ELECTRICALLY CONDUCTIVE FORMING PASTE

Abstract: A forming paste, for example in the form of a sprayable putty, wherein the composition substantially consists of a binder and an electrically conductive component in such an amount that a signal attenuation of at least -30 dB or higher takes place in the range of 30 MHz - 1 Ghz in the electromagnetic interference measurement according to the EMC IEC 11.9.1 standard.

Description: ELECTRICALLY CONDUCTIVE FORMING PASTE The invention relates to a forming paste, for example in the form of a sprayable putty, wherein the composition substantially consists of a binder and an electrically conductive component. Such forming pastes are well-known. US patent US 4,279,783 relates to electrically conductive silicone elastomers wherein the addition of a small amount of carbon fibres enhances the electrical conductivity. The problem of these prior art forming pastes is the (relatively) high electrical resistance value thereof. Other conductive fillers can be added to the forming paste so as to reduce said resistance value. This is not desirable, however, as it causes the viscosity to increase to such an extent that such a forming paste is no longer suitably workable for a great many purposes. It is an object of the invention to provide a forming paste, preferably in sprayable form, which forming paste is suitable for filling a space within a steel housing containing cables for the purpose of electrically connecting said cables to the housing as protection against electromagnetic overtension and/or interference. Thus the forming paste will form a bushing device to protect against electromagnetic overtension and/or interference. Another object of the invention is to provide a fire- resistant, electrically conductive paste which is chemically resistant and which can easily be used, in particular as a bushing device for any type of cable diameter and a non-predetermined number of cables. To this end the invention provides a forming paste which is composed so that a signal attenuation of at least -30 dB or higher takes place in the range of 30 MHz - 1 Ghz in the electromagnetic interference measurement according to the EMC IEC 11.9.1 standard. In order to accomplish the above objectives, the invention furthermore provides a forming paste wherein the binder is selected from the group of elastomers, preferably silicones, and wherein the electrically conductive material is carbon-based, preferably expandable graphite, since this form of graphite also exhibits fire-resistance. Said binder and said form of carbon are advantageous with a view to achieving a low resistance value and a good viscosity. More preferably, oil and/or other agents, such as anti-static agents and viscosity-reducing agents, are added, as a result of which in particular a good workability is obtained. Preferred embodiments of the forming paste are defined in claims 2 - 13. Surprisingly, the invention provides a forming paste which has a suitable viscosity, as a result of which it is capable of being sprayed, thus enabling a wide range of applications, and which has a surprisingly low resistance value. The forming paste according to one preferred embodiment of the invention will be marketed under the name of CONDUCTON * , which is a brand name of Beele Engineering B.V. Said CONDUCTON e forming paste has additional properties : - specific weight 1.4 ± 0.03 g/cm 3 - tensile strength 0.8 MPa - elongation at break 40% - hardness 30 Shore A - elasticity approx. 25% and in addition it adheres well to metal surfaces, such as steel, zinc and copper. The resistance of CONDUCTON " forming paste is less than 100 ohms and in addition it is water repellent . One preferred use is the use of the forming paste as a bushing device for at least one cable to provide protection against electromagnetic overtension and or interference. A bushing device in the form of an non-deformable plug provided with holes is disclosed in the present applicant's Dutch patent application Nl-1008522. Said plugs are limited in use both by the number of bores and by the diameter thereof, which bores are formed in advance, so that the plug cannot be adapted any more once it has been manufactured. The object of the invention is to provide a bushing device which exhibits a high degree of adaptability. This object is accomplished by using the forming paste according to the invention as a bushing device. Electrical installations and machines, wherein generally highly sensitive components are used for control and registration purposes, are easily subject to interference by various external electromagnetic fields and pulses. Said external electromagnetic fields and pulses cause a great deal of malfunctions, which are undesirable, and they are usually enclosed via steel constructions, which function as a Faraday cage. Electrical cables, which are led in and out of such a shielded space, can conduct undesirable electromagnetic fields and pulses into the electronic equipment as yet, however. Said conduction will generally take place over an electrically conductive shield (braiding) of the respective cables that are led through. Because of this, the cable is partially stripped of its insulation sheath and is earthed via the forming paste according to the invention and its housing. The prior art bushing plug is pre-formed, however, so that the diameter of the cables 5 and of the bushing channel as well as the number of cables need to be determined in advance. The use of the present forming paste as a bushing device provides an adaptable mass, so that neither the 10 dimension of a bushing channel nor the number of cables need to be known in advance . Preferred embodiments of the composition of a forming paste according to the invention are shown below on a 15 weight basis. Possible trade names of the products that are used are: Silicone putty Rhone Poulenc CAF22 20 Silicone oil Rhodosil 47/V100 Expandable graphite Callotek 500 CB 140E Kynol 0185 Anjay metachem S-15 L120 25 Antistatic agent Kenstat KS MZ 100 Kenstat KS N100 Viscosity-reducing agent Ken-react KR TTS Ken-react KR 46B • 3 n An example of a formula is (% by weight) Rhone Poulenc CAF 22 100 (75 - 100) Rhodorsil 47/V100 75 (50 - 100) Kenstat KS N100 4 (2 - 4) Callotec 500 CB 140E 175 (150-200) Experiment The electrical conductivity of a forming paste according to the invention was measured by experiment . The electrical resistance was less than 1,000 ohms at all times, and preferably less than 100 ohms. The resistance values are determined via ISO 2878 standard methods in all cases. A sample plate dimensioned 100 x 100 x 10 mm was used for determining the resistance value. Square electrodes dimensioned 25 x 25 mm, which were spaced 50 mm apart, were applied to the surface of the test piece by means of Aquadag (a colloidal suspension of carbon in water) . Resistance values of 80 - 90 Ohms and even lower were recorded. The invention, in one special embodiment thereof, relates to the use of the electrically conductive forming paste in a multi-cable bushing, which use will be understood more clearly when studied in conjunction with the appended drawing. In the drawing, a bushing channel 1 in a housing 2 contains a number of (possibly multi-conductor) cables 3. Said cables 3 are stripped of their sheath along a suitable portion of their length so as to place them into electrically conductive contact with their surroundings. Said portion 4 of the length of cable 3 will then be embedded with the conductive forming paste 5 so as to provide conduction between cables 3 and housing 1. Subsequently, a suitable sealing putty 6 is provided. In addition, cables 3 may be provided with so- called RISE e (brand name of Beele Engineering B.V.) hose portions 7, which are divided lengthways, so that they can be fitted after said cables 3 have been pulled through the bushing 1. Filling hoses are used to fill the remaining space in bushing 1. Possibly, a so-called blind section 8 can be fitted in bushing 1 in order to be used for positioning empty hose portions in bushing 1. Said blind sections 8 can be simply removed when cables 3 are fitted in their place. Said blind sections 8 are electrically conductive and they may be provided with a marking colour. The bushing 1 which is shown in the drawing provides a high-quality, fire-resistant, gas and watertight bushing device, which is also protected against electromagnetic overtension and/or interference. It stands to reason that the variations of the use described herein are possible, but the final positioning of the forming paste 5 is advantageous as regards use and accessibility.

