VITAL WHEAT GLUTEN EXTRACT

Abstract: A method of transforming the clumped untextured putty-like and high viscoelastic adhesion physical and chemical properties of hydrated vital wheat gluten into a loose layered minimally adhering aerated permanently textured fiber strand structure by appropriate shredding, steaming and hot moisture denaturation of the fiber protein, enabling the creation of wheat gluten analogs for ground meat fiber products, such as hamburger and the like.

Description: VITAL WHEAT GLUTEN EXTRACT The present invention relates to wheat gluten extracts and products produced therefrom, being more particularly directed to a novel process for transforming or converting the normal inherent putty-like mass and relatively high viscoelastic adhesion properties of hydrated vital wheat gluten into novel aerated layered fiber strand structures of relatively low adhesion properties. BACKGROUND For many years, the value of vital wheat gluten extracted from wheat flour or berries has been recognised, primarily for its natural protein value for food products, and for its physical and chemical properties, when hydrated, of increasing the viscosity of, for example, flour batters and substantially improving batter adhesion; and, in meat and poultry products and the like, for adhesively binding, extending or filling, and, indeed, providing a chewy texture. Various processes have been developed for deriving the vital wheat gluten from wheat flour or berries, including the "dough" or "Martin" process in which hydrated and kneaded flour is formed into a cohesive elastic dough and is continuously washed to elute the starch granules, or to screen out the starch liquors. Illustrative examples of techniques are described in U.S. Patents Nos. 3,790,553; 3,851 ,085; and 4, 132,566. Until the discovery underlying the present invention, it is believed that uses of vital wheat gluten have had to be confined to applications that can tolerate its highly viscoelastic putty-like dough properties, namely, as in an additive in baking batters, and for meat, fish and poultry products where the addition of the gluten provides "valu- able binding, adhesion, emulsif1 ca ion and water binding qualities" (Midwest Grain Products [Kansas] bulletin, "Challenging The Eighties", pages 32-35). The putty-like, highly cohesive and non-textured pro¬ perties in the hydrated gluten solid or massive "dough" have relegated hydrated vital wheat gluten to uses just as a binder or "glue"-like additive where it is physically intermixed and visually lost in the main product or ingre¬ dients. The total lack of texture let alone lack of open fiber-like texture and appearance, have not heretofore made it even a serious candidate as the primary consti¬ tuent for a close analog for ground meat; and the high sticky viscoelastic properties further distant it from the tender fiber-layer taste sensation and cutting charac¬ teristics of, for example, a meat hamburger. In accordance with basic discoveries made in achieving the present invention, however, a technique was surprisingly found radically and permanently to alter or transform both the physical and chemical properties of vital wheat gluten, particularly when hydrated, amazingly to change the physical characteristics from a clump of tough stretchable untextured "putty" to layered aerated loosely packed fiber strand textured structures, closely and substantially indistinguishably simulating the texture of ground beef or other meat; and chemically to denature the protein and otherwise suppress the activity of the originally high viscoelasti city of the gluten, iust retaining enough to enable the strands to stay together in an analogous way to ground beef and the like—and with substantially identical physical appearance and mouthfeel, chew and taste sensation. To achieve this remarkable transformation of normal physical and chemical properties, long thought to be in¬ herent in hydrated vital wheat gluten, moreover, it was necessary to go in a direction absolutely contralndicated in this art. The art had thought that "gluten can sustain its unique properties when subjected to heat, unlike other hydrated proteins which undergo substantial changes when heated to critical temperatures" ("Challenging the Eigh¬ ties", supra , page 34). Under the discovery of the pre¬ sent invention, quite to the contrary, it has now been found how to coadition and subject the hydrated gluten to 5 heat to achieve very substantial permanent changes in both chemical a d physical characteristics that indeed give rise to the novel results of this