A flame retardant resin composition

Abstract: A flame retardant resin composition comprises 100 parts by weight of the following component (A) or (B) and 0.01 to 30 parts by weight of red phosphorus (C). Mouldings obtained from it are suitable for mechanical parts, electric and electronic parts, automobile parts, and housings and other parts of office automation apparatuses and household electric appliances. Components (A) and (B) are: (A) (a1) 67 to 99.99 wt% (based on the total weight of (a1) and (a2)) of a thermoplastic resin other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers and (a2) 33 to 0.01 wt % (based on the total weight of (a1) and (a2)) of polyethylene terephthalate homopolymer and/or an ethylene terephthalate copolymer; and (B) a thermoplastic resin comprising the following structural components (I), (II), (III) and (IV): where each of R1, R2 and R3, independently, is a divalent aromatic residue.

Description: The present invention relates to a flame retardant resin composition adopting a non-halogen based flame retardant agent. In more detail, it relates to a flame retardant resin composition excellent in flame retardancy, mechanical properties, wet heat resistance and electric properties and suitable for mechanical parts, electric and electronic parts, automobile parts, housings and other parts of, for example, office automation apparatuses, household electric appliances. Thermoplastic resins such as polyester resins, polyamide resins and ABS resins are being used as injection molded materials in a wide range of fields such as mechanical parts, electric and electronic parts, automobile parts, office automation apparatuses and household electric appliances because of their excellent properties. On the other hand, these thermoplastic resins are inherently combustible, and when they are used as industrial materials, they are often required to be safe against flames, i.e., flame retardant, in addition to being well balanced in physical properties. Especially as for flame retardancy, in recent years, since moldings are reduced in weight and size, hence also in thickness, thin moldings are required to be highly flame retardant. Thermoplastic resins are generally made flame retardant by compounding a halogen based organic compound as a flame retardant agent and an antimony compound as a flame retardation assistant into the resin. However, this method tends to evolve a large amount of smoke at the time of burning. So in recent years, it has been strongly desired to use a flame retarding agent free from any halogen based compound. For making a thermoplastic resin flame retardant without using any halogen based flame retardant agent, it is widely known to add a hydrated metal compound such as aluminum hydroxide or magnesium hydroxide, but to achieve satisfactory flame retardancy, the hydrated metal compound must be added in such a large amount as to impair disaavantageously the properties peculiar to the resin. On the other hand, as a method for making a combustible resin flame retardant without using such a hydrated metal compound, the use of red phosphorus is disclosed in, for example, JP-A-60-168758, JP-A-61-219706, JP-A-63-089567, JP-A-01-129061, JP-A-02-169666, JP-A-03-197553, JP-A-06-009887, JP-A-06-145504 and JP-A-06-263983. However, although these publications disclose a flame retarding method of adding red phosphorus to a combustible resin, for example, adding red phosphorus to PET, they do not disclose the use of PET and/or (co)PET for making a combustible resin flame retardant, the use of PET/(co)PET/red phosphorus as a flame retardant agent of a combustible resin, or a combination of a liquid crystal polyester with a specific structure and red phosphorus. Furthermore although the resin compositions obtained by these methods show excellent flame retardancy when the moldings obtained from them are thick 1-6mm (1/16"), they are not sufficient in flame retardancy when the moldings obtained from them are thin 0.8 mm (1/32"), contrary to the demand in recent years for resins. Furthermore, these resin compositions present problems in that they are lowered in mechanical properties because of the flame retardant agent contained, and in that the flame retardant agent bleeds out during dry heat or wet heat treatment, to contaminate the electric contacts of connectors. The present invention addresses the problem of providing a flame retardant resin composition containing a non-halogen based flame retardant agent, which is highly flame retardant irrespective of whether it is molded into a thick product 1.6 mm (1/16") or thin product 0.8 mm (1/32"), excellent in mechanical properties, wet heat resistance, impact resistance and electric properties, and suitable for mechanical parts, electric and electronic parts, automobile parts, and housings and other parts of office automation apparatuses and household electric appliances. In a first aspect, the present invention provides the following. (1) A flame retardant resin composition, comprising 100 parts by weight of the following component (A) and 0.01 to 30 parts by weight of red phosphorus (C): (A) (a1) 67 to 99.99 wt% (based on the total weight of (a1) and (a2)) of a thermoplastic resin which is selected from a non-liquid crystal polyester other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers, a polyamide resin and a styrene based resin, and (a2) 33 to 0.01 wt% (based on the total weight of (a1) and (a2)) of polyethylene terephthalate homopolymer and/or an ethylene terephthalate copolymer. The red phosphorus is covered with a thermosetting resin. The electric conductivity of the red phosphorus (as defined hereinafter) is 0.1 to 1000µs/cm. Embodiments of the present invention provide: (2) A flame retardant resin composition as stated in (1) above wherein the thermoplastic resin (a1) other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers is polybutylene terephthalate. (3) A flame retardant resin composition as seated in (1) above wherein the thermoplastic resin (a1) is a polyamide. (4) A flame retardant resin composition, as stated in (3) above wherein the polyamide is one or more polyamide components selected from nylon 6, nylon 66 and their copolymers. (5) A flame retardant resin composition, as stated in (1) above wherein the thermoplastic resin (a1) is a styrene based resin. As stated above, in the present invention the red phosphorus is covered with a thermosetting resin. and the electric conductivity of the red phosphorus is 0.1 to 1000 µS/cm. The electric conductivity refers to the electric conductivity of the extract obtained by adding 100 ml of pure water to 5 g of red phosphorus, treating the mixture at 121°C for 100 hours, filtering away red phosphorus, and diluting the filtrate to 250 ml. (6) A flame retardant resin composition, as stated in (1) above which additionally contains a metal oxide. (7) A flame retardant resin composition, as stated in (6) above wherein the metal oxide is one or more metal oxide components selected from cadmium oxide, zinc oxide, cuprous oxide, cupric oxide, ferrous oxide, ferric oxide, cobalt oxide, manganese oxide, molybdenum oxide, tin oxide and titanium oxide. (8) A flame retardant resin composition, as stated in (7) wherein the metal oxide is cuprous oxide, cupric oxide or titanium oxide. (9) A flame retardant resin composition, as stated in (1) above which additionally contains a filler. (10) A flame retardant resin composition, as stated in (9) above wherein the filler is glass fibers. (11) A flame retardant resin composition, as stated in (1) above which additionally contains a fluorine based resin. (12) A flame retardant resin composition, as stated in (1) above which additionally contains a hindered phenol based stabilizer. (13) A flame retardant resin composition, as stated in (1) above which additionally contains a salt formed from a triazine based compound and cyanuric acid or isocyanuric acid. (14) In a second aspect the present invention provides a molding, comprising a flame retardant resin composition comprising 100 parts by weight of the following component (A) and 0.01 to 30 parts by weight of red phosphorus (C): (A) (a1) 67 to 99.99 wt% (based on the total weight of (a1) and (a2)) of a thermoplastic resin which is