PHOSPHORUS-SILICATE FIBERS SUITABLE FOR EXTENDED BAND AMPLIFICATION

Abstract: An optically active phosphorus-silicate glass when pumped to directly excite Er ions provides gain in 1565nm to 1620nm range and comprises in weight percent: SiO2 50 to 92%; Er2O3 0.01 to 2%; P2O5 greater than 5%; and Al2O3 0.0 to 0.3%.

Description: PHOSPHORUS-SILICATE FIBERS SUITABLE FOR EXTENDED BAND AMPLIFICATION Background of the Invention Field of the Invention This invention relates to optical fibers for use in optical fiber amplifiers and more particularly to phosphorus-silicate fibers. Technical Background Most of the current erbium doped fiber amplifiers (EDFAs) operate in the conventional band (C-band), approximately from about 1525 nm to about 1565 nm. Driven by the rapid growth in Internet, Metro and LAN applications, the wavelength division multiplexing (WDM) optical transmission systems employing EDFAs have to cope with the increasingly large capacity demands. Thus, it is important to develop new EDFA's that not only provide a flat-gain shape, but also have the widest possible bandwidth. Er-doped Al-Ge-Silica (Er-Al-Ge-Si) fibers have been a common choice for use in EDFA's operating in the long wavelength band (L-band) from 1565 nm to 1605 nm. However, in order to utilize the 1565 nm to 1620 nm capacity offered by the commercially available transmission fibers, there is a need to further increase EDFA's signal band capacity to 1620 nm and beyond, a range known as the extended L-Band. An article entitled "Optical Amplification Characteristics around 1.58 μm of Silica-Based Erbium-Doped Fibers Containing Phosphorous/Alumina as Codopants" published in the Technical Digest, Optical Amplifiers and their Applications Conference, 1998, describes alumina- phosphorus-silicate fibers. This article discloses that these fibers can be utilized in the L-band range. Table 1 of the article describes the core composition of three different fiber types: A, B, and C with varying concentrations of alumina and phosphorus. Type A fiber contains about 7.8 weight percent (wt%) alumina and no phosphorus. Type B fiber contains about 2 wt% alumina and 5 wt% phosphorus oxide. Type C fiber contains aluminum concentration of 0.3 wt% and phosphorus oxide concentration around 8 wt%. Figure 3 of this article depicts the gain curve for each of those fibers. The gain curve for the Type B fiber is lower than that of Type A fiber, primarily because of lower Er concentration. However, although the amount of Er is identical in Type A and C fibers, the Type C fiber extends the L-band gain to longer wavelengths, relative to that of the Type A fiber. Type C fiber, however, provides smaller gain amount and has more gain ripple. Finally, because of its core/clad composition, the Type C fiber would have a relatively low refractive index delta between the core and the cladding (ΔN < 0.004), which results in low pump efficiency and high bending sensitivity. This would, in turn, result in a very large size module, due to high total power and a large coil diameter, and would make the amplifier commercially impractical. The strong presence of AlPO in making silica-based Al-P-Si fibers such as fibers Types B and C has been shown to be problematic. The AIPO 4 units tend to cluster away from the silica-based structural network and form microcrystals (with typical grain sizes of less than 100 μm). These microcrystals cause high scattering loss in the resultant fibers. Moreover, the AlPO 4 units have a lower refractive index than those fibers with P 2 0 5 and Al 2 O 3 . A relatively high ΔN of about 1% is commonly desired for fibers utilized in EDFA applications. More alumina and phosphorus would be desirable to raise the refractive index of the core relative to the clad and to obtain optimal gain shape in the output of EDFA. However, elevated Al and P levels lead to the formation of a high concentration of AlPO 4 units in the glass, which in turn result in lower ΔN, and further aggravate the clustering and the resulting scattering problem. An article entitled "Fabrication and Characterization of Yb 3+ :Er 3+ Phosphosilicate Fibers for Lasers" published in Journal of Lightwave technology, Vol. 16, No. 11, Nov. 1998 also discloses optical fibers with optically active glass. This article, however, is directed