Method for producing polysilanes

Abstract: The present invention provides a method for producing a polysilane characterized in that a starting halosilane is subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a polysilane. The present invention affords the polysilane in a high yield, with a molecular weight which is uniform and high enough to be cast into an excellent thin film, with ease of handling, safety and low cost ensured.

Description: The present invention relates to a method for the production of polysilanes. Polysilanes are attracting attention for their use as ceramic precursors; optoelectronic materials such as photoresist, organic photosensitive material, optical waveguide and optical memory; etc. Heretofore, a method for producing polysilane is known wherein in the presence of alkali metals such as metallic sodium, dialkyldihalosilane or dichlorotetraalkyldisilane dissolved in a solvent as toluene is subjected to reductive coupling while stirring at a temperature over 100°C for a long period (J. Am. Chem. Soc., 103 (1981) 7352). However, the method has the following drawbacks: It requires to be performed under severe reaction conditions (e.g., heat must be applied for a prolonged time). It inevitably causes an inclusion of oxygen atoms in the main chain originated from an oxide film on the metal surface. And the use of alkali metal in large amount poses a serious safety problem where polysilane is industrially mass-produced. To overcome these drawbacks, several methods for producing polysilane under moderate conditions have been proposed, as described below. These methods are carried out by subjecting dihalosilane to electrochemical reduction at room temperature. Method (a) uses mercury or cadmium as anode, platinum, mercury or the like as cathode, tetra-n-butylammonium perchlorate as supporting electrolyte and 1,2-dimethoxyethane as solvent in an H-shaped cell equipped with a diaphragm (J. Organomet. Chem., 212 (1981) 155). Method (b) uses metals such as Al as electrode, quaternary ammonium salt such as tetra-n-butylammonium chloride as supporting electrolyte and 1,2-dimethoxyethane as solvent (Japanese Unexamined Patent Publication No. 3-104893). Method (c) uses metals such as Mg as electrode, lithium perchlorate as supporting electrolyte and tetrahydrofuran (THF) as solvent (J. Chem. Soc., Chem. Commun., 1160, 1990, Japanese Unexamined Patent Publication No. 4-331235, Japanese Unexamined Patent Publication No. 6-73180, Japanese Unexamined Patent Publication No. 6-98075). Method (d) uses Al as electrode, THF plus hexamethylphosphoric triamide (HMPA) as solvent and lithium chloride as supporting electrolyte (NATO ASI Ser. E, 206, 79-85, 1992). However, the method (a) has drawbacks in that the use of the metal (mercury or cadmium) as anode poses a serious problem in view of handling, safety and environmental pollution, and the resulting product is not a compound which can be actually identified as polysilane. The method (b) is not an efficient system for producing polysiiane since the degree of polymerization is merely about 20. When polysilane is applied to optoelectronic materials, it must be formed into a thin film. And in order to make an excellent thin film to be practically used as optoelectronic materials, polysilane must be dissolved in a solvent and have a degree of polymerization of at least 30, preferably over 50. Therefore as a matter of fact, the polysilane obtained pursuant to the method (b) cannot be applied to optoelectronic materials. Moreover, quaternary ammonium salt used as supporting electrolyte is so expensive that this method becomes very costly even if a desired polysilane was obtained. The method (c) provides an efficient electroreductive system affording a high yield of polysilane having high and uniform molecular weight, with an ease of handling and without concern for environmental pollution employing a safe metal anode. However, lithium perclorate used as supporting electrolyte is too expensive and must be handled so carefully. Hence there remains a need for developing a new system using as supporting electrolyte a compound which is inexpensive and easy to handle. The method (d) uses lithium chloride as supporting electrolyte that is inexpensive and easy to handle. However, when the solvent is THF alone, the solubility of lithium chloride is too low to carry the electric current and hence the reaction does not proceed. If HMPA or the like is added as solvent, the reaction can be run, but this solvent is suspected to be carcinogenic. Furthermore, the molecular weight of polysilane thus produced is merely 930 (degree of polymerization : approximately 8) and such a polysilane is quite unable to be cast into a thin film. It is a principal objective of the present invention to provide a new method for producing polysilanes in a high yield, whose molecular weight is uniform and high enough to be formed into an excellent thin film, with an ease of handling, safety and a low cost. This object has been solved by subjecting halosilane to electroreduction with using a specified metal anode, a specified solvent and a specified supporting electrolyte. Further, it has been found that when a specified chemical compound (hereinafter referred to as "current carrying aid") is added to the reaction system, current conductivity is so improved that the time required to produce polysilane is drastically shortened. The present invention provides a method for producing polysilane as described below: 1. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom) is subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a polysilane of the general formula (wherein R is as defined above corresponding to the starting material; n is 20 to 10000). 2. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom) is subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte, an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt as a current carrying aid and an aprotic solvent as solvent, thereby producing a polysilane of the general formula (wherein R is as defined above corresponding to the starting material; n is 20 to 10000). 3. A method for producing polysilane characterized in that a compound of the general formula (wherein R' represents an aromatic group, unsaturated aliphatic group, -(CH 2 ) m - group or -(CH 2 -CH 2 -O) m - group [m is 1 to 20]; R 1 , R 2, R 3 and R 4 are the same or different and represent a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X' represents a halogen atom) is subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a polymer of the following general formula containing Si-Si bonds in a main chain (wherein R', R 1 , R 2, R 3 and R 4 are as defined above; n is 20 to 10000). 4. A method for producing polysilane characterized in that a compound of the general formula (wherein R' represents an aromatic group, unsaturated aliphatic group, -(CH 2 ) m - group or -(CH 2 -CH 2 -O) m - group [m is 1 to 20]; R 1 , R 2, R 3 and R 4 are the same or different and represent a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X' represents a halogen atom) is subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte, an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt as a current carrying aid and an aprotic solvent as solvent, thereby producing a polymer of the following general formula containing Si-Si bonds in a main chain (wherein R', R 1 , R 2, R 3 and R 4 are as defined above; n is 20 to 10000). 5. A method for producing a polysilane characterized in that a trihalosilane of the general formula R''SiX'' 3 (wherein R'' represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X'' represents a halogen atom) is subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte, and an aprotic solvent as solvent, thereby producing a silicon network polymer of the general formula (R''Si) n (wherein R'' is as defined above corresponding to the starting material; n is 20 to 10000). 6. A method for producing a polysilane characterized in that a trihalosilane of the general formula R''SiX'' 3 (wherein R'' represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X'' represents a halogen atom) is subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte, an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt as current carrying aid and an aprotic solvent as solvent, thereby producing a silicon network polymer of the general formula (R''Si) n (wherein R'' is as defined above corresponding to the starting material; n is 20 to 10000). 7. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom) and a trihalosilane of the general formula R''SiX'' 3 (wherein R'' represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X'' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (wherein R is as defined above) and a structural unit of the general formula R''Si≡ (wherein R'' is as defined above). 8. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom) and a trihalosilane of the general formula R''SiX'' 3 (wherein R'' represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X'' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte, an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt as current carrying aid and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (wherein R is as defined above) and a structural unit of the general formula R''Si≡ (wherein R'' is as defined above). 9. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom) and a tetrahalosilane of the general formula SiX''' 4 (wherein X''' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (wherein R is as defined above) and a structural unit of the general formula 10. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom) and a tetrahalosilane of the general formula SiX''' 4 (wherein X''' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte, an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt as current carrying aid and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (wherein R is as defined above) and a structural unit of the general formula 11. A method for producing a polysilane characterized in that a trihalosilane of the general formula R''SiX'' 3 (wherein R'' represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X'' represents a halogen atom) and a tetrahalosilane of the general formula SiX''' 4 (wherein X''' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula R'''Si≡ (wherein R'' is as defined above) and a structural unit of the general formula 12. A method for producing a polysilane characterized in that a trihalosilane of the general formula R''SiX'' 3 (wherein R'' represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X'' represents a halogen atom) and a tetrahalosilane of the general formula SiX''' 4 (wherein X''' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte, an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt as current carrying aid and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula R''Si≡ (wherein R'' is as defined above) and a structural unit of the general formula 13. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom) and a trihalosilane of the general formula R''SiX'' 3 (wherein R'' represents a hydrogen, alkyl group, aryl group, alkoxy group, or amino group, preferably an alkyl group, aryl group, alkoxy group or amino group; X'' represents a halogen atom) and a tetrahalosilane of the general formula SiX''' 4 (wherein X''' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (wherein R is as defined above), a structural unit of the general formula R''Si≡ (wherein R'' is as defined above) and a structural unit of the general formula 14. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom), a trihalosilane of the general formula R''SiX'' 3 (wherein R'' represents a hydrogen, alkyl group, aryl group, alkoxy group, or amino group, preferably an alkyl group, aryl group, alkoxy group or amino group; X'' represents a halogen atom) and a tetrahalosilane of the general formula SiX''' 4 (wherein X''' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte, an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt as current carrying aid and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (wherein R is as defined above), a structural unit of the general formula R''Si≡ (wherein R'' is as defined above) and a structural unit of the general formula Figure 1 is an oblique view of a basket-like container or a basket used in the method of the present invention which contains balls made of Mg or an Mg alloy constituting the anode. Figure 2 is a cross sectional view illustrating an electrolytic cell which takes the shape of a pencil sharpener usable in the method of the present invention. Figure 3 is a cross sectional view schematically showing an electrolytic cell in the shape of a pencil sharpener used in the Examples of the present invention. Figure 4 is a cross sectional view schematically showing an electrolytic cell employing magnesium balls placed in a basket as a consumable anode. The present invention is illustrated in detail below. 1. The 1st embodiment of the present application In the 1st embodiment of the present application, halosilane used as the starting material is a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom). In the 1st embodiment of the present application, the reaction product is a polysilane of the general formula (wherein R is as defined above corresponding to the starting material; n is 20 to 10000). In the dihalosilane represented by the general formula (1), m is 1 to 3, and a hydrogen atom, amino group and organic substituents (alkyl group, aryl group, alkoxy group or amino group) which are represented by R are the same or at least two of them are different. Stated more specifically, two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3. Preferred compounds represented by the general formula (1) are those in which m is 1 or 2. Examples of the alkyl group are those having 1 to 10 carbon atoms, among which those of 1 to 6 carbon atoms are preferable. Examples of the aryl group include, for example, phenyl group, phenyl group substituted with at least one alkyl group of 1 to 6 carbon atoms, p-alkoxyphenyl group, naphthyl group, etc. Examples of the alkoxy group are those having 1 to 10 carbon atoms, among which those of 1 to 6 carbon atoms are preferred. When the Rs are an amino group and organic substituents, at least one of the hydrogen atoms may be substituted with another functional group such as alkyl, aryl or alkoxy group. Examples of the functional group are those as stated above. In the general formula (1), X represents a halogen atom (Cl, F, Br and I). Cl is more preferable as halogen atom. In the method of the 1st embodiment of the present application, a dihalosilane of the general formula (1) is usable singly or at least two of them can be used in mixture. A dihalosilane of the highest purity is preferably used. As a preliminary treatment for use, a liquid dihalosilane is preferably dried over calcium hydride and then distilled, and a solid dihalosilane is preferably purified by recrystallization. Prior to the reaction, the dihalosilane is dissolved in a solvent. Examples of useful solvents include a wide range of aprotic soivents. Specific examples are the ether solvents such as tetrahydrofuran, 1,2-dimethoxyethane, propylene carbonate, acetonitrile, dimethylformamide, dimethylsulfoxide, bis(2-methoxyethyl)ether, p-dioxane, methylene chloride, etc. These solvents are usable singly or at least two of them can be used in mixture. Among the solvents, more preferable are tetrahydrofuran and 1,2-dimethoxyethane. Too low a concentration of the dihalosilane in the solvent causes reduction of the current efficiency. Contrarily, too high a concentration thereof may deteriorate the solubility of the supporting electrolyte. Accordingly a suitable concentration of the dihalosilane in the solvent is about 0.05 to about 20 mol/l, preferably about 0.2 to about 15 mol/l, more preferably about 0.3 to about 13 mol/l. Examples of supporting electrolytes usable in the 1st embodiment of the present application are such inexpensive lithium salts as LiCl, LiNO 3 , Li 2 CO 3 , etc. These supporting electrolytes are usable singly or at least two of them can be used in mixture. Among the examples of supporting electrolytes, LiCl is the most preferable. In case that the concentration of the supporting electrolyte in the solvent is too low, the liquid is almost unable to conduct electricity and the reaction does not proceed. In case that the concentration is too high, an excessive amount of lithium is deposited by reduction, which leads to the cleavage of Si-Si bonds in the main chain, thereby reducing the molecular weight of the desired polysilane. Hence the concentration of the supporting electrolyte in the solvent is preferably about 0.05 to about 5 mol/l, more preferably is about 0.1 to about 3 mol/l and most preferably about 0.15 to about 2.0 mol/l. In the 1st embodiment of the present application, a usable anode is Mg or alloys principally containing Mg. Alloys containing Mg as the main component may contain about 3 to about 10% of Al. Examples of Mg alloys include, for example, 1st species (MgA1), 2nd species (MGA2) generally called "AZ63", 3rd species (MGA3), etc., all of which are specified in the Japanese Industrial Standards H6125-1961. Cathode materials are not limited insofar as electric current can flow. Examples of cathode materials are stainless steels such as SUS 304, SUS 316, etc.; various metals such as Mg, Cu, Zn, Al, Ni, Co, etc.; and