NEGATIVE THERMAL EXPANSION MATERIALS INCLUDING METHOD OF PREPARATION AND USES THEREFOR

Abstract: Negative thermal expansion materials, methods of preparation and uses therefor are disclosed. The materials are useful for negative thermal expansion substrates, such as those used for optical fiber gratings.

Description: NEGATIVE THERMAL EXPANSION MATERIALS INCLUDING METHOD OF PREPARATION AND USES THEREFOR This application claims priority to U.S. Application 60/086,053, filed on 5/19/98, the contents of which are herein incorporated by reference. FIELD OF THE INVENTION The invention pertains to negative thermal expansion materials, devices made therefrom, and methods of making the materials. More particularly, the present invention concerns compositions including zirconium phosphate tungstates, which can be used to make substrates for athermalized optical fiber reflective grating devices. BACKGROUND OF THE INVENTION Negative thermal expansion (contraction with increasing temperature) is an unusual and potentially useful property for a solid material, and very few crystalline materials possess strongly negative expansions over an extended temperature range. Materials that exhibit a negative expansion due to extensive microcrackmg, by virtue of a negative coefficient of thermal expansion ("CTE") along at least one crystallographic axis and a substantially different CTE along at least one other axis, include some lithium alummosilicates, "NZPs" (compounds with crystal structures similar to that of NaZr P3θι_2), and Ta2θ5~ θ3 compounds. On the other hand, materials having negative mean lattice expansions that do not require microcrackmg for negative bulk ceramic CTEs are even more limited, and include certain synthetic alkali-free zeolites having low aluminum contents, ZrW2θ8, Hf 2θ8, ZrV2-χPχθ7 (above about 100°C), and NbZrP3θ]_2 (an NZP type compound). Of the compounds that have negative mean lattice expansions, zeolite expansions from 25 to 100 C C are m the range -20xl0 ~7 °C -1 to -40xl0 -7 °C _1 , but have the disadvantages of oeing dependent upon the amount of adsorbed water in the zeolite, and their CTE curves can exhibit considerable hysteresis. The CTE of NbZrP3θi2 below 100°C is about -27xl0 -7 °C _1 , while that of ZrW2θ8 and Hf 2θ8 is about -90xl0 -7 °C _1 . Thus, Zr 2θ8 and Hf 2θ8 are presently unique as materials that display a CTE more negative than -40xl0 ~7 °C ~ 1 without microcrackmg. Martinek and Hummel { I 960 , J. Amer . Ceram . Soc . , 53 , 159-1 61 ) first reported the existence of Zr2P2WO 2 in their study of the phase relations in the Zrθ2~Wθ3-P2θ5 system at 1125 °C. An XRD powder pattern was presented for this new compound, which reportedly has a melting point above 1750 °C, although extensive volatilization occurs in air at 1600 °C. Synthesis of Zr2P2WOi2 was achieved by calcining a mixture of hydrous zirconium carbonate, tungstic acid, and mono-hydrogen ammonium phosphate . Tsvigunov and Sirot kin ( 1 990 , Russ . Jour , of Inorg. Chem . , 35 , 1 740) subsequently reported a more complete and precise powder XRD pattern for this compound, which they synthesized from a mixture of Zrθ2, WO3, and NH4H2PO4. Evans er al. ( 1995 , Jour . Solid Sta te Chem . , 120, 101 -104 ) have shown that the structure of Zr2P2 w Oi2 (also referred to as Zr2(W0 ) (Pθ4)2) 1Ξ comprised of Zrθ6 octahedra sharing corners with O4 and PO4 tetrahedra. Those workers report that dilatometnc and variable temperature X-ray diffractometry studies indicate that Zr2P2WO_2 exhibits a negative thermal expansion over a broad temperature range. More recently, Evans et al. ( 1991, Journal Sol id Sta te Chem . , 133 , 580-83) have reported that Zr 2 P 2 WOi 2 has a mean lattice CTE of about -SOxlO "70 ^ 1 . The Zr 2 P 2 WOι 2 bodies synthesized according to the methods reported in the above literature have porosities greater than about 25%, typically greater than 30%. Such high porosity bodies generally are not useful for industrial applications. Thus, it would be useful to provide a composition having a low, preferably a negative thermal expansion, comprised of Zr 2 P2WOι 2 , or analogues thereof which Hf is fully or partially substituted for Zr, having a porosity less than about 20%, preferably less than about 10%, and more preferably less than about 5%. Bodies having a highly negative CTE, such as -30 to - lOOxlO -7 °C-1 , can find use as substrates for athermal zation of fiber Bragg gratings (FBGs). In the latter application, a FBG is mounted in tension on the negative expansion substrate. Applications of FBGs include passive wavelength division multiplexing and filtering in dense WDM systems, as well as distributed fiber sensors for smart systems to monitor bridges, structures, and highways. For such applications, variation of the center wavelength of fiber Bragg gratings (FBGs) with respect to temperature, due to thermal expansion of the fiber and variation of the refractive index of the glass, must be minimized. For example, at a Bragg wavelength of 1550 nm, thermal variation of λ B is expected to be 0.012 nm/°C, whereas a value less than 0.002 nm/°C is desired. Variation in λ B with temperature can be reduced to well below 0.002 nm/°C by mounting the FBG in tension on a substrate having a negative thermal expansion of about -70 to -85xl0 "7 °C _1 within that range also -70 to -δOxlO ' ^C "1 , - 75 to -82xlO ~7 °C _1 . The reduction in tension with increasing temperature associated with the contraction of the substrate partially or entirely offsets the contribution to increased optical path length resulting from the thermal expansion and change in refractive index of the glass. β-eucryptite oaseα ceramics formed by controlled devitrification of sintered lithium alummosilicate glass are being studied as FBG suostrates and are disclosed in international patent application no. PCT/US/13062 , Beall et al., entitled, "Athermal Optical Device." The attainment of CTEs of - 1 0 to -85xl0 ~7 °C _1 in β-eucryptite bodies requires extensive microcracKing; an unmicrocracked β-eucryptite exhibits a CTE near -5xl0 ~ °C -1 . This microcrack g results from internal stresses associated with the large difference m CTE along the c and a axes of tne crystals (approximately -176 and +78xlO 7o C ~1 , respectively) , coupled with the coarse gram size of the crystals . United States patent no. 5,694,503, issued to Fleming et al., discloses using the negative coefficient of thermal expansion material ZrW 2 Oe to form substrates for temperature compensated fiber Bragg gratings. Since the coefficient of thermal expansion of ZrW 2 0 8 may be too negative to provide temperature compensation for Bragg gratings, the Fleming et al. patent suggests mixing Zr 2 0 8 witn a positive coefficient of thermal expansion material such as alumina, silica, zirconia, magnesia, calcia, or yttπa in an amount to raise the coefficient of thermal expansion. The mixtures of ZrW 2 0 8 with positive coefficient of thermal expansion materials suggested in the Fleming et al. patent, however, have several disadvantages. Large relative differences in the thermal expansion coefficients of ZrW 2 0 8 and the positive CTE materials can cause microcrackmg in the composite material upon heating and cooling of the material. Such microcrackmg can result in hysteresis in the thermal expansion curve or dimensional change of the body with changes in humidity, characteristics that are undesirable in a fiber Bragg grating substrate. Furthermore, many of the positive CTE components recommended in the Fleming et al. patent react with the ZrW 2 0 8 during sintering to form copious amounts of liquid. Such reactions and liquid formation tend to cause the body to slump αuring firing. Alternatively, some of the positive CTE components recommended in the Fleming et al. patent react with the ZrW 2 0 8 to form other high CTE crystalline phases so that the ceramic body does not have the desired strongly negative CTE after firing. In addition, ceramics comprised of ZrW 2 0 8 and Zr0 2 undergo a length change having an absolute value greater than 500 parts per million over 700 hours at 85% relative humidity and 85 °C, which is undesirably large. The presence of microcrackmg in a FBG substrate requires that the fiber/substrate package be hermetically sealed to prevent dimensional drift of the substrate due to opening and closing of the microcracks resulting from variations in humidity. Hermetic sealing adds significantly to the cost of the assembly, and the reliability of the device becomes dependent upon long-term reliability of the hermetic seal. Thus, it would be desirable to provide an unmicrocracked material having a porosity less than about 25%, preferably less than about 10% and more preferably less than about 5%. Further, there is a need for a body having a CTE of about -70xl0 "7 °C "1 to -85xl0 "7 °C _1 to provide temperature compensation for the gratings of current interest which could be used to make FBG substrates because hermetic sealing would not be required for long-term stability. In addition, it would be desirable to provide a material that has a length change having an absolute value less than 500 ppm over 700 hours at 85°C and 85% relative humidity. SUMMARY OF INVENTION The present invention provides a low-porosity body containing at least one phase having a negative thermal expansion, a method of making tne phase, and devices made from the phase. In one embodiment, the body is comprised of the compound Zr2P2 w °12 which exhibits a room- temperature CTE of about -40xl0 ~7 °C _1 , and a CTE from about 25 to 800°C of aoout -25xl0 ~7 °C _1 . Hafnium may be partially or entirely substituted for zirconium. The body further comprises a crystalline or non-crystalline oxide phase, which may include a glassy phase, which contains a metal selected from the group consisting of alkaline earth metals, alkali metals, manganese, iron, cobalt, copper, zinc, aluminum, gallium, and bismuth. The oxide phase may also contain one or more of the metals selected from the group zirconium, tungsten and phosphorous. In another embodiment, this invention comprises a ceramic body comprised of two negative CTE phases, preferably wherein at least one of the phases has a room temperature CTE more negative than -50xlO "7 C "1 . In an exemplary embodiment, one phase has the composition M 2 B 3 0ι 2 where M is selected from the group including aluminum, scandium, indium, yttrium, the lanthanide metals, zirconium, and hafnium, and where B is selected from the group consisting of tungsten, molybdenum, and phosphorus, and where M and B are selected such that the compound 2 B 3 0i2 has a negative CTE, and comprising a second phase of the composition AX 2 θ 8 , where A is selected from the group consisting of zirconium