AN ION EXCHANGE RESIN CATALYST FOR THE SYNTHESIS OF BISPHENOLS AND ITS PREPARATION

Abstract: An ion exchange resin catalyst containing sulfonated styrene-divinylbenzene copolymer, with special porous structure is disclosed. The catalyst is suitable for the condensation reaction between a phenol and a carbonyl compound to prepare bisphenols,especially suitable for the condensation reaction between phenol and acetone to prepare bisphenol A.

Description: Field of the Invention This invention relates to an ion exchange resin catalyst for the synthesis of bisphenols and the process for preparing the same, more particularly, this invention relates to a styrene-divinylbenzene series strong acidic cation exchange resin catalyst for the synthesis of bisphenols, and the process for preparing the same . Background of the Art There are mainly two industrial processes for bisphenols production, hydrogen chloride process and ion exchange resin process, which use hydrogen chloride and strong acidic cation exchange resin as catalyst, respectively. The later has developed greatly in recent years, because it has advantages of simple process, no corrosion, low requirement to the equipment materials and quality, less quantities of wastes etc., especially with the continuous improvement in the properties of the ion exchange resin catalysts, it has already become an advanced process for the production of bisphenol A, which is the raw material of high quality engineering plastics and high insulation grade epoxy resin. Recently, the base material used in the ion exchange resin catalysts is a gel type or macroreticular type sulfonic acid cation exchange resin with exchange capacity of at least 2.0 meq/g, preferably 3.0-5.5 meq/g dry resin, such as sulfonated styrene-divinylbenzene copolymers, sulfonated phenolformaldehyde resins and sulfonated benzene-formaldehyde resins, suitable trade marks are for example : Amberlite-118, -200, -IR, -XE307; Amberlyst 15, Dowex-50, -MSC-1; Duolite C-20; Permutit QH; Chempro C-20, etc.. The commonly used method for modifying the above mentioned base material of ion exchange resin into catalysts used for the synthesis of bispenols comprises introducing cocatalytic group, such as mercapto group into the base material of ion exchange resin so as to increase its selectivity and reaction velocity. Since the resin process for bisphenol synthesis was invented, the modification research work in this respect has not been interrupted. In the case of introducing mercapto group, there are reported many processes in literature, such as partial reduction method (USP 3,172,916), partial esterification method (USP 3,153,001; BP 937,072), covalence bonding method through sulfonamide (USP 4,294,995; USP 4,346,247; USP 4,396,728) and partial neutralization method. As the catalyst obtained by partial neutralization method has better catalytic performances than those obtained by other methods, i.e. higher recovery and purity of product bisphenol, the partial neutralization method has been paid more attention, and partial neutralization methods using various mercapto group-containing compounds have successively been developed. These mercapto group-containing compounds (mercaptolizing agent) are: tetrahydrothiazole or thiazolidine (USP 3,634,341; USP 3,760,006), aryl mercaptoamine or its salts (USP 4,045,379), pyridylalkylthiol (USP 4,478,956), N-(2-mercapto alkyl) amide (USP 4,595,704; CN 85106111), polymercaptoalkylamine (EP 268,318; USP 4,820,740), N-alkylmercaptoamine (EP 144,735) and alkylmercaptoamine (USP 3,394,089; BP 1,183,564), and the like. Although in the above mentioned prior art, various co-catalytic groups with different molecular structures, and the corresponding methods for introducing these groups into the fundamental resin backbone have been developed, and these techniques do increase the selectivity and activity of the catalysts to some extent, as these techniques are only limited to the change and transform in species of the co-catalytic groups and methods for introducing them, and do not relate to the fundamental resin itself, the increase in selectivity and activity of the catalysts is limited. For example, in the case of using modified resin catalyst in the condensation reaction between phenol and acetone, the conversion of acetone to bisphenol A is lower than 50%, the selectivity to product p - p-bisphenol A is less than 96%, and the color index is as high as 40-50. Even by using a modification method disclosed by this inventors in Chinese Patent Application No. 91108831.8, the conversion of acetone can reach 53%, and the selectivity to product p,p-bisphenol A can reach 99.23%, but the color index of the product is still higher than 20. Summary of the Invention The object of this invention is to provide an ion exchange resin catalyst with special structure for use in synthesizing high