COLOR STABLE POLYARYLATE-CONTAINING COMPOSITIONS

Abstract: The color stability of 1,3-dihydroxybenzene dicarboxylate polyarylates, especially resorcinol isophthalate/terephthalate polyarylates, is enhanced by combination with at least one photobleachable 4-aminocinnamic compound such as 4-dimethylaminocinnamaldehyde. The latter absorbs radiation in the range of about 360-390 nm, balancing the radiation absorbed by hydroxybenzophenone moieties formed in the polyarylate.

Description: COLOR STABLE POLYARYLATE-CONTAINING COMPOSITIONS BACKGROUND OF THE INVENTION This invention relates to color stability, and more particularly to improvement of the color stability of compositions comprising polyarylates. Photoyellowing of polymers over time is a known phenomenon which is undesirable for aesthetic reasons. It is generally the result of absorption of ultraviolet (UV) radiation by the polymer, said radiation causing photochemical reactions which typically form yellow materials. Such base polymers as polycarbonates are particularly sensitive to photoyellowing. This can severely impede the fabrication of light-colored articles such as white or blue articles, since the yellowing tendency can obliterate the white or blue coloring with the passage of time. Alternatively, a higher proportion of the desired colorant can be introduced during fabrication but there will still be a change in appearance over time. A recent development which can minimize photoyellowing is the use of a polyarylate, typically a resorcinol isophthalate/terephthalate, which may be blended with a base polymer, may form a copolymer therewith or may constitute a separate, external layer thereover. Such polyarylates undergo a Fries rearrangement to form hydroxybenzophenone moieties, which serve as ultraviolet absorbers and protect the base polymer from photoyellowing. However, the polyarylates themselves may develop a yellow color with the passage of time, dissipating to at least some extent the benefits of UV absorption. This is because, while they absorb primarily in the range of 360-390 nanometers (nm) in the near ultraviolet portion of the spectrum, their absorption extends a small distance into the visible area, resulting in the yellow color development. One known method of compensating for color development is to introduce into the polymer a photobleachable compound which absorbs in the same region of the spectrum as the hydroxybenzophenone moieties. Yellow dyes generally absorb in this range. Such a dye, if photobleachable, turns colorless at approximately the same rate as that of photoyellowing and the overall color of the polymer remains fairly constant. This method is disclosed in various patents, of which examples in the polyphenylene ether art include US Patents 4,493,915 and 5,478,878. However, the absorption of most photobleachable yellow dyes continues into the range of about 400-450 nm in the visible region of the spectrum, farther than that of the hydroxybenzophenone moieties. This means that their presence initially introduces a yellow tinge of greater intensity than that produced as hydroxybenzophenone moieties are formed. Under such conditions it is at best difficult, and at worst impossible, to produce light colored articles with consistent coloration over the passage of time. SUMMARY OF THE INVENTION The present invention is based on the discovery that color development as the result of the formation of hydroxybenzophenone moieties in polyarylates can be suppressed by the addition of photobleachable compounds having absorption limited, within the near ultraviolet and visible portions of the spectrum, to the aforementioned 360-390 nm region, hereinafter sometimes designated "critical range". It has further been discovered that aminocinnamic compounds have such absorption properties. Accordingly, in one embodiment the invention is a resinous composition comprising the following and any reaction products thereof: (A) at least one thermoplastic polyester comprising structural units derived from a 1,3-dihydroxybenzene organodicarboxylate, and (B) at least one 4-aminocinnamic compound of the formula wherein: each of R and R is an alkyl radical, or R 1 and R together with the