Cooling method and apparatus

Abstract: Apparatus and method for cooling an extruded blown plastics film in which the interior surface of the thin film bubble is contacted with an anhydrous cooling gas which does not contain water vapour thereby to cool the extruded film and form a spent gas employs a mixing chamber 72 having a first inlet 66 for liquid cryogen such as liquid nitrogen and a second inlet 68 for spent gas in order to form the cooling gas. The mixing chamber 72 may form part of an ejector 74 which may be located internally of or outside the bubble itself. Improved film production rates are made possible.

Description: The present invention is directed to an apparatus and method for cooling the interior surface of extruded plastics blown film, in the absence of water vapour. Such cooling can improve the rate of production of the blown film. The technique of blown film extrusion is well known for the production of plastic films having a typical thickness between 10 and 300 microns. Plastics, such as low, linear low, and high density polyethylene (LDPE, LLDPE, HDPE) are extruded through a circular die to form a film. Air is introduced through the centre of the die to maintain the film in the form of a bubble which increases the diameter of the film about two to six-fold, after which the bubble is collapsed onto rollers. As the plastics moves away from the die, it begins to cool due to the near ambient temperature of the air blown on the outside surface of the bubble and, in some cases, inside the bubble. The rate of cooling of the bubble is a production rate limiting factor and therefore efforts have been made to increase the rate at which the bubble is cooled. There are two commercially practised methods for increasing the cooling rate of existing internal bubble cooling systems. The first is to increase the rate at which air is blown into the bubble. The second method is to lower the temperature of the air fed to the bubble. The first method is limited to airflow rates which do not adversely affect the stability of the bubble. As would be expected, an excessive airflow rate would make it difficult to maintain the shape of the bubble or could result in the collapse of the bubble. The second method is limited by the physical changes that air undergoes at low temperatures. It has been estimated by thermal analysis, that to obtain a 20% increase in the production rate of blown films, it is necessary to cool the gas entering an internal bubble cooling system to about -100°C, while maintaining the same flow rate. Quite obviously, when air is cooled to a low temperature the water vapour present in the air will freeze. Existing refrigeration equipment cannot function effectively when such ice formation occurs, and in any case such ice will typically interfere with the surface finish of the bubble. Thus, although significant cooling of the gas is desirable to increase production, there has yet to be developed a practical method of introducing extremely cold air into an internal bubble cooling system which is not hindered by the condensation and/or freezing of water vapour. FR-A-1 434 501 discloses an apparatus for producing synthetic resin tubes by a blowing process in which a regulated amount of cooling gas is repeatedly recirculated. The present invention is generally directed to an apparatus and method for cooling the interior surface of an extruded plastic blown film thereby to obtain significantly greater production rates of the blown film than is commonly achieved using existing techniques, the apparatus and method being defined in the accompanying claims. The method includes the step of introducing a cooled non-water vapour containing gas (hereinafter referred to as "anhydrous gas") into the interior of the extruded film, in the form of a bubble, so that the cooled gas contacts the interior surface of the blown plastics film. The cooling gas gives up its cooling duty to the bubble and is thereafter removed from contact with the inner wall of the bubble. All, or a portion, of the spent gas may then be cooled and recirculated to the bubble-making process. The exclusion of water vapour containing gas from the interior of the bubble allows the use of cryogenic gas in the method and apparatus according to the invention. The contact of the cooling gas with the interior surface of the bubble takes place preferably at low temperatures of less than 10°C, most preferably at temperatures of minus 100°C or less. The cooling duty from the anhydrous cooling gas rapidly cools the thin film even at high feed rates. The transfer of the cooling duty from the cooled gas to the (thin) film raises the temperature of the resulting gas and this warmed spent gas is transported out of the bubble and may be discarded. The spent gas is not entirely discarded. Instead, there is provided an enclosed circulation system in which the spent anhydrous gas is recovered from the bubble and a portion recycled to a cooling means. (This recycling may be performed internally or externally of the bubble.) The cooled gas is then sent back through the enclosed circulation system to the production facility for cooling the extruded plastic film. The production rate of the blown film may be increased by 20% or more over existing methods when employing the method of the present invention. The cooled gas is obtained from a liquid cryogen which, when mixed with a portion of the spent gas, forms a gas at a temperature corresponding to that at the inlet of the bubble of the blown film (e.g. -100°C or less). The liquid cryogen is preferably liquid nitrogen or liquid carbon dioxide, but could be a refrigerant such as Freon (RTM). Means is provided for generating a blown film cooling gas by injecting the coolant into the