Ink compositions

Abstract: An ink composition comprised of a colorant and a reversible crosslinked component vehicle obtained from the reaction product of an anhydride and an organoamine, and which ink possesses a viscosity of from about 1 mPa.s (centipoise) to about 25 mPa.s (centipoise) at a temperature of from about 125°C to about 185°C. The ink compositions are particularly suitable for use in acoustic ink jet printing.

Description: The present invention is directed to ink compositions and, more specifically, the present invention relates to hot melt inks especially useful for acoustic ink printing, processes and apparatuses. More specifically, the present invention is directed to hot melt acoustic ink compositions wherein there can be generated with such inks excellent developed images with acceptable image permanence, excellent projection efficiency on transparencies without a post fusing step, and excellent crease resistance, and wherein the inks possess acceptable, and in embodiments superior lightfastness and superior waterfastness. Moreover, in embodiments of the present invention there is enabled the elimination, or minimization of undesirable paper curl since water is not present, or very small amounts thereof are selected, in the invention inks, and it is preferred that there be an absence of water, and since water is not present in the inks a dryer can be avoided thereby minimizing the cost of the acoustic ink jet apparatus and process. One advantage of a hot melt ink jet is its ability to print on plain paper since the hot melt ink quickly solidifies as it cools and, since it is waxy in nature, does not normally soak into a paper medium. However, hot melt ink jets can be cumbersome in structure and in design, that is, the associated integrated electronics of a thermal ink jet head are considerably more compact than those of a hot melt ink jet head. While the known ink compositions and processes may be suitable for their intended purposes, a need remains for acoustic hot melt ink compositions suitable for thermal ink jet printing. In addition, there is a need for hot melt ink compositions which are compatible with a wide variety of plain papers. Further, there is a need for hot melt ink compositions which generate high quality, waterfast images on plain papers. There is also a need for hot melt ink jet ink compositions which generate high quality, fast-drying images on a wide variety of plain papers at low cost with high quality text and high quality graphics. Further, there is a need for hot melt ink jet ink compositions which exhibit minimal feathering. Additionally, there is a need for hot melt ink jet ink compositions which exhibit minimal intercolor bleed. There is also a need for hot melt ink jet ink compositions which exhibit excellent image permanence. Additionally, there is a need for hot ink compositions suitable for ink jet printing processes wherein the substrate is heated prior to printing and is cooled to ambient temperature subsequent to printing (also known as heat and delay printing processes). There is also a need for ink compositions suitable for ink jet printing wherein high optical densities can be achieved with relatively low dye concentrations. A need also remains for ink compositions suitable for ink jet printing wherein curling of the substrate, such as paper, subsequent to printing is minimized, or avoided. These and other needs can be achievable with the inks of the present invention in embodiments thereof. One object of the present invention is to provide hot ink jet ink compositions which exhibit low viscosity of from about 1 to about 10 mPa.s (1 to about 10 centipoise) at a temperature of from about 125°C to about 160°C. Another object of the present invention is to provide hot melt ink jet ink compositions which exhibit minimal intercolor bleed. A further object of the present invention is to provide hot melt ink jet ink compositions which exhibit excellent image