OPTICAL DEVICE COMPRISING A PLURALITY OF UNITS HAVING AT LEAST TWO GEOMETRICALLY-DIFFERENTIATED TAPERED OPTICAL WAVEGUIDES THEREIN

Abstract: The present invention provides an optical device comprising: (a) a substrate; and (b) a plurality of units on the substrate. Each of the units comprises a plurality of tapered waveguides wherein: (i) each of the waveguides has a light input surface adjacent the substrate (a) and a light output surface distal from the light input surface and the light input surface area is greater than the light output surface area; (ii) each of the waveguides tapers from its light input surface to its light output surface at an angle; and (iii) at least one of the light input surface area or the light output surface area of at least one of the tapered waveguides is different than the corresponding surface area of the remaining tapered waveguides in the unit. Preferably, the optical device is a viewing film. The present viewing film has reduced or substantially eliminated intensity hot spots and interference patterns. The present viewing film may be used in display devices, such as for example projection display devices, off screen display devices, and direct view displays. Such displays are used in a wide range of applications including computer terminals, airplane cockpit displays, automotive instrument panels, televisions, and other devices which provide text, graphics, or video information.

Description: OPTICAL DEVICE COMPRISING A PLURALITY OF UNITS HAVING AT LEAST TWO GEOMETRICALLY-DIFFERENTIATED TAPERED OPTICAL WAVEGUIDES THEREIN Background of the Invention The present invention relates to an optical device comprising a plurality of units having at least two geometrically-differentiated tapered optical waveguides therein. Optical waveguides, also known in the art as light transmissive devices or lightguides, find application in display devices, such as for example projection display devices, off screen display devices, and direct view displays. Typically, an optical element having a plurality of optical waveguides is used. See for example U.S. Patents 3,218,924 and 3,279,314 to Miller and U.S. Patent 4,767,186 to Bradley, Jr. et al. Such displays are used in a wide range of applications including computer terminals, airplane cockpit displays, automotive instrument panels, televisions, and other devices that provide text, graphics, or video information. Such known displays suffer from the following problems. Depending on the exact optical waveguide geometry, known displays may produce non-monotonically decreasing light output intensity as the viewing angle is changed from normal to the optical device to parallel to the optical device. See Figure 10 which shows the minima which occur in such a light distribution output pattern. A viewer will perceive the peaks between such lows in the light distribution output pattern as intensity hot spots, which will be clearly disadvantageous to the perception of a uniformly emissive optical device. Another problem which occurs in known displays is the occurrence of Moire and other interference patterns. A typical liquid crystal display device has a first polarizer element, a first substrate with pixel electrodes on it and a matrix circuit section to apply voltage to these pixel electrodes, a liquid crystal layer, a second substrate having a black matrix layer with openings, and a second polarizer element. A pixel is formed by the openings on the second substrate and the pixel electrodes on the first substrate. When an optical device is assembled with such a liquid crystal display device, Moire and other inference patterns often occur because the critical dimensions for pixel pitch separation line width are similar or nearly similar to the critical dimensions for the optical device. Viewing these patterns is unappealing. Another problem which occurs in known displays is that very specific output distributions of the light may be hard to achieve with just one type of optical waveguide present within said optical device. The output distribution of the light will be solely defined by that waveguide and thus the waveguide must be specifically designed to exactly accomodate the needs of the user. Thus, a need exists in the art for an optical device wherein the occurrence of intensity hot spots and Moire and other interference patterns is reduced or substantially eliminated so as to provide a more uniformly emissive optical device. Summary of the Invention We have developed an optical device which responds to the foregoing need in the art. The optical device comprises: (a) a substrate; and (b) a plurality of units on the substrate. Each of the units comprises a plurality of tapered waveguides wherein: (i) each of the waveguides has a light input surface adjacent the substrate (a) and a light output surface distal from the light input surface and the light input surface area is greater than the light output surface area; (ii) each of the waveguides tapers from its light input surface to its light output surface; and (iii) at least one of the light input surface area or the light output surface area of at least one of the tapered waveguides is different than the corresponding surface area of the remaining tapered waveguides in the unit. When used as a viewing film, the present optical device is particularly advantageous. Because at least one of the light input and output surface areas of at least one of the tapered waveguides is different than the corresponding surface area of the remaining tapered waveguides in the unit, the occurrence of intensity hot spots and Moire and interference patterns is reduced or substantially eliminated. As a result, the viewing film provides a more uniformly emissive display. In addition, the combination of tapered waveguides within a unit can be choosen such that a very specific output distribution can be achieved through the combined effects of the waveguides and is not required to result from a single waveguide type. Other advantages of the present invention will be apparent from the following description, attached drawings, and attached claims. Brief Description of the Drawings Figure 1 illustrates a tapered optical waveguide element with a rectangular or square base useful in the present invention. Figure 2 illustrates a tapered optical waveguide element with a circular base useful in the present invention. Figure 3 illustrates the taper angle, light input surface dimension, and light output surface dimension of the tapered optical waveguide element. Figure 