Curable compositions containing an anaerobically inactive hydrosilation catalyst and method for preparing said compositions

Abstract: The present invention utilizes a class of hydrosilation catalysts that are inhibited in the absence of molecular oxygen to prepare storage stable, one part curable compositions containing (1) compounds with alkenyl radicals and (2) compounds with silicon-bonded hydrogen atoms. The compositions are stable until exposed to molecular oxygen, at which time they cure in the same manner as conventional compositions containing these ingredients.

Description: This invention relates to curable compositions that can be stored for extended periods of time in the absence of molecular oxygen while containing a platinum-group metal based hydrosilation catalyst which is at least partially inhibited under anaerobic conditions. Curing of the compositions is achieved by exposure to molecular oxygen, which activates the catalyst and initiates curing of the composition under either ambient conditions or with heating. Curable compositions containing polyorganosiloxanes or organosiloxane-modified organic polymers yield crosslinked products ranging from flowable gels to elastomers to resins and find use in a wide variety of applications. These compositions can be classified based on the reaction and the conditions used to cure the compositions. One class of compositions cure by a hydrosilation reaction that is catalyzed by a metal from the platinum group of the periodic table or a compound of such a metal. These metals include platinum, rhodium and palladium. The advantages of a hydrosilation reaction include the absence of moisture or excessively high temperatures to initiate the curing reaction. The curing reaction occurs when all of the reactants, namely an organic polymer or polyorganosiloxane containing at least two alkenyl radicals per molecule and a compound containing at least two silicon bonded hydrogen atoms per molecule, are combined with the hydrosilation catalyst under ambient conditions. The disadvantage of this type of curable composition is its poor storage stability. One method for overcoming this disadvantage is to prepare a two part composition by packaging the hydrosilation catalyst and the compound containing the silicon-bonded hydrogen atoms in separate containers. Another approach involves one-part curable compositions with storage stabilities ranging from days to months depending upon the temperature that are prepared using known platinum catalyst inhibitors or acetylenic compounds and amines. Alternatively, the hydrosilation catalyst can be encapsulated in a material that is melted or fragmented to release the catalyst when it is desired to cure the composition. All of these methods have disadvantages associated with them, including increased cost, relative high curing temperature and/or extended curing times. Patents representative of the prior art for such curable compositions are US-A 4,578,497; US-A 4,526,954; US-A 3,249,580; US-A 3,188,300 and EP-A 0 511 882. Technical literature also representative of this art are Lewis, L. and Lewis, N., Chem. of Materials, Vol 1, No. 1, pp 106-114 (1989); Lewis, L., J. Am. Chem. Soc., Vol 112, No 16, 5998-6004 (1990); Lewis, L. and Uriate, R., Organometallics, Vol 9, pp 621-625 (1990); Harrod, J. F. and Chalk A. J., Organic Synthesis via Metal Carbonyls, Wender, I. and Pino, P. Editors, Vol 2, pp 672, 682-683, John Wiley & Sons, New York, New York, (1977); Dickers, H. et al., J. Chem. Soc., Vol 2, pp 308-313, Dalton Transactions (1980). The effect of anaerobic conditions, i.e., the absence of molecular oxygen, on the platinum-catalyzed reaction between organohydrogensilanes and alkenes or non-polymeric organosilicon compounds containing ethylenic unsaturation is reported in the patent and journal literature. This prior art on the effect of molecular oxygen on hydrosilation reactions catalyzed by platinum group metals and compounds used conventional platinum group metal hydrosilation catalysts. The reactants in the hydrosilation reaction did not include polyorganosiloxanes capable of forming gels, elastomers, resins and similar high molecular weight crosslinked materials. GB 2 184 727 A discloses a colloidal hydrosilylation catalyst comprising (A) a reaction product of (i) a silicon hydride or siloxane hydride, and (ii) a platinum(0) or platinum(II) complex; and (B) 2 to 20 parts by weight of aprotic solvent per part of (A). EP 0 337 197 A inter alia discloses a hydrosilylation method comprising effecting reaction between an olefinically unsaturated material and a silicon hydride having up to three chemically combined hydrogen atoms per silicon atom in the presence of an effective amount of a hydrosilylation catalyst comprising a rhodium colloid resulting from the reaction of from 10 to about 100 moles of a silicon hydride, per mole of rhodium trichloride, where the silicon hydride has a boiling point of at least 25 °C at atmospheric pressure and the silicon atom of the silicon hydride is satisfied with from 1 to 3 hydrogen atoms and at least 1, and up to 3 monovalent radicals, other than hydrogen, selected from 1 or 2 C 1-13 hydrocarbon radicals and 1 to 3 C 1-8 alkoxy, siloxy, halogen and mixtures of such monovalent radicals. An objective of this invention is to provide anaerobically inhibited compositions that cure in the presence of molecular oxygen to yield elastomers, foams, resins and other useful crosslinked materials. Another objective is to provide a method for preparing these curable compositions using hydrosilation catalysts that are at least partially inactivated in the absence of oxygen. The present invention utilizes hydrosilation catalysts that are at least partially inactivated in the absence of oxygen to prepare storage stable, one- and multi-part curable compositions containing (1) at least one compound with an average of at least two alkenyl radicals per molecule and (2) at least one compound with an average of at least two silicon-bonded hydrogen atoms. The catalysts are inactivated by reaction with a specified group of organosilicon compounds containing silicon-bonded hydrogen atoms. Curing of the compositions containing these inactivated catalysts is at least partially inhibited until the compositions are exposed to molecular oxygen. Then they cure in the same manner as conventional compositions containing these ingredients. This invention provides curable compositions exhibiting cure inhibition in the absence of oxygen, said composition being stored in the absence of molecular oxygen and comprising: A. a first compound containing at least two ethylenically unsaturated or acetylenically unsaturated groups per molecule; B. an amount sufficient to cure said composition in the presence of an active hydrosilation catalyst of a second compound containing at least two silicon-bonded hydrogen atoms per molecule; and C. an amount sufficient to promote curing of said composition in the presence of oxygen of an anaerobically inhibited hydrosilation catalyst containing a platinum group metal. One class of anaerobically inhibited hydrosilation catalysts suitable for use in the present compositions are reaction products of (1) an anaerobically active hydrosilation catalyst selected from platinum group metals and compounds thereof and (2) at least one organosilicon compound containing at least one silicon-bonded hydrogen atom per molecule. Preferred organosilicon compounds contain from one up to three or more silicon-bonded hydrogen atoms per molecule and include organosilanes, polysilanes and polyorganosiloxanes. The substituents other than hydrogen atoms bonded to the silicon atoms of said organosilicon compounds are selected from monovalent hydrocarbon radicals, alkoxy groups and siloxane units. When the anaerobically active catalyst is a platinum group metal or a compound containing a platinum group metal, particularly platinum in the zero valence state, certain restrictions apply when