A METHOD FOR UPGRADING WAXY FEEDS USING A CATALYST COMPRISING MIXED POWDERED DEWAXING CATALYST AND POWDERED ISOMERIZATION CATALYST FORMED INTO A DISCRETE PARTICLE

Abstract: It has been discovered that waxy feeds can be upgraded using a catalyst made by combining powdered dewaxing catalyst with powdered isomerization catalyst said mixture of powdered catalyst being formed into a discrete particle.

Description: - 1 - A METHOD FOR UPGRADING WAXY FEEDS USING A CATALYST COMPRISING MIXED POWDERED DEWAXING CATALYST AND POWDERED ISOMERIZATION CATALYST FORMED INTO A DISCRETE PARTICLE FIELD OF THE INVENTION This invention relates to the catalytic treatment of wax-containing feeds including slack wax, Fischer-Tropsch wax, waxy raffinates, waxy distillates and hydrocrackates to produce an upgraded liquid product, such as a lube oil product having improved pour point, viscosity, viscosity index, reduced sulfur and/or nitrogen content as compared to the waxy feeds. DESCRIPTION OF THE RELATED ART The isomerization of wax and waxy feeds to liquid products boiling in the lube oil boiling range and catalysts useful in such practice are well known in the literature. Preferred catalysts in general comprise noble Group VUI metals on halogenated refractory metal oxide support, e.g., platinum on fluorided alumina. Other useful catalysts can include noble Group VUI metals on refractory metal oxide support such as silica/alumina which has their acidity controlled by use of dopants such as yttria. Isomerization processes and catalysts used in such processes are disclosed and claimed in numerous patents, see USP 5,059,299; USP 5,158,671; USP 4,906,601; USP 4,959,337; USP 4,929,795; USP 4,900,707; USP 4,937,399; USP 4,919,786; USP 5,182,248; USP 4,943,672; USP 5,200,382; USP 4,992,159, USP 4,923,588, USP 5,294,926, USP 5,254,518. The search for new and different catalysts or catalyst systems which exhibit improved activity, selectivity or longevity, however, is a continuous ongoing exercise. - 2 - Catalytic dewaxing is also a process well documented in the literature, see for example, USP 5,135,638, USP 5,246,566, USP 5,282,958, USP 5,037,528, USP 4,975,177, USP 4,919,788, USP 4,911,821, USP 4,906,350, USP 4,696,732, USP 4,610,778, USP 4,717,465, USP 4,574,043, USP 4,556,477, USP 4,810,357. Isomerization of linear olefins using zeolites is also addressed in the literature, see, for example, USP 5,321,194, USP 5,237,121. U.S. Patent 4,141,859 teaches a novel reforming catalyst and process using such catalyst. Zeolites of controlled activity are mixed with reforming catalyst to yield a composite which is then used as part of a catalyst system including an additional component which is a conventional reforming catalyst. The composite comprises up to 25 wt% of a zeolite of controlled acidity and which may be cation exchanged to contain H, Pt, Pd, etc., in combination with not less than 75 wt% of a carrier material containing 0.01 to about 2 wt% platinum either alone or in combination with other metals and from 0.01 to about 3 wt% halide. The carrier material is preferably alumina. The composite can be prepared by pre-milling a conventional reforming catalyst and mixing it with the zeolite and ball milling the mixture then pelleting the mixture to the desired size. U.S. Patent 4,418,006 teaches a hydrocarbon conversion catalyst system comprising a mixture of a first catalyst containing a noble metal on a refractory inorganic oxide and a second catalyst containing a non-noble metal on a crystalline alumina silicate material dispersed in a high surface area, porous refractory inorganic oxide. The second catalyst can be prepared in any number of ways, one of which involves taking the zeolite which has been cation exchanged and pulverizing it to a powder and physically mixing it with finely divided powder of refractory inorganic oxide and pelleting the mixture and - 3 - impregnating the pellet with the non-noble metal component. The final system comprising the first catalyst and the second catalyst is then prepared. One method involves reducing the size of each particle, blending the reduced size particles and pelleting the blended mixture. U.S. Patent 4,302,358 teaches an improved reforming catalyst of improved activity comprising a first component containing a Group VIII noble metal deposed on a solid acidic support and a second component comprising rhenium or compound thereof deposit on a solid catalyst support. It is taught that there is a substantial activity increase by thoroughly and intimately blending finely-divided particles of the first and second components to provide a thoroughly blended composite and subsequently forming the blended composite into larger particles, in contrast to using only a particulate mixture of the first and second catalyst components. U.S. Patent 4,584,089 teaches a reforming catalyst comprising a two component mixture of thoroughly blended finely divided particles of a first component comprising a Group VQI noble metal on a support having acid catalyst sites and a second component comprising a crystalline borosilicate molecular sieve to produce a thoroughly blended components and forming said composite into particles. U.S. Patent 4,575,416 discloses a method for catalytically dewaxing a feedstock using a dewaxing catalyst which comprises a zeolite having a Constraint Index not less than 1, an acidic catalytic material selected from the group consisting of mordenite, TEA mordenite, dealuminzed Y, USY, REY, amorphous silica-alumina, chlorinate alumina, ZSM-4 and ZSM-20, and a hydrogenation component. SUMMARY OF THE INVENTION This invention relates to a method for upgrading hydrocracked feeds to produce lubricating oils which comprises: (a) contacting the hydrocracked feed under upgrading conditions of elevated temperature and pressure in the presence of hydrogen with a catalyst comprising a unitized powder pellet catalyst made