Reducing exhaust emissions from Otto-cycle engines

Abstract: The amount of nitrogen oxide (NOx) and hydrocarbon emissions emanating via the exhaust during operation of a gasoline engine is reduced by dispensing to a gasoline engine adjusted to operate primarily at an air-to-fuel ratio between lambda of about 0.9 to about 1.15, a gasoline that contains a minor amount of (i) a cyclopentadienyl manganese tricarbonyl compound and (ii) an alkyllead antiknock agent. Components (i) and (ii) are proportioned such that there is dissolved in the fuel a substantially equal weight of manganese as (i) and lead as (ii), and the amount of (i) and (ii) used in the fuel is an amount that reduces the amount of NOx and hydrocarbons in the engine exhaust on combustion of the fuel with an air-to-fuel ratio between lambda of about 0.9 to about 1.15. Lambda is the actual air-to-fuel ratio divided by the stoichiometric air-to-fuel ratio. The stoichiometric air-to-fuel ratio is a lambda value of one.

Description: This invention relates to a new way of minimizing exhaust emissions from spark-ignition internal combustion engines operated on gasoline-type fuels. In many parts of the world it is necessary and thus conventional practice to increase the octane value of the available base gasolines by use therein of a suitable quantity of tetraethyllead. One objective of this invention is to reduce the amount of nitrogen oxide (NOx) emissions and hydrocarbon emissions emanating via the exhaust of gasoline engines as compared to the amount of these emissions produced when operating in accordance with such conventional practice with a fuel of the same or similar octane quality. Another objective is to achieve the foregoing reductions of exhaust emissions while concurrently avoiding, or at least reducing, exhaust valve recession in engines susceptible to exhaust valve recession when operated on unleaded gasoline. Still another objective is to achieve the foregoing advantageous emission control results while at the same time achieving the required fuel octane quality by use of fuels having a reduced metal content. To accomplish one or more of the foregoing objectives, there is dispensed to the Otto-cycle (i.e. four stroke) engine a gasoline fuel that contains a minor amount of (i) a cyclopentadienyl manganese tricarbonyl compound and (ii) an alkyllead antiknock agent, wherein (i) and (ii) are proportioned such that there is dissolved in said fuel a substantially equal weight of manganese as (i) and lead as (ii), and wherein said minor amount of (i) and (ii) is sufficient to reduce the amount of NOx and hydrocarbons in the engine exhaust on combustion of said fuel with an air-to-fuel ratio between lambda of 0.9 to 1.15, where lambda is the actual air-to-fuel ratio divided by the stoichiometric air-to-fuel ratio. The lambda value for the stoichiometric air-to-fuel ratio is one. Results to date from test work on this invention indicate that by dispensing the foregoing fuel composition to a gasoline engine adjusted to operate at least primarily at air-to-fuel ratios between lambda of 0.9 to 1.15, it is possible pursuant to this invention to reduce both NOx and hydrocarbon emissions in the engine exhaust by an average of 14.6% and 26%, respectively. The greatest reductions in NOx emissions at comparable fuel octane levels tends to occur at operation with an air-to-fuel ratio between lambda of 1.02 and 1.15, and the lowest absolute levels of NOx emissions tend to occur pursuant to this invention at air-to-fuel ratios between lambda of 0.9 and 0.95. The greatest reductions in hydrocarbon exhaust emissions at comparable fuel octane levels tends to occur at operation with an air-to-fuel ratio between lambda of 1.03 to 1.15, although very substantial reductions also occur between lambda of 0.95 to 1.03. For best results on reduction and control of both NOx and hydrocarbon exhaust emissions, the fuel is preferably dispensed to a gasoline engine adjusted to operate primarily between lambda of 1.0 to 1.15. Over this same range of between lambda of 1.0 to 1.15, the amount of carbon monoxide emissions is also kept low. Accordingly, this invention involves, inter alia, use of a gasoline-type fuel containing a minor exhaust-emission reducing amount of (i) a cyclopentadienyl manganese tricarbonyl compound and (ii) a lead alkyl antiknock agent, wherein (i) and (ii) are proportioned such that there is dissolved in said fuel a substantially equal weight of manganese as (i) and lead as (ii), in a gasoline engine to