Method for operating a furnace for processes and treatments in a sub-stoichiometric atmosphere

Abstract: Furnace for processes and treatments in a sub-stoichiometric atmosphere, comprising a combustion chamber (1) provided with fuel-feeding means, feeding means (3) for combustion promoter and extraction means (4) for the gases produced in the interior of said chamber (1); said feeding means (3) for combustion promoter and said extraction means (4) for the gases are connected, in an alternating way with suitable selection means (203, 213, 104, 114), to said furnace through at least one device (2) connected by suitable means (402) to an open port (121) on the combustion chamber (1) of said furnace, said device comprising means for post-combustion (102) of the gases, heat exchange and heat storage (112).

Description: The present invention relates to method for operating a furnace for processes and heat treatments, comprising a furnace combustion chamber and at least a pair of alternating phase regenerative preheaters each comprising a chamber connected by suitable means to an open port on the furnace combustion chamber and communicating at one end with selection means, provided with suitable packaging disposed in proximity of the end of said chamber communicating with said selection means, wherein said selection means connect in an alternating way the chamber of each regenerative preheater in a first phase with extraction means for the flue gases produced in the furnace combustion chamber and in a second phase with feeding means for a combustion promoter. A method of this kind is known from the documents US-A-5057010 and US-A-5203859. In the furnaces known from both of these documents in the first phase through the chamber of the regenerative preheater and through the successive post-combustion, heat-exchange and heat-storage means only gases coming from the furnace combustion chamber are conveyed to the extraction means for the flue gases, while in the second phase simultaneously with the combustion promoter coming from the respective feeding means also a fuel is injected into the chamber of the regenerative preheater in order to be burned generating heat and a flame which enter the furnace combustion chamber through the open port between this chamber and the chamber of the generative preheater. It is the object of the present invention to provide a method of the type according to the pre-characterizing part of claim 1, which allows high heat recovery, eliminating the major part of the unburned components of the discharge gases and effecting the transfer of both the discharged gas and the air feed of the furnace through lines at significantly lower temperature. According to the characterizing part of claim 1, the method according to the invention is characterized in that: a) the thermodynamic processes and the heat treatments in the furnace take place in a sub-stoichiometric atmosphere so that the flue gases produced in the interior of the furnace combustion chamber have a high content of unburned components, in particular CO, b) in the first phase the chamber of the regenerative preheater is connected both with the flue gas extraction means and directly with the feeder means for the combustion promoter upstream to the post-combustion, heat-exchange and heat-storage means to effect the complete combustion of the unburned components of the gases coming from the furnace combustion chamber, c) in the second phase only the combustion promoter is fed to the chamber of the regenerative preheater. A preferred embodiment of the invention is characterized in that the chamber of the regenerative preheater contains in its lower part a packaging comprising the post-combustion, heat-exchange and heat-storage means and is connected at its lower end alternatively in the first phase through a valve with the flue gas extraction means and in the second phase through a valve with the feeding means for the combustion promoter, and the upper end of the chamber of the regenerative preheater communicates through a conduit and a diffuser element of refractory material with the open port of the furnace combustion chamber and is connected in the second phase through a feeding conduit and a valve with the feeding means for the combustion promoter. Further advantages and features will be evident from the following detailed description of an embodiment of the present invention, for the purpose of example and without limitation, with reference to the attached single plate of drawings, in which: Figure 1 shows a transverse sectional view of a furnace operated according to the present invention, and Figure 2 shows a plan view from above with parts in section of an enlarged detail of the furnace operated according to the invention. In Figure 1 a furnace operated according to the present invention is illustrated; in the figure, a rotary hearth furnace is illustrated by way of example. The combustion chamber of said furnace is designated 1. This chamber is delimited by two side walls 101, one top wall 201 and one hearth 301 which is mobile relative to the said side walls 101 and the top wall 201. Said hearth is mounted in a manner known per se on a frame 311 which slides with the guides 321 on the wheels 11 mounted on the supports 10. The tightness of the chamber 1 with respect to the gases produced therein is assured for the rotating hearth 301 by the hydraulic seals 20 with liquid 21, in which the flanges 331 of the hearth run and into which the flanges 111 of the sides walls are inserted. On the side walls 101 of the chamber 1, there are open ports 121, to which the devices 2 operated according to the invention are connected. Said device comprises a chamber 102 partially packed with packing material 112, retained by a grid 132 disposed on the bottom of said chamber 102. On said chamber, a