DYE DIFFUSION THERMAL TRANSFER PRINTING

Abstract: A thermal transfer sheet comprising a substrate having a coating comprising a dye of formula (1), wherein: A is the residue of a diazotisable aromatic or heterocyclic amine; R<1> is an optionally substituted branched chain alkyl group; R<2> is an optionally substituted straight or branched chain alkyl group; and Ring B is unsubstituted or may be substituted from 1 to 4 substituent groups, except for 4-(6-thiocyanatobenzothiazol-2-ylazo)-3-methyl-N-ethyl-N-secbutylaniline, 3-(2-[4-N-secbutyl-N-ethylamino)-2-methylphenylazo]-4-chlorothiazol-5-yl)-2-cyanoacrylic acid ethyl ester, 3-(2-[4-(N-secbutyl-N-n-butylamino)-2-methylphenylazo]-4-chlorothiazol-5-yl)-2-cyanoacrylic acid ethyl ester, 3-(2-[4-(N-isopropyl-N-methylamino) phenylazo]-4-chloro-3-cyanothien-5-yl)-2-cyanoacrylic acid n-butyl ester, 4-(3-[2-methoxyethyl]-4-cyanoisothiazol-5-ylazo)-3-acetylamino-N-secbutyl-N-n-butyl aniline, 4-(3-methyl-4-cyanoisothiazol-5-ylazo)-3-acetylamino-N-sechexyl-N-ethylaniline, 4-(3-sechexyl-4-cyanoisothiazol-5-ylazo)-3-acetylamino-N-sechexyl-N-n-propylaniline, 4-(3-methyl-4-cyanoisothiazol-5-ylazo)-N-isopropyl-N-methylaniline, 4-(4,5-dicyano-1-cyanomethylimidazol-2-ylazo)-N,N-diisopropylaniline, 4-(5-nitrothiazol-2-ylazo)-3-acetylamino-6-methoxy-N-isopropyl-N-ethylaniline and 4-(3-ethylthio-1,2,4-thiadiazol-5-ylazo)-3-methyl-N,N-diisopropylaniline. The thermal transfer sheet is used in dye diffusion thermal transfer printing.

Description: DYE DIFFUSION THERMAL TRANSFER PRINTING Introduction This specification describes an invention relating to dye diffusion thermal transfer printing (DDTTP or D2T2 printing, D2T2 is a trade mark of Imperial Chemical Industries PLC), especially to a transfer sheet carrying a dye a dye mixture which has an improved print stability particularly with respect to light fastness and to a transfer printing process in which the dye or the dye mixture is transferred from the transfer sheet to a receiver sheet by the application of heat, and to certain novel dyes. It is known to print woven or knitted textile material by a thermal transfer printing (TTP) process. In such a process a sublimable dye is applied t paper substrate (usually as an ink also containing a resinous or polymeric binde to bind the dye to the substrate until it is required for printing) in the form of a pattern, to produce a transfer sheet comprising a paper substrate printed with a pattern which it is desired to transfer to the textile. Substantially all the dye is then transferred from the transfer sheet to the textile material, to form an identical pattern on the textile material, by placing the patterned side of the transfer sheet in contact with the textile material and heating the sandwich, und light pressure from a heated plate, to a temperature from 180-220°C for a perio of 30-120 seconds. As the surface of the textile substrate is fibrous and uneven it will not be in contact with the printed pattern on the transfer sheet over the whole o the pattern area. It is therefore necessary for the dye to be sublimable and vaporise during passage from the transfer sheet to the textile substrate in order dye to be transferred from the transfer sheet to the textile substrate over the whole of the pattern area. As heat is applied evenly over the whole area of the sandwich ove sufficiently long period for equilibrium to be established, conditions are substantially isothermal, the process is non-selective and the dye penetrates deep into the fibres of the textile material. In DDTTP, a transfer sheet is formed by applying a heat- transferable dye (usually in the form of a solution or dispersion in a liquid also containing a polymeric or resinous binder to bind the dye to the substrate) to a thin (usually < 20 micron) substrate having a smooth plain surface in the form o continuous even film over the entire printing area of the transfer sheet. Dye is then selectively transferred from the transfer sheet by placing it in contact with material having a smooth surface with an affinity for the dye, hereinafter called the receiver sheet, and selectively heating discrete areas of the reverse side of t transfer sheet for periods from about 1 to 20 milliseconds (msec) and temperatures up to 300°C, in accordance with a pattern information signal, whereby dye from the selectively heated regions of the transfer sheet diffuses fr the transfer sheet to the receiver sheet and forms a pattern thereon in accordan with the pattern in which heat is applied to the transfer sheet. The shape of the pattern is determined by the number and location of the discrete areas which ar subjected to heating and the depth of shade in any discrete area is determined b the period of time for which it is heated and the temperature reached. Heating is generally, though not necessarily, effected by a line of heating elements, over which the receiver and transfer sheets are passed togethe Each element is approximately square in overall shape, although the element m optionally be split down the centre, and may be resistively heated by an electric current passed through it from adjacent circuitry. Each element normally corresponds to an element of image information and can be separately heated t 300°C to 400°C, in less than 20 msec and preferably less than 10 msec, usually b an electric pulse in response to a pattern information signal. During the heating period the temperature of an element will rise to about 300-400°C over about 5- 8 msec. With increase in temperature and time more dye will diffuse from the transfer sheet to the receiver sheet and thus the amount of dye transferred onto, and the depth of shade at, any discrete area on the receiver sheet