Use of a porous material for the removal of gaseous impurities from a gas mixture

Abstract: Porous, preferably dimensionally stable material for the removal of gaseous impurities from a gas mixture, such as H₂S, COS, CS₂, and SO₂, into the pores of which there is incorporated a secondary amine which chemically bonds with the constituents to be removed, with the material comprising a hydrophobic polymer with pores having an average diameter in the range of 0,1 to 50 µm and a secondary amine having hydrophobic properties which optionally is incorporated into a hydrophobic liquid. Favourable results have been attained using polypropylene as the hydrophobic polymer and ditridecyl amine as the secondary amine, with a tertiary amine, such as C12/C14-alkyl diethanol amine, being part of the hydrophobic liquid.

Description: The invention relates to the use of a porous, preferably dimensionally stable material for the removal of gaseous impurities from a gas mixture, selected from the group of H 2 S, COS, CS 2 , and SO 2 , into the pores of which there is incorporated a secondary amine which chemically bonds with the constituents to be removed. A similar use of porous material incorporating a secondary amine has earlier been described in GB-A-2 049 468. The porous material described in said document comprises mineral carriers which are inert towards secondary amines. Examples of suitable mineral carriers mentioned are pumice, kieselguhr, bauxite, alumina, carbon, or silicates. The particle size preferably is in the range of 0,1 mm to 5 cm. Further, preference is given to particles having an internal porosity of at least 0,1, for example from 0,1 to 0,8. Internal porosity is defined in this case as the ratio of the volume of internal empty space to the actual volume of the particles of solid; internal porosity is measured for example by means of mercury porosimetry. In actual practice, using the known materials is attended with a wide range of problems connected with, on the one hand, the presence of minerals in the carrier material and, on the other, the hydrophilic nature of both the carrier material and the employed amines. The presence of traces of certain metals in carrier material of mineral origin may catalyse the conversion of CS2 and COS into sulphur. A drawback to the use of hydrophilic amines is that it leads also to the bonding of CO 2 . A further drawback consists in that regeneration by means of, e.g, steam stripping, is not readily workable in the case of every gas, for instance in that of CS 2 . The invention now provides for the use of a porous material incorporating in its pores a secondary amine which chemically bonds with the constituents to be removed, which material is easy to regenerate on a commercial scale. The invention consists in that for the material of the known type mentioned in the opening paragraph use is made of a hydrophobic polymer having pores of an average diameter in the range of 0,1 to 50 µm and the secondary amine has hydrophobic properties which optionally is incorporated into a hydrophobic liquid. The average pore diameter is determined with advantage using mercury porosimetry in accordance with ASTM D 4284-83. It must be regarded as extremely surprising that the use of a porous material having both a hydrophobic surface area and an average pore diameter in the indicated range provides a system which can be regenerated by means of, e.g., steam stripping and is so effective as to now render industrial scale use possible. According to the invention, favourable results are generally obtained when use is made of a porous material where at least 15% of the pores is filled with a liquid composed of secondary amine or a secondary amine-containing liquid. Optimum results are commonly obtained when use is made of a material where at least 60% of the pores is filled with a liquid composed of secondary amine or a secondary amine-containing liquid. It has been found that, as a rule, optimum results can be obtained when use is made of a material having an average pore diameter in the range of 0,2 to 15 µm. The secondary amines to be used according to the invention generally have a low vapour pressure, preference being given to amines having a boiling point of at least 250°C. As a rule, favourable results can be obtained when the secondary amine corresponds to the formula R 1 - NH - R 2 , wherein R 1 represents a functionalised or unfunctionalised (ar)aliphatic group with at least 7 carbon atoms and R 2 represents a functionalised or unfunctionalised (ar)alkyl group with at least 3 carbon atoms. Preference is given in this case to secondary amines having a total