stream of the recycled spent gas to provide the motive force for circulating the resulting recooled gas to the extruded plastic film. The rate at which energy is removed from the blown film by the recooled gas is principally dependent on the rate at which the coolant enters the system. Spray nozzles may be used, for example, to inject the coolant into the stream of the recycled spent gas. The preferred means for injecting the coolant into the system is an ejector which allows the coolant to vaporise and thermally mix with the spent gas. By excluding air from the inside of the blown film and circulation loop, a significant decrease in the temperature of the circulated gas can be obtained without the formation of condensation or ice crystals. In one aspect of the invention, the amount of cooling needed to cool the spent gas to a desirable cooling temperature is balanced with the amount of motive force required to recirculate the cooled gas to the extruded film and the spent gas to the injecting means. The ejector is preferably supplied with a high pressure liquid cryogen, such as liquid nitrogen or liquid carbon dioxide, or a mixed liquid/gaseous cryogen. The mixed liquid/gaseous cryogen significantly increases the kinetic energy available to the system for recirculating the gas while only moderately affecting the available cooling duty. Thus, in accordance with a preferred form of the invention the interior of the blown film is rapidly cooled by the injection of a low temperature gas in a manner which may increase the production rate of the thin film by up to 20% or more. In addition, since all water vapour containing anhydrous gases are substantially eliminated from the system, the problems of condensation and freezing and consequential damage to the blown film are reduced or eliminated. The method according to the invention will now be described by way of example with reference to the accompanying drawings, in which: Figure 1 is a schematic view of a typical conventional blown film extrusion apparatus; Figure 2 is a schematic view of one embodiment of the invention shown in conjunction with a blown film extrusion apparatus of the type shown in Figure 1; Figure 3 is a schematic side view in cross-section of an ejector used in the present invention for thermally mixing and circulating a liquid coolant or liquid/gas mixture with a recirculated spent gas; Figure 4 is a schematic view of another embodiment of the invention shown in conjunction with a blown film extrusion apparatus of the type shown in Figure 1; Figure 5 is a schematic view of still another embodiment of the invention in which an ejector is placed within the bubble of the thin film; and Figure 6 is a graph comparing the temperatures of the cooled gas to the mass ratio of the spent gas/coolant for a given energy level of incoming coolant. Referring to the drawings and particularly to Figure 1 there is shown a known blown film extrusion device 2, comprised of a bubble forming section 4, a control section 6 and a thin film forming section 8. The bubble forming section 4 includes an inlet 10 for receiving a suitable molten, plastic resin such as high or low density polyethylene. A pathway 14 is provided for the flow of the melted resin from the inlet to a narrow annular outlet 16 which forms the molten resin into a continuous bubble 18 when air is blown into the resin within the circumference of the annular outlet. The thickness of the resulting bubble is typically between 10 and 300 microns. The control section 6 controls the size of the bubble. The control section 6 is provided with sensors 20 which detect the diameter of the bubble 18 and transmit a detectable signal to a damper 21 which adjusts internal bubble pressure which determines the size of the bubble. The film forming section 8 includes a frame 24 which draws the sides of the bubble 18 inwardly so that the sides collapse on one another to form two layers of film 26. The film is passed through nip rolls 28 which draws the two layers of film upward and sends the compressed film to a storage facility (not shown). Once the melted resin is extruded out of the annular outlet 16, the resulting bubble 18 must be cooled. Cooling occurs at least on the outer surface of the bubble and, in some blown film systems, on the inner surface as well. External cooling air is supplied through a conduit 30 into a nozzle 32 having openings which allow the cooled air to contact the surface of the bubble 18 around its circumference. Internal cooling is provided by an open ended cooling system 34 comprised of an inlet 36 for receiving refrigerated or ambient temperature air from a source (not shown) through a conduit 38. A positive pressure is applied by a blower (not shown) and the flow is controlled by a damper (not shown). The pressure is sufficient to send the cooled air to a nozzle or diffuser plate 42, placed within the circumference of the resin extruded out of the outlet 16, where the flow is directed along the interior bubble surface. The cooled air is circulated within the bubble 18 and loses its cooling duty to the interior bubble surface. The resulting warmer air (spent gas) is removed from the bubble 18 through an outlet 46 and out of the bubble forming apparatus via a conduit 48 through a damper 21 and a blower (not shown). The rate at which energy is removed from the bubble (i.e. cooling) determines the rate at which the thin film can be extruded. Energy removal may be viewed as the product of the mass flow of the plastic and the energy that must be removed per unit mass of plastic. For example, the energy removal rate of the plastic in the prior art system of Figure 1 may be 30 kW based on a mass flow rate of plastic of 0.075 kg/sec (600 lb/hr) and an amount of energy