ETHYLENE OXIDE CATALYST AND PROCESS FOR ITS PRODUCTION

Abstract: This invention relates to an ethylene oxide catalyst having improved initial selectivity which catalyst comprises silver, a promoting amount of alkali metal, a promoting amount of rhenium and a promoting amount of rhenium co-promoter selected from phosphorous, boron and mixtures thereof, supported on a porous refractory support.

Description: ETHYLENE OXIDE CATALYST AND PROCESS FOR ITS PRODUCTION The invention relates to silver-containing catalysts suitable for the preparation of ethylene oxide and to the use of the catalysts for the preparation of ethylene oxide. Catalysts for the production of ethylene oxide from ethylene and molecular oxygen are generally supported silver catalysts. Such catalysts are typically promoted with alkali metals. Small amounts of the alkali metals potassium, rubidium and cesium were noted as useful promoters in supported silver catalysts in U.S. Patent No. 3,962,136, issued June 8, 1976, and U.S. Patent No. 4,010,115, issued March 1, 1977. The use of other co-promoters, such as rhenium, or rhenium along with sulfur, molybdenum, tungsten and chromium is disclosed in U.S. Patent No. 4,766,105, issued August 23, 1988, and U.S. Patent No. 4,808,738, issued February 28, 1989. It has now been found that catalysts containing one or both of phosphorus and boron as rhenium co-promoters have higher initial selectivities than those obtained with catalysts containing no rhenium co-promoter. The invention therefore relates to a catalyst for the production of ethylene oxide catalyst from ethylene and molecular oxygen in the vapor phase which catalyst comprises a catalytically effective amount of silver, a promoting amount of alkali metal, a promoting amount of rhenium and a rhenium co-promoter selected from phosphorus, boron and mixtures thereof supported on a porous, refractory support. Generally, in the vapor phase reaction of ethylene with oxygen to produce ethylene oxide, the ethylene is present in at least a double amount (on a molar basis) compared with oxygen, but frequently is often much higher. Therefore, the conversion is calculated according to the mole percentage of oxygen which has been consumed in the reaction to form ethylene oxide and any oxygenated by-products. The oxygen conversion is dependent on the reaction temperature, and the reaction temperature is a measure of the activity of the catalyst employed. The value T40 indicates the temperature at 40 mole percent oxygen conversion in the reactor and T is expressed in °C. This temperature for any given catalyst is higher when the conversion of oxygen is higher. Moreover, this temperature is strongly dependent on the employed catalyst and the reaction conditions. The selectivity (to ethylene oxide) indicates the molar amount of ethylene oxide in the reaction product compared with the total molar amount of ethylene converted. In this specification, the selectivity is indicated as S 0, which means the selectivity at 40 mole percent oxygen conversion. The initial selectivity of a catalyst is important because less ethylene is wasted in forming undesired by-products, thus increasing the overall efficiency and advantaging the economics of the more selective process. Additionally, increased selectivity can allow a process to operate at a lower conversion to obtain the same amount of ethylene oxide, thus allowing the process to operate at a lower temperature. As used herein, "selectivity" is used to refer to the selectivity of ethylene oxide catalysts when measured at a given constant oxygen conversion level of 40% at a gas hourly space velocity of approximately 3300 and when measured after the catalyst has been placed on stream for at least several days. The catalysts of the instant invention comprise a catalytically effective amount of silver, a promoting amount of alkali metal, a promoting amount of rhenium and a promoting amount of a rhenium co-promoter selected from phosphorus, boron and mixtures thereof, supported on a porous, refractory support. In general, the catalysts of the present invention are prepared by impregnating porous refractory supports with silver ions or compound(s), complex(es) and/or salt(s) dissolved in a suitable solvent sufficient to cause deposition on the support of from about 1 to about 25 percent by weight, basis the weight of the total catalyst, of silver. The impregnated support is then separated from the solution and the deposited silver compound is reduced to metallic silver. Also deposited on the support either prior to, coincidentally with, or subsequent to the deposition of the silver will be suitable ions, or compound(s) and/or salt(s) of alkali metal dissolved in a suitable solvent. Also deposited on the support either prior to, coincidentally with, or subsequent to the deposition of the silver and/or alkali metal will be suitable