Improved gas dispersion apparatus for molten aluminum refining

Abstract: The maximum useful rate of aluminum refining is increased by baffle means positioned across the refining chamber under the rotor of a spinning nozzle in the refining chamber, with open spaces to facilitate cleaning being provided in the vicinity of the side wall of the refining chamber.

Description: BACKGROUND OF THE INVENTION Field of the Invention This invention relates to the refining of molten aluminum. More particularly, it relates to the dispersion of a gas in the molten aluminum. Description of the Prior Art Molten aluminum, as derived from most common sources, such as primary metal, scrap and re-melt ingot, usually must be purified before being cast into ingots, sheets or bars. This may be done by bubbling an inert gas, i.e., nitrogen or argon, through the aluminum in molten form. In some embodiments, a halogen gas, usually chlorine, is added, or the halogen gas may be used alone for such purification purposes. This type of treatment can remove dissolved hydrogen, alkali metals such as sodium and lithium, and small solid particles such as aluminum oxide. The effectiveness of a given volume of gas in such treatment is increased by reducing the bubble size of the gas in the molten aluminum, thereby increasing the total gas-metal surface area. The effectiveness of the gas bubbles is also increased by the dispersing of said gas bubbles throughout the body of molten aluminum to be treated. One very effective way of both making small bubbles and dispersing them is by the use of a spinning nozzle positioned in the body of molten aluminum. Commercial systems are available for this purpose, including the SNIF™ systems of Union Carbide Industrial Gases Inc. for in-line refining of metals flowing from a holder to a casting station. The Pelton patent, U.S. 4,784,374, discloses and illustrates a particular embodiment of said SNIF™ system. The refining rate of such a spinning nozzle system can be increased by increasing the process gas flow rate employed therein. It is usually also necessary to increase the nozzle rotating speed to continue the desired making of small bubbles and the dispersing of said small bubbles throughout the molten aluminum in the refining zone of the system. Such increase in gas flow and nozzle rotating speed are usually accompanied by increased turbulence on the surface of the molten aluminum. The maximum refining rate of a given refining system, however, is limited by the maximum surface turbulence or roughness that can be tolerated therein. Excessive surface turbulence is undesirable in a refining system for several reasons. Thus, the increased metal surface area that is produced thereby leads to higher reaction rates with any reactive gas that might be present. For example, oxygen from air will react to form aluminum oxide films, and water vapor from the air will react to form hydrogen in the metal and oxide films. Furthermore, when solid particles are carried to the molten metal surface by the refining gas bubbles, surface turbulence may interfere with their desired separation from the bubbles and their incorporation into the floating dross layer formed over the body of molten aluminum. Excessive turbulence may also cause floating dross to be re-dispersed into the molten aluminum. While the quantative effects of excessive surface turbulence are difficult to measure, those skilled in the aluminum refining art are nevertheless aware from experience that high surface turbulence is undesirable, and will strive to limit such surface turbulence to levels considered acceptable in practical commercial operations. US-A-3 870 511 discloses a chamber for refining molten aluminum by using a spinning nozzle assembly to inject an inert gas into the molten metal beneath the surface of the melt. In one embodiment the refining chamber is divided into two subchambers by means of a partitioning wall. Cross-over holes in the partitioning wall facilitate liquid communication between the two adjacent subchambers, which are individually formed and each provided with a spinning nozzle assembly. Furthermore an insulated refractory lined refining chamber for aluminum refining is known from EP-A-0 500 052. This refining chamber includes a spinning nozzle assembly having a rotor portion positioned therein for injection of sparging gas into molten aluminum present in the refining chamber during aluminum refining operations, and comprising vertical baffle means positioned at the floor of and extending across the refining chamber. The baffle means are positioned under the rotor portion of the spinning nozzle assembly. It is an object of the invention to provide for an improved refining system for the production of aluminum which facilitates draining and cleaning operations in the refining chamber. Summary of the invention The present invention provides