COLOUR PHOTOGRAPHIC MATERIAL

Abstract: A colour photographic material is described containing a compound of formula (I) wherein, if n=1, R1 is, inter alia, a radical of formula (II), and, if n=2, R1 is unsubstituted or C1-C4alkyl- or hydroxy-substituted phenylene or naphthylene; or -R12-X-R13-, and other residues are as defined in claim 1. The compound of formula (I) is effective as scavenger of the oxidised form of the developer (Dox scavenger), especially when contained in an interlayer between light sensitive layers. Selected compounds of this class can also be used as additives, for example as dye stabilizer, in colour photographic materials, or as an antioxidant for organic materials.

Description: Colour Photographic Material The present invention relates to colour photographic material comprising a certain lactone (benzofuran-2-one) type compound, to the use of this compound as an additive to photographic material, especially as scavenger for the oxidised form of the developer (Dox- scavenger), to some new compounds of the benzofuran-2-one class, and their use as stabilisers for organic material against oxidative, thermal and/or light-induced degradation. It is well known that one of the problems associated with colour photography is the diffusion of the oxidised colour developer away from the light sensitive silver halide emulsion layer in which it is formed into another silver halide emulsion layer, which can result in the formation of unwanted dyes at undesired places. For instance, while being generated in the green sensitive layer and forming a magenta dye through a coupling reaction with the incorporated magenta coupler, the oxidised developer can also diffuse to the red sensitive layer thereby producing unwanted cyan dye or to the blue sensitive layer thereby producing unwanted yellow dye. This kind of colour formation in the wrong layers will damage the colour balance of the photographic image and thus result in poor colour reproduction. One way of circumventing this problem is to incorporate oxidised developer scavengers in interlayers between the light sensitive silver halide emulsion layers. These scavengers should have additional properties such as low tendency to migrate, good stability towards aerial oxidation and high solublity in photographic oils. Several classes of compounds that are useful as scavengers for oxidised developers are known in literature, e.g. specific derivatives of hydroquinone (EP-A-560198), or compounds of the classes sulphonamidophenol, gallic acid, resorcinol, catechol, aminophenol or aminonaphthol; or natural antioxidants such as vitamin E or vitamin C. Some compounds of the class benzofuran-2-one are described in US-461 1016 or US- 5814692 and publications cited therein. Photographic material containing a certain type of benzofuran-2-one is mentioned in US-3615521 (use as precursor of photographic developing agent) and in US-4366240 (hydroxy substituted compounds as electron donor precursors for reducible colour providing compounds). EP-A-871066 mentions the use of a symmetrically substituted 3-(2-hydroxyphenyl)-benzofuran-2-one in the interlayer of a colour photographic material. It has now been found that certain compounds of the 3-aryl-benzofuran-2-one class are especially useful as additives to photographic material. They are effective in a number of applications and find utility, for example, as scavengers for the oxidised developer (also termed hereafter Dox scavengers), as dye stabilisers, as antioxidants or as antifoggants. Liquid compounds of the below formula I can also be used as a photographic oil. These compounds are especially stable towards aerial oxidation, diffusion fast and also exhibit a good solubility in high boiling photographic oils. They are well suited for use in photographic elements containing pyrazolotriazole couplers as magenta dye providing compounds, since they are harmless to the light fastness of magenta images obtained from such pyrazolotriazole couplers when compared to hydroquinones. Primary subject of the invention is a process for preventing migration of the oxidised developer in a colour photographic material from one colour sensitive layer to another by incorporating a compound of the formula I into said material wherein, if n = 1 , Ri is a cyclic residue selected from naphthyl, phenanthryl, anthryl, 5,6,7,8-tetrahydro-2- naphthyl, 5,6,7,8-tetrahydro-1 -naphthyl, thienyl, benzo[b]thienyl, naphtho[2,3-b]thienyl, thianthrenyl, dibenzofuryl, chromenyl, xanthenyl, phenoxathiinyl, pyrrolyl, imidazolyl, pyrazolyl, pyrazinyl, pyrimidinyl, pyridazinyl, indolizinyl, isoindolyl, indolyl, indazolyl, purinyl, quinolizinyl, isoquinolyl, quinolyl, phthalazinyl, naphthyridinyl, quinoxalinyl, quinazolinyl, cinnolinyl, pteridinyl, carbazolyl, β-carbolinyl, phenanthridinyl, acridinyl, perimidinyl, phenanthrolinyl, phenazinyl, isothiazolyl, phenothiazinyl, isoxazolyl, furazanyl, biphenyl, terphenyl, fluorenyl or phenoxazinyl, each of which is unsubstituted or substituted by d- C 4 alkyl, C r C 4 alkoxy, C 1 -C 4 alkylthio, hydroxy, halogen, amino, Cι-C alkylamino, phenylamino or di(Cι-C 4 -alkyl)amino; or Pn is a radical of formula II and, if n = 2, Ri is unsubstituted or C C alkyl- or hydroxy-substituted phenylene or naphthylene; or R 2 , R 3 , R 4 and R 5 are each independently of one another hydrogen; chloro; hydroxy; Cι-C 25 - alkyl; C 7 -C 9 phenylalkyl; unsubstituted or C C 4 alkyl-substituted phenyl; unsubstituted or C r C 4 alkyl-substituted C 5 -C 8 cycloalkyl; d-C 18 alkoxy; C Cι 8 alkylthio; C C alkylamino; di(C 1 -C 4 -alkyl)amino; CrC^alkanoyloxy; CrC 25 alkanoylamino; C 3 -C 25 alkenoyloxy; C 3 -C 25 alkanoyloxy which is interrupted by oxygen, sulphur or N — R 14 ; C 6 -C 9 cycloalkyl- carbonyloxy; benzoyloxy or Cι-C 12 alkyl-substituted benzoyloxy; or R 2 and R 3 , or R 3 and R , or R and R 5 , together with the linking carbon atoms, form a benzene ring; or R 4 is -CmH 2m -COR 15 , -O-(C v H 2v )-COR' 15 , -O-(CH 2 ) q -OR 32 , -OCH 2 -CH(OH)-CH 2 -R' 15> -OCH 2 -CH(OH)-CH 2 -OR 32 , or -(CH 2 ) q OH; or, if R 3 , R 5 and R 6 are hydrogen, R 4 is additionally a radical of formula III wherein R^ is as defined above for n = 1 ; R 6 is hydrogen or, when R 4 is hydroxy, R 6 can also be CrC 25 alkyl or C 3 -C 25 alkenyl; R 7 , Rs, R 9 , R1 0 and Rn are each independently of one another hydrogen; halogen; hydroxy; Cι-C 25 alkyl; C 2 -C 25 alkyl which is interrupted by oxygen, sulphur or N— R 14 ; C C 25 alkoxy; C 2 -C 25 alkoxy which is interrupted by oxygen, sulphur or N — R 14 ; Cι-C 25 alkylthio; C 3 -C 25 -alkenyl; C 3 -C 25 alkenyloxy; C 3 -C 25 alkynyl; C 3 -C 25 alkynyloxy; C 7 - C 9 phenylalkyl; C 7 -C 9 phenylalkoxy; unsubstituted or C C 4 alkyl-substituted phenyl; unsubstituted or Cι-C alkyl- substituted phenoxy; unsubstituted or d-C alkyl-substituted C 5 - C 8 cycloalkyl; unsubstituted or C C alkyl-substituted C 5 -C 8 cycloalkoxy; C C alkylamino; di(CrC alkyl)amino; CrC 25 alkanoyl; C 3 -C 25 alkanoyl which is interrupted by oxygen, sulphur or N — R 14 ; CrC 25 alkanoyloxy; C 3 -C 25 alkanoyloxy which is interrupted by oxygen, sulphur or N — R 14 ; C C 25 alkanoylamino; C 3 -C 25 alkenoyl; C 3 -C 25 alkenoyl which is interrupted by oxygen, sulphur or N — R 14 ; C 3 -C 25 alkenoyloxy; C 3 -C 25 alkenoyloxy which is interrupted by oxygen, sulphur or N — R 14 ; C 6 -C 9 cycloalkylcarbonyl; C 6 - Cgcycloalkylcarbonyloxy; benzoyl or CrC 12 alkyl-substituted benzoyl; benzoyloxy or d- R , 1 1 R 8 O M R | 2n 0 R | 2 ,<1 C 12 alkyl-substituted benzoyloxy; — O— C — C— R 15 or — O — C — C— O— R 23 or, in R 19 H R^ formula II, R 7 and R 8 , or R 8 and Rn , together with the linking carbon atoms, form a benzene ring; R 12 and R 13 are each independently of the other unsubstituted or C dalkyl-substituted phenylene or naphthylene; R 1 is hydrogen or CrC 8 alkyl; R 15 and R' 15 independently are hydroxy; - 1 r+ — O -γ M d-C^alkoxy; C 3 -C 20 alkoxy interrupted by O and/or substituted by a radical selected from OH, phenoxy, C 7 C 15 alkylphenoxy, C 7 -C 15 alkoxyphenoxy; or are C 5 -C 12 cycloalkoxy; C 7 -Cι 7 phenylalkoxy; R. / '24 phenoxy; — N or a group of the formula Ilia or lllb R 2.5 R 16 and R 17 are each independently of the other hydrogen, CF 3 , C C 12 alkyl or phenyl, or R 16 and R 17 , together with the linking carbon atom, are a C 5 -C 8 cycloalkylidene ring which is unsubstituted or substituted by 1 to 3 C C 4 alkyl; R 18 and Rι 9 are each independently of the other hydrogen, C C 4 alkyl or phenyl; R 20 is hydrogen or C C alkyl; R 21 is hydrogen; unsubstituted or C C 4 alkyl-substituted phenyl; CrC 25 alkyl; C 2 -C 25 alkyl which is interrupted by oxygen, sulphur or N — R 14 ; C 7 -C 9 phenylalkyl which is unsubsti¬ tuted or substituted at the phenyl moiety by 1 to 3 C C alkyl; C 7 -C 25 phenylalkyl which is interrupted by oxygen, sulphur or N — R 14 and which is unsubstituted or substituted at the phenyl moiety by 1 to 3 d-C alkyl; or R 20 and R 21 , together with the linking carbon atoms, form a C 5 -Cι 2 cycloalkylene ring which is unsubstituted or substituted by 1 to 3 CrC alkyl; R 22 is hydrogen or C C 4 alkyl; R 23 is hydrogen; CrC 25 alkanoyl; C 3 -C 25 alkenoyl; C 3 -C 25 alkanoyl which is interrupted by oxygen, sulphur or N — R 14 ; C 2 -C 25 alkanoyl which is substituted by a di(C 1 -C 6 alkyl)phos- phonate group; C 6 -C 9 cycloalkylcarbonyl; thenoyl; furoyl; benzoyl or C C 12 alkyl-substituted benzoyl; -C R 29 R 30 R 2 and R 25 are each independently of the other hydrogen or CrC 18 alkyl; R 26 is hydrogen or d-C 8 alkyl; R 2 is a direct bond; CrCι 8 alkylene; C 2 -Cι 8 alkylene which is interrupted by oxygen, sulphur \ or N — R 14 ; C 2 -Cι 8 alkenylene; C 2 -C 20 alkylidene; C 7 -C 20 phenylalkylidene; C 5 -C 8 cycloalky- lene; C 7 -C 8 bicycloalkylene; unsubstituted or C C alkyl-substituted phenylene; '24 R 28 is hydroxy, - 1 r+ — O -jrM , Cι-Cι 8 alkoxy or — N R '2.5 R 29 is oxygen or -NH-; R 30 is C Cι 8 alkyl or phenyl; R 31 is hydrogen or d-C 18 alkyl; R 32 is CrCι 8 alkanoyl; CrCβalkanoyl substituted by phenyl or C 7 -Cι 5 alkylphenyl; C 3 - C 18 alkenoyl; cyclohexylcarbonyl; or naphthylcarbonyl; L is a linking group of valency (k+1) and is as a divalent group -O-; Q-C 2 -Cι 2 alkylene-Q; -O-CH 2 -CH(OH)-CH 2 -O-; -Q-C 2 -Cι 2 alkylene-Q-CO-C v H 2v -O-; -O-C 2 -C 12 alkylene-O-CH 2 -CH(OH)-CH 2 -O-; Q-interrupted Q-C -Cι 2 alkylene-Q; Q-phenylene-Q or Q-phenylene-D-phenylene-Q with D being C C 4 alkylene, O, S, SO or SO 2 ; L as a trivalent group is Q-capped C 3 -C 12 alkanetriyl, a trivalent residue of a hexose or a hexitol, or a group (-O-CH 2 ) 3 C-CH 2 OH; -Q-C a H 2a -N(C b H 2b -Q-)-C c H 2c -Q-; -Q-C 3 -Cι 2 alkanetriyl(-Q-CO-C v H 2v -O-) 2 ; -O-C 3 -Cι 2 alkanetriyl(-O-CH 2 -CH(OH)-CH 2 -O-) 2 ; and L as a tetravalent group is a tetravalent residue of a hexose or a hexitol; -Q-C 4 -C 12 alkanetetryl(-Q-CO-C v H 2v -O-) 3 ; -O-C 4 -C 12 alkanetetryl(-O-CH 2 -CH(OH)-CH2-O-) 3 ; Q-capped C 4 -C 12 alkanetetryl; a group o M is an r-valent metal cation; Q is oxygen or -NH-; X is a direct bond, oxygen, sulphur or -NR 31 - ; Z is a linking group of valency (k+1) and is as a divalent group C 2 -C 12 alkylene; Q-interrupted C -Cι 2 alkylene; phenylene or phenylene-D-phenylene with D being d-C 4 alkylene, O, S, SO or SO 2 ; Z as a trivalent group is C 3 -C 12 alkanetriyl, a trivalent residue of a hexose or a hexitol, a group (-CH 2 ) 3 C-CH 2 OH, or a group -C a H 2a -N(C b H 2b -)-C c H 2c -; and Z as a tetravalent group is a tetravalent, carbon-ended residue of a hexose or a hexitol, C - Cι 2 alkanetetryl, a group a, b, c and k independently are 1 , 2 or 3; m is 0 or a number from the range 1-12, preferably 1-6; n is 1 or 2; q is 1 , 2, 3, 4, 5 or 6; r is 1 , 2 or 3; and s is 0, 1 or 2; v is 1 , 2, 3, 4, 5, 6, 7 or 8, preferably 1 or 2; provided that, when R 7 is hydroxy, alkanoyloxy or alkanoyloxy interrupted by O, S or N(R 1 ) and R 9 is hydrogen, R 10 is not identical with R ; and when R 9 is hydroxy, alkanoyloxy or alkanoyloxy interrupted by O, S or N(R 14 ) and R 7 is hydrogen, R 8 is not identical with R . Of certain technical interest is a process, where in the compound of formula I R 2 , R 3 , R 4 and R 5 are each independently of one another hydrogen, chloro, hydroxy, C C 25 - alkyl, C 7 -Cgphenylalkyl, unsubstituted or d-C 4 alkyl-substituted phenyl; unsubstituted or d-C 4 alkyl-substituted C 5 -C 8 cycloalkyl; C Cι 8 alkoxy, C C 18 alkylthio, d-dalkylamino, di(C 1 -C -alkyl)amino, Cι-C 25 alkanoyloxy, CrC 25 alkanoylamino, C 3 -C 25 alkenoyloxy; C 3 -C 25 alkanoyloxy which is interrupted by oxygen, sulfur or N — R 14 ; C 6 -Cgcycloalkyl- carbonyloxy, benzoyloxy or CrC 12 alkyl-substituted benzoyloxy; or R 2 and R 3 , or R 3 and R , or R 4 and R 5 , together with the linking carbon atoms, form a benzene ring; or R is -CmH 2m -COR 15 or -(CH 2 ) q OH or, if R 3 , R 5 and R 6 are hydrogen, R 4 is additionally a radical of formula III; and R. r . __.. / / 24 R 1 5 is hydroxy, — O T M • ' , CrC 2 oalkoxy, — N , or a group of the formula Ilia. R 25 is preferably a radical of formula II. These preferred compounds of formula I advantageously carry at least one hydrocarbon or substituted hydrocarbon radical R 2 , R 3 , R 4 , Rs, 7 , Rs, Rg, R 10 and/or Ru, where the total number of carbon atoms in all radicals together is at least 3. More preferred compounds comprise one or more substituents