IMPROVED OPEN CELL MESH AND WASHING IMPLEMENT MANUFACTURED THEREFROM

Abstract: Disclosed are an improved open cell polymer mesh and washing implement made therefrom, which exhibit superior softness, while also retaining good resiliency. To achieve the improved softness and resiliency of the improved washing implement an improved open cell mesh is provided which is softer and sufficiently resilient as a result of its controlled cell structure parameters. In preferred embodiments, the controlled physical parameters of the open cell mesh include basis weight, cell count, node count, node length, node thickness, node width, and cell geometry.

Description: IMPROVED OPEN CELL MESH AND WASHING IMPLEMENT MANUFACTURED THEREFROM TECHNICAL FIELD This invenuon relates generaUy to an unproved extruded open cell mesh, and an implement for bathing, scrubbing, and the like, made therefrom. More particularly, this invention relates to an improved mesh and washing implement which exhibit superior softness while retaining acceptable resiliency. Optimization of the softness and resiliency of the washing implement is accomplished through control of a variety of physical features of the improved extruded open cell mesh. BACKGROUND OF THE INVENTION The production of extruded open cell mesh is known to the art, and have been adapted for use as implements for scrubbing, bathing or the like, due to the relative durability and inherent roughness or scrubbing characteristics of the mesh. Also, open cell meshes improve lather of soaps in general, and more particularly, the lather of liquid soap is improved significantly when used with an implement made from an open cell mesh. Mesh roughness is generally caused by the stiffness ofthe multiple filaments and nodes ofthe open cell mesh, and cause a scratching effect or sensation in many instances. To make a scrubbing or bathing implement, the extruded open cell mesh is shaped and bound into one of a variety of configurations, e.g. a ball, tube, pad or other shape which may be ergonomically friendly to the user of the washing implement. The open cell meshes of the past were acceptable for scrubbing due to the relative stiffness of the fibers and the relatively rough texture of the nodes which bond the fibers together. However, that same stiffness and roughness of prior art mesh was relatively unacceptable to the general consumer when used as a personal skin care product. Prior open cell mesh used to manufacture washing implements has typically been manufactured in tubes through the use of counter-rotating extrusion dies which produce diamond- shaped cells. The extruded tube of mesh is then typically stretched to form hexagonal-shaped cells. Hence, heretofore, there has been a continuing need for an improved washing implement comprising an extruded open cell mesh which would be soft, durable, relatively inexpensive to manufacture, and relatively resilient without being overly stiff and scratchy. More specifically, there is a need for providing an improved open cell mesh, featuring physical characteristics which could be adequately identified and characterized, so that washing implements could be reliably made from mesh exhibiting all ofthe aforementioned desired physical properties. BRIEF DESCRIPTION OF THE DRAWINGS While the specification concludes widi claims particularly pointing out and distinctly claiming the present invention, it is believed the same will better be understood from the following description taken in conjunction with the accompanying drawings in which: FIG. 1 illustrates an exemplary prior art hand-held hourglass shaped washing implement; FIG. 2 illustrates an exemplary prior art hand-held ball shaped washing implement; FIG. 3 illustrates an exemplary section of mesh after extrusion; FIG. 4 illustrates an exemplary extruded mesh section after stretching; FIG. 4A illustrates an enlarged exemplary view of a node after stretching; FIG. 5 is a schematic illustration of testing procedures for measuring: an open cell mesh's resistance to an applied weight; useful in characterizing the open cell mesh made according to the subject invention; FIG. 6 illustrates a section of mesh used for counting cells in an open cell mesh; FIG. 6A is an exploded view ofthe mesh section of FIG. 6; FIG. 7 illustrates a merged node in open cell mesh; FIG. 7A illustrates a cross sectional view ofthe node of FIG. 7; FIG. 8 illustrates an overlaid node in open cell mesh; FIG. 8 A illustrates a cross sectional view ofthe node of FIG. 8; and FIG. 9 illustrates the geometry of a single diamond-shaped cell of open cell mesh. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Reference will now be made in detail to die present preferred embodiments of the improved washing implement comprising an open cell mesh. Examples of washing implements which can be improved by utilization of the improved open cell mesh of the present invention are illustrated in the accompanying drawings where, FIG. 1 is an exemplary hand-held washing implement 10 manufactured in an hourglass shape, according to a method disclosed in U.S. Patent No. 4,462,135, issued to Sanford, hereby incoφorated by reference herein. FIG. 2 shows an alternative, ball-like configuration for a washing implement 20 made of mesh 18, and manufactured by a method disclosed in U.S. Patent No. 5,144,744 issued to Campagnoli on September 8, 1992, hereby incoφorated by reference herein. These configurations for washing implements are exemplary only, and it is well known to those skilled in the art that there are other methods for producing washing implements of various configurations. The embodiments discussed above are described in terms of a washing implement, and more particularly, a hand-held washing implement or 'puff'. The term hand-held is to be broadly construed to generally include open cell mesh