Method of forming lead-acid battery electrode

Abstract: In a preferred method, an electrode (10) for a lead-acid battery is prepared in a new continuous process without the conventional curing step. The general procedure for preparing electrodes (10) according to the invention includes preparing a mixture (paste) comprising an active material precursor and an inhibitor. The active material precursor includes lead oxides having at least 10% by weight lead oxide in the form of Pb₃O₄ (red lead), and a BET surface area of at least about 0.8 m²/gram; desirably about 1.00 to 1.50 m²/gram and preferably about 1.0 to 1.25 m²/gram. The inhibitor prevents formation of tribasic lead sulphate and tetrabasic lead sulphate from the precursor material, except at elevated temperature and consists of hydroxyl-containing organic or inorganic compounds, such as glucose, fructose, sorlitol. The paste is applied to electrode grids (15) and is reacted at elevated temperatures for between about 5 and about 30 minutes, to form the active material (30) of the electrode (10) for both positive and negative electrodes. The electrodes (10) are then assembled into batteries and charged. Negative electrodes differ from the positive electrodes, mainly in the additives used.

Description: This invention relates to electrodes of lead-acid batteries and to a method of manufacture thereof as specified in the preamble of claim 1. Automotive type lead-acid batteries have interlaced positive and negative electrodes, also called plates. Each plate consists of special material, known as "active material", supported on lead-alloy grids. The active material is formed from lead oxide pastes which are processed to a firm, porous form. In the preparation of plates for a lead-acid battery, a mixture is formed containing oxides of lead, a significant amount of metallic lead, sulphuric acid, water, and various additives. As a result of chemical reaction during mixing, a portion of the mixture is initially converted to lead sulphate (PbSO₄), providing an active material precursor paste which includes lead and its oxides and sulphates. The precursor paste is applied to conductive lead grids and, using conventional methods, the freshly-pasted plates are then typically cured to stabilise the precursor material and to enhance the strength of the plates. Both positive and negative plates are made by the same basic process except for the selection of additives. Typically, negative plates are cured for up to three days in a highly humid and warm air atmosphere to oxidise the free lead present therein. Positive plates are cured by treatment with steam at a temperature near 100°C for 3 hours. Plates are assembled in a battery and formed in a multi-stage process which involves electrically charging said plates at a relatively high rate in several stages, each lasting several hours. The curing steps of current processes are time-consuming and often lead to irregular product quality because such curing often fails to fully oxidise the lead present in the plates. The achievement of each plate being essentially lead-free (i.e. a fully-oxidised product) is a key feature of a high-quality product. Therefore, it is desirable to have a new process for preparing electrodes which produces a more consistent and lead-free product. A method of forming an electrode plate for a lead-acid battery according to the present invention is characterised by the features specified in the characterising portion of claim 1. The present invention provides a method of obtaining an electrode for a lead-acid battery, in which said electrode is formed in a continuous process without steaming and curing. The general procedure for preparing electrodes includes preparing a mixture (in the form of a paste) comprising an active material precursor, sulphate-containing acids, and an inhibitor. The active material precursor includes lead oxides having at least 10% by weight lead oxide in the form of Pb₃O₄ (red lead), and a BET surface area of at least 0.80 m²/gram; desirably about 1.00 to about 1.50 m²/gram, and preferably about 1.0 to about 1.25 m²/gram. The inhibitor prevents formation of tribasic lead sulphate and tetrabasic lead sulphate from the precursor material and sulphate-containing acids, except at elevated temperatures. The paste is applied to electrode grids and reacted at elevated temperatures for between about 5 and about 30 minutes, to form the active material of the electrode for both positive and negative electrodes. Plates are then assembled into batteries and charged. Negative electrodes differ from