Printing and PCB members and methods for producing same

Abstract: Printing and printed circuit board members and a method for producing printing member from a member is provided. The printing member includes a topmost protective layer, an IR ablatable layer, a substrate and a wash-off layer. The wash-off layer is washed with a solvent after imagewise ablation of the topmost protective layer so as to expose the substrate, so that the printing member is produced. In one embodiment, the IR ablatable layer is disposed above the topmost protective layer and the wash-off layer is intermediate the topmost protective layer and the substrate

Description: FIELD OF THE INVENTION The present invention relates to printing members useable in a variety of printing presses, such as, gravure, offset lithography, silk screen, flexo and others and to methods for producing same. The term printing members refers throughout the specification and claims to printing members used in printing presses operating with an inking fluid. The invention also applies to printed circuit board (PCB) members. BACKGROUND OF THE INVENTION There are two types of printing members typically used in state of the art printing presses, such as gravure, offset lithography, screen and flexo printing presses and described in Figures 1A through 2B. The printing member of Fig. 1A, generally referenced 10, comprises a base layer 2 and a Ultra Violet (UV) curable layer 4. The member 10 is being recorded by applying a mask 6, as also indicated by step 12 (Fig. 1B). The member is being flood exposed to UV light, the mask blocks the UV light from certain parts of the member, the exposed parts 8 are polymerized (step 14 of Fig. 1B), the mask is then being removed (step 16 in Fig. 1B) and the member 10 is being cleaned so that non exposed areas 7 are removed by washing (step 18 in Fig. 1B). In the Example of Fig. 2A, the mask forms part of the printing member 20. The member 20 comprises a base layer 22 and a UV curable layer 24 which may be similar to layers 2 and 4 (Fig. 1A). The layer 24 is being coated with an Infra Red (IR) absorbable UV blocking material 26 (see also 32 in Fig. 2B which represents the member 20 ready for recording), the image is being ablated in a digital pixel by pixel fashion (step 34 of Fig. 2B) and subsequently the entire member is flood exposed to UV light (step 36 of Fig. 2B) which hardens (polymerizes) the areas 28 from which the coating 26 has been removed. The unexposed areas 23 are removed by cleaning thus providing the printing member 20. During printing with both printing members 10 and 20 ink is first applied to the printing member (step 31 of Fig. 3B) and then transferred to the substrate 35 (Fig. 3A) as also indicated in step 33. These types of printing members are also used not as printing members but as Printed Circuit Boards (PCB) members with the addition of a conductive layer. These two types of members are collectively referred to hereinafter as member or members. EP-A-0678380 discloses a lithographic printing member directly imageable by laser discharge, comprising an ink-accepting first layer characterized by ablative absorption of imaging radiation, a second layer underlying the first layer being at least partially soluble in a cleaning solvent, and a hydrophilic metal substrate. The invention provides a member comprising a protective layer for protecting a washable layer during processing of the member by a washing process; an IR ablatable layer; a substrate; and a wash-off layer for being washed with a solvent after imagewise ablation of said protective layer so as to expose said substrate, so that a printing member is produced, wherein either said IR ablatable layer is disposed above protective layer and said wash-off layer is intermediate said protective layer and said substrate, or wherein said IR ablatable layer is disposed below said protective layer and said wash-off layer is intermediate said IR ablatable layer and said substrate. Further, in accordance with a preferred embodiment of the present invention, the IR ablatable layer includes a resinous binder combined with an Infra Red absorbing dye or pigment. The IR ablatable layer may include acrylic or polyurethane