LASER MACHINED REPLICATION TOOLING

Abstract: The invention relates to a method of manufacturing a replication master tooling article suitable for manufacturing replicated articles by machining a substrate surface with laser energy to produce a plurality of geometric structures in the substrate, the geometric structures having side surfaces extending from the surface of the substrate into the substrate.

Description: LASER MACHINED REPLICATION TOOLING Field of the Invention The invention relates to replication tooling. In particular, the invention relates to laser machined replication tooling useful for production of structured articles. Background of the Invention Replication tooling has been produced by several different techniques. These techniques include, for instance, machining and chemical processing. Machining is accomplished by cutting with a stylus or microdrilling into a substrate. Devices which accomplish such machining are either manually, mechanically or electronically controlled. These devices are capable of producing surfaces with optical grade precision, depending upon their quality. U.S. Patent No. 4,938,563 (Nelson et al.) discloses the use of a diamond stylus for cutting into a flat metal surface of a master tool or mold. U.S. Patent No. 4,959,265 (Wood et al.) discloses the use of a microdrill to form the mold for a pressure-sensitive adhesive tape fastener backing. U.S. Patent No. 5,077,870 (Melbye et al.) relates to the use of a microdrill to form a metal mold used to produce mushroom-type hook strips for a mechanical fastener. These methods are considered slow for all but the simplest replications. In addition, replacement of the stylus and drill bits is expensive and adds to the cost of the machining. Another method for the production of microstructured tooling relates to the use of sharpened or shaped structures, such as pins or rods, being forced into a relatively soft medium, such as described in U.S. Patent No. 3,235,438 (Wisotzky) . U.S. Patent No. 3,235,438 also illustrates the traditional, multi-step approach to the production of a microreplication molding or tooling. A primary negative mold is prepared by forcing the structures into the relatively soft medium. Intermediate positive master molds are made from the negative primary mold and are then joined together to form a large positive mold. A large negative mold is then produced from the large positive mold, which is then used to produce replicated articles. Preparation of the final negative mold requires significant time and cost. Some microreplication applications require optical quality surfaces, which necessitates the use of costly production devices. However, there is a growing number of applications which do not require optical quality tooling since a precisely manufactured article surface is not required. Lasers have been used to machine some finished articles, such as filters, award plaques, rubber stamps, and stencils, but lasers have not been used to make molds or replication toolings. Summary of the Invention The invention relates to a method of manufacturing a microreplication master tooling suitable for manufacturing replicated articles by machining a substrate surface with a laser light source to produce at least one geometric structure having side surfaces extending from the substrate surface into the substrate. The invention also relates to a method of manufacturing a microreplication master tooling suitable for manufacturing replicated articles by machining a flexible, unitary substrate surface to produce at least one geometric structure having side surfaces extending into the substrate, such that the substrate provides structural means for producing articles replicated from the master tooling. The invention further relates to a method of manufacturing a microreplication master tooling suitable for manufacturing replicated articles by machining a flexible substrate surface with a laser light source to produce a plurality of geometric structures having side surfaces extending from the substrate surface into the substrate. The invention also relates to a method of manufacturing an article from a microreplication master tooling by machining a flexible tooling substrate with a laser light source to produce at least one geometric structure in the flexible substrate. A moldable material is then applied to the substrate surface and the at least one geometric structure. The moldable material is solidified to produce a replicated article of the tooling, and the replicated article is removed from the tooling. The invention further relates to an article that is manufactured by the method. In addition, the invention relates to an article replicated from the article which was manufactured. The invention relates to an article which may be used as a replication master tooling suitable for replicating microstructured arrays which includes a flexible substrate having a plurality of geometric structures