PROCESS FOR PREPARING FERRIERITE

Abstract: Ferrierite is prepared by a method that provides extremely pure crystalline material. The method consists of preparing a mixture of silica, alumina, alkali metal and pyridine of a certain composition and heating said mixture to form the crystals. The SiO2/Al2O3 and OH<->/SiO2 are controlled to insure preparation of high SiO2/Al2O3 ratio, high surface area and high purity ferrierite. An olefin skeletal isomerization catalyst is prepared from a high silica to alumina ratio, high surface area and high purity ferrierite.

Description: DESCRIPTION PROCESS FOR PREPARING FERRIERITE Technical Field This invention relates to new ferrierites of high Si0 2 /Al 2 0 3 ratio and high purity, a method of preparing them, and improved olefin iso erization catalysts prepared from such ferrierites. Background Art Ferrierite is a crystalline aluminosilicate that has been found useful as an adsorbent, catalyst or catalyst support. The syntheses of ferrierite and ferrierite-type materials such as ZSM-35 are well known (see e.g., Journal of Catalysis , Vol. 35, 256-272 (1974) and US-A-3,933,974; 3,966,883; 3,992,466; 4,016,245; 4,088,739; 4,107,195 and 4,251,499). For example, it can be prepared by heating aqueous mixtures of alkali and/or alkaline earth metal, alumina and silica. These synthesis methods have several disadvantages. Typically, they require long periods of time and elevated temperatures. The high temperatures that promote crystallization require pressure vessels. The Si0 2 /Al 2 0 3 mole ratio of the product is relatively low, usually less than about 30 and the products exhibit surface areas of less than 350 m 2 /g. The use of organonitrogen compounds commonly called templates partially overcomes some of these difficulties. Shorter crystallization times and lower synthesis temperature result from using a variety of such templates (see, e.g. US-A-4,000,248; 4,107,195; 4,251,499; and 4,795,623). Even these methods do not provide ferrierite of high Si0 2 /Al 2 0 3 ratio and purity that is desirable for many catalytic uses. Many of the organic nitrogen compounds suggested as templates are expensive and are difficult to store and use. Many such compounds have pKa values between 7-12 such as those disclosed in US-A-4,205,053. Pyridine has a pKa of 5.29 but its use in zeolite synthesis appears to be somewhat complicated. For example, US-A-4,797,266 indicates that a preparation involving pyridine provides a mixture of zeolite ZSM-5 and ferrierite. US-A-4,613,488 indicates use of pyridine or a derivative results in a novel aluminum silicate not ferrierite. US-A-4,578,259 discloses the formation of "ISI-6" (an isotypic framework of ferrierite, see Atlas of Zeolite Structure Types, Meier and Olson, Butterworths-Heinemann, third revised edition, 1992, page 98) with the use of pyridine and "non-pyridine" nitrogen containing compounds or with pyridine and an oxygen containing compounds. According to US-A-4,578,259, the use of pyridine alone does not result in the formation of ferrierite. US-A-4,251,499 teaches the use of piperidine and alkyl-substituted piperidines as a template. As a comparative example, the use of pyridine as a template in example 12 led to a product which contained 50% ferrierite, 30% other zeolitic material and 20% amorphous material. EP-A-501,577, in example 2, a ferrierite catalyst having a molar silica to alumina of 72:1 prepared from a reaction gel with a molar composition of 93.5 SiO 2 /1.0 Al 2 0 3 /7.4 Na 2 0/19.6 Na 2 SO 4 /30.0 pyridine/1938 H 2 0; the molar OH " /Si0 2 ratio in the reaction gel was 0.16. EP-A-523,838 discloses in example 4, a ferrierite catalyst with a molar silica to alumina ratio of 87:1 having a surface area of 326 m 2 /g. It is an object of this invention to provide a process for the preparation of highly pure high molar silica to alumina ratio ferrierites having high surface areas which exhibit excellent catalytic performance when used in skeletal olefin isomerization. Disclosure of the Invention Ferrierite powders of exceptional crystal phase purity with very high Si0 2 /Al 2 0 3 ratio can be prepared by forming an aqueous mixture of silica, alumina, alkali metal, and pyridine and heating said mixture until the aluminosilicate crystallizes. Various parameters must be controlled to provide the high ratio, high purity, high surface area material. The synthesis gel must contain a limited amount of alkali metal, the OH " /Si0 2 mole ratio must be in a limited range and sufficient pyridine must be present to promote the reaction. An important aspect of the process of our invention is that it provides ferrierite without forming significant amounts of other crystalline materials such as zeolite ZSM- 5, mordenite, magadiite, various layered materials and quartz as impurities, in contrast to prior art methods to prepare high molar Si0 2 /Al 2 0 3 ratios. Further, the invention provides a catalyst for structurally isomerizing a linear olefin of at least 4 carbon atoms to its corresponding methyl branched isoolefin which exhibit higher selectivities at fixed conversions, greater run life and improved isobutylene yield in processing olefin rich streams compared to catalysts containing ferrierites with lower molar silica to alumina ratio and/or lower surface area prepared by earlier reported methods. Detailed Description of the Preferred Embodiments Ferrierite The process of our invention requires the use of a synthesis mixture of specific composition. Aqueous sources of silica, alumina, alkali metal, pyridine and optionally an acid or acid salt are used. The source of silica is typically an alkali metal silicate, a silica sol or a readily soluble silica gel or precipitate. The alumina source is typically sodium aluminate, aluminum sulfate or a combination of alumina and NaOH. In addition to the alkali metal included with the silica and alumina sources, alkali metal hydroxides and alkali metal salts can be used. Mineral acids can be added if the alkaline nature of the synthesis mixture needs to be reduced. Pyridine is used as a crystal structure directing compound or template. The synthesis mixture should have the following molar com¬ position to provide the high molar silica to alumina ratio, high purity, high surface area product desired in the absence of seeding the synthesis mixture with ferrierite: Al 2 0 3 :60-500 Si0 2 :18-40 pyridine:1.5-4 M 2 0:950-2000 H 2 0 wherein M is an alkali metal, usually sodium. If the synthesis mixture is seeded with ferrierite (as in Example 12 below) , the molar composition of the synthesis mixture can be: A1 2 0 3 :60-500 Si0 2 :10-40 pyridine: 1.5-4 M 2 0:950-2000 H 2 0 Accordingly, the present invention provides a method of preparing a ferrierite crystalline aluminosilicate comprising: a. preparing a mixture comprising sources of an alkali metal, silica, alumina and pyridine, said mixture having the following composition, in moles: A1 2 0 3 :60-500 Si0 2 :10-40 R:1.5-4 M 2 0:950-2000 H 2 0 wherein R is pyridine, M is an alkali metal and said sources of alkali metal and silica are such that there are 0.05 to 0.15 moles of OH " for each mole of Si0 2 , b. heating said mixture at a temperature of 140 to 180°C, and c. recovering the ferrierite. It also provides a crystalline