Anti-microbial enhanced knit fabric

Abstract: A composite textile fabric for removing moisture from the skin is provided. The composite fabric includes an inner, first fabric layer comprising either a polyester, polypropylene, acrylic or nylon yarn material which is naturally, or has been rendered, hydrophilic and an outer, second fabric layer incorporating either a moisture-absorbent material such as cotton or a synthetic yarn which has been rendered hydrophilic, or a combination thereof. The first and second fabric layers are formed concurrently by knitting a plaited construction. The second fabric layer, but not the first layer, is treated with an anti-microbial composition. An elastomeric yarn material may be added to both layers so that the composite fabric is stretchable.

Description: BACKGROUND OF THE INVENTION This invention relates to a composite textile fabric, and more particularly, to a composite fabric comprising first and second fabric layers, in which the first, or inner fabric layer, the layer closer to the skin of the wearer, is made from a synthetic yarn, and the yarn of the second, or outer fabric layer, the layer further from the skin of the wearer, is treated with an anti-microbial composition. The yarn of the second or outer fabric layer may additionally be blended with fibers treated to have anti-microbial properties. Most textile fabrics are likely to result in the substantial enclosure of moisture between the wearer's skin and undergarments or between the undergarments of the wearer and the outerwear due to perspiration of the wearer. When moisture saturation takes place, the body of the wearer is wetted, causing the wearer to feel uncomfortable. U.S. Patent No. 5,312,667, owned by Malden Mills Industries, Inc., describes a composite textile fabric with a first layer made of either polyester or nylon material, and a second layer having a substantial portion of a moisture absorbent material, such as cotton. U.S. Patent No. 5,547,733, also owned by Malden Mills Industries, Inc., describes a composite textile fabric that includes an inner fabric layer made of a yarn comprising a plurality of fibers, primarily of polyester, which have been rendered hydrophilic, and an outer fabric layer made of a yarn comprising a plurality of fibers, primarily of polyester, which have also been rendered hydrophilic. For each of these patented textile fabrics, the two fabric layers are formed concurrently by knitting a plaited construction so that the layers are distinct and separate yet integrated one with the other. While the textile fabrics described in both of these Maiden Mills patents are advantageous, they are less than desirable. In each of these textile materials, liquid sweat migrates from the inner layer to the outer layer. During migration, the oily mixture of lipids and proteins which is secreted by the wearer migrates along with the liquid sweat. As a result of bacterial decomposition of these lipids and proteins, which become concentrated mainly in the outer layer of the textile fabric, an odour commonly called "body odour" is often produced. Accordingly, it would be desirable to provide a textile fabric which facilitates liquid moisture transport to promote evaporation and keep the wearer dry, but which also substantially prevents the production of body odour. EP 1013809 describes a composite textile fabric for removing moisture away from the skin. The composite fabric includes a first fabric layer and a second fabric layer, which are formed concurrently by knitting a plaited construction. Exclusively the second fabric layer is blended with treated synthetic fibres having anti-microbial properties. US 4343853 describes a fabric construction having a backing fabric and a face fabric. At least one of the fabrics is made in part of yarns which have incorporated therein an anti-microbial agent. A tie yarn may join the two faces in plaited relation. SUMMARY OF THE INVENTION Generally speaking, in accordance with the invention, a composite textile fabric for moving liquid moisture away from the skin and evaporating that moisture from the surface of the fabric's outer layer is provided. The composite fabric includes a first or inner fabric layer, being the layer closer to the wearer's body, made of a synthetic yarn material which is naturally or has been chemically rendered to be hydrophilic, and a second or outer fabric layer, being the layer further from the wearer's body, made of a yarn material selected from the group consisting of a moisture-absorbent yarn material such as cotton, or a synthetic yarn material, such as polyester, polypropylene, acrylic or nylon, which has been rendered hydrophilic, or a combination thereof. The inner fabric layer and outer fabric layer are formed concurrently by knitting a plaited construction so that the layers are distinct and separate, yet integrated with one another. The Washburn equation (see E.A. Wulkow and L.C. Buckles, Textile Research Journal, 29:931 et seq., 1959), h = 2ycosê/rpg where h vertical height of wicking, y = surface tension of the liquid, ê = contact angle, r = radius of the tube, p = density of the liquid, and g = gravitational acceleration. This "wicking" is the result of capillary action and is enhanced the finer the denier of the fiber of the outer fabric layer and the greater the difference in denier between the yarn fibers of the two layers. In addition, the denier of the yarn (as opposed to the denier of the yarn fibers) of the inner fabric layer is no greater than the denier of the yarn of the outer fabric layer. This facilitates the horizontal spread of liquid moisture in the outer fabric layer so that moisture is more evenly distributed along this layer, as described by Hollies and his co-workers (see N. Hollies and M. Kaessinger, Textile Research Journal. 