the positive, mainly in the additives used. More specifically, the lead sulphates used at non-elevated temperatures are predominantly monobasic lead sulphate, PbO.PbSO₄ (nPbO.PbSO₄,n=1). At moderately high temperatures, tribasic lead sulphate (3PbO.PbSO₄) forms; and tetrabasic lead sulphates (4PbO.PbSO₄) forms with further processing at temperatures of about 80°C to about 100°C. Typically, the tri-(n=3) and tetra-(n=4) basic lead sulphates form, rather than dibasic lead sulphate (n=2). An important aspect of the invention is the use of a lead sulphate derived from red lead in which the surface area is maximised through control of acid stoichiometry and reaction conditions. The lead sulphate derived from red lead is actually a mixture of PbO₂, PbO, and PbO.PbSO₄. It has been found that the surface area is maximised where the stoichiometry is near the monobasic lead sulphate point (PbO.PbSO₄). That is, a ratio of PbO/PbSO₄ of about 2, providing about one mole equivalent sulphate (SO₄) for every two moles equivalent of lead (Pb). The maximum surface area at this same stoichiometry is obtained through the controlled reaction of 50% sulphuric acid with a red lead, preferably by absorbing the acid on a diatomaceous earth material (such as the material sold under the trade name of Celite 503) prior to adding the red lead. Good results are obtained when at least a minimum amount of red lead, at least down to about 10 weight percent, is used. Objects, features and advantages of this invention are an electrode for a lead-acid battery and method of making it which improves consistency of product, essentially eliminates hard-to-control curing steps, prevents blistering of plates, and enhances plate strength. These and other objects, features and advantages will become apparent from the following description of the preferred embodiments, appended claims and accompanying drawings, in which: Figure 1 is a schematic drawing of an electrode for a battery. Figure 2 is a flow diagram showing some of the important steps of a process according to one aspect of the present invention. Figures 3(a), 3(b), 4, and 5 are flow diagrams showing some of the important steps of other alternative processes of the present invention. Figures 6(a) and (b) are flow diagrams showing some of the important steps of an alternative process of the present invention for forming negative plates. Figures 7, 8, 9, and 10 are diagrams of percent utilisation as a function of battery cycles. Figure 1 shows a schematic drawing of an electrode 10 for use in a lead-acid battery. The electrode has a lead-based alloy substrate 15 which is in the form of a grid with recesses 20. The substrate grid 15 has surfaces containing oxides of lead. A coating 25, comprising an active material 30, is applied to both sides of the grid 15. In Figure 1, only one side is shown with active material. A tab 40 provides a terminal. Electrodes 10 were made from standard production grids 15 available from Delco-Remy, U.S.A.. These grids 15 are made of a typical lead-based 1% tin alloy containing a minor amount of calcium. A grid for a positive electrode 10 is of a 1% tin, 0.05% to 0.07% calcium lead-alloy, with a thickness of about 0.109 cm (0.043"). Electrode grids having an active area of about 11.6 cm² were made. The active area of the grid consisted of about 12 diamond-shaped sections at the lower end of the test electrode. Larger, full-sized electrodes were 264 cm² in area. Smaller electrodes were used primarily for screening purposes. The general procedure for preparing electrodes includes preparing a mixture (paste) comprising an active material precursor and an inhibitor. The active material precursor includes lead oxides having at least 10% by weight lead oxide in the form of Pb₃O₄ (red lead), and a surface area of at least 0.8 m²/gram. Desirably, the red lead (Pb₃O₄) content of the lead oxide is about 5 to about 30 weight percent, and preferably about 7.5 to about 15 weight percent. Desirably, the BET surface area of the lead oxide, having the desired red lead content, is about 0.80 to about 1.50 m²/gram, and preferably about 1.0 to about 1.25 m²/gram. The inhibitor prevents formation of tribasic lead sulphate and tetrabasic lead sulphate from the precursor material, except at elevated temperature, typically in excess of 80°C. The paste is applied to electrode grids and reacted at elevated temperatures in a range of about 80°C to about 100°C for between about 5 and about 30 minutes, to form the active material of the electrode for both positive and negative electrodes. Plates are then assembled