Stencil printing plate

Abstract: A printing plate and a process for plate-making which requires no particular plate-making apparatus, wherein a plate-making can easily be done simply by using a safe aqueous solvent, are provided. A printing plate has a resin layer 1 soluble in an aqueous solvent 3 and a process for plate-making comprises the steps of bringing selectively an aqueous solvent (water sign pen 2) like water in contact with the surface of the resin layer 1, and removing partially or wholly the resin layer 1 in the contact portion by dissolving the resin layer in the aqueous solvent to form a engraved or perforated portion 5. A stencil printing plate having the above resin layer adhered to a porous substrate by means of an adhesive containing a hydrophobic polymer is also provided.

Description: The present invention relates to a stencil printing plate. As a conventional printing plate, a photo-sensitive or heat-sensitive plate is known. The photo-sensitive plate is processed for plate-making by selectively irradiating light onto the plate to vary the physical properties of light-irradiated portions and non-light irradiated portions and by taking advantage of the differences in the hydrophilic and lipophilic properties of light polymeric substances, the solubilities of their solvents, the electrical properties of photo-conductive substances and the adhesive strength of light degradative substances. The heat-sensitive plate is subjected to plate-making by selectively heating the plate to vary the physical properties of the heated and non-heated portions and by taking advantage of the differences in adhesiveness of the heat-sensitive material, the differences in the hydrophilic and lipophilic properties, and the differences in the perforating property of the heat-sensitive film. This process for plate-making, however, requires an expensive plate-making apparatus hardly used in any other process than plate-making. There is also a problem that the process is complicated and the printing plate cannot be made easily. Japanese patent application laid-open No. Sho 61-12387 discloses a process for plate-making by dissolving a printing plate having a water-insoluble resin layer with a resin-soluble solvent. Japanese patent application laid-open No. Sho 59-67051 discloses a process for plate-making by dissolving a stencil plate in an acidic solution. DE-C-456,101 discloses a method of perforating a stencil printing sheet composed of a highly porous substance and a coating predetermined portions of which are removed by subsequent treatment with a solvent. A protein, specifically gelatine, is used as the coating of the stencil printing sheet, and an acidic solution is used as the solvent. However, these processes require special solutions and exhibit problems from the standpoint of safety and environmental pollution. As a stencil printing plate, a heat-sensitive stencil plate has conventionally been known which is obtained by superposing a thermoplastic resin film onto a porous substrate and adhering the same to each other. In this heat-sensitive stencil plate, processes for plate-making include (1) a process for plate-making by using a heat-generating device, such as a flash lamp or an infrared lamp, superposing a hand-written manuscript or preliminarily-prepared manuscript onto a heat-sensitive plate, and melting and perforating the thermoplastic resin film by the heat generated by the device described above, and (2) a process for plate-making by using a thermal head for generating dot-like heat zones, in accordance with letter image information converted into an electric signal, bringing a heat-sensitive stencil plate into contact with the thermal head, and melting and perforating the thermoplastic resin film. However, since the processes for plate-making described above require a series of complicated processes of bringing a light-irradiated and heat-generated manuscript or a thermal head into contact with a heat-sensitive stencil plate, conveying the heat to the thermoplastic resin film of the heat-sensitive stencil plate to melt the thermoplastic resin film, and subsequently perforating the thermoplastic resin film, some problems are experienced. These problems include (1) perforation failure due to incomplete contact between the thermoplastic resin film and a heated manuscript or a thermal head; (2) adhesion failure due to the non-uniformity of the contact pressure of the thermal head and shrinkage of the heat-sensitive stencil plate; (3) transfer failure of the heat-sensitive stencil plate due to the molten material of the thermoplastic resin film adhering to the thermal head; and (4) printing failure since material which has melted remains in the perforated portion and the passage of ink is prevented. In order to solve the problems described above, it is one aim of the present invention to provide a stencil printing plate which does not require a particular plate-making apparatus and can be conveniently perforated using a very safe aqueous solution. It is another aim of the present