and hafnium, and X is selected from the group consisting of tungsten and molybdenum. For example, the ceramic body may comprise a mixture of ZrW 2 0 8 and Zr 2 P 2 WOι 2 , wherein hafnium may be partially or fully substituted for zirconium in Zr 2 P 2 W0 12 and ZrW0 8 . In a preferred embodiment, the ceramic body is unmicrocracked. The ceramic body may further include a crystalline or non-crystalline oxide phase, which may include a glassy phase, which contains a metal selected from the group consisting of alkaline earth metals, alkali metals, lanthanum group metals, niobium, titanium, manganese, iron, cobalt, nickel, copper, zinc, yttrium, scandium, aluminum, gallium, and bismuth. The oxide phase may also contain one or more of the metals selected from the group zirconium, tungsten and phosphorous. The invention also includes a method of making ceramic bodies of the present invention comprising mixing together powders of Zr 2 P 2 WOι 2 or precursor powders of Zr 2 P 2 WOι 2 or analogues of these powders which Hf is substituted for Zr, or mixtures thereof, and at least one oxide or oxide precursor of metals selected from the group consisting of alkaline earth metals, alkali metals, manganese, iron, cobalt, copper, zinc, aluminum, gallium, and bismuth. Another embodiment of this invention involves a method of raising and making the negative thermal expansion of a ceramic body less negative comprising a phase having a room temperature coefficient of thermal expansion more negative than -50xlO "7o C 1 comprising mixing together the first phase with at least a second phase or precursors of the first phase and at least the second phase, the second phase having a negative thermal expansion less negative than -50xlO "7 °C _1 . A body made according to this method preferably will not exhibit microcrackmg. Alternatively, the method includes forming a ceramic body comprising two negative CTE phases, preferably wherein the room temperature CTE of one of the phases is more negative than -50X10 ~7 C _1 and the other phase is less negative than -50X10 ~ 'C _1 , to provide a body having a CTE less negative tnan -50X10 "7 C ~ \ In an exemplary embodiment, one phase has the composition M 2 BO i2 where M is selected from the group including aluminum, scandium, indium, yttrium, the lanthanide metals, zirconium, and hafnium, and where B is selected from the group consisting of tungsten, molybdenum, and phosphorus, and where M and B are selected such that the compound M 2 B 3 0ι 2 has a negative CTE, and comprising a second phase of the composition AX 2 0 8 , where A is selected from the group consisting of zirconium and hafnium, and X is selected from the group consisting of tungsten and molybdenum. In another exemplary embodiment, the method comprises mixing ZrW 2 0 8 or precursors of ZrW 2 0 8 , or analogues of these materials in which Hf is substituted for Zr, with Zr 2 P 2 WOι 2 or precursor powders of Zr 2 P 2 W0χ2 or analogues of these powders in which Hf is substituted for Zr. Optionally, tnese may also be mixed with at least one oxide or oxide precursor of metals selected from the group consisting of alkaline earth metals, alkali metals, manganese, iron, cobalt, copper, zinc, aluminum, gallium, and bismuth. The mixed powders are consolidated together using a ceramic forming method and heated to sinter the ceramic body. Preferably, the heating occurs at a temperature of about 1050°C to 1300°C, more preferably 1120°C to 1230°C for about 1 minute to 10 hours. When the Zr 2 θ 8 phase is desired to oe present in the ceramic body, preferably heating occurs at a temperature of about 1150°C to 1230°C. Another aspect of the invention involves an optical device comprising a negative expansion substrate having a composition comprising two negative CTE phases, preferably wherein at least one of the phases has a room temperature CTE more negative than -50xlO "7o C _1 , and one of the phases has a thermal expansion less negative than -50xlO "7 °C 1 . For example, the substrate composition may comprise a mixture of ZrW 2 0 8 and Zr 2 P 2 Oι 2 . Hafnium may be partially or fully substituted for zirconium m Zr 2 P 2 W0 12 and ZrW 2 0 8 . In a preferred embodiment, the substrate is unmicrocracked. The substrate may further include a crystalline or non- crystalline oxide phase, which may include a glassy phase, which contains a metal selected from the group consisting of alkaline earth metals, alkali metals, lanthanum group metals, niobium, titanium, manganese, iron, cobalt, nickel, copper, zinc, yttrium, scandium, aluminum, gallium, and bismuth. The oxide phase may also contain one or more of the metals selected from the group zirconium, tungsten and phosphorous. The device further comprises a thermally sensitive, positive expansion optical component affixed to the substrate. In one embodiment, the optical component is an optical fiber grating and the substrate has a mean linear coefficient of thermal expansion of about -40xlO "7 °C _1 to -S 5xl O 'lo C l over a temperature range of about -40°C to 85°C. Another aspect of the invention relates to a negative expansion substrate having a composition comprising Zr2P2WOχ 2 and a crystalline or non-crystalline oxide phase, which may include a glassy phase, which contains a metal selected from the group consisting of alkaline earth metals, alkali metals, manganese, iron, cobalt, copper, zinc, aluminum, gallium, and bismuth. Hafnium may be fully or partially substituted for zirconium. The oxide phase may also contain one or more of the metals selected from the group zirconium, tungsten and phosphorous. Thus the present invention generally provides a novel ceramic body comprised of phase having a negative CTE, such as Zr2P2WOχ2 or Hf 2 P2WOι or mixtures thereof, which exhibits a negative coefficient of thermal expansion (CTE) at all temperatures from at least as low as 25 °C to at least as high as 500 °C. The mean CTE near room temperature is about -40xl0 -7 °C-^, while the mean CTE from 25 to 800°C is about -25xl0 -7 °C _1 . The Zr2P2WOi2 or Hf 2 P 2 WOi 2 phase is stable at all temperatures from at least as low as -50°C to at least as high as 1150°C. Also disclosed is a method for fabricating the sintered ceramic body which, in some embodiments, entails the addition of small amounts of additives which function as sintering aids to powders of Zr2P2 W0 12 or Hf 2 P2 Oι 2 or mixtures thereof or their precursors. These additives include the compounds of lithium, sodium, potassium, magnesium, calcium, barium, manganese, iron, copper, and zinc. Aluminum compounds may also be used as sintering aids, but are not as effective. Compounds of rubidium, cesium, and strontium would also likely be effective for densification. The present invention also includes a ceramic body comprised mainly of the phases ZrW 2 0 8 and Zr 2 P2 Oι 2 and their hafnium analogues and mixtures thereof, having a mean linear coefficient of thermal expansion of about -40 to -85xl0 ~7 °C _1 over the temperature range -40°C to +85°C. These bodies also exhibit a negative CTE to higher temperatures as well. Preferred embodiments of the invention nave less than 10% total porosity, especially less than 5% porosity. In one embodiment, achievement of low porosity is enhanced by the addition of small amounts (0.01 to 5.0 wt%) of certain sintering additives, such as the oxides or oxioe-form g compounds of alkali (group IA) metals, alkaline earth (group IIA) metals, manganese, iron, cobalt, nickel, copper, zmc, yttrium, scandium, lanthanide metals, niobium, titanium, aluminum, gallium, and bismuth. Many of these materials have the desirable properties of having excellent dimensional stability at 85 °C and 85% relative humidity and possessing no microcrackmg, and thus exhibit no hysteresis in their thermal expansion curves. Such ceramics are suitable as athermaiizing substrates for fiber Bragg gratings. Additional features and advantages of the invention will be set forth in the description which follows. It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are intended to provide further explanation of the invention as claimed. The accompanvmσ drawings are included to provide a further understanding of the invention and are incorporated in ano constitute a part of this specification, illustrate one embodiment of the invention and together with the description serve to explain the principles of the invention. In the drawings, like reference characters denote similar elements throughout the several views. It is to be understood that various elements of the drawings are not intended to be drawn to scale, but instead are sometimes purposely distorted for the purposes of illustrating the invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 shows the relationship of the dependence of the coefficient of thermal expansion at 25°C on the weight percent of Zr2P2WOi2 m a ceramic body comprised mamly of Zr2P2 Oχ2 and ZrW2θ8; FIG. 2 shows the dimensional change of sample bars of ZrW 2 0 8 with 15 weight percent Zr0 2 at 85°C and 85% relative humidity compared with the dimensional changes of inventive bodies under the same conditions; FIG. 3 is a schematic drawing of an embodiment of an athermal optical fiber grating device; FIG. 4 is a schematic drawing of an embodiment of an athermal optical fiber grating device; FIG. 5 is a schematic drawing an embodiment of an athermal optical fiber grating device; FIG. 6 is an enlarged view of the affixing channel shown in FIG. 5; FIG. 7 is a schematic drawing of an embodiment of an athermal fiber grating device; FIG. 8 is a schematic drawing of an embodiment of an athermal optical fiber fused coupler device; FIG. 9 is a schematic drawing of an embodiment of an athermal planar waveguide device; and FIG. 10 is a plot of center wavelength (nm) versus temperature (°C) of an embodiment of an athermal fiber Bragg grating device. DETAILED DESCRIPTION Reference will now be made m detail to the present preferred embodiment of the invention, an example of which is illustrated in the accompanying drawings. According to one embodiment of the present invention, small amounts of additives, which function as sintering aids, are mixed with Zr2P2 W0 12 powder or to a mixture of precursor compounds that can form Zr2P2 W0 12 by reaction. The precursors may include, for example, Zrθ2, Zr (NO3) 4 -xH2θ, ZrOCl2'xH2θ, Zr ( SO4 ) 2 • XH2O, WO3, H2Wθ4-xH2θ, P2O5, ZrP2θ7, Zr2P2θ9, Zr (HPO4 ) 2 * xH2θ, Zr 2θ8, NH4H2PO4, (NH4)2HP04, (NH4 ) 3PO4 • 3H20, phospho-tungstic acid, etc. Hafnium may be partially or fully substituted for zirconium. The mixtures may be dry mixed or blended using an appropriate organic or inorganic liquid medium. Water may be used when the precursors have low aqueous solubility. If mixed in a fluid medium, the