into batteries and charged. Negative electrodes differ from the positive electrodes, mainly in the additives used. The inhibitor facilitates the use of a two-stage reaction process. In a first stage, discrete lead sulphate or basic lead sulphate is prepared. These compounds may be prepared from either lead oxide or red lead. The lead sulphate of the first stage is subsequently reacted with more lead oxide in a second stage to form tribasic or tetrabasic lead sulphate in the electrode plate. More specifically, the lead sulphates prepared in the first stage are predominantly composed of the monobasic lead sulphate, PbO.PbSO₄ (nPbO.PbSO₄,n=1). This is then reacted in the second stage process to form tribasic lead sulphate (3PbO.PbSO₄) at relatively moderate temperatures, or tetrabasic lead sulphates (4PbO.PbSO₄), with further processing at temperatures of about 80°C to about 100°C. Typically, the tri-(n=3) and tetra-(n=4) basic lead sulphates are formed, rather than dibasic lead sulphate (n=2). It has been found that under certain conditions, lead sulphate forms slowly from lead oxide and sulphuric acid. Thus, the monobasic sulphate is formed as the stable, first-stage material. Ordinarily, these reactions take place quite rapidly in conventional pasting procedures with sulphuric acid. In contrast, in the method of the present invention, the transition from monobasic to tribasic lead sulphates is retarded by the presence of inhibitors which block the surface of the lead oxide until activated by heat. This process permits crystals of tribasic lead sulphate to develop in the pasted plate, rather than in the paste mixer, and to give better plate strength. An important aspect of the invention is the use of a lead sulphate derived from red lead in which the surface area is maximised through control of acid stoichiometry and reaction conditions. The lead sulphate derived from red lead is actually a mixture of PbO₂, PbO, and PbO.PbSO₄. It has been found that the surface area is maximised where the stoichiometry of the sulphate mixture is near the monobasic lead sulphate point (PbO.PbSO₄). That is, a ratio of PbO/PbSO₄ of about 2, providing about one mole equivalent sulphate (SO₄) for every two moles equivalent of lead (Pb). The maximum surface area at this same stoichiometry is obtained through the controlled reaction of 50% sulphuric acid with a red lead, preferably by absorbing the acid on a diatomaceous earth material (Celite 503) prior to adding the red lead. Good results are obtained when at least a minimum amount of red lead, at least down to about 10 weight percent, is used. As shown from the following examples, the use of red lead sulphate with maximised surface area, enhances formation of the positive plates and very probably eliminates blistering after the plate is formed. The use of hydroxyl-containing organic or inorganic reaction inhibitors controls the course of the two-stage chemical reactions which take place in the formation process (pasting process), and gives better plate strength. Desirably, the hydroxyl-containing compound is a polyhydroxyl organic compound, and preferably is glucose, fructose or sorbitol. The various lead oxides and reagents used are as shown in Table 1. The preferred active material formed from red lead is prepared by one of several preferred methods, as described in the following examples. The active material precursor is applied to grids which are not pre-treated to form surface oxides. If desired, oxidised grids could be used. Example 1 Lead sulphate pastes were made by combining red lead (a lead oxide having 25% by weight Pb₃O₄) with 10% by weight of a lead sulphate obtainable from J.T. Baker Chem. Co., U.S.A., in a high speed blender. The resulting dry powder was then mixed with an appropriate amount of water along with a selected inhibitor, typically boric acid or sorbitol (see Table 1). The resulting paste was applied to the grids and the grids were heated in a humid atmosphere in unsealed metal foil envelopes for about 10 to about 15 minutes at about 100°C, removed from the foil envelopes and then dried. The plates thus obtained were then assembled in a battery and charged. The general flow diagram for this process is shown in Figure 2. Example 2 In this example 75% red lead (75% Pb₃O₄) was reacted with sulphuric acid in the presence of sufficient water to form the desired paste consistency in the final stage when more lead oxide was added. The amount of sulphuric acid was varied from the stoichiometric point to slightly more than the amount needed to give monobasic lead sulphate (PbO.PbSO₄). For each batch of 75% red lead it was necessary to titrate for the exact analysis since it was found that the actual amount of red lead present in the lead oxide was closer to 71%, rather than the stated 75%. The acid-water-lead oxide mixture was heated to about 75°C to 80°C, with vigorous stirring for a period of 2 hours, or until the pH value for the mixture rose above 5. The resulting product had a thick, creamy consistency and was light-brown in colour. Electrodes were made by weighing the proper amount of the mixture so as to give a 10% by weight PbSO₄ paste when added to the selected lead oxide or red lead oxide and inhibitor, as shown in Figure 3(a). The inhibitor improved viscosity and retarded hardening of the pastes. The applied pastes were heated at a temperature of about 80°C to about 100°C, for about 20 minutes to about 25 minutes, in a humid (100% relative humidity) atmosphere as per Example 1, and then assembled into a battery. Example 3 A variation of the pasting process of Example 2 used a two-part paste in which 50% to 70% by weight of the paste was tetrabasic lead sulphate for plate stability, and the remainder was from the paste-mix described above and shown in Figure 3(a). This process is shown in Figure 3(b). Comparative Tests In comparative tests, pastes made from 25% red lead (25% Pb₃O₄) and lead sulphate pastes, rapidly turned to a grainy consistency with very poor plasticity, making it almost impossible to paste such pastes on to grids. Increasing the water content caused cracking of dried electrodes, as was seen in previous work. In contrast, the use of 1% boric acid or other inhibitors, preferably organic inhibitors, as in Examples 1 and 2, gave smooth pastes stable for a minimum of 30 minutes. Small and large electrodes made by the method of the examples were tested. Small electrodes were evaluated either against gassing lead counter-electrodes with a lead sponge reference electrode, or in small tri-electrode cells with two small Delco-Remy negative counter-electrodes. Most of the preliminary screening tests were run with gassing counter-electrodes in a large excess of electrolyte. Normally, 1.280 sulphuric acid (37 w/o) was used as the electrolyte. Small electrodes were most commonly formed at the two hour rate with a 25% excess charge above the theoretical amount. Discharge was at the same current density as for formation. If small complete cells were used, the same procedure was used with the exception that the electrolyte contained Formax (phenolsulphonic acid) at a concentration of 0.79 to 1.32 ml/litre (3 to 5 ml/gallon) to help negative electrode formation. Full-sized positive electrodes were always evaluated in polyethylene "baggy" type cells against two Delco-Remy production negative electrodes retained by Plexiglas plates. Daramic separators (silica filled polyethylene) were used around the positive electrodes. In the present work, production Delco-Remy negative electrodes were pre-formed over a 16 hour period to about 25% of the theoretical capacity thereof and then assembled into the test cell with the positive electrodes, formed as per the examples. The test cell was then formed over a 5 hour period at constant current to 125% of the positive theoretical capacity thereof. The discharge of the test cell was at a 2 hour rate to 1.75V. Normal charge during cycling was at a 5 hour rate with a voltage limit of 2.65V. In all cases, the full capacity of the electrodes was removed (100% depth of discharge). Cycling was normally terminated at 20% of theoretical. Plates made with the inhibited paste, produced by the process of Examples 1 and 2, were strong and gave good cycling results, as seen in Figure 7. In contrast to conventional methods, the pastes of Examples 1 and 2 were applied and heated, only. There was no conventional curing step used. After heating, the plates were assembled into a battery and charged. In various tests, it was shown that the surface area of lead dioxide (PbO₂), derived from red lead could be maximised by controlling the amount of residual PbO in the lattice through treatment with nitric acid, rather than sulphuric acid as in Example 2. The condition of red lead treated with either nitric acid or sulphuric acid was similar. Using sulphuric acid, good results were observed by controlling stoichiometry. From Table 1, items 6-9 and 11, it is seen that the surface area of the acid treated red lead goes through a maximum. Although not precisely determined, it appears that the highest surface area takes place at a PbO/H₂SO₄ ratio of 2.25 and slowly decreases