Allyloxymethylated polyamide synthesis, compositions and devices

Abstract: This invention relates in general to allyloxymethylatedpolyamide, and, more specifically, to allyloxymethylatedpolyamide compositions, processes for synthesizing allyloxymethylatedpolyamide, and devices containing allyloxymethylatedpolyamide.

Description: BACKGROUND OF THE INVENTION This invention relates in general to allyloxymethylatedpolyamide, and, more specifically, to allyloxymethylatedpolyamide- compositions, processes for synthesizing allyloxymethylatedpolyamide, and devices containing allyloxymethylatedpolyamide. Tough cross linked materials are highly desirable for long life articles and coatings. For some applications, the need for an acid to cross link polymers such as polyamides led to defective products having undesirable physical and electrical properties. For example, cross linking of Luckamide polyamides through acid catalyzed condensation of methoxymethyl groups attached to a polyamide backbone unavoidably produced a low molecular weight molecule which may be trapped in the bulk and sometimes give rise to a bubble defect upon thermal expansion. Moreover, improvements were desirable in mechanical strength and abrasion resistance when exposed to alcohol, hydrocarbons and other solvents. Electrophotographic imaging members, i.e. photoreceptors, typically include a photoconductive layer formed on an electrically conductive substrate. The photoconductive layer is an insulator in the dark so that electric charges are retained on its surface. Upon exposure to light, the charge is dissipated. Many advanced imaging systems are based on the use of small diameter photoreceptor drums. The use of small diameter drums places a premium on photoreceptor life. A major factor limiting photoreceptor life in copiers and printers, is wear. The use of small diameter drum photoreceptors exacerbates the wear problem because, for example, 3 to 10 revolutions are required to image a single letter size page. Multiple revolutions of a small diameter drum photoreceptor to reproduce a single letter size page can require up to 1 million cycles from the photoreceptor drum to obtain 100,000 prints, a desirable goal for commercial systems. For low volume copiers and printers, bias charging rolls (BCR) are desirable because little or no ozone is produced during image cycling. However, the micro corona generated by the BCR during charging, damages the photoreceptor, resulting in rapid wear of the imaging surface, e.g., the exposed surface of the charge transport layer. For example wear rates can be as high as about 16µ per 100,000 imaging cycles. Similar problems are encountered with bias transfer roll (BTR) systems. One approach to achieving longer photoreceptor drum life is to form a protective overcoat on the imaging surface, e.g. the charge transporting layer of a photoreceptor. This overcoat layer must satisfy many requirements, including transporting holes, resisting image deletion, resisting wear, avoidance of perturbation of underlying layers during coating. Although various hole transporting small molecules can be used in overcoating layers, one of the toughest overcoatings discovered comprises cross linked polyamide (e.g. Luckamide) containing N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (DHTBD). This tough overcoat is described in US-A 5,368,967, the entire disclosure thereof being incorporated herein by reference. Since N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (DHTBD) is sensitive to the oxidative species produced by the various charging devices, a chemical stabilizer is desirable for longer imaging member cycling life. An improved overcoating has been achieved with cross linked polyamide (e.g., Luckamide) and N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (DHTBD) and bis-[2-methyl-4-(N-2-hydroxyethyl-N-ethyl-aminophenyl)]-phenylmethane (DHTPM) as an image deletion stabilizer material. Although excellent overcoatings have been achieved with bis-[2-methyl-4-(N-2-hydroxyethyl-N-ethyl-aminophenyl)]-phenylmethane (DHTPM) as the stabilizer, bis-[2-methyl-4-(N-2-hydroxyethyl-N-ethyl-aminophenyl)]-phenylmethane (DHTPM) is difficult to purify and handle. Moreover, it is expensive, a semi-solid at room temperature and oxidized relatively easily as evidenced by color change of the material during storage. However, since bis-[2-methyl-4-(N-2-hydroxyethyl-N-ethyl-aminophenyl)]-phenylmethane (DHTPM) is soluble in alcohols, the solvents required for forming coatings containing polyamide (e.g. Luckamide), it can be solution coated with a polyamide. Overcoats should be relatively thin due to their relatively poor charge mobilities. Some of the strength of a thin layer depends on how well secured it is to the substrate on which it is coated. This adhesion can be affected by the choice of solvent mixtures used to coat from. Some solvent systems that produce good films and yield formulations with long pot life produce poorly adhered overcoats. Also, during any cross linking process the morphology at the interface with the underlying layer can change in response to the forces produced by the reaction process thereby adversely affecting adhesion. Thus, the overcoating layer has many requirements, including hole transport, deletion resistance, wear resistance to both abrasion and corona, coatabillity without producing adverse effects in previously formed layers, and adhesion to the transport layer. In addition to the properties of the final film, the coating solution must also possess certain other properties. Among these are the necessary solids concentration and solution viscosity to achieve the required overcoating layer thickness and a pot life long enough to achieve maximum economy for the coating process. INFORMATION DISCLOSURE STATEMENT US-A 5,368,967 issued to Schank et al. on November 29, 1994 - An electrophotographic imaging member is disclosed comprising a substrate, a charge generating layer, a charge transport layer, and an overcoat layer comprising a small molecule hole transporting arylamine having at least two hydroxy functional groups, a hydroxy or multihydroxy triphenyl methane and a polyamide film forming binder capable of forming hydrogen bonds with the hydroxy functional groups the hydroxy arylamine and hydroxy or multihydroxy triphenyl methane. This overcoat layer may be fabricated using an alcohol solvent. This electrophotograchic imaging member may be utilized in an electrophotographic imaging process. Specific materials including Elvamide polyamide and N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine and bis-[2-methyl-4-(N-2-hydroxyethyl-N-ethyl-aminophenyl)]-phenylmethane are disclosed in this patent. US-A 4,871,634 to Limburg et al., issued Oct. 3, 1989 - An electrostatographic imaging member is disclosed which contains at least one electrophotoconductive layer, the imaging member comprising a photogenerating material and a hydroxy arylamine compound represented by a certain formula. The hydroxy arylamine compound can be used in an overcoating with the hydroxy arylamine compound bonded to a resin capable of hydrogen bonding such as a polyamide possessing alcohol solubility. US-A 4,297,425 to Pai et al., issued Oct. 27, 1981 - A layered photosensitive member is disclosed comprising a generator layer and a transport layer containing a combination of diamine and triphenyl methane molecules dispersed in a polymeric binder. US-A 4,050,935 to Limburg et al., issued Sep. 27, 1977 - A layered photosensitive member is disclosed comprising a generator layer of trigonal selenium and a transport layer of bis(4-diethylamino-2-methylphenyl) phenylmethane molecularly dispersed in a polymeric binder. US-A 4,457,994 to Pai et al. et al, issued Jul. 3 1984 - A layered photosensitive member is disclosed comprising a generator layer and a transport layer containing a diamine type molecule dispersed in a polymeric binder and an overcoat containing triphenyl methane molecules dispersed in a polymeric binder. US-A 4,281,054 to Horgan et al., issued Jul. 28, 1981 - An imaging member is disclosed comprising a substrate, an injecting contact, or hole injecting electrode overlying the substrate, a charge transport layer comprising an electrically inactive resin containing a dispersed electrically active material, a layer of charge generator material and a layer of insulating organic resin overlying the charge generating material. The charge transport layer can contain triphenylmethane. US-A 5,702,854 to Schank et al., issued December 30, 1998 - An electrophotographic imaging member is disclosed including a supporting substrate coated with at least a charge generating layer, a charge transport layer and an overcoating layer, said overcoating layer comprising a dihydroxy arylamine dissolved or molecularly dispersed in a crosslinked polyamide matrix. The overcoating layer is formed by crosslinking a crosslinkable coating composition including a polyamide containing methoxy methyl groups attached to amide nitrogen atoms, a crosslinking catalyst and a dihydroxy amine, and heating the coating to crosslink the polyamide. The electrophotographic imaging member may be imaged in a process involving uniformly charging the imaging member, exposing the imaging member with activating radiation in image configuration to form an electrostatic latent image, developing the latent image with toner particles to form a toner image, and transferring the toner image to a receiving member. US-A 4,599,286 to Limburg et al., issued Jul. 8, 1982 - An electrophotographic imaging member is disclosed comprising a charge generation layer and a charge transport layer, the transport layer comprising an aromatic amine charge transport molecule in a continuous polymeric binder phase and a chemical stabilizer selected from the group consisting of certain nitrone, isobenzofuran, hydroxyaromatic compounds and mixtures thereof. An electrophotographic imaging process using this member is also described. CROSS REFERENCE TO COPENDING APPLICATIONS US-A Patent Application Serial No. 09/182,606, filed in the names of John F. Yanus et al, entitled "OVERCOATING COMPOSITIONS, OVERCOATED PHOTORECEPTORS, AND METHODS OF FABRICATING AND USING OVERCOATED PHOTORECEPTORS", mailed via Express Mail on October 29, 1998, (Attorney Docket No. D/97676) - An electrophotographic imaging member is disclosed including a supporting substrate coated with at least photoconductive layer, a charge transport layer and an