METHOD OF RADIATION TREATMENT FOR FLUOROPOLYMER MATERIALS

Abstract: A source of radiation (10, 12), particularly a pulsed accelerated electron beam, directs a beam of radiation through an irradiation chamber (14, 50). The irradiation chamber is depleted of oxygen and oxygen containing gases, such has being drawn to a vacuum of 10<-1> or greater Torr by a vacuum pump (20, 52). Particulate fluoropolymer material is entrained (36) in substantially oxygen free gas and conveyed through the irradiation chamber. The accelerated electrons break chemical bonds in the fluoropolymer particles and electrostatically charge the particles. Magnetic fields (42, 60) of different polarity rotate the charged particles such that they are irradiated from different sides. The irradiated fluoropolymer particles are cooled (24) and separated (26) from the entraining gas. The entraining gas is recirculated through pneumatic line (34) for a continuous cycle. In an alternate batch processing embodiment, the fluoropolymer material is placed in the shallow container (50) which is sealed and evacuated. The container is conveyed through the pulsed electron beam.

Description: METHOD OP RADIATION TREATMENT FOR FLUOROPOLYMER MATERIALS Background of the invention The present invention relates to a method and apparatus for irradiating fluoropolymer materials. It finds particular application in conjunction with the irradiation of polytetrafluoroethylene (PTFE) , fluorinated ethylene propylene (FEP) , and chlorotrifluoroethylene (CTFE) to degrade their mechanical properties. It is to be appreciated, however, that the present application is also applicable to the radiation treatment of other polymeric materials to alter chemical resistance, electrical properties, thermal stability, surface properties, and other characteristics. Finally, milled PTFE is used as a common additive to inks and to lubricants. However, PTFE is an extremely tough material with very strong bonds. It is extremely difficult to mill into a fine powder. In order to facilitate the milling process, radiation has been used to break chemical bonds in the PTFE polymer chains. In one technique, Teflon material was placed in open containers in a cobalt.60 ( 60 Co) vault. Gamma rays from the cobalt 60 irradiated the PTFE for a duration which weakened the bonds sufficiently, typically on the order of several hours. In another technique, PTFE material, in granules, sintered shavings, or other thin, small pieces was placed in an open tray. The tray was passed slowly through an accelerated electron beam irradiating the PTFE material. The product was raked or stirred and passed through the electron beam again. These techniques have several drawbacks. First, a significant quantity of hydrogen fluoride (HF) gas is released into the atmosphere. Hydrogen fluoride is highly corrosive and toxic to workers in the environment. Other toxic and corrosive gases, including fluorene, are also released. Further, treatment of PTFE in open containers releases PTFE dust into the environment which settles on walkways and other surfaces. PTFE is an extremely slippery lubricant creating fall and other injury hazards to workers. Moreover, the PTFE dust in the environment can be breathed by the workers. The present invention contemplates a new and improved fluoropolymer material irradiations apparatus and method which overcomes the above referenced problems and others . Summary of the invention In accordance with one aspect of the present invention, a method of irradiating fluoropolymer material is provided. The method includes removing oxygen and oxygen containing gases from an irradiation zone to create an oxygen and oxygen containing gas depleted environment and passing fluoropolymer material through the irradiation zone. At least one of magnetic and electromagnetic fields is applied across the irradiation zone. An accelerated electron beam is pulsed on and off through the irradiation zone, thereby providing alternate irradiation and cooling periods for the fluoropolymer. In accordance with another aspect of the present invention, an apparatus for irradiating fluoropolymer materials is provided. A pulsed electron accelerator generates a pulsed electron beam through an irradiation zone, wherein is located fluoropolymer material. A vacuum pump draws down oxygen and oxygen containing gases from the irradiation zone. At least one of magnets and electromagnetic coils is disposed adjacent the irradiation zone for reorienting the fluoropolymer material. One advantage of the present invention is that it reduces the generation of toxic and corrosive gases. Another advantage of the present invention is that it reduces and substantially eliminates