Stable salad dressings

Abstract: The present invention provides a stable foodstuffs which contain a cholesterol lowering amount of a sterol or stanol ester, crystal fat inhibitors and emulsifiers. The foodstuffs, including salad dressings are stable even when refrigerated.

Description: Field of the Invention This invention relates to stable liquid foods, preferably salad dressings, containing a sterol ester and methods of producing the same. Background of the Invention It has been shown that the addition of plant sterols, such as β-sitosterol, to diets will reduce serum cholesterol levels. The sterols reduce serum cholesterol through the disruption of intestinal absorption of dietary cholesterol by displacing it from bile acid micelli. More recently, β-sitosterol's saturated derivative, β-sitostanol, has been shown to be more effective in the reduction of intestinal cholesterol absorption. The sitostanol itself is virtually unabsorbed, so it does not contribute at all to in vivo serum sterol concentration upon consumption. Unfortunately, typical sterols and stanols are insoluble in the micelli phase of the alimentary canal and have only limited solubility in oils and/or fats or water. Hence, free sterols or stanols themselves are not optimum candidates for use in typical pharmaceutical or dietary dosage forms as cholesterol reducing agents. The incorporation of these materials into foods are also difficult due to the limited solubility of the stanol or sterol in foods such as margarine and salad dressings. Salad dressings are particularly difficult in that they are frequently sold at room temperature, but require refrigeration after opening. Formulating a stable composition is particularly difficult when changes in temperature occur. Summary of the Invention According to the present invention there is provided a liquid food, as defined in appendant claims 1 to 8 and a method for preparing such a food, as defined in claim 9. In a particularly preferred embodiment the present invention is a salad dressing which remains stable even when refrigerated. Detailed Description As disclosed in U.S. Patent Nos. 5,502,045, 5,578,334 and 5,244,887, it is known that consumption of β-sitosterol is known to reduce cholesterol levels in the blood stream. In order to be effective it is necessary to consume from about 0.5 to 1.5 grams, and more preferably about 1 gram of β-sitosterol per serving size. The word sterol ester as used in the present invention is understood to mean any cholesterol lowering agent selected from β-sitosterol, stanols, stanol esters and sterol esters. In order to incorporate an effective amount of β-sitosterol in a salad dressing, in which an average serving size of about 30 grams, it is necessary to incorporate less than about 10 percent by weight, typically less than about 8 percent and most preferably about 6 percent by weight of the β-sitosterol in a salad dressing serving. At this relatively high level of β-sitosterol, it is difficult to formulate a stable product, especially after the product has been opened and requires refrigeration. Refrigeration as used herein, is understood to be temperatures below room temperature, which includes about 16°C (60°F), but the term also includes temperatures of 4°C (40°F) and below. These lower temperatures are commonly found in commercial and residential refrigerators. As used throughout this application, stable is understood to mean that the product does not separate into different phases. Instead the food, most preferably the salad dressing, will be relatively uniform and not separate into distinct layers. An example of a stable system is a salad dressing which remains creamy after a period of time. An example of an unstable system is an Italian salad dressing which after the passage of some time will separate into two distinct regions, an oil phase and an aqueous phase. The present invention requires the incorporation of an effective amount of fat crystal inhibitors which are selected from polyglycerol esters of fatty acids, sorbitan esters of fatty acids such as sorbitan tristearate; and mixtures of these materials. A particularly preferred fat crystal inhibitor is Caprol ET, commercially available from