Biaxially oriented film

Abstract: A biaxially oriented film and a laminated film contain organic particles at a content of 0.001 to 20% by weight. The strength when deformed by 10% (S₁₀) of the organic particles is in the range of 3 to 30 kgf/mm² and the thermal decomposition temperature for causing 10% loss in weight thereof is not lower than 350°C. The weight average diameter thereof is in the range of 0.005 to 5 µm. The film is particularly useful as a base film of a magnetic tape.

Description: The present invention relates to a biaxially orientated film which is excellent in abrasion resistance and scratch resistance such that a surface of the film has excellent scratch resistance even when running at a high speed, for example, when it is processed into, and then used as, a magnetic recording medium. EP-A-0546184, acknowledged under Art.54(3)EPC, discloses a polyester film and laminate containing it, which film contains organic polymeric particles whose strength when deformed by 10% (S 10 ) is not more than 10 kgf/mm 2 (98.1 MPa). Comparative Example 4 describes a laminate containing a film which contains organic polymeric particles whose strength when deformed is 10.8kgf/mm 2 (106MPa). The particles consist of methyl methacrylate/ethylene glycol dimethacrylate (weight ratio 10/90), and have a thermal decomposition temperature not lower than 350°C, a weight diameter of 1.5µm and are present in an amount of 3wt% of the film. Generally, a thermoplastic polyester, for example, polyethylene terephthalate, has excellent mechanical properties and chemical properties, and is widely used for producing a formed product such as a film or fiber. When a thermoplastic polyester is processed into and used as a formed product, the slipping property and the abrasion resistance thereof greatly affect its working ability during production of the final formed product, during processing of the product into articles for various uses, and when using such articles. For example, when the polyester is used as a base film of a magnetic tape, if these properties are unsatisfactory, the friction between the film and a coating roll used in the process for production of magnetic tapes becomes larger, and wrinkles and scratches are likely to occur in the film. Furthermore, production of powder abraded from the film is liable to occur, so that in the process for coating a magnetic layer onto the film, parts of the film are missed, and as a result, part of a magnetic record is likely to be missed ("drop out"). Moreover, recently a problem has been that a magnetic surface can be scratched by contact with a non-magnetic surface in a winding process after coating of a magnetic material and calendering and the scratches cause reduction of image quality such as drop out when the magnetic recording medium is in use. As a conventional method for improving the slipping property of a film, incorporation of inorganic particles such as titanium dioxide, calcium carbonate or silicon dioxide particles in the polyester is proposed in many disclosures. However, since these inorganic particles are hard and poor in their affinity with polyester, then, for example, when the polyester is used as a film and subjected to an external force (caused, for example, by a calendering operation in a magnetic layer coating process, a contact with a roll during running of the film or a contact between the surfaces of the film in winding), the particles easily fall off from the film and this causes occurrence of loose chippings, deterioration of the slipping property and occurrence of wrinkles on the film surface. Moreover, because the fallen particles themselves are hard, the chippings and the wrinkles on the film surface multiply as time passes. Thus, when the amount of the chippings increases and wrinkles occur on the film surface, parts of the coating in a magnetic layer coating process are likely to be missing and drop out is liable to occur. Further, resulting dirt on the calender roll used in the process for coating a magnetic layer remarkably deteriorates the working ability in the production of a magnetic recording film. Thus, since such scratches and poor abrasion resistance (caused by the fact that particles such as inorganic particles, which are hard and poor in their affinity with polyester, are likely to receive directly an external force) have been experienced, there is a desire for improvement. As respective methods for improving the affinity of particles with polyester, treating the surfaces of inorganic particles and using organic particles have been proposed. As the surface treatment of inorganic particles, for example, surface treatment by polyacrylic acid polymers is proposed in JP-A-SHO 63-128031, surface treatment by a phosphorus compound is proposed in JP-A-SHO 62-235353 and 63-234039, surface treatment by a coupling agent is proposed in JP-A-SHO 62-223239 and 63-312345, surface treatment by a silane compound is proposed in JP-A-SHO 63-304038, and surface treatment by a graft using glycol is proposed in JP-A-SHO 63-280763. However, it is difficult to obtain both of an appropriate hardness and a good affinity of the particles, and a sufficient abrasion resistance cannot be obtained by these methods. As the organic particles, crosslinked polymeric particles are proposed in, for example, JP-B-SHO 63-45409, JP-A-SHO 59-217755 and JP-A-HEI 2-189359. However, the particles proposed by these methods do not have specified strength and degree of crosslinkage, and even if these methods are employed, a sufficient abrasion resistance at a high running speed cannot be obtained. As a biaxially oriented thermoplastic resin film used for magnetic recording media, a laminated film, wherein a layer containing inorganic or organic particles is laminated on at least one surface of a film and the relationship between the diameter of the particles and the thickness of the laminated layer is specified, thereby improving the handling ability, the running ability and the abrasion resistance, is known (JP-A-HEI-2-77431). In such a film, because protrusions having a uniform height are formed on the film surface, it is possible to remarkably decrease the damage to a magnetic surface such as the transfer of the shape of excessively large protrusions to the magnetic surface in a curing process or the upward thrust due to the protrusions in a calendering process. Particularly, such a film is suitable as a base film for a metal tape such as an 8mm VTR tape or a business-use VTR tape. Recently in magnetic tape makers, however, further cost down is planned, and a higher production speed or in a part of metal tapes, omission of a backcoat, which has been provided on a running surface of a conventional tape, have been investigated. In a case where a conventional base film for a metal tape has no back coat, then when the fast feed/rewind (FF/REW) operation is repeatedly carried out, a problem arises in that the running surface of the film is scratched or the drop out increases by generation of chipped powder. In particular, because the speed of the FF/REW is expected to be increased in the future, it will become extremely important to further increase the running durability of the surface of a base film. We have found that the abrasion resistance and the scratch resistance of a magnetic surface at a high running speed of a film can be greatly improved by using organic particles having a specified hardness or crosslinked organic particles having a specified hardness and a high degree of crosslinkage. This enables the provision of a biaxially oriented film excellent particularly in abrasion resistance at a high running speed and scratch resistance of magnetic surface at a high running speed. Furthermore, it enables the provision of a biaxially oriented film which can prevent abrasion of the surface of a base film, can suppress the increase of drop out and can maintain a running durability equivalent to that due to a backcoat even though the film runs repeatedly in a VTR. The present invention provides (1) a biaxially oriented film containing organic particles, which organic particles (a) are crosslinked polymer particles having a degree of crosslinking not less than 60%; (b) have a strength when deformed by 10% (S 10 ) which is in the range of 3 to 30 kgf/mm 2 ; (c) have a thermal decomposition temperature, for causing 10% loss in weight, not lower than 350°C; (d) have a weight average diameter in the range of 0.005 to 5µm; and (e) are present in a content of 0.001 to 20% by weight, based on the total weight of the film; and which biaxially oriented film is other than a film of Comparative Example 4 of EP-A-0546184; and (2) a biaxially oriented film having a Young's Modulus in at least one direction of the film of not less than 350 kgf/mm 2 (3435 MPa) and containing organic particles, which organic particles (a) are crosslinked polymer particles having a degree of crosslinking not less than 60%; (b) have a strength when deformed by 10% (S 10 ) which is in the range of 3 to 30 kgf/mm 2 ; (c) have a thermal decomposition temperature, for causing 10% loss in weight, not lower than 350°C; (d) have a weight average diameter in the range of 0.005 to 5µm; and (e) are present in a content of 0.001 to 20% by weight, based on the total weight of the film. A biaxially oriented film according to the present invention contains organic particles, whose strength when deformed by 10% (S 10 ) is in the range of 3 to 30 kgf/mm 2 (29.4 to 294 Mpa), whose thermal decomposition temperature for causing 10% loss in weight is not lower than 350°C and whose weight average diameter is in the range of 0.005 to 5µm, at a content of 0. 