CLEANING, CONDITIONING AND STYLING HAIR CARE COMPOSITIONS

Abstract: Disclosed are hair care compositions and methods for preparing such compositions which provide the benefits of cleaning, conditioning, curl retention, styling and setting properties simultaneously to hair in the application of a single product. The hair care compositions contain fatty alkyl amine salts, long chain quaternary ammonium salts and mixtures thereof of anionic styling polymers in a non-anionic surfactant system, wherein the surfactant system contains nonionic surfactants, semi-polar nonionic surfactants, amphoteric surfactants and mixtures thereof. The styling, setting and conditioning agents are present in the form of fatty alkyl amine salts or fatty quaternary ammonium salts which form anionic styling polymer particulate networks upon dilution in water. These networks are dispersed in the aqueous non-anionic surfactant system and are stabilized and thickened by optional swellable polymer thickening agents. Hair care compositions of the present invention can be made in the form of structured liquids, pearlescent/opaque isotropic liquids and/or translucent/clear isotropic liquids. The hair care compositions of the present invention, which allow for re-styling of the hair by wetting the hair with water, contain non-anionic surfactants, silicones, solvents or cationic polymeric conditioning agents. Furthermore, multiple application of these hair care compositions does not produce a noticeable build-up on the hair.

Description: CLEANING, CONDITIONING AND STYLING HAIR CARE COMPOSITIONS BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to hair care compositions and methods for preparing such compositions which provide the multiple benefits of cleaning, conditioning, styling, curl retention, bodifying, stiffness and setting propeπies to the hair in the application of a single product to the hair. More specifically, the invention relates to hair-care compositions containing a styling polymer and a cationic compound in a non-anionic surfactant system. The surfactant system contains nonionic surfactants, semi-polar nonionic surfactants, amphoteric surfactants and mixtures thereof. The hair care compositions of the present invention, when diluted in water during use, form and/or release the styling/conditioning agents to the hair in the form of macrofibrils or dispersed small complex particles. Description of the Related Art The process of hair care is multifaceted and generally involves washing, conditioning, and styling the hair, often as a three step process. The first step of the process involves the thorough cleaning of the hair with an initial appiicauon of shampoo. After the hair is cleaned and rinsed, the second step of the process involves conditioning the hair with a conditioner, which is applied to the hair and allowed to thoroughly penetrate into the hair. After a sufficient penod of time, the residual conditioner is rinsed off the hair with water. Typically, conditioners contain cationic conditioning agents or suspended silicone conditioning agents which adhere to the hair follicle after the residual conditioning product is rinsed off the hair. The third step of the process optionally involves the application of styling agents to assist in arranging and forming the hair into a desired configuration. The desirable results of the hair care process include a persistent look and feel of clean hair between washings, ease of combing, absence of static electricity, manageability, soft feel and shine. In general, these results are obtained by utilizing a hair conditioning product which is separate from the hair cleaning product. The use of two separate products for cleaning and conditioning of hair involves the use of a shampoo cleaning product and a separate rinse out conditioner or the use of a shampoo cleaning product and a separate leave-on conditioner The use of two separate products in the hair care process is regarded as somewhat of an inconvenience to consumers A limited number of hair care products are available which clean as well as condition the hair by the use of one product, i.e , a two-in-one conditioning shampoo Certain two-in-one conditioning shampoos typically contain water, anionic surfactants, foam stabilizers, insoluble nonvolatile silicone conditioning agents and silicone suspending agents Other such products contain canonic condinoning agents in place of silicone However, all of these two-in-one products have vaπous limitations These limitations are well known in the art Hair care products which impaπ hair styling, I e., shape and style retennon, are numerous Such products typically fall into two catagoπes (1 ) products that chemically alter hair, and (2) products that temporaπly alter the shape or style of hair style Each ol these methods has its own problems For example, temporary styling requires a separate application step following cleaning and/or conditioning of the hair Additionally, many of the polymer based styling aids tend to make the hair feel undesirably sticky and stiff after application Sail other hair care products are available which simultaneously clean, condition and control dandruff, i.e, a 3-ιn-l anti-dandruff shampoo Since known two- and three-in-one hair care products have vaπous limitations, a need exists for surfactant based hair styling shampoo compositions which are capable of dehveπng cleaning, foaming, conditioning, curl retention, body and styling propeπies to the hair in one application step, with limited or no build up of the compositions on the hair after mulnple application, and at the same time are free of nonaqueous solvents Avoiding the use of nonaqueous solvents in hair care compositions is highly desirable, from economical, environmental and consumer demand points-of-view It is desired that new hair care composinons provide comparable or supeπor cleaning, foaming, conditioning, curl retention and styling properues to the hair in one application step, as compared to pnor an hair care compositions and/or the use of two or more products in two or more application steps Further, a need exists for compositions with the above descπbed properues which are efficacious on fine, long, or chemically damaged hair SUMMARY OF THE INVENTION The present invention provides hair care compositions that are substantially free ot nonaqueous solvents, which impart cleaning, foaming, conditioning, curl retention and styling properties to the hair, compπsing: (a) from about 1 percent to about 80 percent by weight, based on the total weight of the hair care composiπon, of a first surfactant member selected from the group consisting of nonionic surfactants, semi-polar nonionic surfactants, amphoteπc surfactants and mixtures thereof, (b) from about 0.1 percent to about 10 percent by weight, based on the total weight of the hair care composiπon, of a second surfactant member selected from the group consisting of cationic surfactants, fatty amine salts and mixtures thereof; and (c) from about 0001 percent to about 10 percent by weight, based on the total weight of the hair care composition, of an anionic polymer member selected from the group consisting of polymers with one or more carboxylic acid groups, polymers with one or more carboxylic acid alkali metal salt groups, polymers with one or more sulfate groups, polymers with one or more sulfonate groups and mixtures thereof. The cationic surfactant employed in the invention is represented by Formula V 1 wherein R], R2, R3, and R4 independently represent hydrocarbyl chains of from about 1 to about 30 carbon atoms, or hydrocarbyl chain having from about 1 to about 30 carbon atoms optionally containing one or more aromatic, ether, ester, amido, or amino moieties present as substituients or as linkages in the hydrocarbyl chain, where at least one of the R 1 -R4 groups is optionally substituted with at least one or more hydrophilic moieties independently selected from alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, and alkylester, and X is a soluble salt forming anion The hair care compositions of the present invention optionally contain from about ϋ l percent to about 10 percent by weight, based on the total weight of the hair care composition, of a swellable polymer thickening agent The present mvennon also provides methods for treating hair compπsing applying to hair a composition according to the invention The present invention further provides methods for prepaπng hair care compositions compπsing combining, in any order, (a) from about 1 percent to about 80 percent by weight, based on the total weight of the hair care composition, of a first surfactant member selected from the group consisting of nonionic surfactants, semi-polar nonionic surfactants, amphoteπc surfactants and mixtures thereof; (b) from about 0.1 percent to about 10 percent by weight, based on the total weight of the hair care composinon, of a second surfactant member selected from the group consisting of canonic surfactants, fatty amine salts and mixtures thereof, and (c) from about 0 001 percent to about 10 percent by weight, based on the total weight ot the hair care composition, of an anionic polymer member selected from the group consisαng of polymers with one or more carboxylic acid groups, polymers with one or more carboxylic acid alkali metal salt groups, polymers with one or more sulfate groups, polymers with one or more sulfonate groups and mixtures thereof In addition, the mvennon encompasses methods for prepaπng a styling and conditioning agent compπsing combining a surfactant member selected from the group consisting of cationic surfactants, fatty amine salts, and mixtures thereof with an anionic polymer The invention also encompasses a styling and conditioning agent prepared by the reacuon of an anionic polymer with a surfactant member selected from the group consisting of canonic surfactants, fatty amine salts, and mixtures thereof The present invention provides methods for prepaπng a hair care composition compπsing combining (a) from about 1 percent to about 80 percent by weight, based on the total weight of the hair care composition, of the first surfactant member descπbed above; and (b) from about 0.001 percent to about 20 percent by weight, based on the total weight of the hair care composinon, of the styling and condinoning agent of the invennon. The mvennon fuπher provides a charge transfer complex produced by the combmanon of an anionic polymer and a surfactant member; wherein the charge transfer complex has a molecular weight of at least 100,000, where the anionic polymer is selected from the group consisting of polymers with one or more carboxylic acid groups, polymers with one or more carboxylic acid alkali metal salt groups, polymers with one or more sulfate groups, polymers with one or more sulfonate groups and mixtures thereof; and where the surfactant member is selected from the group consisting of cationic surfactants, fatty amine salts and mixtures thereof . The present invennon relates to a compound of Formula 2: wherein n is an integer from about 1 - 500,000; m is an integer from about 1 - 1 ,000,000, Rj , R2, R3, and R4 independently represent hydrocarbyl chains of from about 1 to about 30 carbon atoms, or hydrocarbyl chain having from about 1 to about 30 carbon atoms and opuonally containing one or more aromatic, ether, ester, amido, or amino moieties present as substituients or as linkages in the hydrocarbyl chain, where at least one of the R 1 -R4 groups is optionally substituted with at least one or more hydrophilic moieties independently selected from alkoxy (preferably C\ C3 alkoxy), polyoxyalkylene (preferably C1-C3 polyoxyalkylene), alkylamido, hydroxyalkyl, and alkylester The present invennon relates to a compound of Formula 3 wherein n is an integer from about 1 - 500,000; m is an integer from about 1 - 500,000, wherein R is alkyl, alkenyl, alkynyl, aryl, alkylaryl, and mixtures thereof, R ] , R2, R3, and R4 independently represent hydrocarbyl chains of from about 1 to about 30 carbon atoms, or hydrocarbyl chain having from about 1 to about 30 carbon atoms and optionally containing one or more aromanc, ether, ester, amido, or amino moieties present as subsntuients or as linkages in the hydrocarbyl chain, where at least one of the R1-R4 groups is optionally substituted with at least one or more hydrophilic moieties independently selected from alkoxy (preferably C1 -C3 alkoxy), polyoxyalkylene (preferably C1-C3 polyoxyalkylene), alkylamido, hydroxyalkyl, and alkylester In a preferred embodiment, the invention provides hair care compositions compπsing (a) from about 8 percent to about 20 percent by weight, based on the total weight of the hair care