MALEIMIDE-MODIFIED HIGH HEAT ABS RESINS

Abstract: Graft copolymerized maleimide-modified, impact resistant monovinylidene aromatic copolymer compositions have substantially improved impact strength and fatigue resistance properties when the swelling index thereof is 12 or greater and when the numerical difference in maleimide monomer content as between the grafted copolymer and matrix copolymer portions thereof differ by no more than 9 percentage points from each other. Such compositions are conveniently prepared by mass, solution or mass/suspension graft copolymerization processes and by deferring the addition of at least 20 percent of the maleimide monomer ingredient to a point in the process after (and preferably only shortly after) phase inversion of the dissolved impact modifying rubbery polymer ingredient.

Description: MALEIMIDE-MODIFIED HIGH HEAT ΛBS RESINS This invention pertains generally to imoact resistant monovmylidene aromatic coDOiymer compositions sucn as those that are commonly known in the art as ABS resins. In particular, said invention pertains to rubber-modified monovmylidene copolymers which can, for example, be prepared by mass, solution or mass/suspension graft copolymerization tecnniαues and which have incomorated (that is, copolymeπzed) therein one or more N- substituted maleimide monomers for the purpose of enhancing the heat resistance (e.g., the 10 softening point, heat distortion temperature, etc.) of the resulting graft copolymer product. Maleimide-modified, impact resistant styrenic copolymer compositions are already known in the art as a general proposition. For example, in U.S. Patent 3,652,726 there are disclosed certain graft copolymers comprising a diene rubber substrate and a superstrate resin comprising acrylonitriie, N-aryl maleimide and an aromatic olefin, such as styrene. Also ■ 5 disclosed are blends of such graft copolymer with various compatible matrix resins. The reference further teaches at col . 6, 1 i ne 70, that the graft copolymers may be made by a sequential polymerization in which the monomers for the superstrate are polymerized by a free radical process: Bulk, suspension, solution, or emulsion polymerizations are all disclosed as suitable for preparing such polymers. Emulsion techniques are particularly exemplified. 0 More recently (that is, in U.S. Patent 4,808,661) there have been disclosed maleimide-modified ABS-type compositions that are prepared by continuous bulk (or mass) polymerization techniques and which are required to meet certain specified criteria and compositional characteristics in order to provide the balance of performance properties which are contemplated for the specific purposes of that patent. In particular, such patent includes 5 the requirements that: 1. the occluded and/or grafted styrene/acryionitrile/maieimide (S/AN/MI) polymer contained in or on the dispersed rubbery polymer be in the range of 50 to 100 parts per 100 parts of the rubbery polymer; 2. the amount, in weight percent based on the weight of the respective phases, 0 of maleimide in both the grafted/occluded polymer (x) and the continuous matrix phase (y) be in the 1 to 25 weight percent range; 3. the ratio of y:x be greater than 0.5 and less than 2.0; and 4. the crosslinking degree index (hereinafter also referred to as swelling index) thereof be in the range of from 4 to 1 1. 5 It has now been discovered that substantially improved properties (particularly impact strength and fatigue resistance) are obtained in maleimide-modified, impact resistant monovinylidene aromatic copolymer compositions of the sort described above wnen said compositions have or are caused to have swelling index values of 12 or greater. Such finding is considered to be especially surprising in view of the contrary teachings of U.S. Patent 4,808,661 (that is, at Col. 7, lines 41-43 thereof) to the effect that the imoact strength of such compositions is reduceα when the swelling inαex thereof exceeds 1 1. It has additionally been discovered that the impact strength of the suDject 5 maleimiαe-modified coooiymer compositions is also notably improved by ensuring that the maleimiαe monomer content as between the continuous matrix phase ("Y" m weight percent on a matrix phase weight basis) and the grafted/occluded copoiymer constituent ("X" in weight percent on a grafted/occluded copolymer weight basis) of sucn cooolymer compositions is sufficiently balanced such that the numerical difference therein (that is, the - o absolute value of X-Y) is no more than 9 weight percentage points. In light of the foregoing discoveries, the present invention in one of its aspects is a rubber-modified monovinyiidene aromatic copolymer composition which comprises: A. a continuous phase matrix copolymer comprising, in polymerized form and on a matrix copolymer weight basis, from 35 to 89 weight Dercent of a ■ 5 monovmylidene aromatic monomer, from 10 to 40 weight percent of an ethylenically unsaturated nitrile monomer, and from 1 to 25 weight percent of an N-substituted maleimide monomer; and B. dispersed within said matrix copolymer, discrete rubber particles having grafted thereon and occluded therein a rigid copolymer constituent comprising, in 0 polymerized form and on a rigid copolymer constituent weight basis, from 25 to 94 weight percent of a monovinyiidene aromatic monomer, from 5 to 40 weight percent of an