precursors may also be milled by any of the methods known to the art (e.g., ball milling, attrition milling, vibratory milling, etc.) . When some or all of the precursors are soluble in water, they may be dissolved in water and subsequently coprecipitated to form an even more intimate mixture. The mixture may optionally be dried and calcined, followed Dy milling, or may be directly "green" formed into the desired shape. Organic binders such as a polyethylene glycol or methyl cellulose may optionally be added to provide strength to the green body. The body is then raised to and held at a temperature sufficient for densification to take place, such as at 1150 °C for 4 hours . In another aspect of the invention, ceramic bodies are comprised predominately of two materials having a negative CTE, such as ZrW 2 0 8 and Zr 2 P 2 WOι 2 or their hafnium analogues or mixtures thereof, and the bodies exhibit CTEs of -40 to -85xl0 "7 °C "1 between -40°C and +85°C. In one embodiment one of the materials has a room temperature CTE more negative than about -50xlO _7 °C "1 . Depending upon the ratio of the two negative CTE materials, it is possible to achieve these CTEs the body without microcrackmg. Ceramic bodies having negative CTEs within this range without relying upon microcrackmg have not previously been reported in the literature, and represent a unique invention. In a two-phase ceramic containing ZrW 2 0 8 , the second phase must either be in chemical equilibrium with ZrW 2 0 8 at the sintering temperature, or else reaction between the second phase and ZrW 2 0 8 must be sufficiently slow that most of the second phase is retained through the firing process. Also, to avoid microcrackmg, the difference between the CTEs of the two phases, ΔCTE, must be minimized (while still being sufficient to achieve the desired bulk CTE of about -70xl0 "7 °C "1 to -85xl0 "7 °C "1 ) , and the mean gram size of the components must be finer than some critical value whicn is dictated by the value of ΔCTE. The term "grain size" is meant to include either the size of a primary crystal, or the size of a cluster or aggregate of two or more adjacent crystals of the same phase . Addition of chemically compatible phases with positive CTEs, such as ZrSι0 4 , Zr0 2 , or W0 3 , to a ZrW 2 0 8 - based ceramic could be employed to create materials having expansions less negative than that of pure ZrW2θ 8 , however, the large disparity in CTE between the two components would result in microcrackmg unless the grains of the two phases were maintained at less than about 1 micron during sintering . The present invention involves the discovery of an alternative to prevent microcrackmg. Applicant has discovered that the combination of a material having a strongly negative CTE, for example, a first material such as ZrW0 8 having a room temperature CTE more negative than -50xlO " °C ~: , with a second phase whose CTE is also negative, but not as strongly negative as that of the first material, results in lower stresses from the CTE mismatch between the phases. Thus, the present invention provides a body that avoids microcrackmg for grain sizes less than about 15 microns, preferably less than about 10 microns. In an additional alternative embodiment, the gram sizes are greater than 1 micron. Applicant has recently measured the room temperature CTE of the compound Zr 2 P 2 WOι 2 to be about -40xlO ~7o C 1 . Applicant has discovered that because the CTE of this compound is not extremely different from that of ZrW 2 0 8 , a ceramic body containing both phases can exhibit a CTE of intermediate value without undergoing microcrackmg, provided that the gram size of the two components is less than about 10 microns. This restriction on gram size can easily be met for an appropriate choice of starting materials and sintering conditions. According to an exemplary embodiment of the present invention, powders of ZrW 2 0 8 and Zr 2 P 2 WOχ 2 , or precursors that form ZrW 2 0 8 and Zr 2 P 2 0 12 by reaction upon firing, or their hafnium analogues or mixtures thereof, are mixed together and formed into the desired shape by ceramic processes known in the art, e.g., dry pressing, injection molding, extrusion, slip casting, etc. Mixing may be performed on the dry powders, or the powders may be mixed with a liquid and may optionally be further reduced in particle size by ball milling, attrition milling, vibratory milling, etc. An organic binder may be added to the powders to increase handling strength in the green (pre-fired) state. Optionally, inorganic or organometallic compounds which serve as densification aids may also be added in small quantities to the mixture of starting materials. It has been found that oxides or oxide-formmg compounds of alkali (group IA) metals, alkaline earth (group IIA) metals, manganese, iron, cobalt, nickel, copper, zinc, yttrium, scandium, lanthanide metals, niobium, titanium, aluminum, gallium, and bismuth are especially effective at reducing porosity of the ceramic body during firing. The quantity of sintering aids is preferably the minimum amount required for densification, as it has been found that larger additions of such additives tend to produce large-scale cracking of the body during firing. The body may be placed upon a glass or ceramic setter pallet or m a partially enclosed container of a glass or ceramic material and heated to a maximum temperature of between about 1120 and 1230 °C, preferably between about 1150 to 1200 °C, and held for a period of time sufficient for reaction and sintering to take place, such as 1 minute to 10 hours. A glass or ceramic powder or "sand" may be placed oetween the body and the pallet to reduce drag during shrinkage of the body during firing. Zirconium oxide or zircon powder or silica powder or sand are especially preferred in this role. After holding at peak temperature, the body is rapidly cooled to a temperature below about 500°C in a few minutes to minimize decomposition of the ZrW 2 0 8 phase. ZrW 2 0 8 is unstable below about 1140°C, but decomposition proceeds only very slowly at temperatures less than about 800°C. The fired body may optionally undergo surface grinding or other machining if desired. The present invention is illustrated by the following non-limitmg examples. EXAMPLES 1 to 18 Examples 1-18 were prepared by mixing together powders of zirconium oxide, tungsten oxide, and acid zirconium phosphate, Zr (HP0 4 ) 2 -0.93H 2 0, m the proportions required to yield the compound Zr 2 P 2 WOι 2 after firing. Mixtures for Examples 2-18 also contained 1 weight percent addition of a metal oxide, or metal oxide forming source. Powders were mixed with a sufficient amount of isopropanol to form a slurry, and the slurry was milled in a vibratory mill for approximately sixteen hours using zirconium oxide milling media. The slurry was subsequently dried in a dish at about 85 °C, repulverized, and the powder pressed into 1.2 cm diameter, 0.4 cm thick pills, or 7.6 cm x 1.3 cm x 0.4 cm bars in a steel mold at a pressure of about 70 Mpa (10,000 pounds/mch 2 ) . The pills and bars were placed on coarse zirconium oxide sand in covered aluminum oxide setter boxes inside of an electrically heated furnace. Temperature of the furnace was raised at a rate of about 30 °C/hr to 350°C to allow volatilization of the water from the acid zirconium phosphate, then heated at a rate of about 100 to 200°C/hr to a maximum temperature of 1150°C. After holding at 1150°C for 4 hours, power to the furnace was shut off and the samples gradually cooled to room temperature . The fired bars were cut to a 5 cm length for measurement of thermal expansion. Porosity was measured by the Archimedes method, and phases present after firing were determined by powder x-ray diffractometry (XRD) . Coefficients of thermal expansion were measured by dilatometry . Example 1 shows that, in the absence of a sintering additive, the Zr 2 P 2 WOι 2 ceramic was poorly densified, containing about 32 percent porosity. The mean coefficient of thermal expansion (CTE) from 25 to 50°C was -32xlO "" °C "1 , and from 25 to 500°C was -30xl0 "7 °C _1 . This specimen consisted entirely of the desired Zr 2 P 2 WOι 2 phase. Examples 2-4 demonstrate that the addition of only 1% of the carbonates of the alkali (Group IA) metals is highly effective in promoting densification of the Zr 2 P 2 W0 12 ceramics. Samples contain essentially no open porosity, and total porosities are reduced to approximately 1-5%. Thermal expansions remain strongly negative at room temperature. XRD showed that these ceramic bodies contain mostly Zr 2 P 2 Oi 2 with minor amounts of LiZr 2 P 3 0 12 , NaZr 2 P 3 0χ 2 , and KZr 2 P 3 0 12 , in samples 2-4, respectively. These secondary phases are responsible for the somewhat less negative CTE from 25 to 500 °C for Examples 2 and 3. Examples 5-7 illustrate that the addition of only 1% of the oxides or carbonates of the alkaline earth (Group IIA) metals is also very effective in reducing the porosity of Zr 2 P2 0 12 ceramics. Total porosities are less than 3%, and there is virtually no open porosity. Fired bodies contained predominately Zr 2 P 2 WOi2. Example 5 contained a very minor amount of MgW0 4 , Example 6 contained very minor amounts of CaZr 4 P6θ 2 4 and CaW0 4 , and Example 7 had a very small amount of BaZr 4 P6θ 2 4. CTEs were very negative from 25 to 50°C (-27 to -35xl0 "7 °C ~1 ) and 25 to 500°C (-24 to -26xl0 ~7 "C "1 ) . Table 1 Experimental data for Zr 2 P 2 WOι 2 ceramics Measured on pills Measured on bars Mean Coef ficient of Thermal Expans ion ( 10 " > C ' ) Bulk Bulk Example Weight % Weight % Density % Open % Total Density t Open % Tc >tal Number Zr 2 P 2 W0 12 Additive Additive (g/cπr 1 ) Porosity Porosity (g/cm 3 ) Porosity Porosity -40 to + 85 C 25 to 50°C 25 to 500°C 1 100 0 none 2 71 28 5 30 5 2 65 31 1 32 1 -32 -30 2 99 1 Lι 2 C0 3 3 85 0 1 1 3 3 87 0 3 0 8 -25 -15 3 99 1 Na 2 C0 3 3 81 0 0 2 3 3 84 0 1 1 5 -27 -18 4 99 1 K 2 C0 3 3 69 0 4 5 4 3 70 0 5 5 1 - 39 -35 -27 5 99 1 MgO 3 B7 0 0 0 8 3 87 0 1 0 8 -35 -24 6 99 1 CaC0 3 3 72 0 3 4 6 3 81 0 2 2 3 -34 -26 -» 7 99 1 BaC0 3 3 82 0 1 2 1 3 82 0 2 2 1 -27 -24 8 99 1 MnC0 3 3 84 0 0 1 5 3 86 0 0 1 0 -35 -28 9 99 1 Fe 2 0 3 3 82 0 2 2 1 3 80 0 4 2 6 -29 -26 10 99 1 CuO 3 76 0 2 3 6 3 75 0 2 3 8 -36 -27 11 99 1 ZnO 3 87 0 0 0 8 3 88 0 1 0 5 - 39 -38 -26 12 99 1 A1 2 0 3 3 14 16 5 19 5 13 99 1 Tl0 2 2 59 31 4 33 6 14 99 1 NlO 2 47 37 1 36 7 15 99 1 Y,0 3 2 52 32 8 35 4 16 99 1 Sι0 2 2 36 37 8 39 5 17 99 1 SnO 2 66 29 6 31 8 18 99 1 Nb 2 0 5 2 59 33 7 33 6 Examples 8-11 show that the addition of only 1% of the oxides or carbonates of manganese, iron, copper, and zmc is highly effective in densifymg Zr 2 P 2 WOι 2 ceramics to less than 4% total porosity, with essentially