extending into the substrate which were formed by a laser light source. Brief Description of the Drawings The invention will be further explained with reference to the drawings wherein: Figure 1 is a perspective schematic view of a microreplication tooling manufacturing system; Figure 2 is a diagram of a method of extruding the moldable material onto a master microreplication tooling manufactured by the system of Figure 1; Figure 3 is a cross section view of the master microreplication tooling manufactured by the system in Fig. 1, showing a partially removed moldable material which was applied to the surface of the tooling to produce a replicated article of the tooling; Figure 4 is a cross section view of a microreplication master tooling manufactured by the system of Fig. 1 where the geometric configuration is an angled tubular structure; Figure 5 is a side section view of the replicated article produced from a microreplication tooling having a large truncated cone or tubular suction cup configuration; Figure 6 is a side section view of the replicated article produced from a microreplication tooling having a small truncated cone or tubular suction cup geometric configuration; Figure 7 is a top view of the geometric structures protruding from the replicated article shown in Fig. 5; Figure 8 is a top view of the replicated article shown in Fig. 6; Figure 9 is a front section view of the replicated article produced from a microreplication tooling having an angled multiple protrusion geometric configuration; Figure 10 is a side section view of the replicated article shown in Fig. 9; Figure 11 is a top view of the replicated article shown in Figs. 9 and 10; Figure 12 is a front section view of the replicated article produced from a microreplication tooling having a wide angled/separated multiple protrusion geometric configuration; Figure 13 is a side section view of the replicated article shown in Fig. 12; Figure 14 is a top view of the replicated article shown in Figs. 12 and 13; Figure 15 is a front section view of the replicated article produced from a microreplication tooling having a "crow's feet" arrangement; Figure 16 is a side section view of the replicated article shown in Fig. 15; Figure 17 is a top view of the replicated article shown in Figs. 15 and 16; Figure 18 is a front section view of the article produced from a microreplication tooling having an acute angled chevron configuration; Figure 19 is a side section view of the replicated article shown in Fig. 18; Figure 20 is a top view of the replicated article of Figs. 18 and 19 where the chevrons are independent and interconnected; Figure 21 is a top view of the replicated article where the acute angled chevrons are interconnected; Figure 22 is a top view of the replicated article where the chevrons are oriented in different directions; Figure 23 is a front section view of the article produced from a microreplication tooling in which the chevron geometric structures have a substantially perpendicular configuration; Figure 24 is a side section view of a replicated article shown in Fig. 23; Figure 25 is a top view of the replicated article of Figs. 23 and 24; Figure 26 is a side section view of the replicated article produced from a microreplication tooling in which the geometric structure is a single protrusion; Figure 27 is a top view of the replicated article of Fig. 26; Figure 28 is a front section view of an article produced from a microreplication tooling in which the geometric structures are angled protrusions at differing heights; Figure 29 is a side section view of a replicated article shown in Fig. 28; and Figure 30 is a top view of the replicated article of Figs. 28 and 29. These figures, which are idealized, are not to scale and are intended to be merely illustrative and non-limiting. Detailed Description of Illustrative Embodiments The invention relates to replication tooling articles which are used to replicate non-optical quality structured surfaces. The replication toolings of the invention may be used in both micro and macro applications. It should be understood that any reference to microreplication master toolings throughout this application may be interchanged with macroreplication master toolings. Figure 1 illustrates microreplication master tooling manufacturing system 30. Microreplication tooling system 30 generally comprises a laser light source 32 and a substrate 34 positioned on a preferably movable surface, such as a table 36 or other suitable support structure. Table 36 may be moved in a five axis orientation, X,Y,Z and rotations, by a control means 38, such as a computer, to position substrate 34 in different positions and locations under laser light source 32. Alternatively, the laser beam from laser light source 32 can also be moved in a five axis orientation. The motion of table 36 under laser light source 32 produces different geometric configurations within substrate 34. Laser light source 32 