manufactured into an implement that a person can hold in their hand during use. Likewise, die term washing implement is to be broadly construed to include various applications of such an implement for bathing, exfoliating skin, scrubbing pans, dishes and the like, as well as omer uses. The process of manufacturing diamond cell and hexagonal cell mesh for use in washing implements and the like involves the selection of an appropriate resin material which can include polyolefins, polyamides, polyesters, and other appropriate materials which produce a durable and functional mesh. Low density polyethylene (LDPE, a polyolefin), poly vinyl ethyl acetate, high density polyethylene or mixtures thereof are preferred to produce the mesh described herein, although other resin materials can be substituted provided that the resulting mesh conforms with the physical parameters defined below. Additionally, adjunct materials are commonly added to extruded mesh. Mixtures of pigments, dyes, brighteners, heavy waxes and the like are common additives to extruded mesh and are appropriate for addition to the mesh described herein. To produce an improved open cell mesh, die selected resin is fed into an extruder by any appropriate means. Extruder and screw feed equipment for production of synthetic webs and open cell meshes are known and available in the industry. After the resin is introduced into the extruder it is melted so that it flows through extrusion channels and into die counter-rotating die, as will be discussed in greater detail below. Resin melt temperatures mil vary depending upon the resin selected. The material's Melt Index is a standard parameter for correlating extrusion die temperatures to the viscosity of the extruded plastic as it flows through the die. Melt Index is defined as the viscosity of a thermoplastic polymer at a specified temperature and pressure; it is a function of the molecular weight. Specifically, Melt Index is the number of grams of such a polymer that can be forced through a 0.0825 inch orifice in 10 minutes at 190 degrees C by a pressure of 2160 grams. A Melt Index of from about 1.0 to about 10.0 for LDPE is preferred for manufacturing the mesh described herein for use in washing implements, and a Melt Index of from about 2.0 to about 7.0 is especially preferred. However, if alternate resin materials are used and/or otiier ultimate uses for tite mesh are desired, the Melt Index might be adjusted, as appropriate. The temperature range of operation of die extruder can vary significantly between the melt point ofthe resin and the temperature at which the resin degrades. . The liquefied resin can then be extruded through two counter-rotating dies which are common to the industry. U. S. Patent No. 3,957,565 to Livingston, et. al., for example, describes a process for extruding a tubular plastic netting using counter-rotating dies, such disclosure hereby incoφorated herein by reference. A counter-rotating die has an inner and outer die, and both have channels cut longitudinally around their outer and inner circumferences respectively, such that when resin flows through the channels, fibers are extruded. Individual fibers, e.g., F, as seen in FIG. 3, are extruded from each channel of die inner die as well as each channel of die outer die. As the two dies are rotated in opposite directions relative to one anotiier, die channels from die outer die align with die channels of die inner die, at predetermined intervals. The liquefied resin is thereby mixed as two channels align and the two fibers, e.g., F, as seen in FIG. 3, being extruded are bonded until the extrusion channels of die outer and inner die are misaligned due to continued rotation. As die inner die and outer die rotate counter-directionally to each odier, die process of successive alignment and misalignment of die channels of each die occurs repeatedly. The point at which the channels align and two fibers are bonded together is commonly referred to as a "node" (e.g. N of FIG. 3). The 'die diameter" is measured as die inner diameter of die outer die or the outer diameter of the inner die. These two diameters must be essentially equal to avoid stray resin from leaking between die two dies. The die diameter affects die final diameter of die tube of mesh being produced, although die diameter is only one parameter which controls die final diameter of die mesh tube. Although it is believed that a wide variety of die diameters, for example between about 2 inches and about 6 inches, are suitable for manufacturing die meshes described herein, especially preferred die diameters are in the range of between about 2 '/. and 3 Vi inches (about 6.35 and 8.89 centimeters). The extrusion channels can likewise be varied among a variety of geometric configurations known to the art. Square, rectangular, D-shaped, quarter-moon, semi-circular, keyhole, and triangular channels are all shapes known to die art, and can be adapted to produce die mesh described herein. Quarter-moon channels are preferred for die mesh of die present invention, although other channels also provide acceptable results. After die tube of mesh is extruded from the counter-rotating dies, it can be characterized as having diamond-shaped cells, e.g., as shown in FIG. 3, where each of die four corners of the diamond is an individual node N and the four sides of die diamond are four, separately formed filament segments F. The tube is then pulled over a cylindrical mandrel where die longitudinal axis ofthe mandrel is essentially aligned with die longitudinal axis of die counter-rotating dies, i.e., the machine direction (MD as shown in FIGs. 3 and 4). The mandrel serves to stretch the web circumferentially resulting in stretching the nodes and expanding the cells. Typically the mandrel is immersed in a vat of water, oil or other quench solution, which