Charging member, charging device and process cartridge detachably mountable to image forming apparatus

Abstract: A charging member for charging a member to be charged includes a base member; a surface elastic member supported by the base member, the elastic member comprises a foamed member and a coating layer covering the foamed member; wherein a surface of the charging member has an Asker-C hardness of not more than 55 degrees and an international rubber hardness (IRHD) of not more than 80 degrees.

Description: FIELD OF THE INVENTION AND RELATED ART The present invention relates to a charging member and charging device for charging a member to be charged such as an image bearing member, and a process cartridge detachably mountable to an image forming apparatus. In a contact charging type, a charging member supplied with a voltage is contacted to an image bearing member (photosensitive drum) to directly transfer electric charge to the photosensitive drum to charge the surface thereof to d predetermined potential. As compared with a widely used corona discharger, the contact type is advantageous in that the voltage required for providing a predetermined potential on the photosensitive drum surface can be reduced, that the amount of ozone produced through the charging process is so small that the necessity for a filter for removing ozone is eliminated, that the structure of the exhausting system can be simplified correspondingly so that no filter maintenance is required, and the overall structure simplified. For this reason, it is particularly noted as a means replaceable with corona discharger to charge an image bearing member such as a photosensitive member or the dielectric member or another photosensitive member. In the contact charging method or apparatus, there is a type in which an oscillating voltage in the form of a DC biased AC voltage is applied to the contact charging member for the purpose of uniform charging operation. Figure 22 shows an example thereof, in which reference numeral 1 designates a photosensitive drum, which is rotated in a predetermined, namely in the clockwise direction R1, at a predetermined peripheral speed (process speed). It may be an electrophotographic photosensitive member or electrostatic recording dielectric material or the like. Designated by a reference numeral 2 is a conductive roller (charging roller) as the contact charging member. The charging roller 2 comprises a solid type rubber such as a urethane rubber, EPDM or the like having an electroconductivity, as designated by a reference numeral 2r. The hardness thereof is 60 - 70 degrees (Asker-C). The charging roller 2 is press-contacted to the surface of the photosensitive drum 1 at a predetermined pressure provided by springs 3 at the opposite end portions of the core metal 2a. It is rotated by rotation of the photosensitive drum 1 in a direction R2. The charging roller 2 is supplied with a voltage 4, which supplies through a contact leaf spring (not shown) contacted to the core metal 2a of the charging roller 2, a voltage (Vac + Vdc) which is a DC voltage Vdc superimposed with an oscillating voltage Vac having a peak-to-peak voltage Vpp which is not less than twice a charge starting voltage of the photosensitive drum 1. By doing so, the outer peripheral surface of the rotating photosensitive drum 1 is uniformly charged. The charging roller involves the following problems. The solid type rubber charging roller has a high hardness with the result that a part of the charging roller is apart from the photosensitive drum with the result of improper charging. Such improper charging tends to occur in the central portion in the longitudinal direction of the charging roller. When the oscillating voltage is applied charging noise occurs by beating action between the charging roller and the photosensitive drum, and the charging noise is uncomfortable. As a method of reducing the charging noise, there is a means of packing metal or the like in the photosensitive drum, with the result of a problem from the standpoint of weight and the cost. Accordingly, it is a principal concern of the present invention to provide a charging member, a charging device and a process cartridge in which the hardness of the charging member is reduced. It is another concern of the present invention to provide a charging member, a charging device and a process cartridge in which the contact relative to the member to be charged is stabilised to permit satisfactory charging operation. European Patent No. EP-A-0526235 discloses a charging member in which a roller has an elastic surface layer on a foam member. Japanese Patent Abstract No. JP-A-1-179957 discloses a charging roll having a metallic core and an elastic body layer provided on the outside periphery of the core. The Asker C hardness of the roll is below 60 degrees. In accordance with a first aspect of the present invention there is provided a charging member as defined in claim 1. In accordance with further aspects of the present invention there are respectively provided a charging device and a process cartridge incorporating the charging member as set out hereinbefore. An embodiment of the present invention provides a charging member, a charging device and a process cartridge in which the charging noise is reduced. These and other features and advantages of the present invention will become more apparent upon a consideration of the following description of the preferred embodiments of the present invention taken in conjunction with the accompanying drawings. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic cross-sectional view of a charging member according to a first embodiment of the present invention. Figure 2 schematically shows a longitudinal sectional view of a portion adjacent to an end of the charging member. Figure 3 illustrates manufacturing method of the charging roller. Figure 4 illustrates a manufacturing method of the charging roller. Figure 5 is a graph showing a relationship between Asker-C hardness and a charging noise. Figure 6 is a graph showing a relationship between a charging frequency and a noise level. Figure 7 is a graph showing a relationship between a Wallace hardness and toner fusion. Figure 8 is a cross-sectional view of a charging member according to a second embodiment of the present invention. Figure 9 is a schematic longitudinal sectional view of a portion adjacent an end of the charging member. Figure 10 is a table showing a relationship between a magnitude and an angle of a tapered portion and a hardness and volume resistivity. Figure 11 is a graph showing a relationship between a tensile stress of a tube and a wearing amount of the charging roller, in a third embodiment of the present invention. Figure 12 illustrates the amount of wearing. Figure 13 is a perspective view illustrating voids appearing in a surface of a foamed material in a fourth embodiment. Figure 14 is a table illustrating a relationship between a maximum diameter of depth of the voids and evaluation of image quality, in the same Figure. Figure 15 is a perspective view illustrating another configuration of the voids in the surface of the foamed material. Figure 16 shows a relationship between a maximum diameter and depth of the voids and an image quality evaluation. Figure 17 is a perspective view illustrating a further configuration of the voids in the surface of the foamed material. Figure 18 shows a relationship between a maximum diameter and depth of the voids and an image quality evaluation. Figure 19 is a graph showing a relationship between a thickness of a tube and a maximum diameter of the voids. Figure 20 is a graph showing a relationship between a hardness of the tube and a maximum diameter. Figure 21 is a cross-sectional view of a process cartridge. Figure 22 shows a structure of conventional charging roller. DESCRIPTION OF THE PREFERRED EMBODIMENTS Referring to the accompanying drawings, the embodiments of the present invention will be described. Figure 1 is a cross-sectional view of a charging roller 2 as an exemplary charging member according to an embodiment of the present invention. Figure 2 is a partial longitudinal sectional view adjacent a longitudinal end thereof. Designated by reference numeral 1 is a rotatable photosensitive drum of a positive or negative charging property. Designated by reference numeral 2 is a charging roller as a contact charging member. The charging roller 2 comprises a core metal 2a of stainless steel as a supporting member, a foamed material (foamed layer) 2b integrally formed on the outer peripheral surface of the core metal 2a concentrically, and an intermediate resistance electroconductive tube 2c on the outer peripheral surface of the foamed material 2b. Such a charging roller may be produced through a method in which the foamed member 2b is first manufactured, and the core metal 2a and a tube 2c are inserted (Figure 3), or a method in which a core metal 2a is erected within the tube 2c, and the material for the foamed member 2b is filled around the core metal 2a, and then the material is foamed with the tube and the core metal fixed (Figure 4), or the like. With the former method, waving or deviation or the like may occur when the material is inserted, and therefore, it is difficult to provide stabilized images. For this reason, the charging roller is produced through the latter method in this embodiment. The tube 2c covering the conductive foamed member 2b is substantially separated from the electroconductive foamed member 2b. The same applies to between the core metal 2a and the electroconductive foamed member 2b. In order to prevent the deviation in the axial direction, tube 2c and the foamed material 2b may be partly fixed to each other, and the core metal 2a and the foamed material 2b may be partly fixed to each other. As a result, even if an oscillating voltage is applied to the core metal 2a, the heavy core metal 2a does not vibrate, but only the light foamed member 2b and the tube 2c are only vibrated to beat the photosensitive drum 1, and therefore, the beating energy is small with the result of smaller charging noise. The surface of the foamed material 2b is not smooth because of cells on the surface thereof, but the improper charging can be avoided by covering it with the tube 2c having good surface property. In addition, the tube 2c is harder than the electroconductive foamed member, so that deformation of the charging roller due to an external force can be avoided. However, such a charging roller 2 results in toner fusion on the surface of the charging roller because of the hardness of the tube 2c particularly under high temperature and high humidity ambient condition (32.5 °C and 90 %). The improper charging occurs by the local resistance increase caused by the fusion. This is another problem. The description will be made as to relationships among Asker-C hardness of the charging roller (charging member), international rubber hardness standard hardness of the tube, the charging noise, and the toner fusion. As regards the charging noise, interrelations are recognized between the noise pressure of the charging noise and the Asker-C