permanence. A still further object of the present invention is to provide hot ink jet ink compositions that contain no water and which are suitable for use in acoustic ink jet printing processes. According to one aspect of the present invention there is provided an ink composition comprised of a colorant and a reversible vehicle obtained from the reaction product of an anhydride and an organoamine, and which ink possesses a viscosity of from 1 mPa.s (centipoise) to 25 mPa.s (centipoise) at a temperature of from 125°C to 185°C. In embodiments the ink compositions of the present invention comprise a dye or pigment, and a reversible vehicle, and wherein the colorant is present in various effective amounts, such as from 2 to 10 weight percent, and the vehicle is present in an amount of from 60 to 90 weight percent. Embodiments of the present invention include an ink composition comprised of a dye, a reversible vehicle obtained from the reaction of an anhydride and diamine or triamine, and resulting in the equilibria reaction mixture of an organoimide-amine and polyamide. Embodiments of the present invention include an ink composition comprised of a colorant and a reversible crosslinked component vehicle obtained from the reaction product of an anhydride and an organoamine, and which ink possesses a viscosity of from 1 mPa.s (centipoise) to 25 mPa.s (centipoise) at a temperature of from 125°C to 185°C; an ink composition wherein said reversible crosslinked vehicle is obtained from the reaction product of an anhydride like phthalic anhydride and an organoamine, such as a diamine or a triamine, and which reaction product results in a temperature dependent equilibria reaction mixture of an imido amine and polyamide of the structure or wherein R is hydrogen, alkyl, or alkenyl, each with from 1 to 36 carbon atoms, and R 1 is an alkylene or polyoxyalkylene, each with from 2 to 36 carbon atoms; an ink composition wherein the vehicle I or II is comprised of from 75 to 95 percent by weight of polyamide and from 5 to 25 percent by weight of imido amine at a temperature of from 20°C to 100°C, and the vehicle I or II is comprised of from 75 to 95 percent by weight of imido amine and from 5 to 25 percent by weight of polyamide at a temperature of from 120°C to 160°C; an ink composition wherein the anhydride is selected from the group consisting of phthalic anhydride, 3-methylphthalic anhydride, succinic anhydride, 2-alkylsuccinic anhydride such as 2-methylsuccinic anhydride, 2-ethylsuccinic anhydride, 2-propylsuccinic anhydride, 2-butylsuccinic anhydride, 2-octylsuccinic anhydride, 2-stearylsuccinic anhydride, 2-octadecen-2yl-succinic anhydride, 2-decen-2yl-succinic anhydride, and 2-dodecen-2yl-succinic anhydride; an ink composition wherein the polyamide possesses a molecular weight, M w , of from 1,500 to 15,000 grams per mole; an ink composition wherein the ink is a solid at room temperature, 20°C to 40°C; an ink composition wherein said polyamide of I or II is present in an amount of from 60 to 99 weight percent at a temperature of from 20°C to 120°C; an ink composition wherein said polyamide of I or II is present in an amount of from 85 to 97 weight percent at a temperature of from 20°C to 120°C; an ink composition wherein said imido amine of I or II is present in an amount of from 60 to 99 weight percent at a temperature of from 120°C to 165°C; an ink composition wherein said imido amine of I or II is present in an amount of from 85 to 97 weight percent at a temperature of from 120°C to 165°C; a printing process which comprises incorporating into an acoustic ink jet printer an ink comprised of a colorant and a crosslinked reversible vehicle obtained from the reaction product of an anhydride and an organic amine, and which ink possesses a viscosity of from 1 mPa.s (centipoise) to 25 mPa.s (centipoise) at a temperature of from 125°C to 185°C, a viscosity of from 5 mPa.s (centipoise) to 20 mPa.s (centipoise) at a temperature of from 