Glazing unit having three or more glass sheets and having a low thermal edge, and method of making same

Abstract: A glazed unit (20) having three sheets includes a pair of outer glass sheets (22,24) secured to outer legs of a spacer (30) having a generally U-shaped cross section. On the base (42) of the spacer between the outer legs is provided a layer (38) of pliable material having a generally U-shaped cross section and having a desiccant therein. A third or intermediate glass sheet (26) has its edge portion in the groove (48) formed by the layer of pliable material. Movement of the third sheet (26) toward an outer glass sheet is limited by the cooperation of the layer (38) of the pliable material and portion of the outer legs of the spacer (30) at the corners of the unit (20) bent inwardly to move the layer (38) of pliable material at the corner toward the unit during fabrication of the unit. A nozzle for depositing the shaped layer of the pliable material includes a platform having a shaping tip. The shaping tip has converging sides at one end and generally parallel sides at the other end. The portion of the tip at the first end has a lower elevation than the portion of the tip at the second end. Holes for moving the pliable material are provided in the platform on each side of the tip and in tips intermediate its ends. The different elevation and converging end minimizes if not eliminates tailing. A method is also discussed for making the triple glazed unit using the nozzling to provide the shaped layer of pliable material. An injector arrangement fills the unit with an insulating gas e.g. Argon.

Description: FIELD OF THE INVENTION This invention relates to a unit having three or more sheets, and, in particular to a triple unit having a pair of outer sheets separated by an edge assembly, the edge assembly including a spacer arrangement for supporting a sheet between the outer sheets, and method of making of the triple unit. BACKGROUND OF THE INVENTION European Patent Application Publication Number 0 475 213 A1 published 18.03.92 Bulletin 92/12 (hereinafter "The EP Application") based on U.S. Patent Applications Serial Nos. 578,697 filed September 4, 1990; 578,696 filed September 4, 1990, and 686,956 filed April 18, 1991, teaches a glazing unit having an edge assembly having low thermal conductivity and a method of making same. In general, The EP Application teaches an insulating unit having a pair of glass sheets about an edge assembly to provide a compartment between the sheets. The edge assembly has a U-shaped spacer that is moisture and/or gas impervious, and has materials selected and sized to provide the edge assembly with a predetermined RES-value (as defined and determined in the disclosure of The EP Application). The EP Application further discloses a triple glazed unit having a low thermal conducting edge. U.S. Patent No. 4,149,348 teaches a technique for making a triple glazed unit. In general, the triple glazed unit includes a pair of outer glass sheets separated by a spacer-dehydrator element, or metal spacer, having a groove to maintain a third glass sheet between the outer two glass sheets. Although the triple glazed unit taught in U.S. Patent No. 4,149,348 is acceptable, there are limitations. More particularly, the spacer-dehydrator element is structurally stable and is formed with a groove prior to its use. The spacer has desiccant therein; therefore it is stored in a dry environment to prevent absorption of moisture by the desiccant. The metal spacer has to be formed to have groove; the additional forming increases the fabrication cost of the spacer. Further, the groove formed in the spacer disclosed in U.S. Patent No. 4,149,348 maintains the third glass sheet spaced from the outer sheets; therefore, the groove has to be properly sized to prevent movement of the inner sheet relative to the outer sheets. According to FR 79.993 there is provided a glazing unit comprising two or three glass sheets arranged between two profiles. In one embodiment the glazing unit as a generally U-shaped metallic spacer which is arranged between the two outer glass sheets. A third and intermediate glass sheet is held by an elastic mounting within said spacer. The elastic mounting consists of an essentially plane portion which forms a cushion for carrying the intermediate sheet, and two hollow legs securing the lateral position of the intermediate sheet. As can be appreciated, it would be advantageous to provide an insulating unit having three or more sheets that does not require storage or prefabricated materials e. g. a spacer-dehydrator element having a groove, does not require shaping the spacer to have a groove, and does not depend solely on the groove formed in the spacer to secure the intermediate sheet in position. SUMMARY OF THE INVENTION This invention relates to a unit according to the preamble of claim 1 (see FR-A-79 993) and is specified by the characterising portion of claim 1. The unit includes a spacer having a receiving surface to maintain the sheets in spaced relationship to one another. In one embodiment of the invention, the spacer has a base, a first wall and a second wall each extending upward from the base to provide the spacer with a generally U-shaped cross section with the receiving surface between the walls. The sheets are secured to the spacer, e. g. by a moisture and/or gas impervious adhesive on outer surfaces of the walls of the spacer to provide sealed compartments between the outer sheets e. g. as sealed compartment between one of the outer sheets and the intermediate sheet and a sealed compartment between the other outer sheet and the intermediate sheet. A layer of a flowable, pliable material has a generally U-shape cross section to provide a groove to receive marginal edge portions of the third or intermediate sheet. Facilities are provided to maintain the intermediate sheet in a substantially fixed relationship to the outer sheets. In one embodiment of the invention, the wall portions of the spacer at selected corners of the finished unit are bent toward one another and spaced a sufficient distance to receive the intermediate sheet therebetween. The wall portions of the spacer bent toward one another biases the pliable material on the receiving surface of the spacer toward the intermediate sheet to maintain the intermediate sheet in position. In a further embodiment of the invention a desiccant is provided in the pliable material, an insulating gas e.g. argon gas is provided in the compartments formed by adjacent sheets and the spacer, and/or the edge assembly including the spacer, the adhesive and the pliable material have a RES-value equal to or greater than 10 as measured using ANSYS. The invention further relates to a method of making an insulating unit according to claim 26. In one embodiment of the invention, the spacer is formed by providing notches at selected positions on a flat bendable substrate to provide opposed pair of notches defining bend areas of the spacer. The flat substrate is shaped to provide a spacer having a generally U-shaped cross section defined by a first outer leg, a base and a second outer leg. A shaped layer of a flowable material e.g. a pliable material or a material that hardens after flowing and is dimensionally