thereafter. This coincides with conditions needed to maintain an initial composition near to the monobasic lead sulphate. Then the remaining reaction to the tribasic lead sulphate will take place at a later stage when the electrodes have been pasted. The highest surface area was obtained in material No.11, where the reaction was controlled by pre-absorbing the acid on Celite 503. The surface area optimisation effect is seen only with red leads containing more than 50% Pb₃O₄. It is important that each batch of red lead should be analysed to make sure the actual red lead content is matched to the proper amount of acid required. Another important factor is the order of addition of the reaction inhibitor. If the inhibitor is added to the red lead before the addition of the sulphuric acid, the surface area of the product may be reduced by as much as 50%. It is, therefore, important that the inhibitor should always be added after the formation of the red lead sulphate. It should be noted that the treatment of plain lead oxide with sulphuric acid did not produce the same effect as did red lead, and surface area did not vary with stoichiometry. Thus, red lead is the preferred starting material. A large number of plates, both negative and positive, have been made by the method of Example 2, as shown in Figure 3(a). Most of the electrodes made with this process used either a 1% boric acid inhibitor or a 0.25% sorbitol inhibitor. A major portion of the plates in this example were designed with 10% lead sulphate level, red lead content of 15% to 17%, and inhibitors selected from boric acid, sorbitol, fructose, glucose or other simple sugars. Positive plates made by this method gave good cycling results, as shown in Figure 8, when compared with conventional positive plates. Example 4 The method of Example 2 was used except that the 25% red lead was replaced with ordinary leady oxide. When not fully cured to remove the free lead, leady oxide normally gives blistered positive plates in conventional electrodes. The plates made by the method of Example 2 did not show this blistering, and the cycle lives of plates made with pure 25% red lead or leady oxide are essentially the same. Example 5 Plates were made by a modification of the process of Example 2, as shown in Figure 4. In this case, the acid was pre-absorbed by the Celite and then reacted with the red lead. The resulting plates appeared somewhat stronger than those of Example 2 (non-Celite plates), and showed comparable utilisation's and life as shown in Figure 9. An additional benefit of the Celite was the lower loss of the positive active material at the end of battery life. Pasted plates without the Celite showed 20 grams or more active material loss after 50, C/2 rate cycles, whereas the Celite-containing plates lost only 5 to 6 grams. The amount of Celite which could be used in the plates to improve the plate properties was only up to about 3% by weight. Anything above this level tended to reduce the density of the plates too much or lower the strength of the plate. Another problem with the Celite in any of its available forms is the iron content thereof, i.e. about 1% ferric oxide. Small amounts of iron are known to reduce both the hydrogen and oxygen over-voltages at the negative and positive electrodes, respectively. The iron could be removed by acid treatment with hydrochloric acid (HCl), but this would increase the cost significantly. There are other forms of porous ceramic materials available, which have very high liquid absorption values, that can be used as alternatives to Celite. Example 6 A finely powdered red lead sulphate was obtained by a modification of Example 5, in which the acid concentration was increased by restricting the amount of water used prior to reaction with sulphuric acid. Although 50% sulphuric acid gives a granular and essentially non-usable product, increasing the acid concentration to 75% gives a finely-divided material which can be used to make electrodes with good physical and electrochemical properties. Batches of 200 grams Pb₃O₄ were treated with 40 grams of 75 w/o sulphuric acid in a mixer at an acid addition rate such that the heat evolution was not excessive. The reaction was extremely rapid and completed within 5 minutes. The process is shown in Figure 5. The resulting product was stable and could be stored for long periods of time until it is reacted with lead oxide, water, and inhibitor to make the desired paste. The typical cycling results for electrodes made by the concentrated acid method (Example 6, Figure 5) of preparing red lead sulphate