Claims: CLAIMS 1. A forming paste, for example in the form of a sprayable putty, wherein the composition substantially consists of a binder and an electrically conductive component in such an amount that a signal attenuation of at least -30 dB or higher takes place in the range of 30 MHz - 1 Ghz in the electromagnetic interference measurement according to the EMC IEC 11.9.1 standard. 2. A forming paste according to claim 1, characterized in that said attenuation of the signal exceeds -60 dB. 3. A forming paste according to claim 1 or 2, characterized in that said forming paste is electrically conductive and has a resistance of less than 1,000 ohms, preferably less than 100 ohms . 4. A forming paste according to claims 1 - 3, wherein the forming paste is electrically conductive and has a resistance of less than 100 ohms. A forming paste according to claims 1 - 4, wherein said binder has been selected from the group of elastomers and wherein said electrically conductive material is carbon-based. 6. A forming paste according to claims 1 - 5, characterized in that said binder is a silicone rubber and wherein said electrically conductive material is graphite, preferably expandable graphite. 7. A forming paste according to claim 6, characterized in that said electrically conductive material forms 40 - 60 % by weight of the entire composition. 8. A forming paste according to any one of the preceding claims, characterized in that furthermore a plasticizer, such as a silicone oil, has been added to the composition. 9. A forming paste according to any one of the preceding claims, characterized in that an antistatic agent has been added to the paste . 10. A forming paste according to any one of the preceding claims, characterized in that a viscosity-reducing agent has been added to the forming paste. 11. A forming paste according to any one of the preceding claims, characterized in that said silicone rubber and said conductive material are present in equal quantities by weight in the forming paste. 12. A forming paste according to any one of the preceding claims, characterized in that the composition of the forming paste is as follows (in per cent by weight) : - silicones + silicone oil 40 - 60 % by weight - graphite 60 - 40 % by weight - anti-static agents 0 - 3 % by weight - viscosity-reducing agents 0 - 3 % by weight. 13. A forming paste according to any one of the preceding claims having a viscosity which makes it possible to spray said forming paste. 14. Use of a forming paste according to any one of the preceding claims for filling a space in a steel housing in which at least one cable is present, so as to provide protection against electromagnetic overtension and/or interference. 15. Use according to claim 15, characterized in that several cables of different diameters are present in said space. 16. A method for producing a forming paste according to any one of the claims 1 - 13, wherein 40 - 60 % by weight (of the entire composition) of carbon-based electrically conductive parts are mixed in intimate contact with a binder selected from the group of elastomers. 17. A method according to claim 16, characterized in that a plasticizer is mixed with the composition of a binder and an electrically conductive material in a quantity of the same order as the quantities of binder and electrically conductive material.

Inventors: BEELE JOHANNES ALFRED, BEELE, JOHANNES, ALFRED
Applicants: BEELE ENG BV, BEELE JOHANNES ALFRED, BEELE ENGINEERING B.V., BEELE, JOHANNES, ALFRED
Application year: 2000
Main classification: C08K7
IPC codes: C09J9, C09J201, H01B1, H05K9