Process for producing particles of amine reaction product

Abstract: There is provided a process for producing particles of amine reaction product by means of an acid carrier. Processed amine reaction products and finished compositions incorporating such processed product are also herein provided.

Description: The present invention relates to a process for producing particles of amine reaction product salt. Background of the invention Perfumed products are well-known in the art. However, consumer acceptance of such perfumed products like laundry and cleaning products is determined not only by the performance achieved with these products but also by the aesthetics associated therewith. The perfume components are therefore an important aspect of the successful formulation of such commercial products. It is also desired by consumers for treated fabrics to maintain the pleasing fragrance over time. Indeed, perfume additives make such compositions more aesthetically pleasing to the consumer, and in some cases the perfume imparts a pleasant fragrance to fabrics treated therewith. However, the amount of perfume carried-over from an aqueous laundry bath onto fabrics is often marginal and does not last long on the fabric. Furthermore, fragrance materials are often very costly and their inefficient use in laundry and cleaning compositions and ineffective delivery to fabrics results in a very high cost to both consumers and laundry and cleaning manufacturers. Industry, therefore, continues to seek with urgency for more efficient and effective fragrance delivery in laundry and cleaning products, especially for improvement in the provision of long-lasting fragrance to the fabrics. It has recently been found that an amine reaction product of a compound containing a primary amine functional group and an active ketone or aldehyde containing component fulfills such a need. Disclosure of such compounds can be found in recently filed applications EP 98870227.0, EP 98870226.2, EP 99870026.4, and EP 99870025.6. However, a problem now encountered with the use of these compound is their ease of incorporation into fully formulated compositions. Indeed, such amine reaction products are often viscous which renders their incorporation into these fully formulated compositions more cumbersome. It is therefore an object of the invention to provide amine reaction product in a form suitable for easy incorporation into fully formulated composition. It has now been found that the mixing of the amine reaction product with an acid carrier fulfills such a need. Further, it has also been advantageously found that such viscous amine reaction product when processed by the present invention exhibit better deposition and long lasting release than amine reaction product which have not been processed according to this process. Not to be bound by theory, it is believed that the mixing with such carrier acts as a shell around the amine reaction product, thus protecting it from the aggressive wash liquor as well as enhancing its fabric deposition properties. By "viscous", it is meant a product which has a viscosity higher than 1000 cps. The viscosity is measured on a rheometer, TA Instrument CSL 2 100 at a temperature of 25C with a gap setting of 500 microns. By "acid carrier", it is meant a carrier which forms a salt with the amine reaction product. Not to be bound by theory, it is believed that the salt formation occurs by reacting the amine reaction product with an acid. The salt formation takes place via a reaction of the acid at the nitrogen of the β-aminoketone or imine function. Still, and also preferred, the salt formation may also take place at other nucleophilic centers of the amine or amine reaction product. Indeed, it is believed that when the salt formation takes place at the nucleophilic center of the primary amine, the link nitrogen-active tends to be more labile and therefore may liberate the perfume in-situ. Typical examples of such other suitable nucleophilic centers are the tertiary and secondary amine functions in polyethylenimine polymers. Summary of the invention The present invention is a process for making particles of salts of an amine reaction product of a selected type of amine compound containing a primary and/or secondary amine functional group and an active ketone or aldehyde containing component, and which comprises the steps of : a)-providing the amine reaction product, having a viscosity greater than 1000 cps., and b)-mixing therewith an anhydrous acid carrier to thereby form a salt of said amine reaction product, and c)-thereafter forming said salt of said amine reaction product into particles. In a preferred embodiment of the invention, the obtained amine reaction product is further processed to form a coated particle. In another aspect of the invention, the obtained particle or coated particle is incorporated in a finished composition. The selected types of amine compounds which can be used are described hereinafter. Detailed description of the invention Starting materials 1)-Amine reaction product The amine reaction product for use herein is a product of reaction between a compound containing a primary and/or secondary amine functional group and an active ketone or aldehyde containing component, so called hereinafter "amine reaction product". A typical disclosure of amine reaction product suitable for use herein can be found in recently filed applications EP 98870227.0, EP 98870226.2, EP 99870026.4, and EP 99870025.6. A-Primary and/or secondary amine By "primary and/or secondary amine", it is meant a component which carries at least one primary and/or secondary amine and/or amide function. Preferably, the primary and/or secondary amine compound is also characterized by an Odour Intensity Index of less than that of a 1% solution of methylanthranilate in dipropylene glycol. Odour Intensity Index method By Odour Intensity Index, it is meant that the pure chemicals were diluted at 1% in Dipropylene Glycol, odor-free solvent used in perfumery. This percentage is more representative of usage levels. Smelling strips, or so called "blotters", were dipped and presented to the expert panellist for evaluation. Expert panellists are assessors trained for at least six months in odor grading and whose gradings are checked for accuracy and reproducibility versus a reference on an on-going basis. For each amine compound, the panellist was presented two blotters: one reference (Me Anthranilate, unknown from the panellist) and the sample. The panellist was asked to rank both smelling strips on the 0-5 odor intensity scale, 0 being no odor detected, 5 being very strong odor present. Results: The following represents Odour Intensity Index of an amine compound suitable for use in the present invention and according to the above procedure. In each case, numbers are arithmetic averages among 5 expert panellists and the results are statistically significantly different at 95% confidence level: Methylanthranilate 1% (reference) 3.4 Ethyl-4-aminobenzoate (EAB) 1% 0.9 A general structure for the primary amine compound of the invention is as follows: B-(NH2) n ; wherein B is a carrier material, and n is an index of value of at least 1. Compounds containing a secondary amine group have a structure similar to the above excepted that the compound comprises one or more -NH- groups instead of -NH2. Further, the compound structure may also have one or more of both -NH2 and -NH- groups. B carriers are organic carriers. The primary and/or secondary amines, which are useful herein are those selected from polyamines, amino acids and derivatives thereof, substituted amines and amides, glucamines, dendrimers, polyvinylamines and derivatives thereof, and/or copolymer thereof, alkylene polyamine, polyaminoacid and copolymer thereof, cross-linked polyaminoacids, amino substituted polyvinylalcohol, polyoxyethylene bis amine or bis aminoalkyl, aminoalkyl piperazine and derivatives thereof, bis (amino alkyl) alkyl diamine linear or branched, and mixtures thereof. Polyamines suitable for use in the present invention are polyethyleneimines polymers, poly[oxy(methyl-1,2-ethanediyl)], α-(2-aminomethylethyl)-ω-(2-aminomethyl-ethoxy)- (= C.A.S No. 9046-10-0); poly[oxy(methyl-1,2-ethanediyl)], α-hydro-)-ω-(2-aminomethylethoxy)-, ether with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol (= C.A.S. No. 39423-51-3); commercially available under the tradename Jeffamines T-403, D-230, D-400, D-2000; 2,2',2"-triaminotriethylamine; 2,2'-diamino-diethylamine; 3,3'-diaminodipropylamine, 1,3 bis aminoethyl-cyclohexane commercially available from Mitsibushi and the C12 Sternamines commercially available from Clariant like the C12 Sternamin(propylenamine) n with n=3/4, and mixtures thereof. Preferred polyamines are polyethyleneimines commercially available under the tradename Lupasol like Lupasol FG (MW 800), G20wfv (MW 1300), PR8515 (MW 2000), WF (MW 25000), FC (MW 800), G20 (MW 1300), G35 (MW 1200), G100 (MW 2000), HF (MW 25000), P (MW 750000), PS (MW 750000), SK (MW 2000000), SNA (MW 1000000). Preferred amino acids for use herein are selected tyrosine, tryptophane, lysine, glutamic acid, glutamine, aspartic acid, arginine, asparagine, phenylalanine, proline, glycine, serine, histidine, threonine, methionine, and mixture thereof, most preferably selected from tyrosine, tryptophane, and mixture thereof. Preferred amino acid derivatives selected from tyrosine ethylate, glycine methylate, tryptophane ethylate, and mixture thereof. Preferred substituted amines and amides for use herein are selected from nipecotamide, N-coco-1,3-propenediamine; N-oleyl-1,3-propenediamine; N-(tallow alkyl)-1,3-propenediamine; 1,4-diamino cyclohexane; 1,2-diaminocyclohexane; 1,12-diaminododecane, and mixtures thereof. Other primary amine compounds suitable for use herein are the glucamines, preferably selected from 2,3,4,5,6-pentamethoxy-glucamine; 6-acetylglucamine, glucamine, and mixture thereof. Also preferred compounds are the polyethylenimine and/or polypropylenimine dendrimers and the commercially available Starburst® polyamidoamines (PAMAM) dendrimers, generation G0-G10 from Dendritech and the dendrimers Astromols®, generation 1-5 from DSM being DiAminoButane PolyAmine DAB (PA)x dendrimers with x = 2"x4 and n being generally comprised between 0 and 4. Still other preferred primary and/or secondary amine containing compounds are amino-functional polymers. Preferred amino-functional polymers for use in the present invention are selected from the polyvinylamines, derivatives thereof, copolymer thereof, alkylene polyamine, polyaminoacids and copolymer thereof, cross-linked polyaminoacids, amino substituted polyvinylalcohol, polyoxyethylene bis amine or bis aminoalkyl, aminoalkyl piperazine and derivatives, N,N'-bis-(3-aminopropyl)-1,3-propanediamine linear or branched (TPTA), and mixtures thereof. Polyamino acid is one suitable and preferred class of amino-functional polymer. Polyaminoacids are compounds which are made up of amino acids or chemically modified amino acids. They can contain alanine, serine, aspartic acid, arginine, valine, threonine, glutamic acid, leucine, cysteine, histidine, lysine, isoleucine, tyrosine, asparagine, methionine, proline, tryptophan, phenylalanine, glutamine, glycine or mixtures thereof. In chemically modified amino acids, the amine or acidic function of the amino acid has reacted with a chemical reagent. This is often done to protect these chemical amine and acid functions of the amino acid in a subsequent reaction or to give special properties to the amino acids, like improved solubility. Examples of such chemical modifications are benzyloxycarbonyl, aminobutyric acid, butyl ester, pyroglutamic acid. More examples of common modifications of amino acids and small amino acid fragments can be found in the Bachem, 1996, Peptides and Biochemicals Catalog. Preferred polyamino acids are polylysines, polyarginine, polyglutamine, polyasparagine, polyhistidine, polytryptophane or mixtures thereof. Most preferred are polylysines or polyamino acids where more than 50% of the amino acids are lysine, since the primary amine function in the side chain of the lysine is the most reactive amine of all amino acids. The preferred polyamino acid has a molecular weight of 500 to 10.000.000, more preferably between 5.000 and 750.000. The polyamino acid can be cross linked. The cross linking can be obtained for example by condensation of the amine group in the side chain of the amino acid like lysine with the carboxyl function on the amino acid or with protein cross linkers like PEG derivatives. The cross linked polyamino acids still need to have free primary and/or secondary amino groups left for reaction with the active ingredient. The preferred cross linked polyamino acid has a molecular weight of 20.000 to 10.000.000, more preferably between 200.000 and 2.000.000. The polyamino acid or the amino acid can be co-polymerized with other reagents like for instance with acids, amides, acyl chlorides. More specifically with aminocaproic acid, adipic acid, ethylhexanoic acid, caprolactam or mixture thereof. The molar ratio used in these copolymers ranges from 1:1 (reagent/amino acid (lysine)) to 1:20, more preferably from 1:1 to 1:10. The polyamino acid like polylysine can be partially ethoxylated. Examples and supply of polyaminoacids containing lysine, arginine, glutamime, asparagine are given in the Bachem 1996, Peptides and Biochemicals catalog. The polyaminoacid can be obtained before reaction with the active ingredient, under a salt form. For example polylysine can be supplied as polylysine hydrobromide. Polylysine hydrobromide is commercially available from Sigma, Applichem, Bachem and Fluka. Examples of suitable amino functional polymers containing at least one primary and/or secondary amine group for the purpose of the present invention are : Polyvinylamine with a MW of about 300-2.10E6; Polyvinylamine alkoxylated with a MW of about 600, 1200 or 3000 and an ethoxylation degree of 0.5; Polyvinylamine vinylalcohol - molar ratio 2:1, polyvinylaminevinylformamide - molar ratio 1:2 and polyvinylamine vinylformamide-molar ratio 2:1; Triethylenetetramine, diethylenetriamine, tetraethylenepentamine; Bis-aminopropylpiperazine; Polyamino acid (L-lysine / lauric acid in a molar ratio of 10/1), Polyamino acid (L-lysine / aminocaproic acid / adipic acid in a molar ratio of 5/5/1),), Polyamino acid (L-lysine / aminocaproic acid /ethylhexanoic acid in a molar ratio of 5/3/1) Polyamino acid (polylysine-cocaprolactam); Polylysine; Polylysine hydrobromide; cross-linked polylysine, amino substituted polyvinylalcohol with a MW ranging from 400-300,000; polyoxyethylene bis [amine] available from e.g. Sigma; polyoxyethylene bis [6-aminohexyl] available from e.g. Sigma; N,N'-bis-(3-aminopropyl)-1,3-propanediamine linear or branched (TPTA); and 1,4-bis-(3-aminopropyl) piperazine (BNPP). The more preferred compounds are selected from polyethyleneimine polymers commercially available under the tradename Lupasol like Lupasol FG, G20,wfv, PR8515, WF, FC, G20, G35, G100, HF, P, PS, SK, SNA; the diaminobutane dendrimers Astramol®, polylysine, cross-linked polylysine, N,N'-bis-(3-aminopropyl)-1,3-propanediamine linear or branched; 1,4-bis-(3-aminopropyl) piperazine, and mixtures thereof. Even most preferred compounds are those selected from ethyl-4-amino benzoate, polyethyleneimine polymers commercially available under the tradename Lupasol like Lupasol FG, G20,wfv, PR8515, WF, FC, G20, G35, G100, HF, P, PS, SK, SNA; polylysine, cross-linked polylysine, N,N'-bis-(3-aminopropyl)-1,3-propanediamine