AUTOMOTIVE CARBON BLACK AND RUBBER COMPOSITIONS THEREOF

Abstract: The invention relates to an improved carbon black for tire tread rubber. More particularly, the invention relates to a carbon black which imparts upon tire tread rubber improved tread wear, lower rolling resistance, lower heat buildup, and improved tear resistance. The improved carbon black is in the N100 series, and when in rubber, combines the long tread wear and low heat buildup advantages of N121 carbon black with the high tear resistance properties of N115 or N110. The improved carbon black has particular applications to truck and bus steel cord radial tire treads, especially for use in on/off highway conditions, and for high performance passenger car tires.

Description: PATENT APPLICATION TITLE OF THE INVENTION AUTOMOTIVE CARBON BLACK AND RUBBER COMPOSITIONS THEREOF CROSS-REFERENCE TO RELATED APPLICATIONS This application incorporates by reference, and claims priority of: U.S. Provisional Patent Application Serial No. 60/017,583, entitled A CARBON BLACK WITH ABRASION AND HYSTERESIS ADVANTAGES COMPARABLE TO N121 AND TEAR PROPERTIES COMPARABLE TO N115, filed May 16, 1996, and corresponding U.S. Patent Application Serial No. 08/697,734, filed 08/29/96. STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT Not applicable REFERENCE TO A "MICROFICHE APPENDIX" Not applicable BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to improved carbon black for tire tread rubber. More particularly, the present invention relates to carbon black which imparts upon tire tread rubber improved treadwear, lower rolling resistance, lower heat buildup and improved tear resistance. The improved carbon black is in the NlOO series and, when in rubber, combines the improved treadwear and low heat buildup advantages of N121 carbon black with the high tear resistance properties of NI 15. The present invention has particular application to truck and bus steel cord radial tire treads, especially for use in on/off highway conditions, and for high performance passenger car tires. 2. General Background of the Invention As worldwide dependence on truck transportation and other truck tire usage steadily increases, new designs in radial truck tire technology will have an increasingly significant impact on the many economies of the world. In recent years, many radial truck tire performance improvements have been made. However, further advances to resist both premature failure and accelerated treadwear in severe services are still needed in tire design and in compounding materials development. The art has recognized that there is a long felt but unresolved need for improved failure resistance and other performance improvements for tread compounds including longer treadwear, improved tear resistance, lower heat build-up and lower rolling resistance. (See, e.g., M.B. Rodgers and S.M. Mezynski, Kautschuk Gummi Kunst., 46, (9), 718 (1993); and, B. Lambillote and G S. Eiber, Rubber World, 209, (1), 27 (October 1993)). Carbon black, a form of elemental carbon, is widely used as a component of tire rubber, for both natural and synthetic rubbers and blends of natural rubber with synthetic polymers. The physical characteristics of carbon black, such as particle size and structure, affect various performance properties of rubber compounds, such as tire treadwear, rolling resistance, heat buildup and tear resistance. The present invention relates to a new carbon black (herein referred to as "carbon black A") designed to improve the qualities of tire tread rubber, including providing improved treadwear, lower rolling resistance, lower heat buildup and improved tear resistance. The improved carbon black is in the NlOO series and, when in rubber, combines the long treadwear and low heat buildup advantages of N121 carbon black with the high tear resistance properties of NI 15. The carbon black of the present invention is particularly well suited for improving the qualities of tread for truck and bus steelcord radial tires (TBS/RT), and high performance passenger car tires. Medium or heavy-duty steelcord radial truck and bus tires (TBS/RT) encompass a number of market segments classified as over the highway truck and bus, construction/agricultural, mixed on/off road, city service and special fuel economy tires. Currently, NlOO and N200 series tread carbon blacks (as specified in ASTM D 1765) are used in TBS/RT and their retread compounds. These tread blacks are broadly characterized as having both high surface area and high structure levels. The structure of a carbon black is the degree of particle aggregation, with a high structure carbon black having more particles aggregated into random structures than a low structure black. The structure of carbon black can be defined by the n-Dibutyl Phthalate Absoφtion number (DBPA). The larger the DBPA number, the higher the structure of the carbon black. Surface area can be measured by Iodine Adsorption number (Iodine No.). There is an inverse relationship between the iodine number surface area and particle size; the higher the number, the smaller the particle size. The particle size and structure of carbon black affect various qualities of rubber containing carbon black, such as tire treadwear, tread rolling resistance, tread heat buildup and tread tear resistance. Accordingly, different carbon blacks are used in different treads depending on the specific service requirements of the tires. For example, on-highway truck service exposes tires to high loads and high speeds over relatively smooth roads. For this application, in both Europe and North America, tread blacks such as N121, N110 and N234 are mainly used. Here, the performance concerns relate primarily to longer and more even treadwear. However, rolling resistance is becoming a very important performance concern worldwide. In TBS/RT the tread plays the most important role in controlling rolling resistance. The three aforementioned tread blacks (N121, NI 10 and N234), exhibit relatively high hysteresis characteristics (developing higher heat build-up temperatures and higher rolling resistance levels relative to coarser N200 and N300 series counterparts), with NI 10 being the most hysteretic followed by N121 and N234. Relative to each other, N121 develops the highest treadwear rating, followed by N234, and then NI 10. The applications for these tread blacks include new tread and