4-ARYL- AND 4-HETEROARYL -5-OXOPYRAZOLINE DERIVATIVES HAVING PESTICIDAL PROPERTIES

Abstract: The present invention relates to novel, pesticidally effective, 4-aryl- and 4-heteroaryl-5-oxo-pyrazoline derivatives of formula (I), in which R1, R2, R3 and G are as defined in claim 1, to compositions comprising these compounds, to their use as insecticides, acaricides or herbicides, especially in crops of useful plants, and to selective-herbicidal compositions comprising compounds of formula (I) and, as safeners, herbicide-antagonistically effective quantities of either a quinoline derivative of formula (X), in which R15 and X2 are as defined in the description, or a 1-phenylazole-3-carboxylic acid derivative of formula (XI), in which E, R16, R17, R18 and R19 are as defined in the description.

Description: 4-Aryl- and 4-heteroaryl -5-oxopyrazol 1ne derivatives having pestlcldal properties The present invention relates to novel, pesticidally active 4-aryl- and 4-heteroaryl-5-oxo-pyrazoline derivatives, to a process for their preparation, to compositions which comprise these compounds as active substances, and to their use as pesticides, especially as insecticides, acaricides or herbicides. 4-Aryl-5-oxo-pyrazolines and 4-aryl- and 4-heteroarylpyrazolidine-3,5-diones having insecticidal, acaricidal and herbicidal action arc already known and are described, for example, in EP-A-0508 126 and WO-92 16510. Novel 4-aryl- and 4-heteroaryl-5-oxo-pyrazoline derivatives having pesticidal properties have now been found which are distinguished by good activity. The compounds according to the invention arc of the formula in which Ri is the group the substituents R 4 independently of one another are halogen, nitro, cyano, Cι-C 4 alkyl, Cι-C 4 haloalkyI, Cj-C 10 alkoxy, C r C 4 haloalkoxy, C3-C 6 alkenyloxy, C r C 4 alkoxy-C 2 -C 4 alkoxy, C 3 -C 6 alkynyloxy, C r C 4 alkylcarbonyl, ^alkoxycarbonyl, C C alkylthio, C 1 -C 4 alkylsulfinyl, C 1 -C 4 alkylsulfonyl, amino, Cι-C 4 aIkyl__mino or di(Cj -C 4 alkyl)amino; R 5 is the group n is O, 1, 2, 3 or 4; m is 0 or 1, and the sum of m and n is 0, 1, 2, 3 or 4; q is O, 1, 2 or 3; Xj is oxygen, sulfur, -CH 2 - or -N(R 7 )-; the substituents R 6 independently of one another are halogen, C 1 -C 4 haloalkyl, C]-C 4 alkoxy, Cj-C 4 haloalkoxy, nitro, cyano, C j ^alkoxycarbonyl, amino, C 1 -C alkylamino or di(C 1 -C alkyl)amino; R 7 is hydrogen, Cι-C 4 alkyl, formyl or Cι-C alkylcaτbonyl; R 2 and R 3 independently of one another are hydrogen, C C 8 alkyl, C 3 -C 8 alkenyl, C 3 -C 8 alkynyl, C r C g alkoxyalkyl, C r C 8 alkylthioalkyl, C 3 -C 8 cycloalkyl or substituted or unsubstituted aryl; or R 2 and R 3 together form the bivalent radical of a saturated or unsaturated, unsubstituted or substituted, mono-, bi-, tri- or polycyclic system, which system can optionally contain, in positions not adjacent to the nitrogen atoms shown in formula I, one or more ring hetero atoms; G is the group -CO-A (a) or -SO 2 -B (b); A is C r C 8 alkyl substituted by nitro, cyano, Si(Cι-C 4 alkyl) 3 , amino, Cj-C alkylamino, di(C 1 -C 4 alkyl)amino, substituted or unsubstituted benzyloxy or a group ~ CH_ N Ros^ , COORo j o or A is C 3 -C 8 cycloalkyl which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is substituted by Cι-C 4 alkyl, C C 4 alkoxy, Cι-C alkylthio, C 1 -C alkylsulfinyl, ^alkylsulfonyl or substituted or unsubstituted phenyl, or A is C 3 -C 8 cycloalkyloxy which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is substituted by Cj-C 4 alkyl, or A is adamantyl, naphthyl, naphthyl substituted by halogen, C 1 -C alkyl, C r C haloalkyl or Cι-C 4 alkoxy, or A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -R 10 , -(CRgR^ p -Rn or -N(R 10 )R 13 ; Ros, Rrø and R Q IQ independendy of one another are hydrogen or Cι-C 6 alkyl; R 8 and R 9 independently of one another arc hydrogen, C C 6 alkyl or phenyl; R 10 is hydrogen, C 1 -Cι 0 alkyl, Cj-Cjoalkyl substituted by halogen, C r C 4 alkoxy, C r C alkylthio, C 3 -C 1 2cycloalkyl, cyano, aryl or aryloxy, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl substituted by halogen or C 1 -C alkyl, C 3 -Cιoalkenyl, C 3 -Cιoalkynyl, C 3 -C 10 haloalkenyl, C 3 -Cιohaloalkynyl, aiyl, aryl substituted by halogen, C 1 -C alkyl, C r C 4 haloalkyl, C r C 6 alkoxy, nitro, cyano, phenoxy or halo-substituted phenoxy; o and r independently of one another arc 0 or 1; Y and Z independently of one another are oxygen or NR 12 ; p is 1 to 10; RJI is C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl substituted by halogen or ^alkyl, aryloxy, aryloxy substituted by halogen, Cι-C 4 alkyl, C C 4 haloalkyl, Cι-C 4 alkoxy, C 1 -C 4 haloalkoxy, C r C 4 alkylthio, nitro, cyano, phenoxy or halo-substituted phenoxy, benzyloxy, benzyloxy substituted by halogen, Cι-C alkoxy, Cι-C 4 haloalkoxy, Cι-C 4 alkylthio, nitro, cyano, phenoxy or halo-substituted phenoxy, norbornyl or adamantyl, where aryloxy with the exception of phenoxy can in each case be any desired aryloxy group; R 12 is hydrogen, C r C 4 alkyl, C 3 -C 8 cycloalkyl, C 3 -C 10 alkenyl or C 3 -C 10 alkynyl; R j3 is C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl substituted by halogen or -Qalkyl, or cyano-C r C 6 alkyl; B is C r C 10 alkyl substituted by C r C alkoxy, C,-C 6 alkoxy-C r C 4 alkoxy, C r C 4 haloalkoxy, C r C alkylthio, C r C 4 haloalkylthio, C,-C alkylsulfinyl, C r C 4 alkylsulfonyl, C 1 -C 4 alkylsulfonyloxy, C r C alkylcarbonyl, C C 4 alkoxycarbonyl, C r C 4 alkylcarbonyloxy, di(Cι-C 4 alkyl)amino, C 3 -C 8 cycloalkyl, aryl, aryloxy, arylthio, arylsulfonyl, arylsulfinyl, arylsulfonyloxy, arylcarbonyl or pyridyl, it being possible for the aryl and pyridyl groups if desired to be substituted by halogen, Cj-C alkyl, C r C 4 haloalkyl, C r C alkoxy, C j ^haloalkoxy, Cι-C 4 alkylthio, nitro, cyano, phenoxy, halo-substituted phenoxy, phenylthio or halo-substituted phenylthio, or B is C 3 -C 10 alkenyl, C 3 -C 10 haloalkenyl, C 3 -Cιoalkynyl, C 3 -C 10 haloalkynyl, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl substituted by halogen or Cι-C 4 alkyl, benzyl, benzyl substituted by halogen, or C C alkoxy, naphthyl, naphthyl substituted by halogen or nitro, or B is a group -N(R 21 )R 22; R 2 ι is C 1 -C 4 haloalkoxy, C r C alkylthio, C r C 4 haloalkylthio, Cι-C alkylsulfinyl, C r C 4 alkylsulfonyl, C 1 -C 4 alkylsulfonyloxy, Cι-C 4 alkylcarbonyl, C 1 -C 4 alkoxycarbonyl, Cj-C 4 alkylcarbonyloxy, di(Cι-C 4 alkyl)amino, C 3 -C 8 cycloalkyl, aryl, aryloxy, arylthio, arylsulfonyl, arylsulfinyl, arylsulfonyloxy, arylcarbonyl or pyridyl, it being possible for the aryl and pyridyl groups if desired to be substituted by halogen, Ci-C-jalkyl, Cj-C 4 haloalkyl, ^alkoxy, ^haloalkoxy, Cι-C alkylthio, nitro, cyano, phenoxy, halo-substituted phenoxy, phenylthio or halo-substituted phenylthio, or R 2 ι is C 3 -C 0 alkenyl, C 3 -C ohaloalkenyl, C 3 -C 2 oalkynyl, C 3 -C 2 ohaloalkynyl, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl substituted by halogen or C 1 -C alkyl, benzyl or aryl, it being possible for the benzyl and aryl groups if desired to be substituted by halogen, Ci^al yl, C r C 4 haloalkyl, C j -C 4 alkoxy, ^haloalkoxy, Cι-C 4 alkylthio, nitro, cyano, benzoyi, halo-substituted benzoyi, phenoxy or halo-substituted phenoxy; R 22 is as defined for R 2 ι or else alternatively is C Cjoalkyl; or R ι and R^, together with the nitrogen atom to which they arc attached, form an unsubstituted or mono- to trisubstituted, nonaromatic, mono- or bicyclic heterocyclic ring in which the substituents can be Cj-C 4 alkyl, C j ^alkyl substituted by halogen, Cι-C 4 alkoxy, phenyl, benzodioxoyl or trifluoromethylphenyl, C 1 -C 4 -dkoxy, C 1 -C 4 _dkoxycarbonyl, C r C 4 alkylcarbonyl, phenyl, phenyl substituted by halogen, -C 4 alkoxy, nitro or trifluoromethyl, pyridyl, pyrimidinyl or formyl, and salts and diastereomers of the compounds of the formula I, with the proviso that, if R 21 and R 22 are alkyl, at least one of these radicals is a substituted alkyl. In the above definitions, halogen (halo) refers to iodine and preferably to fluorine, chlorine and bromine. Unless specifically mentioned, the alkyl, alkenyl and alkynyl groups preferably have 1 or, respectively, 2 to 8 carbon atoms and can be straight-chain or branched, specifications which also apply to the alkyl, alkenyl and alkynyl moieties of alkylsilanes, haloalkyl, alkoxy, haloalkoxy, alkoxyalkyl, alkoxyalkoxy, alkenyloxy, alkynyloxy, alkylcarbonyl, alkoxycarbonyl, alkylthio, alkenylthio, alkynylthio, alkylthioalkyl, alkylsulfinyl, alkylsulfonyl, alkylamino and dialkylamino groups. Examples of the alkyl groups occurring in the definitions of the substituents are methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl and tert-butyl, and die isomeric pentyls, hexyls, heptyls and octyls. The alkyl groups occurring as or in the substituents preferably have 1-8 carbon atoms. Alkenyl refers for example to allyl, methallyl, 1-methylvinyl or but-2-en-l-yl. Preferred alkenyl radicals are those having a chain length of 2 to 8 carbon atoms. The alkenyl radicals are preferably attached to a heteroatom via a saturated carbon atom. Examples of alkynyl are propargyl, but-2-yn-l-yl, 2-methylbutyn-2-yl, but-3-yn-2-yl and pent-4-yn-l-yl. Preferred alkynyl radicals are those having a chain length of 2 to 8 carbon atoms. The alkynyl radicals are preferably attached to a heteroatom via a saturated carbon atom. Haloalkyl radicals preferably have a chain length of 1 to 8 carbon atoms. Haloalkyl is for example fluoromethyl, difluoromethyl, trifluoromethyl, chloromethyl, dichloromethyl, trichloromethyl, 2,2,2-trifluoroethyl, 2-fluoroethyl, 2-chloroethyl, pentafluoroethyl, l,l-difluoro-2,2,2-trichloroethyl, 2,2,3,3-tetrafluoroethyl and 2,2,2-trichloroethyl; preference is given to trichloromethyl, difluorochloromethyl, difluoromethyl, trifluoromethyl and dichlorofluoromethyl. Suitable haloalkenyl groups are alkenyl groups substituted one or more times by halogen, in whic context halogen is bromine, iodine and, in particular, fluorine and chlorine, examples being 2,2-difluoro-l -methyl vinyl, 3-fluoropropenyl, 3-chloropropenyl, 3-bromopropenyl, 2,3,3-trifluoropropenyl, 2,3,3-trichloropropenyl and 4,4,4-trifluorobut-2-en-l-yl. Among Cs-C^oalkenyl radicals substituted 1, 2 or 3 times by halogen, preference is given to those having a chain length of 3 to 5 carbon atoms. Suitable haloalkynyl groups are, for example, alkynyl groups which are mono- or polysubstituted by halogen, where halogen is bromine, iodine and, in particular, fluorine and chlorine, examples being 3-fluoropropynyl, 3-chloropropynyl, 3-bromopropynyl, 3,3,3-trifluoropropynyl and 4,4,4-trifluorobut-2-yn-l-yl. Among the alkynyl radicals substituted one or more times by halogen, preference is given to those having a chain length of 3 to 5 carbon atoms. Alkoxy radicals preferably have a chain length of 1 to 6 carbon atoms. Alkoxy is for example methoxy, ethoxy, propoxy, i-propoxy, n-butoxy, isobutoxy, sec-butoxy and tert-butoxy and the isomers of pentyloxy and hexyloxy; methoxy and ethoxy arc preferred. Alkylcarbonyl is especially acetyl and propionyl. Alkoxycarbonyl is methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, isopropoxycarbonyl, n-butoxycarbonyl, isobutoxycarbonyl, sec-butoxycarbonyl and tert-butoxycarbonyl; methoxycarbonyl and ethoxycarbonyl are preferred. Haloalkoxy radicals preferably have a chain length of 1 to 8 carbon atoms. Haloalkoxy is for example fluoromethoxy, difluoromethoxy, trifluoromethoxy, 2,2,2-trifluoroethoxy, 1,1,2,2-tetrafluoroethoxy, 2-fluoroethoxy, 2-chloroethoxy, 2,2-difluoroethoxy and 2,2,2-trichloroethoxy; difluoromethoxy, 2-chloroethoxy and trifluoromethoxy are preferred. Alkylthio radicals preferably have a chain length of 1 to 8 carbon atoms. Alkyl thio is for example methylthio, ethylthio, propylthio, isopropylthio, n-butylthio, isobutylthio, sec-butylthio or tert-butylthio; methylthio and ethylthio are preferred. Alkylsulfinyl is methylsulfϊnyl, ethylsulfinyl, propylsulfinyl, isopropylsulfinyl, n-butylsulfinyl, isobutylsulfinyl, sec-butylsulfinyl, tert-butylsulfinyl; methylsulfinyl and ethylsulfinyl arc preferred. Alkylsulfonyl is methylsulfonyl, ethylsulfonyl, propylsulfonyl, isopropylsulfonyl, n-butylsulfonyl, isobutylsulfonyl, sec-butylsulfonyl, tert-butylsulfonyl; methylsulfonyl and ethylsulfonyl are preferred. Alkoxyalkoxy radicals preferably have a chain length of 1 to 8 carbon atoms. Examples of alkoxyalkoxy are methoxymethoxy, methoxyethoxy, methoxypropoxy, ethoxymethoxy, ethoxyethoxy, propoxymethoxy and butoxybutoxy. Alkylamino is for example methylamino, ethylamino, n-propylamino, isopropylamino and die isomeric butylamines. Dialkylamino is for example dimethylamino, methylethylamino, diethylamino, n-propylmethylamino, dibutylamino and diisopropylamino. Preference is given to alkylamino radicals having a chain length of 1 to 4 carbon atoms. Alkoxyalkyl radicals preferably have 1 to 8 carbon atoms. Alkoxyalkyl is for example methoxymethyl, methoxyethyl, ethoxymethyl, ethoxyethyl, n-propoxymethyl, n-propoxyethyl, isopropoxymethyl and isopropoxyethyl. Alkylthioalkyl radicals preferably have 1 to 8 carbon atoms. Alkylthioalkyl is for example methylthiomethyl, methylthioethyl, ethylthiomethyl, ethylthioethyl, n-propylthiomethyl, n-propylthioethyl, isopropylthiomethyl, isopropylthioethyl, butylthiomethyl, butylthioethyl or butylthiobutyl. The cycloalkyl radicals preferably have 3 to 8 ring carbon atoms, for example cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl and cyclooctyl. These cycloalkyl radicals can if desired be interrupted by heteroatoms such as, for example, oxygen atoms and/or sulfur atoms and/or nitrogen atoms. Similar comments apply to the cycloalkyloxy radicals. Phenyl, on its own or as part of a substituent such as phenoxy, benzyl, benzyloxy, benzoyi, phenylthio, phenylalkyl or phenoxyalkyl, can in general be unsubstituted or substituted. In the latter case the substituents can be in an ortho, meta and/or para position. Preferred substituent positions are the