among R 2 -R 5 and R 7 -Rιι, wherein the total number of carbon atoms in all substituents together is 4-35, especially 7-30. In preferred compounds of formula I, R 7 and R 9 are each independently of one another hydrogen; halogen; Cι-C 25 alkyl; C 2 -C 25 alkyl which is interrupted by oxygen, sulphur or N — R 14 ; C 2 -C 25 alkoxy which is interrupted by oxygen, sulphur or N — R 14 ; d-C 25 alkylthio; C 3 -C 25 -alkenyl; C 3 -C 25 alkenyloxy; C 3 -C 25 alkynyl; C 3 -C 25 alkynyloxy; C 7 - Cgphenylalkyl; C 7 -C 9 phenylalkoxy; unsubstituted or C C 4 alkyl-substituted phenyl; unsubstituted or d-C alkyl- substituted phenoxy; unsubstituted or C C 4 alkyl-substituted C 5 - C 8 cycloalkyl; unsubstituted or C C alkyl-substituted C 5 -C 8 cycloalkoxy; Cι-C 4 alkyiamino; di(d-C 4 alkyl)amino; d-dsalkanoyl; C 3 -C 25 alkanoyl which is interrupted by oxygen, sulphur or N — R 14 ; d-C 25 alkanoylamino; C 3 -C 25 alkenoyl; C 3 -C 25 alkenoyl which is interrupted by oxygen, sulphur or N — R 14 ; C 6 -C 9 cycloalkylcarbonyl; benzoyl or d-Cι 2 alkyl-substituted R 1R O R. n l '° II 20 ','21 benzoyl; — O— C — C— R 15 or — 0— C — C— O— R 23 ; R 19 H R 22 more preferably, R 7 and R 9 are hydrogen; halogen; d-C 25 alkyl; C 2 -C 25 alkyl which is interrupted by oxygen, sulphur or N — R 14 ; C 3 -C 25 -alkenyl; C 3 -C 25 alkynyl; C 7 - Cgphenylalkyl; unsubstituted or Cι-C 4 alkyl-substituted phenyl; unsubstituted or C C alkyl- substituted C 5 -C 8 cycloalkyl; most preferably, R 7 and R 9 are hydrogen; halogen; d-C 25 alkyl; C 3 -C 25 -alkenyl; C 3 -C 25 alkynyl; C 7 -C 9 phenylalkyl; unsubstituted or d-C alkyl-substituted phenyl; unsubstituted or d-dalkyl- substituted C 5 -C 8 cycloalkyl; especially hydrogen, chloro or d-C 8 alkyl. R 8 , R 10 and Ru are often as defined above for R 7 and R 9 in the preferred compounds of formula I, or one of these residues, especially Rn, is OH, d-d^alkoxy, phenyl, di(d- ^20 R 21 C alkyl)amino, Cι-C 25 alkanoyloxy, or — O — C — C— O— R 23 . H R Further objects of the invention are the use of a compound of the formula I in colour photographic material, especially as Dox-scavenger, and a photographic material containing a compound of the formula I, especially as herein defined below, e.g. of formula IV. Ri may be, for example, the cyclic residue defined above which is unsubstituted or substituted by d-dalkyl, Cι-C alkoxy, d-C 4 alkylthio, hydroxy, halogen, amino, d- dalkylamino, phenylamino or di(C r C alkyl)amino. Examples and preferred meanings are as given in US-5814692, column 6, line 9, until column 7, line 20; these passages are hereby incorporated by reference. Halogen is typically chloro, bromo or iodo. Chloro is preferred. Alkanoyl of up to 25 carbon atoms is a branched or unbranched radical, typically formyl, acetyl, propionyl, butanoyl, pentanoyl, hexanoyl, heptanoyl, octanoyl, nonanoyl, decanoyl, unde- canoyl, dodecanoyl, tridecanoyl, tetradecanoyl, pentadecanoyl, hexadecanoyl, heptadecano- yl, octadecanoyl, eicosanoyl or docosanoyl. Alkanoyl of 2 to 18, in particular of 2 to 12, e.g. of 2 to 6, carbon atoms is preferred. Acetyl is particularly preferred. Examples for alkanoyl or alkanoyloxy (oxygen-capped alkanoyl) as well as alkanoyl interrupted by O, S or NR 1 , and preferred meanings are as given in US-5814692, column 7, lines 31-48, and column 8, lines 14-38; these passages are hereby incorporated by reference. Alkenoyl of 3 to 25 carbon atoms is a branched or unbranched radical, typically propenoyl, 2- butenoyl, 3-butenoyl, isobutenoyl. Alkenoyloxy is oxygen-capped alkenoyl. Examples and preferred meanings for alkenoyl(oxy) as well as alkenoyl interrupted by O, S or NRι 4 are as given in US-5814692, column 7, line 48, until column 8, line 13; these passages are hereby incorporated by reference. Examples and preferred meanings for C 6 -C 9 cycloalkylcarbonyl or C 6 - C cycloalkylcarbonyloxy, d-C 12 alkyl-substituted benzoyl or benzoyloxy, d-C 25 alkyl, C 3 - C 25 alkenyl, C 3 -C 2 alkenyloxy, C 3 -C 25 alkynyl such as propargyl ( — CH 2 -C≡≡_CH ),alkynyloxy (oxygen capped alkynyl), C 2 -C 25 alkyl interrupted by oxygen, sulphur or NRι ; C 7 -C 9 phenylalkyl which is unsubstituted or substituited or interrupted; phenylalkoxy such as benzyloxy; alkyl substituted phenyl or phenoxy; C 5 -C 8 cycloalkyl or cycloalkoxy which is unsubstituted or substituted by alkyl; d-C 25 alkoxy or O, S or NR 14 - interrupted C 2 -C 25 alkoxy; alkylthio; alkylamino or di(Cι-C alkyl)amino; alkanoylamino; or divalent residues such as d-C 4 alkyl substituted C 5 -d 2 cycloalkylene, interrupted C 2 - C 18 alkylene, C 2 -C 9 alkenylene, C 2 -C 20 alkylidene, phenylalkylidene, C 5 -C 8 cycloalkylene, C 7 - C 8 bicycloalkylene, unsubstituted or alkyl substituted phenylene or naphthylene, or alkyl substituted cycloalkylidene are as given in US-5814692, column 8, line 39, until column 12, line 22; these passages are hereby incorporated by reference. One of the preferred meanings of R 2 and R is, for example, C C 18 alkyl. A particularly preferred meaning of R 4 is d-C 4 alkyl. One of R 2 and R is preferably a branched radical; especially preferred are both R 2 and R 4 branched radicals. A mono-, di- or tri-valent metal cation is preferably an alkali metal cation, alkaline earth metal cation or aluminium cation, typically Na + , K + , Mg ++ , Ca ++ or Al +++ . Preferred are compositions containing a compound of formula I, wherein R 2 , R 3 and R 5 , independently, are H, Cl, hydroxy, C r C 25 alkyl, C 7 -C 9 phenylalkyl, unsubstituted or C r C alkyl-substituted phenyl; C C 18 alkoxy, d-C 25 alkanoyloxy, C 3 -C 25 alkenoyloxy; and where R 4 is Cl, hydroxy, Cι-C 25 alkyl, C -Cgphenylalkyl, unsubstituted or C r C alkyl-substituted phenyl; d-Cι 8 alkoxy, CrC 25 alkanoyloxy, C 3 -C 25 alkenoyloxy or is a group -C m H 2m -CORi 5 , -O-(C v H 2v )-COR'ι 5 , -O-(CH 2 ) q -OR 32 , -OCH 2 -CH(OH)-CH 2 -R' 15 , -OCH 2 -CH(OH)-CH 2 -OR 32 , or where R 3 , R 5 and R 6 are H, R may be a residue of formula III, or where R 8 or R 10 are other than H, R may also be hydrogen; R 6 is H, R 7 and R 9 are each independently of one another hydrogen; halogen; d-C 25 alkyl; C 2 -C 25 alkyl which is interrupted by oxygen, sulphur or — 14 ; C 3 -C 25 -alkenyl; C 3 -C 25 alkynyl; C 7 - C 9 phenylalkyl; unsubstituted or d-C alkyl-substituted phenyl; unsubstituted or d-dalkyl- substituted C 5 -C 8 cycloalkyl; R 8 , Rio and Rn independently are H, halogen, hydroxy, d-C 25 alkyl, O interrupted C 2 - C 25 alkyl; d-C 25 alkoxy, O interrupted C 2 -C 25 alkoxy, C 3 -C 25 alkenyl, C 3 -C 25 alkenyloxy, C 7 - C 9 phenylalkyl, C 7 -Cgphenylalkoxy, unsubstituted or C C 4 alkyl-substituted phenyl; unsubstituted or d-dalkyl substituted phenoxy; unsubstituted or C C alkyl substituted C 5 - C 8 cycloalkyl; unsubstituted or d-C 4 alkyl substituted C 5 -C 8 cycloalkoxy; C C 4 alkylamino, di- (d-C -alkyl)amino, d-C 25 alkanoyl; Cι-C 25 alkanoyloxy; C 6 -C 9 cycloalkylcarbonyl, C 6 - Cgcycloalkylcarbonyloxy, benzoyl or Cι-Cι_alkyl-substituted benzoyl; benzoyloxy or d- C 12 alkyl substituted benzoyloxy; O— R 23 , or where in formula II R 7 and R 8 or R 8 and Ru together with the carbon atoms, they are bonded to, form a phenyl ring; R 15 and R' 15 independently are d-C 18 alkoxy; C 3 -C 20 alkoxy interrupted by O and/or substituted by a radical selected from OH, phenoxy, C 7 -C 15 alkylphenoxy, C 7 - Cι 5 alkoxyphenoxy; or are C 5 -C 12 cycloalkoxy; C 7 -Cι 7 phenylalkoxy; phenoxy; or -NR 23 R 24 ; or a group of formula Ilia or lllb; Rie and R 17 independently are H, CF 3 , C r Cι 2 alkyl or phenyl; or R 16 and R 17 together with the bonding carbon atom form an unsubstituted or 1 -3 d-C 4 alkyl-substituted C 5 - C 8 cycloalkylidene ring; R 18 andR 19 independently are H, d-C alkyl or phenyl; R 20 is H or d-dalkyl; R 21 is H, unsubstituted or d-C 4 alkyl substituted phenyl; d-C 25 alkyl, unsubstituted or on the phenyl ring 1-3 d-C alkyl-substituted C 7 -C 9 phenylalkyl; R 22 is H or d-dalkyl; R 23 is H, d-C 25 alkanoyl, C 3 -C 25 alkenoyl; di(d-C 6 alkyl)phosphonate-substituted C 2 - C 25 alkanoyl; C 6 -C 9 cycloalkylcarbonyl, thenoyl, furoyl, benzoyl or d-C 12 alkyl-substituted benzoyl; CH- H 3 C^ / 0 0 o O II C or c- pu c P r-i— OH Ha -C R 27 C R 28 C R 2g R 30 I CH 3 R 26 R 2 and R 25 independently are H or d-C 18 alkyl; R 26 is H or C r C 8 alkyl; R 27 is a direct bond, C C 18 alkylen, C 2 -C 18 alkenylen, C 7 - C 20 phenylalkyliden, C 5 -C 8 cycloalkylen, unsubstituted or d-dalkyl-substituted phenylene, / R 24 R 2 8 d-Cι 8 alkoxy or — N \ R 25 R 29 isOor-NH-; R 30 d-Cι 8 alkyl or phenyl; M a metal cation of the valency r; X a direct bond, O, S or -NR 31 - ; n 1 or 2; m is a number from the range 1-8; q 1,2, 3, 4, 5 or 6; r 1, 2 or 3; and sisO, 1 or 2. More preferred for use according to present invention is a compound of the formula IV wherein R 2 is H or Cι-C 20 alkyl; R 3 isHorC Cι 8 alkyl; R 4 is d-C 8 alkyl, H, C C 6 alkoxy or a group -C m H 2fn -COR 15 ; -O-(C.H 2 .)-COR 15 , -O-(CH 2 ) q -OR 32 ; -OCH 2 -CH(OH)-CH 2 -R 15 ; -OCH 2 -CH(OH)-CH 2 -OR 32 ; or a group of the formula III ; R 5 is H ord-Cι 8 alkyl; R 7 and R 9 are each independently of one another hydrogen; halogen; d-dsalkyl; C 3 -C 25 - alkenyl; C 3 -C 25 alkynyl; C 7 -C 9 phenylalkyl; unsubstituted or C C 4 alkyl-substituted phenyl; unsubstituted or d-C 4 alkyl-substituted C 5 -C 8 cycloalkyl; R 8 , R 10 and Ru independently are H, OH, chloro, C Cι 8 alkyl, C Cι 8 alkoxy, di(C C alkyl)amino, C 7 -Cgphenylalkyl; unsubstituted or d-dalkyl-substituted phenyl; unsubstituted or d-C alkyl-substituted C 5 -C 8 cycloalkyl; C 2 -Cι 8 alkanoyloxy, C 3 -C 18 - alkoxycarbonylalkoxy or ; especially wherein at least 2 of the residues R 7 , R 8 , R 9 , R 10 , Ru are H; R 15 is d-Cι 8 alkoxy; C 3 -C 20 alkoxy interrupted by O; or are cyclohexyloxy; C 7 -Cι 7 phenylalkoxy; phenoxy; or a group of formula Ilia or lllb; R 16 and R 17 independently are H, d-C^alkyl or phenyl; or R 16 and R 17 together with the bonding carbon atom form a C 5 -C 8 cycloalkylidene ring; R 20 , R 21 and R 22 independently are H or d-C alkyl; R 23 is H, C 2 -Cι 8 alkanoyl or a group R 26 is C r C alkyl; R 32 is C r Cι 8 alkanoyl; d-C 8 alkanoyl substituted by phenyl or C 7 -d 5 alkylphenyl; C 3 - Cι 8 alkenoyl; cyclohexylcarbonyl; or naphthylcarbonyl; L is a divalent group -O-; Q-C 2 -C 12 alkylene-Q; -O-CH 2 -CH(OH)-CH 2 -O-; -Q-C 2 -C 12 alkylene-Q-CO-C v H 2v -O-; -O-C2-C 12 alkylene-O-CH 2 -CH(OH)-CH 2 -O-; Q is oxygen; Z is C 2 -Cι 2 alkylene; k is 1 ; m is 1 , 2, 3, 4, 5 or 6; v is 1 or 2; and s is 0, 1 or 2. Groups of formulae III, Ilia and lllb are as defined above for formula I. R is preferably not H, most preferably not H and not OH. Especially preferred is a compound wherein R 4 is d-dalkyl, especially tertiary C 4 -C 6 alkyl, or a group -C m H 2m -COR 15 , -O-(C v H 2v )- CORi 5 , -O-(CH 2 ) q -OR 3 2, -OCH 2 -CH(OH)-CH 2 -R 15 , -OCH 2 -CH(OH)-CH 2 -OR 32 , or a group of the formula III, especially -C m H 2m -COR 15 or a group of the formula III. Most preferred for use according to present invention is a compound of the formula IV wherein R 2 is d-doalkyl; R 3 is H or Cι-Cι 8 alkyl; R 4 is d-dalkyl, d-C 6 alkoxy or a group -C m H 2m -CORι 5 or a group of the formula III; R 5 is H or Cι-C 18 alkyl; R 7 and R 9 independently are H, chloro, Cι-C 18 alkyl; R 8 , R 10 and Ru independently are H, OH, chloro, C C 18 alkyl, C Cι 8 alkoxy, di(d- > R 20 R 21 C 4 alkyl)amino, phenyl, C 2 -C 18 alkanoyloxy or — O — C — C— O— R 23 H R '2, 2 Ri 5 is d-Cι 8 alkoxy or a group of the formula Ilia; R 20 , R 2 ι and R 22 are H; R 23 is H, C 2 -C 18 alkanoyl or a group R 26 is d-C 4 alkyl; Q is oxygen; Z is C 2 -Ci 2 alkylene; k is 1 ; m is 1 , 2, 3, 4, 5 or 6 and s is 0, 1 or 2. Of special interest are those compounds of formula IV wherein R 7 is H and Rg is H or methyl. More interesting is a process where in the compound of formula I, if n = 1 , R^ is phenyl which is unsubstituted or substituted in para-position by d-d 8 alkylthio or di(d-C 4 -alkyl)amino; mono- to penta-substituted alkylphenyl containing together a total of at most 18 carbon atoms in the 1 to 5 alkyl substituents; naphthyl, biphenyl, terphenyl, phenanthryl, anthryl, fluorenyl, carbazolyl, thienyl, pyrrolyl, phenothiazinyl or 5,6,7,8-tetrahydronaphthyl which are unsubstituted or substituted by C C -alkyl, d-C 4 alkoxy, d-dalkylthio, hydroxy or amino. Also preferred compositions contain compounds of the formula I wherein the bonding atom in R 2 is a secondary or tertiary carbon atom, especially wherein R 2 is secondary C 6 -C 22 alkyl or tertiary C 4 -C 22 alkyl or phenyl or substituted phenyl or alkyl or alkoxy interrupted by COO; R is secondary C 6 -C 22 alkyl or tertiary C 4 -C 22 alkyl or a group of formula III or alkyl or alkoxy interrupted by COO; and Ru is H or methyl or phenyl or alkyl or alkoxy interrupted by COO. Of special technical interest are compounds whose residues R 2 , R 4 or Ru contain an ester group. Especially preferred are compounds of the formula IV wherein R 2 is H or d-C 20 alkyl; R 3 is H or Cι-C 18 alkyl; R 4 is d-dalkyl, -(CH 2 ) p -COR 15 or -C(CH 3 ) 2 -(CH 2 )p-COR 15 ; R 5 is H or C Cι 8 alkyl; R 7 , R 8 , R 9 , R 10 and Rn independently are H, C Cι 8 alkyl, C C 18 alkoxy or especially wherein at least 2 of the residues R 7 , R 8 , R 9 , R 10 , Ru are H; Ri 5 is Cι-C 18 alkoxy; R20, R21 and R 22 are H; and p is 2 or 3. Compounds