Biscyclopentadienyl diene complexes, their preparation and catalyst compositions containing them

Abstract: Biscyclopentadienyl, Group 4 transition metal complexes are formed by contacting a biscyclopentadienyl Group 4 metal halide, hydrocarbyl, hydrocarbyloxy or amide complex with a conjugated diene. When combined with standard activating cocatalysts or activated with an activating technique, the complexes form catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.

Description: This invention relates to activated biscyclopentadienyl and substituted bis(cyclopentadienyl)titanium, zirconium or hafnium complexes possessing diene ligands in which the metal is either in the +2 or +4 formal oxidation state and their use as catalysts for the polymerization of olefins and to methods for preparing such complexes and catalysts. The preparation and characterization of certain biscyclopentadienyl (Cp 2 ) zirconium and hafnium diene complexes is described in the following references: Yasuda, et al., Organometallics , 1982, 1 , 388 (Yasuda I); Yasuda, et al. Acc. Chem. Res., 1985, 18 120 (Yasuda II); Erker, et al., Adv. Organomet. Chem., 1985, 24 , 1 (Erker I); Erker et al. Chem. Ber., 1994, 127 , 805 (Erker II); and US-A-5,198,401. The last reference describes the use of Cp 2 Zr(diene) where the Zr is in the +4 formal oxidation state as an olefin polymerization catalyst in combination with ammonium borate cocatalysts. Biscyclopentadienyl Group 4 transition metal complexes in which the metal is in the +4 formal oxidation state, and olefin polymerization catalysts formed from such complexes by combination with an activating agent, for example, alumoxane or ammonium borate, are known in the art. Thus, US-A-3,242,099 describes the formation of olefin polymerization catalysts by the combination of biscyclopentadienyl metal dihalides with alumoxane. US-A-5,198,401 (see also below) discloses tetravalent bis-cyclopentadienyl Group 4 transition metal complexes and olefin polymerization catalysts obtained by converting such complexes into cationic form in combination with a non-coordinating anion. Particularly preferred catalysts are obtained by the combination of ammonium borate salts with the biscyclopentadienyl titanium, zirconium or hafnium complexes. Among the many suitable complexes disclosed are bis(cyclopentadienyl)zirconium complexes containing a diene ligand attached to the transition metal through σ-bonds where the transition metal is in its highest (+4) formal oxidation state. Erker et al (Chemische Berichte, vol. 115, 1982, pages 3300-3310) discloses the preparation and structural isomerism of certain bis(η 5 -cyclopentadienyl) η 4 -diene zirconium complexes and specifically refers to bis(η 5 -cyclopentadienyl)zirconium η 4 -1,3-butadiene; bis(η 5 -cyclopentadienyl)zirconium η 4 -3-methyl-1,3-butadiene; bis(η 5 -cyclopentadienyt)zirconium η 4 -2,3-dimethyl-1,3-butadiene; bis(η 5 -cyclopentadienyl)-zirconium η 4 -2,3-diphenyl-1,3-butadiene; bis(η 5 -cyclopentadienyl)zirconium η 4 - trans , - trans 2,4-hexadiene; and bis(η 5 -cyclopentadienyl)zirconium η 4 - trans,trans- 1,4-diphenyl-1,3-butadiene. Elschenbroich & Sulzer (Organometallchemie (1986) pages 262-265) discloses bis(cyclopentadienyl)zirconium(η 4 -butadiene)complexes but does not refer to ionic olefin polymerization catalysts derived from them. EP-A-0320762 discloses the preparation of silanediyl bisindenyl hafnium, titanium or zirconium halides (R 1 R 2 Si(indenyl) 2 M 2 halogen 2 ; M 2 = Hf, Ti or Zr) as the virtually pure racemate by reacting the corresponding silanediyl bisindenyl alkali metal compound (R 1 R 2 Si(indenyl) 2 M 1 2 ; M 1 = alkali metal) with a titanium, zirconium or hafnium tetrahalide. US-A-5198401 refers generally to ionic olefin polymerization catalysts having a cation derived from a bis(cyclopentadienyl) Group IV-B metal complex, in which the metal is in the +3 or +4 formal oxidation state, and a non-coordinating anion. It refers generally to olefin, diolefin or aryne ligand substituted bis(cyclopentadienyl)hafnium, titanium or zirconium compounds and specifically to bis(cyclopentadienyl) (1,3-butadiene)-zirconium, bis(cyclopentadienyl)(2,3-dimethyl-1,3-butadiene) zirconium, and bis(pentamethylcyclopentadienyl) (benzyne)zirconium. Example 43 discloses an ethylene polymerization catalyst prepared from bis(cyclopentadienyl)zirconium (2,3-dimethyl-1,3-butadiene) and tri(n-butyl)ammonium tetra(pentafluorophenyl)boron and Example 45 discloses an ethylene polymerization catalyst prepared from bis(cyclopentadienyl)hafnium (2,3-dimethyl-1,3-butadiene) and tri(n-butyl)ammonium tetra(pentafluorophenyl)boron. EP-A-0561479 corresponds in part to US-A-5198401 and discloses ionic Group IV-B metallocene catalysts having a bis(cyclopentadienyl)metal cation and a non-coordinating anion. As in the case of D2, D5 refers generally to olefin, diolefin or aryne ligand substituted bis(cyclopentadienyl)hafnium, titanium or zirconium compounds and specifically to bis(cyclopentadienyl)(1,3-butadiene)zirconium, bis(cyclopentadienyl)(2,3-dimethyl-1,3-butadiene)zirconium, and bis(pentamethylcyclopentadienyl)-(benzyne)zirconium. Examples 43 & 45 are identical with Examples 43 & 45 respectively of US-A-5198401. US-A-5272236 discloses the use of constrained geometry catalysts to prepare novel linear olefin polymers. Specified catalysts include ionic complexes of the formulae in which M can be Hf, Ti or Zr; Cp is an optionally substituted cyclopentadienyl group bound in an η 5 bonding mode to M; Z comprises boron, or a Group 14 element, and optionally sulfur or oxygen, and optionally Cp and Z together form a fused ring system; X is an anionic ligand group or neutral Lewis base ligand; n is 0, 1, 2, 3, or 4 and is 2 less than the valence of M; and A + is a noncoordinating, compatible anion. EP-A-0687682 (published 20th December 1995) discloses certain zwitterionic neutral transition metal compounds for use as components for olefin polymerization catalysts. These compounds are represented by the formula: in which each L independently is a π-ligand or an electron donor; n is 1, 2, 3 or 4; M can be Hf, Ti or Zr; X is a heteroatom or a hydrocarbon group; B is a hydrocarbon group ; A is Group Ib, IIb, IIIa, IIIb, IVa, Va, Vb, VIb, Vllb or VIIIb metal; each R 1 independently is a perhalogenated hydrocarbon; and m is 1, 2, 3, 4 or 5. L preferably is (optionally substituted) cyclopentadienyl. B and/or X can be alkenyl or arylalkenyl and specific reference is made to X being π-allyl or σ-allyl. Exemplified complexes include bis(cyclopentadienyl)zirconium(η 4 -butadiene)][tris(pentafluorophenyl)borate]; bis(methylcyclopentadienyl)zirconium(η 4 -butadiene)][tris(pentafluorophenyl)borate]; bis(n-butylcyclopentadienyl)zirconium(η 4 -butadiene)][tris(pentafluorophenyl)borate]; bisindenylzirconium(η 4 -butadiene)][ tris(pentafluorophenyl)borate]; bis(2-methylbenzoindenyl) zirconium(η 4 -butadiene)][tris(pentafluorophenyl)borate]; and 4-(η 5 -cyclopentadienyl)-4,7,7-trimethyl-(η 5 -4,5,6,7-tetrahydroindenyl)zirconium (η 4 -butadiene)][tris(pentafluorophenyl)borate]. The introduction to EP-A-0687682 acknowledges EP-A-0558158 and US-A-5198401 and reports that salts of the formula [Cp 2 Zr―R―RH] + [B(C 6 F 5 ) 4 ] - are formed after protonolysis of CP 2 MR 2 (in which R are alkyl radicals cyclically bonded to one another), for example Cp 2 Zr(2,3-dimethyl-1,3-butadiene). The present invention provides novel olefin polymerization catalysts which can be employed over a wide range of physical conditions and with a wide range of olefin monomers and combinations of such monomers, thus providing an outstanding opportunity of tailor making polyolefins having specifically desired properties. In one aspect, the present invention provides compositions of matter comprising (1) a metal complex containing two cyclopentadienyl groups or substituted cyclopentadienyl groups, said complex corresponding to the formula: CpCp'MD wherein: M is titanium, zirconium or hafnium in the +2 or +4 formal oxidation state; Cp and Cp' are each substituted or unsubstituted cyclopentadienyl groups bound in an η 5 bonding mode to the metal, said substituted cyclopentadienyl group being substituted with from one to five substituents independently selected from hydrocarbyl, silyl, germyl, halo, cyano, hydrocarbyloxy, and mixtures thereof, said substituent having up to 20 nonhydrogen atoms, or optionally, two such substituents (except cyano or halo) together cause Cp or Cp' to have a fused ring structure; D is a stable, conjugated terminally C 1-10 hydrocarbyl substituted 1, 3-butadiene, or a stable, conjugated diene substituted with one or more silyl groups, hydrocarbylsilyl groups, silylhydrocarbyl