resins with carbon black dispersed in resin or nigrosine dissolved in the resinous solution before deposition. Still further, in accordance with a preferred embodiment of the present invention, the thickness of the IR ablatable layer is generally between 0.01 and 5 µm. Additionally, in accordance with a preferred embodiment of the present invention, the protective layer includes a binder resin which is insoluble in the solvent used for wash out either by its nature or by reason of the cross-linking of the resin during the deposition of the layer or a sheet of polymer or the protective layer has been derived from a cross-linkable water soluble melamine derivative plus a suitable cross-linking catalyst, or an aqueous dispersion of polyurethane, cross-linked with a suitable cross-linking material. The cross-linking catalyst may be toluene sulphonic acid Still further, in accordance with a preferred embodiment of the present invention, the thickness of the protective layer is generally between 0.2 and 5 µm. There is also provided in accordance with a preferred embodiment of the present invention a printing member wherein the wash-off layer comprises UV curable materials, which may include an alkali soluble rosin maleic resin esterified with pentaerythritol, an acrylate oligomer, a monomer-acrylate or methacrylate and a photoinitiator such as hydroxymethyl phenylpropane. Still further, in accordance with a preferred embodiment of the present invention, the thickness of the wash-off layer is generally between 0.2 µms and 5 mm. Further, in accordance with a preferred embodiment of the present invention, the substrate is selected from the group of polyester, aluminum, anodized aluminum or copper cladded glass/epoxy resin. There is also provided in accordance with a preferred embodiment of the present invention a printing member wherein the member is a gravure printing member and wherein the thickness of the IR ablatable layer is between 0.01 to 5 µm, the thickness of the protective layer is between 0.2 to 5 µm, the thickness of the wash-off layer is between 30 - 200 µm, and the thickness of the substrate is between 100 - 3,000 µm. There is also provided in accordance with a preferred embodiment of the present invention a printing member wherein the member is an offset lithographic printing member and wherein the thickness of the IR ablatable layer is between 0.1 to 5 µm, the thickness of the protective layer is between 0.2 to 5 µm, the thickness of the wash-off layer is between 0.1 to 1 µm, and the thickness of the substrate is between 150 - 800 µm. Additionally, in accordance with a preferred embodiment of the present invention, there is provided a printing member wherein the member is a screen printing member, the substrate being a screen of woven polyester, cellulose fiber, nylon or stainless steel, wherein the thickness of the IR ablatable layer is generally between 0.1 to 5 µms, the thickness of the protective layer is generally between 0.2 to 5 µm, the thickness of the wash-off layer is generally between 0.1 to 5 µm, and the thickness of the substrate is between 50 - 300 µm , and wherein the wash off layer is within the material of screen. There is also provided in accordance with a preferred embodiment of the present invention a printing member wherein the member is a printed circuit board member or a flexo printing member. Methods for producing the members of the present invention are also disclosed. In a preferred embodiment, the method includes the step of providing the member of the present invention, exposing it to imagwise IR radiation so as to ablate the IR absorbing layer and the protective layer and washing off the washoff layer so as to expose the substrate whereby the member ready to be used as a PCB or a printing member is ready for use. Further, in accordance with a preferred embodiment of the present invention, the step of washing further including the step of mechanically removing the wash-off layer. Moreover, in accordance with a preferred embodiment of the present invention, the method also includes the step of UV curing the member after said step of washing. Still further, in accordance with a preferred embodiment of the present invention, the member