Ink jet print head and a method of manufacturing the same

Abstract: An ink jet printer head includes a spacer (4) including pressure generating chambers (48) continuous to nozzle openings (2), ink supply paths and reservoirs, a cover member for covering the pressure generating chamber (48) in a sealing fashion, and pressure generating means (30) for generating pressure in the pressure generating chambers (48, 201) in accordance with print data. In processing a silicon single-crystal substrate vertically oriented in (110) by anisotropic etching process, one of the walls of a path hole for forming a pressure generating chamber (48) is aligned with one of the walls of a path hole for forming the ink supply path. Walls defining the path hole for forming a pressure generating chamber (48), which are located in the vicinity of a nozzle opening (2), are connected to each other at an obtuse angle. As a result, the ink supply path serving as a narrow path for ink flow and the pressure generating chamber (48) are formed as smooth flow paths. The walls in an area in the vicinity of the nozzle opening (2) where ink tends to stay are substantially equally distanced from the nozzle opening (2). A smooth flow of ink is ensured.

Description: The present invention relates to an ink jet printer head, a method of manufacturing an ink jet printer head and a method of processing a silicon single crystal substrate in use with an ink jet printer head. An ink jet printer head shoots forth ink droplets onto a recording medium to form dots thereon. Print of extremely high resolution is realized if the size of the ink droplets is reduced. For high speed printing, the number of nozzle openings must be increased. Particularly, in the printer head of the type in which piezoelectric vibrating elements are used as an energy source for expelling ink droplets, the pressure generating chamber must be designed to be as large as possible in order to efficiently use the energy of the piezoelectric vibrating element. This requirement for the efficient use of the energy is contradictory to the current tendency of the size reduction of the printer head. Measure currently taken for the contradictory problem is to reduce the thickness of the wall partitioning the adjacent pressure generating chambers, and to enlarge the pressure generating chambers in the longitudinal direction. To form the pressure generating chambers and the reservoirs, path holes are formed in a spacer for setting the vibrator plate and the nozzle plate fixed distance apart. Since the path holes must be formed in conformity with the pressure generating chambers that are extremely small and complicatedly shaped, the etching technique is usually used. A photosensitive resin film is usually used for the spacer. The spacer made of photosensitive resin has a small mechanical strength. The printer head using such a defective spacer suffers from cross talk, deflection, and the like, and attempt to achieve high resolution is accompanied by deterioration of print quality. To cope with this problem, there are some proposals as disclosed USP No. 4312008 and Examined Japanese Patent Publication No. Sho. 58-40509. In the proposals, a silicon single-crystal substrate vertically oriented in (110) is cut out so as to have the thickness suitable for the spacer. Path holes shaped for pressure generating chambers and ink supply paths are formed in the silicon single-crystal substrate by anisotropic etching process. The spacer of the silicon single-crystal substrate has a large mechanical strength. Therefore, the deflection of the whole print head caused by deformation of the piezoelectric vibrating elements is minimized. The walls undergoing etching are substantially vertical to the surface of the spacer. Because of this, the pressure generating chambers can be uniformly formed. This spacer has the following problem, however. The walls formed by the etching are limited in their directions by the crystal face orientation. Therefore, it is difficult to shape the pressure generating chambers ideal for the ink jet printer head. Because of the unsatisfactorily shaped pressure generating chambers, ink tends to stay and to generate bubbles in the pressure generating chambers. The spacer formed of the silicon single-crystal substrate is advantageous in that the pressure generating chambers may be reduced in size, but is disadvantageous in that a mechanical strength of the whole spacer is small. Because of the fragile spacer, it is difficult to handle the spacers in assembling the ink jet printer head. Further, it is difficult to secure a compliance sufficient for effectively utilizing the pressure energy generated by the piezoelectric vibrating elements and the heat generating means. EP 0 479 441 A discloses a method of processing a silicon single-crystal substrate for use with an ink jet printer head, comprising the steps of: forming anisotropic etching protecting patterns made of silicon dioxide, coincident in configuration with patterns for forming path holes in a mirror image manner on an obverse and a reverse side of the silicon single-crystal substrate; and forming the path holes from the obverse and the reverse sides of the silicon single-crystal substrate by anisotropic etching process, wherein the anisotropic etching protecting patterns include anisotropic etching protecting patterns which are positioned at one side of the silicon single-crystal substrate to form a first path hole and a second path hole which is narrower in width than the first path hole and which are aligned with each other, wherein a blade-like etching protecting pattern is formed in parallel with the second path hole while being substantially aligned with a wall of the second path hole. JP 54150127 A discloses an ink jet printer head according to the preamble of claim 1. Problems exist with respect to smooth flow of ink, stay of ink bubbles and excessive adhesive. Accordingly it is an object of the present invention to provide an ink jet printer head dealing with these problems. This object is solved by appended claim 1. It is further an object of the present invention to provide a methode for manufacturing such printer head. This object is solved by providing a methode for processing a silicon single-crystal substrate for use in the above ink jet printer head according to appended claims 11 and 12. Fig. 1 is an exploded vies showing an ink jet printer head according to an embodiment of the present invention; Fig. 2 is a plan view showing a spacer used in the ink jet printer head; Fig. 3 is an enlarged, perspective view showing a portion of a vibrator plate where it is in contact with piezoelectric vibrating elements; Figs. 4(a) and 4(b) are a perspective view and a cross sectional view showing respectively a piezoelectric vibrator unit and the structure of electrodes of the vibrator unit; Fig. 5 is a cross sectional view showing a part of the ink jet printer head; Fig. 6 is an enlarged, cross sectional view showing pressure generating chambers and their related portions of the ink jet printer head; Figs. 7(a) and 7(b) are enlarged, plan views showing the pressure generating chambers and their related portions of the spacer in the ink jet printer head, the illustration showing a positional relationship among nozzle openings, islands, and piezoelectric vibrating elements when the nozzle plate, the vibrator plate, and the piezoelectric vibrating element are fastened; Fig. 8 is an enlarged view showing the configuration of a path hole forming the pressure generating chamber; Figs. 9 (a) to (e) are diagrams showing a sequence of steps of manufacturing a spacer by processing a silicon single-crystal substrate vertically oriented in (110) by anisotropic etching process; Fig. 10 is an explanation diagram for explaining a state of etching as the result of a misalignment of etching patterns formed on the obverse and the reverse side of the silicon single-crystal substrate, which are used for etching the surface of the substrate vertically oriented in (110) by anisotropic etching process; Fig. 11 is an explanatory diagram for explaining a progress of etching process when the silicon single-crystal substrate vertically oriented in (110) is etched by anisotropic etching process; Figs. 12(a) and 12(b) are diagrams showing an example of patterns to form a spacer by etching the silicon single-crystal substrate by anisotropic etching process, and a state of the structure immediately before the etching process ends; Fig. 13 is an enlarged, plan view showing etching patterns of the reservoirs in the structure for supplying ink from one reservoir to two pressure generating chambers; Figs. 14a and 14b are diagrams showing another pattern for the anisotropic etching, the illustration showing a state of etching immediately before the etching ends; Fig. 15 is an enlarged, plan view showing another etching pattern containing reservoirs in such a structure for supplying ink from one reservoir to two series of pressure generating chambers; Fig. 16 is an enlarged, cross sectional view showing a portion of the path hole forming the pressure generating chamber in the vicinity of the nozzle opening; Fig. 17 is a view showing another path hole forming the pressure generating chamber; Fig. 18 is a view showing yet another path hole forming the pressure generating chamber; Fig. 19 is a view showing still another path hole forming the pressure generating chamber; Fig. 20 is an enlarged, cross sectional view showing a portion of the path hole forming the pressure generating chamber in the vicinity of the nozzle opening; Fig. 21 is a view showing a further path hole forming the pressure generating chamber; Fig. 22a is a plan view showing the structure of another spacer; Fig. 22b is a plan view showing a positional relationship of the nozzle openings, islands, and piezoelectric vibrating elements