Apparatus for gas-liquid contact

Abstract: An apparatus for gas-liquid contact in which tubular structure fillers (2) having a cross section of any of various shapes and having straight tubular portions are arranged (in the apparatus) in a substantially vertical direction in the form of plural steps so that the gas-liquid contact surfaces of the fillers may be parallel with the flow of the gas, whereby the gas is brought into contact with the liquid by feeding the liquid from a site above the fillers, allowing the liquid to flow downward along the filler surfaces, and feeding the gas from a site under the fillers, the apparatus for gas-liquid contact being characterized in that the gas-liquid contact surfaces comprise rough surface portions, porous surface portions, meshes or plates to which meshes adhere, or there is interposed, between the plural steps of the fillers, a dispersing plate for receiving the liquid downward coming from the site above the fillers, dispersing the liquid, and allowing the liquid to downward flow.

Description: FIELD OF THE INVENTION AND RELATED STATEMENT The present invention relates to an apparatus for gas-liquid contact, particularly to an apparatus for gas-liquid contact capable of efficiently bringing a gas into contact with a liquid like a CO 2 gas absorption device for removing a CO 2 gas from an exhaust gas by bringing the CO 2 gas contained in the exhaust gas into contact with a CO 2 gas absorbing liquid. Such an apparatus is for example disclosed in EP-A-0501599 (JP-A-4271809). In recent years, a greenhouse effect due to CO 2 has been pointed out as one of the causes of a global atmosphere warming phenomenon, and it has been internationally required to urgently take measures for the greenhouse effect in order to protect a global atmospheric environment. The generation source of CO 2 lies in every human activity field in which a fossil fuel is burnt, and the exhaust control of CO 2 tends to be further strengthened in future. As one of the measures for the exhaust control, for power generation facilities of thermal power plants in which a large amount of the fossil fuel is used, there have been energetically researched a method for removing and collecting CO 2 from the combustion exhaust gas of a boiler, and a method for storing CO 2 without discharging it to the atmosphere. On the other hand, in a gas-liquid contact technique which is employed in an absorption process of a chemical plant, a bubble cap plate tower and a packed tower have been used so that the gas-liquid contact may be achieved as much as possible. As the filler of the latter, Raschig rings having various shapes have been used. In the apparatus for the gas-liquid contact for absorbing CO 2 in the combustion exhaust gas, it is necessary to efficiently treat a large amount of the gas in a short time. Therefore, an apparatus for gas-liquid contact is desired in which expansion, contraction and collision of a gas flow are not in a gas passage, no eddy occurs, and unnecessary pressure loss due to the above factors hardly takes place. Moreover, an apparatus for gas-liquid contact is desired which is constituted as simply as possible and by which a gas-liquid contact area and a contact time can be increased to resultingly heighten a contact efficiency. As the CO 2 gas absorption device for removing CO 2 from the combustion exhaust gas, the present inventors have previously suggested a CO 2 gas absorption device in which many fillers are arranged so that the gas-liquid contact surfaces of the fillers may be parallel with a gas flow and they comprise tubular structures whose cross section has any of various shapes and whose tubular portions are straight, as shown in Fig. 1 (which shows the whole constitutional view of the CO 2 gas absorption device which will also be used in an embodiment of the apparatus for gas-liquid contact of the present invention) (cf. EP-A-0501599). That is, in Fig. 1, reference numeral 1 is a CO 2 gas absorption device, and numerals 2, 2 are fillers comprising tubular structures whose tubular portion is straight, and these fillers are arranged in the form of plural steps in a substantially vertical direction. Reference numeral 3 is a line for transporting a CO 2 absorbing liquid, numeral 4 is a liquid dispersing nozzle, 5 is a storage space of the absorbing liquid in which CO 2 is absorbed, 6 is a combustion exhaust gas containing CO 2 , and 7 is a clean exhaust gas from which CO 2 is removed. As described above, any of the various shapes can be employed as the cross section of the fillers 2 comprising the tubular structures, and this cross section may be constituted of one or a combination of these shapes. In the fillers 2 comprising the tubular structures, the flow of the gas is