Electron beam display device and production thereof

Abstract: Disclosed is an electron beam display device which has high contrast and excellent image quality, by eliminating halation due to re-collision of the electrons in the fluorescent element area. The present invention provides an electron beam display device comprising a face glass (8) on which an image is formed, a cathode for emitting electron beam, a fluorescent element layer (9) present on the face glass (8) with facing the cathode, to which electron beam is collided to emit light for forming an image on the face glass (8), an aluminum layer as anode (20), present on said fluorescent element layer (9), and a carbon layer (21) present on the aluminum layer (20), having such a thickness sufficient to prevent returning electrons reflected in the aluminum anode (20) layer by collision of electron beam with the aluminum anode layer (20) back into the face glass (8).

Description: The present invention relates to an electron beam display device comprising a face glass on which an image is formed, a cathode for emitting an electron beam, a fluorescent element layer present on said face glass with facing said cathode, to which the electron beam is directed to emit light for forming an image on said face glass, an aluminium layer as an anode, present on said fluorescent element layer, and a carbon layer present on said aluminium layer. More particularly, such a display device is to be used in connection with video appliances and should have a high contrast ratio. Such a display device is already known from EP-A-0 446 878 and will be described with reference to Fig. 1. Fig. 1 shows the principle of such a flat plate type display device. Electrodes are disposed in a vacuum container not shown in the drawing, and number 1 is a back electrode, and 2 denotes a plurality of linear cathodes which emit electron beams. Number 3 is an electron beam focusing electrode, 4 is a modulation electrode, 5 is an electron beam focusing electrode, 6 is a horizontal deflecting electrode, 7 is a vertical deflecting electrode, 8 is a face plate, and 12 is an electron beam. Fig. 7 shows a detailed sectional view of the face plate 8. Number 9 denotes a fluorescent element and 10 is an anode composed of an aluminum layer. When the cathode 2 is heated, an electron beam is released, and passes through the electron beam controlling electrode group, and collides against the anode 10 to illuminate the fluorescent element 9, thereby forming an image. However, when an electron beam is irradiated to the anode of the conventional flat plate type electron beam display device, part of the electron beam is reflected by the anode and come back to the cathode side. The reflected electrons are returned back by action of high electric field applied between the cathodes and anodes for accelerating electron beam, and again dived into the anode. These reflected electrons cause dim lits in the surrounding area of the electron beam irradiation point, which is called "halation". In particular, when the anode voltage is raised, the energy of the reflected electron is increased, and this phenomenon becomes more serious. This phenomenon was a serious problem for image performance because the image contrast is lowered and the sharpness is sacrificed. In order to reduce the halation, it has been proposed that a shadow mask is disposed in front of the anode electrode to trap electrons reflected from the surface of the anode electrode layer, thus preventing returning the electrons back into the anode electrode layer. However, the formation of the shadow mask makes the structure complicated and makes the process for producing the display device complicated. It is also known from EP-A-0 446 878 to provide carbon particles 11 on the aluminium layer 10, as can be seen from Fig. 8. This carbon particle layer 11 suppresses the reflection of electrons. However, such carbon particles were deposited in the form of substantially spherical form, and it was found that such spherical carbon particles do not have sufficient bonding properties in connection with the aluminium layer 10. Accordingly, such carbon particles could become loose, so that these loose parts could contaminate the display device. It is therefore an object of the invention to avoid disadvantages, and to provide a display device in which the carbon particles are firmly fixed to the aluminium layer. In accordance to the invention, the carbon layer is prepared from graphite particles having plate shape, and having a thickness sufficient to prevent returning electrons reflected in said aluminium anode layer by collision of electron beam with the aluminium anode layer back into said face glass. Preferable embodiments are defined in the dependent claims, and particularly as follows. A coating amount of the graphite particles can be expressed by graphite weight per unit area (µg/cm 2 ) and preferably is within the range of 20 to 220 µg/cm 2 , more preferably 20 to 150 µg/cm 2 , most preferably 30 to 120 µg/cm 2 . If the coating amount is less than 20 µg/cm 2 , the preventing effects of halation reduce. If it is more than 220 µg/cm 2 , transmittance of the electron beam is deteriorated. It is further preferable that a thickness of the carbon layer should be more than the thickness of the aluminum anode layer. The carbon