also includes a conductive layer and the method further includes the step of etching the electrically conductive layer after the step of washing. Furthermore, in accordance with a preferred embodiment of the present invention, the method further comprising the step of a second washing after the step of etching. BRIEF DESCRIPTION OF THE DRAWINGS The invention is herein described, by way of example only, with reference to the accompanying drawings, wherein: Figs. 1A and 1B are block diagram and schematic cross sectional illustrations, respectively, of a prior art method for producing printing members suitable for use in a printing press; Figs. 2A and 2B are block diagram and schematic cross sectional illustrations, respectively, of another prior art method for producing printing members suitable for use in a printing press; Figs. 3A and 3B are block diagram and schematic cross sectional illustrations, respectively, of the printing process with the printing member of Figs. 1A and 2A; Figs. 4A and 4B are block diagram and schematic cross sectional illustrations, respectively, of a method for producing printing members suitable for use in a printing press according to the present invention; and Figs. 5A and 5B are block diagram and schematic cross sectional illustrations, respectively, of a method for producing members suitable for use as printed circuit boards (PCB) according to the present invention. DETAILED DESCRIPTION OF THE INVENTION Reference is now made to Figs. 4A and 4B which illustrate the printing member of the present invention and the preferred method for producing same. The printing member of Fig. 4A, generally referenced 40, comprises a protective layer which includes an IR ablatable material, a substrate and a wash-off layer intermediate the protective layer and the substrate. The wash-off layer is washed with a solvent after imagewise ablation of the protective layer so as to expose the substrate, so that the printing member is produced ready for printing. In a preferred embodiment, printing member 40 comprises a base layer 42, a washable layer 44, a protective layer 46 and an IR ablatable layer 48. The base layer 42 may be any suitable substrate, such as polyester, polyimide, aluminum, anodized aluminum, screen, such as a woven polyester, stainless steel or cellulose screens, or copper cladded glass/epoxy resin. The base layer 42 is similar to the base layer of printing members 10 and 20 (Figs. 1A and 1B) as prepared for printing. The washable layer 44 may be similar to the UV curable layers 4 and 24 of the prior art printing members 10 and 20, or for the PCB application it may be a washable non UV curable layer. In a preferred embodiment, the wash-off layer comprises UV curable materials and includes an alkali soluble rosin maleic resin esterified with pentaerythritol, an acrylate oligomer, a monomer-acrylate or methacrylate and a photoinitiator such as hydroxymethyl phenylpropane. Preferably, the thickness of said wash-off layer is generally between 0.2 µms and 5 mm. Unlike the prior art members 10 and 20, printing member 40 also includes a protective layer 46 which protects the layer 44 during washing as described in detail hereinbelow with reference to Fig. 4B. The protective layer 46 preferably comprises a binder resin which is insoluble in the solvent used for wash out either by its nature or by reason of the cross-linking of the resin during the deposition of the layer or a sheet of polymer. The protective layer may be derived from a cross-linkable water soluble melamine derivative and a suitable cross-linking material such as toluene sulphonic acid, or an aqueous dispersion of polyurethane, cross-linked with a suitable cross-linking material. The thickness of the protective layer is generally between 0.2 and 5 µms. Printing member 40 also includes an IR ablatable layer 48 which may be similar to IR ablatable layer 26 (Fig.2A). The protective layer 46 and the IR ablatable layer 48 may be reversed so that the protective layer 46 is uppermost and on top of the IR ablatable layer 48. The IR ablatable layer preferably comprises a resinous binder combined with an Infra-red absorbing dye or pigment. The resin may be an acrylic or a polyurethane with