Sintered or compacted inorganic porous body and use therof as a filter

Abstract: An inorganic, porous, sintered or compacted body comprising inorganic particles in the form of polyhedral crystals having intercommunicating pores between the inorganic particles, wherein said pores have a pore size distribution such that the ratio of D10 to D90 is not more than 3 and D50 is 0.01-5 µm, D10, D50 and D90 being pore sizes at 10%, 50% and 90% cumulation from the largest pore size of the cumulative pore volume distribution, respectively, and wherein the porosity is 10-50%, may be used as a filter.

Description: The present invention relates to an alumina porous sintered body, a filter comprising the alumina porous sintered body as a filtering layer or an intermediate layer, and a filter comprising an alumina particles-packed body as a filtering layer or an intermediate layer. Porous ceramics have been utilized for various applications such as filtration, concentration, isolation and the like in the field of foods, pharmaceutical preparations, electronics, biotechnology and the like. The porous ceramics have also been utilized as a carrier of a catalyst for purifying a waste gas, a carrier for immobilizing a biological catalyst (e.g. enzyme, micro organism, etc.) used for a bioreactor and the like. In these applications, fine and uniform porosity is required in addition to intrinsic properties (e.g. heat resistance, chemical resistance, high strength, nontoxicity to living body, etc.) of the porous ceramics. It has been known that porous ceramics having a uniform pore size distribution can be produced, for example, by a process using spherical ceramics particles or spherical granulated particles as an aggregate (Japanese Patent Kokai(Laid-Open) No. 62-191480), a process for making the surface of alumina aggregate particles round by calcining in a reducing atmosphere at a high temperature more than 1800°C and the like(Japanese Patent Kokai(Laid-Open) No. 2-149482). However, the porous ceramics produced by the process disclosed in Japanese Patent Kokai(Laid-Open) No. 62-191480 have a pore size of more than 10 µm. The porous ceramics produced by the process disclosed in Japanese Patent Kokai(Laid-Open) No. 2-149482 are calcined at high temperature more than 1800°C and, therefore, it is difficult to keep a fine pore structure. Accordingly, these processes were not suited to apply for filtration of an etching solution for electronics. EP-A-0 644 278 discloses an alumina powder comprising single crystal particles having an octa- or higher polyhedral shape shown in Fig. 6 and a particle size distribution such that the D90/D10 ratio is not more than 10. This powder including said polyhedral particles is a suitable raw material for sintered products and for ceramic filters. The present inventors have studied intensively about the porous-ceramics which can be applied for filtration of the etching solution for electronics. As a result, it has been found that an alumina porous sintered body having a uniform pore size distribution and a pore size controlled to 0.01-5 µm can be applied for the above applications and is also superior in filtering characteristics. Thus, the present invention has been accomplished. It is an object of the present invention to provide an inorganic porous sintered body. It is another object of the present invention to provide a filter comprising the inorganic porous sintered body as a filtering layer or an intermediate layer, which is superior in filtering characteristics. It is still another object of the present invention to provide a filter comprising an inorganic particles-packed body as a filtering layer or an intermediate layer, which is superior in filtering characteristics. These objects as well as other objects and advantages of the present invention will become apparent to those skilled in the art from the following description with reference to the accompanying drawings. Fig. 1 is a graph illustrating the cumulative pore volume distribution curve of the porous sintered body obtained in Example 1. Fig. 2 illustrates the structure of the porous sintered body obtained in Example 4 (electron micrograph of 3,500 magnifications). Fig. 3 is a graph illustrating the cumulative pore volume distribution curve of the porous sintered body obtained in Example 5. Fig. 4 illustrates the structure of the porous sintered body obtained in Example 7 (electron micrograph of 1,000 magnifications). Fig. 5 