Process and apparatus for producing a selfsupporting package having an outlet stopper

Abstract: There is disclosed a process for producing a self-supporting package having an outlet stopper (3) which comprises: (a) a process for supplying a self-supporting bag (21) which has an opening part for filling contents at the top thereof and holding the bag at a vertical position, (b) a process for opening the opening part of the self-supporting bag, (c) a process for filling the self-supporting bag with contents, (d) a process for supplying an outlet stopper which has an outlet (2) with a stopper on a ship-shaped flange (7) to the opening part, and (e) a process for sealing the side faces of the ship-shaped flange of the main part of the outlet stopper to the inner side faces of the opening part of the self-supporting bag. These processes are conducted in the order of the processes (a), (b), (c), (d) to (e), consecutively. An apparatus comprising mechanisms corresponding to the processes (a) to (e) is also disclosed. The self-supporting package having an outlet stopper and filled with contents can be produced with high productivity. Shape of the self-supporting package can be freely selected. Sealing time is shorter than that of conventional heat sealing processes. The sealing can be surely achieved even when foreign substances are present on the face of sealing. The self-supporting package produced has excellent sealing stability and simple structure, is provided with an outlet stopper at the top of the package, and is easy for handling.

Description: The invention relates to a process for producing self-supporting packages having an outlet stopper, which packages are used for containing fluid materials, and to an apparatus for producing said packages, the process comprizing the features of the preamble of claim 1 and the apparatus comprizing the features of the preamble of claim 10 Commercial products which have heretofore been sold in bottles of glass or hard plastics, such as milk, soy sauce, oil, cosmetics and other like products of a fluid or slurry form, are recently sold in packages of paper cartons, bottles of thin plastic sheets, and bags of plastic films (pouches). An outlet stopper is attached to paper cartons and thin plastic bottles. A necessary amount of the content is taken out each time from the package through the outlet stopper and the remaining amount is kept in the package by closing the outlet stopper. Pouches having an outlet stopper are also used. Pouches having the self-supporting property which can stand self-supported on a table in the condition filled with contents are produced for realizing still easier handling in use. As self-supporting package having an outlet stopper, a package having an opening part at the top is preferred. Self-supporting packages having an opening part at the top, such as those disclosed in Fig. 1 [JP-U1-60(1985)-139754] and in Fig. 2 [JP-U1-63(1988)-76653], are currently produced. However, the self-supporting packages shown in Figs 1 and 2 have drawbacks in that bulkiness of the main part 1 of the outlet stopper causes a problem in the process of supplying the self-supporting bag, and that the speed of filling contents through the inlet-outlet 2 of the main part of the outlet stopper 1 is very low because the inlet-outlet is generally small, and increase in the productivity is difficult. For increasing the productivity by increasing the speed of filling, a method in which a large open part 4 is formed in addition to the outlet stopper 3 as shown in Figs 3 and 4, and the large open part is closed by heat sealing after the package is filled with contents, has been adopted. However, this method has drawbacks in that bulkiness of the outlet stopper makes a problem in the process of supplying the self-supporting bag and that the outlet stopper cannot be formed at the central top of the self-supporting package and that the shape of the package is limited. As the method of sealing or adhering a packaging bag having a sealing layer of a thermoplastic resin to an outlet stopper made of a thermoplastic resin, a method of heat sealing, a method of using an adhesive, and a method of sealing with high frequency dielectric heating or dielectric heating, are known. Among these methods, the method of using an adhesive has drawbacks in that time and care are required, that long time is necessary for curing, that smell remains after the adhesion, and that many types of adhesive cannot be used depending on contents, and this method is not practically used. The method of sealing with high frequency dielectric heating has drawbacks in that thermoplastic resins generating heat with high frequency dielectric heating are limited to resins having a large dielectric loss such as polyvinyl chloride and polyvinylidene chloride, and that a special method, such as mixing metal powder into the thermoplastic resin to be heated or including pieces of metal in the packaging bag or the outlet stopper, must be used because the high frequency dielectric heating is conducted by making use of Ohm loss caused by the vortex current induced in the material to be heated which is a conductive material like a metal. Therefore, application of this method is very limited. The method of heat sealing is conducted by heating a packaging bag and an outlet stopper with a heating plate from the outside of the packaging bag while they are pressed together. The principle of the heat sealing is to make use of heat transfer and is simple. The heat sealing can be safely performed by using a suitable condition as long as the material of the sealing layer at the inner face of the packaging bag and the material of the outlet stopper are the same. Therefore, the method of heat sealing is generally used. Recently, sealing methods of an outlet stopper using ultrasonic vibration have been proposed. An example of such method is disclosed in JP-U1-60(1985)-187032. In the disclosed method, an outlet stopper like a round stopper having a cylindrical sealing face is sealed by ultrasonic vibration to a plastic film before the plastic film is processed to the form of a bag, and then a packaging bag is prepared from the plastic film having the outlet stopper. This method of preparation of a bag inevitably requires that the packaging bag has a shape in which the outlet stopper is attached to the front side part or the back side part. The outlet stopper at the side part disturbs the operation of filling contents in the process that follows. This causes difficulty for automation and also requires a complicated process to seal the open part again. Therefore, the disclosed method is inferior as industrial process with respect to workability as well as to productivity. For forming a pouch in a horizontal sealing machine it is known (US-A-4,512,136) to seal a bottom outlet element to the pouch by means of ultrasonic energy. A method and apparatus of heat sealing a packaging bag and an outlet stopper in accordance with the preambles of claims 1 and 10 together which has heretofore been used widely is described in the following with reference to Figs 5, 6 and 7. Fig. 5 shows the whole part of an outlet stopper 3. The outlet stopper is composed of the main part 1 and a cap 5. Closing and opening of the main part 1 with the cap 5 are made by using a screw formed on each of the main part 1 and the cap 5. The main part 1 is made of a thermoplastic resin and generally produced by a molding method, such as injection molding. As shape of the sealing part 6 of the outlet stopper, a shape such as that of the ship-shaped flange 7 shown in Fig. 5 is preferable because a large area can be obtained for sealing with the packaging bag. One to several ribs 8 for sealing may be formed on the sealing face of the ship-shaped flange 7. The cap 5 is made of a synthetic resin such as a thermoplastic resin or a metal such as aluminium. The material of the cap is not limited as long as the cap 5 and the main part 1 of the outlet stopper can be screwed into each other and closed together tightly. Fig. 6 (A) shows a packaging bag 9 in the condition before the main part 1 of the outlet stopper is inserted into the opening part 4 at the top of the bag. Fig. 6 (B) shows the packaging bag in the condition after the main part 1 of the outlet stopper has been inserted into the opening part 4 and sealed to the bag. Before the outlet stopper 3 is sealed, the packaging bag 9 has the shape of so called three side sealed bag in which the bottom part and both side parts have been sealed with a suitable method such as heat sealing. The material film of the packaging bag generally has a single layer structure or a multi-layer structure having two or more layers made of thermoplastic resins. As material of the innermost layer, a material of the same type as that of the sealing part 6 of the main part 1 of the outlet stopper 3 is generally used to assure strength of the sealing. When the sealing of the outlet stopper to the packaging bag 9 is made after the packaging bag 9 is filled with contents, the main part 1 of the outlet stopper 3 is generally sealed to the packaging bag while the cap 5 is screwed onto the main part 1 of the outlet stopper. When the sealing is made before the bag 9 is filled with contents, the main part 1 of the outlet stopper 3 is generally sealed to the packaging bag while the cap 5 is taken off from the main part 1 of the outlet stopper, and the cap 5 is screwed onto the main part 1 of the outlet stopper after the bag is filled with contents through the inlet-outlet 2. Fig. 7 is a perspective view illustrating the sealing process of an outlet stopper by heat sealing when the outlet stopper 3 is inserted into the packaging bag 9 by a suitable method, placed at a specified position and sealed to the packaging bag. The ends of sealing plate 10 and sealing plate 11, which are arranged at positions facing to each other, have each a shape corresponding to that of the sealing part 6 of the ship-shaped flange 7 of the outlet stopper 3 which is shown in Fig. 5, and also have each straight side parts 12 which are straightly extending sideward from the shape corresponding to that of the sealing part 6 so that the side parts of the packaging bag shown in Fig. 6 can be sealed simultaneously. The sealing plates 10 and 11 are each connected to heating plates 13 and 14 respectively, by forming a single body or by using bolts. The sealing plates 10 and 11 and the respective heating plates 13 and 14 are made of a metal such as aluminum, stainless steel, and steel. The heating plates have each a heating device