stable, having a groove is provided on the receiving surface of the spacer. The sheet or sheets to be positioned between the outer sheets has peripheral configurations similar to the outer glass sheets and peripheral dimensions less than the outer sheets. The spacer is positioned around the edge of the intermediate sheet with the edges of the intermediate sheet in the groove. The intermediate sheet is maintained in a generally fixed position relative to the outer sheets by the pliable material and/or the spacer. In one embodiment of the invention, as the spacer having the U-shaped cross section is positioned around the periphery of the third sheet, the wall portions of the spacer at the bend areas are bent inward toward one another urging the pliable material toward the corner areas of the intermediate sheet. The layer of the pliable material may have a desiccant mixed therein. The outer sheets are secured to the outer surfaces of the legs of the spacer by an adhesive, e. g. by a moisture and/or gas impervious adhesive. According to EP 0 475 213 A1 a glazing unit according to the prior art disclosed therein is manufactured by forming a metal substrate into a spacer stock, the substrate having bead of moisture pervious adhesive having a desiccant mixed therein. The bead is applied to the center of the substrate in any convenient manner. The bead has a sufficient structural strength and resiliency to keep the sheets spaced apart, which will be provided on the outside of a spacer frame in the last manufacturing step. The substrate is shaped in a single U-shaped spacer stock. The bead could also be applied after the spacer stock has been formed from the substrate. Afterwards the spacer stock is formed into a spacer frame for positioning between the sheets. There are used only two outer sheets which are provided on the outside of the spacer frame. This method differs from the predetermined according to the invention with regard to the different sequence of the manufacturing steps and the material used for the bead and the bead itself. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a frontal view of a triple glazed unit incorporating features of the invention. Fig. 2 is the view taken along lines 2-2 of Fig. 1. Fig. 3 is a view similar to the view of Fig. 2 illustrating another embodiment of an edge assembly incorporating features of the invention. Fig. 4 is a fragmented elevated view of a substrate having portions removed prior to forming a spacer used in the practice of the invention. Fig. 5 is an elevated side view of a nozzle for extruding a shaped layer of adhesive on the base of a spacer. Fig. 6 is a plane view of the tip of the nozzle. Fig. 7 is a side view of the tip of the nozzle. Fig. 8 is a view similar to the view of Fig. 6 illustrating another embodiment of a tip. Fig. 9 is a view similar to the view of Fig. 7 illustrating further details of the tip of Fig. 8. Fig. 10 is a side elevated view of an injector arrangement for filling the compartments of a glazing unit with an insulating gas. Fig. 11 is an end view of the injector arrangement of Fig. 10. Fig. 12 is a view illustrating the use of the injector arrangement of the invention to fill a unit having a single compartment with an insulating gas. Fig. 13 is a view similar to the view of Fig. 12 illustrating the use of the injector arrangement to fill a unit having two sealed compartments. Fig. 14 is a view similar to the view of Fig. 2 showing an insulating unit having three compartments incorporating features of the invention. BRIEF DESCRIPTION OF THE INVENTION With reference to Figs. 1 and 2 there is shown a glazing unit 20 incorporating features of the invention. With specific reference to Fig. 2 the unit 20 includes a pair of outer sheets 22 and 24 and an intermediate sheet 26. The outer sheets 22 and 24 and the intermediate sheet 26 are maintained in spaced relationship by an edge assembly or spacer arrangement 28. In the following discussion the sheets 22, 24 and 26 are referred to as glass sheets; however, as will become apparent, the materials of the sheets are not limited to glass and any one or all of the sheets may be made of any similar or dissimilar material e.g. plastic, metal or wood. Further, one or more of the sheets may be coated e.g. glass or plastic transparent sheets may have an opaque coating of the type used in making spandrels. Still further, one or more of the glass or plastic transparent sheets may have an environmental coating on one or more of the sheet surfaces to selectively pass predetermined wavelength ranges of light. More particularly, glass sheets may have coatings to filter portions of the infrared range e.g. low E coatings and/or coatings to reflect light e.g. reflective coatings. Although not limiting to the invention, coatings disclosed in U.S. Patent Nos. 4,610,711; 4,806,220 and 4,853,256 may be used in the practice of the invention. Still further, one or more of the glass sheets may be coated and or uncoated colored sheets. Although not limiting to the invention, colored sheets of the type disclosed in U.S. Patent Nos. 4,873,206; 5,030,593 and 4,792,536 may be used in the practice of the invention. The outer glass sheets 22 and 24 may have the same peripheral configuration and dimensions; however, as can be appreciated, one outer glass sheet may be larger than the other outer glass sheet and may have a different peripheral configuration. The edge assembly 28 includes a spacer 30 having a generally U-shaped cross section as shown in Fig. 2, an adhesive layer 32 on outer surfaces of outer legs 34 and 36 of the spacer 30 and a shaped layer 38 of material (to be discussed below) on inner surface 40 of base 42 of the spacer 30. A layer 44 of a material similar to or dissimilar to the material of the layers 32 may be provided over outer surface 46 of the base 42 of the spacer 30 as shown in Fig. 2. As can be appreciated, the configuration of the spacer is not limiting to the invention and may have any cross section provided it has a surface to receive the shaped layer 38 and the intermediate glass sheet 26. For example and with reference to Fig. 3, there is shown a unit 50 having the glass sheets 22 and 24 separated by an edge assembly 52 having the adhesive layers 32 to secure the glass sheets 22 and 24 to spacer 54. The spacer 54 may be made of wood, metal or plastic having any cross sectional configuration and a receiving surface 56 to receive the shaped layer 38 in a similar fashion as the surface 40 of the spacer 30 of the edge assembly 28 shown in Fig. 2. As discussed, the spacers 30 and 54 may be made of any material and configuration that preferably provides structural stability to maintain the outer glass sheets 22 and 24 in spaced relationship to one another when biasing forces are applied to secure the glazing unit in a sash or a curtainwall system. Further the spacers 30 and 54 should have a substantially flat surface to receive the shaped layer 38. Although the spacers 30 and 54 may be made of any material and have any configuration provided it has a receiving surface, it is preferred that the spacer have low thermal conductivity so that the edge assembly 28 shown in Fig. 2, and the edge assembly 52 shown in Fig. 3, have a low thermal conductivity or high RES-value