PROCESS FOR PREPARING HOT WATER WHITENING RESISTANT EMULSION PRESSURE SENSITIVE ADHESIVES

Abstract: There is provided clear emulsion acrylic pressure sensitive adhesive polymers which resist water whitening by hot water which are formed by copolymerizing a monomer mixture containing at least one alkyl acrylate ester of an alcohol containing at least 4 carbon atoms, at least one polar comonomer and at least one partially water soluble comonomer present in an amount of at least about 7 % by weight of total monomers. Polymerization is in the presence of at least one nonionic surfactant containing at least about 8 moles of ethylene oxide per mole nonionic surfactant and at least one anionic surfactant containing up to about 10 moles ethylene oxide per mole anionic surfactant. There is added to the product of polymerization at least one base to produce an emulsion having a pH greater than 7 and containing particles having an volume average particle diameter up to about 165 nm as determined by laser light scattering. An electrolyte is post polymerization added to stabilize opacity of adhesive films cast from the emulsion.

Description: PROCESS FOR PREPARING HOT WATER WHITENING RESISTANT EMULSION PRESSURE SENSITIVE ADHESIVES Field of the Invention The invention pertains to clear film emulsion acrylic pressure sensitive adhesives (PSA) which resist whitening by the action of hot water. Background of the Invention A high degree of resistance to water whitening, especially hot water, by pressure sensitive adhesives (PSA's) is required for some label applications. For example, bottles labeled with clear film pressure sensitive adhesive labels can be subjected to pasteurization conditions where the label is expected to remain clear through the process. Historically solvent based adhesives have been used for such demanding applications. Environmental considerations, however, favor elimination of solvents. This and higher coating speeds attainable with emulsion pressure sensitive adhesives, favor their use in place of solvent based pressure sensitive adhesives. Emulsion based pressure sensitive adhesive polymers are made in the presence of surfactants and other water soluble electrolytes such as initiators. In addition, comonomers such as unsaturated carboxylic acids are employed to impart or enhance adhesive properties and tend to be present at the latex-particle interface and remain there during film formation. This had lead to cast films which are sensitive to water and which became cloudy simply when a drop of water was placed on the film. Water whitening is almost assured when the water is hot, e.g., 70°C or more to boiling. The water resistance of emulsion acrylic polymer films has long been addressed in the art particularly with respect to paint films. The art has observed that the presence of water soluble electrolytes, surfactants and polyelectrolytes such as sodium polymethacrylate cause or enhance water sensitivity ("The Applications of Synthetic Resin Emulsions", H. Warson, Ernest Benn Ltd., London, 1972, incorporated herein by reference). It is also well known that surfactants are migratory species that with time move towards and bloom to the surface of films also rendering them water sensitive. The art has taught that the use of low levels of surfactant, a reduction or elimination in soluble electrolytes and crosslinking between the emulsion particles can all serve to improve or impart water resistance. U.S. Patent 5,202,375 to Biale, incorporated herein by reference, teaches for this purpose a polymer emulsion that is synthesized with less than about 1 % by weight surfactant and with high surface tensions (i.e., greater than 45 dynes/cm) and made in the presence of high levels of a crosslinking agent. Although the use of such emulsion polymers as pressure sensitive adhesives is contemplated, no useful PSA properties are reported. Moreover, with such high levels of crosslinking and low levels of surfactant, poor PSA properties would be expected in addition significant stability problems during polymerization. The contemplated use is as a water resistant edge sealer for composite boards and plywood. Low swelling of the films by water after long term drying is used to demonstrate water resistance. European Patent Publication 554832 to Lu et al., incorporated herein by reference, teaches a high solids, moisture resistant pressure sensitive adhesive emulsion polymers. The emulsion polymer is synthesized in the presence of copolymerizable ionic surfactant and in the presence of a hydrophobic polymeric tackifier with a number average molecular weight ranging from 400 to about 50,000. There is no mention of water whitening of the PSA film in the '375 and '832 patent specifications. U.S. Patent 4,994,538 to Lee, et al,. incorporated herein by reference, teaches a silicone acrylate PSA polymer having good water whitening resistance synthesized in the presence of anionic surfactant, Methyl acrylate and vinyl acetate are optionally present. U.S. Patent 5,286,843 to Wood, incorporated herein by reference, teaches a process for improving the water whitening resistance of a PSA by use of ion exchange to remove water soluble ions. The deionized latex is claimed to provide superior resistance to water whitening. Summary of the Invention It has now been found that water whitening can be eliminated or significantly reduced in clear emulsion acrylic pressure sensitive adhesive polymers based on alkyl acrylates by including in the monomer charge at least one partially water soluble comonomer and at least one polar comonomer and forming the copolymers in the presence of a nonionic surfactant containing at least about 8 moles (mols) ethylene oxide per mole (mol) and an ionic surfactant containing less than about 10 moles (mols) ethylene oxide per mole (mol) in which the weight ratio or nonionic to an ionic surfactant is at least about 1 to 1, conducting polymerization under conditions which form particles having volume average diameters up to about 150 nm and in which formed emulsion is neutralized with a base to a pH above 7. The adhesive products formed preferably have an opacity less than about 5%, more preferably less than about 2.5% as measured using the boiling water resistance test as described herein. Opacity is measured on a laminate of a layer of the pressure-sensitive adhesive on a biaxially oriented polypropylene film stock laminated to a 2 mil. polyester release film after exposure of the face stock and adhesive layer to the action of boiling water for ten minutes or ambient temperature water for 60 minutes. Opacity is measured using a spectrocolorimeter. Independent of the opacity characteristics of the adhesive film, opacity can be stabilized against change with time by post polymerization addition to the formed emulsion of an inorganic electrolyte. The adhesive products of the invention provide as part of a label laminate a "no label look". That is a label does not appear to be on a substrate. Detailed Description There is provided, in accordance with the instant invention, clear emulsion acrylic pressure-sensitive adhesive polymer compositions which are substantially unaffected by the action of hot water. The clear emulsion acrylic pressure-sensitive adhesive polymers are comprised of at least one acrylate ester of an alcohol containing at