Thermally stable alpha-substituted acrylate graft copolymers of propylene

Abstract: The thermal stability of alpha-substituted acrylate graft copolymers can be improved by (a) making a graft copolymer comprising a backbone of a propylene polymer material having graft polymerized thereto monomers comprising (i) a 1-3 C alkyl-substituted acrylic acid and (ii) an ester of a 1-3 C alkyl-substituted acrylic acid, wherein the total amount of polymerized monomers is about 20 to about 240 parts per hundred parts of the propylene polymer material and the amount of (i) is about 1 to about 20%, based on the total weight of monomers, and (b) removing any unreacted grafting monomer from the resulting grafted propylene polymer material, decomposing any unreacted initiator, and deactivating any residual free radicals in the material.

Description: Field of the Invention This invention relates to a process for making graft copolymers of a propylene polymer and a polymerizable α-substituted acrylate monomer. Background of the Invention Polymers of α-substituted monomers such as methacrylates, methacrylonitriles, and α-methylstyrene are thermally unstable and are known to depolymerize to their corresponding monomers at temperatures greater than 230°C. Above 300°C, poly(methyl methacrylate) (PMMA) depolymerizes rapidly at high conversions (>95%). Typical extruding and molding temperatures for such polymers are 200°-290°C. Significant depolymerization to the respective monomers would occur in this temperature range, affecting the safety of the operation as well as the properties of the product. Polymethacrylates, and in particular PMMA, are the α-substituted polymers most widely used in commercial applications. In order to broaden the range of applications for these polymers it is critical to improve their thermal stability. In the manufacture of graft copolymers comprising a backbone of a propylene polymer material, to which is grafted poly(methyl methacrylate), small amounts of nonmethacrylate monomers such as methyl acrylate, butyl acrylate and styrene are typically copolymerized with the methyl methacrylate to improve thermal stability, since polymers of these monomers are much more stable to heat and undergo degradation at relatively higher temperatures. However, addition of these monomers affects the mechanical properties of the graft copolymers as well as the molecular weight and grafting efficiency. As reported by Nishimoto et al., Polymer, 32, 1275 (1991), methacrylate monomers have been used with methyl methacrylate to improve compatibility with other functional polymers such as polycarbonates, but the authors concluded that they did not improve thermal stability. EP 420615 discloses graft copolymer impact modifiers comprising a polymer trunk derived from ethylene and propylene in a unit ratio from 35:65 to 70:30 with predominantly methacrylate ester side chains grafted thereon. Quite a lot of other monomer units including methacrylic acid can be incorporated with the methacrylate ester. While being recognized as effective impact resistance improvers, said graft copolymers are not considered at all as far as the improvement of the thermal resistance. EP 560496 describes graft copolymers comprising segments of a polyolefin and segments of a polymer derived from a substituted methacrylate ester and an acrylic or styrenic monomer copolymerized therewith. Said graft copolymers are said to be useful in improving the processing properties of polar polymers when admixed at levels of 1-15%, but no information about the thermal resistance of the graft copolymers is given. Thus there is a need for a method to increase the thermal stability of graft copolymers that include polymerized α-substituted acrylates compared with that achievable with the nonmethacrylate comonomers currently used for this purpose. Summary of the Invention The process of this invention for making thermally stable α-substituted acrylate graft copolymers of a propylene polymer comprises: (a) making a graft copolymer comprising a backbone of a propylene polymer having graft polymerized thereto monomers comprising (i) a C 1 -C 3 alkyl-substituted acrylic acid and (ii) an ester of a C 1 -C 3 alkyl-substituted acrylic acid, wherein the total amount of polymerized monomers is 20 to 240 parts per hundred parts of the propylene polymer and the amount of (i) is 1% to 20%, based on the total weight of the monomers, and (b) removing