nitrogen atom separating them form a heterocyclic radical; R 3 is COOR 4 , C(O)R 4 , or CN; R 4 is hydrogen, alkyl or aryl; and each of R 5 and R 6 is hydrogen, alkyl, or aryl; or R 5 and R 6 together with the carbon atoms connecting them form an alicyclic radical; said 4-aminocinnamic compound absorbing radiation in the range of about 360-390 nm. In another embodiment the invention is a resinous composition comprising the following and any reaction products thereof: (A) at least one thermoplastic polyester comprising structural units derived from a 1 ,3-dihydroxybenzene organodicarboxylate, and (B) at least one 4-aminocinnamic compound of the formula wherein: each of R 1 and R 2 is an alkyl radical, or R 1 and R 2 together with the nitrogen atom separating them form a heterocyclic radical; R 3 is COOR 4 , C(O)R 4 , or CN; R 4 is hydrogen, alkyl or aryl; R 5 is hydrogen, alkyl, or aryl; and each of R 7 and R 8 is hydrogen or an alkyl radical, or R 7 and R 8 together form an alicyclic radical; said 4-aminocinnamic compound absorbing radiation in the range of about 360-390 nm. In another embodiment the invention is a resinous composition comprising the following and any reaction products thereof: (A) at least one thermoplastic polyester comprising structural units derived from a 1 ,3-dihydroxybenzene organodicarboxylate, and (B) at least one 4-aminocinnamic compound of the formula wherein: each of R 1 and R 2 is an alkyl radical, or R 1 and R 2 together with the nitrogen atom separating them form a heterocyclic radical; each of R 5 and R 6 is hydrogen, alkyl, or aryl; or R 5 and R 6 together with the carbon atoms connecting them form an alicyclic radical; and each of R 7 and R 8 is hydrogen or an alkyl radical, or R 7 and R 8 together form an alicyclic radical; said 4-aminocinnamic compound absorbing radiation in the range of about 360-390 nm. DETAILED DESCRIPTION; PREFERRED EMBODIMENTS For the sake of brevity, the constituents of the compositions of this invention are defined as "components" irrespective of whether a reaction between said constituents occurs at any time. Thus, the compositions may include said components and any reaction products thereof. Component A in the compositions of the invention is a thermoplastic polyester comprising structural units derived from a 1 ,3-dihydroxybenzene organodicarboxylate. Suitable polymers for this purpose, specifically arylate polymers, are disclosed in copending, commonly owned application Serial No. 09/152,877, the disclosure of which is incorporated by reference herein. Arylate polymers having a glass transition temperature of at least about 80°C and no crystalline melting temperature, i.e., those that are amorphous, are preferred. The arylate polymer is typically a 1,3-dihydroxybenzene isophthalate/terephthalate comprising structural units of the formula wherein each R is a substituent, especially halo or Cι- 12 alkyl, and p is 0-3, optionally in combination with structural units of the formula wherein R 9 and p are as previously defined and R 10 is a divalent C 3-2 o aliphatic, alicyclic or mixed aliphatic-alicyclic radical. Moieties represented by R 10 are often referred to as "soft block" units. It is within the scope of the invention for other acid groups, such as those derived from aliphatic dicarboxylic acids such as succinic acid, adipic acid or cyclohexane- 1 ,4-dicarboxylic acid, or from other aromatic dicarboxylic acids such as 2,6-naphthalenedicarboxylic acid, to be present, preferably in amounts no greater than about 30 mole percent. Most often, however, component A consists of units of formula IV, optionally in combination with units of formula V. The units of formula IV contain a resorcinol or substituted resorcinol moiety in which any R 9 groups are preferably C alkyl; i.e., methyl, ethyl, propyl or butyl. They are preferably primary or secondary groups, with methyl being more preferred. The most preferred moieties are resorcinol moieties, in which p is zero, although moieties in which p is 1 are also excellent with respect to the invention. Said resorcinol moieties are most often bound to isophthalate and/or terephthalate moieties. Said 1,3-dihydroxybenzene moieties are bound to aromatic