ethylenically unsaturated nitrile monomer, and from 1 to 35 weight percent of a N-substituted maleimide monomer; said rubber-modified monovinyiidene aromatic copolymer composition being further characterized in 5 that it has a swelling index value of at least 12 and in that the difference between the N-substituted maleimide monomer content of the matrix phase copolymer and that of the grafted and occluded rigid copolymer constituent is 9 weight percentage points or less. In another of its aspects, the present invention resides in a process for preparing 0 an improved maleimide-containing, rubber-modified monovmylidene aromatic copolymer composition. Said process comprises the steps of: A. dissolving a rubbery polymer material in a monomer mixture comprising a monovmylidene aromatic monomer, an ethylenically unsaturated nitrile monomer and, optionally, an N-substituted maleimide monomer; 5 B. partially polymerizing the resulting solution of said rubbery polymer material in said monomer mixture; C. adding an N-substituted maleimide monomer to the partially polymerized solution of said rubbery polymer material in said monomer mixture when at least 20 weight percent of said monomer mixture has been converted from monomer to polymer; D. continuing to oolymerize the partially polymerized reaction mixture of step (C) to the desired degree of polymerization; and E. removing any unreacted monomers from the product of step 0 at elevated temperature and reduced pressure and under conditions such that the swelling index of the resulting rubber modified polymer product is 12 or greater. As has been noted above, the resulting rubber-modified copolymer compositions have improved fatigue resistance and impact strength properties relative to otherwise comparable compositions which have swelling indexes of less than 12. Said compositions also exhibit superior impact strength properties when compared to compositions which are essentially the same in all respects except for having maleimide monomer content differences of greater than 9 weight percentage points as between the matrix phase copolymer and the grafted/occluded rigid phase copolymer portions thereof. "Swelling index" as used herein provides a measure of the degree of crosslinking within the dispersed grafted rubber particles of the polymer composition of interest. It is determined for a given rubber-modified copolymer by partially dissolving 0.4 grams of the copolymer in question in 30 mml of a 70:30 volume ratio solvent mixture of toluene and methyl ethyl ketone and thereafter centrifuging the resulting mixture to remove the undissolved material from it. The undissolved material (which does not dissolve due to rubber crosslinking and which will have been caused to swell due to solvent absorption) is then weighed to determine its initial "wet" or swollen weight; dried in a vacuum to remove all of the solvent therefrom; and thereafter is weighed again to determine the dry weight thereof. The swelling index is then calculated as the ratio of the wet weight to the dry weight as determined by the foregoing procedure. That is, Swelling Index = Wet or Swollen Sample Weight Dry Sample Weight As is noted above, the swelling index value provides a measure of the relative degree of crosslinking which is present in the dispersed rubbery polymers of the composition in question. The more highly crosslinked the rubber particle is, the less is its capability for swelling and absorbing larger quantities of solvent. Accordingly, relatively lower swelling index values correspond to relatively higher degrees of crosslinking within the indicated dispersed, grafted rubber particles. Conversely, little or no rubber crosslinking in the sample of interest either results in there being little or no insoluble matter following dissolution thereof in the mixed toluene/methyl ethyl ketone solvent system or results in a relatively high swelling index value such as for example 30 or 40 or more. For the purposes of the σresent invention, the Dercentage of the N-suDstituteα maieimiαe monomer contained in tne grafteα and occluαeα rigid copolymer constituent can oe determined as follows: 1 Add 30 ml of a 70/30 volume ratio mixture of methyl eτhyi ketone 5 (MEK)/methanol to 1.0 gram of the resin to be analyzed and shake the mixture for at least 6 hours 2. Centrifuge at 19,500 RPM and 5°C for 2 hours 3. Pour off the supernatant. 4. Dry the remaining gel phase at 150°C and ambient pressure for 30 minutes, and 10 at 150°C and 5 mm Hg pressure (absolute) for 60 minutes. Gcp * = Graft - f Occlusions = j ( tWweeiιgghntt oofτ dorπieedo g geeli p phnaassee)) _ i • ] I | (1 Q0) (Weight of original sample) (% rubber/100) Rubber ^Grafted ana Occluded Copolymer Percentage 5. Elemental analysis of the gel phase for oxygen content will then allow determination of the percent of N-substituted maleimide monomer contained in the graft and occlusions. 20 The percentage of N-substituted maleimide monomer contained in the matrix phase can be ascertained by first determining the total maleimide monomer content in the overall resin sample via Fourier Transform Infrared Spectroscopy (FTIR) and then subtracting out the amount which has been found via the above-presented procedure to have been polymerized into the grafted and occluded copolymer. 