FIBER BONDING

Abstract: The invention relates to a method of bonding polymer fibers into a nonwoven fabric and a nonwoven fabric manufactured with the aid thereof. According to the invention, the polymer fibers are subjected to hydroentangling, the polymer fibers at the moment of hydroentangling being imparted a temperature exceeding the glass transition temperature of the polymer fiber, but being less than its melting point.

Description: FIBER BONDING Technical field The invention relates to a method for bonding polymer fibers into a nonwoven fabric and a nonwoven fabric manufactured with the aid thereof. According to the invention the polymer fibers are subjected to hydroentangling, the fibers at the moment of hydroentangling being imparted a temperature exceeding the glass transition temperature of the polymer fiber and being less than the melting point of the polymer fiber. Background of the invention The manufacture of cloth and fabrics is very old art. In addition to the wellknown methods of weaving, knitting and crocheting, there are now a number of methods for the manufacture of nonwoven materials. Such materials can be made of both synthetic fibers and natural fibers. A number of methods utilize heat to melt the fibers together, so-called thermobonding. There are also other bonding methods, such as stitch-bonding and hydroentangling or spun-lacing. Hydroentangling or spun-lacing is a technology which was introduced in the nineteen seventies. The method involves the forming of a fiber web, either dry-laid or wet-laid, whereafter the fibers are entangled together with the aid of very fine jets of water under high pressure. Several rows of water jets are directed towards the fiber web, which is carried by a moving wire or drum. Finally, the entangled fiber web is dried. In hydroentangled materials many different types and mixtures of fibers are used, such as for example synthetic staple fibers, synthetic continuous fibers, staple fibers of regenerated cellulose and pulp fibers. Examples of commercially available fibers of regenerated cellulose are rayon, viscose fibers and lyocell. Hydroentangling is a method of bonding fibers without using bonding agents or bonding fibers. Hydroentangled material or spun-lace material of high quality can be made at reasonable cost, and has a high absorption capacity, good mechanical properties and a high textile comfort. They were used as wiping materials for house-hold or industrial use, as disposable materials in medical contexts and for hygiene etc. In order to form a composite web by hydroentangling, the fibers to be entangled must have the right properties for this purpose. One of several critical factors is the flexural rigidity of the fiber = E x I. where E is the initial modulus of the fiber or the modulus of elasticity, and I is the moment of inertia. The moment of inertia is a sectional quantity (I = πd 4 /64 for a circular cross section) which is dependent on the diameter of the fiber. The initial modulus is thus a material parameter, which is temperature-dependent. A stiff fiber is more difficult to entangle and requires more specific energy (kWh/ton) to be bonded than a soft fiber, and this in turn limits the range of fibers which are technically and commercially of interest for use in this technology. Fibers made of thermoplastic polymers, such as e.g. polypropylene, polyester, poly- amide commonly occur in hydroentangling. The properties of thermoplastic and other synthetic fibers are dependent on the properties of the component of polymer or polymers and the type of process used. Often the properties of the polymer cannot be fully utilized. Rather, a compromise must be made due to the technical constraints of the process. It is typically very difficult to manufacture a fiber which is both very strong and at the same time has a low initial modulus. The strength of the fiber is largely determined by the orientation, imodulus follow the same tendency, i.e. a high fiber strength is accompanied by a high initial modulus. CA 841 938 describes the manufacture of a nonwoven fabric by hydroentangling, whereby water under high pressure is pressed through a perforated carrier against a sheet of a fiber suspension, to give rise to entangling of the fibers. WO 95/06769 describes a method and an apparatus for achieving a melt bond and possibly entangling of fibers in a fiber fabric, e.g. a nonwoven fabric. In this case, a steam jet or a jet of superheated steam is used to both melt and entangle the fibers. If one uses jets such as are normally used in hydroentangling, they must be sufficiently hot to melt a meltable component incorporated in the fiber web. WO95/06769 thus describes a process whereby a certain amount of melting of the meltable component is always achieved. This meltable component can either be the fibers themselves or an added meltable component in the form of a powder or granulate. No process for pure hydroentangling is described. US 3 322 584 describes a melt-bonding process for bonding together two plastic webs. The method described can also be used to bond together two layers of plastic fibers, but this also refers to a melt bond, the temperature used