HOMO-LUMO energy gap than the luminescent moiety or moieties closer to the core. 6. A compound according to claim 5, wherein the or each Z contains more than one luminescent moiety. 7. A compound according to claim 5 or 6 which has a luminescent moiety which is not part of Z and has a smaller inherent HOMO-LUMO energy gap than the other luminescent moiety or moieties. 8. A compound according to any one of claims 1 to 6 wherein a luminescent moiety is part of Z. 9. A compound according to claim 8 wherein the luminescent moiety or moieties further from the core have larger HOMO-LUMO energy gaps than those closer to the core. 10. A compound according to any one of the preceding claims wherein at least one surface group is attached to a distal aryl ring carbon atom of Z, said group being a further-reactable alkene, (meth)acrylate, sulphur-containing, or silicon- containing group; sulphonyl group; polyether group; C j -to-C jj alkyl group; amine group; mono- di- or tri-C^to-C^ alkyl amine group; -COOR group wherein R is hydrogen or -to-C^ alkyl; -OR group wherein R is hydrogen, aryl, or C to-C 15 alkyl or alkenyl; -0 2 SR group wherein R is -to-C^ alkyl or alkenyl; -SR group wherein R is aryl, or C r to-C 15 alkyl or alkenyl; -SiR 3 groups wherein the R groups are the same or different and are hydrogen, C to-C 15 alkyl or alkenyl, or -SR' group (R' is aryl or C 1 -to-C 15 alkyl or alkenyl), aryl, or heteroaryl. 11. A compound according to claim 10 wherein the surface group or groups is/ are t-butyl groups. 12. A compound according to any one of the preceding claims wherein Z represents a said dendritic molecular structure. 13. A compound according to any one of the preceding claims wherein the first aryl moiety of Z is a 1, 3, 5-bonded benzene ring. 14. A compound according to claim 13 wherein Z is 3,5- b_s(3\5'-di-t-buty_styryl)phenyl, 3,5-bis[3',5'- bis (3",5"-di-t- butylstyryl)styryl]phenyl or 3,5-b_s{3',5'-bis[3",5"-bis(3" ',5" '-di-_- butylstyryl)styryl]styryl}phenyl. 15. A compound according to any one of claims 1 to 5 wherein Z is not an unsubstituted benzene group. 16. A compound according to claim 15 wherein Z is a 3,5-disubstituted benzene group. 17. A compound according to claim 16 wherein Z is 3,5-di-t-butylphenyl. 18. A compound according to any one of the preceding claims wherein x is 3. 19. A compound according to any one of the preceding claims wherein n 1 and n 2 are 1. 20;- A compound according to any one of the preceding claims wherein X comprises a moiety of benzene, anthracene, pyridine, pyrimidine, triazine, thiophene, oxadiazole or coronene. 21. A compound according to any one of the preceding claims wherein X is connected to the adjacent atoms in the para position. 22. A compound according to any one of the preceding claims, incorporating one or more electron-withdrawing groups which increase its electron-transporting properties. 23. A compound according to claim 1 specifically identified herein. 24. • Process for preparing a compound as claimed in any one of the preceding claims which comprises reacting an aldehyde of the formula: with a Z-containing compound of the formula: TCH 2 -Z wherein Y, n 1 , X, x and Z are as defined above, n 3 is 0, 1 or 2 and T represents a functional group which allows the adjacent methylene group to react with an aldehyde group to form an alkene. 25. Process according to claim 24 wherein the aldehyde is obtained by reacting a bromide of the formula N _ » (-Y)3- with a vinyl compound of the formula: (CH 2 = CH) n 3 -X-CHO 26. Process according to claim 24 or 25 wherein the Z-containing compound is a phosphonate of the formula: (RO) 2 P(0)CH 2 -Z wherein each R, which may be the same or different, represents an alkyl or aryl group. 27. Process according to claim 26 wherein the phosphonate is obtained by reacting the corresponding arylmethyl bromide with the corresponding phosphite. 28. Process according to claim 27 wherein the arylmethyl bromide is obtained by brominating the corresponding alcohol. 29. Process according to claim 28 wherein the alcohol is obtained by reducing an aldehyde of formula OCH-Z. 30. A light emitting device comprising at least one compound as claimed in any one of claims 1 to 23 or one prepared by a process as claimed in any one of claims 24 to 29. 31. A device according to claim 30 wherein the compound forms a light- emitting layer. 32. A device according to claim 30 wherein the compound forms a hole- transporting layer. 33. A method of manufacturing a light emitting device which comprises applying a layer of at least one compound as claimed in any one of claims 1 to 23 or prepared by a process as claimed in any one of claims 24 to 29 as a solution to another layer of said device and evaporating the solvent. 34. A colour display device including pixels comprising one or more light emitting devices as claimed in any one of claims 30 to 32. 35. A compound as claimed in any one of claims 1 to 23 or prepared by a process as claimed in any one of claims 24 to 29 for use as a light emitting element in an electrically-actuated light-emitting diode. 36. Use of a compound as claimed in any one of claims 1 to 23 or prepared by a process as claimed in any one of claims 24 to 29 in any semiconducting device other than a light emitting device, for example, a photodiode, solar cell, FET, or solid state triode. 37. A process for preparing a compound of the formula CORE - [DENDRITE] π in which CORE represents an atom or group, n represents an integer of at least 1 and DENDRITE, which may be the same or different if n is greater than 1, represents an inherently at least partly conjugated dendritic molecular structure comprising aryl and/or heteroaryl groups and alkenyl groups connected to each other via a carbon atom of an alkenyl group to a ring carbon atom of an aryl or heteroaryl group, CORE terminating in the first single bond which is connected to a ring carbon atom of an (hetero) aryl group to which more than one at least partly conjugated dendritic chain is attached, said ring carbon atom forming part of DENDRITE, the CORE and/or DENDRITE being luminescent, which comprises reacting an aldehyde of the central atom or group with of an aryl or heteroaryl compound bearing a functional group which allows the adjacent methylene group to react with the aldehyde to form an alkene thus resulting in the formation of CORE-DENDRITE.

Inventors: BEAVINGTON RICHARD, BURN PAUL LESLIE, LUPTON JOHN MARK, SAMUEL IFOR DAVID WILLIAM, BEAVINGTON, RICHARD, BURN, PAUL, LESLIE, LUPTON, JOHN, MARK, SAMUEL, IFOR, DAVID, WILLIAM
Applicants: BEAVINGTON RICHARD, BURN PAUL LESLIE, ISIS INNOVATION, LUPTON JOHN MARK, SAMUEL IFOR DAVID WILLIAM, BEAVINGTON, RICHARD, BURN, PAUL, LESLIE, ISIS INNOVATION LIMITED, LUPTON, JOHN, MARK, SAMUEL, IFOR, DAVID, WILLIAM
Application year: 2001
Main classification: C09K11
IPC codes: C07C209, C07C211, C07C215, C07C217, C08G83, C09K11, H01L33, H01L51, H05B33