STABILIZER AND BLOWING AGENT USEFUL FOR RIGID FOAMED PVC

Abstract: Improved activation of the blowing agent used to form blown PVC products, as well as thermal stabilization, are provided by a combination of an ester of the formula (R<1>)1-2Sn(-S-R<a>-OC(=O)R<2>)2-3 wherein R<1> is C1-4 alkyl, R<a> is alkyl, and R<2> is C6-24 alkyl or alkenyl; one or both of mono (C1-4 alkyl) and di (C1-4 alkyl) tin sulfides; a complex of diorganotin oxide with an oxygen-containing acid; and optionally an ester HS-R<c>-OC(=O)R<3> wherein R<c> is alkyl and R<3> is C6-24 alkyl or alkenyl.

Description: STABILIZER AND BLOWING AGENT USEFUL FOR RIGID FOAMED PVC FIELD OF THE INVENTION This invention relates to the stabilization and preparation of foamed polyvinylchloride resins. In particular this invention relates to the use of stabilizers for foamed polyvinylchloride resins as activators for the blowing agents used in the 10 preparation of foamed polyvinylchloride resin. An important aspect of this invention is the use of organotin compounds as the thermal stabilizer and activator for the blowing agent in the preparation of rigid foamed polyvinylchloride products. 1^ BACKGROUND OF THE INVENTION It is well established that organotin stabilizers are effective for the thermal stabilization of polyvinylchloride resins. U.S. Pat. 20 No. 2,597,920 to Carroll and No. 2,763,632 to Johnson disclosure reaction products of diorganotin oxides and esters of diorganotin oxides as heat and light stabilizers for vinylchloride resins. Despite their high tin content, these reaction products are rather 2> poor in stabilizing effectiveness. Among the effective organotin stabilizers for inhibiting the polyvinylchloride resins at high temperatures are the organotin ercapto acid esters. Patents disclosing the use of these compounds include ' ^0 55 U.S. Patent No. 2,641,588 and No. 2,641,596 to Leistner et al . , U.S. Patent No. 2,648,650 to Weinberg and U.S. Patent No. 2,809,956 to Mack et al . The dialkyltin bis-alkylthioglycolates, alone and in combination with other components, have been widely accepted for various commercial applications. Among the combinations reported including the dialkyltin bisalkyl thioglycolates as a component are U.S. Patent No. 2,914,506 to Mack et al disclosing combinations of organotin thioglycolates with compounds such as metal salts, epoxy compounds, phosphates and phenols and U.S. Patent No. 3,640,953 to Brecker et al . disclosing combinations of diorganotin mercaptocarboxylic acid esters and a diorganotin-ester complex which is a reaction product of a diorganotin oxide and an ester of an oxygen- containing acid. The combinations of Brecker et al . have particularly been found to be highly efficient in the heat stabilization of polyvinylchloride. One important utility for polyvinylchloride resins is in the preparation of rigid foamed articles. The articles are ordinarily manufactured by known methods, for example by extrusion, by blending the plastics material with a suitable blowing agent and choosing the processing temperature such that it is above the decomposition temperatures of the blowing agent. Often, however, the decomposition temperature is too high above the processing temperature, so that the blowing agent cannot be used alone. For this reason, activators are often employed which hasten the decomposition of the blowing agent and/or lower the decomposition temperature. In the search for effective activators, the use of compounds that are also effective thermal stabilizers has become a highly desirable possibility in order to reduce the number of components of the resin blend. Organotin oxides, organotin alcoholates and mixtures thereof have been described in the literature as being useful as activators. U.S. Patent No. 4,698,368 to Muller discloses mixtures of 10 organotin mercaptides as imparting good light and heat stability and as being effective activators for the manufacture of foamed plastics. These mixtures can optionally contain an organotin carboxylate. Also disclosed in this patent as being useful as light and 1^ heat stabilizers and as activators are mixtures of organotin mercaptides and organotin carboxylates. U.S. Patent No. 4,255,320 to Brecker et al . discloses that certain admixtures of compounds of the formula (R 1 ) 12 Sn(-S-R-0C(=0)R 2 ) 2 _ 3 with monoalkyl tin 20 and/or dialkyi tin sulfides are useful as PVC stabilizers, but there is no disclosure as to usefulness as foam activators. U.S. Patent No. 3,706,679 to Hopton et al . discloses a mixture of organotin thioglycolate, particularly di-n-butyltin bis (isooctylmercaptoacetate) and barium salts of saturated fatty acids having from 14 to 18 carbon atoms, such as barium stearate or palmitate. 30 m U.S. Patent No. 4,977,193 to Croce et al. 1 discloses a mixture of at least one organotin mercapto acid ester of the formula (CH 3 ) -Sn(S-Z- (COOR) 2 wherein Z is an organic radical, R is an organic radical derived from an alcohol having one to about four hydroxyl group and one to thirty carbon atoms, and m is 1-4; and a diorganotin oxide complex with an ester of any of certain oxygen-containing acids. There remains a need for products which exhibit improved performance as activators in the 10 production of foamed PVC resin, especially rigid foamed PVC resin, while also contributing effectiveness as thermal stabilizers. BRIEF SUMMARY OF THE INVENTION 1 One aspect of the present invention is an activator system comprising (a) one or more compounds of formula (A) •^ n (R 1 ) a Sn(-S-R a -0C(=0)R 2 ), -a (A) wherein R 1 independently at each occurrence is straight or branched alkyl containing 1 to 12 carbon atoms; R a is a divalent alkyl radical containing 2 -'5 to 20 carbon atoms; a is 1 to 2; R 2 independently at each occurrence is straight or branched alkyl or alkenyl containing 6 to 24 carbon atoms and 0 to 4 carbon-carbon double bonds; so i c admixed with one or more compounds selected 1 from the group consisting of monoalkyl tin sulfides and dialkyltin sulfides, in which group each alkyl substituent is independently straight or branched alkyl containing 1 to 12 carbon atoms; and 5 (b) a diorganotin complex with an ester of an oxygen-containing acid, wherein the two organo groups are each attached to tin through carbon atoms and are hydrocarbon radicals having from one to about thirty carbon atoms, and said complex is derived from 10 the reaction of the corresponding diorganotin oxide with an ester derived from an