MODIFICATION OF EDIBLE OIL FLAVOUR

Abstract: A useful method for shifting the flavour balance of edible oils comprises sparging nitrogen through the oil at a temperature of 20-65 DEG C. Olive oil is preferably treated at 30-40 DEG C. The treatment may be combined with usual purification steps as are washing and filtration over a filter aid.

Description: Modification of edible oil flavour The present invention is concerned with a method for treating edible oil, particularly olive oil. Olive oil is offered on the market in a range of qualities and tastes. Olive oil of good quality is characterized by a fragrant and delicate flavour which is appreciated by the international gourmet and cherished by the native consumer. Even good quality olive oils widely vary in their flavour balance analogous to the multitude of wine varieties. The best quality olive oils are found in the group named virgin olive oils. The taste of olive oil may vary widely and is partly determined by the origin of the olive culture. The taste may, for example, be influenced by the composition of the soil. An oil from one region may have a taste quite different from a neighbouring region. On account of yearly differences in harvest yields shortages may arise of specific types of olive oil. A shortage in one region or country might be easily compensated by a greater supply in another region or country, if not barriers would exist which are caused by consumers flavour appreciation. Some high quality oils have a peculiar flavour which may not be appreciated by consumers who are not accustomed to that flavour. Therefore a need exists for a method which allows a slight shift in the flavour balance of olive oil. A known method for influencing the flavour of edible oils is sparging them with steam or an inert gas, generally with nitrogen. However, for obtaining sufficient odour removal high temperatures, at least 180°C are applied. In EP 0 405 601 a method is given for deodorising olive oil by sparging nitrogen through olive oil heated at a temperature of at least 180°C. Such treatments are aimed at removing all volatile odiferous substances. Even flavour components which are appreciated disappear under such relatively drastic conditions. In EP 0 475 573 a method is given for transferring attractive flavour components from one oil, a so-called flavorant oil, to another recipient oil. An inert gas such as nitrogen is conducted through the flavorant oil, which is heated to temperatures of at least 65.6°C. While the flavorant oil gets exhausted the inert gas loaded with flavour components is conducted through a relatively cooler oil which absorbs the flavour components from the flavour loaded nitrogen. SUMMARY OF THE DESCRIPTION The above mentioned prior art methods are rather intruding and are primarily directed to the removal of flavours. A less fragrant oil is left behind. However, now a method has been found for treating an edible oil, particularly olive oil. This treatment causes in a mild and delicate way a slight shift in the flavour balance which might be perceived as attractive. The method comprises conducting under reduced pressure inert gas through the oil, provided the temperature is maintained at very moderate levels being 20-65°C. The use of the invention results in an oil which in comparison with the source oil has a slightly shifted flavour balance and which appeals to another and often a larger group of consumers. DETAILS OF THE INVENTION The oil which is subjected to the mild treatment of the invention, might be any edible oil with a flavour, particularly oils which derive their commercial value from an appreciated flavour. A preferred oil is olive oil, more particularly an olive oil from southern Spain with a characteristic strong flavour. In this context a mild treatment is conceived to be a non- intrusive treatment which does not alter the molecular structure of the oil and which does not expose the oil to chemical or to extreme physical conditions such as temperatures over 100°C. The invention relates to a process comprising sparging an edible oil with an inert gas, preferably under reduced pressure, particularly 1-20 mbar and more preferably 5-18 mbar. The inert gas might be any inert gas such as e.g. helium, but preferably is nitrogen. A suitable amount of nitrogen is 0.1 - 25 m 3 of nitrogen per kg of oil. Volumes are to be measured under the pressure to which the oil is exposed. The sparging treatment is carried out at 20-65°C, and preferably at 55-65°C. When treating olive oil a temperature is observed which preferably is 30-40°C. The optimum sparging time for obtaining the desired flavour effect should be established from case to case. When the treatment proceeds, a gradual shift of the flavour balance can be observed. An optimum combination of time, pressure and temperature can be easily found by observation of this flavour shift. In general a suitable sparging time can be found in the range of 0.5-10 hours and preferably is 1-5 hours. Obviously the longer times are necessary when the sparging temperature is relatively low. The inert gas treatment may be combined with other oil treatments such as washing with water and/or a filtration step preceding or following the sparging treatment. It is particularly advantageous to have the olive oil filtered through a filter aid, such as Lignocell™ or Hyflo™. The described invention provides a useful method for shifting the flavour balance of olive oils. It enables an adaptation of the flavour to varying consumer wishes. This method may increase the flexibility of the market for olive oils. The invented treatment is remarkably mild and sparing for the oil, so that it may comply with trade regulations for olive oil processing. For the identification of edible oils which have been subjected to the treatment of the invention use can be made of the contents of oσtanol-1 and hexanol-1 both being usual components of edible oils. Before treatment these alcohols are present in concentrations of which the ratio [octanol- 1] : [hexanol-1] is lower than 0.5. Sparging the oil according to the invention partly removes both octanol-1 and hexanol-1, but the more volatile hexanol-1 to a greater extent, which causes an upward shift in the ratio [octanol-1] : [hexanol-1] . Therefore the invention is also embodied in an edible oil, preferably olive oil, containing octanol-1 and hexanol-1, characterised in that the ratio of the octanol-1 and hexanol-1 concentrations is higher than 1, preferably higher than 5. Example 1 Sparging of olive oil with nitrogen Filtered Andalusian olive oil was washed 6 times with 10 wt.% of water of 40°C. The mixture was subsequently centrifuged and dried at 40°C and at 200 mbar for 30 minutes while being stirred with a tipspeed of 2.45 m/s. Then 0.2% of Hyflo™ was added. The oil was left for 10 minutes at 40°C and at 800 mbar while being stirred with a tip speed of 2.45 m/s. The filtration was carried out at 3 bar overpressure. The oil was then sparged with 15 3 of nitrogen per kg of oil for 90 minutes at 40°C and at 7 mbar. Example 2 Sensory appraisal of treated olive oil To a trained panel of 15 persons three olive oils A, B and C were submitted for sensory appraisal. Oil A is a filtered Andalusian olive oil. Oil B is obtained by subjecting oil A to a further treatment comprising the process, as described in detail in example 1 including sparging with nitrogen. Oil C is a marketed olive oil selected because it has a flavour balance which is considered a desired target. The panel assessed the three oils. Scores were given for sensory properties comprising 61 attributes divided over the categories Smell, Odour, Mouthfeel, Taste and Aftertaste (collected in Table 1) . The flavour balance (sensory profile) has been graphically visualised by connecting the scores of each attribute, resulting in a sensory profile graph (see figures 1-4) . The sensory profiles for oil A (Untreated) , oil B (Treated) and C (Desired) are depicted in the same figure for comparison purposes. The overall impression according to the panel was that oil B had a taste which was very much alike those of oil C. In contrast untreated oil A was clearly perceived different from oil C. This overall impression was confirmed by the appraisal of the specific sensory attributes. The graphs of figures 1-4 clearly show that the nitrogen treatment had a positive influence on the sensory profile of the source oil and has caused a shift into the direction of the desired olive oil flavour balance. TABLE 1 Flavour and sensory attributes Number smell (1-7 not relevant for the purpose) 8 odour intensity 9 sea breeze on the beach 10 prickling 11 apple 12 twig 13 pine/harshy 14 dry wood 15 lemon 16 orange 17 soft fruit (straw, raspberry) 18 candies (fruit) 19 wild flowers in spring 20 fermenting fruit 21 farm 22 oil for salads (bean oil) 23 tallow 24 rancid 25 cod liver oil 26 nuts 27 medicin 28 earthy taste 29 taste intensity 30 sweet 31 sally 32 sour 33 vinegar 34 olives 35 green leaf 36 grass 37 green banana (not ripe) 38 dried green herbes 39 grounded pepper (b/w) 40 red chili pepper 41 cream/butter 42 rancid 43 cocos 44 caramel 45 grotty 46 slightly burned/taste 47 ash tray 48 velpon (glue with ethylacetate) 49 refinery 50 metallic 51 bitter mouthfeel 52 velvet like 53 sticky 54 astringent aftertaste 55 green 56 fruity 57 velpon (see above) 58 cocoa butter/white choc. 59 putty/linseed oil 60 used frying oil 61 trany 62 dry wood 63 dusty after mouthfeel 64 cooling/evaporating 65 rough 66 dry 67 sharp/etching 68 pungent

