LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY ELEMENT

Abstract: A liquid crystal composition containing at least one kind of first component (I-a, I-b), second component (II-a to II-d) and third component (III-a to III-c) respectively, wherein R<1> and R<2> denote an alkyl group having from 1 to 10 carbon atom(s), optional one or non-adjacent two or more than two methylene group(s) (-CH2-) in the above-mentioned groups may be substituted by (an) oxygen atom(s) (-O-) and -CH=CH- in all cases, Z DEG denotes -COO- or -CH2CH2-, Z<1>, Q<1>, A<1> and A<3> denote the defined cyclic groups respectively, p, q and m denote each independently 0 or 1, and n denotes an integer of from 0 to 20.

Description: D E S C R I P I T I O N LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY ELEMENT Technical Field The present invention relates to a nematic liquid crystal composition containing at least one chiral additive arranged within a sealed cell formed of two substrates having transparent electrodes and a liquid crystal display element with use of the said liquid crystal composition. In more detail, the invention relates to a liquid crystal composition suitable for a super twist birefringence (STN) mode and a liquid crystal display element with use of the said liquid crystal composition. Background Art There have been proposed and put to practical uses one after another a twist nematic (TN) mode, a super twist birefringence (STN) mode and an active matrix (AM-LCD) mode etc. Amongst there of, a super twist birefringence (STN) mode proposed by T. J. Scheffer et al. (Appl. Phy. Lett., 45 (10), 1021 (1984)) wherein alignments of liquid crystal molecules in the upper and lower substates are twisted at from 180 to 270° is adapted as LCD's for personal computers and word processors etc. and it becomes to be required more various improvements as to its characteristics. The liquid crystal composition used for the liquid crystal display element of the said STN mode is required to have the following characteristics: (1) a voltage - transmittance characteristic (a sharpness) being sharp in order to increase a contrast of the liquid crystal display element, (2) a phase transition temperature (a transparent point) being high in order to decrease a change in coloring due to a temperature dependency of a refractive anisotropy ( Δn) , and (3) a viscosity ( 7? ) being low in order to decrease a response time as possible. Amongst these characteristics, in particular, correspondency to coloring and correspondency to animation are strongly required recently, and particularly improvements of the above- mentioned characteristics (1) and (3) become important. However, even though such liquid crystal compositions have been zealously investigated, improvements have been always required under present conditions. Disclosure of the Invention We inventors investigated various compositions with use of various liquid crystal compounds in order to solve these subjects, and found that the objects can be attained in the case of using a liquid crystal composition according to the present invention as a STN display element. As clear from the above description, an object of the invention is to propose a liquid crystal composition which satisfies various characteristics required for the above- mentioned STN display mode and simultaneously has a superior voltage - transmittance characteristic (a sharpness) for corresponding to coloring and also a low viscosity for corresponding to a high-speed responce. Best Mode for Carrying out the Invention The present invention is explained as follows. (1) A liquid crystal composition characterized in that at least one compound expressed by the general formulae I-a and I-b (wherein, R 1 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 _ ) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the first component, at least one compound expressed by the general formulae Il-a, Il-b, II-c and Il-d (wherein, R 1 denotes an alkyl group having from 1 to 10 carbon atom(s) , optional one or non-adjacent two or more than two methylene group (s) (-CH2-) in the above-mentioned groups may be substituted by (an) oxygen ato (s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the second component, and one or more than one compound (s) selected from the group of compounds expressed by the general formulae Ill-a, Ill-b and III-c R )—(A l )-<0>-CN (Ill-a) R 2 -(- • ) o —(A 2 )-Z°-(θ>-CN (Ill-b) (wherein, R 2 denotes an alkyl group having from 1 to 10 carbon atom(s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, Z° denotes -COO- or -CH 2 CH 2 -, V denotes -CH 2 CH 2 -, -C00- or a single bond, Q 1 denotes H or F, Al denotes trans-1,4- cyclohexylene, 1, 4-phenylene or 1 , 3-dioxane-2, 5-diyl, A 2 and A 3 denote each independently trans-1, 4-cyclohexylene or 1,4- phenylene, and p, q and m each independently denote 0 or 1.) is contained as the third component. (2) A liquid crystal composition described in the above- mentioned item (1) , characterized in that the first component is from 3 to 50% by weight, the second component is from 3 to 40% by weight and the third component is from 10 to 60% by weight, all based on the total weight of the liquid crystal composition. (3) A liquid crystal composition characterized in that at least one compound expressed by the general formulae I-a and I-b (wherein, R 1 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom(s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the first component, at least one compound expressed by the general formulae II-a, II-b, II-c and 11-d R 1 -(CH 2 ) n CH=CF 2 (H-a) R' R &-©- > "(CH; )π- ■ CH=CHF (Il-d) (wherein, R 1 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the second component, one or more than one compound (s) selected from the group of compounds expressed by the general formulae Ill-a, III-b and III-c (wherein, R 2 denotes an alkyl group having from 1 to 10 carbon atom(s) , optional one or non-adjacent two or more than two methylene group (s) (-CH Z -) in the above-mentioned groups may be substituted by (an) oxygen atom(s) (-0-) and -CH=CH- in all cases, Z° denotes -COO- or -CH 2 CH 2 -, V denotes -CH 2 CH 2 -, -C00- or a single bond, Q 1 denotes H or F, A 1 denotes trans-1,4- cyclohexylene, 1 , 4-phenylene or 1 , 3-dioxane-2, 5-diyl, A 2 and A 3 denote each independently trans-1 , 4-cyclohexylene or 1,4- phenylene, and p, q and m each independently denote 0 or 1.) is contained as the third component, and at least one or