Shielding tape and shielding wire using the same

Abstract: A shielding tape, wherein a shielding layer is laminated on one side with an adhesive agent layer for a core for adhering an insulation shielding material of a core wire, and laminated on the other side with a reinforcing seat layer, and laminated with an adhesive agent layer for a sheath for adhering the sheath on the reinforcing seat layer, is characterized in that adhesive strength of the adhesive agent layer for the core to the insulation shielding material is smaller than adhesive strength between the respective layers. Preferably, the shielding materials and the sheath are composed of a non-halogen material, the adhesive agent for core and the adhesive agent for sheath are composed of the non-halogen material, and adhesive force of the adhesive agent for core to the insulating material is smaller than adhesive force of the adhesive agent for sheath to the sheath.

Description: This invention relates to a shielding wire for electronic equipment such as copier, facsimile and so on, audio set as tape recorder and the like, and further for automobiles and a shielding tape to be used to the shielding wire, and in particular such a shielding wire of flat cable type which may contribute to improvement of productivity, yielding almost nothing of badness or poor results at processing terminals of the shielding wire and excellent in shielding effect of electromagnetic noises, and shielding wires using the same. Further, this invention relates to a shielding wire composed of a material tender to environments not containing halogen material issuing substances polluting environments as hydrohalogen and not spoiling properties as the shielding wire nor missing productivity. A shielding wire of flat cable type as shown in Fig.1 has been used as a shielding wire for electronic equipment as copier, facsimile and the like, or for audio set. In the flat cable type shielding wire, core wires 3, 3 formed integrally by wrapping lead wires 1 with insulation sheathing materials 2 (generally polyvinyl chloride) and drain wire 4 are arranged in parallel with fixed distances, and a shielding tape 5 is adhered closely on allover outer peripheries of the core wires 3, 3 and the drain wire 4, while the shielding tapes 5 are adhered each other to form bridging parts 7 7'for securing the fixed distances. The shielding tapes 5 are further protected on the surfaces with sheaths 6 (generally polyvinyl chloride). In the shielding wire of such a structure, the insulation shielding material 2 and the sheath 6 are generally excellent in heat resistance, insulation and flexibility, and polyvinyl chloride cheap in cost is used. The shielding tape, as shown in Fig.2A, comprises a shielding layer 11, a reinforcing seat layer 12 laminated on the side of a sheath 6 of the shielding layer 11, a sheath adhesive agent layer 13 for adhering the reinforcing seat layer 12 and the sheath, and a core adhesive agent layer 14 for adhering the shielding layer 11 and the core wire 3. The shielding layer 11 is generally composed of a combination of a metal foil 11a of high electric conductivity as copper or aluminum and a metal foil 11b of high permeability as iron or tin. Since the reinforcing seat layer 12 is insufficient in strength only with the shielding layer 11 composed of the metal foil, it is ordinarily laminated with a polyester seat in view of cost and strength. Note that shielding tapes without laminating the reinforcing seat layer are included in the range of the invention. Presently, for the sheath adhesive agent layer 13, adhesive agents of polyethylene terephthalate (hereafter briefly called as "PET") group mainly are used, and for the core adhesive agent layer 14, adhesive agents of copolymer of vinyl chloride and vinyl acetate (hereafter briefly called as "vinyl chloride-vinyl acetate copolymer") mainly are used. The core adhesive agent layer 14 is, as shown in Fig.2B, formed by coating the core adhesive agent in oblique stripes on one side of the shielding layer 11. That is, parts 14a to be coated with the core adhesive agent and parts 14b not to be coated are alternately arranged in a lengthwise direction of the tape, and in the non coating parts 14b, the metal foils composing the shielding layer 11 are exposed. Thus, via the non-coating parts 14b, the drain wire 4 and the metal foil composing the shielding layer 11 are directly contacted to provide electric conductivity. The shielding tape 5 is thereby earthed to shield electromagnetic waves internally and externally of the cable causing strains of signals or noises. On the other hand, by adhesion of the coating part 14a of the core adhesive agent layer 14, the shielding tape 5 closely adheres the core wire 3 to prevent it from slipping out, and to form bridges 7, 7' between the core wires 3 and 3 as well as between the core wire 3 and the drain wire 4 to prevent misregistration of the core wire 3. With respect to processing at terminal of the shielding wire of flat cable type having such structure, an outermost diameter of the portion of the drain wire 4 (outer diameter shielded with the shielding tape 5 and the sheath 6) is made equal to the outer diameter of the core wire 3, and the terminal is processed by a pressure connection system. The pressure connection system is, as shown in Fig.3, that a condition where the sheath 6 and the shielding tape 5 shielding the core wires 3 are scaled off to expose the core wires 3 and the portion of the drain wire 4 is covered with the shielding tape 5 and the sheath 6, and under such condition, contact pins 20 are inserted in a bundle. The insertion of the contact pin 20 is that connecting terminals (not shown) having the connecting contact pins 20 as shown in Fig.4A by the number corresponding to a total amount of the core wires 3 and the drain wires 4, are inserted with the exposed core wires 3 (Fig.4B), and further the core wires 3 are pushed such that the contact pins 20 contact the conductors 1 (Fig.4C), and is furthermore forced into (Fig.4D), whereby the conductors 1 break through the insulation shielding materials 2 and contact the contact pins 20. In a case of the drain wire 4, the contact pin 20 breaks through the shielding tape 5 and sheath 6, and