parallel with the absorbing surface (the gas-liquid contact surface). Thus, in the gas flow path, the expansion, contraction and collision of the gas flow are not present, and no eddy occurs, so that the unnecessary pressure loss due to these factors is very small. In this case, the absorbing liquid is held by the absorbing surfaces of the fillers 2 comprising the tubular structures, and the held absorbing liquid is brought into contact with the gas flow to absorb CO 2 , while flowing downward along the surfaces. Therefore, according to this constitution, the pressure loss can be remarkably decreased, in contrast to fillers such as conventional Raschig rings. However, the above-mentioned CO 2 gas absorption device has the following problems. (a) When the absorbing surfaces of the tubular structures which are the fillers are smoothly mirror-finished, the absorbing liquid flows downward along the absorbing surfaces of the tubular structures in the form of a string owing to surface tension or cohesive force, so that it does not expand all over the absorbing surfaces and so the wet area decreases. In consequence, the gas-liquid contact area tends to decrease and the CO 2 absorption efficiency also tends to deteriorate inconveniently. (b) The unit length of each tubular structure filler in the gas flow direction is restricted in view of manufacture. Therefore, if the fillers having a length of, for example, about 20 m are filled, it is necessary to pile up the tubular structure fillers up to about 20 steps. In this case, a gap is formed between each pair of the tubular structures. When the absorbing liquid flows from upper tubular structures to lower tubular structures, its flow takes the form of a string owing to the above-mentioned gap, so that its dispersibility is impaired. In order to decrease this gap, a high processing precision is required, which leads to increase of cost. (c) The CO 2 gas absorption device has some points to be improved, in the case that the gas-liquid contact surfaces on the inner walls of the tubular structures which are the fillers are mirror-finished. That is, the absorbing liquid flows downward along the gas-liquid contact surfaces of the tubular structures in the form of a string owing to surface tension or cohesive force without expanding all over the inner walls, so that the wet area (the gas-liquid contact area) decreases, and the residence time of the downward flowing liquid on the gas-liquid contact surfaces is also short. In consequence, the CO 2 absorption efficiency is not necessarily satisfied. (d) As another example of the horizontal section of the tubular structure fillers, there is a section in which many wavy crests (or troughs) and the straight portions come in contact with each other. As described above, the fillers of the CO 2 gas absorption device have the shown horizontal section of the tubular structures in which lattices or the above-mentioned wavy crests (or troughs) and the straight portions come in contact with each other, and according to these fillers, the effect of the gas-liquid contact efficiency is present to some extent, but some points to be improved also remain. That is, the absorbing liquid which is fed to the tubular structure from the liquid dispersing nozzle 4 and which flows downward along the gas-liquid contact surfaces hardly expands all over the inner walls due to surface tension or cohesive force, so that the absorbing liquid is liable to collect at the four corners of the lattices and at corners formed by the wavy crests and the straight lines. In consequence, the wet area (the gas-liquid contact area) decreases, and the residence time of the downward flowing absorbing liquid on the gas-liquid contact surfaces is also short. Thus, it is desired to further improve the CO 2 absorption efficiency. OBJECT AND SUMMARY OF THE INVENTION In view of the above-mentioned situations, the present invention has been intended. One object of the present invention is to provide an apparatus for gas-liquid contact capable of solving the above-mentioned problem (a) and improving a gas-liquid contact efficiency by increasing the contact area per unit area of the gas-liquid contact surfaces of tubular structure fillers. A further object of the present invention is to provide an apparatus for gas-liquid contact capable of solving the above-mentioned problem (b) and improving dispersibility during the downward flow of an absorbing liquid from upper step to lower step of the tubular structure fillers. A still further object of the present invention is to provide an apparatus for gas-liquid contact capable of solving the above-mentioned problem (c) by the use of a specific material for the gas-liquid contact surfaces of the tubular structure fillers. Another object