linear or branched, 1,4-bis-(3-aminopropyl) piperazine, and mixtures thereof. Advantageously, such most preferred primary and/or secondary amine compounds also provide fabric appearance benefit, in particular colour appearance benefit, thus providing a resulting amine reaction product with the dual properties of both fabric appearance benefit and delayed release of the active. Further, when the primary and/or secondary amine compound has more than one free primary and/or secondary amine group, several different active ingredients (aldehyde and/or ketone) can be linked to the amine compound. B-Active ketone and/or aldehyde Preferably, for the above mentioned compounds, by active ketone or active aldehyde, it is meant any chain containing at least 1 carbon atom, preferably at least 5 carbon atoms. Preferably, the active ketone or active aldehyde is respectively selected from a flavour ketone or aldehyde ingredient, a pharmaceutical ketone or aldehyde active, a biocontrol ketone or aldehyde agent, a perfume ketone or aldehyde component and mixtures thereof; most preferably a perfume ketone and/or aldehyde. Flavour ingredients include spices, flavor enhancers that contribute to the overall flavour perception. Pharmaceutical actives include drugs. Biocontrol agents include biocides, antimicrobials, bactericides, fungicides, algaecides, mildewcides, disinfectants, sanitiser like bleach, antiseptics, insecticides, insect and/or moth repellant, vermicides, plant growth hormones. Typical antimicrobials include Glutaraldehyde, Cinnamaldehyde, and mixtures thereof. Typical insect and/or moth repellants are perfume ingredients, such as citronellal, citral, N, N diethyl meta toluamide, Rotundial, 8-acetoxycarvotanacenone, and mixtures thereof. Other examples of insect and/or moth repellant for use herein are disclosed in US 4,449,987, 4,693,890, 4,696,676, 4,933,371, 5,030,660, 5,196,200, and "Semio Activity of Flavor and Fragrance molecules on various Insect Species", B.D. Mookherjee et al., published in Bioactive Volatile Compounds from Plants , ASC Symposium Series 525, R. Teranishi, R.G. Buttery, and H. Sugisawa, 1993, pp. 35-48. A typical disclosure of suitable ketone and/or aldehydes, traditionally used in perfumery, can be found in "perfume and Flavor Chemicals", Vol. I and II, S. Arctander, Allured Publishing, 1994, ISBN 0-931710-35-5. Perfume ketones components include components having odoriferous properties. Preferably, for the above mentioned compounds, the perfume ketone is selected from buccoxime; iso jasmone; methyl beta naphthyl ketone; musk indanone; tonalid/musk plus; Alpha-Damascone, Beta-Damascone, Delta-Damascone, Iso-Damascone, Damascenone, Damarose, Methyl-Dihydrojasmonate, Menthone, Carvone, Camphor, Fenchone, Alpha-lonone, Beta-lonone, Gamma-Methyl so-called lonone, Fleuramone, Dihydrojasmone, Cis-Jasmone, Iso-E-Super, Methyl- Cedrenyl-ketone or Methyl- Cedrylone, Acetophenone, Methyl-Acetophenone, Para-Methoxy-Acetophenone, Methyl-Beta-Naphtyl-Ketone, Benzyl-Acetone, Benzophenone, Para-Hydroxy-Phenyl-Butanone, Celery Ketone or Livescone, 6-lsopropyldecahydro-2-naphtone, Dimethyl-Octenone, Freskomenthe, 4-(1-Ethoxyvinyl)-3,3,5,5,-tetramethyl-Cyclohexanone, Methyl-Heptenone, 2-(2-(4-Methyl-3-cyclohexen-1-yl)propyl)-cyclopentanone, 1-(p-Menthen-6(2)-yl)-1-propanone, 4-(4-Hydroxy-3-methoxyphenyl)-2-butanone, 2-Acetyl-3,3-Dimethyl-Norbornane, 6,7-Dihydro-1,1,2,3,3-Pentamethyl-4(5H)-lndanone, 4-Damascol, Dulcinyl or Cassione, Gelsone, Hexalon, Isocyclemone E, Methyl Cyclocitrone, Methyl-Lavender-Ketone, Orivon, Para-tertiary-Butyl-Cyclohexanone, Verdone, Delphone, Muscone, Neobutenone, Plicatone, Veloutone, 2,4,4,7-Tetramethyl-oct-6-en-3-one, Tetrameran, hedione, and mixtures thereof. More preferably, for the above mentioned compounds, the preferred ketones are selected from Alpha Damascone, Delta Damascone, Iso Damascone, Carvone, Gamma-Methyl-lonone, Iso-E-Super, 2,4,4,7-Tetramethyl-oct-6-en-3-one, Benzyl Acetone, Beta Damascone, Damascenone, methyl dihydrojasmonate, methyl cedrylone, hedione, and mixtures thereof. Perfume aldehyde components include components having odoriferous properties. Preferably, for the above mentioned compounds, the perfume aldehyde is selected from adoxal; anisic aldehyde; cymal; ethyl vanillin; florhydral; helional; heliotropin; hydroxycitronellal; koavone; lauric aldehyde; lyral; methyl nonyl acetaldehyde; P. T. bucinal; phenyl acetaldehyde; undecylenic aldehyde; vanillin; 2,6,10-trimethyl-9-undecenal, 3-dodecen-1-al, alpha-n-amyl cinnamic aldehyde, 4-methoxybenzaldehyde, benzaldehyde, 3-(4-tert butylphenyl)-propanal, 2-methyl-3-(para-methoxyphenyl propanal, 2-methyl-4-(2,6,6-trimethyl-2(1)-cyclohexen-1-yl) butanal, 3-phenyl-2-propenal, cis-/trans-3,7-dimethyl-2,6-octadien-1-al, 3,7-dimethyl-6-octen-1-al, [(3,7-dimethyl-6-octenyl)oxy] acetaldehyde, 4-isopropylbenzyaldehyde, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde, 2-methyl-3-(isopropylphenyl)propanal, 1-decanal; decyl aldehyde, 2,6-dimethyl-5-heptenal, 4-(tricyclo[5.2.1.0(2,6)]-decylidene-8)-butanal, octahydro-4,7-methano-1 H-indenecarboxaldehyde, 3-ethoxy-4-hydroxy benzaldehyde, para-ethyl-alpha, alpha-dimethyl hydrocinnamaldehyde, alpha-methyl-3,4-(methylenedioxy)-hydrocinnamaldehyde, 3,4-methylenedioxybenzaldehyde, alpha-n-hexyl cinnamic aldehyde, m-cymene-7-carboxaldehyde, alpha-methyl phenyl acetaldehyde, 7-hydroxy-3,7-dimethyl octanal, Undecenal, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 4-(3)(4-methyl-3-pentenyl)-3-cyclohexen-carboxaldehyde, 1-dodecanal, 2,4-dimethyl cyclohexene-3-carboxaldehyde, 4-(4-hydroxy-4-methyl pentyl)-3-cylohexene-1-carboxaldehyde, 7-methoxy-3,7-dimethyloctan-1-al, 2-methyl undecanal, 2-methyl decanal, 1-nonanal, 1-octanal, 2,6,10-trimethyl-5,9-undecadienal, 2-methyl-3-(4-tertbutyl)propanal, dihydrocinnamic aldehyde, 1-methyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde, 5 or 6 methoxy0hexahydro-4,7-methanoindan-1 or 2- carboxaldehyde, 3,7-dimethyloctan-1-al, 1-undecanal, 10-undecen-1-al, 4-hydroxy-3-methoxy benzaldehyde, 1-methyl-3-(4-methylpentyl)-3-cyclhexenecarboxaldehyde, 7-hydroxy-3,7-dimethyl-octanal, trans-4-decenal, 2,6-nonadienal, paratolylacetaldehyde; 4-methylphenylacetaldehyde, 2-methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal, ortho-methoxycinnamic aldehyde, 3,5,6-trimethyl-3-cyclohexene carboxaldehyde, 3,7-dimethyl-2-methylene-6-octenal, phenoxyacetaldehyde, 5,9-dimethyl-4,8-decadienal, peony aldehyde (6,10-dimethyl-3-oxa-5,9-undecadien-1-al), hexahydro-4,7-methanoindan-1-carboxaldehyde, 2-methyl octanal, alpha-methyl-4-(1-methyl ethyl) benzene acetaldehyde, 6,6-dimethyl-2-norpinene-2-propionaldehyde, para methyl phenoxy acetaldehyde, 2-methyl-3-phenyl-2-propen-1-al, 3,5,5-trimethyl hexanal, Hexahydro-8,8-dimethyl-2-naphthaldehyde, 3-propyl-bicyclo[2.2.1]-hept-5-ene-2-carbaldehyde, 9-decenal, 3-methyl-5-phenyl-1-pentanal, methylnonyl acetaldehyde, 1-p-menthene-q-carboxaldehyde, citral, lilial and mixtures thereof. Most preferred aldehydes are selected from citral, 1-decanal, benzaldehyde, florhydral, 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde; cis/trans-3,7-dimethyl-2,6-octadien-1-al; heliotropin; 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde; 2,6-nonadienal; alpha-n-amyl cinnamic aldehyde, alpha-n-hexyl cinnamic aldehyde, P.T. Bucinal, lyral, cymal, methyl nonyl acetaldehyde, trans-2-nonenal, lilial, trans-2-nonenal, and mixture thereof. In the above list of perfume ingredients, some are commercial names conventionally known to one skilled in the art, and also includes isomers. Such isomers are also suitable for use in the present invention. In another embodiment, especially suitable for the purpose of the present invention are the perfume compounds, preferably the perfume ketones or aldehydes, characterised by having a low Odor Detection Threshold. Such Odor Detection Threshold (ODT) should be lower than 1ppm, preferably lower than 10ppb - measured at controlled Gas Chromatography (GC) conditions such as described here below. This parameter refers to the value commonly used in the perfumery arts and which is the lowest concentration at which significant detection takes place that some odorous material is present, as referred to for example in "Compilation of Odor and Taste Threshold Value Data (ASTM DS 48 A)", edited by F. A. Fazzalari, International Business Machines, Hopwell Junction, NY and in Calkin et al., Perfumery, Practice and Principles, John Willey & Sons, Inc., page 243 et seq (1994). For the purpose of the present invention, the Odor Detection Threshold is measured according to the following method : The gas chromatograph is characterized to determine the exact volume of material injected by the syringe, the precise split ratio, and the hydrocarbon response using a hydrocarbon standard of known concentration and chain-length distribution. The air flow rate is accurately measured and, assuming the duration of a human inhalation to last 0.02 minutes, the sampled volume is calculated. Since the precise concentration at the detector at any point in time is known, the mass per volume inhaled is known and hence the concentration of material. To determine the ODT of a perfume material, solutions are delivered to the sniff port at the back-calculated concentration. A panelist sniffs the GC effluent and identifies the retention time when odor is noticed. The average over all panelists determines the threshold of noticeability. The necessary amount of analyte is injected onto the column to achieve a certain concentration, such as 10 ppb, at the detector. Typical gas chromatograph parameters for determining odor detection thresholds are listed below. GC: 5890 Series II with FID detector 7673 Autosampler Column: J&W Scientific DB-1 Length 30 meters ID 0.25 mm film thickness 1 micron Method: Split Injection: 17/1 split ratio Autosampler: 1.13 microliters per injection Column Flow: 1.10 mL/minute Air Flow: 345 mL/minute Inlet Temp. 245°C Detector Temp. 285°C Temperature Information Initial Temperature: 50°C Rate: 5C/minute Final Temperature: 280°C Final Time: 6 minutes Leading assumptions: 0.02 minutes per sniff GC air adds to sample dilution Examples of such preferred perfume components are those selected from : 2-methyl-2-(para-iso-propylphenyl)-propionaldehyde, 1-(2,6,6-trimethyl-2-cyclohexan-1-yl)-2-buten-1-one and/or para-methoxy-acetophenone. Even more preferred are the following compounds having an ODT ≤ 10ppb measured with the method described above : undecylenic aldehyde, undecalactone gamma, heliotropin, dodecalactone gamma, p-anisic aldehyde, para hydroxyphenyl-butanone, cymal, benzyl acetone, ionone alpha, p.t.bucinal, damascenone, ionone beta and methyl-nonyl ketone. Typically the level of active is of from 10 to 90%, preferably from 30 to 85%, more preferably from 45 to 80% by weight of the amine reaction product. Preferred amine reaction products are those resulting from the reaction of polyethyleneimine polymer like Lupasol polymers, BNPP, or TPTA with one or more of the following Alpha Damascone, Delta Damascone, Carvone, Gamma-Methyl-lonone, Hedione, Florhydral, Lilial, Heliotropine, and 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde. Still other preferred amine reaction products are those resulting from the reaction of Astramol Dendrimers with Carvone as well as those resulting from the reaction of ethyl-4-amino benzoate with one or more of the following 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde, and trans-2-nonenal. Still another preferred amine reaction products are those resulting from the reaction of polylysine with one or more of the following Alpha Damascone, Delta Damascone, Carvone, and 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde. Most preferred amine reaction products are those from the reaction of Lupasol HF with Delta Damascone; LupasolG35 with Alpha Damascone; LupasolG100 with 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde, BNPP or TPTA with Alpha and Delta Damascone; ethyl-4-amino benzoate with 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde. Even most preferred amine reaction products are those fulfilling the Dry Surface Odor Index as per given in co-pending application EP 98870155.3 given at page 29, line 26 to page 32 line 29, in which the specified unperfumed base for fabric sufaces and hard surfaces are respectively as follow: Composition for fabric surface test % by weight LAS 16 NaSKS-6 6 PB1 8 TAED 2.4 Carbonate 1 Sodium Carbonate 1 HEDP 0.4 SRP1 0.2 Photobleach 0.013 Citric acid 1.0 Protease 0.3 Lipase 0.1 Cellulase 0.1 Amylase 0.3 Zeolilte 3.0 TFAA 3.0 QAS1 2.5 Silicone antifoam 1.0 Misc/minors to balance to 100% Composition for hard surface test % by weight C12-14 EO 21 2 C12-14 EO 5 2.5 C9-11 EO 5 2.5 LAS 0.8 Na2CO3 0.2 Citric acid 0.8 Caustic acid 0.5 Fatty acid 0.5 SCS 1.5 Water &Misc/Minors to balance to 100% 2)-Carrier Another essential ingredient of the process invention is an anhydrous acid carrier. By means of this carrier, particles of amine reaction product will be easily and quickly produced. In a preferred aspect, the amine reaction product and the carrier material are in close physical proximity, more preferably in close contact, most preferably in intimate admixture within said obtained particle. Typical of these acid carrier for use herein are the commonly known organic acids or inorganic acids, which fall under the description of Bronsted or Lewis acids. Definition of an acid can be found in March J., Advanced Organic Chemistry, Chapter 8, page 248 for definition of a Bronsted acid and page 260 for the definition of a Lewis acid, John Wiley&Sons, New York, 1992. Suitable acid carrier for use herein have a pKa relative to water of from minus 9 to 16, more preferably from minus 2 to 10, most preferably from 0 to 7. For example, alcohols like phenol derivatives are suitable acid carrier for use herein. A typical example of such phenol derivative is picric acid which has a pKa of 0.25. Preferred organic or inorganic acids include those conventionally known as solid binders or agglomerating agents. More preferred organic acids are substantially water soluble solid binders or agglomerating agents. Most preferred are organic acids used in detergent applications, for example as builders. "Substantially water soluble" shall refer to a material that is soluble in distilled (or equivalent) water, at 25°C., at a concentration of 0.2% by weight, and are preferably soluble at 1.0% by weight. A "solid" is defined as a material that is a solid at ambient temperatures, and so solid substantially water-soluble binder or agglomerating agent must have a melting point of at least 30°C, and preferably of at least 40°C. Suitable water-soluble binders or agglomerating agents as organic acid carriers include monocarboxylic acids, monomeric polycarboxylic acids, homo or copolymeric polycarboxylic acids, inorganic acids, and mixtures thereof. Suitable example of monocarboxylic acids containing one carboxy group include formic acid, acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, pelargonic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, and mixtures thereof. Still other suitable monocarboxylic acids are the monocarboxylic acids substituted by any of the following groups: CH3- (CH2)n, wherein n is an integer of value of at least 1, CH3, OH, NH2, Cl, Br, F, I, OR", NHR", NR"2, NO2, SO3, cyclic rings like cyclopentane, cyclohexane, phenyl, benzyl, or a mixture of these substituents; wherein R" is selected from saturated or unsaturated alkyl chains. Preferred examples are 