AQUEOUS COATING COMPOSITIONS

Abstract: A composition comprising water and the following components: (a) an epoxy compound comprising at least one epoxy group and at least one nitrogen atom; and (b) a carboxy functional polymer, a hydroxy functional polymer, a polymer having carboxy and hydroxy functionality, or a mixture comprising two or more of said polymers; provided that when the epoxy compound has only one epoxy group it has at least one hydrolysable silyl group. Also claimed are epoxy cross-linkers, films, coatings and processes for their preparation.

Description: AQUEOUS COATING COMPOSITIONS The present invention relates to epoxy compounds, to aqueous cross-linkable coating compositions containing a specified epoxy compound and a hydroxy and/or carboxy functional polymer, and to films and coatings obtained therefrom. Industrial coatings are prepared to protect and decorate underlying materials. Originally, these coatings were primarily organic solvent-borne systems, but the development of water-borne coatings has become of increasing interest for a number of reasons. The main reasons for the shift frσn organic solvent-borne coatings to aqueous alternatives is to decrease the amount of organic solvent emitted into the atmosphere. In the development of water-borne coatings it has become apparent that the quality of the coating performance is often inferior to that of solvent-borne coatings. It is known that to improve the properties of the aqueous coating the components of the composition need to be designed such that they react and cross-link with the binder on the substrate. Because of the temperature sensitive nature of many of the substrates it is preferred that such compositions will undergo effective cross-linking at ambient temperatures without the need for catalysts, particularly toxic catalysts. We have now devised a highly effective water-based cross-linkable coating composition which can give films and coatings having good mechanical and physical properties. According to the present invention there is provided a composition comprising water and the following components: (a) an epoxy compound comprising at least one epoxy group and at least one nitrogen atom; and (b) a carboxy functional polymer, a hydroxy functional polymer, a polymer having carboxy and hydroxy functionality, or a mixture comprising two or more of said polymers; provided that when the epoxy compound has only one epoxy group it has at least one hydrolysable silyl group. The epoxy compound preferably has from 1 to 10, more preferably from 1 to 6, epαxy groups. The epoxy groups are alicyclic or preferably aliphatic. In alicyclic epαxy groups the carbon atoms of the epoxy ring form an alicyclic ring, preferably 5-, 6- or 7-membered (for example a cyclopentane or cyclchexane ring) , whereas in aliphatic epαxy grσups the carbon atoms of the epoxy ring form an aliphatic chain. Examples of aliphatic epαxy groups are shown in (I) and (II) and alicyclic epαxy groups are shown in (III) and (IV) . ( i ( i l l ) I V ) Examples of epoxy compounds include those having one epoxy group, at least one nitrogen atom and at least one hydrolysable silyl group and those having more than one epoxy group, at least one nitrogen atom and, optionally, one or more hydrolysable silyl groups. We have found that when the epoxy group in component (a) has an ester group (i.e. -0-C(=0)-) an an adjacent carbon atom then component (a) is a more effective cross-linker for component (b) in terms of the speed and extent of cross-linking. This improvement is particularly marked when the epoxy group is an aliphatic epαxy group. ISxarnples of epoxy groups having an ester group on an adjacent carbon atom are shown in formulae (V) , (VI) , (VII) and (VIII) below: (VII) (VIII) Preferably the nitrogen atom in component (a) is a basic nitrogen atom because this leads to particularly effective cross-linking of component (b) . The nitrogen atom in component (a) is preferably a secondary amino group, more preferably a tertiary a ino group because the epαxy compounds having tertiary amino groups are generally more storage stable. When the nitrogen atom is a secondary amino group it is preferred that the epoxy group(s) is or are 5-, 6- or 7-membered alicyclic rings because these tend to be more storage stable than compounds wherein the epoxy group is aliphatic. The pKa of the basic nitrogen atom preferably lies in the range 1 to 12, more preferably 5 to 11. It is preferred that component (a) has at least 1 or 2 hydrolysable silyl groups. A hydrolysable silyl group is a group which is convertible to a hydroxysilyl group an treatment with aqueous acid or base. A preferred hydrolysable silyl group is of the formula -SiCR 1 ^ wherein each R 1 independently is optionally substituted alkyl (especially C-. 4 -alkyl) or optionally substituted alkoxy (especially C__ 4 - alkαxy or a poly(oxyalkylene) , provided at least one R 1 is optionally substituted alkαxy. Preferably all three groups represented by R 1 are C 1-4 -alkαxy. When one, two or three of the R 1 groups are optionally substituted alkoxy groups the hydroxysilyl groups obtainable from the hydrolysable silyl group are respectively of formula -SiOH, -Si(QH) 2 and -Si(OH) 3 wherein the remaining valencies of Si are taken up by the other R 1 groups. Examples of hydrolysable silyl groups include each of -Si(00. 3 ) 3 , -Si.OCEgjCH,, -S_(OC3_C_;) 3 and -Si.O_H.CH 3 ) O(C__0_0) 2 CH 3 __. Component (a) is preferably water-soluble or, more preferably, water-dispersible. Water-solubility and water dispersibility may be achieved by the presence of sulpho, carboxy or poly(oxyalkylene) groups (especially poly(αxyethylene) and poly(oxyprσpropylene) groups) . The poly(oxyalkylene) groups may be attached to the nitrogen atom in ccmpαnent (a) or, if present, to the silicon atom in the hydrolysable silyl group. A preferred epαxy compound which may be used as component (a) is of the Formula (1) : wherein: X is E-(L 4 -0) m -(C0) n - (T) p -; Y is -Si(R 1 ) 3 or X as hereinbefore defined; T is 0, CH_ or NR 2 ; P is 0 or 1; q is 0, 1, 2, 3 or 4; E comprises an epoxy group,- each L 1 , L 2 , L 3 and L 4 independently is a divalent organic linker group; m and n are each independently 0 or 1; and each R 2 independently is H or optionally substituted alkyl or acyl. When q is 2, 3 or 4 each L 2 may be the same or different. Compounds of Formula (1) wherein n is 1 form a further feature of the invention. Preferably m and n are both 1. Preferably p is 0. In a preferred epoxy compσurid of Formula (1) , m=n=q_l; p=0; L 1 , L 2 , 3 and L 4 are optionally substituted alkylene groups containing from 1 to 6 carbon atoms (especially -CH_-, -(CH_) 2 - or -(C__) 3 -); Y is - SifR'lj wherein each R 1 independently is cptiαnally substituted alkyl (especially C__ 4 -alkyl) or optionally substituted alkoxy (especially C__ 4 - alkαxy or a poly(oxy alkylene) ) , provided at least one R 1 is optionally substituted alkαxy; E is of formula (ii) , (iii) or (iv) (especially of formula (ii) ) ,• and one group represented by R 2 is of formula -I -X wherein 1 and X are as hereinbefore defined (with the preferences for E, L 4 , m, n and p as above) and the other group represented by R 2 is H, optionally substituted alkyl or acyl (especially H or -CONHfC^ o -alkyl) , more especially H or -CONH(C_. 