is typically 25 degrees C or less, which serves to cool and solidify the extruded mesh. The mandrel can be a variety of diameters, although it will be chosen to correspond appropriately to die extrusion die diameter. The mandrel is preferably larger in diameter than die die diameter to achieve a desired stretching effect, but the mandrel must also be small enough in diameter to avoid damaging die integrity of die mesh dirough over-stretching. Mandrels used in conjunction with die preferred 2.5"-3.5" die diameters mentioned above might be between about 3.0" and 6.0" (about 7.62 and 15.24 cm). Mandrel diameter has been found to have a pronounced effect on die resiliency and softness of die mesh produced, which is characterized by die Initial Stretch value described in greater detail below. As die nodes of die diamond cell mesh are stretched, they are transformed from small, ball¬ like objects, e.g., N of FIG. 3, to longer, thinner filament-like nodes, e.g. N of FIG. 4 and 4A. The cells are thereby also transformed from a diamond-like shape to hexagonal-shape wherein the nodes form two sides of die hexagon, and die four individual filament segments F form die other four sides of die hexagon. The geometric configuration of the mesh cells can also vary significantly depending on how die tube of mesh is viewed. Thus, die geometric cell descriptions are not meant to be limiting but are included for illustrative puφoses only. After passing over die mandrel, the tube is then stretched longitudinally over a rotating cylinder whose longitudinal axis is essentially perpendicular to die longitudinal axis of die tube, i.e. the longitudinal axis of die rotating cylinder is peφendicular to die machine direction, MD of die mesh. The mesh tube is then pulled through a series of additional rotating cylinders whose longitudinal axis is peφendicular to die longitudinal axis, or the machine direction, (MD), of die extruded mesh. Preferably the mesh is taken-up faster man it is produced, which supplies die desired longitudinal, or machine direction MD, stretching force. Typically a take-up spool is used to accumulate the finished mesh product. As should be apparent, there are a variety of process parameters (e.g., resin feed rate, die diameter, channel design, die rotation speed and die like) diat affect mesh parameters such as node count, basis weight and cell count. Aldiough the production of open cell mesh in a tube configuration dirough die use of counter-rotating dies as described is preferred for the embodiments of die present invention, alternative processing means are known to die art. For example, U.S. Patent 4,123,491 to Larsen ( the disclosure of which is hereby incoφorated herein by reference), shows die production of a sheet of open cell mesh wherein the filaments produced are essentially perpendicular to one another, forming essentially rectangular cells. The resulting mesh net is preferably stretched in two directions after production, as was die case with die production of tubular mesh described above. . Yet another alternative for manufacturing extruded open cell mesh is described in U.S. Patent No. 3,917,889 to Gaffhey, et al., the disclosure of which is hereby incoφorated herein by reference. The Gaffiiey, et al. reference describes the production of a tubular extruded mesh, wherein the filaments extruded in the machine direction are essentially peφendicular to filaments or bands of plastic material which are periodically formed transverse to the machine direction. The material extruded transverse to die machine direction can be controlled such that thin filaments or thick bands of material are formed. As was the case widi the mesh manufacturing procedures described above, die tubular mesh manufactured according to die Gaffiiey, et al. reference is preferably stretched both circumferentially and longitudinally after extrusion. A key parameter when selecting a manufacturing process for the improved mesh described herein is die type of node produced. As was described above, a node is die bonded intersection between filaments. Typical prior art mesh is made with overlaid nodes (FIGS. 8 and 8A). An overlaid node can be characterized in that the filaments which join together to form die node are still distinguishable, although bonded together at die point of interface. In an overlaid node, me filaments at both ends of die node form a Y -crotch, aldiough die filaments are still relatively distinguishable at die interface of die node. Overlaid nodes result in mesh which has a scratchy feel. A merged node (FIGS. 7 and 7A) can be characterized by the inability after production of die mesh to easily visually distinguish the filaments which formed the node. Typically, a merged node resembles a wide filament segment. A merged node can have a "ball-like" appearance, similar to that shown by N of FIG. 3, or can be stretched subsequent to formation to have die appearance of node N of FIGs. 4 and 4A. In either case, at each end of the node mere is a Y-crotch configuration, e.g., 2 of FIGS. 4 and 4 A, at die point where the filament segments F branch off the node. For both overlaid and merged nodes, node length 24 of FIG. 4 is defined as the distance from die center of die crotch of one Y-shape to the center of die crotch of die Y-shape at the opposite end of die node. The combination of merged nodes widi specific TAG Factor Values (described below) results in a mesh with a consumer preferred range of softness and resiliency, specifically when used in cleansing implements. Node diameter is not easily measured because nodes rarely have uniform cross-sectional diameters. However, an "effective diameter" can be defined as die average between a node's smallest diameter and its largest diameter measured near die midpoint between die Y -crotches at each end. As should be apparent, die