none of the silicon atoms of the organosilicon compound contain more than one hydrogen atom. In this instance, the silicon atoms bonded to hydrogen must also be bonded to two or three oxygen atoms. If the silicon atom is bonded to two oxygen atoms, at least one of the oxygen atoms must be part of a hydrocarbyloxy group. The remaining valence can be satisfied by a monovalent hydrocarbon radical. So long as the restrictions regarding zero valent platinum group metals are observed, the substituents other than hydrogen atoms bonded to the silicon atoms of organosilicon compounds that can be reacted with the anaerobically active platinum group metal-containing hydrosilation catalysts include monovalent hydrocarbon radicals and organosilylalkyl(-R * Si≡), organosiloxy (OSi≡) and/or alkoxy groups, where R * represents an alkylene radical. This invention also provides a method for preparing and storing compositions that cure in the presence of molecular oxygen and exhibit at least partial cure inhibition in the absence of oxygen, said method comprising the sequential steps of 1) blending in the absence of oxygen A. a first compound containing at least two ethylenically or acetylenically unsaturated groups per molecule; B. an amount sufficient to cure said composition in the presence of an active hydrosilation catalyst of a second compound containing at least two silicon-bonded hydrogen atoms per molecule; and C. an amount sufficient to promote curing of said composition in the presence of molecular oxygen of an anaerobically inhibited hydrosilation catalyst; and 2) storing the resultant composition in the absence of molecular oxygen. As used in this specification, "molecular oxygen" refers to the gaseous or liquefied form of oxygen, which can be present alone or as an ingredient in a mixture of gases such as air. The term "absence of molecular oxygen" refers to environments containing less than 1 part per million of molecular oxygen. The present inventors have discovered that the long term storage stability of our curable compositions gradually decreases in proportion to the concentration of molecular oxygen. Methods and devices for isolating compositions from trace amounts of oxygen are known in the art. One such method comprises preparing compositions in an oxygen-free environment and packaging them in hermetically sealed containers. The maximum concentration of oxygen that can be present without substantially decreasing the storage stability of the present compositions is determined by a number of variables, including reactivity of the curable ingredients and the particular catalyst selected and the method of packaging the composition. The catalyst can be packaged separately from the unsaturated reactants and/or the compounds containing silicon-bonded hydrogen atoms during storage to increase the storage stability of the composition. An important feature of the present compositions is their storage stability under anaerobic conditions, i.e. in the absence of molecular oxygen. This feature is due to inhibition of an anaerobically active hydrosilation catalyst, which includes metals from the platinum group of the periodic table and compounds of these metals. A preferred method for inhibiting the hydrosilation catalyst is by reacting it under anaerobic conditions with an organosilicon compound containing at least one silicon-bonded hydrogen atom per molecule. The concentration of organosilicon compound is sufficient to inhibit the activity of the catalyst in the presence of oxygen. When the anaerobically active catalyst contains a platinum group metal in the zero valent state and the organosilicon compound contains a maximum of one hydrogen bonded to any silicon atom, the silicon atoms bonded to hydrogen are also bonded to three siloxy or hydrocarbyloxy groups or to two oxygen atoms, at least one of which is part of a hydrocarbyloxy group. Preferred organosilicon compounds for reacting with anaerobically active catalysts to form the catalysts of the present compositions are organohydrogensilanes, organohydrogendisiloxanes and organohydrogenpolysiloxanes. The silanes and disiloxanes can be represented by formulae I and II R 1 b (OR 2 ) 4-a-b SiH a (SiR 1 2 H) 2 O When the organosilicon compound is an organohydrogenpolysiloxane, the siloxane units containing silicon-bonded hydrogen atoms can be bonded to one, two or three siloxane units. These hydrogen-containing siloxane units can be represented by formula III H c R 1 d (OR 2 ) e SiO (4-c-d-e)/2 In these formulae, R 1 is a monovalent hydrocarbon radical that is free of ethylenic or acetylenic unsaturation, R 2 is alkyl containing from 1 to 4 carbon atoms, a is 1, 2 or 3; b is 0, 1, 2 or 3; and the sum of a and b does not exceed 4; c is 1, 2 or 3; and d and e are each 0, 1 or 2, with the proviso that the sum of c, d and e is 1, 2 or 3. When more than one R 1 and/or R 2 substituents are present these can be identical or different. The hydrocarbon radicals represented by R 1 include alkyl, cycloalkyl, aryl, aralkyl and alkaryl radicals. These hydrocarbon radicals are preferably alkyl containing from 1 to 4 carbon atoms, phenyl and/or 3,3,3-trifluoropropyl and R 2 is preferably methyl or ethyl. When the platinum group metal present in the anaerobically active catalyst is in the zero valence state, such as in the metal itself or in certain complexes of platinum halides with disiloxanes containing ethylenically unsaturated hydrocarbon radicals such as vinyl bonded to silicon, certain restrictions apply to the catalyst deactivating organosilicon compound. These restrictions are described in a preceding section of this specification. The hydrogen-substituted silicon atoms of preferred members of this restricted class of organosilicon compounds containing no more than one hydrogen on any silicon atom can be represented by the formula or HSiR 3 3 where X and Y are individually selected from alkyl or SiR 4 3 , Z is alkyl, alkoxy or OSiR 4 3 , R 3 is alkyl and each R 4 is individually selected from hydrogen atoms, unsubstituted and substituted hydrocarbon radicals, alkoxy groups and organosiloxane groups, with the proviso that when Z is alkyl, X and Y cannot both be SiR 4 3 . Formula IV encompasses silanes and siloxanes. It will be understood that the three R 4 substituents include hydrogen atoms, unsubstituted and substituted hydrocarbon radicals, alkoxy groups and organosiloxane groups. Specific compounds suitable for use with catalysts containing monovalent platinum include alkylsilanes such as n-hexylsilane, diethylsilane and triethylsilane and silanes containing both alkyl radicals and alkoxy groups, such as methyldimethoxysilane. If the platinum group metal present in the anaerobically active hydrosilation catalyst is not in the zero valence state, the catalyst can be converted to an anaerobically inhibited one by reaction with organosilicon compounds corresponding to formula I or II or with any other organosilicon compound containing at least one silicon atom bonded to at least one hydrogen atom. Preferred silanes that can be used to prepare anaerobically inhibited catalysts from anaerobically active platinum compounds include alkylhydrogensilanes such as methylsilane, n-hexylsilane, diethylsilane, triethylsilane, methylphenylsilane, methyldimethoxysilane, trimethoxysilane and triethoxysilane. The anaerobically active platinum catalysts used to prepare the catalyst ingredient of the present compositions can be any of the platinum group metals and compounds of these metals reported in the literature as capable of catalyzing a hydrosilation reaction between alkenyl or alkynyl radicals and silicon-bonded hydrogen atoms. Useful anaerobically active catalysts include platinum, palladium and rhodium and compounds of these metals, particularly the halides and compounds wherein at least a portion of the halogen atoms have been replaced with other atoms such as hydrogen and/or complexes with ethylenically unsaturated organic or organosilicon