Thermally apertured nonwoven product and process for making the same

Abstract: A process for producing an apertured nonwoven fabric combines one or two outer nonwoven layer(s) with a layer of polymeric material having a lower melting temperature and a property of shrinking when melted. Heat and pressure are applied through a calendar roll such that the polymeric material becomes bonded to the fibers of the nonwoven layer(s) and simultaneously shrinks and takes back the fibers away from the calendaring points, thereby generating apertures through the nonwoven fabric. Preferably, the fibers are polyethylene or polypropylene fibers, and the layer of polymeric material is a thin plastic film of polyethylene stretch-wrap, elastomeric, or heat shrink material. One outer nonwoven layer may be combined with the plastic film layer to form a bi-laminate product, or two outer nonwoven layers may be combined with an intermediate plastic film to form a tri-laminate product. Low denier polypropylene/polyethylene bi-component fibers or a blend of higher and lower melting fibers may also be used. Apertured products can also be obtained with non-thermoplastic outer layers and an intermediate plastic film layer.

Description: This invention relates generally to apertured nonwoven fabrics and, particularly, to an apertured nonwoven topsheet product formed by a thermal aperturing process. Background Art Apertured nonwoven fabrics are used in environments where it is desired to combine the properties of a fluid pervious outer layer for contact with the skin of a user with an absorbent layer having fluid absorption capacity. Such apertured nonwoven fabrics find use as a topsheet in diapers, sanitary napkins, and adult incontinence products, etc. Traditionally, apertured nonwoven fabrics are formed by hydraulic processes such as hydroentangling a fibrous web with an apertured pattern or spunlacing, by mechanical processes such as perforating or punching a nonwoven fabric, or by thermo-mechanical processes such as hot pin perforation, embossed roll calendaring, etc. Hydraulic processes require rather costly equipment and complex processing operations. Mechanical or thermo-mechanical processes also require multiple processing steps, e.g., by first forming a bonded nonwoven fabric then perforating or aperturing the same. Some thermo-mechanical processes, such as taught in U.S. Patents 3,507,943 and 3,542,634, can bond and aperture a fibrous layer in one step by pressure fusing the fibers of the nonwoven layer between contact points of embossed rolls or land-groove rolls and at the same time forming apertures therethrough by melting with sufficient heat and pressure, shearing action, etc. However, a high amount of heat and pressure is required to produce well-formed through-holes in the nonwoven layer. Other processes, such as taught in U.S. Patent 4,184,902 to Karami or U.S. Patent 4,780,352 to Palumbo, form a topsheet in one processing step by perforating and/or spot bonding a fluid-pervious nonwoven layer with a plastic intermediate layer. However, the holes or aperture areas generated may not be of sufficient dimension or well-formed shape, and may require additional processing such as hot blowing or stretching to generate apertures of sufficient size and shape. EP-A-0596191 discloses a product having two nonwoven fibrous webs of material bonded together by bonded areas in which apertures are located. It is therefore a principal object of the present invention to produce an apertured nonwoven fabric through a one-step cost-effective process using a simplified technique for generating apertures of sufficient size and shape. It is a particular object that such process take advantage of a physical interaction between polymeric materials of different melting temperatures under application of heat and pressure from the calendaring points of a calendar roll to accomplish simultaneously bonding of the fibers and forming of apertures through the nonwoven fabric. Summary of the Invention In accordance with the present invention, a process for producing an apertured nonwoven fabric comprises the steps of combining a nonwoven layer of fibers having a higher melting temperature and a polymeric material having a lower melting temperature and a property of shrinking under application of heat, and applying heat and pressure to the combination of the first-mentioned fibers and the other polymeric material through calendaring points of a calendar roll, such that the melted polymeric material becomes bonded to the first-mentioned fibers and simultaneously shrinks and takes