Shampoo compositions and suspending agent therefor

Abstract: A hair shampoo composition comprising a cleansing surfactant; a water-insoluble hair treating compound, like a hair conditioner or an antidandruff agent; a suspending agent comprising an amine including at least one long carbon chain and a suitable acid; and a suitable carrier, and a method of treating hair are disclosed. The shampoo compositions effectively suspend the water-insoluble hair-treating compound, effectively cleanse the hair and effectively deliver the water-insoluble hair-treating compound to the hair or scalp.

Description: FIELD OF THE INVENTION The present invention is directed to a shampoo composition including a new and improved suspending agent and to a method of treating hair, wherein the aqueous shampoo composition includes a water-insoluble hair treating compound, such as a silicone conditioning agent or a particulate antidandruff agent, and effectively resists phase separation. More particularly, a shampoo composition of the present invention is an unexpectedly stable suspension for the improved topical delivery of a water-insoluble hair treating compound from an aqueous shampoo composition to the hair or scalp. Therefore, in general, the present invention is directed to a shampoo composition comprising: (a) a cleansing surfactant, such as an anionic surfactant, like sodium lauryl sulfate or ammonium lauryl ether sulfate; (b) a water-insoluble hair treating compound, such as a hair conditioner, like a polydimethylsiloxane, or an antidandruff agent, like zinc pyrithione; (c) a suspending agent comprising: (i) a water-insoluble amine having the general structural formula (I) or (II) or (III), wherein R 1 is an alkyl group, straight chain or branched, including at least about 16 carbon atoms; R 2 and R 3 are, independently, selected from the group consisting of hydrogen, an alkyl group including one to about 22 carbon atoms, benzyl and phenyl; R 4 is an alkyl group, straight chain or branched, including at least 13 carbon atoms; R 5 is an alkylene moiety including 1 to 4 carbon atoms; R 6 and R 7 are, independently, alkyl groups including 1 to 4 carbon atoms; and R 8 and R 9 are, independently, hydrogen or an alkyl group including 1 to 4 carbon atoms, and (ii) a suitable inorganic mineral acid, and (d) a suitable carrier comprising water; wherein the composition includes a sufficient amount of acid such that essentially no solid particles of the amine of general structural formula (I) or (II) or (III) are present in the composition. The shampoo composition effectively resists phase separation, and effectively delivers the water-insoluble hair treating compound to the hair or scalp. BACKGROUND OF THE INVENTION Most individuals buy and use a hair shampoo for its cleansing properties. A consumer often also desires a hair shampoo that imparts other desirable properties to the hair or scalp, such as conditioning, antidandruff and set retention properties. For example, consumers often desire sufficiently-conditioned hair that holds a preset configuration. However, hair shampoos generally are formulated with highly effective synthetic surfactants, like anionic surfactants, that primarily cleanse as opposed to conditioning the hair. Therefore, shampoos usually neither aid in the detangling of wet hair nor impart any residual conditioning benefits to dry hair, such as manageability or styleability of hair sets. The hair normally is left in an unconditioned, cosmetically-unsatisfactory state after washing with an anionic surfactant-based hair shampoo, because anionic surfactants not only remove the dirt and soil from the hair, but also remove essentially all of the sebum naturally present on the surface of the hair fibers. Therefore, although anionic surfactants effectively cleanse the hair, the anionic surfactants also leave the hair in a cosmetically-unsatisfactory condition. In general, hair shampoo compositions containing anionic surfactants, or nonionic surfactants or amphoteric surfactants, leave the hair with an undesirable harsh, dull and dry touch, or feel, usually called "creak", after the hair is shampooed and then rinsed with water. Thoroughly cleansed hair also is extremely difficult to comb, in either the wet or the dry state, because the individual hair fibers tend to snarl, kink and interlock with each other. In addition, incompletely dried hair, such as hair dried with towel, has poor brushing properties, and after complete drying, the hair does not set well. Furthermore, the combing or brushing property of the hair remains, poor, and the hair has undesirable electrostatic properties in a low humidity atmosphere that causes the hair to "fly away", thereby further reducing the brushing properties of the hair. The unsatisfactory combing or brushing property of hair immediately after shampooing, also causes hair damage, such as split ends or hair breakage. In addition, the natural luster and resiliency of the hair is reduced. Consequently, the overall unsatisfactory condition of the shampooed hair usually necessitates a subsequent post-shampoo treatment of the hair with a conditioning composition to improve these undesirable physical characteristics. These conditioning compositions normally are applied separately from the hair shampoo, and usually are rinses or cream-like lotions containing a cationic compound that is substantive to the hair. Therefore, consumer needs traditionally have been met by the application of a shampoo to cleanse the hair, followed by the application of a conditioner composition to improve wet combing and other properties. The commonly accepted method has been to shampoo the hair, followed by rinsing the hair, and then separately applying a conditioner composition, followed by a second rinse. As previously discussed, freshly shampooed hair is inclined to knot and tangle, and therefore is difficult to comb and difficult to manage. The wet combing problem has been solved by treating shampooed hair with a conditioner composition that coats the hair shaft and causes the individual hair shafts in a tress to resist tangling and matting because of the conditioner residue retained on the shaft. Consumers also often use an antidandruff shampoo. The incorporation of antidandruff agents into anionic surfactant-based hair shampoos is well known. The antidandruff agents not only must relieve the flaking and itching symptoms of dandruff, but also must be substantive to the skin and hair in order to extend the efficacy of the antidandruff agent from one shampoo treatment to the next. These properties are most often found in compounds that are insoluble in aqueous media, and this inherent insolubility of the antidandruff agent makes formulation of a stable, aqueous, anionic surfactant-based antidandruff shampoo a difficult problem. In order to incorporate effective, water-insoluble antidandruff agents into an aqueous surfactant-based hair shampoo, one or more suspending agents are required to maintain the antidandruff agent homogeneously dispersed throughout the aqueous solution. Failure to adequately suspend the antidandruff agent leads to eventual shampoo separation as the antidandruff agent settles to the bottom of the container, and results in poor dandruff control and consumer complaints. As a result, investigators have continuously sought suitable suspending agents capable of effectively dispersing antidandruff agents, such as zinc pyrithione or sulfur, in aqueous media. While numerous shampoos that include hair conditioners or antidandruff compounds have been disclosed, such shampoos have not been totally satisfactory for a variety of reasons. In regard to shampoo-conditioner compositions, one problem relates to compatibility problems between anionic cleansing surfactants and cationic compounds that are good conditioning agents. This compatibility problem has caused workers in the field to investigate other surfactants, such as nonionics, amphoterics and zwitterionics, as a total or partial replacement for the anionic cleansing surfactant. Many of these efforts are reflected in patents issued in the shampoo conditioner area. See for example U.S. Pat. No. 3,849,348 to Hewitt; U.S. Pat. No. 3,990,991 to Gerstein; and U.S. Pat. No. 3,822,312 to Sato. However, the nonionic, amphoteric and zwitterionic surfactants are inferior cleansing surfactants compared to the anionic surfactants. Accordingly, to avoid the cationic-anionic incompatibility problem, to increase the degree of conditioning imparted to the hair and to maintain the cleansing efficiency of the hair shampoo, investigators incorporated silicone compounds into surfactant-based shampoo compositions. A problem inherent in formulating a silicone-based shampoo conditioner is the phase separation that results when a water-insoluble silicone conditioning agent is included in the aqueous shampoo-conditioner composition. Silicones included in shampoo-conditioner compositions have been disclosed in a number of different