measurement of node length and node diameter are to be compared at the conclusion of the extrusion process, (i.e., after the material has been dirough die stretching steps). Preferred nodes of mesh to be used for washing implements have an approximate leng h, measured from opposing crotches, of from about 0.020 inches (0.051 cm) to about 0.095 inches (0.241 cm) but more preferably from about 0.051 cm to about 0.200 cm and most preferably from about 0.060 cm to about 0.185 cm, and the nodes have an effective diameter of from about 0.012 inches (0.030 cm) to about 0.028 inches (0.071 cm). The nodes can also be characterized as having a diickness of from about 0.008 inches (0.020 cm) to about 0.015 inches (0.038 cm), and a width of from about 0.015 inches (0.038 cm) to about 0.040 inches (0.102 cm) but more preferably from about 0.050 cm to about 0.102 cm. As should be apparent, die measurements of node length, node width, and node diickness are to be assessed at die conclusion of die manufacturing process, (i.e., after the material has been through the stretching steps). As will be apparent, die measurement of flexibility of a mesh is a critical characterization of die softness and conformability of a mesh. It has been determined that a standardized test of mesh flexibility can be performed as described herein and as depicted in FIG. 5. The resulting measurement of flexibility is defined herein as Initial Stretch. As schematically illustrated in FIG. 5, the procedure for determining Initial Stretch begins by hanging a mesh tube 26 from a test stand horizontal arm 28, which in turn is supported by a vertical support member 30 and which is in turn attached to a test stand base 32. The tube of mesh is hung from arm 28 so that its machine direction (MD) is parallel to arm 28. As was described above, when the open cell mesh is extruded from a counter-rotating die, the mesh is formed in a tube. If a sheet of mesh is produced, as was described in die Larsen '491 patent, the sheet must be formed into a tube by binding the sheet's edges securely together prior to performing the Initial Stretch measurement. The tube of mesh 26 for testing should be 6.0 inches (15.24 centimeters) in length, as indicated by length 34. Six inches was chosen, along with a 50.0 gram weight, as an arbitrary standard for making the measurement. As will be apparent, other standard conditions could have been chosen; however, in order to compare Initial Stretch values for different meshes, it is preferred that die standard conditions chosen and described herein are followed uniformly. As is illustrated in FIG. 5, a standardized weight is suspended from a weight support member 36, which has a weight support horizontal arm 38 placed dirough and hung from die mesh tube 26. It is critical that the total combined weight of die weight support member 36 and die standardized weight equal 50 grams. Distance 40 illustrates die Initial Stretch, and is die distance which mesh tube 26 stretches immediately after the weight has been suspended from mesh tube 26. A linear scale 42 is preferably used to measure distance 40. For mesh ofthe present invention it is generally preferred to have a Initial Stretch value of from about 7.0 inches (17.8 cm) to about 20.0 inches (50.8 cm), more preferred to have an Initial Stretch value of from about 9.0 inches (22.9 cm) to about 18.0 inches (45.7 cm), and most preferred to have an Initial Stretch value of from about 10.0 inches (25.4 cm) to about 16.0 inches (40.6 cm). The resilient property of the open cell mesh can be measured by suspending a larger standardized weight (i.e., 250 grams, shown in FIG. 5) from the mesh sample 26, and substracting the distance 40 from die distance 41. It is critical that the total combined weight of die weight support member and die larger standardized weight equal 250 grams. This value is directly proportional to the level of resilience in the material. FIG. 6 illustrates a standardized method for counting cells; a staggered row of cells are counted out in the machine direction of the tube of mesh, as shown in FIG. 6A. A rigid frame 44 may be used to secure mesh 46 so that the segment of mesh 48 being counted is held firmly in place. The mesh 46 is a length of tubular mesh greater tiian twelve inches in length. The mesh 46 is pulled taught along its machine direction (MD). When the mesh is taught, a twelve inch segment 48 is marked off, for example widi a felt tipped marker. After the mesh section 48 is marked off, tiie mesh may be pulled in a direction transverse to the longitudinal axis; the idea here is to open up the cells enough so that they may be comfortably counted. FIG. 6A illustrates an enlarged portion of the mesh, with numbers 1 through 9 indicating individual cells. As can be seen in FIG. 6A, one cell in each row is counted down die length of die marked off portion of the tube; every other cell is vertically aligned due to the diamond or hexagonal cell configuration. This yields the cells per unit length (in FIG. 6, the value would be about 28.5 cells per foot). For the puφose of standardization, a 12.0 inch section of mesh (30.48 cm) is counted to arrive at the number of cells per foot. As will be apparent, counting a shorter or longer segment of mesh is acceptable, provided that the cell count is divided by die length of the marked off section, and ultimately converted to cells/meter for reasons which will be discussed in more detail hereinafter. Characterizing the improved mesh in the direction transverse to the machine direction is accomplished by counting a string of nodes along a line around the circumference of the tube of mesh. This method is universal to tubes or flat sheets of mesh and simply comprises selecting a linear row of nodes and counting diem. As should be apparent, any row of nodes will contain an identical