quality p,p-bisphenol A ( hereinafter refered to "bisphenol A " ) in high activity and high selectivity starting from preparing the fundamental resin. Another object of this invention is to provide a process for the preparation of this catalyst. Detailed Description of the Invention The ion exchange resin catalyst according to the invention comprises a suifonated styrene-divinylbenzene copolymer, the exchange capacity of which is 2.8-5.5 meq/g dry resin, and 10-30% of the sulfonic acid groups of which are linked to the alkylmercaptoamine having 1-7carbon atoms through an ionic linkage of ammonium sulfonate. This catalyst has a porous structure containing micropore areas and transfer pass networks, the transfer pass network being composed of main pass networks and branch pass networks. In non-swollen state, the pore size of a main pass network is 9 × 10 3 -38 × 10 3 nanometer, the pore size of a branch pass network is 20-150 nanometer ; and the pore size of a micropore area pass is 5-20 nanometer, wherein the pore capacity of the micropore pass with a pore size of 5-10.4 nanometer is more than 50% of the total pore capacity of the micropore areas, and the ratio of the pore capacity of the micropore areas to that of the transfer network areas is 0.25-1.1. The ion exchange resin catalyst of the present invention with the above-mentioned special structure and having high activity and high selectivity is prepared by the following steps: (1) Suspension polymerizing to prepare small resin beads Monomers of styrene and divinylbenzene are suspension polymerized in the presence of a pore-forming agent. The weight ratio of divinylbenzene to styrene is 5-25% : 75-95%, preferably 8-15% : 85-92%. The pore-forming agent is composed of a refined paraffin wax with melting point of 54-62 °C and NY-200 # petroleum spirit with the ratio of parraffin wax to petroleum spirit being 1:3-6.1. The amount of the pore-forming agent used is to enable the monomer : the pore-forming agent = 60-80% : 20-40% (by weight). The amount of water added is about 3-5 fold, preferably about 4 fold by weight of the monomer. The temperature of the polymerization is about 60-95 °C, preferably 80-90 °C. The polymerization is preferably carried out in two stages, in the first stage, the temperature of the polymerization is about 70-90 °C, and the time of the polymerization is about 4-8 hours, preferably about 5-7 hours; in the second stage, the temperature of the polymerization is about 80-95 °C, and the time of the polymerization, identical of different to that in the first stage, is about 4-8 hours, preferably about 5-7 hours. The suspension polymerization according to the present invention can be carried out in a polymerization equipment well known in the art. The suspension polymerization is generally carried out in a crosslinking degree of 3-15%, preferably in a crosslinking degree of 7-12%, (2)Swelling and sulfonating the small resin beads The small resin beads obtained by polymerization are subjected to the following treatments successively in a customary process for preparing sulfonated macroreticular cation exchange resin: (a) Removing the paraffin wax and petroleum spirit by extraction: The small beads are extracted by an extraction agent at a temperature of 0-50 °C, preferably at room temperature until no paraffin wax can be detected in the extract (which could be determined by refractive index measurement). The extraction agent a benzene, toluene, xylene, etc., in an amount of 1-100 fold, preferably 2-15 fold by volume of the small beads, and the extraction is preferably carried out in portions. (b) Swelling and Sulfonating the resin beads: The swelling agent and the sulfonating agent are added to the as-extracted small resin beads. The resin is sulfonated at 70-95 °C for 4-8 hours while it is swollen. The temperature of the sulfonation is generally not more than the boiling point of the mixture of the swelling agent and the sulfonating agent depending upon the boiling point of the mixture of the swelling agent and the sulfonating agent. The swelling agent used is selected from one of alcohols, acetone, phenol acetone-phenol, dichloromethane, dichloroethane and other swelling agents well known in the art, the amount of which is about 30-70%, preferably about 40-60% by weight of the resin beads. The sulfonating agent used is selected from one of sulfuric acid, sulfonic acid, methane-sulfonic acid, benzene sulfonic acid, p-toluene sulfonic acid and the like, which are the sulfonating agents well known in the art. The amount of the sulfonating agent is about 5-10 fold by weight of the small beads. The time for the sulfonation can be selected from 2-10 hours, and the sulfonation is preferably carried out in several stages, for example in two stages, and the temperature in the latter stage can be slightly higher than that in the former