ORGANIC LIGHT EMITTING DIODE COLOUR DISPLAY

Abstract: A multi-colour electroluminescent display has a plurality of discrete, laterally spaced areas of light emitting material formed over respective groups of first and second electrode regions. The light emissive material over each group is capable of emitting radiation of a different colour. The multi-coloured device is formed by a sequence of steps where each emitting layer is deposited as a precursor which is susceptible to patterning and which is then converted into its polymer which is not susceptible to subsequent patterning steps. This allows a second colour to be deposited on top of a first colour, the second colour being patterned while avoiding damage to the first colour below it.

Description: „„,„ WO 97/38445 Title of the Invention ORGANIC LIGHT EMITTING DIODE COLOUR DISPLAY Field of the Invention The invention relates to multi-colour EL displays and a method of manufacture thereof . Background of the Invention The most popular flat panel display technology currently in use is based on liquid crystal devices, which are effectively light shutters used in combination with illumination sources. In graphic displays there are many different pixels that must be independently driven. Typically this is achieved through matrix addressing, where each pixel is addressed by application of a suitable switching voltage applied between row and column conducting tracks on either side of the liquid crystal. Each row is selected by applying a voltage to the row track, and individual pixels within the row selected by application of column data voltages to the column tracks. The rows are addressed sequentially, each for a line address time such that the whole frame is addressed within the frame time. However, because the speed of switching of the liquid crystals is slow relative to the line addressing time, when video frame rates are required (<20ms) , special circuitry has to be typically added to each pixel. This arrangement is called active matrix addressing and often involves the use of thin-film transistors at each pixel. Because of the increased complexity of the active matrix displays they are much more expensive to make than passive matrix devices . Organic electroluminescent devices are made from materials that emit light when a suitable voltage is applied across electrodes deposited on either side of the organic layer(s) . One class of such materials is semiconductive conjugated polymers which have been described in our earlier Patent US 5,247,190, the contents of which are herein incorporated by reference. The metal electrodes can be patterned to form a matrix of rows and columns so that matrix addressing can take place. There are several potential advantages over liquid crystal graphic displays. Because the polymers are directly emissive, no backlight is required. Also polymers of different colours can be fabricated so that a suitably patterned matrix of polymers can be used for a colour display (multi-colour or full-colour RGB) without the use of colour filters as required by a liquid crystal display. Our earlier applications (EP-A-94924916.3 and GB 9507862.2) show ways to achieve patterned emission of different colours. In these different embodiments the polymer materials are not themselves patterned and the emission patterns are defined by the intersection of the injecting electrodes. Multiple colour emission is possible through stacking of the emitting layers on top of each other in a vertical fashion. This approach results in a device fabrication process with many steps, but with low complexity for each step. Another Patent US 5,424,560 recently disclosed an approach for producing Organic LEDs where the emission areas are themselves patterned, avoiding the requirement for multiple electrode depositions. In .this approach an emitting area of one colour is first patterned, and subsequently a material of different colour emission is deposited and patterned to form a separate emission area. This second layer covers the first emitting area and in that area of overlap acts as a transport layer. Thus no patterning above the first layer is required. This approach requires that the overlayers act as hole transport layers as well as emitters, so there is some compromise that must be made on their properties. The simplest structure would be made up of laterally-defined and separated LEP areas but it is not obvious how to pattern such a structure . Direct printing techniques (e.g. gravure) would be possible but the alignment tolerances required between different colours is probably beyond the resolution achievable in printing processes. Summary of the Invention The problem can be solved if, as described herein, layers could be patterned to form emitting areas, but without disturbing previously patterned emitting areas of a different colour. The present invention provides a method of fabricating a multi¬ colour electroluminescent display, comprising the steps of: forming on a substrate a plurality of first electrode regions; forming over a first selected group of said first electrode regions a first layer of a precursor for a first material for emitting radiation of a first colour, said precursor for said first material being susceptible to patterning; at least partially converting said precursor for said first material into said first material which is substantially resistant to subsequent patterning steps; depositing over said first layer and over at least a second selected group of said first electrode regions a second layer of a precursor for a second material for emitting radiation of a second colour, said precursor for said second material being susceptible to patterning; patterning said second layer to remove said second layer from above said