HEATING MEANS FOR CATALYST UNIT

Abstract: Means for heating of a ceramic monolith coated with catalytic material, comprising a flat strip cross section steel wire with at least 15% Cr and at least 0.5% Al placed in the monolith near its entry face.

Description: HEATING MEANS FOR CATALYST UNIT Background of the invention Catalyst units are among other tasks used for cleaning of exhaust gases from combustion engines through oxidation of hydrocarbons and reduction of oxides of nitrogen. They are commonly made as a ceramic carrier monolith body with parallel channels, and a surface coating of cathalytically active material such as platinum, palladium or other metals. The cathalytic materials require an elevated temperature in use to reach full activity. If no special means are employed, the activity is lowest when the exhaust contains most hydrocarbons right after the start of the engine. There is always some low activity, and the increasing temperature of the exhaust due to the exothermic reaction at the oxidation of the hydrocarbons will heat the whole cathalyst unit to an active temperature after a while. Different ways to preheat the cathalyst unit before starting the engine have been suggested, such as making the monolith of electrically conducting material which is then heated by electric current or by magnetically induced eddy currents. Another suggestion has been to blow hot clean gas through the unit. These suggestions have disadvantages in requiring expensive or bulky auxiliary equipment. The invention describes means for rapid heating of cathalyst units comprising ceramic carrier monolith bodies. Principle of the invention A ceramic monolith comprises a great number of channels with thin walls coated with the cathalytic material. The monolith has an entry face and an exit face. According to the invention a metal wire is placed near the entry face across the channels. The wire is made of a heat resistant alloy such as chromium steel with at least 15 % Cr, preferrably between 19 % and 26 %. The wire is preferrably made with a flat strip cross section which is oriented to reduce the resistance of the channels as little as possible, with the large diameter in the direction of the channels. At a start of the engine the wire is heated by an electric current, thereby heating also the adjoining catalytic material to full active temperature through heat radiation, heat conduction or by heating the gas flow. Oxidation of hydrocarbons will then soon yield enough energy to bring the whole monolith to an active temperature. A further improvement is making the wire from a chromium steel containing also at least 0.5 % aluminium, preferrably 4 to 6 %. The metal wire will then have an oxide coat which can be durably coated with the same catalytic material as the monolith in the same operation. In such a case it is sufficient to " heat the wire to the active temperature of the catalytic material, starting the oxidation of the hydrocarbons at the wire surface and bringing the monolith to an active temperature even faster. Description of the invention Ceramic monoliths can be manufactured by different methods. Most common is extrusion according to patent EP 294 106 or EP 294 261 where the channels form patterns of squares or concentric circles. Figure 1 shows how grooves are created near the entry face (11) of a monolith (10) of this kind by removing parts of the walls (12) , and how the metal wire (13) can be placed in the grooves and held by its -elasticity. A metal wire with flat strip cross-section is preferrable because of lower flow resistance and larger available surface for catalytic coating. It is not necessary to let the wire (13) traverse all channels, since the heat will soon spread through the walls to other channels. Another type of ceramic monolith is described in patent US 5,093,178 where the monolith is formed by making a coil of smooth (24) and corrugated (25) aluminium foils, which are later converted to aluminium oxide through anodic oxidation. With this type of monolith the wire can be placed between the foils during coiling as shown in figure 2-3, where figure 3 shows the initial position of the foils and the wire, and figure 2 shows a partially finished coil type monolith. For simplest electric connection, the wire is made as two legs (20,21) joined at a bend (22), with both legs terminating at the peripheral surface of the monolith. In this case it is important that the wire is made from an alloy that is not destroyed by the anodic oxidation. In this case, the chromium steel with at least 15 % Cr and at least 0.5 % Al is also suitable. During coiling the wire (20,21) is placed near the edge (23) which will become the entry face of the monolith. The wire need not traverse all channels, and it is then possible to place one or more corrugated foils and one or more smooth foils (24) between the legs (20,21) of the wire. The wire is preferrably made with flat strip cross-section because of lower flow resistance. The flat strip cross-section can be achieved either by flat rolling of a round wire or by slitting of wider strip into flat wires.

Claims: CLAIMS 1. Means for heating of a cathalyst unit for combustion engines comprising a ceramic monolith with channels for exhaust gas, and a metal wire heated by electric current, characterized by the wire being located within the monolith near that face of the monolith where the exhaust gases enter and traversing a multitude of channels. 2. Means according to claim 1, characterized by the wire having a flat strip cross-section. 3. Means according to claim 1, characterized by the wire (13) being placed in a groove formed by removal of parts of walls (12) near the entry face (11) of a monolith (10) formed by extrusion. 4. Means according to claim 1, characterized by the wire (20,21) being placed between the foils (24,25) near the entry face of a monolith formed by coiling of aluminium foils. 5. Means according to claim 2,3 or 4, characterized by the wire being made from chromium steel with at least 15 % Cr. 6. Means according to claim 2,3 or 4, characterized by the wire being made from steel with at least 15 % Cr and at least 0.5 % Al. 7. Means according to claim 2,3 or 4, characterized by the wire being made from steel with 19 to 26 % Cr and 4 to 6 % Al. __ 8. Means according to claim 2,3 or 4, characterized by the wire being coated with the same catalyst coating as the monolith.

Inventors: CARLBORG CARL-GUSTAF, SUNDSTROEM ERIK, CARLBORG, CARL-GUSTAF, SUNDSTROEM, ERIK
Applicants: CARLBORG CARL GUSTAF, SANDVIK AB, SUNDSTROEM ERIK
Application year: 1993
Main classification: F01N3
IPC codes: B01D53, B01J35, F01N3