LAUNDRY CARE PRODUCTS AND COMPOSITIONS

Abstract: A fabric treatment article for use in a clothes dryer comprises a substrate and a fabric treatment composition comprising at least one laundry benefit agent in an amount effective for reducing wrinkles, stains or odours in clothing applied to the substrate. The substrate is either: (i) a sheet having first and second sides, each side having similar dimensions and raised and depressed portions, wherein between 0.02-0.07 grams of the fabric treatment composition is applied per square centimetre of the sheet, (ii) or a sheet with first and second sides having similar dimensions wherein at least part of the first side has one colour and at least a part of the second side has a different colour. Alternatively, the composition comprises between 0.1-5 wt.% of fabric benefit agent selected from ethoxylated organosilicones; polyalkyleneoxide modified polydimethylsiloxane; linear aminopolydimethylsiloxane polyalkyleneoxide copolymers; sulphated/sulphonated vegetable oils; high molecular weight polyacrylamides; betaine siloxane copolymers; or alkylactam siloxane copolymers. A method of reducing the occurance of wrinkles in laundered clothing is also provided.

Description: LAUNDRY CARE PRODUCTS AND COMPOSITIONS Technical Field The present invention relates to laundry care products and compositions, in particular to fabric treatment articles for use in a laundry drying apparatus and to a method of treating soiled fabric. Background and Prior Art Commercial products available for the care of clothing and fabrics in the home are well known. These products include liquid, powder and tablet detergents, liquid and sheet fabric softeners and other various products. Professional services, such as dry cleaners, are also widely available for cleaning garments subject to shrinkage or for those that are too delicate for common washer/dryer cycles. Typically, desired results from dry cleaning/laundering clothing is stain removal, odour removal, softening, static removal and reduced wrinkling. It is not uncommon for a garment that has recently been cleaned but briefly used to lose those properties that are generally associated with freshly cleaned clothing. Indeed, depending on the environment a fabric is subjected to, odours, wrinkles, small stains and the like can quickly render the fabric "unclean" in the eye of the user. For example, a relatively brief exposure to tobacco smoke can leave a noticeable lingering odour on otherwise clean clothing. It is also common for clean clothing to become wrinkled before they are worn, such as when the clothes are packed in a suitcase for travel. Typically, these otherwise clean clothes are either tolerated by the user or sent back through an entire cleaning process. Therefore, there is a need for a convenient, cost effective and efficient means for reviving clothing that is not in need of a complete laundering or dry cleaning cycle. At least one commercially available product marketed by The Procter & Gamble Company under the name "Dryel", seeks to allow for treatment of clothing in the home dryer. U.S. Patent No. 5,681,355 is marked on the product and is incorporated herein by reference . The Dryel product consists of a plastic bag, a premoistened cloth, bottled stain removal solution and an absorbent pad for use with the stain removal solution. The user is instructed to: 1) completely remove spots and stains prior to placing garments in the bag, preferably by placing the absorbent pad under the garment; 2) add one to four garments to the bag; 3) insert a pre-moistened cloth into the bag containing the garments; 4) seal the bag; 5) tumble the bag, garments and cloth in the dryer for 30 minutes at medium to high heat; and 6) hang the garments promptly to help decrease wrinkling. Users of the Dryel product have complained about the need for a bag and its limited capacity and the potential for entrapment, rather than removal, of particulates . Also, the use of the bottle/pad combination to remove stains adds to the complexity of the process. Therefore, there is also a need for a home garment cleaning process and product that does not have the known drawbacks of the Dryel product . Such a product and process would preferably eliminate the need for a garment bag and simplify the stain removal process . It is also known to use chemicals in clothes dryers to soften, freshen and reduce static on garments. Fabric softener dryer sheets have been used for these purposes for decades and are described, for example, in U.S. Patent Nos.: 4,237,155; 4,238,531; 4,327,133; 4,421,792, 5,094,761; 5,234,610; 5,348,667; and 