of the formula I or IV can be obtained according to methods known in the art, e.g. as described in US-5814692 or publications cited therein, or, like compounds of formula V and VI, in analogy to those methods. Some compounds of the formula I are commercially available. Lactones of present formula I are preferably used to trap the oxidised form of a developer having the following general structure: A where A = Cι-C 6 -alkyl; n = 1 - 6; X = Hydrogen, hydroxy, C C 8 -alkoxy , COR 1 5, NHSO 2 R 30 , where R 15 and R 30 are as defined for formulae I or IV; Y = d-dalkyl, d-C 8 alkoxy, halogen; m = 0 - 4. In the above structure the preferred substituents are A = -CH 2 CH 3 and n=2, X = hydrogen or -NHS0 2 CH 3 or -OH or -OCH 3 , Y = hydrogen or -CH 3 and m = 1. Examples of these are 4-amino-N,N-diethylaniline, 3-methyl-4-amino-N,N-diethylaniline, 4-amino-N-ethyl-N-α-hydroxyethylaniline, 3-methyl-4-amino-N-ethyl-N-α-hydroxyethylaniline, 3-methyl-4-amino-N-ethyl-N-α-hydroxyethylaniline, 3-methyl-4-amino-N-ethyl-N-α-methanesulphonamidoethylaniline, 3-methyl-4-amino-N-ethyl-N-α-methoxyethyl-aniline, 3-α-methanesulphonamidoethyl-4-amino-N,N-diethylaniline, 3-methoxy-4-amino-N-ethyl-N-α-hydroxyethylaniline, 3-methoxy-4-amino-N-ethyl-N- -methoxyethylaniline, 3-acetamido-4-amino-N,N-diethylaniline, 4-amino-N,N-dimethylaniline, N-ethyl-N-α-[α'-(α"-methoxyethoxy)ethoxy]ethyl-3-methyl-4-aminoaniline, N-ethyl-N-α-(α'-methoxyethoxy)ethyl-3-methyl-4-aminoaniline, and also the salts of such compounds, for example sulphates, hydrochlorides or toluenesulphonates. The photographic materials according to this invention comprise a support bearing at least one layer of a light-sensitive silver halide emulsion. Examples of colour photographic materials according to this invention are colour negative films, colour reversal films, colour positive films, colour photographic paper, colour reversal photographic paper, colour-sensitive materials for the dye diffusion transfer process or the silver dye bleach process. Of especial interest is a colour photographic recording material comprising, on a base, at least one blue-sensitive silver halide emulsion layer containing at least one yellow dye providing compound, at least one green-sensitive silver halide emulsion layer containing at least one magenta dye providing compound, at least one red-sensitive silver halide emulsion layer containing at least one cyan dye providing compound, and customary (non light sensitive) top layer(s) and interlayers separating the light-sensitive layers. The layers of the colour photographic material can be arranged in various orders as is well known in the art. The compound of the formula I or IV can be contained in any of the layers of the photographic material, i.e. in any of the light sensitive silver halide emulsion layers or in a non light sensitive layer. For use as a Dox scavenger, the compound of the formula I is preferably contained in one or more non light sensitive layers. In this case, the light sensitive layers may contain a lower concentration of the compound of the formula I or none. Compounds of formula I are preferably incorporated in an interlayer adjacent to the green- sensitive layer containing a magenta coupler. Preferred colour photographic materials within this invention are those wherein the magenta coupler is of the pyrazolo-azole type, e.g. as disclosed in US-5538840, column 49, line 51 , until column 69, line 27, and publications cited therein; this section of US-5538840 is hereby incorporated by reference. Also preferred is a colour photographic material, wherein the silver halide emulsion contains at least 95 mol-% AgCI. In general, the compounds of the formula I or IV are contained in the photographic material in an amount from 10 to 1000 mg/m 2 , especially from 30 to 500 mg/m 2 . The lactones of formula I or IV can be milled with polymers (e.g. PVS, polyester, polyvinyl alcohol etc.) and placed in a layer thus preventing their migration to adjacent layers. Also, the benzofuranones containing a suitable functional group (e.g. ester, hydroxy) can be reacted with a polymer, e.g. a polyvinyl alcohol or polyester, in order to attach them chemically. This form will reduce their migrating tendency. Typical bases for the photographic material include polymeric films and paper (including polymer-coated paper). Details regarding supports and other layers of colour photographic recording materials can be found in Research Disclosure, Item 36544, September 1994. Essential constituents of the photographic emulsion layers are binders, silver halide particles and colour couplers. Details regarding the constituents of the light sensitive layers and other (non light sensitive) layers such as top layers and interlayers separating the silver halide emulsion layers can be found in Research Disclosure, Item 38957, September 1996. The invention therefore also pertains to a colour photographic material comprising a compound of the formula I or IV, and to the use of a compound of the formula I or IV as an additive in a colour photographic material. Preferred compounds of the formula I or IV in the colour photographic material of the invention or the corresponding use are as described for the process of the invention. Compounds of present invention are of special advantage when incorporated into photographic materials containing magenta couplers of the pyrazolotriazole class. Examples for especially suitable yellow, magenta and cyan couplers to be used in combination with compounds of the present invention are as given in US-5538840, column 33, line 3, until column 73, line 34, and publications cited therein. These passages of US- 5538840 are hereby incorporated by reference. The compounds of the formula (I) which can be used in the context of this invention can be incorporated into the colour photographic recording material, on their own or together with the colour coupler and with or without further additives, by pre-dissolving them in high-boiling organic solvents. Preference is given to the use of solvents which boil at higher than 160°C. Typical examples of these solvents are the esters of phthalic acid, phosphoric acid, citric acid, benzoic acid or of fatty acids, and also alkylamides and phenols. Further details on the structure of the colour photographic material of the invention, and the components or further additives which can be employed in the novel material, can be found, inter alia, in US-A-5,538,840, column 27, line 25, to column 33, line 2; and further in US-A- 5,538,840 from column 74, line 18, to column 106, line 16; and in US-A-5,780,625, column 12, line 6, until column 57, line 6, and the publications cited in these 2 references; these passages of US-A-5, 538,840 and US-A-5,780,625 are hereby incorporated by reference. Other useful information, how compounds of the formula I can be used in photographic material, can be taken from EP-A-871066, page 10, line 10, until page 11 , line 32, especially the references cited therein. The photographic layers in the material of this invention may also include UV absorbers, which screen out the UV light and therefore protect the dyes, the couplers or other components against photodegradation. Benzofuran-2-ones compounds according to this invention may be contained in those layers where UV absorbers are present. UV absorbers preferably to be used in the novel material or within the process of present invention include benzotriazoles, 2-hydroxybenzophenones, oxanilides, cyanoacrylates, salicylic esters, acrylonitrile derivatives, thiazolines and 2-hydroxyphenyltriazines. GB-A-2319523 describes from page 49, line 21 , until page 73, line 2, further details of the colour photographic material, especially couplers (page 52, line 1 , until page 56, line 22), UV absorbers (page 56, line 25, until page 68, line 1 ) and dark stabilisers (page 68, line 2, until page 73, line 2). Preferred UV absorbers of the 2-hydroxyphenyltriazine class are also described in detail, for example, in US-5668200, column 1 , line 30, until column 7, line 55, and as specific examples from column 26, line 31 , until column 32, last line, and, together with some advantageous UV absorbers of the benzothazole class, in US-5300414, column 2 to column 10, line 54. These sections of US-5668200 and US-5300414 are hereby incorporated by reference. The compounds of formula I may be used in combination with any known Dox scavengers such as hydrazines, hydrazides, hydroquinones of e.g. formula HQ-1 or HQ-2; 6-hydroxychromanes of e.g formula A-3 or hydroxylamines of e.g. formula A-4: As silver halide emulsions it is possible to use customary silver chloride, silver bromide or silver iodide emulsions or mixtures thereof, such as silver chlorobromide and silver chloro - iodide emulsions, in which the silver halides may have all known crystal forms. The use of silver chloride emulsions is accorded particular importance in the material of this novel process. The preparation of such emulsions and their sensitization are described in research disclosure, Item 307105, November 1989. Besides their use in colour photographic materials, compounds of formula (I) or especially (IV) can also find utility in other recording materials, such as digital recording materials, for example, those for pressure-sensitive copying systems, microcapsule photocopier systems, heat-sensitive copier systems and ink-jet printing. By such materials are meant, for example, those described in Research Disclosure, Item 31429, 1990. Preparation and details of non- silver halide recording material of the invention especially for ink-jet printing can be taken from US-5686633, column 6, line 55, until column 8, line 6, and US-5073448, column 6, line 43, until column 11 , line 57; these sections of US-5686633 and US-5073448 are hereby incorporated by reference. The inks according to the invention preferably contain 0.01-30 % by weight, in particular 0.1 -20 % by weight, of a compound of the formula (I) or (IV). Some of the compounds of the formula I are new compounds. Thus, this invention also pertains to a compound of the formula V or VI wherein R 4 is -(CH 2 ) s -COR' 15 or -CH(CH 3 )-CORι 5 or -C t H2t-COR 15 , wherein C t H 2 t is a straight chain or branched alkylene moiety; or R 4 is -O-(C v H 2v )-COR 15 ; -O-(CH 2 ) q -OR 32 ; -OCH 2 -CH(OH)-CH2-R 15 ; or -OCH 2 -CH(OH)-CH 2 -OR 32 ; R' 7 is Cι-C alkyl and R' 8 is hydrogen or d-C 4 alkyl; R 15 is hydroxy; - 1 r+ -O - -M ; C 1 -C 20 alkoxy; C 3 -C 20 alkoxy interrupted by O and/or substituted by a radical selected from OH, phenoxy, C 7 -C 15 alkylphenoxy, C 7 / R 24 Cι 5 alkoxyphenoxy; or R 15 is C 5 -Cι 2 cycloalkoxy; C 7 -Cι 7 phenylalkoxy; phenoxy; — N \ R '2.5 or a group of formula Ilia or lllb; R' 15 is C 3 -C 20 alkoxy interrupted by O and/or substituted by a radical selected from OH, phenoxy, C 7 -C 15 alkylphenoxy, C 7 -C 15 alkoxyphenoxy; or R 15 is C 5 -C 12 cycloalkoxy; C 7 - C 17 phenylalkoxy; phenoxy; or a group of formula Ilia or lllb; R 32 is d-Cι 8 alkanoyl; d-C 8 alkanoyl substituted by phenyl or C 7 -d 5 alkylphenyl; C 3 - C, 8 alkenoyl; cyclohexylcarbonyl; or naphthylcarbonyl; L is a linking group of valency (k+1 ) and L is as a divalent group -0-; Q-C 2 -d 2 alkylene-Q; -O-CH 2 -CH(OH)-CH 2 -O-; -Q-C2-C 12 alkylene-Q-CO-CvH 2v -0-; -0-C 2 -d 2 alkylene-0-CH2-CH(OH)-CH2-O-; Q-interrupted Q-C -Cι 2 alkylene-Q; Q-phenylene-Q or Q-phenylene-D-phenylene-Q with D being d- C 4 alkylene, O, S, SO or S0 2 ; L as a trivalent group is Q-capped C 3 -Cι 2 alkanetriyl, a trivalent residue of a hexose or a hexitol, or a group (-0-CH 2 ) 3 C-CH 2 OH; -Q-C a H2a-N(C b H 2 -Q-)-C c H2c-Q-; -Q-C 3 -Cι 2 alkanetriyl(-Q-CO-C.H2.-O-) 2 ; -O-C 3 -Cι 2 alkanetriyl(-O-CH 2 -CH(OH)-CH 2 -O-) 2 ; and L as a tetravalent group is a tetravalent residue of a hexose or a hexitol; -Q-C 4 -C 12 alkanetetryl(-Q-CO-C v H2.