Abatement of hydrogen sulfide with an aldehyde ammonia trimer

Abstract: The present invention provides a method for scavenging H 2 S from aqueous and hydrocarbon substrates, preferably natural gas, using aldehyde ammonia trimers.

Description: The invention relates to chemical compositions and methods for scavenging sulfhydryl compounds, particularly hydrogen sulfide (H 2 S), from "sour' aqueous and hydrocarbon substrates. More particularly the invention relates to the use of aldehyde ammonia trimers as scavengers for sulfhydryl compounds in natural gas. The removal of H 2 S from a liquid or gaseous hydrocarbon stream is a problem that has challenged many workers in many industries. One such industry is the petroleum industry, where the H 2 S content of certain crudes from reservoirs in many areas of the world is too high for commercial acceptance. The same is true of many natural gas streams. Even where a crude or gas stream contains only a minor amount of sulfur, the processes to which the crude oil or fractions thereof are subjected often produce one or more hydrocarbon streams that contains H 2 S. The presence of H 2 S in hydrocarbon streams presents many environmental and safety hazards. Hydrogen sulfide is highly flammable, toxic when inhaled, and strongly irritates the eyes and other mucous membranes. In addition, sulfur-containing salts can deposit in and plug or corrode transmission pipes, valves, regulators, and the like. Flaring of natural gas that contains H 2 S does not solve the problem for gas streams because, unless the H 2 S is removed prior to flaring, the combustion products will contain unacceptable amounts of pollutants, such as sulfur dioxide (SO 2 )--a component of "acid rain." Hydrogen sulfide has an offensive odor, and natural gas containing H 2 S often is called "sour" gas. Treatments to reduce or remove H 2 S from hydrocarbon or other substrates often are called "sweetening" treatments. The agent that is used to remove or reduce H 2 S levels sometimes is called a "scavenging agent." The sweetening or scavenging of H 2 S from petroleum or natural gas is only one example of where H 2 S level reduction or removal must be performed. Many aqueous substrates also must be treated to reduce or remove H 2 S. In the manufactured gas industry, or the coke-making industry, the destructive distillation of bituminous coal with a high sulfur content commonly produces coal gas containing an unacceptable amount of H 2 S. Another H 2 S contamination problem arises during the manufacture of water gas or synthesis gas. Water gas or synthesis gas streams that contain H 2 S often are produced by passing steam over a bed of incandescent coke or coal. The incandescent coke or coal often contains a minor amount of sulfur, which contaminates the resulting gas stream. The problem of removing or reducing H 2 S from hydrocarbon and aqueous substrates has been solved in many different ways in the past. Most of the known techniques involve either (a) absorption, or selective absorption by a suitable absorbent, after which the absorbent is separated and the sulfur removed to regenerate and recycle the absorbent, or (b) selective reaction with a reagent that produces a readily soluble product. A number of known systems treat a hydrocarbon stream with an amine, an aldehyde, an alcohol, and/or a reaction product thereof. WO 92/01481 discloses as preferred sulfide-reducing agents compounds of the following Formula I: wherein R' is hydrogen; lower alkyl, such as CH 3 -, CH 3 -CH 2 -, CH 3 CH 2 CH 2 -, (CH 3 ) 2 CH-; hydroxyalkyls of lower alkyl groups, such as HOCH 2 CH 2 -, HOCH 2 -, HO(CH 3 )CH-; and N,N-dialkylalkylene amines of lower alkyl groups, such as (CH 3 ) 2 NCH 2 - or (C 2 H 5 ) 2 NCH 2 -; and R" is selected from hydrogen or lower alkyl, such as CH 3 -, or CH 3 -CH 2 -. In accordance with EP-0 636 675, an H 2 S sour gas or liquid hydrocarbons are treated with 1,3,5-trimethyl-hexahydro-1,3,5 triazine to reduce the level of H 2 S and mercaptans therein. The 1,3,5-trimethyl-hexahydro-1,3,5 triazine may be represented by the following formula (FORMULA I): WO 94/08980, inter alia, relates to a method for reducing the levels of hydrogen sulfide (H 2 S) in a gaseous or liquid stream containing H 2 S comprising adding to said stream an amount of a mixture of amines effective to reduce the H 2 S level, where the mixture of amines comprises a hexahydrotriazine of the formula: where R 1 , R 3 and R 5 are independently selected from the group consisting of hydrogen and an alkyl radical, including substituted alkyl radicals of 1-5 carbon atoms and where R 2 , R 4 and R 6 are independently selected from the group consisting of hydrogen and an alkyl radical, including substituted alkyl radicals of 1-5 carbon atoms; and where at least one of the R 1 , R 2 , R 3 , R 4 , R 5 and R 6 groups is an alkoxyalkylene group. The