ortho and para positions relative to the ring linking site. Preferred substituents are halogen, nitro, cyano, Cι-C 4 alkoxy, C Q-jhaloalkoxy, C r C 4 alkylthio, C r C 4 haloalkylthio, C r C 4 alkyl and C r C haloalkyl. Aryl in the definition of die radicals R 2 , R 3 and R 10 is α- or β-naphthyl, especially phenyl, which aromatic ring systems can carry one or more identical or different substituents, examples being halogen, nitro, cyano, C 1 -C 4 alkoxy, C r C 4 haloalkylthio, C r C 4 alkyl and Cj-C 4 haloalkyl. Corresponding comments apply to aryloxy, arylthio, arylsulfonyl, arylsulfinyl, arylsulfonyloxy and arylcarbonyl in the definition of the radicals R 1( )_ Rn, R 2 ι_ R 22 wd B. Examples of the unsubstituted or mono- to trisubstituted, nonaromatic, mono- or bicyclic heterocyclic rings which the substituents R 2 ι and R 2 2, together with the nitrogen atom to which they are attached, are able to form are, for example, 1-pyrrolidinyl, 1-piperidyl, 2,6-dimeuτyl-l-piperidyl, 4-morpholinyl, 4-methylpiperazin-l-yl, 4-phenylpiperazin-l-yl, 4-benzylpiperazin- 1 -yl, 4-(3,4-dichlorophenyl)piperazin- 1 -yl, 4-thiomorpholinyl, 2,6-dimedιyl-4-morpholinyl, 2,6-dimethylthio-4-moιpholinyl, 1 ,2,3,4-tetrahydro- quinolin-1-yl orindolin-1-yl. Examples of saturated or unsaturated and unsubstituted or substituted mono-, bi-, tri- or polycyclic systems which the substituents R 2 and R 3 , togedier with the two nitrogen atoms of the pyrazoline ring to which they are attached, are able to form are: These ring systems can be substituted by halogen, C C^alkyl, C r C 16 haloalkyl, C 2 -Cι 6 alkenyl, C r C 16 alkoxy-C 2 -C 6 alkyl, C r C 6 polyalkoxy-C 2 -C 6 alkyl or by phenyl or benzyl each of which is unsubstituted or substituted by halogen, nitro, Cι-C 4 alkyl, ^alkoxy or C Cshaloalkyl; and R 14 is halogen or unsubstituted or halo-substituted C or C^alkoxy. Corresponding meanings can also be assigned to the substituents in composite definitions, for example haloalkoxy, haloalkylthio, alkoxyalkoxy, alkoxycarbonyl, alkylcarbonyl, alkylsulfinyl, alkylsulfonyl, alkenyloxy, alkynyloxy, alkenylthio, alkynylthio and cycloalkylthio. The invention likewise comprises the salts which the compounds of the formula I can form with acids. Suitable acids for the formation of die acid addition salts are both organic and inorganic acids. Examples of such acids are inter alia hydrochloric acid, hydrobromic acid, nitric acid, various phosphorus acids, sulfuric acid, acetic acid, propionic acid, butyric acid, valeric acid, oxalic acid, malonic acid, fumaric acid, organic sulfonic acids, lactic acid, tartaric acid, citric acid and salicylic acid. The salts of the compounds of die formula I containing acidic hydrogen, as for example in the definition of the substituent A as Cj-C 8 alkyl substituted by a group -CH-NROSRC , in COORQJO which R Q10 is hydrogen, can also be alkali metal salts, for example sodium salts and potassium salts; alkaline earth metal salts, for example calcium salts and magnesium salts; ammonium salts, i.e. unsubstituted ammonium salts and mono- or polysubstituted ammonium salts, and salts with other organic nitrogen bases. Correspondingly, suitable salt formers are alkali metal hydroxides and alkaline earth metal hydroxides, especially the hydroxides of litfiium, sodium, potassium, magnesium or calcium, with particular importance being attached to those of sodium or potassium. Examples of amines suitable for forming ammonium salts include not only ammonia but also primary, secondary and tertiary Cι-Cι 8 alkylamines, Cι-C 4 hydroxyalkylamines and C 2 -C 4 alkoxyalkylamines, for example methylamine, ethylamine, n-propylamine, isopropylamine, the four isomeric butylamines, n-amylamine, isoamylamine, hexylamine, heptylamine, octylamine, nonylamine, decylamine, pentadecylamine, hexadecylamine, heptadecylamine, octadecylamine, methylethylamine, methylisopropylamine, methylhexylamine, methylnonylamine, methylpentadecylamine, methyloctadecylamine, ethylbutylamine, ethylheptylamine, ethyloctylamine, hexylheptylamine, hexyloctylamine, dimethylamine, diethylamine, di-n-propylamine, diisopropylamine, di-n-butylamine, di-n-amylamine, diisoamylamine, dihexylamine, diheptylamine, dioctylamine, ethanolamine, n-propanolamine, isopropanolamine, N,N-diethanolamine, N-ethylpropanolamine, N-butylethanolamine, allylamine, n-butenyl-2-amine, n-pentenyl-2-amine, 2,3-dimethylbutenyl-2-amine, dibutenyl-2-amine, n-hexenyl-2-amine, propylenediamine, trimethylamine, triethylamine, tri-n-propylamine, tri-isopropylamine, tri-n-butylamine, triisobutylamine, tri-sec-butylamine, tri-n-amylamine, methoxyethylamine and ethoxyethylamine; heterocyclic amines such as, for example, pyridine, quinoline, isoquinoline, morpholine, N-methylmorpholine, thiomoφholine, piperidine, pyrrolidine, indoline, quinuclidine and azepine; primary arylamines such as, for example, anilines, methoxyanilines, ethoxyanilines, o-, m- and p-toluidines, phenylenediamines, benzidines, naphthylamines and o-, m- and p-chloroanilines; but especially triethylamine, isopropylamine and diisopropylamine. In addition, it is possible if desired to form corresponding inner salts, for example in the case of the radical A as C r C 8 alkyl substituted by a group - C H- N RosRrø t j n which Rrø, COORo j o R 09 and RQIQ are hydrogen. Furthermore, it is possible for certain substituents Rj, R 4 to R 13 , and R 2 and R 3 alone or in combination with one another or in combination with die parent structure to which they are attached to exhibit chirality. The invention comprises both the racemate and the enriched and optically pure forms of the respective stereoisomers. In the processes described in this application, the asymmetrically substituted compounds of die formula I are generally - unless chiral precursors are used - obtained as racemates. The stereoisomers can then be separated on die basis of physicochemical properties by known methods, for instance fractional crystallization after die formation of salts with optically pure bases, acids or metal complexes, or else by chromatographic methods such as, for example, high-performance liquid chromatography (HPLC) on acetylcellulose. In the present invention, references to the active substances of the formula I include both the pure optical isomers and the racemates and/or diastereomers. Where no specific reference to the individual optical isomers is made, d e formula given should be taken to refer to those racemic mixtures which are produced in the preparation process indicated. Where an aliphatic C=C double bond is present, geometric isomerization can also occur. The formula I is intended to embrace all of tiiese possible isomers and mixtures thereof. With respect to the insecticidal and acaricidal actions, emphasis should be put on die following compounds of the formula I: Preferred compounds of die formula I are those in which Rj is the group ( _ • Of these compounds, particular preference is given to those in which R 4 is fluorine, chlorine or Cj-C 4 alkyl; n is 1, 2 or 3; and m is 0. Of these compounds, very particular prcference is given to those in which R 4 is fluorine, chlorine or methyl; and n is 2 or 3. Preference is likewise given to compounds in which R 2 and R 3 are C r C 6 alkyl; or R 2 and R 3 togedier form a substituted or unsubstituted alkylene chain -(CH^s-- -(CH 2 ) 4 - or -(CH 2 ) 3 -. Compounds which are likewise preferred are those in which G is the group -CO-A (a). Among tiiese compounds, particular preference is given to those in which A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -R 10 , -(CRsR^ p -Ru or -N(R, 0 )R 13 , or substituted or unsubstituted naphd yl. Among these compounds, very particular preference is given to those in which R 8 and R independently of one anod er are hydrogen or metiiyl; and p is 1 or 2. Of these compounds, very special importance attaches to those in which R 8 and R 9 are methyl. Likewise particularly preferred are compounds in which RJQ is C j -C 8 -alkyl, preferably Cj-Q-alkyl, C 3 -C 6 cycloalkyl, phenyl, phenyl substituted by halogen, or is naphthyl; R ! j is C 3 -Cgcycloalkyl, benzyloxy, benzyloxy substituted by halogen, C C 4 haloalkyl or phenoxy, or is naphthyloxy; and R 13 is C 3 -C 7 cycloalkyl or cyano-C r C 6 alkyl. Other particularly preferred compounds are those in which Y and Z are NR 12 . Among these compounds, particular preference is given to those in which Rι 2 is hydrogen or C r C 4 alkyl. Particular preference is similarly given to compounds in which R 8 and R 9 independendy of one another are hydrogen or methyl; p is 1 or 2; R l0 is C j -Qalkyl, C 3 -C 6 cycloalkyl, phenyl, phenyl substituted by halogen, or is naphthyl; R u is C 3 -C 6 cycloalkyl, benzyloxy, benzyloxy substituted by halogen, C 1 -C 4 haloalkyl or phenoxy, or is naphthyloxy; Y and Z are NR 12 ; R 1 2 is hydrogen or ^alkyl; and R 13 is C 3 -C 8 cycloalkyl orcyano-C r C 6 alkyl. Preferred compounds are those in which Rj is the group & is fluorine, chlorine or C r C alkyl; n is 1, 2 or 3; m is 0; R 2 and R 3 are C C 6 alkyl; or R 2 and R 3 togedier form a substituted or unsubstituted alkylene chain -(CH 2 ) 5 -, -(CH 2 ) 4 - or -(CH^) 3 -; G is the group -CO-A (a); A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -R 10 , -(CRgR^ p -R j , or -N(Rι 0 )R 13 , or is unsubstituted or substituted naphdiyl; R 8 and R 9 independently of one another arc hydrogen or metiiyl; p is 1 or 2; R 10 is Cι-C 4 alkyl, C 3 -C 6 cycloalkyl, phenyl, phenyl substituted by halogen, or is naphthyl; Ru is C 3 -C 8 cycloalkyl, benzyloxy, benzyloxy substituted by halogen, -Chalky!, Cι-C haloalkyl or phenoxy, or is naphthyloxy; and R 13 is C 3 -C cycloalkyl orcyano-C C 6 alkyl. With regard to die herbicidal properties, prefeπed compounds of die formula I are those following in which R 1 is the group ~~ d m is 0- Among these compounds, particular preference is given to those following in which R 4 is - or C 2 alkyl; and n is 1, 2 or 3. Among these compounds of die formula I, very particular preference is given to those in which R 4 is C j - or C^alkyl in positions 2, 4 and 6 relative to the phenyl hnkage site; and η is 3. Other preferred compounds are those in which Ri is the group ; m is 0; R 4 is Cj- or C^alkyl; n is 1, 2 or 3; R 2 and R 3 are Cι-C 6 alkyl; or R 2 and R 3 togedier form a substituted or unsubstituted alkylene chain -(CH 2 ) 5 -, -(CH^ 4 - or -(CH 2 ) 3 -. Likewise preferred are compounds in which G is a group -CO-A (a); and A is Cj-C 8 alkyl substituted by nitro, cyano, Si(C r C 4 alkyl) 3 , amino, Cj ^alkylamino, di(Cι-C 4 alkyl)amino, substituted or unsubstituted benzyloxy or a group ~ CH— NR 08Ro9 , COOR 010 or A is C 3 -C 8 cycloalkyl, which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is substituted by Cι-C 4 alkyl, C r C 4 alkoxy, Cι-C alkylthio, C ] -C 4 alkylsulfonyl or substituted or unsubstituted phenyl, or A is C 3 -C 8 cycloalkyloxy which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is unsubstituted or substituted by Ci-Qalkyl, or A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -R 10 or -(CR 8 R 9 ) p -R 1 j . Other preferred compounds are those in which Rj is the group or C 2 alkyl; n is 1, 2 or 3; m is 0; R 2 and R 3 are C r C 6 alkyl; or R 2 and R 3 togedier form a substituted or unsubstituted alkylene chain -(CH 2 )5-, -(CH^- or -(CH ) 3 -; G is the group -CO-A (a); and A is C r C 8 alkyl substituted by nitro, cyano, Si(C r C 4 alkyl) 3 , amino, C 1 -C 4 alkylamino, di(C 1 -C 4 alkyl)amino, substituted or unsubstituted benzyloxy or a group -CH- NR røRrø t or A is C 3 -C 8 cycloalkyl which can if desired contain as heteroatom COORøio oxygen, sulfur or nitrogen and is substituted by C 1 -C 4 alkyl, C C 4 alkoxy, Cj-C 4 alkyldιio, Cι-C 4 alkylsulfinyl, C j ^alkylsulfonyl or substituted or unsubstituted phenyl, or A is C 3 -C 8 cycloalkyloxy which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is unsubstituted or substituted by Cι-C 4 alkyl, or A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -R 10 or -(CRgR^-Rn. Especially preferred is the compound of the formula I, in which Rj is 2,4,6-trimethylphenyl, R 2 and R 3 together are -(CH 2 ) 4 - and G is -C(=O)-N(CH 3 )CH 2 CH 2 CN. Also especially preferred is the compound of the formula I, in which Rj is 2,4,6-trimethylphenyl, R 2 and R 3 -N together are -CH 2 CH 2 CH(CH 3 )CH 2 - N ~~ ^ C* is -C(=O)-N(CH 3 )CH 2 CH 2 CN. Also especially preferred is the compound of die formula I, in which Rj is 2,6-dichlorophenyl, R 2 and R 3 together are -(.CΗ^ 4 - and G is -C(=O)-N(CH 3 )CH 2 CH 2 CN. The process according to die invention for die preparation of compounds of the formula I is carried out in analogy to known processes and comprises a) for the preparation of the 4-aryl- and 4-heteroaryl-5-oxopyrazoline derivatives of the formula in which R-, R 2 and R 3 are as defined under formula I, G is the group -CO-A (a) and A is as defined under formula I with the exception of the group -N(Rι 0 )R 13 , reacting a compound of the formula in which R j , R 2 and R 3 are as defined, with a compound of die formula in which A is as defined and E j is a leaving group, preferably halogen and especially chlorine; b) for die preparation of the 4-aιyl- and 4-heteroaryl-5-oxopyrazoline derivatives of die formula in which R R 2 and R 3 are as defined under formula I, G is the group -CO-A (a), and A is -N(Rj 0 )Ri 3 , where RJO and Rj3 are as defined under formula I with the exception of R j0 as hydrogen, reacting a compound of the formula in which R R 2 and R 3 are as defined, witii a compound of die formula in which R 10 and R !3 are as defined and Ej is a leaving group, preferably halogen and especially chlorine; or c) for the preparation of the 4-aryl- and 4-heteroaryl-5-oxopyrazoline derivatives of die formula in which R j , R 2 and R 3 are as defined under formula I, G is die group -CO-A (a), and A is -NHR 13 , where g a compound of the formula in which R j , R 2 and R 3 are as defined, witii an isocyanate of the formula R 13 -N=C=O (V), in which R 13 is as defined. The