Agents for and methods of treating synthetic fibers

Abstract: A composition for treating synthetic fibres comprises a lubricant in an amount of from 65 to 94% by weight of the composition, a non-ionic surfactant in an amount of from 5 to 20% by weight of the composition, and an amphoteric surfactant in an amount of from 0.1 to 5% by weight of the composition, wherein said amphoteric surfactant comprises of one or two compounds selected from the group consisting of carboxybetain-type amphoteric surfactants shown by Formula (1) given below, and amino-acid-type amphoteric surfactants shown by Formula (2) given below: wherein R 1 is an alkanoyl group having from 8 to 22 carbon atoms or an alkenoyl group having from 8 to 22 carbon atoms; R 2 is H or a methyl group; R 3 and R 4 are each independently an alkyl group having from 1 to 4 carbon atoms; R 5 is an alkyl group having from 8 to 22 carbon atoms or an alkenyl group having from 8 to 22 carbon atoms; R 6 , R 7 , R 8 and R 9 are each independently an alkyl group having from 1 to 4 carbon atoms; Y is N or P; and n is an integer of 2 or 3. The composition is useful in a method of treating synthetic fibers, particularly false-twisting and drawing processes, comprising the steps of: causing an agent to be adhered to the synthetic fibers so as to be present in amount of from 0.1 to 3% by weight of spun synthetic fibers; and thereafter simultaneously carrying out drawing and false-twisting processes on said spun synthetic fibers.

Description: Background of the Invention This invention relates to agents for and methods of treating synthetic fibers. False-twisting speeds for synthetic fibers have increased greatly in recent years. Most recently, false-twisting apparatus equipped with a non-contact type heater has come to be used to carry out the false-twisting and drawing processes simultaneously at speeds exceeding 1000m/minute. At such a high yarn speeds, the friction between the running yarn and the guide members, together with static electricity which is generated on the running yarn, and the abrasion of the running yarn against the sludge, can combine to cause abnormal tension variations in the yarn. If such an abnormal tension variation occurs in the running yarn, the false-twisted yarn which is obtained contains unevenness in filament fineness and uneven crystallinity, with dyeing specks appearing as a result. Thus, this invention relates to agents for and methods of treating synthetic fibers, whereby occurrence of abnormal tension variations in running yarn can be prevented even during a false-twisting process at a high speed, such that high-quality false-twisted yarns without having dyeing specks can be obtained. Examples of prior art agents for treating synthetic fibers with which false-twisted yarns with good yarn quality can be obtained even by a high-speed false-twisting process include: (1) those having a polyether compound as principal component (Japanese Patent Publications Tokkai 49-31996, 50-155795, 50-199796, 4-24088 and 8-325949 and U.S. patent 4,044,541); (2) those using a polyether compound together with polyether modified silicone or fluoroalkyl modified polydimethylsiloxane (Japanese Patent Publications Tokkai 60-181368, Tokko 6-21380 and U.S. patent 4,561987); and (3) those using a polyether compound together with an organic salt which comprises organic carboxylic acid anions and quaternary ammonium cations having alkyl group or alkenyl group with 5 or less carbon atoms (Japanese Patent Publication Tokkai 9-111659). However, when such prior art agents are used to carry out drawing and false-twisting processes simultaneously at high speeds of over 1000m/minute and if, in particular, this is performed by using a false-twisting apparatus of a recent type equipped with a non-contact type heater, it is not possible to fully prevent the occurrence of tension variations in the running yarn and false-twisted yarns of a sufficiently high quality cannot be obtained. Summary of the Invention The problem, to which the present invention is addressed, is therefore that prior art agents for treating synthetic fibers cannot fully prevent the occurrence of tension variations in the running yarn in a high-speed false-twisting process and only false-twisted yarns of an inferior quality can be obtained. This invention is based on the present inventors' discovery that the above and other problems can be successfully addressed if use is made of an agent for the treatment of the synthetic fibers containing a lubricant, a non-ionic surfactant and a specified kind of amphoteric surfactant, in a specified ratio, and, in particular, if such an agent for the treatment of the sythetic fibres is adhered in a specific proportion to spun synthetic fibers before they are subjected to simultaneous drawing and false-twisting processes. Detailed Description of the Invention According to the present invention there is provided, in a first aspect, an agent for treating synthetic fibers consisting of a composition comprising a lubricant in an amount of from 65 to 94% by weight of the composition, a non-ionic surfactant in an amount of from 