Method and apparatus for laser dye ablation printing with high intensity laser diode

Abstract: A method and apparatus for performing laser dye ablation printing with a laser diode having improved contrast and uniformity utilizes a high intensity write beam. Film exposed to the high intensity write beam exhibits a Dmin of less than 0.11 with significant reductions in visible raster lines. The intensity of write beam generated by the laser diode at the film is preferably at least 1.0 mW/square micron.

Description: Field of the Invention The invention relates in general to the field of laser printing. More specifically, the invention relates to a method and apparatus for performing laser dye ablation printing utilizing a high intensity laser diode source. Background Printing systems that utilize the physical interaction of a laser beam with a coated film material are commercially available. The Crosfield Laser Mask system (available from the Crosfield Company of Glen Rock, New Jersey), for example, utilizes a film support on which graphite particles in a binder are coated. The film support is exposed to a YAG laser. The heat generated by the absorption of the laser beam by the carbon particles causes the carbon to ablate from the film and transfer to a paper receiver. The image is built up, pixel by pixel, by removing carbon from low density areas of the image. The paper receiver constitutes a proof of the image, while the film from which the carbon was removed constitutes a negative transparency of the image. The transparency is utilized in the graphics art industry to expose or "burn" a lithographic plate. While the system has met with some commercial success in the newspaper industry, the use of the YAG laser causes some difficulties. It is difficult, for example, to maintain and control the YAG laser, which requires substantial cooling and has a "noisy" beam in which the power varies erratically. The system also suffers from an inherent lack of resolution caused by the long wavelength of the YAG laser emission. In order to overcome the difficulties experienced with the YAG laser, it has been suggested that a system be developed that utilizes a laser diode to expose the film support. U.S. Patent 4, 973,572, for example, discusses the use of a dye coating consisting of cyan, magenta and infra-red dyes in a cellulose nitrate binder which is exposed to a diode laser beam of .044 mW/square micrometer (See Example 3). An air stream was blown over the surface of the film support to remove sublimed dye. It has been found that the resulting dye removal gives a Dmin (minimum optical density) of 0.30. A Dmin value of 0.30, however, is too high to be generally useful in the graphic arts industry, as the piecing together of images with a Dmin of 0.30 with normal silver halide images having a Dmin of 0.04 and the exposing of a lithoplate with the composite, would result in the high Dmin image portions of the composite image formed therefrom being four times underexposed compared to the silver halide portions of the composite image. The result would be significant dot shrinkage in the underexposed portions of the image, with a corresponding change in printed density on a press. In fact, it is preferably that Dmin be limited to less than 0.11 to yield acceptable results. The high Dmin portions of the image also suffer from visible raster lines, which have been found (as will be discussed in greater detail below) to be caused by the melting of the polyester substrate by the heating action of the diode laser beam. The melted raster lines may be viewed as a kind of non-uniformity in the image. Although the raster lines do not have an impact on contact image exposure, they do cause considerable flare in projection imaging systems like overhead projectors, and do constitute a noticeable cosmetic defect to customers accustomed to the uniform appearance of a silver halide negative. In view of the above, it is an object of the invention to provide a method and apparatus for performing laser dye ablation printing utilizing a laser diode with improved contrast and uniformity, i.e., with Dmin reduced to preferably less than 0.11 and reductions in the appearance of raster lines. Summary of the Invention The invention provides a method and apparatus for performing laser dye ablation printing utilizing a laser diode with improved contrast and uniformity. Film