more than one compound (s) selected from the group of compounds expressed by the general formulae IV and V, Vl-a and Vl-b R 3 -(B)-Z 2 - (C)-R 4 (IV) (wherein, R 3 and R 4 denote each independently an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene grou (s) (-CH 2 -) in the above- mentioned groups may be substituted by (an) oxygen atom (s) and -CH=CH- in all cases, B denotes trans-1, 4-cyclohexylene, pyrimidine-2, 5-diyl or 1, 4-phenylene, C denotes trans-1,4- cyclohexylene or 1 , 4-phenylene, and Z 2 denotes -C≡C-, -C00-, -CH 2 CH 2 -, -CH=CH-. -CF=CF- or a single bond.), R 5 - (D)-Z 3 -(E)-Z 4 -(G)-R 6 (V) (wherein, R 5 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom(s) (-0-) and -CH=CH- in all cases, R 6 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atom (s) , D denotes trans-1 , 4-cyclohexylene or pyrimidine-2, 5-diyl, E denotes trans- 1, 4-cyclohexylene or 1, 4-phenylene in which one H at a branched position may be optionally substituted with F, G denotes trans- 1, 4-cyclohexylene or 1, 4-phenylene, Z 3 denotes -CH 2 CH 2 - or a single bond, and Z 4 denotes -C≡C-, -COO- or -CH=CH- or a single bond. ) , (wherein, R 7 denotes an alkyl group having from 1 to 10 carbon atom(s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom(s) (-0-) and -CH=CH- in all cases, R a denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atom (s) , and Q 2 denotes H or F. ) is contained as the fourth component. (4) A liquid crystal composition described in the above- mentioned item (3) , characterized in that the first component is from 3 to 50% by weight, the second component is from 3 to 40% by weight, the third component is from 10 to 60% by weight, and the fourth component is from 1 to 60% by weight, all based on the total weight of the liquid crystal composition. (5) A liquid crystal composition characterized in that at least one compound expressed by the general formulae I-a and I-b R 1 (CH 2 ) n - • CH=CF 7 (l-a) ■ (CH 2 )„ CH=CHF (l-b) (wherein, R 1 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom(s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the first component, at least one compound expressed by the general formulae Il-a, Il-b. II-c and Il-d (wherein, R 1 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.)' is contained as the second component, one or more than one compound (s) selected from the group of compounds expressed by the general formulae 111-a, Ill-b and III-c (wherein, R 2 denotes an alkyl group having from 1 to 10 carbon atom(s), optional one or non-adjacent two or more than two methylene group (s) (-CH2-) in the above-mentioned groups may be substituted by (an) oxygen atom(s) (-0-) and -CH=CH- in all cases, Z° denotes -COO- or -CH 2 CH 2 -, V denotes -CH 2 CH 2 . -C00- or a single bond, Q 1 denotes H or F, A 1 denotes trans-1,4- cyclohexylene, 1, 4-phenylene or 1, 3-dioxane-2, 5-diyl, A 2 and A 3 denote each independently trans-1, 4-cyclohexylene or 1,4- phenylene, and p, q and m each independently denote 0 or 1.) is contained as the third component, at least one or more than one compound (s) selected from the group of compounds expressed by the general formulae IV and V, Vl-a and Vl-b R 3 -(B)-Z Z -(C)-R 4 (IV) (wherein, R 3 and R 4 denote each independently an alkyl group having from 1 to 10 carbon ato (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above- mentioned groups may be substituted by (an) oxygen atom (s) and -CH=CH- in all cases, B denotes trans-1, 4-cyclohexylene, pyrimidine-2, 5-diyl or 1, 4-phenylene, C denotes trans-1,4- cyclohexylene or 1, 4-phenylene, and Z2 denotes -C≡C-, -C00-, -CH 2 CH 2( -CH=CH-, -CF=CF- or a single bond.), R 5 -(D)-Z 3 -(E)-Z 4 -(G)-R 6 (V) (wherein, R 5 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, R 6 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atom(s) , D denotes trans-1, 4-cyclohexylene or pyrimidine-2, 5-diyl, E denotes trans- 1, 4-cyclohexylene or 1, 4-phenylene in which one H at a branched position may be optionally substituted with F, G denotes trans- 1, 4-cyclohexylene or 1 , 4-phenylene, Z 3 denotes -CH 2 CH 2 - or a single bond, and Z 4 denotes -C≡C-, -COO- or -CH=CH- or a single bond. ) , (wherein, R 7 denotes an alkyl group having from 1 to 10 carbon atom(s), optional one or non-adjacent two or more than two methylene group (s) (-CH 2 ~ ) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, R 8 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atom(s) , and Q z denotes H or F.) is contained as the fourth component, and at least one or more than one compound (s) selected from the group consisting of compounds expressed by the general formulae VII and VIII (wherein, R 9 denotes an alkyl group having from 1 to 10 carbon atom (s) , Q 3 denotes H or F, and k denotes 0 or 1) , (wherein, R 10 denotes an alkyl group having from 1 to 10 carbon atom(s) , J denotes trans-1, 4-cyclohexylene or 1, 4-phenylene, Q 4 and Q 5 denote each independently H or F, Z 5 and Z β denote each independently -COO- or a single bond, and h denotes 0, 1 or 2.) as the fifth component. (6) A liquid crystal composition described in the above- mentioned item (5) , characterized in that the first component is from 3 to 50% by weight, the second component is from 3 to 40% by weight, the third component is from 10 to 60% by weight, the fourth component is from 1 to 60% by weight, and the fifth component is from 1 to 50% by weight, all based on the total weight of the liquid crystal composition. (7) A liquid crystal display element comprising a liquid crystal composition described in any of the above-mentioned items (1) to (6) . The liquid crystal compounds constituting the liquid crystal compositions according to the invention are explained as follows. There may be preferably mentioned the following compounds as the co poundes expressed by the general formula I according to the invention. (whrein, R denotes an alkyl group.) These compounds are known from Toku-Kai-Hei 1-175947 official gazette, Toku-Kai-Hei 1-308239 official gazette (EP0325796B) and Toku-Kai-Hei 2-184642 official gazette (EP377469B1) . These compounds are those with weak positive dielectric anisotropies, and they are used for purposes to lower a viscosity and improve a sharpness. As the compounds expressed by the general formulae Il-a, Il-b, II-c and 11 -d for the second component according to the invention, the followings may be mentioned with structural formulae of the preferable compounds and phase transition points of the typical compounds. ZCHF (ll-b-4) R-^-<@ -(^- H = CF 2 (ll-c-1) R = C 2 H 5 C 7 7. 