number of carbon atoms of at least 14. Examples of secondary amines according to the aforementioned formula include dibenzyl amine and ditridecyl amine. Very favourable results are obtained also when use is made of a secondary amine of the formula R 3 - NH - R 4 - NH-C(O)O - R 5 , wherein R 3 represents a functionalised or unfunctionalised (ar)aliphatic group with at least 7 carbon atoms, R 4 represents a functionalised or unfunctionalised alkylene group with at least 2 carbon atoms, and R 5 represents a substituted or unsubstituted alkyl group with at least 2 carbon atoms. These compounds can be obtained by blocking the primary amino group of a compound having a primary as well as a secondary amino group. As examples of suitable blocking agents may be mentioned ethylene carbonate and propylene carbonate. In said formula R 3 preferably is a coco- or C 12 /C 14 -alkyl group, R 4 is an alkylene group with 2 to 6, preferably with 2 or 3 carbon atoms, and R 5 is a hydroxyalkyl group with 2 or 3 carbon atoms. Alternatively, it is possible to achieve favourable results by using a secondary amine obtained by converting an alkyl amine with an alkyl(meth)acrylate. As an example of such a compound may be mentioned the reaction product of oleyl amine and butyl acrylate. While the hydrophobic secondary amine may be incorporated into the pores of the hydrophobic polymer as such, preference is given to material where the secondary amine is dissolved in a hydrophobic liquid. If a regeneratable absorption system is required, the secondary amine and the hydrophobic liquid must both have high thermal, hydrolytic, oxidative, and chemical stability. The glycerol esters of one or more, preferably unsaturated fatty acids may be indicated as examples of a hydrophobic liquid essentially suitable to be used according to the invention, with preference being given to an oil, e.g., palm oil, olive oil, groundnut oil, paraffin oil, fish oil such as herring oil, linseed oil, and, more particularly, soybean oil and/or castor oil. In general, the use of a hydrophobic liquid having one or more tertiary amino groups will be preferred, favourable results being obtained using an alkyl dialkanol amine, more particularly an alkyl diethanol amine, more particularly still a C 12 /C 14 -alkyl diethanol amine. Preferably, the equivalency ratio of secondary amino groups to tertiary amino groups is ≤ 1. The process of preparing from hydrophobic polymers a porous, preferably dimensionally stable material suitable for use according to the invention has been described, int.al., in US-A-4 247 498. Examples of suitable polymers include: low density polyethylene, high density polyethylene, polypropylene, polystyrene, acrylonitrile-butadiene-styrene terpolymers, styrene-acrylonitrile copolymers, styrene-butadiene copolymers, polybutene, and poly(4-methyl-pentene-1). Optimum results were obtained by using polymers based on polyolefins, with preference being given to the use of a polypropylene based porous material. Generally, the porous polymer is employed in the form of grains having an average particle diameter of 0,1 to 10 mm. Alternatively, the polymer may be employed as a granulate and in the form of membranes, fibres which may be hollow or not, etc. Use in the form of a granulate or powder may be in a packed or fluidised bed. When fibres which may be hollow or not are employed, they are used in the form of fabrics and non-wovens, respectively. The porous materials filled with secondary amine which, according to the invention, are suitable for the removal of gaseous impurities selected from the group of H 2 S, COS, CS 2 and SO 2 may be obtained by filling porous polymers the making of which is described in US-A-4 247 498. However, the preferred material is a variation on one described in GB-A-2 115 425, and is obtainable by dissolving first, 5-90 wt.% of polypropylene with heating, at a temperature beyond the critical demixing temperature Tc, in 10-95 wt.% of a mixture of coco- or C12/C14-alkyl diethanol amine, ditridecyl amine, and triethylene glycol, the mixing ratio being such as will give phase separation on cooling, resulting in a polymer-rich and a polymer-poor phase. On further lowering of the temperature said phase separation structure will be fixed prior to the completion of phase separation due to the polymer vitrifying or crystallising, resulting in a porous polymer material filled with one or more of the above compounds and pre-eminently suited to be used according to the invention, either as such or after a reduction if so desired. The polar triethylene glycol is added to prevent the formation, on account of the ditridecyl amine's strongly apolar character, of a waxy instead of a porous structure on cooling. The pore structure can be affected by adding greater or lesser amounts of triethylene glycol. It has been found the highest absorption capacity for CS 2 is obtained when using an equimolar mixture of the secondary ditridecyl amine and the tertiary C12/C14-alkyl diethanol amine, to which there must further be added about 10 wt.