overcoating layer, the overcoating layer including a hydroxy functionalized aromatic diamine and a hydroxy functionalized triarylamine dissolved or molecularly dispersed in a crosslinked polyamide matrix, the crosslinked polyamide prior to crosslinking being selected from the group consisting of materials represented by the following Formulae I and II: wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000, R is an alkylene unit containing from 1 to 10 carbon atoms, between 1 and 99 percent of the R 2 sites are -H, and the remainder of the R 2 sites are -CH 2 -O-CH 3 , and wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000, R 1 and R are independently selected from the group consisting of alkylene units containing from to 10 carbon atoms, and between 1 and 99 percent of the R 3 and R 4 sites are -H, and the remainder of the R 3 and R 4 sites are -CH 2 -O-CH 3 . Coating compositions for an overcoating layer as well as methods of making and using the overcoated photoreceptor are also disclosed. US-A Patent Application Serial No. 09/182,375, filed in the names of Timothy J. Fuller et al., entitled "PHOTORECEPTOR OVERCOATINGS CONTAINING HYDROXY FUNCTIONALIZE AROMATIC DIAMINE, HYDROXY FUNCTIONALIZED TRIARYLAMINE AND CROSSLINKED ACRYLATED POLYAMIDE", mailed via Express Mail on October 29, 1998 (Attorney Docket No. D/98344) - An electrophotographic imaging member including a supporting substrate coated with at least one photoconductive layer, and an overcoating layer, the overcoating layer including a a hydroxy functionalized aromatic diamine and a hydroxy functionalized triarylamine dissolved or molecularly dispersed in a crosslinked acrylated polyamide matrix, the hydroxy functionalized triarylamine being a compound different from the polyhydroxy functionalized aromatic diamine, the crosslinked polyamide prior to crosslinking being selected from the group consisting of materials represented by the following Formulae I and II: wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000, R is an alkylene group containing from 1 to 10 carbon atoms, between 1 and 99 percent of the R 2 sites are wherein X is selected from the group consisting of -H (acrylate), -CH 3 (methacrylate), alkyl and aryl, and the remainder of the R 2 sites are selected from the group consisting of -H, -CH 2 OCH 3 , and -CH 2 OH, and wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000, R and R 1 are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms; between 1 and 99 percent of R 3 and R 4 are independently selected from the group consisting of wherein X is selected from the group consisting of hydrogen, alkyl, aryl and alkylaryl, wherein the alkyl groups contain 1 to 10 carbon atoms and the aryl groups contain 1 to 3 alkyl groups, y is an integer between 1 and 10, and the remainder of the R 3 and R 4 groups are selected from the group consisting of -H, -CH 2 OH, -CH 2 OCH 3 , and -CH 2 OC(O)-C(X)=CH 2 . The overcoating layer is formed by coating. The electrophotographic imaging member may be imaged in a process. US-A Patent Application Serial No. , filed in the names of D. Renfer et al., entitled "IMPROVED STABILIZED OVERCOAT COMPOSITIONS", filed concurrently herewith (Attorney Docket No. D/98713) - An electrophotographic imaging member is disclosed including a substrate, a charge generating layer, a charge transport layer, and an overcoat layer including a hole transporting hydroxy arylamine compound having at least two hydroxy functional groups, bis-(2-methyl-4-diethylaminophenyl)-phenylmethane and a cross linked polyamide film forming binder. A process for forming an overcoated imaging member is also disclosed. The entire disclosures of each of the aforementioned patents and the pending applications are incorporated herein by reference. BRIEF SUMMARY OF THE INVENTION It is, therefore, an object of the present invention to provide an improved electrophotographic imaging member and process for fabricating the member. It is another object of the present invention to provide an improved imaging member containing a stabilizer that is easier to handle. It is still another object of the present invention to provide an improved imaging member containing a stabilizer that is inexpensive. It is yet another object of the present invention to provide an improved imaging member overcoated with a tough overcoating which resists wear. It is another object of the present invention to provide an improved imaging member which contains an alcohol insoluble stabilizer in a cross liked polyamide. It is still another object of the present invention to provide an improved imaging member which can be free of acidic additives. It is another object of the present invention to provide an improved imaging member with improved adhesion to the transport layer. The foregoing objects and others are accomplished in accordance with this invention by providing an allyloxymethylatedpolyamide composition, process for synthesizing the allyloxymethylatedpolyamide, and devices containing the allyloxymethylatedpolyamide. The allyloxymethylatedpolyamide composition of this invention is represented by Formulae I and II: wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000, R is an alkylene unit containing from 1 to 10 carbon atoms, between 1 and 99 percent of the R 2 sites are -H, and the remainder of the R 2 sites is between 25 percent and 99 percent -CH 2 -O-(CH 2 ) w -CH=CH 2 , wherein w is 1, 2 or 3, between 1 and 75 percent of the R 2 sites are -CH 2 -O-R 5 , and R 5 is an alkyl unit containing 1 to 4 carbon atoms, and wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000, R 1 and R are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms, and between 1 and 99 percent of the R 3 and R 4 sites are -H, and between 25 percent and 99 percent of the remainder of the R 3 and R 4 sites are -CH 2 -O-(CH 2 ) w -CH=CH 2 , wherein w is 1, 2 or 3, and between 1 percent and 75 percent of the R 2 sites are -CH 2 -O-R 5 wherein R 5 is an alkyl unit containing 1 to 4 carbon atoms. For R and R 1 in Formula II, optimum results are achieved when about 40 percent of the total number of alkylene units in R and R 1 contain less than 6 carbon atoms The allyloxymethylatedpolyamide of this invention may be synthesized by reacting an alcohol soluble polyamide with formaldehyde and a linear double bond terminated alcohol. The allyloxymethylatedpolyamide of this invention may be cross linked by a process selected from the group consisting of (a) heating an allyloxymethylatedpolyamide in the presence of a free radical catalyst, and (b) hydrosilating a double bond of an allyloxy group of an allyloxymethylatedpolyamide with a silicon hydride reactant having at least 2 reactive sites. A preferred article comprises a substrate, at least one photoconductive layer, and an overcoat layer comprising a hole transporting hydroxy arylamine compound having at least two hydroxy functional groups, and a cross linked allyloxymethylatedpolyamide film forming binder. A stabilizer may also be added to the overcoat. The novel allyloxymethylatedpolyamide compositions of this invention are functionalized by incorporation of an allyloxymethyl unit on the nitrogen atom of some of the amide linkages in the polyamide backbone. The double bond pendant to the polymer chain allows two alternate methods of crosslinking, free radical and hydrosilation, neither of which involve the use of an acid catalyst and neither of which results in the elimination of a volatile, potentially defect producing, molecule. The polyamide may, for example, be dissolved in formic acid at 60°C. To the polyamide solution is added a solution of paraformaldehyde dissolved in allyl alcohol with a trace of KOH added. The reaction is stirred for about 10 minutes and another portion of alcohol, which may be the same alcohol , a different alcohol, a non-double bond containing alcohol or a mixture of alcohols, is added. The reaction is allowed to proceed for about 20 minutes and poured into a water/acetone mixture. The rubbery mass is isolated. This type of reaction is generally described in Sorenson and Campbell "Preparative Methods of Polymer Chemistry" second edition, pg. 76. However, the novel allyloxymethylatedpolyamide of this invention are not specifically disclosed by Sorenson and Campbell. These allyloxymethylatedpolyamides have many applications including, for example, gears, hot melt adhesives, toughened alcohol borne coating formulations, electrostatographic imaging members (e.g. overcoatings or blocking layers), and the like which benefit from the cross linkability of this material. A preferred allyloxymethylatedpolyamide is represented by the following formula: wherein R', R", R"' are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms, and n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000. Generally, the weight average molecular weights of the allyloxymethylatedpolyamide may vary from about 5,000 to about 1,000,000 prior to cross linking. When employed in coating compositions, the allyloxymethylatedpolyamide preferably has sufficient molecular weight to form a film upon removal of the solvent and also be soluble in alcohol. Any suitable method may be utilized to synthesize the allyloxymethylatedpolyamide of this invention. Preferably, the allyloxymethylatedpolyamide of this invention is synthesized by reacting an alcohol soluble polyamide with formaldehyde and a double bond terminated alcohol. Any suitable alcohol soluble polyamide may be utilized for the preparation of the allyloxymethylatedpolyamides of this invention. The polyamide reactants should have active groups on the nitrogen atom of at least some of the amide linkages in the polyamide backbone which can be replaced by allyloxymethyl units. Typical alcohol soluble polyamides include, for example, Elvamide, Elvamide TM, and the like. Alcohol soluble polyamide reactants having active hydrogen atoms on the nitrogen atom of at least some of the amide linkages in the polyamide backbone which can be replaced by allyloxymethyl units are commercially available and include, for example, Elvamide 8063 and 8061, available from E.I. DuPont Nemours and Company, and the like. Other polyamide reactants include alcohol soluble Elvamide and Elvamide TH resins. Still other examples of polyamides include Elvamide 8064 and Elvamide 8023. An alcohol soluble polyamide reactant prior to reaction with a double bond terminated alcohol is preferably a polyamide is represented by the formulae: wherein n is a