PROCESS FOR PURIFICATION OF WASTE WATERS AND CONTAMINANT SPILLS BASED ON THE USE OF CULTIVATED EMERGENT MACROPHYTES CONVERTED INTO FLOATING CULTURES

Abstract: The present invention relates to a system for the purification of residual waters and contaminants effluents based on the use of aquatic plants of the type of emergent macrophytes which have been conditioned in order to keep floating at the surface of channels, ducts, lagoons or ponds where contaminated water flows. The plants form a mantle floating on the water surface, while keeping immersed the root system, and the rhizones and the basis of the stems. The immersed portion has a large specific surface to which an abondant microbial flora is fixed and of which the growth is enhanced by the oxygen pumped towards that area by the leaves. The assembly formed by the roots and the micro-organisms acts as a filter which eliminates the organic dissolved material in addition to mineral compounds (phosphor and nitrogen, amongst others) which are absorbed mainly by the plants. Periodically, the floating biomass can be easily removed and used for energetic or industrial purposes.

Description: TECHNICAL ASPECTS This process is applicable to Domestic and industrial wastewater treatment, Treatment of eutrophicating effluents, Treatment of effluents containing pollutants which can be removed by aquatic macrophytes PRIOR STATE OF THE ART Conventional wastewater treatment processes are capable of removing organic matter by means of the sedimentation of the suspended solids during the primary treatment and by means of microorganisms fixed to inert media or free in the water which is subjected to natural or artificial aeration in the secondary treatment. The removal of mineral elements (tertiary treatment) is a highly expensive process if carried out using conventional processes (chemical precipitation), as a result of which a large majority of treatment plants do not avail of this type of treatment and discharge water rich in mineral elements, which contributes to the eutrophication of the watercourses and reservoirs (mainly due to the nitrogen and phosphorus involved). Environmental Protection laws are becoming progressively more stringent with regard to requiring that the concentration of these elements in the waters discharged into public watercourses be lowered. What are known as "Green Filter" treatment systems employ inert media such as peat or plant species grown in specific soils or substrates (gravel or sand in most cases) onto which the effluents are discharged. Some of these systems employ "emergent macrophyte" plants which grow naturally along the riverbanks and in marshlands, but are always conceived as rooted in the soil or in an inert substrate, as a result of which the surface area of the roots in contact with water is quite a great deal less than in the case of a floating root system which is bathed all over by water. Another drawback involved in these systems based on plants which have taken root is how difficult it is to harvest all of the plant matter produced (which contains all of the mineral elements removed from the water), given that solely that part which is above the water line is harvested , the biomass of the roots and of the base of the stems remaining in the soil. The treatment systems based on the use of floating plants have employed species which are buoyant by nature, such as the water hyacinth ( Eichornia crassipes ) or the Lemnaceae (genuses Lemma, Wolffia, Spirodella, etc.), but have not afforded good . results. For example, the water hyacinth, which is a tropical species, can cover completely channels and wetlands if it is allowed to grow out of control as a result of its being fast-spreading; and in mild, continental zones, it dies off in the wintertime. As far as the Lemnaceae and other similar species are concerned, due to the fact that they are not extremely high-yield, their water treatment effect is also scant. The method proposed by the patent JP-09-029283 titled "water purifying device using aquatic plant" consists of putting the aquatic plant on a purifying element formed by a "net" like container and a series of floating elements which allow the container to float. The method proposed by our invention does not need that kind of elements or any other permanent floating support. So that, the plants can float during the treatment process. DESCRIPTION OF THIS INVENTION System for the treatment of wastewater and pollutant effluents based on the use of "emergent macrophyte" water plants which are produced and conditioned especially so that they will remain afloat in channels through which wastewater flows or in lagoons or ponds/tanks into which this water is flows. For each case, the macrophyte which best suits the conditions in each individual spot and the type of pollutant(s) to be treated will be employed. This system can be used for tertiary treatment (removal of eutrophicating mineral elements) in the secondary effluents of conventional treatment systems and can