25 Mcnovmylidene aromatic monomers suitable for use in both the matrix phase portion and in the grafted and occluded portion of the subject copolymer compositions include styreπe, oc-methylstyrene, p-vinyitoluene, p-t-butylstyrene, etc. Especially preferred for such usage is styrene. The amount of monovinyiidene aromatic monomer contained in the indicated 30 matrix phase copolymer and in the grafted/occluded rigid coooiymer portion is typically from 25 to 94 weight percent (based upon the weight of the respective copolymer components) and is more preferably in the range of from 35 to 89 (especially from 50 to 85) weight percent. Ethylenically unsaturated nitrile monomers suitable for use herein include acryionitrile and lower alkyl substituted derivatives thereof such as methacrylonitπle, 35 ethacrylonitnle, etc. with acryionitrile being especially preferred in most instances. While not being particularly critical for the purposes of the present invention, the ethylenically unsaturated nitrile monomer content within the matrix and grafted/occluoed copolymer portions of the subject polymer composition is typically in the range of from 5 to 40 weight percent and is preferaoly in the 10 to 40 (especially from 1 5 :o 30) weight percent range N-suostituted maleimioe monomers suitable τor se herein .nc.ude N-alkyl maleimides such as N-methylmaleιmιde, N-ethyimaleimide, N-propylmaleimide, N-isopropylmaleimide, N-t-butylmaleimide, etc , N-cycioaikylmaleimides such as N- cyclohexylmaleimide, N-aryimaleimides such as N-phenyimaleimide, N-naphthylmaleimide, etc , and the like Typically, the indicated N-substituted maleimide monomer will constitute from 1 to 35 (preferably from 1 to 25 and especially from 5 or 10 to 20) weignt percent of the respective matrix copolymer and grafted/occluded copolymer constituents As has been mentioned above, one key feature of the present invention resides in assuring that the N-substituted maleimide monomer content is reasonably well balanced (that is, numerically differing by 9 weight percentage points or less) as between the matrix copolymer portion and the grafted/occluded rigid copolymer portion of the subject polymer composition Preferably, the N-substituted maleimide contents of the indicated matrix and grafted/occluded copolymer components differ from each other by no more than 8 (especially no more than 7) weight percentage points As is noted above and as is seen in the hereinafter presented working examples, the impact strength of the indicated polymer compositions (that is, at a given rubber content and rubber particle size) is substantially decreased when the maleimide content difference between the two phases exceed the aforementioned values. A second key feature of, or requirement for, the subject polymer compositions is that the swelling index thereof (that is, reflecting the degree of crosslinking within the dispersed rubber particles thereof) be at least 12 As is illustrated in the working examples which follow, the impact strength and fatigue resistance haracteristics of such compositions are substantially improved at swelling index values in the range indicated as compared to that which is attained at lower swelling index values Preferably, the swelling index value of the subject polymer composition is in the range of from 15 to 20 or 25 When preparing the compositions hereof by generally known mass, solution or mass/suspension polymerization techniques, the swelling index of the resulting compositions is largely controlled by the type and amount of polymerization initiator employed therein and upon the temperature and residence time utilized in removing residual volatile materials from the polymerized reaction mixture Thus, for the purposes of the present invention, it is important to select and control those parameters in a fashion such that the aforementioned swelling index requirement is met in the resulting polymer composition As is typical of conventional mass, solution or mass/suspension polymerized ABS polymer compositions, the ruDber content of the subject impact modified styrenic copolymer - compositions generally falls within the range of from 5 to 30 (more preferaDly from 7 to 25 and especially 9 to 21 ) weignt percent on a total composition weight basis. As is also typicai of ruober-mooified polymers prepared in the foregoing fashion, tne dispersed rubber particles of the present polymer compositions, when prepared by mass, solution or mass/suspension graft polymerization techniques, wiil general ly have a volume average particle size within the range of from 0.5 to 5 (preferably from 0.8 to 3) micron. Rubbery polymer materials suitable for use in preparing the subject impact- modified monovmylidene aromatic copolymers include homopoiymers of conjugated diene monomers such as 1 ,3-butadiene, isoprene, etc. and copolymers of such diene monomers with up to 40 weignt percent of copolymeπzable monoethylenically unsaturated monomers such as monovinyiidene aromatic monomers, ethylenically unsaturated nitriie monomers, Ci-Q alkyl acrylate or methacryiate monomers, etc. Such rubbery polymer materials generally have a glass transition temperature (Tg) of less than 0°C and, most preferably, the Tg thereof is less than - 20°C for the present invention's purposes. Preparation of the subject polymer compositions is suitably conducted generally in accordance with known mass, solution or mass/suspension polymerization techniques. Thus, the