selected from a non-liquid crystal polyester other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers, a polyamide resin and a styrene based resin, and (a2) 33 to 0.01 wt% (based on the total weight of (a1) and (a2)) of polyethylene terephthalate homopolymer and/or an ethylene terephthalate copolymer, wherein the red phosphorus is covered with a thermosetting resin; and the electric conductivity of the red phosphorus is 0.1 to 1000µs/cm. This electric conductivity refers to the electric conductivity of an extract obtained by adding 100ml of pure water to 5g of red phosphorus, treating the mixture at 121°C for 100 hours, filtering away red phosphorus and diluting the filtrate to 250ml. Embodiments of this second aspect of the invention may provide: (15) A molding, as stated in (14) above, wherein the molding is selected from mechanical parts, electric and electronic parts, automobile parts, office automation apparatus housings, household electric appliance housings, office automation apparatus parts, and household electric appliance parts. A third aspect of the present invention provides: (16) A process for producing a flame retardant resin composition, comprising the steps of melt-kneading a proportion of the following component (A) and red phosphorus (C), to produce a composition (1) high in red phosphorus content, and melt-kneading the remaining amount of the component (A) and the composition (1) high in red phosphorus, by a double-screw extruder: (A) (a1) 67 to 99.99 wt% (based on the total weight of (a1) and (a2)) of a thermoplastic resin which is selected from a non-liquid crystal polyester other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers, a polyamide resin and a styrene based resin, and (a2) 33 to 0.01 wt% (based on the total weight of (a1) and (a2)) of polyethylene terephthalate homopolymer and/or an ethylene terephthalate copolymer, wherein the red phosphorus is covered with a thermosetting resin and has electric conductivity of 0.1 to 1000µS/cm. A fourth aspect of the present invention provides: (17) A flame retardant agent for resins, comprising (a2) 100 parts by weight of polyethylene terephthalate homopolymer and/or an ethylene terephthalate copolymer and (C) 0.01 to 250 parts by weight of red phosphorus, wherein the red phosphorus is covered with a thermosetting resin and the electric conductivity of the red phosphorus is 0.1 to 1000µs/cm. Preferred embodiments of the invention will now be described in more detail. The flame retardant resin composition of the present invention comprises 100 parts by weight of the following component (A) and 0.01 to 30 parts by weight of red phosphorus (C) : (A) (a1) 67 to 99.99 wt% (based on the total weight of (a1) and (a2)) of a thermoplastic resin which is selected from a non-liquid crystal polyester other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers, a polyamide resin and a styrene based resin, and (a2) 33 to 0.01 wt% (based on the total weight of (a1) and (a2)) of polyethylene terephthalate and/or an ethylene terephthalate copolymer The component (A) of the flame retardant resin composition embodying the present invention is described below. The component (A) consists of (a1) a thermoplastic resin which may be a non-liquid crystal polyester other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers and (a2) polyethylene terephthalate and/or an ethylene terephthalate copolymer. The thermoplastic resin (a1) embodying the present invention refers to a synthetic thermoplastic resin other than polyethylene terephthalate and ethylene terephthalate copolymers, which becomes flowable when heated and can be molded because of the flowability. The thermoplastic resins which can be used here include non-liquid crystal polyester resins other than polyethylene terephthalate and ethylene terephthalate copolymers, polyamide resins, styrene based resins such as polystyrene resin, styrene/acrylonitrile copolymer and acrylonitrile/butadiene/styrene copolymer (ABS resin), and mixtures of two of more of these thermoplastic resins. Among the above thermoplastic resins (a1) the non-liquid crystal polyester resins other than polyethylene terephthalate and ethylene terephthalate copolymers include, substantially, polycondensation products of dicarboxylic acids and glycols, ring opened polymers of cyclic lactones, polycondensation products of hydroxycarboxylic acids and polycondensation products of dibasic acids and glycols, more specifically polybutylene terephthalate resin, polyethylene naphthalate resin, polybutylene naphthalate resin, polycyclohexanedimethylene terephthalate resin, polyethylene-1,2-bis(phenoxy)ethane-4,4'-dicarboxylate resin, and also copolymers such as polybutylene terephthalate/isophthalate resin, polybutylene terephthalate/decanedicarboxylate resin and polycyclohexanedimethylene terephthalate/isophthalate resin, and their mixtures. A polyester resin especially suitable for the present invention is polybutylene terephthalate resin. The molecular weight of such a polyester resin is not especially limited, but a polyester resin of 0.10 to 3.00 dl/g, preferably 0.25 to 2.50 dl/g, more preferably 0.40 to 2.25 dl/g in the intrinsic viscosity measured at 25°C using a 1 : 1 mixed solvent of phenol/tetrachloroethane can be used. Among the thermoplastic resins (a1) the polyamide resins include ring opened polymers of cyclic lactams, polycondensation products of aminocarboxylic acids, polycondensation products of dibasic acids and diamines, more specifically aliphatic polyamides such as nylon 6, nylon 66, nylon 46, nylon 610, nylon 612, nylon 11 and nylon 12, aliphatic-aromatic polyamides such as poly(metaxylene adipamide) (hereinafter abbreviated as MDX·6), poly(hexamethylene terephthalamide (hereinafter abbreviated as 6T), poly(hexamethylene isophthalamide) (hereinafter abbreviated as 6I) and poly(tetramethylene isophthalamide) (hereinafter abbreviated as 4I), their copolymers and mixtures. Polyamides especially suitable for the present invention include nylon 6, nylon 66, nylon 6/66 copolymer and nylon 66/6T copolymer. The molecular weight of such a polyamide resin is not especially limited, but a polyamide resin of 1.70 to 4.50, preferably 2.00 to 4.00, more preferably 2.00 to 3.50 in the relative viscosity measured at a concentration of 1% in 98% sulfuric acid at 25°C can be used. Among the thermoplastic resins (a1) the styrene based resins include polystyrene, styrene/acrylonitrile copolymer, rubber modified styrene based resins, polymer blends consisting of a rubber modified styrene based resin and polyphenylene ether. Among them, a rubber modified styrene based resin refers to a graft polymer with a rubbery polymer dispersed as fine grains in a matrix made of an aromatic vinyl polymer, and it can be obtained by publicly known bulk polymerization, bulk suspension polymerization, solution polymerization or emulsion polymerization of an aromatic vinyl monomer or, as required, a monomer mixture consisting of an aromatic vinyl monomer and a copolymerizable vinyl monomer in the presence of a rubbery polymer. The rubber modified styrene based resins which can be used here include, for example, impact resistant polystyrene, ABS resin (acrylonitrile-butadiene-styrene copolymer), AAS (acrylonitrile-acrylic rubber-styrene copolymer) and AES resin (acrylonitrile-ethylene propylene rubber-styrene copolymer). The rubber modified styrene based resins include a structure in which a (co)polymer containing styrene monomer is grafted onto a rubbery polymer and a structure in which a (co)polymer containing styrene monomer is non-grafted to a rubbery polymer. The polyethylene terephthalate and/or an ethylene terephthalate copolymer (a2) used in a composition embodying the present invention refers to a thermoplastic polyester which may consist of terephthalic acid as an acid component and ethylene glycol as a glycol component. In addition, isophthalic acid, orthophthalic acid, naphthalenedicarboxylic acid, oxalic acid, adipic acid or 1,4-cyclohexanedicarboxylic acid, may also be present as a copolymerized acid component, and propylene glycol, 1,4-butanediol, 1,6-hexanediol, 1,4-cyclohexanedimethanol or an ethylene oxide addition product of bisphenol A, for example, may also be present as a