aliphatic or aromatic alcohol or phenol and an acid selected from the group consisting of hydrocarbyl carboxylic acids, sulfur- containing hydrocarbyl carboxylic acids, hydroxy- 1 containing hydrocarbyl carboxylic acids, phosphoric acid, sulfuric acid, sulphurous acid, nitric acid, nitrous acid, boric acid, arsenic acid and silicic acid. Another aspect of the present invention is ^° an activator system comprising the aforementioned components (a) and (b) and a component (c) which is one or more esters of the formula HS-R c -0C(=0)R 3 , wherein R c is a divalent alkyl radical containing 2 to 20 carbon atoms, and R 3 is straight or branched alkyl '" " , or alkenyl containing 6 to 24 carbon atoms and 0 to 4 carbon-carbon double bonds. An additional aspect of the present invention is an activator system comprising (a') one or more compounds of formula (A*) 3 (R 1 ) a Sn(-S-Z-(COOR m ) 4 . a (A*) 1 where R 1 and a are as defined above, Z is an organic radical containing 1 to 30 carbon atoms, each R m is independently an organic radical derived from an 5 alcohol containing 1 to 4 hydroxyl groups and containing 1 to 30 carbon atoms, and m is 1 to 4 ; admixed with one or more compounds selected from the group consisting of monoalkyl tin sulfides and dialkyi tin sulfides, in which group each alkyl substituent 10 independently is straight or branched alkyl containing 1 to 12 carbon atoms; and further comprising a component corresponding to component (b) as defined above, and a component corresponding to component (c) as defined above. Another additional aspect of the present invention is an activator system comprising (a') one or more compounds of formula (A*) 2M (R 1 ) a Sn(-S-Z- (C00R ra ) m ) < . a (A*) where R 1 and a are as defined above, Z is an organic radical containing 1 to 30 carbon atoms, each R m is independently an organic radical derived from an ? r~ > alcohol containing 1 to 4 hydroxyl groups and containing 1 to 30 carbon atoms, and m is 1 to 4; admixed with one or more compounds selected from the group consisting of monoalkyl tin sulfides and dialkyi tin sulfides, in which group each alkyl substituent 'S independently is straight or branched alkyl containing 1 1 to 12 carbon atoms; wherein the molar ratio of monoalkyl tin compounds to dialkyi tin compounds is at least 0.5:1; and further comprising a component r -> corresponding to component (b) as defined above and, optionally, an ester component corresponding to component (c) as defined above. One or more alkyl mercaptans of the formula R'-SH can also be present in addition to, or in place 0 of, the compounds of the formula HS-R c -OC(=0) R . The alkyl group R' is straight or branched and can contain 6 to 24 carbon atoms. Another aspect of the present invention comprises foamed, rigid PVC compositions comprising 5 one (or more) of the activator systems of the present invention. Yet another aspect of the present invention comprises the method of producing a foamed rigid PVC composition, comprising subjecting a foamable θ composition comprising PVC, one or more of the activator systems of the present invention, and one or more blowing agents, to conditions under which said composition is converted into foamed, rigid PVC. DETAILED DESCRIPTION OF THE INVENTION The successful production of rigid articles from foamed polyvinylchloride requires a balance of θ > many factors in the formulation of the compositions to be extruded or otherwise formed. The complete formulation comprises the polyvinylchloride resin, including an activator system of the present invention, and a blowing agent (by which term is meant one or more than one chemical compound which is useful as a blowing compound) and other optional but conventional components such as processing agents, impact modifiers and internal and external lubricants. Chemical blowing compounds that release 0 nitrogen may be used in forming a microcellular structure in the vinylchloride resins used in making the foamed compositions. The preferred chemical blowing agents are amides, particularly azamides and more specifically azodicarbonamide. Examples of other useful blowing agents are: N,N' -dinitroso-N,N' -dimethyl terephthalimide N-aminophthalimide 4,4' -oxybis (benzenesulphonylhydrazide) N,N' -dinitrosopentamethylenetetramine ~ >o Azoisobutyric dinitrile Diazoaminobenzene Dinitropentamethylene tetramine Benzenesulfohydrazide Terephthalyl bis (N-nitrosomethylamide) Toluene-2,4-bis (sulfonyl hydrazide) p-tertiary butylbenzazide p-carbomethoxy benzazide Diarylpentaazadiene 3 methyl-1, 5-diphenylpentaazadiene 5 The blowing agent is used in an amount 1 sufficient to produce the degree of foaming desired and generally can be used in an amount of about 0.1 to about 3.5 parts by weight per 100 parts of resin being blown. 5 The activator system functions to control the temperature at which the vinyl resin fuses to provide the proper environment into which the blowing agent releases gaseous nitrogen. Unless the activator system of this invention is used in combination with a 10 blowing agent as shown in the formulations above, improper blow occurs throughout the structure, the profile is uneven and either is not encased in a skin or the skin becomes uneven and rough due to the presence of blow holes. These problems are especially 15 severe and present when the vinyl resin being blown is unplasticized. One aspect of the present invention comprises compounds of the formula (A) : 20 (R 1 ) a Sn(-S-R a -OC(=0)R 2 ) 4 . a (A) In this formula each R 1 is a straight or branched alkyl group containing 1 to 12, and preferably 1 to 4 carbon atoms. Preferred examples include methyl and or5. butyl. The radical R a contains 2 to 20 carbon atoms, and preferably 2 to 6 carbon atoms. A preferred R a is - H 2 H 2 - - The R 2 is preferably derived from a medium- chain or long-chain fatty acid R 2 C(=0)OH, or a mixture 0 55 of two or more such acids. A preferred example of 1 such a mixture is tall oil fatty acids, which is a well-known term for a mixture generally containing fatty acids 16 to 22 carbon atoms in length. Examples of other R 2 radicals include the residues of acids 5 such as heptanoic, heptenoic, octanoic (caprylic) , octenoic, n nanoic, nonenoic, decanoic, tetradecanoic (myristic) , dodecanoic (lauric) , hexadecanoic (palmitic) , octadecanoic (stearic), as well as oleic, linoleic, linolenic, gadoleic, arachidonic, behenic, 0 and the like. Compositions containing compositions of formula (A) will preferably