4 -alkyl) ) . An especially preferred compound of Formula (1) is of the formula: Wherein each R 1 independently is C__ 4 -alkyl or C_. 4 -alkαxy, provided at least one R 1 is C__ 4 -alkαxy; and one E is H or -CQNH(C_. 20 - alkyl) and the other two groups represented by E are of the formula: A second preferred class of epαxy compound is of Formula (2) wherein: L 1 , L 2 , X, Y and R 2 are as hereinbefore defined; L 5 , 6 and L 7 are each independently divalent organic linker groups; a is 2 to 6; b is 6- (a+c) ; c is 0 to 4; and (a+b+c) = 6. An alternative class of epoxy compound having at least one epoxy group, at least one nitrogen atom and at least one hydrolysable silyl group is of Formula (2) wherein a is 1 to 5; b is 0 to 4; and c is 1 to 5; provided that (a+b+c) = 6; each L 1 , L 2 , L 5 , L s , L 7 and X are as hereinbefore defined and Y is of the formula -Si(R 1 ) 3 as hereinbefore defined. E is preferably of formula (ii) , (iii) or (iv) shown above. The divalent organic linker groups are preferably optionally substituted alkylene, arylene or aralkylene. Preferred cptiαnally substituted alkylene groups contain from 1 to 6 carbon atoms, more preferably 1 to 4 carbon atoms. A preferred optionally substituted arylene group is phenylene. A preferred optionally substituted aralkylene group contains from 7 to 10 carbon atoms, especially benzylene. The optional substituents which may be present on the divalent organic linker groups are preferably methyl, amino, ether, hydroxy or ester groups. The divalent organic linker groups may contain or be free from hetero linking atoms, for example ether or thioether groups. Examples of preferred groups represented by L 1 , L 2 , L 3 , L 4 , L 5 , L 6 and L 7 include -CH_-, -(CH,),-, -(_H_) 3 -, -(C__) 4 -, -C_^-_HOH-C_.-, -CH 2 -CΗ(CX3_CH 2 COC_- 3 )-CH 2 -, -CH_CH_(0CH_CH 2 ) loI _-, -CH_ (00 . 0.(01,) ) 1∞2 -, -CfCHjCH s ) (X) -Cr_OCH(OH)-CH_- (wherein X is as hereinbefore defined) , - (CH_) 4 0CH(OH)CH,- and phenylene. In Formulae (1) and (2) when R 2 is optionally substituted alkyl it is preferably alkyl which is unsubstituted or substituted by a poly(oxyalkylene) group, an epoxy group and/or by a hydrolysable silyl group. Thus R 2 is preferably of formula -V—X wherein X and L 1 are as hereinbefore defined. When R 2 is acyl it is preferably of the formula -C0(C 1 . 4 -alkylene)-C0__I(C 1-4 -alkyl) , -CONH(C__ β -alkyl) or -CO(C^-alkylene) - CO(C 1-4 - lkyl) . When R 2 is H the -NR 2 - group is a secondary arnino group, and when R 2 is optionally substituted alkyl -NR 2 - is a tertiary amino group. Components (a) and (b) are each independently dissolved or dispersed in the water. Thus the composition may be an aqueous dispersion or solution. "Aqueous dispersion" means a dispersion of a component in an aqueous carrier medium of which water is the principal component (usually at least 40 or 55 weight % of the carrier medium) . Minor amounts of organic liquid(s) may be present if desired or required. Typically, component (b) will be in the form of an aqueous latex. Compositions of the invention cross-link well to give film coatings having good mechanical properties and chemical resistance and some have low toxicity. The cross-linking may be performed at ambient temperatures without using toxic catalysts. If desired one may use a catalyst to speed up cross-linking still further. Suitable catalysts include secondary and tertiary amines, especially triethyl amine and tributylamine. It is preferred that a substrate is coated using the composition of the present by applying the composition to a substrate, drying at ambient temperature and ageing the coating so formed at ambient temperature e.g. to develop cross-linking in the coating. The invention also provides a process for forming a film or coating on a substrate comprising applying thereto a composition according to the invention and allowing water to evaporate therefrom, for example at a temperature of 10°C to 30°C, or above 30°C and below 250°C. The weight ratio of component (a) to component (b) preferably lies in the range 0.1:100 to 35:100, more preferably 0.5:100 to 25:100, especially 1:100 to 15:100. Carboxy functional polymer The choice of carboxy functional polymer used as component (b) will depend upon the properties required for the cross-linkable composition. The carboxy functional polymer preferably has a number average molecular weight of from 100 or 500 to 500,000. Preferably the carboxy functional polymer contains an average of at least 1 carboxy group per molecule, more preferably at least 2. Polyesters, polyurethanes and olefinic polymers are preferred and may be used, provided they have a carboxy functionality. As carboxy functional polymer there may be used an addition polymer or a condensation polymer, preferably formed by polymerisation of monomers which provide carboxy groups in the resultant polymer with monomers which do not provide carboxy or hydroxy groups in the resultant polymer. The carboxy functional addition polymer is preferably formed by a free radical polymerisation process, more preferably under aqueous emulsion polymerisation conditions, preferably using a mixture of olefinically unsaturated carboxy functional monomers and olefinically unsaturated monomers which are free from hydroxy and carboxy groups. Alternatively, esters of the olefinically unsaturated monomers may be used to give an ester functional polymer and the ester groups hydrolysed to give the desired carboxy functional polymer. The carboxy functional condensation polymer may be formed by condensation of a polyol and a polyacid (to give a polyester) or of a polyol and polyisocyanate (to give a polyurethane) or of a polyol, polyacid and polyisocyanate (to give a polymer having ester and urethane groups) . Preferred olefinically unsaturated carboxy functional monomers include olefinically