conduit 122 opens which communicates with said port 121 of the wall 101 through the diffuser 402. Moreover, said chamber has, at the same end where the conduit 122 opens, a free space 142 communicating with the conduit 103 which is connected by a control means such as the modulation valve 113 to the header 3 for feeding the combustion-promoting gases. At the opposite end, the chamber 102 terminates in a conduit 302 to which the conduits 203 and 104 communicating with the headers 3 for feeding the combustion promoter and 4 for extracting the gases produced in the chamber 1 can be connected alternatingly by suitable selection means such as the interlock valves 213 and 114 respectively. In the Figure, the furnace zone illustrated in section has two devices 2 shown disposed on the walls 101 of said combustion chamber 1. Figure 2 illustrates a detail of the furnace, regarding the device 2. The same numerals correspond to the same parts. As can be seen, both the conduit 122 and the conduit 103 are arranged tangentially with respect to the chamber 102 of the said device. The operation of the furnace according to the invention will become clear from the following. The combustion in the interior of the furnace chamber 1 evolves gas at high temperature (about 1400°C) and high content of unburned components, in particular CO, in the furnaces for the reduction of metal oxides. The devices 2, with which the furnace operated according to the invention is equipped, operate in alternating phases; in one phase, the valve 114 which controls the conduit 104, which puts the chamber 102 of the device 2 in communication with the extraction header 4, is open, while the valve 213 which controls the conduit 203, which communicates with the header 3 for feeding the combustion promoter is closed. The gas thus flows into the interior of the chamber 102. The quantity of air necessary a) for effecting the complete combustion of the unburned components of the gases coming from the furnace chamber 1 and b) for controlling the temperature of the gas produced at the desired level, for example 1300°C, is injected from the conduit 103 into the chamber 102, modulated owing to the valve 113. The gases, virtually free of unburned residues, then pass through the packing, giving up thereto a large part of their sensible heat, and then enter the header 4 at a temperature of between 200°C and 300°C. The packing material will conveniently be selected from materials resistant to heat and thermal shock and will be disposed in such a way that it provides an adequate permeability and sufficient surface area per unit volume. The chamber 102, the diffuser 402 and the port 121 will be made with an internal lining of refractory material in order to withstand the heat to which they are exposed. In the next phase, the valve 114 and the valve 113 are closed and a valve 213 is opened. Consequently, the combustion promoter, that is to say the air destined to feed the furnace, penetrates into the chamber 102 passing through the packing 112 thereof; in this way, the heat stored in the packing 112 is given up to the combustion promoter which, preheated to the intended temperature (generally about 1000°C), reaches the furnace chamber 1, passing through the diffuser 402 and the port 121. The cycle described above can at this point be repeated again. Advantageously, the conduit 122 and 103 are disposed in the way illustrated in Figure 2, in order to allow better mixing of the respective gas flows, that is to say the gas coming from the combustion chamber of the furnace, as regards the conduit 122, and the combustion-promoting gas coming from the header 3 for combustion promoter, as regards the conduit 103. As is illustrated in the figure for a given furnace zone, the devices 2 are preferably installed in pairs or even numbers, in order to guarantee a constant rate of the gas drawn from a certain zone and of preheated air injected into the latter. The inversion of the operating phase occurs at preset time intervals or when a given temperature threshold is reached, for example a maximum value for the discharge gases or a minimum value for the air injected into the furnace, which expediently is monitored. Advantageously, each furnace zone is controlled as regards the inflow of the combustion promoter and the outflow of the discharge gases by control means disposed on the respective headers. The furnace thus conceived achieves numerous advantages over furnaces of the known type. In particular, the best results can be achieved where the furnace used operates under conditions of so-called diffuse combustion; in these cases, the physical closeness between the point of injection of the combustion promoter and that of the fuel turns out in fact to be less important. Finally, the coupling between the post-combustion of the unburned gases extracted from the furnace chamber and the subsequent heat recovery is effected by the technique of alternating-phase regenerative preheaters. The furnace operated according to the invention makes it possible to exploit the calorific value of the fumes generated in the combustion chamber with a yield of about 90%, which is very much higher than that obtainable with the devices known in the state of the art. Moreover, the diverse furnace zones become less dependent on each other and substantially more controllable, reducing the disturbing effects which the combustion in a given zone can generate on that which occurs in an adjacent zone and further downstream with respect to the direction of the fumes. Finally, the headers for feeding the combustion promoter and for extracting the fumes can be constructed. with smaller dimensions and less insulation or in the absence thereof, since the gases passing through them are at temperatures much lower than those in practice in the devices currently in use.

