PRINTING METHOD AND APPARATUS EMPLOYING ELECTROSTATIC DROP SEPARATION

Abstract: A constant electric field is applied to a drop on demand print head using coincident force address of selected ink drops. This field can be generated by applying one electric potential to the print head, and a different electric potential to a platen which lies on the opposite side of the recording medium. This field does not need to be modulated, or turned on for each drop to be ejected. As a result, a simple high voltage power supply can be used to generate the electric field. No high voltage switching equipment is required. Also, the spacing between nozzles can be small, as the field applied to a nozzle does not need to be separated from fields applied to adjacent nozzles. The electric field is set to be insufficient to cause ink drops to be drawn from the print head when the ink in the nozzles is in the quiescent position. The drop selection method causes the ink meniscus of selected drops to protrude from the front surface of the print head. Charge accumulates at the meniscus of the protruding drop because the drop radius is small, and because the drop meniscus is the closest point to the opposite electrode. This charge concentrates the force produced by the electric potential field onto the selected drop. This force, in combination with the ink pressure, overcomes the surface tension of the ink, and causes the selected drop to separate from the body of ink. The selected drop then accelerates towards the platen, striking the recording medium. By this means, a drop can be printed on a print medium even when the drop selection method does not impart sufficient kinetic energy to the selected drop to cause the selected drop to overcome surface tension forces and separate from the body of ink.

Description: PRINTING METHOD AND APPARATUS EMPLOYING ELECTROSTAΗC DROP SEPARAΗON Field ofthe Invention The present invention is in the field of computer controlled printing devices. In particular, the field is liquid ink drop on demand (DOD) printing systems. Background of the Invention Many different types of digitally controlled printing systems have been invented, and many types are currently in production. These printing systems use a variety of actuation mechanisms, a variety of marking materials, and a variety of recording media. Examples of digital printing systems in current use include: laser electrophotographic printers; LED electrophotographic printers; dot matrix impact printers; thermal paper printers; film recorders; thermal wax printers; dye diffusion thermal transfer printers; and inkjet printers. However, at present, such electronic printing systems have not significantly replaced mechanical printing presses, even though this conventional method requires very expensive setup and is seldom commercially viable unless a few thousand copies of a particular page are to be printed. Thus, there is a need for improved digitally controlled printing systems, for example, being able to produce high quality color images at a high-speed and low cost, using standard paper. Inkjet printing has become recognized as a prominent contender in d e digitally controlled, electronic printing arena because, e.g., of its non-impact, low-noise characteristics, its use of plain paper and its avoidance of toner transfers and fixing. Many types of ink jet printing mechanisms have been invented. These can be categorized as either continuous inkjet (CIJ) or drop on demand (DOD) inkjet. Continuous inkjet printing dates back to at least 1929: Hansell, US Pat. No. 1,941,001. Sweet et al US Pat. No. 3,373,437, 1967, discloses an array of continuous ink jet nozzles where ink drops to be printed are selectively charged and deflected towards the recording medium. This technique is known as binary deflection CIJ, and is used by several manufacturers, including Elmjet and Scitex. Hertz et al US Pat. No. 3,416,153, 1966, discloses a method of achieving variable optical density of printed spots in CIJ printing using the electrostatic dispersion of a charged drop stream to modulate the number of droplets which pass through a small aperture. This technique is used in ink jet printers manufactured by Iris Graphics. Kyser et al US Pat. No. 3,946,398, 1970, discloses a DOD inkjet printer which applies a high voltage to a piezoelectric crystal, causing the crystal to bend, applying pressure on an ink reservoir and jetting drops on demand. Many types of piezoelectric drop on demand printers have subsequently been invented, which utilize piezoelectric crystals in bend mode, push mode, shear mode, and squeeze mode. Piezoelectric DOD printers have achieved commercial success using hot melt inks (for example, Tektronix and Dataproducts printers), and at image resolutions up to 720 dpi for home and office printers (Seiko Epson). Piezoelectric DOD printers have an advantage in being able to use a wide range of inks. However, piezoelectric printing mechanisms usually require complex high voltage drive circuitry and bulky piezoelectric crystal arrays, which are disadvantageous in regard to manufacturability and performance. Endo et al GB Pat. No. 2,007,162, 1979, discloses an electrothermal DOD inkjet printer which applies a power pulse to an electrothermal transducer (heater) which is in thermal contact with ink in a nozzle. The heater rapidly heats water based ink to a high temperature, whereupon a small quantity of ink rapidly evaporates, forming a bubble. The formation of these bubbles results in a pressure wave which cause drops of ink to be ejected from small apertures along the edge of the heater substrate. This technology is known as Bubblejet™ (trademark of Canon K.K. of Japan), and is used in a wide range of printing systems from Canon, Xerox, and other manufacturers. Vaught et al US Pat. No. 4,490,728, 1982, discloses an electrothermal drop ejection system which also operates by bubble formation. In this system, drops are ejected in a direction normal to the plane of the heater substrate, through nozzles formed in an aperture plate positioned above the heater. This system is known as Thermal Ink Jet, and is manufactured by Hewlett-Packard. In this document, the term Thermal Ink Jet is used to refer to both the Hewlett- Packard system and systems commonly known as Bubblejet™. Thermal Ink Jet printing typically requires approximately 20 μJ over a period of approximately 2 μs to eject each drop. The 10 Watt active power consumption of each heater is disadvantageous in itself and also necessitates special inks, complicates the driver electronics and precipitates deterioration of heater elements. Other ink jet printing systems have also been described in technical literature, but are not currently used on a commercial basis. For example, U.S. Patent No. 4,275,290 discloses a system wherein the coincident address of predetermined print head nozzles with heat pulses and hydrostatic pressure, allows ink to flow freely to spacer-separated paper, passing beneath the print head. U.S. Patent Nos. 4,737,803; 4,737,803 and 4,748,458 disclose ink jet recording systems wherein the coincident address of ink in print head nozzles with heat pulses and an electrostatically attractive field cause ejection of ink drops to a print sheet Each of the above-described inkjet printing systems has advantages and disadvantages. However, there remains a widely recognized need for an improved ink jet printing approach, providing advantages for example, as to cost, speed, quality, reliability, power usage, simplicity of construction and operation, durability and consumables. Summary ofthe invention My concurrently filed applications, entitled "Liquid Ink Printing Apparatus and System" and "Coincident Drop-Selection, Drop-Separation Printing Method and System" describe new methods and apparatus that afford significant improvements toward overcoming the prior art problems discussed above. Those inventions offer important advantages, e.g., in regard to drop size and placement accuracy, as to printing speeds attainable, as to power usage, as to durability and operative thermal stresses encountered and as to other printer performance characteristics, as well as in regard to manufacturability and the characteristics of useful inks. One important purpose of the present invention is to further enhance the structures and methods described in those applications and thereby contribute to the advancement of printing technology. One significant objective of the present invention is to provide new methods and apparatus for drop on demand printing that afford improvements in regard to prior approaches. The present invention offers advantages, e.g., in regard to drop size and placement accuracy, as to printing speeds achievable, as to power usage, as to durability and the operative thermal stresses encountered and as to various other printing performance characteristics, noted in more detail hereinafter. In other important features, the present invention offers significant advantages as to manufacture and as to the nature of its useful inks. Thus, in one aspect, the present invention constitutes a drop on demand printing apparatus comprising nozzle means including an array of closely spaced drop ejection orifices, manifold means for supplying a body of ink in common communication with the orifices of said nozzle means, means for applying a positive pressure to ink in said manifold means, sufficient to cause ink to protrude from said orifices, address means for energizing ink in selected orifices to cause the ink to protrude further from selected orifices, and means for producing an electric field between ink in said orifices and a print station spaced opposite said nozzle means sufficient to attractively detach such further protruding ink from the nozzle means. In another aspect, the invention is a method of separating selected drops of ink from the body of ink in such printing apparatus by electrostatic attraction. A constant electric field can be applied to the entire print head. This field can be generated by applying one electric potential to the print head, and a different electric potential to a platen which lies on the opposite side of the recording medium. This field does not need to be modulated, or turned on for each drop to be ejected. As a result, a simple high voltage power supply can be used to generate the electric field. No high voltage switching equipment is required. Also, the spacing between nozzles can be small, as the field applied to a nozzle does not need to be separated from fields applied to adjacent nozzles. The electric field is set to be insufficient to cause ink drops to be drawn from the print head when the ink in the nozzles in the quiescent position. The drop selection method causes the ink meniscus of selected drops to protrude from the front surface of the print head. Charge accumulates at the meniscus of the protruding drop, because the drop radius is small, and because the drop meniscus is the closest point to the opposite electrode. This charge concentrates the force produced by the electric potential field onto the selected drop. This force, in combination with the ink pressure, overcomes the surface tension of the ink, an _ causes the selected drop to separate from the body of ink. The selected drop thin accelerates towards the platen, striking the recording medium. By this means, a drop of can be printed on a print medium even when the drop selection method does not impart sufficient kinetic energy to the selected drop to cause the selected drop to overcome surface tension forces and separate from the body of ink. Brief Description ofthe Drawings Figure 1 (a) shows a simplified block schematic diagram of one exemplary printing apparatus according to the present invention. Figure 1(b) shows a cross section of one variety of nozzle tip in accordance with the invention. Figures 2(a) to 2(f) show fluid dynamic simulations of drop selection. Figure 3(a) shows a finite element fluid dynamic simulation of a nozzle in operation according to an embodiment ofthe invention. Figure 3(b) shows successive meniscus positions during drop selection and separation. Figure 3(c) shows the temperatures at various points during a drop selection cycle. Figure 3(d) shows measured surface tension versus temperature curves for various ink additives. Figure 3(e) shows the power pulses which are applied to the nozzle heater to generate the temperature curves of figure 3(c) Figure 4 shows a block schematic diagram of print head drive circuitry for practice of the invention. Figure 5 shows projected manufacturing yields for an A4 page width color print head embodying features of the invention, with and without fault tolerance. Figure 6 shows a generalized block diagram of a printing system using one embodiment of the present invention. Figure 7 shows a cross section of an example print head nozzle embodiment ofthe invention used for computer simulations shown in Figures 8 to 18. Figure 8(a) shows the power sub-pulses applied to the print head for a single heater energizing pulse. Figure 8(b) shows the temperature at various points in the nozzle during the drop selection process. Figure 9 is a graph of meniscus position versus time for the drop selection process. Figure 10 is a plot of meniscus position and shape at 5 μs intervals during the drop selection process. Figure 11 shows the quiescent position of the ink memscus before the drop selection process. Figures 12 to 17 show the meniscus position and thermal contours at various stages during the drop selection process. Figure 18 shows fluid streamlines 50 μs after the beginning of the drop selection heater pulse. Figures 19(a) to 19(e) show stages in the ejection of an ink drop from a thermally addressed nozzle using electrostatic drop separation. eriled pescription of Preferred Embodiments In one general aspect, the invention constitutes a drop-on-demand printing mechanism wherein the means of selecting drops to be printed produces a difference in position between selected drops and drops which are not selected, but which is insufficient to cause the ink drops to overcome the ink surface tension and separate from the body of ink, and wherein an alternative means is provided to cause separation of the selected drops from the body of ink. The separation of drop selection means from drop