Higher modulus compositions incorporating particulate rubber

Abstract: Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.

Description: The Government of the United States of America has rights in this invention pursuant to Contract No. DE-AC07-88ID12695 awarded by the U.S. Department of Energy. FIELD OF THE INVENTION This invention relates to a method for treating vulcanized crumb rubber to be used as a filler or extender in other polymeric resin systems to improve the stiffness, or modulus, of the rubber material to improve the overall modulus of the resulting polymeric resin system incorporating the rubber filler. One source of such crumb rubber is the recycling of used automotive tires. Various efforts have explored means to improve the recovery or usefulness of rubber reclaimed from automotive tires or other applications. Many of these processes are directed to the devulcanization of the rubber, such as the solvent chlorinolysis process described in a publication on "Chlorinolysis Reclaims Rubber of Waste Tires", J.H. Tervet, G.G. Hull and E.R. DuFresne in NASA Tech Brief Vol. 5, No. 3, Item 55 (January 1981). In general, use of reclaimed or other crumb rubber is limited by the low stiffness or modulus of the rubber. Additional uses can be realized and improved polymer systems benefitting from the inclusion of elastomeric rubber fillers or extenders if the rubber stiffness, or modulus, could be increased. Such high modulus rubber could be used in polyurethane and polyester systems. With fillers of the present invention, rubber reclaimed from used tires may effectively and economically be used as fillers and extenders in substitution for high cost polymers while at the same time effecting the environmentally friendly recycling of the used tires. Other means of producing high modulus rubbers have been described in U.S. Patents 4,992,513 and 4,996,262 for producing rubbers having a high modulus by grafting either nylon or polyester onto the rubber. Other methods have used halogenation of the surfaces of rubbers to improve surface adhesion to other polymers. Examples of such treatments are described in U.S. Patent 4,771,110 (use of fluorine) and U.S. Patent 3,553,857 (surface halogenation with bromine or chlorine to improve adhesion). EP-A-0231918 discloses a process for treatment of polymeric materials having controlled physical properties, said treatment involving contacting of the material with a mixture of fluorine and at least one other reactive gas. Such other reactive gases may be Cl 2 , SO 2 , Br 2 , BrCl 3 , BrCl, CO, or oxygen, the latter being preferred. The British patent specification 433 313 discloses a method for chlorinating rubber by use of pure chlorine gas. The material obtained contains high percentages (63%) of chlorine. Similar high chlorine contents (68%) are obtained according to the Japanese patent application JP 71-29069 by treatment of powderized scrap rubber with chlorine or HCl. SUMMARY OF THE INVENTION This invention provides a relatively easy and inexpensive means for substantially increasing the stiffness, as measured by the Young's modulus, of the bulk of a ground or crumb vulcanized rubber bY a gas-solid phase treatment of the rubber with gas consisting of chlorine and air or inert gases, preferably chlorine/air or, even more preferably, a chlorine/nitrogen mixture. No special pretreatment of the rubber is required. The reaction of the rubber with the chlorine gas mixture can be carried out in any suitable reactor. Since solvents are not used, the expense of solvent handling, recovery and drying are avoided. The specific features of said treatment being as set out in the annexed claims. This invention is carried out by treating the crumb rubber, which can be in a crumb, pulverized or finely ground state, with a chlorine-containing gas. The treatment is carried out in a reactor in which the pulverized rubber is contacted with the chlorine-containing gas at a temperature from about 32 °F (0 °C) to about 200 °F (93.3 °C), with the reaction pressure being preferably within the range of from about 1 atm to about 10 atm. The chlorine-containing gas will generally comprise from about 5% chlorine by volume to substantially pure chlorine. Preferably the chlorine concentration is in the range of from about 8% to about 50% by volume although such concentrations are not deemed critical. Since the diffusion and reaction rates of the chlorine within the rubber particles is a function of the concentration and pressure of the chlorine, the more encompassing definition of preferable chlorine concentrations for treating the rubber would be the partial pressure of the chlorine. Measured in this manner, the partial pressure of the chlorine should preferably be within the range of from about 0.05 atmospheres absolute (corresponding to a 5% concentration of chlorine in a system at atmospheric pressure) to about 0.5 atm. absolute. The other components, referred to as diluents, of the chlorine-containing gas may comprise air or inert gases such as nitrogen. Preferably the diluent