METHOD OF FORMING ELECTRICALLY CONDUCTIVE POLYMER INTERCONNECTS ON ELECTRICAL SUBSTRATES

Abstract: A method is presented for forming a bumped substrate and for forming an electrical circuit which includes the bumped substrate. The method of forming the bumped substrate includes forming at least one electrically conductive polymer bump on each of a first set of bond pads of the substrate. At least one electrically conductive polymer bump is then formed on each of a second set of the bond pads of the substrate. The circuit is formed by selectively forming an organic protective layer around the bond pads of a second substrate by laser ablation of an organic protective coating on the second substrate. The electrically conductive polymer bumps on the first and second portions of the bond pads of the first substrate are then contacted with the bond pads of the second substrate, thereby forming the electrical circuit.

Description: METHOD OF FORMING ELECTRICALLY CONDUCTIVE POLYMER INTERCONNECTS ON ELECTRICAL SUBSTRATES Background of the Invention Integrated circuits have had almost universal application to communication and military technologies for several years. Of increasing importance has been development of microcircuit wafers and methods for interconnection of the circuits by automated equipment. A primary limitation to application of microcircuit technology has been cost efficiency and reliability of interconnection of integrated circuits on chips because of the small size of the chips, which often require hundreds of connections to be made within each circuit. One method of circuit interconnection is called flip chip bonding. Flip chip bonding can offer a shorter signal path and, therefore, more rapid communication between circuits than can other methods, such as tape automated bonding (TAB) or conventional wire bonding, because bond pads on flip chips are not restricted to the periphery of the chip, but rather are usually located at one face of the chip opposite a substrate. In one method of flip chip bonding, a chip or die is formed with the requisite integrated circuit and interconnect wiring required for interconnecting the circuit with other chip circuits on a circuit board, such as a separate printed circuit board or substrate. Bond pads are located at points of interconnection. Bumps are formed by plating of several layers of metals on the bond pads of the flip chips. Following deposition, the chip is heated to reflow the metals, thus causing surface tension of the deposit to form hemispherical solider "bumps." The flip chip is subsequently severed from the wafer of which it was a part and "flipped" for alignment with the bond pads of a substrate. These bumps are then contacted with the bond pads of the substrate and uniformly heated to simultaneously form interconnects between aligned bond pads of the flip chip and the substrate. Use of metals to interconnect bond pads of flip chips and substrates has required, however, that passivation of the flip chip be accomplished by use of a metal barrier such as titanium (Ti) , tungsten (W) or silicon nitride (Si 3 N 4 ) . Both the metal, as a passivation (or barrier) material, and ceramic, as a substrate material, are generally necessitated to allow sufficient heating to enable reflow of the solder bumps for interconnection between the flip chip and the substrate without consequential damage to either. Fabrication of circuits using bumped flip chips have also been limited by the inability to visually inspect interconnections between the flip chip and the substrate. Further, the yield of finished mounted circuits can be detrimentally affected by failure of interconnects caused by the difference between the coefficients of thermal expansion of the various materials comprising the flip chip, the passivation layer, the solder bumps and the substrate. Also, melting of the solder bumps creates an electrically conductive flux as an undesirable byproduct which generally must be removed from between the substrate and the flip chip to allow proper operation of the finished circuit. Problems of heat stress during fabrication have been addressed by various methods, such as by rapid application of heat to a bumped flip chip and rapid conduction of heat from the solder interconnects in order to minimize damage to flip chips, substrates and interconnections due to internal stresses caused by thermal expansion and contraction. However, this method is very expensive. Therefore, a need exists for a method of interconnection substrates such as flip chips, lead frames, multichip modules and printed circuit boards, which is fast, cost-effective and reliable. Also, there is a demand for a simplified method of interconnecting substrates which eliminates the