contacts the drain wire 4. In such a connection system, by keeping fixed a pitch between the contact pins 20, 20, a pitch between the core wires 3, 3 and a pitch between the core 3 and the drain wire 4, it is possible to automatically cut the shielding wires, exfoliate the shielding tape 5 and the sheath 6, and automatically attach the connecting terminals by pressure. Therefore, for connecting exactly the conductors 1 of the plurality of core wires 3 in the shielding wires and the contact pins 20 in a bundle, it is necessary to fix the pitch between the core wires 3, 3 and the pitch between the core wires 3 and the drain wire 4 in response to the pitch between the pitches 20, 20. For this, the shielding tape 5 should be close with the core wire 3 and the drain wire 4 so as to prevent the core wire from misregistration even after scaling off the shielding tape 5 and the sheath 6. On the other hand, in case that the adherence between the shielding tape 5 and the core wire 3 is too high, when exfoliating the sheath 6 and the shielding tape 5 from the terminal of cut face, only the sheath 6 is removed, and the shielding tape 5 is left on the core wire 3 as adhered. If the shielding tape 5 is adhered to the core wire 3, the contact pin 20 and the shielding layer 11 of the shielding tape 5 may be probably contacted, and in such a case the contact shorts till the drain wire 4 via the shielding layer 11 to cause badness. For solving such problems, as a shielding wire, where the exfoliation of the shielding tape is made easy to prevent poor results to be caused by processing at the terminals, for example, JP-A-4-133319U gazette proposes a shielding wire where a core wire is shielded on an overall outer periphery with a tape coiled layer coated with a mold releasing agent, and thus the shielding wire is covered with the shielding tape via the tape coiled layer. Following such a structure, the shielding tape is easily released from the core wire, and between core wires and between a core wire and a drain wire, the core wire can be prevented from misregistration by closely mutual adherence of shielding tapes. However, a one process for forming the tape-coiled layer is added, and this leads to a cost-up. On the other hand, for making the exfoliation work easy, it may be assumed to make small the areas of the coating parts 14a of the core adhesive agent layers 14. But the making small of the area of the coating part 14b leads to lowering of the adhesive force between the core wire 3 and the shielding tape 5, and lowering of the adhesive force between the mutual shielding tapes at the bridge parts 7, 7', resulting with problems of misregistration and slipping out of the core wire, and this is not always a useful instrument. In the shielding tapes generally now used, areas connecting between the mutual coating parts 14a are made larger than areas between the coating parts 14a and the non coating parts 14b of the core adhesive agent of the shielding tape 5 in the bridge parts 7, 7' so as to strengthen fixing of positions of the core wires 3, and for this purpose, an area of the coating part 14a is made larger than that of the non coating parts 14b. In short, a width (W1) of the coating part 14a is set to be larger than a width (w2) of the non coating part 14b. Actually, a length (W1) of the coating part 14a is around 2mm and a length (W2) of the non-coating part 14b is around 1mm. As shielding wires for automobiles, collective strands of the core wires and the drain wires are cylindrically covered with the shielding tape. But since the flat cable type has merits of capable of omitting bundle of wires during production and reducing steps of processing the terminals of the shielding wire, consideration is made for changing to flat cable type similarly to public welfare shielding wires for audio sets, electronic equipment and the like. If changing automobile shielding wires to the flat cable type, the shielding wires of the flat cable type to be produced for public welfare may be employed, thereby enabling to centralize the production line, resulting in saving production cost. However, for development of recent electronics in automobiles, demand for shielding properties to the automobile shielding wires is inteisive, and shielding wires of flat cable type now on sale for public welfare cannot satisfy such demand nor be employed as they are. When polymer containing halogen and polyvinyl chloride is exposed at high temperature (80 to 120°C) not completely burning, it issues poisonous gas as hydrohalogen gas. For solving the problem for environmental measures, it is assumed to employ non-halogen materials such as polymer of polyolefin group as materials for the sheath and the insulation shielding material. However, when substituting the materials of polyolefin group for the sheath and the insulation shielding material in the flat cable typed shielding wire, the balance of the adhesive force of the shielding tape to the sheath and the insulation shielding material is broken, and a new problem arises that yielding of inferior products increases at processing terminals of the shielding wires. The adhesive agent of PET group generally used as the sheath adhesive agent is weak in the adhesive force for the adhesive agent of polyolefin group, and in case that only the sheath is scaled off in an exfoliation work, and shielding tape is adhered and left on the surface of the core wire. In addition, the adhesive agent of vinyl chloride-vinyl acetate group may issue poisonous gas causing environmental pollution as polyvinyl chloride, and so it is desired to change to non-halogen materials. SUMMARY OF THE INVENTION The invention has been realized in view of these circumstances, and it is an object to provide such shielding tapes of less causing badness or poor results in the terminal process and enabling to increase yields as securing close adherence with the core wire, and to offer shielding tapes for shielding wires of flat cable type having excellent shielding characteristics enabling to be applied to automobiles and shielding wires of flat cable type. Further, it is provided a shielding wire where material composing the shielding wire is changed to non-halogen materials, and in a property as the shielding wire and