COTTON FABRIC WITH DURABLE PROPERTIES

Abstract: The present invention relates to compositions and a process which utilizes said compositions for providing cellulosic fabric and cellulosic fabric blends with durable press, said process comprising the steps of contacting fabric with a composition comprising: a) from about 0.1 % to about 20 % by weight, of a cellulose modifying compound having formula (I) wherein R is a backbone linking unit; each R<1> is independently i) a cellulose reactive moiety; ii) a polysaccharide unit; iii) s-triazine units having formula (II); iv) pyrimidine units having formula (III); v) cyclotriphosphazene units having formula (IV); vi) and mixtures thereof; wherein R<2> is hydrogen, C1-C4 alkyl, or R<1>; X is -N-, -CH-, or mixtures thereof; the index m is from 0 to 5, the index n is from 0 to 5; b) from about 0.01 % to about 10 % by weight, of a crosslinking catalyst; and c) the balance carriers and other adjunct ingredients. The compositions of the present invention can take the form of laundry detergent compositions, fabric post-laundry spray-on compositions, and the like.

Description: COTTON FABRIC WITH DURABLE PROPERTIES FIELD OF THE INVENTION The present mvention relates to a method providmg cellulosic fabπc, inter alia, cotton with a durable press finish The present mvention further relates to compositions for use in the present process as well as cellulose fabric modif ing compounds which provide a durable press finish BACKGROUND OF THE INVENTION Garments have been comprised of cotton fiber since antiquity and cotton contmues to be a fabπc of choice for many reasons Cotton, a wholly natural fiber, is compπsed of crosslinked cellulose the surface of which comprises an abundance of hydroxyl umts which are chemically reactive In fact, one negative against cotton fabπc is the ability of materials which compπse stains to react with the cotton fabπc rather than just become absorbed thereto Cotton fabric is modified both in the mill and after it is formed into garments to contain one or more "finishes", inter aha, optical bπghteners, permanent press treatment The consumer can readily delineate between a new garment which still exhibits the "fullness' and "cπspness" in texture which has been applied by the manufacturer and an article of clothing which has been laundered several times and has now lost the "new" feel and appearance Typically, cotton clothing which is treated with anti-wnnkhng agents or "stay-press" agents lose their fabnc finish after several washes or in the case where fabric is chemically modified, the permanent press finish is greatly reduced over time due to mechanical wear and laundermg Ironing, especially ironing with additives, inter aha, starch, is one means by which the consumer attempts to re-new the cnspness and fullness of new cotton fabnc, however, starch must be re-apphed after each wash Post laundry treatments such as ironing mvolve a considerable amount of labor and, therefore, articles of clothing which would desirably have a "pressed" finish are not treated due to the extra work involved However, the consumer does not desire every article of clothing to have a permanent press finish or feel Therefore, a laundry composition which affords all cotton compnsing fabric with a permanent press finish would force the consumer to use two products, one which provides a permanent press benefit and one which does not There is a need in the art for a composition applied to fabric, inter aha, laundry detergent compositions, post laundry spray-on compositions, which provide a permanent press benefit to cotton fabnc, mcludmg cotton blends, which can be exercised by the consumer SUMMARY OF THE INVENTION The present mvention meets the aforementioned needs in that it has been surpnsingly discovered that certain multifunctional cellulosic crosslinkmg agents which provide a permanent press benefit to clothmg can be applied to cotton and cotton-like fabπc duπng the laundry wash or rinse cycle wherem the crosslinkmg, and therefore the permanent press benefit, is selectively executed by the consumer after the laundry cycle has concluded The crosslinkmg can be mitiated by any means desired by the formulator, preferably by applying heat to the cotton garment, by ironing, inter aha The compositions of the present invention compπse a post laundry permanent press system, said system compπsmg one or more multifunctional tπazmes, tπazme ohgomers. pyπmidmes, pyπnudme ohgomers, cyclotnphosphazenes, cyclotnphosphazene ohgomers, or mixtures there of, The post laundry permanent press system, once applied to fabπc, may be executed immediately, or can be used at a time wherem the consumer desires to "re-fresh" the fabπc The durable press systems of the present mvention are also suitable for application in the null or after the fabπc has been formed mto an article of apparel Preferably the systems of the present mvention are applied to clothing compπsmg cellulosic mateπal, mcludmg cellulosic blends, preferably 100% cotton The first aspect of the present mvention relates to a process for providmg fabπc with durable press, said process compnsmg the steps of contacting fabric with a composition compπsmg a) from about 0 1%, preferably from about 1%. more preferably from about 3% to about 20%, preferably to about 10%. more preferably to about 7% by weight, of a cellulose modifying compound accordmg to the present mvention, b) from about 0 01% to about 10% by weight, of a crosslinkmg catalyst, and c) the balance earners and other adjunct ingredients The present mvention further relates to a composition for modifying fabπc, said composition compπsmg from about 0 1% to about 20% by