Regeneration of hydrogen fluoride alkylation catalyst

Abstract: An improved process for the regeneration of an ASO-containing HF catalyst by the removal of ASO from said catalyst through the utilization of a separation column.

Description: This invention relates to the regeneration of a hydrogen fluoride catalyst used in an olefin and isoparaffin alkylation process. In the process for alkylating olefins with isoparaffins in the presence of a hydrogen fluoride (HF) catalyst, a by-product called acid soluble oil (ASO) is produced. This ASO is soluble in the acid phase of an HF catalyst and, because of this solubility, over time, it will build-up in the acid phase of the HF catalyst. If not removed, a high ASO concentration will render the HF catalyst ineffective as an alkylation catalyst. There are certain known methods for regenerating an HF alkylation catalyst, which contains a concentration of ASO, by removing the ASO therefrom. However, many of the known methods for regenerating an HF alkylation catalyst also result in a loss of HF that is lost along with the removed ASO. US-A-4 014 953 discloses a process and apparatus for purifying an HF catalyst from an olefin-isoparaffin alkylation process by separating the HF from ASO in a separator column comprising an upper zone and a lower zone having a plurality of liquid-vapor contact means such as bubble trays in the upper zone. EP-A-0 184 375 relates to a further process of recovering HF from an HF alkylation acid stream containing HF and ASO. The acid stream is charged to a fractionation column, wherein it is stripped with a vaporous hydrocarbon, and an overhead product containing the majority of the HF, and a bottoms product comprising ASO are removed. The bottoms product is mixed with a light hydrocarbon solvent and cooled to induce a phase separation with an upper phase and a lower phase with the lower phase having an HF concentration greater than in the upper phase. It is thus an object of this invention to provide a process for regenerating an HF alkylation catalyst containing therein a concentration of ASO. Another object of this invention is to provide an HF alkylation catalyst regeneration process which removes ASO from such HF alkylation catalyst with a minimum of loss of HF which is removed along with the ASO product. Therefore, the invention provides a process for the regeneration of an HF catalyst as defined in claim 1. Accordingly, the process of the invention for the regeneration of an HF catalyst used in the alkylation of olefins with isoparaffins and containing therein HF and ASO is one which utilizes separation means for separating ASO from the HF catalyst. The separation means comprises a separation column, which defines a separation zone, and a bottom zone, wherein contained within the bottom zone is a series of vertically spaced fractionation trays. HF catalyst is introduced into the intermediate zone of the separation column while a reflux of liquid isoparaffin is introduced into the top zone of the separation column and a vaporous isoparaffin stripping fluid is introduced into the bottom zone of the separation column but below the series of vertically spaced fractionator trays. Removed from the separation column is an overhead stream of HF. Provided in the bottom zone and below the series of vertically spaced fractionator trays are at least two liquid phases including an upper phase having an HF concentration and a lower phase having an HF concentration greater than the HF concentration of the upper phase. The upper phase is removed from the bottom zone and the lower phase is introduced into the intermediate zone of the separation means. In the accompanying drawings: FIG. 1 is a schematic representation of the process which is one embodiment of the invention; FIG. 2 is a vertical cross-sectional view of the separation column; FIG. 3 is a horizontal cross-sectional view of the bottom zone of the separation column as viewed along section 3-3 and showing a fixed valve fractionator tray; and FIG. 4 is a perspective view of a single representative fixed valve of a fixed valve fractionator tray. Other objects and advantages of the invention will be apparent from the foregoing detailed description of the invention and the appended claims. Referring now to FIG. 1 there is shown alkylation reactor 10 which defines a alkylation reaction zone. An olefin feed stream is introduced into alkylation reactor 10 through conduit 12 and an isoparaffin feed stream is introduced into alkylation reactor 10 through conduit 14. The olefin feed generally comprises one or more olefins