of the present invention is to provide an apparatus for gas-liquid contact capable of solving the above-mentioned problem (d) by forming the horizontal section of the tubular structure fillers into a specific shape. The constitutions of the present invention for achieving the above-mentioned objects are characterized by the following items (1) to (4) in an apparatus for gas-liquid contact comprising tubular structure fillers having straight tubular portions arranged (in the apparatus) in a substantially vertical direction in plural steps so that the gas-liquid contact surfaces of the fillers may be parallel with the flow of the gas, whereby the gas can be brought into contact with the liquid by feeding the liquid from a site above the fillers, allowing the liquid to flow downward along the filler surfaces, and feeding the gas from a site under the fillers. (1) In the apparatuses for gas-liquid contact, it is characterized that the gas-liquid contact surfaces of the fillers are made of a material in which a mesh adheres to the surface of plates. (2) In the apparatus for gas-liquid contact of item (1), it is characterized that the gas is a combustion exhaust gas and the liquid is a CO 2 absorbing liquid. The present invention makes it possible to increase the gas-liquid contact area of the inner walls of the fillers arranged in the apparatus for gas-liquid contact, to prolong the residence time of the downward flowing liquid, and to largely improve the gas-liquid contact efficiency.As described above, according to the present invention, the liquid does not flow downward in the form of a string along the gas-liquid contact surface but it widely expands on the contact surface, so that the residence time of the downward flowing liquid can be prolonged, and in consequence, the gas-liquid contact efficiency can be improved. (3) In the apparatus for gas-liquid contact of item (1), it is characterized that the horizontal section of the fillers has a shape selected from the group consisting of a circle (A), a circular arc or a continuous combination of circular arcs (B) and straight lines which do not mutually intersect or contact (C). (4) In the apparatus for gas-liquid contact of item (3), it is characterized that the gas is a combustion exhaust gas and the liquid is a CO 2 absorbing liquid. According to the present invention, the gas-liquid contact area on the inner walls of the fillers arranged in the apparatus for gas-liquid contact can be increased, and the residence time of the downward flowing liquid can be prolonged, whereby the gas-liquid contact efficiency can be remarkably improved. In addition, according to the present invention, the liquid does not flow downward along the gas-liquid contact surface in the form of a string, but it widely expands on the contact surface, so that the residence time of the downward flowing liquid is prolonged and consequently the gas-liquid contact efficiency can be noticeably improved. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a whole perspective view showing a CO 2 gas absorption device for use in an embodiment of the present invention and its related CO 2 gas absorption device; Fig. 2 is a perspective view showing a tubular structure arranged in the CO 2 gas absorption device; Fig. 3 is a partial perspective view of a filler showing the embodiment of the present invention which is arranged in the CO 2 gas absorption device; Fig. 4 is an enlarged view of a gas-liquid contact surface formed on the inner wall of the filler in Fig. 3; Fig. 5 is an illustrative view showing another embodiment of the filler regarding the present invention; Fig. 6 is an illustrative view showing still another embodiment of the filler regarding the present invention; Fig. 7 is an illustrative view of a testing equipment for inspecting an effect of the apparatus for gas-liquid contact according to the present invention; Fig. 8 is a diagram showing test results which elucidate differences of CO 2 absorption efficiency due to different materials for the gas-liquid contact surface; Fig. 9 is a diagram showing test results which elucidate differences of a held liquid volume due to different materials for the gas-liquid contact surface; Fig. 10 is a whole perspective view of a CO 2 gas absorption device to which an apparatus for gas-liquid contact regarding a second embodiment of the present invention is applied; Fig. 11 is an illustrative view of the horizontal section of the tubular structure having straight lines which do not mutually intersect or contact in the second embodiment of the present invention; Fig. 12 is an illustrative view of the horizontal section of the tubular structure having circles in the second embodiment of the present invention; Fig. 13 is an illustrative view