process according to die invention for die preparation of compounds of die formula in which Rj, R 2 and R 3 are as defined under formula I, G is die group -SO 2 -B (b), and B is as defined under foiπiula I, is carried out in analogy to known processes as described, for example, in EP-A-0508 126, and comprises reacting a compound of die formula in which R 1? R and R 3 are as defined under formula I, with a compound of die formula in which B is as defined and E l is a leaving group such as halogen, especially chlorine, if desired in a solvent and in die presence or absence of a base. The reactions according to process variants (a), (b) and (c) can be carried out in analogy to known processes, advantageously in a reaction-inert, hydroxyl-free solvent in the presence of an organic base such as, for example, pyridine, 4-dimethylaminopyridine, lutidine, collidine, trialkylamines, N,N-dialkylaniline, or bicyclic nonnucleophilic bases such as, for example, l,4-diazabicyclo[2.2.2]octane (DABOO), l,5-diazabicyclo[4.3.0]non-5-ene (DBN) or l,8-diazabicyclo[5.4.0]undec-7-ene (DBU). The reaction is generally carried out at temperatures of from 0 to 120°C, preferably from 20 to 90°C, advantageously in the presence of a reaction-inert solvent or solvent mixture. Examples of those suitable for this purpose are aliphatic and aromatic hydrocarbons such as benzene, toluene, petroleum ether or hexane; halogenated hydrocarbons such as chlorobenzene, methylene chloride, ethylene chloride, chloroform, carbon tetrachloride and tetrachloroethylene; ethers and ether-like compounds, such as dialkyl etiiers, for example dietiiyl ether, diisopropyl ether and tert-butyl methyl ether, and also anisole, dioxane and tetrahydrofuran; nitriles such as acetonitrile and propionitrile; esters such as ethyl acetate, propyl acetate and butyl acetate; ketones such as acetone, diethyl ketone and methyl ethyl ketone; and mixtures of such solvents. The reaction of die compound of die formula II widi the reactive sulfonic acid derivative of the formula VI takes place advantageously in equimolar quantities at temperatures of from 0 to 150°C, preferably from 20 to 70°C. Suitable solvents are the customary reaction-inert, polar, organic solvents, such as etiiers, amides, nitriles, alcohols, sulfones or sulfoxides, especially dimetiiyl sulfoxide, tetrahydrofuran or N,N-dimedιylformamide. Suitable binding agents for die acid formed are the known inorganic and organic bases such as sodium hydroxide, sodium carbonate, potassium carbonate or pyridines. The reaction can take place under elevated pressure or, in particular, at atmospheric pressure. If desired it is also possible to operate under phase transfer conditions, in which case from 0.3 to 1.5 mol of reactive sulfonic acid derivative of the formula VI are employed per mole of die compound of die formula II at from 0 to 150°C, preferably from 20 to 70°C. Phase transfer catalysts which can be used are the customary quaternary ammonium salts, such as tetraoctylammonium bromide or benzyltriethylammonium chloride. In this case suitable organic solvents are all inert apolar solvents, such as benzene or toluene. The compounds of die formula II, in which Rj, R 2 and R 3 are as defined under formula I, are known from EP-A-0508 126 and WO 92/16510 and can be prepared by the processes disclosed. The compounds of the formulae III, IV, V and VI required for the preparation processes are eiϋier commercial products or can be prepared in analogy to known standard processes. The end products of the formula I can be isolated in a customary manner by concentration and/or evaporation of the solvent and purified by recrystallization or trituration of the solid residue in solvents in which they are not readily soluble, such as ethers, alkanes, aromatic hydrocarbons or chlorinated hydrocarbons, or by means of chromatography over a silica gel column. Salts of compounds of the formula I can be prepared in a manner known per se. Thus, for example, acid addition salts of compounds of die formula I are obtained by treatment with a suitable acid or a suitable ion exchanger reagent, and salts with bases by treatment with a suitable base or a suitable ion exchanger reagent Salts of compounds of the formula I can be convened into die free compounds of the formula I in a customary manner; acid addition salts, for example, by treatment with a suitable basic agent or a suitable ion exchanger reagent, and salts with bases, for example, by treatment with a suitable acid or a suitable ion exchanger reagent. Salts of compounds of die formula I can be converted into other salts of compounds of die formula I in a manner known per se; acid addition salts, for example, can be converted into other acid addition salts, for example, by treating a salt of an inorganic acid, such as a hydrochloride, with an appropriate metal salt, such as a sodium, barium or silver salt, of an acid, for example with silver acetate, in a suitable solvent in which die inorganic salt which forms, for example silver chloride, is insoluble and therefore separates out of the reaction mixture. Depending on die procedure and reaction conditions, d e compounds of the formula I with salt-forming properties can be obtained in free form or in the form of salts. Unless specific synthesis is carried out for the isolation of pure isomers, the product can be obtained as a mixture of two or more isomers. The isomers can be separated by methods known per se. For the compositions comprising the compounds of the formula I, the preferences which apply are the same as those for the compounds of die formula I. The present invention also relates to a selective-herbicidal composition for controlling grasses and weeds in crops of useful plants, especially in crops of maize and cereal, which composition comprises a herbicide and a safener (counteracting agent, antidote) and which protects the useful plants but not the weeds against the phytotoxic action of the herbicide, and to die use of this composition for weed control in crops of useful plants. When herbicides are used it is possible, for example, depending on the rate and mode of application of die herbicide, on the crop plant, on the nature of the soil and on die climatic conditions, such as period of exposure to light, temperature and amounts of precipitation, for d e crop plants as well to be damaged to a considerable extent. In order to counter this and similar problems, a variety of substances have already been proposed as safeners, which are capable of antagonizing die damaging effect of the herbicide on die crop plant, in other words of protecting the crop plant from said effect, while causing virtually no impairment of the herbicidal action on the weeds to be controlled. In this context it has been found tiiat die proposed safeners often have a very specific action with respect to the crop plants and wid respect to the herbicide and, in some cases, in dependence on die mode of application; in otiier words, a certain safener is often suitable only for one specific crop plant and one specific class of herbicide or a specific herbicide. Thus, for example, EP-A-0094 349 discloses quinoline derivatives which protect crop plants against the phytotoxic effect of herbicides of particular classes, for example chloroacetanilides, phenoxypropionates, ureas, triazines, carbamates or diphenyl ethers. EP-A-0558 448 describes l,5-diphenylpyrazole-3-carboxylic acid derivatives for protecting against the phytotoxic effect of sulfonylureas. It has now been found tiiat safener compounds selected from the classes of the quinoline, pyrazole or triazole derivatives are suitable for protecting crop plants against the phytotoxic effect of 4-aryl- and 4-heteroaryl-5-oxopyrazoline derivatives of the formula I. In accordance witii die invention, dierefore, a selective-herbicidal composition is proposed which comprises, in addition to customary inert formulation auxiliaries such as carriers, solvents and wetting agents, an active substance comprising a mixture of a) a herbicidally effective quantity of a herbicide compound of the formula I as defined hereinbefore and b) a herbicide-antagonistically effective quantity of either a quinoline derivative of die formula in which R 15 is hydrogen, Cj-C 8 alkyl or Cj-C 8 alkyl which is substituted by Cj- alkoxy or C 3 -C $ alkenyloxy; and X 2 is hydrogen or chlorine; or of a l-phenylazole-3-carboxylic acid derivative of die formula in which E is nitrogen or methine; R 16 is -CCI 3 or unsubstituted or halo-substituted phenyl; R 17 and R 18 independently of one another are hydrogen or halogen; and R 19 is C j -C 4 alkyl. Preferred compounds of the formula I in the composition according to the invention arc those in which Rj is the group '- ~~ d m s 0- Among these, particular preference is given to those compounds in which R 4 is Cj- or C^alkyl; and n is 1, 2 or 3. In particular, among diese compounds, very particular preference is given to those in which R 4 is C j - or C 2 alkyl in positions 2, 4 and 6 relative to the phenyl linkage site; and n is 3. Likewise preferred are compositions according to d e invention in which, in die compounds of the formula I, R j is the group m is 0; R is Cj- or C 2 alkyl; n is 1, 2 or 3; R 2 and R 3 are C j -C 6 alkyl; or R and R 3 together form a substituted or unsubstituted alkylene chain -(CH 2 ) 5 -, -(CH^- or -(CH^-. Also preferred are those compositions in which G is die group -CO-A (a); and A is C j -C 8 alkyl substituted by nitro, cyano, Si(Cj-C alkyl) 3 , amino, Cj ^alkylamino, di(C j -C 4 alkyl)amino, unsubstituted or substituted benzyloxy or a group - C H- NR røRrø , COORQJO or A is C 3 -C 8 cycloalkyl which if desired can contain as heteroatom oxygen, sulfur or nitrogen and is substituted by C j ^alkyl, Cj-C 4 alkoxy, Cj-C alkylthio, Cj-C alkylsulfinyl, C j -C 4 alkylsulfonyl or substituted or unsubstituted phenyl, or A is C 3 -C 8 cycloalkyloxy which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is unsubstituted or substituted by or A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -R 10 or Furthermore, preference is given to those compositions in which Rj is the group R 4 is Cj- or C 2 alkyl; n is 1, 2 or 3; m is 0; R 2 and R 3 are Cj-C 6 alkyl; or R 2 and R 3 together form a substituted or unsubstituted alkylene chain -(CH 2 ) 5 -, -(CH^- or -(CH 2 ) 3 -; G is the group -CO-A (a); and A is Cj-Cgalkyl substituted by nitro, cyano, Si(Cj-C 4 alkyl) 3 , amino, Cj ^alkylamino, di(Cj-C 4 alkyl)amino, unsubstituted or substituted benzyloxy or a group ~ ~" ~~ t~t 08 ~ 09 , or A is C 3 -C 8 cycloalkyl which can if COORQIO desired contain as heteroatom oxygen, sulfur or nitrogen and is substituted by C j -C alkyl, Cj-C 4 alkoxy, C j -C alkylthio, Cj-C 4 alkylsulfinyl, Cj-C 4 alkylsulfonyl or substituted or unsubstituted phenyl, or A is C 3 -Cgcycloalkyloxy which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is unsubstituted or substituted by C j -C 4 alkyl, or A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -R, 0 or -(CR 8 R 9 ) p -R π . Furthermore, preference is given to those compositions which comprise a safener of the formula Likewise preferred are compositions which comprise a safener of the formula Further preferred compositions are those which comprise a safener of the formula Further preferred compounds of die formulae X and XI are also listed in Tables 8 and 9. The quinoline derivatives from die scope of the formula X and their preparation are known or they can be prepared by analogy witii known processes, as described for example in EP-A-0094 349. The l-phenylazole-3-carboxylic acid derivatives from the scope of the formula XI are known and are described for example in EP-A-0268 554 and EP-A-0 174 562. In the field of pest control the compounds of die formula I according to die invention, used even at low concentrations, are active substances having preventive and/or curative value, a very favourable biocidal spectrum and favourable tolerance by warm-blooded animals, fish and plants. The active substances according to die invention are effective against all or individual development stages of normally sensitive, but also of resistant, animal pests, such as insects or members of the order Acarina. The insecticidal or acaricidal action of the active substances according to the invention can become apparent direcdy, i.e. in destruction of the pests which occurs immediately or only after a certain time, for example during moulting, or indirecdy, for example in reduced oviposition and/or hatching rates, the favourable action corresponding to a rate of destruction (mortality) of at least 50 to 60 %. The animal pests mentioned include, for example: from the order Lepidoptera, for example Acleris spp., Adoxophyes spp., Aegeria spp., Agrotis spp., Alabama argillaceae, Amylois spp., Anticarsia gemmatalis, Archips spp., Argyrotaenia spp., Autographa spp., Busseola fusca, Cadra cautella, Carposina nipponensis, Chilo spp., Choristoneura spp., Clysia ambiguella, Cnaphalocrocis spp., Cnephasia spp., Cochylis spp., Coleophora spp., Crocidolomia binotalis, Cryptophlebia leucotreta, Cydia spp., Diatraea spp., Diparopsis castanea, Earias spp., Ephestia spp., Eucosma spp., Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Grapholita spp., Hedya nubiferana, Heliothis spp., Hellula undalis, Hyphantria cunea, Keiferia lycopersicella, Leucoptera scitella, Lithocollethis spp., Lobesia botrana, Lymantria spp., Lyonetia spp., Malacosoma spp., Mamestra brassicae, Manduca sexta, Operophtera spp., Ostrinia nubilalis, Pammene spp., Pandemis spp., Panolis flammea, Pectinophora gossypiella, Phthorimaea operculella, Pieris rapae, Pieris spp., Plutella xylostella, Prays spp., Scirpophaga spp., Sesamia spp., Sparganothis spp., Spodoptera spp., Synand edon spp., Thaumetopoea spp., Tortrix spp., Trichoplusia ni and Yponomeuta spp.; from the order Coleoptera, for example Agriotes spp., Anthonomus spp., Atomaria linearis, Chaetocnema ribialis, Cosmopolites spp., Curculio spp., Dermestes spp., Diabrotica