Elastomer-modified polyester SMC

Abstract: There are described elastomer-modified polyesters for sheet molding compounds (SMC) obtained by copolymerizing the elastomer with the polyester. The products have extended storage times without phase separation also enhanced impact resistance when formed into molded articles.

Description: This development relates to an elastomer-modified polyester sheet molding compound (SMC). Specifically, this development relates to elastomer-modified polyester for improved impact-resistant SMC. Further, it is well known that the incorporation of rubber into polyesters significantly lowers the temperature at which laminates begin to soften and hence lowers the upper temperature bound where they will be useful (sometimes called the heat-distortion temperature or HDT). This development also relates to using these compositions for applications in the automotive industry. Unsaturated resin compositions are finding increased use in the automotive industry in SMC formulations from which component parts, especially body panels, can be molded. The unsaturated resin compositions contain, in addition to the unsaturated polyesters and monomer components, so called "low-profile" additives which are thermoplastic polymers that act to prevent undesirable shrinkage as the composition is being molded into a thermoset article. Of particular note recently have been efforts to improve the impact resistance of exterior automotive body panels. One skilled in the field knows that polyester body panels display quite brittle behavior in impact tests relative to traditional materials (e.g., steel). The cause of the low impact resistance generally lies in the dual performance required for these materials: superior reproduction of the mold surface (excellent surface aesthetics) in addition to the usual stiffness and strength requirements typically requires the formulator to employ highly reactive unsaturated polyesters in addition to high amounts of thermoplastic (low profile additive). The formulators also know that blending rubbers with thermosets may improve impact resistance by absorbing the energy of impact and delaying the onset of catastrophic failure. However, adding certain hydrocarbon rubbers to polyesters appears to degrade impact resistance. In the example of simply blending poly(butadiene- co -acrylonitrile) rubber and unsaturated polyester, incompatibility between the rubber and polyester leads to phase separation on a macroscopic scale. Thus, if one blends polyester with rubber and then immediately cures it, the rubber particles apparently assume a very large size and act as failure sites. Further, it is not possible to preblend rubber and polyester for later molding since during storage phase separation occurs between the components and usually gives a rubber phase above the polyester phase. In addition, when rubber is employed to improve impact resistance and adhesion of polyesters, the useful upper service temperature (HDT) significantly decreases. This is due to the lower glass transition temperature of the rubber relative to the pure thermoset. The above situation is greatly improved if rubber is incorporated into the polyester chain. The resulting molecular structure may be visualized as of the (AB) n type, wherein A constitutes polyester segments and B rubber segments. This structure allows significantly better compatibility of rubber and polyester, resulting in a single phase on storage. In this scenario, the rubber phase exists as extremely small rubbery domains dispersed in the polyester phase. Further, incorporation of unsaturated end groups to increase the cross-link density of the resulting polyester multi-block polymer significantly improves the HDT, nearly to that of the unmodified resin. In the method of Siebert, et al. (U.S. 5,268,452), the use of several end-functionalized reactive liquid polymers (named RLPs) based on the poly(butadiene- co -acrylonitrile) family are discussed. This patent encompasses such end groups as carboxy, hydroxy, and epoxy. It teaches the addition of any of the RLPs with the above end groups at the beginning of the polyester preparation, regardless of polyester component choice, is sufficient to incorporate the rubber into the polyester backbone. We have found that only combination of specific RLPs with carefully modified polyesters will result in successful incorporation of rubber into the polyester backbone. Thus, care must be taken in choice of rubber as well as the polyester components if macrophase