3 S 1 3 0. 6 N 1 5 7. 1 I R" ^^ " ^©^ ~C3H6~CH - CF2 (whrein, R denotes an alkyl group.) These compounds are those with weak positive dielectric anisotropies and large refractive anisotropies (Δn) such asΔn> 0.1, and they are used mainly for a purpose to enlarge a nematic range or for purposes to lower a viscosity and improve a sharpness. As the compounds expressed by the general formulae III-a, 111-b and III-c for the third component according to the invention, the following compounds may be preferably mentioned. R - ~~ CH 2 CH 2 - O CN (lll-b-1) R-/ V-COO-Zo -CN (lll-b-2) R -iyy—iy- ^^ ~ {c ~ CN (lll-b-5) R- cθO-/θ cN (lll-c-3) F : → ] ~ ^θ " C0 ° -{θ - N (lll-c-10) (whrein, R denotes an alkyl group. Furthermore, optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by -CH=CH-.) Amongst these compounds, in particular, compounds expressed by the formulae (III-a-1) , (III-a-3) , (III-a-6) , (III-a-7) , (III-b-1) , (III-b-3) , (III-b-5) , (III-c-1) , (III-c-4) . (III-c-5) , (III-c-6) , (III-c-7) , (III-c-10) or (III-c-11) are preferably used. These compounds for the third component are those with positive dielectric anisotropies of large values, and they are used mainly for a purpose to lower a threshold voltage and a purpose to improve a sharpness which is important as a STN characteristic. As the compounds expressed by the general formulae IV and V, Vl-a, VI-b for the fourth component according to the invention, the following compounds may be preferably mentioned, the following compounds may be preferably mentioned. R X >- R' (,V"5) R-^^COO-^^O ' (IV-8) R- θ - oo-g)-R' (iV _ 9) R- " — θ θC 2 H 4 OR' (IV- 11 ) R -/ ~ Vc H 2 CH 2 -^0^° C 2 H 4 0R' ( IV-12 ) R-^ O - ≡c -X Q - OR' (IV-14) R- θV-CH = CH— ^θ — O ' (IV-17) R-^Q^CF = CF — - O)— R' (IV-18) R O>- O OVR ' (V - 6) N r- e C-5 < < I I < cr t I I I (whrein, R and R' denote each independently an alkyl group. Furthermore, optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by -CH=CH-.) Amongst these fourth components, in particular, compounds expressed by the formulae (IV-1) , (IV-2) , (IV-4) . (IV-5), (IV-6), (IV-7) , (IV-8), (IV-13) , (IV-14) , (IV-18) . (IV-19) or (IV-20) are preferably used as the compounds expressed by the formula (IV) . Furthermore, in particular, compounds expressed by the formulae (V-1) , (V-2) . (V-5), (IV-9) , (V-11) , (V-12) , (V-14) or (V-15) are preferably used as the compounds expressed by the formula (V) . Compounds expressed by the general formulae IV and V, Vl-a, VI-b are those with negative or weak positive dielectric anisotropies. Compounds of the general formula IV are used mainly for purposes to lower a viscosity and/or to controlΔn. Furthermore, compounds of the general formula V are used for a purpose to enlarge a nematic range such as raising of a transparent point and/or for purposes ofΔn control and viscosity control. Compounds of the general formulae Vl-a and VI-b have very high transparent points. Thus, they are used for a purpose to enlarge a nematic range such as raising of a transparent point and/or for a purpose of Δn control. As the compounds expressed by the general formulae VII and VIII according to the invention, the following compounds may be preferably mentioned. . yy yo)- ∞o yy F (Vlll-12) (Vlll-15) coo -yy- c °° yy (Vlll-17) O coo -< ό) -^>- F (Vlll-18) (whrein, R denotes an alkyl group.) As the compounds expressed by the general formula (VII) , in particular, compounds expressed by the formulae (VII-1) , (VII-2) or (VI1-3) are preferably used according to the invention. Furthermore, as the compounds expressed by the general formula (VIII), in particular, compounds expressed by the formulae (VIII-1) , (VIII-5) , (VIII-6), (VIII-7) , (VIII-8). (VIII-9), (VIII-10). (VIII-11) . (VIII-12) , (VIII-13) . (VIII-14) , (VIII-15) , (VIII-16) or (VIII-18) are preferably used according to the invention. Compounds expressed by the general formulae VII and VIII are those with positive dielectric anisotropies and they are used particularly for a purpose to lower a threshold voltage and a purpose to improve a temperature dependency. Furthermore, they are used for purposes of viscosity control, Δn control, and nematic range enlargement such as raising of a transparent point. An amount of the first component used according to the invention is preferably from 3 to 50% by weight based on the total weight of the liquid crystal composition. From 5 to 40% by weight is more preferable. If it being less than 3% by weight, effects of the subjective sharpness and high-speed responce are difficult to be obtained, and if it being above 50% by weight, the threshold voltage of the liquid crystal composition becomes high, which is not desirable. An amount of the second component used is preferably from 3 to 40% by weight. From 4 to 35% by weight is more preferable. If it being less than 3% by weight, effects of the subjective sharpness and high-speed responce are difficult to be obtained, and if it being above 40% by weight, the threshold voltage of the liquid crystal composition becomes high, which is not desirable. An amount of the third component used is preferably from 10 to 60% by weight. If it being less than 10% by weight, the threshold voltage of the liquid crystal composition becomes high, which is not desirable. If it being above 60% by weight, the viscosity of the liquid crystal composition becomes high, which is not desirable. An amount of the fourth component used is preferably from 0 to 60% by weight. From 0 to 50% by weight is more preferable. If it being above 60% by weight, the threshold voltage of the liquid crystal composition becomes high, which is not desirable. An amount of the fifth component used is preferably from 0 to 50% by weight. From 0 to 40% by weight is more preferable. In addition to the compounds expressed by the above-mentioned general formulae I to VIII, the liquid crystal composition according to the invention may contain another compounds for purposes of controlling a threshold voltage, a nematic range, Δn, a dielectric anisotropy and a viscosity etc. , within suitable ranges of amounts not damaging the objects of the invention. As examples of such compounds, the following compounds may be mentioned. In the said compounds, R denotes an alkyl group having from 1 to 10 carbon atoms. R yy {y ~ ° ∞ yy yy • CN R ■ CH 2 CH 2 -yyy- coo ~y5 C R ■ CH 2 CH 2 COO~ < 0 - CN The liquid crystal composition according to the