need for elaborate plating procedures. Further, a method which enables greater flexibility of passivation and choice of substrate is also desirable. These improvements could promote cost efficiency and broaden the applications for which microcircuits are suitable. Summary of the Invention The present invention relates to a method of forming electrical interconnection bumps on bond pads of a substrate. In accordance with the present invention, an electrically conductive polymer bump is formed on each of a first set of bond pads,of a substrate. An electrically conductive polymer bump is then formed on each of a second set of the bond pads of the substrate. In one specific embodiment of the invention, a first template is aligned over the substrate. The template has openings which coincide with each of the first set of bond pads of the substrate. Bumps of electrically conductive polymer are formed on each of the first set of bond pads by directing the electrically conductive polymer through said aligned openings of the first template and onto each of the first set of bond pads. The first template is then removed from the substrate and a second template is aligned over the substrate. The second template has openings which coincide with each of the second set of the bond pads of the substrate. Bumps of electrically conductive polymer are then formed on each of the second set of bond pads by directing the electrically conductive polymer through said aligned openings of the second template and onto each of the second set of bond pads. The second template is then removed from the substrate. Further, an electrical circuit can be formed by the method of the invention. A second substrate is coated with an organic protective layer. Bond pads on the second substrate which coincide with the bond pads on the first substrate are exposed by laser ablation of the organic coating. The electrically conductive polymer bumps are then contacted with the bond pads of the second substrate to form the electrical circuit. Formation of electrically conductive polymer bumps in two separate steps allows the formation of distinct polymer bumps in very close proximity to each other. Resulting distances, or pitch, between of at least about six millimeters. Also, organic protective coatings can be selectively formed on substrates by removing portions of the coating by laser ablation. Bond pads on the substrate are thereby exposed for contact with electrically conductive polymer bumps on another substrate. Laser ablation allows precise control over the dimension of the openings formed in the organic protective layer. Also, residual coating remaining on the exposed bond pad is nominal when laser ablation is employed. Further, forming an electrical circuit by a method which includes contacting electrically conductive bumps on a first substrate with bond pads of a second substrate having a selectively formed dielectric coating eliminates resultant void space between the substrates. Consequently, the need to underfill void space is also eliminated. In addition, the organic protective layer provides improved strength of the resultant circuit and typically has an improved thermal conductivity relative to known underfill materials. The present method also forms circuits which are protected from attack by moisture and essentially eliminates the potential for formation of voids between the substrate of the circuit. Brief Description of the Drawing Figure 1 is a plan view of one embodiment of a substrate employed by the method of the present invention. Figure 2 is a section view of the substrate of Figure 1 taken along line II-II, and after a first template has been placed over the substrate. Figure 3 is a section view of the substrate and template shown in Figure 2 after electrically conductive polymer bumps have been formed on a first set of bond pads at the substrate. Figure 4 is a section view of the substrate and electrically conductive bumps as shown Figure 3, following removal of the template. Figure 5 is a section view of the electrically conductive bumps and substrate shown in Figure 4, and of a second template placed over the substrate and electrically conductive polymer bumps. Figure 6 is a section of view of the substrate and template shown in Figure 5 after an electrically conductive bump has been formed on a second set of the bond pads at the substrate. Figure 7 is a section view of the electrically conductive bumps formed on the bond pads of the substrate after the second template has been removed. Figure 8 is a section view of a second substrate suitable for use in an optional embodiment of the invention. Figure 9 is a section view of the substrate shown in Figure 8 following coating of the substrate and bond pads of