rhenium ions or compound(s) , complex (es) and/or salt(s) dissolved in an appropriate solvent. Also deposited on the carrier either prior to, coincidentally with, or subsequent to the deposition of the silver and/or alkali metal and/or rhenium will be suitable ions or salt(s), complex(es) and/or compound(s) of phosphorus and/or boron dissolved in an appropriate solvent. The carrier or support employed in these catalysts in its broadest aspects can be any of the large number of conventional, porous refractory catalyst carriers or support materials which are considered relatively inert in the presence of ethylene oxidation feeds, products and reaction conditions. Such conventional materials are known to those skilled in the art and may be of natural or synthetic origin and preferably are of a macroporous structure, i.e., a structure having a surface area below 10 m 2 /g and preferably below 3 m 2 /g. Particularly suitable supports are those of aluminous composition, in particular those comprising alpha alumina. In the case of alpha alumina-containing supports, preference is given to those having a specific surface area as measured by the B.E.T. method of from about 0.03 m 2 /g to about 10 mVg, preferably from about 0.05 m 2 /g to about 5 m 2 /g, more preferably from about 0.1 m 2 /g to about 3 m 2 /g, and a water pore volume as measured by conventional water absorption techniques of from about 0.1 to about 0.75 cc/g by volume. The B.E.T. method for determining specific surface area is described in detail in Brunauer, S., Emmet, P. Y. and Teller, E., J. Am. Chem. Soc, 60, 309-16 (1938) . The catalysts of the present invention are prepared by a technique in which the alkali metal promoters, the rhenium, and the rhenium co-promoter, in the form of soluble salts and/or compounds are deposited on the catalyst and/or support prior to, simultaneously with, or subsequent to the deposition of the silver and each other. The preferred method is to deposit silver, alkali metal, rhenium and rhenium co-promoter simultaneously on the support, that is, in a single impregnation step. Promoting amounts of alkali metal or mixtures of alkali metal are deposited on a porous support using a suitable solution. Although alkali metals exist in a pure metallic state, they are used as ions or compounds of alkali metals dissolved in a suitable solvent for impregnation purposes. The amount of alkali metal promoter deposited upon the support or present on the catalyst generally lies between 10 and 3000, preferably between 15 and 2000 and more preferably between 20 and 1500, most preferably between 50 and 1000 parts per million by weight of the total catalyst. The alkali metal promoters are present on the catalysts in the form of cations or compounds of complexes rather than as the extremely active free alkali metals, although for convenience purposes they are referred to as "alkali metal" or "alkali metal promoters" . Without intending to limit the scope of the invention, it is believed that the alkali metal compounds are oxidic compounds. In a preferred embodiment, at least a major proportion (greater than 50%) of the alkali metals comprise the higher alkali metals, i.e. the alkali metals selected from the group consisting of potassium, rubidium, cesium and mixtures thereof. A particularly preferred alkali metal promoter is cesium plus at least one additional alkali metal, preferably selected from sodium, lithium and mixtures thereof, with lithium being preferred. It should be understood that the amounts of alkali metal promoters on the catalysts are not necessarily the total amounts of these metals present in the catalyst. These amounts do not include amounts of alkali metals which are locked into the support, for example, by calcining, or are not extractable in a suitable solvent such as water or lower alkanol or amine or mixtures thereof and do not provide a promoting effect. It is also understood that a source of the alkali metal promoter ions, salts and/or compounds used to promote the catalyst may be the carrier. That is, the carrier may contain extractable amounts of alkali metal that can be extracted with a suitable solvent, such as water or lower alkanol . The carrier is also impregnated with rhenium ions, salt(s) , compound (s), and/or complex (es) . This may be done at the same time that the alkali metal promoter is added, or before or later; or at the same time that the rhenium co-promoter is added, or before or later. Preferably, rhenium, alkali metal, rhenium co-promoter and silver are in the same impregnating solution. The preferred amount of rhenium, calculated as the metal, deposited on or present on the carrier or catalyst ranges from 0.1 to 10, more preferably from 0.2 to 5 micromoles per gram of total catalyst, or, alternatively stated, from 19 to I860, preferably from 37 to 930 parts per million by weight of total catalyst. The