carbon black dispersed in the resin or nigrosine dissolved in the resinous solution before deposition. The thickness of the IR ablatable layer 48 is generally between 0.01 and 5 µms. Fig. 4B describes the method of the present invention for recording a latent image on printing member 40. Block 52 represents the member 40 ready for recording. In step 54, printing member 40 is being exposed to imagewise IR laser radiation, for example to pixel by pixel digital information, which ablates both the IR ablatable layer 48 and the protective layer 46. In the non limiting experiments described hereinbelow a Lotem plate setter, commercially available from Scitex Corporation Ltd. of Herzlia, Israel, has been used. In step 56 the washable UV curable layer 44 is being washed by any suitable washing method, such as with water or dilute alkaline or dilute acid or solvent mixtures as known in the art. In the non-limiting experiments described below dilute alkali has been used (Sodium hydroxide dissolved in water). Optionally, mechanical cleaning can be used to assist the chemical washing or to replace it. It will be appreciated that unlike in prior art recording methods, the washing step of the method of the present invention precedes the UV curing step. Thus, the IR ablatable layer of the present invention does not have to be a UV blocking layer as in the case of the prior art recording member 20. Once washed, member 40 may be subjected to UV curing or to printing, depending on the application for which member 40 is used. Printing member 40 may or may not require UV curing after washing as indicated by step 58. For printing applications which require mechanical resistivity of the printing member and resistance to solvents in the printing ink, such as offset lithography, the printing member 40 may be UV cured as indicated by step 60. The printing member 40, now shown as printing member 40A (with or without UV curing) may be used for printing by printing apparatus 100 as indicated by step 62. The following examples illustrate non limiting examples of the printing members of the present invention. In all examples, mixture 1 represents the layer 44, mixture 2 represent the protective layer 46 and mixture 3 represent the IR absorbing layer 48. EXAMPLE 1 - Gravure Printing Plate The following mixture was prepared (all parts by weight); MIXTURE 1 Alsynol RC 12 15.6 parts Ebecryl 1259 8.2 Irgacure 184 0.48 Ethyl Acetate 15 Butyl Acetate 3 Ethyl Alcohol 15 Rose Bengal 0.09 The mixture was stirred until everything was dissolved to give a clear solution. The mixture was coated onto 175 µm polyester with a bar coater and dried in an oven for 2 minutes at 120°C. The resulting dry film was measured as 50 µms thick. The following mixture was then made up; MIXTURE 2 Cymel 373 24 parts Deionised water 46 Cycat 4040 1 part This was bar coated on top of the previous coating and dried at 140°C for 4 minutes to a dry coating weight of 1 gram per square meter. The following mixture was made up; MIXTURE 3 Microlith Black C-WA 100 parts Isopropanol 100 parts The mixture was then bar coated on top of the previous coating to a dry coating weight of 1 gram per square meter measured after drying at 140°C for 4 minutes. The finished plate was then mounted on a machine as described in reference to Fig. 4 and imaged with an Infra Red laser array as described. After imaging the surface of the plate was rubbed with a solution of 0.2 parts of sodium hydroxide dissolved in 31 parts of deionised water. Where there were ablated image areas, the pink first coat was removed, leaving colorless polyester film. The etch solution also removed the black surface layer but left the barrier second layer. The plate was then exposed to W radiation to produce a hard gravure plate with holes corresponding to image areas. The plate was printed by applying gravure ink and wiping with a blade and then impressing paper onto the plate. Hereinbelow, a list of industrial sources of materials mentioned in the example: Alsynol RC 12 Rosin-maleic resin, esterified with pentaerythritol DSM Resins, 3150 AA Hoek van Holland Ebecryl 1259 Aliphatic trifunctional urethane acrylate/methacrylate diluted with 35% HPMA (Hydroxypropyl methacrylate ) UCB Chemicals, Anderlecht St. 33 - B-1620 Drogenbos - Belqium Irgacure 184 1-hydroxy-cyclohexyl-phenyl-ketone, CIBA-Geigy, Corp., CH-4002, Basle, Switzerland. Cymel 373 methoxymethyl methylol melamine in water (85% solution) - Dyno-Cytec, Botleweg 175, 3197 KA Rotterdam, The Netherlands. Cycat 4040 Toluene sulphonic acid cross-linking solution Dyno-Cytec, Botleweg 175, 3197 KA Rotterdam, The Netherlands. Microlith Black C-WA Aqueous dispersion of carbon black with acrylic resin. CIBA-Geigy, Corp., CH-4002, Basle, Switzerland. EXAMPLE 2 The following mixture was prepared; MIXTURE 4 Ethyl Alcohol 200 parts Rose Bengal 0.36 parts Isopropanol 380 parts Ebecryl 1259 200 parts Irgacure 184 1.7 parts BYK 307 1 part Poly Methyl vinyl ether-alt-maleic acid monoisopropyl ester 2 parts The mixture was stirred until everything was dissolved to give a clear solution. The mixture was filtered to remove any extraneous matter and then coated onto 175 µm polyester with a Mayer rod. The coating was left to air dry for half a minute, followed by oven drying for 2 minutes at 120°C. The resulting film was measured as 40 µms thick. The following mixture was then made up; MIXTURE 5. Dehesive 410E 135 parts CAB-O-JET 200 45 Q2-5211 Super Wetting agent 6 Cymel 373 21 Cycat 4045 5.7 Crosslinker V72 30 Each ingredient of the mixture was added in the order as shown, and the complete mixture was then bar coated on top of the previous coating and dried at 140°C for 4 minutes to a dry coating weight of 2 µms. The finished plate was then mounted on a machine as described previously, and imaged with an Infra Red laser array as described. After imaging, the surface of the plate was treated with the following mixture; MIXTURE 6 Deionised water 99 parts Sodium carbonate 0.2 Benzyl alcohol 0.4 Sodium dodecyl laurate 0.2 After 30 seconds, the surface was washed, dried and exposed to UV radiation to produce a gravure plate. The plate was printed by applying gravure ink and wiping it gently with a plastic blade and then impressing paper onto the plate. The following list shows industrial sources of new materials mentioned in the example; BYK 307 Poly Methyl vinyl ether-alt-maleic acid monoisopropyl ester BYK Chemie, Wesel, Germany Aldrich Chemical Co., Milwaukee, Wisconsin, U.S.A. Dehesive 410E - Polydimethyl siloxane emulsion in water Wacker chemle GmbH, Munich, Germany CAB-O-JET 200 Cabot Corporation, Billerca, Massachuetts, US Q2-5211 Super Wetting Agent - Silicone glycol copolymer Dow Corporation, Midland, Ml, USA. Cymel 373 Dyno-Cytec Cycat 4045 Amine blocked P-toluene sulphonic acid, (Dyno-cytec) Crosslinker V72 - Proprietary cross-linker for Dehesive 410E Wacker EXAMPLE 3 - Offset Litho Plate Mixture 1 was wire - rod coated onto 200 µm anodized aluminum to a dry-weight thickness of 1 gram per square meter and dried at 120°C for 1 minute. Mixtures 2 and 3 were then coated onto the surface of the coated plate exactly as described above and the resulting plate imaged and processed as previously described. After processing, the areas where the laser had affected the coating and where the coating had been subsequently cleaned off as described are left with exposed anodized aluminum which is hydrophilic and provide the background of the printing plate. The Mixture 2 surface that remains is oleophilic and provides the image areas of the printing plate. EXAMPLE 4 - Screen Printing Mixture 1 was coated onto a polythene - coated release paper to a dry weight of 30 grams per square meter. The coating was left to air dry for 1 minute and then a polyester mesh screen was laid on top of it and smoothed down with a rubber roller. The composite was then dried in the oven for 2 minutes at 120° C, then treated with Mixtures 2 and 3 and then imaged and washed out as in Example 1. The resulting product was a screen resistant to a large range of solvents after UV curing, and therefore able to be used with a large variety of inks. In one preferred embodiment, the printing member 40 is a gravure printing member, the thickness of its IR ablatable layer is generally between 0.01 to 5 µms, the thickness of its protective layer is generally between 0.2 to 5 µms, the thickness of the wash-off layer is generally between 30 - 