Adhesive for copper foils and adhesive-backed copper foil

Abstract: An adhesive for copper foils comprises (I) 60 to 100 parts by weight of the whole epoxy resin including 0.5 to 20 parts by weight of a rubber-modified epoxy resin, and (II) 5 to 30 parts by weight of a polyvinyl acetal resin; and an adhesive-backed copper foil has the adhesive coated on its one surface.

Description: Background of the Invention 1. Field of the Invention This invention relates to an adhesive for copper foils and also to an adhesive-backed copper foil, which are useful for the preparation of a laminate comprising a copper foil and a base sheet such as a metallic sheet or a plastics sheet. 2. Prior Art Adhesives for copper foils which have conventionally been used comprise as the main component a polyvinyl acetal resin which is modified with a phenol resin or melamine resin. These adhesives or resins are dissolved in an organic solvent such as toluene or methyl ethyl ketone for use as an adhesive varnish. This adhesive varnish is coated on copper foils, dried and then semi-cured in a heating furnace thereby to industrialize the production of adhesive-coated copper foils free of stickiness at room temperatures. This stickiness-free adhesive-backed copper foil is used in combination with a prepreg which is prepared by impregnating a paper substrate, glass cloth or the like with a thermosetting resin such as a phenol resin. Known from JP-A-6-128547 is a copper foil adhesive for copper-clad laminates comprising a polyvinyl butyral resin, an epoxy resin and a curing agent therefor, an amino resin and an elastomer; and an acidic curing agent making them cross-linked. This document teaches the polyvinyl butyral resin as the main component. On the other hand, various methods have been used for bonding together a copper foil and a base sheet such as a metallic sheet or a plastics sheet. They include a method which comprises superimposing a base sheet and an adhesive-backed copper foil one upon the other and then pressing them together, a method which comprises coating a non- solvent type adhesive composition composed of an epoxy resin incorporated with a curing agent onto a copper foil or a base sheet immediately before bonding the copper foil and base sheet together, and a method which comprises wrapping an adhesive composition in a carrier film to prepare a film-like adhesive and then interposing the film-like adhesive between a copper foil and a base sheet. Since an adhesive used in the conventional adhesive-backed copper foil is one containing as the main component a polyvinyl acetal resin, the fluidity of the adhesive is so poor that it is difficult to press-bond the copper foil onto a base sheet with a press or heat rolls within a short period of time. It is of course possible from the technical viewpoint to use an adhesive containing an extremely reduced amount or none of a polyvinyl acetal resin. However, with such an adhesive, the flexing properties of the resulting adhesive layer will be significantly reduced, thus making it difficult to handle the resulting adhesive-backed copper foil in actual use. Accordingly, such an adhesive is of no practical use. Moreover, the phenol resin and melamine resin included as components in the adhesive require a high temperature of not less than 150°C for curing the resins. Further, during curing, these resins release by-products such as water and formaldehyde due to condensation reactions, it therefore requires application of pressure for a long period of time to bond the copper foil and base material together. In the absence of an adhesive-backed foil, a liquid adhesive may be applied to the base material to effect a bond between it and a copper foil, or else a film-like adhesive used between a copper foil and base material for their adhering makes it possible to achieve the adhesion by application of heat and pressure for a short period of time; the above case raises the problem of the pot-life of the applied liquid adhesive or the need of an additional step to remove the carrier film of the film-like adhesive, whereby the above adhesion methods are not attractive from the standpoint of workability and cost in an industrial environment. Summary of the Invention This invention has been made in view of these conventionallimitations.The primary object of this invention is to provide an adhesive for copper foils which is easy to handle , enables a copper foil to be press-bonded onto a base sheet such as a metallic sheet, a plastics sheet or a glass reinforced plastics sheet at a lower temperature and pressure than those employed for press-bonding in the conventional adhesive-backed copper foil, and will exhibit excellent adhesion and heat resistance after curing even if it is cured without applying a pressure, and to provide an adhesive-backed copper foil prepared by coating the adhesive on the,surface of a copper foil. The above object of the present invention may be achieved by the provision of an adhesive for copper foils which comprises (I) 60 to 100 parts by weight of the whole epoxy