unsaturated carboxylic acids, more preferably mono- and dicarbαxylic acids, especially those having 3 to 5 or 6 carbon atoms, more especially acrylic acid, methacrylic acid, fumaric acid, itacαnic acid and β-carboxyethyl acrylate (β-CEA) . Examples of olefinically unsaturated monomers which are free from carboxy and hydroxy groups include 1,3-butadiene, isoprene, styrene, divinyl benzene, acrylαnitrile, methacrylσnitrile, vinyl halides (e.g. vinyl chloride) , vinylidene halides (e.g. vinylidene chloride) , vinyl esters (e.g. vinyl acetate, vinyl propiσnate and vinyl laurate) , (meth)acrylamides, heterocyclic vinyl compounds, alkyl esters of monolefinically unsaturated dicarboxylic acids (e.g. di-n-butyl maleate and di-n-butyl fumarate) and esters of acrylic acid and methacrylic acid of formula: CH_ = CR S COOR 6 where R s is H or methyl and R 6 is an optionally substituted alkyl or cycloalkyl groups of 1 to 20 carbon atoms (more preferably 1 to 8 carbon atoms) or an alkoxysilane group, examples of which are methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, isoprcpyl acrylate, isσprσpyl, methacrylate, n-prcpyl acrylate, n-prσpyl methacrylate and various alkoxysilane functional acrylates and methacrylates, • as mentioned supra R β may also be substituted and such substituents may e.g. be or include functional groups such as amino groups, olefinically unsaturated double bonds and halide atoms such as fluorine, and examples of such monomers include (t- butylamino)ethyl (meth)acrylate, allyl (meth)acrylate, 1,1,1- trifluoroethyl (meth)acrylate and hexafluoroisoprσpyl (meth)acrylate. It is preferred that the carboxy functional addition polymer is derived from a mixture of monomers which comprise from 0.4 to 40% by weight of one or more carboxy functional monomers, more preferably 1.5 to 20%, by weight, and the rei ining monomers which make the balance to 100% are free from carboxy and hydroxy groups. Polymerisation of the monomers is normally effected in an aqueous medium and in particular aqueous emulsion polymerisation is used to prepare an aqueous latex of the polymer with conventional surfactants and initiators being used. The resulting latex of the polymer could be used "as is" in the composition (apart from optional dilution or concentration or the addition of coalescing solvent to assist in film formation) and can be partially or fully neutralised before use. Alternative radical polymerisation methods can be used, for example polymerisation in the bulk or in solution, followed by addition to water. As mentioned above, polymers other than olefinic addition polymers can be used as the carboxy functional polymer. For example a polyurethane or polyester polymer bearing carboxyl groups (e.g. laterally or terminally disposed) can be used. As is well known polyurethane polymers (or analogous polymers such as polyurethane ureas or polyureas) , are generally made by reacting an organic polyisocyanate with an organic c rpound containing at least two isocyanate-reactive groups, particularly a macropolyol with the optional inclusion of a low molecular weight polyol. A favoured route to their formation involves the formation of an isocyanate-terminated prepolymer followed by chain extension with an active hydrogen containing compound. A polyurethane bearing carboxy groups can be made by employing as a reactant, in the polyurethane prepolymer formation step, an isocyanate-reactive compound having at least one carboxy group and at least two isocyanate-reactive groups (such as 2,2-dimethylolpropiαnic acid) , together with other compound(s) bearing isocyanate-reactive groups (usually polyol(s) ) , to form a prepolymer bearing lateral carboxy groups, followed by chain- extension with an active hydrogen containing compound (e.g. hydrazine or a diamino ccxrpσund) . Some of the carboxy groups of the polyurethane can be neutralised with an appropriate base to render it more readily water- dispersible, or the polyurethane could incorporate lateral or terminal or in-chain nan-ionic groups (such as poly(αxyethylene) chain groups) to enhance water-dispersibility (or a combination of both expedients could be used) . Hydroxy functional polymers Preferably the hydroxy functional polymer contains an average of at least 1 hydroxy group per molecule, more preferably at least 2. Polyester polymers bearing hydroxy groups may be prepared by methods known in the art, for example by reacting an excess of a polyol with a diacid. Hydroxy functional polyurethane polymers may be prepared by methods known in the art, for example by reacting excess polyol with an isocyanate, or by reacting an isocyanate-terminated polyurethane with a hydroxyamine to give the desired hydroxy functionality. Functional groups other than carboxy may be present in or absent from the hydroxy functional polymer, for example sulpho and/or phosphato groups may be present to aid water-solubility or dispersibility of the polymer. These groups may be incorporated using commercially available sulpho and phosphato functional monomers, for example sulphoethyl(meth)acrylate or acrylaiixidomethylprcpanesulpihαnic acid. Hydroxy functional polymers may be prepared by free radical polymerisation exactly as described above in relation to carboxy functional polymers except that an olefinically unsaturated hydroxy functional monomer is used in place of the olefinically unsaturated carboxy functional monomer. Examples of olefinically unsaturated hydroxy functional monomers include N-methylol (meth)acrylamide, hydrαxy C__ 8 -alkyl esters of (meth)acrylic acid, e.g. hydrcxyethyl(meth)acrylate, hydroxypropyl(meth)acrylate and mixtures thereof. Polymers having carboxy and hydroxy functionality Carboxy and hydroxy functionality may be introduced by a free radical polymerisation process, for example free radical polymerisation of a mixture comprising an olefinically unsaturated carboxy functional monomer (e.g. as described hereabove) , an olefinically unsaturated monomer having at least one hydroxy group (e.g. as described hereabove) , preferably in the presence of an olefinically unsaturated monomer which is free from carboxy and hydrαxy groups. Examples of monomers which are free from carboxy and hydroxy groups are as hereinbefore described in relation to the carboxy functional polymer. Two convenient routes for the preparation of hydroxy functional polyurethanes are described by P.B. Jacobs and P.C. Yu in J. Coatings Technology, .65, No. 822, July 1993. One route involves reacting an diol or polyol with a deficiency of isocyanate, for example a polyisocyanate is reacted with