Aroma powder and process for its production

Abstract: The invention provides an aroma powder based on an alcohol-containing liquid, in particular a wine powder, which, when used in foods, in particular soups, sauces and desserts, gives rise to the same flavour impression as the addition of the underlying alcohol-containing liquid. The aroma powder displays little taste of its own, is readily free-flowing and meterable, particularly in the dry form, and is non-hygroscopic or only slightly hygroscopic. The aroma powder contains aroma-active constituents of an alcohol-containing liquid and, as a carrier for the aroma-active constituents, a high-amylose starch product, in particular pea starch and pea amylose.

Description: Alcohol-containing liquids such as spirits and, in particular, wine are traditionally used in cuisine for enriching or producing special foods. Known examples include Burgundy sauce, Riesling sauce or Madeira sauce. Just as in soups and sauces, alcoholic beverages are also used with desserts (e.g. in zabaione or tiramisu). Both the alcohol and, particularly, the aroma-active constituents of the alcoholic beverages are relatively volatile, and wine and spirits are therefore generally not added to the foods until the end of the preparation. Nevertheless, even in these traditional applications, sometimes quite considerable aroma and flavour losses are unavoidable. In particular in the production of dry products, the volatility of the aroma-active constituents represents a great difficulty. Using wine as an example, these difficulties may be readily demonstrated. In the case of wine, flavour and aroma are composed in principle of three basic elements, a characteristic bouquet of predominantly highly volatile aroma substances, a likewise characteristic basic taste due to non-volatile constituents and characterized inter alia by sugar and organic acids, and finally the alcohol content. The composition of these basic elements determines the type, and their balance the quality, of the wine in question. Accordingly, in principle, in a wine powder, these three basic elements should be present not only in a sufficiently high concentration typical of the wine in question, but they should also be present in a balanced ratio which goes to make up high quality. Retaining the volatile aroma substances during drying is difficult enough, but it is particularly difficult in the presence of a highly volatile constituent which is present, moreover, in a great excess, in this case alcohol. This is a considerable reason as to why wine powders of satisfactory quality have been virtually unavailable to date. There have been a number of attempts to produce aroma powders from alcohol-containing liquids. Thus, the publications "Alcoholic Powders - Characteristics and Applications", Circle 214 (1977) 18, DE-A 32 14 321, JP-B 72 03 93 55, JP-A 57 09 11 87, JP-A 57 08 62 83, JP-A 57 13 28 76, JP-A 57 12 27 88, JP-A 49 64460 and US-A-3, 786159 disclose various carriers which have differing effects on individual aroma compounds. However, in these publications, aroma powders are generally proposed which are said to have a particularly high alcohol content. Thus, DE-A 32 14 321 proposes as carrier a hydrolysed starch (maltodextrin), which is dried together with a 1:0.75 mixture of red wine and a 95% strength alcohol. The products described there are also suitable, because of the high alcohol content, as beverage powders, preservatives and additives for pharmaceutical products and cosmetic products. These alcohol-rich powders are less suitable as aroma powders for soups and sauces or desserts, since they have only slight aroma stability and sometimes have a high hygroscopicity and therefore require air-tight packages. In the case of aroma substances for soups, sauces and desserts, it is not essentially the alcohol content of the aroma powder which is important, the majority of which in any case evaporates during cooking, but, rather, a balanced and characteristic taste and aroma profile. Economic production, for example of a wine powder, is also only possible if the alcohol can be recovered as completely as possible. Therefore, the production of an aroma-intensive wine powder also includes a very highly selective separation of alcohol and aroma substances. This means, as far as the carrier is concerned: a retention capacity as high as possible for the aroma substances and a low retention capacity for the alcohol. Although polymeric carbohydrates such as starches and dextrins have been studied in the prior art for their suitability as carriers for aroma powders, such as in "Influence of cellulose and starch on the retention of volatiles during freeze-drying of a liquid extract of mushroom", Lebensmittel Wissenschaft und Technik, 8: 174-176; (1975) and "Studies on mechanisms of retention of volatile in freeze-dried food models: The system PVP-n-propanol", J. Food Science 38: 671-674; (1973), they have been considered to date as not very suitable for the production of dry aromas. Starch hydrolysates (maltodextrins of different degrees of hydrolysis) have also been previously proposed as carriers for aroma powders, but in this case also only for powders having high alcohol contents, as in DE-A 32 14 321. In the case of the aroma powders produced in the prior art, it is also frequently necessary to add additional aromas afterwards, and some processes for the production of aroma powders from alcohol-containing liquids require the use of liquids having a decreased alcohol content. Both of these are unfavourable from the economic aspect and do not give a product having outstanding flavour properties. More recent highly effective processes for aroma encapsulation (for cold extrusion) are suitable, for example, for the encapsulation of essential oils, but not for the production of wine powders because of the high water and alcohol contents. An object of the invention is therefore to provide an aroma powder, in particular a wine powder, which, when used in foods such as, in particular, soups, sauces and desserts, gives rise to the same flavour impression as the addition of the underlying alcohol-containing liquid. The aroma powder should have as little as possible taste of its own, be readily free-flowing and meterable, particularly in the dry form, and be non-hygroscopic, or only slightly hygroscopic. The solution of this object is based on the surprising finding that amylose and thus including, in particular, high-amylose starches such as pea starch and modified high-amylose starches, in contrast to conventional modified or non-modified starches, have an outstanding retention capacity for aroma substances and a very low retention capacity for alcohol. When the carriers of the invention are used, it is not necessary to add aroma substances additionally to the aroma powder. The invention therefore provides an aroma powder, a process for its production and a use for this aroma powder. The aroma powder of the invention contains a carrier and aroma-active constituents of an alcohol-containing liquid, the carrier being a high-amylose starch product. The aroma powder is preferably a wine powder. However, aroma powders based on whisky, calvados, cider etc. are also provided according to the invention. The high-amylose starch has at least about 30% amylose, more preferably 34% amylose. The high-amylose starch can be used as such, but it can alternatively be subjected to a slight acid degradation (modification) to decrease the viscosity. The degree of modification is not essential according to the invention and can be set separately for each individual case. However, it is preferred that the degradation by acid hydrolysis is carried out to an extent such that the viscosity is decreased to at least 1/3 of the original viscosity. Further or complete degradation to monomers or oligomers, as is the case in the production of maltodextrins and in which the amylose character is lost, must not occur, however. The use of chemically modified high-amylose starch is also possible. The possibilities of chemically modifying starches for use in aroma powders are known in the prior art. Starch products having an amylose content increased subsequently are also usable, thus, for example, including pure or modified amylose. Preference is given according to the invention to pea starch or pea amylose. The alcohol content of the aroma powder of the invention is less than the alcohol content of the underlying alcohol-containing liquid and, in the case of a wine powder, is preferably less than 10%, more preferably less than 5%, and in particular less than 1%. The aroma powders of the invention may be used in any foods, but preferably in soups, sauces and desserts. The powders of the invention may generally be used in the same manner as the degelatinized starches frequently used in dry products. The aroma powders of the invention can be prepared by processes conventional in the prior art. In a first step, a starch paste is produced from starch and the alcohol-containing liquid, which starch paste is then dried in a second step. The drying process is not critical, but should preferably not be carried out at elevated temperature. If the viscosity of the starch paste permits, the drying can be performed, for example, by spray-drying. However, preferably, the aroma powders of the invention are not produced by spray-drying but by freeze-drying. The ratio between the carrier used and the amount of the alcoholic beverage used depends on the specific alcoholic beverage and the specifically selected carrier. Generally, the amount of the carrier is about 2 to about 50% of the alcohol-containing liquid, preferably 5 to 30%, and in particular 10 to 20%. The amount of aroma powder which is added to the respective foods depends on the respective products and it is not possible to state a general range. Frequently, an addition in the order of magnitude of 1% is suitable. The following examples illustrate the invention. Example 1 : 100 g of pea starch are gelatinized by heating in 900 ml of white wine (Niederkirchner Riesling, Palatinate) and