weight, of a cellulose modifymg compound havmg the formula wherem R is a backbone iinkmg u t, each R 1 is independently I) a cellulose reactive moiety. n) a polysacchande umt. in) s-tπazme umts havmg the formula iv) pyπmidme umts havmg the formula v) cyclotπphosphazene umts havmg the formula N^ ^N II I R' R R vi) and mixtures thereof, wherem R 2 is hydrogen, C 1 -C 4 alkyl, or R 1 , X is -N-, -CH-, or mixtures thereof, the index m is from 0 to 5, the mdex n is from 0 to 5, b) from about 0 01% to about 10% by weight, of a crosslinkmg catalyst, and c) the balance earners and other adjunct mgredients These and other objects, features, and advantages will become apparent to those of ordinary skill in the art from a read g of the following detailed description and the appended claims All percentages, ratios and proportions herein are by weight, unless otherwise specified All temperatures are m degrees Celsius (° C) unless otherwise specified All documents cited are m relevant part, incorporated herem by reference DETAILED DESCRIPTION OF THE INVENTION The present invention relates to the surprising discovery that semi-permanent, renewable and re-freshable durable press can be effectively delivered to cotton fabnc A cellulosic matenal/durable press system compnsing one or more compounds compπsmg I) a cellulosic fiber reactive crosslinkmg component, II) a crosslinkmg catalyst, and III) optionally, one or more fabnc substantive components can be applied to cellulose compnsing fiber wherem said durable press compound reacts with the hydroxyl moieties of the cotton fiber and crosslinks between cotton fibers providmg a permanent press benefit to the cellulosic material The following depicts an example of the application of a durable press system according to the present mvention onto cotton fabπc OH OH HO- [cotton] [cotton] — OH R 1 R l OH O O I I R 1 — [durable press backbone]— R 1 + HO— [cotton] R 1 — [durable press backbone]— R 1 R 1 R 1 OH R 1 O HO- [cotton] OH Once attached to the cotton fabric via the R 1 cellulose reactive umts, the compound provides durable press benefits until the bonds are broken, for example, by mechanical means (wearing) For the purposes of the present mvention the term "durable" is defined as "a compound which provides a fabnc benefit, inter aha, smoothness, when applied to fabnc m a manner wherem said compound is covalently linked to the fabnc and does not become detached for reasons other than mechanical loss" For example, a compound according to the present mvention which is applied to cellulosic fabnc will not transfer to a second surface due to contact with said second surface Instead the compound which provides the benefit remams associated with the fabnc surface The term "durable" also connotes the fact that if by a mechanical process, inter aha, weanng of the fabπc, one or more "reactive umts" no longer form a covalent bond with the bulk of the fiber, non-reacted "reactive umts" can be activated by the consumer thereby re-bonding the compound to the fabπc For the purposes of the present invention the term "semi-permanent" as it relates to the attachment of the present compounds to cotton fabnc, is defined as "durable fabric enhancement compounds which are capable of permanently reacting with one or more hydroxyl umts of cellulosic fabπc wherem the compound is subsequently lost from the fabnc surface due to wear or other type of mechanical action not involving the specific breaking of the cellulose reactive unit- cellulose fabric covalent chemical bonds" For the purposes of the present mvention the term "renewable" relates to the fact that the compounds of the present mvention can be contmuously re-applied and/or re-fixed to the fabric at any point m the "process of use" The "process of use" is defined as "any step which uses the an article of manufacture compnsed of cotton, typically extending from the time of purchase until the article is discarded" Non-limiting examples of steps which comprise the "process of use" mclude, weanng of an article of manufacture compnse cotton, inter aha, as an article of apparel, care of the article, inter aha, laundermg fabπc, pre-soaking, "refreshing fabric", inter aha, spraying with a composition of the present mvention for the purpose of providmg a fabnc enhancement benefit, re-iromng fabric once the fabnc has been worn but pnor to re-laundeπng For the purposes of the present mvention the term "re-freshable' is defined as "a fabric enhancement compound which remams attached or affixed to fabπc and which is capable of further reacting at a subsequent time with additional hydroxyl umts of cellulose to provide a subsequent durable fabnc benefit" "Re-freshable" is an aspect of the compounds "durability" "Refreshable" relates to the aspect of the present mvention wherem between laundry cycles the compounds of the present mvention may be applied to the cellulosic matenal to re-enforce the desired benefit It is a preferred embodiment of the present invention to apply m a first step the durable fabπc enhancement system of the present mvention to cellulosic fabπc. m a second step to fix the components which compnse said system to said cellulosic fabπc, and m a third step to reform new covalent bonds between unreacted cellulose reactive umts and cellulose hydroxyl umts For the purposes of the present mvention the term "cellulosic matenal" is defined as "fibrous cellulose compnsmg-matenal denved from native sources, inter aha, cotton, rayon, flax, mcludmg the pulp of said sources, inter aha, wood pulp, cellulose comprismg deπvatives. non- limit g examples of which mclude cellulose acetates, cellulose ethers" "Cellulosic mateπal" depending upon the