compounds. Preferred anaerobically active hydrosilation catalysts include platinum halides, particularly the dichloride, tetrachloride and chloroplatinic acid and complexes obtained by reacting platinum halides, particularly the tetrachloride and chloroplatinic acid, with olefins, silanes or disiloxanes containing at least one terminally unsaturated alkenyl or alkynyl radical per molecule. When the anaerobically active catalyst is a complex derived from a platinum group metal compound and an ethylenically unsaturated organic or organosilicon compound containing at least one alkenyl radical, the alkenyl radicals contain from two up to eight carbon atoms when the unsaturated compound is an organosilicon compound. Preferred alkenyl radicals are vinyl, allyl and 5-hexenyl. Suitable ethylenically unsaturated organosilicon compounds include vinyl-containing silanes, tetraalkyldivinyldisiloxanes and linear or cyclic organosiloxane oligomers containing up to 12 siloxane units and at least one alkenyl radical per molecule. Useful complexes derived from alkenyl-substituted organosilicon compounds and platinum group metal compounds are described in US-As 3,775,452; 3,715,334; 3,159,601 and 4,288,345. Particularly preferred coordination complexes are reaction products of halogen-containing platinum compounds such as platinum (II) chloride and chloroplatinic acid and terminally unsaturated hydrocarbons, alkenyl-substituted silanes and sym-tetraalkyldivinyldisiloxanes. Complexes derived from disiloxanes and chloroplatinic acid are described in US-A 3,419,593. Preferred olefins for preparing complexes with platinum group metals and compounds of these metals contain from 6 to 10 carbon atoms, are terminally unsaturated and include liquid hydrocarbons such as 1-hexene and 1,5-hexadiene. The present catalysts are prepared by reacting the anaerobically active catalyst with at least one of the catalyst deactivating organosilicon compounds. The catalysts are prepared, isolated and stored under anaerobic conditions. Typically the organosilicon compound is added to the anaerobically active catalyst in the absence of molecular oxygen. The molar ratio of organosilicon compound to catalyst is greater than 1 and is preferably at least 50. It should be understood that if the catalyst contains ethylenically or acetylenically unsaturated compounds, the quantity of silicon-bonded hydrogen added should be sufficient to react with all of the unsaturated carbon atoms. The reaction between the catalyst and the organosilicon compound may be exothermic and it may therefore be necessary to cool the reaction mixture to prevent decomposition of the anaerobically inactive catalyst. To verify that the catalyst is and will remain inhibited under anaerobic conditions, an excess of the SiH-containing organosilicon compound present during preparation of the catalyst together with an ethylenically unsaturated organic or organosilicon compound are added until both compounds are present in unreacted form, indicating that the catalyst has been rendered inactive. If the anaerobically active catalyst does not contain zero valent platinum, an anaerobically inactive catalyst can be prepared by reacting the anaerobically active catalyst, such as hexachloroplatinic acid, with the organohydrogenpolysiloxane used as the curing agent for the curable organosiloxane composition. So long as the reaction between the anaerobically active catalyst and the organohydrogenpolysiloxane is conducted under anaerobic conditions, other reactive ingredients of the curable composition, including the ethylenically or acetylenically unsaturated compound, can be present in the reaction mixture without causing the composition to cure. The catalyst compositions used to prepare the anaerobically stable organosiloxane compositions of this invention typically contain from 0.01 to 1 weight percent or more of the platinum-group metal. The concentration of the present anaerobically inhibited catalysts in the curable compositions of this invention is typically from 10 to 125 parts per weight of the platinum group metal per million parts by weight of the curable composition. In addition to the above curable reactants and the optional oxygen scavengers described in a subsequent portion of this specification, the curable compositions of this invention may contain other optional ingredients such as fillers and property-enhancing additives typically present in compositions that cure by a platinum group metal catalyzed reaction between silicon-bonded hydrogen atoms and ethylenically or acetylenically unsaturated groups. Examples of curable reactants include (1) ethylenically or acetylenically unsaturated organic compounds, including monomers and oligomers and unsaturated organosilicon compounds-and (2) organohydrogensilanes. The compositions can contain one or more species of each type of reactant. The curable compound containing at least two ethylenically or acetylenically unsaturated groups, reactant A, includes both organic and organosilicon compounds. Depending upon the nature of the final cured product, this compound can be a monomer, oligomer or polymer. Cured products that can be prepared using the present compositions range in consistency from gels to elastomers to resins. As used herein, the term "ethylenically unsaturated group" includes alkenyl radicals such as vinyl, allyl and 1,3-butadienyl in addition to groups containing a carbon-to-carbon double bond and hetero atoms such as oxygen and nitrogen. The latter groups include acryloxy, -O(O)CCH=CH 2 and acrylamido, -HN(O)CCH=CH 2 . The only restriction is that the groups do not interfere with storage or curing of the curable composition. The term "acetylenically unsaturated group" includes both hydrocarbon radicals such as ethynyl, -C≡C- and substituted hydrocarbon radicals such as propargyl, -O(O)CC≡CH. The reactive groups present on reactant A are preferably alkenyl radicals containing from 2 to 20 carbon atoms. When reactant A contains the preferred alkenyl radicals as the ethylenically unsaturated group and is a polyorganosiloxane, this reactant can be a liquid or pumpable material exhibiting a viscosity of from 0.1 to 1000 Pa·s at 25°C., or a high consistency gum that is characterized in terms of Williams plasticity values. When reactant A is a polyorganosiloxane, the alkenyl radicals are typically vinyl, allyl or 5-hexenyl. Vinyl and 5-hexenyl are preferred, based on the cost of the corresponding intermediates and the reactivity of the polyorganosiloxanes containing these radicals. The organic groups other than alkenyl radicals that are bonded to the silicon atoms of polyorganosiloxanes used as reactant A and the organohydrogensiloxanes used as curing agents for the present compositions are monovalent hydrocarbon radicals that are free of ethylenic or acetylenic unsaturation. These hydrocarbon radicals can be unsubstituted or can contain one or more substituents that will not interfere with curing of the present compositions. Suitable substituents include halogen atoms such as chlorine, bromine and fluorine. Substituents such as epoxide groups can be present to modify properties such as adhesion of the cured products prepared using the present compositions. Preferred hydrocarbon radicals include alkyl radicals containing from one to about four carbon atoms, haloalkyl radicals such as chloromethyl and 3,3,3-trifluoropropyl and aromatic radicals such as phenyl and tolyl. Most preferably at least 50 percent of the hydrocarbon radicals present on the alkenyl-substituted polyorganosiloxane(s) and the organohydrogensiloxanes present in the curable organosiloxane compositions of this invention are methyl and any remainder are phenyl and/or 3,3,3-trifluoropropyl. This preference is based on the availability of the reactants typically used to prepare the polyorganosiloxanes and the properties of cured elastomers and other materials prepared from these polyorganosiloxanes. Representative embodiments of