Process for the alkylation of aromatic compounds

Abstract: Process for the alkylation of aromatic compounds which comprises contacting an olefin with an aromatic hydrocarbon in the presence of a zeolite and under conventional operating conditions, characterized in that the aromatic hydrocarbon, before the alkylation, is: a) treated to eliminate the oxygen dissolved therein; and/or b) percolated through a fixed bed consisting of particles of alumina modified with silver.

Description: The present invention relates to a process for the alkylation of aromatic compounds. More specifically, the present invention relates to a process for the alkylation of aromatic compounds, carried out in the presence of a solid catalyst, and a method for increasing the period of the catalytic activity of said catalyst. The synthesis of alkylaromatic compounds is known in literature. For example, published European patent application 432.814 describes the synthesis of alkylaromatic compounds, such as cumene or ethylbenzene, by reaction between an aromatic hydrocarbon (benzene) and an olefin (propylene or ethylene) in the presence of a Beta zeolite optionally modified by the substitution of aluminium with boron, gallium or iron. More specifically, according to this application, the reagents of the alkylation are contacted with the catalyst at a temperature between 100 and 300°C, at a pressure between 1 and 5 MPa (10-50 atms) and with a flow rate of the reagents such as to give a WHSV (Weight Hourly Space Velocity) between 0.1 and 200 h -1 . Under these operating conditions, the life of the catalyst, intended as the time which passes between two regenerations, is not lengthy. This life of the catalyst however can be improved. The Applicant has in fact found that in a process for the alkylation of aromatic compounds, it is possible to improve the life of the catalyst of the known art with particular treatment of the reagents, described hereunder, suitable for eliminating or considerably reducing the presence of poisons for the catalyst itself. The present invention thererore relates to a process for the alkylation of aromatic compounds which comprises contacting an olefin selected from ethylene and propylene with an aromatic hydrocarbon selected from benzene and C 1 -C 4 alkyl substituted benzene in the presence of a zeolite and under conventional operating conditions, characterized in that the aromatic hydrocarbon, before the alkylation, is: a) treated to eliminate the oxygen dissolved therein; and/or b) percolated through a fixed bed consisting of particles of alumina modified with silver at a temperature ranging between 25 and 250°C. A further object of the present invention relates to a method for increasing the period of the catalytic activity of a zeolite catalyst for the alkylation of an aromatic hydrocarbon with olefins which comprises: a) eliminating from the aromatic hydrocarbon the oxygen dissolved therein; and/or b) percolating the aromatic hydrocarbon thus treated through a filter consisting of a fixed bed of particles of alumina modified with silver. The elimination of the oxygen from the aromatic hydrocarbon can be carried out with the known techniques such as distillation, also under vacuum, or stripping with inert gases, for example with nitrogen. It is also possible to use aromatic hydrocarbons containing from 10 to 25 carbon atoms, or phenols, which are solid at room temperature. In this case treatments (a) and (b) described above are carried out at such a temperature that the hydrocarbon is in the fluid state. According to the present invention, the preferred treatment for eliminating the oxygen dissolved in the aromatic hydrocarbon is stripping with an inert gas, such as nitrogen. This treatment can be carried out with a semi-continuous or continuous technique. In the former case, the aromatic hydrocarbon, kept in a closed container, is flushed with a stream of nitrogen which bubbles through the liquid mass. In the latter case, the aromatic hydrocarbon is flushed with gaseous nitrogen in countercurrent using, for example, filled columns, plate-columns, etc., said columns being fed continuously at the top with the aromatic hydrocarbon and at the bottom with nitrogen in gas phase. The treatment with nitrogen can be carried out at room temperature or at a high temperature, for example between 50 and 250°C, also depending on the physical state of the aromatic hydrocarbon, and at atmospheric pressure or a pressure slightly higher than atmospheric or under vacuum. Whether the treatment with nitrogen is carried out in semi-continuous or in continuous, at room temperature or at a high temperature, it is preferable to operate with gas/liquid volume ratios of between 10 and 300. The percolation on a fixed bed, following the elimination of the oxygen, is carried out through beds of alumina modified with silver. In particular, an alumina modified with 5-7% of silver can be used, having an essentially spherical form and with a particle diameter varying from 2 to 4 mm. In addition, the modified alumina has a density between 0.7 and 0.85 Kg/l and a specific surface between 100 and 200 m 2 /g. The alumina modified with silver according to the present invention can be prepared with the conventional techniques, for example by impregnation with silver salts and subsequent reduction of the ionic silver to metal silver. The percolation is preferably carried out continuously, by percolating the aromatic hydrocarbon, in a gas or liquid phase, on one or more fixed beds. It is preferable to operate with liquid/solid ratios which are such as to give a WHSV between 5 and 100 h -1 . The alkylation of the aromatic hydrocarbon with olefins is carried out with known methods, for example with the method described in published European patent application 432.814. The alkylation of the aromatic hydrocarbon is generally carried out in liquid, gaseous or mixed phase, batchwise, in continuous or semi-continuous mode. The reaction temperature is between 100 and 300°C, preferably between 110 and 200°C, whereas the pressure is between 0,5 and 5 MPa (5-50 bars), preferably between 2,5 and 4 MPa (25-40 bars). The feeding of the reagents, if the operation is carried out in continuous or semi-continuous mode, is arranged to give a WHSV space velocity within the range of 0.1-200 h -1 . The molar ratios aromatic hydrocarbon/olefin are between 2 and 30. Any zeolite able to provide a catalytic activity in the alkylation reaction of aromatic hydrocarbons can be used in the present invention. Examples are Y or Beta zeolites. The Beta zeolite, described in U.S. patent 3.308.069 is preferred. This zeolite is a synthetic porous crystalline material wtith the following composition: [(x/n)M(1+0.1-x)TEA]AlO 2 ySiO 2 wH 2 O wherein x is a number less than 1, y is between 5 and 100, w is equal to 0 or is between 1 and 4, M is a metal belonging to groups IA, IIA, IIIA or is a transition metal and TEA is tetraethyl ammonium. This catalyst can also be used in a modified form by the partial substitution of the aluminium with boron, gallium or iron. At the end of its catalytic activity the catalyst can be regenerated by thermal treatment in air at temperatures between 500 and 800°C. The time between two regenerations, thanks to the process of the present invention, is generally more than 2000-2500 hours. Some applicative but non limiting examples are provided for a better understanding of the present invention and for its embodiment. The Beta zeolite used in the examples was prepared according to the process described in published European patent application 432.814, having a ratio SiO 2 /Al 2 O 3 equal to 20 and a sodium content of about 200 ppm. This zeolite is in the form of microspheres having an average dimension of 8 micrometres, prepared according to the process described in published European patent application 265.018. EXAMPLE 1 (Comparative) 6 g of Beta zeolite are charged into a pressure-resistant reactor having a capacity of 0.5 litres equipped with a mechanical stirrer and electric heating systems. The reactor operates in continuous mode at a pressure of 4 MPa (40 bars) and at a temperature of 190°C. Benzene is fed, with a flow rate arranged to give a WHSV of 17.5 h -1 , together with ethylene with a molar ratio ethylene/benzene equal to 0.2. Downstream of the reactor the alkylated liquid and the non-reacted reagents, subjected to gaschromatographic analysis, are recovered. The test is interrupted when the conversion of the ethylene is equal to about 60%. Figure 1 shows the plot of the percentage of ethylbenzene present in the effluent from the reactor versus the hours on stream. The obtained productivity is equal to 750 g of ethylbenzene per gram of active phase of catalyst. EXAMPLE 2 The same procedure is carried out as in example 1, except that the benzene, before being fed to the reactor, is flushed with nitrogen in gaseous phase at room temperature. The volume ratio nitrogen/benzene is about 300. Figure 1 shows the plot of the percentage of ethylbenzene present in the effluent from the reactor versus the hours on stream. The obtained productivity is equal to 1,750 g of ethylbenzene per gram of active phase of catalyst. EXAMPLE 3 The same procedure is carried out as in example 1, except that the benzene, before being fed to the reactor is percolated, at 190°C under pressure to maintain the benzene in a liquid phase, through a bed of alumina modified with about 6% by weight of silver, having a specific surface of about 175 m 2 /g and essentially spherical particles with a diameter of 2-4 mm. The WHSV is about 12 h -1 . Figure 1 shows the plot of the percentage of ethylbenzene present in the effluent from the reactor versus the hours on stream. The obtained productivity is equal to 2300 g of ethylbenzene per gram of active phase of catalyst. EXAMPLE 4 The same procedure is carried out in example 1, except that the benzene, before being fed to the reactor, is subjected to both treatments of examples 2 and 3. Figure 1 shows the plot of the percentage of ethylbenzene present in the effluent from the reactor versus the hours on stream. The obtained productivity is equal to 3250 g of ethylbenzene per gram of active phase of catalyst.