hardness of the charging roller, and more particularly, the noise pressure of the charging noise can be reduced if the Asker-C hardness is reduced. This is because the vibration energy of the charging member reduces with reduction of the Asker-C hardness. When the frequency of the oscillating voltage applied to the charging member, which will hereinafter be called (charging frequency), is 1500 Hz, the relationship between the Asker-C hardness and the charging noise pressure, is as shown in Figure 5. The relationship between the charging frequency and the noise pressure when the Asker-C hardness is 65 degrees and 55 degrees, is as shown in Figure 6. From Figures 5 and 6, it will be understood that if Asker C hardness is not more than 55 degrees, the charging noise level can be suppressed below 50 dB up to 1500 Hz of the charging frequency. According to the investigations of the inventors, the charging noise is not uncomfortable in the normal printing operation if the charging noise level is not more than 50 dB. As regards the toner fusion, an interrelation is recognized between the toner fusion on the charging member during long term operation and a microhardness of the charging member surface (the hardness of the tube). More particularly, the amount of toner fusion is small if the microhardness is small. The reason for this is considered as resulting from the cause of the toner fusion. More particularly, when the residual toner on the photosensitive drum not completely removed by the cleaning device and the toner scattered in the main assembly of the apparatus are deposited on the surface of the charging roller, the toner is rubbed at the contact portion with the photosensitive drum if the microhardness on the surface of the charging roller is high, with the result of the toner fusion thereon. Figure 7 shows an interrelation between the toner fusion and the hardness under the international rubber hardness standard IRHD, ISO 48 - 1975 or ASTM D 1415-68, measured by Wallace microhardness meter, available from H.W. Wallace and Co. Ltd. From Figure 7, it will be understood that the problem of the toner fusing can be avoided if the Wallace hardness is not higher than 80 degrees. The description will be made referring to the drawings. In Figures 1 and 2, the foamed member 2b comprises a foamed material such as polystyrene, polyolefine, polyester, polyurethane or polyamide material or a soft material such as EPDM (ethylene propylene diene terpolymer) or urethane material, in which electroconductive powders such as carbon or tin oxide are dispersed to provide the proper volume resistivity. In this embodiment, the use is made with foamed polyurethane material in which carbon is dispersed. Designated by 2b' are cells, filled with air, nitrogen, argon gas or the like. As for the conductive tube, fluorine resin material such as urethane resin, polyester resin, polyethylene resin, TFA resin (perfluoroalkoxy), FEP, PTFE (polytetrafluoroethylene resin), or synthetic rubber such as EPDM, styrene butadiene rubber or the like, in which electroconductive particles such as conductive carbon, tin oxide, titanium oxide, indium oxide or the like, and the materials are mixed and kneaded, thereafter, the tube is foamed through extrusion or the like. In this embodiment, the use is made with polyester urethane resin material in which carbon is dispersed. Specifications of the charging roller 2 in this embodiment are as follows: Core metal 2a: 6 mm in diameter, 260 mm in length and made of stainless steel round rod Foamed material 2b: carbon dispersed foamed polyurethane material having a volume resistivity of 10 2 - 10 6 ohm.cm and having a layer thickness of 2.5 mm and a length of 230 mm Tube 2c: thermoplastic polyurethane elastomer having a volume resistivity of 10 3 - 10 9 ohm.cm and a layer thickness of 250 µm Weight of charging roller 2: 68 g The Asker-C hardness of the charging roller was 42 degrees, and the Wallace hardness was 70 degrees. From the standpoint of avoiding improper charging in the form of stripe non-uniformity due to current leakage from the charging roller 2 to the photosensitive drum, the volume resistivity of the tube 2c is preferably larger than that of the foamed member 2b. Similarly to the conventional charging roller shown in Figure 22, the charging roller 2 of this embodiment is supported by an unshown bearings at the opposite longitudinal ends of the core metal 2a, and is urged to the photosensitive drum by a compression spring 3 to provide a predetermined urging force against the surface of the photosensitive drum (total pressure of 1000 g) in this embodiment. It is rotated by the rotation of the photosensitive drum 1. The charging roller 2 is supplied from a voltage source 4 through a sliding electrode (not shown) contacted to the core metal 2a of the charging roller, with the superimposed oscillating voltage (Vac + Vdc) of the following: AC voltage: 2.0 KVpp, 1500 Hz DC voltage: DC voltage corresponding to a target charging potential. By doing so, the peripheral surface of the rotating photosensitive drum 1 is uniformly charged to the target potential through AC charging process. The noise level of the charging roller of this embodiment and a conventional internal solid type charging roller, have been measured. An example of the conventional charging roller 2 had the following specifications: Core metal 2a: 6 mm in diameter, 260 mm in length made of stainless steel round rod Rubber roller 2r: carbon dispersed solid EPDM conductive rubber, having a volume resistivity of 10 5 ohm.cm, a layer thickness of 2.8 mm