ADHESIVE COMPOSITION AND PNEUMATIC TIRE

Abstract: An adhesion force between a polyester cord and adherend rubber is improved by an adhesive composition comprising vinylpyridine-styrene-butadiene copolymer latex particles having at least two kinds of monomer compositions and a thermosetting resin comprised of resol type condensate and novolak type condensate of resorcin-formaldehyde.

Description: This invention relates to an adhesive composition, and more particularly to an adhesive composition capable of satisfactorily adhering a polyester material or the like to rubber. Furthermore, this invention relates to a pneumatic tire, and more particularly to a pneumatic tire using polyester cord as a reinforcement. A polyester material having an ester bond in its main chain is a linear polymer represented by polyethylene terephthalate and has high initial modulus, excellent dimensional stability under heating and low cost, so that it is very useful as a reinforcement for rubber articles such as tires, belts, air springs, rubber hoses and the like in forms of filament, cord, cable, cord fabric, canvas and the like. However, when polyester material is used as a reinforcement for such rubber articles, since the polyester material has a simple molecular structure and has a low number of functional groups, satisfactory adhesion to rubber is not obtained by an adhesive composition, effective for adhering materials such as nylon, rayon or the like and rubber, comprising a resorcin-formaldehyde condensate obtained by a resolforming reaction and a rubber latex including a vinylpyridine-styrene-butadiene terpolymer. For this end, there have been proposed methods wherein the surface of a polyester cord is subjected to an alkali·amine treatment so as to increase the number of active groups such as -OH, -COOH, -NH 2 or the like on the surface, and methods wherein a compound having a functional group which is capable of hydrogen bonding or primary bonding is introduced onto the surface of the polyester cord using an isocyanate compound or an epoxy compound and then treated with an adhesive solution. However, the strength of the polyester cord is degraded by the alkali·amine treatment. Further, the isocyanate compound or the epoxy compound has high reactivity and reacts with water as a solvent of the adhesive solution or resorcin-formaldehyde condensate in the adhesive solution, so that it is very difficult to provide an adhesive solution usable in a single stage and also the adhesion property is damaged. For this end, it is required to divide the adhesion treating step into two stages and hence extra installations and steps are necessary, which are unfavourable from the viewpoint of resource-saving and energy-saving. Also, the treatment with the isocyanate compound or the epoxy compound is unfavourable from the viewpoint of environmental conservation because of the scattering of these compounds into the air during the adhesion treatment, and of the injurious effects of fumes and steam created during the heat treatment upon the human body. Moreover, the polyester cord treated with the isocyanate compound or the epoxy compound is hardened and the handling thereof is difficult in the production. In addition, there is a most serious problem that when such a polyester cord is used at a high temperature under a high strain, there are caused rapid deterioration of adhesion and degradation of cord strength, and hence the service life of a rubber article using such a cord as a reinforcing material considerably lowers. As reasons of these phenomena, there can be mentioned that since the isocyanate compound or the epoxy compound is primarily bonded to the polyester surface to thereby form a kind of graft polymer on the surface, adhesion breakage of the bonded portion is easily caused by hydrolysis of polyester, aminolysis with a residue of vulcanizing agent in a rubber composition and the like in use at a high temperature, and that the bonded portion is mechanically weak due to the large difference of rigidity between the surface and the inside of the polyester under high strain. Weight reduction is desirable from the viewpoint of energy-saving, and hence it is necessary to further improve the stability and fatigue life to thermal input and mechanical input. For this reason, the use of an isocyanate compound or an epoxy compound is also unfavourable in the treatment for the polyester material. On the other hand, methods of adding a resin imparting adhesion/tackiness as an adhesion promoter to the above-mentioned adhesive solution and adhesive compositions thereof have been proposed as an adhesive for the polyester. They enable the adhesion to be conducted in a single stage and provide excellent energy-saving and cost-saving and also the lowering of strength of a cord treated with such an adhesive is small. Because water having good operability and properties with respect to the environment is mainly used as a solvent, there have been proposed resins easily soluble in water such as phenolic resin as an adhesion/tackiness imparting resin added. For example, when using a resin obtained by a novolak-forming reaction between resorcin and formaldehyde in the presence of a neutral or acidic catalyst, the adhesion force is improved, but if rubber latex as defined in the present invention as mentioned below is not used in the adhesive solution, the adhesion performance is insufficient and particularly adhesion deterioration is caused by thermal input during vulcanization, when the adhesion to adherend rubber should be enhanced, and it can not be said that the above resin is satisfactory. Furthermore, there has been proposed, for example, a reaction product between p-chlorophenol and formaldehyde, and a reaction product between resorcin and triallyl cyanurate. However, they have insufficient adhesion performance and cause adhesion deterioration particularly at higher temperatures, so that it can not be said that they are satisfactory. Recently, in pneumatic tires provided with rubber members such as a carcass using polyester cords as a reinforcing material, since tire performances are improved and the temperature at vulcanization is made higher than the conventionally used temperature to obtain better productivity, and hence thermal input to the polyester cord becomes much severer over a period ranging from this vulcanization step up to use, there is a possibility that even the aforementioned adhesive compositions have insufficient heat resistance. As mentioned above, the properties required in an adhesive composition suitable for use in a polyester material or the like for rubber reinforcement are that it is usable in a single stage, the storing stability is good, that it is free from toxicity and environmental pollution, that the cord strength is not lowered by the adhesion treatment, that the adhesion property is high, and that sufficiently high adhesion force at higher temperatures applied during vulcanization and in use can be maintained, in another words the heat resistance is sufficient. It is an object of the invention to provide an adhesive composition satisfying all of the above properties. It is another object of the invention to provide a pneumatic tire using polyester cords subjected to adhesion treatment with the above adhesive composition as a reinforcing material, in which adhesion deterioration and lowering of strength are not caused even when being used at a high speed under a high load or at a higher temperature under a higher strain. The present invention provides an adhesive composition which comprises 14-205 parts by weight, preferably 38-115 parts by weight, as a solid content of a thermosetting resin including up to 35 parts by weight of a resol type condensate obtained by a resol-forming reaction between resorcin or a resorcin-formaldehyde resin oligomer and formaldehyde and a novolak type condensate obtained by a novolak-forming reaction between resorcin and formaldehyde, based on 100 parts by weight as a solid content of vinylpyridine-styrene-butadiene (Vp-St-Bd) type sequential copolymer rubber latex containing 20-100% by weight of Vp-St-Bd type sequential copolymer obtained by sequential-polymerization of (a) a monomer mixture of 3-25% by weight, preferably 5-15% by weight, of a pyridine ring containing compound, 25-80% by weight, preferably 35-70% by weight, of an unsubstituted styrene and/or substituted styrene, or of an unsubstituted styrene and/or substituted styrene and an aliphatic vinyl compound, and 5-60% by weight, preferably 15-60% by weight, of a conjugated diene compound, and (b) a monomer mixture of 5-25% by weight, preferably 5-20% by weight, of a pyridine ring containing vinyl compound, 5-45% by weight, preferably 10-40% by weight, of an unsubstituted styrene and/or substituted styrene, or of an unsubstituted styrene and/or substituted styrene and an aliphatic vinyl compound, and 40-83% by weight, preferably 40-80% by weight, of a conjugated diene compound, in which a weight ratio of a copolymer component (a') obtained by the polymerization of the monomer mixture (a) to a copolymer component (b') obtained by the polymerization of the monomer mixture (b) in the resulting Vp-St-Bd type sequential copolymer is 10/90-80/20, preferably 50/50-80/20, and the content of