SUBSTITUTED PYRIDINE HERBICIDES

Abstract: Compounds of the formula (I) in which the substituents are as defined in claim 1 are suitable for use as herbicides.

Description: SUBSTITUTED PYRIDINE HERBICIDES The present invention relates to novel herbicidally active pyridine ketones, to processes for their preparation, to compositions which comprise these compounds, and to their use for controlling weeds, in particular in crops of useful plants, or for inhibiting plant growth. Pyridine ketones having herbicidal action are described, for example, in WO 00/15615 and WO/0039094. We have now found novel pyridine ketones having herbicidal and growth-inhibiting properties. The present invention thus provides compounds of the formula I in which p is 0 or 1 ; Ri is a CrC 6 alkylene, C 3 -C 6 alkenylene or C 3 -C 6 alkynylene chain which may be mono- or polysubstituted by halogen or R 5> where the unsaturated bonds of the chain are not attached directly to the substituent X^ X T is oxygen, -O(CO)-, -(CO)O-, -O(CO)O-, -N(R 6 )-O-, -O-NR 51 -, thio, sulfinyl, sulfonyl, -SO 2 NR 7 -, -NR 52 SO 2 - or -NR 8 -; R 2 is a CτC 8 alkyl, C 3 -C 6 alkenyl or C 3 -C 6 alkynyl group which is mono- or polysubstituted by halogen, hydroxyl, amino, formyl, nitro, cyano, mercapto, carbamoyl, d-Cealkoxy, Cι-C 6 alkoxycarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, C 3 -C 6 cycloalkyl, by halogen-substituted C 3 -C 6 cycloalkyl, or by C 3 -C 6 alkenyloxy, C 3 -C 6 alkynyloxy, CrC 6 haloalkoxy, C 3 -C 6 haloalkenyloxy, cyano-C C 6 alkoxy, d-Cβalkoxy- CrC 6 alkoxy, d-Cealkoxy-d-Cealkoxy-Ci-Cealkoxy, CrC 6 alkylthio-Cι-C 6 aikoxy, C^Cealkyl- sulfinyl-CrC 6 alkoxy, CrCealkylsulfonyl-C Cβalkoxy, Cι-C 6 alkoxycarbonyl-CrC 6 alkoxy, CrC 6 alkoxycarbonyl, d-C 6 alkylcarbonyl, d-C 6 alkylthio, Cι-C 6 alkylsulfinyl, d-C 6 alkylsulfonyl, C C 6 haloalkylthio, d-C 6 haloalkylsulfinyl, d-C 6 haloalkyIsulfonyl, oxiranyl, which for its part may be substituted by d-C 6 alkyl, or by (3-oxetanyl)oxy, which for its part may be substituted by C C 6 alkyl, or by benzylthio, benzylsulfinyl, benzylsulfonyl, Cι-C 6 alkylamino, di(d-C 6 alkyl)amino, R 9 S(0) 2 0, R 10 N(R 11 )SO 2 - J thiocyanato, phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl; where the phenyl- or benzyl-containing groups for their part may be substituted by one or more d-C 6 alkyl, C C 6 haloalkyl, d-C 6 alkoxy, d-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro groups, or R 2 is phenyl which may be mono- or polysubstituted by d-C 6 alkyl, C C 6 haloalkyl, d-C 6 alkoxy, C C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; or R 2 is C 3 -C 6 cycIoalkyl, Cι-C 6 aIkoxy- or d-C 6 alkyl-substituted C 3 -C 6 cycloalkyl, 3-oxetanyl or d -C 6 alkyl-substituted 3-oxetanyl; or, if Q is Q 2 or Q 3 , or is Qi in which Rι and R 22 are a C 2 -C 3 alkylene chain, R 2 is additionally also a five- to ten-membered monocyclic or fused bicyclic ring system which may be aromatic, saturated or partially saturated and may contain 1 to 4 heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, where the ring system is attached directly or via a d-C 4 alkylene, C 2 -C 4 alkenyl-C C 4 alkylene, C 2 -C 4 alkynyl-C C 4 alkylene, -N(R 12 )-CrC 4 alkylene, -SO-Cι-C 4 alkylene or -SO 2 -C C 4 alkylene group to the substituent Xi and where each ring system may not contain more than two oxygen atoms and not more than two sulfur atoms and the ring system for its part may be mono-, di- or trisubstituted by d-C 6 alkyl, d-C 6 haloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloaikenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, d-C 6 alkoxy, hydroxyl, C C 6 haloalkoxy, C 3 -C 6 aikenyloxy, C 3 -C 6 alkynyloxy, mercapto, C C 6 alkylthio, Cι-C 6 haloalkylthio, C 3 -C 6 alkenylthio, C 3 -C 6 haloalkenylthio, C 3 -C 6 alkynylthio, C 2 -C 5 alkoxyalkylthio, C 3 -C 5 acetylalkylthio, C 3 -C 6 alkoxycarbonylalkylthio, C 2 -C 4 cyanoalkylthio, CrC 6 alkylsulfinyl, C C 6 haloalkylsulfinyl, d-C 6 alkylsulfonyl, C C 6 ha!oalkylsulfonyl, aminosulfonyl, d-C 2 alkylaminosulfonyl, di(d-C 2 alkyl)aminosulfonyl, di(Cι-C 4 alkyl)amino, halogen, cyano, nitro, phenyl and benzylthio, where phenyl and benzylthio for their part may be substituted on the phenyl ring by d-C 3 alkyl, d-C 3 haloalkyl, C r C 3 alkoxy, C C 3 haloalkoxy, halogen, cyano or nitro, and where the substituents on the nitrogen in the heterocyclic ring are different from halogen; or R 2 is hydrogen or unsubstituted d-C 8 alkyl if a) Ri is substituted by the group R 5 , or b) Q is the group Q 2 , or c) Q is the group Q 3 in which Xi is -O(CO)-, -(CO)O-, -N(R 6 )-O-, -O-NR 51 -, -SO 2 NR 7 -, -NR 52 SO 2 - or -NR 8 -; or d) Q is the group Q T in which X T is -N(R 6 )-O-, -O-NR 51 -, -SO 2 NR 7 -, -NR 52 SO 2 - or -NR 8 -, or e) Q is the group Q, in which Ru and R 22 in Q^ are a C 2 -C 3 alkylene chain and X^ is -O(CO)- or -(CO)O-, R 3 is C C 3 haloalkyl; R 4 is hydrogen, halogen, d-C 3 alkyl, Cι-C 3 haloalkyl, Cι-C 3 alkoxy, d-C 3 alkoxy-d-C 3 alkyI or C C 3 alkoxy-CrC 3 alkoxy; R 5 is hydroxyl, C C 6 alkoxy, C 3 -C 6 cycloalkyloxy, CrCealkoxy-C Cealkoxy, C Cealkoxy-d-Cβalkoxy-d-Cealkoxy or d-C 2 alkylsulfonyloxy; R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R5 1 and R 52 independently of one another are hydrogen, C C 6 alkyl, d-C 6 haloalkyl, d-C 6 alkoxycarbonyl, CrC 6 alkylcarbonyl, CrC-βalkoxy-d-Cealkyl, C Cealkoxy-C Csalkyl substituted by C C 6 alkoxy, benzyl or phenyl, where phenyl and benzyl for their part may be mono- or polysubstituted by C C 6 alkyl, C C 6 haloalkyl, C C 6 alkoxy, d-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; where R 6 and R 9 are not simultaneously hydrogen and hydrogen, d-C 6 alkoxycarbonyl or d-Cβaikylcarbonyl, respectively; Q is Q ! in which A 1 is C(R 1 R 15 ), NR 16 or oxygen; A 2 is C(R-ι 7 R 18 ), C(O), -C=N-O-Rι 9> oxygen, thio, sulfinyl, sulfonyl, -NR 20 or ethylene; with the provisos that A-, is different from oxygen if A 2 is oxygen, C(O), thio, sulfinyl, -C=N-O-R 19 , NR 20 or C(R 17 R 8 ), where R 17 and R 18 independently of one another are d-C 4 alkoxy, d-C alkylthio, C C 4 alkylsulfinyl, d-C 4 alkylsulfonyl; and A^ is different from NR 6 if A 2 is thio, sulfinyl or C(R-| 7 R 18 ), where R 1 and R 18 independently of one another are d-C alkoxy, d-C 4 alkylthio, C C 4 alkylsulfinyl, d-C 4 alkylsulfonyl; R 14 and R 22 independently of one another are hydrogen, d-C 4 alkyl, Cι-C 4 haloalkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, d-C 4 alkylthio, C C 4 alkylsulfinyl, C-,-C 4 alkylsulfonyl, C C 4 alkylsulfonyloxy, C C 4 alkoxy, d-C 4 alkoxycarbonyl or Cι-C 4 alkylcarbonyl; R 15 and R 2 ι independently of one another are hydrogen, d-C 4 alkyl, d-C 4 haloalkyl, C 3 -C 4 alkenyl or C 3 -C 4 alkynyl; R 17 is hydrogen, C-ι-C 4 alkyl, d-C 4 haloaIkyl, Cι-C 4 alkoxy, d-C 4 alkylthio, d-C 4 alkylsulfinyl or C C 4 alkylsulfonyl; R 18 is hydrogen, C C 4 alkyl, Cι-C 4 haloalkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, d-C alkoxy, C C 4 alkylthio, CrC 4 alkylsulfinyl, d-C alkylsulfonyl or C C 4 dialkoxyalkyl-CrC 4 alkyl; R 20 is d-C 4 alkyl, C 3 -C 6 cycloalkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, d-C alkylcarbonyl, C C 4 alkyl- carbonyloxy, di(d-C 4 alkyl)aminocarbonyl or benzyl, where the phenyl group may be mono- or polysubstituted by C C 6 alkyl, d-C 6 haloalkyl, Cι-C 6 alkoxy, C C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; R 19 and Rι 6 independently of one another are hydrogen, d-C alkyl, C 3 -C 6 cycloalkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, benzyl or phenyl, where phenyl and benzyl for their part may be mono- or polysubstituted by d-C 6 alkyl, d-C 6 haloalkyl, d-C 6 alkoxy, d-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; or R 4 and R 22 together form a C 2 -C 3 alkylene chain; or R 14 and R 15 together and/or R 17 and R-ι 8 together and/or R 21 and R 22 together form a C 2 -C 4 alkylene chain which may be interrupted by oxygen and/or carbonyl and/or sulfur, with the proviso that the oxygen and sulfur atoms are separated by at least one methylene group; or R 14 and R 18 together form a C 2 -C 4 alkylene chain; or R 22 and R 18 together form a C 2 -C 4 alkylene chain; or R 18 together with R 22 or R 14 forms a direct bond; or R 16 and Rι 8 together form a C 2 -C 4 alkylene chain; R 13 is hydroxyl, O " M\ where M + is an alkali metal cation or ammonium cation, halogen, d-C 12 alkylsulfonyloxy, amino, C C 4 alkylthio, d-Cι 2 alkylsulfinyl, d-C 12 alkylsulfonyl, C C 12 haloalkylthio, d-C 12 haloaikylsulfinyl, d-C 12 haloalkylsulfonyl, d-C 6 alkoxy- d-C 6 alkyrιhio, d-Cealkoxy-d-Cealkylsulfinyl, d-C 6 alkoxy-d-C 6 alkylsulfonyl, C 3 -C 12 alkenyl- thio, C 3 -C 12 alkenylsulfinyl, C 3 -C 12 alkenylsulfonyl, C 3 -C 12 alkynylthio, C 3 -C 12 alkynylsulfinyl, C 3 -C 12 alkynylsulfonyl, C C 4 alkoxycarbonyl-C C 4 alkylthio, CrC 4 alkoxycarbonyl-d-C 4 alkyl- sulfinyl, CrC 4 alkoxycarbonyl-Cι-C 4 aIkylsulfonyl, (C C 4 alkoxy) 2 P(O)O, C 1 -C 4 alkyl- (d-C 4 alkoxy)P(O)O, H(C C 4 alkoxy)P(O)O, R 23 R 24 N, R 25 R 26 NNH, R 27 R 28 NC(O)O-, R 29 R 30 NC(O)NH-, C C 18 alkylcarbonyloxy, C 2 -Cι 8 alkenylcarbonyloxy, C 2 -C 18 alkynyl- carbonyloxy, C 3 -C 6 cycloalkylcarbonyloxy, d-Cι 2 alkoxycarbonyloxy, d-C 12 alkylthio- carbonyloxy, d-Cι 2 alkylthiocarbamoyl, where the alkyl, alkenyl and alkynyl groups may be substituted by halogen, d-C 6 alkoxy, d-C 6 alkylthio, d-C 6 alkylsulfinyl, CrC 6 alkylsulfonyl or cyano; or R 13 is phenoxy, phenylthio, phenylsulfinyl, phenylsulfonyl, phenylsulfonylamino, phenylsulfonyloxy or benzoyloxy, where the phenyl groups for their part may be substituted by one or more halogen, nitro, cyano, d-C 4 alkyl, d-C haloalkyl, Cι-C 4 alkoxy or d-C 4 halo- alkoxy groups; or R 13 is a group Het-i-thio, Het 2 -sulfinyl, Het 3 -sulfonyl, Het 4 -(CO)O or Het 5 -N(R 33 ); in which Het-i, Het 2 , Het 3 , Het 4 and Het 5 independently of one another are a five- to ten-membered monocyclic or fused bicyclic ring system which may be aromatic or partially saturated and may contain 1 to 4 heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, and where each ring system may not contain more than 2 oxygen atoms and not more than 2 sulfur atoms, and where the ring system itself can be substituted by d-C 6 alkyl, d-Cehaloalkyl, C C 6 alkoxy, d-C 6 haloalkoxy, d-C 6 alkylthio, d-C 6 alkylsulfinyl, C C 6 alkyl- sulfonyl, di(C -C alkyl)aminosulfonyl, di(C 1 -C 4 alkyl)amino, halogen, cyano, nitro or phenyl, and where the substituents on the nitrogen in the heterocyclic ring are different from halogen; R23, R2 4 . R25, 26, R27, 28, R29, R30 and R 33 independently of one another are hydrogen or d-C 6 alkyl; or R 2 3 and R 24 together or R 25 and R 26 together or R 27 and R 28 together or R 29 and R 30 together are pyrolidino, piperidino, morpholino, thiomorphoiino, which may be mono- or polysubstituted by methyl groups; or Q is Q 2 in which R 3 is hydrogen, d-C 4 alkyl, C C 4 haloalkyl, C 3 -C 6 cycloalkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkynyl or benzyl, where the phenyl group may be mono- or polysubstituted by d-C 6 alkyl, d-C 6 halo- alkyl, C C 6 alkoxy, C-|-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; R 35 is hydrogen, Cι-C 4 alkyl, C C 4 haIoalkyl, C 3 -C 6 cycloalkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl or benzyl, where the phenyl group may be mono- or polysubstituted by Cι-C 6 alkyl, d-C 6 halo- alkyl, d-C 6 alkoxy, C-,-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; R 36 is hydroxyl, O " M + , where M + is an alkali metal cation or ammonium cation, halogen, d-C 12 alkylsulfonyloxy, amino, d-C 4 alkylthio, d-C 12 alkylsulfinyl, CrCeaikylsulfonyl, Cι-C 12 haloalkylthio, d-C 12 haloalkylsulfinyl, d-C 2 haloalkylsulfonyl, Cι-C 6 alkoxy- CrC 6 alkylthio, d-Cβalkoxy-d-Cealkylsulfinyl, d-Cealkoxy-d-Cealkylsulfonyl, C 3 -C 12 alkenyl- thio, C 3 -C 12 alkenylsulfinyl, C 3 -C 12 alkenylsulfonyl, C 3 -C 12 alkynylthio, C 3 -C 12 alkynylsulfinyl, C 3 -C 12 alkynylsulfonyl, C C 4 alkoxycarbonyl-Cι-C alkylthio, d-C 4 alkoxycarbonyl-Cι-C 4 alkyl- sulfinyl, C C 4 alkoxycarbonyl-d-C 4 alkylsulfonyl, (C C 4 alkoxy) 2 P(0)O, d-C alkyl- (d-C 4 alkoxy)P(O)O, H(C C 4 alkoxy)P(O)O, R 37 R 38 N, R 39 R 40 NNH, R 41 R 42 NC(O)O-, R 3 R 4 NC(O)NH-, d-Cι 8 alkylcarbonyloxy, C 2 -C 18 alkenylcarbonyloxy, C 2 -C 18 alkynyl- carbonyloxy, C 3 -C 6 cycloalkylcarbonyloxy, d-Cι 2 alkoxycarbonyloxy, d-C 12 alkylthio- carbonyloxy or d-C 12 alkylthiocarbamoyl, where the alkyl, alkenyl and alkynyl groups may be substituted by halogen, d-C 6 alkoxy, d-C 6 alkylthio, Crdialkylsulfinyl, d-C 6 alkylsulfonyl or cyano; or R 36 is phenoxy, phenylthio, phenylsulfinyl, phenylsulfonyl, phenylsulfonylamino, phenylsulfonyloxy or benzoyloxy, where the phenyl groups for their part may be mono- or polysubstituted by halogen, nitro, cyano, d-C alkyl, d-C 4 haloalkyl, C-ι-C 4 alkoxy, C C 4 halo- alkoxy, or R 36 is a group Het 7 -thio, Het 8 -sulfinyl, Het 9 -sulfonyl, Het 10 -(CO)O or Het ι N(R 47 ); in which Het 7 , Het 8 , Het 9 , Het 10 and Het^ independently of one another are a five- to ten-membered monocyclic or fused bicyclic ring system which may be aromatic or partially saturated and may contain 1 to 4 heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, and where each ring system may not contain more than 2 oxygen atoms and not more than 2 sulfur atoms, and where the ring system for its part may be substituted by C C 6 alkyl, d-C 6 haloalkyl, C C 6 alkoxy, d-C 6 haloalkoxy, d-C 6 alkylthio, C C 6 alkylsulfinyl, d-C- 6 alkylsulfonyl, di(d-C 4 alkyl)aminosulfonyl, di(C 1 -C 4 alkyl)amino, halogen, cyano, nitro or phenyl, and where the substituents on the nitrogen in the heterocyclic ring are different from halogen; R37. R38, R39 > R o, R ι , 4 2 > R 4 3, R^ and R 47 independently of one another are hydrogen or d-C 6 alkyl; or R 37 and R 38 together or R 39 and R 40 together or R 41 and R 42 together or R 43 and R^ together are pyrolidino, piperidino, morpholino, thiomorpholino, which may be mono- or polysubstituted by methyl groups; or Q is Q 3 in which R 49 is C C 4 alkyl, C r C haloalkyl, C 3 -C 6 cycloalkyl or halogen-substituted C 3 -C 6 cycloalkyl; R 50 is d-C 3 alkylene which may be substituted by halogen, hydroxyl, C^Cealkoxy, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, Cι-C 6 alkoxy-d-C 6 alkoxy, C C 6 alkoxy- C Cealkoxy-C Cealkoxy, (3-oxetanyl)oxy, or by C C 6 alkyl-substituted (3-oxetanyl)oxy, or by benzylthio, benzylsulfinyl, benzylsulfonyl, phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl, where the phenyl- and benzyl-containing groups for their part may be substituted by one or more C C 6 alkyl, d-C 6 haloalkyl, CrCealkoxy, C C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro groups; or R 50 is phenyl, where the phenyl-containing group for its part may be substituted by one or more d-C 6 alkyl, d-C 6 haloalkyl, C C 6 alkoxy, C Cehaloalkoxy, halogen, cyano, hydroxyl or nitro, or R 50 is C 3 -C 6 cycloalkyl, C C 6 alkoxy- or d-C 6 alkyl-substituted C 3 -C 6 cycloalkyl, 3-oxetanyl or C C 6 alkyl-substituted 3-oxetanyl; and n is 0, 1 or 2; and agronomically acceptable salts/N-oxides/isomers/enantiomers of these compounds. The alkyl groups occurring in the definitions of the substituents can be straight-chain or branched and are, for example, methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, iso- butyl, tert-butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl and dodecyl and their branched isomers. Alkoxy, alkenyl and alkynyl radicals are derived from the alkyl radicals mentioned. The alkenyl and alkynyl groups can be mono- or polyunsaturated. Halogen is generally fluorine, chlorine, bromine or iodine, preferably fluorine and chlorine. This also applies, correspondingly, to halogen in combination with other meanings, such as haloalkyl or halophenyl. HaloalkyI groups preferably have a chain length of from 1 to 6 carbon atoms. Haloalkyl is, for example, fluoromethyl, difluoromethyl, trifluoromethyl, chloromethyl, dichloromethyl, trichloromethyl, 2,2,2-trifluoroethyl, 2-fluoroethyl, 2-chloroethyl, pentafluoroethyl, 1 ,1 -difluoro- 2,2,2-trichloroethyl, 2,2,3,3-tetrafluoroethyl and 2,2,2-trichloroethyl; preferably trichloromethyl, difluorochloromethyl, difluoromethyl, trifluoromethyl and dichlorofluoromethyl. Suitable haloalkenyl groups are alkenyl groups which are mono- or polysubstituted by halogen, halogen being fluorine, chlorine, bromine and iodine and in particular fluorine and chlorine, for example 2,2-difluoro-1 -methylvinyl, 3-fluoropropenyl, 3-chloropropenyl, 3-bromopropenyl, 2,3,3-trifluoropropenyl, 2,3,3-trichloropropenyl and 4,4,4-trifluorobut-2-en- 1 -yl. Among the C 3 -C 20 alkenyl groups which are mono-, di- or trisubstituted by halogen, preference is given to those having a chain length of from 3 to 5 carbon atoms. Suitable haloalkynyl groups are, for example, alkynyl groups which are mono- or polysubstituted by halogen, halogen being bromine, iodine and in particular fluorine and chlorine, for example 3-fluoropropynyl, 3-chloropropynyl, 3-bromopropynyl, 3,3,3-trifluoro- propynyl and 4,4,4-trifluorobut-2-yn-1-yl. Among the alkynyl groups which are mono- or polysubstituted by halogen, preference is given to those having a chain length of from 3 to 5 carbon atoms. In the context of the present invention, the alkali metal cation M + (for example in the definition of R 13 ) is preferably the sodium cation or the potassium cation. Alkoxy groups preferably have a chain length of from 1 to 6 carbon atoms. Alkoxy is, for example, methoxy, ethoxy, propoxy, i-propoxy, n-butoxy, isobutoxy, sec-butoxy and tert- butoxy and also the isomeric pentyloxy and hexyloxy radicals; preferably methoxy and ethoxy. Alkylcarbonyl is preferably acetyl or propionyl. Alkoxycarbonyl is, for example, methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, isopropoxycarbonyl, n-butoxycarbonyl, isobutoxycarbonyl, sec-butoxycarbonyl