carbon materials. The electrode shape is not limited insofar as electric current can stably flow. Preferred examples of the electrode shape are bar, plate, tube, cone, disc, ball or pellet contained in a basket, coiled plate, etc. If desired, the oxide film is removed from the electrode surface prior to the reaction. The removal of an oxide film from the electrode can be performed by any method, as by washing the electrode with an acid and subsequently washing it with ethanol and ether and then drying it under reduced pressure, by polishing the electrode in a nitrogen atmosphere, or by conducting a combination of the above methods, etc. The 1st embodiment of the present application can be carried out in various manners, among which the following two processes are preferable: Process (a) comprising charging the dihalosilane of the general formula (1), the supporting electrolyte and the solvent into a static electrolytic cell with an anode and a cathode placed therein; subsequently applying a specific amount of electricity, preferably with stirring by mechanical or magnetic means; and thereby running the electrochemical reaction. Process (b), which are performed in a flow-type electrolytic cell system composed of an electrolytic cell with an anode and a cathode installed therein, an electrolyte tank, a pump, a pipe and so on, comprising charging the reaction solution consisting of the dihalosilane, the supporting electrolyte and the solvent into the electrolyte tank; circulating the solution by pumping through the electrolytic cell system; subsequently applying a specific amount of electricity; and thereby undergoing the electrochemical reaction. The structure and shape of the electrolytic cell are not limited, but a preferred example is a structure which enables to supply easily the anode-constituting material which dissolves from the anode into the electrolyte and is gradually consumed as the reaction progresses. As shown in Figure 1, the cell may have as an anode a basket or a basket-form container 1 containing small balls or pellets 3 and additional balls or pellets can be supplied from upside as the anode consumption progresses. As outlined in Figure 2, usable also is a structure of the electrolytic cell designed to contain a layer of anode blocks 7 within a cathode sheet 5, pursuant to the example of "pencil sharpener form electrolytic cell" disclosed in the Japanese Unexamined Patent Publication No. 62-56589. Such electrolytic cells, devised to continuously supply anode elements, can dispense with exchange procedure of consumable electrodes per a reaction cycle or per several reaction cycles and therefore allows repeating reaction cycles for a long period of time. Thus the method lowers the expenses needed for exchanging anode, thereby reducing the cost for producing polysilanes. The reactor or the reaction system preferably has a dry atmosphere, more preferably an atmosphere of dry nitrogen or inert gas, even more preferably an atmosphere consisting of deoxidized dry nitrogen or inert gas. An electric current is applied usually in an amount of over about 1 F/mol based on halogen content of the dihalosilane, and the molecular weight of the product can be regulated through controlling the amount of electricity applied. After the polysilane is removed out of the system obtained by applying about 0.1 F/mol or more of electricity, the residual starting dihalosilane can be recovered and still reused. Since the reaction period varies depending on the amount of the starting dihalosilane and the resistance of electrolytic solution associated with the amount of supporting electrolyte or the like, the reaction period may be determined suitably. The reaction temperature is preferably in the range from -20°C to the boiling point of the solvent used, more preferably from -5 to 30°C, most preferably from 0 to 25°C. The 1st embodiment of the present application may employ or can dispense with a diaphragm that is an essential element in the conventional electrode reduction reaction. Without the diaphragm, the 1st embodiment of the present application is easy to handle and it offers additional advantages in a practical use. 2. The 2nd embodiment of the present application The 2nd embodiment of the present application is not substantially different from the 1st embodiment of the present application except that in order to undergo the electrochemical reaction of the present invention efficiently, in addition to the supporting electrolyte the current carrying aid is used to improve the current conductivity. Among the examples of current carrying aids, preferred are Al salts such as AlCl 3 , Al(OEt) 3 , etc; Fe salts such as FeCl 2 , FeCl 3 , etc.; Mg salts such as MgCl 2 , etc.; Zn salts such as ZnCl 2 , etc.; Sn salts such as SnCl 2 , etc.; Co salts such as CoCl 2 , etc.; Pd salts such as PdCl 2 , etc.; V salts such as VCl 3 , etc.; Cu salts such as CuCl 2 , etc.; Ca salts such as CaCl 2 , etc. These current carrying aids are usable singly or at least two of them can be used in mixture. Among the examples of current carrying aids given above, more preferred are AlCl 3 , FeCl 2 , FeCl 3, CoCl 2 , CuCl 2, etc. Too low a concentration of the current carrying aid fails to ensure a satisfactory current passage. Contrarily, at too high a concentration, the aid itself is reduced and fails to participate in the reaction. A suitable concentration of current carrying aid in the solvent is usually about 0.01 to about 6 mol/l, more preferably about 0.03 to about 4 mol/l, most preferably about 0.05 to about 3 mol/l. The addition of such current carrying aids reduces the reaction period drastically and permits efficient production of polysilane. The reaction period can be reduced depending on the concentration of the current carrying aid as well as the concentrations of the supporting electrolyte and the starting dihalosilane. Usually the time needed to complete the reaction is reduced by 1/4 to 3/4, compared with the reaction condition that does not employ a current carrying aid. 3. The 3rd embodiment of the present application In the 3rd embodiment of the present application the halosilane used as the starting material is a compound of the general formula (wherein R' represents an aromatic group, unsaturated aliphatic group, -(CH 2 ) m - group or -(CH 2 -CH 2 -O) m - group [m is 1 to 20]; R 1 , R 2, R 3 and R 4 are the same or different and represent a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X' represents a halogen atom). The reaction product of the 3rd embodiment of the present application is a polymer of the following general formula containing Si-Si bonds in a main chain (wherein R', R 1 , R 2, R 3 and R 4 are as defined above; n is 20 to 10000). The 3rd embodiment of the present application is not substantially different from the 1st embodiment of the present application except that the starting halosilane is a different kind of halosilane and correspondingly the reaction product obtained is a different kind of polymer (which contains Si-Si bonds in a main chain). According to the 3rd embodiment of the present application, a polysilane of the general formula (4) is produced by subjecting the starting halosilane of the general formula (3) to an electrochemical reaction as performed by by the 1st embodiment of the present application. In the general formula (3), the examples of structural components represented by R are the following: a) divalent aromatic group such as phenylene, naphthalene, biphenylene or a compound represented by the general formula (wherein Y represents O, S, Se, Te or N); b) divalent unsaturated aliphatic group such as ethenylene, ethynylene; c) -(CH 2 ) m - group [m is 1 to 20]; d) -(CH 2 -CH 2 -O) m - group [m is 1 to 20]. In the general formula (3), hydrogen atom, amino group and organic substituents (alkyl group, aryl group, alkoxy group) represented by R 1 , R 2, R 3 and R 4 are each different or at least two of them are the same. Examples of the alkyl groups as organic substituents are those having 1 to 10 carbon atoms, among which those of 1 to 6 carbon atoms are preferable. Examples of the aryl group include, for example, phenyl group, phenyl group substituted with at least one alkyl group of 1 to 6 carbon atoms, p-alkoxyphenyl group, naphthyl group, etc. Examples of the alkoxy group are those having 1 to 10 carbon atoms, among which those of 1 to 6 carbon atoms are more preferred. When R 1 , R 2, R 3 and R 4 are amino group and organic substituents, at least one of the hydrogen atoms may be substituted with other functional group such as alkyl, aryl or alkoxy group. In the halosilane of the general formula (3), X represents a halogen atom (Cl, F, Br and I). Cl is more preferable as halogen atom. In the method of the 3rd embodiment of the present application, halosilanes of the general formula (3) are usable singly or at least two of them can be used in mixture. A halosilane of the highest purity is preferably used. As a preliminary treatment for use, a liquid halosilane is preferably dried over calcium hydride and then distilled, and a solid halosilane is preferably purified by recrystallization. 