the substrate with an organic protective layer, according to the method of the present invention. Figure 10 is a section view on the substrate and organic protective layer shown in Figure 9 following laser ablation of portions of the organic protective layer which cover the bond pads of the substrate. Figure 11 is a section view of the substrate and laser ablated organic protective layer of Figure 10, and of the substrate of Figure 7, having electrically conductive polymer bumps at the bond pads of the substrate. Figure 12 is a section view of an electrical circuit formed by contacting the electrically conductive polymer bumps at the first substrate with the bond pads at the second substrate, whereby void space between the first and second substrate is eliminated by the organic protective layer formed on the second substrate. Description of the Preferred Embodiments The above features and other details of the invention, either as steps of the invention or as combinations of parts of the invention, will now be more particularly described with reference to the accompanying drawings and pointed out in the claims. It will be understood that the particular embodiments of the invention are shown by way of illustration and not as limitations of the invention. The principle feature of the invention may be employed in various embodiments without departing from the scope of the invention. In one embodiment of the method of the present invention, a suitable substrate 10, such as that shown in Figure 1, has electrical bond pads 12,14,16,18 on upper planar surface 10 of the substrate. Examples of suitable substrates include flip chip dies, lead frames, multichip modules printed circuit boards, etc. Substrate 10 is formed of a suitable material, such as silicon , gallium arsenide, germanium or some other conventional semiconductor material. As can be seen in figure 2, a first template 22 is placed over upper planer surface 20 of substrate. First template 22 has openings 24,26 which are aligned with bond pads 14,18 which are a first set of the bond pads of substrate 10 is covered by template 22. As defined herein, the first set of bond pads of substrate 10 are those bond pads which are exposed by placement of the first template on substrate 10. The second set of the bond pads, as defined herein, are those bond pads which are covered by placement of the first template on substrate 10. In a specific embodiment, at least one bond pad of the second set of bond pads is located between bond pads of the first set. As seen in Fig. 2, bond pads 14,18 represent the first set and bond pads 12,16 represent the second set of the bond pads of substrate 10. First template 22 is suitable for screen printing electrically conductive polymer bumps onto the first portion of bond pads of substrate 10. An example of a suitable template is a Laseretch stencil, commercially available from IRI. Typically, the distance between the centers of bond pads of the first portion from the centers of bond pads of the second portion, also known as "pitch," is in the range of between about 1 and five millimeters. Generally, the pitch between bond pads of the second set is greater than about two millimeters. It is to bee understood, however, that the pitch between bond pads of the first portion from bond pads of the second set can be greater than five millimeters. Also, bond pads on substrate 10 can be arranged peripherally, in a staggered arrangement, or in an array on upper planar surface of the substrate 10. As shown in Figure 3, electrically conductive polymer bumps 28,30 are formed by directing the electrically conductive polymer through openings 24,26, respectively, of template 22 and onto the first set of the bond pads of substrate 10. Typically, electrically conductive bumps 28,30 are formed of a B-stage polymer or a thermoplastic polymer. The electrically conductive polymer bumps can be gold-filled, silver-filled, or filled with some other electrically conductive polymer bumps 28,30 is about flush with an upper surface 32 of template 22. Template 22 is then removed from substrate 10, thereby leaving free-standing electrically conductive polymer bumps 28,30 on the first set of bond pads of substrate 10, as shown in Figure 4. Second template 34 is then placed over substrate 10 and electrically conductive polymer bumps 28,30 at the first set of the bond pads, as shown in Figure 5. Second template 34 includes openings 36,38. The openings of second template 34 are aligned with bond pads 12, 16 which represent the second set of the bond pads of substrate 10. Second template 34 is of the same type of construction, and is fabricated in the same way, as first template 22, except that openings 36,38 of second template 34 are aligned with the