separation is to be prevented. Overall, attempts to enhance the compatibility between the components are necessary. A convenient measure of compatibility between two polymers is the solubility parameter, δ, (Grulke, E.A., in "Solubility Parameters", Polymer Handbook, 3rd ed., J. Brandup and E.H. Immergut, eds., John Wiley and Sons, N.Y., 1989). In styrene, δ for most polyesters ranges from 9 to 13 (cal/cm 3 ) 1/2 while for most hydrocarbon rubbers it ranges from 7.5 to 8.5 (cal/cm 3 ) 1/2 . If Δδ, the difference in solubility values for two components, is greater than about 1 (cal/cm 3 ) 1/2 , the components will phase separate in most cases. Since most polyesters tend toward the higher end of the range and rubbers to the lower, single-phase solutions of blended rubber and polyester over time have not been observed. We have now found a route to the synthesis of (AB) n copolymers of polyester and hydrocarbon rubbers that allows excellent compatibility as displayed by extended storage times without phase separation and enhanced impact resistance. In accordance with the invention, there is provided a composition for a sheet molding compound comprising a copolymer which is the reaction product of an elastomer and an unsaturated polyester, the polyester being a reaction product of one or more polyhydric alcohols, one or more ethylenically unsaturated polycarboxylic acids and at least one of dicyclopentadiene, long chain hydrocarbon acids and long chain hydrocarbon glycols, and the elastomer is a hydrocarbon rubber having chain ends with reactive functional groups accessible to reaction with the polyester and wherein the elastomer has a solubility parameter of 7 to 12 (cal/cm 3 ) 1/2 , the polyester has a solubility parameter of 8 to 13 (cal/cm3) 1/2 , and the difference between the solubility parameters of the elastomer and of the polyester is 1 (cal/cm 3 ) 1/2 or less, the solubility parameter being measured as described by Grulke in "Solubility Parameters", Polymer Handbook, 3rd ed., John Wiley & Sons, N.Y. 1989. A convenient choice for the rubber component is a copolymer of butadiene and acrylonitrile. The rubber employed generally displays a δ in the 7 to 12 (cal/cm 3 ) 1/2 range. Preferably, δ ranges from 7.5 to 9.5 (cal/cm 3 ) 1/2 . An acrylonitrile content of the rubber of at least 20% (higher levels give δ values closer to that of polyester) is preferred. For ease of process, the rubber generally should display a low viscosity. Reactive functional groups must be attached to the chain ends of the rubber and be accessible to reaction with polyester chain ends (e.g., epoxy groups). The rubber may consist of copolymers with other components such as isoprene and cyclopentadiene. The polyester generally displays a δ in the range of 8 to 13 (cal/cm 3 ) 1/2 and preferably 8 to 12. The polyester must be of generally low viscosity and high acidity before reaction of rubber with the polyester. The polyester generally is synthesized with groups (modifiers) that add considerable hydrophobicity to the alkyd. We have found the most useful modifier to be dicyclopentadiene from both a cost and performance standpoint. Long hydrocarbon chain acids such as 1,10-dodecanedicarboxylic acid as well as long chain glycols, are also useful in adding hydrophobicity to the alkyd. Other modifiers such as glycidyl-acrylates, propoxylated allyl alcohol, and the like will improve HDT. The glycidyl-acrylates are represented by the formula: wherein R 1 is hydrogen or an alkyl radical having 1 to 5 carbon atoms, and R 2 is a glycidyl ester group having the formula: or wherein R 3 ranges from C 7 H 14 O 3 - to C 11 H 20 O 3 -, wherein the glycidyl-acrylates terminate some of the low molecular weight unsaturated polyester with unsaturated end groups. The unsaturated polyester comprises the polycondensation reaction product of one or more dihydridic alcohols and one or more ethylenically unsaturated polycarboxylic acids. By polycarboxylic acid is generally meant the polycarboxylic or dicarboxylic acids or anhydrides, polycarboxylic or dicarboxylic acid halides, and polycarboxylic or dicarboxylic esters. Suitable unsaturated polycarboxylic acids, and the corresponding anhydrides and acid halides that contain polymerizable carbon-to-carbon double bonds, may include maleic anhydride, maleic acid, and fumaric acid. A minor proportion of the unsaturated acid, up to about forty mole percent, may be replaced by dicarboxylic or polycarboxylic acid that does not contain a polymerizable carbon-to-carbon bond. Examples of