any unreacted grafting monomer from the resulting grafted propylene polymer, decomposing any unreacted initiator, and deactivating any residual free radicals in the grafted material. Copolymerization of a small amount of a C 1 -C 3 alkyl-substituted acrylic acid with the α-substituted acrylate during the preparation of graft copolymers of propylene polymers significantly increases the thermal stability of the graft copolymer. The room temperature mechanical properties and molecular weight of the graft copolymer, and the grafting efficiency are not adversely affected. Brief Description of the Drawings Figure 1 is plot of temperature (°C) against the % of the original weight of the sample and shows the weight loss during thermogravimetric analysis and therefore the thermal stability of graft copolymers comprising a backbone of propylene homopolymer, to which was grafted poly(methyl methacrylate), a methyl methacrylate/methyl acrylate (MeAc) copolymer, and methyl methacrylate/methacrylic acid (MAA) copolymers containing varying amounts of methacrylic acid. Figure 2 is a plot of temperature (°C) against the % of the original weight of the sample and shows the weight loss during thermogravimetric analysis and therefore the thermal stability of graft copolymers comprising a backbone of propylene homopolymer to which was grafted poly(methyl methacrylate), a methyl methacrylate/methacrylic acid (MAA) copolymer, a methyl methacrylate/methyl acrylate (MeAc) copolymer, and methyl methacrylate/acrylic acid (AA) copolymers containing varying amounts of acrylic acid. In both figures, sufficient broad molecular weight distribution polypropylene was added to the graft copolymers to adjust the effective add level to 50 parts of polymerized monomers per 100 parts of polypropylene. Detailed Description of the Invention The first step in the process of this invention for making thermally stable α-substituted acrylate graft copolymers is making a graft copolymer comprising a backbone of a propylene polymer having graft polymerized thereto monomers comprising (i) a C 1 -C 3 alkyl-substituted-acrylic acid and (ii) an ester of a C 1 -C 3 alkyl-substituted acrylic acid. The propylene polymer that is used as the backbone of the graft copolymer can be: (a) a crystalline homopolymer of propylene having an isotactic index greater than 80, preferably 85 to 99; (b) ) a crystalline copolymer of propylene and an olefin selected from the group consisting of ethylene and C 4 -C 10 α-olefins, provided that when the olefin is ethylene, the maximum polymerized ethylene content is 10% by weight, preferably 4%, and when the olefin is a C 4 -C 10 α-olefin, the maximum polymerized content thereof is 20%, preferably 16%, by weight, the copolymer having an isotactic index greater than 85; (c) a crystalline terpolymer of propylene and two olefins selected from the group consisting of ethylene and C 4 -C 8 α-olefins, provided that the maximum polymerized C 4 -C 8 α-olefin content is 20% by weight, preferably 16%, and, when ethylene is one of the olefins, the maximum polymerized ethylene content is 5% by weight, preferably 4%, the terpolymer having an isotactic index greater than 85; (d) an olefin polymer composition comprising: (i) 10% to 60% by weight, preferably 15% to 55%, of a crystalline propylene homopolymer having an isotactic index greater than 80, preferably 85 to 98, or a crystalline copolymer selected from the group consisting of (a) propylene and ethylene, (b) propylene, ethylene and a C 1 -C 4 α-olefin, and (c) propylene and a C 4 -C 8 α-olefin, the copolymer having a propylene content of more than 85% by weight, preferably 90% to 99%, and an isotactic index greater than 85; (ii) 5% to 25%, preferably 5% to 20%, of a copolymer of ethylene and propylene or a C 4 -C 8 α-olefin that is insoluble in xylene at 25°C, and (iii) 30% to 70%, preferably 20% to 65%, of an elastomeric copolymer selected from the group consisting of (a) ethylene and propylene, (b) ethylene, propylene, and a C 4 -C 8 α-olefin, and (c) ethylene and a C 4 -C 8 α-olefin, the copolymer optionally containing 0.5% to 10% of a diene, and containing less than 70% by weight, preferably 10% to 60%, most preferably 12% to 55%, of ethylene and being soluble in xylene at 25°C, and having an intrinsic viscosity of 1.5 to 4.0 dl/g, wherein the total amount of (ii) and (iii), based on the total olefin polymer composition, is 50% to 90%, the