Electrically conductive toner powder for image development in electrostatic, electrophotographic or magnetographic image-forming processes

Abstract: An electrically conductive toner powder, the separate particles of which contain thermoplastic resin, additives conventional in toner powders, such as colouring constituents and possibly magnetically attractable material, and an electrically conductive protonised polyaniline complex. The protonised polyaniline complex preferably has an electrical conductivity of at least 1 S/cm. The conductive complex can be distributed over the volume of the toner particles or be present in a polymer-matrix at the surface of the toner particles.

Description: The invention relates to a toner powder which in addition to a thermoplastic binder and other additives conventional in toner powders, e.g. magnetically attractable material and/or colouring constituents, contains as electrically conductive material a protonized polyaniline complex to give the toner powder the required electrical conductivity so that it can be deposited on a charge or potential pattern by inductive attraction. In electrostatography and electrophotography it is known to form a visible image by using electrically conductive toner powder having a resistivity of less than 10 12 Ω.cm, preferably between 10 4 and 10 9 Ω.cm, measured as described in Example 1 of UK patent 1 406 983. Examples of image-forming processes in which such electrically conductive toner powder is used will be found inter alia in the abovementioned UK patent 1 406 983, European patent 0 310 209 and US patent 3 563 734. Electrically conductive magnetically attractable toner powders can also be advantageously used in magnetographic image-forming processes, as described inter alia in US patent 5 154 944. Electrically conductive toner powders usually consist of thermoplastic resin particles in which additives, such as colouring constituents and possibly magnetically attractable material, are present in finely divided or dissolved form and which contain electrically conductive material distributed over the volume of the particles and/or applied to or just beneath the surface of the particles. One electrically conductive material which is frequently used is carbon, the carbon particles preferably being affixed to the surface of the toner particles or being embedded completely or partially in the surface thereof. At the same time the carbon particles act as colouring constituent. Examples of these toner powders are described in UK patent 1 406 983 and US patent 3 639 245. For electrically conductive coloured toner powders use is made of electrically conductive colourless relatively transparent substances, for example tin oxide which, to increase the electrical conductivity, is doped with antimony or fluorine. In this case too, the conductive material is preferably deposited on the surface of the toner particles. See European patent application 0 441 426. Deposition of the conductive powder material on the surface of the toner particles has the advantage that relatively little material is required, usually not more than 8% by weight, to achieve the required electrical conductivity. In the preparation of the toner powder it is necessary to ensure that virtually no loose conductive powder, i.e. not adhering to the surface, is present. The fine conductive powder can be deposited on the image-recording element (photoconductive or dielectric surface), so that the span of life thereof is greatly reduced. If the conductive powder is distributed over the volume of the toner particles, the required electrical conductivity is often only achieved at weight percentages of conductive powder of more than 25. These large quantities of conductive powder in turn have an adverse effect on the heat-fixing properties of the toner powder. The invention relates to a toner powder in accordance with the preamble of claim 1, characterised in that it contains a complex of a polyaniline and a protonising acid as conductive material. The toner powder according to the invention contains conductive material in the form of a polymeric compound deposited in a thin polymer-matrix on the surface of the toner particles or distributed as a conductive matrix in the volume of the toner particles. Suitable polyanilines and complexing protonising acids which can be used in combination therewith are described in International patent application WO 92/22911. Amongst the materials mentioned there for use in toner powder according to the invention, the protonised polyanilines having a conductivity of more than 1 S/cm have proved particularly suitable. The choice of conductive polyaniline complex is also determined by the thermoplastic resin or resin mixture used as the main constituent of the toner powder. Of course, a polyaniline complex should be used that is compatible with the toner resin (or the toner resin mixture) and preferably a polyaniline complex is used which can be so finely distributed in a melt of the toner resin as to give a conductive end product. Thus given correct choice of the polyaniline complex the toner powder according to the invention can be prepared in simple manner by melting the thermoplastic resin or