no open porosity. Example 8 contained a trace of MnW0 4 , and Example 9 contained a very minor amount of an unidentified phase. Examples 10 and 11 exhibited only Zr 2 P 2 WOi 2 in their XRD patterns. All samples had highly negative CTEs of -29 to -SδxlO "70 ^ 1 from 25 to 50°C, and -26 to -28xl0 "7 °C _1 from 25 to 500°C. Example 12 demonstrates that aluminum oxide also serves to lower the porosity of Zr 2 P2 Oι 2 ceramics; however, total porosity is still about 20%. XRD indicated the presence only of Zr 2 P 2 WOι 2 . Thermal expansion was not measured. Examples 13-18 prove that not all oxides are effective as sintering aids for Zr 2 P2WOι 2 ceramics. Thus, the addition of 1% of the oxides of titanium, nickel, yttrium, silicon, tin, and niobium, for example, yield a ceramic body containing greater than 30% porosity. EXAMPLES 19 to 28 Powder preparation for Examples 19 and 21-28 was conducted m the same manner as Examples 1-18, with the proportions of the starting materials ad]usted to yield Zr 2 P2 Oi 2 and ZrW 2 0 8 m the ratios stated in Table 2. In these examples, the weight percentages of Zr 2 P 2 WOι 2 and ZrW 2 0 8 are relative to the sum of the weights of the Zr 2 P2 0 12 and ZrW 2 0 8 components only. Weight percent of additive is relative to total weight percent of starting material . Table 2 Experimental data for Zr 2 P 2 WOκ ceramics with various amounts of ZrW 2 O β Heating rate above Example Weight % eight I Weight ° Sample 900°C Soak Soak Number Zr-PjWOu ZrW 2 O e Additive Additive Geometry (°C/hr) Temperature Time 19 100 0 0 00 none 7 6 cm bar 200 1150 4 20 50 50 0 00 none 7 6 cm bar 100 1150 4 21 49 51 0 00 none 7 6 cm bar 200 1150 4 22 32 68 C 00 none 7 6 cm bar 100 1150 4 32 68 C 00 none 7 6 cm bar 100 1150 4 4 32 68 0 00 none 7 6 cm bar 25 1150 4 25 24 76 0 00 none 7 6 cm bar 200 1150 4 26 10 91 0 00 none 7 6 cm bar 200 1150 4 27 5 95 0 00 none 7 6 cm bar 200 1150 4 28 0 100 0 00 none 7 6 cm bar 200 1150 4 29 32 68 0 25 AlOOH 7 6 cm bar 100 1150 4 30 32 68 0 25 Tl0 2 7 6 cm bar 100 1150 4 32 68 0 25 Nb 2 0^ 7 6 cm bar 100 1150 4 32 32 68 0 25 Sι0 2 7 6 cm bar 100 1150 4 :3 32 68 0 C5 l 2 CO> 6 cm bar 100 1150 4 32 6b 0 10 " 6 cm bar 100 1150 4 35 32 68 0 05 Na 2 CO, 7 6 cm bar 100 1150 4 36 32 66 0 0 ^ Ha 2 CO, 7 6 cm bar 100 1150 4 37 32 68 0 25 KzCOj 7 6 cm bar 100 1150 4 38 32 68 0 25 K C0 3 7 6 cm bar 25 1150 4 39 32 68 0 05 K CO 6 cm bar 100 1150 4 4P 32 68 0 25 CaCO, 7 6 cm bar 100 1150 4 41 32 68 C 25 CaCO 7 D cm bar 25 1150 4 4 ° 32 68 0 05 CaC0 3 7 6 cm bar 100 1150 4 3 32 68 C 25 BaCO 7 6 cm bar 100 1150 4 44 32 68 0 2 = BaCO, 7 6 cm bar 25 1150 4 45 32 68 0 10 BaCO, 7 6 cm bar 100 1150 4 46 32 68 1 00 MgO 1 3 cm disc 100 1150 4 47 32 68 0 25 MgO 7 6 cm bar 100 1150 4 48 32 68 0 25 MσO 7 6 cm bar 25 1150 4 32 68 0 05 MgO 7 6 cm bar 100 1150 4 =0 32 68 . 00 CuO i 3 cm disc 100 1150 4 32 β8 CuO 7 6 cm bar 100 1150 4 52 32 68 0 05 CuO 7 6 cm bar 100 1150 4 53 32 68 1 00 ZnO 1 3 cm disc 100 1150 4 54 32 68 1 00 ZnO 7 6 cm bar 100 1150 4 55 32 68 0 25 ZnO 7 6 cm bar 100 1150 4 56 32 68 0 25 ZnO 7 6 cm bar 25 1150 4 57 32 68 0 10 ZnO 7 6 cm bar 100 1150 4 58 32 68 l 00 MnCOj 1 3 cm disc 100 1150 4 59 32 68 1 30 MnCO 7 6 cm bar lOO 1150 4 60 32 68 0 25 MnCO 7 6 cm bar 100 1150 4 61 32 68 0 25 MnCOi 7 6 cm bar 25 1150 4 c2 32 68 0 05 MnC0 3 7 6 cm bar 100 1150 4 63 32 68 1 00 Fe 2 0, 1 3 cm disc 100 1150 4 64 32 68 1 00 Fe,0 3 7 6 cm bar 100 1150 4 65 32 68 0 25 Fe 2 0 3 7 6 cm bar 100 1150 4 Table 2 (continued) Experimental data for Z 2 P 2 Oι 2 ceramics with various amounts of ZrW 2 Oe Heating rate above Example Weight % Weight % Weight % Sample 900°C Soak Soak Number Zr 2 P 2 WOi2 ZrW 2 0. Additive Additive Geometry (°C/hr) Temperature Time 32 68 0 50 Y 2 O 3 . 11 4 cm bar 100 1150 67 32 68 0 25 Y2O3 7 6 cm bar 100 1150 68 32 68 0 25 Ϊ.O3 11 4 cm bar 100 1150 69 32 68 0 . 25 Y2O3 11.4 cm bar 100 1150 70 32 68 0 12 Y 2 0 3 11.4 cm bar 100 1150 71 32 68 0 05 Ϊr0 3 li 4 cm bar 100 1150 72 32 68 0 05 Y 2 O 3 11 4 cm bar 100 1150 73 32 68 0 05 Y 2 O 3 11.4 cm bar 100 1150 74 25 75 0 05 Y-O, 1 4 cm bar 100 1150 75 25 75 0 05 Y,0 3 ^ 1 4 cm bar 450 1175 76 25 75 0 05 Y203 11 4 cm bar 450 1175 77 15 0 05 γ,o 3 11 4 cm bar 450 1175 78 10 0 05 Y 2 0 3 11 4 cm bar 450 1175 79 0 25 a 2 0 3 7 6 cm bar 100 1160 80 32 68 0 25 CeO, 7 6 cm bar 100 1160 81 32 68 0 25 M0O3 7 6 cm bar 100 1160 82 32 68 0 25 Bl 2 0 3 7 6 cm bar 100 1160 83 32 68 0 25 B 2 0 3 7 6 cm bar 100 1160 84 32 68 0 25 Ga 2 0 3 7 6 cm bar 100 1160 85 32 68 0 25 l n 2 0 3 7 6 cm Par 100 1160 86 32 68 0 25 SnO 7 6 cm bar 100 1160 87 32 68 0 25 Cr 2 0. 7 6 cm bar 100 1160 32 68 0 25 N iO 7 6 cm bar 100 1160 ♦Example 78 also contains 2% tungsten oxide as an additional phase Example 20 was prepared by precipitation from aqueous solutions of ZrOCl 2 -8H 2 0, NH 4 H 2 P0 4 , and H 2 W0 4 . According to this method, 79.18 grams of zirconyl chloride (previously assayed to be 2.739xl0 ~3 moles Zr per gram of salt) was dissolved m 161 grams of water to form the first solution. A second solution was formed by dissolving 16.63 grams of ammonium dihydrogen phosphate in 73 grams of water. A third solution was made by dissolving 54.19 grams of tungstic acid in 152 grams of water and 54 grams of 14.8 N ammonium hydroxide solution, and heating to 95 °C . The tungsten and phosphate solutions were mixed together and then added to the zirconium solution. More ammonium hydroxide was added to the mixture to deflocculate the suspension. The slurry was stirred and heated to 85°C until dry. The solid was then calcined at 900°C for 4 hours and subsequently crushed and vibratory milled in isopropanol for 14 hours with zirconia media. Mixed powders for Examples 19-28 were pressed into 7.6 cm long bars at 70 Mpa . Samples were set on zirconia sand in covered alumina boxes and fired at about 30 °C/hr to 350 °C, then heated at rate ranging from 25 °C/hr to 200 °C/hr to 1150°C and held at that temperature for 4 hours. After 4 hours, the alumina boxes were removed from the furnace and the samples immediately taken from the boxes and transferred to a zirconia sand-covered alumina pallet which was at room temperature. The rapid cooling of the samples prevented the decomposition of the metastable ZrW 2 0 8 phase into Zr0 2 + W0 3 below about 1140 °C . After firing, samples were inspected for appearance and, in some cases, further characterized for porosity, phase assemblage, and CTE. Properties of fired samples are reported in Table 3. Table 3 Experimental data for Zr P 2 WO ceramics with various amounts of ZrW 2 O β Mean Coefficient of Bulk Thermal Expansion (10 Example Densι > Theoretical % Total "C Number Appearance (g/cm ) Density Porosity -40 to +85°C Is "O cracks 2 47 3 90 36 7 -40 20 no cracks -61 * 21 no cracks 3 24 4 43 26 8 -66 * 22 no cracks -72 23 no cracks 3 12 4 63 32 a -72 24 no cracks 25 no cracts 3 66 4 74 22 7 -76 26 no cracts 4 03 4 94 18 4 -83 27 no cracks 4 27 5 01 ι4 7 -85 28 no cracts 4 43 5 08 12 8 -90 2 C no crao ^ 4 42 4 63 4 6 -7ι * 30 4 06 4 63 12 3 -73 3 no c r ac s 4 -3 4 3 -80 ,2 o crao n2 4 0 -~S -> = ~attereα dιι c 4 07 < ■ 63 !<- 4 3n 4 c^ 35 "o crac) s 1 81 4 o 1^ 8 36 "O crαO a 3 16 4 63 31 8 37 extreme v cacke •. 38 4 c 7 5 4 38 highly evaded 39 nc cracks 1 81 4 63 ,7 7 40 °xtreneιy clacked 4 49 4 63 41 oytre ei cracked 42 n o cracrs 4 30 4 63 43 very fe cracks 4 54 4 63 2 0 -70 44 scattered cracks 45 no craOs 4 45 4 63 3 9 -72 4c „ιumpeα 4 35 1 r 1 c r^e r & e^ ■ i 56 4 63 5 48 scaTe^eα cracks 49 ~o cracrs 4 51 4 63 2 6 50 c crac 1 c 4 46 4 6^ 3 7 51 ^catte^ed cr α crs 4 58 4 1 1 52 ^o crac ^ 4 20 4 63 9 4 53 open cracks 4 43 4 63 4 4 54 crazeα 55 e v treτιely c ackec 4 55 4 63 1 8 56 ro cracks -71 57 no cracts 4 51 4 63 2 6 -70 58 ooen cracks 4 47 4 63 3 5 59 open cracks 60 rigMy cracked 4 54 4 63 2 0 61 hiqhly cracked 62 no crao s 4 15 4 63 10 4 mean CTE from -40° to +40°C Table 3 (continued) Experimental data for Zr 2 F 2 WOι 2 ceramics with various amounts of ZrW 2 0 8 Mean Coefficient of Bulk Theoretical Thermal Expansion Example Density Density . Total (10 ",o C " ') Number Appearance (g/cm ) ig/cm » "orositv -40 to +85°C 63 open cra s 4 46 4 63 3 7 65 no cr.C's 4 51 4 63 -75 66 moαera'£ v "racheα 67 no crao 4 38 5 4 -77 68 no crawl s -67 69 no cracr s -70 70 no crαCf c 4 27 4 63 7 8 -66 7 1 po crao s 3 79 4 63 18 1 72 ro cracKs 4 44 4 63 4 1 -68 74 no crac* s -68 75 no crac* *= -70 7 6 ro cracrs -74 77 ro cracf ■= -79 78 ro crac 4 79 4 « 6 -84 7 9 scattered cract s 4 51 4 63 : 6 80 -ery f e« rac^ 4 52 4 63 2 3 8 1 no crao * 3 01 4 63 35 0 82 no crac-' 4 52 4 63 2 4 83 no croc 3 22 4 63 30 4 84 ver j e ao s 4 51 2 7 8 5 no era.. 3 14 4 32 3 8 6 no era 3 19 4 o 3 87 no crao s 3 32 4 63 28 3 88 ex re e 'a eα 4 54 4 63 2 0 from -40" to +40°C With increasing addition of ZrW 2 0 8 to Zr 2 P2WOι 2 , the amount of porosity the ceramic ooαy αecreases, and the thermal expansion becomes progressively more negative, reaching -gOxlO ' ^C "1 for 100% ZrW 2 0 8 as shown in Figure 1. For the preferred range of CTE between -70 and -85xl0 " o C _1 desired for athermalization of fiber Bragg gratings, the amount of Zr 2 P 2 WO 2 is between about 5% and 40%, and the amount of ZrW 2 0 8 is between about 60% and 95%. For the preferred range of CTE between -65 and -80xl0 "7 °C _1 desired for athermalization of fiber Bragg gratings, the amount of Zr 2 P 2 WOi 2 is between about 10% and 50%, and the amount of ZrW 2 0 8 is between about 50% and 90%. EXAMPLES 29 to 88 Powder preparation for Examples 29 to 88 was conducted in the same manner as Examples 1-18, with the proportions of the starting materials adjusted to yield Zr 2 P2WOi2 and ZrW 2 0 8 the ratios stated in Table 2, with the following exceptions: Example 68 was prepared using Zr0 2 , W0 3 , and a ZrP 2 0 powder prepared oy calcination of acid zirconium phosphate at 1050°C for 4 hours, and Examples 69 and 73-78 were prepared from Zr0 2 , W0 3 , and pre-reacted Zr 2 P2 Oι . The pre-reacted Zr 2 P2WOι was formed by dry oall milling a mixture of Zr0 2 , W0 3 ana acid zirconium phosphate in the appropriate ratios and calcining the mixture at 1050°C for 4 hours. Also, the powαers for Examples 72 to 78 were milled in water instead of isopropanol. Examples 29 to 88 were forrau ateα to yield ceramics witn coefficients of thermal expansion between -65 and -85xl0 7 °C _1 . In these examples, the weight percentages of Zr P 2 WOι 2 and ZrW 2 0 8 are relative to the sum of the weights of the Zr 2 p2WOι 2 and ZrW 2 0 8 components only. Weight percent of additive is relative to total weight percent of starting material . Example 29 shows that 0.25% aluminum monohydrate is an effective sintering aid in reducing the porosity of a 68%ZrW 2 0 8 -32%Zr 2 P2W0 12 ceramic to 4.6%. The fired sample exhibited