which include o-phthalic, isophthalic, terephthalic, succinic, adipic, sebacic and methyl-succinic. Dihydric alcohols that are useful in preparing the polyesters include 1,2-propane diol (hereinafter referred to as propylene glycol), dipropylene glycol, diethylene glycol, 1,3-butanediol, ethylene glycol and glycerol. Examples of suitable unsaturated polyesters are the polycondensation products of: (1) propylene glycol and maleic and/or fumaric acids; (2) 1,3-butanediol and maleic and/or fumaric acids; (3) combinations of ethylene and propylene glycols (approximately 50 mole percent or less of ethylene glycol) and maleic and/or fumaric acids; (4) propylene glycol, maleic and/or fumaric acids and dicyclopentadiene reacted with water. In addition to the above-described polyesters, one may also use dicyclopentadiene-modified unsaturated polyester resins as described in the Pratt, et al., U.S. Patent No. 3,883,612. The monomer component of the resinous system comprises materials that copolymerize with the unsaturated polyester. The ethylenically unsaturated monomer that is copolymerizible with the unsaturated polyester is most generally styrene; however, methyl-styrene is also useful, as are acrylates and methacrylates such as methyl-acrylates, ethyl-acrylate, methyl-methacrylate and ethyl methacrylate. The low-profile additive component of the resinous system comprises the thermoplastic polymers which cause phase separation and porosity during the curing reaction. Low-profile additives are materials that, when mixed in an unsaturated polyester and cured, result in a multi-phase system. Some polymers that are useful as low-profile additives include homopolymers and copolymers of acrylic and methacrylic acid esters, cellulose acetate butyrate, vinyl acetate homopolymers and copolymers, polyurethanes prepared from polyisocyanates, preferably diisocyanates, and polyether polyols, numerous saturated polyesters, polycaprolactone, styrene-butadiene copolymers, some modified celluloses, and certain alkyl oxide polymers. The above list of low-profile additives is not intended to list all low-profile additives but rather to show examples of materials which have been used to cause the multi-phase morphology present in low-profile resins. The acid number to which the polymerizable unsaturated polyesters are condensed generally ranges from 10 to 50 mg KOH/g resin. Preferably, the acid number ranges from 15 to 40 mg KOH/g resin. The weight average molecular weight of the unsaturated polyester prior to reaction with rubber ranges from 500 to 5,000 g/mole. Preferably, the molecular weight ranges from 750 to 2,500 g/mole. After reaction with rubber, the molecular weight ranges from 5,000 to 30,000 g/mole. Preferably, the molecular weight after reaction with rubber ranges from 10,000 to 20,000 g/mole. In another aspect of the invention, a reactor is loaded with diacids and glycols, inhibitors, and dicyclopentadiene. Polycondensation is carried out at 175°C to 240°C. When the acid value of the polyester reaches a value of 55 to 85, the reaction mass is cooled to 110°C to 150°C, at which time catalysts and inhibitors are added. Then the rubber is added and the reaction mass held at temperature for 30 to 60 minutes. The final acid value ranges from 17 to 35 mg KOH/g resin. The mass is then cooled and let down into styrene. In another aspect of the invention, a reactor is loaded with diacids and glycols and inhibitors. Polycondensation is carried out at 175°C to 240°C to an acid value of less than 10 mg KOH/g resin. Maleic anhydride and dicyclopentadiene are then added, and the condensation is continued. When the acid value of the polyester reaches a value of 55 to 85, the reaction mass is cooled to 110°C to 150°C, at which time catalysts and inhibitors are added. Then the rubber is added and the reaction mass held at temperature for 30 to 60 minutes. The final acid value ranges from 17 to 35 mg KOH/g resin. The mass is then cooled and let down into styrene. In another aspect of the invention, a reactor is loaded with diacids and glycols and inhibitors. Polycondensation is carried out at 175°C to 240°C to an acid value of less than 10 mg KOH/g resin. Maleic anhydride and dicyclopentadiene are then added, and the condensation is continued. When the acid value of the polyester reaches a value of 55 to 85, the reaction mass is cooled to 110°C to 150°C, at which time catalysts and inhibitors are added. Then the rubber is added, and the reaction mass held at temperature for 30 to 60 minutes. The