the starch paste thus obtained is freeze-dried after cooling. Corresponding wine powders were produced from maize and waxy maize starch from the same wine and in the same manner. Table 1 shows the sensory evaluation of the resulting products (2.5 g of each in 250 ml of a brown sauce) and the contents of ethyl isobutyrate and ethyl butyrate in the wine powder as indicator substances for aroma retention. As a comparison, commercial powders are also used. The commercial powder 1 is a white wine powder from the Sato company, which essentially corresponds to a powder according to the prior art discussed at the outset of the description. It contains 60% sugar as carrier and has an alcohol content of 30%. The white wine powder 2 is the powder FIS IS 21 21, the carrier comprises 91.5% maltodextrin, the alcohol content is 1.3% and the powder has 4% white wine extract. Sensory evaluation Ethyl butyrate content [µg/kg] iso- n- Maize starch very weak, as after extended cooking; <10 <10 Waxy maize starch weak, but somewhat more acidic; <10 <10 Pea starch fruity, typical as of freshly added wine 215 108 Commercial powder I weak, not very typical 10 24 Commercial powder II flat, but still having wine character 84 103 The example shows that markedly improved sensory quality and aroma retention were achieved not only in comparison with other starches but also in comparison with commercial white wine powders. Example 2 : Red wine powders were produced from maize, waxy maize and pea starch in the same manner as in Example 1. Again, two commercial red wine powders were used for comparison. In this case, the initial wine was also analysed and the alcohol content was determined for the starch powders. As regards the commercial red wine powders, the commercial powder 1 is the product Molda IS 1422, which contains glucose syrup, DE 30-33 as carrier, and dealcoholized French red wine. The commercial powder 2 is the product Robertet IS 26 907, which has 80% maltodextrin as carrier, DM > 94%. Sensory evaluation Ethyl butyrate contents [µg/kg] Alcohol content [%] iso- n- Maize starch markedly weaker than pea starch 33 97 0.18 Waxy maize starch ditto 36 37 0.38 Pea starch almost like the initial wine 100 155 0.36 Commercial powder I flat, scarcely like wine <10 <10 n.d. Commercial powder II weak, atypical raspberry-like 75 55 n.d. Initial wine typical 64 68 10.5 The table shows not only the again improved aroma retention of the pea starch in comparison with the other starches (as also in comparison with the commercial products), but also the relatively low retention capacity for ethanol, so that the alcohol can be virtually completely recovered. Based on the initial values, the retention capacity for the esters is 17% and 25%, and for the alcohol present at 90 million-fold excess, only 0.4%. Example 3 : Acid-degraded pea starch is used as aroma-binding carrier. The pea starch is modified by impregnating 100 g of starch with 4 mmol of HCl, then heating to 68°C, subsequently neutralizing with a soda solution equimolar to the HCl concentration and simultaneously cooling. 100 g of the acid-modified pea starch are gelatinized by heating in 400 ml of red wine (Beaujolais) and the starch paste thus obtained is freeze-dried after cooling. A corresponding wine powder was produced from native pea starch from the same wine and in the same manner. STARCH TYPE ETHYL BUTYRATE CONTENT [µg/kg] ALCOHOL CONTENT (%) iso- n- NATIVE PEA STARCH 100 155 3.6 ACID-MODIFIED PEA STARCH 134 590 1.9 Table 3 shows that the improved aroma retention of the pea starch, in comparison with the maize starch and waxy maize starch and the commercial products (cf. Table 2), can be further increased by an acid modification and the alcohol content can be decreased.

Claims: Aroma powder containing a carrier and aroma-active constituents of an alcohol-containing liquid, characterized in that the carrier for the aroma-active constituents is a high-amylose starch product having an amylose content of at least 30 %. Aroma powder according to Claim 1, characterized in that the alcohol-containing liquid is wine. Aroma powder according to one of Claims 1 or 2, characterized in that the high-amylose starch product is unmodified or acid-modified pea starch or pea amylose. Process for the production of an aroma powder according to one of Claims 1 to 3, characterized in that a starch paste is produced from high-amylose starch having an amylose content of at least 30 % and an alcohol-containing liquid and dried, preferably freeze-dried, to form the aroma powder. Process according to Claim 4, characterized in that alcohol-containing liquid having a natural alcohol content is used. Use of an aroma powder according to one of Claims 1 to 3 for the production of soups, sauces and desserts.

Inventors: KLINGLER RUDOLF WOLFGANG PROF, STUTE ROLF DR, KLINGLER, RUDOLF WOLFGANG, PROF.DR., STUTE, ROLF, DR.
Applicants: BESTFOODS, BESTFOODS DE GMBH & CO OHG, BESTFOODS DEUTSCHLAND GMBH & CO. OHG
Application year: 1997
Main classification: A23L1
IPC codes: A23L1, C12G3