and are made of moisture and/or gas impervious materials. In regards to the edge assembly having a low thermal conductivity, spacers made of aluminum conduct heat better than spacers made of metal coated steels e.g. galvanized or tin plated steel, spacers made of metal coated steels conduct heat better than spacers made of stainless steels, and spacers made of stainless steels conduct heat better than spacers made of plastics. Plastic provides a better spacer from the standpoint of low thermal conductivity; however, metal is preferred for spacers because it is easier to shape and lends itself more easily to automation than plastic. The EP Application discusses in detail how RES-value is determined and the contributions of the components of the edge assembly to the RES-value. The following is a less detailed discussion. The heat loss through an edge of a unit is a function of the thermal conductivity of the materials used, their physical arrangement, the thermal conductivity of the frame and surface film coefficient. Surface film coefficient is transfer of heat from air to glass at the warm side of the unit and heat transfer from glass to air on the cold side of the unit. The surface film coefficient depends on the weather and the environment. Since the weather and environment are controlled by nature and not by unit design, no further discussion is deemed necessary. The frame or sash effect is not relevant in the present discussion because the discussion is directed to the thermal conductivity of the materials at the unit edge and their physical arrangement. The resistance of the edge of a unit to heat loss for an insulating unit having sheet material separated by an edge assembly is given by equation (1). (1) RHL = G 1 + G 2 + ... + G n + S 1 + S 2 + ... + S n where RHL is the resistance to edge heat loss at the edge of the unit in hour - °F/BTU/inch of unit perimeter (Hr-°F/BTU-in.) G is the resistance to heat loss of a sheet in Hr-°F/BTU-in. S is the resistance to heat loss of the edge assembly in Hr-°F/BTU-in. For an insulating unit having two sheets separated by a single edge assembly equation (1) may be rewritten as equation (2). (2) RHL = G 1 + G 2 + S 1 The thermal resistance of a material is given by equation (3). (3) R = L/kA where R is the thermal resistance in Hr-°F/BTU-in. k is thermal conductivity of the material in BTU/hour-inch-°F. l is the thickness of the material as measured in inches along an axis parallel to the heat flow. A is the area of the material as measured in square inches along an axis transverse to the heat flow. The thermal resistance for components of an edge assembly that lie in a line substantially perpendicular or normal to the major surface of the unit is determined by equation (4). (4) S = R 1 + R 2 + ... + R n where S and R are as previously defined. In those instances where the components of an edge assembly lie along an axis parallel to the major surface of the unit, the thermal resistance (S) is defined by the following equation (5). (5) R = 1 1 R 1 + 1 R 2 + ··· + 1 R n where R is as previously defined. Combining equations (2), (4) and (5), the resistance of the edge of the unit 20 shown in Fig. 2 to heat flow may be determined by following equation (6). (6) RHL = R 22 + R 24 + 2R 32 + 2R 34 + 1 1 R 42 + 1 R 38 + 1 R 44 where RHL is as previously defined, R 22 and R 24 are the thermal resistance of the glass sheets, R 32 is the thermal resistance of the adhesive layer 32, R 44 is the thermal resistance of the adhesive layer 44, R 34 is the thermal resistance of the outer legs 34 of the spacer 30, R 42 is the thermal resistance of the base 42 of the spacer 30, R 38 is the thermal resistance of the adhesive layer 38, and R 26 is the thermal resistance of the middle sheet 26. For ease of discussion, equation (6) does not consider the thermal conducting contribution of the intermediate sheet 26. If the thermal conductivity contribution of the intermediate sheet 26 were considered, it is expected that the value of RHL in equation (6) would be about 10% higher than the value calculated without considering the contribution of the thermal conductivity of the intermediate sheet 26. In the RES-value given in the specification and claims the RES-value does not include the contribution of the intermediate sheet 26. Although equation (6) shows the relation of the components to determine edge resistance to heat loss, Equation 6 is an approximate method used in standard engineering calculations. Computer programs are available which solve the exact relations governing heat flow or resistance to heat flow through the edge of the unit. One computer program that is available is the thermal analysis package of the ANSYS program available from Swanson Analysis Systems Inc. of Houston, PA. The discussion of the edge resistance of the edge assembly (excluding the outer glass sheets) will now be considered. The edge resistance of the edge assembly is defined by the inverse of the flow of heat that occurs from the interface of the glass sheet 22 and adjacent sealant layer 32 at the inside side of the unit to the interface of glass sheet 24 and adjacent sealant layer 32 at the outside side of the unit per unit increment of temperature, per unit length of edge assembly perimeter (including the intermediate sheet). The outer glass sealant interfaces are assumed to be isothermal to simplify the discussion. Support for the above position may be found, among other places, in the paper entitled Thermal Resistance Measurements of Glazing System Edge-Seals and Seal Materials Using a Guarded Heater Plate Apparatus written by J. L. Wright and H. F. Sullivan ASHRAE TRANSACTIONS 1989, V.95, Pt.2. In the discussion of the instant invention and in the claims, RES-value is defined as the resistance to heat flow of the edge assembly e.g. the edge assembly 28 in Fig. 2 and the edge assembly 52 in Fig. 3, per unit length of perimeter. With continued discussion of the instant invention, the materials of the adhesive layers 32 and the layer 44 are not limiting to the invention and are preferably a material that is moisture and/or gas impervious to prevent the ingress of moisture into the compartment between the sheets. Although not limiting to the invention, butyl hot melts of the type sold by H. B. Fuller e.g. H. B. Fuller 1191 may be made in the practice of the invention. Units filled with an insulating gas e.g. Argon preferably have the adhesive layer 32 and the layer 44 of a moisture and/or gas impervious material to maintain the insulating gas in the compartment between the sheets 24, 26 and 26, 22. It is recommended that the adhesive layer 32 or sealant layer 32 be thin and long to reduce the diffusion of the insulating gas out of the compartments of the unit or atmosphere's gas into the compartments of the unit. More particularly, increasing the thickness of the layer 32 i.e. the distance between the glass sheet and the adjacent leg of the spacer while keeping all other conditions constant increases the diffusion rate, and increasing the length of the layer 32 i.e. the distance between the top of the outer leg of the spacer and the peripheral edge of the sheets or the outer surface 46 of the spacer 30 as viewed in Fig. 2 while keeping all other conditions constant