aluminosilicate having the x-ray diffraction pattern of ferrierite and a composition in the anhydrous state of 1-3 R:0.5-0.9 M 2 0:A1 2 0 3 :40-500 Si0 2 where R is pyridine and M is an alkali metal, having a surface area of at least about 350 m 2 /g, and being essentially ferrierite crystalline phase. The amount of silica in the mixture must be relatively high to produce the high Si0 2 /Al 2 0 3 ratios desired. The amount of M 2 0, usually Na 2 0, must be limited as well. If the amount of alkali metal is too high, even if all the other conditions are maintained the product purity is reduced. An additional requirement is that the molar OH~/Si0 2 must be from 0.05 to 0.15 when preparing product with molar Si0 2 /Al 2 0 3 ratios from 40:1 to 70:1, preferably 50:1 to 70:1. For molar Si0 2 /Al 2 0 3 ratio products greater than 70:1, the OH " /Si0 2 must be from 0.05 to 0.11. Therefore the molar OH " /Si0 2 ratio of 0.05 to 0.11 can be used to produce any ferrierite crystalline aluminosilicate of the invention and having a molar silica to alumina ratio of at least 40:1, preferably at least 50:1. For the OH ~ /Siθ 2 ratio from greater than 0.11 to 0.15 only ferrierite having silica to alumina ratio of 70:1 or less can be produced. If there is less OH " present, the crystallization does not proceed well. If there is more OH " present, the ferrierite product is impure and much less useful for many catalyst applications such as skeletal olefin isomerization of light olefins such as butenes and pentenes. The synthesis mixture can be prepared by mixing the aqueous reactants until relative homogeneity is attained. The mixture can be heated at once or aged for a period of time. Heating is carried out, typically under pressure at about 140 to about 180°C until crystallization is complete, typically about 12 to 72 hours. These conditions differ from many of the earlier ferrierite synthesis methods in that the time required for crystallization is shorter and the temperature at which the crystallization occurs is much lower. The addition of ferrierite to the synthesis mixture can be used to lower the amount of pyridine required and still obtain high molar silica to alumina ratio, high purity, high surface area ferrierite in 24 hours at 170°C. The type of ferrierite added to the synthesis mixture as seed ("seed ferrierite") is preferably high molar silica to alumina ratio, high purity, high surface area ferrierite made by the methods of this invention although other types of ferrierite can also be used. Seeding the synthesis mixture with low purity ferrierite can result in an inferior ferrierite product and/or non-ferrierite contaminants such as those described earlier. The amount of ferrierite useful is typically from about 0.001, preferably from about 0.1, to about 50, preferably to about 10 wt.%, of the anhydrous weight of the synthesis mixture. Upon crystallization, the ferrierite is recovered by separating it from the mother liquor, for example liquor by filtering or centrifuging, and typically then washing, drying (at a temperature of say, 100 to 200°C) and optionally calcining at a temperature of above about 200°C. The product is ferrierite that does not contain additional crystalline zeolite materials (no crystalline impurities) . Ferrierite isotypic frame structure is the only crystalline phase present as determined by X-ray crystalline diffraction. See the Atlas of Zeolite Structure Types. loc. cit. The prominent structural features of ferrierite isotypic frame structure found by x- ray crystallography are parallel channels in the alumino¬ silicate framework which are roughly elliptical in cross- section. Examples of such zeolites having the ferrierite isotypic framework structure include ferrierite (orthorhombic or monoclinic) , Sr-D, FU-9 (EP B-55,529) , ISI- 6 (US-A-4,578,259) , NU-23 (EP-A-103,981) , ZSM-35 (US-A- 4,016,245) and ZSM-38 (US-A-4,375,573) , i.e. "essentially ferrierite crystalline phase". The ferrierite produced contains preferably more than about 50 moles, more preferably more than 60 moles, most preferably more than 65 moles, preferably to about 500 moles, more preferably to 200 moles, of Si0 2 for each mole of A1 2 0 3 . The composition in the anhydrous state is preferably: 1-3 R : 0.5-0.9 M 2 0 : A1 2 0 3 : 50-200 Si0 2 wherein R is pyridine and M is an alkali metal. The surface area is at least about 350 m 2 /g, preferably at least about 370 m 2 /g, to about 450 m 2 /g. It typically has a platelet-like shape where in one dimension of the crystal is very small, on average less than about 0.2 / xm (thin), typically about O.lμm, and the other two dimensions are much larger, typically an average of greater than about 0.6μm to about 2μm. This ferrierite is suitable for use as a catalyst or carrier in numerous hydrocarbon conversion processes such as catalytic dewaxing. It has been found that, by using this ferrierite, an improved skeletal olefin isomerization catalyst can be obtained. Skeletal Olefin Isomerization Catalyst The ferrierites of the present invention are preferably converted into ammonium ferrierite by ammonium ion-exchange and optionally calcined to yield ferrierite substantially in its hydrogen form (see, e.g. US-A- 4,251,499, 4,795,623, and 4,942,027) i.e. "hydrogen ferrierite". This can be achieved by, for example: d) removing at least a portion of the pyridine by heating it at a temperature of about 500° to about 625°C to obtain a calcined ferrierite; e) contacting the calcined-ferrierite with a source of ammonium ion to provide an ammonium-ion exchanged ferrierite, and f) calcining the ammonium-ion exchanged ferrierite at a temperature from about 200°C to 700°C. The catalysts contain the ferrierite described above, optionally a binder and a coke-oxidation promoting metal such as palladium and/or platinum. To obtain higher selectivities at fixed conversions, greater run life and improved isobutylene yield in processing olefin rich streams, the catalyst is essentially ferrierite crystalline phase and contains more than about 50 moles, preferably more than 60 moles, most preferably more than 65 moles, to preferably 500 moles of Si0 2 for each mole of A1 2 0 3 and the surface area is at least about 350 m 2 /g, preferably at least about 370 m 2 /g. A refractory oxide serves as a binder material. Suitable refractory oxides include natural clays, such as bentonite, montmorillonite, attapulgite, and kaolin and hectonite; alumina; silica; silica-alumina; hydrated alumina; titania; zirconia and mixtures thereof. The weight ratio of zeolite to binder material is suitably from about 60:40 to about 99.5:0.5, preferably from about 75:25 to about 99:1(anhydrous basis). Preferably the binder is an alumina. These suitable binders include silica or any of the conventional alumina-containing binders for preparing catalysts, for example, the aluminas, the silica-aluminas and the clays. For purpose of the invention, "alumina- containing binder" include any of the alumina precursors including the hydrated forms of alumina such as bayerite, boehmite and gibbsite which upon calcination are converted to alumina (A1 2 0 3 ) . Preferred silica-aluminas are the amorphous silica-aluminas such as the aluminosilicate gels and sols. The binders can be provided in any