Liquid crystal composition, liquid crystal device using the composition, liquid crystal apparatus and display method

Abstract: A liquid crystal composition includes at least one fluorine-containing mesomorphic compound (a) having a fluorocarbon terminal portion and a hydrocarbon terminal portion, and at least one optically active compound (b) having at least one substituted or unsubstituted terminal alkyl group containing an asymmetric carbon atom directly connected with F, CF₃ or CH₃. The liquid crystal composition shows a layer structure of so-called bookshelf or a layer structure having a small inclination angle (closer to bookshelf structure). The liquid crystal composition is useful in improving response characteristics and display characteristics, particularly a contrast ratio, of a liquid crystal device using the liquid crystal composition.

Description: The present invention relates to a liquid crystal composition, particularly a chiral smectic liquid crystal composition, and a liquid crystal device using the liquid crystal composition suitable for use in flat-panel displays, projection displays, etc. The present invention also relates to a liquid crystal apparatus using the device particularly as a display device, and a display method using the composition. There has been known a cathode ray tube (CRT) as a display device. The CRT has widely been used as a display terminal for outputting motion pictures of a television receiver or a video tape recording (VTR) apparatus or used as a monitor for a personal computer. However, the CRT encounters problems when outputs still images, in view of its characteristics, such that visibility or observability is liable to be lowered by, e.g., scanning fringe due to flicker or insufficient resolution and that degradation or deterioration of a fluorescent substance due to a surface memory is caused to occur in some cases. In recent years, it has been found that an electromagnetic wave generated by the CRT adversely affects the human body. As a result, the CRT can break the health of video display terminal (VDT) operators in some cases. In addition, the CRT has a structure including a large volume behind a picture area (display portion), whereby space-saving utilization of an office or a house in which the CRT is used is hindered. Liquid crystal devices have been used as a display device having solved the above-mentioned problems of the CRT. For instance, there have been known liquid crystal devices using use TN (twisted nematic) type liquid crystals, as shown in "Voltage-Dependent Optical Activity of a Twisted Nematic Liquid Crystal" by M. Schadt and W. Helfrich "Applied Physics Letters" Vol. 18, No. 4 (Feb. 15, 1971) pp. 127-128. One of the above-mentioned TN-type liquid crystal devices is a simple matrix-type liquid crystal device having the advantage of inexpensive production costs. When the liquid crystal device is driven by using an electrode matrix structure with an improved pixel density in accordance with a multiplex driving scheme, the liquid crystal device is liable to encounter a problem of occurrence of crosstalk, so that the number of pixels is restricted. Further, the uses of the device as a display device is also limited since the response speed is too slow, i.e., on the order of at least several ten milli-seconds. In recent years, there have been proposed liquid crystal devices using a thin film transistor (TFT). These liquid crystal devices can control a display state pixel by pixel since each pixel is provided with a transistor, whereby the devices solve problems of crosstalk and response speed. However, as these devices have a larger picture area, it is industrially more difficult to prepare a liquid crystal device with no defective pixels. Even if it is possible to prepare such a liquid crystal device, the device is more expensive. To overcome the above-mentioned drawbacks of such conventional liquid crystal devices, the use of liquid crystal devices using a liquid crystal material having bistability has been proposed by Clark and Lagerwall (e.g. Japanese Laid-Open Patent Appln. (JP-A) No. 56-107216; U.S. Patent No. 4,367,924, etc.). In this instance, as the liquid crystal material having bistability, a ferroelectric liquid crystal having chiral smectic C-phase (SmC*) or H-phase (SmH*) is generally used. The ferroelectric liquid crystal can effect inversion switching due to its spontaneous polarization, thus showing a very high response speed. Further, the ferroelectric liquid crystal shows bistable states (bistability) having a memory characteristic and is excellent in view angle characteristics, so that a liquid crystal device using a ferroelectric liquid crystal is considered suitable for a display device or light-valve having properties including high-speed responsiveness, high resolution and a large picture area. In recent years, there has been proposed an anti-ferroelectric chiral smectic liquid crystal device using three stable states, as described in "Japanese Journal of Applied Physics" vol. 27, p. L729 (1988) by Chanani and Takezoe et al. Such a liquid crystal device using a chiral smectic liquid crystal, however, encounters a problem such that a contrast ratio is lowered by occurrence of a zig-zag alignment defect in some cases, as described in "Structures and Properties of Ferroelectric Liquid Crystals" (1990) by Atsuo Fukuda and Hideo Takezoe issued by Corona Publishing Co. Ltd. (Tokyo Japan). The reason why the zigzag defect occurs may be attributable to the fact that a layer of a chiral smectic liquid crystal disposed between a pair of substrates constituting a cell structure includes two kinds of chevron layer structures. On the other hand there has been the recent trend in layer structure of a (chiral smectic) liquid crystal wherein a high contrast ratio is intended to be realized by suppressing a chevron layer structure resulting in a low contrast ratio and providing the liquid crystal with a bookshelf layer structure (hereinafter referred to as "bookshelf structure") in which boundaries of each liquid crystal molecular layer are disposed in parallel with each other (i.e., like a bookshelf) or with a structure closer to the bookshelf structure (e.g., Atsuo Fukuda (Editor)) "Advanced Liquid Crystal Displays and Liquid Crystal Materials (Zisedai Ekisho Display To Ekisho Zairyo)" (1992), issued by K.K. CMC (Tokyo Japan). One of methods for realizing a bookshelf structure is a method of using a naphthalene-based liquid crystal material having a particular structure. In this method, however, the resultant liquid crystal device has a tilt angle of about 10 degrees, which is considerably smaller than an ideal tilt angle of 22.5 degrees providing a maximum transmittance, thus resulting in a low transmittance or a low contrast. In addition, such a liquid crystal material fails to exhibit a bookshelf structure reversibly with respect to temperature in many cases. Another method for giving a bookshelf structure may include one inducing a bookshelf structure by externally applying an electric field to a liquid crystal device. Such a method, however, involves a problem of unstability against external stimuli such as temperature. In addition, various other problems are presumably present in order to put a liquid crystal material exhibiting a bookshelf structure into practical use since such a material has just discovered or proposed. Further, in quite recent years, there have been proposed a mesomorphic (liquid crystal) compound having a perfluoroether terminal portion (U.S. Patent No. 5,262,082 and International Publication No. WO93/22396) or having a perfluoroalkyl terminal portion (U.S. Patent No. 5,082,587) and a chiral smectic liquid crystal composition (Marc D. Radcliffe et al. The 4th International Ferroelectric Liquid Crystal Conference, P-46 (1993)) as materials exhibiting a bookshelf structure or a structure closer thereto. By using these liquid crystal materials, it is possible to provide a bookshelf structure or a structure showing a small layer inclination angle and being closer to the bookshelf structure without using external fields such as an external electric field. These liquid crystal materials also provide a larger tilt angle. However, these liquid crystal materials (compounds and compositions) are liable to exhibit poor solubility with other many mesomorphic (liquid crystal) compounds due to its particular denser molecular structure and provide an insufficient response speed attributable to a larger tilt angle in some cases. Accordingly, there have been desired to provide a chiral smectic (or ferroelectric) liquid crystal composition suitable for a liquid crystal device showing good switching (driving) characteristics by selecting such a chiral smectic liquid crystal composition as to comprise a mesomorphic (liquid crystal) compound exhibit a bookshelf structure of a liquid crystal layer or a structure having a layer inclination angle closer thereto and comprise a chiral dopant (chiral doping substance) having a sufficient solubility with the mesomorphic compound and inducing a large spontaneous polarization in combination. EP-A-0 625 513, a document according to Art. 54(3) EPC, discloses liquid crystal compositions comprising an optically inactive fluorine-containing mesomorphic compound and an optically active compound (chiral dopant). The optically active mesomorphic compound has a terminal perfluoroalkyl group. On the other hand, EP-A-0 360 521 discloses achiral fluorine-containing liquid crystal compounds having a fluorocarbon terminal portion and a hydrocarbon or another fluorocarbon terminal portion connected by a central core. A liquid crystal composition may comprise the above achiral fluorine-containing liquid crystal compound and at least one chiral component. The two latter teachings report on an improvement in response time and contrast in driving a liquid crystal device using the above compositions. Furthermore, JP-A-4-26679 discloses liquid crystal compositions comprising an achiral mesomorphic compound having a terminal alkyl group and a terminal fluoroalkyl group. The disclosed liquid crystal compositions may further comprise a chiral dopant. Improved response times are reported for these liquid crystal compositions. However, there is still a need for