first layer and leaving said second layer over said second selected group of said first electrode regions; at least partially converting said precursor for said second material into said second material; converting any unconverted precursors into said respective materials; forming a plurality of second electrode regions over said layers in such a manner that said materials for emitting radiation can be selectively excited to emit radiation by applying an electric field between said first and second electrode regions. Preferably, said step of forming a plurality of first electrode regions comprises the steps of: depositing a layer of a conductive material on a substrate; and patterning said layer of said conductive material to form a plurality of first electrode regions . Preferably, said step of forming a first layer of a precursor for a first material comprises the steps of: depositing a layer of a precursor for a first material for emitting radiation of a first colour over said first electrode regions; and patterning said layer of said precursor for said first material to form a layer of said precursor for said first material over a first selected group of said first electrode regions. Preferably, said step of forming a plurality of second electrode regions comprises the steps of: depositing a layer of a conductive material over said layers; and patterning said layer of conductive material to form a plurality of second electrode regions . In one embodiment, said steps of at least partially converting said precursor for said second material into said second material and converting any unconverted precursors for said first and second materials into said first and second materials are performed in a single step. In another embodiment, said second material is substantially resistant to subsequent patterning steps, and said method further comprises, after said step of at least partially converting said precursor for said second material, the steps of: depositing over said first and second layers and over a third selected group of said first electrode regions a third layer of a precursor for a third material for emitting radiation of a third colour, said precursor for said third material being susceptible to patterning; patterning said third layer to remove said third layer from over said first and second layers and leaving said third layer over said third selected group of said first electrode regions; and at least partially converting said precursor for said third material into said third material . Preferably, said steps of at least partially converting said precursor for said third material into said third material and converting any unconverted precursors for said first, second and ~ „„,„.,, « WO 97/38445 third materials into said first, second and third materials are performed in a single step. Preferably, said method further comprises the step of depositing an electron transport layer prior to said step of forming said plurality of second electrode regions. Preferably, said electron transport layer is a conjugated polymer layer. Preferably, the thickness of said electron transport layer is from 5 to 200 nm. Preferably, said method further comprises the step of depositing a hole blocking layer prior to said step of forming said plurality of second electrode regions. Preferably, said hole blocking layer is a dielectric layer. Preferably, the thickness of said hole blocking layer is from 1 to 10 nm. Preferably, said first electrode regions are composed of a light- transmissive conductive material. More preferably, said first electrode regions are composed of indium-tin oxide, tin oxide or zinc oxide. Preferably, said second electrode regions are composed of Al or an alloy thereof. Preferably, the thickness of said first electrode regions is from 10 to 500 nm. Preferably, the thickness of said second electrode regions is from 10 to 1000 nm. Preferably, each of said first and second electrode regions comprises a line. More preferably, the width of each of said lines of said first electrode regions is from 10 to 5000 μm. More preferably, the width of each of said lines of said second electrode regions is from 10 to 5000 μm. More preferably, the spacing between each of said lines of said first electrode regions is from 10 to 5000 μm. More preferably, the spacing between each of said lines of said second electrode regions is from 10 to 5000 μ . More preferably, said first electrode regions are one of columns or rows and said second electrode regions are the other of columns or rows. Preferably, said layers of precursor for each of said materials are formed to a thickness of from 10 to 500 nm. Preferably, said materials for emitting radiation are polymer materials . More preferably, said polymer materials are selected from poly(p- phenylene vinylene) for a green colour, poly(p-phenylene) or poly(p-phenylene vinylene) co-polymer with non-conjugated sections for a blue colour, and poly(1, 4-napthylene vinylene) or a dialkoxy substituted poly(p-phenylene vinylene) for a red colour; - the poly(p-phenylene) precursors comprising: (i) poly(5, 6 dialkyloxy-1, 3 cyclohexadiene) ; (ii) a polymer comprising recurring units of the general formula: X denotes -SR 3 , -SO-R 3 , -S0 2 -R\ -COOR 3 , -NO.,, -CN, -CF 3 or -R 3 , R^ ^ 3 are the same or different and denote -H, -R' 1 or -X, R 4 denotes a straight chain or branched alkyl group with 1 to 20 carbon atoms, phenyl or benzyl, either of which can be substituted once or twice with -R', -OR 1 , -N0 2 , -CN, -Br, -Cl or -F, and Ar denotes an aromatic system, comprising from 4 to 20 carbon atoms which can optionally be substituted; (iii) a thiophene, furan, pyrrole or pyridine analogue of (i) or (ii) ; and (iv) one of (i), (ii) or (iii) with a monosubstitution or 2,5 