preferred alkenyl-substituted polyorganosiloxanes containing vinyl radicals only at the terminal positions include dimethylvinylsiloxy-terminated polydimethylsiloxanes, dimethylvinylsiloxy-terminated polymethyl-3,3,3-trifluoropropylsiloxanes, dimethylvinylsiloxy-terminated dimethylsiloxane/3,3,3-trifluoropropylmethylsiloxane copolymers and dimethylvinylsiloxy-terminated-dimethylsiloxane/methylphenylsiloxane copolymers. The vinyl radicals of these preferred polyorganosiloxanes can be replaced with other alkenyl radicals such as 5-hexenyl. Copolymers containing dimethylsiloxane, dimethylvinylsiloxane, methylsilsesquioxane and trimethylsiloxy units are also particularly suitable as the alkenyl-substituted polyorganosiloxane ingredient. The present curable compositions can contain a single species of polyorganosiloxanes corresponding to the preferred embodiments of reactant A. Alternatively two or more of these polyorganosiloxanes can be present. The polyorganosiloxanes differ with respect to their molecular weight and/or the number of silicon-bonded alkenyl radicals per molecule. Organic compounds containing at least two unreacted ethylenically or acetylenically unsaturated groups per molecule are also suitable for use as reactant A. These compounds can be liquid or solid at room temperature and include monomers such as butadiene, diacrylates derived from polyfunctional alcohols, polyolefins such as polyethylene, polypropylene and copolymers of styrene with other ethylenically unsaturated compounds such as acrylonitrile and butadiene; and polymers derived from functionally substituted organic compounds such as esters of acrylic, methacrylic and maleic acids. The organic compounds, oligomers and polymers can be used alone or in combination with polyorganosiloxanes corresponding to the definition of reactant A. Compositions containing one or more compounds corresponding to the definition of reactant A are cured by reaction with a compound containing at least two silicon-bonded hydrogen atoms per molecule. The SiH-containing compounds can be organic oligomers, organic polymers, silanes containing at least two silicon-bonded hydrogen atoms per molecule or organohydrogensiloxanes. The organic groups bonded to the silicon atoms of the curing agent are monovalent hydrocarbon radicals that are either unsubstituted or contain substituents such as halogen atoms that will not adversely affect the storage stability or curing of the present compositions. These SiH-containing compounds are well known in the art and are free of ethylenic or acetylenic unsaturation. In preferred curable compositions of our invention, one or more polydiorganosiloxanes containing an average of at least two alkenyl radicals groups per molecule react with a relatively low molecular weight, liquid organic polymer or organohydrogensiloxane containing an average of at least two silicon bonded hydrogen atoms per molecule. To obtain crosslinked materials the sum of the average numbers of alkenyl radicals and silicon-bonded hydrogen atoms per molecule of the respective reactants is greater than 4. Suitable organohydrogensiloxanes contain from as few as four silicon atoms per molecule up to an average of 20 or more and preferably exhibits a viscosity of up to 10 Pa·s at 25°C. These organohydrogensiloxanes contain repeating units of the formulae HSiO 1.5 , R 5 HSiO and/or R 5 2 HSiO 0.5 . The- molecules of this reactant may also include one or more monoorganosiloxane, diorganosiloxane, triorganosiloxy and SiO 4/2 units that do not contain silicon bonded hydrogen atoms. In these formulae each R 5 is a monovalent hydrocarbon radical as defined in the preceding section of this specification. Alternatively, reactant B can be a cyclic compound containing at least 4 organohydrogensiloxane units of the formula R 5 HSiO or a compound of the formula HR 5 2 SiO(HR 5 SiO) a SiR 5 2 H, where a is at least 1. Most preferably, R 5 is methyl and reactant B is a linear trimethylsiloxy terminated polymethylhydrogensiloxane or a dimethylsiloxane/methylhydrogensiloxane copolymer containing an average of from 5 to 50 repeating units per molecule of which from 30 to 100 percent are methylhydrogensiloxane units. In addition to hydrocarbon radicals and reactive groups required for curing of the composition, reactants A and B can contain other substituents such as alkoxy and epoxy groups that provide adhesion or other useful properties to the cured materials prepared using the present compositions. However, their use is restricted if they interfere with storage and/or curing of the compositions. The molecular weights of reactants A and B together with the number and distribution of the silicon-bonded hydrogen atoms and alkenyl radicals groups within these ingredients will determine the location of crosslinks in the cured product, which can range in consistency from a glass-like resin to an elastomer to a gel. The concentration of crosslinks per unit volume is often referred to as the "crosslink density" and determines certain physical properties of the cured elastomer, particularly hardness, tensile strength and elongation. The particular combination of reactants A and B that will provide the desired combination of physical properties can readily be determined by routine experimentation with a knowledge of this invention. The molar ratio of silicon bonded hydrogen atoms in reactant B to the alkenyl radicals in reactant A is a major factor in determining the properties of the elastomer or other cured material obtained from the composition. Because of the difficulty often experienced in achieving a complete reaction between all of the silicon bonded hydrogen atoms and all of the alkenyl radicals present in the reaction mixture, it is desirable to have a stoichiometric excess of one of these species in a curable composition. Depending upon the types of reactants, a molar ratio of from 0.3 to 5 silicon bonded hydrogen atoms per alkenyl radical will yield useful products. For the compositions exemplified in this application, this ratio is preferably from 0.5 to 1.5. The preferred ratio for a given composition will be determined at least in part by the average molecular weight of reactants A and B and the physical properties of the final cured product. The storage stability in the absence of oxygen of the curable organosiloxane compositions containing our anaerobically inhibited catalyst compositions can be substantially increased by the addition of conventional aerobic platinum catalyst inhibitors. These inhibitors are well known in the art and include actylenic hydrocarbons, such as 1-propyne and 1-butyne, acetylenic alcohols such as 2-methyl-3-butyn-2-ol and 1-ethynyl-1-cyclohexanol, tertiary amines such as tripropylamine and N,N,N',N'-tetramethylethylenediamine and esters of maleic and fumaric acids. The molar ratio of inhibitor to platinum group metal present in the catalyst is typically from 0.5 to 500 and will depend on the particular inhibitor selected and the desired storage stability and cure time in the presence of oxygen. The inhibitor is preferably added to the catalyst prior to the catalyst addition to the other ingredients of the present compositions. In addition to increasing the storage stability of the organosiloxane compositions, including the present anaerobically stable compositions, many conventional inhibitors for platinum group metal-containing hydrosilation catalysts also increase the curing time of the compositions. This increase in cure time can be reduced by using an inhibitor whose activity is suppressed in the presence of molecular oxygen. These inhibitors include organophosphorus compounds that include the di- and trihydrocarbylphosphines, di- and trihydrocarbylphosphine oxides, di- and trialkylphosphites, phosphinites, phospholene oxides and bis(dihydrocarbyl-phosphino)alkanes. Amine oxides and sulfoxides also have greater inhibiting activity under anaerobic conditions than in the presence of molecular oxygen, but apparently