good integrity, with no cracking. Example 30 shows that 0.25% addition of titania reduces porosity of a 68%ZrW2θ8-32%Zr 2 P2W0 12 ceramic to about 12% with no cracking. Example 31 illustrates that 0.25% addition of niobium oxide reduces the porosity of a 68%Zr 0 8 -32%Zr2P2WOι 2 ceramic to about 14% with no cracking. Example 32 demonstrates that 0.25% silica addition is not effective as a sintering aid for 68%ZrW 2 0 8 -32%Zr 2 P 2 W0 12 ceramics. Example 33 shows that although 0.05% lithium carbonate (equivalent to 0.02% Lι 2 0) reαuces porosity of a 68%ZrW 2 O 8 -32%Zr 2 P 2 W0 12 ceramic, this amount of additive results n scattered cracks. Example 34 illustrates that 0.10% sodium carbonate (equivalent to 0.06% Na 2 0) reduces the porosity of the 68%ZrW 2 0 8 -32%Zr 2 P2WOi2 composition to only 6%, without cracking. Example 35 shows that the amount of Na 2 C0 3 can be reduced to 0.05% (0.03% Na 2 0) and still reduce porosity to 17.8%. However, Example 36 shows that 0.01% sodium carbonate (0.006% Na 2 0) is not sufficient to reduce the porosity of this ceramic composition. Example 37 illustrates that although 0.25% potassium carbonate (equivalent to 0.17% K 2 0) is a very effective sintering aid for the 68%ZrW 2 0 8 -32%Zr 2 P2WO 2 composition, reducing porosity to 5.4%, the ceramic body exhibits extreme cracking after firing. Example 38 shows that slowing the heating rate to 25 °C/hour above 1100°C does not eliminate the cracking of this composition. Thus, the amount of K 2 0 present in a 68%ZrW 2 0 8 -32%Zr 2 P 2 WOι 2 ceramic must be less than 0.17% to avoid cracking. Example 39 demonstrates that even 0.05% K 2 COn (0.034% K 2 0) is effective as a densification aid for these ceramics. Examples 40 and 41 αemonstrate that addition of 0.25% calcium carbonate i, 0.14% CaO) is also very effective in reducing porosity; however, samples are extremely cracked after firing. Thus, the amount of CaO in a 68%ZrW 2 0 8 - 32%Zr 2 P 2 WOi 2 ceramic must be less than 0.14% to avoid cracking. Example 42 shows that even only 0.05% CaC0 3 (0.03% CaO) is sufficient to substantially reduce the porosity these ceramics. Examples 43 and 44 show that the addition of 0.25% barium carbonate (0.19% BaO) is effective in reducing porosity to 2.0%; however, the sintered body exhibits a small amount of cracking. Example 45 shows that reduction of the amount of barium carbonate to 0.1% (0.08% BaO) is still effective in lowering porosity to less than 4%, and results in a crack-free body. Thus, the amount of BaO should be less than about 0.19% to avoid cracking. Example 46 demonstrates that the addition of 1.0% magnesium oxide, MgO, to the 68%ZrW2θ8-32%Zr 2 P2W0 12 composition results in the formation of excessive liquid, so that the body underwent considerable slumping. Examples 47 and 48 show that reduction in the MgO concentration to 0.25% yielded a cracked body that was otherwise well densified. Example 49 demonstrates that addition of only 0.05% MgO still yields a low-porosity body which is also free of cracks. Thus, the amount of MgO must be less than 0.25% to avoid cracking. Examples 50 and 51 show that 1.0% or 0.25% cupric oxide, CuO, is effective m lowering porosity of the 68%ZrW 2 0 8 -32%Zr 2 P 2 WOι 2 composition. However, XRD revealed considerable amounts of zirconium oxide and tungsten oxide m the fired body which are undesirable for strongly negative CTE. However, 0.05% CuO addition (Example 52) still yields a low-porosity ceramic, while maintaining the ZrW 2 0 8 and Zr 2 P 2 WOi2 phases with essentially no secondary zirconium or tungsten oxides. Thus, the amount of CuO should be less than about 0.25% to prevent the formation of excessive amounts of Zr0 2 and Oj in the fired ceramic. Examples 53 and 54 illustrate that addition of 1.0% zmc oxide, ZnO, to the 68%ZrW 2 0 8 -32%Zr 2 P 2 WOι 2 composition is effective in reducing porosity, but results in cracking of the body. Examples 55 and 56 show that reduction of the amount of ZnO to 0.25% is still useful in densifymg the ceramic, and can result in a crack-free body when the heating rate above 1100°C is less than 100 °C/hour. Further lowering of the amount of ZnO to 0.1% results in a dense, crack-free body even for heating rates of 100 °C/hour (Example 57) . Examples 58 and 59 demonstrate that 1.0% manganese carbonate (yielding 0.62% MnO) is effective in densifymg 68%ZrW 2 0 8 -32%Zr2P2WOi2 ceramics, but produces cracking in the fired body. Examples 60 and 61 show that 0.25% MnC0 3 (0.15% MnO) still reduces porosity to low levels, but cracking is present. Example 62 shows that 0.05% MnC0 3 (0.03% MnO) is still effective as a sintering aid, and does not produce cracking. Thus, the amount of MnO in the %ZrW 2 0 8 -32%Zr 2 p 2 WOι 2 ceramic must be less than about 0.15% to prevent crack formation during sintering. Examples 63 and 64 illustrate that 1.0% ferric oxide, Fe 2 0 3 , is effective as a sintering aid for %ZrW 2 0 8 - 32%Zr P2WOi2 ceramics, but results in cracking. Example 65 shows that 0.25% Fe 2 0 3 yields a low-porosity, uncracked body. Thus, the amount of Fe 2 0 3 to be used as a sintering aid for the 68%ZrW 2 0 8 -32%Zr2P2 Oi2 composition is preferably less than 1.0% to avoid cracking. Example 66 shows that addition of 0.50% yttrium oxide, Y 2 0 3 , yields a cracked body of 68%ZrW 2 0 6 -32%Zr 2 P 2 WOι 2 composition. Example 67 shows that reducing the yttria to 0.25% eliminates cracking and still reduces porosity to 5.4%. Example 68 demonstrates that the phosphorus can be supplied as ZrP 2 θ7 powder. Example 69 shows that the phosphorus can be supplieα as pre-reacted Zr 2 P 2 WOι 2 powder. Example 70 illustrates that the amount of yttria can be reduced to 0.12% and still yield a 68%ZrW 2 0 8 -32%Zr 2 P 2 WOι 2 ceramic with low porosity without cracking. Example 71 shows that reduction of the amount of yttria to only 0.05% results in an increase in porosity to 18.1% when the powders are milled in isopropanol. However, Example 72 demonstrates that 0.05% yttria is sufficient to serve as an effective densification aid when the powders are milled in water. Example 73 shows that phosphorus may be supplied as pre-reacted Zr 2 P 2 WOι 2 powder to the raw material mixture. Example 74 αemonstrates that a ceramic comprised of 75% ZrW 2 0 8 and 25% Zr 2 P 2 W0 12 with 0.05% yttria additive is uncracked and possesses a CTE of -68xl0 _7 °C _1 . Examples 75 and 76 show that this composition may be fired at 1175°C for 4 to 8 hours. Example 77 shows that the amount of ZrW 2 0 8 can be increased to 85 weight % with 0.05% yttria as a sintering aid to yield a crack-free sample with a CTE of -79xlO "7 °C "1 . Example 78 shows that the amount of ZrW 2 0 8 can be further increased to 88 weight % with 0.05% yttria as a sintering aid to yield a crack-free, low-porosity ceramic with a CTE of -84xl0 "7 °C _1 . Example 78 also contains an addition of about 2 weight % excess tungsten oxide as a separate phase, addition to the 10 weight % Zr 2 P 2 WOι 2 . Examples 79 and 80 show that addition of 0.25% of the oxides of the rare earth metals lanthanum and cerium are very effective at reducing the porosity of 68% ZrW 2 0 8 and 32% Zr 2 P 2 WOι 2 bodies to less than 3%. Slight cracking of these compositions shows that the amount of La 2 0 3 or Ce0 2 additive is preferably less than 0.25%. Example 81 demonstrates that the addition of 0.25% Mo0 3 is not effective as a sintering aid for 68% ZrW 2 0 8 and 32% Zr 2 P 2 W0 12 ceramics. Example 82 illustrates that 0.25% bismuth oxide greatly lowers the porosity of 68% ZrW 2 0 8 and 32% Zr 2 P 2 W0 i2 bodies, and that no cracking is present. Example 83 shows that addition of 0.25% B 2 0 3 to a 68% ZrW 2 0 8 and 32% Zr 2 P 2 WOι 2 body does not significantly reduce porosity. Example 84 demonstrates that 0.25% gallium oxide is highly effective lowering the porosity of 68% ZrW 2 O s and 32% Zr 2 P 2 Oi 2 ceramics. However, amounts less than 0.25 weight % are preferred to avoid cracking. Examples 85, 86, and 87 illustrate that 0.25% addition of the oxides of indium, or tin, or chromium is not greatly effective in reducing the porosity of 68% ZrW 2 0 8 and 32% Zr 2 P 2 WOι 2 bodies. Example 88 shows that addition of 0.25% nickel oxide to the 68% ZrW 2 0 8 and 32% Zr 2 P 2 WOι 2 composition reduces porosity to very low levels; however, the amount of NiO is preferably less than 0.25% to prevent cracking of the ceramic . COMPARATIVE EXAMPLES Although the thermal expansion coefficient of zirconium tungstate is more strongly negative than that which is required for athermalization of a fiber Bragg grating, ceramic bodies having the desired thermal expansion can be prepared from mixtures of ZrW 2 0 8 with one or more additional phases whose CTEs are either positive or less negative than that of zirconium tungstate. The amount of additional phases that would be required to yield a ceramic having a specific CTE can be estimated from the relation (Equation 1) α m = Via ! + V 2 a 2 -t- V 3 a + . . . V n n in which a ra is the coefficient of thermal expansion of the mixture, αi is the CTE of component 1, chosen to be Zr 2θ 8 , α 2 is the CTE of component 2, etc. for n phases, and V 1; V 2 , . . . V n are the volume fractions of components 1 (ZrW 2 0 8 ) , 2, etc. Equation 1 is only approximate, because it does not take into account the effect of the different elastic moduli of the various phases, or the possibility of microcrackmg . The terms in Equation i refer to the actual volume fractions of the phases that are present in the fired ceramic. For a given mixture of starting materials, one must understand the phase relations for that system at the temperature to which the body is fired. Addition of a metal oxide to the ZrW 2 0 8 precursor (such as Zr0 2 + WO 3 ) does not ensure that the fired ceramic will consist only of ZrW 2 0 8 plus that metal oxide. In many instances, the metal oxide additive will react with the zirconium tungstate to form two or more new phases. In order to achieve the desired CTE in the fired ceramic, it is necessary to know the phases that will form, the volume fractions of those phases, and their CTEs, so that the amount of metal oxide additive (s) can be judiciously selected. In the comparative examples αescπbed below, oxide compounds having positive coefficients of thermal expansion were added to zirconium and tungsten oxides in amounts that nominally would yield ZrW 2 0 8 -based ceramics having mean CTEs of about -75x10 " °C λ if the oxide additives remained unreacted during firing of the ceramic. The amount of metal oxide second phase that would be required to yield a ceramic having this CTE was computed from the relation (Equation 2) α m =-75xl0 ~7 °C λ = V zw α. zw +V mo α mo m which α ra is the mean coefficient of thermal