include a mixture or monoalkyl and dialkyi derivatives, representing different values of the subscript a. However, ^ compositions containing only one compound of formula (A) can be used. The compositions of formula (A) are admixed with one or more monoalkyl tin sulfides and/or dialkyi tin sulfides. In these sulfides, each alkyl group 0 independently contains 1 to 12, and preferably 1 to 4 carbon atoms . Preferred alkyl groups include methyl and butyl. While the monoalkyl tin sulfides and dialkyi tin sulfides can be present together in any mixture of -5 derivatives and in any ratio to each other, or one can be present individually to the exclusion of the others, it is preferred that the mole ratio of all monoalkyl tin compounds (that is, monoalkyl compounds of formula (A) and monoalkyl tin sulfides) to all 0 10 35 dialkyi tin compounds (that is, dialkyi compounds of formula (A) and dialkyi tin sulfides) be at least 0.2:1, more preferably at least 1:1, and yet more preferably 2:1 to 4:1. In a most preferred embodiment this ratio is about 3:1. The ratio of all compounds of formula (A) present, to the total of monoalkyl tin sulfides and dialkyi tin sulfides present should be in the range of about 10:1 to 0.1:1, and preferably in the range of 1:1 to 2:1. The admixture can be prepared by adding monoalkyl tin trihalide and/or dialkyi tin dihalide to an alkaline solution of, for example, ammonium hydroxide, potassium hydroxide, or sodium hydroxide; reacting this solution with an amount of mercapto ester HS-R a -OC(=0)R 2 less than sufficient to react with all the monoalkyl tin and dialkyi tin present; and then adding a solution of a sulfide such as sodium sulfide in water, in an amount that will convert remaining monoalkyl tin and dialkyi tin to the corresponding sulfides. The amounts of the respective reactants used are selected to provide the products in the desired final ratios with respect to each other. Also present in the activators of the present invention is a complex formed of a diorganotin oxide with an ester of an oxygen-containing acid. Preferably the diorgano tin oxide is a dialkyi tin oxide wherein each alkyl group contains 1 to 8 carbon atoms. A preferred oxide is dibutyl tin oxide. Many esters of oxygen-containing acids are useful in the activator. Preferred are the phthalates, including diisooctyl phthalate (DIOP) , as well as dimethyl phthalate, diethyl phthalate, propyl phthalate, dibutyl phthalate, dibutyl phthalate, diamyl phthalate, dioctyl phthalate, butyl glycol phthalate, diphenylphthalate, methoxyethyl phthalate, and butoxyethyl phthalate. Other oxygen-containing esters include but are not limited to ethyl ortho silicate, triethyl arsenate, n-propyl nitrate, n-octyl nitrate, o-cresyl-p-toluene sulphonate, cyclohexyl p- toluene sulphonamide, di-n-propyl sulfate, di-n- dodecyl sulfate, trimethyl phosphate, triethyl phosphate, tri-n-propyl phosphate, tributylphosphate, triisobutyl phosphate, triamyl phosphate, tri-o-cresyl phosphate, tri-p-cresyl phosphate, tri-m-cresyl phosphate, triphenyl phosphate, trixylyl phosphate, butyl di- { β-methoxyethyl) phosphate, butyl di(/3- ethoxyethyl) phosphate, sorbityl hexaphosphate, amylborate, methyl acetate, ethyl acetate, n- propylacetate, isopropyl acetate, butylacetate, - cresyl acetate, phenyl acetate, ethylene glycol diacetate, diglycerol tetraacetate, glycerol monolactate acetate, methyl propionate, n-butyl propionate, sec-butyl propionate, ethylene glycol dipropionate, triethylene glycol dipropionate, ethyl butyrate, n-propyl butyrate, butyl butyrate, pentyl butyrate, 2-propenyl butyrate, hexyl butyrate, ethylene glycol dibutyrate, ethyl laurate, phenyl laurate, ethyl stearate, butyl stearate, ethyl palmitate, 2-naphthyl lactate, ethyl benzoate, β- 1 naphthyl benzoate, benzyl benzoate, methyl o-benzoyl benzoate, ethyl o-benzoyl benzoate, amyl benzoate, sorbityl hexabenzoate, diethyl oxalate, dibutyl oxalate, diethyl oxalate, diamyl oxalate, dimethyl 5 maleate, diethyl maleate, dipropyl maleate, dipropenyl maleate, diethyl adipate, dibutyl adipate, ethoxyethyl adipate, diethyl sebacate, dibutyl sebacate, diethyl succinate, dibutyl succinate, triethyl citrate, tributyl citrate, dibutyl tartrate, dibutyl tartrate, 0 diamyl tartrate, methyl phthalyl ethyl glycolate, ethyl phthalyl ethyl glycolate, butyl phthalyl butyl glycolate, methyl salicylate, phenyl salicylate, dioctyl thiodipropionate and dithiobis (isooctyl propionate) . 5 The complex is preferably formed by combining the oxide and ester components and heating the mixture to liquefaction or dissolution, whereupon the components react and from a stable, homogeneous product. Preferably the mole ratio of the oxide to the acid is in the range 1.1:1 to 1:1.1, and more preferably 1:1. The mole ratio of the amount of the component of formula (A) to the amount of the complex is generally in the range 2:1 to 0.5:1 and preferably 5 1.5:1 to 0.8:1. A mercapto ester component is preferably present in the activator composition together with the admixture of the compound(s) of formula (A), the monoalkyl tin and/or dialkyi tin sulfides, and the 0 13 '3 complex of diorganotin oxide-oxygen-containing acid. This mercapto ester component comprises one or more esters of the formula HS-R c -OC(=0)R 3 . R c is a divalent alkyl radical containing 2 to 20 carbon atoms, and preferably 2 to 6 carbon atoms. A preferred R c is - CH 2 CH a -. The radical R 3 is straight or branched alkyl or alkenyl containing 6 to 24 carbon atoms and 0 to 4 carbon-carbon double bonds. As is the case for the radical R 2 defined herein, R 3 is preferably the residue of a medium-chain or long-chain fatty acid, or of a mixture of such acids. Exemplary radicals include residues of the alkanoic and alkenoic acids exemplified herein for R 2 . When one or more esters of the formula HS- R c -0C(=0)R 3 and/or one or more alkyl ercaptans of the formula R'-SH are present in the activator composition, the total amount thereof should generally correspond to a mole ratio of 0.01:1 to 0.2:1 based on the amount present of compounds of formula (A) . Preferably, this mole ratio is in the range of up to 0.1:1. In another aspect of the present invention, an activator composition can be formed which comprises one or more of the aforementioned complexes of diorganotin oxide and oxygen-containing ester, one or more of the aforementioned esters of the formula HS- R c -0C(=0)R 3 , and an admixture as defined hereinabove of one or more