dicarboxylic acid moieties which may be monocyclic, e.g., isophthalate or terephthalate, or polycyclic, e.g., naphthalenedicarboxylate. Preferably, the aromatic dicarboxylic acid moieties are isophthalate and/or terephthalate. Either or both of said moieties may be present. For the most part, both are present in a molar ratio of isophthalate to terephthalate in the range of about 0.25-4.0: 1, preferably about 0.4-2.5: 1, more preferably about 0.67- 1.5: 1 , and most preferably about 0.9- 1.1:1. In the optional soft block units of formula V, resorcinol or substituted resorcinol moieties are again present in ester-forming combination with R 10 which is a divalent C 3- 0 aliphatic, alicyclic or mixed aliphatic-alicyclic radical. Preferably, R 10 is a C 3-20 straight chain alkylene, C 3- i2 branched alkylene, or C. H2 cyclo- or bicycloalkylene group. More preferably, R 10 is aliphatic and especially C 8- ι 2 straight chain aliphatic. It is usually found that the arylate polymers most easily prepared, especially by interfacial methods, consist of units of formula IV and especially combinations of resorcinol isophthalate and terephthalate units in a molar ratio in the range of about 0.25-4.0: 1, preferably about 0.4-2.5: 1, more preferably about 0.67-1.5: 1, and most preferably about 0.9-1.1: 1. When that is the case, the presence of soft block units of formula V is usually unnecessary. If the ratio of units of formula V is outside this range, and especially when they are exclusively iso- or terephthalate, the presence of soft block units may be preferred to facilitate interfacial preparation. A particularly preferred arylate polymer containing soft block units is one consisting of resorcinol isophthalate and resorcinol sebacate units in a molar ratio between 8.5:1.5 and 9.5:0.5. Arylate polymers useful as component A may be prepared by conventional esterification reactions which may be conducted interfacially, in solution, in the melt or under solid state conditions, all of which are known in the art. Typical interfacial preparation conditions are described in copending application Serial No. 09/030,076, the disclosure of which is incorporated by reference herein. Also useful as component A are the block copolyestercarbonates disclosed and claimed in copending, commonly owned application Serial No. 09/181,902, the disclosure of which is also incorporated by reference herein. They include block copolymers comprising moieties of the formula wherein R and p are as previously defined, each R u is independently a divalent organic radical, m is at least about 10 and n is at least about 4. Soft block moieties corresponding to formula HI may also be present. The most preferred moieties in the arylate blocks are again resorcinol moieties, in which p is zero. In the organic carbonate blocks, each R 1 ' is independently a divalent organic radical. Preferably, said radical comprises at least one dihydroxy-substituted aromatic hydrocarbon, and at least about 60 percent of the total number of R 1 ' groups in the polymer are aromatic organic radicals and the balance thereof are aliphatic, alicyclic, or aromatic radicals. Suitable R 11 radicals include m-phenylene, p-phenylene, 4,4 - biphenylene, 4,4'-bi(3,5-dimethyl)-phenylene, 2,2-bis(4-phenylene)propane, 6,6'- (3,3,3',3'-tetramethyl-l, -spirobi[lH-indan]) and similar radicals such as those which correspond to the dihydroxy-substituted aromatic hydrocarbons disclosed by name or formula (generic or specific) in U.S. Patent 4,217,438, which is incorporated herein by reference. A particularly preferred divalent organic radical is 2,2-bis(p- phenylene)isopropylidene and the dihydroxy-substituted aromatic hydrocarbon corresponding thereto is commonly known as bisphenol A. Component B is at least one 4-aminocinnamic compound of formula I, fl\ or HI. In said compounds, R 1 and R 2 may each be alkyl or may, together with the connecting nitrogen atom, be a heterocyclic radical such as pyrrolyl or piperidinyl. Most often, each of R 1 and R 2 is d-4 alkyl, especially methyl. In said compounds the R 3 radical, when present, may be COOR 4 , C(O)R 4 , or CN. Preferably R 3 is C(O)R 4 . R 4 may be hydrogen, alkyl, aryl or substituted