least 4 carbon atoms, at least one partially water soluble comonomer and at least one polar comonomer. They are formed in the presence of a mixture of nonionic and anionic surfactants provided in a weight ratio of at least 1.5: 1 to form utile particles have a volume average particle diameter (particle size) up to about 150nm preferably about 135 nm as measured by laser light scattering preferably using a Nicomp Instrument spectrometer [Model HN 5-90 equipped with and an autocorrellator Model TC-100]. Butylacrylate, 2-ethylhexyl acrylate and mixtures thereof are the preferred alkyl acrylate. Methyl acrylate, methyl methacrylate and mixtures thereof are the preferred partially water soluble comonomers. Acrylic acid is the preferred polar comonomer and is most preferably employed in admixture with another carboxylic acid, preferably methacrylic acid. The formed latex is adjusted to a pH of at least 7. The preferred pH is from about 7.2 to about 9, more preferably from about 7.8 to about 8. Post polymerization addition of a water soluble inorganic electrolyte stabilizes opacity of films formed from the emulsion. Films cast from such an emulsion when dried exhibit outstanding boiling water resistance as demonstrated by low opacity numbers. As used herein, polymer particles means particles of a polymer comprising a "core" and a "shell" surrounding the core. "Interstitial space" as used herein means the space between particles. It is believed in the art that the emulsion particles on drying form a film wherein the surfactant and other water soluble species, such as electrolytes, remain in the interstitial space between the particles. The interstitial space provides channels or pathways for the water molecules to diffuse into the polymer film. When water diffuses into the film, refractive index between the polymer particles and the interstitial space become significantly different leading to light scattering and coloration of the film. This is believed to cause the phenomenon known as "water whitening." It was our initial intent to minimize the presence of water sensitive species and to compatibilize the water sensitive species present with the rest of the polymer and thereby prevent the formation of channels for diffusion of water into the polymer film. "Water sensitive" species include inorganic species such as potassium persulfate and the like and organic species such as surfactants and the like. Boiling Water Resistance Test A boiling water resistance test was developed to simulate the effect of pasteurization and as a standard to determine candidate adhesive polymer opacity. Opacity is the ratio of the reflectance of a sample backed with a white background to that of the sample backed with a black background times 100 and reported as percent opacity. In the test, a pressure sensitive adhesive is coated to a level of 20-22 g/m 2 on a clear 2 mil-biaxially oriented polypropylene (BOPP) (Label-Lyte™ 434, Mobil Corp) dried at 200°F in an oven for 10 minutes and the pressure-sensitive adhesive, film facestock or backing is immersed in a beaker of boiling water (95+°C) for 10 minutes. The pressure sensitive adhesive coated facestock is then immediately laminated to a clear 2 mil polyester (Mylar™) release film (Hostaphan™ ZSLK, Hoechst Diafoil) and the opacity of the resultant laminate determined using a spectrocolorimeter (Hunter Lab colorquest 45/0). Percentage opacity is used as a measure for boiling water resistance. The lower the number, the greater the boiling water resistance. A laminate of a 2 mil BOPP with an optically clear adhesive to a 2 mil Mylar not subjected to the action of boiling water gave opacities of around 0.4 - 0.6%. This is the lowest number expected for such an adhesive laminate. An opacity up to about 2.5% was regarded as good. An opacity above 5% was regarded as poor for applications requiring a non-water whitening pressure sensitive adhesive. Room Temperature Water Resistance Test A room temperature water (ambient) resistance test was also developed. First, the opacity of the 2 mil BOPP film- adhesive layer- 1.5 mil polyester release liner was determined. The polyester liner was removed and the liner-free adhesive pressure sensitive coated BOPP facestock immersed in deionized ambient temperature water for 60 minutes, removed, and re-laminated to the release liner and opacity remeasured. The difference in percentage opacity before and after immersion was noted. With the good water resistant adhesives, a very small increase in opacity was seen with little or no visual differences before and after immersion in water. Without being bound by theory, emulsion particles formed in accordance with this invention are envisioned to have a "core and shell" type structure with the outer shell being more polar than the core and predominantly the result of the copolymerization of an alkyl acrylate with the partially water soluble comonomer and the polar comonomer. The water soluble comonomer is believed to copolymerize in the aqueous phase before being captured by the growing polymer particles. On neutralization with a base, the shell expands to form a hydrophilic zone adjacent to and surrounding the particle core in which hydrophilic species including nonionic and anionic surfactants dissolve or compatibilize. When the level of water soluble comonomer is too low, the hydrophilic zone is small resulting in exclusion of the hydrophilic species leading to poor resistance to water whitening. The pH of the latex was found to be critical to obtaining good opacity and therefor resistance to water whitening. We had expected to obtain high water resistance by maintaining the emulsions at a low pH since carboxyl groups would be less ionized. We unexpectedly found, by contrast, that pH had to be above 7, preferably at least about 7.2, to about 9 or more preferably from about 7 to about 8. The bases which may be used for neutralization include weak bases such as ammonia; strong bases, such as sodium hydroxide; organic amines and the like. The presently preferred and most effective base is ammonium hydroxide. High water resistance is believed to be induced by the increased polarity and size of the hydrophilic shell outside the emulsion particle core in which the hydrophilic species can be compatibilized. The surfactant systems employed during polymerization must be compatible with the whole emulsion polymer i.e., the predominantly hydrophobic alkyl acrylate core and the hydrophilic copolymer shell surrounding the core and thereby determining water whitening resistance of the coated film product. The surfactant(s) employed during polymerization are also important in stabilizing the particles during polymerization and in storage. We have found that with anionic surfactants, the level of ethoxylation has to be about 10 moles per mole surfactant or less, preferably 4 moles (ethylene oxide units per molecule) or less for good water whitening resistance. When the average moles of ethylene oxide is too high, opacities tend to be high. It was also observed that even when good, the opacities are not reproducible when an anionic surfactant was the only surfactant. That is, repeated film drawdowns from the same emulsion gave desirably low opacities at times and undesirably high opacities at other times. Other anionic surfactants and anionic surfactants with