monoalkyl tin sulfides, dialkyi tin sulfides, or preferably both, with an ester of the formula (A*) (R 1 ) a Sn(-S-Z- (C(=0)OR m ) 4 . a (A*) 1 In this formula, R 1 and a are as defined above, and m is 1 to 4. The moiety -Z- is a divalent organic radical which preferably is alkyl containing 1 to 30 5 carbon atoms, and more preferably is ethyl. The radical R ra is an organic group derived from an alcohol containing 1 to 30 carbon atoms and 1 to 4 hydroxyl groups. The preferred moiety -S-Z- (C(=0)OR m ) m is a thioglycolate such as octyl thioglycolate. Preferred 0 compounds of formula (A*) include dimethyl tin bis (isooctylthioglycolate) . Another embodiment of the present invention comprises activators comprising one or more esters of formula (A*) admixed with monoalkyl tin sulfide and 5 dialkyi tin sulfide, as defined hereinabove, and further comprising one or more of the aforementioned complexes of diorganotin oxide and oxygen-containing ester. The mole ratio of all monoalkyl tin compounds to all dialkyi tin compounds (based on esters of formula (A*) together with sulfides) is at least 0.2:1, more preferably at least 1:1, and most preferably 2:1 to 4:1. Otherwise when an ester of formula (A*) is used, the relative amounts of it to the other activator components, and the amounts of such other components to each other, are the same as stated above for the embodiments when an ester of formula (A) is used. The compositions of the present invention are preferably used to advantage in combination with 15 > vinyl halide resins, preferably polyvinyl chloride 1 resins. The term "polyvinyl chloride" as used herein is inclusive of any polymer formed at least in part of the recurring group (-CHC1-CX 2 -) p and having a chlorine content in excess of 40%. In this formula, each of 5 the X groups can be either hydrogen or chlorine, and p is the number of units in each polymer chain. In polyvinyl chloride homopolymers, each of the X groups is hydrogen. Thus, the terms "PVC" and "polyvinyl chloride" include not only polyvinyl chloride 0 homopolymers but also after-chlorinated polyvinyl chlorides, as well as copolymers of vinyl chloride in a major proportion with other copolymerizable monomers in moderate proportion such as copolymers of vinyl chloride and vinyl acetate, copolymers of vinyl 5 chloride with maleic or fumaric acids or esters, and copolymers of vinyl chloride with styrene. The stabilizer compositions are effective also with mixtures of polyvinyl chloride in major proportion with a minor proportion of other synthetic resins such as chlorinated polyethylene or copolymers of acrylonitrile, butylene and styrene. The compositions of the present invention are used in small but effective amounts to activate the blowing agents and impart heat stability, that is, 5 enhanced resistance to heat-mediated deterioration which is due to exposure to excessive heat, as well as deterioration which is initiated or accelerated by exposure to heat. Effective performance is afforded generally by adding about 0.1 to about 5 phr (parts by 0 16 Y ) weight per hundred parts by weight of resin) of the composition. Preferred amounts of the composition are generally in the range of about 1 to 4 phr. The composition can be compounded into the resin formulation in accordance with conventional t5r. compounding techniques abundantly familiar to one of ordinary skill in this art. The compositions of the present invention can be used with unplasticized or plasticized polyvinyl chloride resin compositions of conventional 10 formulation. Conventional plasticizers well known to those skilled in the art -an be employed such as, for example, dioctyl phthalate, octyl diphenylphospate, and epoxidized soybean oil. Particularly useful plasticizers are the epoxidized esters having from 20 15 to 150 carbon atoms. Plasticizers, if used, generally comprise 5 to 40 phr. The polyvinyl chloride resin composition comprising these components can also contain conventional additional additives such as 2n antioxidants, lubricity agents, flame retardants, fillers, pigments, and the like, in relative amounts effective to fulfill the desired functions of each ingredient. These ingredients, if desired, can be added prior to, during, or subsequent to the step in which the composition of the present invention is compounded into the polyvinyl chloride. Conventional processing aids may also be used in the amounts necessary to smooth and homogenize 17 ~> > the blowable composition melt and facilitate its passage through a conventional extruder. After the components in the formulation have been mixed in the manner described, this dry blend composition is then processed in a conventional extruder which has been fitted with the desired die and which extruder has been heated to the desired temperature. The extruder is then operated at a screw speed under a motor load as indicated for the rate desired. The temperatures and resid e nce times are 0 selected to form products which are commercially acceptable. Unless the activator system as shown herein is used in the formulations described there is danger of excessive decomposition of the exothermic chemical blowing agents resulting in loss of control 5 an unsatisfactory cell structure, required profile dimensions and smoothness of skin which is dependent upon the internal microcellular structure of the profile. The chemical balance present in the blowable 0 composition of this invention results in the proper fluxing of the vinyl resin to produce a molten mixture into which the gaseous nitrogen is released at the proper time by the blowing agent, which then becomes dissolved in the molten plastic under the operating 5r. pressures of the extruder. As the plastic molt passes through the die into the atmosphere the pressure built up within the extruder is relieved causing the dissolved gaseous nitrogen to emerge from solution and form the microcellular gas cells uniformly throughout o 18 the extruded mass other than within the skin layer. The skin layer forms because of the laminar flow across the relatively cool metal surface of the die. Laminar flow is described as being a series of concentric layers of molten plastic, the most interior layer moving somewhat faster than the outer layers. The molten thermoplastic mixture that touches the cooler metal surface of the die becomes much more viscous than the next layer thereof and as a result a smearing action drives the gaseous nitrogen into the interior layers of