back the first-mentioned fibers away from the calendaring points, thereby generating apertures through the nonwoven fabric. In the preferred process, the fibers of the nonwoven layer are carded olefinic fibers, preferably polyethylene or polypropylene fibers, and the layer of polymeric material is a thin plastic film of olefinic material, such as a polyethylene stretch-wrap, or elastomeric material, or heat shrink material. The apertured product can have anywhere from 1 - 50% open (apertured) area. The process can be utilized for apertured nonwoven fabrics having basis weights ranging anywhere from 12.0 to 107.6 [10.0 to 90.0 grams/yd 2 (gsy)]. One outer nonwoven layer may be combined with the plastic film layer to form a bi-laminate product, or two outer nonwoven layers may be combined with an intermediate plastic film to form a tri-laminate product. In one particular example, the fibers of the nonwoven layer(s) are polypropylene having a melting point of about 165 °C, and the plastic film is a 19.1 g/m 2 (16-gsy) polyethylene stretch-wrap having a melting point of 125 °C. Alternatively, low denier polypropylene/polyethylene bi-component fibers or a selected blend of low and high melting fibers may be used to obtain the same physical effect of shrinking and taking back the fibers to form apertures through the nonwoven fabric. A similar effect can be obtained when non-thermoplastic fibers in the outer layers are bonded to and pulled back by an intermediate plastic layer. The resulting products exhibit good bonding, suitable strength, and well-formed apertures. Other objects, features and advantages of the present invention are described in detail below in conjunction with the drawings, as follows: Brief Description of the Drawings Figs. 1a - 1d illustrate the thermal aperturing technique in accordance with the invention for the general example of a tri-laminate product having outer nonwoven layers and an intermediate polymeric layer. Fig. 2 is a schematic view of a process line for the manufacture of apertured nonwoven fabric. Figs. 3 - 8 are photographic examples of apertured nonwoven products produced in accordance with the thermal aperturing technique. Detailed Description of the Invention In the present invention, a one-step bonding and aperturing process is used for manufacturing a thermally apertured nonwoven product using thermal bonding (heated calendaring) technology. The apertured nonwoven product is produced by combining one or two nonwoven layer(s) of fibers with a layer of polymeric material having a lower melting temperature and a property of shrinking when melted, such that under the application of heat and pressure the polymeric material becomes bonded to the fiber layer(s) and shrinks and takes back the fibers to form apertures through the nonwoven fabric. An example of the general process for forming thermally aperturing nonwoven fabric in accordance with the invention is illustrated in Figs. 1a - 1d using a plastic film as the layer of polymeric material. One or two outer nonwoven layers 10a, 10b and a thin plastic film 12 are fed in superposed relation through the nip of a pair of heated calendar rolls 20a, 20b. The calendar rolls have a plurality of calendaring points or lands 22a, 22b which come together to apply heat and pressure to the superposed layers fed in between. The fibers of the nonwoven layers are made of a polymeric material. Preferably, they are olefinic fibers such as polyethylene or, most preferably, polypropylene. The plastic film 12 is made of a polymeric material that has a melting temperature lower than that of the olefinic fibers and a property of shrinking upon application of heat above its melting temperature. Films which can be used include olefinic, such as polyethylene stretch-wrap, elastomeric, or heat shrink films. As shown in Fig. 1c, application of suitable heat and pressure causes the plastic film 12 to melt and shrink away from the area of the calendaring points 20a, 20b. While shrinking back, the melting plastic film fuses to the fibers of the webs 10a, 10b and takes them back away from the calendaring points. As shown in Fig. 1d, the result is that the plastic film 12 and the fibers of the webs 10a, 10b become fused to each other, forming a fused border 32 around the area of the localized regions, specifically the calendaring points, which serves simultaneously to bond the layers together and to define an aperture 30 through the nonwoven fabric. The film acts as a carrier to create the aperture. On a per weight basis, some plastic films are cheaper than the fiber. Therefore, in some