context is defined as "the raw mateπal, inter aha, fibers, or the finished product, inter aha, an article of clothing" The term "cellulose fabπc" is used interchangeably for and is meant to stand equally well for "fabric comprismg 100% cotton fiber, and mixtures of cotton fiber and synthetic fibers" The durable press compounds of the present mvention which compnse the cellulosic fabnc modifymg systems have a modulated reactivity toward cellulosic fabnc As set forth herernabove the compounds of the present mvention react with the hydroxyl moieties which compnse cellulose and provides a ngid link or framework which holds the sections of cellulose fibers together to form a permanent press or durable fabnc finish For example, a mono-tnazine compound will have three cellulose reactive sites Once one site reacts with the fabnc, the two remainmg sites will then be available to react with proximal hydroxyl umts and form a ngid framework resulting m a durable press finish The present mvention, however, allows the formulator to react , m the s- tnazme example, one of the remainmg sites with a non-reactive moiety (for example, a non-leaving group) thereby modulating the amount of "stiffness" that the compound will provide to the substrate fabnc Also by the choice of cellulose reactive umts the formulator can modulate the relative reactivity of the umts toward cellulosic matenal For the purposes of the present mvention, m the case wherem an ohgomenc backbone compnses the several differentiated reactivity R 1 cellulose reactive umts, the most reactive may initially combme with cellulosic fiber and the balance may remain unreacted so as to be mitiated to react with cellulose hydroxyl umts in the future to provide a "durable fabnc press benefit" Durable Press Systems The compositions of the present invention compnse from about 0 1%, preferably from about 1%, more preferably from about 3% to about 20%), preferably to about 10%. more preferably to about 7% by weight, of one or more cellulose modifying compounds The compositions of the present mvention compnse and the processes of the present mvention utilize compositions which compnse one or more fabric modifymg compounds havmg the formula wherem R is a backbone Iinkmg umt wherem each R is independently a umt havmg the formula — (Y) p R 3 (Y)p— wherem R 3 is substituted or unsubstituted C 1 -C 22 alkylene, -C2 2 alkenylene, C3-C 22 cycloalkylene. C6-C22 arylene, C7-C22 alkylarylene, and mixture thereof, preferably R 3 is C 2 -C6 alkylene, phenylene, C7-C 10 alkylarylene, and mixture thereof Y is -0-, NR'-, and mixtures thereof, R' is hydrogen, C 1 -C 4 alkyl, and mixtures thereof, p is 0 or 1 Preferably Y is -NH- when each p is 1 Each R 1 is independently selected from the group consistmg of I) a cellulose reactive moiety The term "cellulose reactive moiety" is defined herein as "a umt which facilitates the formation of a covalent bond between the cellulose modifymg compound and a hydroxyl umt compnsmg the cellulosic fabnc " Preferably each cellulose reactive moiety is independently selected from the group consistmg of halogen, thioglycolate, citrate, mcotinate, (4-sulfonylphenyl)am_no, (4-sulfonylphenyl)oxy, and mixtures thereof, more preferably chlorine, (4- sulfonylphenyl)amιno, (4-sulfonylphenyl)oxy, most preferably chlorine II) a polysacchande umt The term "polysacchande umt" is defined herem as "sacchande umts, mcludmg polysucrose. polyglucose, chitosan. and the like, or other cellulosic-like umts havmg an increased affinity for cellulosic and cellulosic fiber compnsmg fabπc " A prefened polysacchande mcludes chitosan III) s-tnazine umts havmg the formula iv) pyπmidme umts havmg the formula v) cyclotπphosphazene umts havmg the formula vi) and mixtures thereof, wherem R 2 is hydrogen, C]-C 4 alkyl, or R 1 . X is -N-, -CH-. and mixtures thereof, preferably -N-. the mdex m is from 0 to 5, the mdex n is from 0 to 5 For embodunents wherem R 1 umts compnse one or more s-tπazme, pyπmidme. or cyclotπphosphazene umts, the backbone of the ohgomer will be a branched backbone, for example, a backbone havmg the general formula R 1 N ' " N R 1 R N R 1 N N N N R 1 " N R N R N ^ N Rl / - N ^ ^ R ι wherem R umts are any Iinkmg umts as described heremabove, and the R 1 umts are cellulose reactive umts as descπbed herem Another embodiment of the present mvention relates to compounds, compositions compnsmg compounds, or processes utilizmg compounds havmg two s-tπazme or pyπmidme backbone umts (ohgomers), for example, the preferred compounds havmg the formula R 1 R 1 N^ N N ^ N R 1 ^ ^N^ ^ R^ ^ N^ ^ R 1 wherem R has the formula — NH- R 3 -NH — wherem R 3 is C 2 -C 6 alkylene, phenylene, substituted phenylene, and mixtures thereof, and R 1 is selected from the group consistmg of halogen. (4-sulfonyl-phenyl)amιno, (4-sulfonylphenyl)ox\ , and mixtures thereof Non-limiting examples of cellulose modifymg compounds mclude compounds havmg the general formula R 1 N R 1 wherem R 1 is a fabric reactive moiety selected from the group consistmg of halogen, thioglycolate. citrate, mcotmate, (4-sulfonylphenyl)amιno, (4-sulfonylphenyl)oxy, and mixtures thereof, as exemplified by the compound having the formula Non-limiting examples of multiple backbone umt comprising cellulose modifymg compounds include compounds having the general formula wherein R 1 is a fabnc reactive moiety selected from the group consistmg of halogen, thioglycolate, citrate, mcotmate, (4-sulfonylphenyl)amιno, (4-sulfonylphenyl)oxy, and mixtures thereof, as represented by a cellulose modifymg compound havmg the formula or a compound havmg the formula wherem M is hydrogen of a water soluble cation, preferably sodium, potassium, ammonium, and