Composite magnetostrictive material, and process for producing the same

Abstract: A composite magnetostrictive material having a magnetostrictive performance required for practical use and yet a higher strength. A composite magnetostrictive material 1 is comprised of a matrix 2 formed of a magnetostrictive material of an RM-based alloy, wherein R is a rare earth clement and M is one of a transition metal and aluminum, and dispersion phases 3 dispersed in the matrix and formed of at least one of an RM-based alloy, R and M.

Description: The present invention relates to a composite magnetostrictive material, and a process for producing the same. There is a conventionally known magnetostrictive material formed of an SmFe-based alloy. This magnetostrictive material has an excellent magnetostrictive performance, but suffers from the problem that it has a low physical strength. Further examples of rare earth iron-based permanent magnets are known from EP 0386286. WO 95/04996 specifically relates to the permanent magnetic properties of a SmFe alloy, doped with Ta. Reinsch et al. (IEEE Transactions on Magnetics, Vol. 28, No. 5, September 1992) discloses ferromagnetic and non-ferromagnetic alloys consisting of Fe, Sm and Ti. It is an object of the present invention to provide a composite magnetostrictive material having a magnetostrictive performance required for practical use, and a higher physical strength. To achieve the above object, according to the present invention there is provided a composite magnetostrictive material comprising a matrix formed of a magnetostrictive material made of an SmFe-based alloy, and dispersion phases dispersed in the matrix wherein each dispersion phase is formed of an SmCu-based alloy, and the content of Cu is greater than zero but not more than 15% by volume, or wherein each dispersion phase is formed of SmNi and the content of Ni is greater than zero but not more than 18% by volume, or wherein each dispersion phase is formed of Sm. With the above feature of the present invention, the dispersion phase exhibits a composite reinforcing capability, and hence an enhancement in strength of the composite magnetostrictive material is achieved. In this case, as the amount of the dispersion phases is increased, the magnetostrictive performance of the composite magnetostrictive material is lowered. However, the magnetostrictive performance can be maintained at a suitable level for practical use by adjusting the amount of the dispersion phases. It is another object of the present invention to provide a production process which is capable of easily mass-producing a composite magnetostrictive material of the above-described type. To achieve the above object, according to the present invention, there is provided a process for producing a composite magnetostrictive material, comprising the steps of bringing a diffusing material into contact with a magnetostrictive material formed of an SmFe-based alloy, wherein said diffusing material is formed of at least one of Sm, Cu and Ni and subjecting the diffusing material and the magnetostrictive material to a thermal treatment to produce a liquid phase diffusion. With the above process, a composite magnetostrictive material can be easily mass-produced. In this case, it is possible to enhance the diffusion of liquid phases and the magnetostrictive performance of the magnetostrictive material simultaneously by adjusting the heating temperature and time. In the accompanying drawings: Fig. 1 is an illustration of the metallographic structure of a composite magnetostrictive material according to an embodiment of the invention. Fig. 2 is a side view showing the relation between a magnetostrictive material and diffusing materials. Fig. 3 is a photomicrograph showing the metallographic structure of a magnetostrictive material, Fig. 4A is a photomicrograph showing the metallographic structure of a composite magnetostrictive material, and Fig. 4B is a tracing of an essential portion thereof shown in Fig. 4A. Fig. 5 is a graph illustrating the relationship between the content of Ni, the magnetostriction amount and the compression strength. Fig. 6A is a photomicrograph showing the metallographic structure of a composite magnetostrictive material, and Fig. 6B is a tracing of an essential portion thereof shown in Fig. 6A. Fig. 7 is a graph illustrating the relationship between the content of Sm, the magnetostriction amount and the compression strength. Fig. 8A is a photomicrograph showing the metallographic structure of a composite magnetostrictive material and Fig. 8B is a tracing of an essential portion thereof shown in Fig. 8A. Fig. 1 illustrates the metallographic structure of a composite magnetostrictive material 1. The metallographic structure is comprised of a matrix 2 formed of a magnetostrictive material of an RM-based alloy (wherein R is a rare earth element, and M is one selected from the group consists of transition metals and aluminium), and dispersion phases 3 dispersed in the matrix 2 which dispersion phases 3 are formed of at least one of an RM alloy, R and M. The rare earth element R that may be used is any one of the 17 rare earth elements such as Sm, Tb, Dy and the like. A suitable transition metal M is any of the metal elements having atomic numbers from 22 to 30, i.e. from Ti to Zn. If the composite magnetostrictive material 1 is formed in the above manner, the dispersion phase 3 exhibits a composite reinforcing capability, and hence an enhancement in the