when the nozzle plate, the vibrator plate, and the piezoelectric vibrating elements are mounted on the spacer; Fig. 23 is a view showing an additional path hole forming the pressure generating chamber; Fig. 24 is a cross sectional view showing the cross sectional shape of a bridge; Figs. 25 and 26 are views of exemplary etching patterns formed on the obverse and the reverse side of the silicon single-crystal substrate to form the path holes; Figs. 27 (a) to (d) and 28 (a) to (d) are a cross sectional view and a plan view showing a progressive state of the etching that is carried out using the above etching patterns; Fig. 29 is a plan view showing another path hole forming the pressure generating chamber; Figs. 30a and 30b are plan views showing other spacers used for the ink jet printer head according to the present invention; Fig. 31 is a graph showing a curve representative of defective-discharge occurrence rate vs. the width w of the partition wall; Fig. 32 is a perspective view, partly in cross section, showing another embodiment of an ink jet printer head according to the present invention; Fig. 33 is a cross sectional view showing the nozzle plate, the pressure generating chambers, and the vibrator plate near the bridge and the nozzle openings; Figs. 34a and 34b are a plan view and a cross sectional view showing an exemplar spacer; Fig. 35 is a diagram schematically showing the structure including a pressure generating chamber, the illustration showing deformation of the chamber partitioning walls when a pressure is applied to the chamber; Figs. 36a and 36b are a plan view and a cross sectional view showing another spacer; Figs. 37a and 37b are plan views showing patterns formed on the obverse and the reverse sides of a spacer formed of a silicon single-crystal substrate when the spacer is processed by anisotropic etching process; Figs. 38 (a) to (f) are views showing a sequence of steps for forming a spacer by anisotropic etching process; Figs. 39a and 39b are cross sectional -views showing slits formed by anisotropic etching process when viewed in the longitudinal direction of the pressure generating chamber; Figs. 40a and 40b are plan views showing another type of patterns formed on the obverse and the reverse side of the silicon single-crystal substrate; Fig. 41 is a cross sectional view showing an additional spacer; Fig. 42 is an enlarged, perspective view showing a key portion of an ink jet printer head according to an additional proposal not according to the present invention; Figs. 43 (a) to (d) are plan views showing a method of manufacturing the spacer of the ink jet printer head according to the proposal; Fig. 44 is an enlarged, perspective view showing a key portion of an ink jet printer head according to a further proposal not according to the present invention; and Fig. 45 is an enlarged, perspective view showing a key portion of an ink jet printer head according to another proposal not according to the present invention. In Fig. 1 showing an embodiment of the present invention, linear opening arrays 3 each consisting of nozzle openings 2 are formed in a nozzle plate 1. These nozzle openings 2 are linearly arrayed at such pitches as to form a print density of 180 DPI. A spacer 4 is sandwiched between a vibrator plate 10 serving as a first cover plate (to be given later) and the nozzle plate 1 as a second cover plate. As shown in Fig. 2, the spacer 4 contains pressure generating chambers, reservoirs, an ink supply port connecting them, and path holes 5, 6, 7, and 8 for forming fluid paths for distributing ink from an ink tank to the reservoirs. A vibrator plate 10 cooperates with the spacer 4 and the nozzle plate 1 to form the pressure generating chambers. As shown in Fig. 3, each of the pressure generating chambers is formed of an island 11 and a thin portion 12. The island 11, in contact with the top of a piezoelectric vibrating element 30 contained in a piezoelectric vibrator unit 21, has such a rigidity as to transmit a displacement of the piezoelectric vibrating element 30 to the possibly largest area. The thin portion 12 is formed in the peripheral area of the island 11. With such a construction, the pressure generating chamber can efficiently be expanded and compressed in accordance with stretching motions of the piezoelectric vibrating element 30. The piezoelectric vibrator units 21 are arranged as shown in Fig. 4(a). The piezoelectric vibrating elements 30 of the piezoelectric vibrator units 21 are arrayed at fixed pitches along the fixing board 31 in a state that the first ends of the piezoelectric vibrating elements 30 are attached to the fixing board 31, while the second ends thereof are free so as to allow the piezoelectric vibrating elements 30 to vibrate in a longitudinal vibration mode. Each piezoelectric vibrating element 30, as shown in Fig. 4(b), is constructed such that piezoelectric vibrating members 32, drive electrodes 33, and common electrodes 34 are alternately layered. The rear ends of the drive electrodes 33, exposed to outside, are connected in parallel by an external drive electrode 35, which is formed by vapor deposition process, for example. The common electrodes 34 are extended to the free end of the piezoelectric vibrating element 30 and connected in parallel by an external common electrode 36 extended to the sides of the piezoelectric vibrating element. The outer major surfaces of the external drive electrodes 35 of the piezoelectric vibrating elements 30 are substantially flush with the fixing board 31. The external common electrodes 36 of the piezoelectric vibrating elements 30 are electrically and physically coupled with electrodes 40 formed on the bottom end faces of dummy vibrating elements 39, which are located on both sides of the array of the piezoelectric vibrating elements 30, by means of a conductive member 38. The electrodes 40, like the external drive electrode 35, are formed on the bottom end faces of the dummy vibrating elements 39, and are to be coupled with a connection circuit board. Returning to Fig. 1, a print head body 42 includes unit receive holes 43 for receiving piezoelectric vibrator unit 21 in a state that the free ends of the piezoelectric vibrating elements30 are exposed to outside, and an ink supply port 44 for supplying ink from an ink tank to the reservoirs. An assembly of the vibrator plate 10, the spacer 4, and the nozzle plate 1 is firmly attached to the surface of the print head body 42 by means of a frame member 45, which also serves as an electrostatic shield. The resultant is a record head assembly. Fig. 5 is a cross sectional view of the record head assembly thus constructed when viewed in the direction vertical to the nozzle array. The piezoelectric vibrator units 21 are fastened to the print head body 42 by epoxy resin. Reference numeral 46 of Fig.1 designates an inflow port connecting to the ink tank. In the construction of the record head shown in Fig. 1, the path holes 5 of the spacer, as shown in Fig. 6, are closed by the nozzle plate 1 and the vibrator plate 10, thereby forming pressure generating chambers designated by reference numeral 48. When the thin portion 12 of the vibrator plate 10, which receives a stretching motion of the piezoelectric vibrating element 30 through the island 11, is deformed to compress the pressure generating chamber 48, the pressure generating chamber 48 pushes ink contained therein to exterior in the form of ink droplets through the nozzle opening 2. Figs. 7(a) and 7(b) are enlarged, plan views showing the path holes 5, which form the pressure generating chambers, and their related portions of the spacer 4 in the ink jet printer head. Path holes 5 to serve as pressure generating chambers 48, path holes 6 to serve as reservoirs, and path holes 7 to serve as ink supply ports are formed in a silicon single-crystal substrate vertically oriented in (110). The silicon single-crystal substrate has the thickness necessary for the spacer, e.g., 220 µm. The path holes 7 to serve as ink supply ports are each designed such that the walls 7a and 7b defining the path hole 7 are spaced apart from each other such a distance as to gain a flow path resistance suitable for the ink supply path, and that the wall 7a of the path hole 7 is aligned with a wall 5a of the path hole 5 forming the pressure generating chamber 48. In a case where the vibrator plate 10 is bonded to the nozzle plate 1 by adhesive, indentations 50 for receiving adhesive are formed around those path holes by anisotropic etching process. The indentation 50 is approximately 100 µm or shorter long in one of the sides thereof. The depth of the indentation 50 is selected so as to have such a volume as to contain excessive adhesive. An opening area of the indentation 50 is preferably within a range between 0.001 mm 2 and 0.01 mm 2 . When it is smaller than 0.001 mm 2 , the indentation 50 can unsatisfactorily receive the excessive adhesive. When it is larger than 0.01 mm 2 , an unsatisfactory adhesion area is secured, weakening the adhesion of the vibrator plate 10 to the nozzle plate 1. In a proposal not according to the invention, when an eutectic jointing method, not using adhesive, is used, there is no need of using these indentations 50, as a matter of course. Fig. 8 illustrates a path hole forming a pressure generating chamber 48 and a path hole forming an ink supply path, and angles of the walls of these path holes. The path hole 5 forming the pressure generating chamber 48 includes seven walls 5a to 5g. The walls 5b, 5f, 5g, and 5a around the nozzle opening 2 are jointed at angles 3, 4, and 5. The angles 3, 4, and 5 are obtuse angles of approximately 152°, 100°, and 110°, respectively. The walls 5c, 5d, and 5e of the path hole 5, located adjoining to the path hole 7 to serve as the ink supply path, are arranged so as to gradually enlarge a junction area