cases, the cost of making the apertured fabric is significantly less than making a conventional apertured fabric of comparable weight using fibers alone. In Fig. 2, a process line is shown schematically for the manufacture of apertured nonwoven fabric as a continuous roll product. The olefinic fibers are carded at card stations #1 and #2 and fed on card conveyors 14a, 14b, respectively, for the webs 10a, 10b of fibers. The thin plastic film 12 is unwound from an unwind stand 16 and fed in superposed relation between the two carded webs on the card conveyors, and the composite of plastic film enclosed between two carded webs is fed by conveyors 16a, 16b to hot calendar rolls 20a, 20b to be thermally bonded and apertured. The preferred practice employs dual engraved rolls (Novonette #2 pattern), although anvil rolls or even a single engraved roll may also be utilized. On entering the heated calendar rolls, the olefinic fibers are bonded to each other and to the plastic film which melts and shrinks away from the calendaring points carrying fibres with it to generate a pattern of apertures. On exiting the calendar rolls, the bonded and apertured nonwoven fabric is wound up on a roll. The apertured product can be formed with typically 1 - 50% open (apertured) area. However, the product can be tailored with any required open area by modifying the calendar bond pattern, process conditions, etc. While the apertures appear to the naked eye as ovals, they are in fact somewhat irregular in shape when observed under a microscope. The apertured product can also be mechanically tentered (stretched) as it exits in a hot condition from the calendar. Tentering can significantly enhance the aperture clarity and size. Depending on the kind of plastic film used and the type of fiber employed, the fluid handling properties of the apertured nonwoven product can be modified as required for suitable strike-through, re-wet, liquid distribution, and other properties. Comparison trials showed that apertured products can be formed having the strike-through and re-wet properties of a typical diaper topsheet. The fabric can be formed to possess the desired softness for skin contact in various consumer disposable applications, as measured by hand-feel. However, a trade-off exists between fabric softness and the aperture clarity that is obtained. The elasticity of the apertured structure can be easily altered by using elastomeric materials instead of an olefinic film. Apertured products can be made in almost any weight, e.g., ranging from 12.0 to 107.6 g/m 2 [10.0 to 90.0 gsy]. A typical fabric for consumer disposable applications could be in the range of 41.9 to 65.8 g/m 2 (35. 0 to 55.0 gsy). Different variations utilizing other types of plastic films and polymeric materials can produce apertured product using the same basic concept of the invention. Fibers other than olefinic fibers, for example polyesters, polyamides, etc., may be used for the nonwoven layer. Where a plastic film is used, apertured fabric can be made one-sided or two-sided. When the plastic film is embedded between two layers of fiber, a soft product having the same feel on both sides is made, referred to herein as a "tri-laminate" product. On the other hand, attaching the plastic film to one side of the fiber layer results in a product having a different feel on its two sides. One side feels soft due to the presence of fibers, while the other side feels like plastic. This is referred to as a "bi-laminate" product. It is found that using polyethylene (PE) stretch-wrap as the thin film and embedding it between two layers of fiber gives a tri-laminate product with good aperture quality at the lowest cost. A desirable product can be made at anywhere from 36 to 55 g/m 2 [30 to 46 gsy] weights using low-elongation, high tenacity polypropylene (PP) fibers for the nonwoven layers, such as fibers designated T101 1.8 dpf x 38 mm obtained from Hercules Corp., of Norcross, Georgia, and 19.1 g/m 2 (16 gsy) clear stretch wrap film, such as Loadmaster-S, PC-3400, 1.0 mil, LDPE stretch wrap film, from Borden Packaging and Industrial Products, of North Andover, Massachusetts. The above-mentioned polypropylene fibers have a melting point of about 165 °C (330°F), and the polyethylene stretch-wrap has a melting point of about 125 °C (260°F). Optimum softness and hole clarity were obtained at calendar roll temperatures of 160°C (320°F) in particular and 149 to 182°C [300 °F to 360°F] in general when using PP fibers, and at calendar roll pressures in the range of 380 kPa [55 psi (pounds/sq.in.)] or 54 kgs/linear cm [300 pli (pounds/linear inch)]. An apertured plastic film can be used in place of the stretch wrap film. For example, apertured polytheylene (PE) films of different grades, thicknesses, and compositions with or without ethylvinyl acetate (EVA) can be used. The apertured film embedded between two layers of fibers results in a tri-laminate product with very good aperture quality, particularly for apertured PE film with EVA. The product inherits the excellent fluid handling characteristics of the apertured film, e.g., good uni-directional passage of fluid. A bi-laminate variation can also be made. Low denier polypropylene/polyethylene bi-component (PP/PE) fibers are also suitable for this thermal aperturing technique. The low melting polythylene sheath in contrast to the higher melting polypropylene core acts similar to the thin olefinic film described above. In typical examples, cleanly apertured products were manufactured using Chisso ES 0.9 dpf x 38 mm bi-component fibers obtained from the Chisso Company of Japan carded in two layers without any intermediate layer. Calendar roll temperatures of 143 to 146°C (290°F to 295°F) were found to work best with the PP/PE bi-component fibers. A similar variation exploits the same physical effect by blending fibers with higher and lower melting points. The melting point differential is selected to simulate the effect of the thin olefinic film in taking back the fibers from the aperture areas. As an example, 20% of low melting polyethylene fiber can be blended with 80% polypropylene fibers to produce a suitable apertured product. Elastic properties can be imparted to the apertured product by the use of an elastomeric film in place of the thin olefinic film. As an example, an elastomeric film such as one designated xExx56™ obtainable from Exxon Chemicals Corp., of Lake Zurich, Illinois, can produce a product of good aperture clarity and excellent elastic properties in both the machine and cross directions. Both tri- and bi-laminate products can be made. Heat shrink films may also be used to obtain the same physical effect of shrinking and taking back the fibers to form apertures through the nonwoven fabric. For example, low-melting high-shrink films obtained from Exxon Chemicals Corp. produced a product with good aperture quality. Another high shrink film, designated CLYSAR™, Grade #60LLP, from DuPont Corp., gave a unique, bulky, apertured fabric. Only tri-laminates are possible in this case because of the shrink film's reaction to a surface applying heat. The above observations were made using a pilot thermal bonding line with 25.4 cm (10") width. Scaling up to a 81.3 cm (32") wide line tested successfully. Pilot line speeds of up to 0.762 m/s (150 feet/minute) were run without any problems. The use of stretch wrap film and apertured PE film with EVA embedded in PP fiber layers produced very good aperture quality, particularly at 38.3 g/m 2 (32 gsy) fabric weight. Calendar roll temperatures of between 164 to 167°C (328 to 332°F) and calendar pressures of 71.4 - 98.2 kg/linear cm (400 - 550 pli) on the 25.4 cm (10") line and 44.7 - 53.6 kg.linear cm 250 - 300 pli on the wider thermal bonding line were found to provide optimum results. Good aperture quality was obtained with calendar rolls having the Novonette pattern and land widths of 0.165 cm (0.065") and 0.206 cm (0.081"), for percentage of apertured areas of 9% and 16%, respectively. The thermal aperturing technique was also found to be adaptable to tri-laminate products having non-thermoplastic fibers, e.g., rayon for the nonwoven layers, and a suitable plastic film in between. Good apertured products were obtained using 18 g/m 2 (15 gsy) Hercules T101 PP fiber in one layer and 18 g/m 2 (15 gsy) rayon (1.5 dpf x 40 mm) fibers in the other layer, with LDPE stretch wrap, apertured PE with EVA, and elastomeric styene block (SB) copolymer based films. A unique product having good to excellent aperture quality can be made with 18 g/m 2 (15 gsy) rayon fibers in both layers and an apertured PE with EVA or elastomeric SBR film in between. A product having excellent aperture quality can also be obtained with rayon fibers in both layers and a stretch wrap film in between if the calendar roll temperature is increased substantially higher, e.g., 211°C 412°F (instead of 160°C 320°F). A product with excellent aperture quality can also be produced using the Hercules T101 PP fibers as the intermediate layer, but the resulting fabric has lower tensile strengths than when using plastic films. Photographic examples of the apertured products described above show