Anti-fretting coating

Abstract: A method is taught for protecting the surface of an alloy, particularly nickel, cobalt, or titanium alloy, from fretting wear by coating said surface with a coating consisting essentially of from about 88 to about 96 weight percent copper, from about 4 to about 8 weight percent aluminium, and from 0 to about 4 weight percent silicon.

Description: BACKGROUND OF THE INVENTION Field of the invention This invention relates to a method for increasing the high temperature fretting wear resistance of surfaces, particularly of many nickel, cobalt, and titanium alloys. Description of the Prior Art Fretting wear occurs on the mating surfaces of two parts in contact which are designed to be static, but, through transmitted forces such as vibration, oscillate relative to each other with a high frequency, low amplitude motion. Since each surface contains many microscopic asperities in contact, the fretting motion tends to cause local adhesion at these junctions, which may fracture, producing material transfer, wear debris, or both. If the metals in contact are similar, or their constituent elements have good mutual solubilities, the majority of the fretting wear will be adhesive in nature. Elevated temperature will greatly accelerate the process, as may large loads and high frequencies. If the mating surfaces become extremely abraded and gnarled, stress concentrations will result in wear scarring, and a reduction in fatigue strength will result (known specifically as fretting fatigue), causing failure of the part(s). Specific examples of materials subject to fretting wear include turbofan airfoil bladeroots, friction dampers, bearings on shafts with loose fits, and drive-coupling components. Prior art efforts to overcome the onset of fretting have included providing anti-fretting coatings on the surfaces of the materials in contact. These coatings behave as soft metallic films, keeping the substrate surfaces from coming in contact and dissipating vibrational energy by intracoating shear mechanisms. Such prior art anti-fretting coatings for nickel, cobalt, and titanium alloys have been based on Cu-Ni or Cu-Ni-In compositions. Their success is well documented. However, at temperatures above about 1000°F (538°C), accelerated oxidation will rapidly deteriorate the coatings, allowing the substrate surfaces to come in contact and fret. In addition, conventional application methods rely primarily on thermally spraying the constituents onto the desired part. This has further disadvantages due to the line-of-sight nature of thermal spraying, and the detrimental effects this type of operation has (e.g. warping) on thin-gauge materials. SUMMARY OF THE INVENTION In accordance with the method of the present invention, force-transmitting and force-receiving bearing surfaces of nickel, cobalt, and titanium alloys may be protected from fretting wear at temperatures up to 1200°F (649°C) or higher by coating either one or both of the surfaces with a coating of an alloy of copper as defined in claim 1. Preferably, the copper alloy comprises about 92 weight percent copper, and about 8 weight percent aluminium. The metallic structure and compressor airfoil root according to claims 11 and 17, respectively, are further embodiments of the invention. Additions of other elements, such as up to about 5 weight percent iron, or nickel, may provide successful results at temperatures up to about 1000°F (538°C), but generally not at the higher temperatures achieved using the above-identified alloys, as these additional elements usually degrade high temperature oxidation resistance. The thickness of the coating may be within the range of from 0.1 mils (2.5 micrometres) to about 4.0 mils (100 micrometres), and preferably within the range of from about 0.75 mils (19 micrometres) to about 1.5 mils (38 micrometres). The coating may be applied by typical physical vapour deposition techniques. Cathodic arc deposition is the preferred method, although other forms of ion vapour deposition are suitable. BRIEF DESCRIPTION OF THE DRAWING Figure 1 shows comparative results of fretting tests conducted on an uncoated nickel substrate, the same substrate having a conventional anti-fretting coating, and the same substrate having the anti-fretting coating of this invention. DESCRIPTION OF THE PREFERRED EMBODIMENTS It has been determined that coating a thin nickel or nickel alloy work-piece in accordance with the present invention yields a significant improvement in durability as opposed to uncoated work-pieces at temperatures up to at least 1200°F (649°C). The coating of the invention finds particular utility with such parts as compressor airfoil roots, but can be applied with beneficial effect to any nickel or nickel alloy surface where fretting wear is a problem, such as blade and vane airfoil damping systems. The anti-fretting coating is also beneficial for cobalt and titanium alloy surfaces. Since the coating, in accordance with the invention, is beneficial at temperatures up to approximately 1250°F (677°C), it has been found to provide advantages over conventional methods of minimizing fretting wear, which include the use of dry film lubricants and coatings of alloys, such as copper-nickel, and copper-nickel-indium, or silver plating. Such conventional coatings are deficient in being effective only at temperatures up to about 1000°F (538°C), which temperature is below the temperature encountered in many applications where fretting is a problem, such as in components of modern jet engines, e.g. compressor airfoil roots. With the coating of the present invention, it has been found that the copper and aluminium contents, particularly in the presence of silicon, minimize oxidation of the contact surfaces in the high-temperature environments encountered during use of the coated nickel-base alloy surfaces. This results in retention of the protective properties of the coating at temperatures exceeding 1000°F (538°C), at which temperatures conventional coatings are rendered ineffective. By retaining oxidation resistant properties at these elevated temperatures, resistance against fretting is maintained in applications of nickel-based alloys for which conventional coating practices are not effective. In accordance with the method of the invention, test specimens of a nickel-base alloy corresponding to AMS 5544, of the composition, in weight percent, Ni-19.5 Cr-13.5 Co-4.2 Mo-3Ti-1.4 Al-0.08 Zr-0.05C, were coated by ion vapour deposition coating. Coating was performed in a conventional low pressure inert gas vapour deposition chamber to deposit a coating thickness of 32 µm (1.25 mils) of an alloy comprising, in weight percent, Cu-7.5 Al. Test specimens prepared as above were tested in spring form on an oscillating spring-on-plate wear test facility, using plate specimens of alloy AMS 5596 as the contacting surface. Test springs of uncoated AMS 5544 and AMS 5544 coated with a conventional anti-fretting coating of 62 percent copper, 38 percent nickel were prepared and tested simultaneously for comparative results. Two springs of each specimen of 0.015 inch (0.38mm) thickness and containing a 0.050 inch (1.3mm) contact radius were loaded against two uncoated plates of 0.125 inch (3.2mm) thickness, with a load of 15 pounds (6.8kg), producing a maximum contact pressure of 1100 psi (7584 kPa). The springs were held rigid in the vertical plane while the plates were oscillated by an electromagnetic shaker at a frequency of 300 Hz and amplitude of 0.005 inches (0.13mm). The entire fixture was surrounded by a resistant-element furnace producing a temperature of 1200°F (649°C). Thickness measurements were made on the spring and plate specimens at 2-hour intervals, and the test proceeded for either 10 hours or failure, whichever came first. As shown in Figure 1, the coating of the present invention greatly reduced the fretting wear rate of the nickel substrate, as compared to the uncoated substrate and the conventional anti-fretting coating. Similar results are obtained when nickel, cobalt, and titanium substrates are tested using anti-fretting coatings of Cu-8Al, and Cu, 4-8 Al, 0-4 Si. It is to be understood that the above description of the invention is subject to considerable modification, change, and adaptation by those skilled in the art, and that such modifications, changes, and adaptations, are intended to be considered within the scope of the present invention, which is set forth by the claims which follow.