invention to provide a stencil printing plate which does not exhibit perforation failure, any shrinkage at the time of plate-making, or any transfer failure or printing failure in printing. The present invention provides a stencil printing plate, comprising a resin layer and a porous substrate adhered to said resin layer with an adhesive; characterized in that said adhesive is composed of a hydrophobic polymer compound and is in direct contact with said resin layer and said resin layer is composed of a water-soluble resin which is perforatable by contact with an aqueous solvent. Preferably, the solubility parameter of the hydrophobic polymer compound which is designated as an SP value determined by the square root of the coagulating energy density is 10 or less and the hydrophobic polymer compound dissolves and/or swells depending upon an ink to be used in printing. Preferably, said adhesive is included in an amount in the range of from 0.1 to 50 g/m 2 . Preferably, the hydrophobic polymer compound is at least one compound selected from styrene resin, acrylic resin, polyethylene, polybutadiene, natural rubber, styrene-butadiene co-polymer and ethylene-vinyl acetate copolymer. An embodiment of the present invention will be described hereinbelow by way of example only with reference to the accompanying drawings, in which: Fig. 1 is a sectional view showing a stencil printing plate as an embodiment of the present invention. Fig. 2 is an explanatory view showing the perforation of the stencil printing plate of Fig. 1. Fig. 3 is an explantory view showing printing using the stencil printing plate of Fig. 1. As a process for forming a resin layer on a substrate, there are exemplified a process of adhering a water-soluble resin film to a substrate or a process of coating a water-soluble resin solution dissolved or dispersed in water or an aqueous solvent onto a substrate and drying the coated substrate. The resin layer used in the present invention contains a water-soluble resin as a main component. As a water-soluble resin, a resin soluble in water or a water-miscible organic solvent can be used, such as polyvinyl alcohol, methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, polyvinyl pyrolidone, polyethylene-polyvinyl alcohol copolymer, polyethylene oxide, polyvinyl ether, polyvinyl acetal, polyacrylamide, starch, dextrin, alginic acid, ascorbic acid and water-soluble urethane. These resins may be used independently or in admixture. The resin layer may contain pigments, fillers, binders and curing agents, if necessary. The thickness of the resin layer is preferably in the range of from 0.1 to 1000 µm, and more preferably in the range of from 1 to 500 µm. When the thickness is less than 0.1 µm the strength of the stencil plate is insufficient, and when the thickness exceeds 500 µm a large amount of aqueous solvent is necessary to dissolve the resin layer, resulting often in insufficient dissolution. The aqueous solvent to be used contains water as a main component, and is preferably mixed with a water-miscible organic solvent to improve its drying property and wettability prior to use, such as methyl alcohol, ethyl alcohol, isopropyl alcohol, n-propyl alcohol, ethylene glycol, diethylene glycol, propylene glycol, glycerine, acetone, methylethyl ketone, tetrahydrofuran, 1,4-dioxane, formic acid, acetic acid, propionic acid, formaldehyde, acetaldehyde, methylamine, ethylene diamine and pyridine. From the standpoint of the solubilities of water-soluble resins, the content of these organic solvents is preferably 50 wt.% or less to water, and more preferably, 30 wt.% or less. The aqueous solvent can contain dyestuffs, pigments, fillers, binders, hardeners, antiseptics and swelling agents, if necessary. The printing plate of the present invention can be processed for plate-making as follows. First of all, an aqueous solvent is brought selectively into contact with the surface of a water-soluble resin layer, corresponding to a letter image portion, by means of a device such as a syringe, injector, brush or stamp, a writing tool such as a brush containing a black ink, fountain pen, water ball pen or water sign pen, or an instrument such as an ink jet printer. After the water-soluble resin layer is partially or wholly dissolved with an aqueous solvent, the dissolved solution is removed by wiping the surface of the resin layer. As the substrate of the printing plate is a porous substrate, the solution dissolving the resin will be absorbed into the porous substrate, and therefore such a removing step may be omitted. There is no particular limitation as to the means for bringing the aqueous solvent into contact with the resin layer. However, non-contact means such as injection and an ink jet printer are preferable, since the printing plate is not influenced by these means. When the water-soluble resin layer is brought into contact with the aqueous solvent, the resin components in the resulting contact portion dissolve to form a solution until reaching the solubility limit. Accordingly, since the dissolved