for an insulated refractory lined refining chamber for aluminum refining as defined in claim 1. The open spaces near one or both ends of the baffle facilitate draining and cleaning operations in the refining chamber. Brief Description of the Drawings The invention is hereinafter described with reference to the accompanying drawings in which: Fig. 1 is a plan view of a spinning nozzle rotor as used in the SNIF™ system referred to above; Fig. 2 is a side elevational view of said spinning nozzle rotor and the stator commonly employed therewith; Fig. 3 is a plan view of another type of spinning nozzle employed without a stator; Fig. 4 is a side elevational view of the spinning nozzle of Fig. 3; Fig. 5 is a side elevational view of a typical spinning nozzle type of molten aluminum in-line refining system, including the baffle means employed in the practice of the invention; Fig. 6 is a plan view of the spinning nozzle system of Fig. 5; Fig. 7 is a cross-sectional view of a particular embodiment of said baffle means used in the practice of the invention; Fig. 8 is a side elevational view of a particular embodiment of the spinning nozzle refining system incorporating a particular baffle means configuration providing for open spaces at the ends of baffle means in conformity with the invention; Fig. 9 is a side elevational view of a particular aluminum refining chamber useful in the practice of the invention; Fig. 10 is a plan view of the aluminum refining chamber of Fig. 9; Fig. 11 is a plan view of a particularly desirable rotor for use in the practice of the invention; Fig. 12 is a side elevational view of the rotor of Fig. 11 together with a stator used in conjunction therewith in an embodiment of the invention; and Fig. 13 is a side elevational view of another embodiment of the invention providing for open spaces at the ends of baffle means used in the practice of the invention. DETAILED DESCRIPTION OF THE INVENTION As spinning nozzle, for purposes of the invention, will be understood to comprise a cylindrical rotor having protruding vanes and some means for introducing a process gas into a space between the vanes. The rotor used in the SNIF™ systems referred to above is shown in Figs. 1 and 2 of the drawing, with said rotor being represented by the numeral 1 and being mounted on shaft 2 having drive means, not shown, for the rotation of said rotor 1. The rotor is illustrated as having desirable vanes 3 extending from the body thereof in a spaced apart configuration around the circumference of said rotor 1. Slots existing between individual vanes 3 are denoted by the numeral 4. Said vaned rotor 1 is shown in Fig. 2 together with stator 5 positioned around shaft 2 above said rotor. Process gas that is passed downward in the annular space between shaft 2 and stator 5 enters rotor 1 from a space 6 between the top of rotor 1 and the bottom of stator 5. In the embodiment shown in Figs 3 and 4, the spinning nozzle comprises a rotor without an accompanying stator. In this embodiment, rotor 7 is mounted on shaft 8 and includes vanes 9 spaced apart around the circumference thereof, with slots 10 existing between adjacent vanes 9. Shaft 8 has hole 11 extending therethrough so as to enable process gas to be passed downwardly therein to rotor 7. In order to introduce gas to the space between the vanes, i.e., to slots 10, rotor 7 contains gas exit holes 12 therein that extend from hole 11 in shaft 8 outwardly to said slots 10 between vanes 9. A typical spinning nozzle type of molten aluminum in-line refining system is illustrated in Fig. 5 of the drawings, with a rotor-stator assembly such as is shown in Figs. 1 and 2 being included for illustrative purposes only. In this system, an insulated, refractory lined refining chamber 13 is shown with an insulated cover 14 and with molten aluminum inlet 15 and refined molten aluminum outlet 16 positioned at opposite sides thereof. During operation, the molten aluminum is maintained at a desired molten aluminum level 17 with the spinning nozzle assembly, generally represented by the numeral 18, being positioned in the molten aluminum below operating level 17 with stator 19 and shaft 20 enclosed thereby extending upward through insulated cover 14. Rotor 21 is positioned below said stator 19 so as to reduce the size of gas bubbles present in the space 22 between stator 19 and rotor 21 and to disperse said gas bubbles throughout the body of molten aluminum, which is denoted by the numeral 23, present in refining chamber 13 during aluminum refining operations therein. Molten aluminum continuously enters refining chamber 13 through inlet 15 and is continuously refined by the action of spinning nozzle 18 as it mixes the body of molten aluminum 23 and disperses gas introduced therein through said spinning nozzle in the form of small gas bubbles and distributes said small bubbles throughout the molten