will depend o the period for which an element is heated while it is in contact with the reverse side of the transfer sheet. As heat is applied through individually energised elements for very short periods of time the process is selective in terms of location and quantity of dye transferred and the transferred dye remains close to the surface of the receiver sheet. As an alternative heating may be effected using a light source in a light-induced thermal transfer (LITT or L2T2 printing, L2T2 is a trade mark of Imperial Chemical Industries PLC) printer where the light source can be focuse in response to an electronic pattern information signal, on each area of the transfer sheet to be heated. The heat for effecting transfer of the dye from the transfer sheet is generated in the dyesheet which has an absorber for the induci light. The absorber is selected according to the light source used and converts t light to thermal energy, at a point at which the light is incident, sufficient to transfer the dye at that point to the corresponding position on the receiver sheet The inducing light usually has a narrow waveband and may be in the visible, inf red or ultra violet regions although infra- red emitting lasers are particularly suitable. It is clear that there are significant distinctions between TTP onto synthetic textile materials and DDTTP onto smooth polymeric surfaces and thus dyes which are suitable for the former process are not necessarily suitable for th latter. In DDTTP it is important that the surfaces of the transfer sheet a receiver sheet are even so that good contact can be achieved between the printe surface of the transfer sheet and the receiving surface of the receiver sheet over the entire printing area because it is believed that the dye is transferred substantially by diffusion in the molten state in condensed phases. Thus, any defect or speck of dust which prevents good contact over any part of the printing area will inhibit transfer and lead to an unprinted portion on the receiver sheet the area where good contact is prevented, which can be considerably larger than the area of the speck or defect. The surfaces of the substrate of the transfer an receiver sheets are usually a smooth polymeric film, especially of a polyester, which has some affinity for the dye. Important criteria in the selection of a dye for DDTTP are its thermal properties, fastness properties, such as light fastness, and facility for transfer by diffusion into the substrate in the DDTTP process. For suitable performance the dye or dye mixture should transfer evenly and rapidly, in proportion to the heat applied to the transfer sheet so that the amount transferr to the receiver sheet is proportional to the heat applied. After transfer the dye should preferably not migrate or crystallise and should have excellent fastness to light, heat, rubbing, especially rubbing with a oily or greasy object, e.g. a human finger, such as would be encountered in normal handling of of the printed receiv sheet. As the dye should be sufficiently mobile to migrate from the transfer she to the receiver sheet at the temperatures employed, 100-400°C, in the short time scale, generally <20 msec, it is preferably free from ionic and/or water- solubilising groups, and is thus not readily soluble in aqueous or water-miscible media, such as water and ethanol. Many potentially suitable dyes are also not readily soluble in the solvents which are commonly used in, and thus acceptable to, the printing industry; for example, alcohols such as i-propanol, ketones such a methyl ethyl ketone (MEK), methyl i-butyl ketone (MIBK) and cyclohexanone, ethers such as tetrahydrofuran and aromatic hydrocarbons such as toluene. The dye can be applied as a dispersion in a suitable medium or as a solution in a suitable solvent to the substrate from a solution. In order to achieve the potenti for a high optical density (OD) on the receiver sheet it is desirable that the dye should be readily soluble or readily dispersable in the ink medium. It is also important that a dye which has been applied to a transfer sheet from a solution should be resistant to crystallisation so that it remains as an amorphous layer on the transfer sheet for a considerable time. Crystallisation not only produces defects which prevent good contact between the transfer receiver sheet but gives rise to uneven prints. The following combination of properties is highly desirable for a dy which is to be used in DDTTP: - Ideal spectral characteristics (narrow absorption curve) Correct thermochemical properties (high thermal stability and efficient transferability with heat). High optical densities on printing. Good solubility in solvents acceptable to printing industry: this is desirable to produce solution coated dyesheets alternatively good dispersibility in acceptable media is desirable to produce dispersion coated dyesheets. Stable dyesheets (resistant to dye migration or crystallisation). Stable printed images on the receiver sheet (resistant to heat, migration, crystallisation, grease, rubbing and light). DDTTP is used for printing images on suitable substrates. The achievement of good light fastness in DDTTP is extremely difficult because of the unfavourable environment of the dye, close to the surfac of the polyester receiver sheet. Many known dyes for polyester fibre have high light fastness ( > 6 on the International Scale of 1-8) on polyester fibre when applied by TTP because dye penetration into the fibres is good, but the same dy exhibit very poor light fastness on a polyester receiver sheet when applied by DDTTP because of poor penetration into the substrate. It is known to improve the light fastness of dyes for use