where the ink supply path opens to the pressure generating chamber. The wall 7a of the path hole 7 for the ink supply path is formed so as to be continuous to the wall 5a of the path hole 5 for the pressure generating chamber. The wall 7b of the path hole 7 is spaced apart from the wall 7b and arranged in parallel with the latter. The distance between them is selected to such an extent as to gain a flow path resistance suitable for the ink supply path. The wall 7a of the path hole 7, which straightforwardly extends from the pressure generating chambers to the ink supply path, is connected to the wall 6a of the path hole 6 for the reservoir by way of an enlarged junction part defined by the two walls 6b and 6c of the path holes 6. In the figure, an angle 1 is 30°, and an angle 2 is approximately 70°. To assemble, adhesive is applied to the spacer 4 thus structured, and sandwiched by the nozzle plate 1 and the vibrator plate 10 after these are accurately positioned to one another, and the assembly of those components is pressed together. Adhesive not used for bonding them flows into the indentations 50 located around the path holes 5, 6 and 7 respectively for the pressure generating chambers, the ink supply paths, and the reservoirs. As a result, such a disadvantageous situation that adhesive flows into the pressure generating chambers, the ink supply paths, and the reservoirs, thereby changing the volumes of them, will never occur. In the resultant structure produced after completion of the bonding process, each nozzle opening 2 of the nozzle plate 1 is located near at the end of a center line of the path hole 5 to serve as the pressure generating chamber, and each island 11 of the spacer 4 is extended over the substantially entire length of the pressure generating chamber. When the piezoelectric vibrating element 30 is driven in this state, the displacement of the element is transferred to the whole pressure generating chamber by way of the island 11. Therefore, the displacement of the piezoelectric vibrating element 30 can be highly efficiently transformed into a variation of the volume of the pressure generating chamber. In Figs. 9(a) to (e) show a sequence of steps for manufacturing the spacer 4 wherein a silicon single-crystal substrate 60 of the crystallographic axis (110), 220 µm thick (enough to satisfy the thickness required for the spacer), for example, is prepared. A silicon dioxide film 61 which is 1 µm thick, for example, is formed on the surface of the silicon single-crystal substrate 60 by thermal oxidation process. The thickness of 1 µm is sufficient for the film 61 functioning as a protecting film against an anisotropic etching liquid (Fig. 9(a)). A hydrogen fluoride protecting film 62 is formed on the obverse and the reverse side of the silicon single-crystal substrate 60 with the silicon dioxide film 61 formed thereon by a lithography method. The protecting film 62 formed on the substrate includes windows 63 and 64 corresponding to the path holes 5, 6, and 7, and if necessary, the indentations 50 (Fig. 9(b)). In this state, the structure is etched using a hydrogen fluoride liquid, so that the portions of the silicon dioxide film 61 corresponding to the windows for the path holes 5, 6, and 7, and the indentations 50 are etched away (Fig. 9(c)). Patterns 61a and 61b of the silicon dioxide formed on the obverse and the reverse side of the substrate are somewhat different in size from each other so that the pattern 61a on the obverse side covers the pattern 61b on the reverse side, in this instance. Following the step of forming the silicon dioxide patterns, the structure is etched in an aqueous solution of potassium hydroxide of approximately 17 % in density, kept at a fixed temperature, for example, 80°C. In the etching process, only the portions of the silicon dioxide film corresponding to the windows 63 and 64 are etched away at the rate of 2 µm/min., with the patterns 61a and 61b of the silicon dioxide film as protecting films. In this case, the etching progresses from both sides of the substrate at an angle of approximately 35° to the surface of the substrate, viz., in the direction vertical to the crystallographic axis (111). As described above, the patterns 61a and 61b formed on the obverse the and reverse side of the silicon single-crystal substrate 60 are formed so that the pattern 61a covers the pattern 61b. At the time of completing the etching process, a path hole 65 is formed which corresponds in size to the patterns 61b defining the larger window (Fig. 9(d)). Even if a slight misalignment of the patterns on the obverse and the reverse side of the substrate is caused, the etching size can be controlled through by adjusting the positions of the patterns defining the larger window since at least the edges of the patterns located outside are the etching surfaces. Let us consider a case where patterns 70 and 71 of the same size are formed on the obverse and the reverse side of a substrate 72, as shown in Fig. 10. In this case, if these patterns are not aligned with each other, walls 72a and 72b are formed in line with the boundaries of the patterns 70a and 71a located outside a path hole 73 to be formed within the patterns oppositely formed on the obverse and the reverse side of the substrate. The size of the path hole 73 formed by this etching process is different from that of a path hole defined by the patterns 70 and 71. As a result, it is impossible to control the size of the path holes and the positions of the etching faces. After the path hole 65 is formed, the silicon dioxide films 61a and 61b used as a mask are removed by using hydrogen fluoride. Thereafter, the structure is thermally oxidized to form a silicon dioxide film 66 of a thickness of 1 µm for example, (this figure indicates a film thickness satisfactory for the protecting film) over the entire exposed surface thereof. This silicon dioxide film 66 is used as a protecting film against ink (Fig. 9(e)). During the course of the anisotropic etching process of the silicon single-crystal substrate vertically oriented in (110) till an intended pattern is formed, the etching progresses at an angle of approximately 35° to the face vertically oriented in (110), viz., along the face vertically oriented in (111) as shown in Fig. 11. In order to actively use this nature, as shown in Fig. 12(a), an approximately 1/2 region of the path hole 5 for the pressure generating chamber where it faces the nozzle opening is formed such that a boundary 80a of an etching pattern 80 defining the wall of the path hole is deviated toward the wall 5a thereof. A blade-like pattern 81, extended to the path hole 5, is formed on the wall 7b of the path hole 7 for the ink supply path. The wall 7b of the path hole 7 is opposed to the wall 7a thereof, which is in line with the wall 5a of the path hole 5. Further, blade-like patterns 82 and 83 are formed on the inner sides of the path hole 6 for the reservoir in a state that these patterns extend in line with the walls 7a and 7b of the ink supply path 7, respectively. During the anisotropic etching process that is carried out using the etching patterns thus formed, in the stage of forming the path hole 5, the etching progresses on the edge 80b of the etching pattern 80 at a given angle to the wall 5b of the path hole because the etching pattern 80 includes the edge 80b. The etching progresses to reach the region facing the nozzle opening, so that the nozzle opening 2, and the walls 5a, 5b, 5f, and 5g facing the nozzle opening, which are arrayed at obtuse angles, are formed. At the junction part between the ink supply path and the pressure generating chamber and another junction part between the ink supply path and the reservoir, the etching is stopped when these junction parts are expanded to such an extent as to prevent ink from staying the inlet and outlet of the ink supply path as a narrow path for ink flow. With this, a fluid resistance proper for the ink supply path is secured. In the stage of etching the path hole 7 for the ink supply path, the blade-like patterns 81, 82, and 83, the ends of which are extended from the walls, are first etched (Fig. 12(b)). Accordingly, in the final etching stage, viz., an etching stage where a through-hole is formed through the etching from both sides and intended patterns are formed, walls 5d and 5e, slanted at the angle 1 30° to the walls 5c and 7b, are formed in the region or the junction part of the path hole 7 where it opens to the pressure generating chamber. Further, walls 6b and 6c, slanted at the angle 2 70° to the walls 6a and 7a, are formed in the junction part of the path hole 7 where it opens to the reservoir as shown in Fig.8. As a result the inlet and the outlet of the ink supply path are expanded in diameter. With this expanded openings, ink smoothly flows into the pressure generating chamber, from the reservoir, without generating bubbles of ink. Fig. 13 is an enlarged, plan view showing etching patterns of the reservoirs in the structure of the path holes 6 for the reservoirs, in which ink is supplied from one reservoir to two series of the pressure generating chambers. In this structure, the nozzles of the series of the pressure generating chambers are slightly dislocated from one another. Therefore, blade-like patterns 82, 83, 82', and 83', which are extended from the path holes 7 and 7' to serve as ink supply paths to the pressure generating chambers, little lap. Figs. 14a and 14b are diagrams showing another pattern for the anisotropic etching. In this pattern, a junction part of the path hole 7 to serve as an ink supply path and the path hole 6 to serve as a reservoir is formed as a narrow continuous pattern 85. A single blade-like pattern 86 is extended in the axial direction of the path hole 7 to serve as the ink supply path. In this pattern, the junction part of the ink