rhenium compounds used in the preparation of the instant catalysts are rhenium compounds that can be solubilized in an appropriate solvent. Preferably, the solvent is a water-containing solvent. More preferably, the solvent is the same solvent used to deposit the silver and the alkali metal promoter. Examples of suitable rhenium compounds include the rhenium salts such as rhenium halides, the rhenium oxyhalides, the " rhenates, the perrhenates, the oxides and the acids of rhenium. A preferred compound for use in the impregnation solution is the perrhenate, preferably ammonium perrhenate. However, the alkali metal perrhenates, alkaline earth metal perrhenates, silver perrhenates, other perrhenates and rhenium heptoxide can also be suitably utilized. Rhenium heptoxide, Re-O.,, when dissolved in water, hydrolyzes to perrhenic acid, HReO., or hydrogen perrhenate. In a preferred embodiment of the instant invention, the rhenium present on the catalyst is present in a form that is extractable in a dilute aqueous base solution. The carrier is also impregnated with a rhenium co-promoter selected from the group consisting of phosphorus, boron and mixtures thereof. Since the co-promoter is applied to catalyst in the form of ions, salts, compounds and/or complexes and the reducing conditions generally used to reduce the silver to metallic silver are not usually sufficient to reduce the phosphorus or boron to the elemental form, it is believed that the co-promoter deposited on the support or present on the catalyst is in the compound form, and probably in - 1 - the form of an oxygen-containing or oxidic compound. In a presently preferred embodiment, the co-promoter is applied to the catalyst in the oxyanionic form. Examples of anions of phosphorus that can be suitably applied include phosphate, i.e., ortho-phosphate, hydrogen phosphate, dihydrogen phosphate, metaphosphate, fluorophosphate, pyrophosphate, hypophosphate, diphosphate, triphosphate, etc. Examples of anions of boron that can suitably be applied include borate, metaborate, tetraborate, tetrafluoroborate, etc. The anions can be supplied with various counter-ions. Preferred are ammonium, alkali metal, mixed alkali metal and hydrogen (i.e. acid form). The anions can be prepared by the reactive dissolution of various non-anionic materials such as the oxides such as 2O5 B2O3, etc., as well as other materials such as halides, oxyhalides, hydroxyhalides, hydroxides, sulfides, etc., of the metals. The carrier may be impregnated with rhenium co-promoter ions, salt(s), compound(s) and/or complex(es) at the same time that the other components are added, or before and/or later. Preferably, rhenium co-promoter, rhenium, alkali metal and silver are in the same impregnating solution, although it is believed that their presence in different solutions will still provide suitable catalysts. The preferred amount of co-promoter compound present on or deposited on the support or catalyst ranges from 0.1 to 10, preferably from 0.2 to 5 micromoles, expressed as the element, per gram of total catalyst. For purposes of convenience the amount of co-promoter present on the catalyst is expressed as the element irrespective of the form in which it is present. The presence of the indicated and claimed promoting amount of rhenium co-promoters in this specification and claims does not preclude the use of other activators, promoters, enhancers, stabilizers, improvers, etc.. The co-promoter compounds, salts and/or complexes suitable for use in the preparation of the instant catalysts are compounds, salts and/or complexes which can be solubilized in an appropriate solvent. Preferably, the solvent is a water-containing solvent. More preferably, the solvent is the same solvent used to deposit the silver, alkali metal promoter and rhenium. Preferred co-promoter compounds are the oxyanionic compounds of the co-promoter elements, preferably the ammonium and alkali metal oxyanionates, such as ammonium phosphate, potassium phosphate, lithium phosphate, sodium phosphate, potassium hydrogen phosphate, potassium dihydrogen phosphate, potassium borate, lithium borate, sodium borate, potassium metaborate, lithium metaborate, sodium metaborate, potassium tetraborate, sodium tetraborate, lithium tetraborate and the like. Generally, the carrier is contacted with a silver salt, a silver compound, or a silver complex which has been dissolved in an aqueous solution, so that the carrier is impregnated with said aqueous solution; thereafter the impregnated carrier is separated form the aqueous solution, e.g., by centrifugation or filtration and then dried. The thus obtained impregnated carrier is heated to reduce the silver to metallic silver. It is conveniently heated to a temperature in the range of from 50 °C to 600 °C, during a period sufficient to cause reduction of the silver salt, compound or complex to metallic