aryl. Most often, R 4 is hydrogen or C alkyl. In said compounds each of R and R 6 , when present, may be one of the designated radicals. Most often, each of R 5 and R 6 is hydrogen. It should also be noted that, although the configuration of formula I might suggest that R 5 and R 6 are in the trans configuration, the use of both cis and trans compounds is within the scope of the invention. In said compounds each of R 7 and R 8 , when present, may independently be hydrogen or an alkyl radical. Alkyl radicals are typically C M , straight- or branched- chain, and preferably methyl. Alternatively, R and R may be joined together to form an alicyclic radical, preferably a five-membered or six-membered ring. Most often, each of R 7 and R 8 , when present, is hydrogen. Numerous compounds of formulas I, π, and HI are available or can be prepared by the methods described in the literature. For example, compounds of formula I may be prepared by the reaction of a suitable aminobenzaldehyde with a suitable methyl ketone. An essential feature of component B is its capability of absorbing radiation in the critical range. In fact, the compounds of formula I have an absorption maximum in this range but do not absorb a substantial proportion of radiation in the lowest region of the visible spectrum; i.e., in the range of about 400-410 nm. Thus, it does not initially impart a yellow color to the resinous composition but does, in large part, match the absorption of the hydroxybenzophenone moieties formed in the polyarylate. As a result, the resinous composition has a high degree of color stability. Moreover, the color properties of any specific composition can be adjusted as necessary, in both wavelength and intensity, by suitable variations in the substituent values on the compounds of formula I, π, or HI. Component B is present in the compositions of the invention in an amount effective to balance color development as a result of the formation of hydroxybenzophenone moieties. In general, this amount will be in the range of about 50-1,000 ppm by weight based on component A. The exact amount will depend on such factors as the specific resin composition employed and can be readily determined without undue experimentation. The formation of the compositions of the invention may be effected by art- recognized blending techniques. These include melt blending and solution blending. The compositions of the invention may be employed for the fabrication of resinous articles having a high degree of light stability. They may also be employed as weatherability improving additives in blends with at least one other polymer, especially polycarbonates, polyesters, polyetherimides, polyphenylene ethers and addition polymers. Related blends are disclosed in commonly owned, co-pending application Serial No. 09/152,877, the disclosure of which is incorporated by reference herein. The compositions of the invention may also be employed in multilayer articles comprising a substrate layer comprising at least one thermoplastic polymer, thermoset polymer, cellulosic material, glass, ceramic, or metal, and at least one coating layer thereon, said coating layer comprising the composition of the invention. Optionally, the multilayer articles may further comprise an interlayer, for example an adhesive interlayer, between any substrate layer and any polymer coating layer. The compositions of the invention may also contain fillers and/or pigments. Illustrative extending and reinforcing fillers and pigments include silicates, zeolites, titanium dioxide, stone powder, glass fibers or spheres, carbon fibers, carbon black, graphite, calcium carbonate, talc, mica, lithopone, zinc oxide, zirconium silicate, iron oxides, diatomaceous earth, calcium carbonate, magnesium oxide, chromic oxide, zirconium oxide, aluminum oxide, crushed quartz, calcined clay, talc, kaolin, asbestos, cellulose, wood flour, cork, cotton and synthetic textile fibers, especially reinforcing fillers such as glass fibers and carbon fibers, as well as colorants such as metal flakes, glass flakes and beads, ceramic particles, other polymer particles, dyes and pigments which may be organic, inorganic or organometallic. The invention is illustrated by the following examples. EXAMPLE 1 A resorcinol isophthalate/terephthalate bisphenol A carbonate block copolyestercarbonate having a 1 : 1 molar ratio of carbonate to ester groups and a 1 : 1 molar ratio of isophthalate to terephthalate groups was prepared and 2 grams (g) thereof was dissolved in 8 milliliters (ml) of chloroform. 