patents, including U.S. Pat. No. 2,826,551 to Green; U.S. Pat. No. 3,964,500 to Drakoff; U.S. Pat. No. 4,364,837 to Pader; British Pat. No. 849,433 to Woolston; U.S. Pat. No. 4,741,855 to Grote, et al.; U.S. Pat. Nos. 4,788,006 and 4,902,499 to Bolich, Jr. et al. and U.S. Pat. No. 4,704,272 to Oh et al. A particularly difficult problem encountered in silicone-containing shampoo-conditioners is maintaining a dispersed, insoluble silicone material suspended in stable form, while retaining the cleansing and conditioning performance of the conditioning shampoo-conditioner product. A variety of materials have been proposed for inclusion in silicone-containing conditioning shampoos for purposes of thickening and stabilization such as xanthan gum, long chain acyl derivatives, long chain amide oxides, and long chain alkanolamides as disclosed in U.S. Pat. Nos. 4,788,006; 4,704,272; and 4,741,855. In particular, Oh et al., in U.S. Patent No. 4,704,272, disclose shampoo compositions including an anionic surfactant, a nonvolatile silicone, a hair conditioning agent and a suspending agent. The hair conditioning agent can be a tri-long chain (C 8 -C 22 ) amine, such as tri(isodecyl)amine or tri-C 13 amine. Oh et al. also teach that a suspending agent, like a xanthan gum or a long chain acyl derivative, is essential to the composition. Surprisingly, it has been found that a primary, secondary or tertiary amine including at least one carbon chain having at least 16 carbon atoms, and neutralized with a suitable acid, provides a stable shampoo composition that effectively resists separation of the water-insoluble hair-treating compound from the shampoo composition without the need for a separate suspending agent. Bolich et al., in U.S. Patent No. 4,472,375, disclose an aqueous hair conditioning composition comprising a volatile hydrocarbon or a volatile silicone; a nonionic thickening agent; a quaternary ammonium salt and/or a salt of a fatty amine. The composition of Bolich et al. does not include an anionic cleansing surfactant and relies upon the nonionic thickening agent, e.g., a polymer, to suspend the water-insoluble ingredients. The present composition does not rely on a thickening agent to maintain phase stability of the composition. A similar problem is encountered in regard to an antidandruff shampoo wherein a water-insoluble particulate antidandruff agent tends to separate from the aqueous hair shampoo base. Therefore, compositions containing insoluble particulate matter, like an antidandruff agent, require a suspending agent to assist in dispersing the particulate matter evenly throughout the composition. The suspending agent can be any one of a number of inorganic minerals or synthetic or natural polymers or gums. Among the most often used suspending agents are colloidal aluminum oxide, modified magnesium aluminum silicate, xanthan gum, fumed silica, algin products, polyacrylic acid, sodium carboxymethylcellulose, hydroxypropylcellulose, synthetic sodium magnesium silicate, colloidal attapulgite clay, lignins and alkanolamides. Any antidandruff agent and additional suspending agents added to a basic hair shampoo base should add antidandruff properties to the shampoo without detracting from the cleansing efficiency and esthetic appeal of the shampoo. Unfortunately, the antidandruff agents and necessary suspending agents often adversely affect the foaming characteristics of the shampoo composition. Therefore, the need for improved stable compositions that condition the hair, i.e., render the hair more manageable, or that impart antidandruff properties, has long been recognized in the art. Consequently, the present invention is directed to stable hair shampoo compositions including a cleansing surfactant and a water-insoluble hair treating compound, like a silicone conditioner or an antidandruff agent, wherein the hair shampoo composition effectively resists phase separation because of the presence of a new suspending agent comprising an amine including at least one alkyl chain of sufficient chain length and a suitable acid. As will be demonstrated more fully hereinafter, a hair shampoo composition, comprising a cleansing surfactant; a water-insoluble hair treating compound, like a silicone conditioning compound or an antidandruff agent; a suspending agent comprising a fatty amine having at least one alkyl group including at least about 16 carbon atoms or a fatty amidoamine having an alkyl group including at least about 13 carbon atoms and a suitable acid; and a suitable carrier, comprising water, effectively resists phase separation and effectively delivers the water-insoluble hair treating compound to the hair or scalp. SUMMARY OF THE INVENTION In brief, the present invention relates to a composition and method of shampooing and treating hair. More particularly, the present invention relates to a cosmetic treatment of the hair by contacting the hair with a sufficient amount of a cosmetic shampoo composition comprising: (a) 3 % to 40 % by weight of an anionic cleansing surfactant; (b) 0.1 % to 10 % by weight of a water-insoluble hair treating compound; (c) a suspendig agent comprising: (i) from 1 % to 10 % by weight of the composition of an amine having the general structural formula or a combination thereof, wherein R 1 is an alkyl group including at least 16 carbon atoms; R 2 and R 3 are, independently, selected from the group consisting of hydrogen, an alkyl group including one to 22 carbon atoms, benzyl and phenyl; R 4 is an alkyl group including at least 13 carbon atoms; R 5 is an alkylene moiety including one to four carbon atoms; R 6 and R 7 are, independently, an alkyl group including one to four carbon atoms; and R 8 and R 9 are, independently, hydrogen or an alkyl group including 1 to 4 carbon atoms; and (ii) a sufficient amount of an acid such that essentially no solid particles of the amine are present in the composition and such that the composition has a pH of 5 to 8, said acid being selected from an inorganic mineral acid and (d) a carrier comprising water. An aqueous hair shampoo composition of the present invention effectively resists phase separation, demonstrates extended product stability, exhibits excellent cleansing properties and effectively delivers the water-insoluble hair treating compound to the hair or scalp to impart conditioning properties or antidandruff properties. Therefore, one important aspect of the present invention is to provide a shampoo composition that cleanses the hair and imparts improved physical properties and cosmetic properties to the hair or scalp in a single application. Another aspect of the present invention is to provide a physically stable, aqueous shampoo composition including a cleansing surfactant; a water-insoluble hair treating compound, like a silicone conditioner or an antidandruff agent; an amine including at least one alkyl group having a chain length of at least 16 carbon atoms or an amidoamine including an alkyl group having a chain length of at least 13 carbon atoms; and a suitable acid. Another aspect of the present invention is to provide a new and improved shampoo, including a cleansing surfactant, such as a long chain alkyl sulfate or a long chain alkyl ether sulfate, and a water-insoluble hair treating compound, like a silicone conditioning agent or a particulate antidandruff agent, that is unexpectedly stable due to a new and improved suspending agent comprising an amine including at least one alkyl group having at least 16 carbon atoms or an amidoamine including an alkyl group having a chain length of at least 13 carbon atoms, or a combination thereof, and a suitable acid. Still another aspect of the present invention is to provide a new and improved shampoo composition including 3% to 40% of a cleansing surfactant; 0.1% to 10% of a water-insoluble hair treating compound, such as a silicone conditioning compound or an antidandruff agent; wherein the water-insoluble hair treating compound is suspended in the shampoo composition by a suspending agent, the suspending agent comprising: (i) from 1% to 10% by weight of the composition of an amine having the general structural formula (I) or (II) or (III), wherein R 1 is an alkyl group, straight chain or branched, including at least 16 carbon atoms; R 2 and R 3 are, independently, selected from the group consisting of hydrogen, an alkyl group including one to about 22 carbon atoms, benzyl and phenyl; R 4 is an alkyl group, straight chain or branched, including at least 13 carbon atoms; R 5 is an alkylene group including 1 to 4 carbon atoms; R 6 and R 7 are, independently, hydrogen or an alkyl group including 1 to 4 carbon atoms, and R 8 and R 9 are, independently, hydrogen or an alkyl group including 1 to 4 carbon atoms, and (ii) from 0.05% to 5% by weight of the composition of an inorganic mineral acid, wherein the composition includes a sufficient amount of acid such that essentially no solid particles of the amine of general structural formula (I) or (II) or (III) are present in the composition. Another aspect of the present invention is to provide a stable shampoo composition that is capable of cleansing the hair and of imparting improved physical and cosmetic properties to the hair or scalp at a pH of 3 to 8. Another aspect of the present invention is to provide a method of shampooing and treating hair by contacting the hair with a composition having a pH of 3 to 8, and comprising a cleansing surfactant; a water-insoluble hair treating compound, like a polydimethylsiloxane conditioning compound or an antidandruff agent; an amine having at least one carbon chain of at least 16 carbon atoms, an amidoamine having a carbon chain of at least 13 carbon atoms or a combination thereof; an inorganic mineral acid; and water. The above and other aspects and advantages of the present invention will become apparent from the following detailed description of the preferred embodiments. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A hair shampoo composition of the present invention comprises a cleansing surfactant, a water-insoluble hair treating compound, a suspending agent comprising a suitable amine, or a suitable amidoamine, and a suitable acid, and a carrier comprising water. The water-insoluble hair treating compound can be, for example, a water-insoluble hair conditioning compound, like a silicone or a hydrocarbon conditioning agent, or an antidandruff agent. In accordance with an important feature of the present invention, the amine of the suspending agent is a solid, water-insoluble amine having the general structural formula (I) or (II) or (III): wherein R 1 is an alkyl group, straight chain or branched, including at least 16 carbon atoms; R 2 and R 3 are, independently, selected from the group consisting of hydrogen, an alkyl group including one to about 22 carbon atoms, benzyl and phenyl; R 4 is an alkyl group, straight chain or branched, including at least 13 carbon atoms; R 5 is an alkylene moiety including 1 to about 4 carbon atoms; R 6 and R 7 are, independently, an alkyl group including 1 to 4 carbon atoms; and R 8 and R 9 are, independently, hydrogen or an alkyl group including 1 to 4 carbon atoms. In accordance with an other important feature of the present invention, the acid of the suspending agent is selected from the group consisting of an inorganic mineral acid, an aliphatic carboxylic acid including up to about 22 carbon atoms, an aromatic carboxylic acid, and combinations thereof. The aqueous shampoo composition effectively resists phase separation, effectively cleanses the hair and effectively delivers the water-insoluble hair treating compound to the hair or scalp to impart conditioning properties, antidandruff properties or other desired hair or scalp properties. The cleansing surfactant used in the composition and method of the present invention includes any of the anionic surfactants known or previously used in the art of hair shampoos. An anionic surfactant is the preferred cleansing surfactant in the composition of the present invention because it effectively cleanses the hair and generates a high, stable, foam level that consumers equate with cleaning efficiency. Nonionic surfactants generally are not as effective in cleansing the hair and do not provide the high foam level desired by consumers, but such surfactants impart mildness to the composition. Nonionic surfactants also can be included in a composition of the present invention to help increase and stabilize foam, to provide a suitable viscosity, or to furnish other functional or esthetic properties to the composition. Therefore, nonionic surfactants are not used as the primary cleansing surfactant in a composition of the present invention, but can be included in conjunction with an anionic cleansing surfactant. Usually, the preferred anionic surfactant includes a hydrophobic moiety, such as a carbon chain including from about 8 carbon atoms to about 30 carbon atoms, and particularly from about 12 carbon atoms to about 20 carbon atoms; and further includes a hydrophilic moiety, such as sulfate, sulfonate, carbonate, phosphate or carboxylate. Often, the hydrophobic carbon chain is etherified, such as with ethylene oxide or propylene oxide, to impart a particular physical property, such as increased water solubility or reduced surface tension, to the anionic cleansing surfactant. The anionic surfactants are well-known and have been widely used in the art of hair shampoos. Therefore, suitable anionic surfactants include, but are not limited to, compounds in the classes known as alkyl sulfates, alkyl ether sulfates, alkyl ether sulfonates, sulfate esters of an alkylphenoxy polyoxyethylene ethanol, alpha-olefin sulfonates, beta-alkyloxy alkane sulfonates, alkyl arylsulfonates, alkyl carbonates, alkyl ether carboxylates, fatty acids, sulfosuccinates, sarcosinates, octoxynol phosphates, nonoxynol phosphates, taurates, fatty taurides, sulfated monoglycerides, fatty acid amino polyoxyethylene sulfates and isothienates; or combinations thereof. Many additional anionic surfactants are described in McCUTCHEON'S, DETERGENTS AND EMULSIFIERS, 1989 ANNUAL, published by McCutcheon Division, MC Publishing Co. Usually, the anionic surfactant is present in the composition as a neutralized salt in the form of a sodium, potassium, lithium, ammonium, alkylammonium or hydroxyalkylammonium salt, wherein the alkyl moiety includes 1 to about 3 carbon atoms. The alkyl sulfates and alkyl ether sulfates are particularly effective classes of anionic surfactants. Exemplary anionic surfactants useful in the composition and method of the present invention include, but are not limited to, the ammonium, monoethanolamine, diethanolamine, triethanolamine, isopropylamine, sodium, potassium, lithium or magnesium salt of lauryl sulfate, dodecylbenzenesulfonate, lauryl sulfosuccinate, lauryl ether sulfate, lauryl ether carboxylate, lauryl sarcosinate, cocomethyl tauride, and sulfosuccinate half ester amide; or combinations thereof. An example of an especially useful anionic surfactant is a combination of a lauryl sulfate salt and a lauryl ether sulfate salt. In conjunction with the anionic surfactant, an amphoteric surfactant can be included in the shampoo composition. An amphoteric surfactant enhances skin mildness and composition esthetics to improve consumer acceptance. Suitable classes of amphoteric surfactants included in the present invention include, but are not limited to, betaines, hydroxypropylsultaines, amine oxides and combinations thereof. Examples of specific amphoteric surfactants include, but are not limited to, cocamidopropyl betaine, lauramidopropyl betaine, coco/oleamidopropyl betaine, coco betaine, oleyl betaine, cocamidopropyl hydroxysultaine, tallowamidopropyl hydroxysultaine and dihydroxyethyl tallow glycinate or combinations thereof. In general, however, any amphoteric surfactant known and used in the art of hair shampoos can be included in the composition of the present invention. The shampoo compositions of the present invention also can include a nonionic surfactant in combination with the anionic surfactant. In general, nonionic surfactants impart esthetic, physical or cleansing properties to the shampoo composition. Representative nonionic surfactants that can be included in a shampoo composition of the present invention include ethers of polyols and sugars; fatty acid alkanolamides; polyethylene glycols; the ethoxylated or propoxylated alkylphenols; ethoxylated or propoxylated fatty alcohols; and the condensation products of ethylene oxide with long chain amides. These nonionic surfactants, as well as numerous others not cited herein, are well known to person skilled in the art and are fully described in the literature, such as McCUTCHEON'S, DETERGENTS AND EMULSIFIERS, 1989 Annual, published by McCutcheon Division, MC Publishing Co. In particular, a nonionic alkanolamide can be included in the composition to improve composition thickening and foam stability. Suitable alkanolamides include, but are not limited to, those known in the art of hair care formulations, such as cocamide MEA, cocamide DEA, soyamide DEA, lauramide DEA, oleamide MIPA, stearamide MEA, myristamide MEA, lauramide MEA, capramide DEA, ricinoleamide DEA, myristamide DEA, stearamide DEA, oleylamide DEA, tallowamide DEA, lauramide MIPA, tallowamide MEA, isostearamide DEA, isostearamide MEA and combinations thereof. In accordance with an important feature of the present invention, the anionic surfactant is present in the composition in an amount of 3% to 40%, and preferably 5% to 30%, by weight of the composition. It has been found that if the cleansing surfactant is present in an amount of less than 3% by weight of the composition, then the hair is not sufficiently cleansed when contacted with a shampoo composition of the present invention. Therefore, the cleansing surfactant, or combination of cleansing surfactants, generally is included in the hair shampoo composition of the present invention in a