amount of water-soluble resin in the contact portion can be varied, various printing plates for plate-making can be prepared by appropriately controlling both the solubility of the water-soluble resin layer and the amount of the aqueous solvent brought into contact with the water-soluble resin. For instance, after bringing the aqueous solvent selectively into contact with the water-soluble resin layer to dissolve partially the water-soluble resin layer, concave portions are formed in the resin layer by removing the solution in the region thereof. When carrying out stencil printing, a water-soluble resin layer portion, corresponding to the region where an image is presented, is brought into contact with an aqueous solvent. The required amount of aqueous solvent is a sufficient amount that the water-soluble resin layer in the image region will be completely dissolved and perforated. Stencil printing is carried out by wiping away a resin-dissolved solution and then supplying a printing ink to the perforated portions of the resin layer. As a printing ink, an oily ink used in conventional printing or an oil-in-water (w/o) type emulsion ink may be used. In the event of using a w/o emulsion ink, when the water component in the w/o emulsion ink is rich, the printing paper swells, resulting in a lowering of the paper strength. Therefore, it is preferable to set the mixing ratio of water at a value of 50 wt.% or less. The stencil printing plate according to the present invention comprises an adhesive containing a hydrophobic polymer compound between a water-soluble resin layer and a porous substrate. From this constitution, once an aqueous solvent is brought into contact with the resin layer, the aqueous solvent dissolves the resin component in a contact portion thereof up to the solubility limit, and subsequently the resulting solution is absorbed into the porous substrate. Therefore, the perforation is improved in the resin layer portion in contact with the aqueous solvent. If no adhesive containing hydrophobic polymer compound were present between the resin layer and the porous substrate, aqueous solvent brought into contact with the resin layer is liable to be absorbed into the porous substrate before it fully dissolves the resin component in the contact portion. Accordingly, the perforation in the resin layer will be insufficient. Since at the time of plate-making the solution which dissolves the resin component permeates into the porous substrate, the dissolved component is retained in the perforated portion in a manner which does not obstruct the perforations. The perforating properties of the resin layer can be altered by controlling the dissolution rate of the resin layer to the solvent and the viscosity of the dissolved solution. Incidentally, the adhesive referred to in the present invention encompasses such a material as not always exhibits an adhesive property but also a material which at least shows a temporal adhesiveness required for adhering the resin layer. The solubility parameter (which will be designated as an SP value hereinafter) of the hydrophobic polymer compound used in the above-mentioned adhesive is preferably 10 or less, and more preferably 9.5 to 7.0. If the SP value of the hydrophobic polymer compound exceeds 10, the hydrophobic polymer compound cannot easily be dissolved and/or swells due to the oil components contained in the printing ink and the permeability of the ink is often lowered, since the SP values of non-polar solvents and oils, such as high boiling point solvents and machine oils, contained in the ink as an oil component are usually 10 or less. The SP values referred to herein are a square root of the coagulating energy density of a substance. This value is used as an indication of the polarity of a substance. In general, a polymer material shows a good solubility in a solvent having an SP value close to that of the polymer material. As a hydrophobic polymer compound having an SP value of 10 or less, styrene resin (SP value 9.0), acrylic resin (SP value 9.3), polyethylene (SP value 7.9), polybutadiene (SP value 8.4), natural rubber (SP value 8.2), styrene-butadiene copolymer (SP value 8.5) and ethylene-vinyl acetate copolymer (SP value 9.0) are examples. These polymer compounds may be used individually or in admixture. The adhered amount of the adhesive is preferably in the range of from 0.1 to 50 g/m 2 , and more preferably in the range of from 0.5 to 30 g/m 2 . When the adhered amount is less than 0.1 g/m 2 the adhered strength is insufficient. When the adhered amount exceeds 50 g/m 2 the hydrophobic polymer compound takes time to dissolve and/or swells by virtue of the oil component in the ink, resulting in a lowering of the permeability of the ink. As a process for adhering a resin layer soluble in an aqueous solvent and a porous substrate with each other, the following are examples: (1) a process of coating a solution of a hydrophobic polymer compound dissolved or dispersed in a solvent onto a porous substrate, drying the porous substrate, and then adhering