1-methylcyclohexanecarboxylic acid, glycolic acid, mandelic acid, lactic acid, salicylic acid, benzoic acid, and derivatives thereof. The substituents may also be anywhere in the alkyl chain attached to the acidic function. The alkyl chain can be saturated or non saturated. Still other typical of organic acids suitable for use herein as acid carrier includes the polycarboxylic acids containing two carboxy groups. Typical of these ingredients are selected from succinic acid, malonic acid, (ethylenedioxy) diacetic acid, maleic acid, diglycolic acid, tartaric acid, tartronic acid, fumaric acid, oxalic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, or sebacic acid, as well as the ether carboxylic acid and the sulfinyl carboxylic acids, and mixtures thereof. Other dicarboxylic acids suitable for use herein are the dicarboxylic acids substituted by CH3- (CH2)n, wherein n is an integer of value of at least 1, CH3, OH, NH2, Cl, Br, F, I, OR", NHR", NR"2, NO2, SO3, cyclic rings like cyclopentane, cyclohexane, phenyl, benzyl, or a mixture of these substituents; wherein R" is selected from saturated or unsaturated alkyl chain. Preferred examples of such substituted dicarboxylic acids are phtalic acid, isophtalic acid, terephtalic acid, malic acid, fumaric acid, tartaric acid, or mixtures thereof. The substituents may also be anywhere in the alkyl chain attached to the acidic functions. The alkyl chains can be saturated or non saturated. Other polycarboxylic acids suitable for use herein are the polycarboxylic acids containing three carboxy groups and include, in particular, water-soluble citric acid, aconitric and citraconic acid as well as succinic derivatives such as the carboxymethyloxysuccinic described in British Patent No. 1,379,241, lactoxysuccinic described in British Patent No. 1,389,732, and aminosuccinic described in Netherlands Application 7205873, and the oxypolycarboxylic materials such as 2-oxa-1,1,3-propane tricarboxylic described in British Patent No. 1,387,447. Other polycarboxylic acids suitable for use herein are the polycarboxylic acids containing four carboxy groups and include oxydisuccinic disclosed in British Patent No. 1,261,829, 1,1,2,2-ethane tetracarboxylic, 1,1,3,3-propane tetracarboxylic and 1,1,2,3-propane tetracarboxylic. Polycarboxylic containing sulfo substituents include the sulfosuccinic derivatives disclosed in British Patent Nos. 1,398,421 and 1,398,422 and in U.S. Patent No. 3,936,448, and the sulfonated pyrolysed citratic described in British Patent No. 1,439,000. Alicyclic and heterocyclic polycarboxylic include cyclopentane-cis,cis,cis-tetracarboxylic, cyclopentadienide pentacarboxylic, 2,3,4,5-tetrahydrofuran - cis, cis, cis-tetracarboxylic, 2,5-tetrahydrofuran - cis - dicarboxylic, 2,2,5,5-tetrahydrofuran - tetracarboxylic, 1,2,3,4,5,6-hexane - hexacarboxylic, polyacrylic acid, polymaleic acid, polymaleic-acrylic acids, sugar-acids like glucose-phosphonic acid, gluconic acid, glucuronic acid, mannanic acid, galactonic acid, arabinamic acid, and carboxymethyl derivatives of polyhydric alcohols such as sorbitol, mannitol and xylitol. Aromatic polycarboxylic include mellitic acid, pyromellitic acid and the phthalic acid derivatives disclosed in British Patent No. 1,425,343. Other suitable carriers are amino acids like, glycine, lysine, alanine, valine, leucine, isoleucine, proline, phenylalanine, tyrosine, tryptophan, serine, threonine, cysteine, methionine, asparagine, glutamine, aspartate, glutamate, arginine, histidine, and mixtures thereof. Other suitable acid carriers are the so called inorganic acids like for example HF, HCl, HBr, HI, H 2 SO 4 , H 2 SO 3 , H 2 CO 3 , HNO 2 , HNO 3 , HClO 4 , HClO 3 , HClO 2 , HClO, or H 3 PO 4 , H 4 P 2 O 7 , or H 5 P 3 O 10 or mixture thereof. Also useful herein as acid carriers are the protonated forms of the anionic surfactants, like the protonated form of the linear C 11-13 alkyl benzene sulfonate anionic surfactant. Other suitable carriers are acid anhydrides and acyl halides. Acid anhydrides react in the presence of water to acids. Sometimes, the production of the amine reaction product is followed by the incomplete removal of the water in the amine samples. It may then be desired to remove the remaining water by reacting it with the acid anhydrides to form acids which in turn make the salt with the amine reaction product. Other suitable carriers are acids, where the acidic proton is linked to C, N, S, Si or other non-oxygen atoms. Example of such acids is 2,4-pentanedione. To avoid possible hydrolysis of the amine reaction product in-situ due to the eventual additional water coming from the acid carrier, the acid carrier is used in its anhydrous forms. For example, citric acid is available under anhydrous form or as a monohydrate. Of the above, the preferred acid carriers are polycarboxylic acids selected from citric acid, tartaric acid, malonic acid, succinic acid, oxalic acid, adipic acid, maleic acid, malic acid, phtalic acid, succinic acid, hydroxysuccinic acid, polyacrylic acid, and mixtures thereof. Typically when the amine reaction product is mixed with such acid carrier, the amine reaction product will be present in an amount of from 10 to 85%, preferably 20 to 80%, more preferably 45 to 75% by weight of the processed reaction product in the produced particle. In this instance, the amount of carrier will be sufficient to add up to 100%. Of course, the particle may also contain minors but in quantities which will not exceed the amount of carrier material. Hence, if desired, the processed particle may contain one or more additional ingredients like a surfactant for improved solubility or dispersability. Typical of such surfactant are the anionic, nonionic, or cationic surfactants. Preferably, the weight ratio of such additional ingredient(s) to the carrier is of up to 1:1. Typically the acid carrier will be present in an amount of from 5 to 90%, preferably from 15 to 80% and most preferably from 20 to 70%, by weight of the produced particles in the processed amine reaction product. Processing of the amine reaction product with the acid carrier is done by first dissolving the amine reaction product in anhydrous solvent, preferably ethanol. Separately, the acid carrier is also dissolved in the same solvent that is used for the amine reaction product. The two solutions are then slowly added together, by adding the solution of the acid carrier to the solution of the amine reaction product whilst maintaining the temperature upon the addition to room temperature. During the addition the salt of the amine reaction product and the acid carrier precipitate resulting a solid powder. The solvent is removed by either filtering off the salt and drying or by evaporation of the solvent. Preferably the salt is obtained by filtering off. Accordingly, there is provided a processed amine reaction product salt as obtainable by the process of the invention. In a preferred marketing execution, a coating on the particle can be provided, which depending on the nature of this coating will give ease of dispersion, improved storage stability, flowability and/or improved fabric substantivity of the coated particle. Suitable coating materials suitable for use herein are those having a melting point between 30°C and 135°C, preferably between 45°C and 85°C. Suitable additional coating materials for use in the process invention are components like organic polymeric compounds, waxes, paraffins, oils, glycerides, monoglycerides, diglycerides, triglycerides, fatty acids, anionic surfactants; nonionic surfactants, cationic surfactants, zwitterionic surfactants, and mixtures thereof, preferably are selected from organic polymeric compound, nonionic surfactants, and mixtures thereof. Preferred organic polymeric compounds suitable for mixing with primary and/or secondary amine compound herein include polyethylene glycols, and derivatives thereof, particularly those of molecular weight 1000-10000, more particularly 2000 to 8000 and most preferably about 4000. Essentially any nonionic surfactants useful for detersive purposes can be included in the compositions provided it has a melting point between 30°C and 135°C. Exemplary, non-limiting classes of useful nonionic surfactants are listed below. Nonionic polyhydroxy fatty acid amide surfactant Polyhydroxy fatty acid amides suitable for use herein are those having the structural formula R2CONR1Z wherein : R1 is H, C 1 -C 4 hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl, or a mixture thereof, preferable C1-C4 alkyl, more preferably C 1 or C 2 alkyl, most preferably C 1 alkyl (i.e., methyl); and R2 is a C 5 -C 31 hydrocarbyl, preferably straight-chain C 5 -C 19 alkyl or alkenyl, more preferably straight-chain C 9 -C 17 alkyl or alkenyl, most preferably straight-chain C 11 -C 17 alkyl or alkenyl, or mixture thereof; and Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof. Z preferably will be derived from a reducing sugar in a reductive amination reaction; more preferably Z is a glycityl. Nonionic condensates of alkyl phenols The polyethylene, polypropylene, and polybutylene oxide condensates of alkyl phenols are suitable for use herein. In general, the polyethylene oxide condensates are preferred. These compounds include the condensation products of alkyl phenols having an alkyl group containing from about 6 to about 18 carbon atoms in either a straight chain or branched chain configuration with the alkylene oxide with from about 1 to about 150 moles of alkylene oxide per mole of alcohol. Nonionic ethoxylated alcohol surfactant The alkyl ethoxylate condensation products of aliphatic alcohols with from about 1 to about 150 moles of ethylene oxide are suitable for use herein. The alkyl chain of the aliphatic alcohol can either be straight or branched, primary or secondary, and generally contains from 6 to 22 carbon atoms. Particularly preferred are the condensation products of alcohols having an alkyl group containing from 8 to 20 carbon atoms with from about 25 to about 150 moles of ethylene oxide per mole of alcohol, preferably 50 to 100, more preferably 80 moles of ethylene oxide per mole of alcohol. Preferred nonionic ethoxylated alcohol surfactants are selected from tallow (C 16 -C 18 ) alcohol ethoxylated with 25, 50, 80, or 100 moles of ethylene oxide commercially available from under the tradename of Lutensol from BASF, Empilan from Albright and Wilson, and Genapol from Clariant. The most preferred nonionic ethoxylated alcohol surfactant is tallow (C 16 -C 18 ) alcohol ethoxylated with 80moles of ethylene oxide and commercially available under the tradename of Lutensol 80/80 from BASF, Empilan KM 80 from Albright and Wilson, or Genapol T800 from Clariant. Nonionic ethoxylated/propoxylated fatty alcohol surfactant The ethoxylated C 6 -C 22 fatty alcohols and C 6 -C 22 mixed ethoxylated/propoxylated fatty alcohols are suitable surfactants for use herein, particularly where water soluble. Preferably the ethoxylated fatty alcohols are the C 10 -C 22 ethoxylated fatty alcohols with a degree of ethoxylation of from 25 to 150, most preferably these are the C 12 -C 18 ethoxylated fatty alcohols with a degree of ethoxylation from 50 to 80. Preferably the mixed ethoxylated/propoxylated fatty alcohols have an alkyl chain length of from 10 to 18 carbon atoms, a degree of ethoxylation of from 3 to 30 and a degree of propoxylation of from 1 to 30. Nonionic EO/PO condensates with propylene glycol The condensation products of ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol are suitable for use herein. The hydrophobic portion of these compounds preferably has a molecular weight of from about 1500 to about 1800 and exhibits water insolubility. Examples of compounds of this type include certain of the commercially-available Pluronic™ surfactants, marketed by BASF. Nonionic EO condensation products with propylene oxide/ethylene diamine adducts The condensation products of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylenediamine are suitable for use herein. The hydrophobic moiety of these products consists of the reaction product of ethylenediamine and excess propylene oxide, and generally has a molecular weight of from about 2500 to about 3000. Examples of this type of nonionic surfactant include certain of the commercially available Tetronic™ compounds, marketed by BASF. Nonionic alkylpolysaccharide surfactant Suitable alkylpolysaccharides for use herein are disclosed in U.S. Patent 4,565,647, Llenado, issued January 21, 1986, having a hydrophobic group containing from about 6 to about 30 carbon atoms, preferably from about 10 to about 16 carbon atoms and a polysaccharide, e.g., a polyglycoside, hydrophilic group containing from about 1.3 to about 10, preferably from about 1.3 to about 3, most preferably from about 1.3 to about 2.7 saccharide units. Any reducing saccharide containing 5 or 6 carbon atoms can be used, e.g., glucose, galactose and galactosyl moieties can be substituted for the glucosyl moieties. (Optionally the hydrophobic group is attached at the 2-, 3-, 4-, etc. positions thus giving a glucose or galactose as opposed to a glucoside or galactoside.) The intersaccharide bonds can be, e.g., between the one position of the additional saccharide units and the 2-, 3-, 4-, and/or 6- positions on the preceding saccharide units. The preferred alkylpolyglycosides have the formula R2O((CnH2n)O)t(glycosyl) x wherein R2 is selected from the group consisting of alkyl, alkylphenyl, hydroxyalkyl, hydroxyalkylphenyl, and mixtures thereof in which the alkyl groups contain from 10 to 18, preferably from 12 to 14, carbon atoms; n is 2 or 3; t is from 0 to 10, preferably 0, and X is from 1.3 to 8, preferably from 1.3 to 3, most preferably from 1.3 to 2.7. The glycosyl is preferably derived from glucose. Nonionic fatty acid amide surfactant Fatty acid amide surfactants suitable for use herein are those having the formula: R 6 CON(R 7 ) 2 wherein R 6 is an alkyl group containing from 7 to 21, preferably from 9 to 17 carbon atoms and each R 7 is selected from the group consisting of hydrogen, C 1 -C 4 alkyl, C 1 -C 4 hydroxyalkyl, and -(C 2 H 4 O) x H, where x is in the range of from 1 to 3. Preferred coating materials from those above mentioned are the nonionic ethoxylated alcohol surfactants having a melting point between 30°C and 135°C. Other materials suitable for the coating are those above described as water-soluble binder or agglomerating agents. Of course, for the purpose of the invention it is preferred when a coating is provided that this is of a different nature to that of the carrier. As above described, suitable water-soluble binders or agglomerating agents include the water soluble organic polymeric compounds, water soluble monomeric polycarboxylates, or their acid forms, homo or copolymeric polycarboxylic acids or their salts in which the polycarboxylic acid comprises at least two carboxylic radicals separated from each other by not more that two carbon atoms. Suitable organic polymeric compounds suitable as coating agents include cellulose derivatives such as methylcellulose, carboxymethylcellulose, hydroxypropylcellulose and hydroxyethylcellulose, as well as carbohydrates like pectins, and gums. Further compounds are carbohydrates and derivatives such as fructose, xylose, galactose, galacturonic acid or glucose based polymers like inuline, dextran, xyloglucan, pectin or gums Suitable carboxylates containing one carboxy group include the water soluble salts of lactic acid, glycolic acid and ether derivatives thereof. Polycarboxylates containing two carboxy groups include the water-soluble