the distribution of dust and toxic substances into the environment. Another advantage of the present invention resides in improved worker safety. Still further advantages and benefits of the present invention will become apparent to those of ordinary skill in the art upon reading and understanding the following detailed description of the preferred embodiments. Brief Description of the Drawings The invention may take form in various components and arrangements of components, and in various steps and arrangements of steps. The drawings are only for purposes of illustrating preferred embodiments and are not be construed as limiting the invention. FIGURE 1 is a diagrammatic illustration of a fluoropolymer material irradiation system in accordance with the present invention; FIGURE 2 is an alternate embodiment of a fluoropolymer irradiation system; and, FIGURE 3 is a graphic illustration of fluorine gas evolution rate versus radiation dose in air at atmospheric pressure and at vacuums of 10 "1 to 10 "5 Torr. Detailed Description of the Preferred Embodiments A particle accelerator 10 accelerates electrons, preferably in the 1-15 MeV range. A beam of the electrons are conveyed to a scan horn 12 which fans the electron beam out over an elongated region. An irradiation treatment chamber 14 is mounted immediately contiguous to the scan horn to receive the electron beam. Preferably, the irradiation chamber has a height and width which are commensurate with height and width of the fanned electron beam from the scan horn. To minimize electron beam losses, the scan horn and irradiation chamber are separated only by a thin foil layer, preferably aluminum foil. The irradiation chamber 14 is interconnected with a vacuum pump 20 which removes air from the irradiation chamber. Preferably, the vacuum pump draws a vacuum on the order of 10 "1 to 10 "3 Torr. The irradiation chamber is also connected with a source 22 of fluoropolymer material. Preferably, the fluoropolymer material is in particulate, shaving, or flake form. The fluoropolymer material moves through the evacuated treatment chamber 14 at a controlled rate. Preferably, the material has a dwell time in the irradiation chamber of about one minute. On impact, the charged electrons not only break chemical bonds but also impact an electrical charge to the dielectric fluoropolymer particles. After the fluoropolymer material has passed through the irradiation chamber, it passes through a cooler 24 which removes heat accumulated during the irradiation process. Cooling reduces the amount of gases generated. That is, at higher temperatures, particularly above about 110QC, the rate at which toxic gases are generated increases. The cooled and irradiated material passes to a separator 26, such as a cyclone separator, where it is deposited. The separator includes a vacuum sealed valve, such as a rotary pocket valve 28 through which accumulated irradiated fluoropolymer material is passed for receipt and appropriate packaging. More specifically to the preferred embodiment, a valve 30 in one position connects an outlet port of the vacuum pump 20 through a filter and toxic gas recovery system 32 to the atmosphere while the system is drawn down to the preferred pressure level. After the system is drawn down to the preferred pressure level, the valve 30 connects the pump 20 to a pneumatic return path 34 extending to the fluoropolymer material source 22 to make a closed loop pneumatic path. The valve 30 can be operated intermittently to maintain the vacuum in the pneumatic path. An entraining mechanism 36 entrains the material into the low level of recirculated gas. The entraining mechanism may include, for example, a rotary pocketed vacuum valve 38 for passing the fluoropolymer material at a metered rate into the vacuum side of the system. A nozzle or venturi type arrangement 40 assists in entraining the material particles into the moving gas. In order to agitate or stir the material particles as they pass through the reaction chamber, a series of magnets 42 of alternating polarity line the walls of the irradiation chamber. As each charged fluoropolymer particle moves into an opposite polarity region, the electromagnetic forces flip its orientation. The magnets are preferably strong magnets such as samarium cobalt or barium permanent magnets. Alternately, electrical coils can be placed on sides of the irradiation chamber to turn the electrostatically charged particles by electric field changes. Agitation can also be provided mechanically by baffles in the chamber 14. Various alternate techniques are also contemplated for moving the material through the treatment chamber 14. For example, the material can be moved