resin in which 0.5 to 20 parts by weight of a rubber-modified epoxy resin are included, said rubber-modified epoxy resin being the reaction product of an epoxy resin and a rubber, and (II) 5 to 30 parts by weight of a polyvinyl acetal resin. The term "the whole epoxy resin" used in this invention is defined to include both of an ordinary non-modified epoxy resin and a rubber-modified epoxy resin. The copper foils used in the adhesive-backed copper foils include rolled copper foils and electrodeposited copper foils. It is preferable to subject at least one surface of the copper foils to surface-roughening treatment and rust prevention treatment in order to enhance adhesion of the foils. There is no limitation on the thickness of the copper foil, but a copper foil having a thickness ranging generally from 0.009mm to 0.1mm, more generally from 0.018mm to 0.035mm, may be preferably used. There is also no restriction placed on a method for the rust prevention treatment. The epoxy resins useful in this invention include a bisphenol A-type epoxy resin, a bisphenol F-type epoxy resin, a novolak-type epoxy resin, o-cresol novolak-type epoxy resin, a brominated epoxy resin such as diglycidyl ether of tetrabromobisphenol A, triglycidyl isocyanurate, tetrakis (glycidyloxyphenyl) ethane, epoxidized polybutadiene, a glycidyl amine compound such as N,N-diglycidyl aniline and a glycidyl ester compound such as tetrahydrophthalate diglycidyl ester. These epoxy resins may be used singly or jointly. There is no specific restriction placed on the polymerization degree or epoxy equivalent of these epoxy resins. The rubber-modified epoxy resins used herein include reaction products between the above-mentioned low molecular epoxy resin and a compound selected from butadiene rubber having a terminal carboxyl group, acrylonitrile-butadiene copolymers and isoprene rubber. Preferable curing agents for these epoxy resins include well-known dicyandiamide, a latent curing agent such as organic hydrazides and imidazoles, a phenol novolak resin difficultly curable at room temperature and cresol novolak resin. These curing agents may be used singly or jointly. Further, it is possible to additionally use a reaction accelerator such as a tertiary amine or triphenyl phosphine. Polyvinyl acetal resins are effective for adjusting the viscosity of the resulting adhesives. There is no restriction placed on the polymerization degree of polyvinyl alcohol to be used as a raw material for the polyvinyl acetal resins, on the kind of acetal group, existence or non-existence of a modifying agent, the amount of the modifying agent and the concentration of residual hydroxyl group. The adhesive for copper foils according to this invention includes 60 to 100 parts by weight of the whole epoxy resin, the amount including 0.5 to 20 parts by weight of a rubber-modified epoxy resin, and 5 to 30 parts by weight of a polyvinyl acetal resin. Preferably, the adhesive includes 70 to 90 parts by weight of the whole epoxy resin, the amount including 5 to 15 parts by weight of a rubber-modified epoxy resin, and 5 to 20 parts by weight of a polyvinyl acetal resin. If the amount of the whole epoxy resin including the rubber-modified epoxy resin is less than 60 parts by weight, it would be difficult to proceed with the curing of the adhesive without applying pressure after press-bonding the copper foil onto the base sheet, said non-pressure curing method being the object of this invention. Meanwhile, if the amount of the rubber-modified epoxy resin to be used is less than 0.5 parts by weight, the resulting adhesive layer will become fragile whereby it is made difficult to handle. On the other hand, if the amount of the rubber-modified epoxy resin to be used exceeds 20 parts by weight, this resin will be deteriorated in compatibility with other resins thereby making it difficult for the resulting adhesive to be formed into a varnish. If the content of the polyvinyl acetal resin exceeds 30 parts by weight, the fluidity of the adhesive will be adversely affected so that the press-bonding of a copper foil therewith under a low temperature and a low pressure becomes difficult. On the other hand, if the amount of the polyvinyl acetal resin is less than 5 parts by weight, the resultant adhesive will become too fluid so that it is squeezed out during press-bonding. The adhesive including the resinous components as mentioned above is coated on one of the surfaces of a copper foil and then heated to semi-cure the adhesive, thereby achieving the intended adhesive-backed copper foil. If required at this point, a comparatively inexpensive organic solvent such as industrially cheap methanol, acetone, methyl ethyl ketone or toluene may be used to dissolve the adhesive therein before coating the adhesive onto the copper foil. It is also possible according to this invention to incorporate into the adhesive a fire retardant such as a bromine compound or antimony compound, and an inorganic filler such as talc or powdered silica, in addition to the components mentioned above. Additionally, a