having from 2 to 5 carbon atoms, while the isoparaffin stream generally comprises isobutane and/or isopentane. In a typical operation, the olefin feed comprises a mixture of propylene and butylenes, while the isoparaffin feed comprises primarily isobutane. A catalyst comprising hydrogen fluoride is introduced into alkylation reactor 10 through conduit 16 and through recycle conduits 18 and 19. In a typical alkylation process operation, the HF is in the liquid phase and has a purity of at least 90%. Fresh makeup catalyst can be introduced as required through conduit 16. The effluent from alkylation reactor 10 is passed to a settler 20 in which a phase separation is made between the acid phase and hydrocarbon phase. The hydrocarbon phase is removed from settler 20 through conduit 22 and passes to downstream processing. The acid phase is removed from settler 20 through conduit 24. At least a portion of the acid phase stream is recycled directly to alkylation reactor 10 through recycle conduit 19. The remainder of the acid phase stream is passed through conduit 28, having interposed therein heater 30 defining a heat transfer zone and providing means for transferring heat to the acid phase stream, to separator column 32. Separator column 32 defines a separation zone comprising a top zone, an intermediate zone, and a bottom zone and provides separation means for separating ASO from the HF of the acid phase. A purified HF stream is removed as a overhead stream from separator column 32 through conduit 18 and is recycled to alkylation reactor 10. An ASO stream can be removed as a bottoms stream from separator column 32 through conduits 34 and 36, and through conduit 37. A liquid hydrocarbon reflux is introduced into the top zone of separator column 32 through conduit 38 having interposed therein condenser 40 defining a heat transfer zone and providing means for transferring heat from the liquid hydrocarbon reflux. The reflux is introduced onto distribution tray 42 located within the top zone of separator column 32. The bottom zone of separator column 32 is provided with a plurality of vapor-liquid contacting means, the fixed valve fractionator trays 50. Stripping isobutane is directed to the bottom zone of separator column 32 by conduit 44. Interposed in conduit 44 is vaporizer 48 which defines a heat transfer zone and provides means for heating and/or vaporizing the stripping isobutane introduced into separator column 32. A bottoms stream comprising ASO is removed from separator column 32 through conduit 34 and passes downstream by way of conduit 36. As an additional embodiment of the invention, at least a portion of the bottoms stream can be recycled or returned to separator column 32 by way of conduit 52. Interposed in conduit 52 is pump 54 for providing work input required to recycle the at least a portion of the bottoms stream to separator column 32. The at least a portion of the bottoms stream is introduced into the intermediate zone of separator column 32 at a location below the introduction entry point of the acid phase but above the bottom zone of separator column 32 wherein contained is a series of vertically spaced, fixed valve fractionator trays 50. The invention includes drawing the bottoms stream from separator column 32 through conduit 37. FIG. 2 provides an enlarged detail of separator column 32, which includes the bottom zone, containing the series of vertically spaced, fixed valve fractionator trays 50. Each of the vertically spaced, fixed valve fractionator trays 50 includes a plate or a deck 56 having a thickness and defining therein a pattern or plurality of apertures 60 (shown in FIG. 3) for permitting the upwardly flow of gas therethrough. Each individual aperture 60 defined by each plate 56 represents a cross-sectional area in the range of from 4.6 to 368 cm 2 (0.005 square feet to 0.40 square feet), preferably from 9.2 to 276 cm 2 (0.01 square feet to 0.30 square feet) and, most preferably, from 13.8 to 230 cm 2 (0.015 square feet to 0.25 square feet). Provided with each fixed valve fractionator tray 50 is a downcomer 62. Each downcomer 62 can comprise vertical plates secured along opposite edges thereof to the interior surface of separator column 32 so as to extend entirely across the interior of separator column 32. The vertical plate of downcomer 62 extends upwardly above the plane of plate 56 so as to provide an edge 64, which defines an overflow weir, having a height of from 12.7 to 101.6 mm (0.5 inches to 4 inches), for retaining a level of liquid upon each plate 56. The vertical plate of downcomer 62 