decreases the diffusion rate of gas through the adhesive layer 32. The invention may be practiced with the adhesive layer 32 having a thickness less than about 0.125 inch (0.32 cm) and more particularly, of about 0.005 inch (0.013 cm) to about 0.125 inch (0.32 cm), preferably about 0.010 inch (0.025 cm) to about 0.020 inch (0.050 cm) and most preferably about 0.015 inch (0.38 cm), and a height of greater than about 0.010 inch (0.025 cm), and more particularly, of about 0.010 inch (0.025 cm) to about 0.50 inch (1.27 cm), preferably about 0.125 inch (0.32 cm) to about 0.50 inch (1.27 cm) and most preferably about 0.200 inch (0.50 cm). As can be appreciated the thickness and length of the layer 32 may change as the moisture and/or gas resistance value of the moisture and/or gas impervious material changes. For example as the resistance value of the material increases, the thickness of the layer 32 may be increased and the length of the layer 32 decreased and as the resistance value of the material decreases, the thickness of the layer 32 should be decreased and the length of the layer 32 should be increased. Adhesives that may be used in the practice of the invention include but are not limited to butyls, silicons, polyurethane adhesives and are preferably butyls and polyurethanes such as H. B. Fuller 1191, H. B. Fuller 1081A and PPG Industries, Inc. 4442 butyl sealant. With respect to the loss of the fill gas e.g. an insulating gas such as Argon from the unit, in practice the length and thickness of the layer 32 are chosen in combination with the gas permeability of the material so that the rate of loss of the fill gas matches the desired unit performance lifetime. The ability of the unit to contain the fill gas is measured using a European procedure identified as DIN 52293. Preferably, the rate of loss of the fill gas should be less than 5% per year and, more preferably, it should be less than 1% per year. The preferred material for the layer 32 should have a moisture permeability of less than 20 gm mm/M 2 day using ASTM F 372-73 and more preferably less than 5 gm mm/M 2 day. As can be appreciated, the spacer 30 should also be made of a material that is moisture and/or gas impervious e.g. metal or plastic of the type disclosed in The EP Application such as but not limited to metal coated steels, stainless steel, gas pervious spacers covered with a metal or polyvinylidene chloride film and/or a halogenated polymeric material. In Fig. 2 there is shown the layer 44 provided on the outer surface 46 of the spacer 30. The layer 44 may be a material similar to the material of the layers 32 and is preferably non-tacky so that the units when stored or shipped do not stick to the supporting surface. Further when the units have the layer 44, the spacer 30 is preferably below the peripheral edges of the sheets 22 and 24 to provide a channel to receive the layer 44. The thickness of the layer 44 is not limiting to the invention and where used increases the RES-value because of the thermal insulating properties of the sealant. The invention may be practiced with no layer 44 to a layer 44 having a thickness of about 0.50 inch (1.27 cm), preferably about 0.062 inch (0.16 cm) to about 0.250 inch (0.64 cm) and most preferably about 0.150 inch (0.38 cm). Preferably the layer 44 has similar moisture and gas resistance values on the layers 32. With specific reference to Fig. 2, the layer 38 is shaped to provide a groove 48 to receive the peripheral edge of the intermediate sheet 26. The material selected for the layer 38 is a material that is flowable onto the receiving surface 40 of the base 42 of the spacer 30 and adheres thereto as contrasted to a preformed material of the type taught in U.S. Patent No. 4,149,348. Using a flowable material in accordance to the disclosure of the instant invention provides for ease of automating the fabrication of the spacer, edge assembly and/or units, as will be appreciated in the following discussion. The term "flowable material" means a material that may be flowed onto a surface, for example but not limited to the invention by extrusion or pumping. In the selection of the materials for the layer 38, consideration has to be given to maintaining the intermediate sheet 26 in position, e.g. prevent or limit its movement toward one of the outer sheets. Materials that are most preferably used in the practice of the invention are those materials that are flowable and remain pliable after flowing and materials that are flowable and harden e.g. are dimensionally stable after flowing. The term "pliable materials" means materials that have a Shore A Hardness of less than 45 after 10 seconds under load. Pliable materials that may be used in the practice of the invention have a Shore A Hardness of less than 40 after 10 seconds. Pliable materials used in the practice of the invention had a Shore A Hardness of 25 with a range of 20-30 after 10 seconds. The term "hardened material" is a material other than a pliable material. In the instance where the intermediate sheet 26 is to be held in position only by the shaped layer 38, the layer 38 should be a material that is flowed onto the surface 40 of the spacer to provide the groove layer 38, and, thereafter, the material is sufficiently rigid to maintain the intermediate glass sheet in position. In the instance where the material is flowed onto the base and is not sufficiently rigid, it is recommended that facilities be provided to secure the intermediate glass in position. Also if the material of the layer 38 requires time to become sufficiently rigid and the unit is to be moved prior to setting of the layer 38, it is recommended that facilities be provided to secure the intermediate glass in position. The preferred manner in either instance is to use the spacer 30 alone or in combination with the layer 38 in a manner to be discussed below. Other external facilities such as spacer blocks may be used in the practice of the invention. The EP Application teaches a spacer frame having a continuous corner which may be used in the practice of the invention to limit movement of the intermediate sheet 26. With reference to Fig. 2, the continuous corners are formed by portions 58 (see Fig. 2) of the legs 34 and 36 of the spacer 30 biased toward one another at the corner over the receiving surface 40 of the spacer 30. By selectively removing material from the biased portions 58 of the legs of the spacer, a space is provided between the biased portions to accommodate the intermediate sheet. To prevent damage to the intermediate sheet when such sheet is made of glass by contacting the bent portions 58, the space between the bent portions can be increased in a manner discussed below. As the bent portions 58 of the legs 34 and 36 are urged toward one another, portions 60 of the shaped layer 38 are moved against the intermediate glass sheet and are shown by numeral 60 in Fig. 2. As can be appreciated, the spacer of The EP Application may be used with material that is sufficiently rigid to hold the sheet as well as materials that are not sufficiently rigid. The further advantage of the continuous corner is that it provides a continuous non-permeable corner to moisture and/or gas penetration. In the instance where the layer 38 is to carry the desiccant