separation means significantly reduces the energy required to select which ink drops are to be printed. Only the drop selection means must be driven by individual signals to each nozzle. The drop separation means can be a field or condition applied simultaneously to all nozzles. The drop selection means may be chosen from, but is not limited to, the following list: 1 ) Electrothermal reduction of surface tension of pressurized ink 2) Electrothermal bubble generation, with insufficient bubble volume to cause drop ejection 3) Piezoelectric, with insufficient volume change to cause drop ejection 4) Electrostatic attraction with one electrode per nozzle The, drop separation means may be chosen from, but is not limited to, the following list: 1 ) Proximity (recording medium in close proximity to print head) 2) Proximity with oscillating ink pressure 3) Electrostatic attraction 4) Magnetic attraction The table "DOD printing technology targets" shows some desirable characteristics of drop on demand printing technology. The table also lists some methods by which some embodiments described herein, or in other of my related applications, provide improvements over the prior art. DOD printing technology targets Target Method of achieving improvement over prior art High speed operation Practical, low cost, pagewidth printing heads with more than 10,000 nozzles. Monolithic A4 pagewidth print heads can be manufactured using standard 300 mm (12") silicon wafers High image quality High resolution (800 dpi is sufficient for most applications), six color process to reduce image noise Full color operation Halftoned process color at 800 dpi using stochastic screening Ink flexibility Low operating ink temperature and no requirement for bubble formation Low power Low power operation results from drop selection means requirements not being required to fully eject drop Low cost Monohthic print head without aperture plate, high manufacturing yield, small number of electrical connections, use of modified existing CMOS manufacturing facilities High manufacturing Integrated fault tolerance in printing head yield High reliability Integrated fault tolerance in printing head. Elimination of cavitation and kogation. Reduction of thermal shock. Small number of Shift registers, control logic, and drive circuitry can be electrical connections integrated on a monolithic print head using standard CMOS processes Use of existing VLSI CMOS compatibility. This can be achieved because the manufacturing heater drive power is less is than 1% of Thermal Ink Jet facilities heater drive power Electronic collation A new page compression system which can achieve 100:1 compression with insignificant image degradation, resulting in a compressed data rate low enough to allow real-time printing of any combination of thousands of pages stored on a low cost magnetic disk drive. In thermal inkjet (TD) and piezoelectric inkjet systems, a drop velocity of approximately 10 meters per second is preferred to ensure that the selected ink drops overcome ink surface tension, separate from the body of the ink, and strike the recording medium. These systems have a very low efficiency of conversion of electrical energy into drop kinetic energy. The efficiency of TU systems is approximately 0.02%). This means that the drive circuits for TU print heads must switch high currents. The drive circuits for piezoelectric ink jet heads must either switch high voltages, or drive highly capacitive loads. The total power consumption of pagewidth TU printheads is also very high. An 800 dpi A4 full color pagewidth TU print head printing a four color black image in one second would consume approximately 6 kW of electrical power, most of which is converted to waste heat. The difficulties of removal of this amount of heat precludes the production of low cost, high speed, high resolution compact pagewidth TU systems. One important feature of embodiments of the invention is a means of significantly reducing the energy required to select which ink drops are to be printed. This is achieved by separating the means for selecting ink drops from the means for ensuring that selected drops separate from the body of ink and form dots on the recording medium. Only the drop selection means must be driven by individual signals to each nozzle. The drop separation means can be a field or condition applied simultaneously to all nozzles. The table "Drop selection means" shows some of the possible means for selecting drops in accordance with the invention. The drop selection means is only required to create sufficient change in the position of selected drops tiiat the drop separation means can discriminate between selected and unselected drops. Drop selection means Method Advantage Limitation 1. Electrothermal Low temperature increase Requires ink pressure reduction of surface and low drop selection regulating mechanism. Ink tension of pressurized energy. Can be used with surface tension must reduce ink many ink types. Simple substantially as temperature fabrication. CMOS drive increases circuits can be fabricated on same substrate 2. Electrothermal Medium drop selection Requires ink pressure reduction of ink energy, suitable for hot oscillation mechanism. Ink viscosity, combined melt and oil based inks. must have a large decrease with oscillating ink Simple fabrication. in viscosity as temperature pressure CMOS drive circuits can increases be fabricated on same substrate 3. Electrothermal Well known technology, High drop selection energy, bubble generation, simple fabrication, bipolar requires water based ink, with insufficient drive circuits can be problems with kogation, bubble volume to fabricated on same cavitation, thermal stress cause drop ejection substrate 4. Piezoelectric, with Many types of ink base High manufacturing cost, insufficient volume can be used incompatible with integrated change to cause drop circuit processes, high drive ejection voltage, mechanical complexity, bulky 5. Electrostatic Simple electrode Nozzle pitch must be attraction with one fabrication relatively large. Crosstalk electrode per nozzle between adjacent electric fields. Requires high voltage drive circuits Other drop selection means may also be used. The preferred drop selection means for water based inks is method 1: "Electrothermal reduction of surface tension of pressurized ink". This drop selection means provides many advantages over other systems, including; low power operation (approximately 1% of TU), compatibility with CMOS VLSI chip fabrication, low voltage operation (approx. 10 V), high nozzle density, low temperature operation, and wide range of suitable ink formulations. The ink must exhibit a reduction in surface tension with increasing temperature. The preferred drop selection means for hot melt or oil based inks is method 2: 'Εlectrothermal reduction of ink viscosity, combined with oscillating ink pressure". This drop selection means is particularly suited for use with inks which exhibit a large reduction of viscosity with increasing temperature, but only a small reduction in surface tension. This occurs particularly with non-polar ink carriers with relatively high molecular weight This is especially applicable to hot melt and oil based inks. The table "Drop separation means" shows some of the possible methods for separating selected drops from the body of ink, and ensuring that the selected drops form dots on the printing medium. The drop separation means discriminates between selected drops and unselected drops to ensure that unselected drops do not form dots on the printing medium. Drop separation means Means Advantage Limitation 1. Electrostatic Can print on rough Requires high voltage power attraction surfaces, simple supply implementation 2. AC electric field Higher field strength is Requires high voltage AC possible than electrostatic, power supply synchronized operating margins can be to drop ejection phase. increased, ink pressure Multiple drop phase reduced, and dust operation is difficult accumulation is reduced 3. Proximity Very small spot sizes can Requires print medium to be (print head in close be achieved. Very low very close to print head proximity to, but power dissipation. High surface, not suitable for not touching, drop position accuracy rough print media, usually recording medium) requires transfer roller or belt 4. Transfer Very small spot sizes can Not compact due to size of Proximity (print be achieved, very low transfer roller or transfer head is in close power dissipation, high belt. proximity to a accuracy, can print on transfer roller or rough paper belt 5. Proximity with Useful for hot melt inks Requires print medium to be oscillating ink using -viscosity reduction very close to print head pressure drop selection method, surface, not suitable for reduces possibility of rough print media. Requires nozzle clogging, can use ink pressure oscillation pigments instead of dyes apparatus 6. Magnetic Can print on rough Requires uniform high attraction surfaces. Low power if magnetic field strength, permanent magnets are requires magnetic ink used Other drop separation means may also be used. The preferred drop separation means depends upon the intended use. For most applications, method 1: "Electrostatic attraction", or method 2: "AC electric field" are most appropriate. For applications where smooth coated paper or film is used, and very high speed is not essential, method 3: "Proximity" may be appropriate. For high speed, high quahty systems, method 4: 'Transfer proximity" can be used. Method 6: "Magnetic attraction" is appropriate for portable printing systems where the print medium is too rough for proximity printing, and the high voltages required for electrostatic drop separation are undesirable. There is no clear 'best' drop separation means which is applicable to all circumstances. Further details of various types of printing systems according to the present invention are described in the following Austrahan patent specifications filed on 12 April 1995, the disclosure of which are hereby incoφorated by reference: 'A Liquid ink Fault Tolerant (LIFT) printing mechanism' (Filing no. : PN2308); 'Electrothermal drop selection in LIFT printing' (Filing no.: PN2309); 'Drop separation in LIFT printing by print media proximity' (Filing no.: PN2310); 'Drop size adjustment in Proximity LIFT printing by varying head to media distance' (Filing no.: PN2311 ); 'Augmenting Proximity LIFT printing with acoustic ink waves' (Filing no.: PN2312); 'Electrostatic drop separation in LEFT printing' (Filing no.: PN2313); 'Multiple simultaneous drop sizes in Proximity LIFT printing' (Filing no.: PN2321); 'Self cooling operation in thermally activated print heads' (Filing no.: PN2322); and 'Thermal Viscosity Reduction LEFT printing' (Filing no.: PN2323). A simplified schematic diagram of one preferred printing system according to the invention appears in Figure 1 (a). An image source 52 may be raster image data from a scanner or computer, or outline image data in the form of a page description language (PDL), or other forms of digital image representation. This image data is converted to a pixel-mapped page image by the image processing system 53. This may be a raster image processor (RIP) in the case of PDL image data, or may be pixel image manipulation in the case of raster image data. Continuous tone data produced by the image processing unit 53 is halftoned. Halftoning is performed by the Digital Halftoning unit 54. Halftoned bitmap image data is stored in the image memory 72. Depending upon the printer and system configuration, the image memory 72 may be a full page memory, or a band memory. Heater control circuits 71 read data from the image memory 72 and apply time- varying electrical pulses to the nozzle heaters (103 in figure 1(b)) that are part ofthe print head 50. These pulses are applied at an appropriate time, and to the appropriate nozzle, so that selected drops will form spots on the recording medium 51 in the appropriate position designated by the data in the image memory 72. The recording medium 51 is moved relative to the head 50 by a paper transport system 65, which is electronically controlled by a paper transport control system 66, which in turn is controlled by a microcontroller 315. The paper transport system shown in figure 1(a) is schematic only, and many different mechanical configurations are possible. In the case of pagewidth print heads, it is most convenient to move the recording medium 51 past a stationary head 50. However, in the case of scanning print systems, it is usually most convenient to move the head 50 along one axis (the sub-scanning direction) and the recording medium 51 along the orthogonal axis (the main scanning direction), in a relative raster motion. The microcontroller 315 may also control the ink pressure regulator 63 and the heater control circuits 71. For printing using surface tension reduction, ink is contained in an ink reservoir 64 under pressure. In the quiescent state (with no ink drop ejected), the ink pressure is insufficient to overcome the ink surface tension and eject a drop. A constant ink pressure can be achieved by applying pressure to the ink reservoir 64 under the control of an ink pressure regulator 63. Alternatively, for larger printing systems, the ink pressure can be very accurately generated and controlled by situating the top surface of the ink in the reservoir 64 an appropriate distance above the head 50. This ink level can be regulated by a simple float valve (not shown). For printing using viscosity reduction, ink is contained in an ink reservoir 64 under pressure, and the ink pressure is caused to oscillate. The means of producing this oscillation may be a piezoelectric actuator mounted in the ink channels (not shown). When properly arranged with the drop separation means, selected drops proceed to form spots on the recording medium 51 , while unselected drops remain part of the body of ink. The ink is distributed to the back surface of the head 50 by an ink channel device 75. The ink preferably flows through slots and/or holes etched through the silicon substrate of the head 50 to the front surface, where the nozzles and actuators are situated. In the case of thermal selection, the nozzle actuators are electrothermal heaters. In some types of printers according