Photographic element having improved magenta dye light stability and process for its use

Abstract: The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula I: wherein X is hydrogen or a coupling-off group; and R is a tertiary alkyl group and R represents the group in which R 1 , R 2 , and R 3 are independently selected alkyl groups, provided that any two of R 1 , R 2, and R 3 may join to form a ring; R 4 is hydrogen or a substituent, provided that R 3 and R 4 may join to form a ring when R 4 is a substituent; and W is a substituent selected from the group consisting of -C(O)R 5 , -SO 2 R 5 , and -P(O)(OR 6 ) 2 in which R 5 is selected from the group consisting of alkyl, aryl, alkoxy, aryloxy, alkylamino, and arylamino groups and R 6 is selected from the group consisting of alkyl and aryl groups. The element exhibits improved magenta dye light stability.

Description: Field of the Invention This invention relates to a silver halide photographic element and process for its use in which the element contains a lH-pyrazolo[5,1-c]-1,2,4-triazole magenta dye-forming coupler which provides a color photographic image which exhibits improved stability to light. Background of the Invention Conventional color photography depends on the formation of dyes and uses subtractive primaries to form the desired colors. One of the problems encountered with the dyes which form the images is their tendency to degrade when exposed to light. This is of particular importance with respect to photographic elements intended for direct viewing. Direct view elements include reflective prints and color transmission elements such as motion picture prints and projection slides. Such elements receive substantial exposure to light while being viewed. This not only causes the dye images to fade, but when the dyes of different colors fade at different rates, the image changes color and the neutral areas become undesirably colored. Since the advent of color photography there have been ongoing efforts to improve the dye stability. Nevertheless, there is still a need for further improvement in the dye light stability of photographic elements intended for direct viewing. Efforts have been ongoing to provide stabilized dyes which will exhibit improved light stability. Some of these efforts are described as follows. EP0 704 758 of Kawagishi et al. teaches certain 1H-pyrazolo[5,1-c]-1,2,4-triazole compounds which are said to be useful for improving color reproduction, color developability, and magenta dye light stability. The coupler contains at the 3-position an aminoalkylene group bonded to a hetero substituted phenyl group by a -C(O)-, -SO 2 -, -SO 2 NR-, -C(O)NR-, or -COOR- group. Neither the carbon of the aminoalkylene group alpha or beta to the azole ring to which it is bonded is required to be further substituted. Among the specific couplers contemplated are those having, for example, α-methyl, α-isopropyl, α-ethyl, α-dodecyl, α-phenyl and α,α-dimethyl links to the azole ring. In almost every example, the α carbon is linked directly to a heterogroup of the substituent. When there is present a β-carbon, it is never further substituted. EP 602 748 of Tang et al. suggests generic substituent groups for pyrazolotriazole couplers which enhance the combination of color reproduction, dye light stability and coupler reactivity. It is stated that substitution at the alpha carbon is desired, but there is no specific suggestion that further substitution at the beta carbon is advantageous. U.S. Patent No. 5,470,697 of Kita et al. suggests pyrazolotriazole couplers having a fully substituted carbon in the alpha position with an oxygen linked moiety in two of the branches for purposes of improved sensitivity and reduced development pH sensitivity. No data on dye stability is given and there is no recognition of the advantage of any particular substituent combination for purposes of improving dye light stability. U.S. Patent No. 5,032,497 of Nakayama et al. suggests a certain pyrazolotriazole coupler having a tertiary alkyl group in the 3-position and a primary alkyl group in the 6-position for the purpose of improving the absorption spectra of the magenta dye formed upon development and improving the resistance of the dye to formaldehyde and light. In spite of the efforts to improve dye light stability, there is still a need for further improvements in the dye light stability of photographic elements intended for direct viewing. Summary of the Invention The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula I: wherein X is hydrogen or a coupling-off group; and R' is a tertiary carbon and R" represents the group in which R 1 , R 2 , and R 3 are independently selected alkyl groups, provided that any two of R 1 , R 2 , and R 3 may join to form a ring; R 4 is hydrogen or a substituent, provided that R 3 and R 4 may join to form a ring when R 4 is a substituent; and W is a substituent selected from the group consisting of -C(O)R 5 , -SO 2 R 5 , and -P(O)(OR 6 ) 2 in which R 5 is selected from the group consisting of alkyl, aryl, alkoxy, aryloxy, alkylamino, and arylamino groups and R 6 is selected from the group consisting of alkyl and aryl groups; provided that the term "group" includes both substituted and unsubstituted forms of the identified group which do not destroy properties necessary for photographic utility. The invention also provides a process for forming an image in the element of the invention, after the element has been imagewise exposed to light, comprising contacting the element with a color-developing agent. The element exhibits improved magenta dye light stability. Detailed Description of the Invention The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula I: wherein X is hydrogen or a coupling-off group; and R' is a tertiary alkyl group and R" represents the group in which R 1 , R 2 , and R 3 are independently selected alkyl groups, provided that any two of R 1 , R 2, and R 3 may join to form a ring; R 4 is hydrogen or a substituent, provided that R 3 and R 4 may join to form a ring when R 4 is a substituent; and W is a substituent selected from the group consisting of -C(O)R 5 , -SO 2 R 5 , and -P(O)(OR 6 ) 2 in which R 5 is selected from the group consisting of alkyl, aryl, alkoxy, aryloxy, alkylamino, and arylamino groups and R 6 is selected from the group consisting of alkyl and aryl groups. The magenta coupler useful in the invention is termed a 1H-pyrazolo[5,1-c]-1,2,4-triazole compound. Substituent R' of the coupler is any tertiary alkyl group. Suitable examples include 1-methyl-1-cyclopropyl, t-butyl, t-octyl and adamantyl. In substituent R", R 1 , R 2 , and R 3 are independently selected alkyl groups. Suitably