A.C. Humko, which is a mixture of polyglycerol fatty acid esters. Typically these materials are incorporated at levels of from 0.1 to about 3.0 percent by weight, preferably from about 0.2 to about 2.0 and most preferably about 0.5 weight percent. Suitable polyglycerol esters include triglyceryl monostearate, hexaglyceryl distearate, hexaglyceryl monopalimate, hexaglyceryl dipalmitate, decaglyceryl distearate, decaglyceryl monoleate, decaglyceryl dioleate, decaglycerol monopalmitate, decaglycerol dipalmitate, decaglyceryl monostearate, octaglycerol monoleate, octaglycerol monostearate and decaglycerol monocaprylate. Emulsifiers in the practice of the present invention are mono and diglycerides of fatty acids, propylene glycol esters, sucrose fatty acid esters and polyoxyethylene derivatives of sorbitan fatty acid esters. Mixtures of emulsifiers may also be employed. These emulsifiers are well known in the art and are commercially available. The emulsifier level is typically from about 0.01 to about 1.5 weight percent, preferably from about 0.1 to about 1.2 and most preferably from about 0.5 to about 1.0 weight percent. Other suitable emulsifiers include, with HLB values provided in brackets, [ ], include decaglycerol monolaurate[15.5]; decaglycerol distearate [10.5]; decaglycerol dioleate [10.5]; decaglycerol dipalmitate [11.0]; decaglycerol monostearate [13.0]; decaglycerol monooleate [13.5]; hexaglycerol monostearate [12.0]; hexaglycerol monooleate [10.5]; hexaglycerol monoshortening [12.0]; polyoxyethylene (20) sorbitan monolaurate [16.7]; polyoxyethylene (4) sorbitan monolaurate [13.3]; polyoxyethylene (20) sorbitan monopalmitate [15.6]; polyoxyethylene (20) sorbitan monostearate [14.9]; polyoxyethylene (20) sorbitan tristearate [10.5]; polyoxyethylene (20) sorbitan monooleate [15.0]; polyoxyethylene (5) sorbitan monooleate [10.0]; polyoxyethylene (20) sorbitan trioleate [11.0]. As is appreciated by those with skill in the art, the HLB value for a surfactant is an expression of its Hydrophile-Lipophile balance, i.e., the balance of the size and strength of the hydrophilic (polar) and lipophilic (non-polar) groups of the surfactant. Lactic acid derivatives include sodium stearoyl lactylate and calcium stearoyl lactylate. In addition to emulsifiers, hydrocolloids may also be used to stabilize the emulsion at the same levels as the emulsifiers. Suitable hydrocolloids include xantham gum, propylene glycol alginate, guar gum, gum Tragarcanth, locust bean gum, gellan gum, gum Arabic, cellulose gums, cellulose derivatives such hydroxymethylpropyl cellulose, carboxymethyl cellulose, microcrystalline cellulose; modified food starches. In a preferred embodiment, both an emulsifier and hydrocolloid are employed. Hydrocolloids are commonly used in combination with whole egg, egg yolks as well as the emulsifiers set forth above. The preferred stabilizers are combinations of xantham gum, propylene glycol alginate, egg yolk and modified food starches. However it was discovered that the incorporation of stanol esters in the formulations caused crystallization at temperatures below about 18°C (65°F). The destabilization of the emulsion was particularly noted when the amount of egg yolk was limited. In order to have the product defined as cholesterol free, egg yolk in the formulations was limited to less than 2 milligrams per serving. The foods of the present invention also include preservatives, colorings, vitamins, seasonings and excipients which are well known to those in the art. The present invention also provides a method for preparing a stable food emulsion comprising: providing an aqueous stream; providing an food grade acceptable oil; providing a stanol ester; providing a crystal fat inhibitor and a separate emulsifier; admixing said oil, stanol ester, crystal fat inhibitor and emulsifier; heating the admixture to a temperature of from 38°C to 66°C (100 to 150°F) to form a heated oil adding the heated oil to said aqueous system. More preferably the admixture is heated to a temperature of from 49 to 60°C (120 to 140°F). In order to make the salad dressings of the present invention any suitable food grade oils may be employed including soybean, sunflower, corn, vegetable