5,376,287; all of which are incorporated herein by reference. To be effective, however, dryer sheets generally need to interact with damp clothing in order to deliver their intended benefits. As such, these dryer sheets are particularly suited for processing garments after removal from the washing machine and not for dry clothing in need of freshening. Therefore, there is need for a fabric freshening, softening and/or static removing product that can deliver the desired benefits to relatively dry clothing. Furthermore, as previously discussed, the ability to reduce or eliminate wrinkles on relatively clean clothing is also desired. Known attempts to reduce wrinkles by means of chemical ingredients in the wash include the use of zwitterionic surfactants, aminosilicones, curable aminosilicones, cellulose enzymes and alkyl amides. However, each of these ingredients have one or more drawbacks. For example, zwitterionic surfactants are believed to work best in cold water. Aminosilicones can cause yellowing and can be difficult to formulate. Curable aminosilicones require the heat of an iron to reduce wrinkles. Cellulase enzymes generally require several wash cycles before anti-wrinkle benefits become noticeable. Alkyl amides are not very effective relative to other wrinkle reducing agents. Therefore, there is a need for wrinkle reducing formulations and products that can be used in conventional home dryers on relatively dry garments. Such formulations and products would preferably not require the undesirable bag required by the aforementioned Procter & Gamble Dryel cleaning kit. Definition of the Invention Accordingly the present invention provides a fabric treatment article comprising, in combination, a substrate for use in a drying apparatus and a fabric treatment composition applied to the substrate, the fabric treatment composition comprising at least one laundry benefit agent in an amount effective for reducing wrinkles, stains or odours in clothing, wherein the substrate is a non-woven sheet having first and second primary sides, each side having generally the same dimensions and having a plurality of raised and depressed portions, and wherein one side of the substrate sheet has a surface area of X square inches ( square centimetres) and the fabric treatment composition is applied to the substrate from between about 0.14 to about 0.42 grams of the fabric treatment composition per square inch (about 0.02 to 0.07 grams per square centimetre) of the substrate sheet . The invention also provides a fabric treatment article comprising, in combination, a substrate for use in a drying apparatus and a fabric treatment composition applied to the substrate, the fabric treatment composition comprising at least one laundry benefit agent in an amount effective for reducing wrinkles, stains or odours in clothing, wherein the substrate is a sheet having first and second primary sides having generally the same dimensions and wherein at least a portion of the substrate sheet first side has a first colour and at least a portion of the substrate sheet second side has a second colour different from the first colour. The invention further provides a fabric treatment article comprising, in combination, a substrate for use in a drying apparatus and a fabric treatment composition applied to the substrate, the fabric treatment composition comprising between about 0.1 wt % to about 5 wt % of fabric benefit agent selected from the group consisting of: ethoxylated organosilicones; polyalkyleneoxide modified polydimethylsiloxane; linear aminopolydimethylsiloxane polyalkyleneoxide copolymers; sulphated/sulphonated vegetable oils; high molecular weight polyacrylamides; betaine siloxane copolymers; and alkylactam siloxane copolymers . The invention further provides a method of treating a soiled fabric comprising the steps of: providing a substrate having a fabric treatment composition applied thereto, the fabric treatment composition having at least one ingredient useful for removing stains; (i) providing a soiled fabric having at least one identifiable stain; (ii) rubbing a portion of the substrate on the identifiable stain, thereby transferring at least a portion of the fabric treatment composition to the fabric; (iv) placing the fabric and the substrate in a drying apparatus; and (v) running the drying apparatus . Detailed Description of the Invention The present application relates to a product for use in a conventional home clothes dryer that delivers one or more desirable benefits to clothing in need of freshening. The product is particularly suited for delivering the benefits to relatively