they each contain from 1 to 20 carbon atoms, often 6 or less carbons. Typically, methyl, ethyl, propyl, isopropyl or dodecyl groups are employed. It is suitable to have R 1 and R 2 join to form cycloalkyl groups such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, etc. It is generally preferred that R 4 be a substituent rather than hydrogen. R 4 may suitably be an alkyl, aryl or a heterogroup. Suitably, R 4 will have from 1 to 20 carbon atoms and is preferably an alkyl group. Also useful are phenyl groups such as phenyl, methoxyphenyl, methylsulfonamidophenyl, or tolyl and naphthyl groups. In one embodiment of the invention, R 1 through R 4 are each independently selected unsubstituted alkyl groups. In another embodiment they are each unsubstituted methyl groups. The group W is comprised of a group consisting of -C(O)R 5 , -SO 2 R 5 , or -P(O)(OR 6 ) 2. Examples include amide groups, carbamate groups, and urea groups as well as sulfonamides and phosphonamides. In one embodiment, W contains the substituent group -NHC(O)R 7 or -NHSO 2 R 7 where R 7 is an alkyl or aryl group. R 5 is an alkyl, aryl, alkoxy, aryloxy, alkylamino, or arylamino group. Such groups typically have up to 40 carbon atoms. Examples include undecyl, ethylhexyl, isobutyl, and 2-aryloxytridecyl groups. The alkoxy group can contain up to 40 carbon atoms and be derived from methanol, ethanol, t-butanol, dodecanol or 2-aryloxyethanol. Suitable examples of aryl groups include those listed for R 4 . Suitable aryloxy groups include phenols such as 2,4-di-t-pentylphenoxy and naphthols. Alkylamino groups include aliphatic amines such as butylamine and dodecylamine as well as anilines including p-dodecylanilines. R 6 is more narrowly defined than R 5 and extends only to alkyl and aryl groups with examples as indicated above. The photographic element of the invention is most typically a color print element in which the light sensitive layers are provided on a paper or other reflective support. Such materials are suitably developed using the presently employed Kodak RA-4™ process. Alternatively, the element may be comprised of a transparent film support suitable for projection viewing. The following are examples of couplers useful in the invention. (Hereafter, "tBu" represents tertiary butyl, "Et" represents ethyl, "Me" represents methyl, and "Ac" represents acetyl.) To further enhance the light stability of the dyes formed from the couplers useful in the invention, it is generally desired to include one or more stabilizing compounds. The following are examples of stabilizing compounds. The stabilizers represented by generic formulas St-I, St-II, and St-III have been found suitable for use with the couplers used in the invention. and In the formulas: each R g independently represents a hydrogen atom, an alkyl group, an alkenyl group or an aryl group; each R h independently represents a halogen atom, an alkyl group, an alkenyl group, an alkoxy group, an aryl group, an aryloxy group, an alkylthio group, an aryl thio group, an acyl group, an acylamino group, a sulfonyl group, a sulfonamide group or a hydroxy group; each m is, individually an integer of 0 to 4; and A represents a branched or unbranched alkylene group having 1 to 6 carbon atoms in its linear structure extending between the phenoxy rings, R i represents an aryl group or a heterocyclic group; Z 1 and Z 2 each represent an alkylene group having 1 to 3 carbon atoms provided that the total number of carbon atoms in the ring is 3 to 6; n is an integer of 1 or 2; each R j is independently alkyl or alkoxy of 1 to 32 carbon atoms; p is an integer of 1 to 4 and when p is greater than 1, only one R j is alkoxy; Y is -NHSO 2 - or -SO 2 NH-; and R k is an alkyl group of 1 to 16 carbon atoms. Suitable compounds within these formulas are more fully described in U.S. Patent No. 5,561,037. In one embodiment, a compound within St-I and one within St-II are incorporated with the coupler and in another embodiment, three compounds from within each of the three formulas may be employed. Stabilizer St-23, St-1, and St-2 may be employed as species of St-I, St-II, and St-III, respectively. Typically, the couplers and the stabilizers with which they are associated are dispersed in the same layer of the photographic element in a high boiling organic compound known in the art as a coupler solvent. Representative coupler solvents include phthalic acid alkyl esters such as diundecyl phthalate, dibutyl phthalate, bis-2-ethylhexyl phthalate, and dioctyl phthalate, phosphoric acid esters such as tricresyl phosphate, diphenyl phosphate, tris-2-ethylhexyl phosphate, and tris-3,5,5-trimethylhexyl phosphate, citric acid esters such as tributyl acetylcitrate, 2-(2-Butoxyethoxy)ethyl acetate , and 1,4-Cyclohexyldimethylene bis(2-ethylhexanoate), benzoic acid esters such as octyl benzoate, aliphatic amides such as N,N-diethyl lauramide, N,N -Diethyldodecanamide, N,N -Dibutyldodecanamide, mono and polyvalent alcohols such as oleyl alcohol and glycerin monooleate, and alkyl phenols such as p-dodecyl phenol and 2,4-di-t-butyl or 2,4-di-t-pentyl phenol. Commonly used coupler solvents are the phthalate esters, which can be used alone or in combination with one another or with other coupler solvents. Selection of the particular coupler solvent has been found to have an influence both on the activity of the coupler and the hue of the dye formed on coupling. Unless otherwise specifically stated, substituent groups which may be substituted on molecules herein include any groups, whether substituted or unsubstituted, which do not destroy properties necessary for photographic utility. When the term "group" is applied to the identification of a substituent containing a substitutable hydrogen, it is intended to encompass not only the substituent's unsubstituted form, but also its form further substituted with any group or groups as herein mentioned. Suitably, the group may be halogen or may be bonded to the remainder of the molecule by an atom of carbon, silicon, oxygen, nitrogen, phosphorous, or sulfur. The substituent may be, for example, halogen, such as chlorine, bromine or fluorine; nitro; hydroxyl; cyano; carboxyl; or groups which may be further substituted, such as alkyl, including straight or branched chain alkyl, such as methyl, trifluoromethyl, ethyl, t -butyl, 3-(2,4-di-t-pentylphenoxy) propyl, and tetradecyl; alkenyl, such as ethylene, 2-butene; alkoxy, such as methoxy, ethoxy, propoxy, butoxy, 2-methoxyethoxy, sec -butoxy, hexyloxy, 2-ethylhexyloxy, tetradecyloxy, 2-(2,4-di- t -pentylphenoxy)ethoxy, and 2-dodecyloxyethoxy; aryl such as phenyl, 4-t-butylphenyl, 2,4,6-trimethylphenyl, naphthyl; aryloxy, such as phenoxy, 