such as a cartridge heater arranged in it or a heater plate attached to the surface, and a temperature sensor to control the heating plate at a temperature suitable for heat sealing. The heating plates 13 and 14 move away from or to each other to open or close the heating plates, respectively, as indicated by the arrows in Fig. 7. After the outlet stopper 3 is inserted into the packaging bag 9, the heating plates 13 and 14 move to each other to close the sealing plates when the center of the outlet stopper 3 inserted into the packaging bag 9 reaches the position at the center of the sealing plates 10 and 11 which are arranged at positions facing to each other. The sealing layer, which is the innermost layer of the packaging bag 9, and the ship-shaped flange 7 are heated and sealed to each other by pressing the heating plates 13 and 14 to the ship-shaped flange 7 of the main part 1 of the outlet stopper 3 for a specified time at a suitable pressure. Then, the heating plates 13 and 14 move away from each other to open them. By repeating this operation twice or more, a strong sealing can be achieved. The heating plates 13 and 14 are driven by a suitable mechanism such as an air cylinder, an oil pressure cylinder, and mechanical cam driving. The time necessary for one sealing is 1 to 3 seconds, 1.5 seconds in general, although the time is different depending on material and thickness of the packaging bag 9, material of the ship-shaped flange 7 of the main part 1 of the outlet stopper 3, area for the sealing, and pressure for the sealing. Because sufficient sealing strength cannot, be obtained by one sealing operation alone, the sealing operation is repeated two to three times. Furthermore, a process for cooling the sealed part is required to cool the sealed part quickly and prevent detachment of the sealed part. Therefore, increase in the productivity is limited by these factors. Particularly, when a bag is filled with contents through the outlet-inlet 2 of the main part 1 of the outlet stopper 3 shown in Fig. 6 after the outlet stopper 3 is sealed to the packaging bag 9, the time required for filling the packaging bag with the contents, in other words the filling speed, is decreased to a large extent because the outlet-inlet is small. Therefore, increase in the productivity is further difficult. When the packaging bag 9 is filled with contents while the opening part 4 in the packaging bag 9 is open, in other words, when the packaging bag is filled with contents at a high speed while a large opening is made in the packaging bag before the outlet stopper is attached to the packaging bag and then the outlet stopper 3 is sealed to the bag, problems such as those described in the following arise. When the contents are fluid, the fluid contents tend to adhere to the sealing face of the packaging bag 9. The adhered fluid is a foreign substance and is vaporized by the heat of sealing. This causes formation of bubbles on the sealed part and formation of so called blisters. When these phenomena occur to a large extent, defect sealing such as broken bag at the sealed part frequently occurs. When solid contents adhere to the sealing part, such a trouble that the sealing cannot be made at all arises and reliability of the sealing to keep the contents is lost. Particularly, when the content is a food, germs invade into the package through the defect sealed part to cause rot by contamination with the germs. When the content is a drug which requires sterile condition, the worst result of contamination with germs arises. A process and an apparatus for producing self-supporting packages having an outlet stopper comprising the features of the preamble of Claim 1 and the preamble of Claim 10, respectively, are known in the art and described with reference to Figures 5, 6 and 7. DE-A-2 720 907 discloses a similar prior art. The object of the invention accordingly is to provide self-supporting packages which are produced with excellent workability, can be filled with contents at high filling speed, can be provided with an outlet stopper by sealing in short time and, by using an apparatus of simple structure, can be produced with reliable sealing even when foreign substances are present at the sealing face, and with excellent sealing stability, can be produced also with high productivity, and have an outlet stopper at the top of the package for easy handling to consumers. This object is solved in accordance with the present invention by a process comprising the features of Claim 1. Particular improvements of this process are subject matter of Claims 2 to 9. Furthermore, this object is solved in accordance with the present invention by an apparatus comprising the features of Claim 10. Particular improvements of this apparatus are subject matter of Claims 11 to 14. As the result of the extensive studies undertaken by the present inventors to develop a process efficiently producing self-supporting packages which can be handled easily and have excellent sealing stability, it was found that excellent self-supporting packages can be produced without adverse effect on the productivity when the package is filled with contents through a large opening part for filling contents at the top of the bag, then an outlet stopper is attached to the opening part, and the outlet stopper is sealed to the bag by ultrasonic vibration. The present invention has been completed on the basis of this finding. The invention proposes a process for producing a self-supporting package which comprises holding a self-supporting bag having a sealing layer made of a thermoplastic resin on the inner side at a vertical position, filling contents after opening an opening part of the self-supporting bag, supplying an outlet stopper made of a thermoplastic resin to the opening part, and sealing the outlet stopper and the opening part together, and an apparatus for producing said package. The present invention relates to a process and an apparatus having such advantages that the self-supporting bag can be filled with contents at high speed, that excellent sealing can be realized in short time by sealing the layer on the self-supporting bag and the outlet stopper together by ultrasonic vibration, and that the sealing can be surely achieved even when foreign substances are present on the face of sealing. Other and further objects, features and advantages of the invention will appear more fully from the following description. The invention will be further described with reference to the accompanying drawings, wherein Fig. 1 is a side view of a conventional self-supporting bag having an outlet stopper, Fig. 2 is a side view of another conventional self-supporting bag having an outlet stopper, Fig. 3 is a side view of another conventional self-supporting bag having an outlet stopper, Fig. 4 is a side view of another conventional self-supporting bag having an outlet stopper, Fig. 5 is a perspective view of a conventional outlet stopper, Fig. 6 is a perspective view showing a self-supporting bag before and after an outlet stopper is sealed to it, Fig. 7 is a perspective view illustrating the process of sealing an outlet stopper by heat sealing to a self-supporting bag, Fig. 8 is a side view of a self-supporting package, Fig. 9 is a schematic illustration explaining the process for producing self-supporting packages of the present invention, Fig. 10 is a partially sectional side view of the main part of the outlet stopper, Fig. 11 a bottom plan view of the main part of the outlet stopper shown in Fig. 10, Fig. 12 is a sectional top view of the main part of the outlet stopper on the C-C plane shown in Fig. 10, Fig. 13 is a detail view of part of the sealing rib on the main part of the outlet stopper shown in Fig. 10, Fig. 14 is a perspective view showing a mode of application of the ultrasonic method of the present invention for sealing part of the outlet stopper when an ultrasonic actuator and an anvil are used in combination, Fig. 15 is a perspective view showing a mode of application of the ultrasonic method of the present invention for sealing part of the outlet stopper when two ultrasonic actuators and two ultrasonic vibration generators are used in combination, Fig. 16 is a perspective view showing a mode of application of the ultrasonic method of the present invention for sealing part of the outlet stopper when two ultrasonic actuators and one ultrasonic vibration generator of a switching type are used in combination, Fig. 17 is a front view and a side view showing the mode of application of a horn, Fig. 18 is a front view and a side view showing the mode of application of an anvil, Fig. 19 is a schematic illustration explaining the process for producing self-supporting packages of the present invention, and Fig. 20 is a schematic illustration further explaining the process for producing self-supporting packages of the present invention. The present invention is described in more detail with reference to examples in the following. A self-supporting package having an outlet stopper is prepared by the process in which, after a self-supporting bag is filled with contents through an opening part for filling contents at the top of the bag, an outlet stopper is supplied to the opening part, and the side parts of the ship-shaped flange are sealed to the inner sides of the opening part by the ultrasonic vibration. The self-supporting package is produced by sealing the outlet stopper to the bag after the bag is filled with contents. The self-supporting bag in the present invention means a bag which keeps a specified shape and stands self-supportedly on a plane when the bag is filled with contents. The self-supporting package can be filled with contents through a large opening part for filling contents which is placed at the top of the bag and filled with contents at the same speed as those of the conventional pouches having no stopper and bags having stoppers at the side of the bag shown in Figures 3 and 4. A bag having a constriction on the side seal lines, linear grooves and ribs on the surface of the bag, and self-supporting property in the whole parts of the bag including the upper parts, is preferably used as the self-supporting bag of the present invention. The self-supporting bag is composed of the part constituting the trunk and the part constituting the bottom each made of a plastic film. Type of the plastic film is not limited but various types of plastic film can be used. Examples of the plastic used for the plastic film include polyolefins, such as polyethylene and polypropylene; polyolefins containing