DETERGENT COMPOSITION

Abstract: Non-aqueous liquid cleaning product comprising a non-aqueous liquid phase, from 1 to 90 % by weight of solid particles and dispersed droplets comprising a silicone polymer and hydrophobic particles, said droplets having a viscosity of from 5,000 to 60,000 mPa.s 21 s<-1> at 25 DEG C.

Description: DETERGENT COMPOSITION TECHNICAL FIELD The present invention relates to substantially non-aqueous liquid cleaning products, especially detergent compositions and to a method of preparing a non-aqueous liquid. Non-aqueous liquids are those containing little or no water, usually less than 5% by weight, preferably less than 3% by weight, more preferably less than 1% by weight of the composition. PRIOR ART & BACKGROUND Non-aqueous liquid detergent compositions are known in the art and have been described in quite a number of patent publications, e.g. in US-A-4,316,812, US-A-4,874,537 and EP- A-0,484,095. Non-aqueous liquids provide a way of concentrating liquid detergents without giving in on washing performance. Non-aqueous liquid detergent compositions normally comprise a non-aqueous liquid phase having incorporated therein as dispersion, solution or combination thereof, the usual detergent components and adjuncts depending on the purpose of use, primarily surfactants and builders. The liquid phase often comprises a nonionic surfactant as major component, which apart from acting as carrier liquid for the detergent components, usually and preferably also has detergent-active properties, thereby acting wholly or in part as the surfactant ingredient. The liquid phase may comprise a nonionic surfactant and/or surfactant mixtures, such as mixtures of C13-C15 alcohols with an average of 3 ethoxy groups and C13-C15 alcohols with an average of 7 ethoxy groups and liquid phases as described in GB-A-1,462,134, WO 91/12313, WO 91/14765 and EP-A-0,510,762. # WO 93/24603, WO 94/01525 and WO 94/01524 disclose non- aqueous liquids with DB100 a low viscosity silicone polymer material having a viscosity of 3,000 mPa.s at 21s -1 at 25°C. EP-A-515,418 and EP-A-515,435 disclose the use of silicone material in non-aqueous liquids. Non-aqueous liquids of the prior art comprising silicone polymer material may suffer from sedimentation, clear layer formation or poor dispersibility. Surprisingly we have found that one or more of these disadvantages can be overcome. SUMMARY OF THE INVENTION The invention provides a non-aqueous liquid cleaning composition comprising a non-aqueous liquid phase, from 1 to 90% by weight of solid particles and dispersed droplets comprising silicone polymer and hydrophobic particles, said droplets having a high viscosity. Preferably the viscosity of the droplets is of from 5,000 to 60,000 mPa.s at 21s "1 at 25°C. DETAILED DESCRIPTION OF THE INVENTION Although not wishing to be bound by any theory, it is believed that gluing together of solid particles dispersed in a non-aqueous environment is reduced by using dispersed droplets according to the invention. Dispersed droplets The dispersed droplets according to the invention comprise silicone polymer and hydrophobic particles and have a viscosity of at least 5,000 mPa.s at 21s "1 at 25°C, preferably at least 10,000, more preferably at least 15,000, most preferably at least 20,000. Preferably the viscosity of the dispersed droplets is at most 60,000 mPa.s at 21s "1 at 25°C, preferably at most 50,000 mPa.s at 21s "1 at 25°C, more preferably at most 40,000 mPa.s, most preferably at most 35,000 mPa.s. The droplets may be of a viscosity of more than 3,000 mPa.s at 21s "1 at 25°C. Preferably the dispersed droplets also comprise alkoxypoly-di ethyl stabilising agents, e.g. DC-198 (ex Dow Corning) , which is believed to be able to further improve the properties of the non-aqueous liquids as to sedimentation, clear layer formation and/or poor dispersibility. The weight ratio of the silicone polymer to the hydrophobic particles is from 70:30 to 99:1, preferably from 80:20 to 98:2, more preferably from 90:10 to 95:5. The dispersed droplets are present in amounts of from 0.1 to 5.0% by weight of the composition, preferably 0.3 to 3.0% by weight, preferably from 0.5 to 2.0% by weight. Preferably the particle size of the droplets is from 0.5-50 μm (in terms of D(1.0), being the number mean diameter