-O-)3; -O-C 4 -C 12 alkanetetryl(-O-CH 2 -CH(OH)-CH 2 -O-) 3 ; Q-capped C 4 -Cι 2 alkanetetryl; a group O^ H 2 2 H 2 H 2 A o o f a gr o p o c o c o ; .0 — o o- v is 1 , 2, 3, 4, 5, 6, 7 or 8, preferably 1 or 2; Q is oxygen or -NH-, Z is a linking group of valency (k+1) and is as a divalent group C 2 -C 12 alkyiene, Q-interrupted C -Cι 2 alkylene, phenylene or phenylene-D-phenylene with D being C C alkylene, O, S, SO or S0 2 ; Z as a trivalent group is C 3 -d 2 alkanetriyl, a trivalent residue of a hexose or a hexitol, a group (-CH 2 ) 3 C-CH 2 OH, or a group -C a H2_-N(C b H 2b -)-CcH 2 c-; and Z as a tetravalent group is a tetravalent residue of a hexose or a hexitol, C 4 -C 12 alkanetetryl, a group a, b, c and k independently are 1 , 2 or 3, m is 0 or a number from the range 1-12, preferably 1-6, s is 1 or 2, and t is a number from the range 3-12, preferably 3-6; and all other residues are as defined for formula I if n is 1. Preferred compounds of the formula V are, within the limits given, as defined for formulae I or IV above. Also preferred are compounds of formula V, wherein R 3 and R 5 are H and R 2 is d- C 8 alkyl, especially tert.butyl or tert.pentyl. Groups of formulae III, Ilia and lllb are as defined above for formulae I or IV. Where R15 or R' 15 contains a group of formula Ilia or lllb (di-, tri- or tetrameric benzofuranones of formula V), those compounds having symmetrical linking moieties are preferred. Preferred compounds of the formula VI are those wherein R' 7 is methyl or isopropyl and R' 8 is hydrogen or methyl. Compounds of the formulae V and VI are also useful as stabilisers for organic material against degradation by light, oxygen and/or heat. Application of these compounds and methods of stabilising are generally as described in GB-A-2322861 ; examples for organic material which can be stabilized are listed, for example, in GB-A-2319523 from page 15, line 1 1 , until page 20, line 25; possible costabilizers are as listed, for example, in GB-A-2319523 from page 21 , line 16, until page 32, bottom line. Examples for organic materials which can be stabilized as well as methods of stabilization are also listed in US-5668200, from column 8, line 18, to column 11 , line 25, and from column 18, line 29, to column 22, line 53, and additionally in column 25, lines 29-67; possible costabilizers and their dosage are as listed in US-5668200, column 11 , line 51 , to column 18, line 28, and column 22, line 54, to column 25, line 28, and in column 26, lines 9-15; these passages of US-5668200 are hereby incorporated by reference. Compounds of the formula V or VI are used for this application preferably in an amount of 0.0005 to 5%, especially 0.01 to 1%, based on the weight of the organic material to be stabilised. The invention also pertains to a composition comprising (a) an organic material which may be subject to degradation by light, oxygen and/or heat, and (b) as stabilizer against these harmful effects a compound of the formula V and/or VI. Most preferred organic materials to be stabilized are synthetic organic polymers and organic dyes, especially thermoplastic polymers such as polyolefin, photographic or materials or coating materials. Examples for compounds of the formula I to be used within this invention are: Compound 1 a) : Compound 2: Compound 3 a) : Compound 4 a) : Compound 5: Compound 6 ! Compound 7 a) : Compound 8: Compound 9 a). Compound 10 ; Compound 1 1 Compound 12 a) : Compound 13 a) : Compound 14 a) : Compound 15 a) : Compound 16 a) : Compound 17 a) : Compound 18 a). Compound 19: Compound 20: Compound 21 a) : Compound 22: Compound 23 a) : Compound 24: Compound 25 ' ' Compound 26 a) : Compound 27 a a'):. Compound 28: Compound 29: Compound 30: Compound 31 : Compound 32: a) These products may additionally contain minor amounts of other structural isomers in accordance with the substitution at the phenyl ring in 3-position of the benzofuran-2-one. For example, compound 7 comprises the 2 isomers The synthetic methods used for the preparation of the benzofuran-2-ones shown above are described e.g. in US Patents Nos. 5,607,624 and 5,814,692. Examples for the synthesis of some new compounds among the above are given below from example 8 onwards. Percentages given in the following examples are by weight if not otherwise indicated. Room temperature denotes a temperature in the range 20-25°C. Abbreviations: TCP tricresyl phosphate; RH relative humidity; Example 1 To evaluate compounds of this invention with respect to their ability as interlayer scavengers for oxidised developing agent, three layer photographic test elements are prepared by providing layers in the order indicated on a polyethylene-coated paper support: Test element 1 (reference sample) (1 ) A layer containing : - 1800 mg.m "2 of gelatin - 180 mg.m '2 of dibutylphthalate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (2) An interlayer containing : - 1800 mg.m "2 of gelatin - 300 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (3) A photosensitive layer containing : - 260 mg.m '2 (based on silver) of an unsensitized silver bromide emulsion - 1800 mg.m '2 of gelatin - 300 mg.m "2 of magenta-dye-forming coupler M-1 - 300 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent - 2-hydroxy-4,6-dichloro-1 ,3,5-thazine, potassium salt hardener - 7-methyl-5-hydroxy-1 ,3,8-triazaindolizine antifoggant. Test element 2 (check sample) (1) A layer containing : - 1800 mg.m "2 of gelatin - 272 mg.m "2 of cyan-dye-forming coupler C-1 - 180 mg.m "2 of dibutylphthalate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (2) An interlayer having the same composition as the interlayer of test element 1 (3) A photosensitive layer having the same composition as the photosensitive layer of test element 1. Test elements 3-8 (1) A layer having the same composition as the first layer of test element 2 (2) An interlayer containing - 1800 mg.m "2 of gelatin - 0.056x10 "3 mol.m "2 of oxidised developer scavenger as indicated in table 1 below - 300 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (3) A photosensitive layer having the same composition as the photosensitive layer of test element 1. The test elements are imagewise exposed through a step wedge with density increment 0.15 and thereafter subjected to the AGFA P-94 developing process. Within test elements 2-9, cyan dye can only be formed by the wandering of the oxidised developer from the layer in which it is formed (i.e. the uppermost layer) to the bottom layer containing the cyan-dye-forming coupler. The ability of an interlayer scavenger to prevent oxidised developer from diffusing into the bottom layer can thus be assessed by determining the cyan density at any chosen exposure amount. The cyan density at the exposure amount giving a magenta density of 2 is reported in table 1. The cyan density in the test element containing no cyan coupler in the bottom layer (test element 1 ) arises exclusively from the side absorption of the magenta dye in the red part of the visible spectrum. Any cyan density inferior to that observed in sample 2 indicates scavenging of the oxidised developer. It is thus clear from the data in table 1 that compounds within the scope of this invention are very effective in preventing the oxidised developer from wandering and forming dye in the wrong layer. Example 2 Three layer photographic test elements are prepared by providing layers in the order indicated on a polyethylene-coated paper support: Test element 9 (reference sample) Same as test element 1 of example 1 Test element 10 (check sample) (1 ) A layer containing : - 1800 mg.m "2 of gelatin - 272 mg.m '2 of cyan-dye-forming coupler C-2 - 180 mg.m "2 of dibutylphthalate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (2) An interlayer having the same composition as the interlayer of test element 9 (3) A photosensitive layer having the same composition as the photosensitive layer of test element 9. Test elements 11-14 (1) A layer having the same composition as the first layer of test element 10 (2) An interlayer containing - 1800 mg.m "2 of gelatin - 30 mg.m "2 of oxidised developer scavenger as indicated in table 2 below - 300 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (3) A photosensitive layer having the same composition as the photosensitive layer of test element 9. The test elements are exposed and processed in the same manner as in example 1. The cyan density at the exposure amount giving a magenta density 2 is reported in table 2. Table 2 According to the data in table 2, the compounds of this invention used in the test elements 11-14 are very effective oxidised developer scavengers. Example 3 Three layer photographic test elements are prepared by providing layers in the order indicated on a polyethylene-coated paper support: Test element 15 (check sample) (1) A layer containing : - 1800 mg.m "2 of gelatin - 272 mg.m "2 of cyan-dye-forming coupler C-2 - 180 mg.m "2 of dibutylphthalate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (2) An interlayer containing : - 1800 mg.m "2 of gelatin - 300 mg.m '2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (3) A photosensitive layer containing : - 260 mg.m '2 of an unsensitized silver bromide emulsion - 1800 mg.m '2 of gelatin - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent - 2-hydroxy-4,6-dichloro-1 ,3,5-triazine, sodium salt hardener - 7-methyl-5-hydroxy-1 ,3,8-triazaindolizine antifoggant. Test elements 16-27 (1) A layer having the same composition as the first layer of test element 15 (2) An interlayer containing - 1800 mg.m "2 of gelatin - 30 mg.m '2 of oxidised developer scavenger as indicated in table 3 below - 300 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (3) A photosensitive layer having the same composition as the photosensitive layer of test element 15. The test elements are given a stepped exposure and processed as in example 1. Cyan dye formation within the above described test elements will again only result from the wandering of the oxidised developer from the photosensitive layer to the layer containing the cyan-dye-forming coupler. The ability of an interlayer scavenger to prevent oxidised developer from diffusing into the bottom layer can thus be assessed by measuring the cyan density at any given exposure. As the above described samples contain no dye-forming coupler in the photosensitive layer, there is almost no consumption of the oxidised developer within the latter and the flux of oxidised developer through the interlayer towards the layer containing the cyan coupler is thus markedly increased as compared to the samples of examples 1 and 2. In table 3, (D^a n )^ is the cyan density at the exposure amount obtained behind the 1.35 density step of the step wedge. The smaller the (D cyan )ι. 35 value, the more effective the scavenging of the oxidised developer. Table 3 From the data in table 3, it can be seen again that 3-aryl-3H-benzofuran-2-ones according to this invention exhibit outstanding scavenging ability, as evidenced by much smaller cyan density values in the test elements 16-27 as compared to the check sample. Example 4 Three layer photographic test elements are prepared by providing layers in the order indicated on a polyethylene-coated paper support: Test element 28 (reference sample) (1) A layer containing : - 1800 mg.m '2 of gelatin - 180 mg.m "2 of dibutylphthalate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (2) An interlayer containing : - 1800 mg.m "2 of gelatin - 300 mg.m '2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (3) A photosensitive layer containing : - 260 mg.m "2 of an unsensitized silver bromide emulsion - 1800 mg.m "2 of gelatin - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent - 2-hydroxy-4,6-dichloro-1 ,3,5-triazine, sodium salt hardener - 7-methyl-5-hydroxy-1 ,3,8-thazaindolizine antifoggant. Test element 29 (check sample) Same as test element 15 of example 3 except that the cyan coupler used was C-1 instead of C-2. Test elements 30-33 (1) A layer having the same composition as the first layer of test element 29 (2) An interlayer containing - 1800 mg.m "2 of gelatin - Oxidised developer scavenger as indicated in table 4 below - 300 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (3) A photosensitive layer having the same composition as the photosensitive layer of test element 29. The test elements are given a stepped exposure and processed as in example 1. In table 4, (D cyan )ι. θ 5 is the cyan density at the exposure amount obtained behind the 1.05 density step of the step wedge. The smaller the (D cyan )ι.o5 value, the more effective the scavenging of the oxidised developer. Table 4 From the data in table 4, it can be seen that compound 7 according to this invention effectively prevents the formation of cyan dye, and that the Dox scavenging effect increases in proportion to the amount of added compound. Example 5 Three layer photographic test elements with a light sensitive layer on the bottom are similarly prepared, by providing layers in the order indicated onto a polyethylene coated paper support: Test element 34 (reference sample) (1) A photosensitive layer containing : - 260 mg.m "2 (based on silver) of an unsensitized silver bromide emulsion - 1875 mg.m "2 of gelatin - 250 mg.m "2 of magenta-dye-forming coupler M-2 - 250 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent - 7-methyl-5-hydroxy-1 ,3,8-triazaindolizine antifoggant. (2) An interlayer containing : - 1800 mg.m "2 of gelatin - 300 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (3) A layer containing : - 1800 mg.m "2 of gelatin - 180 mg.m '2 of dibutylphthalate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent - 2-hydroxy-4,6-dichloro-1 ,3,5-triazine, potassium salt hardener Test element 35 (check sample) (1) A photosensitive layer having the same composition as the photosensitive layer of test element 34 (2) An interlayer having the same composition as the interlayer of test element 34 (3) A layer containing : - 1800 mg.m "2 of gelatin - 272 mg.m '2 of cyan-dye-forming coupler C-2 - 180 mg.m "2 of dibutylphthalate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent - 2-hydroxy-4,6-dichloro-1 ,3,5-triazine, potassium salt hardener Test elements 36-42 (1) A photosensitive layer having the same composition as the photosensitive layer of test element 34 (2) An interlayer containing : - 1800 mg.m "2 of gelatin - 20 mg.m-2 of oxidised developer scavenger as indicated in table 5 below - 300 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (3) A layer having the same composition as the top layer of test element 35. The test elements are imagewise exposed through a step wedge with density increment 0.15 and thereafter subjected to the AGFA P-94 developing process. Upon processing of the test elements, some oxidised developer migrates from the bottom layer to the top layer, thereby producing unwanted cyan dye. The cyan density at the exposure amount giving a magenta density 2 is reported in table 5. Table 5 Example 6 Three layer photographic test elements are prepared by providing layers in the order indicated on a polyethylene-coated paper support : Test elements 46-73 (1) A layer containing : - 1800 mg.m '2 of gelatin - an oxidised developer scavenger as indicated in table 6 below - 300 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent (2) A photosensitive layer containing : - 260 mg.m "2 (based on silver) of an unsensitized silver bromide emulsion - 1800 mg.m "2 of gelatin - a magenta-dye-forming coupler as indicated in table 6 - a magenta dye light stabiliser as indicated in table 6 - tricresyl phosphate (TCP) as a high boiling solvent in the amount indicated in table 6 - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent - 7-methyl-5-hydroxy-1 ,3,8-triazaindolizine antifoggant. (3) A layer containing : - 1800 mg.m '2 of gelatin - an oxidised developer scavenger as indicated in table 6 - 300 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent - 2-hydroxy-4,6-dichloro-1 ,3,5-thazine, potassium salt hardener. The test elements are imagewise exposed through a step wedge with density increment 0.30 and thereafter subjected to the AGFA P-94 developing process. In order to evaluate them for light fastness, the stepped magenta images obtained in this manner are irradiated through an ultraviolet filter in an Atlas device equiped with a 3500 W Xenon lamp. In a second experiment, magenta images obtained in the above described way are stored in the dark at 60°C, 95% relative humidity (RH) for 72 hours prior to light exposure in the Atlas device. In all cases the light fastness of the magenta image is evaluated based on the percentage of the residual dye density after 30 kJ/cm 2 of light exposure (initial density = 1). The results are given in table 6. 