FILMS HAVING DEAD-FOLD PROPERTIES MADE FROM ALPHA-OLEFIN/VINYL AROMATIC AND/OR ALIPHATIC OR CYCLOALIPHATIC VINYL OR VINYLIDENE INTERPOLYMERS

Abstract: The present invention pertains to a film or sheet or extruded profile having at least one layer comprising; (A) at least one substantially random interpolymer, which comprises; (I) polymer units derived from; (i) at least one vinyl aromatic monomer, or (ii) at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, or (iii) a combination of at least one aromatic vinyl monomer and at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, and (2) polymer units derived from at least one C2-20 alpha -olefin; and optionally (3) polymer units derived from one or more ethylenically unsaturated polymerizable monomers other than those of (1) and (2); or (B) a blend of Component A with at least one polymer other than that of Component A; and wherein said film or sheet or extruded profile has a force relaxation in the cross direction or machine direction or both of greater than or equal to 40 percent. The present invention also pertains to a multilayer film or sheet or extruded profile comprising at least two layers wherein at least one of said layers is a film or sheet or extruded profile having a force relaxation in the cross direction or machine direction or both of greater than or equal to 40 percent, comprising; (A) at least one substantially random interpolymer, which comprises; (1) polymer units derived from; (i) at least one vinyl aromatic monomer, or (ii) at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, or (iii) a combination of at least one aromatic vinyl monomer and at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, and (2) polymer units derived from at least one C2-20 alpha -olefin; and (3) polymer units derived from one or more ethylenically unsaturated polymerizable monomers other than those of (1) and (2); or (B) a blend of Component A with at least one polymer other than that of Component A.

Description: FILMS HAVING DEAD-FOLD PROPERTIES MADE FROM ALPHA- OLEFIN/VINYL AROMATIC AND/OR ALIPHATIC OR CYCLOALIPHATIC VINYL OR VINYLIDENE INTERPOLYMERS This invention pertains to films or sheets or extruded profiles prepared from polymers which comprise at least one substantially random interpolymer comprising polymer units derived from one or more α-olefin monomers with specific amounts of one or more vinyl aromatic monomers or aliphatic or cycloaliphatic vinyl or vinylidene monomers, or a combination thereof, or blend compositions therefrom with other polymers. Films or sheets or extruded profiles prepared from such interpolymers exhibit dead-fold properties as measured by their having a high force relaxation (> 40 percent) in either the machine or cross direction or both. The invention covers films, sheets, and multi-layer laminates. The films according to the invention may be obtained also as co-extruded and multi-layer films, such as one side sealable films, two sides sealable films, coated films, tinted films, cavitated films, untreated films, one side treated films, two sides treated films, and metallized plastic films. The inventive films can also be laminated to conventional oriented polypropylene, polyethylene or polyester films, aluminum foil, paper, foam and others to impart dead fold properties to such multilayer composite structures. Due to the presence of the above stated characteristics or properties, the films and sheets of the present invention may be successfully employed for packaging in general and for packaging small items in particular. Potential applications include, but are not limited to, tooth paste tubes, twist ties, candy twist wrapping, meat overwrap, paper replacement, table cloths and shower curtains . Materials which have the ability to hold their new conformation on shaping are said to exhibit dead-fold properties. Dead fold properties are especially important in a number of packaging application areas including consumer food wraps for enclosing and preparing foods, candy twist wraps, and in closeable flexible walled containers such as for example tooth paste tubes. Presently three distinct classes of films or foil exist for such applications, namely aluminum foil, paper, and plastic films or sheets or extruded profiles. Aluminum foil possesses excellent dead fold and shaping characteristics. That is, once the foil is wrapped around an item it maintains its shape and does not unfold. However aluminum foil is somewhat expensive, is not transparent, and is not suitable for use in microwave ovens. Paper (including glassine paper and waxed paper) although easy to cut, is limited in many packaging applications due to a combination of strength, optical properties, operating temperature range and lack of water resistance properties. A major problem for many plastic films used in wrapping applications has been the tendency of such films to fail to maintain their shape once they are wrapped around a container. That is they have a tendency to spring back or recover to an unfolded state. With the advent of high speed wrapping machines, it is necessary to have recourse to materials with particular characteristics, and to this end, certain films of rigid, amorphous polymers such as polyvinylchloride (PVC), polystyrene and acrylic copolymers have been employed. Plastic films such as those made from polystyrene, flexible PVC and acrylic polymers are typically used for wrapping foods because of their transparency and relatively low cost. Additionally some plastic wraps based on PVC can be used in microwave applications. However flexible PVC, requires formulation with significant levels of plasticizer and contain chlorine which is not environmentally sound. In addition films made from polystyrene, flexible PVC and acrylic polymers typically are brittle and do not demonstrate the toughness required for many packaging applications. Polypropylene and polyethylene films, which would have cost advantages with respect to the above mentioned materials, cannot, on the other hand, be employed in an unmodified form because of their lack of twist retention, and moderate permeability. In many cases, attempts to solve these problems have involved the preparation of multilayer films comprising a mixture of polymers. In addition many such films have often required additional orientation procedures in the film fabrication processes in order to obtain the desired combination of dead fold and other properties. US Patent No. 5,128,183 (P. Buzio, assigned to Borden, Inc), the entire contents, is directed to modified polyolefin films with stable twist retention and dead fold properties to be employed in wrapping in general, and particularly in wrapping small items. The inventive films are obtained by extrusion and stretching of a ternary mixture comprising (1) isotactic polypropylene; (2) high density polyethylene; and (3) a glassy amorphous low molecular weight resin. Japanese Patent 59-68212 (Mitsui Toatsu Chemical Co.) is directed to a polyolefin film with improved rigidity and twist retention obtained by mono-axial longitudinal orientation. Such a film, however, has poor properties in the transverse direction and has a tendency to tearing and Assuring, and its use is therefore limited to longitudinal twist wrapping. In German Patent DE 3514398A1 (Hoechst) a biaxially oriented film is described consisting of polypropylene, inorganic fillers and polymers such as polyamides or polymethylmethacrylate. This type of film, however, shows poor twist retention. In European Application 0288227, published Oct. 26, 1988 (Exxon Chemicals), a biaxially-oriented film is described which is obtained by extrusion of a two component blend consisting of a polypropylene compound, (or a copolymer of propylene with up to 20 weight percent of another olefin, for example ethylene) and 20 to 30 percent by weight of a low molecular weight rosin or resin. The process described therein for obtaining extruded oriented films presents serious difficulties in the extrusion and orientation stages. U.S. Pat. No. 4,842,187 issued Jun. 27, 1989 to Janocha, et al, describes an opaque, biaxially draw-oriented thermoplastic film for candy twist wrapping. The film is formed from a polymer mixture comprising from 40 to 60 percent by weight of polypropylene and from 35 to 55 percent by weight of polystyrene, and from 5 to 15 percent by weight of an inorganic or organic filler. U.S. Pat. No. 4,786,533, issued Nov. 22, 1988 to Crass, et al., teaches the preparation of a twist wrap film produced from a polypropylene base layer and a polydialkylsiloxane top layer. The polypropylene base layer additionally contains a low molecular weight hydrocarbon resin in an amount of 10 to 40 percent by weight. The polypropylene therein is preferably an isotactic propylene homopolymer or a copolymer of ethylene and propylene having an ethylene content of less than 10 percent by weight. This is a two component base layer. EP 0 148 567 Al (published July 7, 1985) to P.J. Canterino describes films comprising a uniform blend of a major proportion of a polyethylene and a minor proportion of a polystyrene as a deadfold food wrap material that has paper tear characteristics. U.S. Pat. No. 4,965,135 by Im et al., issued October 23, 1990 (Dow Chemical) describes a multilayer film with dead fold and twistability characteristics which characteristics are achieved by alternating layers of a first generally ductile material such as LLDPE and a second generally brittle material such as polystyrene or PVC. U.S. Pat. No. 5,560,948 by Peiffer et al., issued October 1, 1996 (Hoechst AG) describes a biaxially oriented multilayer polypropylene film having twist wrap characteristics which characteristics are achieved by the film having at least one base layer containing propylene polymer and at least one outer layer containing alpha olefin polymers from 2 to 10 carbon atoms. U.S. Pat. No. 4,916,025 by L. Pang-Chia issued April 10, 1990 (Mobil Oil Corp), describes high density polyethylene films having good dead fold and water vapor transmission characteristics which characteristics are achieved by the film containing blends of HDPE or microcrystalline wax being oriented up to two times in the machine direction and six times or more in the transverse direction. U.S. Pat. No. 4,659,408 by D. D. Redding issued April 21, 1987 (American Can Company) describes a multilayer sheet structure having improved deadfold and strength properties which properties are achieved by the sheet having an oriented substructure comprising a combination of polymer layers, including a uniaxially oriented polypropylene or high density polyethylene layer. U.K. Pat. Application. GB 2 168 362 A by E. V. Brennan published June 18, 1986 (BCL Ltd.) describes a packaging film having high clarity and dead fold properties formed by extruding a mixture comprising an SBS block copolymer, a styrene butadiene copolymer, and polystyrene though a flat or circular die. U.S. Pat. No. 5,658,625 by J. G. Bradfute et al., issued August 19, 1997 (W. R. Grace and Co.) describes films comprising one or more layers a thermoplastic, homogeneous alpha-olefin/vinyl aroamatic copolymer having improved impact resistance, printability, RF sealability, shrink and optical properties. However Bradfute is open ended as to the amount of substantially random interpolymer in the blend as well as the optimum amounts of ethylene/vinyl and α-olefin monomers in the ethylene/vinylidene aromatic interpolymer blend component and silent to any dead fold properties in the film compositions. The present invention relates to films prepared from polymers which comprise at least one substantially random interpolymer comprising polymer units derived from one or more α-olefin monomers with specific amounts of one or more vinyl aromatic monomers or aliphatic or cycloaliphatic vinyl or vinylidene monomers, or a combination thereof, or blend compositions therefrom with other engineering thermoplastics. Films prepared from such interpolymers exhibit dead- fold properties as measured by a high force relaxation of > 40 percent in the machine direction or cross direction or both. In applications such as tapes, labels or laminating films, such a high force relaxation allows conformability to uneven or irregular surfaces, and over edges, curves, folds, . In addition, extruded profiles such as toy tracks, tubes, gaskets may be twisted, bent or otherwise formed into shapes which will be retained after removal of the shaping force. While the desired properties of the films or sheets or extruded profiles of the present invention can be achieved using single layer films, the invention also covers sheets, and multi-layer laminates. Accordingly, the films according to the invention may be obtained also as co-extruded and multi-layer films, such as one side sealable films, two sides sealable films, coated films, tinted films, cavitated films, untreated films, one side treated films, two sides treated films, and metallized plastic films. The inventive films can also be laminated to conventional polyester films, styrenic polymer films, polyethylene films, oriented polypropylene films, and others to impart dead fold properties to such multilayer composite films. Due to the presence of the above stated characteristics or properties, the films or sheets or extruded profiles of the present invention may be successfully employed for packaging in general and for packaging small items in particular. Other potential applications include, but are not limited to, meat over-wrap, paper replacement, stand-up or flat bottomed bags, table cloths and shower curtains, collapsible bottles or containers, tubes such as toothpaste tubes, fold-down structures, boxes, cartons, window boxes, surgical drapes, formable membranes, toys, tubing and clothing, tapes, laminating films, pressure sensitive labels . The present invention pertains to a film, or sheet or extruded profile having at least one layer comprising; (A) at least one substantially random interpolymer, which comprises; (1) polymer units derived from; (i) at least one vinyl aromatic monomer, or (ii) at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, or (iii) a combination of at least one aromatic vinyl monomer and at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, and (2) polymer units derived from at least one C 2 . 20 α-olefin; and optionally (3) polymer units derived from one or more ethylenically unsaturated polymerizable monomers other than those of (1) and (2); or (B) a blend of Component A with at least one polymer other than that of Component A; and wherein said film or sheet or extruded profile has a force relaxation in the cross direction or machine direction or both of greater than or equal to 40 percent. The present invention also pertains to a multilayer film or sheet or extruded profile comprising at least two layers wherein at least one of said layers is a film or sheet or extruded profile having a force relaxation in the cross direction or machine direction or both of greater than or equal to 40 percent, comprising; (A) at least one substantially random interpolymer, which comprises; (1) polymer units derived from; (i) at least one vinyl aromatic monomer, or (ii) at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, or (iii) a combination of at least one aromatic vinyl monomer and at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, and (2) polymer units derived from at least one C 2 . 