Photographic element containing yellow dye-forming photographic coupler

Abstract: A photographic element comprises a silver halide emulsion layer having associated therewith a dye-forming coupler having Formula F-1: wherein: (1) W 1 is a heteroatom or heterogroup; (2) one of W 2 and W 3 is hydrogen or a substituent group and the other is a group of Formula F-2: in which X is hydrogen or a coupling-off group and Y and Z are independently selected hydrogen or a substituent; and (3) W 4 is a group of atoms necessary to form a fused ring with the ring containing W 1 ; (4) provided that substituents may join to form a ring. The yellow coupler provides yellow density useful for photographic purposes.

Description: FIELD OF THE INVENTION This invention relates to a photographic element containing a silver halide emulsion layer having associated therewith a dye forming coupler based on an annulated heterocyclic ketoacetamido compound. BACKGROUND OF THE INVENTION Conventional color photographic images are formed via a chromogenic development process. After exposure of a color photographic element, the object scene is stored as a composite of red, green and blue silver halide latent images. During the color development process, these silver halide latent images are reductively developed, and an oxidation product of this development reacts with cyan, magenta and yellow dye-forming couplers to provide the desired subtractive primary color images. The composite dye image is then formed by the superpositioning of the cyan, magenta and yellow dye images to afford a reproduction of the original scene. The controlled conversion of silver halide latent image to color dye image is the goal of color photographic chemistry. The yield of dye color density from each unit of silver halide developed is a measure of coupler activity. The higher the activity of a coupler the less silver halide is needed to allow effective image formation. The reduction in the amount of silver halide used in a photographic systems can lead to improved photographic image reproduction, lower cost photographic products, and less potential environmental damage from development processes. Coupler activity, as defined herein, is composed of two prime factors: (1) the efficiency of the dye formation process, i.e ., the chemistry converting coupler to dye, and (2) the light absorption properties of the chromogenically formed dye, i.e. , the dye's spectral bandshape and extinction. Improvements in dye extinction can lead to desirable improvements in coupler activity and thereby to silver halide reductions. Two further important features of photographic reproductions are their color fidelity and their image stabilities. To efficiently reproduce a wide gamut of hues, the dyes comprising the color image must exhibit relatively sharp cutting spectral curves. Additionally, the dyes' spectral response curves must be carefully placed, i.e., have a well positioned maximum absorption and curve shape, to afford the best possible color reproduction. Color photographic images slowly degrade when stored under ambient conditions. Pictures held in the dark, that is, stored in albums, boxes or slide trays and not exposed to direct light, degrade primarily via hydrolytic mechanisms. Images exposed to light fade both via the hydrolytic mechanisms as well as via photochemical processes. The stability of a color image is clearly dependent upon the stabilities of its component dyes. It is apparent from these considerations that the hydrolytic stability of photographic dyes is of primary importance to image stability. The destruction of photographic dyes may be catalyzed by either acids or bases; dyes that are robustly stable to various hydrolytic conditions will provide more stable photographic images. Various efforts have been undertaken to provide a yellow dye-forming coupler that exhibits an improved combination of activity and image stability. A new class of photographic yellow couplers was recently patented by Bernard Clark, et al. in U.S. Patent No. 5,674,667. This patent discloses a novel class of pyrroloyl-acetanilide couplers that exhibit a combination of improved dye contrast and dye stability. In concert these characteristics were found to be comparable or superior to the couplers used in commercial photographic products. Comparative examples of this art are found hereinafter (Cmp-1 through Cmp-4). Additionally, U.S. Patent No. 5,213,958 describes a structurally dissimilar N-acylacetamido or malonamide coupler technology (having the acyl group bonded directly to the azole nitrogen). As shown hereinafter, these compounds are deficient in hydrolytic stability and activity. U.S. Patent No. 2,331,326 discloses a new class of heterocyclic yellow couplers containing an oxygen or sulfur heteroatom. U.S. Patent No. 3,227,554 discloses a wide collection of couplers that are useful DIR releasing couplers. One is a benzofuroyl coupler. In spite of the efforts to obtain improved yellow couplers, there is still a need for a new coupler that provides yellow dye-forming ability useful for imaging. SUMMARY OF THE INVENTION The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler having Formula F-1: wherein: (1) W 1 is a -NR- or -SO 2 - group where R is hydrogen or a substituent; (2) one of W 2 and W 3 is a substituent group and the other is a group of Formula F-2: in which X is hydrogen or a coupling-off group and Y and Z are independently selected from hydrogen or a substituent; and (3) W 4 is a group of atoms necessary to form a fused ring with the ring containing W 1 ; (4) provided that substituents may join to form a ring. The invention also provides a process for forming an image. The element provides yellow dye-forming ability useful for imaging. DETAILED DESCRIPTION OF THE INVENTION The photographic element of the invention incorporating the coupler useful in the invention provides yellow dye density and other useful properties for a photographic imaging processes. In addition, embodiments of the invention provide an improved spectral response. Many characteristics of a photographic image depend upon the spectral response of the dyes forming that image. The greater the coupler reactivity and the molar extinction of the image-forming dye the less silver is needed to produce that dye. Lower silver laydowns can enable sharper photographic images and other advantages. The color of a dye depends upon the position of its maximum light absorption (λmax) and the shape of the absorption curve. With yellow dyes, the deeper the λmax of the dye the more orange the color of the dye. Orange dyes cannot be employed to effectively reproduce bright lemon yellows. Thus lighter yellow dyes are preferred for better color reproduction. Finally, the ideal yellow dye absorbs only light in the blue portion of the visible spectrum; yellow dyes that absorb substantial amounts of green light appear desaturated and therefore yield poorer color reproduction. The bathochromic (long wavelength side) one-half bandwidth (B1/2BW) is a good measure of the degree of unwanted absorption of a particular yellow dye. The B1/2BW is the distance on the dye's spectral response curve, in nanometers, from the λ-max to the wavelength of 1/2 the maximum absorption. The smaller the B1/2BW distance, the more sharp-cutting is the spectral response of a dye and the better the color reproduction available from the dye. As another advantage, embodiments of the invention exhibit improved dye stability. In one aspect, the invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler having Formula F-1: wherein: (1) W 1 is a -NR- or -SO 2 - group where R is hydrogen or a substituent; (2) one of W 2 and W 3 is a substituent group and the other is a group of Formula F-2: in which X is hydrogen or a coupling-off group and Y and Z are independently selected from hydrogen or a substituent; and (3) W 4 is a group of atoms necessary to form a fused ring with the ring containing W 1 ; (4) provided that substituents may join to form a ring. W 1 is -SO 2 - or -N(R)- where R is hydrogen or a substituent (as described hereinafter). Desirably, W 1 is -N(R)- with R suitably being hydrogen or an alkyl or aryl group. Conveniently, R is a lower (C-12 or less) alkyl or phenyl group. Examples of R include methyl, ethyl, dodecyl, octyl, and phenyl. One of W 2 and W 3 is a substituent group and the other is a group of Formula F-2: Typically, W 3 is the group of formula F-2. The group of formula F-2 provides the necessary chromophore of the dye to be formed and may be any acylacetamido group useful for forming a yellow colored coupler. As may be observed, the formula contains several variable substituents. The substituent X is bonded to the coupling position and may be H or any coupling-off group known in the art, as more fully described hereinafter. Such groups are capable of being displaced during oxidative coupling and are typically halogen or a group bonded to the coupling site by a heteroatom such as oxygen, sulfur or nitrogen. Most useful are those employing halogen or a group linked to the coupling site by an atom of oxygen or sulfur or a nitrogen heterocyclic group bonded to the coupling site by a nitrogen atom of the group. One useful group is In this group, R 5 may be any substituent but is desirable usually an electron withdrawing substituent (location relative to the phenoxy oxygen) as described for R 3 in Formula F-3 below. The variable "m" is 0-5, generally 0-2 and suitably 1. In a more specific embodiment, X may be represented by formula X-2: wherein R 5 is as described for formula X-1 and R 6 is hydrogen or a substituent such as any carbon substituent, including alkyl (especially those of 1-8 carbon atoms) or aryl groups, such