number of nodes; this is dependent on the extrusion die configuration. Preferred ranges for node count for mesh to be used for washing implements are between about 90 and about 140. Especially preferred ranges are between about 95 and about 1 15. Basis weight is anotiier empirical measurement which can be performed on any tube or sheet of extruded open cell mesh. A length of mesh is measured along the machine direction, tiien cut in a direction across the machine direction, with this measured and cut section then being weighed. The basis weight is preferably tracked in units of grams per meter. For puφoses of standardization, a 12.0 inch section of mesh (30.48 cm) is measured, cut and weighed, and the results reported in grams per meter. The preferred basis weight for mesh of the subject invention to be used for washing implements is from about 5.60 grams/meter to about 10.50 grams/meter, with an especially preferred range of from about 6.00 grams/meter to about 8.85 grams/meter. The preferred meshes of the present invention can be characterized by a compilation ofthe aforementioned measurable parameters. As should be apparent, die processing parameters described above can be varied individually or in combination to produce the desired physical properties described herein. The most useful value for characterizing the subject meshes is die 'TAG Factor" value. The variables must all be converted to metric units before calculating the "Tag Factor"; i.e., Initial Stretch must be expressed in meters, Basis Weight must be expressed in grams per meter, Cell Count must be expressed as cells per meter, and Node Count would have no units. 'TAG Factor" is defined by a fraction having die Initial Stretch multiplied by the Relative Cell Size as its numerator, and Basis Weight as its denominator. The TAG factor is used since the flexibility of a netting material has been found to be directly proportional to die relative cell size, and inversely proportional to basis weight. The TAG factor accounts (Normalizes) for tiiese relationships thus allowing a variety of netting basis weight and cell size combinations to be compared for their relative flexibility. The TAG factor is computed using the following equation: Initial Stretch / Relative Cell Size TAG Factor = Basis Weight Relative cell size is defined as: 1 Relative Cell Size = (Cell Count * Node Count) Total Cells In this calculation Cell Count multiplied by Node Count is equivalent to die Total Number of cells in a fixed length sample of netting tube, for a given circumference tube. Relative Cell Size is inversely proportional to the total number of cells in a given sample of netting material. This relationship is true since die more cells per fixed sample size, the smaller the size of each individual cell. The units of the TAG Factor are meters/gram. It has been found tiiat meshes having a TAG Factor value of from about 520 meters/gram to about 1800 meters/gram have superior softness characteristics while retaining sufficient resiliency for improved functionality as in washing implements. An especially preferred TAG Factor value is from about 580 meters/gram to about 1700 meters/gram, and an even more preferred range is from about 700 meters/gram to about 1500 meters/gram. Through die course of experimentation we have discovered that netting materials that are highly flexible under a very low level of stress are perceived by consumers as having a much softer feel on the skin. Further, when this highly flexible netting is formed into a bathing implement, the resulting implement significantly improves consumer ratings for both the cleansing implement as well as the cleaning product it is used with. We hypothesize that the improved consumer ratings are directly attributable to the more flexible netting materials ability to conform easily to body contours, and to more evenly distribute applied forces thus reducing abrasion. The result is an improved consumer perception of "softness", and not being "scratchy". Low stress flexibility is quantified by taking a 6 inch sample of netting & measuring the distance it is deformed/stretched under a fixed 50 gram load. This is referred to as a materials Initial Stretch. We have found that for a fixed set of netting parameters (e.g. basis weight & cell size) die greater the magnitude of Initial Stretch the higher die consumer perception of softness. We have also found that a netting materials Initial Stretch measure is inversely related to its' basis weight, and directly related to the size of its' cells. As a result we've found it helpful to "normalize" the Initial Stretch value to account for the corresponding relationships with basis weight & cell size. This normalized value is referred to as the TAG Factor. The TAG Factor enables the flexibility of a variety of materials (having differing basis weights & cell sizes) to be compared for their relative flexibility level. We have found that all currently available netting materials have TAG factors below about 520. Also, we've found that all these materials are relatively firm (not soft), and are generally abrasive on skin ("scratchy"). Materials having a TAG Factor above 520 are directionally more flexible, & are consistently perceived by consumers as being softer. The benefits of die improved mesh of tiiis invention when used as a washing implement or the like, include improved consumer acceptability, improved softness when the washing implement is rubbed against human skin. Improved lathering is also an important quality of bathing implements made from mesh of die present invention. Lather is improved when the soap is in bar, liquid, and most importantly gel form. When mesh is used in the production of washing implements, tactile softness, i.e., the feel of the mesh as it contacts human skin is an important criteria. However, resiliency