Levitation melting method and melting and casting method

Abstract: Disclosed is a levitation melting method comprising applying a high-frequency current to a high-frequency induction coil (20) wound around a melting crucible (12) to induction-heat a material (22) introduced to the melting crucible (12); and erecting the resulting molten metal (22a) to be in no contact with the inner wall surface of the melting crucible (12) with the bottom of the material (22) being maintained in the solidified state; wherein a power input P (kw) of a high-frequency power source to the high-frequency induction coil (20), an inner radius R (mm) at the bottom of the crucible (12) and super heat Δ T (°C) of the molten metal (22a) satisfy the relationship of P/R2 = Δ T·(0.0008 to 0.002), as well as, a melting and casting method for casting the molten metal prepared by the levitation melting method described above into a mold using a snout (26) suspended above the melting crucible such that the lower end of the snout (26) may be submerged in the molten metal (22a).

Description: The present invention relates to a levitation (electromagnetic) melting method and also to a melting and casting method. More particularly, the present invention relates to a levitation melting method for subjecting a metallic material introduced to a melting crucible to induction heating and retaining the resulting molten metal in the melting crucible in no contact with the inner wall surface of the crucible and also to a melting and casting method for casting the molten metal obtained by the levitation melting method into a mold. Description of the Related Art There is known the levitation melting method as a melting method which can prevent, when a metallic material of various kinds introduced to a melting crucible is to be melted therein, the resulting molten metal from being contaminated due to chemical reactions occurring when it is brought into contact with the inner wall surface of the crucible and which can thus achieve improvement in the quality of molten metal. This levitation melting method includes a full-levitation melting method in which a molten metal is fully levitated by an electromagnetic force and a semi-levitation melting method in which a molten metal is erected by an electromagnetic force with the bottom of a material to be melted being maintained in the solidified state using a water-cooled copper crucible. In the full-levitation melting method, since the molten metal is fully levitated, migration of contaminants from the melting crucible can be fully prevented, but it is difficult to retain the molten metal in the levitated state. Further, since the full-levitation method cannot levitate a large amount of molten metal, the semi-levitation melting method is rather employed for industrial applications. To describe briefly the semi-levitation method, the water-cooled copper crucible employable here has a cylindrical main body with a closed bottom. The circumferential wall of the main body is vertically divided into some sectorial segments through which a cooling water is circulated, and these segments are electrically insulated from one another by an insulating material. Further, annular high-frequency induction coils are disposed to surround the water-cooled crucible with predetermined annular spaces being secured between them, and when a material is introduced into the crucible and a high-frequency current is applied to the induction coils, the material is induction-heated. When the material is heated to a predetermined temperature, it is partly melted with the bottom thereof brought into contact with the inner bottom surface of the water-cooled copper crucible being maintained in the solidified state, and the molten metal is retained in the erected state in no contact with the inner wall surface of the crucible by the electromagnetic force penetrating the crucible. In the semi-levitation melting method described above, the super heat (the melting point of the material is the standard temperature (0°C)) of the molten metal retained in the erected state in no contact with the inner circumferential wall surface of the water-cooled copper crucible must be properly maintained. If the temperature of the molten metal is too low when it is poured into a mold, misrunning occurs to give defective products; whereas if it is too high, the mold itself is likely to be damaged. Since the super heat of the molten metal varies depending on various conditions such as an input value of high frequency current to be applied to the induction coils from a high-frequency power source, the size of the water-cooled crucible, the kind of the material, etc., these conditions must be set adequately so as to perform the melting operation efficiently at a super heat suitable for casting the molten metal. Therefore, it has been difficult to preestimate the super heat in the stage of designing the melting equipments, including the water-cooled crucible and the induction coils so as to design the melting apparatus and also to set operational conditions, including the input value of high frequency current to be applied to the induction coils from a