Photographic processing apparatus

Abstract: A photographic processing machine having at least two processing tanks for holding different processing solutions and a removable container (100) containing at least two working strength processing solutions in separate sub-containers (10 - 50) therein from which the processing tanks are fed characterized in that the sub-container which feeds the first used processing tank comprises a level detector (60 and 70) and in that when the level falls to a predetermined limit, an indicator means is activated signalling the necessity for changing the processing solution container.

Description: Field of the Invention This invention relates to photographic processing apparatus and to a method of determining when a batch of processing solution(s) need replacing. Background of the Invention Many known small photographic processing machines are supplied with processing solutions by means of a cartridge or cassette or ready-made working strength solution(s). For example such a multiple cartridge could comprise a colour developer solution, a bleach fix solution and two or three wash and/or stabiliser solutions. Such containers can also contain filter or treatment means. Often such cartridges are returned to the manufacturer for recycling or disposal. U.S. 5184164 discloses a replenishing device using replenishment cartridges, EP-0-192282 discloses a liquid supply reservoir. Problem to be solved by the Invention It is not always clear when to replace the cartridge; too early would be wasteful while too late would cause the processing to go out of control and produce undesirable results. Merely counting the number of sheets or lengths processed and calculating the "worst case" scenario could result in leaving serviceable solutions in the container. Such a scenario, for example, might assume that every frame is fully exposed thus requiring maximum amounts of developer and bleach-fix. Summary of the Invention According to the present invention there is provided a method of processing imagewise exposed photographic materials in a photographic processing machine as defined in claim 1. Additionally the present invention provides a photographic processing apparatus as defined in claim 5 and a processing solution cartridge as defined in claim 8. Advantageous Effect of the Invention The processing solution container of said cartridge is changed neither too early nor too late thus saving waste in the former case and improving the quality of the processing in the latter, eg when the squeegees have deteriorated. The present invention is particularly useful in a case where developer carry-over into the bleach-fix bath reduces the bleach-fixing activity of the solution. When loss by evaporation is small (which is usually the case in small processing machines or minilabs) particularly good results are obtained. Brief Description of the Drawings Figs 1 and 2 of the accompanying drawings show a multicontainer processing solution pack and Fig 3 shows a plot illustrating the results of Example 3 below. Detailed Description of the Invention Provided that the loss from a processor tank due to evaporation is small compared to the volume carried over from one tank to the next, the loss from that container is equivalent to the amount added to the next bath. Applying this to the developer tank, when the level falls to a predetermined amount it would indicate that the second tank's contents are outside acceptable limits. The predetermined amount needs to be established by experiment. It is preferred to locate the level detector in or on the sub-container, especially in the developer sub-container. The level detector maybe of any type with the following being preferred: (a) Electrodes in the sub-container where an increase in resistivity would indicate lack of aqueous solution at the level of the electrodes, (b) A photo-detecting system, eg a photodiode emitter and a radiation-sensitive detector means, relying on total internal reflection or light transmission, or (c) A weighing system where a predetermined loss of weight could be detected. The indicator means may be a bell, buzzer, light or other like means or the level detector and indicator means may be combined as a mark on a transparent part of the sub-container that can be viewed by the operator. Alternatively a totally or partially transparent container having a level mark visible to the operator could act as a combined level detector and indicator means. The present invention is particularly applicable to small processing machines, especially those known as minilabs. Such machines are designed to be operated by someone without much knowledge of processing chemistry and are therefore as automatic as possible. A paper processing machine would normally comprise develop and bleach-fix tanks with one or more wash or stabilise tanks. The process may comprise the steps of: (a) colour development, (b) bleach, (c) fix followed by one or more wash or stabiliser steps or a similar method in which the bleach and fix baths are combined into a single bleach-fix bath. Preferably a sub-container feeding a tank used after the image-forming step(s) contains activated charcoal or an ion-exchange resin or mixtures thereof to remove unwanted processing chemicals, for example, colour developing agent. In a particular embodiment the bleach-fix sub-container contains activated charcoal to remove unwanted colour developer carry-over while the last stabiliser sub-container contains ion exchange resin or mixtures thereof. In particular a mixture of anionic and cationic ion exchange resins can be employed. Alternatively the process may comprise the steps of: (a) development, and (b) fix, followed by one or more wash or stabiliser steps. The developer would typically be a black-and-white developer. A further alternative would be in the case of a redox amplification process in which the first bath is a redox amplification bath or, especially, a redox developer-amplifier bath. Such amplification processes are well known. Redox amplification processes have been described, for example in British Specification Nos. 1,268,126, 1,399,481, 1,403,418 and 1,560,572. In such processes colour materials are developed to produce a silver image (which may contain only small amounts of silver) and then treated with a redox amplifying solution (or a combined developer-amplifier) to form a dye image. The developer-amplifier solution contains a colour developing agent and an oxidising agent which will oxidise the colour developing agent in the presence of the silver image which acts as a catalyst. Oxidised colour developer reacts with a colour coupler to form the image dye. The amount of dye formed depends on the time of treatment or the availability of colour coupler and is less dependent on the amount of silver in the image as is the case in conventional colour development processes. Examples of suitable oxidising agents include peroxy compounds including hydrogen peroxide and compounds which provide hydrogen peroxide, eg addition compounds of hydrogen peroxide; cobalt (III) complexes including cobalt hexammine complexes; and periodates. Mixtures of such compounds can also be used. The materials to be processed and the processes to be used are described in Research Disclosure Item 308119, December 1989 published by Kenneth Mason Publications, Emsworth, Hants, United Kingdom. In the accompanying drawings, Figs 1 and 2 show schematically a removable container containing 4 working strength processing solutions in 5 separate sub-containers. Cartridge 100 contains sub-containers 10 - 50 which respectively contain the processing solutions: developer, bleach-fix, stabiliser, stabiliser and stabiliser. Each solution is supplied to the appropriate processing tank and returned via tubes by circulation means, eg a pump, not shown. The level detection means comprises two electrodes 60 and 70 which stop showing a small resistance when the level of the liquid has fallen below the bottom end of the electrodes. This event can trigger the alarm. To extend the useful life of the container, the bleach-fix sub-container (20) contains activated charcoal 80 to remove developing agent while the last stabiliser sub-container contains ion-exchange resin (90) to remove ionic species carried over from previous baths. In Fig 2 a similar cartridge fitted with a radiation detector and radiation source on the opposite side (not shown). This will trigger when the liquid falls below the level of the detector. The bleach-fix sub-container contains activated charcoal to remove unwanted colour developer carry-over while the second stabiliser sub-container contains ion exchange resin or mixtures thereof. The following Example is included for a better understanding of the invention. EXAMPLE The bleach-fixing time of EKTACOLOR EDGE paper was determined in EKTACOLOR RA bleach-fix NR contaminated with different amounts of EKTACOLOR RA developer. The experiment was carried out by developing a long fogged length of EDGE paper for 45 seconds at 35°C, then stopping it in 5% acetic acid followed by a 2 minute wash. The bleach-fixing time of this was determined by observing the infra red density of the material in the bleach-fix solution in a transparent cell designed for the purpose. This has been described in J.Phot.Sci 32 (1984) 235-244. Amounts of the bleach-fix were used to which different amounts of the developer had been added. The results are shown in fig 3 of the accompanying drawings. It can be seen that the bleach-fix time is beginning to exceed 35 secs, the aim time for the processor, after 40% developer had been added. This indicates the end of the usefulness of the bleach fix solution. If the cartridges illustrated in figs 1 and 2 have 500 ml developer and bleach-fix portions the level sensors should be set to indicate when the developer level has fallen by 200 ml. This would imply that the bleach-fix was approaching being 40% developer, the point at which it has been determined to have failed to function sufficiently well.

