Sugar-free hard coatings and a method for obtaining them

Abstract: The present invention discloses an improved method for applying sugarfree hard coatings to cores consisting of edible, chewable or pharmaceutical components. The present invention discloses a process for coating cores wherein the sorbitol syrup is applied to a rotating mass of cores and then at least one other of the selected polyols is added in a crystalline form. The coated cores are dried and the process is repeated until a coating of the desired thickness and composition is obtained. The crunchiness of the coatings according to the process of this invention is at least comparable to that obtained with sucrose.

Description: Technical field The present invention discloses an improved method for applying sugarfree hard coatings to cores consisting of edible, chewable or pharmaceutical components. The method makes use of crystalline polyols. The present invention relates to sugarfree hard coatings obtained by the application of a combination of sorbitol syrup and at least one other crystalline polyol. The invention also relates to products coated with the said compositions. The coatings based on the compositions of the present invention show an increased crispiness and/or crunchiness. The method for applying the coating is also improved in that the crispy structure is obtained faster. Background of the invention Hard coatings of edible, chewable or pharmaceutical compositions were until recently made of sugars such as saccharose, dextrose, fructose or glucose syrups. Following intensive campaigns for the diminishment of the incidence of caries these coatings are now increasingly made using sugarfree compositions i.e. compositions containing sorbitol, xylitol, mannitol or hydrogenated starch hydrolysates. The process for applying the coatings to the cores generally consists of rotating the cores in a rotating installation at a desired speed and temperature, applying the coating in a liquid form, allowing a film to be formed and drying the material. Variations of this process have been developed and often the process is repeated until the coatings have the desired thickness. The polyols sorbitol and xylitol are often used in sugarfree coating applications. International patent application WO 81/01100 describes a hard coating process. In this process the conditions are chosen in such a way that sorbitol syrup can be used as coating fluid. EP 0 273 856 describes a process for producing a sorbitol coated comestible. The process comprises applying to a substantially anhydrous edible core at least two coating solutions comprising sorbitol to coat the edible core. The first coating solution comprises (a) about 77 to about 81 wt% sorbitol solution containing from about 65 to about 75 wt % sorbitol, and (b) about 9.5. to about 12.5 wt% crystalline sorbitol powder together with a film-forming agent and a crystallisation retardant. The second coating solution comprises (a) from about 82 to about 92 wt% sorbitol solution comprising about 65 to about 75 wt % sorbitol, and (b) about 1.0 to about 1.5 wt% crystalline sorbitol powder together with a film-forming agent and a crystallisation retardant. The solutions have a different sorbitol content and the product is dried between the application of the two layers. The product is reported to be smooth, hard and crunchy. The coating with sorbitol as described for example in WO 81/01100 and EP 0 273 856 is widely used due to the ease of handling of this polyol. Moreover sorbitol is relatively inexpensive. The major drawback of the use of this polyol is that the resulting coating layers do not show the same crunchiness and crispiness as the conventional sucrose-based coatings. Alternatives for the use of sorbitol are therefore awaited. Coating with xylitol is described for example in US patents 4,105,801; 4,127,677; and 4,146,653 and EP 0625311. Xylitol is used for its cooling effect and its well-known cariostatic properties. US patent US 4,238,510 describes sugarless coated comestibles wherein the coating consists essentially of sorbitol alone or in admixture with mannitol, and/or hydrogenated starch hydrolysate. Such coatings are not comparable in hardness to the coatings obtained with normally employed sugars. Other patents describe hard coating using other polyols such as Isomalt, maltitol and erythritol (WO 95/07625 and JP 6292511). Also the idea of a sequential coating with first several layers of one polyol and then several layers of another polyol has been proposed (US 5376389). The main advantage of such a process would be the lower price of the raw material and the reduced hygroscopicity (WO 95/07622 