and a length of 230 mm. Weight of the charging roller: 120 g The Asker-C hardness of the charging roller was 62 degrees. The contact charging device of this embodiment is placed in anechoic chamber, and the charging noise was measured under the above-described voltage application. The measurements were carried out under paragraph 6 of ISO 7779. The results show that the charging noise with the conventional solid integral charging roller was 68 dB, and that of the charging roller of this embodiment was as low as 41 dB. The charging noise reduction effect can be provided irrespective of whether the cells of the foamed material are independent or open. The charging roller of this embodiment is incorporated in a laser beam printer, and the durability test run for image formation was carried out under high temperature and high humidity ambient condition (32.5 °C, 90 %) up to 6000 A4 sheets. As a result, no toner fusion on the surface of the charging roller was observed, and improper image quality due-to improper charging did not occur. As will be understood from the foregoing, the charging noise can be sufficiently reduced if the Asker-C hardness is not higher than 55 degrees, and IRHD hardness is not higher than 80 degrees. In addition, by doing so, the toner fusion on the surface of the charging roller can be avoided without uncomfortable noise. In addition, a high quality image can be provided. Embodiment 2 In this embodiment, the charging roller 2 comprises the electroconductive foamed member 2b, an intermediate resistance tube 2c thereon, a conductive layer 2d thereon, an intermediate resistance layer 2e and a protection layer 2f thereon. Figure 8 is a cross-sectional view of a charging roller according to this embodiment. The protection layer 2f on the intermediate resistance layer 2e is selected in consideration of the relation with the surface layer of the photosensitive drum 1 such that the contamination of the photosensitive drum 1 and the charging roller 2 can be avoided. Examples of the material of the protection layer include electroconductive powder dispersed resin material such as N-methoxymethyl nylon, polyvinylbutyral resin, polyvinylchloride resin, polyvinyl alcohol resin, ethylenevinyl acetate resin, polyurethane resin, acrylic resin or the like. In this embodiment, carbon dispersed N-methoxymethyl nylon was used. In this embodiment, as shown in Figure 9, a taper portion 2c' is provided at each longitudinal end of the tube 2c. When the foaming material is foamed in the tube without the tapers 2c' (Figure 4), the pressure resulting from the foaming of the foaming material is significantly low at the end portions as compared with the longitudinally central portion of the tube 2c. The reason is as follows. In the longitudinally central portion of the tube 2c, the foaming takes place in virtually closed space. On the contrary, at the end portion, it is not closed, and therefore, the foaming pressure in the tube decreased there. The foamed material produced by the low foaming pressure tends to acquire larger cells in the material, with the result of lower hardness of the foamed material, and therefore, a larger volume resistivity. By the provision of the taper 2c' at each longitudinal end portion of the tube 2c, the opening is reduced, thus preventing escape of the foaming material, and providing pressure urging the material toward the longitudinally central portion by the inside wall surfaces of the taper 2c'. By foaming the material in the tube 2c with such tapers 2c' at the opposite ends, the foaming pressure can be provided which is substantially uniform at the central portion and the end portions, and therefore, the sizes of the cells in the foamed material are uniform along the entire length. When the sizes of the inside cells are uniform, the hardness and the volume resistivities are equally uniform. By charging the photosensitive drum using the charging member produced in this manner, the surface potential of the photosensitive drum is uniform, and therefore, good images can be provided without charging non-uniformity. Figure 10 shows results of experiments carried out to determine the proper range of the tapered portion. The size of the tapered portion 2c' is represented as a ratio of a cross-sectional area of the end opening to a cross-sectional area of the tube 2c in the longitudinally central portion thereof, and an angle α (Figure 9) of the tapered portions 2c' relative to the surface of the photosensitive drum. As the effects, the hardness and the volume resistivity of the foamed member 2c at the longitudinal end portions of the tube 2c, and the image qualities are evaluated. As will be understood from Figure 10, uniform images can be provided if the opening area at the end is not more than 90 % relative to the cross-sectional area in the central part, more preferably, it is not more than 80 %. By doing so, the hardness, the volume resistivity of the foamed material 2b is uniform in the longitudinal and circumferential directions, so that further stabilized charging is enabled. As to the angle α, if it is not less than 5 degrees, non-uniform can be provided, and more preferably, if it is not less than 20 degrees, the hardness and the volume resistivity of the foamed member 2b is uniform in the longitudinal and circumferential directions, and therefore, further stabilized charging is enabled. The specifications of this embodiment are as follows: Foamed member 2b: carbon dispersed foamed epichlorohydrin rubber having a volume resistivity of 10 2 - 10 6 ohm.cm and having a layer thickness of 