weight ratio of (ii)/(iii) is less than 0.4, preferably 0.1 to 0.3, and the composition is obtainable by polymerization in at least two stages, and has a flexural modulus of less than 150 MPa; or (e) a thermoplastic olefin composition comprising: (i) 10% to 60%, preferably 20% to 50%, of a crystalline propylene homopolymer having an isotactic index greater than 80, or a crystalline copolymer selected from the group consisting of (a) ethylene and propylene, (b) ethylene, propylene, and a C 4 -C 8 α-olefin, and (c) ethylene and a C 4 -C 8 α-olefin, the copolymer having a propylene content greater than 85% and an isotactic index of greater than 85; (ii) 20% to 60%, preferably 30% to 50%, of an amorphous copolymer selected from the group consisting of (a) ethylene and propylene, (b) ethylene, propylene, and a C 4 -C 8 α-olefin, and (c) ethylene and a C 4 -C 8 α-olefin, the copolymer optionally containing 0.5% to 10% of a diene and containing less than 70% ethylene and being soluble in xylene at 25°C; and (iii) 3% to 40%, preferably 10% to 20%, of a copolymer of ethylene and propylene or a C 4 -C 8 α-olefin that is insoluble in xylene at 25°C, wherein the composition has a flexural modulus of greater than 150 but less than 1200 MPa, preferably 200 to 1100 MPa, most preferably 200 to 1000 MPa. Room or ambient temperature is 25°C. C 4 -C 8 α-olefins useful in the preparation of (d) and (e) include, for example, butene-1; pentene-1; hexene-1; 4-methylpentene-1, and octene-1. The diene, when present, is typically a butadiene; 1,4-hexadiene; 1,5-hexadiene, or ethylidenenorbornene. Propylene polymer materials (d) and (e) can be prepared by polymerization in at least two stages, where in the first stage the propylene; propylene and ethylene; propylene and an α-olefin, or propylene, ethylene and an α-olefin are polymerized to form component (i) of (d) or (e), and in the following stages the mixtures of ethylene and propylene; ethylene and the α-olefin, or ethylene, propylene and the α-olefin, and optionally a diene, are polymerized to form components (ii) and (iii) of (d) or (e). The polymerization can be conducted in liquid phase, gas phase, or liquid-gas phase using separate reactors, all of which can be done either by batch or continuously. For example, it is possible to carry out the polymerization of component (i) using liquid propylene as a diluent, and the polymerization of components (ii) and (iii) in gas phase, without intermediate stages except for the partial degassing of the propylene. All gas phase is the preferred method. The preparation of propylene polymer material (d) is described in more detail in U.S. Patents 5,212,246 and 5,409,992. The preparation of propylene polymer material (e) is described in more detail in U.S. Patents 5,302,454 and 5,409,992. Propylene homopolymer is the preferred propylene polymer backbone. One of the monomers that is graft polymerized onto the backbone of propylene polymer is a C 1 -C 3 alkyl-substituted acrylic acid. Methacrylic acid is the preferred substituted acrylic acid. The amount of substituted acrylic acid is 1% to 20%, preferably 1% to 10%, and most preferably 1% to 5%, based on the total weight of the monomers. Acrylic acid is not effective at similar concentrations (see Figure 2). The other monomer that is graft polymerized onto the backbone of propylene polymer is an ester of a C 1 -C 3 alkyl-substituted acrylic acid. Methacrylic acid is the preferred substituted acrylic acid. Suitable esters include, for example, the methyl, ethyl, butyl, benzyl, phenylethyl, phenoxyethyl, epoxypropyl, and hydroxypropyl esters. Esters of C 1 -C 4 alkanols are preferred. Methyl methacrylate is most preferred. The total amount of polymerizable monomers is 20 to 240 parts, preferably 30 to 95 parts, per hundred parts of the propylene polymer. The graft copolymer can be made according to any one of various methods. One of these methods involves forming active grafting sites on the propylene polymer by treatment with a peroxide or other chemical compound that is a free radical polymerization initiator, or by irradiation with high energy ionizing radiation. The free radicals produced in the polymer as a result of the chemical or irradiation treatment form active grafting sites on the polymer and initiate the polymerization of the monomers at these sites. Graft copolymers produced by peroxide-initiated grafting methods are preferred. During the graft