the aperture quality obtained with the thermal aperturing method of the present invention. Fig. 3 shows a tri-laminate product obtained with polypropylene outer layers and an intermediate thin film. Fig. 4 shows a tri-laminate product with PP/PP outer layers using calendar rolls of a greater land width (16% apertured area). Fig. 5 shows a bi-laminate product obtained with one polypropylene outer layer and an elastomeric film. Fig. 6 shows an apertured product obtained with PP/PE bi-component fibers in two layers without any ntermediate layer. Fig. 7 shows a tri-laminate product with PP and rayon outer layers and an apertured PE film in between. Fig. 8 shows a tri-laminate product obtained with both outer layers of rayon fibers and an apertured PE film in between. In each case, good aperture quality and shape are obtained by having the the lower melting, shrinking plastic material (thin film layer or bicomponent fiber) fusing to and pulling back the fibers of the outer layers. The fusing and taking back of the fibers by the melting/shrinking polymeric material is evident from the crusted ring of fused or congealed material surrounding the apertures and bonding the layers together. Although the invention has been described with reference to certain preferred processes annd examples, it will be appreciated that many other variations and modifications thereof may be devised in accordance with the principles disclosed herein. The invention and all such variations and modifications thereof within the scope and spirit of the invention are defined in the following claims. The present invention extends to a process for producing an apertured nonwoven fabric comprising the steps of: combining a layer of nonwoven fibers having a higher melting temperature and a layer of polymeric material having a lower melting temperature and a property of shrinking under application of heat, and applying heat and pressure to the combination of the first-mentioned fibers and the other polymeric material through calendaring points of a calendar roll, such that the melted polymeric material becomes bonded to the first-mentioned fibers and simultaneously shrinks and takes back the first-mentioned fibers away from the calendaring points, thereby generating apertures through the nonwoven fabric. The fibres of the nonwoven layer may be carded olefinic fibers, for example polypropylene fibers. The layer of polymeric material may be a thin plastic film made of a selected one of an olefinic material, an elastomeric material, and a heat shrink material. The layer of polymeric material may be a polyethylene stretch wrap film, or an elastomeric styrene block copolymer based film, or an apertured polyethylene film with ethylvinyl acetate. The fabric may be formed by combining two outer nonwoven layers and an intermediate plastic film layer in between, or the fabric may be formed by combining one outer nonwoven layer with a plastic film layer. In another embodiment the fabric is formed with the nonwoven layer and layer of polymeric material combined as a layer of bi-component fibers made of a lower-melting sheath and a higher-melting core. Alternatively the fabric is formed with the nonwoven layer and layer of polymeric material combined as a blend of low and high melting fibers. The fabric may be formed with two outer nonwoven layers of olefinic fibers and a thin plastic film in between, or the fabric may be formed with one outer nonwoven layer of olefinic fibers and one outer nonwoven layer of non-thermoplastic fibers and a thin plastic film in between, or the fabric may be formed with two outer nonwoven layers of non-thermoplastic fibers and a thin plastic film in between. The two outer nonwoven layers may be made of rayon fibers. The calendaring roll preferably applies heat at a temperature in the range of 138°C to 232°C (280°F to 450°F). The calendaring roll preferably applies pressure in the range of 35.7 to 107 kg/linear cm (200 to 600 pounds/linear-inch). The apertured area is preferably in the range of 9% to 16% of the fabric area. The invention also extends to an apertured nonwoven fabric comprising a nonwoven layer of fibers having a higher melting temperature and a layer of polymeric material having a lower melting temperature and a property of shrinking under application of heat, wherein the fabric is calendared by heated calendaring points of a calendar roll, such that the polymeric material becomes bonded to the first-mentioned fibers and takes the first-mentioned fibers away from the calendaring points, thereby providing apertures through the nonwoven fabric.