may be any type of laser that interacts well with substrate 34. A carbon dioxide (C0 2 ) laser is preferred since C0 2 lasers couple successfully with a multitude of substrates, and are low in cost. Preferably, a 10 watt to 1000 watt C0 2 laser, more preferably, a 50 to 300 watt C0 2 laser, is utilized. However, other lasers or high energy sources which will couple with the substrate material, such as an excimer laser, may be utilized. Parameters such as pulse spacing, power level, pulse length, mode, wavelength, cavity pressure, feed rate, gas mixture, choice of lens, and standoff distance, or focus, of laser light source 32 may be varied depending on the effect or design desired in substrate 34. Laser light or energy from laser light source 32 rapidly and efficiently machines, i.e., cuts or drills, cavities into substrate 34 at varying depths suitable for the desired end use of master replication mold or tooling 44. Laser light source 32 may be manually, electronically, or automatically controlled by control means 40, such as a computer. Control means 40 may be the same control means used to move table 36, or may be a separate means. The unfocused laser light may be passed through focusing means 42 in laser light source 32 to substrate 34. Focusing means 42 of laser light source 32 controls or shapes the emitted laser energy toward substrate 34. Focusing means 42 preferably accommodates varying focal lengths of the laser light. For example, a 1.5 inch (3.81 cm) asphere lens may be utilized. Substrate 34 is utilized as the microreplication master mold or tooling article 44 for creating replicated articles comprising microstructured arrays or surfaces. Substrate 34 preferably comprises any suitable material which can withstand varying temperatures, pressures, solvents, chemicals, exposure to melt based delivery of materials, and exposure to radiation during curing involved in the manufacture of the article produced using master tooling 44. In addition, master tooling substrate 34 is preferably durable, deformable, has good release capabilities, can satisfactorily receive laser light from laser light source 32, and may be flexible. Preferred substrates 34 comprising master tooling 44 are rubber materials which are thermally stable over time, and more preferably, comprise thermoset materials which have been cross- linked. Most preferred substrates are polysiloxane (silicone) rubbers of different grades conforming to ASTM D-2000 Classification FC, FE, GE, such as are available from General Electric Corporation. Other materials may also be utilized for substrate 34 for master tooling 44, including deformable and flexible materials such as products marketed under the tradename TEFLON by E.I. DuPont de Nemours St Co. , natural rubber, fluoro-elastomers, and thermoplastics; and materials such as wood, ceramics, glass and different metals including steel, copper, lead, aluminum, and the like. These substrate materials may be coated with or have incorporated within a release agent to aid in the removal of the replicated articles. Laser energy has been found to interact with these substrates. Although the resulting geometric structures which result from the machining of these substrates may not be as well defined as the geometric structures in the silicone rubber substrate, the structures may be acceptable for many non-optical quality applications. In addition, the removal of substrate material from tooling 44 made of these materials may not be as readily and completely accomplished as from a silicone rubber substrate. Substrate 34 may be of varying shapes and sizes, depending on the desired use of microreplication master tooling 44. For instance, substrate 34 may comprise a substantially planar plate, as shown in Fig. 1, or may be wrapped around a drum or cylinder, as shown in Fig. 2. Preferably, microreplication master tooling 44 is an integral, single piece substrate 34 which does not need to be pieced together prior to use as a replication master mold. Also, microreplication master tooling 44 may comprise a single layered substrate 34 or a multi- layered substrate 34 comprising one material or a combination of materials in the layers. The surface 46 of substrate 34 may be planar or non-planar, including undulating and pre-grooved surfaces, and is substantially continuous. The non-planar surfaces may also have been laser machined with larger, macro features easily discernible to the naked eye. Preferably, surface 46 of substrate 34 is substantially planar. Referring to Figure 1, laser light from laser light source 32 is used to machine substrate 34 to produce microreplication master tooling 44. Additional machining or etching steps may also be done on master tooling 44. Referring to Fig. 3, surface 46 of substrate 34 is machined by laser light source 32 to produce wall portions defining one or more cavities 48 recessed from substantially continuous surface 46. Cavities 48 include various