2-methylphenoxy, alpha- or beta-naphthyloxy, and 4-tolyloxy; carbonamido, such as acetamido, benzamido, butyramido, tetradecanamido, alpha-(2,4-di- t -pentyl-phenoxy)acetamido, alpha-(2,4-di- t -pentylphenoxy)butyramido, alpha-(3-pentadecylphenoxy)-hexanamido, alpha-(4-hydroxy-3- t -butylphenoxy)-tetradecanamido, 2-oxo-pyrrolidin-1-yl, 2-oxo-5-tetradecylpyrrolin-1-yl, N-methyltetradecanamido, N-succinimido, N-phthalimido, 2,5-dioxo-1-oxazolidinyl, 3-dodecyl-2,5-dioxo-1-imidazolyl, and N-acetyl-N-dodecylamino, ethoxycarbonylamino, phenoxycarbonylamino, benzyloxycarbonylamino, hexadecyloxycarbonylamino, 2,4-di-t-butylphenoxycarbonylamino, phenylcarbonylamino, 2,5-(di- t -pentylphenyl)carbonylamino, p -dodecyl-phenylcarbonylamino, p -toluylcarbonylamino, N-methylureido, N,N-dimethylureido, N-methyl-N-dodecylureido, N-hexadecylureido, N,N-dioctadecylureido, N,N-dioctyl-N'-ethylureido, N-phenylureido, N,N-diphenylureido, N-phenyl-N- p -toluylureido, N-( m -hexadecylphenyl)ureido, N,N-(2,5-di-t-pentylphenyl)-N'-ethylureido, and t butylcarbonamido; sulfonamido, such as methylsulfonamido, benzenesulfonamido, p -toluylsulfonamido, p -dodecylbenzenesulfonamido, N-methyltetradecylsulfonamido, N,N-dipropyl-sulfamoylamino, and hexadecylsulfonamido; sulfamoyl, such as N-methylsulfamoyl, N-ethylsulfamoyl, N,N-dipropylsulfamoyl, N-hexadecylsulfamoyl, N,N-dimethylsulfamoyl; N-[3-(dodecyloxy)propyl]sulfamoyl, N-[4-(2,4-di- t -pentylphenoxy)butyl]sulfamoyl, N-methyl-N-tetradecylsulfamoyl, and N-dodecylsulfamoyl; carbamoyl, such as N-methylcarbamoyl, N,N-dibutylcarbamoyl, N-octadecylcarbamoyl, N-[4-(2,4-di- t -pentylphenoxy)butyl]carbamoyl, N-methyl-N-tetradecylcarbamoyl, and N,N-dioctylcarbamoyl; acyl, such as acetyl, (2,4-di-t-amylphenoxy)acetyl, phenoxycarbonyl, p -dodecyloxyphenoxycarbonyl methoxycarbonyl, butoxycarbonyl, tetradecyloxycarbonyl, ethoxycarbonyl, benzyloxycarbonyl, 3-pentadecyloxycarbonyl, and dodecyloxycarbonyl; sulfonyl, such as methoxysulfonyl, octyloxysulfonyl, tetradecyloxysulfonyl, 2-ethylhexyloxysulfonyl, phenoxysulfonyl, 2,4-di- t -pentylphenoxysulfonyl, methylsulfonyl, octylsulfonyl, 2-ethylhexylsulfonyl, dodecylsulfonyl, hexadecylsulfonyl, phenylsulfonyl, 4-nonylphenylsulfonyl, and p -toluylsulfonyl; sulfonyloxy, such as dodecylsulfonyloxy, and hexadecylsulfonyloxy; sulfinyl, such as methylsulfinyl, octylsulfinyl, 2-ethylhexylsulfinyl, dodecylsulfinyl, hexadecylsulfinyl, phenylsulfinyl, 4-nonylphenylsulfinyl, and p -toluylsulfinyl; thio, such as ethylthio, octylthio, benzylthio, tetradecylthio, 2-(2,4-di- t -pentylphenoxy)ethylthio, phenylthio, 2-butoxy-5-t-octylphenylthio, and p -tolylthio; acyloxy, such as acetyloxy, benzoyloxy, octadecanoyloxy, p -dodecylamidobenzoyloxy, N-phenylcarbamoyloxy, N-ethylcarbamoyloxy, and cyclohexylcarbonyloxy; amine, such as phenylanilino, 2-chloroanilino, diethylamine, dodecylamine; imino, such as 1 (N-phenylimido)ethyl, N-succinimido or 3-benzylhydantoinyl; phosphate, such as dimethylphosphate and ethylbutylphosphate; phosphite, such as diethyl and dihexylphosphite; a heterocyclic group, a heterocyclic oxy group or a heterocyclic thio group, each of which may be substituted and which contain a 3 to 7 membered heterocyclic ring composed of carbon atoms and at least one hetero atom selected from the group consisting of oxygen, nitrogen and sulfur, such as 2-furyl, 2-thienyl, 2-benzimidazolyloxy or 2-benzothiazolyl; quaternary ammonium, such as triethylammonium; and silyloxy, such as trimethylsilyloxy. If desired, the substituents may themselves be further substituted one or more times with the described substituent groups. The particular substituents used may be selected by those skilled in the art to attain the desired photographic properties for a specific application and can include, for example, hydrophobic groups, solubilizing groups, blocking groups, releasing or releasable groups, etc. Generally, the above groups and substituents thereof may include those having up to 48 carbon atoms, typically 1 to 36 carbon atoms and usually less than 24 carbon atoms, but greater numbers are possible depending on the particular substituents selected. The materials useful in the invention can be used in any of the ways and in any of the combinations known in the art. Typically, the materials are incorporated in a silver halide emulsion and the emulsion coated as a layer on a support to form part of a photographic element. Alternatively, unless provided otherwise, they can be incorporated at a location adjacent to the silver halide emulsion layer where, during development, they will be in reactive association with development products such as oxidized color developing agent. Thus, as used herein, the term "associated" signifies that the compound is in the silver halide emulsion layer or in an adjacent location where, during processing, it is capable of reacting with silver halide development products. To control the migration of various components, it may be desirable to include a high molecular weight hydrophobe or "ballast" group in coupler molecules. Representative ballast groups include substituted or unsubstituted alkyl or aryl groups containing 8 to 42 carbon atoms. Representative substituents on such groups include alkyl, aryl, alkoxy, aryloxy, alkylthio, hydroxy, halogen, alkoxycarbonyl, aryloxcarbonyl, carboxy, acyl, acyloxy, amino, anilino, carbonamido, carbamoyl, alkylsulfonyl, arysulfonyl, sulfonamido, and sulfamoyl groups wherein the substituents typically contain 1 to 42 carbon atoms. Such substituents can also be further substituted. The photographic elements can be single color elements or multicolor elements. Multicolor elements contain image dye-forming units sensitive to each of the three primary regions of the spectrum. Each unit can comprise a single emulsion layer or multiple emulsion layers sensitive to a given region of the spectrum. The layers of the element, including the layers of the image-forming units, can be arranged in various orders as known in the art. In an alternative format, the emulsions sensitive to each of the three primary regions of the spectrum can be disposed as a single segmented layer. A typical multicolor photographic element comprises a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler. The element can contain additional layers, such as filter layers, interlayers, overcoat layers or subbing layers. If desired, the photographic element can be used in conjunction with an applied magnetic layer as described in Research Disclosure, November 1992, Item 34390 published by Kenneth Mason Publications, Ltd., Dudley Annex, 12a North Street, Emsworth, Hampshire P010 7DQ, ENGLAND, and as described in Hatsumi Kyoukai Koukai