Ceramic guide rails for photographic film and paper and polymeric web perforation

Abstract: Ceramic guide rails for guiding photographic film into a perforating machine are disclosed. The ceramic includes zirconium oxide and yttria in a molar ratio of yttria to zirconium oxide of from about 3:97 to about 5:95. The zirconium oxide is essentially the tetragonal phase crystal grain. In an alternate embodiment of the present invention the outer surface of the zirconium oxide is altered to the cubic phase crystal grain or the monoclinic crystal grain.

Description: The present invention relates to the use of ceramic guide rails in a photographic film and paper and polymeric web perforating machine. More particularly, the use of ceramic guide rails in a photographic film perforating machine offers advantages over chrome plated stainless steel guide rails. Perforating equipment for photographic films and papers, use chrome plated stainless steel or a hardened stainless steel as guide rails for conveying films to the feed chute for perforation. Precision perforation on the film edges is required to advance or rewind films in cameras and projection of movie films on the screen. The guide rails in a perforator guide the film edges during transportation into a perforator. The guide rails also locate the film precisely prior to perforation. There are three guide rails in a typical perforator. The film edges rub against the guide rails at speeds of 100 to 300 feet per minute (30 to 91 meters per minute) and create a groove on the chrome plated steel rails in a relatively short time. As the groove deepens with time, the guide rails need to be replaced to ensure the film edges are perfectly aligned under the perforator punches for perforation. Thin chrome plating generally provides an adequate hard, wear resistant surface which does not produce scratches on the film. Thick chrome plating, however, generates a rough surface and is not used on stainless steel guide rails, unless the plating is lapped to generate a smooth surface. Moreover, photographic films contain corrosive silver halide salts and other additives which attack stainless steel through microcracks or pores in the chrome plating. The corrosion products along with the wear debris tend to contaminate the film which is being perforated. The present invention replaces the chrome plated stainless steel guide rails with yttria tetragonal zirconia polycrystal ceramic rails. The ceramic rails are in many cases more cost effective and provide superior wear resistance and corrosion resistance than prior art chrome plated stainless guide rails. In addition, the absence of corrosion products and the reduction in wear debris helps reduce film contamination. molar ratio of yttria to zirconium oxide of from about 3:97 to about 5:95. The ceramic of the present invention consists essentially of the tetragonal phase crystal grain. In an alternate embodiment of the present invention the surface of the ceramic guide rail has been modified to the cubic phase crystal grain. In another alternate embodiment of the present invention the surface of the ceramic guide rail has been modified to the monoclinic phase crystal grain. Figure 1 shows a schematic of a feed chute leading to a perforating machine. Figure 2 shows a full length curved ceramic insert guide rail and a straight ceramic insert guide rail. Figure 3 shows segmented ceramic insert guide rail. Figure 4 shows a side view of the stainless guide rail bracket with a ceramic insert. Figure 5 shows a top view of a stainless steel guide rail bracket and a ceramic insert guide rail. Figure 6 shows a third view of a stainless steel guide rail bracket including a ceramic insert. For a better understanding of the present invention, together with other advantages and capabilities thereof, reference is made to the following detailed description and appended claims in connection with the preceding drawings and description of some aspects of the invention. Shown in Figure 1 is a feed chute 10 for guiding a photographic film strip 14 into a perforator. The feed chute 10 includes a first guide rail 11 positioned on one side of the film strip 14 and a second guide rail 12 positioned on the other side of the film strip. A third guide rail is positioned just prior to the perforating machine (not shown). The perforating machine is located just upstream of the film strip in Figure 1. The present invention provides extremely durable and cost effective ceramic guide rails or ceramic inserts for stainless steel guide rails for guiding photographic film into perforating machines. Chrome plated stainless steel guide rails of the prior art do not provide good wear resistance. In addition, chrome plated steel guide rails are prone to corrosion. Loose debris from corrosion contaminates the photographic film. Chrome plated steel guide rails are typically recycled by grinding off the wear grooves and replating the guide rails. After repeated grinding and lapping, the guide rails no longer have the proper dimensional tolerance and must be thrown away. plated steel guide rails are prone to corrosion. Loose debris from corrosion contaminates the photographic film. Chrome plated steel guide rails are typically recycled by grinding off the wear grooves and replating the guide rails. After repeated grinding and lapping, the guide rails no longer have the proper dimensional tolerance and must be thrown away. The present invention uses a novel ceramic material described in US-A-5,336,282 and US-A-5,290,332. The material is yttria alloyed tetragonal zirconium oxide polycrystals (Y-TZP) which contain three to five mole percent of yttria in high purity zirconium oxide. Other alloying compounds like ceria (CeO) or magnesia (MgO) can also be used to achieve similar properties. Materials like silicon carbide, or composites like zirconia reinforced alumina or silicon carbide reinforced alumina may also be used in the present application. Pure zirconium oxide can exist in three different crystallographic states depending on the melting or sintering temperatures. The monoclinic phase forms at the lowest temperature. As the temperature increases, the monoclinic phase first transforms to a meta-stable tetragonal phase and then to the cubic phase. Cubic and tetragonal phases can be stabilized at room temperature by alloying the zirconia with yttria, calcia, ceria and magnesia. Shown in Figure 2 is a full length guide rail used for guiding photographic film into a perforating machine. The guide rail includes a stainless steel guide rail bracket 24, which includes various apertures 25 for mounting. Bonded to the stainless steel guide rail bracket is a curved ceramic (Y-TZP) insert 21. Also shown in Figure 2 is a full length straight Y-TZP ceramic insert 22. Figure 3 shows a similar arrangement as in Figure 2. However, instead of having a full length curved ceramic Y-TZP insert, segmented Y-l2P ceramic insert buttons are shown generally as 32. Figure 3 also shows a straight Y-TZP ceramic insert 22 along with the stainless steel guide rail bracket 24. The bracket 24 includes various apertures 25 for mounting and adjusting. Shown in Figures 4-6 is the third guide rail bracket including a ceramic Y-TZP insert. This bracket corresponds to guide rail 13 shown in Figure 1. Figure 4 shows a side view which includes the stainless steel guide rail bracket 42 and the ceramic insert 41. In Figures 4-6 the ceramic insert is straight. The ceramic inserts are bonded to the stainless steel by using either epoxy, a UV curable photo polymer, or any other known method. Example 1 Zirconium oxide powders were alloyed with up to 5 mole percent yttria, preferable 3 mole percent and calcined to get a single phase tetragonal polycrystal grain structure. These alloyed zirconia powders were cold compacted using high pressure to form green guide rail inserts as shown in Figure 2. The compacting pressures were varied between 10 and 20 kpsi, preferable 15 kpsi (69 and 138 MPa, preferable 100 MPa). The green inserts were sintered at temperatures ranging from 1400 to 1600 degrees C for 2 hours. During sintering, the inserts were placed between 2 flat TZP or alumina plates to keep them from buckling or distorting. The sintered inserts were then bonded to the stainless steel guide rail brackets with epoxy or a UV curable photo polymer. The top surface of the ceramic insert was then ground and lapped to better than a 4 micro inch (1 micrometer) finish. These Y-TZP ceramic insert bonded guide rails were placed in a film perforator and tested along side conventional chrome plated stainless steel guide rails. The Y-TZP ceramic inserts lasted 5 to 15 times longer than the stainless steel rails. In addition, the ceramic Y-TZP ceramic guide rails did not show any corrosion which thereby reduced debris and kept the film cleaner. Example 2 The same procedure was used as described in Example 1. During sintering, however, the active surfaces of the Y-TZP ceramic were made cubic by exposing them to a bed of magnesium oxide powder at 1500 degrees C. This modified the outer surfaces to the cubic structure. The modified guide rail inserts were not tested in a film perforator, however, lab experiments suggest that the modified cubic surfaces may have a longer surface life than the unmodified Y-TZP ceramic rail inserts. Example 3 The same procedure was used as described in Example 1. Dunng sintering, however, the active surfaces of the Y-TZP ceramic were made monoclinic by placing them to a bed of very fine (approximately 0.3 micrometer) pure zirconia powder at 1500 degrees C. This modified the outer surfaces to the monoclinic structure. The modified guide rail inserts were not tested in a film perforator, however, lab experiments suggest that the modified monoclinic surfaces may have a longer surface life than the unmodified Y-T7P ceramic rail inserts.