groups, or mixtures thereof, said D having up to 40 nonhydrogen atoms and forming a π-complex with M when M is in the +2 formal oxidation state, and forming a σ-complex with M when M is in the +4 formal oxidation state; said complex having been activated by use of (2) a cocatalyst or activating technique selected from: 2a) strong Lewis acids; 2b) oxidizing salts corresponding to the formula: (Ox e+ ) d (A d- ) e wherein Ox e+ is a cationic oxidizing agent having a charge of e+; e is 1 or 2; A is a noncoordinating compatible anion having a charge of d-; and d is an integer from 1 to 3; 2c) carbenium salts corresponding to the formula: © + A - wherein © + is a C 1 -C 20 carbenium ion; and A - is a noncoordinating compatible anion having a charge of -1; 2d) an activating technique comprising electrolyzing the metal complex under bulk electrolysis conditions in the presence of an electrolyte of the general formula G + A - wherein A - is a noncoordinating compatible anion having a charge of -1; and G + is a cation which is non-reactive towards the starting and resulting complex; 2e) polymeric or oligomeric alumoxanes; 2f) salts of a silylium ion and a noncoordinating, compatible anion represented by the formula R# 3 Si(X#) s + A - wherein R# is C 1-20 hydrocarbyl, s is 0 or 1, X# is a neutral Lewis base, and A - is as previously defined; and 2g) Bronsted acid salts having the formula (L-H) + d (A) d- wherein L is a neutral Lewis base; (LH) + is a Bronsted acid; A is a noncoordinating compatible anion having a charge of d-; and d is an integer from 1 to 3; with the proviso that when the cocatalyst is a Bronsted acid salt of 2g), then D has 5 to 40 carbon atoms and is π-bonded to the transition metal; and M is titanium, zirconium or hafnium in the +2 formal oxidation state. In the diene complexes in which M is in the +2 formal oxidation state, the diene is associated with M as a π-complex in which the diene normally assumes an s-trans configuration or an s-cis configuration in which the bond lengths between M and the four carbon atoms of the conjugated diene are nearly equal (Δd as defined hereafter ≥ -0.15 Å) whereas in the complexes in which M is in the +4 formal oxidation state, the diene is associated with the transition metal as a σ-complex in which the diene normally assumes a s -cis configuration in which the bond lengths between M and the four carbon atoms of the conjugated diene are significantly different (Δd < -0.15 Å). The formation of the complex with M in either the +2 or +4 formal oxidation state depends on the choice of the diene, the specific metal complex and the reaction conditions employed in the preparation of the complex. The complexes wherein the diene is π-bound and M is in the +2 formal oxidation state constitute the preferred complexes of the present invention. The CpCp'MD complexes are prepared by the reaction of the biscyclopentadienyl dihydrocarbyl, dihydrocarbyloxy, dihalide or diamide Group 4 metal complexes wherein the metal is in the +4 or +3 formal oxidation state, with a diene, D, and a reducing agent. The use of a reducing agent is optional when starting with biscyclopentadienyl dihydrocarbyl complexes. Stated more particularly, the diene metal complexes may be formed by reacting in any order the following components: 1) a complex of the formula: CpCp'M*X or CpCp'M**X 2 wherein; Cp and Cp' are as previously defined; M* is titanium, zirconium or hafnium in the +3 formal oxidation state; M** is titanium, zirconium or hafnium in the +4 formal oxidation state; and X is a C 1-6 hydrocarbyl, halide, C 1-6 hydrocarbyloxy or di-C 1-6 hydrocarbylamide group; 2) a diene corresponding to the formula, D; and 3) optionally when X is C 1-6 hydrocarbyl, otherwise, not optionally, a reducing agent. Uniquely, the process when used with diastereomeric mixtures of rac and meso isomers of metallocenes, can result in formation of only the rac diene metal complex. The metal complexes wherein the metal is in the +2 formal oxidation state are preferred in the formation of the novel catalysts of this invention. According to the present invention there is also provided a polymerization process comprising contacting one or more addition polymerizable monomers and particularly one or more α-olefins with an aforementioned activated catalyst. Generally speaking, the present diene containing complexes are more soluble in hydrocarbon solvents compared to the corresponding dihalide complexes and they are more stable to reductive elimination and other side reactions than are the corresponding dihydrocarbyl complexes. Catalyst systems comprising such diene containing complexes are accordingly better adapted to commercial use than are such alternative systems. All reference to the Periodic Table of the Elements herein shall refer to the Periodic Table of the Elements, published and copyrighted by CRC Press, Inc., 1989. Also, any reference to a Group or Groups shall be to the Group or Groups as reflected in this Periodic Table of the Elements using the IUPAC system for numbering groups. Useful dienes, D, are dienes that do not decompose under reaction conditions used to prepare the complexes of the invention. Under subsequent polymerization conditions, or in the formation of catalytic derivatives of the present complexes, the diene group, D, may undergo chemical reaction or be replaced by another ligand. The complexes of the present invention wherein M is in the +2 formal oxidation state contain a neutral diene ligand which is coordinated via π-complexation through the diene double bonds, and not through a metallocycle resonance form containing σ-bonds. The nature of the diene bond to the metal is readily determined by X-ray crystallography or by NMR spectral characterization according to the techniques of Yasuda I, Yasuda II, and Erker I, supra, as well as the references cited therein. By the term "π-complex" is meant both the donation and back acceptance of electron density by the ligand are accomplished using ligand π-orbitals, that is, the diene is π-bound (π-bound diene). Encompassed within the scope of the present invention also are activated complexes containing a diene ligand which is coordinated formally as a metallocycle containing σ-bonds (σ-bound diene) where the metal is in the +4 formal oxidation state. Such Group 4 metal σ-bound diene complexes have a structure which is formally for example a metallocyclopentene wherein the bonding between the metal and the diene (depicted as structure i) can be described as a divalent 2-butene-1,4-diyl σ-bonded to a tetravalent metal, optionally containing a single π-bond involving the π electrons between internal carbons of the conjugated diene. Such structures are depicted as structure ii and structure iii as follows: The nomenclature for such σ-bound diene complexes can be either as a metallocyclopentene (referring to the compounds as 2-butane-1,4-diyl compounds) or generically as the parent diene, for example, butadiene. Those of skill in the art will recognize the interchangability of these names. For example, the prior art biscyclopentadienyl zirconium complex containing a σ-bound 2,3-dimethyl-1,3-butadiene group would be named either bis-cyclopentadienyl 2-butene-2,3-dimethyl-1,4-diyl zirconium or bis-cyclopentadienyl 2,3-dimethyl-1,3-butadiene zirconium. A suitable method of determining the existence of a π- or σ-complex in conjugated diene containing metal complexes is the measurement of metal-carbon atomic spacings for the four carbons of the conjugated diene using common X-ray crystal analysis techniques. Measurements of atomic spacings between the metal and C1, C2, C3, and C4 (M-C1, M-C2, M-C3, M-C4, respectively) (where C1 and C4 are the terminal carbons of the 4 carbon conjugated diene group and C2 and C3 are the Internal carbons of the 4 carbon conjugated diene group) may be made. If the difference between these bond distances, Δd, using the following formula: is greater than or equal to -0.15 Å, the diene is considered to form a π-complex with M and M is formally in the +2 oxidation state. If Δd is less than -0.15 Å, the diene is considered to form a σ-complex with M and M is formally in the +4 oxidation state. Examples wherein the above method for determination of π-complexes has been applied to prior art compounds are found in Erker, et al., Angew. Chem. Int. Ed. Eng. , 1984, 23 , 455-456 (Erker III) and Yamamoto, et al, Organometallics, 1989, 8 , 105-119. In the former reference (η 3 -allyl)(η 4 -butadiene)(η 6 -cyclopenta-dienyl)zirconium was crystallographically characterized. The M-C1 and M-C4 distances were both 2.360 (±.005) Å. The M-C2 and M-C3 distances were both 2.463 (±.005) Å, giving a Δd of -0.103Å. In