processability of the terminal of shielding wire, equivalent degree to the conventional ones may be maintained. Namely, the shielding tape of the invention is that a shielding layer is laminated on one side with an adhesive agent layer for core for adhering an insulation shielding material of core wire, and laminated on the other side with a reinforcing seat layer, and laminated with an adhesive agent layer for sheath for adhering the sheath on the reinforcing seat layer, characterized in that adhesive force of the adhesive agent layer for core to the insulation shielding material is smaller than adhesive force between the respective layers. The core adhesive agent layer comprises coating parts and non coating parts of core adhesive agent, and it is preferable that adhesive strength of the core adhesive agent to be applied to the coating part to the insulation shielding material is smaller than strength of a sheath adhesive agent to be applied to the sheath adhesive agent layer to the sheath. Further, it is preferable that the adhesive strength of the sheath adhesive agent to the reinforcing seating layer is larger than strength of the core adhesive agent to the insulation shielding material. In particular, it is preferable that the core adhesive agent is polyethylene terephthalate group and the sheath adhesive agent is vinyl chloride-vinyl acetate copolymer group. It is preferable that the coating parts and the non coating parts are disposed alternately in a lengthwise direction of the tape, and the width of the coating part and that of the non coating part are equal, and the width of the coating part is 1 to 2mm. It is preferable that the shielding tape is interposed between a plurality of core wires in shielding wires of flat cable type in parallel disposed in fixed distances with the core wires and the sheath wrapping the core wires in a bundle. In the shielding wire of flat cable type of the invention that a plurality of core wires are in parallel disposed in fixed distances, a shielding tape is furnished to secure the fixed distances by adhering to shield the core wires in a bundle, and the shielding tape is protected on an outer surface with the sheath, the shielding wire of the invention is characterized in that the shielding tape is protected on an outer surface with a sheath, and the shielding tape of the invention is employed as the shielding tape. It is preferable that difference (|SPc - SPz|) between SP value (SPc) of the core adhesive agent and SP value (SPz) of an insulation shielding material is larger than difference (|SPs - SPt|) between SP value (SPs) of the sheath adhesive agent for sheath and SP value (SPt) of the sheath, and in particular the insulation shielding material and the sheath are polyvinyl chloride. In the instant description, the adhesive force is meant by strength of exfoliation resistance, taking the coating are of the adhesive agent into consideration, depending upon not only kinds of the adhesive agents and opponent materials but also the coating areas. The adhesive strength is meant by strength of exfoliation resistance when applying the adhesive agent allover faces, depending upon kinds of the adhesive agents and the opponent material. A shielding wire of the invention, wherein core wires composed by shielding conductors with insulating materials are arranged in parallel with fixed distances, core wires are stuck on outer peripheries with a shielding tap by an adhesive agent for core, securing the fixed distances with the shielding tape, and the shielding tape is stuck on an outer periphery with an adhesive agent for sheath, the shielding wire being of flat cable type, is characterized in that the shielding materials and the sheath are composed of a non-halogen material, the adhesive agent for core and the adhesive agent for sheath are composed of the non-halogen material, and adhesive force of the adhesive agent for core to the insulating material is smaller than adhesive force of the adhesive agent for sheath to the sheath. It is preferable that the insulating material and the sheath are composed of a material of polyolefin group, and the adhesive agent for sheath is composed of a material of polyolefin group. It is preferable that the adhesive agent of polyethyleneterephthalate group is used as the adhesive agent for core. The shielding wire of the invention is suitably served in atmosphere at temperature of 120°C or less. BRIEF DESCRIPTION OF THE PREFERRED EMBODIMENTS Fig. 1 is a cross sectional view showing a structure of the shielding wire of flat cable type to be applied with the shielding tape; Fig. 2A is a cross section view for explaining the structure of the shielding tape, Fig. 2B is a bottom section; Fig. 3 is a view for explaining process at terminals; Figs. 4A to 4D are views for explaining process at terminals; Fig. 5A is a cross section view showing a structure of another embodiment of the shielding tape, and Fig. 5B is a bottom section; Fig.6 is a cross sectional view showing a structure of another embodiment of the shielding wire of flat cable type to be applied with the shielding tape; and Fig.7 is a view for explaining the measuring method of the shielding property of the shielding wire. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS First Embodiment At first, explanation will be made to one embodiment of the shielding tape of the invention, referring to Fig.1. The shielding tape of the instant embodiment is suitably used to the shielding wire of flat cable type as shown in Fig.1, and the structure as shown in Fig.2 is characterized in that the adhesive force of the core adhesive agent layer 14 to the insulation shielding material is smaller than the adhesive force between the respective layers, that is, the adhesive force between the core adhesive agent layer 14 and the shielding layer 11, between the shielding layer 11 and the reinforcing seat layer 12 and between the reinforcing seat layer 12 and the sheath adhesive agent layer 13. Namely, the basic structure of the inventive shielding tape, as shown in Fig.2A, comprises the shielding layer 11, the reinforcing seat layer 12 laminated on the side of the sheath 6 of the shielding layer 11, the sheath adhesive agent layer 13 for adhering the reinforcing seat layer 