being sufficiently high to melt the fibers. US 5 069 735 describes a method of edge-melting adjacent sheets or fabrics to solve the problem that these sheets normally flock and are unsuitable for use in operations for example. US 3 192 560 describes a method for controlled melt-bonding of fiber threads with a suitable medium, e.g. steam or superheated steam, the temperature being kept about or slightly under the melting point of the fiber threads. One problem with hydroentangling is that the fiber components used must have a flexural rigidity' such that the fibers can be entangled using reasonable energy levels. This means a limitation as regards the types of fibers used and means that thin fibers or fibers with a low initial modulus must be used, even if the fibers per se are not optimal for the formation of the fibrous web or for the functional properties of the finished material. One purpose of the present invention is to achieve a process for manufacturing a nonwoven fabric by hydroentangling, where the flexural rigidity of the fiber components used does not limit the degree of entangling as much as previously. An additional purpose of the present invention is to achieve a process making it possible to manufacture nonwoven fabrics having coarser fibers, consuming less energy or being stronger than what is possible with today ' s methods. Another additional purpose of the present invention is to provide a nonwoven fabric with special properties, such as good mechanical properties, high bulk, etc. Summary of the invention We have now found that by raising the temperature at the very moment of entang- ling it is possible to reduce the flexural rigidity of the fibers and achieve a higher degree of entangling. We have also found that it is only at the moment of entanglement that a too high initial modulus is of disadvantage. By reducing the initial modulus only during the entangling itself, and thereafter allowing the initial modulus to return to the original level, a method and a material are provided having great advantages over those previously known. There is less need to compromise in the fiber manufacturing process between the properties strength and rigidity. The strength of the fiber can instead be fully optimized. At the same time it is possible to select fibers for the fabric to be bonded, based on other criteria than the limitations placed by the entangling process. In many cases it is an advantage to have stiff fibers in the finished fabric, depending on to what use the material is to be put. Fibers already well adapted to hydroentangling can be further optimized, providing improved material properties and/or lower energy consumption in the process. According to the invention, a process is achieved for hydroentangling of polymer fibers for producing a nonwoven fabric. The polymer fiber is imparted at the moment of hydroentangling, a temperature which is equal to or exceeds the glass transition temperature for the polymer fiber and is below the melting point for the polymer fiber. According to the invention, there is further achieved a hydroentangled fabric comprising polymer fibers, the polymer fibers in the fabric having an initial modulus > 50 cN/tex . Furthermore, according to the invention a hydroentangled polymer fiber fabric is obtained with a bulk specific volume of > 8 cm /g. Additional embodiments are disclosed in the accompanying subclaims. Detailed description of the invention According to the invention the polymer fiber is heated so that at the moment of entanglement it reaches a temperature above the glass transition temperature (Tg) of the polymer fiber. At this temperature the mobility in the molecules increases to such a degree that the stiffness is dramatically affected and a reduction in the modulus of elasticity or initial modulus by up to several powers of 10 can be obtained. The mechanical properties of synthetic polymers are changed dramatically at the glass transition temperature of the polymer. By momentarily heating the desired fiber to the glass transition temperature or slightly thereabove at hydroentangling, the flexural rigidity and the degree of entangling in the fiber fabric are increased. Many different types and mixtures of polymer fibers can be used. Of particular pre- ference according to the invention is a nonwoven fabric which completely or partially comprises synthetic polymer fibers, or mixtures or copolymers of such polymer fibers. Based primarily on the purpose of the nonwoven fabric, the type of fiber and the percentage of natural fiber are selected. The greater the percentage of synthetic polymers included in the nonwoven fabric, the greater are the possibilities. Examples of fibers which can be used in the material according to the present invention are synthetic staple fibers, synthetic continuous fibers, staple fibers of regenerated cellulose, natural fibers such as plant fibers, pulp fibers or mixtures thereof. Examples of commercially available fibers of regenerated cellulose are rayon, viscose and lyocell. Examples of synthetic fibers are fibers of polyester, polylactic acid , polyamide. polypropylene, polybutylene terephthalat (PBT), polyethylene (PE), polyethylene