an excess of polyester diol and/or polyol and dimethylol prqpionic acid (DMPA) to produce a hydroxy terminated polyurethane oligomer having a carboxy group. A second route involves reacting a polyisocyanate, a polyol and EMPA to give an isocyanate terminated polymer which is reacted with an amino alcohol to give a hydroxy functional polyurethane polymer having a carboxy group. Hybrid polymers having both hydroxy and carboxy functionality may also be used as component (b) of the composition. Such hybrids can be prepared by a number of methods includi g (a) polymerising a hydroxy functional monomer in the presence of a carboxy functional polymer, (b) polymerising a carboxy functional monomer in the presence of a hydroxy functional polymer, (c) polymerising a hydroxy functional monomer and/or a carboxy functional monomer in the presence of a polymer having both hydroxy and carboxy functionality, (d) polymerising a hydrαxy functional monomer and a carboxy functional monomer in presence of a polymer having neither hydroxy or carboxy functionality, and (e) polymerising monomers which are free from hydrαxy and carboxy groups in the presence of a polymer having both hydroxy and carboxy functionality. The polymers referred to in (a) , (b) , (c) , (d) and (e) above are preferably polyurethanes or polyesters. Usually the polymerisation method for forming hybrid polymers is free radical polymerisation process, and the hydrαxy functional monomers and carboxy functional monomers are olefinically unsaturated hydrαxy functional monomers and olefinically unsaturated carboxy functional monomers respectively, especially those described earlier in this specification. In the case of free radical polymerisation of a hydroxy functional monomer or carboxy functional monomer in the presence of a polymer there is normally present one or more olefinically unsaturated monomers which are free from carboxy and hydroxy groups. Mixtures comprising two or more of said Polymers Mixtures and blends of polymers described for component (b) may also be used, for example a mixture comprising the aforementioned hydroxy functional polymer and carboxy functional polymer, or mixtures comprising either or both of these with the polymer having carboxy and hydrαxy functionality. The acid groups which may be present in components (a) and (b) may be in the free acid or salt form, preferably salt form. The compositions of the invention preferably have a solids content within the range of from 10 to 70 wt.%, more preferably 30 to 50 wt.%. The composition may be used as aqueous coating compositions to give films and coatings of excellent properties, and in particular excellent solvent resistance. For this purpose they may be used "as is" or further diluted with water and/or organic solvents, or they may be supplied in more concentrated form by evaporation of water and/or organic components of the liquid medium. As coating compositions, they may be applied to a variety of substrates includ g wood, paper, cardboard, metals, glass, cloth, leather, concrete, paper, plastics, foam and the like, by any conventiαnal method includi g brushing, dipping, flow coating, spraying, and the like. The liquid carrier phase is removed (drying) at elevated or even at ambient temperatures, to form a film or coating. If desired the resultant film or coating can be heated at moderately elevated temperatures to accelerate the cross linking, although very often merely ageing the coating at ambient temperatures will be sufficient to develop excellent cross-linking. The compositions may contain other conventional ingredients, including organic coalescing solvents, pigments, dyes, emulsifiers, surfactants, thickeners, heat stabilisers, levelling agents, wetting agents, anti-cratering agents, fillers, sedimentation inhibitors, fire retardants, UV absorbers, antiαxidants and the like introduced at any stage of inaking the composition or subsequently. The compositions may also be formulated as paints, adhesives or used as binders for printing inks or as overprint lacquers, varnishes and sealants. The present invention also provides a film and a substrate coated by a film wherein the film is obtained or obtainable by evaporation of water from the composition according to the present invention. The preferred substrates are as described above. The present invention is now illustrated by the following examples. Unless otherwise specified, all parts and percentages are by weight. The MEK rub resistance test described in the examples assesses the solvent resistance of a film derived from a composition cast on a glass substrate and cured under the conditions indicated. A rag soaked in MEK is rubbed an the film to and fro until the film fails (i .e. is showing through) and the number of double rubs is recorded, If the film is still present at 200 double rubs it is rated as follows 200 (0/5) film just failed 200 (1/5) film is severely affected 200 (2/5) film is affected 200 (3/5) film is slightly affected 200 (4/5) film is hardly affected 200 (5/5) film is unaffected The following abbreviations are used in the Examples: AA = acrylic acid BA = butylacrylate HEA = hydroxyethylacrylate MAA = methacrylic acid MMA = methylmethacrylate MEK = methylethylketαne β-CEA = beta-carboxyethylacrylate APTMS = 3-arrιinσprσpyltrimethαxysilane APS = ammonium persulphate Akyposal = sodium lauryl ether sulphate from Chem-y Chem. Fabrik 9278R GmbH, Germany. Example 1 Stage a) - Component ___. Preparation of 2,3-epαxycyclohexylmethylacrylate (36.4g) was added to a stirred solution of 1,4-diaminobutane (4.4g) in CH_C1 2 (40cm 3 ) at 30°C and the resultant mixture stirred at 20°C for 4 days. Evaporation of the solvent gave the title product, having 4 alicyclic epαxy groups and two tertiary basic nitrogen atoms, as a yellow oil in approximately 98% yield. Stage b) - Component (b) A monomer emulsion was prepared by mixing deiσnised water (1275g) , Akyposal 9278R (250.2g of a 30% solution in deiαnised water), APS (18.6g) , β-CEA (274.3g) , BA (1616.Og) and MMA (1816.2g) . About 10% of the monomer emulsion was added to a vessel containing deiσnised water (2870g) and Alkyposal 9278R (83.4g of a 30% solution in deiαnised water) of a 30% solution in deiαnised water and the mixture was stirred for 30 minutes, then heated to 85°C and stirred for a further 30 minutes. The remaining monomer emulsion was added to the vessel over 2 hours whilst maintaining a temperature of 85-88°C, then the temperature was raised to 90°C and the inixture was stirred for 1 hour. The mixture was cooled to room temperature, filtered through a 