expansion of the mixture near 25°C, chosen to be -75xlO "7 °C _1 , α zw is the mean CTE of ZrW 2 0 8 near 25°C, which is about α mo is the mean CTE of the metal oxiαe added as the oxide or added as its precursor, and V zw and V m0 are the volume fractions of ZrW 2 0 8 and metal oxide, respectively. The compositions of the examples are provided in Table 4. Table 5 lists the appearances of the samples and their phase compositions after firing as determined by X-ray diffractometry . CTE was measured by dilatometry. Table 4 Experimental data for ZrW 0 H cerami cs with various amoun s of second phase additives Heating rate above Volume % Nominal CTE 1100°C Soak Example Weight % Volume % Weight * Additive of Oxide Sample ( ϋ C/hr) Temperature Soak Time Number ZrW 2 O e ZrW 0 8 Addjtive Additive i 0/ de (25 100°C) Geometry (°C) (hours) Cl 90 4 88 A1 2 0 3 9 6 12 70 11 4 cm bar 100 1150 4 C2 90 4 88 Λ1 2 0> 9 6 12 70 11 4 cm bar 450 1200 8 C3 93 5 91 MgO 6 S 9 120 11 4 cm bar 100 1150 4 C4 89 7 91 CaCOj 10 3 9 130 11 4 cm bar 100 1150 4 C5 88 1 88 Y?0 3 11 9 12 70 11 4 cm bar 100 1150 4 C6 88 1 88 Y 2 O, 11 9 12 70 11 4 cm bar 450 1200 8 C7 86 3 88 Zr0 2 13 7 12 70 11 4 cm bar 100 1150 4 C8 86 3 88 Zr0 2 13 7 12 70 11 4 cm bar 450 1200 8 C9 90 8 81 Fused Sio 2 9 2 19 5 11 4 cm bar 100 1150 4 C O 90 8 81 Fused Si •0 2 9 2 19 5 11 4 cm bar 450 1200 8 Cll 95 1 91 Quartz S 10; 4 9 9 120 11 4 cm bar 100 1150 4 C12 95 1 91 Quartz S 1O2 4 9 9 120 11 4 cm bar 450 1200 8 C13 85 0 83 6 ZrSiO, 15 16 4 40 7 6 cm bar 100 1175 8 5 Table 5 Experiment l data for ZrW 2 0 8 ceramics with various amount of second phase additives Mean Coefficient of CTE predicted by Thermal Expansion weighted average of Example (10 7 °C ') starting oxides Number Appearance Crystalline Phases (Powder XRDI -40 to +8S°C (10 ,0 c-'i Cl Sintered bar Al 2 (WO,) 3 , Zl0 2 -75 C2 Severely slumped bar, severe sticking Al 2 (WO,)3, Zr0 2 , A] 2 0 3 -75 C3 Slumped bar, severe sticking HgW0 4 , ZrO ^ , unidentified phase(s) -76 C4 Severely slumped bar, severe sticking CaW0 4 , Zr0 2 , unidentified phase (s) -75 C5 Concave surfaces, severe sticking Zr0 2 , unidentified phase(s} -75 C6 Deformed, tapered bar, sticking Zr0 2 , unidentified phase(s) -7S C7 Chalky surface Zr 2 0 B , Zr0 2 -75 C8 Chalky surface ZrW 2 O β , Zr0 2 -75 C9 Sintered bar, slightly chalky surface ZrSlO ( , Oj, cristoballte, ZrO; -76 CIO Sintered bar, slightly chalky surface ZrSiO,, 0 3 , cristoballte -76 Cll Sintered bar, slightly chalky surface Zr 2 0 B , ZrSl0 4 , WOj, cri toballte, ZrO. -76 C12 Sintered bar, hard surface ZrW 2 0 8 , ZrSlO,, WOj -61 -76 C13 Sintered bar, hard surface ZrW 2 0 B , ZrSiO, , trace WO , -51 -69 **Too deformed for CTE measurement Samples were prepared by vibratory milling the powders in water for 16 hours, adding a polyethylene glycol binder, drying the slurry, granulating the dried cake, and uniaxially pressing bars of 11.4 cm length, except for Example C13, which was pressed into a bar of 7.6 cm length. Bars were set on zirconium oxide "sand" in an alumina box and fired at 1150°C or 1175°C, or were set on zircon "sand" on an alummosiiicate pallet and fired at 1200°C (Table 4) . Examples Cl and C2 were prepared to yield a ceramic with a nominal composition of 88 volume% Zr 2 0 8 + 12 volume% (9.6 weight!) A1 2 0 3 . However, the results in Table 5 demonstrate tnat Zr 2 0 8 is unstable when fired with alumina, and reacts to form A1 2 (W0 4 ); + Zr0 2 . This results m a positive CTE for this material of +100xlO "7 °C "1 . Thus, the concept of forming a Zr 2 0 8 + A1 2 0 3 ceramic is untenable, because no such ceramic can be produced due to reaction of alumina with zirconium tungstate. However, it is contemplated that a ceramic article consisting of Zr 2 O a with small amounts of A1 2 (W0 4 ) 3 could be fabricated by addition of aluminum and tungsten oxides to the ZrW 2 0 8 precursor powders, and the amount of A1 2 ( 0 4 ) 3 in such a ceramic could be selected so as o yield a body with a CTE that is less negative than -gOxlO "70 ^ 1 . Also, it is contemplated that a body comprised of Zr 2 0 8 +Al 2 (W0 4 ) 3 +Zr0 having a CTE less negative than -90xlO "7 °C _1 could be prepared by adding only alumina, provided that the alumina addition is much less than 9.6 weιght% . Example C3 was prepared to yield a ceramic with a nominal composition of 91 volume! Zr 2 0 8 + 9 volume% (6.5 weιght%) MgO. However, as seen m Table 5, this composition, even when fired at only 1150°C ( ust above the lower thermal stability limit of Zr 2 0 8 ) , undergoes reaction between Zr 2 0 8 and MgO to form MgW0 4 + Zr0 2 + unidentified phases. No Zr 2 0 8 remains in the body, and the remaining phases all have large positive CTEs, making this ceramic inappropriate for use as a substrate for a fiber Bragg grating. Furthermore, the ceramic body underwent slumping and sticking to the zirconia sand due to extensive formation of liquid during firing. Thus, the formation of a Zr 2 0 8 + MgO ceramic is not feasible, because no such ceramic can be produced. Instead, MgO reacts with Zr 2 0 8 to form phases other than MgO. Addition of MgO to Zr 2 0 8 m amounts of more than a few weight percent is undesirable. Example C4 was prepared to yield a ceramic with a nominal composition of 91 volume! ZrW 2 0 8 + 9 volume! CaO, _n which the CaO was provided as 10.3 weight! CaC0 3 . however, as seen in Table 5, this composition, even when fired at only 1150 °C, undergoes reaction between Zr 2 0 8 and CaO to form Ca 0 4 - Zr0 2 + unidentified phases. No Zr 2 0 8 remains in the body, and the remaining phases all have large positive CTEs (the CTE of Ca 0 is about lOOxlO "70 ^ 1 ) , making this ceramic inappropriate for use as a substrate for a fioer Bragg gratirg. Furthermore, the ceramic body underwent severe slumping and sticking to the zirconia sand due to extensive formation of liquid during firing. Thus, the formation of a Zr 2 0 8 + CaO ceramic is not feasible, because no such ceramic can be produced. Instead, CaO reacts with ZrW 2 0 8 to form phases other than CaO. Addition of CaO, or a CaO source such as CaC0 3 , to Zr 2 0β in amounts of more than a few weight percent is undesirable . Examples C5 and C6 were formulated to yield a ceramic with a nominal composition of 88 volume! Zr 2 0 8 + 12 volume! (11.9 weight!) Y 2 0 3 . However, Table 5 shows that, after firing, the ceramic contained no Zr 2 0 8 . Instead, reaction of the starting materials yielded Zr0 2 , and several unidentified phases. The high CTE resulting from this reaction, +101X10 ~7o C ~'1 , demonstrates that the amount of yttria in a zirconium tungstate ceramic should be kept to less than a few percent. Examples C7 and C8 were prepared to yield a ceramic with a nominal composition of 88 volume! Zr 2 0 8 + 12 volume! (13.7 weight!) Zr0 2 . X-ray diffractometry of the fired samples (Table 5) shows that these two phases do, in fact, coexist. The fired bar possessed a very powdery surface after firing, which was found to consist almost entirely of zirconium oxide. Such a surface would be unsuitable for direct attachment of a fiber grating, and would require machining to expose the low-porosity interior of the sample. The CTE of the sample, after removal of tne surface layer, was measured to be -68xl0 7 °C 1 , only slightly less negative than the predicted value of -75xl0 ~7 °C _1 . The dimensional stability of a similar ceramic of ZrW 2 0 8 with 15 weight! Zr0 2 was determined by monitoring the lengths of two sintered bars as a function of time in an 85 °C, 85! relative humidity environment. The dimensional changes of these oars is provided m Table 6 (examples D4 and D5) and depicted in Figure 2. Table 6 Change in ±enαth expressed as ΔL/L, in parts per million, of ceramic bars exposed to 85°C, 85% relative humidity, for indicated durations. Example DI Example D2 Example D3 Example D4 Example D5 68% Zr 2 O β 32% Zr 2 P 2 WOl2 68% ZrW 2 O β 68% ZrW 2 0 8 Time 0.25% Y 2 0 3 32% Zr 2 P 2 WOι: Time 32% Zr 2 P 2 WOι 2 T me Zr 2 0 8 85% ZrW 2 0 8 (hours) 0.25% Y∑O-. (hours) 0.10% BaC0 3 (hours) 15% Zr0 2 15% Zr0 2 0 0 0 0 0 0 0 0 160 -15 -5 178 -13 162 -222 -191 322 0 10 338 -15 301 -476 -458 482 -13 -2 498 -10 462 -1044 -1123 642 -10 658 -13 623 -2279 -2800 802 -10 800 -13 783 -4376 -5441 The severe shrinkage of these ceramics over a relatively short span of time renders them inappropriate for use as a fiber grating substrate. For comparison, bars of the inventive compositions 68!Zr 2 0 8 +32! Zr 2 P 2 WOι 2 + 0.25! Y 2 0 3 (Examples DI and D2 ) and the inventive composition 68!Zr 2 0 8 +32! Zr 2 P 2 Oι 2 + 0.10! BaC0 3 (Example D3) undergo negligible dimensional change with time under the same conditions of temperature and humidity. Examples C9 and CIO were prepared to yield a ceramic with a nominal composition of 81 volume! ZrW 2 0 8 + 19 volume! (9.2 weight!) Sι0 2 in which the Sι0 2 is added as fused silica. Table 5 shows that this combination results in reaction of the ZrW 2 0 8 with Sι0 2 to form zircon (ZrSι0 4 ) + tungsten oxide, which have CTEs at 25°C of about 40xlO "~7 °C ~1 and lβOxlO ' ^C "1 , respectively. Consequently, the CTE of this ceramic body is highly positive, 64xlO "7o C "1 . The presence of a small amount of cristoballte, a crystalline form of silica, indicates that the reaction did not proceed to completion during the time allowed. Thus, the formation of a ZrW 2 0 8 + fused Sι0 2 ceramic is not possible, because no such ceramic can be produced due to reaction of silica with the Zr 2 0 8 . Examples Cll and C12 were formulated to yield a ceramic having a nominal comoosition of 91 volume! Zr 2 0 8 + 9 volume! (4.9 weight!) Sι0 2 in which the Sι0 2 is added as quartz, a crystalline form of silica. Less volume percent of this form of silica was added than for the case where the Sι0 2 was added as fused silica because quartz has a much higher thermal expansion than fused silica, so less is required to compensate the CTE of the mixture by Equation 2. As seen in Table 5, the quartz also reacts with ZrW 2 Og to form zircon and tungsten oxide, although in these two examples the lower amount of silica allows for some Zr 2 0 8 to remain in the body after firing. However, the CTE of this mixed phase ceramic is only -61xl0 _7o C "1 , less negative than desired, and less negative than predicted from Equation 2 because of the reaction of silica with Zr 2 θ 8 . Example C13 was formulated to yield a ceramic consisting of 85 weight! (83.6 volume!) ZrW 2 0 8 + 15 weight! (16.5 volume!) ZrSι0 4 , in which the silicate was added as a very fine zircon powder. After firing, the ceramic consisted of Zr 2 0 8 + ZrSι0 4 , with only trace amounts of residual Zr0 2 and 0 3 . The nominal CTE predicted for this composition is -69xlO " °C "1 ; however, the measured