salts of succinic acid, malonic acid, (ethylenedioxy) diacetic acid, maleic acid, diglycolic acid, tartaric acid, tartronic acid and fumaric acid, as well as the ether carboxylates and the sulfinyl carboxylates. Polycarboxylates containing three carboxy groups include, in particular, water-soluble citrates, aconitrates and citraconates as well as succinate derivatives such as the carboxymethyloxysuccinates described in British Patent No. 1,379,241, lactoxysuccinates described in British Patent No. 1,389,732, and aminosuccinates described in Netherlands Application 7205873, and the oxypolycarboxylate materials such as 2-oxa-1,1,3-propane tricarboxylates described in British Patent No. 1,387,447. Polycarboxylates containing four carboxy groups include oxydisuccinates disclosed in British Patent No. 1,261,829, 1,1,2,2-ethane tetracarboxylates, 1,1,3,3-propane tetracarboxylates and 1,1,2,3-propane tetracarboxylates. Polycarboxylates containing sulfo substituents include the sulfosuccinate derivatives disclosed in British Patent Nos. 1,398,421 and 1,398,422 and in U.S. Patent No. 3,936,448, and the sulfonated pyrolysed citrates described in British Patent No. 1,439,000. Alicyclic and heterocyclic polycarboxylates include cyclopentane-cis,cis,cis-tetracarboxylates, cyclopentadienide pentacarboxylates, 2,3,4,5-tetrahydrofuran - cis, cis, cis-tetracarboxylates, 2,5-tetrahydrofuran - cis - dicarboxylates, 2,2,5,5-tetrahydrofuran - tetracarboxylates, 1,2,3,4,5,6-hexane - hexacarboxylates and carboxymethyl derivatives of polyhydric alcohols such as sorbitol, mannitol and xylitol. Aromatic polycarboxylates include mellitic acid, pyromellitic acid and the phthalic acid derivatives disclosed in British Patent No. 1,425,343. Of the above, the preferred polycarboxylates are hydroxycarboxylates containing up to three carboxy groups per molecule, more particularly citrates. Still other suitable water-soluble binders or agglomerating agents as coating materials include, carbonates, bicarbonates, borates, phosphates, sulfate salts like sodium and magnesium sulfate, inorganic perhydrate salts including perborate like perborate monohydrate, percarbonate, silicates, starch, cyclodextrin, clay as defined hereinafter like smectite and bentonite clay and mixtures of any of the foregoing. Borate, as well as builders containing borate-forming materials that can produce borate under detergent storage or wash conditions can also be used but are not preferred at wash conditions less that about 50°C, especially less than about 40°C. Examples of carbonates are the alkaline earth and alkali metal carbonates, including sodium carbonate and sesqui-carbonate and mixtures thereof with ultra-fine calcium carbonate as disclosed in German Patent Application No. 2,321,001 published on November 15, 1973. Specific examples of water-soluble phosphates are the alkali metal tripolyphosphates, sodium, potassium and ammonium pyrophosphate, sodium and potassium and ammonium pyrophosphate, sodium and potassium orthophosphate, sodium polymeta/phosphate in which the degree of polymerization ranges from about 6 to 21, and salts of phytic acid. Suitable silicates include the water soluble sodium silicates with an SiO 2 : Na 2 O ratio of from 1.0 to 2.8, with ratios of from 1.6 to 2.4 being preferred, and 2.0 ratio being most preferred. The silicates may be in the form of either the anhydrous salt or a hydrated salt. Sodium silicate with an SiO 2 : Na 2 O ratio of 2.0 is the most preferred silicate. Typical disclosure of cyclodextrin derivatives are disclosed in W096/05358, U.S. Pat. Nos: 3,426,011, Parmerter et al., issued Feb. 4, 1969; 3,453,257; 3,453,258; 3,453,259; and 3,453,260, all in the names of Parmerter et al., and all issued July 1, 1969; 3,459,731, Gramera et al., issued Aug. 5, 1969; 3,553,191, Parmerter et al., issued Jan. 5, 1971; 3,565,887, Parmerter et al., issued Feb. 23, 1971; 4,535,152, Szejtli et al., issued Aug. 13, 1985; 4,616,008, Hirai et al., issued Oct. 7, 1986; 4,678,598, Ogino et al., issued Jul. 7, 1987; 4,638,058, Brandt et al., issued Jan. 20, 1987; and 4,746,734, Tsuchiyama et al., issued May 24, 1988; all of said patents being incorporated herein by reference. Although less preferred for use herein because of their lower solubility, partially water soluble coating agents may also be used as coating agent. These compounds are indeed less preferred because during the wash cycle the amine reaction product will still be at least partially coated and therefore can not display its full functionality of long lasting freshness on dry fabrics or hard surfaces. Examples of partially water soluble coating agents include the crystalline layered silicates. Examples of largely water insoluble builders include the sodium aluminosilicates. Crystalline layered sodium silicates have the general formula NaMSi x O x+1.y H 2 O wherein M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20. Crystalline layered sodium silicates of this type are disclosed in EP-A-0164514 and methods for their preparation are disclosed in DE-A-3417649 and DE-A-3742043. For the purpose of the present invention, x in the general formula above has a value of 2, 3 or 4 and is preferably 2. The most preferred material is δ-Na 2 Si 2 O 5 , available from Hoechst AG as NaSKS-6. Suitable aluminosilicate zeolites have the unit cell formula Na z [(AlO 2 ) z (SiO 2 )y]. XH 2 O wherein z and y are at least 6; the molar ratio of z to y is from 1.0 to 0.5 and x is at least 5, preferably from 7.5 to 276, more preferably from 10 to 264. The aluminosilicate material are in hydrated form and are preferably crystalline, containing from 10% to 28%, more preferably from 18% to 22% water in bound form. The aluminosilicate ion exchange materials can be naturally occurring materials, but are preferably synthetically derived. Synthetic crystalline aluminosilicate ion exchange materials are available under the designations Zeolite A, Zeolite B, Zeolite P, Zeolite X, Zeoilte MAP, Zeolite HS and mixtures thereof. Zeolite A has the formula Na 12 [AlO 2 ) 12 (SiO 2 ) 12 ].xH 2 O wherein x is from 20 to 30, especially 27. Zeolite X has the formula Na 86 [(AlO 2 ) 86 (SiO 2 ) 106 ].276 H 2 O. Typically when the amine reaction product is mixed with an acid carrier and further processed to form a coated particle, the amine reaction product will be present in an amount of from 1 to 85%, preferably 5 to 24% by weight of the processed reaction product in the produced particle. Typically the coating agent will be present in an amount of from 10% to 95%, preferably from 30 to 90%, more preferably, 50 to 75% by weight of the particle of the processed amine reaction product. In this instance, the amount of carrier will be sufficient to add up to 100%. Of course, the coated particle may also contain minors but in quantities which will not exceed either of the amount of carrier material or coating agent. Preferred coating materials are selected from nonionic ethoxylated alcohol surfactants having a melting point between 30°C and 135°C, carbonate, starch, cyclodextrin, and mixtures thereof. The surface treatment of the particle can be carried out in a number of ways using equipment known in the art and the process may be taken in batch wise or continuous fashion. One method for applying the coating material involves agglomeration. Any conventional agglomerator/mixer may be used including, but not limited to pan, rotary drum and vertical blender types. Molten coating compositions may also be applied either by being poured onto, or spray atomized onto a moving bed of the mixture of amine reaction product with carrier. Another method for applying the coating is to pour the obtained mixture (so-called particle), as herein before described, onto the coating material and agglomerate it in a Braun Mixer. Care is also taken that the temperature during the mixing and/or coating step does not substantially exceed the melting point of the carrier material. For example, 130g of a mixture containing the citric acid salt of the amine reaction product and 39g of PEG 4000 is poured at 60°C into a Braun Mixer containing 50g of carbonate. The mixing of the ingredients is carried out for about 5 minutes. Care is also taken that the temperature during the coating does not exceed 60°C. The agglomerated particle can then be used as is for incorporation into the finished composition. Still another preferred marketing execution is by mixing the particle with a solvent capable of dissolving the particle, thereby enabling the spraying of the resulting mixture. Incorporation into finished composition The finished compositions aspect of the invention, including laundry compositions, hard surface cleaning compositions, personal cleaning compositions, spray-on products like odor-absorbing composition, dewrinkling composition, comprises the incorporation of the hereinbefore described processed amine reaction product salt together with one or more laundry or cleaning ingredient in a finished composition. Finished compositions incorporating the processed amine reaction product salt will normally contain from 0.01 to 25%, more preferably from 0.02 to 10%, and most preferably from 0.05 to 5% of the processed product on a composition weight basis. Laundry compositions of the invention, which also encompass compositions providing color care, are suitable for use in any steps of the domestic treatment, that is as a pre-treatment composition, as a wash additive as a composition suitable for use in the rinse-cycle of the laundry cycle or applied on a dryer-sheet. Obviously, multiple applications can be made such as treating the fabric with a pre-treatment composition of the invention and also thereafter with a composition of the invention suitable for use in the rinse cycle and/or suitable for use as a dryer-sheet. The liquid finished compositions of the invention may also be in a spray, foam, or aerosol form which for example can be suitable for use while ironing, or applied on the surfaces of the tumble dryer. As mentioned hereinbefore, the incorporation of the processed amine reaction product salt is conveniently made depending on its end form by dry-addition, as is or in coated form. Laundry compositions encompass laundry detergent compositions, including liquid, solid form like powdered, tablets as well as softening compositions including rinse added softening composition as well as dryer added softening compositions. A conventional disclosure of softening ingredients to be used in the softening composition of the invention can be found in EP 98870227.0, incorporated herein by reference. Preferably, the finished composition is a detergent composition, more preferably in solid form. In particular, it is preferred that the detergent composition comprises a clay. Clay The compositions of the invention may preferably contain a clay, preferably present at a level of from 0.05% to 40%, more preferably from 0.5% to 30%, most preferably from 2% to 20% by weight of the composition. For clarity, it is noted that the term clay mineral compound, as used herein, excludes sodium aluminosilicate zeolite builder compounds, which however, may be included in the compositions of the invention as optional components. One preferred clay may be a bentonite clay. Highly preferred are smectite clays, as for example disclosed in the US Patents No.s 3,862,058 3,948,790, 3,954,632 and 4,062,647 and European Patents No.s EP-A-299,575 and EP-A-313,146 all in the name of the Procter and Gamble Company. The term smectite clays herein includes both the clays in which aluminium oxide is present in a silicate lattice and the clays in which magnesium oxide is present in a silicate lattice. Smectite clays tend to adopt an expandable three layer structure. Specific examples of suitable smectite clays include those selected from the classes of the montmorillonites, hectorites, volchonskoites, nontronites, saponites and sauconites, particularly those having an alkali or alkaline earth metal ion within the crystal lattice structure. Sodium or calcium montmorillonite are particularly preferred. Suitable smectite clays, particularly montmorillonites, are sold by various suppliers including English China Clays, Laviosa, Georgia Kaolin and Colin Stewart Minerals. Clays for use herein preferably have a particle dimension of from 10nm to 800nm more preferably from 20nm to 500 mm, most preferably from 50nm to 200 mm. Particles of the clay mineral compound may be included as components of agglomerate particles containing other detergent compounds. Where present as such components, the term "largest particle dimension" of the clay mineral compound refers to the largest dimension of the clay mineral component as such, and not to the agglomerated particle as a whole. Substitution of small cations, such as protons, sodium ions, potassium ions, magnesium ions and calcium ions, and of certain organic molecules including those having positively charged functional groups can typically take place within the crystal lattice structure of the smectite clays. A clay may be chosen for its ability to preferentially absorb one cation type, such ability being assessed by measurements of relative ion exchange capacity. The smectite clays suitable herein typically have a cation exchange capacity of at least 50 meq/100g. U.S. Patent No. 3,954,632 describes a method for measurement of cation exchange capacity. The crystal lattice structure of the clay mineral compounds may have, in a preferred execution, a cationic fabric softening agent substituted therein. Such substituted clays have been termed 'hydrophobically activated' clays. The cationic fabric softening agents are typically present at a weight ratio, cationic fabric softening agent to clay, of from 1:200 to 1:10, preferably from 1:100 to 1:20. Suitable cationic fabric softening agents include the water insoluble tertiary amines or dilong chain amide materials as disclosed in GB-A-1 514 276 and EP-B-0 011 340. A preferred commercially available "hydrophobically activated" clay is a bentonite clay containing approximately 40% by weight of a dimethyl ditallow quaternary ammonium salt sold under the tradename Claytone EM by English China Clays International. In a highly preferred embodiment of the invention, the clay is present in an intimate mixture or in a particle with a humectant and a hydrophobic compound, preferably a wax or oil, such as paraffin oil. Preferred humectants are organic compounds, including propylene glycol, ethylene glycol, dimers or trimers of glycol, most preferably glycerol. The particle is preferably an agglomerate. Alternatively, the particle may be such that the wax or oil and optionally the humectant form an encapsulate on the clay or alternatively, the clay be a encapsulate for the wax or oil and the humectant. It may be preferred that the particle comprises an organic salt or silica or silicate. However, in another embodiment of the invention, the clay is preferably mixed with one or more surfactants and optionally builders and optionally water, in which case the mixture is preferably subsequently dried. Preferably, such a mixture is further processed in a spray-drying method to obtain a spray dried particle comprising the clay. It may be preferred that the flocculating agent is also comprised in the particle or granule comprising the clay. It may also be preferred that the intimate mixture comprises a chelating agent. Flocculating agent The compositions of the invention may contain a clay flocculating agent, preferably present at a level of from 0.005% to 10%, more preferably from 0.05% to 5%, most preferably