as described by M. Alderliesten, Anal. Proc. Vol. 21, May, 1984, 167-172, as can be microscopically determined using a fluorescence imagin technique; images can be digitised so that droplet areas and diameters can be measured and counted using image analysis) , preferably from 1-3Oμm. Surprisingly, we have found that high viscosity droplets according to the invention can be prepared by blending a conventional low viscosity silocone polymer composition with a high viscosity fluid. Optionally, the solid content of the composition, e.g. hydrophobic particles, can be adjusted. Silicone polymer Preferably, the silicone polymer comprises an organo- siloxane polymer, more preferably a polydimethylsiloxane. The polymer may also consist of a mixture of polymers, e.g. a mixture of a polymer that has a high viscosity (due to branching or to a high molecular weight) per se, e.g. more than 5.000 mPa.s at 21s-l at 25°C, and a polymer that has a low viscosity per se, e.g. say lower than 5.000 mPa.s at 21 s-l at 25°C. An example of a high viscosity polymer is polydimethylsilixone of a weight average molecular weight of 137,000 that has a viscosity of 60,000 mPa.s at 21 s-1 at 25°C. DB100 (ex Dow Corning) comprises a polydimethyl- siloxane with a weight average molecular weight of 37,000. These two polymers could for example be mixed in a 50/50 w/w ratio. Hydrophobic particles Preferably, the hydrophobic particles are selected from hydrophobic silica, hydrophobed metal oxide (e.g. aluminium, titanium and magnesium) , α-w dialkylamide alkane, polyvalent metal salt of an alkyl phosphoric acid and polyvalent metal salt of an alkyl carboxylic acid. The most preferred particle to be used in the dispersed droplets is hydrophobic silica Preferably the particle size of the hydrophobic particles is smaller than lOμ , more preferably smaller than lμm. Non-aqueous liquid phase The non-aqueous liquid phase of the compositions according to the present invention may comprise surfactant and other liquid materials, such as liquid bleach precursors solvents and deflocculant material. The non-aqueous liquid phase will generally be present in amounts of at least 10%, preferably 20%, more preferably 30% most prefereably 35% by weight of the non-aqueous liquid composition and generally at most 90%, preferably 70%, more preferably 60% and most preferably 50% by weight of the composition. Generally, non-aqueous liquid detergent products have a free water content of less than 5% by weight, preferably less than 2% by weight, more preferably substantially nil. Surfactants As explained hereinbefore the liquid phase of non- aqueous liquid detergent compositions often and preferably comprises a liquid nonionic surfactant as major component. Nonionic detergent surfactants are well-known in the art. They normally consist of a water-solubilizing polyalkoxylene or a mono- or di-alkanolamide group in chemical combination with an organic hydrophobic group derived, for example, from alkylphenols in which the alkyl group contains from about 6 to about 12 carbon atoms, dialkylphenols in which each alkyl group contains from 6 to 12 carbon atoms, primary, secondary or tertiary aliphatic alcohols (or alkyl-capped derivatives thereof) , preferably having from 8 to 20 carbon atoms, *monocarboxylic acids having from 10 to about 24 carbon atoms in the alkyl group and polyoxypropylenes. Also common are fatty acid mono- and dialkanolamides in which the alkyl group of the fatty acid radical contains from 10 to about 20 carbon atoms and the alkyloyl group having from 1 to 3 carbon atoms. In any of the mono- and di- alkanolamide derivatives, optionally, there may be a polyoxyalkylene moiety joining the latter groups and the hydrophobic part of the molecule. In all polyalkoxylene containing surfactants, the polyalkoxylene moiety preferably consists of from 2 to 20 groups of ethylene oxide or of ethylene oxide and propylene oxide groups. Amongst the latter class, particularly preferred are those described in EP-A-225,654, especially for use as all or part of the liquid phase. Also preferred are those ethoxylated nonionics which are the condensation products of fatty alcohols with from 9 to 15 carbon atoms condensed with from 3 to 11 moles of ethylene oxide. Examples of these are the condensation products of C 11 _ 13 alcohols