Process for manufacturing aluminum alloy sheets excellent in strength and deep drawing formability

Abstract: An aluminium alloy sheet of an aluminium alloy containing 5 to 10 wt.% of Mg, 0.0001 to 0,01 wt.% of Be, 0.01 to 0.05 wt. % of Cr, 0.005 to 0.1 Wt.% of Ti or both 0.005 to 0.1 wt. % of Ti and 0.00001 to 0.005 wt. % of B, Fe and Si as impurities respectively regulated to be less than 0.2 wt.% other inevitable impurities and Al, wherein 0.1 to 0.5 vol.% of intermetallic compounds containing Cr with the mean diameter of not more than 0.2 µm are dispersed into the metal structure of the Al alloy sheet, and the mean grain diameter of the metal structure is in the range of 5 or 30 µm. A process of manufacturing the aluminium alloy sheet comprises subjecting an homogenized alloy slab to hot rolling, carrying out a precipitation treatment of intermetallic compounds containing Cr at least once at 230 to 360°C for 1 to 100 hours subjecting the resultant alloy sheet to final cold rolling and then heating the finally cold rolled alloy sheet at 400 to 500°C for not more than 120 seconds.

Description: BACKGROUND OF THE INVENTION Field of the Invention: This invention relates to aluminum alloy sheets suitable to sheet materials for press forming of auto body panels, air cleaners and oil tanks or like press-formed products which require strength and formability, and a process for manufacturing such aluminum alloy sheets. Description of the Prior Art: In general, cold rolled steel sheets have been largely used as sheet materials for press forming of auto body panels or the like. In recent years, however, there has been a great demand that aluminum alloy sheets are used instead of the cold rolled steel sheets in order to make auto bodies lightweight for improving the fuel consumption thereof. In prior art, as for an aluminum alloy sheet for press forming, which requires strength and formability, there is known O stock of Al-Mg alloy 5052 (chromium alloy containing 2.5 wt.% of Al and 0.25 wt.% of Mg), O stock of Al-Mg alloy 5182 (manganese alloy containing 4.5 wt.% of Al and 0.35 wt.% of Mg ), T4 stock of Al-Cu alloy 2036 (magnesium alloy containing 2.6 wt.% of Al, 0.25 wt.% of Cu and 0.45 wt.% of Mn) or the like. Of all these items described above, the Al-Mg alloy sheets are excellent in both deep drawing formability and strength and often used for deep drawing press-formed products such as inner members. Normally, the Al-Mg alloy sheets for press forming are manufactured by a process including the steps of production of slabs for rolling, homogenizing, hot rolling, cold rolling and final annealing. Additionally, an intermediate annealing step is carried out on the way of the cold rolling step, if necessary. In the case where the sheet material particularly requires flatness, a straightening step is often carried out by a tension leveler, a roller leveler, skin pass rolling or like means after the annealing step. The formability of the conventional Al-Mg alloy sheet manufactured as described above is superior to that of other aluminum alloy sheets but inferior to that of the cold rolled steel sheet. Therefore, there is such a problem as the Al-Mg alloy sheet is easily cracked at the time of press forming, in comparison with the cold rolled steel sheet. Further, since the Al-Mg alloy sheet is inferior in strength to the cold rolled steel sheet, it is hard to make the Al-Mg alloy sheet thinner. Thus, there is also such a problem as the Al-Mg alloy sheet cannot always satisfactorily produce the effect of making the products such as auto bodies lightweight. On the other hand, it has already been known that the elongation of the Al-Mg alloy sheet is improved in proportion to Mg content therein. It has been thus examined an aluminum alloy having Mg content higher than that of the conventional Al-Mg alloy (2.5 to 5.0 wt.% of Mg) in order to improve the elongation. For instance, Japanese Patent Laid-open No. 4-147936 has disclosed an aluminum alloy sheet containing 4 to 8 wt.% of Mg, 0.05 to 0.7 wt.% of Cu, 0.01 to 0.3 wt.% of Mn and 0.002 to 0.01 wt.