also be used for secondary treatment purposes (breakdown of dissolved organic matter) by means of the microorganisms adhered to the plant root system. This system can also aid in the reduction of the suspended solids on adhering to the root system and thus aid in the attack of the organic matter contained in these solids on the part of the microorganisms attached to the roots of these plants which have a large specific surface area. This system can also be used for treating eutrophicated agricultural effluents or effluents from industries which discharge wastewater rich in nitrogen and/or phosphorus and/or potassium, as well as for the treatment of spring waters polluted with any or all of these elements. Some species of emergent plants possess the ability to decontaminate waters laden with some toxic compounds such as phenols and to absorb major quantities of heavy metals, as a result of which this system would also be suitable for treating effluents containing these types of pollutants, provided that the plant species to be employed are suitably selected. The core of this system is comprised of a floating bed or cover of vegetation formed on the surface of a channel or lagoon, the basic components of which are the plants (species selected from among the "emergent" type which are adapted to the enviromental conditions of the particular site) which are going to have their root systems and a portion of the base of the stem under the water. Most of the aquatic plants will also have rhizomes (plant reproductive organs from which new sprouts emerge and which contain an abundant amount of carbohydrates as a reserve food supply) which are submerged under the water along with the roots and attached to the base of the stem from which they grow. The entire underwater surface of the plant is large in surface area due mainly to the many roots and radicles, which serve as a base for the attaching of the microorganisms that break down the organic matter, aided by the oxygen that plants pump from the leaves to and through the roots (a specific property of emergent plants). Emergent macrophytes, such as rushes (Juncus subulatus Forskal, Juncus maritimus Lam., Juncus acutus L., Juncus litoralis C.A. Meyer, Juncus effusus L., Juncus conglomeratus L., Scirpus holoschoenus L., Scirpus maritimus L., Scirpus litoralis Schrader, Scirpus triqueter L., Cyperus serotinus Rotth., Cyperus longus L., Schoenus nigricans L.), bulrushes or reed maces (Typha angustifolia L., Typha latifolia L., Typha domingensis (Pers) Steudel, Typha minima Funck in Hoppe), reeds (Phragmites australis (Cav.) Trin. ex Steudel) and Sparganiaceae (Sparganium erectum L., Sparganium emersum Rehmann, Sparganium angustifolium Michx and Sparganium minimum Wallr) leaf out somewhat at the top and are not as dense as the whole, as a result of which, in order for this type of plants to float and grow, it is necessary to achieve that the portion located under water form a base strong enough and spread out far enough over the surface to allow the leaves and stems to develop above water level and to grow to their natural height, preventing the tendency to fall over into the water and float on its side which a single plant alone would have. The innovation entailed in the system described hereunder consists of achieving that the plants which are naturally rooted in the soil of the beds of watercourses or along their banks will grow and live out their life cycle floating on top of the water flowing through a channel or which is impounded in a pond or lagoon, provided that the pond or lagoon be deep enough (generally speaking, 25-50 cm. in depth). In short, this involves constructing a floating bed comprised of the underwater plant organs (bases of stems, rhizomes and roots) intertwined naturally as a result of their growth. Young plants in growing stage or rhizomes must be used for rapid floating bed establishment. These plants or rhizomes must be attached to a floating bed structure separately or be spaced apart from one another at a suitable distance (approx. 10-30 cm. apart) so as to allow the roots systems of adjacent plants to intertwine. How fast this cover will form will depend greatly upon how far apart the plants or rhizomes are set into place on the floating bed structure. Some emergent plants (i.e. reeds) have a tube-like stem (hollow stalk) which can float lying on its side in the water without requiring any bed structure and give off shoots from buds located on the nodes and roots. The formation of the floating cover directly on a watercourse requires that both the floating bed structures and the tube-like stems of the macrophytes, in the case that said macrophytes are employed, must be anchored to prevent the plants from being swept along by the current. A similar process must be employed for ponds or lagoons if there is a possibility that the wind may blow away the plants. For systems requiring a large number of plants for initially forming the floating cover, the most highly recommended procedure is