4. The 4th embodiment of the present application The 4th embodiment of the present application is not substantially different from the 3rd embodiment of the present application except that in order to run the electrochemical reaction of the present invention efficiently, in addition to the supporting electrolyte a current carrying aid is employed to improve the current conductivity. Species and concentrations of the current carrying aids may be the same as that employed in the 2nd embodiment of the present application. 5. The 5th embodiment of the present application In the 5th embodiment of the present application, the starting material is a trihalosilane of the general formula R''SiX'' 3 (wherein R'' represents a hydrogen, alkyl group, aryl group, alkoxy group, or amino group, preferably an alkyl group, aryl group, alkoxy group or amino group; X'' represents a halogen atom). In the 5th embodiment of the present application, the reaction product is a silicon network polymer of the general formula (R''Si) n (wherein R'' is as defined above corresponding to the starting material; n is 20 to 10000). The 5th embodiment of the present application is not substantially different from the 1st embodiment of the present application except that the starting material used is a trihalosilane of the general formula (5) and correspondingly the polymer produced is a silicon network polymer of the general formula (6). In the trihalosilane of the general formula (5), examples of the alkyl group are those having 1 to 10 carbon atoms, among which those of 1 to 6 carbon atoms are preferable. Examples of the aryl group include, for example, phenyl group, phenyl group substituted with at least one alkyl group of 1 to 6 carbon atoms, p-alkoxyphenyl group, naphthyl group, etc. Examples of the alkoxy group are those having 1 to 10 carbon atoms, among which those of 1 to 6 carbon atoms are preferred. When Rs are an amino group and organic substituents (alkyl, aryl or alkoxy group), at least one of hydrogen atoms may be further substituted with other functional group such as alkyl, aryl or alkoxy group. In the general formula (5), X represents a halogen atom (Cl, F, Br and I). Cl is more preferable as halogen atom. In the method of the 5th embodiment of the present application, trihalosilanes of the general formula (5) are usable singly or at least two of them can be used in mixture. A trihalosilane of the highest purity is preferably used. As a preliminary treatment for use, a liquid trihalosilane is preferably dried over calcium hydride and then distilled, and a solid trihalosilane is preferably purified by recrystallization. 6. The 6th embodiment of the present application The 6th embodiment of the present application is not substantially different from the 5th embodiment of the present application except that in order to proceed the electrochemical reaction of the present invention efficiently, in addition to the supporting electrolyte a current carrying aid is used to improve the current conductivity. Species and concentrations of the current carrying aids may be the same as that used in the 2nd embodiment of the present application. 7. The 7th embodiment of the present application In the 7th embodiment of the present application, the starting materials are a dihalosilane of the above presented general formula (1) and a trihalosilane of the above presented general formula (5). The reaction product of the 7th embodiment of the present application is a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (wherein R is as defined above) and a structural unit of the general formula R''Si≡ The 7th embodiment of the present application is not substantially different from the 1st embodiment of the present application except that the starting material is a combination of at least one species of dihalosilanes of the general formula (1) and at least one species of trihalosilanes of the general formula (5) and correspondingly the polymer obtained is a network polymer composed of a structural unit of the general formula (7) and a structural unit of the general formula (8). In the 7th embodiment of the present application, the mixing proportions of at least one species of dihalosilanes of the general formula (1) and at least one species of trihalosilanes of the general formula (5) are preferably dihalosilane (1) : trihalosilane (5) = 1000 : 1 to 50000. Within the above mixing proportions, the combined materials suitably dissolve in the organic solvent and the polymer obtained can preferably exhibit the conjugated characteristics performed by both polymers, i.e., polymer having straight chain structure and silicon network polymer having network structure. The 7th embodiment of the present application provides a network polymer containing Si-Si bonds in the backbone structure, usually having a weight average molecular weight of about 2000 to about 1000000. 8. The 8th embodiment of the present application The 8th embodiment of the present application is not substantially different from the 7th embodiment of the present application except that in order to run the electrochemical reaction of the present invention efficiently, in addition to the supporting electrolyte a current carrying aid is employed to improve the current conductivity. Species and concentrations of current carrying aids may be the same as that employed in the 2nd embodiment of the present application. The 8th embodiment of the present application provides a network polymer containing Si-Si bonds in the backbone structure, usually having a weight average molecular weight of about 2000 to about 1000000. 9. The 9th embodiment of the present application In the 9th embodiment of the present application, the starting materials are a dihalosilane of the above presented general formula (1) and a tetrahalosilane of the general formula SiX''' 4 (wherein X''' represents halogen atom). The reaction product of the 9th embodiment of the present application is a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (7) and a structural unit of the general formula The 9th embodiment of the present application is not substantially different from the 1st embodiment of the present application except that the starting material is a combination of at least one species of dihalosilanes of the general formula (1) and at least one species of tetrahalosilanes of the general formula (9) and correspondingly the polymer afforded is a network polymer composed of a structural unit of the general formula (7) and a structural unit of the general formula (10). In the 9th embodiment of the present application, the mixing proportions of at least one species of dihalosilanes of the general formula (1) and at least one species of tetrahalosilanes of the general formula (9) are preferably dihalosilane (1) : tetrahalosilane (9) = 1000 : 1 to 1000. Within the above mixing proportions, the combined materials suitably dissolve in the organic solvent and the polymer afforded can preferably exhibit the conjugated characteristics performed by both polymers, i.e., polymer having straight chain structure and silicon network polymer having network structure. The 9th embodiment of the present application provides a network polymer containing Si-Si bonds in the backbone structure, usually having a weight average molecular weight of about 2000 to about 1000000. 10. The 10th embodiment of the present application The 10th embodiment of the present application is not substantially different from the 9th embodiment of the present application except that in order to undergo the electrochemical reaction of the present invention efficiently, in addition to the supporting electrolyte a current carrying aid is used to improve the current conductivity. Species and concentrations of current carrying aids may be the same as that used in the 2nd embodiment of the present application. The 10th embodiment of the present application provides a network polymer containing Si-Si bonds in the backbone structure, usually having a weight average molecular weight of about 2000 to about 1000000. 