of the horizontal section of the tubular structure having connected semi-circular arcs in the second embodiment of the present invention; Fig. 14 is an illustrative view of the horizontal section of the tubular structure having spirals in the second embodiment of the present invention; Fig. 15 is an illustrative view of the tubular structure comprising a plate and a mesh which adheres to the plate in the second embodiment of the present invention; Fig. 16 is an illustrative view of a testing equipment for inspecting an effect of the second embodiment of the apparatus for gas-liquid contact of the present invention; Fig. 17 is a diagram showing test results which elucidate differences of CO 2 absorbing efficiency in the case that absorbing tubes having different shapes of the horizontal section are used; and Fig. 18 is an illustrative view of the shape of the horizontal section of the other tubular structure filler for use in the CO 2 gas absorption device in Fig. 1. DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS Now, suitable embodiments of the present invention will be exemplarily described in detail in reference to drawings. As the embodiment of an apparatus for gas-liquid contact of the present invention, reference will be made to a CO 2 gas absorption device for removing CO 2 from a combustion exhaust gas by bringing the combustion exhaust gas containing CO 2 into contact with a CO 2 absorbing liquid. In Fig. 1, tubular structure fillers 2 are vertically arranged in the form of plural steps in a CO 2 absorption device body 1, and these fillers have an optional shape in a horizontal section and have straight tubular portions. In Fig. 1, the horizontal section of the tubular structure fillers 2 shows the shape of lattice. The apparatus body 1 is equipped with a CO 2 absorbing liquid transport line 3 for connecting a liquid dispersing nozzle 4 in the top of the body 1 to an absorbing liquid storage space 5 on the bottom of the body 1. An absorbing liquid reproduction process (not shown) for removing CO 2 from the absorbing liquid to improve the absorbing capacity may be provided in the middle of the transport line 3. The liquid dispersing nozzle 4 is installed so as to disperse the CO 2 absorbing liquid delivered through the transport line 3 to the fillers 2 as uniformly as possible. On the bottom of the apparatus body 1, there is provided an absorbing liquid storage space 5 for storing the CO 2 absorbing liquid which absorbs CO 2 while the liquid is downward flowing through the fillers 2. An opening, through which a combustion exhaust gas 6 containing CO 2 is introduced into the apparatus body 1, is formed on a side of the lower portion of the apparatus body 1. At the top of the apparatus body 1, there is formed an opening through which a clean exhaust gas 7 is discharged to the outside, and this clean exhaust gas 7 is obtained by removing CO 2 from the combustion exhaust gas with the CO 2 absorbing liquid while the gas flows upward through the fillers 2. Fig. 2 shows an enlarged partial view of the tubular structure filler 2. The filler 2 is formed into a tubular structure having a lattice-like horizontal section, and through this tubular structure filler 2, the exhaust gas 6 can flow upward from the bottom of the apparatus body 1 and the fed CO 2 absorbing liquid can also flow downward from the liquid dispersing nozzle 4. The inside walls of the tubular portions constitute absorbing surfaces (gas-liquid contact surfaces) on which the combustion exhaust gas 6 is reacted with the CO 2 absorbing liquid. The filler 2 is constituted of porcelaneous tubular structures 2' having one lattice side length De of, for example, 15 mm which are laterally arranged as shown by reference numerals 2 1 , 2 2 , 2 3 , 2 4 ... in Fig. 1. The thus constituted filler 2 has, for example, an area of 300 mm 2 and a length of 500 mm. The fillers 2 are vertically arranged in the form of, for example, 20 stages in the apparatus body 1. According to the fillers 2 comprising the above-mentioned tubular structures, the gas flows in parallel with the absorbing surfaces, and expansion, contraction and collision of the gas flow and an eddy scarcely occur in a gas path, so that pressure loss due to these factors can be sufficiently inhibited. The shape of the tubular structure 2' is not restricted to the lattice in Fig. 2, and for example, hexagon, rectangle, triangle and U shape are usable, as long as they form the gas parallel flow. Moreover, with regard to a material for the tubular structure 2', a porcelain, a metal, a ceramic fiber such as silica fiber and a plastic such as polyethylene are usable, so long as they are not corroded or swelled by the CO 2 absorbing liquid. As for a manufacturing method, the structure shorn