physical strength of the composite magnetostrictive material 1 is achieved. In producing the composite magnetostrictive material 1, as shown in Fig. 2, plate-like diffusing materials 5 each formed of at least one of an RM-based alloy, R and M are brought into contact with opposite sides of a plate-like magnetostrictive material 4 which is a cast product and formed of an RM-based alloy. The plate-like magnetostrictive material 4 and the plate-like diffusing materials 5 are clamped by a pair of clamping members 6 and then subjected to a thermal treatment, whereby they are partially molten to produce the diffusion of liquid phases. The thermal treating temperature T is a temperature at which a partial melting is produced. This temperature is determined from state diagrams of the magnetostrictive material 4 and the plate-like diffusing material 5 and is in a range of about 500°C ≤ T ≤ about 900°C, depending on the materials. The thermal treating time t is determined from a liquid phases diffusion coefficient of the diffusing material 5 and is in a range of about 0.5 hr. ≤ t ≤ about 9 hr., depending on the diffusing material. Further, it is desirable that the thermal treatment be carried out in an inert gas atmosphere or in a vacuum for preventing the degradation of the magnetostrictive material 4. In this case, it is possible to enhance the magnetostrictive performance of the magnetostrictive material 4 and thus of the matrix 2 simultaneously with the diffusion of the liquid phases by adjusting the heating temperature and time. EXAMPLES A Using a high-frequency melting furnace, a molten metal having a composition of an SmFe 1.7 alloy (the unit of a numeral value is the number of moles of the atom) was prepared under a reduced pressure (600 Torr) in an atmosphere of argon and poured into a casting mold of copper at a casting temperature of 1200°C, thereby producing a magnetostrictive material 4 in a casting manner. Fig. 3 is a photomicrograph showing the metallographic structure of the magnetostrictive material 4. In Fig. 3, a gray phase of SmFe 2 , a black phase of SmFe 3 and a white phase of Sm are observed. As shown in Fig. 2, plate-like diffusing materials 5 made of an Fe-Ni alloy were brought into contact with opposite sides of the plate-like magnetostrictive material 4, respectively. The plate-like diffusing materials 5 and the plate-like magnetostrictive material 4 were clamped by a pair of clamping members 6 made of iron and then subjected to a thermal treatment in a vacuum at 800°C for 6 hours to produce a composite magnetostrictive material 1, while at the same time enhancing the magnetostrictive performance of the magnetostrictive material 4. Fig. 4A is a photomicrograph showing the metallographic structure of the composite magnetostrictive material 1, and Fig. 4B is a tracing of an essential portion thereof shown in Fig. 4A. In Figs. 4A and 4B, a gray phase of Fe 7 Ni 3 and a black phase of FeNi are formed in a sequentially laminated manner on the surface of the composite magnetostrictive material 1. In the composite magnetostrictive material 1, a matrix 2 comprised of a light gray phase of SmFe 2 of the magnetostrictive material and dark gray phases of Sm 2 Fe 17 , and dispersion phases 3 of SmNi dispersed in the matrix are observed. In this case, the content "C" of Ni in the composite magnetostrictive material 1 was equal to 20 % by volume. Four more composite magnetostrictive materials 1 having different contents of Ni were produced using varied thermal treating times. Then, the magnetostriction amount and the compression strength of each of Examples 1 to 5 of the composite magnetostrictive materials 1 were measured. The magnetostriction amount was measured by applying a magnetic field at 1.5/4π.10 6 A/m (1.5 kOe) using a strain gauge. The compression strength was measured by a usual method. These measuring methods were likewise utilized for examples which will be described hereinafter. Table 1 shows the thermal treating time, the content of Ni, the magnetostriction amount and the compression strength for the Examples 1 to 5. In Table 1, an Example 6 was produced by subjecting the magnetostrictive material 4 after casting to a thermal treatment in a vacuum at 800°C for 6 hours in order to provide an enhanced magnetostrictive performance but without applying a diffusing material 5. Thermal treating temperature: 800°C Examples A Thermal Treating Time (hr) Content of Ni (%by volume) Magnetostriction amount (ppm) Compression strength (kgf/mm 2 ) Example 1 9 25 320 39.0 Example 2 6 20 590 38.6 Example 3 5 15 640 37.0 Example 4 4 10 760 35.6 Example 5 2 5 830 31.9 Example 6 6 0 1060 26.0 Fig. 5 is a graph illustrating the relationship between the content of Ni, the magnetostriction amount and the compression strength, as taken from Table 1. As is apparent from Fig. 5, in the composite magnetostrictive material, the strength is enhanced, but the magnetostriction amount is decreased, as the content of Ni is increased. For a composite magnetostrictive material for practical use, it is required that the composite magnetostrictive material has a magnetostriction amount of 600 ppm or more. From this, the content C of Ni is set in a range of C ≤ 18% by volume (wherein C > 0 % by volume). EXAMPLES B As shown in Fig. 2, plate-like diffusing materials 5 of Fe were brought into contact with opposite sides of a plate-like magnetostrictive material 4, respectively. These materials 4 and 5 were clamped by a pair of clamping members 6 made