125°C to 185°C, and causing droplets of the ink to be ejected in imagewise pattern onto a substrate; a process which comprises (a) providing an acoustic ink printer having a pool of liquid ink with a free surface, and a printhead including at least one droplet ejector for radiating the free surface of said ink with focused acoustic radiation to eject individual droplets of ink therefrom on demand, said radiation being brought to focus with a finite waist diameter in a focal plane, said ink comprising a colorant and a reversible resin obtained from the reaction product of an anhydride and an organic amine, and which ink possesses a viscosity of from 1 mPa.s (centipoise) to 25 mPa.s (centipoise) at a temperature of from 125°C to 185°C, viscosity of from 5 centipoise to 20 centipoise at a temperature of from 125°C to 185°C, and (b) causing droplets of said ink to be ejected onto a recording sheet in an imagewise pattern at a temperature of from 120°C to 185°C; an ink composition wherein alkyl contains from 1 to 6 carbon atoms; an ink composition wherein alkenyl contains from 1 to 10 carbon atoms; an ink composition wherein R 1 is alkenyl with from 2 to 8 carbon atoms; an ink composition wherein the colorant is a pigment; and an ink composition wherein said organic amine is a tetraamine, a diamine, a triamine or mixtures thereof. The organic amine, preferably an organic diamine, can be selected from the group consisting of 1,2-diaminoethane, 1,2-diaminopropane, 1,4-diaminobutane, 1,5-diaminopentane, 2-methylpentylene diamine, 1,6-diaminohexane, 1,8-diaminooctane, 1,10-diaminodecane, 1,12-diaminododecane, poly(oxyalkyleneoxy)-diamine available from Huntsman Corporation as JEFFAMINE™ 148, 230, 400, 192, 700 and 403, illustrated by the formula wherein R 1 and R 2 are hydrogen or alkyl like CH 3 : and n is 2 to 21; and which diamine is utilized in an amount of, for example, from 0.35 mole equivalent to 0.65 mole equivalent of the vehicle. The anhydride utilized in the preparation of the reversible vehicle can be selected from the group consisting of phthalic anhydride, 3-methylphthalic anhydride, succinic anhydride, 2-alkylsuccinic anhydride such as 2-methylsuccinic anhydride, 2-ethylsuccinic anhydride, 2-propylsuccinic anhydride, 2-butylsuccinic anhydride, 2-octylsuccinic anhydride, 2-stearylsuccinic anhydride. 2-octadecen-2yl-succinic anhydride, 2-decen-2yl-succinic anhydride, 2-dodecen-2yl-succinic anhydride, mixtures thereof, including other known anhydrides, and which anhydride is utilized in an amount of, for example, 0.35 mole equivalent to 0.65 mole equivalent of the vehicle. Examples of the imido amines include N-aminododecyl phthalimide, N'-10-amino-decyl phthalimide, N'-8-amino-octyl phthalimide, N'-6-amino-hexyl phthalimide, N'-5-amino-pentyl phthalimide, N'-4-amino-butyl phthalimide, N'-3-amino-propyl phthalimide, N'-2-amino-ethyl phthalimide, N'-ethyloxyethylamine phthalimide, N'-ethyloxyethyloxyethylamine phthalimide, N'-ethyloxyethyloxyethyloxyethylamine phthalimide, N'-ethyloxyethyloxyethyloxyethyloxyethylamine phthalimide. N'-(polyethyloxy)ethylamine phthalimide, N'-(polypropyloxy)propylamine phthalimide, N'-12-aminododecyl 3-methylphthalimide, N'-(polyethyloxy)ethylamine 3-methylphthalimide, N'-(polypropyloxy)propylamine 3-methylphthalimide, N'-12-aminododecyl succinimide, N'-(polyethyloxy)ethylamine succinimide, N'-(polypropyloxy)propylamine succinimide, N'-12-aminododecyl 2-octylsuccinimide, N'-(polyethyloxy)ethylamine 2-octylsuccinimide, N'-(polypropyloxy)propylamine 2-octylsuccinimide, N'-12-aminododecyl 2-stearylsuccinimide, N'-(polyethyloxy)ethylamine 2-stearylsuccinimide, N'-(polypropyloxy)propylamine 2-stearylsuccinimide, N'-(polyethyloxy)ethylamine 2-octadecen-2yl-succinimide, N'-12-aminododecyl 2-octadecen-2yl-succinimide, N'-12-aminododecyl 2-decen-2yl-succinimide, and N'-12-aminododecyl 2-dodecen-2yl-succinmide, and which amine is preferably present in an effective amount of from 60 to 97 percent