Acrylic resin brittle film

Abstract: An acrylic resin brittle film prepared from a resin composition which comprises (A) 100 parts by weight of an acrylic resin having an elongation at break of 10 to 180 %, (B) 10 to 70 parts by weight of at least one type of filler selected from the group consisting of (a) fused silica, (b) aluminum hydroxide, (c) barium sulfate, and (d) calcium carbonate, each having a specific average diameter of particles and specific diameters of constituting particles, and (C) 0 to 30 parts by weight of a plasticizer. The film has excellent transparency and weatherability, can be formed into a thin film, is brittle and easily torn, and shows a suitable degree of flexibility and hardness.

Description: FIELD OF THE INVENTION The present invention relates to a novel acrylic resin brittle film, and more particularly, to an acrylic resin brittle film which has excellent transparency and weatherability, can be formed into a thin film, is brittle and easily torn, and is advantageously used for labels and stickers, such as certificate stamps and sealing labels, and display stickers, such as marks for danger prevention and marks for commercial products, and also for prevention of forgery of passports. PRIOR ART OF THE INVENTION Brittle films have heretofore been used as base films for labels which must be prevented from transfer, such as labels for theft prevention and labels of certificate stamps, by taking advantage of the property of the films, i.e., brittle and easily torn. As the brittle film used for the above applications, various films, such as (1) a brittle film for marking which has a thickness of about 30 to 60 µm and comprises a resin composition containing 100 parts by weight of a vinyl chloride resin, about 5 to 20 parts by weight of an alkyl methacrylate resin, 5 to 30 parts by weight of a plasticizer, and pigments (Japanese Patent Publication No. Showa 54(1979)-34420), (2) a substantially transparent sheet having a layer composed of glass microspheres having a refractive index of 1.8 or more alone (Japanese Patent Application Laid-Open No. Showa 50(1975)-129195), and (3) a safety label using the above transparent sheet as the film which is brittle and easily torn (Japanese Patent Publication No. Showa 61(1986)-47426), have been proposed. However, because the above brittle film for marking (1) is colored due to pigments, this film has drawbacks in that information placed under the film cannot be observed and recognized through the film, and that the film has insufficient brittleness, poor flexibility, and inferior fitting when the film is attached to curved surfaces. Moreover, a plasticizer must be used in combination because the film comprises a vinyl chloride resin, and the use of a plasticizer causes the possibility that adhesion of an adhesive material to the film becomes insufficient due to bleeding out of the plasticizer when the film is attached to an article through the adhesive material. The above transparent sheet (2) and the above safety label (3) using the transparent sheet have drawbacks in that the sheet and the label are inevitably expensive because expensive glass microspheres are used and that complicated procedures are required for uniformly arranging the glass microspheres into a layer composed of the glass spheres alone. A transparent brittle film which has a total light transmittance of 30 % or more and is prepared from a composition containing 100 parts by weight of a vinyl chloride resin and 80 to 250 parts by weight of a material which is incompatible with the vinyl chloride resin and has an average particle size of 10 µm or less and a refractive index of 1.7 or less, is also proposed (Japanese Patent Application Laid-Open No. Showa 64(1989)-79237). However, because this transparent brittle film contains a vinyl chloride resin as the sole resin component, this film has a drawback in that formation of a film is difficult unless a large amount of a plasticizer, such as about 20 to 80 parts by weight of a plasticizer per 100 parts by weight of the vinyl chloride resin, is contained (35 parts by weight of a plasticizer was contained in an example), and this causes the problem that hardness and brittleness of the film are not always satisfactory. Moreover, similarly to the case of the above brittle film for marking (1), there