high-frequency power source. Specifically, under the present circumstances, optimum conditions have been found experimentally at a great cost of labor and time employing laboratory equipments by changing these conditions. Further, the most optimum super heat of the molten metal for casting has not yet been established. Further, there has not been established conditions for the state of the molten metal (for maintaining the erected state) under which the molten metal can be maintained at an adequate super heat while it is retained stably in no contact with the inner wall surface of the crucible. In addition, while a contaminant-free molten metal prepared by the semi-levitation melting method must be poured as such into a mold in order to obtain a quality molded product, there has not been established conditions for efficiently carrying out the casting method and casting operations. SUMMARY OF THE INVENTION The present invention is proposed in view of the disadvantages inherent in the levitation melting method and in the melting and casting method described above and with a view to overcoming them successfully, and it is an objective of the present invention to provide a levitation melting method which enables not only designing of the melting equipments but also simplification of operational conditions by preestimating the super heat of a molten metal; which enables efficient casting operation while the molten metal is maintained at a super heat suitable for casting; which enables maintenance of the molten metal in a proper state in the melting crucible; and which enables casting of the molten metal efficiently. In order to overcome the problems described above and to attain the intended objective of the present invention, the levitation melting method according to one aspect of the present invention comprises applying a high-frequency current to a high-frequency induction coil wound around a melting crucible to induction-heat a material introduced to the melting crucible; and erecting the resulting molten metal to be in no contact with the inner wall surface of the melting crucible with the bottom of the material being maintained in the solidified state; wherein a power input P of a high-frequency power source to the high-frequency induction coil, an inner radius R at the bottom of the crucible and super heat Δ T of the molten metal satisfy the following relationship: P/R 2 = Δ T • (0.0008 to 0.002). BRIEF DESCRIPTION OF THE DRAWINGS The features of the present invention that are believed to be novel are set forth with particularity in the appended claim. The invention, together with the objects and advantages thereof, may best be understood by reference to the following description of the presently preferred embodiments taken in conjunction with the accompanying drawings in which: Fig. 1 is a schematic constitutional view of a melting apparatus in which the levitation melting method according to the present invention can be suitably embodied; Fig. 2 is an explanatory view of a heat flow model showing how super heat of a molten metal is equilibrated in the levitation melting method; Fig. 3 is a table of various numerical values experimentally determined under various operational conditions; Fig. 4 is a table of super heat temperature values Δ T preestimated under an operation constant C = 0.0008 to 0.002 and the experimentally found super heat temperature values Δ T; Fig. 5 is a table showing results of estimation for molded products obtained by using molten metals prepared in the melting apparatus and by casting them into molds by means of vacuum suction molding and the like, as well as, the molds; Fig. 6 is an explanatory view of a melting and casting method; and Fig. 7 is a table showing results of tests made for Examples 1 to 5 satisfying the conditions (1) to (5) (to be described later) and for Comparative Examples 1 to 3 not satisfying one of the conditions (1) to (5). DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT The levitation melting method and the melting and casting method according to the present invention will be described below by way of preferred embodiments referring to the attached drawings. It should be noted that the term "inner bottom radius of a crucible (furnace radius)" used in the following description should not be understood to be limited to that of a circular cross section in the bottom of the crucible but should be appreciated to include imaginary radii in cross sections other than circle. Fig. 1 is a schematic constitutional view of the melting apparatus in which the levitation melting method according to the present invention is embodied. A melting crucible 12 constituting the melting apparatus 10, which is made of copper, has a cylindrical form with a closed bottom, and a plurality of slits 14 are defined vertically at predetermined intervals in the circumferential direction of the crucible 12. Each slit 14 opens inward and outward in the radial direction of the melting crucible 12 and has a predetermined length in the axial direction of the crucible 12. Specifically, the circumferential wall of the crucible 12 consists of several segments 16 vertically