copolymerized glycol component. Among them, a polyethylene terephthalate copolymer with terephthalic acid as a dicarboxylic acid component and ethylene glycol and cylohexanedimethanol as glycol components can be preferably used. When any of other components as described above is copolymerized, the amount of the copolymerized component is not especially limited as far as the effect of the present invention is not significantly impaired. When a dicarboxylic acid or a glycol is used as a copolymerized component, the amount of the dicarboxylic acid or glycol is preferably 40 mol% or less, more preferably 30 mol% or less, further more preferably 25 mol% or less, especially preferably 20 mol% or less based on the total number of moles of the dicarboxylic acids or the total number of moles of the glycols. The polyethylene terephthalate and/or an ethylene terephthalate copolymer (a2) used in the present invention preferably has intrinsic viscosity of 0.25 to 3.00 dl/g, more preferably 0.40 to 2.25 dl/g, measured at 25°C using a 1:1 mixed solvent of phenol/tetrachloroethane. The amount of the polyethylene terephthalate and/or ethylene terephthalate copolymer (a2) present in a composition embodying the invention is 33 to 0.01 wt%, preferably 23 to 0.1 wt%, more preferably 23 to 4.76 wt%, still more preferably 23 to 9.1 wt% based on the total amount of the thermoplastic resin (a1) and the polyethylene terephthalate and/or ethylene terephthalate copolymer (a2) (based on the total amount of (a1) and (a2)). That is, the amount of polyethylene terephthalate and/or an ethylene terephthalate copolymer (a2) added is 0.01 to 50 parts by weight, preferably 0.1 to 30 parts by weight, more preferably 5 to 30 parts by weight, further more preferably 10 to 30 parts by weight, especially preferably 15 to 30 parts by weight against 100 parts by weight of the thermoplastic resin (a1). Especially when the thermoplastic resin (a1) is polybutylene terephthalate resin, the amount of polyethylene terephthalate and/or an ethylene terephthalate copolymer (a2) added is 0.1 to 50 parts by weight, preferably 0.5 to 45 parts by weight, more preferably 1 to 43 parts by weight, still more preferably 2 to 40 parts by weight, especially preferably 5 to 35 parts by weight against 100 parts by weight of polybutylene terephthalate (a1), having regard to the compatibility between (a1) and (a2), the flame retardancy and wet heat resistance of the resin composition and the bleeding of the flame retardant agent. When the thermoplastic resin (a1) is a polyamide resin, the amount of polyethylene terephthalate and/or an ethylene terephthalate copolymer (a2) is 0.1 to 50 parts by weight, preferably 0.1 to 30 parts by weight, more preferably 2 to 27 parts by weight, still more preferably 5 to 25 parts by weight against 100 parts by weight of the polyamide resin (a1) having regard to the compatibility between (a1) and (a2), the flame retardancy and electric properties of the resin composition and the bleeding of the flame retardant agent. When the thermoplastic resin (a1) is a styrene based resin, the amount of polyethylene terephthalate and/or an ethylene terephthalate copolymer (a2) added is 0.1 to 50 parts by weight, preferably 1 to 50 parts by weight, more preferably 1 to 45 parts by weight, still more preferably 1 to 40 parts by weight against 100 parts by weight of the styrene based resin (a1) having regard to the compatibility between (a1) and (a2), the flame retardancy of the resin composition, the bleeding of the flame retardant agent and impact resistance. The polyethylene terephthalate and/or ethylene terephthalate copolymer (a2) used in this case is preferably an ethylene terephthalate copolymer having regard to the compatibility between (a1) and (a2), the flame retardancy and impact resistance of the resin composition and the bleeding of the flame retardant agent. The red phosphorus (C) used in a composition embodying the present invention is described below. Red phosphorus (C) is unstable as it is, and is gradually dissolved in water, to gradually react with it. Thus, red phosphorus treated for preventing such phenomena can be preferably used. Red phosphorus for this purpose can be treated, for example, by transforming red phosphorus into fine grains in a manner such as to avoid grinding it and thus so as not to form crushed faces highly reactive with water and oxygen, on the surfaces of the red phosphorus grains, or by adding a slight amount of aluminum hydroxide or magnesium hydroxide to the red phosphorus, to catalytically inhibit the oxidation of red phosphorus, or by covering the red phosphorus with paraffin or wax, to inhibit its contact with moisture, or by mixing the red phosphorus with ε-caprolactam or trioxane, to stabilize it, or by covering the red phosphorus with a phenol based, melamine based, epoxy based, unsaturated polyester based or other thermosetting resin, to stabilize it, or by treating the red phosphorus with an aqueous solution of a metal salt of, eg, copper, nickel, silver, iron, aluminum or titanium, to precipitate a metal phosphorus compound on the surfaces of the red phosphorus grains for stabilization, or by covering the red phosphorus with, eg., aluminum hydroxide, magnesium hydroxide, titanium hydroxide or zinc hydroxide, or by covering the surfaces of the red phosphorus grains by electroless plating with, eg., iron, cobalt, nickel, manganese or tin, or combining these methods. Preferably, the red phosphorus can be stabilized by transforming the red phosphorus into fine grains in a manner such as to avoid grinding the red phosphorus so as not to form crushed faces on the surfaces of the red phosphorus grains, or by covering the red phosphorus with a phenol based, melamine based, epoxy based, unsaturated polyester based or other thermosetting resin, or by covering the red phosphorus with, eg., aluminum hydroxide, magnesium hydroxide, titanium hydroxide or zinc hydroxide. Especially preferably red phosphorus can be stabilized by transforming the red phosphorus into fine grains without forming crushed faces on the surfaces of the red phosphorus, or covering the red phosphorus with a phenol based, melamine based, epoxy based, unsaturated polyester based or other thermosetting resin. Among these thermosetting resins, for improved moisture resistance, a phenol based thermosetting resin or epoxy based thermosetting resin can be preferably used for covering the red phosphorus and especially preferably a phenol based thermosetting resin can be used for covering the red phosphorus. The average grain size of the red phosphorus used in a composition embodying the present invention is preferably 0.01 to 50 µm, more preferably 0.1 to 45 µm, still more preferably 0.1 to 30 µm having regard to the flame retardancy and mechanical strength of the molding. The electric conductivity of the red phosphorus (C) used in the present invention measured by extraction treatment in hot water (the electric conductivity can be measured by adding 100 ml of pure water to 5 g of red phosphorus, treating for extraction in an autoclave ac 121°C for 100 hours, filtering away red phosphorus and diluting the filtrate to 250 ml) is usually 0.1 to 1000 µS/cm, preferably 0.1 to 800 µS/cm, more preferably 0.1 to 500 µS/cm having regard to the flame retardancy, wet heat resistance, mechanical strength and electric properties (tracking resistance) of the molding obtained. Preferable red phosphorus products marketed as grains with the electric conductivity kept in such a range include "Novaexell 140" and "Novaexell F5" produced by Rinkagaku Kogyo. In a composition embodying the present invention, the amount of red phosphorus (C) added to 100 parts by weight of the component (A) consisting of 67 to 99.99 wt% (based on the total amount of (a1) and (a2)) of a thermoplastic resin (a1) which is selected from a non-liquid crystal polyester other than polyethylene terephthalate and ethylene terephthalate copolymers, a polyamide resin and a styrene based resin, and 33 to 0.01 wt% (based on the total amount of (a1) and (a2)) of polyethylene terephthalate and/or an ethylene terephthalate copolymer (a2) is preferably 0.01 to 30 parts by weight, more preferably 1 to 30 parts by weight, still more preferably 2 to 27 parts