MOVIE FILM CLEANING SOLVENT

Abstract: This invention relates to a solvent system and process for cleaning cellulose triacetate polymer camera film. The solvent system comprises n-propyl bromide and a mix of an alkyl bromide in which the alkyl group contains 4 to 7 carbon atoms and an alkane containing 6 to 7 carbon atoms.

Description: MOVΪE FILM CLEANING SOLVENT Background of the Invention: This invention relates to an environmentally friendly solvent for use in cleaning movie film, in particular, cellulose triacetate film. Movie film is designed for repetitive use and, as such, must be durable and true to its original shape and size over a long period of time. Curling, cracking or peeling of the film is not tolerable. In addition, the film must be kept clean from skin oils, dust and other matter which can be deposited during film processing and handling. It is generally necessary to clean movie film several times during its life. Cleaning is conveniently done by immersing the film in a solvent which is contemporaneously subjected to sonication. The solvent is contained in a tank and the film is fed through the tank via film guides. The film is dried as it is removed from the tank and is rewound. The solvent must be capable of cleaning the film without leaving a deposit on the film and without causing any distortion or damage to the film. Heretofore, a preferred solvent has been 1,1,1 -trichloroethane. However, this solvent is no longer favored as it is to soon be banned world-wide for solvent applications due to environmental concerns. Environmental concerns could be attenuated if an alkyl bromide solvent could be used instead of 1,1,1 -trichloroethane. This would be especially so if n-propyl bromide could be the solvent as it has good cleaning characteristics, a low boiling point and is environmentally friendly, e.g., its Ozone Depletion Potential is low as compared to 1,1,1 -trichloroethane. The low boiling point is advantageous as it insures that there will be no or very little solvent residue left on the cleaned film. n-Propyl bromide was tried on several types of film and was found to be suitable except for films based on cellulose triacetate polymer. For this last type of film, the n-propyl bromide caused unacceptable curling. Despite this fatal infirmity, the benefits of using n-propyl bromide made it well worthwhile to investigate the problem and to search for a solution which would yield an n-propyl bromide based solvent which did not cause film curl but which still retained the benefits of n-propyl bromide. The Invention: This invention relates to an environmentally friendly solvent system suitable for use in cleaning cellulose triacetate polymer based camera film. The solvent systems of this invention comprise 40 to 75 wt% n-propyl bromide product and 60 to 25 wt% of a mix comprised of alkyl bromide in which the alkyl group contains 4 to 7 carbon atoms and an alkane containing 6 to 7 carbon atoms. The weight percentages are based upon the total weight of n-propyl bromide product and alkyl bromide in the solvent system. The n-propyl bromide product used in the solvent systems of this invention can be pure n-propyl bromide or any of the commercially available products which are preferably of high purity, i.e., at least 98+ wt% n-propyl bromide. Lower purity product may be used, say 94 to 97 wt% n-propyl bromide. The main impurity in most all cases is iso-propyl bromide. Iso-propyl bromide is a process impurity and its presence can be reduced by distillation. Thus, for the purposes of this invention, the term "n-propyl bromide product" is to mean pure n-propyl bromide or a product which contains n-propyl bromide and up to 6 wt% normally occurring process impurities, the most prominent of which is often iso-propyl bromide. The most preferred n-propyl bromide product is that which is 99+ wt% pure n-propyl bromide. The weight percentages are based upon the total weight of the n-propyl bromide product. One of the components present in the mix used in the solvent system of this invention is alkyl bromide in which the alkyl group contains 4 to 7 carbon atoms. Exemplary alkyl groups are: n-butyl, iso-butyl, n-pentyl, 2-methylbutyl, 3-methylbutyl, n-hexyl, 2,3-dimethyl butyl, n-heptyl and the like. Mixtures