12 and the sheath, and the core adhesive agent layer 14 for adhering the shielding layer 11 and the core wire 3. The core adhesive agent layer 14 comprises the part 14a coated with the core adhesive agent and the not coated part, i.e., the part 14b exposing the shielding layer 11, and the coated parts 14a and the non coated parts 14b are arranged alternately in oblique stripes in the lengthwise direction of the tape. The shielding layer 11 is generally composed of a combination of the metal foil 11a of high electric conductivity as copper or aluminum and the metal foil 11b of high permeability as iron or tin. Since the reinforcing seat layer 12 is insufficient in strength only with the shielding layer 11 composed of the metal foil, it is ordinarily laminated with a polyester seat in view of cost and strength. As long as the condition is satisfied that the adhesive force of the core adhesive agent layer 14 to the insulation shielding material is smaller than the adhesive force between the respective layers, kinds of the core adhesive agent and the sheath adhesive agent are not specially limited, but may be selected appropriately in response to kinds of the reinforcing seat, the sheath material and the insulation shielding material, and it is preferable to select such adhesive agents where the adhesive strength of the sheath adhesive agent to the reinforcing seat material layer 12 is larger than that of the core adhesive agent to the insulation shielding material. Herein, the adhesive force or the adhesive strength referred to in the invention means actual adhesive force or adhesive strength available when an exfoliation test is performed that 2 sheets of insulation shielding tests pieces are adhered with an adhesive agent to be measured, and these 2 sheets are pulled in opposite directions respectively by a tensile testing machine and exfoliated. The adhesive force is a value, taking the coating area into consideration, and the adhesive strength is a value measured by coating the adhesive agent allover. For selecting actual adhesive agents, a standard can be set up at solubility parameter (SP). It is sufficient to select the adhesive agent such that difference (|SPc - SPz|) between SP value (SPc) of the core adhesive agent and SP value (SPz) of an insulation shielding material is larger than difference (|SPs - SPt|) between SP value (SPs) of the sheath adhesive agent for sheath and SP value (SPt) of the sheath. For example, when the insulation shielding material of the core wire and the sheath material are made of polyvinyl chloride (PS value is 9.55), it is sufficient to select the adhesive agent such that the SP value of the sheath adhesive agent is nearer to the SP value of polyvinyl chloride than the SP value of the core adhesive agent. Accordingly, when the polyvinyl chloride is used as the insulation shielding material and the sheath material, vinyl chloride-vinyl acetate copolymer (SP value is 9.4 to 9.55), the adhesive agent of polyvinyl chloride group (SP value is 9.55), the adhesive agent of polyvinyl acetate group (SP value is 9.4), polymethylmethacrylate (SP value is 9.4) or polyethylacrylate (SP value is 9.7) may be used as the sheath adhesive agent. Among them, vinyl chloride-vinyl acetate copolymer is preferable in cost and others. Further, as the adhesive agent, other than the adhesive agent of polyethyleneterephthalate group, the adhesive agent of polymethacrylonitrile group (SP value is 10.6), the adhesive agent of polypropylacrylate (SP value is 9.0) and the adhesive agent of polybutylmethacrylate (SP value is 9.0) may be used. Among them, the adhesive agent of PET group is preferable. Further, it is preferable that the adhesive strength of the sheath adhesive agent to the reinforcing seat layer 12 is larger than the adhesive strength of the core adhesive agent to the insulation shielding material. When a seat of PET is used as the reinforcing seat layer 12, preferably, the sheath adhesive agent is selected such that the difference between the SP value of the seat adhesive agent and the SP value of PET is smaller than the difference (|SPc-SPz|) between the SP value (SPc) of the core adhesive agent and the SP value (SPz) of the insulation shielding material. For securing the close adherence of the core wire and the shielding tape not to cause misregistration or slipping out of the core wire, it is preferable to select an area ratio of the coating part 14a and the non coating part 14b in the core adhesive agent layer 14 within range of 1:2 to 2:1. In addition, when request for the shielding characteristics is severe as the shielding wire for automobile, preferably as shown in Fig.5, the width W1 of the coating part 14a and the width W2 of the non coating part 14b are made equal. Because, the larger the area of the non coating part 14b is, the larger the area is, where the non coating part 14b, that is, an exposed part of the shielding layer 11 contacts the drain wire, so that the shielding effect of electromagnetic noises can be heightened as securing the adhesive force of preventing misregistration and slipping out of the core wire. The width W1 of the coating part 14a (the width W2 of the non coating part 14b) is 1 to 2mm, preferably 1.3 to 1.7mm, most preferably around 1.5mm. Because, in a case of more than 2mm, the number of the coating parts 14a per length of the tape is less, and lowering of the adhesive force is invited. On the other hand, it is not preferable that the width W1 is made narrower less than 1mm and the number of the coating parts 14a is increased. There may probably occur cases that under high temperature circumstances or at pressing work at high temperature, the coating part 14a is melted and flows into the non coating part 14b, and if the length W2 of the non coating part is narrow as less than 1mm, the melted coating part goes from a next non coating part into a coating part. In such cases, the contacting area of the non-coating part 14b and the drain wire is reduced, resulting in lowering of the shielding characteristics of electromagnetic noises. In the conventional shielding tape, when the length W 1 of the coating part 14a and the width W2 of the non coating part 14b were made equal, the area of the coating part 14a was reduced, and