disubstitution of alkoxy, alkyl, aryloxy, aryl, nitrile, nitro or -CF 3 - the poly(p-phenylene vinylene) precursor comprising: (i) poly(p-xylylene-α-dialkyl sulphonium halide) ; (ii) poly(p-xylylene-α-cycloalkyl sulphonium halide) ; (iii)poly(p-xylylene-α-halide) ; (iv) poly(p-xylylene-α-alkoxide) where the alkyl ether can contain a cross-linkable group; (v) poly(p-xylylene-α-aryloxide) where the aromatic ester can be substituted by a cross-linkable group; (vi) poly(p-xylylene-α-carboxylate) where the ester can be aliphatic or aromatic and contain a cross-linkable group; (vii) a polymer comprising recurring units of the general formula: X denotes -SR 3 , -SO-R 3 , -S0 2 -R 3 , -COOR\-NO ? , -CN, -CF 3 or -R 3 , R R 2 ,R 3 are the same or different and denote -H, -R 4 or -X, R 4 denotes a straight chain or branched alkyl group with 1 to 20 carbon atoms, phenyl or benzyl, either of which can be substituted once or twice with -R 3 , -OR 1 , -N0 2 , -CN, -Br, -Cl or -F, and Ar denotes an aromatic system, comprising from 4 to 20 carbon atoms which can optionally be substituted; (viii) a thiophene, furan, pyrrole or pyridine analogue of any of (i) to (vii) ; and (ix) one of (i) to (viii) with a onosubstitution or 2,5 disubstitution of alkoxy, alkyl, aryloxy, aryl, nitrile, nitro or -CF 3 - the poly(1, 4-napthylene vinylene) precursor comprising: (i) poly(l,4 benzoxylylene-α-dialkyl sulphonium halide) ; (ii) poly(l,4 benzoxylylene-α-cycloalkyl sulphonium halide) ; (iii) poly(1, 4 benzoxylylene-α-halide) ; (iv) poly(1,4 benzoxylylene-α-alkoxide) where the alkyl ether can contain a cross-linkable group; (v) poly(1,4 benzoxylylene-α-aryloxide) where the aromatic ester can be substituted by a cross-linkable group; (vi) poly(1,4 benzoxylylene-α-carboxylate) where the ester can be aliphatic or aromatic and contain a cross-linkable group; and (vii) a polymer comprising recurring units of the general formula: X denotes -SR 3 , -SO-R 3 , -S0 2 -R\ -COOR 3 ,-N0 2 , -CN, -CF 3 or -R 3 , R^RYR 3 are the same or different and denote -H, -R 4 or -X, R 4 denotes a straight chain or branched alkyl group with 1 to 20 carbon atoms, phenyl or benzyl, either of which can be substituted once or twice with -R 1 , -OR 1 , -N0 2 , -CN, -Br, -Cl or -F, and Ar denotes an aromatic system, comprising from 4 to 20 carbon atoms which can optionally be substituted. Preferably, said steps of patterning said precursor materials comprise steps of etching. Λmntt . .. WO 97/38445 - 9 - Preferably, said conversion steps comprise at least one of heat treatment, chemical treatment, electron beam exposure or radiation exposure. More preferably, said conversion steps comprise a heat treatment at a temperature of from 50 to 300 * C in an inert atmosphere. Still more preferably, said heat treatment is performed at about 150'C. Preferably, said layers of said materials for emitting radiation are formed to cover said first electrode regions so as to electrically insulate said first electrode regions from said second electrode regions. Preferably, said layers of said materials for emitting radiation each comprise a plurality of areas, each area overlying a respective one of said first electrode regions. More preferably, said areas of material each comprise a plurality of discrete sub-areas and said second electrode regions are formed to overlie selected ones of said sub-areas. The present invention also provides a multi-colour electroluminescent display, comprising: a substrate; a plurality of first electrode regions formed over said substrate; a plurality of discrete, laterally-spaced areas of light- emissive material formed over said first electrode regions, wherein selected groups of said plurality of areas are each formed of a material for emitting radiation of a different colour and each individual first electrode region has only a material for emitting radiation of one colour formed thereover; and a plurality of second electrode regions formed over said plurality of light-emissive areas; wherein said light-emissive areas can be selectively excited to emit radiation by applying an electric field between said first and second electrode regions. Preferably, said device comprises a plurality of areas of a first material for emitting radiation of a first colour formed over a first selected group of said first electrode regions, a plurality of areas of a second material for emitting radiation of a second colour formed over a second selected group of said first electrode regions, and a plurality of areas of a third material for emitting radiation of a third colour formed over a third selected group of said first electrode regions. More preferably, said plurality of areas of said first, second and third materials are arranged such that each area of said plurality of areas of said second material is adjacent a respective one of said plurality of areas of said first material and a respective one of said plurality of areas of said third material . Preferably, said device further comprises an electron transport layer between said plurality of light-emissive areas and said plurality of said second electrode regions. Preferably, said electron transport layer is a conjugated polymer layer. Preferably, the thickness of said electron transport layer is from 5 to 200 nm. Preferably, said device further comprises a hole blocking layer between said plurality of light-emissive areas and said plurality of said second electrode regions . Preferably, said hole blocking layer is a dielectric layer. Preferably, the thickness of said hole blocking layer is from 1 to 10 nm. „ Λ Λ . WO 97/38445 - 11 - Preferably, said first electrode regions are composed of a light- trans issive conductive material. More preferably, said first electrode regions are composed of indium-tin