control the amount of NOx and hydrocarbons in the exhaust gas emanating from a gasoline engine adjusted to operate primarily at an air to fuel ratio between lambda of 0.9 to 1.15. By "substantially equal weight of manganese as (i) and lead as (ii)" is meant that the weights of manganese and lead provided by components (i) and (ii), respectively, do not differ from each other by more than 20%. Preferably these weights differ by no more than 10%. Most preferably the weights do not differ from each other by more than 2%, and thus the weights in this case, for all practical purposes, are the same. As noted above, the engines in which the foregoing fuel composition is used are adjusted to operate primarily at air-to-fuel ratios between the lambda values specified above. By "primarily" is meant that in normal operation of the engine it is operating with air-to-fuel ratios in the lambda range specified for over 50% of the total time between engine start-up and engine shut down. Preferably the engine is adjusted to operate within the lambda range herein specified for at least 60%, and more preferably, at least 75%, of the total time between engine start-up and engine shut down. In the practice of this invention, the greater the percentage of time the engine operates within the lambda range herein specified, the greater will be the reduction of the exhaust emissions as compared to a conventional leaded fuel of the same octane quality. Figures 1, 2 and 3 present in graphical form the results of certain emission tests described hereinafter. The gasolines utilized in the practice of this invention can be traditional blends or mixtures of hydrocarbons in the gasoline boiling range, or they can contain oxygenated blending components such as alcohols and/or ethers having suitable boiling temperatures and appropriate fuel solubility, such as methanol, ethanol, methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), tert-amyl methyl ether (TAME), and mixed oxygen-containing products formed by "oxygenating" gasolines and/or olefinic hydrocarbons falling in the gasoline boiling range. Thus this invention involves use of gasolines, including the so-called reformulated gasolines which are designed to satisfy various governmental regulations concerning composition of the base fuel itself, componentry used in the fuel, performance criteria, toxicological considerations and/or environmental considerations. The amounts of oxygenated components, detergents, antioxidants, demulsifiers, for example, that are used in the fuels can thus be varied to satisfy any applicable government regulations, provided that in so doing the amounts used do not materially impair the exhaust emission control performance made possible by the practice of this invention. Use in the practice of this invention of gasoline containing one or more fuel-soluble ethers and/or other oxygenates in amounts in the range of up to about 20% by weight, and preferably in the range of 5 to 15% by weight constitutes a preferred embodiment of this invention. The properties of a typical traditional type hydrocarbonaceous gasoline devoid of any additive or oxygenated blending agent are set forth in the following Table I. Property Test Method Value IBP ASTM D86 30°C 5% ASTM D86 42°C 10% ASTM D86 51°C 20% ASTM D86 60°C 30% ASTM D86 71°C 40% ASTM D86 86°C 50% ASTM D86 103°C 60% ASTM D86 114°C 70% ASTM D86 124°C 80% ASTM D86 140°C 90% ASTM D86 165°C 95% ASTM D86 187°C FBP ASTM D86 222°C RVP ASTM D323 7.4 psi Sulfur ASTM D3120 199 ppm wt Gravity ASTM D287 54.8° API Oxidation Stability ASTM D525 1440 minutes Gum Content, washed ASTM D381 0.4 mg/100mL Gum Content, unwashed ASTM D381 2.0 mg/100mL A typical oxygenated base gasoline fuel blend containing 12.8% by volume of methyl tert-butyl ether has the characteristics given in Table II. Property Test Method Value Density at 15°C ASTM D4052 0.772 kg/L IBP ASTM D86 42°C 10% ASTM D86 63°C 50% ASTM D86 106°C 90% ASTM D86 154°C FBP ASTM D86 199°C % Off at 70°C ASTM D86 16 vol % % Off at 100°C ASTM D86 45 vol % % Off at 180°C ASTM D86 98 vol % RON ASTM D2699/86 97.2 MON ASTM D2700/86 86.0 RVP ASTM D323 0.49 bar Sulfur ASTM D3120 < 0.01% Aromatics ASTM D1319 46.9 vol % Olefins ASTM D1319 2.4 vol % Saturates ASTM D1319 50.8 vol % Component (i) . Illustrative cyclopentadienyl manganese tricarbonyl compounds suitable for use in the practice of this invention include such compounds as cyclopentadienyl manganese tricarbonyl, methylcyclopentadienyl manganese tricarbonyl, dimethylcyclopentadienyl manganese