expansion from -40° to +40°C was -51xlO "7 °C _1 . Furthermore, the dilatometric CTE curve exhibited a hysteresis upon heating to +90°C and cooling back to 20°C, with an increase in sample length corresponding to a ΔL/L of over 400 parts per million. Examination of the sample by scanning electron microscopy showed that tne sample had pervasive microcrackmg throughout the ZrW 2 0 8 matrix. The dimensional instability of the sample with thermal cycling above room temperature renders this composition inappropriate for application as a fiber grating substrate . The materials and methods of the present invention can be utilized for a variety of applications requiring negative thermal expansion materials, such as providing temperature compensation for optical devices such as gratings. The materials of the present invention could be used to make support members for such devices. For example, referring to Figure 3, there is illustrated a first exemplary embodiment of the invention. The optical fiber reflective grating device 20 has a substrate 22 formed from a flat block of a negative expansion material, such as the materials of the present invention. An optical fiber 24 having at least one UV-mduced reflective grating 26 written therein is mounted on tne surface 28 and attached at either end of the surface at points 30 and 32. It is important that the fiber is straight and not subject to compression as a result of the negative expansion and thus the fiber is usually mounted under tension. Before attachment the fiber is placed under a controlled tension, as shown schematically by the use of a weight 34. The proper choice of tension assures that the fiber is not under compression at all anticipated use temperatures. However, the fiber can be under tension at all anticipated use temperatures. The required degree of tension to compensate for the negative expansion in a particular application can readily be calculated by those with skill in this art. The attachment material could be an organic polymer, for example an epoxy cement, an inorganic frit, for example ground glass, ceramic or glass-ceramic material, or a metal. In one embodiment the fiber is tacked to the substrate with a UV-cured epoxy adhesive. Mechanical means for attaching the fiber can also be used. Generally the optical fiber reflective grating is supplied with a coating material surrounding the fiber. In the preferred packaging approach the coating in the grating region of the fiber is left intact while it is removed in tne substrate attacnment region at eacn end of the grating. However, the device can have the coating completely removed between the attachment locations. Removal of the coating can be accomplished by one of two methods : a non-contact, non-chemical stripping mechanism or by conventional chemical stripping. In another embodiment shown in Figure 4, the fiber is not attached directly to the substrate. Bonding pads 40, 42 made from a material differing from the substrate, for example a glass or a ceramic, are attached to the substrate at either end. The fiber 26 is mounted to the pads at points 44, 46. These pads afford better attachment properties of the pad to the fiber than could be achieved from the substrate directly to the fiber because of the large thermal expansion mismatch. Suitable pad materials have a coefficient of thermal expansion intermediate between that of the fiber and the substrate, for example, between -50 and + 5xl0 -7 , preferably about -20xl0 ~7 . Alternatively the pad could be a fused silica with a coefficient of expansion closely matching that of the fiber. The pad allows the stress of this joint induced by both the thermal mismatch and the tension of the fiber, to be spread out over a wider area, lessening the chances of cracking and detachment. The attachment materials for the fiber ana paa connections are similar to those used for mounting the fiber directly to the substrate, for example, an epoxy cement, an inorganic frit, for example ground glass, ceramic or glass-ceramic material, or a metal. In another embodiment shown in Figure 5, the negative expansion of the substrate material 22 is used to create a clamping force on the fiber. The attachment feature, which might oe a hole or channel 50, 52 in a raised portion 54, 56 of the substrate, is formed in the substrate at room temperature with a gap that is very slightly smaller than tne fiber. Referring to Figure 6, by lowering the temperature to a point lower than any anticipated use temperature, the substrate expands and allows the insertion of the fiber 24 into the channel 50. Warming of the substrate then causes substrate contraction and creates a clamping force for holding the fiber in the channel. In another embodiment, Figure 7, the fiber 24 is attached to the substrate at points 30, 32 and the intermediate fiber length 60 is cushioned by a low modulus damping material 62. This low-modulus material, for example a silicone rubber coating surrounding the fiber or a pad of a silicone rubber, a natural or synthetic rubber or mixtures thereof, between the fiber and the substrate protects the fiber reflective grating against external perturbations such as mechanical shock or vibration. Bowing of the fiber is also minimized. In one embodiment the low modulus material is adhesively attached to the fiber and the substrate. Mounting the fiber under tension will alter the optical properties of the device (for example, the center wavelength of a grating) . This can be addressed by biasing the device with a reflective grating written therein to account for the tension, or it can be done by mounting a fiber, for example a germania doped silica fiber, without a reflective grating written therein under tension and then exposing the fiber to UV light in order to fabricate the grating in the device m si tu . In a typical embodiment of the invention, the temperature sensitivity of the center wavelength is about 0.0125 nm/°C for the uncompensated grating, the stress sensitivity of the center wavelength is 0.125 nm shift for 9g of tension, the bare fiber has a diameter of 125 microns, a coated fiber has a diameter of 250 microns. The strength of the fiber is greater than 200 kpsi, and therefore has a very high reliability. Although this invention has been described for UV photo induced gratings it can also be applied to the packaging of other thermally sensitive devices. For instance, optical fiber couplers and optical waveguides could be athermalized by attachment to a negative expansion substrate. An optical fiber fused coupler has two or more fibers fused together at one or more points along their length and is mounted on a substrate. Such couplers are thermally sensitive which results in a certain amount of thermal instability. Especially sensitive are biconically tapered couplers in which mterferometric effects are used, for example a Mach-Zehnder interferometer. Such couplers can be athermalized by mounting the coupler to a negative expansion substrate. Figure 8 illustrates a fused bicomcal coupler device 70 wnich includes a negative expansion substrate 72 to which are mounted two fibers 74, 76. The fibers are fused together at regions 78, 80. The fibers are attached to the substrate near the ends at locations 82, 84 in the same manner as described above for the optical fiber reflective grating. Waveguides can be defined, for example, in optical fibers or planar substrates. Such waveguides are thermally sensitive which results in a certain amount of thermal instability. Such waveguides can be athermalized by mounting the waveguide to a negative expansion substrate. Figure 9 illustrates a planar waveguide device 90 which includes a negative expansion substrate 92 on which is adhesively mounted a layer of material 94 in which a planar waveguide 96 is fabricated by methods well known to those skilled in this art. The waveguide material can be, for example, a doped silica such as a germania silicate, other suitable glass compositions, polymers and semiconductors, including semiconductors with gain, such as laser diodes. A fiber Bragg grating device with greatly reduced temperature dependence was fabricated by attaching a fiber Bragg grating under tension to a substrate of Example 78 of Tables 2 and 3 using a tin zmc pnosphate glass frit containing 45 weight ! of a magnesium cobalt pyrophosphate filler. FIG. 10 shows the beneficial athermalization properties of the invention with the center wavelength of this fiber Bragg grating device plotted against temperature of the device. At -5°C the center wavelength of the grating was 1531.353 nm, and at 75°C the center wavelength was 1531.277 nm. Thus, over this range in temperature, the device exhibited a variation in wavelength versus temperature of -0.00095 nm/°C, compared with +0.012 nm/°C for an unattached grating. In a preferred embodiment, the device includes a negative expansion substrate having a composition comprising two phases having negative coefficients of tnermal expansion, one of the phases having a room temperature coefficient of thermal expansion more negative than -50xlO -7 °C "1 and a fiber Bragg grating affixed to the substrate, wherein the absolute value of the average temperature dependence of the Bragg wavelength between 0°C and 70°C is not more than about 0.0025 pm/°C. In a further embodiment, the device includes a negative expansion substrate having a composition comprising two phases having negative coefficients of thermal expansion, one of the phases having a room temperature coefficient of thermal expansion more negative than -50xlO ~7 °C _1 and a fiber Bragg grating affixed to the substrate, wherein the absolute value of the average temperature dependence of the Bragg wavelength between 0°C and 70°C is not more than about 0.001 nm/°C. It will be understood that while tne exemplary device embodiments included flat substrates, this invention is not limited to a particularly shaped substrate. For example, it is contemplated that the ceramic bodies of the present invention could be utilized to make tubular and cylindrical substrates, or substrates that contain a V- shaped, U-shaped, or rectangular trough or groove. The device of this invention is a completely passive system and mechanically simple, and demonstrates athermalization. The method of producing the device is advantageous because it provides temperature compensated optical devices which tolerate shock and vibration and are thermally stable. It will be apparent to those skilled m the art that various modifications and variations can be made in the of the present invention without departing from the spirit or scope of the invention. Thus, it is intended that the present invention cover the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.