from 0.1% to 2% by weight of the composition. The clay flocculating agent functions such as to bring together the particles of clay compound in the wash solution and hence to aid their deposition onto the surface of the fabrics in the wash. This functional requirement is hence different from that of clay dispersant compounds which are commonly added to laundry detergent compositions to aid the removal of clay soils from fabrics and enable their dispersion within the wash solution. Preferred as clay flocculating agents herein are organic polymeric materials having an average weight of from 100,000 to 10,000,000, preferably from 150,000 to 5,000,000, more preferably from 200,000 to 2,000,000. Suitable organic polymeric materials comprise homopolymers or copolymers containing monomeric units selected from alkylene oxide, particularly ethylene oxide, acrylamide, acrylic acid, vinyl alcohol, vinyl pyrrolidone, and ethylene imine. Homopolymers of, on particular, ethylene oxide, but also acrylamide and acrylic acid are preferred. European Patents No.s EP-A-299,575 and EP-A-313,146 in the name of the Procter and Gamble Company describe preferred organic polymeric clay flocculating agents for use herein. The weight ratio of clay to the flocculating polymer is preferably from 1000:1 to 1:1, more preferably from 500:1 to 1:1, most preferably from 300:1 to 1:1, or even more preferably from 80:1 to 10:1, or in certain applications even from 60:1 to 20:1. Inorganic clay flocculating agents are also suitable herein, typical examples of which include lime and alum. The flocculating agent is preferably present in a detergent base granule such as a detergent agglomerate, extrudate or spray-dried particle, comprising generally one or more surfactants and builders. Effervescent Effervescent means may also be optionally used in the compositions of the invention. Effervescency as defined herein means the evolution of bubbles of gas from a liquid, as the result of a chemical reaction between a soluble acid source and an alkali metal carbonate, to produce carbon dioxide gas, i.e. C 6 H 8 O 7 + 3NaHCO 3 → Na 3 C 6 H 5 O 7 + 3CO 2 ↑ + 3H 2 O Further examples of acid and carbonate sources and other effervescent systems may be found in : (Pharmaceutical Dosage Forms : Tablets Volume 1 Page 287 to 291). Carbonate salts Suitable alkali and/ or earth alkali inorganic carbonate salts herein include carbonate and hydrogen carbonate of potassium, lithium, sodium, and the like amongst which sodium and potassium carbonate are preferred. Suitable bicarbonates to be used herein include any alkali metal salt of bicarbonate like lithium, sodium, potassium and the like, amongst which sodium and potassium bicarbonate are preferred. However, the choice of carbonate or bicarbonate or mixtures thereof may be made depending on the pH desired in the aqueous medium wherein the granules are dissolved. For example where a relative high pH is desired in the aqueous medium (e.g., above pH 9.5) it may be preferred to use carbonate alone or to use a combination of carbonate and bicarbonate wherein the level of carbonate is higher than the level of bicarbonate. The inorganic alkali and/ or earth alkali carbonate salt of the compositions of the invention comprises preferably a potassium or more preferably a sodium salt of carbonate and/ or bicarbonate. Preferably, the carbonate salt comprises sodium carbonate, optionally also a sodium bicarbonate. The inorganic carbonate salts herein are preferably present at a level of at least 20% by weight of the composition. Preferably they are present at a level of at least 23% or even 25% or even 30% by weight, preferably up to about 60% by weight or more preferably up to 55% or even 50% by weight. They may be added completely or partially as separate powdered or granular component, as co-granules with other detergent ingredients, for example other salts or surfactants. In solid detergent compositions of the invention, they may also completely or partially be present in detergent granules such as agglomerates or spray dried granules. In one embodiment of the invention, an effervescence source is present, preferably comprising an organic acid, such as carboxylic acids or aminoacids, and a carbonate. Then it may be preferred that part or all of the carbonate salt herein is premixed with the organic acid, and thus present in an separate granular component. Preferred effervescent source are selected from compressed particles of citric acid and carbonate optionally with a binder; and particle of carbonate, bicarbonate and malic or maleic acid in weight ratios of 4:2:4. The dry add form of citric acid and carbonate are preferably used. The carbonate may have any particle size. In one embodiment, in particular when the carbonate salt is present in a granule and not as separately added compound, the carbonate salt has preferably a volume median particle size from 5 to 375 microns, whereby preferably at least 60%, preferably at least 70% or even at least 80% or even at least 90% by volume, has a particle size of from 1 to 425 microns. More preferably, the carbon dioxide source has a volume median particle size of 10 to 250, whereby preferably at least 60 %, or even at least 70% or even at least 80% or even at least 90% by volume, has a particle size of from 1 to 375 microns; or even preferably a volume median particle size from 10 to 200 microns, whereby preferably at least 60 %, preferably at least 70% or even at least 80% or even at least 90% by volume, has a particle size of from 1 to 250 microns. In particular when the carbonate salt is added as separate component, so to say 'dry-added' or admixed to the other detergent ingredients, the carbonate may have any particle size, including the above specified particle sizes, but preferably at least an volume average particle size of 200 microns or even 250 microns or even 300 microns. It may be preferred that the carbon dioxide source of the required particle size is obtained by grinding a larger particle size material, optionally followed by selecting the material with the required particle size by any suitable method. Whilst percarbonate salts may be present in the compositions of the invention as a bleaching agent, they are not included in the carbonate salts as defined herein The preferred detergent composition, embodiment of the invention, will, preferably contain a bleach precursor, a source of alkaline hydrogen peroxide necessary to form a peroxyacid bleaching species in the wash solution and preferably will also contain other components conventional in detergent compositions. Thus, preferred detergent compositions will incorporate one or more of surfactants, organic and inorganic builders, soil suspending and antiredeposition agents, suds suppressors, enzymes, fluorescent whitening agents, photoactivated bleaches, perfumes, colours, and mixtures thereof. Typical disclosure of such components can be found in EP-A-0,659,876 and European patent application No. 98870226.2 which are both incorporated herein by reference. Form of the composition The composition of the invention may take a variety of physical form including liquid, gel, foam in either aqueous or non-aqueous form, granular and tablet forms. Still in another aspect of the invention, there is provided a packaged composition comprising the processed product of the invention or composition of the invention. Preferably, the packaged composition is a closed packaging system having a moisture vapour transmission rate of less than 20g/m 2 /24 hours. Typical disclosure of such a package can be found in WO 98/40464. Still another preferred package is a spray dispenser. Spray Dispenser The present invention also relates to such compositions incorporated into a spray dispenser to create an article of manufacture that can facilitate treatment of fabric articles and/or surfaces with said compositions containing the amine reaction product and other ingredients (examples are cyclodextrins, polysaccharides, polymers, surfactant, perfume, softener) at a level that is effective, yet is not discernible when dried on the surfaces. The spray dispenser comprises manually activated and non-manual powered (operated) spray means and a container containing the treating composition. Typical disclosure of such spray dispenser can be found in WO 96/04940 page 19 line 21 to page 22 line 27. The articles of manufacture preferably are in association with instructions for use to ensure that the consumer applies sufficient ingredient of the composition to provide the desired benefit. Typical compositions to be dispensed from a sprayer contain a level of amine reaction product of from about 0.01% to about 5%, preferably from about 0.05% to about 2%, more preferably from about 0.1% to about 1%, by weight of the usage composition. Method of use Also provided herein is a method for providing a delayed release of an active ketone or aldehyde which comprises the step of contacting the surface to be treated with a a compound or composition of the invention, and thereafter contacting the treated surface with a material, preferably an aqueous medium like moisture or any other means susceptible of releasing the active from the amine reaction product. By "surface", it is meant any surface onto which the compound can deposit. Typical examples of such material are fabrics, hard surfaces such as dishware, floors, bathrooms, toilet, kitchen, paper, skin, and other surfaces in need of a delayed release of a perfume ketone and/or aldehyde such as that with litter like animal litter. Preferably, the surface is selected from a fabric, a tile, a ceramic; more preferably is a fabric. By "delayed release" is meant release of the active component (e.g perfume) over a longer period of time than by the use of the active (e.g., perfume) itself. Still in another aspect of the invention, there is provided the use of the product of the invention for the manufacture of a laundry and/or cleaning composition for delivering residual fragrance and fabric care, in particular color care, onto the fabrics on which it is applied. The following are synthesis examples of compounds as defined in the present invention: I-Synthesis of 1,4-bis-(3-aminopropyl)-piperazine (BNPP) with α-Damascone In order to substitute both primary amine groups with a perfume, 2eq of perfume were used for 1eq of amino functional polymer. To an ice cooled stirred solution of 1mmol of α-Damascone in 6 mL EtOH and molecular sieves (4A, 20 g), 0.5eq of 1,4-bis-(3-aminopropyl)-piperazine was added via an addition funnel. The reaction mixture was stirred under nitrogen atmosphere and protected from light. After the disappearance of the absorption peak from the NMR spectrum of the free perfume raw material (from 3 to 16 hours), the mixture was filtrated and the solvent was removed by vacuum distillation. The yield of β-aminoketone formation is about 90%. Similar results were obtained where the α-Damascone was replaced by δ-Damascone, 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde, vertocitral, bourgeonal, or citronellal. In these instances, excepted δ-Damascone which forms β-aminoketone, Schiff-bases are formed. II-Synthesis of Lupasol with Damascones and 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde The β-amino ketone from Lupasol G100 (commercially available from BASF with a content of 50 % water, 50 % Lupasol G100 (Mw. 5000)) and α-Damascone (or δ-Damascone) was prepared using any one of these three different procedures described as follows: 1. Commercially available Lupasol G100 was dried using the following procedure: 20 g of the Lupasol solution was dried at the rotating evaporator during several hours. The obtained residue, still containing about 4.5 g of H 2 O, was azeotropically distilled at the rotating evaporator using toluene. The residue was then placed in the desiccator dried at 60 °C (using P 2 O 5 as water absorbing material). On basis of the obtained weight we concluded that the oil contained less then 10 % H 2 O. On basis of the NMR-spectra we concluded that this is probably less then 5 %. This dried sample was then used in the preparation of β-amino ketones. 1.38 g of the dried Lupasol G100 obtained above was dissolved in 7 ml. ethanol. The solution was stirred gently with a magnetic stirrer during a few minutes before 2 g Na 2 SO 4 (anhydrous) was added. After stirring again for a few minutes 2.21 g α-Damascone was added over a period of 1 minute. After two days reaction, the mixture was filtrated over a Celite filter (vide supra), and the residue washed thoroughly with ethanol. About 180 ml. of a light foaming filtrate was obtained. This was concentrated until dryness using a rotating evaporator and dried over P 2 O 5 in an desiccator at room temperature. About 3.5 of a colorless oil was obtained. 2. 4.3 g Lupasol G100 solution was without drying dissolved in 10 ml. ethanol. The solution was stirred with a magnetic stirrer during a few minutes before 3.47 g α-Damascone was added over a 1.5 minutes period. After two days reaction at room temperature the reaction mixture was filtrated over Celite (vide supra) and the residue washed thoroughly with ethanol. The filtrate (200 ml., light foaming) was concentrated at the evaporator and dried in an desiccator (P 2 O 5 as drying agent) at room temperature. About 5.9 g of a colorless oil was obtained. 