to keep the space between the sheets i.e. compartments dry, the material should be a moisture pervious material. Although the invention is not limited thereto, materials having a permeability greater than 2 gm mm/M 2 day as determined by the above reference to ASTM F 372-73 are recommended in the practice of the invention. As can now be appreciated, the invention is not limited to the number of corners of a unit that may have bent portions 58 to limit movement of the intermediate sheet 26. For a rectangular unit, two opposite corners having bent portions 58 are sufficient to limit movement of the intermediate sheet toward the outer sheets; however, four corners having bent portions 58 are recommended. In the practice of the invention a unit similar to the unit 20 shown in Figs. 1 and 2 was made having rectangular shaped coated, clear glass sheets 22, 24 and uncoated, clear glass sheet 26. Each of the outer glass sheets 22 and 24 had a length of about 42-7/8 inches (108.9 cm) and a width of about 19-3/4 inches (50.17 cm). The intermediate sheet had a length of about 42-1/2 inches (107.95 cm) and a width of about 19-3/8 inches (49.2 cm). The glass sheets 22 and 24 each had on a major surface a coating of the type made by PPG Industries sold under its registered trademark Sungate® 100 coated glass. The coated surface of each of the sheets 22 and 24 faced the intermediate sheet 26. A spacer having four continuous corners was made as follows. With reference to Fig. 4, a flat tin coated steel strip 70 has a length of about 126 inches (320 cm), a width of about 1.30 inches (3.302 cm) and thickness of about 0.010 inch (0.25 mm) with a tapered and swedged end 72 having a hole 74. Opposite end 76 has a hole 78 and receives the end 72 when the spacer is positioned around the intermediate sheet. The taped end 72 had a length of about 1-1/2 inch (3.81 cm). Space at locations about 1.5 inches (3.8 cm), about 21-1/8 inches (53.65 cm), about 63-7/8 inches (162.24 cm), and about 83-1/2 inches (212.09 cm) from the end 72, material was removed from opposite edge portion of the substrate 70 to provide a set of pair of notches 80, 82, 84 and 86 respectively. The notched areas form the bent portions 58 (see Fig. 2), and the notches provide for the bent portions to be a sufficient distance so as to receive the intermediate sheet. Crease lines 88 were provided at the notches as shown in Fig. 4 for ease of bending the bent portions. Each of the notches of the set of pair of notches 82, 84 and 86 has a length of about 0.536 inch (1.36 cm) at the edge 90 of the substrate, a depth of about 0.170 inch (0.43 cm) as measured from the edge 90 of the substrate toward the center of the substrate. The notches 80 were similar in size as the notches 82, 84 and 86 but the left side of the notch as shown in Fig. 4 were further cut to accommodate the end 72. The distance between the points of pairs of notches depends on the width of the base i.e. the desired spacing between the outer sheets. The unit made had the point of the crease lines spaced about 0.282 inch (0.71 cm) from the edge of the substrate to provide the base with a width of about 21/32 inch (1.67 cm). After the substrate 70 had the notches, crease lines and holes, the substrate is shaped to provide the spacer 30 with the U-shaped cross section. With reference to Fig. 2, the ends of the upright legs 34 and 36 are radiused inwardly to provide stability to the spacer e.g. to reduce flexing of the spacer 30 prior to bending it around the glass sheet 26. After the substrate is shaped, the shaped layer 38 were provided by extruding H. B. Fuller HL-5102-X-125 butyl hot melt matrix having a desiccant therein is flowed onto the base of the spacer in using a nozzle arrangement to be discussed below incorporating features of the invention. As can be appreciated, the invention is not limited to the equipment for providing the shaped layer 38. Each of the raised portions of the shaped layer 38 had a height of 0.125 inch (0.32 cm) and a width of 0.255 inch (0.64 cm) to provide a groove having a depth of 0.093 inch (0.23 cm) and a width of 0.125 inch (0.32 cm). It is preferred to have the material of the layer 38 under the sheet to eliminate any contact between the sheet and the base of the spacer to prevent damage to the edge of the sheet. In the practice of the invention the flat substrate was cut, notched, shaped, and the adhesive applied using the nozzle of the instant invention on, equipment sold by Glass Equipment Development Inc. of Twinsburg, Ohio, Model No. HME 55 PHE-L. Although not limiting to the invention, after the extrusion of the shaped layer 38, the layers 32 are extruded onto the outer walls of the outer legs 34 and 36 of the spacer 30. The sealant adhesive of the layer 32 used was sold by H. B. Fuller as H. B. Fuller 1191 hot melt butyl. The layer 32 had a thickness of about 0.020 inches (0.05 cm) and a height of about 0.300 inch (0.76 cm). As can be appreciated, the shaped layer 38 may be extruded onto the base of the spacer before, after, or during the extrusion of the layers 32 onto the side of the spacer. The intermediate sheet 26 was positioned in the groove 48 of the shaped layer 38 between the pair of notches 82 and 84. The spacer between the pair of notches 84 and 86 was bent to position the groove 48 of the layer 38 between the notches 84 and 86 about the edge of the sheet; the spacer between the pair of notches 86 and the end 76 was bent to position the sheet in the groove 48 of the layer 38 therebetween. The tapered end 72 was bent to a 90 ° angle, and the spacer was bent to position the groove 48 of the spacer layer 38 between the pair of notches 80 and 82 about the intermediate sheet. The tapered end 72 was telescoped into the end 76 of the spacer. As the spacer was positioned about the glass sheet 26, the bent portions 58 at the corners moved the adhesive of the shaped layer 38 toward the corner of the glass sheet 26 as previously discussed. The outer glass sheets 22 and 24 were thereafter positioned over the sealant adhesive 32 and biased toward one another to flow the adhesive 32 and secure the outer glass to the spacer. Thereafter the adhesive 44 was flowed into the channel formed by the peripheral edges of the sheets and the base of the spacer. As can be appreciated the holes 74 and 78 in the substrate for the unit made were aligned with each and with the edge of the intermediate sheet. Therefore the hole was sealed with polyol polyisobutylene and sealed over with the adhesive layer 44. In the practice of the invention, it is recommended that the hole or holes (shown in Fig. 4 as dotted lines 92) be offset from the intermediate sheet 26 and a close end rivet used to secure the ends of the spacer together. In this case the polyol polyisobutylene is not required to seal the compartment. The discussion will now be directed to a nozzle used to provide the shaped layer 38. With reference to Figs. 5-7 there is shown nozzle arrangement 100 having a conditioning chamber 102 and a nozzle 104 secured thereto in any convenient manner e.g. by screws. The conditioning chamber 102 is connected by hose or conduit 106 to a supply of the adhesive material (not shown). In the instance where the material is a hot melt adhesive, the conditioning