200μm screen and the filtrate was adjusted to pH6.8 "using dilute aqueous ammonia. The resultant carboxy functional polymer had the composition BA (43.6%), MMA (49.0%) and β-CEA (7.4%). The solids content was 43.5% w/w. Stage c) - Composition A composition was prepared by mixing equimolar parts of the product from component (a) with the product from stage b) . (In this specification equimolar means the total number of carboxy groups in the polymer is equal to the number of epαxy groups in component (a) ) . The composition was found to be stable at 22°C for several weeks. The composition was applied to glass at 22°C using a Sheen Bar to give a wet film thickness of lOOμm. After heating at 52°C for 18 hours, the resultant film was resistant to over 200 MEK double rubs (200 3 / 5 ) . Stage d) - Comparative test The method of stage c) was repeated and except that in place of the product from stage a) there was used 3,4-epαxycyclohexylmethyl- (3,4-epαxy)cyclchexane carbαxylate which does not contain a nitrogen atom [ERC 4221] . The resultant film was found to be resistant to only 120 MEK double rubs. Example 2 Stage a) - Component (a) Preparation of a polyepoxide of the formula (R) 2 NCH_CH_N(R)O.O.N(R)CELCH-N(R) 2 wherein R is: 2,3-epoxycyclchexylmethylacryclate (91g) was added over 1 hour to a solution of triethylene tetraπiine (12.2g) in CH_C1 2 (50cm 3 ) . Methanol (50cm 3 ) was added to the mixture and, after 3 days, the solvents were evaporated to give the title product as a yellow/brown oil. Η-NMR indicated approximately 95% yield of the title product having four tertiary basic nitrogen atoms and six alicyclic epoxy groups . Stage b) - Component (b) A carboxy functional polymer was prepared as described in Example 1, stage b) . Stage c) - Composition A composition was prepared by mixing equimolar amounts of the product from stage a) with the product from stage b) based on the number of epoxide and carboxylic acid groups. The composition was found to be stable at 22°C for several weeks. The composition was applied to glass and, after heating for 18 hours at 52°C, the resultant film was resistant to over 200 (200 4 / 5 ) MEK double rubs showing it to be more effective than the film derived from 3,4-epαxycycldhexylmethyl- (3,4- epoxy)cyclchexane described in Example 1, stage c) . Example 3 Stage a) - Component (a) Preparation of a an epoxy compound of the formula (R) 2 N-_H(CH 3 )CH 2 (OCH_CH(CH 3 ))--N(R) 2 (from Jeffamine D230, available from Texaco) wherein R is as shown in Example 2 and p is about 3. 2,3-epoxycyclchexylmethylacryclate (9lg) was added to a solution of 30g of an amine of formula H__ICH(OI.)a_ (OCHjOKO.) ) P -N__ equivalent wt active H of 60 in CH_C1 2 (50cm 3 ) . Methanol (50cm 3 ) was added and the mixtuure left to stand until no double bands were detected by Η-nmr. The solvents were evaporated to give the above epoxy compound, having two basic nitrogen atoms and four alicyclic epoxy groups, as a pale yellow oil in approximately 95% yield. Stage b) - Component (b) A carboxy functional polymer was prepared as described in Example 1, stage b) . Stage c) - Composition A composition was prepared by mixing equimolar amounts of the product from stage a) with the product from stage b) . The composition was found to be stable at 22°C for several weeks. The composition was applied to glass and, after curing at ambient temperature for 7 days or for 18 hours at 52°C, the resultant film was resistant to over 200 MEK double rubs. A control test in which the epoxy compound was absent gave an MEK double rub resistance of less than 20. Example 4 Stage a) - Component (a) Preparation of an epoxy compound of the formula (R) 2 N-O_O^(0CH 2 σi 2 ) p -N(R) 2 wherein p is about 2 and R is as shown in Example 2, having an equivalent wt based on active H of 36. 2,3-epoxycyclohexylmethylacryclate (91g) was added to a solution of an amine of formula H_NCH_C-_ (OCH_CH_) P -NH_ equivalent wt 36 (18g, available as Jeffarnine EDR 148 from Texaco) in CH_C1 2 (50cm 3 ) . After standing for 10 days the solvent was evaporated to give the epoxy compound, having two basic nitrogen atoms and four alicyclic epαxy groups, as a yellow oil. Stage b) - Component (b) A carboxy functional polymer was prepared as described in Example 1, stage b) . Stage c) - Composition A composition was prepared by mixing equimolar amounts of the product from stage a) with the product from stage b) . The composition was found to be stable at 22°C for several weeks. The composition was applied to glass plate and when heated at 52°C for 18 hours, or left at ambient temperature for 7 days, gave a film which was resistant to over 200 MEK double rubs. A control test in which the epoxy compound was absent gave an MEK double rub resistance of less than 20. Example 5 Stage a) - Component (a) Preparation of an epoxy compound of the formula wherein x+y+z is from 5-6 and R is a defined in Example 2. 2,3-epoxycyclαhexylmethylacrylate (91g) was added to a solution of the above compound where R is H (40.5g, NH equivalent = 81, available as Jeffarnine T403 from Texaco) in CH.C1 2 (60cm 3 ) . Methanol (50cm 3 ) was added and, after standing for 25 days, the solvents were rαnσved in vacuo to give the above compound having three tertiary basic N atoms and 5-6 epoxy groups in approximately 94% yield. Stage b) - Component (b) A carboxy functional polymer was prepared as described in Example 1, stage b) . Stage c) - Composition A composition was prepared by πiixing equimolar amounts of the product from stage a) with the product from stage b) . The composition was found to be stable at 22°C for several weeks. The composition was applied to a glass plate at 22°C and after curing at room temperature for several days, or at 52°C for 18 hours, a film formed which was resistant to over 200 MEK double rubs (200 4 / s ) . A control test in which the epαxy compound was absent gave an MEK double rub resistance of less than 20. __-ample 6 Stage a) - Component (a) Preparation of an epoxy compound of the formula: wherein x+y+z is from 5 to 6. 