consequently, the adhesive force was lowered to bring about misregistration or slipping out of the core wire. But, in the inventive shielding tape, such problems do not occur for the following reasons. Namely, that the adhesive force of the core adhesive agent layer to the insulation shielding material is smaller than the adhesive force exerting between the core adhesive agent layer 14 and the shielding layer 11, means that the adhesive force of the mutual coating parts 14a of the core adhesive agent in the bridge parts of the shielding wire and the adhesive force of the non coating part 14b exposing the shielding layer 11 are larger than the adhesive force of the core adhesive layer 14 and the core wire, and because the positioning of the core wire is fixed stably when processing the terminal. By setting the width W1 of the coating part 14a within the above range, the number of the coating part 14a per a unit length of the tape is increased in comparison with the conventional shielding tape, and the adherence with the core wire can be secured. As long as the above requirements are satisfied in the inventive shielding tape, no limitations are made to kinds of the reinforcing seat materials, metals composing the shielding layers and laminating ways of them. Shielding tapes without laminating the reinforcing seat layers are included in the range of the shielding tape of the invention. A further reference will be made to the shielding wire of the invention. The inventive shielding wire is of flat cable type using the inventive shielding tape, for example, composed as shown in Fig.1. When using the shielding wire of the invention, the shielding tape 5 is scaled off together with the sheath 6 in the exfoliating process of the sheath 6 at processing the terminal and the shielding tape 5. Because the adhesive force of the core adhesive agent layer 14 to the core wire is weakest. On the other hand, since the core adhesive agent layers are mutually combined integrally as conventionally, the core 3 does not suffer from slipping out or misregistration. In short, the exfoliation can be carried out as keeping fixed the pitch between the core wires 3 and the pitch between the core wire 3 and the drain wire 4. Thus, in the flat cable typed shielding wire using the shielding tape of the invention, the sheath 6 and the shielding tape 5 can be scaled off as keeping the pitch between the core wires 3, 3 and the pitch between the core wire 3 and the drain wire 4, not leaving the shielding tape 5 on the insulation shielding material 2 of the more wire 3, and it is possible to reduce extremely low occurrence of bad products in automatic processing by the pressure connecting system. The structure of the inventive shielding wire is not limited to that of Fig.1. In the invention, the flat cable typed shielding wires, i.e., a plurality of core wires are arranged in parallel with fixed distances, and these core wires are adhered and shielded in a bundle, thereby to provide the shielding tapes securing the fixed distances. Thus, the shielding tape may be applied allover to the shielding wires realized by shielding the outer surface of the shielding tape. For example, the position relative between the drain wire and the core wire is not especially limited, and as shown in Fig. 6, the drain wire may be positioned between the core wires 3, 3. Explanation for an embodiment of Fig.6 is omitted by giving the same numerals as in Fig.1. In case of providing a mechanism earthing the shielding tape, such a flat cable typed shielding wire not arranging the drain wire in parallel with the core wire is sufficient. The number of core wires in the shielding wire is not limited to two pieces, and a flat cable typed shielding wire having a plurality of core wires of three or more pieces is sufficient. The inventive shielding tape usefully exhibits function thereof in the flat cable typed shielding wire, and does not exclude application to shielding wires of other types. [Example] [Production of the shielding tape and the flat cable typed shielding wire] In the shielding tape shown in Fig.5, there were used the adhesive agent of polyethyleneterephthalate group as the core adhesive agent, and the adhesive agent of vinyl chloride-vinyl acetate copolymer as the sheath adhesive agent. The coating parts and the non-coating parts in the core adhesive agent layer were equal as 1.5mm (W1 = W2 = 1.5mm). In addition, the PET seat as the reinforcing seat layer 12 was adhered with a copper foil by a PET adhesive agent, and the copper foil was vapor-deposited with tin so as to produce a shielding layer 11 composed of the copper layer and the tin layer. The shielding tape having such a structure was used to produce the flat cable typed shielding wire as shown in Fig.1. The insulation shielding material 2 and sheath was composed of polyvinyl chloride. [Observation and consideration of the adhesive force and the adhesive strength] With respect to the sheath and core adhesive agents, the adhesive strength to the polyvinyl chloride was measured. The measuring was performed by adhering the two sheets of polyvinyl chloride testing pieces with the respective adhesive agents, pulling them in opposite directions by the tensile testing machine and measuring tensile force when the two sheets were scaled off. The adhesive strength of the sheath adhesive agent (vinyl chloride-vinyl acetate copolymer group) to the polyvinyl chloride was around 170g, and the adhesive strength of the core adhesive agent (PET group) to the polyvinyl chloride was around 120g. The SP value of adhesive agent of polyethylene terephthalate group was 10.6, the SP value of vinyl chloride- vinyl acetate copolymer ranged 9.4 to 9.55, though varying in dependence on the ratio of contents of respective monomers, and the SP value of polyvinyl chloride was 9.55. The relation of the respective SP values is as under and satisfies the requirement of the invention. The difference between the SP value of the core adhesive agent (SPc) and the SP value of the insulation shielding material (SPz) |SPc - SPz| = 1.05 to 1.2, The difference between the SP value of the sheath adhesive agent (SPs) and the SP value of the sheath |SPs - SPt| = 0 to 0.15, and The difference between the SP value of the