as methyl, ethyl, or phenyl. Y and Z may be independently selected hydrogen or substituent groups. Suitable substituents include any alkyl, aryl and hetero groups. Examples include methyl ethyl, phenyl, cyclohexyl, and naphthyl. Typically, Y is a substituent and Z is hydrogen. Most commonly Y is a phenyl group and Z is hydrogen. When Y is a phenyl group, F-2 would have formula F-3: In the above formula, R 2 may be hydrogen or any substituent such as halogen, alkoxy, acyl, amido. Suitable examples are methyl, trifluoromethyl, alkoxy such as methoxy, ethoxy, propoxy and isopropoxy and halogen such as bromine or chlorine. R 3 may be any substituent, particularly one containing an electron withdrawing group (Hammett's Sigma value >0 (location relative to the anilino nitrogen)) such as -SO 2 R 4 , -SO 2 NR 4 , -CO 2 R 4 , -CONR 4 , -COR 4 , -NR 4 COR 4 , - NR 4 SO 2 R 4 wherein each R 4 is independently H or a substituent. The R 4 substituent may be interrupted by one or more heteroatoms or groups. Typically, R 3 contains -SO 2 R 4 , -SO 2 NHR 4 , or -CO 2 R 4 . R 3 most typically contains the electron withdrawing group bonded directly to the coupler residue. R 4 may be hydrogen or any substituent such as an alkyl or aryl group, particularly an alkyl group of 4 to 20 carbon atoms. The variable "n" may be 0-4, suitably 0-3 and typically 1-2. X is hydrogen or a coupling-off group. Commonly, the phenyl ring of formula F-3 bears a ballast substituent, as described more fully hereinafter. A particularly useful example of formula F-3 is shown as formula F-4: In formula F-4, R 2 is a chloro or alkoxy group. The arc is intended to indicate that at least one R 3 substituent is present in the 4- or 5- position of the formula. The R 3 substituent contains an electron with drawing group and is preferably linked to the residue of the coupler by one of the indicated electron withdrawing groups as described for F-3 and contains a ballast group as described hereinafter. Returning to the description of formula F-1, W 4 represents the atoms needed to form a fused ring with the ring bearing W 1 . The fused ring may be five to seven membered, may be carbocyclic or heterocyclic, aromatic or nonaromatic, and may be mono or polycyclic. Suitably the W 4 atoms form a five-or six-membered ring. Examples include phenylene groups such as those unsubstituted and those substituted, for example, with cyano, alkyl, carbamoyl, carbonamido, pyridinyl or alkoxy groups; cycloalkyl groups; and 5 or 6-membered ring groups containing oxygen, nitrogen or sulfur heteroatoms. One embodiment of a coupler useful in the invention is formula A: in which R a is -SO 2 CH 3 , -SO 2 CH 2 CH 3 , -SO 2 NHCH 3 , or -SO 2 N(CH 3 ) 2 ; R g is methyl or phenyl; and R b is -SO 2 - or -SO 2 NH-. A second embodiment is shown by formula B: in which R e is an alkyl group of 1-20 carbon atoms; R c and R d are independently selected substituents; and "q" is 0-5 and "p" is 0-4. In a third embodiment, the coupler has formula C: in which R h and R i are independently selected alkyl or aryl groups; X is H or a coupling-off group; R f is halogen or alkoxy; R d is a substituent; and "p" is 0-4. In a fourth embodiment, the coupler has formula D: in which W represents the atoms necessary to form a six-membered carbocyclic group; R h and R i are independently selected alkyl or aryl; X is H or a coupling-off group; R d is a substituent; and "p" is 0-5. In a fifth embodiment, the coupler has formula E: in which W represents the atoms necessary to form a six-membered carbocyclic or heterocyclic aromatic or non-aromatic group; R h and R i are independently selected alkyl or aryl groups; X is H or a coupling-off group; R d is a substituent; and "p" is 0-5. In a sixth embodiment the coupler has formula F: in which W represents the atoms necessary to form a six-membered carbocyclic or heterocyclic aromatic or non-aromatic group; R h and R i are independently selected alkyl or aryl groups; X is H or a coupling-off group; R d is a substituent; and "p" is 0-5. The following are examples of couplers useful in the invention (Ph represents phenyl): In another aspect of the invention there is provided a process for forming a positive image in an element as herein described after the element has been imagewise exposed to light comprising contacting the element with a black and white developer and thereafter contacting the element with a para-phenylenediamine color developing chemical to form a positive of the image. In a further aspect there is provided a process for forming a color negative of an image in an element as herein described after the element has been imagewise exposed to light comprising contacting the element with a para-phenylenediamine color developing chemical. Thus the imaging process of the invention is any process lying within the scope of Claim 24 or 25 and for forming an image in an element of the invention using a color developer. If desired it may be a reversal element in which the image is first developed with a non-color developer followed by uniform fogging and development with a color developer. The element may also be a color negative provided on transparent film designed for optical printing or one on a transparent or reflective support designed for forming a positive image to be directly or indirectly viewed. Unless otherwise specifically stated, the term substituent means any group or atom other than hydrogen bonded to the remainder of a molecule. Additionally, when the term "group" is used, it means that when a substituent group contains a substitutable hydrogen, it is also intended to encompass not only the substituent's unsubstituted form, but also its form further substituted with any substituent group or groups as herein mentioned, so long as the substituent does not destroy properties necessary for photographic utility. Suitably, a substituent group may be halogen or may be bonded to the remainder of the molecule by an atom of carbon, silicon, oxygen, nitrogen, phosphorous, or sulfur. The substituent may be, for example, halogen, such as chlorine, bromine or fluorine; nitro; hydroxyl; cyano; carboxyl; or groups which may be further substituted, such as alkyl, including straight or branched chain or cyclic alkyl, such as methyl, trifluoromethyl, ethyl, t -butyl, 3-(2,4-di-t-pentylphenoxy) propyl, and tetradecyl; alkenyl, such as ethylene, 2-butene; alkoxy, such as methoxy, ethoxy, propoxy, butoxy, 2-methoxyethoxy, sec -butoxy, hexyloxy, 2-ethylhexyloxy, tetradecyloxy, 2-(2,4-di- t -pentylphenoxy)ethoxy, and 2-dodecyloxyethoxy; aryl such as phenyl, 4-t-butylphenyl, 2,4,6-trimethylphenyl, naphthyl; aryloxy, such as phenoxy, 2-methylphenoxy, alpha- or beta-naphthyloxy, and 4-tolyloxy; carbonamido, such as acetamido, benzamido, butyramido, tetradecanamido alpha-(2,4-di- t -pentylphenoxy)acetamido, alpha-(2,4-di- t -pentylphenoxy)butyramido, alpha-(3-pentadecylphenoxy)-hexanamido, alpha-(4-hydroxy-3- t -butylphenoxy)-tetradecanamido, 2-oxo-pyrrolidin-1-yl, 2-oxo-5-tetradecylpyrrolin-1-yl, N-methyltetradecanamido, N-succinimido, N-phthalimido, 2,5-dioxo-1-oxazolidinyl, 3-dodecyl-2,5-dioxo-1-imidazolyl, and N-acetyl-N-dodecylamino, ethoxycarbonylamino, phenoxycarbonylamino, benzyloxycarbonylamino, hexadecyloxycarbonylamino, 2,4-di-t-butylphenoxycarbonylamino, phenylcarbonylamino, 2,5-(di -t -pentylphenyl)carbonylamino, p -dodecylphenylcarbonylamino, p -tolylcarbonylamino, N-methylureido, N,N-dimethylureido, N-methyl-N-dodecylureido, N-hexadecylureido, N,N-dioctadecylureido, N,N-dioctyl-N'-ethylureido, N-phenylureido, N,N-diphenylureido, N-phenyl-N- p -tolylureido, N-( m -hexadecylphenyl)ureido, N,N-(2,5-di- t -pentylphenyl)-N'-ethylureido, and t -butylcarbonamido; sulfonamido, such as methylsulfonamido, benzenesulfonamido, p -tolylsulfonamido, p -dodecylbenzenesulfonamido, N-methyltetradecylsulfonamido, N,N-dipropylsulfamoylamino, and hexadecylsulfonamido; sulfamoyl, such as N-methylsulfamoyl, N-ethylsulfamoyl, N,N-dipropylsulfamoyl, N-hexadecylsulfamoyl, N,N-dimethylsulfamoyl; N-[3-(dodecyloxy)propyl]sulfamoyl, N-[4-(2,4-di- t -pentylphenoxy)butyl]sulfamoyl, N-methyl-N-tetradecylsulfamoyl, and N-dodecylsulfamoyl; carbamoyl, such as N-methylcarbamoyl, N,N-dibutylcarbamoyl, N-octadecylcarbamoyl, N-[4-(2,4-di- t -pentylphenoxy)butyl]carbamoyl, N-methyl-N-tetradecylcarbamoyl, and N,N-dioctylcarbamoyl; acyl, such as acetyl, (2,4-di-t-amylphenoxy)acetyl, phenoxycarbonyl, p -dodecyloxyphenoxycarbonyl methoxycarbonyl, butoxycarbonyl, tetradecyloxycarbonyl, ethoxycarbonyl, benzyloxycarbonyl, 3-pentadecyloxycarbonyl, and dodecyloxycarbonyl; sulfonyl, such as methoxysulfonyl, octyloxysulfonyl, tetradecyloxysulfonyl, 2-ethylhexyloxysulfonyl, phenoxysulfonyl, 2,4-di- t -pentylphenoxysulfonyl, methylsulfonyl, octylsulfonyl, 2-ethylhexylsulfonyl, dodecylsulfonyl, hexadecylsulfonyl, phenylsulfonyl, 4-nonylphenylsulfonyl, and p -tolylsulfonyl; sulfonyloxy, such as dodecylsulfonyloxy, and hexadecylsulfonyloxy; sulfinyl, such as methylsulfinyl, octylsulfinyl, 2-ethylhexylsulfinyl, dodecylsulfinyl, hexadecylsulfinyl, phenylsulfinyl, 4-nonylphenylsulfinyl, and p -tolylsulfinyl; thio, such as ethylthio, octylthio, benzylthio, tetradecylthio, 2-(2,4-di- t -pentylphenoxy)ethylthio, phenylthio, 2-butoxy-5-t-octylphenylthio, and p -tolylthio; acyloxy, such as acetyloxy, benzoyloxy, octadecanoyloxy, p -dodecylamidobenzoyloxy, N-phenylcarbamoyloxy, N-ethylcarbamoyloxy, and cyclohexylcarbonyloxy; amine, such as phenylanilino, 2-chloroanilino, diethylamine, dodecylamine; imino, such as 1-(N-phenylimido)ethyl, N-succinimido or 3-benzylhydantoinyl; phosphate, such as dimethylphosphate and ethylbutylphosphate; phosphite, such as diethyl and dihexylphosphite; a heterocyclic group, a