second set of bond pads, rather than with the first set of bond pads. As shown in Figure 6, electrically conductive polymer bumps 40,42 are formed by a suitable method, such as stenciling , whereby the electrically conductive polymer is directed through openings 36,38 of second template 34 onto the second set of bond pads, which are bond pads 12,16. However, the height of the electrically conductive polymer bumps 40,42 formed on the second set of the bond pads is about the same as that of the electrically-conductive bumps formed on the first set of the bond pads. Any resultant differences in heights between the electrically conductive polymer bumps formed on the first set of bond pads and of and of the bumps formed on the second set of bond pads is small enough not to affect the formation of electrical interconnections between substrate 10 and a second substrate during fabrication of an electrical circuit. As shown in Figure 7, following removal of second template 34, electrically conductive polymer bumps 28,30,40,42 extend from the first and second sets of the bond pads of substrate 10. Optionally, an organic protective layer, not shown, can be formed on substrate 10 either prior to, or following, formation of the electrically conductive polymer bumps, as described in U.S. 5,237,130, the teachings of which are incorporated by reference. Generally, however an organic protective layer will be formed on upper planar surface 20 of substrate 10 only as a heat sink, which is employed during operation of the fabricated electrical circuit that includes substrate 10. As can be seen in Figure 8, second substrate 44 includes bond pads 46,48,50,52. Examples of suitable substrates include flip chips, lead frames, multichip modules and printed circuit boards. Bond pads 46,48,50,52 can be arranged in a peripheral pattern about upper surface 54 of substrate 44, in a staggered pattern, or in an array. Generally, bond pads 46,48,50,52 of second substrate 44 are arranged for alignment with electrically conductive polymer bumps 28,30,40,42 of first substrate 10. Organic protective layer 56 is formed over substrate 44 and bond pads 46,48,50,52 of substrate 44 by a suitable method. Optionally, substrate 44 can be passivated with silicon nitride or an oxide layer, not shown, before formation of organic protective layer 56. Organic protective layer 56 is preferably a dielectric polymer. An example of a organic material suitable for application in the present invention is Epo-Tek®, manufactured Epoxy Technology, Inc. Organic protective layer 56 passivates and thereby insulates and protects underlying surface 54 of second substrate 44. Bond pads 46,48,50,52 of second substrate 44 are then exposed by laser ablation of organic protective layer 44 to form openings 58,60,62,64. Preferably, laser ablation is preformed by employing an Excimer-type laser. Preferably, the thickness of organic protective layer 56 is about equal to the combined thickness of bond pads 12,14,16,18,46,48,50,52 of first and second substrates, and of electrically conductive polymer bumps 28,30,40,42. As shown in Figure 11, electrically conductive polymer bumps 28,30,40,42 at bond pads 12,14,16,18, of first substrate 10 are aligned with bond pads 46,48,50,52 of second substrate 44. Then, shown in Figure 12, electrically conductive polymer bumps 28,30,40,42 are contacted with bond pads 46,48,50,52 of second substrate 44, thereby forming an electrical circuit of the first and second substrates. Typically, an adhesive, not shown is formed on bond pads 46,48,50,52 of second substrate 44 before electrically conductive polymer bumps 28,30,40,42 are contacted to bond pads 46,48,50,52 of second substrate 44. Examples of adhesives which can be used includes theromsets, thermoplastics and polymer thick film. Adhesive is typically formed on substrate bond pads 46,48,50,52 by screen printing, templating, or by some other conventional method. In a preferred embodiment, first substrate 10 is aligned over second substrate 44 by an aligner bonder, such as a Model M-8 aligner bonder, manufactured by Research Devices, Division of the America Optical Corporation. Eguivalents Although preferred embodiments have been specifically described and illustrated herein, it will be appreciated that many modifications and variations of the present invention are possible, in light of the above teachings, within the purview of the following claims, without departing from the spirit and scope of the invention. For example, while the discussion is directed to a single substrate, or to two substrates to form only one circuit, it is to be understood that the concept can be readily expanded to include more substrates, with bond pads on each, bonded to form a plurality of circuits.