tricarbonyl, trimethylcyclopentadienyl manganese tricarbonyl, tetramethylcyclopentadienyl manganese tricarbonyl, pentamethylcyclopentadienyl manganese tricarbonyl, ethylcyclopentadienyl manganese tricarbonyl, diethylcyclopentadienyl manganese tricarbonyl, propylcyclopentadienyl manganese tricarbonyl, isopropylcyclopentadienyl man-ganese tricarbonyl, tert-butylcyclopentadienyl manganese tricarbonyl, octylcyclopentadienyl manganese tricarbonyl, dodecylcyclopentadienyl manganese tricarbonyl, ethylmethylcyclopentadienyl manganese tricarbonyl, indenyl manganese tricarbonyl, for example, including mixtures of two or more such compounds. Preferred are the cyclopentadienyl manganese tricarbonyls which are liquid at room temperature such as methylcyclopentadienyl manganese tricarbonyl, ethylcyclopentadienyl manganese tricarbonyl, liquid mixtures of cyclopentadienyl manganese tricarbonyl and methylcyclopentadienyl manganese tricarbonyl, mixtures of methylcyclopentadienyl manganese tricarbonyl and ethylcyclopentadienyl manganese tricarbonyl. Preparation of such compounds is described in the literature, e.g., U.S. 2,818,417. Component (ii) . Illustrative alkyllead antiknock compounds suitable for use in this invention include tetramethyllead, methyltriethyllead, dimethyldiethyllead, trimethylethyllead, tetraethyl-lead, tripropyllead, dimethyldiisopropyllead, tetrabutyllead, and related fuel-soluble tetraalkyllead compounds in which each alkyl group has up to about six carbon atoms. The preferred compound is tetraethyllead. Preparation of such compounds is described in the literature, e.g., U.S. 2,727,052; 2,727,053; 3,049,558; and 3,231,510. The alkyllead compound can be used in admixture with halogen scavengers in the manner described for example in such patents as U.S. 2,398,281; 2,479,900; 2,479,901; 2,479,902; 2,479,903; and 2,496,983. Alternatively, the alkyllead compound can be used without any halogen scavenger such as is described for example in 3,038,792; 3,038,916; 3,038,917; 3,038,918 and 3,038,919. In either case, a suitable oxidation inhibitor or stabilizer can be associated with the alkyllead compound, such as is described for example in U.S. 2,836,568; 2,836,609 and 2,836,610. EXAMPLES In order to demonstrate the remarkable results achievable by the practice of this invention, a series of standard tests was conducted using a pulse flame combustion apparatus, a laboratory scale combustion device that has been widely used to study fuel effects on exhaust emissions. The device has been shown to qualitatively simulate the emission performance of spark ignition internal combustion engines under a wide variety of operating conditions. The base fuel used forming the test fuels was a commercially available unleaded regular gasoline. The fuel for the practice of this invention contained 0.1 gram of lead per gallon as tetraethyllead and 0.1 gram of manganese per gallon as methylcyclo-pentadienyl manganese tricarbonyl. In addition, the fuel contained 0.5 theory of bromine as ethylene dibromide and 1.0 theory of chlorine as ethylene dichloride, a theory being two atoms of halogen per atom of lead as the tetraethyllead. Emission levels for the fuels tested were evaluated over a range of rich to lean combustion conditions extending from a lambda of 0.9 to a lambda of 1.15. This air-to-fuel ratio sweep involved making determinations of emissions at eight individual air-to-fuel ratios covering the foregoing lambda range of 0.9 to 1.15. Each determination at a given lambda value was carried out in duplicate. An overall emission value was calculated for the fuels by averaging the emissions measured at each point in the range of air-to-fuel ratios used. For comparative purposes, use was made of a fuel composition made from the same base fuel so as to directly simulate a fuel in wide-spread use in Mexico City. This fuel contained 0.3 grams of lead per gallon. Consequently, the results obtained provide a comparative evaluation of a real-world situation at comparable octane levels, and the benefits of that are achievable by the practice of this invention. It was found that nitrogen oxide emissions were reduced over the entire range of air-to-fuel ratios between a lambda value of 0.9 to a lambda value of 1.15. As compared to the comparative fuel simulating use in Mexico City, a relative reduction in emissions was observed that was significant at least at the 95% statistical confidence level at all air-to-fuel lambda values tested except at stoichiometry. It was also found that in