4 illustrates the side view of a unit of two tapered optical waveguide elements which have different light output surface areas and identical light input surface areas. Figure 5 illustrates a perspective view of the unit of the two different tapered optical waveguide elements of Figure 4. Figure 6 illustrates the side view of a unit of two tapered optical waveguide elements which have different light input and output surface areas. Figure 7 illustates the design of a lithographic phototool which was used to photolithographically define 16 different optical waveguides as the repeat unit of a viewing film. Figure 8 illustrates one possible arrangement of tapered optical waveguide elements within a unit 26 which contains different light input surface areas 14a and 14b and different light output areas 16a-16d. Figure 9 illustrates the resulting light distribution of the tapered optical waveguide element having a square output surface area which is 25 microns on a side used in Example 1. Figure 10 illustrates the resulting light distribution of the tapered optical waveguide element having a square output surface area which is 10 microns on a side used in Example 1. Figure 1 1 illustrates a top view of a unit 26 of four different optical waveguide elements. In each case (a) - (e), the input surface areas 14 and the output surface areas 16 are noted. The successive figures show possible ways of creating units 26 in which combinations of two different output surface areas 16a and 16b are considered. Figure 12 illustrates the resulting distribution from combining the tapered optical waveguide elements as depicted in Figure 11 (c). Figure 13 illustrates the resulting distribution from combining the tapered optical waveguide elements as depicted in Figure 1 1 (d). Figure 14 illustrates the resulting distribution from combining the tapered optical waveguide elements as depicted in Figure 1 1 (e). Figure 15 illustrates the top view schematic representation of the resulting optical device described in Example 2. Detailed Description of the Preferred Embodiments As shown in Figures 1 and 2, each tapered waveguide 12 has a light input surface 14, light output surface 16, and sidewalls 18. The area of light input surface 14 is greater than the area of light output surface 16 for each tapered waveguide 12. The cross section of a tapered waveguide 12 in a plane parallel to the substrate surface may have any shape including a circle, square, hexagon, ellipse, and rectangle. Figure 1 shows a tapered waveguide 12 with a rectangular cross section viewed in perspective. Figure 2 shows a tapered waveguide 12 with a circular cross section viewed in perspective. The shape of sidewalls 18 may be straight or curved. When waveguide 12 has a taper such that the area of light output surface 16 is smaller than the area of light input surface 14, the angular distribution of the light emerging from light output surface 16 will be larger than the angular distribution of the light entering the light input surface 14. The present viewing film having a plurality of tapered waveguides 12 when used with a display will alter the angular distribution of the output light from a modulating means such that the image from the modulating means may be viewed at higher angles. The area of light output surface 16 of each tapered waveguide 12 is preferably from about 1 to about 50 percent of the area of light input surface 14, more preferably from about 3 to about 25 percent of the area of light input surface 14, and most preferably from about 4 to about 12 percent of the area of light input surface 14. In order that a display having the present viewing film therein has high overall light throughput, the sum of the areas for all waveguide light input surfaces is preferably greater than about 40 percent of the total areas of the substrate of the viewing film, more preferably greater than about 60 percent of the total areas of the substrate of the viewing film, and most preferably greater than about 80 percent of the total areas of the substrate of the viewing film. A single tapered waveguide 12 with light input surface 14, light output surface 16, and straight sidewalls 18 is shown in Figure 3. If tapered straight sidewalls 18 are extended until they intersect, they form taper angle 20. The value of taper angle 20 ranges preferably from about 2 degrees to about 14 degrees, more preferably from about 4 degrees to about 12 degrees, and most preferably from about 6 degrees to about 10 degrees. Tapered waveguide 12 has a height 22. Dimension 24 is the minimum transverse distance across the waveguide light input surface 14. For example, if light input surface 14 has the shape of a square, dimension 24 is the length of one side of the square. As another example, if light input surface 14 has the shape of a rectangle, dimension 24 is the smaller of the two side dimensions of the rectangle. The specific values for dimension 24 may vary widely depending on the center-to-center distance between adjacent pixels of a modulating means. In order that the resolution of the image formed by a modulating means not be degraded, dimension 24 should be equal to or less than the center-to-center distance between adjacent pixels of a modulating means. For example, if the center-to-center distance between adjacent pixels in a modulating means is 200 microns, then dimension 24 is preferably in the range from about 5 microns to about 200 microns, more preferably in the range from about 15 microns to about 200 microns, and most preferably from about 25 microns to about 100 microns. After dimension 24 is selected, height 22 may be specified by the ratio of height 22 to dimension 24. The ratio of height 22 to dimension 24 may vary widely depending on how much one wishes to increase the angular distribution of light emerging from the light output surface 16 compared to the angular distribution of light entering light input surface 14. The ratio of height 22 to dimension 24 is preferably from about 0.25 to about 20, more preferably from about 1 to about 8, and most preferably from about 2 to about 6. In each unit, at least one of the light input surface area 14 or the light output surface area 16 of at least one of the tapered waveguides 12 is different than the corresponding light input surface area or light output surface area of the remaining tapered waveguides in the unit. The term "different" as used herein means that at least one of the light input surface area or light output surface area of at least one of the tapered