the conjugated diene compound in the monomer mixture (b) is higher than that in the monomer mixture (a). The term "sequential-polymerization" used herein means "multi-stage feed polymerization". In the thermosetting resin, the resol type condensate is obtained by a resol-forming reaction of resorcin or a resorcin-formaldehyde resin oligomer with formaldehyde in the presence of a basic catalyst and is compounded in an amount of 4-35 parts by weight, preferably 8-15 parts by weight, as a solid content based on 100 parts by weight as a solid content of the rubber latex, while the novolak type condensate is obtained by a novolak-forming reaction of resorcin and form-aldehyde in the presence of a neutral or acidic catalyst and is compounded in an amount of 10-170 parts by weight, preferably 30-100 parts by weight, based on 100 parts by weight as a solid content of the rubber latex. According to further preferred features of the invention: the amount of the aliphatic vinyl compound in each of the monomer mixture (a) and the monomer mixture (b) is not more than 15% by weight, more preferably not more than 5% by weight. more than 80% by weight of styrene-butadiene copolymer and/or the copolymer obtained by the polymerization of only a monomer mixture satisfying a composition range of the monomer mixture (b) is included in the solid content of the rubber latex. the resol type condensate being a constitutional component of the so-called RFL solution is obtained by a resol-forming reaction under mixing with the rubber latex. the novolak type condensate is added as an adhesion promoter to a composition comprising the rubber latex and the resol type condensate. an area ratio of 2-4 resorcin nuclei connecting component in the novolak type condensate is not less than 40%, more preferably not less than 50%, through an analysis of gel permeation chromatography (GPC). The invention in another aspect provides a pneumatic tire characterized by using a polyester cord subjected to an adhesion treatment with an adhesive composition as defined above as a reinforcing material. Reference will be made in the following to the accompanying drawing, wherein Fig. 1 is a GPC chart of a novolak type condensate according to the invention. The present inventors have made various studies with respect to deterioration of adhesion between a reinforcing material and an adherend rubber composition therefor (hereinafter referred to as adherend rubber) through thermal input and found that the participation of the adhesive composition, particularly vulcanization reaction of rubber latex, is large. The form of the reinforcing material for rubber is not particularly restricted but may be cord, film, short fiber, nonwoven fabric or the like. Now, the invention will be described in detail by taking a cord as a form of the reinforcing material. During a step of adhering an adhesive treated cord which has been immersed, for example, in an adhesive composition to an adherend rubber through vulcanization, the latex in the adhesive composition is vulcanized by a vulcanizing agent, a vulcanization accelerator or the like diffused from the adherend rubber to cause hardening of the adhesive layer, whereby stress concentration is caused between the cord and the adhesive layer and the adhesion is deteriorated. Furthermore, it should be considered that even after the adhesion step, the vulcanization reaction proceeds through thermal input generated in the use of the product to cause similar deterioration of adhesion. The inventors have variously studied means for improving the heat resistance by controlling or delaying vulcanization reaction of the adhesive composition and confirmed that a method of providing the heat resistance by previously adding a substance, such as acid, having a vulcanization controlling effect to the adhesive composition (JP-A-6-287865), or a method of reducing butadiene monomer component which is a crosslinking site to control vulcanization of the latex itself (JP-A-3-163181) are effective. When a polyester cord is particularly used as a reinforcing material for rubber articles, however, since the polyester material has a simple molecular structure and has a low number of functional groups, it can not be said that the adhesion is sufficient with the adhesive comprised of the resol type condensate described in JP-A-3-163181 and Vp-St-Bd terpolymer latex obtained by two-stage polymerization having reduced butadiene monomer content. The inventors have made further studies with respect to the addition of adhesion/tackiness imparting resin to the adhesive composition as an adhesion promoter and found that an adhesive composition containing a novolak type condensate as an adhesion promoter satisfies all properties required in the adhesive composition for a polyester cord used as a reinforcement for a reinforcing rubber, that is usable in a single stage, good storing stability, no toxicity·environmental pollution, no lowering of cord tenacity through adhesion treatment, high adhesion property, maintenance of sufficiently high adhesion force even at higher temperatures applied during the vulcanization step or in use, in another words sufficient heat resistance. The reason why such an adhesive composition is particularly suitable for the adhesion between polyester cord and adherend rubber is as follows. That is, since the molecular structure of the novolak type condensate is a straight-chain resin having a relatively low molecular weight and low nucleus-number body consisting essentially of 2-4 aromatic nuclei in one molecule, the solubility and diffusing property is good and the hot melt to the polyester cord is easy in the heat treatment during the adhesive treating step as compared with the resol type condensate having mainly a three-dimensional network molecule, and the surface of the cord is easily wetted owing to the low molecular weight (low nucleus-number body) and further the diffusion is facilitated by mixing with contaminants left on the surface such as various oiling agents used in the spinning of polyester to make the adhesion strong. Furthermore, the novolak type condensate is dissolved and diffused in the adherend rubber to strengthen the adhesion and reinforce the surrounding rubber composition, so that when cracks are created in the adherend rubber, the growth of cracks into the adhesive layer hardly occurs. Moreover, the novolak type condensate acts as an adhesion/tackiness imparting resin (tackifier) even in the adhesive layer to provide aggregation force and tackiness of the adhesive layer so as to increase adhesion force. Moreover, Class et al point out that from the measurement of dynamic mechanical properties of rubber/resin system, the effect of tackifier depends upon the solubility of a resin into a rubber based on its chemical structure and molecular weight and when the compatibility is small, the separation of rubber/resin is caused at a low concentration and hence the tacking effect is insufficient (see J. Appl. "Polymer Sci.". 30. page 805, "Pressure-sensitive adhesive", page 166). The inventors have made various studies with respect to thermosetting resins, particularly resorcin-formaldehyde resin to be added to Vp-St-Bd type sequential copolymer rubber latex, and found that a low nucleus number body of straight chain novolak type molecular structure having a molecular weight distribution consisting mainly of 2-4 nuclei connecting bodies is effective as a tackifier. Further, in general, it is preferable that the ratio of an adhesion/tackiness imparting resin to rubber component by volume is usually 66-150 to 100 of rubber (see page 138 of the above "pressure-sensitive adhesive") when the resin has a good compatibility with rubber. As the compatibility of the resin used as a tackifier becomes smaller, the separation of rubber/resin is apt to be caused, so that the preferable range shifts to a lower concentration. In the invention, it has been found that the solid content of the thermosetting resin comprised of a resol type condensate and a novolak type condensate is 14-205 parts by weight, preferably 38-115 parts by weight based on 100 parts by weight as a solid content of the rubber latex as previously mentioned. It the adhesive composition is comprised only of a novolak type condensate and a rubber latex, however, there is caused contamination to the treating machine due to cohesion during a treating step of applying an adhesive composition to a cord, whereby application of adhesive becomes non-uniform and the adhesion force is undesirably lowered. When the adhesive composition is comprised of a resol type condensate, a rubber latex (RFL) and a novolak type condensate, therefore, it is possible to avoid the occurrence of gum-up characteristic of a rubber latex. In this respect, the use of the resol type condensate is necessary. A resol type condensate can also be obtained by using a novolak type condensate as a starting material and mixing with rubber latex, an alkali and formalin in the presence of a base (see "Emulsion Handbook", p777, printed by Taiseisha). In this case, the molecular weight of the above novolak type condensate is further increased by forming a three-dimensional network to result in a resol-forming reaction product. In general, in known prior art techniques, the