by: (1) mixing powdered 10 member ring unidirectional pore inorganic oxide molecular sieve dewaxing catalyst with a powdered amorphous isomerization catalyst having an acidity of about 0.3 to about 2.5 wherein said acidity is determined by the ability of the isomerization catalyst to convert 2-methylpent-2-ene to 3- methylpent-2-ene and 4-methylpent-2-ene and is expressed as the mole ratio of 3-methylpent-2-ene and 4-methylpent-2-ene, (2) mixing the powdered materials together to form a homogeneous mass, (3) compressing/extruding the mass, and (4) pelleting the extruded/compressed mass. In another embodiment, the invention relates to a method for upgrading wax-containing feeds to produce lubricating oils which comprises: (a) solvent dewaxing the wax-containing feed under solvent dewaxing conditions to obtain a solvent dewaxed oil: and (b) contacting the solvent dewaxed oil from step (a) under upgrading conditions of elevated temperature and pressure in the presence of hydrogen with a catalyst comprising a unitized powder pellet catalyst made by: (1) mixing powdered 10 member ring unidirectional pore inorganic oxide molecular sieve dewaxing catalyst with a powdered amorphous isomerization catalyst having an acidity of about 0.3 to about 2.5 wherein said acidity is determined by the ability of the isomerization catalyst to convert 2-methylpent-2-ene to 3-methylpent-2-ene and 4- methylpent-2-ene and is expressed as the mole ratio of 3-methylpent- 2-ene and 4-methylpent-2-ene, (2) mixing the powdered materials together to form a homogeneous mass, (3) compressing/extruding the mass, and (4) pelleting the extruded/compressed mass. DESCRIPTION OF THE INVENTION The present invention is directed to a unitized mixed powder pellet catalyst and to a method for upgrading waxy feeds using the unitized mixed powder pellet catalyst. The term "unitized" as used here and in the claims means that each pellet is one made by mixing together powdered molecular sieve dewaxing catalyst(s) with powdered amorphous isomerization catalyst(s) and pelletizing the mixture to produce pellets each of which contain all of the powder components previously recited. - 6 - The unitized powder pellet catalyst has been found to produce superior results as compared to using individual catalysts corresponding to the separate components of the mixed powder unitized pellet catalyst. The unitized catalyst can be prepared by starting with individual finished catalysts, pulverizing and powdering such individual finished catalysts, mixing the powdered materials together to form a homogeneous mass, then compressing/extruding and pelleting thus producing the unitized pellet catalysts comprising a mixture of the individual, different, and distinct catalyst components. Pulverizing and powdering is to a consistency achievable using a mortar and pestle or other such conventional powdering means. Alternatively, individual finished catalysts can be pulverized and powdered, then the powdered materials can be mixed together, boehmite or pseudo boehmite powder can be added to the powder mix, the mix can then be compressed/extruded and pelleted and the pellet calcined to covert the boehmite/pseudo-boehmite into alumina resulting in the production of a physically strong, attrition resistant unitized pellet catalyst. The unitized pellet catalyst can be prepared from a wide variety of individual dewaxing and isomerization catalysts. The dewaxing catalyst is a 10 member ring unidirectional inorganic oxide molecular sieve having generally oval 1-D pores having a minor axis between about 4.2A and about 4.8A and a major axis between about 5.4A and about 7.0A as determined by X-ray crystallography. The molecular sieve is preferably impregnated with from 0.1 to 5 wt%, more preferably about 0.1 to 3 wt% of at least one Group VUI metal, preferably a noble Group VUI metal, most preferably platinum or palladium. While the effective pore size as discussed above is important to the practice of the invention, not all intermediate pore size molecular sieves having such effective pore sizes are advantageously usable in the practice of the present invention. Indeed, it is essential that the intermediate pore size molecular sieve catalysts used in the practice of the present invention have a very specific pore shape and size as measured by X-ray crystallography. First, the intracrystalline channels must be parallel and must not be interconnected. Such channels are conventionally referred to as 1-D diffusion types or more shortly as 1-D pores. The classification of intrazeolite channels as 1-D, 2-D and 3-D is set forth by R. M. Barrer in Zeolites, Science and Technology, edited by F. R. Rodrigues, L. O. Rolhnan and C. Naccache, NATO ASI Series, 1984 which classification is incorporated in its entirety by reference (see particularly page 75). The second essential criterion as mentioned above is that the pores must be generally oval in shape, by which is meant the pores must exhibit two unequal axes, referred to herein as a minor axis and a major axis. The term oval as used herein is not meant to require a specific oval or elliptical shape but rather to refer to the pores exhibiting two unequal axes. Thus, as previously stated the 1-D pores of the catalysts useful in the practice of the present invention must have a minor axis between about 4.2A and about 4.8A and a major axis between 5.4A and about 7.0A as determined by conventional X-ray crystallography measurements. Zeolites which are considered to be in this pore range include ZSM-5, ZSM-11, etc. Upon careful examination of the intermediate pore size - 8 - zeolites, however, it has been found that not all of them are efficient as a catalyst for isomerization of a parafEn-containing feedstock. The intermediate pore size zeolites forming part of the present invention are those which in addition to having the correct pore size are also unidirectional. Such 