spp., Epilachna spp., Eremnus spp., Leptinotarsa decemlineata, Lissorhoptrus spp., Melolontha spp., Orycaephilus spp., Otiorhynchus spp., Phlyctinus spp., Popillia spp., Psylliodes spp., Rhizopertha spp., Scarabeidae, Sitophilus spp., Sitotroga spp., Tenebrio spp., Tribolium spp. and Trogoderma spp.; from the order Orthoptera, for example Blatta spp., Blattella spp., Gryllotalpa spp., Leucophaea maderae, Locusta spp., Periplaneta spp. and Schistocerca spp.; from the order Isoptera, for example, Reticulitermes spp.; from the order Psocoptera, for example Liposcelis spp.; from the order Anoplura, for example Haematopinus spp., Linognathus spp., Pediculus spp., Pemphigus spp. and Phylloxera spp.; from the order Mallophaga, for example Damalinea spp. and Trichodectes spp.; from the order Thysanoptera, for example Frankliniella spp., Hercinotiirips spp., Taeniod rips spp., Thrips palmi, Thrips tabaci and Scirtothrips aurantii; from the order Heteroptera, for example Cimex spp., Distantiella theobroma, Dysdercus spp., Euchistus spp., Eurygaster spp. Leptocorisa spp., Nezara spp., Piesma spp., Rhodnius spp., Sahlbergella singularis, Scotinophara spp. and Triatoma spp.; from the order Homoptera, for example Aleurothrixus floccosus, Aleyrodes brassicae, Aonidiella spp., Aphididae, Aphis spp., Aspidiotus spp., Bemisia tabaci, Ceroplaster spp., Chrysomphalus aonidium, Chrysomphalus dictyospermi, Coccus hesperidum, Empoasca spp., Eriosoma larigerum, Erythroneura spp., Gascardia spp., Laodelphax spp., Lecanium comi, Lepidosaphes spp., Macrosiphus spp., Myzus spp., Nephotettix spp., Nilaparvata spp., Paratoria spp., Pemphigus spp., Planococcus spp., Pseudaulacaspis spp., Pseudococcus spp., Psylla spp., Pulvinaria aethiopica, Quadraspidiotus spp., Rhopalosiphum spp., Saissetia spp., Scaphoideus spp., Schizaphis spp., Sitobion spp., Trialeurodes vaporariorum, Trioza erytreae and Unaspis citri; from the order Hymenoptera, for example Acromyπnex, Atta spp., Cephus spp., Diprion spp., Diprionidae, Gilpinia polytoma, Hoplocampa spp., Lasius spp., Monomorium pharaonis, Neodiprion spp., Solenopsis spp. and Vespa spp.; from the order Diptera, for example Aedes spp., Antherigona soccata, Bibio hortulanus, Calliphora erythrocephala, Ceratitis spp., Chiysomyia spp., Culex spp., Cuterebra spp., Dacus spp., Drosophila melanogaster, Fannia spp., Gastrophilus spp., Glossina spp., Hypoderma spp., Hyppobosca spp., Liriomyza spp., Lucilia spp., Melanagromyza spp., Musca spp., Oestrus spp., Orseolia spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp., Rhagoletis pomonella, Sciara spp., Stomoxys spp., Tabanus spp., Tannia spp. and Tipula spp.; from the order Siphonaptera, for example Ceratophyllus spp. and Xenopsylla cheopis; from the order Thysanura, for example Lepisma saccharina and from the order Acarina, for example Acarus siro, Aceria sheldoni, Aculus schlechtendali, Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Calipitrimerus spp., Chorioptes spp., Dermanyssus gallinae, Eotetranychus carpini, Eriophyes spp., Hyalomma spp., Ixodes spp., Olygonychus pratensis, Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Tarsonemus spp. and Tetranychus spp.. Using the active substances according to die invention it is possible to control pests of the type mentioned which occur on plants, especially on useful and ornamental plants in agriculture, gardening and forestry, or on parts of such plants, such as fruits, flowers, foliage, stems, tubers or roots, control in this context meaning restrict or destroy, while in some cases also providing protection against these pests to parts of plants which grow subsequently. Suitable target crops are, in particular, cereals such as wheat, barley, rye, oats, rice, maize or sorghum; beet, such as sugar and fodder beet; fruit, for example pome fruit, stone fruit and soft fruit, such as apples, pears, plums, peaches, almonds, cherries or berries, for example strawberries, raspberries or blackberries; pulses, such as beans, lentils, peas or soya; oil crops, such as oilseed rape, mustard, poppy, olives, sunflowers, coconut, castor, cacao or groundnuts; cucurbits, such as pumpkins, cucumbers or melons; fibre plants such as cotton, flax, hemp or jute; citrus fruits, such as oranges, lemons, grapefruits or tangerines; vegetables, such as spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes or bell pepper, the laurel family, such as avocado, cinnamon or camphor, and also tobacco, nuts, coffee, eggplants, sugar cane, tea, pepper, vines, hops, banana family, latex plants and ornamentals. Further fields of use of die active substances according to die invention are the protection of stocks, warehouses and material and in the hygiene sector, especially the protection of domestic and productive animals against pests of the type mentioned. The invention therefore also relates to pesticides which are forms, to be chosen in accordance with the intended aims and prevailing conditions, such as emulsifiable concentrates, suspension concentrates, direcdy sprayable or dilutable solutions, brushable pastes, dilute emulsions, wettable powders, soluble powders, dispersible powders, dusts, granules or encapsulations in polymeric substances, and which comprise - at least - one of the active substances according to the invention. The active substance is employed in tiiese compositions in pure form, a solid active substance, for example, in a specific particle size, or, preferably, together with - at least - one of the auxiliaries which are customary in die art of formulation, such as extenders, for example solvents or solid carriers, or surface-active compounds (surfactants). Examples of suitable solvents are unmodified or partially hydrogenated aromatic hydrocarbons, preferably the C to Cj 2 fractions of alkylbenzenes, such as xylene mixtures, alkylated naphthalenes or tetrahydronaphdialene, aliphatic or cycloaliphatic hydrocarbons, such as paraffins or cyclohexane, alcohols, such as ethanol, propanol or butanol, glycols and ed ers and esters tiiereof, such as propylene glycol, dipropylene glycol ether, ediylene glycol or ethylene glycol monomethyl or monoethyl ether, ketones, such as cyclohexanone, isophorone or diacetone alcohol, strongly polar solvents, such as N-medιylpyrrolid-2-one, dimethyl sulfoxide or N,N-dimethylformamide, water, unmodified or epoxidized vegetable oils, such as unmodified or epoxidized rapeseed, castor, coconut or soya oil, and silicone oils. As solid carriers, for example for dusts and dispersible powders, use is generally made of ground natural minerals, such as calcite, talc, kaolin, montmorillonite or attapulgite. To improve the physical properties it is also possible to add highly disperse silicas or highly disperse absorbent polymers. Suitable granulated, adsorptive granule carriers arc porous types, such as pumice, broken brick, sepiolite or bentonite, while suitable non-sorbent carrier materials are calcite or sand. Moreover, a large number of granulated materials of inorganic or organic type, especially dolomite or comminuted plant residues, can be used. Suitable surface-active compounds, depending on the nature of the active substance to be formulated, are nonionic, cationic and/or anionic surfactants, or surfactant mixtures having good emulsifying, dispersing and wetting properties. The surfactants listed below should be regarded only as examples; the relevant literature describes many other surfactants which are common in the art of formulation and are suitable in accordance with the invention. Suitable nonionic surfactants are primarily polyglycol ether derivatives of aliphatic or cycloaliphatic alcohols, saturated or unsaturated fatty acids and alkylphenols, which can have 3 to 30 glycol ether groups and 8 to 20 carbon atoms in the (aliphatic) hydrocarbon radical and 6 to 18 carbon atoms in the alkyl radical of die alkylphenols. Also suitable are water-soluble adducts, containing 20 to 250 ethylene glycol ether groups and 10 to 100 propylene glycol ether groups, of polyethylene oxide with polypropylene glycol, ethylenediaminopolypropylene glycol and alkylpolypropylene glycol having 1 to 10 carbon atoms in the alkyl chain. The compounds mentioned usually contain, per propylene glycol unit, 1 to 5 ethylene glycol units. Examples which may be mentioned are nonyl- phenolpolyetiioxyethanols, castor polyglycol ediers, polypropylene-polyethylene oxide adducts, tributylphenoxypolyethoxyethanol, polyethylene glycol and octylphenoxy- polyethoxyetiianol. Also suitable are fatty acid esters of polyoxyethylenesorbitan, such as polyoxyethylenesorbitan trioleate. The cationic surfactants are primarily quaternary ammonium salts which have as substituents at least one alkyl radical having 8 to 22 carbon atoms and, additionally, lower, unmodified or halogenated, alkyl, benzyl or lower hydroxyalkyl radicals. These salts are preferably halides, methyl sulfates or ethyl sulfates. Examples are stearyltrimethyl- ammonium chloride and benzyldi(2-chloroethyl)ethylammonium bromide. Suitable anionic surfactants can be both water-soluble soaps and water-soluble synthetic surface-active compounds. Suitable soaps are the alkali metal, alkaline earth metal and substituted or unsubstituted ammonium salts of higher fatty acids (C 10 -C2 2 ). such as the sodium or potassium salts of oleic or stearic acid, or of natural fatty acid mixtures which can be obtained, for example, from coconut oil or tall oil; the fatty acid mediyl-taurine salts should also be mentioned. More often, however, synthetic surfactants are used, especially fatty sulfonates, fatty sulfates, sulfonated benzimidazole derivatives or alkylarylsulfonates. The fatty sulfonates and fatty sulfates are generally in the form of alkali metal, alkaline earth metal or substituted or unsubstituted ammonium salts and generally have an alkyl radical of 8 to 22 carbon atoms, alkyl also including d e alkyl moiety of acyl radicals; examples which may be mentioned are the sodium or calcium salt of ligninsulfonic acid, of dodecylsulfuric ester or of a fatty alcohol sulfate mixture prepared from natural fatty acids. Also included are the salts of sulfuric esters and sulfonic acids of fatty alcohol-etiiylene oxide adducts. The sulfonated benzimidazole derivatives preferably contain 2 sulfonic acid groups and a fatty acid radical having about 8 to 22 carbon atoms. Alkylarylsulfonates are, for example, the sodium, calcium or triethanolammonium salts of dodecylbenzenesulfonic acid, of dibutylnaphthalenesulfonic acid or of a naphtiialenesulfonic acid-formaldehyde condensation product Also suitable are appropriate phosphates, such as salts of the phosphoric ester of a p-nonylphenol-(4-14)-ethylene oxide adduct or phospholipids. The compositions generally contain from 0.1 to 99 %, in particular from 0.1 to 95 , of active substance and from 1 to 99.9 %, in particular from 5 to 99.9 % of - at least - one solid or liquid auxiliary, it being possible in general for from 0 to 25 %, in particular from 0.1 to 20 %, of the compositions to be surfactants (% denotes in each case percent by weight). Whereas the commercial product tends preferably to comprise concentrated compositions, die end user generally uses dilute compositions with substantially lower concentrations of active substance. Preferred compositions are composed, in particular, as follows (% = percent by weight): Emulsifiable concentrates: Active substance: from 1 to 90%, preferably from 5 to 20% Surfactant: from 1 to 30%, preferably from 10 to 20% Solvent: from 5 to 98%, preferably from 70 to 85% Dusts: Active substance: from 0.1 to 10%, preferably from 0.1 to 1% Solid carrier: from 99.9 to 90%, preferably from 99.9 to 99% Suspension concentrates: Active substance: from 5 to 75%, preferably from 10 to 50% Water from 94 to 24%, preferably from 88 to 30% Surfactant: from 1 to 40%, preferably from 2 to 30% Wettable powders: Active subtance: from 0.5 to 90%, preferably from 1 to 80% Surfactant: from 0.5 to 20%, preferably from 1 to 15% Solid carrier: from 5 to 99%, preferably from 15 to 98% Granules: Active substance: from 0.5 to 30%, preferably from 3 to 15% Solid carrier: from 99.5 to 70%, preferably from 97 to 85% The action of the compositions according to the invention can be substantially broadened and adapted to prevailing circumstances by d e addition of odier insecticidal or acaricidal active substances. In this context, suitable additions of insecticidal or acaricidal active substance are, for example, representatives of die following classes of active substance: organophosphorus compounds, nitrophenols and derivatives, formamidines, acylureas, carbamates, pyrethroids, nitroenamines and derivatives, pyrroles, thioureas and derivatives, chlorinated hydrocarbons and Bacillus tiiuringiensis preparations. The compositions according to the invention can also comprise further solid or liquid auxiliaries, such as stabilizers, for example unmodified or epoxidized vegetable oils (e.g. epoxidized coconut oil, rapeseed oil or soya oil), defoamers, for example silicone oil, preservatives, viscosity regulators, binders and or adhesives, and also fertilizers or other active substances for obtaining specific effects, examples being bactericides, nematicides, molluscicides or selective herbicides. The compositions according to die invention are prepared in a known manner for example in the absence of auxiliaries, by grinding, sieving and/or compression of a solid active substance or active substance mixture, for example to a defined particle size, and, when at least one auxiliary is present, for example by intimate mixing and/or grinding of the active substance or active substance mixture with die auxiliary or auxiliaries. These processes for producing the compositions according to the invention, and the use of die compounds I for the production of tiiese compositions, are likewise a subject of the invention. The invention relates furthermore to the methods of application for die compositions, i.e. die mediods of controlling pests of the type