illustrates the structure of the porous sintered body obtained in Comparative Example 1 (electron micrograph of 3,500 magnifications). Fig. 6 is a graph illustrating the cumulative pore volume distribution curve of the porous sintered body obtained in Comparative Example 3. Fig. 7 is a graph illustrating the relation between the thickness of a filtering layer of various porous sintered body filters and water permeation rate at a differential pressure (1 atm) obtained in Example 8 and Comparative Example 7. The present invention provides an alumina porous sintered body comprising alumina polyhedral particles having a primary particle size within the range from 0.5 to 18 µm, said alumina porous sintered body having intercommunicating pores between the alumina particles, wherein said pores have a pore size distribution such that the ratio of D10 to D90 is not more than 3 and D50 is 0.01-5 µm, D10, D50 and D90 being pore sizes at 10%, 50% and 90% cumulation from the largest pore size of the cumulative pore volume distribution, respectively, and wherein the porosity is 10-50%. The present invention also provides an alumina porous packed body comprising alumina polyhedral particles having a primary particle size within the range of from 0.5 to 18 µm, said alumina porous packed body having intercommunicating pores between the alumina particles, wherein said pores have a pore size distribution such that the ratio of D10 to D90 is not more than 3 and D50 is 0.01-5 µm, D10, D50 and D90 being pore sizes at 10%, 50% and 90% cumulation from the largest pore size of the cumulative pore volume distribution, respectively, and wherein the porosity is 10-50%. Hereinafter, the present invention will be explained in detail. The alumina porous sintered body of the present invention comprises alumina polyhedral particles. The alumina porous sintered body has pores formed by the alumina particles, and the ratio of D10 to D90 is not more than 3, preferably not more than 2, when D10, D50 and D90 are pore sizes at 10%, 50% and 90% cumulation from the largest pore size of a cumulative pore volume distribution, respectively. The pore size (D50) is from 0.01 to 5 µm, preferably from 0.01 to 3 µm, more preferably from 0.01 to 1 µm. The porosity of the inorganic porous sintered body is from 10 to 50%. The process for producing the inorganic porous sintered body of the present invention will be explained. The alumina particles used as an aggregate are polyhedral crystals. The polyhedral crystal has preferably a uniform particle size and form. The alumina particles are preferably polyhedral crystals of α-alumina in view of chemical resistance and heat resistance. Examples of the process for producing the inorganic particles of polyhedral crystals having a uniform particle size and form (e.g. polyhedral crystals of α-alumina) include, for example, processes disclosed in Japanese Patent Kokai (Laid-Open) Nos. 6-191833, 6-191836, 7-187613. That is, it is possible to produce polyhedral crystal particles of high-purity α-alumina, which have uniform particle size and form and have substantially no fracture surface, by calcining a precursor of α-alumina in an atmosphere containing a hydrogen halide, preferably hydrogen chloride. When agglomerated particles are contained in the inorganic particles of polyhedral crystals produced by these processes, they are preferably used after deagglomeration. The alumina particles obtained by said process are polyhedral crystals characterized by having the following crystal surfaces: surface a {1120}, surface c {0001}, surface n {2243} and surface r {1012}. The purity of the particles is preferably not less than 99.9% by weight and primary particles thereof have narrow and uniform particle size distribution. That is, primary particles have a particle size distribution such that the ratio of D10 to D90 is not more than 3, when D10 and D90 are particle sizes at 10% and 90% cumulation from the largest particle size of the cumulative particle size distribution, respectively. The inorganic porous sintered body of the present invention can be produced by press molding, isostatic molding, extrusion molding or slip casting the resulting alumina particles into a desired form, followed by calcining at a temperature from 1000 to 1800°C. A molding aid can be used so as to increase the strength of the molded body. As the molding aid, organic materials removed by calcination, or inorganic materials compatibilized with the raw