FLUID PERMEABLE FLEXIBLE GRAPHITE ARTICLE WITH ENHANCED ELECTRICAL AND THERMAL CONDUCTIVITY

Abstract: Fluid permeable graphite article in the form of a perforated flexible graphite sheet having increased electrical and thermal conductivity transverse to the surfaces of the sheet.

Description: FLUID PERMEABLE FLEXIBLE GRAPHITE ARTICLE WITH ENHANCED ELECTRICAL AND THERMAL CONDUCTIVITY Field of the Invention This invention relates to an article formed of flexible graphite sheet which is fluid permeable in the transverse direction and has enhanced isotropy with respect to thermal and electrical conductivity. Background of the Invention Graphites are made up of layer planes of hexagonal arrays or networks of carbon atoms. These layer planes of hexagonally arranged carbon atoms are substantially flat and are oriented or ordered so as to be substantially parallel and equidistant to one another. The substantially flat, parallel equidistant sheets or layers of carbon atoms, usually referred to as basal planes, are linked or bonded together and groups thereof are arranged in crystallites. Highly ordered graphites consist of crystallites of considerable size: the crystallites being highly aligned or oriented with respect to each other and having well ordered carbon layers. In other words, highly ordered graphites have a high degree of preferred crystallite orientation. It should be noted that graphites possess anisotropic structures and thus exhibit or possess many properties which are highly directional e.g. thermal and electrical conductivity and fluid diffusion. Briefly, graphites may be characterized as laminated structures of carbon, that is, structures consisting of superposed layers or laminae of carbon atoms joined together by weak van der Waals forces. In considering the graphite structure, two axes or directions are usually noted, to wit, the "c" axis or direction and the "a" axes or directions. For simplicity, the "c" axis or direction may be considered as the direction perpendicular to the carbon layers. The "a" axes or directions may be considered as the directions parallel to the carbon layers or the directions perpendicular to the "c" direction. The natural graphites suitable for manufacturing flexible graphite possess a very high degree of orientation. As noted above, the bonding forces holding the parallel layers of carbon atoms together are only weak van der Waals forces. Natural graphites can be treated so that the spacing between the superposed carbon layers or laminae can be appreciably opened up so as to provide a marked expansion in the direction perpendicular to the layers, that is, in the "c" direction and thus form an expanded or intumesced graphite structure in which the laminar character of the carbon layers is substantially retained. Natural graphite flake which has been greatly expanded and more particularly expanded so as to have a final thickness or "c" direction dimension which is at least 80 or more times the original "c" direction dimension can be formed without the use of a binder into cohesive or integrated flexible graphite sheets of expanded graphite, e.g. webs, papers, strips, tapes, or the like. The formation of graphite particles which have been expanded to have a final thickness or "c" dimension which is at least 80 times the original "c" direction dimension into integrated flexible sheets by compression, without the use of any binding material is believed to be possible due to the excellent mechanical interlocking, or cohesion which is achieved between the voluminously expanded graphite particles. In addition to flexibility, the sheet material, as noted above, has also been found to possess a high degree of anisotropy with respect to thermal and electrical conductivity and fluid diffusion, comparable to the natural graphite starting material due to orientation of the expanded graphite particles substantially parallel to the opposed faces of the sheet resulting from very high compression, e.g. roll pressing. Sheet material thus produced has excellent flexibility, good strength and a very high degree of orientation. Briefly, the process of producing flexible, binderless anisotropic graphite sheet mateπal, e g web, paper, strip, tape, foil, mat, or the like, comprises compressing or compacting under a predetermined load and in the absence of a binder, expanded graphite particles which have a "c" direction dimension which is at least 80 times that of the original particles so as to form a substantially flat, flexible, integrated graphite sheet The expanded graphite