Claims: A process for producing an apertured nonwoven fabric comprising the steps of: combining nonwoven fibers having a higher melting temperature and a layer of polymeric material having a lower melting temperature and a property of shrinking under application of heat, and applying heat and pressure to the combination of the nonwoven fibers and the other polymeric material at localized regions, such that the melted polymeric material becomes bonded to the nonwoven fibers and simultaneously shrinks and takes back the nonwoven fibers away from the calendaring points, thereby generating apertures through the fabric. A process according to claim 1 in which the heat and pressure are applied at localized regions by means of calendering. A process as claimed in claim 1 or claim 2 in which the heat and pressure are applied by two calendar rolls on opposing sides of the fabric. A process as claimed in claim 1, 2 or 3 in which the nonwoven fibers are present as a nonwoven layer and the polymeric material is present as a film, which may be apertured. A process as claimed in any one of claims 1 to 4 in which the nonwoven fibers are carded olefinic fibers. A process as claimed in any one of the preceding claims, in which the nonwoven fibers are polypropylene fibers. A process as claimed in claim 6 in which the polypropylene fibers have high tenacity and low elongation characteristcs. A process as claimed in any one of the preceding claims in which the polymeric material comprises an olefinic material, an elastomeric material, or a heat shrink material. A process as claimed in claim 8, in which the polymeric material is a polyethylene stretch wrap material. A process as claimed in claim 8, in which the polymeric material is an elastomeric styrene block copolymer based material. A process as claimed in claim 8, in which the polymeric material, is polyethylene with ethylvinyl acetate. A process as claimed in any one of the preceding claims, in which the fabric is formed by combining two outer nonwoven layers with the polymeric material between them. A process as claimed in claim 12 in which the two outer nonwoven layers are made of the same fibrous material. A process as claimed in claim 12 in which the two outer nonwoven layers are made of different fibrous material. A process as claimed in any one of claims 1 to 11, in which the fabric is formed by combining one outer nonwoven layer with a plastic film layer. A process as claimed in claim 1, 2 or 3 in which the fabric is formed with the nonwoven fibers and the polymeric material combined as a layer of bi-component fibers made of a lower-melting sheath and a higher-melting core. A process as claimed in claim 1, 2 or 3 in which the fabric is formed with the nonwoven fibers and the polymeric material combined as a blend of low and high melting fibers. A process as claimed in any one of the preceding claims, in which the temperature is in the range of 138 to 232°C (280°F to 450°F). A process as claimed in any one of the preceding claims, in which the pressure is in the range of 35 to 107 Kgs/linear cm (200 to 600 pounds/linear-inch). A process as claimed in any one of the preceding claims, in which the apertured area is in the range of 9% to 16% of the fabric area. An apertured nonwoven fabric comprising nonwoven fibers having a higher melting temperature and polymeric film material having a lower melting temperature and a property of shrinking under application of heat, the polymeric film material being bonded to the nonwoven fibers at least in the vicinity of the edges of the apertures. A fabric as claimed in claim 21 in which the nonwoven fibers are polypropylene fibers having high tenacity and low elongation characteristics. A fabric as claimed in claim 21 or claim 22 which is formed with two outer nonwoven layers of olefinic fibers and a thin plastic film in between. A fabric as claimed in claim 23 in which the two outer nonwoven layers are made of the same fibrous material. A fabric as claimed in claim 23 in which the two outer nonwoven layers are made of different fibrous material. A fabric as claimed in any one of claims 21 to 25 in which the fabric has a weight in the range of 10 to 90 gsy. A fabric as claimed in any one of claims 21 to 26 in which each of the apertures is defined by a crusted ring of fused matter along the periphery thereof. A fabric as claimed in claim 21 or claim 22 which is formed with one outer nonwoven layer of olefinic fibers and one outer nonwoven layer of non-thermoplastic fibers and a thin plastic film in between. A fabric as claimed in claim 21 or claim 22 which is formed with two outer nonwoven layers of non-thermoplastic fibers and a thin plastic film in between. A fabric as claimed in claim 29 in which the two outer nonwoven layers are made of rayon fibers.

Inventors: COSLETT W ANDREW, LEONGUERRERO LEONARDO B, MCCOOMBS DONALD V, SRINIVASAN RAMESH, COSLETT, W. ANDREW, LEONGUERRERO, LEONARDO B., MCCOOMBS, DONALD V., SRINIVASAN, RAMESH
Applicants: BBA NONWOVENS SIMPSONVILLE INC, BBA NONWOVENS SIMPSONVILLE, INC.
Application year: 1995
Main classification: D04H13
IPC codes: B32B3, B32B5, D04H1, D04H13