in Fig. 2 can usually be manufactured by an extrusion molding method, but a combination of a flat plate and a molding plate or a corrugate machine molding method is also applicable. Anyway, an economical manufacturing method can be selected in accordance with the shape and material. The present invention is characterized in that the gas-liquid contact surface formed on the inner wall of each tubular structure filler 12 is constituted of a mesh 14 which adheres to the surface of a plate 13. Fig. 3 is a perspective view showing a part of the tubular structure filler 12 corresponding to the tubular structure filler 2 in Fig. 1, and Fig. 4 shows an enlarged view of the gas-liquid contact surface of the filler 12. In Fig. 4, a weaving manner of the mesh which adheres to the surface of the plate 13 is plain weave, but this weave is not limited and any of various weaves inclusive of twill weave can be used. No particular restriction is put on a technique for sticking the mesh 14 on the plate 13, and any means such as welding or bonding can be utilized, as long as the mesh 14 stuck on the tubular structure having an optional shape in the horizontal section by such a technique does not separate from the plate 13 during use. The plate 13 and the body 14 should be made of a material which is not attacked by the gas and the liquid for the gas-liquid contact. For example, a wire mesh, a plastic mesh and a mesh made of another material are usable. The mesh may be disposed so that the wires of the mesh may have a suitable angle to the ground. The size of the mesh to be selected is preferably 3 mesh or more, more preferably 8 mesh or more. Fig. 5 is a perspective view showing another embodiment of the filler 12 of the present invention. In Fig. 5, a strip-like filler 15 formed by zigzagging the plate 13 having the adhered mesh 14 is arranged in the apparatus for gas-liquid contact. Fig. 6 is a perspective view showing still another embodiment of the above-mentioned filler 12 of the present invention. In this embodiment, fillers 17 comprising plates 13 and meshes 14 stuck on their surfaces are arranged with a certain space therebetween in a barrel 16 of a cylindrical CO 2 absorption device so that the gas-liquid contact surfaces of the plates 13 may be parallel with each other. The meshes 14 are stuck on both the sides of each plate 13, and if necessary, a spacer may be inserted between the adjacent plates 13 having the adhered meshes 14. The space between the plates 13 (arrangement density) should be selected so that the absorbing liquids flowing downward along the adjacent plates 13 may not come in contact with each other and so that the flow path resistance of the combustion exhaust gas may not be impaired. In the case of the plate fillers 17 shown in Fig. 6, the absorbing liquid fed from the top attaches to a point of the plate 13, flows downward while horizontally expanded by the mesh 14, and comes in contact with the combustion exhaust gas. Therefore, a contact area increases and the residence time of the downward flowing absorbing liquid also extends, which leads to the remarkable improvement of the gas-liquid contact efficiency. In order to confirm a gas-liquid contact efficiency in the case that a member obtained by stacking the above-mentioned mesh on the surface of the above-mentioned plate was used on a gas-liquid contact surface, a model test was made, and the performance of a cylindrical inside surface formed with the above-mentioned member was compared with that of another cylindrical inside surface formed with another member. Fig. 7 shows a testing equipment which is used herein. In Fig. 7, reference numeral 21 is a vertically disposed stainless steel absorbing tube having a length of 1.15 m and an inside diameter of 18 mm. Three samples are used: a stainless steel tube in which its inside surface is chemically treated by immersing it in a 35% hydrochloric acid solution at a temperature of 30°C for 10 minutes (Comparative Example 1), a stainless steel tube treated by sandblasting (center line average height = 1 µm, Comparative Example 2), and a stainless steel tube to which a 20-mesh wire mesh is attached (Example). Reference numeral 22 is a CO 2 absorbing liquid tank containing a 30% aqueous monoethanolamine solution, and this solution is fed to the top of the absorbing tube 21 through an absorbing liquid inlet 24 by means of a metering pump 23. The absorbing liquid is fed to one point on the inner surface of the absorbing tube 21 at a flow rate of 4 liters/hour, and at the time of the downward flow, an expansion degree of the absorbing liquid varies with the members of the inner surfaces. The absorbing liquid which has flowed downward in contact with a test gas is led to a liquid reservoir 27. On the