or tert-butoxycarbonyl; preferably methoxycarbonyl or ethoxycarbonyl. Haloalkoxy groups preferably have a chain length of from 1 to 8 carbon atoms. Haloalkoxy is, for example, fluoromethoxy, difluoromethoxy, trifluoromethoxy, 2,2,2- trifluoroethoxy, 1 ,1 ,2,2-tetrafluoroethoxy, 2-fluoroethoxy, 2-chloroethoxy, 2,2-difluoroethoxy and 2,2,2-trichloroethoxy; preferably difluoromethoxy, 2-chloroethoxy and trifluoromethoxy. Alkylthio groups preferably have a chain length of from 1 to 8 carbon atoms. Alkylthio is, for example, methylthio, ethylthio, propylthio, isopropylthio, n-butylthio, isobutylthio, sec-butylthio or tert-butylthio, preferably methylthio and ethylthio. Alkylsulfinyl is, for example, methylsulfinyl, ethylsulfinyl, propylsulfinyl, isopropylsulfinyl, n-butylsulfinyl, isobutylsulfinyl, sec-butylsulfinyl, tert-butylsulfinyl; preferably methylsulfinyl and ethylsulfinyl. Alkylsulfonyl is, for example, methylsulfonyl, ethylsulfonyl, propylsulfonyl, isopropylsulfonyl, n-butylsulfonyl, isobutylsulfonyl, sec-butylsulfonyl or tert-butylsulfonyl; preferably methylsulfonyl or ethylsulfonyl. Alkoxyalkoxy groups preferably have a chain length of from 1 to 8 carbon atoms. Examples of alkoxyalkoxy groups are: methoxymethoxy, methoxyethoxy, methoxypropoxy, ethoxymethoxy, ethoxyethoxy, propoxymethoxy or butoxybutoxy. Alkylamino is, for example, methylamino, ethylamino, n-propylamino, isopropylamino or the isomeric butylamines. Dialkylamino is, for example, dimethylamino, methylethylamino, diethylamino, n-propylmethylamino, dibutylamino and diisopropylamino. Preference is given to alkylamino groups having a chain length of from 1 to 4 carbon atoms. Alkoxyalkyl groups preferably have a chain length of 1 to 6 carbon atoms. Alkoxyalkyl is, for example, methoxymethyl, methoxyethyl, ethoxymethyl, ethoxyethyl, n-propoxymethyl, n-propoxyethyl, isopropoxymethyl or isopropoxyethyl. Alkylthioalkyl groups preferably have from 1 to 8 carbon atoms. Alkylthioalkyl is, for example, methylthiomethyl, methylthioethyl, ethylthiomethyl, ethylthioethyl, n-propylthiomethyl, n-propylthioethyl, isopropylthiomethyl, isopropylthioethyl, butylthiomethyl, butylthioethyl or butylthiobutyl. The cycloalkyl groups preferably have from 3 to 8 ring carbon atoms, for example cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl and cyclooctyl. Phenyl, also as part of a substituent such as phenoxy, benzyl, benzyloxy, benzoyl, phenylthio, phenylalkyl, phenoxyalkyl, may be substituted. In this case, the substituents can be in ortho, meta and/or para position. The preferred substituent positions are the ortho and para positions to the ring attachment point. The compounds of the formula I may occur in different tautomeric forms, for example, if R 13 is hydroxyl, in the preferred formulae I' and I"" The invention also embraces the salts which can be formed by compounds of the formula I, preferably with amines, alkali metal and alkaline earth metal bases or quartemary ammonium bases. Suitable salt formers are described, for example, in WO 98/41089. The invention also embraces the salts which can be formed by the compounds of the formula I with amines, alkali metal and alkaline earth metal bases or quartemary ammonium bases. Among the alkali metal and alkaline earth metal hydroxides, the hydroxides of lithium, sodium, potassium, magnesium or calcium, in particular those of sodium or potassium, may be emphasized as salt formers. Examples of amines suitable for ammonium salt formation are both ammonia and primary, secondary and tertiary d-Cι 8 alkylamines, C C 4 hydroxyalky!amines and C 2 -C alkoxy- alkylamines, for example methylamine, ethylamine, n-propylamine, isopropylamine, the four isomeric butylamines, n-amylamine, isoamylamine, hexylamine, heptylamine, octylamine, nonylamine, decylamine, pentadecylamine, hexadecylamine, heptadecylamine, octadecylamine, methylethylamine, methylisopropylamine, methylhexylamine, methylnonyl- amine, methylpentadecylamine, methyloctadecylamine, ethylbutylamine, ethylheptylamine, ethyloctylamine, hexylheptylamine, hexyloctylamine, dimethylamine, diethylamine, di-n- propylamine, diisopropylamine, di-n-butylamine, di-n-amylamine, diisoamylamine, dihexylamine, diheptylamine, dioctylamine, ethanolamine, n-propanolamine, isopropanol- amine, N,N-diethanolamine, N-ethylpropanolamine, N-butylethanolamine, allylamine, n-butenyl-2-amine, n-pentenyl-2-amine, 2,3-dimethylbutenyl-2-amine, dibutenyl-2-amine, n-hexenyl-2-amine, propylenediamine, trimethylamine, triethylamine, tri-n-propylamine, triisopropylamine, tri-n-butylamine, triisobutylamine, tri-sec-butylamine, tri-n-amylamine, methoxyethylamine and ethoxyethylamine; heterocyclic amines, for example pyridine, quinoline, isoquinoline, morpholine, piperidine, pyrrolidine, indoline, quinuclidine and azepine; primary arylamines, for example anilines, methoxyanilines, ethoxyanilines, o,m,p-toluidines, phenylenediamines, benzidines, naphthylamines and o,m,p-chloroanilines; but in particular triethylamine, isopropylamine and diisopropylamine. Preferred quartemary ammonium bases which are suitable for salt formation correspond, for example, to the formula [N(R a RbRcRa )]OH, in which R a , R b , Re and R d independently of one another are C-ι-C 4 alkyl. Other suitable tetraalkylammonium bases with other anions can be obtained, for example, by anion exchange reactions. Compounds of formula I, wherein p is 0, are preferred. Preferred compounds of the formula I are those in which R 1 is -CH 2 -, -CH 2 CH 2 -, -CF 2 , -CH=CHCH 2 -, -CH(CH 3 )- or -C≡CCH 2 -, but particularly preferably -CH 2 - where in each case the free valences on the left are attached to the pyridine ring. Preference is furthermore given to those compounds of the formula I, in which X-i is oxygen, sulfonyl or a group -NR 52 SO 2 -, in particular oxygen. Of particular interest are compounds of the formula I, in which R 2 is -CH 2 OCH 3 , -CH 2 OCH 2 CH 3 , -CHgCH≥OCHa, -CH 2 CH 2 SO 2 CH 3 or -CH 2 CH 2 OCH 2 CH 2 OCH 3 , preferably -CH 2 CH 2 OCH 3 , those compounds standing out in which X T is oxygen and R^ is -CH 2 -. Among this group, preference is given to those compounds in which Q is Q^ and R 13 is hydroxyl. Emphasis is furthermore given to the compounds of the formula I in which R 2 OCH, , or . If, in these preferred meanings of R 2 , no free valency is indicated, as, for CH example, in the case of ° , the point of attachment is the carbon atom indicated by "CH". In a further preferred group of compounds of the formula I, R 3 is CF 3 , CF 2 CF 3 , CF 2 CI, CF 2 H or CCI 3 , particularly preferably CF 3 , where R 4 is preferably hydrogen or methyl, particularly preferably hydrogen. Re, 7, Re, R9, R-io, R11, R12. R51 and R 52 independently of one another are in particular hydrogen, d-C 4 alkyl, CrCealkoxy-d-Cealkyl or d-Cealkoxy-C Cealkyl which is substituted by d-C 6 alkoxy, where in a preferred group of compounds of the formula I additionally Q is Q 2 and Ri is methylene. Very particularly preferably, Q is Qt and R 13 is hydroxyl or halogen, in particular hydroxyl. Among this group, emphasis is given to those compounds in which a) A T is C(R 14 R 15 ) or NR 16 and A 2 is C(R 17 R 18 ), C(O) or oxygen, or b) A-i is C(R 14 Rι 5 ) and A 2 is C(R 17 Rι 8 ) and R 14 and R 22 together form a C 2 -C 3 alkylene chain, preferably an ethylene chain, where R 15 , R 17 , R 18 and R 21 are particularly preferably hydrogen; or c) A 2 is C(O) or C(Rι 7 Rι 8 ), A is C(R 14 R 15 ) and R 14 , R 15 , R 17 and R 18 independently of one another are hydrogen, methyl, ethyl, methoxycarbonyl or ethoxycarbonyl; or d) R 14 and R 15 or R 21 and R 22 together form a C 2 alkylene chain (cyclopropyl ring), A 2 is CH 2 and R 21 and R 22 or R 1 and R 15 independently of one another are hydrogen, C C 4 alkyl, methoxycarbonyl or ethoxycarbonyl; or e) A 2 is C(R 17 R 18 ) and is C(R 14 Rι 5 ) and R 18 and R 1 together form a C 2 -C 3 alkylene chain. In a further outstanding group of compounds of the formula I, Q is Q 3 , R 49 is cyclopropyl and R S0 -S(O) n is methylthio, ethylthio, methylsulfinyl, ethylsulfinyl, methylsulfonyl or ethylsulfonyl. The compounds of the formula I can be prepared by processes known per se, for example those described in WO 97/46530 or WO 00/15615 or WO/0039094, for example in the case of compounds of the formula I, in which Ri, R 2 , R 3 , R 4 and X are as defined under formula I and Q is a group by, for example, either a) reacting a compound of the formula la in which R 1 ( R 2 , R 3 , R and Xt are as defined under formula I and Yi is a leaving group, for example halogen or cyano, in an inert organic solvent in the presence of a base with a compound of the formula II in which R 22 , R 2 , A 2 and A^ are as defined under formula I, to give the compounds of the formulae Ilia and lllb Ilia lllb and then isomerizing these for example in the presence of a base and a catalytic amount of dimethylaminopyridine (DMAP) or a source of cyanide, for example acetone cyanohydrin; or b) reacting a compound of the formula lb in which R^ R 2 , R 3 , R 4 and Xi are as defined under formula I, with a compound of the formula II in which R 22 , R 21 , Ai and A 2 are as defined under formula I, in an inert organic solvent in the presence of a base and a coupling agent to give the compounds of the formula Ilia or lllb Ilia lllb and then isomerizing these, for example as described under route a). Compounds of the formula I, in which Q is a group are prepared similarly to a known process (for example WO 97/46530), wherein either a) a compound of the formula la in which R^ R 2 , R 3 , R 4 and Xi are as defined under formula I and Y is a leaving group, for example halogen or cyano, is reacted with a compound of the formula I la in which R 34 and R 35 are as defined, in an inert organic solvent in the presence of a base to give the compound of the formula lllc lllc in which R 1 ; R 2 , R 3 , R 4 , R 3 , R35 and X^ are as defined under formula I, and this compound is then isomerized, for example in the presence of a base and a catalytic amount of a source of cyanide; or b) a compound of the formula lb in which Ri, R 2 , R 3 , R 4 and X^ are as defined under formula I, is reacted with a compound of the formula I la R 35 in which R 3 and R 35 are as defined above, in an inert organic solvent in the presence of a base and a coupling agent to give the compound of the formula lllc and this compound is then isomerized as described under route a). The compounds of the formula I, in which Q is a group (0)n in which n is 0 and R 50 and R 49 are as defined above, are prepared similarly to known processes (for example those described in WO 00/15615, WO/0039094 or WO 97/43270), wherein either a) a compound of the formula IV in which Xi, R 1 ; R 2 , R 3 , R and R 49 are as defined above, is converted in the presence of a base, carbon disulfide and an alkylating agent of the formula V in which R 50 is as defined under formula I, and Y 2 is a leaving group, for example halogen or sulfonate, into the compound of the formula VI in which R 1 f R 2 , R 3 , R 4 , R 50 , X 1 and R 49 are as defined above, and this compound is then cyclized with hydroxylamine hydrochloride, if appropriate in a solvent, in the presence of a base, for example sodium acetate, to give the isomeric compounds of the formulae Ic and Id and these compounds are then oxidized with an oxidizing agent, for example with peracids, for example meta-chloroperbenzoic acid (m-CPBA) or peracetic acid, to give the corresponding sulfoxides (n = 1) and sulfones (n = 2) of the formulae Ie and If, respectively. Isomers of the formulae Ic and Id (in which n = 0) or Ie and If (in which n = 1 or 2) can be separated and purified by column chromatography, using a suitable mobile phase. The intermediates of the formulae la, lb, IV and VI are novel and were developed specifically for the preparation of the compounds of the formula I. Accordingly, they also form part of the subject-matter of the present invention. Together, the novel intermediates of the formulae la, lb, IV and VI correspond to formula XX in which Q is hydroxyl, halogen, cyano or d-C 6 alkoxy, or is a group of the formula or -CH 2 (CO)R 49 ; and Ri, R 3 , R 4 , R 49 , R 50 , X 1 and p are as defined under formula I and R 2 is a d-C 8 alkyl, C 3 -C 6 alkenyl or C 3 -C 6 alkynyl group which is mono- or polysubstituted by halogen, hydroxyl, amino, formyl, nitro, cyano, mercapto, carbamoyl, d-C 6 alkoxy, C C 6 alkoxycarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, C 3 -C 6 cycloalkyl, by halogen- substituted C 3 -C 6 cycloaIkyl, or by C 3 -C 6 alkenyloxy, C 3 -C 6 alkynyloxy, d-C 6 haloalkoxy, C 3 -C 6 haloalkenyloxy, cyano-d-C 6 alkoxy, C C 6 alkoxy-CrC 6 alkoxy, d-Cealkoxy-d-Cβalkoxy- Cι-C 6 alkoxy, Cι-C 6 alkylthio-d-C 6 alkoxy, C Cealkylsulfinyl-d-Cealkoxy, d-C 6 alkylsulfonyl- d-C 6 alkoxy, Cι-C 6 alkoxycarbonyl-d-C 6 alkoxy, d-C 6 alkoxycarbonyl, d-C 6 alkylcarbonyl, d-C 6 alkylthio, C C 6 aIkylsulfinyl, d-C 6 alkylsulfonyl, d-Cehaloalkylthio, C C 6 haloalkylsulfinyl, d-C 6 -haloalkylsulfonyl, oxiranyl, which for its part may be substituted by d-C 6 alkyl, or by (3-oxetanyl)oxy, which for its part may be substituted by d-C 6 alkyl, or by benzylthio, benzylsulfinyl, benzylsulfonyl, C C 6 alkylamino, di(d-C 6 alkyl)amino, R 9 S(O) 2 O, RιoN(Rn)SO 2 -, thiocyanato, phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl; where the phenyl- or benzyl-containing groups for their part may be substituted by one or more d-C 6 alkyl, C C 6 haloalkyl, d-C 6 alkoxy, d-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro groups, or R 2 is phenyl which may be mono- or polysubstituted by C C 6 alkyl, C C 6 haloalkyl, d-C 6 alkoxy, d-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; or R 2 is C 3 -C 6 cycloalkyl, Cι-C 6 alkoxy- or d-C 6 alkyl-substituted C 3 -C 6 cycloalkyl, 3-oxetanyl or d-C 6 alkyl-substituted 3-oxetanyl; or if Xi is -N(R 6 )-O-, -O-NR5 1 , SO 2 NR 7 - or -NR 52 SO 2 - and R 6 , R 7 , R 51 and R 52 are as defined under formula I, R 2 may additionally be hydrogen, unsubstituted d-C 6 alkyl, or a five- to ten-membered monocyclic or fused bicyclic ring system which may be aromatic, saturated or partially saturated and may contain 1 to 4 heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, where the ring system is attached directly or via a d-C 4 alkylene, C 2 -C 4 alkenyl-C C 4 alkylene, C 2 -C 4 alkynyl-d-C 4 alkylene, -N(Rι 2 )- d-C 4 alkylene, -SO-C C 4 alkylene or -SO 2 -C C 4 alkylene group to the substituent X 1 τ and where each ring system may not contain more than 2 oxygen atoms and not more than two sulfur atoms, and where the ring system for its part may be mono-, di- or trisubstituted by C C 6 alkyl, Cι-C 6 haloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, d-C 6 alkoxy, hydroxyl, d-C 6 haloalkoxy, C 3 -C 6 alkenyloxy, C 3 -C 6 alkynyloxy, mercapto, d-C 6 alkylthio, d-C 6 -haloalkylthio, C 3 -C 6 alkenylthio, C 3 -C 6 haloalkenylthio, C 3 -C 6 alkynylthio, C 2 -C 5 alkoxyalkylthio, C 3 -C 5 acetylalkylthio, C 3 -C 6 alkoxycarbonylalkylthio, C 2 -C 4 cyanoalkylthio, d-C 6 alkylsulfinyl, C C 6 haloalkylsulfinyl, C C 6 alkylsulfonyl, C Cehaloalkylsulfonyl, aminosulfonyl, C C 2 alkylaminosulfonyI, di(d-C 2 alkyl)aminosu!fonyl, di(CrC 4 alkyl)amino, halogen, cyano, nitro, phenyl and benzylthio, where phenyl and benzylthio for their part may be substituted on the phenyl ring by C C 3 alkyl, d-C 3 haloalkyl, CrC 3 alkoxy, d-C 3 haloalkoxy, halogen, cyano or nitro, and where the substituents on the nitrogen in the heterocyclic ring are different from halogen. The preparation of the compounds of the formula I is illustrated in more detail in reaction schemes 1 and 2 below. Reaction scheme 1 Route b): solvent e.g. CH 3 CN, Reaction scheme 1 is preferably used to prepare the compounds of the formula I having the group Q 1 ( in which R 13 is hydroxyl, and the compounds of the formula I having the group Q 2 , in which R 36 is hydroxyl. Reaction scheme 2 If (if n = 1 or 2) I d (if n = 0) Compounds of the formula I, in which p is 1 , i.e. the corresponding N-oxides of the formula I, can be prepared by reacting a compound of the formula I, in which p is 0, with a suitable oxidizing agent, for example the H 2 O 2 /urea adduct in the presence of an acid anhydride, e.g. trifluoroacetic anhydride. Such oxidations are known from the literature, for example from J. Med. Chem., 32 (12), 2561 -73, 1989 or WO 00/15615. According to reaction scheme 1 , route a), the carboxylic acid derivatives of the formula la in which Y T is a leaving group such as halogen, for example iodine, bromine, and in particular chlorine, N-oxyphthalimide or N,O-dimethylhydroxylamino or part of an activated ester, for example (formed from dicyclohexylcarbodiimide (DCC) and the corresponding carboxylic acid) or 2 5 ι 3 3 2 (formed from N-ethyl N'-(3- dimethylaminopropyl)carbodiimide (EDC) and the corresponding carboxylic acid) are used as starting materials for preparing the compounds of the formula I in which Q denotes the groups Q T and Q 2 and R 13 and R 36 are hydroxyl. The starting materials are reacted in an inert organic solvent such as a halogenated hydrocarbon, for example dichloromethane, a nitrile, for example acetonitrile, or an aromatic hydrocarbon, for example toluene, and in the presence of a base such as an alkylamine, for example triethylamine, an aromatic amine, for example pyridine or 4-dimethylaminopyridine (DMAP) with the dione derivatives of the formula II or pyrazoles of the formula lla, to give the isomeric enol ethers of the formula Ilia, lllb or lllc. This esterification can be carried out at temperatures of from 0°C to 110°C. The isomerization of the ester derivatives of the formulae Ilia, lllb and lllc to derivatives of the formula I (in which R 13 and R 36 are