a resin layer soluble in an aqueous solvent to the porous substrate; (2) a process of impregnating a porous substrate with a solution of a hydrophobic polymer compound dissolved or dispersed in a solvent, drying the porous substrate and then adhering a resin layer to the porous substrate; and (3) a process of coating a solution of a hydrophobic polymer compound dissolved or dispersed in a solvent onto a resin layer, drying the resin layer and then adhering a porous substrate to the resin layer. As a resin layer soluble in an aqueous solvent, a film prepared in advance can be used. The film may be prepared by dissolving the resin in a solvent, coating the resulting solution onto a peeling sheet, drying the sheet, and peeling the resin film from the sheet, if necessary. The above-mentioned solution may be coated directly onto an adhesive layer on a substrate, which substrate is then dried. Incidentally, the above-mentioned peeling sheet may be peeled off after the resin layer is adhered to the porous substrate. As a resin for the resin layer soluble in an aqueous solvent, polyvinyl alcohol, methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, polyvinyl pyrolidone, polyethylene-polyvinyl alcohol copolymer, polyethylene oxide, polyvinyl ether, polyvinyl acetal and polyacrylamide are examples. The aqueous solvent refers to water or a water-miscible organic solvent. These resins may be used independently or in admixture. Also, they may contain dyestuffs, pigments, fillers, binders and curing agents. The thickness of the resin layer is normally in the range of from 0.1 to 100 µm, and preferably in the range of from 1 to 50 µm. As a porous substrate used in the present invention, a thin paper, a screen cloth, or a non-woven fabric of natural fibers such as Manila hemp, pulp, Kozo (paper mulberry), Mitsumata (Edgeworthia papyrifera) or Japanese paper, synthetic fibers such as polyester, polyamide, polyvinyl acetate or polyvinyl alcohol, metal fibers, glass fibers or a mixture thereof can be used. The basis weight of the porous substrate is preferably in the range of from 1 to 20 g/m 2 , and more preferably in the range of from 5 to 15 g/m 2 . When the basis weight is less than 1 g/m 2 the resulting strength is too weak to act as a substrate. When the basis weight exceeds 20 g/m 2 the permeability of the ink is often poor at the time of printing. The thickness of the porous substrate is preferably in the range of from 5 to 100 µm, and more preferably in the range of from 10 to 50 µm. When the thickness is less than 5 µm the resulting strength is too weak to act as a substrate, and when the thickness exceeds 100 µm the permeability of the ink is often poor at the time of printing. As an aqueous solvent which dissolves the resin layer, water, solvents of alcohol type, ketone type, ester type, ether type, aldehyde type, carboxylic acid type, amine type and low molecular heterocyclic compounds, can be used. Specifically, water, methyl alcohol, ethyl alcohol, isopropyl alcohol, n-propyl alcohol, butyl alcohol, ethylene glycol, diethylene glycol, propylene glycol, glycerine, acetone, methylethyl ketone, ethyl acetate, ethyl ether, tetrahydrofuran, 1,4-dioxane, formic acid, acetic acid, propionic acid, formaldehyde, acetaldehyde, methylamine, ethylene diamine, dimethyl formamide, pyridine and ethylene oxides are examples. These solvents may be used independently or in admixture. These solvents can contain dyestuffs, pigments, fillers, binders, curing agents, antiseptics, swelling agents, surfactants and pH controllers, if necessary. Plate-making of the stencil printing plate of the present invention may be carried out by bringing a means, such as a brush pen impregnated with an aqueous solvent, into contact with a resin layer directly, but it is preferable to perform plate-making by supplying the aqueous solvent in a non-contact condition from a releasing device to the resin layer so as to perforate the same. As a releasing means, a releasing device provided with a nozzle, slit, injector or porous material (or film) connected to a feed pump, piezoelectric element or heating element so as to release the solvent intermittently or continuously, in other words, in dot or line form, in accordance with a letter image signal, are examples. According to such a method, plate-making can be performed in a non-contact condition of the stencil printing plate with a plate-making apparatus, and therefore, shrinkage or deformation of the printing plate can be prevented at the time of plate-making. In addition, different from a conventional heat-sensitive plate, as the melted resin material at the time of plate-making is not left in the perforated portion, brilliant printed matter can be obtained. Further, there is no need to provide a peeling property, anti-friction or mechanical strength as required in a conventional heat-sensitive stencil plate. The stencil printing plate of the present invention can be used in a normal stencil printing process. For example, an ink is fed onto one side of the plate after plate-making, a