% of Be and having grain diameters set to be in the range of 30 to 100 µm. In this manner, the Al-Mg alloy sheet with high Mg content has a high elongation percentage and thus has improved in stretch forming formability, bending formability and flanging formability or the like, which are highly correlative to the elongation. However, the conventional Al-Mg alloy sheet with high Mg content described above has the following disadvantages. Namely, the conventional Al-Mg alloy sheet with high Mg content is inferior in deep drawing formability to the cold rolled steel sheet. Particularly, in press forming under the poor lubrication condition as in the case of press forming of auto parts, the Al-Mg alloy sheet with high Mg content is easily cracked at the time of press forming, and thus the productivity is degraded. Further, because of the high Mg content, the strength of the conventional Al-Mg alloy sheet with high Mg content is improved more than that of other aluminum alloy sheets, whereas the strength thereof is still inferior to that of the cold rolled steel sheet, and therefore, it is hard to make the conventional Al-Mg alloy sheet with high Mg content thinner. The present inventors have examined the above-mentioned problems of the conventional Al-Mg alloy sheet with high Mg content in detail, and as a result, they have found out that the higher the strength of a material is, the better the deep drawing formability of an aluminum alloy sheet is, and that an alloy sheet obtained by finely recrystallizing an Al-Mg alloy sheet with properly dispersed intermetallic compounds containing Cr has extremely high strength and is also excellent in deep drawing formability, resulting in leading to the completion of the present invention. In JP-A-4-246.147, there is disclosed an aluminum alloy suitable for automobile body sheet material which contains, by weight, 3.5-6.0 % Mg, 0.05-0.5 % Cu, 0.01-<0.06 % Si, 0.01-<0.08 % Fe, 0.005-<0.5 % Ti, 0.0005-<0.05 % B, 0.05-<100 ppm Be or further one or more of 0.02-<0.3 % Mn, 0.02-<0.2 % Cr, 0.02-<0.3 % V, 0.02-<0.10 % Zr and remainder AL. The document also describes as an example an alloy containing, by weight, 5.10 % Mg, 0.25 % Cu, 0.03% Si, 0.05 % Fe, 0.05 % Mn, 0.04 % Cr, <0.01 % V, <0.01 % Zr, 0.01 % Ti, 0.001 % B, 3 ppm Be and remainder Al. In JP-A-2-057.655, there is disclosed an Al-alloy with excellent formability and chemical treatability before coating. The alloy contains, by weight, 4-6 % Mg, 0.2-1.5 % Cu, 0.01-0.05 % Ti, 0.0001-0.01 % Be or futhermore at least one of 0.02-0.20 % Mn, Cr, Zr and V. The document also discloses as an example an alloy containing by weight, 4.9 % Mg, 0.46 % Cu, 0.02 % Ti, 10 ppm Be, 0.05 % Mn, 0.05 % Cr, 0.10 % Fe, 0.08 % Si and remainder Al. Thus, it is an object of the present invention to provide a process for manufacturing an aluminum alloy sheet having the strength and deep drawing formability which are approximately comparable to those of a cold rolled steel sheet by improving the metal structure of an Al-Mg alloy sheet with high Mg content. A process for manufacturing an aluminum alloy sheet according to the invention comprises the steps of preparing an aluminum alloy slab containing 5 to 10 wt.% of Mg, 0.0001 to 0.01 wt.% of Be, 0.01 to 0.05 wt.% of Cr, 0.005 to 0.1 wt.% of Ti or both 0.005 to 0.1 wt.% of Ti and 0.00001 to 0.05 wt.% of B, eventually 0.05 to 1.0 wt.% of Cu, Fe and Si as impurities respectively regulated to be less than 0.2 wt.%, and the remainders consisting of other inevitable impurities and Al ; homogenizing said aluminum alloy slab at 450 to 540°C for not more than 24 hours ; then subjecting the homogenized aluminium alloy slab to hot rolling to provide the alloy sheet ; carrying out a precipitation treatment of intermetallic compounds containing Cr at least once at 230 to 360°C for 1 to 100 hours, immediately after the hot rolling or on the way of cold rolling following said hot rolling ; then subjecting the resultant alloy sheet to final cold rolling up to a predetermined thickness ; and thereafter heating the finally cold rolled alloy sheet at 400 to 500°C for not more than 120 seconds. Now, with reference to each element other than aluminium contained in the composition of the aluminum alloy sheet described above, the detailed description will be given about the reasons why these elements are selected and why the contents thereof are respectively restricted. Mg is added in order to improve the strength and deep drawing formability of an aluminum alloy sheet to be manufactured. When Mg content is less than 5 wt.%, the effect on addition of Mg is insufficient. On the other hand, when the Mg content exceeds 10 wt.