convenient form, such as powders, slurries, gels or sols. When the binders are provided as slurries, gels or sols, at least part of the water used in the mulling step can be found as part of the slurry, gel or sol. Preferred binders are aluminas such as pseudoboehmite and gamma and bayerite aluminas, which are readily available commercially. LaRoche Chemicals, through its VERSAL® family of aluminas and Vista Chemical Company, through its CATAPAL® aluminas, provide suitable alumina powders. Preferred alumina binders, particularly when extrusion is utilized, are the high-dispersibility alumina powders, for example CATAPAL D, which generally have a dispersibility of greater than 50% in aqueous dispersion having an acid (acetic) content of 0.4 milligram equivalents per gram of A1 2 0 3 . The catalysts can be prepared by a variety of methods. In one embodiment, the ferrierite is formed into pellets by compaction or extrusion with a binder and optionally a catalytic metal is added by impregnation of the pellet with a metals-containing solution. After impregnation the catalyst is calcined at elevated temperature. In another embodiment, ferrierite powder and alumina powder are mixed, (e.g., by mulling) with water and one or more compounds of the catalytic metal and the resulting mixture is formed into a pellet. Preferably the pellet is formed by compaction. When extrusion is used, a peptizing acid(s), such as nitric acid, acetic acid, citric acid or mixtures thereof, is added to the mixture and optional extrusion aids such as cellulose derivatives, e.g., METHOCEL® F4M hydroxypropyl methylcellulose, are utilized (The Dow Chemical Company) . The amounts of peptizing acid used are readily determined by routine experimentation and will be an amount that provides a plastic extrudable material. The term "pellets" as used herein can be any shape or form as long as the materials are consolidated. Examples of these shapes, (but not limited to) are cylinders, bi-lobes, tri-lobes, tetra-lobes, gear shapes and spheres that may or may not be hollow. The formed pellets are calcined at a temperature from, say, about 200°C, preferably about 300°C, more preferably about 450°C, to, say about 700°C, preferably about 600°C, more preferably about 525°C. The mixture should be mixed thoroughly or vigorously until the mixture appears uniform. The mixing can be performed by combining all of the components of the mixture at once or by adding the components of the mixture at different stages of mixing. The mixing can be accomplished by mulling, i.e. mixing of powders to which sufficient water has been added to form a thick paste and wherein the mixing is accompanied by shearing of the paste. Commercially available mullers such as the Lancaster Mix Muller and the Simpson Mix Muller can be used. A commercial blender such as a ribbon blender, a high shear mixer and/or a powder mill can also be used for mixing. Hydrocarbon Feed Stream The hydrocarbon feed contains at least one linear (or normal) olefin (or alkene) containing at least four, preferably four to ten, carbon atoms, including a compound containing a linear alkene segment with four to ten carbon atoms. It is believed that long chain linear alkenes and compounds containing long chain linear segments may penetrate the zeolite catalyst for a distance effective to allow isomerization. Thus, the entire molecule need not be small enough to fit entirely within the pore structure of the catalyst. The preferred feed contains butylene (or butene) and/or amylene (or pentene) . As used herein, n-butylene includes all forms of n- butylene, for example 1-butene and 2-butene, either trans-2- butene or cis-2-butene, and mixtures thereof. As used herein, n-amylene or n-pentene, includes 1-pentene, cis- or trans-2-pentene, or mixtures thereof. The n-butylene or n- amylene is generally used in the presence of other substances such as other hydrocarbons. Thus, a feedstream containing n-butylene or n-amylene also can contain other hydrocarbons such as alkanes, other olefins, diolefins such as butadiene and pentadienes, napthenes, acetylenes, aromatics, hydrogen, and inert gases. Typically, the n- butene feedstream used in this invention contains about 10 to 100 wt.% n-butene. For example, a fractionated hydrocarbon feedstream from a fluid catalytic cracking effluent stream generally contains about 20 to about 60 wt.% normal butene and a hydrocarbon effluent from an ethers processing unit, such as methyl-tert-butyl ether (MTBE) generally contains from 40 to about 100 wt.% n-butylene. Feed streams from steam crackers and catalyst crackers may also contain substantial amounts of alkanes, say, up to about 80 wt.%. Olefins obtained by selective hydrogenation of dienes, such as butadiene, may also be used. Isomerizincr Conditions In the processes of this invention, a hydrocarbon stream comprising at least one linear olefin is contacted with the catalytic zeolite under isomerizing conditions. Generally, the hydrocarbon stream is contacted with the above-described zeolite catalyst in a vapor phase at a suitable reaction temperature, pressure and space velocity. Generally, suitable reaction conditions include a temperature of about 200°C to about 650°C, preferably from about 320°C to about 600°C, an olefin partial pressure of above about 0.5 atmosphere, and a total pressure of about 0.5 to about 10.0 atmospheres or higher, a molar hydrogen to hydrocarbon ratio of 0 to about 30 or higher (i.e. the presence of hydrogen is optional) , substantially free of water (i.e., less than about 2.0 wt% of the feed), and a hydrocarbon weight hourly space velocity (WHSV) of about 0.5 to about 100 hr . These reactor streams can contain non- reactive diluents such as alkanes. The hydrogen can be added directly to the feed stream prior to introduction of the isomerization zone, or the hydrogen can be added directly to the isomerization zone. The preferred reaction temperature will depend on a number of factors such as the pressure, the weight hourly space velocity and the feed composition. Lower molecular weight olefins such as butenes are best isomerized at a temperature of above 350°C to 650°C while higher molecular weight olefins are best isomerized at lower temperatures. Pentenes are best isomerized at a temperature form about 200°C to 550°C, and hexenes are best isomerized at a temperature from about 200°C to 500°C. Mixed butenes and pentenes are best isomerized at a temperature from about 200°C to 600°C and mixed pentenes and hexenes from about 200°C to 525°C. The use of a lower temperature may be advantageous when the olefin is easily cracked to lighter unwanted species at higher temperatures. It is also possible to achieve higher concentrations of desired products at lower temperatures due to the fact that higher equilibrium concentrations of the branched olefins are possible at lower temperatures. In a typical butene isomerization process scheme, a butene vapor stream is contacted with such catalyst in a reactor at about 320°C to about 650°C, at an olefin partial pressure of about 5 psia to about 50 psia and a total pressure of about 15 to about 100 psia, and at an olefin based WHSV of about 0.5 to about 50 hr "1 . Preferred isomerizing conditions are a temperature of above 350°C to