particles which generally are worm-like or vermiform in appearance, once compressed, will maintain the compression set and alignment with the opposed major surfaces of the sheet The density and thickness of the sheet matenal can be varied by controlling the degree of compression The density of the sheet material can be withm the range of from about 5 pounds per cubic foot to about 125 pounds per cubic foot The flexible graphite sheet mateπal exhibits an appreciable degree of anisotropy due to the alignment of graphite particles parallel to the major opposed, parallel surfaces of the sheet, with the degree of anisotropy increasing upon roll pressing of the sheet mateπal to increased density In roll pressed anisotropic sheet mateπal, the thickness, I e the direction perpendicular to the opposed, parallel sheet surfaces compπses the "c" direction and the directions ranging along the length and width, I e along or parallel to the opposed, major surfaces compπses the "a" directions and the thermal, electπcal and fluid diffusion properties of the sheet are very different, by orders of magnitude, for the "c" and "a" directions This very considerable difference m properties, l e anisotropy, which is directionally dependent, can be disadvantageous in some applications For example, m gasket applications where flexible graphite sheet is used as the gasket mateπal and in use is held tightly between metal surfaces, the diffusion of fluid, e g gases or liquids, occurs more readily parallel to and between the major surfaces of the flexible graphite sheet It would, in most instances, provide for improved gasket performance, if the resistance to fluid flow parallel to the major surfaces of the graphite sheet ("a" direction) were increased, even at the expense of reduced resistance to fluid diffusion flow transverse to the major faces of the graphite sheet ("c" direction). With respect to electrical properties, the resistivity of anisotropic flexible graphite sheet is high in the direction transverse to the major surfaces ("c" direction) of the flexible graphite sheet, and very substantially less in the direction parallel to and between the major faces of the flexible graphite sheet ("a" direction). In applications such as fluid flow field plates for fuel cells and seals for fuel cells, it would be of advantage if the electrical resistance transverse to the major surfaces of the flexible graphite sheet ("c" direction) were decreased, even at the expense of an increase in electrical resistivity in the direction parallel to the major faces of the flexible graphite sheet ("a" direction). With respect to thermal properties, the thermal conductivity of a flexible graphite sheet in a direction parallel to the upper and lower surfaces of the flexible graphite sheet is relatively high, while it is relatively very low in the "c" direction transverse to the upper and lower surfaces. The foregoing situations are accommodated by the present invention. Summary of the Invention In accordance with the present invention, a graphite article is provided comprising a compressed mass of expanded graphite particles in the form of a sheet having parallel, opposed first and second surfaces. The sheet has a plurality of transverse fluid channels passing through said sheet between the parallel, opposed first and second surfaces, the channels being formed by mechanically impacting a surface of the sheet to displace graphite within the sheet at a plurality of predetermined locations to provide the channels with openings at the first and second parallel opposed surfaces. In a preferred embodiment, the channel openings at one of the parallel opposed surfaces are smaller than their respective openings at the other opposed surface whereby pressurized fluid in contact with the opposed surface having the smaller channel openings enters the respective channels at an initial velocity which is greater than the velocity of the fluid exiting the respective channels, i.e. the gas exit velocity is slowed. The article of the present invention is useful as a fluid permeable electrode in electrochemical fuel cells as hereinafter described. A membrane electrode assembly for an electro-chemical fuel cell is also provided, comprising a pair of electrodes and an ion exchange membrane positioned between the electrodes, at least one of the electrodes being formed of a sheet of a compressed mass of expanded graphite particles having a plurality of transverse fluid channels passing through the sheet between first and second opposed surfaces of the sheet, one