%, the hot workability of the alloy is rapidly lowered, and it becomes hard to manufacture the alloy sheet. Be is added in order to prevent the generation of casting cracks and the oxidation of molten metal at the time of melting and casting and to also prevent the loss of Mg due to the oxidation of the slab under homogenization. When Be content is less than 0.0001 wt.%, the effect on addition of Be is insufficient. On the other hand, when the Be content exceeds 0.01 wt.%, a problem of toxicity arises. Cr is added in order to improve the strength and deep drawing formability of the alloy sheet without lowering the elongation percentage. When Cr is dispersed into the metal structure of the alloy sheet as intermetallic compounds (Al 7 Cr or Al 18 Mg 3 Cr 2 ) containing Cr with a mean diameter of 0.2 µm in the range of 0.1 to 0.5 vol.% by the precipitation treatment which will be described later, the grains of the alloy sheet are made finer to improve the strength and the deep drawing formability. When the mean diameter of the intermetallic compounds containing Cr exceeds 0.2 µm or the dispersed amount thereof is less than 0.1 vol.%, the effect on the dispersion of the intermetallic compounds containing Cr is small. On the other hand, when the dispersed amount exceeds 0.5 vol%, the elongation of the alloy sheet is lowered. When the amount of Cr to be added is less than 0.01 wt.%, the dispersed amount of the intermetallic compounds containing Cr cannot be set to be not less than 0.1 vol.%. On the other hand, when the amount of Cr to be added exceeds 0.05 wt.%, the dispersed amount of the intermetallic compounds containing Cr exceeds 0.5 vol.%. Ti or both Ti and B are added in order to improve the hot workability by homogeneously making the alloy slab structure finer, and to reduce the dispersion in strength and formability after the final annealing. When Ti content is less than 0.005 wt.%, the effect on addition of Ti is small. On the other hand, when the Ti content exceeds 0.1 wt.%, coarse intermetallic compounds are formed to lower the elongation of the alloy sheet. On the other hand, B coexists with Ti to further enhance the effect of making the alloy slab structure finer, it is desirable to add B in the range of 0.00001 to 0.05 wt.%. When B content is less than 0.00001 wt.%, the effect on addition of B is small. On the other hand, when the B content exceeds 0.05 wt.%, coarse TiB 2 compounds are formed to lower the elongation of the alloy sheet. Both Fe and Si are impurities in the alloy, and each content of Fe and Si should be regulated to be less than 0.2 wt.%, respectively. When each content of Fe and Si exceeds 0.2 wt.%, Fe and Si form coarse intermetallic compounds to lower the elongation of the alloy sheet. Further, the hot workability of the alloy is also lowered (i.e., cracks are generated). When the strength and deep drawing formability of the alloy sheet are desired to be further improved, Cu should be added in the range of 0.05 to 1.0 wt.%. When Cu content is less than 0.05 wt.%, the effect on addition of Cu is insufficient. On the other hand, when the Cu content exceeds 1.0 wt.%, the hot workability of the alloy is rapidly lowered. If the total amount of Mn, Zr and V to be added is not more than 0.2 wt.%, the strength of the alloy sheet can be improved more or less without lowering the elongation thereof so much. If the total content of Zn and other inevitable impurities is not more than 0.3 wt.%, there is no particular problem so far as the effects of the invention are concerned. Now, the detailed description will be given with respect to the reasons why the manufacturing conditions are selected as described above in the manufacturing process according to the invention. First of all, an aluminum alloy slab having the above-mentioned component composition is homogenized at 450 to 540°C for not more than 24 hours. The homogenization is carried out in order to attain the uniformity of the distribution of the solute atoms in the alloy slab and to homogenize the structure of the annealed alloy sheet for improving the strength and elongation of the alloy sheet. When the temperature for homogenization is less than 450°C, the effect on the homogenization is insufficient. On the other hand, when the temperature for homogenization exceeds 540°C or the time for homogenization exceeds 24 hours, the loss of Mg due to oxidation becomes