about 450°C, at atmospheric pressure, and an olefin based WHSV of between about 2 to about 25 hr "1 , more preferably between about 2 to about 15 hr "1 . In a typical pentene isomerization process scheme, a pentene vapor stream is contacted with such catalyst in a reactor at about 250°C to about 550°C, at an olefin partial pressure of about 3 psia to about 100 psia and a total pressure of about 15 to about 100 psia, and at an olefin based WHSV of about 1 to about 100 hr "1 . Preferred isomerizing conditions are a temperature of about 300°C to 425°C atmospheric pressure, and an olefin based WHSV of about 2 to about 40 hr "1 . For a mixed feed, reaction conditions between pentene and butene isomerization processes can be used depending on the desired product mix. The following examples further illustrate the present invention. The proportions are in parts by weight (pbw) , percent by weight, moles or equivalents. The x-ray diffraction patterns of the zeolites prepared in the examples were determined. The radiation was the K-alpha doublet of copper. The peak heights (I) and their position as a function of two-theta were read from a spectrometer chart. Theta is the Bragg angle. These readings were used to calculate relative intensities and interplanar spacings according to established practice. The results generated were compared with the results generated from known samples of ferrierite. The crisp nature of the XRD spectra of ferrierite prepared by our method also indicates their phase purity. The surface area of the ferrierite samples was determined by a modification of ASTM test method D3663-92. This method utilizes a modification of the gas adsorption technique of surface area measurement described by Brunauer, Emmett and Teller, (BET) . Ferrierite samples that contained template were calcined in air at 500°C for a period of 3 hours to remove the template before determining the surface area of the ferrierite samples. The samples were degassed by heating in vacuum at 350°C to remove sorbed vapors and then cooled to liquid nitrogen temperature. The quantity of nitrogen adsorbed at low pressure is determined by measuring the pressure difference after the introduction of a fixed volume of nitrogen to the sample. Under these conditions, nitrogen is sorbed into zeolite micropores. The volumetric sorption measurement is measured at pressure levels of P/Po between 0.02 and 0.05. The magnitude of the nitrogen sorbed is calculated using the BET equation. Example 1 This example illustrates the preparation of high molar silica to alumina ratio, high purity, high surface area ferrierite according to the present invention. 21.6g of hydrated aluminum sulfate was dissolved in 1000.2g of deionized water. To this solution was added 109.2g of pyridine followed by 46.9g of 97% sulfuric acid. This solution was mixed well before adding 472.2g of sodium silicate with a composition of 28.7% Si0 2 , 8.9% Na 2 0, balance water. After mixing the resulting gel for 30 minutes, it was placed in a stirred autoclave and heated at 170°C for 24 hours. The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /2.7 Na 2 O/60 Si0 2 /1938 H 2 0/36.7 pyridine The OH " /Si0 2 ratio of the charge was 0.09. The resultant solid product was cooled to room temperature, separated from the liquid by filtration, washed with 33 ml of 150°F water per gram of product and dried at 250°F. A portion of the product was subjected to x-ray analysis and was found to be pure ferrierite. After cal¬ cination at 1000°F for 5 hours to remove the pyridine, the surface area of the product was determined to be 393 m 2 /g. The product had a Si0 2 /Al 2 0 3 of 53 and contained 1.24% Na 2 0, anhydrous. The calcined product was then converted into the ammonium form of ferrierite by ion exchange with aqueous ammonium nitrate, (4 parts by weight of ammonium nitrate per part by weight of ferrierite) . The ammonium ion exchange was conducted at 200°F for two hours. The ion exchanged product was separated from the liquid by filtration, washed with 3 gallons of 150°F water per pound of ferrierite and dried at 250°F. The surface area of the product was determined to be 398 m 2 /g. The dried ammonium exchanged product was analyzed and found to have a molar Si0 2 /Al 2 0 3 of 55:1 and contain 139 ppm Na 2 0, anhydrous. A portion of the dried ammonium exchanged ferrierite was pressed, crushed and sieved into 6-20 mesh particles. The 6-20 mesh particles were converted into the hydrogen form of ferrierite by calcination in flowing air at 500°C for two hours. Example 2 21.Og of hydrated aluminum sulfate was dissolved in 918.2g of deionized water. To this solution was added 123.Ig of pyridine and 54.6g of 97% sulfuric acid. After mixing this solution well, 533.5g of sodium silicate (same composition as Example 1) were added. The resulting gel was mixed well for 30 minutes and charged to a stirred autoclave. The autoclave was heated at 170°C for 24 hours. The resulting solid product was cooled to room temperature, separated from the liquid by filtration, washed with 33 ml of 150°F water per gram of product and dried at 250°F. A portion of the product was subjected to x-ray analysis and was found to be pure ferrierite. After calcination at 1000°F for 5 hours to remove the pyridine, the surface area of the product was determined to be 392 m 2 /g. The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /3.15 Na 2 O/70 Si0 2 /1938 H 2 0/42.8 pyridine The OH"/Si0 2 ratio of the charge was 0.09. The product had a Si0 2 /Al 2 0 3 ratio of 65.1 and contained 1.34% Na 2 0, anhydrous. Example 3 23.1g of hydrated aluminum sulfate was added to 722.Og of deionized water and mixed until it dissolved. To this solution was added 86.6g of pyridine and 81.8g of 97% sulfuric acid. After good mixing of this solution, 736.4g of sodium silicate (same composition as Example 1) was added and the resulting gel was mixed well for 30 minutes. The gel was charged to a stirred autoclave and heated at 150°C for 72 hours. The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /3.13 Na 2 0/87.2 Si0 2 /1661.5 H 2 0/27.1 pyridine The OH'/Si0 2 ratio of the charge was 0.072. The resulting solid product was cooled to room temperature, separated from the liquid by filtration, washed with 33 ml of 150°F water/gram of product and dried at 250°F. A portion of the product was subjected to x-ray analysis and was found to be pure ferrierite. After calcination at 1000°F for 5 hours to remove the pyridine, the surface area of the product was determined to be 391 m 2 /g. The product had a Si0 2 /Al 2 0 3 ratio of 78.0 and contained 1.06% Na 2 0, anhydrous. The calcined product was then converted into the ammonium form of ferrierite by ion exchange with aqueous ammonium nitrate, (2 parts by weight of ammonium nitrate per part by weight of ferrierite) . The ammonium ion exchange was conducted at 200°F for two hours. The ion exchanged product was separated from the liquid by filtration, washed with 3 gallons of 150°F water per pound of ferrierite and dried at 250°F. The surface area of the product was determined to be 395 m 2 /g. The dried ammonium exchanged product was analyzed and found to have a molar Si0 2 /Al 2 0 3 of 78:1 and contain 92 ppm Na 2 0, anhydrous. A portion of the dried ammonium