composition, of a first surfactant member selected from the group consisting of nonionic surfactants, semi-polar nonionic surfactants, amphoteric surfactants and mixtures thereof; (b) from about 0.5 percent to about 5 percent by weight, based on the total weight of the hair care composition, of a second surfactant member selected from the group consisting of cationic surfactants, fatty amine salts and mixtures thereof. Another preferred embodiment of the invention encompasses hair care compositions comprising: (a) from about 10 percent to about 16 percent by weight, based on the total weight of the hair care composition, of a first surfactant member selected from the group consisting of nonionic surfactants, semi-polar nonionic surfactants, amphoteric surfactants and mixtures thereof; (b) from about 1.0 percent to about 3.0 percent by weight, based on the total weight of the hair care composition, of a second surfactant member selected from the group consisting of cationic surfactants, fatty amine salts and mixtures thereof. The hair care compositions of the present invention optionally contain from about 0.001 percent to about 10 percent of optional ingredients selected from the group comprising anti- dandruff agents, fragrance oils, perfumes, coloring agents, dyes, sequestering agents, preservatives, pearlescent/suspending agents, thickener, viscosity modifiers, pH adjusting agents, gelling agents, opacifying agents, foam stabilizing auxiliary surfactants, silicone oils, non-volatile/nonionic silicone conditioning agents, vitamins, protein, sunscreen agents and mixtures thereof. BRIEF DESCRIPTION OF THE DRA WINCS Figure I is a scanning electron micrograph at 5000X magnification of normal hair treated two times with Formulation # 46. Figure II is a scanning electron micrograph at 5000X magnification of normal hair treated with a leading 2-in-l conditioning shampoo (Pert Plus Shampoo for Normal Hair). DETAILED DESCRIPTION OF THE INVENTION By isotropic liquid is meant an optically transparent solution that does not transmit visible light when viewed under a polaπzed light microscope Anisotropic liquid as used herein refers to opncally turbid solutions or dispersions that transmit visible light when viewed under a polaπzed light microscope Such solutions are idennfied as multiple Malthesan crosses It has been surpπsingly discovered that shampooing hair with the composinons descπbed above provides supeπor cleaning, foam generanon, conditioning, styling, setnng and curl retention properties to the hair in a single product appiicauon These compositions are substanually free of nonaqueous solvents (solvents other than water) and anionic surfactants Thus, the compositions of the present invention may contain minor amounts, I e , up to about 5% by weight of the composition, of nonaqueous solvents, such as alcohols, glycols, etc Such nonaqueous solvents are usually impuπties present the surfactant components or other components of the hair care compositions It is preferable to the maintain the level of nonaqueous solvents in the compositions below about 5 percent, based on the total amount of active components in the composition and preferably below 5 percent, based on the total weight of the composition Most preferably, the amount of nonaqueous solvents is less than about 2 percent, based on the total weight of the composition Hair care compositions of the present invennon have the desirable characteπsnc of allowing for restyling of the hair after application Dunng restyling, hair which has been previously treated with a hair care composition of the present invention is moistened with water, combed and allowed to air dry or is dried with a mechanical means, and the hair arranged and formed into a desired configuration Additionally, dunng restyling, hair which has been previously treated with a hair care composition of the present invention is moistened with water, opnonally combed, set on rollers, allowed to air dry or is dned with a mechanical means, the rollers are removed and the hair is combed out to achieve the desired hair style The hair care compositions of the present invention are three-in-one compositions which compπse nonionic, amphoteπc, canonic surfactants and/or fatty amine salts and mixtures thereof, styling aides in the form of anionic polymers and alkali metal salts thereof, swellable polymer thickening agents and other optional ingredients. Significantly, these composinon do not impaπ to the hair a sticky and/or heavily crusted feeling after application Without being bound by any pamcular theory, it is believed that the benefits provided by the present compositions are achieved by dispersing the styling and conditioning system, wherein the styling and conditioning system compπses fatty alkyl amine salts, long chain quaternary ammonium salts, and mixtures thereof, of anionic styling polymers, in the non-anionic surfactant(s). Again without being bound by any particularly theory, it is believed that the anionic styling polymers are completely solubilized as a fine dispersion in the aqueous non-anionic surfactant system and are generally electrolyπcally stable. An important discovery of the present invention resides in the stabilizanon and solubihzanon of the anionic polymer and catiomc surfactants or fatty amine salts by the use of non-ionic and amphoteπc surfactants in combination with swellable polymer thickening agents in the hair care composition, rather than the use of nonaqueous solvents to solubihze the hair styling polymer(s), as taught in the pnor art. In the compositions of the invention, the first surfactant member is present from about 2 percent to about 25 percent by weight, based on the total weight of the hair care composition; more preferably from about 8 percent to about 20 percent by weight, based on the total weight of the hair care composition The second surfactant member is present from about 0 5 percent to about 5.0 percent by weight, based on the total weight of the hair care composition, more preferably from about 1.0 percent to about 3.0 percent by weight, based on the total weight of the hair care composition. The anionic polymer is present from about 0.001 percent to about 5.0 percent by weight, based on the total weight of the hair care composition, more preferably from about 0.3 percent to about 2.0 percent by weight, based on the total weight of the hair care composition. The opnonal swellable polymer thickening agent is present from about 0.2 percent to about 3.0 percent by weight, based on the total weight of the hair care composition, more preferably from about 0.2 percent to about 2.0 percent by weight. Suitable swellable poiymer thickening agents include, for example, methyl cellulose, ethyl cellulose, xanthan gum, gum arabic, gum karaya, guar gum, locust bean gum, ghatti gum, hydrolyzed starches, low molecular weight ethylene oxide polymers, low molecular weight propylene oxide polymers and mixtures thereof The hair care compositions of the present invention can be made in the form of opaque structured liquids, pearlescent/opaque isotropic liquids and/or translucent/clear isotropic liquids These hair care compositions contain no anionic surfactants, solvents or canonic polymeπc condinoning agents Without being bound to any theory, it is believed that dispersed or solubilized amine salts and/or quaternary ammonium salts and solubilized anionic styling polymer acids or salts are present as separate ennties in a concentrated product Upon dilution and at typical use concentration, the viscosity of the system decreases and the rrucellar structure breaks thus releasing mobile surfactant monomers which interact with the anionic styling polymer to form a microfiber-hke styling/conditioning complex The complex appears as microfibers The complex is a fatty alkyl amine salt, a long chain quaternary ammonium salt, or mixtures thereof, of the anionic styling polymer Again without being bound by any particular theory, it is believed that the microfibers are positively charged fibπls or fibers possessing adhesion charactensucs allowing the microfibers to be attracted to the negatively charged surface of the hair The result is the formauon of a continuous film on the hair, providing both conditioning and styling properties If so desired, the compositions of the present invention may be removed from the hair by treanng the hair with a standard shampoo composition The composinons of the present invennon do not cause a build up of the aforementioned film on the hair after multiple application In a prefened embodiment of the present invention, the first surfactant member is a nonionic surfactant or an amphoteπc surfactant or a mixture thereof In such compositions, the first surfactant member is present from about 5% to about 25% by weight, based on the total weight of the hair care composition In a more prefened embodiment of the present invention, the first surfactant member is a nonionic surfactant or an amphotenc surfactant present from about 8% to about 20% by weight, based on the total weight of the hair care composition Nonionic surfactants Suitable nonionic surfactants in accordance with the present invennon are generally disclosed at column, 13 line 14 through column 16, line 6 of U S Patent No 3,929,678, the disclosure of which is incoφorated herein by reference in us entirety Generally, the nonionic surfactant is selected from the group compπsing polyoxyethyleneated alkylphenols polyoxyethyleneated straight chain alcohols, polyoxyethyleneated branched chain alcohols, polyoxyethyleneated polyoxypropylene glycols, polyoxyethyleneated mercaptans, fatty acid esters, glyceryl fatty acid esters, polyglyceryl fatty acid esters, propylene glycol esters, sorbitol esters, polyoxyethyleneated sorbitol esters, polyoxyethylene glycol esters, polyoxyethyleneated fatty acid esters, pπmary alkanolamides, ethoxylated pπmary alkanolamides, secondary alkanolamides, ethoxylated secondary alkanolamides, tertiary acetylenic glycols, polyoxyethyleneated silicones, N-alkylpyrrohdones, alkylpolyglycosides, alkylpolylsacchandes, EO-PO blockpolymers, polyhydroxy fatty acid amides, amine oxides and mixtures thereof Further, exemplary, non-limiting classes of useful nonionic surfactants are listed below 1 . The polyethylene, polypropylene, and polybutylene oxide condensates of alkyl phenols. In general, the polyethylene oxide condensates are preferred These compounds include the condensation products of alkyl phenols having an alkyl group containing from about 6 to 12 carbon atoms in either a straight or branched chain configuration with the alkylene oxide In a prefened embodiment, the ethylene oxide is present in an amount equal to from about 1 to about 25 moles of ethylene oxide per mole of alkyl phenol. Commercially available nonionic surfactants of this type include Igepal® CO-630, marketed by the GAF Coφoration; and Tnton® X-45, X-1 14, X-100 and X- 102, all marketed by the Rohm and Haas Company 2. The condensation products of aliphatic alcohols with from about 1 to about 25 moles of ethylene oxide The alkyl chain of the aliphatic alcohol can either be straight or branched, pπmary or secondary, and generally contain from about 8 to about 22 carbon atoms. Particularly prefened are the condensation products of alcohols having an alkyl group containing from about 6 to about 11 carbon atoms with from about 2 to about 10 moles of ethylene oxide per mole of alcohol Examples of commercially available nonionic surfactants of this type include Tergitol® 15-S-9 (the condensation products ol C1 1-C15 linear alcohol with 9 moles of ethylene oxide), Tergitol® 24-L-6 NMW (the condensation products of C j 2-C 14 pπmary alcohol with 6 moles ot ethylene oxide with a narrow molecular weight distπbution), both marketed by Union Carbide Corporaπon, Neodol® 91-8 (the condensation product of CQ-CI J linear alcohol with 8 moles of ethylene oxide), Neodol® 23-6.5 (the condensation product of C12-C13 linear alcohol with 6 5 moles of ethylene oxide), Neodol® 45-7 (the condensation product of C14-C15 linear alcohol with 7 moles of ethylene oxide), Neodol® 91-6 (the condensation product of C9-C11 linear alcohol with 6 moles of ethylene oxide), marketed by Shell Chemical Company, and Kyro® EOB (the condensation product of C13-C15 linear alcohol with 9 moles of ethylene oxide), marketed by the Procter and Gamble Company 3 The condensation products of ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol The hydrophobic portion of these compounds preferably has a molecular weight of from about 1500 to about 1880 and exhibits water insolubility The addition of polyoxyethylene moieties to this hydrophobic portion tends to increase the water solubility of