PROCESS FOR PRODUCING PAPER OR PAPERBOARD WITH INCREASED STRENGTH FROM MECHANICAL PULP

Abstract: A process for producing paper or paperboard from mechanical pulp, wherein the pulp is treated with a phenol-oxidizing enzyme system after the grinding and/or refining of logs or wood chips has been completed.

Description: PROCESS FOR PRODUCING PAPER OR PAPERBOARD WITH INCREASED STRENGTH FROM MECHANICAL PULP. TECHNICAL FIELD This invention relates to a process for production of paper or paperboard of increased strength from mechanical pulp. BACKGROUND ART Mechanical pulp, such as ground wood pulp, refined mechanical pulp, thermomechanical pulp, etc. is generally produced by grinding logs or chips in a grinder or refiner where the temperature increases to near or above boiling. The three main constituents of the pulp are cellulose, hemicellulose and lignin. From these types of pulp, paper or paperboard is generally manufactured as follows: The pulp is treated in a screening process, is mixed with paper or paperboard making additives in the stock preparation section in order to prepare the paper or paperboard furnish. A paper or paperboard is then made from the furnish on a paper machine. The mechanical pulps have an advantage of providing hig fyield but on the other hand they have inferior strength properties compared to chemical pulps. High paper strength is generally desirable. Conventional methods for increasing the paper strength include the use of wet strength additives and binders. STATEMENT OF THE INVENTION We have found that, surprisingly, the strength of the paper of paperboard can be increased by treating the pulp with a phenol-oxidizing enzyme system (e.g. laccase and oxygen) after the mechanical refining. It is believed that this strengthening is due to polymerization or cross-linking of the lignin present at the surface of the fibers. Accordingly, the invention provides a process for producing paper or paperboard from mechanical pulp, characterized in that the pulp is treated with a phenol-oxidizing enzyme system after the grinding and/or refining of logs or wood chips has been completed (e.g. during stock preparation), i.e. no mechanical refining occurs after the enzyme treatment. EP 429,422 discloses reduction of energy consumption in the refining stages by use of laccase during pulp preparation between the first and second refining stage; the document indicates that some increase of paper strength is also obtained. However, the enzyme treatment is done at 20°C, so this prior-art process requires an extra cooling stage after the first refining step. The process of this invention would obviously defeat the object of EP 429,422 as the enzyme treatment occurs after the last refining stage and therefore has no effect on energy consumption during refining. DETAILED DESCRIPTION OF THE INVENTION Phenol oxidizing enzyme system The enzyme system used in the invention consists of a suitable oxidase together with 0 2 or a suitable peroxidase together with H 2 0 2 . Suitable enzymes are those which oxidize and polymerize aromatic compounds such as phenols and lignin. Examples of suitable enzymes are catechol oxidase (EC 1.10.3.1), laccase (EC 1.10.3.2) and peroxidase (EC 1.11.1.7). Some preferred enzymes are peroxidase derived from a strain of Coprinus, e.g. C. cinerius or C. macrorhizus, peroxidase from Bacillus, e.g. β. pumilus and laccase from Trametes, e.g. T. versicolor (previously called Polyporus). It may be preferable to use two different phenol oxidizing enzymes together. The amount of peroxidase should generally be in the range 10-10,000 PODU per g of dry substance (PODU unit of peroxidase activity defined below). The amount of laccase should generally be in the range 10-10,000 units per g of dry substance (unit of laccase activity defined below). Molecular oxygen from the atmosphere will usually be present in sufficient quantity. A suitable amount of H 2 0 2 will usually be in the range 0.01 -10 mM, particularly 1-10 mM. Process conditions The enzyme treatment can be done at conventional consistency, e.g. 0.5-10 % dry substance, at temperatures of 20-90°C. Determination of peroxidase activity (PODU) Peroxidase activity is determined from the oxidation of 2,2'-azinobis(3- ethylbenzothiazoline-6-sulfonate) (ABTS) by hydrogen peroxide. The greenish-blue colour produced is photometered at 418 nm. The analytical conditions are 0.88 mM hydrogen peroxide, 1.67 mM ABTS, 0.1 M phosphate buffer, pH 7.0, 30°C, 3 minutes reaction. 1 p_eroxidase unit (PODU) is the amount of enzyme that catalyses the conversion of 1 μmol hydrogen peroxide per minute at these conditions. Determination of laccase activity Laccase activity was determined by a similar method without addition of hydrogen peroxide. 1 unit of laccase activity was defined as the amount of enzyme that catalyses the oxidation of 1 μmol ABTS per minute. EXAMPLE 1 6.96 g of a ground wood pulp (GWP) was dissolved in 72 ml 0.1 M buffer (Britton-Robinson buffer consisting of boric acid, phosphoric acid, and acetic acid) at pH 5.5, corresponding to a dry solid content of 1.8 g (2.5%). A laccase from Polyporus pinsitus was added to a concentration of 528 laccase units/g dry pulp. The mixture was shaken in a water bath at 50°C for 2 hours. Subsequently a paper sheet was made from the pulp in a laboratory hand sheet former. The sheet was subsequently pressed and dried in a rapid sheet dryer. The tear index of the paper sheet was determined, and for comparison a similar experiment was done without any enzyme added. The results were as follows: EXAMPLE 2 249 g of a ground wood pulp having a dry solid content of 15%, was dissolved 2500 ml 0.1 M buffer similar to the one described in Example 1 at pH 5.5, corresponding to a dry solid content of 1.5%. The mixture was defibrated in a lab- pulper for 5 minutes and thereafter divided into 3 different parts. To one part laccase from Polyporus pinsitus was added in the same concentration as in Example 1 , to another part inactivated laccase was added, and to the last part water was added. The mixtures were treated for 24 hours at 50°C. Subsequently paper sheets were made as in Example 1 , and the tear index and the tensile index were determined. The results were as follows:

Claims: CLAIMS 1. A process for producing paper or paperboard from mechanical pulp, characterized in that the pulp is treated with a phenol-oxidizing enzyme system after the grinding and/or refining of logs or wood chips has been completed. 2. A process according to Claim 1 , whereby the phenol oxidizing enzyme system consists of a peroxidase and hydrogen peroxide. 3. A method according to Claim 2, wherein the peroxidase is derived from Coprinus or β. pumilus. 4. A method according to Claim 3, wherein the amount of peroxidase is in the range 10-10,000 PODU per g of dry matter, and the amount of hydrogen peroxide is 0.01-10 mM. 5. A method according to Claim 1 , whereby the phenol oxidizing enzyme system consists of laccase or catechol oxidase together with oxygen. 6. A method according to Claim 5, wherein the enzyme is laccase derived from Trametes. 7. A method according to Claim 6, wherein the amount of enzyme is in the range 10-5,000 units per g of dry material. 8. A process according to any preceding claim, whereby the enzyme treatment is at 0.5-10 % consistency, pH 4-10 and 20-90°C.

Inventors: HANSEN TOMAS TAGE, NIELSEN PEDER HOLK, HANSEN, TOMAS, TAGE, NIELSEN, PEDER, HOLK
Applicants: HANSEN TOMAS TAGE, NIELSEN PEDER HOLK, NOVONORDISK AS, NOVO NORDISK A/S
Application year: 1993
Main classification: D21C9
IPC codes: C12S3, D21C5, D21C9, D21H11