layer is prepared from plate-like graphite particles. They are coated on the aluminum anode layer closely packed with little space, which does not deteriorate transmittance of the electron beam and which effectively prevent returning the reflected electrons (or back scattered electrons) back into the aluminum anode. The plate-like graphite particles preferably have a plate ratio (a ratio of longest diameter / shortest diameter) of at least 10/1, more preferably 15 / 1. It is also preferred that the graphite particles have an average particle size of not more than 2 µm, more preferably not more than 1.5 µm; the average particle size being calculated in terms of spherical particles. It is preferred that the plate-like graphite particles are printed on a suitable substrate and then transferred onto the aluminum layer 20. This printing and transferring combination method effectivly reduces stress which occurs in a large-area carbon layer formed by spattering and evaporating methods. The fluorescent element layer may be in a stripe form and be alternately disposed with a black substance layer. Gas vent holes may be preferably formed in the carbon layer, and preferably the gas vent holes should be formed corresponding to the black substance layer among the fluorescent materials. A process for producing the electron beam display device of the invention comprises the steps of laminating a fluorescent element, an aluminum layer, and a carbon layer on the inner surface of a face glass in this order. The aluminum anode layer should have a rough surface on the fluorescent element layer. The aluminum anode layer having rough surface may preferably be prepared by preliminary forming an aluminum layer on a substrate film by any method, rubbing the free surface to form roughness on the surface, and then transferring the aluminum layer on the fluorescent element layer with facing the rough surface to the fluorescent element layer. Fig. 1 is a perspective sectional view of a display device in which the invention can be used. Fig. 2 is a magnified sectional view of a fluorescent element part. Fig. 3 is a process chart of aluminum transfer. Fig. 4 is a sectional structural diagram of gas vent holes of a fluorescent element. Fig. 5 is a magnified sectional view of the fluorescent element part in an embodiment of the invention. Fig. 6 is a relative diagram of graphite particle layer and relative brightness. Fig. 7 is a magnified sectional view of a conventional fluorescent element part. Fig. 8 is another magnified sectional view of a conventional fluorescent element part. Fig. 1 shows the principle of a known flat plate type display device using electron beams. Electrodes are disposed in a vacuum container not shown in the drawing, and number 1 is a back electrode, and 2 denotes a plurality of linear cathodes. Number 3 is an electron beam focusing electrode, 4 is a modulation electrode, 5 is an electron beam focusing electrode, 6 is a horizontal deflecting electrode, 7 is a vertical deflecting electrode, 8 is a face plate, and 12 is an electron beam. Fig. 2 is a detailed drawing showing a sectional laminate structure of the face plate. Number 9 is a fluorescent element layer, prepared from fluorescent particles having a particle size of about 5 µm, which generally has a thickness of about two fluorescent particles. The fluorescent element is formed in a stripe of R, G and B colors with an intermediate black layer 19 as shown in Fig. 4. Number 20 denotes an anode composed of an aluminum layer having a thickness of about 200 nm. The aluminum anode layer 20 has a roughness of about 50 nm on the side of the fluorescent element. As shown in Fig. 3, the aluminum anode layer 20 is formed by preliminary forming an aluminum layer on a substrate, forming roughness by rubbing and the like on the free surface, and then transferring it on to the fluorescent element layer 9 from the substrate. Number 21 is a carbon layer, which is formed by evaporating or sputtering method. The layer thickness can be from about 300 nm to about 1000 nm, but is not limited thereto, and an optimum layer thickness is set depending on the degree of acceleration voltage and back scattering of electron beam. By increasing the thickness of aluminum layer, the reflected electrons from the fluorescent element particles are decreased, but the transmission of electron beam is also decreased, which gives rise to another problem of lowering of brightness. Accordingly, by increasing the thickness of the carbon layer which has relatively high transmittance, reflection when electron beam is collided with the carbon layer is decreased, and reflected electrons from the fluorescent element particles can be decreased at the same time. Moreover, by forming fine roughness on the aluminum layer surface 20 of the fluorescent element side, the reflected (scattering) beam from the fluorescent element can be again scattered by the rough surface of the aluminum layer 20 to suppress re-collision into the aluminum layer 20, thereby substantially decreasing the electron beams returning reversely through the aluminum layer 20. As shown in Fig. 4, tiny holes 22 may be formed in the aluminum layer 20 and carbon layer 21 at positions corresponding to the black layers 19 of the fluorescent element part. As a result, swelling of the aluminum layer 20 