the practice of this invention, hydrocarbon emissions were minimized at all air-to-fuel ratios tested. Once again, as compared to the above comparative fuel, the relative reduction was statistically significant at least at the 95% confidence level at all air-to-fuel ratios tested except at the richest condition at a lambda value of 0.9. Throughout the range of these comparative tests, there was no material difference in carbon monoxide emissions. The results of all of these tests are tabulated in Tables III, IV and V below and depicted graphically in Figures 1, 2 and 3. NOx Emissions, ppm Lambda Value Conventional Practice Practice of the Invention 0.90 257 227 0.95 309 288 0.98 350 315 1.00 358 325 1.02 423 342 1.05 420 345 1.10 411 330 1.15 373 305 Hydrocarbon Emissions, ppm Lambda Value Conventional Practice Practice of the Invention 0.90 2400 2173 0.95 2373 1942 0.98 2184 1747 1.00 1900 1433 1.02 1870 1438 1.05 1640 1203 1.10 1674 976 1.15 2086 1020 Carbon Monoxide Emissions, % Lambda Value Conventional Practice Practice of the Invention 0.90 3.830 3.940 0.95 2.190 2.245 0.98 1.420 1.490 1.00 0.975 0.915 1.02 0.725 0.660 1.05 0.450 0.430 1.10 0.260 0.245 1.15 0.230 0.210 An overall emission value was calculated for the fuels by averaging the emissions measured at each point in the range of air-to-fuel ratios used. Table VI summarizes these averaged emission data. Emission Type Conventional Practice Practice of the Invention NOx (ppm, dry) 362 309 Hydrocarbon (ppm, dry) 2015 1491 Carbon Monoxide (%, dry) 1.26 1.27 A transient method was also used to compare emissions resulting from practice of the invention as compared to conventional practice. In these transient tests, the air-to-fuel ratio was changed periodically by about 3% in a square wave around the stoichiometric point. In one test, the period for the perturbation was 30 seconds and in another test, the period was reduced to 10 seconds. For both tests emissions were measured continuously over several minutes of the switching and an average value was calculated. The average values obtained from these transient tests are summarized in Tables VII and VIII. 30 Second Perturbation Periods Emission Type Conventional Practice Practice of the Invention NOx (ppm, dry) 378 326 Hydrocarbon (ppm, dry) 2097 1943 Carbon Monoxide (%, dry) 1.13 1.06 10 Second Perturbation Periods Emission Type Conventional Practice Practice of the Invention NOx (ppm, dry) 375 331 Hydrocarbon (ppm, dry) 2078 1852 Carbon Monoxide (%, dry) 1.04 0.94 As can be seen from the above results the fuel used in the practice of this invention can contain very small amounts of manganese and lead. In the fuels for the practice of this invention, the total amount of these metals, proportioned as specified hereinabove and dissolved in the fuel in the form of components (i) and (ii), will usually be maintained within the range of 0.025 to 0.5 gram per 3.785 l (U.S. gallon) of fuel. Preferably, the total amount of these metals in the form of components (i) and (ii) will be maintained within the range of 0.05 to 0.3, and more preferably in the range of 0.1 to 0.25, gram per 3.785 l (U.S. gallon) of fuel. In all cases however, the particular amount and proportions of components (i) and (ii) in the particular gasoline fuel used in operating the Otto-cycle engine in the manner described hereinabove must be such as to reduce the amount of NOx and hydrocarbon emissions as compared to the same base fuel containing a higher concentration of the alkyllead compound but no cyclopentadienyl manganese tricarbonyl compound. Particularly preferred fuel compositions for use in the practice of this invention contain 0.08 to 0.12 gram (more preferably about 0.1 gram) of manganese per 3.785 l (U.S. gallon) as the cyclopentadienyl manganese tricarbonyl compound, and 0.08 to 0.12 gram (more preferably about 0.1 gram) per 3.785 l (U.S. gallon) of lead as the tetraalkyllead compound. Other particularly pre-ferred fuel compositions for use in the practice of this invention contain (i) 0.08 to 0.12 gram (more preferably about 0.1 gram) of manganese per 3.785 l (U.S. gallon) as the cyclopentadienyl man-ganese tricarbonyl compound, (ii) 0.08 to 0.12 gram (more preferably about 0.1 gram) per 3.785 l (U.S. gallon) of lead as the tetraalkyllead compound, and (iii) 5 to 15 percent by volume (based on the total volume of the finished fuel) of a gas-oline-soluble oxygen-containing blending agent, preferably an alco-hol and/or an ether, and most preferably at least one fuel-soluble dialkyl