retread compounds. In on/off-highway truck service, the tires, when off the highway, generally experience rougher roads and sharper turns with high loads and at lower speeds than on- highway service. However, when they come back to the highway they experience the same high speeds and temperature conditions as on-highway tires. For Europe and North America, the tread blacks commonly employed for this application include NI 10, NI 15 and N220. The performance concerns relate more to service life of the tread than to treadwear life. The greater the severity of tire service conditions the more important the resistance to failure becomes, particularly in the tread compound. These grades develop lower modulus levels and exhibit more resistance to tear than N121 orN234. NI 10 and NI 15 develop higher heat build-up temperatures and rolling resistance levels than N220 (or NI 21 and N234) and higher tear resistance levels. While N 115 and N 110 are used in on/off highway treads in Europe, N 115 is not used as much in this application in North America. These two tread blacks differ mainly in that NI 15 has higher tint, iodine number and nitrogen surface area levels than NI 10. Nevertheless, they perform similarly in rubber. TBS/RT are often composed of carbon black reinforced polymer systems that are based mostly on natural rubber (NR) or blends of NR and synthetic polymers (emulsion styrene-butadiene copolymer, SBR, and polybutadiene, BR, rubber). (See, e.g., M B. Rodgers and S.M. Mezynski, Kautschuk Gummi Kunst., 46, (9), 718 (1993), which is incoφorated herein by reference)). NR (natural rubber) is a natural product from latex-producing caoutchouc plants, of which the Hevea Brasiliensis is the most common, is a polyisoprene (methyl butadiene) elastomer. BR (butadiene rubber) is a synthetic rubber produced from either an emulsion or solution polymerization of butadiene joined mostly linearly by 1,4 (preferred in cis-1,4 but, also in certain measure, trans- 1,4 conformation) and by 1,2 additions. SBR (styrene-butadiene rubber) is a synthetic rubber produced from either an emulsion or solution polymerization of butadiene and styrene in various ratios. Among the rubbers suitable for use with the present invention are any natural rubbers, synthetic rubbers and blends of natural and synthetic rubbers. These include the so-called diene elastomers, i.e., for example oil-treated natural and synthetic rubbers, such as carboxyl rubbers, epoxy rubbers, transpolypentenamer, halogenated butyl rubbers, rubbers of 2-chlorobutadiene and polybutadiene rubbers. Typical of the synthetic rubbers are styrene-butadiene rubbers (SBR), whether clear or oil extended, emulsion SBR rubbers, high styrene SBR rubbers, solution SBR rubbers, starred solution SBR rubbers and functionalized solution SBR rubbers. Further still, suitable rubbers are rubbers, plastics and mixtures thereof which can be crosslinked with sulfur and vulcanization accelerator(s) and also with peroxide to form elastomers. These include the so-called diene elastomers, i.e. for example oil- extended natural and synthetic rubbers, such as natural rubbers, teφolymers of ethylene, propylene and unconjugated dienes; copolymers of ethylene and propylene and also carboxyl rubbers, epoxy rubbers, transpolypentamer, halogenated butyl rubbers, rubbers of 2-chlorobutadiene, ethyl/vinyl acetate copolymers and, optionally, chemical derivatives of natural rubber and modified natural rubbers. Any suitable natural or synthetic vulcanizable rubber can be used for puφoses of the invention. Copolymers can be used by themselves or mixed with at least one other diene elastomer, in particular polyisoprene, natural rubber or polybutadiene. The elastomer used in the blend is preferably polybutadiene having more than 90% cis-1,4 bonds obtained by known methods of catalysis with the use of transition metal as described, for instance, in French Patent 1,436,706. This other diene elastomer can be present in variable proportions with respect to the copolymer prepared in solution, and preferably up to 70 parts by weight. As conjugated diene, there are suitable, in particular, butadiene- 1,3, isoprene, and 2,3-dimethyl-l,3-butadiene. As aromatic vinyl compound, there are suitable, in particular, styrene, ortho-, meta- and para-methylstyrene or the commercial "vinyl- toluene" mix. The copolymer of conjugated diene and aromatic vinyl compound prepared in solution should have a total content of styrene of between 5 and 50% by weight and a glass transition temperature (Tg) of between 0 degrees and negative 80 degrees Celsius when measured by differential thermal analysis. The content of vinyl bonds in the thermal butadiene fraction incoφorated can be between 20 and 80%, the content of trans- 1,4 bonds can be between 20 and 80%, and the content of cis 1,4 bonds is complementary to the contents of vinyl bonds plus trans- 1,4 bonds. NR systems normally provide improved tear strength and building tack over synthetic polymer compositions and lower hysteresis due to the lower internal energy loss exhibited by NR on deformation. Further, the use of BR with NR can impart enhanced resistance to cut propagation and fatigue and improved abrasion resistance. SBR is used primarily in these blends to improve wet traction performance. Under low severity operating conditions, NR provides the best treadwear resistance performance relative to NR/BR blends. With higher severity highway conditions, NR/BR blends provide the better treadwear resistance performance particularly with a high BR content. NR also has the lower hysteresis response for lower rolling resistance in truck tires. The performance improvements needed for TBS/RT include improved treadwear and the reduction of tread compound hysteresis. The necessary emphasis is to reduce tread damage during service, particularly due to hysteresis, treadwear and tear performances. To satisfy these demands, tire components must develop high tear strength, high tensile strength and low heat build-up properties. For these reasons, the art has recognized a long felt but unresolved need for a more reinforcing and less hystereticNlOO series tread black for use in truck tire tread compounds. (See, e.g., M B. Rodgers and S.M. Mezynski, Kautschuk Gummi Kunst., 46, (9), 718 (1993)). The present invention satisfies this long felt but unmet need and provides a carbon black in the NlOO