26:829-835, 1956 and 27:8-13, 1957), S 1 = ycosê A r x t/2n where S 1 = horizontal distance travelled in time t, y = surface tension of the liquid, r x = effective radius, ê A = an apparent advance contact angle, n = viscosity of the liquid, and t = time. This in turn, further facilitates rapid evaporation of the moisture from the outer layer. The coarser yarn of the outer fabric layer increases that layer's liquid holding capacity and therefore the "sink effect" of the outer fabric layer which, in turn, facilitates rapid transfer of the liquid moisture from the wearer's skin through the inner fabric layer to the outer fabric layer. According to the invention an anti-microbial composition is applied to the outer layer of the inventive textile fabric construction. The composition may be in the form of a paste or coating. Significantly, fibers which have been treated to have anti-microbial properties may be blended in the yarn of the outer layer of the inventive textile fabric construction. Accordingly, any oily mixture of lipids and proteins that is secreted by the wearer, and then migrates with the liquid sweat from the wearer's skin through the inner layer, ultimately collects in the outer layer of the fabric, does not decompose, and the production of body odour is therefore substantially prevented. Preferably, the fibers which have been treated to have anti-microbial properties are selected from nylon or other man-made fibers coated with silver, copper or zinc metal (or ions of any thereof). Alternatively, the blended synthetic yarn may have ionic silver or copper embedded therein. These fibers are blended with the yarn material of the second or outer fabric layer in an amount between about 0.5 and 50 weight percent, preferably between about 0.5 and 30 weight percent. The yarn blended with the treated fiber may be knit into every course of the construction for the highest degree of anti-microbial effect, every other course, every third course, and so on, to vary the level of anti-microbial effect that is desired. Significantly, fibers which have been treated to have anti-microbial properties are not blended in the yarn of the inner fabric layer. Neither is the inner fabric layer coated with an anti-microbial paste or coating. This is important since there is no advantage to interfere with bacterial growth next to the skin of the wearer. Bacterial growth, per se, is not harmful. Accordingly, it is an object of the invention to provide an improved composite textile fabric for enhancing the transport of liquid moisture away from the skin. It is also an object of the invention to provide an improved composite textile fabric having a plurality of synthetic yarn fibers for conducting liquid moisture. Another object of the invention is to provide an improved composite textile fabric which includes plaited layers for promoting the moisture concentration gradient therebetween. A further object of the invention is to provide a composite textile fabric which includes an outer moisture absorbent layer and an inner layer made from a synthetic yarn which has been rendered hydrophilic. Yet another object of the invention is to provide a composite textile fabric which includes an elastomeric yarn to render the fabric stretchable. Still another object of the invention is to provide a composite textile fabric in which some of the fibers used to produce the fabric have anti-microbial properties. Yet a further object of the invention is to provide a composite textile fabric which inhibits bacterial proliferation in the outer fabric layer. Still a further object of the invention is to provide a composite textile fabric which substantially prevents the production of body odour. Still other objects and advantages of the invention will in part be obvious and will in part be apparent from the following description. The invention accordingly comprises fabric and fabric materials having the features, properties and relation of constituents which are exemplified in the following detailed disclosure, and the scope of the invention will be indicated in the claims. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT The composite textile fabric of the invention includes a first or inner fabric layer, being the layer closer to the wearer's body, made of a synthetic yarn material and a second or outer fabric layer, being the layer further from the wearer's body, made of a yarn material selected from the group consisting of a moisture-absorbent yarn material, or a synthetic yarn which has been rendered hydrophilic, or a combination thereof. Both fabric layers are formed concurrently by knitting a plaited construction so that the layers are distinct and separate, yet integrated one with the other. The amount of each fabric layer is selected based on the desired weight of the composite fabric, the use of the composite fabric, and the specific requirements for transferring moisture from the inner fabric layer to the outer fabric layer. In accordance with the invention, the construction of the composite fabric is such that it is plaited. Although each fabric layer is distinct and separate, each is integrated with the other. As a result, the composite fabric functions as a single unit. The composite fabric is either a warp or a weft knit, including circular knits such as 2-end fleece, 3-end fleece, terry with regular plaiting, double terry, double needle raschel, double knit, plaited jersey and tricot. Significantly, the denier of the yarn fibers (as opposed to the denier of the yarn) of the inner fabric layer is preferably at least as great as, and more preferably greater than, the denier of the yarn fibers of the outer fabric layer. This facilitates the transport of liquid moisture which collects on the inner fabric layer to the outer fabric layer. When moisture collects on the first or inner fabric layer, since the denier of the inner layer yarn fibers is at least as great as the denier of the outer layer yarn fibers, and therefore, the inter-fiber space in the yarn of the inner fabric layer is the same as or greater than that of the outer fabric layer yarn, the quick transfer of moisture from the first layer to the second layer due to capillary action is facilitated. Also of significance is the fact that the denier of the yarn (as opposed to the denier of the yarn fibers) of the inner fabric layer is preferably no greater than the denier of the yarn of the outer fabric layer. This provides for a greater liquid capacity in the outer layer than in the inner layer and facilitates the horizontal spreading of moisture along the outer fabric layer - in other words, moisture collected by the inner fabric layer is transferred to the outer fabric layer and more evenly distributed on the outer fabric layer. Overall moisture is more rapidly transported from the inner fabric layer to the outer fabric layer of the composite textile fabric, since there is a lesser build-up of moisture in specific fabric locations in the outer fabric layer as a result of the facilitated spreading along the outer fabric layer. Also, because the yarn of the outer fabric layer is coarser than the yarn of the inner fabric layer, the likelihood of a "sink effect" in the outer fabric layer is increased and the likelihood of liquid moisture back-up into the inner fabric layer, where it would wet the skin of the wearer, is reduced. More specifically, the yarn fibers of the inner fabric layer are preferably in a range of between about 0.3 and 5.0 denier, and the yarn fibers of the outer fabric layer are preferably within a range of between about 0.03 denier and 2.5 denier. The denier of the yarn (itself) of the outer fabric layer is preferably in a range of between about 70 denier and 600 denier, while the denier of the yarn of the inner fabric layer is preferably in a range of between 30 denier and 300 denier. The second or outer fabric layer, as stated above, may be made entirely of a synthetic yarn material, or a moisture absorbent yarn material, or it may be a blend of the two. It may also include an elastomeric yarn material plaited therein. If a moisture absorbent yarn material is included in combination with a synthetic yarn material, the moisture-absorbent yarn material is preferably present in an amount of at least 3 percent by weight, and more preferably in an amount of at least 50 percent by weight, and the synthetic yarn material will have been rendered hydrophilic. The preferred moisture-absorbent material is cotton, as it can absorb 2 to 3 times its weight in water. Other suitable moisture-absorbent materials include rayon and wool, as well as other natural fibers. Alternatively, the second or outer fabric layer is made entirely from a synthetic yarn material, such as nylon or polyester, which has been rendered hydrophilic. The first or inner fabric layer may comprise either polyester, polypropylene, acrylic or nylon material which is or has been rendered hydrophilic. It may also include an elastomeric yarn material plaited or commingled therein. The surface of the first fabric layer may be raised. This is achieved by either sanding, brushing or napping. In the preferred embodiment, the first fabric layer comprises a raised surface fabric, with each fiber end being a conductor of moisture. Alternatively, the first or inner fabric layer may have a flat surface. The first or inner fabric layer may utilize a fiber with a modified cross-section or it may be chemically treated so that it is rendered hydrophilic, as described in U.S. Patent No. 5,312, 667, which is hereby incorporated in its entirety by reference. If the second or outer fabric layer comprises a synthetic yarn material which has been rendered hydrophilic, the denier per fiber will be smaller than the denier per fiber of the yarn in the first or inner fabric layer. This is also achieved as described in U.S. Patent No. 5,312,667. The yarn of the second or outer fabric layer may be spun, multi-filament, textured, end-in-end, or