invention. In view of this surprising transformation, moreover, for the first time, vital wheat gluten can be used as the lOprincipal ingredient itself in producing very close wheat analogs to ground meats, hamburgers, sausages, and the like . Object of Invention 5 An object of the present invention, accordingly, is to provide a new and improved method or process of trans¬ forming hydrated vital wheat gluten from its natural cohe¬ sive, putty-like adhesive- and high viscoelastic physical and chemical characteris ics, to novel layered aerated 20loosely packed fiber strands with minimal low vlscoelasti- city. A further object is to provide, through use of this novel process, a very close gluten analog to meat fiber products such as hamburger, meat loaf, sausages and the like. Other and further objects will be described herein¬ after and are more particularly delineated in the appended claims . Summary In summary, however, from one of its important view¬ points, the invention embraces a method of permanently transforming the clumped putty-like untextured mass and re¬ latively high viscoelastic adhesion physical properties o hydrated vital wheat gluten into a loose layered minimally adhering aerated textured fiber strand structure, that com¬ prises, intimately mixing flour with vital wheat gluten powder particles to interleave with and separate the gluten powder in the mixture; substantially room- emperature hydrating the mixture to enable the absorption of water by the mixture to expand the gluten into a less viscoelastic mass; shredding the mass into a plurality of separated streams of elongated continuous fibers; dropping the separate strands under the action of gravity as a loose aerated deposit upon a retaining surface; immediately subjecting the deposit to heated moisture contacting with the separate fibers throughout the deposit; continuing the application of heated moisture for a sufficient time for the protein of the separate fibers within the deposit to become substan ially denatured, to remove the bulk of the viscoelastic adhesion properties of the gluten while retaining only slight adhering of the fibers; and per¬ mitting evaporation of excess moisture from the deposit to produce a loose layered aerated permanent fiber texture structure of relatively low retained vis coelasti ity. Pre erred and best mode conditions f r operating the method and novel products produced thereby, particularly ground-meat wheat gluten analogs, are hereinafter des¬ cribed in detail. Drawings The invention will now be described in connection with the accompanying drawings, Fig. 1 of which is a sche¬ matic sketch illustrative of the non-textured clumped putty-like, high viscoelastic properties of hydrated vital wheat gluten; Fig. 2 Is a similar sketch of the markedly reduced viscoelastic and somewhat spotted properties produced when a filler of flour and some nutritional leavening is ad¬ mixed with the gluten powder before hydration; Figs. 3 and 4 are photographs of the respective ac¬ tual dry admixture and the hydrated form thereof of Fig. 2; Fig. 5 is a schematic diagram of shredding or parti¬ cularizing the hydrated mixture of Figs. 2-4 into rather critically dimensioned separated streams of fiber-like strands which are allowed to fall freely under gravity into a deposit of loose layers of aerated fiber strands on a retaining surface; Fig. 6 is an actual photograph of such a deposit showing its fiber-textured, particlarized appearance; Fig. 7 is a process flow diagram of the gluten-pro¬ perties physical and cheπrical transforming process of the inventio ; Fig. 8 is a side elevation of an apparatus for apply- ing the technique of the invention to produce a fiber-like textured product analog of ground beef and the like; Fig. 9 is a modification introducing a forming step for shaping an analog "hamburger" pattie or the like; and Figs. 10 and 11 are actual photographs of tne top and section of such an analog product. Description of Invention The first step in the trans ormation of the normal physical and hemical characteristics of hydrated wheat gluten from its usual clumped, untextured, putty-like mass state, with high viscoelasticit —rubbery and adherently binding and elastically resistant to stretching and frac¬ ture, as schematically shown at 1 in Fig. 1—resides in introducing, intimately and thoroughly mixed and inter¬ leaved throughout the initial vital wheat gluten powder, a substantial quantity of particulated filler such as ground grain flour, and preferably a small amount of admixed nutritional (not baker's) yeast, as shown in Fig. 2 