aluminum. The refined molten aluminum is continuously passed from refining chamber 13 through outlet 16. Dross resulting form the extraction of solid particles and alkali metals form the molten aluminum floats on the surface of the molten aluminum and is skimmed off thereof. Hydrogen removed from the molten aluminum by the process gas bubbles enters the gas space 24 above molten aluminum operating level 17 and is removed from refining chamber 13 along with spent process gas. Vertical baffle means 25 is positioned across the bottom of the interior of refining chamber 13 under rotor 21 to increase the maximum useful refining capacity of the spinning nozzle aluminum refining system. As shown in Fig. 6, baffle means 25 is advantageously positioned under the center of rotor 21. Baffle means 25 may be a simple rectangular sheet of refractory material, sufficiently thick to have adequate strength for its intended purpose and provided with open spaces 56 and 57 as illustrated in more detail in Fig. 8. A convenient shape of said baffle means 25 in practical operating systems is shown in Fig. 7, whereby the roughly triangular cross-section is strong enough to resist mechanical damage during post-refining cleaning operations and also provides slanting surfaces that make it easier to clean the bottom of refining chamber 13 than if baffle means had vertically extending walls as in the Fig. 5 embodiment. In the Fig. 8 embodiment, baffle means 25 is shown as having a constant height section 26 under the center and in the vicinity of rotor 21, with raised end sections 27 and 28 extending upward in the direction of the side walls of refining chamber 13. This increasing height baffle means has been found to provide a small increase in refining effectiveness, but it is not an essential feature of the invention. Holes 56 and 57 are cut out of baffle 25 at the lower portion of each end thereof near the side walls of the refining chamber. The spinning nozzle used in aluminum refining is usually positioned at the center of a rectangular refining chamber as shown in Fig. 6. It should be noted, however, that the spinning nozzle may be located off center in said refining chamber if convenient for some reason, such as convenience of construction or access. In any event, the baffle means of the invention will be positioned under the rotor, preferably under the center of the rotor element, of the spinning nozzle. It should be noted that, if the refining chamber is rectangular with approximately vertical sides, said baffle means may be positioned parallel to either the short side, as in the Fig. 6 embodiment, or the long side of the rectangle. However, it is generally most effective when positioned parallel to the short side. Refining chamber 13 may also have a slanting wall, such as wall 29 of Fig. 9, at one end of refining chamber 13, or at one side thereof, to facilitate cleaning or emptying of the chamber. In such embodiments, baffle means 25 is preferably positioned parallel to the base of slanting wall 29. In the embodiment shown in Figs. 9 and 10 a two-nozzle system in which refining chamber 30 has a partition 31 therein that serves to separate the operating space into two separate refining compartments, with molten aluminum being passed into first compartment 32 through inlet 33 and with refined molten aluminum being discharged from the system through outlet 34 from second compartment 35. Crossover hole 36 in partition 31 enables molten aluminum to pass from first compartment 32 to second compartment 35. Spinning nozzle assembly 37 is positioned in said compartment 32, and a second spinning nozzle assembly 38 is positioned in said compartment 35. Front wall 29 of each compartment is slanted at an angle of 20° to facilitate emptying and cleaning. Baffle 39 is placed under the center of the rotor of nozzles 37 and 38 and parallel to slanting front wall 29 and to the back wall of refining chamber 30. Holes 56 and 57 are cut out of baffle 39 at the lower potion of each end thereof near the side walls of the refining chamber 30 as well as near the partition 31. The useful height of the baffle means of the invention will be understood to depend upon the operating circumstances pertaining to any particular refining application, e.g. the size of the refining chamber and of the spinning nozzle employed therein. Typical refining systems presently in use have spinning nozzle ranging in size from about 178 to 254 mm (7" to 10") in diameter and about 63 to 102 mm (2 1/2" to 4") in height. Typical refining chambers are about 508 to 762 mm (20" to 30") in width, about 762 to 1016 mm (30" to 40") in length, with molten metal depths of about 635 to 889 mm (25" to 35"). For such size systems, the height of the baffle means of the invention is typically about 51 to 203 mm (2" to 8") or more, with the baffle means height preferably from about 76 to 127 mm (3" to