the profile to thereby form a relatively smooth and integral skin. The successful performance as just described depends upon the formulation of the expandable composition and particularly upon the combination of the activator system described herein in combination with the chemical blowing agent and the particular resin being blown. The formation of a smooth integral skin is dependent, among other things, upon the amount of chemical blowing agent used. If a certain porosity is desired beyond an amount which requires a greater amount of blowing agent, it is obvious that although the increased porosity is achieved, the skin will have been disrupted and its smoothness destroyed. The present invention permits a maximum expansion of the extruded profile or a minimum density foam without destroying the requirements of a smooth and integral skin. This is achieved in the present invention by the use of the activator system which functions to extract a maximum amount of gas from the blowing agent at the preferred thermal conditions for extrusion, thus producing a blow which would otherwise be possible only by increasing the amount of blowing agent. Thus the present activator system of this invention permits a fine adjustment with regard to the amount of gas released from the chemical blowing agent and thus preserving the desirable properties of the smooth and integral skin required for the profile. The activator system of this invention functions to control the temperature and rate at which the gaseous nitrogen is released from the chemical blowing agent, which temperature and rate are adjusted in such a way that the resin composition becomes a plastic melt at a temperature to permit its expansion while at the same time restricting the size of the cells to the microcellular characteristics required in the profile. The utility of the foamed polyvinylchloride resins of the present invention is extensive, being useful wherever foamed polyvinylchloride resin has found utility. It is particularly of value in locations where it is visible since by use of the present activators in the foaming operation, the foamed resin does not become colored as can occur when the foaming occurs at high temperatures. Thus, for example, the foamed polyvinylchloride resins of the present process can be used as the inner-most layer of pipe, or the intermediate layer of a three-layer system, by coextrusion with unfoamed resin. Other such visible uses include construction profiles such as window and door frames. By limiting the discoloration of the resin and forming a skin of good texture, the present invention produces foamed resin which is not limited by its appearance to interior applications. The following example further illustrates the invention and is not intended to limit the scope of the invention described herein. EXAMPLE 1 Into 200 grams of water was dissolved 130.2 grams (1.4977 moles of chloride) of 3:1 (molar) monomethyl tin chloride: dimethyl tin chloride reagent. This solution was heated to 60-70°C, and then 187.2 grams of a 20 wt.% aqueous solution of NaOH (0.9361 moles NaOH) was added followed by 332.2 grams (0.9361 moles) of 2-mercaptoethyl tallate (9.3% SH) . The resulting mixture was agitated for 30 minutes. Then, 36.5 grams (0.2808 moles) of Na 2 S and 200 grams of water were added. The resulting mixture was agitated and then allowed to settle for 2 hours, whereupon it separated into two distinct layers of liquid. The upper layer was recovered and stripped at 20 mm Hg at up to 110°C. To the stripped product was added 5.0 grams of filter aid ("Superc.il"); the product was filtered, providing 390 grams of product (1-A) comprising mono-/dimethyl tin mercaptoethyl tallate-mono-/dimethyl tin sulfide (mono:di=3 :1) . Separately, 2,250 pounds of diisooctyl phthalate was charged to a reactor and heated to 145- 150°C. To this was added 2,250 pounds of dibutyl tin oxide, over about one hour. The resulting mixture was stirred for about half an hour to produce a clear liquid, which was then cooled to 120-125°C. Filter aid (30 pounds) was added and the liquid was filtered and recirculated, to provide product (1-B) . Equal amounts by weight of products (1-A) and (1-B) were combined and stirred together to form a homogeneous liquid product (1-C) . This product was found to be an effective activator for the degradation of azodicarbonamide in PVC, compared to an equal amount of a 1:1 mixture of a dimethyl tin isooctyl thioglycolate: dibutyl tin oxide/diisooctyl phthalate complex as described in the aforementioned U.S. Patent No. 4,977,193. COMPARATIVE EXAMPLE A composition according to component (a) as defined hereinabove, mono/dimethyl tin mercaptoethyl tallate/sulfide, having a 3 :1 mole ratio of monomethyl tin species to dimethyl tin species, was prepared and formulated into an activator as shown in the table below. This activator was compared, as to its effect as an activator of the blowing agent azodicarbonamide ("AZO") , to a reference activator prepared according to U.S. Patent No. 4,977,193. The compositions contained (in % by weight of the composition) : A= Activator X=Reference of the Invention Activator Dimethyl tin 0. 50 2-ethylhexyl- thioglycolate 3 : 1 Mono/ dimethyl tin mercaptoethyl tallate/sulfide 40 0. Dibutyl tin 50 50. oxide/diisooctyl 10 phthalate, 1:1 (molar) complex Mercaptoethyl 10. 0. tallate Each activator was compounded into a PVC I -. formulation having the following formula: Component Parts by. weight PVC (K-value=67) 100.0 Calcium stearate 1.0 Paraffin waxes 0.5 20 Ti0 2 1.0 CaC0 3 5.0 AZO 0.4 Acrylate processing 4.5 aids ("Paraloid K-400" and "Paraloid K-175", Rohm & Haas) 1.5 25 Activator 1.5 After preparation and extrusion under identical conditions, the sample prepared using the activator of the present invention had a density of 0.53 grams/cc, 50 23 5 whereas the sample prepared using the reference activator had a density of 0.58 grams/cc. This 8.6% improvement in density signifies greatly, improved activation of the AZO blowing agent, and signifies a significantly superior PVC product. While this improvement is clearly seen to be unexpected upon comparison of the densities obtained, the improvement is all the more unexpected given that it was obtained using, with the present invention, fewer moles of tin compound in the PVC sample. The lower amount of tin could be expected to cause the activation to be lower, whereas in fact it was higher, as evidenced by the reduction in density.