11. The 11th embodiment of the present application In the 11th embodiment of the present application, the starting materials are a trihalosilane of the above presented general formula (5) and a tetrahalosilane of the above presented general formula (9). The reaction product of the 11th embodiment of the present application is a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (8) and a structural unit of the general formula (10). The 11th embodiment of the present application is not substantially different from the 1st embodiment of the present application except that the starting material is a combination of at least one species of trihalosilanes of the general formula (5) and at least one species of tetrahalosilanes of the general formula (9) and correspondingly the polymer yielded is a network polymer composed of a structural unit of the general formula (8) and a structural unit of the general formula (10). In the 11th embodiment of the present application, the mixing proportions of at least one species of trihalosilanes of the general formula (5) and at least one species of tetrahalosilanes of the general formula (9) are preferably trihalosilane (5) : tetrahalosilane (9) = 1000 : 1 to 100. Within the above mixing proportions, the combined materials suitably dissolve in the organic solvent and the polymer yielded can preferably exhibit the conjugated characteristics performed by both polymers, i.e., polymer having straight chain structure and silicon network polymer having network structure. The 11th embodiment of the present application provides a network polymer containing Si-Si bonds in the backbone structure, usually having a weight average molecular weight of about 2000 to about 1000000. 12. The 12th embodiment of the present application The 12th embodiment of the present application is not substantially different from the 11th embodiment of the present application except that in order to proceed the electrochemical reaction of the present invention efficiently, in addition to the supporting electrolyte a current carrying aid is employed to improve the current conductivity. Species and concentrations of current carrying aids may be the same as that employed in the 2nd embodiment of the present application. The 12th embodiment of the present application provides a network polymer containing Si-Si bonds in the backbone structure, usually having a weight average molecular weight of about 2000 to about 1000000. 13. The 13th embodiment of the present application In the 13th embodiment of the present application, the starting materials are a dihalosilane of the above presented general formula (1), a trihalosilane of the above presented general formula (5) and a tetrahalosilane of the above presented general formula (9). The reaction product of the 13th embodiment of the present application is a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (7), a structural unit of the general formula (8) and a structural unit of the general formula (10). The 13th embodiment of the present application is not substantially different from the 1st embodiment of the present application except that the starting material is a combination of at least one species of dihalosilanes of the general formula (1), at least one species of trihalosilanes of the general formula (5) and at least one species of tetrahalosilanes of the general formula (9) and correspondingly the polymer afforded is a network polymer composed of a structural unit of the general formula (7), a structural unit of the general formula (8) and a structural unit of the general formula (10). In the 13th embodiment of the present application, the mixing proportions of at least one species of dihalosilanes of the general formula (1), at least one species of trihalosilanes of the general formula (5) and at least one species of tetrahalosilanes of the general formula (9) are preferably dihalosilane (1) : trihalosilane (5) : tetrahalosilane (9) = 1000 : 0.5 to 800 : 0.5 to 100. Within the above mixing proportions, the combined materials suitably dissolve in the organic solvent and the produced polymer can preferably exhibit the conjugated characteristics performed by both polymers, i.e., polymer having straight chain structure and silicon network polymer having network structure. The 13th embodiment of the present application provides a network polymer containing Si-Si bonds in the backbone structure, usually having a weight average molecular weight of about 2000 to about 1000000. 14. The 14th embodiment of the present application The 14th embodiment of the present application is not substantially different from the 13th embodiment of the present application except that in order to run the electrochemical reaction of the present invention efficiently, in addition to the supporting electrolyte a current carrying aid is employed to improve the current conductivity. Species and concentrations of current carrying aids may be the same as that employed in the 2nd embodiment of the present application. The 14th embodiment of the present application provides a network polymer containing Si-Si bonds in the backbone structure, usually having a weight average molecular weight of about 2000 to about 1000000. The present invention achieves remarkably improved effects as described below. (a) The present invention affords a high yield of polysilanes having a uniform molecular weight and a degree of polymerization of over 30. (b) The present invention provides polysilanes safely without producing environmental pollution since there is no need for using dangerous metals or carcinogenic solvents. (c) The present invention produces polysilanes with low costs since expensive supporting electrolytes are not used. (d) When a current carrying aid is employed, the present invention produces polysilanes efficiently in a shortened reaction period since the aid ensures good current passage during the reaction. In case of using the aid, the reaction period can be drastically shortened by 1/4 to 3/4, compared to the condition where the current carrying aid is not employed. (e) In case that AlCl 3 or the like is used as current carrying aid, the electrolyte does not require neutralization after the reaction is completed, which offers an ease in the post-treatment. EXAMPLES The following examples are intended to illustrate the present invention in further detail. Example 1 0.4 g of anhydrous lithium chloride (LiCl) was fed into a 30 ml - volume three-necked flask (hereinafter referred to as "reactor") equipped with a three-way cock, a Mg anode (1 cm in diameter x 5 cm) and a stainless steel (SUS 304) cathode (1 cm x 1 cm x 5 cm). The reactor was heated to 50°C under reduced pressure of 1 mmHg, thereby drying LiCl. Deoxidized dry nitrogen was charged into the reactor. Then 15 ml of tetrahydrofuran preliminarily dried over sodium-benzophenone ketyl was added. 1.6 ml (10 mmol) of methylphenyldichlorosilane preliminarily purified by distillation was added with a syringe. While the reaction mixture was stirred with a magnetic stirrer and the reactor was maintained at room temperature using a water bath, an electric current was applied from a constant-voltage source. The current was applied for about 31 hours to pass 1.8 F/mol of electricity based on the chlorine content of methylphenyldichlorosilane. After completion of the reaction, 20 ml of a 1 N solution of hydrochloric acid was added to the reaction solution, followed by the addition of 80 ml of distilled water. The resulting mixture was extracted with 100 ml of ether and subsequently reprecipitated by adding 80 ml of poor solvent ethanol and 4 ml of good solvent tetrahydrofuran, to thereby afford a product. The result showed that methylphenylpolysilane with a weight average molecular weight of 12200 (average degree of polymerization : approximately 102) was obtained in a yield of 51.6%. Methylphenylpolysilane thus obtained was dissolved into toluene to prepare a solution (the solute content was 10 wt%). From the solution thus prepared, 0.2 ml was taken and applied onto a glass plate by the casting method. Then the plate was dried at 50°C under reduced pressure to give a thin film of polysilane. This thin film had a flat surface and good transparency without turbidity, crack and undulation, thereby meeting the requirements for optoelectronic materials. Example 2 An electrochemical reaction was conducted in the same manner as in Example 1 with the exception that as dihalosilane of the general formula (1), 1.9 ml of cyclohexylmethyldichlorosilane purified by distillation was used. After completion of the reaction, 20 ml of a 1 N solution of hydrochloric acid was added to the reaction solution, followed by the addition of 80 ml of distilled water. The resulting mixture was extracted with 100 ml of n-hexane and subsequently reprecipitated by adding 80 ml of poor solvent acetone and 4 ml of good solvent n-hexane, thereby giving a product. The result showed that cyclohexylmethylpolysilane with a weight average molecular