of any two or more of the alkyl bromides of this invention are suitable to serve as the alkyl bromide component. Preferred alkyl groups are the n-alkyl groups. It is preferred that the alkyl bromide be a primary bromide; however secondary and tertiary bromides are also suitable. Also preferred are those alkyl bromides having a boiling point within 20 C° of the boiling point of n-propyl bromide. The most preferred alkyl bromide is 1-bromo butane, i.e., n-butyl bromide. The other component of the mix is an alkane containing 6 to 7 carbon atoms. Preferred are n-hexane, n-heptane or a mixture thereof. Most prefe ed is n-hexane, as it has a boiling point which approximates that of n-propyl bromide. The mix preferably contains a 10 to 90 wt% of one of the components with the balance being provided by the other component. More preferably, the mix contains 30 to 70 wt% of one component and the balance being the other component. Most preferred are mixes containing 40 to 60 wt% of one component with the balance being the other component. Particularly suitable are mixes containing from 40 to 60 wt% n-butyl bromide and 40 to 60 wt% n-hexane, n-heptane or a mix thereof, with n-hexane being most desired. The respective amounts of n-propyl bromide product and mix of alkyl bromide and alkane is, as before noted, 40 to 75 wt% n-propyl bromide product and 60 to 25 wt% mix. Preferably, the n-propyl bromide product is present in an amount of 50 to 70 wt%, with the mix being present in an amount of 50 to 30 wt%. Especially preferred are 50/50 and 66/34 blends of n-propyl bromide product to mix. The weight percents are based on the total amount of n-propyl bromide product and mix present in the solvent system. The n-propyl bromide product and the mix and its components are highly miscible one with the other and, thus, they can be conventionally mixed together in any order with no particular requirements being needed. The solvent systems of this invention can include additional constituents. For example, the n-propyl bromide can be stabilized against decomposition should it come in contact with a metal such as magnesium, titanium, steel or aluminum. These metals can act as catalysts which dehydrobrominate the n-propyl bromide. The dehydrobromination product is HBr which can, in turn, attack metal and leave it corroded. Generally, any of the conventional stabilizers which are taught by the art to be useful in stabilizing halogenated hydrocarbon solvents are suitable for use in this invention, the only caveat being that the stabilizer not adversely affect the film to be cleaned. The stabilizer may be a singular stabilizer or a combination of stabilizers. The stabilizers can be nitroalkanes, ethers, epoxides, amines or any combination thereof. Preferred are the epoxides. Some art-recognized nitroalkanes are nitromethane, nitroethane, 1 -nitropropane, 2- nitropropane and nitrobenzene. Preferred is nitromethane. They are usable either singularly or in form of a mixture of two or more. The ethers include 1 ,2-dimethyoxyethane, 1,4-dioxane, 1 ,3-dioxolane, diethyl ether, diisopropyl ether, dibuty! ether, trioxane, alkyl cellosolves in which the alkyl group has 1 to - J 10 carbon atoms such as methyl cellosolve, ethyl cellosolve and iso-propyl cellosolve, acetal, acetone dimethyl acetal, 2,2-dimethoxypopane, diethoxymethane, acetaldehyde dimethyl acetal, dimethoxymethane, γ-butyrolactone, methyl t-butyl ether, tetrahydrofuran and N-methylpyrrole, They are usable either singularly or in the form of a mixture of two or more. The epoxides include epichlorohydrin, propylene oxide, butylene oxide, cyclohexene oxide, glycidyl methyl ether, glycidyl methacrylate, pentene oxide, cyclopentene oxide and cyclohexene oxide. Preferred is 1,2-epoxy butane. They are usable either singularly or in the form of a mixture of two or more. The amines include hexylamine, octylamine, 2-ethylhexylamine, dodecylamine, ethylbutylamine, hexylmethylamine, butyloctylamine, dibuty lamine, octadecylmethylamine, triethylamine, tributylamine, diethyloctylamine, tetradecyldimethylamine, diisobutylamine, diisopropylamine, pentylamine, N-methylmorpholine, iso-propylamine, cyclohexylamine, butylamine, isobutylamine, dipropylamine, 2,2,2, 