2,3-epαxycyclαhexylmethylacryclate (0.2 moles) was added to a solution of Jeffarnine T403 (40.5g) in CH_C1 2 (35cm 3 ) and methanol (25cm 3 ) . After 24 hours 0.2 moles of a compound of the formula: was added portiαnwise at 20°C. After 4 weeks standing the reaction was 95% complete and gave the title product, having three basic nitrogen atoms, two alicyclic epαxy groups and two hydrolysable silyl groups. Stage b) - Component (b) A carboxy functional polymer was prepared as described in Example 1, stage b) . Stage c) - Composition A composition was prepared by mixing 6.8 parts of the product from stage a) with 100 parts of the product from stage b) . The composition was found to be stable at 52°C for several weeks. The composition was applied to glass and, when cured for 7 days at ambient temperature or 52°C for 18 hours, the resultant film was resistant to over 200 MEK double rubs (200 4 / 5 ) . A control test in which the epoxy compound was absent gave an MEK double rub resistance of less than 20. Stage d) - Comparative test The method of stage c) was repeated in an identical manner except that in place of the product from stage a) there was used ERC 4221 which does not have a basic nitrogen atom or a hydrolysable silyl group. The resultant film was resistant to less than 50 MEK double rubs. Example 7 Stage a) - Component (a) Preparation of ( CH 3 CH_0) 3 - S i - ( C ι ) y CH . CH_ 2,3-Epαxycyclchexylmethacrylate (36.4g) was added to a stirred solution of 3-aminopropyltriethyaxysilane (22g) in CH_C1 2 (50ml) . After 6 days stirring at room temperature the solvent was removed in vacuo to give the title product, which contains one basic nitrogen atom, two alicyclic epαxy groups and one hydrolysable silyl group, as a yellow oil. Stage b) - Component (b) A carboxy functional polymer was prepared by emulsion polymerisation of BA (43.6%) , MMA (49%) , β-CEA (7.4%) and was found to have 45% solids. Stage c) - Composition A composition was prepared by mixing 10 parts of the product from stage a) , adjusted to pH 7.2, and an equimolar amount of the product from stage b) . The composition was applied to glass and, after storage at room temperature for 7 days, the resultant film was resistant to over 200(4) MEK double rubs. A control test in which the epαxy compound was absent gave an MEK double rub resistance of less than 20. E___πple 8 Stage a) - Component (a) Preparation of O.CH 2 CH 2 0) 2 -CH 3 312 :H 3 CH 2 0- S i - [ CH 2 ) 3 - -CH 2 CH 2 CO Met±ioxyethoxyethanol (0.4 moles) was added to 3-aminopropyltriethoxy silane (0.2 moles) and the mixture was heated at 130°C for 3 hours. The mixture was cooled and CH_C1 2 (75ml) added, followed by 2,3-epαxycyclohexylmethacrylate (0.4 moles) . When no unsaturation was detected by _.-NMR the solvent was removed in vacuo to give the title product, which contains one basic nitrogen atom, two alicyclic epαxy groups and one hydrolysable silyl group, as a yellow viscous oil. Stage b) - Component (b) A carboxy functional polymer was prepared as described in Example 7. Stage c) - Composition A composition was prepared by mixing 10 parts of the product from stage a) with an equimolar amount of the product from stage b) . The composition was applied to glass and, after storage at room temperature for 7 days, the resultant film was resistant to 200 3 / s MEK double rubs. A control test in which the epαxy compound was absent gave an MEK double rub resistance of less than 20. Example 9 Stage (a) Preparation of epoxy corπpounds Preparation I - C H 2 — j-N - ( C H 2 ) 3 - S i ( O C 2 H 5 ) ( I ) To trimethylolpropanetriglycidylether (4.5g, "Heloxy 5048" ex Hi-Tek Polymers. Epoxide equivalent wt = 145-165) was added 3- aminopropyl triethαxysilane (l.lg); Epoxide:active NH 3:1. After 3 days at ambient temperature the ratio of epoxide groups to silicon was shown by NMR to be 2:1 corresponding to the above formula. Preparation II APTMS (11.lg) was added to a solution of Heloxy 5048 (45g) in dry CH.C , (50ml) . After the exotherm had subsided the mixture was left at room temperature for 18 hours, then treated with freshly distilled diketene (8.4g) and dimet ylaininopyridine ("DMAP", O.OOlg) . After a further 10 hours the solvent was evaporated to give the title product as a yellow oil. Preparation III The method for preparation of I was followed except that in place of the 4.5g of Helαxy 5048 there was used 3.0g. The resultant compound, named Preparation III, was less storage stable than Preparation I and gelled after a few days. Preparation IV To a 2 day old sample of Preparation III (4.lg) was added diketene (0.84g) and a catalytic amount of DMAP. The product, namely Preparation TV, was found to be storage stable. Preparation V -(CH 2 ) 4 -OCH 2 -CH-CH 2 - fCH ) 3 -51 [OCH 3 ) 3 V ) To butanedioldiglycidylether (20g, 0.1M) was added APTMS (11.Og, 0.05M) to give the title product having an initial epoxide to active NH ratio of 2:1. After 2 days at room temperature the product was found relatively unchanged. After 6 days the product had gelled. Preparation VI Preparation V was treated with diketene in an analogous manner to that described in Preparation II above. The resultant product, namely Preparation VI, was found to be storage stable. Preparation VII To APTMS (35.8g, 0.2M) was added vinylcycldhexenedioxide (28g, 0.2M) . The mixture was warmed to 50°C for 18 hours after which all the primary amine had reacted. The product gelled after 2 months. Preparation VIII - Comparative Example Butanedioldiglycidylether (20g, 0.1M) and arninσpropyl- triethoxysilane (ll.Og, 0.05M) were added individually (i.e. without reacting them together) to the carboxy functional polymer described below under Test Results. Stage (b) - Preparation of Polymer A carboxy functional polymer was prepared exactly as described in Example 1, stage (b) , except that in place of p-CEA there ws used AA (136.6g) and the amount of BA was increased to 1753g. The resultant polymer had the composition BA (47.3%) , MMA (49%) and AA (3.7%) and a solids content of 45%. Stage (c) - Test Results of Preparations I to VTII The carboxy functional polymer described in stage (b) above was added to the weight of the product I-VTII shown in Table I below. The resultant compositions were cast as films onto glass plates using a lOOμm Sheen Bar and evaluated according to the cure schedules shown by rubbing the films with cotton wool soaked in MEK. Table 1 Note: (a) = Butanediolglycidyl ether (b) = Aririnσpropyltriethαxysilane In VIII unreacted ingredients (a) and (b) were added to the polymer. Example 10 Preparation of further epoxy cαπpounds by Michael Addition Reactions Preparation IX *- OC .CH 2 ) 2 N- CH 2 CH 2 CH 2 S i [OCH 3 ) 3 ( I X) APTMS (17.9g) was added dropwise, with stirring over 15 minutes, to ice- cooled glycidylacrylate (12.9g) . After 2 hours, NMR indicated that the title preparation IX had been formed. Preparation IX was found to be stable for a few hours. Preparation X 0 Λ 9, / (CH 2 ) 3 -Si (OCH 3 ) 3 LJ 0- C [ CH,) 2 N< CONH - D u t y I (X) Butylisocyanate (9.9g) was added to a cold fresh solution of Preparation IX. After 2 hours title Preparation X