the use of nursery-grown plants in a substrate suitably weighted so that the plants will stay upright from the very time at which they are set into place. The weight of the substrate including the root-ball of the plant plus the weight of the plant must be slightly heavier than the force exerted on the submerged volume by the water. Although the type and shape of the floating bed structure may vary to accomplish the desired purposes (growth of the floating cover), generally speaking, it is preferable to use low-density linear bed structures which can be anchored to the sides or to the ends of the channel or to the banks of the ponds or lagoons. In the case of very long channels, the anchoring of linear bed structures, when running lengthwise, can be done in sections. One type of low-density, linear, floating bed structure easy to obtain in sufficient quantities at a reasonable price is that of 12 mm or 16 mm low-pressure polyethylene tubing commonly used for drip irrigation. To facilitate the ready placement of the plants or rhizomes on the floating bed structures, each plant must be delivered on site at the channel with the attachment system incorporated. As a plant attachment system, fine wire (smaller than 1 mm-gauge) with one end wound around the root system or the leaves of the plant and the other ending in a clip or similar means of ready attachment or left free to be used for attaching the plants readily to the floating bed structure. Apart from its water treatment effect, this system affords the possibility of producing biomass for energy production or industrial purposes in an amount far greater than any crop-raising done on land. In the case of reed mace, an annual yield of 2.23 kg/m2 of dry matter is estimated for the part of the plant growing above water, which would be the same as saying that a quantity of biomass possessing a heat capacity approximately equal to that which can be supplied by 1 liter of petrol, is produced. As far as the sugars and starch contained in the rhizomes are concerned, the annual production can be estimated at 1 kg/m2. One use for the carbohydrates contained in the rhizomes would consist of the manufacture of ethanol. Some of this system's major advantages over the treatment systems which employ emerging macrophytes rooted in the soil or substrate include its being: More economical to get under way. Easier to get under way, given that this can be done on the channel or pond proper without requiring any draining and regardless of the depth of the water layer. Greater treatment capacity as a result of the root system being fully in contact with the water. Easy to harvest all of the biomass grown in those cases in which one wishes to remove mineral elements fixed by the plants or to make use of the biomass formed for energy-producing or industrial purposes. In the event that plants producing starchy rhizomes (i.e. bulrushes, etc.), this system provides for ready harvesting of these rhizomes in conjunction with the portion of the plants located above water level, this being something which is more difficult to do when the rhizomes are located down under the soil on the channel bottom or in a bed of peat or gravel, as is normally the case in the conventional systems. This system affords the possibility of using the rhizomes in industry, mainly for the production of starch or the derivatives thereof, one of which is ethanol. DETAILS OF THE EMBODIMENT A description is provided in following, in the form of an example for illustrative purposes, of the embodiment of a wastewater treatment system for a population of 1,000 inhabitants. This description is provided based on the premise that 2.5 m 2 of surface area of floating filter comprised of bulrush ( Typha latifolia) plants is required for the treatment of the wastewater generated by each inhabitant. Building the Channel. Based upon the aspects set forth hereinabove, a channel or pond surface of 2,500 m 2 (0.25 hectares) would be required for installing the floating filter. This process would begin with the pertinent earthwork, ensuring that the bottom of the channel were not graded on more than a 1° slope, installing the pertinent chutes if it were to be necessary to make provision for uneven terrain. The channel may vary in width depending upon the lay of the land, it being recommended that it measure 2m-3m in width so as to provide for the convenient harvesting of the biomass grown. The excavation must be done to a minimum depth of 50 cm, the edges be raised to approx. 