higher levels of ethylene oxide (moles per mole) may be used to stabilize the emulsion particles during polymerization or other reasons but do not impart resistance to water whitening. Functional anionic surfactants include lauryl ether sulfates such as Disponil™ FES-32, Disponil™ FES-993 made by Henkel; salts of sulfated nonyl and octyl phenoxy poly(ethyleneoxy) ethanols such as Aerosol™ NPES-458, Aerosol™ NPES-930 made by Cytek Industries; sulfosuccinates such as Aerosol™ 0T-75, Aerosol™ A-501 made by Cytek Industries; aromatic phosphate ester surfactants such as Rhodafac™ PE-510 made by Rhone Poulenc; copolymerizable surfactants such as sulfated acrylic polyethers such as SAM 211 from PPG Industries and the like. Other anionic surfactants useful for polymerization include salts of dodecyl benzene sulfonate, lauryl sulfate and the like may also be used. It was found that nonionic surfactants which are more compatible with the acrylic polymers, and which contain about 8 or more moles ethylene oxide per mole surfactant also tended to compatibilize in the shell and not be present in the interstitial space. In order to ensure good stability in polymerization process and provide particles having good water whitening (boiling water) resistance, it was found necessary to employ a weight ratio of nonionic to anionic surfactants of at least about 1:1, preferably about 1.5 to 1, more preferably from about 1.5:1 to about 6:1, more preferably from about 1.5: 1 to about 4:1. Among the nonionic surfactants that can be used are octyl and nonylphenol ethoxylates such as the Igepal™ surfactants made by Rhone Poulenc; Polystep™ surfactant made by Stepan Chemical Co. and the like. Copolymerizable nonionic surfactants such as SAM 185N nonylphenoxypoly(ethyleneoxy)-ethyl cryl(methacry)lates available from Monomer-Polymer Labs and the like may also be used. The clear emulsion acrylic pressure-sensitive adhesive polymers of the invention are comprised of a predominate amount of one or more alkyl acrylate esters of an alcohol containing at least 4 carbon atoms, at least one partially water soluble comonomer, and at least one polar comonomer. The alkyl acrylate esters serve tb control glass transition temperature (Tg) of the formed polymer and are generally present in an amount of from about 50 to about 90% by weight, and preferably from about 55 to about 85% by weight of total monomers. Alkyl acrylate esters of an alcohol which form the bulk of the monomers of the core and which contain at least 4 carbon atoms in the alkyl group of the alcohol include, among others, n-butyl acrylate, 2-ethyl hexyl acrylate, hexyl acrylate, decyl acrylate, dodecyl acrylate, isooctylacrylate and the like. Methacrylates can also be used. N-butyl acrylate, 2-ethyl hexyl acrylate and mixtures thereof are presently preferred. A partially water soluble comonomer is required to ensure adequate boiling water or water whitening resistance. It is believed that this comonomer copolymerizes with the polar comonomer and alkyl acrylate ester to form the shell around the emulsion particle core that compatibilizes electrolytes and the anionic surfactant. Partially water soluble comonomers including methyl acrylate, ethyl acrylate, methyl methacrylate, vinyl acetate and the like may used in order to obtain the desired opacity. Methyl acrylate (5.6% by weight soluble in water @45°C) and/or methyl methacrylate (1.5% by weight soluble in water @ 45 °C) are preferred. The partially water soluble monomer content is above about 7% preferably from about 8% to about 25% by weight of total monomers. Levels of about 8 to about 20% provides by weight of monomers optimum opacity and levels above about 10% are generally not required except to modify adhesive properties or glass transition temperature. In addition to partially water soluble comonomer, a highly polar comonomer is required to be present. The amount of polar comonomer is generally in the range of from about 1 to about 10% by weight of the monomers. The preferred polar comonomers are carboxylic acids containing from 3 to about 5 carbon atoms. Acrylic acid and a mixture of acrylic and methacrylic acids are presently preferred. Among the carboxylic acids, there may be mentioned acrylic acid, methacrylic acid, maleic acid, fumaric, itaconic acid, and the like. Results to date show that use of a mixture of polar monomers synegistically gives an opacity lower than the same amount of each polar monomer separately. It is well known in the literature that methacrylic acid tends to become buried inside the particle core to a greater extent than acrylic acid during emulsion polymerization. Combination of polar monomers which tend to partition differently between the polymer particles and the aqueous phase during emulsion polymerization may therefore be effectively used to provide a shell which solubilizes hydrophilic species. Other polar comonomers containing carboxylic and hydroxyl groups can also be used. Examples of such polar comonomers could be beta-carboxyethyl acrylate, monomethacryloylethyl succinate, monomethacryloylethyl phthalate, polyethylene(propylene) glycol monoacry(methacry)lates, 2-hydroxyethyl acry(methacry)late, 2-hydroxypropyl acry(methacry)lates and the like. Other modifying monomers for the clear emulsion acrylic polymers include one or more diesters of a dicarboxylic acid wherein each ester group of the diester acid independently contains from about 8 to about 16, preferably from about 8 to about 12 carbon atoms. Examples of diesters are di-2-ethyl hexyl maleate, di-2- ethyl hexyl fiimarate and mixtures thereof. Other comonomers, such as styrene, tertiary butyl styrene and the like, may be used to modify the Tg or other copolymer properties. Other comonomers including N-vinyl caprolactam, hydroxyethyl (propyl) (meth)acrylate, acetoacetoxyethyl (meth)acrylate, and the like, could be used to further enhance adhesion to various surfaces and partitioning between the aqueous and particle phases while other comonomers, such as glycidyl methacrylate or allyl glycidyl ether, can also be used to further enhance high temperature shear properties. Multifunctional acrylates can also be used to cause cross linking and improve shear properties. Chemical cross-linkers provided in an amount of up to about 1 % by weight, can be effectively used to further increase cohesive strength. These include chromium acetate, zirconium ammonium carbonate, aluminum acetate and the like. Cross-linking may also be achieved using actinic or electron beam radiation. The copolymers of the instant invention can be stabilized against UV and oxidative degradation by using UV stabilizers and antioxidants. In addition, fillers, colorants and the like, tackifiers, plasticizers and oils may be added to modify the properties of the clear acrylic emulsion polymers of this invention. The monomer proportions of the clear acrylic polymer are typically adjusted in such a way that the pressure sensitive adhesive polymer have a glass transition temperature of least 10°C below use temperature and preferably be from about 0°C to about -60°C as measured by a differential scanning calorimeter. Use temperature is the temperature at which a facestock-adhesive laminate is typically applied to a substrate and is normally 25°C. In any event, the polymer has to be designed to convert well, i.e., to