divided by the slits 14. Further, each slit 14 is filled with an insulating material 18 such as a refractory ceramic, and thus each segment 16 is electrically insulated from the other segments 16. A passage (not shown) through which a cooling water is circulated is defined in each segment 16 parallel to the slits 14 so that the melting crucible 12 may be cooled by the cooling water circulating through the passages. Meanwhile, annular high-frequency induction coils 20 are arranged at predetermined annular spaces between them so as to surround the melting crucible 12, and a material 22 placed in the crucible 12 is adapted to be heated by the heat induced when a high-frequency electric current is applied to the induction coils 20. It should be noted here that a solidifying shell 24 having a concave upper surface is provided at the inner bottom of the melting crucible 12 so that the material 22 may be placed on the concaved bottom section 24a. Thus, the material 22 placed at the bottom section 24a of the solidifying shell 24 is melted, when the crucible 12 is induction-heated, with the bottom thereof brought into contact with the shell 24 being maintained in the solidified state, and the thus obtained molten metal 22a is adapted to be erected to be in no contact with the inner wall surface of the crucible 12 under the electromagnetic force penetrating the crucible 12. By the way, since the levitation melting method can generally heat the material 22 to a high temperature, it is suitable for melting active metals having high melting points such as titanium. Accordingly, extremely high heat is inconveniently dissipated from the molten metal prepared by the full-levitation melting method described above, because heat loss occurs by radiation only. On the other hand, the heat to be dissipated from the molten metal 22a obtained by the semi-levitation melting method according to the present embodiment includes radiant heat loss and conduction heat loss through the bottom section 24a. Therefore, the temperature of the molten metal 22a can be set at a level lower than in the full-levitation melting method. According to the semi-levitation melting method embodied in the melting apparatus 10 having the constitution described above, the super heat of the molten metal 22a formed in the melting crucible 12 is rapidly equilibrated. A heat flow model showing such equilibrated state is illustrated in Fig. 2. The following equation is established in this model: P•η =(Δ T/δ)•λ•(α•R 2 ) P: power input (kW) η : efficiency of power input to molten metal (-) Δ T : super heat (°C) δ : thickness of the fluid side boundary layer at the solidifying interface at the bottom of the molten metal (mm) λ : heat conductivity of the molten metal assuming a static state (kw/mm°C) α : shape constant of the heat dissipating surface at the solidifying interface of the material at the bottom of the melting crucible (bottom section 24a) (-) R : Inner radius of the melting crucible (radius of the bottom section 24a) (mm) The left-hand in the above equation represents an energy input to the molten metal 22a; whereas the right-hand represents an outflow energy. The first term (Δ T/ δ) in the right-hand represents the temperature gradient in the fluid side boundary layer at the solidifying interface at the bottom section 24a, and the third term (α · R 2 ) represents the heat dissipating area. The super heat Δ T can be expressed using Equation 1 as follows: Δ T = (P/R 2 )•η•(δ/λ)•(1/α) Thus, the super heat Δ T can be preestimated by employing Equation 2 and by determining the generally unknown numerical values η, δ, λ, α according to some methods and can be controlled. For example, the power input efficiency η can be obtained by subjecting, in place of the molten metal 22a, a work which has a water-cooled structure and also has a similar electric conductivity and a similar shape to the molten metal 22a to induction heating in a crucible and by measuring the heat taken away from it by the cooling water circulated to the work. Meanwhile, the shape constant of the heat dissipation surface α can be determined by solidifying the molten metal 22a in the crucible, examining the solidified block and measuring the shape of the interface. For example, when the interface shape is a flat circle, α assumes the minimum value π ; whereas when it is hemispherical, α assumes a value 2 π. In many cases, although it is difficult to directly measure the boundary layer thickness δ and to know a correct heat conductivity value λ of the molten metal 22a assuming the molten state, these values are considered to be constant if the molten metal 22a is of a fixed material. Accordingly, based on the known experimental data, these values can be obtained in terms of δ / λ (see Fig. 3). The range of operation constant C can be determined by modifying Equation 2 into Equation 3 to incorporate the concept of operation constant C to it and by measuring the values η δ, λ, α by experiments and the like. P/R 2 = Δ T • (λ/δ)•(1/η)•α = Δ T • C Accordingly, designing of the melting apparatus 10 and setting of operational conditions become possible by incorporating a constant C