invention is prepared by any of the conventional processes. Generally, there may be used a process to dissolve various components each other at an elevated temperature. Furthermore, the liquid crystal materials of the invention are improved and optimized by means of suitable additives according to their intended applications. The said additives are well-known by the skilled men in the art and described in detail in literatures etc. Generally, a chiral dopant and so on are added in order to derive a spiral structure of liquid crystals and adjust a required twist angle for prevention of reversetwist. Furthermore, the liquid crystal composition to be used according to the invention can be used as a liquid crystal composition for a guest-host (GH) mode with addition of bichromatic dyes such as merocyanine type, styryl type, azo type, azo ethine type, azoxy type, quinophthalone type, anthraquinone type and tetrazine type dyes etc. Alternatively, the composition can be used as a liquid crystal composition for a polymer disperse type liquid crystal display element (PNLCD) , for example, NCAP made by icrocapsulating nematic crystals or a polymer network liquid crystal display element (PNLCD) having three-dimensional network macromolecules made in liquid crystals. In addition, the composition can be used as a liquid crystal composition for a birefringence control (ECB) mode or a dinamic scattering (DS) mode. Examples The present invention will be illustrated in detail by the following Examples, but the invention is not limited by them. Composition ratios in Comparative Examples and Examples are all expressed in % or part by weight. Furthermore, ways to express compounds in Comparative Examples and Examples are according to Table 1. Herein, as to evaluation of a 240° STN cell, a cell thickness d was selected in such a way that the product Δn-d of a cell thickness d and a refractive anisotropyΔn being about 0.85, and a chiral compound was added in such a way that a ratio d/p of a cell thickness d to a pitch p of a liquid crystal composition being about 0.5 and thereafter poured into a cell. Evaluation of a cell was carried out by means of an yellow mode and a voltage-transmittance characteristic (V-T characteristic) was determined by means of a rectangular wave of 70 Hz. A ratio of a voltage V 90 at a transmittance of 90% and a voltage Vio at a transmittance of 10% is evaluated as a sharpness V i 0 /V 90 . Although compounds shown by the following structural formulae were used as chiral compounds, chiral compounds which can be used according to the invention are not limited by them. Tab le 1 Ways to express compounds by use of symbols * C 6 H 13 ' COO- O λ-COO - ■ CcH: -C 6 H 13 I CH 3 Comparative Example 1 A composition A was prepared from the following components: 3-HB-C 24% 5-HB-C 36% 7-HB-C 25% 5-HBB-C 15%. A transparent point of this composition A was TN1=72.4 (°C) , a viscosity at 20 °C was η 20=27.0 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.137, a dielectric anisotropy at 20°C wasΔ ε = 11.0, and a threshold voltage at 20 °C was Vth=1.78(V) . Comparative Example 2 A liquid crystal composition was prepared by mixing 85 parts by wight of the composition A in Comparative Example 1 and 15 parts by weight of a compounds having the following formula contained in the general formula (I) : 3-HH-VFF. A transparent point of this liquid crystal composition was ( °C ) , a viscosity at 20°C was r? 2 o=20.2 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.123, a dielectric anisotropy at 20°C wasΔ ε =9.6, and a threshold voltage at 20 °C was Vth=l.74 (V) . 0.80 parts by weight of a chiral compound C -33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=6.9ura, and the cell was evaluated by mean-i of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage 90 at a transmittance of 90% = 1.95 (V) , a voltage Vι 0 at a transmittance of 10% = 2.50 (V) and a sharpness Example 1 1V2-BEB (F, F) -C 10% 3-HB-C 12% 3-HB-02 6% 5-HH-VFF 20% 3.-HHB-1 7% 3-H2BTB-2 5% 3-H2BTB-3 5% 3-H2BTB-4 4% 1-BHH-VFF 18% 1-BBH-VFF 13% A transparent point of this liquid crystal composition was TNI =100.8 ( °C), a viscosity at 20°C was r? 20 =16.7 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.132, a dielectric anisotropy at 20°C wasΔ ε =8.7, and a threshold voltage at 20 °C was Vth=2.05 (V) . 0.56 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=5.9 urn, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 9 o at a transmittance of 90% = 2.23 (V) , a voltage V10 at a transmittance of 10% = 2.42 (V) and a sharpness V 1 o/V 9 o=l.085. Furthermore, a response time (the sum of a response time from OFF-state to ON-state and a response time from ON-state to OFF-state) was determined at a driving voltage of 27.6V by using a voltage waveform of l/240dutyl/16bias, to obtain iτ (msec) . As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 2 1V2-BEB (F, F) -C 11.5% 3-HB-C 4.5% 3-HB-02 4% 5-HH-VFF 30% 3-HB(F)TB-2 4% 3-H2BTB-2 4% 3-H2BTB-3 4% 3-H2BTB-4 4% 1-BHH-VFF 19.5% 1-BBH-VFF 14.5% A transparent point of this liquid crystal composition was TNI =100.7 ( °C), a viscosity at 20°C was η 20 =16.6 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.132, a dielectric anisotropy at 20°C wasΔ ε =8.0, and a threshold voltage at 20 °C was Vth=2.10(V). 0.51 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=5.9 urn, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.30 (V) , a voltage V10 at a transmittance of 10% = 2.51 (V) and a sharpness Furthermore, a response time (the sum of a response time from OFF-state to ON-state and a response time from ON-state to OFF-state) was determined at a driving voltage of 28.5V by using a voltage waveform of l/240dutyl/16bias, to obtain iτ o a 1 =212 (msec) . As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 3 1V2-BEB (F, F) -C 12.5% 3-HB-C 4% 3-HB-02 5% 5-HH-VFF 30% 3-HHB-l 3.5% 3-HB(F)TB-2 5% 3-HB(F)TB-3 4% 3-HB(F)TB-4 4% 3-H2BTB-2 4% 3-H2BTB-3 4% 3-H2BTB-4 4% 1-BHH-VFF 20% A transparent point of this liquid crystal composition was T N ι=100.4 ( °C) , a viscosity at 20°C was τj 20 =15.1(mPa-s), a refractive anisotropy at 25 °C wasΔn=0.133, a dielectric anisotropy at 20°C wasΔ ε =8.2, and a threshold voltage at 20 °C was Vth=2.06(V) . 