20 α-olefin; and (3) polymer units derived from one or more ethylenically unsaturated polymerizable monomers other than those of (1) and (2); or (B) a blend of Component A with at least one polymer other than that of Component A. Definitions All references herein to elements or metals belonging to a certain Group refer to the Periodic Table of the Elements published and copyrighted by CRC Press, Inc., 1989. Also any reference to the Group or Groups shall be to the Group or Groups as reflected in this Periodic Table of the Elements using the IUPAC system for numbering groups. Any numerical values recited herein include all values from the lower value to the upper value in increments of one unit provided that there is a separation of at least 2 units between any lower value and any higher value. As an example, if it is stated that the amount of a component or a value of a process variable such as, for example, temperature, pressure, time is, for example, from 1 to 90, preferably from 20 to 80, more preferably from 30 to 70, it is intended that values such as 15 to 85, 22 to 68, 43 to 51, 30 to 32 etc. are expressly enumerated in this specification. For values which are less than one, one unit is considered to be 0.0001, 0.001 , 0.01 or 0.1 as appropriate. These are only examples of what is specifically intended and all possible combinations of numerical values between the lowest value and the highest value enumerated are to be considered to be expressly stated in this application in a similar manner. The term "hydrocarbyl" as employed herein means any aliphatic, cycloaliphatic, aromatic, aryl substituted aliphatic, aryl substituted cycloaliphatic, aliphatic substituted aromatic, or aliphatic substituted cycloaliphatic groups. The term "hydrocarbyloxy" means a hydrocarbyl group having an oxygen linkage between it and the carbon atom to which it is attached. The term "interpolymer" is used herein to indicate a polymer wherein at least two different monomers are polymerized to make the interpolymer. This includes copolymers, terpolymers, etc. The term " film " as used herein is defined as having a thickness less than or equal to 12 mils. The term " sheet " as used herein is defined as having a thickness greater than 12 mils. The term "extruded profile " as used herein is defined as a polymer composition, which has undergone a profile extrusion process for use in a shape specific application. The term " deformation " as used herein is defined as bending, elongation, or compression. The term " dead fold property" as used herein is defined as a measure of the film's ability to retain its shape or fold or crease permanently once it is folded or wrapped about an item and not spring back to an unfolded state. Thus a measure of the degree of such dead fold behavior is the magnitude of the films force relaxation in the machine or cross direction or both. To exhibit dead-fold behavior a film should have a high force relaxation of > 40 percent in the machine or cross direction or both. The term "dead fold film" as used herein is defined as a film having dead fold properties. The term "structure" as used herein is defined as a polymer composition which has undergone a molding process, a film forming process, a sheet forming process, or a foamed film forming process or a foamed sheet forming process or a lamination process to a plastic film, or aluminum foil, or paper, or foam. The term "fabricated article" as used herein is defined as a polymer composition in the form of a finished article which may be formed from an intermediate comprising one of the films described herein. The term "substantially random" (in the substantially random interpolymer comprising polymer units derived from one or more α-olefin monomers with one or more vinyl aromatic monomers or aliphatic or cycloaliphatic vinyl or vinylidene monomers, or a combination thereof) as used herein means that the distribution of the monomers of said interpolymer can be described by the Bernoulli statistical model or by a first or second order Markovian statistical model, as described by J. C. Randall in POLYMER SEQUENCE DETERMINATION, Carbon- 13 NMR Method. Academic Press New York, 1977, pp. 71-78. Preferably, substantially random interpolymers do not contain more than 15 percent of the total amount of vinyl aromatic monomer in blocks of vinyl aromatic monomer of more than 3 units. More preferably, the interpolymer is not characterized by a high degree of either isotacticity or syndiotacticity. This means that in the carbon "13 NMR spectrum of the substantially random interpolymer the peak areas corresponding to the main chain methylene and methine carbons representing either meso diad sequences or racemic diad sequences should not exceed 75 percent of the total peak area of the main chain methylene and methine carbons. The Substantially Random Interpolymers The interpolymers used to prepare the films or sheets or extruded profiles of the present invention include the substantially random interpolymers prepared by polymerizing one or more α-olefins with one or more vinyl aromatic monomers or one or more aliphatic or cycloaliphatic vinyl or vinylidene monomers or a combination thereof, and optionally other polymerizable monomers. Suitable α-olefins include for example, α-olefins containing from 2 to 20, preferably from 2 to 12, more preferably from 2 to 8 carbon atoms. Particularly suitable are ethylene, propylene, butene-1, 4-methyl-l -pentene, hexene-1 or octene-1 or ethylene in combination with one or more of propylene, butene- 1 , 4-methyl- 1 - pentene, hexene-1 or octene-1. These α-olefins do not contain an aromatic moiety. Other optional polymerizable ethylenically unsaturated monomer(s) include norbornene and C,. 10 alkyl or C 6 . 10 aryl substituted norbornenes, with an exemplary interpolymer being ethylene/styrene/norbornene. Suitable vinyl aromatic monomers which can be employed to prepare the interpolymers include, for example, those represented by the following formula: Ar I (CH 2 ) n R i _ C = C(R ) 2 wherein R 1 is selected from the group of radicals consisting of hydrogen and alkyl radicals containing from 1 to 4 carbon atoms, preferably hydrogen or methyl; each R 2 is independently selected from the group of radicals consisting of hydrogen and alkyl radicals containing from 1 to 4 carbon atoms, preferably hydrogen or methyl; Ar is a phenyl group or a phenyl group substituted with from 1 to 5 substituents selected from the group consisting of halo, C,. 4 -alkyl, and C 1 . 4 -haloalkyl; and n has a value from zero to 4, preferably from zero to 2, most preferably zero. Exemplary vinyl aromatic monomers include styrene, vinyl toluene, α-methylstyrene, t-butyl styrene, chlorostyrene, including all isomers of these compounds, . Particularly suitable such monomers include styrene and lower alkyl- or halogen-substituted derivatives thereof. Preferred monomers include styrene, α-methyl styrene, the lower alkyl- (C, - C 4 ) or phenyl-ring substituted derivatives of styrene, such as for example, ortho-, meta-, and para-methylstyrene, the ring halogenated styrenes, para-vinyl toluene or mixtures thereof, . A more preferred aromatic vinyl monomer is styrene. By the term "aliphatic or cycloaliphatic vinyl or vinylidene compounds", it is meant addition polymerizable vinyl or vinylidene monomers corresponding to the formula: A 1 I R i — C = C(R 2 ) 2 wherein A 1 is a sterically bulky, aliphatic or cycloaliphatic substituent of up to 20 carbons, R 1 is selected from the group of radicals consisting of hydrogen and alkyl radicals containing from 1 to 4 carbon atoms, preferably hydrogen or methyl; each R 2 is independently selected from the group of radicals consisting of hydrogen and alkyl radicals containing from 1 to 4 carbon atoms, preferably hydrogen or methyl; or alternatively R 1 and A 1 together form a ring system. Preferred aliphatic or cycloaliphatic vinyl or vinylidene compounds are monomers in which one of the carbon atoms bearing ethylenic unsaturation is tertiary or quaternary substituted. Examples of such substituents include cyclic aliphatic groups such as cyclohexyl, cyclohexenyl, cyclooctenyl, or ring alkyl or aryl substituted derivatives thereof, tert- butyl, norbornyl, . Most preferred aliphatic or cycloaliphatic vinyl or vinylidene compounds are the various isomeric vinyl- ring substituted derivatives of cyclohexene and substituted cyclohexenes, and 5-ethylidene-2-norbornene. Especially suitable are 1-, 3-, and 4-vinylcyclohexene. The substantially random interpolymers may be modified by typical grafting, hydrogenation, functionalizing, or other reactions well known to those skilled in the art. The polymers may be readily sulfonated or chlorinated to provide functionalized derivatives according to established techniques. Although not a requirement for dead-fold behavior, the substantially random interpolymers , or the sheets and films comprising at least one layer of said substantially random interpolymer, may also be modified by various chain extending or cross-linking processes including, but not limited to peroxide-, silane-, sulfur-, radiation-, or azide-based cure systems. A full description of the various cross-linking technologies is described in copending U.S. Patent Application No's 08/921,641 and 08/921,642 both filed on August 27, 1997. Dual cure systems, which use a combination of heat, moisture cure, and radiation steps, may be effectively employed. Dual cure systems are disclosed and claimed in U. S. Patent Application Serial No. 536,022, filed on September 29, 1995, in the names of K. L. Walton and S. V. Karande. For instance, it may be desirable to employ peroxide crosslinking agents in conjunction with silane crosslinking agents, peroxide crosslinking agents in conjunction with radiation, sulfur-containing crosslinking agents in conjunction with silane crosslinking agents, etc. The substantially random interpolymers may also be modified by various cross-linking processes including, but not limited to the incorporation of a diene component as a termonomer in its preparation and subsequent cross linking by the aforementioned methods and further methods including vulcanization via the vinyl group using sulfur for example as the cross linking agent. One method of preparation of the substantially random interpolymers includes polymerizing a mixture of polymerizable monomers in the presence of one or more metallocene or constrained geometry catalysts in combination with various cocatalysts. The substantially random interpolymers can be prepared as described in EP-A- 0,416,815 by James C. Stevens et al. and US Patent No. 5,703,187 by Francis J. Timmers. Such a method of preparation of the substantially random interpolymers includes polymerizing a mixture of polymerizable monomers in the presence of one or more metallocene or constrained geometry catalysts in combination with various cocatalysts. Preferred operating conditions for such polymerization reactions are pressures from atmospheric up to 3000 atmospheres and temperatures from -30°C to 200°C. Polymerizations and unreacted monomer removal at temperatures above the autopolymerization temperature of the respective monomers may result in formation of some amounts of homopolymer polymerization products resulting from free radical polymerization. Examples of suitable catalysts and methods for preparing the substantially random interpolymers are disclosed in U.S. Application Serial No. 702,475, filed May 20, 1991 (EP-A-514,828); as well as U.S. Patents: 5,055,438; 5,057,475; 5,096,867; 5,064,802; 5,132,380; 5,189,192; 5,321,106; 5,347,024; 5,350,723; 5,374,696; 5,399,635; 5,470,993; 5,703,187; and 5,721,185. The substantially random α-olefin/vinyl aromatic interpolymers can also be prepared by the methods described in JP 07/278230 employing compounds shown by the general formula R ι where Cp 1 and Cp 2 are cyclopentadienyl groups, indenyl groups, fluorenyl groups, or substituents of these, independently of each other; R 1 and R 2 are hydrogen atoms, halogen atoms, hydrocarbon groups with carbon numbers of 1-12, alkoxyl groups, or aryloxyl groups, independently of each other; M is a group IV metal, preferably Zr or Hf, most preferably Zr; and R 3 is an alkylene group or silanediyl group used to crosslink Cp 1 and Cp 2 ). The substantially random α-olefin/vinyl aromatic interpolymers can also be prepared by the methods described by John G. Bradfute et al. (W. R. Grace & Co.) in WO 95/32095; by R. B. Pannell (Exxon Chemical Patents, Inc.) in WO 94/00500; and in Plastics Technology, p. 25 (September 1992). Also suitable are the substantially random interpolymers which comprise at least one α-olefin/vinyl aromatic/vinyl aromatic/α-olefin tetrad disclosed in U. S. Application No. 08/708,809 filed September 4, 1996 and WO 98/09999 both by Francis J. Timmers et al. These interpolymers contain additional signals in their carbon- 13 NMR spectra with intensities greater than three times the peak to peak noise. These signals appear in the chemical shift range 43.70 - 44.25 ppm and 38.0 - 38.5 ppm. Specifically, major peaks are observed at 44.1, 43.9, and 38.2 ppm. A proton test NMR experiment indicates that the signals in the chemical shift region 43.70 - 44.25 ppm are methine carbons and the signals in the region 38.0 - 38.5 ppm are methylene carbons. It is believed that these new signals are due to sequences involving two head- to-tail vinyl aromatic monomer insertions preceded and followed by at least one α- olefin insertion, for example an ethylene/styrene/styrene/ethylene tetrad wherein the styrene monomer insertions of said tetrads occur exclusively in a 1,2 (head to tail) manner. It is understood by one skilled in the art that for such tetrads involving a vinyl aromatic monomer other than styrene and an α-olefin other than ethylene that the ethylene/vinyl aromatic monomer/vinyl aromatic monomer/ethylene tetrad will give rise to similar carbon- 13 NMR peaks but with slightly different chemical shifts. These interpolymers can be prepared by conducting the polymerization at temperatures of from -30°C to 250°C in the presence of such catalysts as those represented by the formula 1 / \ wherein: each Cp is independently, each occurrence, a substituted cyclopentadienyl group π-bound to M; E is C or Si; M is a group IV metal, preferably Zr or Hf, most preferably Zr; each R is independently, each occurrence, H, hydrocarbyl, silahydrocarbyl, or hydrocarbylsilyl, containing up to 30 preferably from 1 to 20 more preferably from 1 to 10 carbon or silicon atoms; each R is independently, each occurrence, H, halo, hydrocarbyl, hyrocarbyloxy, silahydrocarbyl, hydrocarbylsilyl containing up to 30 preferably from 1 to 20 more preferably from 1 to 10 carbon or silicon atoms or two R' groups together can be a C,. 