preferred amount ranging from 5% to 30% by weight of the composition, and to achieve the full advantage of the present invention, from 10% to 25% by weight of the composition. Furthermore, surprisingly and unexpectedly, even when a low amount of cleansing surfactant is included in the composition, such as from 3% to 10% by weight of the composition, the presence of the water-insoluble hair treating compound and the amine of the suspending agent do not adversely affect the generation of a sufficient and stable foam level for consumer acceptance. In accordance with another important feature of the present invention, the hair shampoo composition includes a water-insoluble hair treating compound that imparts conditioning properties to the hair, imparts antidandruff properties to the hair and scalp or imparts other desired properties to the hair or scalp. Other classes of water-insoluble hair treating compounds, in addition to hair conditioners and antidandruff agents, that are useful in the shampoo composition of the present invention include, but are not limited to, hair colorants, hair fixatives and pearlizing agents. In general, the hair shampoo composition of the present invention includes from 0.1% to 10%, and preferably from 0.5% to 5% of the water-insoluble hair treating compound. In one important embodiment of the present invention, the shampoo composition is a shampoo-conditioner wherein the water-insoluble hair treating compound is a silicone conditioning agent, a hydrocarbon conditioning agent, a water-insoluble fatty alcohol including 12 to 22 carbon atoms or a water-insoluble fatty ester including 9 to 34 carbon atoms, or other water-insoluble conditioning agent. In particular, the silicone conditioning agent can be a polyalkyl siloxane, a polyaryl siloxane or a polyalkylaryl siloxane. Mixtures of these silicone conditioning agents also can be used. In one embodiment, the silicone conditioning agent is a nonvolatile silicone conditioning agent, like a polydimethylsiloxane compound, such as a mixture, in about a 2:1 weight ratio, of a low molecular weight polydimethylsiloxane fluid and a higher molecular weight polydimethylsiloxane gum. Preferred silicone gums include linear and branched polydimethylsiloxanes of the following general formula: (CH 3 ) 3 SiO - [Si(CH 3 ) 2 O] n - Si(CH 3 ) 3 , wherein n is a number from 2,000 to 15,000, and preferably from 2,000 to 7,000. Silicone gums useful in compositions of the present invention are available from numerous commercial sources, including General Electric Company, Waterford, NY, and Dow Corning Corp., Midland, MI. The nonvolatile polydimethylsiloxane agent is added to the composition of the present invention in an amount sufficient to impart improved combing and improved feel, such as softness, to the hair after shampooing. As referred to herein, the nonvolatile polydimethylsiloxane compounds are nonfunctional siloxanes having a viscosity of from 0,05 to 6000 cm 2 /s (5 to 600,000 cs (centistoke)), and preferably from 3,5 to 100 cm 2 /s (350 to 10,000 cs) at 25 °C. The so-called "rigid silicones", as described in U.S. Patent No. 4,902,499, having a viscosity above 6000 cm 2 /s (600,000 cs) at 20 °C, e.g., 7000 cm 2 /s (700,000 cs) plus, and a weight average molecular weight of at least about 500,000 also are useful in accordance with the present invention. A volatile silicone conditioning agent also is useful in the hair shampoo composition of the present invention as the water-insoluble hair treating compound, either alone or in conjunction with other water-insoluble hair treating compounds. The volatile silicone normally is a low molecular weight polydimethylsiloxane, however a low molecular weight polydimethylsiloxane including phenyl substituents also is useful in the compositions of the present invention. Furthermore, the low molecular weight polydimethylsiloxane compound can be a linear or a cyclic polydimethylsiloxane compound. The volatile polydimethylsiloxane compound provides lubrication and imparts hair conditioning properties to wet hair, and has sufficient volatility to slowly volatilize from the hair such that a residual buildup of silicone compound is not present on dry hair. An example of a linear, low molecular weight, volatile polydimethylsiloxane compound useful in the composition and method of the present invention is hexamethyldisiloxane, available commercially under the tradename DOW CORNING 200 FLUID, from Dow Corning Corp., Midland, Michigan. Hexamethyldisiloxane has a viscosity of 0,0065 cm 2 /s (0.65 cs (centistokes)), is highly volatile, is nongreasy, provides lubrication, and improves the overall combing properties of the hair. Other linear polydimethylsiloxanes, such as decamethyltetrasiloxane, having a boiling point of about 195 °C and a viscosity of 0,015 cm 2 /s (1.5 centistokes); octamethyltrisiloxane; and dodecamethylpentasiloxane, also are useful in the composition of the present invention. In addition, the cyclic, low molecular weight, volatile polydimethylsiloxanes, having the Cosmetic, Toiletry and Fragrance Associate (CTFA) designation cyclomethicones, also are useful in the composition and method of the present invention. The cyclomethicones are low molecular weight, water-insoluble cyclic compounds having an average of 3 to 6 - [O-Si(CH 3 ) 2 ]- repeating group units per molecule and boil at atmospheric pressure in a range of from 150°C to 250°C. Suitable cyclomethicones are available commercially under the tradenames SILICONE SF-1173 (octamethylcyclotetrasiloxane) and SILICONE SF-1202 (decamethylcyclopentasiloxane) from General Electric, Waterford, New York, and SILICONE 334 FLUID and SILICONE 345 FLUID from Dow Corning Corporation, Midland, Michigan, the tetramer being listed first in each instance. The volatile cyclic silicones can be used in combination with a linear volatile silicone, and the volatile silicone conditioner can be used in conjunction with the nonvolatile silicone conditioner. Another suitable water-insoluble conditioning compound that can be included in the composition of the present invention is a nonvolatile hydrocarbon, such as mineral oil. The nonvolatile hydrocarbons provide many of the same benefits as the silicone conditioning agents, and can be included in the composition in conjunction with a silicone conditioning agent. In addition to nonvolatile hydrocarbon conditioning compounds, a volatile hydrocarbon conditioning compound can be included in the composition as the water-insoluble hair treating compound, either alone or in conjunction with other water-insoluble hair treating compounds. The volatile hydrocarbon conditioner, such as a hydrocarbon including 10 carbon atoms to 26 carbon atoms, has sufficient volatility to slowly volatilize from the hair to preclude a residual buildup of hydrocarbon on dry hair. The volatile hydrocarbon provides essentially the same benefits as the volatile silicone, such as lubrication and wet hair conditioning. The preferred volatile hydrocarbon compound is an aliphatic hydrocarbon including from 12 to 24 carbon atoms, and has a boiling point in the range of from 100°C to 300°C. Exemplary volatile hydrocarbons are depicted in general structural formula (IV), wherein n ranges from 2 to 5. Examples of volatile hydrocarbons useful in the compositions of the present invention are the commercially-available compounds PERMETHYL 99A and PERMETHYL 101A, corresponding to compound of general structural formula (IV) wherein n is 2 and 3, respectively, from Permethyl Corporation, Frazer, PA. A volatile hydrocarbon compound is useful in the hair-conditioning composition of the present invention either alone, in combination with another volatile or nonvolatile hydrocarbon, or in combination with a volatile or nonvolatile silicone. In another embodiment, the water-insoluble conditioning compound is a fatty alcohol, wherein the fatty alcohol includes 12 to 22 carbon atoms. Exemplary fatty alcohols include, but are not limited to, lauryl alcohol, oleyl alcohol, myristyl alcohol, tallow alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, behenyl alcohol and combinations thereof. A fatty alcohol can be used alone, or in combination with a silicone conditioning agent or a hydrocarbon conditioning agent. In another embodiment, the water-insoluble conditioning compound is a fatty ester including 9 to 34 carbon atoms. The fatty component of the fatty ester can be derived from a fatty acid or a fatty alcohol, or a combination thereof. In addition, the fatty ester can be a straight chain fatty ester, like isopropyl myristate; a branched chain fatty ester, like Purcellin Oil; a benzoate ester, like C 12-15 alcohols benzoate; or a combination thereof. For example, a useful class of fatty esters is derived from carboxylic acids having 6 to 12 carbon atoms, including both branched and straight chain carboxylic acids. In general, the C 6 to C 12 carboxylic acid is esterified with a fatty alcohol including 12 to 22 carbon atoms to provide a