mentioned, tiiese methods being chosen in accordance with the intended aims and prevailing circumstances and comprising, for instance, spraying, fogging, dusting, brushing, dressing, broadcasting or watering, and to the use of the compositions for controlling pests of the type mentioned. In tins context, typical application concentrations are between 0.1 and 1000 ppm, preferably between 0.1 and 500 ppm, of active substance. The application rates per hectare are generally from 1 to 200 g of active substance per hectare, in particular from 10 to 1000 g ha, preferably from 20 to 600 g/ha. A preferred method of application in the area of plant protection is application to the foliage of die plants (foliar application), the frequency and rate of application depending on the extent of infestation by the respective pest. However, die active substance can also pass into the plants via the root system (systemic action), by saturating die site of the plants with a liquid composition or incorporating the active substance in solid form into the site of die plants, for example into the soil, in die form of granules, for example (soil application). In paddy rice cultures, such granules can be metered out into the flooded rice field The compositions according to the invention are also suitable for protecting vegetative propagation stock, for example seeds, such as fruits, tubers or grains, or plant seedlings, against animal pests. In this case the propagation stock can be treated with the composition before being planted out; seed, for example, can be dressed before sowing. The active substances according to die invention can also be applied to seeds (coating) by eitiier soaking the seeds in a liquid composition or coating diem with a solid composition. The composition can also be applied when the propagation stock is planted out, at the planting site, for example in the seed drill in the case of sowing. These treatment methods for vegetative propagation stock, and die vegetative propagation stock dius treated, are further subjects of die invention. The compounds of the formula I according to die invention arc also herbicidally active. Suitable application methods for d e herbicidal use, according to the invention, of the compounds of the formula I or of compositions comprising them arc all those methods which arc customary in agriculture, such as prcemergence application, postemergence application and seed dressing, and also a variety of methods and techniques such as, for example, the controlled release of active substance. For this purpose, the active substance in solution is applied to mineral granular carriers or polymerized granules (urea/formaldehyde) which are then dried. If desired, it is additionally possible to apply a coating (coated granules) which permits the release of the active substance in regulated amounts over a defined period. The compounds of the formula I can be employed in unaltered form, i.e. as they are obtained in die syndiesis, but are preferably processed in a conventional manner, using d e auxiliaries which are customary in the art of formulation, for example to give emulsifiable concentrates, directly sprayable or dilutable solutions, dilute emulsions, wettable powders, soluble powders, dusts, granules or microcapsules. The mediods of application, such as spraying, misting, dusting, wetting, scattering or pouring, are - like the nature of die compositions - chosen in accordance with die intended aims and d e prevailing conditions. The formulations, i.e. the compositions, preparations or combinations comprising the active substance of the formula I or at least one active substance of the formula I and, if desired, one or more solid or liquid additives, are produced in a known manner, for example by intimate mixing and or grinding of the active substances with the additives, such as solvents or solid carriers, for example. It is also possible, in addition, for surface-active compounds (surfactants) to be used in the production of the formulations. Suitable solvents, solid carriers and surface-active compounds are, for example, of the type described hereinbefore. The herbicidal formulations generally contain from 0.1 to 99 %, in particular from 0.1 to 95 %, of active substance of the formula I, from 1 to 99 % of a solid or liquid formulation auxiliary and from 0 to 25 %, in particular from 0.1 to 25 %, of a surfactant. While the commercial product tends preferably to comprise concentrated compositions, die end user generally uses dilute compositions. The compositions can also comprise further additives, such as stabilizers, for example unmodified or epoxidized vegetable oils (epoxidized coconut oil, rapeseed oil or soya oil), defoamers, for example silicone oil, preservatives, viscosity regulators, binders, adhesives, and also fertilizers or other active substances for obtaining specific effects. In particular, preferred formulations are composed as follows (% = percent by weight): Emulsifiable concentrates: Active substance: from 1 to 90%, preferably from 5 to 50% Surfactant: from 5 to 30%, preferably from 10 to 20% Solvent: from 15 to 94%, preferably from 70 to 85% Dusts: Active substance: from 0.1 to 50%, preferably from 0.1 to 1% Solid carrier: from 99.9 to 90%, preferably from 99.9 to 99% Suspension concentrates: Active substance: from 5 to 75%, preferably from 10 to 50% Water from 94 to 24%, preferably from 88 to 30% Surfactant: from 1 to 40%, preferably from 2 to 30% Wettable powders: Active subtance: from 0.5 to 90%, preferably from 1 to 80% Surfactant: from 0.5 to 20%, preferably from 1 to 15% Solid carrier: from 5 to 95%, preferably from 15 to 90% Granules: Active substance: from 0.1 to 30%, preferably from 0.1 to 15% Solid carrier: from 99.5 to 70%, preferably from 97 to 85% The active substances of the formula I are in general employed successfully at application rates of from 0.001 to 2 kg/ha, in particular from 0.005 to 1 kg/ha. The rate required in order to achieve the desired effect can be determined by means of trials. It is dependent on the nature of the effect, on the stage of development of die crop plant and of the weed, and on the application (site, time, method) and can, depending on tiiese parameters, vary within wide ranges. The compounds of die formula I are distinguished by herbicidal properties which render diem outstanding for use in crops of useful plants, especially in cereals, cotton, soya, oilseed rape, maize, rice and plantation crops. They can additionally be employed as burn-down agents, for example for potatoes, or as defoliants. References to cultures or crops are intended to include those which have been given tolerance to herbicides or classes of herbicide by means of conventional breeding mediods or methods of genetic manipulation. The invention also relates to a process for the selective control of broad-leaved weeds and grasses in crops of useful plants, which comprises treating the useful plants, their seeds or seedlings or their cultivation area, simultaneously or independently of one another, with a herbicidally effective quantity of d e herbicide of die formula I and widi a herbicide-antagonistically effective quantity of a safener of the formula X or XI. Crop plants which can be protected by die safeners of the formulae X and XI against the damaging effect of the abovementioned herbicides are, in particular, maize and cereals. The weeds to be controlled can be eidier monocotyledon or dicotyledon weeds. The areas regarded as cultivation areas are the soil areas on which the crop plants are already growing, or soil areas sown with the seed of tiiese crop plants, and also the areas intended for cultivation with diese crop plants. Depending on the intended use, a safener of the formula X or XI can be used for pretreating die seed of the crop plant (dressing of die seed or of the seedlings), or placed in die soil before or after sowing. It can also, however, be applied, on its own or togedier with the herbicide, following the emergence of the plants. The treatment of the plants or of the seed with d e safener can therefore, in principle, take place independently of the point in time of die application of die herbicide. The plant treatment, however, can also be carried out by simultaneous application of herbicide and safener (for example as a tank mix). The application rate of safener to herbicide to be applied depends largely on the method of application. In a field treatment carried out either using a tank mix comprising a combination of safener and herbicide or by separate application of safener and herbicide, the ratio of herbicide to safener is in general from 100:1 to 1:10, preferably from 20:1 to 1:1. In general, in field treatment, from 0.001 to 5.0 kg of safener/ha, preferably from 0.001 to 0.5 kg of safener/ha, are applied. The application rates of herbicide are generally between 0.001 and 2 kg ha, but preferably between 0.005 and 1 kg/ha. The compositions according to the invention are suitable for all application methods which are customary in agriculture, for example prcemergence application, postemergence application and seed dressing. In die case of seed dressing, in general, from 0.001 to 10 g of safener/kg of seed, preferably from 0.05 to 2 g of safener/kg of seed, arc applied. If the safener is applied in liquid form shortly before sowing, accompanied by seed swelling, then it is expedient to use safener solutions which comprise the active substance in a concentration of from 1 to 10000 ppm, preferably from 100 to 1000 ppm. For application, die safeners of the formula X or XI, or combinations of tiiese safeners with the herbicides of die formula I, arc advantageously processed together witii the auxiliaries which are customary in the art of formulation to give particular formulations, for example emulsion concentrates, brushable pastes, directly sprayable or dilutable solutions, dilute emulsions, wettable powders, soluble powders, dusts, granules or microcapsules. The formulations are prepared in a known manner, for example by intimate mixing and/or grinding of the active substances with liquid or solid formulation auxiliaries such as, for example, solvents or solid carriers. Furthermore, it is possible in addition to use surface-active compounds (surfactants) when producing die formulations. Suitable solvents, solid carriers and surface-active compounds are, for example, of the type described hereinbefore. The agrochemical formulations generally contain from 0.1 to 99 percent by weight, in particular from 0.1 to 95 % by weight, of safener or safener/herbicide active-substance mixture, from 1 to 99 % by weight, in particular from 5 to 99.8 % by weight, of a solid or liquid formulation auxiliary, and from 0 to 25 % by weight, in particular from 0.1 to 25 % by weight, of surfactant. While the preferred commercial product usually comprises concentrated compositions, the end user generally uses dilute compositions. The compositions can also comprise further additives, such as stabilizers, defoamers, viscosity regulators, binders, adhesives and fertilizers or other active substances. For the use of safeners of the formulae X and XI or compositions comprising them for protecting crop plants against the damaging effects of herbicides of the formula I, a variety of methods and techniques are suitable, examples being the following: i) Seed dressing a) The seeds are dressed by shaking them, in a vessel, together with an active substance of die formula X or XI formulated as a wettable powder until the active ingredient is distributed uniformly on the seed surface (dry seed dressing). In this case from about 1 to about 500 g of active substance of the formula X or XI (from 4 g to 2 kg of wettable powder) are used per 100 kg of seed. b) The seeds are dressed with an emulsion concentrate of the active substance of the formula X or XI in accordance with method a) (wet seed dressing). c) The seeds are dressed by immersing them into a liquor containing 100-1000 ppm of active substance of the formula X or XI for from 1 to 72 hours and tiien, if desired, by drying them (seed soaking). The dressing of die seed, and die treatment of the seedling which has begun germinating, are of course the preferred mediods of application, since the treatment with the active substance is directed entirely towards die target crop. As a rule, from 1 to 1000 g of antidote, preferably from 5 to 250 g of antidote, arc used per 100 kg of seed, it being possible to deviate from these limit concentrations up or down repeat dressing, depending on the mediod, which also makes possible the addition of other active substances or micronutrients. ii) Application as a tank mix A liquid preparation of a mixture of antidote and herbicide (mutual quantitative ratio of between 10:1 and 1:100) is used, the application rate of herbicide being from 0.005 to 5.0 kg per hectare. Such tank mixes are applied before or after sowing. iii) Application in the seed drill The safener is incorporated into the open seed drill, containing seed, as an emulsion concentrate, wettable powder or in the form of granules. After the seed drill has been covered over, die herbicide is applied preemergence in a customary manner. iv) Controlled release of active substance The active substance of the formula X or XI is applied in solution to mineral granule carriers or polymerized granules (urea/formaldehyde), which are then dried. If desired, a coating can be applied (coated granules), which enables the release of the active substance in regulated amounts over a defined period. The examples which follow illustrate the invention in more detail without limiting it. Temperatures are given in degrees Celsius. The temperatures given in the Tables, in the column "Phys. data", are the melting points of the corresponding compounds unless odierwise indicated. Preparation Examples: Example HI: Preparation of 3-oxo-2-(2.4,6-trimethylphenyl)-5,6,7,8-tetrahvdro- 3-H-pyrazolori,2-a1pyridazin- 1-yl 2-cyclohexyl-2-methyIpropionate 1.09 g of 