chlorine, such as polyvinyl chloride; aromatic vinyl polymers, such as polystyrene; polyurethanes; polyesters, such as polyethylene terephthalate; polyamides, such as nylon; polycarbonates; polyarylates; polyethers; copolymers of ethylene with copolymerizable monomers, such as ethylene-vinyl acetate copolymers and ethylene-acrylic acid copolymers; ionomers; and the like. The plastic film may be used singly or as a combination of two or more types. When the part constituting the trunk and the part constituting the bottom of the bag are separately prepared, these parts may be made of the same material or different materials. However, it is preferable that these parts are made of the same material because of easier adhesion. The plastic film may have a single layer structure. However, a multi-layer structure having two or more layers is preferable for the process for production of the self-supporting bag. As the multi-layer plastic film having two or more layers, a multi-layer film containing various types of laminated plastic layer, such as layers of the plastics described above and other plastics, can be used. A multi-layer plastic film containing laminated layers of plastics having different melting points is preferable. When the multi-layer plastic film containing laminated layers of plastics having different melting points is used, the plastic layer having a lower melting point is placed at the inner side of the package and used for the sealing. Difference in the melting points is not particularly limited, but preferably 10°C or more, more preferably 20°C or more, and most preferably 30°C or more. Examples of the plastic layer having a lower melting point include layers of polyolefins, such as polyethylene, polypropylene, and the like. Examples of the plastic layer having a higher melting point include layers of engineering plastics, such as stretched nylon 66, stretched polyethylene terephthalate, and the like. A plastic film containing aluminum foil, or a plastic layer, such as a layer of saponified ethylene-vinyl acetate copolymers (EVOH), polyvinylidene chloride, and the like, as the intermediate layer may be used for providing the barrier property to the plastic film. A soft laminated film in which a layer made of a material other than plastics, such as aluminum, paper, and the like, is laminated with a plastic layer, may be used as the plastic film. A plastic film printed on it may be used as well. The self-supporting bag produced by the process of the present invention preferably has the following structure: the bag is composed of the part constituting the trunk and the part constituting the bottom; the part constituting the bottom is folded to make an approximate shape of W by the combination with the parts constituting the trunk; the bag has side seal lines shaping the part constituting the trunk in such a manner that the upper part of the bag has a narrower width than that of the bag at the folded part of the part constituting the bottom; the bag has a constriction part formed by the side seal lines at the middle part of the height of the bag when the bag is in the self-supporting condition; and a pair of linear grooves and a pair of linear ribs each having an approximate shape of arc convex toward the inner side are formed in the trunk part each at a position separated from the side seal line by a distance of 10 % or more of the width of the bag toward the inner side and at approximately the same height as that of the constriction. Size of the opening part is preferably 60 mm or more for generally used self-supporting bags in order to increase the productivity by increasing the speed of filling. An example of the shape of the self-supported bag advantageously produced by the process of the present invention is described with reference to the drawings. In Figure 8, side seal lines 15 which are elements constituting the self-supporting package are formed on the flat part of the part constituting the trunk part by sealing. The side seal lines 15 on the part constituting the trunk of the self-supporting bag has a constriction part at an intermediate position between the points B and C. Width of the bag at the point A in the constriction part is narrower than that at the point C. The point A is located at the inner side of the straight line connecting the points B and C. Distance between the point A and the straight line is preferably 4 to 12 % of the width of the bag. Points A', B' and C' and a constriction part are formed on the side seal line 15 at the other side. The self-supporting bag has a pair of linear groove and a pair of linear rib 16 having a curved part of an approximate shape of an arc convex to the inner side at the inner side of the constriction part and at symmetric positions of both sides. The pairs of linear groove and linear rib 16 are formed on both faces of the part constituting the trunk part. When the points at which a pair of the curve having approximate shape of arc comes closest to each other are designated as D and D', and the points at which the straight line connecting the points D and D' crosses the side seal lines are designated as E and E', the straight line connecting the points D and D' is preferably at a position lower than the straight line connecting the points A and A' by 0 to 20 % of the height of the self-supporting bag, and the distance between the points D and E is preferably 10 to 35 % of the distance between the points E and E'. The pairs of linear groove and linear rib having approximate shape of arc and convex toward inner side at the constriction part may be extended to the upper and lower parts from the constriction part along the side seal lines. The self-supporting bag is easily folded at the linear grooves and the linear ribs and, when the self-supporting bag is filled with contents, the linear grooves and the linear ribs are folded to form the end part of the concave part formed by the presence of the constriction. The grooves and the ribs assures the formation of this concave part in a specified shape and such an excellent self-supporting property is exhibited that the self-supporting property can be maintained even when the amount of the contents is decreased. Furthermore, because the concave part can be kept at a specified position in a specified shape, a very excellent property of keeping the shape can be obtained. The part constituting the bottom folded to form the shape of W with the part constituting the trunk is sealed at the heat seal lines 17 and 18 as well as at the side seal lines 15 so that the bottom part takes an approximately hexagonal shape when the self-supporting bag is filled with contents. Length between the folded part 19 and the end of the bottom part can be suitably selected in accordance with the required properties of the self-supporting package, and is preferably 10 to 40 % of the width of the self-supporting bag. At the top of the self-supporting bag, an opening part 4 is formed. Width of the opening part is preferably about 50 % of the width of the bag at the folded part in the bottom part. In Figure 9, the self-supporting bag 21 placed on a magazine 20 is transferred to a specified position on the table by the apparatus for supplying a bag and held at a vertical position. Method of holding the bag is not particularly limited. For example, the bag can be held by pinching both ends of the bag with a pair of gripper 22. A process for printing on the bag may be added before or after the process of supplying the bag, if necessary. Then, the self-supporting bag is transferred to the opening process by rotation of the table. The opening process of the present invention can be conducted, for example, by opening both sides of the self-supporting bag slightly using vacuum suction plates 23 and blowing the air into the bag from the air blowing nozzle 24. After the opening part of the self-supporting bag is opened, the self-supporting bag is transferred to the filling process. The filling process of the present invention may be arranged in many stages, according to necessity. The fluid used in the present invention is not particularly limited and ranges from a liquid of low viscosity to a paste of high viscosity. Detergents, salad oils, cosmetics, tomato ketchup, mayonnaise, honey, adhesives, and the like, can be used. Solids may be added when the solids are uniformly dispersed or dissolved in a fluid which is filled together. In the filling process, a specified amount of a fluid, a paste, or a solid is filled using a conventional apparatus for quantitative supply 25. The self-supporting bag finished with the filling is transferred to the process of supplying the outlet stopper. In the process for supplying the outlet stopper of the present invention, an outlet stopper which has an outlet with a stopper on a ship-shaped flange is supplied to the opening part of the bag opened in the preceding process and held at a specified position. Material of the outlet stopper of the present invention is not particularly limited so long as the material can be sealed with the material of the innermost layer of the self-supporting bag. For example, polyethylene, polypropylene, polyester, and the like, can be used. However, the same material as that of the innermost layer is preferably used for surely achieving the sealing. It is preferred that the shape of the outlet stopper of the present invention takes the ship-shape shown in Figure 5 which has a large sealing area for sealing to the opening part of the bag. Furthermore, it is particularly preferred that one to several sealing ribs having a width of 0.2 to 0.8 mm and a height of 0.05 to 0.4 mm are formed on both sides of the ship-shaped flange of the outlet stopper where the ultrasonic sealing is made, a plurality of reinforcing rib are formed in the space between the two sides of the ship-shaped flange, and parts with increased thickness having an arc shape or a tapered shape are formed at joint parts of the reinforcing rib and the ship-shaped flange and/or joint parts of the sides of the ship-shaped flange. As the shape of the sealing part 6 of the main part 1 of the outlet stopper, the ship-shape of the flange 7 which can have a large sealing area for sealing to the self-supporting bag 21 is preferable. Material of the cap 5 is a synthetic resin such as a thermoplastic resin or a metal such as aluminum. Material, shape and structure of the cap are not otherwise particularly limited so long as screwing and sealing with the main part of the outlet stopper is surely achieved. In the insertion of the outlet stopper 3 into the