1 The coated amounts (mg.rrr) are indicated in brackets. For the oxidised developer scavenger, the indicated amounts are for each of the two scavenger-containing layers. Components used in test elements 46-73: TCP = Tricresylphosphate S-1 M-1 : see above. From the data in table 6, it can be seen that the oxidised developer scavengers according to this invention are not detrimental to the light stability of the magenta layer, whether the samples are subjected to a preliminary dark storage period at 60°C, 95% RH, or not. In contrast, the comparison hydroquinone scavengers HQ-1 and especially HQ-2 clearly impair the light fastness of the magenta image, especially in test elements that are left under a high temperature and humidity for 72 hours prior to exposure in the Atlas. Example 7 Test element 74 is prepared by providing on a polyethylene-coated paper support a light- sensitive silver halide layer containing: - 260 mg.m "2 (based on silver) of an unsensitized silver bromide emulsion - 5150 mg.m "2 of gelatin - 305 mg.m "2 of magenta-dye-forming compound M-1 - 305 mg.m '2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent - 2-hydroxy-4,6-dichloro-1 ,3,5-thazine, potassium salt hardener - 7-methyl-5-hydroxy-1 ,3,8-triazaindolizine antifoggant Test elements 75 and 76 are prepared identically to test element 74, except that the emulsion layer additionally contains 30 mg.m "2 and 75 mg.m "2 of compound 7, respectively. Test element 77 is prepared by providing on a polyethylene-coated paper support a light- sensitive silver halide layer containing: - 520 mg.m "2 (based on silver) of an unsensitized silver bromide emulsion - 5150 mg.m "2 of gelatin - 417 mg.m "2 of magenta-dye-forming compound M-4 - 208 mg.m "2 of tricresylphosphate - 2-sulphonate-4,8-diisobutyl-naphtalene, sodium salt surface active agent - 2-hydroxy-4,6-dichloro-1 ,3,5-triazine, potassium salt hardener - 7-methyl-5-hydroxy-1 ,3,8-triazaindolizine antifoggant Test element 78 is prepared identically to test element 77, except that the emulsion layer additionally contains 105 mg.m "2 of compound 7. The prepared test elements are imagewise exposed through a step wedge with density increment 0.30 and thereafter subjected to the AGFA P-94 developing process. The stepped magenta images obtained in this manner are irradiated through an ultraviolet filter in an Atlas device equipped with a 3500 W Xenon lamp. The light fastness of the magenta image is evaluated based on the percentage of the residual dye density after 15 kJ/cm 2 of light exposure (initial density = 1 ). The results are given in table 7. As compared to a layer without added benzofuranone, magenta layers containing compound 7 are more stable to light. The benzofuranone derivatives according to this invention can therefore find utility as light stabilisers for photographic dyes, especially for those dyes that result from pyrazolone or pyrazolo-azole couplers. Synthesis of new compounds of formula I Example 8: 5,7-Di-tert-pentyl-3(4-isopropylphenyl)-3H-benzofuran-2-one (compound No. 26) a) 2,6-Di-tert-pentylphenol (161.4 g), glyoxylic acid (122.3 g of the 50% b.w. solution in water) and 1.3 g of p-toluene sulphonic acid are heated in 500 ml of ethylenechloride under nitrogen at reflux temperature in an apparatus designed for the removal of water. After 3.5 hours the reaction mixture is cooled to room temperature, washed 3 times with 25 ml water, dried over magnesium sulphite and evaporated under reduced pressure to give 214.3 g of : 5,7-di-tert-pentyl-3-hydroxy-3H-benzofuran-2-one as an orange coloured oil. b) 29.6 g of the product obtained under (a) are heated together with cumane (150 ml) and an ® acid earth catalyst (Fulcat 22 B, supplied by Laport, GB) under nitrogen to reflux. After 2 hours, the reaction mixture is filtered hot. Evaporation of the filtrate gives 35.1 g of raw product, which is subjected to chromatography on silica gel using hexane/ethyl acetate (4:1 ) as eluant. 26.7 g of the title product (compound No. 26) are obtained as an orange coloured oil. NMR (CDCI 3 ) 3-H: 5.29 ppm. Example 9: Preparation of 7-isopropyl-5-(4-methoxycarbonyl-1 ,1-dimethylbutyl)-3,4- dimethylphenyl-3H-benzofuran-2-one (compound No. 23) a) 5-Methyl-5-(4-hydroxy-3-isopropyl phenyl)-hexanoic acid methyl ester (10.0 g), glyoxylic acid (6.4 g of the 50 % solution in water) and p-toluene sulphonic acid (40 mg) are heated in 40 ml of ethylene chloride under nitrogen at reflux in an apparatus designed for the removal of water. After 5 hours the reaction mixture is cooled to room temperature, washed two times with 25 ml water, dried over magnesium sulphate and evaporated under reduced pressure to give 13 g of 7-isopropyl-5-(4-methoxycarbonyl-1 ,1- dimethylbutyl)-3-hydroxy-3H-benzofuran-2-one as a yellow oil. b) 13 g of the above product (a), o-xylene (50 ml) are heated together with an acid earth catalyst (see example 8b) under nitrogen at reflux for 2.5 hours. The reaction mixture is filtered hot and the filtrate evaporated to give 16.6 g of a yellow oil. This is chromatographed over silica gel using hexane/ethylacetate 20:5 as eluant. 10.4 g of the mixture of the 2 isomers 7-isopropyl-5-(4-methoxycarbonyl-1 ,1 -dimethylbutyl)-3,4- dimethylphenyl-3H-benzofuran-2-one and 7-isopropyl-5-(4-methoxycarbonyl-1 ,1- dimethylbutyl)-3-(2,3-dimethylphenyl)-3H-benzofuran-2-one as a slightly brown resin is obtained. NMR (CDCI 3 ) 3-H: 4.80 ppm. Example 10: Preparation of 7-lsopropyl-5-(4-methoxycarbonyl-1 ,1-dimethylbutyl)-3-(2.5-di- methylphenyl)-3H-benzofuran-2-one (compound No. 22) The product obtained in example 9a (14.35 g), p-xylene (50 ml) and an acid earth catalyst (see example 8b) are treated as described in example 9b to give 9.52 g of the title product (compound No. 22) as a slightly orange resin. NMR (CDCI 3 ) 3-H: 5.05 ppm. Example 11 : Preparation of compound No. 19 a) 3-(7-.tert.-Butyl-2-oxo-3-phenyl-2,3-dihydro-benzofuran-5-yl)-propionic acid 122.3 g (0.55 mol) 3-(3-tert.-butyl-4-hydroxy-phenyl)-propionic acid (CAS Nr. 107551-67- 7) and 92.1 g (0.61 mol) mandelic acid are melted together and then stirred under nitrogen at 200 °C during 4 h. The mixture is then cooled to room temperature, dissolved in toluene and chromatographed on silica gel with dichloromethane-ethyl acetate (3:1) to afford 103 g of the title compound as a pale yellow resin. 1 H-NMR (100 MHz, CDCI 3 ): 7.4- 6.9 m ( 7 ArH), 4.83 s (1 H), 3.00-2.54 m (4H), 1.42 s (t-Bu). b) 23.7 g (0.07 mol) of the product from example 11 a, 4.2 g (0.035 mol) 1 ,6-hexanediol and 0.3 g p-toluene sulphonic acid are refluxed in 250 ml of xylene under Dean-Stark water separator during 6 h. The mixture is then cooled to room temperature, washed with water, dried with MgSO 4 and evaporated under vacuum. Chromatography of the residue on silica gel with dichloromethane-hexane (19:1 ) affords the 14.8 g of the compound No. 19 as a pale yellow oil. 1 H-NMR (100 MHz, CDCI 3 ): 7.4-6.9 m ( 14 ArH), 4.82 s (2H), 4.08-3.96 m (4H), 2.98-2.51 m (8H), 1.61-1.26 m (4H), 1.42 s (t-Bu). Example 12: Preparation of 7-tert.butyl-5-(2-methoxycarbonylethyl)-3-(2,5-dimethylphenyl)- 3H-benzofuran-2-one (compound No. 24) a) 3-(4-hydroxy-3-tert.butylphenyl) propionic acid methyl ester (10.0 g), glyoxylic acid (7.4 g of the 50 % solution in water) and p-toluene sulphonic acid (40 mg) are heated in 40 ml ethylene chloride under nitrogen at reflux for 3 hours distilling off all water present and formed during the reaction. The reaction mixture is washed with water, dried over magnesium sulphate and evaporated under reduced pressure to give 13.0 g of 7- tert.butyl-5-(2-methoxycarbonylethyl)-3-hydroxy-3H-benzofuran-2-one. b) 13 g of the product from the above example 12a, 50 ml of p-xylene and and an acid earth catalyst (see example 8b) are heated under nitrogen at reflux for 2.5 hours. The reaction mixture is filtered hot and the filtrate evaporated under reduced pressure to give 17.0 g of an orange oil. This is purified by column chromatography over 350 g silica gel using hexane/ethylacetate 4:1 as eluant to give the title product, which solidifies after two days. Recrystallization from hexane gives a colourless solid, mp 80°. NMR (CDCI 3 ) 3- H:4.98 ppm. Example 13: Preparation of compound No. 29 a) 2.40 g 2-(3-tert.Butyl-4-hydroxyphenoxy)-acetic acid methyl ester is heated 8hrs. in 100ml toluene at reflux with 0.34g pentaerythritol in the pesence of 0.1 g p-toluenesulphonic acid. The resulting methanol is distilled off using a Hickmann apparatus. The reaction mixture is cooled to room teperature, washed with water, dried over magnesium sulphate and evaporated under reduced pressure. The residue (2,24g ) is treated with glyoxylic acid (1.62g of the 50% solution in water) and p.toluene sulphonic acid (0.1g) and heated in 20ml. ethylene chloride under nitrogen at reflux for 3.5hrs., distilling off all water present and formed during the reaction. The reaction mixture is washed wth water, dried over magnesium sulphate and evaporated under reduced pressure to give 2.80g of compound X of the formula: b) 2.8g Of the above compound X, 25ml. of cymene and an acid earth catalyst (see example 8b) are heated under nitrogen at reflux for 4hrs. The reaction mixture is filtered hot and the filtrate evaporated under reduced pressure to give 3.50g of impure product. This is purified by column chromatography over 160g silica gel using hexane/ ethyl acetate 4:1 as eluant to give purified compound No. 29 as a colourless resin. Example14: Preparation of compound No. 30 a) 3.50g 2-(3-tert-Butyl-4-hydroxyphenoxy)-propionic acid octyl ester is heated 3hrs. under nitrogen with glyoxylic acid(1.62g of the 50% solution in water) and p-toluene sulphonic acid (0.1g) in 20ml ethylene chloride at reflux, distilling off the water present and formed during the reaction. The reaction mixture is washed with water , dried over magnesium sulphate and evaporated under reduced pressure to give 4.05g of the below intermediate XII as a colourless oil: b) 4.05g of the above intermediate XII, 25ml.cymene and an acid catalyst ( see example 8b) are heated under nitrogen at reflux for 3 hrs. The reaction mixture is filtered hot and the filtrate evaporated under reduced pressure to give 4.91 g of the title product XIII. This is purified by column chromatography using 150g silica gel and hexane/ethyl acetate 4:1 as eluant to give purified compound No. 30 as a colourless oil. Example 15: Preparation of compound No. 31 a) 3.00g 1-Butoxy-2-hydroxy-3-(3-tert.butyl-4-hydroxyphenoxy)-propane is treated with glyoxylic acid (1.62g of a 50% solution in water) and p-toluene sulphonic acid (0.1g) and heated in 20ml ethylene chloride under nitrogen at reflux for 2.5 hrs., distilling off all the water present and formed during the reaction. The reaction mixture is washed with water, dried over magnesium sulphate and evaporated under reduced pressure to give 3.62 g of crude intermediate XIV: b) This was heated under nitrogen with an acid catalyst (see example 8b) in 25ml refluxing tert.butylbenzene for 2.5hrs. The reaction mixture is filtered hot and the filtrate evaporated under reduced pressure. The residue is purified by column chromatography over 150g silica gel using hexane/ethylacetate 4:1 as eluant to give compound No. 31 as a colourless oil. Example 16: Preparation of compound No. 32 Proceeding as in example 15, but using 2.92g of compound XVI of formula in step (a) instead of 1 -butoxy-2-hydroxy-3-(3-tert.butyl-4-hydroxyphenoxy)-propane one obtains compound No. 32 as a slightly yellow resin.