comprises substantially nitrogen. The contact time will depend upon the size of the rubber particles, since the gas must diffuse into the bulk of the particles, and also upon the reaction gas chlorine concentration, temperature and pressure, but is generally in the range of from about 20 seconds to about 60 minutes. Certain reaction conditions, such as higher temperature, pressure or chlorine partial pressure, could result in shorter required exposure times for desired modulus increases. The chlorine-containing gas may be used in either a batch reaction mode with an initial charge of gas containing sufficient chlorine for treatment or may be added continuously throughout the reaction. Contact between the chlorine-containing gas and the rubber particles is best achieved by tumbling the rubber particles within the reactor or by using the chlorine-containing gas to fluidize the rubber particles. In other embodiments, both the chlorine-containing gas and rubber particles may be continuously added to and taken from the reactor. After a suitable reaction time, the treated rubber is separated from the chlorine-containing gas and is purged of unreacted chlorine-containing gas by a suitable purge gas, preferably either an air or nitrogen purge. The chlorine treated rubber may then be used as a filler or extender in other polymer systems, such as polyurethanes, polyesters, epoxies, nyrim (reaction injection molded nylon), silicone-based polymers, polycarbonates, phenolics, acrylics, polysulfide and other systems requiring a rubber filler of high modulus. This invention encompasses the chlorine-treated rubber filler materials having a high modulus, the method for making such high-modulus rubber fillers, and composite polymer systems incorporating the high modulus, chlorine-treated rubber fillers and extenders. BRIEF DESCRIPTION OF THE DRAMINGS Fig. 1 is a graph of the Young's modulus of the polyurethane composite containing the treated rubber as a function of the bulk chlorine content of the treated rubber which has been treated in a chlorine/air mixture. Fig. 2 is a graph of the Young's modulus of the polyurethane composite containing the treated rubber as a function of the bulk chlorine content of the treated rubber which has been treated in a chlorine/nitrogen mixture. DETAILED DESCRIPTION OF THE INVENTION This invention provides for the modification of rubber materials used as fillers or extenders for other polymer materials to increase the stiffness, measured by the Young's modulus, of the polymer and treated rubber composite material. Young's modulus is defined as a material's resistance to deformation, or stiffness, and is specifically defined as the initial rate of deformation to strain measured by taking the slope of the stress-strain curve in the region of a very small strain. Young's modulus may be measured in accordance with ASTM Method D-638. This increase in the modulus of the composite polymer and treated rubber material makes the treated rubber material suitable for additional use as a filler or extender in composite polymeric materials without excessive decrease in the modulus of the composite polymer which would be normally incident to the use of untreated rubber of the type obtained from automotive tires. In fact, with highly chlorinated rubber particles, the composite may have flexural moduli higher than the host polymer. Such composite polymers would have substantial uses at considerable cost and energy savings. The treated rubber extender made by chlorinating reclaimed tire rubber powder would cost less than about one half to one fourth of the cost of the host polymers. Since it may be substituted in the polymer as an extender or filler at ratios of up to 70% or even higher, depending upon application and polymer system, while maintaining acceptable physical properties, substantial savings will accrue. Possible uses of the chlorinated rubber and polyurethane composite materials are automotive door and window seals, shoe soles, carpet underlay, rollers and solid tires. The process consists of exposing finely ground rubber particles to chlorine gas consisting of chlorine and air or inert gases. The two most economical gases are air and nitrogen, although other relatively inert gases may be used. It will be seen however, that using an inert gas such as nitrogen results in an accelerated chlorination rate and therefore an improved modulus of the ground rubber particles. The rubber is generally ground to a particle size of from about 0.42 to about 0.74 mm (40 mesh U.S. standard, to about 200 mesh U.S. standard), preferably in the range of) 0.17 to 0.14 mm (80 mesh to about 100 mesh). This grinding can be accomplished in any number of conventional grinding and size reduction processes or machines. The particle size to which the rubber is ground will depend upon the intended application of the rubber as a filler or extender. However, the finer the particle size, the more rapid the subsequent chlorination treatment as to improve the bulk modulus of the rubber particles, the treatment process must