10 member ring, unidirectional zeolites include ZSM-22, ZSM-23, ZSM-35, ferrierite, ZSM-48, and clinoptilolite and materials isostructural with these as defined Atlas of Zeolite Structure types by S. M. Mier and D. H. Olson. Third Revised Edition 1992. The most preferred intermediate pore size silicoaluminophosphate molecular sieve for use in the process of the invention is SAPO-11. SAPO-11 comprises a molecular framework of corner-sharing (SiO 2 ) tetrahedra, (AlO 2 ) tetrahedra and (P0 2 ) tetrahedra. Another preferred molecular sieve is SAPO-41. The isomerization catalyst component can be any of the typical isomerization catalyst such as those comprising refractory metal oxide support base (e.g., alumina, silica-alumina, zirconia, titanium, etc.) on which has been deposited a catalytically active metal selected from the group consisting of Group VI B, Group VII B, Group VUI metals and mixtures thereof, preferably Group VUI, more preferably noble Group VEQ, most preferably Pt or Pd and optionally including a promoter or dopant such as halogen, phosphorus, boron, yttria, magnesia, etc. preferably halogen, yttria or magnesia, most preferably fluorine. The catalytically active metals are present in the range 0.1 to 5 wt%, preferably 0.1 to 3 wt%, more preferably 0.1 to 2 wt%, most preferably 0.1 to 1 wt . The promoters and dopants are used to control the acidity of the isomerization catalyst. Thus, when the isomerization catalyst employs a base- material such as alumina, acidity is imparted to the resultant catalyst by addition of a halogen, preferably fluorine. When a halogen is used, preferably fluorine, it is present in an amount in the range 0.1 to 10 wt%, preferably 0.1 to 3 wt%, more preferably 0.1 to 2 wt%, most preferably 0.5 to 1.5 wt%. Similarly, if silica-alumina is used as the base material, acidity can be controlled by adjusting the ratio of silica to alumina or by adding a dopant such as yttria or magnesia which reduces the acidity of the silica-alumina base material as taught on U.S. Patent 5,254,518 (Soled, McVicker, Gates, Miseo). As with the dewaxing catalyst composite, one or more isomerization catalysts can be pulverized and powdered, and mixed producing the second component of the unitized mixed pellet catalyst. The isomerization catalyst can also be the mixture of discrete particle pair catalysts described in U.S. Patent 5,565,086 which is incorporated herein by reference. That catalyst comprises a mixture of discrete particles of two catalysts having acidities in the range 0.3 to 2.3 wherein the catalysts of the catalyst pair have acidities differing by about 0.1 to about 0.9 wherein acidity is determined by the technique of McVicker-Kramer as described in "Hydride Transfer and Olefin Isomerization as Tools to Characterize Liquid and Solid Acids, Ace Chem Res 19, 1986, pg. 78-84. In general one of the catalysts is deemed to be a high acidity catalyst having an acidity as evidenced by having a 3-methylpent-2-ene to 4-methylpent-2-ene ratio in the range 1.1 to 2.3 whereas the other catalyst will be a low acidity catalyst as evidenced by having a 3 methylpent-2-ene to 4 methylpent-2-ene ratio in the range 0.3 to about 1.1. This method measures the ability of catalytic material to convert 2-methylpent-2-ene into 3-methylpent-2-ene and 4-methylpent-2-ene. More acidic materials will produce more 3-methylpent-2-ene (associated with structural rearrangement of a carbon atom on the carbon skeleton). The ratio of 3-methylpent-2-ene to 4-methypent-2-ene formed at 200°C is a convenient measure of acidity. Isomerization catalyst acidities as determined by the above - 10 - technique lies in the ratio region in the range of about 0.3 to about 2.5, preferably about 0.5 to about 2.0. Zeolitic dewaxing catalysts have acidities, as determined by the above technique which he in the ratio region in the range of about 2.5 to 3.0, preferably 2.6 to 2.8. For a number of catalysts, the acidity as determined by the McVicker/Kramer method, i.e., the ability to convert 2-methylpent-2-ene into 3-methylpent-2-ene and 4-methylpent-2-ene at 200°C, 2.4 w/h/w, 1.0 hour on feed wherein acidity is reported in terms of the mole ratio of 3-methylpent-2-ene to 4-methylpent-2-ene, has been correlated to the fluorine content of platinum on fluorided alumina catalyst and to the yttria content of platinum on yttria doped silica/alumina catalysts. This information is reported below. Acidity of 0.3% Pt on fluorided alumina at different fluorine levels: F Content (%) Aciditv (McVicker/Kramer 0.5 0.5 0.75 0.7 1.0 1.5 1.5 2.5 0.83 1.2 (interpolated) Acidity of 0.37 Pt on yttria doped silica/alumina initially comprising 25 wt% silica: Yttria Content (%) Acidity (McVicker/Kramer 4.0 0.85 9.0 0.7 In practicing the present invention the feed to be isomerized can be any wax or waxy containing feed such as slack wax, which is the wax recovered - 11 - from a petroleum hydrocarbon by either solvent or propane dewaxing and can contain entrained oil in an amount varying up to about 50%, preferably 35% oil, more preferably 25% oil, Fischer-Tropsch wax, which is a synthetic wax produced by the catalyzed reaction of CO and H 2 . Other wax-containing feeds which can be used include waxy distillates or waxy raffinates which can contain anywhere from 5 to 95% wax and hydrocrackates derived from hydrocracking petroleum feedstocks under hydrocracking conditions. Hydrocracking typically involves treating a feedstock with a hydrocracking catalyst at a temperature of 260 to 500°C, hydrogen pressure of 1000-3000 psig, LHSV of 0.1 to 5 and hydrogen treat gas rate of 1000-10,000 scf/B. Hydrocracking catalysts are acidic in nature and contain a hydrogenation function. Typical hydrocracking catalysts include silica-alumina and acidic zeolites. Should the practitioner so desire, the feed can be mildly solvent dewaxed (e.g., to a pour point of about 5°C or 0°C) prior to the upgrading