remarkable, and the hot rolling cracks are easily generated. The aluminum alloy slab homogenized as described above is then subjected to hot rolling. In the hot rolling, it is desirable that each reduction per pass of at least at the initial three times of rolling pass is lowered (preferably not more than 3%) in order to prevent the generation of hot rolling cracks. Further, it is desirable that the grain diameter of the homogenized alloy slab is set to be not more than 1000 µm and the hot mill entrance temperature is set to be in the range of 320 to 470°C in order to prevent the generation of hot rolling cracks. Immediately after the hot rolling described above or on the way of cold rolling following the hot rolling, the precipitation treatment of intermetallic compounds containing Cr is carried out at least once at 230 to 360°C for 1 to 100 hours. The intermetallic compounds containing Cr (A 7 Cr or Al 18 Mg 3 Cr 2 ) with a mean diameter of not more than 0.2 µm are dispersed and precipitated in the range of 0.1 to 0.5 vol.% into the structure of the alloy sheet due to the precipitation treatment under these conditions. The dispersed intermetallic compounds containing Cr as described above control the grain boundary migration of recrystallized grains in the final annealing of the alloy sheet and regulates the grain growth, so that the grains of the structure of the alloy sheet after the final annealing are made finer. Therefore, the strength and deep drawing formability of the alloy sheet can be improved. In the precipitation treatment described above, when the temperature for precipitation treatment is less than 230°C or the time for precipitation treatment is less than one hour, the effect on the precipitation treatment described above is insufficient. On the other hand, when the temperature for precipitation treatment exceeds 360°C, the intermetallic compounds containing Cr become coarse to result in being ineffective in making the grains of the alloy sheet structure finer in the final annealing, and the strength and deep drawing formability of the alloy sheet are lowered. The alloy sheet processed as described above is subjected to high-temperature and short-time annealing at 400 to 500°C for not more than 120 seconds by, for instance, a continuous annealing line (CAL) or the like, and the mean grain diameter of the metal structure of the alloy sheet is made finer to be in the range of 5 to 30 µm. In the alloy sheet manufactured as described above, the finer the grains are, the more both the strength and deep drawing formability are improved. However, when the mean grain diameter of the alloy sheet structure is less than 5 µm, the reduction of the elongation becomes remarkable, and the deep drawing formability is also lowered. When the mean grain diameter of the alloy sheet structure exceeds 30 µm, both the strength and deep drawing formability of the alloy sheet is lowered. The mean grain diameter of the alloy sheet structure in the range of 10 to 25 µm is available for making the deep drawing formability of the alloy sheet most satisfactorily. Since the mean grain diameter of the metal structure of the aluminum alloy sheet is regulated to be in the range of 5 to 30 µm, the alloy sheet not only improves in strength and deep drawing formability as described above but also shows the following characteristics. Namely, the generation of Luders lines (surface strain figures) can be prevented at the time of deep drawing press-forming of the alloy sheet. Further, the brittleness in processing is extremely improved in the extensive temperature environment (e.g, -100°C to room temperature). As a result, there is no possibility that the materials become brittle and are cracked even in case of press forming under the low temperature environment, and that the press-formed products become brittle in use under the low temperature environment and are cracked on weak impact. When the temperature for high-temperature and short-time annealing is less than 400°C, the recrystallization is insufficient, or the mean grain diameter of the alloy sheet structure becomes less than 5 µm even though the recrystallization is made. On the other hand, when the temperature for the above-mentioned annealing exceeds 500°C, the mean grain diameter exceeds 30 µm. As a result, in either case, the deep drawing formability of the alloy sheet is lowered. According