stage. (C) Removing the residual swelling agent and the residual sulfonating agent : After the sulfonation reaction is completed, the swelling agent can be removed by any suitable method, e.g. normal pressure distillation. The reaction solution is then gradually diluted with water and the sulfonated resin is washed to remove residual acid, until the effluent is neutral. (d) Transforming the type of the resin: The sulfonated resin can be transformed to alkali metal ionic type by a basic solution, or can be conviently transformed to H-type by an inorganic acid. The commonly used basic solution is NaOH, KOH or the like, and the concentration of which may be 10-35% (by weight). The commonly used inorganic acid is hydrochloric acid, sulfuric acid or the like, preferably hydrochloric acid, the concentration of which is 2-10%, preferably 4-6% (by weight). Preferably, the resin is transformed to H-type which is practically used. (3) Mercaptolizing the sulfonic acid type resin by mercaptolizing agent solution: Thus prepared sulfonic acid type resin is mercaptolized according to the partial neutralization method disclosed in the prior art, in which alkyl mercaptoamine is used as the mercaptolizing agent. The mercaptolizing agent solution comprises the following components %(by weight): 0.01%-saturated solution of alkylmercaptoamine organic or inorganic acid salt, having 1-7 carbon atoms : 0.01-50% of an acid selected from one of p-toluene sulfonic acid, formic acid, acetic acid, oxalic acid, hydrochloric acid, nitric acid and sulfuric acid; 0-98% of an organic swelling agent selected from one of alcohols having less than 5 carbon atoms, acetone, phenol , acetone-phenol, dichloromethane and dichloroethane ; and balance water. The mercaptolizing agent solution can also be an aqueous solution of alkyl mercaptoamine organic or inorganic acid salt, having 1-7 carbon atoms, which is formed by acidifying the above mentioned alkylmercaptoamine with an acid selected from one of p-toluene sulfonic acid, formic acid, acetic acid, oxalic acid, hydrochloric acid, nitric acid and sulfuric acid, the pH of which is ∋ 5,and the concentration of which is 0.005-0.5% by weight. Preferably, the mercaptolization reaction is carried out by using the second mercaptolizing agent solution with lower concentration. The mercaptolization step can be carried out by statically impregnating the above treated resin with the mercaptoiizing agent solution, or by passing the mercaptolizing agent solution through the resin once or multiple times. The former is preferred, because static impregnation has the following advantages : simplicity of equipment, convenience of operation and the resin being hardly broken and so on. The resin to be mercaptolized can be in dry state, or in swollen state in water or in the above-mentioned organic swelling solvent. The temperature of the mercaptolization is generally about 0-90 °C, preferably 0-50 °C, more preferably 25 °C or even lower. The time of the mercaptolization is generally about 24-96 hours, preferably about 48-72 hours. After the resin is mercaptolized, it is washed until the effluent is neutral, filtrated, and dried, optionally at reduced pressure, to obtain the product. The partial neutralization method for mercaptolizing, sulfonated resin, which is described in Chinese Patent Application No.91108831.8, is incoporated herein by reference. Brief Description of the Drawing The accompanying drawing illustrates the schematic graph of the equipment used for the mercaptolization of the synthesized sulfonic acid type resin according to the present porcess, wherein, 1 is a reactor, 2 is a filter, 3 is a recycle pipe line, 4 is a storage vessel, and 5 is a pump. The equipment used for the mercaptolization of the synthesizd sulfonic acid type resin according to the present process can be the equipment described in Chinese Patent Application No.91111615.X. This equipment is a closed recycle system, comprising a reactor, a filter, a storage vessel, a pump, and connection pipe lines. This equipment enables resin particulates to homogeneously suspended in solution, and to be in a slowly-floating and rolling state wherein the reactor can be a reaction kettle , a tubular reactor, a tower reactor, a reaction column, a vessie, a pot or a tank. The filter can be a device or a material selected from a ceramic filter, sintered glass, porous foam plastics, glass fiber, fiber plastics or its fabric, net and porous plate, which enables the fluid to pass freely, and prevents particulates from passing. In the reactor and the storage vessel, flow deflector, honeycomb duct and heating or cooling jacket can be installed. In the whole closed recycle system, the recycle direction, relative to the reactor, can be downwards, upwards, or transversed. The catalyst provided by this invention has the above-mentioned special porous