shorter response times and higher contrast of liquid crystal compositions. SUMMARY OF THE INVENTION An object of the present invention is to provide a liquid crystal composition, particularly a chiral smectic liquid crystal composition showing a good alignment state and stably exhibiting a bookshelf structure or a structure, having a small layer inclination angle, closer to the bookshelf structure with respect to a liquid crystal layer structure, thereby to realize a liquid crystal device having improved properties such as high responsiveness, high contrast, high definition and high brightness. Another object of the present invention is to provide a liquid crystal composition having an excellent mutual solubility between components thereof to stably exhibit the above required characteristics. Another object of the present invention is to provide a large-area liquid crystal device having the above-mentioned improved properties by using the above liquid crystal composition, a liquid crystal apparatus particularly a liquid crystal display apparatus showing excellent display characteristics by using the above liquid crystal device, and a display method using the above liquid crystal composition or the liquid crystal device. According to the present invention, there is provided a liquid crystal composition, comprising: at least one fluorine-containing mesomorphic compound (a) comprising a fluoroether terminal portion and a hydrocarbon terminal portion, the terminal portions being connected by a central core according to formula (I), the compound (a) having smectic phase or having latent smectic phase; and at least one optically active compound (b) represented by the following formula (II), as defined in claim 1. R 0 -A 0 -R 1 The present invention provides a liquid crystal device comprising a pair of opposite electrode plates and the liquid crystal composition described above disposed between the electrode plates. The present invention further provides a liquid crystal apparatus including the liquid crystal device, particularly including a display panel comprising the liquid crystal device. The present invention still further provides a display method using the liquid crystal composition described above and controlling the alignment direction of liquid crystal molecules in accordance with image data to effect display. These and other objects, features and advantages of the present invention will become more apparent upon a consideration of the following description of the preferred embodiments of the present invention taken in conjunction with the accompanying drawings. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic sectional view of a liquid crystal device using a liquid crystal composition according to the present invention. Figure 2 is a block diagram showing a display apparatus comprising a liquid crystal device utilizing a liquid crystal composition and a graphic controller according to the present invention. Figure 3 is a time chart of image data communication showing time correlation between signal transfer and driving with respect to a liquid crystal display apparatus and a graphic controller. Figure 4 is a view showing a switching signal used in driving conditions adopted in Examples appearing hereinafter. DETAILED DESCRIPTION OF THE INVENTION The liquid crystal composition according to the present invention is characterized by using the fluorine-containing mesomorphic compound (a) and the optically active (or chiral) compound (b) respectively described above in combination. The liquid crystal composition of the present invention has a good homogeneity (or uniformity) due to an excellent mutual solubility between the compound (a) and the compound (b). The liquid crystal composition may preferably be a chiral smectic liquid crystal composition and more preferably be a ferroelectric liquid crystal composition. When the liquid crystal composition of the present invention is used in a liquid crystal device, a liquid crystal layer can exhibit a bookshelf structure or a structure closer thereto having a small layer inclination angle (hereinbelow, sometimes inclusively referred to a "bookshelf structure"), particularly attributable to the compound (a), without using, e.g., an external electric field, thus realizing a good alignment state and high-speed responsiveness. The compound (a) used in the liquid crystal composition of the invention contains a terminal perfluoroether group. The compound (a) has a smectic phase (or mesophase) or a latent smectic phase (or mesophase). Herein, the compound (a) having a latent smectic phase means a compound not showing a smectic phase by itself but showing a smectic phase when used together with a compound having a smectic phase or another compound having a latent smectic phase. On the other hand, the compound (b) used in combination with the compound (a) described above is useful in providing a resultant liquid crystal composition with a chiral smectic phase, i.e., is used as a chiral doping substance or a chiral dopant. As a result, the resultant liquid crystal composition provides a high response speed and stably shows a bookshelf structure while ensuring a mutual solubility between the respective components. Hereinbelow, the fluorine-containing mesomorphic compound (a) will be explained more specifically. The term "mesomorphic compound" used herein covers not only a compound assuming a mesomorphic (liquid crystal) phase but also a compound not assuming a mesomorphic phase per se as long as a liquid crystal composition containing such a compound assumes a mesomorphic phase. The mesomorphic compound (a) has a fluorocarbon terminal portion (perfluoroether group) in view of ease of providing a bookshelf structure. The mesomorphic compound (a) is represented by the following formula (I): in which B 1 , D 1 and F 1 independently denote a, b and c independently denote an integer of 0 - 3 with the proviso that a+b+c is at least 2; M 1 and N 1 independently denote -COO-, -OCO-, -COS-, -SCO-, -COSe-, -SeCO-, -COTe-, -TeCO-, wherein d is an integer of 1 - 4, -CH=CH-, -CH=N-, -N=CH-, -CH 2 O-, -OCH 2 -, -CO-, -O- or a single bond; X, Y and Z independently denote -H, -Cl, -F, -Br, -I, -OH, -OCH 3 , -CN or -NO 2 and 1 , m and n independently denote an integer of 0 - 4; G 1 is -COO-C e H 2e -, -O-C e H 2e -, -C e H 2e -, -OSOO-, -OOSO-, -SOO-, -SOOC e H 2e -, -OC e H 2e -OC e' H 2e' -, -C e H 2e -N(C p H 2p+1 )-SO 2 - or -C e H 2e -N(C p H 2p+1 )-CO- wherein e and e' independently denote an integer of 1 - 20 and p is an integer of 0 - 4; A 1 is a linear or branched group represented by -O-C f H 2f -O-C g H 2g+1 , -C f H 2f -O-C g H 2g+1 , -C f H 2f -R', -O-C f H 2f -R', -COO-C f H 2f -R' or -OCO-C f H 2f -R' wherein R' is -Cl, -F, -CF 3 , -NO 2 , -CN, -H, -COO-C f' H 2f'+1 or -OCO-C f' H 2f'+1 in which and f, f' and g independently denote an integer of 1 - 20; and R is wherein x' is independently an integer of 1 - 10 for each C x' F 2x' O group, y is an integer of 1 - 10, and z is an integer of 1 - 6. The mesomorphic compound (a) ( having the formula (I)) may be synthesized through processes similar to those descried in U.S. Patent Nos. 5,082,587 and 5,262,082 and WO93/22936. Examples of the mesomorphic compound (a) of the formula (I) may include those shown below. Among the mesomorphic compounds of the formula (I) as described above, a fluorine-containing mesomorphic compound having a phenyl-pyrimidine skeleton and represented by the formula (I') shown below may particularly preferably be used since the compound of the formula (I') is effective in providing a resultant liquid crystal composition with a chiral smectic C phase in a wide temperature range including room temperature and with a low viscosity. Formula (I') in which n2 is an integer of 5 - 10; and R" is (C x" F 2x" O) z" C y' F 2y'+1 wherein x" is independently an integer of 1 - 3 for each C x" F 2x" O group, y' is an integer of 1 - 4, and z" is an integer of 1 - 3. By using the mesomorphic compound (a) having the formula (I) and preferably the formula (I')), it is possible to provide a liquid crystal composition containing such a compound (a) with a bookshelf structure or a structure having a small layer inclination angle closer to that of the bookshelf structure without using an external electric field. The liquid crystal composition shows a high response speed due to its low viscosity and provides a larger pretilt angle to a liquid crystal device, whereby it is possible to realize a chiral smectic liquid crystal device showing a high transmittance. The liquid crystal composition according to the present invention may preferably contain at least 30 wt. %, more preferably at least 50 wt. %, of at least one species of a fluorine-containing mesomorphic compound (a) preferably represented by the formula (I) or (I') in order to have the effects of addition thereof as described above, such as ease of providing a bookshelf structure, a large tilt angle and a low viscosity. In the present invention, as described above, the liquid crystal composition contains the compound (a) having a perfluoroether group as a fluorocarbon terminal portion so as to provide a liquid crystal layer structure having a very small layer inclination angle closer to a bookshelf structure by which a good display characteristic (e.g., high contrast) is attained. The composition of the present invention may preferably further comprise at least one fluorine-containing mesomorphic compound having a smectic phase or a latent smectic phase represented by the formula (I'') as defined in claim 19 corresponding to the formula (I) described above, except for the replacement of residue R by the residue R' which is -C x F 2x+1 wherein x is an integer of 1 to 20. In case where the compounds (a) having the above perfluoroether group are used, such compounds (a) may preferably be contained in the resultant liquid crystal composition in an amount of at least 30 wt. %, particularly at least 50 wt. %. Below 30 wt. %, a layer inclination angle of the resultant liquid crystal composition becomes too large, thus resulting in a poor display characteristic, such as a low contrast. On the other hand, even in the case of using the compound (a) in an amount of at least 30 wt. %, an alignment characteristic is lowered when compared