5 to 20% by weight of the composition, and an amphoteric surfactant (of the particular type described below) in an amount of from 0.1 to 5% by weight of the composition. The amphoteric surfactant to be thus contained in an agent of this invention is characterized in that it comprises one or two compounds selected from the group consisting of a first kind of amphoteric surfactants (herein referred to as the "carboxybetain type amphoteric surfactants") shown by Formula (1) given below and a second kind of amphoteric surfactants (herein referred to as the "amino-acid-type amphoteric surfactants") shown by Formula (2) given below: wherein R 1 is an alkanoyl group having from 8 to 22 carbon atoms or an alkenoyl group having from 8 to 22 carbon atoms; R 2 is H or a methyl group; R 3 and R 4 are each independently an alkyl group having from 1 to 4 carbon atoms; R 5 is an alkyl group having from 8 to 22 carbon atoms or an alkenyl group having from 8 to 22 carbon atoms; R 6 , R 7 , R 8 and R 9 are each independently an alkyl group having from 1 to 4 carbon atoms; Y is N or P; and n is an integer of 2 or 3. According to a second aspect of the present invention, there is provided a method of treating synthetic fibers, characterized in that it comprises the steps of causing an agent as described above to be adhered to synthetic fibers after they have been spun in an amount of from 0.1 to 3% by weight of the spun synthetic fibres, and thereafter carrying out drawing and false-twisting processes simultaneously. Examples of a lubricant which may be contained in an agent according to the present invention include (1) polyethers; (2) fatty esters; (3) aromatic esters; (4) (poly)ether-esters; and (5) mineral oils. Examples of the aforementioned polyethers include polyether monools having a polyoxyalkylene group in the molecule, polyether diols and polyether triols. Among these, polyethers obtained by random or block addition of an alkylene oxide having from 2 to 4 carbon atoms to monohydric, dihydric, or trihydric hydroxy compounds are preferred. Particularly preferred are mixtures of such polyethers containing polyethers with a number average molecular weight of from 1000 to 2000 in an amount of from 10 to 40% by weight of the mixture, polyethers with a number average molecular weight of from 2100 to 3000 in an amount of from 40 to 60% by weight of the mixture, and polyethers with a number average molecular weight of from 3100 to 7000 in an amount of from 10 to 30% by weight of the mixture. Examples of the aforementioned fatty esters include (1) esters of a fatty monohydric alcohol and a fatty monocarboxylic acid, such as butyl stearate, octyl stearate, oleyl laurate, oleyl oleate and isopentaeicosanyl isostearate; (2) esters of a fatty polyhydric alcohol and a fatty monocarboxylic acid, such as 1,6-hexanediol didodecanoate and trimethylol propane monooleate monolaurate; and (3) esters of a fatty monohydric alcohol and a fatty polycarboxylic acid, such as dilauryl adipate and dioleyl azelate. Particularly preferred are esters of a fatty monohydric alcohol and a fatty monocarboxylic acid and esters of a fatty polyhydric alcohol and a fatty monocarboxylic acid, with a total of from 15 to 50 carbon atoms. Examples of the aforementioned aromatic esters include (1) esters of an aromatic alcohol and a fatty monocarboxylic acid, such as benzyl stearate and benzyl laurate; and (2) esters of a fatty monohydric alcohol and an aromatic carboxylic acid such as diisostearyl isophthalate and trioctyl trimellitate. Particularly preferred are esters of a fatty monohydric alcohol and an aromatic carboxylic acid, with a total of from 15 to 50 carbon atoms. The aforementioned (poly)ether-esters are essentially those obtainable by introducing a (poly)ether part into a fatty ester or aromatic ester of the kind described above. Examples of such (poly)ether-esters include (1) (poly)ether-esters with from 1 to 3 ester groups in the molecule obtained by esterifying a (poly)ether obtained by adding an alkylene oxide with from 2 to 4 carbon atoms to a fatty monohydric, dihydric, or trihydric alcohol with from 4 to 26 carbon atoms with a fatty carboxylic acid with from 4 to 26 carbon atoms; (2) (poly)ether-esters with from 1 to 3 ester groups in the molecule obtained by esterifying a (poly)ether obtained by adding an alkylene oxide with from 2 to 4 carbon atoms to an aromatic monohydric, dihydric, or trihydric alcohol with a fatty carboxylic acid with from 4 to 26 carbon atoms; and (3) (poly)ether-esters with from 1 to 3 ester groups in the molecule obtained by esterifying a (poly)ether obtained by adding an alkylene oxide with from 2 to 4 carbon atoms to a fatty alcohol with from 4 to 26 carbon atoms with an aromatic carboxylic acid. As for mineral oils, many kinds with different viscosity values can be used, but those with a viscosity of from 1 x 10 -6 to 1 x 10 -2 m 2 /s at 30°C, and a paraffin component ratio of over 60 weight %, are preferred. Examples of such preferred kinds of mineral oil include fluid paraffin oils. Among the agents according to the present invention, those using polyethers or a mixture of