heterocyclic oxy group or a heterocyclic thio group, each of which may be substituted and which contain a 3 to 7 membered heterocyclic ring composed of carbon atoms and at least one hetero atom selected from the group consisting of oxygen, nitrogen and sulfur, such as 2-furyl, 2-thienyl, 2-benzimidazolyloxy or 2-benzothiazolyl; quaternary ammonium, such as triethylammonium; and silyloxy, such as trimethylsilyloxy. If desired, the substituents may themselves be further substituted one or more times with the described substituent groups. The particular substituents used may be selected by those skilled in the art to attain the desired photographic properties for a specific application and can include, for example, hydrophobic groups, solubilizing groups, blocking groups, releasing or releasable groups. Generally, the above groups and substituents thereof may include those having up to 48 carbon atoms, typically 1 to 36 carbon atoms and usually less than 24 carbon atoms, but greater numbers are possible depending on the particular substituents selected. The materials useful in the invention can be used in any of the ways and in any of the combinations known in the art. Typically, the materials are incorporated in a silver halide emulsion and the emulsion coated as a layer on a support to form part of a photographic element Alternatively, unless provided otherwise, they can be incorporated at a location adjacent to the silver halide emulsion layer where, during development, they will be in reactive association with development products such as oxidized color developing agent. Thus, as used herein, the term "associated" signifies that the compound is in the silver halide emulsion layer or in an adjacent location where, during processing, it is capable of reacting with silver halide development products. To control the migration of various components, it may be desirable to include a high molecular weight hydrophobe or "ballast" group in coupler molecules. Representative ballast groups include substituted or unsubstituted alkyl or aryl groups containing 8 to 48 carbon atoms. Representative substituents on such groups include alkyl, aryl, alkoxy, aryloxy, alkylthio, hydroxy, halogen, alkoxycarbonyl, aryloxcarbonyl, carboxy, acyl, acyloxy, amino, anilino, carbonamido, carbamoyl, alkylsulfonyl, arylsulfonyl, sulfonamido, and sulfamoyl groups wherein the substituents typically contain 1 to 42 carbon atoms. Such substituents can also be further substituted. The photographic elements can be single color elements or multicolor elements. Multicolor elements contain image dye-forming units sensitive to each of the three primary regions of the spectrum. Each unit can comprise a single emulsion layer or multiple emulsion layers sensitive to a given region of the spectrum. The layers of the element, including the layers of the image-forming units, can be arranged in various orders as known in the art. In an alternative format, the emulsions sensitive to each of the three primary regions of the spectrum can be disposed as a single segmented layer. A typical multicolor photographic element comprises a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler. The element can contain additional layers, such as filter layers, interlayers, overcoat layers and subbing layers. If desired, the photographic element can be used in conjunction with an applied magnetic layer as described in Research Disclosure , November 1992, Item 34390 published by Kenneth Mason Publications, Ltd., Dudley Annex, 12a North Street, Emsworth, Hampshire P010 7DQ, ENGLAND, and as described in Hatsumi Kyoukai Koukai Gihou No. 94-6023, published March 15, 1994, available from the Japanese Patent Office. When it is desired to employ the inventive materials in a small format film, Research Disclosure , June 1994, Item 36230, provides suitable embodiments. In the following discussion of suitable materials for use in the elements of this invention, reference will be made to Research Disclosure , September 1996, Item 38957, available as described above, which is referred to herein by the term "Research Disclosure". The Sections hereafter referred to are Sections of the Research Disclosure. Except as provided, the silver halide emulsion containing elements employed in this invention can be either negative-working or positive-working as indicated by the type of processing instructions (i.e. color negative, reversal, or direct positive processing) provided with the element. Suitable emulsions and their preparation as well as methods of chemical and spectral sensitization are described in Sections I through V. Various additives such as UV dyes, brighteners, antifoggants, stabilizers, light absorbing and scattering materials, and physical property modifying addenda such as hardeners, coating aids, plasticizers, lubricants and matting agents are described, for example, in Sections II and VI through VIII. Color materials are described in Sections X through XIII. Suitable methods for incorporating couplers and dyes, including dispersions in organic solvents, are described in Section X(E). Scan facilitating is described in Section XIV. Supports, exposure, development systems, and processing methods and agents are described in Sections XV to XX. The information contained in the September 1994 Research Disclosure , Item No. 36544 referenced above, is updated in the September 1996 Research Disclosure , Item No. 38957. Certain desirable photographic elements and processing steps, including those useful in conjunction with color reflective prints, are described in Research Disclosure, Item 37038, February 1995. Coupling-off groups are well known in the art. Such groups can determine the chemical equivalency of a coupler, i.e., whether it is a 2-equivalent or a 4-equivalent coupler, or modify the reactivity of the coupler. Such groups can advantageously affect the layer in which the coupler is coated, or other layers in the photographic recording material, by performing, after release from the coupler, functions such as dye formation, dye hue adjustment, development acceleration or inhibition, bleach acceleration or inhibition, electron transfer facilitation and color correction. The presence of hydrogen at the coupling site provides a 4-equivalent coupler, and the presence of another coupling-off group usually provides a 2-equivalent coupler. Representative classes of such coupling-off groups include, for example, chloro, alkoxy, aryloxy, hetero-oxy, sulfonyloxy, acyloxy, acyl, heterocyclyl, sulfonamido, mercaptotetrazole, benzotriazole, mercaptopropionic acid, phosphonyloxy, arylthio, and arylazo. These coupling-off groups are described in the art, for example, in U.S. Pat Nos. 2,455,169, 3,227,551, 3,432,521, 3,476,563, 3,617,291, 3,880,661, 4,052,212 and 4,134,766; and in UK. Patents and published application Nos. 1,466,728, 1,531,927, 1,533,039, 2,006,755A and 2,017,704A. Image dye-forming couplers may be included in the element such as couplers that form cyan dyes upon reaction with oxidized color developing agents which are described in such representative patents and publications as: "Farbkuppler-eine Literaturübersicht," published in Agfa Mitteilungen, Band III, pp. 156-175 (1961) as well as in U.S. Patent Nos. 2,367,531; 2,423,730; 2,474,293; 2,772,162; 2,895,826; 3,002,836; 3,034,892; 3,041,236; 4,333,999; 4,746,602; 4,753,871; 4,770,988; 4,775,616; 4,818,667; 4,818,672; 4,822,729; 4,839,267; 4,840,883; 4,849,328; 4,865,961; 4,873,183; 4,883,746; 4,900,656; 4,904,575; 4,916,051; 4,921,783; 4,923,791; 4,950,585; 4,971,898; 4,990,436; 4,996,139; 5,008,180; 5,015,565; 5,011,765; 5,011,766; 5,017,467; 5,045,442; 5,051,347; 5,061,613; 5,071,737; 5,075,207; 5,091,297; 5,094,938; 5,104,783; 5,178,993; 5,813,729; 5,187,057; 5,192,651; 5,200,305 5,202,224; 5,206,130; 5,208,141; 5,210,011; 5,215,871; 5,223,386; 5,227,287; 5,256,526; 5,258,270; 5,272,051; 5,306,610; 5,326,682; 5,366,856; 5,378,596; 5,380,638; 5,382,502; 5,384,236; 5,397,691; 5,415,990; 5,434,034; 5,441,863; EPO 0 246 616; EPO 0 250 201; EPO 0 271 323; EPO 0 295 632; EPO 0 307 927; EPO 0 333 185; EPO 0 378 898; EPO 0 389 817; EPO 0 487 111; EPO 0 488 248; EPO 0 539 034; EPO 0 545 300; EPO 0 556 700; EPO 0 556 777; EPO 0 556 858; EPO 0 569 979; EPO 0 608 133; EPO 0 636 936; EPO 0 651 286; EPO 0 690 344; German OLS 4,026,903; German OLS 3,624,777. and German OLS 3,823,049. Typically such couplers are phenols, naphthols, or pyrazoloazoles. Couplers that form magenta dyes upon reaction with oxidized color developing agent are described in such representative patents and publications as: "Farbkuppler-eine Literaturübersicht," published in Agfa Mitteilungen, Band III, pp. 126-156 (1961) as well as U.S. Patents 2,311,082 and 2,369,489; 2,343,701; 2,600,788; 2,908,573; 3,062,653; 3,152,896; 3,519,429; 3,758,309; 3,935,015; 4,540,654; 4,745,052; 4,762,775; 4,791,052; 4,812,576; 4,835,094; 4,840,877; 4,845,022; 4,853,319; 4,868,099; 4,865,960; 4,871,652; 4,876,182; 4,892,805; 4,900,657; 4,910,124; 4,914,013; 4,921,968; 4,929,540; 4,933,465; 4,942,116; 4,942,117; 4,942,118; U.S. Patent 4,959,480; 4,968,594; 4,988,614; 4,992,361; 5,002,864; 5,021,325; 5,066,575; 5,068,171; 5,071,739; 5,100,772; 5,110,942; 5,116,990; 5,118,812; 5,134,059; 5,155,016; 5,183,728; 5,234,805; 5,235,058; 5,250,400; 5,254,446; 5,262,292; 5,300,407; 5,302,496; 5,336,593; 5,350,667; 5,395,968; 5,354,826; 5,358,829; 5,368,998; 5,378,587; 5,409,808; 5,411,841; 5,418,123; 5,424,179; EPO 0 257 854; EPO 0 284 240; EPO 0 341 204; EPO 347,235; EPO 365,252; EPO 0 422 595; EPO 0 428 899; EPO 0 428 902; EPO 0 459 331; EPO 0 467 327; EPO 0 476 949; EPO 0 487 081; EPO 0 489 333; EPO 0 512 304; EPO 0 515 128; EPO 0 534 703; EPO 0 554 778; EPO 0 558 145; EPO 0 571 959; EPO 0 583 832; EPO 0 583 834; EPO 0 584 793; EPO 0 602 748; EPO 0 602 749; EPO 0 605 918; EPO 0 622 672; EPO 0 622 673; EPO 0 629 912; EPO 0 646 841, EPO 0 656 561; EPO 0 660 177; EPO 0 686 872; WO 90/10253; WO 92/09010; WO 92/10788; WO 92/12464; WO 93/01523; WO 93/02392; WO 93/02393; WO 93/07534; UK Application 2,244,053; Japanese Application 03192-350; German OLS 3,624,103; German OLS 3,912,265; and German OLS 40 08 067. Typically such couplers are pyrazolones, pyrazoloazoles, or pyrazolobenzimidazoles that form magenta dyes upon reaction with oxidized color developing agents. Couplers that form yellow dyes upon reaction with oxidized color developing agent are described in such representative patents and publications as: "Farbkuppler-eine Literaturübersicht," published in Agfa Mitteilungen; Band III; pp. 112-126 (1961); as well as U.S. Patents 2,298,443; 2,407,210; 2,875,057; 3,048,194; 3,265,506; 3,447,928; 4,022,620; 4,443,536; 4,758,501; 4,791,050; 4,824,771; 4,824,773; 4,855,222; 4,978,605; 4,992,360; 4,994,361; 5,021,333; 5,053,325; 5,066,574; 5,066,576; 5,100,773; 5,118,599; 5,143,823; 5,187,055; 5,190,848; 5,213,958; 5,215,877; 5,215,878; 5,217,857; 5,219,716; 5,238,803; 5,283,166; 5,294,531; 5,306,609; 5,328,818; 5,336,591; 5,338,654; 5,358,835; 5,358,838; 5,360,713; 5,362,617; 5,382,506; 5,389,504; 5,399,474;. 