Gihou No. 94-6023, published March 15, 1994, available from the Japanese Patent Office. When it is desired to employ the materials useful in the invention in a small format film, Research Disclosure, June 1994, Item 36230, provides suitable embodiments. In the following discussion of suitable materials for use in the emulsions and elements of this invention, reference will be made to Research Disclosure, September 1996, Item 38957, available as described above, which will be identified hereafter by the term "Research Disclosure". The Sections hereafter referred to are Sections of the Research Disclosure. Except as provided, the silver halide emulsion containing elements employed in this invention can be either negative-working or positive-working as indicated by the type of processing instructions (i.e. color negative, reversal, or direct positive processing) provided with the element. Suitable emulsions and their preparation as well as methods of chemical and spectral sensitization are described in Sections I through V. Various additives such as UV dyes, brighteners, antifoggants, stabilizers, light absorbing and scattering materials, and physical property modifying addenda such as hardeners, coating aids, plasticizers, lubricants and matting agents are described, for example, in Sections II and VI through VIII. Color materials are described in Sections X through XIII. Scan facilitating is described in Section XIV. Supports, exposure, development systems, and processing methods and agents are described in Sections XV to XX. Certain desirable photographic elements and processing steps are described in Research Disclosure, Item 37038, February 1995, and desirable features for color prints are described in Research Disclosure, Item 18716, November 1979. Coupling-off groups are well known in the art. Such groups can determine the chemical equivalency of a coupler, i.e., whether it is a 2-equivalent or a 4-equivalent coupler, or modify the reactivity of the coupler. Such groups can advantageously affect the layer in which the coupler is coated, or other layers in the photographic recording material, by performing, after release from the coupler, functions such as dye formation, dye hue adjustment, development acceleration or inhibition, bleach acceleration or inhibition, electron transfer facilitation or color correction. The presence of hydrogen at the coupling site provides a 4-equivalent coupler, and the presence of another coupling-off group usually provides a 2-equivalent coupler. Representative classes of such coupling-off groups include, for example, chloro, alkoxy, aryloxy, hetero-oxy, sulfonyloxy, acyloxy, acyl, heterocyclyl such as oxazolidinyl or hydantoinyl, sulfonamido, mercaptotetrazole, benzothiazole, mercaptopropionic acid, phosphonyloxy, arylthio, and arylazo. These coupling-off groups are described in the art, for example, in U.S. Pat. Nos. 2,455,169, 3,227,551, 3,432,521, 3,476,563, 3,617,291, 3,880,661, 4,052,212 and 4,134,766; and in U.K. Patents and published application Nos. 1,466,728, 1,531,927, 1,533,039, 2,006,755A and 2,017,704A. Image dye-forming couplers may be included in the element such as couplers that form cyan dyes upon reaction with oxidized color developing agents which are described in such representative patents and publications as: U.S. Pat. Nos. 2,367,531, 2,423,730, 2,474,293, 2,772,162, 2,895,826, 3,002,836, 3,034,892, 3,041,236, 4,333,999, 4,883,746 and "Farbkuppler-eine LiteratureUbersicht," published in Agfa Mitteilungen, Band III, pp. 156-175 (1961). Preferably such couplers are phenols and naphthols that form cyan dyes on reaction with oxidized color developing agent. Couplers that form magenta dyes upon reaction with oxidized color developing agent are described in such representative patents and publications as: U.S. Pat. Nos. 2,311,082, 2,343,703, 2,369,489, 2,600,788, 2,908,573, 3,062,653, 3,152,896, 3,519,429, 3,758,309, 4,540,654, and "Farbkuppler-eine LiteratureUbersicht," published in Agfa Mitteilungen, Band III, pp. 126-156 (1961). Preferably such couplers are pyrazolones, pyrazolotriazoles, or pyrazolobenzimidazoles that form magenta dyes upon reaction with oxidized color developing agents. Couplers that form yellow dyes upon reaction with oxidized and color developing agent are described in such representative patents and publications as: U.S. Pat. Nos. 2,298,443, 2,407,210, 2,875,057, 3,048,194, 3,265,506, 3,447,928, 4,022,620, 4,443,536, and "Farbkuppler-eine LiteratureUbersicht," published in Agfa Mitteilungen, Band III, pp. 112-126 (1961). Such couplers are typically open chain ketomethylene compounds. Couplers that form colorless products upon reaction with oxidized color developing agent are described in such representative patents as: U.K. Patent No. 861,138; U.S. Pat. Nos. 3,632,345, 3,928,041, 3,958,993 and 3,961,959. Typically such couplers are cyclic carbonyl containing compounds that form colorless products on reaction with an oxidized color developing agent. Couplers that form black dyes upon reaction with oxidized color developing agent are described in such representative patents as U.S. Patent Nos. 1,939,231; 2,181,944; 2,333,106; and 4,126,461; German OLS No. 2,644,194 and German OLS No. 2,650,764. Typically, such couplers are resorcinols or m-aminophenols that form black or neutral products on reaction with oxidized color developing agent. In addition to the foregoing, so-called "universal" or "washout" couplers may be employed. These couplers do not contribute to image dye-formation. Thus, for example, a naphthol having an unsubstituted carbamoyl or one substituted with a low molecular weight substituent at the 2- or 3- position may be employed. Couplers of this type are described, for example, in U.S. Patent Nos. 5,026,628, 5,151,343, and 5,234,800. It may be useful to use a combination of couplers any of which may contain known ballasts or coupling-off groups such as those described in U.S. Patent 4,301,235; U.S. Patent 4,853,319 and U.S. Patent 4,351,897. The coupler may contain solubilizing groups such as described in U.S. Patent 4,482,629. The materials useful in the invention may be used in association with materials that accelerate or otherwise modify the processing steps e.g. of bleaching or fixing to improve the quality of the image. Bleach accelerator releasing couplers such as those described in EP 193,389; EP 301,477; U.S. 4,163,669; U.S. 4,865,956; and U.S. 4,923,784, may be useful. Also contemplated is use of the compositions in association with nucleating agents, development accelerators or their precursors (UK Patent 2,097,140; U.K. Patent 2,131,188); electron transfer agents (U.S. 4,859,578; U.S. 4,912,025); antifogging