final acid value after reaction with rubber ranges from 25 to 35 mg KOH/g resin. The reaction mass is cooled further to 105°C to 130°C, and a second catalyst and inhibitors are added. Further, oxygen is allowed to enter the reactor by an air sparge at a sufficient rate. At this point, glycidyl methacrylate is added at such a rate so as to prevent the reaction from heating above 130°C. After the addition of GMA is complete, the reactor is held at 120°C to 130°C for 1 hour to complete the reaction. At this point, the mass is let down into styrene and cooled. The sheet molding compound of this invention also may include other conventional materials. For example, conventional chemical thickeners may be physically mixed into the resin. The chemical thickeners generally include metal oxides, hydroxides, and alkoxides of Group II, III, or IV from the Periodic Table. Calcium oxide and magnesium oxide or the respective hydroxides are most often employed. In preferred embodiments, the thickener is present in amounts ranging from 0.5 to 6 parts, by weight. The thickener is generally suspended in a carrier resin, as is known in the art. The carrier material comprises a composition which does not react with the thickener, such as, for example, polymethylmethacrylate, polyvinylacetate, saturated or unsaturated polyesters, and similar materials. The carrier resin is present in amounts ranging from 0.5 to 8 parts, by weights, based on one hundred parts of the system. Catalysts also may be incorporated in small amounts into thermosetting polyester resins containing ethylenically unsaturated monomer to aid in curing or cross-linking the unsaturated polyester with the monomer. Such catalysts are well known and may be similarly utilized in this invention to aid in curing the unsaturated polyester and monomer mixed with the low-profile thermoplastic polymer. Typical catalysts, for example, include organic peroxide and peracids such as tertiary butyl perbenzoate, tertiary butyl peroctoate and benzoyl peroxide. The amounts of catalysts may be varied with the molding process and similarly varied with the level and types of inhibitors utilized, in a manner well known in the art. In preferred embodiments, the catalyst is present in amounts ranging from 0.5 to 2.5 parts, by weight, based on one hundred parts of the system. Curing of the composition is carried out under heat and pressure typically, in closed, preferably positive-pressure-type molds. Mold-release agents may be added to the compositions to perform their normal function, as is well understood in the art. In preferred embodiments, the mold-release agents are present in amounts ranging from 0.5 to 6.0 parts, by weights, based on hundred parts of the four-component resin system. Fibers, fillers, and pigments normally added to resin compositions can be likewise in formulating the sheet molding composition of this invention. Reinforcing fibers or fibrous reinforcement is taken to mean glass fibers in one form or another, such as glass fabrics, chopped glass strands, chopped or continuous-strand glass-fiber mat; however, the terms also include reinforcing agents which may also be used if desired, for example, asbestos, cotton, synthetic organic fibers, and metals. Fillers, usually inert, and inorganic material useful with the compositions include, for example, clay talc, calcium carbonate, silica and calcium silicate. In preferred embodiments, the fillers are present in amounts ranging from 165 to 250 parts, by weight, based on one hundred parts of the system. Examples of pigments include carbon black, iron oxide, titanium dioxide, and the like, as well as organic pigments. In preferred embodiments, the pigments are present in amounts ranging from 0 to 4 parts, by weight, based on one hundred parts of the four-component resinous system. In one aspect of the present invention, the preparation of the sheet molding composition is generally carried out by blending together a first portion comprising the unsaturated polyester, the low-profile additive, the monomer, and such additives as a catalyst, mold-release agent, and fillers. This is generally known in the industry as the A-side formulation. The second portion (generally known as the B-side formulation) comprises the thickening agent and a carrier resin therefor, and such additives as pigments and mold-release agents. In another aspect of the invention, an additional or secondary monomer may be added to the B-side formulation in which the thickener is suspended. The additional monomer comprises