slit, diecut, matrix strip, run on printing presses and be dispensed from labelling machinery to clear substrates such as glass bottles. The clear emulsion acrylic polymers of this invention are to provide adhesion and tack at room temperature, elevated and low temperatures to glass and coated glass or other clear surfaces. What is essential is that they provide low opacities by the boiling water resistance test or minimal changes in opacity by the resistance test to room temperature water. Polymerization can be carried out in the presence of electrolytes such as tetrasodium pyrophosphate to regulate particle size and emulsion viscosity. Electrolytes generally cause particle size to increase with an increase in electrolyte content and this can increase opacity. Independent of the use of electrolytes during polymerization, it was unexpectedly found that on post- polymerization addition of small levels of an inorganic electrolyte to the latex stabilizes the latex against increases in opacity with time. This was unexpected because the relevant literature makes clear that water resistance would be adversely affected by the addition of water sensitive species such as electrolytes. However, our results clearly demonstrate the films containing added inorganic electrolytes even after long term aging retained the initial level of opacity. The amount to electrolyte to be added will range from about 0.025 to about 0.25, preferably from about 0.03 to about 0.1 percent by weight of the emulsion. It is presently preferred to employ as added electrolyte alkali metal sulfates, alkaline earth metal sulfates, alkali metal acetates, alkaline earth metal acetates, alkali metal phosphates, alkaline earth metal phosphates and the preferred metal is sodium. Particle size also controls opacity. Volume average particle diameters up to about 150 nm measured using the Nicomp Instrument spectrometer were found to have good opacities while emulsions having a larger volume average particle diameter had greater opacities than required for use as a clear pressure sensitive adhesive. Conventional water soluble free radical initiators can be used for polymerization. They include potassium, ammonium and sodium persulfates. Other initiators such as water soluble azo initiators (such as Wako V-50 made by Wako Chemicals USA, Inc), redox initiators such as persulfate/bisulfite catalyst systems can also be used. The results indicate that a small amount of strong acid groups may be necessary in the outer shell of the polymer particles to compatibilize with the strong acid groups of the anionic surfactant. Results also indicate that with low or no persulfate content, opacities are high. This is contrary to expectation since higher water resistance as indicated by the absence of such water sensitive sulfate groups at the surface was regarded as important to good water whitening resistance. The emulsion polymers of the instant invention are framed at a solids level of 45 % by weight solids or more preferably from 50% to 60% by weight solids and when cast from emulsion onto a face stock (direct coating) or transferred from a release lever or surface to a face stock (transfer coated) are to provide clear coating at coat weights of about 20 to about 22 grams per square meter with low percentage opacities as per the boiling water resistance test. Percent opacity of the cast film should be about 5% or less, preferably 2.5% or less about preferably 1.5% or less as determined in the boiling water resistance test or remain essentially unchanged in the room temperature water resistance test. Direct coated film laminates generally give lower opacities than transfer coated film laminates. In addition to the Boiling Water Resistance and Room Temperature Water Resistance Tests, the following tests were also performed. Room Temperature Shear Room temperature shear was measured by applying samples of adhesive coated film measuring 1.25 cmx 5 cm strips to a 1.25 x 1.25 cm area of the stainless steel panel. The film is rolled down twice with a 2 kg rubber-clad roller at the rate of 30 cm/min. The panel is then clamped in a vertical position with 500 g weight attached to the exposure end of the strip. The time elapsed before the weight cm pulls the sample from the panel is measured in minutes. % Gel The % gel content was measured by placing an amount of dry adhesive, eg. 75 mg., in a 10 micron polytetrafluoroethylene membrane filter. The edges of the membrane are sealed to contain the sample and placed in a 20 ml. vial containing tetrahydrofuran. The vial is tumbled for 24 hours, filter taken out and dried at elevated temperature under vacuum. The filter is weighed and the percent insolubles is calculated by the formula: % Insolubles = final weight of sample X 100 initial weight of sample Hot Water Bottle Peel The clear film labels employing the adhesives of this invention are normally applied to glass bottles with minimum application pressure. The adhesive is formulated to wet out rapidly on bottles so as to give a "no label look" within about 24 hours of application. During bottle making, the glass bottles may be treated with ingredients to prevent the bottles from scratching. The adhesive should also adhere to such treated surfaces and maintain good adhesion characteristics even under severe conditions such as exposure to high water temperatures. This characteristic is determined by what is known as a hot water bottle peel test (HWBP). In this test, a 1" x 8" strip of adhesive coated on BOPP facestock at a coat weight of 20-22 grams per square meter is applied to a glass bottle with no applied pressure, allowed to dwell for 20 minutes and then immersed in a water maintained at 77°C for 0.5 hour. At the end of this period, the bottle is taken out and 90 peel immediately measured. Peel is reported in Newtons per meter (n/m). The following data is provided to illustrate as regarded as significant towards obtaining and maintaining clear emulsion acrylic polymers of desired opacity which resist water whitening as determined by particle size and/or opacity. Attached Table I contains the meaning of certain abbreviations in Tables II to Table IX. Example 1 There was formed a reactor charge containing a solution of 1.14 g of Disponil FES-32 (32% solids, manufactured by Henkel) dissolved in 123 g of deionized water. A pre- emulsion feed soap solution was formed by dissolving 0.34 g of Aerosol OT-75 (75% solids, Cytec), 0.5 g Aerosol A501:(507 Cytek), 2.27 g of Disponil FES-32 and 4.19 g of Polystep F-4 (Stepan Chemical) in 93 g of deionized water. A monomer mix was made up with 222.4 g of 2-ethyl hexyl acrylate, 73 g of n-butyl acrylate, 52 of methyl acrylate, 6.3 g of methacrylic acid, 9 g of acrylic acid and 0.037 g of n-dodecyl mercaptan. The monomer mix was added to the pre-emulsion solution with mixing and was stirred till the viscosity was about 2000 cps (Brookfield, RV,#3 @ 12 rpm). An "Aqueous Feed" solution was prepared by dissolving 1 g of potassium persulfate in 106 g of deionized water. A kickoff initiator solution was formed of 0.75 g of potassium persulate in 15 g of deionized water. The reactor charge was introduced to a 1 liter reactor which was flushed with nitrogen. The reactor charge was heated to 78 °C and the kickoff initiator solution added. The mixture were held for 10 minutes