% of triethylene glycol, calculated on the amount of ditridecyl amine and C12/C14-alkyl diethanol amine. The invention will be further illustrated with reference to the following examples, which, of course, are not to be construed as limiting in any manner the scope thereof. Example 1 3,5 g of macroporous polypropylene powder having a porosity of 3 ml/g, composed of particles of an average diameter of 320 µm and an average pore diameter of 6 µm, were filled with 1,56 g of dibenzyl amine and 4,94 g of N,N-bis(2-hydroxyethyl) cocoamine (C 12 /C 14 -alkyl diethanol amine). About 2 g of this material were used to fill a column (length 93 mm, diameter 8,3 mm) in the form of a packed bed. Next, there was passed over this bed, per minute, 0,4 l of a CS 2 -containing air mixture (2,5 g CS 2 per m 3 ). The CS 2 concentration of the outflowing air was measured continuously with the aid of an infrared detector. As soon as a CS 2 concentration was measured in the outflowing air which exceeded 1% of the inflowing air mixture's CS 2 concentration, the amount of absorbed CS 2 was calculated. The increase in weight corresponded to 1,2 wt.%, calculated on the bed mass. Example II The experiment of Example I was repeated, with the proviso that this time 3,5 g of the macroporous polypropylene powder were filled with 3,1 g of N-oleyl-butyl-3-aminopropanoate and 3,4 g of N,N-bis(2-hydroxyethyl) cocoamine. After one hour's passage of air the increase in weight of the packed bed was determined, after which the bed was regenerated by being placed in a 90°C oven for half an hour with the passage of 0,4 l of pre-heated nitrogen per minute. Loading and regeneration were repeated eight times. For each of these experiments the increase in weight after one hour's passage of air is given in the table below. Loading experiment wt.% of absorbed CS 2 1 3,7 2 3,6 3 3,4 4 2,8 5 3,1 6 2,6 7 2,8 8 2,6 Example III a Preparation of the absorption material The primary amino group of N-coco-1,3-propane diamine was blocked by the addition, at a temperature in the range of 20° to 30°C, of 117,67 g of propylene carbonate to 300 g of this diamine, after which there was stirring at room temperature for a further hour. Next, 35 g of polypropylene were dissolved in 65 g of the above-mentioned reaction product at a temperature of 240°C. Following cooling and grinding of the solidified mass, amine filled macroporous particles having an average diameter of 400 µm and an average pore diameter of 11 µm were obtained. b Use of the material for CS 2 absorption and regeneration About 2 g of this material were used to fill a column (length 93 mm, diameter 8,3 mm) in the form of a packed bed. Next, there was passed over this bed, per minute, 0,4 l of an air mixture containing 2,5 g CS 2 per m 3 . The CS 2 concentration of the outflowing air was continuously measured with the aid of an infrared detector. As soon as a CS 2 concentration was measured in the outflowing air which exceeded 1% of the inflowing air mixture's CS 2 concentration, the amount of absorbed CS 2 was calculated. The increase in weight corresponded to 3,25 wt.%, calculated on the bed mass. Next, the bed was regenerated by being placed in a 90°C oven for half an hour with the passage of 0,4 l of pre-heated nitrogen per minute. Subsequently, loading with CS 2 was carried out again, with only 0,2 wt.% of CS 2 , calculated on the bed mass, being absorbed. The regeneration temperature was then increased to 110°C, whereupon loading and regeneration were repeated eight times. For each of these experiments the increase in weight after one hour's passage of air is given in the table below. Loading experiment wt.% of absorbed CS 2 1 1,9 2 1,5 3 1,4 4 1,75 5 1,5 6 1,7 7 1,75 8 1,8 Next, a further five loading/regeneration cycles were performed, this time with air of the same composition as the dry CS 2 -containing air mixture but with a relative humidity of 90% (at room temperature) being passed through the bed. Loading and regeneration were repeated five times. For each of these experiments the amount of absorbed CS 2 after one hour's passage of CS 2 -containing humid air is given in the table below. Loading experiment wt.