3-hydroxy-4-mesityl-5-oxo-l,2-tetramethylenepyrazoline and 1.4 ml of triethylamine are dissolved in 25 ml of tetrahydrofuran, and 0.75 g of 2-cyclohexyl-2- methylpropionic acid is added at 20°. The reaction mixture is sπrred at 40° for 3 hours and tiien concentrated on a rotary evaporator. The residue is taken up in toluene and water. The toluene phase is dried over sodium sulfate and concentrated. The residue is stirred in hexane and tiien filtered off with suction to give the desired compound as a white powder having a melting point of 172-173°. Example H2: Preparation of 3-oxo-2-(2,4.6-trimethylphenyl)-5,6 ,8-tetrahydro- 3-H-pyrazolor 1 ,2-alpyridazin- 1 -yl (2-cyanoeth vDmethylcarbamate 1.22 g of 3-hydroxy-4-mesityl-5-oxo-l,2-tetramethylenepyrazoline and 1.14 g of triethylamine are dissolved in 25 ml of tetrahydrofuran, and 0.7 g of (2-cyanoethyl)- methylcarbamoyl chloride is added with stirring. The reaction mixture is stirred at 40° for 3 hours and tiien concentrated on a rotary evaporator. Dichloromethane and ice-water are added to die residue. The organic phase is dried with sodium sulfate and concentrated, and die residue obtained is stined witii hexane, filtered off with suction and dried to give the desired compound as a white powder witii a melting point of 151-153°. Example H3: Preparation of 3-oxo-2-(2A6-trimethyIphenyl)-5.6.7,8-tetra- hvdro-3H-pyrazolori,2-alpyridazin-l-yl cvclohexylmethylsulfamate 2.7 g of 3-hydroxy-4-mesityl-5-oxo-l,2-tetramethylenepyrazoline and 3.0 g of triethylamine are dissolved in 30 ml of tetrahydrofuran, a solution of 2.1 g of cyclohexyl- methylsulfamoyl chloride is added at room temperature, and the reaction mixture is then stirred at 40° for 8 hours. It is concentrated and die residue is taken up with ten-butyl methyl ether and ice-water. The organic phase is dried witii sodium sulfate and concentrated. The crude product is dissolved in ethyl acetate, the solution is filtered over silica gel, the filtrate is concentrated and the residue is stined with hexane. Suction filtration and drying give the desired compound as a white powder with a melting point of 171-173°. The compounds of Tables 1-9 can be prepared by analogy with die above examples and with die preparation methods described. Tables 1-7 below list, as compounds of die formulae la to Ig, compounds of the formula I which are preferred as insecticides and acaricides and also as herbicides. Tables 8 and 9 list compounds which are preferred as safeners of the formulae X and XI. Phys.data -CH(C 6 H 5 )OCOCH 3 145-146° -C(CH 3 ) 2 OCOCH 3 104° -C(CH 3 ) 172-173° adamant- 1 -O 204-2 ° 1.22 CH-, CH 3 -C(CH 3 ) 2 OCOCH 3 148-149° Comp. R 2 R 3 Phys.data No. 1.28 -(CH 2 ) 4 - 1.29 CH 3 CH 3 1.30 -(CH 2 ) 4 - 1.31 -(CH 2 ) 4 - 1.32 -(CH 2 ) 4 - 1.33 -(CH 2 ) 4 - 135-137° CH 7 __7 Comp. R 2 R 3 Phys.data No. Phys.data -N(CH 2 CH 2 CN)C 8 H 15 -c -N(CH 2 CH 2 CN)C 7 H 13 -c -N(CH 2 CH 2 CN)C 12 H 23 -c 154-156° -N(CH 2 CH 2 CN)-(CH 2 ) 3 OCH 3 39° Comp. R 2 Ri R 4 Phys.data No. 2.9 -(CH 2 ) 4 -CH- 6-Cl 106-109° 2.10 -(CH 2 ) 4 - -CH2CH2 -C(CH 3 ) 2 O -COOCH 3 -CH(C 6 H 5 )-OCOCH 3 -C(CH 3 ) 2 -C(CH 3 ) 2 -OCO-t-C 4 H 9 -C(CH 3 ) 2 -OCO-C 6 H 5 -N(CH 3 )CH 2 CH 2 CN -C(CH 3 ) 2 -OCO-t-C 4 H 9 -C(CH 3 ) 2 -N(C 2 H 5 )CH 2 CH 2 CN -N(C 3 H 7 -n)CH 2 CH 2 CN -N(CH 2 CH 2 CN)C 6 H 13 (n) -N(CH 2 CH 2 CN)CH 2 -N(CH 2 CH 2 CN)C 4 H 9 (n) -N(CH 2 CH 2 CN) -N(CH 2 CH 2 CN) -C 8 OH 17 -n -N(C 3 H 7 -n)CH 2 CH 2 CN -N(CH 2 CH 2 CN) 2 2.29 -N(CH 2 CH 2 CN) ^ 6 _ α 125 127 -(CH 2 ) 4 Comp. R 2 R. R 4 Phys. No. data 2.94 -(CH 2 ) 4 - -N(CH 2 CH 2 CN) _ ^\ 6 _ F -N(CH 2 CH 2 CN) 2 6-F -N(CH 2 CH 2 CN)CH 2 CH 2 OCH 3 6-F naphdι-2-yl 6-F -N(CH 3 )CH 2 CH 2 CN 6-CH 3 -N(C 2 H 5 )CH 2 CH 2 CN 6-CH 3 -N(C 3 H 7 -n)CH 2 CH 2 CN 6-CH 3 -N(CH 2 CH 2 CN)C 4 H 9 (n) 6-CH 3 -N(CH 2 CH 2 CN)CH 2 _/ \ 6 _Q -N(CH 2 CH 2 CN)CH 2 _ \ g.Qj Table 3 Cpd. R 2 R 3 No. 3.12 -CH 2 CH(CH 3 )CH 2 CH 2 - 3.13 -CH(CH 3 )-(CH 2 ) 3 - 3.14 -CH 2 CH 2 CH(CH 3 )CH 2 CH 2 - 3.15 -(CH 2 ) 4 - 3.16 -CH 2 CH(CH 3 )CH 2 CH 2 - 3.17 -CH(CH 3 )-(CH 2 ) 3 - 3.18 -CH 2 CH 2 CH(CH 3 )CH 2 CH 2 - 3.19 -(0*2) 4 - 3.20 -(CH 2 ) 3 - 3.21 -(CH 2 ) 5 - 3.22 -CH 2 CH(CH 3 )CH 2 CH 2 - 3.23 -CH 2 CH 2 CH(CH 3 )CH 2 CH 2 - Table 4 Comp.No. R 2 R 3 Phys.data 4.2 -(CH 2 ) 4 - -CH; -CH(C ■ 6 Ho 5 )OCOCH 3 -CH(C 6 H 5 )OCO-i-C 3 H 7 -CH(C 6 H 5 )OCO-t-C 4 H 9 -C(CH 3 ) 2 OCOCH 3 -C(CH 3 ) 2 OCO-i-C 3 H 7 -C(CH 3 ) 2 OCO-t-C 4 H 9 -CCCHaJjOCOQsHs 119-120° Comp.No. R 2 R 3 A Phys.data Table 5 Phys. data 171-173° resin Phys. data resin Phys. data 166-168° resin Comp. R 2 R^ B Phys. data No. 5.126 -CH 3 -CH 3 N(CH 2 CH 3 )C 6 H 5 Comp. R 2 R 3 B Phys. data No. / "~ Λ 5.145 -C 2 H 5 -C 2 H 5 -N 5.146 2 CιH 3 C iH 3 - 1 -Naphthyl 5.147 2 CIH 3 C IH 3 2 2-Naphthyl -C H ~C H-C H-C H * 5.148 2 CIH 3 C IH 3 2 -N(CH 3 )-c-C 6 H π ■ ^H -Cπ-CH-CH-" 5.149 C IH 3 C IH 3 -N(CH 2 CH 2 OCH 3 ) 2 -C π "C H-C H-C H * 5.150 C IH 3 C IH 3 N(CH 2 CH 3 )C 6 H 5 5.154 -(CH 2 ) 3 - 1 -Naphthyl Comp. R 2 B Phys. data No. 5.155 -(CH 2 ) 3 - 2-Naphdιyl 5.156 -(CH 2 ) 3 - -N(CH 3 )-c-C 6 H π 5.157 -(CH 2 ) 3 - -N(CH 2 CH 2 OCH 3 ) 2 5.158 -(CH 2 ) 3 - N(CH 2 CH 3 )C 6 H 5 125-127° Table 6 163-166° 6.14 -(CH 2 ) 3 - 6-Cl Comp. R 2 R-, B RA Phys. data No. 6.30 -CH, -C 7 2H"5 6-Cl Comp. R 2 R 3 B R 4 Phys. data No. 181-183° 6.39 -C2H5 -C2H.5 6.40 -C 2 H 5 -C 2 H 5 - N O 6-Cl 6 - 41 l-Naphthyl 6-Cl -CH ,--CCHH--CCHH--CCH " 6.42 C IIH 3 C II H 3 2-Naphthyl 6-Cl -CH 2 ? --CCHH--CCHH--CCH 2 - 6.43 C IlH u3 C II H 3 -N(CH 3 )-c-C 6 Hjj 6-Cl -C H ,--CCH H--CCH H--CC H ■ 6.44 C IIH 3 C II H 3 -N(CH 2 CH 2 OCH 3 ) 2 6-Cl -CHp -,-^CCHH--CCHH--CCH - 6-45 C I IH 3 C II H 3 N(CH 2 CH 3 )C 6 H 5 6-Cl Comp. R 2 B R. Phys. data No. 6.49 -(CH 2 ) 4 - 1 -Naphthyl 6-F 6.50 -(CH 2 ) 4 2-Naphthyl 6-F 6.51 -(CH 2 ) 4 -N(CH 3 )-c-C 6 H 11 6-F 6.52 -(CH 2 ) 4 -N(CH 2 CH 2 OCH 3 ) 2 6-F 6.53 -(CH 2 ) 4 N(CH 2 CH 3 )C 6 H 5 6-F 156-158° Comp. R 2 B R ~ Phys. data No. 175-176° 156-158° Comp. R 2 R- ~ B R. Phys. data No. 6.79 -CH, -C 2 H 5 ■ N. ■CH 3 6-F CH, 6.80 -CH 3 -C 2 H 5 -N 6-F -C H -C H-C H-C H " 6.89 2 CIH 3 C IH 3 2 1 -Naphthyl 6-F 6.90 2-Naphthyl 6-F -CH -CH-CH-CH - 6.91 2 CιH 3 C 1H 3 - -N(CH 3 )-c-C 6 H jj 6-F Comp. R 2 Ri B Phys. data No. -C H p-CH-C H-C Hp- 6.92 C IH 3 C iH, -N(CH 2 CH 2 OCH 3 ) 2 6-F -CH -CH-CH-CH - 6.93 2 CιH 3 C iH 3 - N(CH 2 CH 3 )C 6 H 5 6-F able 7 n Phys. data Comp. R R 3 B n Phys. data No. 7.14 -(CH 2 ) 4 - 2-C 2 H 5 ,4-C 2 H 5 , 6-C 2 H 5 7.15 -(CH 2 ) 4 - N n. • CH 3 2-C2H 5 .4-C 2 H5, CH, 6-C 2 H 5 Comp. R 2 Ri B R 4 n Phys. data No. 6-C 2 H 5 7.28 CH 3 CH 3 -N(CH 2 CH 2 OCH 3 ) 2 2-C 2 H 5 ,4-C 2 H 5ι 6-C 2 H 5 7.29 CH 3 CH 3 -N(CH 2 CH 3 )C 6 H 5 2-C 2 H 5 ,4-C2H 5 , 6-C 2 H 5 7.30 CH, CH, 2-C 2 H 5 ,4-C 2 H 5 , 6-C 2 H 5 7.31 CH, CH, •N n. CH 3 2-C 2 H 5 ,4-C 2 H 5 , CH 6-C 2 H 5 7.32 CH, CH, - 2-C 2 H 5 ,4-C 2 H 5 , 6-C 2 H 5 7.33 -(CH 2 ) 3 - 1-Naphdιyl 2-CH 3 ,6-CH 3 2 7.34 -(CH 2 ) 3 - 2-Naphthyl 2-CH 3 ,6-CH 3 2 7.35 -(CH 2 ) 3 - -N(CH 3 )-c-C 6 H π 2-CH 3 ,6-CH 3 2 7.36 -(CH 2 )3- -N(CH 2 CH 2 OCH 3 ) 2 2-CH 3 ,6-CH 3 2 7.37 -(CH 2 ) 3 - -N(CH 2 CH 3 )C 6 H 5 2-CH 3 ,6-CH 3 2 7.38 -(CH 2 ) 3 - 2-CH 3 ,6-CH 3 2 7.39 -(CH 2 ) 3 - CH 3 2-CH 3 ,6-CH 3 7.40 -(CH 2 ) 3 - 2-CH 3 ,6-CH 3 Comp. R 2 R 3 B R. n Phys. data No. 6-C2H5 7.47 -(CH 2 ) 3 - 2-C 2 H 5 ,4-C 2 H 5 , 3 6-C 2 H 5 /—\ 7.48 -(CH 2 ) 3 - - N 2-C 2 H 5 ,4-C 2 H 5 , 3 6-C 2 H 5 Table 8 Comp. No. > -15 Table 9 Comp. No. ■ -19 R 16 * 7 * 8 Formulation examples Fl to FIO for insecticidal and acaricidal active substances of the formula I (% = percent by weight) Example Fl: Emulsion concentrates a) b) c) Active substance according to Tables 1-7 25% 40% 50% Calcium dodecylbenzenesulfonate 5% 8% 6% Castor oil polyethylene glycol etiier (36 mol EO) 5% - Tributylphenol polyethylene glycol ether (30 mol EO) - 12% 4% Cyclohexanone - 15% 20% Xylene mixture 65% 25% 20% Mixing of finely ground active substance and additives gives an emulsion concentrate which on dilution with water gives emulsions of desired concentration. Example F2: Solutions a) b) c) d) Active substance according to Tables 1-7 80% 10% 5% 95% Ediylene glycol monomethyl ether 20% - Polyethylene glycol (MW 400) - 70% - N-Methylpyrrolid-2-one - 20% - Epoxidized coconut oil - - 1% 5% Petroleum spirit (boiling range: 160-190°) - - 94% - Mixing of finely ground active substance and additives gives a solution suitable for use in the form of very small drops. The active substance is dissolved in dichloromediane, the solution is applied to die carrier mixture by spraying and the solvent is evaporated off in vacuo. Mixing of active substance and carriers gives ready-to-use dusts. Example F5: Wettable powder Active substance according to Tables 1-7 Sodium ligninsulfonate Sodium lauryl sulfate Sodium diisobutylnaphthalenesulfonate Octylphenol polyethylene glycol ether (7-8 mol EO) Highly disperse silica Kaolin Active substance and additives are mixed and die mixture is ground in a suitable mill. Wettable powders are obtained which can be diluted with water to give suspensions of desired concentration. Example F6: Emulsion concentrate Active substance according to Tables 1-7 10% Octylphenol polyethylene glycol ether (4-5 mol EO) 3% Calcium dodecylbenzenesulfonate 3% Castor oil polyethylene glycol ether (36 mol EO) 4% Cyclohexanone 30% Xylene mixture 50% Mixing of finely ground active substance and additives gives an emulsion concentrate which on dilution with water gives emulsions of desired concentration. Application-ready dusts are obtained by mixing active substance and carrier and grinding die mixture in a suitable mill. Example F8: Extruded granules Active substance according to Tab.1-7 10% Sodium ligninsulfonate 2% Carboxymethylcellulose 1% Kaolin 87% Active substance and additives are mixed, the mixture is ground, wetted with water, extruded and granulated, and die granules are dried in a stream of air. Uniform application of the finely ground active substance to die kaolin, wetted with polyediylene glycol, in a mixer gives dust-free coated granules. Example FIO: Suspension concentrate Active substance according to Tables 1-7 40% Ethylene glycol 10% Nonylphenol polyethylene glycol ether (15molEO) 6% Sodium ligninsulfonate Carboxymediylcellulose 1% Aqueous formaldehyde solution (37%) 0.2% Aqueous silicone oil emulsion (75%) 0.8% Water 32% Mixing of finely ground active substance and additives gives a suspension concentrate which on dilution with water gives suspensions of desired concentration. Formulation Examples Fl 1 to F18 for herbicidal active substances of the formula I (% ■ percent by weight) Fl 1. Emulsion concentrates a) b) c) d) Active substance according to Tables 1-7 5% 10% 25 % 50 % Calcium dodecylbenzenesulfonate 6% 8% 6 % 8 % Castor oil polyglycol ether 4% 4% 4% (36 mol EO) Octylphenol polyglycol ether 4% 2% (7-8 mol EO) Cyclohexanone 10% 20% Aromatic hydrocarbon mixture 85% 78% 55% 16% C9-C12 From such concentrates, by dilution witii water, it is possible to prepare emulsions of any desired concentration. F12. Solutions a) b) c) d) Active substance according to Tables 1-7 5% 10% 50% 90% Dipropylene glycolmethyl ether 20% 20% Polyethylene glycol MW 400 20% 10% N-Methyl-2-pyιτolidone 30% 10% Aromatic hydrocarbon mixture 75% 60% C -C12 The solutions are suitable for use in the form of very small drops. F13. Wettable powders a) b) c) d) Active substance according to Tables 1-7 5 % 25 % 50 % 80 % Sodium ligninsulfonate 4 % - 3 % Sodium lauryl sulfate 2 % 3 % - 4 % Sodium diisobutylnaphthalene- - 6 % 5 % 6 % sulfonate Octylphenol polyglycol ether - 1 % 2 % (7-8 mol EO) Highly disperse silica 1 % 3 % 5 % 10 % Kaolin 88 % 62 % 35 % The active substance is mixed thoroughly with the additives and die mixture is ground dioroughly in a suitable mill. Wettable powders are obtained which can be diluted widi water to give suspensions of any desired concentration. F14. Coated granules a) b) c) Active substance according to Tables 1-7 0.1 % 5 % 15 % Highly disperse silica 0.9 % 2 % 2 % Inorganic carrier material 99.0 % 93 % 83 % (00.1 - l mm) such as, for example, CaCO 3 or SiO 2 The active substance is dissolved in methylene chloride, the solution is applied to the carrier by spraying, and d e solvent is subsequently evaporated off in vacuo. F15. Coated granules a) b) c) Active substance according to Tables 1-7 Polyethylene glycol MW 200 Highly disperse silica Inorganic carrier material 98.0 % 92 80 % (00.1 - 1 mm) such as, for example, CaCO 3 or Siθ 2 The finely ground active substance is applied uniformly, in a mixer, to the carrier material wetted widi polyethylene glycol. In tiiis way, dust-free coated granules are obtained. F16. Extruded granules a) b) c) d) Active substance according to Tables 1-7 Sodium ligninsulfonate Carboxymethylcellulose Kaolin The active substance is mixed with the additives, and the mixture is ground and wetted with water. This mixture is extruded and subsequendy dried in a stream of air. F17. Dusts a) b) c) Active substance according to Tables 1-7 Talc Kaolin Application-ready dusts are obtained by mixing the active substance with the carriers and grinding die mixture on a suitable mill. Water 87 % 79 % 62 % 38 % The finely ground active substance is intimately mixed witii the additives. In this way a suspension concentrate is obtained which can be diluted with water to give suspensions of any desired concentration. Formulation Examples F19 to F26 for mixtures of herbicides of the formula I and safeners of the formula X or XI (% = percent by weight) F19. Emulsion concentrates Active substance mixture Calcium dodecylbenzenesulfonate Castor oil polyglycol edier (36 mol EO) Octylphenol polyglycol ether 2 % (7-8 mol EO) Cyclohexanone 10 % 20 % Aromatic hydrocarbon mixture 85 % 78 % 55 % 16 % C9-C12 From such concentrates it is possible by dilution witii water to prepare emulsions of any desired concentration. F20. Solutions Active substance mixture Dipropylene glycol methyl ether Polyediylene glycol MW 400 N-Methyl-2-pyrrolidone Aromatic hydrocarbon mixture C -C12 The solutions are suitable for use in the form