also extends downwardly to close proximity of the fixed valve fractionator tray 50 positioned below. The downcomers 62 are located on opposite sides of the interior of separator column 32 so as to guide liquids from a fixed valve fractionator tray 50 above to a fixed valve fractionator tray 50 below until the liquid passes along the last of such trays and is directed by its downcomer 62 to the bottom of separator column 32. Thus, the arrangement of fixed valve fractionator trays 50 and downcomers 62 provide for the stair step type flow of liquids down the interior of separator column 32 with the liquid passing horizontally along each plate 56 and being directed to the tray below each downcomer 62. The liquid is held on top of each tray by gases that flow upwardly through separator column 32 and passing through apertures 60. Preferably, the gas flow through apertures 60 should be sufficient to prevent a substantial portion of the liquid contained on top of each plate 56 to fall through such apertures and sufficient to maintain a level of liquid on top of each tray 50. The liquid level formed or provided in the bottom zone of separator column 32 primarily contains ASO, but it also contains a concentration of HF. It has been discovered that at least two liquid phases will form in the bottom zone of separator column 32. The top phase, or upper phase 66, will have a concentration of HF that is less than the concentration of HF in the bottom phase, or lower phase 68. Generally, upper phase 66 will have an HF concentration of less than 20 weight percent, preferably less than 10 weight percent and, most preferably, less than 5 weight percent. As for lower phase 68, the HF concentration is greater than the HF concentration of the upper phase and can be as high as about 50 weight percent. In one embodiment of the invention, it is important for the bottoms stream drawn from separator column 32 to be taken from upper phase 66 as opposed to lower phase 68. By removing upper phase 66 as the bottoms stream, as opposed to lower phase 68, HF loss is reduced due to the lower HF concentration in upper phase 66. The removal of upper phase 66 as the bottoms stream in combination with the recycling of lower phase 68, which has a greater concentration of HF than that of upper phase 66, to the intermediate zone of separator column 32, a significant reduction in HF loss with the bottoms stream is achieved. Provided in FIG. 4 is a close-up perspective view of a single aperture 60 and the associated fixed valve 70. As described earlier herein, each plate 56 shall define a plurality of apertures 60, but associated with each of such aperture 60 is a fixed valve 70 fixedly spaced above each aperture 60. The fixed valve 70 has substantially the same shape as its associated aperture 60 and is provided to direct the flow of the gases which are passing upwardly through apertures 60 in the horizontal direction parallel to plate 56. This configuration provides for the intimate contacting of the upwardly flowing gases with the liquid flowing across each plate 56. The distance of the fixed space above each aperture 60, as measured by the distance from the horizontal plane of plate 56 and the horizontal plane of fixed valve 70, is in the range of from 2.54 to 12.7 mm (0.1 inches to 0.5 inches), preferably from 3.81 to 11.43 mm (0.15 inches to 0.45 inches) and, most preferably, from 5.08 to 10.16 mm (0.2 inches to 0.4 inches). An important aspect of the process in the regeneration of an HF catalyst that contains a concentration of ASO is for the separator column 32 to be properly equipped with fixed fractionator trays 50 as described herein. It has been found that the use of such trays in combination with the other features of the inventive process provides for a separation of ASO from the ASO-containing HF catalyst with a reduction in the amount of HF that is lost along with the ASO removed from the ASO-containing HF catalyst. The ASO-containing HF catalyst is charged to the intermediate zone of separator column 32 at a temperature in the range of from 93 to 149°C (200°F to 300°F), preferably, however, in the range of from 121 to 146°C (250°F to 295°F). The temperature of the overhead stream of purified HF comprising HF can be in the range of from 93 to 149°C (200°F to 300°F) and, preferably between 121 to 146°C (250°F and 295°F). As for the isoparaffin reflux stream, its temperature can be in the range of from 4 to 60°C (40°F to 140°F), preferably, 15 to 49°C (60°F to 120°F). The preferred isoparaffin for use as the isoparaffin reflux stream is isobutane. The