0.50 parts by weight of a chiral compound C -33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=5.9 urn, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.24 (V) , a voltage V ) 0 at a transmittance of 10% = 2.44 (V) and a sharpness Vi Furthermore, a response time (the sum of a response time from OFF-state to ON-state and a response time from ON-state to OFF-state) was determined at a driving voltage of 27.9V by using a voltage waveform of l/240dutyl/16bias, to obtain τ 1 0 tai=224 (msec) . As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 4 2-BEB (F) -C 2% 3-BEB (F) -C 1% 4-BEB (F) -C 2% V-HB-C 12% 4-PyB-C 4% 5-PyB-C 3% 4-BB-2 11% 5-HH-V 18% 5-HH-VFF 4% 5-HH-VF 2% V-HHB-1 7% V2-HHB-1 15% 3-HHB-02V 4% 2-BBH-VF 3% 1-BBH-VFF 3% 1V2-HBB-2 4% 3-HHEBH-3 2.5% 3-HHEBH-4 2.5% A transparent point of this liquid crystal composition was T N I =100.0 ( °C). a viscosity at 20°C was η 20 =17.8 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.135, a dielectric anisotropy at 20°C wasΔ ε =7.8, and a threshold voltage at 20 °C was Vth=2.09(V). 0.60 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=5.9um, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.34 (V) . a voltage Vio at a transmittance of 10% = 2.55 (V) and a sharpness V l o /V 9O =1.090. As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 5 1V2-BEB (F, F) -C 13% V2V-HB-C 10% V2V-HB-1 5% V2V-HH-1 10% V2V-HH-3 10% 3-HH-1VFF 2% 3-HH-2VFF 2% 3-HH-VF 2% 3-HHB-l 5% V2V-HHB-1 13% 1-BHH-VFF 2% V2V-HBB-1 14% 1-BBH-2VF 2% 3-H2BTB-2 5% 3-H2BTB-3 5% A transparent point of this liquid crystal composition was T N ι = 101.0 (°C) , a viscosity at 20°C was r? 20 =16.0 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.132, a dielectric anisotropy at 20°C wasΔ ε =8.4, and a threshold voltage at 20 °C was Vth=2.06(V). 0.58 parts by weight of a chiral compound C -33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=5.9μm, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V90 at a transmittance of 90% = 2.28(V) , a voltage Vio at a transmittance of 10% = 2.49 (V) and a sharpness Vi o/V 9 o=l.092. Furthermore, a response time (the sum of a response time from OFF-state to ON-state and a response time from ON-state to OFF-state) was determined at a driving voltage of 28.2V by using a voltage waveform of l/240dutyl/16bias, to obtain τ to ta ι =232 (msec) . As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 6 1V2-BEB (F, F) -C 8% 3-HB-C 24% 3-HB-02 4% 3-HH-4 10% 3-HH-5 3% 5-HH-VFF 2% 3-HH-VF 2% 5-HH-2 2% 3-HHB-l 10% 3-HHB-3 7% 3-H2BTB-2 5% 3-H2BTB-3 4% 3-H2BTB-4 4% 1-BBH-VFF 2% 1-BBH-3VF 2% V2V-HBB-1 11% A transparent point of this liquid crystal composition was TNI =100.3 (°C) , a viscosity at 20°C was T? 20 =17.3 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.13l, a dielectric anisotropy at 20°C wasΔ =8.9, and a threshold voltage at 20 °C was Vth=2.06(V). 0.60 parts by weight of a chiral compound C -33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=5.9μm, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V90 at a transmittance of 90% = 2.30 (V) , a voltage V10 at a transmittance of 10% = 2.51 (V) and a sharpness As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 7 1V2-BEB(F,F)-C 8% 3-HB-C 21% 3-HB-02 4% 3-HH-4 11% 3-HH-5 3% 3-HH-VFF 2% 5-HH-VFF 2% 3-HHB-l 12% 3-H2BTB-2 4% 3-H2BTB-3 4% 3-H2BTB-4 4% 3-HB(F)TB-2 5% 3-HB(F)TB-3 5% 1-BHH-VFF 15% A transparent point of this liquid crystal composition was T N I =101.8 (°C) , a viscosity at 20°C was n 2 o=15.9 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.133, a dielectric anisotropy at 20°C wasΔ =8.2, and a threshold voltage at 20 °C was Vth=2.10(V) . 0.59 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=5.9um, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.32 (V) , a voltage Vι 0 at a transmittance of 10% = 2.51 (V) and a sharpness V,o/V β o=1.082. As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 8 1V2-BEB (F, F) -C 8% 3-HB-C 22% 3-HB-02 4% 3-HH-4 11% 3-HH-5 2% 3-HH-VF 2% 5-HH-VFF 2% 3-HHB-l 10% 3-HHB-3 10% 3-H2BTB-2 5% 3-H2BTB-3 5% 3-H2BTB-4 4% 1-BHH-VFF 15% A transparent point of this liquid crystal composition was TNI=100.7 (°C) , a viscosity at 20°C was η 20 =16.6 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.132, a dielectric anisotropy at 20°C wasΔ ε =8.5, and a threshold voltage at 20 °C was Vth=2.07(V) . 0.63 parts by weight of a chiral compound C -33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d-5.9μm, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.24 (V) , a voltage V ι 0 at a transmittance of 10% = 2.46 (V) and a sharpness As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 9 1V2-BEB (F, F) -C 8% 3-HB-C 24% 3-HB-02 5% 3-HH-4 10% 3-HH-5 2% 3-HH-VF 2% 3-HH-2VFF 2% 3-HHB-3 16% 3-HB(F)TB-2 5% 3-HB(F)TB-3 4% 3-H2BTB-2 4% 3-H2BTB-3 4% 3-H2BTB-4 4% V2V-HHB-1 6% 1-BHH-VFF 4% A transparent point of this liquid crystal composition was T N ι =101.1 (°C) , a viscosity at 20°C was η 2 o=16.5 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.133, a dielectric anisotropy at 20°C wasΔ =7.9, and a threshold voltage at 20 °C was Vth=2.11 (V) . 0.64 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic! was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.34 (V) , a voltage V [ 0 at a transmittance of 10% = 2.56 (V) and a sharpness As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 10 A liquid crystal composition consisting of the following components was prepared: 3-HH-VFF 9% 5-HH-VFF 16% 2-HB-C 11% 3-HB-C 17% 2-HHB-C 5% 3-HHB-C 5% 4-HHB-C 5% 5-HHB-C 5% 1-BHH-VFF 5% 2-BFVFB-2 5% 3-BFVFB-3 5% 4-BFVFB-4 5% 5-BFVFB-5 7%. A transparent point of this liquid crystal composition was T N 1 =87.6 ( °C), a viscosity at 20°C was 77 20 =14.0 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.134, a dielectric anisotropy at 20°C wasΔ =7.2, and a threshold voltage at 20 °C was Vth=2.03(V) . 0.85 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=6.4um, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.25 (V) , a voltage V ι0 at a transmittance of 10% = 2. 2 (V) and a sharpness As compared with compositions in Comparative Examples 1 and 2 , the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 11 A liquid crystal composition consisting of the following components was prepared: 3-HH-VFF 12% 5-HH-VFF 19% 2-HB-C 6% 3-HB-C 18% 2-HHB-C 5% 3-HHB-C 6% 4-HHB-C 5% 5-HHB-C 5% 2-BTB-01 4% 3-BTB-01 4% 4-BTB-01 4% 4-BTB-02 4% 5-BTB-01 4% 1-BHH-VFF 4%. A transparent point of this liquid crystal composition was T N ι=85.3( °C), a viscosity at 20°C was r? 20 =16.0 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.133, a dielectric anisotropy at 20°C wasΔ ε =6.5, and a threshold voltage at 20 °C was Vth=2.03(V) . 