process to recover valuable wax. Solvent dewaxing utilizes typical dewaxing solvents such as C 3 -C 6 ketones (e.g., methyl ethyl ketone, methyl isobutyl ketone and mixtures thereof), Cβ-Cio aromatic hydrocarbons (e.g., toluene), mixtures of ketones and aromatics (e.g., MEK toluene), autorefrigerative solvents such as liquefied, normally gaseous C 2 -C 4 hydrocarbons such as propane, propylene, butane, butylene and mixtures thereof, etc., at filter temperature of -25°C to - 30°C. The feed, still containing residual wax is then subjected to the upgrading process. Waxy feeds secured from natural petroleum sources contain quantities of sulfur and nitrogen compounds which are known to deactivate wax hydroisomerization catalysts. To prevent this deactivation it is preferred that the - 12 - feed contain no more than 10 ppm sulfur, preferably less than 2 ppm sulfur and no more than 2 ppm nitrogen, preferably less than 1 ppm nitrogen. To achieve these limits the feed is preferably hydrotreated to reduce the sulfur and nitrogen content. Hydrotreating can be conducted using any typical hydrotreating catalyst such as Ni/Mo on alumina, Co/Mo on alumina, Co/Ni/Mo on alumina, e.g., KF-840, KF-843, HDN-30, HDN-60, Criteria C-411, etc. Similarly, bulk catalysts comprising Ni/Mn/Mo or Cr/Ni/Mo sulfides as described in U.S. Patent 5,122,258 can be used. Hydrotreating is performed at temperatures in the range 280 to 400°C, preferably 340 to 380°C at pressures in the range 500 to 3000 psi, hydrogen treat gas rate in the range of 500 to 5000 SCF/bbl and a flow velocity in the range 0.1 to 5 LHSV, preferably 1 to 2 LHSV. The upgrading process is practiced at a temperature in the range 300 to 375°C, preferably 330 to 360°C, a pressure in the range 500 to 3000 psi, preferably 1000 to 1500 psi, a hydrogen treat gas rate in the range of 1000 to 10,000 SCF/bbl, preferably 1000 to 3000 SCF/bbl and a flow velocity of 0.1 to 10 LHSV, preferably 0.5 to 2 LHSV. In both the hydrotreating and upgrading steps, the hydrogen used can be either pure or plant hydrogen (~50-100% H2). Following upgrading the total liquid product is fractionated into a lubes cut and fuels cut, the lubes cut being characterized as having a kinematic - 13 - viscosity of about 2.5 cSt and higher, at 100°C, preferably about 3.0 cSt and higher at 100°C, most preferably about 4 cSt and higher at 100°C. Preferably it has been found that the total liquid product (TLP) from the upgrading process can be advantageously treated in a second stage at mild conditions using isomerization catalyst or simply noble Group VQI on refractory metal oxide catalyst to reduce PNA and other contaminants in the upgraded product and thus yield an oil of improved daylight stability. The total liquid product is passed over a charge of hydrotreating catalyst, isomerization catalyst or over just noble Gp VIQ on, e.g., transition alumina. The conditions used include a temperature in the range of about 170-270°C, preferably about 180°C to 220°C, at pressures of about 300 to 2500 psi H 2 , preferably 500 to 1500 psi H 2 , a hydrogen gas rate of about 500 to 10,000 SCF/bbl, preferably 1000 to 5000 SCF/bbl and a flow velocity of about 0.25 to 10 v/v/hr, preferably about 1-4 v/v/hr. Temperatures at the high end of the range should be employed only when similarly employing pressures at the high end of their recited range. Temperatures in excess of those recited may be employed if pressures in excess of 1500 psi are used, but such high pressures may not be practical or economic. A variation of the procedures is covered in USP 5,158,671. The total liquid product is treated under these conditions in a separate, dedicated unit. It has been found to be unnecessary to fractionate the first stage product prior to this mild second stage treatment. Subjecting the whole product to this mild second stage treatment produces an oil product which upon subsequent fractionation and dewaxing yields a base oil exhibiting a high level of daylight stability and oxidation stability. These base oils can be subjected to subsequent hydrofinishing using conventional catalysts such as KF-840 - 14 - or HDN-30 (e.g., Co/Mo or Ni/Mo on alumina) at conventional conditions to remove undesirable process impurities to further improve product quality. The unitized pellet catalyst can contain the individual powdered components which make it up in a broad ratio. Thus, the components can be present in the ratio in the range 1: 100 or more to 100 or more: 1, preferably 1 :3 to 3:1. Theta-1 (TON) is a 10 ring, unidirectional silica alumina zeolite for which isotypic framework structures include: ZSM-22, NU-10, ISI-1, and KZ-2. This catalyst possesses excellent catalytic dewaxing potential with high wax content oils and is known to be highly active. The isomerization catalyst 0.3% Pt/l%F/Al 2 θ 3 is a mildly acidic, highly active isomerization catalyst for producing high VI base oils from slack wax and waxy raffinates. It was reasoned that a mixture of these two catalysts would produce a low wax content (low pour) and high VI base oil. EXAMPLE 1 A 600N waxy raffinate was hydrotreated over a C-411 hydrotreating catalyst then stripped to remove H 2 S and ammonia. C-411 is a commercial hydrotreating catalyst from Criterion. It is a 1/20" trilobe catalyst containing 2.6% wt% Ni and 14.3% wt% Mo on an alumina base. Its physical properties as quoted in the product bulletin are: surface area = 165 m 2 /g, pore volume = 0.43 cc/g, bulk crush strength = 12.7 kg/cm 2 and attrition index = 98+ wt%. - 15 - The hydrotreated feed following stripping was then sent to units containing either a mixed or stacked bed of discrete particles (25% of a 0.25% Pd loaded TON/75% of a 0.3% Pt/1% F/A1 2 0 3 isom catalyst and wherein in the case of the stacked bed the particles of TON were on top of the isom catalyst component) or a bed of unitized mixed powder pellet catalyst made by