to the high-temperature and short-time annealing under the conditions described above, there is no change in the distributive state of the intermetallic compounds containing Cr in the alloy sheet structure before and after the annealing, and therefore, the distributive state of the intermetallic compounds containing Cr before the annealing can be remained as it is. Further, according to the annealing conditions described above, since the recrystallized grains are equiaxed grains, the grain diameters can be equally measured when being observed either from the sheet surface or from the sheet cross section. When the final annealing described above is carried out in a batch-type furnace, anisotropy is yielded in strength even if the grain diameter may be in the range of 5 to 30 µm. The resultant alloy sheet has a tendency to lower both the elongation and the formability. The alloy sheet subjected to the final annealing as described above can be subjected to straightening by a tension leveler, a roller leveler, skin pass rolling or like means, if necessary. Otherwise, the surface of such finally annealed alloy sheet may be washed with acid or alkali, if necessary. The aluminum alloy sheet manufactured as described above according to the invention is more excellent in strength and deep drawing formability than those of other aluminum alloy sheets, and suitably used for sheet materials for press forming of auto body panels, air cleaners and oil tanks or the like. Further, the generation of Lüders lines can be restrained at the time of deep drawing press-forming. Furthermore, the aluminum alloy sheet of the invention show the excellent characteristics of the brittleness-resistance in processing under the extensive temperature environment (e.g., -100°C to room temperature). BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 shows an enlarged-scale photograph of a metal structure of an aluminum alloy sheet as an embodiment of the invention; and Fig. 2 shows an enlarged-scale photograph of a metal structure of an aluminum alloy sheet manufactured independently of the invention. DESCRIPTION OF THE PREFERRED EMBODIMENT Hereinafter will be described an aluminum alloy sheet and a process for manufacturing same according to the invention in detail on the basis of the following examples. First Example Aluminum alloys having the compositions of alloy samples Nos. 1 to 16 shown in Table 1 were respectively subjected to DC casting (thickness: 400 mm, width: 1650 mm, and length: 4500 mm) by a normal process. Then each of the resultant alloy slabs was homogenized at 490°C for 3 hours, and then subjected to hot rolling up to 5 mm in thickness under the following conditions. Incidentally, the alloys of alloy samples Nos. 1 to 5 in Table 1 have the compositions corresponding to those of Claim 1 of a process of manufacturing an aluminum alloy sheet according to the invention. The alloys of alloy samples Nos. 6 to 8 have the compositions corresponding to those of Claim 2. The alloys of alloy samples Nos. 9 to 16 as comparative examples have the compositions which are those without the range of the invention. In each of the alloy samples given in Table 1, Cu having the content of less than 0.05 wt.% is impurities. The alloy sheet subjected to hot rolling as described above was then subjected to cold rolling up to 2 mm in thickness, then subjected to precipitation treatment at 300°C for 8 hours, further subjected to final cold rolling up to 1 mm in thickness, and then heated for recrystallization at 480°C for 20 seconds in a continuous annealing line (CAL) to manufacture O stock. The section of the alloy sheet thus manufactured was subjected (photographed) to optical microscopic observation at a magnification of 100, and then the mean grain diameter of the metal structure in the alloy sheet was measured according to a crosscut method. The tensile strength, proof stress and elongation of each alloy sheet described above were measured by a tension test, and a test on deep drawing formability was conducted by a deep drawing test machine under the following conditions. Then, the limit drawing height was measured to evaluate the deep drawing formability. Dimension and shape of blank : 100 mm 2 (100 × 100mm) Dimension and shape of punch : 50 mm 2 (50 × 50mm) Dimension and shape of dies : 52 mm 2 (52 × 52mm) Punch shoulder radius : 5 mm Dies shoulder