to be removed per unit mass of plastic of about 400 kJ/kg. It can be assumed that about 1/3 (10 kW) of the energy removed will be from inside the bubble and the remaining 2/3 (20 kW) from outside the bubble. Since the outer cooling load remains largely the same regardless of the type of internal cooling system employed, any attempt to increase the mass flow rate of plastic will require significantly greater cooling from the gas present in the inside of the bubble. For example, if a 30% increase in film production is desired (equivalent to an energy removal rate of 39 kW for the above example), the amount of energy removed from the inside of the bubble will have to increase from 10 kW as in the prior art system described above to 19 kW (a 90% increase). The removal of such greater amounts of energy can be accomplished by having an internal bubble cooling system which can operate at lower temperatures than is customary. In addition, having a system in which water vapour is not present, preferably an enclosed circulation system, eliminates the condensation and/or freezing problems associated with known internal bubble cooling systems operating at low temperatures. Accordingly, the present invention can produce blown films at varying rates of production without concern for the formation of water droplets or ice crystals within the bubble. Referring to Figures 2 and 3, there is shown an embodiment of the internal bubble cooling apparatus of the present invention employing an ejector for distributing the gaseous coolant within the bubble. An extrusion device 52 of the same type shown and described in connection with prior art Figure 1 is provided with a cooling system in the form of an enclosed circulation system, shown generally by numeral 54. The cooling system 54 includes an inlet 56 for injecting a cooled gas into the bubble 58 and an outlet 60 for removing spent gas which has given its cooling duty to the inner surface of the bubble 58. The cooled gas, which is transmitted to the bubble 58 via a conduit 62, is generated within an ejector 64. The ejector 64 combines a liquid coolant, such as a liquid cryogen (e.g. liquid nitrogen or liquid carbon dioxide) or a mixture of liquid and gaseous cryogen, from a first inlet 66 and the spent gas in a manner which provides both cooling and motive force to the spent gas. There is thus generated a stream of cooled gas having sufficient pressure to enter the bubble 58 and cool the inner surface thereof. Referring to Figure 3, the ejector 64 includes the first inlet 66 for receiving the coolant, such as liquid nitrogen, and a second inlet 68 for receiving the spent gas (e.g. nitrogen gas) which is recycled from the bubble 58 via a conduit 70. A chamber 72 receives the liquid coolant from the first inlet 66 and the spent gas from the second inlet 68 and allows thermal mixing thereof. The liquid coolant vaporises and provides both cooling and motive force to the spent gas to thereby form a pressured stream of cooled gas for transmission to the inlet 56. The ejector 64 has a parallel flow region 74 which serves to enhance the intimate thermal and momentum mixing of the liquid coolant and spent gas. The mixed gas is then sent to a diffuser section 76 which allows the mixed gas to increase its pressure prior to exiting the ejector 64 through an exit port 78. It is preferred that the ejector 64 provide as much of the recirculation energy as possible (i.e. the draft at a particular flow rate). It is therefore necessary to consider the draft generated by the ejector 64. The draft is measured by the difference in pressure between the spent gas entering the chamber 72 via the second inlet 68 and the mixed gas exiting through port 78. The majority of the draft requirements for an internal bubble cooling system are associated with the pressure drop entering and exiting the bubble. For a prior art system as shown in Figure 1, the pressure drop into the bubble can be as much as 20" (50.8 an) water column (w.c.) (5000 Pa) and the pressure drop out of the bubble as much as 30" (96.7 cm) w.c. (7,500 Pa). However, it is known from theory that pressure drop increases proportional to the square of the flow rate of air and directly proportional to the absolute air temperature. Therefore, an internal bubble cooling system that utilises the method of the present invention can have significantly different draft requirements compared to the prior art. For example, with a gas inlet temperature of -125°C (compared to about 20°C for the prior art) and a cooling gas flow rate of about 60% of the prior art flow rate, the total draft is reduced from 50" w.c. (12,500 Pa) to 16" w.c. (4,000 Pa) while still achieving a 20-30% production increase. Referring again to Figure 2, the system eliminates from the enclosed circulation system a quantity of spent gas equal to the amount of the coolant entering the system through the ejector 64. Accordingly, the system is provided with a vent means 80 including a conduit 82 for transporting the gas to be vented out of the conduit 70 via a control damper 84 and a blower 86. The control damper 84 is coupled to the bubble size sensors 20 as shown best in Figure 1. The sensors 20 maintain the pressure within the bubble so as to maintain the desired blow-up ratio. For the embodiment shown in Figure 2, it is not possible to balance the exhaust and pressure requirements for the bubble without the use of the control damper 84 and the blower 86. A control damper 88 is also provided on the main conduit 70 to control the rate at which the spent gas is recycled back to the ejector 64. In accordance with the present invention, it is evident that compared to the prior art internal bubble cooling systems, the number of required blowers is reduced from two