and anti color-mixing agents such as derivatives of hydroquinones, aminophenols, amines, gallic acid; catechol; ascorbic acid; hydrazides; sulfonamidophenols; and non color-forming couplers. The materials useful in the invention may also be used in combination with filter dye layers comprising colloidal silver sol or yellow, cyan, and/or magenta filter dyes, either as oil-in-water dispersions, latex dispersions or as solid particle dispersions. Additionally, they may be used with "smearing" couplers (e.g. as described in U.S. 4,366,237; EP 96,570; U.S. 4,420,556; and U.S. 4,543,323.) Also, the compositions may be blocked or coated in protected form as described, for example, in Japanese Application 61/258,249 or U.S. 5,019,492. The materials useful in the invention may further be used in combination with image-modifying compounds such as "Developer Inhibitor-Releasing" compounds (DIRs). DIRs useful in conjunction with the compositions of the invention are known in the art and examples are described in U.S. Patent Nos. 3,137,578; 3,148,022; 3,148,062; 3,227,554; 3,384,657; 3,379,529; 3,615,506; 3,617,291; 3,620,746; 3,701,783; 3,733,201; 4,049,455; 4,095,984; 4,126,459; 4,149,886; 4,150,228; 4,211,562; 4,248,962; 4,259,437; 4,362,878; 4,409,323; 4,477,563; 4,782,012; 4,962,018; 4,500,634; 4,579,816; 4,607,004; 4,618,571; 4,678,739; 4,746,600; 4,746,601; 4,791,049; 4,857,447; 4,865,959; 4,880,342; 4,886,736; 4,937,179; 4,946,767; 4,948,716; 4,952,485; 4,956,269; 4,959,299; 4,966,835; 4,985,336 as well as in patent publications GB 1,560,240; GB 2,007,662; GB 2,032,914; GB 2,099,167; DE 2,842,063, DE 2,937,127; DE 3,636,824; DE 3,644,416 as well as the following European Patent Publications: 272,573; 335,319; 336,411; 346, 899; 362, 870; 365,252; 365,346; 373,382; 376,212; 377,463; 378,236; 384,670; 396,486; 401,612; 401,613. Such compounds are also disclosed in "Developer-Inhibitor-Releasing (DIR) Couplers for Color Photography," C.R. Barr, J.R. Thirtle and P.W. Vittum in Photographic Science and Engineering, Vol. 13, p. 174 (1969), incorporated herein by reference. Generally, the developer inhibitor-releasing (DIR) couplers include a coupler moiety and an inhibitor coupling-off moiety (IN). The inhibitor-releasing couplers may be of the time-delayed type (DIAR couplers) which also include a timing moiety or chemical switch which produces a delayed release of inhibitor. Examples of typical inhibitor moieties are: oxazoles, thiazoles, diazoles, triazoles, oxadiazoles, thiadiazoles, oxathiazoles, thiatriazoles, benzotriazoles, tetrazoles, benzimidazoles, indazoles, isoindazoles, mercaptotetrazoles, selenotetrazoles, mercaptobenzothiazoles, selenobenzothiazoles, mercaptobenzoxazoles, selenobenzoxazoles, mercaptobenzimidazoles, selenobenzimidazoles, benzodiazoles, mercaptooxazoles, mercaptothiadiazoles, mercaptothiazoles, mercaptotriazoles, mercaptooxadiazoles, mercaptodiazoles, mercaptooxathiazoles, telleurotetrazoles or benzisodiazoles. In a preferred embodiment, the inhibitor moiety or group is selected from the following formulas: wherein R I is selected from the group consisting of straight and branched alkyls of from 1 to about 8 carbon atoms, benzyl, phenyl, and alkoxy groups and such groups containing none, one or more than one such substituent; R II is selected from R I and -SR I ; R III is a straight or branched alkyl group of from 1 to about 5 carbon atoms and m is from 1 to 3; and R IV is selected from the group consisting of hydrogen, halogens and alkoxy, phenyl and carbonamido groups, -COOR V and -NHCOOR V wherein R V is selected from substituted and unsubstituted alkyl and aryl groups. Although it is typical that the coupler moiety included in the developer inhibitor-releasing coupler forms an image dye corresponding to the layer in which it is located, it may also form a different color as one associated with a different film layer. It may also be useful that the coupler moiety included in the developer inhibitor-releasing coupler forms colorless products and/or products that wash out of the photographic material during processing (so-called "universal" couplers). As mentioned, the developer inhibitor-releasing coupler may include a timing group which produces the time-delayed release of the inhibitor group such as groups utilizing the cleavage reaction of a hemiacetal (U.S. 4,146,396, Japanese Applications 60-249148; 60-249149); groups using an intramolecular nucleophilic substitution reaction (U.S. 4,248,962); groups utilizing an electron transfer reaction along a conjugated system (U.S. 4,409,323; 4,421,845; Japanese Applications 57-188035; 58-98728; 58-209736; 58-209738) groups utilizing ester hydrolysis (German Patent Application (OLS) No. 2,626,315; groups utilizing the cleavage of imino ketals (U.S. 4,546,073); groups that function as a coupler or reducing agent after the coupler reaction (U.S. 4,438,193; U.S. 4,618,571) and groups that combine the features describe above. It is typical that the timing group or moiety is of one of the formulas: wherein IN is the inhibitor moiety, Z is selected from the group consisting of nitro, cyano, alkylsulfonyl; sulfamoyl (-SO 2 NR 2 ); and sulfonamido (-NRSO 2 R) groups; n is 0 or 1; and R VI is selected from the group consisting of substituted and unsubstituted alkyl and phenyl groups. The oxygen atom of each timing group is bonded to the coupling-off position of the respective coupler moiety of the DIAR. Suitable developer inhibitor-releasing couplers for use in the present invention include, but are not limited to, the following: Useful in this invention are tabular grain silver halide emulsions. Specifically contemplated tabular grain emulsions are those in which greater than 50 percent of the total projected area of the emulsion grains are accounted for by tabular grains having a thickness of less than 0.3 µm (micron) (0.5 µm (micron) for blue sensitive emulsion) and an average tabularity (T) of greater than 25 (preferably greater than 100), where the term "tabularity" is employed in its art recognized usage as T = ECD/t 2 where ECD is the average equivalent circular diameter of the tabular grains in micrometers and t is the average thickness in micrometers of the tabular grains. The average useful ECD of photographic emulsions can range up to about 10 micrometers, although in practice emulsion ECD's seldom exceed about 4 micrometers. Since both photographic speed and granularity increase with increasing ECDs, it is generally preferred to employ the smallest tabular grain ECDs compatible with achieving aim speed requirements. Emulsion tabularity increases markedly with reductions in tabular grain thickness. It is generally preferred