amount of a resol type condensate compounded to a rubber latex is usually about 7-35 parts by weight based on 100 parts by weight as a solid content of the rubber latex, e.g. Vp-St-Bd copolymer rubber latex. When the amount exceeds 40 parts by weight, the compatibility of the adhesive layer to the adherend rubber becomes insufficient due to the hardening of the adhesive layer and the heat treatment at vulcanization step and hence the adhesion force between the adhesive layer and the adherend rubber considerably lowers. This was the same for the rubber latex used in the present invention. Further, the reason why the novolak type condensate is added to the RFL solution is due to the fact that when the addition is carried out during the reaction of forming the resol type condensate, the novolak type condensate is rendered into higher molecular weight and three-dimensional network and hence the effect as an adhesion promoter becomes small. The addition is possible at a time just before and after the substantial completion of the reaction of forming the resol type condensate. During the resol-forming reaction, pH is temporarily lowered due to the formation of methylol group as a reaction intermediate, but as the condensation reaction proceeds, the methylol group is consumed to again increase pH and pH is approximately constant at the completion of the reaction. In the invention, therefore, the addition is carried out by checking such a pH change as an indication. Also, a feature of the invention is that [(amount of resol type condensate) + (amount of novolak type condensate)] compounded is in an amount of 14-205 parts by weight based on 100 parts by weight as a solid content of the rubber latex. Particularly, the preferable compounding range of 38-115 parts by weight is clearly larger than the compounding amount of resorcin-formaldehyde condensate or thermosetting resin compounded in Vp-St-Bd copolymer latex obtained by two-stage polymerization in the known prior art (JP-A-58-2370, JP-A-60-92371, JP-A-60-96674, JP-A-60-96675, JP-A-3-163181 and the like). If the compounding amount of the resin can be made large in the adhesive composition, it is preferable because the bonding to the fiber is strong, but the compatibility of the adhesive composition to the adherend rubber at the boundary between the adhesive layer and the adherend rubber is small and the adhesion force lowers. The resol type condensate is a polymer of three-dimensional network structure, while the novolak type condensate used in the invention has a low molecular weight straight-chain and is better in respect of both the diffusion property and compatibility of the molecular chain, so that the amount of the resin compounded into the adhesive composition can be increased without damaging the compatibility between the adhesive layer and the adherent rubber. From the above reasons, according to a preferred aspect of the invention, the compounding is possible in a higher mixing ratio which has never been attained in the conventional technique, in which the amount of the thermosetting resin is not less than 35 parts by weight based on 100 parts by weight of the rubber latex. Further, the reason why the composition ratios in the copolymer component (a') and the copolymer component (b') constituting the sequential copolymer particles of the rubber latex differ from each other is as follows. That is, the conjugated diene compound component giving double bond to the particle generates a crosslinking reaction through a crosslinking agent mainly migrated and diffused from the adherend rubber in the vulcanization step or under use at higher temperature, and shows the following actions as a result of the crosslinking: Firstly, the change of volume and modulus in the adhesive layer before and after the crosslinking is caused by the crosslinking. The larger such a change, the lower the durability of adhesion force. The crosslinking reaction particularly proceeds at a high temperature, so that the adhesion deterioration at a high temperature becomes larger. In this respect, therefore, it is preferable that the amount of the conjugated diene compound component is smaller. Secondly, the adhesive layer and the adherend rubber are made compatible by heat at an initial stage of the vulcanization to entangle and crosslink the particles and the polymer in the adherend rubber, whereby a boundary bonding force between the adhesive layer and the adherend rubber is obtained. In this respect, therefore, the conjugated diene compound component is necessary. Considering these actions, Vp-St-Bd copolymer rubber latex of a conventional simple composition structure having a butadiene content of about 70% by weight has widely been used. Rubber latex particles comprised only of the copolymer component (a') having a low content of conjugated diene compound are less liable to influence volume·modulus change through the crosslinking and can be expected to improve the durability of adhesion force, but the mixing between the molecular chain of the copolymer in the particle and the molecular chain of the adherend rubber becomes difficult due to the compatibility to the adherend rubber. Since the content of the conjugated diene compound is less, the crosslinking is less and the boundary bonding force between the adhesive layer and the adherend rubber is small, so that the adhesion level lowers. Particularly, when the content of the conjugated diene compound is less than 40% by weight, the compatibility of the particles with the adherend rubber becomes considerably small and the boundary bonding force is hardly generated and there is a problem that adhesion breakage easily occurs between the adhesive and the adherend rubber. In order to improve the adhesion force and to prevent the lowering of the adhesion force at a high temperature, therefore, according to the invention, the structures of both the copolymer component (b') having the conventional conjugated diene compound content (about 70% by weight) and the copolymer component (a') having less conjugated diene content is formed in the same particle. That is, the particles obtained by sequentially polymerizing the monomer mixture (a) having less content of conjugated diene compound and the monomer mixture (b) having the conventional level content of conjugated diene compound can improve the adhesion force, particularly the heat-resistant durability, because the copolymer particles are entangled with a molecular chain of rubber polymer at an initial vulcanization stage and co-vulcanize in the portion of the copolymer component (b') of the rubber latex particle and hence provide a boundary bonding force between adhesive and adherend rubber equal to the conventional one, and at the same time the content of conjugated diene compound in the whole of the rubber latex particles is decreased and hence the influence of volume and modulus changes accompanied with the crosslinking reaction becomes less when thermal input is applied at high temperature or for a long time during the vulcanization, product use or the like. In the invention, 2-vinylpyridine, 3-vinylpyridine, 4-vinylpyridine, 2-methyl-5-vinylpyridine, 5-ethyl-2-vinylpyridine and the like are mentioned as pyridine ring containing vinyl compounds, one or two or more of which may be used. Preferably, 2-vinylpyridine is used. As the unsubstituted styrene and/or substituted styrene, mention may be made of styrene, α-methylstyrene, 2-methylstyrene, 3-methylstyrene, 4-methylstyrene, 2,4-diisopropyl styrene, 2,4-dimethylstyrene, 4-t-butylstyrene, hydroxymethyl styrene and the like, one or two or more of which may be used. Preferably, styrene is used. As the aliphatic vinyl compound, mention may be made of ethylenically unsaturated acid monomers such as acrylic acid, methacrylic acid or the like; ethylenically unsaturated acid anhydride monomers such as anhydrous maleic acid or the like; ethylenically unsaturated acid ester monomers such as methyl methacrylate or the like; and aliphatic vinyl compound monomers such as ethylene, acrylonitrile, vinyl chloride or the like, one or two or more of which may be used. As the conjugated diene compound, mention may be made of aliphatic conjugated diene compound monomers such as 1,3-butadiene, 2-methyl-1,3-butadiene and the like, one or two or more of which may be used. Preferably, 1,3-butadiene is used. In the monomer mixture (a) of the Vp-St-Bd type copolymer rubber latex according to the invention, when the content of pyridine ring containing vinyl compound is less than 3% by weight, the adhesion force of the adhesive composition as a whole undesirably lowers, while when said content exceeds 25% by weight, the vulcanization reaction of the latex is undesirably promoted. When the content of unsubstituted styrene and/or substituted styrene or unsubstituted styrene and/or substituted styrene and aliphatic vinyl compound is less than 25% by weight, the strength of the rubber latex particles lowers and the strength of the adhesive layer lowers and hence lowering of the adhesion force is brought about, while when said content exceeds 80% by weight, the rubber latex particles are too hard and the flexibility lowers and the lowering of the adhesion force when the product is used under high strain becomes remarkable. When