geometric structures having side surfaces which extend from surface 46 into substrate 34. Laser light may contact substrate 34 once to produce one or more cavities 48, or may strike the same cavity 48 multiple times to produce a variety of geometric shapes. The geometric structures may be canted at different angles relative to surface 46 of tooling 44, depending on the relative positions of the laser beam and surface 46 of substrate 34. In addition, the laser beam may be split to produce varying geometric shapes in substrate 34 and/or redirected to intersect substrate 34 at different angles relative to substrate 34. Alternatively, the laser light may be masked to control the energy profile reaching the substrate. Laser light may be used to machine cavities 48 in substrate 34, or may machine all the way through substrate 34. The ability to move substrate 34 under laser light and select or program laser light source 32 for different variables produces varied high feature density patterns, grids, logos, designs and the like within substrate 34. In general, the geometric structures produced in master tooling 44 may be uniform in height, as illustrated in Fig. 26, or may be of multiple differing heights, as shown in Fig. 28, depending on the desired end use of articles produced by tooling 44. Diameters of the geometric structures adjacent surface 46 of substrate 34 and the thicknesses between the geometric structure outer and inner surfaces (i.e., measured in a direction parallel to the axis of the protrusions) also vary, but are of such dimensions suitable for the desired use of tooling 44. Further, the density of the geometric structures in substrate 34 may vary depending on the use of replicated articles produced by tooling 44. Microreplication master tooling manufacturing system 30 is particularly advantageous for manufacturing high feature density toolings 44 at a fast rate which have a large number of detailed or shaped geometric structures per given area. Referring to Figure 3, a moldable material 50 is applied to a first surface 46 of microreplication master tooling 44 by, for example, extrusion or cast molding to create a replicate or article 52 of the microstructured surfaces 46 of microreplication tooling 44. In preferred embodiments, the adhesion of material 50 to tooling 44 is less than the cohesion at the time of removal of material 50 from the tooling. Referring to Fig. 2 and as discussed in more detail in U.S. Patent No. 5,077,870 (Melbye et al.), a feed stream 54 of a moldable material, such as a thermoplastic resin, is fed into an extruder 56 from which a heated resin melt is fed through a die 58 to a rotating cylindrical microreplication mold 60. Alternatively, the moldable material melt may be applied to a planar substrate, such as substrate 34. Moldable material 50 flows into mold cavities 48, is pressed into tooling molds 44, 60, and is hardened by cooling and/or curing material 50. Material 50 is applied to surface 46 of substrate 34 until it is at a thickness suitable for the desired replicated article 52. Material 50 may be applied in a uniform sheet to substrate 34, or may be applied in different configurations, so as to have, for instance, ribs or other structures. Alternatively, replicated article 52 may be produced by compression molding, as disclosed in Examples 1-4. Substantially any moldable material 50 may be used to produce replicated article 52. Preferred moldable materials 50 are thermoplastic resins including polyolefins, such as polypropylene and polyethylene, polyurethane, polyvinyl chloride (PVC) , polyesters, and polyamides such as nylon. The thermoplastic resin may also comprise blends, including polyethylene and polypropylene blends, co-polymers such as polypropylene impact co-polymers, multi-layer films, and co- extrusions. Additives such as plasticizers, fillers, pigments, dyes, anti-oxidants, release agents and the like may also be incorporated into moldable material 50. Replicated article 52 is removed from microreplication master tooling 44 after moldable material 50 has hardened, as shown in Fig. 2, so as to maintain the integrity of the geometric structures. Geometric structures similar to, or mirror images of, the cavities and geometric structures in microreplication master tooling 44 protrude from the surface of replicated article 52. Alternatively, replicated article 52 may be removed from microreplication master tooling prior to complete hardening of moldable material 50 to produce other desired shapes and properties. If desired, the geometric structures in the replicated article may be subjected to post-processing steps to achieve varied configurations, such as bent over hooks, mushroom-type caps, or other shapes. Figure 4 illustrates a cross section view of tooling 44 where the geometric structure is an angled tubular shape 65 having side surfaces 67, 69 and bottom surface 71 extending between side surfaces 67, 69. Two or more angled tubular