with the case of using the compound (a) in an amount below 30 wt. % in some cases. In the present invention, however, such a disadvantage can be remedied by using a specific optically active compound (b) (as a chiral doping substance) as mentioned above in combination, whereby a bookshelf structure (or a closer structure thereto) can be provided stably to allow a uniform alignment state. Hereinbelow, the optically active compound (b) of the formula (II) used together with the mesomorphic compound (a) will be explained in detail. The optically active compound (b) may be a mesomorphic compound, and the compound (b) is used as a chiral dopant and has at least one asymmetric carbon atom directly connected with F, CF 3 or CH 3 as mentioned above. Such a chiral dopant (the compound (b)) having the particular asymmetric carbon atom has a good solubility with the above-mentioned mesomorphic compound (a), particularly those of the formulae (I) and (I'), having a terminal perfluoroether group and has a prescribed spontaneous polarization-imparting property. As a result, a resultant (chiral smectic) liquid crystal composition according to the present invention provides good driving characteristics including a high contrast ratio and an excellent switching characteristic based on the formation of a bookshelf structure of a structure closer thereto having a small layer inclination angle. In the formula (II) representing the compound (b), either one or both of R 0 and R 1 is represented by any one of the following formulae: (i) in which R 35 is a linear or branched alkyl group having 1 - 18 carbon atoms; R 33 is -CH 2 - or -CO-; R 34 is H or CH 3 ; X 33 is a single bond or -CH 2 - when R 33 is -CO-, or X 33 is a single bond, -CO- or -CH 2 - when R 33 is -CH 2 -; and C* is an asymmetric carbon atom; (ii) in which R 43 is a linear or branched alkyl group having 1 - 10 carbon atoms; X 43 is -O-, -COO-, -OCH 2 -, -OCH 2 CH 2 -, -OCOCH 2 -, -CH 2 O-, -COOCH 2 CH 2 -, -CH 2 OCH 2 CH 2 - or -CH 2 COOCH 2 -; and C* is an asymmetric carbon atom; and (iii) in which R 53 is a linear or branched alkyl group having 1 - 18 carbon atoms; L52 is 0 or 1; X 53 is a single bond, -CO- or -CH 2 - when L52 is 0, or X 53 is a single bond or -CH 2 - when L52 is 1; X 54 is -COO- or-O-; L53 is 0 or 1; and C* is an asymmetric carbon atom, and (iv) in the formula (II) representing the optically active compound (b), both of R 0 and R 1 may be an alkyl group having an asymmetric carbon atom directly connected with F, CF 3 or CH 3 . Such groups R 0 and R 1 is particularly effective in imparting a large spontaneous polarization to the resultant liquid crystal composition. The optically active compound (b) represented by the formula (II) used in the present invention may preferably include at least one species of an optically active compound represented by any one of the following formulae (III), (IV), (V) and (VI). Compound (b) of the formula (III) in which R 32 is a linear or branched alkyl group having 1 - 18 carbon atoms capable of including at least one -CH 2 - group which can be replaced by -Y 3 -, -Y 3 -CO-, -CO-Y 3 -, -CO-, -OCOO-, -CH=CH- or -C≡C- wherein Y 3 is O or S; R 35 is a linear or branched alkyl group having 1 - 18 carbon atoms; m 32 is 0, 1 or 2; R 33 is -CH 2 - or -CO-; R 34 is H or CH 3 ; A 32 , A 33 and A 34 independently denote a single bond, 1,4-phenylene; pyridine-2,5-diyl; pyrimidine-2,5-diyl; pyrazine-2,5-diyl; pyridazine-3,6-diyl; 1,4-cyclohexylene; 1,3-dioxane-2,5-diyl; 1,3-dithiane-2,5-diyl; thiophene-2,5-diyl; thiazole-2,5-diyl; thiadiazole-2,5-diyl; benzoxazole-2,5-diyl; benzoxazole-2,6-diyl; benzothiazole-2,5-diyl; benzothiazole-2,6-diyl; benzofuran-2,5-diyl; benzofuran-2,6-diyl; quinoxaline-2,6-diyl; quinoline-2,6-diyl; 2,6-naphthylene; indan-2,5-diyl; 2-alkylindan-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atom; indanone-2,6-diyl; 2-alkylindanone-2,6-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; coumaran-2,5-diyl; or 2-alkylcoumaran-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; X 32 is a single bond, -COO-, -OCO-, -CH 2 O- or -OCH 2 -; X 33 is a single bond or -CH 2 - when R 33 is -CO-, or X 33 is a single bond, -CO- or -CH 2 - when R 33 is -CH 2 -; C* is an asymmetric carbon atom; and A 32 , A 33 and A 34 each may have one or two substituents selected from F, Cl, Br, CH 3 , CF 3 and CN and cannot be a single bond at the same time. Examples of the compound (b) of the formula (III) may include those as described in JP-A Nos. 62-093248, 62-198633, 63-088161, 63-104949, 63-107951, 63-122651, 63-022042, 63-192732, 63-196553, 63-196571, 63-215661, 63-216878, 63-218647, 63-225337, 63-243059, 63-303951, 64-022990, 1-272571, 64-031740, 1-121244, 1-207280, 1-038077, 1-265052, 2-028158, 2-069427, 2-069467, 2-115145, 2-000227, 3-227980 and 4-300871. The compound (b) of the formula (III) may be produced through processes as described in these documents. Specific and preferred examples of the optically active compound (b) of the formula (III) may include those represented by the following structural formulae (Ex. Comp. Nos. 3-1 to 3-105 indicated as Nos. 1 - 105 in Table 1 below) including abbreviations used for the respective groups listed below (hereinbelow, the abbreviations in Tables 2 - 6 represent the same groups as those in Table 1). In Table 1, the structural formula (Ex. Comp. No. 3-64 indicated as No. 64) has m32 being 2. Ml: -CH 2 - My: -CH 3 The optically active compound (b) may particularly preferably be represented by the formula (III) wherein R 32 and R 35 independently denote a linear or branched alkyl group; m32 is 0; R 33 is -CH 2 - or -CO-; R 34 is H or CH 3 ; A 33 is A 34 is and X 33 is a single bond or -CH 2 - when R 33 is -CO-, or X 33 is a single bond, -CO- or -CH 2 - when R 33 is -CH 2 -. Such a compound (b) is effective in allowing a low viscosity and a wide temperature range showing a chiral smectic phase to the resultant liquid crystal composition due to its phenyl-pyrimidine skeleton. Compound (b) of the formula (IV) in which R 42 is a linear or branched alkyl group having 1 - 18 carbon atoms capable of including at least one -CH 2 - group which can be replaced by -Y 4 -, -Y 4 -CO-, -CO-Y 4 -, -CO-, -OCOO-, -CH=CH- or -C≡C- wherein Y 4 is O or S; R 43 is a linear or branched alkyl group having 1 - 10 carbon atoms; m42 is 0, 1 or 2; A 42 , A 43 and A 44 independently denote a single bond, 1,4-phenylene; pyridine-2,5-diyl; pyrimidine-2,5-diyl; pyrazine-2,5-diyl; pyridazine-3,6-diyl; 1,4-cyclohexylene; 1,3-dioxane-2,5-diyl; 1,3-dithiane-2,5-diyl; thiophene-2,5-diyl; thiazole-2,5-diyl; thiadiazole-2,5-diyl; benzoxazole-2,5-diyl; benzoxazole-2,6-diyl; benzothiazole-2,5-diyl; benzothiazole-2,6-diyl; benzofuran-2,5-diyl; benzofuran-2,6-diyl; quinoxaline-2,6-diyl; quinoline-2,6-diyl; 2,6-naphthylene; indan-2,5-diyl; 2-alkylindan-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atom; indanone-2,6-diyl; 2-alkylindanone-2,6-diyl having a linear or branched alkyl group having 1 -. 18 carbon atoms; coumaran-2,5-diyl; or 2-alkylcoumaran-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; X 42 is a single bond, -COO-, -OCO-, -CH 2 O- or -OCH 2 -; X 43 is -O-, -COO-, -OCH 2 -, -OCH 2 CH 2 -, -OCOCH 2 -, -CH 2 O-, -COOCH 2 CH 2 -, -CH 2 OCH 2 CH 2 - or -CH 2 COOCH 2 ; C* is an asymmetric carbon atom; and A 42 , A 43 and A 44 each may have one or two substituents selected from F, Cl, Br, CH 3 , CF 3 and CN and cannot be a single bond at the same time. Examples of the compound (b) of the formula (IV) may include those as descried in JP-A Nos. 1-160986, 1-242543, 2-000127, 2-069440, 2-295943, 3-043488, 3-058980 3-083971, 3-193774, 3-223232, 3-236353, 4-013797, 4-253789 and 4-264052. The compound (b) of the formula (IV) may be produced through processes as described in these documents. Specific and preferred examples of the optically active compound (b) of the formula (IV) may include those represented by the following structural formulae (Ex. Comp. Nos. 4-1 to 4-105 indicated as Nos. 1 - 105 in Table 2 below) including abbreviations used for the respective groups listed below in addition to those listed for Table 1. In Table 2, the structural formula (Ex. Comp. No. 4-60 indicated as No. 60) has m42 being 2. Om: -OCH 2 - Od: -OCH 2 CH 2 - Em: -OCOCH 2 - Mo: -CH 2 -O- Ced: -COOCH 2 CH 2 - Mod: -CH 2 OCH 2 CH 2 - Mce: -CH 2 COOCH 2 - Mcd: -CH 2 -O-CH 2 - The optically active compound (b) may particularly preferably be represented by the formula (IV) wherein R 42 is a linear or branched alkyl or alkoxy group having 1 - 18 carbon atoms; R 43 is a linear or branched alkyl group having 1 -10 carbon atoms; m42 is 0; A 42 is A 43 is and X 43 is -O-, -OCH 2 -, -COO-, -COOCH 2 CH 2 - or -OCH 2 CH 2 -. Such a compound (b) is effective in allowing a low viscosity and a wide temperature range showing a chiral smectic phase to the resultant liquid crystal composition due to its phenyl-pyrimidine skeleton. Compound (b) of the formula (V) in which R 52 is a linear or branched alkyl group having 1 - 18 carbon atoms capable of including at least one -CH 2 - group which can be replaced by -Y 5 -, -Y 5 -CO-, -CO-Y 5 -, -CO-, -OCOO-, -CH=CH- or -C≡C- wherein Y 5 is O or S; R 53 is a linear or branched alkyl or alkoxy group having 1 - 10 carbon atoms; m52 is 0, 1 or 2; A 52 , A 53 and A 54 each may have one or two substituents selected from F, Cl, Br, CH 3 , CF 3 and CN and independently denote a single bond but cannot be a single bond at the same time; 1,4-phenylene ; pyridine-2,5-diyl; pyrimidine-2,5-diyl; pyrazine-2,5-diyl; pyridazine-3,6-diyl; 1,4-cyclohexylene; 1,3-dioxane-2,5-diyl; 1,3-dithiane-2,5-diyl; thiophene-2,5-diyl; thiazole-2,5-diyl; thiadiazole-2,5-diyl; benzoxazole-2,5-diyl; benzoxazole-2,6-diyl; benzothiazole-2,5-diyl; benzothiazole-2,6-diyl; benzofuran-2,5-diyl; benzofuran-2,6-diyl; quinoxaline-2,6-diyl; quinoline-2,6-diyl; 2,6-naphthylene; indan-2,5-diyl; 2-alkylindan-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atom; indanone-2,6-diyl; 2-alkylindanone-2,6-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; coumaran-2,5-diyl; or 2-alkylcoumaran-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; X 52 is a single bond, -COO-, -OCO-, -CH 2 O- or -OCH 2 -; X 53 is a single bond, -CO- or -CH 2 - when L52 is 0, or X 53 is a single bond