Claims: CLAIMS: 1. A method of forming interconnection bumps on bond pads of a substrate, comprising the steps of: a) forming an electrically conductive polymer bump on a first bond pad of the substrate; and thereafter b) forming an electrically conductive polymer bump on a second bond pad of the substrate. 2. A method of forming interconnection bumps on bond pads of a substrate, comprising the steps of: a) forming an electrically conductive polymer bump on each of a first set of bond pads of the substrate; and thereafter b) forming an electrically conductive polymer bump on each of a second set of bond pads of the substrate. 3. A method of Claim 2 wherein at least one bond pad of the first set is located between two bond pads of the second set. 4. A method of forming interconnection bumps on bond pads of a substrate, comprising the steps of: a) aligning a first template over the substrate, said first template having openings which coincide with each of a first set of bond pads of the substrate; b) forming bumps of electrically conductive polymer on the first set of bond pads by directing the electrically conductive polymer through said aligned openings of the first template and onto each of said first set bond pads; c) removing the first template over the substrate; d) aligning a second template over the substrate, said second template having openings which coincide with each of a second set of bond pads of the substrate; e) forming bumps of electrically conductive polymer on the second set of bond pads by directing the electrically conductive polymer through said aligned openings of the second template and onto each of said second set of bond pads; and 5. A method of Claim 4 wherein the electrically conductive polymer bumps are formed on the bond pads of a flip chip. 6. A method of Claim 4 wherein the electrically conductive polymer bumps are formed on the bond pads of a multichip module. 7. A method of Claim 4 wherein the electrically conductive polymer bumps are formed on the bond pads of a lead frame. 8. A method of Claim 4 wherein the electrically conductive polymer bumps are ' formed on the bond pads of a printed circuit board. 9. A method of Claim 4 wherein the electrically conductive bumps are formed on bond pads that are arranged in a peripheral pattern on the substrate. 10. A method of Claim 4 wherein the electrically conductive bumps are formed on bond pads that are arranged in a staggered pattern on the substrate. 11. A method of Claim 4 wherein the electrically conductive bumps are formed in bond pads that are arranged in a array on the substrate. 12. A method of Claim 4 wherein the average distance between bond pads of the first portion and bond pads of the second portion is between about one and six millimeters. 13. A method of Claim 4 wherein thermoplastic electrically conductive polymer bumps are formed on the bond pads. 14. A method of Claim 4 wherein the B-stage polymer electrically conductive bumps are formed on the bond pads. 15. A method of Claim 4 wherein thermoset electrically conductive polymer bumps are formed on the bonds pads. 16. A method of Claim 4 further including the step of forming an organic protective layer over a surface of the substrate. 17. A method of Claim 4 further including the steps of aligning the electrically conductive bumps with the bond pads of a second substrate and then contacting the electrically conductive polymer bumps with the bond pads of said second substrate, thereby forming electrical interconnections between said substrates. 18. A method of claim 4 further including the steps of selectively forming an organic protective layer on a second substrate exposed, and then contacting the electrically conductive polymer bumps with the bond pads of said second substrate, thereby forming electrical interconnections between said substrates. 19. A method of Claim 18 wherein the organic protective layer is selectively formed by coating the second substrate with the organic protective layer and then removing portions of the organic protective layer which cover the bond pads of said second substrate. 20. A method of Claim 19 wherein the portions of the organic protective layer which cover the bond pads are removed by laser ablation. 21. A method of selectively forming an organic protective layer on substrate, comprising the steps of: a) layer; and b) removing portions of the organic protective layer which cover bond pads of the substrate. 22. A method of Claim 21 wherein portions of the organic protective layer which cover the bond pads are removed by laser ablation. 23. A method of forming an electrical circuit, comprising the steps of: a) forming electrically conductive bumps on bond pads of a first substrate; b) selectively forming an organic protective layer on a second substrate exposed; and c) contacting the electrically conductive bumps with the bond pads of the second substrate, thereby forming electrically interconnections between said substrate. 24. A method of Claim 23, wherein the electrically conductive bumps are formed on the bond pads of the first substrate by a method comprising the steps of: a) forming an electrically conductive polymer bump on each of a first set of bond pads of the first substrate; and m i BSTITUTE SHEET (RULE 26) b) forming an electrically conductive polymer bump on each of a second set of bond pads of the first substrate. 25. A method of Claim 24 wherein at least one bond pad of said second set is located between at least two bond pads of said second set. 26. A method of Claim 25 wherein the organic protective layer is formed by forming an organic protective coating on the second substrate and then removing the portion of the organic protective layer which covers the bond pads by laser ablation.

Inventors: ESTES RICHARD H, KULESZA FRANK W, ESTES, RICHARD, H., KULESZA, FRANK, W.
Applicants: EPOXY TECHNOLOGY INC, EPOXY TECHNOLOGY, INC.
Application year: 1994
Main classification: H01L21
IPC codes: H01L21, H01L23, H05K1, H05K3