Claims: WHAT IS CLAIMED IS: 1. An activator system comprising (a) one or more compounds of formula (A) (R 1 ) a Sn(-S-R a -0C(=0)R 2 ) 4 . a (A) wherein R 1 independently at each occurrence is straight or branched alkyl containing 1 to 12 carbon atoms; R a is a divalent alkyl radical containing 2 to 20 carbon atoms; a is 1 to 2; R 2 independently at each occurrence is straight or branched alkyl or alkenyl containing 6 to 24 carbon atoms and 0 to 4 carbon-carbon double bonds; admixed with one or more compounds selected from the group consisting of monoalkyl tin sulfides and dialkyltin sulfides, in which group each alkyl substituent is independently straight or branched alkyl containing 1 to 12 carbon atoms; and (b) a diorganotin complex with an ester of an oxygen-containing acid, wherein the two organo groups are each attached to tin through carbon atoms and are hydrocarbon radicals having from one to about thirty carbon atoms, and said complex is derived from the reaction of a diorganotin oxide with an ester derived from an aliphatic or aromatic alcohol or phenol and an acid selected from the group consisting of hydrocarbyl carboxylic acids, sulfur-containing hydrocarbyl carboxylic acids, hydroxy-containing hydrocarbyl carboxylic acids, phosphoric acid, sulfuric acid, sulphurous acid, nitric acid, nitrous acid, boric acid, arsenic acid and silicic acid. 2. An activator system according to Claim 1 comprising a mixture of one or more compounds of formula (A) wherein a is 1, one or more compounds of formula (A) wherein a is 2, one or more monoalkyl tin sulfides, and one or more dialkyi tin sulfides. 3. An activator system according to Claim 1 wherein R 1 contains 1 to 4 carbon atoms, and the alkyl substituents in said group consisting of monoalkyl tin sulfides and dialkyi tin sulfides contain 1 to 4 carbon atoms. 4. An activator system according to Claim 3 wherein all R 1 substituents and the alkyl groups on all monoalkyl and dialkyi tin sulfides present are methyl . 5. An activator system according to Claim 1 wherein R a contains 2 to 6 carbon atoms. 6. An activator system according to Claim 1 wherein said diorganotin oxide is dialkyi tin oxide and said ester is a dialkyi phthalate. 7. An activator system according to Claim 6 wherein said diorganotin oxide is dibutyl tin oxide and said ester is diisooctyl phthalate. 8. An activator system according to Claim 2 wherein all R 1 substituents and the alkyl groups on all monoalkyl and dialkyi tin sulfides present are methyl; R is -CH 2 CH 2 -; said diorganotin oxide is dibutyl tin oxide and said ester is diisooctyl 1 phthalate. 9. An activator system according to Claim 1, further comprising one or more esters of the formula HS-R c -0C(=0)R 3 , wherein R c is a divalent alkyl 5 radical containing 2 to 20 carbon atoms, and R 3 is straight or branched alkyl or alkenyl containing 6 to 24 carbon atoms and 0 to 4 carbun-carbon double bonds. 10. An activator system according to Claim 9 comprising a mixture of one or more compounds of 10 formula (A) wherein a is 1, one or more compounds of formula (A) wherein a is 2, one or more monoalkyl tin sulfides, and one or more dialkyi tin sulfides. 11. An activator system according to Claim 9 wherein R 1 contains 1 to 4 carbon atoms, and the 15 alkyl substituents in said group consisting of monoalkyl tin sulfides and dialkyi tin sulfides contain 1 to 4 carbon atoms. 12. An activator system according to Claim 11 wherein all R 1 substituents and the alkyl groups on 20 all monoalkyl and dialkyi tin sulfides present are methyl . 13. An activator system according to Claim 9 wherein R a contains 2 to 6 carbon atoms. 14. An activator system according to Claim 25 9 wherein said diorganotin oxide is dialkyi tin oxide and said ester is a dialkyi phthalate. 30 27 i l j 15. An activator system according to Claim 1 14 wherein said diorganotin oxide is dibutyl tin oxide and said ester is a diiooctyl phthalate. 16. An activator system according to Claim 10 wherein all R 1 substituents and the alkyl groups on 5 all monoalkyl and dialkyi tin sulfides present are methyl; R a is -CH 2 CH 2 -; R is -CH_,CH 2 -; said diorganotin oxide is dibutyl tin oxide; and said ester is diisooctyl phthalate. 17. An activator system comprising 10 (a') one or more compounds of formula (A*) (R 1 ) a Sn(-S-Z-(C00R m ) 4 . a (A*) where R 1 independently at each occurrence is straight 5 or branched alkyl containing 1 to 12 carbon atoms, a is 1 to 2, Z is an organic radical containing 1 to 30 carbon atoms, each R m is independently an organic radical derived from an alcohol containing 1 to 4 hydroxyl groups and containing 1 to 30 carbon atoms, 0 and m is 1 to 4 ; admixed with one or more compounds selected from the group consisting of monoalkyl tin sulfides and dialkyi tin sulfides, in which group each alkyl substituent independently is straight or branched alkyl containing 1 to 12 carbon atoms; 5 (b) a diorganotin complex with an ester of an oxygen-containing acid, wherein the two organo groups are each attached to tin through carbon atoms and are hydrocarbon radicals having from one to about thirty carbon atoms, and said complex is derived from 30 28 ' 35 the reaction of a diorganotin oxide with an ester derived from an aliphatic or aromatic alcohol or phenol and an acid selected from the group consisting of hydrocarbyl carboxylic acids, hydroxy-containing hydrocarbyl carboxylic acids, phosphoric acid, sulfuric acid, arsenic acid and silicic acid; and one or more esters of the formula HS-R C - 0C(=0)R 3 , wherein R c is a divalent alkyl radical containing 2 to 20 carbon atoms, and R 3 is straight or branched alkyl or alkenyl containing 6 to 24 carbon atoms and 0 to 4 carbon-carbon double bonds. 18. An activator system according to Claim 17 comprising a mixture of one or more compounds of formula (A) wherein a is 1, one or more compounds of formula (A) wherein a is 2, one or more monoalkyl tin sulfides, and one or more dialkyi tin sulfides. 19. An activator system according to Claim 17 wherein R l contain 1 to 4 carbon atoms, and the alkyl substituents in said group consisting of monoalkyl tin sulfides and dialkyi tin sulfides contain 1 to 4 carbon atoms. 20. An activator system according to Claim 19 wherein all R 1 substituents and the alkyl groups on all monoalkyl and dialkyi tin sulfides present are methyl. 21. An activator system according to Claim 17 wherein R c contains 2 to 6 carbon atoms. 