polymerization, the monomers also polymerize to form a certain amount of free or ungrafted polymer or copolymer. The morphology of the graft copolymer is such that the propylene polymer is the continuous or matrix phase, and the polymerized monomers, both grafted and ungrafted, are a dispersed phase. The last step of the process of this invention is removing any unreacted grafting monomer from the resulting grafted propylene polymer, decomposing any unreacted initiator, and deactivating any residual free radicals in the grafted material. Preparation of graft copolymers by contacting the propylene polymer with a free radical polymerization initiator such as an organic peroxide and a vinyl monomer is described in more detail in U.S. 5,140,074. Preparation of graft copolymers by irradiating an olefin polymer and then treating with a vinyl monomer is described in more detail in U.S. 5,411,994. The graft copolymers of this invention can easily be impact-modified by the addition of one or more rubber components selected from the group consisting of (i) an olefin copolymer rubber, (ii) a monoalkenyl aromatic hydrocarbon-conjugated diene block copolymer, and (iii) a core-shell rubber. Any of these rubber components can have acid or anhydride functionality or can be free of these functional groups. The preferred rubber components are (i) and (ii), either alone or in combination. Preferably a composition comprises the graft copolymer obtainable from process of the invention with the features defined in the subject-matter of claims 10 to 13. Suitable olefin copolymer rubbers include, for example, saturated olefin copolymer rubbers such as ethylene/propylene monomer rubbers (EPM), ethylene/octene-1, and ethylene/butene- 1 rubbers, and unsaturated olefin terpolymer rubbers such as ethylene/propylene/diene monomer rubbers (EPDM). The preferred olefin copolymer rubbers are ethylene/propylene, ethylene/butene-1, and ethylene/octene-1 copolymers. The monoalkenyl aromatic hydrocarbon-conjugated diene block copolymer can be a thermoplastic elastomer of the A-B (or diblock) structure, the linear A-B-A (or triblock) structure, the radial (A-B) n type where n = 3-20, or a combination of these structure types, wherein each A block is a monoalkenyl aromatic hydrocarbon polymer block, and each B block is an unsaturated rubber block. Various grades of copolymers of this type are commercially available. The grades differ in structure, molecular weight of the mid and end blocks, and ratio of monoalkenyl aromatic hydrocarbon to rubber. The block copolymer can also be hydrogenated. Typical monoalkenyl aromatic hydrocarbon monomers are styrene, ring-substituted C 1 -C 4 linear or branched alkyl styrenes, and vinyltoluene. Styrene is preferred. Suitable conjugated dienes include, for example, butadiene and isoprene. Preferred block copolymers are hydrogenated styrene/ethylene-butene/styrene triblock copolymers. The weight average molecular weight M w of the block copolymers generally will be in the range of 45,000 to 260,000 g/mole, average molecular weights in the range of 50,000 to 125,000 g/mole being preferred because they produce compositions having the best balance of impact strength and stiffness. Also, while block copolymers having unsaturated as well as saturated rubber blocks can be used, copolymers having saturated rubber blocks are preferred, also on the basis of the impact/stiffness balance of the compositions containing them. The weight ratio of monoalkenyl aromatic hydrocarbon to conjugated diene rubber in the block copolymer is in the range of 5/95 to 50/50, preferably 10/90 to 40/60. The core-shell rubber components comprise small particles of crosslinked rubber phase surrounded by a compatibilizing shell, normally a glassy polymer or copolymer. The core is typically a diene rubber such as butadiene or isoprene, or an acrylate. The shell is typically a polymer of two or more monomers selected from styrene, methyl methacrylate, and acrylonitrile. Particularly preferred core-shell rubbers have an acrylate core. Suitable impact modifiers include, for example, Engage™ 8100, 8150, and 8200 ethylene/octene-1 copolymers, commercially available from DuPont Dow Elastomers; EPM 306P random ethylene/propylene copolymer, commercially available from Miles Inc., Polysar Rubber Division; Kraton™ G 1652 styrene/ethylene-butene/styrene triblock copolymer, commercially available from Shell Chemical