polyethers and (poly)ether-esters as the lubricant are preferred. Examples of non-ionic surfactants to be used in the compositions according to the present invention include: (1) non-ionic surfactants having a polyoxyalkylene group in the molecule, such as polyoxyalkylene alkylethers, polyoxyalkylene alkylphenylethers, polyoxyalkylene alkylesters, polyoxyalkylene caster oil and polyoxyalkylene alkylaminoethers; (2) non-ionic surfactants which are a partial ester of a fatty acid and a polyhydric alcohol, such as sorbitan monolaurate, sorbitan trioleate, glycerine monolaurate and diglycerine dilaurate; and (3) non-ionic surfactants which are an ester of a polyoxyalkylene polyhydric alcohol and a fatty acid, such as those obtained by adding an alkylene oxide to a partial ester of a trihydric, tetrahydric, pentahydric, or hexahydric alcohol and a fatty acid; partial and complete esters of a trihydric, tetrahydric, pentahydric, or hexahydric alcohol with an alkylene oxide added and a fatty acid; and those obtained by adding an alkylene oxide to an ester of a trihydric, tetrahydric, pentahydric, or hexahydric alcohol and a hydroxy fatty acid. Preferred among these are polyoxyethylene alkylethers, wherein the oxyethylene group repeating number is from 3 to 15, and wherein the alkyl group has from 8 to 18 carbon atoms. Particularly preferred are those wherein the oxyethylene group repeating number is from 4 to 14, and wherein the alkyl group has from 10 to 16 carbon atoms. The amphoteric surfactant to be used in the compositions according to the present invention is characterized, as explained above, in that it contains one or two compounds selected from the group consisting of carboxybetain-type amphoteric surfactants shown by Formula (1) given above and amino-acid-type amphoteric surfactants shown by Formula (2) given above. R 1 in Formula (1) may be: (1) an alkanoyl group with from 8 to 22 carbons atoms, such as octanoyl group, nonanoyl group, decanoyl group, hexadecanoyl group, octadecanoyl group, nonadecanoyl group, icosanoyl group, henicosanoyl group and docosanoyl group; or (2) an alkenoyl group with from 8 to 22 carbon atoms, such as hexadecenoyl group, icosenoyl group and octadecenoyl group. Among these, however, alkanoyl groups with from 12 to 18 carbon atoms are preferred. R 2 may be hydrogen or methyl group, but hydrogen is preferred. R 3 and R 4 are each independently an alkyl group with from 1 to 4 carbon atoms, such as methyl group, ethyl group, propyl group and butyl group. Among these, however, methyl group is preferred. Regarding Formula (2) given above, R 5 may be: (1) an alkyl group with from 8 to 22 carbon atoms, such as octyl group, nonyl group, decyl group, hexadecyl group, octadecyl group, nonadecyl group, icosyl group, henicosyl group and docosyl group; or (2) an alkenyl group with from 8 to 22 carbon atoms, such as hexadecenyl group, eicocenyl group and octadecenyl group. Among these, however, alkyl groups with from 12 to 18 carbon atoms are preferred. The cationic group including Y + of Formula (2) may be: (1) a quaternary phosphonium cationic group if Y is P, or (2) a quaternary ammonium cationic group if Y is N. Examples of quaternary phosphonium cationic groups include those wherein R 6 , R 7 , R 8 and R 9 in Formula (2) are each independently an alkyl group with from 1 to 4 carbon atoms, such as tetramethyl phosphonium, triethylmethyl phosphonium, tripropylethyl phosphonium, tributylmethyl phosphonium and tetrabutyl phosphonium. Among these, however, tetramethyl phosphonium is preferred. Examples of quaternary ammonium cationic groups include those wherein R 6 , R 7 , R 8 and R 9 in Formula (2) are each independently an alkyl group with from 1 to 4 carbon atoms, such as tetramethyl ammonium, triethylmethyl ammonium, tripropylethyl ammonium, tributylmethyl ammonium and tetrabutyl ammonium. The carboxybetain-type amphoteric surfactants shown by Formula (1) given above can be obtained by known methods of synthesis such as are described in U.S. patent 2,082,275, and the amino acid type amphoteric surfactants shown by Formula (2) given above can also be obtained by known methods of synthesis such as are described in U.S. patent 2,213,979. As explained above, the compositions according to the present invention for treating synthetic fibers are characterized in that they contain a lubricant in an amount of from 65 to 94% by weight of the composition, a non-ionic surfactant in an amount of from 5 to 20% by weight of the composition, and an amphoteric surfactant as described above in an amount of from 0.1 to 5% by weight of the composition. However, compositions containing the amphoteric surfactant in an amount of from 0.5 to 1.5% by weight of the composition are preferred. Compositions containing these three components in a total amount of 90% or more by weight of the composition are preferred, and those containing them in a total amount of 95% or more by weight of the composition are most preferred. The agents of the present invention may further contain an antioxidant. Examples of antioxidants which may be contained include: triethylene