mixtures thereof The followmg are preferred durable press compounds accordmg to the present mvention A B^N^C FORMULATIONS The present mvention relates to a composition for modifying cellulose or cellulose compnsmg fabric, said composition compnsmg a) from about 0 1%, preferably from about 1%. more preferably from about 3% to about 20%), preferably to about 10%, more preferably to about 7% by weight, of a cellulose modifying compound as descnbed herein above, b) from about 0 01% to about 10% by weight, of a crosslinkmg catalyst, and c) the balance earners and other adjunct ingredients Crosslinkmg Catalyst The compositions of the present mvention which are applied to fabnc at the pomt of manufacture by the process of the present mvention comprises from about 0 01%, preferably from about 0 1%, more preferably from about 1% to about 10%, preferably to about 7%, more preferably to about 5% by weight, of a crosslinkmg catalyst Preferably said crosslinkmg catalyst is a base selected from the group consistmg of alkali metal carbonates, alkalme earth metal carbonates, alkali metal hydroxides, alkalme earth metal hydroxides, and mixtures thereof More preferred catalyst is sodium carbonate, sodium bicarbonate, and mixtures thereof ADJUNCT INGREDIENTS Aside from the requirement that the compositions of the present invention comprise a cellulose modifymg compound and a crosslinkmg catalyst, the balance of the composition may comprise one or more adjunct ingredients as well as earners The followmg are non-limiting examples of earners and preferred adjunct mgredients Fabπc Softening Actives The compositions of the present mvention optionally compnse at least about 1%, preferably from about 10%. more preferably from about 20% to about 80%, more preferably to about 60%), most preferably to about 45% by weight, of the composition of one or more fabric softener actives The preferred fabnc softening actives accordmg to the present mvention are amines havmg the formula (R) N^CCH^-Q-R 1 3-m quaternary ammonium compounds havmg the formula and mixtures thereof, wherem each R is mdependently Cj-Cg alkyl. Ci -Cg hydroxyalkyl. benzyl. and mixtures thereof, R* is preferably C^ 1-C22 linear alkyl, C \- >22 branched alkyl. Cj 1-C22 lmear alkenyl, C } 1-C22 branched alkenyl, and mixtures thereof, Q is a carbonyl moiety mdependently selected from the umts havmg the formula O O R 2 O O R 2 I I I I I II II I — 0— C— ' — C— 0 — ' — N-C— ' — C— N — . o O R 3 3 0 O— C " — R 1 1 O I I I I I I II — 0— C— O — — CH-O— C — — CH-CH 2 -0— C — wherem R^ is hydrogen, C1-C4 alkyl, preferably hydrogen, R^ is C1-C4 alkyl, preferably hydrogen or methyl, preferably Q has the formula O o I I — 0 — -C 1__- or NH-C — X is a softener compatible anion, preferably the anion of a strong acid, for example, chlonde. bromide, methylsulfate, ethylsulfate, sulfate, mtrate and mixtures thereof, more preferably chloride and methyl sulfate The anion can also, but less preferably, carry a double charge, m which case X' " •' represents half a group The mdex m has a value of from 1 to 3 , the index n has a value of from 1 to 4, preferably 2 or 3. more preferably 2 One embodiment of the present mvention provides for amines and quaternized amines havmg two or more different values for the mdex n per molecule, for example, a softener active prepared from the starting amine methyl(3-ammopropyl)(2-hydroxyethyl)_ιmme More prefeπed softener actives accordmg to the present invention have the formula wherem the unit havmg the formula 0 — O— C 1 1 — R i 1 is a fatty acyl moiety Suitable fatty acyl moieties for use m the softener actives of the present mvention are deπved from sources of tnglycendes mcludmg tallow, vegetable oils and/or partially hydrogenated vegetable oils mcludmg inter aha canola oil, safflower oil, peanut oil, sunflower oil. corn oil, soybean oil, tall oil, nee bran oil Yet more prefeπed are the Diester Quaternary Ammonium Compounds (DEQA's) wherem the mdex m is equal to 2 The formulator, dependmg upon the desired physical and performance properties of the final fabnc softener active, can choose any of the above mentioned sources of fatty acyl moieties, or alternatively, the formulator can mix sources of tnglyceπde to form a "customized blend" However, those skilled m the art of fats and oils recognize that the fatty acyl composition may vary, as in the case of vegetable oil, from crop to crop, or from variety of vegetable oil source to vaπety of vegetable oil source DEQA's which are prepared usmg fatty acids denved from natural sources are prefeπed A prefeπed embodiment of the present invention provides softener actives compnsmg R^ umts which have at least about 3%, preferably at least about 5%, more preferably at least about 10%, most preferably at least about 15 > Cj 1-C22 alkenyl, mcludmg polyalkenyl (polyunsaturated) umts inter aha oleic, linoleic, linolenic For the purposes of the present invention the term "mixed cham fatty acyl umts" is defined as "a mixture of fatty acyl units compπsmg alkyl and alkenyl chams havmg from 10 carbons to 22 carbon atoms mcludmg the carbonyl carbon atom, and m the case of alkenyl chams, from one to three double bonds, preferably all double bonds m the as configuration" With regard to the R* umts of the present mvention, it is preferred that at least a substantial percentage of the fatty acyl groups are unsaturated, e g , from about 25%, preferably from about 50% to about 70%. preferably to about 65% The total level of fabπc softenmg active contammg polyunsaturated fatty acyl groups can be from about 3%, preferably from about 5%, more preferably from about 10% to about 30%), preferably to about 25%, more