the content of conjugated diene compound is less than 5% by weight, the crosslinking is too little and the adhesion force lowers, while when said content exceeds 60% by weight, the crosslinking is too great and the heat resistance undesirably lowers. In the monomer mixture (b), when the content of pyridine ring containing vinyl compound is less than 5% by weight, the adhesion force of the adhesive layer as a whole lowers likewise the above case, while when said content exceeds 25% by weight, the adhesive becomes undesirably brittle. When the content of unsubstituted styrene and/or substituted styrene or unsubstitued styrene and/or substituted styrene and aliphatic vinyl compound is less than 5% by weight, the strength of the rubber latex particles and of the adhesive layer lowers and hence the adhesion force lowers, while when said content exceeds 45% by weight, the co-vulcanizability between adhesive layer and adherend rubber lowers and the adhesion force also undesirably lowers. When the content of conjugated diene compound is less than 40% by weight, the crosslinking is too little and the adhesion force lowers, while when said content exceeds 83% by weight, the adhesion force undesirably lowers. As long as the weight ratio of the copolymer component (a') to the copolymer component (b') is 10/90-80/20, three or more kinds of monomer mixtures may be sequentially polymerized. The weight ratio of the copolymer component (a') to the copolymer component (b') is defined to be 10/90-80/20; if the weight ratio of the copolymer (a') is too small, the effect of improving the heat-resistant adhesion force as compared with the conventional product of Vp-St-Bd copolymer rubber latex is slight, while if the content of copolymer (a') is too large, the initial adhesion force lowers. The composition of the produced rubber latex particles can be determined by a method of measuring a polymer composition ratio from a peak area of a chart obtained through NMR (nuclear magnetic resonance) process, or by a method of measuring viscoelastic behaviour of a polymer to determine a polymer composition ratio from loss thereof. Further, a two-phase structure of copolymers having different staining degrees in the particles is observed by means of an electron microscope after staining the rubber latex with osmium. Also, the reason why the solid content of a Vp-St-Bd type sequential copolymer in the rubber latex is required to be not less than 20% by weight of the rubber latex solid content is due to the fact that when it is less than the above value, the effect by using this latex can not be obtained. The preparation of the latex can be carried out by the well-known sequential polymerization process. As the sequential polymerization process, there are, for example, a two-stage polymerization process, and a power feed polymerization process. Further, the addition method of the monomer is not particularly restricted and there may be used siamese addition, divisional addition, or continuous addition as long as the method can provide a latex containing both the copolymer (a') and the copolymer (b'). Specifically, an emulsifying agent such as potassium rhodinate is added to water, to which is added the monomer mixture (a) or (b). Further, an electrolyte such as sodium phosphate and an initiator such as peroxide are added to conduct polymerization. After a given conversion is attained, the other monomer mixture (b) or (a) is added to continue the polymerization. After a given conversion is obtained, a charge transferring agent is added to stop the polymerization and then the remaining monomer is removed to obtain rubber latex having a structure comprised of polymers having different composition ratios. As the novolak type condensate, use may be made of commercially available products (e.g. Penacolite R50, trade name, made by Indospec Co., Ltd,, Sumikanol 700(s), trade name, made by Sumitomo Chemical Co., Ltd.) and a synthetic product obtained by the following method. That is, resorcin is dissolved in water and added with formaldehyde, which is subjected to a heat treatment at a certain temperature within a range of 100-110°C for a certain time within a range of 6-8 hours to obtain a reaction product. These condensates may be used alone or in admixture of two or more. Further, a novolak type condensate between a phenolic derivative other than resorcin and formaldehyde may be used. Novolak type condensates having different molecular weight distributions were prepared by a method described in examples as mentioned later in which low molecular weight compounds such as resorcin monomer, two-nucleus resorcin-formaldehyde condensate and the like are mainly extracted from the resulting reaction product by extraction with a solvent such as toluene, xylene or the like. The molecular weight distribution of these novolak type condensates can be measured by an area ratio through GPC. When the solid content of the thermosetting resin is less than 14 parts by weight based on 100 parts by weight as a solid content of the copolymer rubber latex, the adhesion force between the adhesive composition and the polyester material or the like lowers, while when said content exceeds 205 parts by weight, the adhesion force between the adhesive composition and the adherend rubber undesirably lowers. Furthermore, a content of less than 38 parts by weight or exceeding 115 parts by weight is undesirable because it is outside a preferred range of either of the compounding amounts of the novolak type condensate and the resol type condensate constituting the thermosetting resin. When said content is within a range of 38-115 parts by weight, a good balance between the rubber latex and both the condesates is attained and the effect of the invention is remarkable. As long as the solid content of the thermosetting resin is within a range of 14-205 parts by weight based on 100 parts by weight of the rubber latex solid content, a thermosetting resin component other than resorcin-formaldehyde condensate, or a resorcin-formaldehyde resin containing a third component may be added, if necessary. In each of the monomer mixture (a) and the monomer mixture (b), the aliphatic vinyl compound is preferably not more than 15% by weight. When said amount exceeds the above value, the content of unsubstituted styrene and/or substituted styrene is decreased to reduce the effect of the invention. Further, when the aliphatic vinyl compound is not more than 5% by weight, the effect of the invention is more clearly obtained. The reason why the content of conjugated diene compound in the monomer mixture (b) is defined to be higher than that of the monomer mixture (a) is due to the fact that the adhesion property is poor in the reverse case. In the invention, not more than 80% by weight of a component other than the sequential copolymer may be included in the rubber latex component. As such a component, mention may be made of vinylpyridine-conjugated diene compound copolymer latex and its carboxy-modified latex, styrene-butadiene copolymer latex and its modified latex, acrylonitrile-butadiene copolymer latex and its modified latex, natural rubber latex, acrylic ester copolymer latex and the like, one or two or more of which may be included. When such a component is not Vp-St-Bd type copolymer obtained by polymerization of a monomer mixture satisfying the composition range of the monomer mixture (b), if the content is not more than 70% by weight, the effect of the invention is clearer and is favourable. When the content as a solid content of the resol type condensate is less than 4 parts by weight based on 100 parts by weight of the rubber latex solid content, the tackiness is high and in the course of applying the adhesive composition to the cord, contamination of the treating machine is caused and hence the adhesion force tends to lower because the adhesive can not be applied well, while when said content exceeds 35 parts by weight, the adhesion between the adherend rubber and the adhesive layer tends to lower undesirably. More particularly, when said content is not less than 8 parts by weight but not more than 15 parts by weight, the tackiness of the adhesive applied to the polyester cord is optimum and the cohesion to a jig or machine or between mutual cords after a long time can be controlled and further the state of the adhesive surface is good and a high adhesion force is obtained. Further, when the content as a solid content of the novolak type condensate is less than 10 parts by weight based on 100 parts by weight of the rubber latex solid content, the adhesion promoting effect to the adhesion force is slight, while when said content exceeds 170 parts by weight, the adhesion between the adhesive composition and the adherend rubber undesirably lowers. Particularly, a content of not less than 30 parts by weight but not more than 100 parts by weight is more preferable because the adhesion promoting effect is remarkable. The resol type condensate is preferably obtained under mixing with the rubber latex by a resol-forming reaction, which lowers the tackiness of the adhesive composition to control the occurrence of scale and gum-up at the adhesion treating step. A method of mixing starting materials of resorcin-formaldehyde condensate (resorcin, relatively