wide variety of processes, patents, and publications that describe methods for removing H 2 S from hydrocarbon streams is evidence that it is desirable and necessary to remove H 2 S from aqueous and hydrocarbon streams. A continuing need exists for alternative processes and compositions to reduce and/or remove H 2 S from aqueous and hydrocarbon substrates. The present invention provides a method for scavenging H 2 S from aqueous and hydrocarbon substrates, preferably natural gas, comprising mixing said substrate with an effective amount of a scavenging agent essentially consisting of an aldehyde ammonia trimer having the following general structure: wherein R 1 , R 2 , and R 3 are independently selected from the group consisting of hydrogen and hydrocarbon groups having between 1-8 carbon atoms, selected from the group consisting of straight, branched, and cyclic alkyl groups, aryl, alkaryl, and aralkyl groups, and heterocyclic alkyls containing oxygen or tertiary nitrogen as a ring constituent. In a preferred embodiment, R 1 , R 2 , and R 3 are methyl groups. The scavenging agents of the present invention may be used to treat aqueous and hydrocarbon substrates that are rendered "sour" by the presence of "sulfhydryl compounds", such as hydrogen sulfide (H 2 S), organosulfur compounds having a sulfhydryl (-SH) group, known as mercaptans, also known as thiols (R-SH, where R is a hydrocarbon group), thiol carboxylic acids (RCO-SH), dithio acids (RCS-SH), and related compounds. As used in this application, the term "aqueous substrate" refers to any "sour" aqueous substrate, including waste water streams in transit to or from municipal waste water treatment facilities, tanning facilities, and the like. The term "hydrocarbon substrate" is meant to include unrefined and refined hydrocarbon products, including natural gas, derived from petroleum or from the liquefaction of coal, both of which contain hydrogen sulfide or other sulfur-containing compounds. Thus, particularly for petroleum-based fuels, the term "hydrocarbon substrate" includes wellhead condensate as well as crude oil which may be contained in storage facilities at the producing field. "Hydrocarbon substrate" also includes the same materials transported from those facilities by barges, pipelines, tankers, or trucks to refinery storage tanks, or, alternately, transported directly from the producing facilities through pipelines to the refinery storage tanks. The term "hydrocarbon substrate" also includes refined products, interim and final, produced in a refinery, including distillates such as gasolines, distillate fuels, oils, and residual fuels. As used in the claims, the term "hydrocarbon substrate" also refers to vapors produced by the foregoing materials. A wide variety of aqueous and hydrocarbon substrates can be treated using the scavenging agents of the present invention, a preferred substrate being natural gas. The trimers preferably should be added to the substrate at a high enough temperature that the substrate is flowable for ease in mixing. The treatment may take place at temperatures up to the temperature at which the material being treated begins to decompose. Preferred treatment temperatures are between ambient to about 65.6°C (150°F). The aldehyde ammonia trimers of the present invention exhibit a high uptake capacity for hydrogen sulfide, and the raw materials required to manufacture the trimers are low cost materials. Aldehyde ammonia trimers are commercially available in small quantities from Aldrich Chemical Co., Milwaukee, Wisconsin. Aldehyde ammonia trimers also may be manufactured by reacting acetaldehyde with aqueous ammonia in a 1:1 molar ratio. Water or another solvent, such as methanol, can be used in the reaction to prevent solid trimer from precipitating out of the solution. The amount of water used may vary depending upon how the product will be used. For example, if the substrate will be hydrophobic, e.g. , a dry oil phase, the trimer may be formulated in isopropanol rather than water. In the field, the trimer preferably should be used in a solution having an active concentration of about 2-30%, preferably about 10-20%. In a preferred embodiment, the substrate is natural gas and the trimer is added at a stoichiometric ratio of at least one molecule of trimer per three molecules of H 2 S. The ratio preferably should be somewhat higher than 1:3 to assure abatement of H 2 S. Preferably, between about 0.8-1.7 ppm of scavenger should be added per ppm of H 2 S, most preferably about 1.3 ppm per 1 ppm of H 2 S. The amount of H 2 S in the natural gas may be measured by standard means. For ease in measurement, about 3 . 