Company; Exact™ ethylene/butene-1 copolymers, commercially available from Exxon Chemical Company, and KS080 and KS350 heterophasic polyolefins, commercially available from Montell USA Inc. The impact modifier, if present, is used in an amount of 2% to 30%, preferably 5% to 15%, by weight, based on the total weight of the composition. The composition can also contain a broad molecular weight distribution (M w /M n ) propylene polymer material (BMWD PP). The BMWD PP has a M w /M n of 5 to 60, preferably 5 to 40; a melt flow rate of 0.5 to 50, preferably 1 to 30 g/10 min, and xylene insolubles at 25°C of greater than or equal to 94%, preferably greater than or equal to 96%, and most preferably greater than or equal to 98%. The propylene polymer material having a broad molecular weight distribution can be a homopolymer of propylene or an ethylene/propylene rubber impact-modified homopolymer of propylene, wherein the propylene homopolymer has a broad molecular weight distribution. The BMWD PP can be prepared by sequential polymerization in at least two stages, in the presence of a Ziegler-Natta catalyst supported on magnesium halide in active form. The polymerization process occurs in separate and consecutive stages, and in each stage polymerization takes place in the presence of the polymer and the catalyst coming from the preceding stage. The polymerization process can be carried out in a batch or in a continuous mode according to known techniques, operating in liquid phase in the presence or not of an inert diluent, or in gas phase, or liquid-gas phase, preferably in gas phase. The preparation of the BMWD PP is described in more detail in U.S. Patent 5,286,791. . The BMWD PP, if present, is used in an amount of 5% to 90%, preferably 10% to 70%, based on the total weight of the composition. Other additives such as fillers and reinforcing agents, e.g., carbon black and glass fibers, as well as inorganic powders such as calcium carbonate, talc, and mica; pigments; slip agents; waxes; oils; antiblocking agents, and antioxidants can also be present. The test methods used to evaluate the molded specimens were: Izod impact ASTM D-256A Tensile strength ASTM D-638-89 Flexural modulus ASTM D-790-86 Flexural strength ASTM D-790-86 Elongation to yield ASTM D-638-89 Elongation to break ASTM D-638-89 Weldline strength ASTM D-638-89 Retained weldline strength Determined by dividing the weldline strength by the tensile strength and multiplying by 100. Heat distortion temperature ASTM D-648 Melt flow rate, 230°C, 3.8 kg ASTM 1238 The porosity of the propylene homopolymer used as the backbone polymer in the manufacture of the graft copolymers is measured as described in Winslow, N. M. and Shapiro, J. J., "An Instrument for the Measurement of Pore-Size Distribution by Mercury Penetration," ASTM Bull., TP 49, 39-44 (Feb. 1959), and Rootare, H. M., "Review of Mercury Porosimetry," 225-252 (In Hirshhom, J. S. and Roll, K. H., Eds., Advanced Experimental Techniques in Powder Metallurgy , Plenum Press, New York, 1970). In this specification, all parts and percentages are by weight unless otherwise noted. Example 1 This example demonstrates the thermal stability of a graft copolymer comprising a propylene homopolymer backbone, to which was grafted methyl methacrylate/methacrylic acid copolymers (MMA/MAA) with varying amounts of methacrylic acid. The results were compared with the thermal stability of a graft copolymer comprising a propylene homopolymer backbone to which was grafted poly(methyl methacrylate) or a methyl methacrylate/methyl acrylate copolymer (MMA/MeAc). In this and the following examples the propylene homopolymer used as the backbone polymer had the following properties: spherical form, melt flow rate (MFR) of 9 g/10 min, a porosity of 0.45 cm 3 /g and a weight average molecular weight (M w ) of 170,000. The monomers were grafted onto the polypropylene backbone at a grafting temperature of 115°C using the previously described peroxide-initiated graft polymerization process. Ninety-five parts by weight of monomers were added per 100 parts of polypropylene. Lupersol™ PMS 50% t-butyl peroxy-2-ethyl hexanoate in mineral spirits, commercially available from Elf Atochem, was used as the peroxide initiator. The monomers were fed at a rate of 1 pph/min. A monomer to initiator molar ratio of 120 was used. After the grafting reaction was complete the temperature was raised to 140°C for 2 hours