dry clothing and can be added directly to the dryer without the need for a bag to contain the product and clothing during the dryer cycle . In a preferred embodiment, chemicals suitable for providing one or more of the above desirable benefits are applied to a substrate, such as a fabric-like sheet, that can be added directly to the dryer with the clothing. After running the dryer for a period of time, the freshened clothes are removed. A surprising finding is that a de-wrinkling effect can be achieved from a moist sheet in a relative short period of time. For example, de-wrinkling is evident in about 10-20 minutes using a 12" x 12" (about 30.5 cm x 30.5 cm) substrate containing about 40g to about 45g of fabric treatment agent. In a most preferred embodiment, the fabric treatment agent is in liquid form and, for simplicity, the fabric treatment agent will be referred to as a liquid. However, the term "fabric treatment agent" will be understood to encompass formulations other than liquids, such as gels, creams and the like. The substrate is preferably absorbent enough to hold a suitable amount of liquid product to deliver the desired benefits and, at the same time, not be overly saturated so as to drip or otherwise release liquid in an undesirable manner. Nonetheless, the substrate must also suitably release its liquid contents. In the disclosed embodiment wherein the substrate/liquid is intended to deliver cleaning benefits, it is preferred that the user can rub the substrate directly on noticeable stains/spots to remove or reduce the appearance of the stains/spots. The same substrate can then be added to the dryer with the clothing to complete the freshening/cleaning process. This embodiment eliminates the cumbersome bottle/pad combination for stain removal in the Dryel product . With respect to wrinkle reduction, the ingredients that deliver this benefit are believed to lubricate fibre surfaces. By lubricating the fibre surfaces of garments, for example, the fibres slide more easily relative to each other and are less likely to entangle, resulting in less wrinkles. The preferred fibre lubricants disclosed herein have been shown to noticeably reduce the number of wrinkles, The preferred embodiments also overcome one or more of the above noted disadvantages of prior wrinkle reducing agents or methods . Brief Description of the Drawings Figure 1 is a top plan view of a first embodiment of a preferred substrate; Figure 2 is a side elevational view of a portion of figure l; Figure 3A is a side elevational view in partial cross section of figure 1; Figure 3B is a side elevational view in partial cross section of an alternate embodiment of the substrate illustrated in figure 1; Figure 4 is a partial top perspective view of an alternative embodiment of a preferred substrate; and Figure 5 is a top view of an alternative embodiment of a preferred substrate. Detailed Description of Preferred Embodiments Turning to figure 1, a first embodiment of a preferred substrate 10 is shown having dimensions X and Y. Preferably, X is approximately 12" (about 30.5 cm) and Y is approximately 12" (about 30.5 cm) . However, it is clearly within the scope of the invention to have dimensions X and Y different, smaller or larger depending on the amount of active ingredients desired to be placed in the dryer. It is also not necessary that the substrate be relatively flat or rectangular. When the substrate is a sheet, it preferably has first and second primary sides having generally the same dimensions, such as upper and lower layers 16a and 16b of substrate 10. With reference to figures 2 and 3A, substrate 10 is fabricated from an inner layer 18 surrounded by upper and lower layers 16a and 16b. Preferably, inner layer 18 is an absorbent material that facilitates liquid retention while outer layers 16a and 16b are hydrophobic . In a most preferred embodiment, inner layer 18 is a 50/50 polypropylene/rayon blend and outer layers 16a and 16b are polyester. Because these layered materials are heat sensitive, application of heat can weld the materials together to create patterns such as those shown in figures 1-3B. Figures 2-3B show welds 12a joining the materials together and unwelded portions 14 that create a "puffiness" to the substrate. Most preferably, the outer edges of substrate 10 has weld 11 that seals the substrate's periphery. With respect to figure 3B, additional layers 20a and 20b are disposed between inner layer 18 and outer layers 16a and 16b. In this embodiment, inner intermediate layers 20a and 20b are preferably polyproplene material. Any suitable combination of polymeric materials