about 5"). The distance between the top of the baffle means of the invention and the bottom of the spinning nozzle rotor may be varied from a fraction of 25 mm (an inch), e.g. on the order of about 13 mm (1/2"), up to about 102 mm (4") or more. It should be noted that a very small clearance, e.g. 13 mm (1/2") will work well in relatively clean molten aluminum. In practice, however, small, hard pieces of refractory from up-stream sources may inadvertently be present in the molten aluminum. Such pieces of refractory can become caught between the baffle of the invention and the rotor, causing breakage of the rotor or its shaft, typically made of graphite. From a practical operating viewpoint, therefore, it is generally desirable to employ a clearance in the range of from about 51 mm (2") to about 76 mm (3") between the top of the baffle means and the bottom of the rotor. A clearance of about 51 mm (2") over a baffle 102 mm (4") high, for example, will avoid the likelihood of damage from most kinds and sizes of refractory pieces commonly found in operating SNIF™ systems for the refining of aluminum. In a preferred embodiment of the invention, even better refining rates were obtained at a given surface roughness by the use of a special rotor in conjunction with the use of the baffle means of invention. This rotor is shown in plan view of Fig. 11 and in side view in conjunction with a desirable stator shape in Fig. 12. The essential difference between the special rotor and a conventional vaned rotor as shown in Figs. 1 and 2 is that the liquid entry from the bottom of the rotor is partially restricted, while liquid entry from the top of the rotor is not so restricted. The special rotor design also directs the flow of liquid from the bottom into the base of the rotor slots and in a mostly upward direction. In addition, this special rotor configuration presents a continuous circular shape on its lower outer edge. This shape is much less subject to damage from hard solid pieces of foreign material that may be drawn up and into the rotor during commercial operations. The special rotor, represented by the numeral 40 and mounted on rotor drive shaft 41 in Fig. 11, has vanes 42 positioned around the rotor periphery, with slots 43 located between adjacent vanes. As shown in Fig. 12 and unlike the rotor of Figs. 1-4, slots 43 do not extend to the full height of adjacent vanes 42 but for only a slot portion 44 thereof. Below said slot portion 44, restricted portion 45 remains and forms, together with adjacent vanes 42, a cylindrical base portion 46 of rotor 40, as will be seen in Fig. 11. In order to provide for passage of molten aluminum from the region below the rotor to slot portion 44, openings or holes 47 are provided in each said restricted portion 45. Said openings 47 are preferably positioned essentially at the innermost end of restricted portion 45, and provide access for molten aluminum to slot portion 44 of each slot 43, preferably toward the innermost portion thereof for enhanced molten liquid flow effect. In the use of the invention, it is desirable that the process gas enter the rotor continuously and uniformly in all rotor slots 44. However, the turbulent motion of the liquid as it approaches the rotor from above tends to produce a non-uniform gas flow to the rotor. If, for example, the liquid momentarily flow toward the rotor more rapidly from one side thereof, it tends to shut off the gas exiting on that side and to increase the flow to other parts of the rotor. This tendency can be reduced by making the gap 49 between the top of rotor 40 and the bottom of stator 48 very small so as to produce an appreciable pressure drop at this point. For such purpose in practice, however, it is necessary to reduce this gap to about 0.51 mm (0.020") or less for most embodiments. Since the gap is set during assembly of the rotor-stator unit at a desired plant location, the achieving of this very small gap is dependent upon the care and skill with which it is assembled. In addition, the gap can change in operation due to temperature changes and the like. A more suitable means for achieving such gas flow control is thus desired for practical commercial applications. As shown in Fig. 12, a preferred means of achieving desired gas flow control is obtained simply by the inclusion of a stator boss and corresponding rotor recess. Thus, boss portion 50 is provided at the bottom end of stator 48 and is adapted to fit into a recess portion 51 at the top of rotor 40. The small gap passage required to produce more uniform gas distribution throughout the rotor is provided by radial gap 52 between the outside diameter of boss 50 and the inside diameter of recess 51 on the side toward rotor slot 44. This gap 52 can be controlled at the point of manufacture and is not dependent, as is a conventional small gap between the top of the rotor and the bottom