exchanged ferrierite was pressed, crushed and sieved into 6-20 mesh particles. The 6-20 mesh particles were converted into the hydrogen form of ferrierite by calcination in flowing air at 500°C for two hours. Example 4 38.4g of hydrated aluminum sulfate was dissolved in 1470.3g of deionized water. To this solution was added 158.8g of pyridine and 150.3g of 97% sulfuric acid. This solution was mixed well before adding 1307.2g of sodium silicate (same composition as Example 1) . The resulting gel was mixed well for 30 minutes and placed in a stirred autoclave. The autoclave was heated at 150°C for 72 hours. The resulting solid product was cooled to room temperature, separated from the liquid by filtration, washed with 33 ml of 150°F water/gram of product and dried at 250°F. A portion of the product was subjected to x-ray analysis and was found to be pure ferrierite. After calcination at 1000°C for 5 hours to remove the pyridine, the surface area of the product was determined to be 389 m 2 /g. The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /2.81 Na 2 0/93.5 Siθ 2 /1938 H 2 O/30 pyridine The OH"/Si0 2 ratio of the charge was 0.06. The product had a Si0 2 /Al 2 0 3 of 84.4 and contained 1.28% Na 2 0, anhydrous. Example 5 20.5g of hydrated aluminum sulfate was added to 914.Ig of deionized water and dissolved with mixing. To this solution was added 98.3g of pyridine and 35.Ig of sodium hydroxide. 83.2g of sodium sulfate was added to the solution and dissolved. After mixing well, 498.8g of a 40% silica sol (composition 40% Si0 2 , 0.5% Na 2 0, balance water) was added. The resulting gel was mixed well for 30 minutes before placing it in a stirred autoclave. The autoclave was heated at 170°C for 36 hours. The resultant solid product was cooled to room temperature, separated from the liquid by filtration, washed with 33 ml of 150°F water/gram of product and dried at 250°F. A portion of the product was subjected to x-ray analysis and found to be pure ferrierite. After calcination at 1000°F for 5 hours to remove the pyridine, the surface area of the product was determined to be 351 m 2 /g. The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /4.3 Na 2 0/93.5 Si0 2 /1938 H 2 0/22.5 Na 2 SO 4 /30 pyridine The 0H"/Si0 2 ratio of the charge was 0.092. The product had a molar Si0 2 /Al 2 0 3 ratio of 77.2 and contained 1.64% Na 2 0, anhydrous. Example 6 This is an example illustrating the product formed when the present invention is not followed. 24.4g of hydrated aluminum sulfate was dissolved in 757.8g of deionized water. To this solution was added 92.9g of 97% sulfuric acid and 91.Og of pyridine. The solution was mixed well before adding 774.Ig of sodium silicate (same composition as Example 1) . The resulting gel was mixed for 30 minutes and placed in a stirred autoclave. The autoclave was heated at 150°C for 72 hours. The resultant solid product was cooled to room temperature, separated from the liquid by filtration, washed with 33 ml of 150°F water/gram of product and dried at 250°F. A portion of the product was submitted to x-ray analysis and found to be amorphous. The molar composition of the autoclave charge was: 1. 0 Al 2 0 3 /1.53 Na 2 0/87 . 2 Si0 2 / 1661. 5 H 2 0/27. 1 pyridine The OH " /Si0 2 ratio of this formulation was 0. 035. This is below the amount required according to the present invention. Example 7 This is another example of the product formed when the present invention is not followed. 23.4g of hydrated aluminum sulfate was dissolved in 747.5g of deionized water. To this solution was added 71.Ig of 97% sulfuric acid and 87.5g of pyridine. This solution was mixed well before adding 720.6g of sodium silicate (same composition as Example 1) . The resulting gel was placed in a stirred autoclave and heated at 150°C for 72 hours. The resultant solid product was cooled to room temperature, separated from the liquid by filtration, washed with 33 ml of 150°F water/gram of product and dried at 250°F. A portion of the product was submitted to x-ray analysis and found to contain some ferrierite contaminated with magadiite-like material(s). The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /5. 1 Na 2 0/84 .4 Si0 2 / 1661. 5 H 2 0/27. 1 pyridine The OH"/Si0 2 ratio of this formulation was 0.12. This ratio is too high for the molar silica to alumina ratio used in this example. Example 8 This is an example of the product resulting when the present invention is not followed. 20.5g of hydrated aluminum sulfate was dissolved in 899.3g of deionized water. To this solution was added 84.5g of pyridine and 64.Og of 50% sodium hydroxide. 81.5g of sodium sulfate was then added to the well mixed solution. The mixture was agitated until the solids dissolved. Finally 500.3g of 40% silica sol (same composition as Example 5) was added and the resulting gel was mixed for 30 minutes. The gel was placed in a stirred autoclave and heated at 170°C for 36 hours. The resultant solid product was cooled to room temperature, separated from the liquid by filtration, washed with 33 ml. of 150°F water/gram of product and dried at 250°F. A portion of the product was submitted to x-ray analysis and found to contain some ferrierite as well as quartz and other crystalline silica phases. After calcination at 1000°F for 5 hours to remove the pyridine, the product had a surface area of 254 m 2 /g. The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /9.35 Na 2 0/93.5 Si0 2 /1938 H 2 0/19.1 Na 2 SO 4 /30 pyridine The product had a Si0 2 /Al 2 0 3 of 65.8 and contained 2.23% Na 2 0, anhydrous. The OH " /Si0 2 ratio of this formulation was 0.2. This ratio is outside the amounts required for the present invention. Example 9 This is an example where ferrierite was prepared using piperidine instead of pyridine as template. 21.5g of hydrated aluminum sulfate was dissolved in 995.3g of deionized water. To this solution was added 116.8g of piperidine and 46.5g of 97% sulfuric acid. This solution was mixed well and 470.Og of sodium silicate (same composition as in Example 1) was added. The resulting gel was mixed well for 30 minutes and placed in a stirred autoclave. The autoclave was heated at 170°C for 36 hours. The resultant solid product was treated as described in the previous examples, and was found to be ferrierite contam¬ inated with magadiite. The surface area of the product was 322 m 2 /g. The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /2.7 Na 2 O/60 Si0 2 /1938 H 2 0/36.7 piperidine The OH " /Si0 2 ratio of the charge was 0.09. The product had a Si0 2 /Al 2 0 3 of 37.6 and contained 0.78% Na 2 0, anhydrous. Contaminated ferrierite was produced in this example because piperidine was substituted directly for pyridine as the template in the formulation. Example 10 This example follows the teachings of the present invention and describes a more efficient synthesis of high molar silica to alumina ratio, high purity, high surface area ferrierite. 