with (say) 3 or 7 moles of ethylene oxide. These may be used as the sole nonionic surfactants or in combination with those of the described in the last-mentioned European specification, especially as all or part of the liquid phase. Another class of suitable nonionics comprise the alkyl polysaccharides (polyglycosides/oligosaccharides) such as described in any of specifications US 3,640,998; US 3,346,558; US 4,223,129; EP-A-92,355; EP-A-99,183; EP 70,074, '75, '76, '77; EP 75,994, '95, '96. Mixtures of different nonionic detergent surfactants may also be used. Mixtures of nonionic detergent surfactants with other detergent surfactants such as anionic, cationic or ampholytic detergent surfactants and soaps may also be used. Preferably the level of nonionic surfactants is from 10-90% by weight of the composition, more preferably from 20-70%, most preferably from 35 to 50%. While nonionic surfactants are quite effective at oily and greasy soil removal (e.g. sebum) , particulate soils, such as clay soils and the like, may be more effectively removed by anionic surfactants. Thus within the ambit of the present invention, a very wide variation in surfactant types and levels is possible. The selection of surfactant types and their proportions will be fully within the capability of those skilled in the art. Useful composition within the invention normally comprise blends of different surfactant types. Typical blends include those where the primary surfactants comprise a nonionic and/or non-alkoxylated anionic and/or alkoxylated anionic surfactant. Cationic, zwitterionic and amphoteric surfactants may also be present usually in minor amounts as desirable. These and other surfactants are described in "Surface Active Agents" Vol. I, by Schwartz & Perry, Interscience 1949; "Surface Active Agents" Vol. II, by Schwartz, Perry & Berch, Interscience 1958; the current editions of "McCutcheon's Emulsifiers & Detergents" published by the McCutcheon Manufacturing Confectioners Company; in "Tensid-Taschenbuch", H. Stache, 2nd Edition, Carl Hanser Verlag, Munchen & Wien, 1981; and in the various patent literature describing various types of liquid detergent compositions, which for the purpose of the invention need no further detailing. Other liquid materials Examples of other liquid materials which may be present in the liquid phase are liquid bleach precursors such as for example glyceroltriacetate, solvent materials for example ethanol and dodecanol and deflocculant material, as described in EP-A-266199 (Unilever) , e.g. deflocculants selected from Bronsted acids and Lewis acids. The level of liquid bleach precursors is preferably 0- 20% by weight, more preferably 1-25%, most preferably 2-10%. The level of solvents other than nonionic surfactants is preferably from 0-20%, most preferably 0-15%, more preferably 0-10% by weight. Deflocculant material may be present, preferably at levels of from 0-15% by weight, in many cases the level is at least 0.01%, usually 0.1% or more preferred at least 1% by weight, and may be as high as 15% by weight. For most practical purposes, the amount ranges from 2-12%, preferably from 4-10% by weight, based on the final composition. Solid particles The compositions may comprise a solid dispersed phase. In that case, the solid phase may be present in amounts as low as 1% by weight, however at least 10% is preferred and more preferably 20%, most preferably 30% by weight of the composition and preferably at most 90%, more preferably 80% and most preferably 70% and particularly preferred 60% by weight of the composition. The solid phase may comprise one or more ingredients selected from bleach materials, solid bleach activators, builders, abrasives, fabric softening material, enzymes and minor ingredients such as fluorescers, which particles size may not necessarily be the same as that of the biopolymer material. Usually the particle size of the solid phase defined in terms of D(3,2) will be less than lOOμm, preferably not more than 30μm, more preferably up to lOμm. Usually the D(3,2) of the solid phase is more than O.lμm, preferably at least lμm and more preferably at least 2.5μm. For the purpose of the present invention references to the D(3,2) average particle diameter refer to the D(3,2) particle size, which is the average surface weighted, volume/weight