positive integer sufficient to achieve a weight average molecular weight of between 5000 and about 100,000, R is an alkylene unit containing from 1 to 10 carbon atoms and wherein: Z is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000, and R 1 and R are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms. For R and R 1 in Formula III, optimum results are achieved when the number of alkylene units containing less than 6 carbon atoms are about 40 percent of the total number of alkylene units. Preferably, the alkylene units R 1 and R 2 in polyamide Formula III are independently selected from the group consisting of (CH 2 ) 4 and (CH 2 ) 6 , and the concentration of (CH 2 ) 4 and (CH 2 ) 6 is between about 40 percent and about 60 percent of the total number of alkylene units in the polyamide of Formula III. A preferred allyloxymethylatedpolyamide is represented by the following formula: wherein R 1 , R 2 and R 3 are alkylene units independently selected from units containing from 1 to 10 carbon atoms, and n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000. Any suitable reactive double bond terminated alcohol may be utilized in the process for synthesizing the allyloxymethylatedpolyamide. Typical alcohols include, for example, allyl alcohol, 3-butene-1-ol , 4-pentene-1-ol and the like. Preferred alcohols may be represented by the formula wherein w is 1, 2 or 3. Thus, for example, allyl alcohol may be reacted with an alcohol soluble polyamide and formaldehyde. The resultant polymer can be recovered as a rubbery mass; which is still soluble in alcohol. A preferred synthesis technique is illustrated as follows: wherein R is an alkylene unit containing from 1 to 10 carbon atoms. Typically, the process can involve, for example, placing 90 grams formic acid in a 500 ml 3 neck round bottom flask, equipped with a mechanical stirrer and a heating mantle. This can be warmed to 60°C. To the formic acid can be added 30 grams Elvamide 8063. This is allowed to dissolve completely. In a 125 ml erlenmeyer flask can be placed 30 grams paraformaldehyde, 58 grams Allyl alcohol, supplied by Aldrich Chemical Co. 24,053-2, and about .2 gram powdered KOH. This can be stirred using a magnetic stirrer with gentle heating until dissolved. When dissolved this solution is added slowly at first, then more rapidly to the polyamide solution. After stirring for about 10 minutes an additional 58 grams of allyl alcohol is added to the reaction mixture. The reaction, still maintained at 60°C, is allowed to continue for 20 minutes. The reaction solution is then poured into 1800 mls of a mixture of acetone and water (800 mls acetone and 1000 mls water). Aqueous NaOH is slowly added until the solution registered neutral to pH paper. The liquid was decanted off from a whitish rubbery solid. The product is washed repeatedly with water. Any suitable alcohol solvent may be employed for the film forming allyloxymethylatedpolyamide. Typical alcohol solvents include, for example, methanol, butanol, propanol, ethanol, and the like and mixtures thereof. Any suitable technique may be utilized to cross link the allyloxymethylatedpolyamide of this invention. For example, the allyloxymethylatedpolyamide may be cross linked by heating the allyloxymethylatedpolyamide in the presence of a free radical catalyst. Any suitable free radical catalyst may be employed. Typical free radical catalysts include, for example, azo-type initiators such as 2-2'-azobis(dimethyl-valeronitrile), azobis(isobutyronitrile) (AIBN), ,azobis(cyclohexane-nitrile), azobis(methyl-butyronitrile), and the like, and mixtures thereof. For use in electrophotographic imaging members, the catalyst selected should not react adversely with the charge transport material in underlying layers of the imaging member such as a charge transport layer. AIBN is particularly preferred for photoreceptor overcoating applications because it does not react with components in the underlying charge transport layer. Typically, depending upon the specific polyamide and free radical selected, the temperature employed for cross linking is between about 70°C and about 110°C. Cross linking may also be accomplished by hydrosilation of the double bond in the allyloxy groups of the allyloxymethylatedpolyamide. By using allyloxymethylatedpolyamide and silicon hydride reactants with at least two reactive sites in each of the reactant molecules, cross links are formed resulting in a tough, alcohol insoluble matrix. Typical silicon hydrides having at least 2 reactive sites include, for example, polyethylhydrosiloxane (Gelest HES-992, available from Gelest Inc. Tullytown, Pa.), methylhydrosiloxane-phenylmethylsiloxane copolymer, hydride terminated (Gelest HPM-502), 1,3-diphenyl-1,1,3,3-tetrakis(dimethylsiloxy)disiloxane (Gelest SID4582.0), and the like. A preferred hydrosilation cross linking agent is Gelest HDP-111, available from Gelest Inc. Tullytown, Pa. This cross linking agent is represented by the formula: By using polymers and reactants with several reactive sites, cross links are formed. The mechanism for hydrosilation cross linking involves the Si-H addition of the cross linking agent to the double bond on the allyloxymethylatedpolyamide polyamide. The mechanism is illustrated as follows: A crude representation of the crosslinked material is illustrated below: Generally, depending upon the specific allyloxymethylatedpolyamide and silicon hydride selected, the cross linking is accomplished with about 25 percent by weight of silicon hydride and about 50 percent by weight of allyloxymethylatedpolyamide, based on the total weight of solids in a photoreceptor type film. Typically, depending upon the specific polyamide and silicon hydride selected, the temperature employed for cross linking is between about 30°C and about 120°C. A room temperature cure can be achieved with this material. A gel can be produced this way. If allowed to dry a room temperature a very pliable elastic material is obtained. This may be of use in conformable photoreceptors. If the gel is not allowed to air dry rapidly it might be possible, using a very slow controlled drying process, to produce an open cell foam. This would be analogous to the process used to produce aerogels. As a more conventional photoreceptor overcoat the cross linked allyloxymethylatedpolyamide of this invention has the advantage, over some known formulations, of having a long pot life when an appropriate platinum (Pt) catalyst inhibitor is incorporated in the coating solution. One such inhibitor used is 2-methyl-3-butyn-2-ol which complexes with the Pt catalyst and inactivates it at room temperature. During the drying process the Pt catalyst is thermally reactivated and the crosslinking reaction proceeds. The uncross linked material is much more elastic than the starting allyloxymethylatedpolyamide, however, the crosslinked product has enhanced rigidity, hardness and creep resistance relative to the starting allyloxymethylatedpolyamide. The cross linked material can be further toughened with the use of conventional fillers. The allyloxymethylatedpolyamide of this invention is particularly useful in overcoating layers of electrophotographic imaging members. Electrophotographic imaging members are well known in the art. Electrophotographic imaging members may be prepared by any suitable technique. Typically, a flexible or rigid substrate is provided with an electrically conductive surface. A charge generating layer is then applied to the electrically conductive surface. A charge blocking layer may optionally be applied to the electrically conductive surface prior to the application of a charge generating layer. If desired, an adhesive layer may be utilized between the charge blocking layer and the charge generating layer. Usually the charge generation layer is applied onto the blocking layer and a charge transport layer is formed on the charge generation layer. This structure may have the charge generation layer on top of or below the charge transport layer. The substrate may be opaque or substantially transparent and may comprise any suitable material having the required mechanical properties. Accordingly, the substrate may comprise a layer of an electrically non-conductive or conductive material such as an inorganic or an organic composition. As electrically non-conducting materials there may be employed various resins known for this purpose including polyesters, polycarbonates, polyamides, polyurethanes, and the like which are flexible as thin webs. An electrically conducting substrate may be any metal, for example, aluminum, nickel, steel, copper, and the like or a polymeric material, as described above, filled with an electrically conducting substance, such as carbon, metallic powder, and the like or an organic electrically conducting material. The electrically insulating or conductive substrate may be in the form of an endless flexible belt, a web, a rigid cylinder, a sheet and the like. The thickness of the substrate layer depends on numerous factors, including strength desired and economical considerations. Thus, for a drum, this layer may be of substantial thickness of, for example, up to many centimeters or of a minimum thickness of less than a millimeter. Similarly, a flexible belt may be of substantial thickness, for example, about 250 micrometers, or of minimum thickness less than 50 micrometers, provided there are no adverse effects on the final electrophotographic device. In embodiments where the substrate layer is not conductive, the surface thereof may be rendered electrically conductive by an electrically conductive coating. The conductive coating may vary in thickness over substantially wide ranges depending upon the optical transparency, degree of flexibility desired, and economic factors. Accordingly, for a flexible photoresponsive imaging device, the thickness of the conductive coating may be between about 20 angstroms to about 750 angstroms, and more preferably from about 100 angstroms to about 200 angstroms for an optimum combination of electrical conductivity, flexibility and light transmission. The flexible conductive coating may be an electrically conductive metal layer formed, for example, on the substrate by any suitable coating technique, such as a vacuum depositing technique or electrodeposition. Typical metals include aluminum, zirconium, niobium, tantalum, vanadium and hafnium, titanium, nickel, stainless steel, chromium, tungsten, molybdenum, and the like. An