inorganic particles by calcination are preferred. Specific examples thereof include, for example, polyvinyl alcohol, polyvinyl butyral, methylcellulose, alumina sol and titania sol, but are not limited thereto. The calcining temperature is from 1000 to 1800°C, preferably from 1200 to 1600°C. When the calcining temperature is less than 1000°C, the strength of the porous sintered body may become weak, therefore, it is not suitable for practical use. On the other hand, when it exceeds 1800°C, the pore size distribution may become wide and the porosity may become small. Thus, there can be produced the inorganic porous sintered body of the present invention wherein the ratio of D10 to D90 is not more than 3, preferably not more than 2, D50 is from 0.01 to 5 µm, preferably from 0.01 to 3 µm, more preferably from 0.01 to 1 µm, and the porosity is from 10 to 50%. The diameter and porosity of pores of the inorganic porous sintered body can be appropriately adjusted by selecting the average particle size of the inorganic particles as the raw material according to applications. An alumina particles-packed body can be obtained by packing the polyhedral crystalline alumina particles obtained by the above production process in a retention container. Since the alumina particles produced by the above process have uniform form and particle size, they can be packed in the retention container, easily and densely. Therefore, a filter comprising the alumina particles-packed body as the filtering layer can be produced. As another embodiment of producing the alumina particles-packed body, for example, the alumina particles-packed body can also be produced by press molding (e.g. uniaxial molding), isostatic molding, extrusion molding or slip casting molding. The alumina particles constituting the alumina particles-packed body thus obtained are polyhedral crystals, and the alumina particles-packed body has pores formed by the alumina particles which are polyhedral crystals. The ratio of D10 to D90 is not more than 3, preferably not more than 2, and D50 is from 0.01 to 5 µm, preferably from 0.01 to 3 µm, more preferably from 0.01 to 1 µm, when D10, D50 and D90 are pore sizes at 10%, 50% and 90% cumulation from the largest pore size of a cumulative pore volume distribution, respectively. The porosity is from 10 to 50%. The above alumina porous sintered body and alumina particles-packed body are suitably used as a filter. These can be used alone as the filter, or can also be used in combination with another base material or used by laminating on another material, as a filtering layer in a multi-layer filter. Examples of the other base material used in combination include inorganic porous sintered body (e.g. alumina having a larger pore size) or porous sintered metal body or porous glass. When using the alumina porous sintered body and alumina particles-packed body as a filter, the thickness of the alumina porous sintered body or alumina particles-packed body is preferably about from 1 to 100 µm. The alumina porous sintered body is preferably used in the multi-layer filter comprising the alumina porous sintered body as the substantial filtering layer by laminating it on the other base material. In this case, the other base material preferably has superior permeability to fluids (e.g. water), for example, inorganic porous sintered body (e.g. alumina having a larger pore size) or porous sintered metal body or porous glass. According to this process, it is possible to improve the permeability while maintaining excellent filtering characteristics of the alumina porous sintered body, thereby improving the treating capacity of the filter. The alumina porous sintered body of the present invention is composed of an aggregate of alumina polyhedral particles, and has narrow pore volume distribution such that the ratio of D10 to D90 is not more than 3 when D10, D50 and D90 are pore sizes at 10%, 50% and 90% cumulation from the largest pore size of the cumulative pore volume distribution, respectively. Therefore, when using the alumina porous sintered body as the filter, a rate of passing particles having a diameter larger than the desired particle size becomes small, and screening characteristics as the filter are excellent. The alumina porous sintered body of the present invention is composed of an aggregate of polyhedral particles which have substantially no fracture surface, and has few closed pores derived from non-uniform particles and