be allowed sufficient reaction time to enable the chlorine to diffuse and penetrate into the bulk of the rubber particles. Finer particle size provides a higher surface to volume ratio and reduces the required diffusion or penetration distance into the particle interior. The finely divided rubber particles are exposed to the chlorine-containing atmosphere in a suitable reactor in which the rubber powder may be agitated by stirring, tumbling or by fluidization or agitation by the chlorine-containing gas. The treatment may be carried out by any suitable method of contacting the chlorine-containing gas with the powder. The reactor may be charged with a batch of rubber powder and an initial charge of chlorine-containing gas and operated in a batch mode. Alternatively, the chlorine-containing gas may be continuously circulated through the reactor, with or without addition or replenishment of the contained chlorine gas. When used in a continuous addition or recirculation mode, the chlorine-containing gas may advantageously be used to fluidize the rubber powder. Constant recirculation also permits the most efficient use of the contained chlorine and facilitates environmental control. In addition, it is possible to perform the rubber treatment in a fully continuous mode, where chlorine-containing gas and rubber particles are continuously added to and removed from the reactor. To process the rubber safely, the reactor used should be capable of venting dust explosion pressures of up to ten times the starting pressure. Vessels should be designed in accordance with NFPA 68 for ST-1 class dust explosions. The chlorine concentration in the chlorine-containing gas is generally in the range of from about 5% by volume up to 50% by volume. Higher concentrations of chlorine in the treating gas generally require shorter treatment times. With chlorine concentrations of from about 10% to about 50%, with particle sizes generally in the range of from about 0.17 to 0.14 mm (80 mesh to about 100 mesh), and at treatment temperatures in the range of from about 50 °F (10 °C) to about 90 °F (32 °C), treatment times are generally of the order of 1 to 10 minutes for batch reactors. Continuous treatment times can be of 20 to 60 seconds residence time. After an adequate treatment time in the presence of the chlorine-containing gas, the treated rubber particles are separated from the chlorine-containing gas and the treated rubber particle mass are purged of the chlorine-containing gas, generally with air or nitrogen. During such purging, agitation of the powder is continued to assure full removal of the chlorine-containing gas from the powder mass. Once purged of the chlorine-containing gas, the rubber particles may be used as fillers or extenders, in conventional manner, with various polymer systems, but with the result of higher bulk modulus of the resulting composite polymer than if untreated rubber particles were used for filler or extender. Examples Rubber Chlorination Samples of rubber obtained from reclaimed automotive tires were subjected to the chlorine treatment of this invention in a reactor for contacting the rubber with the chlorine-containing gas at atmospheric pressure and ambient temperature. Suitable reactors would include a Rota-Cone" reactor manufactured by Paul 0. Abbe Corp. or a fluidized bed-type reactor. In this example, the reactor consisted of a 316 stainless steel pipe, 15.24 cm (6 inches) in diameter and 30.48 cm (12 inches) long. It was fitted with flanges at both ends. Through the top end, a mechanical stirrer entered the reactor. At the bottom end, a sintered, porous stainless steel plate would support the rubber particles while distributing the reactant gas entering from below. The reactor was water jacketed to control the reactor temperature and to remove the exothermic reaction heat. Chlorine-containing gas was delivered to the reactor throughout the reaction period at rates from 5.6·10 -3 to 13.7·10 -3 m 3 /min (0.20 to 0.49 SCF/min). Temperature of the reactions was at approximately 70 °F (21 °C). The pressure of the reactor was maintained at atmospheric pressure. Gas compositions of from 8-40% Cl 2 in air or N 2 at atmospheric pressure were evaluated. Treatment levels of 1.24·10 -3 - 0.23 m 3 Cl 2 /kg (0.02-3.63 SCF Cl 2 /lb) of rubber were used. At equal treatment levels (SCF Cl 2 /lb rubber), shorter exposure times with higher chlorine concentration in gas) leads to higher bulk chlorine in the treated rubber (Run 3 compared to Run 8; Run 6 vs. Run 12; Run 1 vs. Run 2; and Run 4 vs. Run 5) for both diluent gases. Examples of exposure regimens with the resulting bulk chlorine content in the treated rubber, as measured by elemental combustion analysis, are as follows: Run % Cl in gas Diluent gas Total CFM gas SCF Cl 2 /lb rubber Reaction Time (sec) Bulk % Cl 1 20.0 Air 0.2 0.182 180 2.42 2 40.0 Air 0.2 0.182 90 4.08 3 40.0 Air 0.2 0.364 180 5.38 4 9.2 N 2 0.42 0.182 180 1.47 5 25.0 N 2 0.32 0.182 90 1.95 6 25.0 N 2 0.32 0.364 180 3.23 7 28.6 Air 0.28 0.04 20 1.38 8 28.6 Air 0.28 0.364 180 3.87 