001 to 20% by weight. In the biaxially oriented film according to the present invention, the organic particles present have an appropriate hardness, that is, the particles are not too hard and are not too soft, because the strength of the particles when deformed by 10% (S 10 ) is in the range of 3 to 30 kgf/mm 2 (29.4 to 294 Mpa). Further, since the particles are organic particles, this allows them to have a good affinity with a matrix resin of the film. Therefore, the particles can form protrusions on the film surface, which do not easily fall down from the film surface and which can prevent damage to a magnetic surface when used as a base film of a magnetic tape such as the transfer of the shape of large protrusions to the magnetic surface in a curing process or the thrust up due to the protrusions in a calendering process. Thus, good abrasion resistance and scratch resistance of a magnetic surface at a high running speed can be obtained. Furthermore, the thermal resistance of the particles is maintained at a high level because the thermal decomposition temperature for causing 10% loss in weight of the particles is not lower than 350°C. The agglomeration of the organic particles can be prevented and the protrusion forming ability of the organic particles can be ensured particularly at the time of film formation. Therefore, preferable protrusions can be formed with certainty and the size and height of the protrusions can be controlled so as to be relatively uniform. Furthermore, since the weight average diameter of the organic particles is controlled in the range of 0.005 to 5 µm, protrusions having an appropriate size and an appropriate height are uniformly formed on the film surface. Therefore, the film surface can have an excellent running durability as well as good abrasion resistance and scratch resistance, especially when the film is used in a magnetic recording medium running at a high speed as described above. Such particles as described above are present in the biaxially oriented film at a content of 0.001 to 20% by weight. Therefore, the desired protrusions are appropriately formed on the film surface. FIG. 1 s a schematic sectional view showing a method for measuring the strength of particles (S 10 ) present in a film according to the present invention. Although the resin forming the biaxially oriented film according to the present invention is not particularly restricted, it is preferably a polyester. The polyester used for a biaxially oriented film embodying the present invention may be prepared from a dicarboxylic acid whose main acid constituent is an aromatic dicarboxylic acid or an ester-forming derivative thereof and a glycol. As the aromatic dicarboxylic acid in the polyester, for example, terephthalic acid, 2,6-naphthalene dicarboxylic acid, ethylene α,β-bis(2-chlorophenoxy)ethane-4,4'-dicarboxylic acid, diphenyldicarboxylic acid and isophthalic acid can be employed. As the glycol component in the polyester, for example, an aliphatic glycol such as ethylene glycol, butanediol, tetramethylene glycol or hexamethylene glycol or a cyclic diol such as cyclohexanedimethanol can be employed. As the polyester used in a film embodying the present invention, for example, a polyester whose main constituent is an alkylene terephthalate or alkylene naphthalate is preferred. The polyester may be a homopolyester or copolyester. As the copolymerized component, for example, an aliphatic dicarboxylic acid such as adipic acid or sebacic acid, a cyclic dicarboxylic acid such as hexahydroterephthalic acid or hexahydroisophthalic acid, polyethylene glycol, polypropylene glycol or 5-sodium sulfoisophthalic acid can be employed. In particular, it may be desirable to copolymerize a compound having a sulfonic group or a sufonate at a content of 0.1 to 5% by weight, preferably 0.1 to 3% by weight,to improve the dispersion property. In the biaxially oriented film according to the present invention, organic particles are present. As the organic particles, crosslinked organic particles, in more detail, crosslinked organic polymeric particles are preferred. The type of crosslinked organic polymeric particles present in a film embodying the present invention is not particularly restricted. Any particle at least a part of which is composed of a crosslinked polymer insoluble in the polyester can be used. As the crosslinked organic polymeric particles, generally, a copolymer of a monovinyl compound (A) having only one aliphatic unsaturated bond in the molecule and a compound (B) having two or more aliphatic unsaturated bonds in the molecule which is used as a crosslinking component can be employed. As examples of the compound (A) in the above copolymer, an aromatic monovinyl compound such as styrene, α-methylstyrene, fluorostyrene, vinyl pyridine or ethylvinylbenzene, a vinyl cyanide compound such as acrylonitrile or methacrylonitrile, an acrylate monomer such as methylacrylate, ethylacrylate, propylacrylate, butylacrylate, octylacrylate, dodecylacrylate, hexadecylacrylate, 2-ethylhexylacrylate, 2-hydroxyethylacrylate, glycidylacrylate or N,N'-dimethylaminoethylacrylate, a methacrylate monomer such as methylmethacrylate, ethylmethacrylate, propylmethacrylate, isopropylmethacrylate, butylmethacrylate, sec-butylmethacrylate, arylmethacrylate such as phenylmethacrylate, benzylmethacrylate, 2-ethylhexylmethacrylate, 2-hydroxyethylmethacrylate, glycidylmethacrylate or N,N'-dimethylaminoethylmethacrylate, a mono- or dicarboxylic acid and an acid anhydride of a dicarboxylic acid such as acrylic acid, methacrylic acid, maleic acid or itaconic acid, or an amide monomer such as acrylic amide or methacrylic amide can be employed. In particular, styrene, ethylvinylbenzene and methylmethacrylate are preferably employed. As examples of the compound (B), a divinylbenzene compound, or a polyfunctional acrylate or methacrylate such as ethylene glycol diacrylate, ethylene glycol dimethacrylate, polyethylene glycol diacrylate, polyethylene glycol dimethacrylate, 1,3-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, trimethylolpropanetriacrylate or trimethylolpropanetrimethacrylate can be employed. Among these compounds (B), particularly divinylbenzene, ethylene glycol dimethacrylate or trimethylolpropanetrimethacrylate is preferably used. With the crosslinked organic polymeric particles according to the present invention, a degree of crosslinkage of the particles relative to the whole of the organic components constituting the particles, which is defined by the following equation (1), is not less than 60%. Degree of crosslinkage = (weight of crosslinkage component in raw material monomer)/(total weight of raw material monomer) × 100 (%) More preferably the degree of crosslinkage is not less than 70%, and further more preferably not less than 75% in order to further stabilize the form of the particles and improve the abrasion resistance at a high running speed. With respect to the crosslinked organic polymeric particles according to the present invention, the strength of the particles when deformed by 10% (hereinafter, referred to as S 10 ) must be in the range 3 to 30 kgf/mm 2 (29.4 to 294 MPa). If the strength S 10 is more than 30 kgf/mm 2 (294 MPa), the particles themselves or fallen particles are likely to scratch a magnetic surface. On the other hand, if the strength S 10 is less than 3 kgf/mm 2 (29.4 MPa), although the abrasion resistance of the film surface at a low running speed is good, the abrasion resistance at a high running speed for a long period of running time decreases. The strength S 10 is desired to be in the range of 4 to 25 kgf/mm 2 (39.2 to 245 MPa) and preferably in the range of 5 to 20 kgf/mm 2 (49 to 196 MPa) in order to particularly improve the abrasion resistance of a formed product. The S 10 of particles is an index representing the hardness of the particles, and can be determined by, for example, measuring the deformation of the particle caused by an external force by a method such as that now described with reference to FIG. 1. In this method, the particles are dispersed on a lower press indenter 1, and one fine particle 3 is fixed between an upper press indenter 2 and the lower press indenter 1. Then, a load is applied at a constantly increasing rate, the deformation of the fine particle and the load are automatically measured, the S 10 is calculated from the load P (kgf = 9.81 N) measured when the particle is deformed ( squashed) by 10% relative to the maximum height before deformation in the direction of the application of the load, using the following equation (2). (This measurement is repeated ten times, and the average value is defined as the S 10 .) S 10 = 2.8 P /π D 2 (kgf/mm 2 or 9.81 MPa) Where, "D" represents particle diameter (mm). This S 10 can be determined on particles present in the polyester film. For example, the S 10 can be measured by dissolving the polyester with o-chlorophenol or an alkali, separating only the particles from the polyester and drying them and measuring S 10 in a manner similar to that described above. Further, since it is difficult to measure the S 10 of a particle having a diameter of less than 0.5 µm, in the present invention, the S 10 of the particle is defined by measuring the S 10 of a particle having a diameter of 1 to 3 µm which has the same composition as that of the particle having a diameter of less than 0.5 µm. In the present invention, the weight average diameter d" of the crosslinked organic polymeric particles is in the range of 0.005 to 5 µm, preferably in the range of 0.01 to 3 µm, more preferably in the range of 0.1 to 2 µm. If the weight average diameter "d" is more than 5 µm, the protrusions formed on the film surface are too high, the particles are liable to fall from the film surface, and the scratch resistance, the abrasion resistance and the dubbing resistance (when the film is used as a base film of a magnetic recording medium) deteriorate. On the other hand, if the weight average diameter "d" is less than 0.005 µm, the height of the protrusions formed on the film surface is too small, the friction of the surface becomes large, and the running ability, the scratch resistance, the running durability and the dubbing resistance deteriorate. As examples of a preferred composition for the crosslinked organic polymeric particles according to the present invention, for example, divinylbenzene polymer, ethylvinylbenzene-divinylbenzene copolymer, styrenedivinylbenzene copolymer, styrene-ethylvinylbenzenedivinylbenzene copolymer, ethylene glycol dimethacrylate polymer, styrene-ethylene glycol dimethacrylate copolymer and methylmethacrylate-divinylbenzene copolymer can be used. Further, the crosslinked organic polymeric particles may be composed of a composition having a three or more component system. The process for producing the crosslinked organic polymeric particles according to the present invention will be explained. For example, there are processes for producing the particles by the following emulsion polymerizations after mixing compounds (A) and (B). (a) soap free polymerization process: i.e., process for polymerizing without an emulsifier or using a very small amount of an emulsifier (b) seed polymerization process for adding polymer particles in a polymerization system prior to emulsion polymerization and thereafter emulsion polymerizing (c) core shell polymerization process for emulsion polymerizing a part of a monomer component and polymerizing the residual monomer in the polymerization system (d) polymerization process by the "ugel stat" disclosed in JP-A-SHO 54-97852 and JP-A-SHO 54-126288 (e) polymerization process without using an expanding agent in the above process (d) In a case where the organic polymeric particles are composed of a silicone resin, a composition in which not less than 80 wt% of the structural units of the particle are preferably trifunctional organopolysiloxane represented by CH 3 SiO 3/2 . In this organopolysiloxane, 80 wt% of the structural units have a three-dimensional bonding structure represented by CH 3 SiO 3/2 , and the degree of polymerization thereof is preferably not less than 100 in order to achieve the advantages according to the present invention more efficiently. Further, in order to give an appropriate specified hardness to the crosslinked organic polymeric particles, a metal element such as, in the long-period type periodic table, an element which belongs to the I group (other than hydrogen), II group, III group (other than boron), IV group (other than carbon and silicon), VIII group, and the sub groups "a" of V, VI and VII groups or silicon may be introduced into the particles in the production of the particles. As such a metal element, for example, an element such as Ca, Mg, Al, Zr, Ti, Fe, Zn, Si, Ge and Sb can be employed. The mole ratio of the element in the particle relative to carbon is in the range of 0.0001 to 1, preferably in the range of 0.001 to 0. 