in conventional dyeing techniques by introducin electron-withdrawing groups into the dye molecule but this is generally accompanied by an undesirable hyposchromic shift. The present invention overcomes this problem by providing a convenient means of improving light fastness of dyes in DDTTP without the disadvantage of substantially changing th absorption maximum of the dye. According to the present invention there is provided a thermal transfer sheet comprising a substrate having a coating comprising a dye of Formula (1): Formu l a ) wherein: A is the residue of a diazotisable aromatic or heterocyclic amine; R 1 is an optionally substituted branched chain alkyl group; R 2 is an optionally substituted straight or branched chain alkyl group; and Ring B is unsubstituted or may be substituted from 1 to 4 substituent groups, except for 4-(6-thiocyanatobenzothiazol-2-ylazo)-3-tnethyl-N-ethyl-N-sec butylaniline, 3-(2-[4-N-secbutyl-N-ethylamino)-2-rnethylphenylazo]-4- chlorothiaz 5-yl)-2-cyanoacrylic acid ethyl ester, 3-(2-[4-(N-secbutyl-N-n-butylamino)-2- methylphenylazo]-4-chlorothiazol-5-yl)-2-cyanoacrylic acid ethyl ester, 3-(2-[4-(N- isopropyl-N-methylamino) phenylazo]-4-chloro- 3-cyanothien-5-yl)-2-cyanoacrylic acid n-butyl ester, 4-(3-[2-methoxyethyl]-4-cyanoisothiazol-5-ylazo)-3-acetylamino N-secbutyl-N-n-butyl aniline, 4-(3-methyl-4-cyanoisothiazol-5-ylazo)-3-acetylamin N-sechexyl-N-ethylaniline, 4-(3-sechexyl-4-cyanoisothiazol-5-ylazo)-3-acetylamino- N-sechexyl-N-n-propylaniline, 4-(3-methyl-4-cyanoisothiazol-5-ylazo)-N-isopropyl- N-methylaniline, 4-(4,5-dicyano- l-cyanomethylimidazol-2-ylazo)-N,N- diisopropylaniline, 4-(5-nitrothiazol-2-ylazo)-3-acetylamino-6-methoxy-N-isopropyl N-ethylaniline and 4-(3-ethylthio-l,2,4,-thiadiazol-5-ylazo)-3-methyl-N,N- diisopropylaniline. A is preferably selected from phenyl, naphthyl, thiazolyl, isothiazol benzothiazolyl, benzoisothiazolyl, pyrazolyl, thiadiazolyl, imidazolyl, thienyl, pyrid and pyridoisothiazolyl each of which may be optionally substituted. Where A is phenyl it is preferably of the Formula (2): Formu l a C 2 ~ ι wherein: R 3 is -H, optionally substituted alkyl, optionally substituted alkoxy, -NO,, -CN, -CF 3 , -SCN, halogen, alkoxyalkyl, -COalkyl, -OCOalkyl, -COOalkyl, -SO 2 NH 2 , -S0 2 F, -SO 2 Cl, -CONH 2 , -COF, -COC1, -S0 2 alkyl, -CONH(alkyl), -CON(alkyl) 2 , -S0 2 N(alkyl) 2 , -Salkyl, -Sphenyl; and n is an integer from 1 to 5. Where A is naphthyl it is preferably a naphth-1-yl of the Formula (3): Formu l a ( 3} wherein: R 3 is as hereinbefore defined; and n is an integer from 1 to 4. Where A is thiazolyl it is preferably a thiazol-2-yl of the Formula (4): Formu l a (4) wherein: R 4 is -H or optionally substituted alkyl, optionally substituted alkoxy, optionally substituted aryl, halogen or -Saikyl; and R 5 is -H, optionally substituted alkyl, alkenyl, -CN, -N0 2 , -S0 2 alkyl, -COOalkyl, halogen or -CHO. Where A is isothiazolyl it is preferably an isothiazol-5-yl of the Formula (5): ormu l a ' -0 wherein: R° is -H, optionally substituted alkyl, optionally substituted aryl, -S0 2 alkyl, -Saikyl, -Saryl or halogen; and R 7 is -H, -CN, -N0 2 , -SCN or -COOalkyl. Where A is benzothiazolyl it is preferably a benzothiazol-2-yl of t Formula (6): Formu l a C 53 wherein: R 8 is -H, -SCN, -N0 2 , -CN, halogen, optionally substituted alkyl, optionally substituted alkoxy, -COOalkyl, -OCOalkyl or -SO 2 alkyl; and n 2 is from 1 to 4. Where A is benzoisothiazolyl it is preferably a benzoisothiazol-3-yl of the Formula (7): Formu l a ( 7] wherein: R 8 is as hereinbefore defined; and n" is from 1 to 4. Where A is pyrazolyl it is preferably a pyτazol-5-yl of the Formula (8): Formu l a f 8 j wherein: each R^ is independently as hereinbefore defined; and R is -H, optionally substituted alkyl or optionally substituted aryl. Where A is thiadiazolyl it is preferably a 1,2,4-thiadiazol- 5-yl of Formula (9): Formu l a C 91 wherein: R 10 is -Saikyl, -Saryl, -SO : alkyl or halogen or is a l,3,4-thiadiazol-5-yl o Formula (10): Formu l a ~ ' 0~) wherein: R 10 is as hereinbefore defined. Where A is imidazolyl it is preferably an imidazol-2-yl of the Formula (11): Formu l a ( 11) w erein: R 11 is -CN, -CHO, -CH=C(CN) 2 or -CH = C(CN)(COOaIkyl); R 12 is -CN or -Cl; and R 13 is -H or optionally substituted alkyl. Where A is thienyl it is preferably a thien-2-yl of the Formula (12) Formu i a f 121 wherein: R 14 is -NO 2 , -CN, alkylcarbonylamino or alkoxy carbonyl; R 15 is -H, halogen, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted aryl or -Saikyl; and R 16 is -H, optionally substituted alkyl, -CN, -N0 2 , -SO 2 alkyl, -COOalkyl, halogen, -CH = C(CN) 2 or -CH=C(CN)(COOalkyl). Where A is pyridyl it is preferably a pyrid-2-yl, pyrid-3-yl or pyrid-4 yl of the Formula (13): Formu l a 3D wherein: R 3 is as hereinbefore defined; and TT is from 1 to 4. Where A is pyridoisothiazolyl it is preferably a pyridoisothiazol-3-yl of the Formula (14): wherein: R 17 is -CN or -NO : ; and R 18 is optionally substituted alkyl. Where any one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 8 , R 9 , R 13 , R 15 , R 16 or R is optionally substituted alkyl, optionally substituted alkoxy or optionally substituted aryl the optional substituents are preferably selected from -CN, -SCN -N0 2 , halogen, especially -F, -Cl and -Br, -SC M -alkyl, -Sphenyl, C M -alkoxy, -COOC M -alkyl. Where any one of R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 13 , R 14 , R 15 , R 16 or R 18 is or contains alkyl or alkoxy groups it is preferably C^-alkyl, more preferably C -alkyl or preferably C^-alkoxy, more preferably C M -alkoxy groups respectively. The halogen group represented by R 3 , R 4 , R 5 , R 6 , R 8 , R 10 or R 