indicated rubbery polymer is initially dissolved in a monomer mixture containing the desired monomer materials and optionally containing an organic solvent or diluent and the resulting rubbery polymer/monomer solution is polymerized (partially) to a point at which phase inversion occurs (that is, at which the dissolved rubbery polymer comes out of the solution and takes the form of discrete rubber particles dispersed within the polymerizing monomer mixture). Polymerization of the resulting heterogeneous (that is, two phase) mixture is then continued until the desired degree of monomer-to- polymer conversion has been achieved (typically from 50 to 95, preferably from 60 to 0 and more preferably from 70 to 90, weight percent conversion of the monomers charged to the process to polymerized product) and the resulting reaction mixture is then devolatilized (typically under elevated temperature and reduced pressure conditions) to remove any residual monomer materials (and any diluent used in the process) and to thereby recover the desired graft copolymer product. Although the present invention may be practiced in a batch polymerization process, it is preferably conduαed in a continuous fashion in either a backmixed or a plug flow (non-backmixed) reactor. One such suitable process employs one or more well stirred tubular reactors. Desirably, the polymerization is conducted in a train consisting of two and preferably three plug flow, stirred tube reactors connected in series. Phase inversion preferably occurs in the first reactor and the polymerizing mixture is discharged from the first reactor into the second reactor and subsequent reactors. In the remaining reactors polymerization is continued in the presence of agitation to the desired final degree of polymerization. In conducting the indicated polymerization process, it has been observed that the N-substituted maleimide monomer employed therein exhibits a relatively rapid rate of polymerization As a result, there tenos to oe a supstantial "composition oπft" (that is, in terms oτ N-suostituted maleimide monomer content) as oetween cooolymer τormeo during the early stages oτ tne polymerization (e g , grafteo-aπd occluded coooiymer ano some of the matrix onase cooolymer) and that portion of the continuous matrix σnase coooivmer wnicn is formed 5 'ater in tne process Thus, for example, it has oeen found that in those instances wnerein ail of the N- suostituted maieimide monomer component is charged to the graft polymerization process at or near tne verv oeginning thereof, the difference in the maieimioe monomer content as between the respective grafteo/occiuded cooolymer and matrix copolymer portions will < 0 typically be in the range of 10 weignt percentage points or more ano can ouite commonly be in the range of 13 to 15 weight percentage points or more. Accordingly, in order to ensure thatthe maieimide monomer contents of the respective grafted/occluded and matrix copolymer phases are sufficiently balanced for the purposes of this invention, the subject polymer compositions are prepared by withholding at 15 least a portion (e.g., from 20 to 100 weight percent and preferaoly from 30 to 75 weight percent) of the N-substituted maleimide monomer from the initial monomer charge and by deferring the addition thereof until later in the polymerization process. Thus, the initial monomer charge will typically contain from 0 to 80 (preferably from 25 to 70) weight percent of the total amount of of N-substituted maleimide monomer that is to be employed in the 20 overall polymerization process. Typically, it is advantageous to introduce the deferred maleimide monomer charge or feed stream at a point in the process at which at least 20 percent (and preferably at least 25 or 30 percent) of the original monomer charge has been converted from monomer to polymer. 25 Most preferably, the indicated deferred maleimide monomer addition is conducted at a stage in the graft polymerization process which is after (and preferably only shortly after) the rubber phase inversion which has been described above (that is, phase separation of the previously dissolved rubbery polymer to form discrete particles of dispersed rubbery polymer material) has already occurred. 30 I is also generally preferred that the indicated deferred maleimide monomer addition be conducted at stage in the process whicn is prior to 60 (more preferably prior to 50) percent conversion of the original monomer charge or feed stream Typically, the aforementioned graft polymerization process will be conducted at a temperature in the range of from 80 to 180 °C and will employ an effective amount (e.g., from 35 50 to 200 ppm) of a conventional polymerization initiator such as, for example, 1 ,1-bis (t- butylperoxy) cyclohexane, dicumylperoxide, t-butylperoxy-2-ethylhexanoate, etc. Devolati zation of the resulting reaction mixture (that is, to recover the desired graft copolymer product) is typically conducted at a temperature in the range of from 200 to 300 C C. at a pressure of 30 mil l imeters of mercury (absol ute) ano for a residence time of from 0.2 to 1 .5 hours As wi n unoouoteoiy oe readi ly aoparent to those SK I I led in the art, the suDject mass, solution or masysuspension graft copoiymer compositions nereof can oe readily compounded with other conventional ingredients such as pigments, moid release agents, nalogenateo