by weight, especially preferably 5 to 25 parts by weight. More specifically, the amount of red phosphorus (C) added to the thermoplastic resin (a1) is preferably 0.1 to 30 parts by weight, more preferably 1 to 30 parts by weight, still more preferably 2 to 27 parts by weight, especially preferably 5 to 25 parts by weight against 100 parts by weight of the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers. If the thermoplastic resin (a1) is polybutylene terephthalate, the amount of red phosphorus (C) added is preferably 0.1 to 30 parts by weight, more preferably 1 to 25 parts by weight, still: more preferably 2 to 20 parts by weight, especially preferably 5 to 15 parts by weight against 100 parts by weight of polybutylene terephthalate. If the amount is less than 0.1 part by weight, flame retardancy is insufficient. If more than 30 parts, the mechanical properties become poor and the flame retardancy also becomes poor. If the thermoplastic resin (a1) is a polyamide resin, the amount of red phosphorus (C) added is preferably 0.1 to 30 parts by weight, more preferably 1 to 20 parts by weight, still more preferably 1 to 10 parts by weight, especially preferably 1 to 5 parts by weight against 100 parts by weight of the polyamide resin. If the amount is less than 0.1 part by weight, the flame retardancy is insufficient. If more than 30 parts by weight, the mechanical properties become poor and the flame retardancy also becomes poor. If the thermoplastic resin (a1) is a styrene based resin, the amount of red phosphorus (C) added is preferably 0.1 to 30 parts by weight, more preferably 1 to 25 parts by weight, still more preferably 2 to 20 parts by weight, especially preferably 5 to 15 parts by weight against 100 parts by weight of the styrene based resin. If the amount is less than 0.1 part by weight, the flame retardancy is insufficient. If more than 30 parts by weight, the mechanical properties become poor, and the flame retardancy also becomes poor. If a metal oxide is added, as a stabilizer for the red phosphorus, to the flame retardant resin composition of the present invention, the stability during extrusion and molding, strength, heat resistance, can, for example, be improved. The metal oxides which can be used here include cadmium oxide, zinc oxide, cuprous oxide, cupric oxide, ferrous oxide, ferric oxide, cobalt oxide, manganese oxide, molybdenum oxide, tin oxide, titanium oxide. Among them, cadmium oxide, cuprous oxide, cupric oxide and titanium oxide are preferable. Among them, cuprous oxide, cupric oxide and titanium oxide are more preferable. Titanium oxide is especially preferable. Titanium oxide is effective not only as a stabilizer for red phosphorus, but also for improving the coloration resistance of the resin composition obtained and the dispersibility of red phosphorus. The amount of the metal oxide is preferably 0.01 to 20 parts by weight, more preferably 0.1 to 10 parts by weight, still more preferably 0.1 to 5 parts by weight against 100 parts by weight of the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers. The flame retardant resin composition of the present invention can be greatly improved, for example, in strength, rigidity, heat resistance, by further containing a fibrous and/or granular filler. The fillers which can be used here include fibrous (including whiskers), powdery, granular or sheet-like organic or inorganic fillers such as glass fibers, carbon fibers, aromatic polyamide fibers, potassium titanate fibers, aluminum borate fibers, gypsum fibers, brass fibers, stainless steel fibers, steel fibers, ceramic fibers, boron fibers, asbestos fibers, alumina fibers, silica alumina fibers, graphite, mica, talc, silica, calcium carbonate, glass beads, glass flakes, glass microballoons, clay, wollastonite, titanium oxide and molybdenum disulfide. Among them, glass fibers, carbon fibers, potassium titanate fibers, aluminum borate fibers, mica and talc are preferable. Especially glass fibers are preferable. These fillers can also be treated by a silane based, titanate based or other coupling agent, or any other surface treating agent. The amount of the filler added is preferably 5 to 140 parts by weight, more preferably 5 to 100 parts by weight against 100 parts by weight of the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers. If a fluorine based resin is further added to a flame retardant resin composition embodying the present invention, the dripping of droplets during burning can be inhibited. The fluorine based resins which can be used here include polytetrafluoroethylene, polyhexafluoropropylene, (tetrafluoroethylene/hexafluoropropylene) copolymer, (tetrafluoroethylene/perfluoroalkyl vinyl ether) copolymers, (tetrafluoroethylene/ethylene) copolymer, (hexafluoropropylene/propylene) copolymer, polyvinylidene fluoride and (vinylidene fluoride/ethylene) copolymer. Among them, polytetrafluoroethylene, (tetrafluoroethylene/perfluoroalkyl vinyl ether) copolymers, (tetrafluoroethylene/hexafluoropropylene) copolymer, (tetrafluoroethylene/ethylene) copolymer and polyvinylidene fluoride are preferable. Especially polytetrafluoroethylene and (tetrafluoroethylene/ethylene) copolymer are preferable. The amount of the fluorine based resin is usually 0.01 to 5 parts by weight, preferably 0.1 to 2 parts by weight, more preferably 0.2 to 1 part by weight against 100 parts by weight of the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers having regard to mechanical properties and moldability. If a hindered phenol based oxidation stabilizer is additionally added to a flame retardant resin composition embodying the present invention, very good mechanical properties can be maintained. The stabilizers which can be used here include, for example, triethylene glycol-bis[3-(3-t-butyl-5-methyl-4-hydroxyphenyl) propionate], 1,6-hexanediol-bis[3-(3,5-di-t-butyl-4-hydroxyphenyl) propionate], pentaerythrityl-tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl) propionate], 2,2-thio-diethylenebis[3-(3,5-di-t-butyl-4-hydroxyphenyl) propionate], octadecyl-3-(3,5-di-t-butyl-4-hydroxyphenyl) propionate, 3,5-di-t-butyl-4-hydroxybenzyl phosphate diethyl ester, 1,3,5-trimethyl-2,4,5-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene, bis or tris(3-t-butyl-6-methyl-4-hydroxyphenyl)propane, N,N'-hexamethylenebis(3,5-di-t-butyl-4-hydroxy-hydrocinnamide) and N,N'-trimethylenebis(3,5-di-t-butyl-4-hydroxy-hydrocynnamide) In the present invention, such a hindered phenol based oxidation stabilizer can be added as required, and in this case the amount of the hindered phenol based oxidation stabilizer added is usually 0.01 to 3 parts by weight, preferably 0.02 to 1 part by weight, more preferably 0.03 to 0.5 part by weight against 100 parts by weight of the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers. If a salt formed by a triazine based compound and a cyanuric acid or isocyanuric acid is additionally added to a flame retardant resin composition embodying the present invention, the flame retardancy can be further enhanced. The salt of a triazine based compound and cyanuric acid or isocyanuric acid in a composition of the present invention is an addition product consisting of cyanuric acid or isocyanuric acid and a triazine based compound usually of 1:1 (molar ratio), or, as the case may be, 1:2 (molar ratio). The triazine based compounds which do not form a salt with cyanuric acid or isocyanuric acid are excluded. The triazine based compounds which can be used here include those represented by the following general formula (1) In the general formula (1), each of R4, R5, R6 and R7, independently, is a hydrogen atom, aryl group, alkyl group, aralkyl group, cycloalkyl group or -CONH 2 . The aryl group in this case preferably has 6 to 15 carbon atoms, and the alkyl group preferably has 1 to 10 carbon atoms. The aralkyl group preferably has 7 to 16 carbon atoms, and the cycloalkyl group preferably has 4 to 15 carbon atoms. Furthermore, R stands for the same group as -NR4R5 or -NR6NR7, or independently from them, a hydrogen atom, aryl group, alkyl group, aralkyl group, cycloalkyl group, -NH 2 or -CONH 2 . In this case, the aryl group preferably has 6 to 15 carbon atoms, and the alkyl group preferably has 1 to 10 carbon atoms. The