is the possibility that adhesion of an adhesive material to the film becomes insufficient due to bleeding out of the plasticizer when the film is attached to an article through the adhesive material. Transparency and weatherability are not always sufficient because a vinyl chloride resin is used as the sole resin component. Resin compositions comprising a vinyl chloride resin have another drawback in that disposal and incineration of waste materials are difficult. SUMMARY OF THE INVENTION Accordingly, the present invention has an object of overcoming the drawbacks of conventional brittle films and providing a brittle film which has excellent transparency and weatherability, is brittle and easily torn, shows a suitable degree of flexibility and hardness, exhibits excellent adhesion to an adhesive material when the film is attached to a article through the adhesive material, is disposed or incinerated without problems, and can be produced inexpensively by a simple process. As the result of the extensive studies conducted by the present inventors to develop a brittle film having the above advantageous properties, it has been found that the above object can be achieved by a film prepared from a resin composition comprising specific amounts of an acrylic resin having a specific elongation at break, a filler having a specific average diameter and specific diameters of constituting particles, and a plasticizer which is used optionally. The present invention has been completed on the basis of this knowledge. Thus, the present invention provides: (1) An acrylic resin brittle film prepared from a resin composition which comprises (A) 100 parts by weight of an acrylic resin having an elongation at break of 10 to 180 %, (B) 10 to 70 parts by weight of at least one type of filler selected from the group consisting of (a) fused silica comprising aggregates of particles having an average diameter of the particles in the range of 5 to 20 µm and diameters of the particles in the range of 0.5 to 100 µm, (b) aluminum hydroxide comprising aggregates of particles having an average diameter of the particles in the range of 1 to 20 µm and diameters of the particles in the range of 0.2 to 50 µm, (c) barium sulfate comprising aggregates of particles having an average diameter of the particles in the range of 1 to 20 µm and diameters of the particles in the range of 0.2 to 50 µm, and (d) calcium carbonate comprising aggregates of particles having an average diameter of the particles in the range of 0.5 to 20 µm and diameters of the particles in the range of 0.1 to 50 µm, and (C) 0 to 30 parts by weight of a plasticizer; (2) An acrylic resin brittle film described in (1), which has a tear strength of 3.0 to 20.0 g; (3) An acrylic resin brittle film described in any of (1) and (2), which has a tensile strength at break of 1.0 to 3.0 kg/mm 2 and an elongation at break of 2.0 to 20.0 %; and (4) An acrylic resin brittle film described in any of (1) to (3), which has a thickness of 20 to 80 µm. DETAILED DESCRIPTION OF THE INVENTION It is necessary that the acrylic resin used as component (A) in the film of the present invention have an elongation at break in the range of 10 to 180 %. When the elongation at break is outside this range, it is difficult that a brittle film having a desired elongation at break is obtained. The elongation at break of the acrylic resin is preferably in the range of 20 to 150 %. For the measurement of the elongation at break, a sample is conditioned by being left standing at the temperature 22 to 25°C for 1 hour or more. The conditioned sample having a rectangular shape of a size of 20 × 100 mm is subjected to the test by using an Instron-type tensile tester under the condition of an extension speed of 5 mm/minute, a chart speed of 100 mm/minute, and a distance between chucks of 50 mm. The test is repeated 6 times, and the values of the elongation are averaged to obtain the elongation at break. The above sample is prepared by coating a polyethylene phthalate film used as the support with a solution which is obtained by mixing the acrylic resin alone with a solvent and completely dissolving the acrylic resin into the solvent, and drying the solution by heating to obtain a film of the acrylic resin having a prescribed thickness. Examples of the acrylic resin include