terephthalat (PET) and copolymers thereof, such as polyesteramides. Bicomponent fibers, i.e. fibers having a core of a first polymer, e.g. PET, and a casing of a second polymer, e.g. PE, may be used. The synthetic polymer fibers can comprise both polymer fibers made of natural fibers and polymer fibers made of synthetic fibers. Even continuous filaments, such as melt-blown and spun-bond fibers can be used as well as profiled so-called capillary fibers. These profiled fibers are often very stiff and nor-mally difficult to handle, but can be entangled with the aid of the present invention. Even mixtures of these different fibers can be used. A typical mixture is 40-50% long, synthetic fibers and the rest pulp, but all mixtures are applicable. The pulp fibers can be of chemical, mechanical, thermomechanical, chemomechanical or chemothermomechanical pulp (CTMP). Mixing in of mechanical, thermomechanical, chemomechanical or chemothermomechanical pulp fibers provides a material with higher bulk and improved absorption and softness, which is described in SE 9500585-6. According to the invention, primarily thermoplastic, synthetic polymers and in particular semi-crystalline polymers can be used. Amorphous polymers can also be used. The heating of the polymer fiber at the moment of hydroentangling can be done in many different ways. One method of achieving a momentary temperature rise in the process is to heat the entangling water to such a temperature that the fiber, at the moment of hydroentangling reaches a temperature above Tg. Suitably this process is used when the Tg of the polymer lies below 100°C. This process can also be used at Tg-temperatures above 100°C, but will then require special equipment to produce superheated steam. A further method of heating the fiber can be by IR-heating, e.g. by IR-radiation of the fiber web, or alternatively of the entangling water. Other radiation heating can be used or microwave heating. A further possibility is to use metal wires, e.g. of copper, which is heated up with the aid of hot air, hot water or another medium or a combination thereof. The hydroentangling can be done starting from either a dry-laid or a wet-laid fiber web. In dry-forming, the dry fibers are air-laid on a wire, whereafter the fiber web is subjected to hydroentangling. In wet-laying, a wet- or foam- formed web is made by the fibers being dispersed in liquid or in a foam liquid containing a foam-forming tenside and water. An example of a suitable foam- forming process of this type is described in SE 9402470-0. The fiber dispersion can be dewatered on a wire and thereafter be hydroentangled. The hydroentangling can be effected with conventional equipment. Hydroentangling of a wet- or foam-formed fiber web can be done either in-line, i.e. directly when the fiber web has been dewatered on the wire, or on a wet-formed sheet which has been dried and rolled up after forming. Several such sheets can be laminated together by hydroentangling. It is also possible to combine dry-forming with wet- or foam-forming in such a way that an air-laid web of synthetic fibers, for example, is entangled together with a wet- or foam-formed paper sheet of pulp fibers. After the hydroentangling, the material is pressed and dried and rolled up. The finished material can then be converted in a known manner to a suitable format and be packed. According to one embodiment of the present process, a fiber dispersion is formed of the desired polymer fiber(s). The fiber dispersion is formed on a rotating carrier, e.g. a wire, and when the dispersion has been formed it is subjected to hydro-entangling by water jets striking against the layer of the fiber dispersion and in this manner entangling the fibers. At the moment of hydroentangling at least, the polymer fiber is imparted a temperature exceeding Tg for the polymer fiber, but at the same time being less than its melting point. This is done by heating the water used to produce the hydroentangling, at least during the hydroentangling itself, to a temperature above Tg for the polymer fiber by one of the above ways. Typical energy levels used are 300 - 600 kWh/ton with a water pressure of 80 - 120 bar. Preferably, the present invention is used for polymer fibers with a Tg > 20°C, especially 20 - 100°C, suitably 50 - 100°C and more particularly 50 - 70°C. Tg is preferably below 150°C. A particularly preferred polymer fiber is polylactic acid (PLA), which has a Tg of 50 - 70°C. The reported glass transition temperature for a polymer can vary widely, on one hand due to the fact that glass transition occurs over a temperature interval and not at a certain temperature, and on the other hand depending on what method is used to determine the glass transition temperature. One method which is usable in the present invention to determine the glass transi- tion temperature is DSC (Differential Scanning Calorimetry), which measures the change in enthalpy as a function of temperature. At the glass transition temperature, the enthalpy-temperature curve makes it jump, and the value at this jump gives the glass transition temperature. Another method which is considered more sensitive is DMA (Dynamic Mechanical