of the opposed surfaces abutting said ion exchange membrane, said transverse fluid channels being formed by mechanically impacting an opposed surface of the sheet to displace graphite within the sheet at predetermined locations. Brief Description of the Drawings Figure 1 is a plan view of a transversely permeable sheet of flexible graphite having transverse channels in accordance with the present invention; Figure 1 (A) shows a flat-ended protrusion element used in making the channels in the perforated sheet of Figure 1; Figure 2 is a side elevation view in section of the sheet of Figure 1 ; Figures 2(A), (B), (C) show various suitable flat-ended configurations for transverse channels in accordance with the present invention; Figures 3, 3(A) shows a mechanism for making the article of Figure 1 ; Figure 4 shows an enlarged sketch of an elevation view of the oriented expanded graphite particles of prior art flexible graphite sheet material; Figure 5 is a sketch of an enlarged elevation view of an article formed of flexible graphite sheet in accordance with the present invention; Figure 5, 6, 7 and 7(A) show a fluid permeable electrode assembly which includes a transversely permeable article in accordance with the present invention; and Figure 8 is a photograph at 100X (original magnification) corresponding to a portion of the side elevation view sketch of Figure 5. Detailed Description of the Invention Graphite is a crystalline form of carbon comprising atoms covalently bonded in flat layered planes with weaker bonds between the planes. By treating particles of graphite, such as natural graphite flake, with an intercalant of, e.g. a solution of sulfuric and nitric acid, the crystal structure of the graphite reacts to form a compound of graphite and the intercalant. The treated particles of graphite are hereafter referred to as "particles of intercalated graphite". Upon exposure to high temperature, the particles of intercalated graphite expand in dimension as much as 80 or more times its original volume in an accordion-like fashion in the "c" direction, i.e. in the direction perpendicular to the crystalline planes of the graphite. The exfoliated graphite particles are vermiform in appearance, and are therefore commonly referred to as worms. The worms may be compressed together into flexible sheets which, unlike the original graphite flakes, can be formed and cut into various shapes and provided with small transverse openings by deforming mechanical impact A common method for manufactuπng graphite sheet, e g foil from flexible graphite is described by Shane et al in U S Pat No 3,404,061 the disclosure of which is incorporated herein by reference In the typical practice of the Shane et al method, natural graphite flakes are intercalated by dispersing the flakes m a solution containing an oxidizing agent of, e g a mixture of nitπc and sulfuric acid The intercalation solution contains oxidizing and other intercalating agents known in the art Examples include those containing oxidizing agents and oxidizing mixtures, such as solutions containing nitπc acid, potassium chlorate, chromic acid, potassium permanganate, potassium chromate. potassium dichromate, perchloric acid, and the like, or mixtures, such as for example, concentrated nitπc acid and chlorate, chromic acid and phosphoπc acid, sulfuπc acid and nitπc acid, or mixtures of a strong organic acid, e g tπfluoroacetic acid, and a strong oxidizing agent soluble in the organic acid In a prefeπed embodiment, the intercalating agent is a solution of a mixture of sulfuπc acid, or sulfuπc acid and phosphoπc acid, and an oxidizing agent, l e nitπc acid, perchloπc acid, chromic acid, potassium permanganate, hydrogen peroxide, lodic or peπodic acids, or the like Although less prefeπed, the intercalation solutions may contain metal halides such as feme chloπde, and feme chloπde mixed with sulfuπc acid, or a hahde, such as bromine as a solution of bromine and sulfuπc acid or bromine in an organic solvent After the flakes are intercalated, any excess solution is drained from the flakes and the flakes are water-washed The quantity of intercalation solution retained on the flakes after draining may range from 20 to 150 parts of solution by weight per 100 parts by weight of graphite flakes (pph) and more typically about 50 to 120 pph Alternatively, the quantity of the intercalation solution may be limited to between 10 to 50 parts of solution per hundred parts of graphite by weight (pph) which permits the washing step to be eliminated as taught and descπbed