the latter reference (η 5 -pentamethylcyclopentadienyl)(η 4 -1,4-diphenyl-1,3-butadiene)titanium chloride was shown to have M-C1 and M-C4 distances of 2.233 (±.006) Å. The M-C2 and M-C3 distances were both 2.293 (±.005) Å, giving a Δd of -0.060Å. Accordingly, these two complexes contain π-bound diene ligands and the metal of each is in the +2 formal oxidation state. Erker I also disclosed bis(cyclopentadienyl)zirconium (2,3-dimethyl-1,3-butadiene). In this complex the M-C1 and M-C4 distances were 2.300 Å. The M-C2 and M-C3 distances were both 2.597 A, giving a Δd of -0.297Å. Accordingly, this complex contains a π-bound diene and the zirconium is in the +4 formal oxidation state. In the use of such X-ray crystal analysis techniques at least "good" and preferably "excellent" determination quality as defined by G. Stout et al., X-ray Structure Determination. A Practical Guide. MacMillan Co., pp. 430-431 (1968) is used. Alternatively, complexes of the present invention wherein X is a conjugated diene in the form of a π-complex and M is in the +2 formal oxidation state are identified using nuclear magnetic resonance spectroscopy techniques. The teachings of Erker, I to III, supra. C. Krüger, et al. Organometallics , 4, 215-223, (1985), and Yasuda I, supra, disclose these well known techniques for distinguishing between π-bound complexes and metallocyclic coordination or σ-bound diene complexes. It is to be understood that the present complexes may be formed and utilized as a mixture of the π-complexed and σ-complexed diene compounds where the metal centers are in the +2 or +4 formal oxidation state. Preferably the complex in the +2 formal oxidation state is present in a molar amount from 0.1 to 100.0 percent, more preferably in a molar amount from 10 to 100.0 percent, most preferably in a molar amount from 60 to 100.0 percent. Techniques for separation and purification of the complex in the +2 formal oxidation state from the foregoing mixtures are known in the art and disclosed for example in the previously mentioned Yasuda, I, supra, and Erker, I to III, supra, references and may be employed if desired to prepare and isolate the complexes in greater purity. The metal complexes used to form the diene complexes of the present invention are the bis(cyclopentadienyl) dihalides, dihydrocarbyls, diamides and dialkoxides which have heretofore been employed in the formation of metallocene complexes, or which are readily prepared using well known synthetic techniques. An extensive list of biscyclopentadienyl complexes is disclosed in US-A-5,198,401. Preferred complexes for use in the present invention correspond to the formula: wherein: M is titanium, zirconium or hafnium, preferably zirconium or hafnium, in the +2 or +4 formal oxidation state; R' and R" in each occurrence are independently selected from hydrogen, hydrocarbyl, silyl, germyl, cyano, halo and combinations thereof, said R' and R" having up to 20 non-hydrogen atoms each, or adjacent R' groups and/or adjacent R" groups (when R' and R" are not hydrogen, halo or cyano) together form a divalent derivative (that is, a hydrocarbadiyl, siladiyl or germadiyl group); and D is a stable, conjugated terminally C 1-10 hydrocarbyl substituted 1, 3-butadiene or a stable, conjugated diene substituted with one or more silyl groups, hydrocarbylsilyl groups, silylhydrocarbyl groups, or mixtures thereof, said D having up to 40, preferably up to 30, non-hydrogen atoms, which forms a π-complex with M when M is in the +2 formal oxidation state and a σ-complex with M when M is in the +4 formal oxidation state. Preferably, R' and R" independently in each occurrence are selected from hydrogen, methyl, ethyl, and all isomers of propyl, butyl, pentyl and hexyl, as well as cyclopentyl, cyclohexyl, norbornyl, benzyl, and trimethyl silyl, or adjacent R' groups and/or adjacent R" groups on each cyclopentadienyl ring (except hydrogen) are linked together thereby forming a fused ring system such as an indenyl, 2-methyl-4-phenylindenyl, 2-methyl-4-naphthylindenyl, tetrahydroindenyl, fluorenyl, tetrahydrofluorenyl, or octahydrofluorenyl group. Examples of suitable D moieties include: η 4 -1,4-diphenyl-1,3-butadiene; η 4 -1-phenyl-1,3-pentadiene; η 4 -1,4-dibenzyl-1,3-butadiene; η 4 -2,4-hexadiene; η 4 -1,4-ditolyl-1,3-butadiene; and η 4 -1,4-bis(trimethylsilyl)-1,3-butadiene. Of the foregoing 1,4-diphenyl-1,3-butadiene, 1-phenyl-1,3-pentadiene, and 2,4 hexadiene, i.e., the terminally di-C 1-10 hydrocarbyl substituted 1,3-dienes generally form π-complexes, whereas the solely internally C 1-10 hydrocarbyl substituted 1,3-dienes, such as isoprene or 2,3-dimethyl butadiene generally form σ-complexes. Preferred dienes are terminally C 1-10 hydrocarbyl substituted 1,3-butadienes, 2,4-hexadiene, 1-phenyl-1,3-pentadiene, 1,4-diphenylbutadiene or 1,4-ditolylbutadiene. Examples of the above metal complexes where the metal is titanium, zirconium or hafnium and preferably zirconium or hafnium include: bis(η 5 -cyclopentadienyl)zirconium s -trans(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene),, (bis-η 5 -cyclopentadienyl)zirconium η 4 -1,4-ditolyl-1,3-butadiene, bis(-η 5 -cyclopentadienyl)zirconium η 4 -2,4-hexadiene, bis(η 5 -cyclopentadienyl)zirconium η 4 -3-methyl-1,3-pentadiene, bis(η 5 -cyclopentadienyl)zirconium η 4 -1-phenyl-1,3-pentadiene, bis(pentamethyl-η 5 -cyclopentadienyl)zirconium η 4 -1,4-diphenyl-1,3 butadiene, bis(pentamethyl-η 5 -cyclo-pentadienyl)zirconium η 4 -1,4-dibenzyl-1,3-butadiene, bis(pentamethyl-η 5 -cyclopentadienyl)zirconium η 4 -2,4-hexadiene, bis(pentamethyl-η 5 -cyclopentadienyl)zirconium η 4 -3-methyl-1,3-pentadiene, bis(ethyltetramethyl-η 5 -cyclopentadienyl)zirconium η 4 -1,4-diphenyl-1,3-butadiene, bis(ethyltetramethyl-η 5 -cyclopentadienyl)zirconium η 4 -1,4-dibenzyl-1,3-butadiene, bis(ethyltetramethyl-η 5 -cyclopentadienyl)zirconium η 4 -2,4-hexadiene, bis(ethyltetramethyl-η 5 -cyclopentadienyl)zirconium η 4 -3-methyl-1,3-pentadiene, (pentamethyl-η 5 -cyclopentadienyl), (η 5 -cyclopentadienyl)zirconium η 4 -1,4-dibenzyl-1,3-butadiene, (pentamethyl-η 5 -cyclopentadienyl), (η 5 -cyclopentadienyl)zirconium η 4 -2,4-hexadiene, bis(t-butyl-η 5 -cyclopentadienyl)-1,2-zirconium η 4 -1,4-diphenyl-1,3-butadiene, bis(t-butyl-η 5 -cyclopentadlenyl)-zirconium η 4 -1,4-dibenzyl-1,3-butadiene, bis(t-butyltetramethyl-η 5 -cyc1opentadienyl)-zirconium η 4 -2,4-hexadiene, η 5 -cyclopentadienyl, (tetramethyl-η 5 -cyclopentadienyl)-zirconium η 4 -3-methyl-1,3-pentadiene, bis(pentamethyl-η 5 -cyclopentadienyl)zirconium η 4 -1,4-diphenyl-1,3-butadiene, bis(pentamethyl-η 5 -cyclopentadienyl)zirconium η 4 -1-phenyl-1,3-pentadiene, bis-(tetramethyl-η 5 -cyclopentadienyl)zirconium η 4 -3-methyl-1,3-pentadiene, bis(methyl-η 5 -cyclopentadienyl)zirconium η 4 -1,4-diphenyl-1,3-butadiene, bis(η 5 -cyclopentadienyl)zirconium η 4 -1,4-dibenzyl-1,3-butadiene, bis(trimethyl-silyl-η 5 -cyclopentadienyl)zirconium η 4 -2,4-hexadiene, bis(trimethylsilyl-η 5 -cyclopentadienyl)-zirconium η 4 -3-methyl-1,3-pentadiene, (η 5 -cyclopentadienyl)(trimethylsilyl-η 5 -cyclopentadienyl)zirconium η 4 -1,4-diphenyl-1,3-butadiene, (η 5 -cyclopentadienyl)(trimethylsilyl-η 5 -cyclopentadienyl)zirconium η 4 -1,4-dibenzyl-1,3-butadiene, (trimethylsilyl-η 5 -cyclopentadienyl)-(pentamethyl-η 5 -cyclopentadienyl)zirconium η 4 -2,4-hexadiene, bis(benzyl-η 5 -cyclopentadienyl)zirconium η 4 -3-methyl-1,3-pentadiene, bis(η 5 -indenyl)zirconium η 4 -1,4-diphenyl-1,3-butadiene, bis(η 5 -indenyl)zirconium η 4 -1,4-dibenzyl-1,3-butadiene, bis(η 5 -indenyl)zirconium η 4 -2,4-hexadiene, bis(η 5 -indenyl)-zirconium η 4 -3-methyl-1,3-pentadiene, bis(η 5 -fluorenyl)zirconium η 4 -1,4-diphenyl-1,3-butadiene, (pentamethylcyclopentadienyl)(η 5 -fluorenyl)zirconium η 4 -1-phenyl-1,3-pentadiene, bis(η 5 -fluorenyl)zirconium η 4 -1,4-dibenzyl-1,3-butadiene, bis(η 5 -fluorenyl)-zirconium η 4 -2,4-hexadiene, and bis(η 5 -fluorenyl)zirconium η 4 -3-methyl-1,3-pentadiene. In general, the complexes use in the present invention can be prepared by combining a diene compound, corresponding to the group D in the resulting complex, with a metal complex containing only hydrocarbyl leaving groups. Heating the solution, for example use of boiling toluene, may expedite the reaction. In the event the metal complex contains hydrocarbyloxy, amide or halogen ligands (and otherwise containing the desired structure of the resulting complexes) and optionally when the metal complex contains only hydrocarbyl leaving groups, the metal complex, the diene, or the above mixture of metal complex and diene, is also contacted with a reducing agent. The process preferably is conducted in a suitable noninterfering solvent at a temperature