sintering. Accordingly, when using the alumina porous sintered body as the filter, a permeation resistance of a fluid is small and a water permeation rate is large. Therefore, permeating characteristics as the filter are excellent. The filter comprising the alumina particles-packed body of the present invention as the filtering layer also has a narrow pore volume distribution such that the ratio of D10 to D90 is not more than 3 when D10 and D90 are pore sizes at 10% and 90% cumulation from the largest pore size of the cumulative pore volume distribution, respectively, similar to the alumina porous sintered body of the present invention, and is superior in permeating characteristics as the filter. The following Examples further illustrate the present invention in detail but are not to be construed to limit the scope thereof. The measurement of physical properties in the Examples was conducted according to the following procedures. (1) Measurement of average primary particle size A SEM (scanning electron microscope T-300, manufactured by JEOL Ltd.) photograph of polyhedral crystals was taken. Eighty to one hundred particles were selected from the photograph and image analysis was conducted to determine an average value of a corresponding circle diameter. The corresponding circle diameter means a value obtained by converting into a diameter of a perfect circle having the same area. (2) Measurement of average pore size (D50) and pore size distribution (D10/D90) It was measured using a mercury porosimeter (Autoscan-60, manufactured by Yuasa Ionix Corp.) based on the principle of the mercury penetration process. D10/D90 was determined as a measure of the pore size distribution and a value of D50 is an average pore size when D10, D50 and D90 are pore sizes at 10%, 50% and 90% cumulation from the largest pore size of a cumulative pore volume distribution, respectively. (3) Measurement of water permeation rate It was measured using a flow pore size distribution measuring device "Perm Porometer" manufactured by Porous Material Inc. A water permeation rate was measured by sandwiching a plate-like sample between circular rubber ring having a diameter of 2 cm from both surfaces and making pressurized (0-3 atm) deionized water permeates into this circle. (4) Measurement of porosity After a dry weight of an inorganic porous sintered body or a packed body of inorganic particles was measured, air in pores was substituted with ethanol by deaerating in the state of being dipped in ethanol. After completion of the substitution, an in-liquid weight was measured in ethanol. Furthermore, the porous sintered body or packed body was pulled out from ethanol and a wet weight was measured in the state where pores are filled with ethanol. The porosity was calculated by the following equation: Porosity (%) = 100 x (wet weight - dry weight)/(wet weight - in-liquid weight) The powder of polyhedral α-alumina particles having a uniform particle size and form used in the following Examples was produced by the process described in Japanese Patent Kokai (Laid-Open) No. 6-191833 or 6-191836. An aluminum oxide powder (manufactured by Sumitomo Chemical Industries Co., Ltd., AKP-G15, γ-alumina) was calcined in a reaction system into which hydrogen chloride gas was introduced. A mixed powder containing aluminum oxide powder (manufactured by Sumitomo Chemical Industries Co., Ltd., AKP-50, α-alumina) as a seed crystal was prepared and this mixed powder was calcined in the reaction system into which the hydrogen chloride gas was introduced (concentration of hydrogen chloride gas: 100 volume fraction %). A retention temperature was from 900 to 1100°C and a retention time was 60 minutes. Example 1 A polyhedral α-alumina powder (average primary particle size: 0.5 µm, D90/D10: 2.5) was molded into a disk form having a diameter of 54 mm and a thickness of 2 mm by molding (molding pressure: 300 kg/cm 2 ) using a uniaxial press. This molded body was calcined in an air atmosphere. A calcining temperature was 1100°C and a calcining time was 2 hours. A cumulative pore volume distribution curve of the resulting porous sintered body measured by the mercury permeation process is shown in Fig. 1. The results of an average pore size, a ratio of D10 to D90 and a porosity are shown in Table 1. Example 2 A porous sintered body was made under the same conditions as those of Example 1 except for using a polyhedral α-alumina powder (average primary particle size: 2 