the molecule as a whole, and the liquid character of the product is retained up to the point where the polyoxyethylene content is about 50% of the total weight of the condensation product, which corresponds to condensation with up to about 40 moles of ethylene oxide Examples of compounds of this type include certain of the commercially available Pluronic® surfactants, marketed by BASF 4 The condensanon products of ethylene oxide with the product resulnng from the reacnon of propylene oxide and ethylenediamine The hydrophobic moiety of these products consists of the reacnon product of ethylenediamine and excess propylene oxide, and generally has a molecular weight of from about 2500 to about 3000 This hydrophobic moiety is condensed with ethylene oxide to the extent that the condensanon product contains from about 40 % to about 80 % by weight ot polyoxyethylene and has a molecular weight of from about 5,000 to about 11 ,000 Examples of this type of nonionic surfactant include certain of the commercially available Tetronic® compounds, marketed by BASF 5 Semi-polar nonionic surfactants are a special category ot nonionic surfactants which include water-soluble amine oxides containing on alkyl moiety ot from about 10 to about 18 carbon atoms and 2 moieties selected from the group compπsing alkyl groups and hydroxyalkyl groups containing from about 1 to about 3 carbon atoms, and water-soluble sulfoxides containing alkyl moienes of from about 10 to about 18 carbon atoms and a moiety selected from the group compπsing alkyl groups and hydroxylalkyl groups of from about 1 to about 3 carbon atoms 6 Alkylpolysacchandes disclosed in U.S Pat No 4,565,647, Lenado, issued Jan 21, 1986, incoφorated herein by reference, having a hydrophobic group containing from about 6 to about 30 carbon atoms, preferably from about 10 to about 16 carbon atoms and a polysacchande, e.g., a polyglucoside, hydrophilic group containing from about 1.3 to about 10, preferably from about 1.3 to about 3, most preferably from about 1.3 to about 2.7 sacchaπde units Any reducing sacchaπde containing 5 or 6 carbon atoms can be used, e.g., glucose, galactose and galactosyl moienes can be subsntuted for the glucosyl moienes. (Optionally, the hydrophobic group is attached at the 2-, 3-, 4-, etc. positions thus giving a glucose or galactose as opposed to a glucoside or galactoside.) The intersacchande bonds can be, e.g., between the one position of the additional sacchaπde units and the 2-, 3-, 4-, and/or 6- positions on the preceding sacchaπde units. 7 An ethyl ester ethoxylate and/or alkoxylate such as those descπbed in U S Pat. No. 5,220,046, incorporated herein by reference These mateπal may be prepared according to the procedure set forth in Japanese Kokai patent application No. HEI 5 [1993]-222396. For example, they may be prepared by a one-step condensation reacnon between an alkyl ester and an alkylene oxide in the present of a catalyuc amount of magnesium together with another ion selected from the group of Al + -\ Ga +3 , In + -\ Co+ 3 , Sc+ 3 , La +3 and Mn +3 Optionally, and less desirably, there can be a polyalkyleneoxide chain joining the hydrophobic moiety and the polysacchande moiety The preferred alkyleneoxide is ethylene oxide. Typical hydrophobic groups include alkyl groups, either saturated or unsaturated, branched or unbranched, containing from about 8 to about 18, preferably from about 12 to about 14 carbon atoms; n is 2 or 3, preferably 2; t is from about 0 to about 10, preferably 0; and x is from about 1.3 to about 10, preferably from about 1.3 to 3, most preferably from about 1.3 to about 2.7. The glycosyl is preferably derived from glucose. To prepare these compounds, the alcohol or alkylpolyethoxy alcohol is formed first and then reacted with glucose, or a source of glucose, to form the glucoside (attachment at the 1-position). The additional glucosyl units can then be attached between their 1-position and the preceding glycosyl units 2-, 3-, 4- and/or 6-position, preferably predominately the 2-position. 8. Other nonionic surfactants include alkoxylated mono- and diglycerides of fatty acids. Preferred are ethoxylated and/or propoxylated glycerides of fatty acids having from 6-40 carbon atoms. Suitable alkoxylated mono- and diglycerides of such acids are commercially available from Witco Coφoration. Examples of such nonionic surfactants include Varonic LI-63 (PEG-30 Glyceryl Cocoate, Witco), Varonic LI-67 (PEG-80 Glyceryl Cocoate, Witco), Varonic LI-67, 75% (PEG-80 Glyceryl Cocoate, Witco), Varonic LI-42 (PEG-20 Glyceryl Tallowate, Witco), Varonic LI-48 (PEG-80 Glyceryl Tallowate, Witco), and Varonic LI-420, 70% (PEG-200 Glyceryl Tallowate, Witco). 9. Additional nonionic surfactants are alkoxylated alkyl esters of fatty acids. Preferred alkoxylated alkyl esters are ethoxylated and/or propoxylated methyl esters of fatty acids having from 8-40 carbon atoms. Suitable alkoxylated methyl esters of such acids are commercially available from Lion Coφoration. Examples of such nonionic surfactants include RCO 2 (CH 2 CH 2 O) π CH 3 where R is C 12 , and n is about 10.9 (commercially available from Lion Coφoration, Japan, as LC-1 10M), and RCO 2 (CH 2 CH 2 O) n CH 3 where R is C 12 , and n is about 14.6 (commercially available from Lion Coφortaion, Japan, as LC-150M-92). Amphoteric Surfactants Suitable amphoteric surfactants are selected from the group comprising alkyl glycinates, propionates, imidazolines, amphoalkylsulfonates sold as "Miranol"® by Rhone Poulenc, N- alkylaminopropionic acids, N-alkyliminodipropionic acids, imidazoline carboxylates, N- alkylbetaines, amido propyl betaines, sarcosinates, cocoamphocarboxyglycinates, amine oxides, sulfobetaines, sultaines and mixtures thereof Additional suitable amphoteπc surfactants include cocoamphoglycinate, cocoamphocarboxyglycinate, lauramphocarboxyglycinate, cocoamphopropionate, lauramphopropionate, stearamphoglycinate, cocoamphocarboxypropionate, tallowamphopropionate, tallowamphoglycinate, oleoamphoglycmate, caproamphoglycinate, caprylamphopropionate, caprylamphocarboxyglycinate, cocoyl imidazoline, lauryl imidazoline, stearyl imidazoline, behenyl imidazoline, behenylhydroxyethyl imidazoline, caprylamphopropylsulfonate, cocamphopropylsulfonate, stearamphopropylsolfonate, oleoamphopropylsulfonate and the like Amine Oxide Surfactants Amine oxide surfactants which are generally suitable for use in the present mvenuon are alkylamine and amidoamine oxides Examples of betaines and sultaines which are suitable for use in the present invention are alkyl betaines and sultaines sold as "Mirataine"® by Rhone Poulenc , "Lonzaine"® by Lonza, Ine , Fairlawn, N J Examples of betaines and sultaines are cocobetaine, cocoamidoethyl betaine, cocoamidopropyl betaine, lauryl betaine, lauramidopropyl betaine, palmamidopropyl betaine, stearamidopropyl betaine, stearyl betaine, coco-sultaine, lauryl sultaine, tallowarmdopropyl hydroxysultaine and the like. Canonic Surfactants In a prefened embodiment of the present invennon, the canonic surfactant, the fatty amine salt or a mixture thereof is present from about 0 5 percent to about 5 0 percent, based on the total weight of the hair care composition In a more prefened embodiment of the present invennon, the canonic surfactant, the fatty amine salt or a mixture thereof is present from about 1 0 percent to about 3 0 percent, based on the total weight of the hair care composinon Generally, the cationic surfactant is a surfactant selected from the group compπsing fatty amine salts, fatty diamine salts, polyamine salts, quaternary ammonium compounds, polyoxyethyleneated fatty amines, quatermzed polyoxyethyleneated fatty amines, amine oxides and mixtures thereof A vaπety of canonic surfactants useful as detersive surfactants and as conditioning agents are well know in the art These mateπals contain amino or quaternary ammonium hydrophilic moienes which are positively charged when dissolved in the composiuons of the present mvenuon Whether the cationic surfactant functions as a detersive surfactant or as a conditioning agent, or both, will depend upon the particular compound as is well understood by those skilled in the art In general, compounds with longer chain length moieties attached to the canonic nitrogen tend to exhibit greater conditioning benefits Cauonic surfactants among those useful herein are disclosed in the following documents, all incoφorated by reference herein M C Publishing Co , McCutcheon' s Detergents & Emulsifiers, (North Amencan Ed , 1993), Schwartz et al , Surface Active Agents, Their Cliemistry and Technology, New York, Interscience Publisher, 1949, U S. Pat No. 3,155,591, Hilfer, issued Nov 3, 1964, U S Pat No 3,929,678, Laughlin et al , issued Dec 30, 1975, U S Pat No 3,959,461, Bailey et al , issued May 25, 1976, and U.S Pat No 4,387,090, Bolich, Jr , issued June 7, 1983 Canonic surfactants in the form of quaternary ammonium salts include dialkyldiethyl ammonium chlondes and tnalkyl methyl ammonium chlondes, wherein the alkyl groups have from about 12 to about 22 carbon atoms and are deπved from long-chain fatty acids, such as hydrogenated tallow fatty acid (tallow fatty acids yield quaternary compounds wherein Ri and RT have predominately from about 16 to about 18 carbon atoms) These types of canonic surfactants are useful as hair conditioning agents Examples of quaternary ammonium salts useful herein include ditallowdimethyl ammonium chloπde, ditallowdimethyl ammonium methyl sulfate, dihexadecyl dimethyl ammonium chloπde, dι-(hydrogenated tallow) dimethyl ammonium chloπde, dioctadecyl dimethyl ammonium chloπde, dieicosyl dimethyl ammonium chloπde, didocosyl dimethyl ammonium chloπde, dι-(hydrogenated tallow) dimethyl ammonium acetate, dihexadecyl dimethyl ammonium chloπde, dihexadecyl dimethyol ammonium acetate, ditallow dipropyl ammonium phosphate, ditallow dimethyl ammonium nitrate, dι-(coconutalkyl) dimethyl ammonium chloπde, and stearyl dimethyl benzyl ammonium chloπde Ditallow dimethyl ammonium chloπde, dicetyl dimethyl ammonium chloπde, stearyl dimethyl benzyl ammonium chloride and cetyl tπmethyl ammonium chloride are prefened quaternary ammonium salts useful herein. Dι-(hydrogenated tallow) dimethyl ammonium chlonde and tπcetyl methyl ammomum chloπde are particularly prefened quaternary ammonium salts Preferred ot the conventional canonic conditioning agents are cetyl tnmethyl ammonium chloπde, lauryl tnmethyl ammonium chloπde, tπcetyl methyl ammonium chloπde, stearyldimethyl benzyl ammonium chloπde, and di- (pamally hydrogenated tallow)dιmethyl ammonium chlonde, these matenals may also provide anu-static benefits to the present compositions Salts of pπmary, secondary and tertiary fatty amines are also suitable canonic surfactant matenals The alkyl groups of such amines preferably have from about 12 to about 22 carbon atoms, and may be substituted or unsubstituted Secondary and ternary amines are prefened, ternary amines are particularly prefened. Such amines, useful herein, include stearamido propyl dimethyl amine, diethyl amino ethyl stearamide, dimethyl stearamine, dimethyl soyamine, soyamine, myπstyl amine, tπdecyl amine, ethyl stearylamine, N-tallowpropane diamine, ethoxylated (5 moles E O ) stearylamine, dihydroxy ethyl stearylamine, and arachidylbehenylamine Suitable amine salts include the halogen, acetate, phosphate, nitrate, citrate, lactate and alkyl sulfate salts Such salts include stearylamine hydrogen chlonde, soyamine chloπde, stearylamine formate, N-tallowpropane diamine dichloπde and stearamidopropyl dimethylamine citrate Canonic amine surfactants included among those useful in the present invention are disclosed in U S Pat No 4,275,055, Nachtigal, et al , issued June 23, 1981, incoφorated herein by reference Canonic surfactants which are especially useful in compositions of the present invention are quaternary ammonium or amino compounds having at least one N-radical containing one or more nonionic hydrophilic moieties selected from the group compπsing alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, and alkylester moieties, and combinations thereof The compounds contain at least one hydrophilic moiety within 4, preferably within 3, carbon atoms (inclusive) of the quaternary nitrogen or canonic amino nitrogen Additionally, carbon atoms that are part of a hydrophilic moiety, e g , carbon atoms in a hydrophilic polyoxyalkylene (e g ,-CH2-CH2-O-), tiiat are adjacent to other hydrophilic moieties are not counted when determining the number of hydrophilic moieties within 4, or preferably 3, carbon atoms of the canonic nitrogen In general, the alkyl portion of any hydrophilic moiety is preferably a C1-C3 alkyl Suitable hydrophile- containmg