stripping isoparaffin stream is introduced into the bottom zone of separator column 32 at an entry point below the series of vertically spaced, fixed valve fractionator trays contained within the bottom zone of separator column 32, and is in the form of a vapor or a gas. This vaporous isoparaffin rises upwardly through apertures 60 of each fixed valve fractionator tray 50 and provides for the separation of ASO and HF from the ASO-containing HF catalyst. The preferred stripping isoparaffin is isobutane, and it can have a temperature exceeding 135°C (275 °F) and, preferably, can be in the range of from 149 to 204°C (300°F to 400°F). The pressure at which column 32 is operated can generally be in the range of from 0.69 to 1.38 MPa (100 psia to 200 psia), preferably, from 0.86 to 1.21 MPa (125 psia to 175 psia). The ASO-containing HF catalyst will generally have a concentration of ASO exceeding 1.0 weight percent ASO based on the total weight of the ASO-containing HF catalyst. Specifically, the ASO concentration can be in the range of from 1.25 weight percent to 10 weight percent, and, more specifically, it can be in the range of from 1.5 weight percent to 5 weight percent. The overhead stream of purified HF comprising HF shall have a concentration of ASO that is lower than that of the ASO-containing HF catalyst. Therefore, the ASO concentration will generally be less than 1.0 weight percent. As for the bottoms stream of ASO, it is desirable to minimize the amount of HF in such streams; and, indeed, this is an advantage of the instant invention in that the amount of HF that is lost along with the ASO bottoms stream is much less than for other methods of regeneration of ASO-containing HF catalyst streams. The bottoms stream will comprise ASO at a concentration of at least 50 weight percent based on the total weight of the bottoms streams. Preferably, the ASO concentration can be at least 60 weight percent and, more preferably, it can be at least 70 weight percent. It is most desirable to minimize the concentration of HF in the bottoms stream m order to also minimize the amount of HF lost with the bottoms stream, thus, the HF concentration can be less than 50 weight percent of the bottoms stream, preferably less than 40 weight percent and, most preferably less than 30 weight percent. As discussed elsewhere herein, it has been discovered that the liquid level established in the bottom zone of separator column 32 forms at least two separate liquid phases, including an upper phase and a lower phase. The upper phase has a concentration of HF that is smaller than the concentration of HF in the lower phase. Generally, the lower phase will have a concentration of HF that is greater than the concentration of HF in the upper phase. Specifically, the concentration of HF in the upper phase is less than 20 weight percent, preferably, less than 10 weight percent and, most preferably, less than 5 weight percent. The lower phase has an HF concentration as high as about 50 weight percent. The following examples are provided to further illustrate the invention and the benefits thereof. EXAMPLE I The example summarizes the results of an actual installation and operation of the invention at the Phillips Petroleum Company refinery located at Sweeny, Texas. The process had experienced high acid losses with its use of a separation column containing therein conventional sloping or inclined trays. The inclined trays were removed from the separation column and replaced with fixed valve fractionator trays. After a period of operation, the data clearly establishes the enormously improved performance of the separation column and the significant reduction in the loss of HF with the ASO bottoms product. The following Table I provides actual HF losses for each of six time periods immediately prior to the modification of the separation column and for each of seven time periods subsequent to the modification of the separation column. The data show that the average HF lost in the ASO bottoms product for the conventional process was 15,729 kg (34,676 pounds) per time period and was significantly higher than the average HF loss of 8,452 kg (18,633 pounds) per time period after the installation and operation of the novel process. These figures amounted to an average acid consumption in the associated alkylation process of 0.34 kg HF per m 3 (0.12 pounds HF per barrel) alkylate produced for the conventional process versus 0.17 kg HF per m 3 (0.06 pounds of HF per barrel) alkylate produced for the novel process. Time Period kg HF (LBS HF) Lost With ASO Product kg HF per m 3 (LBS HF Per Bbl) Alkylate Produced Old Process 1 19,241 (42,420) 0.42 (0.15) 2 22,906 (50,500) 0.45 (0.16) 3 11,911 (26,260) 0.25 (0.09) 4 13,744 (30,300) 0.34 (0.12) 5 11,911 (26,260) 0.23 (0.08) 6 14,660 ( 32,320 ) 0.28 ( 0.10 ) Average 15,729 (34,676) 0.34 (0.12) New Process 1 7,897 (17,409) 0.23 (0.08) 2 7,619 (16,796) 0.14 (0.05) 3 12,030 (26,521) 0.20 (0.07) 4 9,761 (21,520) 0.17 (0.06) 5 10,277 (22,658) 0.20 (0.07) 6 7,577 (16,705) 0.14 (0.05) 7 4,004 ( 8,827 ) 0.11 ( 0.04 ) Average 8,452 (18,633) 0.17 (0.06) Example II This example provides selected values from a calculated material balance used for designing a revamp of an acid rerun column of a Phillips Petroleum Company HF Alkylation Process Unit. The stream numbers correspond to those of FIG's. 1 and 2. As can be seen from the stream compositions, the HF concentration of stream 37 is 0.5 weight percent as compared with an HF concentration of 10 weight percent for stream 34. This demonstrates that the upper liquid phase in the bottom liquid level of the acid rerun column has a lower HF concentration than that of the bottom liquid phase. Also, the material balance shows that by recycling the bottom phase, HF loss with the ASO product is significantly reduced and minimized. Selected Stream Compositions Stream No. 28 34 36 44 37 Components: (kg/h (lb/hr)) Hydrogen Fluoride 13588.5 (29956.7) 519.1 (1144.3) 0 56.1 (123.7) 1.6 (3.5) Ethane 0.2 (0.5) 0.0 0 1.3 (2.5) 0.0 Propylene 0.0 0.0 0 0.0 0.0 Propane 81.8 (178.8) 0.0 0 1034.8 (2281.3) 0.0 Iso-Butane 877.9 (1935.3) 0.0 0 11519.4 (25395.2) 0.0 Butylenes 0.0 0.0 0 0.0 0.0 Amylenes 0.0 0.0 0 0.0 0.0 N-Butane 28.0 (61.7) 0.0 0 374.8 (826.3) 0.0 Pentanes Plus 52.1 (114.8) 0.0 0 193.7 (427.0) 0.0 Heavy Alkylate 1.1 (2.4) 0.0 0 0.0 0.0 Acid Soluble Oil 599.7 (1322.0) 4671.7 (10299.1) 0 0.0 299.8 (661.0) Water 299.8 (661.0) 0.0 0 0.0 0.0 Total 15528.4 (34233.1) 5190.8 (11443.4 0 13180.0 (29056.0) 301.4 (664.5) While this invention has been described in terms of the presently preferred embodiment, reasonable variations and modifications are possible by those skilled in the art. Such variations ad modifications are within the scope of the described invention and the appended claims.

Claims: A process for regenerating an HF catalyst, containing HF and acid soluble oil (ASO), used in an olefin and isoparaffin alkylation process, said process comprising the steps of: utilizing separation means for separating ASO from said HF catalyst, said separation means comprises a separator column (32) which defines a separation zone and having a top zone, an intermediate zone, and a bottom zone, wherein contained within said bottom zone are a series of vertically spaced, fractionation trays (50); introducing said HF catalyst (28) into said intermediate zone; introducing, as a reflux, liquid isoparaffin (38) into said top zone; introducing into said bottom zone and below said series of vertically spaced, fractionation trays (50) a vaporous isoparaffin stripping fluid (44); removing from said top zone an overhead stream (18) of purified HF, comprising HF; providing in said bottom zone and below said series of vertically spaced, fixed valve fractionation trays (50) at least two liquid phases, including an upper phase (66); having an HF concentration, and a lower phase (68); having an HF concentration greater than said HF concentration of said upper phase (66); removing said upper phase (66) from said bottom zone; and introducing said lower phase (68) into said intermediate zone, wherein said series of vertically spaced, fractionation trays (50) are of feed valve type wherein each of said fixed valve fractionation trays (50) include a plate (56) defining a plurality of apertures (60) and wherein fixedly spaced above each of said apertures (60) is a valve (70) having a shape substantially the same as said apertures (60) for directing the flow of gas passing upwardly through said apertures (60) of said plate (56) into the direction substantially parallel to said plate (56). The process of claim 1 wherein said HF concentration of said upper phase (66) is less than 10 weight percent. The process of claim 2 wherein said HF concentration of said upper phase (66) is less than 5 weight percent. The process of any of the preceding claims wherein said upper phase (66) comprises ASO and HF, and wherein said lower phase (68) comprises water and HF.

Inventors: CARLSON LEROY W, CARLSON, LEROY W.
Applicants: PHILLIPS PETROLEUM CO, PHILLIPS PETROLEUM COMPANY
Application year: 1995
Main classification: B01J27
IPC codes: C07C9, C07B61, B01D3, B01J27, C07C2, B01J38