any combination thereof. In the embodiment in which the second or outer fabric layer comprises a moisture-absorbent yarn material, transport of water from the surface of the first or inner fabric layer to the moisture-absorbent second or outer fabric layer is enhanced due to the first fabric layer being rendered hydrophilic. In particular, liquid moisture is made readily transportable along the surface of each polyester, acrylic or nylon fiber. In the embodiment in which both the yarns of the first and second fabric layers are synthetic materials and are naturally, or are rendered, substantially hydrophilic, the transfer of liquid moisture from the surface of the first or inner fabric layer to the second or outer fabric layer is also enhanced. Particularly, liquid moisture is made transportable along the surface of each fiber of the first or inner fabric layer. Moisture that has been conducted to the second or outer fabric layer spreads along the surface of that layer, and is rapidly evaporated, enabling the outer fabric layer to remain substantially dry. A composition having anti-microbial properties is applied exclusively to the outer layer of the inventive fabric. The composition, which may be in the form of a paste or coating, preferably includes at least one of particulate silver, copper, zinc, or ions of any thereof. These particles are preferably incorporated into the composition in an amount between about 0.01 and 50 percent by volume. The particles may be suspended in the composition. Appropriate pastes or coatings are readily available in the marketplace. The amount of the coating or paste which is applied to the outer layer of the fabric is preferably between about 0.01 and 75 percent o.w.f. The main component of the composition (called the vehicle), into which the particles are incorporated, may be polyurethane, acrylic or silicone polymers. The composition may be hydrophilic such as by selecting polymers that are hydrophilic or may be rendered hydrophilic by subsequent treatment, following application to the second layer. In order to improve fabric breathability, the composition may be an aerated material selected from a foam or a froth. It may be aerated prior to application to the fabric; it may also be applied to the outer fabric layer in a pattern or design having uncoated areas. In general, application of the composition to the outer layer of the fabric is carried out with a roller, plain or rotogravure, a knife or by any other conventional coating technique. Application may also be carried out by screen printing. In accordance with the inventive composite textile fabric, fibers treated to have anti-microbial properties may be blended exclusively in the yarn of the outer fabric layer. These fibers may be selected from nylon or other man-made fibers treated with at least one of silver, copper or zinc metal (or ions of any thereof) preferably physically or chemically bonded thereon or therein. Nylon that is physically or chemically bonded with ionic silver or copper is preferred and is available in the marketplace. Nylon which has ionic silver or copper embedded within the fiber is also available in the market place. The silver, copper, zinc or ions of any thereof may alternatively be embedded in the fibers. Whether the nylon or other synthetic yarn is either coated with ionic silver or copper, or has one of these substances embedded therein, the amount of this special fiber that is blended into the yarn of the second layer is preferably between about 0.5% and 50% by weight. Testing of composite textile fabrics in which the second or outer fabric layer has incorporated therein nylon or another synthetic yarn coated or imbedded with ionic silver or copper demonstrates that bacterial proliferation in the second layer is substantially inhibited. As a result, any oily mixture of lipids and proteins that has been secreted and which has migrated with liquid sweat from the wearer's skin through the inner layer, ultimately collecting in the outer layer of the fabric, does not decompose, and the production of body odour is substantially prevented. Thus, the inventive fabric, because there is nothing interposed between the first and second fabric layers, rapidly moves moisture away from the skin and through a garment made with the composite fabric, enhanced by the creation of a moisture concentration gradient. In addition, because the second fabric layer incorporates fibers with anti-microbial properties, bacterial growth in that layer is substantially inhibited, and therefore, body odour is materially prevented. It will thus be seen that the objects set forth above, among those made apparent from the preceding description, are efficiently attained, and since certain changes may be made in the textile fabric described herein without departing from the spirit and scope of the invention, it is intended that all matter contained in the above description shall be interpreted as illustrative and not in a limiting sense. It is also to be understood that the following claims are intended to cover all of the generic and specific features of the invention described herein, and all statements of the scope of the invention which, as a matter of language, might be said to fall therebetween.