under a nitrogen purge. The % conversion of monomer to polymer was 97.2 - 97.7 for the MMA/MAA copolymers and 99.7 for the MMA/MeAc copolymer The graft copolymer (68.4 wt. %) was then blended with 31.6 wt. % of a broad molecular weight distribution polypropylene (BMWD PP) having a polydispersity index of 7.4, a MFR of 1 g/10 min, and xylene solubles at 25°C of 1.5%, commercially available from Montell USA Inc. The BMWD PP was added to adjust the effective add level to 50 parts of polymerized monomer(s) per hundred parts of polypropylene. The samples were compounded on a 34 mm co-rotating, intermeshing Leistritz LSM twin screw extruder. Each sample was extruded as pellets at a barrel temperature of 210°C, a screw speed of 300 rpm, and a throughput rate of 9.06 kg/hr (20 lb/hr). The stabilizer package used was 0.1 wt. % calcium stearate and 0.25 wt. % Irganox™ B215 antioxidant. Irganox™ B 215 antioxidant is a mixture of 1 part Irganox™ 1010 tetrakis[methylene(3,5-di-t-butyl-4-hydroxyhydrocinnamate)]methane antioxidant, and 2 parts Irgafos 168 tris(2,4-di-t-butylphenyl) phosphite antioxidant, both commercially available from CIBA Specialty Chemicals Corporation. The thermal stability of the pelletized samples was assessed by thermogravimetric analysis (TGA) using a Perkin-Elmer TGA-7 analyzer. 10 mg of sample were scanned at 10°C/min in nitrogen from 30°C to 900°C and the weight loss was monitored. The region of interest lies between 200°C and 350°C, where poly(methyl methacrylate) tends to lose weight by depolymerization. The results are shown in Table 1 and Figure 1. Polymer Composition (Wt.%) Weight Loss at Temperature (°C) 1% 2% 3% 4% 5% 10% MMA (100%) 228 289 305 315 322 346 MMA/MeAc (4.4%) 264 296 309 321 333 360 MMA/MAA (1%) 294 316 331 343 350 371 MMA/MAA (2%) 302 329 342 351 357 375 MMA/MAA (3%) 300 329 346 356 363 381 MMA/MAA (5%) 320 345 356 363 368 383 MMA/MAA (10%) 315 347 360 368 374 NA MMA/MAA (20%) 313 347 363 373 379 NA The data show that the graft copolymers having various levels of methacrylic acid are more stable at a given temperature than the graft copolymers made with 100% MMA or MMA/MeAc (4.4%). Example 2 This example demonstrates the physical properties of a graft copolymer comprising a propylene homopolymer backbone, to which was grafted a methyl methacrylate/methacrylic acid copolymer with varying amounts of methacrylic acid. The results were compared with a control comprising a graft copolymer comprising a propylene homopolymer as the backbone polymer, to which was grafted a MMA/MeAc copolymer containing 4.4% methyl acrylate. The graft copolymers were prepared as described in Example 1. The graft copolymer (38.6 wt. %) was then blended with 42.9 wt. % of the BMWD PP described in Example 1 to adjust the effective add level to 30 pph of polymerized monomers per hundred parts of polypropylene. Engage™ 8150 ethylene/octene elastomer containing 25% octene, commercially available from DuPont-Dow Elastomers (14.55 wt. %), was added to the samples. Ampacet™ 19472 black pigment, commercially available from Ampacet Corporation, was also added in an amount of 2.91 wt. %. The stabilizer package used was 0.05% Pationic™ 1240 modified calcium salt of lactic acid, commercially available from Patco Polymer Additives Division, American Ingredients Company; 0.20% of Irganox™ LC 20 FF stabilizer, a mixture of 1 part Irganox™ 1010 antioxidant and 1 part Irgafos™ 12 stabilizer, which is 2,2',2"-nitrilotriethyl-tris[3,3',5',5'-tetra-t-butyl-1,1'-biphenyl-2,2'-diyl] phosphite, both commercially available from CIBA Specialty Chemicals Corporation; 0.30% Tinuvin™ 328 2-(2-hydroxy-3,5-di-t-amylphenyl)-2H-benzotriazole antioxidant, commercially available from CIBA Specialty Chemicals Corporation; 0.24% Tinuvin™ 770 bis(2,2,6,6-tetramethyl-4-piperidinyl) sebacate antioxidant, commercially available from CIBA Specialty Chemicals Corporation, and 0.24% Chimmasorb™ 119 antioxidant, commercially available from CIBA Specialty Chemicals Corporation. The samples were compounded on a 40 mm co-rotating, intermeshing twin screw Werner & Pfleiderer ZSK extruder. Each sample was extruded as pellets at a barrel temperature of 210°C, a screw speed of 490 rpm, and a throughput rate of 77 kg/hr (170 lb/hr). Compounded samples were dried at 80°C for at least 4 hours prior to molding to remove surface moisture. 