oxide, tin oxide or zinc oxide. Preferably, said second electrode regions are composed of Al or an alloy thereof. Preferably, the thickness of said first electrode regions is from 10 to 500 nm. Preferably, the thickness of said second electrode regions is from 10 to 1000 nm. Preferably, each of said first and second electrode regions comprises a line. More preferably, the width of each of said lines of said first electrode regions is from 10 to 5000 μm. More preferably, the width of each of said lines of said second electrode regions is from 10 to 5000 μm. More preferably, the spacing between each of said lines of said first electrode regions is from 10 to 5000 μm. More preferably, the spacing between each of said lines of said second electrode regions is from 10 to 5000 μ . More preferably, said first electrode regions are one of columns or rows and said second electrode regions are the other of columns or rows. Preferably, said areas of light-emissive material are each formed to a thickness of from 10 to 500 nm. Preferably, said materials for emitting radiation are polymer materials . More preferably, said polymer materials are selected from poly (p- phenylene vinylene) for a green colour, poly (p-phenylene) or poly(p-phenylene vinylene) co-polymer with non-conjugated sections for a blue colour, and poly(1 , 4-napthylene vinylene) or a dialkoxy substituted poly(p-phenylene vinylene) for a red colour. Preferably, said areas of material for emitting radiation cover said first electrode regions so as to electrically insulate said first electrode regions from said second electrode regions. Preferably, said areas of material for emitting radiation each comprise a plurality of sub-areas, each sub-area overlying a respective one of said first electrode regions. More preferably, said sub-areas of material each comprise a plurality of further discrete sub-areas and said second electrode regions are formed to overlie selected ones of said further sub- areas . It will be understood that in the context of the present invention a precursor of a material is to be construed broadly as encompassing any precursor from which the material can in any way be formed. A method of manufacture of a colour polymer EL display is described herein wherein two or more precursor polymer materials are used to define the emitting areas and are deposited in sequence onto one electrode of the device, patterned and converted to their final form before deposition of the next polymer layer such that the converted polymers are not in any way damaged by the deposition, patterning or conversion of subsequent precursor layers . In one embodiment of the invention, one colour is first deposited then lithographically defined, and finally converted to its final form. Subsequently other colours are deposited and lithographically defined before conversion. Conversion of the precursor occurs through heat treatment or chemical treatment or electron beam exposure or radiation exposure (including electromagnetic radiation) or some combination of these techniques . In another embodiment of the invention the underlying electrode and/or the subsequently deposited top electrode are patterned to define areas of emission from the converted polymers, and the area of overlap between the electrodes is chosen to ensure that there is always an emitting polymer layer between the two electrodes . In another embodiment of the invention a further unpatterned layer is deposited on top of the patterned electroluminescent polymers and prior to the deposition of the final electrode, such layer being either a charge transport layer or a very thin dielectric layer whose thickness and constitution is chosen to increase the overall efficiency of the EL device; the area of overlap between the electrodes is chosen to ensure that there is always an emitting polymer layer between the two electrodes. The underlying mechanism that causes the precursor polymer to be changed into its final robust form can include scission of solubilising side groups or cross-linking of side groups on different polymer chains. Lithographic definition can take place through the use of compatible photoresists (i.e. that can be put down without disturbing the underlying layer) followed by masked exposure and development. Also possible is partial conversion using masked UV exposure prior to development and removal of the unwanted areas followed by a full conversion. The full conversion can be performed prior to the deposition of the next precursor polymer, or after any subsequent polymers have been patterned depending on the effect of subsequent solvents on the partially converted material. The final form of the polymers is insoluble in subsequent solvents. A final unpatterned layer can be subsequently deposited over all the emitting areas to improve efficiency. For a better understanding of the present invention and to show how the same may be carried into effect, reference will now be made by way of example to the accompanying drawings . Brief Description of the Drawings Figure 1 is a schematic section through part of a multi¬ colour device; Figure 2 is formulae of side-group leaving precursor materials for red, green and blue precursors and final polymer forms at a conversion temperature of 200°C; Figure 3 is an energy band diagram; and Figure 4 is a RGB dot-matrix architecture. Description of the Preferred Embodiment A specific embodiment that uses three precursors to red, green and blue emitters is now described. The final structure after processing is shown in Figure 1. The structure comprises a glass substrate 2 with patterned regions of a transparent electrode, which in the preferred embodiment is indium tin oxide. The strips define columns of the RGB dot-matrix architecture. As can be