to the invention, an external field 74 is required to ensure that the selected drop separates from the body of the ink and moves towards the recording medium 51. A convenient external field 74 is a constant electric field, as the ink is easily made to be electrically conductive. In this case, the paper guide or platen 67 can be made of electrically conductive material and used as one electrode generating the electric field. The other electrode can be the head 50 itself. Another embodiment uses proximity of he print medium as a means of discriminating between selected drops and unselected drops. For small drop sizes gravitational force on the ink drop is very small; approximately 10" 4 of the surface tension forces, so gravity can be ignored in most cases. This allows the print head 50 and recording medium 51 to be oriented in any direction in relation to the local gravitational field. This is an important requirement for portable printers. Figure 1(b) is a detail enlargement of a cross section of a single microscopic nozzle tip embodiment of the invention, fabricated using a modified CMOS process. The nozzle is etched in a substrate 101 , which may be silicon, glass, metal, or any other suitable material. If substrates which are not semiconductor materials are used, a semiconducting material (such as amorphous sihcon) may be deposited on the substrate, and integrated drive transistors and data distribution circuitry may be formed in the surface semiconducting layer. Single crystal silicon (SCS) substrates have several advantages, including: 1) High performance drive transistors and other circuitry can be fabricated in SCS; 2) Print heads can be fabricated in existing facilities (fabs) using standard VLSI processing equipment; 3) SCS has high mechanical strength and rigidity; and 4) SCS has a high thermal conductivity. In this example, the nozzle is of cylindrical foπn, with the heater 103 forming an annulus. The nozzle tip 104 is formed from sihcon dioxide layers 102 deposited during the fabrication of the CMOS drive circuitry. The nozzle tip is passivated with sihcon nitride. The protruding nozzle tip controls the contact point of the pressurized ink 100 on the print head surface. The print head surface is also hydrophobized to prevent accidental spread of ink across the front of the print head. Many other configurations of nozzles are possible, and nozzle embodiments of the invention may vary in shape, dimensions, and materials used. Monohthic nozzles etched from the substrate upon which the heater and drive electronics are formed have the advantage of not requiring an orifice plate. The elimination of the orifice plate has significant cost savings in manufacture and assembly. Recent methods for eliminating orifice plates include the use of 'vortex' actuators such as those described in Domoto et al US Pat No. 4,580,158, 1986, assigned to Xerox, and Miller et al US Pat No. 5,371,527, 1994 assigned to Hewlett-Packard. These, however are complex to actuate, and difficult to fabricate. The preferred method for elimination of orifice plates for print heads of the invention is incorporation of the orifice into the actuator substrate. This type of nozzle may be used for print heads using various techniques for drop separation. Operation with Electrostatic Drop Separation As a first example, operation using thermal reduction of surface tension and electrostatic drop separation is shown in figure 2. Figure 2 shows the results of energy transport and fluid dynamic simulations performed using FIDAP, a commercial fluid dynamic simulation software package available from Fluid Dynamics Inc., of Illinois, USA. This simulation is of a thermal drop selection nozzle embodiment with a diameter of 8 μm, at an ambient temperature of 30°C. The total energy apphed to the heater is 276 nJ, apphed as 69 pulses of 4 nJ each. The ink pressure is 10 kPa above ambient air pressure, and the ink viscosity at 30°C is 1.84 cPs. The ink is water based, and includes a sol of 0.1% palmitic acid to achieve an enhanced decrease in surface tension with increasing temperature. A cross section of the nozzle tip from the central axis of the nozzle to a radial distance of 40 μm is shown. Heat flow in the various materials of the nozzle, including sihcon, silicon nitride, amoφhous sihcon dioxide, crystalline sihcon dioxide, and water based ink are simulated using the respective densities, heat capacities, and thermal conductivities of the materials. The time step of the simulation is 0.1 μs. Figure 2(a) shows a quiescent state, just before the heater is actuated. An equilibrium is created whereby no ink escapes the nozzle in the quiescent state by ensuring that the ink pressure plus external electrostatic field is insufficient to overcome the surface tension of the ink at the ambient temperature. In the quiescent state, the meniscus of the ink does not protrude significantly from the print head surface, so the electrostatic field is not significantly concentrated at the meniscus. Figure 2(b) shows thermal contours at 5°C intervals 5 μs after the start of the heater energizing pulse. When the heater is energized, the ink in contact with the nozzle tip is rapidly heated. The reduction in surface tension causes the heated portion ofthe meniscus to rapidly expand relative to the cool ink meniscus. This drives a convective flow which rapidly transports this heat over part of the free surface of the ink at the nozzle tip. It is necessary for the heat to be distributed over the ink surface, and not just where the ink is in contact with the heater. This is because viscous drag against the solid heater prevents the ink directiy in contact with the heater from moving. Figure 2(c) shows thermal contours at 5°C intervals 10 μs after the start of the heater energizing pulse. The increase in temperature causes a decrease in surface tension, disturbing the equilibrium of forces. As the entire meniscus has been heated, the ink begins to flow. Figure 2(d) shows thermal contours at 5°C intervals 20 μs after the start of the heater energizing pulse. The ink pressure has caused the ink to flow to a new memscus position, which protrudes from the print head. The electrostatic field becomes concentrated by the protruding conductive ink drop. Figure 2(e) shows thermal contours at 5°C intervals 30 μs after the start of the heater energizing pulse, which is also 6 μs after the end of the heater pulse, as the heater pulse duration is 24 μs. The nozzle tip has rapidly cooled due to conduction through the oxide layers, and conduction into the flowing ink. The nozzle tip is effectively 'water cooled' by the ink. Electrostatic attraction causes the ink drop to begin to accelerate towards the recording medium. Were the heater pulse significantly shorter (less than 16 μs in this case) the ink would not accelerate towards the print medium, but would instead return to the nozzle. Figure 2(f) shows thermal contours at 5°C intervals 26 μs after the end of the heater pulse. The temperature at the nozzle tip is now less than 5°C above ambient temperature. This causes an increase in surface tension around the nozzle tip. When the rate at which the ink is drawn from the nozzle exceeds the viscously limited rate of ink flow through the nozzle, the ink in the region ofthe nozzle tip 'necks', and the selected drop separates from the body of ink. The selected drop then travels to the recording medium under the influence of the external electrostatic field. The meniscus of the ink at the nozzle tip then returns to its quiescent position, ready for the next heat pulse to select the next ink drop. One ink drop is selected, separated and forms a spot on the recording medium for each heat pulse. As the heat pulses are electrically controlled, drop on demand ink jet operation can be achieved. Figure 3(a) shows successive memscus positions during the drop selection cycle at 5 μs intervals, starting at the beginning of the heater energizing pulse. Figure 3(b) is a graph of meniscus position versus time, showing the movement of the point at the centre of the meniscus. The heater pulse starts 10 μs into the simulation. Figure 3(c) shows the resultant curve of temperature with respect to time at various points in the nozzle. The vertical axis of the graph is temperamre, in units of 100°C. The horizontal axis of the graph is time, in units of 10 μs. The temperamre curve shown in figure 3(b) was calculated by FIDAP, using 0.1 μs time steps. The local ambient temperature is 30 degrees C. Temperature histories at three points are shown: A - Nozzle tip: This shows the temperature history at the circle of contact between the passivation layer, the ink, and air. B - Meniscus midpoint: This is at a circle on the ink memscus midway between the nozzle tip and the centre of the meniscus. C - Chip surface: This is at a point on the print head surface 20 μm from the centre of the nozzle. The temperature only rises a few degrees. This indicates that active circuitry can be located very close to the nozzles without experiencing performance or lifetime degradation due to elevated temperatures. Figure 3(e) shows the power apphed to the heater. Optimum operation requires a shaφ rise in temperature at the start of the heater pulse, a maintenance of the temperature a little below the boiling point of the ink for the duration of the pulse, and a rapid fall in temperature at the end of the pulse. To achieve this, the average energy apphed to the heater is varied over the duration of the pulse. In this case, the variation is achieved by pulse frequency modulation of 0.1 μs sub-pulses, each with an energy of 4 nJ. The peak power apphed to the heater is 40 mW, and the average power over the duration of the heater pulse is 11.5 mW. The sub-pulse frequency in this case is 5 Mhz. This can readily be varied without significandy affecting the operation of the print head. A higher sub-pulse frequency allows finer control over the power apphed to die heater. A sub-pulse frequency of 13.5 Mhz is suitable, as this frequency is also suitable for minimizing the effect of radio frequency interference (RFI). Inks with a negative temperature coefficient of surface tension The requirement for the surface tension of the ink to decrease wid increasing temperature is not a major restriction, as most pure hquids and many mixtures have this property. Exact equations relating surface tension to temperature for arbitrary hquids are not available. However, the following empirical equation derived by Ramsay and Shields is satisfactory for many hquids: Where γ-ris the surface tension at temperature T, k is a constant, T c is the critical temperamre ofthe hquid, M is the molar mass of the liquid, x is the degree of association ofthe hquid, and p is the density ofthe hquid. This equation indicates that the surface tension of most hquids falls to zero as the temperamre reaches the critical temperature of the hquid. For most hquids, the critical temperature is substantially above the boiling point at atmospheric pressure, so to achieve an ink with a large change in surface tension with a small change in temperature around a practical ejection temperature, the admixture of surfactants is recommended. The choice of surfactant is important. For example, water based ink for thermal in jet printers often contains isopropyl alcohol (2-propanol) to reduce the surface tension and promote rapid drying. Isopropyl alcohol has a boiling point of 82.4°C, lower than that of water. As the temperamre rises, the alcohol evaporates faster than the water, decreasing the alcohol concentration and causing an increase in surface tension. A surfactant such as 1-Hexanol (b.p. 158°C) can be used to reverse this effect, and achieve a surface tension which decreases shghtiy with temperamre. However, a relatively large decrease in surface tension with temperamre is desirable to maximize operating latitude. A surface tension decrease of 20 mN/m over a 30°C temperature range is preferred to achieve large operating margins, while as httle as lOmN/m can be used to achieve operation of the print head according to die present invention. Ink. With Lar -ά ∑ Several methods may be used to achieve a large negative change in surface tension with increasing temperature. Two such methods are: 1) The ink may contain a low concentration sol of a surfactant which is solid at ambient temperatures, but melts at a threshold temperature. Particle sizes less than 1,000 A are desirable. Suitable surfactant melting points for a water based ink are between 50°C and 90°C, and preferably between 60°C and 80°C. 2) The ink may contain an oil/water microemulsion with a phase inversion temperature (PIT) which is above the maximum ambient temperamre, but below the boiling point of the ink. For stability, the PIT of the microemulsion is preferably 20°C or more above the maximum non-operating temperature encountered by die ink. A PIT of approximately 80°C is suitable. Inks with Surfactant Sols Inks can be prepared as a sol of small particles of a surfactant which melts in the desired operating temperature range. Examples of such surfactants include carboxylic acids witii between 14 and 30 carbon atoms, such as: Name Formula m.p. Synonym Tetradecanoic acid CH 3 (CH 2 )ι 2 COOH 58°C Myristic acid Hexadecanoic acid CH 3 (CH 2 ), 4 COOH 63°C Palmitic acid Octadecanoic acid CH 3 (CH 2 ), 5 COOH 71°C Stearic acid Eicosanoic acid CH 3 (CH 2 ), 6 COOH 77°C Arachidic acid Docosanoic acid CH 3 (CH 2 ) 20 COOH 80°C Behenic acid As the melting point of sols with a small particle size is usually shghtiy less than ofthe bulk material, it is preferable to choose a carboxyhc acid with a melting point shghtiy above the desired drop selection temperamre. A good example is Arachidic acid. These carboxyhc acids are available in high purity and at low cost. The amount of surfactant required is very small, so the cost of adding them to the ink is insignificant A mixmre of carboxyhc acids with shghtiy varying chain lengths can be used to spread the melting points over a range of temperatures. Such mixtures will typically cost less than the pure acid. It is not necessary to restrict the choice of surfactant to simple unbranched carboxyhc acids. Surfactants with branched chains or phenyl groups, or other hydrophobic moieties can be used. It is also not necessary to use a carboxylic acid. Many highly polar moieties are suitable for the hydrophihc end of the surfactant. It is desirable that the polar end be ionizable in water, so that the surface of the surfactant particles can be charged to aid dispersion and prevent flocculation. In the case of carboxylic acids, this can be achieved by adding an alkali such as sodium hydroxide or potassium hydroxide. Preparation of Inks with Surfactant Sols The surfactant sol can be prepared separately at high concentration, and added to the ink in the required concentration. An example process for creating the surfactant sol is as follows: 1) Add the carboxyhc acid to purified water in an oxygen free atmosphere. 