25.4 mm x 3.2 mm (one inch x 1/8 inch) test bars were used for all of the physical property measurements. Test bars were produced on a 141.75 g (5 oz) Battenfeld injection molding machine at a barrel temperature 232.2°C (450°F) and a mold temperature of 54.4°C (130°F). The results of the property evaluations for each sample are given in Table 2. Sample 1 2 3 4 5 6 Control MMA/MAA (1%) (wt. %) 38.6 MMA/MAA (2%) (wt. %) 38.6 MMA/MAA (3%) (wt. %) 38.6 MMA/MAA (5%) (wt. %) 38.6 MMA/MAA (10%) (wt.%) 38.6 MMA/MAA (20%) (wt.%) 38.6 MMA/MeAc (4.4%) (wt.%) 38.6 BMWD PP (wt. %) 42.9 42.9 42.9 42.9 42.9 42.9 42.9 Engage 8150 (wt. %) 14.55 14.55 14.55 14.55 14.55 14.55 14.55 Pationic 1240 (wt. %) 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Irganox LC 20 FF (wt. %) 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Tinuvin 328 (wt. %) 0.30 0.30 0.30 0.30 0.30 0.30 0.30 Tinuvin 770 (wt. %) 0.24 0.24 0.24 0.24 0.24 0.24 0.24 Chimmasorb 119 (wt. %) 0.24 0.24 0.24 0.24 0.24 0.24 0.24 Black pigment (wt. %) 2.91 2.91 2.91 2.91 2.91 2.91 2.91 Izod impact (J/m) 736.6 693.9 677.9 731.3 715.2 464.6 704.6 (ft.lb/in) (13.8) (13) (12.7) (13.7) (13.4) (8.7) (13.2) Tensile strength (MPa) 30.1 30.5 30.0 30.6 29.8 29.8 30.0 (psi) (4371) (4427) (4354) (4435) (4328) (4320) (4360) Elongation to yield (%) 6.12 5.9 5.9 5.7 5.7 5.6 6.23 Elongation to break w/extensometer (%) 173 179 185 85 134 187 168 Weldline strength (MPa) 23.8 24.0 23.2 24.0 23.6 24.2 22.8 (psi) (3456) (3482) (3369) (3484) (3417) (3515) (3310) Elongation to break at weldline (%) 5.5 5.5 5 5.4 5.5 6.1 4.9 Retained strength (%) 79.1 78.7 77.4 78.6 79.0 81.4 75.9 Flexural modulus at 1.27 mm/min (MPa) 1474 1498 1480 1535 1498 1475 1480 (at 0.05"/min kpsi) (213.8) (217.2) (214.6) (222.6) (217.2) (213.9) (214.7) Flexural strength at 1.27 mm/min (MPa) 41.4 42.2 41.9 43.7 42.7 42.1 41.8 (at 0.05"/min (psi) (6012) (6117) (6077) (6345) (6191) (6108) (6067) H.D.T. at 455 KPa 3.2 mm (66 psi 1/8") (°C) 97.6 98.2 98.2 99.4 102 102 92.1 H.D.T. at 1820 KPa 3.2 mm (264 psi 1/8") (°C) 59 59.4 59.9 60.3 59.9 59.6 59.2 Melt flow rate at 3.8 kg, 230°C (g/10min) 6.4 6.4 6.2 5 5.2 5.8 10.2 The data show that all of the graft copolymers containing methacrylic acid as one of the grafting monomers exhibited properties similar to those of the control. Example 3 This example shows the effect of using methacrylic acid as one of the grafting monomers on the molecular properties and grafting efficiency of a graft copolymer comprising a backbone of propylene homopolymer to which was grafted a methyl methacrylate/methacrylic acid copolymer. The results were compared to the properties of a graft copolymer comprising a backbone of propylene homopolymer, to which was grafted poly(methyl methacrylate) or a MMA/MeAc (4.4%) copolymer. The graft copolymers were prepared as described in Example 1. Weight and number average molecular weights, soluble MMA copolymer (XSRT) and grafting efficiency were measured using a Bio-Rad FTS-7 infrared spectrometer and a Perkin-Elmer room temperature gel permeation chromatography (GPC) assembly with a refractive index detector and a tetrahydrofuran mobile phase. It was found that MMA/MAA copolymer grafts were only sparingly soluble in xylene, the solvent normally used for the XSRT measurements, even when only 1% MAA was present in the poly(methyl methacrylate). Cycloheptanone was therefore chosen as the solvent. The total amount of monomers, which is needed for the grafting efficiency calculation, was measured by Fourier transform infrared analysis, assuming the polymer to be 100% poly(methyl methacrylate). This assumption was expected to incur minimal error for copolymers containing less than 5% MAA. The results are given in Table 3. In Table 3, total pph refers to the total amount of monomers per hundred parts of the propylene homopolymer. M w and M n are the weight average and number average molecular weights, respectively, of the polymerized monomers that are not grafted to the polypropylene backbone. MAA in MMA/MAA (wt. %) Total pph M w (10 3 ) M n (10 3 ) XSRT (wt. %) Grafting Efficiency (%) 0 41.8 264 113 22.9 22.3 1 46.1 239 104 24.0 24.5 2 45.6 239 103 21.7 30.7 3 45.0 227 107 21.0 32.3 5 42.4 225 80 22.5 24.4 MMA/MeAc (4.4%) 50.1 124 48 28.5 14.5 The data show that addition of MAA does not affect the molecular weight of the ungrafted polymerized monomers, or the grafting efficiency to the same extent that methyl acrylate does. Higher values for molecular weight and grafting efficiency are preferred.