to one and the flow rate the blowers must handle is significantly reduced as well (e.g. by 1/2 to 1/4). Due to the operating characteristics of ejectors, as the mass ratio of spent gas to the coolant entering the ejector increases, the pressure boost or draft produced by the ejector decreases. This behaviour, coupled with large draft requirements in some blown film installations, may produce situations where the ejector 64 cannot provide the total pressure boost. In this event, the blower 86 is preferably placed in the mainstream of the recycled flow to assist the ejector 64 in handling the draft requirement. Referring to Figure 4, there is shown an embodiment of the invention in which the blower 86 is positioned within the enclosed circulation system in a manner which assists the ejector 64 in providing the necessary pressure boost for circulating the spent gas. The blower 86 is therefore positioned along the conduit 70. Control dampers 84 and 88, as described in connection with Figure 2. For this embodiment of the invention, there is also a reduction of one blower compared to the prior art. However, in this embodiment, the blower must handle the full flow rate from the bubble rather than only the amount vented to the atmosphere. In the embodiment shown in Figure 4, an ejector is not required for circulation because the blower 86 can be properly sized to provide the full pressure boost required. In this case, the ejector can be replaced with spray nozzles fed by the coolant and directed into the conduit 70. In another embodiment of the invention, the pressure boost requirements for the ejector are essentially eliminated by positioning the ejector within the bubble. As a result, the ejector can provide a much broader range of mass ratios of spent gas to coolant (up to at least 3:1) without regard to the pressure boost. Referring to Figure 5, an ejector 64 is shown within the bubble 58. A coolant is provided to the ejector 64 via a conduit 90. The line 90 extends to the upper portion of the ejector 64 and provides a pathway for the flow of the coolant to a first inlet 92. The spent gas enters the ejector 64 through a second inlet 68 while the mixed cooled stream for cooling the bubble leaves the ejector 64 through an exit port 96. The mixed stream, upon leaving the exit port 96, is directed (as in the prior art shown in Figure 1) to a nozzle or diffuser plate 42, where the flow is directed along the inner surface of the bubble until it is drawn into the second inlet 68. Control damper 88 is provided within second inlet 68 to control the rate at which spent gas is recycled back to ejector 64. The vent gas is removed from the bubble 58 through a conduit 98, which extends upward into the bubble to ensure withdrawal of the warmer spent gas by a blower 102. Control of the bubble internal pressure is made, as in the prior art, by a control damper 100 coupled to a size sensor 20 (see Figure 1). The amount of vent gas expelled from the system through the conduit 98 is substantially equal to the coolant added to the system through the conduit 90. As previously described, because the coolant is mixed with the spent gas, the actual gas inlet temperature to the blown film will vary depending on the mass ratio of the spent gas to the incoming coolant. The energy removal rate provided by the cold gas for the plastic film is governed by the flow rate of the coolant into the ejector; however the inlet temperature of the cold gas as it enters the bubble and the total inlet flow rate is controlled by the amount of spent gas which is recirculated and mixed with the coolant in the ejector. Referring to Figure 6, there is illustrated a typical graph for liquid nitrogen coolant which shows that the outlet temperature of the mixed stream is a function of the mass ratio of the spent gas to the injected coolant. For a given amount of cooling (determined by the flow rate of the coolant), the product of the mass flow rate of cold gas entering the bubble multiplied by the temperature difference between the inlet and outlet gas streams will be constant. Therefore, small mass ratios (with correspondingly small mixed gas flow rates) will have relatively cold inlet temperatures while large mass ratios (with large mixed gas flow rates) will have relatively warmer inlet temperatures. There are several advantages to operating an internal bubble cooling system at low flow rates, including increased bubble stability and lower draft requirements. However, because of the mechanical problems associated with operating at very low temperatures (e.g. less than -100°C), it is not always possible to operate the system at mass ratios as low as 1:1. The system of the present invention provides for rapid cooling of the extruded film which may be sufficient to increase production rate over known air cooled systems by up to 20% or more. The change in the pressure drop caused by a change in the mass flow rate can be handled by either an ejector alone or with the assistance of an in-line blower. Example An embodiment of the invention in accordance with Figure 2 is employed in this example. 0.057 kg/s of liquid nitrogen at a pressure of 0.31-1.24 MPa (45-180) psia and 0.114 kg/s of spent nitrogen gas is fed to an ejector of the type shown and described in connection with Figure 3. The total mixed feed of 0.171 kg/s having a temperature of from -134 to -118°C is fed to the inlet of a standard blown film internal bubble cooling system of the type shown in Figure 1. The ejector will provide from 7" to 15" water column (1,750 to 3,750 Pa) draft. The spent gas is removed from the outlet at a temperature of 0°C. The rate of production of the film is 0.0975 kg/s (774 lb./hr.) and would exceed known air cooling systems by about 20 to 30%.