8, and more preferably in the range of 0.01 to 0.6. These elements can be introduced at any stage during the production of the particles. For example, a method for adding a compound containing the above element into the polymerization system of the particles and thereby containing the element in the particles can be used. However, the introduction method is not particularly restricted . Further, even in a case where the particles are formed as composite particles of an organic component and an inorganic component such as the above metal elements and so forth, the degree of crosslinkage of the organic component in the particles is preferred to be not less than 60%. The content of the crosslinked organic polymeric particles is in the range of 0.001 to 20.0% by weight relative to the total weight of the layer containing the particles, preferably in the range of 0.005 to 10.0% by weight, more preferably in the range of 0.01 to 8.0% by weight. As the form of the crosslinked organic polymeric particles in a film, a form represented by a volume shape factor of 0.35 to 0.52 is preferred to ensure a good slipping property. The volume shape factor "f" is represented by the following equation (3). f = V/D 3 Where, V ( µm 3 ) indicates the volume of a particle, and D indicates the maximum diameter (µm) of the particle in a plane of projection. In order to achieve both of a good affinity of the crosslinked organic polymeric particles with a polyester and a good dispersion property of the particles in the polyester, it is preferred that the surfaces of the particles are treated with a compound such as sodium methacrylate or sodium acrylate which has a low reactivity with the polyester or which does not react with polyester. Although the method for the surface treatment is not particularly restricted, a method for firstly producing crosslinked organic polymeric particles as the matrix and thereafter adding a surface treatment agent and adsorbing the agent on the surface or reacting the agent with the surface is preferred from the viewpoint of the thermal resistance of the particles. For example, when using sodium acrylate, styrene-ethylvinylbenzene-butylacrylate-divinylbenzene copolymer particles are produced as the matrix particles, and thereafter, styrene and acrylic acid are added and a part thereof is polymerized, and then, -COONa group originating from Na-methacrylate can be introduced into the surfaces of the particles by adjusting the pH of the system to the alkaline side. It is desirable for the amount of the surface treatment agent to be within the range of 0.01-500 parts by weight, preferably 0.1-300 parts by weight, relative to 100 parts by weight of the matrix particles. With respect to the thermal resistance of the crosslinked organic polymeric particles present in a film in accordance with the present invention, the thermal decomposition temperature measured by a thermobalance for causing 10% loss in weight is not lower than 350 °C, preferably not lower than 360 °C, and particularly preferably not lower than 380°C. As a result, agglomeration of the particles can be efficiently prevented when the polyester composition is molten and formed or when a formed product is recycled. Therefore, the uniformity of the film surface and a good abrasion resistance can be ensured. In a biaxially oriented film according to the present invention, it is preferred that agglomerated particles are contained in the film from the viewpoint of further improvement of the scratch resistance and the dubbing resistance. The primary particle diameter of the agglomerated particles is preferably in the range of 5 to 150nm, more preferably in the range of 10 to 100nm. Although the secondary particle diameter of the agglomerated particles is not particularly restricted, it is preferably in the range of 30 to 800nm, more preferably in the range of 40 to 600nm in order to further improve the scratch resistance and the dubbing resistance. The content of the agglomerated particles is preferably in the range of 0.01 to 3% by weight, more preferably in the range of 0.05 to 2% by weight and particularly preferably in the range of 0.1 to 1% by weight, from the viewpoint of improvement of the scratch resistance and the dubbing resistance. If the content is more than 3% by weight, the dubbing resistance may deteriorate, and if the content is less than 0.01% by weight, the improvement of the scratch resistance is not necessarily to be expected. Although the kind of the agglomerated particles is not particularly restricted, for example, alumina particles having a crystal form of δ-type, -type, η-type and γ-type, and zirconia, agglomerated silica and titanium dioxide particles can be used. Two or more kinds of these particles may be jointly used. Although the biaxially oriented film according to the present invention has main components of the above polymer and the above organic particles, a different kind of polymer may be blended in a range which does not significantly impair the properties of the film, and an organic additive such as oxidation inhibitor, thermal stabilizer, lubricant or ultraviolet absorbent may be added in amounts generally employed. The biaxially oriented film according to the present invention is a film formed by biaxially orientating the above-described composition. A uniaxially oriented film or a non-oriented film is not preferred because a good scratch resistance cannot be obtained. Although the degree of orientation of the biaxially oriented film is not particularly restricted, Young's modulus, which is an index of the molecular orientation of a polymer, is preferably not less than 350 kg/mm 2 in both longitudinal and transverse directions to further improve the scratch resistance. The upper limit of the Young's modulus, which is an index of the molecular orientation of a polymer, is generally about 1500 kg/mm 2 in production of the film. Further, even if the Young's modulus of the film according to the present invention is in the above range, it is preferred that in a part of the film in the thickness direction, for example, in a portion near the surface of the film, the molecular orientation of the polymer is not in a non-oriented or uniaxially oriented condition; that is, it is preferred that the molecular orientation of the polymer throughout the whole extent of its thickness is in a biaxially oriented condition, in order to further improve the scratch resistance and the dubbing resistance. In particular, when the molecular orientation measured by an Abbe refractometer or a refractometer using a laser or determined by total reflection Raman spectroscopic analysis is determined to be biaxially oriented at both the surface and the back surface, further improved scratch resistance and dubbing resistance can be obtained. Furthermore, in the biaxially oriented film according to the present invention, the number of protrusions formed on at least one surface of the film is preferably in the range of 2 x 10 3 to 5 x 10 5 /mm 2 , more preferably in the range of 3 x 10 3 to 4 x 10 5 /mm 2 , especially more preferably in the range of 5 x 10 3 to 3 x 10 5 /mm 2 , from the viewpoint of the scratch resistance and dubbing resistance. Although the composition according to the present invention can be applied to both a single layer film and laminated film having a plurality of layers, a laminated film having at least one film layer with the composition aforementioned is preferred from the viewpoint of the running ability, running durability and abrasion resistance. A "laminated film" means a film having at least two layers in the thickness direction, and such a laminated film may, of course, have 3 or more such layers. Furthermore, in the laminated film, it is preferred that at least one outermost layer is composed of the biaxially oriented film according to the present invention from the viewpoint of the running ability and running durability. A laminated film both surfaces of which are composed of the biaxially oriented film according to the present invention is particularly preferred. As the lamination structure of the laminated film, various formations are available. For example, in the case of a two-layer laminated film, a simple two-layer lamination structure of the layer (layer A) containing organic crosslinked polymeric particles according to the present invention and another layer (layer B), a lamination structure wherein a coating layer (for example, a good adhesive layer) is provided on the layer A, a lamination structure wherein a coating layer (for example, a good adhesive layer) is provided on the layer B or a lamination structure wherein a back coat layer is provided on the layer B can be employed. In the case of a three-layer laminated film, a simple three-layer lamination structure of layer A/layer B/layer A, a lamination structure wherein a coating layer is provided on the surface of one of the layers A or a lamination structure wherein coating layers are provided on the surfaces of both the layers A (on both surfaces of the laminated film) etc. can be employed. In this case, the thickness of the layer A is preferably in the range of 0.1 to 1.5 µm, and the thickness of the coating layer is preferably about 0.1 µm. In the case of a four or more layer laminated film, since basically the number of the layers B (intermediate layer) in the above three-layer laminated film merely increases, the relative positions of the layer A and the coating layer are the same as that of the three-layer laminated film. In such a laminated film, the weight average diameter of the organic particles "d" (nm) and the thickness of a layer containing the organic particles "t" (nm) preferably satisfies the equation: 0.1d ≦ t ≦ 100d. A more preferable relationship between the "d" and the "t" is that represented by the equation: 0.2d ≦ t ≦ 10d. By controlling the relationship between "d" and "t" within such a range, better scratch resistance, running ability, running durability, abrasion resistance and dubbing resistance can be obtained. Furthermore, in the-case where the aforementioned agglomerated particles are added, the organic particles and the agglomerated particles may be present in the same layer or may be present in respective layers different from each other. The following cases (1) and (2) are particularly preferred from the viewpoint of improvement of scratch resistance and dubbing resistance. (1) a case where the organic particles and the agglomerated particles are contained in the same layer of at least one outermost layer of the film, and the thickness of the layer "t" and the particle diameter of the organic particles "d" satisfies 0.2d ≦ t ≦ 10d, preferably 0.5d ≦ t ≦ 5d, more preferably 0.5d ≦ t ≦ 3d (2) a case where the thickness of the layer "t" containing the organic particles and the particle diameter of the organic particles "d" satisfies 0.2d≦ t ≦ 10d, preferably 0.5d≦ t ≦ 5d, more preferably 0.5d≦ t ≦ 3d, and a layer containing the agglomerated particles