shapes 65 may intersect surface 46 of substrate 34 at different angles, including angles not feasible or contemplated by any other replication process. The geometric structures recessed into substrate 34, and those which protrude from each replicated article 52, may include a wide variety of shapes, designs and patterns. Side surfaces of the geometric structures may intersect surface 46 of substrate 34 at varying acute angles determined to be suitable for different end uses of replicated article 52. Since replicated article 52 has essentially identical geometric structures as tooling 44, the geometric structures will be discussed with reference to replicated article 52. Fig. 3 illustrates a cross section view of master tooling 44 and replicated article 52 having conical or pyramidal geometric structures 62 formed by side surfaces 64, 66. Side surfaces 64, 66 taper inwardly and away from surface 46 into substrate 34. The angle at which side surfaces 64, 66 intersect surface 46 of tooling 44 may vary, depending on the size of pyramidal or conical geometric structure 62 desired. Figures 5 and 6 show a side section view of replicated article 52, and Figures 7 and 8 depict a top view of article 52, respectively, in which geometric structure 68 has a suction cup or truncated cone or tubular configuration. As shown in Figures 5-8, side surface 70 of suction cup geometric configuration 68 is substantially annular and continuous, and is adjacent bottom surface 73. Side surface 70 may be of varying heights, as illustrated in Figures 5 and 6. As side surface 70 of suction cup 68 increases in height, as in Figure 5, side surface 70 tapers outwardly in a direction away from surface 72 of article 52, such that the diameter d at the top surface 74 of suction cup 68 is larger than the diameter d, of the base 76 of suction cup 68, as seen in Figure 7. For smaller suction cups 68, as seen in Figures 6 and 8, top surface 74 is approximately the same diameter as base 76, although this may vary. Side surface 70 may include other configurations, such as elliptical, and rectangular. Referring to Figures 9-14, a geometric configuration having a plurality or grouping of angled protrusions or pins is illustrated. Figures 9 and 12 illustrate a front section view of angled protrusions 78, 80 which extend from replicated article surface 72 at selected, different acute angles, and which may be of varying dimensions. Protrusions 78, 80 include side surfaces 82, 84, 86, 88, as shown in Figures 9 and 12. Figures 10 and 13 show a side section view of angled protrusion 78 extending from surface 72 of replicated article 52. Referring to Figures 11 and 14, a top view of protrusions 78, 80 extending at different angles from surface 72 of replicated article 52 is shown. Referring to Figures 15-17, a front section view of replicated article 52, a side section view of replicated article 52, and a top view of replicated article 52, respectively, configured in a "crow's feet" arrangement is illustrated. Pins or protrusions 90, 92, 94 extend from surface 72 at selected acute angles to surface 72 of replicated article 52. Protrusions 90, 94 are generally at a selected acute angle relative to surface 72 of replicated article 52. Protrusion 92 extends in a substantially perpendicular orientation to surface 72 of replicated article 52. The dimensions of protrusions 90, 92, 94 may vary, and protrusions 90, 92, 94 may intersect surface 72 of article 52 at varying angles. Each protrusion 90, 92, 94 comprises side surfaces 96, 98, 100, 102, 104, 106. Figures 18-25 illustrate an article 52 in which the protruding geometric structures have a chevron configuration. Figures 18 and 23 show a front view of replicated article 52. Figures 19 and 24 illustrate a side section view of article 52. Figures 20-22 and 25 illustrate a top view of article 52. Chevrons 108 are formed by the intersection of side surfaces 110, 112 at leading edge 114. Side surfaces 110, 112 intersect surface 72 of article 52 at varying acute angles. Side surfaces 110, 112 of chevrons 108 may be at a selected acute angle to surface 72 of article 52, as seen in Figures 18-22, or may be almost perpendicular to surface 72 of article 52, as seen in Figures 23-25. As shown in Figures 20-22, chevrons 108 may be may be interconnected and independent on the same replicated article 52, may be interconnected, and/or oriented in multiple directions, and of varying dimensions. Referring to Figure 26, a side section view of replicated article 52 is shown. Figure 27 shows a top view of article 52 in which the geometric structure is a single upwardly extending protrusion or pin 116 formed in a row. Pin 116 may be of varying dimensions, and has side surfaces 118, 120 which intersect surface 72 of article 52 at varying acute angles. Alternatively, a single continuous ridge or structure 115 may be produced in replicated article 52, as shown in Figure 27. Figure 28 is a front section view