mean diameter calculated as described by M. Alderliesten, Anal. Proc. Vol. 21, May, 1984, 167-172. The particle size can for example be determined by using a Malvern Mastersizer or a Coulter LS 130, as appropriate. Bleaches Bleaches include the halogen, particularly chlorine bleaches such as are provided in the form of alkalimetal hypohalites, e.g. hypochlorites. In the application of fabrics washing, the oxygen bleaches are preferred, for example in the form of an inorganic persalt, preferably with a bleach precursor or as a peroxy acid compound. In the case of the inorganic persalt bleaches, the bleach precursor or activator makes the bleaching more effective at lower temperatures, i.e. in the range from ambient temperature to about 60°C, so that such bleach systems are commonly known as low-temperature bleach systems and are well-known in the art. The inorganic persalt such as sodium perborate, both the monohydrate and the tetrahydrate, acts to release active oxygen in solution, and the activator is usually an organic compound having one or more reactive acyl residues, which cause the formation of peroxy acids, the latter providing for a more effective bleaching action at lower temperatures than the peroxybleach compound alone. The ratio by weight of the peroxybleach compound to the activator is from about 20:1 to about 1:1, preferably from about 10:1 to about 1.5:1. The preferred level of the peroxybleach compound in the composition is from 0-30% by weight, more preferably 2-20%, most preferably 4-15%, while the preferred level of the activator is from 0-20% by weight, more preferably 1-10%, most preferably 2-8%. Typical examples of the suitable peroxybleach compounds are alkalimetal perborates, both tetrahydrates and monohydrates, alkali metal percarbonates, persilicates and perphosphates, of which sodium perborate and sodium percarbonate are preferred. A preferred bleach activator is TAED. A further preferred class of bleach activators is that of hydrophobic peroxy acid bleach precursors, such as sodium nonanoyloxy benzene sulphonate and sodium -3,5,5- trimethyl hexanoyloxy benzene sulphonate. These activators are deemed to cause less (local) dye damage. In certain cases and for particular reasons it may be desirable to also include a bleach catalyst, such as a transition metal compound or complex and the sulphonimines as described in US Patents 5,041,232 and 5,047,163, which may be used instead of or together with said bleach activators. A specifically preferred bleach catalyst for use herein is a manganese complex of formula [Mn IV 2 (μ-O) 3 (Me- MeTACN) 2 ] (PF 6 ) 2 as described in EP-A-0,458,397 and EP-A- 0,458,398. Another preferred bleach catalyst is a manganese complex as described in our co-pending GB patent application 9127060.3. Alternatively the ligand and a manganese source can be separately added such as is described in co-pending GB application 9204706.7. It is particularly preferred to include in the compositions, a stabiliser for the bleach or bleach system, for example hydroxyethylidene-1,1-diphosphonic acid, ethylene diamine tetramethylene phosphonate and diethylene triamine pentamethylene phosphonate or other appropriate organic phosphonate or salt thereof, such as the Dequest® range hereinbefore described. These stabilisers can be used in acid or salt form, such as the calcium, magnesium, zinc or aluminium salt form. The stabiliser may be present at a level of up to about 1% by weight, preferably between about 0.1% and about 0.5% by weight. Detergency builders The detergency builders are those materials which counteract the effects of calcium, or other ion, water hardness, either by precipitation or by an ion sequestering effect. They comprise both inorganic and organic builders. They may also be sub-divided into the phosphorus-containing and non-phosphorus types, the latter being preferred when environmental considerations are important. In general, the inorganic builders -"omprise the various phosphate-, carbonate-, silicate-, borate- and aluminosilicates-type materials, particularly the alkali¬ metal salt forms. Mixtures of these may also be used. Examples of phosphorus-containing builders, when present, include the water-soluble salts, especially alkali metal pyrophosphates, orthophosphates, polyphosphates and