fire retardant ingredients, fillers, reinforcing materials, plowing agents, other thermoplastic resin ingredients, etc. as may oe desired in a given instance. In one sucn preferred empodimeπt hereof, the indicated maleimide-modified mass, solution or mass/susoension graft copoiymer is melt compounded with from 5 to 40 o weight percent (on a total composition weignt basis) of an emulsion graft polymerized rubber concentrate material in order to further enhance the impact strength and toughness characteristics of the resulting polymer composition. Said grafted rubber concentrate typically contains from 30 to 70 weight percent of dispersed rubber particles (usually having volume average particle sizes in the range of from 0.05 to 1 , preferably from 0.1 to 0.6, micron) having 5 grafted thereto a rigid superstrate copoiymer of a monovmylidene aromatic monomer, an ethylenically unsaturated nitrile monomer ano, optionally, an N-substituted maleimide monomer. The present invention is further illustrated and understood by reference to the following working examples in which all parts and percentages are stated on a weight basis unless otherwise indicated. Within such working examples, the various physical properties and characteristics of the resulting polymer compositions were determined as indicated below: Izod Impact - ASTM D256-87 using injection molded test specimens Tensile (Tm, Ty, Tr, % E) -- ASTM D638-87b using injection molded specimens Instrumented Dart Drop - ASTM D3763-86 (Injected molded specimens) Distortion Temperature Under Load (DTUL) -- ASTM D648-82 Vicat - ASTM D 1525-87 Melt Flow Rate (MFR) - ASTM D 1238-86 Gloss - ASTM D523-89 Molecular Weight (Mw, Mn) - Determined by Gel Permeation Chromatograph (GPC) Reduced Viscosity - Determined as described at Column 4, lines 40-45 of U.S. Patent 4,808,661 Fatigue - Tensile fatigue testing using double notched, compression molded ASTM tensile bars at 1 cycle per second, peak load of 1 ,500 psi and minimum: maximum load ratio of 0.1. Example 1 A continuous solution polymerization process is conducted utilizing three well stirred reactors connected in series Eacn reactor is caoaple oτ rolding 2 8 lbs ( 1 27 Kg) oτ reaction mixture and all three of them are operated at * uil voiumetπc capacity A main monomer reed stream comprising styrene (61 percent) ano acryionitrile (14 9 percent) having dissolved therein 8 8 percent polybutaoiene ruboer (Diene 55 available from the Firestone Tire and Ruboer Company), 15 4 percent ethylbenzene solvent, 0 2 percent hindered phenolic antioxidant (Irganox 1076), 138 parts per million initiator, 1 ,1 -bιs(t-butyl peroxy)cyclohexane, o and 100 parts per million of chain transfer agent (n-dooecyl mercaptan) is introduced to the first reactor at a rate of 0 78 lb/hr (0.35Kg/hr) A second monomer stream containing 40.3 percent acryionitrile, 26.8 percent N-phenylmaieimioe (N-PMI) and 32.9 percent ethylbenzene solvent is added at three points in the polymerization where the main monomer feedstream conversion fraction is 0.084, 0.332 and 0 41 1 The total amount of this stream (that is, the so- 5 called "Split N-PMI Addition" feeα stream) is 0 079 Ib/hr (0 036 Kg/hr) ano is added in equal amounts at each of the three points of addition. An additional 900 parts per million of chain transfer agent (on a main monomer feedstream basis) is added at the point in the reactor train where monomer conversion is 0.332 The first reactor is maintained at an average temperature of 104°C with stirring Phase inversion occurs in the first reactor (at a point where monomer 0 conversion is approximately 17 percent) and the effluent is charged to the second reactor in the series. The temperature of the second reactor is maintained at 125°C. The product from the second reactor is charged to the third reactor which is maintained at a temperature of 145°C. The final product is devolatilized to remove unreacted monomer and solvent and is then pelletized. The properties of the resulting polymer are shown in Table 1 5 Comparative Example 1-A The polymerization process and reaction conditions of Example 1 are substantially repeated with the exception that all the N-phenyimaleimide is added in the monomer feed stream before it enters the first polymeπzer The properties of the resulting polymer are shown in Table 1 0 Comparative Example 1-B The graft copolymer of Example 1 is fed to a twin screw extruder operating at an average temperature of 200°C along with 0 1 percent of 2,5-dιmethyl-2,5-dι-(t-butyl peroxy) hexane (Lupersol 101) in order to further crosslink the rubber component thereof and to thereby reduce the swelling index of the resulting composition The properties of the resulting 5 polymer are shown in Table 1 Comparative Example 1-C The graft copolymer of Comparative Example 1-A is also fed to a twin screw extruder operating at an average temperature of 200°C along with 0.1 percent of 2,5-dιmethyl- 2.5-dι-(t-butyl oeroxy) hexane (Luoersoi 101 ) to reduce the swelling inoex of that graft copoiymer. The properties of the resulting polvmer are snown in Table 1 Example 2 Example 1 is suostantially repeated with the exception that tne main monomer *' eeo stream contains 53.6 percent styrene, 16.8 percent acryionitrile, 0.9 Dercent N- pnenyimaieimide, 12.0 percent of a styrene-butaoiene diblock ruober (Stereon 730A from Firestone "ire ano Rubber Company) and 