vinyl toluene or styrene and is present in amounts ranging from 1 to 8 parts, by weight, based on one hundred parts of the four-component resinous system. The sheet molding composition of the present invention can be prepared by mixing the components in a suitable apparatus at temperatures which are conventional and known to those skilled in the art. Once the sheet molding composition is formulated, the composition can be molded into thermoset articles having a desired shape. The actual molding cycle will, of course, depend upon the exact composition being molded. In preferred embodiments, suitable molding cycles are conducted at temperatures ranging from 250°-350°F (121°-177°C) for periods of time ranging from 1/3 to about 5 minutes. The following formulations are provided to illustrate examples of the compositions of the present invention. Example I Into a 4-liter reactor fitted for polyester condensation is placed: 471 g isophthalic acid 378 g dipropylene glycol 254 g 2-methyl-1,3-propanediol The contents are allowed to react at 200°C with a nitrogen gas flow to remove water until the acid value is 9.5 mg KOH/g resin. At this point, the following are added: 821 g maleic anhydride 510 g dicyclopentadiene The reaction is held at 155°C for 30 minutes. At this point, the following is added to the reactor: 378 g dipropylene glycol 254 g 1-methyl-1,3-propanediol 0.5 g Toluhydroquinone The reactor is heated to 195°C, and reaction is allowed to proceed until a Gardner timed bubble of 6.0 1/100 min. (2:1 resin:styrene) and an acid value of 35 is reached. The reactor is cooled to 130°C, and the following is added: 3.4 mL N,N-dimethylbenzylamine 350 g EPI-REZ 58042 (epoxy-terminated poly(butadiene-co-acrylonitrile), acrylonitrile content 26%, acid value = 1.5, viscosity = 500,000 cps (500 Pa·s) at 20°C, δ = 9.15 (cal/cm 3 ) 1/2 , number average molecular weight = 3,150 g/mole, Tg = 39°C). The reaction is allowed to continue at 150°C for 1 hour. At that time, the acid value of 18 and the Gardner timed bubble viscosity was 19.5 1/100 minute. The reaction mass was let down into the following mixture: 1,560 g styrene 0.0746 para -Benzoquinone 0.16 g mono- tert -butylhydroquinone One hundred (100) g of the resin was mixed with 1.0 g benzoyl peroxide and placed into an oven at 60°C for 16 hours. The casting was then post cured at 120°C for 4 hours. Table I and Table II below contain physical property data for this material. Example II Into a 4 liter reactor fitted for polyester condensation is placed: 463 g isophthalic acid 284 g dipropylene glycol 254 g 2-methyl-1,3-propanediol The contents are allowed to react at 200°C with a nitrogen gas flow to remove water until the acid value is 6.3 mg KOH/g resin. At this point, the following are added: 850 g maleic anhydride 400 g dicyclopentadiene The reaction is held at 155°C for 30 minutes. At this point, the following is added to the reactor: 395 g dipropylene glycol 202 g 1-methyl-1,3-propanediol 0.5 g Toluhydroquinone The reactor is heated to 195°C, and reaction is allowed to proceed until a Gardner timed bubble of 19 l/100 minute (2:1 resin: styrene) and an acid value of 83 is reached. The reactor is cooled to 130°C and the following is added: 3.4 mL N,N-dimethylbenzylamine 333 g EPI-REZ 58042 The reaction is allowed to continue at 150°C for 1 hour. At this point, the reactor was cooled to 125°C, and air was introduced to the mixture by a sparge line. To the reaction mass was then added: 1.0 g Butylatedhydroxytoluene (BHT) 3.4 mL N,N-Dimethylbenzlamine 0.3 g para -Benzoquinone 250 g Glycidyl methacrylate (GMA) The GMA was added at such a rate so as not to exceed 125°C. After addition was complete, the reaction was held for 1 hour at 120°C. At that time, the acid was 35 and the Gardner timed bubble viscosity was 130 1/100 minute. The reaction mass was let down into the following mixture: 1,560 g styrene 0.0746 g para -Benzoquinone 0.16 g mono- tert -butylhydroquinone One hundred (100) g of the resin was mixed with 1.0 g benzoyl peroxide and placed into an oven at 60°C for 16 hours. The casting was then post cured at 120°C for 4 hours. Table I and Table II below contain physical property data for this material. Mechanical Data Control Example I Example II Notched Izod (J/m) 35.3 39.6 35.6 Unnotched Izod (J/m) 94.3 182.2 140.9 Flexural Stress MPa 86.1 77.2 132.7 Flexural Modulus GPa 3.9 2.8 4.5 Tensile Stress MPa 46.6 46.4 71.3 Tensile Modulus GPa 3.1 2.5 3.6 Tensile Elongn. % 1.7 3.3 2.8 Thermal Data Coef. of Thermal Expansion, in/in/°C (mm/mm/°C) Control 61.8 Example I 69.2 Example II 56.2 The data shows that the inventive compositions have mechanical and thermal properties better than the control polyester. Example III To a 10-gallon stainless steel reactor fitted for polyester condensation we loaded: 3.23 kg dipropylene glycol 2.98 kg 2-methyl-1,3-propanediol 5.43 kg of isophthalic acid The reactor was brought to 200°C, and condensation continued until the acid value was 10 mg KOH/g resin. The reaction mass was cooled to 175°C, and the following ingredients were added: 13.03 kg maleic anhydride 3.1 kg Dicyclopentadiene The reaction was held at 155°C for 30 minutes. At this point, the following is added to the reactor: 3.63 kg dipropylene glycol 2.98 kg 2-methyl-1,3-propanediol 5.0 g toluhydroquinone The reactor is heated to 205°C, and condensation was effected until the acid value reached 60 mg KOH/g resin. The reactor was cooled to 140°C, and the following ingredients were added: 35.0 g N,N-dimethylbenzylamine 1.57 kg ER-58042 The rubber was allowed to react at 150°C for 1 hour. After the reaction with rubber, the resin was cooled to 120°C and let down into the following mixture: 34 kg styrene 0.51 g para -Benzoquinone 2.56 g mono- tert -Butylhydroquinone

Claims: A composition for a sheet molding compound comprising a copolymer which is the reaction product of an elastomer and an unsaturated polyester, the polyester being a reaction product of one or more polyhydric alcohols, one or more ethylenically unsaturated polycarboxylic acids and at least one of dicyclopentadiene, long chain hydrocarbon acids and long chain hydrocarbon glycols, and the elastomer is a hydrocarbon rubber having chain ends with reactive functional groups accessible to reaction with the polyester and wherein the elastomer has a solubility parameter of 7 to 12 (cal/cm 3 ) 1/2 the polyester has a solubility parameter of 8 to 13 (cal/cm 3 ) 1/2 , and the difference between the solubility parameters of the elastomer and of the polyester is 1 (cal/cm 3 ) 1/2 or less, the solubility parameter being measured as described by Grulke in "Solubility Parameters", Polymer Handbook, 3rd ed., John Wiley & Sons, N.Y., 1989. A composition according to claim 1, wherein the elastomer has a solubility parameter of 7.5 to 9.5 (cal/cm 3 ) 1/2 and the polyester has a solubility parameter of 8 to 12 (cal/cm 3 ) 1/2 . A composition according to claim 1 or claim 2, wherein the hydrocarbon rubber is a diene rubber. A composition according to claim 1 or claim 2, wherein the rubber is polybutadiene rubber. A composition according to any one of claims 1 to 4, wherein the functional groups on the elastomer are epoxy groups. A composition according to any one of claims 1 to 5, wherein the elastomer contains at least 20% acrylonitrile. A composition according to any one of claims 1 to 6, wherein the polyester has chain ends with reactive functional groups derived from glycidylacrylates or carboxyl or hydroxyl modified allylic compounds. A composition according to claim 7, wherein the reactive functional groups are derived from propoxylated allyl alcohol. A composition according to claim 7, wherein the reactive functional groups are derived from glycidyl-acrylate or glycidyl methacrylate. A composition according to any one of claims 1 to 9, including also one or more olefinically unsaturated monomers which copolymerize with the polyester. A composition according to any one of claims 1 to 10, wherein the polyester is the reaction product of isophthalic acid, dipropylene glycol, maleic anhydride and dicyclopentadiene, and the elastomer is epoxy-terminated poly(butadiene-co-acrylonitrile). A composition according to any one of claims 1 to 10, wherein the polyester is the reaction product of isophthalic acid, dipropylene glycol, maleic anhydride, dicyclopentadiene and glycidylmethacrylate, and the elastomer is epoxy-terminated poly(butadiene-co-acrylonitrile). A composition according to any one of claims 10 to 12, including styrene. A composition according to any one of claims 1 to 13, including also one or more thermoplastic polymers which causes phase separation and porosity during the curing reaction. A sheet molding compound including a composition according to any one of claims 1 to 14.

Inventors: BECKMAN JAY J, HAGER WILLIAM, KRUMLAUF PAUL R, BECKMAN, JAY J., HAGER, WILLIAM, KRUMLAUF, PAUL R.
Applicants: OWENS CORNING FIBERGLASS CORP, OWENS CORNING
Application year: 1995
Main classification: C08G81
IPC codes: C08L67, C08F299, C08J5, C08L63, C08G81, C08G59