or -CH 2 - when L52 is 1; L52 and L53 are 0 or 1; and C* is an asymmetric carbon atom. Examples of the compound (b) of the formula (V) may include those as descried in JP-A Nos. 61-293288 and 63-44551. The compound (b) of the formula (V) may be produced through processes as described in these documents. Specific and preferred examples of the optically active compound (b) of the formula (V) may include those represented by the following structural formulae (Ex. Comp. Nos. 5-1 to 5-105 indicated as Nos. 1 - 105 in Table 3 below) including abbreviations used for the respective groups listed below in addition to those listed for Table 1. In Table 3, the structural formula (Ex. Comp. No. 5-59 indicated as No. 59) has m52 being 2. The above-mentioned optically active compound (b) of the formula (V) is excellent in mesomorphism, spontaneous polarization and a solubility with the fluorine-containing mesomorphic compound (a) due to its particular structure. Further, the compound (b) of the formula (V) has the advantage of effectively controlling a helical pitch or the direction of the helix affecting an alignment characteristic resulting from various structures of a chiral portion readily modified. The above advantages (e.g., a large spontaneous polarization and a control of helical pitch or the direction of helix) can also be realized by using two or more species of the compound (b) of the formula (V). The optically active compound (b) may particularly preferably be represented by the formula (V) wherein R 52 is a linear or branched alkyl or alkoxy group having 1 - 18 carbon atoms; R 53 is a linear or branched alkyl group having 1 - 10 carbon atoms; m52 and L52 are 0; A 52 is A 53 is and X 53 is a single bond or -CO-. Such a compound (b) is effective in allowing a low viscosity and a wide temperature range showing a chiral smectic phase to the resultant liquid crystal composition due to its phenyl-pyrimidine skeleton. Compound (b) of the formula (VI) R 62 -(A 62 -X 62 ) m62 -A 63 -A 64 -X 63 -R 63 in which R 62 and R 63 independently denote a linear or branched alkyl group having 1 - 18 carbon atoms and at least one asymmetric carbon atom directly connected with F, CF 3 or CH 3 and capable of including at least one -CH 2 - group which can be replaced by -Y 6 -, -Y 6 -CO-, -CO-Y 6 -, -CO-, -OCOO-, -CH=CH- or -C≡C- wherein Y 6 is O or S; m62 is 0, 1 or 2; A 62 , A 63 and A 64 each may have one or two substituents selected from F, Cl, Br, CH 3 , CF 3 and CN and independently denote a single bond but cannot be a single bond at the same time; 1,4-phenylene ; pyridine-2,5-diyl; pyrimidine-2,5-diyl; pyrazine-2,5-diyl; pyridazine-3,6-diyl; 1,4-cyclohexylene; 1,3-dioxane-2,5-diyl; 1,3-dithiane-2,5-diyl; thiophene-2,5-diyl; thiazole-2,5-diyl; thiadiazole-2,5-diyl; benzoxazole-2,5-diyl; benzoxazole-2,6-diyl; benzothiazole-2,5-diyl; benzothiazole-2,6-diyl; benzofuran-2,5-diyl; benzofuran-2,6-diyl; quinoxaline-2,6-diyl; quinoline-2,6-diyl; 2,6-naphthylene; indan-2,5-diyl; 2-alkylindan-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atom; indanone-2,6-diyl; 2-alkylindanone-2,6-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; coumaran-2,5-diyl; or 2-alkylcoumaran-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; and X 62 and X 63 independently denote a single bond, -COO-, -OCO-, -CH 2 O- or -OCH 2 -. Examples of the compound (b) of the formula (VI) may include those as descried in JP-A Nos. 6-234749. The compound (b) of the formula (VI) may be produced through a process as described in the documents. Specific and preferred examples of the optically active compound (b) of the formula (VI) may include those represented by the following structural formulae (Ex. Comp. Nos. 6-1 to 6-105 indicated as Nos. 1 - 105 in Table 4 below) including abbreviations used for the respective groups listed below in addition to those listed for Table 1. In Table 4, the structural formula (Ex. Comp. No. 6-67 indicated as No. 67) has m62 being 2. In the formula (VI), R 62 - corresponds to R 62' -ψ (any one of ψ 1 to ψ 7 )- and -R 63 corresponds to -Σ6 (any one of Σ61 to Σ65)-R 63' indicated in Table 4. R 63 in the formula (VI) may preferably be represented by the following formula: in which R 64 is a linear or branched alkyl group having 1 - 16 carbon atoms in view of improvements in spontaneous polarization, viscosity and mutual solubility due to a chiral fluorine portion (-C * H(F)-). Similarly, R 62 in the formula (VI) may preferably be represented by the following formula: in which R 65 is a linear or branched alkyl group having 1 - 16 carbon atoms, and d is an integer of 1-6 in view of improvements in properties as described in the case of R 63 . The optically active compound (b) may particularly preferably be represented by the formula (VI) wherein m62 is 0; A 63 is and A 64 is Such a compound (b) is effective in allowing a low viscosity, a mutual solubility of the respective components and a wide temperature range showing a chiral smectic phase to the resultant liquid crystal composition due to its phenyl-pyrimidine skeleton. The optically active compound (b) of the formula (VI) is used as a so-called double chiral-type chiral dopant having two chiral centers (which provide a spontaneous polarization) each located in an inner portion of a terminal group, i.e., located on the both sides of a central core portion. When the double chiral-type chiral dopant (the compound (b) of the formula (VI)) is used together with the compound (a) having a terminal perfluoroether group or a terminal perfluoroalkyl group effective in providing a bookshelf structure or a structure having a small layer inclination angle closer thereto, the resultant liquid crystal composition shows a good mutual solubility and a large spontaneous polarization to attain good driving characteristics. The (chiral smectic) liquid crystal composition according to the present invention may be obtained by mixing at least one species of the fluorine-containing mesomorphic compound (a) having the formula (I) or preferably having the formula (I') with at least one species of the optically active compound (b) of the formula (II) (preferably of any one of the formulae (III) to (VI)) in an appropriate proportions. The optically active compound (b) of any one of the formulae (II) to (VI) may generally be contained in the liquid crystal composition in an amount of trace to below 50 wt. %, preferably 2 - 40 wt. %. The optically active compound (b) may also be contained in the liquid crystal composition in a very small amount (e.g., 1x10 -5 wt. %) so long as it functions as a chiral dopant. If the addition amount of the optically active compound (b) is at least 50 wt. %, the resultant liquid crystal composition shows a high viscosity and a narrow chiral smectic temperature range in some cases. The (chiral smectic) liquid crystal composition of the invention may further contain at least one species of another mesomorphic compound and/or another chiral dopant each different from those described above and also contain additives such as an antioxidant, an ultraviolet ray-absorbing agent, a colorant and a pigment. Examples of another mesomorphic compound may include those as described in Demus et al., Flüssige Kristalle in Tabellen II (VEB Deutschev Verlag für Grundstoffindustrie, Liepzig, 1984). The liquid crystal device according to the present invention may preferably be a (chiral smectic) liquid crystal device using the above-mentioned chiral smectic liquid crystal composition. Hereinbelow, an embodiment of the liquid crystal device of the present invention will be explained with reference to Figure 1. Figure 1 is a schematic sectional view of an embodiment of the liquid crystal device for explanation of the structure thereof. Referring to Figure 1, the liquid crystal device includes a liquid crystal layer 1 comprising a chiral smectic liquid crystal composition disposed between a pair of substrates 2 each having thereon a transparent electrode 3 and an alignment control layer 4. In the present invention, the transparent electrode 3 and/or the alignment control layer may be formed on one of the substrates 2. The substrates 2 are placed or arranged opposite to each other. The periphery of the substrates 2 is sealed up with a sealing agent 5. Outside the thus treated substrates 2, a pair of polarizers 6 are disposed so as to modulate incident light I 0 from a light source 7 in cooperation with the liquid crystal 1 to provide modulated light I. The liquid crystal device can be driven by controlling (or switching) the alignment (or orientation) direction of liquid crystal molecules in accordance with image data based on a switching signal from a signal power supply.(not shown), thus effecting display. Accordingly, the liquid crystal device functions as a a display device. Further, in case where two transparent electrodes 3 are arranged in matrix on the pair of substrates, it is possible to perform pattern display and pattern exposure, so that the liquid crystal device is used as a display device for a personal computer, a word processor, etc., or as a light valve for a printer. The liquid crystal layer 1 may preferably have a thickness of at most 5 µm in order to exhibit bistability. The liquid crystal layer 1 may be constituted by a lot of smectic liquid crystal molecular layers forming a bookshelf structure or a closer structure thereto having a small layer inclination angle. Each of two substrates 2 comprises glass or plastic and is coated with a transparent electrode 3 comprising a film of SnO 2 , In 2 O 3 , SnO 2 or ITO (indium-tin-oxide) to form an electrode plate. Further thereon, the alignment control layer 4 is formed by applying a solution containing a material for the alignment control layer or by vapor deposition or sputtering of a material for the alignment control layer. Examples of the material for the alignment control layer 4 may include: an inorganic material, such as silicon monoxide, silicon dioxide, aluminum oxide, zirconium oxide, magnesium fluoride, cerium oxide, cerium fluoride, silicon nitride, silicon carbide, or boron nitride; and an organic material, such as polyvinyl alcohol, polyimide, polyamide-imide, polyester, polyamide, polyester-imide, polyparaxylylene, polycarbonate, polyvinyl acetal, polyvinyl