optional hole blocking layer may be applied to the substrate. Any suitable and conventional blocking layer capable of forming an electronic barrier to holes between the adjacent photoconductive layer and the underlying conductive surface of a substrate may be utilized. An optional adhesive layer may applied to the hole blocking layer. Any suitable adhesive layer well known in the art may be utilized. Typical adhesive layer materials include, for example, polyesters, polyurethanes, and the like. Satisfactory results may be achieved with adhesive layer thickness between about 0.05 micrometer (500 angstroms) and about 0.3 micrometer (3,000 angstroms). Conventional techniques for applying an adhesive layer coating mixture to the charge blocking layer include spraying, dip coating, roll coating, wire wound rod coating, gravure coating, Bird applicator coating, and the like. Drying of the deposited coating may be effected by any suitable conventional technique such as oven drying, infra red radiation drying, air drying and the like. At least one electrophotographic imaging layer is formed on the adhesive layer, blocking layer or substrate. The electrophotographic imaging layer may be a single layer that performs both charge generating and charge transport functions as is well known in the art or it may comprise multiple layers such as a charge generator layer and charge transport layer. Charge generator layers may comprise amorphous films of selenium and alloys of selenium and arsenic, tellurium, germanium and the like, hydrogenated amorphous silicon and compounds of silicon and germanium, carbon, oxygen, nitrogen and the like fabricated by vacuum evaporation or deposition. The charge generator layers may also comprise inorganic pigments of crystalline selenium and its alloys; Group II-VI compounds; and organic pigments such as quinacridones, polycyclic pigments such as dibromo anthanthrone pigments, perylene and perinone diamines, polynuclear aromatic quinones, azo pigments including bis-, tris- and tetrakis-azos; and the like dispersed in a film forming polymeric binder and fabricated by solvent coating techniques. Phthalocyanines have been employed as photogenerating materials for use in laser printers utilizing infrared exposure systems. Infrared sensitivity is required for photoreceptors exposed to low cost semiconductor laser diode light exposure devices. The absorption spectrum and photosensitivity of the phthalocyanines depend on the central metal atom of the compound. Many metal phthalocyanines have been reported and include, oxyvanadium phthalocyanine, chloroaluminum phthalocyanine, copper phthalocyanine, oxytitanium phthalocyanine, chlorogallium phthalocyanine, hydroxygallium phthalocyanine magnesium phthalocyanine and metal-free phthalocyanine. The phthalocyanines exist in many crystal forms which have a strong influence on photogeneration. Any suitable polymeric film forming binder material may be employed as the matrix in the charge generating (photogenerating) binder layer. Typical polymeric film forming materials include those described, for example, in US-A 3,121,006, the entire disclosure of which is incorporated herein by reference. Thus, typical organic polymeric film forming binders include thermoplastic and thermosetting resins such as polycarbonates, polyesters, polyamides, polyurethanes, polystyrenes, polyarylethers, polyarylsulfones, polybutadienes, polysulfones, polyethersulfones, polyethylenes, polypropylenes, polyimides, polymethylpentenes, polyphenylene sulfides, polyvinyl acetate, polysiloxanes, polyacrylates, polyvinyl acetals, polyamides, polyimides, amino resins, phenylene oxide resins, terephthalic acid resins, phenoxy resins, epoxy resins, phenolic resins, polystyrene and acrylonitrile copolymers, polyvinylchloride, vinylchloride and vinyl acetate copolymers, acrylate copolymers, alkyd resins, cellulosic film formers, poly(amideimide), styrenebutadiene copolymers, vinylidenechloride-vinylchloride copolymers, vinylacetate-vinylidenechloride copolymers, styrene-alkyd resins, polyvinylcarbazole, and the like. These polymers may be block, random or alternating copolymers. The photogenerating composition or pigment is present in the resinous binder composition in various amounts. Generally, however, from about 5 percent by volume to about 90 percent by volume of the photogenerating pigment is dispersed in about 10 percent by volume to about 95 percent by volume of the resinous binder, and preferably from about 20 percent by volume to about 30 percent by volume of the photogenerating pigment is dispersed in about 70 percent by volume to about 80 percent by volume of the resinous binder composition. In one embodiment about 8 percent by volume of the photogenerating pigment is dispersed in about 92 percent by volume of the resinous binder composition. The photogenerator layers can also fabricated by vacuum sublimation in which case there is no binder. Any suitable and conventional technique may be utilized to mix and thereafter apply the photogenerating layer coating mixture. Typical application techniques include spraying, dip coating, roll coating, wire wound rod coating, vacuum sublimation and the like. For some applications, the generator layer may be fabricated in a dot or line pattern. Removing of the solvent of a solvent coated layer may be effected by any suitable conventional technique such as oven drying, infrared radiation drying, air drying and the like. The charge transport layer may comprise a charge transporting small molecule dissolved or molecularly dispersed in a film forming electrically inert polymer such as a polycarbonate. The term "dissolved" as employed herein is defined herein as forming a solution in which the small molecule is dissolved in the polymer to form a homogeneous phase. The expression "molecularly dispersed" is used herein is defined as a charge transporting small molecule dispersed in the polymer, the small molecules being dispersed in the polymer on a molecular scale. Any suitable charge transporting or electrically active small molecule may be employed in the charge transport layer of this invention. The expression charge transporting "small molecule" is defined herein as a monomer that allows the free charge photogenerated in the transport layer to be transported across the transport layer. Typical charge transporting small molecules include, for example, pyrazolines such as 1-phenyl-3-(4'-diethylamino styryl)-5-(4"- diethylamino phenyl)pyrazoline, diamines such as N,N'-diphenyl-N,N'-bis(3-methylphenyl)-(1,1'-biphenyl)-4,4'-diamine, hydrazones such as N-phenyl-N-methyl-3-(9-ethyl)carbazyl hydrazone and 4-diethyl amino benzaldehyde-1,2-diphenyl hydrazone, and oxadiazoles such as 2,5-bis (4-N,N'-diethylaminophenyl)-1,2,4-oxadiazole, stilbenes and the like. However, to avoid cycle-up in machines with high throughput, the charge transport layer should be substantially free (less than about two percent) of triphenyl methane. As indicated above, suitable electrically active small molecule charge transporting compounds are dissolved or molecularly dispersed in electrically inactive polymeric film forming materials. A small molecule charge transporting compound that permits injection of holes from the pigment into the charge generating layer with high efficiency and transports them across the charge transport layer with very short transit times is N,N'-diphenyl-N,N'-bis(3-methylphenyl)-(1,1'-biphenyl)-4,4'-diamine. Any suitable electrically inactive resin binder insoluble in the alcohol solvent used to apply the overcoat layer may be employed in the charge transport layer of this invention. Typical inactive resin binders include polycarbonate resin, polyester, polyarylate, polyacrylate, polyether, polysulfone, and the like. Molecular weights can vary, for example, from about 20,000 to about 150,000. Preferred binders include polycarbonates such as poly(4,4'-isopropylidene-diphenylene)carbonate (also referred to as bisphenol-A-polycarbonate, poly(4,4'-cyclohexylidinediphenylene) carbonate (referred to as bisphenol-Z polycarbonate), and the like. Any suitable charge transporting polymer may also be utilized in the charge transporting layer of this invention. The charge transporting polymer should be insoluble in the alcohol solvent employed to apply the overcoat layer of this invention. These electrically active charge transporting polymeric materials should be capable of supporting the injection of photogenerated holes from the charge generation material and be incapable of allowing the transport of these holes therethrough. Any suitable and conventional technique may be utilized to mix and thereafter apply the charge transport layer coating mixture to the charge generating layer. Typical application techniques include spraying, dip coating, roll coating, wire wound rod coating, and the like. Drying of the deposited coating may be effected by any suitable conventional technique such as oven drying, infra red radiation drying, air drying and the like. Generally, the thickness of the charge transport layer is between about 10 and about 50 micrometers, but thicknesses outside this range can also be used. The hole transport layer should be an insulator to the extent that the electrostatic charge placed on the hole transport layer is not conducted in the absence of illumination at a rate sufficient to prevent formation and retention of an electrostatic latent image thereon. In general, the ratio of the thickness of the hole transport layer to the charge generator layers is preferably maintained from about 2:1 to 200:1 and in some instances as great as 400:1. The charge transport layer, is substantially non-absorbing to visible light or radiation in the region of intended use but is electrically "active" in that it allows the injection of photogenerated holes from the photoconductive layer, i.e., charge generation layer, and allows these holes to be transported through itself to selectively discharge a surface charge on the surface of the active layer. If desired the electrophotographic imaging member embodiment of this invention may comprise a supporting substrate, a charge transport layer, charge generating layer and an overcoating layer instead of a supporting substrate, charge generating layer, a charge transport layer and an overcoating layer containing the cross linked allyloxymethylatedpolyamide of this invention. Where the charge generating layer overlies the charge transport layer, the