3. To 3.0 g of Lupasol G100 solution (used as such) was added 2.41 g α-Damascone. The mixture was stirred without using solvent. After stirring for 4 days the obtained oil was dissolved in 100 ml. THF, dried with MgSO 4 , filtrated and the filtrate concentrated at the rotating evaporator. After drying in the desiccator (P 2 O 5 ) at room temperature about 4 g of a colorless oil was obtained. This oil still contained about 13 % (w/w) of THF, even after a prolonged drying (3 days). The product obtained from the three procedures had identical NMR-spectra. Similar results are obtained where Lupasol G35 or Lupasol HF is used instead of Lupasol G100. Similar results were obtained where the α-Damascone was replaced by 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde. Still another possible route of synthesis is by using Lupasol P. The β-amino ketone from Lupasol P and α-Damascone was prepared using the procedure described as follows: 1.8g Lupasol P solution (50 % H 2 O, 50 % Lupasol Mw. 750000, as obtained from BASF) was dissolved in 7 ml ethanol, the solution was stirred for a few minutes with a magnetic stirrer before 1.44 g α-Damascone was added. After three days the reaction mixture was filtrated over a celite filter (vide supra) and the residue washed thoroughly with ethanol. After concentrating of the filtrate and drying of the obtained oil in the desiccator (P 2 O 5 ) at room temperature, about 3 g of the reaction product between Lupasol and α-Damascone was obtained. Processing method for the salt formation Processing of the amine reaction product with the acid carrier is done as hereinbefore described. In particular, 10g of the δ-Damascone-Lupasol HF, as synthesized above, was dissolved in 70 ml of dry ethanol. Separately, 5g of anhydrous citric acid was dissolved in 80ml of dry ethanol. The solution were added slowly together in glass container while mixing, by addition of the Lupasol HF-δ-Damascone solution to the citric acid solution. The temperature during the mixing is kept at room temperature. After the addition is complete, 1g anhydrous citric acid is added till a complete precipitation of the Lupasol HF-δ-Damascone is obtained. The precipitation is filtered off and dried. About 16 g of the salt is obtained. Total time for the experiment is about 1 hour. Processing method for the coating If a coating is desired, the obtained mixture (so-called particle), as herein before described, is pour onto the coating material and agglomerated it in a Braun Mixer. Care is taken that the temperature during the mixing and/or coating step does not substantially exceed the melting point of the carrier material. For example, 130g of a mixture containing the citric acid salt of the amine reaction product and 39g of PEG 4000 is poured at 60°C into a Braun Mixer containing 50g of carbonate. The mixing of the ingredients is carried out for about 5 minutes. Care is also taken that the temperature during the coating does not exceed 60°C. Abbreviations used in the following laundry and cleaning composition Examples In the laundry and cleaning compositions, the abbreviated component identifications have the following meanings: DEQA : Di-(tallowyl-oxy-ethyl) dimethyl ammonium chloride DTDMAC : Ditallow dimethylammonium chloride DEQA (2) : Di-(soft-tallowyloxyethyl) hydroxyethyl methyl ammonium methylsulfate. DTDMAMS : Ditallow dimethyl ammonium methylsulfate. SDASA : 1:2 ratio of stearyldimethyl amine:triple-pressed stearic acid. Fatty acid : Stearic acid of IV=0 Electrolyte : Calcium chloride PEG : Polyethylene Glycol 4000 Neodol 45-13 : C14-C15 linear primary alcohol ethoxylate, sold by Shell Chemical CO. Silicone antifoam : Polydimethylsiloxane foam controller with siloxane-oxyalkylene copolymer as dispersing agent with a ratio of said foam controller to said dispersing agent of 10:1 to 100:1. PEI : Polyethyleneimine with an average molecular weight of 1800 and an average ethoxylation degree of 7 ethyleneoxy residues per nitrogen HEDP : 1,1-hydroxyethane diphosphonic acid LAS : Sodium linear C 11-13 alkyl benzene sulfonate TAS : Sodium tallow alkyl sulfate CxyAS : Sodium C 1x - C 1y alkyl sulfate C46SAS : Sodium C 14 - C 16 secondary (2,3) alkyl sulfate CxyEzS : Sodium C 1x -C 1y alkyl sulfate condensed with z moles of ethylene oxide CxyEz : C 1x -C 1y predominantly linear primary alcohol condensed with an average of z moles of ethylene oxide QAS : R 2 .N + (CH 3 ) 2 (C 2 H 4 OH) with R 2 = C 12 - C 14 QAS 1 : R 2 .N + (CH 3 ) 2 (C 2 H 4 OH) with R 2 = C 8 - C 11 APA : C 8 - C 10 amido propyl dimethyl amine Soap : Sodium linear alkyl carboxylate derived from an 80/20 mixture of tallow and coconut fatty acids STS : Sodium toluene sulphonate CFAA : C 12 -C 14 (coco) alkyl N-methyl glucamide TFAA : C 16 -C 18 alkyl N-methyl glucamide TPKFA : C 12- C 14 topped whole cut fatty acids STPP : Anhydrous sodium tripolyphosphate TSPP : Tetrasodium pyrophosphate Zeolite A : Hydrated sodium aluminosilicate of formula Na 12 (A1O 2 SiO 2 ) 12 .27H 2 O having a primary particle size in the range from 0.1 to 10 micrometers (weight expressed on an anhydrous basis) NaSKS-6 : Crystalline layered silicate of formula δ-Na 2 Si 2 O 5 Citric acid : Anhydrous citric acid Borate : Sodium borate Carbonate : Anydrous sodium carbonate with a particle size between 200µm and 900µm Bicarbonate : Anhydrous sodium bicarbonate with a particle size distribution between 400µm and 1200µm Silicate : Amorphous sodium silicate (SiO 2 :Na 2 O = 2.0:1) Sulfate : Anhydrous sodium sulfate Mg sulfate : Anhydrous magnesium sulfate Citrate : Tri-sodium citrate dihydrate of activity 86.4% with a particle size distribution between 425µm and 850µm MA/AA : Copolymer of 1:4 maleic/acrylic acid, average molecular weight about 70,000 MA/AA (1) : Copolymer of 4:6 maleic/acrylic acid, average molecular weight about 10,000 AA : Sodium polyacrylate polymer of average molecular weight 4,500 CMC : Sodium carboxymethyl cellulose Cellulose ether : Methyl cellulose ether with a degree of polymerization of 650 available from Shin Etsu Chemicals Protease : Proteolytic enzyme, having 3.3% by weight of active enzyme, sold by NOVO Industries A/S under the tradename Savinase Protease I : Proteolytic enzyme, having 4% by weight of active enzyme, as described in WO 95/10591, sold by Genencor Int. Inc. Alcalase : Proteolytic enzyme, having 5.3% by weight of active enzyme, sold by NOVO Industries A/S Cellulase : Cellulytic enzyme, having 0.23% by weight of active enzyme, sold by NOVO Industries A/S under the tradename Carezyme Amylase : Amylolytic enzyme, having 1.6% by weight of active enzyme, sold by NOVO Industries A/S under the tradename Termamyl 120T Lipase : Lipolytic enzyme, having 2.0% by weight of active enzyme, sold by NOVO Industries A/S under the tradename Lipolase Lipase (1) : Lipolytic enzyme, having 2.0% by weight of active enzyme, sold by NOVO Industries A/S under the tradename Lipolase Ultra Endolase : Endoglucanase enzyme, having 1.5% by weight of active enzyme, sold by NOVO Industries A/S PB4 : Sodium perborate tetrahydrate of nominal formula NaBO 2 .3H 2 O.H 2 O 2 PB1 : Anhydrous sodium perborate bleach of nominal formula NaBO 2 .H 2 O 2 Percarbonate : Sodium percarbonate of nominal formula 2Na 2 CO 3 .3H 2 O 2 NOBS : Nonanoyloxybenzene sulfonate in the form of the sodium salt NAC-OBS : (6-nonamidocaproyl) oxybenzene sulfonate TAED : Tetraacetylethylenediamine DTPA : Diethylene triamine pentaacetic acid DTPMP : Diethylene triamine penta (methylene phosphonate), marketed by Monsanto under the Tradename Dequest 2060 EDDS : Ethylenediamine-N,N'-disuccinic acid, (S,S) isomer in the form of its sodium salt. Photoactivated : Sulfonated zinc phthlocyanine encapsulated in bleach (1) dextrin soluble polymer Photoactivated : Sulfonated alumino phthlocyanine encapsulated in bleach (2) dextrin soluble polymer Brightener 1 : Disodium 4,4'-bis(2-sulphostyryl)biphenyl Brightener 2 : Disodium 4,4'-bis(4-anilino-6-morpholino-1,3,5-triazin-2-yl)amino) stilbene-2:2'-disulfonate HEDP : 1,1-hydroxyethane diphosphonic acid PEGx : Polyethylene glycol, with a molecular weight of x (typically 4,000) PEO : Polyethylene oxide, with an average molecular weight of 200000 to 400000 TEPAE : Tetraethylenepentaamine ethoxylate PVI : Polyvinyl imidosole, with an average molecular weight of 20,000 PVP : Polyvinylpyrolidone polymer, with an average molecular weight of 60,000 PVNO : Polyvinylpyridine N-oxide polymer, with an average molecular weight of 50,000 PVPVI : Copolymer of polyvinylpyrolidone and vinylimidazole, with an average molecular weight of 20,000 QEA : bis((C 2 H 5 O)(C 2 H 4 O) n )(CH 3 ) -N + -C 6 H 12 -N + -(CH 3 ) bis((C 2 H 5 O)-(C 2 H 4 O)) n , wherein n = from 20 to 30 SRP 1 : Anionically end capped poly esters SRP 2 : Diethoxylated poly (1, 2 propylene terephtalate) short block polymer PEI : Polyethyleneimine with an average molecular weight of 1800 and an average ethoxylation degree of 7 ethyleneoxy residues per nitrogen Silicone antifoam : Polydimethylsiloxane foam controller with siloxane-oxyalkylene copolymer as dispersing agent with a ratio of said foam controller to said dispersing agent of 10:1 to 100:1 Opacifier : Water based monostyrene latex mixture, sold by BASF Aktiengesellschaft under the tradename Lytron 621 Wax : Paraffin wax PA30 : Polyacrylic acid of average molecular weight of between about 4,500 - 8,000. 480N : Random copolymer of 7:3 acrylate/methacrylate, average molecular weight about 3,500. Polygel/carbopol : High molecular weight crosslinked polyacrylates. Metasilicate : Sodium metasilicate (SiO 2 :Na 2 O ratio = 1.0). Nonionic : C 13 -C 15 mixed ethoxylated/propoxylated fatty alcohol with an average degree of ethoxylation of 3.8 and an average degree of propoxylation of 4.5. Neodol 45-13 : C14-C15 linear primary alcohol ethoxylate, sold by Shell Chemical CO. MnTACN : Manganese 1,4,7-trimethyl-1,4,7-triazacyclononane. PAAC : Pentaamine acetate cobalt(III) salt. Paraffin : Paraffin oil sold under the tradename Winog 70 by Wintershall. NaBz : Sodium benzoate. BzP : Benzoyl Peroxide. SCS : Sodium cumene sulphonate. BTA : Benzotriazole. PH : Measured as a 1% solution in distilled water at 20°C. PARP1 : Processed amine reaction product of Lupasol G35 with α-Damascone as made from Synthesis example II, mixed with a citric acid carrier as per processing method above described. PARP2 : Processed amine reaction product of Lupasol HF with 6-Damascone as made from Synthesis example II, mixed with a citric acid carrier and coated with carbonate and PEG4000 as per processing method above described. PARP3 : Processed amine reaction product of Lupasol HF with 6-Damascone as made from Synthesis example II, mixed with malonic acid carrier as per processing method above described. PARP4 : Processed amine reaction product of BNPP with 6-Damascone as made from Synthesis example I, mixed with a tartaric acid carrier as per processing method above described. PARP5 : Processed amine reaction product of LupasolG100 with 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde as made from Synthesis example II, mixed with a citric acid carrier and coated with PEG4000 and carbonate according to processing method above described. Clay I : Bentonite clay Clay II : Smectite clay Flocculating agent I : polyethylene oxide of average molecular weight of between 200,000 and 400,000 Flocculating agent II: polyethylene oxide of average molecular weight of between 400,000 and 1,000,000 Flocculating agent III: polymer of acrylamide and/ or acrylic acid of average molecular weight of 200,000 and 400,000 DOBS: Decanoyl oxybenzene sulfonate in the form of the sodium salt SRP 3 : Polysaccharide soil release polymer SRP 4 : Nonionically end capped poly esters Polymer : Polyvinylpyrrolidone K90 available from BASF under the tradename Luviskol K90 Dye fixative : Dye fixative commercially available from Clariant under the tradename Cartafix CB Polyamine : 1,4-Bis-(3-aminopropyl)piperazine Bayhibit AM : 2-Phosphonobutane-1,2,4-tricarboxylic acid commercially available from Bayer Fabric softener active: Di-(canoloyl-oxy-ethyl)hydroxyethyl methyl ammonium methylsulfate HPBDC : Hydroxypropyl beta-cyclodextrin RAMEB : Randomly methylated beta-cyclodextrin Bardac 2050 : Dioctyl dimethyl ammonium chloride, 50% solution Bardac 22250 : Didecyl dimethyl ammonium chloride, 50% solution Genamin C100 : Coco fatty amine ethoxylated with 10 moles ethylene oxide and commercially available from Clariant Genapol V4463 : Coco alcohol ethoxylated with 10 moles ethylene oxide and commercially available from Clariant Silwet 7604: Polyalkyleneoxide polysiloxanes of MW 4000 of formula R-(CH 3 ) 2 SiO-[(CH 3 ) 2 SiO] a -[(CH 3 )(R)SiO] b -Si(CH 3 ) 2 -R, wherein average a+b is 21, and commercially available from Osi Specialties, Inc., Danbury, Connecticut Silwet 7600: Polyalkyleneoxide polysiloxanes of MW 4000, of formula R-(CH 3 ) 2 SiO-[(CH 3 ) 2 SiO] a -[(CH 3 )(R)SiO] b -Si(CH 3 ) 2 -R, wherein average a+b is 11, and commercially available from Osi Specialties, Inc., Danbury, Connecticut In the following formulation examples all levels are quoted as % by weight of the composition unless otherwise stated, and incorporation of the processed amine reaction product so called herein after "PARP" in the fully formulated composition is carried out by dry addition in the composition as defined herein before. Example 1 The following high density granular laundry detergent compositions are in accord with the invention: A B C D E LAS 6.0 6.0 8.0 8.0 8.0 TAS 1.0 0.1 - 0.5 - C46(S)AS - - 2.0 2.5 - C25AS 4.5 5.5 - - - C68AS - - 2.0 5.0 7.0 C25E5 4.6 4.6 - - 3.4 C25E7 - - 3.4 3.4 1.0 C25E3S 5.0 4.5 - - - QAS - - - 0.8 - QAS (I) 0.5 1.0 - - - Zeolite A 20.0 18.1 18.1 18.0 14.1 Citric acid - 2.5 - - - Carbonate 10.0 13.0 13.0 13.0 25.0 SKS-6 - 10.0 - - - Silicate 0.5 0.3 1.4 1.4 3.0 Citrate - - - 1.0 - Sulfate - - 26.1 26.1 26.1 Mg sulfate - 0.2 0.3 - - MA/AA 1.0 1.0 0.3 0.3 0.3 CMC 0.4 0.4 0.2 0.2 0.2 PB4 - - 9.0 9.0 5.0 Percarbonate 18.0 18.0 - - - TAED 3.9 4.2 1.5 0.4 1.5 NAC-OBS - - - 2.0 1.0 DTPMP - - 0.25 0.25 0.25 SRP 2 - 0.2 - - - EDDS 0.5 0.5 - 0.25 0.4 CFAA - - - 1.0 - HEDP 0.4 0.4 0.3 0.3 0.3 QEA - 0.5 - - - Protease I - - - - 0.26 Protease 1.5 1.0 0.26 0.26 - Cellulase 0.3 0.3 0.3 - - Amylase 0.5 0.5 0.1 0.1 0.1 Lipase (1) 0.5 0.5 0.3 - - Photoactivated bleach (ppm) 20 ppm 20 ppm 15 ppm 15 ppm 15 ppm Brightener 1 0.09 0.09 0.09 0.09 0.09 Perfume spray on 0.4 0.4 0.3 0.3 0.3 PARP 1 - - 0.2 - - PARP 2 - - - - 0.4 PARP 3 0.2 0.1 - - - PARP 5 1 - - 2.0 - Silicone antifoam 0.3 0.3 0.5 0.5 0.5 Misc/minors to 100% Density in g/litre 850 850 850 850 850 F G H I LAS 2.0 6.0 6.0 5.0 TAS 0.5 1.0 0.1 1.5 C25AS 7.0 4.5 5.5 2.5 C68AS - - - 0.2 C25E5 10.0 4.6 4.6 2.6 C25E3S 2.0 5.0 4.5 0.5 QAS (I) 0.8 0.5 1.0 1.5 Zeolite A 18.1 20.0 18.1 16.2 Citric acid 2.5 - 2.5 1.5 Carbonate 10.0 10.0 13.0 20.6 SKS-6 10.0 - 10.0 4.3 Silicate 0.3 0.5 0.3 - Citrate 3.0 - - 1.4 Sulfate 6.0 - - - Mg sulfate 0.2 - 0.2 0.03 MA/AA 4.0 1.0 1.0 0.6 CMC 0.2 0.4 0.4 0.3 Percarbonate - 18.0 18.0 9.0 TAED - 3.9 4.2 3.2 DTPMP 0.25 - - - SRP 2 0.2 - 0.2 - EDDS - 0.5 0.5 0.1 CFAA 2.0 - - - TFAA - - - 1.1 HEDP 0.3 0.4 0.4 0.3 QEA 0.2 - 0.5 - Protease I 1.0 - - 0.3 Protease - 1.5 1.0 - Cellulase 0.3 0.3 0.3 0.3 Amylase 0.4 0.5 0.5 0.1 Lipase (1) 0.5 0.5 0.5 0.1 Photoactivated bleach (ppm) - 20 ppm 20 ppm 20 ppm PVNO/PVPVI 0.1 - - - Brightener 1 - 0.09 0.09 0.01 Brightener 2 - - - 0.09 Perfume spray on 0.4 0.4 0.4 0.4 PARP 1 - 0.1 0.08 - PARP 2 0.8 0.4 - 1.4 Silicone antifoam - 0.3 0.3 0.3 Clay II - - - 12.0 Flocculating agent I - - - 0.3 Glycerol - - - 0.6 Wax - - - 0.4 Misc/minors to 100% Density in g/litre 850 850 850 850 Example 2 The following granular laundry detergent compositions of particular utility under European machine wash conditions are in accord with the invention: A B C D E F LAS 5.5 7.5 5.0 5.0 6.0 7.0 TAS 1.25 1.86 - 0.8 0.4 0.3 C24AS/C25AS - 2.24 5.0 5.0 5.0 2.2 C25E3S - 0.76 1.0 1.5 3.0 1.0 C45E7 3.25 - - - - 3.0 TFAA - - 2.0 - - - C25E5 - 5.5 - - - - QAS 0.8 - - - - - QAS II - 0.7 1.0 0.5 1.0 0.7 STPP 19.7 - - - - - Zeolite A - 19.5 25.0 19.5 20.0 17.0 NaSKS-6/citric acid (79:21) - 10.6 - 10.6 - - NaSKS-6 - - 9.0 - 10.0 10.0 Carbonate 6.1 10.0 9.0 10.0 10.0 18.0 Bicarbonate - 2.0 7.0 5.0 - 2.0 Silicate 6.8 - - 0.3 0.5 - Citrate - - 4.0 4.0 - - Sulfate 39.8 - - 5.0 - 12.0 Mg sulfate - - 0.1 0.2 0.2 - MA/AA 0.5 1.6 3.0 4.0 1.0 1.0 CMC 0.2 0.4 1.0 1.0 0.4 0.4 PB4 5.0 12.7 - - - - Percarbonate - - - - 18.0 15.0 TAED 0.5 3.1 - - 5.0 - NAC-OBS 1.0 3.5 - - - 2.5 DTPMP 0.25 0.2 0.3 0.4 - 0.2 HEDP - 0.3 - 0.3 0.3 0.3 QEA - - 1.0 1.0 1.0 - Protease I - - - 0.5 1.2 - Protease 0.26 0.85 0.9 1.0 - 0.7 Lipase (1) 0.15 0.15 0.3 0.3 0.3 0.2 Cellulase 0.28 0.28 0.2 0.2 0.3 0.3 Amylase 0.1 0.1 0.4 0.4 0.6 0.2 PVNO/PVPVI - - 0.2 0.2 - - PVP 0.9 1.3 - - - 0.9 SRP 1 - - 0.2 0.2 0.2 - Photoactivated bleach (1) (ppm) 15 ppm 27 ppm - - 20 ppm 20 ppm Photoactivated bleach (2) (ppm) 15 ppm - - - - - Brightener 1 0.08 0.19 - - 0.09 0.15 Brightener 2 - 0.04 - - - - Perfume 0.3 0.3 0.4 0.3 0.4 0.3 PARP1 0.4 0.20 0.1 - - - PARP2 - - 1.0 0.5 0.1 0.4 Silicone antifoam 0.5 2.4 0.3 0.5 0.3 2.0 Minors/misc to 100% Density in g/litre 750 750 750 750 750 750 Example 3 The following detergent formulations of particular utility under European machine wash conditions were prepared in accord with the invention. A B C D Blown powder LAS 6.0 5.0 11.0 6.0 TAS 2.0 - - 2.0 Zeolite A 24.0 - - 20.0 STPP - 27.0 24.0 - Sulfate 4.0 6.0 13.0 - MA/AA 1.0 4.0 6.0 2.0 Silicate 1.0 7.0 3.0 3.0 CMC 1.0 1.0 0.5 0.6 Brightener 1 0.2 0.2 0.2 0.2 Silicone antifoam 1.0 1.0 1.0 0.3 DTPMP 0.4 0.4 0.2 0.4 Spray on Brightener 0.02 - - 0.02 C45E7 - - - 5.0 C45E2 2.5 2.5 2.0 - C45E3 2.6 2.5 2.0 - Perfume 0.5 0.3 0.5 0.2 Silicone antifoam 0.3 0.3 0.3 - Dry additives QEA - - - 1.0 EDDS 0.3 - - - Sulfate 2.0 3.0 5.0 10.0 