not to the same degree as the organophosphorus compounds which are preferred. As in the case of conventional catalyst inhibitors, the concentration of oxygen-deactivated inhibitor relative to hydrosilation catalyst required to extend the storage life of a curable composition will be determined by a number of factors, including the activity of the inhibitor and the curing catalyst, the reactivity of reactants A and B, the desired storage stability of the curable composition in the absence of oxygen and the working time of the composition in the presence of oxygen. It appears that the molar ratio of inhibitor to platinum group metal present in the curing catalyst is generally within the range of from 2 to 200. For the most effective oxygen deactivated catalyst inhibitors, such as the triorganophosphines and trialkylphosphine oxides, the molar ratio of inhibitor to platinum group metal is from 2 to 20. Both the storage stability of the present compositions under anaerobic conditions and their cure rate in the presence of oxygen appears directly proportional to the concentration of oxygen deactivated catalyst inhibitor. Compositions containing triorganophosphines, phosphites or phosphinites as inhibitors typically require relatively long time periods to cure at temperatures of from 20 to 30°C. The curing times of these compositions can be reduced from weeks or months at 25°C. to days or hours by curing them at temperatures above 80°C. The storage stability of the present compositions under anaerobic conditions can be further increased by the presence in the curable composition of any of the known oxygen scavengers. Suitable scavengers include carbohydrazide (H 2 NNHC(O)NHNH 2 ), aldehydes, amino acids, hydroquinones, active ferrous oxide, organosilicon polyboranes, trialkylboranes, phenylbutenones, hydroxycarboxylic acids such as ascorbic acid, ethylenically unsaturated carboxylic acids such as linoleic acid and potassium hydroquinone sulfonate. The reaction rate of the oxygen scavenger with molecular oxygen can be accelerated by use of a suitable catalyst, such as oxidizable salts of divalent cobalt, copper and manganese. The concentration of these oxygen scavengers is selected to provide the desired storage stability and cure characteristics and is typically from 50 to 10,000 moles per mole of platinum present in the inhibited catalyst. In addition to the aforementioned ingredients the compositions can contain other additives including reinforcing and non-reinforcing fillers, treating agents for these fillers, pigments, processing aids, adhesion promoters, stabilizers and flame retardants. The anaerobically inhibited compositions of this invention are prepared by blending reactant A with reactant B, the anaerobically inhibited catalyst and any other optional ingredients under anaerobic conditions. All of the reactants and other additives should be substantially free of molecular oxygen at the time they are combined with the other ingredients of the present curable compositions. Methods for achieving this are described in the preceding section of this specification relating to preparation of the anaerobically inhibited catalysts. Preferred methods for preparing anaerobically inhibited curable compositions are described in the accompanying examples. It will be understood that any of the known methods for excluding or removing oxygen from an environment can be used to generate the anaerobic conditions under which the present compositions are prepared and stored. These methods include the use of hermetically sealed rigid and flexible containers and the storage of our compositions in the presence of oxygen-free inert gases and/or oxygen scavengers. To avoid premature curing of anaerobically stable curable compositions containing the present catalysts, all of the reactions used to prepare the catalysts should be conducted in the substantial absence of molecular oxygen. Known methods for removing oxygen from reactants and reaction vessels include sparging with nitrogen or other inert oxygen-free gas, use of oxygen scavengers and subjecting reactants to reduced pressure, which can be accompanied by freezing and thawing of the material and back-filling of the container with nitrogen or other inert gas. Under preferred conditions for preparing the present compositions the concentration of oxygen is preferably less than 1 part of oxygen per million parts of nitrogen or other inert gases that constitute the atmosphere under which the compositions are prepared. In accordance with a preferred method for preparing the present compositions, all ingredients are sparged with an inert oxygen-free gas such as nitrogen or argon and stored under this atmosphere until transferred to the reactor in which the composition will be prepared. The consistency of the present curable compositions can range from pourable liquids to pastes that flow only under pressure to gum rubber stocks. Cured materials prepared using the present compositions are useful in the same applications as materials prepared by hydrosilation reactions using conventional platinum catalysts. These uses include elastomers, resins, gels for protecting various substrates, coatings for paper, electronic circuit boards and other substrates. When packaged in a single container in the absence of oxygen, the present compositions can be stored at 25°C. for periods ranging from days to months, depending upon the types of reactants, catalyst and other additives, such as catalyst inhibitors, that are present in the composition. Compositions with virtually unlimited storage stability can be obtained by packaging the present compositions in at least two parts, with the catalyst in one container and reactant A and/or reactant B in a second container. When the ingredients are combined and stored under anaerobic conditions the compositions will have working times of from several hours to several months under ambient conditions. In the presence of oxygen, the curing times are often considerably shorter relative to compositions containing conventional platinum catalyst inhibitors. The present compositions cure in the presence of oxygen. Methods for curing the compositions include exposing the compositions to air, a stream of oxygen gas and generating oxygen within the compositions such as by blending the composition with organic peroxides and subsequently heating the composition to decompose the peroxide. Peroxides that are stable under the conditions used to store the curable compositions can also be included as an ingredient of these compositions. The cure rate of the compositions can be controlled by regulating the amount of oxygen to which the composition is exposed in a given period of time. Curing can be accelerated by adding oxygen to the curable composition by sparging and/or heating the composition. The following examples describe preferred methods for preparing anaerobically inhibited platinum-containing hydrosilation catalysts and the storage stable compositions of the present invention containing these catalysts. Unless otherwise indicated, all parts and percentages in the examples are by weight, viscosity values were measured at 25°C. and the nitrogen used to remove oxygen from the catalyst and curable compositions contained less than one part per million of oxygen. Example 1 This example describes the preparation of a preferred platinum hydrosilation catalyst that is inhibited in the absence of oxygen. 1.0 g. of a conventional anaerobically active platinum-containing hydrosilation catalyst and 9.0 g. of dodecamethyl-pentasiloxane were placed in a vial equipped with a septum cap and stopcock. The contents of the vial were frozen at a temperature of 77° Kelvin, at which time a cycle of evacuating the vial to 66.7 Pa (0.5 Torr), warming the contents to room temperature and back filling with high purity (99.99%) argon was repeated for 30 minutes. 