self-supporting bag 21, both upper sides of the self-supporting bag 21 are held with sucking by a sucking tool, such as a vacuum sucking plate, and pulled apart to the outward directions. Then, the opening part 4 is fixed in this condition. While the self-supporting bag is held in this condition, the outlet stopper 3 is held with a gripping and inserting tool such as a robot at a position close to the cap 5, or at a specially formed gripping flange 39, inserted into a specified position in the opening part 4 of the self-supporting bag 21, and fixed at this position. It is preferred that a temporary sealing process is conducted at the same time. In the temporary sealing process, the sealing layer of the opening part 4 of the self-supporting bag 21 and the ship-shaped flange 7 of the main part 1 of the outlet stopper are spot sealed together by lightly pressing the opening part 4 from one or both directions at the outside of the bag 21 to the ship-shaped flange 7 with a heated rod or the like which is controlled to a suitable temperature. The rod or the like is not shown in the figure. For the operation of the temporary sealing, suitable methods other than the method of heat sealing with a rod or the like described above, such as the ultrasonic sealing and high frequency method, may also be adopted according to the material. An examples of the shape of the outlet stopper of the present invention is described with reference to Figures 10, 11, 12, and 13. Figure 10 shows a partially sectional side view of the main part of the outlet stopper. Figure 11 shows a bottom plan view of the main part of the outlet stopper shown in Figure 10. Figure 12 shows a sectional top view of the main part of the outlet stopper on the C-C plane shown in Figure 10. Figure 13 shows detail view of the sealing rib part of the main part of the outlet stopper shown in Figure 10. In Figure 10, the main part 1 of the outlet stopper has a screw part 26 in the upper part and the stopper can be opened or closed by screwing of the cap 5 shown in Figure 5. An outlet hole 27 for pouring out contents is formed in the main part 1 of the outlet stopper. The lower part of the main part 1 of the outlet stopper has a ship-shaped flange 7, the sides of which form the sealing part 6 of the outlet stopper. On the sides of the ship-shaped flange 7, one or a plurality of sealing rib 8 are formed. Three ribs are formed in the example shown in Figure 10. The opening part 4 of the self-supporting bag 21 shown in Figure 8 is brought to a position close to the upper end 28 of the sealing part 6 of the ship-shaped flange 7 shown in Figure 10 and sealed to the sealing part 6 with ultrasonic vibration by the ultrasonic method. In Figures 10 and 11, it is preferred that the sealing part 6 of the ship-shaped flange 7 has a convex shape, such as an arc shape or elliptic shape. The arc shape is more preferable because preparation of the mold for molding the main part 1 of the outlet stopper by injection molding or the like is easier and the shape is simple. Therefore, the arc shape is shown in the example. It is preferred that two end parts 29 and 30 of the ship-shaped flange 7 have a shape tapered toward the tip in order that the sealing extending to the side parts 31 of the bag shown in Figure 8 can be achieved smoothly and surely. The sealing rib 8 of the ship-shaped flange 7 has a shape having a suitable height from the sealing base 32 which is the base part of the sealing part 6 of the outlet stopper, and a convex section. The sealing rib 8 is laid along the arc shape of the sealing base 32. The sealing base 32 has a convex part 33 of a radius of curvature R 1 shown in Figure 11 and the ends 29 and 30 of the ship-shaped flange 7 have each a concave part 34 of a radius of curvature r 1 shown in Figure 11. The convex part 33 and the concave parts 34 are connect to each other with the tangents common to the both. In the space part 35 between the two sides of the ship-shaped flange 7, a plurality of reinforcing ribs are formed and parts of increased thickness having an arc shape or a tapered shape are formed at the joint parts 37 which are the joint parts of the reinforcing rib 36 and the sides of the ship-shaped flange 7. Parts of increased thickness having an arc shape are also formed at the joint parts 38 where two sides of the ship-shaped flange 7 are jointed. The convex parts 33 are pressed between the horn and the anvil or between the two horns and the reinforcing rib 36 provides the strength enduring the pressure. When the ship-shaped flange 7 is used in the sealing with the mechanical vibration of the ultrasonic frequency, stress of the high frequency vibration is concentrated at the joint parts 37 and the joint parts 38 and cracks tend to be formed when the joint parts 37 and the joint parts 38 have a shape of a sharp angle. Therefore, the parts of increased thickness having an arc shape or a tapered shape are formed at the joint parts 37 and the joint parts 38 to prevent this phenomenon. This structure is characteristic for the ultrasonic sealing and is not necessary for conventional heat sealing. Figure 12 shows a sectional top view of the main part of the outlet stopper on the C-C plane shown in Figure 10. A gripping flange 39 having parallel faces is formed at an intermediate position above the ship-shaped flange 7 and below the screw part 26. When the ship-shaped flange 7 of the main part 1 of the outlet stopper is inserted into the opening part 4 of the self-supporting bag 21 shown in Figure 8, the main part 1 of the outlet stopper is held at the gripping flange 39 with a gripping and inserting tool, such as a robot. Figure 13 shows a detail view of the sealing rib 8 formed on both sides of the ship-shaped flange 7 shown in Figure 10. The figure shows a part of the sealing rib 8 formed in the convex part 33 shown in Figure 11. Width W and height h of the sealing rib 8 formed on the sealing base 32 are important factors in the ultrasonic sealing. When the sealing layer in the opening part 4 of the self-supporting bag 21 shown in Figure 8 and the sealing rib 8 are sealed together by the ultrasonic vibration, the sealing rib 8 plays the roll of an adhesive. The sealing rib melts with the friction heat and the molecular heat and, when the sealing completed, the sealing layer of the self-supporting bag is sealed directly to the sealing base 32. In the ultrasonic sealing, quality of the sealing is varied depending on length, number, width W, and height h of the sealing rib 8. Length and number of the sealing rib are the factors directly related to the output power of the ultrasonic vibration generator, and the width and the height of the sealing rib are the factors directly related to reliability of the sealed part. For example, when the width of the sealing rib 8 is more than 0.8 mm and the height is more than 0.4 mm, time required for the sealing is increased and the sealed part of the self-supporting bag is broken by the severe vibration of the ultrasonic wave. When the width is less than 0.2 mm and the height is less than 0.05 mm, amount of the material having the function of the adhesive in the sealing is decreased and the sealing becomes incomplete. A width of the sealing rib 8 of 0.2 to 0.8 mm, preferably 0.3 to 0.6 mm, and a height of the sealing rib 8 of 0.05 to 0.4 mm, preferably 0.1 to 0.3 mm, are preferable to obtain the excellent ultrasonic sealing. Number of the sealing rib 8 is preferably plural to increase the reliability. The output power of the ultrasonic vibration generator required for the sealing can be decided basically in accordance with the length and the number of the sealing rib 8. The self-supporting bag filled with contents and the outlet stopper are transferred to the next sealing process while they are kept at the same relative positions. In the sealing process of the present invention, the inner face of the opening part of the self-supporting bag and the side face of the flange of the outlet stopper can be sealed by using a sealing apparatus 40 for heat sealing, high frequency sealing, ultrasonic sealing, or the like. The ultrasonic sealing is particularly preferable among them. In the ultrasonic sealing used in the present invention, the outlet stopper made of a thermoplastic resin is inserted into the self-supporting bag having the sealing layer made of a thermoplastic resin and sealed together. The process of the present invention has the following characteristics. As the first characteristic of the process: an ultrasonic actuator which generates mechanical vibration of an ultrasonic frequency is placed at a position on the axis line perpendicular to the sealing faces of the outlet stopper; an anvil or another ultrasonic actuator is placed at a position on the opposite side of the outlet stopper and on the axis line perpendicular to the sealing faces of the outlet stopper in such a manner that the ultrasonic actuator is faced to the anvil or the other ultrasonic actuator at the opposite side of the outlet stopper; the ultrasonic actuator at one side and the anvil or the other ultrasonic actuator at the opposite side are driven to open or close along the axis line perpendicular to the sealing faces of the outlet stopper in a synchronized manner; and the side faces of the ship-shaped flange of the outlet stopper are sealed to the inner side faces of the opening part of the self-supporting bag. As the second characteristic of the process: resonance frequencies of the ultrasonic actuators at both sides are different from each other. As the third characteristic of the process: the ultrasonic actuators at both sides are driven by one ultrasonic vibration generator having a switching function in such a manner that the actuators at both sides are consecutively driven by the switching function of the ultrasonic vibration generator. As the fourth characteristic of the process: the working end of a horn in the ultrasonic actuator and/or the receiving part in the anvil has such a shape that the concave part of the working end and/or the receiving part has a radius of curvature which is obtained by adding 0.6 to 1.4 times the thickness of the self-supporting bag to the radius of curvature of the corresponding convex part of a sealing base in the ship-shaped flange and, and the convex part of the working end and/or the receiving part has a radius of curvature which is obtained by subtracting 0.6 to 1.4 times the thickness of the self-supporting bag from the radius of curvature of the corresponding concave part of the sealing base in the ship-shaped flange. Figure 14 