Claims: Claims: 1. Process for preventing migration of the oxidised developer in a colour photographic material from one colour sensitive layer to another by incorporating a compound of the formula I into said material wherein, if n = 1 , Ri is a cyclic residue selected from naphthyl, phenanthryl, anthryl, 5,6,7,8-tetrahydro-2- naphthyl, 5,6,7,8-tetrahydro-1 -naphthyl, thienyl, benzo[b]thienyl, naphtho[2,3-b]thienyl, thianthrenyl, dibenzofuryl, chromenyl, xanthenyl, phenoxathiinyl, pyrrolyl, imidazolyl, pyrazolyl, pyrazinyl, pyrimidinyl, pyridazinyl, indolizinyl, isoindolyl, indolyl, indazolyl, purinyl, quinolizinyl, isoquinolyl, quinolyl, phthalazinyl, naphthyridinyl, quinoxalinyl, quinazolinyl, cinnolinyl, pteridinyl, carbazolyl, β-carbolinyl, phenanthridinyl, acridinyl, perimidinyl, phenanthrolinyl, phenazinyl, isothiazolyl, phenothiazinyl, isoxazolyl, furazanyl, biphenyl, terphenyl, fluorenyl or phenoxazinyl, each of which is unsubstituted or substituted by Cr dalkyl, d-C 4 alkoxy, d-C 4 alkylthio, hydroxy, halogen, amino, d-C 4 alkylamino, phenylamino or di(Cι-C 4 -alkyl)amino; or is a radical of formula II and, if n = 2, R T is unsubstituted or d-C 4 alkyl- or hydroxy-substituted phenylene or naphthylene; or -Rι 2 -X-Rι 3 - ; R 2 , R 3 , R and R 5 are each independently of one another hydrogen; chloro; hydroxy; C C 25 - alkyl; C 7 -C 9 phenylalkyl; unsubstituted or C C alkyl-substituted phenyl; unsubstituted or d-dalkyl-substituted C 5 -C 8 cycloalkyl; CrCι 8 alkoxy; d-C 18 alkylthio; C C 4 alkylamino; di(Cι-C -alkyl)amino; d-C 25 alkanoyloxy; d-dsalkanoylamino; C 3 -C 25 alkenoyloxy; C 3 -C 25 alkanoyloxy which is interrupted by oxygen, sulphur or N — R 14 ; C 6 -C 9 cycloalkyl- carbonyloxy; benzoyloxy or d-C 12 alkyl-substituted benzoyloxy; or R 2 and R 3 , or R 3 and R , or R and R 5 , together with the linking carbon atoms, form a benzene ring; or R 4 is -C m H 2m -COR 15 , -O-(C v H 2v )-COR' 15 , -O-(CH 2 ) q -OR 32 , -OCH 2 -CH(OH)-CH 2 -R' 15 , -OCH 2 -CH(OH)-CH 2 -OR 32 , or -(CH 2 ) q OH; or, if R 3 , R 5 and R 6 are hydrogen, R 4 is additionally a radical of formula III wherein Ri is as defined above for n = 1 ; R 6 is hydrogen or, when R 4 is hydroxy, R 6 can also be d-C 25 alkyl or C 3 -C 25 alkenyl; R 7 , Re, R 9 , R 10 and Rn are each independently of one another hydrogen; halogen; hydroxy; d-C 25 alkyl; C 2 -C 25 alkyl which is interrupted by oxygen, sulphur or N — R 14 ; d- C 25 alkoxy; C 2 -C 25 alkoxy which is interrupted by oxygen, sulphur or N — R 14 ; d-C 25 alkylthio; C 3 -C 25 -alkenyl; C 3 -C 25 alkenyloxy; C 3 -C 25 alkynyl; C 3 -C 25 alkynyloxy; C 7 - C 9 phenylalkyl; C 7 -C 9 phenylalkoxy; unsubstituted or d-dalkyl-substituted phenyl; unsubstituted or C r C alkyl- substituted phenoxy; unsubstituted or C C 4 alkyl-substituted C 5 - dcycloalkyl; unsubstituted or Cι-C 4 alkyl-substituted C 5 -C 8 cycloalkoxy; C C alkylamino; di(Cι-C 4 alkyl)amino; d-C 25 alkanoyl; C 3 -C 25 alkanoyl which is interrupted by oxygen, sulphur \ or N— R 14 ; d-C 25 alkanoyloxy; C 3 -C 25 alkanoyloxy which is interrupted by oxygen, / sulphur or N— R 14 ; C C 25 alkanoylamino; C 3 -C 25 alkenoyl; C 3 -C 25 alkenoyl which is interrupted by oxygen, sulphur or N— R 14 ; C 3 -C 25 alkenoyloxy; C 3 -C 25 alkenoyloxy which \ is interrupted by oxygen, sulphur or N — R 14 ; C 6 -C 9 cycloalkylcarbonyl; C 6 / Cgcycloalkylcarbonyloxy; benzoyl or Cι-C 12 alkyl-substituted benzoyl; benzoyloxy or d- R 18 O R , 2on0 R I 18 I I 21 C 12 alkyl-substituted benzoyloxy; — O — C — C— R 15 or — O — C — C— O— R 23 or, in R 19 H R 22 formula II, R 7 and R 8 , or R 8 and Rn, together with the linking carbon atoms, form a benzene ring; R 12 and R 13 are each independently of the other unsubstituted or d-C alkyl-substituted phenylene or naphthylene; R 14 is hydrogen or C C 8 alkyl; R 15 and R' 15 independently are hydroxy; 1 r+ — 0 ; d-C 20 alkoxy; C 3 -C 20 alkoxy interrupted by O and/or substituted by a radical selected from OH, phenoxy, C 7 - C 15 alkylphenoxy, C 7 -d 5 alkoxyphenoxy; or are C 5 -C 12 cycloalkoxy; C 7 -C 17 phenylalkoxy; / R "2.4 phenoxy; — N ; or a group of the formula Ilia or lllb 25 Rie and R 17 are each independently of the other hydrogen, CF 3 , Cι-Cι 2 alkyl or phenyl, or R 16 and Rι 7 , together with the linking carbon atom, are a C 5 -C 8 cycloalkylidene ring which is unsubstituted or substituted by 1 to 3 C C 4 alkyl; Rι 8 and Rι 9 are each independently of the other hydrogen, Cι-C alkyl or phenyl; R 20 is hydrogen or d-C 4 alkyl; R 2 is hydrogen; unsubstituted or d-C alkyl-substituted phenyl; d-C 25 alkyl; C 2 -C 25 alkyl \ which is interrupted by oxygen, sulphur or ~ N— R 14 ; C 7 -C 9 phenylalkyl which is unsubsti¬ tuted or substituted at the phenyl moiety by 1 to 3 C C alkyl; C 7 -C 25 phenylalkyl which is interrupted by oxygen, sulphur or N — R 14 and which is unsubstituted or substituted at the phenyl moiety by 1 to 3 Cι-C 4 alkyl; or R 20 and R 21 , together with the linking carbon atoms, form a C 5 -d 2 cycloalkylene ring which is unsubstituted or substituted by 1 to 3 d-C alkyl; R 22 is hydrogen or d-C 4 alkyl; R 23 is hydrogen; d-C 25 alkanoyl; C 3 -C 25 alkenoyl; C 3 -C 25 alkanoyl which is interrupted by oxygen, sulphur or N — R 14 ; C 2 -C 25 alkanoyl which is substituted by a di(d-C 6 alkyl)phos- phonate group; C 6 -C 9 cycloalkylcarbonyl; thenoyl; furoyl; benzoyl or Cι-C 12 alkyl-substituted benzoyl; R and R 25 are each independently of the other hydrogen or Cι-C 18 alkyl; R 26 is hydrogen or d-C 8 alkyl; R 27 is a direct bond; d-C 18 alkylene; C 2 -C 18 alkylene which is interrupted by oxygen, sulphur or N — R 14 ; C 2 -C 18 alkenylene; C 2 -C 20 alkylidene; C 7 -C 20 phenylalkylidene; C 5 -C 8 cycloalky- lene; C 7 -C 8 bicycloalkylene; unsubstituted or d-C alkyl-substituted phenylene; / R 24 - 1 r+ R 28 is hydroxy, -O - M , Cι-C 18 alkoxy or — N \ R 25 R 29 is oxygen or -NH-; R 30 is C C 18 alkyl or phenyl; R 3 ι is hydrogen or C Cι 8 alkyl; R 32 is d-Cι 8 alkanoyl; Cι-C 8 alkanoyl substituted by phenyl or C 7 -C 15 alkylphenyl; C 3 - Cι 8 alkenoyl; cyclohexylcarbonyl; or naphthylcarbonyl; L is a linking group of valency (k+1 ) and is as a divalent group -O-; Q-C 2 -C 12 alkylene-Q; -O-CH 2 -CH(OH)-CH 2 -O-; -Q-C2-C 12 alkylene-Q-CO-C v H 2 .-0-; -O-C 2 -C 12 alkylene-O-CH 2 -CH(OH)-CH 2 -O-; Q-interrupted Q-C -Cι 2 alkylene-Q; Q-phenylene-Q or Q-phenylene-D-phenylene-Q with D being d-C 4 alkylene, O, S, SO or SO 2 ; L as a trivalent group is Q-capped C 3 -C 12 alkanetriyl, a trivalent residue of a hexose or a hexitol, or a group (-O-CH 2 ) 3 C-CH 2 OH; -Q-CaH 2a -N(C b H2 b -Q-)-C c H2c-Q-; -Q-C 3 -C 12 alkanetriyl(-Q-CO-C v H 2v -0-) 2 ; -O-C3-C 12 alkanetriyl(-O-CH2-CH(OH)-CH2-O-) 2 ; and L as a tetravalent group is a tetravalent residue of a hexose or a hexitol; -Q-C 4 -Cι 2 alkanetetryl(-Q-CO-C v H 2v -0-) 3 ; -0-C 4 -C 12 alkanetetryl(-0-CH 2 -CH(OH)-CH 2 -0-) 3 ; Q-capped C 4 -Cι 2 alkanetetryl; a group 0 M is an r-valent metal cation; Q is oxygen or -NH-; X is a direct bond, oxygen, sulphur or -NR 31 - ; Z is a linking group of valency (k+1 ) and is as a divalent group C 2 -Cι 2 alkylene; Q-interrupted C 4 -Cι 2 alkylene; phenylene or phenylene-D-phenylene with D being C C alkylene, O, S, SO or S0 2 ; Z as a trivalent group is C 3 -Cι 2 alkanethyl, a trivalent residue of a hexose or a hexitol, a group (-CH 2 ) 3 C-CH 2 OH, or a group -C a H 2a -N(C H 2b -)-C c H 2c -; and Z as a tetravalent group is a tetravalent, carbon-ended residue of a hexose or a hexitol, C 4 - Cι 2 alkanetetryl, a group a, b, c and k independently are 1 , 2 or 3; m is 0 or a number from the range 1 -12, preferably 1-6; n is 1 or 2; q is 1 , 2, 3, 4, 5 or 6; r is 1 , 2 or 3; and s is O, 1 or 2; v is 1 , 2, 3, 4, 5, 6, 7 or 8, preferably 1 or 2; provided that, when R 7 is hydroxy, alkanoyloxy or alkanoyloxy interrupted by O, S or N(R 14 ) and R 9 is hydrogen, R 0 is not identical with R ; and when R 9 is hydroxy, alkanoyloxy or alkanoyloxy interrupted by O, S or N(R 14 ) and R 7 is hydrogen, R 8 is not identical with R 4 . 