Analysis). In this method the storage modulus, the loss modulus and tanδ are measured at a frequency (normally 1 Hz) as a function of temperature. At the glass transition temperature, the storage module for an amorphous polymer changes by several orders of ten, while the loss module and tanδ go through maximums. With this method it is also possible to get an idea of how much the modulus changes at the glass transition temperature. The glass transition temperatures of most polymers are given in handbooks well-known to the person skilled in the art. For the purposes of the invention, Tg can be taken from "Polymer Handbook" by J. Brandrup and E.H. Immergut, publisher "Interscience Publishers". Tg can also be derived with the aid of one of the methods DSC or DMA. The method according to the invention is particularly suited to fibers with high flexural rigidity. High flexural rigidity can be achieved either by a high initial modulus value or by high fiber thickness. This means that polymer fibers especially suitable are either fibers with a high initial modulus or very thick polymer fibers, for example a thin fiber with a high initial modulus or a thick fiber with a less pronounced or low initial modulus. Alternatively, fibers which are both thick and have a high initial modulus can be used. The initial modulus for a polymer fiber is expressed in cN/tex. Measurement of the initial modulus value for a fiber can for example be done by measuring the initial slope of a stress-strain diagram from a tensile test performed according to SS-EN ISO 5079. One example of the equipment, which can be used to measure the initial modulus according to the present invention, is a Lenzing Vibro- dyn. With the aid of DMA it is also possible to get an idea of how much the modulus changes at the glass transition temperature. The initial modulus value for the polymer fiber is, in accordance with the present invention, the initial modulus value for the fiber at room temperature (see SS-EN ISO 5079). Fibers of all thicknesses can be used, i.e. both microfibers, fibers of normal thick- ness about 1-2 dtex, and thick fibers about 6-7 dtex. According to a special embodiment, very thick fibers can be entangled to form a fiber fabric with high bulk. According to the invention, new materials are also achieved, i.e. new nonwoven fabrics produced by hydroentangling. Suitably, the polymer fiber has an initial modulus value > 20 cN/tex, especially > 50 cN/tex and most preferably > 100 cN/tex. It is also possible to achieve nonwoven fabrics of polymers with very high initial modulus values, such as 100-2000 cN/tex, especially 500-1500 cN/tex, more particularly 200-750 cN/tex, and even more par- ticularly 250-600 cN/tex. According to one embodiment, the process according to the invention can be used to produce very strong nonwoven fabrics of fibers with very high initial modulus values, e.g. aromatic polyamides and aromatic polyesters. Of special interest is the fact that according to the invention it is possible to manufacture nonwoven fabrics having a high bulk. With the aid of the present method, nonwoven fabrics having very thick fibers, e.g. 6-7 dtex, and which provide a non- woven fabric with very high bulk specific volume, can be manufactured. Thick fibers generally refer to fibers > 5 dtex, but with the aid of such fibers a mate- rial with very high bulk specific volume > 8 cm /g can be achieved in accordance with the present invention. Bulk is expressed as thickness divided by surface weight of the material (cm /g). According to the present invention there are achieved nonwoven fabrics with a bulk specific volume of 5-15 cm /g, especially 8-15 cm /g and more particularly 10-15 cm 3 /g. One example of a nonwoven fabric manufactured with the aid of the present inven- tion is a nonwoven fabric with a very high bulk of 10-50 cm /g, a product, which has very good resilience. 25-50 μm fibers are used in this case. Such fibers, due to their stiffness, are very difficult to entangle by other methods. Such a material is particularly usable as a wicking layer in diapers, but it can be used in a number of different areas, where high bulk and good resilience are desirable properties, such as wipes. It is of particular advantage to be able to make materials of semi-crystalline polymers, with fibers of thick diameter and/or high modulus of elasticity. The nonwoven fabric produced, by being less dependent on the stiffness of the fiber, can provide a nonwoven fabric consisting substantially 100% of the polymer fiber or the fiber mixture, i.e. a fiber to which no softeners or other additives need to be added as might be required to handle a stiff fiber, for example. The present method for manufacturing nonwoven fabrics is thus less dependent than previous methods on the flexural rigidity of the fiber and. as is evident from the above, provide various possibilities to exploit the potential created. New materials with new properties can be made. For example, a fiber can be optimally stretch- ed before hydroentangling so that it is as stiff as possible, and be entangled. Examples of suitable fibers of this type are polyester fibers and polypropylene fibers. By