phosphonates. Specific examples of inorganic phosphate builders include sodium and potassium tripolyphosphates, phosphates and hexametaphosphates. Examples of non-phosphorus-containing inorganic builders, when present, include water-soluble alkali metal carbonates, bicarbonates, borates, silicates, metasilicates, and crystalline and amorphous aluminosilicates. Specific examples include sodium carbonate (with or without calcite seeds) , potassium carbonate, sodium and potassium bicarbonates, silicates such as sodiummetasilicate and zeolites. Examples of organic builders include the alkali metal, ammonium and substituted ammonium, citrates, succinates, malonates, fatty acid sulphonates, carboxymethoxy succinates, ammonium polyacetates, carboxylates, polycarboxylates, aminopolycarboxylates, polyacetyl carboxylates and polyhydroxysulphonates. Specific examples include sodium, potassium, lithium, ammonium and substituted ammonium salts of ethylenediaminetetraacetic acid, nitrilotriacetic acid, oxydisuccinic acid, melitic acid, benzene polycarboxylic acids and citric acid. Other examples are organic phosphonate type sequestering agents such as those sold by Monsanto under the tradename of the Dequest® range and alkanehydroxy phosphonates. Other suitable organic builders include the higher molecular weight polymers and co-polymers known to have builder properties, for example appropriate polyacrylic acid, polymaleic acid and polyacrylic/polymaleic acid co- polymers and their salts, such as those sold by BASF under the Sokalan® Trade Mark. Polyacrylates or their derivatives may also be useful for their anti-ashing properties. Preferably the level of builder materials is from 5-50% by weight of the composition, more preferably 10-40%, most preferably 15-35%. Other optional ingredients Other ingredients comprise those remaining ingredients which may be used in liquid cleaning products, such as fabric conditioning agents, enzymes, perfumes (including deoperfumes) , fluorescent agent, micro-biocides, colouring agents, soil-suspending agents (anti-redeposition agent) , corrosion inhibitors, enzyme stabilising agents, and lather depressants. Amongst the fabric conditioning agents which may be used, either in fabric washing liquids or in rinse conditioners, are fabric softening materials such as fabric softening clays, quaternary ammonium salts, imidazolinium salts, fatty amines and cellulases. Enzymes which can be used in liquids according to the present invention include proteolytic enzymes (protease) , amylolytic enzymes (amylase) , lipolytic enzymes (Upases) and cellulolytic enzymes (cellulase) . Various types of proteolytic enzymes and amylolytic enzymes are known in the art and are commercially available. They may be incorporated as "prills", "marumes" or suspensions e.g.. Preferably enzymes are added as suspensions in a non-aqueous liquid surfactant. The preferred level of enzyme materials is from 0.01 to 5% by weight of the composition. The total amount of the fluorescent agent or agents used in a detergent composition is generally from 0.02-2% by weight. When it is desired to include anti-redepostion agents in the liquid cleaning products, the amount thereof is normally from about 0.1% to about 5% by weight, preferably from about 0.2% to about 2.5% by weight of the total liquid composition. Preferred anti-redeposition agents include carboxy derivatives of sugars and celluloses, e.g. sodium carboxymethyl cellulose, anionic poly-electrolytes, especially polymeric aliphatic carboxylates, or organic phosphonates. USE Composition in accordance with the present invention may be used for several detergency purposes, for example the cleaning of surfaces and the washing of fabrics. For the washing of fabrics, preferably an aqueous liquor containing 0.1 to 10 %, more preferably 0.2 to 2%, of the non-aqueous detergent composition of the invention is used. PROCESSING During manufacture of the non-aqueous liquid, it is preferred that all raw materials should be dry and (in the case of hydratable salts) in a low hydration state, e.g. anhydrous phosphate builder, sodium perborate monohydrate and dry calcite abrasive, where these are employed in the composition. In a preferred process, the dry, substantially anhydrous solids are blended with the liquid phase in a dry vessel. If deflocculant