of very small drops. F21. Wettable powders a) b) c) d) Active substance mixture 5 % 25 % 50 % 80 % Sodium ligninsulfonate 4 % - 3 % - Sodium lauryl sulfate 2 % Sodium diisobutylnaphthalene- sulfonate Octylphenol polyglycol ether (7-8 mol EO) Highly disperse silica Kaolin The active substance is mixed dioroughly with the additives and the mixture is ground dioroughly in a suitable mill. Wettable powders are obtained which can be diluted witii water to give suspensions of any desired concentration. The active substance is dissolved in methylene chloride, die solution is applied to die carrier by spraying and die solvent is subsequently evaporated off in vacuo. The finely ground active substance is applied uniformly, in a mixer, to the carrier material wetted with polyethylene glycol. In diis way, dust-free coated granules are obtained. F24. Extruded granules a) b) c) d) Active substance mixture 0.1 % 3 % 5 % 15 % Sodium ligninsulfonate 1.5 % 2 % 3 % 4 % Carboxymediylcellulose 1.4 % 2 % 2 % 2 % Kaolin 97.0 % 93 % 90 % 79 % The active substance is mixed with die additives, ground and wetted witii water. This mixture is extruded and then dried in a stream of air. F25. Dusts Active substance mixture Talc Kaolin Application-ready dusts are obtained by mixing the active substance with the carriers and grinding die mixture in a suitable mill. F26. Suspension concentrates Active substance mixture Ethylene glycol Nonylphenol polyglycol ether (15 mol EO) Sodium ligninsulfonate Carboxymethylcellulose 37% aqueous formaldehyde solution Silicone oil emulsion Water The finely ground active substance is intimately mixed widi the additives. In this way, a suspension concentrate is obtained which can be diluted with water to give suspensions of any desired concentration. Biological examples (% = per cent by weight, unless otherwise indicated) A. Insecticidal action Example Bl: Action against Myzus persicae Pea seedlings are infected widi Myzus persicae, subsequently sprayed with a spray mixture comprising 400 ppm of active ingredient and tiien incubated at 20°. The test is evaluated after 3 and 6 days. The percentage reduction in die population (% action) is determined by comparing die number of dead aphids on die treated plants with tiiose on untreated plants. Compounds of Tables 1 to 7 exhibit a good action in this test Example B2: Action against Nilaparvata lugens Rice plants are treated widi an aqueous emulsion spray liquor comprising 400 ppm of active ingredient and, after die spray coating has dried on, arc populated widi stage 2 and 3 cicada larvae. 21 days later, die percentage reduction in die population (% action) is determined by comparing die number of surviving cicadas on die treated plants with those on untreated plants. Compounds of Tables 1 to 7 exhibit a good action in this test. Example B3: Action against Nilaparvata lugens (systemic) Pots containing rice plants are placed in an aqueous emulsion solution comprising 400 ppm of active ingredient. The plants are then populated widi stage 2 and 3 larvae. 6 days later, die percentage reduction in the population (% action) is determined by comparing the number of cicadas on die treated plants with those on untreated plants. Compounds of Tables 1 to 7 exhibit a good action in this test. B. Acaricidal action Example B4: Action against Boophilus microplus Fully satiated adult female ticks are stuck onto a PVC plate and covered widi a cottonwool pad, and 10 ml of aqueous test solution comprising 125 ppm of active ingredient are poured over die animals. The cottonwool pad is removed, and die ticks are incubated for 4 weeks for oviposition. The action is evident either in the female, as mortality or sterility, or in the eggs, as ovicidal action. Compounds of Tables 1 to 7 exhibit a good action in this test. Example B5: Action against Tetranychus urticae Young bean plants are populated widi a mixed population of Tetranychus urticae, sprayed 1 day later with an aqueous emulsion spray liquor comprising 400 ppm of active ingredient, incubated at 25° for 6 days and subsequently evaluated. The percentage reduction in the population (% action) is determined by comparing the number of dead eggs, larvae and adults on the treated plants widi tiiose on untreated plants. Compounds of Tables 1 to 7 exhibit a good action in this test An action of more than 80% is shown, in particular, by the compounds nos. 1.1 to 1.9, 1.11 to 1.28, 1.33 to 1.40, 1.44 to 1.49, 1.51, 1.53, 1.55 to 1.61, 2.2, 2.6 to 2.14, 2.16, 2.17, 2.20, 2.21, 3.1, 5.15, 5.47, 5.80, 5.88, 5.107, 5.110, 5.112, 5.122, 6.2 to 6.4 and 6.7. C. Herbicidal action Example B6: Herbicidal action before emergence of the plants (preemergence) Monocotyledon and dicotyledon test plants are sown in standard soil in plastic pots. Direcdy after sowing, the test substances are sprayed on in an aqueous suspension prepared from a 25 % wettable powder (Example F13, b)), at a rate of 2 kg of AS/ha (500 1 of water/ha). The test plants are subsequently grown in the greenhouse under optimum conditions. After a test duration of 3 weeks, the experiment is evaluated using a 9-point rating scale (1 = complete damage, 9 = no action). Ratings from 1 to 4 (especially 1 to 3) denote a good to very good herbicidal action. In diis experiment, compounds of Tables 1-7 exhibit a strong herbicidal action, as can be seen, for example, from the results presented in Table 10. Table 10 Compound No. A vena Setaria Sinapis Stellaria 1.5 3 1 3 8 1.9 2 2 2 7 1.13 2 3 9 1.14 2 2 9 1.19 2 2 5 1.21 2 3 7 1.24 3 3 7 1.25 3 3 7 1.26 1 2 8 1.27 3 3 7 1.33 2 2 9 1.35 2 1 6 4.15 1 9 9 4.16 1 9 8 4.22 2 9 9 Example B7: Post-emergence herbicidal action (contact herbicide) Monocotyledon and dicotyledon test plants are grown in standard soil in the greenhouse in plastic pots and, at die 4- to 6-leaf stage, are sprayed with an aqueous suspension of die test substances of the formula I, prepared from a 25 % wettable powder (Example F13, b)), at a rate of 2000 g of AS/ha (5001 of water/ha). The test plants are subsequendy grown on in the greenhouse under optimum conditions. After a test period of about 18 days, die experiment is evaluated using a 9-point rating scale (1 = complete damage, 9 = no action). Ratings from 1 to 4 (especially 1 to 3) denote a good to very good herbicidal action. In this experiment, compounds of Tables 1-7 exhibit a strong herbicidal action, as can be seen, for example, from the results presented in Table 11. Table 11 ellaria Example B8: Safener effect Under greenhouse conditions, die test plants are grown in plastic pots to the 4-leaf stage. At this stage, both the herbicide alone and die mixtures of the herbicide with die test substances to be tested as safeners are applied to die test plants. Application takes place in the form of an aqueous suspension of the test substances, prepared from a 25 % wettable powder (Example F21, b)), with 5001 of water/ha. 3 weeks after application, the phytotoxic action of die herbicide on die crop plants, for example maize and cereal, is evaluated using a percentage scale. 100 % denotes tiiat the test plant has died, while 0 % denotes no phytotoxic effect. This experiment shows that, widi compounds of die formula X or XI, for example with the compound no. 8.1, the damage caused to crop plants, for example maize or cereal plants, by herbicide compounds of die formula I, for example by the compound no. 1.13, can be substantially reduced.

Claims: WHAT IS CLAIMED IS: 1. A compound of die formula in which R j is the group the substituents R 4 independendy of one another are halogen, nitro, cyano, Cj-C alkyl, Cj-C 4 haloalkyl, Cι-C 10 alkoxy, Cj-C haloalkoxy, C 3 -C 6 alkenyloxy, Cj-C 4 alkoxy-C 2 -C alkoxy, C 3 -C 6 alkynyloxy, Cj-C alkylcarbonyl, Cj-C alkoxycarbonyl, Cj-C 4 alkylthio, Cj-C alkylsulfinyl, Cj-C 4 alkylsulfonyl, amino, Cj-C 4 alkylamino or di(C j -C alkyl)amino; R 5 is the group n is 0, 1, 2, 3 or 4; m is 0 or 1, and die sum of m and n is 0, 1, 2, 3 or 4; q is O, 1, 2 or 3; Xj is oxygen, sulfur, -CH 2 - or -N(R 7 )-; the substituents R 6 independendy of one another are C r C alkyl, halogen, C j -C 4 haloalkyl, Cj-C 4 alkoxy, Cj-C 4 haloalkoxy, nitro, cyano, Cj-C alkoxycarbonyl, amino, Cj-C alkylamino or di(Cj-C 4 alkyl)amino; R 7 is hydrogen, C j -C 4 alkyl, formyl or C j -C alkylcarbonyl; R 2 and R 3 independendy of one anodier are hydrogen, Cj-C 8 alkyl, C 3 -Cgalkenyl, C 3 -C 8 alkynyl, C j -C 8 alkoxyalkyl, C j -C 8 alkylthioalkyl, C 3 -C 8 cycloalkyl or substituted or unsubstituted aryl; or R 2 and R 3 together form the bivalent radical of a saturated or unsaturated, unsubstituted or substituted, mono-, bi-, tri- or polycyclic system, which system can optionally contain, in positions not adjacent to die nitrogen atoms shown in formula I, one or more ring hetero atoms; G is the group -CO-A (a) or -SO 2 -B (b); A is C r C 8 alkyl substituted by nitro, cyano, Si(Cj-C 4 alkyl) 3 , amino, C r C 4 alkylamino, di(Cj-C 4 alkyI)amino, substituted or unsubstituted benzyloxy or a group ~ ~ U— Roβ rø , COOR 010 or A is C 3 -C 8 cycloalkyl which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is substituted by Cj- alkyl, Cj-C 4 alkoxy, C j -C 4 alkylsulfinyl, C j -C 4 alkylsulfonyl or substituted or unsubstituted phenyl, or A is C 3 -C 8 cycloalkyloxy which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is substituted by C ] -C 4 alkyl, or A is adamantyl, naphdiyl, naphthyl substituted by halogen, C j -C 4 alkyl, C j -C 4 haloalkyl or - alkoxy, or A is a group -(CR 8 R 9 ) p -(Y) 0 -CO-(Z) r -R,o, -(CRgRjyRjj or -N(Rj 0 )R 13 ; R , R 09 and R Q I Q independently of one another are hydrogen or Cj-C 6 alkyl; R 8 and R 9 independendy of one another are hydrogen, Cj-C 6 alkyl or phenyl; RJO is hydrogen, Cj-C j oalkyl, Cj-C 10 alkyl substituted by halogen, Cj-C 4 alkoxy, Cj-C 4 haloalkoxy, C j -C 4 alkylthio, C 3 -C j2 cycloalkyl, cyano, aryl or aryloxy, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl substituted by halogen or C j -C 4 alkyl, C 3 -C 10 alkenyl, C 3 -Cj 0 alkynyl, C 3 -C j ohaloalkenyl, C 3 -C 10 haloalkynyl, aryl, aryl substituted by halogen, Cj-C alkyl, Cj-C 4 haloalkyl, Cj-C 6 alkoxy, Cj-C 4 haloalkoxy, Cj-C 4 alkylthio, nitro, cyano, phenoxy or halo-substituted phenoxy; o and r independently of one anodier are 0 or 1; Y and Z independently of one anodier are oxygen or NR 12 ; p is 1 to 10; RH is C 3 -C 8 cycloalkyl, C -C 8 cycloalkyl substituted by halogen or C j -C 4 alkyl, aryloxy, aryloxy substituted by halogen, C j -C 4 alkyl, C j -C 4 haloalkyl, C j -C 4 alkoxy, Cj-C haloalkoxy, Cj-C 4 alkylthio, nitro, cyano, phenoxy or halo-substituted phenoxy, benzyloxy, benzyloxy substituted by halogen, C j -C 4 alkyl, C j -C 4 haloalkyl, C j - alkoxy, Cj-C 4 haloalkoxy, Cj-C 4 alkylthio, nitro, cyano, phenoxy or halo-substituted phenoxy, norbomyl or adamantyl, where aryloxy with die exception of phenoxy can in each case be any desired aryloxy group; Rj 2 is hydrogen, C j -C 4 alkyl, C 3 -C 8 cycloalkyl, C 3 -Cι 0 alkenyl or C 3 -Cjoalkynyl; Rj 3 is C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl substituted by halogen or C j -C 4 alkyl, or cyano-Cj-C 6 alkyl; B is Cj-Cjoalkyl substituted by Cj-C 4 alkoxy, Cj-C 6 alkoxy-Cj-C 4 alkoxy, C ] -C 4 haloalkoxy, C j -C 4 alkylthio, Cj-Qhaloalkylthio, C j -C 4 alkylsulfinyl, Cj-C 4 alkylsulfonyl, C j -C 4 alkylsulfonyloxy, C j -C 4 alkylcarbonyl, C r C 4 alkoxycarbonyl, Cj-C 4 alkylcarbonyloxy, di(Cj-C 4 alkyl)amino, C 3 -C 8 cycloalkyl, aryl, aryloxy, arylthio, arylsulfonyl, arylsulfinyl, arylsulfonyloxy, arylcarbonyl or pyridyl, it being possible for the aryl and pyridyl groups if desired to be substituted by halogen, Cj-C 4 alkyl, C j -C 4 haloalkyl, C j -C 4 alkoxy, Cj-C 4 haloalkoxy, Cj-C 4 alkylthio, nitro, cyano, phenoxy, halo-substituted phenoxy, phenylthio or halo-substituted phenylthio, or B is C 3 -C 10 alkenyl, C 3 -C 10 haloalkenyl, C 3 -C j oalkynyl, C 3 -Cjohaloalkynyl, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl substituted by halogen or Cj- alkyl, benzyl, benzyl substituted by halogen, C r C 4 alkyl, C r C 4 haloalkyl or Cj-C 4 alkoxy, naphthyl, naphdiyl substituted by halogen or nitro, or B is a group -N(R 2 j)R 22 ; R 2 ι is C j -C 10 alkyl substituted by Cj-C 4 alkoxy, C 1 -C 6 alkoxy-C 1 -C 4 alkoxy, Cj-C 4 haloalkoxy, C j - alkylthio, Cj-C 4 haloalkylthio, Cj-C 4 alkylsulfinyl, Cj-C 4 alkylsulfonyl, C j -C 4 alkylsulfonyloxy, Cj-C 4 alkylcarbonyl, Cj-C 4 alkoxycarbonyl, Cj-C 4 alkylcarbonyloxy, di(C 1 -C 4 alkyl)amino, C 3 -C 8 cycloalkyl, aryl, aryloxy, aryldiio, arylsulfonyl, arylsulfinyl, arylsulfonyloxy, arylcarbonyl or pyridyl, it being possible for the aryl and pyridyl groups if desired to be substituted by halogen, Cj-C 4 alkyl, Cj-C 4 haloalkyl, Cj-C alkoxy, Cj-C 4 haloalkoxy, Cj-C alkylthio, nitro, cyano, phenoxy, halo-substituted phenoxy, phenylthio or halo-substituted phenyltiiio, or R 2 j is C 3 -C 2 Qalkenyl, C 3 -C 2 ohaloalkenyl, C 3 -C 2 oalkynyl, C 3 -C 2 ohaloalkynyl, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl substituted by halogen or Cj-C 4 alkyl, benzyl or aryl, it being possible for the benzyl and aryl groups if desired to be substituted by halogen, Cj-C 4 alkyl, Cj-C haloalkyl, Cj-C alkoxy, Cj-C haloalkoxy, Cj-C 4 alkylthio, nitro, cyano, benzoyi, halo-substituted benzoyi, phenoxy or halo-substituted phenoxy; R 22 is as defined for R 2 j or else alternatively is Cj-Cjoalkyl; or R 21 and R 22 . together widi die nitrogen atom to which they are attached, form an unsubstituted or mono- to trisubstituted, nonaromatic, mono- or bicyclic heterocyclic ring in which the substituents can be C 1 -C 4 alkyl, Cj-C alkyl substituted by halogen, Cι-C 4 alkoxy, phenyl, benzodioxoyl or trifluoromethylphenyl, Cj-Qalkoxy, Cj-C alkoxycarbonyl, C j - alkylcarbonyl, phenyl, phenyl substituted by halogen, Cj-C 4 alkyl, Cj-Qalkoxy, nitro or trifluoromethyl, pyridyl, pyrimidinyl or formyl, and salts and diastereomers of die compounds of die formula I, with die proviso tiiat, if R 2 j and R 22 are alkyl, at least one of these radicals is substituted alkyl. 