hydroxyl) can be carried out, for example, similarly to EP-A-0 353 187, EP-A-0 316 491 or WO 97/46530 in the presence of a base such as an alkylamine, for example triethylamine, a carbonate, for example potassium carbonate, and a catalytic amount of DMAP or a source of cyanide, such as acetone cyanohydrin or potassium cyanide. In particular if a cyanide compound of the formula la (Yi = cyano) is used, or in the presence of a catalytic amount of acetone cyanohydrin or potassium cyanide, the two reaction steps can be carried out in situ without isolating the intermediates III. According to reaction scheme 1 , route b), the desired derivatives of the formula I (in which R 13 and R 36 are hydroxyl) can be obtained, for example, similarly to E. Haslem, Tetrahedron, 2409-2433, 36, 1980, by esterifying the carboxylic acids of the formula lb with the dione derivatives of the formula II or pyrazoles of the formula lla in an inert solvent such as a halogenated hydrocarbon, for example dichloromethane, a nitrile, for example acetonitrile, or an aromatic hydrocarbon, for example toluene, in the presence of a base such as an alkylamine, for example triethylamine, and a coupling agent such as 2-chloro-1 -methyl- pyridinium iodide. Depending on the solvent used, this esterification is carried out at temperatures of from 0°C to 1 10°C, giving initially, as described under route a), the isomeric ester of the formula Ilia, lllb or lllc, which can be isomerized as described under route a), for example in the presence of a base and a catalytic amount of DMAP, or a source of cyanide, for example acetone cyanohydrin, to give the desired derivative of the formula I (R 13 and R 36 = hydroxyl). The activated carboxylic acid derivatives of the formula la in reaction scheme 1 (route a), in which Y, is a leaving group such as halogen, for example bromine, iodine or, in particular, chlorine, can be prepared by known standard processes, for example those described in C. Ferri "Reaktionen der organischen Synthese" [Reactions of organic sythesis], Georg Thieme Verlag, Stuttgart, 1978, page 460 ff. Such reactions are generally known and described in the literature in different variations with respect to the leaving group The preparation of the compounds of the formula I, in which Q denotes the group Q 3 , can be carried out according to reaction scheme 2 by reacting the β-diketone derivative of the formula IV for example similarly to Synthesis 1991, 301 ; ibid. 1988, 793; or Tetrahedron 32, 3055, 1976, with carbon disulfide in the presence of a base such as a carbonate, for example potassium carbonate, a metal hydride, for example sodium hydride, or potassium fluoride on aluminum, and an alkylating agent of the formula V, in which Y 2 is a leaving group such as halogen, for example iodine, bromine and, in particular, chlorine, CH 3 SO 2 O- or CH g -<\ — S0 2 0- • This reaction is expediently carried out in a solvent such as an amide, for example N,N-dimethylformamide (DMF), a sulfoxide, for example dimethyl sulfoxide (DMSO), or a nitrile, for example acetonitrile. The ketene thioacetal of the formula VI that is formed is cyclized with the aid of hydroxylamine hydrochloride in the presence of a base such as sodium acetate in a solvent such as an alcohol, for example ethanol, or an ether, for example tetrahydrofuran, to give the isomeric compounds of the formulae Ic and Id (in which n is 0). This cyclization reaction is carried out at temperatures of from 0°C to 100°C. If appropriate, the compounds of the formulae Ic and Id in which n is 0 can be oxidized similarly to known standard processes as described, for example, in H. O. House, "Modern Synthetic Reactions", W. A. Benjamin, Inc., Menlo Park, California, 1972, pages 334-335 and 353-354, to give the corresponding sulfones and sulfoxides of the formulae Ie and If (n = 1 or 2). The compounds of the formula IV in reaction scheme 2 can be obtained by standard processes for example from the corresponding compounds of the formula la (la), in which R f R 2 , R 3 , R 4 , and Xi are as defined above and Y, is a leaving group, for example halogen, for example by Claisen condensation, or from the compounds of the formula la by reaction with a ketocarboxylic acid salt of the formula VII COO M " H 2 C (VII), \ COR 49 in which R g is as defined under formula I and M + is an alkali metal ion (cf., for example, WO 96/26192). Compounds of the formula I, in which R-, is, in particular d-C 2 alkyl, can, for example, also be prepared by heating an N-oxide of the formula IX under known reaction conditions in the presence of an acid anhydride (see, for example, Konno, K.; Hashimoto, K.; Shirahama, H.; Matsumoto, T.; Heterocyctes 1986, 24, 2169, or WO 00/15615) and hydrolyzing the resulting products (Ig) in a protic solvent, for example water or a water/methanol mixture, if appropriate in the presence of a base (for example lithium hydroxide or sodium hydroxide), and then converting the resulting alcohol X in the presence of a base, for example sodium hydride or potassium hydroxide, if appropriate in the presence of a phase-transfer catalyst or a crown ether, and an alkylating agent R 2 -Y3, in which R 2 is as defined under formula I and Y 3 is a leaving group, for example halogen or methyl sulfonate, in an aprotic solvent, for example, tetrahydrofuran or dimethylformamide, into the corresponding derivatives of the formula Ih (in which X^ is oxygen). Compounds of the formula I, in which R 2 is CrC 6 alkoxymethyl or 2-tetrahydropyranyl or 2-tetrahydrofuryl, can be prepared, for example, by treating an alcohol of the formula X with a vinyl ether of the formula VE 1 , in which R 03 , R 04 , and R 05 are d-C 6 alkyl or R 03 together with R 05 forms a C 2 -C 3 alkylene chain, in the presence of an acidic catalyst, for example para-toluenesulphonic acid, in an inert solvent, for example methylene chloride. Such reactions are generally known in the literature (see, for example, Synthesis, p. 169, 1973). The two reaction sequences are demonstrated using the example below: Reaction scheme 3 Compounds of the formula I, in which R^ is, in particular, d-C 2 alkyl or d-C 2 haloalkyl, can, for example, also be prepared by oxidzing a compound of the formula XI, in which R 13 is in particular chlorine, d-C 4 alkoxycarbonyloxy or benzoylcarbonyloxy (prepared similarly to WO 00/15615 or WO/0039094), under known halogenation conditions using, for example, N-bromosuccinimide or N-chlorosuccinimide in the presence of light and a free-radical initiator such as benzoyl peroxide to give the 1 -bromo or 1 -chloro, 1 ,1-dibromo or 1 ,1 -dichloro compound and then refunctionalizing these compounds into the corresponding derivatives of the formula I, for example by reaction with a nucleophile R 2 -Z, in which Z is, for example, -SH, -OH, -C(O)OH, -O-N(R 51 )H, -N(R 6 )-OH, -SO 2 N(R 52 )H or -N(R 8 )H and R 2 , R 52 , R 8 , R 6 and R 51 are as defined under formula I, in the presence of a base, for example sodium hydride, potassium hydroxide or potassium carbonate, followed by aqueous work-up. These reaction sequences, too, are demonstrated by the example below. Reaction scheme 4 R 01 = H, C 1 -C 4 alkyl 01 CI, Br; X 02 = H, X, 1. Z-R 2 , base e.g. NaH solvent e.g. DMF 2. aqueous work-up X 01 = H, CI, Br R 01 = H, C C 4 alkyl Z = S, O, N(R 8 ), N(R 52 )S0 2 , N(R β )0, ON(R 51 ), O(CO) Compounds of the formula I, in which Q denotes Q^ or Q 2 and in which R 13 or R 36 are different from hydroxyl or halogen, can be prepared by conversion processes generally known from the literature, for example acylations or carbamoylations with appropriate acid chlorides from compounds of the formula I, in which Rι 3 or R 36 is hydroxyl, in the presence of a suitable base, or they can be prepared by nucleophilic substitution reactions on chlorides of the formula I, in which R 13 and R 36 are chlorine, the chlorides likewise being obtainable according to known processes by reaction with a chlorinating agent, such as phosgene, thionyl chloride or oxalyl chloride. The starting materials used are, for example, appropriately substituted amines, or hydroxylamines directly, or alkylsulfonamides, mercaptans, thiophenols, phenols, heterocyclic amines or heterocyclic thiols in the presence of a base, for example 5-ethyl-2-methylpyridine, diisopropylethylamine, triethylamine, sodium bicarbonate, sodium acetate or potassium carbonate. Compounds of the formula I, in which R 13 and R 36 contain thio groups, can be oxidized similarly to known standard processes using, for example, peracids, for example meta- chloroperbenzoic acid (m-CPBA) or peracetic acid, to give the corresponding sulfones and sulfoxides of the formula I. The degree of oxidation at the sulfur atom (SO- or S0 2 -) can be controlled by the amount of oxidizing agent. The resulting derivatives of the formula I, in which R 13 and R 36 are different from hydroxyl, can likewise occur in different isomeric forms which, if appropriate, can be isolated in pure form. Accordingly, the invention also embraces all of these stereoisomeric forms. Examples of these isomeric forms are the formulae I * , I ** and I *** below in which Q denotes the group The compounds of the formulae I) and lla are known and can be prepared similarly as described, for example, in WO 92/07837, JP 10265441 , DE-A-3818958, EP-A-0 338 992, DE-A-3902818, EP-A-0 278 742, WO 98/29412, JP 02059566, US-A-5,089,046, GB-A- 2205316, WO 00/27821 or EP-A-0 384 736. The required intermediates of the formula lb (or Ik, II or Im) are synthesized similarly to known processes as described, for example, in WO 00/15615, WO/00/39094 or WO 97/46530, or they can be prepared for example, according to generally known conversion methods such as the Stille (see, for example Angew. Chem. 1986, 98(6), 504- 19), Heck (see, for example, Angew. Chem. 1994, 106 (23/24), 2473-506), Sonogashira (see, for example, "Comprehensive Organometallic Synthesis", Pergamon Verlag, Oxford, Vol 3, 1991, page 521 ff.) or Wittig (for example C. Ferri "Reaktionen der organischen Synthese", Georg Thieme Verlag, Stuttgart, 1978, p. 354 ff.) reactions, starting from halogen derivatives of the formula XIV (preparation as described in WO 00/15615 or WO/0039094) or XVII (preparation similar to EP 522392) (reaction scheme 5): Reaction scheme 5 r eaction Intermediates of the formula lb, in which R 1 ( R 2 , R 3 , R 4 and X are as defined under formula I, can also be prepared by the method according to reaction scheme 6: Using generally known oxidation methods such as dihydroxylation, Wacker oxidation, epoxidation, hydroboration with subsequent oxidation, starting with vinyl or allyl compounds of the formula XVIII (preparation as described in WO 00/15615 or WO/0039094), intermediates of the formulae II, In, Iq and Ir are obtained which can be converted by conversion processes known to the person skilled in the art (for example alcohol activation, for example as sulfonate, alkylation, for example using an alkylating agent R 2 -Y 3 or R 5 -Y 3 , in which R 2 and R 5 are as defined under formula I and Y 3 is a leaving group, for example halogen), in the presence of a base, or using nucleophile reactions, for example with a nucleophile Z-R 2 , in which Z and R 2 are as defined above, into compounds of the formula I. Intermediates of the formula lb, in which R-, is Cι-C 2 alkyl and R 2 , R 3 , R 4 and X-, are as defined under formula I, can also be prepared by reacting a compound of the formula XlVa, in which R 3 and R 4 are as defined above under formula I and Y is halogen, with a nucleophile R 2 -Z, in which Z is -SH, -OH, -C(O)OH, -O-N(R 51 )H, -N(R 6 )-OH -SO 2 N(R 52 )H or - N(R 8 )H and R 2 , Rs 2 , Rs, Re, R5 1 are as defined above under formula I, in the presence of a base such as sodium hydride or an alkaline earth metal oxide or carbonate in an inert solvent such as dimethylformamide or THF at temperatures between -5 and 160°C, or, to prepare the corresponding sulfinyl or sulfonyl derivatives of the formula lu, by reacting with an oxidizing agent such as m-chloroperbenzoic acid or sodium periodate, or sodium perborate, with, depending on the degree of oxidation, temperature control known to the person skilled in the art (for example -30°C-+50°C for n=1 and -20°C-+100°C for n=2 respectively) , in an inert solvent such as dichloromethane, to give compound of the formula Iv. In reaction scheme 7 below, this is illustrated in more detail for the case Z = OH, SH, SO 2 N(R 52 )H and N(R 8 )H: Reaction scheme 7 Intermediates of the formula I, in which Q denotes a group OR 02 (R0 2 = CrC 6 alkyl), can be converted by hydrolysis using, for example, a base, for example LiOH, in a protic solvent, for example H 2 O or H 2 O/methanol mixtures, into products of the formula lb. For preparing all further compounds of the formula I functionalized according to the definitions of R 1 ; R 2 , R 3 , R 4 and X 1 ? there are a large number of suitable known standard methods, for example alkylation, halogenation, acylation, amidation, oximation, oxidation and reduction, the choice of the preparation methods which are suitable depending on the properties (reactivity) of the substituents in the intermediates. The reactions to give compounds of the formula I are advantageously carried out in aprotic inert organic solvents. Such solvents are hydrocarbons such as benzene, toluene, xylene or cyclohexane, chlorinated hydrocarbons such as dichloromethane, trichloromethane, tetrachloromethane or chlorobenzene, ethers such as diethyl ether, ethylene glycol dimethyl ether, diethylene glycol dimethyl ether, tetrahydrofuran or dioxane, nitriles such as acetonitrile or propionitrile, amides such as N,N-dimethylformamide, diethylformamide or N-methylpyrrolidinone. The reaction temperatures are advantageously between -20°C and +120°C. In general, the reactions are slightly exothermic and, as a rule, they can be carried out at room temperature. To shorten the reaction time, or else to start the reaction, the mixture may be heated briefly to the boiling point of the reaction mixture. The reaction times can also be shortened by adding a few drops of base as reaction catalyst. Suitable bases are, in particular, tertiary amines such as trimethylamine, triethylamine, quinuclidine, 1 ,4-diazabicyclo[2.2.2]octane, 1 ,5-diazabicyclo[4.3.0]non-5-ene or 1 ,5-diazabicyclo- [5.4.0]undec-7-ene. However, inorganic bases such as hydrides, e.g. sodium hydride or calcium hydride, hydroxides, e.g. sodium hydroxide or potassium hydroxide, carbonates such as sodium carbonate and potassium carbonate, or hydrogen carbonates such as potassium hydrogen carbonate and sodium hydrogen carbonate may also be used as bases. The bases can be used as such or else with catalytic amounts of a phase-transfer catalyst, for example a crown ether, in particular 18-crown-6, or a tetraalkylammonium salt. The compounds of the formula I can be isolated in the customary manner by concentrating and/or by evaporating the solvent and purified by recrystallization or trituration of the solid residue in solvents in which they are not readily soluble, such as ethers, aromatic hydrocarbons or chlorinated hydrocarbons. All application methods which are conventionally used in agriculture, for example pre- emergence application, post-emergence application and seed treatment, as well as various methods and techniques, for example the controlled release of active ingredients, are suitable for the use according to the invention of the compounds of the formula I or of compositions comprising them. To this end, the active ingredient in solution is applied to mineral carriers for granules or to polymerized granules (urea/formaldehyde) and dried. If appropriate, an additional coating can be applied (coated granules), which allows the active ingredient to be released in a controlled manner over a specific period of time. The compounds of the formula I can be employed as herbicides as such, i.e. as obtained from synthesis. However, they are preferably processed in the customary manner together with the auxiliaries conventionally used in the art of formulation, for example to give emulsifiable concentrates, directly sprayable or dilutable solutions, dilute emulsions, wettable powders, soluble powders, dusts, granules or microcapsules. Such formulations are described, for example, in WO 97/34485 on pages 9 to 13. The application methods such as spraying, atomizing, dusting, wetting, scattering or pouring, as well as the type of composition, are chosen to suit the intended aims and the prevailing circumstances. The formulations, i.e. the compositions, preparations or products which comprise the active ingredient of the formula I or at least one active ingredient of the formula I and, as a rule, one or more solid or liquid formulation auxiliaries, are prepared in the known manner, for example by intimately mixing and/or grinding the active ingredients together with the formulation auxiliaries, for example solvents or solid carriers. Furthermore, surface-active compounds (surfactants) may additionally be used when preparing the formulations. Examples of solvents and solid carriers are indicated for example in WO 97/34485 on page 6. Suitable surface-active compounds are, depending on the nature of the active ingredient of the formula I to be formulated, nonionic, cationic and/or anionic surfactants and surfactant mixtures which have good emulsifying, dispersing and wetting properties. Examples of suitable anionic, nonionic and cationic surfactants are enumerated, for example, in WO 97/34485 on pages 7 and 8. The surfactants conventionally used in the art of formulation which are described, inter alia, in "McCutcheon's Detergents and Emulsifiers Annual" MC Publishing Corp., Ridgewood New Jersey, 1981 , Stache, H., "Tensid- Taschenbuch" ["Surfactants Guide"], Carl Hanser Verlag, Munich/Vienna, 