printing paper is attached on the other side of the plate, and then ink is passed through the perforated portion by means of pressing or squeezing to transfer the ink to the printing paper, resulting in printed matter. As a printing ink, an oily ink used in conventional printing or an oil-in-water drop (w/o) type emulsion ink can be used. As the oil components in these inks, liquids, such as high boiling point solvents, high boiling point oils, machine oils and surfactants, are contained to provide the necessary fluidity, permeability and stability. Since these components are dissolved and/or swell on being brought into contact with a hydrophobic polymer compound used as an adhesive component, the permeation of the ink becomes easy. Fig. 1 is a sectional view showing a stencil printing plate in accordance with an embodiment of the present invention. In the drawing, a stencil printing plate 101 comprises a porous substrate 103 and a resin layer 102 soluble in an aqueous solvent adhered to each other by an adhesive 104. Fig. 2 is an explanatory view showing the perforation of the stencil printing plate of the present invention. In the drawing, an aqueous solvent 105 is released from a releasing means 109 so as to be brought into contact with the surface of the resin layer 102 soluble in the aqueous solvent 105. The contacted aqueous solvent 106 dissolves the resin layer 102 in the contact portion to give a resin solution, which permeates into the porous substrate 103 through the layer of the adhesive 104, resulting in perforation of the resin layer 102 in the contact portion. Reference sign 107 shows a resin solution permeated into the porous substrate 103, and reference sign 108 shows a perforated portion of the resin layer 102. Fig. 3 is an explanatory view showing printing by means of the stencil printing plate of the present invention. In the drawing, when an ink 110 is fed onto the resin layer soluble in the aqueous solvent of the stencil printing plate 101 and squeezed, the ink 110 is transferred to a printing paper 113 through the porous substrate of the stencil printing plate 101 from the perforated portion. Reference sign 111 shows ink passing through the perforated portion, and reference sign 112 shows ink transferred to the printing paper 113. The present invention will be explained in detail with reference to the following Examples. It should be understood, however, that these Examples are not intended to limit the scope of the claimed invention. Incidentally, each part in the following Examples will be represented by weight. Example 1 A stencil printing plate shown in Fig. 1 was prepared as follows. A resin solution consisting of polyethylene oxide (15 parts), isopropyl alcohol (15 parts) and water (70 parts) was coated by a reverse coater onto a silicone treated paper and the coated paper was dried to form a resin layer of 3 µm in thickness. A polyester fiber cloth having a sieve opening of 300 mesh as a substrate was immersed in an adhesive solution consisting of acrylic resin (SP value 9.3, 20 parts), isocyanate (5 parts), toluene (45 parts) and ethyl acetate (30 parts), and then drawn up and dried. After drying, the adhered amount of the adhesive was 5 g/m 2 . The above-mentioned resin layer was superposed on the polyester fiber cloth, left in a constant temperature chamber at 40°C over night, and then a separating paper on the resin layer was peeled off to give a stencil printing plate. An aqueous solvent consisting of isopropyl alcohol (20 parts), ethylene glycol (10 parts) and water (70 parts) was released in a letter shape from a releasing means provided with a nozzle of 8 dots/mm and a piezoelectric element onto the surface of the resin layer of the stencil plate and the resin component (polyethylene oxide) of the releasing portion was dissolved, resulting in perforation of the resin portion. A black oily ink consisting of carbon black (10 parts), alkyd resin (20 parts), rosin modified phenolic resin (10 parts) and Niseki (Registered Trademark) #4 solvent (60 parts) was provided on the stencil plate after plate-making, followed by superposing a printing paper on the other side of the printing plate, and squeezing the ink by a blade through the printing plate. As a result, brilliant black letters corresponding to the perforated portions were printed on the printing paper. Example 2 Example 1 was repeated except that a solution consisting of ethylene-vinyl acetate copolymer (SP value 9.0, 20 parts), toluene (40 parts) and methylethyl ketone (40 parts) was used as the adhesive solution and the adhered amount of the adhesive was made to 10 g/m 2 . The plate-making and printing of the stencil plate thus obtained was carried out in the same manner as in Example 1. As a result, good printed matter was obtained. Example 3 A resin solution consisting of polyvinyl ether (15 parts), methyl alcohol (15 parts) and water (70 parts) was coated by a reverse coater onto a polypropylene film of 40 µm in thickness, followed by drying to form a resin layer (3 µm in thickness) soluble in