Carbonate 6.0 13.0 11.0 14.0 Citric acid 2.5 - - 2.0 QAS II 0.5 - - 0.5 SKS-6 10.0 - - - Percarbonate 18.5 - - - PB4 - 18.0 10.0 21.5 TAED 2.0 2.0 - 2.0 NAC-OBS 3.0 2.0 4.0 - Protease 1.0 1.0 1.0 1.0 Lipase - 0.4 - 0.2 Lipase (1) 0.4 - 0.4 - Amylase 0.2 0.2 0.2 0.4 Brightener 1 0.05 - - 0.05 PARP3 0.08 0.1 0.4 0.2 Misc/minor to 100% Example 4 The following granular detergent formulations were prepared in accord with the invention. A B C D E F Blown powder LAS 23.0 8.0 7.0 9.0 7.0 7.0 TAS - - - - 1.0 - C45AS 6.0 6.0 5.0 8.0 - - C45AES - 1.0 1.0 1.0 - - C45E35 - - - - 2.0 4.0 Zeolite A 10.0 18.0 14.0 12.0 10.0 10.0 MA/AA - 0.5 - - - 2.0 MA/AA (1) 7.0 - - - - - AA - 3.0 3.0 2.0 3.0 3.0 Sulfate 5.0 6.3 14.3 11.0 15.0 19.3 Silicate 10.0 1.0 1.0 1.0 1.0 1.0 Carbonate 13.0 19.0 8.0 20.7 8.0 6.0 PEG 4000 0.4 1.5 1.5 1.0 1.0 1.0 DTPA - 0.9 0.5 - - 0.5 Brightener 2 0.3 0.2 0.3 - 0.1 0.3 Spray on C45E7 - 2.0 - - 2.0 2.0 C25E9 3.0 - - - - - C23E9 - - 1.5 2.0 - 2.0 Perfume 0.3 0.3 0.3 2.0 0.3 0.3 Agglomerates C45AS - 5.0 5.0 2.0 - 5.0 LAS - 2.0 2.0 - - 2.0 Zeolite A - 7.5 7.5 8.0 - 7.5 Carbonate - 4.0 4.0 5.0 - 4.0 PEG 4000 - 0.5 0.5 - - 0.5 Misc (water etc) - 2.0 2.0 2.0 - 2.0 Dry additives QAS (I) - - - - 1.0 - Citric acid - - - - 2.0 - PB4 - - - - 12.0 1.0 PB1 4.0 1.0 3.0 2.0 - - Percarbonate - - - - 2.0 10.0 Carbonate - 5.3 1.8 - 4.0 4.0 NOBS 4.0 - 6.0 - - 0.6 Methyl cellulose 0.2 - - - - - SKS-6 8.0 - - - - - STS - - 2.0 - 1.0 - Cumene sulfonic acid - 1.0 - - - 2.0 Lipase 0.2 - 0.2 - 0.2 0.4 Cellulase 0.2 0.2 0.2 0.3 0.2 0.2 Amylase 0.2 - 0.1 - 0.2 - Protease 0.5 0.5 0.5 0.3 0.5 0.5 PVPVI - - - - 0.5 0.1 PVP - - - - 0.5 - PVNO - - 0.5 0.3 - - QEA - - - - 1.0 - SRP1 0.2 0.5 0.3 - 0.2 - PARP3 0.2 0.1 0.4 0.5 0.3 0.25 Silicone antifoam 0.2 0.4 0.2 0.4 0.1 - Mg sulfate - - 0.2 - 0.2 - Misc/minors to 100% G H I J Blown powder Clay I or II 7.0 10.0 6.0 2.0 LAS 16.0 5.0 11.0 6.0 TAS - 5.0 - 2.0 Zeolite A - 20.0 - 10.0 STPP 24.0 - 14.0 - Sulfate - 2.0 - - MA/AA - 2.0 1.0 1.0 Silicate 4.0 7.0 3.0 - CMC 1.0 - 0.5 0.6 Brightener 1 0.2 0.2 0.2 0.2 Carbonate 10.0 10.0 20.0 - DTPMP 0.4 0.4 0.2 - Spray on Brightener 1 0.02 - - 0.02 C45E7 or E9 - - 2.0 1.0 C45E3 or E4 - - 2.0 4.0 Perfume 0.5 - 0.5 0.2 Silicone antifoam 0.3 - - - Dry additives Flocculating agent I or II 0.3 1.0 1.0 0.5 QEA - - - 1.0 HEDP/EDDS 0.3 - - - Sulfate 2.0 - - - Carbonate 20.0 13.0 15.0 24.0 Citric acid 2.5 - - 2.0 QAS - - 0.5 0.5 NaSKS-6 3.5 - - 5.0 Percarbonate - - - 9.0 PB4 - - 5.0 NOBS - - - 1.3 TAED - - 2.0 1.5 Protease 1.0 1.0 1.0 1.0 Lipase - 0.4 - 0.2 Amylase 0.2 0.2 0.2 0.4 Brightener 2 0.05 - - 0.05 Perfume 1.0 0.2 0.5 0.3 Speckle 1.2 0.5 2.0 - PARP2 0.66 0.8 0.4 1.0 Misc/minor to 100% Example 5 The following nil bleach-containing detergent formulations of particular use in the washing of coloured clothing, according to the present invention were prepared: A B C Blown Powder Zeolite A 15.0 15.0 - Sulfate 0.0 5.0 - LAS 3.0 3.0 - DTPMP 0.4 0.5 - CMC 0.4 0.4 - MA/AA 4.0 4.0 - Agglomerates C45AS - - 11.0 LAS 6.0 5.0 - TAS 3.0 2.0 - Silicate 4.0 4.0 - Zeolite A 10.0 15.0 13.0 CMC - - 0.5 MA/AA - - 2.0 Carbonate 9.0 7.0 7.0 Spray On Perfume 0.3 0.3 0.5 C45E7 4.0 4.0 4.0 C25E3 2.0 2.0 2.0 Dry additives MA/AA - - 3.0 NaSKS-6 - - 12.0 Citrate 10.0 - 8.0 Bicarbonate 7.0 3.0 5.0 Carbonate 6.0 - 7.0 PVPVI/PVNO 0.5 0.5 0.5 Alcalase 0.5 0.3 0.9 Lipase 0.4 0.4 0.4 Amylase 0.6 0.6 0.6 Cellulase 0.6 0.6 0.6 PARP1 0.7 0.2 0.1 Silicone antifoam 5.0 5.0 5.0 Dry additives Sulfate 0.0 9.0 0.0 Misc/minors to 100% 100.0 100.0 100.0 Density (g/litre) 700 700 700 Example 6 The following granular detergent formulations were prepared in accord with the invention. A B C D Base granule Zeolite A 30.0 22.0 24.0 10.0 Sulfate 10.0 5.0 10.0 7.0 MA/AA 3.0 - - - AA - 1.6 2.0 - MA/AA (1) - 12.0 - 6.0 LAS 14.0 10.0 9.0 20.0 C45AS 8.0 7.0 9.0 7.0 C45AES - 1.0 1.0 - Silicate - 1.0 0.5 10.0 Soap - 2.0 - - Brightener 1 0.2 0.2 0.2 0.2 Carbonate 6.0 9.0 10.0 10.0 PEG 4000 - 1.0 1.5 - DTPA - 0.4 - - Spray on C25E9 - - - 5.0 C45E7 1.0 1.0 - - C23E9 - 1.0 2.5 - Perfume 0.2 0.3 0.3 - Dry additives Carbonate 5.0 5.0 15.0 6.0 PVPVI/PVNO 0.5 - 0.3 - Protease 1.0 1.0 1.0 0.5 Lipase 0.4 - - 0.4 Amylase 0.1 - - 0.1 Cellulase 0.1 0.2 0.2 0.1 NOBS - 4.0 - 4.5 PB1 1.0 5.0 1.5 6.0 Sulfate 4.0 5.0 - 5.0 SRPI - 0.4 - - PARP1 0.1 0.5 0.2 - PARP3 - 0.1 - 0.2 Sud supressor - 0.5 0.5 - Misc/minor to 100% Example 7 The following granular detergent compositions were prepared in accord with the invention. A B C Blown powder Zeolite A 20.0 - 15.0 STPP - 20.0 - Sulphate - - 5.0 Carbonate - - 5.0 TAS - - 1.0 LAS 6.0 6.0 6.0 C68AS 2.0 2.0 - Silicate 3.0 8.0 - MA/AA 4.0 2.0 2.0 CMC 0.6 0.6 0.2 Brightener 1 0.2 0.2 0.1 DTPMP 0.4 0.4 0.1 STS - - 1.0 Spray on C45E7 5.0 5.0 4.0 Silicone antifoam 0.3 0.3 0.1 Perfume 0.2 0.2 0.3 Dry additives QEA - - 1.0 Carbonate 14.0 9.0 10.0 PB1 1.5 2.0 - PB4 18.5 13.0 13.0 TAED 2.0 2.0 2.0 QAS (I) - - 1.0 Photoactivated bleach 15 ppm 15 ppm 15ppm SKS-6 - - 3.0 Protease 1.0 1.0 0.2 Lipase 0.2 0.2 0.2 Amylase 0.4 0.4 0.2 Cellulase 0.1 0.1 0.2 Sulfate 10.0 20.0 5.0 PARP5 1.2 2.0 1 Misc/minors to 100% Density (g/litre) 700 700 700 Example 8 The following detergent compositions, according to the present invention were prepared: A B C Blown Powder Zeolite A 15.0 15.0 15.0 Sulfate 0.0 5.0 0.0 LAS 3.0 3.0 3.0 QAS - 1.5 1.5 DTPMP 0.4 0.2 0.4 EDDS - 0.4 0.2 CMC 0.4 0.4 0.4 MA/AA 4.0 2.0 2.0 Agglomerates LAS 5.0 5.0 5.0 TAS 2.0 2.0 1.0 Silicate 3.0 3.0 4.0 Zeolite A 8.0 8.0 8.0 Carbonate 8.0 8.0 4.0 Spray On Perfume 0.3 0.3 0.3 C45E7 2.0 2.0 2.0 C25E3 2.0 - - Dry additives Citrate 5.0 - 2.0 Bicarbonate - 3.0 - Carbonate 8.0 15.0 10.0 TAED 6.0 2.0 5.0 PB1 14.0 7.0 10.0 PEO - - 0.2 PARP3 0.2 0. 0.075(c) Bentonite clay - - 10.0 Protease 1.0 1.0 1.0 Lipase 0.4 0.4 0.4 Amylase 0.6 0.6 0.6 Cellulase 0.6 0.6 0.6 Silicone antifoam 5.0 5.0 5.0 Dry additives Sodium sulfate 0.0 3.0 0.0 Misc/minors to 100% 100.0 100.0 100.0 Density (g/litre) 850 850 850 D E F G H Blown Powder STPP/Zeolite A 9.0 15.0 15.0 9.0 9.0 Flocculating agent II or III 0.5 0.2 0.9 1.5 - LAS 7.5 23.0 3.0 7.5 7.5 QAS 2.5 1.5 - - - DTPMP 0.4 0.2 0.4 0.4 0.4 HEDP or EDDS - 0.4 0.2 - - CMC 0.1 0.4 0.4 0.1 0.1 Sodium carbonate 5.0 20.0 20.0 10.0 - Brightener 0.05 - - 0.05 0.05 Clay I or II - 10.0 - - - STS 0.5 - - 0.5 0.5 MA/AA 1.5 2.0 2.0 1.5 1.5 Agglomerates Suds suppresser (silicon) 1.0 1.0 - 2.0 0.5 Agglomerate Clay 9.0 - - 4.0 10.0 Wax 0.5 - - 0.5 1.5 Glycerol 0.5 - - 0.5 0.5 Agglomerate LAS - 5.0 5.0 - - TAS - 2.0 1.0 - - Silicate - 3.0 4.0 - - Zeolite A - 8.0 8.0 - - Carbonate - 8.0 4.0 - - Spray On Perfume 0.3 - - 0.3 0.3 C45E7 or E9 2.0 - - 2.0 2.0 C25E3 or E4 2.0 - - 2.0 2.0 Dry additives Citrate or citric acid 2.5 - 2.0 2.5 2.5 Clay I or II - 5.0 5.0 - - Flocculating agent I or II - - - - 0.2 Bicarbonate - 3.0 - - - Carbonate 15.0 - - 25.0 31.0 TAED 1.0 2.0 5.0 1.0 - Sodium perborate or percarbonate 6.0 7.0 10.0 6.0 - SRP1, 2, 3 or 4 0.2 0.1 0.2 0.5 0.3 CMC or nonionic cellulose ether 1.0 1.5 0.5 - - Protease 0.3 1.0 1.0 0.3 0.3 Lipase - 0.4 0.4 - - Amylase 0.2 0.6 0.6 0.2 0.2 Cellulase 0.2 0.6 0.6 0.2 0.2 Silicone antifoam - 5.0 5.0 - - Perfume (starch) 0.2 0.3 1.0 0.2 0.2 Speckle 0.5 0.5 0.1 - 1.0 NaSKS-6 (silicate 2R) 3.5 - - - 3.5 Photobleach 0.1 - - 0.1 0.1 Soap 0.5 2.5 - 0.5 0.5 Sodium sulfate - 3.0 - - - PARP2 2.0 1.6 1.0 0.4 0.08 Misc/minors to 100% 100.0 100.0 100.0 100.0 100.0 Density (g/litre) 850 850 850 850 850 Example 9 The following detergent formulations, according to the present invention were prepared: A B C D LAS 18.0 14.0 24.0 20.0 QAS 0.7 1.0 - 0.7 TFAA - 1.0 - - C23E56.5 - - 1.0 - C45E7 - 1.0 - - C45E3S 1.0 2.5 1.0 - STPP 32.0 18.0 30.0 22.0 Silicate 9.0 5.0 9.0 8.0 Carbonate 9.0 7.5 - 5.0 Bicarbonate - 7.5 - - PB1 3.0 1.0 - - PB4 - 1.0 - - NOBS 2.0 1.0 - - DTPMP - 1.0 - - DTPA 0.5 - 0.2 0.3 SRP 1 0.3 0.2 - 0.1 MA/AA 1.0 1.5 2.0 0.5 CMC 0.8 0.4 0.4 0.2 PEI - - 0.4 - Sodium sulfate 20.0 10.0 20.0 30.0 Mg sulfate 0.2 - 0.4 0.9 Protease 0.8 1.0 0.5 0.5 Amylase 0.5 0.4 - 0.25 Lipase 0.2 - 0.1 - Cellulase 0.15 - - 0.05 Photoactivated bleach (ppm) 30ppm 20ppm - 10ppm PARP5 2.0 1 0.8 2 Perfume spray on 0.3 0.3 0.1 0.2 Brightener 1/2 0.05 0.2 0.08 0.1 Misc/minors to 100% Example 10 The following is a composition in the form of a tablet, bar, extrudate or granule in accord with the invention A B C D E F G Sodium C 1 -C 13 alkylbenzenesulfonate 12.0 16.0 23.0 19.0 18.0 20.0 16.0 Sodium C 14 -C 15 alcohol sulfate 4.5 - - - 4.0 C 14 -C 15 alcohol ethoxylate (3) sulfate - - 2.0 - 1.0 1.0 1.0 Sodium C 14 -C 15 alcohol ethoxylate 2.0 2.0 - 1.3 - - 5.0 C 9 -C 14 alkyl dimethyl hydroxy ethyl quaternary ammonium salt - - 1.0 0.5 2.0 Tallow fatty acid - - - - 1.0 Sodium tripolyphosphate / Zeolite 23.0 25.0 14.0 22,0 20.0 10.0 20.0 Sodium carbonate 25.0 22.0 35.0 20.0 28.0 41.0 30.0 Sodium Polyacrylate (45%) 0.5 0.5 0.5 0.5 - - - Sodium polyacrylate/maleate polymer - - 1.0 1.0 1.0 2.0 0.5 Sodium silicate (1:6 ratio NaO/SiO 2 )(46%) 3.0 6.0 9.0 8.0 9.0 6.0 8.0 Sodium sulfate - - - - - 2.0 3.0 Sodium perborate/ percarbonate 5.0 5.0 10.0 - 3.0 1 0 - Poly(ethyleneglycol), MW ∼4000 (50%) 1.5 1.5 1.0 1.0 - - 0.5 Sodium carboxy methyl cellulose 1.0 1.0 1.0 - 0.5 0.5 0.5 NOBS/DOBS - 1.0 - - 1.0 0.7 - TAED 1.5 1.0 2.5 - 3.0 0.7 - SRP 1 1.5 1.5 1.0 1.0 - 1 0 - Clay I or II 5.0 6.0 12.0 7.0 10.0 4.0 3.0 Flocculating agent I or III 0.2 0.2 3.0 2.0 0.1 1.0 0.5 Humectant 0.5 1.0 0.5 1.0 0.5 0.5 - Wax 0.5 0.5 1.0 - - 0.5 0.5 Moisture 7.5 7.5 6.0 7.0 5.0 3.0 5.0 Magnesium sulphate - - - - - 0.5 1.5 Chelant - - - - 0.8 0.6 1.0 Enzymes, including amylase, cellulase, protease and lipase - - - - 2.0 1.5 2.0 Speckle 2.5 4.1 4.2 4.4 5.6 5.0 5.2 minors, e.g. perfume, PVP, PVPVI/PVNO, brightener, photo-bleach, 2.0 1.0 1.0 1.0 2.5 1.5 1.0 PARP2 1.6 2.0 0.8 0.2 1.0 0.16 0.5 H I J K Sodium C 11 -C 13 alkylbenzenesulfonate 23.0 13.0 20.0 18.0 Sodium C 14 -C 15 alcohol sulfate - 4.0 - - Clay I or II 5.0 10.0 14.0 6.0 Flocculating agent I or II 0.2 0.3 0.1 0.9 Wax 0.5 0.5 1.0 - Humectant (glycerol/ silica) 0.5 2.0 1.5 - C 14 -C 15 alcohol ethoxylate sulfate - - 2.0 Sodium C 14 -C 15 alcohol ethoxylate ( 2.5 3.5 - - C 9 -C 14 alkyl dimethyl hydroxy ethyl quaternary ammonium salt - - 0.5 Tallow fatty acid 0.5 - - - Tallow alcohol ethoxylate (50) - - 1.3 Sodium tripolyphosphate - 41.0 - 20.0 Zeolite A, hydrate (0.1-10 micron size) 26.3 - 21.3 - Sodium carbonate 24.0 22.0 35.0 27.0 Sodium Polyacrylate (45%) 2.4 - 2.7 - Sodium polyacrylate/maleate polymer - - 1.0 2.5 Sodium silicate (1.6 or 2 or 2.2 ratio NaO/SiO 2 )(46%) 4.0 7.0 2.0 6.0 Sodium sulfate - 6.0 2.0 - Sodium perborate/ percarbonate 8.0 4.0 - 12.0 Poly(ethyleneglycol), MW ∼4000 (50%) 1.7 0.4 1.0 - Sodium carboxy methyl cellulose 1.0 - - 0.3 Citric acid - - 3.0 - NOBS/ DOBS 1.2 - - 1.0 TAED 0.6 1.5 - 3.0 Perfume 0.5 1.0 0.3 0.4 SRP 1 - 1.5 1.0 1.0 Moisture 7.5 3.1 6.1 7.3 Magnesium sulphate - - - 1.0 Chelant - - - 0.5 speckle 1.0 0.5 0.2 2.7 Enzymes, including amylase, cellulase, protease and lipase - 1.0 - 1.5 minors, e.g. brightener. photo-bleach 1.0 1.0 1.0 1.0 PARP2 0.2 0.5 1.6 0.8 Example 11 The following liquid detergent formulations were prepared in accord with the invention (levels are given as parts per weight). A B C D E LAS 11.5 8.8 - 3.9 - C25E2.5S - 3.0 18.0 - 16.0 C45E2.25S 11.5 3.0 - 15.7 - C23E9 - 2.7 1.8 2.0 1.0 C23E7 3.2 - - - - CFAA - - 5.2 - 3.1 TPKFA 1.6 - 2.0 0.5 2.0 Citric acid (50%) 6.5 1.2 2.5 4.4 2.5 Calcium formate 0.1 0.06 0.1 - - Sodium formate 0.5 0.06 0.1 0.05 0.05 Sodium cumene sulfonate 4.0 1.0 3.0 1.18 - Borate 0.6 - 3.0 2.0 2.9 Sodium hydroxide 5.8 2.0 3.5 3.7 2.7 Ethanol 1.75 1.0 3.6 4.2 2.9 1, 2 propanediol 3.3 2.0 8.0 7.9 5.3 Monoethanolamine 3.0 1.5 1.3 2.5 0.8 TEPAE 1.6 - 1.3 1.2 1.2 Protease 1.0 0.3 1.0 0.5 0.7 Lipase - - 0.1 - - Cellulase - - 0.1 0.2 0.05 Amylase - - - 0.1 - SRP1 0.2 - 0.1 - - DTPA - - 0.3 - - PVNO - - 0.3 - 0.2 PARP1 0.1 - - - - PARP2 - 0.8 - - - PARP3 - - 0.2 - - PARP5 - - - 1.4 1.0 Brightener 1 0.2 0.07 0.1 - - Silicone antifoam 0.04 0.02 0.1 0.1 0.1 Water/minors up to 100% Example 12 The following liquid detergent formulations were prepared in accord with the invention (levels are given in parts per weight): A B C D E F G H LAS 10.0 13.0 9.0 - 25.0 - - - C25AS 4.0 1.0 2.0 10.0 - 13.0 18.0 15.0 C25E3S 1.0 - - 3.0 - 2.0 2.0 4.0 C25E7 6.0 8.0 13.0 2.5 - - 4.0 4.0 TFAA - - - 4.5 - 6.0 8.0 8.0 APA - 1.4 - - 3.0 1.0 2.0 - TPKFA 2.0 - 13.0 7.0 - 15.0 11.0 11.0 Citric acid 2.0 3.0 1.0 1.5 1.0 1.0 1.0 1.0 Dodecenyl/tetradecenyl succinic acid 12.0 10.0 - - 15.0 - - - Rape seed fatty acid 4.0 2.0 1.0 - 1.0 - 3.5 - Ethanol 4.0 4.0 7.0 2.0 7.0 2.0 3.0 2.0 1,2 Propanediol 4.0 4.0 2.0 7.0 6.0 8.0 10.0 13.0 Monoethanolamine - - - 5.0 - - 9.0 9.0 Triethanolamine - - 8.0 - - - - - TEPAE 0.5 - 0.5 0.2 - - 0.4 0.3 DTPMP 1.0 1.0 0.5 1.0 2.0 1.2 1.0 - Protease 0.5 0.5 0.4 0.25 - 0.5 0.3 0.6 Alcalase - - - - 1.5 - - - Lipase - 0.10 - 0.01 - - 0.15 0.15 Amylase 0.25 0.25 0.6 0.5 0.25 0.9 0.6 0.6 Cellulase - - - 0.05 - - 0.15 0.15 Endolase - - - 0.10 - - 0.07 - SRP2 0.3 - 0.3 0.1 - - 0.2 0.1 Boric acid 0.1 0.2 1.0 2.0 1.0 1.5 2.5 2.5 Calcium chloride - 0.02 - 0.01 - - - - Bentonite clay - - - - 4.0 4.0 - - Brightener 1 - 0.4 - - 0.1 0.2 0.3 - Sud supressor 0.1 0.3 - 0.1 0.4 - - - Opacifier 0.5 0.4 - 0.3 0.8 0.7 - - PARP1 0.2 - 0.1 - 0.5 - 0.08 0.2 PARP3 - 0.2 - 0.1 - 0.08 0.1 0.07 Water/minors up to 100% NaOH up to pH 8.0 8.0 7.6 7.7 8.0 7.5 8.0 8.2 Example 13 The following liquid detergent compositions were prepared in accord with the invention (levels are given in parts per weight). A B LAS 27.6 18.9 C45AS 13.8 5.9 C13E8 3.0 3.1 Oleic acid 3.4 2.5 Citric acid 5.4 5.4 Sodium hydroxide 0.4 3.6 Calcium formate 0.2 0.1 Sodium formate - 0.5 Ethanol 7.0 - Monoethanolamine 16.5 8.0 1,2 propanediol 5.9 5.5 Xylene sulfonic acid - 2.4 TEPAE 1.5 0.8 Protease 1.5 0.6 PEG - 0.7 Brightener 2 0.4 0.1 Perfume spray on 0.5 0.3 PARP2 0.4 - PARP5 1.2 1.0 Water/minors up to 100% Example 14 The following laundry bar detergent compositions were prepared in accord with the invention (levels are given in parts per weight). A B C D E F G H LAS - - 19.0 15.0 21.0 6.75 8.8 - C28AS 30.0 13.5 - - - 15.75 11.2 22.5 Sodium laurate 2.5 9.0 - - - - - - Zeolite A 2.0 1.25 - - - 1.25 1.25 1.25 Carbonate 10.0 - 11.0 5.0 2.0 7.0 13.0 9.0 Calcium carbonate 27.5 39.0 35.0 - - 40.0 - 40.0 Sulfate 5.0 5.0 3.0 5.0 3.0 - - 5.0 TSPP 5.0 - - - - 5.0 2.5 - STPP 5.0 15.0 10.0 - - 7.0 8.0 10.0 Bentonite clay - 10.0 - - 5.0 - - - DTPMP - 0.7 0.6 - 0.6 0.7 0.7 0.7 CMC - 1.0 1.0 1.0 1.0 - - 1.0 Talc - - 10.0 15.0 10.0 - - - Silicate - - 4.0 5.0 3.0 - - - PVNO 0.02 0.03 - 0.01 - 0.02 - - MA/AA 0.4 1.0 - - 0.2 0.4 0.5 0.4 SRP1 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Protease - 0.12 - 0.08 0.08 - - 0.1 Lipase - 0.1 - 0.1 - - - - Amylase - - 0.8 - - - 0.1 - Cellulase - 0.15 - - 0.15 0.1 - - PEO - 0.2 - 0.2 0.3 - - 0.3 Perfume 1.0 0.5 0.3 0.2 0.4 - - 0.4 Mg sulfate - - 3.0 3.0 3.0 - - - PARP1 0.1 - - - - 0.08 - - PARP2 - 0.8 - - - - 0.2 - PARP3 - - 0.2 - - - - 1 PARP5 - - - 1.4 1.0 - - 1.0 Brightener 0.15 0.10 0.15 - - - - 0.1 Photoactivated bleach (ppm) - 15.0 15.0 15.0 15.0 - - 15.0 Example 15 The following detergent additive compositions were prepared according to the present invention : A B C LAS - 5.0 5.0 STPP 30.0 - 20.0 Zeolite A - 35.0 20.0 PB1 20.0 15.0 - TAED 10.0 8.0 - PARP1 0.1 - 0.1 PARP2 - 0.4. 