preferably to about 18% As stated herem above as and trans isomers can be used, preferably with a cisltrans ratio is of from 1 1, preferably at least 3 1, and more preferably from about 4 1 to about 50 1, more preferably about 20 1, however, the minimum bemg 1 1 The level of unsaturation contained within the tallow, canola, or other fatty acyl unit cham can be measured by the lodme Value (IV) of the correspondmg fatty acid, which m the present case should preferably be in the range of from 5 to 100 with two categones of compounds bemg distinguished, havmg a IV below or above 25 Indeed, for compounds havmg the formula deπved from tallow fatty acids, when the lodme Value is from 5 to 25, preferably 15 to 20. it has been found that a cisltrans isomer weight ratio greater than about 30/70, preferably greater than about 50/50 and more preferably greater than about 70/30 provides optimal concentrabihty For compounds of this type made from tallow fatty acids havmg a lodme Value of above 25, the ratio of as to trans isomers has been found to be less cπtical unless very high concentrations are needed A further prefeπed embodiment of the present mvention compnses DEQA's wherem the average lodme Value for R^ IS approximately 45 The R! umts suitable for use in the isotropic liquids present mvention can be further charactenzed in that the lodme Value (IV) of the parent fatty acid, said IV is preferably from about 10, more preferably from about 50, most preferably from about 70, to a value of about 140, preferably to about 130, more preferably to about 115 However, formulators, dependmg upon which embodiment of the present mvention they choose to execute, may wish to add an amount of fatty acyl umts which have lodme Values outside the range listed herem above For example, "hardened stock" (IV less than or equal to about 10) may be combmed with the source of fatty acid admixture to adjust the properties of the final softener active A prefered source of fatty acyl umts, especially fatty acyl umts havmg branching, for example, "Guerbet branching", methyl, ethyl, etc umts substituted along the primary alkyl chain, synthetic sources of fatty acyl umts are also suitable For example, the formulator may with to add one or more fatty acyl umts havmg a methyl branch at a "non-naturally occuπng" position, for example, at the third carbon of a C j η chain What is meant herem by the term "non-naturally occuπng" is "acyl umts whihc are not found m significant (greater than about 0 1 %) quantities is common fats and oils which serve as feedstocks for the source of tnglycendes descnbed herem " If the desired branched cham fatty acyl umt is unavailable from readily available natural feedstocks, therefore, synthetic fatty acid can be suitably admixed with other synthetic matenals or with other natural triglyceride denved sources of acyl umts The followmg are examples of preferred softener actives according to the present mvention N,N-dι(tallowyl-oxy-ethyl)-N,N-dιmethyl ammonium chlonde, N,N-dι(canolyl-oxy-ethyl)-N,N-dιmethyl ammonium chlonde, N,N-dι(tallowyl-oxy-ethyl)-N-methyl, N-(2-hydroxyethyl) ammonium methyl sulfate, N,N-di(canolyl-oxy-ethyl)-N-methyl, N-(2-hydroxyethyl) ammonium methyl sulfate, N,N-dι(tallowylamιdoethyl)-N-methyl, N-(2-hydroxyethyl) ammonium methyl sulfate, N,N-dι(2-tallowyloxy-2-oxo-ethyl)-N,N-dιmethyl ammonium chlonde. N,N-dι(2-canolyloxy-2-oxo-ethyl)-N,N-dιmethyl ammonium chlonde, N,N-dι(2-tallowyloxyethylcarbonyloxyethyl)-N,N-dιmethyl ammonium chlonde, N.N-dι(2-canolyloxyethylcarbonyloxyethyl)-N.N-d_methyl ammonium chloride, N-(2-tallowoyloxy-2-ethyl)-N-(2-tallowyloxy-2-oxo-ethyl)-N,N-dιmethyl ammonium chlonde, N-(2-canolyloxy-2-ethyl)-N-(2-canolyloxy-2-oxo-ethyl)-N,N-dimethyl ammomum chlonde, N,N,N-tn(tallowyl-oxy-ethyl)-N-methyl ammonium chlonde, N,N,N-tn(canolyl-oxy-ethyl)-N-methyl ammonium chlonde, N-(2-tallowyloxy-2-oxoethyl)-N-(tallowyl)-N,N-dιmethyl ammonium chlonde, N-(2-canolyloxy-2-oxoethyl)-N-(canolyl)-N.N-dιmethyl ammonium chlonde, l,2-dιtallowyloxy-3-N,N,N-tnmethylammomopropane chlonde, and 1 ,2-dιcanolyloxy-3 -N,N,N-tnmethylammomopropane chlonde, and mixtures of the above actives Particularly preferred is N,N-dι(tallowoyl-oxy-ethyl)-N.N-dιmethyl ammonium chlonde, where the tallow chams are at least partially unsaturated and N,N-dι(canoloyl-oxy-ethyl)-N,N- dimethyl ammonium chlonde, N,N-dι(tallowyl-oxy-ethyl)-N-methyl, N-(2-hydroxyethyl) ammonium methyl sulfate, N,N-dι(canolyl-oxy-ethyl)-N-methyl, N-(2-hydroxyethyl) ammonium methyl sulfate, and mixtures thereof Additional fabnc softenmg agents useful herem are descnbed m U S 5,643,865 Mermelstein et al , issued July 1, 1997, U S 5,622.925 de Buzzaccanm et al , issued Apnl 22, 1997, U S 5,545,350 Baker et al , issued August 13, 1996, U S 5.474,690 Wahl et al , issued December 12, 1995, U S 5,417,868 Turner et al . issued January 27, 1994, U S 4,661,269 Tπnh et al , issued April 28, 1987, U S 4,439,335 Burns, issued March 27, 1984, U.S 4,401,578 Verbruggen, issued August 30, 1983, U S 4.308,151 Cambre, issued December 29, 1981, U S 4,237,016 Rudkin et al , issued October 27, 1978. U S 4,233,164 Davis, issued November 11. 1980, U S 4,045,361 Watt et al , issued August 30. 