2) Heat the mixture to above the melting point of the carboxyhc acid. The water can be brought to a boil. 3) Ultrasonicate the mixttire, until the typical size of the carboxyhc acid droplets is between lOOA and l.OOOA. 4) Allow the mixture to cool. 5) Decant the larger particles from the top of the mixmre. 6) Add an alkali such as NaOH to ionize the carboxylic acid molecules on the surface ofthe particles. A pH of approximately 8 is suitable. This step is not absolutely necessary, but helps stabilize the sol. 7) Centrifuge the sol. As the density of the carboxyhc acid is lower than water, smaller particles will accumulate at the outside of the centrifuge, and larger particles in the centre. 8) Filter the sol using a microporous filter to eliminate any particles above 5000 A. 9) Add the surfactant sol to the ink preparation. The sol is required only in very dilute concentration. The ink preparation will also contain either dye(s) or pigment(s), bactericidal agents, agents to enhance the electrical conductivity of the ink if electrostatic drop separation is used, humectants, and other agents as required. Anti-foaming agents will generally not be required, as there is no bubble formation during the drop ejection process. Cationic surfactant sols Inks made with anionic surfactant sols are generally unsuitable for use with cationic dyes or pigments. This is because the cationic dye or pigment may precipitate or flocculate with the anionic surfactant. To allow the use of cationic dyes and pigments, a cationic surfactant sol is required. The family of alkylamines is suitable for this p pose. Various suitable alkylamines are shown in the following table: Name Formula Synonym Hexadecylamine CH_(CH 2 ) 14 CH 2 NH 2 Palmityl amine Octadecylamine CH 3 (CH 2 ) 16 CH 2 NH 2 Stβaryl amine Eicosylamine CH 3 (CH 2 ) 18 CH 2 NH 2 Arachidyl amine Docosylamine CH 3 (CH 2 ) 20 CH 2 NH 2 Behβnyl amine The method of preparation of cationic surfactant sols is essentially similar to that of anionic surfactant sols, except that an acid instead of an alkali is used to adjust the pH balance and increase the charge on the surfactant particles. A pH of 6 using HCI is suitable. Microemulsion Based Inks An alternative means of achieving a large reduction in surface tension as some temperature threshold is to base the ink on a microemulsion. A microemulsion is chosen with a phase inversion temperature (PIT) around the desired ejection threshold temperature. Below the PIT, the microemulsion is oil in water (O W), and above the PIT the microemulsion is water in oil (W/O). At low temperatures, the surfactant forming the microemulsion prefers a high curvature surface around oil, and at temperamres significandy above the PIT, the surfactant prefers a high curvature surface around water. At temperatures close to the PIT, the microemulsion forms a continuous 'sponge' of topologically connected water and oil. There are two mechanisms whereby this reduces the surface tension. Around the PIT, the surfactant prefers surfaces with very low curvature. As a result, surfactant molecules migrate to the ink/air interface, which has a curvature which is much less than the curvature of the oil emulsion. This lowers the surface tension of the water. Above the phase inversion temperature, the microemulsion changes from O/W to W/O, and therefore the ink/air interface changes from water/air to oil/air. The oil/air interface has a lower surface tension. There is a wide range of possibilities for the preparation of microemulsion based inks. For fast drop ejection, it is preferable to chose a low viscosity oil. In many instances, water is a suitable polar solvent. However, in some cases different polar solvents may be required. In these cases, polar solvents with a high surface tension should be chosen, so that a large decrease in surface tension is achievable. The surfactant can be chosen to result in a phase inversion temperamre in the desired range. For example, surfactants of the group poly(oxyethylene)a_kylphenyl ether (ethoxylated alkyl phenols, general formula: can be used. The hydrophilicity of the surfactant can be increased by increasing m, and the hydrophobicity can be increased by increasing n. Values of m of approximately 10, and n of approximately 8 are suitable. Low cost commercial preparations are the result of a polymerization of various molar ratios of ethylene oxide and alkyl phenols, and the exact number of oxyethylene groups varies around the chosen mean. These commercial preparations are adequate, and highly pure surfactants with a specific number of oxyethylene groups are not required. The formula for this surfactant is C_Hι 7 C 4 H_(CH 2 CH 2 O)_OH (average n=10). Synonyms include Octoxynol-10, PEG- 10 octyl phenyl ether and POE (10) octyl phenyl ether The HLB is 13.6, the melting point is 7°C, and the cloud point is 65°C. Commercial preparations of this surfactant are available under various brand names. Supphers and brand names are listed in the following table: Trade name Supplier Akyporox OP100 Chem-Y GmbH Alkasurf OP-10 Rhone-Poulenc Surfactants and Specialties Dehydrophen POP 10 Pulcra SA Hyonic OP-10 Henkel Coφ. Iconol OP- 10 BASF Coφ. Igepal O Rhone-Poulenc France Macol OP- 10 PPG Industries Maloφhen 810 Huls AG Nikkol OP-10 Nikko Chem. Co. Ltd. Renex 750 ICI Americas Inc. Rexol 45/10 Hart Chemical Ltd. Synperonic OP10 ICI PLC Teric XlO ICI Australia These are available in large volumes at low cost (less than one dollar per pound in quantity), and so contribute less than 10 cents per liter to prepared microemulsion ink with a 5% surfactant concentration. Other suitable ethoxylated alkyl phenols include those listed in the following table: Trivial name Formula HLB Cloud point Nonoxynol-9 C 9 H, 9 C 4 H 6 (CH 2 CH 2 O)_ 9 OH 13 54°C Nonoxynol-10 ■ C 9 H„C 4 H <i (CH 2 CH 2 O)-,oOH 13.2 62°C Nonoxynol-11 C 9 H,.C 4 H.(CH 2 CH 2 O)-„OH 13.8 72°C Nonoxynol-12 C 9 Hi 9 C 4 H.(CH 2 CH 2 O)-,_OH 14.5 81°C Octoxynol-9 CgH l7 C 4 H 6 (CH 2 CH 2 O)- 9 θH 12.1 61°C Octoxynol-10 C_H 17 C 4 H_(CH 2 CH 2 O)_.oOH 13.6 65°C Octoxynol-12 C . H 17 C 4 H_(CH 2 CH 2 O)-,_OH 14.6 88°C Dodoxynol-10 CnHzsCΛ^HzCHzO-.oOH 12.6 42°C Dodoxynol-11 C, 2 H 2 5C H 6 (CH 2 CH 2 O)_„OH 13.5 56°C Dodoxynol-14 14.5 87°C Microemulsion based inks have advantages other than surface tension control: 1) Microemulsions are therm odynamically stable, and will not separate. Therefore, the storage time can be very long. This is especially significant for office and portable printers, which may be used sporadically. 2) The microemulsion will form spontaneously with a particular drop size, and does not require extensive stirring, centrifuging, or filtering to ensure a particular range of emulsified oil drop sizes. 3) The amount of oil contained in the ink can be quite high, so dyes which are soluble in oil or soluble in water, or both, can be used. It is also possible to use a mixmre of dyes, one soluble in water, and the other soluble in oil, to obtain specific colors. 4) Oil miscible pigments are prevented from flocculating, as they are trapped in the oil microdroplets. 5) The use of a microemulsion can reduce the mixing of different dye colors on the surface of the print medium. 6) The viscosity of microemulsions is very low. 7) The requirement for humectants can be reduced or eliminated. Dves and pigments in microemulsion based inks Oil in water mixtures can have high oil contents - as high as 40% - and still form O/W microemulsions. This allows a high dye or pigment loading. Mixtures of dyes and pigments can be used. An example of a microemulsion based ink mixture with both dye and pigment is as follows: 1) water 2) water soluble dye 3) surfactant 4) oil 5) oil miscible pigment The following table shows the nine basic combinations of colorants in the oil and water phases of the microemulsion that may be used. Combination Colorant in water phase Colorant in oil phase 1 none oil miscible pigment 2 none oil soluble dye 3 water soluble dye none 4 water soluble dye oil miscible pigment 5 water soluble dye oil soluble dye 6 pigment dispersed in water none 7 pigment dispersed in water oil miscible pigment 8 pigment dispersed in water oil soluble dye 9 none none The ninth combination, with no colorants, is useful for printing transparent coatings, UV ink, and selective gloss highlights. As many dyes are amphiphilic, large quantities of dyes can also be solubilized in the oil-water boundary layer as this layer has a very large surface area It is also possible to have multiple dyes or pigments in each phase, and to have a mixture of dyes and pigments in each phase. When using multiple dyes or pigments the absoφtion spectrum of the resultant ink will be the weighted average of the absoφtion spectra of the different colorants used. This presents two problems: 1) The absoφtion spectrum will tend to become broader, as the absoφtion peaks of both colorants are averaged. This has a tendency to 'muddy' the colors. To obtain brilliant color, careful choice of dyes and pigments based on their absoφtion spectra, not just their human-perceptible color, needs to be made. 2) The color of the ink may be different on different substrates. If a dye and a pigment are used in combination, the color of the dye will tend to have a smaller contribution to the printed ink color on more absoφtive papers, as the dye will be absorbed into the paper, while the pigment will tend to 'sit on top' of the paper. This may be used as an advantage in some circumstances. Surfactants with a Krafft point in the drop selection temperamre range For ionic surfactants there is a temperature (the Krafft point) below which the solubihty is quite low, and the solution contains essentially no micelles. Above the Krafft temperature micelle formation becomes possible and there is a rapid increase in solubihty of the surfactant If the critical micelle concentration (CMC) exceeds the solubility of a surfactant at a particular temperature, then the minimum surface tension will be achieved at the point of maximum solubihty, rather than at the CMC. Surfactants are usually much less effective below the Krafft point. This factor can be used to achieve an increased reduction in surface tension witii increasing temperamre. At ambient temperamres, only a portion of the surfactant is in solution. When the nozzle heater is turned on, the temperamre rises, and more of the surfactant goes into solution, decreasing the surface tension. A surfactant should be chosen with a Krafft point which is near the top of the range of temperatures to which the ink is raised. This gives a maximum margin between the concentration of surfactant in solution at ambient temperamres, and the concentration of surfactant in solution at the drop selection temperature. The concentration of surfactant should be approximately equal to the CMC at the Krafft point In this manner, the surface tension is reduced to the maximum amount at elevated temperamres, and is reduced to a minimum amount at ambient temperamres. The following table shows some commercially available surfactants with Krafft points in the desired range. Surfactants with a cloud point in the drop selection temperature range Non-ionic surfactants using polyoxyethylene (POE) chains can be used to create an ink where the surface tension falls with increasing temperature. At low temperatures, the POE chain is hydrophihc, and maintains the surfactant in solution. As the temperamre increases, the structured water around the POE section of the molecule is disrupted, and the POE section becomes hydrophobic. The surfactant is increasingly rejected by the water at higher temperatures, resulting in increasing concentration of surfactant at the air/ink interface, thereby lowering surface tension. The temperature at which the POE section of a nonionic surfactant becomes hydrophihc is related to the cloud point of that surfactant POE chains by themselves are not particularly suitable, as the cloud point is generally above 100°C Polyoxypropylene (POP) can be combined with POE in POE POP block copolymers to lower the cloud point of POE chains without introducing a strong hydrophobicity at low temperatures. Two main configurations of symmetrical POE/POP block copolymers are available. These are: 1 ) Surfactants with POE segments at the ends of the molecules, and a POP segment in the centre, such as the poloxamer class of surfactants (generically CAS 9003- 11 -6) 2) Surfactants with POP segments at the ends of the molecules, and a POE segment in the centre, such as the meroxapol class of surfactants (generically also CAS 9003-11-6) Some commercially available varieties of poloxamer and meroxapol with a high surface tension at room temperature, combined with a cloud point above 40°C and below 100°C are shown in the following table: Otl ler varieties of p ( .loxamer and meroxapol cai a readily be synthesized using well known techniques. Desirable characteristics are a room temperature surface tension which is as high as possible, and a cloud point between 40°C and 100°C, and preferably between 60°C and 80°C. Meroxapol [HO(CHCH3CH 2 O) x (CH 2 CH 2 O) y (CHCH 3 CH 2 O) z OH] varieties where the average x and z are approximately 4, and the average y is approximately 15 may be suitable. If salts are used to increase the electrical conductivity of the ink, then the effect of this salt on the cloud point of the surfactant should be considered. The cloud point of POE surfactants is increased by ions that disrupt water structure (such as I " ), as this makes more water molecules available to form hydrogen bonds with the POE oxygen lone pairs. The cloud point of POE surfactants is decreased by ions that form water structure (such as CI " , OH " ), as fewer water molecules are available to form hydrogen bonds. Bromide ions have relatively little effect The ink composition can be 'tuned' for a desired temperamre range by altering the lengths of POE and POP chains in a block copolymer surfactant, and by changing the choice of salts (e.g CI " to Br " to I ) that are added to increase electrical conductivity. NaCl is likely to be the best choice of salts to increase ink conductivity, due to low cost and non-toxicity. NaCl shghtiy lowers the cloud point of nonionic surfactants. Hot Melt Inks The ink need not be in a hquid state at room temperature. Sohd 'hot melt' inks can be used by heating the printing head and ink reservoir above the melting point of the ink. The hot melt ink must be formulated so that the surface tension of the molten ink decreases with temperamre. A decrease of approximately 2 mN/m will be typical of many such preparations using waxes and other substances. However, a reduction in surface tension of approximately 20 mN/m is desirable in order to achieve good operating margins when relying on a reduction in surface tension rather than a reduction in viscosity. The temperature difference between quiescent temperamre and drop selection temperature may be greater for a hot melt ink than for a water based ink, as water based inks are constrained by the boiling point of the water. The ink must be liquid at the quiescent temperature. The quiescent temperature should be higher than the highest ambient temperature likely to be encountered by the printed page. T he quiescent temperamre should also be as low as practical, to reduce the power needed to heat the print head, and to provide a maximum margin between the quiescent and the drop ejection temperamres. A quiescent temperamre between 60°C and 90°C is generally suitable, though other temperatures may be used. A drop ejection temperature of between 160°C and 200°C is generally suitable. -32- There are several methods of achieving an enhanced reduction in surface tension with increasing temperature. 