exists on the outer side of the layer containing the organic particles as an outermost layer, and the thickness of the outermost layer is in the range of 0.005 to 1 µm, preferably in the range of 0.01 to 0.5 µm, more preferably in the range of 0.02 to 0.3 µm Although the polymer of a layer other than the layer containing the above organic particles in the laminated film according to the present invention is not particularly restricted, the polymer is preferably a polyester. Although the polyester is not particularly restricted, a polyester containing at least one of ethylene terephthalate, ethylene α,β-bis(2-chlorophenoxy)ethane-4,4'-dicarboxylate and ethylene 2,6-naphthalate as its main constituent is particularly preferable, because the scratch resistance and the dubbing resistance obtained can be further improved. Among these polyesters, a polyester containing ethylene terephthalate as its main constituent is particularly preferred to further improve the scratch resistance and the dubbing resistance. Particles may be present in this polymer forming a layer other than the layer containing the organic particles in the laminated film. As such particles, calcium carbonate, alumina, silica, titanium and carbon black particles can be used. The intrinsic viscosity of the layer containing the organic particles is preferably not less than 0.75, more preferably not less than 0.8. When the intrinsic viscosity of the layer containing the organic particles is not less than 0.75, even if in a case where FF/REW running is repeatedly carried out, scratches are hardly generated on the surface of the base film of a magnetic tape, and therefore, particularly the running durability can be greatly improved when the FF/REW running speed is increased. Where, in order to control the intrinsic viscosity of the layer containing the organic particles to a value of not less than 0.75, it is preferred that the intrinsic viscosity of the pellets before melting and extrusion is not less than 0.9. In the present invention, although a number of protrusions are formed on the film surface by the organic particles, a ratio Q/P of the number Q of the protrusions having a diameter of not less than 0.7 µm to less than 2.6 µ m to the number P of the protrusions with a diameter of not less than 0.2 µm to less than 0.7 µm is preferably in the range of 1/50 to 1/10,000, more preferably in the range of 1/100 to 1/3,000, and still more preferably in the range of 1/200 to 1/1,000, in order to obtain a better winding property and achieve a much higher yield in slitting the film. As a method for forming such protrusions, a method using at least two kinds of particles having different distributions of particle diameter together is preferred to obtain an excellent running durability. In this case, as long as the crosslinked organic polymeric particles satisfying the aforementioned conditions are used, particles having the same composition can be employed and particles having compositions different from each other can be employed. As to the method, especially the timing, for adding the crosslinked organic polymeric particles to the polyester, a known method, for example, adding the particles to a reaction system for preparing the polyester in the form of a powder or slurry in glycol or kneading the particles into the polyester in a form of a powder or a slurry using a low boiling point solvent can be employed. Among these methods, kneading the particles into a polyester in a form of a slurry of water or organic compound having a boiling point of not higher than 200°C is preferred to obtain a good dispersion condition of the particles. In this case, it is further preferred to use a vent-type forming apparatus for deaeration. In the slurry of crosslinked polymeric particles, an anionic interfacial active agent such as sodium dodecylbenzene sulfonate or sodium lauryl sulfate, a nonionic interfacial active agent such as polyoxyethylenenonylphenylether or polyethylene glycol monostearate, or a protective agent such as polyvinyl pyrrolidone, polyvinyl alcohol or carboxylmethylcellulose is preferably present for improved particle dispersion. The content of the protective agent relative to the crosslinked polymeric particles is preferably in the range of 0.01 to 10% by weight, more preferably in the range of 0.1 to 5% by weight. Further, although the concentration of crosslinked polymeric particles in a slurry with water and/or an organic compound having a boiling point of not higher than 200°C is not particularly restricted, the content of the water and/or the organic compound having a boiling point of not higher than 200 °C relative to the particles is preferably in the range of not less than 2% by weight to not more than 30% by weight, and more preferably in the range of not less than 2% by weight to not more than 20% by weight. Such a condition is preferred because the dispersion property of the particles in the polymer is good and the intrinsic viscosity of the polymer does not decrease. A process for producing such a laminated film as described above will be more specifically explained. First, after polyester pellets have been blended at a predetermined rate and dried, the pellets are supplied to known extruders for melting the pellets and laminating the molten polymers, the polymers are delivered out from a die with a slit in the form of a sheet, and the sheet is cooled and solidified on a casting roll to make a non-stretched film. Namely, the polymers are laminated using two or more extruders and a manifold or a feed block for two or more layers (for example, a feed block having a rectangular laminating portion), a sheet having two or more layers is delivered out from a die, and the sheet is cooled to make a non-stretched film. In this process, it is effective to provide a static mixer and a gear pump in the polymer path. Further, it is effective to control the melting temperature of the extruder for extruding the polymer of the outermost layer to a temperature lower than that for the base layer by 5-10 °C . Next, the non-stretched film is biaxially stretched and biaxially oriented. As the stretching process, a sequential biaxially stretching process or a simultaneous biaxially stretching process can be used. However, a sequential biaxially stretching process for firstly stretching in the longitudinal direction, thereafter stretching in the transverse direction, dividing the longitudinal stretching into three or more stages, and controlling the total longitudinal draw ratio within the range of 3.0 to 6.5 times, is particularly preferred. Although the preferred temperature for the longitudinal stretching varies depending the kind of polyester and therefore cannot be specified, usually it is effective to control the temperature of the first stage in the range of 50 to 130 °C and the temperature of the succeeding stages at a temperature higher than the temperature of the first stage. The stretching speed in the longitudinal direction is preferably in the range of 5000 to 50000 %/min. Generally, a process for using a stenter is employed for the transverse stretching. The draw ratio is preferably in the range of 3.0 to 5.0 times. The stretching speed in the transverse direction is preferably in the range of 1000 to 20000 %/min, and the temperature thereof is preferably in the range of 80 to 160 °C. Next, the stretched film is heat treated. The temperature of the heat treatment is preferably in the range of 170 to 220°C, particularly in the range of 180 to 210 °C, and the time is preferably in the range of 0.2 to 20 seconds. Next, methods for determining the characteristics of a film embodying the present invention and estimating the effects achieved will be explained. (1) Weight average diameter of particles: Photographs of the organic particles in the polymer or the film are taken (size of the photograph: 8 cm x 10 cm, number of the photographs: 30) observing by an electron microscope at a magnification of 20,000 to 50,000, the equivalent sphere diameter of the organic particles is determined, and the weight average diameter (d) is determined using the equivalent sphere diameter. The equivalent sphere diameter is a diameter of a sphere having the same volume as that of the particle. (2) Strength of particle (S 10 ): The deformation is measured using a small compression tester (MCTM-201; produced by Shimadzu Seisakusyo Corporation) by applying a load of 0 to 1 gf (9.81 mN) at a loading speed of 0.0145 gf/s (9.81 mN/s). S 10 is calculated from a load P (kgf = 9.81 N) resulted when the particle is deformed by 10% using the aforementioned equation (2) (this measurement is repeated 10 times and the mean value of the 10 measurements is defined as S 10 ). (3) Volume shape factor of particle: Very thin samples having a thickness of about 0.3 µm are prepared from a biaxially oriented film according to the present invention on the respective cross sections in the longitudinal and transverse directions, using an apparatus for making a very thin film. Then, the respective samples are observed by a transmission type electron microscope and number average diameters of the observed particles in the longitudinal, transverse and thickness directions are determined (the respective diameters are indicated as "a", "b" and "c"). The volume of the particle (V) is defined by the following equation (4) and the maximum diameter of the particle in a plane of projection (D) is defined by the following equation (5). The volume shape factor "f" is calculated from the aforementioned equation (3). V = 4/3π · a · b · c D = max (a, b, c) (4) Content of particles: The film is treated with a solvent which dissolves the resin constituting the film (for example, polyester) but which does not dissolve the particles, and the particles are separated from the resin by centrifugation. The content of the particles is defined as the ratio of the weight of the separated particles to the total weight of the film (% by weight). Alternatively, as needed, the determination may be carried out by utilizing infrared spectrophotometry. (5) Average height, Number and Relative standard deviation of height distribution of protrusions formed on film surface: The height data of the protrusions measured with a two beam and two detector type scanning electron microscope (ESM-3200; produced by Elionics Corporation) and a cross section measuring apparatus (PMS-1; produced by Elionics Corporation) by scanning the surface of the film setting the planar portion of the surface as the base (height 0) is transferred to an image processor (IBAS-2000; produced by Karlzuis Corporation), and an image of the protrusions on the film surface is reconstructed on the display of the image processor. Then, the circle equivalent diameter is determined from the area data of the individual particle obtained by processing the portion of the protrusion in a binary condition in the reconstructed image; this circle equivalent diameter is defined as the average diameter of the particle. Further, the highest value among each height of the protrusion portions processed in a binary condition is defined as the height of the protrusion, and this determination is repeated on the