Claims: A process for making thermally stable α-substituted acrylate graft copolymers of propylene comprising: (a) making a graft copolymer comprising a backbone of a propylene polymer having graft polymerized thereto monomers comprising (i) a C 1 -C 3 alkyl-substituted acrylic acid and (ii) an ester of a C 1 -C 3 alkyl-substituted acrylic acid, wherein the total amount of polymerized monomers is 20 to 240 parts per hundred parts of the propylene polymer and the amount of (i) is 1% to 20%, based on the total weight of the monomers, and (b) removing any unreacted grafting monomer from the grafted propylene polymer, decomposing any unreacted initiator, and deactivating any residual free radicals. The process of claim 1 wherein the propylene polymer is a crystalline homopolymer of propylene having an isotactic index greater than 80. The process of claim 1 wherein the propylene polymer is a crystalline copolymer of propylene and an olefin selected from the group consisting of ethylene and C 4 -C 10 α-olefins, provided that when the olefin is ethylene, the maximum polymerized ethylene content is 10% by weight, and when the olefin is a C 4 -C 10 α-olefin, the maximum polymerized content thereof is 20% by weight, the copolymer having an isotactic index greater than 85; The process of claim 1 wherein the propylene polymer is a crystalline terpolymer of propylene and two olefins selected from the group consisting of ethylene and C 4 -C 8 α-olefins, provided that the maximum polymerized C 4 -C 8 α-olefin content is 20% by weight, and, when ethylene is one of the olefins, the maximum polymerized ethylene content is 5% by weight, the terpolymer having an isotactic index greater than 85; The process of claim 1 wherein the propylene polymer is a propylene homopolymer. The process of claim 1 wherein the C 1 -C 3 alkyl-substituted acrylic acid in (i) and (ii) is methacrylic acid. The process of claim 6 wherein the ester of the methacrylic acid is a methacrylate of a C 1 -C 4 alkanol. The process of claim 7 wherein the ester is methyl methacrylate. The process of claim 1 wherein the amount of (a)(i) is 1% to 5%, based on the total weight of the monomers. A composition comprising the product obtainable with the process of claim 1 and 2% to 30%, based on the total weight of the composition, of one or more rubber components selected from the group consisting of (a) an olefin copolymer rubber, (b) a monoalkenyl aromatic hydrocarbon-conjugated diene block copolymer, and (c) a core-shell rubber. The composition of claim 10 which further comprises 5% to 90%, based on the total weight of the composition, of a broad molecular weight distribution propylene polymer material having a M w /M n of 5 to 60, a melt flow rate of 0.5 to 50 g/10 min and xylene insolubles at 25°C of greater than or equal to 94%. A composition comprising the product obtainable with the process of claim 8 and 2% to 30%, based on the total weight of the composition, of one or more rubber components selected from the group consisting of (a) an olefin copolymer rubber, (b) a monoalkenyl aromatic hydrocarbon-conjugated diene block copolymer, and (c) a core-shell rubber. The composition of claim 12 that further comprises 5 % to 90%, based on the total weight of the composition, of a broad molecular weight distribution propylene polymer material having a M w /M n of 5 to 60, a melt flow rate of 0.5 to 50 g/10 min and xylene insolubles at 25°C of greater than or equal to 94%.

Inventors: SYED ABUZAR, SYED, ABUZAR
Applicants: BASELL POLIOLEFINE SPA, BASELL POLIOLEFINE ITALIA S.P.A.
Application year: 1999
Main classification: C08F255
IPC codes: C08F6, C08F2, C08F255, C08L51