by weight of the ink at a temperature of from 120°C to 165°C during jetting from the acoustic printing device onto paper, and present in an amount of from 5 to 35 percent by weight of the ink when the ink is on the paper or substrate, and cooled to a temperature of from 20°C to 45°C. Examples of the polyamide include a poly(N'-12-dodecyl) phthalamide, poly(N'-10-decyl) phthalamide, poly(N'-8-octyl) phthalamide, poly(N'-6-hexyl) phthalamide, poly(N'-5-pentyl) phthalimade, poly(N'-4-butyl) phthalamide, poly(N'-3-propyl) phthalimide, poly(N'-2-ethyl) phthalamide, poly(N'-ethyloxyethyl) phthalamide, poly(N'-ethyloxyethyloxyethyl) phthalamide, poly(N'-ethyloxyethyloxyethyloxyethyl) phthalamide, poly(N'-ethyloxyethyloxyethyloxyethyloxyethyl) phthalamide, poly(N'-(polyethyloxy)ethyl) phthalamide, poly(N'-(polypropyloxy)propyl) phthalamide, poly(N'-12-dodecyl) 3-methylphthalamide, poly(N'-(polyethyloxy)ethyl) 3-methylphthalamide, poly(N'-(polypropyloxy)propyl) 3-methylphthalamide, poly(N'-12-dodecyl) succinamide, poly(N'-(polyethyloxy)ethyl) succinamide, poly(N'-(polypropyloxy)propyl) succinamide, poly(N'-12-dodecyl) 2-octylsuccinamide, poly(N'-(polyethyloxy)ethyl) 2-octylsuccinamide, poly(N'-(polypropyloxy)propyl) 2-octylsuccinamide, poly(N'-12-dodecyl) 2-stearylsuccinamide, poly(N'-(polyethyloxy)ethyl) 2-stearylsuccinamide, poly(N'-(polypropyloxy)propyl) 2-stearylsuccinamide, poly(N'-(polyethyloxy)ethyl) 2-octadecen-2yl-succinamide, poly(N'-12-dodecyl) 2-octadecen-2yl-succinamide, poly(N'-12-dodecyl) 2-decen-2yl-succinamide, and poly(N'-12-dodecyl) 2-dodecen-2yl-succinamide, and which polyamide is preferably present in an effective amount of, for example, from 5 to 65 percent by weight of the ink at a temperature of from 120°C to 165°C during jetting from the acoustic printing device onto paper, and which polyamide is, for example, present in an amount of from 65 to 97 percent by weight of the ink when the ink is on the paper or substrate and cooled to a temperature of from 20°C to 45°C. Examples of colorants, preferably dyes selected for the inks of the present invention, are known, reference the Color Index, and include those as illustrated in U.S. Patent 5,310,887 and, for example, Resorcin Crystal Violet, Orasol Black RL or Intraplast Black RL/Solvent Black 29, Lapranol Black BR, Savinyl Black RLS, Orasol Black RLP, Neozapon Black X57; solvent yellow dyes inclusive of Savinyl Yellow 2 RLS, Savinyl Yellow RLSN, Intraplast Yellow 2GLN, Neozapon Yellow 081, Neozapon Yellow 141, Levaderm Lemon Yellow, Zapon Fast Yellow CGR, Aizen Fast Yellow CGNH, Zapon Yellow 100, Zapon Yellow 157, and Savinyl Yellow RLS; magenta dyes such as Neozapon Red 492, Direct Brilliant Pink B, Savinyl Pink 6 BLS, Savinyl Red 3 BLS, Orasol Red 2 BL, Intraplast Red G (Orasol Red), Savinyl Red BLSN, Savinyl Scarlet RLS, Savinyl Fire Red 3GLS, and Zapon Red 335; cyan dyes such as Orasol Blue 2 GLN, Neozapon Blue 807, Savinyl Blue RLS, Savinyl Blue GLS, Orasol Blue GN, and Losol Blue; brown dyes inclusive of Zapon Brown 187 and Savinyl Brown GLS, Solvent Green 3, Sudan Black B, Ceres Blue 2V, Liquid Oil Jet Black, Macrolex Red G Gram, Macrolex Yellow 3G, Victoria Blue R, available from Bayer AG, Leverkusen, Germany, Morfast Blue 100, Morfast Red 104, and Morfast Red 100, available from Morton International Specialty Chemicals Group, Chicago, IL; mixtures thereof; with preferred dyes in embodiments including Reactint Black 57AB, Reactint Black X40LV, Reactint Blue 17AB, Reactint Blue X3LV, Reactint Blue X19, Reactint Red X26B-50, Reactint Red X520, Reactint Violet X80LT, Reactint Orange X38, and Reactint Yellow X15, all available from Milliken Chemicals. Typically, the dye or pigment is present in the ink in an amount of from 0.01 to 10 percent by weight, preferably from 0.05 to 4 percent by weight, and more preferably from 0.1 to 3 percent by weight, although the amount can be outside these ranges. Specific pigment examples include carbon