1981 and M. and J. Ash, "Encyclopedia of Surfactants", Vol l-lll, Chemical Publishing Co., New York, 1980-81 are furthermore also suitable for preparing the herbicidal compositions according to the invention. As a rule, the herbicidal formulations comprise 0.1 to 99% by weight, in particular 0.1 to 95% by weight, of herbicide, 1 to 99.9% by weight, in particular 5 to 99.8% by weight, of a solid or liquid formulation auxiliary and 0 to 25% by weight, in particular 0.1 to 25% by weight, of a surfactant. While concentrated compositions are more preferred as commercially available goods, the end consumer uses, as a rule, dilute compositions. The compositions can also comprise further additives such as stabilizers, for example epoxidized or non-epoxidized vegetable oils (epoxidized coconut oil, rapeseed oil or soya oil), antifoams, e.g. silicone oil, preservatives, viscosity regulators, binders, tackifiers and fertilizers or other active ingredients. As a rule, the active ingredients of the formula I are applied to the plant or its environment at rates of 0.001 to 4 kg/ha, in particular 0.005 to 2 kg/ha. The dosage required for the desired action can be determined by experiments. It depends on the type of the action, the developmental stage of the crop plant and of the weed, and on the application (location, timing, method) and can, owing to these parameters, vary within wide limits. The compounds of the formula I are distinguished by herbicidal and growth-inhibitory properties which allow them to be employed in crops of useful plants, in particular in cereals, cotton, soya, sugar beet, sugar cane, plantation crops, rapeseed, maize and rice and for the non-selective control of weeds. Crops are also to be understood as including those which have been rendered tolerant to herbicides or classes of herbicides by means of conventional plant-breeding or genetic-engineering methods. The weeds to be controlled may be both mono- and dicotyledonous weeds such as Stellaria, Nasturtium, Agrostis, Digitaria, Avena, Setaria, Sinapis, Lolium, Solanum, Echinochloa, Scirpus, Monochoria, Sagittaria, Bromus, Alopecurus, Sorghum halepense, Rottboellia, Cyperus, Abutilon, Sida, Xanthium, Amaranthus, Chenopodium, Ipomoea, Chrysanthemum, Galium, Viola and Veronica. The examples which follow illustrate the invention in greater detail without limiting it. Preparation examples: Example H1 : Preparation of ethyl 2-bromomethyl-6-trifluoromethylnicotinate: 434.4 g (1.866 mol) of ethyl 2-methyl-6-trifluoromethylnicotinate (preparation similar to Heterocycles 129, 46, 1997) and 398.5 g (2.239 mol) of N-bromosuccinimide in 3 500 ml of carbon tetrachloride in the presence of 30.6 g (0.1866 mol) of α, -azaisobutyronitrile are heated at 75°C, with irradiation from a 150 Watt lamp. After 3 hours, the reaction is terminated, the mixture is cooled to 15°C and precipitated succinimide is removed by filtration. After evaporation of the solvent, the residue is distilled under reduced pressure. This gives ethyl 2-bromomethyl-6-trifluoromethylnicotinate as an oily product (260.2 g, 44.7% of theory, b.p. 74°C/0.04 mmHg). Example H2: 2-(2-Methoxyethoxymethyl)-6-trifluoromethylnicotinic acid: At room temperature,177.2 g of ethyl 2-bromomethyl-6-trifluoromethylnicotinate are dissolved in 3 000 ml of toluene and reacted with 398 ml (1.704 mol) of a 21 % ethanolic solution of sodium ethoxide. After 8 hours at room temperature, 1500 ml of ethanol and 100 ml of 30% aqueous sodium hydroxide solution are added with vigorous stirring, and the reaction mixture is stirred at this temperature for another 4 hours. The reaction mixture is poured into water and extracted with ethyl acetate, and the aqueous phase is acidified to pH 1. Following extraction with ethyl acetate, drying over sodium sulfate, evaporation under reduced pressure and trituration with hexane, pure 2-(2-methoxyethoxymethyl)-6-trifluoro- methylnicotinic acid is obtained in the form of white crystals of melting point 62-63°C. Example H3: 4-Hvdroxy-3-f2-(2-methoxyethoxymethyl)-6-trifluoromethylpyridine-3-carbonvn- bicyclof3.2.1 loct-3-en-2-one: 24.9 g (0.1 mol) of 2-(2-methoxyethoxymethyl)-6-trifluoromethylnicotinic acid are dissolved in 200 ml of methylene chloride and 20 ml of oxalyl chloride, and 0.1 ml of dimethylformamide is then added dropwise. After the strong evolution of gas has ceased, triethylamine (27.9 ml, 0.2 mol), dimethylaminopyridine (1.22 g, 0.01 mol) and 15.2 g (0.1 1 mol) of bicyclo[3.2.1]octane-2,4-dione are added at a temperature of from 0 to 5°C. After 3 hours at 22°C, the reaction mixture is extracted with 2 N hydrochloric acid. The methylenechloride phase is separated off, washed with water and then extracted with 10% aqueous sodium bicarbonate solution, dried over sodium sulfate and concentrated. This gives 36.9 g (100% of theory) of 4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-(2-methoxyethoxymethyl)-6-trifluoromethyl- nicotininate as an oil, which can be used further without purification. 36.9 g (0.1 mol) of 4-oxobicyclo[3.2.1]oct-2-en-2-yl 2-(2-methoxyethoxymethyl)-6-trifluoro- methylnicotinate and 27.9 ml (0.2 mol) of triethylamine are dissolved in 400 ml of acetonitrile. At a temperature of 22°C, 0.92 ml (0.01 mol) of acetone cyanohydrin is added. After 18 hours at 22°C, the reaction mixture is poured into a water/2 N hydrochloric acid mixture and extracted with ethyl acetate. The ethyl acetate phase is washed with water and then with concentrated sodium chloride solution, dried over sodium sulfate and concentrated, and the residue is triturated with hexane. Filtration gives 27.9 g (75.6% of theory) of 4-hydroxyl-3- [2-(2-methoxyethoxymethyl)-6-trifluoromethylpyridine-3-carbonyl]bicyclo[3.2.1]oct-3-en-2-one in the form of white crystals (m.p. 55-56°C). Example H4: 3-(2-Hvdroxy-4-oxobicvclo[3.2.noct-2-en-3-carbonyl)-6-trifluoromethylpyridin-2- yl methyl acetate: 5.0 g (1 mmol) of 4-hydroxy-3-(2-methyl-1 -oxy-6-trifluoromethylpyridin-3-carbonyl)- bicyclo[3.2.1 ]oct-3-en-2-one (preparation as described in WO 00/15615) are dissolved in 100 ml of toluene and, in the presence of 6.9 ml (0.073 mol) of acetic anhydride, heated at reflux temperature for 10 hours. The mixture is then partitioned between water and ethyl acetate and the organic phase is dried over sodium sulfate and concentrated under reduced pressure. The residue that remains is chromatographed on silica gel. The viscous oil obtained by eluting with a mixture of toluene, ethyl alcohol, dioxane, triethylamine and water (100:40:20:20:5 parts by volume) is dissolved in ethyl acetate and washed successively with 10% hydrochloric acid and water. The organic solution is dried over Na 2 SO 4 and concentrated, giving 2.14 g (38%) of pure 3-(2-hydroxy-4-oxobicyclo[3.2.1]oct-2-ene-3- carbonyl)-6-trifluoromethylpyridin-2-ylmethyl acetate in the form of an oil. 1 H-NMR (250 MHz, CDCI 3 ): 17.06 (s), 1 H; 7.67 (s), 2H; 5.27 (d, J = 12.5 Hz), 1 H; 5.20 (d, J = 12.5 Hz), 1 H; 3.18, (t, J = 5.0 Hz), 1 H; 2.92, (t, J = 5.0 Hz), 1 H; 2.29-1.98 (m), 4H; 2.00, (s), 3H; 1.81 -1.73 ppm (m), 2H. Example H5: 4-Hvdroxy-3-(2-oxiranylmethoxymethyl-6-trifluoromethylpyridine-3-carbonyl)- bicyclo[3.2.1 loct-3-en-2-one: 5 g (0.013 mol) of 3-(2-hydroxy-4-oxobicyclo[3.2.1]oct-2-ene-3-carbonyl)-6-trifluoromethyl- pyridin-2-ylmethyl acetate are dissolved in 60 ml of methanol/water (3:1 mixture), and 1.4 g (0.046 mol) of lithium hydroxide hydrate are added a little at a time at a temperature of 22°C. After 3 hours at 22°C, the reaction mixture is poured into ethyl acetate and 10% hydrochloric acid, and the organic phase is washed three times with water, dried with sodium sulfate and concentrated. This gives 4.1 g of 4-hydroxy-3-(2-hydroxymethyl-6-trifluoromethylpyridine-3- carbonyl)bicyclo[3.2.1]oct-3-en-2-one as an oil which can be reacted further without purification. 1.5 g of 4-hydroxy-3-(2-hydroxymethyl-6-trifluoromethylpyridine-3-carbonyl)-bicyclo[3.2.1]oct- 3-en-2-one are dissolved in 15 ml of dimethylformamide and, at room temperature, treated with 0.4 g of sodium hydride (80% suspension in oil, 0.013 mol), a little at a time. After 15 minutes at a temperature of 22°C, 3ml (0.036 mol) of epibromohydrin are added dropwise, and the reaction mixture is stirred at this temperature for another 18 hours. Ethyl acetate is then added, and the mixture is acidified to pH 3 using 10% hydrochloric acid and extracted with ethyl acetate. The organic phase is dried over sodium sulfate and the crude product is purified chromatographically (mobile phase: toluene/ethyl alcohol/dioxane/triethylamine/water 100:40:20:20:5 parts by volume). This gives the title compound (triethylamine salt) in the form of a yellowish resin, which is released similarly to example H4. Trituration with hexane gives 600 mg of pure 4-hydroxy-3-(2-oxiranylmethoxy- methyl-6-trifluoromethylpyridin-3-carbonyl)bicyclo[3.2.1]oct-3-en-2-one of melting point 54-56°C. Example H6: (5-Hydroxy-1 ,3-dimethyl-1 H-pyrazol-4-yl)-| " 2-(2-methoxyethoxymethyl)- 6-trifluoromethylpyridin-3-vHmethanone: 1.0 g (0.004 mol) of 2-(2-methoxyethoxymethyl)~6-trifluoromethylnicotinic acid is dissolved in 10 ml of oxalyl chloride. Three drops of dimethylformamide are added, and the mixture is stirred at room temperature for 1 hour. The mixture is then concentrated using a rotary evaporator, and the residue (2-(2-methoxyethoxymethyl)-6-trifluoromethylnicotinoyl chloride) is taken up in 10 ml of methylene chloride. At a temperature of 0°C, 0.84 ml (0.006 mol) of triethylamine and 0.45 g (0.004 mol) of 2,5-dimethyl-2,4-dihydropyrazol-3-one are added. After 2 hours at a temperature of 22°C, the solvent is removed using a vacuum rotary evaporator, and the residue that remains is dissolved in 10 ml of acetonitrile and, to rearrange the intermediate (2,5-dimethyl-2H-pyrazol-3-yl 2-(2-methoxyethoxymethyl)-6- trifluoromethylnicotinate), admixed with 0.1 ml of acetone cyanohydrin and 1.13 ml (0.008 mol) of triethylamine. The reaction solution is stirred at room temperature for four hours and then concentrated. The syrup that remains is chromatographed on silica gel. The viscous oil obtained by eluting with a mixture of toluene, ethyl alcohol, dioxane, triethylamine and water (100:40:20:20:5 parts by volume) is dissolved in ethyl acetate and washed successively with 10% hydrochloric acid and water. The organic solution is dried over Na 2 SO 4 and concentrated, giving 0.93 g of (5-hydroxy-1 ,3-dimethyl-1 H-pyrazol-4-yl)-[2-(2- methoxyethoxymethyl)-6-trifluoromethylpyridin-3-yl]methanone in the form of a viscous oil. 1 H NMR (300 MHz, CDCI 3 , δ in ppm): 7.81 , (d, J = 6 Hz), 1 H; 7.74, (d, J = 6 Hz), 1 H; 4.84, (s), 2H; 2H: 3.71 , (s), 3H; 3.59, (t, J= 6 Hz) 2H; 3.38, (dd, J 4.0, 3.0 Hz), 1 H; 3.26, (s), 3H; 1.82 ppm, (s), 1 H. Preferred compounds of the formula I and their intermediates are listed in the tables below. In the table below, the left-hand valency of the radical Ri is attached to the pyridine ring. If CH no free valency is indicated in the substituent R 2 , as, for example, in the case of ° , the point of attachment is at the "CH" carbon atom. In the table below, the compounds of the formula I are represented as: A-Q where the formula A denotes the following radicals: Radical Ri R 2 R 4 R 3 Xi P A2 CH 2 CH 2 CH 3 H CF 3 O 0 A3 CH 2 (CH 3 ) 2 CH H CF 3 O 0 A4 CH 2 PhCH 2 H CF 3 O 0 A5 CH 2 CH 3 H CF 3 s 0 A6 CH 2 CH 3 H CF 3 SO 0 A7 CH 2 CH 3 H CF 3 SO 2 0 A8 CH 2 CH 3 OCH 2 H CF 3 O 0 A9 CH 2 CH 3 CH 2 OCH 2 H CF 3 O 0 A10 CH 2 CH 3 OCH 2 CH 2 H CF 3 O 0 Radical i R 2 R 4 R 3 Xi P A11 CH 2 CH 3 CH2OCH 2 CH2 H CF 3 O 0 A12 CH 2 CH 3 OC(CH 3 ) 2 CH 2 H CF 3 O 0 A13 CH 2 CH 3 OCH(CH 3 )CH 2 H CF 3 O 0 A14 CH 2 CH 3 OCH 2 CH(CH 3 ) H CF 3 O 0 A15 CH 2 CH 3 OCH 2 C(CH 3 ) 2 H CF 3 O 0 A16 CH 2 CH 3 OCH(CH 3 ) H CF 3 O 0 A17 CH 2 CH 3 OC(CH 3 ) 2 H CF 3 O 0 A18 CH 2 HC≡CCH 2 H CF 3 O 0 A19 CH 2 H 2 C=CHCH 2 H CF 3 O 0 A20 CH 2 CH 3 C≡CCH 2 H CF 3 O 0 A21 CH 2 • [ H H CF 3 O 0 A22 CH 2 ° CH H CF 3 O 0 A23 CH 2 H CF 3 O 0 CH 0 A24 CH 2 Λ ^ CH H CF 3 O 0 A25 CH 2 r H CF 3 O 0 A26 CH 2 H CF 3 O 0 C CH A29 CH 2 H CF 3 O 0 O^ / CH A31 CH 2 H CF 3 O 0 Q.CH Radical Ri Xi A43 CH 2 H CF 3 O 0 N^ Radical R^ R 2 R 4 Ra Radical Ri R R 3 Xt A58 CH 2 A ^CH 2 H CF 3 O 0 A60 CH 2 /\^CH 2 H CF 3 O 0 A61 CH 2 /\ ^ CH 2 H CF 3 O 0 A62 CH 2 CH, H CF 3 O 0 Radical R ? R Λ Xi A73 CH, J OCH p CH p H CF 3 O Radical Ri Rp X A91 CH 2 CH 2 CH 3 H CF 3 O 0 A92 CH2CH2 CH 3 CH 2 H CF 3 O 0 A93 CH 2 CH 2 (CH 3 ) 2 CH H CF 3 O 0 A94 CH 2 CH 2 PhCH 2 H CF 3 O 0 A95 CH 2 CH 2 CH 3 H CF 3 S 0 A96 CH 2 CH CH 3 H CF 3 SO 0 A98 CH 2 CH 2 (CH 3 ) CHCH 2 H CF 3 O Radical Ri Xi A133 CH 2 CH 2 H CF 3 O 0 Radical R n R 2 RA Xi Radical Ri Rp R 3 Xi A147 CH 2 CH 2 [>-CH 2 H CF 3 O 0 A149 CH 2 CH 2 Λv- CH 2 H CF 3 O 0 A151 CH 2 CH 2 ^N-CH 2 H CF 3 O 0 A152 CH 2 CH 2 ^^CH 2 H CF 3 O 0 o—l A158 CH 2 CH 2 H CF 3 O 0 Radical Ri Rp R4 R 3 X1 A159 CH 2 CH 2 H CF 3 O 0 OCH, A164 CH CH 2 H CF 3 O 0 A168 CHPCHP H CF 3 O 0 Radical R 1 R 2 R 4 R 3 Xi p A175 CH 2 CH 2 O H H CF 3 O 0 ΓΎ CHZ A177 CH 2 CH 2 H H2 2 HH CCFF 33 O 0 A182 CH(OCH 3 )CH 2 CCHH 33 HH CCFF 33 O 0 A183 CH(OCH 3 )CH 2 CCHH 33 CCHH 22 HH CCFF 33 O 0 A184 CH(OCH 3 )CH 2 ((CCHH 33 )) 22 CCHH HH CCFF 33 O 0 Radical R R 2 R 4 R 3 X 1 p _____ _____________ ^ _ __ _ _ O^CH A212 CH(OCH 3 )CH 2 Q ^ H CF 3 O 0 ,CH A213 CH(OCH 3 )CH 2 H CF 3 O 0 A214 CH(OCH 3 )CH 2 H CF 3 O 0 A215 CH(OCH 3 )CH 2 H CF 3 O 0 A216 CH(OCH 3 )CH 2 H CF 3 O 0 A217 CH(OCH 3 )CH 2 H CF 3 O 0 A218 CH(OCH 3 )CH 2 H CF 3 O 0 A219 CH(OCH 3 )CH 2 H CF 3 O 0 A220 CH(OCH 3 )CH 2 H CF 3 O 0 A221 CH(OCH 3 )CH 2 H CF 3 O 0 A222 CH(OCH 3 )CH 2 n H CF 3 O 0 I CH 3 Radical Ri R 2 R R 3 Xi p A224 CH(OCH 3 )CH 2 H CF 3 O 0 0 A232 CH(OCH 3 )CH 2 H CF 3 O 0 A233 CH(OCH 3 )CH 2 / H CF 3 O 0 o A234 CH(OCH 3 )CH 2 H CF 3 O 0 Radical Ri Rp R 4 Xi A238 CH(OCH 3 )CH 2 ^-CH 2 H CF 3 O 0 A239 CH(OCH 3 )CH 2 H CF 3 O 0 A240 CH(OCH 3 )CH 2 ^CH 2 H CF 3 O 0 A241 CH(OCH 3 )CH 2 CH, H CF 3 O 0 O A242 CH(OCH 3 )CH 2 CH, H CF 3 O 0 A243 CH(OCH 3 )CH 2 CH, H CF 3 O 0 o A244 CH(OCH 3 )CH 2 H CF 3 O 0 A246 CH(OCH 3 )CH 2 H CF 3 O 0 A247 CH(OCH 3 )CH 2 H CF 3 O 0 A248 CH(OCH 3 )CH 2 H CF 3 O 0 ° O1 CH, Radical Ri R 2 4 R 3 Xi F CH(OCH 3 )CH 2 H CF 3 O 0 C A253 CH(OCH 3 )CH 2 H CF 3 O 0 A254 CH(OCH 3 )CH 2 / CH 2 H CF 3 O 0 A255 CH(OCH 3 )CH 2 0 H CF 3 O 0 A256 CH(OCH 3 )CH 2 H CF 3 O 0 A257 CH(OCH 3 )CH 2 H CF 3 O 0 A258 CH(OCH 3 )CH 2 H CF 3 O 0 A259 CH(OCH 3 )CH 2 H CF 3 O 0 A260 CH(OCH 3 )CH 2 ^^ CH 2 H CF 3 O 0 Radical R n R 2 R 4 R 3 X ! p A262 CH(OCH 3 )CH 2 H CF 3 O 0 A263 CH(OCH 3 )CH 2 H CF 3 O 0 A264 CH(OCH 3 )CH 2 H CF 3 O 0 A265 CH(OCH 3 )CH 2 0CH 3 H CF 3 O 0 CΎ CHZ A266 CH(OCH 3 )CH 2 OH H CF 3 O 0 fy CH _ A267 CH(OCH 3 )CH 2 X H 2 H CF 3 O 0 A268 CH(OCH 3 )CH 2 / CH 2 H CF 3 O 0 O A269 CH(OCH 3 )CH 2 H CF 3 O 0 A270 CH(OCH 3 )CH 2 H CF 3 O 0 A271 CH(OCH 3 )CH 2 H CF 3 O 0 A272 CH(OCH 3 )CH 2 H CF 3 O 0 Radical R 1 R 2 R 4 R 3 X, p ~ A300 CH 2 CH(OCH 3 )CH 2 H CY 3 O 0 ~ A301 CH 2 CH(OCH 3 )CH 2 ^\ H CF 3 O 0 V CH A302 CH 2 CH(OCH 3 )CH 2 ^\ H CF 3 O 0 O^ / CH A303 CH 2 CH(OCH 3 )CH 2 Q ^ H CF 3 O 0 ,CH A304 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A305 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A306 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A307 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A308 CH 2 CH(OCH 3 )CH 2 H CF 3 O A309 CH 2 CH(OCH 3 )CH 2 H CF 3 O A310 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A311 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A312 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 Radical R, R 2 R 4 R 3 X 1 p A314 CH 2 CH(OCH 3 )CH 2 H CF 3 O A315 CH 2 CH(OCH 3 )CH 2 H CF 3 O A316 CH 2 CH(OCH 3 )CH 2 (^^ H CF;3 ° A317 CH 2 CH(OCH 3 )CH 2 H CF 3 O A318 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A319 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A320 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A321 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A322 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A323 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A324 CH 2 CH(OCH 3 )CH 2 / H CF 3 O 0 Radical Ri Xi A325 CH 2 CH(OCH 3 )CH 2 H CF 3 O A326 CH 2 CH(OCH 3 )CH 2 H CF 3 O A327 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A328 CH 2 CH(OCH 3 )CH 2 H CF 3 O A329 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A330 CH 2 CH(OCH 3 )CH 2 o~. H CF 3 O 0 A331 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A332 CH 2 CH(OCH 3 )CH 2 -CH, H CF 3 O 0 o. A333 CH 2 CH(OCH 3 )CH 2 -CH, H CF 3 O 0 A334 CH 2 CH(OCH 3 )CH 2 -CH, H CF 3 O 0 A335 CH 2 CH(OCH 3 )CH 2 H, H CF 3 O 0 A336 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A337 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A338 CH 2 CH(OCH 3 )CH 2 O H CF 3 O 0 CH, Radical Ri R 4 Xi A340 CH 2 CH(OCH 3 )CH 2 CH, A341 CH 2 CH(OCH 3 )CH 2 r * H CF 3 O 0 A343 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A344 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A345 CH 2 CH(OCH 3 )CH 2 y CH 2 H CF 3 O 0 A346 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A347 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A348 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A349 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A350 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 Radical R R 2 R 4 R 3 p A352 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A353 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A354 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A355 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A356 CH 2 CH(OCH 3 )CH 2 OCH 3 H CF 3 O 0 c" 2 A357 CH 2 CH(OCH 3 )CH 2 ? H H CF 3 O 0 rγ 0H' A358 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A359 CH 2 CH(OCH 3 )CH 2 H CF 3 O A360 CH 2 CH(OCH 3 )CH 2 H CF 3 O A361 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 A362 CH 2 CH(OCH 3 )CH 2 H CF 3 O 0 Radical Rp