to high power fiber lasers operating at 1.5μm, and specifically to Yb and Er co-doped fiber lasers. The article teaches that in order to achieve high output power a 1064nm Nd: YAG laser is used to activate Yb elements, thus indirectly pumping Er ions. The excited Yb elements transfer energy to the Er ions, enabling optical signal amplification from the Er ions. More specifically, this article discloses that a high power (800mW) Nd: YAG laser was used to achieve the high output power from the optical fiber. In a commercially deploy able amplifier such a Nd: YAG pump laser would be prohibitively large. Therefore, a Nd:YAG laser would not be utilized in a typical optical amplifier where component miniaturization and space conservation are extremely important. Furthermore, such a laser can not be used effectively to directly pump Er ions. SUMMARY OF THE INVENTION According to one aspect of the present invention an optically active phosporus- silicate glass when pumped to directly excite Er ions, provides gain in 1565nm to 1620nm range and comprises in weight percent: SiO 2 50 to 92%; Er 2 O 3 0.01 to 2%; P 2 O 5 greater than 5%; and Al 2 O 3 0.0 to 0.3%. According to an embodiment of the present invention this glass includes, in weight percent: SiO 2 65 to 92%; Er 2 O 3 0.01 tol%; P 2 O 5 greater than 5%; Al 2 O 3 0 toθ.3%; and one or more oxides of the following elements: Ge, Yb; Y; Ga; Ta, Gd, Lu, La, and Sc in an amount from 0.1% to 20% wt %. An advantage of the inventive glass is that it can be used in optical gain medium fiber in L-band optical amplifiers, extending the L- band beyond 1605 nm to 1620 nm or beyond. The foregoing general description and the following detailed description are merely exemplary of the invention, and are intended to provide an overview or framework for understanding the nature and character of the invention as it is claimed. The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. The drawings illustrate various features and embodiments of the invention, and together with the description serve to explain the principles and operation of the invention. BRIEF DESCRIPTION OF THE DRAWINGS Figures 1 is a graph of fluorescence spectrums of three Er + doped phospho-silicate glass fibers containing less than 0.03Wt% of A1 2 0 3 and that of phospho-silicate glass fiber containing a relatively large amount of A1 2 0 3 . Figure 2 is a plot of calculated gain vs. wavelength for these fibers. Figure 3 is a schematic cross-sectional illustration of an improved Er + doped phospho-silicate glass fiber. Figure 4 is a schematic illustration of an optical amplifier that utilizes the optical fiber of figure 3. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS One preferred embodiment of the present invention includes Er-doped, Al 2 0 3 -free, phospho-silicate composition which is suitable for use in an optical fiber as gain medium in the optical amplifiers suited for the extended L-band. Fiber with Al 0 3 -free core compositions provides more gain at large wavelengths than fibers containing even small concentrations of alumina. Advantages of this fiber are low passive loss and relatively high refractive index delta. Passive loss (also referred to as background loss) includes, for example, loss due to scatter from scattering centers (for example, microcrystals and refractive index discontinuities) and loss due to spurious absorption (water or iron, or other metal absorbtion, for example). Refractive index delta is defined as core index minus cladding index, divided by cladding index, or ΔN= core " clad Preferably, these fibers have a refractive index delta of ΔN that is n clad greater than 0.005. More preferably, 0.007< ΔN <0.015 and even more preferably 0.008<ΔN<0.013. In some embodiments the fiber will have ΔN in the range 0.009< ΔN ≤O.Ol 1. These ΔN values minimize fiber bend losses and result in better pump power conversion efficiency. To further modify the extended L-band gain spectra, we utilize one or more gain modifying or gain flattening agents. These agents may be, for example, Ga and Sb. It is preferred that these agents comprise 0.5 to 20 wt% of the glass. These elements overcome the dip in the gain curve at about 1575 nm (see figure 2) and improve gain. An increase in phosphorus concentration increases the refractive index