representative of various operational conditions when the super heat temperature Δ T is set in a temperature range suitable for casting. The values R,P, Δ T, η, α, δ/λ ,C were experimentally determined under various conditions, and the results are summarized in Fig. 3. It was found from the test results shown in Fig. 3 that operation constants C of common metals concentrate to a certain range, so that if the operation constant C is set between 0.0008 and 0.002, it is quite possible to substantially control the super heat Δ T of the molten metal 22a. Super heat values Δ T preestimated provided that the operation constant C is between 0.0008 and 0.002 and experimentally found super heat values Δ T are shown in Fig. 4. The test data shown in Fig. 4 demonstrated that the found super heat values Δ T are all included within the preestimated ranges respectively. More specifically, if the operation constant C is set between 0.0008 and 0.002 in Equation 3, the inner radius R (mm) of the crucible, power input P (kw) and super heat Δ T (°C) can be set, thus enabling designing of an optimum melting apparatus 10 based on the conditions preestimated according to Equation 3 and also setting of efficient operational conditions. The method and results shown in Figs. 5 to 7 are for technical explanation. They do not form part of the invention. (Second levitation melting method) Next, various materials Ti-6Al-4V, TiAl and SUS304 were melted using the melting apparatus 10 at different super heat temperature levels Δ T, and the resulting molten metals were poured into molds to be molded by means of vacuum suction casting method and the like, followed by estimation of the resulting molded products and the molds. The results are summarized in Fig. 5. As the results of Fig. 5 show, it was confirmed that, when the super heat Δ T of the molten metal is set lower than 20°C, the resulting products are defective due to misrunning; whereas when the super heat Δ T is set higher than 300°C, the molds are damaged by the high heat. In other words, it was found that the casting operations can be performed smoothly by maintaining the super heat Δ T of the molten metal between 20°C and 300°C. (Third levitation melting method) In a semi-levitation melting method employing the melting apparatus 10 having the constitution as described above, the super heat of the molten metal 22a can be maintained at a level suitable for casting while the molten metal 22a formed in the melting crucible 12 is retained stably in no contact with the inner wall surface of the crucible 12, provided that (1) a relationship H/D > 0.5 is established between the center height H of the molten metal 22a and the inner diameter D of the melting crucible 12. Incidentally, the center height H of the molten metal 22a is measured from the lower edge of the molten metal 22a from where it erects, as shown in Fig. 6. Specifically, since the center height H of the molten metal 22a in the melting crucible 12 is small and the top of the molten metal 22a is close to the bottom section 24a if H/D is 0.5 or less, the molten metal 22a cannot be heated sufficiently to the super heat Δ T, in some cases, due to heat conduction loss through the bottom section 24a. In addition, since the molten metal 22a assumes a thin flat shape, it sometimes becomes extremely difficult to put a snout 26 (to be described later) into it when it is cast, disadvantageously. Meanwhile, when H/D is set greater than 0.5, the top of the molten metal 22a is sufficiently spaced from the bottom section 24a, so that the super heat Δ T can be prevented from lowering due to heat conduction loss through the bottom section 24a. Besides, since the center height H of the molten metal 22a is regulated relative to the inner diameter D of the melting crucible 12, the erected molten metal 22a can be also prevented from being brought into contact with the inner wall surface of the crucible 12. (Fourth levitation melting method) In a semi-levitation melting method employing the melting apparatus 10 having the constitution described above, melting operation is carried out (2) with the clearance S of 3 to 10 mm being secured between the inner wall surface of the crucible 12 and the outer surface of the molten metal 22a at the half height H/2 thereof. Thus, the super heat Δ T of the molten metal 22a formed in the melting crucible 12 can be maintained at a level suitable for casting while the molten metal 22a is stably retained in no contact with the inner wall surface thereof. Namely, if the clearance S is too small, the molten metal 22a wavers to readily touch the inner wall surface of the crucible 12. Accordingly, the minimum width of the clearance S is restricted to 3 mm so as to surely avoid contact of the wavering molten metal 22a with the inner wall surface of the crucible 12 and deterioration of the molten metal 22a. Meanwhile, if the clearance S is too great, the top of the molten metal 22a is tapered to readily waver, and thus the molten metal 22a becomes unstable. In addition, heating efficiency of the high-frequency induction coils 20 becomes too low to maintain the super heat Δ T at a proper level. In order to cope