respective protrusions. The determination is repeated 500 times changing measuring portions, the average value of the heights of protrusions measured is defined as the average height of protrusions. Further, the standard deviation of the height distribution is determined from the height data of the respective protrusions. The value obtained by dividing the determined standard deviation by the above average height is defined as the relative standard deviation. The magnification of the scanning electron microscope (SEM) is 1000 to 8000 times. In some cases, the above data obtained by the SEM may be substituted by the data obtained by using a high precision light interference type three dimensional surface analyzer (TOPO-3D produced by WYKO Corporation; objective lens: 40-200 magnifications, effective to use a high level image dissector type camera). (6) Thickness of lamination: In a case where the particles contained in the film at the highest density are organic polymeric particles, the thickness of the laminated layer is determined by measuring the depth profile of the particle density by XPS (X-ray photoelectron spectrum), IR (infrared spectroscopic analysis) or a confocal microscope while etching from the surface. In the surface layer of the film wherein a layer is laminated on one surface of the film, the particle density is low because of the boundary of the surface, and the particle density increases as its distance from the surface increases. In the film wherein a layer is laminated on one surface of the film according to the present invention, the particle density becomes the maximum at a depth [I] and thereafter decreases again. Based on this particle density curve, a depth [II], at which the particle density becomes half of the maximum value, is defined as the thickness of the laminated layer (where, II>I). Further, with respect to other laminated films, the thickness is determined by analyzing in a similar manner from a portion beginning to indicating a particle density. In the case where inorganic particles are present the ratio of the density of the element originating from the particles present at the highest density in the film to the density of the carbon in the polyester (M + /C + ) determined by using secondary ion mass spectrum (SIMS) is defined as the particle density, and the analysis is carried out in the depth (thickness) direction from the surface of polyester A layer. The thickness of the lamination is determined in a manner similar to that described above. Further, the thickness also can be determined by observing the cross section of the film or using a level difference measuring apparatus of a thin film. (7) Parameter of surface roughness Ra, Rt: The parameter of surface roughness is measured using a high-accuracy level difference measuring apparatus for a thin film (ET-10 produced by Kosaka Kenkyusyo Corporation). Ra is the center line average height, and Rt is the height and is represented by the distance between the highest and deepest peaks in the roughness curve. The measuring conditions are as follows, and the mean value of 20 measurements is defined as the parameter of surface roughness. Radius of the tip of probe : 0.5 µm Load of the probe : 5mg Measuring length : 1mm Cut off : 0.08mm An explanation of the respective parameters is given in, for example, "Method for determining and estimating surface roughness" by Jiro Nara (Sogo Gijutsu Center, 1983). Further, the meanings of Ra and Rt are defined in JIS-B-0601 and ISO-468-1982 (Rt is represented as Rmax in the JIS and as Ry in the ISO). (8) Intrinsic viscosity of laminated layer (η : d1/g): The laminated layer is cut off from a non-stretched film melt-extruded from a die, and after a predetermined amount of sample thereof is taken, the intrinsic viscosity is calculated by the following equation (6) from a solution viscosity determined under conditions where the sample is dissolved in orthochlorophenol and at a temperature of 25°C. η SP /C = [η] + K[η] 2 · C where, η SP = (solution viscosity/solvent viscosity) - 1, C is the weight of dissolved polymer per 100ml of solvent (g/100ml, usually 1.2), K is Huggins' constant (0.343), and the solution viscosity and solvent viscosity are measured by using an Ostwald's viscometer. (9) Primary particle diameter and Secondary particle diameter of agglomerated particles: A cross section of a film is observed by using a transmission type electron microscope (TEM) at a magnification of not less than 500,000 times. The thickness of a sample for observation by TEM is about 100nm. The sample is observed and determined at fields of not less than 100 changing the measuring field. The primary particle diameter of agglomerated particles is determined from a minimum unit of particle which cannot be further divided, and the secondary particle diameter of agglomerated particles is determined from an agglomerated unit, as a mean value of diameters of equivalent circles of the observed units, respectively. (10) Young's modulus: Young's modulus is determined at 25°C and 65%RH using a tensile tester, based upon the method defined in JIS-Z-1702. (11) Molecular orientation at film surface: The measurement is carried out using a light source of sodium D ray (wave length: 589nm) and using an Abbe refractometer. Methylene iodide is used as the mount liquid, and the measurement is carried out under conditions of a temperature of 25 °C and a humidity of 65%RH. When the refractive indexes in the longitudinal, transverse and thickness directions are represented by N1, N2 and N3, respectively, the biaxial orientation of the polymer can be represented by the condition that the absolute value of (N1-N2) is not more than 0.07 and N3/ {(N1+N2)/2} is not more than 0.95. The refractive index may be measured by a laser type refractometer. Further, if it is difficult to determine refractive index by the above method, the total reflection laser Raman method can be employed. In the total reflection laser Raman method, the total reflection Raman spectrum is measured by a Ramanor U-1000 Raman system produced by Jobin-Yvon Corporation, for example, in the measurement of polyethylene terephthalate, the fact that the polarimetry ratio of the band intensity ratio of 1615 cm -1 (skeletal vibration of benzene ring) and 1730 cm -1 (stretching vibration of carbonyl group) corresponds to the molecular orientation, can be utilized; the polarimetry ratio may be represented, for example, by the ratio YY/XX, where YY signifies that the polarization direction of the laser is set to Y and Raman ray parallel to direction Y is detected, and XX signifies that the polarization direction of the laser is set to X and Raman ray parallel to direction X is detected. The biaxial orientation of the polymer can be determined by changing the parameter obtained from the Raman method to the refractive indexes in the longitudinal and transverse directions, and calculating the absolute values thereof and the difference therebetween. In such a measurement, the measuring conditions are as follows. 1 ○ Light source: argon ion laser (5,145 Å) 2 ○ Setting of sample: The film surface is pressed onto a total reflection prism, and the incident angle of the laser into the prism (angle relative to the thickness direction of the film) is set to 60 degrees. 3 ○ Detector: PM: RCA31034/Photon Counting System (Hamamatsu C1230) (supply: 1600V) 4 ○ Measuring conditions: Slit : 1000 µm Laser : 100mW Gate time : 1.0sec Scan speed : 12 cm -1 /min Sample interval : 0.2cm -1 Repeat time : 6 (12) Coefficient of dynamic friction at a high running speed (µk): The film is slit to prepare a tape with a width of 1/2 inch. The tape is set in a tape running tester (TBT-300D/H; produced by Yokohama System Kenkyusyo Corporation) and is run under conditions of 25 °C and 65%RH, and the coefficient of the dynamic friction between the tape and a guide pin is determined by the following equation (7). µk = (1/) x log (T 2 /T 1 ) where, T 1 is the entrance side tension and T 2 is the exit side tension, the diameter of the guide pin is 6 mm , the material of the guide pin is SUS27 (surface roughness: 0. 2S), the winding angle is 60 degrees, the running speed is 250 m/min. and T 1 is 90g. In the tables of examples described later, this is indicated merely as "µk" and is not indicated as "coefficient of dynamic friction at a high running speed". In the measurement of a friction coefficient determined at a running speed which is not high, i.e. at a low running speed, measuring conditions are as follows Winding angle: 180 degrees Running speed: 3.3 cm/sec. (13) Abrasion resistance: The tape made by slitting the film at a width of 1/2 inch is brought into contact with a guide roll of stainless steel SUS-304 at a winding angle of 60 degrees, a running speed of 250 m/min., and a tension of 95g over a length of 500m, and the abrasion resistance is assessed by the amount of white powder generating on the surface of the guide roll as follows. Ranks A and B are determined acceptable. Rank A: There is no generation of white powder. Rank B: There is a small amount of white powder. Rank C: There is a fairly large amount of white powder. Rank D: There is a large amount of white powder. (14) Scratch resistance of magnetic surface: A video tape sold on the market is wound onto a pin with a diameter of 7mm under conditions where the magnetic surface is placed into the surface side of the wound tape, a tension of 100g is applied and the longitudinal direction of the tape is directed to the circumferential direction of the pin. Then, a sample film slit at a width of 1/2 inch is wrapped on the wound vide tape at a winding angle of 120 degrees and a tension of 50g, and the sample film is run and turned back ten times by a length of 5cm at a running speed of 200 cm/min. The scratches generated on the magnetic surface in the running of the sample film are observed by a differential interference microscope at a magnification of 50 times. In a case where almost no scratches are generated, the scratch resistance of the magnetic surface is assessed as "good", and in a case where not less than 20 scratches are generated, the scratch resistance of magnetic surface is assessed as "not good". (15) Scratch resistance: The film is slit into a tape with a width of 1/2 inch, and using a tape running tester, the slit sample is run on the guide pin (surface roughness: Ra = 100nm) (running speed: 250m/min, running times: 1 pass, winding angle: 60 degrees, running tension: 90g). After the running, the scratches resulting on the film surface are observed by a microscope. If the number of the scratches having a width of not less than 1 µm per the width of the tape is less than 2, the scratch resistance is assessed as "excellent". If the number of the scratches is not less than 2 and less than 10, the scratch resistance is assessed as "good". If the number of the scratches is not less than 10, the scratch resistance is assessed as "not good". Although an "excellent" rank is desired, films having the "good" rank are practically useful. (16) Dubbing resistance: A magnetic coating solution with the following composition is coated on the film using a gravure roll and the coated