series which imparts upon tire tread rubber improved treadwear, lower rolling resistance, lower heat buildup and improved tear resistance. The improved carbon black is in the NlOO series and, when in rubber, combines the long treadwear and low heat buildup advantages of N121 carbon black with the high tear resistance properties of NI 15. The present invention particularly applies to truck and bus steel cord radial tire treads, especially for use in on/off highway conditions, and for high performance passenger car tires. BRIEF SUMMARY OF THE INVENTION The present invention relates to improved carbon black for tire tread rubber. More particularly, the present invention relates to carbon black which imparts upon tire tread rubber improved treadwear, lower rolling resistance, lower heat buildup and improved tear resistance. The present invention has particular application to truck and bus steel cord radial tire treads, especially for use in on/off highway conditions, and for high performance passenger car tires. More particularly, the present invention relates to a carbon black in the NlOO series, having a reduced structure, with a mean particle size of between about 16.0 and about 19.0 nm and a structure level, measured in DBPA of between about 100 to about 115 cc/lOOg. More particularly, carbon black having a reduced structure, wherein the mean particle size is measured per ASTM D3849, procedure D and is between about 17.0 and about 18.0 nm. Still more particularly, a carbon black having a reduced structure, wherein the structure is measured by ASTM D2414 and is between about 105 and about HO cc/lOOg. The present invention also relates to an improved carbon black having a modified aggregate shape distribution as determined by electron microscopy (See, e.g., C. R. Herd, et al., Rubber Chemistry and Technology 66, 491 (1993)) in conjunction with skeletonization of the aggregates via automated image analysis. Of the four shape categories defined for carbon black aggregates (1 -Spheroidal, 2 -Ellipsoidal, 3 -Linear and 4-Branched), the present invention relates to an improved carbon black having a higher level of low structure ellipsoidal aggregates compared to conventional tread blacks NI 15 and N121. Further, it was found that the carbon black of the present invention has a lower number of volume- weighted aggregate branches about the mode of the volume- weighted distribution of branches. This narrower distribution about the mode is characterized by the DELTA B50, which is the full width at half maximum of the volume- weighted branch distribution. The present invention further relates to an improved rubber composition containing an improved carbon black. More particularly, the present invention relates to an improved rubber composition containing an improved carbon black, wherein the carbon black imparts upon rubber composition improved treadwear, lower rolling resistance, lower heat buildup and improved tear resistance. The present improved rubber composition has particular application to truck and bus steel cord radial tire treads, especially for use in on/off highway conditions, and for high performance passenger car tires. More particularly, the present invention relates to an improved rubber composition containing an improved carbon black in the NlOO series, the improved composition having a treadwear rating for a natural rubber tread formulation on radial passenger cars of 107.2% relative to NI 10 at 100%, and tan delta hysteresis levels of 0.131 versus 0.137 and 0.145 for N110 and N115, respectively. The trouser tear resistance level of the improved composition is 82.6 kN/m compared to 81.3 and 49.3 kN/m for Ni l 5 and N121, respectively. More particularly, the improved rubber composition has abrasion and hysteresis properties of about 5%-10% higher and about 4 to 11% lower, respectively, and equivalent tear properties relative to NI 10 or NI 15. Still more particularly, the improved rubber composition has improved abrasion resistance (treadwear) and lower hysteresis properties of about 7% to about 10%, and about 5% to about 10%, respectively, as measured in relative treadwear ratings and tan delta level performances. Further, the present invention relates to an improved rubber composition, having an improved carbon black with a reduced structure, in DBPA, of between about 105 to about 110 cc/lOOg and improved tear resistance properties, comparable to NI 10 and NI 15, measured in kN/m, of between about 80 and about 85 kN/m. The data herein describe a new tread black, carbon black A, that has been developed for application in truck/bus steelcord radial tire treads to address the specific needs for improved treadwear, lower rolling resistance, lower heat build-up and improved tear resistance. This tread black is classified as having an NlOO fineness level, with a low surface microporosity level and a DBPA structure level comparable to NI 10 or N115. In the experiments below, carbon black A was evaluated relative to conventional Nl OO and N200 series tread blacks in two separate truck tread formulations: NR and NR/BR (65/35). In the non-oil-extended NR formulation, carbon black A was compounded at a 50 phr loading level relative to Nl lO, NI 15 and N121 at the same loading. In the oil-extended (25 phr) NR/BR formulation, carbon black A was compounded at a 60 phr loading level relative to Nl lO, N115, N121 and N234. However, the tread blacks were preferentially located in the elastomer blends with more (49.5 phr) in the NR phase. This distribution was achieved through the preparation and subsequent blending of separate elastomer masterbatches. In both tread formulations, carbon black A (relative to NI 10, NI 15 and N121) was shown to provide the desired specific performances of improved tear resistance, lower predicted rolling resistance, lower heat build-up and lower Mooney viscosity levels, while maintaining acceptable stress-strain and hardness property levels. In treadwear testing in the NR tread formulation, carbon black A had better treadwear ratings than Nl lO, with ratings equal to N121. For the NR/BR tread formulation, carbon black A exhibited better fatigue and better cut-growth resistances relative to NI 10, NI 15, N121 and N234. With respect to predicted relative wet traction peifOrrnance, carbon black A was superior to NI 10, comparable to NI 15 and N234, and close to the performance level