4-Dimethylamino- cinnamaldehyde, 700 micrograms (μg), was added to the solution. A 25.4-micron film thereof was cast on a glass surface using a doctor blade and the solvent was evaporated. The film was mounted in a slide holder and exposed in a Ci35A weatherometer (B/B filter, 0.77 watts per square meter [W/m 2 ]). The color data after various periods of exposure are listed in Table I. The parameters L*, a* and b* respectively represent the light intensity (100 = white light), yellow-blue hue (positive is yellow) and red-green hue (positive is red). The parameter ΔE varies directly with the change in color of the sample and is the square root of the expression (L*ι - L* 0 ) 2 + (a*ι - a* 0 ) 2 + (b*ι - b*o) 2 , where L*ι, a*ι and b*ι are the values after exposure and L* 0 , a* 0 and b* 0 the initial values. TABLE I These results show that there is little change in color properties of the film upon weathering. EXAMPLE 2 A film identical to that of Example 1 was compression molded at 200°C on a white bisphenol A polycarbonate plaque and the assemblage was exposed as in Example 1. The results are given in Table IL TABLE H For comparison, the results in Table HI were obtained for a control in which the polyarylate film contained no 4-dimethylaminocinnamaldehyde. TABLE m -0.49 -2.94 -3.15 -3.45 -3.57 3.27 8.79 9.50 10.86 11.22 ΔE 6.04 6.77 8.15 8.53 It can be seen that the color change for the control was substantially greater than that for the plaque coated with the composition of the invention.

Claims: WHAT IS CLAIMED IS: 1. A resinous composition comprising the following and any reaction products thereof: (A) at least one thermoplastic polyester comprising structural units derived from a 1 ,3-dihydroxybenzene organodicarboxylate, and (B) at least one 4-aminocinnamic compound of the formula wherein: each of R 1 and R 2 is an alkyl radical, or R 1 and R 2 together with the nitrogen atom separating them form a heterocyclic radical; R 3 is COOR 4 , C(O)R 4 , or CN; R 4 is hydrogen, alkyl or aryl; and each of R 5 and R 6 is hydrogen, alkyl, or aryl; or R 5 and R 6 together with the carbon atoms connecting them form an alicyclic radical; said 4-aminocinnamic compound absorbing radiation in the range of about 360-390 nm. 2. The composition according to claim 1 wherein component A comprises structural units of the formula wherein each R is a substituent and p is 0-3, optionally in combination with structural units of the formula wherein R 9 and p are as previously defined and R 10 is a divalent C 4 . 12 aliphatic, alicyclic or mixed aliphatic-alicyclic radical. 3. The composition according to claim 2 wherein component A consists of structural units of formula IV and p is zero. 4. The composition according to claim 3 wherein the structural units are mixed isophthalate/terephthalate units. 5. The composition according to claim 2 wherein component A consists of structural units of formulas TV and V, p is zero and R" is a C 8- ι 2 straight chain aliphatic radical. 6. The composition according to claim 5 wherein the structural units of formula II are mixed isophthalate/terephthalate units. 7. The composition according to claim 2 wherein component A is a block copolyestercarbonate comprising structural units of the formula each R is a substituent, each R 11 is independently a divalent organic radical, m is at least about 10, n is at least about 4 and p is 0-3. 8. The composition according to claim 7 wherein p is zero and R 1 ' is 2,2- bis(p-phenylene)isopropylidene. 9. The composition according to claim 8 wherein the ester units are mixed isophthalate/terephthalate units. 10. The composition according to claim 1 wherein each of R 1 and R 2 is Q. 4 alkyl and each of R 5 and R 6 is hydrogen. 11. The composition according to claim 10 wherein each of R 1 and R 2 is methyl. 12. The composition according to claim 10 wherein R 1 and R 2 taken together are piperidinyl. 