0.80 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=6.4u m, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V ~ T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.24 (V) , a voltage V ι 0 at a transmittance of 10% = 2.37 (V) and a sharpness Vιo/V βo =1.054. As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 12 A liquid crystal composition consisting of the following components was prepared: 3-HH-VFF 8% 5-HH-VFF 12% 3-HB-C 10% V2-HB-C 14% 1V2-HB-C 14% 2-BTB-01 9% 3-HHB-l 4% 1-BHH-1VFF 2% 1-BHH-2VFF 2% 3-HHB-01 3% 3-HB(F)TB-2 5% 3-HB(F)TB-3 5% 3-H2BTB-2 4% 3-H2BTB-3 4% 3-H2BTB-4 4% A transparent point of this liquid crystal composition was T N (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.153, a dielectric anisotropy at 20°C wasΔ ε =6.0, and a threshold voltage at 20 °C was Vth=2.29(V) . 0.85 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=5.5/ m, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.45(V) , a voltage V ι0 at a transmittance of 10% = 2.53 (V) and a sharpness As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 13 A liquid crystal composition consisting of the following components was prepared: 5-HH-VFF 13% 3-HB-C 15% V2-HB-C 8% 1V2-HB-C 7% 3-PyBB-F 6% 2-BTB-l 7.25% l-BTB-6 14.5% 4-BTB-4 7.25% 3-HHB-l 2% 1-BHH-3VFF 2% 1-BHH-1VF 2% 3-H2BTB-2 4% 3-H2BTB-3 4% 3-H2BTB-4 4% 3-HB(F)TB-2 4% A transparent point of this liquid crystal composition was T N ι=70.0( °C), a viscosity at 20°C was η 2 o=15.9 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.170, a dielectric anisotropy at 20°C wasΔ ε =5.5, and a threshold voltage at 20 °C was Vth=2.01(V). 1.09 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.11(V) , a voltage Vι 0 at a transmittance of 10% = 2.41 (V) and a sharpness As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 14 A liquid crystal composition consisting of the following components was prepared: 5-HH-VFF 13% 3-HH-1VF 2% V2-HB-C 8% 1V2-HB-C 8% 1V2-BEB (F, F) -C 9% 5-PyB-F 8% 3-HHB-F 5% 3-HHB-01 5% 3-HHB-l 8% 3-HHB-3 13% 1-BHH-2VF 2% 1-BHH-3VF 2% 3-HB(F)TB-2 5% 3-H2BTB-2 4% 3-H2BTB-3 4% 3-H2BTB-3 4% A transparent point of this liquid crystal composition was T N ι=101.7 (°C) , a viscosity at 20°C was 77 20 =17.0 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.133, and a threshold voltage at 20 °C was Vth=2.00(V) . 0.59 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=6.4ura, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.19 (V) , a voltage Vj 0 at a transmittance of 10% = 2.34 (V) and a sharpness As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 15 A liquid crystal composition consisting of the following components was prepared: 5-HH-VFF 13% 3-HH-2VF 2% 3-HB-C 17% 1V2BEB(F,F)-C % 3-HHB-F 5% 3-PyB-2 4% 3-HB-02 5% 3-HHB-01 2% 3-HHB-l 8% 3-HHB-3 15% 1-BHH-VFF 2% 1-BBH-1VFF 2% 3-H2BTB-2 3% 3-H2BTB-3 3% 3-H2BVB-3 4% 3-HB(F)TB-2 7% A transparent point of this liquid crystal composition was T N i =101.5 (°C) , a viscosity at 20°C was 77 20 =16.2 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.130, and a threshold voltage at 20 °C was Vth=2.07(V). 0.55 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=6.5μm, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.19 (V) , a voltage V ! 0 at a transmittance of 10% = 2.36 (V) and a sharpness As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 16 A liquid crystal composition consisting of the following components was prepared: 3-HH-VFF 14% 5-HH-VFF 15% 3-HH-3VF 2% 3-H2B-C 4% 3-HB-C 6% 1V2-BEB(F,F)-C 10% 2-BTB-01 10% 4-BTB-02 5% 5-BTB-01 5% 3-HHB-l 6% 3-HHB-01 4% 3-HHB-3 12% 1-BHH-VFF 2% 1-BHH-VF 2% 3-H2BTB-2 3% A transparent point of this liquid crystal composition was 12.9 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.133, a dielectric anisotropy at 20°C wasΔ ε =6.5, and a threshold voltage at 20 °C was Vth=1.93(V). 0.82 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% = 2.15(V) , a voltage V ] 0 at a transmittance of 10% = 2.30 (V) and a sharpness V lo /V 9o =1.070. Example 17 A liquid crystal composition consisting of the following components was prepared: 5-HH-2VFF 10% 3-HH-3VFF 2% 2-BB-C 8% 4-BB-C 8% 5-BB-C 8% 2-HB-C 6% 3-HHB-C 8% 3-PyB(F)-F 5% 3-HHB-F 4% 3-HBEB-F 4% 3-HB-02 4% 101-HH-3 4% 3-HH-4 4% 2-HHB-l 2% 3-HHB-l 3% 3-HHB-01 3% 3-HHB-3 13% 1-BHH-VFF 2% 1-BHH-VF 2% A transparent point of this liquid crystal composition was T N I =76.0 ( °C), a viscosity at 20°C was 77 20 =19.6 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.120, a dielectric anisotropy at 20°C wasΔ ε =7.2, and a threshold voltage at 20 °C was Vth=1.79(V) . 0.80 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=7.0um, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% =1.92 (V) , a voltage V i0 at a transmittance of 10% = 2.09 (V) and a sharpness Vi 0 /V 90 =l.089. Example 18 A liquid crystal composition consisting of the following components was prepared: 5-HH-1VFF 10% 3-PyB(F)-F 10% 3-HB(F)-C 8% 3-HH-4 7% 2-PyB-2 4% 3-PyB-2 4% 4-PyB-2 4% 2-HHB-C 4% 3-HHB-C 6% 2-HHB(F)-F 7% 3-HHB(F)-F 7% 5-HHB(F)-F 7% 3-HHB-l 4% 1-BHH-VFF 4% 3-HHB-01 4% 3-PyBB-F 5% 4-PyBB-F 5% A transparent point of this liquid crystal composition was T N ι=75.8( °C), a viscosity at 20°C was 77 20 =18.5 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.110, a dielectric anisotropy at 20°C wasΔ ε =7.8, and a threshold voltage at 20 °C was Vth=1.70(V) . 0.78 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=7.5μm, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% =1.86 (V) , a voltage Vι 0 at a transmittance of 10% = 2.03 (V) and a sharpness Vi 0 /V 90 =l.091. Example 19 A liquid crystal composition consisting of the following components was prepared: 3-HH-VFF 7% 5-HH-VFF 7% 201-BEB (F) -C 8% 301-BEB (F) -C 8% 2-HB(F)-C 7% 2-HHB(F)-F 12% 3-HHB(F)-F 12% 5-HHB(F)-F 12% 2-HBB(F)-F 2% 3-HBB(F)-F 2% 1-BBH-2VFF 2% 1-BBH-3VFF 2% 3-PyBB-F 4% 3-H2BTB-2 3% 3-H2BTB-3 3% 3-H2BVB-3 3% 3-HB(F)TB-2 3% 3-HB(F)TB-2 3% A transparent point of this liquid crystal composition was TNI=85.3( °C) , a viscosity at 20°C was τ 20 =23.2 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.125, a dielectric anisotropy at 20°C wasΔ ε =10.8, and a threshold voltage at 20°C was Vth=1.43(V) . 