78.5g of hydrated aluminum sulfate was dissolved in 1235.4g of deionized water. To this solution was added 166.5g of 97% sulfuric acid and 1681.Og of sodium silicate (same composition as in Example 1) . The resulting gel was mixed well for 30 minutes before adding 208.6g of pyridine followed again by 30 minutes of mixing. The final mix was placed in a stirred autoclave and heated at 170°C for 24 hours. The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /2.7 Na 2 O/60 Si0 2 /975 H 2 0/19.7 pyridine The 0H"/Si0 2 ratio of the charge was 0.09. The resultant solid product was treated as described in the previous examples and was found to be pure ferrierite with a surface area of 388 m 2 /g. The product had a Si0 2 /Al 2 0 3 of 57:1 and contained 1.97% Na 2 0, anhydrous. The calcined product was then converted into the ammonium form of ferrierite by ion exchange with aqueous ammonium nitrate, (2 parts by weight of ammonium nitrate per part by weight of ferrierite) . The ammonium ion exchange was conducted at 200°F for two hours. The ion exchanged product was separated from the liquid by filtration, washed with 3 gallons of 150°F water per pound of ferrierite and dried at 250°F. The surface area of the product was determined to be 369 m 2 /g. The dried ammonium exchanged product was analyzed and found to have a molar Si0 2 /Al 2 0 3 of 62:1 and contain 480 ppm Na 2 0, anhydrous. The product had a n-hexane sorption capacity of 7.3 grams per 100 grams of zeolite. A portion of the dried ammonium exchanged ferrierite was pressed, crushed and sieved into 6-20 mesh particles. The 6-20 mesh particles were converted into the hydrogen form of ferrierite by calcination in flowing air at 500°C for two hours. Example 11 This example follows the teachings of the present invention but shows that a certain minimum amount of pyri- dine is required to crystallize high ratio, high purity, high surface area ferrierite. 22.4g of hydrated aluminum sulfate was dissolved in 1040.2g of deionized water. To this solution was added 34.5g of pyridine and 48.7g of 97% sulfuric acid. This solution was mixed well. 491.Og of sodium silicate (same composition as in Example 1) was added to the solution and the resulting gel was mixed well for 30 minutes. The gel was placed in a stirred autoclave and heated at 170°C for 24 hours. The resultant solid product was treated as described in the earlier examples and was found to be amorphous. The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /2.7 Na 2 O/60 Si0 2 /1938 H 2 0/15.4 pyridine The OH " /Si0 2 ratio of the charge was 0.09. Example 12 This example shows the effect of seeding the synthesis mix with crystalline ferrierite on preparation of high ratio, high purity, high surface area ferrierite following the teachings of the present invention. 23.Ig of hydrated aluminum sulfate was dissolved in 1046.4g of deionized water. To this solution was added 49.Og of pyridine and 37.3g of 97% sulfuric acid with good mixing. 7.3g of high ratio, high purity ferrierite prepared by the present invention was added to the solution and dispersed well. To this slurry was added 494.2g of sodium silicate (same composition as in Example 1) and the resulting gel was mixed well for 30 minutes. The gel was placed in a stirred autoclave and heated at 170°C for 24 hours. The resultant solid product was treated as described in the previous examples and was found to be high ratio, high purity ferrierite with a surface area of 419 m 2 /g. The molar composition of the autoclave charge was: 1.0 Al 2 0 3 /2.7 Na 2 O/60 Si0 2 /1938 H 2 0/12 pyridine The OH " /Si0 2 ratio of the charge was 0.09. The product had a Si0 2 /Al0 3 of 57.2 and contained 1.93% Na 2 0, anhydrous. Example 13 This example describes an additional advantage of high ratio, high purity, high surface area ferrierite prepared according to the present invention. This product can be ion exchanged before calcination to remove the pyridine trapped in the zeolite. A 3N NH 4 N0 3 solution was prepared by dissolving 200g of NH 4 N0 3 in 833.3g of deionized water. To this solution was added 205.3g of a filter cake (LOI = 51.29%) of as-synthesized high ratio, high purity ferrierite made according to Example 10. The solids were dispersed well with good mixing and the slurry was heated at 200°F for 2 hours. The resulting solid product was cooled to room temperature, separated from the liquid by filtration, washed with 25 ml of 150°F water per gram of product and dried at 250°F. The elemental composition of the product was analyzed using atomic adsorption spectroscopy. The product had a Si0 2 /Al 2 0 3 of 61.6 and contained 270 ppm of Na 2 0. After calcination at 1000°F for 5 hours to remove the pyridine, the product had a surface area of 385 m 2 /g. Example 14 A sample of ammonium ferrierite was prepared by the methods outlined in US-A-4,251,499, 4,795,623 and 4,942,027. The sample was pressed, crushed and sieved into 6-20 mesh particles. The particles were then calcined for two hours at 500°C to produce a H-ferrierite catalyst with a surface area of 404 m 2 /g and a molar silica to alumina ratio of 19:1. Example 15 A sample of potassium/sodium ferrierite with a molar silica to alumina ratio of 16:1 was obtained from TOSOH Corporation. The material was ammonium ion-exchanged and converted into 6-20 mesh particles by the methods described above. The particles were then calcined for two hours at 500°C to produce a catalyst with a surface area of 323 m 2 /g and a molar silica to alumina ratio of 16:1. Example 16 A sample of ammonium ferrierite was prepared by the methods outlined in Example 2 of EP-A-501,577. The 0H " /Si0 2 ratio of the autoclave charge was 0.16. The ammonium ferrierite was pressed, crushed and sieved into 6-20 mesh particles. These particles were then calcined for two hours at 500°C to produce a hydrogen ferrierite (H-ferrierite) catalyst with a surface area of 326 m 2 /g and a bulk molar silica to alumina ratio of 87:1. The sample contained about 5-10% non-ferrierite impurities after crystallization and washing. The concentration of these impurities was reduced (but not eliminated) upon the ammonium ion exchange and calcination of the sample. Example 17 This example demonstrates the preparation of an extruded ferrierite catalyst useful in skeletal olefin isomerization. A Lancaster mix muller was loaded with 645 grams of ammonium-ferrierite (5.4% LOI) prepared by the method outlined in Example 10 and 91 grams of CATAPAL® D alumina (LOI of 25.7%) . The alumina was blended with the ferrierite for 5 minutes during which time 152 milliliters of de¬ ionized water was added. A mixture of 6.8 grams glacial acetic acid, 7.0 grams of citric acid and 152 milliliters of de-ionized water was added slowly to the muller in order to peptize the alumina. The mixture was mulled for 10 minutes. 