8 1 (one gallon) of the 10-20% active trimer solution may be added for every 0.45 kg (one pound) of H 2 S. The aqueous or hydrocarbon substrates should be treated with the scavenging agent until reaction with hydrogen sulfide, or with other sulfhydryl compounds, has produced a product in which the sulfhydryls in the vapor (or liquid) phase have been removed to an acceptable or specification grade product. Typically, a sufficient amount of scavenging agent should be added to reduce the sulfhydryls in the vapor phase to at least about 4 ppm or less. The invention will be better understood with reference to the following examples: Experimental Procedures The Bubble Tower Test In the following examples, the effectiveness of the scavenging agent is tested in an apparatus known as a "bubble tower." The "bubble tower" is a transparent acrylic column having a preferred internal diameter of 31.8 mm (1.25 inches). In order to test a particular scavenging agent, a solution of the scavenging agent is placed in the column to a given height, and gas having a known composition is bubbled through the solution. In the following experiments: the gas contains 2000 ppm H 2 S, 1% CO 2 , and a balance of methane; the H 2 S content of the gas exiting the solution is measured at given time intervals; and, measurements are made using stain tubes obtained from Sensidyne Gastech, located in Largo, Florida. The solution is observed for foaming and for precipitate formation, both of which are undesirable. Generally, only candidates that exhibit minimum foaming and little to no precipitate formation are selected for further study. Foaming may be desirable for some applications; however, foaming generally is undesirable when treating natural gas in a bubble tower. The amount of foaming that results using a given candidate generally may be altered using defoaming compositions. In the following examples, foaming is given as a measure of column height. Basically, the less the increase in column height, the less foam has been generated by the candidate. To perform the "bubble tower" test, the following steps are performed: 1. Prepare 100 grams of a bulk dilution or a 5% active solution (if activity is known) of the scavenging agent in distilled water; 2. Place the solution in the "bubble tower" and pressurize the solution to 138 kPa (20 psi). 3. Adjust the flow rate of the test gas to 0.15 m 3 /h (5.5 standard cubic feet per hour ( scfh) 4. Record the outlet H 2 S concentration at 1, 5, 10, and 15 minutes and every 15 minutes thereafter until H 2 S levels reach inlet levels. 5. Observe for foaming and solids formation up to 24 hrs. The Uptake Test The uptake test determines the activity of a particular candidate by measuring the weight gain of the candidate before and after exposure to pure H 2 S gas. Basically, 100 grams of a 5% solution of candidate in water is placed in a graduated cylinder with a dispersion stone and the total weight of the solution and the cylinder is measured using a balance. Thereafter, pure H 2 S gas is bubbled through the cylinder at 28.317·10 -3 m 3 /h (1 scfh). The weight of the solution is monitored until the weight remains substantially constant. The weight gain is a measure of the activity of the candidate. Example 1 Aldehyde trimer for use in the following experiments was prepared as follows. A 500 ml three-necked reaction flask containing 169.4 g of 28% by weignt aqueous ammonia and equipped with a magnetic stirrer, a reflux condenser, a pressure equalizing dropping funnel, and a thermometer was cooled in an ice bath. Chilled acetaldehyde (122.8 g) was added dropwise at such a rate as to keep the internal temperature below 30°C (86°F) to yield a white suspension. The suspension was dissolved by adding 107.6 g of methanol and 40.0 g of water to yield a colorless solution containing 27.25% by weight reaction product. Proton and carbon NMR spectroscopy performed on the solution before and after the dissolution in methanol and water confirmed that the primary reaction product was an aldehyde ammonia trimer having the following structure: Example 2 The aldehyde ammonia trimer prepared in Example 1 was used to scavenge sulfur-containing compounds from natural gas. The efficacy of the aldehyde ammonia trimer was tested using the bubble tower test, described under "Experimental Procedures." The H 2 S concentration in the outlet gas and the change in height due to foaming are reflected in Table I: TIME OUTLET [H 2 S] (ppm) COLUMN HEIGHT (cm) (inches) 1 minute 0 17.8 (7) 5 minutes 0 15.2 (6) 10 minutes 0 15.2 (6) 15 minutes 0.1 30.5 (12) 30 minutes 4.2 30.5 (12) 45 minutes 10 30.5 (12) 60 minutes 60 30.5 (12) 75 minutes 90 minutes 1300 30.5 (12) 105 minutes 1600 27.9 (11) 120 minutes 1600 27.9 (11) After 24 hours, a 2 phase liquid reaction product was formed which contained no solids. Example 3 The aldehyde ammonia trimer of Example 1 was used in the "Uptake Test" outlined under "Experimental Procedures." The scavenger solution was made using 5.15 gm of aldehyde ammonia trimer. The results are given in Table II: MINUTES WEIGHT OF