resins forming the main constituent of the toner powder and distributing in the melt the required additives (such as magnetisable material and/or colouring constituents) together with the protonised complex of the polyaniline and protonising acid. After cooling of the melt, the material is ground to give particles of the required particle size. In combination with the epoxy and phenoxy resins, polyester resins derived from an alkoxylated bisphenol and a dicarboxylic acid, such as fumaric acid and mixtures of epoxy and polyester resins, which are frequently used in toner powders, polyaniline complexes of polyaniline emeraldine, protonised with camphor sulphonic acid or dodecylbenzene sulphonic acid, are particularly attractive. Apart from mixing in the resin melt, toner powders according to the invention can be produced by dissolving the thermoplastic resin in a suitable, preferably polar, solvent, distributing the protonised polyaniline complex, or the polyaniline and protonising acid, in the solution, then distributing the other additives in the liquid, and then evaporating the solvent and grinding the solid material to give particles of the required size. An alternative to evaporating the solvent and grinding the solid is spray-drying of the dispersion. Volume-conducting toner powders can be prepared in the above-described manner with only 5-10% by weight of polyaniline complex being required to achieve the required electrical resistivity of the toner powder (usually between 10 4 -10 9 Ω.cm). In this way, according to the invention, toner powders having good heat-fixing properties are obtained. A toner powder can also be prepared by preparing thermoplastic resin cores in which the additives (including magnetisable material and colouring material) are finely distributed and then coating these thermoplastic resin cores with a conductive polymer-matrix, preferably consisting of 5-10% by weight of protonised polyaniline complex and 90-95% by weight of the same thermoplastic resin as present in the cores themselves. In this way surface-conductive toner powder is obtained which is free of fine electrically conductive powder dust. Since the protonised polyaniline complexes used according to the invention are practically colourless, they are particularly suitable for preparing electrically conductive coloured toner powders. Example 1 100 g of polyester resin (Atlac 500 T of ICI, England) are melted, whereupon there are added to the melt and distributed thoroughly therein 9 g of protonised complex of polyaniline emeraldine and camphor sulphonic acid, prepared in accordance with the instructions of examples 1 and 3 of the patent application WO 92/22911. The following are then added to and homogeneously distributed in the melt: 33 g magnetisable pigment (type Bayferrox B 318 M of Bayer AG, Germany). After cooling, the solid mass is ground and sifted, particles having a size of between 10 and 25 micrometers being separated. The resulting toner powder had a resistivity of about 10 8 Ω.cm and was usable with good results for magnetic brush development of latent charge images formed on a photoconductor element. Example 2 160 g of polyester resin as used in Example 1 were melted, whereupon the following were homogeneously distributed in the melt: 20 g carbonyl iron having on average a particle size of about 3 micrometers 2.4 g Astra Phloxine 0.8 g Basonyl Rot 560-perchlorate 3.2 g Macrolex Fluorescent Yellow 10 GN. After cooling, the mass was ground and sifted, particles having a size of between ± 10 and ± 20 micrometres being separated. The resulting cores were rapidly added with agitation to a solution of the following: 20 g polyester resin (Atlac 500T) 1.2 g complex of polyaniline and dodecyl sulphonic acid prepared in accordance with Example 2 of patent application WO 92/22911 0.4 g Basonyl Rot 560-perchlorate 150 ml o-Cresol The dispersion was then spray-dried. This gave toner powder of a red colour with a resistivity of about 10 7 Ω.cm.

Claims: An electrically conductive electrostatic, electrophotographic or magnetographic toner powder, the separate particles of which contain thermoplastic resin, electrically conductive material, and possibly other additives conventional in such toner powders, such as magnetisable material and/or colouring material, characterised in that the electrically conductive material consists of a protonised polyaniline complex. A toner powder according to claim 1, characterised in that the protonised polyaniline complex is distributed over the volume of the thermoplastic resin. A toner powder according to claim 2, characterised in that the protonised polyaniline complex is present in a quantity of between 5 and 10% by weight. A toner powder according to claim 1, characterised in that the protonised polyaniline complex is present in a polymer-matrix at the surface of the toner particles. A toner powder according to one or more of the preceding claims, characterised in that the protonised polyaniline complex has a conductivity of at least 1S/cm.

Inventors: VAN RITTER HENDRIK RALPH PATRI, VAN RITTER, HENDRIK RALPH PATRICK
Applicants: OCE TECH BV, OCE-TECHNOLOGIES B.V.
Application year: 1994
Main classification: G03G9
IPC codes: G03G9