is also an important physical criteria. It may be intuitive that producing a softer mesh would result in a relatively limp mesh which may not retain the desired shape for the washing implement, i.e., stiffness sacrificed in favor of softness. However, mesh of the present invention which has a TAG Factor value greater than about 520 meters/gram has been found to have die unique properties of being both soft and relatively resilient, i.e. the mesh is able to retain its shape when used as a washing implement. A washing implement which is soft but does not conform to the skin or object being scrubbed (i.e., the implement is limp), or is not resilient, is generally not acceptable to consumers. Therefore, the improved open cell mesh described herein provides a material which is both soft to the touch and, when used to manufacture washing implements, is resilient enough to provide die necessary conformability which is preferred by consumers. Durability. Absoφtive/Dispersive Capacity. Cell Geometry The benefits of the improved mesh of this invention include improved consumer acceptability, and improved softness when die washing implement is rubbed against human skin. Improved lathering is also an important. Resiliency is also an important physical criteria. It may be intuitive that producing a softer mesh would result in a relatively limp mesh which may not retain the desired shape for the washing implement, i.e., stiffness sacrificed in favor of softness. However, mesh of the present invention has been found to have the unique properties of being both soft and relatively resilient, i.e. the mesh is able to retain its shape when used as a washing implement. The present implement achieves softness, in part through a lower mesh basis weight, while at least maintaining durability of die implement, in comparison to prior art implements. This means that the present implement retains its shape and size over time widi continued use by the consumer; prior art implements tend to expand and grow limp and unwieldy witii continued use. We have found that tiiis quality is due to die degree of cell openness, or the overall cell geometry, which we have quantified in terms of a ratio (see FIG. 8). When the net extrusion process is known, the ratio can be measured directly. When die extrusion process is unknown, measurement of die cell angle in the mesh can be used to accurately measure tiiis ratio. Prior art implements are typically made with cells tiiat are relatively closed, or have a very small cell angle, ø, as depicted in FIG. 8. During use, these small-angled cells relax and open which causes growth and deterioration of the implement's shape. If the cells in the raw mesh are within a certain range of openness before the mesh is made into an implement, the implement will not tend to grow and lose its shape during use, and will last much longer. We have found that the preferred range of β is about 29 degrees to about 151 degrees, which corresponds to an X/Y ratio of from about 0.25 to about 0.97. A more preferred range of X/Y is from about 0.31 to about 0.95. . Referring to FIG. 8, the X/Y ratio is equal to the sin (o/2), where o is the open angle of a given cell. Y is the length of one cell as measured when the mesh is pulled taught in die machine direction. Y/2 can be determined through the measurements made when determining cell count, supra; Y/2 is equal to the length of mesh measured off for the cell count calculation divided by the number of cells counted. Recall tiiat cells are counted in a staggered fashion, which accounts for a result of Y/2 rather than Y. X/2 is half the width of a cell, as shown in FIG. 8, as measured when the tube of mesh is in a relaxed state. X/2 is equal to "pi times die relaxed tube diameter", divided by "two times the node count". Pi times die tube diameter is equal to the tube circumference, and two times the node count is equal to two times the number of cells around the tube circumference; the result is half the overall width of a single cell. Cell count and node count are easily determined for any puff or net material as described, supra. Tube diameter and ø are not easily measurable, which gives rise to the need for the X/Y ratio. The following two examples will better illustrate cell geometry determination: Example 1 - Process for Manufacture of Netting is Known The tube diameter is known from the netting process. It is either the die diameter if no mandrel is subsequently used, or the mandrel diameter if die tube is stretched over a mandrel. Because cell count, node count, and tube diameter are all known, ø, X, and Y can all be calculated, and therefore X/Y can be calculated. Example 2 - Process for Manufacture of Netting is Unknown Here, only cell count and node count can be easily determined. The relaxed cell angle protocol (described infra) can be used to approximate the X/Y ratio. Based on the open angle calculated from the relaxed cell angle protocol, the X/Y ratio can be calculated geometrically. The objective of the relaxed cell angle protocol is to estimate the cell angle as it exists as the netting tube comes off the manufacturing process. This method becomes necessary when an implement is made of netting from an unknown manufacturing process, and die netting comes from a disassembled implement and is therefore folded and irregular in shape. The objective here is to relax the netting and return it to the form it was in prior to deformation into an implement shape. Measurement of cell angles taken after using this method correlate well with measurement of cell angles taken from netting straight off the manufacturing process. The equipment necessary to perform this method is as follows: a hot plate, a stir bar, a thermometer or pyrometer, a flat spatula, and a wide vessel. Using a hot plate, heat water in the vessel to 175 degrees