Claims: CLAIMS 1. Method for shifting the flavour balance of an edible oil by a mild treatment, characterised in that the treatment comprises sparging the oil with an inert gas at a temperature of 20-65°C. 2. Method according to claim 1, characterised in that the inert gas is nitrogen. 3. Method according to any one of claims 1 - 2, characterised in that the temperature is 55-65°C. 4. Method according to claim 1 or 2 , characterised in that the edible oil is olive oil. 5. Method according to claim 4, characterised in that the temperature is 30-40°C. Method according to any one of claims 1-5, characterriised in that 0.1 - 25 m 3 of nitrogen per kg of oil is spent. 7. Method according to any one of claims 1-6, characterised in that the sparging treatment is combined with a washing treatment and/or a filtration with a filter aid. 8. Method according to any one of claims 1-6, characterised in that the treatment is carried out at reduced pressure, preferably 5-18 mbar. 9. Edible oil containing octanol-1 and hexanol-1, characterised in that the ratio of the octanol-1 and hexanol-1 concentrations is higher than 1. 10. Edible oil according to claim 9, characterised in that the ratio is higher than 5. 11. Edible oil according to claims 9 or 10, characterised in that the edible oil is olive oil.

Inventors: HOFMAN CORNELIS, KOUUMDJIEV MARCHO STEFANOV, KUIN ADRIANUS JOZEF, VAN AALST GERARDUS MARINUS, VAN PUTTE KAREL P A M, HOFMAN, CORNELIS, KOUUMDJIEV, MARCHO, STEFANOV, KUIN, ADRIANUS, JOZEF, VAN AALST, GERARDUS, MARINUS, VAN PUTTE, KAREL, P., A., M.
Applicants: AALST GERARDUS MARINUS VAN, HOFMAN CORNELIS, KOUUMDJIEV MARCHO STEFANOV, KUIN ADRIANUS JOZEF, PUTTE KAREL P A M VAN, UNILEVER NV, UNILEVER PLC, HOFMAN, CORNELIS, KOUUMDJIEV, MARCHO, STEFANOV, KUIN, ADRIANUS, JOZEF, UNILEVER N.V., VAN AALST, GERARDUS, MARINUS, VAN PUTTE, KAREL, P., A., M.
Application year: 1994
Main classification: A23D9
IPC codes: A23D9