5,405,737; 5,411,848; 5,427,898; EPO 0 327 976; EPO 0 296 793; EPO 0 365 282; EPO 0 379 309; EPO 0 415 375; EPO 0 437 818; EPO 0 447 969; EPO 0 542 463; EPO 0 568 037; EPO 0 568 196; EPO 0 568 777; EPO 0 570 006; EPO 0 573 761; EPO 0 608 956; EPO 0 608 957; and EPO 0 628 865. Such couplers are typically open chain ketomethylene compounds. Couplers that form colorless products upon reaction with oxidized color developing agent are described in such representative patents as: UK. 861,138; U.S. Pat. Nos. 3,632,345; 3,928,041; 3,958,993 and 3,961,959. Typically such couplers are cyclic carbonyl containing compounds that form colorless products on reaction with an oxidized color developing agent. Couplers that form black dyes upon reaction with oxidized color developing agent are described in such representative patents as U.S. Patent Nos. 1,939,231; 2,181,944; 2,333,106; and 4,126,461; German OLS No. 2,644,194 and German OLS No. 2,650,764. Typically, such couplers are resorcinols or m-aminophenols that form black or neutral products on reaction with oxidized color developing agent. In addition to the foregoing, so-called "universal" or "washout" couplers may be employed. These couplers do not contribute to image dye-formation. Thus, for example, a naphthol having an unsubstituted carbamoyl or one substituted with a low molecular weight substituent at the 2- or 3- position may be employed. Couplers of this type are described, for example, in U.S. Patent Nos. 5,026,628, 5,151,343, and 5,234,800. It may be useful to use a combination of couplers any of which may contain known ballasts or coupling-off groups such as those described in U.S. Patent 4,301,235; U.S. Patent 4,853,319 and U.S. Patent 4,351,897. The coupler may contain solubilizing groups such as described in U.S. Patent 4,482,629. The coupler may also be used in association with "wrong" colored couplers (e.g. to adjust levels of interlayer correction) and, in color negative applications, with masking couplers such as those described in EP 213.490; Japanese Published Application 58-172,647; U.S. Patent Nos. 2,983,608; 4,070,191; and 4,273,861; German Applications DE 2,706,117 and DE 2,643,965; UK. Patent 1,530,272; and Japanese Application 58-113935. The masking couplers may be shifted or blocked, if desired. Typically, couplers are incorporated in a silver halide emulsion layer in a mole ratio to silver of 0.05 to 1.0 and generally 0.1 to 0.5. Usually the couplers are dispersed in a high-boiling organic solvent in a weight ratio of solvent to coupler of 0.1 to 10.0 and typically 0.1 to 2.0 although dispersions using no permanent coupler solvent are sometimes employed. The materials useful in the invention may be used in association with materials that release Photographically Useful Groups (PUGS) that accelerate or otherwise modify the processing steps e.g. of bleaching or fixing to improve the quality of the image. Bleach accelerator releasing couplers such as those described in EP 193,389; EP 301,477; U.S. 4,163,669; U.S. 4,865,956; and U.S. 4,923,784, may be useful. Also contemplated is use of the compositions in association with nucleating agents, development accelerators or their precursors (UK Patent 2,097,140; UK. Patent 2,131,188); electron transfer agents (U.S. 4,859,578; U.S. 4,912,025); antifogging and anti color-mixing agents such as derivatives of hydroquinones, aminophenols, amines, gallic acid; catechol; ascorbic acid; hydrazides; sulfonamidophenols; and non color-forming couplers. The materials useful in the invention may also be used in combination with filter dye layers comprising colloidal silver sol or yellow, cyan, and/or magenta filter dyes, either as oil-in-water dispersions, latex dispersions or as solid particle dispersions. Additionally, they may be used with "smearing" couplers (e.g. as described in U.S. 4,366,237; EP 96,570; U.S. 4,420,556; and U.S. 4,543,323.) Also, the compositions may be blocked or coated in protected form as described, for example, in Japanese Application 61/258,249 or U.S. 5,019,492. The materials may further be used in combination with image-modifying compounds that release PUGS such as "Developer Inhibitor-Releasing" compounds (DIR's). DIR's useful in conjunction with the compositions useful in the invention are known in the art and examples are described in U.S. Patent Nos. 3,137,578; 3,148,022; 3,148,062; 3,227,554; 3,384,657; 3,379,529; 3,615,506; 3,617,291; 3,620,746; 3,701,783; 3,733,201; 4,049,455; 4,095,984; 4,126,459; 4,149,886; 4,150,228; 4,211,562; 4,248,962; 4,259,437; 4,362,878; 4,409,323; 4,477,563; 4,782,012; 4,962,018; 4,500,634; 4,579,816; 4,607,004; 4,618,571; 4,678,739; 4,746,600; 4,746,601; 4,791,049; 4,857,447; 4,865,959; 4,880,342; 4,886,736; 4,937,179; 4,946,767; 4,948,716; 4,952,485; 4,956,269; 4,959,299; 4,966,835; 4,985,336 as well as in patent publications GB 1,560,240; GB 2,007,662; GB 2,032,914; GB 2,099,167; DE 2,842,063, DE 2,937,127; DE 3,636,824; DE 3,644,416 as well as the following European Patent Publications: 272,573; 335,319; 336,411; 346, 899; 362, 870; 365,252; 365,346; 373,382; 376,212; 377,463; 378,236; 384,670; 396,486; 401,612; 401,613. Such compounds are also disclosed in "Developer-Inhibitor-Releasing (DIR) Couplers for Color Photography," C.R. Barr, J.R. Thirtle and P.W. Vittum in Photographic Science and Engineering, Vol. 13, p. 174 (1969). Generally, the developer inhibitor-releasing (DIR) couplers include a coupler moiety and an inhibitor coupling-off moiety (IN). The inhibitor-releasing couplers may be of the time-delayed type (DIAR couplers) which also include a timing moiety or chemical switch which produces a delayed release of inhibitor. Examples of typical inhibitor moieties are: oxazoles, thiazoles, diazoles, triazoles, oxadiazoles, thiadiazoles, oxathiazoles, thiatriazoles, benzotriazoles, tetrazoles, benzimidazoles, indazoles, isoindazoles, mercaptotetrazoles, selenotetrazoles, mercaptobenzothiazoles, selenobenzothiazoles, mercaptobenzoxazoles, selenobenzoxazoles, mercaptobenzimidazoles, selenobenzimidazoles, benzodiazoles, mercaptooxazoles, mercaptothiadiazoles, mercaptothiazoles, mercaptotriazoles, mercaptooxadiazoles, mercaptodiazoles, mercaptooxathiazoles, telleurotetrazoles or benzisodiazoles. In a preferred embodiment, the inhibitor moiety or group is selected from the following formulas: wherein R I is selected from the group consisting of straight and branched alkyls of from 1 to 8 carbon atoms, benzyl, phenyl, and alkoxy groups and such groups containing none, one or more than one such substituent; R II is selected from R I and -SR I ; R III is a straight or branched alkyl group of from 1 to 5 carbon atoms and m is from 1 to 3; and R IV is selected from the group consisting of hydrogen, halogens and alkoxy, phenyl and carbonamido groups, -COOR V and -NHCOOR V wherein R V is selected from substituted and unsubstituted alkyl and aryl groups. Although it is typical that the coupler moiety included in the developer inhibitor-releasing coupler forms an image dye corresponding to the layer in which it is located, it may also form a different color as one associated with a different film layer. It may also be useful that the coupler moiety included in the developer inhibitor-releasing coupler forms colorless products and/or products that wash out of the photographic material during processing (so-called "universal" couplers). A compound such as a coupler may release a PUG directly upon reaction of the compound during processing, or indirectly through a timing or linking group. A timing group produces the time-delayed release of the PUG such groups using an intramolecular nucleophilic substitution reaction (U.S. 4,248,962); groups utilizing an electron transfer reaction along a conjugated system (U.S. 4,409,323; 4,421,845; 4,861,701, Japanese Applications 57-188035; 58-98728; 58-209736; 58-209738); groups that function as a coupler or reducing agent after the coupler reaction (U.S. 4,438,193; U.S. 4,618,571) and groups that combine the features describe above. It is typical that the timing group is of one of the formulas: wherein IN is the inhibitor moiety, R VII is selected from the group consisting of nitro, cyano, alkylsulfonyl; sulfamoyl; and sulfonamido groups; a is 0 or 1; and R VI is selected from the group consisting of substituted and unsubstituted alkyl and phenyl groups. The oxygen atom of