exposed in accordance with the invention has a Dmin (minimum optical density) of less than 0.11 and exhibits significant reductions in visible raster lines. Specifically, a laser printing apparatus is provided that includes a mechanism for retaining a film to be exposed, a laser diode source for generating a write beam, and a mechanism for scanning the write beam across the film to generate an image. The intensity of write beam generated by the laser diode source at the film is preferably at least 1.0 mW/square micrometer. During operation, a film to be exposed is placed in the retaining mechanism and the write beam is scanned across the film to generate an image. Brief Description of the Drawing The invention will be described in greater detail with reference to Fig. 1, which illustrates a laser printing apparatus in accordance with the invention. Detailed Description of Preferred Embodiment The invention is based, in part, on the discovery that the limit as to how low the Dmin value can go is a function of energy delivered to the film support. By utilizing a drum printer with a laser diode running at full power and varying the rotation speed of the drum, it has been observed that the Dmin value is high at fast rotations of the drum (low energy per unit area), the Dmin values improve as the drum is slowed (higher energy per unit area), but that the Dmin value begins to increase again as the drum is slowed further (highest energy per unit area). It is believed that at slow rev/min, the energy delivered to the film support is so high that the polyester base of the film begins to melt and discolor from the generated heat, thereby causing an increase in Dmin and the appearance of raster lines. Another factor in determining the limit of the Dmin value of the film is the intensity of the laser spot. If a low power lens is used that writes a large area laser spot, the intensity of the laser beam will be low (for a given laser diode power). A high power lens that writes a small area spot will give a high intensity beam. A low intensity beam may not supply enough energy per unit area to raise the temperature of the dye layer high enough to remove all of the dye, which results in a high Dmin value. Thus, obtaining the best Dmin value is not just a factor of increasing the power of the laser source, but also is related to the intensity of the laser at the film surface. In order to define the laser intensity needed for satisfactory image quality, an experiment was conducted using a laser printing apparatus of the type illustrated in Fig. 1. The apparatus includes an 70.446 cm circumference drum 10 driven by a motor 12 that is used to retain a film to be exposed, a printhead 14 incorporating a 500 milliwatt laser diode (power measured at drum surface) operating at 830 nm, and a motor driven leadscrew 16, operating at a 945 lines per centimeter pitch, which is used to linearly index the printhead 14. The average spot size of the laser was 112 square micrometers, based on the 945 lines per centimeter pitch, and this value was used in calculations of the intensity of the laser beam (the measured gaussian beam of the laser at the 1/e 2 point was 25 x 12 micrometers). A graphics film 18 was loaded onto the drum 10 and exposed to a series of power steps starting at 300 mW and decreasing by 6/255 of 300 for each step of the leadscrew 16. The graphics film 18 was prepared using a 100 micrometer thick layer of polyethleneterphthalate coated with a mixture of the following dyes at a thickness of 24.2 cc/square meter: 100 parts cyan dye # 1 100 parts cyan dye # 2 175 parts yellow dye 175 parts infra-red dye 100 parts ultra-violet dye 350 parts nitrocellulose 11,900 parts solvent (metho iso-butyl ketone) The compositions of the dyes are illustrated in Appendix A, attached hereto, which forms part of this specification. When dry, the film was overcoated with the following solution at 21.5 cc/square meter: 300 parts nitrocellulose 15 parts surfactant (Dow Corning silicon oil DC510) 24,000 parts solvent (butyl acetate) The drum 10 was rotated at 100, 200, 300, 400 and 500 rev/min, successively, and the graphics film 18 was exposed long enough to print several millimeters of an image at each of the specified drum speeds. After exposure, the Dmin densities were measured on an X-Rite 361T graphic arts densitometer (X-Rite is a registered trademark of