% of absorbed CS 2 9 2,6 10 2,55 11 2,55 12 2,35 13 2,45 Example IV The experiment of Example I was repeated, with the proviso that this time 3,5 g of the macroporous polypropylene powder were filled with 3,05 g of ditridecyl amine and 3,45 g of N,N-bis(2-hydroxyethyl) cocoamine. About 2 g of this material were used to fill a column (length 93 mm, diameter 8,3 mm) in the form of a packed bed. Next, there was passed over this bed, per minute, 0,4 l of a CS 2 -containing air mixture (2,5 g CS 2 per m 3 ). The CS 2 concentration of the outflowing air was continuously measured with the aid of an infrared detector. As soon as a CS 2 concentration was measured in the outflowing air which exceeded 1% of the inflowing air mixture's CS 2 concentration, the amount of absorbed CS 2 was calculated, after which the bed was regenerated by being placed in a 90°C oven for half an hour with the passage of 0,4 l of preheated nitrogen per minute. Loading and regeneration were repeated eight times. For each of these experiments the weight percentage of absorbed CS 2 calculated on the bed weight, is indicated in the table below. Loading experiment wt.% of absorbed CS 2 1 3,15 2 2,15 3 2,15 4 1,95 5 1,80 6 1,95 7 1,90 8 1,45 9 1,60 10 1,65 Next, the packed bed was regenerated at 110°C. For each of these experiments the weight percentage of absorbed CS 2 , calculated on the bed weight, is given in the table below. Loading experiment wt.%of absorbed CS 2 11 1,70 12 1,60 Next, a further three loading/regeneration cycles were performed, this time with air of the same composition as the dry CS 2 -containing air mixture but with a relative humidity of 90% (at room temperature) being passed through the bed. Loading and regeneration were repeated three times. For each of these experiments the weight percentage of absorbed CS 2 , calculated on the bed weight, is given in the table below. Loading experiment wt.% of absorbed CS 2 13 2,0 14 2,1 15 2,2 Example V a Preparation of the absorption material At a temperature of 250°C, 30 g of polypropylene were dissolved in 36 g of ditridecyl amine, 7 g of triethylene glycol, and 27 g of N,N-bis(2-hydroxyethyl) cocoamine and homogenised until a clear solution was obtained. Following cooling and grinding of the solidified mass, amine filled macroporous particles having an average diameter of 350 µm and an average pore diameter of 5 µm were obtained. b Use of the material for CS 2 absorption and regeneration About 2 g of this material were used to fill a column (length 93 mm, diameter 8,3 mm) in the form of a packed bed. Next, there was passed over this bed, per minute, 0,4 l of a CS 2 -containing air mixture (2,5 g CS 2 per m 3 ). The CS 2 concentration of the outflowing air was continuously measured with the aid of an infrared detector. As soon as a CS 2 concentration was measured in the outflowing air which exceeded 1% of the inflowing air mixture's CS 2 concentration, the amount of absorbed CS 2 was calculated. Next, the bed was regenerated by being placed in a 110°C oven for half an hour with the passage of 0,4 l of pre-heated nitrogen per minute. In all, six experiments were carried out using the same packed bed. For each of these experiments the weight percentage of absorbed CS 2 , calculated on the bed weight, is given in the table below. Loading experiment wt.% of absorbed CS 2 1 3,95 2 3,50 3 3,50 4 3,75 5 3,80 6 4,10 Example VI The experiment of Example V was repeated, with the proviso that there was passed over the bed 0,28 l/minute of a humid air mixture containing 0,45 g CS 2 per m 3 . The CS 2 concentration of the outflowing air was continuously measured with the aid of an infrared detector. As soon as a CS 2 concentration was measured in the outflowing air which exceeded 1% of the inflowing air mixture's CS 2 concentration, the amount of absorbed CS 2 was calculated. At that moment 2,2 wt.% of CS 2 had been absorbed by the bed. Example VII The experiment of Example VI was repeated, with the proviso that this time the rate of flow of the air mixture was 2 l per minute. The CS 2 concentration of the outflowing air was continuously measured with the aid of an infrared detector. As soon as a CS 2 concentration was measured in the outflowing air which exceeded 1% of the inflowing air mixture's CS 2 concentration, the amount of absorbed CS 2 was calculated. At that moment 2,1 wt.% of CS 2 had been absorbed by the bed. Example VIII The experiment of Example V was repeated, with the proviso that this time 0,4 l per minute of an air mixture containing 1,8 wt.% of CO 2 was passed over the bed. The CO 2 concentration of the outflowing air was measured with the aid of an infrared detector. It was found that no CO 2 was absorbed.