R 3 Xi P A390 CH=CHCH 2 CH H CF 3 O o- A394 CH=CHCH 2 H CF 3 O 0 L^CH A402 CH=CHCH 2 H CF 3 O 0 Radical R Rp R 4 Xi Radical Ri Rp R 3 Xi A420 CH=CHCH 2 [ -CH 2 H CF 3 O 0 A422 CH=CHCH 2 A423 CH=CHCH 2 r -CH, H CF 3 O 0 CH, H CF 3 O 0 o A425 CH=CHCH 2 ^N- C H 2 H CF 3 0 o—l Radical Ri R 4 R 3 A432 CH=CHCH 2 H CF 3 O 0 Radical Ri Xi A442 CH=CHCH 2 .CH, H CF 3 O 0 o o O O O O O O O O o III OIII O O O O O O O O O O O O O o o o O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O ro X ro X ~ X ~ X~ ~ X ~ X _ X ~ ~ X ~ X X X X X X X X X X X X X X X x X X X X X X X X X X X X X X X X X X X X X X o o Tl o Ti o Tl o o o o o o O O O O O O O O O O O O O O O θ n ω O O O O O Radical R R 2 R 4 R 3 Xi p ___ _ __ _ _ A479 C≡CCH 2 A480 C≡CCH 2 CH H CF 3 O 0 A481 C≡CCH 2 CH H CF 3 O A484 C≡CCH 2 /\ H CF 3 O 0 O^^CH A485 C≡CCH 2 o^ H CF 3 O 0 XH A492 C≡CCH 2 / H CF 3 O 0 Q Radical R 1 Rp R 3 Xi Radical Ri Rp R 4 R 3 Xi A51 1 C≡CCH 2 P>-CH 2 H CF 3 O 0 A513 C≡CCH 2 H CF 3 O 0 A514 C≡CCH 2 CH, H CF 3 O 0 o A515 C≡CCH 2 CH, H CF 3 O 0 A516 C≡CCH 2 CH, H CF 3 O 0 o Radical R 1 R 2 R 4 R 3 X n p Radical Ri R 2 A532 C≡CCH P ,CH, H CF 3 O Radical Ri Rp R 4 R 3 P A546 CH 2 CH 3 H CF 2 CI O 0 A547 CH 2 CH 3 CH 2 H CF 2 CI O 0 A548 CH 2 (CH 3 ) 2 CH H CF 2 CI O 0 A549 CH 2 PhCH 2 H CF 2 Cl O 0 A550 CH 2 CH 3 H CF 2 Cl S 0 A551 CH 2 CH 3 H CF 2 CI SO 0 A552 CH 2 CH 3 H CF 2 CI SO 2 0 A553 CH 2 CH 3 CH 2 CH 2 H CF 2 CI O 0 A554 CH 2 CH 3 OCH 2 H CF 2 CI O 0 A555 CH 2 CH3CH2OCH2 H CF 2 CI O 0 A556 CH 2 CH 3 OCH CH 2 H CF 2 CI O 0 A557 CH 2 CH 3 CH 2 OCH 2 CH 2 H CF 2 CI O 0 A558 CH 2 CH 3 OC(CH 3 ) 2 CH 2 H CF 2 CI O 0 A559 CH 2 CH 3 OCH(CH 3 )CH 2 H CF 2 CI O 0 A560 CH 2 CH 3 OCH 2 CH(CH 3 ) H CF 2 CI O 0 A561 CH 2 CH 3 OCH 2 C(CH 3 ) 2 H CF 2 CI O 0 A562 CH 2 CH 3 OCH(CH 3 ) H CF 2 CI O 0 A563 CH 2 CH 3 OC(CH 3 ) 2 H CF 2 CI O 0 A564 CH 2 HC≡CCH 2 H CF 2 CI O 0 A565 CH 2 H 2 C=CHCH 2 H CF 2 CI O 0 A566 CH 2 CH 3 C=CCH 2 H CF 2 CI O 0 A568 CH 2 ° CH H CF 2 CI O 0 Radical R^ R 2 R 4 R 3 Xi p A571 CH 2 CH H CF 2 CI O 0 A572 CH 2 CH H CF 2 CI O 0 O- A574 CH 2 ^\ H CF 2 CI O 0 V CH A575 CH 2 /\ H CF 2 CI O 0 O^_^CH A576 CH 2 p^ H CF 2 CI O 0 CH Radical Ri R 3 Xi A594 CHp H CF 2 CI O 0 Radical Ri Xi P A598 CHp H CFoCI O A602 CH 2 >-CH 2 H CF 2 CI O 0 A603 CH 2 O L -CH 2 H CF P CI O A604 CH 2 CH, H CF 2 CI O 0 A605 CH 2 -CH, H CF 2 CI O O. A606 CH 2 CH, H CF,CI O A607 CH P H CFPCI O A608 CH 2 H CF 2 CI O Radical Ri R 2 R 4 Radical R 4 R 3 Xi A621 CH 2 H CF 2 CI O ~OCH 2 CH 2 CH, Radical R R 3 P A637 CH 2 CH 3 H CHF 2 O 0 A638 CH CH 2 CH 3 H CHF 2 O 0 A639 CH 2 (CH 3 ) 2 CH H CHF 2 O 0 A640 CH 2 PhCH 2 H CHF 2 O 0 A641 CH 2 CH 3 H CHF 2 S 0 A642 CH 2 CH 3 H CHF 2 O 0 A643 CH 2 CH 3 H CHF 2 O 0 A644 CH 2 CH 3 OCH 2 H CHF 2 O 0 A645 CH 2 CH 3 CH2OCH2 H CHF 2 O 0 A646 CH 2 CH 3 OCH2CH 2 H CHF 2 O 0 A647 CH 2 CH 3 CH 2 OCH 2 CH 2 H CHF 2 O 0 A648 CH 2 CH 3 OC(CH 3 ) 2 CH 2 H CHF 2 O 0 A649 CH 2 CH 3 OCH(CH 3 )CH 2 H CHF 2 O 0 A650 CH 2 CH 3 OCH 2 CH(CH 3 ) H CHF 2 O 0 A651 CH 2 CH 3 OCH 2 C(CH 3 ) 2 H CHF 2 O 0 A652 CH 2 CH 3 OCH(CH 3 ) H CHF 2 O 0 A653 CH 2 CH 3 OC(CH 3 ) 2 H CHF 2 O 0 A654 CH 2 HC≡CCH 2 H CHF 2 O 0 A655 CH 2 H 2 C=CHCH 2 H CHF 2 O 0 A656 CH 2 CH 3 C=CCH 2 H CHF 2 O 0 A657 CH 2 ^CH H CHF 2 O 0 Radical R^ R 2 R 4 R 3 X^ p ^_ _ _ ___ _ __ A658 CH 2 A661 CH 2 CH H CHF 2 O A662 CH 2 CH H CHF 2 O O- A665 CH 2 /\ H CHF 2 O 0 O^ H A666 CH 2 -^ H CHF 2 O 0 XH Radical Ri Rp Xi Radical Ri R? R 3 Xi A692 CH 2 [^CH 2 H CHF 2 O 0 A694 CH 2 CH, H CHF 2 O 0 A695 CH 2 CH, H CHF 2 O 0 O Radical R, R 2 R 4 R 3 X, p A704 CH 2 XH 2 r H CHF 2 O 0 K ^ OCH 3 Radical Ri R 2 R 3 Xi Radical Ri R p R 4 R 3 X1 A727 CH 2 CH 3 H CF 3 O 1 A728 CH 2 CH 2 CH 3 H CF 3 O 1 A729 CH 2 (CH 3 ) 2 CH H CF 3 O 1 A730 CH 2 PhCH 2 H CF 3 O 1 A731 CH 2 CH 3 H CF 3 S 1 A732 CH 2 CH 3 H CF 3 SO 1 A733 CH 2 CH 3 H CF 3 SO 2 1 A734 CH 2 CH 3 OCH 2 H CF 3 O 1 A735 CH 2 CH 3 CH 2 OCH 2 H CF 3 O 1 A736 CH 2 CH3OCH2CH2 H CF 3 O 1 A737 CH 2 CH3CH2OCH2CH2 H CF 3 O 1 A738 CH 2 CH 3 OC(CH 3 )2CH 2 H CF 3 O 1 A739 CH 2 CH 3 OCH(CH 3 )CH 2 H CF 3 O 1 A740 CH 2 CH 3 OCH 2 CH(CH 3 ) H CF 3 O 1 A741 CH 2 CH 3 OCH 2 C(CH 3 ) 2 H CF 3 O 1 A742 CH 2 CH 3 OCH(CH 3 ) H CF 3 O 1 A743 CH 2 CH 3 OC(CH 3 ) 2 H CF 3 O 1 A744 CH 2 HC≡CCH 2 H CF 3 O 1 A745 CH 2 H 2 C=CHCH 2 H CF 3 O 1 A746 CH 2 CH 3 C≡CCH 2 H CF 3 O 1 Radical R R 2 R R 3 X p A747 CH 2 [>H H CF 3 O A748 CH 2 ° CH H CF, O A749 CH 2 H CF 3 O C CH A751 CH 2 H CF 3 O Cf" A752 CH 2 CH H CF 3 O O- A755 CH 2 /\ H CF 3 O O^ H A756 CH 2 Q ^\ H CF 3 O CH Radical Ri R 2 R 3 Xi Radical R 3 Xi P A782 CH 2 [>-CH 2 H CF 3 O A784 CH 2 ^CH 2 H CF 3 O A787 CH 2 ^^CH 2 H CF 3 O o— ' Radical R^ R 2 R 4 R 3 Xi i A793 CH 2 ^^CH 2 H CF 3 O 1 A799 CH 2 CH 3 . /O CH 2 CH 2 H CF 3 0 1 ^CH, Radical Ri R 3 Xi Radical Ri R 2 R 4 R3 X1 P A817 CH 2 CH 3 SCH 2 CH 2 H CF 3 O 0 A818 CH 2 CH 3 SOCH 2 CH 2 H CF 3 O 0 A819 CH 2 CH 3 SO 2 CH 2 CH 2 H CF 3 O 0 A820 CH 2 CH3OCH2CH2 H CF 2 CI O 1 A821 CH 2 CH 3 OCH 2 CH2 H CF 2 H O 1 A822 CH 2 CH 3 OCH 2 CH 2 F CF 3 O 0 A823 CH 2 CH 3 OCH 2 CH 2 CH 3 CF 3 O 0 A824 CH 2 CH 3 OCH 2 CH2 CH 3 CF 3 O 1 A825 CH 2 CH3OCH2CH2 H CF 3 s 0 A826 CH 2 CH 3 OCH 2 CH 2 H CF 3 SO 0 A827 CH 2 CH 3 OCH 2 CH 2 CH 3 CF 3 SO 2 0 A828 CH 2 CH 3 SO 2 CH 2 CH 2 CH 3 CF 3 O 0 Radical i X! P A833 CH 2 CH 3 C(O) H CF 3 O 0 A834 CH 2 CF 3 CH 2 H CF 3 O 0 A835 CH 2 CH 3 OCH 2 CH2θCH 2 CH2 H CF 3 O 0 A836 CH 2 HC≡CCH2CH2 H CF 3 O 0 A837 CH 2 H CF 3 O 0 Or A838 CH 2 CH 3 CH 2 C(OCH3)HOCH 2 CH2 H CF 3 O 0 A839 CH 2 (CH 3 ) 3 CC(O) H CF 3 O 0 A840 CH 2 CH 2 =CHCH 2 OCH 2 CH 2 H CF 3 O 0 A841 CH 2 CH 3 CH 2 CH 2 OCH 2 CH 2 H CF 3 O 0 A843 CH 2 n-Heptyl-C(O) H CF 3 O 0 A844 CH 2 Phenyl-C(O) H CF 3 O 0 A845 CH 2 CF3CH2OCH2CH2 H CF 3 O 0 A846 CH 2 CH 3 OCH2CH2CH2 H CF 3 O 0 A847 CH 2 HOCH2CH2CH2 H CF 3 O 0 A849 CH 2 N≡CCH 2 CH 2 H CF 3 O 0 A850 CH 2 CICH2CH2 H CF 3 O 0 A851 CH 2 p-\ H CF 3 O 0 CH o __/ A852 CH, O H CF, O CH, -o A853 CH, CH 3 OCH 2 C(Br)HCH 2 H CF 3 O Radical Rp R 3 Xi P A854 CH, O H CF 3 O ~ 0 CH, -s A856 CH 2 HOCH 2 CH 2 H CF 3 O 0 A858 CH 2 CH 3 (OCH 2 CH 2 ) 3 H CF 3 O 0 A859 CH 2 CH 3 CH 2 OC(CH 3 )HOCH 2 CH 2 H CF 3 O 0 A860 CH 2 n-Heptyl-C(O)OCH 2 CH 2 H CF 3 O 0 A861 CH 2 CH 3 C(O)OCH 2 CH 2 H CF 3 O 0 A862 CH 2 CH 3 SO 2 OCH 2 CH 2 H CF 3 O 0 A864 CH 2 CH 3 H CF 3 -NCH3SO2- 0 A865 CH 2 HOCH 2 C(OH)HCH 2 H CF 3 O 0 A866 CH 2 Phenyl-C(O)OCH 2 CH 2 H CF 3 O 0 A867 CH 2 t-Butyl-C(O)OCH 2 CH 2 H CF 3 O 0 A868 CH 2 CH 3 OC(O)CH 2 H CF 3 O 0 In the table below, in the case of rings, the ring attachment points for the substituents A^ and A 2 are at the carbon atom which is marked "C", for example he ^ , in the case of open-chain structures, "(CH 3 ) 2 C" denotes, for example, H:i0 In the formula A-Q, Q denotes Q and Qi denotes the following radicals B: Radical A T A 2 n R21 R22 l3 B1 CH 2 CH 2 0 H H OH B2 CH 2 CH 2 0 CH 3 H OH B3 CH 2 CH 2 0 CH 3 CH 3 OH B4 (CH 3 )CH CH 2 0 CH 3 CH 3 OH B5 (CH 3 ) 2 C CH 2 0 CH 3 CH 3 OH B6 CH CH 0 CH 3 - OH B7 CH 2 CH 2 0 CH 3 CH 2 =CHCH 2 OH B8 CH 2 CH 2 0 CH 3 HC≡CCH 2 OH B9 CH 2 CH 2 0 CH 3 CH 3 S OH B10 CH 2 CH 2 0 CH 3 CH 3 SO OH B11 CH 2 CH 2 0 CH 3 CH 3 SO 2 OH B12 CH 2 CH 2 0 CH 3 CH 3 O OH B13 CH 2 CH 2 0 CH 3 CH 3 OC(O) OH B14 CH 2 CH 2 0 CH 3 CH 3 CH 2 OC(O) OH B15 CH 2 (CH 3 ) 2 C 0 H H OH B16 O CH 2 0 H H OH B17 l CH 2 0 H H OH B20 CH 2 0 H H OH B21 CH 2 0 CH 3 H OH B22 CH 2 0 CH 3 CH 3 OH B23 (CH 3 ) 2 C O 0 CH 3 CH 3 OH B24 CH 2 O 0 CH 3 CH 3 OH Radical A T A 2 n R21 R22 ι 3 B25 CH 3 N O 0 CH 3 CH 3 OH B28 CH 3 N (CH 3 )CH 0 H H OH B29 CH 3 N (CH 3 )CH 0 CH 3 H OH B30 NH (CH 3 )C 0 H - OH B31 NH CH 0 CH 3 - OH B32 CH 3 N (CH 3 )C 0 H - OH B33 CH 3 N CH 0 CH 3 - OH B34 O (CH 3 ) 2 C 0 H - OH B35 O (CH 3 ) 2 C 0 CH 3 CH 3 OH B36 O (CH 3 ) 2 C 0 CH 3 H OH B37 O (CH 3 )C 0 H - OH B38 O CH 0 CH 3 - OH B39 (CH 3 ) 2 C C=O 0 CH 3 CH 3 OH B40 (CH 3 ) 2 C (OH)CH 0 CH 3 CH 3 OH B41 C=O 0 CH 3 CH 3 OH B42 [ C=O 0 CH 2 CH 2 OH B43 (CH 3 ) 2 C 0 CH 3 CH 3 OH V c B44 (CH 3 ) 2 C CH 3 O χ 0 CH 3 CH 3 OH CH 3 0^ C B47 (CH 3 ) 2 C HON=C 0 CH 3 CH 3 OH B48 (CH 3 ) 2 C CH 3 ON=C 0 CH 3 CH 3 OH B49 (CH 3 ) 2 C BnON=C 0 CH 3 CH 3 OH B50 CH O 1 H CH 2 OH B51 CH C=O 1 H CH 2 OH Radical A, A 2 n R21 R22 Rl3 B1 11 CH 2 (CH 3 )CH 0 H H OH B112 CH 2 CH 2 1 H CH 2 t-Butyl-C(O)O B113 CH 2 CH 2 1 H CH 2 t-Heptyl-C(O)O or Q in the formula A-Q denotes Q 2 and Q 2 denotes the following radicals C: Radical R 34 R35 R36 C1 CH 3 H OH C2 CH 3 CH 3 OH C3 H HC≡CCH 2 OH C4 H CH 3 SO 2 OH C5 H CH 3 OH C6 H PhCH 2 OH C7 CF 3 CH 3 OH C9 CH 3 OCH 2 CH 2 OCH 2 CH 3 OH C10 H CH 3 CI C11 H CH 3 NH 2 C12 H CH 3 CH 3 SO 2 NH C13 H CH 3 CH 3 OCH 2 CH 2 S C14 H CH 3 CH 3 OCH 2 CH 2 SO C15 H CH 3 CH 3 OCH 2 CH2SO 2 Radical R 3 R35 R36 C16 H CH 3 (CH 3 ) 2 NC(O)NH C17 H CH 3 PhC(O)O C18 H CH 3 CH 3 OC(O)O C19 H CH 3 CH 3 (CH 2 ) 7 S C20 H CH 3 CH 3 (CH 2 ) 7 SO C21 H CH 3 CH 3 (CH 2 ) 7 SO 2 C22 H CH 3 (CH 3 ) 2 NSO 2 NH C23 H CH 3 PhS C24 H CH 3 PhSO C25 H CH 3 PhSO 2 C28 H CH 3 CH 3 SO 2 O C29 H CH 3 p-ToiylSO 2 O or Q in the formula A-Q denotes Q 3 and Q 3 denotes the following radicals D (the point of attachment of R 49 to the heterocycle is the "CH" group): Radical R 49 R 50 n D1 ^ CH CH 3 0 Radical R 9 R50 n D2 [ H CH 3 1 D5 ^CH CF 3 1 D6 [ H CF 3 2 D7 [ H Ph 0 D8 [ H Ph 1 D9 ^CH Ph 2 D10 CH PhCH 2 0 D11 [ H PhCH 2 1 D12 [ H PhCH 2 2 Table 1 : Intermediates for preparing the compounds of the formula I, represented as formula A-Q in which Q denotes hydroxyl: OH OH OH OH OH OH OH OH OH OH OH OH A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A71 A72 A73 A74 A75 A76 A77 A78 A79 A80 A81 A82 A83 A84 OH OH OH OH OH OH OH OH OH OH OH OH A85 A86 A87 A88 A89 A90 - - ' - - - - A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148 A149 A150 A151 A152 A153 A154 A155 A156 A157 A158 A159 A160 A161 A162 A163 A164 A165 A166 A167 A168 A169 A170 A171 A172 A173 A174 A175 A176 A177 A178 A179 A180 A181 A182 A183 A184 A185 A186 A187 A188 A189 A190 A191 A192 A193 A194 A195 A196 A197 A198 A199 A200 A201 A202 A203 A204 A205 A206 A207 A208 A209 A210 A211 A212 A213 A214 A215 A216 A217 A218 A219 A220 A221 A222 A223 A224 A225 A226 A227 A228 A229 A230 A231 A232 A233 A234 A235 A236 A237 A238 A239 A240 A241 A242 A243 A244 A245 A246 A247 A248 A249 A250 A251 A252 A253 A254 A255 A256 A257 A258 A259 A260 A261 A262 A263 A264 A265 A266 A267 A268 A269 A270 A271 A272 A273 A274 A275 A276 A277 A278 A279 A280 A281 A282 A283 A284 A285 A286 A287 A288 A289 A290 A291 A292 A293 A294 A295 A296 A297 A298 A299 A300 A301 A302 A303 A304 A305 A306 A307 A308 A309 A310 A311 A312 A313 A314 A315 A316 A317 A318 A319 A320 A321 A322 A323 A324 A325 A326 A327 A328 A329 A330 A331 A332 A333 A334 A335 A336 A337 A338 A339 A340 A341 A342 A343 A344 A345 A346 A347 A348 A349 A350 A351 A352 A353 A354 A355 A356 A357 A358 A359 A360 A361 A362 A363 A364 A365 A366 A367 A368 A369 A370 A371 A372 A373 A374 A375 A376 A377 A378 A379 A380 A381 A382 A383 A384 A385 A386 A387 A388 A389 A390 A391 A392 A393 A394 A395 A396 A397 A398 A399 A400 A401 A402 A403 A404 A405 A406 A407 A408 A409 A410 A411 A412 A413 A414 A415 A416 A417 A418 A419 A420 A421 A422 A423 A424 A425 A426 A427 A428 A429 A430 A431 A432 A433 A434 A435 A436 A437 A438 A439 A440 A441 A442 A443 A444 A445 A446 A447 A448 A449 A450 A451 A452 A453 A454 A455 A456 A457 A458 A459 A460 A461 A462 A463 A464 A465 A466 A467 A468 A469 A470 A471 A472 A473 A474 A475 A476 A477 A478 A479 A480 OH OH OH OH OH OH OH OH OH OH OH OH A481 A482 A483 A484 A485 A486 A487 A488 A489 A490 A491 A492 A493 A494 A495 A496 A497 A498 A499 A500 A501 A502 A503 A504 A505 A506 A507 A508 A509 A510 A511 A512 A513 A514 A515 A516 A517 A518 A519 A520 A521 A522 A523 A524 A525 A526 A527 A528 A529 A530 A531 A532 A533 A534 A535 A536 A537 A538 A539 A540 A541 A542 A543 A544 A545 - - A554 A555 A556 A557 A558 A559 A560 A561 A562 A563 A564 A565 A566 A567 A568 A569 A570 A571 A572 A573 A574 A575 A576 A577 A578 A579 A580 A581 A582 A583 A584 A585 A586 A587 A588 A589 A590 A591 A592 A593 A594 A595 A596 A597 A598 A599 A600 A601 A602 A603 A604 A605 A606 A607 A608 A609 A610 A611 A612 A613 A614 A615 A616 A617 A618 A619 A620 A621 A622 A623 A624 A625 A626 A627 A628 A629 A630 A631 A632 A633 A634 A635 A636 A644 A645 A646 A647 A648 A649 A650 A651 A652 A653 A654 A655 A656 A657 A658 A659 A660 A661 A662 A663 A664 A665 A666 A667 A668 A669 A670 A671 A672 A685 A686 A687 A688 A689 A690 A691 A692 A693 A694 A695 A696 A697 A698 A699 A700 A701 A702 A703 A704 A705 A706 A707 A708 A709 A710 A711 A712 A713 A714 A715 A716 A717 A718 A719 A720 A721 A722 A723 A724 A725 A726 - - - - - - A733 A734 A735 A736 A737 A738 A739 A740 A741 A742 A743 A744 A745 A746 A747 A748 A749 A750 A751 A752 A753 A754 A755 A756 A757 A758 A759 A760 A761 A762 A763 A764 A765 A766 A767 A768 A769 A770 A771 A772 A773 A774 A775 A776 A777 A778 A779 A780 A781 A782 A783 A784 A785 A786 A787 A788 A789 A790 A791 A792 A793 A794 A795 A796 A797 A798 A799 A800 A801 A802 A803 A804 A805 A806 A807 A808 A809 A810 A811 A812 A813 A814 A815 A816 A817 A818 A819 A820 A821 A822 A823 A824 A825 A826 A827 A828 A829 A830 A831 A832 - - - - - - - - Table 2: Compounds of the formula I, represented as compounds of the formula A-Q in which Q denotes Q f and Q^ denotes the radical B52: B52 B52 B52 B52 B52 B52 B52 B52 B52 B52 B52 B52 A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A71 A72 A73 A74 A75 A76 A77 A78 A79 A80 A81 A82 A83 A84 A85 A86 A87 A88 A89 A90 A91 A92 A93 A94 A95 A96 A97 A98 A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148 A149 A150 A151 A152 A153 A154 A155 A156 A157 A158 A159 A160 A161 A162 A163 A164 A165 A166 A167 A168 A169 A170 A171 A172 A173 A174 A175 A176 A177 A178 A179 A180 A181 A182 A183 A184 A185 A186 A187 A188 A189 A190 A191 A192 A193 A194 A195 A196 A197 A198 A199 A200 A201 A202 A203 A204 A205 A206 A207 A208 A209 A210 A211 A212 A213 A214 A215 A216 A217 A218 A219 A220 A221 A222 A223 A224 A225 A226 A227 A228 A229 A230 A231 A232 A233 A234 A235 A236 A237 A238 A239 A240 A241 A242 A243 A244 A245 A246 A247 A248 A249 A250 A251 A252 A253 A254 A255 A256 A257 A258 A259 A260 A261 A262 A263 A264 A265 A266 A267 A268 A269 A270 A271 A272 A273 A274 A275 A276 A277 A278 A279 A280 A281 A282 A283 A284 A285 A286 A287 A288 A289 A290 A291 A292 A293 A294 A295 A296 A297 A298 A299 A300 A301 A302 A303 A304 A305 A306 A307 A308 A309 A310 A311 A312 A313 A314 A315 A316 A317 A318 A319 A320 A321 A322 A323 A324 B52 B52 E352 B52 H£ B52 B52 B52 B52 B52 B52 B52 A325 A326 A327 A328 A329 A330 A331 A332 A333 A334 A335 A336 A337 A338 A339 A340 A341 A342 A343 A344 A345 A346 A347 A348 A349 A350 A351 A352 A353 A354 A355 A356 A357 A358 A359 A360 A361 A362 A363 A364 A365 A366 A367 A368 A369 A370 A371 A372 A373 A374 A375 A376 A377 A378 A379 A380 A381 A382 A383 A384 A385 A386 A387 A388 A389 A390 A391 A392 A393 A394 A395 A396 A397 A398 A399 A400 A401 A402 A403 A404 A405 A406 A407 A408 A409 A410 A411 A412 A413 A414 A415 A416 A417 A418 A419 A420 A421 A422 A423 A424 A425 A426 A427 A428 A429 A430 A431 A432 A433 A434 A435 A436 A437 A438 A439 A440 A441 A442 A443 A444 A445 A446 A447 A448 A449 A450 A451 A452 A453 A454 A455 A456 A457 A458 A459 A460 A461 A462 A463 A464 A465 A466 A467 A468 A469 A470 A471 A472 A473 A474 A475 A476 A477 A478 A479 A480 A481 A482 A483 A484 A485 A486 A487 A488 A489 A490 A491 A492 A493 A494 A495 A496 A497 A498 A499 A500 A501 A502 A503 A504 A505 A506 A507 A508 A509 A510 A511 A512 A513 A514 A515 A516 A517 A518 A519 A520 A521 A522 A523 A524 A525 A526 A527 A528 A529 A530 A531 A532 A533 A534 A535 A536 A537 A538 A539 A540 A541 A542 A543 A544 A545 A546 A547 A548 A549 A550 A551 A552 A553 A554 A555 A556 A557 A558 A559 A560 A561 A562 A563 A564 A565 A566 A567 A568 A569 A570 A571 A572 A573 A574 A575 A576 A577 A578 A579 A580 A581 A582 A583 A584 A585 A586 A587 A588 A589 A590 A591 A592 A593 A594 A595 A596 A597 A598 A599 A600 A601 A602 A603 A604 A605 A606 A607 A608 A609 A610 A611 A612 A613 A614 A615 A616 A617 A618 A619 A620 A621 A622 A623 A624 A625 A626 A627 A628 A629 A630 A631 A632 A633 A634 A635 A636 A637 A638 A639 A640 A641 A642 A643 A644 A645 A646 A647 A648 A649 A650 A651 A652 A653 A654 A655 A656 A657 A658 A659 A660 A661 A662 A663 A664 A665 A666 A667 A668 A669 A670 A671 A672 A673 A674 A675 A676 A677 A678 A679 A680 A681 A682 A683 A684 A685 A686 A687 A688 A689 A690 A691 A692 A693 A694 A695 A696 A697 A698 A699 A700 A701 A702 A703 A704 A705 A706 A707 A708 A709 A710 A711 A712 A713 A714 A715 A716 A717 A718 A719 A720 B52 B52 B52 B52 B52 B52 B52 |δ2 £352 BK B52 B52 ~ A721 A722 A723 A724 A725 A726 A727 A728 A729 A730 A731 A732 ~ A733 A734 A735 A736 A737 A738 A739 A740 A741 A742 A743 A744 A745 A746 A747 A748 A749 A750 A751 A752 A753 A754 A755 A756 A757 A758 A759 A760 A761 A762 A763 A764 A765 A766 A767 A768 A769 A770 A771 A772 A773 A774 A775 A776 A777 A778 A779 A780 A781 A782 A783 A784 A785 A786 A787 A788 A789 A790 A791 A792 A793 A794 A795 A796 A797 A798 A799 A800 A801 A802 A803 A804 A805 A806 A807 A808 A809 A810 A811 A812 A813 A814 A815 A816 A817 A818 A819 A820 A821 A822 A823 A824 A825 A826 A827 A828 A829 A830 A831 A832 - - - - - - - - Table 3: Compounds of the formula I, represented as compounds of the formula A-Q in which Q denotes Qi and Q-i denotes the radical B39: B39 B39 B39 B39 B39 B39 B39 B39 B39 B39 B39 B39 A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A71 A72 A73 A74 A75 A76 A77 A78 A79 A80 A81 A82 A83 A84 A85 A86 A87 A88 A89 A90 A91 A92 A93 A94 A95 A96 A97 A98 A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148 A149 A150 A151 A152 A153 A154 A155 A156 B39 B39 B39 B39 B39 B39 B39 B39 B39 B39 B39 B39 A157 A158 A159 A160 A161 A162 A163 A164 A165 A166 A167 A168 A169 A170 A171 A172 A173 A174 A175 A176 A177 A178 A179 A180 A181 A182 A183 A184 A185 A186 A187 A188 A189 A190 A191 A192 A193 A194 A195 A196 A197 A198 A199 A200 A201 A202 A203 A204 A205 A206 A207 A208 A209 A210 A211 A212 A213 A214 A215 A216 A217 A218 A219 A220 A221 A222 A223 A224 A225 A226 A227 A228 A229 A230 A231 A232 A233 A234 A235 A236 A237 A238 A239 A240 A241 A242 A243 A244 A245 A246 A247 A248 A249 A250 A251 A252 A253 A254 A255 A256 A257 