radicals include, for example, ethoxy, propoxy, polyoxyethylene, polyoxypropylene, ethylamido, propylamido, hydroxymethyl, hydroxyethyl, hydroxypropyl, methyl ester, ethyl ester, propyl ester, or mixtures thereof, as nonionic hydrophile moieties The compounds must be positively charged at the pH of the shampoo compositions. Generally, the pH of the shampoo composiuons will be less than about 10, typically from about 3 to about 9 Among the cationic surfactants useful herein are those of the general formula wherein R] , R2, R3, and R4 independently represent hydrocarbyl chains of from about 1 to about 30 carbon atoms, or hydrocarbyl chain having from about 1 to about 30 carbon atoms and opnonally containing one or more aromatic, ether, ester, amido, or amino moieties present as subsntuients or as linkages in the hydrocarbyl chain, where at least one of the R 1-R4 groups is optionally substituted with at least one or more hydrophilic moieties independently selected from alkoxy (preferably C \ - C3 alkoxy), polyoxyalkylene (preferably Q-C3 polyoxyalkylene), alkylamido, hydroxyalkyl, and alkylester; and X is a soluble salt forming anion. Preferably X is selected from the group comprising halogens (especially chloπne), acetate, phosphate, nitrate, sulfonate, and alkyl sulfate radicals Preferably, the canonic conditioning surfactant contains from about 2 to about 10 nonionic hydrophile moieties located within the above stated ranges. For puφoses herein, each hydrophilic amido, alkoxy, hydroxyalkyl, alkylester, alkylamido or other unit is considered to be a distinct nonionic hydrophile moiety. . Prefened cationic surfactants include polyoxyethylene (2) stearyl methyl ammonium chloride, methyl bιs-(hydrogenated tallowamidoethyl) 2-hydroxyethyl ammonium methyl sulfate, polyoxypropylene (9) diethyl methyl ammonium chlonde, tnpolyoxyethylene (total PEG- 10) stearyl ammonium phosphate, bis-(N-hydroxyethyl-2-oleyl imidazolinium chloπde) polyethylene glycol (1), and isododecylbenzyl triethanolammomum chloπde Other ammonium quaternary and amino compounds include those of the above general formula in the form of nng structures formed by covalently linking two of R 1 -R4 groups Examples include imidazolines, lmidazohniums, and pyπdiniums, etc., wherein said compound has at least one nonionic hydrophile-contaimng radical as set forth above Specific examples include 2-heptadecyl-4,5-dihydro- 1 H-imidazol- 1 -ethanol, 4,5-dιhydro- 1 -(2-hydroxyethyl)-2- isoheptadecyl-1-phenylmethylimidazolium chloride, and l-[2-oxo-2-[[2-[(l- oxoctadecyl)oxyJethylJamino)ethyl] pyridinium chloride. Salts of primary, secondary and tertiary fatty amines are also preferred canonic surfactant materials. The alkyl groups of such amines preferably have from about 1 to about 30 carbon atoms and must contain at least one, preferably about 2 to about 10, nonionic hydrophilic moieties selected from the group comprising alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, and alkylester groups, and mixtures thereof. Secondary and tertiary amines are prefened, tertiary amines are particularly preferred. Specific examples of suitable amines include diethyl aminoethyl polyoxyethylene (5) laurate, coco-polyglyceryl (4) hydroxypropyl dihydroxy ethylamine and dihyroxyethyl tallowamine hydrochloride. The pH of the present compositions is not generally cπtical and may be in the range of from about 2 to about 10, preferably from about 3 to about 9, more preferably from about 4 to about 8. Thus, it is believed that the pH does not affect the interaction of the canonic conditioning agent and the anionic polymer. In a prefened embodiment of the present invention, the anionic polymer is present from about 0.001 percent to about 5.0 percent, based on the total weight of the hair care composition. In a more prefened embodiment of the present invention, the amomc polymer is present from about 0.3 percent to about 2.0 percent, based on the total weight of the hair care composition. In general, the anionic polymer compnses a polymer with one or more carboxylic acid groups, one or more carboxylic acid alkali metal salt groups, one or more sulfate groups, one or more sulfonate groups and mixtures thereof. Thus, the anionic polymer is a polymer selected from, but not limited to, the group compnsmg polymenc condensation products of methyl vinyl ether and maleic anhydride and salts, half acid esters and half acid amides thereof, salts of the half acid ester and/or half amide ester of the copolymenc condensation products of methyl vinyl ether and maleic anhydride, sodium salts of teφolymers of octyl acrylamide, polymenc condensation products of acrylate esters and butylammoethyl methacrylate, acrylic acid polymers cross-linked with a polyfuncnonal agent and mixtures thereof The polyfunctional agent is an agent selected from, but not limited to, the group comprising a polyol, a polyamine, carboxymethyl cellulose and mixtures thereof Addmonally, the anionic polymer member may contain at least one carboxylic acid group, or at least one sulfate group, or at least one sulfonate group, or a mixture thereof, and is the product of a radical polymeπzation reaction of an ethylenically unsaturated monomer In a prefened embodiment of the present invention, the swellable polymer thickening agent is present from about 0 2 percent to about 3 0 percent, based on the total weight of the hair care composition In a more prefened embodiment of the present invention, the swellable polymer thickening agent is present from about 0 2 percent to about 2 0 percent, based on the total weight of the hair care composition The swellable polymer thickening agent is an agent selected from the group compπsing methyl cellulose, ethyl cellulose, xanthan gum, gum arabic, gum karaya, guar gum, locust bean gum, ghatti gum, hydrolyzed starches, low molecular weight ethylene oxide polymers, low molecular weight propylene oxide polymers and mixtures thereof The opnonal ingredients in accordance with the present invention are selected from the group compnsmg ann-dandruff agents, fragrance oils, perfumes, colonng agents, dyes, sequestenng agents, preservatives, pearlescent/suspending agents, thickeners, viscosity modifiers, pH adjusnng agents, gelling agents, opacifying agents, foam stabilizing auxiliary surfactants, silicone oils, nonvolanle/noniomc silicone conditioning agents, vitamins, protein, sunscreen agents and mixtures thereof This list of optional ingredients is not meant to be exclusive, and other opnonal components can be utilized These opnonal ingredients generally are used individually at a level of from about 0 001 % to about 10 %, most commonly from about 0 5 to about 5 % by weight of the composition Suitable anti-dandruff agents are selected from the group compπsing zmc pyπthione, selenium sulfide, sulfur, coal tar, zinc omadine, piroctone olamme and mixtures thereof Suitable preservaπves are selected from the group compnsmg benzyl alcohol, methyl paraben, propyl paraben and lmidazohdinyl urea Suitable thickeners and viscosity modifiers are selected from the group compπsing diethanolamides of long chain fatty acids (e g , PEG-3 lauramide), block polymers of ethylene oxide and propylene oxide such as Pluromc® F88 offered by BASF, Wyandotte, sodium chloπde, sodium sulfate, ammonium xylene sulfonate, ethyl alcohol and poiyhydπdic alcohols such as, for example, propylene glycol and polyvinyl alcohol Suitable gelling agents include, for example, hydroxyethyl cellulose Suitable pH adjusting agents are selected from the group compπsing citπc acid, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate, etc Suitable sequestenng agents include, for example, disodium ethylenediamine tetraacetate Suitable foam stabilizing auxiliary surfactants include, for example, amides, amine oxides, betaines, sultaines and Cg-Cjg fatty alcohols Amine oxides useful as foam stabilizing auxiliary surfactants in the present invention include long-chain amine oxides, I e , those compounds having the general formula O R 3 (R 4 0) x t N± (R 5 )2 wherein R3 is selected from an alkyl, hydroxyalkyl, acylamidopropyl and alkyl phenyl group, or mixtures thereof, containing from about 8 - 26 carbon atoms, preferably from about 8 - 16 carbon atoms; R4 is an alkylene or hydroxyalkylene group containing from about 2 -3 carbon atoms, preferably 2 carbon atoms, or mixtures thereof, x is from about 0 -3, preferably 0, and each R5 is an alkyl or hydroxyalkyl group containing from about 1 -3, preferably from about 1 - 2 carbon atoms, or a polyethylene oxide group containing from about 1 - 3, preferably 1 , ethylene oxide groups The R5 groups can optionally be attached to each other, e g , through an oxygen or nitrogen atom, to form a πng structure These foam stabilizing amine oxide auxiliary surfactants in particular include CiQ-Cj g alkyl dimethyl amine oxides and Cg-Ci 2 alkoxy ethyl dihydroxyethyl amine oxides Examples of such matenals include dimethyloctylamine oxide, diethyldodecylamine oxide, bιs- ( 2 hydroxyethyl)dodecylamιne oxide, dimethyldodecylamine oxide, dodecylamidopropyl .11. dimethylamine oxide and dimethyl-2-hydroxyoctadecylamine oxide. Prefened are C]()-Cig alkyl dimethylamine oxide, and CIQ-C ] g acylamido alkyl dimethylamine oxide. Betaines The betaines useful as foam stabilizing auxiliary surfactants in the present invention include compounds having the formula R(R j )2N + R2COO" wherein R is a C -Ci g hydrocarbyl group, preferably Ci()-Ci 6 alkyl group, each R ] is typically C1 -C3, alkyl, preferably methyl, and R2 is a C1-C5 hydrocarbyl group, preferably a C1 -C5 alkylene group, more preferably a C\- C2 alkylene group. Examples of suitable betaines include coconut acylamidopropyldimethyl betaine; hexadecyl dimethyl betaine; C j 2-C j 4 acylamidopropylbetaine; Cg-Cj4 acylamidohexyldiethyl betaine; 4-[C j 4-Ci6 acylmethylamidodiethylammonioj-l-carboxybutane; Cl6"Ci8 acylamidododimethylbetaine; C^-Cjg acylamidopentanediethylbetaine; C12-C16 acylmethylamidodimethylbetaine. Prefened betaines are C12-C18 dimethylamoniohexanoate and the CI Q-CI g acylamidopropane (or ethane) dimethyl (or diethyl) betaines. Sultaines The sultaines useful as foam stabilizing auxiliary surfactants in the present invention include compounds having the formula R(R i)2N + R2SO3", wherein R is a 0,-Cι g hydrocarbyl group, preferably a CIQ-CJO alkyl group, more preferably a C12-C13 alkyl group; each Ri is typically C1-C3 alkyl, preferably methyl and R2 is a C\-C^ hydrocabyl group, preferably a Cj- C3 alkylene or, preferably, hydroxyalkylene group. Examples of suitable sultaines are Q2-C14 dihydroxyethylammino propane sulfonate, and Cig-C j g dimethylammonio hexane sulfonate, with C12-C14 amido propyl ammonio-2-hydroxypropyl sultaine being prefened. Optional components The auxiliary foam stabilizing surfactant may also be a fatty acid amide surfactant. Preferred amides are Cg-C2ø alkanol amides, monoethanolamides, diethanolamides and isopropanolamides. A particularly prefened amide is a mixture of myristic monoethaolamide and lauric monoethanolamide. This prefened amide is sold by Stepan Company, Northfield, Illinois as Ninol® LMP. Optional non-volatile, nonionic silicone conditioning agents suitable for the present invention are selected from the group comprising polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers and mixtures thereof However, it should also be noted that any silicone fluid having hair conditioning properties may used as an opuonal ingredient in the present Compositions The nonvolatile polyalkyl siloxane fluids that may be used include, for example, polydimethylsiloxanes, available , for example, from General Electnc Company as SF 1075 methyl phenyl fluid or from Dow Corning as 556 Cosmenc Grade Fluid. The polyether siloxane copolymers that may be used include, for example, a polypropylene oxide modified dimethylpolystloxane (E.g., Dow Corning DC-1248) although ethylene oxide or mixtures of ethylene oxide and propylene oxide may also be used. Optional silicone fluids hereof also include polyalkyl or polyaryl siloxanes with the following general formula: wherein R is alkyl or aryl, and x is an integer form about 7 to about 8,000 "A" represents groups which block the ends of the silicone chains The alkyl or aryl groups substituted on the siloxane chain or at the ends of the siloxane chains (A) may have any structure as long as the resulting silicones remain fluid at room temperature, are hydrophobic, are neither lmtatmg, toxic nor otherwise harmful when applied to the hair, are compatible with the other components of the present compositions, are chemically stable under normal use and storage conditions, and are capable of being opnonally deposited