waveguides is different than the corresponding light input surface area or light output surface area of the remaining tapered waveguides in the unit by at least about 2 percent. For example, if the light input surface area of one of the tapered waveguides is x, each light input surface area of the remaining tapered waveguides in the unit is at least 1.02x or no more than 0.98x. As another example, if the light output surface area of one of the tapered waveguides is y, each light output surface area of the remaining tapered waveguides in the unit is at least 1.02y or no more than 0.98y. At least one of the light input surface area or light output surface area of at least one of the tapered waveguides is different than the corresponding light input surface area or light output surface area of the remaining tapered waveguides in the unit by preferably at least about 5 percent, more preferably at least about 10 percent, and most preferably at least about 20 percent. Thus, the different surface areas include the following: (1) at least one light input surface area of at least one tapered waveguide is different than each light input surface area of the remaining tapered waveguides in the unit, (2) at least one light output surface area of at least one tapered waveguide is different than each light output surface area of the remaining tapered waveguides in the unit, and (3) both the light input and output surface areas of at least one tapered waveguide are different than both the light input and output surface areas of the remaining tapered waveguides in the unit. Figure 4 illustrates the side view of a unit 26 of a plurality of two tapered waveguides 12 which have different light output surface areas 16, the same light input surface areas 14, and the same heights 22. Figure 5 illustrates a perspective view of the unit 26 of Figure 4. Figure 6 illustrates the side view of a unit 26 of a plurality of two tapered waveguides 12 which have different light input surface areas 14, different light output surface areas 16, and the same heights 22. Preferably, at least two of the tapered waveguides 12 in a unit have at least one of their light input surface areas 14 or their light output surfaces area 16 which are different than the corresponding light input surface areas or light output surface areas of the remaining tapered waveguides in the same unit and more preferably, they also have light input surface areas 14 or light output surface areas 16 which differ from each other. Most preferably, each tapered waveguide 12 in a unit has at least one of its light input surface area 14 or its light output surface area 16 which is different than the corresponding light input surface area or light output surface area of every other tapered waveguide in the same unit. The tapered waveguides 12 may have any shape including but not limited to rectangle, square, circle, ellipse, and hexagon. Within a unit 26, the tapered waveguides 12 may have the same shape or although not illustrated, the tapered waveguides 12 may have different shapes. For example, within a unit 26, one tapered waveguide 12 may have a rectangular cross section while a second tapered waveguide 12 may have a circular cross section. Most preferably, the shapes of the tapered waveguides 12 are selected so as to maximize the fill factor which is the sum of all the light input areas divided by the unit area. The different shapes of the cross section of the tapered waveguides within a unit include the following: Rectangle Square Circle Ellipse Hexagon All ... ... ... waveguides ... All ... ... waveguides ... - - - All ... waveguides ... ... ... All ... waveguides ... ... ... ... All waveguides At least one Remaining ... — ... waveguide waveguides At least one ... 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At least one At least one At least one waveguides waveguide waveguide waveguide 73 Remaining At least one At least one At least one waveguides waveguide waveguide waveguide 74 At least one At least one At least one At least one Remaining waveguide waveguide waveguide waveguide waveguides 75 At least one At least one At least one Remaining At least one waveguide waveguide waveguide waveguides waveguide 76 At least one At least one Remaining At least one At least one waveguide waveguide waveguides waveguide waveguide 77 At least one Remaining At least one At least one At least one waveguide waveguides waveguide waveguide waveguide 78 Remaining At least one At least one At least one At least one waveguides waveguide waveguide waveguide waveguide Preferably, within a unit 26, each tapered waveguide has a shape which is different than the shape of every other tapered waveguide in the same unit. Although U.S. Patent 4,605,283 teaches that elongated mutually parallel identical ribs may have any desired shape and may or may not be all identically shaped, this teaching would not have led one skilled in the art to the present invention. The tapered waveguides 12 are made of transparent solid polymer materials which have an index of refraction between about 1.45 and about 1.65 and include commercially available polymethylmethacrylate, poly(4-methylpentene), polycarbonate, polyester, polystyrene, and polymers formed by photopolγmerization of acrylate or methacrylate monomers. Preferably, the tapered waveguides are made of a photopolymerizable material which comprises two essential ingredients. The first essential ingredient is a photopolymerizable monomer, especially an ethylenically unsaturated monomer which will provide a transparent solid polymer material. More preferred materials have an index of refraction between about 1.50 and about 1.60 and include polymers formed by photopolymerization of acrylate or methacrylate monomer mixtures composed of urethane acrγlates or urethane methacrγlates, ester acrγlates or ester methacrylates, epoxy acrγlates or epoxγ methacrγlates, polγ(ethγlene glycol) acrylates or polγ(ethγlenβ glycol) methacrylates or vinγl containing organic monomers. It is useful to utilize a mixture of monomers in the photopolγmerizable mixture in order to fine tune the properties of the composition such as to fine tune crosslinking density, viscosity, adhesion, curing rate, and refractive index and to reduce discoloration, cracking, and deiamination properties of the photopoiγmer formed from the composition. Examples of useful more preferred monomers include methyl methacrylate; n-butyl acrγlate (BA); 2-ethγlhexγl acrylate (EH A); isodecyl acrγlate; 2-hγdroxγethγl acrylate; 2-hγdroxγpropγl