High strength, storage stable, anthraquinone blue dye solutions

Abstract: The present invention provides a dye solution of anthraquinone blue dyes in a non-polar organic solvent, which dyes are a mixture of dyes of the general formula: where the Rs on each compound are selected from 2-ethylhexyl, mixed amyl, n-butyl and methyl, and wherein said dye mixture is the reaction product of quinizarin and/or leuco quinizarin and between 15 and 35 mole % of each of 2-ethylhexylamine, n-butylamine, amylamine and methylamine. The dye solutions, at high concentrations, are stable at low temperatures. These dye solutions also provide high tinctorial strength.

Description: The present invention is directed to aminoanthraquinone blue colorants, more particularly to anthraquinone dye solutions which can be highly concentrated and which at high concentrations exhibit stability at low temperatures. Background of the Invention U.S. Patent Application 08/911,889 (US 5 756 844), is directed to a method of producing aminoanthraquinone blue colorants. The method set forth therein reacts quinizarin and/or its leuco derivative with a mixture of aliphatic amines, wherein the reaction is carried out in the presence of a glycol and/or a glycol ether. Subsequent to the reaction, excess amine and water are removed, leaving a highly concentrated solution of dyes in the glycol or glycol ether. The solution can be directly diluted with a non-polar aromatic solvent to provide a dye solution of high concentration. While U.S. Patent application 08/911,889 (US 5 756 844) described the production of highly concentrated dye solutions, experience has shown that there is a limit to the concentration of such solutions if they are subject to exposure to low temperatures, e.g., -20°C, during shipping and handling. There has been a need to have even more highly concentrated dye solutions which are stable at low temperatures, i.e., down to -20°C. The present invention is directed to a dye solution which is the reaction product of quinizarin and/or leuco-quinizarin and a mixture of four particular amines in specific relative molar ratios, which dye solution can be highly concentrated, yet stable at low temperatures, e.g., down to -20°C. Summary of the Invention In accordance with the invention there is provided a dye solution which is a mixture of dyes of the general formulae: where the R's on each compound are selected from the group consisting of 2-ethylhexyl, mixed amyl, n-butyl and methyl, and wherein the dye mixture is the reaction product of quinizarin and/or leuco quinizarin and between about 15 and about 35 mole%, preferably between about 20 and about 30 mole %, of each of 2-ethylhexyl amine, n-butyl amine, amyl amine, and methylamine. Concentrated solutions, i.e., 40 wt% or more, preferably 50 wt% or more, most preferably 60 wt% or more exhibit excellent low-temperature stability. Detailed Description of Certain Preferred Embodiments As described in above-referenced U.S. Patent Application 08/911,889 (US 5 756 844), the reaction which forms aminoanthraquinone dyes is preferably carried out in the presence of a glycol and/or a glycol ether. Preferably, the reaction is carried out in between 2.05 to 2.50 moles of amine per mole of quinizarin. After the reaction is completed, water and excess amine are removed, leaving a homogeneous anthraquinone dye solution. Subsequently, the solution is diluted to its end-use concentration with a non-polar aromatic solvent. Such non-polar aromatic solvents include, but are not limited to, toluene, xylene, naphthenics, heavy aromatic solvent naphthas, etc. This particular combination of amines used to form the dye solutions of the present invention can be used to produce very concentrated solutions; these concentrated solutions are stable at low temperature. Solutions as concentrated as 53 wt% in non-polar aromatic solvents are stable to -20°C. That is, at this temperature, the dye does not precipitate and the solution remains a liquid. The anthraquinone blue dye solutions of the present invention have high tinctorial strength. That is, these dyes have high spectral strength relative to their weight percent in solution. The high tinctorial strength of such dye solutions are important for certain applications. The invention will now be described in greater detail by way of specific examples. Examples 1-8 (1-4 and 6-8 comparative) An anthraquinone dye solution in accordance with the invention (Example 5) was prepared as follows: A mixture of 33.9 g leuco-quinizarin, 134.5 g quinizarin, 69 g dipropylene glycol monomethyl ether, 48.9 g 2-ethylhexylamine, 32.9 g amylamine, 27.6 g butylamine, and 11.7 g methylamine were gradually heated over about 1 hour to 100°C and maintained at this temperature for a further 6 hours. The product was cooled to 85°C and air passed through for 4 hours. Excess amine and water of reaction were removed by vacuum distillation and 265 g of a high flash solvent were added. The product was screened to remove insoluble material. Comparative Examples 2-4 and 6 were similarly prepared but with different amine ratios. Comparative Example 7 was similarly prepared but with a different amine mixture. Comparative Examples 1 and 8 are made from different amine mixtures. Table 1 below gives the relative molar ratio of amines in the various samples. "Relative strength %" is the relative weight percent relative to Comparative Example 1 (Automate® Blue 8). Example 1 2 3 4 5 6 7 8 2-ethylhexylamine 61.3 39.0 49.0 30.0 25.0 20.0 45.0 30.0 amylamine 26.2 32.0 27.0 30.0 25.0 20.0 45.0 25.0 n-butylamine 19.5 14.5 25.0 25.0 20.0 methylamine 12.5 9.5 9.5 10.0 25.0 40.0 5.0 15.0 methoxypropylamine 5.0 30.0 relative strength % 100 100 121 121 121 121 121 121 stability @ ambient fluid fluid fluid fluid fluid fail slurry fluid stability @ -10°C fluid poor solid poor fluid solid fluid stability@ -20°C fluid lumps fluid solid fluid Table 2 below compares Example 5 diluted to various weight percentages relative to Example 1 (calculated at 100) and gives spectral strength relative to Example 1 (calculated at 100). Tinctorial gain is calculated by dividing the relative spectral strength by the relative weight percent. Example 1 8 5 5 5 5 dye wt% 37.6 41.5 41.8 53.0 55.4 60.9 relative (weight) 100 119.9 111.2 141.0 147.3 162.0 relative (spectral) 100 121.6 121.6 154.1 161.0 176.9 tinctorial gain 1.00 1.01 1.09 1.09 1.09 1.09. It can thus be seen that the anthraquinone of the present invention can be provided at high weight strength, is stable in solution at low temperatures down to -20°C, and provides enhanced tinctorial gain relative to related commercial blue dyes.

Claims: A dye solution of anthraquinone blue dye in a non-polar organic solvent, which dye comprises a mixture of dyes of the general formula: wherein the R's on each dye in the mixture are selected from 2-ethylhexyl, mixed amyl, n-butyl and methyl, and wherein said dye mixture is the reaction product of quinizarin and/or leuco quinizarin and between 15 and 35 mole % of each of 2-ethylhexylamine, n-butylamine, amylamine and methylamine. A dye solution according to claim 1 wherein said dye mixture is the reaction product of between 20 and 30 mole % of each of said amines with quinizarin and/or leuco quinizarin, wherein 2.05 to 2.50 moles of amine is reacted per mole of quinizarin and/or leuco quinizarin. A dye solution according to claim 1 or claim 2 wherein said dye mixture is dissolved in the non-polar organic solvent in an amount of at least 40 wt.%. A dye solution according to claim 3 wherein said dye mixture is dissolved in the non-polar organic solvent in an amount of at least 50 wt.%. A dye solution according to claim 4 wherein said dye mixture is dissolved in the non-polar organic solvent in an amount of at least 60 wt.%.

Inventors: BAXTER RODERICK D, CRANMER JOHN P, BAXTER, RODERICK D., CRANMER, JOHN P.
Applicants: MORTON INT INC, MORTON INTERNATIONAL, INC.
Application year: 1999
Main classification: C09B67
IPC codes: C09B67