Formation of silicided junctions in deep sub-micron MOSFETS by defect enhanced CoSi2 formation

Abstract: A method of providing defect enhanced CoSi2 formation and improved silicided junctions in deep submicron MOSFETs. A silicon wafer having a diffusion window is first precleaned with hydrofluoric acid. After the HF precleaning, the silicon wafer is transferred to a conventional cobalt sputtering tool where it is sputter cleaned by bombardment with low energy Ar+ ions so as to form an ultra-shallow damage region (7). After the sputter cleaning, and without removing the wafer from the sputtering tool, Cobalt metal (4) is deposited on the silicon wafer at room temperature and a CoSi2 layer is formed in the diffusion window.

Description: I. Background of the Invention A. Field of the Invention This invention relates to an improved method of forming semiconductor integrated circuit devices and more particularly to an improved method of forming silicided junctions as part of such devices. B. Related Art Silicides provide low sheet and contact resistance in deep sub-micron MOSFETs (MOSFETS having junction depths smaller than 150 nm (1500 Angstroms)). Self-aligned silicide processes are useful in deep sub-micron MOSFETS. The drive-in of dopants from silicides also lowers the generation of defect induced junction leakage current. The silicide formation at the silicon surface is determined by the properties of the metal/silicon interface. The deposition of highly pure metal and a clean surface are required for silicide reaction. Any residues or contaminants lead to non-uniform and rough silicide layers. The process of integration requires the formation of a stable silicide phase. Metastable silicide layers may interfere with adjacent layers and influence the performance of the devices. The mechanism of the silicide formation and the thermal budget of the integrated process determine the grain size of the cobalt silicides. A high surface energy of cobalt silicide grains leads to an agglomeration of large silicide grains during the annealing process. The grains may even penetrate the diffusion layer. Eventually, an epitaxial regrowth of silicon between the silicide grains degrades the silicide layers. Leakage currents of such silicided junctions are increased by some orders of magnitude. Conventionally, the cleaning of the silicon surface is performed with hydrofluoric acid (HF) prior to the metal deposition. The thermodynamically stable CoSi2 phase is formed at an annealing temperature of 750 degrees Celsius (30 seconds, rapid thermal annealing RTA) via the Co2Si and CoSi phases. This results in a rough suicide/silicon interface. Further processing, such as ion implantation into the silicide, can lead to damage of the silicon crystal if the suicide film is pulled off the corner of the diffusion windows. The large grains agglomerate at higher annealing temperatures, i.e. during the drive-in of the dopants. Neither an HF dip, and HF bath or HF spraying procedure guarantee a uniformly clean silicon surface in diffusion windows (adhesion, surface energy). Cleaning the corners of diffusion windows efficiently is especially problematic. The disadvantages are rough silicide/silicon interfaces and highly stressed silicide layers which will often lead to heavy agglomeration, layer degradation and leaky junctions. A method of forming a metal silicide on an exposed surface area of a semiconductor substrate is described in EP-A-325 328. Prior to the deposition of the metal, the exposed surface areas are subjected to an in-situ sputter etch with inert ions to remove oxide. Preferably , Ar+-ions with an energy from 30eV to 300 eV are used. After the metal deposition the substrate is subjected to an annealing step, during this annealing the metal suicide is formed. A similar method to form a cobalt disilicide layer which uses an in-situ sputter etch with inert ions prior to the cobalt deposition and an annealing step after the deposition is described in the article IEEE Transact. ED 36 (1989) Nov., No.11, p.2440-2446. II. Summary of the Invention The present invention provides defect enhanced CoSi2 formation and improved silicided junctions in deep submicron MOSFETs. According to one aspect of the present invention, a silicon wafer is first precleaned with hydrofluoric acid. After the HF precleaning, the silicon wafer is transferred to a conventional cobalt sputtering tool where it is sputter cleaned by bombardment with low energy ions. The low energy bombardment forms an ultra-shallow damage region in the bulk silicon. After the sputter cleaning, cobalt metal is deposited on the silicon wafer at room temperature so as to form the CoSi2 layer. III. Brief Description of the Drawings The present invention will be better understood by reference to the drawings, in which: FIG. 1 shows an uncleaned silicon wafer having a diffusion window open in the oxide isolation so as to expose the bulk silicon; FIG. 2 shows the silicon wafer of FIG. 1 after HF dip and sputter cleaning according to an embodiment of the present invention; FIG. 3 shows the silicon wafer of FIG. 2 after cobalt deposition according to an embodiment of the present invention; FIG. 4 shows the silicon wafer of FIG. 3 after conventional selective wet etching of the unreacted cobalt; and, FIG. 5 is a flow chart of a method of forming silicided junctions in a deep sub-micron MOSFET according to an embodiment of the present invention. Like reference numerals appearing in more than one Figure depict like elements. IV. Detailed Description of the Preferred Embodiment First, silicon wafers which have been precleaned in an HF dip (in a conventional manner) are transferred to a conventional cobalt sputtering tool. FIG. 1 shows an uncleaned silicon wafer 6 having a diffusion window 5 open in the oxide isolation 1 so as to expose the bulk silicon 2. Formation of the diffusion window is accomplished in a conventional manner and is not the subject of this invention. According to an embodiment of the present invention, silicon wafers of the type shown in FIG. 1 are first precleaned in an HF dip and then transferred to a conventional cobalt sputtering tool. Next, the tool is evacuated and the wafers' silicon surfaces are sputter cleaned, in the cobalt sputtering tool, with low energy Ar+ ions. For example, in an Applied Materials AME 5500 Cobalt sputtering tool, the appropriate parameters for the sputter cleaning are 1.5 keV at 1 µA for 10 minutes. It should be understood, that the present method contemplates that the time and energy values could vary from those in the example depending upon the characteristics of the sputtering tool. A typical range for the time and energy values is 0.5 - 1.5 keV at 1 - 2 µA for 10 - 15 minutes. In any event, the selected energy level must avoid radiation damage in the bulk substrate while damaging only the uppermost layers (in the range of three to twenty monolayers) of the silicon exposed by the diffusion window. FIG. 2 shows the silicon wafer of FIG. 1 after the HF dip and sputter cleaning. During the HF dip, a portion of the oxide isolation 1 is removed from each wafer 6. The low energy Ar+ ion bombardment during sputter cleaning causes the several monolayers of the exposed surface of the bulk silicon 2 to be damaged. This sputter induced, ultra shallow damage region 7 provides a significantly larger number of nucleation sites 8 for silicide formation than would otherwise be achieved with a smooth HF cleaned only sample. An advantage of the low energy used during sputtering is that the depth of the damage region can be better controlled and limited to a small number of monolayers (typically about 20). This also causes the nucleation sites to be more evenly disbursed within the damage region. Also, advantageously, the sputter induced damage is not dependant on the topography of the product wafers. The silicon surface at mask edges or in diffusion windows is equally exposed to the Ar+ ions. Next, at room temperature (about 25 degrees Celsius), cobalt metal 4 is deposited on the wafers using the same cobalt sputtering tool in which the wafers were sputter cleaned. FIG. 3 shows the silicon wafer of FIG. 2 after the cobalt deposition. Advantageously, the wafers are not removed from the Cobalt sputtering tool. Thus, there is no exposure to air and no contamination chalks the cleaning and the deposition steps. The advantage of the presputtering (described above) is the defect induced formation of the thermodymanically stable CoSi2 phase in an exothermal reaction. Thus, the CoSi2 layer 3 is formed during the metal deposition at room temperature. CoSi2 layers of less than 30 nanometers are formed without any annealing step. Thicker CoSi2 layers are formed without phase transitions at low temperatures, because of the high diffusivity of cobalt and the isotropic CoSi2 phase. It should be understood that an annealing step of about 700-800 degrees Celsius can be added after the sputter process which will cause the damage to become shallower. Even with such an annealing step, the number of damaged sites will typically be sufficient for a stable CoSi2 layer. After the cobalt deposition, the wafers are wet etched in a conventional manner so as to remove the deposited unreacted cobalt. FIG. 4 shows the silicon wafer of FIG. 3 after the conventional selective wet etching. FIG. 5 (steps 502-512) is a flow chart summary of the above-described method of forming silicided junctions in a deep submicron MOSFET. An advantage of the present invention is that the thermal stability of the CoSi2 layers is improved. Ion implantation into the silicide will not generate any crystal damage in the silicon. Further, the silicide layers do not degrade during the outdiffusion of dopants. Other advantages of the present invention include the provision of a highly reproducible process, uniform silicide layers (little or no agglomeration) and controlled CoSi2 formation. The present invention also provides improved thermal stability of the CoSi2 junctions and improved junction leakage. After the sputter preclean, the silicide/silicon interface is smooth. Therefore, the junction depth is better defined and leaking pipes of CoSi2 through ultra-shallow junctions are prevented. Many modifications of the above-described preferred embodiments will now occur to those skilled in the art. Thus it should be understood that the preferred embodiments are described by way of example and not by way of limitation, the scope of the invention being defined by the appended claims.