appreciated from the view of Figure 4, in the final structure these represent strips of indium tin oxide. The strips are denoted in Figure 1 by the reference numerals 4a, 4b and 4c. On top of each strip of indium tin oxide is a strip of a li- t emitting polymer. The polymers atop the strips 4a, 4b and 4c respectively emit light of different wavelengths, red, green and blue as illustrated. The red emitting polymer strip 6a lies on top of ITO strip 4a. The green emitting polymer 6b lies on top of ITO strip 4b. The blue emitting polymer strip 6c lies on top of ITO strip 4c. The respective wavelengths of emission are - 15 - indicated by the capital letters on the arrows. An optional electron transport/hole blocking layer extends crosswise and over the strips 4a, 4b and 4c. When the electron transport/hole blocking layer 8 is present the polymer strips can be narrower than the ITO strips. Atop this, lie a plurality of aluminium electrode strips 10. Once again, as can be seen from Figure 4 the aluminium electrode strips 10 and the electron transport/hole blocking layer extend crosswise to define rows of the dot matrix architecture. Each of the light emitting polymer strips 6a, 6b, 6c is derived from a respective precursor. The structure of Figure 1 is manufactured in accordance with the following steps. A layer of indium tin oxide is patterned on the glass substrate 2 to form the indium tin oxide strips 4a, 4b and 4c. A layer of a first precursor is formed over a first selected group of the ITO portions, that is those which are to excite emission of a first colour. For example, in the preferred embodiment the precursor to the red emitting polymer could be put down first. That precursor is susceptible to patterning, for example by etching, in its precursor form but, when converted or partially converted into its final polymer is substantially resistant to subsequent patterning steps. After being put down over the first selected group of ITO portions, the precursor is at least partially converted into its red emitting polymer. Then, a second precursor material is deposited over the first layer and over a second selected group of ITO portions. For example, the precursor to the green emitting polymer could next be deposited. That precursor is also susceptible to patterning, for example by etching, in its precursor form but is substantially resistant to patterning when at least partially converted. Thus, the second layer can be patterned while in its precursor form to remove it from above the first layer, but leaving the second layer over the second selected group of ITO portions. Then, the second precursor is at least partially converted into the green emitting polymer. Similar steps are carried out for the blue emitting polymer. Finally, any unconverted precursors are converted into their respective polymers . It will readily be appreciated that the precursors can be fully converted after being deposited and patterned. The order in which the precursors are put down may not be significant, though the materials with the most severe conversion conditions should be processed first (i.e. to minimize the damage to previously deposited emitting areas) . The three precursors are shown in Figure 2 (Formulae I, II and III) . The green emitter precursor (Formula I) is a polyphenylenevinylene (PPV) polymer with a tetrahydrathiophene leaving group and bromine counter ion. Conversion in an inert atmosphere can be effected at between 150 and 200°C. The blue emitter (Formula II) is a block copolymer which limits the conjugation length of the PPV monomer and thereby shifts the emission wavelength into the blue. For example, the blue copolymer is a PPV copolymer with non- conjugated sections. Similar conversion conditions to the green emitter are required. Finally a red emitting precursor (Formula III) is shown based on a polynaphthalene polymer with a tetrahydrathiophene leaving group and bromine counter ion. Again, similar conversion conditions to the green emitter are required. In this specific embodiment the ITO is patterned as lines (columns of a passive matrix display) and the subsequent precursor polymers are patterned as parallel lines each associated with a single ITO line, and each slightly wider so that the ITO lines are completely covered as in Figure 4. Finally the top electrode (e.g. aluminium) is deposited as orthogonal rows . Such a display can be addressed by applying data voltages to the columns and by sequential row selection so that within each selected row the required pixel/colour combinations are switched on. ΛmnoΛ Λ - WO 97/38445 - 17 - Alternatively before depositing the top electrode the optional second layer 8 above the RGB emitters can be added, both to help prevent shorting of the top contact to the ITO at the edge of the top electrode, and to increase the efficiency of emission. A conjugated polymer electron transport layer with a bandgap E qA as shown in Figure 3 can be used but may cause differential efficiency from each of the RGB areas. In the described embodiment E gA >E g B >E g G >E g R where E g BRG represents the energy gap of the blue red or green polymers respectively. In Figure 3, LUMO represents the lowest unoccupied molecular orbital and HOMO represents the highest occupied molecular orbital. Preferred is a thin dielectric layer (of order 10-lOOA thick) which allows electron injection from the cathode by tunnelling, but blocks holes from moving to the cathode as well as preventing any shorting or current flow between the top cathode and the ITO in areas where there is no emitting polymer. Because the dielectric has a high energy bandgap, it also has similar barrier properties with respect to each of the emitters and therefore will enhance the efficiencies of all the colour emitters.