of the glass and, correspondingly, the lower phosphorus concentration the lower is the refractive index. The addition of Ge, Ta, Yb, La, Y or other index increasing elements such as optically inactive elements with an atomic number greater than 15 increases the refractive index of the glass and compensates for lower phosphorus concentration. The optically inactive elements are elements that show substantially no absorption or emission in the 800 nm-1700 nm wavelength range. Thus, if the amount of phosphorus in the fiber core is less than 10 percent, it is preferable that these elements comprise 0J wt% to 20 wt% of the core's glass composition. It is preferable that they comprise 1 to 15 wt%, more preferable that they comprise 1-10 wt% and most preferable that they comprise 1-5 wt% of the total glass composition. It is also preferred that one or more of the following elements be utilized as Er ion de-clustering agents: Yb, Y, Sc, La, Ga, Gd and Lu. It is preferred, when Er concentration is high (0Jwt%, for example) that these de-clustering agents comprise 0.5 to 20wt % of the glass composition. This group of elements has no detrimental effect on gain shape. These elements, to our knowledge, do not form complex unit formation with P 2 0 5> but have shown to produce some degree of the desired broadening and Er-ion de-clustering effect when incorporated into rare earth-doped silica glasses. Figure 1 shows that the spectral emissions (fluorescence) from four rare-earth doped phosphosilicate fibers. More specifically, Figure 1 depicts four curves corresponding to four optically active fiber core glass compositions A', B', C, D', respectively. An optically active glass contains a rare-earth material and provides gain in a range from about 800 to about 1700nm. For example, an Er doped optically active glass provides gain in the 1500nm to 1650nm range. The first phosphorus- silicate composition A' includes about 20 wt% of phosphorus-oxide (for example, P 2 O 5 ), about 10 wt% of Yb-oxide (Yb 2 O 3 ) and, about 0.25 wt% of erbium oxide (for example, Er 2 O 3 ) and about 4.5wt% of Al-oxide (for example, Al 2 O 3 ). The second composition B' includes about 23wt% of phosphorus-oxide, about 2.5% wt5 of Yb-oxide and about 0J9wt% of erbium oxide. The second glass composition includes no aluminum. The third composition C includes about 20 wt% of phosphorus oxide, no Yb-oxide, no Aluminum oxide and about 0.25 wt% of erbium oxide. The fourth composition D' includes about 22 wt% of phosphorus oxide, about 2 wt% of Yttrium oxide and about 0.2 wt% of erbium oxide. The fourth composition contains no aluminum oxide . Considering the issues mentioned above with regard to the Al 2 O 3 compositions, it is highly advantageous to use low Al-oxide and even more preferably to use the Al 2 O 3 -free phosphosilicate compositions to overcome those problems. Figure 2 illustrates gain spectrum for these fibers and shows that the gain spectrum extends into 1620 nm range and beyond. Therefore, using Er-doped phospho-silicate based compositions (P 2 O 5 , 2-45wt%), with low concentration (for example, less than 0.3 wt%, and preferably less than 0.2 wt%) of aluminum is highly advantageous oxide for use in the extended L-band amplifier applications. It is even more preferrable that the amount of the aluminum oxide be less than 0J wt% and preferably less than 0.05 wt%. It is most preferrable that these oxide phosphosilicate based compositions be essentially aluminum free. Referring to figure 3, an examplarary embodiment optical fiber 10 according to the invention includes a core 12 with a low concentration of aluminum- oxide (less than 0.3% and preferably 0% ) and at least one cladding 14 surrounding the core. More specifically, the core 12 includes, in weight percent: 65%<SiO 2 <92%; 0.01%<RE X O<2%, where RE is a rare earth material other tan Yb and x,y are integers greater than 0 (for example, Er 2 O 3 ); P 2 O 5 >8%; and 0.0%<A1 2 O 3 <0.3%. It is preferable that the rare eart material be erbium. It is preferable that the amount of Er 2 O 3 be 0J to 1.0wt% and more preferable that the amount of Er 2 O 3 be be 0.2 to 0.4wt%. This amount of Er 2 O 3 provides good gain characteristics without too much clustering. As discussed above, the core 12 may also include index raising co-dopants