weight of 11500 (average degree of polymerization : approximately 91) was obtained in a yield of 61.2%. Example 3 An electrochemical reaction was conducted in the same manner as in Example 1 with the exception that as dihalosilane of the general formula (1), 2.0 ml of n-hexylmethyldichlorosilane purified by distillation was used. After completion of the reaction, 20 ml of a 1 N solution of hydrochloric acid was added to the reaction solution, followed by the addition of 80 ml of distilled water. The resulting mixture was extracted with 100 ml of ether and subsequently reprecipitated by adding 80 ml of poor solvent acetone and 4 ml of good solvent n-hexane, to thereby yield a product. The result showed that n-hexylmethylpolysilane with a weight average molecular weight of 10500 (average degree of polymerization : approximately 82) was obtained in a yield of 53.2%. Example 4 An electrochemical reaction was conducted in the same manner as in Example 1 with the exception that as dihalosilane of the general formula (1), 1.5 ml of methoxymethyldichlorosilane purified by distillation was used. After completion of the reaction, 20 ml of a 1 N solution of hydrochloric acid was added to the reaction solution, followed by the addition of 80 ml of distilled water. The resulting mixture was extracted with 100 ml of ether and subsequently reprecipitated by adding 80 ml of poor solvent ethanol and 4 ml of good solvent tetrahydrofuran (THF), thereby affording a product. The result showed that methoxymethylpolysilane with a weight average molecular weight of 3900 (average degree of polymerization : approximately 73) was obtained in a yield of 23%. Example 5 An electrochemical reaction was conducted in the same manner as in Example 1 with the exception that starting dihalosilane of the general formula (1) was 1.9 ml of p-anisylmethyldichlorosilane purified by distillation. After completion of the reaction, 20 ml of a 1 N solution of hydrochloric acid was added to the reaction solution, followed by the addition of 80 ml of distilled water. The resulting mixture was extracted with 100 ml of ether and subsequently reprecipitated by adding 80 ml of poor solvent ethanol and 4 ml of good solvent THF, thereby giving a product. The result showed that p-anisylmethylpolysilane with a weight average molecular weight of 9900 (average degree of polymerization : approximately 66) was obtained in a yield of 51.1%. Example 6 An electrochemical reaction was conducted in the same manner as in Example 1 with the exception that starting dihalosilane of the general formula (1) was 1.5 ml of 1,2-dichloro-1,1,2-trimethyl-2-phenyldisilane purified by distillation. After completion of the reaction, 20 ml of a 1 N solution of hydrochloric acid was added to the reaction solution, followed by the addition of 80 ml of distilled water. The resulting mixture was extracted with 100 ml of ether and subsequently reprecipitated by adding 80 ml of poor solvent ethanol and 4 ml of good solvent THF, thereby affording a product. A corresponding polysilane having a high molecular weight was obtained in a high yield. Example 7 An electrochemical reaction was conducted in the same manner as in Example 1 with the exception that as starting dihalosilane of the general formula (1), methylphenyldibromosilane was used. Methylphenylpolysilane was obtained in a yield of 42.1% (average degree of polymerization : approximately 85) with a weight average molecular weight of 10200. Example 8 Methylphenyldichlorosilane was subjected to electrochemical reaction in the same manner as in Example 1 with the exception that Mg alloy (Mg 90%, Al 9%, Zn 1%; 1 cm x 1 cm x 5 cm) was used as anode. Methylphenylpolysilane was given in a yield of 55.3% (average degree of polymerization : approximately 128) with a weight average molecular weight of 15300. Example 9 An electrochemical reaction using methylphenyldichlorosilane as starting material was conducted in the same manner as in Example 1 with the exception that the cathode was glassy carbon (1 cm x 0.1 cm x 5 cm). Methylphenylpolysilane having a high molecular weight was afforded in a high yield. Example 10 Methylphenyldichlorosilane was subjected to electrochemical reaction in the same manner as in Example 1 with the exception that 0.65 g of lithium nitrate was used as supporting electrolyte. Methylphenylpolysilane having a high molecular weight was obtained in a high yield. Example 11 An electrochemical reaction using methylphenyldichlorosilane as starting material was conducted in the same manner as Example 1 with the exception.that 0.70 g of lithium carbonate was used as supporting electrolyte. Methylphenylpolysilane having a high molecular weight was afforded in a high yield. Example 12 0.40 g of anhydrous lithium chloride (LiCl) and 0.25 g of anhydrous aluminum chloride (AlCl 3 ) were fed into a 30 ml - volume three-necked flask (hereinafter referred to as "reactor") equipped with a three-way cock, a Mg anode (1 cm in diameter x 5 cm) and a stainless steel (SUS 316) cathode (1 cm x 1 cm x 5 cm). The reactor was heated to 50°C under reduced pressure of 1 mmHg, to thereby dry LiCl and AlCl 3 . Deoxidized dry nitrogen was charged into the reactor. Then 15 ml of tetrahydrofuran preliminarily dried over sodiumbenzophenone ketyl was added. 1.6 ml (10 mmol) of methylphenyldichlorosilane preliminarily purified by distillation was added with a syringe. While the reaction mixture was stirred with a magnetic stirrer and the reactor was maintained at room temperature using a water bath, an electric current was applied from a constant-voltage source. The current was applied for about 10 hours to pass 1.8 F/mol of electricity based on the chlorine content of methylphenyldichlorosilane. After completion of the reaction, 20 ml of a 1 N solution of hydrochloric acid was added to the reaction solution, followed by the addition of 80 ml of distilled water. The resulting mixture was extracted with 100 ml of ether and subsequently reprecipitated by adding 80 ml of poor solvent ethanol and 4 ml of good solvent tetrahydrofuran, thereby yielding a product. The result showed that methylphenylpolysilane with a weight average molecular weight of 17100 (average degree of polymerization : approximately 143) was given in a yield of 54.8%. Example 13 Methylphenyldichlorosilane was subjected to electrochemical reaction in the same manner as in Example 12 with the exception that the amount of LiCl used was; 0.8 g. It took about 9 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. As a result, methylphenylpolysilane was obtained in a yield of 40.6% (average degree of polymerization : approximately 203) with a weight average molecular weight of 24300. Example 14 An electrochemical reaction using methylphenyldichlorosilane as starting material was conducted in the same manner as in Example 12 with the exception that 0.18 g of MgCl 2 was used as current carrying aid. It took about 15 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. The result showed that methylphenylpolysilane was obtained in a yield of 47.5% (average degree of polymerization : approximately 83) with a weight average molecular weight of 9900. Example 15 Methylphenyldichlorosilane was subjected to electrochemical reaction in the same manner as in Example 12 with the exception that 0.26 g of ZnCl 2 was used as current carrying aid. It took about 17 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. As a result, methylphenylpolysilane was obtained in a yield of 43.1% (average degree of polymerization : approximately 88) with a weight average molecular weight of 10500. Example 16 An electrochemical reaction using methylphenyldichlorosilane as starting material was conducted in the same manner as in Example 12 with the exception that current carrying aid was 0.52 g of CaCl 2 . It took about 20 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. Methylphenylpolysilane was given in a yield of 49.0% (average degree of polymerization : approximately 71) with a weight average molecular weight of 8550. Example 17 Methylphenyldichlorosilane was subjected to electrochemical reaction in the same manner as in Example 12 with the exception that the solvent was 15 ml of DME preliminarily dried over sodium-benzophenone ketyl. Methylphenylpolysilane was obtained in a yield of 39.5% (average degree of polymerization : approximately 63) with a weight average molecular weight of 7600. Example 18 An electrochemical reaction was conducted in the same manner as in Example 12 with the exception that 6.4 ml of methylphenyldichlorosilane purified by distillation was used as starting dihalosilane. Methylphenylpolysilane was afforded in a yield of 48.5% (average degree of polymerization : approximately 332) with a weight