blending 25% powdered 0.25 Pd TON with 75% powdered 0.3% Pt/1% F-Al 2 O 3 and pelleting the resulting blended powder. The TON has a silica alumina ratio of about 60: 1. In all three cases the effluent from these units was then sent to a second reactor loaded with 0.3% Pt/1% F-Al 2 O 3 and run at 200°C as a stabilization step (in accordance with USP 5,158,671). All reactors were run in up-flow mode. In all cases the catalysts were crushed and sieved to collect the 7-14 mesh (Tyler) fraction. The units employed 64 g (100 cc) of the 7-14 mesh particles. The catalysts were activated using the following procedure: 1. Hydrogen flow at 0.6 f^/h (approximately 0.6 SCF/h per 100 cc) at 2.4 MPa (350 psig). No liquid flow. 2. Heat at 8°C/h to 200°C. 3. Hold 24 h. 4. Increase pressure to 4.5 MPa (650 psig) and increase hydrogen rate to 1.6 ft 3 /h. 5. Increase reactor temperature to 400°C at 8°C/h and hold 400°C for 4 h. 6. Cool to SOR operating temperature (330°C). - 16 - 7. Introduce feed (hydrotreated 600NR) at 330°C. The feed was hydrotreated over C-411 at 370°C, 0.7/hour LHSV, 1000 psig and 1500 SCF/bbl pure hydrogen treat gas rate. Hydrotreated feed was then introduced into the isomerization unit where the conditions initially were 330°C, 1.0/hour LHSV, 1000 psig total pressure and 2500 SCF/bbl pure hydrogen treat gas rate. The temperature was then increased stepwise to 340°C and 360°C, all other operating conditions being held constant. The total liquid product from the isomerization unit was fractionated by modified Hivac (Topping) to produce a 370°C cut (lubes cut) which was analyzed for pour point. The results obtained in this Example are presented in Tables 1A, IB, and lC. The Tables show that the product obtained using the unitized pellet catalyst (having a VI of 106) is of lower pour point (-29 to < -46°C) as compared to the product obtained using a mixed bed of Pd TON pellet catalyst and 0.3% Pt/1%F-Al 2 0 3 pellet catalyst (having a VI of 111 and a pour point of -4 to -11°C) or a stacked bed of discrete pellets (VI- 110-114 and a pour point of -2 to -7°C) at equivalent reactor temperatures. TABLE 1A o Blended Powders and Pelleted 4-- 600N 25% Pd TON, 25% Pd TON, 25% Pd TON, © CATALYST Raffinate Hvdrotreatment 75% ISOM Cat 75% ISOM Cat 75% ISOM Cat Temperature, °C 370 330 340 360 Pressure, psi 1000 1000 1000 1000 LHSV 0.75 1 1 1 sclTbbl 2500 2500 2500 2500 Knockout Liquid Yield on Feed 9.55 8.72 8.17 Bottoms Liquid Yield on Feed 99 87 83.8 76.6 370°C+ Topped Yield on Bottoms 100 95.1 84.4 82.3 71.9 370°C- Fuels 0 4.9 15.6 17.7 28.1 I— 1 DryWax, wt% 23.7 26.9 0 0 0 Overall DWO Yield on Feed 76.30 68.82 69.83 65.59 52.38 Topped to 370°C yes no (stripped) yes yes yes R. I. @ 75°C Density ® 15°C 0.8815 0.867 H. A. Sulfur, wppm 4700 2.2 1.3 < 1 Antek N, wppm 89 < 1 < 1 < 1 < 2 FLS Sats, wt% 69.57 94.2 92.25 86.62 FLS Aromatics, wt% 30.43 5.8 7.75 13.38 Viscosity cSt @ 40°C 70.11 66.83 53.61 Viscosity cSt @ 100°C 10.889 8.065 9.157 8.852 7.642 VI 106 106 106 n 1 tZ) o o ^-1 TABLE 1A (continued) Blended Powders and Pelleted 600N 25% Pd TON, 25% Pd TON, 25% Pd TON, l © CATALYST Raffinate Hvdrotreatment 75% ISOM Cat 75% ISOM Cat 75% ISOM Cat % C 86.6 % H 13.4 Pour Point, °C 52 53 -29 -33 < -46 DSC Wax, wt% 28.9 Noack Volatility (GCD, wt%) 1.8 9.2 6.2 6.5 9.9 IBP, 0 C 391 250 342 344 331 5% of-; °c 444 350 392 390 373 50% off, °C 506 494 490 488 477 95% off, °C 576 567 564 563 555 oo FBP, °C 616 605 611 611 603 Topped to 370°C yes yes H. A. Sulfiir, wppm 5800 5.1 Antek N, wppm 114 < 1 Viscosity, cSt @ 40°C 128.802 76.27 Viscosity, cSt @ 100°C 12.863 9.658 VI 91.6 105 Pour Point, °C -23 -24 Noack Volatility (GCD, wt%) 1.9 5.3 IBP 387 343 5% off 442 399 "T5 n 50% off 504 494 55% off 574 564 in yo FBP 609 602 y o © " t_j © TABLE IB Stacked Beds I 600N 25% Pd TON, 25% Pd TON, 25% Pd TON, CATALYST Raffinate Hydrotreatment 75% ISOM Cat 75% ISOM Cat 75% ISOM Cat Temperature, °C 395 330 340.5 360.4 Pressure, psi 1000 1000 1000 1000 LHSV 0.75 1 1 1 scfi bl 2500 2500 2500 2500 Knockout Liquid Yield on Feed 0.00 0.85 1.41 Bottoms Liquid Yield on Feed 99 89 83.2 77.8 370°C+ Topped Yield on Bottoms 100 96.0 85 82.9 73.5 370°C- Fuels 0 5 15 17.1 26.5 DryWax, wt% 23.7 26.30 Overall DWO Yield on Feed 76.30 60.78 71.34 65.04 53.92 Topped to 370°C yes no (stripped) yes yes yes R. I. @ 75°C 1.4551 Density @ 15°C 0.8815 0.8668 H. A. Sulfur, wppm 4700 3.2 Antek N, wppm 89 0.5 FLS Sats, wt% 69.57 85.6 FLS Aromatics, wt% 30.43 14.4 Viscosity cSt @ 40°C 66.46 62.56 49.39 Viscosity cSt @ 100°C 10.889 8.003 8.974 8.622 7.464 VI 110 110 114 n T3. % C 86.6 85.82 % H 13.4 14.18 © © ^1 TABLE IB (continued) Stacked Beds 600N 25% Pd TON, 25% Pd TON, 25% Pd TON, <A © CATALYST Raffinate Hydrotreatment 75% ISOM Cat 75% ISOM Cat 75% ISOM Cat Pour Point, °C 52 -2 -3 -7 DSC Wax, wt% 28.9 38.3 Noack Volatility (GCD, wt%) 1.9 9 5.8 6.5 9.6 mp, °c 391 235 345.6 341.6 329 5% off, °C 444 350.5 394.3 389.2 372.7 50% off, °C 506 494.5 491.1 488.2 478 95% off, °C 576 566.6 564.1 561.9 554.1 mp, °c 616 605.3 602.4 601.2 592.7 Topped to 370°C yes no (stripped) to O H. A. Sulfiir, wppm 5600 Antek N, wppm 114 FLS Sats, wt% 63.25 FLS Aromatics, wt% 36.75 Viscosity, cSt @ 40°C 128.802 66.803 Viscosity, cSt @ 100°C 12.863 8.59 VI 91.6 106 Pour Point, °C -23 -23 Noack Volatility (GCD, wt%) 1.9 9.9 IBP 387 265.3 5% off 442 347.4 O 50% off 504 490.9 H 95% off 574 563.6 FBP 609 600.5 VO © I*) —> TABLE IC V© Mixed Pellets 600N 25% Pd TON, 25% Pd TON, 25% Pd TON, © CATALYST Raffinate Hydrotreatment 75% ISOM Cat 75% ISOM Cat 75% ISOM Cat Temperature, °C 370 330 340 360 Pressure, psi 1000 1000 1000 1000 LHSV 0.7 1 1 1 sc-Tbbl 1500 2500 2500 2500 370°C+ Topped Yield on Bottoms 100 83.9 84.9 73.7 370°C- Fuels 0 16.1 15.1 26.3 Dry Wax, wt% 23.7 7.69 8.50 2.61 Overall DWO Yield on Feed 76.30 Topped to 370°C yes no (stripped) yes yes yes R. I. @ 75°C Density @ 15°C 0.9815 0.9651 H. A. Sulfur, wppm 4700 < 1 Antek N, wppm 89 0.5 FLS Sats, wt% 69.57 FLS Aromatics, wt% 30.43 Viscosity cSt @ 40°C 63 53.7 Viscosity cSt @ 100°C 10.989 7.797 8.696 7.816 VI 111 111 % C 86.6 85.99 % H 13.4 14.01 o Pour Point, °C 52 55 -4 -3 -11 DSC Wax, wt% 28.9 37.34 © IA TABLE IC (continued) yo >© Mixed Pellets 600N 25% Pd TON, 25% Pd TON, 25% Pd TON, t o*» CATALYST Raffinate Hydrotreatment 75% ISOM Cat 75% ISOM Cat 75% ISOM Cat Noack Volatility (GCD, wt%) 1.9 9.4 IBP, 0 C 391 269.4 5% off, °C 444 352 50% off, °C 506 491.8 95% off, °C 576 564.6 FBP, °C 616 602.3 Topped to 370°C yes yes yes yes H. A. Sulfur, wppm 5600 < 3.2 6.2 < 3.3 t Antek N, wppm 114 < 1.6 < 1.6 < 1.7 to FLS Sats, wt% 63.25 93.1 91.64 89.47 FLS Aromatics, wt% 36.75 6.9 8.36 10.53 Viscosity, cSt @ 40°C 128.802 66.3 65.651 53.951 Viscosity, cSt @ 100°C 12.863 8.857 8.813 7.763 VI 91.6 107.1 107.4 108.6 Pour Point, °C -23 -23 -25 -30 DSC Wax, wt% 17.51 17.05 13.55 NMRH, wt% 13.92 13.81 13.94 Noack Volatility (GCD, wt%) 1.9 6.2 6.4 8.8 IBP 387 346 346 339 5% off 442 391 390 377 o 50% off 504 489 477 479 95% off 574 561 560 555 v© FBP 609 600 600 597 v© © © -4 - 23 - Example 2 The same 600N raffinate of Example 1 was subjected to hydro- treatment over a C-411 hydrotreating catalyst then, following stripping to remove H2S and ammonia was fed to a unit loaded only with palladium loaded TON catalyst pellets (0.25 wt% Pd) operated under a range of conditions. The conditions of operations and the results of the runs are presented in Table 2 below. TABLE 2 v© v© 0.25% 0.25% 0.25% CATALYST 600N C-411 Pd TON Pd TON Pd TON © Temperature, °C 370 300.3 330.6 360.5 Pressure, psi 1000 1000 1000 1000 LHSV 0.74 1.01 1.05 1.01 scfibbl 2368 2460 2342 2369 Knockout Liquid Yield on Feed 3.57 3.89 7.14 Bottoms Liquid Yield on Feed 100.4 92.30 81.6 73.3 370°C+ Topped Yield on Bottoms 100 93.4 83.1 82 81 18 19 370°C- Fuels 0 16.6 16.9 Dry Wax, wt% 23.7 20.1 t Overall DWO Yield on Feed 76.30 74.93 77.01 67.18 59.61 4>- Topped to 370°C yes no (stripped) yes yes yes R. I. @ 75°C 1.4545 Density @ 15°C 0.8815 0.865 H. A. Sulfur, wppm 4700 1.9 1.1 0.8 0.6 Antek N, wppm 89 0.5 0.5 0.5 0.5 FLS Sats, wt% 69.57 85.46 91.7 90.01 89.71 FLS Aromatics, wt% 30.43 14.54 8.3 9.99 10.29 Viscosity cSt @ 40°C 68 64.88 63.59 Viscosity cSt @ 100°C 10.889 7.61 9.188 8.837 8.734 VI 111 110 110 % c 86.6 86.06 85.94 86.09 85.95 n % H 13.4 13.92 14.06 13.91 14.05 H Pour Point, °C 52 55 -1 -4 -6 (73 v© DSC Wax, wt% 28.9 © © TABLE 2 (continued) y o v© 0.25% 0.25% 0.25% CATALYST 600N C-411 Pd TON Pd TON Pd TON © Noack Volatility (GCD, wt%) 1.8 10.9 5.4 5.9 6.2 BP, °C 391 250.6 344.6 344.4 345.8 5% off, °C 444 332.5 397.1 393.6 390.8 50% off, °C 506 491.9 493.3 489.6 490 95% off, °C 576 565.9 565.9 561.9 563 FBP, °C 616 604.5 605.2 598.3 601.4 Solvent DWO Topped to 370°C yes yes H. A. Sulfur, wppm 5600 t Antek N, wppm 114 FLS Sats, wt% 63.25 81.8 FLS Aromatics, wt% 366.75 18.2 Viscosity, cSt @ 40°C 128.802 66.39 Viscosity, cSt @ 100°C 12.863 9.068 VI 91.6 112 Pour Point, °C -23 -8 Noack Volatility (GCD, wt%) 1.9 IBP 387 5% off 442 50% off 504 95% off 574 n FBP 609 >© © © - 26 - EXAMPLE 3 The same 600N raffinate of Example 1 was subjected to hydro- treatment over a C-411 hydrotreating catalyst, then stripped to remove H2S and ammonia and the stripped product was fed to a unit containing unitized blended powder pellets catalyst comprising 25% of a 0.25 wt% Pd on ZSM-5/75% of a 0.3 wt% Pt, 1% F/Al 2 O 3 . The ZSM-5 had a silica/alumina ratio of about 64: 1. The conditions and results are reported in Table 3 below: TABLE 3 25% Pd ZSM5 v© v© Feed to HO7 25% Pd ZSM5 75% RFT-10 iA CATALYST 600N Raffinate Feed to HO6 75% RTF-10 (Blended Powders) © Temperature, °C 370 270.1 299.8 Pressure, psi 1000 1000 1000 LHSV 0.73 1 1.02 scf/bbl 2438 2497 2447 Knockout Liquid Yield on Feed 6.87 7.60 Bottoms Liquid Yield on Feed 100.5 91.9 83 370°C+ Topped Yield on Bottoms 100 95.6 85.2 84.5 370°C- Fuels 0 4.4 14.8 15.5 Dry Wax, wt% 23.7 24.27 to Overall DWO Yield on Feed 76.30 72.76 78.69 70.49 Topped to 370°C yes no (stripped) yes yes R. I. @ 75°C 1.4557 Density ® 15°C 0.8815 0.8682 H. A. Sulfur, wppm 4700 3.7 Antek N, wppm 89 0.5 FLS Sats, wt% 69.57 83.05 FLS Aromatics, wt% 30.43 16.95 Viscosity cSt @ 40°C 82.37 86.75 Viscosity cSt @ 100°C 10.889 8.325 10.1 10.16 VI 103 97 %c 86.6 o % H 13.4 H Pour Point, °C 52 -19 tΛ v© ^© DSC Wax, wt% 28.9 © Noack Volatility (GCD, wt%) 1.8 8.1 4.5 5.4 © ^1 TABLE 3 (continued) 25% Pd ZSM5 v© \© Feed to HO7 25% Pd ZSM5 75% RFT-10 CATALYST 600N Raffinate Feed to HO6 75% RTF-10 (Blended Powders) © IBP, 0 C 391 262.9 355.4 350.8 5% off, °C 444 363.9 406.3 397.6 50% off, °C 506 495.3 495.4 492.1 95% off, °C 576 566.6 566.3 564 FBP, °C 616 602.5 603.8 599.9 Mass Spec (ASTM D2786-71) 0-Ring Isoparaffins 30.7 31.3 1-Ring Cycloparaffins 14.2 21.5 2-Ring Cycloparaffins 12.8 17 t 3 -Ring Cycloparaffins 11.2 10.9 00 4-Ring Cycloparaffins 9.2 5.3 5 -Ring Cycloparaffins 2.5 1.7 6-Ring Cycloparaffins 2.7 0.6 Monoaromatics 16.8 11.8 DWO Code # DNZ-000428 DNZ-001176 Topped to 370°C yes yes H. A. Sulfur, wppm 5600 6.5 Antek N, wppm 114 0.5 FLS Sats, wt% 63.25 79.54 FLS Aromatics, wt% 36.75 20.46 Viscosity, cSt @ 40°C 128.802 79.49 O Viscosity, cSt @ 100°C 12.863 9.883 H VI 91.6 104 v© © IA © ^1 TABLE 3 (continued) 25% Pd ZSM5 ^© yo Feed to HO7 25% Pd ZSM5 75% RFT-10 CATALYST 600N Raffinate Feed to HO6 75% RTF-10 (Blended Powders) © Pour Point, °C -23 -18 DSC Wax, wt% NMRH, wt% Noack Volatility (GCD, wt%) 1.9 4.7 IBP 387 347.2 5% off 442 404.8 50% off 504 494.2 95% off 574 564 FBP 609 598.2 t Mass Spec (ASTM D2786-71) 0-Ring Isoparaffins 20.5 21.2 1-Ring Cycloparaffins 15.3 22.3 2-Ring Cycloparaffins 15 19.8 3 -Ring Cycloparaffins 13.2 12.8 4-Ring Cycloparaffins 10.6 6.7 5-Ring Cycloparaffins 2.5 2.8 6-Ring Cycloparaffins 2.7 1.4 Monoaromatics 20.2 13.1 O H © O -≤ © - 30 - From this it is seen that not all zeolites are appropriate for use