silver and to form a layer of finely divided silver, which is bound to the surface of the carrier, both the exterior and pore surface. Air, or other oxidizing gas, reducing gas, an inert gas or mixtures thereof may be conducted over the carrier during this heating step. There are several known methods to add the silver to the carrier or support. One method of preparing the silver containing catalyst can be found in U.S. Patent 3,702,259. Other methods for preparing the silver-containing catalysts which in addition contain higher alkali metal promoters can be found in U.S. Patent 4,010,115 and U.S. Patent 4,356,312; U.S. Patent 3,962,136 and U.S. Patent 4,012,425. Methods for preparing silver-containing catalysts containing higher alkali metal and rhenium promoters can be found in U.S. Patent No. 4,761,394 and methods for silver-containing catalysts containing higher alkali metal and rhenium promoters and sulfur and/or molybdenum and/or tungsten and/or chromium rhenium co-promoters can be found in U.S. Patent No. 4,766,105. There are known excellent methods of applying the promoters coincidentally with the silver on the carrier. A particularly preferred process of impregnating the carrier consists of impregnating the carrier with an aqueous solution containing a silver salt of a carboxylic acid, an organic amine, a salt of cesium, ammonium perrhenate and ammonium sulfate dissolved therein. Silver oxalate is a preferred salt. While addition of the amine to the silver oxide before adding the oxalic acid is possible, it is not preferred since it can give rise to solutions which are unstable or even explosive in nature. The support is impregnated in a single or multiple impregnation with one solution containing silver, alkali metal, rhenium and rhenium co-promoter in differing amounts; or in multiple impregnations with two or more solutions, wherein each solution contains at least one component selected from silver, alkali metal, rhenium and rhenium co-promoter, with the proviso that all of the components of silver, alkali metal, rhenium and rhenium co-promoter will individually be found in at least one of the solutions. The concentration of the silver (expressed as the metal) in the silver-containing solution will range from about 1 g/1 up to the solubility limit when a single impregnation is utilized. The concentration of the alkali metal (expressed as the metal) will range from 1 x 10 ~3 up to 12 and preferably, from 10 x 10 ~3 to 12 g/1 when a single impregnation step is utilized. The concentration of the rhenium (expressed as the metal) will range from 5 x 10 -3 to 20 and preferably from 50 x 10 -3 to 20 g/1 when a single impregnation step is utilized. The concentration of rhenium co-promoter (expressed as the element) will range from 1 x 10 ~3 to 20 and preferably from 10 x 10 ~3 to 20 g/1 when a single impregnation step is utilized. Concentrations selected within the above noted ranges will depend upon the pore volume of the catalyst, the final amount desired in the final catalyst and whether the impregnation is single or multiple. The amount of silver deposited on the support or present on the support is to be a catalytically effective amount of silver, i.e., an amount that catalyzes the reaction of ethylene and oxygen to produce ethylene oxide. Preferably this amount will range from 1 to 30, more preferably from 1 to 25 and even more preferably from 5 to 20 percent by weight of the total catalyst. The silver catalysts according to the present invention have been shown to have a particularly high initial selectivity for ethylene oxide production in the direct oxidation of ethylene with molecular oxygen to ethylene oxide. The conditions for carrying out such an oxidation reaction in the presence of the silver catalysts according to the present invention broadly comprise those already described in the prior art. This applies, for example, to suitable temperatures, pressures, residence times, to the presence of diluent materials such as nitrogen, carbon dioxide, steam, argon. methane or other saturated hydrocarbons, to the presence of moderating agents to control the catalytic action, for example, 1-2-dichloroethane, vinyl chloride, ethyl chloride or chlorinated polyphenyl compounds, to the desirability of employing recycle operations or applying successive conversations in different reactors to increase the yields of ethylene oxide, and to any other special conditions which may be selected in processes for preparing ethylene oxide. Pressures in the range of from atmospheric to about 3500 kPa are generally employed. Higher pressures, however, are not excluded. Molecular oxygen employed as reactant can be obtained from conventional sources. The suitable oxygen charge may consist essentially of relatively pure oxygen, a concentrated oxygen stream comprising oxygen in major amount with lesser amounts of one or