glycol-bis(3-(3-t-butyl-5-methyl-4-hydroxyphenyl) propionate), 1,6-hexanediol-bis(3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate), 2,4-bis-(n-octylthio)-6-(4-hydroxy-3,5-di-t-butylanilino)-1,3,5-triazine, pentaerythrityl-tetrakis(3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate), 2,2-thiodiethylene bis(3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate), octadecyl-3-(3,5-di-t-butyl-4-hydroxyphenyl) propionate, 2,2-thiobis(4-methyl-6-t-butylphenol), 3,5-di-t-butyl-4-hydroxybenzyl phosphonate-diethylester, 1,3,5-tris(4-t-butyl-3-hydroxy-2,6-dimethyl) isocyanic acid, and tris(3,5-di-t-butyl-4-hydroxybenzyl) isocyanate. Among these, 1,3,5-tris(4-t-butyl-3-hydroxy-2,6-dimethyl) isocyanic acid and tris(3,5-di-t-butyl-4-hydroxybenzyl) isocyanate are preferred. Such antioxidants may be contained in the composition in an amount of from 0.1 to 3% by weight of the composition. The agents of the present invention may further contain a polyether modified silicone. Examples of such polyether modified silicones include those having a polydimethyl siloxane chain with average molecular weight of from 1500 to 3000 as the main chain and a polyoxylalkylene chain with average molecular weight of from 700 to 5000 as a side chain, but those having a polydimethyl siloxane chain with average molecular weight of from 2000 to 2500 as the main chain and a polyoxylalkylene chain with average molecular weight of from 1500 to 3000 as a side chain are preferred. Such polyether modified silicones may be contained in the composition in an amount of from 0.1 to 2.5% by weight of the composition. The agents of the present invention may still further contain one or more compounds selected from the group consisting of salts of half-esters of a dibasic organic acid and a long-chain alcohol and salts of long-chain alkyl or alkenyl phosphoric acids. Examples of such salts of half-esters of a dibasic organic acid and a long-chain alcohol include those wherein the long-chain alcohol is an alkyl alcohol with from 8 to 22 carbon atoms and those wherein the long-chain alcohol is an alkenyl alcohol with from 8 to 22 carbon atoms. Examples of such salts of long-chain alkyl or alkenyl phosphoric acids include those having an alkyl group with from 8 to 22 carbon atoms and those having an alkenyl group with from 8 to 22 carbon atoms. Among these, alkali metal salts of half-esters of a dibasic organic acid and an alkenyl alcohol having from 12 to 18 carbons atoms, organic amine salts of half-esters of a dibasic organic acid and an alkenyl alcohol having from 12 to 18 carbons atoms, alkali metal salts of alkenyl phosphoric acids wherein the alkenyl group has from 12 to 18 carbons atoms, and organic amine salts of alkenyl phosphoric acids wherein the alkenyl group has from 12 to 18 carbons atoms are preferred. These compounds, or mixtures thereof, may be contained in the composition in an amount of from 0.1 to 1% by weight of the composition. The agents according to the present invention may be applied to synthetic fibers in known ways, for example, as a neat oil, as a solution in an organic solvent, or as an aqueous solution. It may be applied during the spinning process or during a process whereby drawing and spinning are carried out simultaneously. Methods of application include such conventional methods as the roller oiling method, the guide oiling method with a measuring pump, the immersion oiling method and the spray oiling method. The agents according to the present invention are effective when applied as an aqueous solution to synthetic fibers in an amount of from 0.1 to 3 weight % of the composition to the synthetic fibers, and the synthetic fibers are then subjected to a false twisting process simultaneously with the drawing process at a high speed. They are effective particularly if the simultaneous drawing and false-twisting processes are carried out at a high speed by using a false-twisting apparatus equipped with a non-contact type beater. During such a high-speed false-twisting process, the agents according to the present invention can prevent the occurrence of abnormal tension variations in the running fibers, and hence false-twisted yarns with a high yarn quality without dyeing specks can be obtained. The kinds of synthetic fibers to which the agents according to the present invention can be applied include polyester fibers, polyamide fibers, polyacryl fibers, polyolefin fibers and polyurethane fibers, but the agents according to the present invention are particularly effective when applied to polyester fibers or polyamide fibers. The invention is described next in terms of the following seven particular Examples. These Examples are intended to illustrate, and in no way to limit, the scope of the invention. Example 1: A composition containing lubricant (L-1) in an amount of 75 weight %, lubricant (L-3) in an amount of 10 weight %, non-ionic surfactant (D-1) in an amount of 10 weight %, amphoteric surfactant (AD-1) in an amount of 0.5 weight %, antioxidant (A-1) in an amount of 0.5 weight %, polyether modified silicone (S-1) in an amount of 1 weight %, potassium lauryl succinate (LA-1) in an