of N121 in the NR/BR formulation. The predicted dry traction was better than N121, similar to N234 and less than NI 10 and NI 15. Although this invention relates to tread compounds containing NR or NR with BR, use of carbon black A in synthetic elastomers is expected to provide similar performance improvements. The unique performance of carbon black A with respect to Nl lO, N115 and N121 suggests applicability to truck tire treads where more severe service demands are experienced as well as to off-the-road tire treads. Here, the good heat build-up, tear, fatigue and cut-growth properties will provide improved tire performances. Other appropriate applications for carbon black A include high performance passenger tires, racing tires and truck tire retread compounds. BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS For a further understanding of the nature, objects, and advantages of the present invention, reference should be had to the following detailed description, read in conjunction with the following drawings, wherein like reference numerals denote like elements and wherein: FIGURE 1 shows 300% modulus (300% M) in NR tread, expressed in MPa; FIGURE 2 shows tensile strength (TS) in NR tread, expressed in MPa; FIGURE 3 shows shore hardness in NR tread, expressed in shore hardness units (SHU); FIGURE 4 shows Mooney viscosity (MV) (ML 1+4) in NR tread, at 100 degrees Centigrade; FIGURE 5 shows Goodyear-Healey pendulum rebound (G-H PR) in NR tread; FIGURE 6 shows dynamic properties elastic modulus (E 1 ) and viscous modulus (E") in NR tread; FIGURE 7 shows predicted rolling resistance (PRR) in NR tread; FIGURE 8 shows modified Veith trouser tear (MVTT) in kN/m in NR tread, both tear strength (TS) and knotty tear index (KTI); FIGURE 9 shows treadwear ratings relative to N 110 at 100 (TRR/N 1 10@ 100) in NR tread; FIGURE 10 shows 300% modulus (300% M) in NR/BR tread, in MPa; FIGURE 11 shows tensile strength (TS - in MPa) in NR/BR tread; FIGURE 12 shows shore hardness in NR/BR tread, expressed in shore hardness units (SHU); FIGURE 13 shows Zwick pendulum rebound (ZPR) in NR/BR tread; FIGURE 14 shows Goodrich heat buildup (GHB) in NR/BR tread; FIGURE 15 shows predicted rolling resistance (PRR) in NR/BR tread, FIGURE 16 shows dynamic properties elastic modulus (F) and viscous modulus (E") in NR/BR tread; FIGURE 17 shows predicted relative wet traction based on E" (RWT/E") in NR/BR tread; FIGURE 18 shows predicted relative dry traction based on D" (RDT/D") in 1/MPa in NR/BR tread; FIGURE 19 shows fatigue to failure, char, life (FTF) in kC in NR/BR tread; FIGURE 20 shows cut growth at 68% strain (CG/68%S) in NR/BR tread; FIGURE 21 shows trouser tear strength (TTS) in NR/BR tread; FIGURE 22 shows trouser tear knotty index (TTKI) in NR/BR tread; and FIGURE 23 shows a schematic comparison of the relative hysteresis properties, abrasion resistance properties and tear resistance properties of NI 15/N110, N121 and carbon black A, and specifically tan delta/treadwear rating ratio (TD/TRR) as a function of modified Veith trouser tear level (MVTTL). DETAILED DESCRIPTION OF THE INVENTION FIGS. 1-9 show reinforcement properties in NR tread, FIGS. 10-22 show reinforcement properties in NR/BR tread, and FIG. 23 shows relative hysteresis (tan ddta>-treadwear-tear properties of carbon black A (C.B. A), NI 10/Nl 15 and N121 in NR formulation. I. Production of carbon black A To produce carbon black A, CATII reactors (U.S. Patent No. 4,927,607) having an equivalent choke diameter of 8" were employed. The reactor was operated in accordance with U.S. Patent Number 4,927,607 using air rates and cutoff spray positions familiar to those skilled in the art as outlined in Table 1. TABLE 1 Furnace Operating Conditions for Production of C.B.A.* ♦ Carbon Black A (1) mscfh = 1000 standard cubic feet per hour (2) All positions are measured relative to the exit of the reactor choke. Downstream is positive. (3) Reactor volume between choke exit and quench position. A plant feedstock oil normally employed for the production of tread blacks was employed for the production of carbon black A. The furnace setup for the carbon black A was similar to those used for an NlOO series grade carbon black (see Furnace Operating Conditions). The concentration and the amount of potassium structure control chemical that was used for structure control was varied to satisfy the DBPA requirements for carbon black A. The concentration of potassium in the feedstock oil was 48 ppm. π. Colloidal and Electron Microscopic Properties of carbon black A Compared to Conventional Tread Blacks The colloidal and electron microscopic (EM) moφhological properties of carbon black A are given in Tables 2 and 3 relative to conventional tread blacks. The carbon black A can be classified as a moderately high structure NlOO series tread black based on structure (DBPA and 24M4) and the various surface area levels. The EM particle morphology analysis confirms this NlOO classification with respect to both mean diameter and surface area level. Table 2: Carbon Black Colloidal Properties TABLE 3 ELECTRON MICROSCOPE (EM) MORPHOLOGICAL PROPERTIES (ASTM D 3849) PARTICLE ANALYSIS VTA CAB PAINT CHIP DISPERSIONS C.B.A.* N115 N121 MEAN DIAMETER, nm 17.4 17.5 18.5 WT. MEAN DIAMETER, nm 26.8 28.1 28.8 HETEROGENEITY INDEX 1.54 1.56 1.56 EM SURFACE AREA, m 2 /g 141 136 124 AGGREGATE SIZE ANALYSIS IN DRY STATE MEAN DIAMETER, nm 71.3 63.0 84.2 WT. MEAN DIAMETER, nm 139 135 181 HETEROGENEITY INDEX 1.95 2.14 2.16 V/V INTRA-AGGREGATE ABSORPTION 1.85 2.12 2.50 SKELETONIZATION ANALYSIS IN DRY STATE AVERAGE AGGREGATE BRANCHES, 11.2 11.6 26.2 WEIGHT % DELTA B50* 11.1 12.9 31.0 WEIGHT PERCENT OF SHAPE TYPES 1-SPHEROIDAL 0.8 0.6 0.4 2-ELLIPSOrDAL 17.2 13.6 8.8 3-LINEAR 41.8 48.8 28.7 4-BRANCHED 40.2 37.0 62.1 *FULL WIDTH AT HALF MAXIMUM OF DISTRIBUTION OF AGGREGATE BRANCHES ON A WEIGHT PERCENTAGE BASIS *Carbon Black A Pertaining to mean and weight mean particle diameters and particle size distributional characteristics, carbon black A is similar to conventional NlOO series tread blacks. This size distribution measurement is represented in Table 3 by the heterogeneity index which is the weight mean diameter divided by the mean diameter (higher values indicate broader size distribution). Carbon black A, Ni l 5 and N121 in Table 3 differ in mean and weight mean aggregate diameters and size distribution. These