and labelled as the first step I of the process flow chart of Fig. 7. Upon appropriate hydration, this has been found very substantially to reduce the viscoelasticity and high elastic tensile strength of the hydrated product, again as visually illustrated In Fig. 2 by the much narrower outer dotted stretch profile than in Fig. 1. While not desiring to be bound by theories, It strongly appears that the in¬ troduction of the flour particles In sufficient quantity between wheat gluten powder prevents the high degree of clumping and tight adhesive binding that occurs when all the gluten powder particles are contiguous. Whether this is or is not the totally correct theory, it is sufficient to describe the steps of the process of the invention as they actually have been found to occur i practice. Using, as an example, Midwest Grain Products, Inc. (Kansas) pulverized dehydrated vital wheat gluten powder in about a half pound sample (Fig. 1) , and hydrating and kneading with about a cup of water at room temperature, tensile strength measurements showed the high viscosity requirement of about 11 to 12 pounds of stretching force to fracture off a piece of the mass. With the same size sample of the dry wheat gluten powder thoroughly admixed with whole grain wheat flour in proportion about 1 part gluten-to-half a part flour by weight, Figs. 2 and 3, the similarly hydrated product (step II in Fig. 7) was found to have a greatly reduced tensile strength, requiring only about one to one and a half pounds to pull off a piece from the much more pliable mass—a considerable re- duction in viscoelasticity and a much looser feel for the product . A further and preferred additive to the dry mix Is a leavening agent of the nutritional yeast type, Figs. 2 and 7, such as that of Universal Foods of Wisconsin, which, unlike baker's yeast, provides both flavor and, during hy- dration, a gentle generation of gaseous bubbles that cause further expansion and some aeration texturing, as at 1 ' in Fig. 2 and in the product of Fig. 4. In Fig. 5 and step III of the process flow chart of Fig. 7, the hydrated product 1 ' (preferably in the propor¬ tion of about 12 ounces of dry mixture to about 8 ounces of water) is fed into a particularizing shredder or grinder 2 to shred and comminute the mass and pressure * — exude or squeeze and stretch into a plurality of adjacent but separated fiber strands 1". The strands fracture as they fall under the influence of gravity (step IV, Fig. 7) and deposit (preferably with about an 8-inch fall, more or less) as loose random layers of strands at 1"'. This stripping of thin strands from the mass and exuding as fiber streams further reduces the already lowered visco- elasticity and creates a true elongated fiber texture. If these are immediately subjected to heated moisture permeating within the total deposit, step V, Fig. 7, before the strand layers have time to coalesce, the hot moisture will permeate into and uniformly through the c loose aerated multi-layer fiber strand deposits 1 '", per¬ mit moisture absorption and thickness swelling of the deposit as the hot moisture fills the voids in between and amongst the fiber layers. With fiber strands of rather critical cross-dimension of about 0.3 inch, as later more T Q fully discussed, and a heated water solution in which they are immersed of the order of about 212°F, it has been found that the continued application of the hot moisture contacting and enveloping the fibers for the order of about 25 minutes, step VI, Fig. 7, substan ially ■ it completely chemically de-natures the protein, permanently eliminating the bulk of the gelatulous viscoelastic pro¬ tein "glue", and physically assuming permanent fibrous texture characteristics. The process of the invention has thus transformed the untextured clump putty, unmanageable elastic adhesively binding mass characteristics of hydrated wheat gluten, tough and resistant to fracturing, into a totally manage¬ able low viscoelastic open fiber-strand textured struc¬ ture, pliable and readily chewable and separable. As before stated, this remarkable physical and chemi¬ cal transformation now allows uses of wheat gluten pre¬ viously impossible with its natural hydrated characteris¬ tics, and enables uses that are primarily the gluten it- self, as distinguished from mere additive and binder uses in other materials. Among such new applica ions, as pre¬ viously discussed, is the important simulation of meat fiber products . With the above fiber strand cross-dimensions, the fiber texture closely resembles the fibers of ground beef, fortuitously