on and of optionally conditioning the hair Suitable A groups include methyl, methoxy, ethoxy, propoxy, and aryloxy The two R groups on the silicone atom may represent the same or different groups Preferably, the two R groups represent the same group. Suitable R groups include, for example, methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl The prefened silicones are polydiemethyl siloxane, polydiethyl siloxane and polymethylphenyl siloxane Polydiemethyl siloxane is especially prefened The optional pearlescent/suspending agents suitable for use in the present invention include any of several long chain acyl deπvative matenals or mixtures of such matenals, such as long chain acyl deπvatives, long chain amine oxides, and mixtures thereof, wherein such suspending/pearlescent agents are present in the composition in crystalline form These pearlescent/suspending agents are descπbed in U S Pat No 4,741 ,855, Grote and Russell, issued May 3, 1988, the disclosure of which is incoφorated herein by reference in its entirety Included are ethylene glycol esters of fatty acids having from about 16 to about 22 carbon atoms Prefened are the ethylene glycol stearates, both mono- and distearate, but particularly the distearate containing less than about 7 % of the monostearate Other suspending agents found useful are alkanolamides, preferably with about 16 to about 18 carbon atoms Prefened alkanolamides are steaπc monoethanolamide, steanc diethanolamine, steanc monoisopropanolamide and steanc monoethanolamide stearate Other long chain acyl deπvatives include long chain esters of long chain fatty acids (e g , stearyl stearate, cetyl palmitate, etc ). glyceryl esters (e.g., glyceryl distearate) and long chain ester of long chain alkanol amides (e g , stearamide DEA distearate, stearamide MEA stearate). Additional optional pearlescent/suspending agents suitable for use in the present invention arc alkyl (Ct g-C22) dimethyl amine oxides, such as stearyl dimethyl amine oxide If the compositions contain an amine oxide or a long chain acyl denvative as a surfactant the pearlescent/suspending function could also be provided by such surfactant and addiuonal pearlescent/suspending agents may not be needed Further opnonal pearlescent/suspending agents that can be used are long chain acyl denvatives, including, for example, N,N-dιhydroxycarbyl amido benzoic acid and soluble thereof (e.g., Na and K salts), particularly N,N-dι(hydrogenated) C j ^, Qg and tallow amido benzoic acid species of this family, which are commercially available from Stepan Company (Northfield, Illinois, USA) Another type of pearlescent/suspending agent which can be used in the present invention is xanthan gum Xanthan gum is well known to those skilled in the art For example, hair care compositions utilizing xanthan gum as a pearlescent/suspending agent for the silicone hair conditioning component are described in U.S Pat No 4,788,066, Bolich and Williams, issued Nov 29, 1988, the disclosure of which is incoφorated herein by reference in its entirety See also, Whistler, Roy L Editor Industrial Gums - Polysacchaπdes and Their Deπvatives, New York: Academic Press, 1973 Xanthan gum is commercially available from Kelco, a division of Merck & Co., Ine as Keltrol. Combinations of long chain acyl denvatives and xanthan gum are disclosed as pearlescent/suspending agents for silicone hair conditioners in U.S Pat No 4,704,272, Oh et al., issued Nov 3, 1987, both of which are incoφorated herein by referencein their entirety, and may also be used in the present compositions. Gel formulauons have high levels of pearlescent/suspending agents relauve to pourable, liquid formulauons which used as the pπmary means of impairing the gel-like viscosity to the composinon. Opnonal gelling agents suitable for use in the present invention include, for example, hydroxy ethylcellulose. While compositions of the present invention have been disclosed for used in hair care applications, other applications for these compositions are possible The compositions of the present invennon may be useable in or as liquid dish washing compositions, hand soaps, muln- puφose cleaners, body washes, laundry detergent compositions, textile treatment compositions, etc. All documents, e g , patents and journal articles, cited above or below are hereby incoφorated by reference in their entirety In the following examples, all amounts are stated in percent by weight of active matenal unless indicated otherwise. One skilled in the art will recognize that modifications may be made in the present invention without deviating from the spmt or scope of the invention The invention is illustrated further by the following examples which are not to be construed as limiung the mvennon or scope of the specific procedures or compositions descnbed herein The definitions and CTFA designations used in the present invention are as follows Methocel J75MS hydroxypropyl methylcellulose Keltrol RD xanthan gum Gantrez AN179 poly(methyl vinyl ether/maleic anhydπde) (PVM/MA) copolymer Ammonyx CETAC cetyl tnmethyl ammonium chlonde Amphosol SB or SBG cocoamidopropyl hydroxysultaine Amphosol CA cocoamidopropyl betaine KESSCO EGDS ethyleneglycol distearate KESSCO EGMS ethyleneglycol monostearate Glydant dimethyl dimethyl (DMDM) hydantoin Ammonyx 4 stearylalkonium chloπde Ammonyx GA70 PG dipalrrutoylethyl hydroxyethylammomum methosulfate Ammonyx D34 dicetyldimomum chloπde Ammonyx KP olealkonium chloπde Amphomer octylacrylamide/acrylates/butylaminoethyl methacrylates copolymer Carbopol ETD2001 car bomer 2001 Luvimer 100P acrylates copolymer Plantaran 2000 decyl polyglucoside Ammonyx LO lauramine oxide Stepanol AM ammonium lauryl sulfate Lexamine S-13 stearamidopropyl dimethylamine Armeen 18D stearamine Armeen OD oleamine Armeen 2HT dihydrogenated tallow amine Ninol LMP lauπc/myπstic monoethanolamide LA 150M C12 with 14 6 moles ethoxylated methyl ester (Lion Coφ , Japan) LC 1 10M C12 with 10.8 moles ethoxylated methyl ester (Lion Coφ., Japan) Neodol 91-8 Co, and Ci i ethoxylated fatty alcohol with 8 moles ethylene oxide (Shell Chemical Company) DDABDT dodecyl dimethylaminobenzezmide propyldimethylammomum tosylate (ISP) Example I Method of Preparation #1 (Formulations 2 and 3) A suitable vessel equipped with a means for mixing, a means for heating, and a means for cooling is sequenually charged with deionized water and Keltrol RD. These ingredients are mixed to produce a homogeneous dispersion The contents of the vessel are heated to 70°C The combined ingredients are mixed to produce a homogeneous solution Next, Gantrez AN 179 solution is added followed by the addition of the AMMONYX CETAC, AMPHOSOL SB or SBG, AMPHOSOL CA, KESSCO EGDS, or KESSCO EGMS The resulting combinauon of ingredients is mixed for 10-15 minutes. The mixture is cooled to 40°C and the Glydant added. The pH of the mixture is adjusted to 4.0 - 7 5 and mixture cooled to ambient temperature Preferred Method of Preparation #2 (Formulation 1) A suitable vessel equipped with a means for mixing and a means for cooling is sequennally charged with deionized water and Keltrol RD. These ingredients are mixed to produce a homogeneous dispersion. The combined ingredients are mixed to produce a homogeneous solution. Next, Gantrez AN 179 solution is added followed by the addition of the AMPHOSOL SB or SBG, AMPHOSOL CA, and AMMONYX CETAC. The resulnng combinauon of ingredients is mixed for 10-15 minutes and the Glydant is added. The pH of the final mixture is adjusted to 4 0 - 7.5. Preferred Method of Preparation #3 A suitable vessel equipped with a means for mixing, a means for heating, and a means for cooling is sequennally charged with deionized water and Keltrol RD. These ingredients are mixed to produce a homogeneous dispersion. The contents of the vessel are heated to 70°C The combined ingredients are mixed to produce a homogeneous solution Next, Gantrez AN 179 solution is added followed by the addition of the AMPHOSOL SB or SBG and AMPHOSOL CA, AMMONYX CETAC, KESSCO EGDS or KESSCO EGMS. The resulting combinauon of ingredients is mixed for 10-15 minutes. The mixture is cooled to ambient temperature and the Glydant added. The pH of the final mixture is adjusted to 4 0 - 6.5. Example 2 Preparation of Cant res AN179 Solution A suitable vessel equipped with a means for mixing, a means for heating, and a means for cooling is charged with deionized water and heated to 80°C. Gantrez AN 179 powder is added and the resulting mixture agitated for 30 minutes or until a clear, homogeneous solution is foπned. The mixtures is finally cooled to ambient temperature Isolation of Styling/Conditioπin-? Agents A suitable vessel equipped with a means for mixing is sequennally charged with 400 ml of water, 5 g of formulation 1 (other formulations may be substituted) and the resulting mixture stirred for 2 minutes Dunng this peπod of time, the fibnls are released into the solution and were be isolated by filtraπon using filter paper Example 3 Method for Re-Stvlin ? the Hair #1 Hair that has been previously treated with a hair care composition of the present invention (I e. formulations 1 , 2 and 3) is wetted with water The hair is combed and allowed to air dry or is dned with a mechanical means Method for Re-Styling the Hair #2 Hair that has been previously treated with a hair care composition of the present invention (i.e. formulations 1, 2 and 3) is wetted with water The hair is combed, set on rollers, allowed to air dry or is dned with a mechanical means, the rollers are removed and the hair is combed out to achieve the desired hair style Example 4 The following formulations were prepared according to the according to the methods set forth above. FORMULATION 1 2 3 wt. % (as is) wt. % (as is) wt. % (as is) 1. D.I. Water Q.S. to 100.0 Q.S. lo 100.0 Q.S. to 100.0 2. Keltrol RD 1.0 1.0 1.0 3. Gantrez AN 179 (5%) 8.00 8.00 8.00 4. AMMONYX® CETAC (30%) 5.80 5.80 5.80 5. AMPHOSOL® SB or SBG (50%) 24.00 24.00 24.00 6. AMPHOSOL® CA (30%) 10.00 10.00 10.00 7. KESSCO® EGDS — 2.00 — 8. KESSCO® EGMS — — 2.00 9. Glydant 0.25 0.25 0.25 Conditioning Effect on hair Excellent Excellent Excellent Styling/Setling/Body/Stiffness on hair Excellent Excellent Excellent pH 5.6 5.6 5.6 Appearance Translucent Opaque Pearlescent opaque Dispersion type Isotropic liquid Anisotropic Isotropic liquid liquid rORiYHJLATIQN 4 5 6 7 wt. % (as is) wt. % (as is) wt. % (as is) wi. % (as is) 1. D.I. Water Q.S. to 100.0 Q.S. to 100.0 Q.S. to 100.0 Q.S. to 100.0 2. Methocel J75MS 0.75 0.75 0.75 0.75 3. Keltrol RD 0.40 0.40 0.40 0.40 4. NaOH 50% 0.05 0.05 0.05 0.05 5. Gantrez AN 179 (5%) 8.00 8.00 8.00 8.00 6. AMMONYX® 4 (18%) 9.70 — — 7. AMMONYX® GA70 PG (70%) 2.50 8. AMMONYX® D34 (68%) — — 2.56 9. AMMONYX® KP (50%) 3.48 10. AMPHOSOL®SB or SBG (50%) 24.00 24.00 24.00 24.00 11. AMPHOSOL® CA (30%) 10.00 10.00 10.00 10.00 10. KESSCO® EGMS 2.00 2.00 2.00 2.00 11. Glydant 0.25 0.25 0.25 0.25 Conditioning Effect on hair Excellent Excellent Excellent Excellent S tyling/S etung/Bod y /S ti f f ness Excellent Excellent Excellent Excellent on hair pH 5.6 4.0 5.6 5.6 Appearance Opaque Opaque Opaque Opaque Pearlcsccnt Pearlescent Pearlescent Pearlescent Dispersion type Isotropic liquid Isotropic liquid Isotropic liquid Isotropic liquid FORM ULATI ON 8 9 10 1 1 wt. % (as is) wt. % (as is) wt. % (as is) wt. % (as is) 1. D.I. Water Q.S. to 100.0 Q.S . to 100.0 Q.S . to 100 0 Q.S . to 100 0 2. Mcthocel J75MS 0.75 0.75 0.75 0.75 3. Keltrol RD 0.40 0.40 0.40 0.40 4. NaOH 50% 0.05 0.05 0.05 0.05 5. Gantrez AN 179 (5%) 8.00 8.00 8.00 8.00 6. Lexamine S-13 1 .75 7. Armeen 18D 1.75 8. Armeen OD 1.75 9. Armeen 2HT -- — — 1 .75 10. AMPHOSOL® SB or SBG 24.00 24.00 24.00 24.00 (50%) 11. AMPHOSOL® CA (30%) 10.00 10.00 10.00 10.00 10. KESSCO® EGMS 2.00 2.00 2.00 2.00 11. Glydant 0.25 0.25 0.25 0.25 Condiuoning Effect on hair Excellent Excellent Excellent Excellent Styling/Setting/Body/Stiffness Excellent Excellent Good Good on hair pH 5.6 5.6 5.6 5.6 Appearance Opaque Opaque Opaque Opaque Pearlescent Pcarlesceni Pearlescent Pearlescent Dispersion type Isotropic liquid Isotropic liquid Isotropic liquid Isotropic liquid FORMULATION (all components by Weight %, as is) 12 13 14) 15 16 1. D.I. Water Q.S. to 100.0 Q.S. to 100.0 Q.S. to 100.0 Q.S. to 100.0 Q.S. to 100.0 2. Methocel J75MS 0.75 0.75 0.75 0.75 0.75 3. Keltrol RD 0.40 0.40 0.40 0.40 0.40 4. NaOH 50% 0.05 0.05 0.05 0.05 0.05 5. Gantrez AN119 (5%) 8.00 6. Gantrez AN903 (5%) 8.00 7. Amphomer (5%) 8.00 8. Carbopol ETD2001 (2%) 20.00 9. Luvimer 100P (5%) 8.00 10. AMMONYX® CETAC 5.80 5.80 (30%) 5.80 5.80 5.80 11. AMPHOSOL® SB 24.00 or SBG (50%) 24.00 24.00 24.00 24.00 12. AMPHOSOL® 10.00 CA (30%) 10.00 10.00 10.00 10.00 13. KESSCO® EGDS 2.00 