various aggregate properties fall between Nil 5 and N121 for carbon black A. This average aggregate size would also be smaller than that observed for N234 or N220. Further, carbon black A has aggregates with lower occlusion capacity as shown by a lower V/V. This is a measure of the ability of the aggregates to shield elastomer between aggregate branches which affects reinforcement and failure properties. Skeletonization measurements indicate a slightly lower average number of aggregate branches (weight percent) than N115 and much lower than N121. Characterization of the shape types further indicate carbon black A to have higher percentage of low-occlusion capacity ellipsoidal aggregates It is also relatively low in percentage of branched aggregates. In terms of Delta B50, carbon black A is slightly lower than NI 15 and both are much lower than N121. m. Performance Advantages of carbon black A Relative to Conventional Grades of Carbon Black In Tread Compounds of TBS/RT To demonstrate the performance advantages of the carbon black A relative to conventional grades in the tread compounds of TBS/RT, two studies were conducted. The first study comprised a NR truck tire tread formulation (Table 4) with the carbon black A being compared to N 121 , N 115 and Nl lO using conventional mixing techniques. The tread black loading level was fixed at 50 phr. This tread formulation was not oil- extended. Table 4: Study 1 - Natural Rubber Tread Formulation The second study is based on a NR/BR (65/35) tread formulation (Table 5) where the polymer phase distribution of each tread black is controlled by the blending of separate black masterbatches of NR and BR as previously described. In this study the tread blacks (carbon black A, NI 10, NI 15, N121 and N234) were located with a higher loading in the NR phase, which produced the best balance of tear, fatigue, heat build-up and hysteresis properties in previous studies. The final tread black and oil loading levels were fixed at 60 and 25 phr, respectively. Table 5: Study 2 - NR/BR Tread Formulation Compound Preparations All of the NR and NR/BR compounds in Studies 1 and 2 were prepared as masterbatches in a BR Banbury (Farrell) mixer using procedures previously described in W.M. Hess, P.C. Vegvari and R.A. Swor, Rubber Chem. Technol., 58, 350 (1985), which is incorporated herein by reference. In Study 2, the separate NR and BR masterbatches were cooled overnight before blending in the Banbury. The curatives were added on a two-roll mill after an overnight cooling of the masterbatches for Study 1 and immediately following the blending of the two masterbatches for Study 2. Dispersion indexes greater than 95 were achieved for all the compounds. 10 For Study 2, the NR masterbatch contained 76.2 phr of the tread black and the BR masterbatch 30 phr of the same tread black. Preparation of masterbatches restricts the movement of the tread blacks during blending which reduces interphase migration of the tread blacks. The two masterbatches were blended to achieve the 65/35 blend of NR/BR, along with the proper levels of stearic acid and antidegradant, prior to the addition of the curatives. The distribution of the tread black in the final elastomer blend was 49.5 phr (82.5%) in the NR and 10.5 phr (17.5%) in the BR. Predictive Dynamic Property Testing The dynamic property measurements needed to predict the relative rolling resistance and traction performances of the tread compounds in Studies 1 and 2 were determined using an Instron Model 1332 non-resonant dynamic tester as previously described in W.M. Hess and W.W. Klamp, Rubber Chem. Technol., 56, 390 (1983), which is incorporated herein by reference (Table 6). Table 6: Dynamic Testing Conditions Predicting Tire Performance The predicted rolling resistance is based on the Tan Delta measurement in compression at 50°C, interpreted relative to N220 and reported in the Figures (7 and 15) relative to NI 10. The predicted relative wet and dry traction responses are based on the loss modulus (E") and loss compliance (D") measurements, respectively, in compression at 0°C and are reported in Figures 17 and 18 relative to NI 10. Treadwear Testing Treadwear testing was performed using only the NR tread compounds of Study 1. This testing was conducted at a Texas test track relative to an NI 10 control. Single tread compound recaps were placed on new radial passenger tire casings (P195-R75-14). The overall rate of wear was about 7600 km/mm (120 miles/mil), and the tires were evaluated for 14,500km (9,000 miles). Although not necessarily reflecting the actual ratings for truck tire usage, these treadwear measurements provide a relative performance ranking of these tread blacks. Tear Testing A modified trouser tear test was used to determine the tearing energy as defined by Rivlin and Thomas. R.S. Rivlin and A G. Thomas, J. Polymer Sci., 10, 91(1953). The specimen preparation and test procedures have been described by Hess and Chirico. W. M. Hess and V E. Chirico, Rubber Chem. Technol., 50,301 (1977). Eight specimens were tested for each sample at 100°C and 8.5mm/s. Two types of tear resistance were measured: tear strength and knotty tear index. The tear strength is defined as the median load value divided by the specimen thickness. The knotty tear index is the difference between the median tearing load and the median load where tear propagation along the prescribed path ceases. Fatigue/Cut Growth Testing These tests were conducted using constant-strain cycles on a Monsanto Fatigue to Failure Tester. Fatigue testing was performed with eight dumbbell specimens per tread compound (having no central cut) at a 0-90% strain. Fatigue data are reported in kilocycles to failure of 63.2% of the specimens (Characteristic Fatigue Life) as determined by means of the Weibull distribution function. Cut growth testing used eight fatigue dumbbell specimens per tread compound, with each specimen having a central cut of 0.5mm (0.2 inches). A cam providing a strain of 0-68% was used. The average kilocycles to failure of the eight specimens for each tread compound was used to judge performance. Study 1-NR Tread Figures 1-9 and Table 7 indicate the in-rubber and predicted tire performances of carbon black A relative to three conventional tread blacks in the NR tread. With respect to NllO and NI 15, carbon black A provides the expected levels of reinforcement (similar static and elastic moduli, tensile strength and hardness levels). Slightly higher rebound and lower predicted rolling resistance levels are also observed for carbon black A relative to NI 10 and NI 15, indicating an advantage in lower hysteresis properties for carbon black A. TABLE 7 IN-RUBBER PROPERTIES IN NR THREAD FORMULATION C.B.A.