10 hydrocarbyl substituted 1,3- butadiene; m is 1 or 2; and optionally, but preferably in the presence of an activating cocatalyst. Particularly, suitable substituted cyclopentadienyl groups include those illustrated by the formula: wherein each R is independently, each occurrence, H, hydrocarbyl, silahydrocarbyl, or hydrocarbylsilyl, containing up to 30 preferably from 1 to 20 more preferably from 1 to 10 carbon or silicon atoms or two R groups together form a divalent derivative of such group. Preferably, R independently each occurrence is (including where appropriate all isomers) hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, phenyl or silyl or (where appropriate) two such R groups are linked together forming a fused ring system such as indenyl, fluorenyl, tetrahydroindenyl, tetrahydrofluorenyl, or octahydrofluorenyl. Particularly preferred catalysts include, for example, racemic- (dimethylsilanediyl)-bis-(2-methyl-4-phenylindenyl)zirconium dichloride, racemic- (dimethylsilanediyl)-bis-(2-methyl-4-phenylindenyl)zirconium 1 ,4-diphenyl- 1,3- butadiene, racemic-(dimethylsilanediyl)-bis-(2-methyl-4-phenylindenyl)zirconium di- Cl-4 alkyl, racemic-(dimethylsilanediyl)-bis-(2-methyl-4-phenylindenyl)zirconium di-Cl-4 alkoxide, or any combination thereof . It is also possible to use the following titanium-based constrained geometry catalysts, [N-(l , 1 -dimethylethyl)- 1 , 1 -dimethyl- 1 -[(1 ,2,3,4,5-η)- 1 ,5,6,7-tetrahydro-s- indacen-l-yl]silanaminato(2-)-N]titanium dimethyl; (l-indenyl)(tert- butylamido)dimethyl- silane titanium dimethyl; ((3-tert-butyl)(l,2,3,4,5-η)-l- indenyl)(tert-butylamido) dimethylsilane titanium dimethyl; and ((3-iso- propyl)(l,2,3,4,5-η)-l-indenyl)(tert-butyl amido)dimethylsilane titanium dimethyl, or any combination thereof . Further preparative methods for the interpolymers used in the present invention have been described in the literature. Longo and Grassi (Makromol. Chem., Volume 191, pages 2387 to 2396 [1990]) and D'Anniello et al. (Journal of Applied Polymer Science, Volume 58, pages 1701-1706 [1995]) reported the use of a catalytic system based on methylalumoxane (MAO) and cyclopentadienyltitanium trichloride (CpTiCl 3 ) to prepare an ethylene-styrene copolymer. Xu and Lin (Polymer Preprints, Am. Chem. Soc, Div. Polym. Chem.) Volume 35, pages 686,687 [1994]) have reported copolymerization using a MgCl 2 /TiCl 4 /NdCl 3 / Al(iBu) 3 catalyst to give random copolymers of styrene and propylene. Lu et al (Journal of Applied Polymer Science, Volume 53, pages 1453 to 1460 [1994]) have described the copolymerization of ethylene and styrene using a TiCl 4 /NdCl 3 / MgCl, /Al(Et), catalyst. Sernetz and Mulhaupt, fMacromol. Chem. Phys., v. 197, pp. 1071-1083, 1997) have described the influence of polymerization conditions on the copolymerization of styrene with ethylene using Me 2 Si(Me 4 Cp)(N-tert-butyl)TiCl 2 /methylaluminoxane Ziegler-Natta catalysts. Copolymers of ethylene and styrene produced by bridged metallocene catalysts have been described by Arai, Toshiaki and Suzuki (Polymer Preprints, Am. Chem. Soc. Div. Polym. Chem.) Volume 38, pages 349, 350 [1997]) and in United States patent number 5,652,315, issued to Mitsui Toatsu Chemicals, Inc. The manufacture of α-olefin/vinyl aromatic monomer interpolymers such as propylene/styrene and butene/styrene are described in United States patent number 5,244,996, issued to Mitsui Petrochemical Industries Ltd or United States patent number 5,652,315 also issued to Mitsui Petrochemical Industries Ltd or as disclosed in DE 197 11 339 Al to Denki Kagaku Kogyo KK. While preparing the substantially random interpolymer, an amount of atactic vinyl aromatic homopolymer may be formed due to homopolymerization of the vinyl aromatic monomer at elevated temperatures. The presence of vinyl aromatic homopolymer is in general not detrimental for the purposes of the present invention and can be tolerated. The vinyl aromatic homopolymer may be separated from the interpolymer, if desired, by extraction techniques such as selective precipitation from solution with a non solvent for either the interpolymer or the vinyl aromatic homopolymer. For the purpose of the present invention it is preferred that no more than 30 weight percent, preferably less than 20 weight percent based on the total weight of the interpolymers of atactic vinyl aromatic homopolymer is present. Blend Compositions Comprising the Substantially Random Interpolymers The present invention also provides films prepared from blends of the substantially random α-olefin/ vinyl or vinylidene interpolymers with one or more other polymer components which span a wide range of compositions. The other polymer component of the blend can include, but is not limited to, one or more of an engineering thermoplastic, an α-olefm homopolymer or interpolymer, a thermoplastic olefin, a styrenic block copolymer, a styrenic homo- or copolymer, an elastomer, or a vinyl halide polymer. Engineering Thermoplastics The third edition of the Kirk-Othmer Encyclopedia of Science and Technology (Volume 9, p 118 - 137) defines engineering plastics as thermoplastic resins, neat or unreinforced or filled, which maintain dimensional stability and most mechanical properties above 100°C and below 0°C. The terms "engineering plastics" and "engineering thermoplastics", can be used interchangeably. Engineering thermoplastics include acetal and acrylic resins, polyamides (for example nylon-6, nylon 6,6,), polyimides, polyetherimides, cellulosics, polyesters, poly(arylate), aromatic polyesters, poly(carbonate), poly(butylene) and polybutylene and polyethylene terephthalates, liquid crystal polymers, and selected polyolefins, blends, or alloys of the foregoing resins, and some examples from other resin types (including for example polyethers) high temperature polyolefins such as polycyclopentanes, its copolymers, and polymethylpentane.). An especially preferred engineering thermoplastic are the acrylic resins which derive from the peroxide-catalyzed free radical polymerization of methyl methacrylate (MMA). As described by H. Luke in Modern Plastics Encyclopedia, 1989, pps 20-21, MMA is usually copolymerized with other acrylates such as methyl- or ethyl acrylate using four basic polymerization processes, bulk, suspension, emulsion and solution. Acrylics can also be modified with various ingredients including butadiene, vinyl and butyl acrylate. The α-Olefin Homopolymers and Interpolymers The α-olefin homopolymers and interpolymers comprise polypropylene, propylene/C 4 -C 20 α- olefin copolymers, polyethylene, and ethylene/C 3 -C 20 α- olefin copolymers, the interpolymers can be either heterogeneous ethylene/α-olefin interpolymers or homogeneous ethylene/α-olefm interpolymers, including the substantially linear ethylene/α-olefin interpolymers. Also included are aliphatic α- olefins having from 2 to 20 carbon atoms and containing polar groups. Suitable aliphatic α-olefin monomers which introduce polar groups into the polymer include, for example, ethylenically unsaturated nitriles such as acrylonitrile, methacrylonitrile, ethacrylonitrile, etc.; ethylenically unsaturated anhydrides such as maleic anhydride; ethylenically unsaturated amides such as acrylamide, methacrylamide etc.; ethylenically unsaturated carboxylic acids (both mono- and difunctional) such as acrylic acid and methacrylic acid, etc.; esters (especially lower, for example C,-C 6 , alkyl esters) of ethylenically unsaturated carboxylic acids such as methyl methacrylate, ethyl acrylate, hydroxyethylacrylate, n-butyl acrylate or methacrylate, 2-ethyl-hexylacrylate, or ethylene-vinyl acetate copolymers etc.; ethylenically unsaturated dicarboxylic acid imides such as N-alkyl or N-aryl maleimides such as N-phenyl maleimide, etc. Preferably such monomers containing polar groups are acrylic acid, vinyl acetate, maleic anhydride and acrylonitrile. Halogen groups which can be included in the polymers from aliphatic α-olefm monomers include fluorine, chlorine and bromine; preferably such polymers are chlorinated polyethylenes (CPEs) Heterogeneous interpolymers are differentiated from the homogeneous interpolymers in that in the latter, substantially all of the interpolymer molecules have the same ethylene/comonomer ratio within that interpolymer, whereas heterogeneous interpolymers are those in which the interpolymer molecules do not have the same ethylene/comonomer ratio. The term "broad composition distribution" used herein describes the comonomer distribution for heterogeneous interpolymers and means that the heterogeneous interpolymers have a "linear" fraction and that the heterogeneous interpolymers have multiple melting peaks (that is, exhibit at least two distinct melting peaks) by DSC. The heterogeneous interpolymers have a degree of branching less than or equal to 2 methyls/1000 carbons in 10 percent (by weight) or more, preferably more than 15 percent (by weight), and especially more than 20 percent (by weight). The heterogeneous interpolymers also have a degree of branching equal to or greater than 25 methyls/1000 carbons in 25 percent or less (by weight), preferably less than 15 percent (by weight), and especially less than 10 percent (by weight). The Ziegler catalysts suitable for the preparation of the heterogeneous component of the current invention are typical supported, Ziegler-type catalysts. Examples of such compositions are those derived from organomagnesium compounds, alkyl halides or aluminum halides or hydrogen chloride, and a transition metal compound. Examples of such catalysts are described in U.S. Pat Nos. 4,314,912 (Lowery, Jr. et al.), 4,547,475 (Glass et al.), and 4,612,300 (Coleman, III). Suitable catalyst materials may also be derived from a inert oxide supports and transition metal compounds. Examples of such compositions are described in U.S. Pat No. 5,420,090 (Spencer, et al). The heterogeneous polymer component can be an α-olefin homopolymer preferably polyethylene or polypropylene, or, preferably, an interpolymer of ethylene with at least one C3-C20 α-olefin or C4-C18 dienes or a combination thereof. Heterogeneous copolymers of ethylene, and propylene, 1-butene, 1-hexene, 4-methyl- 1 -pentene and 1-octene are especially preferred. The relatively recent introduction of metallocene-based catalysts for ethylene/α-olefm polymerization has resulted in the production of new ethylene interpolymers known as homogeneous interpolymers. The homogeneous interpolymers useful for forming the compositions described herein have homogeneous branching distributions. That is, the polymers are those in which the comonomer is randomly distributed within a given interpolymer molecule and wherein substantially all of the interpolymer molecules have the same ethylene/comonomer ratio within that interpolymer. The homogeneity of the polymers is typically described by the SCBDI (Short Chain Branch Distribution Index) or CDBI (Composition Distribution Branch Index) and is defined as the weight percent of the polymer molecules having a comonomer content within 50 percent of the median total molar comonomer content. The CDBI of a polymer is readily calculated from data obtained from techniques known in the art, such as, for example, temperature rising elution fractionation (abbreviated herein as "TREF") as described, for example, in Wild et al, Journal of Polymer Science, Poly. Phys. Ed, Vol. 20, p. 441 (1982), in U.S. Patent 4,798,081 (Hazlitt et al.), or as is described in USP 5,008,204 (Stehling). The technique for calculating CDBI is described in USP 5,322,728 (Davey et al. ) and in USP 5,246,783 (Spenadel et al). or in U.S. Patent 5,089,321 (Chum et al). The SCBDI or CDBI for the homogeneous interpolymers used in the present invention is preferably greater than 30 percent, especially greater than 50 percent. The homogeneous interpolymers used in this invention essentially lack a measurable "high density" fraction as measured by the TREF technique (that is, the homogeneous ethylene/α-olefin interpolymers do not contain a polymer fraction with a degree of branching less than or equal to 2 methyls/1000 carbons). The homogeneous interpolymers also do not contain any highly short chain branched fraction (that is, they do not contain a polymer fraction with a degree of branching equal to or more than 30 methyls/1000 carbons). The substantially linear ethylene/α-olefin polymers and interpolymers of the present invention are also homogeneous interpolymers but are further herein defined as in U.S. Patent No. 5,272,236 (Lai et al.), and in U.S. Patent No. 5,272,872. Such polymers are unique however due to their excellent processability and unique rheological properties and high melt elasticity and resistance to melt fracture. These polymers can be successfully prepared in a continuous polymerization process using the constrained geometry metallocene catalyst systems. The term "substantially linear" ethylene/α-olefin interpolymer means that the polymer backbone is substituted with 0.01 long chain branches/1000 carbons to 3 long chain branches/1000 carbons, more preferably from 0.01 long chain branches/1000 carbons to 1 long chain branches/1000 carbons, and especially from 0.05 long chain branches/1000 carbons to 1 long chain branches/1000 carbons. Long chain branching is defined herein as a chain length of at least one carbon more than two carbons less than the total number of carbons in the comonomer, for example, the long chain branch of an ethylene/octene substantially linear ethylene interpolymer is at least seven (7) carbons in length (that is, 8 carbons less 2 equals 6 carbons plus one equals seven carbons long chain branch length). The long chain branch can be as long as about the same length as the length of the polymer back-bone. Long chain branching is determined by using ^C nuclear magnetic resonance (NMR) spectroscopy and is quantified using the method of Randall (Rev. Macromol. Chem. Phys., C29 (2&3), p. 285-297). Long chain branching, of course, is to be distinguished from short chain branches which result solely from incorporation of the comonomer, so for example the short chain branch of an ethylene/octene substantially linear polymer is six carbons in length, while the long chain branch for that same polymer is at least seven carbons in length. The catalysts used to prepare the homogeneous interpolymers for use as blend components in the present invention are metallocene catalysts. These metallocene catalysts include the bis(cyclopentadienyl)-catalyst systems and the mono(cyclopentadienyl) Constrained Geometry catalyst systems (used to prepare the substantially linear ethylene/α-olefin polymers). Such constrained