6-tetramethylpiperidine, N,N-diallyl-p- phenylenediamine, diallyamine, aniline, ethylenediamine, propylenediamine, diethylene- triamine, tetraethylenepentamine, benzylamine, dibenzylamine, diphenylamine and diethyl- hydroxyamine. They are usable either singularly or in the form of a mixture of two or more. A preferred stabilizer is 1 ,2-butylene oxide. The amount of stabilizer used can be the conventional amount, e.g., from 0.1 wt% to 15 wt%, with the weight percent being based upon the total weight of the n-propyl bromide product in the solvent. A most preferred stabilizer amount is 0.25 - 1.0 wt% 1 ,2-butylene oxide. The weight percent is based upon the total weight of the solvent system. The solvent system of this invention is used conventionally and could be seen as a suitable replacement for 1 , 1 , 1 -trichloroethane. The solvent system is kept at a bath temperature within the range of from 20 to 45° C. The residency time for the film in the bath is conven- tional, say 0.1 to 5 seconds. The film drying temperature is 25 to 35° C. The cellulose triacetate polymer based camera films discussed herein are available from Eastman Kodak Company. These camera films are used in movie cameras. EXAMPLES A solvent system bath at room temperature was prepared in a vessel. Into the bath was immersed processed Eastman Kodak Company color negative camera film. The film was a cellulose triacetate polymer based film. The immersion lasted for 10 minutes. The film was removed and dried at room temperature. The dried film was then examined for curling, cracking and peeling. The following Table gives the results obtained. TABLE Solvent System Curling Cracking Peeling Discoloration* 1,1,1-TCE none none none none 99 t% NPB slight curl none none none 50 wt% NPB none none none none 25 t% HEX 25 wt% NBB • discoloration of the solvent system TCE - trichloroethane NPB - n-propyl bromide NBB - n-butyl bromide HEX - hexane

Claims: CLAIMS 1. A solvent system comprised of 40 to 75 wt% n-propyl bromide product and 60 to 25 wt% of a mix comprised of alkyl bromide in which the alkyl group contains 4 to 7 carbon atoms and an alkane containing 6 to 7 carbon atoms. 2. The solvent system of claim 1 wherein the n-propyl bromide product is present in an amount of from 50 to 70 wt% and wherein the mix is present in an amount of from 50 to 30 wt%. 3. The solvent system of claim 1 wherein the alkyl bromide is n-butyl bromide and the alkane is n-hexane. 4. The solvent system of claim 2 wherein the alkyl bromide is n-butyl bromide and the alkane is n-hexane. 5. The solvent system of claim 1 wherein the alkyl bromide is n-butyl bromide and the alkane is n-hexane and wherein the n-propyl bromide product is present in an amount of from 50 to 66 wt% and wherein the mix is present in an amount of from 50 to 34 wt%. 6. The solvent system of claim 1 wherein the mix contains from 40 to 60 wt% n-butyl bromide and 40 to 60 wt% n-hexane, n-heptane or a mix thereof. 7. A process for cleaning cellulose triacetate polymer based camera film, which process comprises immersing the film into a solvent system comprised of from 40 to 75 wt% of a n-propyl bromide product and from 60 to 25 wt% of a mix containing alkyl bromide in which the alkyl group contains 4 to 7 carbon atoms and an alkane containing 6 to 7 carbon atoms. 8. The process of claim 7 wherein the n-propyl bromide product is present in an amount of from 50 to 70 wt% n-propyl bromide and wherein the mix is present in an amount of from 50 to 30 wt%. 9. The process of claim 7 wherein the alkyl bromide is n-butyl bromide and the alkane is hexane. 10. The process of claim 8 wherein the alkyl bromide is n-butyl bromide and alkane is hexane. 1 1. The process of claim 7 wherein the alkyl bromide is n-butyl bromide, the alkane is hexane and wherein the n-propyl bromide product is present in an amount of from 50 to 66 wt% and wherein the mix is present in an amount of from 50 to 34 wt%. 12. The process of claim 7 wherein the mix contains from 40 to 60 wt% n-butyl bromide and 40 to 60 wt% n-hexane, n-heptane or a mix thereof.

Inventors: AZARNIA FARAH D, LEE BURNELL, AZARNIA, FARAH, D., LEE, BURNELL
Applicants: ALBEMARLE CORP, ALBEMARLE CORPORATION
Application year: 1997
Main classification: G03C11
IPC codes: C07C9, C07C19, C11D7, G03C11