more diluents, such as nitrogen and argon, or another oxygen-containing stream, such as air. It is therefore evident that the use of the present silver catalysts in ethylene oxide reactions is in no way limited to the use of specific conditions among those which are known to be effective. For purposes of illustration only, the following table shows the range of conditions that are often used in current commercial ethylene oxide reactor units. TABLE I * GHSV 1500-10,000 Inlet Pressure 1000-3500 kPa Inlet Feed Ethylene 1-40% 0 2 3-12% Ethane 0-3% Argon and/or methane and/or 0.3-20 ppmv total nitrogen diluent chlorohydro- carbon moderator Coolant temperature 180-315 °C Catalyst temperature 180-325 °C O2 conversion level 10-60% EO Production (Work Rate) 32-320 kg EO/m 3 catalyst/hr. *Volume of gas at standard temperature and pressure passing over one volume of packed catalyst per hour, In a preferred application of the silver catalysts according to the present invention, ethylene oxide is produced when an oxygen-containing gas is contacted with ethylene in the presence of the present catalysts at a temperature in the range of from about 180 °C to about 330 °C and preferably about 200 °C to about 325 °C. The invention will be illustrated by the following illustrative embodiments. Illustrative Embodiments Illustrative Embodiment 1 This illustrative embodiment describes typical preparative techniques for making the catalysts of the instant invention (and comparative catalysts) and the typical technique for measuring the properties of these catalysts. Part A: Preparation of stock silver oxalate/ethylene-diamine solution for use in catalyst preparation: 1) Dissolve 415 grams (g) of reagent-grade sodium hydroxide in 2340 milliliters (ml) deionized water. Adjust the temperature to 50 °C. 2) Dissolve 1699 g of "Spectropure" (high purity) silver nitrate in 2100 ml deionized water. Adjust the temperature to 50 °C. 3) Add sodium hydroxide solution slowly to the silver nitrate solution with stirring while maintaining a temperature of 50 °C. Stir for 15 minutes after addition is complete, and then lower the temperature to 40 °C. 4) Insert clean filter wands and withdraw as much water as possible from the precipitate created in step (3) in order to remove sodium and nitrate ions. Measure the conductivity of the water removed and add back as much fresh deionized water as was removed by the filter wands. Stir for 15 minutes at 40 °C. Repeat this process until the conductivity of the water removed is less than 90 μmho/cm. Then add back 1500 ml deionized water. 5) Add 630 g of high-purity oxalic acid dihydrate in approximately 100 g increments. Keep the temperature at 40 °C and stir to mix thoroughly. Add the last portion of oxalic acid dihydrate slowly and monitor pH to ensure that pH does not drop below 7.8. 6) Remove as much water from the mixture as possible using clean filter wands in order to form a highly concentrated silver-containing slurry. Cool the silver oxalate slurry to 30 °C. 7) Add 699 g of 92 percent weight (%w) ethylenediamine (8% deionized water) . Do not allow the temperature to exceed 30 °C during addition. The above procedure yields a solution containing approximately 27-33%w silver. Part B: Preparation of impregnation solutions For Catalyst A (1.5 Re/0.33 P) , into a 10 ml beaker is added 0.163 g of (NH4)Reθ and approximately 2.0 g of ethylene-diamine/H2θ (50/50 by weight) , and the mixture is allowed to dissolve with stirring. 0.0157 g of ( H4)H2Pθ4 is dissolved in 1 ml of water in a weighing dish, and then added to the perrhenate solution. 0.3422 g of LiNθ3 is dissolved in 2 ml of water and added to the perrhenate solution. The perrhenate/phosphate/- nitrate solution is allowed to stir, ensuring complete dissolution. This solution are then added to 183 g of the above-prepared silver solution (specific gravity = 1.556 g/cc) , and the resulting solution is diluted with water to a total weight of 204 g. One-fourth of this solution is used to prepare a catalyst. 0.082 g of CsOH solution (42.9% Cs) is added to a 51 g portion of the silver oxalate/dopant solution to prepare the final impregnation solution. For Catalyst B (1.5 Re/1.0 P) , the procedure for Catalyst A is followed, except that 0.0476 g of (NH4)H2Pθ4 is used. For Catalyst C (1.5 Re/0.33 B) , the procedure for Catalyst A is followed, except that 0.0084 g of H3BO3 is used in place of the (NH4>H2Pθ4. For Catalyst D, (1.5 Re/4.0 B) , the procedure for Catalyst A is followed, except that 0.1018 g of H3BO3 is used in place of the (NH 4 )H2Pθ and 0.1013 g of the aqueous CsOH solution is used. For Catalyst E (2.0 Re), the general procedure for catalyst A is followed. However, no phosphate or borate co-promoter is added. 0.055 g of (NH4)Reθ is dissolved in a minimum of 50/50 by weight ethylenediamine/H2θ solution, and this is added to 50 g of the above-prepared silver solution (specific gravity = 1.556 g/ml) . 