200 µms, and the thickness of the substrate is between 100 - 3,000 µms. In another embodiment, the printing member 40 is an offset lithographic printing member, the thickness of the IR ablatable layer is generally between 0.1 to 5 µms, the thickness of said protective layer is generally between 0.2 to 5 µm, the thickness of the wash-off layer is generally between 0.1 to 1 µm, and the thickness of said substrate is between 150 - 800 µms. In another embodiment of the present invention, the printing member 40 is a screen printing member, the substrate being a screen of woven polyester, cellulose fiber, nylon or stainless steel. The thickness of the IR ablatable layer is generally between 0.1 to 5 µms, the thickness of the protective layer is generally between 0.2 to 5 µm, the thickness of said wash-off layer is generally between 0.1 to 5 µm, and the thickness of the substrate is between 50 - 300 µm , and the wash off layer is within the material of screen. In a further embodiment the printing member 40 is a flexo printing member. Reference is now made to Figs. 5A and 5B which are schematic cross sectional illustration and block diagram, respectively, of a member, generally referenced 50, and a method for producing a member suitable for use as a printed circuit board according to the present invention. Member 50 is similar to printing member 40 except that it also includes an electrically conductive metal layer 43, an intermediate substrate 42 and a washable layer 44. For PCB manufacturing applications, layer 42 is laminated or coated usually with copper. As shown in Fig. 5B, steps 52 - 56 for producing printing member 50 are similar to those used for producing printing member40. Member 50 is then etched by any etching method known in the art as indicated by step 68. After etching of layer 43, member 50 may require additional washing (step 70) to remove the portions of washable layer 44 and the protective layer 46 which may remain on top of the copper layer. If such washing is required then these layers are being so washed (step 72). The resulting member 50A is now ready for use (step 74), for example as a circuit board. Alternatively, the etched member 50 is not being washed again (step 72 is omitted) and is used as is, as shown by reference numeral 50B. A non limiting example for producing member 50 is provided below. EXAMPLE 5 - Circuit Board Preparation As shown in Fig. 5A, layer 42 is laminated or coated, usually with copper. All coating and treatment are as in Example 1 but with no UV curing. Instead, the material is soaked in a 30% Ferric Chloride. EXAMPLE 6 The following mixture was prepared; MIXTURE 7 Cymel 385 26.4 parts Deionised water 98.2 Tegowet KL245 2.8 Cycat 4040 1.2 The above mixture was stirred and then bar coated onto an epoxy copper laminate (18 µms thick copper on 100 µms epoxy). The coating was dried in an oven at 140°C for 4 minute to a dried coating weight of 2 gram per square meter. The following mixture was then prepared; MIXTURE 8 Cabojet 200 15.9 parts Neorez 972 9.9 Tegowet KL245 2.0 Water 9.6 Isopropanol 9.9 CX-100 Crosslinker 2.0 The mixture was stirred and bar coated onto the previous mixture coating and dried in the oven at 140°C for 4 minute to a dried coating weight of 1.5 gram per square meter. The resulting plate was imaged and processed as described in Example 1, but with no UV curing. Instead, the material was soaked in 30% Ferric chloride at 50°C until the copper in the imaged areas was entirely etched away. The remaining coatings that had been used to protect the copper during etching were then removed by rubbing with methyl ethyl ketone. The following list shows industrial sources of new materials mentioned in the example; Cymel 385 Methoxymethyl methylol melamine-Dyno-Cytec Tegowet KL245 - polyether siloxane copolymer Tego Chemi Service GmbH, Essen, Germany Neorez 972 - Aqueous colloidal dispersion of polyurethane Zeneca Corporation, Wilmington, Massachussetts, USA CX-100 Crosslinker - Polyfunctional aziridine cross-linker Zeneca While the invention has been described with respect to a limited number of embodiments, it will be appreciated that many variations, modifications and other applications of the invention may be made.