from -100°C to 300°C, preferably from -78 to 130°C, most preferably from -10 to 120°C. Metal complexes in either the +4 or +3 formal oxidation state may be utilized. By the term "reducing agent" as used herein is meant a metal or compound which, under reducing conditions can cause the transition metal to be reduced from the +4 or +3 formal oxidation state to the +2 formal oxidation state. The same procedure is employed for the preparation of the diene complexes where M is in the +2 formal oxidation state or in the +4 formal oxidation state, the nature of formal oxidation state of M in the complex being formed being primarily determined by the diene employed. Examples of suitable metal reducing agents are alkali metals, alkaline earth metals, aluminum, zinc and alloys of alkali metals or alkaline earth metals such as sodium/mercury amalgam and sodium/potassium alloy. Specific examples of suitable reducing agent compounds are sodium naphthalenide, potassium graphite, lithium alkyls, aluminum trialkyls and Grignard reagents. Most preferred reducing agents are the alkali metals or alkaline earth metals, C 1-6 alkyl lithium, tri C 1-6 alkyl aluminum and Grignard reagents, especially lithium, n-butyl lithium and triethyl aluminum. The use of a C 1-6 alkyl lithium or triethylaluminum reducing agent is especially preferred. Highly preferred diene compounds are 1,3-pentadiene; 1,4-diphenyl-1,3-butadiene; 1-phenyl-1,3-pentadiene; 1,4-dibenzyl-1,3-butadiene; 2,4-hexadiene; 3-methyl-1,3-pentadiene; 1,4-ditolyl-1,3-butadiene; and 1,4-bis-(trimethylsilyl)-1,3-butadiene. All geometric isomers of the foregoing diene compounds may be utilized. Suitable reaction media for the formation of the complexes are aliphatic and aromatic hydrocarbons and halohydrocarbons, ethers, and cyclic ethers. Examples include straight and branched-chain hydrocarbons such as isobutane, butane, pentane, hexane, heptane, octane, and mixtures thereof; cyclic and alicyclic hydrocarbons such as cyclohexane, cycloheptane, methylcyclohexane, methylcycloheptane, and mixtures thereof; aromatic and hydrocarbyl-substituted aromatic compounds such as benzene, toluene, xylene, C 1-4 dialkyl ethers, C 1-4 dialkyl ether derivatives of (poly)alkylene glycols, and tetrahydrofuran. Mixtures of the foregoing list of suitable solvents are also suitable. The recovery procedure involves separation of the resulting byproducts and devolatilization of the reaction medium. Extraction into a secondary solvent may be employed if desired. Alternatively, if the desired product is an insoluble precipitate, filtration or other separation technique may be employed. The complexes are rendered catalytically active by combination with one or more activating cocatalysts, by use of an activating technique, or a combination thereof. Suitable activating cocatalysts for use herein include polymeric or oligomeric alumoxanes, especially methylalumoxane, triisobutyl aluminum modified methylalumoxane, or diisobutylalumoxane; strong Lewis acids (the term "strong Lewis acid" as used herein is defined as trihydrocarbyl substituted Group 13 compounds, especially tri(hydrocarbyl)aluminum- or tri(hydrocarbyl)boron compounds and halogenated derivatives thereof, having from 1 to 10 carbons in each hydrocarbyl or halogenated hydrocarbyl group, more especially perfluorinated tri(aryl)boron compounds, and most especially tris(pentafluorophenyl)borane); amine, phosphine, aliphatic alcohol and mercaptan adducts of halogenated tri(C 1-10 hydrocarbyl)boron compounds, especially such adducts of perfluorinated tri(aryl)boron compounds; nonpolymeric, ionic, compatible, noncoordinating, activating compounds (including the use of such compounds under oxidizing conditions); bulk electrolysis (explained in more detail hereinafter); and combinations of the foregoing activating cocatalysts and techniques. The foregoing activating cocatalysts and activating techniques have been previously taught with respect to different metal complexes in the following references: EP-A-0277003, US-A-5,153,157, US-A-5,064,802, EP-A-0468651, EP-A-0520732, and WO-A-9303250. Combinations of strong Lewis acids, especially the combination of a trialkyl aluminum compound having from 1 to 4 carbons in each alkyl group and a halogenated tri(hydrocarbyl)boron compound having from 1 to 10 carbons in each hydrocarbyl group, especially tris(pentafluorophenyl)borane; further combinations of such strong Lewis acid mixtures with a polymeric or oligomeric alumoxane; and combinations of a single strong Lewis acid, especially tris(pentafluorophenyl)borane with a polymeric or oligomeric alumoxane are especially desirable activating cocatalysts. When utilizing such strong Lewis acid cocatalysts to polymerize higher α-olefins, especially propylene, to form homopolymers thereof, it has been found especially desirable to also contact the catalyst/cocatalyst mixture with a small quantity of ethylene or hydrogen (preferably at least one mole of ethylene or hydrogen per mole of metal complex, suitably from 1 to 100,000 moles of ethylene or hydrogen per mole of metal complex). This contacting may occur before, after or simultaneously to contacting with the higher α-olefin. If the foregoing Lewis acid activated catalyst compositions are not treated in the foregoing manner, either extremely long induction periods are encountered or no polymerization at all results. The ethylene or hydrogen may be used in a suitably small quantity such that no significant affect on polymer properties is observed. For example, polypropylene having physical properties equal to or superior to polypropylene prepared by use of other metallocene catalyst systems is prepared according to the present invention. Thus the invention further comprises an activated polymerization catalyst system comprising in combination: a) a metal complex corresponding to the formula: CpCp'MD wherein: M, Cp, Cp', and D are as previously defined, b) a Lewis acid, and c) ethylene or hydrogen, the quantity of ethylene or hydrogen being at least equal to the quantity necessary to activate the catalyst system for polymerization of a C 3 or higher α-olefin, preferably at least 1 mole per mole of metal complex, more preferably from 1 to 100,000 moles per mole of metal complex. The technique of bulk electrolysis involves the electrochemical oxidation of the metal complex under electrolysis conditions in the presence of a supporting electrolyte comprising a noncoordinating, inert anion. In the technique, solvents, supporting electrolytes and electrolytic potentials for the electrolysis, are used such that electrolysis byproducts that would render the metal complex catalytically inactive are not substantially formed during the reaction. More particularly, suitable solvents are materials that are liquids under the conditions of the electrolysis (generally temperatures from 0 to 100°C), capable of dissolving the supporting electrolyte, and inert. "Inert solvents" are those that are not reduced or oxidized under the reaction conditions employed for the electrolysis. It Is generally possible in view of the desired electrolysis reaction to choose a solvent and a supporting electrolyte that are unaffected by the electrical potential used for the desired electrolysis. Preferred solvents include difluorobenzene (ortho, meta, or para isomers), dimethoxyethane, and mixtures thereof. The electrolysis may be conducted in a standard electrolytic cell containing an anode and cathode (also referred to as the working electrode and counter electrode respectively). Suitable materials of construction for the cell are glass, plastic, ceramic and glass coated metal. The electrodes are prepared from inert conductive materials, by which are meant conductive materials that are unaffected by the reaction mixture or reaction conditions. Platinum or palladium are preferred inert conductive materials. Normally an ion permeable membrane such as a fine glass frit separates the cell into separate compartments, the working electrode compartment and counter electrode compartment. The working electrode is Immersed in a reaction medium comprising the metal complex to be activated, solvent, supporting electrolyte, and any other materials desired for moderating the electrolysis or stabilizing the resulting complex. The counter electrode is immersed in a mixture of the solvent and supporting electrolyte. The desired voltage may be determined by theoretical calculations or experimentally by sweeping the cell using a reference electrode such as a silver electrode immersed in the cell electrolyte. The background cell current, the current draw in the absence of the desired electrolysis, is also determined. The electrolysis is