other hand, the test gas having a CO 2 concentration of 9.7-9.8 vol% (nitrogen concentration = 90.2-90.3 vol%) is fed at a flow rate of 2 m 3 /hour to the absorbing tube 21 through a gas inlet 25 provided at a lower portion of the absorbing tube 21. A CO 2 concentration of the test gas is analyzed in the vicinity of the gas inlet 25 of the absorbing tube 21 by a CO 2 continuous analyzer 28, and the test gas is then brought into contact with the CO 2 absorbing liquid during rising through the absorbing tube 21. After the CO 2 concentration of the test gas has been similarly analyzed again in front of a gas outlet 29, the test gas is discharged from the system. Every test was made at room temperature (25°C). Reference numerals 30, 30, 30 are three gas cylinders filled with a CO 2 gas, a nitrogen gas, and an oxygen gas, respectively. Numeral 31 is a gas flow rate controller, and 32 is a switch cock. The obtained results of this test are shown in Figs. 8 and 9. Fig. 8 shows relations between a CO 2 absorption ratio (%, ordinate) and a liquid/gas ratio L/G (liter/m 3 N, abscissa) on the basis of the different members for the gas-liquid contact surfaces. Moreover, Fig. 9 shows a liquid hold up volume (ml/m, ordinate) in the case that the respective contact surface members are used. It is apparent from Figs. 8 and 9 that the stainless steel absorbing tube provided on the inside surface thereof with the 20-mesh wire mesh is much more excellent in the absorption ratio and the liquid hold up volume than other members, the aforesaid wire mesh corresponding to the member of the present invention comprising the plate and the mesh stuck on the surface thereof. After the test, the inside walls of the absorbing tubes are inspected. As a result, wet ratios are 60% in Comparative Example 1, 26% in Comparative Example 2, and 81% in Example. As the second embodiment of the apparatus for gas-liquid contact of the present invention, an example which is applied to a CO 2 gas absorption device for removing CO 2 from a combustion exhaust gas by bringing the combustion exhaust gas containing CO 2 into contact with a CO 2 absorbing liquid will be described in reference to the drawings (Figs. 10 to 17). Fig. 10 shows a CO 2 gas absorption device in which tubular structure fillers 40 are arranged instead of the tubular structure fillers 2 in Fig. 1. Other members in Fig. 10 have the same reference numerals as in Fig. 1, and they have already been described and so the description regarding them will be omitted. Between the plural steps of the fillers 40, a mesh-like member such as a wire mesh may be interposed for the sake of the redispersion of the downward flowing absorbing liquid. The present invention is characterized in that the horizontal section of the filler has a shape selected from the group consisting of circles (A), circular arcs or continuously combined circular arcs (B) and straight lines (C) which neither mutually intersect nor contact. In general, the horizontal section of the filler comprises only one of these shapes, but it may comprise two or more thereof. In Fig. 10, the shape of the horizontal section of the tubular structure filler 40 is one of the shapes usable in the present invention, and this shape comprises the group of the straight lines which neither mutually intersect nor contact, particularly it comprises parallel lines in this example. In this case, the tubular structure is constituted of a plurality of vertically arranged plates, as apparently shown in Fig. 10. The arrangement density of these plates should be selected so that the absorbing liquids flowing downward along the vertically or horizontally adjacent plates 13 may not come in contact with each other and so that the flow path resistance of the combustion exhaust gas may not be impaired. Preferably, the plates are arranged at a higher density in consideration of these requirements. This arrangement density may be adjusted by interposing a spacer between the adjacent plates. Fig. 11 shows another example of the filler, i.e., a linear filler 42 in which the shape of a horizontal section comprises straight lines which neither mutually intersect nor contact; Fig. 12 shows a circular filler 52; Fig. 13 shows a continuous semicircular arc filler 62; and Fig. 14 shows a spiral filler 72 which seems to be continuously combined circular arcs having a gradually increasing (or decreasing) radius. The continuous combination of the circular arcs additionally includes a smoothly formed free curve. However, a shape in which another circular arc is combined with the circular arc at a point is excluded from the category of the continuous combination regarding the present invention. Incidentally, each of reference numerals 41, 51, 61 and 71 in Figs. 11, 12, 