2. Process according to claim 1 , wherein in the compound of formula I R 7 and R 9 are each independently of one another hydrogen; halogen; Cι-C 25 alkyl; C 2 -C 25 alkyl which is interrupted by oxygen, sulphur or N — R 14 ; C 2 -C 25 alkoxy which is interrupted by oxygen, sulphur or N — R 14 ; Cι-C 5 alkylthio; C 3 -C 25 -alkenyl; C 3 -C 25 alkenyloxy; C 3 - C 25 alkynyl; C 3 -C 25 alkynyloxy; C 7 -C 9 phenylalkyl; C 7 -C 9 phenylalkoxy; unsubstituted or d- C alkyl-substituted phenyl; unsubstituted or Cι-C 4 alkyl- substituted phenoxy; unsubstituted or d-dalkyl-substituted C 5 -C 8 cycloalkyl; unsubstituted or d-C 4 alkyl-substituted C 5 - C 8 cycloalkoxy; Cι-C 4 alkylamino; di(d-C 4 alkyl)amino; d-C 25 alkanoyl; C 3 -C 25 alkanoyl which is interrupted by oxygen, sulphur or N — R 14 ; d-C 25 alkanoylamino; C 3 -C 25 alkenoyl; C 3 - C 25 alkenoyl which is interrupted by oxygen, sulphur or N — R 14 ; C 6 -C 9 - R 18 o I 18 II cycloalkylcarbonyl; benzoyl or d-Cι 2 alkyl-substituted benzoyl; — O — C — C— R 15 or R '1.9 — 3. Process according to claim 1 wherein in the compound of formula I R T is naphthyl, phenanthryl, anthryl, 5,6,7,8-tetrahydro-2-naphthyl, 5,6,7,8-tetrahydro-1- naphthyl, thienyl, benzo[b]thienyl, naphtho[2,3-b]thienyl, thianthrenyl, dibenzofuryl, chrome- nyl, xanthenyl, phenoxathiinyl, pyrrolyl, imidazolyl, pyrazolyl, pyrazinyl, pyrimidinyl, pyridazi- nyl, indolizinyl, isoindolyl, indolyl, indazolyl, purinyl, quinolizinyl, isoquinolyl, quinolyl, phthala- zinyl, naphthyridinyl, quinoxalinyl, quinazolinyl, cinnolinyl, pteridinyl, carbazolyl, β-carbolinyl, phenanthridinyl, acridinyl, perimidinyl, phenanthrolinyl, phenazinyl, isothiazolyl, phenothia- zinyl, isoxazolyl, furazanyl, biphenyl, terphenyl, fluorenyl or phenoxazinyl, each of which is unsubstituted or substituted by C C alkyl, Cι-C 4 alkoxy, d-C alkylthio, hydroxy, halogen, amino, d-C 4 alkylamino, phenylamino or di(d-C 4 -alkyl)amino, or R^ is a radical of formula II and, if n = 2, Ri is unsubstituted or d-dalkyl- or hydroxy-substituted phenylene or naphthylene; or -Rι 2 -X-Rι 3 - , R 2 , R 3 , R 4 and R 5 are each independently of one another hydrogen, chloro, hydroxy, d-C 25 - alkyl, C 7 -C 9 phenylalkyl, unsubstituted or d-C alkyl-substituted phenyl; unsubstituted or d-dalkyl-substituted C -C 8 cycloalkyl; d-C 18 alkoxy, C Cι 8 alkylthio, d-dalkylamino, di(C C 4 -alkyl)amino, Cι-C 25 alkanoyloxy, CrC 25 alkanoylamino, C 3 -C 25 alkenoyloxy; C 3 -C 25 alkanoyloxy which is interrupted by oxygen, sulphur or N — R 14 ; C 6 -C 9 cycloalkyl- carbonyloxy, benzoyloxy or d-C 12 alkyl-substituted benzoyloxy; or R 2 and R 3 , or R 3 and R , or R 4 and R 5 , together with the linking carbon atoms, form a benzene ring; or R 4 is -C m H 2m -CORi 5 or -(CH 2 ) q OH or, if R 3 , R 5 and R 6 are hydrogen, R 4 is additionally a radical of formula III wherein R^ is as defined above for n = 1 ; R 6 is hydrogen or, when R 4 is hydroxy, R 6 can also be C r C 25 alkyl or C 3 -C 25 alkenyl; R7, Re, Rg, RIQ and Rn are each independently of one another hydrogen, halogen, hydroxy, Crd δ alkyl; d-dsalkyl which is interrupted by oxygen, sulphur or N — R 14 ; d- C 25 alkoxy; C 2 -C 25 alkoxy which is interrupted by oxygen, sulphur or N — R 14 ; Cι-C 25 alkylthio, C 3 -C 25 -alkenyl, C 3 -C 25 alkenyloxy, C 3 -C 25 alkynyl, C 3 -C 25 alkynyloxy, C 7 - dphenyialkyl, C 7 -C 9 phenylalkoxy, unsubstituted or d-C 4 alkyl-substituted phenyl; unsubstituted or d-C alkyl- substituted phenoxy; unsubstituted or Cι-C 4 alkyl-substituted C 5 - dcycloalkyl; unsubstituted or Cι-C alkyl-substituted C 5 -C 8 cycloalkoxy; d-C 4 alkylamino, di(C C alkyl)amino, d-C 25 alkanoyl; C 3 -C 25 alkanoyl which is interrupted by oxygen, sulphur or N — R 14 ; d-C 25 alkanoyloxy; C 3 -C 25 alkanoyloxy which is interrupted by oxygen, sulphur or N — R 14 ; d-C 25 alkanoylamino, C 3 -C 25 alkenoyl; C 3 -C 25 alkenoyl which is interrupted by oxygen, sulphur or N — R 14 ; C 3 -C 25 alkenoyloxy; C 3 -C 25 alkenoyloxy which is interrupted by oxygen, sulphur or N — R 14 ; C 6 -C 9 cycloalkylcarbonyl, C 6 - Cgcycloalkylcarbonyloxy, benzoyl or d-Cι 2 alkyl-substituted benzoyl; benzoyloxy or d- R 1R O R 9n R,, I 18 II I 20 I 21 Cι 2 alkyl-substituted benzoyloxy; — 0— C — C— R 15 or — O — C — C— O— R 23 or, in R 19 H R 22 formula II, R 7 and R 8 , or R 8 and Rn, together with the linking carbon atoms, form a benzene ring, R 12 and R 13 are each independently of the other unsubstituted or d-C 4 alkyl-substituted phenylene or naphthylene, Ru is hydrogen or d-C 8 alkyl, / R 24 R 15 is hydroxy, 1 r+ — 0 , d-C 20 alkoxy, — N \ or a group of the formula Ilia '25 Rie and Rι 7 are each independently of the other hydrogen, CF 3 , C C 12 alkyl or phenyl, or R 16 and R 17 , together with the linking carbon atom, are a C 5 -C 8 cycloalkylidene ring which is unsubstituted or substituted by 1 to 3 d-C 4 alkyl; R 18 and R 19 are each independently of the other hydrogen, d-dalkyl or phenyl, R 2 o is hydrogen or C r C alkyl, R 2 ι is hydrogen, unsubstituted or d-C alkyl-substituted phenyl; d-dsalkyl; C 2 -C 25 alkyl which is interrupted by oxygen, sulphur or N — R 14 ; C 7 -C 9 phenylalkyl which is unsubsti¬ tuted or substituted at the phenyl moiety by 1 to 3 Cι-C 4 alkyl; C 7 -C 25 phenylalkyl which is interrupted by oxygen, sulphur or N — R 14 and which is unsubstituted or substituted at the phenyl moiety by 1 to 3 d-C 4 alkyl, or R 20 and R 2 ι, together with the linking carbon atoms, form a C 5 -Cι 2 cycloalkylene ring which is unsubstituted or substituted by 1 to 3 d-dalkyl; R 22 is hydrogen or d-C 4 alkyl, R 23 is hydrogen, C 1 -C 25 alkanoyl, C 3 -C 25 alkenoyl; C 3 -C 25 alkanoyl which is interrupted by oxygen, sulphur or N — R 14 ; C 2 -C 2 5alkanoyl which is substituted by a di(d-C 6 alkyl)phos- phonate group; C 6 -C 9 cycloalkylcarbonyl, thenoyl, furoyl, benzoyl or d-C 12 alkyl-substituted benzoyl; R 24 and R 25 are each independently of the other hydrogen or Cι-C 18 alkyl, R 26 is hydrogen or Cι-C 8 alkyl, R 27 is a direct bond, Cι-C 18 alkylene; C 2 -Cι 8 alkylene which is interrupted by oxygen, sulphur \ or N — R 14 ; C 2 -Cι 8 alkenylene, C 2 -C 20 alkylidene, C 7 -C 20 phenylalkylidene, C 5 -C 8 cycloalky- / lene, C 7 -C 8 bicycloalkylene, unsubstituted or C C alkyl-substituted phenylene, / R 24 R 28 is hydroxy, - 1 r+ — o -7 M Cι-C 18 alkoxy or — N \ R L 2, 5 R 29 is oxygen or -NH-, R 30 is Cι-Cι 8 alkyl or phenyl, R 31 is hydrogen or d-C 18 alkyl, M is an r-valent metal cation, Q is oxygen or -NH-, X is a direct bond, oxygen, sulphur or -NR 31 - , Z is a linking group of valency (k+1) and is as a divalent group C 2 -d 2 alkylene, Q-interrupted d-C 12 alkyiene, phenylene or phenylene-D-phenylene with D being d-C 4 alkylene, O, S, SO or SO 2 ; Z as a trivalent group is C 3 -Cι 2 alkanetriyl, a trivalent residue of a hexose or a hexitol, a group (-CH 2 ) 3 C-CH 2 OH, or a group -CaH 2a -N(C b H 2b -)-C c H 2c -; and Z as a tetravalent group is a tetravalent residue of a hexose or a hexitol, C 4 -d 2 alkanetetryl, a group a, b, c and k independently are 1 , 2 or 3, m is 0 or a number from the range 1 -12, preferably 1 -6, n is 1 or 2, q is 1 , 2, 3, 4, 5 or 6, r is 1 , 2 or 3, and s is 0, 1 or 2; provided that, when R 7 is hydroxy, alkanoyloxy or alkanoyloxy interrupted by O, S or N(R 14 ) and R 9 is hydrogen, Rι 0 is not identical with R . 4. Process according to claim 1 , wherein in the compound of formula I R 2 , R 3 and R 5 , independently, are H, Cl, hydroxy, d-C 25 alkyl, C 7 -C 9 phenylalkyl, unsubstituted or d-dalkyl-substituted phenyl; C C 18 alkoxy, d-C 25 alkanoyloxy, C 3 -C 25 alkenoyloxy; and where R 4 is Cl, hydroxy, C C 25 alkyl, C 7 -C 9 phenylalkyl, unsubstituted or Cι-C 4 alkyl-substituted phenyl; d-C 18 alkoxy, CrC 25 alkanoyloxy, C 3 -C 25 alkenoyloxy or is a group -C m H 2m -CORι 5 , -O-(C v H 2v )-COR' 15 , -O-(CH 2 ) q -OR 32 , -OCH 2 -CH(OH)-CH 2 -R' 15 , -OCH 2 -CH(OH)-CH 2 -OR 32) or where R 3 , R 5 and R 6 are H, R 4 may be a residue of formula III, or where R 8 or R 10 are other than H, R may also be hydrogen; R 6 is H, R 7 and R 9 are each independently of one another hydrogen; halogen; d-C 25 alkyl; C 2 -C 25 alkyl which is interrupted by oxygen, sulphur or N — R 14 ; C 3 -C 25 -alkenyl; C 3 -C 25 alkynyl; C 7 - C 9 phenylalkyl; unsubstituted or Cι-C 4 alkyl-substituted phenyl; unsubstituted or d-dalkyl- substituted C 5 -C 8 cycloalkyl; R 8 , Rio and R independently are H, halogen, hydroxy, d-C 25 alkyl, O interrupted C 2 - C 25 alkyl; d-C 25 alkoxy, O interrupted C 2 -C 25 alkoxy, C 3 -C 25 alkenyl, C 3 -C 25 alkenyloxy, C 7 - Cgphenylalkyl, C 7 -C 9 phenylalkoxy, unsubstituted or Cι-C 4 alkyl-substituted phenyl; unsubstituted or d-dalkyl substituted phenoxy; unsubstituted or C C 4 alkyl substituted C 5 - Cscycloalkyl; unsubstituted or d-C alkyl substituted C 5 -C 8 cycloalkoxy; C C 4 alkylamino, di- (C C -alkyl)amino, C C 25 alkanoyl; d-C 25 alkanoyloxy; C 6 -C 9 cycloalkylcarbonyl, C 6 - Cgcycloalkylcarbonyloxy, benzoyl or d-Cι 2 alkyl-substituted benzoyl; benzoyloxy or C R 18 O R ,'2on0 R 2. 1 Cι 2 alkyl substituted benzoyloxy; — O — C — C— R 15 or — O — C — C— O— R 23 , or R 19 H R 22 where in formula II R 7 and R 8 or R 8 and R together with the carbon atoms, they are bonded to, form a phenyl ring; R 15 and R'ι 5 independently are C Cι 8 alkoxy; C 3 -C 20 alkoxy interrupted by O and/or substituted by a radical selected from OH, phenoxy, C 7 -Cι 5 alkylphenoxy, C 7 - C 15 alkoxyphenoxy; or are C 5 -d 2 cycloalkoxy; C 7 -Cι 7 phenylalkoxy; phenoxy; or -NR 23 R 2 ; or a group of formula Ilia or lllb; R 16 and Rι 7 independently are H, CF 3 , C C 12 alkyl or phenyl; or R 16 and Rι 7 together with the bonding carbon atom form an unsubstituted or 1 -3 C C alkyl-substituted C - C 8 cycloalkylidene ring; R 18 andR 19 independently are H, C r C 4 alkyl or phenyl; R 20 is H or d-dalkyl; R 21 is H, unsubstituted or C C 4 alkyl substituted phenyl; C r C 25 alkyl, unsubstituted or on the phenyl ring 1-3 d-C 4 alkyl-substituted C 7 -C 9 phenylalkyl; R 22 is H or d-dalkyl; R 23 is H, Cι-C 25 alkanoyl, C 3 -C 25 alkenoyl; di(d-C 6 alkyl)phosphonate-substituted C 2 - C 25 alkanoyl; C 6 -C 9 cycloalkylcarbonyl, thenoyl, furoyl, benzoyl or d-C 12 alkyl-substituted benzoyl; R 24 and R 25 independently are H or C C 18 alkyl; R 26 is H or d-C 8 alkyl; R 27 is a direct bond, C Cι 8 alkylen, C 2 -C 18 alkenylen, C 7 -C 20 phenylalkyliden, C 5 - Cscycloalkylen, unsubstituted or C C alkyl-substituted phenylene, ({ or / R 24 R 28 C r C 18 alkoxy or — N \ '25 R 29 is O or -NH-; R 3 o Cι-C 18 alkyl or phenyl; M a metal cation of the valency r; X a direct bond, O, S or -NR 31 - ; n 1 or 2; m is a number from the range 1-8; q 1 , 2, 3, 4, 5 or 6; r 1 , 2 or 3; and s is O, 1 or 2. 