low molecular weight resorcin-formaldehyde condensate, formalin) with latex in the presence of an alkali solution, and a method of starting a resol-forming reaction of the starting materials for the resorcin-formaldehyde condensate in the presence of an alkali solution without mixing with latex at the start of the reaction and mixing the reaction intermediate of a low condensing degree with latex at an initial reaction stage to continue the reaction, are generally used as the method of reacting a resorcin-formaldehyde condensate obtained by the resol formation with rubber latex, in which the mixing with the rubber latex is conducted before the completion of the condensation reaction of the resol type resorcin-formaldehyde condensate (the judging method is mentioned above). It is preferable that the novolak type condensate is added to RFL solution as an adhesion promoter, which prevents further polymerization of novolak type condensate to gain molecular weight and maintain the function as an adhesion promoter as previously mentioned. As a result of various studies with respect to the novolak type condensate, it has been confirmed that when an area ratio of 2-4 resorcin nuclei connecting component is not less than 40%, more preferably not less than 50%,through GPC analysis of the resin, the adhesion force is good and also a peak area ratio of monomer of not more than 25% through the same GPC analysis is preferable for maintaining the adhesion force inclusive of heat resistance. As the content of 5 or more nuclei connecting component increases, the water solubility of the resin tends to lower the formation of higher molecular weight polymer, and also the diffusibility of the resin in the adhesion forming course lowers to make the adhesion effect small. Further, the aggregation force of the rubber latex becomes large and the elasticity of the adhesive increases to improve the durability, but the tackiness lowers and the adhesion effect tends to become small. An adhesive treated polyester cord can be prepared by applying the adhesive composition of the above construction to a cord such as a polyester cord and subjecting it to an adequate heat treatment. The thus obtained cord is embedded in an uncured rubber and vulcanized, whereby the cord can be strongly adhered to the rubber. As methods of applying the adhesive composition to a cord, there may be selected a method of immersing the cord in an adhesive composition, a method of applying an adhesive composition with a brush, or a method of spraying an adhesive composition. It is preferable that a heat treatment following the drying is carried out at a temperature above the glass transition temperature of a polymer in the cord, preferably at a temperature of not lower than [melting point of the polymer - 70°C] but not higher than [melting point - 20°C]. When the temperature is lower than the glass transition temperature of the polymer, the molecular motion of the polymer is poor and sufficient interaction between the polymer and the adhesion/tackiness imparting resin in the adhesive composition is not attained and hence sufficient bonding force between the adhesive composition and the cord is not obtained. Further, when the temperature exceeds [melting point of polymer - 20°C], there is a tendency of degrading the fiber material and the rubber latex in the adhesive composition. The adhesive composition according to the invention is preferably applied to polyester materials. The polyester is a polymer having ester bonds in its main chain, in which not less than 80% of the bonding form of repeating units in the main chain is an ester bonding form. Such a polyester is obtained by condensing through an esterification reaction or an ester interchange reaction between a glycol such as ethylene glycol, propylene glycol, butylene glycol, methoxypolyethylene glycol, pentaerythritol or the like and a dicarboxylic acid such as terephthalic acid, isophthalic acid or a dimethyl ester thereof. The polyester is most preferably polyethylene terephthalate. Such polyester materials may take any form of cord, cable, filament, filament chip, cord fabric, canvas and the like. Further, they may be subjected to a pretreatment step such as treatment with electron rays microwaves, corona discharge, plasma or the like. The adhesive composition according to the invention can be applied to not only the polyester fiber as mentioned above but also to all materials represented by rayon, vinylon, aliphatic polyamide fibers such as 6-nylon, 6,6-nylon, 4,6-nylon or the like, aromatic polyamide fiber such as paraphenylene terephthalamide or the like, carbon fiber and glass fiber. Further, the adhesive composition according to the invention can be applied to fibers such as polyester fiber, aromatic polyamide fiber, carbon fiber and the like treated with an epoxy compound or an isocyanate compound in or after the polymerization·spinning step, or fiber materials previously worked through a treatment with electron rays, microwaves, plasma or the like. As the form of these fiber materials, use may be made of cord, cable, filament, filament chip, cord fabric, canvas and the like. The adhesive composition according to the invention is applicable to any rubber articles such as tires, conveyor belts, belts, hoses, and air springs. The invention will be further described with reference to the following Examples and Comparative Examples. The concentration of solid content in the examples was measured according to the method of measuring nonvolatile content of adhesive in the measurement of "other adhesives" of JIS K6833. (1) Preparation of Vp-St-Bd type sequential copolymer rubber latex (A) Preparation of rubber latex used in Comparative Examples 1-33 and Examples 1-42 The Vp-St-Bd type copolymer rubber latex used in Comparative Examples 1-33 and Examples 1-42 is prepared by charging and dissolving 130 parts by weight of deionized water and 4.0 parts by weight of potassium rhodinate in an autoclave of 5 liters in capacity purged with nitrogen and provided with a stirrer. To the resulting solution are added monomer mixtures having compositions as mentioned below and t-dodecylmercaptan to conduct polymerization and the concentration is adjusted to obtain a rubber latex having a solid content concentration of 40%. (i) Preparation of rubber latex used in Comparative Examples 3-5, 7-11, 17, 19-26 and Examples 1-7, 9-34 and 40-42 A monomer mixture (a) having a composition shown in Tables 5-9 and 11 and 0.2 part by weight of t-dodecylmercaptan as a chain transfer agent are charged and emulsified. Thereafter, the temperature is raised to 50°C and then 0.5 part by weight of potassium persulfate is added to start the polymerization. After the conversion of the monomer mixture (a) reaches 80-90%, a monomer mixture (b) shown in Tables 5-9 and 11 and 0.2 part by weight of t-dodecylmercaptan are added to continue the polymerization. After the conversion reaches 95%, 0.1 part by weight of hydroquinone is added to stop the polymerization. Then, unreacted monomers are removed under a reduced pressure to obtain a copolymer rubber latex. (ii) Preparation of rubber latex used in Comparative Example 6 and Example 8 A monomer mixture (b) shown in Table 6 and 0.2 part by weight of t-dodecylmercaptan are charged and emulsified. Thereafter, the temperature is raised to 50°C and 0.5 part by weight of potassium persulfate is added to start the polymerization. After the conversion of the monomer mixture (b) reaches 80-90%, a monomer mixture (a) shown in Table 6 and 0.2 part by weight of t-dodecylmercaptan are added to continue the polymerization. After the conversion reaches 95%, 0.1 part by weight of hydroquinone is added to stop the polymerization. Then, the unreacted monomers are removed under a reduced pressure to obtain a copolymer rubber latex. (iii) Preparation of rubber latex used in Comparative Examples 1, 2, 12 and 13 A monomer mixture having a composition shown in Tables 5 and 7 and 0.55 part by weight of t-dodecylmercaptan are charged and emulsified. Thereafter, the temperature is raised to 50°C and 0.5 part by weight of potassium persulfate is added to start the polymerization. After the conversion reaches 90%, 0.1 part by weight of hydroquinone is added to stop the polymerization. Then, the unreacted monomers are removed to obtain a copolymer rubber latex. (iv) Preparation of rubber latex used in Comparative Examples 15, 18 and 31-33 A monomer mixture having a composition shown in Tables 7, 8 and 11 and 0.40 part by weight of t-dodecylmercaptan are charged and emulsified. Thereafter, the temperature is raised to 50°C and 0.5 part by weight of potassium persulfate is added to start the polymerization. After the conversion reaches 90%, 0.1 part by weight of hydroquinone is added to stop the polymerization. Then, the unreacted monomers are removed to obtain a copolymer rubber latex. (v) Preparation of rubber latex used in Comparative Example 14 The rubber latex of Comparative Example 1 (or Comparative Example 12) prepared in the item (iii) is mixed with the rubber latex of Comparative Example 18 at a weight ratio of 90 parts by weight to 10 parts by weight. (vi) Preparation of rubber latex used in Comparative Example 16 The rubber latex of Comparative Example 1 (or Comparative Example 