9 28.6 Air 0.28 1.09 540 5.58 10 28.6 Air 0.28 3.63 1800 6.96 11 28.6 N 2 0.28 0.04 20 1 12 28.6 N 2 0.28 0.364 180 4.19 13 28.6 N 2 0.28 1.09 540 7.03 14 28.6 N 2 0.28 3.63 1800 7.96 15 8.2 N 2 0.49 0.02 20 0.62 16 8.2 N 2 0.49 0.182 180 1.83 17 8.2 N 2 0.49 0.545 540 2.92 18 8.2 N 2 0.49 1.8165 1800 4.01 19 9.5 Air 0.42 0.02 20 0.74 20 9.5 Air 0.42 0.182 180 1.89 21 9.5 Air 0.42 0.545 540 3.19 22 9.5 Air 0.42 1.8165 1800 4.37 23 -- -- -- -- -- <0.3 Various host polymer systems were composited using chlorinated rubber fillers prepared according to the above examples. Examples of these systems and a comparison of their flexural strength and flexural modulus were made using unchlorinated rubber powder and chlorinated rubber powder as filler in the host polymers. Urethane composites Urethane elastomers containing 15 weight percent of powdered rubber modified according to this invention were prepared using Airthane™ PET 95A urethane resin (Air Products and Chemicals, Inc.) and Ethacure™ 300 (Ethyl Corporation) cross-linker. The urethane elastomers were prepared by combining the identified rubber with preheated resin at 70°-80°C with thorough mixing. Entrained air was removed by vacuum until no further outgassing occurred. The resin was then placed in an oven until the mixing temperature of about 85°C was reached. The resin was then combined with sufficient crosslinker to give an index of 1.05 (equivalent to amine/NCO stoichiometry ratio of 0.95). After thorough mixing, the blend was again degassed and then placed in a mold. The sample was cured at 100°C for 16 hours. The finished specimens were removed from the mold and post-cured for two weeks at room temperature prior to testing. The following results were obtained in accordance with ASTM D-638. Run No. % Cl in gas Diluent gas SCF Cl 2 /lb rubber Reaction Time (sec) Bulk % Cl Young's Modulus 19 9.5 Air 0.02 20 0.74 73.8 7 28.6 Air 0.04 20 1.38 64.1 20 9.5 Air 0.182 180 1.89 69.2 1 20.0 Air 0.182 180 2.42 72.4 21 9.5 Air 0.545 540 3.19 89.1 8 28.6 Air 0.364 180 3.87 79.9 2 40.0 Air 0.182 90 4.08 81.4 22 9.5 Air 1.8165 1800 4.37 114.0 3 40.0 Air 0.364 180 5.38 95.7 9 28.6 Air 1.09 540 5.58 92.5 10 28.6 Air 3.63 1800 6.96 103.2 15 8.2 N 2 0.02 20 0.62 136.8 11 28.6 N 2 0.04 20 1 76.1 4 9.2 N 2 0.182 180 1.47 68.1 16 8.2 N 2 0.182 180 1.83 111.2 5 25.0 N 2 0.182 90 1.95 68.1 17 8.2 N 2 0.545 540 2.92 124.1 6 25.0 N 2 0.364 180 3.23 74.1 18 8.2 N 2 1.8165 1800 4.01 150.2 12 28.6 N 2 0.364 180 4.19 112.0 13 28.6 N 2 1.09 540 7.03 149.8 14 28.6 N 2 3.63 1800 7.96 204.4 23 -- -- -- -- -- 64.1 Fig. 1 is a graph of the Young's modulus of the polyurethane composite containing the treated rubber as a function of the bulk chlorine content of the treated rubber which has been treated in a chlorine/air mixture. Fig. 2 is a graph of the Young's modulus of the polyurethane composite containing the treated rubber as a function of the bulk chlorine content of the treated rubber which has been treated in a chlorine/nitrogen mixture. Both Cl 2 /N 2 and Cl 2 /air treatments of the rubber are effective in increasing the modulus of the rubber, but the effect of the Cl 2 /N 2 treatment on composite bulk modulus is more pronounced.

Claims: A method for increasing the flexural modulus of rubber particles by chlorinating said rubber particles comprising contacting the rubber particles in a gas/solid phase reactor with a gas consisting of chlorine and air or inert gases at a temperature in the range of 0°C (32°F) to 93.3°C (200°F) at a chlorine gas partial pressure in the range of from about 0.05 to about 0.5 atm abs. sufficient to increase the bulk chlorine content of the rubber particles to between about 0.5% and 10%. The method according to claim 1 wherein the partial pressure of the chlorine gas is between from about 0.1 to about 0.5 atm abs., the reaction of the rubber particles and the chlorine containing gas is carried out at from about 0.5 to about 25 atm total pressure, and the resulting rubber particles have a bulk chlorine content from about 1 to about 10 wt% chlorine. The method according to claim 2 wherein the reaction is carried out at atmospheric pressure (1 atm total pressure). The method according to any of the preceding claims wherein the inert gas is nitrogen. A composite polymer comprising a matrix polymer containing as a filler rubber powder having a bulk chlorine content of between 0.5% and 10%, wherein the matrix polymer is selected from the group consisting of polyurethanes, polyesters, epoxies, nylon, silicone based polymers, polycarbonates, phenolics, acrylics and polysulfides. Granulated reclaimed tire rubber having a bulk chlorine content of from 1 to 10 weight percent.

Inventors: BAUMAN BERNARD DANIEL, MCINNIS EDWIN LEE, SCHARFF ROBERT PAUL, WILLIAMS MARK ALAN, BAUMAN, BERNARD DANIEL, MCINNIS, EDWIN LEE, SCHARFF, ROBERT PAUL, WILLIAMS, MARK ALAN
Applicants: COMPOSITE PARTICLES INC, COMPOSITE PARTICLES, INC.
Application year: 1993
Main classification: C08C19
IPC codes: C08L67, C08C19, C08L15, C08L69, C09J175, C08L77, C08L101, C08L63, C08L75, C08F8