homopolymers of alkyl esters of acrylic acid and alkyl esters of methacrylic acid in which the alkyl group preferably has about 1 to 15 carbon atoms, such as methyl acrylate, ethyl acrylate, n-propyl acrylate, isopropyl acrylate, n-butyl acrylate, isobutyl acrylate, sec-butyl acrylate, t-butyl acrylate, n-hexyl acrylate, cyclohexyl acrylate, 2-ethylhexyl acrylate, n-octyl acrylate, methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, sec-butyl methacrylate, t-butyl methacrylate, n-hexyl methacrylate, cyclohexyl methacrylate, 2-ethylhexyl methacrylate, and n-octyl methacrylate; copolymers obtained from combinations of two or more types of these alkyl esters of acrylic acid and alkyl esters of methacrylic acid; and copolymers obtained from combinations of one or more types of these alkyl ester of acrylic acid and alkyl esters of methacrylic acid and one or more monomers selected from other copolymerizable monomers. Examples of the other copolymerizable monomer include acrylic acid, methacrylic acid, styrene, vinyltoluene, acrylonitrile, methacrylonitrile, acrylamide, methacrylamide, vinyl acetate, conjugated diene compounds such as butadiene, isoprene, 1,3-pentadiene, cyclopentadiene, and dicyclopentadiene, and non-conjugated diene compounds such as 1,4-hexadiene and ethylidenenorbornene. The acrylic resin may be used singly or as a combination of two or more types. When a single type of the acrylic resin is used, it is necessary that the acrylic resin itself has an elongation at break in the range of 10 to 180 %. When a combination of two or more types of the acrylic resin is used, acrylic resins used as the components may have an elongation at break outside the above range as long as the acrylic resin comprising the acrylic resins used as the components has an elongation at break in the range of 10 to 180 %. The elongation at break of the acrylic resin can be adjusted by the chain length of the alkyl group in the alkyl ester of acrylic acid or methacrylic acid which is used as the monomer. In general, an alkyl ester of acrylic acid or methacrylic acid having an alkyl group of a longer chain length tends to give a polymer having a larger elongation at break in comparison with an alkyl ester of acrylic acid or methacrylic acid having an alkyl group of a shorter chain length. Preferable examples of the acrylic resin include (1) copolymers of methyl methacrylate, methyl acrylate, butyl acrylate, and styrene, and (2) mixtures of a copolymer of methyl methacrylate and methyl acrylate and a copolymer of methyl methacrylate, styrene, and butyl acrylate. The filler used as component (B) in the film of the present invention plays the roles of maintaining the transparency of the film and providing the film with brittleness. As the filler, fused silica, aluminum hydroxide, barium sulfate, calcium carbonate, or a mixture of these materials is used. In the present invention, it is necessary that fused silica comprise aggregates of particles having an average diameter of the particles in the range of 5 to 20 µm and diameters of the constituting particles in the range of 0.5 to 100 µm. When the average diameter of the particles is less than 5 µm, the dispersed solution containing the aggregates of particles shows poor homogeneity, and there is the possibility that transparency of the film becomes inferior. When the average diameter of the particles exceeds 20 µm, smoothness of the surface of the film is inferior. When the aggregates contain a large amount of particles having a diameter less than 0.5 µm, the dispersed solution containing the aggregates of particles shows poor homogeneity and tends to have high viscosity. When the aggregates contain a large amount of particles having a diameter exceeding 100 µm, the surface of the film becomes rough. From the standpoint of homogeneity and viscosity of the dispersed solution and transparency and smoothness of the film, it is preferable that fused silica has an average diameter of the particles in the above range and diameters of the particles constituting the aggregates in the range of 1 to 70 µm. It is particularly preferable that the fused silica has a broad distribution of the diameter of the particles. It is necessary that aluminum hydroxide and barium sulfate each comprises aggregates of particles having an average diameter of the