supply path 7 and the path hole 6 for the reservoir is blocked by the narrow continuous pattern 85. Therefore, an unnecessary progression of the etching can be stopped by only one blade-like pattern 86. In a case where ink is supplied from one reservoir to two series of the pressure generating chambers as in Fig. 13, the object can be achieved by forming narrow continuous patterns 85 and 85' near to the ends of the path holes 7 and 7' for the ink supply paths and forming blade-like patterns 86 and 86' extending from the narrow continuous patterns in alignment with the path holes 7 and 7', as shown in Fig. 15. Therefore, if these are displaced from the nozzle positions of the nozzle series, the blade-like patterns 86 and 86' may be laid out in a plane without lapping them. In the above-mentioned embodiment, the etching process is stopped when the wall 5f comes in contact with the wall 5g. However, if the etching process is further continued, two walls 5f1 and 5f2 are additionally formed on the wall 5f, and the wall 5f is incurved in shape, as shown in Fig. 16. As a result, an additional wall 5h is grown, which is slanted at an angle 8 = 152° to the wall 5b defining the pressure generating chamber 48, as shown in Fig. 17. An angle 7 is approximately 125°. An angle 6 of the wall 5f1 (wall 5f2) to the surface of the spacer 4 is approximately 35°. As the result of the etching process, a total of seven walls are formed around the nozzle opening 2. These walls are five walls 5a, 5g, 5f, 5h, and 5b arranged at obtuse angles in plan and standing up at a right angle to the surface of the silicon single-crystal substrate, and two walls 5f1 and 5f2 connecting to the wall 5f at the angle 6 as viewed in the cross sectional direction of the silicon single-crystal substrate. With this structure, a more smoothly flow of ink is secured in the vicinity of the nozzle opening 2. Accordingly, stay of bubbles never happens. As in the embodiment where the four walls are formed around the nozzle opening 2, a path hole 92 for an ink supply path, which connects a path hole 90 for a pressure generating chamber to a path hole 91 for a reservoir, may be formed such that walls 90c and 90d are formed which are obliquely extended from the longitudinal walls 90a and 90b defining the pressure generating chamber, and the path hole 92 is located substantially in alignment with the center line of the pressure generating chamber (Fig. 18 showing a proposal not according to the invention). With this structure, ink is supplied from the reservoir to the pressure generating chamber by way of an outlet of the ink supply path, which is defined by the walls 90c and 90d outwardly expanded from the locations near to the center of the end of the chamber toward the pressure generating chamber, and walls 90e and 90f secondarily formed along the crystal axis during the etching process. Ink flows from the reservoir to the pressure generating chamber more smoothly, without any stay of ink bubbles. After the wall 5h is formed, the etching process is further continued. Then, the etching of the wall 5f selectively progresses. The end of the wall 5f closer to the wall 5b grows, so that the wall 5g formed in the previous step disappears. As a result, as shown in Figs. 19 and 20, six walls 5a, 5g, 5f', 5f1', 5f2', and 5b, which are arranged at obtuse angles in plan and standing up at a right angle to the surface of the silicon single-crystal substrate, are formed around the nozzle opening 2. Ink smoothly flows in the vicinity of the nozzle opening 2, and ink bubbles never stay there. As in the previous case, a path hole 92 for an ink supply path, which connects a path hole 90 for a pressure generating chamber to a path hole 91 for a reservoir, may be formed such that walls 90c and 90d are formed which are obliquely extended from the longitudinal walls 90a and 90b defining the pressure generating chamber, and the path hole 92 is located substantially in alignment with the center line of the pressure generating chamber (Fig. 21 showing a proposal not according to the invention). With this structure, ink is supplied from the reservoir to the pressure generating chamber by way of an outlet of the ink supply path, which is defined by the walls 90c and 90d outwardly expanded from the locations near to the center of the end of the chamber toward the pressure generating chamber, and walls 90e and 90f secondarily formed along the crystal axis during the etching process. Ink flows from the reservoir to the pressure generating chamber more smoothly, without any stay of ink bubbles. The above-mentioned spacer has such a structure that the path holes 5 for the pressure generating chambers the path holes 7 for the ink supply paths and the path holes 6 for the reservoirs are formed in the thin silicon single-crystal substrate of approximately 220 µm thick. In this structure, the substrate is segmented at locations near the path holes for the pressure generating chambers. Accordingly, the upper side of the substrate is easily slid against the lower side thereof and vice versa. With this structure, when the spacer is inserted between the nozzle plate 1 and the vibrator plate 10, and those members are bonded together, those path holes 5 and 7 are frequently deformed. In other words, the walls defining the pressure generating chambers are extended in a cantilever fashion. When the spacer is bonded to other related members, the walls are easily bent. If the walls are bent, the path holes 7 for the ink supply paths are deformed. Fig. 22a is a plan view showing the structure of a spacer which withstands the deformation of the path holes for the pressure generating chamber 48 and the path holes 7 for the ink supply paths. This undeformable structure is applied for the above-mentioned spacer structure of the type in which seven walls are formed around the nozzle opening 2. Fig. 22b is a plan view showing relative positions of the pressure generating chamber 48, the nozzle opening 2, and piezoelectric vibrating elements 30 of the spacer. Fig. 23 is an enlarged view showing the configuration of a path hole forming the pressure generating chamber and its related portions. As shown, a path hole 5 forming a pressure generating chamber 48, a path hole 6 forming a reservoir, and a path hole 7 forming an ink supply path are formed in a silicon single-crystal substrate vertically oriented in (110), the thickness of which is sufficient for the spacer, e.g., 220 µm. A bridge 95 is obliquely formed across the path hole 5 at a location closer to the path hole 7. The bridge 95 formed across the path hole is slanted at angles 9 = 126° and 10 = 55° to the walls of the path hole 5, which define the pressure generating chamber. The cross sectional structure of the bridge 95 is shown in Fig. 24. As shown, it is a triangle of which the bottom 95c lies on the side of the substrate to be in contact with the nozzle plate. A slanting surface 95a of the bridge 95 is slanted so as to increase the cross section of the pressure generating chamber toward the nozzle opening 2, and at an angle 11 (about 35°) to the surface of the nozzle plate. Another slanting surface 95b is slanted toward the ink supply path 7 at an angle 12 (approximately 35°) to the nozzle plate. The angle of the bridge 95 at its vertex is an obtuse angle, approximately 110°. Therefore, the bridge 95 causes no vortex of ink in the pressure generating chamber, and hence does not impede the flow of ink therein. The height h of the bridge 95 is selected to be such a value as not to impede the flow of ink and as to secure a satisfactory strength of the bridge. The height of the bridge is preferably 25 % of the thickness t of the spacer. Figs. 25 and 26 are views showing etching patterns suitable for forming the pressure generating chambers with the bridges 95. An etching protecting pattern 96 defining the bottom 95c of the bridge 95 is formed in a location (facing the nozzle opening of the path hole 5) on the etching pattern 80 defining the whole pressure generating chamber. In the portion to serve as a slanting side thereof facing the vibrator plate 10, patterns 99 and 100, which are relatively narrow when compared with the etching protecting pattern 96, are formed in the locations near to the center line of the etching pattern 96. These narrow patterns 99 and 100 are not aligned with each other. An etching protecting pattern 97a, shaped like a blade, is extended on one of the boundaries of the etching protecting pattern 96 in parallel with the wall 5a of the path hole 5 for the pressure generating chamber. An etching protecting pattern 98a, shaped like a blade, is extended from the wall 5c of the path hole 5 toward the path hole 5. The wall 5c faces the wall 7a of the path hole 7 in line with the wall 5a of the path hole 5 for the pressure generating chamber (the wall 7a is one of the walls defining the path hole 7 for the ink supply path). A straight pattern, connected at the central part thereof to the patterns 99 and 100, is horizontally extended. The left side of the straight pattern is designated by reference numeral 97b, while the right side thereof, by numeral 98b. These narrow patterns 97b and 98b, which serve as etching protecting patterns, are located corresponding to the narrow etching protecting patterns 97a and 98a. The silicon single-crystal substrate vertically oriented in (110) with the etching protecting patterns thus formed is etched by the anisotropic etching method. The etching progresses along the (111) face slanted at an angle of approximately 35° to the obverse and the reverse side of the silicon single-crystal substrate, as described above (Fig. 27(a)). In a stage where the etching, which starts from the obverse and the reverse side of the substrate, progresses into the substrate, viz., the etching depth reaches about the half of the thickness of the substrate (Fig. 27(b)), the edge 80b of the etching pattern 80 grows in the direction substantially vertical to the (110) face of the silicon single-crystal substrate (Fig. 27(c)). Thus, the etching vertically progresses up to the end of the etching protecting pattern 96 on the nozzle plate side. In other words, the etching progresses so that the surface of the substrate is left at the angle of about 35°, and progresses till it intersects the etching patterns 99 and 100 on the vibrator plate side (Figs. 27(d) and 28(a)). In Fig. 28, each arrow indicates an inclination of the left surface. Specifically, the left surface is inclined in the direction indicated by the arrow head. For the regions covered with the etching protecting patterns 97a, 98a, 97b, and 98b, the etching progresses in the direction substantially vertical to the obverse and the reverse side of the silicon single-crystal substrate so as to shorten the regions. With these patterns, the etching reaches the boundary of the etching protecting pattern 96. Then, the etching progresses so that the surface slanted at the angle of 35° to the surface of the silicon single-crystal substrate is left, as in the previous case (Fig. 28(b)). The etching reaches the narrow etching protecting patterns 99 and 100, and further progresses. Then, the etching protecting pattern is bifurcated into two patterns. With the bifurcation, the etching advances toward the walls 5a and 5b, while the etching advances in the same direction as that of the etching protecting patterns 97a, 97b, 98a, and 98b (Fig. 28(c)). As recalled, the narrow etching protecting patterns 99 and 100, which form the ridge of the bridge triangular in cross section, are not aligned with each other. Accordingly, an edge part where the (111) faces intersect is formed, thereby preventing the formation of a vertical wall. If the etching protecting patterns 99 and 100 are aligned with each other, a wall of which the crystal face of (111) is vertical which resembles in shape the etching protecting patterns 99 and 100 is formed. This wall segments the pressure generating chamber into two sections. After the etching protecting patterns 99 and 100, which are formed on the vibrator plate side, disappear, the etching is further continued. Then, a bridge 95 is formed in which the slanting surfaces 95a and 95b of the (111) faces, slanted at about 35°, intersect when viewed in cross section. If the etching process is further continued, the ridge of the bridge is etched to be flat. However, the etching process is stopped when the regions around the nozzle opening and the ink supply path are shaped as intended. Accordingly, the etching protecting patterns 96, 99, and 100 are determined by the timing of the stop of the etching process. In the above instance, the bridge 95 is formed across the path hole 5 to be the pressure generating chamber 48. If required, it may be formed across the path hole 7 to be the ink supply path, as shown in Fig. 29. As shown, a bridge 102 triangular in cross section is formed across the path hole 7. A method similar to that used for forming the bridge 95 may be used for forming the bridge 102. Also in this instance of the embodiment, the walls 7a and 7b of the path hole 7 are supported by the bridge 102. Because of this structure, the width size of the path hole 5 and the path hole 7 can be maintained throughout the assembling stage. The spacer 4 made of the silicon single-crystal substrate is very thin, approximately 220 µm thick. Because of this, the mechanical strength of the spacer, particularly a specific region of the spacer, is weak. The spacer 4 contains large spaces, such as pressure generating chambers 48 and the reservoirs. In this sense, the spacer 4 consists of a main area 4a and a peripheral area 4b (Fig. 30). The main area 4a includes a plural number of the path holes 5 for the pressure generating chambers 48. The peripheral area 4b includes a plural number of the path holes 6 for the reservoirs in association with the path holes 5. In each of these large spaces, the major surfaces of the large space, or the upper or the lower sides, which define the large space, are supported in a cantilever fashion. Therefore, a boundary region between the main area 4a and the peripheral area 4b is mechanically fragile. To cope with this, the present embodiment uses reinforcing means for reinforcing this fragile region. The reinforcing means is realized in the form of a partition wall 105 formed between the main area 4a and the peripheral area 4b in the vicinity of the ink supply path 104, which receives ink from an external ink tank (Fig. 30(a). The partition wall 105 is slanted at an angle  (70.5°) with respect to the vertical line in the drawing. The partition wall 105 may be formed in a previous manner. The partition wall 105 is bridged between the walls of the path holes 6 or the ink supply path 104, while traversing the ink supply path 104. It is obstructive in the flow of ink from the ink tank to the reservoir. Therefore, after an old ink cartridge is exchanged with a new one, the problem of a defective ink discharge may arise highly possibly. However, this problem can be solved by properly selecting the width W of the partition wall 105 as seen from a graph of Fig. 31 showing a curve representative of defective-discharge occurrence rate vs. the width of the partition wall. As seen from Fig. 31, the defective-discharge occurrence rate abruptly increases when the width W of the partition wall 105 exceeds 80 µm. For the spacer of 180 to 200 µm, if the width W of the partition wall 105 is selected to be approximately 20 µm, a satisfactory mechanical strength of the boundary region of the spacer can be secured and the defective-discharge problem can be solved. Accordingly, it is suggestible to select the width W of the partition wall 105 to be within 20 to 80 µm. The reinforcing means may be modified as shown in Fig. 30(b). In the modification, another partition wall 105b crosses the partition wall 105 (denoted as 105a in this instance) at the central part of the ink supply path 104. This modified reinforcing means prevents poor bonding that is possibly caused by a bending of the vibrator plate 10 in a part thereof near the ink supply path 104 when the nozzle plate 1, the spacer 4, and the vibrator plate 10 are assembled and bonded together, and are fastened to the print head body 42. Accordingly, no ink is leaked into the piezoelectric vibrating members 32, and a normal operation of the piezoelectric vibrating members 32 is ensured. The partition wall 105b includes the surfaces in parallel with the walls 5a and 5b of the path hole 5. The width W' of the partition wall 105b is selected to preferably be 20 to 80 µm, as seen from Fig. 31. The length L1 of the partition wall 105b where it is connected to the vibrator plate 10 is preferably the thickness of the spacer 4 or larger. More than three partition walls may be formed in consideration of the defective-discharge problem, and others. An ink jet printer head according to a second embodiment of the present invention will be described with reference to Figs. 32 and 33. As shown, in the ink jet printer head, pressure generating chambers 48 are partitioned by unique chamber partitioning means. The chamber partitioning means consists of a narrow space 110 defined by a couple of very thin partition walls 111 and 112. A spacer used for the ink jet printer head is illustrated in Figs. 34a and 34b. As shown, the narrow spaces 110 partitioning the pressure generating chambers 48 take the form of slits 114. Each slit 114 is extended from the ink supply path 7 to a location beyond the nozzle opening 2. In the embodiment, the partition walls 111 and 112 of the chamber partitioning means are 15 µm thick. The partition walls 111 and 112 have such a thickness as to allow these walls to be resiliently deformable when the walls receive a pressure caused when a pressure is applied to ink for ink discharge. A slanted bridge 95, triangular in cross section, traverses each pressure generating chamber 48 in a state that it connects the partition walls 111 and 112 of the adjacent chamber partitioning means, as shown. The bridge 95 is located at the central part of each pressure generating chamber 48 when viewed in the longitudinal direction of the chamber. The bridge 95 is located on the side of the spacer 4, closer to the nozzle plate 1, and spaced from the vibrator plate 10 at a fixed distance. provision of the bridge 95 is not obstructive in the flow of ink within the pressure generating chamber 48. The thickness of the bridge 95 is selected to such an extent as to prevent the partition walls 111 and 112 from falling toward the narrow space 110 or the pressure generating chamber 48. In this embodiment, the height from the base of the triangle (of the cross section of the bridge 95) to the vertex is approximately 70 µm. In the ink jet printer head thus constructed, the piezoelectric vibrating elements 30, which vibrate in a longitudinal vibration mode, are fastened at the first ends of the pressure generating chambers 48 and attached at the second ends thereof to the islands 11 of the vibrator plate 10. Drive signals based on print data are applied to the print head. In response to the drive signals, the piezoelectric vibrating elements 30 longitudinally expand to compress the pressure generating chambers 48 to cause pressure in the chambers. The pressure generated expands the pressure generating chamber 48, thereby bending the partition walls 111 and 112 toward the narrow spaces 110 and the vibrator plate 10 outward, and causing ink to shoot forth through the nozzle opening 2. The narrow spaces 110 of the chamber partitioning means, which partition the pressure generating chambers 48, absorb the deformation of the partition walls 111 and 112 defining the narrow spaces 110, thereby blocking the