22. An activator system according to Claim 17 wherein said diorganotin oxide is dialkyi tin oxide and said ester is a dialkyi phthalate. 23. An activator system according to Claim 1 22 wherein said diorganotin oxide is dibutyl tin oxide and said ester is a diisooctyl phthalate. 24. An activator system according to Claim 18 wherein all R 1 substituents and the alkyl groups on 5 all monoalkyl and dialkyi tin sulfides present are methyl; R c is -CH 2 CH 2 -; said diorganotin oxide is dibutyl tin oxide; and said ester is diisooctyl phthalate. 25. An activator system comprising (a 1 ) one 10 or more compounds of formula (A*) (RO.SnJ-S-Z- (C00R ro ) 4 . a (A*) wherein R 1 independently at each occurrence is straight or branched alkyl containing 1 to 12 carbon atoms, a is 1 to 2, Z is an organic radical containing 15 l to 30 carbon atoms, each P m is independently an organic radical derived from an alcohol containing 1 to 4 hydroxyl groups and containing 1 to 30 carbon atoms, and m is 1 to 4 ; admixed with one or more monoalkyl tin sulfides and one or more dialkyi tin 20 sulfides, in which each alkyl substituent independently is straight or branched alkyl containing 1 to 12 carbon atoms; wherein the molar ratio of monoalkyl tin compounds to dialkyi tin compounds is at least 0.2:1, o r5, based on all compounds of formula (A*) and all monoalkyl and dialkyi tin sulfides present; (b) a diorganotin complex with an ester of an oxygen-containing acid, wherein the two organo groups are each attached to tin through carbon atoms 30 30 35 and are hydrocarbon radicals having from one to about thirty carbon atoms, and said complex is derived from the reaction of a diorganotin oxide with an ester derived from an aliphatic or aromatic alcohol or phenol and an acid selected from the group consisting of hydrocarbyl carboxylic acids, hydroxy-containing hydrocarbyl carboxylic acids, phosphoric acid, sulfuric acid, arsenic acid and silicic acid. 26. An activator system according to Claim 25 comprising a mixture of one or more compounds of formula (A) wherein a is 1, one or more compounds of formula (A) wherein a is 2, one or more monoalkyl tin sulfides, and one or more dialkyi tin sulfides. 27. An activator system according to Claim 25 wherein R 1 contain 1 to 4 carbon atoms, and the alkyl substituents in said group consisting of monoalkyl tin sulfides and dialkyi tin sulfides contain 1 to 4 carbon atoms. 28. An activator system according to Claim 27 wherein all R 1 substituents and the alkyl groups on all monoalkyl and dialkyi tin sulfides present are methyl . 29. An activator system according to Claim 25 wherein R c contains 2 to 6 carbon atoms. 30. An activator system according to Claim 25 wherein said diorganotin oxide is dialkyi tin oxide and said ester is dialkyi phthalate. 31. An activator system according to Claim 30 wherein said diorganotin oxide is dibutyl tin oxide and said ester is diisooctyl phthalate. 32. An activator system according to Claim 26 wherein all R 1 substituents and the alkyl groups on all monoalkyl and dialkyi tin sulfides present are methyl; R c is -CH 2 CH 2 -; said diorganotin oxide is dibutyl tin oxide; and said ester is diisooctyl phthalate. 33. A foamed rigid PVC composition comprising an activator system according to Claim l. 34. A foamed rigid PVC composition comprising an activator system according to Claim 8. 35. A foamed rigid PVC composition comprising an activator system according to Claim 9. 36. A foamed rigid PVC composition comprising an activator system according to Claim 16. 37. A foamed rigid PVC composition comprising an activator system according to Claim 17. 38. A foamed rigid PVC composition comprising an activator system according to Claim 24. 39. A foamed rigid PVC composition comprising an activator system according to Claim 25. 4o. A foamed rigid PVC composition comprising an activator system according to Claim 32. 41. A method of producing a foamed rigid PVC composition comprising subjecting a foamable composition comprising PVC, a blowing agent for said foamable composition, and an activator system according to Claim 1, to conditions under which said foamable composition is converted into foamed rigid PVC. 42. A method of producing a foamed rigid PVC composition comprising subjecting a foamable composition comprising PVC, a blowing agent for said foamable composition, and an activator system according to Claim 8, to conditions under which said foamable composition is converted into foamed rigid PVC. 43. A method of producing a foamed rigid PVC composition comprising subjecting a foamable composition comprising PVC, a blowing agent for said foamable composition, and an activator system according to Claim 9, to conditions under which said foamable composition is converted into foamed rigid PVC. 44. A method of producing a foamed rigid PVC composition comprising subjecting a foamable composition comprising PVC, a blowing agent for said foamable composition, and an activator system according to Claim 16, to conditions under which said foamable composition is converted into foamed rigid 45. A method of producing a foamed rigid PVC composition comprising subjecting a foamable composition comprising PVC, a blowing agent for said foamable composition, and an activator system according to Claim 17, to conditions under which said foamable composition is converted into foamed rigid PVC. 46. A method of producing a foamed rigid PVC composition comprising subjecting a foamable composition comprising PVC, a blowing agent for said foamable composition, and an activator system according to Claim 24, to conditions under which said foamable composition is converted into foamed rigid PVC. 47. A method of producing a foamed rigid PVC composition comprising subjecting a foamable composition comprising PVC, a blowing agent for said foamable composition, and an activator system according to Claim 25, to conditions under which said foamable composition is converted into foamed rigid PVC. 48. A method of producing a foamed rigid PVC composition comprising subjecting a foamable composition comprising PVC, a blowing agent for said foamable composition, and an activator system according to Claim 32, to conditions under which said foamable composition is converted into foamed rigid PVC. AMENDED CLAIMS [received by the International Bureau on 23 May 1997 (23.05.97); original claims 1-48 replaced by new claims 1-14 (4 pages)] 1. An activator system comprising (a) one or more compounds of formula (A) (R 1 ) β Sn(-S-R a -OC(=0)R 2 ) 4-1 ( A) wherein R 1 independently at each occurrence is straight or branched alkyl containing 1 to 12 carbon atoms; R* is a divalent alkyl radical containing 2 to 20 carbon atoms; a is 1 to 2; R 2 independently at each occurrence is straight or branched alkyl or alkenyl containing 6 to 24 carbon atoms and 0 to 4 carbon-carbon double bonds; admixed with one or more compounds selected from 0 the group consisting of monoalkyl tin sulfides and dialkyltin sulfides, in which group each alkyl substituent is independently straight or branched alkyl containing 1 to 12 carbon atoms; and (b) a diorganotin complex with an ester of an -* oxygen-containing acid, wherein the two organo groups are each attached to tin through carbon atoms and are hydrocarbon radicals having from one to about thirty carbon atoms, and said complex is derived from the reaction of a diorganotin oxide with an ester derived from an aliphatic or 0 aromatic alcohol or phenol and an acid selected from the group consisting of hydrocarbyl carboxylic acids, sulfur- containing hydrocarbyl carboxylic acids, hydroxy-containing hydrocarbyl carboxylic acids, phosphoric acid, sulfuric acid, sulphurous acid, nitric acid, nitrous acid, boric -> acid, arsenic acid and silicic acid. 2. An activator system according to Claim 1, further comprising one or more esters cf the formula HS-R C - OC(»0)R 3 , wherein R c is a divalent alkyl radical containing 2 to 20 carbon atoms, and R 3 is straight cr branched alkyl or ° alkenyl containing 6 to 24 carbon atoms and 0 to 4 carbon- carbon double bonds. 3. An activator system comprising (a' ) one or more compounds cf formula (A*) 5 (R α ) a Sn(-S-Z- (COOR ra ) 4 . a " (A*) where R 1 independently at each occurrence is straight or branched alkyl containing 1 to 12 carbon atoms, a is 1 to 2, Z is an organic radical containing 1 to 30 carbon atoms, 1 each R m is independently an organic radical derived from an alcohol containing 1 to 4 hydroxyl groups and containing 1 to 30 carbon atoms, and m is 1 to 4 ; admixed with one or more compounds selected from the group consisting of monoalkyl tin sulfides and dialkyi tin sulfides, in which group each alkyl substituent independently is straight or branched alkyl containing 1 to 12 carbon atoms; (b) a diorganotin complex with an ester of an oxygen-containing acid, wherein the two organo groups are 0 each attached to tin through carbon atoms and are hydrocarbon radicals having from one to about thirty carbon atoms, and said complex is derived from the reaction of a diorganotin oxide with an ester derived from an aliphatic or aromatic alcohol or phenol and an acid selected from the ■ ^ group consisting of hydrocarbyl carboxylic acids, hydroxy- containing hydrocarbyl carboxylic acids, phosphoric acid, sulfuric acid, arsenic acid and silicic acid; and one or more esters of the formula HS-R c -0C(=0)R 3 , wherein R c is a divalent alkyl radical containing 2 to 20 O carbon atoms, and R 3 is straight or branched alkyl or alkenyl containing 6 to 24 carbon atoms and 0 to 4 carbon-carbon double bonds. 4. An activator system comprising (a 1 ) one or more compounds of formula (A*) 5 (R 1 ) a Sn(-S-Z-(COOR m ) 4-a (A*) wherein R 1 independently at each occurrence is straight or branched alkyl containing 1 to 12 carbon atoms, a is 1 to 2, Z is an organic radical containing 1 to 30 carbon atoms, each R m is independently an organic radical derived from an 0 alcohol containing 1 to 4 hydroxyl groups and containing 1 to 30 carbon atoms, and m is 1 to 4; admixed with one or more monoalkyl tin sulfides and one or more dialkyi tin 35 5 AMENDED SHEET {ARTICLE 19) sulfides, in which each alkyl substituent independently is straight or branched alkyl containing 1 to 12 carbon atoms; wherein the molar ratio of monoalkyl tin compounds to dialkyi tin compounds is at least 0.2:1, based on all compounds of formula (A*) and all monoalkyl and dialkyi tin sulfides present; (b) a diorganotin complex with an ester of an oxygen-containing acid, wherein the two organo groups are each attached to tin through carbon atoms and are hydrocarbon radicals having from one to about thirty carbon atoms, and said complex is derived from the reaction of a diorganotin oxide with an ester derived from an aliphatic or aromatic alcohol or phenol and an acid selected from the group consisting of hydrocarbyl carboxylic acids, hydroxy- containing hydrocarbyl carboxylic acids, phosphoric acid, sulfuric acid, arsenic acid and silicic acid. 5. An activator system according to any one of Claims 1 to 4 comprising a mixture of one or more compounds of formula (A) wherein a is 1, one or more compounds of formula (A) wherein a is 2, one or more monoalkyl tin sulfides, and one or more dialkyi tin sulfides. 6. An activator system according to any one of Claims 1 to 4 wherein R 1 contain 1 to 4 carbon atoms, and the alkyl substituents in said group consisting of monoalkyl tin sulfides and dialkyi tin sulfides contain 1 to 4 carbon atoms. 7. An activator system according to Claim 6 wherein all R 1 substituents and the alkyl groups on all monoalkyl and dialkyi tin sulfides present are methyl. 8. An activator system according to Claim 1 or 2 wherein R a contains 2 to 6 carbon atoms. 9. An activator system according to Claims 3 or 4 wherein R c contains 2 to 6 carbon atoms. 10. An activator system according to any one of Claims 1 to 4 wherein said diorganotin oxide is dialkyi tin oxide and said ester is dialkyi phthalate. 11. An activator system according to Claim 10 wherein said diorganotin oxide is dibutyl tin oxide and said ester is diisooctyl phthalate. 12. An activator system according to Claim 5 wherein all R l substituents and the alkyl groups on all monoalkyl and dialkyi tin sulfides present are methyl; R a and R c is -CH 2 CH 2 - ; said diorganotin oxide is dibutyl tin oxide ; and said ester is diisooctyl phthalate. 13. A foamed rigid PVC composition comprising an activator system according to any one of Claims 1 to 12. 14. A method of producing a foamed rigid PVC composition comprising subjecting a foamable composition comprising PVC, a blowing agent for said foamable composition, and an activator system according to any one of Claims 1 to 12, to conditions under which said foamable composition is converted into foamed rigid PVC. 38 AMENDED SHEET {ARTICLE 19)

Inventors: MARTIN CURTIS R, MARTIN, CURTIS, R.
Applicants: WITCO CORP, WITCO CORPORATION
Application year: 1997
Main classification: C08K15
IPC codes: C07F7, C08J9, C08K5