geometry metal complexes and methods for their preparation are disclosed EP-A-416,815EP-A- 468,651; EP-A-514,828; as well as US-A-5,055,438, US-A-5,057,475, US-A- 5,096,867, US-A-5,064,802, US-A-5,132,380, US-A-5,721,185, US-A-5,374,696 and US-A-5,470,993 In EP-A 418,044, published March 20, 1991 certain cationic derivatives of the foregoing constrained geometry catalysts that are highly useful as olefin polymerization catalysts are disclosed and claimed. In US-A 5,453,410 combinations of cationic constrained geometry catalysts with an alumoxane were disclosed as suitable olefin polymerization catalysts. For the teachings contained therein, the aforementioned pending United States Patent applications, issued United States Patents and published European Patent Applications are herein incoφorated in their entirety by reference thereto. The homogeneous polymer component can be an α-olefin homopolymer preferably polyethylene or polypropylene, or, preferably, an interpolymer of ethylene with at least one C3-C20 α-olefin C4-C18 dienes. Homogeneous copolymers of ethylene, and propylene, 1-butene, 1-hexene, 4-methyl-l -pentene and 1-octene are especially preferred. Thermoplastic Olefins Thermoplastic olefins (TPOs) are generally produced from propylene homo- or copolymers, or blends of an elastomeric material such as ethylene/propylene rubber (EPM) or ethylene/propylene diene monomer terpolymer (EPDM) and a more rigid material such as isotactic polypropylene. Other materials or components can be added into the formulation depending upon the application, including oil, fillers, and cross- linking agents. Generally, TPOs are characterized by a balance of stiffness (modulus) and low temperature impact, good chemical resistance and broad use temperatures. Because of features such as these, TPOs are used in many applications, including automotive facia and instrument panels, and also potentially in wire and cable The polypropylene is generally in the isotactic form of homopolymer polypropylene, although other forms of polypropylene can also be used (for example, syndiotactic or atactic). Polypropylene impact copolymers (for example, those wherein a secondary copolymerization step reacting ethylene with the propylene is employed) and random copolymers (also reactor modified and usually containing 1.5-7 percent ethylene copolymerized with the propylene), however, can also be used in the TPO formulations disclosed herein. In-reactor TPO's can also be used as blend components of the present invention. A complete discussion of various polypropylene polymers is contained in Modern Plastics Encyclopedia/89, mid October 1988 Issue, Volume 65, Number 11, pp. 86-92. The molecular weight of the polypropylene for use in the present invention is conveniently indicated using a melt flow measurement according to ASTM D- 1238, Condition 230°C/2.16 kg (formerly known as "Condition (L)" and also known as 12). Melt flow rate is inversely proportional to the molecular weight of the polymer. Thus, the higher the molecular weight, the lower the melt flow rate, although the relationship is not linear. The melt flow rate for the polypropylene useful herein is generally from 0.1 grams/10 minutes (g/10 min) to 35 g/10 min, preferably from 0.5 g/10 min to 25 g/10 min, and especially from 1 g/10 min to 20 g/10 min. Styrenic Block Copolymers Also included are block copolymers having unsaturated rubber monomer units including, but not limited to, styrene-butadiene (SB), styrene-isoprene(SI), styrene- butadiene-styrene (SBS), styrene-isoprene-styrene (SIS), α-methylstyrene-butadiene- α-methylstyrene and α-methylstyrene-isoprene-α-methylstyrene. The styrenic portion of the block copolymer is preferably a polymer or interpolymer of styrene and its analogs and homologs including α-methylstyrene and ring-substituted styrenes, particularly ring-methylated styrenes. The preferred styrenics are styrene and α-methylstyrene, and styrene is particularly preferred. Block copolymers with unsaturated rubber monomer units may comprise homopolymers of butadiene or isoprene or they may comprise copolymers of one or both of these two dienes with a minor amount of styrenic monomer. Preferred block copolymers with saturated rubber monomer units comprise at least one segment of a styrenic unit and at least one segment of an ethylene- butene or ethylene-propylene copolymer. Preferred examples of such block copolymers with saturated rubber monomer units include styrene/ethylene-butene copolymers, styrene/ethylene-propylene copolymers, styrene/ethylene- butene/styrene (SEBS) copolymers, styrene/ethylene-propylene/styrene (SEPS) copolymers. Styrenic Homo- and Copolymers In addition to the block copolymers are the various styrene homopolymers and copolymers and rubber modified styrenics. These include polystyrene, high impact polystyrene and copolymers such as acrylonitrile-butadiene-styrene (ABS) polymers, styrene-acrylonitrile (SAN). Elastomers The elastomers include, but are not limited to, rubbers such as polyisoprene, polybutadiene, natural rubbers, ethylene/propylene rubbers, ethylene/propylene diene (EPDM) rubbers, styrene/butadiene rubbers, thermoplastic polyurethanes. Vinyl Halide Polymers Vinyl halide homopolymers and copolymers are a group of resins which use as a building block the vinyl structure CH 2 =CXY, where X is selected from the group consisting of F, Cl, Br, and I and Y is selected from the group consisting of F, Cl, Br, I and H. The vinyl halide polymer component of the blends of the present invention include but are not limited to homopolymers and copolymers of vinyl halides with copolymerizable monomers such as α-olefins including but not limited to ethylene, propylene, vinyl esters of organic acids containing 1 to 18 carbon atoms, for example vinyl acetate, vinyl stearate and so forth; vinyl chloride, vinylidene chloride, symmetrical dichloroethylene; acrylonitrile, methacrylonitrile; alkyl acrylate esters in which the alkyl group contains 1 to 8 carbon atoms, for example methyl acrylate and butyl acrylate; the corresponding alkyl methacrylate esters; dialkyl esters of dibasic organic acids in which the alkyl groups contain 1 - 8 carbon atoms, for example dibutyl fumarate, diethyl maleate, and so forth. Preferably the vinyl halide polymers are homopolymers or copolymers of vinyl chloride or vinylidene chloride. Poly (vinyl chloride) polymers (PVC) can be further classified into two main types by their degree of rigidity. These are "rigid" PVC and "flexible" PVC. Flexible PVC is distinguished from rigid PVC primarily by the presence of and amount of plasticizers in the resin. Flexible PVC typically has improved processability, lower tensile strength and higher elongation than rigid PVC. Of the vinylidene chloride homopolymers and copolymers (PVDC), typically the copolymers with vinyl chloride, acrylates or nitriles are used commercially and are most preferred. The choice of the comonomer significantly affects the properties of the resulting polymer. Perhaps the most notable properties of the various PVDC's are their low permeability to gases and liquids, barrier properties; and chemical resistance. Also included in the family of vinyl halide polymers for use as blend components of the present invention are the chlorinated derivatives of PVC typically prepared by post chlorination of the base resin and known as chlorinated PVC, (CPVC). Although CPVC is based on PVC and shares some of its characteristic properties, CPVC is a unique polymer having a much higher melt temperature range (410 - 450°C) and a higher glass transition temperature (239 - 275°F) than PVC. The compositions comprising at least one substantially random inteφolymer used to prepare the films or sheets or extruded profiles of the present invention in addition to optionally comprising one or more of another polymer components can optionally comprise one or more fillers. Fillers Also included as a potential component of the polymer compositions used in the present invention are various organic and inorganic fillers, the identity of which depends upon the type of application in the blend is to be utilized. Representative examples of such fillers include organic and inorganic fibers such as those made from asbestos, boron, graphite, ceramic, glass, metals (such as stainless steel) or polymers (such as aramid fibers) talc, carbon black, carbon fibers, calcium carbonate, alumina trihydrate, glass fibers, marble dust, cement dust, clay, feldspar, silica or glass, fumed silica, alumina, magnesium oxide, magnesium hydroxide, antimony oxide, zinc oxide, barium sulfate, aluminum silicate, calcium silicate, titanium dioxide, titanates, aluminum nitride, B 2 O 3 , nickel powder or chalk. Other representative organic or inorganic, fiber or mineral, fillers include carbonates such as barium, calcium or magnesium carbonate; fluorides such as calcium or sodium aluminum fluoride; hydroxides such as aluminum hydroxide; metals such as aluminum, bronze, lead or zinc; oxides such as aluminum, antimony, magnesium or zinc oxide, or silicon or titanium dioxide; silicates such as asbestos, mica, clay (kaolin or calcined kaolin), calcium silicate, feldspar, glass (ground or flaked glass or hollow glass spheres or microspheres or beads, whiskers or filaments), nepheline, perlite, pyrophyllite, talc or wollastonite; sulfates such as barium or calcium sulfate; metal sulfides; cellulose, in forms such as wood or shell flour; calcium terephthalate; and liquid crystals, or ground up plastrics such as thermoset polymers. Mixtures of more than one such filler may be used as well. These fillers could be employed in amounts from 0 to 90, preferably from 0 to 80, more preferably from 0 to 70 percent by weight based on the weight of the polymer or polymer blend. Other Additives Additives such as antioxidants (for example, hindered phenols such as, for example, Irganox™ 1010, and phosphites, for example, Irgafos™ 168, (both are registered trademarks of, and supplied by Ciba-Geigy Corporation, NY), u.v. stabilizers (including Tinuvin™ 328 and Chimassorb™ 944, both are registered trademarks of, and supplied by Ciba-Geigy Corporation, NY), cling additives (for example, polyisobutylene), slip agents (such as erucamide stearamide), antiblock additives, antifogging agents, colorants, pigments, can also be included in the inteφolymers blends employed to prepare the films or sheets or extruded profiles of the present invention, to the extent that they do not interfere with the properties of the substantially random inteφolymers. Processing aids, which are also referred to herein as plasticizers, are optionally provided to reduce the viscosity of a composition, and include the phthalates, such as dioctyl phthalate and diisobutyl phthalate, natural oils such as lanolin, and paraffin, naphthenic and aromatic oils obtained from petroleum refining, and liquid resins from rosin or petroleum feedstocks. Suitable modifiers which can be employed herein as the plasticizer include at least one plasticizer selected from the group consisting of phthalate esters, trimellitate esters, benzoates, adipate esters, epoxy compounds, phosphate esters (triaryl, trialkyl, mixed alkyl aryl phosphates), glutarates and oils. Particularly suitable phthalate esters include, for example, dialkyl C4-C18 phthalate esters such as diethyl, dibutyl phthalate, diisobutyl phthalate, butyl 2-ethylhexyl phthalate, dioctyl phthalate, diisooctyl phthalate, dinonyl phthalate, diisononyl phthalate, didecyl phthalate, diisodecyl phthalate, diundecyl phthalate, mixed aliphatic esters such as heptyl nonyl phthalate, di(n-hexyl, n-octyl, n-decyl) phthalate (P610), di(n-octyl, n-decyl) phthalate (P810), and aromatic phthalate esters such as diphenyl phthalate ester, or mixed aliphatic-aromatic esters such as benzyl butyl phthalate or any combination thereof . Exemplary classes of oils useful as processing aids include white mineral oil (such as Kaydol™ oil (available from Witco), and Shellflex™ 371 naphthenic oil (available from Shell Oil Company). Another suitable oil is Tuflo™ oil (available from Lyondell). Antifogging or antistatic agents can be added to the films and sheets of the present invention to increase surface conductivity and prevention of water droplet formation and attraction of dust and dirt on the film surface. These antifogging agents include, but are not limited to, glycerol mono-stearate, glycerol mono-oleate, lauric diphthalamides, ethoxylated amines, ethoxylated esters, and other additives known in the industry. Tackifiers can also be added to the polymer compositions used to prepare the films or sheets or extruded profiles of the present invention in order to alter the Tg and thus extend the available application temperature window of the film. Examples of the various classes of tackifiers include, but are not limited to, aliphatic resins, polyteφene resins, hydrogenated resins, mixed aliphatic-aromatic resins, styrene/α-methylene styrene resins, pure monomer hydrocarbon resin, hydrogenated pure monomer hydrocarbon resin, modified styrene copolymers, pure aromatic monomer copolymers, and hydrogenated aliphatic hydrocarbon resins. Exemplary aliphatic resins include those available under the trade designations Escorez™, Piccotac™, Mercures™, Wingtack™, Hi-Rez™, Quintone™, Tackirol™, etc. Exemplary polyteφene resins include those available under the trade designations Nirez™, Piccolyte™, Wingtack™, Zonarez™, etc. Exemplary hydrogenated resins include those available under the trade designations Escorez™, Arkon™, Clearon™, etc. Exemplary mixed aliphatic-aromatic resins include those available under the trade designations Escorez™, Regalite™, Hercures™, AR™, Imprez™, Norsolene™ M, Marukarez™, Arkon™ M, Quintone™, Wingtack™, etc. One particularly preferred class of tackifiers includes the styrene/α-methylene stryene tackifiers available from Hercules. Particularly suitable classes of tackifiers include Wingtack™ 86 and Hercotac™ 1149, Eastman H-130, and styrene/α-methyl styrene tackifiers. These additives are employed in functionally equivalent amounts known to those skilled in the art. For example, the amount of antioxidant employed is that amount which prevents the polymer or polymer blend from undergoing oxidation at the temperatures and environment employed during storage and ultimate use of the polymers. Such amount of antioxidants is usually in the range of from 0.01 to 10, preferably from 0.05 to 5, more preferably from 0.1 to 2 percent by weight based upon the weight of the polymer or polymer blend. Similarly, the amounts of any of the other enumerated additives are the functionally equivalent amounts such as the amount to render the polymer or polymer blend antiblocking, to produce the desired result, to provide the desired color from the colorant or pigment. Such additives can suitably be employed in the range of from 0.05 to 50, preferably from 0.1 to 35, more preferably from 0.2 to 20 percent by weight based upon