stretching, the breaking strength of these fibers can be increased to impart new properties to the fiber and the nonwoven fabric produced therefrom and with the aid of the present method, such a fiber can be hydroentangled. A fiber pretreated in this manner is often impossible to hydroentangle by today's methods. The significance of the invention is that fibers having greater stiffness and/or greater thickness than what is normally used in hydroentangling. can be entangled to a high degree of entanglement at reasonable energy levels. Alternatively, fibers of normal stiffness and thickness for hydroentangling can be entangled at lower energy levels and/or to a higher degree of entanglement. The method allows nonwoven fabrics containing very thick fibers to be easily entangled and thus achieve a material of high bulk and good resilience. An additional advantage is that material can be manufactured at lower cost since the manufacturing cost of synthetic fibers is dimension-related, decreasing with increasing fiber thickness. An additional advantage is that fibers of very high strength can be entangled into a nonwoven fabric with very good mechanical properties, primarily high wet strength, without the high flexural rigidity of these fibers negatively affecting the degree of entanglement or the energy consumption. In conclusion it can be said that the present invention creates a potential, not only by expanding the number of potential types of fibers as regards polymers and dimensions, but also by making it possible to optimize the fiber components used based on other criteria than limiting the flexural rigidity of the fiber. This potential can be used for improved material properties (increased bulk, resilience, tensile strength, etc.) or reduced costs in the form of lower energy consumption and/or lower cost for the components used. As was mentioned previously, the nonwoven fabric can comprise various mixtures of fibers, including mixtures of non-synthetic fibers. The greater the percentage of synthetic polymer fibers included, the greater will be the possibility of using the free potential achieved. The nonwoven fabric will, of course, also have many different properties, depending on the degree of admixture and the type of fiber. On the whole, the present invention provides greater possibilities for optimizing and using new materials. The nonwoven fabric made according to the present invention can be used as i.a. wiping material for household use or for industrial use, such as major consumers in- eluding shops, industries, hospitals, etc. It can also be used for disposable hospital articles, e.g. operation coats, sheets and the like. It can also be used for hygienic purposes, e.g. as components in absorbent products such as sanitary napkins, panty liners, diapers, incontinence products, bed protectors, surgical dressings, compresses and the like. This is particularly true of nonwoven fabrics made according to the present invention with high wet strength. Nonwoven fabrics of high bulk specific volume are particularly advantageous for use as wicking layers in diapers but also as wiping materials for household use. It is evident from Example 1 below that the tenside strength of the fiber (PLA-fiber) has increased by 20-25% by virtue of the fact that the Tg-temperature was exceeded at hydroentangling. This provides a potential of 20-25%. which can be used in various manners. As can be seen in Example 1, a stronger material can be obtained, but the potential can also be used to provide energy savings and thus savings in costs. EXAMPLE 1 A foam-formed fiber dispersion consisting of 60% pulp fiber of chemical sulphate pulp and 40% thermoplastic synthetic fiber (1.7 dtex, 19 mm) was formed on a rotating wire. The fiber dispersion was hydroentangled from one side at an ener-gy input of 300 kWh/ton. The trial encompassed 3 different variants (Trials 1, 2 and 3) of polylactic acid fiber (with Tg = 50-70°C) and polyamide 6 (PA, with Tg - 50 °C; trial 5) as thermoplastic synthetic fiber. At every trial, hydroentangling was performed both with water at room temperature (20°C) and with water heated to 75°C. As a comparison a trial (trial 4) was made according to the same method with a fiber of polyethylene terephthalat (Tg = 85°C). The tensile strength in dry and wet states (water and tenside solutions) as well as elongation, surface weight, bulk, etc. were measured and the values are displayed in Table 1 below. Tg was measured with the aid of a Perkin Elmer DSC 7 and the measurement was done from room temperature to 50°C over the melting point. The values of initial modulus were obtained in the following manner. The tensile test was performed on a Lenzing Vibrodyn with a pulling speed of 50 mm/min. and a gauge length of 10 mm. A weight of 100 mg was used to pretension the fiber. The initial modulus was calculated manually by drawing in the tangent to the tensile testing curves in the linear range. The values of the initial modulus given in the table are at room temperature. In the dry state, the fibers have a relatively high friction against each other and the dry strength of the nonwoven fabric largely depends on the mechanical properties