chloride, polystyrene, cellulose resin, melamine resin, urea resin or acrylic resin. The surface of the thus prepared alignment control layer 4 may be subjected to uniaxial alignment treatment, as desired, e.g., by rubbing the surface thereof with a fibrous material such as velvet, cloth or paper. The uniaxial alignment treatment (rubbing treatment) may be performed to one of the alignment control films 4 so as to effectively control an alignment state of liquid crystal molecules. The alignment control layer 4 may be formed by an oblique vapor deposition method wherein a film of an oxide such as SiO 2 or an nitride is vapor-deposited on the electrode plate(s) from the oblique direction to the electrode plate. The liquid crystal device of the invention may further comprise a short circuit-preventing layer for the pair of substrates, such as an insulating layer, an inorganic material layer and an organic material layer other than those for the above-mentioned alignment control layer, if necessary. In view of ease of formation and a high alignment control ability, the alignment control layer 4 may preferably comprise a polyimide film or a polyamide film, e.g., formed by applying a polyimide precursor solution or a polyamic acid solution and curing the solution, followed by uniaxial alignment treatment, particularly rubbing treatment of the resultant film. Examples of a polyimide and a polyamide used for forming the alignment control layer 4 may preferably include those having a molecular structure with a high rigidity, a high linear property and a high crystallinity in order to uniformly align the chiral smectic liquid crystal composition. Such a polyimide and polyamide may preferably be represented by the following formula (VII) and formula (VIII), respectively. Formula (VII) in which R 71 is , R 72 and R 74 independently denote R 73 is a single bond or -O-; and 1 is 0, 1 or 2. Formula (VIII) (R 81 -R 82 -R 83 -R 84 -(R 85 ) r8 R 86 ) in which R 81 is an alkylene group having 1 - 20 carbon atoms, or R 82 and R 86 are independently -CONH- or -NHCO-: R 83 and R 85 are independently or an alkylene group having 1-20 carbon atoms: R 84 is a single bond or -O-; and r8 is 0, 1 or 2. Specific examples of the polyimide of the formula (VII) and the polyamide of the formula (VIII) may include those having the following recurring units shown below. In the present invention, one of the alignment control layers formed on one substrate may comprise a material therefor which is different from that for the other alignment control layer in order to improve an alignment characteristic in the case of providing a bookshelf structure. The liquid crystal device of the present invention may be arranged in various modes or forms as long as it uses a liquid crystal composition containing the fluorine-containing mesomorphic compound (a) and the optically active compound (b) as essential components'thereby to impart required functions. In the present invention, it is possible to effect a display with better performances, such as a high contrast ratio, a high brightness, a large display area and a high definition by using the liquid crystal composition or the liquid crystal device as mentioned above. According to an embodiment of the display method according to the present invention, it is possible to effect a binary display (black and white (or dark and bright)) each at one pixel by sandwiching a liquid crystal cell (i.e., the liquid crystal device before a pair of polarizer is disposed) between a pair of polarizer so as to provide one of bistable states showing the darkest state and then applying an electric field to find a position so as to provide the other of bistable states showing a bright state. It is also possible to effect a multiple display (or gradational display) by using a method wherein plural times of a binary (bright-dark) display are performed at a prescribed interval within a certain period of time or a method wherein a part of one pixel is subjected to switching. The liquid crystal device according to the present invention can be used as an active element, particularly an active display element, for various liquid crystal apparatus, one embodiment of which is described below. Based on an arrangement appearing hereinbelow and data format comprising image data accompanied with scanning line address data and by adopting communication synchronization using a SYNC signal as shown in Figures 2 and 3, there is provided a liquid crystal display apparatus of the present invention which uses the liquid crystal device according to the present invention as a display panel portion. Referring to Figure 2, a liquid crystal display apparatus 101 includes a graphic controller 102, a display panel 103, a scanning line drive circuit 104, a data line drive circuit 105, a decoder 106, a scanning signal generator 107, a shift resistor 108, a line memory 109, a data signal generator 110, a drive control circuit 111, a graphic central processing unit (GCPU) 112, a host central processing unit (host CPU) 113, and an image data storage memory (VRAM) 114. Image data are generated in the graphic controller 102 in an apparatus body and transferred to a display panel 103 by signal transfer means. The graphic controller 102 principally comprises a CPU (central processing unit, hereinafter referred to as "GCPU") 112 and a VRAM (video-RAM, image data storage memory) 114 and is in charge of management and communication of image data between a host CPU 113 and the liquid crystal display apparatus (FLCD) 101. The control of the display apparatus is principally performed by the graphic controller 102. A light source (not shown) is disposed at the back of the display panel 103. Hereinbelow, the present invention will be explained more specifically with reference to examples. It is however to be understood that the present invention is not restricted to these examples. Example 1 Three chiral smectic liquid crystal compositions (1), (2) and (3) were prepared by mixing the following compounds (having the indicated structural formulae and phase transition temperatures (°C))) in the proportions indicated below. A/B 1 /B 2 /B 3 /C 1 = 50/15/10/15/10 (wt. %) (C 1 : C 1 -1 for Composition (1), C 1 -2 for Composition (2) and C 1 -3 for Composition (3)) Compound (a) A: Phase transition (°C) B 1 : Phase transition (°C) B 2 : Phase transition (°C) B 3 : Phase transition (°C) Compound (b) C 1 (chiral dopant) C 1 - 1 : C 1 - 2 : C 1 - 3 : In the above phase transition series, Sx denotes a smectic phase (unidentified); Sc denotes a smectic C phase; S A denotes a smectic A phase; and Iso denotes an isotropic phase. Each of liquid crystal cells was prepared as follows. To one glass plate provided with an ITO film, a solution of a polyimide precursor (providing a polyimide having a recurring unit of the formula shown below) in a mixture solvent (n-methylpirrolidone (NMP)/n-butylcellosolve (nBC) = 2/1) was applied by spin coating. The thus coated glass plate was subjected to hot curing treatment and a rubbing treatment. To another glass plate provided with an ITO film, a solution of a silane coupling agent comprising octadecyltriethoxysilane was applied by spin coating, followed by hot curing. After silica beads as a spacer were dispersed on one of the above-treated two glass plates, the two glass plates were applied to each other to form a blank cell having a cell gap of 1.8 µm. Into the thus-prepared liquid crystal cells, the above-prepared liquid crystal compositions (1) to (3) heated into an isotropic liquid were injected, respectively, by a capillary method. Each of the liquid crystal cells was then gradually cooled to room temperature to prepare a liquid crystal device according to the present invention. Each of the thus-prepared liquid crystal devices using the liquid crystal compositions (1) to (3), respectively, was subjected to measurement of an apparent tilt angle a, a contrast ratio and a threshold value (for switching). The results are shown in Table 5 appearing hereinafter. (at 40 °C) Composition No. Chiral dopant a (degrees) Contrast Threshold value (µsec) (1) C 1 -1 21.4 35 62 (2) C 1 -2 18.9 32 60 (3) C 1 -3 19.9 31 49 Herein, the respective characteristics were evaluated or measured as follows. Apparent tilt angle a (A half of an angle between optical axes in two stable states (memory state)) An liquid crystal device sandwiched between right angle cross nicol polarizes was supplied with a single pulse of one polarity exceeding the threshold voltage of the liquid crystal and was then rotated under no electric field horizontally relative to the polarizers to find a first extinction position. Then, the liquid crystal device was supplied with a single pulse of the opposite polarity exceeding the threshold voltage of the ferroelectric liquid crystal and was then rotated under no electric field relative to the polarizers to find a second extinct position. An apparent tilt angle a was measured as a half of the angle between the first and second extinct positions. Contrast ratio The contrast ratio was measured by fixing a stage providing the darkest optical axis by means of a photomultiplier (available from Hamamatsu Photonics K.K.) under observation through a polarizing microscope and under application of a rectangular pulse having a switching signal waveform (voltage: ± 5 V, pulse width: 1.2 times that of a threshold pulse width) shown in Figure 4, thereby to find an output value for a dark (black) state and an output value for a bright (white) state. The contrast ratio was determined by dividing the output value for the white state by the output value for the black state. Threshold value The threshold value was determined by using a switching signal shown in Figure 4 and gradually changing a pulse width to find a minimum pulse width (µsec) for effecting switching. Layer inclination angle δ The layer inclination angle δ was measured according to a method described in Jpn. J. Appl. Phys. 27 , p. L725 (1988). Example 2 A liquid crystal composition (4) was prepared in the same manner as in Example 1 except that the respective components were mixed in the following proportions. Composition (4): A/B 1 /B 2 /B 3 /C 1 -1 = 80/3/3/4/10 (wt. %) The liquid crystal composition was evaluated in the same manner as in Example 1 except for