Claims: Method for operating a furnace for processes and heat treatments comprising a furnace combustion chamber (1) and at least a pair of alternating phase regenerative preheaters (2) each comprising a chamber (102) connected by suitable means (402) to an open port (121) on the furnace combustion chamber (1) and communicating at one end (302) with selection means (203, 213, 104, 114), provided with suitable packaging (112) disposed in proximity of the end (302) of said chamber (102) communicating with said selection means (203, 213, 104, 114), wherein said selection means connect in an alternating way the chamber (102) of each regenerative preheater (2) in a first phase with extraction means (4) for the flue gases produced in the furnace combustion chamber (1) and in a second phase with feeding means (3) for a combustion promoter, characterized in that a) the thermodynamic processes and the heat treatments in the furnace take place in a sub-stoichiometric atmosphere so that the flue gases produced in the interior of the furnace combustion chamber (1) have a high content of unburned components, in particular CO, b) in the first phase the chamber (102) of the regenerative preheater (2) is connected both with the flue gas extraction means (4) and directly with the feeder means (3) for the combustion promoter upstream to the post-combustion, heat-exchange and heat-storage means (112) to effect the complete combustion of the unburned components of the gases coming from the furnace combustion chamber, c) in the second phase only the combustion promoter is fed to the chamber (102) of the regenerative preheater (2) Method according to claim 1, characterized in that the chamber (102) of the regenerative preheater contains in its lower part a packing (112) comprising the post-combustion, heat-exchange and heat-storage means and is connected at its lower end (302) alternatively in the first phase through a valve (114) with the flue gas extraction means (4) and in the second phase through a valve (213) with the feeding means (3) for the combustion promoter, and the upper end of the chamber (102) of the regenerative preheater (2) communicates through a conduit (102) and a diffuser element (402) of refractory material with the open port (121) of the furnace combustion chamber (1) and is connected in the second phase through a feeding conduit (103) and a valve (113) with the feeding means (3) for the combustion promoter. Method according to claim 2, characterized in that said conduit (122) connecting the chamber (102) of the regenerative preheater (2) with the open port (121) of the furnace combustion chamber (1) and said feeding conduit (103) connecting the chamber (102) with the feeding means (3) for the combustion promoter are joined tangentially to the side walls of said chamber (102). Method according to claim 2, characterized in that the packing (112) of the post-combustion, heat-exchange and heat-storage means comprises randomly packed spherules or granules of refractory material. Method according to claim 2, characterized in that the packing (112) of the post-combustion heat-exchange and heat-storage means comprises perforated stacked refractory bricks.

Inventors: FONTANA PIERGIORGIO, FONTANA, PIERGIORGIO
Applicants: SMS DEMAG S P A, SMS DEMAG S.P.A.
Application year: 1997
Main classification: F27D17
IPC codes: F27B9, F27D17