average molecular weight of 39800. Example 19 An electrochemical reaction was conducted in the same manner as in Example 12 with the exception that 1.3 ml of 1,4-bis(methylphenylchlorosilyl) benzene purified by distillation was used as starting halosilane. Poly[p-(disilanilene)phenylene] was produced in a yield of 33.9% (average degree of polymerization : approximately 41) with a weight average molecular weight of 11300. Example 20 An electrochemical reaction was conducted in the same manner as in Example 12 with the exception that phenyltrichlorosilane purified by distillation was used as starting halosilane. Electricity was passed to reach 2.0 F/mol based on the chlorine content of the starting material. As a result, a silicon network polymer was produced in a yield of 41.5% (average degree of polymerization : approximately 124) with a weight average molecular weight of 13000. Example 21 An electrochemical reaction was conducted in the same manner as in Example 12 with the exception that cyclohexyltrichlorosilane purified by distillation was used as starting halosilane. Electricity was passed to reach 2.0 F/mol based on the chlorine content of the starting material. As a result, a silicon network polymer was afforded in a yield of 62.3% (average degree of polymerization : approximately 102) with a weight average molecular weight of 11300. Example 22 An electrochemical reaction was conducted in the same manner as in Example 12 with the exception that starting halosilane was a combination of 45 ml of methylphenyldichlorosilane and 0.16 ml of phenyltrichlorosilane, both preliminarily purified by distillation. Electricity was passed to reach 2.0 F/mol based on the chlorine content of the starting materials. The result showed that a network polymer was obtained containing Si-Si bonds in the backbone structure having a weight average molecular weight of 8050 in a yield of 61.5%. Example 23 An electrochemical reaction was conducted in the same manner as in Example 12 with the exception that a combination of 1.13 ml of methylphenyldichlorosilane and 0.34 ml of tetrachlorosilane, both preliminarily purified by distillation, was used as starting material. Electricity was passed to reach 2.0 F/mol based on the chlorine content of the starting materials. The result showed that a network polymer containing Si-Si bonds in the backbone structure having a weight average molecular weight of 7700 was produced in a yield of 38.5%. Example 24 An electrochemical reaction was conducted in the same manner as in Example 12 with the exception that starting material was a combination of 1.60 ml of phenyltrichlorosilane and 0.06 ml of tetrachlorosilane, both preliminarily purified by distillation. Electricity was passed to reach 2.0 F/mol based on the chlorine content of the starting materials. As a result, a network polymer was obtained containing Si-Si bonds in the backbone structure having a weight average molecular weight of 7200 in a yield of 34.0%. Example 25 An electrochemical reaction was conducted in the same manner as in Example 12 with the exception that a combination of 1.60 ml of methylphenyldichlorosilane, 0.16 ml of phenyltrichlorosilane and 0.06 ml of tetrachlorosilane, all preliminarily purified by distillation, was used as starting halosilane. Electricity was passed to reach 2.0 F/mol based on the chlorine content of the starting materials. The result showed that a network polymer containing Si-Si bonds in the backbone structure having weight average molecular weight of 8100 was given in a yield of 52.2%. Example 26 Methylphenyldichlorosilane was subjected to electrochemical reaction in the same manner as in Example 12 with the exception that 0.24 g of FeCl 2 was used as current carrying aid. It took about 11 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. As a result, methylphenylpolysilane was obtained in a yield of 60.5% (average degree of polymerization : approximately 186) with a weight average molecular weight of 22300. Example 27 An electrochemical reaction using methylphenyldichlorosilane as starting material was conducted in the same manner as in Example 12 with the exception that current carrying aid was 0.31 g of FeCl 3 . It took about 12 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. As a result, methylphenylpolysilane was obtained in a yield of 43.7% (average degree of polymerization : approximately 125) with a weight average molecular weight of 15000. Example 28 Methylphenyldichlorosilane was subjected to electrochemical reaction in the same manner as in Example 12 with the exception that 0.49 g of SnCl 2 was used as current carrying aid. It took about 22 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. As a result, methylphenylpolysilane was obtained in a yield of 56.2% (average degree of polymerization : approximately 76) with a weight average molecular weight of 9100. Example 29 An electrochemical reaction was conducted in the same manner as in Example 12 with the exception that 0.24 g of CoCl 2 was used as current carrying aid. It took about 17 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. The result showed that methylphenylpolysilane with a weight average molecular weight of 13000 (average degree of polymerization : approximately 108) was given in a yield of 61.8%. Example 30 An electrochemical reaction using methylphenyldichlorosilane as starting material was conducted in the same manner as in Example 12 with the exception.that current carrying aid was 0.33 g of PdCl 2 . It took about 23 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. As a result, methylphenylpolysilane with a weight average molecular weight of 7400 (average degree of polymerization : approximately 61) was afforded in a yield of 36.7%. Example 31 Methylphenyldichlorosilane was subjected to electrochemical reaction in the same manner as in Example 12 with the exception that 0.29 g of VCl 3 was used as current carrying aid. It took about 23 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. As a result, methylphenylpolysilane was obtained in a yield of 26.4% with a weight average molecular weight of 15700 (average degree of polymerization : approximately 131). Example 32 An electrochemical reaction was conducted in the same manner as in Example 12 with the exception that 0.25 g of CuCl 2 was used as current carrying aid. It took about 18 hours for the passed electricity to reach 1.8 F/mol based on the chlorine content of the starting material. The result showed that methylphenylpolysilane with a weight average molecular weight of 10400 (average degree of.polymerization : approximately 86) was given in a yield of 41.8%. Example 33 27 g of anhydrous lithium chloride (LiCl) and 17 g of anhydrous aluminum chloride (AlCl 3 ) were fed into the electrolyte tank of the flow-type electrolytic cell system. The system was composed of a filterpress-type electrolytic cell (distance between the electrodes : 5 mm) equipped with a Mg anode (12 cm x 15 cm x 1 cm) and a stainless steal (SUS 316) cathode (12 cm x 15 cm x 1 cm), a 3 l - volume electrolyte tank, a bellows-type pump and circulation pipes. The system was heated to 50°C under reduced pressure of 1 mmHg, to thereby dry LiCl and AlCl 3 . Deoxidized dry nitrogen was introduced into the electrolytic cell system. Then 1.0 l of tetrahydrofuran preliminarily dried over sodium-benzophenone ketyl was added. 107.9 ml (0.67 mol) of methylphenyldichlorosilane preliminarily purified by distillation was added. While circulating the electrolyte by means of the bellows-type pump (linear velocity between the electrodes : 20 cm/sec.) and maintaining the reaction temperature at room temperature by means of a cooler, an electric current was applied with a constant-voltage source. The current was applied for about 36 hours to pass 1.8 F/mol of electricity based on the chlorine content of starting material. After completion of the reaction, 1.5 l of distilled water was added to the electrolyte. Then the mixture was extracted with 1.5 l of ether, followed by reprecipitation by adding 2 l of poor solvent ethanol and 50 ml of good solvent benzene, to thereby yield a product. The result showed that methylphenylpolysilane with a weight average molecular weight of 18500 (average degree of polymerization : approximately 154) was obtained in a yield of 39.9%. Example 34 The method of the present invention was carried out using the pencil sharpener form electrolytic cell as illustrated in Figure 3. A pencil sharpener form electrolytic cell 17 containing an anode of built-up bodies made of magnesium composed of cone 11 (105 cm in height x 22 cm in diameter) and cylinder 13 (22 cm in diameter x 45 cm in thickness, composed of three blocks each 15 cm in thickness) and a cathode sheet 15 made of SUS 304 (the sheet partly constituted the external wall of the electrolytic cell) placed at 5 mm distance from the anode cone 11; a 20 l - volume electrolyte tank (which is not illustrated in the drawing); circulation pumps and pipes (which are not illustrated in the drawing) and so on were equipped as primary components in the flow-type electrolytic cell system. 