black, magenta, yellow, cyan pigments, or mixtures thereof selected in effective amounts of, for example, from 1 to 10 weight percent. Optional ink additives include biocides, such as Dowicil 150, 200, and 75, benzoate salts, sorbate salts, present in effective amounts, such as for example an amount of from 0.0001 to 4 percent by weight, and preferably from 0.01 to 2.0 percent by weight; pH controlling agents such as acids; or bases, phosphate salts, carboxylates salts, sulfite salts, amine salts, present, for example, in an amount of from 0 to 1 percent by weight and preferably from 0.01 to 1 percent by weight, based on the weight of the ink components. The inks of the present invention are particularly suitable for printing processes wherein the substrate, such as paper, transparency material, is heated during the printing process to facilitate formation of the liquid crystalline phase within the ink. When transparency substrates are employed, temperatures typically are limited to a maximum of 100°C to 110°C, since the polyester typically employed as the base sheet in transparency sheets tends to deform at higher temperatures. Specially formulated transparencies and paper substrates can, however, tolerate higher temperatures, and frequently are suitable for exposure to temperatures of 150°C or even 200°C in some instances. Typical heating temperatures are from 40°C to 140°C, and preferably from 60°C to 95°C; although the temperature can be outside these ranges. The reversible vehicle can be prepared by reacting an anhydride with an organic diamine compound by a condensation process. In one embodiment of this invention, the reversible vehicle can be prepared, for example, by charging a reactor, such as a 300 milliliter Parr reactor equipped with a distillation apparatus, with from about 0.5 mole equivalent of an anhydride, such as phthalic anhydride or succinic anhydride, with 0.5 mole equivalent of an organic diamine such as 1,12-dodecane diamine, and optionally a condensation catalyst, such as dibutylstannoic acid, at a temperature of from 150°C to 185°C with stirring for a duration of from 3 to 6 hours. During this time, water is collected as a byproduct in the distillation receiver. The reaction mixture is then poured into a pan and allowed to cool to room temperature, about 25°C. The inks of the present invention can be prepared by any suitable method. For example, the inks can be prepared by gently stirring or shaking the individual components, such as melt mixing the vehicle with a colorant at a temperature of from 90°C to 130°C, followed by cooling to about 25°C. EXAMPLE I Synthesis of the reversible vehicle from JEFFAMINE™ EDR-192, a poly(ethylylene glycol) bis(2-aminopropyl ether) of a molecular weight of 192 grams per mole, and phthalic anhydride was accomplished as follows: A 300 milliliter Parr reactor equipped with a mechanical stirrer and a distillation apparatus was charged with 94 grams of JEFFAMINE™ 192 obtained from Huntsman Chemical Company, and 74 grams of phthalic anhydride. The mixture was then heated to 100°C over a 2 hour period, followed by increasing the temperature slowly to 150°C and then to 175°C over a four hour period. The pressure was then reduced from atmospheric pressure to about 0,133 kPa (1 millimeter Hg), and these conditions were maintained for an additional one hour, wherein the total amount of water collected in the distillation receiver during the process was measured to be about 5 milliliters. The pressure was then increased to atmospheric pressure and the product, a viscous liquid, comprised of a mixture of N'-ethyloxyethyloxy ethyloxyethylamine phthalimide and poly(N'-(ethyloxyethyloxy ethyloxy)ethyl) phthalamide, was poured into a metal container and left undisturbed to cool down to room temperature (about 25°C throughout the Examples). EXAMPLE II Synthesis of the reversible vehicle from JEFFAMINE™ D-230, a poly(propylene glycol) bis(2-aminopropyl ether) of molecular weight of 