of the individual fibers, such as tenacity, elongation and initial modulus. As can be seen in Table 1 , the strength in the dry state is hardly affected at all or to a lesser extent, which indicates that the fibers have reassumed their original mechanical properties after the momentary heat treatment to which they were subjected. When tensile tests are performed in water, the fibers will slide more easily against each other and the degree of mechanical bonding (entangling) will assume greater importance for the mechanical properties of the nonwoven fabric. Table 1 shows that for all of the trials the tensile index was somewhat greater for those materials which have been hydroentangled with hot water. For tensile testing in the tenside solution, the friction between the fibers was essentially removed, and this made the degree of entanglement the dominant factor for the mechanical properties of the nonwoven fabric. As is evident from Table 1, there is a significant increase of between 20 and 25% for PLA and more than 50 % for PA in the tensile index when the material was hydroentangled in hot water. The values of the stiffness index were essentially unchanged (certain of them have increased somewhat, certain have decreased somewhat) and this shows that the type of bonding is unchanged. If the increase in the tenside strength were dependent on the fact that the fibers had been thermally bonded to each other during the heat treatment, this would also be revealed as a dramatic increase in the rigidity index. In order to achieve thermobonding of polylactic acid, significantly higher temperatures are required however. What has been achieved is thus a nonwoven fabric where the fibers have their original mechanical values, but where the structure has been changed in such a way that the fibers have been entangled to a higher degree. o © W ^ Λ. H U r~- V© o

Claims: CLAIMS 1. Method of hydroentangling polymer fibers to manufacture a nonwoven fabric, characterized in that the polymer fiber, at the moment of hydroentangling, is imparted a temperature equal to or exceeding the glass transition temperature (Tg) of the polymer fiber and being less than the melting point of the polymer fiber. 2. Method according to Claim 1. characterized in that the polymer fiber has an initial modulus > 50 cN/tex. at room temperature. 3. Method according to Claim 1. characterized in that the polymer fiber has an initial modulus > 100 cN/tex, at room temperature. 4. Method according to Claim 3, characterized in that the polymer fiber has an initial modulus of 100 - 2000 cN/tex, especially 500 - 1500 cN/tex, more particularly 200 - 750 cN/tex, and even more particularly 250 - 600 cN/tex, at room temperature. 5. Method according to one of Claims 1 - 4, characterized in that the temperature is achieved with the aid of hot or superheated water. 6. Method according to one of Claims 1 - 4, characterized in that the temperature is achieved with the aid of IR-heat. 7. Method according to one of Claims 1 - 4, characterized in that the temperature is achieved with the aid of microwaves. 8. Method according to one of Claims 1 - 7, characterized in that the polymer fi- ber has a glass transition temperature (Tg) of > 20°C. . Method according to one of Claims 1 - 8, characterized in that the poly er fiber has a glass transition temperature (Tg) of 20 - 100°C, especially 50 - 70°C. 10. Method according to one of Claims 1 - 9, characterized in that the polymer included in the polymer fibers comprises polyester, polylactic acid , polyamide or polypropylene, or copolymers or mixtures thereof. 11. Hydroentangled nonwoven fabric comprising polymer fibers, characterized in that the polymer fibers in the nonwoven fabric have an initial modulus > 50 cN/tex, at room temperature. 12. Nonwoven fabric according to Claim 10, characterized in that the polymer fibers in the nonwoven fabric have an initial modulus of 100 - 2000 cN/tex, especially 500 - 1500 cN/tex, more particularly 200 - 750 cN/tex, and even more particularly 250 - 600 cN/tex, at room temperature. 13. Nonwoven fabric according to one of Claims 10 - 1 1, characterized in that the polymer fibers in the nonwoven fabric have a glass transition temperature (Tg) of > 20°C. 14. Nonwoven fabric according to Claim 12, characterized in that the polymer fibers in the nonwoven fabric have a glass transition temperature (Tg) of 20 - 100°C, especially 50 - 70°C. 15. Nonwoven fabric according to one of Claims 10 - 13, characterized in that the nonwoven fabric has a bulk specific volume of > 8 cm /g. 16. Nonwoven fabric according to Claim 14, characterized in that the nonwoven fabric has a bulk specific volume of 8 - 15 cm /g, especially 10 - 15 cm /g. 7. Nonwoven fabric according to one of Claims 10 - 15, characterized in that the polymer included in the polymer fibers comprises polyester, polylactic acid , poly-amide or polypropylene, or copolymers or mixtures thereof.

Inventors: FINGAL LARS, STRAALIN ANDERS, FINGAL, LARS, STRAALIN, ANDERS
Applicants: FINGAL LARS, SCA HYGIENE PROD AB, STRAALIN ANDERS, FINGAL, LARS, SCA HYGIENE PRODUCTS AB, STRAALIN, ANDERS
Application year: 2000
Main classification: D04H1
IPC codes: D04H1