Claims: A composite textile fabric comprising a first fabric layer of a synthetic yarn selected from the group consisting of polyester, acrylic and nylon, said synthetic yarn of said first fabric layer being naturally, or having been rendered, hydrophilic, and a second fabric layer wherein only said second fabric is blended with fibers having anti-microbial properties, wherein said first and second layers are formed concurrently by knitting a plaited construction, characterized in that : said second fabric layer has one of the following materials: a. a moisture-absorbent yarn material selected from the group consisting of cotton, rayon and wool; or b. a synthetic yarn which has been rendered hydrophilic and selected from the group consisting of polyester, polypropylene, acrylic and nylon; or c. a combination of a moisture-absorbent yarn material selected from the group consisting of cotton, rayon and wool, and a synthetic yarn material which has been rendered hydrophilic and selected from the group consisting of polyester, polypropylene, acrylic and nylon; wherein only said second fabric layer is treated by applying a composition which includes particles suspended therein and selected from the group consisting of silver, copper, or zinc metal, or ions of any thereof in an amount between about 0.01 and 75 percent o.w.f. A fabric according to Claim 1, wherein only said second fabric layer is exclusively blended with synthetic yarn fibers treated with at least one of silver, copper, zinc or ions of any thereof. A composite textile fabric according to Claim 1 or Claim 2, wherein the second fabric layer is additionally treated by blending the yarn of said second fabric layer with at least one of silver, copper, or zinc metal or ions of any thereof in an amount between about 0.5 and 50 weight percent. The fabric of any preceding claim, wherein said composition is discontinuously applied to said second layer. The fabric of any preceding claim, wherein a first denier of said yarn of said first fabric layer is no greater than a second denier of the yarn of said second fabric layer. The fabric of Claim 5, wherein said yarn of said second fabric layer has said second denier of between about 70 and 600 and said yarn of said first fabric layer has said first denier of between about 30 and 300. The fabric of any preceding claim, wherein said first fabric layer comprises said yarn fibers having a first denier of at least that of a second denier of said yarn fibers of said second fabric layer. The fabric of Claim 7, wherein said yarn fibers of said first fabric layer have said first denier between 0.3 and 5.0 and said yarn fibers of said second fabric layer have said second denier between 0.03 and 2.5. The fabric of any preceding claim, wherein said layers have an elastomeric yarn plaited therein. The fabric of any preceding claim, wherein said composition is an aerated material selected from the group consisting of a foam and a froth. The fabric of any preceding claim, wherein said particles are included in said composition in an amount between about 0.01 and 50.0 percent by volume. The fabric of any preceding claim, wherein the second fabric layer is adapted to be away from the skin surface of a wearer of the fabric.

Inventors: DIONNE EDWARD P, HARYSLACK CHARLES, LIE WILLIAM K, ROCK MOSHE, VAINER GADALIA, DIONNE, EDWARD P., HARYSLACK, CHARLES, LIE, WILLIAM K., ROCK, MOSHE, VAINER, GADALIA
Applicants: MALDEN MILLS IND INC, MALDEN MILLS INDUSTRIES, INC.
Application year: 2001
Main classification: D04B1
IPC codes: D04B1, A61F13, D06M11, A41B17, D03D11, A61L2, D04B21