0.260 g. of methylphenylsilane was then added to the vial using a syringe, the resultant mixture was heated for 30 minutes at 75°C. while under an argon atmosphere and then allowed to cool to room temperature under the same atmosphere. The contents of the vial were then subjected to three cycles of freezing, evacuation and thawing followed by filling the vial with argon. The resultant catalyst will be referred to as "catalyst A". The conventional platinum catalyst was a reaction product of hexachloroplatinic acid and sym-tetramethyldivinyldisiloxane that had been diluted with a liquid dimethylvinylsiloxy terminated polydimethylsiloxane with a viscosity of 0.4 Pa·s in an amount sufficient to achieve a platinum content of 0.7 weight percent. 80 µ l of catalyst A were added to 50 g of a blend of 800 parts of a dimethylvinylsiloxy-terminated polydimethylsiloxane exhibiting a viscosity of 0.5 Pa·s and containing 0.45 weight percent vinyl radicals and 20.8 parts of a trimethylsiloxy-terminated polydiorganosiloxane containing an average of five methylhydrogensiloxane units and three dimethylsiloxane units per molecule with a silicon-bonded hydrogen atom content in the range from 0.7 to 0.8 weight percent. The blend had been sparged with argon for 1 hour prior to addition of the catalyst composition and was kept in a closed container. This blend will be referred to hereinafter as polymer blend A. The catalyzed composition contained 1 ppm of platinum and 23 ppm of the dodecamethylpentasiloxane, equivalent to a silane/Pt molar ratio of 50. For comparative purposes the same amount of catalyst was added to 50 grams of polymer blend A that had not been sparged with argon. The gel time of the composition that had been maintained under argon was 96 hours at 25°C. The comparative sample exposed to air had a gel time less than 17 hours at the same temperature. Gel time is defined as the time required for the composition to crosslink to the extent that it no longer flows under its own weight. Example 2 This example demonstrates the beneficial effect of adding a conventional platinum catalyst inhibitor, 1-ethynyl-1-cyclohexanol, to a catalyst composition of the present invention. 1-Ethynyl-1-cyclohexanol was subjected to three cycles of freezing, evacuating and thawing while backfilling with argon. 10.4 microliters of this inhibitor were added to 50 grams of polymer blend A that had been sparged with argon for one hour, which is equivalent to an inhibitor concentration of 200 parts per million. The same volume of inhibitor was added to 50 grams of polymer blend A that had been in contact with air. Eighty microliters of catalyst A described in Example 1 were added to each of the polymer blends, following which the containers were shaken and allowed to stand at 25°C. The gel time of the composition prepared entirely under argon was at least 72 days under these conditions. The polymer blend maintained in contact with air gelled in 31 days under the same conditions. Example 3 This example describes the preparation of curable compositions containing a second type of anaerobically stable catalyst of the present invention. Ten grams of a known platinum catalyst for hydrosilation reactions and 10 g. of toluene were placed in a reactor equipped with a water cooled reflux condenser, thermometer, stirrer and addition funnel. Nitrogen that had been passed through copper powder heated at a temperature of 120°C. to reduce the molecular oxygen content below one part per million was bubbled (sparged) into the triethoxysilane in the addition funnel and through a syringe needle that extended through the septum and below the surface of the liquid in the reactor. The known platinum catalyst was a reaction product of hexachloroplatinic acid and sym-tetramethyldivinyldisiloxane and contained 4.212 weight percent of platinum. Following 60 minutes of nitrogen sparging 10 g. (0.06 mole) of triethoxysilane were added slowly through the addition funnel. Samples were withdrawn from the reactor at approximately 20 minute intervals, diluted with a mixture of 0.5 g of toluene and 0.05 g. decane and blended with 0.005 g of N,N,N',N'-tetraethylenediamine to inactivate the platinum catalyst. The resultant samples were analyzed by gas liquid chromatography to determine the presence of triethoxysilane and 1,3-divinyltetramethyldisiloxane. When 5 g. of triethoxysilane had been added an exothermic reaction was observed. A sample withdrawn at this time contained 1,3-divinyltetramethyldisiloxane, but no detectable amount of triethoxysilane. Addition of approximately one cm 3 portions of triethoxysilane was continued with analysis following each addition until the presence of unreacted silane was detected, an indication that the catalyst had been deactivated. A mixture containing equal weights of the silane and the disiloxane was sparged with nitrogen and added and no additional reaction was detected after several days. A total of 6.15 parts of 1,3-divinyltetramethyldisiloxane and 24.5 parts of triethoxysilane had been added to the reactor and the final anaerobically stable catalyst (catalyst B) contained 8316 parts of platinum metal per million parts of the catalyst composition. A curable organosiloxane composition was prepared by adding one drop (approximately 0.005 g.) of catalyst B to 4.1 grams of a mixture (polymer blend B) prepared by blending 97.15 parts of a dimethylvinylsiloxy-terminated polydimethylsiloxane having a viscosity of 0.4 Pa·s at 25°C. and 2.85 parts of a trimethylsiloxy-terminated polydiorganosiloxane having an average of five methylhydrogensiloxane units and three dimethylsiloxane units per molecule with a silicon-bonded hydrogen atom content in the range from 0.7 to 0.8 weight percent. The molar ratio of silicon-bonded hydrogen atoms to vinyl radicals in polymer mixture B was 1.25. For comparative purposes, a curable composition was prepared using the procedure described in the two immediately preceding paragraphs but substituting for the catalyst 0.2 g. of a solution prepared from equal weight of dry toluene and the platinum catalyst used to prepare catalyst B. The solution was sparged with nitrogen for 60 minutes before being added to the other ingredients. The resultant composition cured in 2-3 minutes either when stored under nitrogen and or following exposure to air, demonstrating the absence of any anaerobic inhibition. Prior to addition of the catalyst the polymer mixture had been sparged for 60 minutes with nitrogen that had been treated as described in the preceding section of this example. The resultant mixture cured, i.e. converted from a liquid to a gel, in 310 minutes when stored under nitrogen. When exposed to air under ambient conditions the mixture cured in 6 to 8 minutes. To determine the effect of 3,5-dimethylhexyn-3-ol, a known platinum catalyst inhibitor, on the storage stability of the composition, 0.0134 g. of this inhibitor was added to 0.005 g. of catalyst B, equivalent to a molar ratio of inhibitor to platinum of 500. The resultant inhibitor/catalyst mixture was sparged with nitrogen for 60 minutes. 0.0184 g. of this mixture was added to 4.1 g. of polymer mixture B that had been sparged with and stored under nitrogen. The resultant curable composition remained liquid for more than 11 months when stored under nitrogen. When exposed to air under ambient conditions the composition cured in 10 hours. A second inhibited catalyst sample was prepared using 0.0312 g. of the same inhibitor and 0.2596 g. of catalyst B, equivalent to a molar ratio of inhibitor to platinum of 21 and sparged with nitrogen. A curable composition prepared by blending 0.0053 g. of the inhibitor/catalyst mixture with 4.1 g. of polymer mixture B cured in 23 days when stored under nitrogen and in 13 hours following exposure to ambient air. As a comparative example, the effect of the same inhibitor, 3,5-dimethylhexyn-3-ol, on the storage stability of a curable composition prepared in the absence of oxygen was determined using a conventional platinum hydrosilation catalyst. The inhibited catalyst composition was prepared by blending under nitrogen 0.0305 g. of 3,5-dimethyl-1-hexyn-3-ol with 0.2479 g. of a solution obtained by diluting 3.5 parts of the reaction product of hexachloroplatinic acid and sym-tetramethyldivinyldisiloxane (platinum content 4.212 weight percent) with 1 part of toluene. 