the weight of the polymer or polymer blend. Preparation of the Blends Comprising the Substantially Random Inteφolymers The blended polymer compositions used to prepare the films or sheets or extruded profiles of the present invention can be prepared by any convenient method, including dry blending the individual components and subsequently melt mixing or melt compounding in a Haake torque rheometer or by dry blending without melt blending followed by part fabrication, either directly in the extruder or mill used to make the finished article (for example, the automotive part), or by pre-melt mixing in a separate extruder or mill (for example, a Banbury mixer), or by solution blending, or by compression molding, or by calendering. Preparation of the Films or Sheets or Extruded Profiles of the Present Invention The dead fold films of the present invention can be made using conventional fabrication techniques, for example simple bubble extrusion (usually with a high blow-up ratio (BUR)), biaxial orientation processes (such as tenter frames or double bubble processes), simple cast/sheet extrusion, coextrusion, lamination, etc. Conventional simple bubble extrusion processes (also known as hot blown film processes) are described, for example, in The Encyclopedia of Chemical Technology. Kirk-Othmer, Third Edition, John Wiley & Sons, New York, 1981, Vol 16, pp. 416- 417 and Vol. 18, pp. 191-192. Biaxial orientation film manufacturing processes such as described in the "double bubble" process of USP 3,456,044 (Pahlke), and the processes described in USP 4,352,849 (Mueller), USP 4,820,557 and 4,837,084 (both to Warren), USP 4,865,902 (Golike et al), USP 4,927,708 (Herran et al.), USP 4.952,451 (Mueller), and USP 4,963,419 and 5,059,481 (both to Lustig et al), can also be used to make the novel film structures of this invention. Biaxially oriented film structures can also be made by a tenter-frame technique, such as that used for oriented polypropylene. Injection molding, thermo forming, extrusion coating, profile extrusion, and sheet extrusion processes are described, for example, in Plastics Materials and Processes, Seymour S. Schwartz and Sidney H. Goodman, Van Nostrand Reinhold Company, New York, 1982, pp. 527-563, pp. 632-647, and pp. 596-602. The strips. tapes and ribbons of the present invention can be prepared by the primary extrusion process itself or by known post-extrusion slitting, cutting or stamping techniques. Profile extrusion is an example of a primary extrusion process that is particularly suited to the preparation of tapes, bands, ribbons . The dead fold films of the present invention can also be rendered pervious or "breathable" by any method well known in the art including by apperturing, slitting, microperforating, mixing with fibers or foams, or the like and combinations thereof. Examples of such methods include, USP 3,156,242 by Crowe, Jr., USP 3,881,489 by Hartwell, USP 3,989,867 by Sisson and USP 5,085,654 by Buell, the disclosures of all of which are incoφorate herein by reference. The film structure and the substantially random inteφolymer selected for use in the practice of this invention will depend in large part upon the particulars of the application, for example the preferred properties of a film used in a shrink wrap are different than the preferred properties of a film used in a stretch overwrap. The present dead fold film structures can be monolayer film or a multilayer film in which one or more film layers comprises at least one substantially random inteφolymer. In those embodiments in which the film structure is multilayer, it can be of any conventional structure, for example 2-ply, 3-ply, 4-ply, 5-ply, 6-ply, 7-ply, etc. The structure will generally have an odd number of layers, and the film layer(s) comprising a substantially random inteφolymer can be one or both outer layers one or more core layers. Those layer(s) constructed from polymer other than a substantially random inteφolymer can comprise any suitable material generally compatible with a film constructed from a substantially random inteφolymer, for example one or more conventional LDPE, LLDPE, ULDPE, EVA, EAA, . Additives such as those described above with respect to monolayer films can also be used in these multilayer films, and these additives can be incoφorated into any of the film layers as desired, for example tackifiers and slip agents into one or both outer layers, fillers in one or more core layers, etc. Other multilayer film manufacturing techniques for food packaging applications are described in Packaging Foods With Plastics by Wilmer A. Jenkins and James P. Harrington (1991), pp. 19-27, and in "Coextrusion Basics" by Thomas I. Butler, Film Extrusion Manual: Process, Materials. Properties, pp. 31-80 (published by TAPPI Press (1992)). Other desirable properties of the plastic films used in this invention include, depending on the nature of the other film layers in the structure, ease of fabrication and good oxygen permeability (particularly with respect to films made from such copolymers as EVA and EAA), oxygen impermeability (particularly with respect to films containing an oxygen barrier such as SARAN or ethylene vinyl alcohol), dart impact, puncture resistance, tensile strength, low modulus, tear resistance, shrinkability, high clarity and a low affect on the taste and odor properties of the packaged food. The plastic films of this invention are well suited for stretch overwrap packaging various fresh foods, for example retail-cut red meats, fish, poultry, vegetables, fruits, cheeses, and other food products destined for retail display and that benefit from access to environmental oxygen. These films are preferably prepared as nonshrink films (for example, without biaxial orientation induced by double bubble processing) with good oxygen permeability, stretch, elastic recovery and hot tack characteristics, and can be made available to wholesalers and retailers in any conventional form, for example stock rolls, and used on all conventional equipment. Other plastic films of this invention can be used as shrink, skin and vacuum form packages for foods. The films comprising the shrink packages are typically biaxially oriented, exhibit low shrink tension, are of a density greater than 0.89 g/cm^, and are typically 0.6 to 2 mil in thickness. The elastic film structures used in vacuum skin packaging can be multilayered, are typically 5 to 12 mil in thickness. The dead fold films of the present invention can also be formed by extrusion processes and, most preferably, by art-known coextrusion methods. Following coextrusion the film is cooled to a solid state by, for example, cascading water or chilled air quenching. For some structures a precursor film layer or layers may be formed by extrusion with additional layers thereafter being extrusion coated thereon to form multilayer films. Two multilayer tubes may also be formed with one of the tubes thereafter being coated or laminated onto the other. Properties of the Inteφolymers and Blend Compositions Used to Prepare the Films or Sheets or Extruded Profiles of the Present Invention The polymer compositions used to prepare the films or sheets or extruded profiles of the present invention comprise from 25 to 100, preferably from 40 to 95, more preferably from 50 to 95 wt percent, (based on the combined weights of this component and the polymer component other than the substantially random inteφolymer) of one or more inteφolymers of one or more α-olefins and one or more monovinyl aromatic monomers or one or more aliphatic or cycloaliphatic vinyl or vinylidene monomers, or a combination thereof. These substantially random inteφolymers usually contain from 29 to 65 preferably from 33 to 65, more preferably from 35 to 65 mole percent of at least one vinyl aromatic monomer or aliphatic or cycloaliphatic vinyl or vinylidene monomer, or combination thereof, and from 35 to 71, preferably from 35 to 67, more preferably from 35 to 65 mole percent of at least one aliphatic α-olefin having from 2 to 20 carbon atoms. The number average molecular weight (Mn) of the substantially random inteφolymer used to prepare the films or sheets or extruded profiles of the present invention is greater than 10,000, preferably from 20,000 to 500,000, more preferably The melt index (I 2 ) of the substantially random inteφolymer used to prepare the films or sheets or extruded profiles of the present invention is from 0.01 to 100, preferably of from 0.1 to 20, more preferably of from 0.1 to 5 g/10 min. The molecular weight distribution (MJM n ) of the substantially random inteφolymer used to prepare the films or sheets or extruded profiles of the present invention is from 1.5 to 20, preferably of from 1.8 to 10, more preferably of from 2 to 5. The density of the substantially random inteφolymer used to prepare the films or sheets or extruded profiles of the present invention is greater than 0.930, preferably from 0.930 to 1.045, more preferably of from 0.930 to 1.040, most preferably of from 0.930 to 1.030 g/cm 3 . The polymer compositions used to prepare the films or sheets or extruded profiles of the present invention can also comprise from 0 to 75, preferably from 5 to 60, more preferably from 5 to 50 weight percent of at least one polymer other than the substantially random inteφolymer (based on the combined weights of this component and the substantially random inteφolymer) which can comprise a homogenous α- olefin homopolymer or inteφolymer comprising polypropylene, propylene/C 4 -C 20 α- olefin copolymers, polyethylene, and ethylene/C 3 -C 20 α- olefin copolymers, the inteφolymers can be either heterogeneous ethylene/α-olefm inteφolymers , preferably a heterogenous ethylene/ C 3 -C 8 α-olefin inteφolymer, most preferably a heterogenous ethylene/ octene-1 inteφolymer or homogeneous ethylene/α-olefm inteφolymers, including the substantially linear ethylene/α-olefm inteφolymers, preferably a substantially linear ethylene/α-olefin inteφolymer, most preferably a substantially linear ethylene/C 3 -C 8 α-olefin inteφolymer; or a heterogenous ethylene/α-olefm inteφolymer; or a thermoplastic olefin, preferably an ethylene/propylene rubber (EPM) or ethylene/propylene diene monomer teφolymer (EPDM) or isotactic polypropylene, most preferably isotactic polypropylene; or a styreneic block copolymer, preferably styrene-butadiene (SB), styrene-isoprene(SI), styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS) or styrene- ethylene/butene-styrene (SEBS) block copolymer, most preferably a styrene- butadiene-styrene (SBS) copolymer; or styrenic homopolymers or copolymers, preferably polystyrene, high impact polystyrene, polyvinyl chloride, copolymers of styrene and at least one of acrylonitrile, methacrylonitrile, maleic anhydride, or α- methyl styrene, most preferably polystyrene, or elastomers, preferably polyisoprene, polybutadiene, natural rubbers, ethylene/propylene rubbers, ethylene/propylene diene (EPDM) rubbers, styrene/butadiene rubbers, thermoplastic polyurethanes, most preferably thermoplastic polyurethanes; or vinyl halide homopolymers and copolymers, preferably homopolymers or copolymers of vinyl chloride or vinylidene chloride or the chlorinated derivatives therefrom, most preferably poly (vinyl chloride) and poly (vinylidene chloride); or engineering thermosplastics, preferably poly(methylmethacrylate) (PMMA), cellulosics, nylons, poly(esters), poly(acetals); poly(amides),the poly(arylate), aromatic polyesters, poly(carbonate), poly(butylene) and polybutylene and polyethylene terephthalates, most preferably poly (methylmethacry late) (PMMA), and poly (esters). The films or sheets or extruded profiles according to the present invention may be successfully employed for packaging in general and for packaging small items in particular. Other potential applications include, but are not limited to, meat over-wrap, paper replacement, stand-up or flat bottomed bags, table cloths and shower curtains, collapsible bottles or containers, tubes such as toothpaste tubes, fold-down structures, boxes, cartons, window boxes, surgical drapes, formable membranes, toys, tubing and clothing, tapes, laminating films, pressure sensitive labels The following examples are illustrative of the invention, but are not to be construed as to limiting the scope thereof in any manner. EXAMPLES Test Methods a) Melt Flow and Density Measurements The molecular weight of the polymer compositions for use in the present invention is conveniently indicated using a melt index measurement according to ASTM D-1238, Condition 190°C/2.16 kg (formally known as "Condition (E)" and also known as 12) was determined. Melt index is inversely proportional to the molecular weight of the polymer. Thus, the higher the molecular weight, the lower the melt index, although the relationship is not linear. Also useful for indicating the molecular weight of the substantially random inteφolymers used in the present invention is the Gottfert melt index (G, cm 3 / 10 min) which is obtained in a similar fashion as for melt index (I 2 ) using the ASTM D1238 procedure for automated plastometers, with the melt density set to 0.7632, the melt density of polyethylene at 190°C. The relationship of melt density to styrene content for ethylene-styrene inteφolymers was measured, as a function of total styrene content, at 190°C for a range of 29.8 percent to 81.8 percent by weight styrene. Atactic polystyrene levels in these samples was typically 10 percent or less. The influence of the atactic polystyrene was assumed to be minimal because of the low levels. Also, the melt density of atactic polystyrene and the melt densities of the samples with high total styrene are very similar. The method used to determine the melt density employed a Gottfert melt index machine with a melt density parameter set to 0.7632, and the collection of melt strands as a function of time while the I2 weight was in force. The weight and time for each melt strand was recorded and normalized to yield the mass in grams per 10 minutes. The instrument's calculated I2 melt index value was also recorded. The equation used to calculate the actual melt density is ' 0.7632 x 12 /I2 Gottfert where δ 07632 = 0.7632 and 12 Gottfert = displayed melt index. A linear least squares fit of calculated melt density versus total styrene content leads to an equation with a correlation coefficient of 0.91 for the following equation: δ = 0.00299 x S + 0.723 where S = weight percentage of styrene in the polymer. The relationship of total styrene to melt density can be used to determine an actual melt index value, using these equations if the styrene content is known. So for a polymer that is 73 percent total styrene content with a measured melt flow (the "Gottfert number"), the calculation becomes: x=0.00299*73 + 0.723 = 0.9412 where 0.9412/0.7632 = I-/ G# (measured) = 1.23 The density of the substantially random inteφolymers used in the present invention was determined in