had been formed and was found to be storage stable. Preparation XI ) 3 - S i (OCH 3 ) 3 (XI ) Preparation IX (30.8g) was treated dropwise with diketene (8.4g) to give the title Preparation XI. Preparation XII 0-CH 2 -C-CH 2 -0-π ι -CH =CH 2 H 0 ( IX) To a fresh sample of Preparation IX was added 1 equivalent of TMPTA (Trimethylolpropanetriacrylate) (a three fold excess of acrylic groups to -NH- group) to give the title product as a storage stable liquid. Preparation XIII (XI I I ) APTMS (8.84g, 0.045M) was added a solution of glycidyl acrylate (13g, 0.1M) in dry CH__1 2 (15ml) . The temperature rose to 33°C and the mixture was stood for 3 days, after which unsaturation had reduced to a steady value equivalent to 80% conversion of starting materials to title preparation. A further portion of APTMS (2g) was added. After 1 month the product had gelled. Preparation XIIIA . Preparation XIII was reacted with butylisocyanate to give Preparation XIIIA. Preparation XIIIB Preparation XIII was reacted with diketene to give Preparation XIIIB. Preparation XIV Isophorene diisocyanate (11.Og) was added dropwise with stirring to a solution of Preparation IX (30.8g) in dry CH_C1 2 (50ml) at 0-5°C. After standing for 16 hours the α_Cl 2 was removed in vacuo to give preparation XIV as a clear viscous oil. Preparation XV E E E-N-CH 2 CH_-N-(CH 2 ) 3 -Si(OCH 3 ) 3 (XV) wherein one E is H and the other two groups represented by E are epoxy groups of the formula: H 2 NCH 2 CH 2 NH(C_H_) 3 -Si(OC3_) 3 (22.2g) in dry CH_C1 2 (50ml) was added over hour, with stirring, to a solution of glycidyl acrylate (25.6g) in dry α_Cl 2 (50ml) at 0°C. After 5% hours NMR indicated the formation of Preparation XV having very low residual unsaturation. Preparation XVA Preparation XV (23.9g) was reacted with butylisocyanate (5g) to give preparation XVA, having the formula XV shown above but with a -CO-NH-Butyl group in place of the hydrogen atom represented by E. Preparation XVB Preparation XV (23.9g) was reacted with diketene (4.3g) to give preparation XVB, having the formula XV shown above but with a -αX3_C0CH_ group in place of the hydrogen atom represented by E. Preparation XVI (XV I 2,3-Epoxycycldhexylmethylacrylate (125g, "Cyclomer A200", available from Diacel) was added over 30 minutes to APTMS (123g) . After 1 day stirring the title preparation XVI was isolated and found to be storage stable. Preparation XVII Preparation XVI was reacted with one equivalent of diketene at 20-25°C to give preparation XVII. Preparation XVIIA Preparation XVI was reacted with one equivalent of butylisocyanate to 20-25°C to give preparation XVIIA. Preparation XVIII APTMS (17.9g, 0.1M) was added to a solution of Cyclomer A200 (36.4g, 0.2M) in C__C1_ (50ml) and methanol (10ml) . After 3 days NMR indicated that the reaction was complete giving preparation XVIII as a storage stable material. Preparation XIX R R R-NCH 2 CH_N(CH 2 ) 3 Si(OCH 3 ) 3 (XIX) wherein one R is H and two groups represented by R are as defined in Example 2. Cyclomer A200 (0.1M) was added dropwise with stirring to H 2 NCti 2 CH 2 NH(CH 2 ) 3 Si(oσϊ.) 3 (0.2) . After standing at room temperature for VA- days NMR indicated that the title preparation XIX had been formed. Preparation XIX was found to be storage stable. Preparation XX Preparation XX was made according to the method described in Example 6, stage a) . Preparation XXI The method described above for Preparation XV was followed except that in place of glycidyl acrylate there was used 2,3-epαxycyclchexylmethylacrylate. The product, namely Preparation XXI, was obtained as a storage-stable pale yellow liquid. Test Results of Preparations IX to XXI The carboxy functional polymer described in Example 9, stage (b) was treated individually with Preparations IX to XXI before casting onto glass plates using a lOOμm Sheen Bar and evaluating MEK rub resistance. The results are shown in Table 2: Table 2 Example 11 Preparation XXII The method described in Example 10, Preparation XV, was followed except that in place of H 2 _ .CH 2 NH(ai 2 ) 3 -Si (00^) 3 there was used H_NCH_α_NH(CH,) 3 -siα . (OCH 3 ) 2 , to give Preparation XXII. Preparation XXIII Methyl polyethylene glycol methacrylate (0.04M, 25.4g, available from B.P. Chemicals as MPEG 550 MA) was added to H 2 NCH 2 CH 2 _H(C__) 3 Si(OC_I 3 ) 3 (0.2M, 44.4g) and the mixture stood for 2 days at 52°C. Glycidyl acrylate (0.34M, 43.5g) was added at room temperature over 30 minutes. The temperature rose to 30°C and the mixtuire was maintained at 30°C for 6 hours, cooled to 10°C and treated with butyl isocyanate (2.0M, 19.8g) . The resultant product was found to be dispersible in water. Example 12 Preparation and Comparison of Carboxy Polymers with Polymers having Carboxy and Hydrαxy Functionality Step a) - A polymer having carboxy and hydroxy functionality was prepared as follows (hereinafter the "OH+COOH polymer") . A 1 litre round bottom flask was fitted with a stirrer, dropping funnel and thermometer was purged with nitrogen gas. A solution of Alkyposal 9278R surfactant (7.4g) in water (280ml) was added to the flask. An emulsion comprising water (112g) , MAA (I4.6g) , HEA (19.6g), MMA (138g) , BA (155g) , Alkyposal 9278R (22g) and airmσniurπpersiilphate (l.64g) was charged into the dropping funnel. Approximately 10% of the dropping funnel contents was added to the flask and the flask was then heated to 85°C. The remaining contents of the dropping funnel were added dropwise over 1.5 hours and the flask was heated at 85°C for a further 1 hour. The flask contents were filtered and the filtrate cooled to give the OH+COOH polymer as a low viscosity white emulsion having a solids content of about 44%. Step b) - Preparation of a polymer having carboxy groups and no hydroxy groups (hereinafter the "carboxy polymer") . A carboxy polymer was prepared exactly as described in Example 1, stage (b) , except that in place of β-CEA there was used MAA (165g) , the amount of BA was increased to 1812g and the amount of MMA was decreased to 1726g. The resultant polymer contained MAA (4.45%) , MMA (46.6%) and BA (48.9%). Step c) - Evaluation The polymers described in steps a) and b) were adjusted to pH 6.8 and treated with the cross-linker preparations mentioned in the first column of Table 3. The second column states the amount of preparation used (weight % relative to the polymer) . Table 3 Table 3 shows that compositions comprising the crosslinker preparations and a polymer having both carboxy and hydroxy functionality have higher MEK rub resistance than compositions where the polymer has only carboxy groups.