through the chamber with a mechanical conveyor, such as a belt or auger. As another example, the particles can fall by gravity. As yet another example, the material can be formed into ribbons or tubes that are pulled through the evacuated chamber. Numerous other conveying techniques will be apparent to those of ordinary skill in the art. With reference to FIGURE 2, in a batch- processing embodiment, fluoropolymer material in particulate or flake form is placed in a relatively flat, wide container 50 which is sealed to the environment. The container is connected to a vacuum pump 52 which draws a vacuum therein, again preferably on the order of 10 "1 Torr or less. After evacuation, the container 50 is preferably disconnected from the vacuum pump. The evacuated container is placed on a flat belt or other conveyer system 54 for carrying the conveyer below a ceiling mounted scan horn 56. The container is passed through the beam one or more times until a selected dose is achieved. A pulsed particle accelerator 58 again accelerates particles which are focused and aimed by the scan horn through the material in the container 50. Electrical windings or magnets 60 of alternating polarity are disposed adjacent the scan horn for stirring or agitating particles in the container 50. Optionally, a cooling system 62 is placed below the belt to cool the material that has been heated by the electron beam. Preferably, the electron beam has an energy in the 1-5 MeV range. The container is moved back and forth until the Teflon particles have received about 30-150 Mrad of radiation, more preferably 100-120 Mrad. This can typically be achieved with a total cumulative radiation time of about one minute. The fluoropolymer materials have long fluorocarbon chains which are broken by the oxidizing effect of the electrons into smaller chains and chain segments including some short C 2 F 4 chain segments. In the ionizing environment of the irradiation chamber, some of the short chains degrade into free or reactable carbon and fluorine molecules. C 2 F 2 »> 2C + 2F Analogously, water vapor in environmental air is also ionized: H 2 0 + e " = OH + H The free hydrogen and fluorine react to form hydrogen fluoride: F + H = HF The remaining carbon and hydroxide radicals react to form carbon dioxide and hydrogen gas. Analogously, other C 2 F 4 radicals react directly with oxygen from the air and free hydrogen from ionized water vapor to form -CF 2 COOOH + HF. By removing the oxygen and water vapor by drawing a significant vacuum, the amount of oxygen and water vapor available to engage in the reactions which form hydrogen fluoride are greatly reduced, greatly reducing the generation of hydrogen fluoride. Even if a small amount of hydrogen fluoride and fluorine gases are still generated, such gases continue to be circulated through the system. A rise in the pressure due to these gases does not increase the generation of hydrogen fluoride or fluorine, so long as oxygen and water vapor are not introduced into the system. Alternately, rather than maintaining a vacuum, the system can be evacuated of oxygen and water vapor and replaced with an inert gas or other gas which does not adversely interact with fluoropolymer materials to form hydrogen fluoride or other toxic gases. Optionally, other forms of radiation can be utilized, including gamma rays and higher energy x-rays. However, being lower in energy than the electron beam, gamma and x-radiation will require longer irradiation times to achieve the same degree of treatment. The electron beam is preferably pulsed. Pulsing the electron beam provides alternate irradiation and cooling periods for the treated particles. Typically, the electron beam is scanned back and forth across the scan horn. The scanning, again provides intermittent irradiation or alternating irradiation and cooling periods. Typical - e-beam radiation settings include 1.0-5.0 MeV electron beam with a pulsed beam current of 1-5 kA and a pulse duration of 10-500 n sec. Although a vacuu of 10 "1 to 10 "3 Torr is preferred, higher vacuums achieve a further reduced rate of hydrogen fluoride and fluorine gas generation. With reference to FIGURE 3, curve 70 illustrates the rate of fluorine gas generation in milligrams per MGy of radiation dose in air at atmosphere pressure and at various vacuum levels. Curve 72 illustrates the generation rate of hydrogen fluoride versus dose for 10 "1 Torr vacuum levels; curve 74 for 10 "2 Torr; curve 76 for 10 "4 Torr; and curve 78 for 10 "5 Torr. It will be noted that while 10 "1 torr produces satisfactory results, results at 10 "2 torr are again significantly improved with a gas generation at lO " " 4 torr or lower greatly improved.