reinforcing seat (SPh) and the SP value of the sheath adhesive agent (SPs) |SPh - SPs| = 1.05 to 1.2. Herein, since the reinforcing seat adhesive agent and the core adhesive agent are composed of the PET group, the difference (|SPc-SPz|) between the SP value of the core adhesive agent and the SP value of the insulation shielding material is equal to the difference (|SPh-SPs|) between the SP value of the reinforcing seat and the SP value of the sheath adhesive agent. But the coating area of the core adhesive agent is 40 to 50%, while the sheath adhesive agent is coated allover the reinforcing seal layer, and so the adhesive force between the sheath adhesive agent and the reinforcing seat is larger than the adhesive force of the core adhesive agent to the insulation shielding material. Accordingly, this fact satisfies the requirement of the invention that the adhesive force of the core adhesive agent to the insulation shielding material is smaller than the adhesive force between the respective layers in the shielding tape. [The process of terminals of the shielding wire] When the produced shielding wire was automatically processed at the terminal by the pressing system, the shielding tape was scaled off together with the sheath, and there was no inferior product leaving the shielding tape. [The shielding property] The shielding property of the produced shield flat cable against electromagnetic noises was measured by an adsorption clamp method as shown in Fig.7. In the measuring apparatus as shown in Fig.7, both ends of the shield flat cable were connected to BNG connectors. Electric current was sent to the core wire of the shield flat cable, and electromagnetic noise radiated from the core wire was detected by the adsorption clamp and analyzed by a spectrum analyzer, and when gain to the electromagnetic noise at the core wire only was measured, it was -45dB practically available as the shielding wire for automobiles. For reference, with respect to the shield flat cable similarly produced by using the shielding tape having the coating width of 1mm and the non-coating width of 2mm, the shielding property was measured and a result was -35dB. As the shielding wire for automobiles, since the shielding property must be -40dB or more, this cannot be used for automobiles. According to the invention, the terminal can be processed by exfoliating the shielding tape as securing the close adherence to the core wire not generating slipping out and misregistation of the core wire without leaving the shielding tape at the outer periphery of the core wire. Therefore, in the case of the flat cable typed shielding wire using the shielding tape of the invention, inferior products by automatically processing the terminal using the pressure connection system can be less produced than the prior art. Further, by using the shielding tape where the width of the coating part and the width of the non coating part of the adhesive agent are equal in the core adhesive agent layer, the shielding tape has the excellent shielding property against the magnetic noises and can be applied to the wire for automobiles. Second Embodiment The shielding wire is, as shown in Fig.1, that core wires 3, 3 formed integrally by wrapping the conductors 1 with insulating materials 2 and a drain wire 4 are arranged in parallel with fixed distances, and a shielding tape 5 covers closely allover outer peripheries of the core wires 3, 3 and the drain wire 4, and further the shielding tapes 5 are shielded on the surfaces with a sheath 6. Distances between the core wires 3, 3 and between the core wire 3 and the drain wire 4 are maintained by sticking the mutual sheath adhesive layers 13 of the shielding tape 5 to form bridges 7, 7'. In the current structure, the insulating material 2 of the sheath 6 and the core wire 3 is composed of non-halogen material, that is, polymer not containing halogen. Concretely enumerated are homopolymer of olefin having comparatively simple structure as ethylene, propylene, buten, isoprene, penten, methylpentene, etc., or other than copolymer of these combination, copolymer of vinyl acetate group of ethylene-vinyl acetate copolymer, etc., copolymer of (meta) acrylate group of ethylene-ethyl (meta) acrylate copolymer, etc., ternary copolymer of ethylene-propylene- diene group, and so on. Among them, in view of cost, preferabley used is polymer of polyolefin group such as polyethylene, polypropylene, or ethylene-propylene copolymer, and more preferable is polypropylene having higher melting point among them. Polymer of non halogen group may be used as materials of the sheath 6 and the insulating material 2 as they are, and if necessary, bridging formation may be provided, or heat resistance of flame resistance may be imparted by mixing flame retarders of halogen. As flame retarders of non-halogen, enumerated is metal hydroxide such as magnesium hydroxide, aluminum hydroxide, or calcium hydroxide As the shielding tape 5, that of the structure as shown in Fig.2 is generally used. Namely, the shielding tape comprises a shielding layer 11, a reinforcing seat layer 12 laminated on the side of a sheath 6 of the shielding layer 11, a sheath adhesive agent layer 13 for adhering the reinforcing seat layer 12 and the sheath 6, and a core adhesive agent layer 14 for adhering the shielding layer 11 and the core wire 3. The core adhesive agent layer 14 is formed by partially coating the core adhesive agent as in oblique strains, and it is sufficient that areas for coating the core adhesive agent are selected within ranges enabling to secure the adherence of the core wire and the shield tape so as not to cause misregistration or slipping out of the core wire. Actually, an area ratio of the core adhesive agent and the metal foil composing the shielding layer (the adhesive agent : the metal foil) is around 1 : 2 to 2 : 1 In the shielding tape 5 having such a structure, the adhesive agent is selected such that the adhesive force of the sheath adhesive agent layer 13 to the sheath is larger than the adhesive force of the core adhesive agent layer to the insulating material 14. Further, it is preferable that the adhesive force of the sheath adhesive agent layer 13 to the reinforcing eat layer 12 is larger than the adhesive force of