230 grams per mole, and phthalic anhydride was accomplished as follows: A 300 milliliter Parr reactor equipped with a mechanical stirrer and a distillation apparatus was charged with 115 grams of JEFFAMINE™ D-230 obtained from Huntsman Chemical Company, and 74 grams of phthalic anhydride. The mixture was then heated to 100°C over a 2 hour period, followed by increasing the temperature slowly to 150°C and then to 175°C over a four hour period. The pressure was then reduced from atmospheric pressure to about 1 millimeter Hg, and these conditions were maintained for an additional one hour, wherein the total amount of water collected in the distillation receiver during the process was measured to be about 8 milliliters. The pressure was then increased to atmospheric pressure and the product, a viscous liquid comprised of a mixture of N'-(polypropyloxy)propylamine phthalimide and poly(N'-(polypropyloxyl)propyl) phthalamide, was poured into a metal container and left undisturbed to cool down to room temperature. EXAMPLE III Synthesis of the reversible vehicle obtained from JEFFAMINE™ D-400, a poly(propylene glycol) bis(2-aminopropyl ether) of a molecular weight of 400 grams per mole, and phthalic anhydride was accomplished as follows: A 300 milliliter Parr reactor equipped with a mechanical stirrer and a distillation apparatus was charged with 100 grams of JEFFAMINE™ D-400 obtained from Huntsman Chemical Company, and 37 grams of phthalic anhydride. The mixture was then heated to 100°C over a 2 hour period, followed by increasing the temperature slowly to 150°C and then to 175°C over a four hour period. The pressure was then reduced from atmospheric pressure to about 0,133 kPa (1 millimeter Hg), and these conditions were maintained for an additional hour, wherein the total amount of water collected in the distillation receiver during the process was measured to be about 4 milliliters. The pressure was then increased to atmospheric pressure and the product, a viscous liquid comprised of a mixture of N'-(polypropyloxy)propylamine phthalimide and poly(N'-(polypropyloxyl)propyl) phthalamide, was poured into a metal container and left undisturbed to cool down to room temperature. EXAMPLE IV Synthesis of the reversible vehicle obtained from JEFFAMINE™ T-403, a poly(propylene glycol) tris(2-aminopropyl ether) of molecular weight of 403 grams per mole, and phthalic anhydride was accomplished as follows: A 300 milliliter Parr reactor equipped with a mechanical stirrer and a distillation apparatus was charged with 100.8 grams of JEFFAMINE™ T-403 obtained from Huntsman Chemical Company, and 37 grams of phthalic anhydride obtained from Fisher Chemical Company. The mixture was then heated to 100°C over a 2 hour period, followed by increasing the temperature slowly to 150°C and then to 175°C over a four hour period. The pressure was then reduced from atmospheric pressure to about 0,133 kPa (1 millimeter Hg), and these conditions were maintained for an additional one hour, wherein the total amount of water collected in the distillation receiver during the process was measured to be about 4 milliliters. The pressure was then increased to atmospheric pressure and the product, a viscous liquid comprised of a mixture of N'-(polypropyloxy)propylamine phthalimide and poly(N'-(polypropyloxyl)propyl) phthalamide, was poured into a metal container and left undisturbed to cool down to room temperature. EXAMPLE V Synthesis of the reversible vehicle generated from 1,12-dodecanediamine and phthalic anhydride was accomplished as follows: A 300 milliliter Parr reactor equipped with a mechanical stirrer and a distillation apparatus was charged with 66.8 grams of 1,12-dodecanediamine obtained from E.I. DuPont and 49.4 grams of phthalic. The mixture was then heated to 100°C over a 2 hour period, followed by increasing the temperature slowly to 150°C and then to 175°C over a four hour period. The pressure was then reduced from atmospheric pressure to