each timing group is bonded to the coupling-off position of the respective coupler moiety of the DIAR. The timing or linking groups may also function by electron transfer down an unconjugated chain. Linking groups are known in the art under various names. Often they have been referred to as groups capable of utilizing a hemiacetal or iminoketal cleavage reaction or as groups capable of utilizing a cleavage reaction due to ester hydrolysis such as U.S. 4,546,073. This electron transfer down an unconjugated chain typically results in a relatively fast decomposition and the production of carbon dioxide, formaldehyde, or other low molecular weight by-products. The groups are exemplified in EP 464,612, EP 523,451, U.S. 4,146,396, Japanese Kokai 60-249148 and 60-249149. Suitable developer inhibitor-releasing couplers for use in the present invention include, but are not limited to, the following: It is also contemplated that the concepts of the present invention may be employed to obtain reflection color prints as described in Research Disclosure , November 1979, Item 18716, available from Kenneth Mason Publications, Ltd, Dudley Annex, 12a North Street, Emsworth, Hampshire P0101 7DQ, England. Materials useful in the invention may be coated on pH adjusted support as described in U.S. 4,917,994; on a support with reduced oxygen permeability (EP 553,339); with epoxy solvents (EP 164,961); with nickel complex stabilizers (U.S. 4,346,165; U.S. 4,540,653 and U.S. 4,906,559 for example); with ballasted chelating agents such as those in U.S. 4,994,359 to reduce sensitivity to polyvalent cations such as calcium; and with stain reducing compounds such as described in U.S. 5,068,171. Other compounds useful in combination with the invention are disclosed in Japanese Published Applications described in Derwent Abstracts having accession numbers as follows: 90-072,629, 90-072,630; 90-072,631; 90-072,632; 90-072,633; 90-072,634; 90-077,822; 90-078,229; 90-078,230; 90-079,336; 90-079,337; 90-079,338; 90-079,690; 90-079,691; 90-080,487; 90-080,488; 90-080,489; 90-080,490; 90-080,491; 90-080,492; 90-080,494; 90-085,928; 90-086,669; 90-086,670; 90-087,360; 90-087,361; 90-087,362; 90-087,363; 90-087,364; 90-088,097; 90-093,662; 90-093,663; 90-093,664; 90-093,665; 90-093,666; 90-093,668; 90-094,055; 90-094,056; 90-103,409; 83-62,586; 83-09,959. Conventional radiation-sensitive silver halide emulsions can be employed in the practice of this invention. Such emulsions are illustrated by Research Disclosure , Item 38755, September 1996, I. Emulsion grains and their preparation. Especially useful in this invention are tabular grain silver halide emulsions. Tabular grains are those having two parallel major crystal faces and having an aspect ratio of at least 2. The term "aspect ratio" is the ratio of the equivalent circular diameter (ECD) of a grain major face divided by its thickness (t). Tabular grain emulsions are those in which the tabular grains account for at least 50 percent (preferably at least 70 percent and optimally at least 90 percent) of total grain projected area. Preferred tabular grain emulsions are those in which the average thickness of the tabular grains is less than 0.3 micrometer (preferably thin--that is, less than 0.2 micrometer and most preferably ultrathin--that is, less than 0.07 micrometer). The major faces of the tabular grains can lie in either {111} or {100} crystal planes. The mean ECD of tabular grain emulsions rarely exceeds 10 micrometers and more typically is less than 5 micrometers. In their most widely used form tabular grain emulsions are high bromide {111} tabular grain emulsions. Such emulsions are illustrated by Kofron et al U.S. Patent 4,439,520, Wilgus et al U.S. Patent 4,434,226, Solberg et al U.S. Patent 4,433,048, Maskasky U.S. Patents 4,435,501,, 4,463,087 and 4,173,320, Daubendiek et al U.S. Patents 4,414,310 and 4,914,014, Sowinski et al U.S. Patent 4,656,122, Piggin et al U.S. Patents 5,061,616 and 5,061,609, Tsaur et al U.S. Patents 5,147,771, '772, '773, 5,171,659 and 5,252,453, Black et al 5,219,720 and 5,334,495, Delton U.S. Patents 5,310,644, 5,372,927 and 5,460,934, Wen U.S. Patent 5,470,698, Fenton et al U.S. Patent 5,476,760, Eshelman et al U.S. Patents 5,612,,175 and 5,614,359, and Irving et al U.S. Patent 5,667,954. Ultrathin high bromide {111} tabular grain emulsions are illustrated by Daubendiek et al U.S. Patents 4,672,027, 4,693,964, 5,494,789, 5,503,971 and 5,576,168, Antoniades et al U.S. Patent 5,250,403, Olm et al U.S. Patent 5,503,970, Deaton et al U.S. Patent 5,582,965, and Maskasky U.S. Patent 5,667,955. High bromide {100} tabular grain emulsions are illustrated by Mignot U.S. Patents 4,386,156 and 5,386,156. High chloride {111} tabular grain emulsions are illustrated by Wey U.S. Patent 4,399,215, Wey et al U.S. Patent 4,414,306, Maskasky U.S. Patents 4.400,463, 4,713,323, 5,061,617, 5,178,997, 5,183,732, 5,185,239, 5,399,478 and 5,411,852, and Maskasky et al U.S. Patents 5,176,992 and 5,178,998. Ultrathin high chloride {111} tabular grain emulsions are illustrated by Maskasky U.S. Patents 5,271,858 and 5,389,509. High chloride {100} tabular grain emulsions are illustrated by Maskasky U.S. Patents 5,264,337, 5,292,632, 5,275,930 and 5,399,477, House et al U.S. Patent 5,320,938, Brust et al U.S. Patent 5,314,798, Szajewski et al U.S. Patent 5,356,764, Chang et al U.S. Patents 5,413,904 and 5,663,041, Oyamada U.S. Patent 5,593,821, Yamashita et al U.S. Patents 5,641,620 and 5,652,088, Saitou et al U.S. Patent 5,652,089, and Oyamada et al U.S. Patent 5,665,530. Ultrathin high chloride {100} tabular grain emulsions can be prepared by nucleation in the presence of iodide, following the teaching of House et al and Chang et al, cited above. The emulsions can be surface-sensitive emulsions, i.e., emulsions that form latent images primarily on the surfaces of the silver halide grains, or the emulsions can form internal latent images predominantly in the interior of the silver halide grains. The emulsions can be negative-working emulsions, such as surface-sensitive emulsions or unfogged internal latent image-forming emulsions, or direct-positive emulsions of the unfogged, internal latent image-forming type, which are positive-working when development is conducted with uniform light exposure or in the presence of a nucleating agent. Tabular grain emulsions of the latter type are illustrated by Evans et al. U.S. 4,504,570. Photographic elements can be exposed to actinic radiation, typically in the visible region of the spectrum, to form a latent image and can then be processed to form a visible dye image. Processing to form a visible dye image includes the step of contacting the element with a color developing agent to reduce developable silver halide and oxidize the color developing agent. Oxidized color developing agent in turn reacts with the coupler to yield a dye. If desired "Redox Amplification" as described in Research Disclosure XVIIIB(5) may be used. With negative-working silver halide, the processing step described above provides a negative image. One type of such element, referred to as a color negative film, is designed for image capture. Speed (the sensitivity of the element to low light conditions) is usually critical to obtaining sufficient image in such elements. Such elements are typically silver bromoiodide emulsions coated on a transparent support and may be processed, for example, in known color negative processes such as the Kodak C-41 process as described in The British Journal of Photography Annual of 1988, pages 191-198. If a color negative film element is to be subsequently employed to generate a viewable projection print as for a motion picture, a process such as the Kodak ECN-2 process described in the H-24 Manual available from Eastman Kodak Co. may be employed to provide the color negative image on a transparent support. Color negative development times are typically 3' 15" or less and desirably 90 or even 60 seconds or less. The photographic element of the invention can be incorporated into exposure structures intended for repeated use or exposure structures intended for limited use, variously referred to by names such as "single use cameras", "lens with film", or "photosensitive material package units". Another type of color negative element is a color print. Such an element is designed to receive an image optically printed from an image capture color negative element. A color print element may be provided on a reflective support for reflective viewing (e.g. a snap shot) or on a transparent support for projection viewing as in a motion picture. Elements destined for color reflection prints are provided on a reflective support, typically paper, employ silver chloride emulsions, and may be optically printed using the so-called negative-positive process where the element is exposed to light through a color negative film which has been processed as described above. The element is sold with instructions to process using a color negative optical printing process, for example the Kodak RA-4 process, as generally described in PCT WO 87/04534 or U.S. 4,975,357, to form a positive image. Color projection prints may be processed, for example, in accordance with the Kodak ECP-2 process as described in the H-24 Manual. Color print development times are typically 90 seconds or less and desirably 45 or even 30 seconds or less. A reversal element is capable of forming a positive image without optical printing. To provide a positive (or reversal) image, the color development step is preceded by development with a non-chromogenic developing agent to develop exposed silver halide, but not form dye, and followed by uniformly fogging the element to render