radius : 3 mm Blank folding force : 2500 kg Further, a thinned specimen (thickness: 2800 to 3500Å) of the finally annealed alloy sheet described above was prepared according to a jet grinding method by use of a mixed solution of nitric acid and methanol (volume ratio of 1:2). Then, this thinned specimen was observed by a transmission electron microscope under an acceleration voltage of 200 Kv and at a magnification of 40000. The resultant electromicroscopic photos (30 visual fields) were analyzed by an image analyzer to calculate the mean diameter and dispersed amount of intermetallic compounds containing Cr. In addition, it was confirmed by the analytical technique described above that the dispersive state of the intermetallic compounds containing Cr of the alloy sheet after the completion of the precipitation treatment described above is identical with that after the final annealing. The results thus obtained from the measurement, observation and calculation are given in Table 2. As apparent from the results shown in Table 2, each of the sheets manufactured from the alloys of the alloy samples No. 1 to 8 of the invention has high strength and is excellent in deep drawing formability. On the other hand, each of the sheets manufactured from the alloy of the alloy sample No. 9 with a small content of Mg and slightly high contents of Fe and Si is inferior in both deep drawing formability and elongation. With respect to the alloy of the alloy sample No. 10 with small contents of Ti and B and a high content of Fe, since the grain diameter after the casting is large, the hot rolling cracks were generated, and the manufacture of the alloy sheet was impossible. With respect to the sheet manufactured from the alloy of the alloy sample No. 11 with a small content of Cr, since the dispersed amount of the intermetallic compounds containing Cr is small and the grain diameter after the final annealing is large, the strength is low and the deep drawing formability is poor. With respect to the sheet manufactured from the alloy of the alloy sample No. 12 with a high content of Cr, the elongation is low and the deep drawing formability is poor. With respect to the alloy of the alloy sample 13 with a high content of Cu and the alloy of the alloy sample No. 14 with a high content of Mg, the hot rolling cracks were generated, and the manufacture of the alloy sheet was impossible. With respect to the alloy of the alloy sample No. 15 with a small content of Be, the cracks were generated at the time of casting, and the manufacture of the alloy sheet was impossible. With respect to the sheet manufactured from the alloy of the alloy sample No. 16 with a high content of Ti, the elongation is low, and the deep drawing formability is poor. Second Example The hot rolled alloy sheet (thickness: 5 mm) manufactured from the alloy of the alloy sample No. 4 in Table 1 was successively subjected to cold rolling, precipitation treatment, final cold rolling and annealing under the different conditions as shown in Cases Nos. 17 to 29 in Table 3 respectively to prepare an aluminum alloy sheet with a thickness of 1 mm. The mean grain diameter of the aluminum alloy sheet thus manufactured was measured, and the tensile strength, proof stress and elongation thereof were also measured by a tension test. Further, a test on deep drawing formability was conducted under the same conditions as those in case of the first example. Then, the limit drawing height was measured to evaluate the deep drawing formability. The results thus obtained are shown in Table 4. Incidentally, the manufacturing conditions in Cases Nos. 17 to 21 in Table 3 are those within the range of the manufacturing process of the invention, and the manufacturing conditions in Cases No. 22 to 29 are those without the range of the manufacturing process of the invention. As apparent from Tables 3 and 4, each of the aluminum alloy sheets in Cases Nos. 17 to 21 according to the manufacturing conditions of the process of the invention is excellent in not only elongation and strength but also deep drawing formability. On the other hand, with respect to each of the alloy sheets in Cases Nos. 22 and 26, in which the precipitation treatment was not carried out, and each of the alloy sheets in Cases Nos. 23 and 24, in which the temperature for precipitation treatment is lower than that in the conditions of the