fatty (C 12 to C 22 ) ester of a C 6 to C 12 carboxylic acid that is useful in the present invention. Such fatty alcohols include, but are not limited to, lauryl alcohol, myristyl alcohol, cetyl alcohol, cetearyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, tallow alcohol, behenyl alcohol and mixtures thereof. Accordingly, fatty (C 12 to C 22 ) esters of C 6 to C 12 carboxylic acids useful in the composition and method of the present invention include, but are not limited to, cetyl octanoate, stearyl heptanoate, stearyl caprylate, stearyl octanoate, lauryl octanoate, myristyl heptanoate, and oleyl octanoate, or mixtures thereof. These fatty esters can occur naturally or can be synthesized. In place of, or in combination with, the fatty (C 12 to C 22 ) ester of a C 6 to C 12 carboxylic acid, a fatty ester derived from a fatty acid including 8 to 22 carbon atoms esterified with an alcohol including 1 to 6 carbon atoms can be included in the composition of the present invention. Examples of such fatty esters include, but are not limited to, isopropyl myristate, isopropyl palmitate, isopropyl laurate, isopropyl linoleate, isopropyl tallowate, isopropyl ricinoleate, methyl laurate, methyl linoleate, methyl myristate, methyl stearate, methyl ricinoleate, methyl carprylate, methyl oleate, methyl palmitate, methyl stearate, methyl behenate, methyl soyate, methyl tallowate, isopropyl behenate, isopropyl soyate, propyl oleate, butyl oleate, butyl stearate, methyl coconate, methyl lardate, isobutyl palmitate, butyl myristate, ethyl palmitate, ethyl myristate, ethyl oleate, ethyl stearate, isobutyl stearate, isobutyl myristate and combinations thereof. Another class of fatty esters that can be included in the composition of the present invention, either alone or in combination with the fatty esters described above, is the benzoate esters. Suitable benzoate esters include esters of benzoic acid wherein the esterifying alcohol includes 8 carbon atoms to 22 carbon atoms. Examples of suitable benzoate esters include, but are not limited to, the commercial products FINSOLV TN, benzoic acid esterified with fatty alcohols including 12 to 15 carbon atoms; FINSOLV SB, isostearyl benzoate; FINSOLV P, PPG-15 stearyl ether benzoate; or combinations thereof, all available from Finetex Inc., Elmwood Park, NJ. Examples of other specific water-insoluble conditioning compounds that can be incorporated into the conditioning shampoos of the present invention include, but are not limited to, polysiloxane polyether copolymers; acetylated lanolin alcohols; lanolin-derived extract of sterols and sterol esters; lanolin alcohol concentrate; isopropyl ester of lanolin fatty acids; polyol fatty acid; keratin protein derivatives; amino-functional silicones; fatty alcohol fraction of lanolin; mineral oil and lanolin alcohol mixture; high molecular weight esters of lanolin; vinylpyrrolidone/dimethylaminoethylmethacrylate copolymer; 5 mole ethylene oxide adduct of soya sterol; 10 mole ethylene oxide adduct of soya sterol; stearic acid ester of ethoxylated methyl glucoside; hydroxylated lanolin; lactamide MEA; stearamide MEA; mixed ethoxylated and propoxylated long chain alcohols; hydrolyzed animal keratin; ethyl hydrolyzed animal keratin; avocado oil; sweet almond oil; grape seed oil; jojoba oil; apricot kernel oil; sesame oil; hybrid safflower oil; wheat germ oil; ethyl esters of hydrolyzed animal protein; blend of cetyl and stearyl alcohols with ethoxylated cetyl or stearyl alcohols; propoxylated (1-10 moles) lanolin alcohols; isostearamide DEA; and hydrolyzed collagen protein. Other water-insoluble conditioning agents are listed in CTFA Cosmetic Ingredient Handbook, First Edition , The Cosmetic Toiletry and Fragrance Association, Inc., New York, N.Y. (1988), pp. 71-73. In accordance with another important embodiment of the present invention, the shampoo composition of the present invention is an antidandruff shampoo wherein the water-insoluble hair treating compound is an antidandruff agent. The antidandruff agent usually is a particulate compound that is capable of relieving the symptoms of dandruff and is substantive to the hair and scalp to impart residual antidandruff properties between shampoos. Examples of particulate compounds exhibiting antidandruff properties include, but are not limited to, salicylic acid, elemental sulfur, selenium sulfide, zinc pyrithione, a water-insoluble 1-hydroxy pyridone, an azole antimycotic, and undecylenic acid. Particularly advantageous antidandruff agents useful in the shampoo composition of the present invention are zinc pyrithione and elemental sulfur. Zinc pyrithione is the zinc complex of 2-pyridinethiol-1-oxide, and is available commercially from Olin Corp. under the brand name of ZINC OMADINE. Useful sulfurs include elemental sulfur of sufficient purity and particle size to function as an antidandruff agent, as is well known to those skilled in the art. The antidandruff agents are extremely water insoluble and, therefore, are present in the antidandruff shampoo composition as discrete solid particles. These particles should be homogeneously dispersed and suspended throughout the shampoo to ensure the consumer receives an efficacious dose of the antidandruff agent at each shampooing. Without a suspending agent, the antidandruff agent can completely separate from the antidandruff shampoo composition resulting in poor dandruff control, and ultimately in consumer dissatisfaction and complaints. Therefore, a suspending agent composition must be incorporated into the basic antidandruff formulation to retard, minimize or eliminate settling of the insoluble antidandruff agent. In general, the suspending agent of the present invention effectively suspends a particulate antidandruff agent, and other particulate and liquid hair treating compounds. In addition to the cleansing surfactant and the water-insoluble hair treating compound, a hair shampoo of the present invention also includes a suspending agent. The suspending agent maintains the water-insoluble hair treating compound homogeneously dispersed throughout the composition for at least the expected life of the product, and does not adversely affect the foaming, cleansing, conditioning, antidandruff or other hair treating properties of the shampoo. Many suspending agents operate on the principle of thickening the composition to a sufficient viscosity to retard the settling or separation of the water-insoluble hair treating compound to such an extent that the composition is stable over its expected lifetime. However, considering the relatively high percentage of water-insoluble hair treating compound included in shampoos, a suspending agent that relies only on thickening often is incorporated into the composition in such a high percentage that an unacceptably viscous product results. Shampoo compositions having such a high viscosity are not acceptable to consumers because the compositions are difficult to dispense, difficult to spread evenly on the hair and scalp, and often do not generate an adequate foam. Accordingly, a shampoo composition of the present invention includes a suspending agent, comprising an amine having the general structural formula (I) or (II) or (III) and a suitable acid, that does not rely merely on thickening to suspend the water-insoluble hair treating compound. The amine is present in an amount of 1% to 10%, and preferably 1.5% to 5%, by weight of the composition; the acid is present in a sufficient amount such that essentially no solid particles of the amine of structural formula (I) or (II) or (III) are present in the composition. Therefore, in general, the acid is present in an amount of 0.05% to 5% by weight of the composition. In accordance with an important feature of the present invention, an amine useful in the present invention is depicted by the general structural formula (I) or (II) or (III), wherein R 1 is an alkyl group, straight chain or branched, including at least 16 carbon atoms; R 2 and R 3 are, independently, selected from the group consisting of hydrogen, an alkyl group including one to 22 carbon atoms, benzyl and phenyl; R 4 is an alkyl group, straight chain or branched, including at least 13 carbon atoms; R 5 is an alkylene moiety including 1 to 4 carbon atoms; R 6 and R 7 are, independently, an alkyl group including 1 to 4 carbon atoms; and R 8 and R 9 are, independently, hydrogen or an alkyl group including 1 to 4 carbon atoms. The alkyl groups R 1 and R 4 of the amine of general structural formulas (I), (II), and (III) can be derived from a fatty acid, and therefore do not have to be solely, or primarily, ot one chain length, i.e., the long chain need not be derived only from cetyl (C 16 ) or stearyl (C 18 ). Rather, a compound of general structural formula (I) or (II) or (III) wherein the alkyl group R 1 or R 4 is a mixture of lengths can be used, as long as the amine is water insoluble and includes at least one alkyl group of sufficient chain length to impart water