400 g of anhydrous lithium chloride (LiCl) and 250 g of anhydrous ferrous chloride (FeCl 2 ) were fed into the cell. The system was heated to 50°C under reduced pressure of 1 mmHg, to thereby dry LiCl and FeCl 2 . Deoxidized dry nitrogen was introduced into the system. Then 15 l of dried tetrahydrofuran was added. Into the mixture, 1.5 kg of methylphenyldichlorosilane was added. While circulating the electrolyte in the direction of the arrow by means of a circulation pump (linear velocity at the intermediate point between the electrodes : 20 cm/sec.) and maintaining the reaction temperature at room temperature by means of a cooler, constant-current electrolysis was conducted at a current value of 34 A. The current was applied for about 22 hours to pass 3.5 F/mol of electricity based on the starting material. After completion of the reaction, the electrolyte was washed, extracted and reprecipitated in accordance with the conventional method to yield 385 g of methylphenylpolysilane. Observation of the Mg electrode consumption after the reaction indicated that the Mg electrode was consumed and shortened by about 5 mm at the upper end. In view of the extent of the consumption, it is apparent that the upper portion of the cylinder 13 constituting Mg anode 45 cm in height (three blocks each 15 cm in height) will be consumed completely and thus there will be a need to supply another Mg block only after the above reaction cycle will be repeated about 90 times. Example 35 The method of the present invention was performed using an anode of the type illustrated in Figure 1 and an electrolytic cell of the type illustrated in Figure 4. The electrolytic cell 23 containing as an anode Mg balls 3 (diameter: 1 cm) placed in a basket 1 made of PTFE (20 cm in diameter x 40 cm in height) up to 35 cm high from the bottom of the basket and a cathode of cylinder-type container 21 made of SUS 304, placed at 5 mm distant from the anode basket 1; a 20 l - volume of electrolyte tank (which is not illustrated in the drawing); circulation pumps and pipes (which are not illustrated in the drawing) and so on were equipped as primary components in the flow-type electrolytic cell system. Into the system, 400 g of anhydrous lithium chloride (LiCl) and 250 g of anhydrous ferrous chloride (FeCl 2 ) were fed. The system was heated to 50°C under reduced pressure of 1 mmHg, to thereby dry LiCl and FeCl 2 . Deoxidized dry nitrogen was introduced into the system. Then 15 l of dried tetrahydrofuran was added. Into the mixture, 1.5 kg of methylphenyldichlorosilane was added. While circulating the electrolyte in the direction of the arrow by means of the circulation pump (linear velocity between the electrodes : 20 cm/sec.) and maintaining the reaction temperature at room temperature by means of a cooler, constant-current electrolysis was conducted at a current value of 34 A. The current was applied for about 22 hours to pass 3.5 F/mol of electricity based on the starting material. After completion of the reaction, the electrolyte was washed, extracted and reprecipitated in accordance with the conventional method to give 339 g of methylphenylpolysilane. Observation of the Mg electrode consumption after the reaction indicated that the Mg electrode was consumed and shortened by about 1 cm at the upper end. In view of the extent of the consumption, it is apparent that the height of Mg balls was lowered from the upper end by one third and thus there is no need to supply another Mg ball until the above reaction is repeated about 70 times.

Claims: A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents halogen atom) is subjected to an electrochemical reaction using Mg or an Mg alloy as anode, alithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a polysilane of the general formula (wherein R is as defined above corresponding to the starting material; n is 20 to 10000), wherein additionally an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt is used as current carrying aid. A method for producing a polysilane characterized in that a compound of the general formula (wherein R' represents an aromatic group, unsaturated aliphatic group, -(CH 2 ) m - group or -(CH 2 -CH 2 -O) m - group [m is 1 to 20]; R 1 , R 2, R 3 and R 4 are the same or different and represent a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X' represents a halogen atom) is subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a polymer of the following general formula containing Si-Si bonds in a main chain (wherein R', R 1 , R 2, R 3 and R 4 are as defined above; n is 20 to 10000), wherein additionally an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt is used as current carrying aid. A method for producing a polysilane characterized in that a trihalosilane of the general formula R"SiX" 3 (wherein R" represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X" represents a halogen atom) is subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte, and an aprotic solvent as solvent, thereby producing a silicon network polymer of the general formula (R"Si) n (wherein R" is as defined above corresponding to the starting material; n is 20 to 10000), wherein additionally an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt is used as current carrying aid. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom) and a trihalosilane of the general formula R"SiX" 3 (wherein R" represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X" represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (wherein R is as defined above) and a structural unit of the general formula R"Si≡ (wherein R" is as defined above), wherein additionally an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt is used as current carrying aid. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents ahydrogenatom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom) and a tetrahalosilane of the general formula SiX"' 4 (wherein X"' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (wherein R is as defined above) and a structural unit of the general formula wherein additionally an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt is used as current carrying aid. A method for producing a polysilane characterized in that a trihalosilane of the general formula R"SiX" 3 (wherein R" represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group; X" represents a halogen atom) and a tetrahalosilane of the general formula SiX"' 4 (wherein X"' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte, and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula R"Si≡ (wherein R" is as defined above) and a structural unit of the general formula wherein additionally an Al salt, Fe salt, Mg salt, Zn salt, Sn salt, Co salt, Pd salt, V salt, Cu salt or Ca salt is used as current carrying aid. A method for producing a polysilane characterized in that a dihalosilane of the general formula (wherein m is 1 to 3; R represents a hydrogen atom, alkyl group, aryl group, alkoxy group or amino group and two Rs are the same or different in case of m=1, four Rs are the same or at least two of them are different in case of m=2 and six Rs are the same or at least two of them are different in case of m=3; X represents a halogen atom) and a trihalosilane of the general formula R"SiX" 3 wherein R" represents an alkyl group, aryl group, alkoxy group, or amino group; X" represents a halogen atom and a tetrahalosilane of the general formula SiX"' 4 (wherein X"' represents a halogen atom) are subjected to an electrochemical reaction using Mg or an Mg alloy as anode, a lithium salt as supporting electrolyte and an aprotic solvent as solvent, thereby producing a network polymer containing Si-Si bonds in the backbone structure composed of a structural unit of the general formula (wherein R is as defined above), a structural unit of the general formula R"Si≡ (wherein R" is as defined above) and a structural unit of the general formula The method according to any of claims 1 to 7 wherein LiCl is used as supporting electrolyte. The method according to claim 8 wherein AlCl 3 , FeCl 2 , FeCl 3 , CoCl 2 or CuCl 2 is used as current carrying aid.

Inventors: KAWASAKI SHINICHI, MURASE HIROAKI, NISHIDA RYOICHI, KAWASAKI, SHINICHI, MURASE, HIROAKI, NISHIDA, RYOICHI
Applicants: OSAKA GAS CO LTD, OSAKA GAS CO., LTD.
Application year: 1995
Main classification: C08G77
IPC codes: C08G77