components of the charge generating layer should be insoluble in the alcohol solvent employed to apply the overcoat layer of this invention. The solution employed to form the overcoat layer of this invention comprises a hole transporting arylamine compound, an alcohol and a cross linkable allyloxymethylatedpolyamide film forming binder capable of cross linking. Any suitable alcohol soluble hole transporting arylamine compound may be used with the cross linkable allyloxymethylatedpolyamide in the overcoating embodiment of this invention. Typical hole transporting arylamine compounds include, for example, polyhydroxy diaryl amines. Any suitable polyhydroxy diaryl amine small molecule charge transport material having at least two hydroxy functional groups may be utilized in the overcoating layer embodiment of this invention. A preferred small molecule hole transporting material can be represented by the following formula: wherein: m is 0 or 1, Z is selected from the group consisting of: n is 0 or 1, Ar is selected from the group consisting of: R is selected from the group consisting of -CH 3 , -C 2 H 5 , -C 3 H 7 , and -C 4 H 9 , Ar' is selected from the group consisting of: and X is selected from the group consisting of: and s is 0, 1 or 2, the dihydroxy arylamine compound being free of any direct conjugation between the -OH groups and the nearest nitrogen atom through one or more aromatic rings. The expression "direct conjugation" is defined as the presence of a segment, having the formula: -(C=C) n -C=C- in one or more aromatic rings directly between an -OH group and the nearest nitrogen atom. Examples of direct conjugation between the -OH groups and the nearest nitrogen atom through one or more aromatic rings include a compound containing a phenylene group having an -OH group in the ortho or para position (or 2 or 4 position) on the phenylene group relative to a nitrogen atom attached to the phenylene group or a compound containing a polyphenylene group having an -OH group in the ortho or para position on the terminal phenylene group relative to a nitrogen atom attached to an associated phenylene group. Typical polyhydroxy arylamine compounds utilized in the overcoat of this invention include, for example: N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine; N,N,N',N',-tetra(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine ; N,N-di(3-hydroxyphenyl)-m-toluidine; 1,1-bis-[4-(di-N,N-m-hydroxyphenyl)-aminophenyl]-cyclohexane; 1,1-bis[4-(N-m-hydroxyphenyl)-4-(N-phenyl)-aminophenyl]-cyclohexane ; Bis-(N-(3-hydroxyphenyl)-N-phenyl-4-aminophenyl)-methane; Bis[(N-(3-hydroxyphenyl)-N-phenyl)-4-aminophenyl]-isopropylidene; N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1':4',1"-terphenyl]-4,4"-diamine; 9-ethyl-3.6-bis[N-phenyl-N-3(3-hydroxyphenyl)-amino]-carbazole ; 2,7-bis[N,N-di(3-hydroxyphenyl)-aminol-fluorene; 1,6-bis[N,N-di(3-hydroxyphenyl)-amino]-pyrene; 1,4-bis[N-phenyl-N-(3-hydroxyphenyl)]-phenylenediamine. This material with the hole transporting hydroxy arylamine compound forms a hard glassy tough film. When crosslinked it has increased abrasion resistance and the added property of maintaining mechanical strength while exposed to alcohol, hydrocarbons and other solvents. When the allyloxymethylatedpolyamides of this invention are utilized in overcoats applied to the charge transport layer of an electrophotographic imaging member, the overcoat provides the charge transport layer with greater conformability characterisitics, high mobility and the ability to chemically bond to the overcoat embodiment of this invention. To achieve chemical bonding between the overcoat and the charge transport layer, the charge transport layer has available double bond sites which react with the overcoating composition. thereby eliminating any possibility of the overcoat delaminating during image cycling. These charge transport layer has available double bond sites can contain polysiloxanes containing arylamine moieties and double bond functionality. Preferred polysiloxanes containing arylamine moieties and double bond functionality are represented by the following structure wherein BPA represents bis phenol A, TBD represents the polyhydroxy arylamine monomer, n is an integer from 5 to 30, m is an integer from 5 to 30, x is an integer from 5 to 30, and z is an integer from 5 to 30. Alternatively, any suitable charge transporting electrically active small molecule may be employed in the overcoating layer of this invention. Generally, higher loadings of the charge transporting small molecule is employed. The expression charge transporting "small molecule" is defined herein as a monomer that allows the free charge photogenerated in the transport layer to be transported across the transport layer. Typical charge transporting small molecules include, for example, pyrazolines such as 1-phenyl-3-(4'-diethylamino styryl)-5-(4"- diethylamino phenyl)pyrazoline, diamines such as N,N'-diphenyl-N,N'-bis(3-methylphenyl)-(1,1'-biphenyl)-4,4'-diamine, hydrazones such as N-phenyl-N-methyl-3-(9-ethyl)carbazyl hydrazone and 4-diethyl amino benzaldehyde-1,2-diphenyl hydrazone, and oxadiazoles such as 2,5-bis (4-N,N'-diethylaminophenyl)-1,2,4-oxadiazole, stilbenes and the like. However, to avoid cycle-up in machines with high throughput, the charge transport layer should be substantially free (less than about two percent) of triphenyl methane. As indicated above, suitable electrically active small molecule charge transporting compounds are dissolved or molecularly dispersed in electrically inactive polymeric film forming materials. A small molecule charge transporting compound that permits injection of holes from the pigment into the charge generating layer with high efficiency and transports them across the charge transport layer with very short transit times is N,N'-diphenyl-N,N'-bis(3-methylphenyl)-(1,1'-biphenyl)-4,4'-diamine. if desired, a stabilizer may be added to the overcoating solution. A preferred stabilizer is bis-(2-methyl-4-diethylaminophenyl)-phenylmethane [BDETPM]. Generally, an alcohol miscible solvent for bis-(2-methyl-4-diethylaminophenyl)-phenylmethane is also preferred to ensure that the bis-(2-methyl-4-diethylaminophenyl)-phenylmethane dissolves in the coating solution Bis-(2-methyl-4-diethylaminophenyl)-phenylmethane can be represented by the following formula: Bis-(2-methyl-4-diethylaminophenyl)-phenylmethane is insoluble in alcohol and will not form a solution with a mixture of a hole transporting hydroxy arylamine compound having at least two hydroxy functional groups, an alcohol and the allyloxymethylatedpolyamide film forming binder. When bis-(2-methyl-4-diethylaminophenyl)-phenylmethane is employed in the overcoat coating solution, the solution also comprises a solvent which dissolves bis-(2-methyl-4-diethylaminophenyl)-phenylmethane, the solvent also being miscible with alcohol. Typical solvents which dissolve bis-(2-methyl-4-diethylaminophenyl)-phenylmethane, and are also miscible with alcohol include, for example, tetrahydrofuran, chlorobenzene, and the like. The expressions "dissolves" and "miscible" as employed herein are defined as solvents which form clear solutions with the other materials employed in the overcoat compositions of this invention. The solvent for bis-(2-methyl-4-diethylaminophenyl)-phenylmethane may be mixed with bis-(2-methyl-4-diethylaminophenyl)-phenylmethane prior to admixing with the alcohol and other components of the overcoating composition or the solvent for bis-(2-methyl-4-diethylaminophenyl)-phenylmethane may be admixed with the alcohol and other components of the overcoating composition prior to combination with bis-(2-methyl-4-diethylaminophenyl)-phenylmethane. Overcoatings for photoreceptors may be formed from charge transporting components and a film forming binder such as alcohol soluble polyamide polymers having methoxy methyl groups attached to the nitrogen atoms of amide groups in the polymer backbone. Unfortunately, these coating compositions have a relatively short pot life. To achieve longer pot life it is usually necessary to change the solvent composition or use a lower solids content. With lower solids content, adequately thick protective overcoatings are normally not achieved with dip coating systems. It has been found that the thickness of an overcoating containing alcohol soluble polyamide polymers having methoxy methyl groups attached to the nitrogen atoms of amide groups in the polymer backbone can be increased by adding an allyloxymethylatedpolyamide which increases the solids concentration of the overcoating coating composition while also enhancing pot life of the coating composition. Typical alcohol soluble polyamide polymers having methoxy methyl groups attached to the nitrogen atoms of amide groups in the polymer backbone include, for example, hole insulating alcohol soluble polyamide film forming polymers such as Luckamide 5003 from Dai Nippon Ink, Nylon 8 with methylmethoxy pendant groups, CM4000 from Toray Industries, Ltd. and CM8000 from Toray Industries, Ltd. and other N-methoxymethylated polyamides, such as those prepared according to the method described in Sorenson and Campbell "Preparative Methods of Polymer Chemistry" second edition, pg. 76, John Wiley & Sons Inc. 1968, and the like and mixtures thereof. These polyamides can be alcohol soluble, for example, with polar functional groups, such as methoxy, ethoxy and hydroxy groups, pendant from the polymer backbone. It should be noted that polyamides, such as Elvamides from DuPont de Nemours & Co., do not contain methoxy methyl groups attached to the nitrogen atoms of amide groups in the polymer backbone. Generally, where an overcoating binder contains alcohol soluble polyamide polymers having methoxy methyl groups attached to the nitrogen atoms of amide groups in the polymer backbone, e.g. Luckamides, the overcoating solution should also comprise between about 5 and about 20 percent by weight of allyloxymethylatedpolyamide, based on the total weight of film forming binder in the overcoat coating solution. The mixture of polyamide polymers having methoxy methyl groups attached to the nitrogen atoms of amide groups in the polymer backbone and allyloxymethylatedpolyamide are structurally similar and compatible, both in solution and in the final film. This similarity in structure is evident by comparing the structure of a typical polyamide polymer having methoxy methyl groups attached to the nitrogen atoms of amide groups