and WO95/07621). Summary of the invention The present invention discloses that a combination of sorbitol syrup and a selected polyol gives rise to a crispy and crunchy coating when applied to edible, chewable or pharmaceutical cores. The present invention discloses a sugarfree hard coated comestible obtainable by treating a core portion with a sorbitol syrup and at least one other polyol in crystalline form. The polyol is selected from the group consisting of Isomalt r , xylitol, and erythritol. The present invention discloses a process for coating cores wherein the sorbitol syrup is applied to a rotating mass of cores and then at least one other of the selected polyols is added in a crystalline or powdered form. The coated cores are dried and the process is repeated until a coating of the desired thickness and composition is obtained. The sugarfree coatings of the present invention are applied to edible, chewable and pharmaceutical cores. Preferably the sugarfree coatings of the present invention are used for coating chewing gum, confectionery products (such as candies), chocolate and nuts. The present invention discloses products which have been coated with the composition containing sorbitol syrup and at least one other crystalline polyol. Detailed description of the invention The present invention discloses a process for coating cores wherein the sorbitol syrup is applied to a rotating mass of cores and then at least one other of the selected polyols is added in a crystalline form. The coated cores are dried and the process is repeated until a coating of the desired thickness and composition is obtained. The cores are composed of edible, chewable or pharmaceutical material. The process of the present invention is performed as follows. As coating solution a sorbitol-syrup with dry substance of about 60 wt% to about 95 wt % and a sorbitol-content more than about 60 wt % is used. The syrup is applied to the rotating cores at a temperature of 20 - 60°C. The cores are in a rotating pan (speed 10 - 30 rpm) small portions of the syrup are added and the syrup forms a thin film on the surface of the cores. The solution may also contain gelatine, gum-arabic or celluloses and other known ingredients as binding-agent. After the cores are moistened by the syrup a small portion (max. about 4% of the weight of cores) of crystalline xylitol, Isomalt, or erythritol (granulometry < 200µm) is brought on the surface of the cores. The coated cores are dried. To reduce drying-time air with a temperature of 15 - 45 °C and a moisture content of at most 50% relative humidity is applied. When the cores are dry the process is repeated until the desired thickness and composition of the coating is reached. By repeating the described process, coatings of from 1 to about 100 layers are easily obtained, preferably the number of layers is between 1 and 40. The optimal amount of layers will depend on the desired applications and can be determined experimentally. Different polyols can also be applied as mixture of crystals or in separate layers. Optionally the last or finishing layer or layers may contain components to give the product a glossy appearance. Obviously slight adaptations of the process may be necessary with regards to temperature, drying time, concentration of sorbitol and amount of crystalline polyol without departing from the present invention. Such adaptations depend on the quality and type and composition of the ingredients employed. Moreover the type of equipment such a drying pan, rotating drum may also influence the exact conditions. Colours like titanium dioxide or others are applied by addition to the sorbitol syrup. Liquid flavours are used by addition to the syrup, powdered flavours are used in a blend with the crystalline polyol. In addition to the polyols hydrocolloids are generally added to an amount of about 3% such hydrocolloids include gum arabic, gelatine and cellulose. The final coating contains the crystalline polyols in an amount of less than 20 wt%, for xylitol a preferred amount would be 15 % as at this concentration the cariostatic effect is present, for Isomalt and erythritol the amounts can be even lower than 10%. In general polyols with a lower solubility have a greater effect. When the method of the present invention is applied to hard coating of chewing gum any conventional chewing gum centre (or core) may be used. Preferably the centre is sugarfree and contains sorbitol, mannitol, xylitol, lactitol, maltitol and/or hydrogenated starch hydrolysate. The gum centre constitutes from about 35 to about 65 % of the chewing gum product. The present invention is illustrated by way of the following