insolubility. Such amine compounds are prepared conveniently from naturally occurring materials, such as tallow, soya oil and the like, or from synthetically produced mixtures. In particular, an amine of general structural formula (I) is a primary, a secondary or a tertiary amine including at least one alkyl group including at least 16 carbon atoms and is a solid compound at room temperature. It should be understood that a commercial amine of general structural formula (I), and having at least one carbon chain of at least 16 carbon atoms as the predominant chain length also can include a minor amount of an amine having a carbon chain of fewer than 16 carbon atoms. A minor amount of an amine having carbon chain including less than 16 carbon atoms, e.g., up to about 5% by weight of the amine present in the composition, does not adversely affect the composition. Suitable amines of general structural formula (I) are solid compounds at room temperature, and are water-insoluble compounds exhibiting a water solubility of 0.5 g (grams) or less per 100 ml (milliliters) of water. When an amine of general structural formula (I) is sufficiently neutralized such that essentially no solid particles of the amine are present in the composition, the neutralized amine forms a network that suspends the water-insoluble hair treating compound, such as a silicone conditioning agent or an antidandruff agent. The network effectively suspends the water-insoluble hair treating compound at least for the expected life of the product, e.g., about one year, without adversely affecting the other properties of the shampoo composition, like foam generation. Specific primary amines of general structural formula (I) useful in a shampoo composition of the present invention include, but are not limited to, C 20-22 amine, soya amine, hydrogenated tallow amine, stearyl amine, tallow amine, oleyl amine, hexadecylamine, octadecylamine, and combinations thereof. Suitable secondary amines include, but are not limited to, di(hydrogenated tallow)amine, disoyamine, dipalmityl amine, and combinations thereof. Suitable tertiary amines includes, but are not limited to, tri(hydrogenated tallow)amine, di(hydrogenated tallow) methylamine, distearyl methyl amine, methyl dibehenamine, dimethyl behenamine, dimethyl tallowamine, dimethyl stearamine, dimethyl tetradecylamine, dimethyl hexadecyl amine, dimethyl octadecyl amine, dimethyl soyamine, dimethyl oleyl amine, stearyl methyl benzyl amine, dimethyl palmitamine, dimethyl (hydrogenated tallow)amine, and combinations thereof. The shampoo compositions also can include a combination of primary and/or secondary and/or tertiary amines having the general structural formula (I). As stated above, a suitable amine also can have a distribution of alkyl groups wherein the predominant alkyl group includes at least 16 carbon atoms and wherein a minor portion, such as 5% or less, of the alkyl groups include less than 16 carbon atoms. It also should be understood that a diamine of general structural formula (III) is a suitable amine. Exemplary diamines include, but are not limited to, hydrogenated tallow diamine, tallow diamine, soya diamine or oleyl diamine, having the structural formula (V): R 1 NH(CH 2 ) n NH 2 , wherein n is a number 1 through 4 and R 1 is an alkyl group including at least 16 carbon atoms. In addition to an amine of general structural formula (I) or (III), an amine of general structural formula (II) also can be included in the shampoo composition as the amine, either alone or in combination with an amine of general structural formula (I) or (III) . A useful amine of general structural formula (II), generally termed an amidoamine, is a water-insoluble compound having a water solubility of 0.5 g or less per 100 ml of water. Examples of an amine of general structural formula (II) include but are not limited to, stearamidopropyl diethylamine, stearamidoethyl diethylamine, stearamidoethyl dimethylamine, palmitamidopropyl dimethylamine, behenamidopropyl dimethylamine, myristamidopropyl dimethylamine, oleamidopropyl dimethylamine, ricinoleamidopropyl dimethylamine, stearamidopropyl dimethylamine, and combinations thereof. In addition to an amine having the general structural formula (I) or (II) or (III), the suspending agent of the shampoo composition also includes a suitable acid. To provide a suspending agent that effectively suspends the water-insoluble hair treating compound in the shampoo composition, a sufficient amount of an inorganic mineral acid is included in the composition to neutralize the amine such that essentially no solid particles of the amine are present in the composition. Accordingly, the acid used to neutralize the amine compound is of sufficient acid strength to neutralize a free amine nitrogen. Such acids include, but are not limited to, the inorganic mineral acids, like hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, and combinations thereof. In addition to the above-described essential ingredients, other common cosmetic components and additives can be included in the shampoo composition of the present invention to impart desirable or esthetic properties, as long as the basic properties of the shampoo composition are not adversely affected. Such optional cosmetic components and additives include, but are not limited to, nonionic surfactants, amphoteric surfactants, fragrances, dyes, hair colorants, opacifiers, pearlescing agents, thickeners, inorganic salts, humectants, hydrotropes, foam stabilizers, solubilizers, preservatives, water softening agents, buffers and the like. These optional components and additives usually are present in weight percentages of 0% up to 5% by weight of the shampoo composition each, and usually 0% to 20% by weight of the shampoo composition in total. The composition also can include optional conditioning agents and emulsifiers. In general, such optional conditioning agents and emulsifiers, like quaternary ammonium compounds, are well-known to those skilled in the art, and can be included in the present shampoo composition in an amount of 0% to 5% by weight of the composition. The carrier of the shampoo composition is predominantly water, but nonaqueous solvents also can be included to help solubilize composition ingredients that are not sufficiently soluble in water, to adjust the viscosity of the composition or to act as a humectant. Suitable solvents include polyols, like glycerol; glycols, like ethylene glycol, propylene glycol and hexylene glycol; or mixtures thereof. The optional nonaqueous solvents should not adversely affect the ability of the composition to cleanse and treat the hair and scalp, or adversely affect consumer appeal of the composition. A nonaqueous solvent can be present in the hair shampoo-conditioner composition of the present invention in an amount ranging from 0% up to about 5% by weight of the composition. To achieve the full advantage of the present invention, the shampoo composition is a moderately viscous mixture, having a viscosity in the range of from 1 Pa·s (1000 cps (centipoises)) to 15 Pa·s (15,000 cps), that is stable indefinitely at temperatures normally found in commercial product storage and shipping. A shampoo composition of the present invention generally is a suspension that is stable and that resists phase separation or settling of composition ingredients at a temperature of 20°C to 25°C essentially indefinitely. The compositions also have demonstrated sufficient stability to phase separation and settling of ingredients at temperatures normally found in commercial product storage and shipping to remain unaffected for periods of one year or more. In accordance with the method of the present invention, several shampoo compositions were prepared, then applied to human hair, to demonstrate the improved suspending properties and the ability of the shampoo composition to deliver a water-insoluble hair treating compound to the hair or scalp provided by a composition comprising a cleansing surfactant; a water-insoluble hair treating compound; and a suspending agent comprising an amine compound of general structural formula (I) or (II) or (III) and a suitable acid. It has been demonstrated that to maximize suspension properties, the shampoo composition of the present invention should include the amine and the acid in a sufficient amount such that essentially no solid particles of the amine are present in the composition. It should be noted, however, that the acid is not necessarily present in an equimolar, or equimolar equivalent, amount in relation to the amine. A stoichiometric amount of acid in relation to the amine is not necessarily required because other ingredients in the shampoo composition may neutralize the amine. Therefore, a stoichiometric amount of acid can be included in the composition. However, as little as 20% of the stoichiometric amount of acid can be added to sufficiently neutralize the amine depending upon the particular composition ingredients and the desired