further measuring a layer inclination angle δ. The results are shown below. a: 22.3 degrees, Threshold value: 48 µsec, Contrast: 52, and δ = 2 degrees. Reference Example 1 A liquid crystal composition (5) was prepared and evaluated in the same manner as in the case of the liquid crystal composition (1) used in Example 1 except that the chiral dopant C 1 -1 was changed to the following chiral dopant. The results are shown below. a: 17 degrees. Threshold value: A clear threshold value was not obtained although a pulse width was increased to 5 msec. Contrast: 8.3 at a pulse width of 100 µsec. Reference Example 2 A liquid crystal composition (6) was prepared in the same manner as in the case of the liquid crystal composition (1) used in Example 1 except that the chiral dopant C 1 -1 was changed to the following chiral dopant. However, the liquid crystal composition (6) caused precipitation of an insoluble component at room temperature, thus showing a poor mutual solubility. Example 3 Liquid crystal cells were prepared in the same manner as in Examples 1 and 2 except that the polyimide alignment film was changed to a polyimide film having a recurring unit (P1) below or a recurring unit (P2) below and the liquid crystal compositions (1) - (4) used in Examples 1 and 2 were used. All of the resultant liquid crystal cells (devices) using the polyimide film having the recurring unit (P1) or (P2) showed a very good alignment state over the entire cell similarly as in the case of polyimide films used in Examples 1 and 2. Example 4 Two liquid crystal compositions (7) and (8) were prepared by mixing the following compounds (A, B 1 , B 2 and B 3 are identical to those used in Example 1) in the indicated proportions, respectively. (composition) (components) (mixing ratio by wt. %) (7) A/B 1 /B 2 /B 3 /C 2 80/3/3/4/10 (8) A/B 1 /B 2 /B 3 /C 2 50/15/10/15/10 C 2 (chiral dopant) Two liquid crystal devices were prepared and evaluated in respects of the layer inclination angle δ and the contrast ratio in the same manner as in Example 1 by using the liquid crystal compositions (7) and (8), respectively. The results are shown below. Composition Contrast δ (deg.) (7) 54 3 (8) 39 - Example 5 Two liquid crystal compositions (9) and (10) were prepared in the same manner as in the case of the liquid crystal composition (7) used in Example 4 except that the chiral dopant C 2 was changed to optically active compounds (as a chiral dopant) (Ex. Comp. Nos. 2-7 and 2-37), respectively. The liquid crystal compositions (9) and (10) were subjected to measurement of a contrast ratio in the same manner as in Example 4. As a result, the liquid crystal composition (9) provided a contrast ratio of 47 and the liquid crystal composition (10) provided a contrast ratio of 41. Example 6 Liquid crystal cells were prepared in the same manner as in Examples 4 and 5 except that the polyimide alignment film was changed to a polyimide film having a recurring unit (P1) below or a recurring unit (P2) below and the liquid crystal compositions (7) - (10) used in Examples 4 and 5 were used. All of the resultant liquid crystal cells (devices) using the polyimide film having the recurring unit (P1) or (P2) showed a very good alignment state over the entire cell similarly as in the case of polyimide films used in Examples 4 and 5. Reference Example 3 A liquid crystal composition (11) was prepared and evaluated in respect of the contrast ratio in the same manner as in the case of the liquid crystal composition (7) used in Example 4 except that the chiral dopant C 2 was changed to the following chiral dopant. The liquid crystal composition (11) provided a poor contrast ratio of 6.2. Reference Example 4 A liquid crystal composition (12) was prepared in the same manner as in the case of the liquid crystal composition (7) used in Example 4 except that the chiral dopant C 2 was changed to the following chiral dopant. However, the liquid crystal composition (12) caused precipitation of an insoluble component at room temperature, thus showing a poor mutual solubility. Example 7 Two liquid crystal compositions (13) and (14) were prepared by mixing the following compounds (A, B 1 , B 2 and B 3 are identical to those used in Example 1) in the indicated proportions, respectively. (composition) (components) (mixing ratio by wt. %) (13) A/B 1 /B 2 /B 3 /C 3 80/3/3/4/10 (14) A/B 1 /B 2 /B 3 /C 3 50/15/10/15/10 C 3 (chiral dopant) Two liquid crystal devices were prepared and evaluated in respects of the layer inclination angle δ and the contrast ratio in the same manner as in Example 1 by using the liquid crystal compositions (13) and (14), respectively. The results are shown below. Composition Contrast δ (deg.) (13) 65 3 (14) 45 - Example 8 Two liquid crystal compositions (15) and (16) were prepared in the same manner as in the case of the liquid crystal composition (13) used in Example 7 except that the chiral dopant C 3 was changed to optically active compounds (as a chiral dopant) (Ex. Comp. Nos. 3-9 and 3-12), respectively. The liquid crystal compositions (15) and (16) were subjected to measurement of a contrast ratio in the same manner as in Example 7. As a result, the liquid crystal composition (15) provided a contrast ratio of 39 and the liquid crystal composition (16) provided a contrast ratio of 43. Example 9 Liquid crystal cells were prepared in the same manner as in Examples 7 and 8 except that the polyimide alignment film was changed to a polyimide film having a recurring unit (P1) below or a recurring unit (P2) below and the liquid crystal compositions (13) - (16) used in Examples 7 and 8 were used. All of the resultant liquid crystal cells (devices) using the polyimide film having the recurring unit (P1) or (P2) showed a very good alignment state over the entire cell similarly as in the case of polyimide films used in Examples 7 and 8. Reference Example 5 A liquid crystal composition (17) was prepared and evaluated in respect of the contrast ratio in the same manner as in the case of the liquid crystal composition (14) used in Example 7 except that the chiral dopant C 3 was changed to the following chiral dopant. The liquid crystal composition (17) provided a poor contrast ratio of 6.2. Example 10 Two liquid crystal compositions (18), (19) and (20) were prepared by mixing the following compounds (A, B 1 , B 2 and B 3 are identical to those used in Example 1) in the indicated proportions, respectively. A/B 1 /B 2 /B 3 /C 4 50/15/10/15/10 (wt. %) C 4 (chiral dopant) 6-15 (for Comp. (18)): 6-19 (for Comp. (19)): 6-36 (for Comp. (20)): Two liquid crystal devices were prepared and evaluated in the same manner as in Example 1 by using the liquid crystal compositions (18), (19) and (20), respectively. The results are shown in Table 6 below. (at 40 °C) Composition No. Chiral dopant a (degrees) Contrast Threshold value (µsec) (18) 6-15 24.4 43 14 (19) 6-19 19.0 47 97 (20) 6-36 17.2 41 8 Example 11 A liquid crystal composition (21) was prepared in the same manner as in the case of the liquid crystal composition (18) used in Example 10 except that the respective components were mixed in the following proportions. Composition (21): A/B 1 /B 2 /B 3 /C 4 (Ex.Comp. No. 6-15) = 80/3/3/4/10 (wt. %) The liquid crystal composition was evaluated in the same manner as in Example 1 except for further measuring a layer inclination angle δ. The results are shown below. a: 21.6 degrees, Threshold value: 10 µsec, Contrast: 58, and δ = 3 degrees. Example 12 Liquid crystal cells were prepared in the same manner as in Examples 10 and 11 except that the polyimide alignment film was changed to a polyimide film having a recurring unit (P1) below or a recurring unit (P2) below and the liquid crystal compositions (18) - (21) used in Examples 10 and 11 were used. All of the resultant liquid crystal cells (devices) using the polyimide film having the recurring unit (P1) or (P2) showed a very good alignment state over the entire cell similarly as in the case of polyimide films used in Examples 10 and 11. Reference Example 6 Liquid crystal compositions were prepared by mixing the following compounds in the indicated proportions. A/B 1 /B 2 /B 3 /Chiral = 25/23/20/22/10 (wt. %) In the above, A, B 1 , B 2 and B 3 are identical to those used in Example 1 and "Chiral" is each of the respective chirl dopants used in Examples 1 - 12. When the thus-prepared liquid crystal compositions were subjected to measurement of a contrast ratio in the same manner as in Example 1, all of the liquid crystal compositions provided a contrast ratio below 10. As described above, according to the invention, there is provided a liquid crystal composition, particularly a chiral smectic liquid crystal composition, showing a high mutual solubility of components thereof, providing a liquid crystal molecular layer having a bookshelf structure or a structure closer thereto having a small layer inclination angle, and exhibiting a good alignment state of the liquid crystal layer. As a result, a (chiral smectic or ferroelectric) liquid crystal device using the liquid crystal composition according to the present invention provides various improved properties such as a high responsiveness, a high contrast ratio, a high definition, a high brightness and a large picture area. In addition, when the liquid crystal device is used as a display device in combination with a light source, drive circuit, etc., a liquid crystal apparatus, such as a liquid crystal display apparatus, providing good display characteristics can be realized. A liquid crystal composition includes at least one fluorine-containing mesomorphic compound (a) according to formula (I) having a fluoroether terminal portion and a hydrocarbon terminal portion, and at least one optically active compound (b) according to formula (II) having at least one substituted or unsubstituted terminal alkyl group containing an asymmetric carbon atom directly connected with F, CF 3 or CH 3 . The liquid crystal composition shows a layer structure of so-called bookshelf or a layer structure having a small inclination angle (closer to bookshelf structure). The liquid crystal composition is useful in improving response characteristics and display characteristics, particularly a contrast ratio, of a liquid crystal device using the liquid crystal composition.