Farenheit, and agitate the water with the stir bar. This temperature is below the glass transition point of low density polyethylene, which is the typical polymer of choice for bathing implements of this type; this temperature therefore does not alter the physical state of the netting beyond that of its original state as manufactured. Take the netting from a disassembled implement, and cut a 2 inch length of tube across the machine direction of the tubing. Cut this circle of netting into two semicircles, and lay them out flat to form two rectangles 2 inches by 1/2 the tube circumference in area. Immerse net samples into water bath for 10 seconds. Remove die samples from the water bath with the spatula. After cooling, measure the cell angle as shown in FIG. 8; a preferred method of measurement is to measure at least five regions of the sample and average them. Any of various angle measurement techniques may be used. When the range of cell angle specified above is combined with a mesh basis weight of from about 5.60 grams per meter to about 10.40 grams per meter, the relationship between softness and durability of die implement is optimized. The ability of the present implement to absorb and deliver water and cleansing lather has also been improved. Because of its lower basis weight, die present implement contains a longer tube of mesh tiian prior art implements, when comparing implements of equal weight. This additional length of mesh, in addition to the openness of cells within the mesh, provides for more open space within individual cells and more individual cells. The result is an increased capacity to pick up water and lather, and then deliver the increased amounts of water and lather to the consumer's body. The preferred range of basis weight for improved absoφtion and delivery is from about 5.60 grams per meter to about 8.50 grams per meter, with a more preferred range being from about 6.00 grams per meter to about 8.00 grams per meter. The following protocol was developed to measure the mass of cleansing product and water solution that is absorbed by the present cleansing implement, the mass of cleansing product and water dispersed by the implement, and the volume of lather dispersed by the implement during use. At lower basis weights, more lather is generated per the following test method. The test method demonstrates the ability of an implement to deliver the absorbed product as consumer noticed lather. This absoφtion and dispersion protocol was developed to determine if different implements have different capacities to absorb and then disperse product and water. The test is designed to closely pattern consumer use: the first step is to saturate the implement with water and product and allow excess to run off. Product is mixed with the water in order to prepare a controlled surfactant solution. The use of this surfactant solution enables each implement to retain an amount of product directly related to its absorbtive capacity instead of using some fixed amount which biases implements of different size. The surfactant solution is kept at a controlled temperature to simulate actual shower water. The dispersion section of die test measures the amount of product, water and lather that leave the puff during a controlled scrubbing motion for a controlled time, much like die consumer would perform in use. The necessary equipment includes an 800 mL beaker, a hot plate, a stirrer, a water hardness kit (if performing the test with 14 grain water), and a standard medium-sized Rubbermaid bath mat. The protocol is as follows: 1. Prepare the surfactant solution: add 70 grams of product to 630 mL of water (either de-ionized/distilled or 14 grain hardness water). 2. Using a hot plate and stirrer, bring water temperature to 95 degrees F, and stir for 5 minutes prior to testing. Keep stirrer on for duration of test. 3. Weigh dry implement. Submerge implement for 10 seconds in solution to saturation point. 4. Remove implement from solution, and suspend implement for 15 seconds to allow excess to drip off. 5. Weigh implement (this is reported as absoφtion mass). 6. Place implement on rubber testing surface (bath mat). Rub implement back and forth using a controlled amount of compression and stroke length (18 inches). Each back and forth motion should take approximately one second. Repeat the motion 60 times (about 1 minute). 7. Weigh implement (this is reported as dispersion mass). 8. Collect accumulated lather using teflon spatula and place it in 800 mL beaker. Level lather and record volume filled in beaker (this is reported as lather volume). 9. Rinse and hang implement to dry. Having showed and described the preferred embodiments of the present invention, further adaptation of the improved open cell mesh and resulting washing implement can be accomplished by appropriate modifications by one of ordinary skill in the art without departing from the scope of the present invention. A number of alternatives and modifications have been described herein and others will be apparent to those skilled in the art. For example, specific methods of manufacturing washing implements from open cell mesh have been described although other manufacturing processes can be used to produce the desired implement. Likewise, broad ranges for the physically measurable parameters have been disclosed for the inventive open cell mesh as preferred embodiments ofthe present invention, yet within certain limits, the physical parameters ofthe open cell mesh can be varied to produce other preferred embodiments of improved mesh of the present invention as desired. Accordingly, the scope of the present invention should be considered in terms ofthe following claims and is understood not be limited to die details ofthe structures and methods shown and described in the specification and in the drawings.