materials are used, these should preferably -at least partly- be mixed with the liquid phase, prior to the addition of the solids. In- order to minimise the rate of sedimentation of the solids, this blend is passed through a grinding mill or a combination of mills, e.g. a colloid mill, a corundum disc mill, a horizontal or vertical agitated ball mill. A preferred combination of such mills is a colloid mill followed by a horizontal ball mill since these can be operated under the conditions required to provide a narrow size distribution in the final product. Of course particulate material already having the desired particle size need not be subjected to this procedure and if desired, can be incorporated during a later stage of processing. During this milling procedure, the energy input results in a temperature rise in the product and the liberation of air entrapped in or between the particles of the solid ingredients. It is therefore highly desirable to mix any heat sensitive ingredients into the product after the milling stage and a subsequent cooling step. It may also be desirable to de-aerate the product before addition of these (usually minor) ingredients and optionally, at any other stage of the process. Typical ingredients which might be added at this stage are perfumes and enzymes, but might also include highly temperature sensitive bleach components or volatile solvent components which may be desirable in the final composition. However, it is especially preferred that volatile material be introduced after any step of de- aeration. Suitable equipment for cooling (e.g. heat exchangers) and de-aeration will be known to those skilled in the art. It follows that all equipment used in this process should preferably be completely dry, special care being ta after any cleaning operations. The same is true for subsequent storage and packing equipment. The particles comprising carrier material and dye material associated thereto, according to the invention, can be prepared separately, as discussed above, whereafter they are dispersed in the non-aqueous phase of the non-aqueous cleaning product, e.g. by mixing using high shear or using a mill. Preferably, the D(3,2) particle size is of from 0.1 μm to 2000 μm in the non-aqueous phase. A further embodiment of the invention provides a method of preparing a non-aqueous liquid detergent composition comprising a non-aqueous liquid phase, from 1 to 90% by weight of solid particles and dispersed droplets, said droplets comprising silicone polymer and hydrophobic particles and having a viscosity of from 5,000 to 60,000 mPa.s at 21s "1 at 25°C, wherein the solid particles are mixed with the non-aqueous liquid phase and wherein optionally the solid particles are milled before, during or after the mixing with the non-aqueous liquid phase, whereafter the droplets are dispersed in the non-aqueous liquid phase. Surprisingly we have found that post-dosing the silicone polymer not only make the milling step more efficient, but also improves sedimentation, lowers clear layer formation and/or poor improves dispersibility of the non-aqueous liquid. The invention will now be illustrated with respect to the following non-limiting examples. Example 1 The following formulation was prepared in a conventional way (including a ball-mill step) and the mixture of the silicone and hydrophobic particles was post- dosed and mixed for 10 minutes with a tip speed of 2m/s (standard to paddle arrangement) : Ingredient % w/w Nonionic - 1) 22.40 Nonionic 2 > 27.30 LAS acid 6.00 Na Carbonate 16.40 Ca Carbonate 6.00 SCMC 1.50 Anti-ash polymer 1.50 CBS-X (fluorescer) 0.15 Silica 3 > 4.00 Na Perborate 1H20 10.50 Enzymes 1.05 Perfume 0.50 Q2-3302 4 > 2.70 1 > Vista 1012-62 2 > Dobanol 25-3 3 * Sipernat D17 ex Degussa 4) mixture comprising hydrophobic silica and polydimethylsiloxane ex Dow Corning (density 0.98-1.02; viscosity about 30.000mPa.s) The non-aqueous liquid of the Example showed good properties with regard to sedimentation and dispersibility. Example 2 The formulation of Example 1 (without enzymes and perfume) was prepared with the following chances: Composition A: without Q2-3302; with 2.7% by wt of DB100 5) Composition 1: with 2.7% Q2-3302 (post-dosed, as in Ex. 1) Composition 2: with 2.7% Q2-3302 (ball-milled together with composition) Composition 3: with 2.7% Q2-3302 and 1.2% DC198 6) (both post-dosed) . Composition B: same as for composition A, but with thorough de-aeration after preparation. Composition 4: same as for composition 1, but with thorough de-aeartion after preparation. 