that aim tabular grain projected areas be satisfied by thin (t < 0.2 micrometer) tabular grains. To achieve the lowest levels of granularity it is preferred that aim tabular grain projected areas be satisfied with ultrathin (t < 0.06 micrometer) tabular grains. Tabular grain thicknesses typically range down to about 0.02 micrometer. However, still lower tabular grain thicknesses are contemplated. For example, Daubendiek et al U.S. Patent 4,672,027 reports a 3 mole percent iodide tabular grain silver bromoiodide emulsion having a grain thickness of 0.017 micrometer. Ultrathin tabular grain high chloride emulsions are disclosed by Maskasky U.S. 5,217,858. As noted above tabular grains of less than the specified thickness account for at least 50 percent of the total grain projected area of the emulsion. To maximize the advantages of high tabularity it is generally preferred that tabular grains satisfying the stated thickness criterion account for the highest conveniently attainable percentage of the total grain projected area of the emulsion. For example, in preferred emulsions, tabular grains satisfying the stated thickness criteria above account for at least 70 percent of the total grain projected area. In the highest performance tabular grain emulsions, tabular grains satisfying the thickness criteria above account for at least 90 percent of total grain projected area. Suitable tabular grain emulsions can be selected from among a variety of conventional teachings, such as those of the following: Research Disclosure, Item 22534, January 1983, published by Kenneth Mason Publications, Ltd., Emsworth, Hampshire P010 7DD, England; U.S. Patent Nos. 4,439,520; 4,414,310; 4,433,048; 4,643,966; 4,647,528; 4,665,012; 4,672,027; 4,678,745; 4,693,964; 4,713,320; 4,722,886; 4,755,456; 4,775,617; 4,797,354; 4,801,522; 4,806,461; 4,835,095; 4,853,322; 4,914,014; 4,962,015; 4,985,350; 5,061,069 and 5,061,616. The emulsions can be surface-sensitive emulsions, i.e., emulsions that form latent images primarily on the surfaces of the silver halide grains, or the emulsions can form internal latent images predominantly in the interior of the silver halide grains. The emulsions are negative-working emulsions, such as surface-sensitive emulsions or unfogged internal latent image-forming emulsions. Photographic elements can be exposed to actinic radiation, typically in the visible region of the spectrum, to form a latent image and can then be processed to form a visible dye image. Processing to form a visible dye image includes the step of contacting the element with a color developing agent to reduce developable silver halide and oxidize the color developing agent. Oxidized color developing agent in turn reacts with the coupler to yield a dye. With negative-working silver halide, the processing step described above provides a negative image. One type of such element is designed for image capture, and speed (the sensitivity of the element to low light conditions) is usually critical to obtaining sufficient image in such elements. When such elements are to be subsequently used to optically generate a color print, they are provided on a transparent support. They may then be processed, for example, in known color negative processes such as described in The British Journal of Photography Annual of 1988, pages 191-198. If such an element is to be employed to generate a viewable projection print as for a motion picture, a process such as the Kodak ECN-2 process described in the H-24 Manual available from Eastman Kodak Co. may be employed to provide the print on a transparent support. Color negative development times are typically 3' 15" or less and desirably 90 or even 60 seconds or less. Elements destined for color reflection prints are provided on a reflective support and may be exposed via optical negative/positive printing and processed, for example, using the Kodak RA-4 process as described in The British Journal of Photography Annual of 1988, Pp 198-199; color projection prints may be processed, for example, in accordance with the Kodak ECP-2 process as described in the H-24 Manual. Reflective color prints are typically provided using silver halide emulsions containing 99% or more of silver chloride, and development times are typically 90 seconds or less and desirably 45 or even 30 seconds or less. To provide a positive (or reversal) image, the color development step can be preceded by development with a non-chromogenic developing agent to develop exposed silver halide, but not form dye, and followed by uniformly fogging the element to render unexposed silver halide developable. Such reversal emulsions are typically sold with instructions to process using a color reversal process such as the Kodak E-6 process. Alternatively, a direct positive emulsion can be employed to obtain a positive image. The above emulsions are typically sold with instructions to process using the appropriate method such as the mentioned color negative (Kodak C-41), color print (Kodak RA-4), or reversal (Kodak E-6) process. Preferred color developing agents are p -phenylenediamines such as: 4-amino-N,N-diethylaniline hydrochloride, 4-amino-3-methyl-N,N-diethylaniline hydrochloride, 4-amino-3-methyl-N-ethyl-N-(2-methanesulfonamidoethyl)aniline sesquisulfate hydrate, 4-amino-3-methyl-N-ethyl-N-(2-hydroxyethyl)aniline sulfate, 4-amino-3-(2-methanesulfonamidoethyl)-N,N-diethylaniline hydrochloride and 4-amino-N-ethyl-N-(2-methoxyethyl)- m -toluidine di- p -toluene sulfonic acid. Development is usually followed by the conventional steps of bleaching, fixing, or bleach-fixing, to remove silver or silver halide, washing, and drying. The coupler useful in the invention is readily prepared through conventional techniques. The following will demonstrate a suitable method. Synthetic Example - Coupler M-1 Synthesis of Compound A (Ethyl alpha nitro isobutyrate) Sodium nitrate 36g (0.52 mol) was dissolved in 600 ml of dimethylformamide and the ethyl bromoisobutyrate (58.5g, 0.3 mol) was added in one portion and the reaction was stirred overnight at room temperature. The reaction was partitioned with diethyl ether and water. The aqueous layer was extracted with additional ether and the combined ether layers were washed with water. The ether was dried with MgSO 4 , and concentrated to yield 42g (87%) of the desired nitro compound. (See N. Kornblum, JACS (1957), vol. 79, p2507 Synthesis of Compound B The sodium salt of nitropropane was prepared from adding 1 equiv. of nitropropane with rapid stirring to a solution of sodium methoxide (1 equiv.) in methanol. The solution is concentrated to a white solid. Compound A (40g, 0.24 mol) was dissolved in DMSO (500 ml) and