shows a perspective view showing a mode of application of the ultrasonic method of the present invention to the sealing part of the outlet stopper. An example of the process in which an ultrasonic actuator 41 and an anvil 42 are used in combination is shown in the figure. The ultrasonic actuator 41 is basically composed of an ultrasonic vibration generator 43, a booster 44, and a horn 45. When amplitude of vibration of the working end 46 of the horn 45 is sufficient for ultrasonic sealing, the horn 45 may be connected directly to the ultrasonic vibration generator 43 without using the booster. As the ultrasonic vibration generator 43, any of an electric strain vibration generator and a magnetic strain vibration generator can be used. The electric strain vibration generator is preferable because of superior conversion efficiency of electric energy to mechanical energy. Ultrasonic resonance frequency is 10 to 100 kHz, preferably 15 to 40 kHz, because a larger vibration amplitude can be obtained with less noise. As material of the booster, an aluminum alloy, steel or a titanium alloy is preferable. A titanium alloy is particularly preferable because it has the highest toughness under the high frequency of the ultrasonic vibration and has excellent durability. It is suitable that amplification by the booster 44 is in the range of 1.2 to 4, preferably 1.5 to 2.5, when a titanium alloy is used because formation of crack by the stress concentration can be prevented. As material of the horn 45, a high tension aluminum alloy, such as duralmine and the like, or a titanium alloy, is preferable because of high toughness. It is not desirable that the horn 45 must have a shape generating an excessively large amplitude. Therefore, it is desirable that the amplification is made by the booster 44 in principle and the amplification by the horn is kept at 1 to 2 to avoid excessive load on the horn 45. The amplitude of the working end 46 of the horn 45 is 10 to 120 µm, preferably 30 to 90 µm. When an electric strain type vibration generator is used, the output power of the ultrasonic vibration of 0.5 to 4 KW, preferably 1.5 to 3 KW, is suitable for the object of the present invention. The ultrasonic vibration element 43 of the ultrasonic actuator 41 is connected to the ultrasonic vibration generator 48 with a high frequency cable 47. The anvil 42 is composed of a receiving part 49 having an end of the same shape as that of the working end 46 of the horn 45 and the main part 50 of the anvil. The receiving part 49 and the main part 50 of the anvil may be formed as a single body or connected with a binding tool such as a bolt. Material of the anvil 42 is a metal, such as aluminum, an aluminum alloy, iron, stainless steel, and the like, or a combination of these metals. The self-supporting bag 21 and the outlet stopper 3 which have been sealed together temporarily is transferred to the next process of ultrasonic sealing shown in Figure 9. The ultrasonic actuator 41 and the anvil 42 are placed at positions on the axis line which is perpendicular to the line connecting the end parts 29 and 30 of the ship-shaped flange 7 of the outlet stopper 3. The ultrasonic actuator 41 and the anvil 42 are fixed by a suitable method to a mechanism which can move along the axis line perpendicular to the line connecting the ends 29 and 30 of the flange 7 as shown by the arrow in Figure 14. The mechanism is, for example, a reciprocally driving mechanism containing an air cylinder, an oil cylinder, a mechanical cam, or a combination of them. The ultrasonic actuator 41 and the anvil 42 wait in the open condition. When the self-supporting bag 21 temporarily sealed with the outlet stopper 3 is supplied and stops at the specified position on the axis line of the ultrasonic actuator 41 and the anvil 42, the ultrasonic actuator 41 and the anvil 42 move to the direction of closing in a synchronized manner and press the sealing parts 51 at both sides of the self-supporting bag 21 simultaneously. In Figure 14, the ultrasonic actuator 41 moves to the left and the anvil 42 moves to the right. The ultrasonic vibration of the ultrasonic actuator 41 may be started at the time when the movement of the ultrasonic actuator 41 and the anvil 42 to the closing direction is started, at a time in the movement, or at the time when pressing of the sealing part 51 by the ultrasonic actuator 41 and the anvil 42 is started. When the vibration is started while the ultrasonic actuator is pressed to the sealing part 51, the output power of the ultrasonic vibration generator 48 must be large because there is the possibility that an excessive load is added to the ultrasonic vibrating element 43. It is more efficient that the sealing by pressing is made after foreign substances adhered to the sealing part 51 of the self-supporting bag 21 are flipped away by the ultrasonic vibration. Therefore, it is preferable that the vibration of the ultrasonic actuator 41 is started before the horn 45 is pressed to the sealing part 51. By pressing the working end 46 of the horn 45 which is already vibrating to the sealing part 51, the ship-shaped flange 7 of the main part 1 of the outlet stopper and the sealing layer in the self-supporting bag are mechanically vibrated at a high speed of ultrasonic frequency and sealed by the friction heat and the molecular heat. The mechanical vibration of high frequency is transmitted to the main part 1 of the outlet stopper. The ship-shaped flange 7 and the sealing layer of the self-supporting bag at the side which is pressed by the receiving part 49 of the anvil 42 are also mechanically vibrated with high frequency simultaneously, and sealed by the friction heat and the molecular heat. A cycle of the ultrasonic sealing is finished after the sum of the weld time and the hold time. The weld time is a period of time in which the ultrasonic vibration is continuing. The hold time is a period of time in which the ultrasonic vibration is stopped while the components are kept pressed together and the sealed part is solidified by cooling. These times are set by a timer 52 in the ultrasonic vibration generator 48. It is preferred that the hold time is generally set at about a half or less of the weld time. At the end of the hold time, the ultrasonic actuator 41 and the anvil 42 are opened by moving away from each other simultaneously. The self-supporting package having the outlet stopper is taken out by a suitable method such as dropping and the sealing process is finished. An example of the process in which two ultrasonic actuators and two ultrasonic vibration generators are used in combination is described in the following with reference to Figure 15. Basic construction and arrangement comprising an ultrasonic actuator 41, an ultrasonic vibration generators 48 and a self-supporting bag 21 temporarily sealed with an outlet stopper 3 are the same as those shown in Figure 14. The ultrasonic actuator 53 is composed of an ultrasonic vibration element 54, a booster 55, and a horn 56. Structure, material, and function of the ultrasonic actuator 53 are basically the same as those in the ultrasonic actuator 41. The ultrasonic actuator 53 is connected to an ultrasonic vibration generator 58 with a high frequency cable 57. The ultrasonic actuator 53 is placed at the same position as that of the anvil 42 in Figure 14, which is the position on the axis of the ultrasonic actuator 41 and faced to the ultrasonic actuator 41 with the outlet stopper 3 between them. The ultrasonic actuators 41 and 53 are fixed by a suitable method to a mechanism which can move along the axis line perpendicular to the line connecting the ends 29 and 30 of the ship-shaped flange as shown by the arrows in Figure 15. The mechanism is, for example, a reciprocally driving mechanism containing an air cylinder, an oil cylinder, a mechanical cam, or a combination of them. The ultrasonic actuators 41 and 53 wait in the open condition. When the self-supporting bag 21 temporarily sealed with the outlet stopper 3 is supplied and stops at the specified position on the axis line of the ultrasonic actuators 41 and 53, the ultrasonic actuators 41 and 53 move to the direction of closing in a synchronized manner and press the sealing parts 51 at both faces of the self-supporting bag 21 simultaneously. In Figure 15, the ultrasonic actuator 41 moves to the left and the ultrasonic actuator 53 moves to the right. The ultrasonic vibration of the ultrasonic actuators 41 and 53 may be started at the time when the movement of the ultrasonic actuators 41 and 53 to the closing direction is started, at a time in the movement, or at the time when pressing of the sealing part 51 by the ultrasonic actuators 41 and 53 is started. When the vibration is started while the ultrasonic actuator is pressed to the sealing part 51, the output powers of the ultrasonic vibration generators 48 and 58 must be large because there is the possibility that an excessive load is added to the ultrasonic vibrating elements 43 and 54. When the outlet stopper 3 is sealed to the self-supporting bag 21 after the bag is filled with contents, it is more efficient that the sealing by pressing is made after foreign substances adhered to the sealing part 51 of the self-supporting bag 21 are flipped away by the ultrasonic vibration. Therefore, it is preferable that the vibration of the ultrasonic actuators 41 and 53 is started before the horns 45 and 56 are pressed to the sealing part 51. The weld time which is the time of ultrasonic vibration and the hold time which is the cooling time are set by the timer 52 in the ultrasonic vibration generator 48 and the timer 59 in the ultrasonic vibration generator 58. At the end of the hold time, the ultrasonic actuators 41 and 53 are opened by moving away from each other simultaneously. The self-supporting package having the outlet stopper is taken out by a suitable method such as dropping and the sealing process is finished. The more important point of the mode of the process of the present invention described above is that the ultrasonic vibration system (I) composed of the ultrasonic actuator 41 and the ultrasonic vibration generator 48 and the ultrasonic vibration system (II) composed of the ultrasonic actuator 53 and the ultrasonic vibration generator 58 have resonance frequencies different from each other. When the resonance frequencies of the ultrasonic vibration systems (I) and (II) are the same, a problem arises as described in the following: at a moment when the working end 46 of the horn 45 pressed to the sealing part 51 has a movement in the vibration