chamber 102 is provided with heating elements to heat the adhesive to its flow temperature; in the instance where the adhesive is a two component adhesive, the adhesive is mixed in the conditioning chamber 102. With specific reference to Figs. 6 and 7, the nozzle 104 has a base 108 supporting a raised platform 110 having a pair of opposite flat sides 112 clearly shown in Fig. 6. The platform 110 has a forming surface including a forming tip 114 that forms the shaped layer 38 in a manner to be discussed. The forming tip 114 has a generally arrow shaped end 116 narrower than opposite end 118. The end 116 is lower in height than the end 118 with the end 118 sloping toward the platform 110 as shown by numeral 120 in Fig. 7. In practice the U-shaped spacer 30 advances from left to right as shown in Fig. 7. As the lead end of the spacer 30 engages the tip 114 the sloped end 120 biases the leading end of the spacer downward as viewed in Fig. 7 against conveyor 122 in those instances where the lead end of the spacer is raised. As the spacer 30 advances past the nozzle 104 the adhesive is extruded through holes 124 and 126 onto the base of the spacer as the forming tip 114 shapes the adhesive to provide the shaped layer 38 on the base of the spacer. In the practice of the invention for making the unit discussed above, the base 108 had an outside diameter of about 2-1/2 inches (6.35 cm) and a thickness of about 1/4 inch (0.635 cm). The platform 110 had a height of about 3/8 inch (0.95 cm). The platform was circular with a diameter of about 0.52 inch (1.37 cm) except for the flat sides 112 that are spaced from each other about 0.485 inches (1.23 cm) and each have a length of about 0.23 inch (0.53 cm). The tip 114 at the narrow end 116 has a width of about 0.028 inch (0.020 cm) and expands toward the center line of the tip to a width of about 0.062 inch (0.157 cm). The slope surface 120 starts at the edge of the platform 110 and terminates about 0.125 inch (0.37 cm) therefrom. With reference to Fig. 7, the tip 114 at the sloped end 118 has a height of about 0.080 inch (0.20 cm) and at the narrow end 116 of about 0.065 inch (0.165 cm). The holes 124 in the platform each had a diameter of about 0.120 inch (0.3 cm) and the hole 126 in the tip had a diameter of about 0.093 inch (0.236 cm). In practice, H. B. Fuller adhesive HL-5102-X-125 having a desiccant therein is heated to about 250°F (121°C). As the U-shaped spacer 30 moves past the nozzle 104, the platform 110 is positioned between the outer legs 34 and 36 of the spacer with the highest portion of the tip 114 e.g. end 118 of the tip spaced about 1/32 inch (0.08 cm) from the base 42 of the spacer 30. As the spacer 30 moves past the nozzle the sloped end 120 urges the leading edge of the spacer downward, if lifted, toward the conveyor as adhesive is extruded from the holes 124 and 126 to provide the shaped layer 38. The narrow portion of the tip and the step of the tip prevent tailing of the adhesive when the flowing e.g. pumping or extrusion of the material is stopped. It is expected that providing a step for the platform 110 similar to that of the tip will further ensure elimination of tailing. With reference to Figs. 8 and 9, there is shown nozzle 130 having platform 132. The nozzle 130 is similar to the nozzle 104 except the platform 132 is provided with a lower portion 134 and a raised portion 136 and the platform and nozzle where the change in elevation occurs is radiused surface 140 as shown in Fig. 8. It is expected that the radiused surfaces 140 and change in elevation will eliminate tailing. The term "tailing" as used herein is the noted effect that occurs when the flowing e.g. pumping or extrusion of the material is stopped but due to the adhesive adhering to the nozzle, strings of adhesive are pulled. In the instance where an insulating unit e.g. the unit 20 shown in Figs. 1 and 2 has an insulating gas between adjacent glass sheets 22, 26 and 26, 24, the insulating gas may be flowed into the compartment between the glass sheets in any convenient manner. For example and with reference to Figs. 10 and 11 there is shown injector arrangement 150 that may be used to move an insulating gas into a compartment while removing air in the compartment through a single spacer hole. The injector arrangement 150 includes a spring biased bifurated member 152 having outer legs 154 and 156 connected to a base 158. The spring member 152 is made of spring metal such that the legs 154 and 156 are spring biased toward one another to engage the glazing unit in a manner discussed below. The member 152 used in the practice of the invention was a binder clip. An inner tube 160 has an enlarged end 162 mounted in a housing 164 and passes through the housing. The tube 160 extends beyond the housing and outer tube 166 and is shown in Fig. 11 as end 168. The end 168 of the tube 160 is sized for insertion through the base 42 of the spacer 30 (see Fig. 2). The housing 164 has a hole 170 that provides access to the hollow interior of the housing. The outer tube 166 has end connected to the housing 164 and has external threads thereon. The housing arrangement is secured to the base 158 of the member 152 by passing the outer tube through a hole (not shown) in the base 158. A nut 172 threaded on the outer tube 166 engages O rings 174 on each side of the base 158 about the tube 166 to capture the base between the housing 164, the O rings 174 and the nuts 172 as shown in Fig. 11. In practice the end 162 of the inner tube 160 is connected to an Argon supply (not shown), and the injector arrangement clamped to the unit by spreading the legs 154 and 156 apart by urging members 180 and 182 toward one another and inserting the end 168 of the inner tube 160 in a hole (not shown) in the spacer e.g. aligned holes in the substrate 70. The members 180 and 182 are released to clamp the nozzle arrangement 152 on the edge of a unit as shown in Fig. 12. It is recommended that the clamp engage the glass at the edge assembly of the unit e.g. edge assembly 28 of the unit 20 shown in Fig. 2, to prevent damage to the glass. As Argon moves into the unit through the inner tube 168, air in the compartment between the sheets is displaced and moves out of the compartment through the annulus between the outer tube 166 and the inner tube 160 through the housing 164 and out of the hole 170. After the compartment is filled with Argon the nozzle is removed and the hole sealed in any convenient manner e.g. with a sealant or a closed end rivet. When the unit has one chamber e.g. as taught in The EP Application, one nozzle centrally located as shown in Fig. 12 is preferred. When the unit has two or more compartments e.g. unit 20 shown in Fig. 2, one nozzle may be used for each compartment or a nozzle arrangement having two nozzles may be used e.g. nozzle arrangement 194 shown in Fig. 13. As can now be appreciated the invention is not limited to making a triple glazed unit. For example as shown in Fig. 14 there is a unit 200 having four glass sheets 22, 24 and 202. When more than three sheets are used, a blank or spacer 204 may be used between glass sheets 202 shown in Fig. 14. Further, the intermediate sheet may have a hole drilled therein to interconnect the compartments of the triple glazed unit.