16 4 percent ethylbenzene solvent. The second monomer stream is identical in composition to Example 1 ano is added at the same points of conversion as m Example 1 but at a total rate of 0.095 Ib/hr. The properties of the resulting poiymer are shown in Table 1 Comparative Example 2 The graft copolymer of Example 2 was fed to a twin screw extruder operating at an average temperature of 200°C along with 0.1 percent of 2,5-dimethyl-2,5-di-(t-butyl peroxy) hexane (Lupersol 101) to crosslink the rubber particles thereof and to thus reduce the swelling index of the resulting polymer composition. The properties of the resulting poiymer are shown in Table 1. TABLE 1 *Connotes posL-phase inversion addition of at least a portion of the N-PMI monomer, TABLE 1 continued I As can be seen from the results in Table 1 , the addition of at least a portion of the N-ohenyimaieimioe (N-PMI) monomer component at a later stage in the polymerization process (that is, a ter the point of ruoberpnase inversion as in the case of Examples 1 and 2) proviαes notaoly improved impact strength results relative to those wnicn are ootained by adding ail of N-PMI monomer in the beginning stages of the polymerization process (that is, pre-pnase inversion). As can also be seen (that is, by comparing Example 1 with Comparative Example 18 and Example 2 with Comparative Example 2), the graft copoiymer compositions of the present invention (that is, having a swelling index of at least 12) have notably improved fatigue o resistance and impact strength relative to comparaDie compositions that have swelling indexes of less than 12. Example 3 Example 1 is substantially repeated with the exception that the main monomer feed stream contains 59.3 percent styrene, 14.2 percent acryionitrile, 6.3 percent N- 5 pnenylmaleimide, 6.0 percent Diene 55 polybutadiene rubber and 14.3 percent ethylbenzene solvent. The second monomer stream is identical in composition to that of Example 1 and is added in equal amounts at conversion points of 0.3 and 0.4 at a total rate of 0.13 Ib/hr (0.059 Kg/hr). The resulting graft copolymer is compounded with 19 percent of a grafted rubber concentrate for additional impact resistance and 1 percent of a bis-stearamide wax. The 0 properties of the resulting polymer are shown in Table 2. The grafted rubber concentrate employed in this example is one in which styrene and acryionitrile (in a 70:30 weight ratio) have been emulsion graft polymerized to a 93:7 weight ratio butadiene/styrene copoiymer latex. Such grafted rubber concentrate has a rubber content of 52 weight percent, a volume averaged particle size of 0.15 micron and a grafted copolymer to rubber ratio of 0.3. Comparative Example 3-A Example 3 is substantially repeated with the exception that the main feed, containing styrene (50.7 percent) and acryionitrile (17.9 percent) having dissolved therein 5.1 percent polybutadiene Diene 55 rubber, 17.0 percent ethylbenzene solvent, has all of the N- phenylmaieimide monomer (9.3 percent)added to it before it enters the first polymerizer. This graft copolymer is also compounded with 19 percent of the grafted rubber concentrate of Example 3 above for additional impact resistance and 1 percent of a bis-stearamide wax. The properties of the resulting poiymer are shown in Table 2. Comparative Example 3-B The polymerization process of Example 1 is substantially repeated with the exception thatthe main monomer feed stream contains styrene (65 percent), acryionitrile (11.6 percent) and N-phenylmaleimide (4.4 percent) having dissolved therein 6.6 percent Diene 55 polybutadiene rubber and 12.5 percent ethylbenzene solvent. The second monomer stream is identical in composition to Example 1 and is added at the same points of conversion but at a total rate of 0.2 Ib/hr (0.091 Kg/hr) The resulting graft coooiymer is meit comoounαed with 19 percent of the grafted rubber concentrate of ExamDie 3 aoove for additional impact resistance ano 1 percent of a bis-stearamide wax. The properties of tne resulting polymer are shown in Table 2. Example 4 Ξxampie 1 is substantially repeated with the exception that the main monomer feed stream contains 62.1 percent styrene, 12.9 percent acryionitrile and 5.4 percent N- phenyimaleimide. 6.2 percent Diene 55 polybutadiene rubber and 13.4 percent ethylbenzene solvent. The second monomer stream is identical in composition to Example 1 and is added in equal amounts at main monomer feed conversion points of 0.3 and 0.4 at a total rate of 0.17 Ib/hr (0.077 Kg/hr). The resulting graft copoiymer is compounded with 19 percent of grafted rubber concentrate of Example 3 for additional impact resistance and 1 percent of a bis- stearamide wax. The properties of the resulting polymer are shown in Table 2. Example 5 Example 1 is substantially repeated with the exception that the main monomer feed stream contains 56.6 percent styrene, 15.3 percent acryionitrile, 7.3 percent N- phenylmaleimide, 5.7 percent Diene 55 polybutadiene rubber and 15.2 percent ethylbenzene solvent. The second monomer stream is identical in composition to Example 1 and is added in equal amounts at main feed monomer conversion points of 0.3 and 0.4 at a total rate of 0.095 Ib/hr (0.043 Kg/hr). The resulting graft copolymer is compounded with 19 percent of the grafted rubber concentrate of Example 3 for additional impact resistance and 1 percent.of a