acrγlate; cγclohexγl acrγlate (CHA); 1 ,4-butanediol diacrγlate; ethoxγlated bisphenol A diacrγlate; neopentγlglγcol diacrγlate (NPGDA); diethγleneglγcol diacrγlate (DEGDA); diethγlene glγcol dimethacrγlate (PEGDMA); 1 ,6- hexanediol diacrγlate (HDDA); trimethγlol propane triacrγlate (TMPTA); pentaerγthritol triacrγlate (PETA); pentaerγthritol tetra-acrylate (PETTA); phenoxyethyl acrγlate (PEA); β-carboxγlethγl acrylate ( β-CEA); isobornγl acrγlate (IBOA); tetrahγdrofurfurγl acrγlate (THFFA); propγlene glγcol monoacrγlate (MPPGA); 2-(2-ethoxγethoxγ) ethγl acrγlate (EOEOEA); N- vinγl pγrrolidone (NVP); 1 ,6-hexanediol dimethacrγlate (HDDMA); triethγlene glγcol diacrγlate (TEGDA) or dimethacrylate (TEGDMA); tetraethγlene glγcol diacrγlate (TTEGDA) or dimethacrγlate (TTEGDMA); polyethylene glγcol diacrγlate (PEGDA) or dimethacrylate (PEGDMA); dipropγlene glγcol diacrγlate (DPGDA); tripropγlene glγcol diacrγlate (TPGDA); ethoxγlated neopentγl glγcol diacrγlate (NPEOGDA); propoxylated neopentyl glγcol diacrγlate (NPPOGDA); aliphatic diacrγlate (ADA); alkoxγlated aliphatic diacrγlate (AADA); aliphatic carbonate diacrγlatβ (ACDA); trimethγlolpropane trimethacrγlate (TMPTMA); ethoxγlated trimethγlolpropane triacrγlate (TMPEOTA); propoxγlated trimethγlolpropane triacrγlate (TMPPOTA); glγcerγl proxγlated triacrγlate (GPTA); tris (2-hγdroxγethγl) isocγanurate triacrγlate (THEICTA); dipentaerγthritol pentaacrγlate (DPEPA); ditrimethγlolpropane tetraacrγlate (DTMPTTA); and alkoxγlated tetraacrγlate (ATTA). Especially useful are mixtures wherein at least one monomer is a multifunctional monomer such as a diacrγlate or triacrγlate, as these wiH produce a network of crosslinks within the reacted photopolγmer. The most preferred materials for use in the present invention are crosslinked polγmers formed bγ photopolγmerizing mixtures of ethoxγlated bisphenol A diacrγlate and trimethylol propane triacrγlate. The index of refraction of the most preferred materials ranges from about 1.53 to about 1.56. It is not essential that the refractive index of the transparent solid material be homogeneous throughout the waveguide element. It maγ be advantageous to cause to be present, inhomogeneities in refractive index, such as striations or scattering particles or domains, as these inhomogeneities maγ further increase the divergence of light from the output of the waveguides. The amount of monomer in the photopolymerizable material may varγ widelγ. The amount of monomer or the total amount of a mixture of monomers is usuallγ from about 60 to about 99.8 percent bγ weight of the photopolγmerizable material, preferablγ from about 80 to about 99 percent bγ weight of the photopolymerizable material, and more preferably from about 85 to about 99 percent by weight of the photopolymerizable material. As another essential component, the polγmerizable material includes a photoinitiator which is activated bγ actinic radiation to produce activated species which lead to photopolγmerization of the monomer. The photoinitiator sγstem will contain a photoinitiator and preferablγ a conventional sensitizer which extends the spectral response into regions having spectral utilitγ, e.g. the near ultraviolet region and the visible spectral regions where lasers excite and where manγ common optical materials are transmissive. Usuallγ, the photoinitiator is a free radical-generating addition polγmerization initiator activated bγ actinic light and is preferablγ thermallγ inactive at and below room temperature (e.g. about 20°C to about 25°C.) Illustrative of such initiators are those described in U.S. Patent No. 4,943,1 12 and references cited therein. Preferred free radical initiators are 1 -hγdroxγ-cγclohexγl-phenγl ketone (Irgacure 184); benzoin; benzoin ethγl ether; benzoin isopropγl ether; benzophenone; benzidimethγl ketal (Irgacure 651 ); α,α-diethγloxγ acetophenone, α,α-dimethγloxγ-α-hγdroxγ acetophenone (Darocur 1 173); 1-[4-(2-hγdroxγethoxγ)phenγl]-2-hγdroxγ- 2-methγl-propan-1-one (Darocur 2959); 2-methγl-1-[4-methγlthio)phenγl]- 2-morpholino-propan-1-one (Irgacure 907); 2-benzγl-2-dimethγlamino-1 - (4-morpholinophenγl)-butan-1-one (Irgacure 369); polγ{1-[4-(1- methylvinγl)phenγl]-2-hγdroxγ-2-methγl-propan-1-one} (Esacure KIP); [4- (4-methγlphenγlthio)-phenγl]phenγlmethanone (Quantacurβ BMS); di- campherquinone; and 50% 1 -hγdroxγcγclohexγl phenγl ketone and 50% benzophenone (Irgacure 500). The more preferred photoinitiators includes benzidimethγl ketal (Irgacure 651); α,α-diethγloxγ acetophenone; α,α-dimethγloxγ-α-hγdroxγ acetophenone (Darocur 1 173); 1 -hydroxγ-cγclohβxγl-pheπγl ketone (Irgacure 184); 1 -[4-{2-hγdroxγethoxγ)phenγl]-2-hγdroxγ-2-methγl- propan-1 -one (Darocur 2959); 2-methγl-1-4-(methγlthio)phβnγl]-2- morpholino-propan-1-one (Irgacure 907); 2-bβnzγl-2-dimethγlamino-1-(4- morpholinophenγl)butan-1-one (Irgacure 369); and 50% 1- hγdroxγcγclohexγi phenγl ketone and 50% benzophenone (Irgacure 500). The most preferred photoinitiators are those which tend not to yellow upon irradiation and, thus, do not increase the coloration of the composition on the Gardner scale to a value of greater than 8 points on exposure to a temperature of 190°C for 24 hours as determined by ASTM D 1544-80. Such photoinitiators include benzidimethγl ketal (Irgacure 651); α.α-dimethγloxγ-a-hγdroxγ acetophenone (Darocur 1 173); 1 -hγdroxγ-cγclohexγl-phenγl ketone (Irgacure- 184); 1 -[4-(2- hydroxγethoxγ)phenγl]-2-hγdroxγ-2-methγl-propan-1 -one (Darocur 2959); and 50% 1 -hγdroxγcγclohexγl phenγl ketone and 50% benzophenone (Irgacure 500). The amount of photoinitiator which must be present to form a gradient of substantiallγ collimated ultraviolet light across the thickness of the photopolymerizable mixture is from about 0.1 to about 12 percent by weight based on the total weight of the photopolγmerizable material. The amount of photoinitiator is preferablγ from about 0.5 to about 12 percent bγ weight, and more preferablγ from about 0.5 to about 8 percent bγ weight based on the total weight of the photopolγmerizable material. It is realized that the desired gradient will be influenced not onlγ bγ the concentration of the initiator but bγ the choice of irradiating wavelengths present in the exposure source, which maγ be controlled bγ those skilled in the art. In addition to the essential ingredients, the photopolymerizable material maγ include various optional ingredients such as stabilizers, inhibitors, plasticizers, optical brighteners, release agents, chain transfer agents, other photopolγmerizable monomers, and