amount of 0.5 weight %, diethanol amine lauryl phosphate (LP-1) in an amount of 0.5 weight %, and ethylene glycol in an amount of 2 weight %; where lubricant (L-1) is a mixture of (1) a polyether monool with number average molecular weight 1500 obtained by block addition of ethylene oxide and propylene oxide to methyl alcohol, (2) a polyether monool with number average molecular weight 2300 obtained by block addition of ethylene oxide and propylene oxide to methyl alcohol, and (3) a polyether triol with number average molecular weight 5000 obtained by block addition of ethylene oxide and propylene oxide to glycerine, in a weight ratio of (1)/(2)/(3) = 19/58/23; lubricant (L-3) is octyloxy polyethoxy (ethoxy unit repeating number of 6) ethyl decanate; non-ionic surfactant (D-1) is a mixture of (1) a polyoxyethylene alkylether having a polyoxyethylene group with oxyethylene unit repeating number of 5 and having alkyl groups with 13 carbon atoms and (2) a polyoxyethylene alkylether having a polyoxyethylene group with oxyethylene unit repeating number of 10 and having alkyl groups with 14 carbon atoms, in a weight ratio of (1)/(2) = 50/50; amphoteric surfactant (AD-1) is a carboxybetain-type amphoteric surfactant of Formula (1) wherein R 1 is a stearoyl group, R 2 is hydrogen, R 3 and R 4 are each a methyl group, and n = 3; antioxidant (A-1) is 1,3,5-tris(4-t-butyl-3-hydroxy-2,6-dimethyl) isocyanic acid; and polyether modified silicone (S-1) is one having a polydimethyl siloxane chain with average molecular weight 2500 as the main chain and a polyoxyethylene chain with average molecular weight 1500 as the side chain. Example 2: A composition containing lubricant (L-2) in an amount of 75 weight %, lubricant (L-4) in an amount of 15 weight %, non-ionic surfactant (D-2) in an amount of 7 weight %, amphoteric surfactant (AD-2) in an amount of 1 weight %, the aforementioned antioxidant (A-1) in an amount of 0.5 weight %, the aforementioned polyether modified silicone (S-1) in an amount of 1 weight %, and sodium dodecenyl succinate (LA-2) in an amount of 0.5 weight %; where lubricant (L-2) is a mixture of (1) a polyether monool with number average molecular weight 1500 obtained by random addition of ethylene oxide and propylene oxide to methyl alcohol, (2) a polyether monool with number average molecular weight 2300 obtained by random addition of ethylene oxide and propylene oxide to methyl alcohol, and (3) a polyether triol with number average molecular weight 5000 obtained by random addition of ethylene oxide and propylene oxide to glycerine, in a weight ratio of (1)/(2)/(3) = 35/47/18; lubricant (L-4) is dilauryl polyethoxy (ethoxy unit repeating number of 3) ethyl adipate; non-ionic surfactant (D-2) is a mixture of (1) a polyoxyethylene alkylether having a polyoxyethylene group with oxyethylene unit repeating number of 5 and having alkyl groups with 13 carbon atoms and (2) a polyoxyethylene alkylether having a polyoxyethylene group with oxyethylene unit repeating number of 10 and having alkyl groups with 14 carbon atoms, in a weight ratio of (1)/(2) = 70/30; and amphoteric surfactant (AD-2) is a carboxybetain-type amphoteric surfactant of Formula (1) wherein R 1 is palmitoyl group, R 2 is hydrogen, R 3 and R 4 are each a methyl group, and n = 3. Example 3: A composition containing the aforementioned lubricant (L-1) in an amount of 65 weight %, the aforementioned lubricant (L-4) in an amount of 15 weight %, the aforementioned non-ionic surfactant (D-1) in an amount of 15 weight %, amphoteric surfactant (AM-1) in an amount of 1 weight %, the aforementioned antioxidant (A-1) in an amount of 0.5 weight %, polyether modified silicone (S-2) in an amount of 1 weight %, diethanol amine lauryl phosphate (LP-1) in an amount of 0.5 weight %, and diethylene glycol in an amount of 2 weight %; where amphoteric surfactant (AM-1) is an amino-acid-type amphoteric surfactant of Formula (2) wherein R 5 is a stearyl group, Y is P, and R 6 - R 9 are each a methyl group; and polyether modified silicone (S-2) is one having a polydimethyl siloxane chain with average molecular weight 2000 as the main chain and a polyoxyethylene chain with average molecular weight 3000 as the side chain. Example 4: A composition containing the aforementioned lubricant (L-2) in an amount of 70 weight %, the aforementioned lubricant (L-3) in an amount of 10 weight %, the aforementioned non-ionic surfactant (D-1) in an amount of 14.5 weight %, amphoteric surfactant (AD-3) in an amount of 1 weight %, the aforementioned antioxidant (A-1) in an amount of 0.5 weight %, the aforementioned polyether modified silicone (S-1) in an amount of 1 weight %, potassium dodecenyl succinate (LA-1) in an amount of 0.5 weight %, diethanol amine lauryl phosphate (LP-1) in an amount of 0.5 weight %, and ethylene glycol in an amount of 2 weight %; where amphoteric surfactant (AD-3) is a carboxybetain-type amphoteric surfactant of Formula (1) wherein R 1 is a lauroyl group, R 2 is hydrogen, R 3 and R 4 are each a methyl group, and n = 3. Example 5: A composition containing the aforementioned lubricant (L-1) in an amount of 80 weight %, the