Claims: A member (40) comprising a protective layer (46) for protecting a washable layer during processing of the member by a washing process; an IR ablatable layer (48); a substrate (42); and a wash-off layer (44) for being washed with a solvent after imagewise ablation of said protective layer (46) so as to expose said substrate (42), so that a printing member (40) is produced, wherein either said IR ablatable layer (48) is disposed above protective layer (46) and said wash-off layer (44) is intermediate said protective layer (46) and said substrate (42), or wherein said IR ablatable layer (48) is disposed below said protective layer (46) and said wash-off layer (44) is intermediate said IR ablatable layer (48) and said substrate (42). A member according to claim 1, wherein said IR ablatable layer (48) comprises a resinous binder combined with an Infra Red absorbing dye or pigment. A member according to claim 1 or 2, wherein said IR ablatable layer (48) comprises acrylics or polyurethane resins with carbon black dispersed in resin or nigrosine dissolved in the resinous solution before deposition. A member according to claim 1, 2 or 3, wherein the thickness of said IR ablatable layer is between 0.01 and 5 µm. A member according to any one preceding claim, wherein said protective layer (46) comprises a binder resin which is insoluble in the solvent used for wash out either by its nature or by reason of the cross-linking of the resin during the deposition of the layer or a sheet of polymer. A member according to any one preceding claim, wherein said protective layer (46) has been derived from a cross-linkable water soluble melamine derivative plus a suitable cross-linking catalyst, or an aqueous dispersion of polyurethane, cross-linked with a suitable cross-linking catalyst. A member according to claim 6 wherein the cross-linking catalyst is toluene sulphonic acid A member according to any one preceding claim, wherein the thickness of said protective layer (46) is between 0.2 and 5 µm. A member according to any one preceding claim, wherein said wash-off layer (44) comprises UV curable materials. A member according to any one preceding claim, wherein said wash-off layer (44) comprises an alkali soluble rosin maleic resin esterified with pentaerythritol, an acrylate oligomer, a monomer-acrylate or methacrylate, and a photoinitiator such as hydroxymethyl phenylpropane. A member according to any one preceding claim, wherein the thickness of said wash-off (44) layer is between 0.2 µm and 5 mm. A member according to any one preceding claim wherein said substrate (42) is selected from the group of polyester, aluminum, anodized aluminum, screen or copper cladded glass/epoxy resin. A member according to any one preceding claim, wherein said member (40) is any one of a group of members including a gravure printing member, an offset lithographic printing member, a screen printing member, a printed circuit board member or a flexo printing member. A member according to claim 12, wherein for said gravure printing member, the thickness of said IR ablatable layer (48) is between 0.01 to 5 µm, the thickness of said protective layer (46) is between 0.2 to 5 µm, the thickness of said wash-off layer (44) is between 30 - 200 µm, and the thickness of said substrate (42) is between 100 - 3,000 µm, or wherein for said offset lithographic printing member, the thickness of said IR ablatable (48) layer is between 0.1 to 5 µm, the thickness of said protective layer (46) is between 0.2 to 5 µm, the thickness of said wash-off layer (44) is between 0.1 to 1 µm, and the thickness of said substrate (42) is between 150 - 800 µm. A member according to claim 12, wherein for said screen printing member, said substrate (42) is a screen of woven polyester, cellulose fiber, nylon or stainless steel and the thickness of said IR ablatable layer (48) is between 0.1 to 5 µm, the thickness of said protective layer (46) is between 0.2 to 5 µm, the thickness of said wash-off layer (44) is between 0.1 to 5 µm, and the thickness of said substrate (42) is between 50 - 300 µm, and wherein said wash off layer (44) is within the material of screen. A method for producing a printing member (40) from a member as claimed in any one preceding claim, comprising the steps of: ablating said protective layer (46) by imagewise Infra Red radiation representing an image; washing off said wash-off layer (44) so as to expose said substrate (42), whereby said printing member (40) is produced. A method according to claim 16, wherein said step of washing further comprises the step of mechanically removing said wash-off layer (44). A method according to claim 16, additionally comprising the step of UV curing said member (40) after said step of washing. A method according to claim 16, wherein said member also comprises a conductive layer (43) and wherein said method further comprises the step of etching said conductive layer (43) after said step of washing. A method according to claim 19, additionally comprising the step of a second washing after said step of etching.

Inventors: FIGOV MURRAY, STEINBLATT SERGE, FIGOV, MURRAY, STEINBLATT, SERGE
Applicants: CREO IL LTD, CREO IL. LTD.
Application year: 1999
Main classification: B41C1
IPC codes: H05K3, G03F1