Claims: A method for protecting an alloy surface selected from the group consisting of nickel, cobalt, and titanium alloys from fretting wear, said method comprising coating said surface with a coating consisting essentially of from 88 to 96 weight percent copper, from 4 to 8 weight percent aluminium, and from 0 to 4 weight percent silicon. The method of claim 1, wherein said coating is deposited by physical vapor deposition. The method of claim 1, wherein said coating is applied by cathodic arc deposition. The method of any preceding claim, wherein said coating is characterized by anti-fretting capability at temperatures up to about 1250°F (677°C). The method of any preceding claim wherein the alloy surface is of a nickel-base alloy. The method of any preceding claim, wherein said coating consists essentially of about 92 weight percent copper and about 8 weight percent aluminium. The method of any one of claims 1 to 5, wherein said coating comprises about 92.5 weight percent copper and about 7.5 weight percent aluminium. The method of any preceding claim, wherein said coating is from about 0.1 mils (2.5 micrometres) to about 4 mils (100 micrometres) thick. The method of claim 8, wherein said coating is from about 0.75 mils (19 micrometres) to about 1.5 mils (38 micrometres) thick. The method of claim 9, wherein said coating is from about 1.0 mils (25 micrometres) to about 1.5 mils (38 micrometres) thick. A metallic structure comprising a substrate selected from the group consisting of nickel, cobalt, and titanium alloys, and an anti-fretting coating on said substrate, said coating consisting essentially of from 88 to 96 weight percent copper, from 4 to 8 weight percent aluminium, and from 0 to 4 weight percent silicon. A structure as claimed in claim 11, wherein said substrate is a nickel-base alloy. A structure as claimed in claim 11 or claim 12, wherein said coating consists essentially of copper and aluminium. A structure as claimed in claim 13, wherein said coating consists essentially of about 92.5 weight percent copper and about 7.5 weight percent aluminium. A structure as claimed in any one of claims 11 to 14 wherein said coating is from about 1.0 mils (25 micrometres) to about 1.5 mils (38 micrometres) thick. A method for reducing fretting wear between contacting surfaces at a temperature of from about 1000°F (538°C) to about 1250°F (677°C), said method comprising applying to at least one of said contacting surfaces a coating consisting essentially of from about 88 to about 96 weight percent copper, from about 4 to about 8 percent aluminium, and from 0 to about 4 weight percent silicon. A fretting-fatigue resistant compressor airfoil root for use at a temperature of from about 1000°F (538°C) to about 1250°F (677°C), comprising an airfoil root of a metal selected from nickel, cobalt and titanium alloys, the surface thereof having a coating of an alloy consisting essentially of from 88 to 96 weight percent copper, from 4 to 8 weight percent aluminium, and from 0 to 4 weight percent silicon, said coating being from 0.1 mils (2.5 micrometres) to 4 mils (100 micrometres) thick.

Inventors: BEERS RUSSELL A, MACHINCHICK MICHAEL F, NOETZEL ALLAN A, BEERS, RUSSELL A., MACHINCHICK, MICHAEL F., NOETZEL, ALLAN A.
Applicants: UNITED TECHNOLOGIES CORP, UNITED TECHNOLOGIES CORPORATION
Application year: 1994
Main classification: C23C14
IPC codes: B32B15, F01D5, C23C14