CYLINDER (GM) 0 199.9 5 202.3 10 202.9 15 203.3 20 203.4 OVERALL WEIGHT CHANGE +3.5 Example 4 Aldehyde ammonia trimer, prepared as set out in Example 1, was used to scavenge sulfur-containing compounds from natural gas. The efficacy of the aldehyde ammonia trimer was tested using the bubble tower test, described under "Experimental Procedures." The bubble tower used in this example had an internal diameter of 28.57 mm (1.125") rather than 31.8 mm (1.25"). The H 2 S concentration in the outlet gas and the change in height due to foaming are reflected in Table III: TIME OUTLET [H 2 S] (ppm) COLUMN HEIGHT cm (inches) 1 minute 0 33.0 (13+) 5 minutes 0 27.9 (11) 10 minutes 2 25.4 (10) 15 minutes 1.5 22.8 (9) 30 minutes 11 22.8 (9) 45 minutes 61 27.9 (11) 60 minutes 275 30.5 (12) 75 minutes 1200 33.0 (13+) 90 minutes 1600 33.0 (13+) Example 5 Aldehyde ammonia trimer was prepared as set out in Example 1, and used to scavenge sulfur-containing compounds from natural gas. 17.0 gm of the resulting trimer was diluted to a total of 100 gm of solution in distilled water. The efficacy of the aldehyde ammonia trimer was tested using a bubble tower with an internal diameter of 31.8 mm (1.25"). The H 2 S concentration in the outlet gas and the change in height due to foaming are reflected in Table IV: TIME OUTLET [H 2 S] (ppm) COLUMN HEIGHT (cm) (inches) 0 minute 0 33.0 (13) 5 minutes 0 30.5 (12) 10 minutes 0.9 27.9 (11) 15 minutes 1.0 30.5 (12) 30 minutes 7.0 30.5 (12) 45 minutes 24 30.5 (12) 60 minutes 125 30.5 (12) 75 minutes 900 30.5 (12) 90 minutes 1350 30.5 (12) 105 minutes 1600 30.5 (12) No solids formed in the test solution after 24 hours. Example 6 Aldehyde ammonia trimer was prepared as set out in Example 1, and the procedures given in Example 5 were repeated. The H 2 S concentration in the outlet gas and the change in height due to foaming are reflected in Table IV: TIME OUTLET [H 2 S] (ppm) COLUMN HEIGHT (cm) (inches) 0 minute 0 27.9 ((11) 5 minutes 0 22.8 (9) 10 minutes 1.0 22.8 (9) 15 minutes 1.0 22.8 (9) 30 minutes 7.0 20.3 (8) 45 minutes 24 20.3 (8) 60 minutes 125 20.3 (8) 75 minutes 900 30.5 (12) 90 minutes 1350 30.5 (12) 105 minutes 1600 30.5 (12) Less than 1% by volume of crystalline solid precipitate formed after 24 hours. Example 7 The uptake test was performed on a 5% active solution of aldehyde ammonia trimer prepared as in Example 1 and the Uptake Test was performed. The total H 2 S uptake was 4.6 gm. Example 8 Acetaldehyde trimer obtained from Aldrich Chemical Co. was used to prepare a 4.23% active solution and the Uptake Test was performed. The total H 2 S uptake was 3.5 gm. The foregoing examples demonstrate that the aldehyde trimers of the present invention exhibit high uptake efficiency for hydrogen sulfide, do not exhibit an undesirable level of foaming, and do not exhibit an undesirable level of precipitate formation.

Claims: A method for scavenging sulfhydryl compounds from sour aqueous and hydrocarbon substrates comprising mixing said substrate with an effective amount of a scavenging agent essentially consisting of an aldehyde ammonia trimer having the following general structure: wherein R 1 , R 2 , and R 3 are independently selected from the group consisting of hydrogen and hydrocarbon groups having between 1-8 carbon atoms, selected from the group consisting of straight, branched, and cyclic alkyl groups, aryl, alkaryl, and aralkyl groups, and heterocyclic alkyls containing oxygen or tertiary nitrogen as a ring constituent. The method of Claim 1 wherein R 1 , R 2 , and R 3 are methyl groups. The method of Claim 1 or 2 wherein said substrate is natural gas. The method of one of Claims 1 to 3 wherein said substrate is treated at a temperature of between ambient to about 65.6°C (150°F). The method of one of Claims 1 to 3 wherein said effective amount of said scavenging agent is between about 0.8-1.7 ppm of scavenger for every 1 ppm of hydrogen sulfide in substrate. Aqueous and hydrocarbon substrates comprising an amount of aldehyde ammonia trimer sufficient to scavenge sulfhydryl compounds from said substrate, wherein said aldehyde ammonia trimer has the following general structure: wherein R 1 , R 2 , and R 3 are independently selected from the group consisting of hydrogen and hydrocarbon groups having between 1-8 carbon atoms, selected from the group consisting of straight, branched, and cyclic alkyl groups, aryl, alkaryl, and aralkyl groups, and heterocyclic alkyls containing oxygen or tertiary nitrogen as a ring constituent. The substrate of Claim 6 wherein R 1 , R 2 , and R 3 are methyl groups. The substrate of Claim 6 or 7 wherein said substrate comprises natural gas.

Inventors: CALLAWAY MICHAEL, RIVERS GORDON T, CALLAWAY, MICHAEL, RIVERS, GORDON T.
Applicants: BAKER HUGHES INC, BAKER HUGHES INCORPORATED
Application year: 1996
Main classification: C10L3
IPC codes: C10G21, C10G29, C10L3