* N11S Nl lO N121 STRESS-STRAIN PROPERTIES 300% MODULUS, MPa 14.4 13.4 14.0 16.5 TENSILE, MPa 32.5 31.8 31.5 32.3 ELONGATION,% 591 607 596 560 Shore HARDNESS 59 60 59 60 MOONEY VISC, ML 1+4 @ 100°C 69.6 76 70 73 HYSTERESIS PROPERTIES Goodyear-HEALEY Rebound % 67.6 66.0 67.3 67.3 DYNAMIC PROPERTIES - ROLLING RESIS 1TANCE CONDITIONS F, MPa 8.27 9.13 8.20 8.53 E'\ MPa 1.08 1.32 1.12 1.04 PRED. ROL. RES., % 82.7 85.8 84.0 80.8 TAN DELTA 0.131 0.145 0.137 0.122 MODIFIED VEITH TROUSER TEAR TEAR STRENGTH, KN/M 82.6 81.3 49.3 KNOTTY TEAR INDEX, KN/M 27.5 26.0 23.6 ABRASION PROPERTIES TREADWEAR RATING, % Nl lO 107.2 100 107.4 ♦ Carbon Black A It has been shown in the art that the heat generation of radial truck tire treads is primarily related to their loss modulus (E") properties. (See, e.g., P. Kainradl and G. Kaufmann, Rubber Chem. Technol., 49, 823 (1976), which is incoφorated herein by reference). On this basis, carbon black A has predicted heat build-up properties similar to NI 10 and N121 and slightly lower than NI 15 (Figure 6) in this formulation. These reinforcement and hysteresis responses are consistent with the structure-fineness-porosity relationships of the carbon black A discussed earlier. The elongation levels for these tread blacks range from 560-607%, with the carbon black A performing equal to NI 10 at 591%. Rheometer cure rates (T90) at 165°C are equivalent for these four tread blacks. In terms of Mooney viscosity properties, the carbon black A develops the lowest level (69.6 units) observed in this formulation. This lower response implies that the tread compound processability characteristics will not be adversely affected by substitution of this new tread black for one of the conventional grades. Relative to N121, carbon black A shows lower moduli (static and elastic), comparable tensile and slightly higher hysteresis levels as predicted. The hardness level is also slightly lower. Two other relevant in-rubber performance improvements observed for carbon black A are tear and treadwear resistance properties. For the former property, a comparison to NI 15 and N121 in the NR tread formulation is made. Figure 23, prepared using the data from Table 7, shows a schematic comparison of the relative hysteresis properties, abrasion resistance properties and tear resistance properties of NI 15/N110, N121 and carbon black A. In Figure 8, the tear strength of carbon black A is equivalent to N115 and significantly greater than N121. With respect to knotty tear index, a similar, but less dramatic, performance pattern is observed. In reference to the treadwear resistance properties, a comparison of carbon black A is made to Nl lO and N121 in Figure 9. Carbon black A shows a performance equivalent to N121 and significantly higher than NI 10 in treadwear resistance. From the above discussion, it is apparent that the performance advantages for carbon black A over conventional tread blacks used for TBS/RT have been demonstrated. These performance improvements are better tear, treadwear, heat build-up and rolling resistances. Study 2-NR/BR Tread Figures 10-22 and Table 8 identify the in-rubber and predicted tire performances of carbon black A relative to NI 10, NI 15, N121 and N234 in the NR/BR tread. For the reinforcement and rebound properties given in Figures 10-13, the observed performance advantages of carbon black A are consistent with the trends reported for Study 1 in the NR formulation. As expected, carbon black A develops slightly lower modulus and equal hardness levels, and slightly higher tensile and lower rebound levels relative to N234. TABLE 8 IN-RUBBER PROPERTIES IN NR/BR THREAD FORMULATION C.B.A.* N115 Nl lO N121 N234 STRESS-STRAIN PROPERTIES 300% MODULUS, MPa 9.43 7.53 8.69 12.07 10.26 TENSILE, MPa 23.11 21.66 21.61 22.83 22.06 ELONGATION,% 593 616 634 519 556 Shore HARDNESS 55 53 54 56 55 HYSTERESIS PROPERTIES ZWICK Rebound % 51.5 50.2 52.5 51.8 53.0 HEAT BUILDUP, ©C 49.5 52.2 50.6 49.4 48.3 FAILURE TESTING CUT GROWTH, KG 97.2 61.8 86.0 78.8 55.2 FATIGUE, CHAR.LIFE, KC 706 636 673 607 692 DYNAMIC PROPERTIES - ROLLING RESISTANCE CONDITIONS E, MPa 7.88 6.89 6.97 8.10 7.17 E M , MPa 1.25 1.18 1.19 1.25 1.10 PRED. ROL. RES., % 88.3 91.4 91.4 8.77 8.77 TAN DELTA 0.159 0.171 0.171 0.154 0.153 DYNAMIC PROPERTIES - TRACTION CONDITIONS E", MPa 1.29 1.23 1.18 1.32 1.26 D", 1/MPa .0295 .0325 .0304 .0257 .0295 MODIFIED VEITH TROUSER TEAR PROPERTIES TEAR STRENGTH, KN/M 62.3 56.6 57.0 39.0 61.1 KNOTTY TEAR INDEX, KN/M 18.0 18.1 17.9 10.3 22.2 *Carbon Black A The elongation levels for these tread blacks range from 519-634%, with carbon black A(593%) being lower than NI 10 and NI 15 at 634 and 616%, respectively (Table 8). Rheometer cure rates are similar for these tread blacks in this formulation. The relative hysteresis performances in this tread formulation, as indicated by heat build-up and predicted rolling resistance levels are shown in Figures 14 and 15. Carbon black A exhibits heat build-up and predicted rolling resistance levels lower than Nl lO and NI 15 and equal to N121. Compared to N234, carbon black A develops a slightly higher heat build-up level but nearly equal predicted rolling resistance levels. Relative to NI 10, the elastic modulus level of carbon black A is higher in this formulation than observed in the NR tread compounds in Study 1 and approaches the performance of N121 (Figures 6 and 16). N234 performs closer to NI 10 and NI 15 in E" level. The viscous modulus property levels of these tread blacks are more similar in the NR/BR formulation than found in the NR formulation, with carbon black A having a slightly higher E" level than Nl lO and N 115. This E" level is comparable to N 121 and higher than N234. The predicted relative traction properties for carbon black A are given in Figures 17 and 18. The wet traction performance is comparable to N121 and slightly higher than NllO, NI 15 orN234. In terms of dry traction its predicted performance is slightly lower than NI 10 and N234, lower than NI 15 and higher than N121. In Study 2, fatigue and