16 is preferably -F, -Cl or -Br. Especially preferred groups represented by R 3 are selected from -NO,, -CN, -COOC -alkyl and C -alkyl. In phenyl groups of Formula (2) n is preferably from 1 to 3, more preferably 1 to 2. When the phenyl group of Formula (2) carries 3 substituents these are preferably in the 2-, 4- and 6-positions, when the phenyl group of Formula (3) carries 1 or 2 substituents these are preferably in the 2- or 4- or in both the 2- and 4-positions, more preferably in the 4-position with respect to the -N = N- linkage. The optionally substituted aryl group represented by R 4 , R 6 , R 9 or R 15 is preferably phenyl or substituted phenyl. R 4 is preferably -H, optionally substituted C M -alkyl, optionally substituted C M -alkoxy, optionally substituted phenyl, -F, -Cl, -Br or -SC w -alkyl, more preferably -H, C M -alkyl, C w -alkoxy, phenyl or -SC alkyl and especially -H, -CH 3 or C,H 5 . R 5 is preferably -H, optionally substituted C M -alkyl, -CN, -NO 2 , -S0 2 C M -alkyl, -COOC -alkyl, -Cl, -F, -Br or -CHO, C^-alkenyl, more preferabl -H, C -alkyl, cyano-C M -alkyl, -CN, -N0 2 , -CHO, C 2 . 3 -alkenyl and especially -NO -CN, -CHO, vinyl or -CH 2 CN. R° is preferably -H, optionally substituted C M -alkyl, optionally substituted phenyl, -SO 2 C M -alkyl, -SC -alkyl, -Sphenyl, -Cl, -F or -Br. more preferably C M -alkyl, phenyl or -S0 2 C M -alkyl, and especially -CH 3 , -S0 2 CH 3 . R 7 is preferably -CN, -NO 2 , -SCN or -COOC -alkyl, more preferably -CN or -NO,. In benzothiazolyl groups of Formula (6) n 2 is preferably 1 or 2 and is more preferably 1 and the substituent represented by R 8 is preferably in the 6- position. R 8 is preferably -H, -SCN, -NO,, -Cl, -F, -Br, optionally substituted C -alkyl, optionally substituted C M -alkoxy, -COOC M -alkyl, -OCOC -alkyl or -SO 2 C w -alkyl, more preferably -H, -SCN, -NO,, C M -alkyl, C M -alkoxy or -SO 2 C w alkyl and especially -SCN or -SO,CH 3 . In benzoisothiazolyl groups of Formula (7) n 3 is preferably 1 or 2 and is more preferably 1. R 9 is preferably -H, optionally substituted C M -alkyl or optionally substituted phenyl, more preferably cyano-C M -alkyl and, especially cyanomethyl. R 10 is preferably -SC M -alkyl, -Sphenyl or -S0 2 C M -alkyl, more preferably -SC M -alkyl and -SO z C M -alkyl and especially -SCH 3 or -SC 2 H . R 11 is preferably -CN, -CHO, -CH = C(CN) 2 or -CH=C(CN)COOC -alkyl and more preferably -CN. R 12 is preferably -CN. R 13 is preferably cyano-C -alkyl, especially cyanomethyl. R 14 is preferably -NO 2 , -CN, C -alkylcarbonylamino or C M - alkoxycarbonyl more preferably -NO 2 , -CN, ethoxycarbonyl or methylaminocarbonyl. R 15 is preferably -H, halogen, optionally substituted C -alkyl, optionally substituted C M -alkoxy, optionally substituted phenyl -SC M -alkyl, more preferably C w -alkoxy, -Cl, -Br, phenyl, -SC M -alkyl and especially -H, -Cl or methyl. R 16 is preferably -H, C M -alkyl, -CN, -N0 2 , -SO,C^-alkyl, -COOC M -alkyl, -Cl, -F, -Br, -CH = C(CN) 2 or -CH = C(CN)(COOC M -alkyl) and more preferably -NO,, -CN, -CH = C(CN), or -CH = C(CN)(COOC M -alkyl). In pyridyl groups of Formula (13) n 4 is preferably from 1 to 3, mor preferably 1 or 2 and especially 1. R 18 is preferably optionally substituted C M -alkyl and more preferably C M -alkyl and especially methyl or ethyl. A is preferably phenyl, naphth-1-yl, thiazol-2-yl, isothiazol-5-yl, benzothiazol-2-yl, benzoisothiazol-3-yl, pyrazol-5-yl, l,2,4-thiadiazol-5-yl, 1,3,4- thiadiazol-5-yl, imidazol-2-yl, thien-2-yl, pyrid-2-yl, pyrid-3-yl, pyrid-4-yl or pyridoisothiazol-3-yl, more preferably phenyl, thiazol-2-yl, isothiazol-5-yl, 1,3,4- thiadiazol-5-yl or thien-2-yl, especially phenyl substituted by from 1 to 3 groups selected from -NO,, -CN, -Br and -CH 3 , thiazol-2-yl substituted by 1 or 2 groups selected from -Cl or -CHO, isothiazol-5-yl substituted by 1 or 2 groups selected from -CN and -CH 3 , l,3,4-thiadiazol-5-yl substituted by ethylthio or thien-2-yl substituted by from 1 to 3 groups selected from -CN, -CH 3 and -CO- j H^ The branched chain alkyl group represented by R 1 is preferably an optionally substituted C^^-alkyl group, more preferably an optionally substituted C^-alkyl group such as -CH(CH 3 ) 2 , -CH 2 CH(CH 3 ) 2 , -CH O^ H -CH(CH 3 )C 3 H 7 , -CH,CH(CH 3 )C,H 5 , -CH^H^, -CH 2 CH,CH(CH 3 ) 2 , -CH(CH 3 )C 4 H 9 , -CH,CH(CH 3 )C 3 H 7 , -CH,CH 2 CH(CH 3 )C 2 H 5 , -CH,CH,CH 2 CH(CH 3 ) 2 , -CH(CH 3 )CH(CH 3 ) 2 , -CH(C 2 H 5 )CH 2 CH 2 CH 3 , -CH(CH(CH 3 ) 2 )C 2 H 5 or a-methylbenzyl and especially an alkyl group branched the os-position. Especially preferred alkyl groups represented by R 1 are isopropy sec-butyl and os-methylbenzyl. The alkyl group represented by R 2 is preferably a . jQ -alkyl group, more preferably a C^-alkyl group, especially a C -alkyl group such as methyl, ethyl, 2-acetoxyethyl, n-propyl, isopropyl, n-butyl, isobutyl and sec-butyl, and mor especially optionally substituted C 2^ ,-alkyl such as 2-acetoxyethyl. Where Ring B carries substituent groups these may be selected fro -CN; -NO 2 ; halogen preferably -F, -Cl and Br; -SCN; -OH; NH 2 ; C^-alkyl; C w - alkoxy; C w -alkylCN; C^-alkylOH; C w -alkylCl; C^-alkylBr; C^-alkylF; C w - alkoxy-C, .6 -alkyl; C-^-alkylthio; C^-alkylcarbonyl; C^-alkoxycarbonyl; trifluoromethyl; C,^-alkylamino; di(C 1 ^-alkyl)amino; -NHS0 2 C 1 _ 6 -alkyl; -NHSO j phenyl, -NHCOC-^-alkyl and -NHCOphenyl. The substituents for Ring are preferably selected from -CN, -CH 3 , -C,H 5 , -CH 2 CN and -NHCOCH 3 , more preferably from -CH 3 and -NHCOCH 3 , and especially -NHCOCH 3 . Where Ring B carries substituent groups these are preferably in th 2-,3-,5- or 6-positions, more preferably in the 2- or 3-positions and especially in the 