aforementioned non-ionic surfactant (D-1) in an amount of 17 weight %, amphoteric surfactant (AM-2) in an amount of 1 weight %, the aforementioned antioxidant (A-1) in an amount of 0.5 weight %, the aforementioned polyether modified silicone (S-1) in an amount of 1 weight %, and sodium dodecenyl succinate (LA-2) in an amount of 0.5 weight %; where amphoteric surfactant (AM-2) is an amino-acid-type amphoteric surfactant of Formula (2) wherein R 5 is a lauryl group, Y is P, and R 6 - R 9 are each a butyl group. Example 6: A composition containing the aforementioned lubricant (L-2) in an amount of 75 weight %, the aforementioned non-ionic surfactant (D-2) in an amount of 19.5 weight %, amphoteric surfactant (AM-4) in an amount of 1.5 weight %, the aforementioned antioxidant (A-1) in an amount of 0.5 weight %, the aforementioned polyether modified silicone (S-2) in an amount of 1 weight %, diethanol amine lauryl phosphate (LP-1) in an amount of 0.5 weight %, and diethylene glycol in an amount of 2 weight %; where amphoteric surfactant (AM-4) is an amino-acid-type amphoteric surfactant of Formula (2) wherein R 5 is a stearyl group, Y is N, and R 6 - R 9 are each a methyl group. Example 7: A composition containing the aforementioned lubricant (L-1) in an amount of 85 weight %, the aforementioned non-ionic surfactant (D-2) in an amount of 9 weight %, amphoteric surfactant (AM-5) in an amount of 1.5 weight %, the aforementioned antioxidant (A-1) in an amount of 0.5 weight %, the aforementioned polyether modified silicone (S-1) in an amount of 1 weight %, potassium dodecenyl succinate (LA-1) in an amount of 0.5 weight %, diethanol amine lauryl phosphate (LP-1) in an amount of 0.5 weight %, and ethylene glycol in an amount of 2 weight %; where amphoteric surfactant (AM-5) is an amino-acid-type amphoteric surfactant of Formula (2) wherein R 5 is a lauryl group, Y is N, and R 6 - R 9 are each a methyl group. The method of treating synthetic fibers according to the present invention will now be further described by way of the following Example 8: Example 8 This Example illustrates a method of preparing an aqueous solution of one of the compositions described above in Examples 1-7, causing this aqueous solution to be adhered to spun synthetic polyester fibers so as to be present in an amount of 0.5% by weight of the spun polyester fibres, and thereafter subjecting the fibers simultaneously to drawing and false-twisting processes by means of a false-twisting apparatus equipped with a non-contact type heater, at a fiber speed of 1000m/minute. Next, the invention will be further described by way of test examples but it is stressed that these test examples are not intended to limit in any way the scope of the invention. In what follows, "parts" will mean "parts by weight" and "%" will mean "weight %". Part 1: Preparation of agents for treating synthetic fibers Test examples ("Test") and Comparative examples ("Comp.") of compositions for treating synthesis fibers were produced. The kinds of amphoteric surfactants used are shown in Tables 1 and 2 with reference to Formulas (1) and (2), and the compositions of the Test and Comparative examples which were employed are summarized in Table 3. The symbols used in Table 3, not having been explained above, are as follows: L-5: Octyl isostearate; L-6: Fluid paraffin oil with viscosity 2 x 10 -5 m 2 /s at 30°C D-3: Mixture of (1) a polyoxyethylene alkylether having a polyoxyethylene group with oxyethylene unit repeating number of 7 and having alkyl groups with 12 carbon atoms and (2) a polyoxyethylene branched alkylether having a polyoxyethylene group with oxyethylene unit repeating number of 12 and having branched alkyl groups with 18 carbon atoms, in a weight ratio of (1)/(2) = 50/50; MX-1: Mixture of A-1, S-1, LA-1, LP-1 and AU-1 in a weight ratio of 0.5/1/0.5/0.5/2; MX-2: Mixture of A-1, S-1 and LA-2 in a weight ratio of 0.5/1/0.5; MX-3: Mixture of A-1, S-2, LP-1 and AU-2 in a weight ratio of 0.5/1/0.5/0.5/2; MX-4: Mixture of A-1 and S-1 in a weight ratio of 0.5/0.5; S-2: Polyether modified silicone having a polydimethyl siloxane chain with average molecular weight 2000 as the main chain and a polyoxyethylene chain with average molecular weight 3000 as the side chain; LP-2: Dibutylethanol amine isostearyl phosphate; AU-1: Ethylene glycol; AU-2: Diethylene glycol; and aa-1: Tetraethyl ammonium lactate. Kind R 1 R 2 R 3 R 4 n AD-1 stearoyl group hydrogen methyl group methyl group 3 AD-2 palmitoyl group hydrogen methyl group methyl group 3 AD-3 lauroyl group hydrogen methyl group methyl group 3 AD-4 oleoyl group methyl group methyl group methyl group 2 ad-1 hexanoyl group hydrogen methyl group methyl group 3 ad-2 lauryl group methyl group methyl group methyl group 3 Kind R 5 (group) Y R 6 (group) R 7 (group) R 8 (group) R 9 (group) AM-1 stearyl P methyl methyl methyl methyl AM-2 lauryl P butyl butyl butyl butyl AM-3 oleyl P butyl butyl butyl butyl AM-4 stearyl N methyl methyl methyl methyl AM-5 lauryl N ethyl ethyl ethyl ethyl AM-6 oleyl N ethyl ethyl ethyl ethyl am-1 hexyl P methyl methyl methyl methyl am-2 hexyl N methyl methyl methyl methyl