0.20 Grams of tetraammine palladium nitrate in 153 grams of de-ionized water were then added slowly as the mixture was mulled for 5 additional minutes. Ten grams of METHOCEL®(R) F4M hydroxypropyl methylcellulose was added and the zeolite/alumina mixture was mulled for 15 additional minutes. The extrusion mix had an LOI of 43.5%. The 90:10 zeolite/alumina mixture was transferred to the 2.25 inch Bonnot extruder and extruded using a stainless steel die plate with 1/16" holes. The extrudate was dried at 125°C for 16 hours and then calcined in flowing air at a maximum temperature of 500°C for two hours. The calcined extruded had a surface area of 364 m 2 /g. Skeletal Olefin Isomerization A stainless steel tube, 1 inch OD, 0.6 inch ID and 26 inches long was used as a reactor. A thermowell extended 20 inches from the top of the tube. To load the reactor, it was first inverted and a small plug of glass wool was slid down the reactor tube over the thermowell until it hit the bottom of the tube. Silicon carbide (20 mesh) was added to a depth of about 6 inches. Over this was placed a small plug of glass wool. Approximately 4 grams of catalyst particles, 6-20 mesh, (or small extrudates) admixed with about 60 grams of fresh silicon carbide (60-80 mesh) were added in two parts to distribute the catalyst particles evenly. The catalyst bed was typically about 10 inches long. Another piece of glass wool was added to the top of the catalyst and the reactor was topped with 20 mesh silicon carbide, followed by a final plug of glass wool. A multipoint thermocouple was inserted into the thermowell and was positioned such that the temperature above, below and at three different places in the catalyst bed could be monitored. The reactor was inverted and installed in a temperature controlled furnace. The feed utilized was 1-butene obtained from Scott Specialty Gases with a 1-butene content of greater than 99.2% weight. The 1-butene was fed to the reactor in the gas phase. To start up the reactor, it was first heated to the desired operating temperature over a four hour period and held at the operating temperature for 2 hours, all under flowing nitrogen. After this pretreatment, the nitrogen flow was shut off and the 1-butene was added at a rate of 36 g/hr to give the desired weight hourly space velocity of 9.0 hr "1 . The reactor was operated at an outlet pressure of 3 psig and at a temperature of 430°C. Regeneration After running the catalysts in the isomerization process described above, they were found to be black due to the build-up of carbonaceous material (coke) comprising about 10 to 20% wt. Each catalyst was removed from the test reactor and its weight was measured. To demonstrate that the catalyst could be regenerated, two of the catalysts tested were reloaded separately into two test reactors and regenerated by the following procedure. Each reactor was pressurized to 90 psig and a flow of approximately 6 standard liters per hour of air was started. The samples were heated by the following controlled heating procedure: ramp from 25°C to 125°C at 10°C per minute; hold at 125°C for 30 minutes; ramp from 125°C to 350°C at 2°C per minute; ramp from 350°C to 470°C at 1°C per minute and hold at 470°C for 24 hours. The reactors were then cooled and the regenerated catalysts were unloaded. Substantially complete regeneration of the catalysts was confirmed by the disappearance of the black color of the unregenerated catalysts. The catalyst was weighed to measure the coke loss. Calculations Conversion and selectivity are calculated for each sample during testing runs. Therefore the calculation of conversion and selectivity reflect the feed (FD) and effluent (EFF) concentrations of butene-l (BI) and butene-2 (B2) and isobutylene (IB1) . Conversion is calculated as: ^Conversion- i*t*Bl + wt%B2) FD- jwtΛBl + wt%B2) EFF χiQQ (wt%Bl+wt%B2) FD selectivity is calculated as: ^Selectivity- (wt%IBl) EFF- (wt%IBl) FD y (wt%Bl + wt%B2)FD- (wt%Bl + wt%B2)EFF and yield is calculated as: o. γ± d _ ( wt IB1 ) EFF -(wt%IBl) FD y . 0f) (wt%Bl+wt%B2) FD Table 1 shows the skeletal olefin isomerization performance results obtained in testing some of the catalysts prepared in the above Examples. This table provides the hours of run life of the catalyst in the isomerization tests, i.e. the time from the start-of-run to the time at which the concentration of methyl branched olefin in the product (isobutylene in these tests)has declined to 36 Wt.% after having reached its peak concentration. Some of the catalyst tested (Examples 14 and 15) never reached this high a concentration of isobutylene in the product. The catalysts of the present invention were able to achieve the longest run life. The long run life was maintained and sometimes increased upon regeneration of the catalyst. In commercial operation, it may be desirable to let the catalyst operate until the product concentration declines to less than 20 Wt.% isobutylene in the product before regenerating the catalyst. A sample prepared by the methods described in Example 1 had a run life of 603 hours when allowed to run until the isobutylene content dropped to 20 Wt.% in the product. Longer run lives could also be achieved by operating at lower Weight Hourly Space Velocities, WHSV, of 1-butene. Increases in the run life can also be obtained by diluting the olefin content of the feedstock with less reactive gases often present in skeletal olefin isomerization feedstocks. Suitable diluent gases include propane, butanes, pentanes, nitrogen, hydrogen for example. These use of these gases serves to lower the partial pressure of the olefin to be isomerized and leads to higher reported selectivities to the branched olefin. Although the use of diluent gases can increase the run life and the selectivity to isobutylene of the catalysts of this invention, the presence of a diluent gas is not required to obtain longer run life and higher selectivities at fixed conversions than reported for non ferrierite catalysts of the type reported in DE-A-3,000,650 and US-A-5,043,523. Table I also provides the selectivities of the various catalysts at 40% conversion, 45% conversion and 50% conversion and the highest concentration (weight percent) of isobutylene in the product during the testing. As can be seen from Table 1, the catalysts of the present invention (Examples l, 3 and 17) , obtained the highest selectivities at fixed conversion levels and the highest isobutylene concentrations in the product when compared to samples with lower molar silica to alumina ratios (Examples 14, 15) and/or lower surface areas (Examples 15 and 16) . Table 1 clearly shows the improvement in skeletal olefin isomerization performance obtained with catalysts made with high purity, higher molar silica to alumina ferrierite which exhibits high surface areas. The catalyst prepared by Example 3 obtained a selectivity to isobutylene of 95% at 40% conversion. Selectivities of almost 100% were obtained at slightly lower conversion levels with the catalyst of the present invention. At 45% conversion Example 3 obtained 88% selectivity to isobutylene under the conditions of the testing. The catalysts prepared with lower molar silica to alumina ratio ferrierite (Examples 15 and 14) achieved 68% and 70% selectivities to isobutylene at 45% conversion. The catalyst of Example 16 which was made with a high molar silica to alumina ferrierite that had a surface area of 326 m 2 /g achieved a selectivity to isobutylene of 79% at 45% conversion. The catalysts prepared by the present invention all exhibited selectivities to isobutylene of 83% or higher at 45% conversion. The performance advantages of high purity, high molar silica to alumina ferrierite prepared by the present invention allowed extruded catalyst such as the one prepared in Example 17 to outperform the catalysts of Examples 14, 15 and 16 even when diluted with a binder such that it contains less total ferrierite, (Example 17) . These performance advantages were maintained upon multiple regenerations of the ferrierite catalysts. The