Claims: A unit (20) having at least three sheets (22,24,26), comprising: a pair of outer sheets (22,24); a spacer (30,54) between the sheets (22,24,26) to maintain the sheets (22,24,26) in spaced relationship to one another, the spacer (30,54) having a receiving surface (40,56); means for securing the sheets (22,24,26) to the spacer (30,54) to provide a compartment between the pair of outer sheets (22,24) with the receiving surface (40,56) of the spacer (30,54) facing the compartment; a sheet (26) defined as an intermediate sheet (26); characterized by a first portion (38) of a pliable material on selected portions of the receiving surface (40,56) of the spacer (30,54) adjacent one of the outer sheets (22,24) and a second portion (38) of a pliable material on selected portions of the receiving surface (40,56) of the spacer (30,54) adjacent the other one of the outer sheets (22,24) spaced from the first portion to provide a groove (48); wherein the spacer (30) has a base (42) and a first outer leg (34) and a second outer leg (36) with the receiving surface (40) between the outer legs (34,36), one of the outer sheets (22) secured to the outer surface of the first outer leg (34) and the other one of the outer sheets (24) secured to the outer surface of the second outer leg (36), means cooperating with said first and second portions (38) of pliable material for maintaining the intermediate sheet (26) in the groove (48) in a substantially fixed relationship to the pair of outer sheets (22.24) to provide the glazing unit (20) having the at least three sheets (22,24,26); wherein the maintaining means includes at least one of the following: selected portions (58) of the outer legs (34,36) of the spacer (30) bent toward and spaced from one another with portions of the intermediate sheet therebetween, and raised portions (60) of pliable material, to limit movement of the intermediate sheet (26) toward one of the outer sheets (22,24). The unit (20) of claim 1 wherein the base (42) and the outer legs (34,36) of the spacer (30) form a generally U-shaped cross section of the spacer (30). The unit (20) of claim 2 wherein the maintaining means includes portions of the spacer (30) selectively engaging portions of the intermediate sheet (26). The unit (20) of claim 2 wherein the unit (20) has corners and the selected portions (58) of the outer legs (34,36) of the spacer (30) are bent at selected corners of the unit. The unit (20) of claim 2 wherein the unit has corners and the selected portions (58) of the outer legs (34,36) are between the corners. The unit (20) of claim 1 wherein the spacer (30,54) has an outer surface (46) opposite the receiving surface (40,56) and the outer surface (46) of the spacer (30,54) is aligned with the peripheral edges of the sheet (22,24). The unit (20) of claim 1 wherein the spacer (30,54) has an outer surface (46) opposite the receiving surface (40,56) and the outer surface (40) is recessed to provide a peripheral channel around the unit (20) and further including a sealant in the channel. The unit (20) of claim 2 wherein the means for securing the sheets (22,24) to the spacer (30) includes a layer (32) of a moisture and gas impervious sealant between outer surface of outer legs (34,36) of the spacer (36) and marginal edge portion of adjacent outer sheet (22,24). The unit (20) of claim 8 wherein the layer (32) has a thickness of about less than 0.32 cm (0.125 inch) as measured between the outer surface and marginal edge portion of adjacent outer sheet (22,24) and a height of greater than about 0.025 cm (0.010 inch) as measured from the opposite surface of the substrate toward the compartment. The unit (20) of claim 9 wherein the layer (32) has a thickness of about 0.050 cm (0.020 inch) and a height of about 0.76 cm (0.30 inch). The unit (20) of claim 1 wherein the pliable material of at least one of first or second raised portions (60) is a moisture and/or gas pervious material and further includes a layer (38) of the pliable material between the substrate and peripheral edge of the sheet (26). The unit (20) of claim 11 wherein the pliable material of the first and second raised portions (38) and the layer (38) of the pliable material is a moisture and/or gas pervious material. The unit (20) of claim 12 wherein the pliable material has a of Shore A Hardness of less than 45 after 10 seconds. The unit (20) of claim 13 wherein a desiccant is dispersed in the pervious material. The unit (20) of claim 1 wherein the sheets (22,24,26) are glass sheets. The unit (20) of claim 15 wherein at least one of the sheets (22,24,26) has an environmental coating or at least one major surface. The unit (20) of claim 16 wherein the environmental coating is a coating to selectively pass predetermined wavelength ranges of light and further having a reflective coating on a major surface of one of the sheets (22,24,26). The unit (20) of claim 15 wherein the pair of outer sheets (22,24) has similar peripheral configuration and peripheral dimensions. The unit (20) of claim 15 wherein the pair of outer sheets (22,24) has different peripheral configurations and peripheral dimensions. The unit (20) of claim 15 wherein the intermediate sheet (26) has peripheral dimensions equal to or less than one of the pair of outer sheets (22,24). The unit (20) of one claims 1 or 2 wherein the spacer (30) and the sheets (22, 24, 26) have four corners to provide the unit (20) with four corners and wherein : the spacer (30) at at least two corners has the first and second wall portions (58) bent toward one another; the maintaining means including the bent portions (58) of the first and second walls (34,36) of the spacer bent toward one another and spaced a sufficient distance to receive the third glass sheet (26) therebetween with the bent portions (58) biasing the first and second raised portions (60) of the pliable material toward the adjacent corner of the sheets (22,24,26), and the securing means including a layer (32) of a moisture and/or gas impervious adhesive on outer surfaces of the first and second walls (34,36) of the spacer (30) to secure marginal edge of ones of the glass sheets (22,24) to ones of the outer surfaces of the spacer (30) to provide a sealed compartment between the outer glass sheets (22,24); and further comprising: an insulating gas between the outer glass sheets (22,24) and intermediate sheet (26); a desiccant in the pliable material; a layer (38) of the pliable material between the receiving surface (40) and peripheral edge of the intermediate sheet (26); the sheets (22,24,26) are glass sheets, and the spacer (30), pliable material and moisture impervious adhesive form an edge assembly (28) having a RES-value equal to or greater than 10 as determined using ANSYS. The unit (20) of claim 21 has a RES-value equal to or greater than 50 as determined using ANSYS. The unit (20) of claim 22 has a RES-value equal to or greater than 75 as determined using ANSYS. The unit (20) of claim 23 wherein the unit at four corners has the first and second wall portions (58) bent toward one another. The unit (20) of claim 24 wherein the unit has four glass sheets. A method of making an insulating unit (20) having at least three sheets comprising the steps of: providing three sheets (22,24,26), two of the sheets defined as a first outer sheet (22) and a second outer sheet (24), and the third sheet defined as an intermediate sheet (26); providing a spacer (30,54) of a predetermined length, the spacer having a receiving surface (40,56); flowing material on the receiving surface (40,56) of the spacer (30,54) to provide spaced beads having a groove (48) on the receiving surface (40,56); forming the spacer (30,54) into a spacer frame encircling the intermediate sheet (26) with the peripheral edge portions of the