3-position with respect to the -NR'R 2 group. A preferred sub-group of dyes of Formula (1) is that in which A is phenyl, isothiazol-5-yl, benzoisothiazol-3-yl, l,2,4-thiadiazol-5-yl, l,3,4-thiadiazol-5 yl or pyrazol-5-yl, Ring B is unsubstituted or carries a 3-methyl or a 3- methylacetylamino substituent, R 1 is an α-branched optionally substituted C 1Q - alkyl group and R 2 is C 0 -alkyl. A further preferred sub-group of dyes of Formula (1) is that in which A is phenyl, thiazol-2-yl, isothiazol-5-yl, l,3,4-thiadiazol-5-yl or thien-2-yl, Ring B is unsubstituted or carries a 3-methyl or a 3-methylacetylamino substitue R 1 is an α-branched optionally substituted C 3 _ 10 -alkyl group and R 2 is C 0 -alkyl. A further preferred sub-group of dyes of Formula (1) is that in which R 1 is secbutyl, isopropyl or α-methylbenzyl, R 2 is ethyl, n-butyl, 2- phenoxyethyl, 2-acetoxyethyl or secbutyl, Ring B is unsubstituted or carries a 3- methyl or a 3-methylacetylamino substituent and A is 3-methyl-4-cyanoisothiazol- yl, benzoisothiazol-3-yl, l,2,4-thiadiazol-5-yl, l,3,4-thiadiazol-5-yl or pyrazol-5-yl. A further preferred sub-group of dyes of Formula (1) is that in which R 1 is secbutyl, isopropyl or α-methylbenzyl, R 2 is ethyl, n-butyl, 2- acetoxyethyl or secbutyl, Ring B is unsubstituted or carries a 3-methyl or 3- methylacetylamino substituent and A is 3-methyl-4-cyanoisothiazol-5-yl. A further preferred sub-group of dyes of Formula (1) is that in which R 1 is secbutyl, isopropyl or α-methylbenzyl, R 2 is ethyl, n-butyl, 2- phenoxyethyl, 2-acetoxyethyl or secbutyl, Ring B carries a 3-methyl or 3- methylacetylamino substituent and A is 3-methyl-4-cyanoisothiazol-5-yl. A further preferred sub-group of dyes of Formula (1) is that in which R 1 is secbutyl, or α-methylbenzyl, R 2 is ethyl, n-butyl, 2-phenoxyethyl, 2- acetoxyethyl or secbutyl, Ring B carries a 3-methyl acetylamino substituent and A is 4-cyano-3-methylisothiazol-5-yl. According to a further feature of the present invention there is provided the use of a monoazo dye having a coupling component of Formula (15 c ormu l a ( 15) wherein: R 1 , R 2 and Ring B are as hereinbefore defined, in a coating for a thermal trans printing sheet which improves the light fastness of an image printed onto a receiver sheet from the thermal transfer printing sheet, except for the use of 4-( thiocyanatobenzothiazol-2-ylazo)-3-methyl-N-ethyl-N-secbutylaniline, 3-(2-[4-N- secbutyl-N-ethylamino)-2-methylphenylazo]-4- chlorothiazol-5-yl)-2-cyanoacrylic acid ethyl ester, 3-(2-[4-(N-secbutyl- N-n-butylamino)-2-methylphenylazo]-4- chlorothiazol-5-yl)-2-cyanoacrylic acid ethyl ester, 3-(2-[4-(N-isopropyl-N-methyl amino)phenylazo]-4-chloro-3-cyanothien-5-yl)-2-cyanoacrylic acid n-butyl ester, 4 (3-[2-methoxyethyl]-4-cyanoisothiazol-5-ylazo)-3-acetylamino-N-secbutyl-N-n-buty aniline, 4-(3-methyl-4-cyanoisothiazol-5-ylazo)-3-acetylamino-N-sechexyl-N- ethylaniline, 4-(3-sechexyl-4-cyanoisothiazol-5-ylazo)-3-acetylamino-N-sechexyl-N propylaniline, 4-(3-methyl-4-cyanoisothiazol-5-ylazo)-N-isopropyl-N-methylaniline 4-(4,5-dicyano-l-cyanomethylimidazol-2-ylazo)-N,N-diisopropylaniline and 4-(5- nitrothiazol-2-ylazo)-3-acetylamino-6-methoxy-N-isopropyl-N-ethylaniline, 4-(3- ethylthiol,2,4,-thiadiazol-5-ylazo)-3-methyl-N,N-diisopropylaniline. According to a further feature of the present invention there is provided a dye of Formula (1) in which A is isothiazol-5-yl, benzoisothiazol-5-yl pyrazol-5-yl, R 1 , R 2 and Ring B are as hereinbefore defined except for 4-(3-[2- methoxyethyl]-4-cyanoisothiazol- 5-ylazo)-3-acetylamino-N-secbutyl-N-n- butylaniline. Where A is isothiazol-5-yl it is preferably of Formula (4), or benzoisothiazol-3-yl it is preferably of Formula (5), or pyrazol-5-yl it is preferabl of Formula (6). According to a further feature of the present invention there is provided a dye of Formula (1) in which A is l,2,4-thiadiazol-5-yl, R 1 , R 2 and Ri B are as hereinbefore defined provided that R 1 and R 2 are different. Where A i l,2,4-thiadiazol-5-yl, it is preferably of Formula (7). According to a further feature of the present invention there is provided a dye of Formula (1) in which A is l,3,4-thiadiazol-5-yl, R 1 , R 2 and Ring B are as hereinbefore defined except for 4-(2-ethylsulphonyl-l,3,4-thiadiazol-5- ylazo)-3-acetylamino-N-ethyl-N-(2-cyanoethoxy-l-methylethyl)aniline, 4-(2-bromo- l,3,4-thiadiazol-4-ylazo)-3-acetylamino-N-isopropyl-N-prop-2-ene aniline and 4-(2- ethylthio-l,3,4-thiadiazol-5-ylazo)-3-acetylamino-N-ethyl-N-(l-methyl-3- oxobutyl)aniline. Where A is l,3.4-thiadiazol-5-yl it is preferably of Formula (8). According to a further feature of the present invention there is provided a dye of Formula (1) wherein A is a pyridoisothiazol-3-yl of Formula (9) and R 1 , R 2 and Ring B are as hereinbefore defined. The Coating The coating suitably comprises a binder together with a dye or mixture of dyes of Formula (1). The ratio of binder to dye is preferably at least 0.7:1 and more preferably from 1:1 to 4:1 and especially preferably 1:1 to 2:1 in order to provide good adhesion between the dye and the substrate and inhibit migration of the dye during storage. The coating may also contain other additives, such as curing agents, preservatives, etc., these and other ingredients being described more fully in EP 133011A, EP 133012A and EP 111004 A. The Binder The binder may be any resinous or polymeric material suitable for binding the dye to the substrate which has acceptable solubility in the ink medium, i.e. the medium in which the dye and binder are applied to the transfer sheet. It is preferred however, that the dye is soluble in the binder so that it can exist as a solid solution in the binder on the