about 0,133 kPa (1 millimeter Hg), and these conditions were maintained for an additional hour, wherein the total amount of water collected in the distillation receiver during the process was measured to be about 5 milliliters. The pressure was then increased to atmospheric pressure and the product comprised of a mixture of N'-(12-aminododecyl) phthalimide and poly(N'-12-dodecyl) phthalamide, was poured into a metal container and left undisturbed to cool down to room temperature. EXAMPLE VI Synthesis of the reversible vehicle polymer generated from 1,12-dodecanediamine and dodecenyl succinic anhydride was accomplished as follows: A 300 milliliter Parr reactor equipped with a mechanical stirrer and a distillation apparatus was charged with 66.8 grams of 1,12-dodecanediamine obtained from E.I. DuPont, and 88.7 grams of dodecenyl succinic anhydride obtained from Lonza. The mixture was then heated to 100°C over a 2 hour period, followed by increasing the temperature slowly to 150°C and then to 175°C over a four hour period. The pressure was then reduced from atmospheric pressure to about 0,133 kPa (1 millimeter Hg), and these conditions were maintained for an additional hour, wherein the total amount of water collected in the distillation receiver during the process was measured to be about 5 milliliters. The pressure was then increased to atmospheric pressure and the product comprised of a mixture of N'-(12-aminododecyl) 2-stearylsuccinimide and poly(N'-12-dodecyl)2-stearylsuccinamide was poured into a metal container and left undisturbed to cool down to room temperature. Viscosity Measurements The rheological characterization, and more specifically, the viscosity of the above prepared vehicles was performed using the Carri-Med CSL-100 controlled stress rheometer using a 4 centimeter, 2 degree cone and plate geometry. Example Viscosity (mPa.s (cp)) at 160°C I 13 II 13 III 8 IV 10 V 15 The vehicles were melt mixed with 5 percent by weight of Neopan Blue dye to form inks, and each ink was incorporated into an acoustic ink jet printing test fixture utilizing the ejection mechanism disclosed in J . Appl . Phys . 65(9), 1 May 1989, and references therein. A jetting frequency of 160 MHz was used to generate drops of about 2 picoliters, up to 12 drops per pixel at 236 dots/cm (600 dpi). The images formed exhibited excellent quality, high definition, sharp edges, and waterfastness.

Claims: An ink composition comprising a colorant and a reversible component vehicle obtainable from the reaction of an anhydride and an organoamine, and which ink possesses a viscosity of from 1 mPa.s (centipoise) to 25 mPa.s (centipoise) at a temperature of from 125°C to 185°C. An ink composition in accordance with claim 1 wherein said reversible vehicle is obtainable from the reaction of an anhydride and an organoamine, and which reaction product results in a temperature dependent equilibria reaction mixture of an imido amine and polyamide or wherein R is hydrogen, alkyl, or alkenyl, each with from 1 to 36 carbon atoms, and R 1 is an alkylene or polyoxyalkylene, each with from 2 to 36 carbon atoms. An ink composition in accordance with claim 2 wherein the vehicle I or II comprises from 75 to 95 percent by weight of polyamide and from 5 to 25 percent by weight of imido amine at a temperature of from 20°C to 100°C, and the vehicle I or II comprises from 75 to 95 percent by weight of imido amine and from 5 to 25 percent by weight of polyamide at a temperature of from 120°C to 160°C. An ink composition in accordance with claim 1 wherein the anhydride is selected from the group consisting of phthalic anhydride, 3-methylphthalic anhydride, succinic anhydride, 2-alkylsuccinic anhydride, 2-methylsuccinic anhydride, 2-ethylsuccinic anhydride, 2-propylsuccinic anhydride, 2-butylsuccinic anhydride, 2-octylsuccinic anhydride, 2-stearylsuccinic anhydride, 2-octadecen-2yl-succinic anhydride, 2-decen-2yl-succinic anhydride, and 2-dodecen-2yl-succinic anhydride. An