intermediate sheet in the groove (48); preventing substantial movement of intermediate sheet (26) by positioning the intermediate sheet (26) in the groove (48) while practicing at least one of the following steps: bending portions (58) of the outer legs (34,36) of the spacer (30) toward one another and foward the intermediate sheet (26), and moving portions (60) of pliable material of the spaced beads against the intermediate sheet (26) during the practice of the step of forming the spacer (30,54) into the spacer frame; securing the spacer (30,54) and outer sheets (22,24) together to provide a compartment between one of the outer sheets (22) and the intermediate sheet (26) and the other outer sheet (24) and the intermediate sheet (26). The method of claim 26 wherein the flowable material hardens sufficiently to limit movement of the intermediate sheet (26) toward one of the outer sheets (22,24) and said preventing movement step includes hardening of the flowable material. The method of claim 26 wherein the flowable material is a pliable material. The method of claim 26 wherein the sheets (22,24,26) are glass sheets. The method of claim 29 further including the step of providing an environmental coating on at least one of the major surfaces of at least one of the sheets (22,24,26). The method of claim 30 wherein the environmental coating is a coating to selectively pass predetermined wavelength ranges of light and further including the step of providing a reflective coating on another at least one of the major surfaces of at least one of the sheets (22,24,26). The method of claim 26 wherein the sheets (22,24,26) are colored glass sheets. The method of claim 26 wherein said step of providing a spacer (30) includes the step of shaping a flat substrate (70) to provide a spacer (30) having a base (42), a first outer leg (34) extending upwardly from the base, a second outer leg (36) extending upwardly from the base to provide the spacer (30) with a generally U-shaped cross sectional configuration, wherein the receiving surface (40) is the surface of the base (42) facing the space between the sheets (22,24,26). The method of claim 33 wherein the step of shaping the substrate (70) includes: selectively removing edge portions of the substrate (70) to provide sets of pair of opposed notches (80,82,84,86) defining bending lines (88) such that during the practice of said encircling step the spacer (30) formed from the substrate (70) is bent along bending lines (88) between the opposed notches (80,82,84,86); said providing spaced beads include the step of providing a layer (38) of material having a generally U-shaped cross section on surface (40) of the spacer (30) between the outer legs (34,36) and facing the space between the sheets (22,24,26) defining the necessary surface. The method of claim 33 wherein prior to practicing the step of shaping the flat substrate (70) the step of providing spaced beads is practiced to provide a flowable material having a generally U-shaped cross section on the flat substrate (70) spaced inwardly from the edges of the substrate (70). The method of claim 26 wherein the step of providing three sheets (22,24,26) includes the step of providing glass sheets. The method of claim 33 wherein said step of flowing a material includes the step of providing a desiccant in the flowable material. The method of claim 37 wherein the step of flowing a material includes the step of providing a pliable material having a desiccant and the maintaining step includes biasing the wall portions (34,36) of the spacer toward one another to move the pliable material toward the third sheet (26), the bent wall portions (58) limiting movement of the third sheet (26) toward the first or second outer sheet (22,24): and said securing step includes the step of providing a layer (32) of a moisture and/or gas pervious adhesive between the marginal edges of the first and second sheet (22,24) and adjacent outer surface of the wall portions (34,36). The method of claim 38 wherein the glazing unit (20) has a rectangular shape and the bent wall portions (58) are at selected corners. The method of claim 26 wherein the flowable material is a moisture and/or gas pervious material that is dimensionally stable after it is flowed and has a desiccant therein. The method of claim 37 wherein the step of securing the spacer (30) and outer sheets (22,24) together includes the step of providing a layer (32) of a moisture and/or gas impervious material between the sheets (22,24) and spacer (30) and further including the step of selecting the material for the spacer layer (38) of flowable material and the layer (32) of moisture and/or gas impervious material to provide an edge assembly (28) having a RES-value of equal to or greater than 10 as determined using the ANSYS program. The method of claim 26 further including the step of providing an insulating gas between one of the outer sheets (22) and the intermediate sheet (26) defined as a first compartment and the other one of the outer sheets (24) and the intermediate sheet (26) defining a second compartment. The method of claim 41 wherein the step of providing an insulating gas includes the steps of: providing external access through the spacer (30) to the first and second compartments; providing an injector arrangement (150) having: a C-shaped clamp (152) having the outer legs (154,156) biased toward one another; members (180,182) on each of the outer legs (154,156) to bias the outer legs (154,156) away from one another; an inner tube (160) having a free end (168) and the other end (162) connected to a supply of insulating gas; an outer tube (166) surrounding portions of the inner tube (160); biasing the members (180,182) toward one another to increase the distance between the outer legs (154,156) of the clamp (152); mounting the clamp (152) on the edge of the unit (20) with the free end (168) of the inner tube (160) inserted through the spacer (30); releasing the members (180,182) to secure the clamp (152) on the edge of the unit (20); moving the insulating gas through the inner tube (160) into a compartment while moving the air in the compartment through the outer tube (166); and sealing the external access after the compartment is filled with the insulating gas. The method of one of claims 26 to 41 further including the use of a nozzle (104,130) for extruding a flowable material, the nozzle (104,130) comprising: a platform (110,132); a shaping member (114) mounted on the platform (132); and a hole (124) in the platform (110,132) on each side of the shaping member (114) and a hole in the platform (110,132). The method of claim 44 wherein the shaping member (114) has one end (116) that has converging sides defined as the first and the other end (118) with generally parallel sides defined as the second side. The method of claim 45 wherein the second side has a sloping surface (120). The method of claim 46 wherein the elevation of the first end (116) and the second end (118) are different. The method of claim 47 wherein the surface of the first end (116) is closer to the platform (110,132) than the second end (118). The method of claim 48 wherein the opposed sides (112) of the platform (110,132) are flat and parallel to one another. The method of claim 49 wherein the platform (132) has different elevations defined by a wall (140) that is radiused. The method of claim 50 wherein the nozzle (104,130) further includes: a chamber (102) having heating means; a base (108) secured to an end of the chamber (102), and the platform (110,132) secured to the base.

Inventors: KOVACIK PAUL J, LEOPOLD EDMUND A, KOVACIK, PAUL J., LEOPOLD, EDMUND A.
Applicants: PPG IND OHIO INC, PPG INDUSTRIES OHIO, INC.
Application year: 1994
Main classification: E06B3
IPC codes: B29C47, E06B3, C03C27