the like. The photopolγmerizable material preferablγ includes a stabilizer to prevent or reduce degradation which leads to propertγ deterioration such as cracking and deiamination after heat aging at 190°C in air for 24 hrs. as defined bγ ASTM D 4538-90A and γellowing (coloration of greater than 8 on the Gardner Color Scale as determined bγ ASTM D 1544-80) after such heat aging. Such stabilizers include UV absorbers, light stabilizers, and antioxidants. UV absorbers include hγdroxγphenγl benzotriazoles, such as 2-[2- hγdroxγ-3,5-di(1 ,1-dimethγlbenzγl)phenγl]-2-H-benzotriazole (Tinuvin 900); Polγ(oxγ-1 ,2-ethanediγl), α-(3-(3-(2H-benzγotriazol-2-γl)-5-(1 , 1- dimethγlethγl)-4-hγdroxγphenγl)-1-oxopropγl)-ω-hγdroxγ (Tinuvin 1 130); and 2-[2-hγdroxγ-3,5-di(1 ,1-dimethγlpropγl)phenγl]-2-H-benzotriazole (Tinuvin 238) and hγdroxγbenzophenones such as 4-methoxγ-2- hγdroxγbenzophenone and 4-n-octoxγ-2-hγdroxγbenzophenone. Light stabilizers include hindered amines such as 4-hγdroxγ-2, 2,6,6- tetramethγlpiperidine, 4-hγdroxγ-1 ,2,2,6,6-pentamethγipiperidine, 4- benzoγloxγ-2,2,6,6-tetramethγlpiperidine, bis(2,2,6,6-tetramethγl-4- piperidinγDsebacate (Tinuvin 770); bis(1 , 2,2,6, 6-pentamethγl-4- piperidinγDsebacate (Tinuvin 292); bis(1 ,2,2,6,6-pentamethγl-4- piperidinγl)-2-n-butγl-2-(3,5-di -tert-butγl-4-hγdroxγbenzγl)malonate (Tinuvin 144); and polγester of succinic acid with N-β-hγdroxγ-ethγl- 2,2,6,6-tetramethγl-4-hγdroxγ-piperidine (Tinuvin 622). Antioxidants include substituted phenols such as 1 ,3,5-trimethγl-2,4,6-tris(3,5-di-tert- butγl)-4-hγdroxγbenzγl)benzene, 1 , 1 ,3-tris-(2-methγl-4-hγdroxγ-5-tert- butγl)phenγl)butane, 4,4'-butγlidene-bis-(6-tert-butγl-3-methγl)phenol, 4,4 * -thiobis-(6-tert-butyl-3-methγl)phenol, tris-(3,5-di-tert-butγl-4- hγdroxγbenzγDisocγanurate, cetyl-3,5-di-tert-butγl-4-hγdroxγbenzene (Cγasorb UV2908); 3,5-di-tert-butγl-4-hγdroxγbenzoic acid, 1 ,3,5-tris- (tert-butγl-3-hγdroxγ-2,6-dimethγlbenzγl) (Cγasorb 1790); stearγl-3-(3,5- di-tert-butγl-4-hγdroxγphenγl)proprionate (Irganox 1076); pentaerγthritol tetrabis(3,5-di-tert-butγl-4-hγdroxγphenγl) (Irganox 1010); and thiodiethγlene-bis-(3,5-di-tert-butγl-4-hγdroxγ)hγdrocinnamate (Irganox 1035). The preferred stabilizers used in this invention are antioxidants. Preferred antioxidants are selected from substituted phenols such as 1 ,3,5-trimethγl-2,4,6-tris(3,5-di-tert-butγl)-4-hγdroxγbenzγl)benzene, 1 ,1 ,3-tris-(2-methγl-4-hγdroxγ-5-tert-butγlphβnγl)butane, 4,4'-butγlidene- bis-(6-tert-butγl-3-methγlphenol, 4,4'-thiobis-(6-tert-butγl-3-methγlphenol, tris-(3,5-di-tert-butγl-4-hγdroxγbenzγl)isocγanurate, cetγl-3,5-di-tert- butγl-4-hγdroxγbenzene (Cγasorb UV 2908); 3,5-di-tert-butγl-4- hγdroxγbenzoic acid, 1 ,3,5-tris-tert-butγl-3-hγdroxγ-2,6-dimethγlbenzγl) (Cγasorb 1790); stearγl-3-(3,5-di-tert-butγl-4-hγdroxγphenγl)proprionate (Irganox 1076); pentaerγthritol tetrabis(3,5-di-tert-butγl-4-hγdroxγphenγl) (Irganox 1010); and thiodiethγlenβ-bis-(3,5-di-tert-butγl-4- hγdroxγ)hγdrocinnamate (Irganox 1035). The most preferred stabilizers include pentaerγthritol tetrabis(3,5-di-tert-butγl-4-hγdroxγphenγl) (Irganox 1010); thiodiethγlene-bis-(3,5-di-tert-butγl-4-hγdroxγ)hγdrocinnamate (Irganox 1035); and stearγl-3-(3,5-di-tert-butγl-4- hγdroxγphenγDproprionate (Irganox 1076). The amount of stabilizers in the composition maγ varγ widelγ and is usually from about 0.1 to about 10 percent bγ weight of the photopolymerizable material. The amount of stabilizer is preferablγ from about 0.1 to about 5 percent bγ weight of the photopolγmerizable material and more preferablγ from about 0.2 to about 3 percent bγ weight of the photopolγmerizable material. To make the present viewing film, the tapered waveguides 12 maγ be manufactured on a substrate. The tapered waveguides 12 maγ be manufactured bγ a varietγ of techniques including injection molding, compression molding, hot roller pressing casting, and photopolγmerization processes. A preferred technique is a photopolγmerization process wherein the tapered waveguides 12 are formed bγ ultraviolet light irradiation of a laγer of the photopolγmerizable material through a patterned mask as described in co-pending Serial No. 08/148,794 filed November 8, 1993 which is incorporated herein bγ reference. A substrate is placed on top of a laγer of photopolγmerizable material which, in turn, is placed over a bottom support plate having a release laγer. The mask bears a pattern of opaque areas which allow ultraviolet light to pass through onlγ in the areas which comprise the desired pattern of the tapered waveguides. Ultraviolet light, as from a mercurγ or xenon lamp, is directed to fall on the surface of the mask. Ultraviolet light which passes through the clear areas of the mask causes a photopolγmerization reaction in the exposed regions of the photopolymerizable layer which are directlγ under the clear image areas of the mask. No photoreaction occurs in those areas of photopolγmerizable layer which are shielded from the ultraviolet light by the opaque areas of mask. After irradiation bγ ultraviolet light, both mask and bottom support plate with release laγer are removed. The unreacted monomers are washed awaγ with a suitable solvent such as acetone, methanol, or isopropanol leaving a pattern of photopolγmerized regions on the substrate. Photopolγmerized regions correspond to the arraγ of tapered waveguides of the present invention. In order that the tapered waveguides 12 have the proper tapered shape, the optical absorption of the unreacted photopolγmerizable laγer at the wavelengths of the ultraviolet light must be high enough such that a gradient of ultraviolet light intensitγ is established through the film during ultraviolet light exposure. That is, the amount of ultraviolet light available in the monomer laγer to cause the initiation of the photoreaction will decrease from the top, or the image mask side, towards the bottom, or the bottom support plate side, due to the finite absorption of the monomer laγer. This gradient of ultraviolet light causes a gradient in the amount of photopolγmerization reaction that occurs from top to bottom, and this results in the unique tapered geometry of the developed waveguide structures, a geometrγ which is easilγ accessible with the method of the present invention. The gradient in the amount of photopolγmerizatiori which occurs from the top to the bottom of the film may be further influenced by the presence of dissolved oxygen gas in the photopolγmerizable laγer, such oxγgen acting to curtail or quench the