of the stator, upon the care and skill of assembly of the rotor-stator unit. Small radial gap 52 will generally be controlled at about 0.64 mm (0.025"), although somewhat larger or smaller distances can be employed depending upon the overall structure of the unit and of the refining chamber and application with which it is to be employed. In this preferred embodiment, stator boss portion 50 and rotor recess portions 51 can both be about 6.4 mm (1/4") high or deep in common practice. The vertical gap 49 between the bottom of stator 48 and the top of rotor 40 and between the bottom of stator boss portion 50 and the top of rotor recess portion 51, can be set at a greater tolerance, e.g., about 1.6 mm (1/16") with the exact setting not being critical for the desired gas flow control purposes. As shown in the illustrated embodiment of Fig. 12, process gas passes downward through gas entry passage 53 adjacent rotor shaft-stator bearing 54, and through gas passageway 55 to stator-rotor gap 49, including small radial gap 52 for the desired gas flow control. The gas exits from stator-rotor gap 49 and enters rotor slots 44 in a continuous and uniform manner. The stator diameter is preferably made slightly larger than the root diameter of the rotor, i.e., the diameter at the base of the vanes, so that the process or sparging gas is caused to pass downward into the rotor slots by the downward flow of molten aluminum, and none of said process gas is allowed to escape upward and avoid being dispersed by the action of the rotor. When no stator is employed, the process gas is introduced into the rotor via holes that lead to the spaces between rotor vanes as shown in Figs. 3 and 4. In the absence of a stator, it may be desirable to employ a cylindrical abutment to essentially duplicate the function of the stator in directing the flow of process gas downward. The area of the openings 47 in restricted portion 45 in the bottom of the rotor in relation to the total opening, if unrestricted, is generally in the range of from about 25% to about 75%, with an opening area of about 50% being preferred. The height of restricted portion 45 of rotor 40 should be generally in the range of from about 20% to about 40% of the overall rotor height, with a restricted portion height of about 30% being preferred for use in typical sized refining chamber units. The rotor as shown in Fig. 11 has rounded corners at the base of the vanes, and the holes for molten aluminum entry from below the rotor also have rounded edges. While the radii thereof are not essential to the performance of the rotor, they result from a convenient means of machining the rotor by cutting slots and entry holes therein with a vertically oriented end mill. It will be understood that, while reference is made herein to aluminum refining in general, the invention can be practiced with respect to aluminum or to the various alloys thereof. The invention can be practiced in systems having refining chambers having one or more refining compartments or stages, each of which is adapted for the positioning of a spinning nozzle assembly therein during aluminum refining operations. In a typical two-stage refining system, molten aluminum is commonly passed into the inlet of the first stage and removed from the outlet from the second stages. The separate compartments are separated by a baffle adapted to enable molten aluminum to flow from the first stage to the second stage. Other such systems can incorporate more than two such refining stages therein. The bottom baffle means of the invention will desirably be employed in each refining compartment. Said baffle means can be constructed of any suitable refractory material suitable for incorporation in the refining chamber. Silicon carbide is a generally preferred material of construction for this purpose, although other refractories, e.g., graphite, can also be employed. While the baffle means is preferably positioned so as to be located under the center of the rotor portion of the spinning nozzle assembly upon placement thereof in the refining chamber, the baffle means may also be otherwise positioned so as to be located under said rotor portion, but should not be positioned beyond the periphery of the rotor. The baffle means of the invention, as illustrated in the drawings, are positioned at the floor of and extend all the way across the refining chamber. The baffle means serve to change the flow pattern of molten aluminum so as to enable higher gas flows and/or nozzle rotating speeds to be employed, without excessive surface turbulence. To facilitate draining or cleaning operations in the refining chamber while advantageously employing said baffle means, essentially open space is provided at one or both ends of the baffle means at or near the walls of the refining vessel. It enables the flow pattern to be changed to enable higher gas flows and/or