12) prepared in the item (iii) is mixed with the rubber latex of Comparative Example 18 at a weight ratio of 30 parts by weight to 70 parts by weight. (vii) Preparation of rubber latex used in Comparative Example 30 There is used a styrene-butadiene copolymer rubber latex made by Japan Synthetic Rubber Co., Ltd. (trade name: JSR2108, solid content concentration: 40%). (viii) Preparation of rubber latex used in Examples 35-37 The Vp-St-Bd type sequential copolymer rubber latex of Example 1 prepared in the item (i) and the styrene-butadiene copolymer rubber latex (SBR latex) of Comparative Example 30 are mixed at a composition ratio shown in Table 10. (ix) Preparation of rubber latex used in Comparative Examples 27-29 The Vp-St-Bd type copolymer rubber latex of Comparative Example 1 prepared in the item (iii) and the above SBR latex are mixed at a composition ratio shown in Table 10. (x) Preparation of rubber latex used in Examples 38 and 39 The Vp-St-bd type sequential copolymer rubber latex of Example 1 prepared in the item (i) and the Vp-St-Bd copolymer rubber latex of Comparative Example 1 prepared in the item (iii) are mixed at a composition ratio shown in Table 10. (B) Preparation of rubber latex used in Example 43 and Comparative Example 34 The Vp-St-Bd type copolymer rubber latex used in Example 43 and Comparative Example 34 is prepared by charging 130 parts by weight of deionized water, 7.0 parts by weight of polyoxyethylene lauryl ether and 0.05 part by weight of sodium ethylenediamine tetraacetate in an autoclave of 5 liters in capacity purged with nitrogen and provided with a stirrer. To the resulting mixture are added monomer mixtures having compositions as mentioned below and t-dodecylmercaptan to conduct polymerization and the concentration is adjusted to obtain a rubber latex having a solid content concentration of 40%. (i) Preparation of latex used in Example 43 A monomer mixture (a) having a composition shown in Table 11 and 0.2 part by weight of t-dodecylmercapatan are charged and emulsified. Thereafter, the temperature is raised to 50°C and 0.5 part by weight of potassium persulfate is added to start the polymerization. After the conversion of the monomer mixture (a) reaches 80-90%, a monomer mixture (b) having a composition shown in Table 11 and 0.15 part by weight of t-dodecylmercaptan are added to continue the polymerization. After the conversion reaches 95%, 0.1 part by weight of hydroquinone is added to stop the polymerization. Then, the unreacted monomers are removed under a reduced pressure to obtain a copolymer rubber latex. (ii) Preparation of rubber latex used in Comparative Example 34 A monomer mixture having a composition shown in Table 11 and 0.35 part by weight of t-dodecylmercapatan are charged and emulsified. Thereafter, the temperature is raised to 50°C and 0.5 part by weight of potassium persulfate is added to start the polymerization. After the conversion reaches 95%, 0.1 part by weight of hydroquinone is added to stop the polymerization. Then, the unreacted monomers are removed under a reduced pressure to obtain a copolymer rubber latex. (2) Preparation of a composition comprised of resol type condensate and rubber latex mixture (i) Preparation of Examples 1-8, 10-43, Comparative Examples 1-4, 6, 8-34 The rubber latex obtained in the item (1) and a mixed solution of starting materials for resol type condensate having a composition shown in Table 1 are mixed at a composition ratio shown in Table 1 and matured at 25°C for 24 hours to obtain a composition comprised of the rubber latex and the resol type condensate. (ii) Preparation of Example 9, Comparative Example 7 A mixed solution of starting materials for resol type condensate having a composition shown in Table 1 is prepared and left to stand at 25°C for 8 hours and then mixed with given parts by weight of the rubber latex obtained in the item (1), which is matured at 25°C for 16 hours to obtain an RFL solution. (3) Preparation of novolak type condensate As the novolak type condensate, there are used commercially available products (Penacolite R50, trade name, made by Indospec Co., Ltd. Sumikanol 700(s), trade name, made by Sumitomo Chemical Co., Ltd.) and synthetic products obtained by the following methods (Examples 3-7). That is, 100 parts by weight of resorcin and 16.3 parts by weight of water are charged into a reaction device provided with a thermometer, a stirrer, a reflux condenser and a dropping funnel and dissolved at room temperature, to which is added dropwise 97.7 parts by weight of 37% formalin over 0.5 hour with stirring at 110°C and further the stirring is continued for 6.0 hours. After cooling to 90°C, 1.3 parts by weight of an aqueous solution of 1N ammonia is added as a pH adjusting agent for restraining the reaction to adjust pH to about 4 and then cooled to room temperature to obtain a novolak type condensate shown in Example 3 of Table 5. In order to prepare novolak type condensates of Examples 4, 5, 6 having different molecular weight distributions from the novolak type condensate obtained by the above condensation reaction, monomer and low molecular weight component are extracted with toluene. In order to raise the extraction efficiency in these examples, the novolak type condensate obtained by the above condensation reaction is condensed (azeotropic distillation) and then extracted at a temperature of 106°C. That is, 100 parts by weight of an aqueous solution of the above condensation reaction product and 200 parts by weight of toluene are charged into an azeotropic distillation/extraction device provided with a thermometer, a stirrer, a Dean-Stark type trap, a Liebig condenser, and a reflux condenser and raised to a temperature of 90°C and thereafter water is distilled off from the aqueous solution of the novolak type condensate through azeotropic distillation and condensed until the azeotropic temperature is 106°C. Thereafter, stirring is continued for 60 minutes while holding the temperature of 106°C and the reaction mass is left to stand for 5 minutes, whereby a toluene layer and a water layer are separated, which are decantated to remove about 195 parts by weight of toluene extracting resorcin and low molecular weight resorcin-formaldehyde condensate. In this case, toluene is distilled off by distillation, whereby there can be obtained novolak type condensate shown in Example 4 of Table 5. In the case of preparing novolak type condensate having a different molecular weight distribution shown in Example 5 of Table 5, however, the distillation is not carried out, but the following extraction operation is continued and then toluene is distilled off. That is, 100 parts by weight of toluene is again added and stirred at 106°C for 60 minutes and left to stand for 5 minutes and the toluene extracted layer is removed by decantation. Moreover, the condensate having a smaller content of low molecular weight component shown in Example 6 of Table 5 can be obtained by further repeating the above extraction operation 2 times and distilling off toluene. Also, the composition of Example 7 having reduced high molecular weight component (5 or more nuclei bodies) as compared with that of the novolak type condensate of Example 6 can be obtained by utilizing precipitation with a low temperature water as mentioned below because the solubility of the novolak type condensate in water is poor as the molecular weight becomes large. That is, the novolak type condensate of Example 6 is heated to 95°C and diluted with 100 parts by weight of water at 95°C, which is cooled to 5°C and left to stand over a day to settle the precipitate and then a novolak type condensate with a higher molecular weight is obtained through decantation of the supernatant liquid. The molecular weight distributions of these novolak type condensates are measured by the following method by means of a gel permeation chromatograph measuring machine [made by TOSOH, trade name: HLC-8020]. A sample of 2 µl is injected from a solution obtained by adding 10 ml of tetrahydrofuran to 32 mg of an aqueous solution of the novolak type condensate through a syringe and passes with tetrahydrofuran (first class grade chemical) as a carrier solvent at a flowing rate of 1 ml/min and at an atmosphere temperature of 40°C through a column of G2000HxL, and then a molecular weight pattern of elute is measured by an RI detector. As a typical example, the amount of each nuclei connecting body is determined from the corresponding area of the GPC chart shown in Fig. 1 as follows. (a) Peaks of nuclei connecting bodies in the obtained GPC waveform are monomer M, 2 nuclei connecting body D, 3 nuclei connecting body T, 4 nuclei connecting body Q and 5 or more nuclei connecting body P from the low molecular weight side. (b) A base line (X) is formed by connecting the lower side foot of the peak for the lowest molecular weight component and the higher side foot of the peak for the highest molecular weight component. (c) A normal line (Y) is drawn from a valley (bottom portion) between the peaks in the waveform showing each molecular weight to the base line, which is a boundary between adjacent nuclei bodies. (d) The percentage of each area corresponding to each nucleus body to the total area (area of M+D+T+Q+P), which is a content of