to the left direction in Figure 15 to press the sealing part 51, the working end 60 of the horn 56 pressed to the sealing part 51 has a movement in the vibration to the right direction in Figure 15 to release the pressure to the sealing part 51; at another moment when the working end 60 of the horn 56 pressed to the sealing part 51 has a movement in the vibration to the left direction in Figure 15 to press the sealing part 51, the working end 46 of the horn 45 pressed to the sealing part 51 has a movement in the vibration to the right direction in Figure 15 to release the pressure to the sealing part 51; these phenomena are repeated and the sealing part 51 just moves to the right or to the left in accordance with the movements of the working ends 46 and 60; the friction heat and the molecular heat which are the source of the heating by the ultrasonic vibration are not generated; therefore, sealing cannot be achieved at all. This problem can be avoided when the resonance frequencies of the ultrasonic vibration systems (I) and (II) are different from each other. The effect exhibited by the different resonance frequencies is very remarkable. For example, when the resonance frequency of the ultrasonic vibration system (I) is 20 kHz, it is desirable that the resonance frequency of the ultrasonic vibration system (II) is different from the value described above by 1 kHz or more, preferably 5 kHz or more. An example of the process in which two ultrasonic actuators and one ultrasonic vibration generator of the switching type are used in combination is described in the following with reference to Figure 16. Arrangement of ultrasonic actuators 41 and 61 and the self-supporting bag 21 temporarily sealed with the outlet stopper 3 are the same as those in Figure 15. The ultrasonic actuators 61 having the same material, construction, and resonance frequency as those of the ultrasonic actuator 41 is used. The ultrasonic vibration element 43 of the ultrasonic actuator 41 and the ultrasonic vibration element 62 of the ultrasonic actuator 61 are connected to an ultrasonic vibration generator of the switching type 64 of the present invention with a high frequency cables 47 and 63, respectively. The ultrasonic vibration generator of the switching type 64 of the present invention has one function of generating ultrasonic vibration and the function of switching vibration elements. The ultrasonic vibration generator of the switching type 64 has the function by which two ultrasonic vibration generators required for two ultrasonic actuators in Figure 15 can be replaced with a single ultrasonic vibration generator. In the switching function of vibration generators, a device for switching contact points, such as a relay, is inserted between the single ultrasonic vibration generator and two high frequency cables 47 and 63 which are connected to the ultrasonic vibrating elements 43 and 62, respectively, and the contact points are switched in such a manner that the combination of the weld time and the hold time is consecutively switched from one of the ultrasonic vibration elements 43 and 62 in the ultrasonic actuators 41 and 61, respectively, to the other. In the present example, the switching is made by the timers 65 and 66 contained in the ultrasonic vibration generator of the switching type 64. The timers 65 and 66 may be units separated from the ultrasonic vibration generator 64 of the switching type and connected to it with cables. Working of the two ultrasonic actuators 41 and 61 and a single ultrasonic vibration generator of the switching type 64 is specifically described in detail with reference to Figure 16. The ultrasonic actuators 41 and 61 wait in the open condition. When the self-supporting bag 21 temporarily sealed with the outlet stopper 3 is supplied and stops at the specified position on the axis line of the ultrasonic actuators 41 and 62, the ultrasonic actuators 41 and 61 move to the direction of closing in a synchronized manner and press the sealing parts 51 at both faces of the self-supporting bag 21 simultaneously. In Figure 16, the ultrasonic actuator 41 moves to the left and the ultrasonic actuator 61 moves to the right. The ultrasonic actuator 41 alone is vibrated first and the sealing is made. Weld time and hold time are controlled by the timer 65. Either at the end of the weld time or at the end of the hold time of the ultrasonic actuator 41, the ultrasonic vibration generator is switched to the ultrasonic actuator 61 by the device for switching contact points and the ultrasonic actuator 61 alone is vibrated with the ultrasonic frequency to make the sealing. Weld time and hold time are controlled by the timer 66. At the end of the hold time controlled by the timer 66, the ultrasonic actuators 41 and 61 are opened by moving away from each other simultaneously. The self-supporting package having the outlet stopper is taken out by a suitable method such as dropping and the sealing process is finished. In the operation described above, the ultrasonic vibration of the ultrasonic actuator 41 may be started at the time when the movement of the ultrasonic actuator 41 to the closing direction is started, at a time in the movement, or at the time when pressing of the sealing part 51 by the ultrasonic actuator 41 is started. It is preferred that the vibration of the ultrasonic actuator 41 is started before the ultrasonic actuator 41 is pressed to the sealing part 51 because the ultrasonic vibration can be started more easily and foreign substances adhered to the sealing part are flipped away. When it is difficult to start the vibration of the ultrasonic actuator 61 while the ultrasonic actuator 61 is pressed to the sealing part 51, it is preferred that the ultrasonic actuator 61 is pulled back slightly to the opening direction and the ultrasonic actuator 61 is started before it is pressed to the sealing part 51 again, because power required for the vibration of the ultrasonic vibration generator of the switching type 64 can be held low. It is also preferred that the switching from the ultrasonic actuator 41 to the ultrasonic actuator 61 is made at the end of the weld time of the ultrasonic actuator 41 because time of operation can be decreased. In the examples with reference to Figures 14 to 16, control of the weld time which is the time of ultrasonic vibration has been described by the method of control using a timer. Other methods of control of the present invention, such as the method of control by the moving distance of the horn and the method of control by the energy in which electricity provided to an ultrasonic vibration element is measured for control, are described with reference to examples and Figure 14 as one of the related figures in the following. The method of control by the moving distance of the horn is described with reference to Figure 14. In this method, the time of ultrasonic vibration is controlled by one of the following three moving distances. The first moving distances is the distance from the position where the ultrasonic actuator 41 is in the open condition at the right end of the figure to the position where the sealing is completed. The second moving distance is the distance from the position where a trigger device is operated to the position where the ultrasonic sealing is completed. The trigger device is located at a position between the position where the movement of the ultrasonic actuator 41 to the closing direction is started and the position where the ultrasonic actuator 41 is pressed to the sealing part 51. The trigger device triggers the start of the ultrasonic vibration and is a limit switch or the like. The third moving distance is the distance from the position where the pressure of the ultrasonic actuator 41 on the sealing part 51 reaches a trigger pressure which has been set to a specified value in advance and the position where the ultrasonic sealing is completed. The pressure on the sealing part is measured by a pressure measuring device such as a load cell connected to the ultrasonic actuator 41. The three moving distances can be measure by using a device for measuring the moving distance, such as a displacement sensor like a LED displacement sensor, a laser displacement meter, a ultrasonic displacement sensor, a linear access sensor, and the like; and a device for length measurement like a laser micrometer, a photoelectric sensor, a video sensor, a linear encorder, and the like. Among these devices, the linear encoder is preferable because of a simple structure and superior accuracy. Among the three methods using the three moving distances, the method using the trigger pressure can achieve the best accuracy for realizing better sealing stability. The method using the trigger pressure is described in more detail in the following. When the ultrasonic actuator reaches the position where the pressure reaches the trigger pressure which has been set to a specified value in advance, a trigger signal triggers vibration of the ultrasonic vibration generator 48. The ultrasonic actuator 41 continues moving forward to the pressing direction while the ultrasonic actuator 41 is vibrated by the ultrasonic vibration and the self-supporting bag 21 and the sealing part 51 of the outlet stopper 3 are sealed with the ultrasonic vibration. At the time when the moving distance measured from the position where the ultrasonic vibration is triggered reaches to a moving distance set to a specified value in advance, the ultrasonic vibration is stopped to finish the process of the weld time and, at the same time, the hold time which is the process for cooling is started. Time of the hold time can be set by a conventional timer according to the conventional method. An example of the method of control by the energy of the present invention is described in the following with reference to Figure 14. The energy in the present invention is the electric energy required for the ultrasonic vibration generator 48 to generate vibration of the ultrasonic actuator 41 to seal the self-supporting bag 21 and the sealing part 51 of the outlet stopper 3 together, which is integrated over the period of the weld time. The position where the ultrasonic vibration of the ultrasonic actuator 41 is started is detected by a position detecting sensor such as a photoelectric sensor, an access sensor, a limit switch, and the like, similarly to the method of control by the time. The ultrasonic vibration generator 48 is vibrated by the detected signal used as the trigger and the ultrasonic sealing is started. When the electric energy of the ultrasonic vibration