m U S Pat No 4,895,713 the disclosure of which is also herein incorporated by reference The thus treated particles of graphite are sometimes referred to as "particles of intercalated graphite" Upon exposure to high temperature, e g 700°C to 1000°C and higher, the particles of intercalated graphite expand as much as 80 to 1000 or more times its ongmal volume in an accordion-like fashion in the c-direction, I e m the direction perpendicular to the crystalline planes of the constituent graphite particles The expanded, l e exfoliated graphite particles are vermiform in appearance, and are therefore commonly referred to as worms The worms may be compressed together into flexible sheets which, unlike the ongmal graphite flakes, can be formed and cut into vaπous shapes and provided with small transverse openings by deforming mechanical impact as hereinafter descπbed Flexible graphite sheet and foil are coherent, with good handling strength, and are suitably compressed, e g by roll-pressing, to a thickness of 0 003 to 0 15 inch and a density of 0 1 to 1 5 grams per cubic centimeter From about 1 5-30% by weight of ceramic additives, can be blended with the intercalated graphite flakes as descπbed in U S Patent 5,902,762 (which is incorporated herein by reference) to provide enhanced resm impregnation m the final flexible graphite product The additives include ceramic fiber particles having a length of 0 15 to 1 5 millimeters The width of the particles is suitably from 0 04 to 0 004 mm The ceramic fiber particles are non-reactive and non-adheπng to graphite and are stable at temperatures up to 2000°F, preferably 2500°F Suitable ceramic fiber particles are formed of macerated quartz glass fibers, carbon and graphite fibers, zirconia, boron nitride, silicon carbide and magnesia fibers, naturally occurring mineral fibers such as calcium metasilicate fibers, calcium aluminum silicate fibers, aluminum oxide fibers and the like. With reference to Figure 1 and Figure 2, a compressed mass of expanded graphite particles, in the form of a flexible graphite sheet is shown at 10. The flexible graphite sheet 10 is provided with channels 20, which are preferably smooth-sided as indicated at 67 in Figures 5 and 8, and which pass between the parallel, opposed surfaces 30, 40 of flexible graphite sheet 10. The channels 20 preferably have openings 50 on one of the opposed surfaces 30 which are larger than the openings 60 in the other opposed surface 40. The channels 20 can have different configurations as shown at 20' - 20"" in Figures 2(A), 2(B), 2(C) which are formed using flat-ended protrusion elements of different shapes as shown at 75, 175, 275, 375 in Figures 1(A) and 2(A), 2(B), 2(C), suitably formed of metal, e.g. steel and integral with and extending from the pressing roller 70 of the impacting device shown in Figure 3. The smooth flat-ends of the protrusion elements, shown at 77, 177, 277, 377, and the smooth bearing surface 73, of roller 70, and the smooth bearing surface 78 of roller 72 (or alternatively flat metal plate 79), ensure deformation and complete displacement of graphite within the flexible graphite sheet, i.e. there are no rough or ragged edges or debris resulting from the channel-forming impact. Prefeπed protrusion elements have decreasing cross-section in the direction away from the pressing roller 70 to provide larger channel openings on the side of the sheet which is initially impacted. The development of smooth, unobstructed surfaces 63 surrounding channel openings 60, enables the free flow of fluid into and through smooth-sided (at 67) channels 20. In a preferred embodiment, openings one of the opposed surfaces are larger than the channel openings in the other opposed surface, e.g. from 1 to 200 times greater in area, and result from the use of protrusion elements having converging sides such as shown at 76, 276, 376 The channels 20 are formed in the flexible graphite sheet 10 at a plurality of pre-determined locations by mechanical impact at the predetermined locations in sheet 10 using a mechanism such as shown in Figure 3 compπsmg a pair of steel rollers 70, 72 with one of the rollers having truncated, I e flat-ended, pπsm-shaped protrusions 75 which impact surface 30 of flexible graphite sheet 10 to displace graphite and penetrate sheet 10 to form open channels 20 In practice, both rollers 70, 72 can be provided with "out-of-register" protrusions, and a flat metal plate indicated at 79, can be used in place of smooth-surfaced roller 72 Figure 4 is an enlarged sketch of a sheet of