invention or the time for precipitation treatment is shorter than that in the conditions of the invention, the dispersed amount of the intermetallic compound containing Cr in the metal structure of each alloy sheet is small. With respect to each of the alloy sheets in Cases Nos. 25 and 27, in which the temperature for precipitation treatment is higher than that in the conditions of the invention, the intermetallic compounds containing Cr in the metal structure of each alloy sheet are coarse, and the dispersed amount of the intermetallic compounds containing Cr becomes excessive. As a result, each of these alloy sheets has the mean grain diameter exceeding 30 µm after the annealing, and also is inferior in both strength and deep drawing formability to each of the alloy sheets in Cases Nos. 17 to 21. Further, with respect to each of the alloy sheets in Cases Nos. 28 and 29, in which the temperature for final annealing is higher than that in the conditions of the invention, or the time for annealing is longer than that in the conditions of the invention, each of these alloy sheets also has the mean grain diameter exceeding 30 µm after the annealing and is inferior in both strength an deep drawing formability to each of the alloy sheets in Cases Nos. 17 to 21. The transmission electron microscopic photographs of thinned specimens (thickness: 0.28 µm) of the alloy sheets in Cases Nos. 19 and 22 are respectively shown in Figs. 1 and 2. Fig. 1 shows a transmission electron microscopic image of the metal structure of the finally annealed alloy sheet in Case No. 19 as the example of the invention, and 0.23 vol.% of the intermetallic compounds containing Cr with the mean grain diameter of 0.08 µm are dispersed. On the other hand, with respect to the alloy sheet in Case No. 22 as a comparative example, the mean grain diameter of the intermetallic compounds containing Cr in the structure of this alloy sheet is 0.11 µm, and the dispersed amount thereof is 0.6 vol.%. The aluminum alloy sheet according to the process of the invention is excellent in both strength and deep drawing formability which are approximately comparable to those of the cold rolled steel sheet, and any Lüders line is hard to be generated at the time of deep drawing press-forming. Further, the aluminum alloy sheet according to the invention and the press-formed product thereof are excellent in characteristics of brittleness-resistance in processing under the extensive temperature environment, in particular under the low-temperature environment. According to the process of manufacturing the aluminum alloy sheets of the invention, the aluminum alloy sheets having the characteristics described above can be manufactured industrially.

Claims: A process of manufacturing an aluminum alloy sheet excellent in strength and deep drawing formability, comprising the steps of : preparing an aluminum alloy slab containing 5 to 10 wt.% of Mg, 0.0001 to 0.01 wt.% of Be, 0.01 to 0.05 wt.% of Cr, 0.005 to 0.1 wt.% of Ti or both 0.005 to 0.1 wt.% of Ti and 0.00001 to 0.05 wt.% of B, eventually 0.05 to 1.0 wt.% of Cu, Fe and Si as impurities respectively regulated to be less than 0.2 wt.%, and the remainders consisting of other inevitable impurities and Al ; homogenizing said aluminum alloy slab at 450 to 540°C for not more than 24 hours ; then subjecting the homogenized aluminium alloy slab to hot rolling to provide the alloy sheet ; carrying out a precipitation treatment of intermetallic compounds containing Cr at least once at 230 to 360°C for 1 to 100 hours, immediately after the hot rolling or on the way of cold rolling following said hot rolling ; then subjecting the resultant alloy sheet to final cold rolling up to a predetermined thickness ; and thereafter heating the finally cold rolled alloy sheet at 400 to 500°C for not more than 120 seconds. A process of manufacturing an aluminum alloy sheet excellent in strength and deep drawing formability according to claim 3, wherein said aluminum alloy slab contains 0.05 to 1.0 wt.% of Cu.

Inventors: BEKKI YOICHIRO, SHOJI RYO, BEKKI, YOICHIRO, SHOJI, RYO, BEKKI, YOICHIRO, C/O THE FURUKAWA ELEC. CO., LTD., SHOJI, RYO, C/O THE FURUKAWA ELECTRIC CO., LTD.
Applicants: FURUKAWA ELECTRIC CO LTD, KAWASAKI STEEL CO, KAWASAKI STEEL CORPORATION, THE FURUKAWA ELECTRIC CO., LTD.
Application year: 1993
Main classification: C22C21
IPC codes: C22C21, C22F1