transfer of the displacement of the partition walls 111 and 112 to the adjacent pressure generating chambers 48. Provision of the narrow spaces 110 effectively prevents the cross talk. In Figs. 36a and 36b, there is shown another spacer adaptable for the second embodiment of the ink jet printer head. As shown, in this spacer, a second slit 115 is formed which extends in the direction of the array of the nozzle openings 2. The second slit 115 is continuous to the slits 114 as the narrow spaces 110 and opened at the opening 115a to the air. With this structure, the narrow spaces 110 are not closed by the nozzle plate 1 and the vibrator plate 10. Accordingly, the partition walls 111 and 112 are undeformable under ambient temperature variation. In this instance of the embodiment, the narrow spaces 110 defined by the partition walls 111 and 112 are connected to the second slit 115 located at one end of the spacer 4. If required, these narrow spaces 110 or the slits 114 may directly be opened to the air at both ends of the spacer individually. Figs. 37a and 37b are plan views showing etching patterns for manufacturing the spacer 4 structured as mentioned above by etching a silicon single-crystal substrate of the crystallographic axis (110) by an anisotropic etching method. Fig. 37a shows an etching pattern on the side of the silicon single-crystal substrate on which the bridge 95 is formed, and Fig. 37b shows an etching pattern on the side thereof on which a space is provided above the bridge 95 so as to secure the free flow of ink in the pressure generating chamber 48. In Figs. 37a and 37b, the hatched areas indicate etching protecting films. In Fig. 37a, reference numerals 120a and 120b indicate windows for defining etching areas to secure spaces for the pressure generating chambers 48 on one side of the silicon single-crystal substrate. In Fig. 37b, reference numerals 120c and 120d also indicate windows for defining etching areas to secure spaces for the pressure generating chambers 48 on the other side of the silicon single-crystal substrate. A protecting film 121a for protecting an area corresponding to the bridge 95 against the etching is formed between the windows 120a and 120b. A small protecting film 121b for resisting the etching to a certain degree is formed in the etching pattern on the other side of the silicon single-crystal substrate. Narrow windows 122a and 122b are formed in the etching pattern on the nozzle opening side of the silicon single-crystal substrate (Fig. 37a). The narrow windows 122a and 122b ranges between the windows 120a and 120b for forming the slits 114 each defined by the partition walls 111 and 112. Windows 123a and 123b for the path holes 6 of the reservoirs are formed closer to the ink supply paths to the pressure generating chambers. The windows 123a and 123b are connected to the windows 120b and 120d for forming the pressure generating chambers 48 by narrow windows 124a and 124b, respectively. These narrow windows 124a and 124b are for etching the path holes 7 for the ink supply paths. Etching protecting patterns 125 are used for checking the progress of an excessive etching into relatively narrow spaces, which is caused by the edging effect in the anisotropic etching process. Of those windows 120a to 120d for the pressure generating chambers, the windows 120a and 120b on one side of the silicon single-crystal substrate (Fig. 37a) are larger than the windows 120c and 120d on the other side (Fig. 37b) or vice versa. The same thing is correspondingly applied to the windows 124a and 124b. More specifically, the windows 120a, 120b, and 124a on one side of the substrate are about 5 µm larger than those corresponding windows 120c, 120d, and 124b on the other side thereof so that the former windows can cover the latter ones when those windows are erroneously positioned in the stage of printing the etching patterns. An anisotropic etching process will be described. A silicon single-crystal substrate 130 of the crystallographic axis (110), 220 µm thick (enough to satisfy the thickness required for the spacer), for example, is prepared. A silicon dioxide film 131 of 1 µm thick, for example, is formed on the entire surface of the silicon single-crystal substrate 130 by thermal oxidation process. The 1 µm thick of the film 131 is sufficient for the film 131 functioning as a protecting film against an anisotropic etching liquid (Fig. 38(a)). Photo-setting photosensitive layers are formed on the silicon dioxide film 131 on the obverse and the reverse side of the silicon single-crystal substrate 130. After the patterns (Fig. 37a) are positioned on one side of the substrate and the patterns (Fig. 37c) are positioned on the other side thereof, then the structure is exposed to light. Thereafter, the structure is immersed into photolithography liquid. The exposed areas, i.e., the areas in which path holes are to be formed, on the substrate are dissolved to form the windows 133 and 134 since those areas are not hardened (Fig. 38(b)). In this state, the structure is etched using hydrogen fluoride liquid. The silicon dioxide films 131 within the windows 133 and 134 are removed. As described above, the silicon dioxide pattern 131a formed on one side of the substrate covers the silicon dioxide pattern 131b on the other side thereof (Fig. 38(c)). The structure is etched in an aqueous solution of potassium hydroxide of approximately 17 % in density, kept at a fixed temperature, for example, 80°C. In the etching process, only the portions of the silicon dioxide film corresponding to the windows 133 and 134 are etched away at the rate of 2 µm/min., with the patterns 131a and 131b of the silicon dioxide film as protecting films. In this case, the etching progresses from both sides of the substrate at an angle of approximately 35° to the surface of the substrate, viz., in the direction vertical to the crystallographic axis (111). The patterns 131a and 131b formed on the obverse and the reverse side of the silicon single-crystal substrate 130 are sized such that one pattern covers the other patter, viz., the boundary of the etching protecting pattern defining a position of the wall is positioned at a location outside the boundary of the etching protecting pattern that is located against the former etching protecting pattern in a mirror image fashion. Accordingly, at the completion of the etching process, the wall of a formed path hole 135 is defined by the pattern 131b of which the boundary is positioned outside (Fig. 38(d)). For this reason, even if the alignment of the patterns on the obverse and the reverse side of the substrate is not exact, the etching is carried out while being defined by the larger window 134. When anisotropic etching process is carried out using a pattern with only one window 136 (Fig. 38(e)), the etching progresses along a specific crystal axis. As a result, the etching progresses while being defined by the window 136, thereby to form a concavity 138 trapezoidal in cross section on the window-formed side of the structure (Fig. 38(f)). When slits are thus formed by anisotropic etching process using the window 136 that is formed on only one of the sides of the substrate, particularly only the side thereof to be fastened to the nozzle plate 1, each of the resultant slits is shaped trapezoidal in cross section as shown in Fig. 39a. As seen from the figure, the opening area of the slit that faces the vibrator plate 10 is small. Therefore, a large contact area is secured between the spacer and the vibrator plate 10 which receives force from the piezoelectric vibrating members at the time of ink expelling. Further, mechanical strength of the partition walls 111 and 112 is increased on the side of the structure not having the bridges 95 and to be fastened to the vibrator plate 10. In the above-mentioned embodiment, the slit is long enough to cover the full height of the pressure generating chamber. However, the length of the slit may be adjusted in accordance with a compliance required for the pressure generating chamber. If the length of the pressure generating chamber is so selected, the compliance optimal for the ink expelling can be obtained. In the above-mentioned embodiment, the slits 114 are formed from only one side of the spacer or the substrate by etching process. If required, as shown in Figs. 40a and 40b, narrow windows 122a and 122b, and 122c and 122d for forming the slits are formed on the patterns on both sides of the silicon single-crystal substrate. The slits are formed by etching the silicon single-crystal substrate from both sides thereof using the windows. In this case, the opening areas of the top and the bottom end of each slit are equal to each other, as shown in Fig. 39b. When this slit forming method by processing the substrate from both sides thereof by anisotropic etching process is applied for a case where the nozzle openings are arrayed at relatively large pitches, it is easy to obtain the compliance as intended. In the above-mentioned embodiment, the partition walls horizontally defining the pressure generating chamber are uniform in thickness. However, the narrow spaces 110 may be constructed deviated to one pressure generating chamber as shown in Fig. 41. In this case, of the partition walls 111 and 112 horizontally defining the pressure generating chamber, the partition wall 111 takes the charge of the compliance. In the above-mentioned embodiments, the so-called face ink jet printer head in which the nozzle plate, the spacer, and the vibrator plate are stacked one on another, has been discussed. It is evident that the present invention is applied to the spacer of a called edge ink jet printer head in which the nozzle plate, the spacer, and the vibrator plate are stacked one on another, and the nozzle openings are formed in the end faces of the pressure generating chambers (when longitudinally