Claims: Having thus described the preferred embodiments, the invention is now claimed to be: 1. A method of irradiating fluoropolymer material characterized by: removing oxygen and oxygen containing gases from an irradiation zone (14, 50) to create an oxygen and oxygen containing gas depleted environment; passing fluoropolymer material through the irradiation zone; applying at least one of magnetic and electromagnetic fields across the irradiation zone; and pulsing an accelerated electron beam on and off through the irradiation zone, thereby providing alternate irradiation and cooling periods for the fluoropolymer. 2. The method as set forth in claim 1, further characterized by the pulsing step including: accelerating electrons; and directing the accelerated electrons through the irradiation zone to break chemical bonds in and electrically charge the fluoropolymer material, the at least one of the magnetic and electromagnetic fields interacting with the charged fluoropolymer material to agitate the material in the irradiation zone. 3. The method as set forth in either one of preceding claims 1 and 2, further characterized by the removing step including: removing air and water vapor from the irradiation zone. 4. The method as set forth in any one of preceding claims 1-3, further characterized by the removing step including drawing a vacuum in the irradiation zone. 5. The method as set forth in claim 4 , further characterized by: the vacuum being at least 10 "1 Torr. 6. The method as set forth in claim 4, further characterized by: the vacuum being at least 10 "4 Torr. 7. The method as set forth in any one of preceding claims 1-6, further characterized by: cooling the irradiated polymeric material. 8. The method as set forth in any one of preceding claims 1-7, further characterized by: entraining the fluoropolymer material in a gas which is depleted of oxygen and oxygen-containing gases and passing the gas and entrained fluoropolymer material through the irradiation zone; after passing the entrained fluoropolymer material through the irradiation zone, separating the fluoropolymer material from the gas; and recirculating the gas to entrain more fluoropolymer material. 9. The method as set forth in claim 8, further characterized by: the step of pulsing an accelerated electron beam electrostatically charging the fluoropolymer material: the at least one of magnetic and electromagnetic fields rotating the charged material magnetically or electrostatically; and the method further including: irradiating the charged rotating material with additional pulses of electrons. 10. An apparatus for irradiating fluoropolymer materials characterized by: a pulsed electron accelerator (10, 58) for generating a pulsed electron beam through an irradiation zone, wherein is located fluoropolymer material; a vacuum pump (20, 52) for drawing down oxygen and oxygen containing gases from the irradiation zone; at least one of magnets (42) and electromagnetic coils disposed adjacent the irradiation zone for reorienting the fluoropolymer material. 11. The apparatus as set forth in claim 10, further characterized by: a source (22) of fluoropolymer material for supplying fluoropolymer material to the irradiation zone. 12. The apparatus as set forth in either one of preceding claims 10 and 11, further characterized by: a cooler (24, 62) for cooling the material which has been irradiated in the irradiation zone. 13. The apparatus as set forth in any one of preceding claims 10-12, further characterized by: a scan horn (12, 56) which fans the electrons into an electron beam directed into the irradiation zone. 14. The apparatus as set forth in any one of preceding claims 10-13, further characterized by: an entraining mechanism (36) for entraining particulate fluoropolymer material into a stream of oxygen depleted gas; a pneumatic conduit for conveying the entrained fluoropolymer material from the entraining mechanism to the irradiation zone; a separator (26) disposed downstream from the irradiation zone for separating the fluoropolymer material from the entraining gas; another pneumatic conduit (34) which conveys gas from the separator back to the entraining mechanism; and a pump (20) for circulating the gas. 15. The apparatus as set forth in claim 14, further characterized by: a chiller (24) disposed between the irradiation zone and the separator. 16. The apparatus as set forth in any one of preceding claims 10-15, further characterized by: the vacuum pump (20) drawing a vacuum of at least 10 "1 Torr on the irradiation zone. 17. The apparatus as set forth in any one of preceding claims 10-16, further characterized by: a conveyor (54) for conveying the irradiation zone through the electron beam.

Inventors: KORENEV SERGEY ALEXANDROVICH, KRIEBEL JERRY, MASEFIELD JOHN, KORENEV, SERGEY, ALEXANDROVICH, KRIEBEL, JERRY, MASEFIELD, JOHN
Applicants: STERIS INC, STERIS INC.
Application year: 2001
Main classification: B29B13
IPC codes: B29B13, B29C35, B29K27, C08F2, C08J7