are shown in Figure 10. The cycling results were similar to other data with the exception that the capacity was relatively flat for about 30 cycles, rather than reaching a maximum and then slowly decreasing. The initial utilisation was quite good in spite of the fact that the surface area of the red lead sulphate made by the concentrated acid method was only in the 3 to 4 m²/gram range. It may well be that areas as high as the 6 to 7 m²/gram seen with the Celite methods are not necessary. The most important factor to be considered in preparing the red lead sulphate is that there should be no agglomeration of the crystals which gives non-uniform electrodes with poor strength. Example 7 Negative plate pastes were made by slight modifications to the positive plate procedures, primarily by addition of an expander. Plates were then reacted in open foil envelopes similar to those used with the positive plates. These processes are shown in Figures 6(a) and 6(b). As shown in Figure 6(a), 25% red lead by weight, derived from 75% red lead, was added to the dry ingredients and processed. In another variation (Figure 6(b)), the red lead was pre-reacted with the acid in a large batch followed by the addition of the lead oxide, expander, inhibitor, and polymer fibres. This method was used to make both positive plates and negative plates from a single batch. Positive plates are made first, and to the remaining part of the mix, an expander is added for making the negative plates. Tests showed that the negative plates made by the process of Figure 6(a) gave cycling results essentially the same as those obtained with conventional negative plates. Negative plates made by the process shown in Figure 6(b) have also been shown to give good cycling properties. Whilst the process shown in Figure 6(b) is more complicated than the process shown in Figure 6(a), the process shown in Figure 6(b) is the preferred one because the electrodes obtained thereby are stronger. Comparative Tests - Negative Plates Negative plates were made using leady oxide and with all ingredients combined at the beginning. The sulphuric acid was added last and the paste applied to the grids. These did not form or cycle well. There were large areas of unconverted lead sulphate, and capacities were lower than that of plates made as shown in Figures 6(a) and 6(b). Thirty full-sized positive and negative plates, made according to the invention, were evaluated in full-sized 9 plate cells consisting of 5 positive and 4 negative plates. Positive plates were made by the method of Example 2 with leady oxide as the major component and with boric acid inhibitor. Negative plates were made by the process shown in Figure 6(a) also using leady oxide and a boric acid inhibitor. All cells were given a standard 130Ah/lb formation. The cell capacities were all within acceptable limits for the first 25A rate tests, but showed poor results when given a cold cranking test at -17.8°C (0°F). This was due to the effects of the boric acid inhibitor in the negative electrodes. When boric acid was replaced with sorbitol or one of the other simple sugars, good results were obtained. The organic inhibitors used in the Examples have at least one hydroxyl group per carbon atom. Preferably, they are simple sugars and related compounds. Boric acid and ammonium bicarbonate were also used as inhibitors, although the organic polyhydroxyl compounds are preferred. Best results were obtained using organic compounds where most of the carbon atoms have hydroxyl groups attached. Linear molecules are preferred. Random ketone, aldehyde or carboxyl groups are acceptable, unless there is reaction to form acetic acid, which will ruin the positive electrode of the battery. Good results were obtained with sorbitol, mannitol, fructose, glucose, and even sucrose. There are many other polyhydroxyl compounds which will work as well, including optical and geometrical isomers of simple sugars and their acids. The simple sugars such as glucose and fructose, as well as sorbitol, are preferred since they are low in cost. They are effective in the 0.05 to 0.50 w/o range, and in the preferred range of 0.10 to 0.25 w/o. While specifically added as a reaction inhibitor in positive pastes, the polyhydroxyl compounds appear to improve the negative electrode as well. The surface area of the lead sulphate on cycling is in the range of 1.0 to 1.34 m²/gram with the sorbitol and a maximum of only 0.79 m²/gram without sorbitol. The embodiments of the invention in which an exclusive property or privilege is claimed are defined in the appended claims.