pH for the composition. An excess amount of acid does not adversely effect the stability of the composition, but also does not increase stability, and therefore is wasted except for the purposes of adjusting a composition property, such as pH. Although the mechanism of interaction between the amine, the acid and other composition ingredients is not known precisely, it has been theorized that the acid-neutralized amine forms a network that suspends the water-insoluble hair treating compound. It should be noted that a shampoo composition including only free amine, i.e., an amine compound of general structural formula (I) or (II) or (III) not neutralized with an acid, underwent a phase separation relatively rapidly, such as in less than 24 hours. Accordingly, it is the acid-neutralized amine compound that suspends the water-insoluble hair treating compound in the shampoo composition. Furthermore, laboratory and salon tests have shown that hair shampooed with a composition of the present invention is effectively cleansed and that the water-insoluble hair treating compound is effectively delivered to the hair or scalp. To demonstrate the new and unexpected results achieved by the method and composition of the present invention, the following Examples 1 through 7 were prepared by an identical method, wherein the anionic cleansing surfactant, as an approximately 30% by weight aqueous solution, first was added to a vessel, then heated to about 82 °C (180 °F) under moderate agitation. Then the amine compound was added to the vessel, followed by the acid. The resulting mixture was maintained at about 82 °C (180 °F), and stirred for about 30 to about 90 minutes to homogenize the mixture. The remaining amount of water was added to cool the mixture, then the remaining ingredients were added to the resulting mixture individually, in any desired order. Agitation speed was increased after addition of the water-insoluble hair treating compound to effectively disperse the water-insoluble hair treating compound throughout the composition. The compositions of Examples 8 through 14 utilized a different secondary amine (ADOGEN 240) and varied the acid used in the suspending agent. The compositions of Examples 8-14 each effectively resisted phase separation at 43 °C (110 °F) and 49 °C (120 °F) for a period of at least six months. To further demonstrate the ability of an amine having the general structural formula (I) or (II) or (III) and a suitable acid to suspend a water-insoluble hair treating compound, different combinations of various amines and various acids were tested for an ability to suspend a silicone blend, or a combination of a silicone blend and sulfur, in water. In each test, the aqueous solution included 2% by weight of a silicone blend including one part by weight Silicone GUM SE-30 and 2 parts by weight SF 96-350 Silicone Fluid. The solution did not include a cleansing surfactant. Therefore, from the composition listed in TABLE I, wherein each composition was absent a cleansing surfactant, it was shown that the combination of the amine and the acid suspends the silicone and, when present, the sulfur. In the composition of Example 15 summarized in TABLE I, the amine was present in an amount of from 3% to 5% by weight; the acid was present in an amount of from 0.5% to 1.6% by weight. Suspending Agents Including an Amine and an Acid Example Amine Acid 8 ADOGEN 232 (3%) Phosphoric Acid (0.80 %) The composition of Example 8 was a stable composition that effectively suspended the silicone and the sulfur after storage at room temperature and at 49 °C (120 °F) for 3 months. Therefore, the silicone was effectively suspended by the suspending agent of the present invention. In compositions including a tertiary amine, it was found that flocculation, or curdling, of the composition can occur after one day of storage at 49 °C (120 °F), however the silicone remains suspended in the composition. Overall, the composition of Example 8 of TABLE I show that a primary, secondary, or tertiary amine having the general structural formula (I) or (III), or an amine having the general structural formula (II), when neutralized with a sufficient amount of a suitable acid, effectively suspends a water-insoluble hair treating compound, either liquid or particulate, in an aqueous composition. Further, TABLE I, and Examples 1-7 , show that an inorganic mineral acid (e.g., composition of Example 8 , is a suitable acid to neutralize the amine. TABLE I also shows that an amine of general structural formula (I) (Example 8), after neutralization by a sufficient amount of a suitable acid, effectively suspend a water-insoluble hair treating compound in a hair shampoo composition. To further demonstrate the stability of a shampoo composition of the present invention, various amines and acids, in varying amounts, were used as the suspending agent in a composition that included 2% by weight of a water-insoluble silicone blend of 1 part Silicone GUM SE-30 and 2 parts by weight SF 96-350 Silicone Fluid; 12.10% by weight, in total, of the anionic surfactants ammonium lauryl sulfate, ammonium lauryl ether sulfate (1 mole EO) and sodium lauryl sulfate; and 0.90% of the alkanolamide lauramide DEA. TABLE II lists the particular amine and particular acid used in each compositions of Examples 9 through 14 the amount of amine and acid included in each composition, and the stability of each composition. The percentages included in TABLE II are the weight percentages of the active amount of amine and acid included in each composition. Stability of Shampoo Compositions Including an Amine-Acid Suspending Agent Example Amine Acid Stability 9 ADOGEN 240 (3 %) PHOSPHORIC 0.51 % Stable at all temp. 10 ADOGEN 240 (3 %) SULFURIC 0.30 % Stable at all temp. 11 ADOGEN 240 (3%) HYDROCHLORIC 0.22% Stable at all temp. 12 ADOGEN 240 (2.5%) HYDROCHLORIC 0.18% Stable at all temp. 13 ADOGEN 240 (2.0%) HYDROCHLORIC 0.14% Stable at all temp. 14 ADOGEN 240 (3.0%) HYDROCHLORIC 0.22% Stable at all temp. TABLE II shows that a variety of amines having general structural formula (I) can be neutralized with a variety of inorganic acids or organic carboxylic acids to provide an effective suspending agent for a shampoo composition including a water-insoluble hair treating compound. In addition, compositions of Examples 9 through 14 were subjected to laboratory and beauty center evaluations, and found to have physical and esthetic properties, such as pearl, wet and dry combing, cleansing performance, lather and feel, that equal the properties exhibited by SUAVE, a leading hair shampoo conditioner composition available commercially from Helene Curtis, Inc., Chicago, Illinois. To further demonstrate the ability of the suspending agent to provide a stable hair shampoo composition including a water-insoluble hair-treating compound, the following compositions of Examples 15 through 18 (comparison examples) were prepared by the above-described method. The compositions of Examples 15 through 18 each include a water-insoluble antidandruff compound; the compositions of Examples 16 to 18 further include a water-insoluble silicone blend as a hair conditioner. Each composition of Examples 15 through 18 resisted phase separation and effectively delivered the water-insoluble hair treating compound, or compounds, to hair shampooed with the composition. Ingredient EX. 15 EX. 16 EX. 17 EX. 18 Ammonium Lauryl Sulfate 3.75 3.75 -- -- Sodium Lauryl Sulfate 6.75 6.75 10.5 10.5 Ammonium Lauryl Ether Sulfate 2.4 2.4 2.8 2.8 Lauramide DEA 1.05 1.05 1.23 1.23 ADOGEN 240 3.50 3.50 3.00 3.00 Citric Acid 0.50 0.50 0.50 0.50 Sulfur 2.00 9 2.00 9 -- -- Zinc complex of 2-pyridinethiol-1-oxide -- -- 1.05 1.05 Silicone Blend -- 2.00 -- 2.00 Tetrasodium EDTA 0.08 0.08 -- -- Dye 0.001 0.001 0.002 0.002 Fragrance 0.35 0.35 0.35 0.35 Preservative 0.15 0.15 0.15 0.15 Ammonium Xylene Sulfonate 0.15 0.15 0.18 0.18 Soft water q.s. q.s. q.s. q.s. Appearance: pearlescent pearlescent pearlescent pearlescent Therefore, the method and composition of the present invention provide a shampoo composition that exhibits an exceptional ability to suspend either a liquid or a particulate water-insoluble hair treating compound, or a combination thereof. The increased ability to suspend the water-insoluble hair treating compound permits the incorporation of unexpectedly high amounts of silicones, hydrocarbons and other water-insoluble conditioning agents, or an antidandruff agent, or other hair-treating compound into a shampoo composition, or combination. It is both surprising and unexpected for an aqueous composition of the present invention, including a water-insoluble hair-treating compound, like a polydimethylsiloxane or an antidandruff agent, to effectively resist phase separation, to effectively cleanse the hair and to effectively deliver the hair treating compound to the hair or scalp, while maintaining an acceptable foam level and exhibiting sufficient physical and esthetic properties for consumer acceptance.