No. Agent Comparison Amt Evaluation L NIS AS Others *1 *2 kind/ ratio kind/ ratio kind/ ratio kind/ ratio Test. 1 L-1/75 D-1/10 AD-1/0.5 MX-1/4.5 0.5 AAA AAA L-3/10 2 L-2/75 D-2/7 AD-2/1 MX-2/2 0.5 AAA AAA L-4/15 3 L-1/65 D-1/15 AM-1/1 MX-3/4 0.3 AAA AAA L-4/15 4 L-2/70 D-1/14.5 AD-3/1 MX-1/4.5 0.5 AAA AAA L-3/10 5 L-1/80 D-1/17 AM-2/1 MX-2/2 0.7 AAA AAA 6 L-2/75 D-2/19.5 AM-4/1.5 MX-3/4 0.5 AAA AAA 7 L-1/85 D-2/9 AM-5/1.5 MX-1/4.5 0.5 AAA AAA 8 L-1/80 D-1/15.5 AD-1/0-5 MX-4/4 0.5 AA AA 9 L-2/85 D-2/11 AM-1/1-5 A-1/2.5 0.5 AA AA 10 L-1/60 D-2/13.5 AD-1/1.5 A-2/1 0.5 AA AA L-3/25 11 L-1/85 D-1/14.5 AD-4/0.5 0.3 A A 12 L-2/60 D-2/10.5 AM-3/1.5 0.7 A A L-3/28 13 L-5/80 D-3/19 AM-6/1 0.4 A A 14 L-6/80 D-2/19 AD-4/1 0.6 A A Comp. 1 L-1/98 D-1/1.5 AM-1/0.5 0.5 C C 2 L-1/60 D-1/38 AM-1/2 0.5 B B 3 L-1/80 D-1/19.95 AM-1/0.05 0.5 C C 4 L-1/80 D-1/13 AM-1/7 0.5 C C 5 L-1/94 D-1/3 AM-1/3 0.5 B B 6 L-1/74 D-1/25 AM-1/1 0.5 B B 7 L-1/80 D-1/18.5 ad-1/1.5 0.5 C C 8 L-1/80 D-1/18.5 ad-2/1.5 0.5 B B 9 L-1/80 D-1/18.5 am-1/1.5 0.5 C C 10 L-1/80 D-1/18.5 am-2/1.5 0.5 C C 11 L-1/80 D-1/18.5 aa-1/1.5 0.5 B B 12 L-1/80 D-1/16 MX-4/4 0.5 B B where L: Lubricant NIS: Non-ionic surfactant AS: Amphoteric surfactant ratio: % contained in composition Amt: Amount of composition in % added to synthetic fibers Evaluation * 1: Abnormal tension variation Evaluation *2: Dyeing specks Part 2: Adhered Amount of Agent, False-Twisting and Evaluation Adhesion of agent onto Synthetic fibers Each of the compositions as described in Part 1 was uniformly mixed with water to produce a 10% aqueous solution. After polyethylene terephthalate chips with intrinsic viscosity 0.64 and containing titanium oxide in an amount of 0.2% by weight were dried by a known method, an extruder was used for spinning at 295°C. Each of the prepared 10% aqueous solutions was applied by a guide oiling method with a measuring pump to the running fibers after they were extruded, cooled and solidified such that the adhered amount (as the agent) became as shown in Table 3. The fibers thus processed were then cohered and wound up at a speed of 4000m/minute without mechanical drawing to obtain partially oriented yarn (POY) of 76.9Nm (13tex)-36 filaments in the form of a plurality of 10kg wound cakes. False twisting process bv a false-twisting apparatus with a high-temperature short heater Each of the cakes thus obtained was subjected to a false-twisting process by using a false-twisting apparatus (Model HTS-1500 produced by Teijin Seiki Co., Ltd.) under the following conditions: Yarn speed = 1 000m/minute Drawing ratio = 1.685 Twist method = friction with 9mm polyurethane disk First heater: Length = 1m Entrance temperature = 420°C Exit temperature = 330°C Second heater = None Target twist number = 3300 Twists per minute. Evaluation of abnormal tension variations An on-line tensor (Model OLT produced by Temeo) was set immediately downstream of the twisting section of the aforementioned false-twisting apparatus with a high-temperature short heater to record the variations in the tension of the running yarns. An average value of tension variations was obtained corresponding to 1 ton of POY obtained as the aforementioned 10kg wound cakes, and abnormal tension variations were evaluated according to the standard given below in terms of the number of occurrences of abnormal tension variations relative to this average value. AAA: No abnormal tension variations greater than the average value ±10% AA: Abnormal tension variations with magnitude equal to the average value ±10% - ±30% occurring once or twice A: Abnormal tension variations with magnitude equal to the average value ±10% - ±30% occurring 3 to 4 times B: Abnormal tension variations with magnitude equal to the average value ±10% - ±30% occurring over 5 times C: occurrence of abnormal tension variations greater than the average value ±30% Evaluation of dyeing specks A circular knitting machine was used to produce knit fabrics with diameter 70mm and length 1.2mm from the same false-twisted yarns on which the abnormal tension variations were measured. The fabrics thus produced were dyed with a disperse dye (Model Kayalon polyester blue EBL-E produced by Nippon Kayaku Co., Ltd.) by the high-pressure dyeing method. The dyed fabrics were washed with water, subjected to a reduction cleaning process and dried according to a known routine. They were thereafter set on an iron cylinder of diameter 70mm and length 1m, and the number of deeply dyed parts on the fabric surfaces were visually counted. The results of the counting were evaluated according to the following standard: AAA: No deeply dyed parts AA: 1-2 deeply dyed parts A: 3-6 deeply dyed parts B: 7-12 deeply dyed parts C: Over 13 deeply dyed parts Table 3 clearly shows that the present invention makes it possible to provide false-twisted yarns with a high quality capable of preventing occurrence of abnormal tension variations not only during a high-speed false-twisting process but also when drawing and false-twisting processes are carried out simultaneously at a high speed by using a false-twisting apparatus equipped with a non-contact type heater.