0.2 Protease - 0.3 0.3 Amylase - 0.06 0.06 Minors, water and miscellaneous Up to 100% Example 16 The following compact high density (0.96Kg/l) dishwashing detergent compositions were prepared according to the present invention : A B C D E F G H STPP - - 54.3 51.4 51.4 - - 50.9 Citrate 35.0 17.0 - - - 46.1 40.2 - Carbonate - 15.0 12.0 14.0 4.0 - 7.0 31.1 Bicarbonate - - - - - 25.4 - - Silicate 32.0 14.8 14.8 10.0 10.0 1.0 25.0 3.1 Metasilicate - 2.5 - 9.0 9.0 - - - PB1 1.9 9.7 7.8 7.8 7.8 - - - PB4 8.6 - - - - - - - Percarbonate - - - - - 6.7 11.8 4.8 Nonionic 1.5 2.0 1.5 1.7 1.5 2.6 1.9 5.3 TAED 5.2 2.4 - - - 2.2 - 1.4 HEDP - 1.0 - - - - - - DTPMP - 0.6 - - - - - - MnTACN - - - - - - 0.008 - PAAC - - 0.008 0.01 0.007 - - - BzP - - - - 1.4 - - - Paraffin 0.5 0.5 0.5 0.5 0.5 0.6 - - PARP5 1.2 1.4 1.2 1.1 - - - 0.5 PARP1 - - - - 0.1 0.3 0.2 - Protease 0.072 0.072 0.029 0.053 0.046 0.026 0.059 0.06 Amylase 0.012 0.012 0.006 0.012 0.013 0.009 0.017 0.03 Lipase - 0.001 - 0.005 - - - - BTA 0.3 0.3 0.3 0.3 0.3 - 0.3 0.3 MA/AA - - - - - - 4.2 - 480N 3.3 6.0 - - - - - 0.9 Perfume 0.2 0.2 0.2 0.2 0.2 0.2 0.1 0.1 Sulphate 7.0 20.0 5.0 2.2 0.8 12.0 4.6 - pH 10.8 11.0 10.8 11.3 11.3 9.6 10.8 10.9 Miscellaneous and water Up to 100% Example 17 The following granular dishwashing detergent compositions of bulk density 1.02Kg/L were prepared according to the present invention : A B C D E F G H STPP 30.0 30.0 33.0 34.2 29.6 31.1 26.6 17.6 Carbonate 29.5 30.0 29.0 24.0 15.0 36.0 2.1 38.0 Silicate 7.4 7.4 7.5 7.2 13.3 3.4 43.7 12.4 Metasilicate - - 4.5 5.1 - - - - Percarbonate - - - - - 4.0 - - PB1 4.4 4.2 4.5 4.5 - - - - NADCC - - - - 2.0 - 1.6 1.0 Nonionic 1.2 1.0 0.7 0.8 1.9 0.7 0.6 0.3 TAED 1.0 - - - - 0.8 - - PAAC - 0.004 0.004 0.004 - - - - BzP - - - 1.4 - - - - Paraffin 0.25 0.25 0.25 0.25 - - - - PARP5 1.0(c) 0.5(c) 1.4 1.8 - - 1.0(c) 0.5(c) PARP2 - - - - 1.0 1.5 0.8 0.1 Protease 0.036 0.015 0.03 0.028 - 0.03 - - Amylase 0.003 0.003 0.01 0.006 - 0.01 - - Lipase 0.005 - 0.001 - - - - - BTA 0.15 0.15 0.15 0.15 - - - - Perfume 0.2 0.2 0.2 0.2 0.1 0.2 0.2 - Sulphate 23.4 25.0 22.0 18.5 30.1 19.3 23.1 23.6 pH 10.8 10.8 11.3 11.3 10.7 11.5 12.7 10.9 Miscellaneous and water Up to 100% Example 18 The following tablet detergent compositions were prepared according to the present invention by compression of a granular dishwashing detergent composition at a pressure of 13KN/cm 2 using a standard 12 head rotary press: A B C D E F STPP - 48.8 49.2 38.0 - 46.8 Citrate 26.4 - - - 31.1 - Carbonate - 4.0 12.0 14.4 10.0 20.0 Silicate 26.4 14.8 15.0 12.6 17.7 2.4 PARP1 0.2 - - - 0.05 - PARP2 - 1.0 - - - 1.0 PARP5 - - 1.2 1 - - Protease 0.058 0.072 0.041 0.033 0.052 0.013 Amylase 0.01 0.03 0.012 0.007 0.016 0.002 Lipase 0.005 - - - - - PB1 1.6 7.7 12.2 10.6 15.7 - PB4 6.9 - - - - 14.4 Nonionic 1.5 2.0 1.5 1.65 0.8 6.3 PAAC - - 0.02 0.009 - - MnTACN - - - - 0.007 - TAED 4.3 2.5 - - 1.3 1.8 HEDP 0.7 - - 0.7 - 0.4 DTPMP 0.65 - - - - - Paraffin 0.4 0.5 0.5 0.55 - - BTA 0.2 0.3 0.3 0.3 - - PA30 3.2 - - - - - MA/AA - - - - 4.5 0.55 Perfume - - 0.05 0.05 0.2 0.2 Sulphate 24.0 13.0 2.3 - 10.7 3.4 Weight of tablet 25g 25g 20g 30g 18g 20g pH 10.6 10.6 10.7 10.7 10.9 11.2 Miscellaneous and water Up to 100% Example 19 The following liquid dishwashing detergent compositions of density 1.40Kg/L were prepared according to the present invention : A B C D STPP 17.5 17.5 17.2 16.0 Carbonate 2.0 - 2.4 - Silicate 5.3 6.1 14.6 15.7 NaOCI 1.15 1.15 1.15 1.25 Polygen/carbopol 1.1 1.0 1.1 1.25 Nonionic - - 0.1 - NaBz 0.75 0.75 - - PARP3 0.08 0.2 0.1 0.5 NaOH - 1.9 - 3.5 KOH 2.8 3.5 3.0 - pH 11.0 11.7 10.9 11.0 Sulphate, miscellaneous and water up to 100% Example 20 The following liquid rinse aid compositions were prepared according to the present invention : A B C Nonionic 12.0 - 14.5 Nonionic blend - 64.0 - Citric 3.2 - 6.5 HEDP 0.5 - - PEG - 5.0 - SCS 4.8 - 7.0 Ethanol 6.0 8.0 - PARP5 3 - 1 PARP3 - 0.2 0.1 pH of the liquid 2.0 7.5 / Miscellaneous and water Up to 100% Example 21 The following liquid dishwashing compositions were prepared according to the present invention : A B C D E C17ES 28.5 27.4 19.2 34.1 34.1 Amine oxide 2.6 5.0 2.0 3.0 3.0 C12 glucose amide - - 6.0 - - Betaine 0.9 - - 2.0 2.0 Xylene sulfonate 2.0 4.0 - 2.0 - Neodol C11E9 - - 5.0 - - Polyhydroxy fatty acid amide - - - 6.5 6.5 Sodium diethylene penta acetate - - 0.03 - - (40%) TAED - - - 0.06 0.06 Sucrose - - - 1.5 1.5 Ethanol 4.0 5.5 5.5 9.1 9.1 Alkyl diphenyl oxide disulfonate - - - - 2.3 Ca formate - - - 0.5 1.1 Ammonium citrate 0.06 0.1 - - - Na chloride - 1.0 - - - Mg chloride 3.3 - 0.7 - - Ca chloride - - 0.4 - - Na sulfate - - 0.06 - - Mg sulfate 0.08 - - - - Mg hydroxide - - - 2.2 2.2 Na hydroxide - - - 1.1 1.1 Hydrogen peroxide 200ppm 0.16 0.006 - - PARP3 0.4 - 0.2 - 0.1 PARP5 - 1.6 - 1.4 1. Protease 0.017 0.005 .0035 0.003 0.002 Perfume 0.18 0.09 0.09 0.2 0.2 Water and minors Up to 100% Example 22 The following liquid hard surface cleaning compositions were prepared according to the present invention : A B C D E PARP1 0.8 - 0.6 - 0.4 PARP5 - 1.2 - 1.0 0.5 Amylase 0.01 0.002 0.005 - - Protease 0.05 0.01 0.02 - - Hydrogen peroxide - - - 6.0 6.8 Acetyl triethyl citrate - - - 2.5 - DTPA - - - 0.2 - Butyl hydroxy toluene - - - 0.05 - EDTA 0.05 0.05 0.05 - - Citric / Citrate 2.9 2.9 2.9 1.0 - LAS 0.5 0.5 0.5 - - C12 AS 0.5 0.5 0.5 - - C10AS - - - - 1.7 C12(E)S 0.5 0.5 0.5 - - C12,13 E6.5 nonionic 7.0 7.0 7.0 - - Neodol 23-6.5 - - - 12.0 - Dobanol23-3 - - - - 1.5 Dobanol 91-10 - - - - 1.6 C25AE1.8S - - - 6.0 Na paraffin sulphonate - - - 6.0 Perfume 1.0 1.0 1.0 0.5 0.2 Propanediol - - - 1.5 Ethoxylated tetraethylene - - - 1.0 - pentaimine 2, Butyl octanol - - - - 0.5 Hexyl carbitol 1.0 1.0 1.0 - - SCS 1.3 1.3 1.3 - - pH adjusted to 7-12 7-12 7-12 4 - Miscellaneous and water Up to 100% Example 23 The following spray composition for cleaning of hard surfaces and removing household mildew was prepared according to the present invention : PARP3 0.3 Amylase 0.01 Protease 0.01 Na octyl sulfate 2.0 Na dodecyl sulfate 4.0 Na hydroxide 0.8 Silicate 0.04 Butyl carbitol 4.0 Perfume 0.35 Water/minors up to 100% Example 24 The following lavatory cleansing block compositions were prepared according to the present invention. A B C C16-18 fatty alcohol/50EO 70.0 - - LAS - - 80.0 Nonionic - 1.0 - Oleoamide surfactant - 25.0 - Partially esterified copolymer of vinylmethyl ether and maleic anhydride, viscosity 0.1-0.5 5.0 - - Polyethylene glycol MW 8000 - 38.0 - Water-soluble K-polyacrylate MW 4000-8000 - 12.0 - Water-soluble Na-copolymer of acrylamide (70%) and acryclic acid (30%) low MW - 19.0 - Na triphosphate 10.0 - - Carbonate - - - PARP5 1.0 - 1.6 PARP3 - 0.2 0.5 Dye 2.5 1.0 1.0 Perfume 3.0 - 7.0 KOH / HCL solution pH 6-11 Example 25 The following toilet bowl cleaning composition was prepared according to the present invention. A B C14-15 linear alcohol 7EO 2.0 10.0 Citric acid 10.0 5.0 PARP2 2.0 - PARP5 - 4.0 DTPMP - 1.0 Dye 2.0 1.0 Perfume 3.0 3.0 NaOH pH 6-11 Water and minors Up to 100% Example 26 The following fabric softening compositions are in accordance with the present invention Component A B C D E F DTDMAC - - - - 4.5 15.0 DEQA 2.6 2.9 18.0 19.0 - - Fatty acid 0.3 - 1.0 - - - HCI 0.02 0.02 0.02 0.02 0.02 0.02 PEG - - 0.6 0.6 - 0.6 Perfume 1.0 1.0 1.0 1.0 1.0 1.0 Silicone antifoam 0.01 0.01 0.01 0.01 0.01 0.01 PARP 3 0.4 0.1 0.08 0.2 1.0(s) 0.15 Electrolyte (ppm) - - 600 1200 - 1200 Dye (ppm) 10 10 50 50 10 50 Water and minors to balance to 100% Example 27 The following dryer added fabric conditioner compositions were prepared according to the present invention : A B C D DEQA(2) - - - 50.0 DTMAMS - - 26.0 - SDASA 70.0 70.0 42.0 35.0 Neodol 45-13 13.0 13.0 - - Ethanol 1.0 1.0 - - PARP 5 1.5 - 1.5 3.0 PARP 1 - 0.2 - - Perfume 0.75 0.75 1.0 1.5 Glycoperse S-20 - - - 10.0 Glycerol monostearate - - 26.0 - Digeranyl Succinate 0.38 0.38 - - Clay - - 3.0 - Dye 0.01 0.01 - - Minors to balance to 100% Example 28 The following are non-limiting examples of pre-soak fabric conditioning and/or fabric enhancement compositions according to the present invention which can be suitably used in the laundry rinse cycle. Ingredients A B C D E F Polymer 3.5 3.5 3.5 3.5 3.5 3.5 Dye fixative 2.3 2.3 2.4 2.4 2.5 2.5 Polyamine 15.0 15.0 17.5 17.5 20.0 20.0 Bayhibit AM 1.0 1.0 1.0 1.0 1.0 1.0 C 12 -C 14 dimethyl hydroxyethyl quaternary ammonium chloride - 5.0 5.0 - - - Fabric softener active - - 2.5 2.5 - - Genamin C100 0.33 - 0.33 0.33 0.33 - GenapolV4463 0.2 - 0.2 0.2 0.2 - PARP2 2.0 4.0 0.2 1.0 0.1 0.16 Water & minors balance balance balance balance balance balance Example 29 The following are non-limiting examples of odor-absorbing compositions suitable for spray-on applications: Examples A B C D E Ingredients Wt.% Wt.% Wt.% Wt.% Wt.% HPBCD 1.0 - 1.0 - 1.2 RAMEB - 1.0 - 0.8 - Tetronic 901 - - 0.1 - - Silwet L-7604 - - - 0.1 - Silwet L-7600 0.1 - - - 0.1 Bardac 2050 - - - 0.03 - Bardac 2250 - 0.2 - - 0.1 Diethylene glycol - 1.0 - - 0.2 Triethylene glycol - - 0.1 - - Ethanol - - - - 2.5 Perfume 1 0.1 - - - - Perfume 2 - 0.05 - 0.1 - Perfume 3 - - 0.1 - 0.1 Kathon 3 ppm 3 ppm 3 ppm 3 ppm - HCI to pH 4.5 to pH 4.5 to pH 3.5 to pH 3.5 to pH 3.5 PARP2 5.0 2.0 1.0 0.2 0.16 Distilled water Bal. Bal. Bal. Bal. Bal. The perfume 1, 2, and 3 have the following compositions: Perfume 1 2 3 Perfume Ingredients Wt.% Wt.% Wt.% Anisic aldehyde - - 2 Benzophenone 3 5 - Benzyl acetate 10 15 5 Benzyl salicylate 5 20 5 Cedrol 2 - - Citronellol 10 - 5 Coumarin - - 5 Cymal - - 3 Dihydromyrcenol 10 - 5 Flor acetate 5 - 5 Galaxolide 10 - - Lilial 10 15 20 Linalyl acetate 4 - 5 Linalool 6 15 5 Methyl dihydro jasmonate 3 10 5 Phenyl ethyl acetate 2 5 1 Phenyl ethyl alcohol 15 15 20 alpha-Terpineol 5 - 8 Vanillin - - 1 Total 100 100 100

Claims: A process for making particles of amine reaction product of a compound containing a primary and/or secondary amine functional group and being selected from i) polyamines; ii) amino adds and derivatives thereof; iii) substituted amines and amides; iv) glucamines; v) dendrimers; vi) polyvinylamines and derivatives and/or copolymers thereof; vii) alkylene polyamines; viii) polyaminoacids and copolymers thereof; ix) cross-linked polyaminoacids; x) amino-substituted polyvinylalcohols; xi) polyoxyethylene bis amines or bis aminoalkyls; x) aminoalkylpiperazines aand derivatives thereof; xi) bis (amino alkyl) diamines, linear or branched; and xii) mixtures thereof; with an active ketone or aldehyde containing component, and which comprises the steps of: a)-providing an amine reaction product having a viscosity greater than 1000 cps, and b)-mixing therewith an anhydrous acid carrier to thereby form a processed amine reaction product salt; and c)-thereafter forming said processed amine reaction product salt into particles. A process according to Claim 1, wherein compound has an Odor Intensity Index of less than that of a 1% solution of methyl anthranilate in dipropylene glycol. A process according to either one of Claim 1 or 2, wherein the primary and/or secondary amine is selected from polyethyleneimine polymers; polylysine, cross-linked polylysine, N,N'-bis-(3-aminopropyl)-1,3-propanediamine linear or branched, 1,4-bis-(3-aminopropyl) piperazine, and mixtures thereof. A process according to any one of Claims 1-3, wherein the active is selected from a flavour ketone or aldehyde ingredient, a pharmaceutical ketone or aldehyde active, a biocontrol ketone or aldehyde agent, a perfume ketone or aldehyde component, a refreshing cooling ketone or aldehyde agent and/or mixtures thereof. A process according to any one of Claims 1-4, wherein said active component is an insect and/or moth repellant, preferably selected from citronellal, citral, N, N diethyl meta toluamide, Rotundial, 8-acetoxycarvotanacenone, and mixtures thereof. A process according to any one of Claims 1-4, wherein said active component is an antimicrobial, preferably selected from Glutaraldehyde, Cinnamaldehyde, and mixtures thereof. A process according to any one of Claims 1-4, wherein the active is a perfume, preferably selected from alpha-damascone, delta damascone, Carvone, Gamma-Methyl-lonone; Damascenone, hedione, 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde, Florhydral, Lilial, heliotropine, trans-2-nonenal, citral, and mixtures thereof. A process according to any one of Claims 1-7, wherein the amount of amine reaction product ranges from 10 to 85%, preferably 20 to 80%, more preferably 45 to 75%, by weight of the particles. A process according to any one of Claims 1-8, wherein the acid carrier has a pKa relative to water of from minus 9 to 16, more preferably from minus 2 to 10, most preferably from 0 to 7. A process according to any one of Claims 1-9, wherein the acid carrier is selected from organic acids, inorganic acids, and mixtures thereof, preferably is an organic acid selected from monocarboxylic acids, monomeric polycarboxylic acids, homo or copolymeric polycarboxylic acids, inorganic acids, and mixtures thereof, more preferably is a polycarboxylic acid selected from citric acid, tartaric acid, malonic acid, oxalic acid, adipic acid, maleic acid, malic acid, phtalic acid, succinic acid, hydroxysuccinic acid, polyacrylic acid, and mixtures thereof. A process according to any one of Claims 1-10, wherein the amount of acid carrier material ranges from 5 to 90%, preferably from 15 to 80% and most preferably from 20 to 70%, by weight of the particles. A process according to any one of Claims 1-11, wherein said particles are treated to form a coated particle. A process according to any one of Claims 1-12, wherein the particles are further treated with a coating material selected from nonionic ethoxylated alcohol surfactants having a melting point between 30°C and 135°C, polyethylene glycols, carbonate, starch, cyclodextrin, sulfate salts, and mixtures thereof. A process according to Claim 13, wherein the amount of amine reaction product ranges from 1 to 85%, preferably 15 to 55% by weight of the coated particle. Particles of a processed amine reaction product salt as obtainable by the process of Claims 1-14. A method of incorporating particles of a processed amine reaction product salt according to Claim 15 into finished product, comprising combining said particles with one or more laundry or cleaning ingredients. A finished composition comprising one or more laundry or cleaning ingredients and particles of a processed amine reaction product salt according to Claim 15. A composition according to Claim 17, wherein said composition is selected from a laundry composition, hard surface cleaning composition, and personal cleaning composition. A composition according to Claim 18, wherein said composition is a laundry detergent composition further comprising a clay. A composition according to Claim 19, wherein the laundry detergent composition further comprises a flocculating agent. A method for delivering residual active to a surface which comprises the steps of contacting said surface with particles according to Claim 15, or composition according to any one of Claim 17-20, and thereafter contacting the treated surface with a material so that the active is released. Use of particles as defined in Claim 15 for the manufacture of a laundry and/or cleaning composition for delivering residual fragrance on a surface on which it is applied. Use of particles as defined in Claim 15 for the manufacture of a laundry and/or cleaning composition for delivering residual fragrance and fabric care onto the fabrics on which it is applied. A packaged composition comprising the particles of Claim 15 or composition of any one of Claims 17-20.

Inventors: BUSCH ALFRED, SMETS JOHAN, BUSCH, ALFRED, SMETS, JOHAN
Applicants: PROCTER & GAMBLE, THE PROCTER & GAMBLE COMPANY
Application year: 1999
Main classification: C11D3
IPC codes: C11D17, C09K3, A61Q19, C07C221, C11D3, A61K8, C07D295, C11D7, C11B9, C07C225, A01N35, A01N25, C11B15