0.80 parts by weight of a chiral compound C -33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=6.9μm, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% =1.50(V), a voltage Vio at a transmittance of 10% = 1.64 (V) and a sharpness V, 0 /V 90 =l.093. Example 20 A liquid crystal composition consisting of the following components was prepared: 4-HH-VFF 6% 5-HH-VFF 7% 2-BEB-C 5% 3-HB-C 10% 101-HB-C 6% 3-HEB-04 6% 5-HEB-01 6% 4-HEB-3 6% 4-HEB-4 6% 3-HHEB(F,F)-F 4% 3-HHEB-F 4% 3-HBEB(F,F)-F 4% 3-HBEB-F 4% 2-HHB(F)-F 4% 3-HHB(F)-F 4% 5-HHB(F)-F 4% 1-BBH-VF 2% 1-BBH-1VF 2% 3-PyBB-F 3% 4-PyBB-F 3% 5-PyBB-F 4% A transparent point of this liquid crystal composition was TNI=80.6 ( °C), a viscosity at 20°C was 77 20 =24.0 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.110, a dielectric anisotropy at 20°C wasΔ ε =7.5, and a threshold voltage at 20 °C was Vth=1.6Q(V) . 0.48 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then pour e d into a 240 ° STN cell having a thickness of d=7.5μm, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 9 o at a transmittance of 90% =1.74 (V) , a voltage V10 at a transmittance of 10% = 1.89 (V) and a sharpness V t 0 /V 90 =l.086. Example 21 A liquid crystal composition consisting of the following components was prepared: 3-HH-VFF 6% 5-HH-VFF 8% 201-BEB (F) -C 8% 301-BEB (F) -C 8% 2-HB(F)-C 7% 2-HHB(F)-F 13% 3-HHB(F)-F 12% 5-HHB (F) -F 11% 2-HBB(F)-F 2% 3-HBB(F)-F 2% 1-BBH-2VFF 2% 1-BBH-3VFF 2% 3-PyBB-F 4% 3-H2BTB-2 2% 3-H2BTB-3 2% 3-H2BVB-3 3% 101-HBB (F) H-3 2% 3-HB(F)TB-2 3% 3-HB(F)VB-2 3% A transparent point of this liquid crystal composition was TN ( °C) , a viscosity at 20°C was 23.9 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.126, a dielectric anisotropy at 20°C wasΔ ε =11.0, and a threshold voltage at 20°C was Vth=1.45(V) . 0.80 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=6.9μm, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% =1.52 (V) , a voltage Vι 0 at a transmittance of 10% = 1.66 (V) and a sharpness V1 0 /V 90 =1.092. Example 22 A liquid crystal composition consisting of the following components was prepared: 5-HH-VFF 13% 3-HB-C 16% V2-HB-C 7% 1V2-HB-C 7% 3-PyBB-F 6% 2-BTB-l 7.2% l-BTB-6 14.5% 4-BTB-4 7.3% 3-HHB-l 2% 1-BHH-3VFF 2% 1-BHH-1VF 2% 3-H2BTB-2 4% 3-H2BTB-3 4% 3-H2BTB-4 3% 3-HB(F)TB-2 3% 3-HHEBH-3 2% A transparent point of this liquid crystal composition was T N i =70.8 ( °C), a viscosity at 20°C was 77 20 =16.3 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.169, a dielectric anisotropy at 20°C wasΔ ε =5.6, and a threshold voltage at 20 °C was Vth=2.03(V) . 1.09 parts by weight of a chiral compound C -33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=5.0μm, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% =2.13 (V) , a voltage V10 at a transmittance of 10% = 2.44 (V) and a sharpness V 10 /V 90 =l.146. As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Example 23 A liquid crystal composition consisting of the following components was prepared: 3-HH-VFF 9% 5-HH-VFF 11% 3-HB-C 9% V2-HB-C 15% 1V2-HB-C 14% 2-BTB-01 9% 3-HHB-l 4% 1-BHH-1VFF 2% 1-BHH-2VFF 2% 3-HHB-01 3% 3-HB(F)TB-2 5% 3-HB(F)TB-3 5% 3-H2BTB-2 3% 3-H2BTB-3 3% 3-H2BTB-4 4% 3-HBBH-5 2% A transparent point of this liquid crystal composition was T N ι=90.9( °C), a viscosity at 20°C was 77 2 o=15.7 (mPa-s) , a refractive anisotropy at 25 °C wasΔn=0.154, a dielectric anisotropy at 20°C wasΔ ε =6.0, and a threshold voltage at 20 °C was Vth=2.30(V) . 0.86 parts by weight of a chiral compound CM-33 was added to 100 parts by weight of this liquid crystal composition to prepare a composition, which was then poured into a 240 ° STN cell having a thickness of d=5.5μm, and the cell was evaluated by means of an yellow mode. A voltage - transmittance characteristic (V-T characteristic) was determined by a rectangular wave of 70 Hz, to obtain a voltage V 90 at a transmittance of 90% =2.47 (V) , a voltage V i0 at a transmittance of 10% = 2.55 (V) and a sharpness Vi 0 /V 90 =1.032. As compared with compositions in Comparative Examples 1 and 2, the transparent point became high and the viscosity became low. Furthermore, the sharpness was more improved than the compositon in the Comparative Example 2. Effects of the Invention As shown by Examples, a liquid crystal co psition which satisfies various characteristics required for a STN display mode and also which is superior in a voltage - transmittance characteristic (a sharpness) necessary for corresponding particularly to coloring, as well as a liquid crystal composition with a low viscosity necessary for corresponding to a high-speed response can be proposed according to the invention.

Claims: C L A I S 1. A liquid crystal composition characterized in that at least one compound expressed by the general formulae I-a and I-b (wherein, R 1 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH Z -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the first component, at least one compound expressed by the general formulae II-a, Il-b, II-c and Il-d (wherein, R 1 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (~CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the second component, and one or more than one compound (s) selected from the group of compounds expressed by the general formulae III-a, Ill-b and III-c R 2 -(- y-)—(A 2 )-z°-/θ N (Ill-b) ) m —(A 3 )-Z'- O>- N (III-c) (wherein, R 2 denotes an alkyl group having from 1 to 10 carbon atom(s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, Z° denotes -COO- or -CH 2 CH 2 -, V denotes -CH 2 CH 2 -, -C00- or a single bond, Q 1 denotes H or F, Al denotes trans-1,4- cyclohexylene, 1 , 4-phenylene or 1 , 3 ~ dioxane-2, 5-diyl, A 2 and A 3 denote each independently trans-1, 4-cyclohexylene or 1,4- phenylene, and p, q and m each independently denote 0 or 1.) is contained as the third component. 2. A liquid crystal composition according to Claim 1, characterized in that the first component is from 3 to 50% by weight, the second component is from 3 to 40% by weight and the third component is from 10 to 60% by weight, all based on the total weight of the liquid crystal composition. 