aralkyl group preferably has 7 to 16 carbon atoms, and the cycloalkyl group preferably has 4 to 15 carbon atoms. Each of R4, R5, R6 and R7 may be, more specifically, a hydrogen atom, phenyl group, p-toluyl group, α-naphthyl group, β-naphthyl group, methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, sec-butyl group, tert-butyl group, hydroxymethyl group, methoxymethyl group, benzyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 2-methyl-1-pentyl group, 4-methyl-1-cyclohexyl group or amido group. Among them, a hydrogen atom, phenyl group, methyl group, hydroxymethyl group, methoxymethyl group, benzyl group and amido group are preferable. R may be, more specifically, an amino group, amido group, methylamino group, dimethylamino group, ethylamino group, diethylamino group, mono(hydroxymethyl)amino group, di(hydroxymethyl)amino group, mono(methoxymethyl)amino group, di(methoxymethyl)amino group, phenylamino group, diphenylamino group, hydrogen atom, phenyl group, p-toluyl group, α-naphthyl group, β-naphthyl group, methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, sec-butyl group, tert-butyl group, benzyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, 2-methyl-1-pentyl group or 4-methyl-1-cyclohexyl group. Among them, a hydrogen atom, amino group, amido group, methyl group, mono(hydroxymethyl)amino group, di(hydroxymethyl)amino group, mono(methoxymethyl)amino group, di(methoxymethyl)amino group, phenyl group and benzyl group are preferable. The salts formed by any of the compounds represented by the general formula (1) and cyanuric acid or isocyanuric acid which can be preferably used in a composition embodying the present invention are salts of melamine, benzoguanamine, acetoguanamine, 2-amido-4,6-diamino-1,3,5-triazine, mono(hydroxymethyl)melamine, di(hydroxymethyl)melamine and tri(hydroxymethyl)melamine. Among them, salts of melamine, benzoguanamine and acetoguanamine are preferable. The salt formed from a triazine based compound and' cyanuric acid or isocyanuric acid may be a powder obtained by forming a water slurry of a mixture consisting of the triazine based compound and cyanuric acid or isocyanuric acid, mixing it sufficiently to form the salt of both the compounds as fine grains, filtering the slurry, and drying the residue. It is not a simple mixture. The salt is not required to be perfectly pure, and may contain a small amount of an unreactive triazine based compound or cyanuric acid or isocyanuric acid. The average grain size of the salt is preferably 0.01 to 100 µm, more preferably 0.1 to 80 µm, still more preferably 1 to 50 µm, having regard to the flame retardancy, mechanical strength and surface properties of the molding. If the salt is poor in dispersibility, a dispersing agent such as tris(β-hydroxyethyl) isocyanurate can also be used together. The amount of the salt used is usually 0.01 to 40 parts by weight, preferably 0.1 to 30 parts by weight, still more preferably 0.5 to 20 parts by weight against 100 parts by weight of the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers. Furthermore, one or more conventional additives such as a phosphorus based, sulfur based or other antioxidant other than hindered phenol based antioxidants, thermal stabilizer, ultraviolet absorbent, lubricant, releasing agent and colorant including a dye or pigment can also be added to a flame retardant resin composition embodying the present invention, as far as the desired properties of a composition embodying the present invention are not impaired. A flame retardant resin composition embodying the present invention can be produced by any ordinary publicly known method. For example, it can be produced by feeding a thermoplastic resin (a1) other than polyethylene terephthalate and ethylene phthalate copolymers and polyethylene terephthalate and/or an ethylene terephthalate (a2), red phosphorus (C) and other necessary additives, to an extruder, after or without preliminarily mixing them, to sufficiently melt-knead. Preferably, for improved handling convenience and productivity, it can be produced by once melt-kneading a proportion of the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers or a proportion of the polyethylene terephthalate and/or ethylene terephthalate copolymer (a2), with red phosphorus (C), to produce a resin composition (D) higher in red phosphorus content than the red phosphorus content to be achieved in the intended flame retardant resin composition, and melt-kneading the resin composition (D) higher in red phosphorus and other additives used as desired, to the remaining amount of the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers or the polyethylene terephthalate and/or ethylene terephthalate copolymer (a2). As a further alternative method, it can be produced by once melt-kneading part of the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers, or a proportion of the polyethylene terephthalate and/or ethylene terephthalate copolymer (a2), with red phosphorus (C) and other additives used as desired, to produce a resin composition (D) higher in red phosphorus content than the red phosphorus content to be achieved in the intended flame retardant resin composition, and melt-kneading the resin composition (D) higher in red phosphorus and additives other than the additives used for producing the resin composition (D) higher in red phosphorus content, to the remaining amount of the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers or the polyethylene terephthalate and/or ethylene terephthalate copolymer (a2). When the additives used as desired are added when the resin composition (D) higher in red phosphorus content than the red phosphorus content to be achieved in the intended flame retardant resin composition is produced, it is preferable to mix the additives used as desired, with red phosphorus beforehand. Especially when a metal oxide, particularly titanium oxide used as a stabilizer of red phosphorus is added among the additives used as desired, the titanium oxide is preferably added when the resin composition (D) higher in red phosphorus is produced. Furthermore, if red phosphorus and titanium oxide are mixed by a mechanical mixer such as Henschel mixer, the stability and dispersibility of red phosphorus and the coloration resistance of the resin composition obtained can be improved. The resin composition (D) higher in red phosphorus can be preferably used as so-called master pellets, but the form is not limited to this, and it can also be in the form of chips, powder or a mixture thereof. The thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers to be mixed with the resin composition (D) higher in red phosphorus content can preferably take the form of pellets, but its form is not limited to these, and it can also be in the form of chips, powder or a mixture thereof. It is preferable that the resin composition higher in red phosphorus content, and the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers, to be mixed with it are almost the same or similar in form and size in view of the possibility to mix homogeneously. When the flame retardant resin composition is produced, a single-screw, double-screw or triple-screw extruder with "Unimelt" type screw(s) or, eg., a kneader, can also be used. Furthermore, as described above, the present invention is intended to make the thermoplastic resin (a1) other than polyethylene terephthalate and ethylene terephthalate copolymers flame retardant by using the polyethylene terephthalate and/or ethylene terephthalate copolymer (a2) and red phosphorus (C). Therefore, the resin composition of the present invention consisting of the polyethylene terephthalate and/or ethylene terephthalate copolymer (a2) and red phosphorus (C) can be used as a flame retardant agent of the thermoplastic resin (a1) which is selected from a non-liquid crystal polyester other than polyethylene terephthalate and ethylene terephthalate copolymers, a polyamide resin and styrene based resin. The resin composition consisting of the polyethylene terephthalate and/or ethylene terephthalate copolymer (a2) and red phosphorus (C) as a flame retardant agent preferably consists of 100 parts by weight of the polyethylene terephthalate and/or ethylene terephthalate copolymer (a2) and 