polyester resin, phenol resin, melamine resin and/or urethane resin may be added to the adhesive if they are capable of being chemically combined with the epoxy resin. These additional resins are effective in adjusting the viscosity of the adhesive and also in lowering the manufacturing cost of the adhesive. The base material to be used in combination with the adhesive of this invention includes a plastics film, a printed wiring board provided thereon with an inner circuit, a plywood for decorative boards or a ceramic board for electric circuit. Since the adhesive for copper foils of this invention contains an epoxy resin in a larger amount than a polyvinyl acetal resin, it exhibits high fluidity even at a relatively low temperature, thereby making it possible to perform the press-bonding of a copper foil with the adhesive by a press or a heat roll within a short period of time. Further, since the epoxy resin does not generate by-products therefrom during the curing thereof, the curing can still proceed after the press-bonding of the copper foil even if no pressure is applied to effect the bonding, resulting in a cured product excellent in adhesiveness and heat resistance. The deterioration of flexibility of the adhesive layer due to the quantitative reduction of the polyvinyl acetal resin can be effectively prevented by the addition of a rubber-modified epoxy resin in a suitable amount. Description of the Preferred Embodiments This invention will be better understood by the following Examples and Comparative Examples. Example 1 Methyl ethyl ketone was added as an organic solvent to a mixture comprising 10 parts by weight of a rubber-modified epoxy resin (trade name: EPICLON TSR-930, produced by Dai Nippon Ink Co., Ltd.), 50 parts by weight of an epoxy resin (trade name: EPOTOHTO YD-128, produced by Tohto Kasei Co., Ltd.), 20 parts by weight of another epoxy resin (trade name: D.E.R438, produced by Dow Chemical Japan Co.), 12 parts by weight of a mixed solution consisting of dicyandiamide (reagent) and dimethylformamide (mixing weight ratio: 1:3), 0.2 parts by weight of dimethylbenzylamine (reagent) as an accelerator, and 20 parts by weight of a polyvinyl acetal resin (trade name: DENKA BUTYRAL #5000A, produced by Denki Kagaku Kogyo Co., Ltd.), thereby to obtain an adhesive varnish containing 80% by weight of solid matter. The adhesive varnish thus prepared was coated on the matte surface of an electrodeposited copper foil (35µm in thickness, a product of Mitsui Mining & Smelting Co., Ltd.), air-dried and subsequently, heated at 130°C for 5 minutes to produce an adhesive-backed copper foil with an adhesive thickness of 30 to 40µm. Example 2 A mixture comprising 15 parts by weight of a rubber-modified epoxy resin (trade name: EPOTOHTO YR-207, produced by Tohto Kasei Co., Ltd.), 25 parts by weight of an epoxy resin (trade name: EPOMIC R-304, produced by Mitsui Petrochemical Co., Ltd.), 20 parts by weight of another epoxy resin (trade name: EPOTOHTO YDCN-704P, produced by Tohto Kasei Co., Ltd.), 15 parts by weight of a curing agent for an epoxy resin (trade name: PHENOLITE VH-4170, produced by Dai Nippon Ink Co., Ltd.), 15 parts by weight of a polyvinyl acetal resin (trade name: DENKA BUTYRAL #5000A, produced by Denki Kagaku Kogyo Co., Ltd.) and 10 parts by weight of a blocked isocyanate resin (trade name: MILLIONATE MS-50, produced by Nihon Polyurethane Co., Ltd.) was uniformly dissolved in methyl ethyl ketone thereby to obtain an adhesive varnish containing 60% by weight of solid matter. The adhesive varnish thus prepared was coated on the matte surface of an electrodeposited copper foil (35µm in thickness, a product of Mitsui Mining & Smelting Co., Ltd.) air-dried and subsequently heated at 130°C for 5 minutes to produce an adhesive-backed copper foil with an adhesive thickness of 30 to 40µm. Comparative Example 1 A mixture comprising 20 parts by weight of an epoxy resin (trade name: EPOTOHTO YDCN-704P, produced by said Tohto Kasei Co.), 50 parts by weight of a polyvinyl acetal resin (trade name: DENKA BUTYRAL #5000A, produced by said Denki Kagaku Kogyo Co.) and 30 parts by weight of a resol phenolic resin (trade name: SHONOL BLS-364, produced by Showa High Molecular Co., Ltd.), was uniformly dissolved in methyl ethyl ketone, thereby obtaining an adhesive varnish containing 20% by weight of solid matter. The adhesive varnish thus prepared was coated on the matte surface of an electrodeposited copper foil (35um in thickness, a product of said Mitsui Co.) air-dried and subsequently heated at 130°C for 5 minutes to produce an adhesive-backed copper foil with an adhesive thickness of 30 to 40µm, Comparative Example 2 The procedure of Example 1 was repeated except that the amount of EPOTOHTO YD-128 (said Tohto Kasei Co.) was changed from the 50 parts by weight to 30 parts by weight, and the amount of DENKA BUTYRAL #5000A (said Denki Kagaku Kogyo Co.) was changed from the 20 parts by weight to 40 parts by weight, thereby obtaining an adhesive varnish containing 80% by weight of solid matter. Then, the adhesive