at 78°C. The pre-emulsion feed was started at the rate of 1.99 g/min. Ten minutes after start of pre-emulsion feed, the Aqueous Feed was added at the rate of 0.89 g/min. The pre-emulsion was added over four hours. Aqueous Feed was added over 4 hours. Through out the feeds, the temperature inside the reactor was maintained at about 80°C. After the feeds were completed, the contents were held at 80°C for an additional 45 minutes and then cooled. The final pH was 3.1. The latex was neutralized with a dilute ammonium hydroxide solution to a pH of 7.9. The final latex solids were 57.3 % , and viscosity was 3150 cps (Brookfield, RV, #4@20rpm) and particle diameter was 112 nm. The latex was coated directly onto a 2 mil BOPP facestock (Mobil-Labelyte 434), dried in an oven at 70°C for 10 minutes to a dry coat weight of 20-22 grams per square meter and laminated to a 1.5 mil polyester release liner. A sample cut out from this laminate was used for measuring boiling water resistance, the release liner was removed, the adhesive- facestock laminate immersed in boiling water and its opacity after exposure to boiling water for 10 minutes in the test was found to be 1.21 %. When the cold water test was applied for the products of Example 1 in comparison to a normally clear commercial general purpose permanent (GPP) pressure sensitive adhesive, the percentage opacity of the product of Example 1 increased by 0.31 while the percentage point increase in opacity of the GPP adhesive was 12 percentage points. Example 2 There was formed a reactor charge containing a solution of 0.65 g of Disponil FES- 32, 0.35 g of Polystep G-5, 0.16 g of Aerosol A-501 dissolved in 123 g of deionized water. A pre-emulsion feed soap solution was formed by dissolving 0.34 g of Aerosol OT-75, 0.34 g of Aerosol A-501, 2.27 g of Disponil FES-32 and 3.88 g of Polystep F-5 in 110 g of deionized water. A monomer mix was made up with 217.4 g of 2-ethyl hexyl acrylate, 84 g of n-butyl acrylate, 46 of methyl methacrylate, 6.5 g of methacrylic acid, 9.1 g of acrylic acid and 0.248 g of n-dodecyl mercaptan. The monomer mix was added to the pre-emulsion solution with mixing and was stirred till the viscosity was about 2000 cps (Brookfield, RV,#3 @ 12 rpm). An "Aqueous Feed" solution was prepared by dissolving 1 g of potassium persulfate in 106 g of deionized water. A kickoff initiator solution was formed of 0.75 g of potassium persulate in 15 g of deionized water. The reactor charge was introduced to a 1 liter reactor which was flushed with nitrogen. The reactor charge was heated to 78°C and the kickoff initiator solution added. The mixture were held for 10 minutes at 78°C. The pre-emulsion feed was started at the rate of 1.99 g/min. Ten minutes after start of pre-emulsion feed, the Aqueous Feed was added at the rate of 0.89 g/min over 4 hours. Through out the feeds, the temperature inside the reactor was maintained at about 80° C. After the feeds were completed, the contents were held at 80°C for an additional 45 minutes and then cooled. The final solids was 51.4%, pH was 3.2 and latex viscosity was 400 cps (Brookfield, RV, #@20 φm). The latex was neutralized with a dilute ammonium hydroxide solution to a pH of 7.8. The final viscosity was 3350 cps (Brookfield, RV, #4@20rpm) and particle diameter was 124 nm. The latex was coated directly onto a 2 mil BOPP facestock (Mobil-Labelyte 434), dried in an oven at 70 °C for 10 minutes to a dry coat weight of 20-22 grams per square meter and laminated to a 1.5 mil polyester release liner. A sample cut out from this laminate was used for measuring boiling water resistance, the release liner was removed, the adhesive- facestock laminate immersed in boiling water and its opacity after exposure to boiling water for 10 minutes in the test was found to be 1.35%. When the cold water test was applied for the products of Example 1 in comparison to a normally clear commercial general purpose permanent (GPP) pressure sensitive adhesive, the percentage opacity point of the product of Example 1 increased by 0.31 while the percentage point increase in opacity of the GPP adhesive was 12 percentage points. Example 3 There was formed a reactor charge containing a solution of 0.9 g of Disponil FES-32 (32% solids, manufactured by Henkel) disssolved in 123 g of deionized water. A pre- emulsion feed soap solution was formed by dissolving 0.39 g of Aerosol OT-75 (75% solids, Cytec), 2.61 g of Disponil FES-32 and 3.9 g of Polystep F-4 in 110 g of deionized water. A monomer mix was made up with 240 g of 2-ethyl hexyl acrylate, 55 g of n-butyl acrylate, 55 of methyl methacrylate, 6.5 g of methacrylic acid, 9.1 g of acrylic acid and 0.238 g of n-dodecyl mercaptan. The monomer mix was added to the pre-emulsion solution with mixing and was stirred till the viscosity was about 2000 cps (Brookfield, RV,#3 @ 12 rpm). An "Aqueous Feed 1" solution was prepared by dissolving 0.74 g of of Disponil FES- 32, 1.25 g Polystep F-5 and 0.5 g of potassium persulfate in 70 g of deionized water. An "Aqueous Feed 2" solutio was prepared by mixing 0.50 g of potassium persulfate in 50 g of deionized water. A kickoff initiator solution was formed of 0.75 g of potassium persulate in 15 g of deionized water. The reactor charge was introduced to a 1 liter reactor and was flushed with nitrogen. The reactor charge was heated to 78 °C and the kickoff initiator solution added. T e mixture were held for 10 minutes at 78°C. The pre-emulsion feed was started at the rate of 1.99 g/min. Ten minutes after start of pre-emulsion feed, the Aqueous Feed 1 was added at the rate of 0.6 g/min. The pre-emulsion was added over four hours. Aqueous Feed 1 was added over two hours. After completion of addition of the Aqueous Feed 1, Aqueous Feed 2 was started and added at the rate of 0.42 g/min. for two hours. Through out the feeds, the temperature inside the reactor was maintained at about 80 °C. After the feeds were completed, the contents were held at 80 °C for an additional 45 minutes and then cooled. The final solids was 50.441 %, pH was 2.3 and lates viscosity was 480 cps (Brookfield, RV, #4@20rpm). The latex was neutralized with a dilute ammonium hydroxide solution to a pH of 7 g. The final viscosity was 3100 cps (Brookfield, RV, #4@20rpm) and particle diameter was 114nm. The latex was coated directly onto a 2 mil BOPP facestock (Mobii-Labelyte 434), dried in an oven at 70°C for 10 minutes to a dry coat weight of 20-22 grams per square meter and laminated to a 1.5 mil polyester release liner. A sample cut out from this laminate was used for measuring boiling water resistance, the release liner was removed, the adhesive- facestock laminate immersed in boiling water and its opacity after exposure to boiling water for 10 minutes in the test was found to be 1. 