FUNCTIONALIZED STYRENE POLYMERS AND COPOLYMERS

Abstract: The present invention provides a functionalized styrenic polymer or copolymer which contains functionalized styrene moiety having formula (I), wherein R1 is hydrogen, alkyl, primary and secondary halo alkyl groups; and R2 is formula (II), where n is an integer of from 2 to about 10, R3 is independently hydrogen or an alkyl group and X is NH, O or S. The novel copolymers of the present invention have particular utility in forming polymer blends. For example, the amine and alcohol functionalized polymers can be used as compatibilizers by reacting them with a carboxylic acid containing polymer or the like.

Description: FUNCTIONALIZED STYRENE POLYMERS AND COPOLYMERS Field ofthe Invention This invention relates to functionalized copolymers of styrene and an isoolefin. Background ofthe Invention Styrene containing polymers, especially copolymers of para-alkylstyrene and an isoolefin having from about 4 to 7 carbon atoms, are well-known in the art. Indeed, copolymers of para-alkylstyrene and isobutylene are low Tg elastomers which possesses low air permeability, unique damping properties, excellent environmental aging resistance and low surface energy which makes them particularly desirable in many applications. Unfortunately, these polymers also have low reactivity and poor compatibility with most other polymers. Thus there is a need for functionalizing styrenic containing polymers and copolymers, especially copolymers of isoolefins and para- alkylstyrene, with more compatible units for blending. It is an object ofthe present invention therefore to functionalize styrene containing polymers with reactive groups which will permit the functionalized polymer to be co-reacted or compatabilized with other polymers by grafting techniques. Summary ofthe Invention Accordingly, the present invention provides a functionalized styrenic polymer or copolymer which contains functionalized styrene moiety having the formula: wherein Ri is hydrogen, alkyl, primary or secondary halo alkyl groups, and R2 is where n is an integer of from 2 to 10, R3 is independently hydrogen or an alkyl group of from 1 to 10 carbon atoms and X is NH, O or S. The novel copolymers ofthe present invention have particular utility in forming polymer blends. For example, the amine and alcohol functionalized polymers can be used as compatabilizers by reacting them with a carboxylic acid containing polymer or the like. Detailed Description ofthe Invention Polymers containing styrene units may be functionalized in accordance with the process ofthe present invention. Particularly suitable styrene containing polymers for functionalization are copolymers of an isoolefin having from about 4 to 7 carbon atoms and a styrene or para-alkylstyrene moiety represented by the formula wherein R\, is a hydrogen, alkyl, primary or secondary halo alkyl which alkyl and halo alkyl groups have from about 1 to about 6 carbon atoms. In the practice ofthe present invention, however, it is particularly preferred to use a copolymer of isobutylene and para-methyl styrene. The foregoing polymers are functionalized by reacting the styrene containing polymer or copolymer with a compound having the formula in the presence of a Lewis acid. In the foregoing formula, R3 is independently hydrogen or an alkyl group of from 1 to about 10 carbon atoms, A is NH, O, S and CO3 and y is an integer of from 2 to 10. In the case when A is NH, R3 preferably is an alkyl group. A specific example of such a compound is methylaziridine. In the case when A is CO3, propylene carbonate is particularly suitable. When A is O, an epoxy, such as epoxy butane is suitable. Finally, ethylene sulfide is useful when A is S. Any Lewis acid catalyst can be used in preparing the functionalized styrene containing polymers; however, the preferred Lewis acid catalysts are based on metals such as boron, aluminum, gallium, indium, titanium, zirconium, tin, arsenic, antimony and bismuth. Especially preferred are the halide containing compounds ofthe foregoing metals such as boron trifluoride, aluminum trichloride, aluminum dichloride and the like. Typically, the functionaliztion will be carried out in the presence of a hydrocarbon diluent such as aliphatic hydrocarbons or in the presence of a polar solvent such as nitrobenzene, methylene chloride, 1, 2 dichloroethane and the like. It is particularly preferred in the practice ofthe present invention to carry out the process in the presence of a solvent. The functionalization ofthe polymers typically is carried out at temperatures of from about -50°C to about 100°C, for times sufficient to add the functional group, i.e., the alkyl amine or alkyl alcohol, to the aromatic ring ofthe styrene containing polymer. The ratio of aziridine, alkylene oxide, or alkylene carbonate to the styrenic units in the styrene containing polymer can vary widely. In general, however, from about 0.01 to 10 mols of aziridine, alkylene oxide or alkylene carbonate per 1 mols of styrenic moieties in the styrene containing polymer will be employed. The following examples illustrate the invention: Example 1 The copolymer of para-methylstyrene and isobutylene utilized in this example contained 7.5 wt.% paramethylstyrene. The copolymer had a Mooney viscosity of 50. 3.00 g of copolymer was dissolved in 30 ml dichloromethane in a three neck flask equipped with condenser, nitrogen bubblier and a dropping funnel. 0.5 g of methylaziridine was added to above solution, followed by 0.22 grams of AICI3. The mixture was stirred at room temperature for 18 hours. The product was isolated by adding to the solution 100 ml of 50:50 acetone/water mixture. The product was washed with acetone and dried. The product contained 0.17% N and the infrared spectra had an absorption peak at 3396 cm"l characteristic ofthe amine functionality. Example 2 The copolymer of isobutylene and para-methylstyrene utilized in this example contained 6.0 wt% paramethylstyrene. The copolymer had weight average molecular weight (Mw) of 5400 and a number average molecular weight (Mm) of 2000 with a polydispersity of 2.7. 2.10 g of copolymer was dissolved in a 30 ml of anhydrous dichloromethane in a three neck flask equipped with condenser, nitrogen bubblier and a dropping funnel. 1.0 g of 1,2-epoxybutane was added to above solution, followed by 1.2 grams of AICI3. The solvent dichloromethane was removed by nitrogen stripping and the product was stirred with 100 ml IN HCl for 1 hour to dissolve aluminum salt. After decanting the liquid phase, the solid product was then washed with acetone and dried under vacuum. The FTIR ofthe product showed characteristic absorption at 3452 cm" for hydroxyl group.