transfer sheet. In this form it is generally more resistant to migration and crystallisation during storage. Examples of binders include cellulose derivatives, such as ethylhydroxyethylcellulose (EHEC), hydroxypropylcellulose (HPC), ethylcellulose, methylcellulose, cellulose acetate and cellulose acetate butyrate; carbohydrate derivatives, such as starch; alginic acid derivatives; alkyd resins; vinyl resins and derivatives, such as polyvinyl alcohol, polyvinyl acetate, polyvinyl butyral, polyvinyl acetoacetal and polyvinyl pyrrolidone; polycarbonates such as AL-71 from Mitsubishi Gas Chemicals and MAKROLON 2040 from Bayer (MAKROLON is a trade mark); polymers and co- polymers derived from acrylates and acrylate derivatives, such as polyacrylic acid, polymethyl methacrylate and styrene-acrylate copolymers, styrene derivatives such as polystyrene, polyester resins, polyamide resins, such as melamines; polyurea and polyurethane resins; organosilicones, such as polysiloxanes, epoxy resins and natural resins, such as gum tragacanth and gum arabic. Mixtures of two or more of the above resins may also be used, mixtures preferably comprise a vinyl resin or derivative and a cellulose derivative, more preferably the mixture comprises polyvinyl butyral and ethylcellulose. It is also preferred to use a binder or mixture of binders which is soluble in one of the above-mentioned commercially acceptable organic solvents. The dye or mixture of dyes of Formula (1) has good thermal properties giving rise to even prints on the receiver sheet, whose depth of shade is accurately proportional to the quantity of applied heat so that a true grey scale of coloration can be attained. The dye or mixture of dyes of Formula (1) also has strong absorbance properties and is soluble in a wide range of solvents, especially those solvents which are widely used and accepted in the printing industry, for example, alkanols, such as i-propanol and butanol; aromatic hydrocarbons, such as toluene, ethers, such as tetrahydrofuran and ketones such as MEK, MIBK and cyclohexanone. Alternatively the mixture of dyes may be dispersed by high shear mixing in suitable media such as water, in the presence of dispersing agents. This produces inks (solvent plus mixture of dyes and binder) which are stable and allow production of solution or dispersion coated dyesheets. The latter are stable, being resistant to dye crystallisation or migration during prolonged storage. The combination of strong absorbance properties and good solubility in the preferred solvents allows the achievement of good OD of the dye or mixture of dyes of Formula (1) on the receiver sheet. The transfer sheets of the present invention have good stability and produce receiver sheets with good OD and which are fast to both light and heat. The Substrate The substrate may be any sheet material preferably having at least one smooth even surface and capable of withstanding the temperatures involved in DDTTP, i.e. up to 400°C for periods up to 20 msec, yet thin enough to transmit heat applied on one side through to the dyes on the other side to effect transfer of the dye onto a receiver sheet within such short periods. Examples of suitable materials are polymers, especially polyester, polyacrylate, polyamide, cellulosic and polyalkylene films, metallised forms thereof, including co-polymer and laminated films, especially laminates incorporating a smooth even polyester receptor layer on which the dye is deposited. Thin ( <20 micron) high quality paper of even thickness and having a smooth coated surface, such as capacitor paper, is also suitable. A laminated substrate preferably comprises a backcoat, on the opposite side of the laminate from the receptor layer, which, in the printing process, holds the molten mass together, such as a thermosetting resin, e.g a silicone, acrylate or polyurethane resin, to separate the heat source from the polyester and prevent melting of the latter during the DDTTP operation. The thickness of the substrate depends to some extent upon its thermal conductivity but it is preferably less than 20μmand more preferably less than lOμm. The DDTTP Process According to a further feature of the present invention there is provided a dye diffusion thermal transfer printing process which comprises contacting a transfer sheet comprising a coating comprising a dye or mixture of dyes of Formula (1) with a receiver sheet, so that the coating is in contact with the receiver sheet and selectively applying heat to discrete areas on the reverse side of the transfer sheet whereby the dye on the opposite side of the sheet to the heated areas is transferred to the receiver sheet. Heating in the selected areas may be effected by contact with heating elements, which can be heated to 200-450°C, preferably 200-400°C, over periods of 2 to 10 msec, whereby the dye mixture may be heated to 150-300°C, depending on the time of exposure, and thereby caused to transfer, substantially by diffusion, from the transfer to the receiver sheet. Good contact between coating and receiver sheet at the point of application is essential to effect transfer. The density of the printed image is related to the time period for which the transfer sheet is heated. The Receiver Sheet The receiver sheet conveniently comprises a polyester sheet material, especially a white polyester film, preferably of polyethylene terephthalate (PET). Although some dyes of Formula (1) are known for the coloration of textile materials made from PET, the coloration of textile materials, by dyeing or printing is carried out under such conditions of time and temperature that the dye can penetrate into the PET and become fixed therein. In thermal transfer printing, the