in the polymer backbone illustrated below with the structure of a typical allyloxymethylatedpolyamide illustrated below As readily evident, the structures are similar except that the methoxy group of polyamide polymer having methoxy methyl groups attached to the nitrogen atoms of amide groups in the polymer backbone has been substituted in the second formula with a vinyl group containing allyloxy unit. Thus, for example, an overcoat coating solution in which 20 weight percent of the total weight of binder is made up of the allyloxymethylatedpolyamide has substantially longer pot life than polyamide polymer having methoxy methyl groups attached to the nitrogen atoms of amide groups in the polymer backbone alone. Typical alcohols in which the polyamide reactant and allyloxymethylatedpolyamide are soluble include, for example, butanol, ethanol, methanol, and the like. For the overcoating layer embodiments of this invention, the coating composition preferably comprises between about 50 percent by weight and about 98 percent by weight of the crosslinked film forming crosslinkable alcohol soluble allyloxymethylatedpolyamide, based on the total weight of the overcoating layer after crosslinking and drying. Cross linking is described in detail above. Cross linking is accomplished by heating in the presence of a catalyst. Any suitable catalyst may be employed. Typical catalysts include, for example, Pt(IV) complexes representatives of these include platinum -divinyl tetramethyldisiloxane complex, Gelest SiP6830.0, platinum-divinyl tetramethylsioxane complex in xylene, Gelest SiP6831.0, platinum-cyclovinylmethylsiloxane complex, Gelest SiP6832.0, platinum-octanaldehyde/octanol complex, Gelest SiP6833.0, and the like. The temperature used for crosslinking varies with the specific catalyst and heating time utilized and the degree of cross linking desired. Generally, the degree of crosslinking selected depends upon the desired flexibility of the final photoreceptor. For example, complete crosslinking may be used for rigid drum or plate photoreceptors. However, partial crosslinking is preferred for flexible photoreceptors having, for example, web or belt configurations. The degree of crosslinking can be controlled by the relative amount of catalyst employed and the concentration of double bonds and Si-H functionality. The amount of catalyst to achieve a desired degree of crosslinking will vary depending upon the specific polyamide, the amount of silicon hydride functionality, catalyst type, temperature and time used for the reaction. A typical crosslinking temperature used for allyloxymethylate polyamide using Gelest SiP6831.0 catalyst is about 110°C -125°C for about 30 minutes. A typical concentration of Pt catalyst solution is between 10 percent and 20 percent by weight, based on the weight of the allyloxymethylated elvamide. Typical catalyst solutions contain about 2-5 weight percent platinum. After crosslinking, the overcoating should be substantially insoluble in the solvent in which it was soluble prior to crosslinking. Thus, no overcoating material will be removed when rubbed with a cloth soaked in the solvent. Crosslinking results in the development of a three dimensional network which restrains the hydroxy functionalized transport molecule as a fish is caught in a gill net. All the components utilized in the overcoating solution of this invention should be soluble in the mixture of alcohol and non-alcoholic bis-(2-methyl-4-diethylaminophenyl)-phenylmethane solvents employed for the overcoating. When at least one component in the overcoating mixture is not soluble in the solvent utilized, phase separation can occur which would adversely affect the transparency of the overcoating and electrical performance of the final photoreceptor. Generally, the weight ratio range of the components of the overcoating solution of this invention is 0.8 to 1 parts by weight hydroxy arylamine compound : 0.05 to 0.15 parts by weight bis-(2-methyl-4-diethylaminophenyl)-phenylmethane [BDETPM] : 0.3 to 0.5 parts by weight bis-(2-methyl-4-diethylaminophenyl)-phenylmethane [BDETPM] non-alcoholic solvent : 0.9 to 1.5 parts by weight polyamide : 9 to 15 parts by weight alcohol. However, the specific amounts can vary depending upon the specific polyamide, alcohol and bis-(2-methyl-4-diethylaminophenyl)-phenylmethane [BDETPM] : bis-(2-methyl-4-diethylaminophenyl)-phenylmethane [BDETPM] non-alcoholic solvent selected. Preferably, the solvent mixture contains between about 85 percent and about 99 percent by weight of alcohol and between about 1 percent and about 15 percent by weight of bis-(2-methyl-4-diethylaminophenyl)-phenylmethane non-alcoholic solvent, based on the total weight of the solvents in the overcoat coating solution. Various techniques may be employed to form coating solutions containing bis-(2-methyl-4-diethylaminophenyl)-phenylmethane [BDETPM], polyamide and polyhydroxy diaryl amine small molecule. For example, bis-(2-methyl-4-diethylaminophenyl)-phenylmethane [BDETPM] may be dissolved in a suitable alcohol soluble solvent such as tetrahydrofuran prior to mixing with a solution of polyhydroxy diaryl amine (e.g. N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine [DHTBD]) and allyloxymethylatedpolyamide in alcohol. Alternatively, from about 5 percent to about 20 percent by weight, based on the total weight of solvents of a co-solvent, such as chlorobenzene, may be mixed with polyhydroxy diaryl amine (e.g. N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine [DHTBD]) and allyloxymethylatedpolyamide dissolved in alcohol followed by dissolving, with warming, bis-(2-methyl-4-diethylaminophenyl)-phenylmethane [BDETPM] in the coating solution. Good films have been coated using these methods. N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine [DHTBD], can be represented by the following formula: Bis-[2-methyl-4-(N-2-hydroxyethyl-N-ethyl-aminophenyl)]-phenylmethane (DHTPM) can be represented by the following formula: The thickness of the continuous overcoat layer embodiment selected depends upon the abrasiveness of the charging (e.g., bias charging roll), cleaning (e.g., blade or web), development (e.g., brush), transfer (e.g., bias transfer roll), etc., in the system employed and can range up to about 10 micrometers. A thickness of between about 1 micrometer and about 5 micrometers in thickness is preferred. Any suitable and conventional technique may be utilized to mix and thereafter apply the overcoat layer coating mixture to the charge generating layer. Typical application techniques include spraying, dip coating, roll coating, wire wound rod coating, and the like. Drying of the deposited coating may be effected by any suitable conventional technique such as oven drying, infrared radiation drying, air drying and the like. The dried overcoating of this invention should transport holes during imaging and should not have too high a free carrier concentration. Free carrier concentration in the overcoat increases the dark decay. Preferably the dark decay of the overcoated layer should be about the same as that of the unovercoated device. A number of examples are set forth hereinbelow and are illustrative of different compositions and conditions that can be utilized in practicing the invention. All proportions are by weight unless otherwise indicated. It will be apparent, however, that the invention can be practiced with many types of compositions and can have many different uses in accordance with the disclosure above and as pointed out hereinafter. EXAMPLE I Synthesis of allyloxymethylated Elvamide I: In a 500 ml 3 neck round bottom flask, equipped with a mechanical stirrer and a heating mantle, was placed 90 grams formic acid. This was warmed to 60°C. To the formic acid was added 30 grams Elvamide 8063, available from E. I. Dupont de Nemours & Co. This was allowed to dissolve completely. In a 125 ml erlenmeyer flask was placed 30 grams paraformaldehyde, 58 grams allyl alcohol, (supplied by Aldrich Chemical Co. 24,053-2); and about .2 gram powdered KOH. This was stirred using a magnetic stirrer with gentle heating until dissolved. When dissolved this solution was added slowly at first, then more rapidly to the polyamide solution. After stirring for about 10 minutes an additional 58 grams of allyl alcohol was added to the reaction mixture. The reaction, still maintained at 60°C, was allowed to continue for 20 minutes. The reaction solution was then poured into 1800 mls of a mixture of acetone and water (800 mls acetone and 1000 mls water). Aqueous NaOH was slowly added until the solution registered neutral to pH paper. The liquid was decanted off from the resulting whitish rubbery solid. The product was washed repeatedly with water. EXAMPLE II Synthesis of Allyloxymethylated Elvamide II: In a 500 ml 3 neck round bottom flask, equipped with a mechanical stirrer and a heating mantle, was placed 90 grams formic acid. This was warmed to 60°C. To the formic acid was added 30 grams Elvamide 8061, available from E. I. Dupont Nemours & Company. This was allowed to dissolve completely. In a 125 ml erlenmeyer flask was placed 30 grams paraformaldehyde, 58 grams allyl alcohol (supplied by Aldrich Chemical Co. 24,053-2), and about .2 gram powdered KOH. This was stirred using a magnetic stirrer with gentle heating until dissolved. When dissolved this solution was added slowly at first, then more rapidly to the polyamide solution. After stirring for about 10 minutes an additional 58 grams of allyl alcohol was added to the reaction mixture. The reaction, still maintained at 60°C, was allowed to continue for 30 minutes. The reaction solution was then poured into 1800 mls of a mixture of acetone and water (800 mls acetone and 1000 mls water). Aqueous NaOH was slowly added until the solution registered neutral to pH paper. The liquid was decanted off from the resulting whitish rubbery solid. The product was washed repeatedly with water.] EXAMPLE III Photoreceptors were prepared by forming coatings using conventional techniques on a substrate comprising a vacuum deposited titanium layer on a polyethylene terephthalate film. The first coating formed on the titanium layer was a siloxane barrier layer formed from hydrolyzed gamma aminopropyltriethoxysilane having a thickness of 0.005 micrometer (50 Angstroms). The barrier layer coating composition was prepared by mixing 3-aminopropyltriethoxysilane (available from PCR Research Center Chemicals of Florida) with ethanol in