1 ) A dispersion of microfine particles of a surfactant with a melting point substantially above the quiescent temperature, but substantially below the drop ejection temperamre, can be added to the hot melt ink while in the hquid phase. 2) A polar/non-polar microemulsion with a PIT which is preferably at least 20°C above the melting points of both the polar and non-polar compounds. To achieve a large reduction in surface tension with temperamre, it is desirable that the hot melt ink carrier have a relatively large surface tension (above 30 mN/m) when at the quiescent temperamre. This generally excludes alkanes such as waxes. Suitable materials will generally have a strong intermolecular attraction, which may be achieved by multiple hydrogen bonds, for example, polyols, such as Hexanetetrol, which has a melting point of 88°C. Surface tension reduction of various solutions Figure 3(d) shows the measured effect of temperature on the surface tension of various aqueous preparations containing the following additives: 1) sol of Stearic Acid 2) sol of Palmitic acid 3) solution of Pluronic 10R5 (trade mark of BASF) 4) solution of Pluronic L35 (trade mark of BASF) 5) solution of Pluronic L44 (trade mark of BASF) Inks suitable for printing systems of the present invention are described in the following Austrahan patent specifications, the disclosure of which are hereby incoφorated by reference: 'Ink composition based on a microemulsion' (Filing no.: PN5223, filed on 6 September 1995); 'Ink composition containing surfactant sol' (Filing no.: PN5224, filed on 6 September 1995); 'Ink composition for DOD printers with Krafft point near the drop selection temperature sol' (Filing no.: PN6240, filed on 30 October 1995); and 'Dye and pigment in a microemulsion based ink' (Filing no.: PN6241, filed on 30 October 1995). Operation Using Reduction of Viscosity As a second example, operation of an embodiment using thermal reduction of viscosity and proximity drop separation, in combination with hot melt ink, is as follows. Prior to operation of the printer, sohd ink is melted in the reservoir 64. The reservoir, ink passage to the print head, ink channels 75, and print head 50 are maintained at a temperamre at which the ink 100 is hquid, but exhibits a relatively high viscosity (for example, approximately 100 cP). The Ink 100 is retained in the nozzle by the surface tension of the ink. The ink 100 is formulated so that the viscosity of the ink reduces with increasing temperamre. The ink pressure oscillates at a frequency which is an integral multiple of the drop ejection frequency from the nozzle. The ink pressure oscillation causes oscillations of the ink meniscus at the nozzle tips, but this oscillation is small due to the high ink viscosity. At the normal operating temperamre, these oscillations are of insufficient amphtude to result in drop separation. When the heater 103 is energized, the ink forming the selected drop is heated, causing a reduction in viscosity to a value which is preferably less than 5 cP. The reduced viscosity results in the ink meniscus moving further during the high pressure part of the ink pressure cycle. The recording medium 51 is arranged sufficiently close to the print head 50 so that the selected drops contact the recording medium 51, but sufficiendy far away that the unselected drops do not contact the recording medium 51. Upon contact with the recording medium 51, part of the selected drop freezes, and attaches to the recording medium. As the ink pressure falls, ink begins to move back into the nozzle. The body of ink separates from the ink which is frozen onto the recording medium. The memscus of the ink 100 at the nozzle tip then returns to low amphtude oscillation. The viscosity of the ink increases to its quiescent level as remaining heat is dissipated to the bulk ink and print head. One ink drop is selected, separated and forms a spot on the recording medium 51 for each heat pulse. As the heat pulses are electrically controlled, drop on demand ink jet operation can be achieved. Manufacturing of Print Heads Manufacturing processes for monohthic print heads in accordance with the present invention are described in the following Austrahan patent specifications filed on 12 April 1995, the disclosure of which are hereby incoφorated by reference: 'A monohthic LIFT printing head' (Filing no.: PN2301); 'A manufacturing process for monohthic LIFT printing heads' (Filing no.: PN2302); 'A self-aligned heater design for LIFT print heads' (Filing no.: PN2303); 'Integrated four color LIFT print heads' (Fihng no.: PN2304); 'Power requirement reduction in monohthic LIFT printing heads' (Filing no.: PN2305); ' A manufacturing process for monohthic LEFT print heads using anisotropic wet etching' (Filing no.: PN2306); 'Nozzle placement in monohthic drop-on-demand print heads' (Filing no.: PN2307); 'Heater structure for monohthic LIFT print heads' (Fihng no.: PN2346); 'Power supply connection for monohthic LIFT print heads' (Filing no.: PN2347); 'External connections for Proximity LIFT print heads' (Filing no.: PN2348); and 'A self-aligned manufacturing process for monohthic LIFT print heads' (Filing no.: PN2349); and 'CMOS process compatible fabrication of LIFT print heads' (Filing no.: PN5222, 6 September 1995). 'A manufacturing process for LIFT print heads with nozzle rim heaters' (Filing no.: PN6238, 30 October 1995); Α modular LIFT print head' (Filing no.: PN6237, 30 October 1995); 'Method of increasing packing density of printing nozzles' (Filing no.: PN6236, 30 October 1995); and 'Nozzle dispersion for reduced electrostatic interaction between simultaneously printed droplets' (Filing no.: PN6239, 30 October 1995). Control of Print Heads Means of providing page image data and controlling heater temperamre in print heads of the present invention is described in the following Australian patent specifications filed on 12 April 1995, the disclosure of which are hereby incoφorated by reference: 'Integrated drive circuitry in LIFT print heads' (Filing no.: PN2295); 'A nozzle clearing procedure for Liquid Ink Fault Tolerant (LIFT) printing' (Filing no.: PN2294); 'Heater power compensation for temperamre in LIFT printing systems' (Filing no.: PN2314); 'Heater power compensation for thermal lag in LIFT printing systems' (Filing no.: PN2315); 'Heater power compensation for print density in LIFT printing systems' (Filing no.: PN2316); 'Accurate control of temperamre pulses in printing heads' (Filing no.: PN2317); 'Data distribution in monohthic LIFT print heads' (Filing no.: PN2318); 'Page image and fault tolerance routing device for LIFT printing systems' (Filing no.: PN2319); and 'A removable pressurized hquid ink cartridge for LIFT printers' (Filing no.: PN2320). Image Processing for Print Heads An objective of printing systems according to the invention is to attain a print quahty which is equal to that which people are accustomed to in quahty color pubhcations printed using offset printing. This can be achieved using a print resolution of approximately 1 ,600 dpi. However, 1 ,600 dpi printing is difficult and expensive to achieve. Similar results can be achieved using 800 dpi printing, with 2 bits per pixel for cyan and magenta, and one bit per pixel for yellow and black. This color model is herein called CC'MM'YK. Where high quahty monochrome image printing is also required, two bits per pixel can also be used for black. This color model is herein called CC'MM'YKK' . Color models, halftoning, data compression, and real-time expansion systems suitable for use in systems of this invention and other printing systems are described in the following Austrahan patent specifications filed on 12 April 1995, the disclosure of which are hereby incoφorated by reference: 'Four level ink set for bi-level color printing' (Filing no.: PN2339); 'Compression system for page images' (Fihng no.: PN2340); 'Real-time expansion apparatus for compressed page images' (Filing no.: PN2341); and 'High capacity compressed document image storage for digital color printers' (Filing no.: PN2342); 'Improving JPEG compression in the presence of text' (Fihng no.: PN2343); 'An expansion and halftoning device for compressed page images' (Filing no.: PN2344); and 'Improvements in image halftoning' (Filing no.: PN2345). Applications Using Print Heads According to this Invention Printing apparatus and methods of this invention are suitable for a wide range of applications, including (but not limited to) the following: color and monochrome office printing, short run digital printing, high speed digital printing, process color printing, spot color printing, offset press supplemental printing, low cost printers using scanning print heads, high speed printers using pagewidth print heads, portable color and monochrome printers, color and monochrome copiers, color and monochrome facsimile machines, combined printer, facsimile and copying machines, label printing, large format plotters, photographic duphcation, printers for digital photographic processing, portable printers incoφorated into digital 'instant' cameras, video printing, printing of PhotoCD images, portable printers for 'Personal Digital Assistants', wallpaper printing, indoor sign printing, billboard printing, and fabric printing. Printing systems based on this invention are described in the following Austrahan patent specifications filed on 12 April 1995, the disclosure _f which are hereby incoφorated by reference: 'A high speed color office printer with a high capacity digital page image store' (Filing no.: PN2329); 'A short run digital color printer with a high capacity digital page image store' (Filing no. : PN2330); 'A digital color printing press using LIFT printing technology' (Filing no.: PN2331); 'A modular digital printing press' (Filing no.: PN2332); 'A high speed digital fabric printer' (Fihng no.: PN2333); 'A color photograph copying system' (Filing no.: PN2334); 'A high speed color photocopier using a LIFT printing system' (Filing no.: PN2335); 'A portable color photocopier using LIFT printing technology' (Filing no.: PN2336); 'A photograph processing system using LIFT printing technology' (Filing no.: PN2337); 'A plain paper facsimile machine using a LIFT printing system' (Filing no.: PN2338); 'A PhotoCD system with integrated printer' (Filing no.: PN2293); 'A color plotter using LIFT printing technology' (Filing no.: PN2291); 'A notebook computer with integrated LIFT color printing system' (Filing no.: PN2292); 4 A portable printer using a LIFT printing system' (Filing no.: PN2300); 'Fax machine with on-line database interrogation and customized magazine printing' (Filing no.: PN2299); 'Miniature portable color printer' (Filing no.: PN2298); 'A color video printer using a LIFT printing system' (Filing no.: PN2296); and 'An integrated printer, copier, scanner, and facsimile using a LIFT printing system' (Filing no.: PN2297) Compensation of Print Heads for Environmental Conditions It is desirable that drop on demand printing systems have consistent and predictable ink drop size and position. Unwanted variation in ink drop size and position causes variations in the optical density of the resultant print, reducing the perceived print quahty. These variations should be kept to a small proportion of the nominal ink drop volume and pixel spacing respectively. Many environmental variables can be compensated to reduce their effect to insignificant levels. Active compensation of some factors can be achieved by varying the power applied to the nozzle heaters. An optimum temperamre profile for one print head embodiment involves an instantaneous raising of the active region of the nozzle tip to the ejection temperamre, maintenance of this region at the ejection temperamre for the duration of the pulse, and instantaneous cooling of the region to the ambient temperature. This optimum is not achievable due to the stored heat capacities and thermal conductivities of the various materials used in the fabrication ofthe nozzles in accordance with the invention. However, improved performance can be achieved by shaping the power pulse using curves which can be derived by iterative refinement of finite element simulation of the print head. The power apphed to the