Claims: CLAIMS What is claimed is: 1. A ceramic body comprising A 2 P 2 W0 12 and a crystalline or non-crystalline oxide phase, including a glassy phase, which contains a metal selected from the group consisting of alkaline earth metals, alkali metals, manganese, iron, cobalt, copper, z c, aluminum, gallium, and bismuth, wherein A is selected from the group consisting of Zr and Hf . 2. The ceramic body of claim 1, wherein the A 2 P 2 O 2 is present in amount greater than about 95 weight percent and the body nas a porosity less than about 5!. 3. The ceramic body of claim 1, further comprising AW 2 0 8 , and wherein the metal of the oxide phase further may be selected from the group yttrium, lanthanide metals, scandium, niobium, titanium, and nickel. 4. The ceramic body of claim 3, wherein, on a weight percent basis, the AW 2 0 8 is present in an amount ranging from about 1! to 95!, the A2P2 O 1 2 is present in amount of about 5! to 99!, and the metal oxide is present in amount of about 0.01% to 7!. 5. The ceramic body of claim 3, wherein, on a weight percent basis, the AW0 8 is present in an amount ranging from about 50! to 90!, the AP 2 WOι is present in amount of about 10! to 50!, and the metal oxide is present in amount of about 0.01! to 3!. 6. The ceramic body of claim 3, wherein, on a weight percent basis, the AW 2 0 8 is present in an amount ranging from about 65! to 90!, the A 2 P 2 WOi 2 is present in amount of about 10% to 35%, and the metal oxide is present in amount of about 0.01% to 1%. 7. The ceramic body of claim 6, wherein the AW 2 0 8 is present in an amount ranging from about 80% to 88%, the A 2 P 2 W0 12 is present in an amount of about 12% to 20%, and the metal oxide is present in an amount of about 0.01% to 0.50%. 8. The ceramic body of claim 6, wherein the ceramic body has a tungsten oxide phase amount less than about 4 weight % and a zirconium oxide phase amount less than about 5 weight ! . 9. The ceramic body of claim 7, wherein the ceramic body has a tungsten oxide phase amount less than about 3 weight ! and a zirconium oxide phase amount less than about 4 weight ! . 10. The ceramic body of claim 4, wherein the body has a total porosity of less than about 10!. 11. The ceramic body of claim 4, wherein the body has a total porosity less than about 5%. 12. The ceramic body of claim 4, wherein the body has a coefficient of thermal expansion over a temperature range of about -50°C to about 100°C in the range of about -50x10 " 7 °C _1 to about -88xlO ~7 °C -1 13. The ceramic body of claim 4, wnere the body exhibits a length change having an absolute value less than 150 ppm over 700 hours at 85°C and 85! relative humidity. 14. The ceramic body of claim 4, wherein the body exhibits a length change having an absolute value less than 35 ppm over 700 hours at 85°C and 85! relative humidity. 15. The ceramic body of claim 4, wherein the body exhibits a length change having an absolute value less than 20 ppm over 700 hours at 85°C and 85! relative humidity. 16. A ceramic body comprising two phases having negative coefficients of thermal expansion, wherein one of the phases has a room temperature coefficient of thermal expansion more negative than -50xlO ~7 °C _1 . 17. The ceramic body of claim 16, wherein the body does not exhibit microcrackmg. 18. The ceramic body of claim 16, wherein one phase has the composition M 2 B 3 0ι 2 where M is selected from the group including aluminum, scandium, indium, yttrium, the lanthanide metals, zirconium, and hafnium, and where B is selected from the group consisting of tungsten, molybdenum, and phosphorus, and where M and B are selected such that the compound M 2 B 3 0ι has a negative CTE, and comprising a second phase of the composition AX 2 0 8 , where A is selected from tne group consisting of zirconium and hafnium, and X is selected from the group consisting of tungsten and molybdenum. 19. The ceramic body of claim 17, wherein the first phase is A 2 P 2 WOi 2 and the second phase is AW 2 0 8 , wherein A is selected from the group consisting of Zr and Hf, and wherein the body exhibits a length change having an absolute value less than 150 ppm over 700 hours at 85°C and 85% relative humidity. 20. The ceramic body of claim 17, wherein the first phase is A 2 P2 O12 and the second phase is AW 2 0 8 , wherein A is selected from the group consisting of Zr and Hf, and wherein the body exhibits a length change having an absolute value less than 35 ppm over 700 hours at 85°C and 85% relative humidity. 21. The ceramic body of claim 17, wherein the first phase is A 2 P 2 O 12 and the second phase is AW 2 0 8 , wherein A is selected from the group consisting of Zr and Hf, and wherein the body exhibits a length change having an absolute value less than 20 ppm over 700 hours at 85°C and 85% relative humidity. 22. A method of making a ceramic body having a porosity less than 10% comprising: mixing together powders of A2P2 O12 or precursor powders of A 2 P2 O12, and at least one oxide or oxide precursor of metals selected from the group consisting of alkaline earth metals, alkali metals, manganese, iron, cobalt , copper, zmc, aluminum, gallium, and bismuth wherein A is selected from the group consisting of Zr and Hf; consolidating the powders together using a ceramic forming method; and heating the consolidated powders at a temperature of about 1050°C to 1300°C for about 1 minute to 10 hours. 23. The method of claim 22, wherein the mixing step further comprises mixing together powders of AW 2 0 8 or precursor powders of AW 2 0 8 , and wherein the metal of the oxide phase further may be selected from the group yttrium, lanthanide metals, scandium, niobium, titanium, and nickel. 24. The method of claim 22, wherein the metal oxide or metal oxide precursor is present in an amount of less than 2 weight percent. 25. The method of claim 23, wherein the metal oxide or metal oxide precursor is present in an amount of less than 2 weight percent. 26. The method of claim 23, wherein the powder of AW 2 0 8 or precursor powder of AW 2 0 8 is present in amount ranging from about 50 weight percent and 95 weight percent and the powder of AP 2 WOι 2 or precursor powder of AP 2 WOι is present m an amount of about 5 weight percent to 50 weight percent . 27. The method of claim 23, wherein the heating step is performed at a temperature of about 1150°C to 1220°C for about 1 minute to 10 hours. 28. A method of raising the negative thermal expansion (i.e. making the thermal expansion less negative) of a ceramic body comprising a phase having a room temperature coefficient of thermal expansion more negative than -50x10 " °C _1 comprising mixing together the first phase with at least a second phase or precursors of the first phase and at least the second phase, the second phase having a negative thermal expansion less negative than -50xlO "7o C _1 . 29. The method of claim 28, wherein the material does not exhibit microcrackmg. 30. The method of claim 28, wherein one phase has the composition AX 2 0 8 , where A is selected from the group consisting of zirconium and hafnium, and X is selected from the group consisting of tungsten and molybdenum, and wherein the second phase has the composition 2 B 3 O 12 where M is selected from the group including aluminum, scandium, indium, yttrium, the lanthanide metals, zirconium, and hafnium, and where B is selected from the group consisting of tungsten, molybdenum, and phosphorus, and where M and B are selected such that the compound M 2 B 3 0ι 2 has a negative CTE. 31. An optical device comprising: a negative expansion substrate having a composition comprising two phases having negative coefficients of thermal expansion, one of the phases having a room temperature coefficient of thermal expansion more negative than -δOxlO ' ^C "1 ; and a thermally sensitive, positive expansion optical component affixed to the substrate. 32. The optical device of claim 31, wherein one phase has the composition M 2 B 3 0ι 2 where M is selected from the group including aluminum, scandium, indium, yttrium, the lanthanide metals, zirconium, and hafnium, and where B is selected from the group consisting of tungsten, molybdenum, and phosphorus, and where M and B are selected such that the compound M 2 B 3 0 12 has a negative CTE, and wherein the second phase has the composition AX 2 0 8 , where A is selected from the group consisting of zirconium and hafnium, and X is selected from the group consisting of tungsten and molybdenum. 33. The optical device of claim 31, wherein the first material is AW 2 0 8 and the second material is A 2 P 2 WOι 2 , wherein A is selected from the group consisting of Zr and Hf . 34. The optical device of claim 33, wherein the substrate does not exhibit microcrackmg. 35. The optical device of claim 33, wherein the substrate further includes a crystalline or non-crystalline oxide phase, including a glassy phase, which contains a metal selected from the group consisting of alkaline earth metals, alkali metals, manganese, iron, cobalt, copper, zinc, aluminum, gallium, bismuth, yttrium, lanthanide metals, scandium, niobium, titanium and nickel. 36. The optical device of claim 34, wherein, on a weight percent basis, the AW 2 0 8 is present in an amount ranging from about 50% to 95%, A 2 P 2 WOι 2 is present in amount of about 5% to 50%. 37. The optical device of claim 31, wherein the optical component is a an optical fiber grating. 38. The optical device of claim 34, wherein the substrate has a mean linear coefficient of thermal expansion of about -40xlO ~7 °C -1 to -88xlO "7 °C _1 over a temperature range of about -40°C to 85°C. 39. The optical device of claim 33, wherein the device is not hermetically sealed. 40. An optical device comprising: a negative expansion substrate having a composition comprising two phases having negative coefficients of thermal expansion, one of the phases having a room temperature coefficient of thermal expansion more negative than -50xl0 ~7 °C _i ; and a fiber Bragg grating having a Bragg wavelength affixed to the substrate, wherein the absolute value of the average temperature dependence of the Bragg wavelength between 0°C and 70°C is not more than about 0.0025 nm/°C. 41. The optical device of claim 40, wherein one phase has the composition M 2 B 3 0i2 where M is selected from the group including aluminum, scandium, indium, yttrium, the lanthanide metals, zirconium, and hafnium, and where B is selected from the group consisting of tungsten, molybdenum, and phosphorus, and where M and B are selected such that the compound M2B 3 O 1 2 has a negative CTE, and wherein the second phase has the composition AX 2 0 8 , where A is selected from the group consisting of zirconium and hafnium, and X is selected from the group consisting of tungsten and molybdenum. 42. The optical device of claim 40, wherein the first material is AW 2 0 8 and the second material is A 2 P 2 W0i2, wherein A is selected from the group consisting of Zr and Hf . 43. The optical device of claim 42, wherein the substrate does not exhibit microcrackmg.

Inventors: MERKEL GREGORY A, MERKEL, GREGORY, A.
Applicants: CORNING INC, MERKEL GREGORY A, CORNING INCORPORATED, MERKEL, GREGORY, A.
Application year: 1999
Main classification: G02B
IPC codes: C04B35, G02B6