completed when the current drops from the desired level to the background level. In this manner, complete conversion of the initial metal complex can be easily detected. Suitable supporting electrolytes are salts comprising a cation and an inert, compatible, noncoordinating anion, A - . Preferred supporting electrolytes are salts corresponding to the formula: G + A - wherein: G + is a cation which is nonreactive towards the starting and resulting complex; and A - is a noncoordinating, compatible anion. Examples of cations, G + , include tetrahydrocarbyl substituted ammonium or phosphonium cations having up to 40 nonhydrogen atoms. A preferred cation is the tetra-n-butylammonium cation. During activation of the complexes of by bulk electrolysis the cation of the supporting electrolyte passes to the counter electrode and A - migrates to the working electrode to become the anion of the resulting oxidized product. Either the solvent or the cation of the supporting electrolyte is reduced at the counter electrode in equal molar quantity with the amount of oxidized metal complex formed at the working electrode. Preferred supporting electrolytes are tetrahydrocarbylammonium salts of tetrakis(perfluoro-aryl) borates having from 1 to 10 carbons in each hydrocarbyl group, especially tetra-n-butylammonium tetrakis(pentafluorophenyl) borate. Suitable compounds useful as an activating cocatalyst in one embodiment of the present invention comprise a cation which is a Bronsted acid capable of donating a proton, and an inert, compatible, noncoordinating, anion, A - . Preferred anions are those containing a single coordination complex comprising a charge-bearing metal or metalloid core which anion is capable of balancing the charge of the active catalyst species (the metal cation) which is formed when the two components are combined. Also, said anion should be sufficiently labile to be displaced by olefinic, diolefinic and acetylenically unsaturated compounds or other neutral Lewis bases such as ethers or nitriles. Suitable metals include, but are not limited to, aluminum, gold and platinum. Suitable metalloids include, but are not limited to, boron, phosphorus, and silicon. Compounds containing anions which comprise coordination complexes containing a single metal or metalloid atom are, of course, well known and many, particularly such compounds containing a single boron atom in the anion portion, are available commercially. Therefore, said single boron atom compounds are preferred. Preferably such cocatalysts may be represented by the following general formula: (L * -H) + d (A d- ) wherein: L * is a neutral Lewis base; (L * -H) + is a Bronsted acid; A d- is a noncoordinating, compatible anion having a charge of d-, and d is an integer from 1 to 3. More preferably A d- corresponds to the formula: (M' k+ Q n ) d- wherein: k is an integer from 1 to 3; n is an integer from 2 to 6; n-k = d; M' is an element selected from Group 13 of the Periodic Table of the Elements; and Q independently each occurrence is selected from hydride, dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, and halosubstituted-hydrocarbyl radicals, said Q having up to 20 carbons with the proviso that in not more than one occurrence is Q halide. In a more preferred embodiment, d is one, that is the counter ion has a single negative charge and corresponds to the formula A - . Activating cocatalysts comprising boron which are particularly useful in the preparation of catalysts of this invention may be represented by the following general formula: (L * -H) + (BQ' 4 ) - wherein: L * is as previously defined; B is boron in a valence state of 3; and Q' is a fluorinated C 1-20 hydrocarbyl group. Most preferably, Q' is in each occurrence a fluorinated aryl group, especially a pentafluorophenyl group. Illustrative, but not limiting examples of boron compounds which may be used as an activating cocatalyst in the preparation of the improved catalysts of this invention are tri-substituted ammonium salts such as: trimethylammonium tetraphenylborate, triethylammonium tetraphenylborate, tripropylammonium tetraphenylborate, tri(n-butyl)ammonium tetraphenylborate, tri(t-butyl)-ammonium tetraphenylborate, N,N-dimethylanilinium tetraphenylborate, N,N-diethylanilinium tetraphenylborate, N,N-dimethyl-(2,4,6-trimethylanilinium) tetraphenylborate, trimethylammonium tetrakis(pentafluorophenyl)borate, triethylammonium tetrakis-(pentafluorophenyl) borate, tripropylammonium tetrakis(pentafluorophenyl)borate, tri(n-butyl)ammonium tetrakis(pentafluorophenyl) borate, tri(sec-butyl)ammonium tetrakis-(pentafluorophenyl)borate, N,N-dimethylanilinium tetrakis(pentafluorophenyl) borate, N,N-diethylanilinium tetrakis(pentafluorophenyl) borate, N,N-dimethyl-(2,4,6-trimethylanilinium) tetrakis(pentafluorophenyl)borate, trimethylammonium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, triethylammonium tetrakis-(2,3,4,6-tetrafluorophenyl) borate, tripropylammonium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, tri(n-butyl)ammonium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, dimethyl(t-butyl)ammonium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, N,N-dimethylanilinium tetrakis-(2,3,4,6-tetrafluorophenyl)-borate, N,N-diethylanilinium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, and N,N-dimethyl-(2,4,6-trimethylanilinium) tetrakis-(2,3,4,6-tetrafluorophenyl)borate; dialkyl ammonium salts such as: di-(i-propyl)ammonium tetrakis(pentafluorophenyl)borate, and dicyclohexylammonium tetrakis(pentafluorophenyl)borate; and tri-substituted phosphonium salts such as: triphenylphosphonium tetrakis(pentafluorophenyl)borate, tri(o-tolyl)phosphonium tetrakis(pentafluorophenyl)borate, and tri(2,6-dimethylphenyl)phosphonium tetrakis-(pentafluorophenyl)borate. Preferred [L * -H] + cations are N,N-dimethylanilinium and tributylammonium. Another suitable ion forming, activating cocatalyst comprises a salt of a cationic oxidizing agent and a noncoordinating, compatible anion represented by the formula: (Ox e+ ) d (A d- ) e wherein: Ox e+ is a cationic oxidizing agent having a charge of e+; e is an integer from 1 to 3; and A d- , and d are as previously defined. Examples of cationic oxidizing agents include: ferrocenium, hydrocarbyl-substituted ferrocenium, Ag + , or Pb +2 . Preferred embodiments of A d- are those anions previously defined with respect to the Bronsted acid containing activating cocatalysts, especially tetrakis(pentafluorophenyl)borate. Another suitable ion forming, activating cocatalyst comprises a compound which is a salt of a carbenium ion and a noncoordinating, compatible anion represented by the formula: © + A - wherein: © + is a C 1-20 carbenium ion; and A - is as previously defined. A preferred carbenium ion is the trityl cation, that is triphenylcarbenium. A further suitable ion forming, activating cocatalyst comprises a compound which is a salt of a silylium ion and a noncoordinating, compatible anion represented by the formula: R# 3 Si(X#) s + A - wherein: R# is C 1-20 hydrocarbyl, s is 0 or 1, X# is a neutral Lewis base, and A - is as previously defined. Preferred silylium salt activating cocatalysts are trimethylsilylium tetrakispentafluorophenylborate, triethylsilylium tetrakispentafluorophenylborate and ether substituted adducts thereof. Silylium salts have been previously generically disclosed in J. Chem Soc. Chem. Comm., 1993, 383-384, as well as Lambert, J. B., et al., Organometallics, 1994, 13, 2430-2443. The foregoing activating technique and ion forming cocatalysts are also preferably used in combination with a tri(hydrocarbyl)aluminum compound having from 1 to 4 carbons in each hydrocarbyl group, an oligomeric or polymeric alumoxane compound, or a mixture of a tri(hydrocarbyl)aluminum compound having from 1 to 4 carbons in each hydrocarbyl group and a polymeric or oligomeric alumoxane. The molar ratio of catalyst/cocatalyst employed preferably ranges from 1:10,000 to 100:1, more preferably from 1:5000 to 10:1, most preferably from 1:1000 to 1:1. In a particularly preferred embodiment of the invention the cocatalyst can be used in combination with a C 3-30 trihydrocarbyl aluminum compound or oligomeric or polymeric alumoxane. Mixtures of activating cocatalysts may also be employed. It is possible to employ these aluminum compounds for their beneficial ability to scavenge impurities such as oxygen, water, and aldehydes from the polymerization mixture. Preferred aluminum compounds include C 2-6 trialkyl aluminum compounds, especially those wherein the alkyl groups are ethyl, propyl, isopropyl, n-butyl, isobutyl, pentyl, neopentyl, or isopentyl, and methylalumoxane, modified methylalumoxane and diisobutylalumoxane. The