magnetic layer is dried and magnetically oriented. After the coated film has been calendered by a small-sized test calendering apparatus (steel roll/nylon roll; 5 stages) at a temperature of 70 °C and a line pressure of 200 kg/cm, the film is cured at a temperature of 70 °C for 48 hours. The film is slit to a tape with a width of 1/2 inch to make a pancake. The tape taken from the pancake is incorporated into a VTR cassette by a length of 250m to make a VTR cassette tape. Composition of magnetic coating solution (all parts are by weight) Co-containing iron oxide: 100 parts Vinyl chloride/vinyl acetate copolymer: 10 parts Polyurethane elastomer : 10 parts Polyisocyanate : 5 parts Lecithin : 1 parts Methylethylketone : 75 parts Methylisobutylketone : 75 parts Toluene : 75 parts Carbon black : 2 parts Lauric acid : 1.5 parts 100% chromatic signal generated by a television testing wave generator is recorded in the above tape using a domestic VTR, and chromatic S/N is determined from the regenerated signal using a color video noise measuring apparatus and the obtained data is referred to as "A". On the other hand, the same signal is recorded on the pancake of a master tape, the recorded signal is dubbed to the same sample tape (non-recorded) as that for the measurement of " A" using a video soft high-speed print system (sprinter) of magnetic field transfer type, and the chromatic S/N of the signal-transferred tape is measured in the same manner as that in the measurement of "A", and the obtained data is referred to as "B". If the reduction of the chromatic S/N in this dubbing (A-B) is less than 3dB, it is asessed as "excellent". If the reduction of the chromatic S/N is in the range of not less than 3dB and less than 5dB, it is assessed as "good", and if the reduction of the chromatic S/N is not less than 5dB, it is assessed as " not good". The rank "excellent" is desirable, but even the rank "good" is sufficient for practical use. (17) Running durability at the time of FF/REW: The video tape prepared in the above item (16) is incorporated into a VTR cassette, and using a domestic video tape recorder, the cassette tape is fast fed (FF) and rewound (REW) repeatedly 100 times. The amount of chipped powder adhering to a pin in the video tape recorder is observed and the running durability is determined by the following criteria. There is no chipped powder adhering. :"excellent" There is a small amount of powder, but there is no problem in practical use as a video tape. :"good" There is a large amount of powder and it is impossible to use it for most applications as a video tape. :"not good" (18) Winding property: The film is wound into a film roll with a width of 1,000 mm and a length of 18,000m (winding speed: 300 m/min), the end surfaces are determined in detail with respect to telescoping (shifting) and longitudinal wrinkles, and the result is assessed as follows. If the amount of shifting at the end surface of the film roll (shifting in the width direction) is less than 0.5 mm and no defect such as longitudinal wrinkles occurs even after the roll is stored for more than 24 hours as it is, it is assessed as "excellent". If the amount of shifting at the end surface of the film roll is less than 0.5 mm and no longitudinal wrinkles occur immediately after winding but weak longitudinal wrinkles are slightly recognized after the roll is stored for more than 24 hours, it is assessed as "good". If the amount of shifting at the end surface of the film roll is not less than 0.5 mm or if longitudinal wrinkles are slightly recognized immediately after winding, it is assessed as "not good". The rank of "excellent" is desired, but even the rank of "good" is sufficient for practical use. EXAMPLES AND COMPARATIVE EXAMPLES Preferred Examples of films embodying the invention will now be described together with Comparative Examples. Example 1 Non-dried polyethylene terephthalate pellets with an intrinsic viscosity of 0.660 and a water content of 0.3 wt% were made molten using a vent-type twin screw extruder. Separately, particles of an ethylvinylbenzenedivinylbenzene copolymer, having a monomer weight ratio of 20/80 and the surface of which had been modified by methacrylic acid at 1 wt% relative to the particles and - COONa had been formed by NaOH, were dispersed, in the presence of an interfacial active agent, as a water slurry with a particle concentration of 20 wt%. Sufficient slurry was added to the polyester to provide a content of particles of 3 wt%. The particles had an average diameter "d" of 0.3 µm, d/Dn (Dn: number average diameter) was 1.40, with maximum values at positions of 0.05 µm and 0.3 µm, the ratio of the number of the particles with a small particle diameter distribution to the number of the particles with a large particle diameter distribution as aforementioned was 1:3, S 10 was 7.5 kgf/mm 2 (73.6 MPa), the volume shape factor was 0.51, and the thermal decomposition temperature was 420°C. The vent pressure was maintained at a vacuum degree of 10 Torr and the resin was melt extruded at a temperature of 280°C to obtain a polyethylene terephthalate containing crosslinked polymeric particles (I). The intrinsic viscosity of the polymer obtained was 0.640. Separately, polyethylene terephthalate (II) with an intrinsic viscosity of 0.650 was prepared by a regular method using dimethyl terephthalate at 100 parts by weight, ethylene glycol at 70 parts by weight, magnesium acetate at 0.06 part by weight as a catalyst for transesterification, antimony trioxide at 0.03 part by weight as a catalyst for polymerization and trimethylphosphate at 0.03 part by weight as a thermal stabilizer. Then, the polyethylene terephthalate composition (I) was laminated on the polyethylene terephthalate (II) by a co-extrusion process at a temperature of 290°C , and the extruded laminated sheet was cooled and solidified on a casting drum using an electrostatic casting method to form a non-stretched laminated film. The non-stretched film was stretched in the longitudinal direction in three stretching stages wherein the first stage was at 123 °C and 1.2 times, the second stage was at 126 °C and 1.45 times and the third stage was at 114°C and 2.3 times. The uniaxially stretched film obtained was stretched in the transverse direction at 111°C and 3.5 times using a stenter, and then the film was heat treated under conditions of a constant length at 200°C for five seconds to make a film having a thickness of 8.3 µm (lamination thickness: 0.3 µm). The content of the crosslinked polymeric particles in the outermost layer of the obtained film was 3.0 wt%, Ra was 0.011, Rt -was 0.270 and the relative standard deviation of the height distribution of the formed protrusions was 0.61, as shown in Table 1. With these characteristics of the film, the µk was 0.28, the abrasion resistance was Rank A, and the scratch resistance of magnetic surface was good. In Table 1, "EVB" represents ethylvinylbenzene and DVB" represents divinylbenzene. Example 2: A polyethylene terephthalate composition containing crosslinked polymeric particles was prepared. This composition was similar to composition (I) in Example 1 but differed in that a polyethylene terephthalate copolymerized with 5-sodium sulfoisophthalic acid component at 0.5 wt% was used instead of the polyethylene terephthalate used in Example 1, and in that the particle slurry was prepared in the presence of polyvinylpyrrolidone (molecular weight: 10,000) at a content of 1 wt% relative to the particles. Then, a laminated film was obtained in a manner similar to that of Example 1. As a result, as shown in Table 1, Ra was 0.011, Rt was 0.212, and the relative standard deviation of height distribution of the formed protrusions was 0.52. As to the film property, µk was 0.30, the abrasion resistance was rank A, and the scratch resistance of the magnetic surface was good. This film was excellent particularly in flatness (Rt/Ra) and had a uniform surface. Example 1 Example 2 Kind of particle EVB/DVB EVB/DVB Composition ratio [Weight ratio] 20/80 20/80 Weight average diameter (µ m) 0.3 0.3 s 10 (kgf/mm 2 or 9,81 MPa) 7.5 7.5 Degree of crosslinkage (%) 80 80 Thermal decomposition temperature (°C) 430 430 Content (wt%) 3.0 3.0 Kind of film laminated film (two layers) laminated film (two layers) Ra (µ m) 0.011 0.011 Rt (µ m) 0.270 0.212 Rt/Ra 24.5 19.3 Relative standard deviation of height distribution of protrusions 0.61 0.52 µk 0.28 0.30 Abrasion resistance A A Scratch resistance of magnetic surface good good Examples 3-7 The lamination structure of the films, and the diameter, the kind and the addition method of the crosslinked polymeric particles were changed as shown in Table 2. In Example 3, the diameter and the content of the particles were changed as compared with Example 1, and the polymer containing the particles was laminated on both surfaces of polyethylene terephthalate (II) to form a laminated film of a three-layer lamination structure. As a result, good film properties could be obtained. In Table 2, ST represents styrene and EDMA represents ethylene glycol dimethacrylate. In Example 4, polyethylene terephthalate (I) containing the crosslinked polymeric particles and polyethylene terephthalate (II) were blended to form a single layer film. As a result, both the abrasion resistance and the scratch resistance of magnetic surface were good. In Example 5, a polyethylene terephthalate containing crosslinked polymeric particles whose weight average diameter was 0.3 µm (polyethylene terephthalate copolymerized with 5-sodium sulfoisophthalic acid component of 0.5 wt% ) and a polyethylene terephthalate containing crosslinked polymeric particles whose weight average diameter was 0.8 µm were blended, and a laminated film of a two layer lamination structure was formed in a manner similar to that in Example 1. As a result, in particular, an excellent running ability (µk) could be obtained. In Example 6, an ethylene glycol slurry of the crosslinked polymeric particles was added after transesterification, and a single layer film was formed in a manner similar to that in Example 4. As a result, both the abrasion resistance and the scratch resistance of the magnetic surface were good. In Example 7, Al was introduced into the skeleton of the molecule of the crosslinked polymeric particles so that the mole ratio of the Al relative to the carbon in the particles was 0.1, the crosslinked polymeric particles were prepared in a manner, and a laminated film of a two layer lamination structure was formed in a manner, similar to that in Example 1. As a result, the height of the protrusions formed was uniform and good film properties could be obtained. Comparative Example 1 A film was formed in a manner similar to that in Example 4 using spherical silicon dioxide particles having a weight average diameter of 0.45 µm. As a result, as shown in Table 3, the affinity was low, a large amount of particles fell out, - the abrasion resistance was rank C and the scratch resistance of magnetic surface was not good. Comparative Example 2 A film was formed in a manner similar to that in Example 4 using crosslinked particles prepared using divinylbenzene sold on the market (divinylbenzene: 