0.01 to 250 parts by weight, preferably 10 to 200 parts by weight, still more preferably 20 to 100 parts by weight of red phosphorus (C). Therefore, the flame retardant resin composition can be molded bv any ordinary publicly known method, for example, into a sheet or film by, for example injection molding, extrusion molding or compression molding. Above all, the flame retardant resin composition is especially suitable for injection molding, and its features can render it suitable, for example, for mechanical parts, electric and electronic parts, automobile parts, and housings and parts of office automation apparatuses and household electric appliances. Examples The effects of especially preferred embodiments of the present invention are described below in more detail with reference to Examples, in which the "parts" are "parts by weight", unless otherwise stated. The respective properties were measured according to the following methods. Specimens for evaluation of flame retardancy obtained by injection molding were evaluated in flame retardancy according to the criterion specified in UL94, for samples of thickness 1-6 mm (1/16") and 0.8 mm (1/32"). The flame retardancy levels are in the order of V-0 > V-1 > V-2 > HB. (2) Mechanical property Dumbbell specimens obtained by injection molding were measured to find their tensile yield strengths according to ASTM D 638. (3) Wet heat resistance (bleed-out) Specimens obtained by injection molding were treated at 121°C at 100% RH for 100 hours, and the surfaces of the specimens were observed by an optical microscope. Bleed-out levels were in the order of oo (no precipitate was observed), o (little precipitate was observed), Δ (some precipitate was observed), and x (much precipitate was observed). (4) Wet heat resistance (tensile strength holding ratio) Dumbbell specimens obtained by injection molding were treated at 121°C at 100% RH for 100 hours, and measured to find their tensile yield strengths according to ASTM D 638. Tensile strength holding ratio were calculated from the following formula: Tensile strength holding ratio (%) = (Tensile strength after treatment/Tensile strength before treatment) x 100 < Making PBT resins flame retardant > Examples 1 to 8, and Comparative Examples 1 to 10 Polyethylene terephthalate (PET) of 0.65 in intrinsic viscosity (1 : 1 mixed solvent of phenol/tetrachloroethane at 25°C) and red phosphorus ("Novaexell" 140 produced by Rinkagaku Kogyo, 29.7 µm in average grain size, 200 µS/cm in electric conductivity obtained by adding 100 ml of pure water to 5 g of red phosphorus, treating the mixture in an autoclave at 121°C for 100 hours for extraction, filtering away red phosphorus, diluting the filtrate to 250 ml, and measuring using an electric conductivity meter (Personal SC Meter produced by Yokogawa Electric Corp.) and other additives were mixed at a ratio shown in Table 1, 2 or 3 with 100 parts by weight of Toray PBT1100S (PBT resin produced by Toray Industries. Inc.), and under nitrogen flow, the mixture was melt-extruded in a resin temperature range of 260 to 280°C using a coaxially rotating double-screw extruder of 30 mm in screw diameter and 45.5 in L/D (TEX-30 produced by The Japan Steel Works, Ltd., using two screws engaged with each by 3.5 mm; screw elements consisting of 10 kneading discs of L/D = 4 inclined at 45° are provided in alternately forward and backward directions, with a reverse full-flighted element provided additionally to give a screw form capable of exerting a powerful kneading force). The pallets obtained were dried and inspection-molded (80°C in mold temperature), to prepare specimens for evaluation. The evaluation results of respective samples in flame retardancy, wet heat resistance (bleed-out and strength holding rate) and mechanical property (tensile strength) are shown in Tables 1 to 3. The resins and additives used were as stated below. When glass fibers were used for reinforcement, they were added to achieve a glass fiber content of 30 wt% with the entire resin composition as 100 wt%. PBT: Toray PBT1100S (produced by Toray Industries, Inc.) Nylon: Polyamide 6 ("CM1010" produced by Toray Industries, Inc.) GF: Glass fibers ("CS3PE941S" produced by Nitto Boseki Co., Ltd.) Fluorine based resin: Polytetrafluoroethylene ("Teflon 6J" produced by Mitsui-Du Pont Fluorochemicals) Cyanurate: Melamine cyanurate ("MC440" produced by Nissan Chemical Industries, Ltd.) Stabilizer: Pentaerythrityl-tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl) propionate) ("IR-1010" produced by Chiba-Geigi) Metal oxide: Cuprous oxide (produced by Katayama Chemical Industries, Ltd.) From the evaluation results of Examples 1 to 3 and Comparative Examples 1 to 4, it can be seen that if PET and red phosphorus are added to PBT respectively in amounts specified in the present invention, the resin composition obtained has, specifically, excellent flame retardancy and can be specifically prevented from bleeding and from declining in strength holding ratio when treated at high temperature and high humidity. Furthermore, from Comparative Example 1, it can be seen that if red phosphorus only is used, the flame retardancy is poor, but that if PET and red phosphorus are used together by amounts specified in the present invention, even a thin molding can have excellent flame retardancy. Thus, it can be seen that PET and red phosphorus manifest the effect of a flame retardant agent. On the other hand, from Example 2 and Comparative Example 4, it can be seen that even if nylon 6 is used instead of PET, excellent flame retardancy and wet heat resistance cannot be manifested. From the evaluation results of Examples 4 to 6 and Comparative Examples 5 to 8, it can be seen that also when glass fibers are used for reinforcement, adding specific amounts of PET and red phosphorus to PBT resin allows specifically excellent flame retardancy and wet heat resistance to be manifested. From Example 7 and Comparative Example 9, it can be seen that if specific amounts of PET and red phosphorus, and furthermore a fluorine based resin and a cyanurate are used together, the molding is more excellent in flame retardancy even when it is thin. From Example 8 and Comparative Example 10, it can be seen that also when glass fibers are used for reinforcement, excellent flame retardancy and wet heat resistance can be manifested. From the above, it can be seen that if specific amounts of PET and red phosphorus are added to PBT resin, PET and red phosphorus manifest their effect as a flame retardant agent, to provide excellent flame retardancy, and can furthermore inhibit the bleeding in high temperature high humidity treatment and the decline of strength holding ratio. Example 9 Fifty parts by weight of red phosphorus ("Novaexell" 140 produced by Rinkagaku Kogyo) were mixed with 100 parts by weight of Toray PBT1100S (PBT resin produced by Toray Industries, Inc.), and under nitrogen flow, the mixture was melt-extruded in a resin temperature range of 260 to 280°C using a coaxially rotating double-screw extruder of 30 mm in screw diameter and 45.5 L/D (TEX-30 produced by The Japan Steel Works, Ltd.), to produce a PBT composition high in red phosphorus content. The PBT composition high in red phosphorus was used for extruding and molding a resin composition as described in the above Examples. The results are shown in Table 4. Example 10 Fifty parts by weight of red phosphorus ("Novaexell" 140 produced by Rinkagaku Kogyo) were mixed with 100 parts by weight of polyethylene terephthalate (PET) of 0.65 in intrinsic viscosity (1 : 1 mixed solvent of phenol/tetrachloroethane at 25°C), and under nitrogen flow, the mixture was melt-extruded in a resin temperature range of 260 to 280°C using a coaxially rotating double-screw extruder of 30 mm in screw diameter and 45.5 in L/D (TEX-30 produced by The Japan Steel Works, Ltd.), to produce a PET composition high in red phosphorus content. The PET composition high in red phosphorus content was used for extruding and molding a resin composition as described in the above Examples. The results are shown in Table 4. From a comparison of Example 8 with Examples 9 and 10, it can be seen that if a composition high in red phosphorus content is used, the burning time can be shortened