2.5 mm and a length of 230 mm. Tube 2c: polyester urethane thermoplastic elastomer having a volume resistivity of 10 3 - 10 9 ohm.cm and having a layer thickness of 250 µm. Electroconductive layer 2d: N-methoxymethyl nylon in which conductive powder such as carbon or tin oxide or the like is dispersed having a volume resistivity of 10 1 - 10 6 ohm.cm and having a layer thickness of 10 µm. Intermediate resistance layer 2e: epichlorohydrin rubber having a volume resistivity of 10 7 - 10 10 ohm.cm having a layer thickness of 200 µm. Protection layer 2f: N-methoxymethyl nylon having a volume resistivity of 10 7 - 10 12 ohm.cm and having a layer thickness of 5 µm. Weight of charging roller 2: 70 g The Asker-C hardness of the charging roller 2 was 48 degrees, and the Wallace hardness was 75 degrees. Using the charging roller 2, the charging noise was produced in the same manner as in Embodiment 1, and the image forming test run was carried out under high temperature and high humidity condition. The measured charging noise was as small as 44 dB. In the image forming test run, no toner fusion occurs onto the charging roller 2 surface, and therefore, the foamed images were satisfactory, as in Embodiment 1. Embodiment 3 In this embodiment, similar charging roller 2 as in Embodiment 2 was used, but a tensile stress of the tube 2c was changed, and a plastic deformation (permanent set in fatigue) was checked. Since the charging roller 2 is pressed to the photosensitive drum 1, the deformation thereof increases with increase of the softness of the foamed member 2b of the charging roller 2. If the charging roller 2 does not restore, the rotation of the charging roller becomes non-uniform because of the permanent deformation with the result of improper charging or blurred images. Since the charging roller 2 of this embodiment is provided with a tube 2c covering the foamed member 2b, and therefore, the plastic deformation does not easily occur, and it depends on the tensile stress of the tube 2c. These have been found through experiments. The amount of fatigue of the charging roller is measured when the tensile stress of the tube 2c is changed in the charging roller 2 of the second embodiment. Figure 11 shows the results with evaluation of the images. The tensile stress is measured in the following manner. The use is made with a sample material of the same material as the tube having a thickness of 0.2 mm and a width of 10 mm. It was pulled in a distance of 50 mm. The measurement is carried out using a tensile tester. The pulling speed was 50 mm/min constant. The load was read at the point of time when the elongation reaches 100 % (F100). The tensile stress M100 is defined as the value divided by the cross-sectional area, namely, M100 (kgf/cm 2 ) = F100 (kgf) / cross-sectional area of the material (cm 2 ) As for the measurement of the amount of fatigue, the outer diameter (D1) of the charging roller 2 is measured, and the charging roller is pressed against the photosensitive drum 1 with a total pressure of 1000 g. They are left as it is for one month under 40 °C and 95 % humidity ambience. Thereafter, the diameter d2 as shown in Figure 12 is measured. The amount of fatigue is defined as (d1 - d2). From the results of the experiments, it is understood that the amount of fatigue of the charging roller 2 decreases with increase of the tensile stress M100 of the tube 2c. This is because the high tensile stress or strength tube 2c is provided, and therefore, the force produced by the urging of the charging roller 2 to the photosensitive drum 2 is distributed to wide area in the tube 2c so that local deformation of the charging roller 2 at the contact portion is reduced. With the decrease of the amount of fatigue, the improper charging or image blurness can be reduced correspondingly. In this embodiment, the amount of fatigue not resulting in the improper image formation is 0.2 mm or lower, and the tensile stress M100 of the tube 2c satisfying this is 100 kgf/cm 2 or higher. As described, by using for the tube 2c the material having the tensile stress M100 of not less than 100 kgf/cm 2 , the charging roller 2 can exhibit small amount of fatigue and good surface property, and therefore, the charging noise can be sufficiently reduced. In addition, the improper charging can be prevented. Embodiment 4 In this embodiment, the charging roller 2 is manufactured by foaming a foaming material as described in conjunction with Figure 4. In this case, there is no way of air escape at the interface with the tube with the result that the air remains as a great number of bubbles, which will hereinafter be called "voids". This is not recognized from the outer appearance. However, the following has been found. When this charging member is contacted to the photosensitive drum and the photosensitive drum is rotated, residual toner not having been removed by the cleaning blade enters between the charging member to the photosensitive drum, and the residual toner may stagnate in the voids with the result of improper charging and black spots on the image. It will be possible to remove the voids by abrading the elastic surface of the foamed material. However, the difficulty will arise then, in that the straightness in the longitudinal direction is difficult to maintain, and in addition the manufacturing cost is increased. In this embodiment, the foamed material is provided with an integral skin layer at the surface thereof, and therefore, the cells of the foamed material are not exposed to the outside. In this sense, the void is distinguished from cell. In