1 %. When the cold water test was applied for the products of Example 1 in comparison to a normally clear commercial general purpose permanent (GPP) pressure sensitive adhesive, the percentage opacity point of the product of Example 1 increased by 0.31 while the percentage point increase in opacity of the GPP adhesive was 12 percentage points. Example 4 There was formed a reactor charge containing a solution of 0.9 g of Disponil FES-32 dissolved in 123 g of deionized water. A pre-emulsion feed soap solution was formed by dissolving 0.34 g of Aerosol OT-75, and 4.19 g of Polystep F-5 (Stepan Chemical) in 105 g of deionized water. A monomer mix was made up with 240 g of 2-ethyl hexyl acrylate, 55 g of n-butyl acrylate, 55 of methyl methacrylate, 6.5 g of methacrylic acid, 9.2 g of acrylic acid and 0.238 g of n-dodecyl mercaptan. The monomer mix was added to the pre-emulsion solution with mixing and was stirred till the viscosity was about 2000 cps (Brookfield, RV,#3 @ 12 rpm). An "Aqueous Feed 1" solution was prepared by dissolving 1.5 g of Polystep F-5 and 0.5 g of potassium persulfate in 60 g of deionized water. An "Aqueous Feed 2" solution was prepared by mixing 0.5 g of potassium persulfate in 60 g of deionized water. A kickoff initiator solution was formed of 0.75 g of potassium persulate in 15 g of deionized water. The reactor charge was introduced to a 1 liter reactor which was flushed with nitrogen. The reactor charge was heated to 78°C and the kickoff initiator solution added. The mixture were held for 10 minutes at 78 °C. The pre-emulsion feed was started at the rate of 1.99 g/min. Ten minutes after start of pre-emulsion feed, the Aqueous Feed 1 was added at the rate of 0.6 g/min. The pre-emulsion was added over four hours. Aqueous Feed 1 was added over two hours. After completion of addition of the Aqueous Feed 1, Aqueous Feed 2 was started and added at the rate of 0.42 g/min for tow hours. Through out the feeds, the temperature inside the reactor was maintained at about 80°C. After the feeds were completed, the contents were held at 80 °C for an additional 45 minutes and then cooled. The final solids was 50.5%, pH was 2.52 and lates viscosity was 420 cps (Brookfield, RV, #4@20rpm). The latex was neutralized with a dilute ammonium hydroxide solution to a pH of 7.9. The particle diameter was 137 nm. The latex was coated directly onto a 2 mil BOPP facestock (Mobil-Labelyte 434), dried in an oven at 70°C for 10 minutes to a dry coat weight of 20-22 grams per square meter and laminated to a 1.5 mil polyester release liner. A sample cut out from this laminate was used for measuring boiling water resistance, the release liner was removed, the adhesive- facestock laminate immersed in boiling water and its opacity after exposure to boiling water for 10 minutes in the test was found to be 0.8%. When the cold water test was applied for the products of Example 1 in comparison to a normally clear commercial general purpose permanent (GPP) pressure sensitive adhesive, the percentage opacity point of the product of Example 1 increased by 0.31 while the percentage point increase in opacity of the GPP adhesive was 12 percentage points. Example 5 There was formed a reactor charge containing a solution of 0.855 g of Disponil FES- 32 (32% solids, manufactured by Henkel) dissolved in 123 g of deionized water. A pre- emulsion feed soap solution was formed by dissolving 2.7 g of SAM 211 (80% solids, PPG), 0.69 g tetrasodium pyrophosphate and 3.37 g of Polystep F-4 (Stepan Chemical) in 93 g of deionized water. A monomer mix was made up with 287.4 g of 2-ethyl hexyl acrylate, 59 of methyl methacrylate, 6.3 g of methacrylic acid, 9 g of acrylic acid and 0.24 g of n-dodecyl mercaptan. The monomer mix was added to the pre-emulsion solution with mixing and was stirred till the viscosity was about 2000 cps (Brookfield, RV,#3 @ 12 rpm). An "Aqueous Feed 1" solution was prepared by dissolving 0.3g of SAM 211, 1.24 g of Polystep F-5 and 0.5 g of potassium persulfate in 77 g of deionized water. The "Aqueous Feed 2" solution was prepared by mixing 0.5 g of potassium persulfate in 53 g of deionized water. The reactor charge was introduced to a 1 liter reactor which was flushed with nitrogen. The reactor charge was heated to 78°C and the kickoff initiator solution added. The mixture were held for 10 minutes at 78 C C. The pre-emulsion feed was started at the rate of 1.99 g/min. Ten minutes after start of pre-emulsion feed, the Aqueous Feed 1 was added at the rate of 0.60 g/min. The pre-emulsion was added over four hours. Aqueous Feed 1 was added over two hours. After completion of the Aquious Feed 1, Aquious Feed 2 was started and added at the rate of 0.42 g/min for two hours. Through out the feeds, the temperature inside the reactor was maintained at about 80°C. After the feeds were completed, the contents were held at 80 °C for an additional 45 minutes and then cooled. The pH was 2.8 and latex viscosity was 200 cps (Brookfield, RV, #4@20rpm). The latex was neutralized with a dilute ammonium hydroxide solution to a pH of 7.8. The final latex solids were 49.4%, viscosity was 7300 cps (Brookfield, RV, #4@20rpm) and particle diameter was 136 nm. The latex was coated directly onto a 2 mil BOPP facestock (Mobil-Labelyte 434), dried in an oven at 70°C for 10 minutes to a dry coat weight of 20-22 grams per square meter and laminated to a 1.5 mil polyester release liner. A sample cut out from this laminate was used for measuring boiling water resistance, the release liner was removed, the adhesive- facestock laminate immersed in boiling water and its opacity after exposure to boiling water for 10 minutes in the test was found to be 1.27%. When the cold water test was applied for the products of Example 1 in comparison to a normally clear commercial general purpose permanent (GPP) pressure sensitive adhesive, the percentage opacity point of the product of Example 1 increased by 0.31 while the percentage point increase in opacity of the GPP adhesive was 12 percentage points. Examples 6-27 and Table II Table II shows the effect of surfactant choice on opacity. The principal surfactant employed was "Anionic 1." "Anionic 2" contained no ethylene oxide units while "Anionic 3" was a proprietary blend contained an unknown amount of ethylene oxide units. The supplemental anionics were useful for other conditions such as stabilization of the emulsion. An opacity of about 2.5% or less may be regarded as "good" while products having an opacity less than 5 may also be employed. We found that with an anionic surfactant, the level of ethoxylation has to be below about 10 moles per mole for good hot water resistance. When the moles of ethylene oxide were about 10 or at times when at 10, higher opacities were obtained. When a anionic surfactant was the only surfactant system employed, opacities were not reproducible. (See Example 6) that is, opacity varied significantly from drawdown to drawdown, where drawdown is the forming of a coated layer to a coat level of 20-22 g/sq. meter. This lead to the use of a non-anionic surfactant. Employing an anionic surfactant of 4 ethylene oxide units and a nonionic surfactant of 8 or more ethylene oxide units gave very low opacities. Without being bound by theory, it is believed that the nonionic surfactants which are compatible with the acrylic polymers are present to the lesser degree in the interstitial spaces between particles. Examples 28 to 38 and Table ITI The partly water soluble monomer is believed to be primarily present in the shell of the polymer particle and renders the particle more hydrophilic by polymerizing with the polar comonomer and the alkyl acrylate to provide a transition from a hydrophobic core which is primarily an alkyl acrylate outward to a polar end group which imparts hydrophilicity. This allows the surfactants to disperse within the shell of the polymer particle enhancing resistance