while the tensile strength can be improved. < Making nylon resins flame retardant > Examples 11 to 22 and Comparative Examples 11 to 16 Resin compositions were produced as described above. The resins and other additives used were as stated below. Polyamide 6 (PA6): Amilan CM1010 (produced by Toray Industries, Inc.) Polyamide 66 (PA66): Amilan CM3001 (produced by Toray Industries, Inc.) Polyethylene terephthalate (PET): Polyethylene terephthalate of 0.65 in intrinsic viscosity (1 : 1 mixed solvent of phenol/tetrachloroethane at 25°C) Ethylene terephthalate copolymer: Ethylene terephthalate copolymer "Easter" GN002 (produced by Eastman Kodak) with terephthalic acid used as a dicarboxylic acid component, and ethylene glycol and cyclohexanedimethanol used at a molar ratio of 70/30 The results of respective samples in flame retardancy, wet heat resistance (bleed-out) and mechanical property (tensile strength) are shown in Tables 5 and 6. Since the samples were not so different in the decline of strength, the bleed-out property was used as a wet heat resistance indicator. From an evaluation of the results of Examples 11 to 22 and Comparative Examples 11 to 16, it can be seen that if PET or its copolymer and red phosphorus are added to a polyamide resin by amounts specified in the present invention, a resin composition which is specifically excellent in flame retardancy and which does not bleed out the flame retardant agent in dry heat treatment can be obtained. As can be seen from Comparative Examples 11 and 12, if red phosphorus only is added to PA6 or PA66, a product of 1/16" is V-0 in flame retardancy, but a product as thin as 1/32" is not sufficient in flame retardancy. Furthermore, in wet heat treatment, the product bleeds out. From Comparative Examples 13 to 16, it can be seen that if the amount of PET or red phosphorus is too large, the flame retardancy rather declines, and the tensile strength also declines. On the other hand, as shown in the examples of the present invention, if PET and red phosphorus are used in amounts specified in the present invention, a flame retardancy level of V-1 or V-0 can be achieved even if the product is as thin as 1/32", and that the bleed-out property can also be improved. From the evaluation results of Examples 23 to 26, if specific amounts of PET or its copolymer and red phosphorus, and furthermore a fluorine based resin and a cyanurate, etc. are used together, the burning time can be further shortened, and more excellent flame retardancy can be obtained. From an evaluation of the results of Examples 27 to 30 and Comparative Examples 17 to 22, it can be seen that even if glass fibers are used for reinforcement, specific amounts of PET or its copolymer and red phosphorus added to a polyamide resin can provide a resin composition specifically excellent in flame retardancy without causing the flame retardant agent to be bled out, as in the case of a resin composition not reinforced by glass fibers. From Examples 31 to 34, it can be seen that additional use of a fluorine based resin and a cyanurate, etc. allows the burning time to be shortened further and allows highly excellent flame retardancy to be obtained. Examples 35 and 36 Fifty parts by weight of red phosphorus ("Novaexell" 140 produced by Rinkagaku Kogyo) were added to 100 parts by weight of Amilan CM1010 (produced by Toray Industries, Inc.) or Amilan CM3001 (produced by Toray Industries, Inc.), and under nitrogen flow, the mixture was melt-extruded in a resin temperature range of 260 to 280°C using a coaxially rotating double-screw extruder of 30 mm in screw diameter and 45.5 in L/D (TEX-30 produced by The Japan Steel Works, Ltd.), to produce a PA6 or PA66 composition high in red phosphorus content. The composition high in red phosphorus content was used for extruding and molding a resin composition as described in the above Examples. The results are shown in Table 7. It can be seen that the use of a resin composition high in red phosphorus content allows the burning time to be further shortened and the tensile strength to be further enhanced. < Making an ABS resin flame retardant > Examples 37 to 39, and Comparative Examples 23 to 26 The resins and other additives used in these Examples were as stated below. ABS resin: "Toyolac" (type 100) (produced by Toray Industries, Inc.) PC (polycarbonate): "Iupilon" S2000 (produced by Mitsubishi Gas Chemical Co., Inc.) Polyamide 6 (PA6): Amilan CM1010 (produced by Toray Industries, Inc.) Aromatic phosphate: "PX-200 (produced by Daihachi Chemical) The ABS resin, polyester resin and/or polyamide resin, red phosphorus and other compounds were mixed at a ratio shown in Table 8, and the mixture was melt-kneaded and extruded at a resin temperature of 230°C, to produce a polymer as pellets. It was molded into specimens by an injection molding machine at a cylinder temperature of 230°C at a mold temperature of 60°C. The ABS resin compositions obtained were evaluated in flame retardancy, mechanical property (impact strength), wet heat resistance (bleed-out), heat resistance (load deflection temperature) and flowability (MFR) according to the following methods. Since they were not so different in their decline in strength, the bleed-out property was used as a wet heat resistance indicator. The mechanical property was evaluated with reference to impact strength. (1) 1/2" Izod impact strength: According to ASTM D 256-56A. (2) MFR: According to JIS K 7210 (220°C, 10000 g in load) . A larger value means better flowability at the time of molding. (3) Load deflection temperature: According to ASTM D 648 (1.82 MPa in load). (4) Flame retardancy: A vertical burning test was conducted using burning specimens of 1/16" x 1/2" x 5" according to UL94. The results of respective samples in flame retardancy, wet heat resistance (bleed out) and mechanical properties are shown in Table 8. From the measured results of Examples 37 to 39 and Comparative Examples 23 to 26, it can be seen that if PET and red phosphorus are added to ABS, resin compositions as excellent as V-0 at 1/16" or V-2 at 1/32", excellent in wet heat resistance and good in impact resistance and flowability at the time of molding can be obtained. Furthermore, from Example 39, it can be seen that if a fluorine based resin is added, a thin molding (1/32") excellent in flame retardancy can be obtained. On the other hand, from Comparative Example 25, it can be seen that if red phosphorus only is added to an ABS resin, the resin cannot be made flame retardant, and from Comparative Examples 24 and 26, it can be seen that even if PC or PA6 is added in addition to PET, the resin obtained cannot be made flame retardant and is also low in bleed resistance and other properties. From Comparative Example 23, it can be seen that even if an aromatic phosphate and PC are added instead of red phosphorus, the resin obtained cannot be made flame retardant and remarkably declines in bleed resistance and load deflection temperature. Example 40 Fifty parts by weight of red phosphorus ("Novaexell" 140 produced by Rinkagaku Kogyo) were mixed with 100 parts of an ethylene terephthalate copolymer with terephthalic acid used as a dicarboxylic acid component, and with ethylene glycol and cyclohexanedimethanol used at a molar ratio of 70/30, "Easter" GN002 (produced by Eastman Kodak), and under nitrogen flow, the mixture was melt-extruded at a resin temperature of 230°C using a coaxially rotating double-screw extruder of 30 mm in screw diameter and 45.5 in L/D (TEX-30 produced by Japan Steel Works, Ltd.), to produce a composition high in red phosphorus content. The polyethylene terephthalate copolymer composition high in red phosphorus content was used for extruding and molding a resin composition as described in the above Examples. results are shown in Table 9. From comparison between Examples 38 and 40, it can be seen that the use of a composition high in red phosphorus content allows the burning time to be further shortened and the mechanical property to be further enhanced. Available red phosphorus products include: Red phosphorus ("Novaexell" 140) produced by Rinkagaku Kogyo or red phosphorus ("Novaexell" F5, 4.5 µ in average grain size and 200 µS/cm in electric conductivity) produced by Rinkagaku Kogyo.