in order to achieve the refractive index delta ΔN of greater than 0.005. The core 12 may also have the following composition (in weight percent): 50%<SiO 2 <92%; 0.01% < Er 2 O 3 < 1%; P 2 O 5 > 5%; 0.0% < A1 2 O 3 <0.3%; and one or more of the above descibed index raising elements in the amount of 0Jwt% to 20wt%. In this embodiment the cladding 14 of the optical fiber 10 contains Si and may contain P, F, and/or Ge. More specifically, the cladding 14 contains less than 5 wt% P 2 O 5; less than 1 wt% of F, and about 2 wt% of Ge. Tables 1 and 2 disclose examples of chemical compositions and important parameters of various examplarary phosphorus silicate fibersmade with such compositions. More specifically, Table 1 provides fiber composition data and measured data from some of these fibers. This measured data includes mode field diameters (MFD) at 1500 nm, cut-off wavelengths (nm), and total background noise (TBN) measured at 1250 nm, 1300 nm and 1619 nm, for each of the optical fibers. Table 1 Table 2 specifies pump power utilized to excite Er ions in the optical fiber, the signal power provided with the tunable laser (TLS pwr) and the specific wavelengths ranges (in nm, tabulated in the wavelength column) for the fibers 2 and 3 of Table 1. Table 2 shows that these fibers have very low polarization mode dispersion (PMD) at the specified wavelength ranges. (It is noted that the signal wavelength in a telecommunication system is typically about in the 1550nm.) Table 2 *Polarization mode dispersion These fibers may be used in an extended L band amplifier. A schematic of an exemplary amplifier 100 is shown in Fig 4. The amplifier 100 operates in the 1565 to 1620 nm band and as illustrated includes two coils 110, 120 made of low aluminum (and preferably no aluminum) phosphorus silicate fiber 10. These coils may have identical or differing compositions. Those skilled in the art will recognize that an amplifier may also be designed with a single coil or with more the two coils, of a fiber according to the present invention. In addition, this amplifier may also include one or more of the following components: an isolator, avariable optical attenuator, a filter, or a grating. The fiber coils 110 and 120 are utilized to provide gain to signals in the extended L-band range. The amplifier 100 also includes optical isolators 130, 140, and 150. These isolators prevent unwanted reflections between gain stages (corresponding to fiber coils 110 and 120) and other optical components. The optical pumps 160, 165, and 170 are utilized to directly excite the Er ions to an upper level, initiating stimulated emission and gain. Pumps 160, 165, and 170 are either 1480nm or 980 nm pumps. When Yb is not used as a codopant (Y can be used as a de-clustering agent, if needed) both 980 and 1480 pumps can be utilized to directly excite Er ions. In the presence of Yb only 1480 pumps are used. Therefore, we do not utilize a 1060 nm pump to excite Yb ions and, thus, do not indirectly transfer energy to Er by energy transfer from Yb ions to Er ions. Wavelength Division Multiplexers (WDMs) 175, 180 and 185 or other pump/signal combiners combine the pump and signal light into one fiber, thus providing both the signal light and pump energy to the first gain stage. The gain flattening filter (GFF) 190 levels the gain shape to an acceptable amount. The variable optical attenuator (VOA) 195 may also be used to control the signal level. Other optical components that may be included are: pump or signal taps (for monitoring), circulators (for signal routing), optical filters, fiber gratings, signal multiplexers and demultiplexers, signal add/drops, or dispersion compensation modules. Those skilled in the art will appreciate that an amplifier according to the present invention may include other optical components, or the above described optical components in different arrangements, chosen as to result in desired output and performance characteristics. Accordingly, it will be apparent to those skilled in the art that various modifications and adaptations can be made to the present invention without departing from the scope of the invention. It is intended that the present invention cover the modifications and adaptations of this invention as defined by the appended claims and their equivalents.