each nucleus body. Moreover, the solid content concentration of the aqueous solution of novolak type condensate in the commercially available products and the synthetic products were measured by the aforementioned method, and if necessary water is added so as to adjust the solid content concentration to 50% (in this case, water is added at a temperature of 95°C and cooled to room temperature). (4) Preparation of adhesive composition (i) Examples 1-43, Comparative Examples 1, 2, 9, 11-34 The novolak type resorcin-formaldehyde condensate shown in Table 1 (solid content concentration: 50%) is rendered into an adhesion promoter solution by adjusting pH with a caustic soda solution having a composition shown in Table 2. This solution is added to RFL solution obtained in the item (2) at a composition shown in Table 1 to prepare an adhesive composition. (ii) Comparative Example 4 An adhesive composition of Comparative Example 4 is prepared by forming a solution of resorcin in caustic soda having a composition shown in Table 3 and adding this aqueous solution to the RFL solution obtained in the item (2) at a composition shown in Table 1. (iii) Comparative Example 5 An adhesive composition is prepared by forming a solution of novolak type condensate having a solid content concentration of 50% in caustic soda having a composition shown in Table 2 and adding 350 parts by weight of this aqueous solution to 400 parts by weight of rubber latex obtained in the item (1). (iv) Comparative Examples 3, 6, 7, 8, 10 As the adhesive compositions of Comparative Examples 3, 6, 7, 8, 10, there is used RFL solution prepared in the item (2) as it is. (5) Preparation of cords treated with adhesive composition As a polyester material, there are used polyethylene terephthalate tire cords having a twisting structure of 1500 d/2, ply twist number of 40 turns/10 cm and cable twist number of 40 turns/10 cm, which are immersed in the adhesive composition obtained in the item (4), dried at 150°C for 1.5 minutes and treated in an atmosphere held at 240°C for 2 minutes. (6-1) Vulcanization I The cords treated with the adhesive composition of the item (5) are embedded in an uncured rubber composition having a compounding recipe shown in Table 4 and vulcanized at 170°C under a pressure of 20 Kg/cm 2 for 30 minutes. (7-1) Measurement of initial adhesion force The cord end is taken out of the vulcanizate obtained in the item (6-1) and the cord is peeled off therefrom at a velocity of 30 cm/min to measure a resisting force, which is an initial adhesion force. The results are shown in Tables 5-11. (6-2) Vulcanization II The cords treated with the adhesive composition of the item (5) are embedded in an uncured rubber composition having a compounding recipe shown in Table 4 and vulcanized at 190°C under a pressure of 20 kg/cm 2 for 30 minutes. (7-2) Measurement of heat-resistant adhesion force The cord end is taken out of the vulcanizate obtained in the item (6-2) and the cord is peeled off therefrom at a velocity of 30 cm/min likewise the above case to measure a resisting force, which is a heat-resistant adhesion force. The results are shown in Tables 5-11. (8) Tire durability A radial tire for a passenger car having a single-layer carcass ply using the treated cord obtained in the item (5) is prepared. The tire size is 185/70 R14. The thus prepared tire is mounted onto a rim according to a method of 5.3.1 in JIS D4230 and then a total running distance until the breakage of the tire is measured by using a testing device of 5.3.2 in the same JIS while continuously increasing the load by 5% every 24 hours even after the completion of a third stage in a testing method of 5.3.3 in the same JIS. A tire durability (A) is represented by an index in Tables 5-7 on the basis that the result using the adhesive composition of Comparative Example 3 is 100. Next, polyethylene terephthalate tire cords having a twisting structure of 1500 d/2, ply twist number of 23 turns/10 cm and cable twist number of 23 turns/10 cm are prepared. Such cords are immersed in each of the adhesive compositions, dried at 150°C for 1.5 minutes and subjected to an adhesion treatment by heating in an atmosphere held at 240°C for 2 minutes. A radial tire for a passenger car having a two-layer belt ply is prepared by using the thus treated cord. The tire size is 185SR14. The thus prepared tire is mounted onto a rim according to a method of 5.3.1 in JIS D4230 and then a total running distance until the breakage of the tire is measured by using a testing device of 5.3.2 in the same JIS and continuously increasing the speed by 10 km/h every 30 minutes even after the completion of a fourth stage in a testing method of 5.4.3 in the same JIS. A high-speed tire durability (B) is represented by an index in Tables 5-7 on the basis that the result using the adhesive composition of Comparative Example 3 is 100. Furthermore, polyethylene terephthalate tire cords having a twisting structure of 1500 d/2, ply twist number of 40 turns/10 cm and cable twist number of 40 turns/10 cm are prepared. Such cords are subjected to an adhesion treatment by immersing in each of the adhesive compositions, drying at 150°C for 1.5 minutes and heating in an atmosphere held at 240°C for 2 minutes. A radial tire for a small-size truck having a three-layer carcass ply is prepared by using the thus treated cord. The tire size is 6.50R15, 10PR (ply plating). The thus prepared tire is mounted onto a rim according to a method of 5.3.1 in JIS D4230 and then a total running distance until the breakage of the tire is measured by using a testing device of 5.3.2 in the same JIS and continuously increasing the load by 10% every 24 hours even after the completion of a third stage in a testing method of 5.3.3 in the same JIS. A tire durability (C) is represented by an index in Tables 5-7 on the basis that the result using the adhesive composition of Comparative Example 3 is 100. Soft water Aqueous caustic soda solution (10%) Novolak type condensate (50%) Examples 1∼12, 16∼43 Comparative Examples 1, 2, 5, 9, 12∼34 199.72 10.28 140.00 Example 13 57.02 2.94 40.00 Example 14 342.37 17.63 240.00 Example 15 485.03 24.97 340.00 Comparative Example 11 627.69 32.31 440.00 * Compounding unit is parts by weight at wet. * Numerical value in parenthesis is a solid content concentration. Soft water 269.72 parts by weight Aqueous caustic soda solution (10%) 10.28 parts by weight Resorcin (100%) 70.00 parts by weight * Compounding unit is parts by weight at wet. * Numerical value in parenthesis is a solid content concentration. Natural rubber 80 parts by weight Styrene-butadiene copolymer rubber 20 parts by weight Carbon black 40 parts by weight Stearic acid 2 parts by weight Petroleum softening agent 10 parts by weight Pine tar 4 parts by weight Zinc white 5 parts by weight N-phenyl-β-naphthylamine 1.5 parts by weight 2-benzothiazyldisulfide 0.75 part by weight Diphenyl guanidine 0.75 part by weight Sulfur 2.5 parts by weight Example 40 Acrylonitrile Comparative Example 31 Acrylonitrile Example 41 Methyl methacrylate Comparative Example 32 Methyl methacrylate Example 42 Monomer mixture (a): Acrylonitrile Monomer mixture (b): Methyl methacrylate Comparative Example 33 Acrylonitrile/methyl methacrylate (=6:4 (weight ratio)) Example 43 Itaconic acid Comparative Example 34 Itaconic acid As shown in Tables 5-11, it is apparent that each of the examples has excellent initial adhesion force, heat-resistant adhesion force and tire (high-speed) durability as compared with the corresponding comparative example(s). Moreover, they are specifically mentioned as follows. Comparative Example 5 is an example having no resol type condensate as compared with Example 1. Example 7 is an example having a reduced amount of 5 or more nuclei connecting bodies in the novolak type condensate. Example 8 has the same composition as in Example 1, but is an example wherein the charging order of the monomer mixtures is inverse in the preparation of the rubber latex. Comparative Example 6 is an example not compounding the novolak type condensate as compared with Example 8. Example 9 is an example wherein the preparation method of resol type condensate is different from that of Example 1. Comparative Example 7 is an example not compounding the novolak type condensate as compared with Example 9. Comparative example 8 is an example co-using the novolak type condensate (ISC-R50) as a starting material for the preparation of the resol type condensate. When the novolak type condensate is used as a starting material for the resol type condensate, it can be seen that the improvement of the adhesion force aimed at by the invention is not obtained. Example 10 is an example compounding the novolak type condensate into Comparative Example 8. Examples 11, 12 and Comparative Examples 5, 9 are examples showing that the compounding amount of the resol type condensate based on 100 parts by weight as a solid content of the rubber latex is suitably within a range of 4-35 parts by weight. Comparative Example 10 is an example wherein the total amount of resorcin-formaldehyde resin is equal to 84 parts by weight of Example 1. It is apparent that even if the total amount is the same, the novolak type condensate is necessary for obtaining the high adhesion force. Examples 