Claims: A method of processing imagewise exposed photographic materials in a photographic processing apparatus having at least two processing tanks for holding different processing solutions and a removable container (100) containing at least two working strength processing solutions in separate sub-containers (10-50) therein from which the processing tanks are fed, characterised by the step of: providing a solution level detector in the sub-container which monitors the first used processing tank of the apparatus so as to activate an indicator means when the solution level falls to a predetermined limit, thus signalling the necessity for changing the processing solution container. A method as claimed in claim 1 which comprises the steps of: (a) colour developing of the photographic materials, (b) bleaching of the photographic materials, (c) fixing of the photographic materials, followed by one or more washing or stabilising steps or similar steps in which the bleach and fix baths are combined into a single bleach-fix bath. A method as claimed in claim 1 which comprises the steps of: (a) developing of the photographic materials, (b) fixing of the photographic materials, followed by one or more washing or stabilising steps. A method as claimed in claim 1 or 2 in which the first used processing tank bath is a redox amplification bath or a redox developer-amplifier bath. Photographic processing apparatus comprising at least two processing tanks for holding different processing solutions and a removable container (100) containing at least two working strength processing solutions in separate sub-containers (10-50) therein from which the processing tanks are fed characterised in that a solution level detector (60, 70) is provided within the sub-container which monitors the first used processing tank of the apparatus and an indicator means is provided on the apparatus, activatable by the level detector (60, 70) so as to signal the necessity for changing the processing solution container when the solution level in the sub-container falls to a predetermined level. Processing apparatus as claimed in claim 5 which comprises four processing tanks and in which the container comprises four sub-containers. Processing apparatus as claimed in claim 5 or 6 which comprises means for circulating each processing solution to and from each respective pair of tanks and corresponding sub-containers. A photographic processing solution cartridge comprising a container (100) to be used in a photographic processing apparatus having at least two processing tanks, the container containing at least two separate sub-containers (10-50) therein with working strength processing solutions characterised in that one of the sub-containers comprises a level detector which monitors the first used processing tank. A photographic processing solution cartridge as claimed in claim 8 in which the level detector comprises: (a) Electrodes (60, 70) in the sub-container where an increase in conductivity would indicate lack of aqueous solution at the level of the electrodes, or (b) A photo-detecting system comprising a photodiode emitter and a radiation-sensitive detector means, or (c) A weighing system where a predetermined loss of weight could be detected, or as a combined level detector and indicator means (d) a totally or partially transparent container having a level mark visible to the operator. A photographic processing solution cartridge as claimed in claim 8 or 9 which contains activated charcoal (80) in a bleach-fix or fix sub-container (20). A photographic processing solution cartridge as claimed in any of claims 8-10 in which the last wash or stabiliser sub-container (50) contains an ion-exchange resin (90) or mixtures thereof.

Inventors: FYSON JOHN RICHARD, FYSON, JOHN RICHARD, FYSON, JOHN RICHARD, C/O KODAK LIMITED
Applicants: EASTMAN KODAK CO, KODAK LTD, EASTMAN KODAK COMPANY, KODAK LIMITED
Application year: 1994
Main classification: G03D3
IPC codes: G03C7, G03D3