flexible graphite 110 which shows a typical pπor art orientation of compressed expanded graphite particles 80 substantially parallel to the opposed surfaces 130, 140 This oπentation of the expanded graphite particles 80 results in anisotropic properties in flexible graphite sheets, l e the electπcal conductivity and thermal conductivity of the sheet being substantially lower in the direction transverse to opposed surfaces 130, 140 ("c " direction) than in the direction ("a" direction) parallel to opposed surfaces 130, 140 In the course of impacting flexible graphite sheet 10 to form channels 20, as illustrated in Figure 3, graphite is displaced withm flexible graphite sheet 10 by flat- ended (at 77) protrusions 75 to push aside graphite as it travels to and bears against smooth surface 73 of roller 70 to disrupt and deform the parallel onentation of expanded graphite particles 80 as shown at 800 in Figure 5 This region of 800, adjacent channels 20, shows disruption of the parallel oπentation into an oblique, non-parallel oπentation is optically observable at magnifications of 100X and higher In effect the displaced graphite is being "die-molded" by the sides 76 of adjacent protrusions 75 and the smooth surface 73 of roller 70 as illustrated m Figure 5 This reduces the anisotropy m flexible graphite sheet 10 and thus increases the electπcal and thermal conductivity of sheet 10 in the direction transverse to the opposed surfaces 30, 40 A similar effect is achιe\ ed with frusto-comcal and parallel-sided peg-shaped flat-ended protrusions 275 and 175 The perforated gas permeable flexible graphite sheet 10 of Figure 1 can be used as an electrode in an electrochemical fuel cell 500 shown schematically in Figures 6, 7 and 7(A) Figure 6, Figure 7 and Figure 7(A) show, schematically, the basic elements of an electrochemical Fuel Cell, more complete details of which are disclosed in U S Patents 4,988,583 and 5,300,370 and PCT WO 95/16287 (15 June 1995) and each of which is incorporated herein by reference With reference to Figure 6, Figure 7 and Figure 7(A), the Fuel Cell indicated generally at 500, compπses electrolyte in the form of a plastic e g a solid polymer ion exchange membrane 550 catalyst coated at surfaces 601, 603, e g coated with platinum 600 as shown in Figure 7(A), perforated flexible graphite sheet electrodes 10 m accordance with the present invention, and flow field plates 1000, 1100 which respectively abut electrodes 10 Pressuπzed fuel is circulated through grooves 1400 of fuel flow field pate 1 100 and pressuπzed oxidant is circulated through grooves 1200 In operation, the fuel flow field plate 1100 becomes an anode, and the oxidant flow field plate 1000 becomes a cathode with the result that an electπc potential, l e voltage is developed between the fuel flow field plate 1000 and the oxidant flow field plate 1100 The above descπbed electrochemical fuel cell is combined with others in a fuel cell stack to provide the desired level of electπc power as descπbed in the above-noted U S Patent 5,300,370 The operation of Fuel Cell 500 requires that the electrodes 10 be porous to the fuel and oxidant fluids, e g hydrogen and oxygen, to permit these components to readily pass from the grooves 1400, 1200 through electrodes 10 to contact the catalyst 600, as shown in Figure 7(A), and enable protons deπved from hydrogen to migrate through ion exchange membrane 550 In the electrode 10 of the present invention, channels 20 are positioned to adjacently co\ er grooves 1400, 1200 of the flow field plates so that the pressuπzed gas from the grooves passes through the smaller openings 60 of channels 20 and exits the larger openings 50 of channels 20 The initial velocity of the gas at the smaller openings 60 is higher than the gas flow at the larger openings 50 with the result that the gas is slowed down when it contacts the catalyst 600 and the residence time of gas-catalyst contact is increased and the area of gas exposure at the membrane 550 is maximized This feature, together with the increased electπcal conductivity of the flexible graphite electrode of the present invention enables more efficient fuel cell operation Figure 8 is a photograph (original magnification 100X) of a body of flexible graphite coπespondmg to a portion of the sketch of Figure 5 The articles of Figures 1 and 5 and the mateπal shown in the photograph (100X) of Figure 8 can be shown to have increased thermal and electπcal conductivity in the direction transverse to opposed parallel, planar surfaces 30, 40 as compared to the thermal