of a replicated article having angled protrusions 122 extending at selected acute angles from surface 72 of article 52. Figure 29 is a side section view of article 52. Figure 30 is a top view of article 52. Protrusions 122 include at least side surfaces 124, 126. As illustrated in Figures 28-30, protrusions 122 may be of varying dimensions on the same article 52 so as to produce a sculptured surface effect on article 52. As can be seen in Figures 3-30, the varied geometric structures may range from conical to tubular to annular to angular in shape, and may comprise a single or multiple protrusion configuration. In addition, the dimensions of the geometric structures may vary depending on the end use of the replicated article. In addition, any geometric structures produced in tooling 44 or replicated article 52 may be independent from one another, interconnected, in rows, and/or oriented in different or multiple directions. Also, the geometric structure protrusions on replicated article 52 may be uniform in height, or may be at varying heights through out replicated article 52. Many varied geometric patterns and configurations determined by the selected pulse length, power level, pulse space, wavelength, feed rate, gas mixture, cavity pressure, mode, choice of lens, and focus of laser light source 32 are within the contemplation of this invention. Articles replicated from microreplication master tooling 44 may be used in a wide variety of applications. For instance, the replicate or article 52 may be used as a mechanical fastener for use in the disposable soft goods industry. In addition, a pressure sensitive adhesive may be applied to surface 72 of replicated article 52 to create a mechanical-adhesive fastener, as shown in U.S. Patent No. 4,959,265 (Wood), for the disposable soft goods industry, such as disposable diapers, adult incontinence products, and feminine hygiene products. In operation, substrate 34 is positioned on table 36. The desired pulse length, power level, pulse spacing, lens system, mode, wavelength, cavity pressure, feed rate, gas mixture, and focus for laser light source 32 are selected and preferably programmed into control means 40. Laser light from laser light source 32 is then emitted. Control means 38 positions substrate 34 under laser light source 32, moving substrate 34 into different positions and orientations with respect to laser light source 32. Patterns of desired geometric structures are machined into substrate 34 using laser energy. Depending on the use of microreplication master tooling 44, the entire surface 46 of substrate 34 may be machined by laser light or only selected areas of substrate 34 may be machined. After fabrication of microreplication master tooling 44, moldable material 50 is applied to surface 46 of tooling 44. Moldable material 50 covers the surface 46 of master replication tooling 44, and flows into cavities 48 in tooling 44 and around the geometric structures contained within cavities 48. After moldable material 50 hardens or solidifies to the desired degree, replicated article 52 is removed from contact with microreplication master tooling 44. If cylindrical mold 60 is used, replicated article 52 may be continually removed from mold 60. Post processing of replicated article 52 may be done to produce a variety of shaped hook, mushroom, or the like configurations. The replicated articles produced may also be used to produce additional, multi-generational replicated articles. Examples The invention will ve further explained by the following illustrative examples. EXAMPLES 1-3 A substrate comprising an approximately 1140 micron (45 mil) thermoset polysiloxane rubber conforming to ASTM D-2000 Classification FC, FE, GE and a 0.64 centimeter (1/4 inch) thick number 304 steel plate was obtained from Industrial Molded Rubber, Inc. After grinding the polysiloxane layer down to an approximate 0.076 cm (30 mil) caliper, the siloxane surface was exposed to an 80 joule/sec. (80 watt) C0 2 laser to produce three separate 5 cm by 10 cm (2 inch by 4 inch) machined areas with 1550 holes per cm 2 (10,000 holes per square inch) under the conditions indicated in Table I. The laser focus was set to machine the smallest entrance hole going into the siloxane rubber surface. In Example 1, the laser machined the substrate at the rate of about 140 cavities per second. In Examples 2 and 3, the laser machined the substrate at a rate of about 240 cavities per second. TABLE I PULSE CAVΠΎ MEASURED TOOLING EXAMPLE FEED RATE LENGTH SPACING PRESSURE POWER TIME meterg/min (millisecond) microns Pascals (W) (see) in/min mils millibar-; 240 1500 1 * 100 1.0 9.5 15 47 569.6 5.0 240 1500 200 0.1 9.5 15 43 332.2 5.0 240 1500 200 0.1 9.5 15 31 332.2 * Note: Example 1 was machined through to steel plate. The tool in each of Examples 1-3 was replicated with a polypropylene impact co-polymer resin (Shell Chemical 7C50) via compression molding in a Tetrahedron Associates, Inc. MTP