varnish thus prepared was used in the same manner as in Example 1, thereby obtaining a copper foil provided with an adhesive layer. Comparative Example 3 A mixture comprising 100 parts by weight of an epoxy resin (trade name: EPICLON 1050-75X, produced by said Dai Nippon Ink Co.), 2 parts by weight of a curing agent for the epoxy resin (trade name: CURESOL 2MA-OK, produced by Shikoku Kasei Co., Ltd.) and 2 parts by weight of an anti-settling agent (trade name: AEROSIL #300, produced by Nippon Aerosil Co., Ltd.), was uniformly dispersed using a three-roll mill and then incorporated with methyl ethyl ketone, thereby obtaining an adhesive varnish containing 70% by weight of solid matter. Then, the adhesive varnish thus prepared was coated on a matte surface of an electrodeposited copper foil (35µm in thickness, a product of said Mitsui Co.) air-dried and subsequently heated at 140°C for 5 minutes to produce an adhesive-backed copper foil with an adhesive thickness of 30 to 40µm. The adhesive-backed copper foils prepared in Examples 1 and 2, as well as in Comparative Examples 1 to 3 were evaluated for the flexibility of their adhesive layer in accordance with JIS K 5400. The diameter of a spindle used in this evaluation was 10mm. As base materials or substrates, lmm-thick silicon steel plates were employed. The base material and each of the above adhesive-backed copper foils were superimposed one upon the other so that the adhesive layer was contacted with the base material, after which the whole was pressed with a hot press at 100°C and a pressure of 98 bar (100Kgf/cm 2 ) for 60 seconds. After being removed from the hot press, the copper-laminated steel plate was cut into two halves. One of them was measured for its peel strength by striping the copper foil from the base material by hand, while the other was heated to 200°C for 30 minutes to cure the adhesive without the application of pressure. After being cured, the copper-laminated steel plate was evaluated for the presence or absence of any blisters generated. The copper-laminated steel plates having no blisters generated, were further measured for their peel strength and soldering heat resistance in accordance with JIS C 6481. The results are shown in Table 1. As explained above, the copper foil having an adhesive layer of this invention can be handled as easily as the conventional adhesive-backed copper foil, and can be press-bonded to a base material at lower temperature and pressure than for conventional adhesive-backed foils. Moreover, it is apparent that the adhesive-backed copper foil will, after being press-bonded to the base material, allow the curing of the adhesive layer to proceed even if no pressure is applied thereon, resulting in a cured product which is excellent in adhesiveness and heat resistance. Unit: Part by weight Ex. 1 Ex. 2 Comp. Ex. 1 Comp. Ex. 2 Comp. Ex. 3 components rubber-modified epoxy resins EPICLON TSR-930 10 10 EPOTOHTO YR-207 15 epoxy resins EPOTOHTO YD-128 50 30 D.E.R 438 20 20 EPICLON 1050-75X 100 EPOMIC R-304 25 EPOTOHTO YDCN-704P 20 20 curing agents or curing accelerator dicyandiamide(25%) 12 12 CURESOL 2MA-OK 2 PHENOLITE VH-4170 15 dimethylbensylamine 0.2 0.2 polyvinyl acetal resin DENKA BUTYRAL # 5000A 20 15 50 40 components other resins or inorganic filler MILLIONATE MS-50 10 SHONOL BLS-364 30 AEROSIL #300 2 results flexibility of the coated adhesive good good good good no good strength of press-bonding good good no good no good good blister after curing good good no good no good good peel strength, bar (Kgf/cm 2 ) 2.01 (2.05) 1.82 (1.86) impossible to measure due to blister 1.78 (1.82) soldering heat resistance (Sec.) 120< 120< 120<

Claims: An adhesive-backed copper foil provided on its one surface with an adhesive comprising (I) a non-modified epoxy resin and a rubber-modified epoxy resin in the total amount of 60 to 100 parts by weight wherein the amount of said rubber-modified epoxy resin is 0.5 to 20 parts by weight, said rubber-modified epoxy resin being the reaction product of an epoxy resin and a rubber, and (II) 5 to 30 parts by weight of a polyvinyl acetal resin. An adhesive-backed copper foil according to claim 1, wherein said rubber is selected from the group consisting of butadiene rubber having a terminal carboxyl group, acrylonitrile-butadiene copolymers and isoprene rubber. An adhesive-backed copper foil according to claim 1, wherein said epoxy resin is selected from the group consisting of a bisphenol A-type epoxy resin, a bisphenol F-type epoxy resin, a novolak-type epoxy resin, o-cresol novolak-type epoxy resin, a brominated epoxy resin, triglycidyl isocyanurate, tetrakis(glycidyloxyphenyl)ethane, epoxidized polybutadiene, a glycidyl amine compound and a glycidyl ester compound. An adhesive-backed copper foil according to claim 1, wherein said adhesive is coated on a roughened surface of said copper foil.

Inventors: SATOH TETSURO, SATOH, TETSURO
Applicants: MITSUI MINING & SMELTING CO, MITSUI MINING & SMELTING CO., LTD.
Application year: 1995
Main classification: C09J163
IPC codes: H05K3, C09J163