Claims: A ceramic guide rail for guiding photographic film and paper without adverse affect on said film and paper comprising a net-shape ceramic consisting essentially of zirconium oxide and yttria wherein the ceramic has a molar ratio of yttria to zirconium oxide of from about 3:97 to about 5:95 and wherein the ceramic consists essentially ofthe tetragonal crystal phase. A ceramic guide rail for guiding photographic film and paper without adverse affect on said film and paper comprising a net-shape ceramic consisting essentially of zirconium oxide and yttria wherein the ceramic has a molar ratio of yttria to zirconium oxide offrom about 3:97 to about 5:95 and wherein the ceramic comprises a tetragonal crystal phase grain core and a cubic crystal phase grain surface. A ceramic guide rail for guiding photographic film and paper without adverse affect on said film and paper comprising a net-shape ceramic consisting essentially of zirconium oxide and yttria wherein the ceramic has a molar ratio of yttria to zirconium oxide of from about 3:97 to about 5:95 and wherein the ceramic comprises a tetragonal crystal phase grain core and a monoclinic crystal phase grain surface. The ceramic guide rail as claimed in claim I wherein an outer surface of the guide rail has a 4 micro inch (1 micrometer) finish. The ceramic guide rail as claimed in claim I wherein an outer surface of the guide rail is curved.

Inventors: CHATTERJEE DILIP KUMAR, GHOSH SYAMAL KUMAR, KOLB THEODORE R, CHATTERJEE, DILIP KUMAR, GHOSH, SYAMAL KUMAR, KOLB, THEODORE R.
Applicants: EASTMAN KODAK CO, EASTMAN KODAK COMPANY
Application year: 1996
Main classification: C04B35
IPC codes: B65H23, C04B35