and the like. The oils are typically less than 50 % of the salad dressing, more preferably from about 25 to about 40 weight percent. The following examples are provided to further illustrate the claimed invention. Unless noted otherwise, all weights are presented in weight percent. Example 1 The following examples are examples of a stable salad dressings containing sufficient stanol esters to provide an effective amount of stanol ester to reduce cholesterol when a serving of 30 grams is used. Sorbitan tristearate could be substituted for Caprol ET or combined with Caprol ET in each of the formulations. All of the following formulations additionally contain seasoning, preservatives, coloring, flavoring as desired for taste. RANCH DRESSING FORMULATION Ingredients Composition Typical Formula Range of Ingredients Ingredients Percent Percent Soybean oil, salad oil 40.000 30 - 50 Vinegar, 6.000 4.0 - 10 stanol esters 5.750 3.0 - 10 Sugar, 4.000 3.0 - 6.0 Cultured buttermilk solids 1.000 0.5 - 3.0 Caprol ET 0.500 0.2 - 2.0 Egg yolk, 0.360 0 - 2.0 Xanthan gum 0.300 0.15 - 0.5 Polysorbate 60 (Tween 60) 0.300 0 - 0.30 Propylene glycol alginate 0.160 0.05 - 0.30 Polysorbate 80 (Tween 80) 0.160 0.0 - 0.30 Water 36.568 To 100% Total 100.000 100 FRENCH STYLE DRESSING FORMULATION Ingredients Composition Typical Formula Range of Ingredients Ingredients Percent Percent Soybean oil 35.000 25 - 40 Sugar 14.000 8.0 - 20 Vinegar 6.000 4.0 - 10 Tomato Paste ( ∼ 31% solids) 6.000 3.0 - 10 Stanol esters 5.600 3.0 - 10 Caprol ET 0.500 0.1 - 2.0 Egg yolk 0.350 0 - 2.0 Polysorbate 60 0.300 0 - 0.3 Xanthan gum 0.200 0.1 - 0.5 Propylene glycol alginate 0.100 0 - 0.5 Polysorbate 80 0.100 0.0 - 0.3 Water 28.831 To 100% Total 100.000 THOUSAND ISLAND DRESSING FORMULATION Ingredients Composition Typical Formula Range of Ingredients Ingredients Percent Percent Soybean oil 35.000 25 - 40 Sweet relish 10.00 4.0 - 15 Sugar 9.000 4.0 - 15 Vinegar 6.000 4.0 - 10 Stanol esters 5.600 4.0 - 10.0 Tomato paste 5.000 2.0 - 8.0 Egg yolk, liquid, 10% salt 0.400 0 - 1.0 Caprol ET 0.500 0.1 - 1.5 Polysorbate 60 0.300 0.1 - 0.30 Xanthan gum 0.300 0.1 - 0.5 Propylene glycol alginate 0.130 0.05 - 0.5 Polysorbate 80 0.100 0.0 - 0.3 Water 25.700 To 100% Total 100.000 100 CREAMY ITALIAN DRESSING FORMULATION Ingredients Composition Typical Formula Range of Ingredients Ingredients Percent Percent Soybean oil 33.000 25 - 40 Vinegar 9.200 5.0 - 15 Sugar 6.000 3.0 - 10 Stanol esters 5.750 4.0 - 8.0 Diced sweet Bell peppers, dried 0.600 0.2 - 1.5 Caprol ET 0.520 0.1 - 1.0 Buttermilk 0.500 0 - 1.0 Eggs 0.400 0 - 1.0 Xanthan gum 0.320 0.1 - 0.5 Polysorbate 60 0.300 0 - 0.30 Modified food starch 0.250 0 - 1.0 Titanium dioxide 0.200 0 - 0.5 Propylene glycol alginate 0.160 0.05 - 0.5 Polysorbate 80 0.090 0.0 - 0.30 Water 37.330 To 100% Total 100.000 REDUCED FAT RANCH DRESSING FORMULATION Ingredients Composition Typical Formula Range of Ingredients Ingredients Percent Percent Soybean oil 24.500 15 - 28 Vinegar 8.000 4.0 - 12 Stanol esters) 5.750 4.0 - 8.0 Ranch seasoning 5.000 3.0 - 8.0 Sugar 4.000 2.0 - 7.0 Cultured buttermilk solids 1.400 0.2 - 3.0 Caprol ET 0.650 0.1 - 1.50 Lemon juice concentrate 0.450 0 - 2.0 Xanthan gum 0.450 0.1 - 0.60 Egg yolk 0.350 0 - 1.0 Polysorbate 60 0.300 0.1 - 0.30 Modified food starch 0.300 0 - 1.60 Propylene glycol alginate 0.215 0.05 - 0.5 Distilled mono- & diglyceride 0.200 0 - 1.50 Water 46.765 To 100% Total 100.000 Comparative Examples The following examples demonstrate formulations which were found to be unstable when refrigerated. However, when the stanol ester was removed and the formulation reconstituted, the formulation was once again stable, even when refrigerated. Ranch Style Salad Dressing Ingredients Composition Unstable Formula Stable Formula Ingredients Percent Percent Soybean oil, salad oil 40.000 45.750 Vinegar 6.000 6.000 stanol esters 5.750 0.000 Sugar, 4.500 4.500 seasoning 4.000 4.000 Cultured buttermilk solids 1.000 1.000 Cooking salt 0.400 0.400 Egg yolk, liquid, 10% salt 0.360 0.360 Xanthan gum 0.340 0.340 Propylene glycol alginate 0.160 0.160 Preservatives, colorings vitamins and seasonings Balance of formulation Balance of formulation Water 36.988 36.988 