13. The composition according to claim 10 wherein R 3 is COOR 4 . 14. The composition according to claim 13 wherein R 4 is hydrogen. 15. The composition according to claim 13 wherein R 4 is C M alkyl. 16. The composition according to claim 13 wherein R 4 is aryl. 17. The composition according to claim 10 wherein R 3 is CN. 18. The composition according to claim 1 wherein component B is present in the range of about 50-1,000 ppm by weight based on component A. 19. A resinous composition comprising the following and any reaction products thereof: (A) at least one thermoplastic polyester comprising structural units derived from a resorcinol isophthalate/terephthalate, and (B) about 50-1,000 ppm by weight, based on component A, of at least one aminocinnamic compound of the formula wherein: each of R 1 and R 2 is an alkyl radical, or R 1 and R 2 together with the nitrogen atom separating them form a heterocyclic radical; R 3 is COOR 4 , C(O)R 4 , or CN; R 4 is hydrogen, alkyl or aryl; and each of R 5 and R 6 is hydrogen, alkyl, or aryl; or R 5 and R 6 together with the carbon atoms connecting them form an alicyclic radical; said 4-aminocinnamic compound absorbing radiation in the range of about 360-390 nm. 20. A resinous composition comprising the following and any reaction products thereof: (A) at least one thermoplastic polyester comprising structural units derived from a 1 ,3-dihydroxybenzene organodicarboxylate, and (B) at least one 4-aminocinnamic compound of the formula wherein: each of R 1 and R 2 is an alkyl radical, or R 1 and R 2 together with the nitrogen atom separating them form a heterocyclic radical; R 3 is COOR 4 , C(O)R 4 , or CN; R 4 is hydrogen, alkyl or aryl; R 5 is hydrogen, alkyl, or aryl; and each of R 7 and R 8 is hydrogen or an alkyl radical, or R 7 and R 8 together form an alicyclic radical; said 4-aminocinnamic compound absorbing radiation in the range of about 360-390 nm. 21. The composition according to claim 20 wherein component A comprises structural units of the formula wherein each R is a substituent and p is 0-3, optionally in combination with structural units of the formula wherein R 9 and p are as previously defined and R 10 is a divalent C 4 - 12 aliphatic, alicyclic or mixed aliphatic-alicyclic radical. 22. The composition according to claim 21 wherein component A consists of structural units of formula IV and p is zero. 23. The composition according to claim 22 wherein the structural units are mixed isophthalate/terephthalate units. 24. The composition according to claim 21 wherein component A consists of structural units of formulas IV and V, p is zero and R 2 is a Cg_ι 2 straight chain aliphatic radical. 25. The composition according to claim 24 wherein the structural units of formula II are mixed isophthalate/terephthalate units. 26. The composition according to claim 21 wherein component A is a block copolyestercarbonate comprising structural units of the formula each R 9 is a substituent, each R n is independently a divalent organic radical, m is at least about 10, n is at least about 4 and p is 0-3. 27. The composition according to claim 26 wherein p is zero and R 1 ' is 2,2-bis(p-phenylene)isopropylidene. 28. The composition according to claim 27 wherein the ester units are mixed isophthalate/terephthalate units. 29. The composition according to claim 20 wherein each of R and R is C M alkyl and each of R 5 , R 7 , and R 8 is hydrogen. 30. The composition according to claim 29 wherein each of R and R 2 i-s methyl. 31. The composition according to claim 29 wherein R 1 and R 2 taken together are piperidinyl. 32. The composition according to claim 29 wherein R 3 is COOR 4 . 33. The composition according to claim 32 wherein R 4 is hydrogen. 34. The composition according to claim 32 wherein R 4 is C M alkyl. 