heater can be varied in time by various techniques, including, but not limited to: 1 ) Varying the voltage apphed to the heater 2) Modulating the width of a series of short pulses (PWM) 3) Modulating the frequency of a series of short pulses (PFM) To obtain accurate results, a transient fluid dynamic simulation with free surface modeling is required, as convection in the ink, and ink flow, significantly affect the temperamre achieved with a specific power curve. By the incoφoration of appropriate digital circuitry on the print head substrate, it is practical to individually control the power apphed to each nozzle. One way to achieve this is by 'broadcasting' a variety of different digital pulse trains across the print head chip, and selecting the appropriate pulse train for each nozzle using multiplexing circuits. An example of the environmental factors which may be compensated for is hsted in the table "Compensation for environmental factors". This table identifies which environmental factors are best compensated globally (for the entire print head), per chip (for each chip in a composite multi-chip print head), and per nozzle. Compensation for environmental factors Factor Scope Sensing or user Compensation compensated control method mechanism Ambient Global Temperature sensor Power supply voltage Temperature mounted on print head or global PFM patterns Power supply Global Predictive active Power supply voltage voltage fluctuation nozzle count based on or global PFM patterns with number of print data active nozzles Local heat build-up Per Predictive active Selection of appropriate with successive nozzle nozzle count based on PFM pattem for each nozzle actuation print data printed drop Drop size control Per Image data Selection of appropriate for multiple bits nozzle PFM pattern for each per pixel printed drop Nozzle geometry Per Factory measurement, Global PFM patterns variations between chip datafile supplied with per print head chip wafers print head Heater resistivity Per Factory measurement, Global PFM patterns variations between chip datafile supphed with per print head chip wafers print head User image Global User selection Power supply voltage, intensity electrostatic adjustment acceleration voltage, or ink pressure Ink surface tension Global Ink cartridge sensor or Global PFM patterns reduction method user selection and threshold temperamre Ink viscosity Global Ink cartridge sensor or Global PFM patterns user selection and/or clock rate Ink dye or pigment Global Ink cartridge sensor or Global PFM patterns concentration user selection Ink response time Global Ink cartridge sensor or Global PFM patterns user selection Most applications will not require compensation for all of these variables. Some variables have a minor effect and compensation is only necessary where very high image quahty is required. Print head drive circuits Figure 4 is a block schematic diagram showing electronic operation of an example head driver circuit in accordance with this invention. This control circuit uses analog modulation ofthe power supply voltage apphed to the print head to achieve heater power modulation, and does not have individual control of the power apphed to each nozzle. Figure 4 shows a block diagram for a system using an 800 dpi pagewidth print head which prints process color using the CC'MM'YK color model. The print head 50 has a total of 79,488 nozzles, with 39,744 main nozzles and 39,744 redundant nozzles. The main and redundant nozzles are divided into six colors, and each color is divided into 8 drive phases. Each drive phase has a shift register which converts the serial data from a head control ASIC 400 into parallel data for enabling heater drive circuits. There is a total of 96 shift registers, each providing data for 828 nozzles. Each shift register is composed of 828 shift register stages 217, the outputs of which are logically anded with phase enable signal by a nand gate 215. The output of the nand gate 215 drives an inverting buffer 216, which in mm controls the drive transistor 201. The drive transistor 201 actuates the electrothermal heater 200, which may be a heater 103 as shown in figure 1(b). To maintain the shifted data valid during the enable pulse, the clock to the shift register is stopped the enable pulse is active by a clock stopper 218, which is shown as a single gate for clarity, but is preferably any of a range of well known glitch free clock control circuits. Stopping the clock of the shift register removes the requirement for a parallel data latch in the print head, but adds some complexity to the control circuits in the Head Control ASIC 400. Data is routed to either the main nozzles or the redundant nozzles by the data router 219 depending on the state of the appropriate signal of the fault status bus. The print head shown in figure 4 is simplified, and does not show various means of improving manufacturing yield, such as block fault tolerance. Drive circuits for different configurations of print head can readily be derived from the apparatus disclosed herein. Digital information representing patterns of dots to be printed on the recording medium is stored in the Page or Band memory 1513, which may be the same as the Image memory 72 in figure 1(a). Data in 32 bit words representing dots of one color is read from the Page or Band memory 1513 using addresses selected by the address mux 417 and control signals generated by the Memory Interface 418. These addresses are generated by Address generators 411, which forms part of the 'Per color circuits' 410, for which there is one for each of the six color components. The addresses are generated based on the positions of the nozzles in relation to the print medium. As the relative position of the nozzles may be different for different print heads, d e Address generators 411 are preferably made programmable. The Address generators 411 normally generate the address corresponding to the position of the main nozzles. However, when faulty nozzles are present, locations of blocks of nozzles containing faults can be marked in the Fault Map RAM 412. The Fault Map RAM 412 is read as the page is printed. If the memory indicates a fault in the block of nozzles, the address is altered so that the Address generators 411 generate the address corresponding to the position of the redundant nozzles. Data read from the Page or Band memory 1513 is latched by the latch 413 and converted to four sequential bytes by the multiplexer 414. Timing of these bytes is adjusted to match that of data representing other colors by the FIFO 415. This data is then buffered by the buffer 430 to form the 48 bit main data bus to the print head 50. The data is buffered as the print head may be located a relatively long distance from die head control ASIC. Data from the Fault Map RAM 412 also forms the input to the FIFO 416. The timing of this data is matched to the data ouφut of the FIFO 415, and buffered by the buffer 431 to form the fault status bus. The programmable power supply 320 provides power for the head 50. The voltage of the power supply 320 is controlled by the DAC 313, which is part of a RAM and DAC combination (RAMDAC) 316. The RAMDAC 316 contains a dual port RAM 317. The contents of the dual port RAM 317 are programmed by the Microcontroller 315. Temperamre is compensated by changing the contents of the dual port RAM 317. These values are calculated by the microcontroller 315 based on temperature sensed by a thermal sensor 300. The thermal sensor 300 signal connects to the Analog to Digital Converter (ADC) 311. The ADC 311 is preferably incoφorated in the Microcontroller 315. The Head Control ASIC 400 contains control circuits for thermal lag compensation and print density. Thermal lag compensation requires that the power supply voltage to the head 50 is a rapidly time-varying voltage which is synchronized with the enable pulse for the heater. This is achieved by programming the programmable power supply 320 to produce this voltage. An analog time varying programming voltage is produced by the DAC 313 based upon data read from the dual port RAM 317. The data is read according to an address produced by the counter 403. The counter 403 produces one complete cycle of addresses during the period of one enable pulse. This synchronization is ensured, as the counter 403 is clocked by the system clock 408, and the top count of the counter 403 is used to clock the enable counter 404. The count from the enable counter 404 is then decoded by the decoder 405 and buffered by the buffer 432 to produce the enable pulses for the head 50. The counter 403 may include a prescaler if the number of states in the count is less than the number of clock periods in one enable pulse. Sixteen voltage states are adequate to accurately compensate for the heater thermal lag. These sixteen states can be specified by using a four bit connection between the counter 403 and the dual port RAM 317. However, these sixteen states may not be linearly spaced in time. To allow non-linear timing of these states the counter 403 may also include a ROM or other device which causes the counter 403 to count in a non-linear fashion. Alternatively, fewer than sixteen states may be used. For print density compensation, the printing density is detected by counting the number of pixels to which a drop is to be printed ('on' pixels) in each enable period. The 'on' pixels are counted by the On pixel counters 402. There is one On pixel counter 402 for each ofthe eight enable phases. The number of enable phases in a print head in accordance with the invention depend upon the specific design. Four, eight, and sixteen are convenient numbers, though there is no requirement that the number of enable phases is a power of two. The On Pixel Counters 402 can be composed of combinatorial logic pixel counters 420 which determine how many bits in a nibble of data are on. This number is then accumulated by the adder 421 and accumulator 422. A latch 423 holds the accumulated value valid for the duration of the enable pulse. The multiplexer 401 selects the ouφut of the latch 423 which corresponds to the current enable phase, as determined by the enable counter 404. The output of the multiplexer 401 forms part of the address of the dual port RAM 317. An exact count of the number of 'on' pixels is not necessary, and the most significant four bits of this count are adequate. Combining the four bits of thermal lag compensation address and the four bits of print density compensation address means that the dual port RAM 317 has an 8 bit address. This means that the dual port RAM 317 contains 256 numbers, which are in a two dimensional array. These two dimensions are time (for thermal lag compensation) and print density. A third dimension - temperature - can be included. As the ambient temperamre of the head varies only slowly, the microcontroller 315 has sufficient time to calculate a matrix of 256 numbers compensating for thermal lag and print density at the current temperature. Periodically (for example, a few times a second), the microcontroller senses the current head temperature and calculates this matrix. The clock to the print head 50 is generated from the system clock 408 by the Head clock generator 407, and buffered by the buffer 406. To facilitate testing of the Head control ASIC, JTAG test circuits 499 may be included. Comparison with thermal ink iet technology The table "Comparison between Thermal inkjet and Present Invention" compares the aspects of printing in accordance with the present invention with thermal inkjet printing technology. A direct comparison is made between the present invention and thermal inkjet technology because both are drop on demand systems which operate using thermal actuators and hquid ink. Although they may appear similar, the two technologies operate on different principles. Thermal ink jet printers use the following fundamental operating principle. A thermal impulse caused by electrical resistance heating results in the explosive formation of a bubble in hquid ink. Rapid and consistent bubble formation can be achieved by superheating the ink, so that sufficient heat is transferred to the ink before bubble nucleation is complete. For water based ink, ink temperatures of approximately 280°C to 400°C are required. The bubble formation causes a pressure wave which forces a drop of ink from the aperture with high velocity. The bubble then collapses, drawing ink from the ink reservoir to re-fill the nozzle. Thermal ink jet printing has been highly successful commercially due to the high nozzle packing density and the use of well established integrated circuit manufacturing techniques. However, thermal ink jet printing technology faces significant technical problems including multi-part precision fabrication, device yield, image resolution, 'pepper' noise, printing speed, drive transistor power, waste power dissipation, satellite drop formation, thermal stress, differential thermal expansion, kogation, cavitation, rectified diffusion, and difficulties in ink formulation. Printing in accordance with the present invention has many ofthe advantages of thermal inkjet printing, and completely or substantially eliminates many of the inherent problems of thermal ink jet technology. Comparison between Thermal inkjet and Present Invention Self-cooling No (high energy required) Yes: printed ink carries operation away drop selection energy Drop ejection High (approx. 10 m/sec) Low (approx. 1 m sec ) velocity Crosstalk Serious problem requiring Low velocities and pressures careful acoustic design, associated with drop which limits nozzle refill ejection make crosstalk very rate. small. Operating thermal Serious problem hmiting Low: maximum temperamre stress print-head life. increase approx. 90°C at centre of heater. Manufacturing Serious problem hmiting Same as standard CMOS thermal stress print-head size. manufacturing process. Drop selection Approx. 20 μJ Approx. 270 nJ energy Heater pulse period Approx. 2-3 μs Approx. 15-30 μs Average heater Approx. 8 Watts per Approx. 12 mW per heater. pulse power heater. This is more than 500 times less than Thermal Ink- Jet. Heater pulse Typically approx. 40V. Approx. 5 to 10V. voltage Heater peak pulse Typically approx. 200 mA Approx. 