13 and 14 is a CO 2 absorption device. When the filler having the shape of this example is used, the absorbing liquid fed from the top does not get together at a certain position to flow downward in the form of a string, but tends to expand in the horizontal direction of the inner wall, when it flows downward along the inner wall (the gas-liquid contact surface) of the tubular structure. In consequence, a gas-liquid contact efficiency is remarkably improved. Fig. 15 shows an enlarged view of the gas-liquid contact surface of the filler material. In Fig. 15, a weaving manner of the mesh 81 is plain weave, but this weave is not limited and any of various weaves inclusive of twill weave can be used. No particular restriction is put on a technique for sticking the mesh 81 on the plate 82, and any means such as welding or bonding can be utilized, as long as the mesh 14 stuck on the tubular structure having an optional shape in the horizontal section by such a technique does not separate from the plate during use. As the mesh, for example, a wire mesh, a plastic mesh and a mesh made of another material are usable. The mesh may be disposed so that the wires of the mesh may have a suitable angle to the ground. The size of the mesh to be selected is preferably 3 mesh or more, more preferably 8 mesh or more. As the filler material of this example, there can be employed a material which is not attacked by the gas and the liquid for the gas-liquid contact. In order to confirm a gas-liquid contact efficiency in the case that a filler having a horizontal section shape of this embodiment was used, a CO 2 absorbing test was made, as the simplest case, using a circular absorbing tube (Example), a triangular absorbing tube (Comparative Example 1), and a quadrangular absorbing tube (Comparative Example 2) which were the barrels of absorption devices having an inside diameter of 15 mm and which were made of a transparent acrylic resin. These tubes having the respective shapes were designed so that the total areas of their inside walls might be equal to each other. Fig. 16 shows a testing equipment which is used herein. In Fig. 16, reference numeral 91 is a vertically disposed absorbing tube having a length of 1.15 m. Numeral 92 is a CO 2 absorbing liquid tank containing a 30% aqueous monoethanolamine solution, and the CO 2 absorbing liquid is fed to the top of the absorbing tube 91 through an absorbing liquid inlet 94 by means of a metering pump 93. The absorbing liquid is constantly fed to the inner wall of the absorbing tube at a flow rate of 4 liters/hour by overflow, as shown in this drawing. At the time of the downward flow, an expansion degree of the absorbing liquid, a wet degree of the inside walls and a CO 2 absorbing efficiency vary with the shapes of the above-mentioned absorbing tubes 91. The absorbing liquid which has flowed downward in contact with a test gas is led to a liquid reservoir 97. On the other hand, the test gas having a CO 2 concentration of 9.7-9.8 vol% (nitrogen concentration = 90.2-90.3 vol%) is fed at a flow rate of 2 m 3 /hour to the absorbing tube 91 through a gas inlet 95 provided at a lower portion of the absorbing tube 91. A CO 2 concentration of the test gas is analyzed in the vicinity of the gas inlet 95 of the absorbing tube 91 by a CO 2 continuous analyzer 98, and the test gas is then brought into contact with the CO 2 absorbing liquid during rising through the absorbing tube. After the CO 2 concentration of the test gas has been similarly analyzed again in front of a gas outlet 99, the test gas is discharged from the system. Every test was made at room temperature (25°C). Reference numerals 100, 100, 100 are three gas cylinders filled with a CO 2 gas, a nitrogen gas, and an oxygen gas, respectively. Numeral 101 is a gas flow rate controller, and 102 is a switch cock. The obtained results of this test are shown in Fig. 17. Fig. 17 shows relations between a CO 2 absorption ratio (%, ordinate) and a liquid/gas ratio L/G (liter/m 3 N, abscissa) on the basis of the different shapes for the gas-liquid contact surfaces. As is apparent from Fig. 17, when the circular absorbing tube having the filler horizontal section shape of this embodiment is used, a CO 2 absorption ratio is much more excellent than in the cases of the quadrangular tube and the triangular tube. Moreover, during the absorbing test, a downward flow state of the absorbing liquid was observed. As a result, it was apparent that the inner wall of the circular absorbing tube was entirely wetted with the absorbing liquid and a wet rate was 100%. On the contrary, in the quadrangular tube and the triangular tube, the absorbing liquid tended to get together and flow only at corners and the wet rates of the both tubes were about 20%.