to water whitening as indicated by low opacity. The absence of partly water soluble comonomer resulted in too high in opacity (Ex. 24) or significantly inconsistent opacities (Ex. 26 and 30). Examples 39 to 43 and Table IV Table IV shows the effect of particle size on opacity in that a variety of polymers formed having a volume average particle diameter approaching 150nm had borderline opacities. When particle diameter was 198 nm opacity was unacceptable. The preferred upper volume average particle diameter is 135 nm. Examples 44-49 and Table V Table V shows the effect of initiator on opacity. The results show that when too little persulfate is employed or is absent, opacities are high indicating the likelihood that persulfate beneficially provides water sensitive sulfate groups at the surface of the shell of the polymer. This is contrary to expectation since a lack of sulfate groups would have been expected to induce water-resistance by eliminating the presence of water sensitive groups in the shell. Examples 50-56 and Table VI Table VI, independent of surfactant system, shows the general effect of carboxylic acid on opacity. Acrylic acid and mixtures of methacrylic and acrylic acids gave significantly better opacities than methacrylic acid alone. Examples 57 to 69 and Table VH Table Vn, shows effect on pH and base on opacity. Below a pH of seven opacities are quite high. The best results are obtained for ammonium hydroxide at a pH above 7.0. Examples 70 to 79 and Table VIII Table VIII shows the effect of use cross linking monomers and chain transfer agents on bottle peel and shear. Examples 76 to 85 and Table IX Table IX shows the effect of post polymerization addition of an electrolyte to the emulsion on changes in opacity with time. The starting point (Ex. 80 and 84) were the emulsions as formed with addition of ammonium hydroxide to a pH of 7.5-8.0. For Examples 80 and 84 no electrolyte was post polymerization added and opacity of films drawn from the emulsion increase significantly with days(d) of aging whether at room temperature or 50°C. When an electrolyte was added post polymerization retention of initial opacity was significant. Example 5 which had an initial opacity of 1.27 and to which no electrolyte was added after polymerization had an opacity of 3.03 after exposure to 50° C for two days. Table I EHA - 2 ethyl hexyl acrylate BA - n-butyl acrylate MeA or MA-methyl acrylate MMA - methylmethacrylate MAA - methacrylic acid AA - acrylic acid TSPP - tetrasodium pyrophosphate Disponil FES-77 - sodium lauryl ether sulfate - 30 moles ethylene oxide (Henkel) Disponil FES-993 - sodium lauryl ether sulfate - 10 moles ethylene oxide (Henkel) Disponil FES-32 - sodium lauryl ether sulfate - 4 moles ethylene oxide (Henkel) Aerosol A-501 - proprietary monoester sulfosuccinate (Cytek) Aerosol OT-75 - sodium dioctyl sulfosuccinate (Cytek) NPES-930 - ammonium salt of sulfated nonylphenoxy poly(ethyleneoxy)ethanol - 9 moles Ethylene oxide (Cytek) Rhodafac PE-510 aromatic phosphate ester - 6 moles ethylene oxide (Rhone Poulenc) Polystep F4 - nonylphenol ethoxylate - 10 moles ethylene oxide (Stepan) Polystep F5 - nonylphenol ethoxylate - 12 moles ethylene oxide (Stepan) Polystep F3 - nonylphenol ethoxylate - 8 moles ethylene oxide (Stepan) Igepal CO-850 - nonylphenolethoxyiate - 20 moles ethylene oxide (Rhone Poulenc) Igepal CO-887 - nonylphenolethoxyiate - 30 moles ethylene oxide (Rhone Poulenc) SAM 211 - surface active monomer - 15 moles ethylene oxide (PPG) HEA - hydroxyethyl acrylate VAc - vinyl acetate HDODA - hexanediol diacrylate n-DDM - n-dodecyl mercaptan pphm - parts hundred parts parts monomers PSize - particle diameter

Claims: WHAT IS CLAIMED IS: 1. A process for the production of clear emulsion acrylic pressure sensitive adhesives copolymers which resist water whitening which comprises copolymenzing a mixture of monomers containing at least one alkyl acrylate ester of an alcohol containing at least 4 carbon atoms, at least one polar comonomer and at least one partially water soluble comonomer present in an amount of at least about 7% by weight of total monomers and dispersed in an aqueous polymerization media in the presence of at least one nonionic surfactant containing at least about 8 moles of ethylene oxide per mole nonionic surfactant and at least one anionic surfactant containing up to about 10 moles ethylene oxide per mole anionic surfactant. 2. A process as claimed in claim 1 in which the pH is from about 7.2 to about 9. 3. A process as claimed in claim 1 in which the pH is from about 7.8 to about 8. 4. A process as claimed in claim 1, 2 or 3 in which the partially water soluble comonomer is present in an amount of from about 8 to about 25% by weight of the total monomers. 5. A process as claimed in claim 1, 2 or 3 in which the partially water soluble comonomer is present in an amount of from about 8 to about 20% by weight of the total monomers. 6. A process as claimed in any one of the previous claims in which the partially water soluble comonomer is selected from the group consisting of methyl acrylate, methyl methacrylate and mixtures thereof. 7. A process as claimed in any one of the previous claims in which the polar comonomer is selected from the group consisting of acrylic acid and a mixture of acrylic acid and methacrylic acid. 8. A process as claimed in any one of claims 1 to 7 in which the weight ratio of nonionic surfactant to anionic surfactant is about 1 to 1. 9. A process as claimed in any one of claims 1 to 7 in which the weight ratio of nonionic surfactant to anionic surfactant is about 1.5:1 to 3:1. 10. A process as claimed in any one of the previous claims in which the anionic surfactant contains about 4 moles of ethylene oxide per mole of anionic surfactant. 11. A process as claimed in any one of the previous claims in which the base is ammonium hydroxide. 12. A process as claimed in any one of the previous claims in which based on the total weight of monomers alkyl acrylate ester of an alcohol containing at least 4 carbon atoms is present in an amount of from about 50 to about 90% by weight, the polar comonomer is present in an amount of from about 1 to 10% by weight, the partially water soluble comonomer is present in an amount of about 7 to about 20% by weight. 13. A process as claimed in any one of the previous claims in combination with adding to said emulsion following polymerization of said monomer mixture, at least one electrolyte provided in an amount sufficient to stabilize opacity of a pressure sensitive adhesive film cast from said formed emulsion. 14. Emulsion acrylic pressure sensitive adhesive copolymers which form clear films which resist water whitening comprised of copolymerized mixture of monomers containing at least one alkyl acrylate ester of an alcohol containing at least 4 carbon atoms, at least one polar comonomer and at least one partially water soluble comonomer present in an amount of at least about 7% by weight of the monomers forming the total mixture, said copolymer formed in an aqueous polymerization media in the presence of at least one nonionic surfactant containing at least about 8 moles of ethylene oxide per mole nonionic surfactant and at least one anionic surfactant containing up to about 10 moles ethylene oxide per mole anionic surfactant, at a weight ratio of said nonionic surfactant to said anionic surfactant being at least about 1 to 1 in which the product of polymerization is neutralized in emulsion by at least one base to produce an emulsion a pH greater than 7, said copolymers when formed as a film on a biaxially oriented polypropylene film to a level of 20 to 22 g/m 2 and immersed in water of at least 95 °C for 10 minutes and laminated to a 1.5 mil polyester release film providing an opacity of about 5% or less using a spectrocolorimeter. 