this embodiment, various configurations of voids 2g are foamed in the charging roller 2 having the structure of the second embodiment, and durability test run is carried out to evaluate image quality including improper charging, for 10,000 sheets. In the case of Figure 13, the voids 2g have substantially circular configuration. Figure 14 shows the results of experiments. From this Figure, it will be understood that the improper charging is rather dependent upon the outer diameter than the depth of the voids 2g. Furthermore, it will be understood that if the outer diameter is not more than 5 mm, the improper charging does not occur. Subsequently, the observations have been made for the case in which the voids 2g are oval which is long along a circumferential direction of the charging roller. An example of such voids are shown in Figure 15. The inside surface of the tube 2c is roughened randomly in the circumferential and longitudinal directions by a sand paper. A conductive rubber which is a material of the foamed material 2b and the core metal 2a are inserted, and integral foaming is carried out, by which the voids 2g long in the circumferential direction are produced. It is added here that if it is roughened only in the circumferential direction, the escape for the air extends only in the circumferential direction with the result that the void 2g extends all around the circumference. Figure 16 shows an interrelationship between the maximum diameter of the voids 2g and the image evaluation. In the case of the oval void 2g having a circumferential long axis, if the maximum diameter is not more than 5 mm, the improper charging does not occur. In addition, the observations have been made for the case in which the voids 2g have an oval configuration which is long along the length of the charging roller. An example of such voids 2g is shown in Figure 17. In the inside surface of the tube 2c, about 150 grooves having a height of 0.3 mm are formed in the longitudinal direction. The core metal 2a and conductive rubber which is the material for the foamed material 2b are inserted, and the integral foaming is carried out, by which oval voids 2g which is long in the longitudinal direction are provided. Figure 18 shows the relation between the maximum diameter of the voids 2g and the image evaluation. As contrasted to the above-described embodiment, the improper charging does not occur if the longer side length of the void 2g is not less than approx. 7 mm. It will be understood that the improper charging tends to occur when the voids 2g are long in the circumferential direction. In the foregoing, three void configurations are investigated, and as a result, if the maximum diameter of the voids 2g is less than 5 mm, satisfactory images can be provided at all times. The thickness and the hardness of the tube 2c of the charging roller 2 are changed, and the investigations have been made as to the interrelation between the voids and the image. Figures 19 and 20 show the relation between the maximum diameter of the voids 2g and the improper charging when the thickness and the hardness of the tube 2c are changed. In the Figure "o" indicates satisfactory image, and "x" indicates occurrence of improper charging. The charging roller 2 used with respect to Figure 19 is similar to that of Embodiment 2. The hardness thereof is approx. 40 degrees (IRHD), and the thickness of the tube 2c is changed. As to the thickness of the tube 2c, it is difficult to manufacture a thin tube 2c having a thickness of 0.15 mm or lower because of the stability in the manufacturing of the tube 2c. From the standpoint of the charging noise, the tube is not proper if the thickness thereof is 0.3 mm or larger. For this reason, the relation between the maximum void diameter and the image is investigated in the range of 0.15 mm - 0.3 mm of the tube. As will be understood from the Figure, the satisfactory images can be provided if the maximum diameter of the voids 2g is not more than 5 mm, irrespectively of the thickness of the tube 2c. The charging roller 2 related to Figure 20 is similar to that of Embodiment 2, and the thickness of the tube 2c is approx. 0.25 mm. The hardness is the international rubber hardness (IRHD). With respect to the hardness, it is changed in the range between approx. 30 degrees and approx. 50 degrees. It has been found that the maximum diameter of the voids 2g for satisfactory images is 5 mm. When the international rubber hardness of the tube 2c is lower than 30 degrees, the fatigue of the charging roller is not easily restored, when the apparatus is left with no rotation of the charging roller or the photosensitive member, with the possibility of result of improper charging. Therefore, it is preferable that the rubber hardness (IRHD) is not less than 30 degrees. As described in the foregoing, the maximum diameter of the voids 2g is preferably not more than 5 mm in order to provide satisfactory images. The advantages are particularly remarkable when the thickness of the tube is not less than 0.15 mm and not more than 0.3 mm, or the IRHD hardness of the charging roller 2 is not more than 30 degrees. The ranges are practical from the standpoint of manufacturing the charging roller 2. In order to permit stabilized manufacturing of the tube 2c, and in order to avoid the problem of the charging noise when an AC voltage is applied, the above-described range is most suitable. In addition, combinations of embodiments 1 - 4 are possible. Particularly, it is desirable that the Asker-C hardness of the surface of the charging member is 55 degrees or