unexposed silver halide developable. Such reversal emulsions are typically sold with instructions to process using a color reversal process such as the Kodak E-6 process as described in The British Journal of Photography Annual of 1988, page 194. Alternatively, a direct positive emulsion can be employed to obtain a positive image. The above elements are typically sold with instructions to process using the appropriate method such as the mentioned color negative (Kodak C-41), color print (Kodak RA-4), or reversal (Kodak E-6) process. Preferred color developing agents are p -phenylenediamines such as: 4-amino-N,N-diethylaniline hydrochloride, 4-amino-3-methyl-N,N-diethylaniline hydrochloride, 4-amino-3-methyl-N-ethyl-N-(2-methanesulfonamidoethyl)aniline sesquisulfate hydrate, 4-amino-3-methyl-N-ethyl-N-(2-hydroxyethyl)aniline sulfate, 4-amino-3-(2-methanesulfonamidoethyl)-N,N-diethylaniline hydrochloride, and 4-amino-N-ethyl-N-(2-methoxyethyl)- m -toluidine di- p -toluene sulfonic acid. Development is usually followed by the conventional steps of bleaching, fixing, or bleach-fixing, to remove silver or silver halide, washing, and drying. The yellow coupler useful in the invention may be employed, for example in elements comprising the following: In a color negative element, the materials useful in the invention may replace or supplement the materials of an element comprising a support bearing the following layers from top to bottom: (1) one or more overcoat layers containing ultraviolet absorber(s); (2) a two-coat yellow pack with a fast yellow layer containing "Coup 1": Benzoic acid, 4-chloro-3-((2-(4-ethoxy-2,5-dioxo-3-(phenylmethyl)-1-imidazolidinyl)-3-(4-methoxyphenyl)-1,3-dioxopropyl)amino)-, dodecyl ester and a slow yellow layer containing the same compound together with "Coup 2": Propanoic acid, 2-[[5-[[4-[2-[[[2,4-bis(1,1-dimethylpropyl)phenoxy]acetyl]amino]-5-[(2,2,3,3,4,4,4-heptafluoro-1-oxobutyl)amino]-4-hydroxyphenoxy]-2,3-dihydroxy-6-[(propylamino)carbonyl ]phenyl]thio]-1,3,4-thiadiazol-2-yl]thio]-, methyl ester and "Coup 3": 1-((dodecyloxy)carbonyl) ethyl(3-chloro-4-((3-(2-chloro-4-((1-tridecanoylethoxy) carbonyl)anilino)-3-oxo-2-((4)(5)(6)-(phenoxycarbonyl)-1H-benzotriazol-1-yl)propanoyl)amino))benzoate; (3) an interlayer containing fine metallic silver; (4) a triple-coat magenta pack with a fast magenta layer containing "Coup 4": Benzamide, 3-((2-(2,4-bis(1,1-dimethylpropyl)phenoxy)-1-oxobutyl)amino)-N-(4,5-dihydro-5-oxo-1-(2,4,6-trichlorophenyl)-1H-pyrazol-3-yl)-, "Coup 5": Benzamide, 3-((2-(2,4-bis(1,1-dimethylpropyl)phenoxy)-1-oxobutyl)amino)-N-(4',5'-dihydro-5'-oxo-1'-(2,4,6-trichlorophenyl) (1,4'-bi-1H-pyrazol)-3'-yl)-,"Coup 6": Carbamic acid, (6-(((3-(dodecyloxy)propyl) amino)carbonyl)-5-hydroxy-1-naphthalenyl)-, 2-methylpropyl ester, "Coup 7": Acetic acid, ((2-((3-(((3-(dodecyloxy)propyl)amino) carbonyl)-4-hydroxy-8-(((2-methylpropoxy)carbonyl) amino)-1-naphthalenyl)oxy )ethyl)thio)-, and "Coup 8" Benzamide, 3-((2-(2,4-bis(1,1-dimethylpropyl) phenoxy)-1-oxobutyl)amino)-N-(4,5-dihydro-4-((4-methoxyphenyl) azo)-5-oxo-1-(2,4,6-trichlorophenyl)-1H-pyrazol-3-yl)-; a mid-magenta layer and a slow magenta layer each containing "Coup 9": a ternary copolymer containing by weight in the ratio 1:1:2 2-Propenoic acid butyl ester, styrene, and N-[1-(2,4,6-trichlorophenyl)-4,5-dihydro-5-oxo-1H-pyrazol-3-yl]-2-methyl-2-propenamide; and "Coup 10": Tetradecanamide, N-(4-chloro-3-((4-((4-((2,2-dimethyl-1-oxopropyl)amino)phenyl)azo)-4,5-dihydro-5-oxo-1-(2,4,6-trichlorophenyl)-1H-pyrazol-3-yl)amino)phenyl)-, in addition to Coups 3 and 8; (5) an interlayer; (6) a triple-coat cyan pack with a fast cyan layer containing Coups 6 and 7; a mid-cyan containing Coup 6 and "Coup 11": 2,7-Naphthalenedisulfonic acid, 5-(acetylamino)-3-((4-(2-((3-(((3-(2,4-bis(1,1-dimethylpropyl)phenoxy) propyl)amino)carbonyl)-4-hydroxy-1-naphthalenyl) oxy)ethoxy)phenyl)azo)-4-hydroxy-, disodium salt; and a slow cyan layer containing Coups 2 and 6; (7) an undercoat layer containing Coup 8; and (8) an antihalation layer. In a color paper format, the materials useful in the invention may replace or supplement the materials of an element comprising a support bearing the following layers from top to bottom: (1) one or more overcoats; (2) a cyan layer containing "Coup 1": Butanamide, 2-(2,4-bis(1,1-dimethylpropyl)phenoxy)-N-(3,5-dichloro-2-hydroxy-4-methylphenyl)-, "Coup 2": Acetamide, 2-(2,4-bis(1,1-dimethylpropyl)phenoxy)-N-(3,5-dichloro-2-hydroxy-4-methylphenyl)-, and UV Stabilizers: Phenol, 2-(5-chloro-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)-;Phenol, 2-(2H-benzotriazol-2-yl)-4-(1,1-dimethylethyl)-;Phenol, 2-(2H-benzotriazol-2-yl)-4-(1,1-dimethylethyl)-6-(1-methylpropyl)-; and Phenol, 2-(2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylpropyl)- and a poly(t-butylacrylamide) dye stabilizer; (3) an interlayer; (4) a magenta layer containing "Coup 3": Octanamide, 2-[2,4-bis(1,1-dimethylpropyl)phenoxy]-N-[2-(7-chloro-6-methyl-1H-pyrazolo[1,5-b][1,2,4]triazol-2-yl)propyl]- together with 1,1'-Spirobi(1H-indene), 2,2',3,3'-tetrahydro-3,3,3',3'-tetramethyl-5,5',6,6'-tetrapropoxy-; (5) an interlayer, and (6) a yellow layer containing "Coup 4": 1-Imidazolidineacetamide, N-(5-((2-(2,4-bis(1,1-dimethylpropyl)phenoxy)-1-oxobutyl)amino)-2-chlorophenyl)-.alpha.-(2,2-dimethyl-1-oxopropyl)-4-ethoxy-2,5-dioxo-3-(phenylmethyl)-. In a reversal format, the materials useful in the invention may replace or supplement the materials of an element comprising a support bearing the following layers from top to bottom: (1) one or more overcoat layers; (2) a nonsensitized silver halide containing layer; (3) a triple-coat yellow layer pack with a fast yellow layer containing "Coup 1": Benzoic acid, 4-(1-(((2-chloro-5-((dodecylsulfonyl)amino)phenyl) amino)carbonyl)-3,3-dimethyl-2-oxobutoxy)-, 1-methylethyl ester; a mid yellow layer containing Coup 1 and "Coup 2": Benzoic acid, 4-chloro-3-[[2-[4-ethoxy-2,5-dioxo-3-(phenylmethyl)-1-imidazolidinyl]-4,4-dimethyl-1,3-dioxopentyl] amino]-, dodecylester; and a slow yellow layer also containing Coup 2; (4) an interlayer; (5) a layer of fine-grained silver; (6) an interlayer; (7) a triple-coated magenta pack with a fast and mid magenta layer containing "Coup 3": 2-Propenoic acid, butyl ester, polymer with N-[1-(2,5-dichlorophenyl)-4,5-dihydro-5-oxo-1H-pyrazol-3-yl]-2-methyl-2-propenamide; "Coup 4": Benzamide, 3-((2-(2,4-bis(1,1-dimethylpropyl)phenoxy)-1-oxobutyl)amino)-N-(4,5-dihydro-5-oxo-1-(2,4,6-trichlorophenyl)-1H-pyrazol-3-yl)-; and "Coup 5": Benzamide, 3-(((2,4-bis(1,1-dimethylpropyl)phenoxy)acetyl)amino)-N-(4,5-dihydro-5-oxo-1-(2,4,6-trichlorophenyl)-1H-pyrazol-3-yl)-; and containing the stabilizer 1,1'-Spirobi(1H-indene), 2,2',3,3'-tetrahydro-3,3,3',3'-tetramethyl-5,5',6,6'-tetrapropoxy-; and in the slow magenta layer Coups 4 and 5 with the same stabilizer; (8) one or more interlayers possibly including fine-grained nonsensitized silver halide; (9) a triple-coated cyan pack with a fast cyan layer containing "Coup 6": Tetradecanamide, 2-(2-cyanophenoxy)-N-(4-((2,2,3,3,4,4,4-heptafluoro-1-oxobutyl)amino)-3-hydroxyphenyl)-; a mid cyan containing "Coup 7": Butanamide, N-(4-((2-(2,4-bis(1,1-dimethylpropyl)phenoxy)-1-oxobutyl)amino)-2-hydroxyphenyl)-2,2,3,3,4,4,4-heptafluoro- and "Coup 8": Hexanamide, 2-(2,4-bis(1,1-dimethylpropyl)phenoxy)-N-(4-((2,2,3,3,4,4,4-heptafluoro-1-oxobutyl)amino)-3-hydroxyphenyl)-; and a slow cyan layer containing Coups 6,7, and 8; (10) one or more interlayers possibly including fine-grained nonsensitized silver halide; and (11) an antihalation layer. Synthesis Schemes The couplers and dyes for use in this invention can be prepared from the requisite heterocyclic parents using the method of U.S. 5,674,667 and variations thereof. A variety of useful heterocycles, in turn, are readily available via literature procedures as described, for example, in A.R. Katritzky and C.W. Rees in Comprehensive Heterocyclic Chemistry , Pergamon Press, New York. As an example, such couplers and dyes can be synthesized as outlined in the following Scheme 1 and Scheme 2. Synthetic Example The following are experimental procedures for the preparation of C-1 and D-1 according to the synthetic scheme depicted above (Scheme 1). These procedures may also be extended to the preparation of a variety of other heteroaromatic couplers. Preparation of I-2 (a representative β-ketoester formation reaction): A mixture of 1-methyl-2-phenylindole (Aldrich Chemical Co.; 12.4 g, 59.9 mmol) and ethyl malonyl chloride (Aldrich Chemical Co.; 9.46 g, 62.8 mmol) in 100 mL 1,2-dichloroethane was treated with stannic chloride (Aldrich Chemical Co.; 7.5 mL, 64 mmol) after which a mildly exothermic reaction ensued. The mixture was heated at reflux for 1.25 hours and then poured onto ice water. An extractive work-up using dichloromethane afforded a dark residue. Silica gel chromatography with dichloromethane gave the solid β-ketoester 13.0 g, 67%), mp 103-106°C. The product was chromatographically homogenous and displayed an NMR spectrum consistent with its assigned structure. Preparation of C-1 (a representative anilide formation reaction): A mixture of I-2 (3.21 g, 10.0 mmol) and 4-butylaniline (Aldrich Chemical Co.; 2.5 g, 16.7 mmol) in 25 mL of xylenes was heated at reflux for 2 hrs. The mix was cooled to near ambient temperature then diluted with about one volume of heptane. The solid was collected by filtration then recrystallized from methanol to afford a cream solid (2.49 g, 59%), mp 76-78°C. The product was chromatographically homogenous and displayed an NMR spectrum consistent with its assigned structure. Anal. (dry 25°C): Fd. % (Calc.