2.00 2.00 2.00 2.00 14. Glydant 0.25 0.25 0.25 0.25 0.25 Conditioning Effect on hair Excellent Excellent Good Good Good Styling/Setting/Body/ Excellent Excellent Good Good Fair Stiffness on hair pH 5.6 5.6 5.6 5.6 5.6 Appearance Opaque Opaque Opaque Opaque Opaque Pearlescent Pearlescent Pearlescent Peariescent Pearlesceni FORMULATION (all componenis by Weight %, as is) 17* 1 8 19 20 1. D.I. Water Q.S. to Q.S. to Q.S. to Q.S . to 100.0 100.0 100.0 100.0 2. Keltrol RD 1 .0 1 .0 1 .0 1 .0 3. AMPHOSOL® SB (50%) 24.0 24.0 24.0 24.0 4. AMPHOSOL® CA (30%) 10.0 10.0 10.0 10.0 5. Gantrez AN 179 (5%) — 5.00 8.00 8.00 6. AMMONYX® CETAC (30%) 5.0 6.67 3.33 Molar Ratio of Gantrez AN179 to — 2: 1 2.7 : 1 1 .3 AMMONYX GA70 PG Conditioning Effect on hair Very poor Excellent Excellent Good Styling/Setting/Body/Stiffness Very poor Excellent Excellent Good on hair PH 4.5 4.5 4.5 4.5 Appearance Translucent Translucent Translucent Translucent *No styling/conditioning complex FORMULATION 21 22 23 24 25 vt. % (as is) wt. % (as is) wt. % (as is) wt. % (as IS) wt. % (as is) 1. D.I. Water '.S. to 100.0 Q.S . to 100.0 Q.S . to 100.0 Q.S . to 100.0 Q.S . to 100.0 2. Methocel J75MS 0.75 0.75 0.75 0.75 0.75 3. Keltrol RD 0.40 0.40 0.40 0.40 0.40 4. NaOH 50% 0.05 0.05 0.05 0.05 0.05 5. Gantrez AN 179 (5%) 1.0 2.0 3.0 6.0 8.0 6. AMMONYX® CETAC 5.80 5.80 5.80 5.80 5.80 (30%) 7. AMPHOSOL® SB or SBG 24.00 24.00 24.00 24.00 24.00 (50%) 8. AMPHOSOL® CA (30%) 10.00 10.00 10.00 10.00 10.00 9. KESSCO® EGDS 2.00 2.00 2.00 2.00 2.00 10. Glydant 0.25 0.25 0.25 0.25 0.25 Conditioning Effect on hair Excellent Excellent Excellent Excellent Excellent Styling/SetUng/Body/Stiffness Poor Fair Good VERY Good Excellent on hair PH 5.6 5.6 5.6 5.6 5.6 Appearance Opaque Opaque Opaque Opaque Opaque Pearlescent Pearlescent Pearlescent Pearlescent Pearlescent FORMULATION (all components by Weight %, as ISI 26 27 28 29 30 31 1. D.I. Water Q.S. to 100.0 2. Methocel J75MS 0.75 0.75 0.75 0.75 0.75 0.75 3. Keltrol RD 0.40 0.40 0.40 0.40 0.40 0.40 4. NaOH 50% 0.05 0.05 0.05 0.05 0.05 0.05 5. Gantrez AN 179 (5%) 8.00 8.00 8.00 8.00 8.00 8.00 6. AMMONYX® CETAC 5.80 5.80 5.80 5.80 5.80 5.80 (30%) 7. AMPHOSOL® SB or 24.00 24.00 24.00 SBG (50%) 8. Plantaran 2000 (50%) 10.00 30.0 9. AMMONYX® LO (30%) 3.33 10.0 10. AMPHOSOL® CA 10.00 50.0 (30%) 11. STEPANOL® AM 48.00 (29%) 12. NINOL® LMP — 3.00 — ... ... 13. KESSCO® EGMS 2.00 2.00 2.00 2.00 2.00 2.00 14. Glydant 0.25 0.25 0.25 0.25 0.25 0.25 Conditioning Effect on hair Excellent Very Good Very poor Excellent Excellent Excellent Sryling/Seiting/Body/Stiffne Excellent Very Good Very poor Excellent Poor Excellent ss on hair pH 5.6 5.6 5.6 5.6 5.6 5.6 Appearance Opaque Opaque Opaque Opaque Opaque Opaque Pearlescent Pearlescent Pearlescent Pearlescent Pearlescent Pearlescent FORMU LATION 32 33 34 35 wt. % (as is) wt. . % (as is) wt. % (as is) wt. % (as is) 1. D.I. Water Q.S. to 100.0 Q S ;. to IOO.O Q.S . to 100.0 Q.S ;. to ioo.o 2. Methocel J75MS 0.75 0.75 — 0.75 3. Keltrol RD 0.40 0.40 1.0 0.40 4. NaOH 50% 0.05 0.05 — 0.05 5. Gantrez AN179 (5%) 8.00 8.00 8.0 8.00 6. AMMONYX® CETAC (30%) 5.80 5.80 5.8 5.80 7. AMPHOSOL® SB or SBG (50%) 30.00 30.00 10.0 30.00 8. Plantaran 2000 (50%) — — 10.0 — 9. AMPHOSOL® CA (30%) 10.00 10.00 10.00 10. AMMONYX® LO (30%) — — 10.0 — 9. KESSCO® EGDS 2.00 2.00 2.0 10. Silicone Gum/Silicone fluid (350cps) 65:35 ratio 1.00 1.00 11. Zinc Pyrithione (48%) 2.10 12. STEPAN TAB-2®/ SAB-2 — — — 3.5 13. Glydant 0.25 0.25 0.25 0.25 Conditioning Effect on hair Excellent Excellent Excellent Excellent Styling/Sctting/Body/Stiffness on hair Excellent Excellent Excellent Excellent PH 5.6 5.6 7.0 5.6 Appearance Opaque Opaque Opaque Opaque Pearlescent Pearlescent Formulation 36 37 Wt.% (as is) Wt.% (as is) 1. D.I. Water Q.S. to 100.0 Q.S. to 100.0 2. Keltrol RD 1.0 1.0 3. AMPHOSOL®SB(50%) 30.O 30.O 4. AMPHOSOL®CA(30%) 16.7 16.7 5. Gantrez AN 179 (5%) 8.0 8.0 6. Lexein QX 3000 (30%) — 5.8 7. DDABDT 1.75 — 8. Glydant 0.25 0.25 Conditioning Effect on hair Excellent Fair Styling/Setting/Body/Stiffness on hair Excellent Fair pH 5.2 5.2 Appearance Clear Clear FORMULATION 38 39 40 wt. % (as is) wt. % (as is) wt. % (as is) 1. D.I. Water Q.S. to 100.0 Q.S. to 100.0 Q.S. to 100.0 2. Keltrol RD 1.0 1.0 1.0 3. LA 150M (92%) 8.97 8.97 4. LC 110M (100%) 8.25 5. AMPHOSOL® CA (30%) 14.2 14.2 14.2 6. NINOL LMP 2.5 2.5 2.5 7. Gantrez AN 179 (5%) 8.0 8.0 8. NaOH (50%) 0.05 0.05 0.5 9. AMMONYX® CETAC (30%) 5.8 5.8 5.8 10. KESSCO® EGDS 2.00 2.0 1 1. Glydant 0.25 0.25 0.25 Conditioning Effect on hair Excellent Excellent Poor Styling/Setting/Body/Stiffness on hair Excellent Excellent Poor pH 5.6 5.6 7.0 Appearance Opaque Clear Opaque Pearlescent Pearlescent Phase Type Isotropic Isotropic Isotropic Liquid Liquid Liquid FOR M U LATI ON (all components by Weighi t %, as is) 41 42 43 44 45 1. D.I. Water Q.S. to 100.0 2. AMPHOSOL® SB (50%) 30 30 30 30 — 3. Keltrol RD 1.0 1.0 1.0 1.0 1.0 4. AMPHOSOL® CA (30%) 16.7 16 7 16.7 16.7 66.5 5. Gantrez AN 179 (5%) — 8.0 — 8.0 8.0 6. AMMONYX® CETAC (30%) — — 5.8 5.8 5.8 CondiUoning Effect on hair Very poor Very poor Excellent Excellent Excellent Styling/Setting/Body/Stiffness Poor Poor Poor Excellent Excellent CMC (mg/l) 80 60 80 60 60 32 35 30.4 29.0 28.8 Surface Tension at CMC (mN/M) Clear Clear Clear with Clear with Clear with Dilution in DI water (6g/ 100ml) fibrils* fibπls** hbπls* *Agglomeraιed;**Non-agglomeraιcd FORMULATION (all components by Weight %, as is) 46 47 48 49 50 51 1. D.I. Water Q.S. to Q.S. to Q.S. to Q.S. to Q.S. to Q.S. to 100.0 100.0 100.0 100.0 100.0 100.0 2. Kcldrol RD 0.5 0.5 0.8 0.8 0.5 0.5 3. Neodol 91 -8 5.0 5.0 5.0 5.0 5.0 5.0 4. AMPHOSOL® CA (30%) 25.0 25.0 25.0 25 0 25.0 25.0 5. Ninol LMP 2.5 2 5 2 5 2 5 2.5 2 5 6. Gantrez AN179 (5%) 12.0 12.0 — — 12 0 7. NaOH (50%) Q.S. Q.S. Q.S Q S 8. AMMONYX® CETAC 5.8 5.8 5.8 5.8 (30%) 9. KESSCO® EGDS — 2.0 — 1 5 — — 10. Glydant 0.25 0.25 0.25 0.25 0.25 0.25 CondiUoning Effect on hair Excellent Excellent Excellent Excellent Very poor Very poor Styling/Setung/Body/ Excellent Excellent Poor Poor Very poor Very poor Stiffness on hair pH 5.5 7.2 5.5 7 2 5.5 5.5 Clear Liquid Opaque/ Clear Liquid Opaque/ Clear Liquid Clear Liquid Appearance Pearlescent Pearlescent Liquid Liquid Isotropic Isotropic Isotropic Isotropic Isotropic Isotropic Phase Type Liquid Liquid Liquid Liquid Liquid Liquid As can be seen, several of the formulations exhibit low cnncal micelle concentration (CMC), as well as very low surface tension at the CMC These characteristics are desirable in hair care compositions to impart excellent conditioning and styling benefits to the hair Formulation #44 and formulation #45 contain cationic surfactants, anionic polymers, have cnncal micelle concentraπons of about 60 mg/l, have surface tensions at the CMC of about 29 mN/m and impart excellent conditioning and styling propeπies to the hair In contrast, formulation 42 and formulation 43 contain only anionic styling polymer or canonic surfactant These formulations have a CMC of about 60 mg/l and 80 mg/l, respectively, and have surface tensions at the CMC's of about 35 nM/m and 30 5 mN/m, respectively These formulations do not fulfill the requirements of low surface tension and low CMC, and as a result, do not impart both condiuoning and styling propeπies to the hair However, because formulation #43 shows very low surface tension, it does impaπ excellent condinoning benefits to the hair, but no styling propeπies. Example 5 The Use of Pre-Formed Styling Agents A pre-formed anionic polymer/cationic surfactant (Gantrez AN 178 - Ammonyx CETAC) complex may be added to an non-tonic/amphoteπc shampoo base to achieve desired cleaning, conditioning, and styling propeπies An anionic polymer/canonic surfactant complex is formed according to Formulation # 54. Formulatior ι # 54 Ingredient Weuzht % 1 . Deionized Water 84.2 2 Gantrez AN179 (5%) 10.0 3. Na OH (50%) Q.S. To pH 5 8 4 Ammonyx CETAC (30%) 5 8 A suitable vessel equipped with a means for mixing and heating is charged with ingredients 1 and 2 added and the resulting mixture agitated The pH of the mixture is adjusted with ingredient 3 to a pH of about 5.8 Ingredient 4 is slowly added which results in the formation of the desired complex as a thick paste The water is then substantially removed from paste by evaporation A three-in-one styling/conditioning shampoo is prepared utilizing the complex prepared according to Formulation 54 as shown below in Formulation # 55 Formulation # 55 Ingredient Weieht % 1. Deionized Water 64.5 2. BIO-SOFT FF600 5 0 3. AMPHOSOL CA (30%) 25.0 4. NINOL 55LL 2.5 5. Complex Form. #54 3 0 6. Na OH 50% Q.S. to pH 5 8 A suitable vessel equipped with a means for mixing and heating is charged with ingredients 1 through 4 at ambient temperature The resulting mixture is heated to 140°F and ingredient 5 is added; the resulting slurry is agitated until homogenous. The resulting product is a clear isotropic liquid. The normally insoluble styling/conditioning agent prepared in Formulanon 54 readily dissociates into the individual complex components, i.e the canonic surfactant and the anionic polymer, when added into a non-ionic/amphoteπc surfactant base Approximately 6 grams of Formulation # 55 are diluted in deionized water The styling/conditioning agent in the form of macrofibπls is present and readily falls out of solution Formulation #55 showed excellent foaming, conditioning, and styling propernes on De Meo Brothers European natural brown hair Comparative Example 1 : The Use of Anionic Surfactants Several attempts were made in the use of anionic surfactants in the present mvenuon in place of the aforementioned nonionic surfactants or in combination with the nonionic surfactants Example formulations 52 and 53 are shown below as examples which utilize an alkyl ether carboxylate (AEC, deπved from Neodol® 23-6, Shell) and coconut fatty acid potassium soap (from Mclntyre) respecnvely Formulations 52 and 53 were evaluated as follows A 6 g poπion of each sample was added to 100 ml of deionized water Neither sample produced styling/conditioning fibnls upon dilution as desired Each formulation was tested on virgin brown hair and both formulauons produced very poor styling and conditioning propeπies, as compared to the more efficacious formulation previously disclosed herein. In addition, formulations 52 and 53 had a very poor foaming profile Similar results were obtained for other anionic surfactants, such as linear alkylbenzene sulfonates, alpha olefin sulfonates, alcohol sulfates, alcohol ether sulfates, etc FORMULATION 52 53 1. D.I Water Q.S. to 100 0 Q.S to 100 0 2. Keldrol RD 0.8 0.8 3. AEC 5.3 — 4. AMPHOSOL® CA (30%) 25.0 25.0 5. Nιnol 55LL 2.5 2.5 6. Gantrez AN179 (5%) 12.0 12.0 7. NaOH (50%) Q.S. Q.S. 8. AMMONYX® CETAC (30%) 5.8 5.8 9. Mackadet 40K — 12.5 10. Glydant 0.25 0.25 Conditioning Effect on hair Very Poor Very Poor Very Poor Very Poor on hair pH 5.8 7.5 Appearance Translucent Translucent Foaming Very Poor Very Poor Without being bound by any pamcular theory, it is believed that any available anionic surfactant preferentially reacts with the cationic surfactant in the composinon to form an undesirable anionic surfactant-cationic surfactant complex, rather than allowing for the formation the desired anionic polymer-cationic styling/conditioning complex in the presence of a non- anionic surfactant system. Example 6 1. Human Hair Evaluations Human hair is required for the testing of many personal care compositions and applications, including the compositions of the present invention. The hair also needs to be in a suitable pseudo-realistic form for testing in a laboratory environment. Generally, a swatch of hair glued on to a Plexiglas board for testing. The hair which is typically utilized for testing is 8" European Dark Brown from Demeo Bros. The following test protocol is typically used for the preparation of hair swatches by one skilled in the aπ. 1. Separate 8" hair into swatches 2.5 grams in weight (for a final weight of 2 grams on a hair swatch that is cut to 6.5" final length). 2. For a different size tress separate 8" hair into swatches 3.5 grams in weight (for a final weight of 3.5 grams on a hair swatch that is cut to 6.5" final length). 3. Wearing gloves, the root end of the hair is glued onto a Plexiglas square. Note: The hair needs to be thoroughly saturated with glue. Glue is applied to the Plexiglas before the hair is laid onto it, and then more glue is applied over the top of the hair as well. On the finished tress board there is usually 1/8" of space left on each side of the Plexiglas board from the hair. The hair is distributed evenly across the board and laid on Saran wrap to dry (this is done to prevent it from inadveπendy gluing to the surface it is drying on). 