A258 A259 A260 A261 A262 A263 A264 A265 A266 A267 A268 A269 A270 A271 A272 A273 A274 A275 A276 A277 A278 A279 A280 A281 A282 A283 A284 A285 A286 A287 A288 A289 A290 A291 A292 A293 A294 A295 A296 A297 A298 A299 A300 A301 A302 A303 A304 A305 A306 A307 A308 A309 A310 A311 A312 A313 A314 A315 A316 A317 A318 A319 A320 A321 A322 A323 A324 A325 A326 A327 A328 A329 A330 A331 A332 A333 A334 A335 A336 A337 A338 A339 A340 A341 A342 A343 A344 A345 A346 A347 A348 A349 A350 A351 A352 A353 A354 A355 A356 A357 A358 A359 A360 A361 A362 A363 A364 A365 A366 A367 A368 A369 A370 A371 A372 A373 A374 A375 A376 A377 A378 A379 A380 A381 A382 A383 A384 A385 A386 A387 A388 A389 A390 A391 A392 A393 A394 A395 A396 A397 A398 A399 A400 A401 A402 A403 A404 A405 A406 A407 A408 A409 A410 A411 A412 A413 A414 A415 A416 A417 A418 A419 A420 A421 A422 A423 A424 A425 A426 A427 A428 A429 A430 A431 A432 A433 A434 A435 A436 A437 A438 A439 A440 A441 A442 A443 A444 A445 A446 A447 A448 A449 A450 A451 A452 A453 A454 A455 A456 A457 A458 A459 A460 A461 A462 A463 A464 A465 A466 A467 A468 A469 A470 A471 A472 A473 A474 A475 A476 A477 A478 A479 A480 A481 A482 A483 A484 A485 A486 A487 A488 A489 A490 A491 A492 A493 A494 A495 A496 A497 A498 A499 A500 A501 A502 A503 A504 A505 A506 A507 A508 A509 A510 A511 A512 A513 A514 A515 A516 A517 A518 A519 A520 A521 A522 A523 A524 A525 A526 A527 A528 A529 A530 A531 A532 A533 A534 A535 A536 A537 A538 A539 A540 A541 A542 A543 A544 A545 A546 A547 A548 A549 A550 A551 A552 B39 B39 B39 B39 H B39 B39 U9 B39 B39 B39 B39 A553 A554 A555 A556 A557 A558 A559 A560 A561 A562 A563 A564 A565 A566 A567 A568 A569 A570 A571 A572 A573 A574 A575 A576 A577 A578 A579 A580 A581 A582 A583 A584 A585 A586 A587 A588 A589 A590 A591 A592 A593 A594 A595 A596 A597 A598 A599 A600 A601 A602 A603 A604 A605 A606 A607 A608 A609 A610 A611 A612 A613 A614 A615 A616 A617 A618 A619 A620 A621 A622 A623 A624 A625 A626 A627 A628 A629 A630 A631 A632 A633 A634 A635 A636 A637 A638 A639 A640 A641 A642 A643 A644 A645 A646 A647 A648 A649 A650 A651 A652 A653 A654 A655 A656 A657 A658 A659 A660 A661 A662 A663 A664 A665 A666 A667 A668 A669 A670 A671 A672 A673 A674 A675 A676 A677 A678 A679 A680 A681 A682 A683 A684 A685 A686 A687 A688 A689 A690 A691 A692 A693 A694 A695 A696 A697 A698 A699 A700 A701 A702 A703 A704 A705 A706 A707 A708 A709 A710 A711 A712 A713 A714 A715 A716 A717 A718 A719 A720 A721 A722 A723 A724 A725 A726 A727 A728 A729 A730 A731 A732 A733 A734 A735 A736 A737 A738 A739 A740 A741 A742 A743 A744 A745 A746 A747 A748 A749 A750 A751 A752 A753 A754 A755 A756 A757 A758 A759 A760 A761 A762 A763 A764 A765 A766 A767 A768 A769 A770 A771 A772 A773 A774 A775 A776 A777 A778 A779 A780 A781 A782 A783 A784 A785 A786 A787 A788 A789 A790 A791 A792 A793 A794 A795 A796 A797 A798 A799 A800 A801 A802 A803 A804 A805 A806 A807 A808 A809 A810 A81 1 A812 A813 A814 A815 A816 A817 A818 A819 A820 A821 A822 A823 A824 A825 A826 A827 A828 A829 A830 A831 A832 Table 4: Compounds of the formula I, represented as compounds of the formula A-Q in which Q denotes Q 1 and Q^ denotes the radical B3: B3 B3 B3 B3 B3 B3 B3 B3 B3 B3 B3 B3 ____ _ __ __ _ _ __ _ _ _ _ __ A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A71 A72 A73 A74 A75 A76 A77 A78 A79 A80 A81 A82 A83 A84 A85 A86 A87 A88 A89 A90 A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148 A149 A150 A151 A152 A153 A154 A155 A156 A157 A158 A159 A160 A161 A162 A163 A164 A165 A166 A167 A168 A169 A170 A171 A172 A173 A174 A175 A176 A177 A178 A179 A180 A181 A182 A183 A184 A185 A186 A187 A188 A189 A190 A191 A192 A193 A194 A195 A196 A197 A198 A199 A200 A201 A202 A203 A204 A205 A206 A207 A208 A209 A210 A211 A212 A213 A214 A215 A216 A217 A218 A219 A220 A221 A222 A223 A224 A225 A226 A227 A228 A229 A230 A231 A232 A233 A234 A235 A236 A237 A238 A239 A240 A241 A242 A243 A244 A245 A246 A247 A248 A249 A250 A251 A252 A253 A254 A255 A256 A257 A258 A259 A260 A261 A262 A263 A264 A265 A266 A267 A268 A269 A270 A271 A272 A273 A274 A275 A276 A277 A278 A279 A280 A281 A282 A283 A284 A285 A286 A287 A288 A289 A290 A291 A292 A293 A294 A295 A296 A297 A298 A299 A300 A301 A302 A303 A304 A305 A306 A307 A308 A309 A310 A311 A312 A313 A314 A315 A316 A317 A318 A319 A320 A321 A322 A323 A324 A325 A326 A327 A328 A329 A330 A331 A332 A333 A334 A335 A336 A337 A338 A339 A340 A341 A342 A343 A344 A345 A346 A347 A348 A349 A350 A351 A352 A353 A354 A355 A356 A357 A358 A359 A360 A361 A362 A363 A364 A365 A366 A367 A368 A369 A370 A371 A372 A373 A374 A375 A376 A377 A378 A379 A380 A381 A382 A383 A384 ___ _ _ __ __ _ __ _ __ __ _ gg A385 A386 A387 A388 A389 A390 A391 A392 A393 A394 A395 A396 A397 A398 A399 A400 A401 A402 A403 A404 A405 A406 A407 A408 A409 A410 A411 A412 A413 A414 A415 A416 A417 A418 A419 A420 A421 A422 A423 A424 A425 A426 A427 A428 A429 A430 A431 A432 A433 A434 A435 A436 A437 A438 A439 A440 A441 A442 A443 A444 A445 A446 A447 A448 A449 A450 A451 A452 A453 A454 A455 A456 A457 A458 A459 A460 A461 A462 A463 A464 A465 A466 A467 A468 A469 A470 A471 A472 A473 A474 A475 A476 A477 A478 A479 A480 A481 A482 A483 A484 A485 A486 A487 A488 A489 A490 A491 A492 A493 A494 A495 A496 A497 A498 A499 A500 A501 A502 A503 A504 A505 A506 A507 A508 A509 A510 A511 A512 A513 A514 A515 A516 A517 A518 A519 A520 A521 A522 A523 A524 A525 A526 A527 A528 A529 A530 A531 A532 A533 A534 A535 A536 A537 A538 A539 A540 A541 A542 A543 A544 A545 - - - - - - - A554 A555 A556 A557 A558 A559 A560 A561 A562 A563 A564 A565 A566 A567 A568 A569 A570 A571 A572 A573 A574 A575 A576 A577 A578 A579 A580 A581 A582 A583 A584 A585 A586 A587 A588 A589 A590 A591 A592 A593 A594 A595 A596 A597 A598 A599 A600 A601 A602 A603 A604 A605 A606 A607 A608 A609 A610 A611 A612 A613 A614 A615 A616 A617 A618 A619 A620 A621 A622 A623 A624 A625 A626 A627 A628 A629 A630 A631 A632 A633 A634 A635 A636 A644 A645 A646 A647 A648 A649 A650 A651 A652 A653 A654 A655 A656 A657 A658 A659 A660 A661 A662 A663 A664 A665 A666 A667 A668 A669 A670 A671 A672 A685 A686 A687 A688 A689 A690 A691 A692 A693 A694 A695 A696 A697 A698 A699 A700 A701 A702 A703 A704 A705 A706 A707 A708 A709 A710 A711 A712 A713 A714 A715 A716 A717 A718 A719 A720 A721 A722 A723 A724 A725 A726 A733 A734 A735 A736 A737 A738 A739 A740 A741 A742 A743 A744 A745 A746 A747 A748 A749 A750 A751 A752 A753 A754 A755 A756 A757 A758 A759 A760 A761 A762 A763 A764 A765 A766 A767 A768 A769 A770 A771 A772 A773 A774 A775 A776 A777 A778 A779 A780 A781 A782 A783 A784 A785 A786 A787 A788 A789 A790 A791 A792 B3 U B3 B3 U B3 U B3 U B3 B3 B3 A793 A794 A795 A796 A797 A798 A799 A800 A801 A802 A803 A804 A805 A806 A807 A808 A809 A810 A81 1 A812 A813 A814 A815 A816 A817 A818 A819 A820 A821 A822 A823 A824 A825 A826 A827 A828 A829 A830 A831 A832 - Table 5: Compounds of the formula I. represented as compounds of the formula A-Q in which Q denotes Q 2 and Q 2 denotes the radical C5: C5 C5 C5 C5 C5 C5 C5 C5 C5 C5 C5 C5 A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A71 A72 A73 A74 A75 A76 A77 A78 A79 A80 A81 A82 A83 A84 A85 A86 A87 A88 A89 A90 A91 A92 A93 A94 A95 A96 A97 A98 A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148 A149 A150 A151 A152 A153 A154 A155 A156 A157 A158 A159 A160 A161 A162 A163 A164 A165 A166 A167 A168 A169 A170 A171 A172 A173 A174 A175 A176 A177 A178 A179 A180 A181 A182 A183 A184 A185 A186 A187 A188 A189 A190 A191 A192 A193 A194 A195 A196 A197 A198 A199 A200 A201 A202 A203 A204 A205 A206 A207 A208 A209 A210 A211 A212 A213 A214 A215 A216 A217 A218 A219 A220 A221 A222 A223 A224 A225 A226 A227 A228 C5 C5 C5 C5 C5 C5 C5 C5 C5 C5 C5 C5 A229 A230 A231 A232 A233 A234 A235 A236 A237 A238 A239 A240 A241 A242 A243 A244 A245 A246 A247 A248 A249 A250 A251 A252 A253 A254 A255 A256 A257 A258 A259 A260 A261 A262 A263 A264 A265 A266 A267 A268 A269 A270 A271 A272 A273 A274 A275 A276 A277 A278 A279 A280 A281 A282 A283 A284 A285 A286 A287 A288 A289 A290 A291 A292 A293 A294 A295 A296 A297 A298 A299 A300 A301 A302 A303 A304 A305 A306 A307 A308 A309 A310 A311 A312 A313 A314 A315 A316 A317 A318 A319 A320 A321 A322 A323 A324 A325 A326 A327 A328 A329 A330 A331 A332 A333 A334 A335 A336 A337 A338 A339 A340 A341 A342 A343 A344 A345 A346 A347 A348 A349 A350 A351 A352 A353 A354 A355 A356 A357 A358 A359 A360 A361 A362 A363 A364 A365 A366 A367 A368 A369 A370 A371 A372 A373 A374 A375 A376 A377 A378 A379 A380 A381 A382 A383 A384 A385 A386 A387 A388 A389 A390 A391 A392 A393 A394 A395 A396 A397 A398 A399 A400 A401 A402 A403 A404 A405 A406 A407 A408 A409 A410 A411 A412 A413 A414 A415 A416 A417 A418 A419 A420 A421 A422 A423 A424 A425 A426 A427 A428 A429 A430 A431 A432 A433 A434 A435 A436 A437 A438 A439 A440 A441 A442 A443 A444 A445 A446 A447 A448 A449 A450 A451 A452 A453 A454 A455 A456 A457 A458 A459 A460 A461 A462 A463 A464 A465 A466 A467 A468 A469 A470 A471 A472 A473 A474 A475 A476 A477 A478 A479 A480 A481 A482 A483 A484 A485 A486 A487 A488 A489 A490 A491 A492 A493 A494 A495 A496 A497 A498 A499 A500 A501 A502 A503 A504 A505 A506 A507 A508 A509 A510 A511 A512 A513 A514 A515 A516 A517 A518 A519 A520 A521 A522 A523 A524 A525 A526 A527 A528 A529 A530 A531 A532 A533 A534 A535 A536 A537 A538 A539 A540 A541 A542 A543 A544 A545 A546 A547 A548 A549 A550 A551 A552 A553 A554 A555 A556 A557 A558 A559 A560 A561 A562 A563 A564 A565 A566 A567 A568 A569 A570 A571 A572 A573 A574 A575 A576 A577 A578 A579 A580 A581 A582 A583 A584 A585 A586 A587 A588 A589 A590 A591 A592 A593 A594 A595 A596 A597 A598 A599 A600 A601 A602 A603 A604 A605 A606 A607 A608 A609 A610 A611 A612 A613 A614 A615 A616 A617 A618 A619 A620 A621 A622 A623 A624 C5 C5 C5 C5 C5 C5 C5 C5 C5 C5 C5 C5 A625 A626 A627 A628 A629 A630 A631 A632 A633 A634 A635 A636 A637 A638 A639 A640 A641 A642 A643 A644 A645 A646 A647 A648 A649 A650 A651 A652 A653 A654 A655 A656 A657 A658 A659 A660 A661 A662 A663 A664 A665 A666 A667 A668 A669 A670 A671 A672 A673 A674 A675 A676 A677 A678 A679 A680 A681 A682 A683 A684 A685 A686 A687 A688 A689 A690 A691 A692 A693 A694 A695 A696 A697 A698 A699 A700 A701 A702 A703 A704 A705 A706 A707 A708 A709 A710 A71 1 A712 A713 A714 A715 A716 A717 A718 A719 A720 A721 A722 A723 A724 A725 A726 A727 A728 A729 A730 A731 A732 A733 A734 A735 A736 A737 A738 A739 A740 A741 A742 A743 A744 A745 A746 A747 A748 A749 A750 A751 A752 A753 A754 A755 A756 A757 A758 A759 A760 A761 A762 A763 A764 A765 A766 A767 A768 A769 A770 A771 A772 A773 A774 A775 A776 A777 A778 A779 A780 A781 A782 A783 A784 A785 A786 A787 A788 A789 A790 A791 A792 A793 A794 A795 A796 A797 A798 A799 A800 A801 A802 A803 A804 A805 A806 A807 A808 A809 A810 A811 A812 A813 A814 A815 A816 A817 A818 A819 A820 A821 A822 A823 A824 A825 A826 A827 A828 A829 A830 A831 A832 Table 6: Compounds of the formula I, represented as compounds of the formula A-Q in which Q denotes Q 2 and Q 2 denotes the radical C2: C2 C2 C2 C2 C2 C2 C2 C2 C2 C2 C2 C2 A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 _____ ___ _ _ __ _ _ _ _ _ __ __ A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A7Ϊ A72 A73 A74 A75 A76 A77 A78 A79 A80 A81 A82 A83 A84 A85 A86 A87 A88 A89 A90 A91 A92 A93 A94 A95 A96 A97 A98 A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148 A149 A150 A151 A152 A153 A154 A155 A156 A157 A158 A159 A160 A161 A162 A163 A164 A165 A166 A167 A168 A169 A170 A171 A172 A173 A174 A175 A176 A177 A178 A179 A180 A181 A182 A183 A184 A185 A186 A187 A188 A189 A190 A191 A192 A193 A194 A195 A196 A197 A198 A199 A200 A201 A202 A203 A204 A205 A206 A207 A208 A209 A210 A211 A212 A213 A214 A215 A216 A217 A218 A219 A220 A221 A222 A223 A224 A225 A226 A227 A228 A229 A230 A231 A232 A233 A234 A235 A236 A237 A238 A239 A240 A241 A242 A243 A244 A245 A246 A247 A248 A249 A250 A251 A252 A253 A254 A255 A256 A257 A258 A259 A260 A261 A262 A263 A264 A265 A266 A267 A268 A269 A270 A271 A272 A273 A274 A275 A276 A277 A278 A279 A280 A281 A282 A283 A284 A285 A286 A287 A288 A289 A290 A291 A292 A293 A294 A295 A296 A297 A298 A299 A300 A301 A302 A303 A304 A305 A306 A307 A308 A309 A310 A311 A312 A313 A314 A315 A316 A317 A318 A319 A320 A321 A322 A323 A324 A325 A326 A327 A328 A329 A330 A331 A332 A333 A334 A335 A336 A337 A338 A339 A340 A341 A342 A343 A344 A345 A346 A347 A348 A349 A350 A351 A352 A353 A354 A355 A356 A357 A358 A359 A360 A361 A362 A363 A364 A365 A366 A367 A368 A369 A370 A371 A372 A373 A374 A375 A376 A377 A378 A379 A380 A381 A382 A383 A384 A385 A386 A387 A388 A389 A390 A391 A392 A393 A394 A395 A396 A397 A398 A399 A400 A401 A402 A403 A404 A405 A406 A407 A408 A409 A410 A411 A412 A413 A414 A415 A416 A417 A418 A419 A420 A421 A422 A423 A424 A425 A426 A427 A428 A429 A430 A431 A432 A433 A434 A435 A436 A437 A438 A439 A440 A441 A442 A443 A444 A445 A446 A447 A448 A449 A450 A451 A452 A453 A454 A455 A456 C2 C2 C2 C2 C2 C2 C2 C2 C2 C2 C2 C2 A457 A458 A459 A460 A461 A462 A463 A464 A465 A466 A467 A468 A469 A470 A471 A472 A473 A474 A475 A476 A477 A478 A479 A480 A481 A482 A483 A484 A485 A486 A487 A488 A489 A490 A491 A492 A493 A494 A495 A496 A497 A498 A499 A500 A501 A502 A503 A504 A505 A506 A507 A508 A509 A510 A511 A512 A513 A514 A515 A516 A517 A518 A519 A520 A521 A522 A523 A524 A525 A526 A527 A528 A529 A530 A531 A532 A533 A534 A535 A536 A537 A538 A539 A540 A541 A542 A543 A544 A545 A546 A547 A548 A549 A550 A551 A552 A553 A554 A555 A556 A557 A558 A559 A560 A561 A562 A563 A564 A565 A566 A567 A568 A569 A570 A571 A572 A573 A574 A575 A576 A577 A578 A579 A580 A581 A582 A583 A584 A585 A586 A587 A588 A589 A590 A591 A592 A593 A594 A595 A596 A597 A598 A599 A600 A601 A602 A603 A604 A605 A606 A607 A608 A609 A610 A611 A612 A613 A614 A615 A616 A617 A618 A619 A620 A621 A622 A623 A624 A625 A626 A627 A628 A629 A630 A631 A632 A633 A634 A635 A636 A637 A638 A639 A640 A641 A642 A643 A644 A645 A646 A647 A648 A649 A650 A651 A652 A653 A654 A655 A656 A657 A658 A659 A660 A661 A662 A663 A664 A665 A666 A667 A668 A669 A670 A671 A672 A673 A674 A675 A676 A677 A678 A679 A680 A681 A682 A683 A684 A685 A686 A687 A688 A689 A690 A691 A692 A693 A694 A695 A696 A697 A698 A699 A700 A701 A702 A703 A704 A705 A706 A707 A708 A709 A710 A711 A712 A713 A714 A715 A716 A717 A718 A719 A720 A721 A722 A723 A724 A725 A726 A727 A728 A729 A730 A731 A732 A733 A734 A735 A736 A737 A738 A739 A740 A741 A742 A743 A744 A745 A746 A747 A748 A749 A750 A751 A752 A753 A754 A755 A756 A757 A758 A759 A760 A761 A762 A763 A764 A765 A766 A767 A768 A769 A770 A771 A772 A773 A774 A775 A776 A777 A778 A779 A780 A781 A782 A783 A784 A785 A786 A787 A788 A789 A790 A791 A792 A793 A794 A795 A796 A797 A798 A799 A800 A801 A802 A803 A804 A805 A806 A807 A808 A809 A810 A811 A812 A813 A814 A815 A816 A817 A818 A819 A820 A821 A822 A823 A824 A825 A826 A827 A828 A829 A830 A831 A832 - - - - - - - - Table 7: Compounds of the formula I, represented as compounds of the formula A-Q in which Q denotes Q 2 and Q 2 denotes the radicals D1 , D2 or D3: D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 . _ _ _ A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A71 A72 A73 A74 A75 A76 All A78 A79 A80 A81 A82 A83 A84 A85 A86 A87 A88 A89 A90 - - - - - - - - A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148 A149 A150 A151 A152 A153 A154 A155 A156 A157 A158 A159 A160 A161 A162 A163 A164 A165 A166 A167 A168 A169 A170 A171 A172 A173 A174 A175 A176 A177 A178 A179 A180 A181 A182 A183 A184 A185 A186 A187 A188 A189 A190 A191 A192 A193 A194 A195 A196 A197 A198 A199 A200 A201 A202 A203 A204 A205 A206 A207 A208 A209 A210 A211 A212 A213 A214 A215 A216 A217 A218 A219 A220 A221 A222 A223 A224 A225 A226 A227 A228 A229 A230 A231 A232 A233 A234 A235 A236 A237 A238 A239 A240 A241 A242 A243 A244 A245 A246 A247 A248 A249 A250 A251 A252 A253 A254 A255 A256 A257 A258 A259 A260 A261 A262 A263 A264 A265 A266 A267 A268 A269 A270 A271 A272 A273 A274 A275 A276 A277 A278 A279 A280 A281 A282 A283 A284 A285 A286 A287 A288 D1/D2/ D1/D2/ DVD2I D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D27 D1/D27 D1/D2/ D1/D2/ D1/D2/ D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 A289 A290 A291 A292 A293 A294 A295 A296 A297 A298 A299 A300 A301 A302 A303 A304 A305 A306 A307 A308 A309 A310 A311 A312 A313 A314 A315 A316 A317 A318 A319 A320 A321 A322 A323 A324 A325 A326 A327 A328 A329 A330 A331 A332 A333 A334 A335 A336 A337 A338 A339 A340 A341 A342 A343 A344 A345 A346 A347 A348 A349 A350 A351 A352 A353 A354 A355 A356 A357 A358 A359 A360 A361 A362 A363 A364 A365 A366 A367 A368 A369 A370 A371 A372 A373 A374 A375 A376 A377 A378 A379 A380 A381 A382 A383 A384 A385 A386 A387 A388 A389 A390 A391 A392 A393 A394 A395 A396 A397 A398 A399 A400 A401 A402 A403 A404 A405 A406 A407 A408 A409 A410 A411 A412 A413 A414 A415 A416 A417 A418 A419 A420 A421 A422 A423 A424 A425 A426 A427 A428 A429 A430 A431 A432 A433 A434 A435 A436 A437 A438 A439 A440 A441 A442 A443 A444 A445 A446 A447 A448 A449 A450 A451 A452 A453 A454 A455 A456 A457 A458 A459 A460 A461 A462 A463 A464 A465 A466 A467 A468 A469 A470 A471 A472 A473 A474 A475 A476 A477 A478 A479 A480 A481 A482 A483 A484 A485 A486 A487 A488 A489 A490 A491 A492 A493 A494 A495 A496 A497 A498 A499 A500 A501 A502 A503 A504 A505 A506 A507 A508 A509 A510 A511 A512 A513 A514 A515 A516 A517 A518 A519 A520 A521 A522 A523 A524 A525 A526 A527 A528 A529 A530 A531 A532 A533 A534 A535 A536 A537 A538 A539 A540 A541 A542 A543 A544 A545 - - - - - - - - A554 A555 A556 A557 A558 A559 A560 A561 A562 A563 A564 A565 A566 A567 A568 A569 A570 A571 A572 A573 A574 A575 A576 A577 A578 A579 A580 A581 A582 A583 A584 A585 A586 A587 A588 A589 A590 A591 A592 A593 A594 A595 A596 A597 A598 A599 A600 A601 A602 A603 A604 A605 A606 A607 A608 A609 A610 A611 A612 A613 A614 A615 A616 A617 A618 A619 A620 A621 A622 A623 A624 A625 A626 A627 A628 A629 A630 A631 A632 A633 A634 A635 A636 - - - - - - - A644 A645 A646 A647 A648 A649 A650 A651 A652 A653 A654 A655 A656 A657 A658 A659 A660 D1/D2/ D1/D2/ D1/D2 D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2/ D1/D2 D1/D2/ D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 A661 A662 A663 A664 A665 A666 A667 A668 A669 A670 A671 A672 A685 A686 A687 A688 A689 A690 A691 A692 A693 A694 A695 A696 A697 A698 A699 A700 A701 A702 A703 A704 A705 A706 A707 A708 A709 A710 A711 A712 A713 A714 