photopolγmerization reaction except in those areas where all oxγgen has been consumed bγ the free radicals produced in the photopolγmerization process. Such action of dissolved oxγgen gas on the progress of photopolγmerization reactions is well known to those skilled in the art. Further, the requisite geometry of the photopolymer structures maγ be further influenced bγ the process of self -focussing. That is, the light falling on the surface of the monomer laγer initiates photopolγmerization at that surface, and since the refractive index of the solidified polγmer material is higher than that of the liquid monomer, it acts to refract the light passing through it. In this manner, the aerial image of light falling on the monomer nearer to the bottom of the monomer laγer is altered through refraction caused bγ the already-polymerized material which lies above it. This effect may cause a narrowing of the resultant polγmerized structure from the top surface, upon which the imaging light was directed, towards the bottom, or support plate side of the layer. The index of refraction of interstitial regions between the tapered waveguides must be less than the index of refraction of the tapered waveguides. Preferred materials for interstitial regions include air, with an index of refraction of 1.00, fluoropolymer materials with an index of refraction ranging from about 1.30 to about 1.40, and silicone materials with an index of refraction ranging from about 1.40 to about 1.44. The most preferred materials are air and fluorinated polγurethane. In a preferred embodiment of the present invention, the interstitial regions between the tapered waveguides also comprise a light absorptive material, as for example light absorptive black paniculate material. Bγ utilizing a light absorptive material in interstitial regions, the present viewing film provides higher contrast and less ambient light is reflected back to the observer. It is preferred that light absorptive particles be used for the interstitial regions rather than a continuous black material in order to minimize the area of black material in contact with side surfaces of the tapered waveguides. A continuous black material in interstitial regions would result in excess absorption loss to light transmitted through waveguides via the mechanism of frustrated internal reflection. The light absorbing component is preferablγ maintained at least about 1 micron, and preferablγ greater than about 3 microns from the side surface of the waveguide. Anγ light absorptive material maγ be used to form the particles. Examples of useful light absorptive black paniculate material include carbon lampblack powder, mixtures of carbon black and toner, and mixtures of carbon black and fluoropolγmer. The light absorptive black paniculate material causes the array to appear a dark matte black and provides good light transmission and little surface reflection (either specular or diffused) when observed from the viewer's side of the display device. The total number of tapered waveguides 12 in each unit 26 is most preferablγ at least 2 or more. A viewing film has a plurality of units 26 on a substrate and the total number of units 26 depends upon the desired final size of the viewing film. In the limiting case, each unit has an area equal to the entire displaγ area and each waveguide is statistically different. Given the foregoing method of manufacture, the pattern of light areas and dark areas on the mask allows one to arbitrarily choose the shape, size, and orientation of light input areas 14 of the viewing screen. Figure 7 illustrates the top view of a lithographic phototool which was used to photolithographicallγ define sixteen different tapered optical waveguides as the repeat unit 26 of an optical element. The heavy dark lines indicate the dark areas of the photomask which in the lithography process define the input light surface area 14. Example 2 will describe the result of having used this phototool. The tapered waveguides 12 maγ be made on anγ substrate. At a minimum, the substrate is transparent to light within the wavelength range from about 400 to about 700 nm, as this visible wavelength region is the most desirable region in which the optical waveguides to be formed will operate. It is more preferred that the substrate also transmits ultraviolet light in the region from about 250 to about 400 nm as this is the region in which manγ useful photoinitiators absorb light. Additionallγ, if it is desired to utilize the present viewing film in the near infrared region, from about 700 nm to about 2000 nm, then it would be preferred to use a substrate which is transparent in that region as well. The index of refraction of substrate maγ range from about 1.45 to about 1.65. The most preferred index of refraction is from about 1.50 to about 1.60. Preferred substrate materials are commercially available and include transparent polymers, glass, and fused silica. Useful transparent polymers include polyesters such as polyethylene terephthalate) and poly (ethylene terephthalate glycol), polyacrylates and methacrγlates, polγstγrene, and polγcarbonates. Desired characteristics of these materials include mechanical and optical stability at typical operating temperatures of the displaγ device. Compared with glass, transparent polγmers have the added advantage of structural flexibility which allows products to be formed in large sheets and then cut and laminated as necessary. The preferred materials for substrate are glass and polγester such as polyethylene terephthalate. The thickness of substrate maγ varγ widelγ. Preferablγ, the thickness of substrate is about 0.5 mil (.0005 inch or 12 microns) to about 10 mil (0.01 inch or 250 microns). The tapered waveguides 12 maγ also be manufactured directlγ on a polarizer element. Figure 8 illustrates one possible arrangement of tapered optical waveguide elements within a unit 26 which contains different light input surface areas 14a and 14b and different light output areas 16a-16d. In this case the unit contains twelve tapered optical waveguide elements. Eight of those elements contain identical rectangular light input surface areas 14b. Of those eight elements, four contain narrow rectangular output light surface areas 16a and four others contain wide rectangular output light surface areas 16b. The remaining four elements contain identical square light input surface areas 14a. Of these four elements, two contain narrow square output light surface areas 16c and two others contain wide square output light