Cubic boron nitride powder suitable for production of cutting tools and method for its production

Abstract: The present invention relates to a method of making a PCBN cutting tool insert. The method includes the following steps: mixing raw material powders containing cBN and one or more of hBN, TiC, TiN, Ti(C,N), WC, W, C, Co, Co 2 Al 9 , Al, AlN, Al 2 O 3 with a suitable liquid (e.g. ethanol) and a suitable agent (e.g. polyethylene glycol, PEG) to form a homogeneous slurry with desired composition forming spherical powder agglomerates, typically 100 µm in diameter, preferably by spray drying filling the PCBN powder into recesses, pockets, grooves etc of a cemented carbide or cermet substrate. causing the PCBN powder to be sintered together and simultaneously bonded to the substrate inside a container under HP/HT-conditions to form a composite body.

Description: The present invention relates to a cubic boron nitride powder suitable for subsequent production of cutting tools and method for its production. Cutting tools having cutting edges formed of a superhard abrasive such as a cubic boron nitride (cBN) based material are manufactured by powder metallurgical techniques and are mainly used for the machining of cast iron and hardened steel. For cast iron a tough material with 80-100 wt% cBN is used, while for hardened steel 10-50 wt% of TiC, TiN or Ti(C,N) is usually added. This decreases toughness but greatly improves the chemical stability of the material. Most often, the PCBN material also contains smaller amounts (typically <10 wt% of each, in total <25 wt-%) of other components, e.g. Co, Ni, WC, Al, AlN, and Al 2 O 3 . These are either added to the raw material powder or obtained during processing. PCBN cutting tools are mainly produced in two different ways: i) By high pressure/high temperature (HP/HT) sintering a PCBN powder mixture into a solid body that is cut and ground into a finished cutting tool insert. ii) By HP/HT sintering a thin layer of PCBN powder which simultaneously bonds to a substrate (usually a cemented carbide disc), from which smaller pieces (chips) are cut out. These chips are brazed onto a regular cemented carbide tool (e.g. insert, end-mill, drill) and ground to finished state. The tools are relatively expensive to produce due to the many steps they must undergo before they are finished. Also, usually only one or two cutting edges per tool are available. Through US 5,676,496 a technique is known for producing PCBN cutting tool inserts in a more cost efficient way. This is achieved by placing a cemented carbide or cermet substrate into a container and then packing PCBN powder into appropriately placed grooves in the substrate. The container is then HP/HT-sintered so that the PCBN powder is consolidated to a fully dense body, which is simultaneously bonded to the substrate. The substrate/PCBN compound may then directly be ground to a cutting tool insert. Although the method described leads to extensive cost reductions per cutting edge, it has one major drawback in that the packing of a powder mixture containing PCBN into the grooves in principle must be done manually. The poor flow properties of PCBN powder in combination with the required groove geometry make automatic processing unreliable. Apart from obvious health hazards, manual packing may lead to uneven packing density and to excessive oxygen exposure of the PCBN powder. The uneven packing density makes it necessary to choose a larger groove dimension than desired to ensure that the amount of PCBN obtained is always sufficient. Careful control of the oxygen content in the PCBN powder is critical for the HP/HT sintering since excessive oxygen affects the consolidation process negatively. In principle, one would like to have a high and highly reproducible packing density and minimize the oxygen pickup during handling and storage. According to the present invention, there is provided a PCBN containing powder with good flow properties. The powder is particularly suitable to make bodies in complicated shapes with tight tolerances and highly reproducible green body density. According to the method of the invention the making of a powder suitable for producing the material described above, comprises the following steps: 1. Mixing raw material powders i.e. cBN and one or more of hBN(hexagonal boron nitride), TiC, TiN, Ti(C,N), WC, W, C, Co, Co 2 Al 9 , Al, AlN, Al 2 O 3 with a suitable liquid (e.g. ethanol) and a suitable agent (e.g. polyethylene glycol, PEG) to form a homogeneous slurry with desired composition. The amount of TiC+TiN+Ti(C,N) is <50 wt% and the amount of other additions is <25 wt-%. 2. Forming spherical powder agglomerates typically 100 µm in diameter with good flow properties using the spray drying technique. 3. Filling the PCBN powder into recesses, pockets, grooves etc of a cemented carbide or cermet substrate. 4. Removing said agent from the powder at a suitable temperature and atmosphere (preferably 200-400 °C in flowing hydrogen for PEG). 5. Causing the PCBN powder to be sintered together and simultaneously bonded to the substrate inside a container under HP/HT-conditions to form a composite body e.g. a cutting tool insert. The method has been described with reference to PCBN but it is obvious that it can be used also using diamond as the abrasive material or mixtures thereof.

Claims: Method of making a PCBN cutting tool insert characterised in mixing raw material powders i.e. cBN and one or more of hBN, TiC, TiN, Ti(C,N), WC, W, C, Co, Co 2 Al 9 , Al, AlN, Al 2 O 3 with a suitable liquid (e.g. ethanol) and a suitable agent (e.g. polyethylene glycol, PEG) to form a homogeneous slurry with desired composition forming spherical powder agglomerates, typically 100 µm in diameter, preferably by spray drying filling the PCBN powder into recesses, pockets, grooves etc of a cemented carbide or cermet substrate removing said agent from the powder at a suitable temperature and atmosphere causing the PCBN powder to be sintered together and simultaneously bonded to the substrate inside a container under HP/HT-conditions to form a composite body. Powder comprising PCBN characterised by spherical powder agglomerates, typically 100 µm in diameter.

Inventors: ROLANDER ULF, WEINL GEROLD, ROLANDER, ULF, WEINL, GEROLD
Applicants: SANDVIK AB, SANDVIK AKTIEBOLAG
Application year: 2000
Main classification: C04B35
IPC codes: C22C29, B23P15, C04B37, C04B35, B22F7, B23B27