bis-stearamide wax. The properties of the resulting polymer are shown in Table 2. TABLE 2 I *Connotes that at least a portion of the N-PMI is added following rubber phase inversion. TABLE 2 continued I As can oe seen from the data in Table 2. compositions which have a V-'.VIi content difference of iess than 9 oercentage points as between the craήeo/occiuded oDO'vπe*- portion and the matrix onase portion thereof exnibit suostantiaiiy ennanceo ;moac: s rengtn properties. Comparative Example 4 Example 1 is substantially repeated with the exception of the main monomer feed stream contains 60.1 percent styrene, 15.0 percent acryionitrile, 9.4 percent Diene 55 polybutadiene rubber ano 15.5 percent ethylbenzene solvent. The second monomer stream is identical in composition to Example 1 and is added at a main monomer feed conversion point of 0.08 at a rate of 0.15 Ib/hr (0.068 Kg/hr). The properties of the resulting polymer are shown in Table 3. Example 6 Example 1 is substantially repeated with the exception thatthe main monomer feed stream contains 60.3 percent styrene, 14.9 percent acryionitrile, 9.5 percent Diene 55 polybutadiene rubber and 15.4 percent ethylbenzene solvent. The second monomer stream is identical in composition to Example 1 is added at conversion points of 0.08, 0.3 and 0.4. The total amount of this stream is 0.18 Ib/hr (0.082 Kg/hr) and is added in equal amounts at the three conversion point locations. The properties of the resulting polymer are shown in Table 3. Example 7 Example 1 is substantially repeated with the exception thatthe main monomer feed stream contains 60.3 percent styrene, 14.9 percent acryionitrile, 9.5 percent Diene 55 polybutadiene rubber and 15.4 percent ethylbenzene solvent. The second monomer stream is identical in composition to Example 1 and is added at conversion points of 0.08, 0.3 and 0.4 in amounts of 0.12, 0.03 and 0.03 Ib/hr (0.055, 0.014 and 0.014 Kg/hr), respectively The properties of the resulting polymer are shown in Table 3. TABLE 3 *Connotes that at least a portion of the N-PMI monomer is added following rubber phase inversion. 0 As can be seen from the results in Table 3, substantially better room temperature Dart impact strength results are obtained when at least a portion of the maleimide monomer is 5 added after rubber phase inversion thereby causing the maleimide monomer contents of the grafted/occluded copolymer and the matrix phase copolymerto be within 9 percentage points of each other. Example 8 Example 1 is suostantiaily repeated with tne exception that a styrene-outaoiene diblock ruooer (Stereon 730A) is used in piace of the butadiene nomoDOiymer ruooer of Example 1. The properties of the resulting polymer are snown in Table 4 Comparative xample 8 Comparative 1-A is also substantially repeated witn the exception of using the Stereon 730A block cooolymer rubber in piace of Diene 55 butadiene homooolymer ruober The Drooerties of the resulting polymer are shown in Table 4 :ABLE 5'Connotes post-phase inversion addition of at least a portion of the N-PMI monomer. 0 Example 9 Example 1 is suostantiaily repeated with the exception that the main monomer feeo stream contains 57 8 percent styrene,' 14 0 percent ac r yιonιtπle " 2 7 percent Stereon 730A styrene-butadiene oiolock ruboer and 15 5 percent ethylbenzene solvent ano is added at a rate 5 of 0 89 Ib/hr (0 405 Kg/hr) -ne second monomer stream is identical n composition to that of Example 1 and is added at main feed conversion points of 0 09, 0 3 ano 0 55 The total amount of this stream is O 18 Ib/hr (0 082 Kg/hr) and is added in eouai amounts at the three conversion point locations The properties of the resulting poiymer are shown in Table 5 Example 10 1 o A modification to tne process described in Example 1 results in the first and second stirred reactors being continuously recirculated (or "backmixed") at a rate of 21 : 1 (material being recιrculated:fresh feed). The recirculation stream has monomer to polymer conversion of 41 percent and the main monomer feed stream to the recirculated reactors contains 48.3 percent styrene, 18.4 percent acryionitrile, 10.6 percent Stereon 730A rubber, and 15 18 0 percent ethylbenzene, and 190 parts per mii on initiator, 1 ,1-bιs(t-butyl oeroxy)cyclohexane. The temperature of the recirculated reactors is maintained at 103°C wιth stirring. Phase inversion of the freshly added feed is instantaneous. The third reactor, which is not recirculated, is maintained at a temperature of 130°C. The properties of the resulting polymer are shown in Table 5 0 5 0 5 7A3 E As can be seen from the results in Table 5, the resin prepared using the recirculation or backmixing technique of Example 10 resulted in a resin having a difference of only 4.6 percent as between the N-PMI content of the grafted/occluded copolymer and the matrix phase. It can also be seen, however, that utilization of the split feed/post phase inversion N-PMI addition in the context of a plug flow (non-backmixed) graft polymerization process provided relatively tougher final product having notably better Izod impact strength and Dart impact strength characteristics. While the present invention has been described and illustrated with reference to certain specific and preferred embodiments thereof, such is not to be interpreted as in any way restricting or limiting the scope of the instantly claimed invention.