viewed). The spacer made of silicon in which the pressure generating chambers, the spacer, and the reservoirs are formed by the path holes has been described. Another type of the spacer will be described. Fig. 42 is an enlarged, perspective view showing a key portion of an ink jet printer head according to a proposal not according to the present invention. In Fig. 42, a nozzle plate with nozzle openings 210a, a spacer 200, and a vibrator plate 211 are stacked to form ink flow paths. The spacer 200 is made of a silicon single-crystal having the crystal face vertically oriented in (110). Spaces which substantially determine the volumes of the ink flow paths of pressure generating chambers 201, ink supply paths 202, and reservoir 203, are formed by called anisotropic etching process using an etching liquid in which an etching rate depends on the crystal orientation. The surface of each ink path is tempered by a protecting film (not shown) in which impurity atoms are added to silicon by thermally diffusing oxygen atoms, thereby improving the resistance properties of the ink path against ink and the affinity thereof with ink. The protecting film is not essential. When ink used is properly selected or adjusted, there is no need of using the protecting film. The ink supply path,202 is triangular (shaped like V) in cross section, and its volume is smaller than that of the pressure generating chamber 201 contoured rectangularly. Flow resistance of the ink supply path 202 is larger than that of the pressure generating chamber 201, thereby improving the efficiency of forcibly discharging ink droplets. At the time of ink expelling, the quantity of ink flowing into the nozzle 210 is increased, while at the same time the quantity of ink flowing into the reservoir 203 from the ink supply path 202 is decreased. The space to be the pressure generating chamber 201, contoured parallelogram, is enclosed by the (111) faces parallel to the crystal axes <211>. The space to be the ink supply path 202 is defined by the (111) faces slanted parallel to the <110> axis. The space for the ink supply path 202 is located at the acutely angled corner of the parallelogram of the pressure generating chamber 201, in order to secure a smooth flow of ink and a smooth discharge of ink bubbles. A method of manufacturing the ink jet printer head thus structured will now be described. Figs. 43(a) to 43(d) show a set of diagrams showing a sequence of steps for manufacturing the ink jet printer head. A silicon single-crystal substrate 200 in which the crystal face of the surface of the substrate is vertically oriented in (110), is heated at 900 to 1100 °C , and placed in high temperature gas of oxidizing agent, such as oxygen or aqueous vapor, thereby diffusing oxygen atoms in the surface region of the substrate. In this proposal, through the thermal oxidizing process, a film 230 made of silicon oxide, 1.7 µm thick, was formed. The silicon dioxide film 230 is used as a mask in the step of anisotropic etching process to be given later. Any of other methods than the thermal oxide process, such as CVD (chemical vapor deposition) method, an ion implantation method and anode oxide method, may be used for forming the film 230. The silicon substrate film may be replaced by a silicon nitride film, a called p-type silicon film added with boron or gallium atoms, or a called n-type silicon film added with arsenic or antimony atoms. The thickness of the silicon single-crystal substrate is preferably 0.1 to 0.5 mm, more preferably 0.15 to 0.3 mm. In the present proposal, the silicon single-crystal substrate 200 of a thickness of 0.18 mm was used. Resin resist is applied to the silicon single-crystal substrate, thereby forming a pattern thereon. The silicon oxide film 230 is selectively etched away using acid etching liquid, such as an aqueous solution of fluorine oxide. After the resin resist is removed, a mask pattern of the silicon oxide film 230 that is patterned in the previous process step appears on the substrate as shown in Fig. 43(a). A window 231 is a location for the pressure generating chamber 201. A window 232 is a location for the ink supply path 202. A window 233 is a location for the reservoir 203. The silicon single-crystal substrate 200 is etched by anisotropic etching process, using an etching liquid in which the etching rate varies depending on the crystal face orientation, such as an aqueous solution of sodium hydroxide or an aqueous solution of potassium hydroxide. The anisotropic etching process ends in a state shown in Fig. 43(c) through a state shown in Fig. 43(b). Specifically, the (111) face vertical to the (110) face of the surface of the silicon single-crystal substrate 200 and the (111) face slanted to the same appear in the window 231 after it undergoes the anisotropic etching process. A slanted (111) face appears also in the window. The anisotropic etching process is further continued. Then, the slanted (111) face disappears and a vertical (111) face appears. Through the above process steps, spaces 201a each of which substantially determines the volume of a pressure generating chamber 101, spaces 202a each of which substantially determines the volume of the ink supply path 202, and a space 203a which substantially determines the volume of the reservoir 203 are formed while being partitioned by vertical (111) faces 234. In the present proposal, for the anisotropic etching, the silicon single-crystal substrate 200 was immersed for about 90 minutes in an aqueous solution containing sodium hydroxide of 20 wt. %, kept at 80 °C. The resultant structure was as shown in Fig. 43(c). A partition wall 234a, depending upon the vertical (111) faces, for partitioning the spaces 201a to be the pressure generating chambers 201 and the spaces 202a to be the ink supply paths, and a partition wall 234b for partitioning the spaces 202a to be the ink supply paths and the space 203a to be the reservoir are removed by an isotropic etching liquid, such as an aqueous solution of fluorine oxide. The silicon oxide film 230 is also removed in the etching process using the isotropic etching liquid. The etching rate in this etching process is substantially equal to that in the etching process for the silicon single-crystal substrate 200. Accordingly, the thickness of the partition walls 234 is set at 1.7 µm, equal to that of the silicon oxide film 230. Impact by ultrasonic vibrations, in place of the isotropic etching liquid, may be used for removing the partition walls 234. Then, a protecting film (not shown) is formed for obtaining a desired resistance properties of the ink path against ink and a desired affinity thereof with ink. The type of the protecting film to be formed and the means for forming the protecting film are the same as those in the step for forming the mask pattern 230. It is suggestible to form a silicon oxide film by the thermal oxide process. With provision of the partition walls 234 (234a and 234b) for partitioning the spaces 201a and 202a, there is eliminated an excessive etching at the acutely angled corner of the parallelogram that secondarily occurs in the anisotropic etching process. As a result, the spaces 201a and 202a can be shaped as desired. It is noted that the ink supply paths 202 and the pressure generating chambers 201 are integrated into a single part (silicon single-crystal substrate 200). With this structure, the precise shaping as one of the advantageous features of silicon is well used to provide uniform discharging characteristics of the ink paths and less variation of the product characteristics of lots. Only the (111) faces where the etching rate is low when compared with other crystal faces are left. Accordingly, a tolerable range within which the etching conditions may be varied in the anisotropic etching process is broad. Extremely stable products can be manufactured. Fig. 44 is a perspective view showing a key portion of an ink jet printer head according to yet another proposal not according to the present invention. In this proposal, each pressure generating chamber 201 is provided with a plural number (two in this proposal) of ink supply paths 202. Spaces 202a to be the ink supply paths 202 are respectively located the acutely and obtusely angled corners of the parallelogram of the space 201a to be the pressure generating chamber 201. With this, a smooth flow of ink and a smooth discharge of ink bubbles are ensured. Fig. 45 is a perspective view showing a key portion of an ink jet printer head according to a further proposal not according to the present invention. Spaces 204a which substantially determine the volumes of the nozzle openings are also formed like the spaces 202a of the ink supply paths 202. The nozzle openings 204 are located on a peripheral edge of the silicon single-crystal substrate 200. The ink jet printer head of this embodiment is a so-called edge ink jet printer head. Since a plural number of the nozzle openings 204 are arrayed on one side face of the silicon single-crystal substrate 200, the peripheral edge 200a is finished to be flat by cutting means, such as a rotary grinder. As described above, the plural number of the ink supply paths 202 can stably be manufactured so as to have a desired flow resistance. Those ink supply paths, together with the pressure generating chambers 201, can be formed in the silicon single-crystal substrate 200. Each ink supply path 202 is supported at both ends by the ink supply paths 202 on both sides thereof, and similarly each pressure generating chamber 201 is supported at both ends by the pressure generating chambers 201 on both sides. Therefore, easy handling of the silicon single-crystal substrate 200 after the ink supply paths 202 and the pressure generating chambers 201 are formed therein is realized although the silicon of the silicon single-crystal substrate 200 is fragile.