due to gas when baking the fluorescent element can be prevented. Formation of gas vent holes 22 on the black layers 19 is effective for avoiding the problem of reflected electron beam from the fluorescent element particles. The electron beam emitted by heating from the cathode 2 passes through the electron beam control electrode group, and impinges against the anode 20 to illuminate the fluorescent element 9 to form an image, but the back scatter (reflected) electrons of the fluorescent element part is substantially decreased, thereby realizing a display device of excellent image quality free from image deterioration due to halation. Fig. 5 shows an embodiment of the invention. In Fig. 5, number 8 denotes a face plate, 9 is a fluorescent element layer, 10 is an aluminum layer, and 30 is a carbon layer formed from plate-like graphite particles. Table 1 shows the unevenness of thickness of carbon atom layer and degree of halation by varying the plate ratio and particle size of graphite particles used in the carbon atom layer of the embodiment. The adhesion strength of graphite particle layer is also shown in the table. As is understood from the table, graphite particles having a low plate ratio are generally large in particle size, and the unevenness of thickness of carbon atom layer tends to be greater. In particles lower in plate ratio and smaller in particle size, relatively excellent properties are shown. However, in such graphite particle layer, the graphite adhesion strength is weak, and a problem in reliability may be caused. Comprehensively judging from the table, as the graphite particles to be used in the carbon atom layer, fine graphite particles having a plate ratio of 1:10 or more and a particle size (calculated in terms of spherical particle) of 2 µm or less are found to be preferred. Graphite plate ratio Mean particle size (µm) Degree of thickness unevenness Degree of halation Adhesion strength of graphite particles Example 1 1:15 1.5 Small Small Strong Example 2 1:20 1.2 Small Small Strong Example 3 1:30 1.0 Small Small Fairly strong Example 4 1:35 0.5 Small Small Very strong Example 5 1:5 3.0 Large Large Weak Example 6 1:8 2.5 Large Large Weak Example 7 1:15 2.5 Medium Medium Medium Example 8 1:8 1.5 Small Small Weak Fig. 6 shows the display brightness and halation by varying the amount of graphite particles to be laminated on the carbon atom layer in the embodiment. When the amount of graphite particles is less than 20 µg/cm 2 per unit surface area, halation suppression effect is hardly recognized. If exceeding 220 µg/cm 2 per unit surface area, to the contrary, the display brightness is extremely lowered. To satisfy the two contradictory properties of brightness and halation, hence, it is required to define the graphite content in a range of 20 to 220 µg/cm 2 . As described herein, according to the invention, by eliminating halation due to re-collision of back scatter (reflected) electrons in the fluorescent element part of the display device, a display device of high contrast and excellent image quality may be achieved.

Claims: An electron beam display device comprising a face glass (8) on which an image is formed, a cathode (2) for emitting an electron beam, a fluorescent element layer (9) present on said face glass (8) with facing said cathode (2), to which the electron beam is directed to emit light for forming an image on said face glass (8), an aluminium layer (10) as an anode, present on said fluorescent element layer (9), and a carbon layer (30) present on said aluminium layer (10), characterized in that said carbon layer (30) is prepared from graphite particles having plate shape, and having a thickness sufficient to prevent returning electrons reflected in said aluminium anode layer by collision of electron beam with the aluminium anode layer (10) back into said face glass (8). An electron beam display device according to claim 1 wherein said plate-like graphite particles have a plate ratio (a ratio of longest diameter / shortest diameter) of at least 10/1. An electron beam display device according to claim 2 wherein said plate-like graphite particles have an average particle size of less than 2 µm; the average particle size being calculated in terms of spherical particles. An electron beam display device according to claim 1 wherein a coating amount of said graphite particles is within the range of 20 to 220 µg/cm 2 . An electron beam display device according to claim 1 wherein a thickness of the carbon layer (30) is more than the thickness of the aluminum anode layer (10). An electron beam display device according to claim 1 wherein said fluorescent element layer (9) is in a stripe form and is alternately disposed with a black substance layer. An electron beam display device according to claim 1 wherein the carbon layer (10) and/or the aluminum layer (10) have gas vent holes. An electron beam display device according to claim 1 wherein said aluminum anode layer (10) has a rough surface on the fluorescent element layer (9).

Inventors: ISHIKURA YASUHISA, NISHIMURA YUTAKA, NONOMURA KINZO, YAMAZAKI FUMIO, ISHIKURA, YASUHISA, NISHIMURA, YUTAKA, NONOMURA, KINZO, YAMAZAKI, FUMIO
Applicants: MATSUSHITA ELECTRIC IND CO LTD, MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
Application year: 1994
Main classification: H01J29
IPC codes: H01J29