METHOD OF PREPARING CHEMI-MECHANICAL PULP

Abstract: The present invention relates to a method of producing chemi-mechanical pulp, comprising grinding wood in a grinding mill housed in a grinding chamber, maintaining the chamber at an overpressure and spraying water onto the wood. The invention is characterized by supplying oxygen via the spray water to the grinding mill chamber. Highly advantageous results are achieved when the oxygen addition is supplemented with a peroxide addition. The spray water is preferably alkaline.

Description: METHOD OF PREPARING CHEMI-MECHANICAL PULP. The present invention relates to a method for manufacturing chemimechanical pulp in which wood material is ground with the aid of a grinder in a grinding chamber, and in which the chamber is maintained at an overpres¬ sure and water is sprayed onto the wood. One method of producing mechanical pulp comprises grinding wood in a grinding mill. The wood is treated with hot water in a pressurized grinding chamber, with the intention of producing a higher quality pulp, said chamber als being maintained at a high temperature. The properties concerned include brightness, tensile index, tear index and opacity, among others. Hydrogen peroxide has also been added in recent times, together with a stabilizer therefor These measures have resulted in a pulp having satisfactory properties and produced at a competitive cost. However, it is desired to improve ground mechanical or chemimechanical pulp still further. Accordingly, an object of the present invention is to produce a chemimechanical pulp which has improved properties. By improved properties is meant in the present document an improvemen in the "sum" of the properties of the pulp. Thus, one property may be impaired while the other properties are improved when taken together. This object is achieved in accordance with the present invention by mean of a method for producing chemimechanical pulp in which wood is ground in a grinding mill in a grinding chamber, and in which the chamber is maintained at a overpressure and water is sprayed onto the wood. The method is characterized by supplying oxygen via the spray water to the chamber. Advantageous embodiments of the present invention are evident from the dependent Claims. It has surprisingly been found that the properties of pulp produced in a pressurized grinding mill at elevated temperatures are improved when oxygen is supplied to the grinding chamber. The oxygen is supplied to the chamber of the grinding mill dissolved in, or otherwise being part of, the spray water. For example, a part of the oxygen can be present i foam when alkaline spray water i used. It has also been found particularly advantageous to combine the oxygen charge with a hydrogen peroxide charge. Further advantages are gained when the water is alkaline. The invention will now be described in more detail with reference to an exemplifying embodiment thereof and also with reference to the accompanying drawing, the single Figure of which is a schematic illustration of equipment used to produce ground pulp. Wood is charged through a shaft 14 to a grinding mill 1 mounted in a pressurized grinding chamber. The necessary infeed valve has not been shown. The ground material defibered in the grinding mill is then passed to a shredder through a conduit 7. The pulp is taken from the shredder and passed to a cyclone 3, in which the pulp is separated from the gas, so that the pulp removed from the cyclone is under atmospheric pressure. The pulp taken from the cyclon 3 is passed through a conduit 9 to a disc filter 4, in which the pulp is de-watered and is passed from the filter through a conduit 15 for further treatment. The filtrate obtained in the filter 4 is collected in a tank 5 and is passed from the tank to the grinding mill 1 through a conduit 17 and with the aid of a pump 6. Water is added to the system through the conduit 17, via a further conduit 18, so as to compensate for the water that accompanies the pulp from the disc filter. According to an embodiment of the invention, oxygen is added to the spray water in the conduit 17 downstream of the pump 6, through a conduit 12. The oxygen supplied constitutes at most 5 percent by weight, preferably 0.2 to 2 percent by weight calculated on dry ground pulp. The properties of the pulp are further improved when hydrogen peroxide i added in the aforesaid embodiment. This peroxide addition may be effected through a conduit 11 between the filter tank 5 and the pump 6 in the conduit 17. The peroxide content of the water is at most 4 percent by weight, preferably between 0.5 to 2 percent by weight calculated on ground pulp. The following Table shows the results obtained from tests. Table Nitrogen Air 1 % H 2 θ2 1% H 2 θ2 0.5% H 2 C 1.5% O2 1.5 % 02 (H 2 ) (in air) (in air) Brightness 61.1 65.0 67.0 68.5 63.4 Tensile index 10.9 13.3 16.0 18.2 19.7 Tear index 2.2 2.4 2.5 2.9 3.0 Opacity 96.5 95.2 95.3 94.9 95.0 The first column of the Table defines a number of properties. The second column discloses the values obtained in respect of the properties listed in colum 1 when carrying out the test under a pressure of 4.5 bars in a pure nitrogen atmosphere. Column 3 discloses the values obtained in corresponding tests as i column 2, but while using air instead of nitrogen. No chemical additions were made during these tests. The water supplied to the system had a pH of about 7. A comparison between the values contained in columns 2 and 3 shows that the oxygen content of the air has a substantial influence on the properties of the pulp. The values given in column 4 were obtained by adding 1 percent by weight hydrogen peroxide. The chamber was pressurized to 4.5 bars with nitrogen. The water had a pH of about 11.5. A hydrogen peroxide stabilizer was also supplied to the system. The tests show that hydrogen peroxide has a great influence on the pulp properties. The first tests carried out in accordance with the invention and listed in column 5 were carried out at a pressure of 4.5 bars. The spray water contained 1.5 percent oxygen, 1 percent hydrogen peroxide and stabilizer. The water had pH of 11.5. The grinding chamber was pressurized with air. These tests illustrat the synergistic effect of oxygen and hydrogen peroxide. The last column of the Table illustrates the same tests as those in the pre ceding column, but with the difference that the hydrogen peroxide concentration was halved. All pressures recited relate to overpressures.

Claims: CLAIMS 1. A method of producing chemimechanical pulp, comprising grinding wood in a grinding mill housed in a grinding chamber, maintaining the chamber at an overpressure and spraying water onto the wood, characterized by supplying oxygen via the spray water to the grinding chamber. 2. A method according to Claim 1 , characterized by adding hydrogen peroxide to the spray water. 3. A method according to Claim 1 or 2, characterized in that the oxygen content is at most 5 percent by weight, prefer-ably 0.2-2 percent by weight, calculated on ground pulp. 4. A method according to one or more of Claims 1-3, characterized in that the pH of the spray water is within the range of 5-12, preferably within the range of 9-11. 5. A method according to Claim 1 , characterized in that the pressure exceeds 2 bars. 6. A method according to Claim 1 , characterized in that the pressure exceeds 4 bars. 7. A method according to one more of Claims 2-6, characterized in that the hydrogen peroxide content of the spray water is at most 4 percent by weight, preferably 0.5 to 2 percent by weight, calculated on dry pulp.

Inventors: BOKSTROEM MONICA, BOKSTROEM, MONICA
Applicants: AGA AB, BOKSTROEM MONICA, AGA AKTIEBOLAG, BOKSTROEM, MONICA
Application year: 1994
Main classification: D21B1
IPC codes: D21B1, D21C1