0.0847 g of CsOH solution (50.7% Cs) is also added to the impregnation solution. Part C: Catalyst impregnation and curing For Catalysts A and B, approximately 30 g of a catalyst carrier (98.8 %wt alpha alumina, B.E.T. Surface Area 0.51 m 2 /g, Water Pore Volume 0.38 ml/g) are placed under 25 mm vacuum for 3 minutes at room temperature. Approximately 50 g of doped impregnating solution is then introduced to submerge the carrier, and the vacuum is maintained at 25 mm for an additional 3 minutes. At the end of this time, the vacuum is released, and excess impregnating solution is removed from the carrier by centrifugation for 2 minutes at 500 rpm. If the impregnating solution is prepared without monoethanol- amine, then the impregnated carrier is then cured by being continuously shaken in a 8496 litre/hr. air stream flowing across a cross-sectional area of approximately 19-32 square cm at 250-270 °C for 5-6 minutes. If significant monoethanolamine is present in the impregnating solution, then the impregnated carrier is cured by being continuously shaken in a 8496 litre/hr. air stream at 250 °C for 2.5 minutes, followed by a 2832 litre/hr. air stream at 270 °C for 7.5 minutes (all over a cross-section area of approximately 19-32 square cm) . The cured catalyst is then ready for testing. For Catalysts C and D, the above procedure is followed, except that a carrier having 98.0 %wt alpha alumina, 0.68 m 2 /g B.E.T. Surface Area and 0.37 ml g Water Pore Volume, is used as the support. For Catalyst E, the above procedure is followed, except that a carrier having 98.0 %wt alpha alumina, 0.42 m 2 /g B.E.T. Surface Area and 0.36 ml g Water Pore Volume, is used as the support. This procedure will yield catalysts which contain approximately 13.5 %w Ag with the following approximate dopant levels (expressed in parts per million by weight basis the weight of the total catalyst, i.e., ppmw) and which are approximately optimum in cesium for the given silver and rhenium and co-promoter levels (P, B) and support with regard to initial selectivity under the test conditions described below. Cs, ppmw Re, ppmw P, pp w B, ppmw Catalyst A 340 279 10 Catalyst B 340 279 31 Catalyst C 340 279 — 4 Catalyst D 460 279 — 43 Catalyst E 438 372 Part D: Standard Microreactor Catalyst Test Conditions/Procedure 3 to 5 grams of crushed catalyst (14-20 mesh, 1.410-0.841 mm) are loaded into a inch diameter stainless steel U-shaped tube. The U tube is immersed in a molten metal bath (heat medium) and the ends are connected to a gas flow system. The weight of the catalyst used and the inlet gas flow rate are adjusted to achieve a gas hourly space velocity of 3300 ml of gas per ml of catalyst per hour. The inlet gas pressure is 1548 kPa. The gas mixture passed thorough the catalyst bed (in once-through operation) during the entire test run (including startup) consists of 30% ethylene, 8.5% oxygen, 5% carbon dioxide, 54.5% nitrogen, and 2.0 to 6.0 ppmv ethyl chloride. The initial reactor (heat medium) temperature is 225 °C. After 1 hour at this initial temperature, the temperature is increased to 235 °C for 1 hour, and then adjusted to 245 °C for 1 hour. The temperature is then adjusted so as to achieve a constant oxygen conversion level of 40%. Performance data at this conversion level are usually obtained when the catalyst has been onstream for a total of at least 2-3 days. Due to slight differences in feed gas composition, gas flow rates, and the calibration of analytical instruments used to determine the feed and product gas compositions, the measured selectivity and activity of a given catalyst may vary slightly from one test run to the next. To allow meaningful comparison of the performance of catalysts tested at different times, all catalysts described in this illustrative embodiment were tested simultaneously with a reference catalyst. All performance data reported in this illustrative embodiment are corrected relative to the average initial performance of the reference catalyst (S 40 = 81.0%; T40 = 230 °C) . The results are presented below in Table II. All selectivity values are expressed as %. TABLE II Initial Performance of Catalyst Catalyst Initial Selectivity A (1.5 Re/0.33 P) 85.9% B (1.5 Re/1.0 P) 85.0% C (1.5 Re/0.33 B) 85.4% D (1.5 Re/4.0 B) 85.6% E (2.0 Re) 81.9% As mentioned previously, selectivity is of tremendous importance and higher selectivities are desired in order to run the process in a more efficient and cost effective manner. As can be seen in Table II, both the catalysts which contain a phosphorus co-promoter in combination with rhenium (Catalysts A and B) , and the catalysts which contain a boron co-promoter in combination with rhenium (Catalysts B and C) , have higher initial selectivities than the catalyst which contains no phosphorus or boron rhenium co-promoter (Catalyst E) .