particles in the range of 1 to 20 µm and diameters of the constituting particles in the range of 0.2 to 50 µm. When the average diameter of the particles is less than 1 µm, the dispersed solution containing the aggregates of particles shows poor homogeneity, and there is the possibility that transparency of the film becomes inferior. When the average diameter of the particles exceeds 20 µm, smoothness of the surface of the film is inferior. When the aggregates contain a large amount of particles having a diameter less than 0.2 µm, the dispersed solution containing the aggregates of particles shows poor homogeneity and tends to show high viscosity. When the aggregates contain a large amount of particles having a diameter exceeding 50 µm, the surface of the film becomes rough. From the standpoint of homogeneity and viscosity of the dispersed solution and transparency and smoothness of the film, it is preferable that aluminum hydroxide and barium sulfate each has an average diameter of the particles in the above range and diameters of the particles constituting the aggregates in the range of 0.7 to 30 µm. It is necessary that calcium carbonate comprises aggregates of particles having an average diameter of the particles in the range of 0.5 to 20 µm and diameters of the constituting particles in the range of 0.1 to 50 µm. When the average diameter of the particles is less than 0.5 µm, the dispersed solution containing the aggregates of particles shows poor homogeneity, and there is the possibility that transparency of the film becomes inferior. When the average diameter of the particles exceeds 20 µm, smoothness of the surface of the film is inferior. When the aggregates contain a large amount of particles having a diameter less than 0.1 µm, the dispersed solution containing the aggregates of particles shows poor homogeneity and tends to show high viscosity. When the aggregates contain a large amount of particles having a diameter exceeding 50 µm, the surface of the film becomes rough. From the standpoint of homogeneity and viscosity of the dispersed solution and transparency and smoothness of the film, it is preferable that calcium carbonate has an average diameter of the particles in the above range and diameters of the particles constituting the aggregates in the range of 0.2 to 30 µm. Any of calcium carbonate prepared by the precipitation process, heavy calcium carbonate, and light calcium carbonate can be used as the above calcium carbonate. The diameter of the particles of the filler used as component (B) in the present invention is measured in accordance with the method of sedimentation turbidity. In the present invention, the content of the filler is selected in the range of 10 to 70 parts by weight per 100 parts by weight of the acrylic resin of component (A). When the content is less than 10 parts by weight, brittleness of the film is insufficient. When the content exceeds 70 parts by weight, transparency of the film is inferior, and the film becomes excessively brittle to deteriorate the property for handling. From the standpoint of transparency, brittleness, and the property for handling of the film, the content of the filler is preferably in the range of 20 to 50 parts by weight per 100 parts by weight of the acrylic resin. In the film of the present invention, it is not always required that a plasticizer be used because the resin component is an acrylic resin. However, a plasticizer may be used as component (C) to provide the film with a suitable degree of flexibility. The plasticizer is not particularly limited and a suitable plasticizer may be selected from conventional plasticizers used for acrylic resins. For example, plasticizers having good compatibility with the acrylic resin (A) can be used. Examples of such plasticizers include alkyl benzyl phthalates, such as octyl benzyl phthalate and myristyl benzyl phthalate; dialkyl phthalates, such as dibutyl phthalate, dihexyl phthalate, and dioctyl phthalate; esters of phosphoric acid, such as tricresyl phosphate and trioctyl phosphate; esters of fatty acids, such as dibutyl sebacate and acetyl tributyl citrate; polyesters, such as polyesters derived from adipic acid, polyesters derived from sebacic acid, and polyesters derived from phthalic acid; derivatives of glycols, such as diethylene glycol dibenzoate, dipropylene