of iron and then subjected to a thermal treatment in a vacuum at 800°C for 4 hours, thereby producing a composite magnetostrictive material 1, while at the same time, enhancing the magnetostrictive performance of the magnetostrictive material 4. Fig. 6A is a photomicrograph showing the metallographic structure of the composite magnetostrictive material 1, and Fig. 6B is a tracing of an essential portion thereof shown in Fig. 6A. In Figs. 6A and 6B a matrix 2 comprised of a gray phase of SmFe 2 and dispersion phases 3 of Sm dispersed in the matrix 2 are observed. In this case, the content C' of Sm in the composite magnetostrictive material 1 is equal to 5% by volume. In the thermal treatment, a portion of the phase of Sm in the magnetostrictive material reacted with Fe to produce a phase of SmFe 2 , and hence the phase of Sm in Fig. 6 is an unreacted remaining phase of Sm. Then, utilizing varied thermal treating times, four more composite magnetostrictive materials 1 having different contents of Sm were produced in the same manner. Then, the magnetostriction amount and the compression strength of each of Examples 1 to 5 of the composite magnetostrictive materials 1 were measured. Table 2 shows the thermal treating time, the content of Sm, the magnetostriction amount and the compression strength for the Examples 1 to 5. In Table 2, the Example 6 is the same as the Example 6 in Table 1. Thermal treating temperature: 800°C Examples B Thermal Treating Time (hr) Content of Sm (%by volume) Magnetostriction amount (ppm) Compression strength (kgf/mm 2 ) Example 1 0.5 25 295 38.5 Example 2 1.0 20 510 36.3 Example 3 1.5 15 600 34.6 Example 4 2.0 10 720 29.4 Example 5 4.0 5 820 30.0 Example 6 6.0 0 1060 26.0 Fig. 7 is a graph illustrating the relationship between the content of Sm, the magnetostriction amount and the compression strength, as taken from Table 2. As is apparent from Fig. 7, in the composite magnetostrictive material 1, the strength is enhanced, but the magnetostriction amount is decreased, as the content of Sm is increased. For a composite magnetostrictive material for practical use, it is required that the composite magnetostrictive material has a magnetostriction amount of 600 ppm or more. From this, the content C' of Sm is set in a range of C' ≤ 15% by volume (wherein C' > 0% by volume). EXAMPLES C A magnetostrictive material 4 of SmFe 1.5 alloy (the unit of a numerical value is the number of moles of the atom) was produced in the same process as described above. The magnetostrictive material 4 also had a metallographic structure similar to the magnetostrictive material as for Examples A above. As shown in Fig. 2, plate-like diffusing materials 5 made of copper (Cu) were brought into contact with opposite sides of the plate-like magnetostrictive material 4, respectively. These materials 4 and 5 were clamped by a pair of clamping members 6 made of copper and then subjected to a thermal treatment in a vacuum at 800°C for 6 hours to produce a composite magnetostrictive material 1, while at the same time enhancing the magnetostrictive performance of the magnetostrictive material 4. Fig. 8A is a photomicrograph showing the metallographic structure of the composite magnetostrictive material 1, and Fig. 8B is a tracing of an essential portion thereof shown in Fig. 8A. In Figs. 8A and 8B, a matrix 2 comprised of gray phases of SmFe 2 and a black phase of Sm 2 Fe 17 and light gray dispersion phases 3 of Sm 7 Cu 3 dispersed in the matrix are observed. In this case, the content C" of Cu in the composite magnetostrictive material 1 was equal to 20% by volume. According to the present invention, it is possible to provide a composite magnetostrictive material having a magnetostrictive performance required for practical use and yet a higher strength. In addition, according to the present invention, it is possible to provide a process for easily mass-producing a composite magnetostrictive material of the above-described type.

Claims: A composite magnetostrictive material comprising a matrix formed of a magnetostrictive material made of an SmFe-based alloy, characterised in that dispersion phases are dispersed in the matrix wherein each dispersion phase is formed of an SmCu-based alloy, and the content of Cu is greater than zero but not more than 15% by volume, or wherein each dispersion phase is formed of SmNi and the content of Ni is greater than zero but not more than 18% by volume. A composite magnetostrictive material comprising a matrix formed of a magnetostrictive material made of an SmFe-based alloy, characterised in that dispersion phases are dispersed in said matrix wherein each dispersion phase is formed of Sm. A composite magnetostrictive material according to claim 2, wherein the content of Sm is greater than zero but not more than 15% by volume. A process for producing a composite magnetostrictive material comprising the steps of bringing a diffusing material into contact with a magnetostrictive material formed of an SmFe-based alloy, wherein said diffusing material is formed of at least one of Sm, Cu and Ni, and subjecting said diffusing material and said magnetostrictive material to a thermal treatment effective to produce a liquid phase diffusion.

Inventors: KITA TERUYOSHI, SUKIGARA TOHRU, TAKIZAWA JUN, KITA, TERUYOSHI, SUKIGARA, TOHRU, TAKIZAWA, JUN
Applicants: HONDA MOTOR CO LTD, HONDA GIKEN KOGYO KABUSHIKI KAISHA
Application year: 1997
Main classification: H01L41
IPC codes: C22F1, H01L41, C22C28, C22C38, H01F1