time period is so short that penetration of the PET is much less effective and the substrate is preferably provided with a receptive layer, on the side to which the dye is applied, into which the dye mixture more readily diffuses to form a stable image. Such a receptive layer, which may be applied by co-extrusion or solution coating techniques, may comprise a thin layer of a modified polyester or a different polymeric material which is more permeable to the dye than the PET substrate. While the nature of the receptive layer will affect to some extent the depth of shade and quality of the print obtained it has been found that the dyes of Formula (1) give particularly strong and good quality prints (e.g. fastness and storage properties) on any specific transfer or receiver sheet, with the benefit of improved light fastness compared with other dyes of similar structure which have been proposed for thermal transfer printing processes. The design of receiver and transfer sheets is discussed further in EP 133,011 and EP 133012. The invention is further illustrated by the following examples and comparative examples in which all parts and percentages are by weight. Ink Preparation The inks were prepared by dissolving 0.15g of the dye in a solution containing 5g of a 6% w/w solution of ethylhydroxyethyl cellulose (EHEC) in tetrahydrofuran and 4.85g tetrahydrofuran (THF). Transfer Sheet TS1 This was prepared by applying Ink 1 to a όμmpolyester film (substrate) using a wire-wound metal Meyer-bar (K-bar No 3) to produce a wet film of ink on the surface of the sheet. The ink was then dried with hot air to give a dry film on the surface of the substrate. Printed Receiver Sheet RSI A sample of TS1 was contacted with a receiver sheet, comprising a composite structure based in a white polyester base having a receptive coating layer on the side in contact with the printed surface of TS1. The receiver and transfer sheets were placed together on the drum of a transfer printing machine and passed over a matrix of closely-spaced elements which were selectively heated using a constant power of 0.37W/pixel for periods from 2 to 10 msec, whereby a quantity of the dye, in proportion to the heating period, at the position on the transfer sheet in contact with an element while it was hot was transferred from the transfer sheet to the receiver sheet. After passage over the array of elements the transfer sheet was separated from the receiver sheet. Evaluation of Inks. Transfer Sheets and Printed Receiver Sheets The stability of the ink was assessed by visual inspection. An ink was considered to be stable if there was no precipitation over a period of two weeks at ambient. The light fastness of receiver sheets was assessed by calculating the colour difference of the receiver sheets before and after exposure to xenon light as follows: Half of the receiver sheet was covered before exposure, in an Atlas Ci35 Weatherometer, to xenon arc light at 0.8W/m" at a black panel temperature of 45°C and relative humidity of approximately 50% for 24 hours. The colour difference (ΔE) between the exposed and the unexposed areas on the receiver sheets which correspond to a print time of lOmsec was measured using a Minolta Chromameter utilising the following equation: ΔE X: (L^-L *2 ) 2 + (a *-a 2 ) 2 + (b • 1 ~ -b ) where L *1 , a '1 and b "1 are the values before exposure and L '2 , a "2 and b *2 are the values after exposure to xenon light. The smaller the value of ΔE the more light fast is the dye on the receiver sheet. The colour difference (ΔE) values for a range of dyes of the present 5. invention, Dyes 1 to 18, along with comparative examples, Dyes A to O, are summarised in the following tables: Table 1 Table 2 Dye type: Table 3 Dye type: Table 4 Dye type: H 3 C CN NHCOCH j Table 5 Dye type: F Table 6 Dye type: Dye type: The light fastness of some of the above dyes was assessed after exposure to xenon light for 100 hours under similar conditions to those above, the results are summarised in Table 8: Table 8 The above tabulated data shows that the dyes of the present invention having at least one branched chain N-alkyl have lower ΔE values and hence better light fastness than the straight chain analogous dyes.

Claims: CLAIMS 1. A thermal transfer sheet comprising a substrate having a coating comprising a dye of Formula (1): Formu l a C O wherein: ? ■ A is the residue of a diazotisable aromatic or heterocyclic amine; R 1 is an optionally substituted branched chain alkyl group; R 2 is an optionally substituted straight or branched chain alkyl group; and Ring B is unsubstituted or may be substituted from 1 to 4 substituent groups, except for 4-(6-thiocyanatobenzothiazol-2-ylazo)-3-methyl-N-ethyl-N-sec butylaniline, 3-(2-[4-N-secbutyl-N-ethylamino)-2-methylphenylazo]-4- chlorothiazol- 5-yl)-2-cyanoacrylic acid ethyl ester, 3-(2-[4-(N-secbutyl-N-n-butylamino)-2- methylphenylazo]-4-chlorothiazol-5-yl)-2-cyanoacrylic acid ethyl ester, 3-(2-[4-(N- isopropyl-N-methylamino) phenylazo]-4-chloro- 3-cyanothien-5-yl)-2-cyanoacrylic acid n-butyl ester, 4-(3-[2-methoxyethyl]-4-cyanoisothiazol-5-ylazo)-3-acetylamino- N-secbutyl-N-n-butyl aniline, 4-(3-methyl-4-cyanoisothiazol-5-ylazo)-3-acetylamino- N-sechexyl-N-ethylaniline, 4-(3-sechexyl-4-cyanoisothiazol-5-ylazo)-3-acetyIamino- N-sechexyl-N-n-propylaniline, 4-(3-methyl-4-cyanoisothiazol-5-ylazo)-N-isopropyl- N-methylaniline, 4-(4,5-dicyano-l-cyanomethylimidazol-2-ylazo)-N,N- diisopropylaniline, 4-(5-nitrothiazol-2-ylazo)-3-acetylamino-6-methoxy-N-isopropyl- N-ethylaniline and 4-(3-ethylthio- l,2,4,-thiadiazol-5-ylazo)-3-methyl-N,N- diisopropylaniline . 