programmable platen press using the program conditions set forth in Table II. TABLE II RAM FORCE DWELL DWELL STEP TEMP OS TEMP RATE FORCE RATE TEMP(°F) TD E(scc) β F "Ctmin ketmin 'Ftmin lb Ib/min 175 110 880 110.000 1 350 200 400 50,000 OFF 60 125 no 55.000 440.000 2 350 200 25,000 200,000 OFF 60 M 110 55.000 440.000 3 145 200 25,000 200,000 OFF 15 4 END Upon completion of the cycle, the quenched replicated article was stripped from the plate and cross-sectioned for profile measurement using scanning electron microscopy (SEM) to determine the shape and the dimensions of the machined holes, as reported in Table III. TABLE III EXAMPLE HEIGHT BASE TIP SHAPE (microns) (microns) (microns) 1 773 190 102 tubular 2 182 159 23 conical 3 140 123 21 conical EXAMPLE 4 A 0.41 cm (160 mil) substrate was made from silicone conforming to ASTM D-2000 Classification FC, FE, GE. The silicone surface was exposed to a 250 joule/sec. (250 watt) C0 2 laser (82% He, 13.5% N 2 , 4.5% C0 2 ) under the conditions set forth in Table IV. TAB: LE ΓV EXAMPLE LENS STAND¬ POWER FEED PULSE CAVΠΎ SPACING FOCAL OFF Joule/sec RATE LENGTH PRESSURE microns LENGTH cm/min (m. sec.) (torr) mil cm in/min in 9.53 406 635 4 3.75 0 250 160 0.3 19 25 9.53 406 890 5 5 3.75 0 260 150 0.3 18 35 A mirror image replicate was made of the master tool by pressing three sheets of 125 micron (5 mil.) thick film of Shell Chemical WRS 6-166 polypropylene random co-polymer resin in an MTP programmable platen press as in Examples 1-3 under the conditions set forth in Table V having the dimensions and properties set forth in Table VI. TABLE V TEMP TEMP MOLDING FORCE DWELL DWELL RATE PRESSURE RATE TEMP(°F) TIME(βec) desrces/min ke/min lbs./min STEP 1 170 β C 110 β C 2.1 x 10 4 Pat 110.000 OFF 60 350 β F 200 β F 3 lb/inch 2 50,000 STEP 2 175 β C 110 β C 1.4 x 10* Pa/ 440.000 OFF 60 350 β F 200 β F 200 lb/inch 2 200,000 STEP 3 63 β C 110 β C 1.4 x 10* Pat 440.000 OFF 15 145 β F 200 β F 200 lb/inch 2 200,000 STEP 4 END TABLE VI EXAMPLE HEIGHT BASE DENSITY SHAPE microns WIDTH nins/cm 2 mil microns pins/in 2 ) mil 1630 210 250 Tubular 64.3 8.2 1600 ≤IO 190 ,126 Tubular 20 7.5 816 EXAMPLE 5 A silicone tool substrate was exposed to a 260 joule/sec (260 watt) C0 2 laser under the conditions set forth in Table IV. A mirror image replicated article was made of the master tool by extruding an impact polypropylene resin (Shell Chemical SRD7-463) onto the mold at a delivery temperature of 290°C (550°F) . The resin was pressed into the mold using a roller pressure of 186 pli. Physical dimensions and properties of the protrusions are reported in Table VI. There are several advantages to using the laser machined microreplication tooling of the present invention. First, laser energy can efficiently machine patterns into substrate 34 at a high speed to produce a high feature density pattern. In addition, since a one piece substrate is utilized, piecing together of numerous intermediate molds to produce the final mold is not required. Due to the high speed machining directly onto the one-piece substrate, without intermediate molds being required, significant savings in time and cost result. Use of a preferably deformable, flexible substrate, such as a silicone rubber, is also advantageous. First, silicone rubbers are readily available at a reasonable cost. Second, silicone rubber molds or toolings are deformable, which minimizes the shear, and reduces the breakage of the geometric structures as replicated article 52 is removed from microreplication tooling 44. In addition, silicone rubbers are durable and are resistant to degradation. The low energy surface of a silicone rubber mold permits easy release of the replicated article from the mold or substrate. Since the silicone mold is deformable, the laser light may do further undercutting of the mold substrate than is done with conventional methods and still have the ability to easily remove the replicated article from the mold. Laser energy is received well by silicone rubber substrates. Vaporization of the silicone rubber by laser light removes the material from the machined cavity, producing a minimum flash residue, which is easily cleaned and removed. Laser machining of the microreplication tooling is advantageous in that the molds may be produced at a high speed at a significantly reduced cost. In addition, pattern flexibility is achieved since a wide variety of geometric structures may be machined into the microreplication tooling. Further, using a laser to machine the silicone tooling provides profile flexibility in the geometric structures. In addition, entrance holes in the molding substrate which are approximately 200 microns (8 mils) in diameter with aspect ratios of approximately 8:1 have been achieved. Smaller, highly detailed shaped structures may be obtained that are not possible with current machining technologies. Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention as described herein.