ether having a total of at least 5 carbon atoms per molecule. It is contemplated that in the practice of this invention, use of fuels containing the oxygenated blending components (particularly the dialkyl ethers) together with the manganese and lead components will result in significant reductions in carbon monoxide emissions. When utilizing the present invention in connection with motor vehicles, it preferred to employ the invention with vehicles devoid of an exhaust gas catalyst. However, it is possible to utilize the invention with vehicles equipped with lead-resistant exhaust catalysts, that is catalysts that do not materially lose activity even when exposed to lead during operation. Any standard test procedure for measuring NOx and hydrocarbon emissions in the exhaust gas of an internal combustion engine can be used for this purpose provided that the method has been pub-lished in the literature. In the case of motor vehicles, the preferred methodology involves operating the vehicle on a chassis dynamometer (e.g., a Clayton Model ECE-50 with a direct-drive variable-inertia flywheel system which simulates equivalent weight of vehicles from 453.6 to 4025.6 kg (1000 to 8875 pounds) in 56.7 kg (125-pound) increments) in accordance with the Federal Test Procedure (United States Code of Federal Regulations, Title 40, Part 86, Subparts A and B, sections applicable to light-duty gasoline vehicles). The exhaust from the vehicle is passed into a stainless steel dilution tunnel wherein it is mixed with filtered air. Samples for analysis are withdrawn from the diluted exhaust by means of a constant volume sampler (CVS) and are collected in bags (e.g., bags made from Tedlar resin) in the customary fashion. The Federal Test Procedure utilizes an urban dynamometer driving schedule which is 1372 seconds in duration. This schedule, in turn, is divided into two segments; a first segment of 505 seconds (a transient phase) and a second segment of 867 seconds (a stabilized phase). The procedure calls for a cold-start 505 segment and stabilized 867 segment, followed by a ten-minute soak then a hot-start 505 segment.

Claims: Use of a gasoline fuel containing a minor exhaust-emission reducing amount of (i) a cyclopentadienyl manganese tricarbonyl compound and of (ii) an alkyllead antiknock agent, wherein (i) and (ii) are proportioned such that there is dissolved in said fuel substantially equal weights of manganese as (i) and lead as (ii), in a gasoline engine adjusted to operate primarily at an air-to-fuel ratio such that lambda is from 0.9 to 1.15 to reduce the amount of NOx and hydrocarbons in the engine exhaust on combustion of said fuel in said engine, where lambda is the actual air-to-fuel ratio divided by the stoichiometric air-to-fuel ratio, said stoichiometric air-to-fuel ratio being a lambda value of one. Use according to claim 1, wherein said engine is adjusted to operate primarily at an air-to-fuel ratio between lambda of 1.0 to 1.15. Use according to claim 1 or 2, wherein said fuel contains about 0.1 gram of manganese per 3.785 litres (U.S. gallon) as (i) and about 0.1 gram of lead per 3.785 litres (U.S. gallon) as (ii). Use according to claim 1 or 2, wherein (i) is methylcyclopentadienyl manganese tricarbonyl and (ii) is tetraethyllead. Use according to claim 1, wherein said engine is adjusted to operate primarily at an air-to-fuel ratio lambda from 1.0 to 1.15, said fuel contains about 0.1 gram of manganese per 3.785 litres (U.S. gallon) as (i) and about 0.1 gram of lead per 3.785 litres (U.S. gallon) as (ii), and (i) is methylcyclopentadienyl manganese tricarbonyl and (ii) is tetraethyllead. Use according to any one of the preceding claims, wherein said engine is in a motor vehicle devoid of an exhaust gas catalyst. Use according to any one of the preceding claims, wherein said fuel contains 5 to 15 percent by volume, based on the total volume of the fuel, of a gasoline-soluble oxygen-containing blending agent. Use according to claim 7, wherein said blending agent is an alcohol or an ether. Use according to claim 8, wherein said blending agent is a dialkyl ether. Use according to any one ofthe preceding claims, wherein said engine is adjusted to operate at said air-to-fuel ratio for at least 75% of the total time between engine start up and engine shut down.

Inventors: PERRY NEWTON A, ROOS JOSEPH W, PERRY, NEWTON A., ROOS, JOSEPH W.
Applicants: ETHYL CORP, ETHYL CORPORATION
Application year: 1995
Main classification: C10L1
IPC codes: F02B75, C10L1, F02B1, C10L10