15. Emulsion polymers as claimed in claim 14 in which the emulsion produced is neutralized to a pH of about 7.2 to about 9. 16. Emulsion polymers as claimed in claim 14 in which the the emulsion produced is neutralized to a pH of about 7.8 to about 8. 17. Emulsion polymers as claimed in any one of claims 14 to 16 in which the partially water soluble comonomer is present in an amount of from about 8 to about 25% by weight of the total monomers. 18. Emulsion polymers as claimed in any one of claims 14 to 16 in which the partially water soluble comonomer is present in an amount of from about 8 to about 20% by weight of the total monomers. 19. Emulsion polymers as claimed in any one of claims 14 to 16 in which the partially water soluble comonomer is selected from the group consisting of methyl acrylate, methyl methacrylate and mixtures thereof. 20. Emulsion polymers as claimed in any one of claims 14 to 16 in which the polar comonomer is selected from the group consisting of acrylic acid and a mixture of acrylic acid and methacrylic acid. 21. Emulsion polymers as claimed in any one of claims 14 to 1 in which the alkyl acrylate is selected from the group consisting of 2 ethyl hexyl acrylate, butyl acrylate and mixtures thereof. 22. Emulsion polymers as claimed in any one of claims 14 to 21 in which the base is ammonium hydroxide. 23. Clear emulsion acrylic pressure sensitive adhesives polymers comprised of a copolymerized a monomer mixture comprising at least one alkyl acrylate ester of an alcohol containing at least 4 carbon atoms present in an amount of from about 50 to about 70% by weight, at least one polar comonomer present in an amount of at least 1 % by weight of monomer mixture, and at least of one partially water soluble comonomer present in an amount of at least about 7% by weight of monomer mixture, dispersed in an aqueous emulsion polymerization media and copolymerized in the presence of at least one nonionic surfactant containing at least about 8 moles of ethylene oxide per mole nonionic surfactant and at least one anionic surfactant containing ethylene oxide in an amount up to about 10 moles per mole anionic surfactant at a weight ratio of said nonionic surfactant to said anionic surfactant of at least about 1 to 1 neutralized by at least one base to a pH greater than 7 and containing particles having a volume average particle diameter up to about 150 nm as determined by laser light scattering, said particles when formed as a coating on a biaxially oriented polypropylene film to a level of 20 to 22 g/nr and immersed in water of at least 95°C for 10 minutes and laminated to a 1.5 mil polyester release film providing an opacity of about 5% or less using a spectrocolorimeter. 24. Clear polymers as claimed in claim 23 in which the opacity is less than about 2.5%. 25. Clear polymers as claimed in claim 23 or 24 in which the pH is from about 7.2 to about 9. 26. Clear polymers as claimed in claim 23 or 24 in which the pH is from about 7.8 to about 8. 27. Clear polymers as claimed in any one of claims 23 to 26 in which the base is ammomum hydroxide. 28. Clear polymers as claimed in any one of claims 23 to 27 in combination with adding to said emulsion following polymerization of said mixture of monomers, at least one electrolyte provided in an amount sufficient to stabilize opacity of a pressure sensitive adhesive film formed from said polymers. 29. In a process for the formation of clear emulsion acrylic polymers useful as pressure sensitive adhesives by emulsion polymerization of a mixture of monomers containing at least one alkyl acrylate ester of an alcohol containing at least 4 carbon atoms and adding at least one base to said emulsion to a pH of at least 7 to provide emulsion particles which deposit as clear films from the emulsion the improvement which comprises adding to the emulsion having the pH of at least 7 following polymerization of said mixture of monomers at least one inorganic electrolyte in an amount sufficient to stabilize the opacity of a film formed from the emulsion. 30. A process as claimed in claim 29 in which the electrolyte is added in an amount from about 0.025 to about 0.25 percent by weight of the emulsion. 31. A process as claimed in claim 29 in which the inorganic electrolyte is added to the emulsion in an amount of from about 0.03 to about 0.1 percent by weight of the emulsion. 32. A process as claimed in claims 29, 30 or 31 in which the inorganic electrolyte is selected from the group consisting of alkali metal sulfates, alkaline earth metal sulfates, alkali metal acetates, alkaline earth metal acetates, alkali metal phosphates, alkaline earth metal phosphates, and mixtures thereof. 33. A process as claimed in claim 32 in which the alkali metal is sodium. 34. A process as claimed in any one of claims 29 to 33 in which the monomer mixture contains at least one alkyl acrylate ester of an alcohol containing at least 4 carbon atoms, at least one polar comonomer present in an amount of at least about 7% by weight of the monomer mixture, and at least one polar comonomer, said monomer mixture being formed in the presence of at least one anionic surfactant containing up to about 10 moles ethylene oxide per mole anionic surfactant. 35. A process as claimed in claim 34 in which the partially water soluble comonomer is present in an amount of from about 8 to about 25% by weight of the total monomers. 36. A process as claimed in any one of claims 29 to 35 in which the added base comprises ammonium hydroxide. 37. A process as claimed in any one of claims 29 to 36 in which the emulsion particles have a volume average particle diameter up to about 150 nm as determined by laser light scattering. 38. A process as claimed in any one of claims 34 to 37 in which there is also present at least one nonionic surfactant containing 8 moles of ethylene oxide per mole nonionic surfactant. 39. A process as claimed in claim 38 in which the weight ratio nonionic surfactant to anionic surfactant is at least 1 to 1. 40. A process as claimed in any one of claims 27 to 39 in which the pH is from about 7.2 to about 9. 41. A process as claimed in any one of claims 27 to 39 in which the pH is from about 7.8 to about 8. 42. A process as claimed in any one of claims 37 to 41 in which the partially water soluble comonomer is present in an amount of from about 8 to about 20% by weight of the monomers. 43. A process as claimed in any one of claims 37 to 42 in which the partially water soluble comonomer is selected from the group consisting of methyl acrylate, methyl methacrylate and mixtures thereof.

Inventors: DILTS GEORGE, LI XING-YA, MALLYA PRAKASH, SMITH COLIN C, DILTS, GEORGE, LI, XING-YA, MALLYA, PRAKASH, SMITH, COLIN, C.
Applicants: AVERY DENNISON CORP, AVERY DENNISON CORPORATION
Application year: 1996
Main classification: C08L33
IPC codes: C08F220, C09J133