nozzle rotating speeds to be employed, without excessive surface turbulence, while also facilitating draining and cleaning operations in the refining chamber operations in the refining chamber. Thus, baffle means having the open spaces enables debris, such as that formed in refining chamber cleaning operations, to be readily scraped or pushed into one section of the bottom of the chamber for removal. In illustrative examples of the invention, a baffle arrangement as shown in Fig. 8 was employed, with baffle 25 having a baffle section 26 that is 660 mm (26") long and 102 mm (4") high, with rotor 21 being positioned 51 mm (2") above the baffle, i.e., 153 mm (6") above the floor of refining chamber 13. As shown in Fig. 8, holes 56 and 57 are cut out of baffle 25 at the lower portion of each end thereof near the side walls of the refining chamber. The holes are 51 mm (2") high and 102 mm (4") wide, with the overall length of baffle 25 being 660 mm (26"). The presence of such cut-outs was not found to affect the refining operation in any observable way. While holes of such size were convenient for purposes of the desired draining and cleaning operations, in which molten aluminum is removed from the refining chamber and in which debris is conveniently scraped or pushed into one portion of the bottom of the refining chamber for convenient removal, cut-out portions of other suitable sizes can be employed for such purposes. In further illustrative examples of the invention, straight baffles were employed without the end riser portions shown in Fig. 8. In the examples, various baffle lengths were employed, with the baffle being positioned under the center of the rotor means used in refining operations. In addition to a full length baffle, shorter baffles, not extending all the way across the refining chamber from one side to the other, were employed. Thus, in Fig. 13, refining chamber 58 is shown with spinning nozzle 59 having rotor 60 positioned therein, and with baffle means 61 of shorter overall length than in the previously illustrated embodiments, positioned on the floor of the chamber. Open spaces 62 and 63 are thereby provided on each side of the chamber to facilitate draining and cleaning operations. In each case, baffle means 61 and rotor 60 were desirably centered in refining chamber 58, although this is not essential for acceptable refining operation purposes. Starting with a baffle 61 of full length, i.e., one extending all the way across the chamber from one end to the other, the baffle was first shortened by cutting 51 mm (2") from each end, making the baffle 559 mm (22") long in a refining chamber 58 660 mm (26") across. Thus, openings 62 and 63 were each 51 mm (2") long from the wall of refining chamber 58 to the nearest end of baffle 61. Using this shortened baffle, there was a small but noticeable increase in surface roughness when the refining system, having the shortened baffle in place, was employed instead of the baffle extending all the way across the refining chamber, which had the rotor of Figs. 11 and 12 positioned therein. The baffle means was then shortened in additional increments of 102 mm (4") down to a baffle 254 mm (10") long, and then to a baffle 191 mm (7 1/2") long, which is the same as the rotor diameter. Each step of decreased baffle length was found to decrease the effectiveness of the baffle, upon use in refining operations. However, even the shortest baffle was found to be advantageous as compared to the use of no baffle at all. Those skilled in the art will appreciate that various changes and modifications can be made in the details of this aspect of the invention intended to facilitate draining and cleaning of the refining chamber, while achieving the beneficial effects of the baffle means in changing the flow pattern of molten aluminum as described above. Baffles as short as the rotor diameter are useful for purposes of the invention, i.e., baffles having a length of about 30% of the width of the chamber, i.e., the smallest horizontal dimension of the chamber. The particular length of the baffles useful in any given application will be determined by the overall configuration and size of the refining chamber and the spinning nozzle employed. While employing a shortened baffle providing open ends at both ends of the refining chamber, e.g., open ends 62 and 63 in Fig. 13, is generally desired, it will be understood that the baffle means may also, in other embodiments, extend from one side of the refining chamber in the direction of the other side, such as to leave an open end at only one side of the chamber, e.g., only open space 62 or 63, but not both. Likewise, the cut-out openings at the bottom of the baffle in the vicinity of the sides of the refining chamber, i.e., openings 56 and 57 in Fig. 8, can be made of any convenient size for the desired draining and cleaning purposes. If openings 