crystalline ferrierite samples prepared in the Examples were analyzed by Transmission Electron Microscopy, TEM, and Scanning Electron Microscopy, SEM, at magnifications as high as 21,200X. FIG. 1 is a TEM micrograph of the ferrierite produced by the methods of Example 1. The micrograph was taken at 21,20OX magnification. The ferrierite crystals of the present invention exhibit a well-defined platelet type of morphology; one dimension of the crystal has a mean average diameter of about 0.1 μm. The mean of the second largest diameter is about 0.8μm and the mean of the largest diameter is about 1.1 μm. Some of the crystals prepared in Example 1 had a largest diameter of about 2μm. The morphology of the ferrierite made in the present invention is different form that of the morphology of the ferrierite made in Example 14, which appears as smaller, more rounded and irregular crystals. FIG. 2 is a TEM micrograph of the ferrierite prepared by the methods of Example 14. The micrograph was taken at 21,200X magnification. The mean of the largest diameter of the ferrierite crystals made by Example 14 was about 0.4μm. The second largest mean diameter was about 0.2μm. Some of the crystals were about O.lμm or less in all three dimensions. The crystalline morphology of the ferrierite prepared in the present invention is also different from that of the microcrystalline ZSM-35 (a ferrierite isotype) prepared by the method of US-A-3,992,466. The microcrystalline ZSM-35 is reported to exist as very small particles having diameters in the range of 0.005μm to O.lμm. The larger platelet like morphology of the crystals in the present invention, the high surface area and the high molar silica to alumina ratio of the ferrierite allow these high purity ferrierite catalysts to exhibit superior selectivity to isobutylene at fixed conversion levels when processing butylene containing feedstocks. These same ferrierite attributes allow the catalysts to work equally well with other C4-C10 olefin containing feedstocks. TABLE 1. EXAMPLE MOLAR SURFACE AREA %SELECTIVITY AT FIXED CONV. RUN LIFE MAX. IB. No. Si0 2 /Al 2 0 3 (m 2 /g) 50%Conv. 45%Conv. 40%Conv. Hours Produced,%Wt 15 16 323 63 68 73 (a) 32.5 14 19 404 65 70 75 (b) 33.0 1 55 398 77 86 91 233 39.1 1(c) 55 398 78 87 (d) (e) 39.9 17 62 364 74 83 88 142 38.2 17(f) 62 364 74 83 88 144 38.2 3 78 395 77 88 95 233 39.9 16 87 326 69 79 87 75 36.2 t (a) Did not ever achieve 36 %Wt. isobutylene in the product; maximum was 32.5 %Wt. (b) Did not ever achieve 36 %Wt. isobutylene in the product; maximum was 33.0 %Wt. (c) Sample was "run and then regenerated" twice before this test. (d) The run was terminated when the conversion had dropped to 43.4%. (e) Terminated run before the product IB concentration had declined to 36.0 %Wt. The run was stopped with a product IB concentration of 38.9% Wt. after 241.3 hours stream. (f) This extruded sample was "run and then regenerated" twice before this test.

Claims: CLAIMS 1. A crystalline aluminosilicate having the x-ray diffraction pattern of ferrierite and a composition in the anhydrous state of 1-3 R : 0.5-0.9 M 2 0 : A1 2 0 3 : 40-500 Si0 2 wherein R is pyridine and M is an alkali metal, having a surface area of at least about 350 m 2 /g, and being essentially ferrierite crystalline phase. 2. A crystalline aluminosilicate according to claim 1 having a surface area of at least about 370 m 2 /g. 3. A crystalline aluminosilicate according to claim 1 having a surface area of up to about 450 m 2 /g. 4. A crystalline aluminosilicate according to any one of claims l to 3 having a composition in the anhydrous state of 1-3 R : 0.5-0.9 M 2 0 : A1 2 0 3 : 50-200 Si0 2 . 5. A crystalline aluminosilicate according to any one of claims 1 to 4 having a composition in the anhydrous state of 1-3 R : 0.5-0.9 M 2 0 : A1 2 0 3 : 65-100 Si0 2 . 6. A crystalline aluminosilicate according to any one of claims 1 to 5 wherein one dimension of the crystal averages less than about 0.2 μm and the other two dimensions average greater than about 0.6μm. 7. A crystalline aluminosilicate according to claim 1 substantially as described in any one of Examples l to 5 and 10 to 13. 8. A process for preparing a ferrierite crystalline aluminosilicate comprising: a. preparing a mixture comprising sources of an alkali metal, silica, alumina and pyridine, said mixture hav¬ ing the following composition in moles: A1 2 0 3 : 60-500 Si0 2 : 10-40 R : 1.5-4 M 2 0 : 950-2000 H 2 0 wherein R is pyridine, M is an alkali metal and said sources of alkali metal and silica are such that there are 0.05 to 0.15 moles of OH " for each mole of Si0 2 b. heating said mixture at a temperature of 140 to 180°C; c. recovering the ferrierite. 9. A process according to claim 8 wherein the mixture further comprises seed ferrierite to assist in the nucleation and/or growth of the ferrierite. 10. A process according to claims 8 or 9 wherein 0.05 to 0.11 moles of 0H~ are present per mole of Si0 2 . 11. A process according to claim 8 substantially as described in any one of Examples 1 to 5 and 10 to 13. 12. A ferrierite crystalline aluminosilicate whenever prepared by a process as claimed in any one of claims 7 to 11. 13. A process for preparing a hydrogen ferrierite having a surface area of at least about 350 m 2 /g, a silica to alumina ratio of at least 50 and essentially ferrierite crystalline phase which comprises: d. removing at least a portion of the pyridine present in a ferrierite as claimed in any one of claims 1 to 7 and 12 by heating it at a temperature from 500 to 526°C to obtain a calcined-ferrierite, e. contacting the calcined-ferrierite with a source of ammonium ion to provide an ammonium-ion exchanged ferrierite, and f. calcining the ammonium-ion exchanged ferrierite at a temperature from 200°C to 700°C. 14. A process according to claim 13 substantially as described in any one of Examples 1 to 5 and 10 to 13. 15. A hydrogen ferrierite having a surface area of at least about 350 m 2 /g, a silica to alumina ratio, of at least 50 and essentially ferrierite crystalline phase whenever prepared by a process as claimed in claim 13 or 14. 16. A process for structurally isomerizing a linear olefin of at least 4 carbon atoms to its corresponding methyl branched isoolefin which comprises contacting, at a temperature of from 200°C to 650°C, a hydrocarbon feed stream containing at least one said linear olefin with an isomerizing catalyst comprising a hydrogen ferrierite having a surface area of greater than 350 m 2 /g, a silica to alumina ratio of greater than 50, and essentially ferrierite crystalline phase. 17. A process according to claim 16 wherein the isomerizing catalyst is a hydrogen ferrierite having a surface area of at least about 370 m 2 /g. 18. A process according to claims 16 or 17 wherein the isomerizing catalyst is a hydrogen ferrierite having molar silica to alumina ratio of more than 60:1. 19. A process according to any one of claims 16 to 18 wherein the hydrogen ferrierite is one claimed in claim 15.

Inventors: MURRAY BRENDAN DERMOT, PASQUALE GARY MICHAEL, MURRAY, BRENDAN, DERMOT, PASQUALE, GARY, MICHAEL
Applicants: PQ CORP, SHELL OIL CO, PQ CORPORATION, SHELL OIL COMPANY
Application year: 1996
Main classification: C01B39
IPC codes: B01J29, C01B39, C07C5, C07C11