a 1:50 volume ratio. The coating composition was applied by a multiple clearance film applicator to form a coating having a wet thickness of 0.5 mil. The i coating was then allowed to dry for 5 minutes at room temperature, followed by curing for 10 minutes at 110 degree centigrade in a forced air oven. The second coating was an adhesive layer of polyester resin (49,000, available from E.I. duPont de Nemours & Co.) having a thickness of 0.005 micrometer (50 Angstroms). The second coating composition was applied using a 0.5 mil bar and the resulting coating was cured in a forced air oven for 10 minutes. This adhesive interface layer was thereafter coated with a photogenerating layer containing 40 percent by volume hydroxygallium phthalocyanine and 60 percent by volume of a block copolymer of styrene (82 percent) / 4-vinyl pyridine (18 percent) having a Mw of 11,000. This photogenerating coating composition was prepared by dissolving 1.5 grams of the block copolymer of styrene / 4-vinyl pyridine in 42 ml of toluene. To this solution was added 1.33 grams of hydroxygallium phthalocyanine and 300 grams of 1/8 inch diameter stainless steel shot. This mixture was then placed on a ball mill for 20 hours. The resulting slurry was thereafter applied to the adhesive interface with a Bird applicator to form a layer having a wet thickness of 0.25 mil. This layer was dried at 135°C for 5 minutes in a forced air oven to form a photogenerating layer having a dry thickness 0.4 micrometer. The next applied layer was a transport layer which was formed by using a Bird coating applicator to apply a solution containing one gram of N,N'-diphenyl-N,N'-bis(3-methyl-phenyl)-(1,1'-biphenyl)-4,4'-diamine and one gram of polycarbonate resin [poly(4,4'-isopropylidene-diphenylene carbonate (available as Makrolon® from Farbenfabricken Bayer A.G.) dissolved in 11.5 grams of methylene chloride solvent. The N,N'-diphenyl-N,N'-bis(3-methyl-phenyl)-(1,1'-biphenyl)-4,4'-diamine is an electrically active aromatic diamine charge transport small molecule whereas the polycarbonate resin is an electrically inactive film forming binder. The coated device was dried at 80°C for half an hour in a forced air oven to form a dry 25 micrometer thick charge transport layer. EXAMPLE IV One of the devices of Example III was overcoated with an overcoat layer material of the prior art (cross linked overcoat of US-A 5,702,854). The overcoat layer was prepared by mixing 10 grams of a 10 percent by weight solution of polyamide containing methoxymethyl groups (Luckamide 5003, available from Dai Nippon Ink) in a 90:10 weight ratio solvent of methanol and n-propanol and 10 grams of N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1-biphenyl]-4,4"-diamine, a hydroxy functionalized aromatic diamine, in a roll mill for 2 hours. Immediately prior to the application of the overcoat layer mixture, 0.1 gram of oxalic acid was added and the resulting mixture was roll milled briefly to assure dissolution. This coating solution was applied to the photoreceptor using a #20 Mayer rod. This overcoat layer was air dried in a hood for 30 minutes. The air dried film was then dried in a forced air oven at 125°C for 30 minutes. The overcoat layer thickness was approximately 3 micrometers. The oxalic acid caused crosslinking of the methoxymethyl groups of the polyamide to yield a tough, abrasion resistant, hydrocarbon liquid resistant top surface. EXAMPLE V One of the devices of Example III was overcoated with an overcoat layer material of this invention. The charge transport layer was coated with a composition of 2 grams of the allyloxymethylatedpolyamide of Example I , 12.5 grams of methyl alcohol, 5 grams n-propanol, 2 grams of N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (DHTBD), 0.2 gram bis-(2-methyl-4-diethylaminophenyl) phenylmethane (BDETPM) dissolved in 0.5 gram tetrahydrofuran, 0.1 gram 2-methyl-3-butyn-2-ol, a Pt catalyst inhibitor available from Aldrich Chemical Co., 0.4 gram HDP-111 (hydride functional polysiloxane; available from Gelest Inc. Tully Town Pa.), and 0.3 gram Pt catalyst complex in xylene, (also available from Gelest Inc.), to form an overcoat. The film was cast using a 1 mil coating bar. The coating was dried in a forced air oven at 110°C for 30 minutes. The dried film had an average thickness of 3.5 micrometers. EXAMPLE VI One of the devices of Example III was overcoated with an overcoat layer material of this invention. The charge transport layer was coated with a composition of 2 grams of the allyloxymethylatedpolyamide of Example II, 12.5 grams of methyl alcohol, 5 grams n-propanol, 2 grams of N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine DHTBD, 0.2 gram bis-(2-methyl -4-diethylaminophenyl) phenylmethane (BDETPM) dissolved in 0.5 gram THF, 0.1 gram 2-methyl-3-butyn-2-ol, a Pt catalyst inhibitor (available from Aldrich Chemical Co.), 0.4 gram HDP-111 (hydride functional polysiloxane available from Gelest Inc., Tully Town Pa.), and 0.3 gram Pt catalyst complex in xylene, also available from Gelest Inc., to form an overcoat. The film was cast using a 1 mil coating bar. The coating was dried in a forced air oven at 110°C for 30 minutes. The dried film had an average thickness of 3.5 micrometers. EXAMPLE VII Devices of Example IV (device of US-A 5,702,854) and Examples V and VI (devices of this invention) were first tested for xerographic sensitivity and cyclic stability. Each photoreceptor device was mounted on a cylindrical aluminum drum substrate which was rotated on a shaft of a scanner. Each photoreceptor was charged by a corotron mounted along the periphery of the drum. The surface potential was measured as a function of time by capacitively coupled voltage probes placed at different locations around the shaft. The probes were calibrated by applying known potentials to the drum substrate. The photoreceptors on the drums were exposed by a light source located at a position near the drum downstream from the corotron. As the drum was rotated, the initial (pre-exposure) charging potential was measured by voltage probe 1. Further rotation leads to the exposure station, where the photoreceptor was exposed to monochromatic radiation of a known intensity. The photoreceptor was erased by light source located at a position upstream of charging. The measurements made included charging of the photoreceptor in a constant current of voltage mode. The photoreceptor was corona charged to a negative polarity. As the drum was rotated, the initial charging potential was measured by voltage probe 1. Further rotation lead to the exposure station, where the photoreceptor was exposed to monochromatic radiation of known intensity. The surface potential after exposure was measured by voltage probes 2 and 3. The photoreceptor was finally exposed to an erase lamp of appropriate intensity and any residual potential was measured by voltage probe 4. The process was repeated with the magnitude of the exposure automatically changed during the next cycle. The photodischarge characteristics were obtained by plotting the potentials at voltage probes 2 and 3 as a function of light exposure. The charge acceptance and dark decay were also measured in the scanner.. The residual potential was equivalent (15 volts) for all three photoreceptors and no cycle-up was observed when cycled for 10,000 cycles in a continuous mode. The overcoat layer of this invention clearly did not introduce any deficiencies. EXAMPLE VIII Deletion resistance test: A negative corotron was operated (with high voltage connected to the corotron wire) opposite a grounded electrode for several hours. The high voltage was turned off, and the corotron was placed (parked ) for thirty minutes on a segment of the photoconductor device being tested. Only a short middle segment of the photoconductor device was thus exposed to the corotron effluents. Unexposed regions on either side of the exposed regions were used as controls. The photoconductor device was then tested in a scanner for positive charging properties for systems employing donor type molecules. These systems were operated with negative polarity corotron in the latent image formation step. An electrically conductive surface region (excess hole concentration) appears as a loss of positive charge acceptance or increased dark decay in the exposed regions (compared to the unexposed control areas on either side of the short middle segment). Since the electrically conductive region is located on the surface of the photoreceptor device, a negative charge acceptance scan is not affected by the corotron effluent exposure (negative charges do not move through a charge transport layer made up of donor molecules). However, the excess carriers on the surface cause surface conductivity resulting in loss. of image resolution, and in severe cases, causes deletion. The photoreceptor device of Example IV of the prior art and of Example V and VI of the present invention were tested for deletion resistance. The region not exposed to corona effluents charged to 1000 volts positive in all devices. However the corona exposed region of the device of Example IV of the prior art charged to 500 volts (a loss of 500 volts of charge acceptance) whereas the corona exposed regions of the devices of Examples V and VI were charged to 900 volts (a loss of only 100 volts of charge acceptance). Thus, the composition of this invention has improved deletion resistance by a factor of 5. EXAMPLE IX Electrophotographic imaging members were prepared by applying by dip coating a charge blocking layer onto the rough surface of eight aluminum drums having a diameter of 4 cm and a length of 31 cm. The blocking layer coating mixture was a solution of 8 weight percent polyamide (nylon 6) dissolved in 92 weight percent butanol, methanol and water solvent mixture. The butanol, methanol and water mixture percentages were 55, 36 and 9 percent by weight, respectively. The coating was applied at a coating bath withdrawal rate of 300 millimeters / minute. After drying in a forced air oven, the blocking layers had thicknesses of 1.5 micrometers. The dried blocking layers were coated with a charge generating layer containing 2.5 weight percent hydroxy gallium phthalocyanine pigment particles, 2.5 weight percent polyvinylbutyral film forming polymer and 95 weight percent cyclohexanone solvent. The coatings were applied at a coating bath withdrawal rate of 300 millimeters / minute. After drying in a forced air oven, the charge generating layers had thicknesses of 0.2 micrometer. The drums were subsequently coated with charge transport layers containing N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1;-biphenyl-4,4'-diamine dispersed in polycarbonate (PCZ200, available from the Mitsubishi Chemical Company). The coating mixture consisted of 8 weight percent N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1'-biphenyl-4,4;-diamine, 12 weight percent binder and 80 weight percent monochlorobenzene solvent. The coatings were applied in a Tsukiage dip coating apparatus. After drying in a forced air oven for 45 minutes at 118°C, the transport layers had thicknesses of 20 micrometers. EXAMPLE X The drum of Example IX was overcoated with an overcoat layer of this invention. The charge transport layer was dip coated with a composition of 2 grams of the allyloxymethylatedpolyamide of Example I, 12.5 grams of methyl alcohol, 5 grams n-propanol, 2 grams of N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (DHTBD), 0.2 gram bis-(2-methyl -4-diethylaminophenyl) phenylmethane (BDETPM) dissolved in 0.5 gram tetrahydrofuran, 0.1 gram 2-methyl-3-butyn-2-ol, a Pt catalyst inhibitor available from Aldrich Chemical Co. ), 0.4 gram HDP-111 (hydride functional polysiloxane, available from Gelest Inc. Tully Town Pa.) and 0.3 gram Pt catalyst complex in xylene, also available from Gelest Inc, to form an overcoat. 