glycol dibenzoate, and triethylene glycol di(2-ethylhexoate); derivatives of glycerol, such as glycerol triacetate and glycerol tributyrate; and epoxy derivatives, such as epoxidized soy bean oil. In the present invention, the plasticizer may be used singly or in a combination of two or more types. The content of the plasticizer is selected in the range of 0 to 30 parts by weight per 100 parts by weight of the acrylic resin of component (A). When the content exceeds 30 parts by weight, the film becomes excessively soft, and brittleness is decreased. Therefore, the object of the present invention is not achieved. From the standpoint of the film forming property of the dispersed solution and suitable flexibility and brittleness of the film, the content of the plasticizer is preferably in the range of 0 to 20 parts by weight per 100 parts by weight of the acrylic resin. The brittle film of the present invention is prepared by using a resin composition comprising components (A) and (B) and optional component (C). The resin composition may additionally contain various additives, such as antioxidants, ultraviolet absorbents, light stabilizers, antistatic agents, flame retarders, coloring agents such as dyestuffs and pigments, and coloring fillers, in accordance with desire within the range that the object of the present invention is not adversely affected. The thickness of the brittle film of the present invention is generally in the range of 20 to 80 µm. When the thickness is less than 20 µm, the film is excessively easily torn to deteriorate the property for handling. When the thickness exceeds 80 µm, transparency and flatness are inferior, and cost is increased. From the standpoint of having a good balance between the property for handling, transparency, flatness, and economy, the thickness is preferably in the range of 35 to 65 µm. The film of the present invention preferably has a tear strength in the range of 3.0 to 20.0 g. When the tear strength is less than 3.0 g, the film is excessively easily torn to deteriorate the property for handling. When the tear strength exceeds 20.0 g, brittleness is decreased. Therefore, such a tear strength is not preferable. From the standpoint of having a good balance between the property for handling and brittleness, the tear strength is preferably in the range of 5.0 to 17.0 g. For the measurement of the tear strength, a sample is conditioned by being left standing at the temperature 22 to 25°C for 1 hour or more. Ten sheets of the conditioned sample having a size of 50 × 100 mm were laid to form a laminate, and the Elmendorf tear test of the laminate was repeated 6 times in accordance with the method of Japanese Industrial Standard K 7128. From the results obtained by the test, the average value of the tear strengths was obtained, and 1/10 of the obtained value was used as the tear strength of the sample. The film of the present invention preferably has a tensile strength at break in the range of 1.0 to 3.0 kg/mm 2 and an elongation at break in the range of 2.0 to 20.0 %. When the tensile strength at break is less than 1.0 kg/mm 2 , the strength is excessively small to deteriorate the property for handling. When the tensile strength exceeds 3.0 kg/mm 2 , the film is excessively hard to cause inferior fitting when the film is attached to curved surfaces. From the standpoint of the property for handling and fitting to curved surfaces, the tensile strength at break is more preferably in the range of 1.5 to 2.5 kg/mm 2 . When the elongation at break is less than 2.0 %, flexibility is excessively small, and the property for handling is inferior. When the elongation at break exceeds 20.0 %, the brittleness tends to be decreased. From the standpoint of the property for handling and brittleness, the elongation at break is more preferably 3.0 to 15.0 %. For the measurement of the tensile strength at break and the elongation at break, a sample was conditioned by being left standing at the temperature 22 to 25°C for 1 hour or more. The conditioned sample having a rectangular shape of a size of 20 × 100 mm was subjected to the test by using an Instron-type tensile tester under the condition of an extension speed of 5 mm/minute, a chart speed of 100 mm/minute, and a distance between chucks of 50 mm. The test was repeated 6 times, and the