Total 100.000 100.000 FRENCH STYLE DRESSING FORMULATION Ingredients Composition Unstable formula Stable formula Ingredients Percent Percent Soybean oil, salad oil 35.000 40.600 Sugar, fine granulated 17.500 17.500 Vinegar, 120 grain, white distilled 6.000 6.000 Tomato Paste ( ∼ 31% solids) 6.000 6.000 Stanol esters 5.600 0.000 Egg yolk, liquid, 10% salt 0.350 0.350 Xanthan gum 0.200 0.200 Propylene glycol alginate 0.100 0.100 Preservatives, colorings vitamins and seasonings Balance of formulation Balance of formulation Water 26.231 26.231 Total 100.000 100.000 TYPICAL THOUSAND ISLAND DRESSING FORMULATION Ingredients Composition Unstable formula Stable formula Ingredients Percent Percent Soybean oil 35.000 40.600 Sweet relish 11.00 11.000 Sugar, fine granulated 9.000 9.000 Vinegar, 120 grain, white distilled 6.000 6.000 Stanol esters 5.600 0.000 Tomato paste ( ∼ 31% solids) 5.000 5.000 Egg yolk, liquid, 10% salt 0.400 0.400 Xanthan gum 0.300 0.300 Propylene glycol alginate 0.150 0.150 Preservatives, colorings vitamins and seasonings Balance of formulation Balance of formulation Water 25.580 25.580 Total 100.000 100.000 TYPICAL CREAMY ITALIAN DRESSING FORMULATION Ingredients Composition Unstable formula Stable formula Ingredients Percent Percent Soybean oil, salad oil 33.000 38.750 Vinegar 9.200 9.200 Sugar 6.000 6.000 Stanol esters 5.750 0.000 Buttermilk 0.500 0.500 Eggs 0.400 0.400 Xanthan gum 0.320 0.320 Modified food starch 0.250 0.250 Water 38.240 38.240 Preservatives, colorings vitamins and seasonings Balance of formulation Balance of formulation Total 100.000 100.000 TYPICAL LIGHT RANCH DRESSING FORMULATION Ingredients Composition Unstable formula Stable formula Ingredients Percent Percent Soybean oil, salad oil 24.500 30.260 Vinegar, 8.000 8.000 Stanol esters) 5.750 0.000 Seasoning 5.000 5.000 Sugar 4.000 4.000 Cultured buttermilk solids 1.400 1.400 Lemon juice concentrate 0.450 0.450 Xanthan gum 0.450 0.450 Egg yolk 0.350 0.350 Polysorbate 60 0.300 0.300 Modified food starch 0.300 0.300 Propylene glycol alginate 0.215 0.215 Preservatives, colorings vitamins and seasonings Balance of formulation Balance of formulation Water 47.615 47.615 Total 100.000 100.000

Claims: A liquid food comprising: a food grade acceptable oil; a cholesterol reducing amount of any cholesterol reducing agent selected from β-sitosterol, stanols, stanol esters and sterol esters; a emulsifier selected from a mono- or di- glyceride of a fatty acid, a propylene glycol ester, a sucrose fatty acid ester or a polyoxyethylene derivative of a sorbitan fatty acid ester, or hydrocolloid; a fat crystal inhibitor which is a polyglycerol ester of a fatty acid or a sorbitan ester of fatty acid, or a mixture thereof. The food of claim 1, which is salad dressing. The food of claim 1 or claim 2, which is stable when refrigerated. The food of any one of claims 1 to 3, wherein the emulsifier is a polysorbate 80 or polysorbate 60. The food of any one of claims 1 to 4, wherein the emulsifier level is from 0.01 to 1.5 weight percent. The food of any one of claims for 1 to 5, wherein the crystal fat inhibitor level is from 0.1 to 3.0 weight percent. The food of any one of claims 1 to 6, wherein the hydrocolloid is a xanthan gum, proplyene glycol alginate, a modified food starch or a cellulose derivative. The food of any one of claims 1 to 7, which contains from 0.5 to 1.5 grams of said cholesterol reducing agent per serving. A method for preparing a stable food emulsion comprising: providing an aqueous system; providing a food grade acceptable oil; providing a cholesterol reducing agent as defined in claim 1; providing a crystal fat inhibitor as defined in claim 1 and an emulsifier as defined in claim 1; admixing said oil, cholesterol reducing agent, crystal fat inhibitor and emulsifier; heating the admixture to a temperature of from 39 to 66°C (100 to 150°F) to form a heated oil; and adding the heated oil to said aqueous system.

Inventors: BRUCE RICHARD D, BURRUANO BRID T, DARTEY CLEMENCE K, HIGGINS III JOHN D, BRUCE, RICHARD D., BURRUANO, BRID T., DARTEY, CLEMENCE K., HIGGINS III, JOHN D.
Applicants: MCNEIL PPC INC, MCNEIL-PPC, INC.
Application year: 1999
Main classification: A23L1
IPC codes: A23L1