accordance with ASTM D-792. b) Styrene Analyses Inteφolymer styrene content and atactic polystyrene concentration were determined using proton nuclear magnetic resonance (Η N.M.R). All proton NMR samples were prepared in 1, 1, 2, 2-tetrachloroethane-d 2 (TCE-d 2 ). The resulting solutions were 1.6 - 3.2 percent polymer by weight. Melt index (I 2 ) was used as a guide for determining sample concentration. Thus when the I 2 was greater than 2 g/10 min, 40 mg of inteφolymer was used; with an I 2 between 1.5 and 2 g/10 min, 30 mg of inteφolymer was used; and when the I 2 was less than 1.5 g/10 min, 20 mg of inteφolymer was used. The inteφolymers were weighed directly into 5 mm sample tubes. A 0.75 mL aliquot of TCE-d 2 was added by syringe and the tube was capped with a tight-fitting polyethylene cap. The samples were heated in a water bath at 85°C to soften the inteφolymer. To provide mixing, the capped samples were occasionally brought to reflux using a heat gun. Proton NMR spectra were accumulated on a Varian VXR 300 with the sample probe at 80°C, and referenced to the residual protons of TCE-d 2 at 5.99 ppm. The delay times were varied between 1 second, and data was collected in triplicate on each sample. The following instrumental conditions were used for analysis of the inteφolymer samples: Varian VXR-300, standard Η: Sweep Width, 5000 Hz Acquisition Time, 3.002 sec Pulse Width, 8 μsec Frequency, 300 MHz Delay, 1 sec Transients, 16 The total analysis time per sample was 10 minutes. Initially, a Η NMR spectrum for a sample of the polystyrene, Styron™ 680 (available from and a registered trademark of the Dow Chemical Company, Midland, MI) was acquired with a delay time of one second. The protons were "labeled": b, branch; a, alpha; o, ortho; m, meta; p, para, as shown in Figure 1. Figure 1. Integrals were measured around the protons labeled in Figure 1 ; the 'A' designates aPS. Integral A 7 , (aromatic, around 7.1 ppm) is believed to be the three ortho/para protons; and integral A 66 (aromatic, around 6.6 ppm) the two meta protons. The two aliphatic protons labeled α resonate at 1.5 ppm; and the single proton labeled b is at 1.9 ppm. The aliphatic region was integrated from 0.8 to 2.5 ppm and is referred to as A al . The theoretical ratio for A 7 , : A 66 : A al is 3 : 2: 3, or 1.5 : 1 : 1.5, and correlated very well with the observed ratios for the Styron™ 680 sample for several delay times of 1 second. The ratio calculations used to check the integration and verify peak assignments were performed by dividing the appropriate integral by the integral A 66 Ratio A r is A 7 , / A 66 . Region A 6 _ was assigned the value of 1. Ratio Al is integral A al / A 66 . All spectra collected have the expected 1.5: 1: 1.5 integration ratio of (o+p): m: (α+b). The ratio of aromatic to aliphatic protons is 5 to 3. An aliphatic ratio of 2 to 1 is predicted based on the protons labeled α and b respectively in Figure 1. This ratio was also observed when the two aliphatic peaks were integrated separately. For the ethylene/styrene inteφolymers, the Η NMR spectra using a delay time of one second, had integrals C 7 ,, C 66 , and C aI defined, such that the integration of the peak at 7.1 ppm included all the aromatic protons of the copolymer as well as the o & p protons of aPS. Likewise, integration of the aliphatic region C al in the spectrum of the inteφolymers included aliphatic protons from both the aPS and the inteφolymer with no clear baseline resolved signal from either polymer. The integral of the peak at 6.6 ppm C 66 is resolved from the other aromatic signals and it is believed to be due solely to the aPS homopolymer (probably the meta protons). (The peak assignment for atactic polystyrene at 6.6 ppm (integral A 66 ) was made based upon comparison to the authentic sample Styron™ 680 (available from and a registered trademark of the Dow Chemical Company, Midland, MI)). This is a reasonable assumption since, at very low levels of atactic polystyrene, only a very weak signal is observed here. Therefore, the phenyl protons of the copolymer must not contribute to this signal. With this assumption, integral A 6 _ becomes the basis for quantitatively determining the aPS content. The following equations were then used to determine the degree of styrene incoφoration in the ethylene/styrene inteφolymer samples: (C Phenyl) = C 7 1 + A 7 1 - ( 1.5 x A 66 ) (C Aliphatic) = C al - ( 1 5 x A 66 ) s c = (C Phenyl) /5 e c = (C Aliphatic - (3 x s c )) /4 E = e c / (e c + s c ) S c = s c / (e c + s c ) and the following equations were used to calculate the mol percent ethylene and styrene in the inteφolymers. and where: s c and e c are styrene and ethylene proton fractions in the inteφolymer, respectively, and S c and E are mole fractions of styrene monomer and ethylene monomer in the inteφolymer, respectively. The weight percent of aPS in the inteφolymers was then determined by the following equation: The total styrene content was also determined by quantitative Fourier Transform Infrared spectroscopy (FTIR). Preparation of ESI Inteφolymers Used in Examples and Comparative Experiments of Present Invention 1) Preparation of ESI #'s 1-7 ESI #'s 1 - 7 are substantially random ethylene/styrene inteφolymers prepared using the following catalyst and polymerization procedures. Preparation of Catalyst A (dimethyll -f l.l-dimethylethyl)-l,l-dimethyl-l-r(T ,2,3,4.5- η)-l,5,6,7-tetrahvdro-3-phenyl-s-indacen-l-yl]silanaminato(2-)-N]- titanium) 1) Preparation of 3,5, 6,7-Tetrahydro-s-Hydrindacen-l(2H)-one Indan (94.00 g, 0.7954 moles) and 3-chloropropionyl chloride (100.99 g, 0.7954 moles) were stirred in CH 2 C1 2 (300 mL) at 0°C as A1C1 3 (130.00 g, 0.9750 moles) was added slowly under a nitrogen flow. The mixture was then allowed to stir at room temperature for 2 hours. The volatiles were then removed. The mixture was then cooled to 0°C and concentrated H 2 S0 4 (500 mL) slowly added. The forming solid had to be frequently broken up with a spatula as stirring was lost early in this step. The mixture was then left under nitrogen overnight at room temperature. The mixture was then heated until the temperature readings reached 90°C. These conditions were maintained for a 2 hour period of time during which a spatula was periodically used to stir the mixture. After the reaction period crushed ice was placed in the mixture and moved around. The mixture was then transferred to a beaker and washed intermittently with H 2 0 and diethylether and then the fractions filtered and combined. The mixture was washed with H 2 0 (2 x 200 mL). The organic layer was then separated and the volatiles removed. The desired product was then isolated via recrystallization from hexane at 0°C as pale yellow crystals (22.36 g, 16.3 percent yield). Η NMR (CDC1 3 ): d2.04-2.19 (m, 2 H), 2.65 (t, 3 JHH=5.7 HZ, 2 H), 2.84-3.0 (m, 4 H), 3.03 (t, 3 JHH=5.5 HZ, 2 H), 7.26 (s, 1 H), 7.53 (s, 1 H). 1 C NMR (CDC1 3 ): d25.71, 26.01, 32.19, 33.24, 36.93, 118.90, 122.16, 135.88, 144.06, 152.89, 154.36, 206.50. GC-MS: Calculated for C, 2 H 12 O 172.09, found 172.05. 2) Preparation of 1,2,3, 5-Tetrahydro-7-phenyl-s-indacen. 3,5,6,7-Tetrahydro-s-Hydrindacen-l(2H)-one (12.00 g, 0.06967 moles) was stirred in diethylether (200 mL) at 0°C as PhMgBr (0.105 moles, 35.00 mL of 3.0 M solution in diethylether) was added slowly. This mixture was then allowed to stir overnight at room temperature. After the reaction period the mixture was quenched by pouring over ice. The mixture was then acidified (pH=l) with HCl and stirred vigorously for 2 hours. The organic layer was then separated and washed with H 2 0 (2 x 100 mL) and then dried over MgS0 4 . Filtration followed by the removal of the volatiles resulted in the isolation of the desired product as a dark oil (14.68 g, 90.3 percent yield). Η NMR (CDC1 3 ): d2.0-2.2 (m, 2 H), 2.8-3.1 (m, 4 H), 6.54 (s, 1H), 7.2-7.6 (m, 7 H). GC-MS: Calculated for C, 18 H 16 232.13, found 232.05. 3) Preparation of 1,2,3, 5-Tetrahydro-7-phenyl-s-indacene, dilithium salt. l,2,3,5-Tetrahydro-7-phenyl-s-indacen (14.68 g, 0.06291 moles) was stirred in hexane (150 mL) as nBuLi (0.080 moles, 40.00 mL of 2.0 M solution in cyclohexane) was slowly added. This mixture was then allowed to stir overnight. After the reaction period the solid was collected via suction filtration as a yellow solid which was washed with hexane, dried under vacuum, and used without further purification or analysis (12.2075 g, 81.1 percent yield). 4) Preparation of Chlorodimethyl( 1 ,5,6,7-tetrahydro-3-phenyl-s-indacen- 1 -yl)silane. l,2,3,5-Tetrahydro-7-phenyl-s-indacene, dilithium salt (12.2075 g, 0.05102 moles) in THF (50 mL) was added dropwise to a solution of Me 2 SiCl 2 (19.5010 g, 0.1511 moles) in THF (100 mL) at 0°C. This mixture was then allowed to stir at room temperature overnight. After the reaction period the volatiles were removed and the residue extracted and filtered using hexane. The removal of the hexane resulted in the isolation of the desired product as a yellow oil (15.1492 g, 91.1 percent yield). 'H NMR (CDC1 3 ): dθ.33 (s, 3 H), 0.38 (s, 3 H), 2.20 (p, 3 JHH=7.5 Hz, 2 H), 2.9-3.1 (m, 4 H), 3.84 (s, 1 H), 6.69 (d, 3 JHH=2.8 HZ, 1 H), 7.3-7.6 (m, 7 H), 7.68 (d, 3 JHH=7.4 HZ, 2 H). C NMR (CDC1 3 ): dθ.24, 0.38, 26.28, 33.05, 33.18, 46.13, 116.42, 119.71, 127.51, 128.33, 128.64, 129.56, 136.51, 141.31, 141.86, 142.17, 142.41, 144.62. GC-MS: Calculated for C 2Q H 2 .ClSi 324.11, found 324.05. 5) Preparation of N-(l,l-Dimethylethyl)-l,l-dimethyl-l-(l,5,6,7-tetrahydro-3- phenyl-s-indacen-l-yl)silanamine. Chlorodimethyl(l,5,6,7-tetrahydro-3-phenyl-s-indacen-l-yl)silane (10.8277 g, 0.03322 moles) was stirred in hexane (150 mL) as NEt 3 (3.5123 g, 0.03471 moles) and t-butylamine (2.6074 g, 0.03565 moles) were added. This mixture was allowed to stir for 24 hours. After the reaction period the mixture was filtered and the volatiles removed resulting in the isolation of the desired product as a thick red-yellow oil (10.6551 g, 88.7 percent yield). 'H NMR (CDC1 3 ): dθ.02 (s, 3 H), 0.04 (s, 3 H), 1.27 (s, 9 H), 2.16 (p, 3 JHH=7.2 HZ, 2 H), 2.9-3.0 (m, 4 H), 3.68 (s, 1 H), 6.69 (s, 1 H), 7.3-7.5 (m, 4 H), 7.63 (d, 3 JHH=7.4 HZ, 2 H). I3 C NMR (CDC1 3 ): d-0.32, -0.09, 26.28, 33.39, 34.11, 46.46, 47.54, 49.81, 115.80, 119.30, 126.92, 127.89, 128.46, 132.99, 137.30, 140.20, 140.81, 141.64, 142.08, 144.83. 6) Preparation of N-(l,l-Dimethylethyl)-l,l-dimethyl-l-(l,5,6,7-tetrahydro-3- phenyl-s-indacen-1-yl) silanamine, dilithium salt. N-(l,l-Dimethylethyl)-l,l-dimethyl-l-(l,5,6,7-tetrahydro-3-phenyl-s-indacen- l-yl)silanamine (10.6551 g, 0.02947 moles) was stirred in hexane (100 mL) as nBuLi (0.070 moles, 35.00 mL of 2.0 M solution in cyclohexane) was added slowly. This mixture was then allowed to stir overnight during which time no salts crashed out of the dark red solution. After the reaction period the volatiles were removed and the residue quickly washed with hexane (2 x 50 mL). The dark red residue was then pumped dry and used without further purification or analysis (9.6517 g, 87.7 percent yield). 7) Preparation of Dichloro[N-(l , 1 -dimethylethyl)-l , 1 -dimethyl- 1 -[(1 ,2,3,4,5-η)- 1 ,5,6,7-tetrahydro-3-phenyl-s-indacen- 1 -yl]silanaminato(2-)-N]titanium N-( 1 , 1 -Dimethylethyl)- 1 , 1 -dimethyl- 1 -( 1 ,5 ,6,7-tetrahydro-3 -phenyl-s-indacen- l-yl)silanamine, dilithium salt (4.5355 g, 0.01214 moles) in THF (50 mL) was added dropwise to a slurry of TiCl 3 (THF) 3 (4.5005 g, 0.01214 moles) in THF (100 mL). This mixture was allowed to stir for 2 hours. PbCl 2 (1.7136 g, 0.006162 moles) was then added and the mixture allowed to stir for an additional hour. After the reaction period the volatiles were removed and the residue extracted and filtered using toluene. Removal of the toluene resulted in the isolation of a dark residue. This residue was then slurried in hexane and cooled to 0°C. The desired product was then isolated via filtration as a red-brown crystalline solid (2.5280 g, 43.5 percent yield). Η NMR (CDC1 3 ): dθ.71 (s, 3 H), 0.97 (s, 3 H), 1.37 (s, 9 H), 2.0-2.2 (m, 2 H), 2.9- 3.2 (m, 4 H), 6.62 (s, 1 H), 7.35-7.45 (m, 1 H), 7.50 (t, HZ, 2 H), 7.57 (s, 1 H), 7.70 (d, 3 JHH=7.1 HZ, 2 H), 7.78 (s, 1 H). 'H NMR (C 6 D 6 ): dθ.44 (s, 3 H), 0.68 (s, 3 H), 1.35 (s, 9 H), 1.6-1.9 (m, 2 H), 2.5-3.9 (m, 4 H), 6.65 (s, 1 H), 7.1-7.2 (m, 1 H), 7.24 (t, 3 JHH=7.1 HZ, 2 H), 7.61 (s, 1 H), 7.69 (s, 1 H), 7.77-7.8 (m, 2 H). 13 C NMR (CDC1 3 ): dl.29, 3.89, 26.47, 32.62, 32.84, 32.92, 63.16, 98.25, 118.70, 121.75, 125.62, 128.46, 128.55, 128.79, 129.01, 134.11, 134.53, 136.04, 146.15, 148.93. I3 C NMR (C 6 D 6 ): dθ.90, 3.57, 26.46, 32.56, 32.78, 62.88, 98.14, 119.19, 121.97, 125.84, 127.15, 128.83, 129.03, 129.55, 134.57, 135.04, 136.41, 136.51, 147.24, 148.96. 8) Preparation of Dimethyl[N-(l , 1 -dimethylethyl)- 1 , 1 -dimethyl- 1 -[(1 ,2,3,4,5-η)- l,5,6,7-tetrahydro-3-phenyl-s-indacen-l-yl]silanaminato(2-)-N]titanium Dichloro[N-(l,l-dimethylethyl)-l,l-dimethyl-l-[(l,2,3,4,5-η)-l,5,6,7- tetrahydro-3-phenyl-s-indacen-l-yl]silanaminato(2-)-N]titanium (0.4970 g, 0.001039 moles) was stirred in diethylether (50 mL) as MeMgBr (0.0021 moles, 0.70 mL of 3.0 M solution in diethylether) was added slowly. This mixture was then stirred for 1 hour. After the reaction period the volatiles were removed and the residue extracted and filtered using hexane. Removal of the hexane resulted in the isolation of the desired product as a golden yellow solid (0.4546 g, 66.7 percent yield). *H NMR (C 6 D 6 ): dθ.071 (s, 3 H), 0.49 (s, 3 H), 0.70 (s, 3 H), 0.73 (s, 3 H), 1.49 (s, 9 H), 1.7-1.8 (m, 2 H), 2.5-2.8 (m, 4 H), 6.41 (s, 1 H), 7.29 (t, 3 JHH=7.4 HZ, 2 H), 7.48 (s, 1 H), 7.72 (d, 3 JHH=7.4 HZ, 2 H), 7.92 (s, 1 H). 13 C NMR (C 6 D 6 ): d2.19, 4.61, 27.12, 32.86, 33.00, 34.73, 58.68, 58.82, 118.62, 121.98, 124.26, 127.32, 128.63, 128.98, 131.23, 134.39, 136.38, 143.19, 144.85. Preparation of Catalyst B;(lH-cvclopenta[l]phenanthrene-2-yl)dimethyl(t- butylamidoVsilanetitanium 1 ,4-diphenylbutadiene) 1) Preparation of lithium lH-cyclopenta[l]phenanthrene-2-yl To a 250 ml round bottom flask containing 1.42 g (0.00657 mole) of 1H- cyclopenta[l]phenanthrene and 120 ml of benzene was added dropwise, 4.2 ml of a 1.60 M solution of n-BuLi in mixed hexanes. The solution was allowed to stir overnight. The lithium salt was isolated by filtration, washing twice with 25 ml benzene and drying under vacuum. Isolated yield was 1.426 g (97.7 percent). 1H NMR analysis indicated the predominant isomer was substituted at the 2 position. 2) Preparation of ( 1 H-cyclopenta[l]phenanthrene-2-yl)dimethylchlorosilane To a 500 ml round bottom flask containing 4.16 g (0.0322 mole) of dimethyldichlorosilane (Me 2 SiCl 2 ) and 250 ml of tetrahydrofuran (THF) was added dropwise a solution of 1.45 g (0.0064 mole) of lithium lH-cyclopenta[l]phenanthrene- 2-yl in THF. The solution was stirred for approximately 16 hours, after which the solvent was removed under reduced pressure, leaving an oily solid which was extracted with toluene, filtered through diatomaceous earth filter aid (Celite™), washed twice with toluene and dried under reduced pressure. Isolated yield was 1.98 g (99.5 percent). 