Claims: C L A I S 1. An ethylene oxide catalyst for the vapor phase production of ethylene oxide from ethylene and oxygen comprising a catalytically effective amount of silver, a promoting amount of alkali metal, a promoting amount of rhenium and a rhenium co-promoter supported on a suitable support having a surface area in the range of from about 0.05 m 2 /g to about 10 m 2 /g, characterized in that the rhenium co-promoter is selected from phosphorus, boron and mixtures thereof. 2. The catalyst of claim 1 wherein the support comprises alpha alumina. 3. The catalyst of claim 1 or 2 wherein the alkali metal is cesium. 4. The catalyst of claim 3 wherein the alkali metal comprises cesium plus at least one additional alkali metal. 5. The catalyst of claim 1 wherein the amount of silver is in the range of from 1 to 25 percent by weight of the total catalyst, the amount of alkali metal promoter is in the range of from 10 to 3000 parts per million, expressed as the metal, by weight of the total catalyst, the amount of rhenium promoter is in the range of from 0.1 to 10 micromoles of rhenium, expressed as the metal, per gram of total catalyst and the amount of rhenium co-promoter is in the range of from 0.1 to 10 micromoles of rhenium, expressed as the element, per gram of total catalyst. 6. A process for preparing a catalyst according to claim 1 which comprising impregnating a porous refractory support with one or more solutions comprising compounds of silver, alkali metal, rhenium and a rhenium co-promoter selected from the group consisting of phosphorus, boron and mixtures thereof, wherein the concentration of the silver (expressed as the metal) in the solution ranges from 1 gram/litre to the solubility limit of silver in the solution, the concentration of alkali metal (expressed as the metal) in the solution ranges from 1 x 10 ~3 to 12 grams/litre, the concentration of the rhenium (expressed as the metal) in the solution ranges from 5 x 10 ~3 to 20 grams/litre and the concentration of the rhenium co-promoter (expressed as the element) in the solution ranges from 1 x 10 -3 to 20 grams/litre to provide the catalyst with a catalytically effective amount of silver, a promoting amount of alkali metal, a promoting amount of rhenium, and a promoting amount of rhenium co-promoter. 7. The process of claim 6 wherein after impregnation, the silver is reduced to metallic silver by heating at a temperature between about 50 °C and about 600 °C. 8. The catalyst of claim 6 wherein the rhenium co-promoter compound comprises an oxidic compound or an oxyanion. 9. The catalyst of claim 8 wherein the rhenium co-promoter compound is selected from the group consisting of phosphate, borate and mixtures thereof. 10. The catalyst of claim 9 wherein the rhenium co-promoter compound is a phosphate selected from the group consisting of ortho-phosphate, hydrogen phosphate, dihydrogen phosphate, metaphosphate, fluorophosphate, pyrophosphate, hypophosphate, diphosphate, triphosphate and mixtures thereof. 11. The catalyst of claim 9 wherein the rhenium co-promoter is a borate selected from the group consisting of metaborate, tetraborate, tetrafluoroborate and mixtures thereof.

Inventors: KEMP RICHARD ALAN, KEMP, RICHARD, ALAN
Applicants: SHELL INT RESEARCH, SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
Application year: 1995
Main classification: B01J23
IPC codes: B01J23, B01J27, B01J35, C07D301, C07D303