examples. Example A) Coating The following conditions were used to prepare the chewing gums. The coating solution was a sorbitol syrup with dry substance of 70% and a sorbitol-content of 97%. The syrup was applied to the cores at room temperature (20 - 25°C). The cores were in a rotating pan (speed 20 rpm, diameter 0.5m, velocity at outer circumference 1m/s). The pan contained 2 kg of centres and the uncoated chiclets' weight was 1·21g each. For the first ten layers 10 ml of sorbitol syrup was added. From layer twenty the amount was increased to 25 ml and from layer 37 it was further increased to 35 ml. Every fifth layer 1 min. after the addition of the sorbitol solution 0.57% (based on the weight of the centres) of C Eridex (fine fraction, < 100 micrometers) was added. The coating process was stopped after 40 layers. This resulted in a coating of 4.2% (by weight). The solution may also contain gelatine, gum-arabic or celluloses as binding-agent. Crystalline maltitol, xylitol and Isomalt were brought on the surface of the cores under similar conditions. To reduce drying-time air with a temperature of 15 - 45 °C and a moisture content of < 50% relative humidity can be applied. When the cores are dry the process is repeated until the desired thickness of the coating is reached. Colours like titanium dioxide (in the present case 0.5%) or others are applied by addition to the syrup. Liquid flavours are used by addition to the syrup, powdered flavours are used in a blend with the crystalline polyol. This process was used to prepare coatings based on sorbitol syrup with crystalline maltitol, Isomalt and erythritol. Pure sorbitol syrup and sucrose were used as blanks. B) Determination of Crunchiness The crunchiness of a coating layers is normally only determined by sensorial tests. To apply a more quantitative method the following system was evaluated. The hardness of the coating-layer was measured with a Stable Micro Systems Texture analyser XT.RA, dimension V3.7A . The measurement-system was equipped with a needle with a diameter of 1 mm and the force required to penetrate this needle 1 mm into the coating layer was measured. It was found, that samples, which showed a desired crunchiness had the maximum penetration force at a shorter penetration-distance than 1 mm. To quantify this finding maximum force was divided by the penetration-depth at maximum force in mm. This figure is defined as the 'crunchiness-factor' the higher the figure, the more crunchy the coating layer. This was verified by sensorial testing. The dimension of this 'crunchiness-factor' is g/mm. Immediately after coating, the following 'crunchiness-factors' were found. Sucrose 1675 g/mm Sorbitol-syrup pure 1030 g/mm Sorbitol-syrup + Maltitol powder 854 g/mm Sorbitol-syrup + Isomalt powder 2583 g/mm Sorbitol-syrup + Erythritol powder 2018 g/mm The advantage of this coating is the increased crunchiness and crispiness compared to a pure sorbitol coating. The best results are obtained by the use of a crystalline polyol with lower solubility compared to sorbitol like Isomalt or Erythritol.

Claims: A sugarfree hard coated comestible obtainable by treating a core portion with a sorbitol syrup and at least one other polyol in crystalline form and wherein the polyol is selected form the group consisting of Isomalt, xylitol, and erythritol. A hard coated comestible according to claim 1 wherein the polyol is present in an amount of at most 20 % of the total of sorbitol and polyol dry weight. A hard coated comestible according to claim 1 wherein the coating consists of from 1 to 100 layers. A process for coating edible, chewable or pharmaceutical cores with a number of layers wherein a) sorbitol syrup is applied to a rotating mass of cores, b) at least one other polyol selected from the group consisting of Isomalt, xylitol and erythritol in crystalline form is added, c) the product is dried, d) steps a) to c) are repeated until the coating has reached the desired thickness and composition. A process according to claim 4 wherein the application of the layers is repeated between 1 and 100 times. A process according to claim 5 wherein the polyol is selected from the group consisting of Isomalt, xylitol and erythritol and the selected polyol is not identical in every layer. An edible, chewable or pharmaceutical product coated with the process of claim 4. A chewing gum, confectionery product such as candies, chocolate or nut coated with the process of claim 4.

Inventors: ROSENPLENTER KURT CHRISTIAN, ROSENPLENTER, KURT CHRISTIAN
Applicants: CERESTAR HOLDING BV
Application year: 1997
Main classification: A23G3
IPC codes: A23G4, A23G1, A23L1, A61K47, A61K9, A23G3, A23P1