A715 A716 A717 A718 A719 A720 A721 A722 A723 A724 A725 A726 - - - - - - A733 A734 A735 A736 A737 A738 A739 A740 A741 A742 A743 A744 A745 A746 A747 A748 A749 A750 A751 A752 A753 A754 A755 A756 A757 A758 A759 A760 A761 A762 A763 A764 A765 A766 A767 A768 A769 A770 A771 A772 A773 A774 A775 A776 A777 A778 A779 A780 A781 A782 A783 A784 A785 A786 A787 A788 A789 A790 A791 A792 A793 A794 A795 A796 A797 A798 A799 A800 A801 A802 A803 A804 A805 A806 A807 A808 A809 A810 A811 A812 A813 A814 A815 A816 A817 A818 A819 A820 A821 A822 A823 A824 A825 A826 A827 A828 A829 A830 A831 A832 ~ ~ " _ ~ ~ " Table 8: Compounds of the formula Ip: in which R 1 ? R 2 , R 3 , R 4l Xi and p have the same meaning as given for the radical A, and n is 0, 1 or 2: A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A71 A72 A73 A74 A75 A76 A77 A78 A79 A80 A81 A82 A83 A84 A85 A86 A87 A88 A89 A90 - A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148 A149 A150 A151 A152 A153 A154 A155 A156 A157 A158 A159 A160 A161 A162 A163 A164 A165 A166 A167 A168 A169 A170 A171 A172 A173 A174 A175 A176 A177 A178 A179 A180 A181 A182 A183 A184 A185 A186 A187 A188 A189 A190 A191 A192 A193 A194 A195 A196 A197 A198 A199 A200 A201 A202 A203 A204 A205 A206 A207 A208 A209 A210 A211 A212 A213 A214 A215 A216 A217 A218 A219 A220 A221 A222 A223 A224 A225 A226 A227 A228 A229 A230 A231 A232 A233 A234 A235 A236 A237 A238 A239 A240 A241 A242 A243 A244 A245 A246 A247 A248 A249 A250 A251 A252 A253 A254 A255 A256 A257 A258 A259 A260 A261 A262 A263 A264 A265 A266 A267 A268 A269 A270 A271 A272 A273 A274 A275 A276 A277 A278 A279 A280 A281 A282 A283 A284 A285 A286 A287 A288 A289 A290 A291 A292 A293 A294 A295 A296 A297 A298 A299 A300 A301 A302 A303 A304 A305 A306 A307 A308 A309 A310 A311 A312 A313 A314 A315 A316 A317 A318 A319 A320 A321 A322 A323 A324 A325 A326 A327 A328 A329 A330 A331 A332 A333 A334 A335 A336 A337 A338 A339 A340 A341 A342 A343 A344 A345 A346 A347 A348 A349 A350 A351 A352 A353 A354 A355 A356 A357 A358 A359 A360 A361 A362 A363 A364 A365 A366 A367 A368 A369 A370 A371 A372 A373 A374 A375 A376 A377 A378 A379 A380 A381 A382 A383 A384 A385 A386 A387 A388 A389 A390 A391 A392 A393 A394 A395 A396 A397 A398 A399 A400 A401 A402 A403 A404 A405 A406 A407 A408 A409 A410 A411 A412 A413 A414 A415 A416 A417 A418 A419 A420 A421 A422 A423 A424 A425 A426 A427 A428 A429 A430 A431 A432 A433 A434 A435 A436 A437 A438 A439 A440 A441 A442 A443 A444 A445 A446 A447 A448 A449 A450 A451 A452 A453 A454 A455 A456 A457 A458 A459 A460 A461 A462 A463 A464 A465 A466 A467 A468 A469 A470 A471 A472 A473 A474 A475 A476 A477 A478 A479 A480 A481 A482 A483 A484 A485 A486 A487 A488 A489 A490 A491 A492 A493 A494 A495 A496 A497 A498 A499 A500 A501 A502 A503 A504 A505 A506 A507 A508 A509 A510 A511 A512 A513 A514 A515 A516 A517 A518 A519 A520 A521 A522 A523 A524 A525 A526 A527 A528 A529 A530 A531 A532 A533 A534 A535 A536 A537 A538 A539 A540 A541 A542 A543 A544 A545 A554 A555 A556 A557 A558 A559 A560 A561 A562 A563 A564 A565 A566 A567 A568 A569 A570 A571 A572 A573 A574 A575 A576 A577 A578 A579 A580 A581 A582 A583 A584 A585 A586 A587 A588 A589 A590 A591 A592 A593 A594 A595 A596 A597 A598 A599 A600 A601 A602 A603 A604 A605 A606 A607 A608 A609 A610 A611 A612 A613 A614 A615 A616 A617 A618 A619 A620 A621 A622 A623 A624 A625 A626 A627 A628 A629 A630 A631 A632 A633 A634 A635 A636 A644 A645 A646 A647 A648 A649 A650 A651 A652 A653 A654 A655 A656 A657 A658 A659 A660 A661 A662 A663 A664 A665 A666 A667 A668 A669 A670 A671 A672 A685 A686 A687 A688 A689 A690 A691 A692 A693 A694 A695 A696 A697 A698 A699 A700 A701 A702 A703 A704 A705 A706 A707 A708 A709 A710 A711 A712 A713 A714 A715 A716 A717 A718 A719 A720 A721 A722 A723 A724 A725 A726 - - - - - - A733 A734 A735 A736 A737 A738 A739 A740 A741 A742 A743 A744 A745 A746 A747 A748 A749 A750 A751 A752 A753 A754 A755 A756 A757 A758 A759 A760 A761 A762 A763 A764 A765 A766 A767 A768 A769 A770 A771 A772 A773 A774 A775 A776 A777 A778 A779 A780 A781 A782 A783 A784 A785 A786 A787 A788 A789 A790 A791 A792 _ _ _ _ _ _ __ _ _ __ _ _ A793 A794 A795 A796 A797 A798 A799 A800 A801 A802 A803 A804 A805 A806 A807 A808 A809 A810 A811 A812 A813 A814 A815 A816 A817 A818 A819 A820 A821 A822 A823 A824 A825 A826 A827 A828 A829 A830 A831 A832 - - - - - - - - Table 9: Compounds of the formula I, represented as compounds of the formula A-Q in which A denotes A10: A10 A10 A10 A10 A10 A10 A10 A10 A10 A10 A10 A10 B1 B2 . B4 B5 B6 B7 B8 B9 B10 B11 B12 B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24 B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36 B37 B38 - B40 B41 B42 B43 B44 B45 B46 B47 B48 B49 B50 B51 - B53 B54 B55 B56 B57 B58 B59 B60 B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72 B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84 B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B96 B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108 B109 B110 - - - - - - - - - - Table 10: Compounds of the formula I, represented as <compounds of the formula A-Q in which A denotes A10: A10 A10 A10 A10 A10 A10 A10 A10 A10 A10 A10 A10 C1 - C3 C4 - C6 C7 C8 C9 C10 C11 C12 C13 C14 C15 C16 C17 C18 C19 C20 C21 C22 C23 C24 C25 C26 C27 - - - - - - - - - Table 11 : Compounds of the formula I, represented as compounds of the formula A-Q in which A denotes A10: A10 A10 A10 A10 A10 A10 A10 A10 A10 A10 A10 A10 D4 D5 D6 D7 D8 D9 D10 D11 D12 Table 12: Compounds of the formula I, represented as compounds of the formula A-Q in which A denotes A556: A556 A556 A556 A556 A556 A556 A556 A556 A556 A556 A556 A556 B1 B2 . B4 B5 B6 B7 B8 B9 B10 B11 B12 B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24 B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36 B37 B38 - B40 B41 B42 B43 B44 B45 B46 B47 B48 B49 B50 B51 - B53 B54 B55 B56 B57 B58 B59 B60 B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72 B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84 B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B96 B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108 A556 A556 A556 A556 A556 A556 A556 A556 A556 A556 A556 A556 ____________ _ _ _ . . . . . _ _ Table 13: Compounds of the formula I, represented as compounds of the formula A-Q in which A denotes A556: A556 A556 A556 A556 A556 A556 A556. A556 A556 A556 A556 A556 C1 - C3 C4 - C6 C7 C8 C9 C10 C11 C12 C13 C14 C15 C16 C17 C18 C19 C20 C21 C22 C23 C24 C25 C26 C27 - - - - - - - - - Table 14: Compounds of the formula I, represented as compounds of the formula A-Q in which A denotes A556: A556 A556 A556 A556 A556 A556 A556 A556 A556 A556 A556 A556 D4 D5 D6 D7 D8 D9 D10 D11 D12 Table 15: Compounds of the formula I, represented as compounds of the formula A-Q in which A denotes A646: A646 A646 A646 A646 A646 A646 A646 A646 A646 A646 A646 ______ B1 B2 _ B4 B5 B6 B7 B8 B9 B10 B11 B12 B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24 B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36 B37 B38 - B40 B41 B42 B43 B44 B45 B46 B47 B48 B49 B50 B51 - B53 B54 B55 B56 B57 B58 B59 B60 B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72 B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84 B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B96 B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108 B109 B110 - - - - - - - - - - Table 16: Compounds of theι formula I, represented as compounds of the formula A-Q in which A denotes A646: A646 A646 A646 A646 A646 A646 A646 A646 A646 A646 A646 A646 C1 - C3 C4 - C6 C7 C8 C9 C10 C11 C12 C13 C14 C15 C16 C17 C18 C19 C20 C21 C22 C23 C24 C25 C26 C27 - Table 17: Compounds of the formula I, represented as compounds of the formula A-Q in which A denotes A646: A646 A646 A646 A646 A646 A646 A646 A646 A646 A646 A646 A646 D4 D5 D6 D7 D8 D9 D10 D11 D12 Table 18: Physical data for the compounds of the formula I given in the tables above: (the melting points are given in °C.) Compound m.p. (range) Phys. state A1 -C2 138-140 crystalline A2-C2 138-140 crystalline A833-B52 (K + ) 145-150 crystalline A833-B52 (H4) - oil A830-B52 - amorphous/liquid A829-B52 - oil A829-B1 - oil A10-B52 (H3) 54-56 crystalline A10-B1 71 -73 crystalline A10-B3 - viscous A10-B14 - viscous A10-B39 99-100 crystalline A736-B52 100-102 crystalline A10-C2 (H6) - viscous A57-B52 (H5) 54-56 crystalline A18-B52 71-74 crystalline A8-B52 95-98 crystalline A19-B52 53-55 crystalline A1 -C5 32-34 crystalline A2-C5 32-33 crystalline A10-C5 - resin A11 -C5 38-39 crystalline A11-B52 - resin A834-B52 - crystalline A835-B52 - viscous A854-B52 - viscous A90-B52 - viscous Compound m.p. (range) Phys. state A33-B52 113-115 crystalline A556-B52 - crystalline A646-B52 - viscous A868-B52 106-107 crystalline A855-B52 - viscous A817-B52 - viscous A819-B52 - crystalline A856-B52 - solid A857-B52 - viscous A63-B52 - resin A20-B52 - solid A858-B52 - resin A836-B52 - crystalline A859-B52 - viscous A818-B52 - viscous A837-B52 - viscous A28-B52 - viscous A28-B52 (Et 3 NH + ) - crystalline A838-B52 - viscous A839-B52 - viscous A860-B52 - viscous A860-B1 13 - viscous A861-B52 90-93 crystalline A840-B52 - oil A841 -B52 41 -43 crystalline A842-B52 - viscous A843-B52 - viscous A866-B100 96-98 crystalline A844-B52 - viscous A866-B112 - viscous A867-B112 - viscous A856-B112 79-81 crystalline A20-C5 - viscous A10-C28 - resin A11-C28 - resin Compound m.p. (range) Phys. state A10-B52 (Et 3 NH + ) - viscous A862-B52 - viscous A24-B52 102-105 crystalline A845-B52 40-44 crystalline A837-B52 - viscous (Et 3 NH + ) A67-B52 68-69 crystalline A863-B52 80-80 crystalline A10-B17 40-42 crystalline A846-B52 - crystalline A847-B52 - viscous A848-B52 - crystalline A56-B52 - vitreous A26-B52 - vitreous A849-B52 - viscous A10-B4 - viscous A865-B52 - viscous A850-B52 63-64 crystalline A10-C29 - resin A10-B111 76-78 crystalline A3-C5 - resin A834-C5 - resin A851 -B52 - vitreous A852-B52 - viscous A10-B25 - amorphous/liquid A853-B52 - viscous A27-B52 - oil A864-C5 149-150 crystalline A864-B52 1 10-112 crystalline A834-B39 - oil A-852-OH - oil A-851-OH 102-103 crystalline A-835-OH - oil A-24-OH - solid A-858-OH - oil Compound m.p. (range) Phys. state A-859-OH - oil A-864-OH - solid A-851 -OH 73-74 crystalline A-848-OH 81 -82 crystalline A-27-OH - oil A-855-OH 102-104 crystalline A-90-OH 111-114 crystalline A-124-OH 117-1 19 crystalline A-834-OH - crystalline A-852-OH - oil A-851 -OH 102-103 crystalline A-835-OH - oil A10-OH 62-63 crystalline A830-OH 157-158 crystalline A831 -OH 188-189 crystalline A829-OH 131 -134 crystalline A832-OH 1 10-112 crystalline Table 19: Physical data for the compounds of the formula I given in the tables above: (the melting points given in °C): In the following formulas, end-standing valences denote methyl groups (in all cases except alkyne or alkene groups) or hydrogen (in the case of alkyne or alkene groups), for example and CH Comp. Corresponding Formula m.p. (range) No. Phys. state Comp. Corresponding Formula m.p. (range) No. Phys. state (m);3.57- 3.60(m); 3.71 (s); 4.84 (s); 7.74 (d); 7.82 (d) Comp. Corresponding Formula m.p. (range) No. Phys. state o^ 1.010 ° ° J° VISCOUS I r° OH O «-° 95-98 1.017 < F crystalline Comp. Corresponding Formula m.p. (range) No. Phys. state e e e e e Comp. Corresponding Formula m.p. (range) No. Phys. state Comp. Corresponding Formula m.p. (range) No. Phys. state Comp. Corresponding Formula m.p. (range) No. Phys. state resin solid resin crystalline 0 J 1.041 o^ OHO υ viscous Comp. Corresponding Formula m.p. (range) No. Phys. state viscous viscous viscous crystalline VISCOUS VISCOUS Comp. Corresponding Formula m.p. (range) No. Phys. state S S S Comp. Corresponding Formula m.p. (range) No. Phys. state S S S Comp. Corresponding Formula m.p. (range) No. Phys. state VISCOUS VISCOUS resin crystalline 1.064 s OH O VISCOUS Comp. Corresponding Formula m.p. (range) No. Phys. state e e e e Comp. Corresponding Formula m.p. (range) No. Phys. state Comp. Corresponding Formula m.p. (range) No. Phys. state Comp. Corresponding Formula m.p. (range) No. Phys. state s s s Comp. Corresponding Formula m.p. (range) No. Phys. state Biological examples Example B1 : Herbicidal action before emergence of the plants (pre-emergence action) Monocotyledonous and dicotyledonous test plants are sown in standard soil in pots. Immediately after sowing, the test substances are sprayed on at an optimum dosage (500 I of water/ha) as an aqueous suspension (prepared from a wettable powder (example F3, b) according to WO 97/34485) or emulsion (prepared from an emulsion concentrate (example F1 , c) according to WO 97/34485). The test plants are then grown under optimum conditions in a greenhouse. After a test period of 4 weeks, the test is evaluated using a 9-level scale of ratings (1 = complete damage, 9 = no effect). Ratings of 1 to 4 (in particular 1 to 3) mean good to very good herbicidal action. Table B1 : Pre-emergence action: ("NT" means "not tested"): Compound g/ha Panicum Digitaria Echino. Abutilon Amaranthus Chenop. A10-B1 250 2 2 2 1 A10-B52, (H3) 250 1 1 1 1 A830-B52 250 4 9 3 4 A1 -C2 250 6 3 3 3 A833-B52 (K+) 250 2 2 2 A833-B52, (H4) 250 1 1 1 A10-B1 250 2 2 2 1 A10-B3 250 1 1 1 A10-B14 250 3 6 3 1 A10-B39 250 1 1 1 A736-B52 250 4 2 1 A10-C2 (H6) 250 3 3 3 2 A57-B52 (H5) 250 1 1 1 A18-B52 250 1 1 2 NT A8-B52 250 1 1 1 NT A19-B52 250 1 1 2 NT A1-C5 250 2 2 1 2 A2-C5 250 2 2 1 A10-C5 250 2 3 1 1 A11-C5 250 2 1 1 A11-B52 250 1 1 2 A834-B52 250 1 1 2 A835-B52 250 2 1 1 A556-B52 250 1 1 2 A646-B52 250 1 1 2 A819-B52 250 7 9 7 2 A63-B52 250 2 3 1 5 3 NT A20-B52 250 1 1 3 3 NT A836-B52 250 2 1 5 2 3 A837-B52 250 2 2 1 2 NT A28-B52 250 2 2 2 3 NT A28-B52 (Et3NH+) 250 2 2 3 1 NT Compound g/ha Panicum Digitaria Echino. Abutilon Amaranthus Chenop. A838-B52 250 1 3 2 1 A839-B52 250 1 3 2 1 A840-B52 250 1 2 2 2 2 1 A841 -B52 250 1 2 1 1 A842-B52 250 1 6 2 2 2 1 A843-B52 250 1 2 2 1 A844-B52 250 1 2 2 1 A20-C5 250 1 2 2 1 A10-C28 250 1 3 2 1 A11-C28 250 ; I 2 1 2 A10-B52 (Et3NH+) 250 1 1 2 1 A24-B52 250 I 1 1 A845-B52 250 1 1 1 A837-B52 (Et3NH+) 250 1 1 2 1 A67-B52 250 I 2 2 3 2 1 A10-B17 250 I 1 4 2 1 A846-B52 250 1 1 2 A847-B52 250 1 3 2 4 1 4 A848-B52 250 1 1 7 A56-B52 250 I 2 3 A26-B52 250 I 1 1 A849-B52 250 I 2 2 2 A10-B4 250 i . 3 3 A850-B52 250 1 2 2 1 A10-C29 250 ; . 2 1 NT A10-B111 250 1 1 1 NT A3-C5 250 I 2 2 1 NT A834-C5 250 l 3 2 NT A851 -B52 250 1 1 1 A852-B52 250 1 4 1 2 A10-B25 250 1 2 1 1 A853-B52 250 1 2 1 2 A27-B52 250 2 3 4 1 3 The same results are obtained when the compounds of the formula I are formulated according to the other examples of WO 97/34485. Example B2: Post-emergence herbicidal action Monocotyledonous and dicotyledonous test plants are grown in standard soil in pots. At the 2- to 3-leaf stage of the test plants, the test substances are sprayed at optimum dosage (500 I of water/ha) as an aqueous suspension (prepared from a wettable powder (example F3, b) according to WO 97/34485) or emulsion (prepared from an emulsion concentrate (example F1 , c) according to WO 97/34485). The test plants are then grown further under optimum conditions in a greenhouse. After a test period of 2 to 3 weeks, the test is evaluated using a 9-level scale of rating (1 = complete damage, 9 = no effect). Ratings of 1 to 4 (in particular 1 to 3) mean good to very good herbicidal action. Table B2: Post-emergence action Compound g/ha Panicum Digitaria Echino. Abutilon Xanth. Ipopur. Amaranth Chenop. A10-B1 250 2 2 2 2 2 2 2 1 A10-B52, (H3) 250 1 1 2 1 2 2 2 1 A830-B52 250 4 9 3 5 4 5 4 4 A829-B52 250 2 6 4 3 6 4 2 2 A829-B1 250 7 9 7 7 4 6 2 2 A1 -C2 250 7 8 4 3 4 3 2 4 A833-B52 (K+) 250 3 3 4 3 2 3 3 3 A833-B52, (H4) 250 3 3 4 3 1 2 2 3 A10-B3 250 1 1 3 1 1 2 1 A10-B14 250 2 2 3 2 2 2 2 A10-B39 250 1 3 3 1 2 2 A736-B52 250 1 1 2 1 2 2 A10-C2 (H6) 250 2 4 3 2 1 3 A57-B52 (H5) 250 1 1 2 1 2 2 A18-B52 250 1 1 2 1 2 2 A8-B52 250 1 1 1 1 2 1 A19-B52 250 1 1 2 1 2 1 Compound g/ha Panicum Digitaria Echino. Abutilon Xanth. Ipopur. Amaranth Chenop. A1 -C5 250 4 2 2 2 4 2 2 1 A2-C5 250 1 2 2 2 2 2 1 1 A10-C5 250 2 2 2 2 2 2 1 1 A11-C5 250 1 2 2 2 2 2 2 1 A11-B52 250 1 1 2 2 2 2 1 1 A834-B52 250 1 1 2 2 2 2 1 1 A835-B52 250 1 1 2 2 3 2 2 1 A854-B52 250 1 2 2 2 2 2 1 1 A90-B52 250 2 2 3 2 3 4 3 1 A33-B52 250 2 2 2 2 3 2 2 1 A556-B52 250 1 2 2 1 2 2 2 1 A646-B52 250 1 2 2 2 2 2 2 1 A855-B52 250 2 2 2 2 2 2 2 1 A817-B52 250 1 2 2 2 2 2 2 1 A819-B52 250 2 3 2 2 2 2 2 1 A856-B52 250 2 2 2 2 2 1 2 1 A857-B52 250 2 2 2 2 2 2 2 1 A63-B52 250 1 2 2 2 2 2 2 2 A20-B52 250 1 2 2 2 2 2 2 1 A858-B52 250 2 2 2 2 2 2 1 2 A836-B52 250 2 2 2 2 3 3 2 1 A859-B52 250 1 2 2 2 2 2 2 1 A818-B52 250 2 2 3 2 2 2 2 1 A837-B52 250 1 2 2 2 2 2 1 1 A28-B52 250 1 2 2 2 3 4 1 1 A28-B52 (Et3NH+) 250 1 2 2 2 3 2 2 1 A838-B52 250 2 2 3 1 2 2 2 1 A839-B52 250 2 2 2 2 2 2 2 1 A860-B52 250 2 1 2 2 2 2 2 1 A861-B52 250 2 3 5 3 2 2 2 1 A840-B52 250 2 3 4 3 3 3 2 1 A841 -B52 250 2 4 4 3 3 3 1 1 A842-B52 250 3 3 5 3 3 3 2 1 A843-B52 250 2 3 3 3 3 6 3 1 Compound g/ha Panicum Digitaria Echino. Abutilon Xanth. Ipopur. Amaranth Chenop. A844-B52 250 2 3 4 3 3 3 3 1 A856-B112 250 3 3 5 2 3 3 3 1 A20-C5 250 2 3 4 3 3 3 2 1 A10-C28 250 4 4 4 3 3 3 2 1 A11 -C28 250 3 4 4 3 3 3 2 1 A10-B52 (Et3NH+) 250 2 2 2 2 2 2 2 1 A862-B52 250 2 2 3 3 2 5 2 1 A24-B52 250 2 2 2 2 2 2 2 1 A845-B52 250 2 2 2 2 2 2 2 1 A837-B52 (Et3NH+) 250 2 2 2 2 2 2 2 1 A67-B52 250 2 2 2 2 2 3 2 1 A863-B52 250 2 2 3 2 2 3 2 1 A10-B17 250 2 1 2 2 2 2 2 1 A846-B52 250 1 2 2 2 2 1 2 2 A847-B52 250 1 2 1 2 2 4 3 1 A848-B52 250 2 2 2 2 2 2 1 1 A56-B52 250 1 2 2 2 2 2 1 1 A26-B52 250 2 2 2 2 2 2 2 1 A849-B52 250 2 2 3 2 2 2 2 2 A10-B4 250 1 1 2 1 2 1 2 1 A850-B52 250 2 2 2 2 2 2 2 1 A10-C29 250 2 3 3 2 2 1 2 1 A10-B111 250 2 2 3 3 3 3 2 1 A3-C5 250 3 4 3 3 3 3 3 1 A851 -B52 250 3 3 4 3 3 3 2 1 A852-B52 250 3 4 4 3 3 3 3 1 A10-B25 250 3 4 4 3 3 3 2 1 A27-B52 250 1 2 2 3 2 4 2 5 A864-C5 250 1 2 2 2 2 2 1 1 A864-B52 250 2 2 2 2 2 2 2 1 The same results are obtained when the compounds of the formula I are formulated according to the other examples of WO 97/34485.