and electπcal conductivity m the direction transverse to surfaces 130, 140 of pπor art mateπal of Figure 4 in which particles of expanded natural graphite unaligned with the opposed planar surfaces are not optically detectable A sample of a sheet of flexible graphite 0 01 inch thick having a density of 0 3 grams/cc, representative of Figure 4, was mechanically impacted by a device similar to that of Figure 3 to provide channels of different size in the flexible graphite sheet The transverse ("c" direction) electπcal resistance of the sheet mateπal samples was measured and the results are shown m the table below Also, the transverse gas permeability of channeled flexible graphite sheet samples, in accordance with the present invention, was measured, using a Gurley Model 4118 for Gas Permeability Measurement. Samples of channeled flexible graphite sheet in accordance with the present invention were placed at the bottom opening (3/8 in. diam.) of a vertical cylinder (3 inch diameter cross-section). The cylinder was filled with 300 cc of air and a weighted piston (5 oz.) was set in place at the top of the cylinder. The rate of gas flow through the channeled samples was measured as a function of the time of descent of the piston and the results are shown in the table below. Flexible Graphite Sheet (0 01 inch thick, density = 0 3 gms/cc) In the present invention, for a flexible graphite sheet having a thickness of 003 inch to 015 inch adjacent the channels and a density of 0 5 to 1 5 grams per cubic centimeter, the prefeπed channel density is from 1000 to 3000 channels per square inch and the prefeπed channel size is a channel in which the ratio of the area of larger channel opening to the smaller is from 50 1 to 150 1 In the practice of the present invention, the flexible graphite sheet can, at times, be advantageously treated with resm and the absorbed resin, after cuπng, enhances the moisture resistance and handling strength, I e stiffness of the flexible graphite sheet Suitable resm content is preferably 20 to 30% by weight, suitably up 60% by weight The article of the present invention can be used as electπcal and thermal coupling elements for integrated circuits in computer applications, as conformal electπcal contact pads and as electncally energized gπds in de-icmg equipment The above descπption is intended to enable the person skilled m the art to practice the invention It is not intended to detail all of the possible vaπations and modifications which will become apparent to the skilled worker upon reading the descπption It is intended, however, that all such modifications and vaπations be included within the scope of the invention which is defined by the following claims The claims are intended to cover the indicated elements and steps in any aπangement or sequence which is effective to meet the objectives intended for the invention, unless the context specifically indicates the contrary

Claims: WHAT IS CLAIMED IS: 1) A fluid permeable graphite article comprising a compressed mass of expanded graphite particles in the form of a sheet having parallel, opposed first and second surfaces, said sheet having a plurality of transverse fluid channels passing through said sheet between said first and second parallel, opposed surfaces, said channels being formed by mechanically impacting at least one of the first and second surface of said sheet at a plurality of locations to displace graphite within said sheet at said locations and provide said channels with openings at both of said first and second parallel, opposed surfaces. 2) Article in accordance with claim 1 wherein said compressed mass of expanded graphite particles is characterized by expanded graphite particles adjacent said channels extending obliquely with respect to said parallel opposed surfaces. 3) Article in accordance with claim 1 wherein the channel openings at said second surface of said sheet are suπounded by a smooth graphite surface. 4) Article in accordance with claim 1 wherein the channel openings at said first surface are larger than the channel openings at said second surface. 5) Article in accordance with claim 1 wherein the channel openings at said first surface are from 50 to 150 times larger in area than the channel openings at said second surface. 6) Article in accordance with claim 1 wherein 1000 to 3000 channels per square inch are present in said sheet. 7) Article in accordance with claim 1 wherein said graphite sheet has a thickness of 0.003 inch to 0.015 inch adjacent said channels and a density of 0.5 to 1.5 grams per cubic centimeter. 