cut-growth measurements were conducted using the Monsanto Fatigue To Failure Tester (Figures 19 and 20). The fatigue life data do not correlate with the hysteresis performance of the tread blacks. Carbon black A exhibits a characteristic life comparable to Nl lO and N234, and better than N115 and N121. Figure 20 indicates that carbon black A performs better than all of the tread blacks in this study in terms of cut-growth resistance, followed by N 110. In terms of trouser tear properties, carbon black A develops a slightly higher tear strength level than Nl lO and NI 15, and a much higher level than N121 (Figure 21). A similar trend is observed for knotty tear index (Figure 22). The present invention is directed to a new, distinct form of carbon black for use in tire treads. The carbon black of the present invention when used in the manufacture of tire tread rubber imparts upon the tire tread rubber improved treadwear, lower rolling resistance, lower heat buildup and improved tear resistance. More specifically, the carbon black of the instant invention has a mean particle size of between 16.0 and 19.0 nm, and a structure level of between 100 to about 115 cc/lOOg as measured in n-Dibutyl Phthalate Absoφtion (DBPA) number. Furthermore, the carbon black of the present invention comprises a high level (approximately 17%) of low occlusion ellipsoid aggregates. These aggregates have an intra-aggregate absoφtion number (a measure of the ability of the aggregates to shield elastomer between aggregate branches, V/V) of about 1.85. This ability to shield elastomer between aggregate branches affects reinforcement and failure properties. This unique property of the carbon black of the present invention is unlike conventional NlOO and N200 series carbon blacks. Conventional carbon blacks do not have a high percentage of aggregates with low occlusion capacity. For example, the weight percent of ellipsoidal aggregates of NI 15 carbon blacks is 13.6 while the weight percent of ellipsoidal aggregates of N234 carbon blacks is only 8.8. Furthermore the carbon blacks of the present invention have the advantageous hysteresis and abrasion properties comparable to NI 21 carbon blacks. These hysteresis and abrasion properties include low heat buildup, a high Goodyear-Healey rebound, and a high treadwear rating. In addition, the carbon blacks of the present invention also possess the tear resistant properties characteristic of NI 15 carbon blacks. The tear strength in natural rubber tread for the invention carbon black is 82.6 kN/m comparable to the 81.3 kN/m for N115 carbon black but well above the 49.3 kN/m of N121 carbon black. Additionally, the delta B50 properties of the present invention are important, with the inventive carbon black having a delta B50 of less than 12. The delta B50 discussed herein refers to the full width at half maximum (FWHM) of the distribution of aggregate branches measured via skeletonization. This delta B50 is similar to delta D50, which is FWHM of an aggregate size ("D") distribution. The delta B50 is the aggregate branch distribution as obtained by skeletonization. The carbon blacks of the present invention, suitable for use in tire tread rubber, comprise a high percentage of low occlusion ellipsoidal aggregates which impart upon the rubber improved hysteresis and abrasion properties including at least increased tear resistance. V/V is an aggregate occlusion factor based on the ratio of the internal aggregate void volume, V, to the actual aggregate carbon volume V. This function is clear from, for example, A.I. Medalia, J. Colloid Interface Sci. 32, 115 (1970), see also, e.g., CR. Herd, G.C. McDonald and W.M. Hess, Rubber Chem. Technol. 65, 107 (1992). For example, this function is based on the equivalent sphere concept established by, and well known from, Medalia, V = Ves - Vagg, where Ves is the volume of the equivalent sphere. The equivalent sphere diameter is taken as the average Da (the equivalent circular diameter) and a diameter based on the average of eight Feret measurements. The volume of the aggregate is calculated as per ASTM 3489 and the ratio of the occluded volume to the aggregate volume, V/V, provided a dimensionless number that describes the capacity for an aggregate to occlude polymer. The present invention includes a carbon black particle of a specific size and surface area and further having the property of a high percentage of low occlusion aggregates. These low occlusion aggregates are ellipsoidal and comprise about 17 weight percent and impart upon the carbon black the property of increased treadwear, low heat buildup and increased tear-resistance compared to known carbon blacks. Because many varying and different embodiments may be made within the scope of the inventive concept herein taught, and because many modifications may be made in the embodiments herein detailed in accordance with the descriptive requirement of the law, it is to be understood that the details herein are to be inteφreted as illustrative and not in a limiting sense. What is claimed as invention is:

Claims: CLAIMS 1. A carbon black having a particle diameter of between about 16.0 and about 19.0 nm and a structure, measured in DBPA, of between about 100 to about 115 cc/lOOg. 2. The carbon black of claim 1 further characterized as having delta B50 of less than 12, 14% or greater ellipsoidal aggregate types, and 2.05 or less V/V. 3. The carbon black of claim 1 wherein the particle size is measured per ASTM D3849 procedure D and is between about 16.0 and about 19.0 nm. 4. The carbon black of claim 1 wherein the DBPA structure is measured by ASTM D2414 and is between about 100 and about 115 cc/1 OOg. 5. The carbon black rubber composition product of either of claims 1, 2, 3, or 4, characterized by improved abrasion resistance (treadwear rating) properties of about 4% to about 11%, lower tan delta hysteresis properties of about 5% to about 10%, and comparable tear-resistance properties relative to N115 or N110. 6. The carbon black rubber composition product of claim 5 wherein the improved abrasion resistance (treadwear rating) and the tan delta properties are equivalent to N 121 , and tear resistant properties are greater than N 121. 