treated with the nitropopane sodium salt and stirred at room temperature with a UV lamp probe in a sleeve inside the flask for 12 hours. (The use of a light source reduces the reaction time by a factor of 3 to 5.) The reaction was partitioned between water and ligroin. The organic layer was washed with water, dried with MgSO 4 and concentrated to yield 44g (90%) of the desired compound 2. Synthesis of Compound C (Hydrolysis of Compound B) Compound B (40g, 0.2 mol) was mixed with methanol (300 ml) and with sodium hydroxide (40 g of 50% by weight, O.5 mol) and water 100 ml and tetrabutylammonium sulfate (2g) and heated at reflux for 3 days. The reaction was concentrated to remove methanol and extracted with ethyl acetate for remove any unreacted ester. Ice was added to the aqueous layer and a mixture of conc. HCl (42 ml, 0.5 mol) and ice was added carefully. (Note: rapid decarboxylation occurs if the solution warms to room temperature). A white solid is collected, washed with water, and dried to give 22g (63%) of compound C. Synthesis of Acid Chloride Compound D The carboxylic acid compound C (20g, .11 mol) was mixed with dichloromethane (150 ml) and treated with oxalyl chloride (13 ml, 0.15 mol) and a few drops of dimethylformamide. The reaction was stirred at room temperature for 3 hr and concentrated. Synthesis of Compound E The hydrazinothiadiazine hydrochloride salt (24g, 0.11 mol) was mixed with acetonitrile (300 ml) and triethylamine (11g, 0.11 mol) and stirred at room temperature for 15 min. The acid chloride compound D was dissolved in 20 ml of acetonitrile and added dropwise to the thiadiazine mixture. The reaction was stirred overnight and concentrated to a solid. The solid was partitioned between EtOAc and sat'd NaHCO 3 (tetrahydrofuran was added to the organic layer to keep the product from crystallizing out). The organic layer was dried and conc. to yield 27g (71%) of compound E. Synthesis of Compound F Compound E (20g, 0.06 mol) was mixed with acetic acid (100 ml) and heated at reflux for 24 hr. The reaction was diluted with water and a solid was collected. The solid was washed with water and dried to yield 16g (84%) of compound F. Synthesis of Compound G Compound F (10g, 0.03 mol) was mixed with acetic anhydride (100 ml) and heated at reflux for 24 hr. The reaction was cooled to room temperature and carefully treated with conc. HCl (95 ml). The reaction was heated at 60 C for one hour and partitioned between EtOAc and water. The organic layer was washed with sat'd NaHCO 3 until neutralized. The organic layer was dried and concentrated to a solid. The solid was crystallized from heptane to yield 7g (77%) of product. Synthesis of Compound H The nitro compound G (6g) was dissolved in ethanol and treated with 6g of Rainey nickel and shaken with hydrogen at room temperature for 48 hr. The reaction was filtered and concentrated to a thick oil which was carried on. Synthesis of Coupler M- 1 The coupler amine compound H (4g, 0.015 mol) was dissolved in THF and treated with N,N dimethylaniline (1.8g, 0.015), and the ballast acid chloride (7.1g, 0.015 mol) in THF was added dropwise at room temperature for 3 hr. (The ballast acid chloride may be prepared in any well-known manner such as that described in U.S. Patent 4,124,396.) The reaction was concentrated and partitioned between EtOAc and 10% HCl. The organic layer was dried and conc. to a thick oil. The oil was chromatographed with heptane and EtOAc to give (7g, 67%) of product. The product was dissolved with CH 2 Cl 2 and treated with solid N-chlorosuccinimide (2g, .008 mol). The reaction was stirred for 1 hr at room temperature and partitioned with water. The organic layer was dried and conc. to an oil. The oil was chromatographed on silica with heptane and EtOAc to give 5.5g (87%) yield of Coupler M-1. Photographic Examples Dispersions of the couplers were prepared as described below. In one vessel, the coupler, coupler solvent, stabilizers, and ethyl acetate were combined and warmed to dissolve. To this solution was added gelatin, surfactant, and water. After manual mixing the mixture was passed three times through a Gaulin colloid mill. Example 1. The photographic elements were prepared by coating the following layers in the order listed on a resin-coated paper support: 1st layer Gelatin 3.23 g/m 2 2nd layer Gelatin 1.78 g/m 2 Coupler M-1 0.45 g/m 2 Solvent S-1 0.27 g/m 2 Solvent S-2 0.27 g/m 2 Stabilizer St-1 0.18 g/m 2 Stabilizer St-2 0.18 g/m 2 Stabilizer St-23 0.14 g/m 2 Green sensitized AgCl emulsion 0.17 g/m 2 3rd layer Gelatin 1.34 g/m 2 2-(2H-benzotriazol-2-yl)-4,6-bis-(1,1-dimethylpropyl)phenol 0.73 g/m 2 UV-1 - Tinuvin™ 326(Ciba-Geigy) 0.13 g/m 2 Hexanoic acid, 2-ethyl-, 1,4-cyclohexanediyl bis(methylene) ester 0.29 g/m 2 1,4-Benzenediol, 2,5-bis(1,1,3,3-tetamethylbutyl)- 0.18 g/m 2 4th layer Gelatin 1.40 g/m 2 Bis(vinylsulfonylmethyl) ether 0.14 g/m 2 EXPOSING AND PROCESSING OF PHOTOGRAPHIC ELEMENTS The photographic elements were given stepwise exposures to blue light and processed as follows at 35 °C: Developer 45 seconds Bleach-Fix 45 seconds Wash (running water) 1 minute, 30 seconds The developer and bleach-fix were of the following compositions: Developer Water 700.00 mL Triethanolamine 12.41 g Blankophor REU (Mobay Corp.) 2.30 g Lithium polystyrene sulfonate (30%) 0.30 g N,N-Diethylhydroxylamine (85%) 5.40 g Lithium sulfate 2.70 g N- {2-[(4-amino-3-methylphenyl)ethylamino]ethyl}methane sulfonamidesesquisulfate 5.00 g 1-Hydroxyethyl-1,1-diphosphonic acid (60%) 0.81 g Potassium carbonate, anhydrous 21.16 g Potassium chloride 1.60 g Potassium bromide 7.00 mg Water to make 1.00 L pH @ 26.7 °C adjusted to 10.04 +/- 0.05 Bleach-Fix Water 700.00 mL Solution of ammonium thiosulfate (54.4%) + ammonium sulfite (4%) 127.40 g Sodium metabisulfite 10.00 g Acetic acid (glacial) 10.20 g Solution of ammonium ferric ethylenediaminetetraacetate (44%) + ethylenediamine tetraacetic acid (3.5%) 110.40 g Water to make 1.00 L pH @ 26.7 °C adjusted to 5.50 +/- 0.10 PHOTOGRAPHIC TESTS Magenta dyes were formed upon processing. The following photographic characteristics were determined: D max (the maximum density to green light); Speed (the relative log exposure required to yield a density to green light of 1.0); and Contrast (the ratio (S-T)/0.6, where S is the density at a log exposure 0.3 units greater than the Speed value and T is the density at a log exposure 0.3 units less than the Speed value). The combination used in this invention provides comparable and acceptable values for D max Contrast, Speed, and other photographic properties when they are coated, exposed in a controlled manner, and processed as above. This combination also improves