30 cm above the surface of the terrain in order to prevent the falling in of soil or other objects. Both the sides and bottom of the channel must be covered with a sheet of plastic or any waterproofing component to prevent the plants from taking root. The channel can also be built out of concrete or prefabricated components, although this can make the building process most expensive. So that the water layer will always be a minimum of 30 cm in height, depending upon the slope of the channel, locks or sluices are to be installed at the required distances. Hence, in order to keep the water at depths of 30 cm - 50 cm. (for example) in a channel which is sloped at a 1° angle at the bottom, sluices measuring 50 cm in height should be installed every 20 m. For the case of a width of 2.5 m, a total length of 1,000 m would be necessary, which could be built following the natural course of the drainage flow. Preparation of the Plants from Seeds. The bulrush seeds are to be initially sown in flats and, following approximately one month of growth, are to be transplanted to 4 x 4 seedling starter pack containers 7 cm in depth filled with a substrate comprised of peat - topsoil - sand in a 1-1-2 proportion in volume. When preparing the seedling starter pack containers with the pertinent substrate, a 0.5 mm-gauge annealed iron wire measuring 15-20 cm in length bent at a right angle approx. 5 mm from the lower tip is inserted to facilitate the intertwining of the root-ball of the plant. In addition to providing the iron which the young plant needs for growth, this wire is going to serve as the basis for attaching the plant to the floating bed structure when it is being put into place on the channel. Following 2-3 month of growth, the plants will be ready to be moved to the channel. The best time of year for setting them out is in the springtime, in order to foster the forming of the floating cover by taking advantage of the active growth period. Setting the Plants Out on the Channel. As the floating bed structures, 12 mm low-pressure polyethylene tubing (of the type used for drip irrigation) is to be used and laid along each section of the channel, then secured to both ends. To achieve a ready formation of the floating cover, it is recommended that the floating bed structures be spaced approx. 50 cm apart. In a channel 2.5 m in width, it would be necessary to install 5 lengthwise bed structures. The initial spacing of the plants on each bed structure would be approx. 25 cm. apart. The plants, which are to already be fitted with the device for securing them to the bed structure (wire wound around the root-ball of the plant), are to be secured by means of an easy-to-handle system, the root-ball of each plant serving to weight the plants down at the bottom to keep them upright. Depending on the temperature conditions of the area in question, the cover may take 3-6 months for full growth. For a relatively fast first planting, approx. 8-10 plants per m 2 will be required. The wire employed will remain intact long enough to allow the floating cover to grow. After a certain length of time, the wire completely breaks down, at which time the polyethylene tubing bed structures can be removed leaving the cover comprised solely of plant matter in place. Removing the Biomass. At the end of the growing period, the portion of the plants located above water level can be cut and all or part of the floating cover removed, although it can be left in place for several years. Dry biomass of the part above water level can be used for energy-producing purposes (burning), for crafts (mainly chair seats), as building insulation, as a raw material for paper stock or as a binder for making lightweight panels used in the construction industry. Biomass located under water contains rhizomes rich in starch, the industrial use of which depends upon the total volume of the yield and upon the existence of the pertinent processing industry.

Claims: A process for treating wastewater comprising the step of providing a floating bed of emergent macrophyte aquatic plants on the surface of said wastewater, characterized by a removable floating support needed to facilitate the roots and rhizomes of the plants intertwining, and afterwards the support can be removed leaving the intertwined plants float by themselves, and by a floating bed made of emergent macrophyte aquatic plants whose roots and rhizomes, once they are intertwined, float by themselves, without any kind of support. A process according to c la im 1 characterized by emergent macrophyte aquatic plants selected from the group consisting of rushes ( Juncus subulatus Forskal, Juncus maritimus Lam., Juncus acutus L., Juncus litoralis C.A. Meyer, Juncus effusus L., Juncus conglomeratus L., Scirpus holoschoenus L., Scirpus maritimus L., Scirpus litoralis Schrader, Scirpus triqueter L., Cyperus serotinus Rotth., Cyperus longus L., Schoenus nigricans L.), bulrushes or reed maces ( Typha angustifolia L., Typha latifolia L., Typha domingensis (Pers) Steudel, Typha minima Funck in Hoppe), reeds ( Phragmites australis (Cav.) Trin. ex Steudel) and Sparganiaceae ( Sparganium erectum L., Sparganium emersuadim Rehmann, Sparganium angustifolium Michx and Sparganium minimum Wallr). A process according to claim 1 characterized by the depth of said wastewater is at least 25 cm.

Inventors: FERNANDEZ JESUS, FERNANDEZ, JESUS
Applicants: UNIV MADRID POLITECNICA, UNIVERSIDAD POLITECNICA DE MADRID
Application year: 1998
Main classification: C02F3
IPC codes: C02F3