Claims: Claims : 1 A ruoDer-mooified monovinvnoene aromatic coDθiyτe r composition Λ-hicn comprises A a continuous onase matrix copolymer comprising, in polymerized ro r m ana on a 5 matrix coooiyme r weignt basis, τrom 35 to 89 weignt percent oτ a monovinyiidene aromatic monomer, from 10 to 40 weight p ercent or an ethylenically unsaturated nitrile monomer, and from 1 to 25 weight percent of an N-substituted maieimide monomer, and B dispersed within said matrix copoiymer, discrete ruober particles having grafted ι o thereon and occluded therein a rigid coooiymer constituent comprising, in polymerized form and on a rigid copolymer constituent weight basis, from 25 to 94 weight percent of a monovmylidene aromatic monomer, from 5 to 40 weight percent of an ethylenically unsaturated nitrile monomer, and from 1 to 35 weight percent of a N-substituted maieimide monomer; saiα rubber-modified ■ 5 monovmylidene aromatic copolymer composition oeing further characterized in that it has a swelling index value of at least 12 and in that the difference between the N-substituted maleimide monomer content of the matrix phase cooolymer and that of the grafted and occluded rigid copolymer constituent is 9 weight percentage points or less 0 2 The aromatic copolymer composition of Claim 1 wherein the N-substituted maleimide monomer of both matrix copolymer and the grafted and occluded rigid copoiymer is an N-aryi maleimide. 3. The aromatic copolymer composition of Claim 2 wherein the N-aryl maleimide is N-phenyl maleimide 5 4. The aromatic copoiymer composition of Claim 3 wherein, in both tne matrix copolymer and the grafted ana occluded copolymer, the monovmylidene aromatic monomer is styrene and the ethylenically unsaturated nitrile is acryionitrile 5. The aromatic copoiymer composition of Claim 1 wherein the difference between the N-substituted maleimide content of the matrix phase ana the N-substituted 0 maleimide content of the grafted and occluded rigid copolymer is 8 weight percentage points or less. 6 The aromatic copolymer composition of Claim 1 wnere the swelling index thereof is from 15 to 25 7. The aromatic copoiymer composition of Claim 1 wherein the rubber content 5 thereof is from 5 to 30 percent based upon the total weight of said composition 8. The aromatic copolymer composition of Claim 1 wherein said composition has been prepared by a mass, solution or mass/suspension polymerization process 9. The aromatic coooiymer comDOSition of Clai m 8 wnerem said comDOSition further comprises, on a total comoosition weignt basis, from 5 to 40 weignt Dercent of an emulsion graft ooiymeπzeα ruooer concentrate wnich comoπses. on a ruooer concentrate weignt basis, from 30 to 70 weignt percent of dispersed ruober particles navmg grafted thereto a rigid superstrate poiymer comprisi ng, i n poiymeπzeo form , a monovinyi idene aromatic monomer, an ethylenicaily unsaturated nitrile monomer ano, optionally, an N-substituted maleimide monomer. 10. A process for preparing a rubber-modified monovinyiidene aromatic copolymer composition, said process comoπsi ng the steps of: A. dissolving a rubbery polymer material in a monomer mixture comprising a monovinyiidene aromatic monomer, an ethylenically unsaturated nitrile monomer and, optionally, an N-substituted maleimide monomer; B. partially polymerizing the resulting solution of said rubbery polymer material in said monomer mixture; C ' adding an N-substituted maieimide monomer to the partially polymerized solution of said rubbery polymer material in said monomer mixture when at least 20 weight percent of said monomer mixture has been converted from monomer to polymer; D. continuing to polymerize the partially polymerized reaction mixture of step (C) to the desired degree of polymerization; and E. removing any unreacted monomers from the product of step D at elevated temperature and reduced pressure and under conditions such that the swelling index of the resulting rubber modified polymer product is 12 or greater. 1 1. The process of Claim 10 wherein the N-substituted maleimide monomer addition of step C is conducted at a point in the polymerization process after the dissolved rubbery polymer has phase separated to form discrete particles of dispersed rubbery material. 12. The process of Claim 1 1 wherein at least 30 weight percent of the total N- substituted maieimide monomer employed in said process is added after the point of said rubber phase separation.

Inventors: TRAUGOTT THOMAS D, WORKENTINE SHARI L, TRAUGOTT, THOMAS, D., WORKENTINE, SHARI, L.
Applicants: DOW CHEMICAL CO, THE DOW CHEMICAL COMPANY
Application year: 1994
Main classification: C08F279
IPC codes: C08F279, C08L21, C08L25, C08L33, C08L35, C08L51, C08L55