molar ratio of aluminum compound to metal complex is preferably from 1:10,000 to 1000:1, more preferably from 1:5000 to 100:1, most preferably from 1:100 to 100:1. The combination of the CpCp'MD complexes with strong Lewis acid activating cocatalysts in a preferred embodiment corresponds to one of the two zwitterionic equilibrium structures of the formula: wherein: M is titanium, zirconium or hafnium in the +4 formal oxidation state; Cp and Cp' are each substituted or unsubstituted cyclopentadienyl group bound in an η 5 bonding mode to M, said substituted cyclopentadienyl group being substituted with from one to five substituents independently selected from hydrocarbyl, silyl, germyl, halo, cyano, and mixtures thereof, said substituent having up to 20 nonhydrogen atoms, or optionally, two such substituents other than cyano or halo together cause Cp or Cp' to have a fused ring structure; Q independently each occurrence is selected from hydride, dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, and halosubstituted-hydrocarbyl radicals, said Q having up to 20 carbons with the proviso that in not more than one occurrence is Q halide; R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently hydrogen, hydrocarbyl, silyl and combinations thereof, each of said R 1 to R 6 having up to 20 nonhydrogen atoms; and B is boron in a valence state of 3. Preferred zwitterionic equilibrium structures correspond to the formula: wherein: R 1 , R 2 , R 5 and R 6 are hydrogen; R 3 and R 4 are hydrogen, C 1-4 alkyl or phenyl, M is zirconium in the +4 formal oxidation state, and R' and R" in each occurrence are independently selected from hydrogen, hydrocarbyl, silyl, germyl, cyano, halo and combinations thereof, said R' and R" having up to 20 non-hydrogen atoms each, or adjacent R' groups and/or adjacent R" groups (when R' and R" are not hydrogen, halo or cyano) together form a divalent derivative (that is, a hydrocarbadiyl, siladiyl or germadiyl group which forms a fused ring system). Most highly preferred are the equilibrium zwitterionic metal coordination complexes corresponding to the formula: wherein: M is zirconium in the +4 formal oxidation state; R 1 , R 2 , R 5 and R 6 are hydrogen; R 3 and R 4 are hydrogen or methyl; and R' and R" in each occurrence are independently selected from hydrogen, hydrocarbyl, silyl, germyl, cyano, halo and combinations thereof, said R' and R" having up to 20 non-hydrogen atoms each, or adjacent R' groups and/or adjacent R" groups (when R' and R" are not hydrogen, halo or cyano) together form a divalent derivative (that is, a hydrocarbadiyl, siladiyl or germadiyl group which forms a fused ring system). The catalysts may be used to polymerize ethylenically and/or acetylenically unsaturated monomers having from 2 to 20 carbon atoms either alone or in combination. Preferred monomers include the C 2-10 α-olefins especially ethylene, propylene, isobutylene, 1-butane, 1-hexane, 4-methyl-1-pentane, and 1-octene and mixtures thereof. Other preferred monomers include vinylcyclohexene, vinylcyclohexane, styrene, C 1-4 alkyl substituted styrene, tetrafluoroethylene, vinylbenzocyclobutane, ethylidenenorbornene, piperylene and 1,4-hexadiene. The ethylene/1-olefin copolymers formed using catalysts of the present invention are characteristic of the type of ethylene polymers that can be obtained with metallocene catalysts. The polyolefins that can be produced with the catalysts of the present invention range from elastomeric to plastomeric, that is, substantially non-elastomeric products, depending on the monomers, monomer amounts and polymerization conditions employed. As used herein the term "elastomeric" is meant to signify polymers having tensile modulus values as measured by ASTM D-638 of less than 15,000 N/cm 2 , preferably less than 5000 N/cm 2 , and most preferably less than 500 N/cm 2 . These products find application in all the uses heretofore developed for such polyolefins and can be fabricated into such end-use products by the methods heretofore developed for polyolefins including, for example, molding, casting, extrusion and spinning. The polyolefins obtained with the catalysts of the present invention are useful in such end-use applications as films for packaging, including shrink wrap applications, foams, coating, Insulating devices, including for wire and cable, and household items. The polyolefins made with the catalysts of the present invention can be shown to have superior properties in these applications over heretofore used materials in these applications using the tests that have been established to measure performance in the intended end-use or by tests not heretofore applied to measure performance in such end-use applications. In general, the polymerization may be accomplished at conditions well known in the prior art for Ziegler-Natta or Kaminsky-Sinn type polymerization reactions, that is, temperatures from 0-250°C and pressures from atmospheric to 3000 atmospheres (0.1 to 300 MPa). Suspension, solution, slurry, gas phase or high pressure, whether employed in batch or continuous form or under other process conditions, including the recycling of condensed monomers or solvent, may be employed if desired. Examples of such processes are well known in the art for example, WO-A-8802009 or US-A-5,084,534, disclose conditions that can be employed with the polymerization catalysts of the present invention. A support, especially silica, alumina, or a polymer (especially polytetrafluoroethylene or a polyolefin) may be employed, and desirably is employed when the catalysts are used in a gas phase polymerization process. Such supported catalysts are generally not affected by the presence of liquid aliphatic or aromatic hydrocarbons such as may be present under the use of condensation techniques in a gas phase polymerization process. Methods for the preparation of supported catalysts are disclosed in numerous references, examples of which are US-A-4,808,561, US-A-4,912,075, US-A-5,008,228, US-A-4,914,253, and US-A-5,086,025 and are suitable for the preparation of supported catalysts of the present invention. In most polymerization reactions the molar ratio of catalyst:polymerizable compounds employed is from 10 -12 :1 to 10 -1 :1, more preferably from 10 -12 :1 to 10 -5 :1. Suitable solvents for solution, suspension, slurry or high pressure polymerization processes are noncoordinating, inert liquids. Examples include straight and branched-chain hydrocarbons such as isobutane, butane, pentane, hexane, heptane, octane, and mixtures thereof; cyclic and alicyclic hydrocarbons such as cyclohexane, cycloheptane, methylcyclohexane, methylcycloheptane, and mixtures thereof; perfluorinated hydrocarbons such as perfluorinated C 4-10 alkanes, and aromatic and alkyl-substituted aromatic compounds such as benzene, toluene, and xylene. Suitable solvents also include liquid olefins which may act as monomers or comonomers including ethylene, propylene, butadiene, cyclopentene, 1-hexene, 3-methyl-1-pentene, 4-methyl-1-pentene, 1,4-hexadiene, 1-octene, 1-decene, styrene, divinylbenzene, allylbenzene, and vinyltoluene (including all isomers alone or in admixture). Mixtures of the foregoing are also suitable. The catalysts may also be utilized in combination with at least one additional homogeneous or heterogeneous polymerization catalyst in separate reactors connected in series or In parallel to prepare polymer blends having desirable properties. Examples of such processes are disclosed in WO-A-9400500 and WO-A-9417112. Having described the invention the following examples are provided as further illustration thereof and are not to be construed as limiting. Unless stated to the contrary all parts and percentages are expressed on a weight basis. Example 1 - Preparation of bis(η 5 -cyclopentadienyl)zirconium s -trans(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene). In an inert atmosphere glove box, 586 mg (2.01 mmol) of (C 5 H 5 ) 2 ZrCI 2 and 413 mg (2.00 mmol) of trans, trans-1,4-diphenyl-1,3-butadiene are combined in 90 ml of mixed alkanes (Isopar E™, available from Exxon Chemicals Inc.). To the stirred slurry is added 1.60 ml of 2.5 M n-butyl lithium. The mixture turns dark red immediately. After stirring at 25°C for 2 hours, the mixture is heated to reflux for 3 hours. The warm solution is filtered. The red solid residue is extracted with a total volume of 90 ml of warm toluene. The extracts are filtered and combined with the hexanes filtrate. The total volume of the solution is concentrated to 40 ml under reduced pressure. At this point a red precipitate is formed. The mixture is warmed until the solid redissolves and the solution is placed in a freezer (-25°C). Dark red crystals are subsequently collected on a glass frit. Drying under reduced pressure gives 210 mg (25 percent yield) of (C 5 H 5 ) 2 Zr(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene) as verified by 1 H NMR analysis. The product has a 95 percent s -trans, 5 percent s -cis-configuration. Example 2 - Combination of Lewis Acid with bis(cyclopentadienyl)zirconium s -trans(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene). In an inert atmosphere glove box, 8.4 mg (0.020 mmol) of (C 5 H 5 ) 2 Zr s -trans(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene) of Preparation #1 and 10.0 mg (0.020 mmol) of B(C 6 F 5 ) 3 is combined in .75 ml of benzene-d6 to form a homogeneous solution. Analysis by 1 H NMR shows the reactants to be completely consumed. Example 3 - Polymerization using a combination of (C 5 H 5 ) 2 Zr s -trans(η 4 -1,4-trans, trans-dlphenyl-1,3-butadiene) and B(C 6 F 6 ) 3 . A two-liter reactor is charged with 746 g of mixed alkanes and 120 g of 1-octene comonomer. Hydrogen is added as a molecular weight control agent by differential pressure expansion from a 75 ml addition tank from 300 psig (2.1) MPa) to 275 psig (1.9 MPa). The reactor is heated to the polymerization temperature of 140°C and saturated with ethylene at 500 psig (3.4 MPa). 