%) N 6.6 (6.6), C 79.0 (79.2), H 6.7 (6.6). Preparation of D-1 (a representative dye forming reaction): A mixture of C-1 (0.32 g, 0.75 mmol), the nitrosoaniline (CAS # 56046-62-9; 0.28 g, 1 mmol), and potassium carbonate (0.26 g, 1.9 mmol) in 25 mL ethanol were heated at reflux for 1.25 hr then poured into ice water. An extractive work-up with ethyl acetate gave the crude dye. Silica gel chromatography, eluting with mixtures of dichloromethane and ethyl acetate, afforded the pure dye as a red glass (0.41 g, 79%). The product was chromatographically homogenous and displayed NMR and mass spectra consistent with its assigned structure. The procedures outlined in Scheme 2 show typical methods for the preparation of substituted photographic couplers. Representative preparations of couplers bearing a halogen atom (C-3), a phenoxy group (C-4) and a nitrogen acid (C-5) are provided. Preparation of C-3 (a representative halogenation procedure): A mixture of C-2 (prepared via a minor variant of the procedures outlined in Scheme 1; 12.7 g, 20.0 mmol) and 1,3-dibromo-5,5-dimethylhydantoin (Aldrich Chemical Co.; 2.86 g 10.0 mmol) in 150 mL toluene was heated at 100°C for 0.5 h. The mixture was cooled to ambient temperature, the solid by-product was filtered away, then the filtrate was concentrated in vacuo. The residue was triturated with isopropyl ether to provide C-3 (10.3 g, 72%). The product was chromatographically homogenous and displayed an NMR spectrum consistent with its assigned structure. Preparation of C-4 ( a representative protocol for the preparation of phenoxy-couplers): A mixture of 4,4'-sulfonyldiphenol (Aldrich Chemical Co.; 11.2 g, 44.8 mmol) in 150 mL of N,N-dimethylacetamide (DMAc) was treated with potassium t-butoxide (Aldrich Chemical Co.; 4.4 g, 39.2 mmol). The mixture stirred at ambient temperature for 10 min then was treated with C-3 (4.00 g, 5.61 mmol). The reaction stirred at ambient temperature for 3 hrs, and then was poured into cold dilute hydrochloric acid; an extractive work-up using ethyl acetate gave a crude product. This product was sequentially triturated with 1,2-dichloroethane then isopropyl ether filtering off the excess 4,4'-sulfonyldiphenol. After each trituration the filtrate was concentrated in vacuo . The resulting crude product was chromatographed on silica gel, eluting with mixtures of heptane and ethyl acetate, to provide the coupler as an oil. Trituration with ethyl ether afford C-4 as a colorless solid, (3.58 g, 72%). The product was chromatographically homogenous and displayed an NMR spectrum consistent with its assigned structure. Anal. (dry 25°C): Fd.% (Calc.%) N 3.2 (3.2) C 65.1 (65.2) H 5.8 (5.8). Preparation of C-5 (a a representative protocol for the preparation of couplers bearing nitrogen heterocycles): A mixture of 1-benzyl-5-ethoxyhydantoin (CAS # 65855-02-9; 4.92 g, 21.0 mmol) in 70 mL DMAc was treated with potassium t-butoxide (2.16 g, 19.2 mmol). The mixture stirred at ambient temperature for 10 min then C-3 (5.00 g, 7.00 mmol) was added. The reaction mixture stirred at 55-60°C for 1.5 h. The mixture was the poured into cold dilute hydrochloric acid; an extractive work-up using ethyl acetate gave the crude product. Sequential silica gel chromatographies, eluting first with mixtures of heptane and ethyl acetate, then secondly with dichloromethane, gave the product as a glassy foam (4.66 g, 77%). The product was chromatographically homogenous and displayed an NMR spectrum consistent with its assigned structure. Anal. (dry 25°C): Fd.% (Calc.%) N 6.3 (6.5) C 66.8 (66.5) H 6.4 (6.4). Using these and analogous procedures couplers C-1 to C-10 were prepared. In addition, dyes were prepared as shown in Table II. PHOTOGRAPHIC EXAMPLES Example 1 Monochrome photographic coatings of several couplers were prepared: On a gel-subbed, acetate support were coated the following layers: First Layer : a photosensitive layer containing (per square meter) 3.23 g gelatin, 0.86 g blue-sensitized silver bromo-iodide emulsion, a coupler dispersion containing 2.69 x 10 -3 mole of coupler, 0.027 g surfactant Olin 10G, 0.055 g surfactant Triton X-200® (a 28 wt% solution in water of a mixture of sulfonated polyether alkylphenols of average MW = 380.). The coupler dispersion contained the coupler, coupler solvent (coupler : solvent 1:0.33 di-n-butyl sebacate), 6 % gelatin, and Alkanol XC (a 10 wt% solution in water of sodium salts of a mixture of mono-, di-, tri-, and tetra-isopropyl 2-naphthalene sulfonic acids) at a level equal to 10% of the weight of the gelatin in the dispersion. Second Layer : A protective layer containing (per square meter) 0.97 g gelatin and 0.086 g bis-(vinylsulfonyl)methane. Check samples were prepared using comparison couplers and dyes as follows: The samples were subjected to stepwise light exposure using the following exposure conditions: 1B sensitometer, 0.01 sec using HA-50, DLVa and 0.6 inconel filters, and 0-3 step tablet. Samples were then processed using process E-6 solutions and conditions as follows: Process Step Time (min.) Temp (C) Agitation 1st developer 3.0 36.9 N 2 burst (2" on, 8" off) 1st wash 2.0 36.9 Reversal Bath 2.0 36.9 Color Developer 6.0 36.9 N 2 burst Prebleach 2.0 36.9 Bleach 6.0 36.9 Continuous air Fixer 4.0 36.9 N 2 burst Final Wash 4.0 36.9 No Agitation The Status A transmission density of each step of the processed strip to blue light was read. The D-max, the step of highest density, was derived from these data. A series of couplers useful in this invention were compared to examples of known yellow couplers, and the results are presented in Tables IV and V. Coupler Photographic Responses 1 Compound Dmax Activity Ratio Cmp-5 4.29 1.53 Cmp-8 2.80 1.00 Cmp-9 3.83 1.37 Coupler Photographic Responses 2 Compound Dmax Activity Ratio Cmp-5 - 1.53 Cmp-8 1.46 1.00 Cmp-9 2.07 1.40 C-4 2.44 1.67 C-6 2.56 1.75 C-7 2.67 1.83 C-8 2.12 1.45 C-9 1.97 1.35 C-10 2.45 1.68 The data from Table IV show that comparative Cmp-9 displayed a 37% increase in activity over comparative Cmp-8 and that comparative Cmp-5 displayed an increase of 53%. In a second coating set (Table V), where the couplers were coated at reduced levels, a similar difference in activity of (40%) was encountered between Cmp-9 and Cmp-8. The Table also shows that the couplers useful in the invention are superior to the well established pivaloylacetanilide couplers (Cmp-8 and Cmp-9) with several affording a 70% increase in activity. The ratio data also demonstrate that the couplers useful in the invention can provide activity greater than that seen with Cmp-5. Example 2 As mentioned previously, many characteristics of a photographic image depend upon the spectral response of the dyes forming that image. The greater the molar extinction of an image-forming dye the less silver is needed to produce that dye; lower silver laydowns may lead to sharper photographic images. The color of a dye depends upon the position of its maximum light absorption (λ-max). With yellow dyes, the deeper (more bathochromic) the λmax of the dye the more orange the color of the dye. Orange dyes cannot be employed to effectively reproduce bright lemon yellows, thus lighter yellow dyes are preferred for better color reproduction. Finally, the ideal yellow dye absorbs only light in the blue portion of the visible spectrum; yellow dyes that absorb substantial amounts of green light appear desaturated and therefore yield poorer color reproduction. The bathochromic (long wavelength side) one-half bandwidth (B1/2BW) is a good measure of the degree of unwanted absorption of a yellow dye. The B1/2BW is the distance on the long wavelength side of the dye's spectral response curve, in nanometers, from the λmax to the wavelength of 1/2 the maximum absorption. The smaller the B1/2BW distance, the more sharp-cutting is the spectral response of a dye and the better the color reproduction available from the dye. The spectrophotometric response data for several dyes are summarized in Table VI. Dye Characteristics Compound λmax (nm) Extinction B1/2BW (nm) Cmp-1 430 12,800 42 Cmp-2 428 13,900 40 Cmp-3 426 13,700 40 Cmp-4 434 12,600 40 Cmp-7 428 11,800 42 D-1 426 19,700 32 D-2 426 10,000 37 D-4 428 16,200 37 D-5 428 16,800 37 D-6 426 17,300 38 D-7 430 14,100 35 D-8 426 16,600 33 D-9 422 19,300 34 D-10 424 17,700 35 D-11 426 21,300 33 D-12 430 20,100 33 D-14 438 11,900 46 The dyes useful in the invention generally display spectral responses superior to those of the art. These dyes show higher extinctions than the comparative examples with the best examples showing about a 50% increase in extinction. Furthermore, these dyes also afford much lower absorption of green light; since their B1/2BW's are substantially narrower than that of the comparison dyes. Example 3 The hydrolytic stability or acid catalyzed decomposition of yellow azomethine dyes is an important pathway in the degradation of photographic images. It is believed that the stability of yellow dyes toward acidic hydrolysis is predictive of their stability in color photographic images. The rates of hydrolysis of a variety of dyes have been measured using an accelerated solution test format. The dyes (1.0 mM dye in 6% Triton X-100®) in buffered acidic solutions (pH = 2.0, µ = 0.2, phosphate buffer) were held at 50°C. The rates of dye destruction were monitored using standard HPLC procedures. Under these conditions the dyes exhibited first-order fade kinetics; the rate constants and associated half-lives are reported in Table VII. These data clearly show that the dyes derived from the couplers useful in the invention generally afford much greater hydrolytic stability than that provided by the comparison dyes. Kinetics of Yellow Dye Hydrolysis Compound k obs rate of hydrolysis (x 10 6 )s -1 t 1/2 -time for 1/2 the dye to hydrolyze (hr) Cmp-10 