7. A carbon black, suitable for use in the fabrication of tire tread rubber, comprising: a. a carbon black particle size of between about 16.0 nm and about 19.0 nm; b. said carbon black having a dibutylphtalate absoφtion value of between about 100 cc/1 OOg to about 115 cc/lOOg; c. said carbon black further comprising a weight percentage of ellipsoidal aggregates greater than about 14; wherein said carbon black increases treadwear resistance, lowers heat buildup, and increases tear resistance of said tire tread rubber. 8. The carbon black of claim 7, wherein said mean particle size is between about 17.0 nm and about 18.0 nm. 9. The carbon black of claim 7, wherein said aggregates further comprise: a. a mean diameter of between about 63.0 nm and about 84.2 nm; b. a weight mean diameter of between about 135 nm and 181 nm; c. a heterogeneity index lower than about 2.14; d. an intra-aggregate absoφtion value lower than about 2.12; e. an average number of branches less than about 11.6; and f . a delta B 50 of less than 12. 10. The carbon black of claim 7, wherein the weight percent of ellipsoidal aggregates is about 17.2. 11. The carbon black of claim 10, wherein said aggregates further comprise: a. a mean diameter of about 71.3 nm; b. a weight mean diameter of about 139 nm; c. a heterogeneity index of about 1.95; and d. an intra-aggregate absoφtion of about 1.85. 12. A rubber composition suitable for use in the fabrication of tire tread rubber composition comprising: a. a carbon black, wherein said carbon black comprises: 1. a carbon black particle size of between about 16.0 and about 19.0 nm; 2. said carbon black particle having a dibutylphtalate absoφtion value of between about 100 to about 115 cc/1 OOg; 3. said carbon black particle further comprising aggregates having a weight percent of ellipsoidal aggregates greater than about 14; wherein said carbon black increases treadwear resistance, lowers heat buildup, and increases tear resistance of said tire tread rubber. 13. The rubber composition of claim 12, wherein said carbon black particles have a mean particle size of between about 17.0 nm and about 18.0 nm. 14. The rubber composition of claim 12, wherein said aggregates comprise: a. a mean diameter of between about 63.0 nm and about 84.2 nm; b. a weight mean diameter of between about 135 nm and 181 nm; c. a heterogeneity index lower than about 2.14. d. an intra-aggregate absoφtion value lower than about 2.12; e. an average number of branches less than about 11.5; and f. a delta B50 ofless than l2. 15. The rubber composition of claim 12, wherein the weight percent of ellipsoidal aggregates is about 17.2. 16. The rubber composition of claim 12, wherein said aggregates comprise: a. a mean diameter of about 71.3 nm; b. a weight mean diameter of about 139 nm; c. a heterogeneity index of about 1.95; and d. an intra-aggregate absoφtion of about 1.85. 17. The rubber composition of claim 16, wherein said aggregates further comprise a weight percent of about 17.2 18. The rubber composition of claim 12, wherein the rubber is further suitable for use in on/off highway conditions. 19. The rubber composition of claim 12, wherein said rubber is suitable for use in high performance passenger vehicle tires. 20. The rubber composition of daim 12, wherein the rubber comprises natural rubber. 21. The rubber composition of claim 12, wherein the rubber comprises a blend of natural rubber and synthetic polymers. 22. The rubber composition of claim 21, wherein the synthetic polymer is selected from the group consisting of styrene-butadiene rubber and butadiene rubber. 23. The rubber composition of claim 22, wherein the styrene butadiene is selected from the group consisting of clear, oil extended, solution, starred solution and functionalized styrene butadiene rubber. 24. The rubber composition of claim 21 , wherein the rubber further comprises an elastomer. 25. The rubber composition of claim 24, wherein the elastomer is a diene elastomer. 26. The rubber composition of claim 25, wherein the diene elastomer is selected from the group consisting of carboxyl rubbers, epoxy rubbers, t-ranspolypentenamer, halogenated butyl rubbers, 2-chlorobutadiene rubbers, teφolymers of ethylene, propylene, unconjugated dienes, copolymers of ethylene and propylene, copolymers of ethyl acetate and vinyl acetate, aromatic vinyl compounds, polyisoprene, conjugated dienes, chemical derivatives of natural rubbers and modified natural rubbers, and polybutadiene rubbers. 27. The rubber composition of claim 21, wherein the natural and synthetic rubbers are oil extended. 28. The rubber composition of claim 21 , wherein the rubbers are vulcanizable rubbers. 29. The rubber composition of claim 24, wherein the elastomer is mixed with at least one other second diene elastomer selected from the group consisting of carboxyl rubbers, epoxy rubbers, transpolypentenamer, halogenated butyl rubbers, 2- chlorobutadiene rubbers, teφolymers of ethylene, propylene, unconjugated dienes, copolymers of ethylene and propylene, copolymers of ethyl acetate and vinyl acetate, aromatic vinyl compounds, polyisoprene chemical derivatives of natural rubbers and modified natural rubbers, conjugated dienes and polybutadiene rubbers. 30. The rubber composition of claim 29, wherein said second diene elastomer comprises up to 70 parts by weight with respect to said first diene elastomer present. 31. The rubber composition of claim 30, wherein said second diene elastomer is polyisoprene further comprising >90 percent cis- 1 ,4 bonds. 32. The rubber composition of claim 26, wherein the conjugated dienes are selected from the group consisting of butadiene- 1,3, isoprene, and 2,3-dimethyl-l,3- butadiene. 33. The rubber composition of claim 26, wherein the aromatic vinyls are selected from the group consisting of styrene, ortho-methylstyrene, meta-methylstyrene, para-methylstyrene, or vinyl-toluene. 34. The rubber composition of claim 26, wherein the copolymer of conjugated diene and aromatic vinyl compound further comprise a total content of styrene of between 5 and 50 percent by weight, and a glass transition temperature of between 0 degrees and negative 80 degrees Celsius when measured by differential thermal analysis.

Inventors: BOMO FRANCIS G, SWOR RONALD A, WATSON JAMES M, BOMO, FRANCIS, G., SWOR, RONALD, A., WATSON, JAMES, M.
Applicants: BOMO FRANCIS G, COLUMBIAN CHEM, SWOR RONALD A, WATSON JAMES M, BOMO, FRANCIS, G., COLUMBIAN CHEMICALS COMPANY, SWOR, RONALD, A., WATSON, JAMES, M.
Application year: 1997
Main classification: C09C1
IPC codes: C08K3, C09C1