Claims: A liquid crystal composition, comprising: at least one fluorine-containing mesomorphic compound (a) having a smectic phase or having a latent smectic phase being represented by the following formula (I): in which B 1 , D 1 and F 1 independently denote a, b and c independently denote an integer of 0 - 3 with the proviso that a + b + c is at least 2; M 1 and N 1 independently denote -COO-, -OCO-, -COS-, -SCO-, -COSe-, -SeCO-, -COTe-, -TeCO-, -(CH 2 CH 2 ) d - wherein d is an integer of 1 - 4, -CH=CH-, -CH=N-, -N=CH-, -CH 2 O, -OCH 2 -, -CO-, -O- or a single bond; X, Y and Z independently denote -H, -Cl, -F, -Br, -I, -OH, -OCH 3 , -CN or -NO 2 ; and 1 , m and n independently denote an integer of 0 - 4; G 1 is -COO-C e H 2e -, -O-C e H 2e -, -C e H 2e -, -OSOO-, -OOSO-, -SOO-, -SOOC e H 2e -, -OC e H 2e -OC e' H 2e' -, -C e H 2e -N (C p H 2p+1 ) -SO 2 - Or -C e H 2e -N(C p H 2p+1 ) -CO- wherein e and e' independently denote an integer of 1 - 20 and p is an integer of 0 - 4; A 1 is a linear or branched group represented by -O-C f H 2f -O-C g H 2g+1 , -C f H 2f -O-C g H 2g+1 , -C f H 2f -R', -O-C f H 2f -R', -COO-C f H 2f -R' or-OCO-C f H 2f -R' wherein R' is -Cl, -F, -CF 3 , -NO 2 , -CN, -H, -COO-C f' H 2f'+1 or -OCO-C f' H 2f'+1 in which f, f' and g independently denote an integer of 1 - 20; and R is (C x' F 2x' O) z' C y F 2y+1 wherein x' is independently an integer of 1 - 10 for each C x' F 2x' O group, y is an integer of 1 - 10, and z' is an integer of 1 - 6 and at least one optically active compound (b) represented by the following formula (II): R 0 -A 0 -R 1 wherein A 0 is a mesogen group comprising one to four divalent groups each connected by a single bond, -COO-, -OCO-, -CH 2 O- or -OCH 2 - and each capable of having one or two substituents selected from the group consisting of F, Cl, Br, CH 3 , CF 3 and CN, the divalent group being selected from the group consisting of 1,4-phenylene; pyridine-2,5-diyl; pyrimidine-2,5-diyl; pyrazine-2,5-diyl; pyridazine-3,6-diyl; 1,4-cyclohexylene; 1,3-dioxane-2,5-diyl; 1,3-dithiane-2,5-diyl; thiophene-2,5-diyl; thiazole-2,5-diyl; thiadiazole-2,5-diyl; benzoxazole-2,5-diyl; benzoxazole-2,6-diyl; benzothiazole-2,5-diyl; benzothiazole-2,6-diyl; benzofuran-2,5-diyl; benzofuran-2,6-diyl; quinoxaline-2,6-diyl; quinoline-2,6-diyl; 2,6-naphthylene; indan-2,5-diyl; 2-alkylindan-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; indanone-2,6-diyl; 2-alkylindanone-2,6-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; coumaran-2,5-diyl; and 2-alkylcoumaran-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; and R 0 and R 1 independently denote a linear or branched alkyl group having 1 - 18 carbon atoms; each of the alkyl groups R 0 and R 1 being capable of including at least one -CH 2 - group which can be replaced by -Y-, -Y-CO-, -CO-Y-, -CO-, -OCOO-, -CH=CH- or -C≡C- in which Y is O or S; and at least one of R 0 and R 1 having at least one asymmetric carbon atom directly connected with F, CF 3 or CH 3 , R 0 and R 1 satisfying any one of the following conditions (i) to (iv): (i) any one of R 0 and R 1 is represented by the following formula: in which R 35 is a linear or branched alkyl group having 1 - 18 atoms; R 33 is -CH 2 - or -CO-; R 34 is H or CH 3 ; X 33 is a single bond or -CH 2 - when R 33 is -CO-, or X 33 is a single bond, -CO- or -CH 2 - when R 33 is -CH 2 -; and C * is an asymmetric carbon atom; (ii) any one of R 0 and R 1 is represented by the following formula: in which R 43 is a linear or branched alkyl group having 1 - 10 carbon atoms; X 43 is -O-, -COO-, -OCH 2 -, -OCH 2 CH 2 -, -OCOCH 2 -,-CH 2 O-, -COOCH 2 CH 2 -, -CH 2 OCH 2 CH 2 - or -CH 2 COOCH 2 -; and C * is an asymmetric carbon atom; (iii) any one of R 0 and R 1 is represented by the following formula: in which R 53 is a linear or branched alkyl group having 1 - 18 carbon atoms; L52 is 0 or 1; X 53 is a single bond, -CO- or -CH 2 - when L52 is 0, or X 53 is a single bond or -CH 2 - when L52 is 1; X 54 is -COO- or -0-; L53 is 0 or 1; and C * is an asymmetric carbon atom; and (iv) both of R 0 and R 1 are an alkyl group having an asymmetric carbon atom directly connected with F, CF 3 or CH 3 . A composition according to claim 1, wherein the compound (a) of the formula (I) is a fluorine-containing mesomorphic compound represented by the following formula (I'): in which n2 is an integer of 5 - 10; and R'' is (C x'' F 2x'' O) z'' C y' F 2y'+1 wherein x'' is independently an integer of 1 - 3 for each C x'' F 2x'' O group, y' is an integer of 1 - 4, and z" is an integer of 1 - 3. A composition according to claim 1, which comprises at least 30 wt. % of a fluorine-containing mesomorphic compound (a) . A composition according to claim 1, which comprises at least 50 wt. % of a fluorine-containing mesomorphic compound (a) . A composition according to claim 1, wherein the compound (b) of the formula (II) is an optically active compound represented by the following formula (III): in which R 32 is a linear or branched alkyl group having 1 - 18 carbon atoms capable of including at least one -CH 2 - group which can be replaced by -Y 3 -, Y 3 -CO-, -CO-Y 3 -, -CO-, -OCOO-, -CH=CH-, or -C≡C- wherein Y 3 is O or S; R35 is a linear or branched alkyl group having 1 - 18 carbon atoms; m32 is 0, 1 or 2; R 33 is -CH 2 - or -CO-; R 34 is H or CH 3 ; A 32 , A 33 and A 34 independently denote a single bond, 1,4-phenylene; pyridine-2,5-diyl; pyrimidine-2,5-diyl; pyrazine-2,5-diyl; pyridazine-3,6-diyl; 1,4-cyclohexylene; 1, 3-dioxane-2,5-diyl; 1,3-dithiane-2,5-diyl; thiophene-2,5-diyl; thiazole-2,5-diyl; thiadiazole-2,5-diyl; benzoxazole-2,5-diyl; benzoxazole-2,6-diyl; benzothiazole-2,5-diyl; benzothiazole-2,6-diyl; benzofuran-2,5-diyl; benzofuran-2,6-diyl; quinoxaline-2,6-diyl; quinoline-2,6-diyl; 2, 6-naphthylene; indan-2,5-diyl; 2-alkylindan-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atom; indanone-2,6-diyl; 2-alkylindanone-2,6-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; coumaran-2,5-diyl; or 2-alkylcoumaran-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; X 32 is a single bond, -COO-, -OCO-, -CH 2 O- or -OCH 2 -; X 33 is a single bond or -CH 2 - when R 33 is -CO-, or X 33 is a single bond, -CO- or -CH 2 - when R 33 is -CH 2 -; C * is an asymmetric carbon atom; and A 32 , A 33 and A 34 each can have one or two substituents selected from the group consisting of F, Cl, Br, CH 3 , CF 3 and CN and cannot be a single bond at the same time. A composition according to claim 5, wherein R 32 and R 35 independently denote a linear or branched alkyl group; m32 is 0; R 33 is -CH 2 - or -CO-; R 34 is H or CH 3 ; A 33 is A 34 is and X 33 is a single bond or -CH 2 - when R 33 is -CO-, or X 33 is a single bond, -CO- or -CH 2 - when R 33 is -CH 2 -. A composition according to claim 5, which comprises below 50 wt. % of an optically active compound of the formula (III). A composition according to claim 1, wherein the compound (b) of the formula (II) is an optically active compound represented by the following formula (IV): in which R 42 is a linear or branched alkyl group having 1 - 18 carbon atoms capable of including at least one -CH 2 - group which can be replaced by -Y 4 -, -Y 4 -CO-, -CO-Y 4 -, -CO-, -OCOO-, -CH=CH- or -C=C- wherein Y 4 is 0 or S; R 43 is a linear or branched alkyl group having 1 - 10 carbon atoms; m42 is 0, 1 or 2; A 42 , A 43 and A 44 independently denote a single bond, 1, 4-phenylene; pyridine-2,5-diyl; pyrimidine-2,5-diyl; pyrazine-2,5-diyl; pyridazine-3,6-diyl; 1,4-cyclohexylene; 1,3-dioxane-2,5-diyl; 1,3-dithiane-2,5-diyl; thiophene-2,5-diyl; thiazole-2,5-diyl; thiadiazole-2,5-diyl; benzoxazole-2,5-diyl; benzoxazole-2,6-diyl; benzothiazole-2,5-diyl; benzothiazole-2,6-diyl; benzofuran-2,5-diyl; benzofuran-2,6-diyl; quinoxaline-2,6-diyl; quinoline-2,6-diyl; 