4 mA per heater. current per heater. This requires This allows the use of small bipolar or very large MOS MOS drive transistors. drive transistors. Fault tolerance Not implemented. Not Simple implementation practical for edge shooter results in better yield and type. reliability Constraints on ink Many constraints including Temperamre coefficient of composition kogation, nucleation, etc. surface tension or viscosity must be negative. Ink pressure Atmospheric pressure or Approx. 1.1 atm less Integrated drive Bipolar circuitry usually CMOS, nMOS, or bipolar circuitry required due to high drive current Differential thermal Significant problem for Monohthic construction expansion large print heads reduces problem Pagewidth print Major problems with yield, High yield, low cost and heads cost precision long life due to fault construction, head life, and tolerance. Self cooling due power dissipation to low power dissipation. Yield and Fault Tolerance In most cases, monohthic integrated circuits cannot be repaired if they are not completely functional when manufactured. The percentage of operational devices which are produced from a wafer run is known as the yield. Yield has a direct influence on manufacmring cost A device with a yield of 5% is effectively ten times more expensive to manufacture than an identical device with a yield of 50%. There are three major yield measurements: 1) Fab yield 2) Wafer sort yield 3) Final test yield For large die, it is typically the wafer sort yield which is the most serious hmitation on total yield. Full pagewidth color heads in accordance with this invention are very large in comparison with typical VLSI circuits. Good wafer sort yield is critical to the cost-effective manufacture of such heads. Figure 5 is a graph of wafer sort yield versus defect density for a monohthic full width color A4 head embodiment of the invention. The head is 215 mm long by 5 mm wide. The non fault tolerant yield 198 is calculated according to Muφhy's method, which is a widely used yield prediction method. With a defect density of one defect per square cm, Muφhy's method predicts a yield less than 1 %. This means that more than 99% of heads fabricated would have to be discarded. This low yield is highly undesirable, as the print head manufacmring cost becomes unacceptably high. Muφhy's method approximates the effect of an uneven distribution of defects. Figure 5 also includes a graph of non fault tolerant yield 197 which explicitly models the clustering of defects by introducing a defect clustering factor. The defect clustering factor is not a controllable parameter in manufacturing, but is a characteristic of the manufacturing process. The defect clustering factor for manufacturing processes can be expected to be approximately 2, in which case yield projections closely match Muφhy's method. A solution to the problem of low yield is to incoφorate fault tolerance by including redundant functional units on the chip which are used to replace faulty functional units. In memory chips and most Wafer Scale Integration (WSI) devices, the physical location of redundant sub-units on the chip is not important However, in printing heads the redundant sub-unit may contain one or more printing actuators. These must have a fixed spatial relationship to the page being printed. To be able to print a dot in the same position as a faulty actuator, redundant actuators must not be displaced in the non-scan direction. However, faulty actuators can be replaced with redundant actuators which are displaced in the scan direction. To ensure that the redundant actuator prints the dot in the same position as the faulty actuator, the data timing to the redundant actuator can be altered to compensate for the displacement in the scan direction. To allow replacement of all nozzles, there must be a complete set of spare nozzles, which results in 100% redundancy. The requirement for 100% redundancy would normally more than double the chip area, dramatically reducing the primary yield before substituting redundant units, and thus eliminating most of the advantages of fault tolerance. However, with print head embodiments according to d is invention, the minimum physical dimensions of the head chip are determined by the widtii of the page being printed, the fragility of the head chip, and manufacmring constraints on fabrication of ink channels which supply ink to the back surface of the chip. The minimum practical size for a full width, full color head for printing A4 size paper is approximately 215 mm x 5 mm. This size allows the inclusion of 100% redundancy without significantly increasing chip area, when using 1.5 μm CMOS fabrication technology. Therefore, a high level of fault tolerance can be included without significantly decreasing primary yield. When fault tolerance is included in a device, standard yield equations cannot be used. Instead, the mechanisms and degree of fault tolerance must be specifically analyzed and included in the yield equation. Figure 5 shows the fault tolerant sort yield 199 for a full width color A4 head which includes various forms of fault tolerance, the modeling of which has been included in the yield equation. This graph shows projected yield as a function of both defect density and defect clustering. The yield projection shown in figure 5 indicates that thoroughly implemented fault tolerance can increase wafer sort yield from under 1% to more than 90% under identical manufacmring conditions. This can reduce the manufacmring cost by a factor of 100. Fault tolerance is highly recommended to improve yield and reliability of print heads containing thousands of printing nozzles, and thereby make pagewidth printing heads practical. However, fault tolerance is not to be taken as an essential part of the present invention. Fault tolerance in drop-on-demand printing systems is described in the following Austrahan patent specifications filed on 12 April 1995, the disclosure of which are hereby incoφorated by reference: 'Integrated fault tolerance in printing mechanisms' (Filing no.: PN2324); 'Block fault tolerance in integrated printing heads' (Fihng no.: PN2325); 'Nozzle duphcation for fault tolerance in integrated printing heads' (Filing no.: PN2326); 'Detection of faulty nozzles in printing heads' (Fihng no.: PN2327); and 'Fault tolerance in high volume printing presses' (Filing no.: PN2328). Printing System Embodiments A schematic diagram of a digital electronic printing system using a print head of this invention is shown in Figure 6. This shows a monohthic printing head 50 printing an image 60 composed of a multitude of ink drops onto a recording medium 51. This medium will typically be paper, but can also be overhead transparency film, cloth, or many other substantially flat surfaces which will accept ink drops. The image to be printed is provided by an image source 52, which may be any image type which can be converted into a two dimensional array of pixels. Typical image sources are image scanners, digitally stored images, images encoded in a page description language (PDL) such as Adobe Postscript, Adobe Postscript level 2, or Hewlett-Packard PCL 5, page images generated by a procedure-call based rasterizer, such as Apple QuickDraw, Apple Quickdr aw GX, or Microsoft GDI, or text in an electronic form such as ASCII. This image data is then converted by an image processing system 53 into a two dimensional array of pixels suitable for the particular printing system. This may be color or monochrome, and the data will typically have between 1 and 32 bits per pixel, depending upon the image source and the specifications of the printing system. The image processing system may be a raster image processor (REP) if the source image is a page description, or may be a two dimensional image processing system if the source image is from a scanner. If continuous tone images are required, then a halftoning system 54 is necessary. Suitable types of halftoning are based on dispersed dot ordered dither or error diffusion. Variations of these, commonly known as stochastic screening or frequency modulation screening are suitable. The halftoning system commonly used for offset printing - clustered dot ordered dither - is not recommended, as effective image resolution is unnecessarily wasted using this technique. The ouφut of the halftoning system is a binary monochrome or color image at the resolution of the printing system according to the present invention. The binary image is processed by a data phasing circuit 55 (which may be incoφorated in a Head Control ASIC 400 as shown in figure 4) which provides the pixel data in the correct sequence to the data shift registers 56. Data sequencing is required to compensate for the nozzle arrangement and the movement of the paper. When the data has been loaded into the shift registers 56, it is presented in parallel to the heater driver circuits 57. At the correct time, the driver circuits 57 will electronically connect the corresponding heaters 58 with the voltage pulse generated by the pulse shaper circuit 61 and the voltage regulator 62. The heaters 58 heat the tip ofthe nozzles 59, affecting the physical characteristics of the ink. Ink drops 60 escape from the nozzles in a pattern which corresponds to the digital impulses which have been apphed to the heater driver circuits. The pressure of the ink in the ink reservoir 64 is regulated by the pressure regulator 63. Selected drops of ink drops 60 are separated from the body of ink by the chosen drop separation means, and contact the recording medium 51. During printing, the recording medium 51 is continually moved relative to the print head 50 by the paper transport system 65. If the print head 50 is the full width of the print region of the recording medium 51 , it is only necessary to move the recording medium 51 in one direction, and the print head 50 can remain fixed. If a smaller print head 50 is used, it is necessary to implement a raster scan system. This is typically achieved by scanning the print head 50 along the short dimension of the recording medium 51 , while moving the recording medium 51 along its long dimension. Computer simulation of nozzle dynamics Details ofthe operation of print heads according to this invention have been extensively simulated by computer. Figures 8 to 18 are some results from an example simulation of a preferred nozzle embodiment's operation using electrothermal drop selection by reduction in surface tension, combined with electrostatic drop separation. Computer simulation is extremely useful in determining the characteristics of phenomena which are difficult to observe directly. Nozzle operation is difficult to observe experimentally for several reasons, including: 1 ) Useful nozzles are microscopic, with important phenomena occurring at dimensions less than 1 mm. 2) The time scale of a drop ejection is a few microseconds, requiring very high speed observations. 3) Important phenomena occur inside opaque sohd materials, making direct observation impossible. 4) Some important parameters, such as heat flow and fluid velocity vector fields are difficult to directly observe on any scale. 5) The cost of fabrication of experimental nozzles is high. Computer simulation overcomes the above problems. A leading software package for fluid dynamics simulation is FIDAP, produced by Fluid Dynamics International Inc. of Illinois, USA (FDI). FEDAP is a registered trademark of FDI. Other simulation programs are commercially available, but FIDAP was chosen for its high accuracy in transient fluid dynamic, energy transport, and surface tension calculations. The version of FIDAP used is FIDAP 7.51. The simulations combine energy transport and fluid dynamic aspects. Axi-symmetric simulation is used, as the example nozzle is cylindrical in form. There are four deviations from cylindrical form. These are the connections to the heater, the laminar air flow caused by paper movement, gravity (if the printhead is not vertical), and the presence of adjacent nozzles in the substrate. The effect of these factors on drop ejection is minor. To obtain convergence for transient free surface simulations with variable surface tension at micrometer scales with microsecond transients using FIDAP 7.51, it is necessary to nondimensionahze the simulation. Only the region in the tip of the nozzle is simulated, as most phenomena relevant to drop selection occur in this region. The simulation is from the axis of symmetry of the nozzle out to a distance of 40 μm. A the beginning of the simulation, the entire nozzle and ink is at the device ambient temperamre, which in this case is 30°C. During operation, the device ambient temperamre will be shghtiy higher than the air ambient temperature, as an equilibrium temperature based on printing density is reached over the period of many drop ejections. Most of the energy of each drop selection is carried away with the ink drop. The remaining heat in the nozzle becomes very evenly distributed between drop ejections, due to the high thermal conductivity of sihcon, and due to convection in the ink. Geometry of the simulated nozzle Figure 7 shows the geometry and dimensions of the a preferred nozzle embodiment modeled in this simulation. The nozzle is constructed on a single crystal sihcon substrate 2020. The substrate has an epitaxial boron doped sihcon layer 2018, which is used as an etch stop during nozzle fabrication. An epitaxial sihcon layer 2019 provides the active substrate for the fabrication of CMOS drive transistors and data distribution circuits. On this substrate are several layers deposited CMOS processing. These are a thermal oxide layer 2021, a first interlevel oxide layer 2022, first level metal 2023, second interlevel oxide layer 2024, second level metal 2025, and passivation oxide layer 2026. Subsequent processing of the wafers forms the nozzles and heaters. These structures include the active heater 2027(a), an ESD shield formed from 'spare' heater material 2027(b), and a sihcon nitride passivation layer 2028. The heater is atop a narrow 'rim' etched from the various oxide layers. This is to reduce the 'thermal mass' of the material around the heater, and to prevent the ink from spreading across the surface of the print head. The print head is filled with electrically conductive ink 2031. An electric field is apphed to the print head, using an electrode which is in electricd