2. A compound according to claim 1, in which Rj is the group 3. A compound according to claim 2, in which R 4 is fluorine, chlorine or Cj-C 4 alkyl; n is 1, 2 or 3; and m is O. 4. A compound according to claim 3, in which R.- J is fluorine, chlorine or methyl; and n is 2 or 3. 5. A compound according to claim 1, in which R 2 and R 3 are Q-Qalkyl; or R 2 and R 3 together form a substituted or unsubstituted alkylene chain -(CH 2 )5-, -(CH 2 ) 4 - or -(CΑ Q ) 3 -. 6. A compound according to claim 1, in which G is the group -CO-A (a). 7. A compound according to claim 6, in which A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -R 10 , -(CR 8 R 9 ) p -R j j or -N(R 10 )Rj 3 , or substituted or unsubstituted naphthyl. 8. A compound according to claim 7, in which R 8 and R 9 independently of one another are hydrogen or methyl; and p is 1 or 2. 9. A compound according to claim 8, in which R 8 and R 9 are methyl. 10. A compound according to claim 7, in which Rj 0 is Cj-C 8 alkyl, Q-Qcycloalkyl, phenyl, phenyl substituted by halogen, or is naphthyl; R n is C 3 -C 8 cycloalkyl, benzyloxy, benzyloxy substituted by halogen, C j -Qalkyl, C j -Qhaloalkyl or phenoxy, or is naphthyloxy; and RJ3 is C 3 -Cτcycloalkyl or cyano-Cj-Qalkyl. 11. A compound according to claim 7, in which Y and Z are NRj 2 . 12. A compound according to claim 11, in which R 12 is hydrogen or -Qalkyl. 13. A compound according to claim 7, in which R and R 9 independendy of one another are hydrogen or methyl; p is 1 or 2; R j0 is Q-Qalkyl, Q-Qcycloalkyl, phenyl, phenyl substituted by halogen, or is naphthyl; Rj j is Q-Qcycloalkyl, benzyloxy, benzyloxy substituted by halogen, Q-Qalkyl, Q-Qhaloalkyl or phenoxy, or is naphthyloxy; Y and Z are NRj 2 ; R 1 is hydrogen or Q-Qalkyl; and Rj 3 is Q-Qcycloalkyl or cyano-Q-Qalkyl. 14. A compound according to claim 1, in which Rj is die group ιs fluorine, chlorine or Q-Qalkyl; n is 1, 2 or 3; m is 0; R and R 3 are Q-Qalkyl; or R 2 and R 3 togedier form a substituted or unsubstituted alkylene chain -(CH 2 ) 5 -, -(CH 2 ) 4 - or -(CH 2 ) 3 -; G is the group -CO-A (a); A is a group -(CR 8 R9) p -(Y) o -CO-(Z) r -R j0 , -(CR 8 R ) p -R j j or -N(R 10 )Ri 3 , or is unsubstituted or substituted naphdiyl; R 8 and R independendy of one another arc hydrogen or methyl; p is 1 or 2; Rj 0 is Q-Qalkyl, Q-Qcycloalkyl, phenyl, phenyl substituted by halogen, or is naphthyl; Rj j is Q-Qcycloalkyl, benzyloxy, benzyloxy substituted by halogen, Q-Qalkyl, Q-Qhaloalkyl or phenoxy, or is naphthyloxy; and R 13 is Q-Qcycloalkyl or cyano-C j -Qalkyl. 15. A compound according to claim 1, in which Rj is the group and m is O. 16. A compound according to claim 15, in which 1^ is Cj- or Qalkyl; and n is 1, 2 or 3. 17. A compound according to claim 16, in which R^ is C j - or Qalkyl in positions 2, 4 and 6 relative to the phenyl linkage site; and n is 3. 18. A compound according to claim 1, in which Rj is die group m is 0; R 4 is Cj- or Qalkyl; n is 1, 2 or 3; R 2 and R 3 are C j -Qalkyl; or R 2 and R 3 together form a substituted or unsubstituted alkylene chain -(CH 2 ) 5 -, -(CH 2 or -(CH 2 ) 3 -. 19. A compound according to claim 1, in which G is a group -CO-A (a); and A is Q-Qalkyl substituted by nitro, cyano, Si(Q-Qalkyl) 3 , amino, Q-Qalkylamino, di(Q-Qalkyl)amino, substituted or unsubstituted benzyloxy or a group — CH— N RrøRrø t COORQJO or A is Q-Qcycloalkyl, which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is substituted by Q-Qalkyl, Q-Qalkoxy, Q-Qalkylthio, Q-Qalkylsulfinyl, Q-Qalkylsulfonyl or substituted or unsubstituted phenyl, or A is Q-Qcycloalkyloxy which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is unsubstituted or substituted by Q-Qalkyl, or A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -Rj 0 or -(CR 8 R 9 ) p -Rn. 20. A compound according to claim 1, in which Rj is die group R is Cj- or C 2 alkyl; n is 1, 2 or 3; m is 0; R 2 and R 3 are Cj-C 6 alkyl; or R 2 and R 3 together form a substituted or unsubstituted alkylene chain -(CH 2 ) 5 -, -(CH 2 ) - or -(CH^) 3 -; G is the group -CO-A (a); and A is Q-Qalkyl substituted by nitro, cyano, Si(Q-Qalkyl) 3 , amino, Q-Qalkylamino, di(Q-Qalkyl)amino, substituted or unsubstituted benzyloxy or a group - CH - N Ro- R rø , or A is Q-Qcycloalkyl which can if desired contain as heteroatom COORQJO oxygen, sulfur or nitrogen and is substituted by Q-Qalkyl, Q-Qalkoxy, Q-Qalkylthio, Q-Qalkylsulfinyl, Q-Qalkylsulfonyl or substituted or unsubstituted phenyl, or A is Q-Qcycloalkyloxy which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is unsubstituted or substituted by Q-Qalkyl, or A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -Rj 0 or -(CRg^ p -R,,. 21. A process for the preparation of a compound of die formula in which Rj, R 2 and R 3 are as defined in claim 1, G is die group -CO-A (a) and A is as defined in claim 1 widi die exception of the group -N(R 10 )RJ3, which comprises reacting a compound of die formula in which Rj, R 2 and R 3 are as defined, with a compound of the formula in which A is as defined and E j is a leaving group. 22. A process for the preparation of a compound of the formula in which R lf R 2 and R 3 arc as defined in claim 1, G is the group -CO-A (a), and A is -N(R 10 )R j3 , where R j0 and Rj 3 are as defined in claim 1 with die exception of R 10 as hydrogen, which comprises reacting a compound of die formula in which Rj, R 2 and R 3 arc as defined, with a compound of die formula in which R 10 and R 13 arc as defined and Ej is a leaving group. 23. A process for the preparation of a compound of die formula in which Rj, R 2 and R 3 are as defined in claim 1, G is the group -CO-A (a), and A is -NHRj 3 , where Rj 3 is as defined in claim 1, which comprises reacting a compound of die formula in which R j, R 2 and R 3 are as defined, widi an isocyanate of the formula R 13 -N=C=O (V), in which R 13 is as defined. 24. A process for the preparation of a compound of die formula in which R j , R 2 and R 3 are as defined in claim 1, G is die group -SO 2 -B (b), and B is as defined in claim d of die formula in which R j , R 2 and R 3 are as defined in claim 1, widi a compound of die formula B-SO 2 -E j (VI), in which B is as defined and E j is a leaving group, if desired in a solvent and in die presence or absence of a base. 25. A pesticidal composition comprising, in addition to customary formulation auxiliaries, at least one compound of die formula I according to claim 1 as active substance. 26. The use of a pesticidal composition according to claim 25 for controlling insects, representatives of the order Acarina or broad-leaved weeds and grasses. 27. A method of controlling broad-leaved weeds and grasses, which comprises treating the crop plants which are to be protected against broad-leaved weeds and grasses, or die broad-leaved weeds and grasses themselves, widi a composition according to claim 25. 28. A pesticidal composition according to claim 25, which is used for controlling insects or representatives of the order Acarina. 29. A pesticidal composition according to claim 25, which is used for the selective control of broad-leaved weeds and grasses in crops for useful plants. 30. The use of a composition according to claim 26 for controlling insects or representatives of the order Acarina. 31. The use of a composition according to claim 26 for the selective control of broad-leaved weeds and grasses in crops of useful plants. 32. A method of controlling insects or representatives of the order Acarina, which comprises applying a composition according to claim 28 to the pests or their habitat 33. A method according to claim 32 for protecting vegetative propagation stock against infestation by insects or representatives of die order Acarina, which comprises treating the propagation stock or the site where the propagation stock is planted out. 34. Vegetative propagation stock treated by die mediod described in claim 33. 35. A method for controlling unwanted plant growth, which comprises treating the crop plants which are to be protected against broad-leaved weeds, and/or the broad-leaved weeds and grasses, with a composition according to claim 25. 36. A composition according to claim 28, which contains from 0.1 to 99 percent by weight of active substance. 37. A method according to claim 32, wherein from 0.001 to 2 kg of active substance are applied per hectare. 38. A composition according to claim 29, which contains from 0.1 to 95 percent by weight of active substance of the formula I. 39. A method according to claim 35, which comprises applying a compound of die formula I in a quantity of from 0.001 to 2 kg per hectare. 40. A selective-herbicidal composition which comprises, in addition to customary inert formulation auxiliaries, a mixture of a herbicidally effective quantity of a compound of die formula I and safener, as active substance. 41. A herbicidal composition according to claim 40, wherein die safener is a quinoline derivative, pyrazole derivative or triazole derivative. 42. A composition according to claim 41, wherein die safener is either a quinoline derivative of the formula in which R 15 is hydrogen, Q-Qalkyl or Q-Qalkyl which is substituted by Q-Qalkoxy or Q-Qalkenyloxy; and X 2 is hydrogen or chlorine; or a l-phenylazole-3-carboxylic acid derivative of the formula in which E is nitrogen or methine; R 16 is -CCI 3 or unsubstituted or halo-substituted phenyl; R ι 7 and R 18 independently of one another are hydrogen or halogen; and R 19 is Q-Qalkyl. 43. A composition according to claim 40, wherein, in the compounds of die formula I, the radical Rj is die group m 1S 0- 44. A composition according to claim 43, in which R 4 is Q- or Qalkyl; and n is 1, 2 or 3. 45. A composition according to claim 44, in which R 4 is Cj- or Qalkyl in positions 2, 4 and 6 relative to the phenyl linkage site; and n is 3. 46. A composition according to claim 40, wherein, in the compounds of the formula I, R j is the group m is O; R is Cj- or C 2 alkyl; n is l, 2 or 3; R and R 3 are C j -C 6 alkyl; or R 2 and R 3 together form a substituted or unsubstituted alkylene chain -(CH 2 ) 5 -, -(CH 2 ) 4 - or -(CH 2 ) 3 -. 47. A composition according to claim 40, wherein, in the compounds of die formula I, G is die group -CO-A (a); and A is Q-Qalkyl substituted by nitro, cyano, Si(Q-Qalkyl) 3 , amino, Q-Qalkylamino, di(Q-Qalkyl)amino, unsubstituted or substituted benzyloxy or a group -CH-_ v π. 08 R 09 1 0 r A is Q-Qcycloalkyl which if desired can contain as COOR 010 heteroatom oxygen, sulfur or nitrogen and is substituted by Q-Qalkyl, Q-Qalkoxy, Q-Qalkyldiio, Q-Qalkylsulfinyl, Q-Qalkylsulfonyl or substituted or unsubstituted phenyl, or A is Q-Qcycloalkyloxy which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is unsubstituted or substituted by Q-Qalkyl, or A is a group -(CR 8 R 9 ) p -(Y) 0 -CO-(Z) r -Rιoor -(CR 8 R 9 ) p -R 11 . 48. A composition according to claim 40, wherein, in die compounds of die formula I, R j is the group Q-Qalkyl; or R and R 3 together form a substituted or unsubstituted alkylene chain -(CH^-, -(CH 2 ) 4 - or -(CR-^ ; G is die group -CO-A (a); and A is Q-Qalkyl substituted by nitro, cyano, Si(Q-Qalkyl) 3 , amino, Q-Qalkylamino, di(Q-Qalkyl)amino, unsubstituted or substituted benzyloxy or a group ~ CH— N RoβR w , or A is Q-Qcycloalkyl COORQJO which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is substituted by Q-Qalkyl, Q-Qalkoxy, Q-Qalkylthio, Q-Qalkylsulfinyl, Q-Qalkylsulfonyl or substituted or unsubstituted phenyl, or A is Q-Qcycloalkyloxy which can if desired contain as heteroatom oxygen, sulfur or nitrogen and is unsubstituted or substituted by Q-Qalkyl, or A is a group -(CR 8 R 9 ) p -(Y) o -CO-(Z) r -R 10 or -(CR 8 R 9 ) p -Rn. 49. A composition according to claim 42, which comprises as safener a compound of die formula 50. A composition according to claim 42, which comprises as safener a compound of the formula 51. A composition according to claim 42, which comprises as safener a compound of die formula 52. A method for the selective control of broad-leaved weeds and grasses in crops of useful plants, which comprises treating the crops, their seed or dieir cultivation area, simultaneously or independently of one anodier, with an effective quantity of a herbicide of the formula I and a herbicide-antagonistically effective quantity of a safener of the formula X or XI according to claim 42. 53. A method according to claim 52, which comprises treating stocks of crop plants or cultivation areas for crop plants with from 0.001 to 2 kg ha of a herbicide of the formula I and a quantity of from 0.001 to 0.5 kg/ha of a safener of the formula X or XI. 54. A method according to claim 52, wherein the crop plants are maize and cereals. 55. A compound according to claim 1 of die formula I, in which Rj is 2,4,6-trimethylphenyl, R 2 and R 3 togedier are -(CH 2 ) 4 - and G is -C(=O)-N(CH 3 )CH 2 CH 2 CN. 56. A compound according to claim 1 of die formula I, in which Rj is 2,4,6-trimethylphenyl, R 2 and R 3 -N together are -CH 2 CH 2 CH(CH 3 )CH 2 - N and G is -C(=O)-N(CH 3 )CH 2 CH 2 CN. 57. A compound according to claim 1 of the formula I, in which R j is 2,6-dichlorophenyl, R 2 and R 3 together are -(CH 2 ) 4 - and G is -C(=O)-N(CH 3 )CH 2 CH 2 CN.

Inventors: BOEGER MANFRED, CEDERBAUM FREDRIK, EKKUNDI VADIRAJ SUBBANNA, KULKARNI SURENDRA UMESH, MAIENFISCH PETER, NADKARNI PRADEEP JEEVAJI, PITTERNA THOMAS, BOEGER, MANFRED, CEDERBAUM, FREDRIK, EKKUNDI, VADIRAJ, SUBBANNA, KULKARNI, SURENDRA, UMESH, MAIENFISCH, PETER, NADKARNI, PRADEEP, JEEVAJI, PITTERNA, THOMAS
Applicants: BOEGER MANFRED, CEDERBAUM FREDRIK, CIBA GEIGY AG, EKKUNDI VADIRAJ SUBBANNA, KULKARNI SURENDRA UMESH, MAIENFISCH PETER, NADKARNI PRADEEP JEEVAJI, PITTERNA THOMAS, BOEGER, MANFRED, CEDERBAUM, FREDRIK, CIBA-GEIGY AG, EKKUNDI, VADIRAJ, SUBBANNA, KULKARNI, SURENDRA, UMESH, MAIENFISCH, PETER, NADKARNI, PRADEEP, JEEVAJI, PITTERNA, THOMAS
Application year: 1995
Main classification: C07D231
IPC codes: A01N43, A01N47, C07D215, C07D231, C07D249, C07D401, C07D487, C07F7