Claims: An ink jet printer head comprising: spacer (4, 200) including path holes (5, 90) for forming pressure generating chambers (48, 201) continuous to nozzle openings (2, 210a, 204), ink supply paths (104, 202), and reservoirs (203); a cover member (1, 210) for sealingly covering the pressure generating chamber (48, 201); and pressure generating means (30) for generating pressure in the pressure generating chamber (48, 201) in accordance with print data, wherein the spacer (4, 200) includes a vertically oriented {110} silicon single-crystal substrate (60, 72, 130) which is processed by anisotropic etching, characterized in that said spacer (4, 200) is processed in such a manner that one of the walls (5a, 5b) defining the path hole (5) being a through hole and forming the pressure generating chamber (48) is continuously aligned in line to one of the walls (7a, 7b) defining a path hole (7) forming the ink supply path (104, 202), and a plurality of indentations (50) for receiving excessive adhesive are disposed around the path holes (5, 6, 7, 90, 91, 92). The ink jet printer head according to claim 1, wherein an end portion of the path hole (5, 90) forming the pressure generating chamber (48, 201) is defined by four wide walls (5a, 5b, 5f, 5g) connected to one another at obtuse angles. (3, 4, 5). The ink jet printer head according to claim 1 or 2, wherein an end portion of the path hole (5, 90) forming the pressure generating chamber (48, 201) is defined by six wide walls (5a, 5g, 5f', 5f1', 5f2', 5b) connected to one another at obtuse angles (4, 5, 6, 7, 8). The ink jet printer head according to any of the preceding claims, wherein an end portion of the path hole (5, 90) forming the pressure generating chamber (48, 201) is defined by seven wide walls (5a, 5b, 5f, 5g, 5h, 5f1, 5f2) connected to one another at obtuse angles (4, 5, 6, 7, 8). The ink jet printer head according to any of the preceding claims, wherein one of the walls (7a, 7b) defining the end of the path hole (7) for the ink supply path (202) where the path hole (7) is connected to the reservoir (203) consists of two walls (6b, 6c) so that the diameter of the end of the path hole (7) connecting to the reservoir (203) gradually increases toward the reservoir (203). The ink jet printer head according to any of the preceding claims, wherein one of the walls (7a, 7b) defining the end of the path hole (7) for the ink supply path (104, 202) where the path hole is connected to the pressure generating chamber (48) consists of two walls (5d, 5e, 90e, 90f) so that the diameter of the end of the path hole (7) connecting to the pressure generating chamber (48) gradually increases toward the pressure generating chamber (48). The ink jet printer head according to any one of the preceding claims, wherein said indentations are formed by rectangular indentations (50). The ink jet printer head according to claim 7, wherein the opening area of each of the indentations (50) is 0.001 mm 2 to 0.01 mm 2 . The ink jet printer head according to any one of the preceding claims, wherein a film of silicon dioxide (61, 66, 131, 230) is formed on the surface of the spacer (4, 200). The ink jet printer head according to any one of the preceding claims, wherein a bridge means (95, 102) is formed across one or more of the path holes (5, 7, 90, 92) forming the pressure generating chamber (48, 201) and the ink supply path (104, 202) respectively. A method of processing a silicon single-crystal substrate for use with an ink jet printer head as defined in claim 1, comprising the steps of: forming anisotropic etching protecting patterns made of silicon dioxide, coincident in configuration with patterns for forming path holes in a mirror image manner on an obverse and a reverse side of the vertically oriented {110} silicon single-crystal substrate; and forming the path holes from the obverse and the reverse sides of the silicon single-crystal substrate by anisotropic etching process, wherein the anisotropic etching protecting patterns include anisotropic etching protecting patterns which are positioned at one side of the silicon single-crystal substrate to form a first path hole and a second path hole which is narrower in width than the first path hole and which are aligned with each other, wherein a blade-like etching protecting pattern is formed in parallel with the second path hole while being substantially aligned with a wall of the second path hole. A method of processing a silicon single-crystal substrate for use with an ink jet printer head as defined in claim 1, comprising the steps of: forming anisotropic etching protecting patterns made of silicon dioxide, coincident in configuration with patterns for forming path holes in a mirror image manner on an obverse and a reverse side of the vertically oriented {110} silicon single-crystal substrate; and forming the path holes from the obverse and the reverse sides of the silicon single-crystal substrate by anisotropic etching process, wherein the anisotropic etching protecting patterns include anisotropic etching protecting patterns which are positioned at one side of silicon single-crystal substrate to form a first path hole and a second path hole which is narrower in width than the first path hole and which are aligned with each other, wherein a blade-like etching protecting pattern is formed to align with the longitudinal direction of the second hole and which is parallel to the second path hole. The method of processing a silicon single-crystal substrate according to claim 11 or 12, wherein one of the silicon dioxide patterns located in a mirror image fashion is coincident in position with the path hole formed by the etching process, while the other is dislocated to the inner side of the path hole to be formed. The method of processing a silicon single-crystal substrate according to one of claims 11 to 13, wherein an end region requiring a smooth wall in the first path hole is dislocated toward the second wall and an etching protecting pattern with a protruded part is formed thereon. The method of processing a silicon single-crystal substrate according to claim 14, wherein the resultant structure is processed by anisotropic etching process.

Inventors: KAMOI KAZUMI, KATAKURA TAKAHIRO, MOMOSE KAORU, KAMOI, KAZUMI, KATAKURA, TAKAHIRO, MOMOSE, KAORU, Kamoi, Kazumi, Seiko Epson Corp., Katakura, Takahiro, Seiko Epson Corp., Momose, Kaoru, Seiko Epson Corp.
Applicants: SEIKO EPSON CORP, SEIKO EPSON CORPORATION
Application year: 1994
Main classification: B41J2
IPC codes: B41J2