contact with the ink, and another electrode which is behind the recording medium. The nozzle radius is 8 μm, and the diagram is to scale. Theoretical basis of calculations The theoretical basis for fluid dynamic and energy transport calculations using the Finite Element Method, and the manner that this theoretical basis is apphed to the FEDAP computer program, is described in detail in the FIDAP 7.0 Theory Manual (April 1993) pubhshed by FDI, the disclosure of which is hereby incoφorated by reference. Material characteristics The table "Properties of materials used for FIDAP simulation" gives approximate physical properties of materials which may be used in the fabrication of the print head in accordance with this invention. The properties of 'ink' used in this simulation are that of a water based ink with 25% pigment loading. The ink contains a suspension of fine particles of palmitic acid Oiexadecanoic acid) to achieve a pronounced reduction in surface tension with temperature. The surface tensions were measured at various temperatures using a surface tensiometer. The values which have been used in the example simulation using the FIDAP program are shown in the table "Properties of materials used for FIDAP simulation". Most values are from direct measurement, or from the CRC Handbook of Chemistry and Physics, 72nd edition, or Lange's handbook of chemistry, 14th edition. Properties of materials used for FIDAP simulation Specific Heat (c p ) Heater 250 Jkg-'K '1 0.2589 Specific Heat (c p ) Si 3 N 4 712 Jkg-'K 1 0.7373 Density (p) Ink 1.036 gem 1 1.586 Density (p) Sihcon 2.320 gem '1 3.551 Density (p) SiO_ 2.190 gem '1 3.352 Density (p) Heater 10.50 gem 1 16.07 Density (p) Si 3 N 4 3.160 gem '1 4.836 Fluid dynamic simulations Figure 8(a) shows the power apphed to the heater. The maximum power applied to the heater is 40 mW. This power is pulse frequency modulated to obtain a desirable temporal distribution of power to the heater. The power pulses are each of a duration of 0.1 μs, each delivering 4 nJ of energy to the heater. The drop selection pulse is started 10 μs into the simulation, to allow the meniscus to settle to its quiescent position. The total energy delivered to the heater during the drop selection pulse is 276 nJ Figure 8(b) shows the temperature at various points in the nozzle during the simulation. Point A is at the contact point of the ink meniscus and the nozzle rim. For optimal operation, it is desirable that this point be raised as close as possible to the boiling point of the ink, without exceeding the boiling point, and maintained at this temperature for the duration of the drop selection pulse. The 'spiky' temperature curve is due to the pulse frequency modulation of the power applied to the heater. This 'spikiness' can be reduced by increasing the pulse frequency, and proportionally reducing the pulse energy. Point B is a point on the ink meniscus, approximately midway between the centre of the meniscus and the nozzle tip. Point C is a point on the surface of the sihcon, 20 μm from the centre of the nozzle. This shows that the temperature rise when a drop is selected is very smaU a short distance away from the nozzle. This aUows active devices, such as drive transistors, to be placed very close to the nozzles. Figure 9 shows the position versus time of a point at the centre of the meniscus. Figure 10 shows the meniscus position and shape at various times during the drop selection pulse. The times shown are at the start of the drop selection pulse, (10 μs into the simulation), and at 5 μs intervals, until 60 μs after the start of the heater pulse. Figure 11 shows temperature contours in the nozzle just before the beginning of the drop selection pulse, 9 μs into the simulation. The surface tension balances the combined effect of the ink pressure and the external constant electric field. Figure 12 shows temperamre contours in the nozzle 5 μs after beginning of the drop selection pulse, 15 μs into the simulation. The reduction in surface tension at the nozzle tip causes the surface at this point to expand, rapidly carrying the heat around the meniscus. The ink has begun to move, as the surface tension is no longer high enough to balance the combined effect of the ink pressure and the external constant electric field. The centre of the meniscus begins to move faster than the outside, due to viscous drag at the nozzle walls. In figures 12 to 17 temperamre contours are shown starting at 35 °C and increasing in 5°C intervals. Figure 13 shows temperamre contours in the nozzle 10 μs after beginning of the drop selection pulse, 20 μs into the simulation. Figure 14 shows temperature contours in the nozzle 20 μs after beginning of the drop selection pulse, 30 μs into the simulation. Figure 15 shows temperamre contours in the nozzle 30 μs after beginning of the drop selection pulse, 40 μs into the simulation. This is 6 μs after the end of the drop selection pulse, and the nozzle has begun to cool down. Figure 16 shows temperature contours in the nozzle 40 μs after beginning of the drop selection pulse, 50 μs into the simulation. If is clear from this simulation that the vast majority of the energy of the drop selection pulse is carried away with the selected drop. Figtire 17 shows temperature contours in the nozzle 50 μs after beginning of the drop selection pulse, 60 μs into the simulation. At this time, the selected drop is beginning to 'neck', and the drop separation process is beginning. Figure 18 shows streamlines in the nozzle at the same time as figure 17. The approximate duration of three consecutive phases in the drop ejection cycle are: 1) ms heater energizing cycle 2) ms to reach drop separation 3) ms to return to the quiescent position The total of these times is 124 μs, which results in a maximum drop repetition rate (drop frequency) of approximately 8 Khz. Drop ejection cycle of print heads using electrostatic separation The principle of operation of printing using electrostatic drop separation is shown in Figure 19(a) through Figure 19(e). In this case, the drop is selected by electrothermal transducers, which heat the ink at the nozzle tip, causing an increase in temperamre at the meniscus. The increased temperamre causes a reduction of surface tension below a critical surface tension, resulting in ink egress from the nozzle tip. Charge accumulates at the meniscus of the protruding drop, because the drop radius is smaU, and because the drop meniscus is the closest point to the opposite electrode. This charge concentrates the force produced by the electric potential field onto the selected drop. This force, in combination with the ink pressure, overcomes the reduced surface tension of the ink, and causes the selected drop to separate from the body of ink. The selected drop then accelerates towards the platen, striking the recording medium. The nozzle shown in figures 19(a) to 19(e) is of a type as manufactured by a process described in 'A self-aligned manufacturing process for monohthic LIFT print heads'. Figures 19(a) to 19(e) are shown to scale, with the nozzle radius being 20 μm, with the exception that the distance between the print head and the recording medium and platen is shown as being much less than recommended. A distance of between 0.3 mm and 1 mm is recommended. In figures 19(a) to 19(e) 67 is the platen and one of the pair of electrodes which generate the electric field, 51 is the print medium, 5 is the direction of print medium movement, 74 represents the 'lines of force' of the electric field, 100 is the body of ink, 101 is sihcon, 102 is sihcon dioxide, 103 is the electrothermal actuator (also referred to as 'heater'), 105 is boron doping of the sihcon substrate, 106 is an electrode connecting the heater to the drive circuitry, 108 is a passivation layer, and 109 is the print head hydrophobic layer. The print head assembly and body of ink is the other electrode of the pair of electrodes which generate the electric field. Figure 19(a) shows the nozzle in quiescent position. The ink is under pressure, resulting in the ink meniscus bulging. The bulge in the ink meniscus concentrates the electric field shghtiy. The combined forces due to the ink pressure and the electric field are in equilibrium with the ink surface tension. Figure 19(b) shows the nozzle shortly after an energizing pulse has been apphed to the heater 103. The heat is conducted to the ink surface, where the resultant rise in temperamre causes a local decrease in the surface tension of the ink. The decrease in surface tension may be the result of the natural properties of the ink, but is preferably enhanced by the inclusion of an agent in the ink which causes a significant faU in surface tension at the temperamre to which the ink is heated. The electric field becomes further concentrated at the ink meniscus. Figure 19(c) shows the drop evolution a short time later. The selected drop takes on a substantially cylindrical form due to a surface tension gradient from the nozzle tip to the centre of the meniscus. At this stage, the electric force acting upon the ink becomes sufficient to attract ink from the nozzle, though most of the ink movement is stiU caused by the positive ink pressure. Figure 19(d) shows the drop evolution a short time after the heater has been turned off. The surface tension begins to rise, causing ink to start to flow back into the nozzle. As the ink in the tip of the selected drop is stiU being attracted in the direction of the recording medium, the ink meniscus begins to 'neck'. The shght 'tilt' of the selected drop is due to the laminar air flow between the print head and the recording medium 51, caused by the movement of the recording medium. Figure 19(e) shows the selected drop after it separates from the body of ink. The selected drop becomes partially polarized in the electric field, but also retains some charge. The net force due to the electric field is in the direction of the platen 67, so the selected drop accelerates towards the platen, striking the recording medium 51. The meniscus of the remaining ink in the nozzle will osciUate shghtiy before returning to its quiescent position. The nozzle is ready to eject another drop once the meniscus has returned sufficiently to its quiescent position. The foregoing describes various general and preferred embodiments of the present invention. Modifications, obvious to those skilled in the art, can be made thereto without departing from the scope of the invention.

Claims: I Claim: 1. A drop on demand printing apparatus comprising: (a) nozzle means including an array of closely spaced drop ejection orifices; (b) manifold means for supplying a body of ink in common communication with the orifices of said nozzle means; (c) means for applying a positive pressure to ink in said manifold means, sufficient to cause ink to protrude from said orifices; (d) address means for energizing ink in selected orifices to cause the ink to protrude further from selected orifices; and (e) means for producing an electric field between ink in said orifices and a print station spaced opposite said nozzle means sufficient to attractively detach such further protruding ink from the nozzle means. 2. The invention defined in claim 1 wherein the magnitude of said positive pressure and said electric field are selected to be insufficient to cause separation of an ink drop from said ink body in absence of energization by said address means. 3. The invention defined in claim 2 wherein said address comprises means for heating ink proximate the egress of selected orifices. 4. The invention defined in claim 3 wherein the energy apphed by said address means is less than about 2 microjoules per drop ejection. 5. The invention defined in claim 3 wherein said electric field is in the range of between about 500V/mm and about 2,000V/mm. 6. The invention defined in claim 5 wherein the spacing between said orifices and said print station is in the range from about 0.3 to 1.0 mm. 7. The invention defined in claim 6 wherein the orifice radius of said nozzle means is about 20 μm. 8. The invention defined in claim 3 wherein said positive pressure is at least 2% above ambient 9. The invention defined in claim 3 wherein said pressure is approximately 1.1 atmospheres. 10. The invention defined in claim 3 wherein the pulse power of said address means is about 6mA per heater. 11. The invention defined in claim 3 wherein the pulse voltage of said address means is about 10V. 12. The invention defined in claim 3 wherein said address means apphes about lμJ per drop selection. 13. A method of separating selected drops from a body of ink in a print head comprising an orifice array and an ink manifold, said method including the steps of: (a) causing said elected drops to protrude from orifices of said piint head; and (b) applying an electric field to selected drops and unselected drops, the field strength of said electrostatic field being sufficient to move said selected drops far enough from said body of ink so that drop separation occurs, said field strength also being insufficient to cause said unselected drops to separate from said body of ink. 14. The method as claimed in claim 13 where said causing step comprises applying a positive pressure of about 1.1 atmospheres to ink in said manifold and heating ink in said orifices with about lμJ. 15. The method defined in claim 13 wherein said electric field has a strength of between about 500V/mm and about 2,000V/mm. 16. A drop on demand printer which includes a nozzle array and means for supplying a body of ink to said array, said printer comprising: (a) pressure means for causing ink to protrude from all nozzles to a first region; (b) selection means for causing said selected drops to protrude from selected nozzles to a second, further region; and (c) means for applying an electric field to selected drops and unselected drops, the field strength of said electric field being sufficient to move said selected drops far enough from said body of ink so that drop separation occurs, said field strength also being insufficient to cause said unselected drops to separate from said body of ink.

Inventors: SILVERBROOK KIA, SILVERBROOK, KIA
Applicants: EASTMAN KODAK CO, SILVERBROOK KIA, EASTMAN KODAK COMPANY, SILVERBROOK, KIA
Application year: 1996
Main classification: B41J2
IPC codes: B41J2