Claims: CLAIMS : 1. A method of fabricating a multi-colour electroluminescent display, comprising the steps of: forming on a substrate a plurality of first electrode regions; forming over a first selected group of said first electrode regions a first layer of a precursor for a first material for emitting radiation of a first colour, said precursor for said first material being susceptible to patterning; at least partially converting said precursor for said first material into said first material which is substantially resistant to subsequent patterning steps; depositing over said first layer and over at least a second selected group of said first electrode regions a second layer of a precursor for a second material for emitting radiation of a second colour, said precursor for said second material being susceptible to patterning; patterning said second layer to remove said second layer from above said first layer and leaving said second layer over said second selected group of said first electrode regions; at least partially converting said precursor for said second material into said second material; converting any unconverted precursors into said respective materials; forming a plurality of second electrode regions over said layers in such a manner that said materials for emitting radiation can be selectively excited to emit radiation by applying an electric field between said first and second electrode regions. 2. A method of fabricating a multi-colour electroluminescent display according to claim 1, wherein said step of forming a plurality of first electrode regions comprises the steps of: depositing a layer of a conductive material on a substrate; and patterning said layer of said conductive material to form a plurality of first electrode regions. 3. A method of fabricating a multi-colour electroluminescent display according to claim 1 or 2, wherein said step of forming a first layer of a precursor for a first material comprises the steps of : depositing a layer of a precursor for a first material for emitting radiation of a first colour over said first electrode regions; and patterning said layer of said precursor for said first material to form a layer of said precursor for said first material over a first selected group of said first electrode regions . 4. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 3 , wherein said step of forming a plurality of second electrode regions comprises the steps of: depositing a layer of a conductive material over said layers; and patterning said layer of conductive material to form a plurality of second electrode regions. 5. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 4, wherein said steps of at least partially converting said precursor for said second material into said second material and converting any unconverted precursors for said first and second materials into said first and second materials are performed in a single step. 6. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 4 , wherein said second material is substantially resistant to subsequent patterning steps, and further comprising, after said step of at least partially converting said precursor for said second material, the steps of : depositing over said first and second layers and over a third selected group of said first electrode regions a third layer of a precursor for a third material for emitting radiation of a third colour, said precursor for said third material being susceptible to patterning; patterning said third layer to remove said third layer from over said first and second layers and leaving said third layer over said third selected group of said first electrode regions; and at least partially converting said precursor for said third material into said third material. 7. A method of fabricating a multi-colour electroluminescent display according to claim 6, wherein said steps of at least partially converting said precursor for said third material into said third material and converting any unconverted precursors for said first, second and third materials into said first, second and third materials are performed in a single step. 8. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 7, further comprising the step of depositing an electron transport layer prior to said step of forming said plurality of second electrode regions. 9. A method of fabricating a multi-colour electroluminescent display according to claim 8, wherein said electron transport layer is a conjugated polymer layer. 10. A method of fabricating a multi-colour electroluminescent display according to claim 8, wherein the thickness of said electron transport layer is from 5 to 200 nm. 11. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 7, further comprising the step of depositing a hole blocking layer prior to said step of forming said plurality of second electrode regions. 12. A method of fabricating a multi-colour electroluminescent display according to claim 11, wherein said hole blocking layer is a dielectric layer. 13. A method of fabricating a multi-colour electroluminescent display according to claim 11, wherein the thickness of said hole blocking layer is from 1 to 10 nm. 14. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 13, wherein said first electrode regions are composed of a light-trans issive conductive material . 15. A method of fabricating a multi-colour electroluminescent display according to claim 14, wherein said first electrode regions are composed of indium-tin oxide, tin oxide or zinc oxide . 16. A method of fabricating a multi-colour electroluminescent display according to claim 14 or 15, wherein said second electrode regions are composed of Al or an alloy thereof. 17. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 16, wherein the thickness of said first electrode regions is from 10 to 500 n . 18. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 17, wherein the thickness of said second electrode regions is from 10 to 1000 nm. 19. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 18, wherein each of said first and second electrode regions comprises a line. 20. A method of fabricating a multi-colour electroluminescent display according to claim 19, wherein the width of each of said lines of said first electrode regions is from 10 to 5000 μm. 21. A method of fabricating a multi-colour electroluminescent display according to claim 19 or 20, wherein the width of each of said lines of said second electrode regions is from 10 to 5000 μm. 22. A method of fabricating a multi-colour electroluminescent display according to any of claims 19 to 21, wherein the spacing between each of said lines of said first electrode regions is from 10 to 5000 μm. 23. A method of fabricating a multi-colour electroluminescent display according to any of claims 19 to 22, wherein the spacing between each of said lines of said second electrode regions is from 10 to 5000 μm. 24. A method of fabricating a multi-colour electroluminescent display according to any of claims 19 to 23, wherein said first electrode regions are one of columns or rows and said second electrode regions are the other of columns or rows . 25. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 24, wherein said layers of precursor for each of said materials are formed to a thickness of from 10 to 500 nm. 26. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 25, wherein said materials for emitting radiation are polymer materials. 27. A method of fabricating a multi-colour electroluminescent display according to claim 26, wherein said polymer materials are selected from poly(p-phenylene vinylene) for a green colour, poly(p-phenylene) or poly(p-phenylene vinylene) co-polymer with non-conjugated sections for a blue colour, and poly (1,4- napthylene vinylene) or a dialkoxy substituted poly(p-phenylene vinylene) for a red colour; - the poly(p-phenylene) precursors comprising: (i) poly(5,6 dialkyloxy-1, 3 cyclohexadiene) ; (ii) a polymer comprising recurring units of the general formula X denotes -SR 3 , -SO-R 3 , -S0 2 -R\ -COOR J ,-N0 2 , -CN, -CF 3 or -R\ R^R^R 3 are the same or different and denote -H, -R 4 or -X, R 4 denotes a straight chain or branched alkyl group with 1 to 20 carbon atoms, phenyl or benzyl, either of which can be substituted once or twice with -R 3 , -OR 1 , -N0 2 , -CN, -Br, -Cl or -F, and Ar denotes an aromatic system, comprising from 4 to 20 carbon atoms which can optionally be substituted; (iii) a thiophene, furan, pyrrole or pyridine analogue of (i) or (ii) ; and (iv) one of (i) , (ii) or (iii) with a onosubstitution or 2,5 disubstitution of alkoxy, alkyl, aryloxy, aryl, nitrile, nitro or -CF 3 - the poly(p-phenylene vinylene) precursor comprising: (i) poly(p-xylylene-α-dialkyl sulphonium halide) ; (ii) poly(p-xylylene-α-cycloalkyl sulphonium halide) ; (iii)poly(p-xylylene-α-halide) ; (iv) poly(p-xylylene-cf-alkoxide) where the alkyl ether can contain a cross-linkable group; (v) poly(p-xylylene-α-aryloxide) where the aromatic ester can be substituted by a cross-linkable group; (vi) poly(p-xylylene-cf-carboxylate) where the ester can be aliphatic or aromatic and contain a cross-linkable group; (vii) a polymer comprising recurring units of the general formula: R 1 R 2 I I ( C - Ar - C ) X R 3 X denotes -SR 3 , -SO-R 3 , -S0 2 -R J , -COOR\-NO ? , -CN, R RYR 3 are the same or different and denote -H, -R 4 or -X, R 4 denotes a straight chain or branched alkyl group with 1 to 20 carbon atoms, phenyl or benzyl, either of which can be substituted once or twice with -R', -OR 1 , -N0 2 , -CN, -Br, -Cl or -F, and Ar denotes an aromatic system, comprising from 4 to 20 carbon atoms which can optionally be substituted; (viii) a thiophene, furan, pyrrole or pyridine analogue of any of (i) to (vii) ; and (ix) one of (i) to (viii) with a monosubstitution or 2,5 disubstitution of alkoxy, alkyl, aryloxy, aryl, nitrile, nitro or -CF 3 - the poly(1, 4-napthylene vinylene) precursor comprising: (i) poly(l,4 benzoxylylene-α-dialkyl sulphonium halide) ; (ii) poly(l,4 benzoxylylene-α-cycloalkyl sulphonium halide) ; (iii) poly(1, 4 benzoxylylene-α-halide) ; (iv) poly (1,4 benzoxylylene-α-alkoxide) where the alkyl ether can contain a cross-linkable group; (v) poly (1,4 benzoxylylene-α-aryloxide) where the aromatic ester can be substituted by a cross-linkable group; (vi) poly (1,4 benzoxylylene-α-carboxylate) where the ester can be aliphatic or aromatic and contain a cross-linkable group; and (vii) a polymer comprising recurring units of the general formula: R 1 R 2 I I ( C - Ar - C ) I l 3 X R 3 X denotes -SR 3 , -SO-R 3 , -S0 2 -R\ -COOR\-N0 2 , -CN, -CF 3 or -R 3 , R λ ,R 2 ,R 3 are the same or different and denote -H, -R 4 or -X, R 4 denotes a straight chain or branched alkyl group with 1 to 20 carbon atoms, phenyl or benzyl, either of which can be substituted once or twice with -R 3 , -OR 1 , -N0 2 , -CN, -Br, -Cl or -F, and Ar denotes an aromatic system, comprising from 4 to 20 carbon atoms which can optionally be substituted. 28. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 27, wherein said steps of patterning said precursor materials comprise steps of etching. 29. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 28, wherein said conversion steps comprise at least one of heat treatment, chemical treatment, electron beam exposure or radiation exposure. 30. A method of fabricating a multi-colour electroluminescent display according to claim 29, wherein said conversion steps comprise a heat treatment at a temperature of from 50 to 300 "C in an inert atmosphere . 31. A method of fabricating a multi-colour electroluminescent display according to claim 30, wherein said heat treatment is performed at about 150 * C. 32. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 31, wherein said layers of said materials for emitting radiation are formed to cover said first electrode regions so as to electrically insulate said first electrode regions from said second electrode regions. 33. A method of fabricating a multi-colour electroluminescent display according to any of claims 1 to 32, wherein said layers of said materials for emitting radiation each comprise a plurality of areas, each area overlying a respective one of said first electrode regions. 34. A method of fabricating a multi-colour electroluminescent display according to claim 33, wherein said areas of material each comprise a plurality of discrete sub-areas and said second electrode regions are formed to overlie selected ones of said sub-areas . 