with this, the maximum width of the clearance S is restricted to 10 mm, so that the molten metal 22a can be stabilized and the super heat Δ T can be maintained at a level suitable for casting. (First melting and casting method) In a first melting and casting method, when a molten metal 22a prepared according to the third levitation melding method described above is poured into a mold (not shown), for example, a snout 26 communicating to the mold is suspended above the melting crucible 12 such that the lower end portion of the snout 26 may be submerged in the molten metal 22a with a closed vessel containing the mold being maintained under reduced pressure (see Fig. 6). Thus, the contaminant-free molten metal 22a in the crucible 12 is as such sucked into the mold through the snout 26 without being brought into contact with the inner wall surface of the crucible 12. In this case, the casting operation can be performed stably and efficiently under the following conditions, and besides the accuracy of molded products can be improved. (3) The height H1 of the lower end of the snout 26 submerged in the molten metal 22a is at least 5 mm as measured from the bottom section 24a of the melting crucible 12. (4) The length H2 of the submerged portion of the snout 26 in the molten metal 22a is maintained at least to 10 mm. (5) A relationship of d/D ≦ is established between the inner diameter d of the snout 26 and the inner diameter D of the melting crucible 12. If the requirement (3) is satisfied, the lower end of the snout 26 is prevented from contacting with the bottom section 24a of the melting crucible so as not to damage the snout 26 or the bottom section 24a, and the molten metal 22a can be sucked through the snout 26 smoothly. Meanwhile, if the requirement (4) is satisfied, since the lower end of the snout 26 is prevented from being exposed out of the molten metal 22a when the molten metal 22a is sucked through the snout 26 to have a low storage level, and thus sucking of a gas through the snout 26 to form defective molded products can be avoided. Further, if the requirement (5) is satisfied, since the inner diameter of the snout 26 is small relative to the molten metal 22a maintained in the erected state to have a hemispherical upper surface, the lower end of the snout 26 is prevented from being exposed out of the molten metal 22a, even when the snout 26 is shifted radially due to its displacement. (Second melting and casting method) In the second melting and casting method, the molten metal 22a prepared according to the fourth levitation melting method described above is poured into a mold through a snout 26 suspended above the melting crucible 12 such that the lower end of the snout 26 may be submerged in the molten metal 22a. In this case, if the requirements (3),(4) and (5) are satisfied, the contaminant-free molten metal 22a in the crucible 12 can be again poured as such into a mold, and thus not only casting operation can be performed stably but also the accuracy of molded products can be improved. As the method of casting the molten metal 22a in the melting crucible 12 through the snout 26 into the mold in the first and second melting and casting methods, the vacuum casting method may be employed in place of the vacuum suction casting method, or an inert gas may be blown into the crucible 12 to increase the internal pressure thereof relative to that of the mold (reduced pressure or vacuum) and to pressurize the molten metal 22 to be fed into the snout 26. (Test Examples) Tests were carried out for Examples 1 to 5 all satisfying the requirements (1) to (5) described above and Comparative Examples 1 to 3 which do not satisfy any of these five requirements, respectively. The test results are shown in Fig. 7. The test results of Fig. 7 show that, in the cases where the requirements (1) to (5) are all satisfied, stability of super heat, presence of contact of the molten metal 22a with the inner wall surface of the crucible 12, and presence of sucked gas were all evaluated as excellent or good (absent). On the other hand, in the cases where any of these requirements are not satisfied, these items were evaluated as inadequate or unacceptable (present).

Claims: A levitation melting method comprising: applying a high-frequency current to a high-frequency induction coil (20) wound around a melting crucible (12) to induction-heat a material (22) introduced to said melting crucible (12); and erecting the resulting molten metal (22a) to be in no contact with the inner wall surface of said melting crucible (12) with the bottom of said material (22) being maintained in the solidified state; wherein a power input P (kW) of a high-frequency power source to said high-frequency induction coil (20), an inner radius R (mm) at the bottom of said crucible (12) and super heat Δ T (°C) of said molten metal (22a) satisfy the following relationship: P/R 2 = Δ T•(0.0008 to 0.002).

Inventors: DEMUKAI NOBORU, YAMADA JUNJI, DEMUKAI, NOBORU, YAMADA, JUNJI
Applicants: DAIDO STEEL CO LTD, DAIDO TOKUSHUKO KABUSHIKI KAISHA
Application year: 1996
Main classification: F27B14
IPC codes: C22B9, B22D18, F27D11, H05B6, F27B14, C21C5