56 and 57 in the Fig. 8 embodiment were enlarged upward, it will be seen that such openings would approach the open spaces 62 and 63 as provided by the shortened baffles of the Fig. 13 embodiment. It will also be understood that, in the practice of the cut-out opening embodiment of the invention, a cut out opening can be provided at only one side of the refining chamber, desirably in the vicinity of the wall thereof, to provide the desired draining and cleaning capability, although the providing of openings at both ends of the baffle, preferably in the immediate vicinity of the side walls of the refining chamber is preferable. It should be noted that, using the rotor as shown in Fig. 1 and 2 at a rotor distance of 152 mm (6") from the refining chamber floor, and employing baffles extending all the way across the chamber and shortened baffles, down to 254 mm (10") long, as in Fig. 13, the results were essentially the same as when the rotor of Figs. 11 and 12 were employed. At the shortest baffle length, e.g., 191 mm (7 1/2"), it was necessary to adjust the position of the rotor downward, e.g., to 121 mm (4 3/4") above the refining chamber floor, to obtain improved results by the use of the baffle means. At this rotor height, the operation was further improved as the baffle length was increased in steps. In other examples of the practice of this embodiment of the invention, the baffles were oriented in the refining chamber from one end to the other, i.e., for and aft, rather than being positioned along the shorter distance across the chamber from one side to the other. In each case, the rotor of Figs. 11 and 12 was employed at a rotor height of 152 mm (6"), using straight baffles of from 254 mm to 559 mm (10" to 22") in length. In each case, the baffles improved performance, i.e., enabled a smoother surface of molten aluminum to be obtained, but the amount of improvement was markedly less than when the baffle was oriented across the chamber in the preferred embodiments of the invention. The invention will thus be seen, in enabling the maximum useful rate of refining in a refining chamber to be substantially increased over conventional practice, to provide a highly desirable and useful advance in the aluminum refining art.

Claims: An insulated refractory lined refining chamber for aluminum refining, including a spinning nozzle assembly (18, 37, 38, 59) having a rotor portion (21, 40, 60) positioned therein for the injection of sparging gas into molten aluminum present in the refining chamber (13, 58) during aluminum refining operations, and comprising vertical baffle means (25, 61) positioned at the floor of and extending across said refining chamber. said baffle means being positioned under the rotor portion of said spinning nozzle assembly characterized in that said baffle means (25, 61) provides an open space (56, 57, 62, 63) immediately adjacent to one or both side walls of the refining chamber (13, 58). The refining chamber of claim 1 in which said baffle means (25, 61) is such as to provide open spaces (56, 57, 62, 63) immediately adjacent to each side wall of the refining chamber (13, 58). The refining chamber of claim 1 in which the baffle means (25) contain one or more cut out openings (56, 57) to provide the open space immediately adjacent to one or both side walls of the refining chamber (13). The refining chamber of claim 3 in which said cut out openings (56, 57) are provided immediately adjacent to each side wall of the refining chamber (13). The refining chamber of claim 1 in which the length of the baffle means (61) is such that an open space (62, 63) is provided between the end of the baffle means and the side wall of the refining chamber (58) immediately adjacent to one or both said walls of the refining chamber. The refining chamber of claim 5 in which said baffle (61) has a length of at least about 30 % of the length of a baffle extending all the way across the floor of the refining chamber (58) from one side to the other. The refining chamber of claim 5 or 6 in which the baffle (61) is positioned so as to provide an open space (62, 63) immediately adjacent to each side wall of the refining chamber (58). The refining chamber of claim 3 or 4 in which said cut out openings are on the order of 50,8 mm (2") high and 101,6 mm (4") long. The refining chamber of claim 7 in which the distance across the refining chamber is about 660,4 mm (26"), said baffle having a length of from about 559 mm (22") to about 190,5 mm (7 ½"). The refining chamber of anyone of the preceding claims in which said baffle means (25. 61) is located under the center of the rotor portion (21, 40, 60) of the spinning nozzle assembly (18, 37, 38, 59).

Inventors: PELTON JOHN FRANKLIN, PELTON, JOHN FRANKLIN
Applicants: FOSECO INT, FOSECO INTERNATIONAL LIMITED
Application year: 1994
Main classification: C22B21
IPC codes: C22B21, F27D23, F27D3