generator 48 accumulated in the ultrasonic sealing period which is started by the trigger signal reaches a specific electric energy which is set in advance, process of the ultrasonic vibration which means the weld time is finished and, at the same time, the cooling process which means the hold time is started. The hold time can be set by using a conventional timer according to a conventional method. For applying the method of control by the moving distance or the method of control by the energy described above with reference to Figure 14 to the example shown in Figure 15, the control method is applied simultaneously to both of the ultrasonic vibration system (I) composed of the ultrasonic actuator 41 and the ultrasonic vibration generator 48 and the ultrasonic vibration system (II) composed of the ultrasonic actuator 53 and the ultrasonic vibration generator 58. For applying the method of control by the moving distance or the method of control by the energy described above with reference to Figure 14 to the example shown in Figure 16, the method is applied consecutively to one or the other of the ultrasonic actuators 41 and 61 because the ultrasonic actuators 41 and 61 are vibrated consecutively by the ultrasonic vibration generator of the switching type 64. Particularly, the function can be effectively exhibited by adopting the method in which the ultrasonic actuator 61 is temporarily pulled back. As the method of control of the ultrasonic vibration, a combination of the method of control by the time, the method of control by the moving distance, and the method of control by the energy may be suitably adopted. Shapes of the horn and the anvil are described in the following with reference to Figures 17 and 18. Figure 17 shows an example of the horn 45 of the present invention. (D) shows a front view and (E) shows a side view. The horn 45 has such a structure that, for example, a screw part 68 for connecting the booster 44 or the ultrasonic vibration element 43 shown in Figure 14 is formed at the upper end 67 and the amplitude of the ultrasonic vibration can be increased in proportion to the ratio of sectional areas of the upper end 67 and the lower end 69. Length of the working end 46 of the horn 45 is larger than the length of the opening part 4 shown in Figure 6. The shape of the working end 46 is the important technical element deciding quality of the ultrasonic sealing. Width of the working end 46 shown in Figure 17 (E) is the same as or more than the height of the sealing part 6 of the outlet stopper in Figure 10. The working end 46 of the horn has a concave part 70 having the radius of curvature R 2 as shown in Figure 17 (D). The working end 46 of the horn also has convex parts 71 which are pressed to the end parts 29 and 30 of the ship-shaped flange of the outlet stopper shown in Figure 11 and has the radius of curvature r 2 as shown in Figure 17 (D). The concave part 70 and the convex part 71 are connected to each other with the tangent common to both parts. The concave part 70 of the working end has a radius of curvature R 2 which is obtained by adding 0.6 to 1.4 times, preferably 0.8 to 1.2 times, the thickness of the self-supporting bag to the radius of curvature R 1 of the corresponding convex part 33 of the sealing base 32 in the ship-shaped flange shown in Figure 11. When an amount less than 0.6 times the thickness of the self-supporting bag is added, sealing around the top of the upward concave part 33 becomes insufficient. When an amount more than 1.4 times the thickness of the self-supporting bag is added, sealing at the end parts 29 and 30 and side parts 31 in Figure 8 is insufficient. Similarly, the convex parts 71 of the working end have a radius of curvature r 2 which is obtained by subtracting 0.6 to 1.4 times, preferably 0.8 to 1.2 times, the thickness of the self-supporting bag from the radius of curvature r 1 of the corresponding concave parts 34 of the sealing base 32 in the ship-shaped flange shown in Figure 11. When an amount less than 0.6 times the thickness of the self-supporting bag is subtracted, sealing at the end parts 29 and 30 and side parts 31 in Figure 8 is insufficient. When an amount more than 1.4 times the thickness of the self-supporting bag is subtracted, sealing around the top of the convex part 33 becomes insufficient. Figure 18 shows an example of the anvil 42. (F) shows the front view and (G) shows the side view. The anvil is composed of the main part 50 and the receiving part 49. Shape of the receiving part is the important technical factor deciding the quality of the ultrasonic sealing. The receiving part of the anvil has the same shape as that of the working end of the horn 45 shown in Figure 17. Width of the receiving part in Figure 18 (G) is the same as the width of the working end 46 in Figure 17 (E). Radius of curvature of the concave part 72 of the receiving part 49 of the anvil is the same as the radius of curvature of the concave part 70 of the horn R 2 . Radius of curvature of the convex parts 73 of the anvil is the same as the radius of curvature of the convex parts 71 of the horn r 2 . In the above, the examples of the present invention have been described mainly with reference to Figures 14, 15, and 16. In the description, the ultrasonic actuators and anvils are shown to have movements to the horizontal directions. However, the direction of the movement is not particularly limited but may be vertical directions, or inclined directions. For example, the present invention includes a method in which the self-supporting bag is placed vertically, the upper part of the bag is forced to bend 90 degrees, and the ultrasonic actuators are moved approximately vertically for the ultrasonic sealing. Combination of the ultrasonic sealing and the heat sealing of the present invention is described in the following. When the outlet stopper 3 is sealed to the self-supporting bag 21 by the ultrasonic method described in Figures 14, 15, and 16, and then the heat sealing shown in Figure 7 is applied, more reliable sealing can be achieved. Sealing stability can be significantly increased by the combination of the heat sealing with the ultrasonic sealing, in which the heat sealing is made after foreign substances are flipped away by the ultrasonic sealing. The heat sealing may be conducted once or repeated a plurality of times. The cooling process may be added after the heat sealing process. It is possible that the sealed part is cooled by a cooling apparatus 74 such as a cooling seal or an air blowing apparatus in the last process of the production. The self-supporting package having the outlet stopper filled with contents is discharged from the table. In the present invention, the operations of each process can be performed by transferring the product between the processes intermittently with one-pitch movement. Mechanisms of each process can be operated in the manner synchronized with the continuous movement of the self-supporting bag, if necessary. A mode of the present invention which includes continuous production of the self-supporting bag from a long sheet of the material film of the package is described in the following. In Figure 19, the material film 76 sent out from a roll 75 is provide with holes by the process for punching holes in the bottom part 77, folded after passing the process for transferring the sheet of material film 78, and, at the same time, the material constituting the bottom part is inserted in the folded shape in the process for folding and inserting the bottom part 79. A process for forming ribs on the material film (not shown in the figure) is occasionally added to a part of the process of transferring the sheet of material film 78. Then, the film is heat sealed in the process for heat sealing the bottom part 80 and the process for heat sealing the side parts 81, punched to the shape of the self-supporting bag in the punching process 82, supplied to the table similar to that in Figure 9, and, after the processes for holding, opening, filling, supplying of the outlet stopper, and sealing, the self-supporting package having an outlet stopper is discharged. In another mode of the present invention, the processes for punching of the self-supporting bag, supplying, holding, opening, filling, supplying an outlet stopper, sealing, and discharge can be arranged on a straight line as shown in Figure 20. The apparatus of the present invention is an apparatus for producing the self-supporting package having the outlet stopper which comprises mechanisms having the corresponding functions described in the processes of the process of the present invention in the order of the corresponding processes. By using a self-supporting bag made of a multi-layer film having the inner layer of polypropylene film and the outer layer of stretched 66 nylon film, and having the height of 26 cm, the width at the folded part 19 of 14 cm, the width of the opening part 4 at the top of the bag of 8 cm, and distance between the folded part 19 and the bottom end part of 4 cm, the present invention was conducted using the apparatus shown in Figure 9. The self-supporting bag held in the magazine 20 was supplied to the specified position of the table by using the apparatus for supplying the bag and held approximately vertically by the gripper 22. Both sides of the bag were slightly pulled apart with the vacuum sucking plates 23, and air was blown into the slip thus formed from the air blowing nozzle 24. After the bag was thus opened, the bag was filled with 800 ml of salad oil from the apparatus for quantitative supply 25. Then, the outlet stopper 3 having an outlet with stopper on the ship-shaped flange made of polypropylene was supplied to the opening part 4. The ship-shaped flange of the main part 1 of the outlet stopper and the inner faces of the opening part were sealed together by the ultrasonic sealing. Salad oil adhered to the inner face of the opening part was flipped away by the ultrasonic vibration and a strong sealing was achieved. To summarize the advantages of the present invention, a self-supporting package having an outlet stopper filled with contents can be produced with high productivity. Shape of the self-supporting package can be freely selected. Sealing time is shorter than that of conventional heat sealing processes. The sealing can be surely achieved even when foreign substances are present on the face of sealing. The self-supporting package produced has excellent sealing stability and simple structure, provided with an outlet stopper at the top of the package, and is easy for handling.