values of the tensile strength and the elongation were averaged to obtain the tensile strength at break and the elongation at break, respectively. When the film of the present invention is prepared in the form of a transparent brittle film without adding color pigments or coloring fillers, the film generally has a light transmittance of 20 % or more, preferably 30 % or more, for light in the range of the wave length of 300 to 700 nm. The above light transmittance is obtained by the measurement using the computer color matching system (CCM). The process for producing the brittle film of the present invention is not particularly limited. For example, the film can be produced by any of the casting process, the extrusion process, the calendering process, or the solution coating process. Among these processes, the solution coating process is preferable from the standpoint of productivity and quality of the produced film. In the solution coating process, a homogeneous dispersed solution of a resin composition is prepared by thoroughly mixing a suitable solvent, components (A) and (B), optional component (C), and various additives used where necessary. A support having the releasing property, such as a processing paper and a polyethylene terephthalate film, is coated with the prepared dispersed solution to a prescribed thickness, and a brittle film is prepared by drying the dispersed solution on the support at 80 to 180°C. As the solvent used in the above process, a solvent which dissolves the resin of component (A) and has a boiling point of about 80 to 180°C is preferable. Examples of such a solvent include aromatic hydrocarbons, such as toluene, xylene, ethylbenzene, and trimethylbenzene; ketones, such as methyl ethyl ketone, diisobutyl ketone, and cyclohexanone; and dimethylformamide. The solvent may be used singly or as a combination of two or more types. The amount of the solvent used in the solution coating process is generally 100 to 400 parts by weight, preferably 150 to 350 parts by weight, per 100 parts by weight of the acrylic resin of component (A). To summarized the advantages of the present invention, the acrylic resin brittle film of the present invention has the following characteristics: (1) The film is brittle and easily torn and has a suitable degree of flexibility and hardness; (2) The film can be produced inexpensively by a simple process; (3) Because it is not necessary that a plasticizer is used as an essential component, adhesion of the film to an adherend does not have an adverse effect of bleeding out of a plasticizer when the film is attached to an article through the adhesive; (4) The film shows excellent transparency when no coloring pigments or coloring fillers are used as optional components; (5) The film has excellent weatherability and can be formed into a thin film; and (6) The film is easily disposed or incinerated because no vinyl chloride resin is used. Therefore, the film can be used for labels and stickers, such as certificate stamps and sealing labels, and display stickers, such as marks for danger prevention and marks for commercial products, and also for prevention of forgery of passports. The film is particularly advantageously used as a base film for labels for preventing transfer, such as labels for preventing theft and certificate stamps. EXAMPLES The present invention is described in more detail with reference to examples in the following. However, the examples are not to be construed to limit the scope of the invention. For evaluation of the quality of the obtained film, light transmittance (300 to 700 nm), tear strength, tensile strength at break, and elongation at break were obtained in accordance with the methods described above. The thickness was also measured. Example 1 A copolymer of methyl methacrylate and methyl acrylate (a product of MITSUBISHI RAYON Co., Ltd., ACRYPET MD, elongation at break: 2.6 %) in an amount of 60 parts by weight, 40 parts by weight of a copolymer of methyl methacrylate, styrene, and butyl acrylate (a product of MITSUBISHI RAYON Co., Ltd., ACRYPET RF065, elongation at break: 165.0 %), 30 parts by weight of fused silica (a product of TATSUMORI Co., Ltd., FUSELEX E-2, average particle diameter: 6.2 µm, range of particle diameter: 1 to 48 µm), 176 parts by weight of dimethylformamide, and 68 parts by