Cryogenic air separation process and apparatus

Abstract: A single column air separation unit having a top condenser cooled with expanded bottoms liquid is supplied with cryogenic liquid from an external source. The rate of supply of cryogenic liquid is determined in dependence on the liquid level at the bottom of the column.

Description: The present invention relates to a process and apparatus for cryogenically separating air, and in particular to such a process and apparatus for the production of nitrogen. It is well known to supply part of the refrigeration requirements of an air separation process by liquid assist. This involves the injection of a cryogenic liquid into the distillation column or a condenser of the column at a point where the liquid in the column has a similar composition to that of the liquid used for the liquid assist. Examples of liquid assist processes are to be found in US 2 908 144 and US 3 620 032 and in " Recent Developments in Industrial Oxygen Production by M.P. Dubs, Trans. Instr. Chem. Engs. Vol. 36, 1958. The standard technique used to regulate the amount of liquid assist sent to a single column is to vary the amount of liquid injected into the column in dependence on the level of liquid in the top condenser of the column (see for example EP-A-0 144 430, EP-A-191 862, J53-14351, J61-24968, US-A-2 685 181). The same regulation technique is disclosed in a general context FR 2 076 020. US-A-2 685 181 discloses the features of the preambles of the independent claims to follow. It is an object of the present invention to provide an air separation process which can be more accurately controlled. According to the invention, there is provided a cryogenic air separation process in a distillation column having a top condenser comprising compressing and purifying the air; cooling the air after compression and purification thereof to a temperature suitable for distillation; separating the air in a distillation column so that an oxygen enriched liquid and a nitrogen enriched gas are produced within the column; sending a stream of cryogenic liquid to the column; sending oxygen-enriched liquid from the column to the condenser regulating a flow rate of the cryogenic liquid; and withdrawing a product stream from the column, characterised in that the flow rate is regulated in dependence on the level of oxygen enriched liquid at the bottom of the column. Preferably, the column is a single column nitrogen generator with a top condenser. There is further provided according to the invention a cryogenic air separation apparatus comprising a distillation column having a top condenser, means for providing cooled compressed air to the distillation column, means for removing nitrogen-enriched fluid from the column, means for sensing a liquid level at the bottom of the column, means for sending a cryogenic liquid to the column, means for sending oxygen-enriched liquid from the bottom of the column to the condenser, means for controlling the flow rate of the cryogenic liquid sent to the column characterised in that de means for controlling the flow rate are adapted to control the flow rate in dependence on said liquid level. The column may contain trays or packings of the structured or random type. As the column is generally of smaller diameter than the condenser, a requirement for increased refrigeration will be reflected by a drop in liquid level of greater magnitude that the drop in liquid level in the condenser. This enables the refrigeration requirement to be met with greater accuracy. An embodiment of the invention will now be described with reference to Figure 1. An air stream 1 is sent to the bottom portion of a single column nitrogen generator 11 . Crude liquid oxygen 3 from the bottom of the column is sent to top condenser 9 which serves to condense the nitrogen formed at the top of the column. This condensation may be total or partial. Product nitrogen gas or liquid 7 is removed from the top of the column and evaporated crude liquid oxygen 5 is removed from above the condenser. Some or all of the refrigeration for the process is supplied by injecting liquid nitrogen from storage tank 13 into the top of the column via conduit 15 and valve 16. The opening of valve 16 is controlled in dependence on the liquid leval at the bottom of the column 11 detected by LIC sensor 17. Part of the refrigeration may optionally be provided by expansion of feed air or evaporated crude liquid oxygen. As the liquid level rises, valve 16 reduces the amount of liquid nitrogen sent via conduit 15 and as the liquid level falls, valve 16 increases the amount of liquid nitrogen sent via conduit 15. Optionally the flow of liquid nitrogen in conduit 15 may also be varied in dependence on the liquid level detected by sensor 21. Thus two liquid levels at different positions are used to control the cryogenic liquid injection.

Claims: A cryogenic air separation process in a distillation column (11) having a top condenser (9) comprising compressing and purifying the air; cooling the air after compression and purification thereof to a temperature suitable for distillation; separating the air in the distillation column so that an oxygen enriched liquid and a nitrogen enriched gas are produced within the column; sending a stream of cryogenic liquid from an external source to the column; sending oxygen-enriched liquid to the top condenser regulating a flow rate of the cryogenic liquid; and withdrawing a product stream from the column. characterised is that the flow rate is regulated in dependence on the level of oxygen enriched liquid at the bottom of the column. The process of claim 1 comprising additionally regulating the flow rate of cryogenic liquid in dependence on the level of liquid in the top condenser. The process of claim 1 or 2 wherein the cryogenic liquid is nitrogen. A cryogenic air separation apparatus comprising a distillation column (11) having a top condenser (9), means for providing cooled compressed air to the distillation column, means (7) for removing nitrogen-enriched product from the column, means (17) for sensing a liquid level at the bottom of the column, means (15, 16) for sending a cryogenic liquid from an external source to the column, means for sending oxygen-enriched liquid from the bottom of the column to the condenser, means (16) for controlling the flow rate of the cryogenic liquid sent to the column characterized in that the means for controlling the flow rate are adapted to control the flow rate in dependence or said liquid level. The apparatus of claim 4 comprising means (21) for sensing a further liquid level in the condenser (9) and controlling said flow rate in dependence on said further liquid level.

Inventors: GRETER LUCIEN, VENET FRANCOIS, GRETER, LUCIEN, VENET, FRANCOIS, Venet, François
Applicants: AIR LIQUIDE, L'AIR LIQUIDE, S.A. A DIRECTOIRE ET CONSEIL DE SURVEILLANCE POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
Application year: 1999
Main classification: F25J3
IPC codes: F25J3