µm, D90/D10: 2.0) and increasing the calcining temperature to 1500°C, and then the porous sintered body was evaluated. The results are shown in Table 1. Example 3 To a polyhedral α-alumina powder (average primary particle size: 2 µm, D90/D10: 2.0) was added an alumina sol (alumina manufactured by Condea Corp., Pural SB, specific surface area: 250 m 2 /g as a molding aid, was dispersed in an aqueous 1 wt% nitric acid solution to give an alumina sol) in an amount of 10% by weight (in terms of powder weight) per polyhedral α-alumina powder, and the mixture was dried to obtain a mixed powder. A porous sintered body was made under the same conditions as those of Example 1 except for increasing the calcining temperature to 1300°C, and then the porous sintered body was evaluated. The results are shown in Table 1. Example 4 A porous sintered body was made under the same conditions as those of Example 1 except for using a polyhedral α-alumina powder (average primary particle size: 3 µm, D90/D10: 2.0) and increasing the calcining temperature to 1700°C, and then the porous sintered body was evaluated. The results are shown in Table 1. An electron micrograph (3,500 magnifications) illustrating a fine structure of the resulting porous sintered body is shown in Fig. 2. It was confirmed by Fig. 2 that polyhedral grains densely agglomerate to form homogeneous pores. Example 5 A polyhedral α-alumina powder (average primary particle size: 5 µm, D90/D10: 1.8) (50 g) was weighed, and deionized water (200 g) and 1% by weight per polyhedral α-alumina powder, in term of powder weight, of a polyvinyl alcohol (manufactured by Kuraray Corp., Kuraray Poval PVA-205) as a molding aid were added to obtain a slurry. The slurry was dried to obtain a mixed powder. A molded body was made under the same conditions as those of Example 1, and then the molded body was calcined at 1700°C to make a porous sintered body and the obtained porous sintered body was evaluated. A cumulative pore volume distribution curve of the resulting porous sintered body due to the mercury penetration process is shown in Fig. 3. Example 6 A molded body was made using a polyhedral α-alumina powder (average primary particle size: 10 µm, D90/D10: 2.2) under the same conditions as those of Example 5, and then the molded body was calcined at 1500°C to make a porous sintered body and the obtained porous sintered body was evaluated. The results are shown in Table 1. Example 7 A molded body was made using a polyhedral α-alumina powder (average primary particle size: 18 µm, D90/D10: 2.5) under the same conditions as those of Example 5, and then the molded body was calcined at 1600°C to make a porous sintered body and the obtained porous sintered body was evaluated. The results are shown in Table 1. An electron micrograph (1,000 magnifications) illustrating a fine structure of the resulting porous sintered body is shown in Fig. 4. Comparative Example 1 To an α-alumina powder (manufactured by Fujimi Kenmazai Kogyo Co., Ltd., WA#6000, average primary particle size: 2 µ m, alumina powder of free-form particles which are not polyhedral crystals) made by the electromelting process was added an alumina sol (alumina manufactured by Condea Corp., Pural SB, specific surface area: 250 m 2 /g, as a molding aid, was dispersed in an aqueous 1 wt% nitric acid solution to give an alumina sol) in an amount of 10% by weight (in terms of powder weight) per electromolten α-alumina powder, and then the mixture was dried to obtain a mixed powder. A porous sintered body was made using this mixed powder under the same conditions as those of Example 3, and then the porous sintered body was evaluated. The results are shown in Table 1. An electron micrograph (3,500 magnifications) illustrating a fine structure of the resulting porous sintered body is shown in Fig. 5. Comparative Example 2 An α-alumina powder (manufactured by Fujimi Kenmazai Kogyo Co., Ltd., WA#2000, average primary particle size: 8 µ m, alumina powder of free-form particles which are not polyhedral crystals) made by the electromelting process was molded into a disk form having a diameter of 54 mm and a thickness of 2 mm by molding (molding pressure: 300 kg/cm 2 ) using an uniaxial press. This molded body was calcined in an air atmosphere. A calcining temperature was 1700°C and a calcining time was 2 hours. The resulting porous sintered body was evaluated. The results are shown in Table 1. Comparative Example 3 A porous sintered body