the core wire of the core adhesive agent layer 14 to the insulation shielding material. A non-halogen material satisfying the requirement does not especially limit kinds of the core adhesive agent and the sheath adhesive agent, and may appropriately select kinds in response to kinds of the reinforcing seat, sheath material, or insulation shielding material. As the sheath adhesive agent, adhesive agents of polyolefin group such as the adhesive agents of polypropylen, and as the core adhesive agent, PET group is preferably used. Herein, the adhesive force referred to in the invention means adhesive force available when an exfoliation test is performed that 2 sheets of insulation shielding tests pieces are adhered with an adhesive agent to be measured, and these 2 sheets are pulled in opposite directions respectively by a tensile testing machine and exfoliated. For selecting actual adhesive agents, a standard can be set up at solubility parameter (SP). It is sufficient to select the adhesive agent such that difference (|SPc - SPz|) between SP value (SPc) of the core adhesive agent and SP value (SPz) of an insulation shielding material is larger than difference (|SPs - SPt|) between SP value (SPs) of the sheath adhesive agent for sheath and SP value (SPt) of the sheath. For example, when the insulation shielding material of the core wire and the sheath material are made of polyethylene or isotacticpolypropylene (PS value is 8.1 to 8.3), it is sufficient to select the adhesive agent such that the SP value of the sheath adhesive agent is nearer to 8.1 to 8.3 than the SP value of the core adhesive agent. Actually, as the sheath adhesive agent, there may be used adhesive agent of polyacrylonitrile group (SP value 8.1), adhesive agent of polybutadiene group (SP value 8.4), adhesive agent of polyethylene group (SP value 8.1),or adhesive agent of polymethylene group (SP value 8.1). As the core adhesive agent, there may be used, other than adhesive agent of reethyleneterephthalate group (SP value 10.6), adhesive agent of polyvinyl acetate group (SP value 9.4), adhesive agent of polymethylmethacrylate group (SP value 9.4), adhesive agent of polyethylacrylate group (SP value 9.7), adhesive agent of polyethylmethacrylate group (SP value 9.2), adhesive agent of methacrylonitrile group (SP value 10.6), adhesive agent of polypropylacrylate group (SP value 9.0), adhesive agent of polybutylmethacrylate (SP value 9.0), or adhesive agent of polystyrene group (SP value 9.0). It is preferable to select, among them, an adhesive agent having heat resistance in response to temperature of a using environment. When a seat of PET is used as the reinforcing seat layer 12, preferably, the sheath adhesive agent is selected such that the difference between the SP value of the seat adhesive agent and the SP value of PET is smaller than the difference (|SPc-SPz|) between the SP value (SPc) of the core adhesive agent and the SP value (SPz) of the insulation shielding material. As mentioned, the inventive shielding wire is composed of non-halogen material in all of the sheath, insulating material of the core wire, sheath adhesive agent composing the shielding tape, core adhesive agent, and reinforcing seat, and therefore, even in case of such environments of 80 to 120°C during driving as in automobile engine rooms, poisonous gas of hydrohalogen gas is not generated. In the shielding wire where the core and sheath adhesive agents satisfy the above mentioned relation, the shielding tape 5 is exfoliated together with the sheath 6 from the core wire. On the other hand, in the bridge parts 7, the mutual core adhesive agent layers 14 are unitary, so that the pitch between the core wires 3, and the pitch between the core wire 3 and the drain wire 4 are maintained fixed. Thus, in the flat cable typed shielding wire, when processing the terminal thereof, the shielding tape 5 at the cut terminal and the sheath 6 can be exfoliated without causing slipping out or misregistration of the core wire 3 and leaving the shielding tape 5 on the surface of the insulating material 2 of the core wire 3. It is therefore possible to reduce extremely occurrence of bad products in automatic processing by the pressure connecting system. In the shielding tape to be used to the shielding wire of the invention, material for the reinforcing seat is ordinarily polyester in view of cost and strength, but not limited to it, and seat of non-halogen group may be used, provided that adherence with the sheath adhesive agent is not spoiled. The metal foil to be used to the shielding layer is generally composed of a combination of a metal foil 11a of high electric conductivity as copper or aluminum and a metal foil 11b of high permeability as iron or tin, but not limited thereto. In the flat cable typed shielding wire of the invention, the position relative between the drain wire and the core wire is not especially limited, and as shown in Fig.6, the drain wire may be positioned between the core wires 3, 3. Explanation for an embodiment of Fig.6 is omitted by giving the same numerals as in Fig.1. Furthermore, in case of providing a mechanism earthing the shielding tape, such a flat cable typed shielding wire not arranging the drain wire in parallel with the core wire is sufficient. The number of core wires in the shielding wire is not limited to two pieces, and the inventive shielding tape can be applied to a flat cable typed shielding wire having a plurality of core wires of three or more pieces. Since the shielding wire of the invention is composed of non-halogen material in the composing elements of sheath, insulating material and shielding tape, it does not issue poisonous gas causing environmental pollution in using conditions or burning after use. The inventive shielding wire is tender to the environment. In the shielding wire of the invention, the core adhesive agent and the sheath adhesive agent are selected such that the exfoliation work can be performed as securing the adherence in the relation between the sheath, shielding tape and core wire so as not to cause slipping out or misregistration of the core wire. It is therefore possible to reduce occurrence of bad products in automatic processing by the pressure connecting system than conventionally.