ink composition in accordance with claim 2 wherein the organoamine is an organic diamine of 1,2-diaminoethan, 1,2-diaminopropane, 1,4-diaminobutane, 1,5-diaminopentane, 2-methylpentylene diamine, 1,6-diaminohexane, 1,8-diaminooctane, 1,10-diaminodecane, 1,12-diaminododecane, or poly(oxyalkyleneoxy)-diamine of the formula wherein R 1 and R 2 are hydrogen or alkyl; and n is a number of from 2 to 21. An ink composition in accordance with claim 2 wherein the imido amine is selected from the group consisting of N-aminododecyl phthalimide, N'-10-aminodecyl phthalimide, N'-8-amino-octyl phthalimide, N'-6-amino-hexyl phthalimide, N'-5-amino-pentyl phthalimide, N'-4-amino-butyl phthalimide, N'-3-amino-propyl phthalimide, N'-2-amino-ethyl phthalimide, N'-ethyloxyethylamine phthalimide, N'-ethyloxyethyloxyethylamine phthalimide, N'-ethyloxyethyloxyethyloxyethylamine phthalimide, N'-ethyloxyethyloxyethyloxyethyloxyethylamine phthalimide, N'-(polyethyloxy)ethylamine phthalimide, N'-(polypropyloxy)propylamine phthalimide, N'-12-aminododecyl 3-methylphthalimide, N'-(polyethyloxy)ethylamine 3-methylphthalimide, N'-(polypropyloxy)propylamine 3-methylphthalimide, N'-12-aminododecyl succinimide, N'-(polyethyloxy)ethylamine succinimide, N'-(polypropyloxy)propylamine succinimide, N'-12-aminododecyl 2-octylsuccinimide, N'-(polyethyloxy)ethylamine 2-octylsuccinimide, N'-(polypropyloxy)propylamine 2-octylsuccinimide, N'-12-aminododecyl 2-stearylsuccinimide, N'-(polyethyloxy)ethylamine 2-stearylsuccinimide, N'-(polypropyloxy)propylamine 2-stearylsuccinimide, N'-(polyethyloxy)ethylamine 2-octadecen-2yl-succinimide, N'-12-aminododecyl 2-octadecen-2yl-succinimide, N'-12-aminododecyl 2-decen-2yl-succinimide, and N'-12-aminododecyl 2-dodecen-2yl-succinimide. An ink composition in accordance with claim 2 wherein said polyamide is poly(N'-12-dodecyl) phthalamide, poly(N'-10-aminodecyl) phthalamide, poly(N'-8-octyl) phthalamide, poly(N'-6-hexyl) phthalamide, poly(N'-5-pentyl) phthalamide, poly(N'-4-butyl) phthalamide, poly(N'-3-propyl) phthalimade, poly(N'-2-ethyl) phthalamide, poly(N'-ethyloxyethyl) phthalamide, poly(N'-ethyloxyethyloxyethyl) phthalamide, poly(N'-ethyloxyethyloxyethyloxyethyl) phthalamide, poly(N'-ethyloxyethyloxyethyloxyethyloxyethyl) phthalamide, poly(N'-(polyethyloxy)ethyl) phthalamide, poly(N'-(polypropyloxy)propyl) phthalamide, poly(N'-12-dodecyl) 3-methylphthalamide, poly(N'-(polyethyloxy)ethyl) 3-methylphthalamide, poly(N'-(polypropyloxy)propyl) 3-methylphthalamide, poly(N'-12-dodecyl) succinamide, poly(N'-(polyethyloxy)ethyl) succinamide, poly(N'-(polypropyloxy)propyl) succinamide, poly(N'-12-dodecyl) 2-octylsuccinamide, poly(N'-(polyethyloxy)ethyl) 2-octylsuccinamide, poly(N'-(polypropyloxy)propyl) 2-octylsuccinamide, poly(N'-12'-dodecyl) 2-stearylsuccinamide, poly(N'-(polyethyloxy)ethyl) 2-stearylsuccinamide, poly(N'-(polypropyloxy)propyl) 2-stearylsuccinamide, poly(N'-(polyethyloxy)ethyl) 2-octadecen-2yl-succinamide, poly(N'-12-dodecyl) 2-octadecen-2yl-succinamide, poly(N'-12-dodecyl) 2-decen-2yl-succinamide, or poly(N'-12-dodecyl) 2-dodecen-2yl-succinamide. An ink composition in accordance with claim 1 wherein the vehicle is solid at about 25°C, and liquid at jetting temperatures of from 120°C to 165°C. An ink composition in accordance with any of claims 1 to 8 wherein said colorant is a dye present in an amount of from 0.05 to 20 weight percent, based on the weight of the ink components. A printing process which comprises incorporating into an acoustic ink jet printer an ink in accordance with any of claims 1 to 9, and causing droplets of the ink to be ejected in imagewise pattern onto a substrate.

Inventors: DRAPPEL STEPHEN V, KOVACS GREGORY J, MAYER FATIMA M, PAINE ANTHONY J, SACRIPANTE GUERINO G, DRAPPEL, STEPHEN V., KOVACS, GREGORY J., MAYER, FATIMA M., PAINE, ANTHONY J., SACRIPANTE, GUERINO G.
Applicants: XEROX CORP, XEROX CORPORATION
Application year: 1998
Main classification: C09D11
IPC codes: C09D11, B41M5