1977, U S 3,974,076 Wiersema et al , issued August 10, 1976, U S 3,886,075 Bernadino, issued May 6, 1975, U S 3,861,870 Edwards et al , issued January 21 1975, and European Patent Application publication No 472,178, by Yamamura et al , all of said documents bemg incorporated herem by reference Crystal Growth Inhibitor The compositions of the present mvention optionally compnse from about 0 005%, preferably from about 0 5%, more preferably from about 0 1% to about 1%, preferably to about 0 5%, more preferably to about 0 25%, most preferably to about 0 2% by weight, of one or more crystal growth inhibitors Carboxylic Compounds Non-limiting examples of carboxylic compounds which serve as crystal growth inhibitors mclude glycohc acid, phytic acid, polycarboxyhc acids, polymers and co-polymers of carboxylic acids and polycarboxyhc acids, and mixtures thereof The inhibitors may be m the acid or salt form Preferably the polycarboxyhc acids compnse materials havmg at least two carboxylic acid radicals which are separated by not more than two carbon atoms (e g , methylene umts) The prefeπed salt forms mclude alkali metals, lithium, sodium, and potassium, and alkanolammonium The polycarboxylates suitable for use m the present mvention are further disclosed m U S 3,128,287, U S 3,635,830, U S 4,663,071, U S 3.923,679, U S 3,835,163, U S 4,158,635, U S 4,120,874 and U S 4,102,903, each of which is mcluded herem by reference Further suitable polycarboxylates mclude ether hydroxypolycarboxylates, polyacrylate polymers, copolymers of maleic anhydπde and the ethylene ether or vinyl methyl ethers of acrylic acid Copolymers of 1,3,5-tnhydroxybenzene, 2, 4, 6-tnsulphomc acid, and carboxymethyloxysuccmic acid are also useful Alkali metal salts of polyacetic acids, for example, ethylenediamine tetraacetic acid and mtπlotnacetic acid, and the alkali metal salts of polycarboxylates, for example, mellitic acid, succinic acid, oxydisuccinic acid, polymaleic acid, benzene 1,3,5-tπcarboxylιc acid, carboxymethyloxysuccmic acid, are suitable for use m the present mvention as crystal growth inhibitors The polymers and copolymers which are useful as crystal growth inhibitors have a molecular weight which is preferably greater than about 500 daltons to about 100,000 daltons. more preferably to about 50,000 daltons Examples of commercially available matenals for use as crystal growth inhibitors mclude polyacrylate polymers Good-Rite® ex BF Goodnch, Acrysol® ex Rohm & Haas, Sokalan® ex BASF, and Norasol® ex Norso Haas Prefeπed are the Norasol® polyacrylate polymers, more prefeπed are Norasol® 4 ION (MW 10.000) and Norasol® 440N (MW 4000) which is an ammo phosphomc acid modified polyacrylate polymer, and also more prefened is the acid form of this modified polymer sold as Norasol® QR 784 (MW 4000) ex Norso-Haas Polycarboxylate crystal growth inhibitors mclude citrates, e g , citric acid and soluble salts thereof (particularly sodium salt), 3,3-dιcarboxy-4-oxa-l,6-hexanedιoates and related compounds further disclosed m U S 4,566,984 incorporated herem by reference. C5-C20 alkyl, C5-C20 alkenyl succinic acid and salts thereof, of which dodecenyl succmate, lauryl succmate, mynstyl succmate, palmityl succmate, 2-dodecenylsuccιnate, 2-pentadecenyl succmate, are non-limiting examples Other suitable polycarboxylates are disclosed m U S 4.144,226, U S 3,308,067 and U S 3,723,322, all of which are incorporated herem by reference Organic Phosphomc Acids Organic diphosphomc acid are also suitable for use as crystal growth inhibitors For the purposes of the present mvention the term "organic diphosphomc acid" is defined as "an organo- diphosphonic acid or salt which does not compnse a mtrogen atom" Preferred organic diphosphomc acids include C 1 -C 4 diphosphomc acid, preferably C 2 diphosphomc acid selected from the group consistmg of ethylene diphosphomc acid, α-hydroxy-2 phenyl ethyl diphosphomc acid, methylene diphosphomc acid, vmyhdene- 1,1 -diphosphomc acid . l,2-dιhydroxyethane-l,l- diphosphomc acid, hydroxy-ethane 1,1 diphosphomc acid, the salts thereof, and mixtures thereof More preferred is hydroxyethane- 1,1 -diphosphomc acid (HEDP) A more prefeπed phosphomc acid I 2-phosphonobutane-l,2,4-tπcarboxyhc acid (PBTC) available as Bayhibit ® AM ex Bayer Electrolyte The compositions of the present mvention may also optionally, but preferably comprise, one or more electrolytes for control of phase stability, viscosity, and or clanty For example, the presence of certain electrolytes inter aha calcium chlonde. magnesium chlonde may be key to insuring initial product clanty and low viscosity, or may affect the dilution viscosity of liquid embodiments, especially isotropic liquid embodiments Not wishing to be limited by theory, but only wishing to provide an example of a circumstance wherem the formulator must msure proper dilution viscosity, includes the followmg example An electrolyte may be added to the compositions of the present mvention to msure phase stability and prevent the fabnc modifymg compound from "gelling out" or from undergomg an undesirable or unacceptable viscosity 7 mcrease Prevention of gelling or formation of a "swelled", high viscosity solution insures thorough delivery of the fabπc modifymg composition during the process of the present mvention However, those skilled m the art of fabnc softener compositions will recognize that the level of electrolyte is also influenced by other factors inter aha the type of fabric onto which the composition is deposed, the type of R 1 fabnc reactive umts and the final pH of the solution, the amount of principal solvent, and the level and type of nomomc surfactant Therefore, the formulator must consider all of the ingredients, namely, fabric modifymg compound, nomomc surfactant, and m the case of isotropic liqmds, the principal solvent type and level, as well as level and identity of adjunct ingredients before selectmg the type and/or level of electrolyte A wide vanety of lonizable salts can be used Examples of suitable salts are the hahdes of the Group IA and IIA metals of the Penodic Table of the elements, e g , calcium chlonde. sodium chlonde, potassium