3. A liquid crystal composition characterized in that at least one compound expressed by the general formulae I-a and I-b R 1 (CH 2 ) n - -CH=CHF (l-b) (wherein, R 1 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the first component, at least one compound expressed by the general formulae Il-a, I l -b , I I - c and I l -d R, R 1 — o)— y— yy ~ (cH2)n — CH==CHF (Il-b) R' - θ) (5) (y —(Crl 2 )s— CH = CHF (ll-d) (wherein, R l denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom(s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the second component, one or more than one compound (s) selected from the group of compounds expressed by the general formulae 111-a. III-b and III-c (Ill-a) (wherein, R 2 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, Z° denotes -COO- or -CH 2 CH 2 -, V denotes -CH 2 CH 2 -, -C00- or a single bond, Q' denotes H or F, Al denotes trans-1,4- cyclohexylene, 1.4-phenylene or 1, 3-dioxane-2, 5-diyl, A 2 and A 3 denote each independently trans-1 , 4-cyclohexylene or 1,4- phenylene, and p, q and m each independently denote 0 or 1.) is contained as the third component, and at least one or more than one compound (s) selected from the group of compounds expressed by the general formulae IV and V, Vl-a and Vl-b R 3 -(B)-Z Z -(C)-R 4 (IV) (wherein, R 3 and R 4 denote each independently an alkyl group having from 1 to 10 carbon atom(s), optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above- mentioned groups may be substituted by (an) oxygen atom (s) and -CH=CH- in all cases, B denotes trans-1, 4-cyclohexylene, pyrimidine-2, 5-diyl or 1, 4-phenylene, C denotes trans-1,4- cyclohexylene or 1, 4-phenylene, and Z 2 denotes -C≡C-, -C00-, -CH 2 CH 2 -, -CH=CH-, -CF=CF- or a single bond.) , R S -(D)-Z 3 -(E)-Z 4 -(G)-R 6 (V) (wherein, R 5 denotes an alkyl group having from 1 to 10 carbon atom(s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, R 6 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atom(s), D denotes trans-1, 4-cyclohexylene or pyrimidine-2, 5-diyl, E denotes trans- 1, 4-cyclohexylene or 1, 4-phenylene in which one H at a branched position may be optionally substituted with F, G denotes trans- 1, 4-cyclohexylene or 1, 4-phenylene, Z 3 denotes -CH 2 CH 2 - or a single bond, and Z 4 denotes -C≡C-, -COO- or -CH=CH- or a single bond. ) , 7 O (vi-a) R' COO- O - R 8 (Vl-b) (wherein, R 7 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom(s) (-0-) and -CH=CH- in all cases, R 8 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atom(s), and Q 2 denotes H or F. ) is contained as the fourth component. 4. A liquid crystal composition according to Claim 3. characterized in that the first component is from 3 to 50% by weight, the second component is from 3 to 40% by weight, the third component is from 10 to 60% by weight, and' the fourth component is from 1 to 60% by weight, all based on the total weight of the liquid crystal composition. 5. A liquid crystal composition characterized in that at least one compound expressed by the general formulae I-a and I-b (wherein, R 1 denotes an alkyl group having from 1 to 10 carbon atom(s), optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the first component, at least one compound expressed by the general formulae II-a, I l -b , I I - c and I l - d ■ -<O>- -0- <CH *- -CH = CF, (ll-a) (wherein. R 1 denotes an alkyl group having from 1 to 10 carbon atom(s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, and n denotes an integer of from 0 to 20.) is contained as the second component, one or more than one compound (s) selected from the group of compounds expressed by the general formulae 111-a, Ill-b and III-c (wherein, R 2 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, Z° denotes -COO- or -CH 2 CH 2 -, V denotes -CH 2 CH 2 -, -C00- or a single bond, Q l denotes H or F, A 1 denotes trans-1,4- cyclohexylene, 1, 4-phenylene or 1, 3-dioxane-2, 5-diyl, A 2 and A 3 denote each independently trans-1, 4-cyclohexylene or 1,4- phenylene, and p, q and m each independently denote 0 or 1.) is contained as the third component, at least one or more than one compound (s) selected from the group of compounds expressed by the general formulae IV and V, Vl-a and Vl-b R 3 -(B)-Z 2 -(C)-R 4 (IV) (wherein, R 3 and R 4 denote each independently an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above- mentioned groups may be substituted by (an) oxygen atom(s) and -CH=CH- in all cases, B denotes trans-1, 4-cyclohexylene, pyrimidine-2, 5-diyl or 1, 4-phenylene, C denotes trans-1,4- cyclohexylene or 1, 4-phenylene, and Z 2 denotes -C≡C-, -C00-, -CH 2 CH 2 -,-CH=CH-. -CF=CF- or a single bond.) , R S -(D)-Z 3 -(E)-Z 4 -(G)-R 6 (V) (wherein, R 5 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non-adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom (s) (-0-) and -CH=CH- in all cases, R 6 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atom (s) , D denotes trans-1, 4-cyclohexylene or pyrimidine-2, 5-diyl, E denotes trans- 1, 4-cyclohexylene or 1, 4-phenylene in which one H at a branched position may be optionally substituted with F, G denotes trans- 1, 4-cyclohexylene or 1, 4-phenylene, Z 3 denotes -CH 2 CH 2 - or a single bond, and Z" denotes -C≡C-, -COO- or -CH=CH- or a single bond. ) , (wherein, R 7 denotes an alkyl group having from 1 to 10 carbon atom (s) , optional one or non- " adjacent two or more than two methylene group (s) (-CH 2 -) in the above-mentioned groups may be substituted by (an) oxygen atom(s) (-0-) and -CH=CH- in all cases, R 8 denotes an alkyl group, an alkoxy group or an alkoxymethyl group having from 1 to 10 carbon atom(s) , and Q z denotes H or F.) is contained as the fourth component, and at least one or more than one compound (s) selected from the group consisting of compounds expressed by the general formulae VII and VIII (wherein, R 9 denotes an alkyl group having from 1 to 10 carbon atom(s), Q 3 denotes H or F, and k denotes 0. or 1) , (wherein, R 10 denotes an alkyl group having from 1 to 10 carbon atom(s) , J denotes trans-1, 4-cyclohexylene or 1, 4-phenylene, Q 4 and Q 5 denote each independently H or F, Z 5 and Z 6 denote each independently -COO- or a single bond, and h denotes 0, 1 or 2.) as the fifth component. 6. A liquid crystal composition according to Claim 5, characterized in that the first component is from 3 to 50% by weight, the second component is from 3 to 40% by weight, the third component is from 10 to 60% by weight, the fourth component is from 1 to 60% by weight, and the fifth component is from 1 to 50% by weight, all based on the total weight of the liquid crystal composition. 7. A liquid crystal display element comprising a liquid crystal composition according to any of Claims 1 to 6.

Inventors: MATSUSHITA TETSUYA, MURAOKA TOSHIHIKO, MURASHIRO KATSUYUKI, NAKAGAWA ETSUO, TAKESHITA FUSAYUKI, MATSUSHITA, TETSUYA, MURAOKA, TOSHIHIKO, MURASHIRO, KATSUYUKI, NAKAGAWA, ETSUO, TAKESHITA, FUSAYUKI
Applicants: CHISSO CORP, MATSUSHITA TETSUYA, MURAOKA TOSHIHIKO, MURASHIRO KATSUYUKI, NAKAGAWA ETSUO, TAKESHITA FUSAYUKI, CHISSO CORPORATION, MATSUSHITA, TETSUYA, MURAOKA, TOSHIHIKO, MURASHIRO, KATSUYUKI, NAKAGAWA, ETSUO, TAKESHITA, FUSAYUKI
Application year: 1997
Main classification: C09K19
IPC codes: C09K19, G02F1