8) A fluid permeable graphite electrode comprising a compressed mass of expanded graphite particles in the form of a sheet having parallel, opposed first and second surfaces, said sheet having a plurality of transverse fluid channels passing through said sheet between said first and second parallel, opposed surfaces, said channels being formed by mechanically impacting at least one of the first and second surface of said sheet at a plurality of locations to displace graphite within said sheet at said locations and provide said channels with openings at both of said first and second parallel, opposed surfaces. 9) Electrode in accordance with claim 8 wherein said compressed mass of expanded graphite particles is characterized by expanded graphite particles adjacent said channels extending obliquely with respect to said parallel opposed surfaces. 10) Electrode in accordance with claim 8 wherein the channel openings at said second surface of said sheet are suπounded by a smooth graphite surface. 11) Electrode in accordance with claim 8 wherein the channel openings at said first surface are larger than the channel openings at said second surface. 12) Electrode in accordance with claim 8 wherein the channel openings at said first surface are from 50 to 150 times larger in area than the channel openings at said second surface. 13) Electrode in accordance with claim 8 wherein 1000 to 3000 channels per square inch are present in said sheet. 14) Electrode in accordance with claim 8 wherein said graphite sheet has a thickness of 0.003 inch to 0.015 inch adjacent said channels and a density of 0.5 to 1.5 grams per cubic centimeter. 15) Method for making a fluid permeable graphite article comprising: (i) providing a compressed mass of expanded graphite particles in the form of a sheet having parallel, opposed planar first and second surfaces; (ii) mechanically impacting at least one of said first and second surface of said sheet at a plurality of predetermined locations with flat-ended protrusions extending outward from a pressing member which penetrate said sheet and contact a smooth bearing surface directly beneath said sheet to form a plurality of channels passing through said sheet from said first surface to said second surface by displacing graphite within said sheet and forming channel openings at said first surface and said second surface. 16) Method in accordance with claim 15 wherein said flat ended pror sions decrease in cross-section as they extend outward from the pressing member to provide larger channel openings at said first surface 17) A membrane electrode assembly comprising a pair of electrodes and an ion exchange membrane positioned between said electrodes, at least one of said electrodes being formed of a sheet of a compressed mass of expanded graphite particles having a plurality of transverse fluid channels passing through said sheet between first and second parallel, opposed surfaces of said sheet, one of said opposed surfaces abutting said ion exchange membrane 18) Assembly in accordance with claim 17, said transverse fluid channels being formed by mechanically impacting an opposed surface of said sheet to displace graphite within said sheet at a plurality of predetermined locations 19) Assembly in accordance with claim 17 wherein said compressed mass of expanded graphite particles is characteπzed by expanded graphite particles adjacent said channels extending obliquely with respect to said parallel opposed surfaces 20) Assembly in accordance with claim 17 wherein the channel openings at said second surface of said sheet are suπounded by a smooth graphite surface 21) Assembly in accordance with claim 20 wherein the channel openings at said first surface are larger than the channel openings at said second surface 22) Assembly in accordance with claim 21 wherein the channel openings at said first surface are from 50 to 150 times larger m area than the channel openings at said second surface 23) Assembly m accordance with claim 17 wherein 1000 to 3000 channels per square inch are present in said sheet 24) Assembly in accordance with claim 17 wherein said graphite sheet has a thickness of 0 003 inch to 0 015 inch adjacent said channels and a density of 0 5 to 1 5 grams per cubic centimeter

Inventors: MERCURI ROBERT ANGELO, WARDDRIP MICHAEL LEE, WEBER THOMAS WILLIAM, MERCURI, ROBERT, ANGELO, WARDDRIP, MICHAEL, LEE, WEBER, THOMAS, WILLIAM
Applicants: GRAFTECH INC, GRAFTECH INC.
Application year: 2001
Main classification: H01M4
IPC codes: C04B35, H01M4, H01M8