5.00 µmol of the catalyst combination of Example 2 (0.00500 M solutions in toluene) is transferred to a catalyst addition tank. The polymerization is initiated by injecting this solution into the contents of the reactor. The polymerization conditions are maintained for 10 minutes with ethylene provided on demand at 500 psi (3.4 MPa). The polymer solution is removed from the reactor and combined with 100 mg of a hindered phenol anti-oxidant (Irganox™ 1010 available from Ciba Geigy Corp.). Volatiles are removed from the polymer in a vacuum oven set at 120°C for about 20 hours. The polymer yield is 16.8 g. Example 4 - Combination of (C 5 H 5 ) 2 Zr s -trans(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene) with dimethylanilinium tetrakis(pentafluorophenyl) borate. In an inert atmosphere glove box, 0.043 g (0.010 mmol) of bis-cyclopentadienyl zirconium s -trans(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene) is dissolved in 20 ml of toluene followed by addition of 0.0780 g (0.099 mmol) of dimethylanilinium tetrakis(pentafluorophenyl) borate using 10 ml of toluene to wash the solids into the reaction flask. After one hour the solvent is removed under reduced pressure. The product is washed with pentane (3 x 10 ml with drying after the final wash). The product is isolated as an oil. Example 5 - Electrolytic preparation of [(C 5 H 5 ) 2 Zr s -trans(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene)] [tetrakis(pentafluorophenyl) borate]. A standard H-cell for electrolysis comprising two electrode wells separated by a fine glass frit, platinum mesh working and counter electrodes, and a silver reference electrode is placed inside an inert atmosphere glove box filled with argon. Each half of the cell is filled with 1,2-difluorobenzene solvent (5 ml in the working compartment, 4 ml in the counter compartment) and tetra-n-butylammonium tetrakis(pentafluorophenyl) borate supporting electrolyte (8 mmol). The complex, bis(cyclopentadienyl)Zr s -trans(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene) (0.017 g) is placed in the working compartment. A sweep of the working electrode potential is used to determine the voltage to be applied during electrolysis. The solution Is stirred and the potential is stepped to the first oxidation wave of the complex and adjusted to obtain a 1.5 mA current. The applied potential is turned off when the current drops to 30 percent of its original value having passed a total of 3.3 coulombs. This represents a conversion of 72 percent. The working compartment solution is then pipetted into a round bottom flask and the solvent is removed under vacuum. The resulting solid product is extracted with toluene (2.0 ml) and is directly transferred to the polymerization reaction in Example 6. Example 6 - Polymerization using catalyst of Example 5. A 2 L stirred reactor is charged with the desired amounts of mixed alkanes solvent and 15 g 1-octene comonomer. Hydrogen is added as a molecular weight control agent by differential pressure expansion (25 Δpsi (200 ΔkPa)) from an approximately 75 ml addition tank at 300 psi (2.1 MPa). The reactor is heated to the polymerization temperature and saturated with ethylene at 500 psi (3.4) MPa. 5.00 µmol of the catalyst of Example 5 dissolved in toluene is transferred to a catalyst addition tank and injected into the reactor. The polymerization is allowed to proceed for the desired time with ethylene provided on demand at 500 psi (3.4 MPa). After 15 minutes run time, the solution is removed from the reactor and quenched with isopropanol. A hindered phenol anti-oxidant is added to the polymer solution. The resulting solid polymer of ethylene and 1-octene is dried in a vacuum oven set at 120°C for about 20 hours. Example 7 - Polymerization using (C 5 H 5 ) 2 Zr s -trans(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene) with alumoxane. A stirred 5 L autoclave reactor is charged with 1850 g of anhydrous hexane through a mass-flow meter. A solution containing 100 µmols of triisopropylaluminum modified methylalumoxane (MMAO, obtained from Akzo Corporation) in 10 ml of hexane is then added to the reactor via a pressurized stainless steel cylinder prior to heating to 80°C. At this point the reactor pressure is increased to 10 psig (70 kPa) by the addition of hydrogen followed by ethylene sufficient to bring the total pressure to 175 psig (1.21 MPa). The ethylene is supplied continuously to the reactor by a demand feed regulator on the line. 12.5 µmol of the diene complex of Example 1 is slurried in hexane and is then added to the reactor to initiate the polymerization. After 30 minutes the ethylene flow is stopped and the reactor is vented and cooled. The resulting polyethylene is filtered and dried at 80°C overnight in a vacuum oven. Example 8 - Preparation of Supported Catalysts (a) Preparation of support Dried silica (2.5 g, Davison 948, dried at 800°C) is slurried with 10 mL of 1.0 M methylaluminoxane (MAO, 1.0 M in toluene) and the mixture is stirred for 30 minutes. The slurry is filtered and washed five times with 10 mL portions of pentane. The washed slurry is dried under vacuum. (b) Preparation of supported catalyst Bis(n-butylcyclopentadienyl)zirconium s -trans(η 4 -1,4-trans-trans-diphenyl-1,3-butadiene) is prepared analogously to bis(cyclopentadienyl)zirconium s -trans(η 4 -1,4-trans-trans-diphenyl-1,3-butadiene) (Example 1). A 100 mL flask is charged with 0.50 g of bis(n-butylcyclopentadienyl)zirconium s -trans(η 4 -1,4-trans-trans-diphenyl-1,3-butadiene) (1.17 mmol). A solution of MAO (50 mL of a 1.0 M solution in toluene) is added. The solution is stirred for five minutes followed by the addition of 2.5 g of the treated silica obtained from part (a) above. The mixture is stirred for five minutes, and the toluene is removed under vacuum to give the supported catalyst. Example 9 - High-Pressure polymerization A 1000 mL stirred steel autoclave equipped to perform Ziegler polymerizations at pressures up to 250 MPa and temperatures up to 300°C is used. The reaction system is equipped with a thermocouple and a pressure transducer to measure temperature and pressure continuously, and with means to supply purified ethylene, nitrogen, hydrogen, and 1-butene. The reactor is also equipped with means for continuously introducing a measured flow of catalyst solution and equipment for rapidly venting and quenching the reaction and for collecting the polymer product. The catalyst is prepared by combining 564 mg of bis(n-butyl-cyclopentadienyl)zirconium s -trans(η 4 -1,4-trans-trans-diphenyl-1,3-butadiene) with 1.0 L of 0.8 M MAO in 10 L of toluene in an inert atmosphere drybox. This catalyst solution is continuously fed into the reactor at a rate necessary to maintain a temperature of 180°C in the reactor. During the run, ethylene and 1-hexene are pressured into the reactor at a total pressure of 100 MPa at a mass flow of 50 kg/h. The reactor Is stirred at 1000 rpm. A solid copolymer of ethylene and 1-hexene is obtained. Example 10 - High Pressure Polymerization The procedure of Example 9 is repeated, except that no MAO is used and the catalyst is prepared by simultaneously adding equimolar amounts of 0.005 M solutions of bis(n-butylcyclopentadienyl)zirconium s -trans(η 4 -1,4-trans-trans-diphenyl-1,3-butadiene) and B(C 6 F 5 ) 3 to the flowing stream of 1-hexene just prior to the reactor. A solid copolymer of ethylene and 1-hexene is obtained.