5) low viscosity droplets of silicone polymer and hydrophobic particles; viscosity of 3,000 mPa.s at 21s~ 1 at 25°C; ex Dow Corning; 6) alkoxypoly-dimethyl stabilising agents; ex Dow Corning. The compositions were compared in a model experiment in which clear layer formation was measured with stoppered glass 100 cm 3 measuring cylinders containing 80cm 3 of the product. These were suspended vertically in a glass-sided water bath and thermostatted at 37°C. Compositions A, 1, 2 and 3 were stored for 12 weeks and compositions B and 4 were stored for 4 weeks. The height in centimeters of the liquid meniscus and the clear layer separation layer was measured in dulpo using a cathetometer (clear layer separation of Composition 2 was only determined once) . The results are shown in the attached figure. The composition is identified on the X-axis, the clear layer separation on the Y-axis in cm. It is clear that compositions 1, 2, 4 and in particular 3 have a lower clear layer separation than of the comparative compositions A and B. Example 3 DB100 (viscosity of 3000mPa.s) was blended with silicone fluid (viscosity 60000 mPa.s) using a Haake Rheocord 90 with a Rheomix 3000E head with Z blade paddles rotating at 100 rpm. Three batches were made, two consisting of a 50/50 by weight mixture of DB100 to silicone fluid and one consisting of a 43/57 by weight mixture. One of the 50/50 mixtures was blended for 30 minutes after addition of the fluid to the DB100, the other for 45 minutes after addition of DB100 to the fluid. The 43/57 mixture was also blended for 45 minutes after addition of DB100 to the fluid. In all instances, addition of one ingredient to the other was accompanied by continuous mixing. Viscosity of the blends was found to be about 20,500 mPa.s at 21s "1 at 25°C for the 50/50 mixtures and 25,600 mPa.s at 21s "1 at 25°C for the 43/57 mixture. This Example shows that a high viscosity silicone polymer composition can be made by blending a conventional silicone polymer with a high viscosity fluid. Optionally, the solid content of the composition, e.g. hydrophobic particles, can be adjusted.

Claims: CLAIMS 1. Non-aqueous liquid cleaning composition comprising a non-aqueous liquid phase, from 1 to 90% by weight of solid particles and dispersed droplets comprising silicone polymer and hydrophobic particles, said droplets having a viscosity of from 5,000 to 60,000 mPa.s at 21s -1 at 25°C. 2. Composition according to claim 1, wherein the hydrophobic particles are hydrophobic silica. 3. Composition according to claims 1-2, wherein the silicone polymer is polydimethylsiloxane. 4. Composition according to claims 1-3, wherein the droplets are present in an amount of from 0.1 to 5.0% by weight of the composition. 5. Composition according to claims 1-4, wherein the polymer comprises a mixture of a high viscosity polydimethylsiloxane and a low viscosity polydimethylsiloxane. 6. Method of preparing a non-aqueous liquid detergent composition comprising a non-aqueous liquid phase, from 1 to 90% by weight of solid particles and dispersed droplets, said droplets comprising silicone polymer and hydrophobic particles and having a high viscosity, wherein the solid particles are mixed with the non-aqueous liquid phase and optionally milled before, during or after the mixing with the non-aqueous liquid phase, whereafter the droplets are dispersed in the non-aqueous liquid phase. 7. Non-aqueous liquid cleaning composition comprising a non-aqueous liquid phase, from 1 to 90% by weight of solid particles and dispersed droplets comprising silicone polymer and hydrophobic particles, said droplets having a viscosity of more than 3,000 mPa.s at 21s -1 at 25°C.

Inventors: GARRETT PETER ROBERT, KOWALSKI ADAM JAN, PRESCOTT ANDREW JOHN, VAN DER HOEVEN PHILIPPUS CORNE, YORKE JOHN WILLIAM H, GARRETT, PETER, ROBERT, KOWALSKI, ADAM, JAN, PRESCOTT, ANDREW, JOHN, VAN DER HOEVEN, PHILIPPUS, CORNELIS, YORKE, JOHN, WILLIAM, H.
Applicants: UNILEVER NV, UNILEVER PLC, UNILEVER N.V.
Application year: 1994
Main classification: C11D17
IPC codes: C11D3, C11D17