Claims: Apparatus for cooling an extruded blown film comprising: (a) means for forming an anhydrous cooling gas; (b) means for contacting an interior surface of a bubble of the extruded blown film with said anhydrous cooling gas thereby to cool the extruded blown film and form a spent gas; (c) means for recovering spent gas from the bubble of the blown film; (d) a vent conduit (82,98) communicating with the interior of the bubble for discharging spent gas to outside the apparatus; wherein said gas forming means comprises a mixer (64) having a first inlet for the intake of liquid cryogen communicating with a source of liquid cryogen and wherein the spent gas recovery means includes a second inlet of said mixer (64), whereby, in use, a part of the spent anhydrous gas is vented to outside the apparatus, and a circulation system is provided in which another part of the spent anhydrous gas is recovered from the bubble and recycled to the contacting means, the recycling being performed internally or externally of the bubble and motive force for the recycling being provided by injection of the liquid cryogen into the spent anhydrous gas. Apparatus according to Claim 1, wherein said mixer (64) comprises a mixing chamber separate from and unbounded by said bubble. Apparatus according to Claim 1, wherein said mixer (64) comprises an ejector (64) located within the bubble, and having an outlet (96) which is positioned such that in use the ejector also functions as said contacting means. Apparatus according to Claim 3, wherein said second inlet has a damper (88) provided within it for controlling the rate at which spent gas is taken into the ejector. Apparatus according to any one of the preceding claims, wherein said vent conduit (82,98) has a blower (86,102) disposed in it. Apparatus according to Claim 5, wherein there is a damper (84,100) in said vent conduit (82,98) upstream of the blower (86,102) operable to adjust the rate at which spent gas is vented. Apparatus according to Claim 2, wherein the second inlet communicates with the interior of the bubble via a first conduit (70), and its outlet (78) communicates with the interior of the bubble via a second conduit (62), and the vent conduit (82) communicates with the bubble via the first conduit (70). Apparatus according to Claim 7, including a first damper (88) in the first conduit (70) for adjusting the pressure in the bubble, and a second damper (84) in the vent conduit (82) for controlling the rate of venting gas. Apparatus according to Claim 8, in which a blower (86) is located either in the first conduit (70) or the vent conduit (82). Apparatus according to any one of Claims 7 to 9, wherein the mixer (64) is in the form of an ejector (64). Apparatus according to any one of Claims 7 to 9, wherein the mixer (64) comprises a length of the first conduit (70). A method of cooling an extruded blown film comprising (a) contacting the interior surface of a bubble of the blown film with an anhydrous cooling gas, (b) forming the anhydrous cooling gas in a mixer having a first inlet for liquid cryogen communicating with a source of the liquid cryogen and a second inlet for spent gas communicating with the interior of the bubble, and (c) venting a portion of the spent gas, whereby a circulation system is provided in which another portion of the spent gas is recovered from the bubble and mixed with the liquid cryogen, and the resulting mixture is recycled to the bubble as the anhydrous cooling gas, the recycling being performed internally or externally of the bubble and motive force for the recycling being provided by injection of the liquid cryogen into the other portion of the spent gas. A method according to Claim 12, in which the liquid cryogen is liquid nitrogen. A method according to Claim 12 or Claim 13, in which the cooling gas leaves the mixer at a temperature of -100°C or less.

Inventors: KIRSCHNER MARK JOSEPH, LEE RON CLARK, KIRSCHNER, MARK JOSEPH, LEE, RON CLARK
Applicants: BOC GROUP INC, THE BOC GROUP, INC.
Application year: 1993
Main classification: B29C47
IPC codes: B29C47, B29C49, B29L7