2. A thermal transfer printing sheet according to Claim 1 in which A in the dye of Formula (1) is selected from phenyl, naphthyl, thiazolyl, isothiazolyl, benzothiazolyl, benzoisothiazolyl, pyrazolyl, thiadiazolyl, imidazolyl, thienyl, pyridyl and pyridoisothiazolyl each of which may be optionally substituted. 3. A thermal transfer printing sheet according to Claim 1 in which A in the dye of Formula (1) is phenyl, naphth-1-yl, thiazol-2-yl, isothiazol-5-yl, benzothiazol-2-yl, benzoisothiazol-3-yl, pyrazol-5-yl, l,2,4-thiadiazol-5-yl, 1,3,4- thiadiazol-5-yl, imidazol-2-yl, thien-2-yl, pyrid-2-yl, pyrid-3-yl, pyrid-4-yl or pyridoisothiazol-3-yl. 4. A thermal transfer printing sheet according to Claim 1 in which A in the dye of Formula (1) is selected from phenyl, thiazol-2-yl, isothiazol-5-yl, 1,3,4- thiadiazol-5-yl or thien-2-yl. 5. A thermal transfer printing sheet according to Claim 1 in which A in the dye of Formula (1) is phenyl substituted by from 1 to 3 groups selected from - N0 2 , -CN, -Br and -CH 3 , thiazol-2-yl substituted by 1 or 2 groups selected from - Cl or -CHO, isothiazol-5-yl substituted by 1 or 2 groups selected from -CN and - CH 3 , l,3,4-thiadiazol-5-yl substituted by ethylthio or thien-2-yl substituted by from 1 to 3 groups selected from -CN, -CH 3 and -COj Hj. 6. A thermal transfer printing sheet according to any one of Claims 1 to 5 in which R 1 is an alkyl group branched at the α-position. 7. A thermal transfer printing sheet according to any one of Claims 1 to 5 in which R 1 is optionally substituted C 3 _ 10 -alkyl and R 2 is C^o-alkyl. 8. A thermal transfer printing sheet accroding to any one of Claims 1 to 5 in which R 1 is secbutyl or α-methylbenzyl and R 2 is selected from methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl and secbutyl. 9. A thermal transfer printing sheet according to Claim 1 wherein in the dye of Formula (1) R 1 is secbutyl or α-methylbenzyl, R 2 is ethyl, n-butyl, 2- phenoxyethyl, 2-acetoxyethyl or secbutyl, Ring B is unsubstituted or carries a 3- methyl or 3-acetylaminosubstituent and A is 3-methyl-4-cyanoisothiazol-5-yl, benzoisothiazol-3-yl, l,2,4-thiadiazol-5-yl, l,3,4-thiadiazol-5-yl or pyrazol-5-yl. 10. A thermal transfer printing sheet according to Claim 1 wherein in the dye of Formula (1) A is phenyl, isothiazol-5-yl, benzoisothiazol-3-yl, 1,2,4- thiadiazol-5-yl, l,3,4-thiadiazol-5-yl or pyrazol-5-yl, Ring B is unsubstituted or carries a 3-methyl or a 3-methylacetylamino substituent, R 1 is an α-branched optionally substituted C^^-alkyl group and R 2 is C j . j o-alkyl. 11. A thermal transfer printing sheet according to Claim 1 wherein in the dye of Formula (1) A is phenyl, thiazol-2-yl, isothiazol-5-yl, l,3,4-thiadiazol-5-yl or thien-2-yl, Ring B is unsubstituted or carries a 3-methyl or a 3- methylacetylamino substituent, R 1 is an α-branched optionally substituted Cy. w - alkyl group and R 2 is C^^-alky!. 12. A thermal transfer printing sheet according to Claim 1 wherein in the dye of Formula (1) R 1 is secbutyl or α-methylbenzyl, R 2 is ethyl, n-butyl, 2- acetoxyethyl or secbutyl, Ring B is unsubstituted or carries a 3-methyl or 3- methylacetylamino substituent and A is 3-methyl-4-cyanoisothiazol-5-yl. 13. A thermal transfer printing sheet according to Claim 1 wherein in the dye of Formula (1) R 1 is secbutyl or α-methylbenzyl, R 2 is ethyl, n-butyl, 2- phenoxyethyl, 2-acetoxyethyl or secbutyl, Ring B carries a 3-methyl or 3- methylacetylamino substituent and A is 3-methyl-4-cyanoisothiazol-5-yl. 14. A thermal transfer printing sheet according to Claim 1 wherein in the dye of Formula (1) R 1 is secbutyl or α-methylbenzyl, R 2 is ethyl, n-butyl, 2- phenoxyethyl, 2-acetoxyethyl or secbutyl, Ring B carries a 3-methyl acetylamino substituent and A is 4-cyano-3-methylisothiazol-5-yl. 15. A dye diffusion thermal transfer printing process which comprises contacting a transfer sheet comprising a coating comprising a dye or mixture of dyes of Formula (1) with a receiver sheet, so that the coating is in contact with the receiver sheet and selectively applying heat to discrete areas on the reverse side of the transfer sheet whereby the dye on the opposite side of the sheet to the heated areas is transferred to the receiver sheet. 16. The use of a monoazo dye having a coupling component of Formula (15): Formu l a ( 15) wherein: R\ R 2 and Ring B are as hereinbefore defined, in a coating for a thermal transfer printing sheet which iihproves the light fastness of an image printed onto a receiver sheet from the thermal transfer printing sheet, except for 4-(6- thiocyanatobenzothiazol-2-ylazo)-3-methyl-N-ethyl-N-secbutylaniline, 3-(2-[4-N- secbutyl-N-ethylamino)-2-methyl phenylazo]-4- chlorothiazol-5-yl)-2-cyanoacrylic acid ethyl ester, 3-(2-[4-(N-secbutyl- N-n-butylamino)-2-methylphenylazo]-4- chlorothiazol-5-yl)-2-cyanoacrylic acid ethyl ester, 3-(2-[4-(N-isopropyl-N-methyl amino)phenylazo]-4-chloro- 3-cyanothien-5-yl)-2-cyanoacrylic acid n-butyl ester, 4- (3-[2-methoxyethyl]-4-cyanoisothiazol-5-ylazo)-3-acetylamino-N-secbutyl-N-n-butyl aniline, 4-(3-methyl-4-cyanoisothiazol-5-ylazo)-3-acetylamino-N-sechexyl-N- ethylaniline, 4-(3-sechexyl-4-cyanoisothiazol-5-ylazo)-3-acetylamino-N-sechexyl-N-n- propylaniline, 4-(3-methyl-4-cyanoisothiazol-5-ylazo)-N-isopropyl-N-methylaniline, 4-(4,5-dicyano-l-cyanomethylimidazol-2-ylazo)-N,N-diisopropylaniline, 4-(5- mtrothiazol-2-ylazo)-3-acetylamino-6-methoxy-N-isopropyl-N-ethylaniline and 4-(3- ethylthio-l,2,4,-thiadiazol-5-ylazo)-3-methyl-N,N-diisopropylaniline.

Inventors: BRADBURY ROY, SHAWCROSS ANDREW PAUL, BRADBURY, ROY, SHAWCROSS, ANDREW, PAUL
Applicants: BRADBURY ROY, ICI PLC, SHAWCROSS ANDREW PAUL, IMPERIAL CHEMICAL INDUSTRIES PLC
Application year: 1993
Main classification: B41M5
IPC codes: B41M5, C09B29, D06P1, D06P5