lower, the IRHD hardness is 80 degrees or lower, the tensile stress when the tube member is expanded by 100 % is 100 kgf/cm 2 or higher, and the maximum diameter of the voids in the outer surface of the foamed member is 5 mm or smaller. The description will be made as to an example in which the charging members according to Embodiments 1 - 4, are incorporated in a process cartridge detachably mountable to an image forming apparatus, and the image bearing member is charged by the charging member. In the process cartridge for an image forming apparatus, the charging member of any one of this embodiment is used as a charging means for charging the image bearing member. Figure 21 shows a structure of the process cartridge. The process cartridge comprises an electrophotographic photosensitive member in the form of a rotatable drum as an image bearing member, a charging roller 2 as a contact charging member, a developing device 6, and cleaning device 9 (four process means). However, the process cartridge may contain at least the photosensitive member 1 and the charging member 2. The charging roller 2 is the same as any one of those of Embodiments 1, 2, 3 or 4. The developing device 6 comprises a developing sleeve 60, a developer (toner) 61, a developing blade for applying the developer on the developing sleeve 6 in a uniform thickness. The cleaning device 9 includes a cleaning blade 90. Designated by a reference numeral 11 is a drum shutter, and is openable from teh closing position indicated by the solid line to the open position indicated by the broken line. When the process cartridge is taken out of the main assembly of the image forming apparatus (not shown), it is in the closed position indicated by the solid line, and it protects the surface of the photosensitive drum by covering the exposed surface of the photosensitive drum 1. When the process cartrige is mounted in the main assembly of the image forming apapratus, the shutter 11 is opened as indicated by the broken line, or the shuter 11 is automatically opened in the mounting process of the prcess cartridge. When the process cartridge is mounted in place, the exposed portion of the photosensitive drum 1 is press-contacted to a transfer roller 8 in the main assembly of the image forming apparatus. The process cartridge is coupled with the main assembly of the image forming apparatus mechanically and electrically, by which the photosensitive drum 1, the developing sleeve 60 and the like can be operated by the driving mechanism in the main assembly of the image forming apparatus. In addition, the application of the charging bias voltage to the charging roller 2 and the application of the developing bias voltage to the developing sleeve 20 or the like are enabled from the voltage source (electric circuit) in the main assembly through electrodes. Therefore, the image forming operations is enabled. Designated by a reference numeral 5 is a laser beam introduced from a laser scanner (not shown) in the main assembly, and it is projected into the process cartridge on the surface of the rotating photosensitive drum 1 to scan therewith. Since the charging process means is not fixed in the laser beam printer main assembly, but it is in the process cartridge detachably mountable thereto, the vibration produced by the beating of the photosensitive drum by the charging roller is easily propagated over the entirety of the process cartridge, and therefore, the charging noise is amplified. Therefore, the beat of the charging noises which is one of the problems underlying the present invention is amplified with the result of further uncomfortable noise. However, by the use of the charging roller having the structure described above, the charging noise can be suppressed significantly even if an oscillating voltage is applied, and therefore, the charging noise can not be hard. In addition, compact process cartridge can be provided with high image quality without improper charging or the like. As described in the foregoing, according to the present invention, the charging noise can be sufficiently reduced, and the fusing of the toner on the surface of the charging member can be prevented. In addition, the charging roller exhibit small fatigue, and exhibits satisfactory surface property so that the occurrence of the improper charging can be prevented. In addition, the toner stagnation can be suppressed, and therefore, improper charging can be avoided. Thus, image forming apparatus capable of providing quite high quality image, can be provided. The voltage applied to the charging member is preferably a voltage having a periodically changing voltage level, and the waveform of the oscillating voltage may be a sine wave, a triangular wave or rectangular wave or the like. The oscillating voltage may be a combination of a DC voltage and an AC voltage provided by rendering on and off a DC voltage. In order to prevent spot like non-uniformity of charging of the member to be charged, the peak-to-peak voltage of the oscillating voltage is preferably not less than twice the charge starting voltage of the member to be charged. The charge starting voltage is a DC voltage when the charging of the member to be charged starts when only a DC voltage is applied between the charging member and the member to be charged and is gradually increased. While the invention has been described with reference to the structures disclosed herein, it is not confined to the details set forth and this application is intended to cover such modifications or changes as may come within the scope of the following claims.