X-Rite Company, of 4101 Roger B. Chaffee Drive, SE, Grand Rapids, Michigan) in the ultraviolet mode. The densitometer was zeroed on air. The results of the experiment are shown in Table 1 below: mW/µ 2 Laser Intensity 100 rpm 200 rpm 300 rpm 400 rpm 500 rpm mW Laser Power 2.679 0.587 0.265 0.109 0.077 0.074 300.000 2.614 0.583 0.254 0.119 0.084 0.075 292.800 2.550 0.571 0.247 0.114 0.083 0.075 285.600 2.491 0.552 0.234 0.104 0.079 0.074 279.000 2.427 0.525 0.230 0.100 0.080 0.074 271.800 2.363 0.495 0.215 0.095 0.080 0.075 264.600 2.298 0.471 0.198 0.093 0.081 0.077 257.400 2.239 0.455 0.185 0.089 0.082 0.080 250.800 2.175 0.460 0.128 0.087 0.083 0.083 243.600 2.111 0.445 0.135 0.085 0.083 0.086 236.400 2.046 0.432 0.135 0.085 0.083 0.087 229.200 1.988 0.419 0.130 0.085 0.084 0.094 222.600 1.923 0.404 0.121 0.086 0.087 0.098 215.400 1.859 0.403 0.110 0.086 0.088 0.100 208.200 1.795 0.397 0.108 0.086 0.091 0.100 201.000 1.730 0.371 0.097 0.087 0.096 0.102 193.800 1.671 0.264 0.093 0.088 0.102 0.104 187.200 1.607 0.311 0.093 0.089 0.107 0.109 180.000 1.543 0.289 0.092 0.091 0.113 0.116 172.800 1.479 0.249 0.089 0.096 0.112 0.131 165.600 1.420 0.216 0.090 0.101 0.115 0.141 159.000 1.355 0.189 0.093 0.105 0.118 0.160 151.800 1.291 0.169 0.094 0.113 0.125 0.197 144.600 1.227 0.161 0.096 0.121 0.139 0.273 137.400 1.168 0.145 0.100 0.132 0.161 0.391 130.800 1.104 0.134 0.103 0.127 0.210 0.598 123.600 1.039 0.128 0.106 0.143 0.277 0.796 116.400 0.975 0.123 0.117 0.161 0.405 1.084 109.200 0.916 0.121 0.131 0.195 0.625 1.363 102.600 0.852 0.121 0.152 0.290 1.014 1.730 95.400 0.788 0.125 0.175 0.519 1.476 2.101 88.200 0.723 0.133 0.211 0.972 1.872 2.391 81.000 0.659 0.154 0.329 1.479 2.278 2.703 73.800 0.600 0.196 0.701 2.025 2.637 2.932 67.200 0.536 0.264 1.566 2.611 2.943 3.066 60.000 0.471 0.681 2.398 2.948 3.128 3.150 52.800 0.407 2.160 2.951 3.209 3.133 3.184 45.600 0.348 2.843 3.184 3.172 3.219 3.340 39.000 0.284 3.390 3.300 3.340 3.310 3.320 31.800 From Table 1, the threshold points where image quality is acceptable was extracted, i.e. the point at which Dmin becomes less than 0.11, and used to calculate the energy required for acceptable image quality. For example, Dmin was equal to 0.100 when the drum was running at 200 rev/min and the average laser intensity (the power of the laser divided by the total area written) was 1.168, yielding a calculated exposure of 526 mJ/cm2 as shown by the calculation: 945/(200/60)(70.446) x 130.8 = 526 mJ/cm 2 The above calculation is based on one square centimeter being equal to 945 linearly written centimeters, the number of rotations per second multiplied by the drum circumference yielding the linear writing speed; dividing 945 by the linear writing speed to yield the square centimeter write time, and multiplying the square centimeter write time by the laser power to yield the exposure energy per square centimeter. Table 2 illustrates exposure levels at additional points wherein Dmin is at about the same level. As shown by the data, higher laser intensities are more efficient and require less power to produce images of acceptable quality, while also permitting faster write times, i.e. higher drum speeds. Average Intensity mWatts per square micrometer Minimum Exposure (Dmin less than 0.11) mJoules per square centimeter 1.168 516 1.42 426 1.671 377 1.859 335 As shown by the data illustrated in Table 1, Dmin increases for a given laser power level as the drum slows. For example, Dmin is 0.100 at 200 rev/min when the average laser intensity is 1.168, but increases to 0.145 when the drum is slowed to 100 rev/min. Similarly, for a drum speed of 200 rev/min, an acceptable Dmin of less than 0.11 is achieved once the average laser intensity reaches about 1.0 mW/square micrometer (Dmin 0.106 for average intensity of 1.039 mW/square micrometer), but begins to climb out of the acceptable range when the average laser intensity increases (Dmin 1.110 for average laser intensity of 1.859 mW/square micrometer). It is believed that the increases in Dmin as the drum slows for a given intensity or as the intensity is increased for a given speed is due to the melting and/or discoloration of the film base as described above, which contributes to deformation and visibility of raster lines. Films having a Dmin of less than 0.11 were observed, however, to have significant reductions in visible raster lines. The amount