an aqueous solvent. Next, a pressure sensitive adhesive solution consisting of polybutadiene (SP value 8.4, 20 parts) and toluene (80 parts) was coated by a gravure coater onto a polyester fiber cloth having a sieve opening of 300 mesh, and dried to adhere a pressure sensitive adhesive in an amount of 10 g/m 2 thereon. Subsequently, this pressure sensitive adhesive and the above-mentioned resin layer were superposed on each other and adhered by a pressure roller at 5 kg/cm 2 . Then, the polypropylene film was peeled off from the resin layer to obtain a stencil printing plate 101 as shown in Fig. 1. In the drawing, reference sign 102 is a resin layer, reference sign 103 is a porous substrate, and reference sign 104 is an adhesive. An aqueous solvent consisting of isopropyl alcohol (15 parts), glycerine (5 parts) and water (80 parts) was released in a letter shape from a solvent releasing means provided with a nozzle of 8 dots/mm and a heating element onto the stencil plate and the resin component (polyvinyl ether) in the released portion was dissolved for perforation. Then, an oily ink the same as that used in Example 1 was deposited on the stencil plate after plate-making, a printing paper was superposed thereon and impressed, and a brilliant letter image corresponding to the perforated portion was printed on the printing paper. Example 4 A pressure sensitive adhesive solution consisting of styrene-butadiene copolymer (SP value 8.5, 30 parts) and toluene (70 parts) was coated onto a polyvinyl alcohol film 102 of 5 µm in thickness and dried to obtain a pressure sensitive adhesive 104 in an amount of 15 g/m 2 adhered thereon as shown in Fig. 1. A Japanese paper 103 having a basis weight of 12 g/m 2 was adhered on the adhesive layer 104 by a pressure roller at 5 kg/cm 2 to provide a stencil plate 101 as shown in Fig. 1. Following the same process as that of Example 3, plate-making was performed on the stencil plate thus obtained, followed by printing. As a result, good printed matter was obtained. Example 5 A resin solution consisting of polyvinyl acetal (15 parts), isopropyl alcohol (15 parts) and water (70 parts) was coated by a reverse coater onto a polypropylene film of 40 µm in thickness and dried to form a resin layer soluble in an aqueous solvent of 3 µm in thickness. Then, an adhesive solution consisting of styrene resin (SP value 9.0, 20 parts), toluene (40 parts) and methylethyl ketone (40 parts) was coated onto the resin layer as described above by a gravure coater so as to obtain an adhered amount of 10 g/m 2 after drying. A Japanese paper as a porous substrate having a basis weight of 12 g/m 2 was adhered to the resin layer through the adhesive, followed by drying to obtain a stencil printing plate. Following the same process as that of Example 3, plate-making was performed on the stencil plate thus obtained, followed by printing. As a result, good printed matter was obtained. Using the stencil printing plate of the present invention, plate-making can be performed easily and safely with no particular apparatus. According to the stencil printing plate of the present invention, perforation can be done in a non-contact condition using an aqueous solvent, and therefore, perforation failure at the time of plate-making, shrinkage and transfer failure can be prevented. Since a hydrophobic polymer compound is used as an adhesive, the perforation of the resin layer by using an aqueous solvent is made sufficiently and brilliantly. Furthermore, a hydrophobic polymer compound is dissolved and/or swells depending upon the ink components, the permeation of the ink at the time of printing becomes good and brilliant printed matter can be obtained.

Claims: A stencil printing plate (101), comprising a resin layer (102) and a porous substrate (103) adhered to said resin layer (102) with an adhesive (104); characterized in that said adhesive (104) is composed of a hydrophobic polymer compound and is in direct contact with said resin layer (102) and said resin layer (102) is composed of a water-soluble resin which is perforatable by contact with an aqueous solvent. A stencil printing plate according to claim 1, wherein the solubility parameter of the hydrophobic polymer compound which is designated as an SP value determined by the square root of the coagulating energy density is 10 or less and the hydrophobic polymer compound dissolves and/or swells depending upon an ink to be used in printing. A stencil printing plate according to claim 1, wherein said adhesive (104) is included in an amount in the range of from 0.1 to 50 g/m 2 . A stencil printing plate according to claim 1, wherein the hydrophobic polymer compound is at least one compound selected from styrene resin, acrylic resin, polyethylene, polybutadiene, natural rubber, styrene-butadiene co-polymer and ethylene-vinyl acetate copolymer.

Inventors: WATANABE HIDEO, WATANABE, HIDEO,, WATANABE, HIDEO, C/O RISO KAGAKU CORPORATION
Applicants: RISO KAGAKU CORP, RISO KAGAKU CORPORATION
Application year: 1994
Main classification: B41C1
IPC codes: B41C1