Claims: Compositions of matter useful as olefin polymerization catalysts comprising: 1) a metal complex containing two cyclopentadienyl groups or substituted cyclopentadienyl groups, said complex corresponding to the formula: CpCp'MD wherein: M is titanium, zirconium or hafnium in the +2 or +4 formal oxidation state; Cp and Cp' are each substituted or unsubstituted cyclopentadienyl groups bound in an η 5 bonding mode to the metal, said substituted cyclopentadienyl group being substituted with from one to five substituents independently selected from hydrocarbyl, silyl, germyl, halo, cyano, hydrocarbyloxy, and mixtures thereof, said substituent having up to 20 nonhydrogen atoms, or optionally, two such substituents (except cyano or halo) together cause Cp or Cp' to have a fused ring structure; D is a stable, conjugated terminally C 1-10 hydrocarbyl substituted 1, 3-butadiene, or a stable, conjugated diene substituted with one or more silyl groups, hydrocarbylsilyl groups, silylhydrocarbyl groups, or mixtures thereof, said D having up to 40 nonhydrogen atoms and forming a π-complex with M when M is in the +2 formal oxidation state, and forming a σ-complex with M when M is In the +4 formal oxidation state; said complex having been activated by use of: 2) a cocatalyst or activating technique selected from: 2a) strong Lewis acids; 2b) oxidizing salts corresponding to the formula: (Ox e+ ) d (A d- ) e wherein: Ox e+ is a cationic oxidizing agent having a charge of e+; e is 1 or 2; A is a noncoordinating compatible anion having a charge of d-; d is an integer from 1 to 3; 2c) carbenium salts corresponding to the formula: © + A - wherein: © + is a C 1 -C 20 carbenium ion; and A - is a noncoordinating compatible anion having a charge of -1; 2d) an activating technique comprising electrolyzing the metal complex under bulk electrolysis conditions in the presence of an electrolyte of the general formula: G + A - wherein A - is a noncoordinating compatible anion having a charge of -1; and G + is a cation which is non-reactive towards the starting and resulting complex; 2e) polymeric or oligomeric alumoxanes; 2f) salts of a silylium ion and a noncoordinating, compatible anion represented by the formula: R# 3 Si(X#) s + A - wherein: R# is C 1-20 hydrocarbyl, s is 0 or 1, X# is a neutral Lewis base, and A - is as previously defined; and 2g) Bronsted acid salts having the formula: (L-H) + d (A) d- wherein: L is a neutral Lewis base; (LH) + is a Bronsted acid; A is a noncoordinating compatible anion having a charge of d-; and d is an integer from 1 to 3; with the proviso that when the cocatalyst is a Bronsted acid salt of 2g), then D has 5 to 40 carbon atoms and is π-bonded to the transition metal; and M is titanium, zirconium or hafnium in the +2 formal oxidation state. A composition as claimed in Claim 1, wherein the metal complex corresponds to the formula: wherein: M is zirconium or hafnium, in the +2 or +4 formal oxidation state; R' and R" in each occurrence are independently selected from hydrogen, hydrocarbyl, silyl, germyl, cyano, halo and combinations thereof, said R' and R" having up to 20 non-hydrogen atoms each, or adjacent R' groups and/or adjacent R" groups (when R' and R" are not hydrogen, halo or cyano) together form a divalent derivative thereby forming a fused ring; and D is as previously defined in Claim 1. A composition as claimed in Claim 1 or Claim 2, wherein the cocatalyst is a strong Lewis acid selected from C 1-30 hydrocarbyl substituted Group 13 compounds; halogenated C 1-30 hydrocarbyl substituted Group 13 compounds; amine-, phosphine-, aliphatic alcohol-, and mercaptan- adducts of halogenated C 1-30 hydrocarbyl substituted Group 13 compounds, and combinations thereof. A composition as claimed in Claim 3, additionally comprising hydrogen or ethylene. A composition as claimed in Claim 4, wherein M is zirconium or hafnium in the +4 formal oxidation state and the diene is bound to the metal by a σ-complex structure and is in the s-cis configuration. A composition as claimed in Claim 2, wherein M is zirconium or hafnium in the +2 formal oxidation state and the diene is bound to the metal by a π-complex structure. A composition as claimed in Claim 6, wherein D is a 1,3-butadiene that is terminally substituted with one or two C 1-10 hydrocarbyl groups. A composition as claimed in Claim 6, wherein the diene is 1,4-diphenylbutadiene or 1,4-ditolylbutadiene. A composition as claimed in any one of Claims 3 to 8, wherein the cocatalyst is tris(pentafluorophenyl)borane. A composition as claimed in any one of Claims 3 and 6 to 9, additionally comprising a polymeric or oligomeric alumoxane. A composition as claimed in Claim 1, obtained by combining a diene complex with a Bronsted acid salt wherein the diene complex has the formula: wherein: M' is zirconium or hafnium in the +2 formal oxidation state; R' and R" in each occurrence is independently selected from hydrogen, hydrocarbyl, silyl, germyl, cyano, halo and combinations thereof said R' and R" having up to 20 non-hydrogen atoms, or adjacent R' groups and/or adjacent R" groups (when R' and R" are not hydrogen, halo or cyano) together form a divalent derivative thereby forming a fused ring; D has from 5 to 40 carbon atoms and is π-bonded to the metal; and the Bronsted acid salt has the formula: (L-H) + (BQ' 4 ) - wherein: L is a neutral Lewis base; (L-H) + is a Bronsted Acid; B is boron; Q' is a fluorinated C 1 to C 20 hydrocarbyl group. A composition as claimed in Claim 11, wherein (BQ' 4 ) - is tetrakispentafluorophenyl borate, M' is zirconium or hafnium and the diene is 2,4-hexadiene, 1-phenyl-1,3-pentadiene, 1,4-diphenylbutadiene or 1,4-ditolylbutadiene. A composition as claimed in Claim 1, wherein the metal complex is bis(η 5 -cyclopentadienyl)zirconium s -trans(η 4 -1,4-trans, trans-diphenyl-1,3-butadiene) A metal complex corresponding to one of the two zwitterionic equilibrium structures of the formula: wherein: M is titanium, zirconium or hafnium in the +4 formal oxidation state; Cp and Cp' are each a substituted or unsubstituted cyclopentadienyl group bound in an η 5 bonding mode to M, said substituted cyclopentadienyl group being substituted with from one to five substituents independently selected from hydrocarbyl, silyl, germyl, halo, cyano, and mixtures thereof, said substituent having up to 20 nonhydrogen atoms, or optionally, two such substituents other than cyano or halo together cause Cp or Cp' to have a fused ring structure; Q independently each occurrence is selected from hydride, dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, and halosubstituted-hydrocarbyl radicals, said Q having up to 20 carbons with the proviso that in not more than one occurrence is Q halide; R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently hydrogen, hydrocarbyl, silyl and combinations thereof, each of said R 1 to R 6 having up to 20 nonhydrogen atoms and either (i) at least one of R 1 , R 2 , R 3 , R 4 , R 5 and R 6 is silyl, hydrocarbylsilyl or silylhydrocarbyl or (ii) at least one of R 1 , R 2 , R 5 and R 6 is C 1-10 hydrocarbyl; and B is boron in a valence state of 3. A metal complex as claimed in Claim 14 wherein R 3 and R 4 are hydrogen or methyl. An olefin polymerization process comprising contacting at least one α-olefin having from 2 to 10 carbon atoms under polymerization conditions with a composition as defined in any one of Claims 1 to 15. A process as claimed in Claim 16, wherein the olefin is propylene. A process as claimed in Claim 16, wherein a combination of ethylene with one or more monomers selected from propylene, 1-butane, 1-hexene, 1-octene, styrene, ethylidenenorbornene, piperylene, and 1,4-hexadiene is polymerized. A process as claimed in any one of Claims 16 to 18, wherein the catalyst is supported. A process as claimed in Claim 19, which is a gas phase polymerization. A process as claimed in Claim 20, which incorporates recycle of condensed monomers or solvent.

Inventors: DEVORE DAVID D, NEITHAMER DAVID R, PATTON JASSON T, ROSEN ROBERT K, STEVENS JAMES C, TIMMERS FRANCIS J, DEVORE, DAVID D., NEITHAMER, DAVID R., PATTON, JASSON T., ROSEN, ROBERT K., STEVENS, JAMES C., TIMMERS, FRANCIS J.
Applicants: DOW GLOBAL TECHNOLOGIES INC, DOW GLOBAL TECHNOLOGIES INC.
Application year: 1995
Main classification: C07F17
IPC codes: C08F4, C07F17