5.57 35 Cmp-11 12.1 16 Cmp-6 2.48 78 D-15 0.17 1,150 D-16 0.38 500 D-17 0.31 610 D-18 9.63 20 D-19 1.91 101 As can be seen, the time to degradation of 1/2 of the dye sample is far longer, in general, for the dyes useful in the invention than for the comparison dyes. Example 4 : A multilayer photographic element designed for reversal processing in accordance with Process E-6 of Eastman Kodak Co. provides useful yellow images and is constructed on a gel-subbed acetate support in the following manner. Amounts are in grams per square meter. Laydowns of silver containing components are expressed in grams of silver per square meter. Layer 1: Antihalation Layer Black colloidal Silver 0.25 (as silver) UV Dye UV-1 0.04 Dispersed in Solvent S-1 0.04 Gelatin 2.44 Layer 2: First Interlayer Fine Grain Silver Bromide 0.055 µm equivalent spherical diameter 0.05 (as silver) SCV-1 0.05 Gelatin 1.22 Layer 3: Low speed Red Sensitive Layer Silver iodobromide emulsion 0.50µm (diameter) by 0.058 µm (thickness) 4% bulk iodide emulsion spectrally sensitized with dyes SD-0 and SD-1 0.25 (as silver) Fine Grain Silver Bromide 0.055 µm equivalent spherical diameter 0.04 (as silver) Cyan Coupler Cy-1 0.09 Dispersed in Solvent S-3 0.04 Gelatin 1.08 Layer 4: Medium Speed Red Sensitive Layer Silver Iodobromide Emulsion 0.88 µm (diameter) by 0.091 µm (thickness) 4% bulk iodide spectrally sensitized with dyes SD-0 and SD-1 0.34 (as silver) Fine Grain Silver Bromide 0.055 µm equivalent spherical diameter 0.05 (as silver) Cyan Coupler Cy-1 0.41 Dispersed in Solvent S-3 0.20 Gelatin 0.73 Layer 5: High Speed Red Sensitive Layer Silver Iodobromide Emulsion 1.11 µm (diameter) by 0.103 µm (thickness) 3% bulk iodide spectrally sensitized with dyes SD-0 and SD-1 0.46 (as silver) Fine Grain Silver Bromide 0.055 µm equivalent spherical diameter 0.03 (as silver) Cyan Coupler Cy-1 0.70 Dispersed in Solvent S-3 0.35 Gelatin 1.19 Layer 6: Second Interlayer Filter Dye FD-1 0.06 Inhibitor I-1 0.001 SCV-1 0.16 Gelatin 0.81 Layer 7: Third Interlayer Gelatin 0.61 Layer 8: Low Speed Green Sensitive Layer Silver Iodobromide Emulsion 0.44 µm (diameter) by 0.057 µm (thickness) 4% bulk iodide spectrally sensitized with dyes SD-4 and SD-5 0.31 (as silver) Fine Grain Silver Bromide 0.055 µm equivalent spherical diameter 0.04 (as silver) Magenta Coupler M-1 0.07 Magenta Coupler M-2 0.03 co-dispersed in Solvent S-2 0.05 Gelatin 0.47 Layer 9: Medium Speed Green Sensitive Layer Silver Iodobromide Emulsion 0.64 µm (diameter) by 0.105 µm (thickness) 3% bulk iodide spectrally sensitized with dyes SD-4 and SD-5 0.38 (as silver) Fogged silver Iodobromide Emulsion 0.0005 (as silver) Magenta Coupler M-1 0.34 Magenta Coupler M-2 0.15 Co-dispersed in Solvent S-2 0.25 Gelatin 0.91 Layer 10: High Speed Green Sensitive Layer Silver Iodobromide Emulsion 1.26 µm (diameter) by 0.137 µm (thickness) 3% bulk iodide spectrally sensitized with dyes SD-4 and SD-5 0.54 (as silver) Magenta Coupler M-1 0.72 Magenta Coupler M-2 0.31 Co-dispersed in Solvent S-2 0.52 Gelatin 1.78 Layer 11: Fourth Interlayer Gelatin 0.61 Layer 12: Fifth Interlayer Carey Lea Silver 0.07 (as silver) SCV-1 0.11 Gelatin 0.68 Layer 13: Sixth Interlayer SCV-1 0.05 Gelatin 1.22 Layer 14: Low Speed Blue Sensitive Layer Silver Iodobromide Emulsion 1.04 µm (diameter) by 0.125 µm (thickness) 3% bulk iodide spectrally sensitized with dyes SD-6 and SD-7 0.22 (as silver) Silver Iodobromide Emulsion 0.50 µm (diameter) by 0.130 µm (thickness) 3% bulk iodide spectrally sensitized with dyes SD-6 and SD-7 0.15 (as silver) Yellow Coupler of Formula A, B, C, D, or E 0.4-.9 Dispersed in Solvent S-3 0.25-0.90 Gelatin 1.23 Layer 15: High Speed Blue Sensitive Layer Silver Iodobromide Emulsion 2.59 µm (diameter) by 0.154 µm (thickness) 2% bulk iodide spectrally sensitized with dyes SD-6 and SD-7 0.67 (as silver) Yellow Coupler of Formula A, B, C, D, or E 0.5-1.80 Dispersed in Solvent S-3 0.51 PC-1 0.02 Gelatin 2.03 Layer 16: First Overcoat SCV-1 0.07 UV Dye UV-4 0.41 UV Dye UV-1 0.09 Dispersed in Latex L-1 0.45 PC-1 0.06 Gelatin 1.40 Layer 17: Second Overcoat Fine Grain Silver Bromide 0.055 µm equivalent spherical diameter 0.12 (as silver) Matte 3.3 µ spherical diameter 0.02 Hardener H-1 1.38% of total gel Gelatin 0.97 The exposed strips were processed in the standard E-6 process. The components employed for the preparation of light-sensitive matenals not already identified above are shown below: S-1 1,4-Cyclohexylenedimethylene bis(2-ethylhexanoate) S-2 Phosphoric Acid, tris(methylphenyl) ester S-3 1,2-benzenedicarboxylic acid, dibutyl ester In concert, the foregoing data, relating to coupler activity, dye hue and dye stability, clearly establish that the invention is photographically useful and that embodiments of the invention are superior in several respects to the established coupler classes.

Claims: A photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler having Formula F-1: wherein: (1) W 1 is a -NR- or -SO 2 - group wherein R is hydrogen or a substituent; (2) one of W 2 and W 3 is a substituent group and the other is a group of Formula F-2: in which X is hydrogen or a coupling-off group and Y and Z are independently selected from hydrogen or a substituent; and (3) W 4 is a group of atoms necessary to form a fused ring with the ring containing W 1 ; (4) provided that substituents may join to form a ring. The element of claim 1 wherein W 1 is -NR- wherein R is hydrogen or a substituent. The element of claim 1 wherein W 1 is -SO 2 -. The element of claim 1 wherein W 2 is represented by formula F-2. The element of claim 1 wherein W 3 is represented by formula F-2. The element of claim 1 wherein W 4 represents the atoms necessary to complete an aromatic or nonaromatic carbocyclic group. The element of claim 6 wherein W 4 represents the atoms to form a phenylene group. The element of claim 1 wherein W 4 represents the atoms necessary to form an aromatic or nonaromatic heterocyclic group. The element of claim 1 wherein Y is a phenyl group and Z is H. The element of claim 9 wherein formula F-2 is represented by formula F-3: wherein R 2 is hydrogen or a substituent; R 3 is a substituent containing an electron withdrawing group; X is hydrogen or a coupling-off group and "n" is 0-4. The element of claim 9 wherein formula F-2 is represented by formula F-4: wherein R 2 is a chloro or alkoxy group; R 3 is a substituent containing an electron withdrawing group and the arc is intended to indicate that at least one R 3 substituent is present in the 4- or 5- position of the anilino ring; and X is hydrogen or a coupling-off group. The element of claim 1 wherein X is a coupling-off group. The element of claim 1 wherein X is a coupling-off group selected from the group consisting of halogen, aryloxy, arylthio, and N-heterocycle. The element of claim 13 wherein X is represented by formula X-1: wherein R 5 is a substituent and "m" is 0-5. The element of claim 14 wherein X is represented by formula X-2: wherein R 5 is an electron withdrawing substituent and R 6 is hydrogen or a substituent. The element of claim 1 wherein X is a N-heterocycle linked to the coupling site by a nitrogen atom of the heterocycle. The element of claim 1 wherein the coupler has formula A: in which R a is -SO 2 CH 3 , -SO 2 CH 2 CH 3 , -SO 2 NHCH 3 , or -SO 2 N(CH 3 ) 2 ; R g is methyl or phenyl; and R b is -SO 2 - or -SO 2 NH-. The element of claim 1 wherein the coupler has formula B: in which R e is an alkyl group of 1-20 carbon atoms; R c and R d are independently selected substituents; and "q" is 0-5 and "p" is 0-4. The element of claim 1 wherein the coupler has formula C: in which R h and R i are independently selected alkyl or aryl groups; X is H or a coupling-off group; R f is halogen or alkoxy; R d is a substituent; and "p" is 0-4. The element of claim 1 wherein the coupler has formula D: in which W represents the atoms necessary to form a six-membered carbocyclic group; R h and R i are independently selected alkyl or aryl; X is H or a coupling-off group; R d is a substituent; and "p" is 0-5. The element of claim 1 wherein the coupler has the formula: in which W represents the atoms necessary to form a six-membered carbocyclic or heterocyclic aromatic or non-aromatic group; R h and R i are independently selected alkyl or aryl groups; X is H or a coupling-off group; R d is a substituent; and "p" is 0-5. The element of claim 1 wherein the coupler has the formula: in which W represents the atoms necessary to form a six-membered carbocyclic or heterocyclic aromatic or non-aromatic group; R h and R i are independently selected alkyl or aryl groups; X is H or a coupling-off group; R d is a substituent; and "p" is 0-5. A multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, characterised in that the yellow dye-forming coupler has the formula as defined in any one of the preceding claims. A process for forming a positive image in an element as defined in claim 23 after the element has been imagewise exposed to light comprising contacting the element with a black and white developer and thereafter contacting the element with a para-phenylenediamine color developing chemical to form a positive of the image. A process for forming a color negative of an image in an element as defined in claim 23 after the element has been imagewise exposed to light comprising contacting the element with a para-phenylenediamine color developing chemical.

Inventors: REYNOLDS JAMES HENRY, WELTER THOMAS ROBERT, REYNOLDS, JAMES HENRY, WELTER, THOMAS ROBERT, Reynolds, James Henry, Eastman Kodak Company, Welter, Thomas Robert, Eastman Kodak Company
Applicants: EASTMAN KODAK CO, EASTMAN KODAK COMPANY
Application year: 1999
Main classification: G03C7
IPC codes: G03C7, C07D471, C07D209