Claims: A shielding tape (5) comprising: a shielding layer (11); a core adhesive agent layer (14) laminated on one side of said shielding layer, which adheres an insulation shielding material of a core wire; a reinforcing seat layer (12) laminated on another side of said shielding layer; and a sheath adhesive agent layer (13) for adhering a sheath on said reinforcing seat layer; wherein adhesive force of said core adhesive agent layer (14) to the insulation shielding material is smallest among the respective layers. The shielding tape as set forth in claim 1, wherein the core adhesive agent layer comprises coating parts and non-coating parts of core adhesive agent, and adhesive strength of the core adhesive agent to be applied to the coating part to the insulation shielding material is smaller than strength of a sheath adhesive agent to be applied to the sheath adhesive agent layer to the sheath. The shielding tape as set forth in claim 1, wherein the adhesive strength of the sheath adhesive agent to the reinforcing seating layer is larger than the adhesive strength of the core adhesive agent to the insulation shielding material. The shielding tape as set forth in claim 2, wherein the core adhesive agent is polyethylene terephthalate group and the sheath adhesive agent is vinyl chloride-vinyl acetate copolymer group. The shielding tape as set forth in claim 2, wherein the coating part and the non coating part are disposed alternately in a lengthwise direction of the tape, and the width of the coating part and that of the non coating part are equal. The shielding tape as set forth in claim 5, wherein the width of the coating part is 1 to 2mm. The shielding tape as set forth in claim 1, wherein the shielding tape is interposed between a plurality of core wires in shielding wires of flat cable type in parallel disposed in fixed distances with the core wires and the sheath wrapping the core wires in a bundle. A shielding wire of flat cable type, in which a plurality of core wires (3) are in parallel disposed in fixed distances, said shielding wire comprising: a shielding layer (11); a core adhesive agent layer (14) laminated on one side of said shielding layer, which adheres an insulation shielding material of said core wire; a reinforcing seat layer (12) laminated on another side of said shielding layer; and a sheath adhesive agent layer (13) for adhering a sheath on said reinforcing seat layer; wherein adhesive force of said core adhesive agent layer (14) to the insulation shielding material is smallest among the respective layers. The shielding wire as set forth in claim 8, wherein difference (|SPc - SPz|) between SP value (SPc) of the core adhesive agent and SP value (SPz) of an insulation shielding material is larger than difference (|SPs - SPt|) between SP value (SPs) of the sheath adhesive agent and SP value (SPt) of the sheath. The shielding wire as set forth in claim 9, the insulation shielding material and the sheath are polyvinyl chloride. A shielding wire as claimed in claim 8, wherein the shielding materials and the sheath are composed of a non-halogen material, the adhesive agent for core and the adhesive agent for sheath are composed of the non-halogen material. The shielding wire as set forth in claim 11, wherein the insulating material and the sheath are composed of a material of polyolefin group, and the adhesive agent for sheath is composed of a material of polyolefin group. The shielding wire as set forth in claim 12, wherein an adhesive agent of polyethyleneterephthalate group is used as the adhesive agent for core. The shielding wire as set forth in claim 11, wherein the shielding wire is served in atmosphere at temperature of 120°C or less.

Inventors: TANAKA ATSUO, TANAKA, ATSUO, Tanaka, Atsuo, c/o Harness System Tech. R., Ltd.
Applicants: AUTONETWORKS TECHNOLOGIES LTD, SUMITOMO ELECTRIC INDUSTRIES, SUMITOMO WIRING SYSTEMS, AUTONETWORKS TECHNOLOGIES, LTD., SUMITOMO ELECTRIC INDUSTRIES, LTD., SUMITOMO WIRING SYSTEMS, LTD.
Application year: 1999
Main classification: H01B7
IPC codes: H01B7