bromide, and lithium chlonde The lonizable salts are particularly useful during the process of mixing the mgredients to make the compositions herem, and later to obtain the desired viscosity The amount of lonizable salts used depends on the amount of active ingredients used m the compositions and can be adjusted accordmg to the desires of the formulator Typical levels of salts used to control the composition viscosity are from about 20 to about 10,000 parts per million (ppm), preferably from about 20 to about 5,000 ppm, of the composition Alkylene polyammomum salts can be incorporated mto the composition to give viscosity control in addition to or m place of the water-soluble, lonizable salts above, In addition, these agents can act as scavengers, forming ion pairs with anionic detergent earned over from the mam wash, m the rinse, and on the fabncs, and can improve softness performance These agents can stabilized the viscosity over a broader range of temperature, especially at low temperatures, compared to the morgamc electrolytes Specific examples of alkylene polyammomum salts mclude L-lysme, monohydrochlonde and 1,5-dιammomum 2 -methyl pentane dihydrochlonde Dispersibihty Aids When dispersibihty aids are present, the total level is from 0 1%, preferabh from 0 3% more preferably from 3%, even more preferably from 4%. and most preferably from 5% to 25% preferably to 17%. more preferably to 15%. most preferably to 13%> by weight, of the composition The total level of dispersibihty aid includes any amount that may be present as part of another adjunct ingredient Prefeπed dispersibihty aids are GENAMINE ® and GENAPOL ® ex Clanant When PVP is present in the compositions of the present mvention. a prefeπed embodiment compnses both a cocoyl ethoxylated amine and a cocoyl ethoxylated alcohol, wherem the ethoxylation is approximately 10, each of which are available as GENAMINE ® and GENAPOL ® A preferred example of the use of this admixture is a composition which compnses, for example. 0 2% GENAMINE ® and 0 1% GENAPOL ® Pπncipal solvent Although water is the preferred carrier of the present mvention. the compositions of the present mvention may compnse as a earner a pπncipal solvent The level of pπncipal solvent present in the compositions of the present mvention is typically less than about 95%. preferably less than about 50%, more preferably less than about 25%, most preferably less than about 15% by weight Some embodiments of present mvention may comprise no pπncipal solvent but ma) substitute instead a suitable nomomc surfactant as descnbed herem above When utilized, the principal solvents suitable for use m the present invention are selected from those havmg a ClogP of from about 0 15 to about 1. preferably from about 0 15 to about 0 64, more preferably from about 0 25 to about 0 62. most preferably from about 0 4 to about 0 6 Preferably the principal solvent is at least to some degree an asymmetnc molecule, preferabh havmg a meltmg, or solidification pomt which allows the pπncipal solvent to be liquid at or near room temperature Low molecular weight principal solvents may be desirable for some embodiments More prefeπed molecules are highly asymmetncal PROCESS The present mvention relates to a manufacturing process for providmg fabnc with an enhanced fabric benefit, said process compnsmg the steps of contacting fabnc with a composition m the form of an aqueous emulsion, said composition compnsmg a) from about 0 1%, preferably from about 1%, more preferably from about 3%o to about 20%, preferably to about 10%. more preferably to about 7% by weight, of a cellulose modifymg compound as descnbed herem above, b) from about 0 01%, preferably from about 0 1%. more preferably from about 1% to about 10%, preferably to about 7%, more preferably to about 5% by weight of a crosslinkmg catalyst, and c) the balance earners and other adjunct ingredients The followmg is a non-limiting example for prepaπng a cellulose modifymg compound accordmg to the present mvention EXAMPLE 1 Preparation of 1.4-bιs.4.6-dι-(4-sulfophenyl)-1.3.5-trιazmyl]phenylenedιan_ιne Sodio 4-hydroxybenzene sulfomc acid (78 98 g, 0 33 mole) is charged to a 2-L 3-neck flask fitted with a mechanical stiπer and argon inlet tube Water (456 g) is added and the solution strrred Separately, cyanunc chlonde (31 05 g, 0 167 mole) is dissolved m acetone (223 mL) and charged to an addition funnel The initial pH of the sulfomc acid solution is 5 28 The cyanunc chloride solution is added dropwise while mamtainmg the pH between 3 5 and 4 by the mtermittent addition of sufficient sodium bicarbonate (23 89 g) 1.4-Phenylenediamme (9 3 g, 0 083 mole) is dissolved m water (225 mL) and gently warmed The aqueous solution of 1.4-phenylenedιamιne is then added dropwise to the stiπed solution mamtainmg a temperature below 25 °C and a pH less than 5 by the alternate addition of aqueous sodium bicarbonate The solution is stiπed 18 hours and the pH adjusted to 5 usmg additional sodium bicarbonate Potassium chloride (134 g) is added and the solution is filtered over cehte to obtain the crude product which is isolated by standard procedures The following are non-limiting examples of the compositions of the present invention. The following can be directly sprayed onto fabric or the compositions can be incorporated into granular or liquid laundry detergent compositions, fabric softening compositions and the like. TABLE I weight % 1. 1 ,4-bis [4, 6-di-(4-sulfophenyl)- 1,3,5 -triazinyljphenylenediamine . 2. 2-chloro-4,6-di-(4-sulfophenyl)- 1,3,5-triazine. 3. Neodol 91-8. 4. Neodol 13-5. 5. Sodium carbonate. 6. Sodium bicarbonate. 7. Di-(tallowyl-oxy-ethyl) dimethyl ammonium chloride.