structure, thus has higher selectivity and activity than those of the catalyst in the prior art, the present catalyst is suitable for the condensation reaction between a phenol and a carbonyl compound to produce bisphenols, especially suitable for the condensation reaction of phenol and acetone to form bisphenol A. For example, in the case of the molar ratio of phenol to acetone of 8, and at reaction temperature of 75°C, the catalyst provided by this invention can transfer acetone to bisphenol A with a conversion of 58-74%, selectivity to bisphenol A of 99.2-99.7%, and color index of less than 10. The quality of the obtained product bisphenol A can reach polymer grade, common epoxy resin grade and insulated epoxy resin grade. In the process for preparing the present calalyst, as a pore-forming agent with special composition is used, fundamental resin particulates with special porous structure are synthesized. Moreover, as a special mercaptolization process is used, the problem of the resin particulates being broken has been solved, which is usually encountered in many mercaptolization techniques in the prior art, and mercapto groups can be homogeneously distributed on surface of or inside the resin particulates. This perfect preparation precess imparts excellent selectivity to resin catalyst. Example Following examples will further illustrate this invention, but is not intended to limit the scope of this invention. In examples, the porous structure of the catalyst was measured on Autopore 9220 type automatic porosimeter made in Micrometrtics Corporation (US) by mercury intrusion method. The conversion of phenol and acetone to bisphenol A, and the selectivity to the target product bisphenol A were calculated as follows: conversion C = C BP (M p ×R+M A M BP × 100% in which C BP is the content of bisphenol A in the product; Mp is the molecular weight of phenol; R is the molar ratio of the starting phenol to acetone, M A is the molecular weight of acetone and M BP is the molecular weight of bisphenol A. selectivity S = C BP C BP +C 2 +C 3 +C 4 +C 5 ×100% in which, C BP , C 2 , C 3 , C 4 , C 5 are the contents of bisphenol A, 2,4-bisphenol A, triphenol, chroman, and other inpurities in the reaction product, respectively. The contents of all the components in the product were measured by HPLC. The color index of the product bisphenol A was measured by colorimetry on Pt-Co spectrophotometer. Example 1 To a 5L three-neck flask was added 16.5g of polyvinylalcohol (product from The Third Reagent Plant in Beijing) and 1600 ml of distilled water, then added 364.8g of styrene (product from the Chemical Industry Corporation in Lanzhou), 36.5g of divinylbenzene (product from the Chemical Industry Corporation in Lanzhou), 40.2g of benzoyl peroxide ( product from The Third Reagent Plant in Beijing), 17.7g of refined paraffin wax (product from the Petroleum Chemical Corporation in Daqing) and 107.4g of NY-200 # petroleum spirit (product from the Petroleum Chemical Corporation in Daqing) respectively. The reaction was carried out with stirring at 82 °C for 6 hours, and at 90 °C for 6 hours, then the resin materials were removed, washed with water, and air-dried, thus the resin particulates containing paraffin wax and petroleum spirit were obtained. The above white beads was extracted three times with 1200ml of benzene (product from the First Reagent Plant in Tianjing) in a Soxhlet's extractor until no pataffin was detected (by refractive index measurement) in the extract. Using 200g of dichloroethane (product from the First Reagent Plant in Tianjing) as swelling agnet, and 2800g of 94 % by weight of sufuric acid solution (product from the Third Reagent Plant in Tianjing) as sulfonating agent, the reaction was carried out with stirring at 70 °C for 2 hours, and at 80 °C for another 6 hours. The temperature of the system was raised to 90 °C, at which temperature the dichloroethane was distilled off, and the distillation was continueously carried out at 110-120 °C at normal pressure for 2 hours, and under reduced pressure for 1 hour. When the temperature of the system gradually dropped to below 35 °C, the solution in the system was diluted gradually with water, and the resin was washed to remove the residual acid until the effluent was neutral. The resin was transformed into H-type with 5% aqueous solution of hydrochloric acid. 395g of small white beads was obtained after drying. To a mercaptolization reaction equipement was charged with 180g of dry resin, 18g of mercaptoethylamine hydrochiride (product from Medical Raw Material Plant in Changshou City), and 360ml of water, then the pH of the solution was adjusted to 3 using hydrochloric acid. The resin was impregnated at room temperature for 36 hours, then the resin was removed, and was washed with water until the effluent was neutral, filered, and dried at 80 °C