4. The glue is allowed to dry for a minimum of 24 hours. 5. After this period of time, the tress is combed out to untangle and remove any excess hair from the tress board. 6. The hair tress is cut to the appropriate length, usually 6.5" in length from the bottom of the Plexiglas board to the end of the hair. Note: The length of all the tresses is the same. As described in number 1 above where 2.5 grams of 8" hair is cut to 6.5" in length, the final weight of the hair swatch is 2 grams. 7. The hair is washed in a 10% shampoo solution prior to testing or evaluation. 2. Sensory Evaluations Sensory evaluation are performed in order to determine perceptual performance and property differences between the 3-ιn- l hair care compositions of the present invention and leading commercial 2-in-l conditioning shampoo compositions. A summary of these results is shown in the tables below. The sensory evaluation test methods utilized are as follows: 1. Hair swatches are prepared by weighing 2 g of 8" De Meo Brothers European Natural (virgin) or bleached/waved hair (damaged). The hair is glued on a 1.5" X 1.5" plastic tab using Duco cement and allowed to dry for 24 hours. 2. The swatches are cleaned by washing two times with a non-conditioning shampoo and are then allowed to air dry. 3. The hair swatches are then labeled and treated with the appropπate test product (Formulation 46, 47 and a leading commercial 2-ιn- 1 conditioning shampoo) Approximately 1 g of test hair care composition is applied to wet hair, worked up into a lather using the fingers and allowed to remain on the hair for 60 seconds; the hair swatches are πnsed for 30 seconds under warm running tap water and the treatment repeated a second nme 4. The hair swatches are clipped to a stand and a senes of panelists are asked to rate the treated hair swatches for detangling (initial break) and ease of wet combabihty (course side of a mechanical comb). The rating scale used for these subjective tests was 1 = worse (most difficult) and 5 = best (easiest). The hair swatches were dned and re-wetted pπor to each panelist's evaluation. 5. Treated, dry hair swatches were also rated by a senes of panelists for body/style/stiffness, dry combability and static control. The rating scale used for these subjective tests was 1 = worse (most difficult) and 5 = best (easiest) As shown in Table # 1 and Table # 2. Formulations 46 and 47 out-performed the leading commercial non-conditioning base shampoo and the leading commercial styiing shampoo, with respect to detangling, wet combability, dry combability, stanc control and body/style/softness The leading commercial 2-in-l conditioning shampoo performed better that the leading commercial non-conditioning base shampoo and the leading commercial styling shampoo, with respect to detangling, wet combability and dry combability However, the three test compositions were comparable with respect to static control and body/style/softness Formulation 46 and 47 out-performed the leading commercial 2-in-l conditioning shampoo, with respect to detangling, wet combability, dry combability, stanc control and body/style/softness The leading commercial base non-condinoning shampoo gave poor performance in all areas overall and was comparable in performance to the leading commercial styling shampoo, with respect to detangling, wet combability, dry combability, static control and body/style/softness 3. Curl Retention Studies The curl retennon propeπies of the composinons of the present invention were evaluated and compared to that of leading commercial hair care compositions It is known to one skilled in the art that curl retennon coπelates directly with style retention, both of which propeπies are important from a consumer point-of-view Curl retention studies allow for the evaluanon of concentraαon effects, temperature effects and/or humidity effects on curl retennon propeπies of vanous test products The procedure used for the curl retention tests performed is as follows Three hair swatches were prepared for each test product using the same lot of De Meo Brothers natural or damaged hair (bleached/waved) according to the aforementioned procedure for gluing human hair The swatches are washed two times using a non-conditioning shampoo and allowed to air dry. The hair is wet with luke warm running tap water Approximately 1 gram of test product is applied to the hair and massaged with the fingers while spreading evenly to cover all of the hair The test product is left on the hair for 1 minute The hair is then πnsed for 30 seconds under running tap water A second 1 gram of test product is applied to the hair and massaged with the fingers while spreading evenly to cover all of the hair The test product is left on the hair for 1 minute The hair is then nnsed for 30 seconds under running tap water TABLE #1 : SENSORY EVALUATION ON HAIR TRESSES BY AN EXPERT PANEL - VIRGIN HAIR State of the art shamnoos Attributes Base Formulations Shampoo 46 &47 Conditioning Stvline Detangling 2.3 S 5.0 S 3.3 2.3 Wet combing 2.4 S 5.0 S 3.3 2.4 Dry combing 2.9 S 4.0 S 3.5 2.7 Static control 2.8 S 4.6 S 2.8 2.6 Body/Style/Stiffness 1.5 S 5.0 S 1.4 1.5 Rating Scale 1 = worst 5 = best S = significant difference at 95% confidence limit n=10 TABLE #2: SENSORY EVALUATION ON HAIR TRESSES BY AN EXPERT PANF.Ϊ . . DAMAGED HAIR State of the art shampoos Attributes Base Formulat ions Conditionine Stvline Shamnoo 46 & ι 17 Detangling 2.0 S 5.0 S 3.0 1 .8 Wet combing 2.2 S 5.0 S 3.1 2.0 Dry combing 2.8 S 3.9 S 3.2 2.6 Static control 2.6 S 4.7 s 2.7 2.4 Body/Style/Stiffness 1.4 S 5.0 s 1.8 1 .6 Ratine Scale 1 = worst 5 = best S = significant difference at 95% confidence limit n= = 10 The hair swatches are curled on a 5/8" roller and are then clipped on a stand which has a vertical numerical scale under each swatch. The swatches allowed to 24 hours at ambient temperature. After this period of time, the rollers are removed, the hair swathes are re-attached to the stand and are placed it into a chamber with a temperature of about 80°F and relative humidity (RH) of about 90%. Numerical readings are taken from the vertical scale as to the position of the bottom of the hair (i.e. how much the hair as dropped) initially and after 30, 60, 90, 120, 160, 180, 200 and 240 minute intervals. The percent curl retention for each test swatch is calculated using the following equation: where L = length of hair fully extended L 0 = initial curl length L { = curl length at a given time t where L - L 0 represents the initial amount of curl. The term L - L t represents the amount of curl at time interval t. The average percent curl retention is calculated according to the following equation: Average % curl retention for a test product = X = x ] + xi + X3/3 where \\, xi ^d X3 represents % curl retention for each hair swatch. The following conclusions can be drawn from the curl retention results depicted in the graphs below, which involve the testing of natural hair (virgin; Table #3) and bleached/waved hair (damaged; Table #4) . Formulations 46 and 47 of the present invention had far superior average % curl retention at the same time intervals, as compared to the leading commercial 2-in-l compositions (such as Suave Balsam & Protein Regular Shampoo, Wash-N-Curl, and Pert Plus Shampoo for Normal Hair). The leading commercial 2-in- l compositions had very poor average % curl retention on both natural and damaged hair. Formulation 46 and 47 performed comparable to a leading commercial non-aerosol hair spray product. Example 7 Scanning Electron Microscopy Evaluations Scanning electron microscopy (SEM) was utilized to determine if the three-in-one compositions of the present invention deposition on the hair in the form of a continuous film. SEM allows for comparison of two or more hair samples in terms of deposition of active conditioning/styling agents on the hair. The following procedure was utilized to evaluate test hair samples. 1 The hair sample is mounted on aluminum stubs with sticky tape on both sides 2 The hair sample is spattered with gold/palladium 60 40 mixture 3 The sample is placed in a compaπment and viewed with a Jeol JM-35C microscope at 5000 magnification 4 An elecπon beam is introduced which interacts with the topography of the hair fiber The interacuon takes place between the electrons and the gold/palladium metal mixture on the surface of the hair, which serves as an indicator to create the surface image 5 The resulting surface images are recorded in the form of a photograph Figure I depicts hair treated two πmes with Formulauon # 46; Figure II depicts hair treated with a leading 2-in-l conditioning shampoo (Pen Plus Shampoo for Normal Hair) The areas with high levels of interaction are smooth and appear white in color This smoothness is an indicaπon that a desirable film deposited on the hair as a result of treatment with the hair care composition The areas of less interacuon or no interacnon at all, are dark/black which indicates no deposition of the hair care composiuon occuπed on the hair surface. The following conclusions can be drawn from the SEM studies and the resulnng photographs. Only the hair treated with Formulation 46 which contains both AMMONYX CETAC and Gantrez AN 179 shows significant deposinon of styling/condinomng mateπal Formulation 49 with AMMONYX CETAC and no Gantrez AN179 styling polymer showed deposition on the hair. Formulation 51 with Gantrez AN179 styling polymer and no AMMONYX CETAC quat showed little if any deposition on the hair Formulauon 50 without AMMONYX CETAC quat and Gantrez AN 179 styling polymer showed no deposition on the hair. Hair treated two times with a leading commercial 2-m- 1 hair care composition (i.e Pen Plus Shampoo for Normal Hair which contains dimethicone active condittoning agent or Suave Balsam & Protein Regular Conditioner which contains distearyldimonium chlonde and cetnmonium chloπde quats) showed deposition on the hair From the foregoing, it will be appreciated that although specific embodiments of the invention have been descπbed herein for purposes of illustration, vaπous modifications may be made without deviating from the spiπt or scope of the invention

Claims: WHAT IS CLAIMED IS: 1 . A hair care composition comprising: (a) from about 1 percent to about 80 percent by weight, based on the total weight of the hair care composition, of a first surfactant member selected from the group consisting of nonionic surfactants, semi-polar nonionic surfactants, amphoteric surfactants and mixtures thereof; (b) from about 0.1 percent to about 10 percent by weight, based on the total weight of the hair care composition, of a second surfactant member selected from the group consisting of cationic surfactants, fatty amine salts and mixtures thereof; and (c) from about 0.001 percent to about 10 percent by weight, based on the total weight of the hair care composition, of an anionic polymer member selected from the group consisting of polymers with one or more carboxylic acid groups, polymers with one or more carboxylic acid alkali metal salt groups, polymers with one or more sulfate groups, polymers with one or more sulfonate groups and mixtures thereof. 2. A hair care composition according to claim 1, which optionally contains from about 0.1 percent to about 10 percent by weight, based on the total weight of the hair care composition, of a swellable polymer thickening agent. 3. A hair care composition according to claim 2, wherein the optional swellable polymer thickening agent is present from about 0.2 percent to about 3.0 percent by weight, based on the total weight of the hair care composition. 4. A hair care composition according to claim 3, wherein the optional swellable polymer thickening agent is present from about 0.2 percent to about 2.0 percent by weight, based on the total weight of the hair care composition. 5. A hair care composition according to claim 1 , wherein the first surfactant member is present from about 2 percent to about 25 percent by weight, based on the total weight of the hair care composition. 