can be used, however, it is most preferred that the outer layer be hydrophobic so as to inhibit excessive transfer of liquids to clothing during the freshening process. It is also preferred that the outer layer has a melting point above that which can be present within a dryer during a drying cycle . Turning to figure 4, an alternative substrate is shown, in this embodiment, substrate 30 has alternating raised and depressed rectangular areas 32 and 34 respectively. In a most preferred embodiment, this particular substrate is a 50/50 rayon/PET blend, wherein the fabric is preferably non- woven. Substrates, such as that shown in figure 4, are available from PGI located in North Carolina, USA. Yet another alternative embodiment is shown in figure 5. This particular fabric substrate, 40, is preferable polyester, rayon, or a combination of both. Substrate 40 has a plurality of holes 42 passing there through in a determined pattern. Substrates, such as those shown in figure 5, are available from PGI (under the Miratec trademark) . In each of the above substrate embodiments, it is preferable to have at least a portion of one side the substrate coloured differently than a portion of the other. For example, top layer 16a of substrate 10 can be white while bottom layer 16b can be at least partially blue and, most preferably, all blue. Difference in colour is herein defined as a difference in colour or colour intensity, i.e., 16a can be light blue while 16b can be a darker shade of blue. Of course, other colours pleasing to the consumer can also be used. In order to provide colour to the non-woven substrate of figure 4, dyed fibres can be used during a portion of the non-woven manufacturing process. For example, white fibres are used/visible on one side of the substrate while blue fibres are used/visible on the other side of the substrate. When used in a dryer to freshen clothing, it has been found that it preferable to deliver between about 20 and about 60 grams of liquid agent to the dryer load of 1-4 garments. It has further been found that when the above described fabric substrate sheets are in a dimension of approximately 12" x 12" (about 30.5 cm x 30.5 cm) and have a dry weight of about 3.5g per square yard (about 2.93 g per square metre), 40 grams of liquid material can be absorbed thereon and be properly delivered to the dryer. This calculates to about 0.29 grams per square inch (about 0.045 grams per square centimetre) . If 45 grams of liquid are desired, this calculates to about 0.31 grams per square inch (about 0.048 grams per square centimetre) . In embodiments where the fabric substrate is 12" x 12" (about 30.5 cm x 30.5 cm), and the preferred liquid quantity is between 20 and 60 grams, the substrate delivers approximately 0.14 grams per square inch to about 0.42 grams per square inch (about 0.02 grams per square centimetre to about 0.065 grams per square centimetre) . As such, once a preferred quantity of liquid to be delivered to the dryer is known, it is possible to determine the area of substrate required. In addition, if a heavier substrate is used, it is possible to deliver greater quantities of liquid to the dryer without increasing the length and width dimensions of the substrate. As previously discussed, while the preferred substrates disclosed herein are square, it is clearly within the scope of the present invention that other shapes, such as circles, triangles and odd shapes, can also be used to deliver the proper amount of liquid. Several molecules have been identified for wrinkle reduction and other benefits, such as static reduction benefits when included on one of the above-identified substrates and used on clothing in a dryer. Using the American Association of Textile Chemists and Colorists (AATCC) method # 124 (described in greater detail, below), the following molecular classes were found to be effective on test cloths: ethoxylated organosilicones; polyalkyleneoxide modified polydimethylsiloxane; linear aminopolydimethylsiloxane polyalkyleneoxide copolymers; sulphated/sulphonated vegetable oils; high molecular weight polyacrylamides; betaine siloxane copolymers; and alkylactam siloxane copolymers. Of the foregoing, the most preferred wrinkle reducing agent is a polyalkyleneoxide modified polydimethyl siloxane sold under the name Silwet L-7622, available from Witco, Greenwich, CT, USA. Adogen 66, a tallow alkyl BIS (polyethoxy) ethyl ammonium, ethyl sulfate, also available from Witco can be used in combination with one or more of the above compounds to reduce static. Use with Silwet L- 7622 is preferred. One or more of the molecules/compounds from the above- identified classes are preferably formulated in an amount from about 0.1 wt % to about 5 wt % and most preferably from about 0. 