4.5 micrometer thick overcoats were applied in the dip coating apparatus with a pull rate of 190 millimeters / min. Upon drying at 125°C for 30 minutes, the coating formed a hard glassy tough film having a dry thickness of 4.5 micrometers. This cross linked film exhibited increased abrasion resistance and retained mechanical strength when exposed to alcohol and hydrocarbon solvent, hexane for 0.5 hours. The photoreceptor was print tested in a Xerox 4510 machine for 500 consecutive prints. There was no loss of image sharpness, no problem with background or any other defect resulting from the overcoats. EXAMPLE XI The drum of Example IX was overcoated with an overcoat layer of this invention. The charge transport layer was dip coated with a composition of 2 grams of the allyloxymethylatedpolyamide of Example II, 12.5 grams of methyl alcohol, 5 grams n-propanol, 2 grams of N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (DHTBD), 0.2 gram bis-(2-methyl -4-diethylaminophenyl) phenylmethane (BDETPM) dissolved in 0.5 gram tetrahydrofuran, 0.1 gram 2-methyl-3-butyn-2-ol, ,a Pt catalyst inhibitor available from Aldrich Chemical Co. ), 0.4 gram HDP-111 (hydride functional polysiloxane available from Gelest Inc. Tully Town Pa.), and 0.3 gram Pt catalyst complex in xylene, also available from Gelest Inc, to form an overcoat. 4.5 micrometer thick overcoats are applied in the dip coating apparatus with a pull rate of 190 millimeters / min. Upon drying at 125°C for 30 minutes, the coating formed a hard glassy tough film having a dry thickness of 4.5 micrometers. This cross linked film exhibited increased abrasion resistance and retained mechanical strength when exposed to alcohol and hydrocarbon solvent, hexane for 0.5 hours. The photoreceptor was print tested in a Xerox 4510 machine for 500 consecutive prints. There was no loss of image sharpness, no problem with background or any other defect resulting from the overcoats. EXAMPLE XII An unovercoated drum of Example IX and overcoated drums of Example X and XI of this invention were tested in a wear fixture that contained a bias charging roll for charging. Wear was calculated in terms of nanometers / kilocycles of rotation (nm/Kc). Reproducibility of calibration standards was about ±2 nm/Kc. The wear of the drum without the overcoat of Example IX was greater than 80 nm/Kc. Wear of the overcoated drums of this invention of Examples X and Xl was ∼7nm/Kc. Thus, the improvement in resistance to wear for the photoreceptor of this invention, when subjected to bias charging roll cycling conditions, was very significant. EXAMPLE XIII One of the devices of Example III was overcoated with an overcoat layer material of this invention. The charge transport layer was coated with a composition of 2 grams of the allyloxymethylatedpolyamide of Example I, 12.5 grams of methyl alcohol, 5 grams n-propanol, 2 grams of N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (DHTBD), 0.2 gram bis-(2-methyl-4-diethylaminophenyl) phenylmethane (BDETPM) dissolved in 0.5 gram tetrahydrofuran, 0.1 gram 2-methyl-3-butyn-2-ol, a Pt catalyst inhibitor available from Aldrich Chemical Co., 0.1 gram 1,3-diphenyl-1,1,3,3-tetrakis (dimethyl siloxy) disiloxane (Gelest SiDY582.0), 0.1 gram methylhydrosiloxane-phenylmethylsiloxane copolymer, hydride terminated HPM-502 and 0.2 gram Gelest HDP-111and 0.3 gram Pt catalyst complex in xylene, (also available from Gelest Inc.), to form an overcoat. The film was cast using a 1 mil coating bar. The coating was dried in a forced air oven at 110°C for 30 minutes. The dried film had an average thickness of 3.5 micrometers. EXAMPLE XIV One of the devices of Example III was overcoated with an overcoat layer material of this invention. The charge transport layer was coated with a composition of 2 grams of the allyloxymethylatedpolyamide of Example II, 12.5 grams of methyl alcohol, 5 grams n-propanol, 2 grams of N,N'-diphenyl-N,N'-bis(3-hydroxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (DHTBD), 0.2 gram bis-(2-methyl -4-diethylaminophenyl) phenylmethane (BDETPM) dissolved in 0.5 gram tetrahydrofuran, 0.1 gram 2-methyl-3-butyn-2-ol, a Pt catalyst inhibitor (available from Aldrich Chemical Co.), 0.1 gram 1,3-diphenyl-1,1,3,3-tetrakis (dimethyl siloxy) disiloxane (Gelest SiDY582.0), 0.1 gram methylhydrosiloxane-phenylmethylsiloxane copolymer, hydride terminated HPM-502 and 0.2 gram Gelest HDP-111 and 0.3 gram Pt catalyst complex in xylene, also available from Gelest Inc., to form an overcoat. The overcoat film was cast using a 1 mil coating bar. The coating was dried in a forced air oven at 110°C for 30 minutes. The dried film had an average thickness of 3.5 micrometers. EXAMPLE XV Devices of Example XIII and XIV were tested for xerographic sensitivity and cyclic stability as explained in EXAMPLE VII. The residual potential was equivalent (15 volts) for both photoreceptors and no cycle-up was observed when cycled for 10,000 cycles in a continuous mode. The overcoat layers of this invention clearly did not introduce any deficiencies. Although the invention has been described with reference to specific preferred embodiments, it is not intended to be limited thereto, rather those having ordinary skill in the art will recognize that variations and modifications may be made therein which are within the spirit of the invention and within the scope of the claims.

Claims: An allyloxymethylatedpolyamide represented by Formulae I and II: wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000, R is an alkylene unit containing from 1 to 10 carbon atoms, between 1 and 99 percent of the R 2 sites are -H, and the remainder of the R 2 sites is between 25 percent and 99 percent -CH 2 -O-(CH 2 ) w -CH=CH 2 , wherein w is 1, 2 or 3, between 1 and 75 percent of the R 2 sites are -CH 2 -O-R 5 , and R 5 is an alkyl unit containing 1 to 4 carbon atoms, and wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000, R 1 and R are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms, between 1 and 99 percent of the R 3 and R 4 sites are -H, and between 25 percent and 99 percent of the remainder of the R 3 and R 4 sites are -CH 2 -O-(CH 2 ) w -CH=CH 2 , wherein w is 1, 2 or 3, and between 1 percent and 75 percent of the R 2 sites are -CH 2 -O-R 5 wherein R 5 is an alkyl unit containing 1 to 4 carbon atoms. An allyloxymethylatedpolyamide according to claim 1 wherein the allyloxymethylatedpolyamide is represented by the formula wherein R', R", R"' are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms, and n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000. A process for synthesizing an allyloxymethylatedpolyamide comprising reacting an alcohol soluble polyamide with formaldehyde and a linear double bond terminated alcohol. A process for cross linking an allyloxymethylatedpolyamide, the process being selected from the group consisting of heating an allyloxymethylatedpolyamide in the presence of a free radical catalyst, and hydrosilating a double bond of an allyloxy group of an allyloxymethylatedpolyamide with a silicon hydride reactant having at least 2 reactive sites. An electrophotographic imaging member comprising a substrate, at least one photoconductive layer, and an overcoat layer comprising a hole transporting hydroxy arylamine compound having at least two hydroxy functional groups, and a cross linked allyloxymethylatedpolyamide film forming binder. An electrophotographic imaging member according to claim 5 wherein the overcoat layer also comprises a cross linked polyamide formed by cross linking a cross linkable alcohol soluble polyamide polymer having methoxy methyl groups attached to nitrogen atoms of amide groups in the polymer backbone. An electrophotographic imaging member according to claim 5 wherein the overcoat layer also comprises a stabilizer. An electrophotographic imaging member according to claim 7 wherein the stabilizer is bis-(2-methyl-4-diethylaminophenyl)-phenylmethane. A process for overcoating an electrophotographic imaging member comprising providing an electrophotographic imaging member, forming a coating on the electrophotographic imaging member, the coating comprising a solution of a hole transporting arylamine compound, an alcohol and a cross linkable allyloxymethylatedpolyamide film forming binder, and curing the coating to cross link the allyloxymethylatedpolyamide film forming binder to form an overcoating layer. A process for overcoating an electrophotographic imaging member according to claim 9 wherein the solution also comprises a cross linkable alcohol soluble polyamide polymer film forming binder having methoxy methyl groups attached to nitrogen atoms of amide groups in the polymer backbone.

Inventors: DEFO PAUL J, FULLER TIMOTHY J, LIMBURG WILLIAM W, NOLLEY ROBERT W, PAI DAMODAR M, RENFER DALE S, WARD ANTHONY T, YANUS JOHN F, DEFO, PAUL J., FULLER, TIMOTHY J., LIMBURG, WILLIAM W., NOLLEY, ROBERT W., PAI, DAMODAR M., RENFER, DALE S., WARD, ANTHONY T., YANUS, JOHN F.
Applicants: XEROX CORP, XEROX CORPORATION
Application year: 1999
Main classification: C08G69
IPC codes: C08G69, G03G5, C09D179, C08F299