Claims: What is claimed is : 1. A method of manufacturing a replication master tooling article suitable for manufacturing replicated articles, characterized in that said method comprises the steps of: a) providing a substrate having a first surface; and b) machining the first surface of the substrate with a laser light source to produce at least one geometric structure having side surfaces extending from the first surface into the substrate. 2. The method of claim 1 further characterized in at least one of the following: a) the substrate is selected from the group consisting of aluminum, lead, wood, ceramics, glass, copper, and steel; or b) the substrate is flexible. 3. A method of manufacturing a replication master tooling article suitable for manufacturing replicated articles, characterized in that said method comprises the steps of: a) providing a flexible, integral substrate having a first and a second surface; and b) machining the first surface of the substrate witha laser light source to produce at least one geometric structure having side surfaces extending from the substrate first surface into the substrate, such that the substrate provides structural means for producing articles replicated from the replication master tooling. 4. The method of claim 3 further characterized in that the substrate first surface is machined from the first surface through the second surface of the substrate. 5. A method of manufacturing an article from a replication master tooling article, characterized in that said method comprises the steps of: a) providing a flexible tooling substrate having a first surface; b) machining the first surface of the tooling substrate with a laser light source to produce at least one geometric structure having side surfaces extending from the first surface of the substrate into the substrate; c) applying a moldable material to the first surface and the geometric structures of the flexible tooling substrate; d) at least partially solidifying the moldable material to produce a replicated article of the replication tooling; and e) removing the replicated article from contact with the flexible substrate. 6. The method of any one of claims l, 3, or 5 further characterized in that the substrate first surface is machined so that a plurality of the side surfaces intersect the substrate first surface at acute angles. 7. The method of claim 6, further characterized in at least one of the following: a) the geometric structure side surfaces form a group of angled tubular structures; or b) the geometric structure side surfaces are substantially conical; or c) the geometric structure side surfaces are substantially pyramidal; or d) the geometric structures are a chevron configuration. 8. The method of any one of claims 1, 3, or 5 further characterized in at least one of the following: a) the machining produces geometric structures in which each structure comprises a bottom surface extending between the side surfaces; or b) the geometric structures are truncated cones. 9. The method of any one of claims 1, 3, or 5 further characterized in at least one of the following: a) the substrate is integral; or b) the substrate is selected from a group consisting of rubber, nylon, TEFLON, fluoro elastomers, thermoset materials, and thermoplastic materials; or c) the substrate material is cross linked silicone rubber. 10. The method of claim 6 further characterized in that the moldable material is selected from the group consisting of multi-layer films and thermoplastic resins. 11. The method of claim 10 further characterized in that the thermoplastic resin is selected from the group consisting of polypropylene, polyethylene, polyester, polyurethane, polyvinyl chloride, nylon, thermoplastic blends, co-polymers, and co-extrusions. 12. An article manufactured in accordance with the method of claims 1, 3, or 5. 13. An article which is a replicate of the article of claim 12. 14. The article of claim 13 further characterized in that the replicate is selected from the group consisting of mechanical fasteners for disposable soft goods and mechanical-adhesive fasteners for disposable soft goods including diapers, feminine hygiene products and adult incontinence products. 15. An article useful as a replication master tooling for replicating structured arrays, characterized in that said article comprises: a) a flexible substrate having a first surface; and b) a plurality of geometric structures extending into the substrate through the first surface of the substrate, the geometric structures being formed by a laser light source.

Inventors: FOX HERBERT J, HANSCHEN THOMAS P, MILLER PHILIP, MORRIS TERRY L, FOX, HERBERT, J., HANSCHEN, THOMAS, P., MILLER, PHILIP, MORRIS, TERRY, L.
Applicants: MINNESOTA MINING & MFG, MINNESOTA MINING AND MANUFACTURING COMPANY
Application year: 1994
Main classification: B23K26
IPC codes: A44B18, B23K26, B29C33, B29C35, B29C41, B29C59, B29D5