55%, ethylvinylbenzene: 40%, ethylbenzene: 5%). The degree of crosslinkage was 55%. As a result, as shown in Table 3, the abrasion resistance deteriorated. Comparative Example 3 A film was formed in a manner similar to that in Example 4 using titanium dioxide particles having a weight average diameter of 0.6 µm. As a result, as shown in Table 3, particularly the abrasion resistance and the scratch resistance of magnetic surface both deteriorated. Comparative Example 1 Comparative Example 2 Comparative Example 3 Kind of particle silicon dioxide EVB/DVB titanium dioxide Composition ratio [Weight ratio] - 40/50 - Weight average diameter (µm) 0.45 0.5 0.6 S 10 (kgf/mm 2 or 9.81 MPa) 20.3 4.0 54.6 Degree of crosslinkage (%) - 55 - Thermal decomposition temperature (°C) - 345 - Content (wt%) 0.5 0.5 0.5 Kind of film single-layer film single-layer film single-layer film Ra (µm) 0.013 0.012 0.013 Rt (µm) 0.321 0.295 0.291 Rt/Ra 24.7 24.6 22.4 Relative standard deviation of height distribution of protrusions 0.70 0.73 0.54 µk 0.27 0.31 0.27 Abrasion resistance C C D Scratch resistance of magnetic surface not good good not good Example 8 -type alumina particles were dispersed in ethylene glycol, and polyethylene terephthalate master pellets were prepared by polymerizing the ethylene glycol slurry with terephthalic acid. A water slurry of divinylbenzene particles whose divinylbenzene composition was 81% and whose weight average diameter was 0.55 µm was directly blended with the polyethylene terephthalate pellets and kneaded therewith using a vent-type twin-screw extruder to prepare polyethylene terephthalate master pellets to be used. Further, polyethylene terephthalate master pellets which did not contain particles were also prepared. These polymers were blended at an appropriate rate (polymer A: no particles, -type alumina particles or divinylbenzene particles, polymer B: no particles), the blended polymers were dried under reduced pressure conditions at 180°C for eight hours (3 Torr), and thereafter, were supplied to extruders (No. 1 and No. 2) and made molten at 290°C and 280°C , respectively. These polymers were filtered at a high filtration degree, and then laminated in a rectangular lamination portion at a lamination structure of three layers (A/B/A). The laminated sheet was cast on a casting drum whose surface temperature was 25°C using an electrostatic casting method, and the sheet was cooled and solidified on the drum to form a non-stretched film. At that time, the ratio of the slit gap of the die to the thickness of the non-stretched film was set to 10. The total thickness of the film and the thickness of the polymer layer A were controlled by adjusting the discharge speeds of the respective extruders. The non-stretched film was stretched in the longitudinal direction at 90 °C and 3.6 times. This stretching was carried out in four stages by utilizing the speed differences between four sets of pairs of rollers. The uniaxially oriented film formed was then stretched in the transverse direction using a stenter at a draw speed of 2,000 %/min. and a draw ratio of 4.2 times and at a temperature of 105°C , and thereafter, the film was heat treated under conditions of a constant length at 200 °C for five seconds to form a biaxially oriented laminated film having a total thickness of 15 µm and a thickness of the laminated layer of 0.6 µm. The particles present and the properties of the obtained film were as shown in Tables 4 and 5, and excellent scratch resistance and dubbing resistance could be obtained. Examples 9 and 10, Comparative Examples 4-6 Changing the kind, particle diameter and 10% deformation strength (S 10 ) of the particles, films were formed in a manner similar to that in Example 8. As shown Tables 4 and 5, the film satisfying the ranges required by the present invention had good scratch resistance and dubbing resistance, but the films outside the present invention could not provide such good scratch resistance and dubbing resistance. Lamination structure Lamination thickness (µm) Scratch resistance Dubbing resistance Example 8 A / B / A excellent excellent 0.6 / 13.8 / 0.6 Example 9 A / B excellent excellent 0.2 / 7.2 Example 10 single layer 14 excellent good Comparative Example 4 single layer 14 not good not good Comparative Example 5 A / B / A not good not good 1 / 14 / 1 Comparative Example 6 A / B not good not good 6 / 5 Example 11 A water slurry of divinylbenzene particles whose divinylbenzene content was 81% and whose weight average diameter was 0.45 µm was directly blended with polyethylene terephthalate pellets and kneaded therewith using a vent-type twin-screw extruder to prepare polyethylene terephthalate master pellets to be used. In addition, other polyethylene terephthalate master pellets which did not contain particles were also prepared. These polymers were blended at an appropriate rate (polymer A: no particles or divinylbenzene particles, polymer B: no particles), the blended polymers were dried under reduced pressure conditions at 180 °C for eight hours (3 Torr), and thereafter, were supplied to extruders (No. 1 and No. 2) and made molten at 290°C and 280°C, respectively. These polymers were filtered at a high filtration degree, and then laminated in a rectangular lamination portion at a lamination structure of three layers (A/B/A). The laminated sheet was cast on a casting drum whose surface temperature was 25°C using an electrostatic casting method, and the sheet was cooled and solidified on the drum to form a non-stretched film. At that time, the ratio of the slit gap of the die to the thickness of the non-stretched film was set to 10. The total thickness of the film and the thickness of the polymer layer A were controlled by adjusting the discharge speeds of the respective extruders. The non-stretched film was stretched in the longitudinal direction at 85 °C and 3.5 times. This stretching was carried out in four stages by utilizing the speed differences between four sets of pairs of rollers. The uniaxially oriented film formed was then stretched in the transverse direction using a stenter at a draw speed of 2,000 %/min. and a draw ratio of 4.0 times and at a temperature of 100°C , and thereafter, the film was heat treated under conditions of a constant length at 200 °C for five seconds to form a biaxially oriented laminated film having a total thickness of 15 µm and a thickness of the laminated layer of 0.5 µm. The particles present and the properties of the obtained film were as shown in Tables 6 and 7, and excellent scratch resistance and dubbing resistance could be obtained. Examples 12-14, Comparative Examples 7-9 Changing the kind, particle diameter and 10% deformation strength (S 10 ) of the particles, films were formed in a manner similar to that in Example 11. As shown Tables 6 and 7, the film satisfying the ranges required by the present invention had good scratch resistance and dubbing resistance, but the films outside the present invention could not provide such good scratch resistance and dubbing resistance. Lamination struclure Lamination thickness (µm) Number of protrusions at surface (number/mm 2 ) Scratch resistance Dubbing resistance Example 11 A / B / A 40000 excellent excellent 0.5 / 14 / 0.5 Example 12 A / B 450000 excellent excellent 0.2 / 7.2 Example 13 single layer 15 15000 good excellent Example 14 single layer 14 20000 good good Comparative Example 7 single layer 14 4500 not good not good Comparative Example 8 A / B / A 1500 not good not good 1 / 14 / 1 Comparative Example 9 A / B 20000 not good not good 0.5 / 8.5 Example 15 Non-dried polyethylene terephthalate pellets with an intrinsic viscosity of 0.66 were made molten using a vent-type twin screw extruder, and ethylvinylbenzene-divinylbenzene copolymer particles dispersed as a water slurry at 20 wt% which had a weight average diameter of 0.3 µm, S 10 of 7.5 kgf/mm 2 and a volume shape factor of 0.51 were added such that the content of the particles was 3 wt% in the polyester. The vent pressure was maintained at a vacuum degree of 10 Torr, the resin was melt extruded at a temperature of 280°C to obtain a polyethylene terephthalate containing crosslinked polymeric particles (intrinsic viscosity: 0.64). The polymerization degree of the polymer was increased by a known solid phase polymerization to prepare master pellets with an intrinsic viscosity of 1.20. This polymer was referred to as "thermoplastic resin A". Separately, polyethylene terephthalate pellets containing the above particles at a content of 0.1 wt% were prepared, and this polymer was referred to as "thermoplastic resin B" (intrinsic viscosity: 0.65). The thermoplastic resin A was supplied to extruder No.1 and the thermoplastic resin B was supplied to extruder No.2, and these polymers were made molten at 280 °C, the polymers were laminated in a feed block, the laminated sheet was cooled and solidified on a casting drum with a surface temperature of 25 °C using an electrostatic casting method to form a non-stretched laminated film having a two-layer lamination structure of A/B. In this lamination, the desired thickness of the layer A was obtained by adjusting the discharge amount of the extruder No. 1. The non-stretched film obtained was stretched in the longitudinal direction in three stretching stages wherein the first stage was at 123 °C and 1.2 times, the second stage was at 126 °C and 1.45 times and the third stage was at 114°C and 2.3 times. The uniaxially stretched film obtained was stretched in the transverse direction at 95 °C and 3.5 times using a stenter, and then the film was heat treated under conditions of a constant length at 200°C for five seconds to make a biaxially oriented laminated film having a total thickness of 9 µm. The particles and the film properties are shown in Tables 8 and 9. The intrinsic viscosity of the layer A was 0.87, and the scratch resistance and FF/REW running durability were excellent and the winding property was good. Example 16 A small amount of particles having the same composition as that of the particles used in Example 15 and having a weight average diameter of 0.8 µm were used together, and a biaxially oriented laminated film was formed in a manner similar to that of Example 15. The particles having a weight average diameter of 0.8 µm were prepared by producing master pellets having a weight average diameter of 0.8 µm separately from the production of the particles used in Example 15 and increasing the intrinsic viscosity thereof to 1.2 by solid phase polymerization. The content of the particles was controlled by blending two kinds of master pellets containing the respective crosslinked polymeric particles and polyethylene terephthalate pellets containing no particle (intrinsic viscosity: 0.85). As a result, the scratch resistance and FF/REW running durability obtained were excellent, and the winding property was also excellent, as shown in Table 9. Examples 17-19 Changing the S 10 and the composition of the crosslinked polymeric particles, biaxially oriented laminated films were formed in a manner similar to that of Example 16 (Examples 17 and 18). In Example 19, the contents of particle 1 and particle 2 and the lamination thickness