3. Preparation of (lH-cyclopenta[l]phenanthrene-2-yl)dimethyl(t-butylamino)silane To a 500 ml round bottom flask containing 1.98 g (0.0064 mole) of (1H- cyclopenta[l]phenanthrene-2-yl)dimethylchlorosilane and 250 ml of hexane was added 2.00 ml (0.0160 mole) of t-butylamine. The reaction mixture was allowed to stir for several days, then filtered using diatomaceous earth filter aid (Celite™), washed twice with hexane. The product was isolated by removing residual solvent under reduced pressure. The isolated yield was 1.98 g (88.9 percent). 4. Preparation of dilithio (lH-cyclopenta[l]phenanthrene-2-yl)dimethyl(t- butylamido)silane To a 250 ml round bottom flask containing 1.03 g (0.0030 mole) of (1H- cyclopenta[l]phenanthrene-2-yl)dimethyl(t-butylamino)silane) and 120 ml of benzene was added dropwise 3.90 ml of a solution of 1.6 M n-BuLi in mixed hexanes. The reaction mixture was stirred for approximately 16 hours. The product was isolated by filtration, washed twice with benzene and dried under reduced pressure. Isolated yield was 1.08 g (100 percent). 5. Preparation of (1 H-cyclopenta[l]phenanthrene-2-yl)dimethyl(t- butylamido)silanetitanium dichloride To a 250 ml round bottom flask containing 1.17 g (0.0030 mole) of TiCl3»3THF and 120 ml of THF was added at a fast drip rate 50 ml of a THF solution of 1.08 g of dilithio (lH-cyclopenta[l]phenanthrene-2-yl)dimethyl(t- butylamido)silane. The mixture was stirred at 20 °C for 1.5 h at which time 0.55 gm (0.002 mole) of solid PbCl2 was added. After stirring for an additional 1.5 h the THF was removed under vacuum and the reside was extracted with toluene, filtered and dried under reduced pressure to give an orange solid. Yield was 1.31 g (93.5 percent). 6. Preparation of ( 1 H-cy clopenta[l]phenanthrene-2-y l)dimethy l(t- butylamido)silanetitanium 1 ,4-diphenylbutadiene To a slurry of (lH-cyclopenta[l]phenanthrene-2-yl)dimethyl(t- butylamido)silanetitanium dichloride (3.48 g, 0.0075 mole) and 1.551 gm (0.0075 mole) of 1 ,4-diphenyllbutadiene in 80 ml of toluene at 70 °C was add 9.9 ml of a 1.6 M solution of n-BuLi (0.0150 mole). The solution immediately darkened. The temperature was increased to bring the mixture to reflux and the mixture was maintained at that temperature for 2 hrs. The mixture was cooled to -20 °C and the volatiles were removed under reduced pressure. The residue was slurried in 60 ml of mixed hexanes at 20 °C for approximately 16 hours. The mixture was cooled to -25 °C for 1 h. The solids were collected on a glass frit by vacuum filtration and dried under reduced pressure. The dried solid was placed in a glass fiber thimble and solid extracted continuously with hexanes using a soxhlet extractor. After 6 h a crystalline solid was observed in the boiling pot. The mixture was cooled to -20 °C, isolated by filtration from the cold mixture and dried under reduced pressure to give 1.62 g of a dark crystalline solid. The filtrate was discarded. The solids in the extractor were stirred and the extraction continued with an additional quantity of mixed hexanes to • give an additional 0.46 gm of the desired product as a dark crystalline solid. Preparation of Cocatalyst E, (Bis(hydrogenated-tallowalkyl)methylamine Methylcyclohexane (1200 mL) was placed in a 2L cylindrical flask. While stirring, bis(hydrogenated-tallowalkyl)methylamine (ARMEEN ® M2HT, 104 g, ground to a granular form) was added to the flask and stirred until completely dissolved. Aqueous HCl (1M, 200 mL) was added to the flask, and the mixture was stirred for 30 minutes. A white precipitate formed immediately. At the end of this time, LiB(C 6 F 5 ) 4 • Et 2 0 • 3 LiCl (Mw = 887.3; 177.4 g) was added to the flask. The solution began to turn milky white. The flask was equipped with a 6" Vigreux column topped with a distillation apparatus and the mixture was heated (140 °C external wall temperature). A mixture of ether and methylcyclohexane was distilled from the flask. The two-phase solution was now only slightly hazy. The mixture was allowed to cool to room temperature, and the contents were placed in a 4 L separatory funnel. The aqueous layer was removed and discarded, and the organic layer was washed twice with H 2 0 and the aqueous layers again discarded. The H 2 0 saturated methylcyclohexane solutions were measured to contain 0.48 weight percent diethyl ether (Et 2 0). The solution (600 mL) was transferred into a 1 L flask, sparged thoroughly with nitrogen, and transferred into the drybox. The solution was passed through a column (1" diameter, 6" height) containing 13X molecular sieves. This reduced the level of Et 2 0 from 0.48 weight percent to 0.28 weight percent. The material was then stirred over fresh 13X sieves (20 g) for four hours. The Et 2 0 level was then measured to be 0.19 weight percent. The mixture was then stirred overnight, resulting in a further reduction in Et 2 0 level to approximately 40 ppm. The mixture was filtered using a funnel equipped with a glass frit having a pore size of 10-15 μm to give a clear solution (the molecular sieves were rinsed with additional dry methylcyclohexane). The concentration was measured by gravimetric analysis yielding a value of 16.7 weight percent. Polymerization ESI #'s 1 - 7 were prepared in a 6 gallon (22.7 L), oil jacketed, Autoclave continuously stirred tank reactor (CSTR). A magnetically coupled agitator with Lightning A-320 impellers provided the mixing. The reactor ran liquid full at 475 psig (3,275 kPa). Process flow was in at the bottom and out of the top. A heat transfer oil was circulated through the jacket of the reactor to remove some of the heat of reaction. At the exit of the reactor was a micromotion flow meter that measured flow and solution density. All lines on the exit of the reactor were traced with 50 psi (344.7 kPa) steam and insulated. Toluene solvent was supplied to the reactor at 30 psig (207 kPa). The feed to the reactor was measured by a Micro-Motion mass flow meter. A variable speed diaphragm pump controlled the feed rate. At the discharge of the solvent pump, a side stream was taken to provide flush flows for the catalyst injection line (1 lb/hr (0.45 kg/hr)) and the reactor agitator (0.75 lb/hr ( 0.34 kg/ hr)). These flows were measured by differential pressure flow meters and controlled by manual adjustment of micro- flow needle valves. Uninhibited styrene monomer was supplied to the reactor at 30 psig (207 kpa). The feed to the reactor was measured by a Micro-Motion mass flow meter. A variable speed diaphragm pump controlled the feed rate. The styrene stream was mixed with the remaining solvent stream. Ethylene was supplied to the reactor at 600 psig (4,137 kPa). The ethylene stream was measured by a Micro-Motion mass flow meter just prior to the Research valve controlling flow. A Brooks flow meter/controller was used to deliver hydrogen into the ethylene stream at the outlet of the ethylene control valve. The ethylene/hydrogen mixture combines with the solvent/styrene stream at ambient temperature. The temperature of the solvent/monomer as it enters the reactor was dropped to ~5 °C by an exchanger with - 5°C glycol on the jacket. This stream entered the bottom of the reactor. The three component catalyst system and its solvent flush also entered the reactor at the bottom but through a different port than the monomer stream. Preparation of the catalyst components took place in an inert atmosphere glove box. The diluted components were put in nitrogen padded cylinders and charged to the catalyst run tanks in the process area. From these run tanks the catalyst was pressured up with piston pumps and the flow was measured with Micro-Motion mass flow meters. These streams combine with each other and the catalyst flush solvent just prior to entry through a single injection line into the reactor. Polymerization was stopped with the addition of catalyst kill (water mixed with solvent) into the reactor product line after the micromotion flow meter measuring the solution density. Other polymer additives can be added with the catalyst kill. A static mixer in the line provided dispersion of the catalyst kill and additives in the reactor effluent stream. This stream next entered post reactor heaters that provide additional energy for the solvent removal flash. This flash occurred as the effluent exited the post reactor heater and the pressure was dropped from 475 psig (3,275 kPa) down to ~250mm of pressure absolute at the reactor pressure control valve. This flashed polymer entered a hot oil jacketed devolatilizer. Approximately 85 percent of the volatiles were removed from the polymer in the devolatilizer. The volatiles exited the top of the devolatilizer. The stream was condensed with a glycol jacketed exchanger and entered the suction of a vacuum pump and was discharged to a glycol jacket solvent and styrene/ethylene separation vessel. Solvent and styrene were removed from the bottom of the vessel and ethylene from the top. The ethylene stream was measured with a Micro-Motion mass flow meter and analyzed for composition. The measurement of vented ethylene plus a calculation of the dissolved gasses in the solvent/styrene stream were used to calculate the ethylene conversion. The polymer separated in the devolatilizer was pumped out with a gear pump to a ZSK-30 devolatilizing vacuum extruder. The dry polymer exits the extruder as a single strand. This strand was cooled as it was pulled through a water bath. The excess water was blown from the strand with air and the strand was chopped into pellets with a strand chopper. The various catalysts, co-catalysts and process conditions used to prepare the various individual ethylene styrene inteφolymers (ESI #'s 1 - 7) are summarized in Table 1 and their properties are summarized in Table 2. Table 1. Preparation Conditions for ESI #'s 1 - 7 *N/A = not available a Catalyst A is dιmethyl[N-(l l-dιmethylethyl)-l,l-dιmethyl-l-[(l,2,3,4,5-η)-l,5,6,7-tetrahydro-3-phenyl-s-mdacen-l- yl]sιlanammato(2-)-N]- titanium b Catalyst B is ,(lH-cyclopenta[l]phenanthrene-2-yl)dιmethyl(t-butylamιdo)-sιlanetιtanιum 1,4-dιphenylbutadιene) c Catalyst C is (t-butylamιdo)dιmethyl(tetramethylcyclopentadιenyI)sιlane-tιtanιum (II) 1,3-pentadiene prepared as described in U S Patent * 5,556,928, Example 17 d Cocatalyst D is tπs(pentafluorophenyl)borane, (CAS# 001109-15-5), e Cocatalyst E is bis-hydrogenated tallowalkyl methylammonium tetrakis (pentafluorophenyl)borate f a modified methylaluminoxane commercially available from Akzo Nobel as MMAO-3A (CAS# 146905-79-5) Table 2. Properties of ESI #'s 1 - 7. Example 1 A sample ESI 2 containing 38.4 mol percent styrene (69.8 weight percent) and having a Gottfert melt index (G#) of 0.9 cm7l0 min was fabricated into film using a 1.25 inch extruder with a 12/6/6 24:1 L/D screw operating at a melt temperature of 415°F. The die was 3" in diameter with a 60 mil die gap. (the extrusion conditions are summarized in Table 3) The resulting film of approximately 1.5 - 2.0 mil thickness was submitted for force relaxation testing as a measure of dead-fold properties as described herein. The results are summarized m Table 4 and demonstrate the desired percent force relaxation of greater than 40 percent in the MD or CD or both. Example 2 A sample ESI 3 containing 43.6 mol percent styrene (74.6 weight percent) and having a Gottfert melt index (G#) of 1.3 cm7l 0 min was fabricated into film and tested as for Example 1. The results are summarized in Table 4 and demonstrate the desired percent force relaxation of greater than 40 percent in the MD or CD or both. Example 3 A sample ESI 7 containing 43.1 mol percent styrene (73.7 weight percent) and having a Gottfert melt index (G#) of 2.4 cm 3 / 10 min was fabricated into film and tested as for Example 1. The results are summarized in Table 4 and demonstrate the desired percent force relaxation of greater than 40 percent in the MD or CD or both. Comparative Experiment 1. A sample ESI 1 containing 15.4 mol percent styrene (40.3 weight percent) and having a Gottfert melt index (G#) of 1.4 cm7l0 min was fabricated into film and tested as for Example 1. The results are summarized in Table 4 and do not demonstrate the desired percent force relaxation of greater than 40 percent in the MD or CD or both. Comparative Experiment 2. A sample ESI 4 containing 10.5 mol percent styrene (30.3 weight percent) and having a Gottfert melt index (G#) of 1.6 cmVlO min was fabricated into film and tested as for Example 1. The results are summarized in Table 4 and do not demonstrate the desired percent force relaxation of greater than 40 percent in the MD or CD or both. Comparative Experiment 3. A sample ESI 5 containing 26.2 mol percent styrene (56.9 weight percent) and having a Gottfert melt index (G#) of 1.2 cm7l 0 min was fabricated into film and tested as for Example 1. The results are summarized in Table 4 and do not demonstrate the desired percent force relaxation of greater than 40 percent in the MD or CD or both. Comparative Experiment 4. A sample ESI 6 containing 17.2 mol percent styrene (43.6 weight percent) and having a Gottfert melt index (G#) of 1.0 cm7l0 min was fabricated into film and tested as for Example 1. The results are summarized in Table 4 and do not demonstrate the desired percent force relaxation of greater than 40 percent in the MD or CD or both. : Not applicable as zone was removed from extruder Test Methods Force relaxation MD (machine direction) sample dimension was 25 mm wide in CD (cross direction) and 127 mm long in MD. Sample was pulled on a tensile testing machine with a 50 mm gauge length setting at 250 mm/min to 100 percent. The sample was then held at that elongation for 30 seconds. The initial force and the force after 30 seconds are recorded. The sample was then unloaded at the same speed to the original 50 mm gauge length. The sample was then unloaded at the same speed to the original 50 mm gauge length. percent force relaxation is defined as: (average of five measurements is reported below) ((initial force at peak elongation - force at peak elongation after 30 sec) x lQQVimtial force at peak elongation In order to exhibit dead-fold behavior the material should have a percent force relaxation of greater than or equal to 40 percent the machine cross directions. Table 4. Force Relaxation as an Indication of Dead Fold Properties of Examples #'s 1 - 3 and Comparative Experiments 1 - 4 Examples 2 and 3 both show excellent dead-fold properties with high percent force relaxation in both the CD and MD due to their high styrene content. Example 1 also show good dead-fold properties with acceptable percent force relaxation in both the CD and MD. Comparative Examples 1 2, 3 and 4 all show poor dead-fold properties with low percent force relaxation in both the CD and MD due to their low styrene contents.