Claims: Use of a porous material for the removal of gaseous impurities from a gas mixture, selected from the group of H 2 S, COS, CS 2 , and SO 2 , into the pores of which there is incorporated a secondary amine which chemically bonds with the constituents to be removed, characterised in that the material comprises a hydrophobic polymer having pores of an average diameter in the range of 0,1 to 50 µm and the secondary amine has hydrophobic properties. Use according to claim 1, characterised in that the secondary amine is incorporated into a hydrophobic liquid. Use according to claim 1, characterised in that the average diameter of the pores is in the range of 0,2 to 15 µm. Use according to claim 1, characterised in that at least 15% of the pores is filled with a liquid composed of secondary amine or a secondary amine-containing liquid. Use according to claim 1, characterised in that at least 60% of the pores is filled with a liquid composed of secondary amine or a secondary amine-containing liquid. Use according to claim 1, characterised in that the secondary amine corresponds to the formula R 1 - NH - R 2 , wherein R 1 represents a functionalised or unfunctionalised (ar)aliphatic group with at least 7 carbon atoms and R 2 represents a functionalised or unfunctionalised (ar)alkyl group with at least 3 carbon atoms. Use according to claim 6, characterised in that the secondary amine is dibenzyl amine. Use according to claim 6, characterised in that the secondary amine is ditridecyl amine. Use according to claim 1, characterised in that the secondary amine is a compound of the formula R 3 - NH - R 4 - NH-C(O)O - R 5 , wherein R 3 represents a functionalised or unfunctionalised (ar)aliphatic group with at least 7 carbon atoms, R 4 represents a functionalised or unfunctionalised alkylene group with at least 2 carbon atoms, and R 5 represents a substituted or unsubstituted alkyl group with at least 2 carbon atoms. Use according to one or more of the preceding claims, characterised in that a tertiary amine is part of the hydrophobic liquid. Use according to claim 10, characterised in that the tertiary amine is alkyl dialkanol amine. Use according to claim 10, characterised in that the tertiary amine is alkyl diethanol amine. Use according to claim 10, characterised in that the tertiary amine is C12/C14-alkyl diethanol amine. Use according to claim 1, characterised in that the hydrophobic polymer is a polyolefin. Use according to claim 14, characterised in that the polyolefin is polypropylene. Use of a porous material for the removal of gaseous impurities from a gas mixture, selected from the group of H 2 S, COS, CS 2 , and SO 2 , into the pores of which there is incorporated a secondary amine which chemically bonds with the constituents to be removed, obtainable by first dissolving 5-90 wt.% of polypropylene with heating, at a temperature beyond the critical demixing temperature Tc, in 10-95 wt.% of a mixture of coco- or C12/C14-alkyl diethanol amine and triethylene glycol, the mixing ratio being such as will give phase separation on cooling, resulting in a polymer-rich and a polymer-poor phase, followed by mechanical reduction of the mass solidified by further cooling.

Inventors: BOS JOHANNES, SCHOMAKER ELWIN, BOS, JOHANNES, SCHOMAKER, ELWIN
Applicants: AKZO NOBEL NV, AKZO NOBEL N.V.
Application year: 1994
Main classification: B01D53
IPC codes: B01D53, B01J20