in the present invention. The mixed powder pellet catalyst containing 25 wt% Pd/ZSM-5 produced a product of only 97 VI with a pour point of -19°C on a feed which if simply solvent dewaxed would have a VI of 104 and a pour point of -18. This is to be compared with the product produced using a mixed powder pellet catalyst containing 25 wt% Pd-TON (Example 1) which had a VI of 106 and a pour point of -46°C (on a feed which if simply solvent dewaxed would have a VI of 105 and a pour of -24°C) or even with the product produced in Example 2 using only Pd/TON (no isom catalyst component) which had a VI of 110 and a pour point of -6 on a feed which if simply solvent dewaxed would have a VI of 112 and a pour point of -8°C. ZSM-5 is an oval pore zeolite but is not unidirectional. This is to be compared with the structure of Theta-1 (TON or ZSM-22) which is a 10 member ring-unidirectional pore material wherein the pores are oval. EXAMPLE 4 A 250N raffinate was hydrotreated over a C-411 hydrotreating catalyst, stripped to remove H S and ammonia then fed to units containing either unitized mixed powder pellet catalyst comprising 25 wt% of 0.25% Pd-ZSM- 5/75 wt% of a 0.3% Pt/1.0% F/A1 2 0 3 catalyst or a 0.25% Pd on TON catalyst. The ZSM-5 had a silica/alumina ratio of about 64: 1. The conditions used and the results obtained are presented in Table 4, below. TABLE 4 25% Pd- 25% Pd- 25% Pd- Feed 250N 0.25% 0.25% 0.25% ZSM5, 75% ZSM5, 75% ZSM5, 75% © Raffinate C-411 Pd TON Pd TON Pd TON ISOM CAT ISOM CAT 75% ISOM ( Blended Powders/Pelleted ) Temperature, °C 370 300.5 330.4 360.3 300.3 280.2 269.2 Pressure, PSI 1000 1000 1000 1000 1000 1000 1000 LHSY 0.73 1 1.01 1.06 1.01 1.04 1.01 SCF/B 3149 2525 2491 2331 2461 2380 2412 Knockout Liquid Yield on Feed 5.84 5.54 7.81 13.32 9.57 6.05 Bottoms Liquid Yield on Feed 96.7 91.4 83.6 68.7 74.8 80.3 85.4 370°C+ Topped Yield on Bottoms 100 92.3 79.9 79.2 77.7 76.6 77.9 79 3 370°C- Fuels 0 7.7 20.1 20.8 22.3 23.2 22.1 20.7 Dry Wax, wt% 17.7 20.5 Overall DWO Yield on Feed 82.30 70.96 70.62 64.03 51.62 55.55 60.49 65.49 Topped to 370°C Yes No Yes Yes Yes Yes Yes Yes (Stripped) R.1. @ 75°C 1.4598 Density @ 15°C 0.8754 H.A. Sulfur, wppm 7200 1.6 0.6 0.7 0.5 0.5 0.5 0.5 Antek N, wppm 44 0.5 0.5 0.5 0.5 0.5 0.5 0.5 FLS Sats, wt% 71.8 87.8 87.6 89.34 91.54 93.48 92.55 91.91 FLS Aromatics, wt% 26.2 12.2 12.4 10.66 8.46 6.52 7.45 8.09 Viscosity, cSt @ 40°C 37.48 37.66 36.53 44.97 43.72 41.99 n Viscosity, cSt @ 100°C H 6.855 5.091 6.176 6.154 6.024 6.563 6.575 6.473 VI 112 110 109 95 CΛ 101 104 v© v© © © TABLE 4 (continued) o 25% Pd- 25% Pd- 25% Pd- Feed 250N 0.25% 0.25% 0.25% (A ZSM5, 75% ZSM5, 75% ZSM5, 75% Raffinate C-411 Pd TON Pd TON Pd TON ISOM CAT ISOM CAT 75% ISOM ( Blended Powders/Pelleted ) % c 86.28 85.82 86.06 85.82 % H 13.72 14.18 13.94 14.18 Pour Point, °C 38 -9 -14 -16 -49 -24 -17 DSC Wax, wt% 32.5 7.6 14.23 Noack Volatility (GCD, wt%) 6.2 17.2 10.5 10.5 11.4 10.6 10.2 IBP, 0 C 243.1 335.4 335.4 330.3 330.2 336.1 337.2 5% off, °C 311.9 378.7 378.9 373.9 371.2 378.3 380.7 ω 50% off, °C 449.3 451.7 452.3 450.7 448.4 451.4 452.2 to 95% off, °C 509.8 510 510.6 509.3 508.1 509.5 509.8 FBP, °C 545.5 541.4 542.4 541.3 539.8 540 540.4 DWO Code GGM-000513 DNZ-001153 Topped to 370°C Yes Yes H.A. Sulfur, wppm 8500 Antek N, wppm 47 FLS Sats, wt% 67.38 84.7 FLS Aromatics, wt% 32.62 15.3 Viscosity, cSt @ 40°C 50.38 35.28 Viscosity, cSt @ 100°C 7.154 5.987 VI 96 114 n **1 Pour Point, °C -16 -17 © © TABLE 4 (continued) o 25% Pd- 25% Pd- 25% Pd- Feed 250N 0.25% 0.25% 0.25% ZSM5, 75% ZSM5, 75% ZSM5, 75% © Raffinate C-411 Pd TON Pd TON Pd TON ISOM CAT ISOM CAT 75% ISOM ( Blended Powders/Pelleted ) DSC Wax, wt% NMRH, wt% Noack Volatility (GCD, wt%) 10.8 IBP 329.6 5% off 376.7 50% off 451.9 95% off 509.9 FBP 541.9 "0 O H CΛ O © © © - 34 - From this it is seen that using a unitized mixed powder pellet catalyst containing 25 wt% of a zeolite of the kind ZSM-5 produces a product of lower VI (VI #104 at equivalent pour point) as compared to the product obtained by practicing either solvent dewaxing (VI #114) or treatment using only 0.25% Pd-TON (VI #109). There is no advantage to using a mixed powder pellet catalyst wherein one of the components is of the type represented by ZSM-5, i.e., an oval pore zeolite which is not unidirectional. EXAMPLE 5 This example illustrates the advantage of catalytic dewaxing a hydrocrackate versus solvent dewaxing to the same pour point. The catalytic dewaxed products have higher VI' s and better low temperature properties than a solvent dewaxed product at the same pour point. The hydrocrackate has the following properties: Viscosity, cSt at 100°C, 3.808 Viscosity, cSt at 135°C, 2.28 SUS, cP at 100°F 177 Pour Point, °C 39 Boiling Range, 5/95, GCD,°C 325-503 The hydrocrackate was topped at 350°C to give a 350°C+ product which was solvent dewaxed using MIBK in a 3: 1 solvent to hydrocrackate ratio and a filter temperature of -21°C to make a dewaxed oil having the properties shown in Table 5. - 35 - TABLE 5 Product Properties Viscosity, cSt at 100°C 3.94 Viscosity, cSt at 40°C 18.56 SUS, cP at 100°F 98.5 VI 110 Pour Point, °C -18 Yield on TLP, wt% 75 Brookfield Viscosity, cP at -40°C >25000 The hydrocrackate was catalytically dewaxed over a 0.3 wt% Pd TON, silica-alumina (25:75wt wt, zeolite: silica-alumina) mixed powder composite catalyst under the conditions shown in Table 6 and to produce the products, after topping at 350°C, shown in Table 6. TABLE 6 Process Conditions Pressure, psig 1000 1000 TGR, scf B 2500 2500 Space Velocity, v/v/hr 1.0 1.0 Temperature, °C 314 329 Yield, wt% 74 65 Product Properties Viscosity, cSt at 100°C 3.75 3.706 Viscosity, cSt at 40°C 16.45 16.551 SUS, cP at 100°F 88.6 147.2 VI 117 110.0 Pour Point, °C -18 -44 Brookfield Viscosity, at -40°C 12540 9300 The dewaxed oils, both solvent dewaxed and the products from the catalytic dewaxer, were formulated as Automatic