for 6 hours, then dried in vaccum at 72 °C for 12 hours. Example 2 The reaction was conducted using essentially the same materials, experimental precedures and operation conditions as in Example 1, except that the ratio of petroleum spirit to paraffin wax was different. The amount of petroleum spirit used in this example was 90.5g, and the amount of paraffin wax was 29.2g, the ratio thereof was 3.1. Eample 3 The reaction was conducted using essentially the same materials, experimental porcedures and operation conditions as those in Example 2, except that the concertration of the mercaptolizing agent mercaptoethylamine hydrochloride, was lower, and was 0.3% (by weight). Correspondingly, longer impregnation time, 72 hours was used. The relavent properties of the catalyst obtained in the above examples were analysed, with the results listed in the following Table 1. Example 1 Example 2 Example 3 The weight ratio of petroleum spirit to paraffin wax 6.1 3.1 3.01 Exchange capacity (meq/g dry resin) 4.66 4.72 4.73 Percent ratio of the pore capacity of micropore pass to the total pore capacity of micropore area 51 78 65 The ratio of the pore capacity of the micropore area to that of the transfer pass network 0.25 1 1.1 Mercaptolizing degree (%) 16.95 17.2 16.8 Number of the catalyst A B C Example 4-6 The catalyst of the present invention was prepared in the equipement escribed in in CN 911 11615.XA. The resin beads were prepared according to the processes described in Examples 1-3, and they were sulfonated and transformed. The mercaptolization reaction was conducted in the equipement shown in Figure 1, wherein the reactor is a tower reactor with an inner diameter of 40mm and a height of 590mm; the filter is a sintered porous glass filter; the recycle pipe line was a glass tube with an inner diameter of 8mm, and the storage vessel is a glass lined kettle with a capacity of 10 liters. 500g of the above-mentioned sulfonated resin was charged into the reactor, and 6L of an aqueous solution containing 20g of mercaptoethylamine hydrochloride (pH=1) which was acidified with p-toluene sulfonic acid (product from the Chemical Industry Plant in Beijing ) was charged into the storage vessel. The aqueous solution of the mercaptolizing agent was pumped at a flow rate of 14 liter per hour by a pump at room temperature from the storage vessel via the filter into the bottom of the reactor, where it contacted with the resin. The effluent flowed out from the top of the reactor through filtration, then returned back into the strorage vessel and recycled consecutively for 24 hours. After the recycle was over, the resin was washed until the effluent was neutral, filtered, and dried at 80 °C for 6 hours, and in vaccum at 72 °C for 12 hours. The revalent properties of the above-mentioned catalysts was analysed, with the results listed in the following Table 2. Example 4 Example 5 Example 6 The weight ratio of petroleum spirit to paraffin wax 6.1 3.1 3.01 Exchange capacity (meq/g dry resin) 4.66 4.72 4.73 Percent ratio of the pore capacity of micropore pass to the total pore capacity of micropore area 51 78 65 The ratio of the pore capacity of the micropore area to that of the transfer pass network 0.25 1 1.1 Mercaptolizing degree (%) 16.85 17.1 16.9 Number of the catalyst D E F Application Examples 1-6 When used to prepare bisphenol A, the catalyst of the present invention possesses higher activity and selectivity with better color index of bisphnol A. 130g of phenol (porduct from the First Reagent Plant in Tianjing) and 10g of acetone (product from the Chemical Industry Plant in Beijing ) were reacted with stirring in the presence of 20g of the catalyst at 75 °C for 1 hour, the conversion of acetone to bisphenol A, the selectivity to bisphenol A and the color index of bisphenol A were measured, the results were listed in Table 3. To illustrate the characterization of the present catalyst, another three prior catalysts without the porous structure of the present catalyst were measured in parallel under the same conditions, the results were also listed in Table 3. Catalyst A B C D E F Control 1 Control 2 Control 3 Percent ratio of the pore capacity of micropore pass to the total pore capacity of micropore area 51 78 65 51 78 65 32 48 15 Ratio of the pore capacity of micropore area to the pore capacity of transfer pass network 0.25 1 1.1 0.25 1 1.1 0.12 0.14 1.8 Conversion of acetone to bisphenol A (%wt) 58.6 63.9 60.2 73.7 74.1 73.8 49.08 53 43 Selectivity of bisphenol A (%wt) 99.25 99.6 99.4 99.3 99.7 99.5 96.1 99.23 92.5 The color index of bisphenol A 9.8 8.4 8.9 9 8 8.5 40 22 50