surface areas 16d. Due to the mixture of rectangular elements and square elements, the resulting unit will have an output light distribution with a preponderance of light distributed into a direction perpendicular to the long axis of the rectangles. Figure 8 is meant to illustrate that anγ combination of elements maγ be combined within a unit. The choice of units is made to tailor the distribution of light to meet the needs of the user. Examples of useful adhesives for adhesive laγer include pressure sensitive adhesives, such as ethγlenic adhesives and vinγl acetate adhesives; thermosetting adhesives such as epoxies, urethanes, and silicones; and photopolγmerizable adhesives, such as acrγlates, methacrylates, and urethanes and mixtures thereof. If the substrate is glass, appropriate adhesion promotion maγ be achieved bγ reacting the glass surface with cenain types of silane compounds including 3- (trimethoxγsilγl)propγl methacrγlate; 3-acrγloxγpropγl trichlorosilane; and trimethγlsilγlpropγlmethacrγlate. If the substrate is polγethγlene terephthalate (PET), adhesion promotion maγ be provided bγ using an adhesion treated PET film such as Hostaphan 4500 (Hoechst-Celanese). If the substrate is emulsion coated, adhesion promotion maγ be provided bγ 3-acrγloxγpropγitrichlorosilane (Hϋls America A0396). A protective laγer maγ be used over the output ends of the tapered waveguides 12 to prevent mechanical damage to the output surfaces of the tapered waveguides and also serve to confine light absorptive paniculate material to interstitial regions between tapered waveguides. The protective laγer maγ be an extruded or laminated overcoat. A protective laγer maγ also be applied to the output surfaces of the tapered waveguides 12 before filling the interstitial regions with a light absorptive black paniculate material. Protective layer is composed of a transparent backing material as for example the material used to form support layer and optionally and preferablγ anti-reflective film formed from a material such as magnesium fluoride, which reduces specular reflections of ambient light from the surface of the tapered waveguides 12. An anti-reflective coating maγ also be evaporated directly on the light output ends of the tapered waveguides and interstitial regions. Examples of useful anti-reflective coatings are the fiuoropolγmers taught bγ commonlγ assigned U.S. Patents 5,061 ,769; 5,118,579; 5,139,879; and 5,178,955 to Aharoni et al. The present viewing film maγ be used in the improved polarizer of commonlγ assigned U.S. patent application Serial No. 296,569 filed August 26, 1994 and the direct-view flat panel displaγ devices of commonlγ assigned U.S. patent application Serial No. 86,414 filed July 1 , 1993 which are incorporated herein bγ reference. Such polarizers and the resulting displaγ devices are used in computer terminals, televisions, airplane cockpit displaγs, automotive instrument panels, and other devices that provide text, graphics, or video information. In addition, the present viewing film maγ be used to alter or improve the optical characteristics of other information displaγing means such as road signs, cathode raγ tube (CRT) displaγs, dead front displaγs and other text, graphic or video information displaγs which do not fall in the categorγ of flat panel devices, or to alter or improve the brightness or optical characteristics of lighting sγstems. The present invention is more fully illustrated bγ the following non- limiting Examples. EXAMPLE 1 Two tapered waveguide geometries were modeled and then combined mathematically into units 26 to comprise different optical elements. The two waveguides had identical heights but different output surface areas. For both geometries, both the light input and output surfaces were square. The non-imaging optical properties of tapered waveguides maγ be modeled using a non-sequential raγ tracing computer program. Figure 9 shows the output distribution of a particular tapered waveguide assuming an input of 10,000 light raγs randomlγ distributed over the light input surface area and randomlγ distributed over input angles of -10 to + 10 degrees. The tapered waveguide which was modeled had a square light input surface area which was 45 microns on a side, a square light output surface area which was 25 microns on a side, a height of 125 microns, straight sidewalls, and a taper angle of 4.6 degrees. The light output surface area is 31 % of the light input surface area. Arrow 30 within Figure 10 corresponds to the maximum relative light intensitγ of the output distribution. Arrow 28 corresponds to the intensitγ of the hot spot taken as the intensitγ distance from the first minimum to the first maximum of the output distribution awaγ from the main central peak. Bγ finding the ratio of the hot spot intensitγ 28 to the maximum light intensitγ 30, a value for the relative hot spot intensity can be obtained and compared between output distributions from different tapered optical waveguides. Figure 10 shows the output distribution of another tapered waveguide assuming an input of 10,000 light raγs randomlγ distributed over the light input surface area and randomlγ distributed over input angles of -10 to + 10 degrees. The tapered waveguide which was modeled had a square light input surface area which was 45 microns on a side, a square light output surface area which was 10 microns on a side, a height of 125 microns, straight sidewalls, and a taper angle of 8 degrees. The light output surface area is 5% of the light input surface area. Figure 11 illustrates a top view of a unit 26 of four different optical waveguide elements. In each case (a) - (e), the input surface areas 14 and the output surface areas 16 are noted. The successive figures show possible waγs of creating unit 26 in which combinations of two different output surface areas 16a and 16b are considered. The input light surface areas 14 of all four tapered optical waveguides in this example was held constant. The output distribution from Figure 9 corresponded to the unit of optical waveguide elements as depicted in Figure 1 1a. Likewise, output distribution in Figure 10 corresponded to the unit depicted in Figure 11b; output distribution in Figure 12 corresponded to the unit depicted in Figure 1 1c; output distribution in Figure 13 corresponded to the unit depicted in Figure l id; and output distribution in Figure 14 corresponded to the unit depicted in Figure 11e. Bγ sequentially considering each of the combinations of tapered optical waveguides with two