Transmission Fluids using a - 36 - Ford type ATF ad pack (22 wt% treat rate of ATF ad pack, 78 wt% dewaxed oil) and Brookfield Viscosities at -40°C measured. The Brookfield Viscosities for both feed and products are shown in Tables 5 and 6 respectively and show that catalytic dewaxed products give superior Brookfield Viscosities versus solvent dewaxing. EXAMPLE 6 This example illustrates the advantage of catalytic dewaxing a hydrocrackate dewaxed oil (DWO). The trim catalytic dewaxed products (solvent dewaxing followed by catalytic dewaxing) have much better low temperature properties than the corresponding solvent dewaxed products. The hydrocrackate dewaxed oil has the following properties: TABLE 7 Viscosity, cSt at 100°C 3.853 Viscosity, cSt at 40°C 18.006 SUS, cP at 100°F 99.3 VI 107 Pour Point, °C -22 Brookfield Viscosity 25050 This dewaxed oil was then catalytically dewaxed over a 0.5 wt% Pt TON (zeoliteVPt Silica-alumina (25:75wt/wt, zeolite: silica-alumina) mixed powder composite catalyst under the conditions shown in Table 8 and to produce the product, after fractionation at 350°C, shown in Table 8. - 37 TABLE 8 Process Conditions Pressure, psig 1000 TGR, scffbbl 2500 Space Velocity, v/v/hr 1.0 Temperature, °C 314 Yield, wt% 58 Product Properties Viscosity, cSt at 100°C 3.824 Viscosity, cSt at 40°C 17.712 SUS, cP at 100°F 94.6 VI 106 Pour Point, °C -36 Brookfield Viscosity, cP at -40°C 13920 The dewaxed oils, both feed and product from the catalytic dewaxer were formulated as Automatic Transmission Fluids using a Ford type ATF adpack (22 wt% treat rate of ATF ad pack, 78 wt% dewaxed oil) and Brookfield Viscosities at -40°C measured. The Brookfield Viscosities for both feed and products are shown in Tables 7 and 8 respectively, and illustrate that the trim dewaxed product has much better low temperature properties than the corresponding solvent dewaxed feed.

Claims: - 38 - CLAIMS: 1. A method for upgrading hydrocracked feeds to produce lubricating oils which comprises: (a) contacting the hydrocracked feed under upgrading conditions of elevated temperature and pressure in the presence of hydrogen with a catalyst comprising a unitized powder pellet catalyst made by: (1) mixing powdered 10 member ring unidirectional pore inorganic oxide molecular sieve dewaxing catalyst with a powdered amorphous isomerization catalyst having an acidity of about 0.3 to about 2.5 wherein said acidity is determined by the ability of the isomerization catalyst to convert 2-methylpent-2-ene to 3-methylpent-2-ene and 4-methylpent-2-ene and is expressed as the mole ratio of 3-methylpent-2-ene and 4-methylpent-2-ene, (2) mixing the powdered materials together to form a homogeneous mass, (3) compressing/extruding the mass, and (4) pelleting the extruded/compressed mass. 2. A method for upgrading wax-containing feeds to produce lubricating oils which comprises: (a) solvent dewaxing the wax-containing feed under solvent dewaxing conditions to obtain a solvent dewaxed oil: and - 39 - (b) contacting the solvent dewaxed oil from step (a) under upgrading conditions of elevated temperature and pressure in the presence of hydrogen with a catalyst comprising a unitized powder pellet catalyst made by: (1) mixing powdered 10 member ring unidirectional pore inorganic oxide molecular sieve dewaxing catalyst with a powdered amorphous isomerization catalyst having an acidity of about 0.3 to about 2.5 wherein said acidity is determined by the ability of the isomerization catalyst to convert 2-methylpent-2-ene to 3-methylpent-2-ene and 4-methylpent-2-ene and is expressed as the mole ratio of 3-methylpent-2-ene and 4-methylpent-2-ene, (2) mixing the powdered materials together to form a homogeneous mass, (3) compressing/extruding the mass, and (4) pelleting the extruded/compressed mass. 3. The method of claim 1 or 2 wherein the 10 member ring unidirectional pore inorganic oxide molecular sieve has generally oval 1-D pores having a minor axis between about 4.2 A and about 4.8 A and a major axis between about 5.4A and about 7.0A. 4. The method of claim 1 or 2 wherein the powdered molecular sieve and the powdered isomerization catalyst are mixed together and boehmite or pseudo boehmite is added to the mixture, the mixture is compressed/extruded - 40 - and pelleted and the pellets calcined to convert the boehmite/pseudo boehmite into alumina producing the catalyst pellets. 5. The method of claim 1 or 2 wherein the powdered molecular sieve dewaxing catalyst and the powdered isomerization catalyst are combined in a ratio of from 1:100 to 100:1. 6. The method of claim 1 or 2 wherein the inorganic oxide molecular sieve contains from 0.1 to 5 wt%, based on molecular sieve, of at least on Group VUI metal. 7. The method of claim 6 wherein the Group VIII metal is Pt or Pd. 8. The method of claim 1 or 2 wherein the inorganic oxide molecular sieve is selected from ZSM-22, ZSM-23, ZSM-35, ZSM-48, ferrierite, clinoptilolite and materials isostructural therewith, and SAPO-11. 9. The method of claim 1 or 2 wherein the isomerization catalyst comprises at least one catalytically active metal selected from Group VIB, VIIB and Group VIQ on a refractory metal oxide support base. 10. The method of claim 9 wherein the refractory metal oxide support base further includes a dopant selected from halogen, phosphorus, yttria and magnesia. 11. The method of claim 2 wherein the wax-containing feed is hydrotreated prior to being upgraded.

Inventors: BRANDES DEE ANN, CODY IAN ALFRED, FORD THOMAS JOHN, LINEK SANDARA JEAN ALWARD, MURPHY WILLIAM JOHN, ZINKIE DAVID NORMAN EDMUND, BRANDES, DEE, ANN, CODY, IAN, ALFRED, FORD, THOMAS, JOHN, LINEK, SANDARA, JEAN, (ALWARD), MURPHY, WILLIAM, JOHN, ZINKIE, DAVID, NORMAN, EDMUND
Applicants: EXXON RESEARCH ENGINEERING CO, EXXON RESEARCH AND ENGINEERING COMPANY
Application year: 1999
Main classification: C10G47
IPC codes: B01J29, B01J35, C10G45, C10G47, C10G65, C10G67