Claims: Process for producing self-supporting packages (9; 21) having an outlet stopper (1, 3), the process comprises the steps of (a) supplying a self-supporting bag (9; 21) having an opening part (4) for filling contents at its top and holding the bag in vertical position with the opening part upside, (b) opening the opening part of the bag, (c) filling the bag through the opened opening part with contents, (d) supplying an outlet stopper (1, 3) including an outlet (2) with a stopper (3) on a ship-shaped flange (7) having two side sealing faces (6), to the opening part, with at least one raised sealing rib (8) on both side sealing faces of the ship-shaped flange, and (e) sealing said side sealing faces (6) of the ship-shaped flange of the outlet stopper to inner side sealing faces (15) of the opening part of the bag, wherein the steps are conducted in the order of these steps (a), (b), (c), (d) and (e) consecutively, characterized in that the sealing step (e) comprises the steps of placing an ultrasonic actuator (41) producing mechanical vibration of an ultrasonic frequency at one side of the outlet stopper (1, 3) on an axis line perpendicular to the side sealing faces (6) of the outlet stopper, placing another ultrasonic actuator (53; 61) or an anvil (42, 50) at a position on the opposite side of the outlet stopper and on the axis line perpendicular to the side sealing faces (6) of the outlet stopper such that the ultrasonic actuator on one side of the outlet stopper faces the other ultrasonic actuator or the anvil at the opposite side of the outlet stopper, and driving the ultrasonic actuator at one side of the outlet stopper and the other ultrasonic actuator or the anvil at the opposite side to open or close along the axis line perpendicular to the side sealing faces of the outlet stopper in synchronized manner, to thereby ultrasonically seal the at least one raised sealing rib (8) on both sides of the side sealing faces (6) of the ship-shaped flange (7) of the outlet stopper (1, 3) to the inner side sealing faces (15) of the opening part of the self-supporting bag, wherein said sealing steps are conducted in the order of these steps (a), (b), (c), (d) and (e), consecutively. Process according to Claim 1, wherein each sealing rib (8) has a width of 0.2 to 0.8 mm and a height of 0.05 to 0.4 mm and is formed on both sides of the ship-shaped flange, (7) of the outlet stopper (1, 3), a plurality of reinforcing ribs are formed in the space between the two sides of the ship-shaped flange, parts of increased thickness are formed at joint parts of the reinforcing ribs and the ship-shaped flange, and two end parts (29; 30) of the ship-shaped flange having a shape tapered toward the tip are formed. Process according to Claim 1 or 2, wherein the working end of a horn (45; 56) in the ultrasonic actuator (41; 53) and/or the receiving part (49) in the anvil (42; 50) has such a shape that the concave part of the working end (46) and/or the receiving part (49) has a radius of curvature which is obtained by adding 0.6 to 1.4 times the thickness of the self-supporting bag (9; 21) to the radius of curvature of the corresponding convex part of the sealing base in the ship-shaped flange (7), and the convex part of the working end (46) and/or the receiving part (49) has a radius of curvature r 2 which is obtained by subtracting 0.6 to 1.4 times the thickness of the self-supporting bag (9; 21) from the radius of curvature of the corresponding concave parts of the sealing base (32) in the ship-shaped flange (7). Process according to any of Claims 1 to 3, wherein for temporary sealing both sealing faces (6; 15) are spot sealed by lightly pressing the outside of the opening part of the self-supporting bag (9; 21) toward the ship-shaped flange (7) of the outlet stopper (1, 3) from one or two directions by using a heated rod of a controlled temperature, by ultrasonic vibration, or by high frequency wave, after the step (d) and before the step (e). Process according to any of Claims 1 to 4, wherein after ultrasonic sealing the self-supporting bag (9; 21) to the ship-shaped flange (7) in the step (e) a heat sealing is applied to achieve a more reliable sealing. Process according to any of Claims 1 to 5, wherein the resonance frequencies of both ultrasonic actuators (41; 53) are different from one another. Process according to any of Claims 1 to 5, wherein both ultrasonic actuators (41; 53) are driven by one ultrasonic vibration generator (64) having a switching function in such a manner that both actuators are consecutively driven by means of the switching function of the ultrasonic vibration generator. Process according to any of Claims 1 to 7, wherein the self-supporting bag (9; 21) is produced continuously from a long sheet of film material (76) before the step (a). Process according to any of Claims 1 to 8, wherein the whole part including the upper part of the self-supporting bag (9; 21) has the self-supporting property which is provided by side seal lines forming the trunk part of the bag, a constriction part formed by the side seal lines forming the trunk part of the bag, a constriction part formed by the side seal lines at the middle part of the height of the bag when the bag is in the self-supporting condition, and a pair of linear grooves and a pair of linear ribs each having an approximate shape of arc convexed toward the inner side and formed in the trunk part each at a position separated from the side line by a distance of 10 to 35 % of the width of the bag toward the inner side. Apparatus for producing self-supporting packages having an outlet stopper, the apparatus comprises (a) a mechanism for supplying a self supporting bag (9; 21) which has an opening part for filling contents at the top of the bag, and holding the bag in vertical position with the opening part upside, (b) a mechanism for opening the opening part of the bag (9; 21), (c) a mechanism for filling the bag (9; 21) through the opened opening part with contents, (d) a mechanism for supplying an outlet stopper (1, 3) including an outlet (2) with a stopper (3) on a ship-shaped flange (7) having two side sealing faces (6) to the opening part, with at least one raised sealing rib (8) on both side sealing faces of the ship-shaped flange, and (e) a mechanism for sealing side sealing faces (6) of the ship-shaped flange (7) of the outlet stopper (1, 3) to inner side sealing faces (15) of the opening part of the bag (9; 21), wherein the mechanisms are arranged in the order of the mechanisms (a), (b), (c), (d) and (e), consecutively, in the apparatus, characterized in that the sealing mechanism includes an ultrasonic actuator (41) producing mechanical vibration of ultrasonic frequency arranged at one side of the outlet stopper (1, 3) and on an axis line perpendicular to the side sealing faces of the outlet stopper, another ultrasonic actuator (53; 61) or an anvil (42, 50) arranged on the opposite side of the outlet stopper and on the axis line perpendicular to the side sealing faces of the outlet stopper such that the ultrasonic actuator on one side of the outlet stopper faces the other ultrasonic actuator or the anvil at the opposite side of the outlet stopper, and a driver for driving the ultrasonic actuator at one side of the outlet stopper and the other ultrasonic actuator or the anvil at the opposite side to open or close along the axis line perpendicular to the side sealing faces of the outlet stopper in a synchronized manner, to thereby ultrasonically seal said at least one raised sealing rib (8) on both sides of the side sealing faces (6) of the ship-shaped flange (7) of the outlet stopper (1, 3) to the inner side sealing faces (15) of the opening part of the self-supporting bag, Apparatus according to Claim 10, wherein two end parts (29, 30) of the ship-shaped flange (7) have a shape tapered toward the tip, the sealing base has a convex part of a radius of curvature R 1 , the end parts have a concave part of a radius of curvature r 1 , the convex part and the concave part being connected to each other with the tangent common to both, the working end of the horn (45) and the receiving part of the anvil (42, 50) have a horn concave part of a radius of curvature R 2 and horn convex parts with a radius of curvature r 2 , the horn concave part and the horn convex part being connected to each other with the tangent common to the both, and R 1 , R 2 , r 1 and r 2 have the follow-ing relations with the thickness t of the self-supporting bag: R 2 = R 1 + (0.6 ∼ 1.4) t r 2 = r 1 - (0.6 ∼ 1.4) t. Apparatus according to Claims 10 or 11, wherein a mechanism (10 to 14) for heat sealing the bags (9;21) obtained by the ultrasonic actuators (41, 53) of the sealing mechanism (e) is provided after the ultrasonic sealing mechanism. Apparatus according to one of Claims 10 to 12, wherein the resonance frequencies of both ultrasonic actuators (41; 53) are different from one another. Apparatus according to one of Claims 10 to 12, wherein both ultrasonic actuators (41; 53) are driven by a single ultrasonic vibration generator (64) having a switching function in such a manner that the actuators at both sides are consecutively driven by means of the switching function of the single ultrasonic vibration generator.

Inventors: KATAYAMA MITUHARU, NOGUCHI YASUO, TAKAGAKI TADAO, KATAYAMA, MITUHARU                               ., NOGUCHI, YASUO, TAKAGAKI, TADAO, Katayama, Mituharu, c/o Sumitomo Bakelite Co.,Ltd., Noguchi, Yasuo, c/o Sumitomo Bakelite Co.,Ltd., Takagaki, Tadao, c/o Sumitomo Bakelite Co.,Ltd.
Applicants: SUMITOMO BAKELITE CO, SUMITOMO BAKELITE COMPANY LIMITED
Application year: 1994
Main classification: B65B3
IPC codes: B65B3, B65D75, B65B51, B29C65