Claims: A charging member for charging a member to be charged, comprising: a base member; a surface elastic member supported by said base member, said elastic member comprising a foamed member and a coating layer covering the foamed member; wherein the surface of said charging member has an Asker-C hardness of not more than 55 degrees and an international rubber hardness (IRHD) of not more than 80 degrees. A member according to claim 1, wherein said coating layer comprises a tube. A member according to claim 2, wherein said tube is of urethane resin, polyester resin, polyethylene resin, TFA resin (perfluoroalkoxy), FEP, PTFE (polytetrafluoroethylene resin), or a synthetic rubber e.g. EPDM, styrene butadiene rubber or the like, in which electroconductive particles are dispersed. A member according to claim 3, wherein the conductive particles dispersed in the resin of said tube are selected from carbon, tin oxide, titanium oxide, indium oxide or the like. A member according to any one of claims 2, 3 or 4, wherein the tube is of polyester polyurethane resin containing dispersed carbon. A member according to any one of claims 2 to 5, wherein the tube is of thickness 0.15-0.3 mm. A member according to any one of claims 2 to 6, wherein the tube is of volume resistivity about 10 3 -10 9 ohm cm. A member according to any preceding claim, wherein said charging member is capable of being supplied with a voltage. A member according to claim 8, wherein the voltage is an oscillating voltage. A member according to claim 8, wherein the voltage is in the form of a DC biased AC voltage. A member according to any preceding claim, wherein said coating layer has a volume resistivity larger than that of said foamed member. A member according to any preceding claim wherein said coating layer comprises a conductive layer and a resistance layer outside the tube in this order. A member according to claim 14, wherein the conductive layer is of volume resistivity 10 1 -10 6 ohm cm. A member according to claim 12 or 13, wherein the conductive layer is of layer thickness about 10 µm. A member according to any one of claims 12 to 14, wherein the conductive layer is of a nylon containing dispersed carbon or tin oxide. A member according to any one of claims 12 to 15, wherein the resistance layer is of volume resistivity of 10 7 -10 10 ohm cm. A member according to any one of claims 12 to 16, wherein the resistance layer is of thickness about 200 µm. A member according to any one of claims 12 to 17, further comprising a protective layer. A member according to claim 18, wherein the protective layer has a volume resistivity of 10 7 -10 12 ohm cm. A member according to claim 18 or claim 19, wherein the protective layer has a thickness of about 5 µm. A member according to any preceding claim wherein the foamed member has a volume resistivity of 10 2 -10 6 ohm cm. A member according to any preceding claim, wherein the foamed member is a foamed polyurethane rubber or a foamed epichlorohydin rubber containing dispersed carbon. A member according to any preceding claim, wherein the foamed layer is of thickness about 2.5 mm. A member according to claim 2 and any one of claims 3 to 23 where dependent on claim 2, wherein the tensile stress of said tube when it is expanded by 100% is not less than 100 kgf/cm 2 . A member according to claim 2 or 24, wherein a maximum diameter of voids formed in the surface of said foamed member adjacent said tube is not more than 5 mm. A member according to any preceding claim wherein the international rubber hardness is not less than 30 degrees. A member according to any of claims 2 to 26, wherein said tube is provided with an inward tapered portion toward a longitudinal end thereof. A member according to any preceding claim, wherein said charging member is in the form of a roller. A member according to any preceding claim, wherein said charging member is contactable to a member to be charged for charging the member to be charged. A charging device for charging an electrophotographic member to be charged, comprising: a charging member contactable to the electrophotographic member to be charged to charge it, said charging member being as defined in any preceding claim. A device according to claim 30, further comprising means for supplying an oscillating voltage to the charging member. A device according to claim 31, wherein said means is arranged to supply a DC biased AC voltage. A device according to claim 31 or claim 32, wherein said means is arranged to supply a voltage oscillating at a frequency up to 1500 Hz. Imaging forming apparatus including a photosensitive member and a charging device as claimed in any of claims 30 to 33 having its charging member in contact with the photosensitive member. A process cartridge detachably mountable to an image forming apparatus, comprising: a member to be charged capable of bearing an image; a charging member contactable to said member to be charged for charging said member to be charged, wherein a voltage is capable of being applied between said charging member and said member to be charged from a voltage source of a main assembly of said apparatus, said charging member being as defined in any of claims 1-31. A process cartridge according to claim 35, wherein said member to be charged is an electrophotographic photosensitive member. A process cartridge according to claim 36, further comprising a developing device for developing said electrophotographic photosensitive member.

Inventors: INAMI SATORU, KATO JUNICHI, OJIMA MASAKI, SAKURAI KAZUSHIGE, SANO TETSUYA, SATO HIROSHI, SUWA KOUICHI, INAMI, SATORU, KATO, JUNICHI, OJIMA, MASAKI, SAKURAI, KAZUSHIGE, SANO, TETSUYA, SATO, HIROSHI, SUWA, KOUICHI
Applicants: CANON KK, CANON KABUSHIKI KAISHA
Application year: 1994
Main classification: G03G15
IPC codes: G03G15