Claims: A method of forming an electrode plate for a lead-acid battery in which an active material precursor paste containing oxides of lead, metallic lead, and lead sulphates is applied to a conductive lead grid, characterised in that the method comprises the steps of: a) forming an oxide of lead having at least 10% by weight lead oxide in the form of Pb₃O₄ (red lead); b) forming a wet mixture containing basic lead sulphate (nPbO.PbSO₄) predominantly in the monobasic form (PbO.PbSO₄) by reacting the oxide of step (a) with one or more compounds containing a sulphate group in an amount sufficient to provide at least one mole equivalent of sulphate (SO₄) for every two moles equivalent of lead (Pb) in the oxide of step (a); c) forming an oxide of lead having less than 1% by weight lead in the form of free lead; d) intermingling the mixture formed in step (b), the oxide of step (c), and an inhibitor having at least one hydroxyl group to form said active material precursor paste; e) applying the product of step (d) to said grid; and f) heating the applied product for a time and at a temperature and at a humidity sufficient to react the monobasic lead sulphate therein so as to form at least one of tribasic lead sulphate (3PbO.PbSO₄) and tetrabasic lead sulphate (4PbO.PbSO₄). A method according to claim 1, in which the temperature used in step f) is 80°C to about 100°C. A method according to claim 1 or 2, in which the time used in step f) is less than 5 minutes for producing a negative electrode and between about 10 and 15 minutes for producing a positive electrode. A method according to claim 1, 2 or 3, in which the heating of step f) takes place in an atmosphere essentially saturated with water (100% relative humidity). A method according to claim 1, in which the compound containing a sulphate group used in step b) is either sulphuric acid or ammonium sulphate. A method according to claim 1, in which step (d) is accomplished by first intermingling the oxide of step (c) with the inhibitor and then including the mixture formed in step (b). A method according to claim 1, in which the inhibitor is selected from the group consisting of hydroxyl-containing organic and inorganic compounds. A method according to claim 1, in which the inhibitor is selected from the group consisting of glucose, fructose and sorbitol. A method according to claim 1, in which the lead oxide of step (a) has a surface area of at least 1.0 m²/gram. A method according to claim 1, in which the compound containing a sulphate group in step (b) is an acid, and step b) is conducted by first causing the acid to be absorbed by ceramic particles, and then mixing the ceramic particles with the oxides of step (a), so that the acid reacts with the oxide. A method of forming an electrode plate for a lead-acid battery in which an active material precursor paste containing oxides of lead, metallic lead, and lead sulphates is applied to a conductive lead grid, characterised in that the method comprises the steps of: a) forming said active material precursor paste as a wet mixture comprising basic lead sulphate (nPbO.PbSO₄) predominantly in the monobasic form (PbO.PbSO₄), at least one oxide of lead and an inhibitor having at least one hydroxyl group; b) applying the mixture of step (a) to said grid; and c) heating the applied mixture for a time and at a temperature and at a humidity sufficient to react the monobasic lead sulphate therein to form at least one of tribasic lead sulphate and tetrabasic lead sulphate. A method according to claim 11, in which, before step (a), the basic lead sulphate is formed by reacting an oxide of lead having at least 10% by weight lead oxide in the form of Pb₃O₄ (red lead) with one or more acids containing a sulphate group in an amount sufficient to provide at least one mole equivalent of sulphate (SO₄) for every two moles equivalent of lead (Pb). A method according to claim 12, in which the oxide of lead having at least 10% by weight lead oxide in the form of Pb₃O₄ has a surface area of at least 1.0 m²/gram. A method according to claim 12, in which said one acid is absorbed by ceramic particles and the ceramic particles are then mixed with the oxide, so that the acid reacts with the oxide. A method according to claim 14, in which the acid is sulphuric acid. A method according to claim 11, in which at least one oxide of lead is selected from the group consisting of leady oxide (PbO/Pb), lead oxide (PbO), and an oxide of lead having at least 10% by weight lead oxide in the form of Pb₃O₄ (red lead). A method according to claim 11, in which the temperature used in step c) is 80°C to about 100°C. A method according to claim 11, in which the heating in step c) takes place in an atmosphere essentially saturated with water (100% relative humidity). A method according to claim 11, in which, before step (a), the basic lead sulphate is formed by reacting lead sulphate (PbSO₄) with an oxide of lead having at least 25% by weight lead oxide in the form of Pb₃O₄ (red lead). A method according to claim 19, in which the oxide of lead having at least 25% by weight lead oxide in the form of Pb₃O₄ has a surface area of at least 1.0 m²/gram. A method according to claim 11, in which the inhibitor is selected from the group consisting of glucose, fructose, and sorbitol.

Inventors: GARABEDIAN GREGORY CHARLES, WITHERSPOON ROMEO RICHARD, GARABEDIAN, GREGORY CHARLES, WITHERSPOON, ROMEO RICHARD
Applicants: GEN MOTORS CORP, GENERAL MOTORS CORPORATION
Application year: 1993
Main classification: H01M4
IPC codes: H01M4