providing a ready wheat gluten analog of ham¬ burger when the transformation method of the invention is applied to producing such a product. In this event, appropriate spices, flavorings and vegetable coloring may be introduced into the mixture closely to simulate the appearance and flavors of ground beef or other meat In the myriad of applications for different ethnic tastes, inclu¬ ding, for example, Mexican, middle and far eastern and Italian flavors, among others. After cooling and some eva- poration and shrinkage, step VIII in the process flow chart of Fig. 7, that analog product may be broiled , boiled, fried, grilled or otherwise prepared in the same manner as ground beef or the like, or refrigerated or flash—frozen for subsequent final cooking. A suitable apparatus for the hot moisture denaturing steps V and VI for the production of ground meat protein analogs is shown in Fig. 8, where the strands 1" are deposited upon a screen belt S and carried through a hot water bath or tank W, immersing the deposits 1 ' " in the heated water as they are carried through the tank. As before stated, nearly a half an hour of such immersion at about 212°F has been found to be sufficient to effect the substantial denaturation of the gluten protein and the permanent desired alteration or transformati n of the phy¬ sical and chemical properties as above described. The heated bath may also contain appropriate flavorings or colorings, if desired. The product may be totally "vege¬ tarian", or, If desired, in the mixture hydration stage or in the hot moisture immersion stage or otherwise, meat bullion (beef, pork, poultry, etc.) or other flavorings may be used to produce a genuine meat flavor to the gluten meat analog product. It has further been found most desirable for preven¬ ting separation or friable effects during the heated mols- ture treatment, to restrain the deposit from movement, such as tumbling that can break up the deposit, or elonga¬ tion. The use of a screen surface S admirably serves this function since, as the strands are deposited at 1 '", they tend to stick or lock Into the screen openings. After completion of the denaturing process at the far end of the tank W, the screen belt S may reverse direction, as shown, and transfer the product to a further belt S' . Clearly other well-known apparatus may also be adapted for these purposes, as well. Where shaped patties, loafs or other forms are desired, instead of chunks suitable, for example, for pizza toppings or pasta dishes or the like, a shaping form may be Introduced before the prompt hot moisture treatment as at F in Fig. 9. Figs. 10 and 11 show the actual sub¬ stantially indistinguishable appearance and texture from meat hamburger patties; aτιd the chew, mouthfeel and taste sensation are also indistinguishable—a totally grain pro¬ tein realistic analog, and with the added advantage of no fat. With this fiberizing by comminuting or the grindlng- shredding of the mass mixture and forcing or squeezing exuded stretched strands of appropriate cross dimension that are then denatured, the per unit volume adhesion or viscoelasticity Is much further reduced to a very low value, totally comparable to ground meat, and just enough to hold the analog together. As previously stated, how- ever, a certain crltlcality to cross-dimension of the exu¬ ded strands has been noted. With small cross—dimensIons of the order of about 0.1 inch or less, minimal or no fiber texture results after protein denaturation, the pro¬ duct appearing solid, mushy and friable. With strands as large as about 0.6 inch or greater, the strands tend to clump and an uneven texture results. The bef re—ment1oned cross-dimension range of the order of about 0.3 inch has experimentally been found consistently to produce uniform textured fiber layers throughout the product. The relative proportion of grain flour or other filler in the dry mix may be varied for different applica¬ tions, generally ranging "from about 1:0.5 to about 1:0.15, by weight. The preferred grind of whole grain wheat flour has been found to be 3-265 milling grind, in order to be °f appropriate grain size for its required function, before described. The proportion of nutritional yeast is preferably of the order of about eight percent by weight. The added water of hydration is preferably in the ratio of about 12 ounces dry mix to about 8 ounces, as before mentioned . Further modifications, however, will occur to those skilled in this art and such are considered to fall within the spirit and scope of the invention as defined in the appended claims.