6 A hair care composition according to claim 5, wherein the first surfactant member is present from about 8 percent to about 20 percent by weight, based on the total weight ot the hair care composition 7 A hair care composition according to claim 1 , wherein the second surfactant member is present from about 0 5 percent to about 5 0 percent by weight, based on the total weight of the hair care composition 8. A hair care composition according to claim 7, wherein the second surfactant member is present from about 1.0 percent to about 3 0 percent by weight, based on the total weight of the hair care composition 9 A hair care composition according to claim 1 , wherein the anionic polymer is present from about 0 001 percent to about 5 0 percent by weight, based on the total weight of the hair care composition 10. A hair care composition according to claim 9, wherein the anionic polymer is present from about 0 3 percent to about 2 0 percent by weight, based on the total weight of the hair care composition 1 1 The hair shampoo composition according to claim 1 , wherein the first surfactant member is a nonionic surfactant selected from the group consisting essenually of polyoxyethyleneated straight chain alcohols, pπmary alkanolamides, ethoxylated pπmary alkanolamides, alkylpolyglycosides, alkylpolylsacchaπdes, polyhydroxy fatty acid amides, amine oxides or a mixture thereof 12 The hair shampoo composition according to claim 1 1 , wherein the first surfactant member is a nonionic surfactant selected from the group consisting essentially of polyoxyethyleneated straight chain alcohols, primary alkanolamides, alkylpolyglycosides, amine oxides of a mixture thereof. 13. The hair shampoo composition according to claim 1 , wherein the first surfactant member is an amphoteric surfactant selected from the group consisting essentially of betaines, sulfobetaines, amidopropyl betaines, a cocobetaines, cocoamidopropyl betaines, lauryl betaines, lauramidopropyl betaines, amine oxides, alkylamine oxides, amidoamine oxides, sultaines or a mixture thereof. 14. The hair shampoo composition according to claim 13, wherein the first surfactant member is an amphoteric surfactant selected from the group consisting essentially of cocoamidopropyl betaines, alkylamine oxides, amidoamine oxides, sulfobetaines or a mixture thereof. 15. The hair shampoo composition according to claim 1 , wherein the first surfactant member is a semi-polar nonionic surfactant selected from the group consisting essentially of long- chain amine oxides having the formula wherein R3 is an alkyl, hydroxyalkyl, acylamidopropyl or alkyl phenyl group; each R4 is independently an alkylene or hydroxyalkylene group; each R5 is independently an alkyl or hydroxyalkyl group; and wherein the R5 groups can be attached to each other, either by an oxygen or nitrogen atom to form a ring structure and mixtures thereof. 16. The hair shampoo composition according to claim 15, wherein the first surfactant member is a semi-polar nonionic surfactant selected from the group consisting essentially of C \Q- C\g alkyl dimethyl amine oxides, a Cg-Cjo alkoxy ethyl dihydroxyethyl amine oxides, dimethyldodecylamine oxides or a mixture thereof. 17. The hair shampoo composition according to claim 1 , wherein the second surfactant member is a cationic surfactant selected from the group consisting essentially of fatty amine salts, fatty diamine salts, polyamine salts, quaternary ammonium compounds, polyoxyethyleneated fatty amines, quatemized polyoxyethyleneated fatty amines, amine oxides or mixtures thereof. 18. The hair shampoo compostion according to claim 17, wherein cationic surfactant is of the formula: wherein Ri , R7, R3, and R4 independently represent hydrocarbyl chains of from about 1 to about 30 carbon atoms, or hydrocarbyl chain having from about 1 to about 30 carbon atoms optionally containing one or more aromatic, ether, ester, amido, or amino moieties present as substituients or as linkages in the hydrocarbyl chain, where at least one of the R1-R4 groups is optionally substituted with at least one or more hydrophilic moieties independently selected from alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, and alkylester; and X is a soluble salt forming anion. 19. The hair shampoo composition according to claim 18, wherein the second surfactant member is a cationic surfactant selected from the group consisting essentially of di- (hydrogenated tallow) dimethyl ammonium chlonde, dioctadecyl dimethyl ammonium chloπde, stearyl dimethyl benzyl ammonium chloπde, dicetyl dimethyl ammonium chlonde, cetyl tnmethyl ammonium chloπde, tπcetyl methyl ammonium chlonde, methyl bιs-(hydrogenated tallowamidoethyl) 2-hydroxyethyl ammonium methyl sulfate or mixtures thereof 20. The hair shampoo composition according to claim 19, the second surfactant member is a canonic surfactant selected from the group consisting essentially of stearyl dimethyl benzyl ammonium chloπde, cetyl tnmethyl ammonium chloπde, dicetyl dimethyl ammonium chloπde and mixtures thereof 21 The hair shampoo composition according to claim 1 , wherein the the second surfactant member is a fatty amine salt selected from the group consisting essenually stearamidopropyl dimethyl amine, diethylaminoethyl stearamide, dimethyl stearamine and mixtures thereof 22. The hair shampoo composinon according to claim 21 , wherein the second surfactant member is a fatty amine salt selected from the group consisung essenually stearamidopropyl dimethyl amine, dimethyl stearamine and mixtures thereof 23 The hair shampoo composition according to claim 1 , wherein the anionic polymer member is selected from the group consisting essentially of polymenc condensation products of methyl vinyl ether and maleic anhydnde and salts thereof, salts of an ethyl half ester of copolymenc condensation products of methyl vinyl ether and maleic anhydπde, sodium salts of terpolymers of octyl acrylamide, polymenc condensation products of acrylate esters and butylaminoethyl methacrylate, acrylic acid polymers cross-linked with a polyfuncuonal agent, sulfated polyethers, sulfated polyesters, sulfonated polyethers, sulfonated polyesters, sulfonated polystyrene and mixtures thereof 24. The hair shampoo composition according to claim 1, wherein the anionic polymer member contains at least one carboxylic acid group, or at least one sulfate group, or at least one sulfonate group, or a mixture thereof, and is the product of a radical polymeπzation reaction of an ethylenically unsaturated monomer 25. The hair shampoo composition according to claim 23, wherein the polyfuncuonal agent is an agent selected from the group consisting essentially of polyols, polyamines, carboxymethyl cellulose and mixtures thereof 26. The hair shampoo composition according to claim 2, wherein the swellable polymer thickening agent is selected from the group consisting essentially of methyl cellulose, ethyl cellulose, xanthan gum, gum arabic, gum karaya, guar gum, locust bean gum, ghatπ gum, hydrolyzed starches, low molecular weight ethylene oxide polymers, low molecular weight propylene oxide polymers and mixtures thereof. 27 A method for treating hair compnsmg the application of a hair care composition to the hair compnsmg- (a) from about 1 percent to about 80 percent by weight, based on the total weight of the hair care composinon, of a first surfactant member selected from the group consisung of nonionic surfactants, amphotenc surfactants and mixtures thereof; (b) from about 0 1 percent to about 10 percent by weight, based on the total weight of the hair care composition, of a second surfactant member selected from the group consisung of canonic surfactants, fatty amine salts and mixtures thereof, and (c) from about 0.001 percent to about 10 percent by weight, based on the total weight of the hair care composition, of an anionic polymer member selected from the group compnsmg polymers with one or more carboxylic acid groups, polymers with one or more carboxylic acid alkali metal salt groups, polymers with one or more sulfate groups, polymers with one or more sulfonate groups and mixtures thereof 28 A method for prepanng a hair care composition compnsmg the combining in any order of (a) from about 1 percent to about 80 percent by weight, based on the total weight of the hair care composition, ot a first surfactant member selected from the group consisung of nonionic surfactants, semi-polar nonionic surfactants, amphotenc surfactants and mixtures thereof, (b) from about 0 1 percent to about 10 percent by weight, based on the total weight of the hair care composition, of a second surfactant member selected from the group consisung of canonic surfactants, fatty amine salts and mixtures thereof; and (c) from about 0 001 percent to about 10 percent by weight, based on the total weight of the hair care composition, of an anionic polymer member selected from the group consisting of polymers with one or more carboxylic acid groups, polymers with one or more carboxylic acid alkali metal salt groups, polymers with one or more sulfate groups, polymers with one or more sulfonate groups and mixtures thereof. 29. A method for prepanng a styling and conditioning agent compnsmg combining a surfactant member selected from the group consisung essentially of catiomc surfactants, fatty amine salts, and mixtures thereof with an anionic polymer 30. A styling and conditioning agent prepared by the reaction of an anionic polymer with a surfactant member selected from the group consisung essentially of canonic surfactants, fatty amine salts, and mixtures thereof 31 A method for prepanng a hair care composition compπsing the combining of (a) from about 1 percent to about 80 percent by weight, based on the total weight of the hair care composition, of a first surfactant member selected from the group consisting of a nonionic surfactant, an amphoteπc surfactant and mixtures thereof, (b) from about 0.001 percent to about 20 percent by weight, based on the total weight of the hair care composition, of the styling and conditioning agent 32. A charge transfer complex produced by the combination of an anionic polymer and a surfactant member; wherein the charge transfer complex has a molecular weight of at least 100,000, where the anionic polymer is selected from the group consisting of polymers with one or more carboxylic acid groups, polymers with one or more carboxylic acid alkali metal salt groups, polymers with one or more sulfate groups, polymers with one or more sulfonate groups and mixtures thereof; and where the surfactant member is selected from the group consisting of cationic surfactants, fatty amine salts and mixtures thereof . 33. A compound of the formula: wherein n is an integer from about 1 - 500,000; m is an integer from about 1 - 1 ,000,000; Rj , R2, R3, and R4 independently represent hydrocarbyl chains of from about 1 to about 30 carbon atoms, or hydrocarbyl chain having from about 1 to about 30 carbon atoms and optionally containing one or more aromatic, ether, ester, amido, or amino moieties present as subsntuients or as linkages in the hydrocarbyl chain, where at least one of the R 1-R4 groups is optionally substituted with at least one or more hydrophilic moieties independently selected from alkoxy (preferably C\ - C3 alkoxy), polyoxyalkylene (preferably C1-C3 polyoxyalkylene), alkylamido, hydroxyalkyl, and alkylester. 34. A compound of the formula: wherein n is an integer from about 1 - 500,000; m is an integer from about 1 - 500,000; wherein R is alkyl, alkenyl, alkynyl, aryl, alkylaryl, and mixtures thereof; R i , R2, R3, and R4 independently represent hydrocarbyl chains of from about 1 to about 30 carbon atoms, or hydrocarbyl chain having from about 1 to about 30 carbon atoms and optionally containing one or more aromatic, ether, ester, amido, or amino moieties present as substituients or as linkages in the hydrocarbyl chain, where at least one of the R 1 -R4 groups is optionally substituted with at least one or more hydrophilic moieties independently selected from alkoxy (preferably C1 -C3 alkoxy), polyoxyalkylene (preferably C1 -C3 polyoxyalkylene), alkylamido, hydroxyalkyl, and alkylester. 35. A hair care composition comprising: (a) from about 8 percent to about 20 percent by weight, based on trie total weight of the hair care composition, of a first surfactant member selected from the group consisting of nonionic surfactants, semi-polar nonionic surfactants, amphoteric surfactants and mixtures thereof; (b) from about 0.5 percent to about 5 percent by weight, based on the total weight of the hair care composition, of a second surfactant member selected from the group consisting of cationic surfactants, fatty amine salts and mixtures thereof. 36. A hair care composition according to claim 35, comprising: (a) from about 10 percent to about 16 percent by weight, based on the total weight of the hair care composition, of a first surfactant member selected from the group consisting of nonionic surfactants, semi-polar nonionic surfactants, amphoteric surfactants and mixtures thereof;

Inventors: RAO Y KAMESHWER, SAJIC BRANKO, RAO, Y., KAMESHWER, SAJIC, BRANKO
Applicants: RAO Y KAMESHWER, SAJIC BRANKO, STEPAN CO, RAO, Y., KAMESHWER, SAJIC, BRANKO, STEPAN COMPANY
Application year: 1996
Main classification: A61K7
IPC codes: A61K8, A61Q5, C11D3