13, 14, 15 and Comparative Example 11 are examples showing suitable compounding amounts of the novolak type condensate based on 100 parts by weight as a solid content of the rubber latex within a range of 10-170 parts by weight. In Comparative Example II, the amount of novolak type condensate is 220 parts by weight, and the amount of resol type condensate is 14 parts by weight, so that the total combined amount thereof is 234 parts by weight, which is greater than the maximum amount of 205 parts by weight defined in the invention. Further, Examples 1-7 are examples showing that in order to obtain a high adhesion force including the heat resistance, the novolak type condensate preferably contains a 2-4 resorcin nuclei connecting component so as to have an area ratio through GPC analysis of not less than 40%, preferably not less than 50%. Further, it is apparent that it is suitable that the peak area ratio of monomer component through GPC analysis is not more than 25% and that of a component connecting 5 or more resorcin nuclei bodies is not more than 50%. Examples 16-19 and Comparative Example 17 are examples showing that the weight ratio of copolymer obtained from the monomer mixture (a) to copolymer obtained from the monomer mixture (b) is required to be 10/90 - 80/20 in order to obtain an effect of providing an initial adhesion force equal to or more than the comparative example and of controlling the lowering of the heat-resistant adhesion force. Moreover, Comparative Examples 12-16, 18 are examples using rubber latex particles obtained by polymerizing a monomer mixture having a single composition. Comparative Example 12 has a polymer composition ratio equal to the composition of the copolymer (b') in Examples 16-19 and the like, Comparative Example 18 has a polymer composition ratio equal to the composition of the copolymer (a') in Examples 16-19 and the like, Comparative Example 13 has a polymer composition ratio equal to the composition of the whole particles in Example 16, and Comparative Example 15 has a polymer composition ratio equal to the composition of the whole particles in Example 19. The polymer composition ratios in Comparative Examples 14, 16 are a mixture of Comparative Example 12 equal to the composition of the copolymer component (b') and Comparative Example 18 equal to the composition of the copolymer component (a') in Examples 16-19 and the like, in which the mixing ratio of Comparative Example 14 is equal to the weight ratio of copolymer component (a')/copolymer component (b') in Example 16 and Comparative Example 16 is equal to the weight ratio of copolymer component (a')/copolymer component (b') in Example 19. The adhesion forces of these comparative examples, i.e. initial adhesion force and heat-resistant adhesion force are poor as compared with those of the examples, from which it is apparent that the same particles have the structure of copolymers having different composition ratios. Examples 20-28 and Comparative Examples 19-22 are examples showing that the necessary range of monomer composition in the monomer mixture (a) is low in the butadiene content as compared with the monomer mixture (b), and comprises 3-25% by weight in vinylpyridine content, 25-80% by weight in styrene content and 5-60% by weight in butadiene content. Examples 29-34 and Comparative Examples 23-26 are examples showing that the necessary range of monomer composition in the monomer mixture (b) is high in respect of the butadiene content as compared with the monomer mixture (a), and comprises 5-25% by weight in vinylpyridine content, 5-45% by weight in styrene content and 40-83% by weight in butadiene content. Example 2, 35-39 and Comparative Examples 27-30 are examples showing that the Vp-St-Bd type sequential copolymer rubber latex is effective to be included in an amount of not less than 20% by weight. Comparative Examples 27-29 are examples using the styrene-butadiene copolymer rubber latex, and Examples 38, 39 are examples using a mixture of Vp-St-Bd copolymer rubber latex obtained by polymerization of the monomer mixture satisfying the composition range of the monomer mixture (b). Examples 40-43 are examples replacing a part of styrene monomer in each of the monomer mixture (a) and the monomer mixture (b) with another copolymerizable monomer unit (aliphatic vinyl compound) in the Vp-St-Bd sequentially polymerized copolymer rubber latex, from which it is clear that the replacement is possible in a suitable amount. Moreover, Comparative Examples 31-34 are examples showing that vinylpyridine-styrene-butadiene copolymer particles obtained by sequentially polymerizing the monomer mixture (a) and the monomer mixture (b) are necessary. As mentioned above, the adhesion deterioration accompanied with the vulcanization reaction is controlled by compounding the rubber latex, so that there can be obtained the effect of controlling the lowering of the adhesion force at a higher temperature in a vulcanization step or in product use. Further, the effect of improving the adhesion force between the reinforcing material and adherend rubber can be obtained by the action of the novolak type condensate used in the adhesive composition according to the invention as an adhesion/tackiness imparting resin. Also, the adhesive composition according to the invention can be used in a single stage when adhering adherend rubber and the reinforcing material and can provide effects such as good storage stability, freedom from toxicity·environmental pollution, freedom from lowering of fiber strength by the adhesion treatment, high adhesion property, and sufficient high adhesion force can be maintained at a higher temperature applied in the course of working or in use or sufficient heat resistance is maintained. Moreover, the effect of realizing a high-durability pneumatic tire not causing any lowering of adhesion nor of strength even under use at high speed and high load, in another words at a high temperature and high strain, can be obtained by using the adhesive composition according to the invention.

Claims: An adhesive composition which comprises 14-205 parts by weight as a solid content of a thermosetting resin including 4 to 35 parts by weight of a resol type condensate obtained by a resol-forming reaction between resorcin or a resorcin-formaldehyde resin oligomer and formaldehyde and a novolak type condensate obtained by a novolak-forming reaction between resorcin and formaldehyde, based on 100 parts by weight as a solid content of vinylpyridine-styrene-butadiene type sequential copolymer rubber latex containing 20-100% by weight of vinylpyridine-styrene-butadiene type sequential copolymer obtained by sequential-polymerization of (a) a monomer mixture of 3-25% by weight of a pyridine ring containing compound, 25-80% by weight of an unsubstituted styrene and/or substituted styrene, or of an unsubstituted styrene and/or substituted styrene and an aliphatic vinyl compound, and 5-60% by weight of a conjugated diene compound, and (b) a monomer mixture of 5-25% by weight of a pyridine ring containing vinyl compound, 5-45% by weight of an unsubstituted styrene and/or substituted styrene, or of an unsubstituted styrene and/or substituted styrene and an aliphatic vinyl compound, and 40-83% by weight of a conjugated diene compound, in which a weight ratio of a copolymer component (a') obtained by the polymerization of the monomer mixture (a) to a copolymer component (b') obtained by the polymerization of the monomer mixture (b) in the resulting vinylpyridine-styrene-butadiene type sequential copolymer is 10/90-80/20, and the content of the conjugated diene compound in the monomer mixture (b) is higher than that in the monomer mixture (a). An adhesive composition as claimed in claim 1, characterized in that the amount of the aliphatic vinyl compound in each of the monomer mixture (a) and the monomer mixture (b) is not more than 15% by weight. An adhesive composition as claimed in claim 1 or 2, characterized in that not more than 80% by weight as a solid content of the rubber latex is styrene-butadiene copolymer and/or the copolymer obtained by the polymerization of a monomer mixture satisfying a composition range of the monomer mixture (b). An adhesive composition as claimed in claim 1, 2 or 3, characterized in that the resol type condensate is obtained by a resol-forming reaction under mixing with the rubber latex. An adhesive composition as claimed in claim 1, 2, 3 or 4, characterized in that the novolak type condensate is added as an adhesion promoter to a composition comprising the rubber latex and the resol type condensate. An adhesive composition as claimed in claim 1, 2, 3, 4 or 5, characterized in that an area ratio of 2-4 resorcin nuclei connecting component in the novolak type condensate is not less than 40% through an analysis of gel permeation chromatography. A pneumatic tire characterized by using polyester cord subjected to an adhesion treatment with an adhesive composition as claimed in any one of claims 1-6 as a reinforcing material.

Inventors: NAKAMURA MASAAKI, SASAKI KOZO, NAKAMURA, MASAAKI, SASAKI, KOZO
Applicants: BRIDGESTONE CORP, BRIDGESTONE CORPORATION
Application year: 1996
Main classification: C09J109
IPC codes: C08L9, C09J161, C09J109, B60C9, C08J5, C09J153, B60C1