Claims: An ion exchange resin catalyst containing sulfonated styrene-divinylbenzene copolymer, characterized in that : (1) its exchange capacity is 2.8∼5.5 meq/g dry resin; (2) its 10∼30% sulfonic acid groups are linked to the alkylmercaptoamine containing 1∼7 carbon atoms through an ionic linkage of ammonium sulfonate ; (3) it contains a porous structure with micropore area and transfer pass networks, the transfer pass network is composed of main pass networks and branch pass networks, in non-swollen state, the pore size of the main pass network is 9 × 10 3 - 38 × 10 3 nanometer and the pore size of the branch pass network is 20-150 nanometer, the pore size of the micropore area pass is 5-20 nanometer, wherein the pore capacity of the micropore pass with the pore size of 5-10.4nm is more than 50% of the total pore capacity of the micropore area, and the ratio of the pore capacity of the micropore area to that of the transfer network area is 0.25-1.1. The process for the preparation of the ion exchange resin catalyst claimed in claim 1, comprising the following steps : (1) suspension polymerizing styrene and divinylbenzene monomers to prepare small white resin beads in the presence of a pore-forming agent, wherein the weight ratio of divinylbenzene to styrene is 5-25% : 95-75%, the pore-forming agent is composed of a refined paraffin wax and petroleum spirit with the weight ratio of paraffin wax to petroleum spirit being 1:3-6.1 ; (2) swelling and sulfonating the small resin beads comprising a) removing the paraffin wax and petroleum spirit from the resin obtained by the above polymerization by using an extracting agent, b) swelling and sulfonating the tesin beads by using a swelling agent and a sulfonating agent, c) removing the residual swelling agent and the residual sulfonating agent, and d) transforming the type of the resin into Na type or H type; and (3) mercaptolizing the sulfonic acid type resin by using a mercaptolizing agent solution, washing the resin, drying and obtaining the catalyst product. The process according to claim 2, characterized in that the suspension polymerization is carried out in a cross-linking degree of 3-15%. The process according to claim 3, characterized in that the suspension polymerization is carried out in a cross-linking degree of 7-12%. The process according to claim 2, characterized in that the mercaptolization is proceeded at ambient temperature by statically impregnating the resin with a mercaptolizing agent solution or by passing the mercaptolizing agent solution through the resin once or multiple times. The process according to claim 5, characterized in that the mercaptolizing agent solution has the following components (% by weight ): 0.01%-saturated solution of alkyl mercaptoamine organic or inorganic acid salt having 1-7 carbon atoms; 0.01-50% of an acid selected from one of p-toluene sulfonic acid, formic acid, acetic acid, oxalic acid, hydrochloric acid, nitric acid and sulfuric acid; 0-98% of an organic swelling agent selected from one of alcohols having less than 5 carbon atoms, acetone, phenol , acetone-phenol, dichloromethane and dichloroethane ; and balance water. The process according to claim 5, characterized in that the mercaptolizing agent solution is an aqueous solution of alkyl mercaptoamine organic or inorganic acid salt having 1-7 carbon atoms, which is formed by acidifying the above mentioned alkylmercaptoamine with an acid selected from one of p-toluene sulfonic acid, formic acid, acetic acid, oxalic acid, hydrochloric acid, nitric acid and sulfuric acid, the pH of which is ≤ 5, and the concentration of which is 0.005-0.5% by weight. The process according to claim 7, characterized in that the mercaptolizing process is proceeded in a closed recycle equipment comprising a reactor, a filter, a storage vessel, a pump, and connection pipe lines. The process according to claim 3, characterized in that the reactor can be a reaction kettle, a tubular reactor, a tower reactor, a reaction column, a vessel, a pot or a tank. The process according to claim 8, characterized in that the filter can be a device or a material selected from a ceramic filter, sintered glass, porous foam plastics, glass fiber, fibreplastics or its fabric, net and porous plate, which enables fluid to pass freely and prevents particulates from passing. The process according to claim 8, characterized in that a flow deflector, a honeycomb duct, or a jacket can be installed in the reactor or the storage vessel. The process according to claim 5, characterized in that the resin to be mercaptolized can be in dry state or in swellon state in water or in an organic swelling agent. The use of the ion exchange resin catalyst claimed in claim 1 in synthesizing bisphenol A.

Inventors: HE BINGJUN, JIANG HONGSHOU, JIN ZUQUAN, LIU ZONGZHAND, TAN QIU, HE, BINGJUN, JIANG, HONGSHOU, JIN, ZUQUAN, LIU, ZONGZHAND, TAN, QIU
Applicants: CHINA PETROCHEMICAL CORP, UNIV TIANJIN, CHINA PETRO-CHEMICAL CORPORATION, TIANJIN UNIVERSITY
Application year: 1995
Main classification: B01J31
IPC codes: B01J31, C08F8, C07B61, B01J37, C07C37, C08F212, C07C39