Claims: A shampoo composition comprising: (a) 3% to 40% by weight of an anionic cleansing surfactant; (b) 0.1% to 10% by weight of a water-insoluble hair treating compound; (c) a suspending agent comprising: (i) from 1% to 10% by weight of the composition of an amine having the general structural formula or a combination thereof, wherein R 1 is an alkyl group including at least 16 carbon atoms; R 2 and R 3 are, independently, selected from the group consisting of hydrogen, an alkyl group including one to 22 carbon atoms, benzyl and phenyl; R 4 is an alkyl group including at least 13 carbon atoms; R 5 is an alkylene moiety including one to four carbon atoms; R 6 and R 7 are, independently, an alkyl group including one to four carbon atoms; and R 8 and R 9 are, independently, hydrogen or an alkyl group including 1 to 4 carbon atoms; and (ii) a sufficient amount of an acid such that essentially no solid particles of the amine are present in the composition and such that the composition has a pH of 5 to 8, said acid being selected from an inorganic mineral acid; and (d) a carrier comprising water. The composition of claim 1, wherein the water-insoluble hair treating compound is a conditioning agent, an antidandruff agent, or a combination thereof. The composition of claim 2, wherein the conditioning agent is selected from the group consisting of a silicone conditioning agent, preferably a nonvolatile silicone conditioning agent, a volatile silicone conditioning agent, or a combination thereof, a hydrocarbon conditioning agent, preferably a volatile hydrocarbon conditioning compound, a water-insoluble fatty alcohol including 12 to 22 carbon atoms, a water-insoluble fatty ester including 9 to 34 carbon atoms, and combinations thereof. The composition of claims 2 or 3, wherein the conditioning agent is selected from the group consisting of a polysiloxane polyether copolymer; an acetylated lanolin alcohol; a lanolin-derived extract of sterol or a sterol ester; lanolin alcohol concentrate; an isopropyl ester of a lanolin fatty acid; a polyol fatty acid; a keratin protein derivative; an amino-functional silicone; a mineral oil and lanolin alcohol mixture; a high molecular weight ester of lanolin; a vinylpyrrolidone/dimethylaminoethylmethacrylate copolymer; a 5 mole ethylene oxide adduct of soya sterol; a 10 mole ethylene oxide adduct of soya sterol; a stearic acid ester of an ethoxylated methyl glucoside; a hydroxylated lanolin; lactamide MEA; stearamide MEA; an ethoxylated long chain alcohol; a propoxylated long chain alcohol; hydrolyzed animal keratin; ethyl hydrolyzed animal keratin; avocado oil; sweet almond oil; grape seed oil; jojoba oil; apricot kernel oil; sesame oil; hybrid safflower oil; wheat germ oil; an ethyl ester of a hydrolyzed animal protein; a blend of cetyl and stearyl cetearyl alcohol with an ethoxylated cetyl or stearyl alcohol; a propoxylated (1-10 moles) lanolin alcohol; isostearamide DEA; a hydrolyzed collagen protein; and combinations thereof. The composition of any one of claims 2 to 4, wherein the antidandruff agent is selected from the group consisting of salicylic acid, elemental sulfur, selenium sulfide, zinc pyrithione, an azole antimycotic, a water-insoluble 1-hydroxy pyridone, undecylenic acid, and combinations thereof. The composition of any one of claims 1 to 5, wherein the water-insoluble hair treating compound is present in the amount of 0.5% to 5% by weight of the composition. The composition of any one of claims 1 to 6, wherein the amine is a solid compound at room temperature and has a water solubility of 0.5 grams or less per 100 milliliters of water, and is preferably present in an amount of 1.5% to 5% by weight of the composition. The composition of any one of claims 1 to 7, wherein the amine is selected from the group consisting of C 20-22 amine, soya amine, hydrogenated tallow amine, stearyl amine, tallow amine, oleyl amine, hexadecylamine, octadecylamine, di(hydrogenated tallow)amine, disoyamine, dipalmityl amine, tri(hydrogenated tallow) amine, di(hydrogenated tallow) methylamine, distearyl methyl amine, methyl dibehenamine, dimethyl behenamine, dimethyl tallowamine, dimethyl stearamine, dimethyl tetradecylamine, dimethyl hexadecyl amine, dimethyl octadecyl amine, dimethyl soyamine, dimethyl oleyl amine, stearyl methyl benzyl amine, dimethyl palmitamine, dimethyl (hydrogenated tallow)amine, dimethyl myristamine, stearamidopropyl diethylamine, stearamidoethyl diethylamine, stearamidoethyl dimethylamine, palmitamidopropyl dimethylamine, behenamidopropyl dimethylamine, myristamidopropyl dimethylamine, oleamidopropyl, dimethylamine, ricinoleamidopropyl dimethylamine, stearamidopropyl dimethylamine, hydrogenated tallow diamine, tallow diamine, soya diamine, oleyl diamine, and combinations thereof. The composition of anyone of claims 1 to 8, wherein the inorganic mineral acid is selected from the group consisting of hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, and combinations thereof. The composition of anyone of claims 1 to 9 further comprising 0% to 5% of a nonaqueous solvent. The composition of anyone of claims 1 to 10, wherein the anionic cleansing surfactant is an alkyl sulfate, an alkyl ether sulfate or a combination thereof; the water-insoluble hair treating compound is a polydimethylsiloxane, a volatile hydrocarbon, zinc pyrithione, elemental sulfur, or a combination thereof; the amine is hydrogenated tallow amine, di(hydrogenated tallow)amine, dipalmityl amine, tri(hydrogenated tallow)amine, distearyl amine, hydrogenated tallow diamine, distearyl methyl amine or a combination thereof; and the acid is citric acid, lactic acid, phosphoric acid, hydrochloric acid, palmitic acid, lauric acid or a combination thereof. The composition of anyone of claims 1 to 11 further comprising 0% to 5% by weight of a nonionic surfactant, preferably an alkanol amide. A suspending agent for suspending a water-insoluble compound in an aqueous composition comprising: (a) 1% to 10% by weight of the aqueous composition of an amine having the general structural formula or a combination thereof, wherein R 1 is an alkyl group including at least 16 carbon atoms; R 2 and R 3 are, independently, selected from the group consisting of hydrogen, an alkyl group including one to 22 carbon atoms, benzyl and phenyl; R 4 is an alkyl group including at least 13 carbon atoms; R 5 is an alkylene moiety including one to four carbon atoms; R 6 and R 7 are, independently, an alkyl group including one to four carbon atoms; and R 8 and R 9 are, independently, hydrogen or an alkyl group including 1 to 4 carbon atoms; and (b) a sufficient amount of an acid such that essentially no solid particles of the amine are present in the composition and such that the composition has a pH of 5 to 8, said acid being selected from an inorganic mineral acid. A method of cosmetic treatment of the hair comprising contacting the hair with a sufficient amount of a cosmetic shampoo composition, said shampoo composition being defined as in any one of claims 1 to 12.

Inventors: DOWELL TERESA JOLANTA, NEWELL GERALD PATRICK, ZEFFREN EUGENE, DOWELL, TERESA JOLANTA, NEWELL, GERALD PATRICK, ZEFFREN, EUGENE
Applicants: CURTIS HELENE IND INC, HELENE CURTIS, INC.
Application year: 1993
Main classification: A61K7
IPC codes: A61Q5, A61K8, C11D3, C08L83