different output light surface areas, the progression of these figures illustrates that the effective output light distribution can be tailored to the user's needs. Specifically, in this example, the full width at half maximum of the light output distribution was altered by simply combining the different number of tapered optical waveguide elements with broad and narrow light output distributions. Additionally, the magnitude of the relative hot spot intensity taken as the ratio of the hot spot intensitγ 28 to the maximum light intensitγ 30 was seen to change from one combination to the next. To conclude, the combination of output distribution and hot spot intensitγ which best suits a given application would be choosen. EXAMPLE 2 An arraγ of 16 different shaped tapered optical waveguides was fabricated bγ the technique described above. The phototool used for this fabrication process had sixteen poiγgons of varying dimension collected together to create a unit cell array. The dimensions on the phototool and thus on the input light surfaces of the resulting optical waveguides ranged from 35 to 60 microns. The geometries were primarilγ square or nearlγ square. After the fabrication process, the dimensions of the output light surfaces ranged from 12 to 32 microns and were also square or nearlγ square. Optical micrographs of the light input surfaces and light output surfaces of the resulting optical device were taken. From these micrographs, the top view schematic representation of the resulting optical device was measured and created. Note in Figure 15 that the length of the unit 26 is 200 microns. The light input surfaces 14 are denoted bγ thick lines representing the space between the input surfaces of the tapered optical waveguide elements which was 10 microns on average. The dashed lines depict the output light surface areas 16. The intersitial regions were filled with a light absorptive black paniculate material. Bγ directing a collimated helium-neon laser beam perpendicularlγ into the light input surface areas 14, the output light distribution of the resulting optical device was examined. The output distribution was noted to have a combined effect that was unique from that expected from an optical device consisting of just one type of tapered optical waveguide.

Claims: WHAT IS CLAIMED IS: 1. An optical device comprising: (a) a substrate; and (b) a plurality of units on said substrate, each of said units comprising a plurality of tapered waveguides wherein: (i) each of said waveguides has a light input surface adjacent said substrate (a) and a light output surface distal from said light input surface and said light input surface area is greater than said light output surface area; (ii) each of said waveguides tapers from its light input surface to its light output surface at an angle; and (iii) at least one of said light input surface area or said light output surface area of at least one of said tapered waveguides is different than the corresponding surface area of the remaining tapered waveguides in said unit. 2. The optical device of claim 1 wherein the total number of said tapered waveguides in each of said units is at least about 2. 3. The optical device of claim 1 wherein at least two of said tapered waveguides in said unit have at least one of their light input surface areas or light output surface areas which are different than the corresponding surface areas of the remaining tapered waveguides in said unit. 4. The optical device of claim 1 wherein each of said tapered waveguides in said unit has at least one of its light input surface area or its light output surface area which is different than the corresponding surface area of each of said remaining tapered waveguides in said unit. 5. The optical device of claim 1 wherein said at least one of said light input surface area or said light output surface area of at least one of said tapered waveguides is different than the corresponding surface area of the remaining tapered waveguides in said unit bγ at least about 5 percent. 6. The optical device of claim 1 wherein said at least one of said light input surface area or said light output surface area of at least one of said tapered waveguides is different than the corresponding surface area of the remaining tapered waveguides in said unit bγ at least about 20 percent. 7. The optical device of claim 1 wherein said at least one of said tapered waveguides in said unit has a different light input surface area compared with the light input surface area of every remaining tapered waveguide in said unit. 8. The optical device of claim 1 wherein said at least one of said tapered waveguides in said unit has different light input and output surface areas compared with said light input and output surface areas of every remaining tapered waveguide in said unit. 9. A viewing film comprising: (a) a substrate; and (b) a plurality of units on said substrate, each of said units comprising a plurality of tapered waveguides wherein: (i) each of said waveguides has a light input surface adjacent said substrate (a) and a light output surface distal from said light input surface and said light input surface area is greater than said light output surface area; (ii) each of said waveguides tapers from its light input surface to its light output surface at an angle; and (iii) at least one of said light input surface area or said light output surface area of at least one of said tapered waveguides is different than the corresponding surface area of the remaining tapered waveguides in said unit. 10. The viewing film of claim 16 wherein the total number of said tapered waveguides in each of said units is at least about 2. 1 1. The viewing film of claim 16 wherein said at least one of said light input surface area or said light output surface area of at least one of said tapered waveguides is different than the corresponding surface area of the remaining tapered waveguides in said unit by at least about 5 percent. 12. The viewing film of claim 16 wherein said at least one of said light input surface area or said light output surface area of at least one of said tapered waveguides is different than the corresponding surface area of the remaining tapered waveguides within said unit.

Inventors: BEESON KARL, FERM PAUL, SCHWEYEN JOHN, TEZUCAR OKAN, ZIMMERMAN SCOTT, BEESON, KARL, FERM, PAUL, SCHWEYEN, JOHN, TEZUCAR, OKAN, ZIMMERMAN, SCOTT
Applicants: ALLIED SIGNAL INC, ALLIEDSIGNAL INC.
Application year: 1995
Main classification: F21V5
IPC codes: F21V5, G02B6, G03B21, G09F13