Claims: A process for the alkylation of aromatic compounds which comprises contacting an olefin selected from ethylene and propylene with an aromatic hydrocarbon selected from benzene and C 1 -C 4 alkyl substituted benzene in the presence of a zeolite and under conventional operating conditions, characterized in that the aromatic hydrocarbon, before the alkylation, is: a) treated to eliminate the oxygen dissolved therein; and/or b) percolated through a fixed bed consisting of particles of alumina modified with silver at a temperature ranging between 25 and 250°C. The process according to claim 1, wherein the elimination of the oxygen from the aromatic hydrocarbon is carried out by distillation or by stripping with nitrogen. The process according to claim 2, wherein the stripping treatment with nitrogen is carried out at room temperature or at temperatures of between 50 and 250°C. The process according to claim 2 or 3, wherein the treatment with nitrogen is carried out with volume ratios gas/liquid of between 10 and 300. The process according to any of the previous claims, wherein the percolation, following the treatment with nitrogen, is carried out through beds of alumina modified with 5-7% by weight of silver. The process according to any of the previous claims, wherein the alumina modified with silver consists of particles having a diameter between 2 and 4 mm. The process according to any of the previous claims, wherein the modified alumina has a density between 0.7 and 0.85 kg/l and a specific surface between 100 and 200 m 2 /g. The process according to any of the previous claims, wherein the percolation operation is carried out with WHSV between 5 and 100 h -1 . A method for increasing the period of the catalytic activity of a zeolite catalyst for the alkylation of an aromatic hydrocarbon selected from benzene and C 1 -C 4 alkyl substituted benzene with olefins selected from ethylene and propylene which comprises: a) eliminating from the aromatic hydrocarbon the oxygen dissolved therein; and/or b) percolating the aromatic hydrocarbon thus treated through a filter consisting of a fixed bed of particles of alumina modified with silver at a temperature ranging between 25 and 250°C.

Inventors: ANDREOLI EUGENIO, BENCINI ELENA, GOFFREDI GINO, ANDREOLI, EUGENIO, BENCINI, ELENA, GOFFREDI, GINO
Applicants: ENICHEM SPA, ENICHEM S.P.A.
Application year: 1996
Main classification: C07C2
IPC codes: C07C2, C07C15, C07C7, B01J29, C07B61