Claims: An apparatus for gas-liquid contact comprising tubular structure fillers (2) having straight tubular portions, said tubular structure fillers (2) being arranged in a substantially vertical direction in plural steps within the apparatus so that the gas-liquid contact surfaces of the fillers are parallel with the flow of the gas (6), whereby the gas (6) can be brought into contact with the liquid by feeding the liquid from a site above the fillers (2), allowing the liquid to flow downwardly along the filler surfaces, and feeding the gas from a site under the fillers (2), said apparatus being characterized in that the fillers (2) consist of plates (13) and that a mesh (14) is adhered to the plates (13). An apparatus for gas-liquid contact according to claim 1 wherein the horizontal section of the fillers (2) has a shape selected from the group consisting of circular arcs and straight lines which neither mutually intersect nor contact. The apparatus for gas-liquid contact according to claim 1 or 2, wherein the gas (6) is a combustion exhaust gas and the liquid is a CO 2 absorbing liquid.

Inventors: FUJII MASUMI, HOTTA YOSHITSUGU, IIJIMA MASAKI, JINNO YUKIHIRO, KARASAKI MUTSUNORI, KAWASAKI MASAMI, KITAMURA KOUICHI, MIMURA TOMIO, MITSUOKA SHIGEAKI, SHIMOJO SHIGERU, SUDA TAIICHIRO, YOSHIDA KUNIHIKO, FUJII, MASUMI, HOTTA, YOSHITSUGU, IIJIMA, MASAKI, JINNO, YUKIHIRO, KARASAKI, MUTSUNORI, KAWASAKI, MASAMI, KITAMURA, KOUICHI, MIMURA, TOMIO, MITSUOKA, SHIGEAKI, SHIMOJO, SHIGERU, SUDA, TAIICHIRO, YOSHIDA, KUNIHIKO, FUJII, MASUMI, C/O THE KANSAI ELECTRIC POWER, HOTTA, YOSHITSUGU, C/O THE KANSAI ELECTRIC POWER, IIJIMA, MASAKI, C/O MITSUBISHI JUKOGYO K.K., JINNO, YUKIHIRO, C/O THE KANSAI ELECTRIC POWER, KARASAKI, MUTSUNORI, C/O MITSUBISHI JUKOGYO K.K., KAWASAKI, MASAMI, C/O THE KANSAI ELECTRIC POWER, KITAMURA, KOUICHI, C/O THE KANSAI ELECTRIC POWER, MIMURA, TOMIO, C/O THE KANSAI ELECTRIC POWER, Mitsuoka, Shigeaki, c/o Hiroshima Res &amp; Dev Center, Shimojo, Shigeru, c/o Technical Research Center, SUDA, TAIICHIRO, C/O THE KANSAI ELECTRIC POWER, YOSHIDA, KUNIHIKO, C/O THE KANSAI ELECTRIC POWER
Applicants: KANSAI ELECTRIC POWER CO, MITSUBISHI HEAVY IND LTD, MITSUBISHI JUKOGYO KABUSHIKI KAISHA, THE KANSAI ELECTRIC POWER CO., INC.
Application year: 1994
Main classification: B01D53
IPC codes: B01J19, B01D53