5. Process according to claim 1 wherein the compound of formula I corresponds to the formula IV wherein R 2 is H or Cι-C 20 alkyl; R 3 is H or d-Cι 8 alkyl; R 4 is Cι-C 8 alkyl, H, d-C 6 alkoxy or a group -C m H 2m -CORι 5 ; -O-(C v H 2v )-COR 15 , -O-(CH 2 ) q -OR 32 ; -OCH 2 -CH(OH)-CH 2 -R 15 ; -OCH 2 -CH(OH)-CH 2 -OR 32 ; or a group of the formula III R 5 is H or d-C 18 alkyl; R 7 and R 9 are each independently of one another hydrogen; halogen; C C 25 alkyl; C 3 -C 25 - alkenyl; C 3 -C 25 alkynyl; C 7 -C 9 phenylalkyl; unsubstituted or C C 4 alkyl-substituted phenyl; unsubstituted or d-C 4 alkyl-substituted C 5 -C 8 cycloalkyl; R 8 , R 10 and Rn independently are H, OH, chloro, d-Cι 8 alkyl, d-Cι 8 alkoxy, di(C C 4 alkyl)amino, C 7 -C 9 phenylalkyl; unsubstituted or C C alkyl-substituted phenyl; unsubstituted or Cι-C 4 alkyl-substituted C 5 -C 8 cycloalkyl; C 2 -Cι 8 alkanoyloxy, C 3 -Cι 8 - R 20 R 21 alkoxycarbonylalkoxy or — O — C — C— O— R 23 ; H R 2 2 especially wherein at least 2 of the residues R 7 , R 8 , R 9 , R 10, R are H; R 15 is Cι-C 18 alkoxy; C 3 -C 20 alkoxy interrupted by O; or are cyclohexyloxy; C 7 -Cι 7 phenylalkoxy; phenoxy; or a group of formula Ilia or lllb; Ri 6 and Rι 7 independently are H, Cι-C 12 alkyl or phenyl; or R 16 and Rι 7 together with the bonding carbon atom form a C 5 -C 8 cycloalkylidene ring; R 20 , R 2 ι and R 22 independently are H or d-C alkyl; R 23 is H, C 2 -C 18 alkanoyl or a group R 26 is C r C 4 alkyl; R 32 is C C 18 alkanoyl; d-C 8 alkanoyl substituted by phenyl or C 7 -d 5 alkylphenyl; C 3 - C 18 alkenoyl; cyclohexylcarbonyl; or naphthylcarbonyl; L is a divalent group -O-; Q-C 2 -C 12 alkylene-Q; -O-CH 2 -CH(OH)-CH 2 -O-; -Q-Ca-C^alkylene-Q-CO-C v Hg v -O-j -O^-C^alkylene-O-CHz-CH^HJ-CHs-O-; Q is oxygen; Z is C 2 -C 12 alkylene; k is 1 ; m is 1 , 2, 3, 4, 5 or 6; v is 1 or 2; and s is 0, 1 or 2. 6. Process according to claim 5 wherein in the compound of formula IV R 2 is d-C 20 alkyl; R 3 is H or d-C 18 alkyl; R is d-dalkyl, d-C 6 alkoxy or a group -C m H 2m -COR 15 or a group of the formula R 5 is H or d-Cι 8 alkyl; R 7 and R 9 independently are H, chloro, C C 18 alkyl; R 8 , R 10 and Rn independently are H, OH, chloro, Cι-Cι 8 alkyl, d-dealkoxy, di(d- C 4 alkyl)amino, phenyl, C 2 -d 8 alkanoyloxy or — O — C — C— O— R '23 H '22 R 15 is d-Cι 8 alkoxy or a group of the formula Ilia R 26 is d-C 4 alkyl; Q is oxygen; Z is C 2 -Cι 2 alkylene; k is 1 ; m is 1 , 2, 3, 4, 5 or 6 and s is O, 1 or 2. 7. Process according to claim 5 wherein in the compound of formula IV, R is d-C 6 alkyl, or a group -C m H 2m -COR 15 , -0-(C v H 2v )-CORι 5 , -0-(CH 2 ) q -OR 32 , -OCH 2 -CH(OH)-CH 2 -R 15 , -OCH 2 -CH(OH)-CH 2 -OR 32 , or a group of the formula III. 8. Process according to claim 1 , wherein the compound of formula I is incorporated into the colour photographic material in an amount from 10 to 1000 mg/m 2 . 9. Process according to claim 1 , wherein the compound of formula I is concentrated in one or more interlayers separating light sensitive layers of the colour photographic material. 10. Process according to claim 9, wherein a green-sensitive layer containing a magenta coupler of the pyrazolo-azole class is adjacent to an interlayer containing the compound of formula I. 11. Use of a compound of the formula I according to claim 1 as a scavenger for the oxidised developer in a colour photographic material. 12. A colour photographic material or digital recording material containing a compound of the formula IV wherein R 2 is H or d-C 20 alkyl; R 3 is H or d-C 18 alkyl; R 4 is C r C 8 alkyl, d-C 6 alkoxy or a group -C m H 2m -COR 15 ; -0-(C v H 2v )-CORι 5 , -0-(CH 2 ) q -OR 32 ; -OCH 2 -CH(OH)-CH 2 -R 15 ; -OCH 2 -CH(OH)-CH 2 -OR 32 ; or a group of the formula III R 5 is H or d-C 18 alkyl; R 7 and R 9 independently are H, chloro, Cι-C 18 alkyl or phenyl; R 8 , Rio and Rn independently are H, OH, chloro, C r Cι 8 alkyl, C r Ci_alkoxy, di(C r C alkyl)amino, phenyl, C -C 18 alkanoyloxy, C 3 -C 18 -alkoxycarbonylalkoxy or , 20 R 21 -O— C — C— O— 23 H R '2.2 R 15 is C Cι 8 alkoxy; C 3 -C 20 alkoxy interrupted by O; or are cyclohexyloxy; C 7 -Cι 7 phenylalkoxy; phenoxy; or a group of formula Ilia or lllb; Rie and R 17 independently are H, C Cι 2 alkyl or phenyl; or R 16 and R 17 together with the bonding carbon atom form a C 5 -C 8 cycloalkylidene ring; R_o, R 21 and R 22 independently are H or C C 4 alkyl; R 23 is H, C 2 -C 18 alkanoyl or a group R 26 is Cι-C 4 alkyl; R 32 is d-C 18 alkanoyl; C C 8 alkanoyl substituted by phenyl or C 7 -C 15 alkylphenyl; C 3 - Cι 8 alkenoyl; cyclohexylcarbonyl; or naphthylcarbonyl; L is a divalent group -0-; Q-C 2 -C 12 alkylene-Q; -0-CH 2 -CH(OH)-CH 2 -0-; -Q-C 2 -Cι 2 alkylene-Q-CO-CvH 2v -0-; -0-C 2 -C 12 alkylene-0-CH 2 -CH(OH)-CH 2 -O-; Q is oxygen; Z is C 2 -C 12 alkylene; k is 1 ; m is 1 , 2, 3, 4, 5 or 6; v is 1 or 2 and s is 0, 1 or 2. 13. Use of a compound of the formula IV according to claim 12 as an additive in a colour photographic material or digital recording material. 14. Compound of the formula V or VI wherein R 4 is -(CH 2 ) s -COR'i 5 or -CH(CH 3 )-COR 15 or -C,H 2t -COR 15 , wherein C,H 2 , is a straight chain or branched alkylene moiety; or R 4 is -O-(C v H 2v )-COR 15 ; -O-(CH 2 ) q -OR 32 ; -OCH 2 -CH(OH)-CH 2 -R 15 ; or -OCH 2 -CH(OH)-CH 2 -OR32; R' 7 is d-C alkyl and R' 8 is hydrogen or d-C 4 alkyl; R 15 is hydroxy, - 1 r+ -0 -γ M , d-C 20 alkoxy; C 3 -C 20 alkoxy interrupted by O and/or substituted by a radical selected from OH, phenoxy, C 7 -d 5 alkylphenoxy, C 7 / R 24 C 15 alkoxyphenoxy; or R 15 is C 5 -d 2 cycloalkoxy; C 7 -C 17 phenylalkoxy; phenoxy; — N \ R 2.5 or a group of formula Ilia or lllb; R' 15 is C 3 -C 20 alkoxy interrupted by O and/or substituted by a radical selected from OH, phenoxy, C 7 -C 15 alkylphenoxy, C 7 -C 15 alkoxyphenoxy; or R' 15 is C 5 -C 12 cycloalkoxy; C 7 - Cι 7 phenylalkoxy; phenoxy; or a group of formula Ilia or lllb; R 32 is C r C 18 alkanoyl; C C 8 alkanoyl substituted by phenyl or C 7 -C 15 alkylphenyl; C 3 - C 18 alkenoyl; cyclohexylcarbonyl; or naphthylcarbonyl; L is a linking group of valency (k+1 ) and is, as a divalent group, -0-; Q-C 2 -C 12 alkylene-Q; -0-CH 2 -CH(OH)-CH 2 -0-; -Q-C 2 -C 12 alkylene-Q-CO-C v H 2v -0-; -0-C 2 -C 12 alkylene-0-CH 2 -CH(OH)-CH 2 -0-; Q-interrupted Q-C 4 -Cι 2 alkylene-Q; Q-phenylene-Q or Q-phenylene-D-phenylene-Q with D being d-C alkylene, O, S, SO or S0 2 ; L, as a trivalent group, is Q-capped C 3 -C 12 alkanetriyl, a trivalent residue of a hexose or a hexitol, or a group (-0-CH 2 ) 3 C-CH 2 OH; -Q-C a H 2a -N(C b H 2b -Q-)-C c H 2c -Q-; -Q-C 3 -d 2 alkanethyl(-Q-CO-C v H 2v -0-) 2 ; -O-C3-C 12 alkanethyl(-O-CH 2 -CH(OH)-CH 2 -O-) 2 ; and L, as a tetravalent group, is a tetravalent residue of a hexose or a hexitol; -Q-C 4 -C 12 alkanetetryl(-Q-CO-C v H 2v -O-) 3 ; -O-C 4 -C 12 alkanetetryl(-O-CH 2 -CH(OH)-CH 2 -O-) 3 ; Q-capped C 4 -Cι 2 alkanetetryl; a group -ex H 2 H 2 H 2 H 2 "CH, .. / C-. H^C^ / C^H / C^ or a group 0 C O C O O . .0 — o o- Q is oxygen or -NH-, Z is a linking group of valency (k+1) and is as a divalent group C 2 -Cι 2 alkylene, Q-interrupted d-Cι 2 alkylene, phenylene or phenylene-D-phenylene with D being C C 4 alkylene, O, S, SO or SO 2 ; Z, as a trivalent group, is C 3 -d 2 alkanetriyl, a trivalent residue of a hexose or a hexitol, a group (-CH 2 ) 3 C-CH 2 OH, or a group -C a H 2 a-N(CbH 2b -)-C c H 2 o-; and Z, as a tetravalent group, is a tetravalent residue of a hexose or a hexitol, C -Cι 2 alkanetetryl, a group ; a, b, c and k independently are 1 , 2 or 3, m is 0 or a number from the range 1 -12, s is 1 or 2, and t is a number from the range 3-12, v is 1 , 2, 3, 4, 5, 6, 7 or 8; and all other residues are as defined in claim 1 for formula I if n is 1. 15. Process for stabilizing an organic material against deterioration by light, oxygen and/or heat, which process comprises incorporating a compound of the formula V and/or VI according to claim 14 as stabilizer into said organic material. 16. Use of a compound of the formula V and/or VI according to claim 14 as stabilizer for organic material against deterioration by light, oxygen and/or heat.

Inventors: BIRY STEPHANE, JEGANATHAN SURULIAPPA GOWPER, LEPPARD DAVID GEORGE, NESVADBA PETER, BIRY, STEPHANE, JEGANATHAN, SURULIAPPA, GOWPER, LEPPARD, DAVID, GEORGE, NESVADBA, PETER
Applicants: BIRY STEPHANE, CIBA SC HOLDING AG, JEGANATHAN SURULIAPPA GOWPER, LEPPARD DAVID GEORGE, NESVADBA PETER, BIRY, STEPHANE, CIBA SPECIALTY CHEMICALS HOLDING INC., JEGANATHAN, SURULIAPPA, GOWPER, LEPPARD, DAVID, GEORGE, NESVADBA, PETER
Application year: 1999
Main classification: G03C7
IPC codes: C07D307, C08K5, G03C7