were changed. In each Example, good film properties could be obtained as shown in Table 9. Example 20 Crosslinked polymeric particles having a weight average diameter of 0.45 µm were used instead of the particles used in Example 15, and a biaxially oriented laminated film having a three-layer lamination structure of A/B/A was formed. In particular, the FF/REW running durability was excellent as shown in Table 9. Comparative Examples 10 and 11 Using crosslinked polymeric particles having changed S 10 and weight average diameter, biaxially oriented laminated films having a two-layer lamination structure of A/B were formed in a manner similar to that of Example 15. However, solid phase polymerization was not carried out on the polymer used for the layer A, and the polymer used therefor was a polymer having an intrinsic viscosity of about 0.6. In these Examples, as shown in Table 9, particularly the FF/REW running durability was not good, and the scratch resistance also was not good. Comparative Example 12 Using spherical silica particles having a weight average diameter of 0.3 µm as shown in Table 8, a biaxially oriented laminated film having a two-layer lamination structure of A/B was formed in a manner similar to that of Example 15. In this Example, as shown in Table 9, particularly the FF/REW running durability was not good because many particles fell out. Property of film Lamination structure Intrinsic viscosity of layer A (dl/g) t/d Q/P Scratch resistance FF/REW Running durability Winding property Example 15 A/B 0.87 0.7 1/8000 excellent excellent good Example 16 A/B 0.84 0.6 1/250 excellent excellent excellent Example 17 A/B 0.79 0.6 1/250 excellent excellent excellent Example 18 A/B 0.82 0.6 1/300 excellent excellent excellent Example 19 A/B 0.84 1.2 1/1500 excellent excellent good Example 20 A/B/A 0.77 1.1 1/80 good excellent good Comparative Example 10 A/B 0.57 0.7 1/8000 not good not good good Comparative Example 11 A/B 0.61 0.7 1/70 not good not good good Comparative Example 12 A/B 0.78 0.7 1/350 good not good excellent Example 21 Changing the thermal decomposition temperature of the crosslinked polymeric particles as compared with that in Example 15, a biaxially oriented laminated film having a two-layer lamination structure of A/B and having a total thickness of 9 µm was formed in a manner similar to that of Example 15, as shown in Tables 10 and 11. In this Example, the coefficient of dynamic friction at a high running speed was low, and the FF/REW running durability was excellent. Example 22 Changing the thermal decomposition temperature of the crosslinked polymeric particles as compared with that in Example 16, a biaxially oriented laminated film having a two-layer lamination structure of A/B was formed in a manner similar to that of Example 21, as shown in Tables 10 and 11. In this Example, the coefficient of dynamic friction at a high running speed was low, the FF/REW running durability was excellent, and further the winding property was excellent. Examples 23-25 Changing the S 10 , the degree of crosslinkage, the composition, the ratio of lamination thickness to particle diameter (t/d) and the thermal decomposition temperature of the crosslinked polymeric particles, biaxially oriented laminated films having a two-layer lamination structure of A/B were formed in a manner similar to that of Example 21, as shown in Tables 10 and 11. In each Example, good film properties could be obtained. Example 26 Crosslinked polymeric particles having a weight average diameter of 0.45 µm were used instead of the particles used in Example 21, and a biaxially oriented laminated film having a three-layer lamination structure of A/B/A was formed in a manner similar to that of Example 21. In particular, the FF/REW running durability was excellent as shown in Table 11. Comparative Examples 13-15 Using crosslinked polymeric particles having the same composition as that of the particles used in Example 21 but having S 10 of 2.5 kgf/mm 2 (245 MPa) and a degree of crosslinkage of 55% as shown in Table 10, biaxially oriented laminated films having a two-layer lamination structure of A/B were formed in a manner similar to that of Example 21. In these Examples, as shown in Table 11, the coefficient of dynamic friction at a high running speed was high, and the FF/REW running durability was not good. In Example 15, particularly the winding property was not good. Comparative Example 16 Using spherical silica particles having a weight average diameter of 0.3 µm as shown in Table 10, a biaxially oriented laminated film having a two-layer lamination structure of A/B was formed in a manner similar to that of Example 21. In this Example, as shown in Table 11, particularly the FF/REW running durability was not good because many particles fell out. Property of film Lamination structure t/d Q/P Coefficient of dynamic friction at high running speed FF/REW Running durability Winding property Example 21 A/B 0.7 1/8000 0.12 excellent good Example 22 A/B 0.6 1/250 0.14 excellent excellent Example 23 A/B 0.6 1/450 0.10 excellent excellent Example 24 A/B 0.9 1/300 0.14 excellent excellent Example 25 A/B 1.2 1/1500 0.17 excellent good Example 26 A/B/A 1.1 1/80 0.14 excellent good Comparative Example 13 A/B 0.7 1/8000 0.29 not good good Comparative Example 14 A/B 0.7 1/70 0.26 not good good Comparative Example 15 A/B 0.7 1/12000 0.30 not good not good Comparative Example 16 A/B 0.6 1/350 0.17 not good excellent

Claims: A biaxially oriented film containing organic particles, which organic particles (a) are crosslinked polymer particles having a degree of crosslinking not less than 60%; (b) have a strength when deformed by 10% (S 10 ) which is in the range of 29 to 294 MPa (3 to 30 kgf/mm 2 ); (c) have a thermal decomposition temperature, for causing 10% loss in weight, not lower than 350°C; (d) have a weight average diameter in the range of 0.005 to 5µm; and (e) are present in a content of 0.001 to 20% by weight, based on the total weight of the film; and which biaxially oriented film is other than a film of Comparative Example 4 of EP-A-0546184. A biaxially oriented film having a Young's Modulus in at least one direction of the film of not less than 350 kgf/mm 2 (3435 MPa) and containing organic particles, which organic particles (a) are crosslinked polymer particles having a degree of crosslinking not less than 60%; (b) have a strength when deformed by 10% (S 10 ) which is in the range of 29 to 294 MPa (3 to 30 kgf/mm 2 ); (c) have a thermal decomposition temperature, for causing 10% loss in weight, not lower than 350°C; (d) have a weight average diameter in the range of 0.005 to 5µm; and (e) are present in a content of 0.001 to 20% by weight, based on the total weight of the film. A biaxially oriented film according to claim 1 or claim 2, wherein the crosslinked organic particles are crosslinked divinylbenzene particles. A biaxially oriented film according to any preceding claim, which contains particles other than the said organic particles, which other particles are agglomerated particles each having a primary particle diameter of 5 to 150nm. A biaxially oriented film according to claim 4, wherein the agglomerated particles are selected from alumina, zirconia, silica and titania particles. A biaxially oriented film according to claim 5, wherein the agglomerated particles are alumina particles selected from δ-type, -type, η-type and γ-type alumina particles. A laminated film having at least one layer of a biaxially orientated film containing organic particles, which organic particles (a) are crosslinked polymer particles having a degree of crosslinking not less than 60%; (b) have a strength when deformed by 10% (S 10 ) which is in the range of 3 to 30 kgf/mm 2 ; (c) have a thermal decomposition temperature, for causing 10% loss in weight, not lower than 350°C; (d) have a weight average diameter in the range of 0.005 to 5µm; (e) are present in a content of 0.001 to 20% by weight of the total weight of the layer; and which biaxially oriented film is other than a film of Comparative Example 4 of EP-A-0546184. A laminated film having at least one layer of biaxially oriented film, which film has a Young's Modulus in at least one direction of the film of not less than 350 kgf/mm 2 (3435 MPa) and containing organic particles , which organic particles (a) are crosslinked polymer particles having a degree of crosslinking not less than 60%; (b) have a strength when deformed by 10% (S 10 ) which is in the range of 3 to 30 kgf/mm 2 ; (c) have a thermal decomposition temperature, for causing 10% loss in weight, not lower than 350°C; (d) have a weight average diameter in the range of 0.005 to 5µm; (e) are present in a content of 0.001 to 20% by weight of the total weight of the layer. A laminated film according to claim 7 or claim 8, wherein the laminated film is a two-layer laminated film and at least one layer of the two-layer laminated film comprises the said biaxially oriented film. A laminated film according to claim 7 or claim 8, wherein the laminated film is a three or more layer laminated film and at least one outermost layer of the laminated film comprises the said biaxially oriented film. A laminated film according to any one of claims 7 to 10, wherein the weight average diameter of the said organic particles "d" (nm) and the thickness of a layer containing the said organic particles "t" (nm) satisfies the equation: 0.1d ≤ t ≤ 100d. A laminated film according to claim 11, wherein the weight average diameter of said organic particles "d" (nm) and the thickness of a layer containing the said organic particles "t" (nm) satisfies the equation: 0.2d ≤ t ≤ 10d. A laminated film according to any one of claims 7 to 12, wherein the said crosslinked organic particles are crosslinked divinylbenzene particles. A laminated film according to any one of claims 7 to 13, wherein the laminated film contains particles other than the said organic particles, which other particles are agglomerated particles each having a primary particle diameter of 5 to 150nm. A laminated film according to claim 14, wherein the agglomerated particles are selected from alumina, zirconia, silica and titania particles. A laminated film according to claim 15, wherein the agglomerated particles are alumina particles selected from δ-type, -type, η-type and γ-type alumina particles. A laminated film according to any one of claims 14 to 16, wherein the organic particles and the agglomerated particles are present at least in the same outermost layer. A laminated film according to any one of claim 14 to 16, wherein a layer containing the agglomerated particles is an outermost layer laminated on a layer containing the organic particles.

Inventors: ABE KOICHI, KIMURA MASAHIRO, MASATOSHI AOYAMA, MINAMIZAWA HIDEHITO, NAKAMORI YUKARI, OKAMOTO KATSUYA, OKAZAKI IWAO, SUZUKI MASARU, TANAKA HIROYUKI, ABE, KOICHI, KIMURA, MASAHIRO, MASATOSHI, AOYAMA, MINAMIZAWA, HIDEHITO, NAKAMORI, YUKARI, OKAMOTO, KATSUYA, OKAZAKI, IWAO, SUZUKI, MASARU, TANAKA, HIROYUKI, OKAZAKI, IWAO, LIONSMANSION JYURAKUNIJYO 504, 857
Applicants: TORAY INDUSTRIES, TORAY INDUSTRIES, INC.
Application year: 1993
Main classification: C08J5
IPC codes: C08J5, B32B27, G11B5