weight of methyl ethyl ketone were mixed together. The components were sufficiently dissolved or dispersed by being stirred, and a dispersed solution containing 33.5 % by weight of solid substances was prepared. A polyethylene terephthalate film as the support was coated with the dispersed solution prepared above. The obtained product was heated to 180°C to vaporize the solvents and then dried to obtain a transparent brittle film having a thickness of 48 µm. The quality of the obtained film is shown in Table 1. Examples 2 to 15 and Comparative Examples 1 to 7 Dispersed solutions having the compositions shown in Table 1 were prepared in accordance with the same procedures as those conducted in Example 1, and transparent brittle films were prepared from these dispersed solutions. The quality of the obtained films is shown in Table 1. Example Comparative Example 1 2 3 Composition of dispersed solution (part by wt.) component (A) ACRYPET MD 1) 60 40 60 ACRYPET RF065 2) 40 60 40 DELPET SR8350 3) - - - DELPET SR8500 4) - - - elongation at break 5) (%) 24.6 57.2 24.6 filler of component (B) 6) type fused silica fused silica aluminum hydroxide amount 30 30 30 component (C) PN350 7) - - - solvent DMF 8) 182 188 182 MEK 9) 76 84 76 Concentration of solid substances (% by wt.) 33.5 32.3 33.5 Quality of the film thickness (µm) 46 44 51 tensile strength at break (kg/mm 2 ) 2.40 2.31 2.30 2.08 2.02 2.27 elongation at break (%) 2.2 2.7 4.7 4.3 4.4 4.2 tear strength (g) 8.4 8,2 8.2 8.2 9.2 9.4 light transmittance (%) 50∼63 49∼61 34∼39 Example 4 5 6 7 8 Comparative Example Composition of dispersed solution (part by wt.) component (A) ACRYPET MD 1) 60 60 - - 60 ACRYPET RF065 2) 40 40 - - 40 DELPET SR8350 3) - - 100 - - DELPET SR8500 4) - - - 100 - elongation at break 5) (%) 24.6 24.6 77.1 92.9 24.6 filler of component (B) 6) type calcium carbonate barium sulfate fused silica fused silica fused silica amount 30 30 30 30 30 component (C) PN350 7) - - - - 5 solvent DMF 8) 182 182 200 200 182 MEK 9) 76 76 100 100 76 Concentration of solid substances (% by wt.) 33.5 33.5 30.2 30.2 34.4 Quality of the film thickness (µm) 47 53 47 46 45 tensile strength at break (kg/mm 2 ) 2.58 2.62 2.42 2.38 2.69 2.65 2.66 2.66 2.56 2.46 elongation at break (%) 4.9 3.5 3.6 3.5 3.9 3.7 6.9 7.2 2.8 3.0 tear strength (g) 10.0 10.0 9.6 10.2 9.4 9.8 9.2 9.8 9.2 9.6 light transmittance (%) 35∼41 20∼28 50∼62 47∼60 50∼65 Example 9 10 11 12 13 Comparative Example Composition of dispersed solution (part by wt.) component (A) ACRYPET MD 1) 60 60 - - - ACRYPET RF065 2) 40 40 100 100 100 DELPET SR8350 3) - - - - - DELPET SR8500 4) - - - - - elongation at break 5) (%) 24.6 24.6 165.0 165.0 165.0 filler of component (B) 6) type fused silica fused silica fused silica fused silica fused silica amount 30 30 50 60 70 component (C) PN350 7) 10 15 - - - solvent DMF 8) 182 182 205 210 215 MEK 9) 76 76 100 100 100 Concentration of solid substances (% by wt.) 35.2 36.0 33.0 34.0 35.1 Quality of the film thickness (µm) 47 47 48 50 50 tensile strength at break (kg/mm 2 ) 2.20 2.19 1.98 1.96 1.34 1.32 1.37 1.34 1.40 1.36 elongation at break (%) 2.7 3.2 3.1 3.4 7.4 7.3 4.6 4.5 2.5 2.6 tear strength (g) 10.4 10.8 9.6 10.2 9.8 9.6 8.2 8.2 6.8 6.6 light transmittance (%) 50∼65 51∼67 45∼52 42∼49 41∼46 Example 14 15 Comparative Example 1 2 3 Composition of dispersed solution (part by wt.) component (A) ACRYPET MD 1) 60 40 100 - - ACRYPET RF065 2) 40 60 - - - DELPET SR8350 3) - - - 100 - DELPET SR8500 4) - - - - 100 elongation at break 5) (%) 24.6 57.2 2.6 77.1 92.9 filler of component (B) 6) type fused silica fused silica fused silica - - amount 20 20 30 - - component (C) PN350 7) - - - - - solvent DMF 8) 182 188 170 200 200 MEK 9) 76 84 60 100 100 Concentration of solid substances (% by wt.) 31.7 30.6 36.1 25.0 25.0 Quality of the film thickness (µm) 46 45 44 49 50 tensile strength at break (kg/mm 2 ) 2.76 2.72 2.28 2.20 2.40 2.45 3.25 3.12 2.90 2.88 elongation at break (%) 4.0 3.8 7.3 6.8 1.0 1.0 78.8 75.3 92.7 93.0 tear strength (g) 11.2 11.4 11.4 11.6 6.8 7.4 23.2 23.8 23.2 23.4 light transmittance (%) 58∼73 57∼72 52∼67 90∼92 90∼92 Example Comparative Example 4 5 6 7 Composition of dispersed solution (part by wt.) component (A) ACRYPET MD 100 60 - 80 ACRYPET RF065 - 40 100 20 DELPET SR8350 - - - - DELPET SR8500 - - - - elongation at break (%) 