Claims: WHAT IS CLAIMED IS: 1. A compound of the formula I in which p is 0 or 1 ; R T is a C-|-C 6 alkylene, C 3 -C 6 alkenylene or C 3 -C 6 a!kynylene chain which may be mono- or polysubstituted by halogen or R 5 , where the unsaturated bonds of the chain are not attached directly to the substituent X-i; X ! is oxygen, -O(CO)-, -(CO)O-, -O(CO)O-, -N(R 6 )-O-, -O-NR 5 r, thio, sulfinyl, sulfonyl, -SO 2 NR 7 -, -NR 52 SO 2 - or -NR 8 -; R 2 is a C C 8 alkyl, C 3 -C 6 alkenyl or C 3 -C 6 alkynyl group which is mono- or polysubstituted by halogen, hydroxyl, amino, formyl, nitro, cyano, mercapto, carbamoyl, C-|-C 6 alkoxy, C C 6 alkoxycarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 hafoaIkynyl, C 3 -C 6 cycloalkyl, by halogen-substituted C 3 -C 6 cycloalkyl, or by C 3 -C 6 alkenyloxy, C 3 -C 6 alkynyloxy, d-C 6 haloalkoxy, C 3 -C 6 haloalkenyloxy, cyano-Cι-C 6 alkoxy, C Cealkoxy-C Cealkoxy, d-Cealkoxy-d-Cealkoxy-d-Cealkoxy, d-Cealkylthio-d-Cεalkoxy, C Cealkylsulfinyl-CrCβalkoxy, C C 6 alkylsulfonyl-Cι-C 6 alkoxy, d-C 6 alkoxycarbonyl- C C 6 alkoxy, CrC 6 alkoxycarbonyl, C C 6 alkylcarbonyl, CrC 6 alkylthio, CrC 6 alkylsulfinyl, C C 6 alkylsulfonyl, Cι-C 6 haloalkylthio, CrC 6 haloalkylsulfinyl, d-C 6 haloalkylsulfonyl, oxiranyl, which for its part may be substituted by Cι-C 6 alkyl, or by (3-oxetanyl)oxy, which for its part may be substituted by C C 6 alkyl, or by benzylthio, benzylsulfinyl, benzylsulfonyl, d-C 6 alkylamino, di(CrC 6 alkyl)amino, R 9 S(O) 2 O, R 10 N(Rn)SO 2 -, thiocyanato, phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl; where the phenyl- or benzyl-containing groups for their part may be substituted by one or more d-C 6 alkyl, d-C 6 haloalkyl, C-ι-C 6 alkoxy, d-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro groups, or R 2 is phenyl which may be mono- or polysubstituted by d-C 6 alkyl, d-Cβhaloalkyl, d-C 6 alkoxy, d-C 6 haloaIkoxy, halogen, cyano, hydroxyl or nitro; or R 2 is C 3 -C 6 cycloalkyl, d-C 6 alkoxyl- or d-C 6 alkyl-substituted C 3 -C 6 cycloalkyl, 3-oxetanyl or CrC 6 alkyl-substituted 3-oxetanyI; or, if Q is Q 2 or Q 3 , or is Qi in which R 14 and R 22 are a C 2 -C 3 alkylene chain, R 2 is additionally also a five- to ten-membered monocyclic or fused bicyclic ring system which may be aromatic, saturated or partially saturated and may contain 1 to 4 heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, where the ring system is attached directly or via a d-C 4 alkylene, C 2 -C 4 alkenyl-C C 4 alkylene, C 2 -C 4 alkynyl-C C 4 alkylene, -N(R 12 )-C C 4 alkylene, -SO-C C 4 alkylene or -SO 2 -C r C 4 alkylene group to the substituent X-i and where each ring system may not contain more than two oxygen atoms and not more than two sulfur atoms and the ring system for its part may be mono-, di- or trisubstituted by d-C 6 alkyl, d-C 6 haloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, d-Cealkoxy, hydroxyl, d-C 6 haloalkoxy, C 3 -C 6 alkenyloxy, C 3 -C 6 alkynyloxy, mercapto, d-C 6 alkylthio, d-C 6 haloalkylthio, C 3 -C 6 alkenylthio, C 3 -C 6 haloalkenylthio, C 3 -C 6 alkynylthio, C 2 -C 5 alkoxyalkylthio, C 3 -C 5 acetylalkylthio, C 3 -C 6 alkoxycarbonylalkylthio, C 2 -C 4 cyanoalkylthio, CrC 6 alkylsulfinyl, d-C 6 haloalkylsulfinyl, Cι-C 6 alkylsulfonyl, Cι-C 6 haloalkylsulfonyl, aminosulfonyl, d-C 2 alkylaminosulfonyl, di(Cι-C 2 alkyl)aminosulfonyl, di(CrC alkyl)amino, halogen, cyano, nitro, phenyl and benzylthio, where phenyl and benzylthio for their part may be substituted on the phenyl ring by d-C 3 alkyl, d-C 3 ha!oalkyl, d-C 3 alkoxy, d-C 3 haloalkoxy, halogen, cyano or nitro, and where the substituents on the nitrogen in the heterocyclic ring are different from halogen; or R 2 is hydrogen or unsubstituted d-C 8 alkyl if a) Ri is substituted by the group R 5 , or b) Q is the group Q 2 , or c) Q is the group Q 3 in which X^ is -O(CO)-, -(CO)O-, -N(R 6 )-O-, -O-NR 5 r, -SO 2 NR 7 -, -NR 52 SO 2 - or -NR 8 -; or d) Q is the group Q ή in which X is -N(R 6 )-O-, -O-NR 51 -, -SO 2 NR 7 -, -NR 52 SO 2 - or -NR 8 -, or e) Q is the group Qi in which R 14 and R 22 in Q^ are a C 2 -C 3 alkylene chain and X^ is -O(CO)- or -(CO)O-, R 3 is C C 3 haloalkyl; R 4 is hydrogen, halogen, C C 3 alkyl, C C 3 haloalkyl, d-C 3 alkoxy, d-dalkoxy-d-Csalkyl or d-C 3 alkoxy-CrC 3 alkoxy; R 5 is hydroxyl, d-C 6 alkoxy, C 3 -C 6 cycloaIkyloxy, d-C 6 alkoxy-Cι-C 6 alkoxy, C C 6 alkoxy- C C 6 alkoxy-d-C 6 alkoxy or d-C 2 alkylsulfony!oxy; Re, R7 > Re, Rg, R10, R11, R12, R51 and R 52 independently of one another are hydrogen, C C 6 alkyf, d-C 6 haloalkyI, CrC 6 alkoxycarbonyl, d-C 6 alkyIcarbonyl, Cι-C 6 alkoxy-d-C 6 alkyI, d-Cealkoxy-d-Cealkyl substituted by d-C 6 alkoxy, benzyl or phenyl, where phenyl and benzyl for their part may be mono- or polysubstituted by C C 6 alkyl, d-C 6 haloalkyl, C C 6 alkoxy, C C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; where R 6 and R 9 are not simultaneously hydrogen and hydrogen, C C 6 alkoxycarbonyf or d-C 6 alkylcarbonyl, respectively; in which A-, is C(R 14 R 15 ), NR 16 or oxygen; A 2 is C(R 17 R 18 ), C(O), -C=N-O-R 19 , oxygen, thio, sulfinyl, sulfonyl, -NR 20 or ethylene; with the provisos that A^ is different from oxygen if A 2 is oxygen, C(O), thio, sulfinyl, -C=N-O-R 19 , NR 20 or C(Rι 7 R 18 ), where R 17 and R 18 independently of one another are C r C 4 alkoxy, d-C alkylthio, C C alkylsulfinyl, Cι-C 4 alkylsulfonyl; and A-i is different from NRι 6 if A 2 is thio, sulfinyl or C(R 17 R 18 ), where R 17 and R 18 independently of one another are Cι-C 4 alkoxy, Cι-C 4 alkylthio, d-C 4 alkylsulfinyl, d-C alkylsulfonyl; R 14 and R 22 independently of one another are hydrogen, d-C 4 alkyl, C C 4 haloalkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, d-C 4 alkylthio, C C 4 alkylsulfinyl, d-C 4 alkylsulfonyl, d-C 4 alkylsulfonyloxy, C C 4 alkoxy, C C 4 alkoxycarbonyl or d-C 4 alkylcarbonyl; R 15 and R 21 independently of one another are hydrogen, C 1 -C alkyl, d-C 4 haloalkyl, C 3 -C 4 alkenyl or C 3 -C alkynyl; R 17 is hydrogen, d-C 4 alkyl, C C 4 haloalkyl, d-C alkoxy, d-C 4 alkylthio, C C 4 alkylsulfinyl or C C 4 alkylsulfonyl; R 18 is hydrogen, d-C 4 alkyl, d-C haloalkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, C C 4 alkoxy, C-,-C 4 alkylthio, C -C alkylsulfinyl, C C 4 alkylsulfonyl or C C 4 dialkoxyalkyl-C C alkyl; R 20 is d-C 4 alkyl, C 3 -C 6 cycloalkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, d-C 4 alkylcarbonyl, C C 4 alkyl- carbonyloxy, di(CrC 4 alkyl)aminocarbonyl or benzyl, where the phenyl group may be mono- or polysubstituted by d-C 6 alkyl, d-C 6 haloalkyl, d-C 6 alkoxy, d-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; R- I9 and R 6 independently of one another are hydrogen, Cι-C 4 alkyl, C 3 -C 6 cycIoalkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, benzyl or phenyl, where phenyl and benzyl for their part may be mono- or polysubstituted by d-C 6 alkyl, Cι-C 6 haloalkyl, d-C 6 alkoxy, d-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; or R 14 and R 22 together form a C 2 -C 3 alkylene chain; or R 14 and R 15 together and/or Rι 7 and Rι 8 together and/or R 21 and R 22 together form a . C 2 -C alkylene chain which may be interrupted by oxygen and/or carbonyl and/or sulfur, with the proviso that the oxygen and sulfur atoms are separated by at least one methylene group; or R 4 and R 18 together form a C 2 -C 4 alkylene chain; or R 22 and R-| 8 together form a C 2 -C 4 alkylene chain; or R 18 together with R 22 or R 14 forms a direct bond; or R 16 and R 18 together form a C 2 -C alkylene chain; R 13 is hydroxyl, O " M + , where M + is an alkali metal cation or ammonium cation, halogen, d~Cι 2 alkylsulfonyloxy, amino, Cι-C 4 alkylthio, C C 12 alkylsulfinyl, d-Cι 2 alkylsulfonyl, Cι-Cι 2 haloalkylthio, d-C 12 haloalkylsulfinyl, d-Cι 2 haloalkylsulfonyl, CrC δ alkoxy-CrCealkylthio, d-Cβalkoxy-d-Cealkylsulfinyl, d-Cealkoxy-d-Cealkylsulfonyl, C 3 -C 12 alkenylthio, C 3 -Cι 2 alkenylsulfinyl, C 3 -Cι 2 alkenylsulfonyl, C 3 -d 2 alkynylthio, C 3 -C 12 alkynylsulfinyl, C 3 -C 12 alkynylsulfonyl, CrC 4 alkoxycarbonyl-C C 4 alkylthio, Cι-C 4 alkoxycarbonyl-d-C 4 alkylsulfinyl, d-C 4 alkoxycarbonyl-d-C 4 alkylsulfonyl, (C C 4 alkoxy) 2 P(O)0, d-C 4 alkyl-(C C 4 alkoxy)P(O)O, H(C 1 -C 4 alkoxy)P(O)O > R 23 R 24 NR 25 R 26 N, NH, R 27 R 28 NC(O)O-, R 29 R 30 NC(O)NH-, d-C 18 alkylcarbonyloxy, C 2 -C 18 alkenylcarbonyloxy, C 2 -C 18 alkynylcarbonyloxy, C 3 -C 6 cycloaikylcarbonyloxy, C C 12 alkoxycarbonyloxy, d-Cι 2 alkylthiocarbonyloxy, d-dgalkylthiocarbamoyl, where the alkyl, alkenyl and alkynyl groups may be substituted by halogen, d-C 6 alkoxy, d-C 6 alkylthio, d-C 6 alkylsulfinyl, C-|-C 6 alkylsulfonyl or cyano; or R 13 is phenoxy, phenylthio, phenylsulfinyl, phenylsulfonyl, phenylsulfonylamino, phenylsulfonyloxy or benzoyloxy, where the phenyl groups for their part may be substituted by one or more halogen, nitro, cyano, C C 4 alkyl, d-C 4 haloa!kyl, Cι-C 4 alkoxy or C C 4 halo- alkoxy groups; or R 13 is a group Het thio, Het 2 -sulfinyl, Het 3 -sulfonyl, Het 4 -(CO)O or Het 5 -N(R 33 ); in which Het-i, Het 2 , Het 3 , Het 4 and Het 5 independently of one another are a five- to ten-membered monocyclic or fused bicyclic ring system which may be aromatic or partially saturated and may contain 1 to 4 heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, and where each ring system may not contain more than 2 oxygen atoms and not more than 2 sulfur atoms, and where the ring system itself can be substituted by d-C 6 alkyl, C C 6 haloalkyl, C C 6 alkoxy, d-C 6 haloalkoxy, d-C 6 alkylthio, C C 6 alkylsulfinyl, C C 6 alkyl- sulfonyl, di(C C alkyl)aminosulfonyl, di(d-C 4 alkyl)annino, halogen, cyano, nitro or phenyl, and where the substituents on the nitrogen in the heterocyclic ring are different from halogen; R 23 , R 24 , R 2 5, R 2 6, R 27> R28, R29, R 3 o and R 33 independently of one another are hydrogen or CrCealkyl; or R 23 and R 24 together or R 25 and R 26 together or R 27 and R 28 together or R 29 and R 30 together are pyrolidino, piperidino, morpholino, thiomorpholino, which may be mono- or polysubstituted by methyl groups; or Q is Q 2 in which R 34 is hydrogen, d-C 4 alkyl, C 1 -C 4 haloalkyl, C 3 -C 6 cycloalkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkynyl or benzyl, where the phenyl group may be mono- or polysubstituted by d-C 6 alkyl, C C 6 halo- alkyl, d-C 6 alkoxy, CrC 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; R 35 is hydrogen, C C alkyl, d-C 4 haloalkyl, C 3 -C 6 cycloalkyl, C 3 -C alkenyl, C 3 -C 4 alkynyl or benzyl, where the phenyl group may be mono- or polysubstituted by d-C 6 alkyl, C C 6 halo- alkyl, d-C 6 alkoxy, C C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; R 36 is hydroxyl, O " M + , where M + is an alkali metal cation or ammonium cation, halogen, d-Cι 2 alkylsuIfonyloxy, amino, d-C 4 alkylthio, C C 12 alkylsulfinyl, d-C 12 alkylsulfonyl, d-Cι 2 haloalkylthio, d-d 2 haloalkylsulfinyl, d-C 12 haloalkylsulfonyl, d-Cealkoxy-d-Cealkylthio, d-Cealkoxy-d-Cealkylsulfinyl, d-C 6 alkoxy-d-C 6 alkylsulfonyl, C 3 -Cι 2 alkenylthio, C 3 -C 12 alkenylsulfinyl, C 3 -C l2 alkenylsulfonyl, C 3 -C-| 2 alkynylthio, C 3 -C 12 alkynylsulfinyl, C 3 -C 12 alkynylsulfonyl, d-dalkoxycarbonyl-d-dalkylthio, d-C 4 alkoxycarbonyl-C C 4 alkylsulfinyl, d-C 4 alkoxycarbonyl-C C alkylsulfonyl, (d-C 4 alkoxy) 2 P(O)O, C 1 -C 4 aikyl-(C 1 -C 4 alkoxy)P(O)0 J H(C C 4 alkoxy)P(O)O, R 37 R 38 , R 39 R 40 NNH, R 41 R 42 NC(O)O-, R 43 R 4 NC(0)NH-, C C 18 alkylcarbonyloxy, C 2 -C 18 alkenylcarbonyloxy, C 2 -C 18 alkynylcarbonyloxy, C 3 -C 6 cycloalkylcarbonyloxy, d-C 12 alkoxycarbonyloxy, d-Cι 2 alkylthiocarbonyloxy or d-Cι 2 alkylthiocarbamoyl, where the alkyl, alkenyl and alkynyl groups may be substituted by halogen, d-C 6 alkoxy, d-C 6 alkylthio, d-C 6 alkylsulfinyl, d-C 6 alkylsulfonyl or cyano; or R 36 is phenoxy, phenylthio, phenylsulfinyl, phenylsulfonyl, phenylsulfonylamino, phenylsuifonyloxy or benzoyloxy, where the phenyl groups for their part may be mono- or polysubstituted by halogen, nitro, cyano, d-C 4 alkyl, C -C 4 haloalkyl, C C 4 alkoxy, d-C 4 halo- alkoxy, or R 36 is a group Het 7 -thio, Het 8 -sulfinyl, Het 9 -sulfonyl, Het 10 -(CO)O or Het ι N(R 47 ); in which Het 7 , Het 8 , Het 9 , Het 10 and Het^ independently of one another are a five- to ten-membered monocyclic or fused bicyclic ring system which may be aromatic or partially saturated and may contain 1 to 4 heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, and where each ring system may not contain more than 2 oxygen atoms and not more than 2 sulfur atoms, and where the ring system for its part may be substituted by d-C 6 alkyl, d-C 6 haloalkyl, d-C 6 alkoxy, d-C 6 haloalkoxy, d-C 6 alkylthio, d-C 6 alkylsulfinyl, d-C 6 alkylsulfonyl, di(C C 4 alkyl)aminosulfonyl, di(d-C 4 alkyl)amino, halogen, cyano, nitro or phenyl, and where the substituents on the nitrogen in the heterocyclic ring are different from halogen; R37, 38, R39. R 4 o, R 4 ι, R 2, R 43 , R t and R 47 independently of one another are hydrogen or d-C 6 alkyl; or R 37 and R 38 together or R 39 and R 0 together or R 1 and R 42 together or R 43 and Rψ* together are pyrolidino, piperidino, morpholino, thiomorpholino, which may be mono- or polysubstituted by methyl groups; or Q is Q 3 in which R 49 is d-C 4 alkyl, Cι-C 4 haloalkyl, C 3 -C 6 cycloalkyl or halogen-substituted C 3 -C 6 cycloalkyl; R 50 is d-C 3 alkylene which may be substituted by halogen, hydroxyl, d-C 6 alkoxy, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, d-Cealkoxy-d-dalkoxy, C Cealkoxy-CrCealkoxy-C Cealkoxy, (3-oxetanyl)oxy, or by C C 6 alkyl-substituted (3- oxetanyl)oxy, or by benzylthio, benzylsulfinyl, benzylsulfonyl, phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl, where the phenyl- and benzyl-containing groups for their part may be substituted by one or more d-C 6 alkyl, d-C 6 haloalkyl, d-C 6 alkoxy, d-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro groups; or R 50 is phenyl, where the phenyl-containing group for its part may be substituted by one or more d-C 6 alkyl, d-C 6 haloalkyl, CrC 6 alkoxy, C C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro, or R 50 is C 3 -C 6 cycloalkyl, C C 6 alkoxy- or C C 6 alkyl-substituted C 3 -C 6 cycloalkyl, 3-oxetanyl or d-C 6 alkyl-substituted 3-oxetanyl; and n is 0, 1 or 2; and agronomically acceptable salts/N-oxides/isomers/enantiomers of this compound. 2. A process for preparing compounds of the formula I as claimed in claim 1 , which comprises, to prepare compounds of the formula I, in which Ri, R 2 , R 3 , R 4 and X are as defined under formula I and Q is a group Q t , either a) reacting a compound of the formula la in which R^ R 2 , R 3 , R 4 and X^ are as defined under formula I and Y, is a leaving group, in an inert organic solvent in the presence of a base with a compound of the formula II (ll), in which R 22 , R 2 -ι, A 2 and A-i are as defined under formula I, to give the compounds of the formulae Ilia and lllb lib and then isomerizing these in the presence of a base and a catalytic amount of dimethylaminopyridine (DMAP) or a source of cyanide, for example acetone cyanohydrin; or b) reacting a compound of the formula lb in which Ri, R 2 , R 3 , R 4 and Xi are as defined under formula I, with a compound of the formula II in which R 22 , R 21 , A-i and A 2 are as defined under formula I, in an inert organic solvent in the presence of a base and a coupling agent to give the compound of the formula Ilia or lllb, and then isomerizing these as described under route a); or, to prepare the compounds of the formula I, in which Q is a group Q 2 , either a) reacting a compound of the formula la in which R-i, R 2) R 3 , R and Xi are as defined under formula I and Yi is a leaving group, with a compound of the formula lla in which R 34 and R 35 are as defined under formula I, in an inert organic solvent in the presence of a base to give the compound of the formula lllc lllc in which R-i, R 2 , R 3 , R 4 , R 34 , R 35 and Xi are as defined under formula I, and then isomerizing this compound in the presence of a base and a catalytic amount of a source of cyanide; or b) reacting a compound of the formula lb in which Ri, R 2 , R 3 , R 4 and Xi are as defined under formula I, with a compound of the formula lla in which R 34 and R 35 are as defined above, in an inert organic solvent in the presence of a base and a coupling agent to give the compound of the formula lllc and then isomerizing this compound as described under route a); or, to prepare compounds of the formula I, in which Q is a group in which n is 0 and R 50 and R 9 are as defined above, either a) converting a compound of the formula IV in which Xi, Ri, R 2 , R 3 , R 4 and R 9 are as defined above, in the presence of a base, carbon disulfide and an alkylating agent of the formula V in which R 5 o is as defined under formula I, and Y 2 is a leaving group, into the compound of the formula VI in which Ri, R 2 , R 3 , R 4 , R 50 , Xi and R 49 are as defined under formula I, and then cyclizing this compound with hydroxylamine hydrochloride in the presence of a base to give the isomeric compounds of the formulae Ic and Id and then oxidizing these compounds with an oxidizing agent, for example with peracids, to give the corresponding sulfoxides (n = 1) and sulfones (n = 2) of the formulae Ie and If, respectively. 3. A herbicidal and plant-growth-inhibiting composition, which contains a herbicidally effective amount of a compound of the formula I on an inert carrier. 4. A method for controlling undesirable plant growth, wherein a herbicidally effective amount of an active compound of the formula I or a composition which contains this active compound is applied to the plants or their habitat. 5. A method for inhibiting plant growth, wherein a herbicidally effective amount of an active compound of the formula I or a composition which contains this active compound is applied to the plants or their habitat. 6. A compound of the formula XX in which Q is hydroxyl, halogen, cyano or Cι-C 6 alkoxy, or is a group of the formula i, R3, R 4 , R 9, R50, Xi and p are as defined under formula I and R 2 is a CrC 8 alkyl, C 3 -C 6 alkenyl or C 3 -C 6 alkynyl group which is mono- or polysubstituted by halogen, hydroxyl, amino, formyl, nitro, cyano, mercapto, carbamoyl, d-C 6 alkoxy, CrC 6 alkoxycarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, C 3 -C 6 cycloalkyl, by halogen- substituted C 3 -C 6 cycloaIkyl, or by C 3 -C 6 alkenyloxy, C 3 -C 6 alkynyloxy, CrC 6 haloalkoxy, C 3 -C 6 haloalkenyloxy, cyano-CrC 6 alkoxy, CrC 6 alkoxy-CrC 6 alkoxy, d-C 6 alkoxy- C -C 6 alkoxy-d -C 6 alkoxy, C 1 -C 6 alkylthio-Cι -C 6 alkoxy, d -C 6 alkylsulf inyl-d -C 6 alkoxy, CrC 6 alkylsulfonyl-CrC 6 alkoxy, CrC 6 alkoxycarbonyl-CrC 6 alkoxy, CrC 6 alkoxycarbonyl, CrC 6 alkylcarbonyl, CrC 6 alkylthio, d-C 6 alkylsulfinyl, d-C 6 alkylsulfonyl, C C 6 haloalkylthio, CrC 6 haloalkylsulfinyl, CrC 6 -haloalkylsuifonyl, oxiranyl, which for its part may be substituted by CrC 6 alkyl, or by (3-oxetanyl)oxy, which for its part may be substituted by d-C 6 alkyl, or by benzylthio, benzylsulfinyl, benzylsulfonyl, d-Cβalkylamino, di(CrC 6 alkyl)amino, R 9 S(O) 2 O, Rι 0 N(Rιι)SO 2 -, thiocyanato, phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl; where the phenyl- or benzyl-containing groups for their part may be substituted by one or more d-C 6 alkyl, C C 6 haloalkyl, d-C 6 alkoxy, C C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro groups, or R 2 is phenyl which may be mono- or polysubstituted by CrC 6 alkyl, d-C 6 haloalkyl, d-C 6 alkoxy, d-C 6 haloalkoxy, halogen, cyano, hydroxyl or nitro; or R 2 is C 3 -C 6 cycloalkyl, CrC 6 alkoxy- or d-C 6 alkyl-substituted C 3 -C 6 cycloalkyl, 3-oxetanyl or CrC 6 alkyl-substituted 3-oxetanyl; or if Xi is -N(R 6 )-O-, -O-NR 51 , SO 2 NR 7 - or -NR 52 SO 2 - and R 6 , R 7 , R 5 ι and R 52 are as defined under formula I, R 2 may additionally be hydrogen, unsubstituted d-C 6 alkyl, or a five- to ten-membered monocyclic or fused bicyclic ring system which may be aromatic, saturated or partially saturated and may contain 1 to 4 heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur, where the ring system is attached directly or via a CrC 4 alkylene, C 2 -C alkenyl-d-C 4 alkylene, C 2 -C 4 alkynyl-CrC 4 alkylene, -N(Rι 2 )-CrC 4 alkylene, -SO-d-C alkylene or -S0 2 -CrC 4 alkylene group to the substituent Xi, and where each ring system may not contain more than 2 oxygen atoms and not more than two sulfur atoms, and where the ring system for its part may be mono-, di- or trisubstituted by C C 6 alkyl, CrC 6 haloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, d-C 6 alkoxy, hydroxyl, CrC 6 haloalkoxy, C 3 -C 6 alkenyloxy, C 3 -C 6 alkynyloxy, mercapto, d-C 6 alkylthio, C C 6 -haloalkylthio, C 3 -C 6 alkenylthio, C 3 -C 6 haloalkenylthio, C 3 -C 6 alkynylthio, C 2 -C 5 alkoxyalkylthio, C 3 -C 5 acetylalkylthio, C 3 -C 6 alkoxycarbonylalkylthio, C 2 -C 4 cyanoalkylthio, CrC 6 alkylsulfinyl, CrC 6 haloalkylsulfinyl, CrC 6 alkylsulfonyl, Ci-Cehaloalkylsulfonyl, aminosulfonyl, d-dalkylaminosulfonyl, di(C C 2 alkyl)aminosulfonyl, di(CrC 4 alkyl)amino, halogen, cyano, nitro, phenyl and benzylthio, where phenyl and benzylthio for their part may be substituted on the phenyl ring by CrC 3 alkyl, d-C 3 haloalkyl, d-C 3 alkoxy, d-C 3 haloalkoxy, halogen, cyano or nitro, and where the substituents on the nitrogen in the heterocyclic ring are different from halogen.

Inventors: DE MESMAEKER ALAIN, EDMUNDS ANDREW, LUETHY CHRISTOPH, SCHAETZER JUERGEN, DE MESMAEKER, ALAIN, EDMUNDS, ANDREW, LUETHY, CHRISTOPH, SCHAETZER, JUERGEN
Applicants: EDMUNDS ANDREW, LUETHY CHRISTOPH, MESMAEKER ALAIN DE, SCHAETZER JUERGEN, SYNGENTA PARTICIPATIONS AG, DE MESMAEKER, ALAIN, EDMUNDS, ANDREW, LUETHY, CHRISTOPH, SCHAETZER, JUERGEN
Application year: 2001
Main classification: C07D401
IPC codes: A01N43, C07B61, C07D213, C07D401, C07D405, C07D409, C07D413, C07D417