Claims: What is claimed is: 1. An optically active phosphorus-silicate glass comprising in weight percent: SiO 2 50 to 92%; Er 2 O 3 0.01 to2%; P 2 O 5 greater than 5%; and Al 2 O 3 0.0 to 0.3%, wherein said optically active glass, when pumped to directly excite Er ions, provides gain in 1565nm to 1620nm range. 2. An optically active glass according to claim 1, wherein the amount of P 2 O 5 is greater than 8 wt%. 3. An optical fiber comprising an optically active glass of claim 1. 4. An optical amplifier comprising an optical fiber of claim 3. 5. An optically active glass according to claim 1, wherein concentration of Al 2 O 3 is≤ 0J wt%. 6. An optically active glass according to claim 5, wherein Al 2 O 3 concentration is 0 to 0.05 wt%. 7. An optically active glass according to claim 7, wherein the amount of P 2 O 5 is greater than 20wt%. 8. An optically active glass according to claim 1 further comprising in the amount of 0.1% to 20% one or more of the elements increasing refractive index, said elements being selected from: Ge, Yb, Y, Ga, Ta, or optically inactive elements with Atomic Number greater than 15. 9. An optical amplifier comprising an optical pump and an optical fiber comprising an optically active glass of claim 8, wherein said Er ions are directly excited by energy provided by said optical pump. 10. An optically active glass according to claim 1, further comprise 0.5 to 20wt% of Er-ion de-clustering agents, said de-clustering agents being selected from a group of :Yb, Y, Sc, La, Ga, Gd and Lu. 11. An optically active glass according to claim 1, further comprising 0.5 to 20wt% of gain fattening agents, said gain flattening agents being selected from a group of : Ga and Sb. 12. An optically active glass comprising in weight percent: SiO 2 50 to 92%; E 2 O 3 0.01 to 1%; P 2 O 5 greater than 5 % ; Al 2 O 3 0 to 0.3%; and one or more of the following elements to increase the index of refraction Ge, Yb; Y; Ga; Ta in the amount of 0J to 20%; wherein said optically active glass, when pumped to directly excite rare earth ions, provides gain in 1565nm to 1620nm range. 13. An optically active glass according to claim 12, were in the amount of P 2 O 5 is greater than 15wt%. 14. An optically active glass according to claim 12, wherein the amount of E 2 O 3 is 0.2 to 0.4wt%. 15. An optical fiber comprising: a core and at least one cladding surrounding said core, said core comprising with the optically active glass of claim 1, said cladding containing at least one of the following elements: P, F, and Ge. 16. The optical fiber of claim 15, wherein said core contains Ge. 17. The optical fiber of claim 16, wherein the amount of Ge is less than 0.5 wt%. 18. An optical fiber comprising: a core having refractive index N core , said core comprising the optically active glass of claim 1 ; at least one cladding surrounding said core, said cladding having refractive index N c ι a d ; wherein 0.007 < ΔN < 0.015, where ΔN =(N core - N clad )/ N clad. 19. On optical fiber according to claim 18, wherein 0.008< ΔN <0.013. 20. On optical amplifier comprising: the optical fiber of claim 15, said amplifier further including at least one optical pump providing optical radiation to said optical fiber such that said Er ions are being directly pumped by said pump, and at least one other optical component.

Inventors: GOFORTH DOUGLAS E, KOHLI JEFFREY T, MINELLY JOHN D, MURTAGH MICHAEL T, QI GANG, TRUESDALE CARLTON M, WANG JI, GOFORTH, DOUGLAS, E, KOHLI, JEFFREY, T, MINELLY, JOHN, D, MURTAGH, MICHAEL, T, QI, GANG, TRUESDALE, CARLTON, M, WANG, JI
Applicants: CORNING INC, CORNING INCORPORATED
Application year: 2001
Main classification: C03C13
IPC codes: C03C3, C03C4, C03C13, H01S3