Claims: CLAIMS 1. A composition comprising water and the following components: (a) an epoxy compound comprising at least one epoxy group and at least one nitrogen atom,- and (b) a carboxy functional polymer, a hydroxy functional polymer, a polymer having carboxy and hydroxy functionality, or a mixture comprising two or more of said polymers; provided that when the epαxy compound has only one epαxy group it has at least one hydrolysable silyl group. 2. A composition according to Claim 1 wherein component (a) has one epαxy group, at least one nitrogen atom and at least one hydrolysable silyl group. 3. A composition according to Claim 1 wherein component (a) has more than one epoxy group, at least one nitrogen atom and no hydrolysable silyl groups. 4. A composition according to Claim l wherein component (a) has more than one epαxy group, at least one nitrogen atom and one or more hydrolysable silyl groups. 5. A composition according to any one of the preceding claims wherein the epαxy compound comprises at least one aliphatic epαxy group and at least one nitrogen atom. 6. A composition according to any one of the preceding claims wherein the epαxy compound comprises at least one epoxy group having an ester group on an adjacent carbon atom and at least one nitrogen atom. 7. A composition according to any one of the preceding claims wherein said nitrogen atom in component (a) is a basic nitrogen atom. 8. A composition according to any one of the preceding claims wherein components (a) and (b) are dispersed in the water. 9. A composition according to any one of the preceding claims wherein component (b) is a polymer having carboxy and hydroxy functionality. 10. A composition according to any one of Claims 1 to 8 wherein component (b) is a carboxy functional polymer. 11. A composition according to any one of the preceding claims wherein the weight ratio of component (a) to (b) lies in the range of 0.1:100 to 35:100. 12. A composition according to Claims 1, 5, 6, 7, 8, 9 , 10 or 11 wherein component (a) is of the Formula (1) : wherein: X is E-(L 4 -0) m -(CO) n -(T) p -; Y is -Si(R 1 ) 3 or a group defined for X above,- T is 0, CH_ or NR 2 ; P is 0 or 1; q is 0, 1, 2, 3 or 4; E comprises an epαxy group; each L 1 , L 2 , L 3 and L 4 independently is a divalent organic linker group; m and n are each independently 0 or 1; each R 1 independently is cptionally substituted alkyl or optionally substituted alkoxy; and each R 2 independently is H or optionally substituted alkyl or acyl; provided that when Y is -Si(R 1 ) 3 at least one R 1 is optionally substituted alkoxy. 13. A composition according to any one of Claims 1, 5, 6, 7, 8, 9, 10 or 11 wherein component (a) is of the Formula (2) : wherein: L 1 , L 2 , X, Y and R 2 are as defined in claim 12; L 5 , L 6 and L 7 are each independently organic linker groups; a is 2 to 6; b is 6- (a+c) ; c is 0 to 4; and (a+b+c) = 6. 14. A compound of Formula (1) wherein : X is E-(L 4 -0) m -(CO) n -(T) p -; Y is -Si(R 1 ) 3 or a group defined for X above,- T is 0, CH. or NR 2 ; p is 0 or 1; q is 0, 1, 2, 3 or 4; E comprises an epoxy group,- each L 1 , L 2 , L 3 and L 4 independently is a divalent organic linker group,- m is 0 or 1; n is 1; each R 1 independently is optionally substituted alkyl or optionally substituted alkoxy,- and each R 2 independently is H or optionally substituted alkyl or acyl; provided that when Y is -Si(R 1 ) 3 at least one R 1 is optionally substituted alkαxy. 15. A compound according to Claim 14 wherein L 1 , L 2 , L 3 and L 4 are each independently -CH_-, -(03_) 2 - or -(σ_) 3 -,- each R 1 independently is C^-alkαxy or C_. 4 -alkyl, provided at least one R 1 is C 1-4 -alkαxy,- and one R 2 is H or acyl and any other R 2 is of formula -L 1 -C0-O-L 4 -E wherein L 1 , L 4 and E are as hereinbefore defined. 16. A compound according to claim 15 wherein the acyl group is -CONH(C_. 20 -alkyl) . 17. A compound according to any one of claims 14 to 16 of the formula : E E-N-α_CH . -N-Si(R 1 ) ; wherein each R 1 independently is C^ -alkyl or C_. 4 -alkαxy, ' provided at least one R 1 is C__ 4 -alkoxy,- and one E is H or -<__NH(C__ 20 -alkyl) and the other two groups represented by E are of the formula : -CH 2 C 18. A compound of Formula (1) , as shown in claim 14, wherein m=n=q=l,- p=o, L 1 , L 2 , L 3 and L 4 are optionally substituted alkylene groups containing from 1 to 6 carbon atoms,- Y is -Si(R 1 ) 3 wherein each R 1 independently is optionally substituted alkyl or optionally substituted alkαxy provided at least one R 1 is optionally substituted alkoxy,- E is of formula (ii) , (iii) or (iv) and one group represented by R 2 is of formula -L 1 -X wherein L 1 and X are ashereinbef ore defined and the other group represented by R 2 is H, optionally substituted alkyl or acyl. 19. A compound according to Claim 14 of the formula wherein E is of the formula (ii) , (iii) or (iv) L 1 , L 2 , L 3 and L 4 are each independently -CE_-, -(CH_) 2 - or -(α_) 3 -,- each R 1 independently is C_. 4 -alkαxy or C__ 4 -alkyl provided at least one R 1 is C 1-4 -alkoxy,- and one R 2 is of formula -L 1 -C0-0-L 4 -E and the other R 2 is H or acyl; wherein L 1 , L 4 and E are as hereinbefore defined. 20. A compound of Formula (2) , as defined in Claim 13. 21. A film obtained or obtainable by evaporation of water from a composition according to any one of Claims 1 to 13. 22. Use of a composition according to any one of Claims 1 to 13 as a binder for a printing ink. 23. A process for forming a film or coating an a substrate comprising applying thereto a composition according to any one of Claims 1 to 13 and allowing water to evaporate from the composition. 24. A process according to Claim 23 wherein the water is allowed to evaporate from the composition at a temperature of 10°C-30°C. 25. A process according to Claim 23 wherein the water is allowed to evaporate from the composition at a temperature above 30°C and below 250°C.

Inventors: CAREY JOHN GERARD, PADGET JOHN CHRISTOPHER, PEARS DAVID ALAN, CAREY, JOHN, GERARD, PADGET, JOHN, CHRISTOPHER, PEARS, DAVID, ALAN
Applicants: CAREY JOHN GERARD, PADGET JOHN CHRISTOPHER, PEARS DAVID ALAN, ZENECA LTD, CAREY, JOHN, GERARD, PADGET, JOHN, CHRISTOPHER, PEARS, DAVID, ALAN, ZENECA LIMITED
Application year: 1995
Main classification: C09D133
IPC codes: C07D303, C08G59, C08K5, C09D133, C09D163