0.0053 g. of the resultant inhibitor/catalyst mixture was added to 4.1 g. of polymer mixture B. One portion of the resultant curable composition was stored under nitrogen and a second was in contact with air. Both compositions cured in 9 hours. The cure times of the curable ingredients and inhibited platinum catalyst described in the example were determined using two other known platinum catalyst inhibitors, N,N,N',N'-tetramethylethylenediamine (TMEDA), 3,5-dimethylhexyn-1-ol (DMH) and diethyl fumarate (DEF). The procedures used to prepare and evaluate the samples are the same ones described in the preceding section of this example. In each instance one drop, equivalent to 0.005 g., of the inhibitor catalyst mixture was added to polymer blend B. The molar ratio of inhibitor to platinum (Inh/Pt) and the cure times of the resultant compositions stored under nitrogen and exposed to air are listed in the following Table 1. Inhibitor Molar Ratio Inh/Pt Cure Times Under N 2 In Air TMEDA 1.3 > 11 months 7 hours TMEDA 1.0 5.5 days 75 minutes TMEDA 0.7 4 days 35 minutes TMEDA 0.26 8.5 hours 20 minutes DEF 7.4 13 days 8.5 hours DMH 498 >11 months 10 hours Example 4 This example demonstrates the effect of oxygen scavengers on the storage stability of the anaerobically stable curable compositions of this invention. Curable compositions were prepared and evaluated as described in Example 3, with the modification of adding the required amount of three known oxygen scavengers to catalyst B and sparging the resultant scavenger/catalyst mixture with nitrogen. The scavengers were added to 4.1 g. of polymer blend B and the resultant curable composition was blended to homogeneity while sparging it with nitrogen. The type of oxygen scavenger, molar ratio of oxygen scavenger to platinum (OS/Pt) and the cure times of the curable compositions under nitrogen and in air are listed in Table 2. The platinum concentration in each composition was 10 parts per million. The oxygen scavengers evaluated were carbohydrazide (CBHZ), trimethylacetaldehyde (TMA) and N-phenylglycine (NPG) as a 10 percent by weight solution in ethanol. For the liquid oxygen scavengers 0.005 g of a mixture of the oxygen scavenger and catalyst were added. The weight ratios of catalyst to liquid oxygen scavenger were as follows: CBHZ = 10 and TMA = 12.8 N-phenylglycine was the only solid scavenger used and was added as a 10 weight percent solution in ethanol and was combined with 0.005 g. of the catalyst composition. The amounts of liquid oxygen scavengers and solutions of solid scavengers added are recorded in Table 2. Oxygen Molar Ratio Cure Times Scavenger (g.) OS/Pt Under N 2 In Air CBHZ (0.1) 5200 14.5 days 28 hours CBHZ (0.05) 2600 12 days 26 hours CBHZ (0.01) 520 12 days 14 hours TMA (0.042) 2500 14 days 32 hours TMA (0.029) 1700 14 days 32 hours NPG (0.15) 318 > 6 months 30 days NPG (0.075) 237 3.5 months 2 days NPG (0.025) 79 60 days 38 hours Example 5 This example demonstrates the efficacy of the anaerobically stable catalyst described in Example 3 using a different polymer composition. Curable compositions containing an anaerobically inactive catalyst were prepared and evaluated using the general procedure described in Example 3. The polymer blend, referred to as C, contained 92.5 parts of a dimethylvinylsiloxy-terminated dimethylsiloxane/methylvinylsiloxane copolymer containing 2 mole percent of methylvinylsiloxane units and exhibiting a viscosity of 0.3 Pa·s and 6.98 parts of a liquid trimethylsiloxy-terminated polymethylhydrogensiloxane with a silicon-bonded hydrogen content of 1.6 weight percent. The molar ratio of silicon-bonded hydrogen atoms to vinyl radicals in this mixture was 3. 0.021 g. of the anaerobically stable catalyst described in Example 3 was added under a nitrogen atmosphere to 35 g. of polymer blend C and mixed well. When exposed to air under ambient conditions the composition cured in 10-12 minutes. The cure time of the same composition when maintained under nitrogen was about 8 hours. Example 6 This example demonstrates the storage stability imparted to curable compositions by an anaerobically stable catalyst of this invention. The catalyst was prepared by combining 10 g. of 1-hexene with 10 g. of a reaction product of hexachloroplatinic acid and sym-tetramethyldivinyldisiloxane containing 4.212 weight percent of platinum. The resultant mixture was sparged with nitrogen for 60 minutes, at which time a mixture containing 70 weight percent of triethoxysilane and the remainder unreactive condensation products of this silane, referred to hereinafter as the silane mixture, was added gradually to the reaction vessel. An exothermic reaction was observed after 10 grams of the silane mixture had been added. Analysis of the reaction mixture did not reveal the presence of unreacted triethoxysilane. An additional 7 g. of the silane mixture was added, at which time unreacted triethoxysilane was detected in the reaction mixture. A mixture of 3 g. of 1-hexene and 4 g. of the silane mixture was then added, for a total of 21 g. of the silane mixture and 18 g. of 1-hexene. This catalyst mixture, referred to hereinafter as catalyst C contained 8596 parts per million of platinum. One drop (approximately 0.0044 g.) of catalyst C was added to 3.8 g. of polymer blend B described in Example 3 and mixed well. The polymer blend and the catalyst had been prepared and stored under nitrogen. The curable composition cured in 430 minutes when stored under nitrogen and in 10-13 minutes following exposure to air under ambient conditions. For comparative purposes, a curable composition was prepared as described in the first part of this example using 3.9 g. of polymer blend B and replacing the platinum catalyst with 0.20 g. of a solution obtained by diluting the reaction product of hexachloroplatinic acid and sym-tetramethyldivinyldisiloxane (platinum content 4.212 weight percent) with an equal weight of toluene. The resultant composition cured in 2-3 minutes either when stored under nitrogen or following exposure of the freshly prepared composition to air under ambient conditions. When one drop of catalyst C was added to 3.8 g. of polymer blend C described in Example 5 under nitrogen the resultant composition cured in 300 minutes under nitrogen and in 13-15 minutes following exposure of the freshly prepared composition to air under ambient conditions. A comparative sample prepared by combining 3.9 g. of polymer blend C with 0.20 g. of a solution obtained by diluting the reaction product of hexachloroplatinic acid and sym-tetramethyldivinyldisiloxane (platinum content 4.212 weight percent) with an equal weight of toluene cured in 2 minutes either when stored under nitrogen or following exposure of the freshly prepared composition to air under ambient conditions. Example 7 This example describes the preparation and evaluation of curable compositions wherein known anaerobically active hydrosilation catalysts are reacted with a number of organosilicon compounds containing silicon-bonded hydrogen atoms. The example demonstrates the effect of these organosilicon compounds on the storage stability of the curable composition. The catalysts were prepared, stored and evaluated in an air-tight chamber under an atmosphere of nitrogen containing less than 0.3 ppm of oxygen. The temperature in the chamber was 25°C. The quantity of organosilicon compound listed in Table 3 was gradually added to the platinum compound, at which time a color change was observed. After remaining undisturbed for 5 minutes the resultant deactivated catalyst was added to 77.72 parts of a dimethylvinylsiloxy-terminated polydimethylsiloxane having a viscosity of 0.4 Pa·s at 25°C. This