2.6 24.6 165.0 11.1 filler of component (B) type - - - - amount - - - - component (C) PN350 - - - - solvent DMF 170 182 200 176 MEK 60 76 100 68 Concentration of solid substances (% by wt.) 30.3 27.9 25.0 29.1 Quality of the film thickness (µm) 46 46 47 45 tensile strength at break (kg/mm 2 ) 4.26 4.16 3.26 3.22 1.70 1.68 3.62 3.64 elongation at break (%) 2.6 2.5 24.4 24.8 162 1.68 10.9 11.2 tear strength (g) 23.8 23.4 25.0 24.8 27.8 28.4 13.7 13.6 light transmittance (%) 90∼92 90∼92 90-92 90∼92 As shown in Table 1, all brittle films of the present invention were brittle and easily torn, had a suitable degree of flexibility, and showed excellent transparency. When the brittle films comprising various types of filler are compared, the brittle films comprising fused silica showed more excellent transparency than that of the films comprising aluminum hydroxide, calcium carbonate, or barium sulfate. In contrast, the film obtained in Comparative Example 1 showed inferior flexibility and had a small elongation at break because an acrylic resin having an elongation at break of 2.6 % was used. Therefore, this film is not suitable as a brittle film. The films obtained in Comparative Examples 2 to 7 which comprised no filler had inferior brittleness as shown by large tear strengths and large tensile strengths at break although the films had excellent transparency. These films had large elongations at break, also. Example 16 A dispersed solution containing two types of coating material shown in Table 2 was prepared in accordance with the same procedures as those conducted in Example 1, and a colored transparent brittle film was prepared from this dispersed solution. The quality of the obtained film is shown in Table 2. Examples 17 and 18 Dispersed solutions having the compositions shown in Table 2 were prepared in accordance with the same procedures as those conducted in Example 1, and opaque brittle films were prepared from these dispersed solutions. The quality of the obtained films is shown in Table 2. Example 16 17 18 Composition of dispersed solution (part by wt.) component (A) ACRYPET MD 40 60 60 ACRYPET RF065 60 40 40 elongation at break 57.2 24.6 24.6 (%) filler of component (B) type fused silica calcium carbonate calcium carbonate amount 25 10 10 component (C) PN350 - 24 17 other additives type ME1343 ME1345 ME1011P CR60 amount 0.80 1.00 6 60 solvent DMF 188 182 182 MEK 84 75 75 Concentration of solid substances (% by wt.) 31.8 35.3 42.1 Quality of the film thickness (µm) 30 49 49 tensile strength at break (kg/mm 2 ) 2.17 2.00 1.80 2.42 elongation at break (%) 4.6 4.3 6.7 3.1 tear strength (g) 6.4 6.6 13.0 8.0 light transmittance (%) 35∼65 - -

Claims: An acrylic resin brittle film prepared from a resin composition which comprises (A) 100 parts by weight of an acrylic resin having an elongation at break of 10 to 180 %, (B) 10 to 70 parts by weight of at least one type of filler selected from the group consisting of (a) fused silica comprising aggregates of particles having an average diameter of the particles in the range of 5 to 20 µm and diameters of the particles in the range of 0.5 to 100 µm, (b) aluminum hydroxide comprising aggregates of particles having an average diameter of the particles in the range of 1 to 20 µm and diameters of the particles in the range of 0.2 to 50 µm, (c) barium sulfate comprising aggregates of particles having an average diameter of the particles in the range of 1 to 20 µm and diameters of the particles in the range of 0.2 to 50 µm, and (d) calcium carbonate comprising aggregates of particles having an average diameter of the particles in the range of 0.5 to 20 µm and diameters of the particles in the range of 0.1 to 50 µm, and (C) 0 to 30 parts by weight of a plasticizer. An acrylic resin brittle film according to Claim 1, which has a tear strength of 3.0 to 20.0 g. An acrylic resin brittle film according to any of Claims 1 and 2, which has a tensile strength at break of 1.0 to 3.0 kg/mm 2 and an elongation at break of 2.0 to 20.0%. An acrylic resin brittle film according to any of Claims 1 to 3, which has a thickness of 20 to 80 µm.

Inventors: MATSUI ETSUO, MATSUI, ETSUO
Applicants: LINTEC CORP, ZEON KASEI KK, LINTEC CORPORATION, ZEON KASEI CO. LTD.
Application year: 1997
Main classification: C08J5
IPC codes: C08K3, G09F3, C08J5, C08L33