Claims: CLAIMS 1. A method of permanently transforming clumped putty-like untextured mass and relatively high viscoelastic adhesion physical and chemical properties of hydrated vital wheat gluten into a loose layered minimally adhering textured fiber strand structure, that comprises, intimately mixing flour with vital wheat gluten powder to interleave with and separate the gluten powder particles in a mixture; at substantially room temperature, hydrating the mixture to enable absorption of water by the mixture to expand the gluten into a less viscoelastic mass; shredding the mass into a plurality of separated streams of strands of elongated continuous fibers; dropping the separate strands under the action of gravity as a loose deposit upon a retaining surface; immediately subjecting the deposit to heated moisture along the separate fibers within and throughout the deposit; continuing the application of heated moisture for a sufficient time for protein of the separate fibers within the deposit to become substantially denatured, to remove the bulk of the viscoelastic adhesion properties of the gluten, and permitting evaporation of excess moisture from the deposit to produce a loose layered permanent fiber structure of relatively low retained viscoelasticity. 2. A method as claimed in claim 1 and in which temperature of the heated moisture is of the order of about 212°F. 3. A method as claimed in claim 2 and in which said sufficient time for denaturing is of the order of about 25 minutes. 4. A method as claimed in claim 2 and in which weight proportion of gluten powder to flour is in the range of from about 1 :0.5 to about 1:0.15. 5. A method as claimed in claim 1 and in which a leavening agent is added to said mixture before hydrating. 6. A method as claimed in claim 5 and in which said leavening agent comprises nutritional yeast. 7. A method as claimed in claim 1 and in which, upon the deposits dropping upon the ret∑tining surface, the surface is passed through a heated water tank to effect the moisture absorption and the ultimate gluten fiber denaturation. 8. A method as claimed in claim 7 and in which, prior to passing the deposit-carrying retaining surface through the tank, the deposit is formed into a predetermined shape. 9. A method as claimed in claim 7 and in which the deposits are restrained from tumbling and elongation during the heated water treatment. 10. A method as claimed in claim 1 and in which the fibers produced by the shredding are of dimensions similar to those of ground meat. 11. A method as claimed in claim 10 and in which the cross-dimension of the fibers is of the order of about 0.3 inches. 12. A wheat gluten analog for ground meat formed by the method of claim 10. 13. A wheat gluten analog as claimed in claim 12 and in which the composition of the analog is 1 part wheat gluten and from about 0.5 to 0.15 part flour, by weight. 14. A wheat gluten analog for pieces, parties and loaves of ground beef hamburger, comprising loose layers of fiber strands of heat-denatured vital wheat gluten. 15. A wheat gluten analog as claimed in claim 13 formed from a dry mixture of vital wheat gluten protein powder and grain flour, and with added nutritional leavening agent and spices. 16. A method of producing a vital wheat gluten analog of ground meat, such as hamburger, by transforming clumped putty-like untextured mass and relatively high viscoelastic adhesion physical and chemical properties of hydrated vital wheat gluten into a loose layered minimally adhering textured fiber strand structural analog of the ground meat, the method comprising, intimately mixing grain flour particles with vital wheat gluten powder particles and nutritional yeast to interleave the flour particles with and separate the gluten powder particles in a mixture, the weight ratios of gluten powder particles to flour particles being of the order of from about 1 :0.5 to about 1:0.15; at substantially room-temperature, hydrating the mixture in a ratio of the order of about 12 ounces of mixture to about 8 ounces of water to enable the absorption of water by the mixture to expand the gluten into a less viscoelastic mass; grinding and extruding the mass into a plurality of separated streams of strands of elongated continuous fibers of cross-dimension of the order of about 0.3 inch; dropping the separated strands under the action of gravity as a loose deposit upon a retaining surface; immediately immersing the deposit in heated water of about 212°F wetting the separate fibers within and throughout the deposit; continuing the heated water immersion for a sufficient time of the order of about 25 minutes for the protein of the separate fibers within the deposit to become substantially denatured, to remove the bulk of the viscoelastic adhesion properties of the gluten, simulating ground meat fibers; and permitting evaporation of excess moisture from and shrinkage of the cooling deposit to produce a loose layered permanent fiber structural analog of the ground meat. 17. A method as claimed in claim 16 and in which, after droppings of the deposits, they are formed into a predetermined shape of hamburger patties or loaves, before immersion in heated water. 18. A method as claimed in claim 17 and in which flavouring and colouring are added to the mixture further to simulate the ground meat product. 19. A method as claimed in claim 18 and in which the analog is cooked in the same manner generally employed with ground meat products. 20. A method as claimed in claim 17 and in which the analog is fast frozen for subsequent cooking. 21. A food product made by the method as claimed in any one of the preceding claims.

Inventors: HUBER CYNTHIA, LONGO NANCY, HUBER, CYNTHIA, LONGO, NANCY
Applicants: HUBER CYNTHIA, LONGO NANCY, HUBER, CYNTHIA, LONGO, NANCY
Application year: 1996
Main classification: A23J3
IPC codes: A23J3, A23L1