the light stability of the magenta dye that is formed using the conventional RA-4™ process. Table I contains data on Status A density losses that are observed from processed strips when they are exposed to 50 klux intensity light for 21 days. Coupler Fade from 1.0 Fade from 1.7 M-1 -0.18 -0.26 M-2 -0.21 -0.32 M-3 -0.20 -0.34 M-4 -0.20 -0.33 M-5 -0.21 -0.32 Comparison 1 -0.24 -0.35 Comparison 2 -0.28 -0.48 Comparison 3 -0.24 -0.37 An analysis of the data shows that the magenta dye formed from the couplers of the invention are more stable to light exposure than the dye formed by the comparison couplers by from 3 to 45 %. Comparison 1 is functionally equivalent to M-34 of EP 0 704 758 and was prepared to demonstrate the importance of the α and β substituents. It is observed that the fade exhibited by the comparison is 24% from 1.0 but is reduced to a value ranging from 18 to 21% when the inventive coupler is employed. Comparison 3 compares closely to M-1 with the difference being that the comparison contains a single ethyl substituent on the α carbon as compared to two α methyl substituents. This comparison shows the same fade % from 1.0 as Comparison 1. Even worse fad is observed for Comparison 3 which contains a β hexylene ring. The column labeled "Fade from 1.7" shows similar improvements for the inventive couplers when measured at this density level. Example 2. Dispersions of the couplers were prepared as below. In one vessel, the coupler, coupler solvent, stabilizers, and ethyl acetate were combined and warmed to dissolve. To this solution was added gelatin, surfactant, and water. After manual mixing the mixture was passed three times through a Gaulin colloid mill. The evaluation format demonstrating this invention used a constant molar laydown of image coupler (0.27 millimoles/m 2 ). The levels of solvents and stabilizers incorporated in the imaging layer were included at a given weight percentage of the coupler. As the weight of the coupler laydown varied due to variation in the molecular weight of the coupler, the level of stabilizers was adjusted to provide constant weight ratios of the solvents and stabilizers to the image coupler. Sample preparation: First Layer Gelatin 3.23 g/m 2 Second Layer Gelatin 2.15 g/m 2 Coupler 0.27 millimoles/m 2 Solvent 3 1.0 times coupler Stabilizer St-1 0.20 times coupler Stabilizer St-2 0.20 times coupler Stabilizer St-23 1.60 times coupler Green sensitized AgCl emulsion 0.17 g/m 2 Third Layer Gelatin 1.34 g/m 2 2-(2H-benzotriazole-2-yl)-4,6-bis-(1,1-dimethylpropyl)phenol 0.73 g/m 2 Tinuvin 326™ (Ciba-Geigy) 0.13 g/m 2 Hexanoic acid, 2-ethyl-1,4-cyclohexanediyl-bis(methylene) ester 0.29 g/m 2 1,4-Benzenediol, 2,5-bis(1,1,3,3-tetramethylbutyl)- 0.18 g/m 2 Fourth Layer Gelatin 1.40 g/m 2 Bis(vinylsulfonylmethyl)ether 0.14 g/m 2 The photographic elements were exposed, processed, and tested as previously described for Example 1. The results are shown in Table II. 3 week 50 Klux Daylight Coupler Fade from 1.0 Fade from 1.7 M-1 -.17 -.25 M-26 -.20 -.31 Comparison 4 -.23 -.35 Comparison 5 -.23 -.34 An analysis of the data shows that the magenta dye formed from the couplers of the invention are more stable to light exposure than the dye formed by couplers containing no substituents or only a substituents on the carbon atoms adjacent to the pyrazoloazole ring. Example 3 An embodiment of the invention is a multilayer element provided on a reflective support and employing silver chloride emulsions and coated as taught in Research Disclosure, September 1996, Item 38957 which is exemplified by the following: Coating Format Laydown mg/m 2 Layer Blue Sensitive Layer Gelatin 1300 Blue sensitive silver 640 Y-1 440 St-24 440 S-1 190 Layer Interlayer Gelatin 650 Sc-2 55 S-1 160 Layer Green Sensitive Layer Gelatin 1100 Green sensitive silver 70 M-1 270 S-1 75 S-3 32 St-2 20 St-1 165 St-23 530 Layer UV Interlayer Gelatin 635 UV-1 30 UV-2 160 Sc-2 50 S-4 30 S-1 30 Layer Red Sensitive Layer Gelatin 1200 Red sensitive silver 170 C-1 365 S-1 360 UV-2 235 S-5 30 Sc-2 3 Layer UV Overcoat Gelatin 440 UV-1 20 UV-2 110 Sc-2 30 S-4 20 S-1 20 Layer SOC Gelatin 490 Sc-2 17 SiO 2 200 Surfactant 2 S-5 CH 3 COOC 2 H 4 OC 2 H 4 OC 4 H 9 St-24 N-t-butyl(acrylamide)/n-butyl acrylate copolymer (50:50)

Claims: A photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula I: wherein X is hydrogen or a coupling-off group; and R' is a tertiary alkyl group and R" represents the group in which R 1 , R 2 , and R 3 are independently selected alkyl groups, provided that any two of R 1 , R 2, and R 3 may join to form a ring; R 4 is hydrogen or a substituent, provided that R 3 and R 4 may join to form a ring when R 4 is a substituent; and W is a substituent selected from the group consisting of -C(O)R 5 , -SO 2 R 5 , and -P(O)(OR 6 ) 2 in which R 5 is selected from the group consisting of alkyl, aryl, alkoxy, aryloxy, alkylamino, and arylamino groups and R 6 is selected from the group consisting of alkyl and aryl groups; provided that the term "group" includes both substituted and unsubstituted forms of the identified group which do not destroy properties necessary for photographic utility. The element of claim 1 wherein R' is selected from the group consisting of a t-butyl group, a 1-methyl-1-cyclopropyl group, a t-octyl group, and an adamantyl group.. The element of claim 1 or 2 wherein X is chloro. The element of claims 1-3 wherein R 1 , R 2 , and R 3 are each alkyl groups of 6 carbons or less. The element of claim 4 wherein R 1 , R 2 , and R 3 are each independently selected from the group consisting of methyl, ethyl, cyclopentyl, and cyclohexyl groups. The element of claim 1-5 wherein R 4 is selected from the group consisting of hydrogen, methyl and ethyl groups. The element of claims 1-6 wherein W is -C(O)R 5 or -SO 2 R 5 . The element of claims 1-7 wherein R' is t-butyl, R 1 through R 4 are alkyl groups and W is -C(O)R 5 where R 5 is an alkyl group. The element of claim 8 wherein R 1 through R 4 are methyl groups and W is -C(O)R 5 where R 5 is an alkyl group. The element of claims 1-9 wherein the element is provided on a reflective support. A process for forming an image in an element as defined in claims 1-10 after the same has been imagewise exposed to light, comprising contacting the element with a color-developing agent.

Inventors: BURNS PAUL ANDREW, HARDER JOHN WILLIAM, SPARA PAUL PATRICK, BURNS, PAUL ANDREW, HARDER, JOHN WILLIAM, SPARA, PAUL PATRICK, Burns, Paul Andrew, Eastman Kodak Company, HARDER, JOHN WILLIAM, EASTMAN KODAK COMPANY, Spara, Paul Patrick, Eastman Kodak Company
Applicants: EASTMAN KODAK CO, EASTMAN KODAK COMPANY
Application year: 1997
Main classification: G03C7
IPC codes: G03C7