Claims: CLAIMS: 1. A functionalized styrene polymer or copolymer which contains in the polymeric chain monomeric units ofthe formula: wherein R\ is of hydrogen, alkyl, primary or secondary halo alkyl; R2 is where n is an integer of from 2 to 10, R3 is hydrogen or an alkyl group, and X is NH, O or S. 2. The functionalized polymer of claim 1 wherein the styrene polymer is a copolymer of styrene and an isoolefin from about 4 to about 7 carbon atoms. 3. The functionalized copolymer of claim 2 wherein the styrene polymer is a copolymer of para-alkylstyrene and an isoolefin having from about 4 to about 7 carbon atoms. 4. The polymer of claim 3 wherein Ri is methyl. 5. The polymer of claim 3 wherein X is NH. 6. The polymer of claim 3 wherein X is O. 7. The polymer of claim 5 or 6 wherein R3 is an alkyl group of from 1 to about 10 carbon atoms. 8. A method for functionalizing a styrene containing polymer or copolymer comprising: contacting the polymer or copolymer with a compound having the formula: wherein y is an integer of from 2 to about 10, R3 is hydrogen or an alkyl group of from 1 to about 10 carbon atoms and A is NH, CO3, O, or S, the contacting being conducted in the presence of a Lewis acid catalyst at temperatures of from about -50°C to about 100°C for a time sufficient to functionalize the polymer. 9. The method of claim 8 wherein the contacting is conducted in the presence of a solvent and the mole ratio of compound to styrene moiety in the polymer or copolymer ranges from about 0.01 : 1 to about 10: 1. 10. The method of claim 9 wherein A is NH. 11. The method of claim 9 wherein A is O.

Inventors: PATIL ABHIMANYU O, PATIL, ABHIMANYU, O.
Applicants: EXXON RESEARCH ENGINEERING CO, EXXON RESEARCH AND ENGINEERING COMPANY
Application year: 1996
Main classification: C08F8
IPC codes: C08F8, C08F212, C08G81