Claims: A method of forming silicided junctions in asubmicron MOSFET comprising the successive steps of : precleaning a silicon wafer (6), having a diffusion window (5) formed therein, with hydrofluoric acid; transferring the silicon wafer to a cobalt sputtering apparatus, and sputter cleaning the silicon wafer by bombardment with low energy ions; without removing the silicon wafer (6) from the cobalt sputtering apparatus, depositing cobalt metal (4) on the silicon wafer characterised by damaging only from 3 to 20 monolayers of the silicon exposed by the diffusion window by the sputter cleaning; and depositing the cobalt metal (4) at room temperature and forming a cobalt disilicide (CoSi2) layer (3) in the diffusion window (5) without any further annealing step. The method of Claim 1 wherein the bombardment with low energy ions is performed using Ar+ ions with an energy in the range 0.5 - 1.5 keV at 1 - 2 µA. The method of claim 2 wherein the bombardment with Ar+ ions occurs for 10 - 15 minutes. The method of any of claims 1 - 3 wherein the CoSi2 layer (3) formed during the deposition of the cobalt metal (4) is less than 30 nanometers in depth.

Inventors: DOEBLER UWE, HAENSCH WILFRIED, SCHWALKE UDO, ZEININGER HEINRICH, ZELLER CHRISTOPH, DOEBLER, UWE, HAENSCH, WILFRIED, SCHWALKE, UDO, ZEININGER, HEINRICH, ZELLER, CHRISTOPH
Applicants: SIEMENS AG, SIEMENS AKTIENGESELLSCHAFT
Application year: 1994
Main classification: H01L21
IPC codes: H01L29, H01L21