mixture was aged for ten minutes, at which time 2.28 parts of a trimethylsiloxy-terminated polyorganosiloxane having an average of five methylhydrogensiloxane units and three dimethylsiloxane units per molecule with a silicon-bonded hydrogen atom content in the range from 0.7 to 0.8 weight percent was added. This polyorganosiloxane was used as the reactant for the anaerobically active catalyst in one instance. The resultant composition of this invention was mixed well and divided into several portions. One of these was sealed and kept in the chamber in which it was prepared and the time required for the composition to cure was determined. Other samples were exposed to air under ambient conditions and the cure time determined. The anaerobically active hydrosilation catalysts were: 1. hexachloroplatinic acid (H 2 PtCl 6 ) 2. platinum dichloride (PtCl 2 ) 3. platinum tetrachloride (PtCl 4 ) 4. a reaction product of hexachloroplatinic acid and sym-tetramethyldivinyldisiloxane that has been diluted to a platinum content of 0.7 weight percent using a liquid dimethylvinylsiloxy terminated polydimethylsiloxane (referred to as catalyst A') 5. Platinum acetylacetonate Pt(AcAc)2 6. Norbornadiene complex with platinum(II) chloride (PtCl 2 .NOBD) Pt Compound SiH Compound Cure Time in Air Storage Stability Under Nitrogen H 2 PtCl 6 (EtO) 3 SiH 3.5 Hrs. 3 Days " Me(MeO) 2 SiH 3.0 Hrs. 10 Hrs. " (Me 2 HSi) 2 O 3.5 Hrs. 10 Hrs. " Curing Agent 1 15 Hrs. 12 Days PtCl 2 (EtO) 3 SiH 55 Min. 15 Hrs. " Me(MeO) 2 SiH 70 Min. 17.5 Hrs. PtCl 4 (EtO) 3 SiH 2 Hrs. 12 Hrs. PtCl 4 Me(MeO) 2 SiH 100 Min 5.5 Hrs A' n-HexSiH 3 3.5 Hrs. 3 Days " Et 2 SiH 2 4 Hrs. 17 Hrs. " Et 3 SiH 55 Min. 9 Hrs. " Me(OMe) 2 SiH 15 Min. 90 Min. " (Me 2 HSiO) 4 Si 2 N.E. N.E. Pt(AcAc) 2 3 Me(OMe) 2 SiH 15 Hrs. 4.5 Days PtCl 2 .NOBD Et 2 SiH 2 5.5 Hrs. 1 Day " n-HexSiH 3 9.5 Hrs. 3.5 Days 9.5 Hrs. 3.5 Days Me = Methyl Et = Ethyl n-Hex = n-hexyl 1 = The organohydrogenpolysiloxane ingredient of the curable composition. 2 = Comparative Example. Platinum is in the zero valent state. Addition of SiH compound to catalyst resulted in solidification. Catalyst could not be evaluated (N.E. = not evaluated). 3 = Platinum bis-acetylacetonate

Claims: Curable composition exhibiting cure inhibition in the absence of oxygen, said composition being stored in the absence of molecular oxygen and comprising: A. a first compound containing at least two ethylenically unsaturated or acetylenically unsaturated groups per molecule; B. an amount sufficient to cure said composition in the presence of an active hydrosilation catalyst of a second compound containing at least two silicon-bonded hydrogen atoms per molecule; and C. an amount sufficient to promote curing of said composition in the presence of oxygen of an anaerobically inhibited hydrosilation catalyst containing a platinum group metal. A composition according to claim 1 where said anaerobically inhibited catalyst is a reaction product of (1) an anaerobically active hydrosilation catalyst selected from platinum group metals and compounds thereof with (2) at least one organosilicon compound selected from organohydrogensilanes containing up to three silicon-bonded hydrogen atoms per molecule, organohydrogendisiloxanes, organohydrogenpolysilanes and organohydrogenpolysiloxanes, the concentration of said organosilicon compound being sufficient to inhibit the activity of said catalyst in the absence of oxygen and the substituents other than hydrogen atoms bonded to the silicon atom of said organosilicon compounds are selected from monovalent hydrocarbon radicals, alkoxy groups and siloxane units, with the proviso that when said platinum group metal is in the zero valence state and none of the silicon atoms of said organosilicon compound are bonded to more than one silicon-bonded hydrogen atom, the hydrogen-substituted silicon atoms of the organosilicon compound are represented by the formula or HSiR 3 3 where X and Y are individually selected from alkyl or SiR 4 3 , Z is alkyl, alkoxy or OSiR 4 3 , R 3 is alkyl and each R 4 is individually selected from hydrogen atoms, unsubstituted and substituted hydrocarbon radicals, alkoxy groups and organosiloxane groups, with the proviso that when Z is alkyl, X and Y cannot both be SiR 4 3 . A composition according to claim 2 where said anaerobically active hydrosilation catalyst is selected from platinum, rhodium and compounds of platinum and rhodium and said organosilicon compound is selected from compounds of the formulae R 1 b (OR 2 ) 4-a-b SiH a and (SiR 1 2 H) 2 O and organohydrogenpolysiloxanes comprising units of the formula H c R 1 d (OR 2 ) e SiO (4-c-d-e)/2 , where R 1 is a monovalent hydrocarbon, phenyl or 3,3,3-trifluoropropyl radical that is free of ethylenic or acetylenic unsaturation, R 2 is alkyl containing from 1 to 4 carbon atoms, a is 1, 2 or 3; b is 0, 1, 2 or 3; and the sum of a and b does not exceed 4; c is 1, 2 or 3 and d and e are each 0, 1 or 2, with the proviso that the sum of c , d and e is 1, 2 or 3 and when more than one R 1 or R 2 substituent is present these substituents are identical or different. A composition according to claim 3 where said organosilicon compound is selected from ethylsilane, n-hexylsilane, diethylsilane, triethylsilane, methylphenylsilane, methyldimethoxysilane, trimethoxysilane and triethoxysilane, the platinum in said anaerobically inhibited hydrosilation catalyst constitutes from 0.1 to 1 percent of the total weight of said catalyst and platinum constitutes from 10 to 125 parts by weight per million parts of said composition. A composition according to claim 2 where said composition contains an inhibitor for platinum group metal-containing hydrosilation catalysts. A composition according to claim 5 where said inhibitor is selected from the group consisting of acetylenic hydrocarbons and alcohols, tertiary amines and esters of maleic and fumaric acid. A composition according to claim 5 where said inhibitor is deactivated in the presence of molecular oxygen. A composition according to claim 7 where the oxygen-deactivated inhibitor is selected from (1) organophosphorus compounds selected from phosphine oxides, phosphines, phosphites, phosphinites, phospholene oxides and bis(dihydrocarbylphosphino)alkanes; (2) amine N-oxides and (3) sulfoxides, where the organic groups present on said organophosphorus compounds, amine oxides and sulfoxides are monovalent hydrocarbon radicals and the molar ratio of said inhibitor to platinum group metal present in said catalyst is from 2 to 200. A composition according to claim 1 where said first compound is selected from organic polymers and polyorganosiloxanes containing at least two alkenyl radicals per molecule, said second compound is selected from organic polymers and organohydrogenpolysiloxanes wherein the organic groups bonded to the silicon atoms of said second compound are monovalent substituted or unsubstituted hydrocarbon radicals that are free of ethylenic unsaturation, the sum of the average number of alkenyl radicals present per molecule of said first compound and the average number of silicon-bonded hydrogen atoms present per molecule of said second compound is greater than 4. A composition according to claim 2 where said composition is stable for at least one day at 25°C. in the absence of oxygen. A method for preparing an anaerobically stable organosiloxane composition that cures in the presence of molecular oxygen and is at least partially inhibited from curing in the absence of oxygen, said method comprising the sequential steps of 1) blending in the absence of oxygen the ingredients of the curable composition of claim 1; and 2) storing the resultant composition in the absence of molecular oxygen.

Inventors: BILGRIEN CARL JOSEPH, LUTZ MICHAEL ANDREW, NGUYEN BINH THANH, BILGRIEN, CARL JOSEPH, LUTZ, MICHAEL ANDREW, NGUYEN, BINH THANH
Applicants: DOW CORNING, DOW CORNING CORPORATION
Application year: 1994
Main classification: C08L83
IPC codes: C08L83, C08G77