35. A multi-colour electroluminescent display, comprising: a substrate; a plurality of first electrode regions formed over said substrate; a plurality of discrete, laterally-spaced areas of light- emissive material formed over said first electrode regions, wherein selected groups of said plurality of areas are each formed of a material for emitting radiation of a different colour *and each individual first electrode region has only a material for emitting radiation of one colour formed thereover; and a plurality of second electrode regions formed over said plurality of light-emissive areas; wherein said light-emissive areas can be selectively excited to emit radiation by applying an electric field between said first and second elec . rode regions . 36. A multi-colour electroluminescent display according to claim 35, comprising a plurality of areas of a first material for emitting radiation of a first colour formed over a first selected group of said first electrode regions, a plurality of areas of a second material for emitting radiation of a second colour formed over a second selected group of said first electrode regions, and a plurality of areas of a third material for emitting radiation of a third colour formed over a third selected group of said first elertrode regions. 37. A multi-colour electroluminescent display according to claim 36, wherein said plurality of areas of said first, second and third materials are arranged such that each area of said plurality of areas of said second material is adjacent a respective one of said plurality of areas of said first material and a respective one of said plurality of areas of said third material . 38. A multi-colour electroluminescent display according to any of claims 35 to 37, further comprising an electron transport layer between said plurality of light-emissive areas and said plurality of said second electrode regions. 39. A multi-colour electroluminescent display according to claim 38, wherein said electron transport layer is a conjugated polymer layer. 40. A multi-colour electroluminescent display according to claim 38, wherein the thickness of said electron transport layer is from 5 to 200 nm. 41. A multi-colour electroluminescent display according to any of claims 35 to 37, further comprising a hole blocking layer between said plurality of light-emissive areas and said plurality of said second electrode regions . 42. A multi-colour electroluminescent display according to claim 41, wherein said hole blocking layer is a dielectric layer. 43. A multi-colour electroluminescent display according to claim 41, wherein the thickness of said hole blocking layer is from 1 to 10 nm. 44. A multi-colour electroluminescent display according to any of claims 35 to 43, wherein said first electrode regions are composed of a light-transmrssive conductive material. 45. A multi-colour electroluminescent display according to claim 44, wherein said first electrode regions are composed of indium- tin oxide, tin oxide or zinc oxide. 46. A multi-colour electroluminescent display according to claim 44 or 45, wherein said second electrode regions are composed of Al or an alloy thereof. 47. A multi-colour electroluminescent display according to any of claims 35 to 46, wherein the thickness of said first electrode regions is from 10 to 500 nm. 48. A multi-colour electroluminescent display according to any of claims 35 to 47, wherein the thickness of said second electrode regions is from 10 to 1000 nm. 49. A multi-colour electroluminescent display according to any of claims 35 to 48, wherein each of said first and second electrode regions comprises a line. 50. A multi-colour electroluminescent display according to claim 49, wherein the width of each of said lines of said first electrode regions is from 10 to 5000 μm. 51. A multi-colour electroluminescent display according to claim 49 or 50, wherein the width of each of said lines of said second electrode regions is from 10 to 5000 μm. 52. A multi-colour electroluminescent display according to any of claims 49 to 51, wherein the spacing between each of said lines of said first electrode regions is from 10 to 5000 μm. 53. A multi-colour electroluminescent display according to any of claims 49 to 52, wherein the spacing between each of said lines of said second electrode regions is from 10 to 5000 μm. 54. A multi-colour electroluminescent display according to any of claims 49 to 53, wherein said first electrode regions are one of columns or rows and said second electrode regions are the other of columns or rows . 55. A multi-colour electroluminescent display according to any of claims 35 to 54, wherein said areas of light-emissive material W - 29 - are each formed to a thickness of from 10 to 500 nm. 56. A multi-colour electroluminescent display according to any of claims 35 to 55, wherein said materials for emitting radiation are polymer materials. 57. A multi-colour electroluminescent display according to claim 56, wherein said polymer materials are selected from poly(p-phenylene vinylene) for a green colour, poly(p-phenylene) or poly(p-phenylene vinylene) co-polymer with non-conjugated sections for a blue colour, and poly(1, 4-napthylene vinylene) or a dialkoxy substituted poly(p-phenylene vinylene) for a red colour. 58. A multi-colour electroluminescent display according to any of claims 35 to 57, wherein said areas of material for emitting radiation cover said first electrode regions so as to electrically insulate said first electrode regions from said second electrode regions. 59. A multi-colour electroluminescent display according to any of claims 35 to 58, wherein said areas of material for emitting radiation each comprise a plurality of sub-areas, each sub-area overlying a respective one of said first electrode regions. 60. A multi-colour electroluminescent display according to claim 59, wherein said sub-areas of material each comprise a plurality of further discrete sub-areas and said second electrode regions are formed to overlie selected ones of said further sub-areas. 61. A method of fabricating a multi-colour electroluminescent display substantially as hereinbefore described with reference to the accompanying drawings . 62. A multi-colour electroluminescent display substantially as hereinbefore described with reference to the accompanying drawings .

Inventors: MAY PAUL, MAY, PAUL
Applicants: CAMBRIDGE DISPLAY TECH, MAY PAUL, CAMBRIDGE DISPLAY TECHNOLOGY LIMITED, MAY, PAUL
Application year: 1997
Main classification: H01L27
IPC codes: C09K11, H01L27, H01L51, H05B33