3 wt % to about 1.5 wt %. Particularly preferred examples are set forth, below. The following sets forth preferred fabric treatment formulation ranges suitable for use with a substrate: PREFERRED FORMULATION RANGES The microbiocide can be eliminated if the other ingredients provide suitable biocidal activity. For example, it is believed that glycerol triacetate can provide such suitable activity. Laboratory tests have shown that when the formulations referred to herein are absorbed onto a substrate, such as shown in the figures, and placed in a dryer with clothing, one or more of the identified clothing benefits are achieved, In addition, the formulations have been found effective in stain removal . Stain removal can be achieved before the dryer is activated by rubbing a portion of the substrate, such as a corner, on the stained area. The substrate having formulation absorbed therein is preferably enclosed in a hermetically sealed pouch. The pouch will preferably inhibit egress of the chemical agents and inhibit ingress of bacteria and other foreign matter. One or more of the pouches can be packed in an enclosed carton for commercial sale. The pouch is preferably manufactured from a heat sealable, foil laminate material. To freshen clothing, the user simply removes the substrate from the pouch, removes stains by rubbing as needed, places the clothes and substrate into a dryer and runs the dryer. Agents will act on the clothing to reduce wrinkles, reduce odours, reduce stains and/or reduce static. During this process the substrate can contact the inner surfaces of the dryer. The process, as previously discussed, is effective and suitable for use on relatively dry clothing. While the presently disclosed preferred embodiments provide a clear advantage over the Procter & Gamble Dryel product, it is within the scope of the present disclosure to use the preferred chemicals and substrates, and their equivalents, within the confines of a dryer bag. As such, the use of one or more of the above preferred embodiments within a bag for use in a dryer is also deemed to be within the scope of this disclosure . Test Method A preferred method of measuring wrinkle reduction is by using the American Association of Textile Chemists and Colorists' (AATCC) method # 124, Appearance of Fabrics after Repeated Home Laundering. In this method, four cloth types (silk, rayon, cotton, and linen) are washed, dried and stored in a well defined way. The dried cloths are then evaluated for wrinkle content by comparison with wrinkle smoothness replicas which can be purchased from AATCC. Factors such as the light used, the angle of the cloths and replicas to the light, and the background are carefully controlled and described in the method. There are six replicas with values of 1, 2, 3, 3.5, 4, and 5 with 5 being perfectly smooth and 1 being very wrinkled. Three trained observers are asked to give a value of 1-5, to the nearest 0.5 unit, to each cloth based on which replica it most closely resembles. The results are totaled and averaged over the three observers for each cloth type . According to the method, a difference of > 0. 17 between the results for two products indicates there is a significant difference at the 95% confidence level. A difference of greater than or equal to 0.25 indicates a significant difference at the 99% confidence level . The compositions may be prepared by any suitable method. Further modifications can also be made without departing from the spirit of this disclosure. Examples The following examples are preferred formulations suitable for use with a substrate. Other formulations within the scope of the present invention will be apparent to the person skilled in the art. While particularly preferred wt % active levels are disclosed, the particular wt . % in the final formulation for each ingredient can vary from that which is particularly disclosed. Such wt . % levels are considered to be within the scope of the present disclosed. Formulation 1 Formulation 2 Formulation 3 * Available from Freedom Chemical company, Charlotte NC