Claims: What is claimed is: 1. A process for providing fabric with durable press, said process comprising the steps of contacting fabric with a comprising: a) from 0.1 % to 20% by weight, of a cellulose modifying compound having the formula: wherein R is a backbone linking unit; each R 1 is independently i) a cellulose reactive moiety; ii) a polysaccharide unit; iii) s-triazine units having the formula: iv) pyrimidine units having the formula: v) cyclotriphosphazene units having the formula: vi) and mixtures thereof, wherem R 2 is hydrogen, C 1 -C 4 alkyl. or R 1 . X is -N-, -O- -CH-. or mixtures thereof, the mdex m is from 0 to 5. the mdex n is from 0 to 5, b) from 0 01 % to 10% by weight, of a crosslinkmg catalyst, and c) the balance earners and other adjunct mgredients A process accordmg to Claim 1 wherem each R is mdependently a unit havmg the formula — (Y) p R 3 (Y) p — wherem R 3 is C1-C22 alkylene, C1-C22 alkenylene, C 3 -C 22 cycloalkylene. C 6 -C 22 arylene, C7- C 22 alkylarylene, and mixture thereof, Y is -0-, NR'-, and mixtures thereof. R' is hydrogen, C 1 -C 4 alkyl, and mixtures thereof, p is 0 or 1 A process accordmg to either Claim 1 or 2 wherein said fabric reactive moiety is mdependently selected from the group consistmg of halogen, thioglycolate, citrate, mcotmate, (4-sulfonylphenyl)amιno, (4-sulfonylphenyl)oxy. and mixtures thereof A process accordmg to any of Claims 1 3 wherein said fabnc modifymg compound has the formula wherein R 1 is a fabπc reactive moiety selected from the group consistmg of halogen, thioglycolate, citrate, mcotmate, (4-sulfonylphenyl)amιno, (4-sulfonylphenyl)oxy. and mixtures thereof A process accordmg to any of Claims 1 - 4 wherem said fabnc modifymg compound has the formula A composition for modifymg cellulosic fabnc, said composition compnsmg a) from 0 1% to 20% by weight, of a fabnc modifying compound havmg the formula wherem R is a backbone Iinkmg umt, each R 1 is mdependently l) a fabπc reactive moiety, n) a polysacchande umt, in) s-tnazme umts havmg the formula iv) pyπrmdme umts havmg the formula v) cyclotπphosphazene umts havmg the formula p N ^N R' ,/ N R R 2 vi) and mixtures thereof, wherem R 2 is hydrogen, C 1 -C 4 alkyl, or R 1 , X is -N-, -O- -CH-, or mixtures thereof, the mdex m is from 0 to 5. the index n is from 0 to 5, b) from 0 01% to 10% by weight, of a crosslinkmg catalyst, and c) the balance earners and other adjunct ingredients A composition accordmg to Claim 6 wherem said crosslinkmg catalyst is a base selected from the group consisting of alkali metal carbonates, alkalme earth metal carbonates, alkali metal hydroxides, alkalme earth metal hydroxides, and mixtures thereof A composition according to either Claim 6 or 7 wherem each R is independently a umt havmg the formula (Y) p R 3 (Y) p — wherem R 3 is C1-C 22 alkylene, C1-C22 alkenylene, C3-C 22 cycloalkylene, C 6 -C 2 2 arylene, C 7 - C 22 alkylarylene, and mixture thereof, Y is -0-, NR'-, and mixtures thereof, R' is hydrogen, C 1 -C 4 alkyl. and mixtures thereof, p is 0 or 1 A composition accordmg to any of Claims 6 - 8 wherem said cellulose reactive moiety is mdependently selected from the group consistmg of halogen, thioglycolate, citrate, mcotmate, (4-sulfonylphenyl)amιno, (4-sulfonylphenyl)oxy, and mixtures thereof A composition accordmg to any of Claims 6 - 9 wherem said fabric modifymg compound has the formula wherem R 1 is a fabnc reactive moiety selected from the group consistmg of halogen, thioglycolate, citrate, mcotmate, (4-sulfonylphenyl)amιno, (4-sulfonylphenyl)oxy, and mixtures thereof

Inventors: BERNAERTS AN, HUBESCH BRUNO ALBERT, LEWIS DAVID MALCOLM, SIVIK MARK ROBERT, BERNAERTS, AN, HUBESCH, BRUNO, ALBERT, LEWIS, DAVID, MALCOLM, SIVIK, MARK, ROBERT
Applicants: BERNAERTS AN, HUBESCH BRUNO ALBERT, LEWIS DAVID MALCOLM, PROCTER & GAMBLE, SIVIK MARK ROBERT, BERNAERTS, AN, HUBESCH, BRUNO, ALBERT, LEWIS, DAVID, MALCOLM, SIVIK, MARK, ROBERT, THE PROCTER & GAMBLE COMPANY
Application year: 2000
Main classification: D06M13
IPC codes: C08K3, C08L5, C11D3, D06M13, D06M15, D06M23, D06M101