of raster line thermal distortion of the film base was estimated by holding the film at arms length, observing a light source through the film, and noting the intensity of the rainbow of diffraction colors around the light source. The invention has been described with reference to certain preferred embodiments thereof. It will be understood, however, that modifications and variations are possible within the scope of the appended claims. The invention, for example, is not limited to a rotating drum type printer in which a laser source is linearly indexed with respect to the rotating drum, but is also applicable to printers in which the film is scanned by rotating and indexing the laser source with respect to the film, or printers in which the film is exposed by scanning a laser beam from a fixed laser source. It will also be understood that the results obtained will vary, in some degree, with respect to the characteristics of the film, namely, the threshold intensity for obtaining an acceptable Dmin value for different certain films may require slightly higher or lower intensities than those illustrated in Fig. 1. Reference Numerals 10 Drum 12 Motor 14 Printhead 16 Leadscrew 18 Film

Claims: A laser printing apparatus having means (10) for retaining a film (18) to be exposed, and a laser diode source (14) for generating a write beam, characterized in that the average intensity of the write beam generated by the laser diode source (14) at the film (18) is at least 1.0 mW/square micrometer, such that an image generated by scanning the write beam across the film has a minimum density (Dmin) of less than 0.11. A laser printing apparatus as claimed in claim 1, wherein the average intensity of the write beam generated by the laser diode source (14) at the film (18) is at least 1,039 mW/square micrometer. A laser printing apparatus as claimed in claim 1, wherein the average intensity of the write beam generated by the laser diode source (14) at the film (18) is at least 1.355 mW/square micrometer. A laser printing apparatus as claimed in claim 1, wherein the average intensity of the write beam generated by the laser diode source (14) at the film (18) is at least 1.607 mW/square micrometer. A laser printing apparatus as claimed in claim 1, wherein the average intensity of the write beam generated by the laser diode source (14) at the film (18) is in the range of 1.039 mW/square micrometer to 1.795 mW/square micrometer. A laser printing apparatus as claimed in claim 1, wherein the average intensity of the write beam generated by the laser diode source (14) at the film (18) is in the range of 1.355 mW/square micrometer to 2.491 mW/square micrometer. A method of laser printing an image by retaining a film (18) to be exposed with a film retainer (10) and generating a write beam with a laser diode source (14), characterized by selecting the average intensity of the write beam generated by the laser diode source (14) at the film (18) to at least 1.0 mW/square micrometer, and scanning the write beam across the film (18) to generate an image having a minimum density (Dmin) of less than 0.11. The method of claim 7, wherein the average intensity of the write beam generated by the laser diode source (14) at the film (18) is selected to at least 1.039 mW/square micrometer. The method of claim 7, wherein the average intensity of the write beam generated by the laser diode source (14) at the film (18) is selected to at least 1.355 mW/square micrometer. The method of claim 7, wherein the average intensity of the write beam generated by the laser diode source (14) at the film (18) is selected to at least 1.607 mW/square micrometer. The method of claim 7, wherein the average intensity of the write beam generated by the laser diode source (14) at the film (18) is selected within the range of 1.039 mW/square micrometer to 1.795 mW/square micrometer. The method of claim 7, wherein the average intensity of the write beam generated by the laser diode source (14) at the film (18) is selected within the range of 1.355 mW/square micrometer to 2.491 mW/square micrometer.

Inventors: BAEK SEUNG HO, DEBOER CHARLES DAVID, BAEK, SEUNG HO, DEBOER, CHARLES DAVID, BAEK, SEUNG HO, C/O EASTMAN KODAK CO., DEBOER, CHARLES DAVID, C/O EASTMAN KODAK CO.
Applicants: EASTMAN KODAK CO, EASTMAN KODAK COMPANY
Application year: 1995
Main classification: B41M5
IPC codes: B41M5, B41J2