Claims: A flame retardant resin composition comprising: 100 parts by weight of the following component (A): (A) (a1) 67 to 99.99 wt% (based on the total weight of (a1) and (a2)) of a thermoplastic resin which is selected from a non-liquid crystal polyester other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers, a polyamide resin and a styrene based resin, and (a2) 33 to 0.01 wt% (based on the total weight of (a1) and (a2)) of polyethylene terephthalate homopolymer and/or an ethylene terephthalate copolymer; and 0.01 to 30 parts by weight of red phosphorus (C) wherein the red phosphorus is covered with a thermosetting resin; and the electric conductivity of the red phosphorus is 0.1 to 1000 µS/cm, which electric conductivity refers to the electric conductivity of an extract obtained by adding 100 ml of pure water to 5 g of red phosphorus, treating the mixture at 121°C for 100 hours, filtering away red phosphorus and diluting the filtrate to 250 ml. A flame retardant resin composition comprising (a1) 100 parts by weight of a thermoplastic resin which is selected from a non-liquid crystal polyester other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers, a polyamide resin and a styrene based resin, (a2) 0.01 to 50 parts by weight of polyethylene terephthalate homopolymer and/or an ethylene terephthalate copolymer, and (C) 0.1 to 30 parts by weight of red phosphorus, wherein the red phosphorus is covered with a thermosetting resin; and the electric conductivity of the red phosphorus is 0.1 to 1000 µS/cm, which electric conductivity refers to the electric conductivity of an extract obtained by adding 100 ml of pure water to 5 g of red phosphorus, treating the mixture at 121°C for 100 hours, filtering away red phosphorus and diluting the filtrate to 250 ml. A flame retardant resin composition according to claim 1 or 2, wherein the thermoplastic resin (a1) which is a non-liquid crystal polyester other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers is polybutylene terephthalate. A flame retardant resin composition according to claim 1 or 2, wherein the thermoplastic resin (a1) is a polyamide. A flame retardant resin composition according to claim 4, wherein the polyamide is one or more polyamide components selected from nylon 6, nylon 66 and their copolymers. A flame retardant resin composition according to claim 1 or claim 2, wherein the thermoplastic resin (a1) is a styrene based resin. A flame retardant resin composition according to any preceding claim, which additionally contains a metal oxide. A flame retardant resin composition according to claim 7, wherein the metal oxide is one or more metal oxide component selected from cadmium oxide, zinc oxide, cuprous oxide, cupric oxide, ferrous oxide, ferric oxide, cobalt oxide, manganese oxide, molybdenum oxide, tin oxide and titanium oxide. A flame retardant resin composition according to claim 8, wherein the metal oxide is cuprous oxide, cupric oxide or titanium oxide. A flame retardant resin composition according to any preceding claim, which additionally contains a filler. A flame retardant resin composition according to claim 10, wherein the filler is glass fibers. A flame retardant resin composition according to any preceding claim, which additionally contains a flourine based resin. A flame retardant resin composition according to any preceding claim, which additionally contains a hindered phenol based stabilizer. A flame retardant resin composition according to any preceding claim, which additionally contains a salt formed from a triazine based compound and a cyanuric acid or isocyancuric acid. A moulding comprising a flame retardant resin composition comprising 100 parts by weight of the following component (A) and 0.01 to 30 parts by weight of red phosphorus (C) : (A) (a1) 67 to 99.99 wt% (based on the total weight of (a1) and (a2)) of a thermoplastic resin which is selected from a non-liquid crystal polyester other than polyethylene terephthalate homopolymer and ethylene terephthalate copolymers, a polyamide resin and a styrene based resin, and (a2) 33 to 0.01 wt% (based on the total weight of (a1) and (a2)) of polyethylene terephthalate homopolymer and/or an ethylene terephthalate copolymer, wherein the red phosphorus is covered with a thermosetting resin; and the electric conductivity of the red phosphorus is 0.1 to 1000 µS/cm, which electric conductivity refers to the electric conductivity of an extract obtained by adding 100 ml of pure water to 5 g of red phosphorus, treating the mixture at 121°C for 100 hours, filtering away red phosphorus and diluting the filtrate to 250 ml. A molding according to claim 15, wherein the molding is selected from mechanical parts, electric and electronic parts, automobile parts, office automation apparatus housings, household electric appliance housings, office automation apparatus parts and household electric appliance parts. A process for producing a flame retardant resin composition, comprising the steps of melt-kneading a proportion of the following component (A) and red phosphorus (C), to produce a composition (1) higher in red phosphorus content than the red phosphorus content intended to be achieved in the intended flame retardant composition, and melt-kneading the remaining amount of the component (A) and the composition (1) high in red phosphorus content by a double-screw extruder: (A) (a1) 67 to 99.99 wt& (based on the total weight of (a1) and (a2)) of a thermoplastic resin which is selected from a non-liquid crystal polyester other than the polyethylene terephthalate homopolymer and ethylene terephthalate copolymers, a polyamide resin and a styrene based resin, and (a2) 33 to 0.01 wt% (based on the total weight of (a1) and (a2)) of polyethylene terephthalate homopolymer of (a1) and (a2)) of polyethylene terephthalate homopolymer and/or an ethylene terephthalate copolymer, and wherein the red phosphorus is covered with a thermosetting resin; and the electric conductivity of the red phosphorus is 0.1 to 1000 µS/cm, which electric conductivity refers to the electric conductivity of an extract obtained by adding 100 ml of pure water to 5 g of red phosphorus, treating the mixture at 121°C for 100 hours, filtering away red phosphorus and diluting the filtrate to 250 ml. A flame retardant agent for resins, comprising (a2) 100 parts by weight of polyethylene terephthalate homopolymer and/or an ethylene terephthalate copolymer and (C) 0.01 to 250 parts by weight of red phosphorus, wherein the red phosphorus is covered with a thermosetting resin; and the electric conductivity of the red phosphorus is 0.1 to 1000 µS/cm, which electric conductivity refers to the electric conductivity of an extract obtained by adding 100 ml of pure water to 5 g of red phosphorus, treating the mixture at 121°C for 100 hours, filtering away red phosphorus and diluting the filtrate to 250 ml.

Inventors: INOUE TOSHIHIDE, MATSUMOTO HIDEKI, MATSUOKA HIDEO, YAMAUCHI KOUJI, INOUE, TOSHIHIDE, MATSUMOTO, HIDEKI, MATSUOKA, HIDEO, YAMAUCHI, KOUJI
Applicants: TORAY INDUSTRIES, TORAY INDUSTRIES, INC.
Application year: 1997
Main classification: C08L67
IPC codes: C08L77, C08L71, C08L67, C08K3, C08L55