Claims: WHAT IS CLAIMED IS: 1. An improved open cell mesh wherein the mesh comprises: a series of cells defined by a plurality of filament sections and a plurality of nodes, wherein the nodes comprise intersections of the filament sections; the open cell mesh characterised by a TAG Factor value of from 520 meters/gram to 1800 meters/gram. 2. An improved open cell mesh wherein the mesh comprises: a series of cells defined by a plurality of filament sections and a plurality of nodes, wherein die nodes comprise merged intersections ofthe filament sections; the open cell mesh characterised by a TAG Factor value of from 520 meters/gram to 1800 meters/gram. 3. An extruded open cell mesh wherein the mesh comprises: a basis weight, a plurality of nodes, and a plurality of cells, the mesh having properties which result in a consumer preferred combination of softness and resiliency, the mesh characterised by a) a node length ranging from 0.051 centimeters to 0.200 centimeters; b) a node width ranging from 0.038 centimeters to 0.102 centimeters; c) a node thickness ranging from 0.020 centimeters to 0.038 centimeters; d) a cell count ranging from 130 cells per meter to 260 cells per meter; and e) a basis weight ranging from 5.60 grams per meter to 10.50 grams per meter. 4. An extruded open cell mesh wherein the mesh comprises: a basis weight, a plurality of merged nodes, and a plurality of cells, the mesh having properties which result in a consumer preferred combination of softness and resiliency, the mesh characterised by a) a node length ranging from 0.051 centimeters to 0.200 centimeters; b) a node width ranging from 0.038 centimeters to 0.102 centimeters; and c) a node diickness ranging from 0.020 centimeters to 0.038 centimeters. 5. A washing implement comprising extruded open cell mesh, the open cell mesh characterized by a basis weight of from 5.60 grams per meter to 8.50 grams per meter, the mesh being shaped and bound into a hand-held implement suitable for cleansing applications. 6. A washing implement comprising extruded open cell mesh, the open cell mesh characterized by a basis weight of from 5.60 grams per meter to 10.40 grams per meter and an X/Y ratio of from 0.25 to 0.97, die mesh being shaped and bound into a hand-held implement suitable for cleansing applications. 7. An improved open cell mesh according to any of die preceding claims, wherein the open cell mesh is shaped and bound into a hand held implement suitable for use as a washing implement. 8. An improved open cell mesh according to any one of the preceding claims, wherein the open cell mesh has a TAG Factor value of from 580 meters/gram to 1700 meters/gram. 9. An improved open cell mesh according to any one of the preceding claims, further comprising a node count of from 70 to 140, but more preferably from 70 to 125, and most preferably from 90 to 115. 10. An improved open cell mesh according to any one of the preceding claims, further comprising a cell count ranging from 130 cells per meter to 260 cells per meter, a basis weight ranging from 5.60 grams per meter to 10.50 grams per meter but more preferably from 6.00 grams per meter to 8.00 grams per meter, and a node count ranging from 70 to 140 but more preferably from 90 to 140. 11. The washing implement according to any of the preceding claims, wherein the range of X/Y is from 0.25 to 0.97, more preferably from 0.25 to 0.71, and most preferably from 0.31 to 0.60.

Inventors: ALTONEN GENE MICHAEL, GIRARDOT RICHARD MICHAEL, TUTHILL LYLE BROWN, ALTONEN, GENE, MICHAEL, GIRARDOT, RICHARD, MICHAEL, TUTHILL, LYLE, BROWN
Applicants: PROCTER & GAMBLE, THE PROCTER & GAMBLE COMPANY
Application year: 1997
Main classification: B29C47
IPC codes: A47K7, A47L13, A47L17