2,6-naphthylene, indan-2,5-diyl; 2-alkylindan-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; indanone-2,6-diyl; 2-alkylindanone-2,6-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; coumaran-2,5-diyl; or 2-alkylcoumaran-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; X 42 is a single bond, -COO-, -OCO-, -CH 2 O- or -OCH 2 -; X 43 is -O-, -COO-, -OCH 2 -, -OCH 2 CH 2 -, -OCOCH 2 -, -CH 2 O-, -COOCH 2 CH 2 -, -CH 2 OCH 2 CH 2 - or -CH 2 COOCH 2 ; C * is an asymmetric carbon atom; and A 42 , A 43 and A 44 each can have one or two substituents selected from the group consisting of F, Cl, Br, CH 3 , CF 3 and CN and cannot be a single bond at the same time. A composition according to claim 8, wherein R 42 is a linear or branched alkyl or alkoxy group having 1 - 18 carbon atoms; R 43 is a linear or branched alkyl group having 1-10 carbon atoms; m42 is 0; R 42 is A 43 is ; and X 43 is -O-, -OCH 2 -, -COO-, -COOCH 2 CH 2 - or -OCH 2 CH 2 -. A composition according to claim 8, which comprises below 50 wt. % of an optically active compound of the formula (IV). A composition according to claim 1, wherein the compound (b) of the formula (II) is an optically active compound represented by the following formula (V): in which R 52 is a linear or branched alkyl group having 1 - 18 carbon atoms capable of including at least one -CH 2 - group which can be replaced by -Y 5 -, -Y 5 -CO-, -CO-Y 5 -, -CO-, -OCOO-, -CH=CH- or -C≡C- wherein Y 5 is 0 or S; R 53 is a linear or branched alkyl or alkoxy group having 1 - 10 carbon atoms; m52 is 0, 1 or 2; A 52 , A 53 and A 54 independently denote a single bond, 1,4-phenylene; pyridine-2,5-diyl; pyrimidine-2,5-diyl; pyrazine-2,5-diyl; pyridazine-3,6-diyl; 1,4-cyclohexylene; 1,3-dioxane-2,5-diyl; 1,3-dithiane-2,5-diyl; thiophene-2,5-diyl; thiazole- 2,5-diyl; thiadiazole-2,5-diyl; benzoxazole-2,5-diyl; benzoxazole-2,6-diyl; benzothiazole-2,5-diyl; benzothiazole-2,6-diyl; benzofuran-2,5-diyl; benzofuran-2,6-diyl; quinoxaline-2,6-diyl; quinoline-2,6-diyl; 2, 6-naphthylene; indan-2,5-diyl; 2-alkylindan-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atom; indanone-2,6-diyl; 2-alkylindanone-2,6-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; coumaran-2,5-diyl; or 2-alkylcoumaran-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; X 52 is a single bond, -COO-, -OCO-, -CH 2 O- or -OCH 2 -; X 53 is a single bond, -CO- or -CH 2 - when L52 is 0 or X 53 is a single bond or -CH 2 - when L52 is 1; L52 and L53 are 0 or 1; C * is an asymmetric carbon atom; and A 52 , A 53 and A 54 each can have one or two substituents selected from the group consisting of F, Cl, Br, CH 3 , CF 3 and CN and cannot be a single bond at the same time. A composition according to claim 11, wherein R 52 is a linear or branched alkyl or alkoxy group having 1 - 18 carbon atoms; R 53 is a linear or branched alkyl group having 1 - 10 carbon atoms; m52 and L52 are 0; A 52 is A 53 is and X 53 is a single bond or -CO-. A composition according to claim 11, which comprises below 50 wt. % of an optically active compound of the formula (V). A composition according to claim 1, wherein the compound (b) of the formula (II) is an optically active compound represented by the following formula (VI): R 62 -(A 62 -X 62 ) m62 -A 63 -A 64 -X 63 -R 63 in which R 62 and R 63 independently denote a linear or branched alkyl group having 1 - 18 carbon atoms and at least one asymmetric carbon atom directly connected with F, CF 3 or CH 3 and capable of including at least one -CH 2 - group which can be replaced by -Y 6 -, -Y 6 -CO-, -CO-Y 6 -, -CO-, -OCOO-, -CH=CH- or -C≡C- wherein Y 6 is O or S; m62 is 0, 1 or 2; A 62 , A 63 and A 64 independently denote a single bond, 1, 4-phenylene; pyridine-2,5-diyl; pyrimidine-2,5-diyl; pyrazine-2,5-diyl; pyridazine-3,6-diyl; 1, 4-cyclohexylene; 1,3-dioxane-2,5-diyl; 1,3-dithiane-2,5-diyl; thiophene-2,5-diyl; thiazole-2,5-diyl; thiadiazole-2,5-diyl; benzoxazole-2,5-diyl; benzoxazole-2,6-diyl; benzothiazole-2,5-diyl; benzothiazole-2,6-diyl; benzofuran-2,5-diyl; benzofuran-2,6-diyl; quinoxaline-2,6-diyl; quinoline-2,6-diyl; 2,6-naphthylene; indan-2,5-diyl; 2-alkylindan-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; indanone-2,6-diyl; 2-alkylindanone-2,6-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; coumaran-2,5-diyl; or 2-alkylcoumaran-2,5-diyl having a linear or branched alkyl group having 1 - 18 carbon atoms; and X 62 and X 63 independently denote a single bond, -COO-, -OCO-, -CH 2 O- or -OCH 2 -; and A 62 , A 63 and A 64 each can have one or two substituents selected from the group consisting of F, Cl, Br, CH 3 , CF 3 and CN and cannot be a single bond at the same time. A composition according to claim 14, wherein R 63 in the formula (VI) is represented by the following formula: in which R 64 is a linear or branched alkyl group having 1 - 16 carbon atoms. A composition according to claim 14, wherein R 62 in the formula (VI) is represented by the following formula: in which R 65 is a linear or branched alkyl group having 1 - 16 carbon atoms, and d is an integer of 1 - 6. A composition according to claim 14, wherein m62 is 0; A 63 is and A 64 is A composition according to claim 14, which comprises below 50 wt. % of an optically active compound of the formula (VI). A composition according to claim 1, further comprising at least one fluorine-containing mesomorphic compound having smectic phase or having latent smectic phase and represented by the following formula (I'') : in which B 1 , D 1 and F 1 independently denote a, b and c independently denote an integer of 0 - 3 with the proviso that a + b + c is at least 2; M 1 and N 1 independently denote -COO-, -OCO-, -COS-, -SCO-, -COSe-, -SeCO-, -COTe-, -TeCO-, -(CH 2 CH 2 ) d - wherein d is an integer of 1 - 4, -CH=CH-, -CH=N-, -N=CH-, -CH 2 O-, -OCH 2 -, -CO-, -O- or a single bond; X, Y and Z independently denote -H, -Cl, -F, -Br, -I, -OH, -OCH 3 , -CN or -NO 2 ; and 1 , m and n independently denote an integer of 0 - 4; G 1 is -COO-C e H 2e -, -O-C e H 2e -, -C e H 2e -, -OSOO-, -OOSO-, -SOO-, -SOOC e H 2e -, -OC e H 2e -, -OC e' H 2e' -, -C e H 2e -N (C p H 2p+1 ) -SO 2 - or -C e H 2e -N(C p H 2p+1 )-CO- wherein e and e' independently denote an integer of 1 - 20 and p is an integer of 0 - 4; A 1 is a linear or branched group represented by -O-C f H 2f -O-C g H 2g+1 , -C f H 2f -O-C g H 2g+1 , -C f H 2f -R', -O-C f H 2f -R', -COO-C f H 2f -R' or-OCO-C f H 2f -R' wherein R' is -Cl, -F, -CF 3 , -NO 2 , -CN, -H, -COO-C f' H 2f'+1 or -OCO-C f' H 2f'+1 in which f, f' and g independently denote an integer of 1 - 20; and R' is -C x F 2x+1 wherein x is an integer of 1 - 20. A liquid crystal device, comprising a liquid crystal composition according to any one of claims 1 - 19. A device according to claim 20, comprising a pair of opposite electrode plates and the liquid crystal composition being disposed between the electrode plates. A device according to claim 21; which further comprises an alignment control layer formed on at least one of the electrode plates. A device according to claim 22, wherein the alignment control layer comprises a polyimide having a recurring unit represented by the following formula (VII): in which R 71 is R 72 and R 74 independently denote or R 73 is a single bond of -0-; and 1 is 0, 1 or 2. A display method, comprising: providing a liquid crystal composition according to any of claims 1 to 19; and controlling the alignment direction of liquid crystal molecules in accordance with image data to effect display. A liquid crystal apparatus comprising a liquid crystal device according to claim 20.

Inventors: KITAYAMA HIROYUKI, SATO KOICHI, SHINJO KENJI, KITAYAMA, HIROYUKI, SATO, KOICHI, SHINJO, KENJI
Applicants: CANON KK, CANON KABUSHIKI KAISHA
Application year: 1995
Main classification: C09K19
IPC codes: C09K19