was made using an α-alumina powder (manufactured by Fujimi Kenmazai Kogyo Co., Ltd., WA#2000, average primary particle size: 8 µm, alumina powder of free-form particles which are not polyhedral crystals) made by the electromelting process under the same conditions as those of Comparative Example 1, and then the porous sintered body was evaluated. A cumulative pore volume distribution curve of the resulting porous sintered body due to the mercury penetration process is shown in Fig. 6. Comparative Example 4 A porous sintered body was made using an α-alumina powder (manufactured by Fujimi Kenmazai Kogyo Co., Ltd., WA#800, average primary particle size: 20 µm, alumina powder of free-form particles which are not polyhedral crystals) made by the electromelting process under the same conditions as those of Comparative Example 2, and then the porous sintered body was evaluated. The results are shown in Table 1. Comparative Example 5 A porous sintered body was made using an α-alumina powder (manufactured by Fujimi Kenmazai Kogyo Co., Ltd., WA#800, average primary particle size: 20 µm, alumina powder of free-form particles which are not polyhedral crystals) made by the electromelting process under the same conditions as those of Comparative Example 1, and then the porous sintered body was evaluated. The results are shown in Table 1. Comparative Example 6 A molded body was made using an α-alumina powder (manufactured by Sumitomo Chemical Industries Co., Ltd., AKP-20, average primary particle size: 0.5 µm, alumina powder of free-form particles which are not polyhedral crystals) made by the hydrolysis process under the same conditions as those of Example 1, and then the molded body was calcined at 1100°C. The resulting porous sintered body was evaluated. The results are shown in Table 1. Example 8 A polyhedral α-alumina powder (average primary particle size: 2 µm, D90/D10: 2.0) (50 g) was weighed, and deionized water (30 g), a dispersing agent (SN-5468, San Nopco Co., Ltd.)(0.5% by weight based on the powder weight) and polyvinyl alcohol (manufactured by Kuraray Corp., Kuraray Poval PVA. 205) (1% by weight based on the powder weight) as a molding aid were added to obtain a slurry. Four kinds of molded bodies were made using this slurry by the slip casting process, and then the molded bodies were calcined at 1400°C to obtain inorganic porous sintered bodies having a diameter of 30 to 60 mm and a thickness of 1 to 3 mm. An average pore size of these inorganic porous sintered bodies is from 0.5 to 0.6 µm and D10/D90 was 1.4 to 1.5. Furthermore a base material was made using a polyhedral α-alumina powder (average primary particle size: 18 µm, D90/D10: 2.5) according to the same manner as that described above, and then the base material was calcined at 1700°C. The resulting base material was dipped in a slurry containing the above polyhedral α-alumina powder (average primary particle size: 2 µm), pulled out from the slurry, and then dried, and then calcined at 1400°C to obtain a two-layer filter having a filtering layer (thickness: about 100 µm) as a porous sintered body of a polyhedral α-alumina powder having an average particle size of 2 µm on the base material. A water permeation rate of these porous sintered bodies was measured using deionized water. The measuring results were arranged to give a relation between a thickness of a filtering layer and a water permeation rate. The relation is shown in Fig. 7. As is apparent from Fig. 7, the water permeation rate of this porous sintered body was superior to that of the porous sintered body of Comparative Example 7. Comparative Example 7 An inorganic porous sintered body having a diameter of 30 to 60 mm and a thickness of 1 to 3 mm was obtained using an α-alumina powder (manufactured by Fujimi Kenmazai Kogyo Co., Ltd., WA#6000, average primary particle size: 2 µm, alumina powder of free-form particles which are not polyhedral crystals) according to the same manner as that described in Example 8. An average pore size of these inorganic porous sintered bodies is from 0.6 to 0.7 µm and D10/D90 was 2.0 to 2.7. Furthermore a base material was made using a polyhedral α-alumina powder (average primary particle size: 18 µm, D90/D10: 2.5) according to the same manner as that described above, and then the base material was calcined at 1700°C. The resulting base material was dipped in a slurry containing an α-alumina powder (average primary particle size: 2 µm) made by the above