Claims: CLAIMS WHAT IS CLAIMED IS: L A film or sheet or extruded profile having at least one layer comprising; (A) at least one substantially random inteφolymer, which comprises; (1) polymer units derived from; (i) at least one vinyl aromatic monomer, or (ii) at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, or (iii) a combination of at least one aromatic vinyl monomer and at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, and (2) polymer units derived from at least one C 2 _ 20 α-olefin; and optionally (3) polymer units derived from one or more ethylenically unsaturated polymerizable monomers other than those of (1) and (2); or (B) a blend of Component A with at least one polymer other than that of Component A; and wherein said film or sheet or extruded profile has a force relaxation in the cross direction or machine direction or both of greater than or equal to 40 percent. 2. The film or sheet or extruded profile of Claim 1 wherein; (I) said substantially random inteφolymer, Component A, is present in an amount from 25 to 100 weight percent (based on the combined weights of Components A and said polymer other than that of Component A) and has an I 2 of 0.01 to 100 g/10 min and an M w /M n of 1.5 to 20, and comprises; (1) from 29 to 65 mol percent of polymer units derived from; (i) at least one vinyl aromatic monomer, or (ii) at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, or (iii) a combination of at least one aromatic vinyl monomer and at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, and (2) from 35 to 71 mol percent of polymer units derived from at least one C 2 . 20 α-olefin; and (3) from 0 to 20 mol percent of polymer units derived from one or more of said ethylenically unsaturated polymerizable monomers other than those derived from (1) and (2); and (II) said polymer other than that of Component A is present in an amount from 0 to 75 weight percent (based on the combined weights of Components A and said polymer other than that of Component A). film or sheet or extruded profile of Claim 1 wherein; (I) said substantially random inteφolymer Component (A) is present in an amount of 40 to 95 weight percent (based on the combined weights of Components A and said polymer other than that of Component A) and has an I 2 of 0.1 to 20 g/10 min and an M w /M n of 1.8 to 10; and comprises (1) from 33 to 65 mol percent of polymer units derived from; (i) said vinyl aromatic monomer represented by the following formula; Ar I (CH 2 ) n R 1 - C = C(R 2 ) 2 wherein R 1 is selected from the group of radicals consisting of hydrogen and alkyl radicals containing three carbons or less, and Ar is a phenyl group or a phenyl group substituted with from 1 to 5 substituents selected from the group consisting of halo, C -alkyl, and C M -haloalkyl, and n has a value from zero to 4; or (ii) said aliphatic or cycloaliphatic vinyl or vinylidene monomer is represented by the following general formula; A 1 I R 1 — C = C(R 2 ) 2 wherein A 1 is a sterically bulky, aliphatic or cycloaliphatic substituent of up to 20 carbons, R 1 is selected from the group of radicals consisting of hydrogen and alkyl radicals containing from 1 to 4 carbon atoms,; each R 2 is independently selected from the group of radicals consisting of hydrogen and alkyl radicals containing from 1 to 4 carbon atoms, 1; or alternatively R 1 and A 1 together form a ring system; and (2) from 35 to 67 mol percent of polymer units derived from said α- olefin which comprises ethylene, or ethylene and at least one of propylene, 4-methyl- 1 -pentene, butene- 1 , hexene- 1 or octene- 1 ; and (3) said ethylenically unsaturated polymerizable monomers other than those derived from (1) and (2) comprises norbornene, or a C 0 alkyl or C 6 . 10 aryl substituted norbornene; aid polymer other than that of Component A is present in amount from 5 to 60 weight percent (based on the combined weights of Components A and said polymer other than that of Component A) and comprises one or more of a) a homogeneous inteφolymer, b) a heterogeneous inteφolymer; c) a thermoplastic olefin, d) a styrenic block copolymer, e) a styrenic homo- or copolymer, f) an elastomer, g) a vinyl halide polymer, or h) an engineering thermoplastic. or sheet or extruded profile of Claim 1 wherein; said substantially random inteφolymer, Component (A), is present in an amount from 50 to 95 weight percent (based on the combined weights of Components A and said polymer other than that of Component A) and has an I 2 of 0.1 to 5 g/10 min and an M ^ /M,, from 2 to 5; and comprises (1) from 35 to 65 mol percent of polymer units derived from; i) said vinyl aromatic monomer which comprises styrene, α-methyl styrene, ortho-, meta-, and para-methylstyrene, and the ring halogenated styrenes, or ii) said aliphatic or cycloaliphatic vinyl or vinylidene monomers which comprises 5-ethylidene-2-norbornene or 1-vinylcyclo- hexene, 3-vinylcyclo-hexene, and 4-vinylcyclohexene; (2) from 35 to 65 mol percent of polymer units derived from said α- olefin, which comprises ethylene, or ethylene and at least one of propylene, 4-mefhyl- 1 -pentene, butene- 1 , hexene- 1 or octene- 1 ; and (3) said ethylenically unsaturated polymerizable monomers other than those derived from (1) and (2) is norbornene; said polymer other than that of Component A is present in amount from 5 to 50 weight percent (based on the combined weights of Components A and said polymer other than that of Component A) and comprises one or more of; a) a substantially linear ethylene/α-olefin inteφolymer; b) a heterogeneous ethylene/C 3 -C 8 α-olefin inteφolymer; c) an ethylene/propylene rubber (EPM), ethylene/propylene diene monomer teφolymer (EPDM) , isotactic polypropylene; d) a styrene/ethylene-butene copolymer, a styrene/ethylene- propylene copolymer, a styrene/ethylene-butene/styrene (SEBS) copolymer, a styrene/ethylene-propylene/styrene (SEPS) copolymer, e) the acrylonitrile-butadiene-styrene (ABS) polymers, styrene-acrylonitrile (SAN), polystyrene, high impact polystyrene, f) polyisoprene, polybutadiene, natural rubbers, ethylene/propylene rubbers, ethylene/propylene diene (EPDM) rubbers, styrene/butadiene rubbers, thermoplastic polyurethanes, g) homopolymers or copolymers of vinyl chloride or vinylidene chloride, h) poly (methylmethacry late), polyester,nylon-6, nylon-6,6, poly(acetal); poly(amide), poly(arylate), poly(carbonate), poly(butylene) and polybutylene, polyethylene terephthalates. 5. The film or sheet or extruded profile of Claim 4 wherein Component Al(i) is styrene, Component A2 is ethylene, and said polymer other than that of Component A is polystyrene. 6. The film or sheet or extruded profile of Claim 4 wherein Component Al(i) is styrene; and Component A2 is ethylene and at least one of propylene, 4-methyl-l - pentene, butene-1 , hexene-1 or octene-1 ; and said polymer other than that of Component A is polystyrene. 7. A fabricated article comprising the film or sheet or extruded profile of Claim 1. 8. A fabricated article comprising the film or sheet or extruded profile of Claim 5. 9. A fabricated article comprising the film or sheet or extruded profile of Claim 6. 10. The fabricated article of Claims 7 - 9 in the form of a meat over- wrap, paper replacement, stand-up or flat bottomed bag, table cloth, shower curtain, collapsible bottles or container, toothpaste tube, fold-down structure, box, carton, window box, surgical drape, formable membrane, toy, tubing, clothing, tape, laminating film, or a pressure sensitive label. 11. A multilayer film or sheet or extruded profile comprising at least two layers wherein at least one of said layers is a film or sheet or extruded profile having a force relaxation in the cross direction or machine direction, or both of greater than or equal to 40 percent, comprising; (A) at least one substantially random inteφolymer, which comprises; (1) polymer units derived from; (i) at least one vinyl aromatic monomer, or (ii) at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, or (iii) a combination of at least one aromatic vinyl monomer and at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, and (2) polymer units derived from at least one C 2 . 20 α-olefin; and (3) polymer units derived from one or more ethylenically unsaturated polymerizable monomers other than those of (1) and (2); or (B) a blend of Component A with at least one polymer other than that of Component A. 12. The multilayer film or sheet or extruded profile of Claim 11 wherein; (I) said substantially random inteφolymer, Component A, is present in an amount from 25 to 100 weight percent (based on the combined weights of Components A and B) and has an I 2 of 0.01 to 100 g/10 min and an M w /M n of 1.5 to 20, and comprises; (1) from 29 to 65 mol percent of polymer units derived from; (i) at least one vinyl aromatic monomer, or (ii) at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, or (iii) a combination of at least one aromatic vinyl monomer and at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, and (2) from 35 to 71 mol percent of polymer units derived from at least one C 2 . 20 α-olefin; and (3) from 0 to 20 mol percent of polymer units derived from one or more of said ethylenically unsaturated polymerizable monomers other than those derived from (1) and (2); and (II) said polymer other than that of Component A is present in an amount from 0 to 75 weight percent (based on the combined weights of Components A and said polymer other than that of Component A) of at least one polymer other than that of Component A. 13. The multilayer film or sheet or extruded profile of Claim 11 wherein; (I) said substantially random inteφolymer Component (A) is present in an amount of 40 to 95 weight percent (based on the combined weights of Components A and B) and has an I 2 of 0.1 to 20 g/10 min and an MJM_ of 1.8 to 10; and comprises (1) from 33 to 65 mol percent of polymer units derived from; (i) said vinyl aromatic monomer represented by the following formula; Ar I (CH 2 ) n R i — C = C(R 2 ) 2 wherein R 1 is selected from the group of radicals consisting of hydrogen and alkyl radicals containing three carbons or less, and Ar is a phenyl group or a phenyl group substituted with from 1 to 5 substituents selected from the group consisting of halo, C -alkyl, and C -haloalkyl, and n has a value from zero to 4; or (ii) said aliphatic or cycloaliphatic vinyl or vinylidene monomer is represented by the following general formula; A' I Rl - C = C(R 2 ) 2 wherein A 1 is a sterically bulky, aliphatic or cycloaliphatic substituent of up to 20 carbons, R ! is selected from the group of radicals consisting of hydrogen and alkyl radicals containing from 1 to 4 carbon atoms,; each R 2 is independently selected from the group of radicals consisting of hydrogen and alkyl radicals containing from 1 to 4 carbon atoms,; or alternatively R 1 and A 1 together form a ring system; and (2) from 35 to 67 mol percent of polymer units derived from said α- olefin which comprises ethylene, or ethylene and at least one of propylene, 4-methyl- 1 -pentene, butene- 1 , hexene- 1 or octene- 1 ; and (3) said ethylenically unsaturated polymerizable monomers other than those derived from (1) and (2) comprises norbornene, or a C M0 alkyl or C 6 . 10 aryl substituted norbornene; II) said polymer other than that of Component A is present in amount from 5 to 60 weight percent (based on the combined weights of Components A and said polymer other than that of Component A) and comprises one or more of a) a homogeneous inteφolymer, b) a heterogeneous inteφolymer; c) a thermoplastic olefin, d) a styrenic block copolymer, e) a styrenic homo- or copolymer, f) an elastomer, g) a vinyl halide polymer, or h) an engineering thermoplastic. 14. The multilayer film or sheet or extruded profile of Claim 11 wherein; (I) said substantially random inteφolymer, Component (A), is present in an amount from 50 to 95 weight percent (based on the combined weights of Components A and said polymer other than that of Component A) and has an I 2 of 0.1 to 5 g/10 min and an M w /M n from 2 to 5; and comprises (1) from 35 to 65 mol percent of polymer units derived from; i) said vinyl aromatic monomer which comprises styrene, α- methyl styrene, ortho-, meta-, and para-methylstyrene, and the ring halogenated styrenes, or ii) said aliphatic or cycloaliphatic vinyl or vinylidene monomers which comprises 5-ethylidene-2 -norbornene or 1-vinylcyclo-hexene, 3-vinylcyclo-hexene, and 4- vinylcyclohexene; (2) from 35 to 65 mol percent of polymer units derived from said α- olefin, which comprises ethylene, or ethylene and at least one of propylene, 4-methyl- 1 -pentene, butene- 1 , hexene- 1 or octene- 1 ; or (3) said ethylenically unsaturated polymerizable monomer other than those derived from (1) and (2) is norbornene; said polymer other than that of Component A is present in amount from 5 to 50 weight percent (based on the combined weights of Components A and said polymer other than that of Component A) and comprises one or more of; a) a substantially linear ethylene/α-olefin inteφolymer; b) a heterogeneous ethylene/C 3 -C 8 α-olefin inteφolymer; c) an ethylene/propylene rubber (EPM), ethylene/propylene diene monomer teφolymer (EPDM) , isotactic polypropylene; d) a styrene/ethylene-butene copolymer, a styrene/ethylene- propylene copolymer, a styrene/ethylene-butene/styrene (SEBS) copolymer, a styrene/ethylene-propylene/styrene (SEPS) copolymer, e) the acrylonitrile-butadiene-styrene (ABS) polymers, styrene-acrylonitrile (SAN), polystyrene, high impact polystyrene, f) polyisoprene, polybutadiene, natural rubbers, ethylene/propylene rubbers, ethylene/propylene diene (EPDM) rubbers, styrene/butadiene rubbers, thermoplastic polyurethanes, g) homopolymers or copolymers of vinyl chloride or vinylidene chloride, h) poly(methylmethacrylate), polyester,nylon-6, nylon-6,6, poly(acetal); poly(amide), poly(arylate), poly(carbonate), poly(butylene) and polybutylene, polyethylene terephthalates. 15. The multilayer film or sheet or extruded profile of Claim 14 wherein Component (Ali) is styrene, Component (A2) is ethylene, and said polymer other than that of Component A is polystyrene. 16. The multilayer film or sheet or extruded profile of Claim 14 wherein Component Al(i) is styrene; and Component A2 is ethylene and at least one of propylene, 4- methyl- 1 -pentene, butene- 1 , hexene- 1 or octene- 1 ; and said polymer other than that of Component A is polystyrene. 17. A fabricated article comprising the multilayer film or sheet or extruded profile of Claim 11. 18. A fabricated article comprising the multilayer film or sheet or extruded profile of Claim 15. 19. A fabricated article comprising the multilayer film or sheet or extruded profile of Claim 16. 20. The fabricated article of Claims 17 - 19 in the form of a meat over- wrap, paper replacement, stand-up or flat bottomed bag, table cloth, shower curtain, collapsible bottles or container, toothpaste tube, fold-down structure, box, carton, window box, surgical drape, formable membrane, toy, tubing, clothing, tape, laminating film, or a pressure sensitive label. 21. The film or sheet or extruded profile of Claim 1 further comprising a filler. 22. The multilayer film or sheet or extruded profile of Claim 11 further comprising a filler. 23. The film or sheet or extruded profile of Claim 1 wherein Component A is cross- linked. 24. The multilayer film or sheet or extruded profile of Claim 11 wherein Component A is cross-linked.

Inventors: CHEUNG YUNWA W, GUEST MARTIN J, VAN VOLKENBURGH WILLIAM R, CHEUNG, YUNWA, W., GUEST, MARTIN, J., VAN VOLKENBURGH, WILLIAM, R.
Applicants: CHEUNG YUNWA W, DOW CHEMICAL CO, GUEST MARTIN J, VOLKENBURGH WILLIAM R VAN, CHEUNG, YUNWA, W., GUEST, MARTIN, J., THE DOW CHEMICAL COMPANY, VAN VOLKENBURGH, WILLIAM, R.
Application year: 1999
Main classification: C08J5
IPC codes: B32B27, C08J5, C08L53, C08L101