Claims: A composition for treating synthetic fibres, said composition comprising a lubricant in an amount of from 65 to 94% by weight of the composition, a non-ionic surfactant in an amount of from 5 to 20% by weight of the composition, and an amphoteric surfactant in an amount of from 0.1 to 5% by weight of the composition, wherein said amphoteric surfactant comprises of one or two compounds selected from the group consisting of carboxybetain-type amphoteric surfactants shown by Formula (1) given below, and amino-acid-type amphoteric surfactants shown by Formula (2) given below: wherein R 1 is an alkanoyl group having from 8 to 22 carbon atoms or an alkenoyl group having from 8 to 22 carbon atoms; R 2 is H or a methyl group; R 3 and R 4 are each independently an alkyl group having from 1 to 4 carbon atoms; R 5 is an alkyl group having from 8 to 22 carbon atoms or an alkenyl group having from 8 to 22 carbon atoms; R 6 , R 7 , R 8 and R 9 are each independently an alkyl group having from 1 to 4 carbon atoms; Y is N or P; and n is an integer of 2 or 3. A composition according to claim 1, wherein R 1 is an alkanoyl group having from 12 to 18 carbon atoms, R 2 is H, R 3 and R 4 are each a methyl group, and R 5 is an alkyl group having from 12 to 18 carbon atoms. A composition according to claim 1 or claim 2, wherein said lubricant comprises of a mixture of polyethers, optionally together with a (poly)ether-ester, said mixture of polyethers containing polyethers with a number average molecular weight of from 1000 to 2000 in an amount of from 10 to 40% by weight of the mixture, polyethers with a number average molecular weight of from 2100 to 3000 in an amount of from 40 to 60% by weight of the mixture, and polyethers with a number average molecular weight of from 3100 to 7000 in an amount of from 10 to 30% by weight of the mixture. A composition according to any of claims 1 to 3, wherein said non-ionic surfactant is a polyoxyethylene alkylether, wherein the oxyethylene group repeating number is from 3 to 15, and wherein the alkyl group has from 8 to 18 carbon atoms. A composition according to any of claims 1 to 4, further comprising an antioxidant in an amount of from 0.1 to 3% by weight of the composition, a polyether modified silicone in an amount of from 0.1 to 2.5% by weight of the composition, and one or more compounds selected from the group consisting of fatty dibasic acid salts and fatty phosphoric acid salts in an amount of from 0.1 to 1% by weight of the composition. A method of treating synthetic fibers comprising the steps of: causing an agent to be adhered to the synthetic fibers so as to be present in amount of from 0.1 to 3% by weight of spun synthetic fibers; and thereafter simultaneously carrying out drawing and false-twisting processes on said spun synthetic fibers; wherein said agent is a composition according to any of claims 1 to 5. A method according to claim 6, wherein said drawing and false-twisting processes are simultaneously carried out by using a false-twisting apparatus equipped with a non-contact type heater.

Inventors: KIMURA FUMIHIKO, NAGAI YUKIKO, NAGAYA MASAHIRO, SAKURABA SHIGEHIKO, KIMURA, FUMIHIKO, NAGAI, YUKIKO, NAGAYA, MASAHIRO, SAKURABA, SHIGEHIKO
Applicants: TAKEMOTO OIL & FAT CO LTD, TAKEMOTO YUSHI KABUSHIKI KAISHA
Application year: 2000
Main classification: D06M13
IPC codes: C11D3, C10M133, D02G1, D06M11, D06M13, C11D1, D06M15, C10M107, D06M101, C10N40, C10N20