electromelting process, pulled out from the slurry, and then dried , and then calcined at 1400°C to obtain a two-layer filter having a filtering layer (thickness: about 50 µm) as a porous sintered body of an electromolten α-alumina powder having an average particle size of 2 µm on the base material. A water permeation rate of these porous sintered bodies was measured using deionized water. The measuring results were arranged to give a relation between a thickness of a filtering layer and a water permeation rate. The relation is shown in Fig. 7. Example 9 A polyhedral α-alumina powder (average primary particle size: 2 µm, D90/D10: 2.0) was charged in a cylindrical metal container (inner diameter: 2 cm, the bottom part is a sintered metal plate having an average pore size of 10 µm) and packed by tapping. Then, the powder was pressurized at 300 kg/cm 2 using an uniaxial press. The water permeation rate was measured using a packed body wherein a thickness of the resulting powder layer is 3 mm according to the same manner as that described in Example 8. The water permeation rate was 0.35 ml/sec. Filtering characteristics were good. raw material powder primary particle size (µm) molding aid D50 (µm) D10 (µm) D90 (µm) D10/D90 porosity (%) water permeation rate (ml/sec) Ex.1 polyhedral α-alumina 0.5 no 0.26 0.30 0.22 1.37 42.9 - Ex.2 polyhedral α-alumina 2 no 0.56 0.67 0.45 1.49 28.4 0.23 Ex.3 polyhedral α-alumina 2 alumina sol 0.62 0.75 0.41 1.84 37.8 - Ex.4 polyhedral α-alumina 3 no 0.85 1.11 0.68 1.63 21.3 - Ex.5 polyhedral α-alumina 5 PVA 1.21 1.57 0.86 1.83 25.5 0.5 Ex.6 polyhedral α-alumina 10 PVA 2.75 4.33 2.17 2.00 39.1 - Ex.7 polyhedral α-alumina 18 PVA 4.10 5.60 2.45 2.28 38.9 1.3 C.Ex.1 electromolten α-alumina 2 alumino sol 0.75 1.21 0.45 2.70 45.2 0.20 C.Ex.2 electromolten α-alumina 8 no 1.89 2.96 1.27 2.34 - 0.3 C.Ex.3 electromolten α-alumina 8 alumina sol 2.30 3.93 1.00 3.91 43.3 - C.Ex.4 electromolten α-alumina 20 no 6.78 9.03 3.50 2.58 - 0.9 C.Ex.5 electromolten α-alumina 20 alumina sol 3.54 4.56 1.49 3.06 41.6 - C.Ex.6 hydrolysis α-alumina 0.5 no 0.20 0.38 0.15 2.53 - -

Claims: An alumina porous sintered body comprising alumina polyhedral particles having a primary particle size within the range from 0.5 to 18 µm, said alumina porous sintered body having intercommunicating pores between the alumina particles, wherein said pores have a pore size distribution such that the ratio of D10 to D90 is not more than 3 and D50 is 0.01-5 µm, D10, D50 and D90 being pore sizes at 10%, 50% and 90% cumulation from the largest pore size of the cumulative pore volume distribution, respectively, and wherein the porosity is 10-50%. An alumina porous packed body comprising alumina polyhedral particles having a primary particle size within the range from 0.5 to 18 µm, said alumina porous packed body having intercommunicating pores between the alumina particles, wherein said pores have a pore size distribution such that the ratio of D10 to D90 is not more than 3 and D50 is 0.01-5 µm, D10, D50 and D90 being pore sizes at 10%, 50% and 90% cumulation from the largest pore size of the cumulative pore volume distribution, respectively, and wherein the porosity is 10-50%. A filter comprising an alumina porous sintered body or alumina porous packed body according to claim 1 or 2, alone or in combination with another material. A process for the preparation of an alumina porous sintered body according to claim 1, which process comprises press molding, isostatic molding, extrusion molding or slip casting polyhedral crystalline alumina particles having a particle size distribution such that the ratio of D10 to D90 is not more than 3, followed by calcining at a temperature of from 1000 to 1800°C. A process for the preparation of an alumina porous packed body according to claim 2, which process comprises packing in a retention container or press molding, isostatic molding, extrusion molding or slip casting polyhedral crystalline alumina particles having a particle size distribution such that the ratio of D10 to D90 is not more than 3. Use of an alumina porous sintered body or alumina porous packed body according to claim 1 or 2 as a filter. Use according to claim 6 in the filtration of an etching solution for electronics.

Inventors: MOHRI MASAHIDE, UMEDA TETSU, MOHRI, MASAHIDE, UMEDA, TETSU
Applicants: SUMITOMO CHEMICAL CO, SUMITOMO CHEMICAL COMPANY, LIMITED
Application year: 1996
Main classification: C04B38
IPC codes: B01D39, C04B38