Claims: CLAIMS 1. A fabric treatment article comprising, in combination, a substrate for use in a drying apparatus and a fabric treatment composition applied to the substrate, the fabric treatment composition comprising at least one laundry benefit agent in an amount effective for reducing wrinkles, stains or odours in clothing, wherein the substrate is a non-woven sheet having first and second primary sides, each side having generally the same dimensions and having a plurality of raised and depressed portions, and wherein one side of the substrate sheet has a surface area of X square inches (W square centimetres) and the fabric treatment composition is applied to the substrate from between about 0.14 to about 0.42 grams of the fabric treatment composition per square inch (about 0.02 to 0.07 grams per square centimetre) of the substrate sheet. 2. The article according to claim 1, wherein X is about 144 square inches (W is about 930 square centimetres) and between about 20 grams to about 60 grams of the fabric treatment composition, preferably about 40 to about 45 grams, is applied to the substrate sheet. 3. A fabric treatment article comprising, in combination, a substrate for use in a drying apparatus and a fabric treatment composition applied to the substrate, the fabric treatment composition comprising at least one laundry benefit agent in an amount effective for reducing wrinkles, stains or odours in clothing, wherein the substrate is a sheet having first and second primary sides having generally the same dimensions and wherein at least a portion of the substrate sheet first side has a first colour and at least a portion of the substrate sheet second side has a second colour different from the first colour. 4. The article according to claim 3, wherein the first colour is white and the second colour is blue. 5. A fabric treatment article comprising, in combination, a substrate for use in a drying apparatus and a fabric treatment composition applied to the substrate, the fabric treatment composition comprising between about 0.1 wt % to about 5 wt % of fabric benefit agent selected from the group consisting of: ethoxylated organosilicones; polyalkyleneoxide modified polydimethylsiloxane; linear aminopolydimethylsiloxane polyalkyleneoxide copolymers; sulphated/sulphonated vegetable oils; high molecular weight polyacrylamides; betaine siloxane copolymers; and alkylactam siloxane copolymers . 6. The article according to claim 5, wherein the fabric treatment composition further comprises polyalkyleneoxide modified polydimethylsiloxane. 7. The article according to claim 7, wherein the fabric treatment composition comprises about 2 wt % polyalkyleneoxide modified polydimethylsiloxane. 8. The article according to claim 5, wherein the fabric treatment composition further comprises an effective amount of a tallow alkyl BIS (polyethoxy) ethyl ammonium, ethyl sulfate for reducing static. 9. The article according to claim 5, wherein the substrate is a sheet having first and second primary sides having generally the same dimensions. 10. The article according to claim 9, wherein one side of the substrate sheet has a surface area of X square inches (W square centimetres) and the fabric treatment composition is applied to the substrate from between about 0.14 to about 0.42 grams of the fabric treatment composition per square inch (about 0.02 to 0.07 grams per square centimetre) of the substrate sheet. 11. The article according to claim 9, wherein the substrate is a sheet having a surface area of about 144 square inches (about 930 square centimetres) and between about 20 grams to about 60 grams of the fabric treatment composition is applied thereto. 12. The article according to claim 9, wherein at least a portion of the substrate sheet first side has a first colour and at least a portion of the substrate sheet second side has a second colour different from the first colour. 13. The article according to claim 12, wherein the first colour is white and the second colour is blue. 14. A method of treating a soiled fabric comprising the steps of : (i) providing a substrate having a fabric treatment composition applied thereto, the fabric treatment composition having at least one ingredient useful for removing stains; (ii) providing a soiled fabric having at least one identifiable stain; (iii) rubbing a portion of the substrate on the identifiable stain, thereby transferring at least a portion of the fabric treatment composition to the fabric; (iv) placing the fabric and the substrate in a drying apparatus ; and (v) running the drying apparatus .

Inventors: BISHOP CAROL CALDWELL, CICCIARI KARLA JEAN, GOMES FILOMENA AUGUSTA, HAUBERT HARRY HAMILTON, MURPHY DENNIS STEPHEN, ZUCKER SHERRYL ILANA, BISHOP, CAROL, CALDWELL, CICCIARI, KARLA, JEAN, GOMES, FILOMENA, AUGUSTA, HAUBERT, HARRY, HAMILTON, MURPHY, DENNIS, STEPHEN, ZUCKER, SHERRYL, ILANA
Applicants: LEVER HINDUSTAN LTD, UNILEVER NV, UNILEVER PLC, HINDUSTAN LEVER LIMITED
Application year: 1999
Main classification: C11D17
IPC codes: C11D3, C11D11, C11D17