35. The composition according to claim 32 wherein R 4 is aryl. 36. The composition according to claim 29 wherein R 3 is CN. 37. The composition according to claim 20 wherein component B is present in the range of about 50- 1 ,000 ppm by weight based on component A. 38. A resinous composition comprising the following and any reaction products thereof: (A) at least one thermoplastic polyester comprising structural units derived from a resorcinol isophthalate/terephthalate, and (B) about 50-1,000 ppm by weight, based on component A, of at least one aminocinnamic compound of the formula wherein: each of R 1 and R 2 is an alkyl radical, or R 1 and R 2 together with the nitrogen atom separating them form a heterocyclic radical; R 3 is COOR 4 , C(O)R 4 , or CN; R 4 is hydrogen, alkyl or aryl; R 5 is hydrogen, alkyl, or aryl; and each of R 7 and R 8 is hydrogen or an alkyl radical, or R 7 and R 8 together form an alicyclic radical; said 4-aminocinnamic compound absorbing radiation in the range of about 360-390 nm. 39. A resinous composition comprising the following and any reaction products thereof: (A) at least one thermoplastic polyester comprising structural units derived from a 1,3-dihydroxybenzene organodicarboxylate, and (B) at least one 4-aminocinnamic compound of the formula wherein: each of R 1 and R 2 is an alkyl radical, or R 1 and R 2 together with the nitrogen atom separating them form a heterocyclic radical; each of R 5 and R 6 is hydrogen, alkyl, or aryl; or R 5 and R 6 together with the carbon atoms connecting them form an alicyclic radical; and 7 R 7 ft each of R and R is hydrogen or an alkyl radical, or R and R together form an alicyclic radical; said 4-aminocinnamic compound absorbing radiation in the range of about 360-390 nm. 40. The composition according to claim 39 wherein component A comprises structural units of the formula wherein each R is a substituent and p is 0-3, optionally in combination with structural units of the formula wherein R 9 and p are as previously defined and R 10 is a divalent C 4 .ι 2 aliphatic, alicyclic or mixed aliphatic-alicyclic radical. 41. The composition according to claim 40 wherein component A consists of structural units of formula IV and p is zero. 42. The composition according to claim 41 wherein the structural units are mixed isophthalate/terephthalate units. 43. The composition according to claim 40 wherein component A consists of structural units of formulas IV and V, p is zero and R 2 is a C 8 -ι 2 straight chain aliphatic radical. 44. The composition according to claim 43 wherein the structural units of formula π are mixed isophthalate/terephthalate units. 45. The composition according to claim 40 wherein component A is a block copolyestercarbonate comprising structural units of the formula each R is a substituent, each R 1 ' is independently a divalent organic radical, m is at least about 10, n is at least about 4 and p is 0-3. 46. The composition according to claim 45 wherein p is zero and R 1 ' is 2,2-bis(p-phenylene)isopropylidene. 47. The composition according to claim 46 wherein the ester units are mixed isophthalate/terephthalate units. 48. The composition according to claim 39 wherein each of R 1 and R 2 is C alkyl and each of R 5 , R 6 , R 7 , and R 8 is hydrogen. 49. The composition according to claim 48 wherein each of R 1 and R 2 is methyl. 50. The composition according to claim 48 wherein R 1 and R 2 taken together are piperidinyl. 51. The composition according to claim 1 wherein component B is present in the range of about 50-1,000 ppm by weight based on component A. 52. A resinous composition comprising the following and any reaction products thereof: (A) at least one thermoplastic polyester comprising structural units derived from a resorcinol isophthalate/terephthalate, and (B) about 50-1,000 ppm by weight, based on component A, of at least one aminocinnamic compound of the formula wherein: each of R' and R is an alkyl radical, or R 1 and R z together with the nitrogen atom separating them form a heterocyclic radical; each of R 5 and R 6 is hydrogen, alkyl, or aryl; or R 5 and R 6 together with the carbon atoms connecting them form an alicyclic radical; and each of R and R 8 is hydrogen or an alkyl radical, or R 7 and R 8 together form an alicyclic radical; said 4-aminocinnamic compound absorbing radiation in the range of about 360-390 nm.

Inventors: SHAKHNOVICH ALEXANDER ISAAKOVI, SHAKHNOVICH, ALEXANDER, ISAAKOVICH
Applicants: GEN ELECTRIC, GENERAL ELECTRIC COMPANY
Application year: 2000
Main classification: C08K5
IPC codes: C08G63, C08K5, C08L67, F02B61