WAVEGUIDE TYPE LIGHT DIRECTIONAL COUPLER

Abstract: A power-saving, miniaturized, high-performance light directional coupler. At least two closely-arranged parallel light waveguides of an LiNbO₃ monocrystal film are formed in an LiTaO₃ mono-crystalline substrate or on the substrate. Means for varying the refractive index of the waveguide is provided at least on one of the light waveguides. In addition, the crystal lattice of the LiTaO₃ monocrystal substrate and that of the LiNbO₃ monocrystal film constituting the light waveguides are matched with each other.

Description: TECHNICAL FIELD The present invention relates to an optical coupler according to the preamble of claim 1, more particularly relates to a waveguide type optical coupler for use as an optical modulator and an optical switch in an optical integrated circuit used in an optical fiber communication system, an optical information processing system, an optical sensing system, an optical data registration system and the like. In the field of the optical communication system, in order to build up optical fiber communication networks, it is necessary to develop the optical device such as an optical matrix switch, or the like. The optical directional coupler is a component of such a matrix switch. Such an optical directional coupler is an element used to control in electro-optical effect a phase difference which dominates a transfer of electric power in case of approaching two parallel waveguides. BACKGROUND ART An optical directional coupler according to the preamble of the attached claim 1 is known from "DATABASE WPI," Week 8004, Derwent Publications Ltd., London, GB, AN 80-06403C(04) and JP-A-54 156 555. As an optical directional coupler, hithertofore, a number of Ti diffused LiNbO 3 channel waveguides have been developed. LiNbO 3 is generally utilized as an optical device using the electro-optical effect, since it has a relatively larger electro-optical constant among stable inorganic optical crystals. Means for diffusing Ti into LiNbO 3 is well known as a method of forming a waveguide. However, the Ti diffused LiNbO 3 waveguide has an electro-optical constant different from that of a bulk crystal (or LiNbO 3 ), since it has a different crystallizability from that of virgin LiNbO 3 , after the waveguide has been formed. Accordingly, when such an optical waveguide is used as the optical directional coupler, the problem has arisen of an inability to realise the electrical-power-saving and the down-sizing since a larger switching voltage and a longer effective length are required. In the document "Soviet Physics Technical Physics, Vol. 28, No. 9, pp. 1159-1160, K. S. Buritskii et al, "Electro-optical Modulator with Coupled Ti:LiNbO 3 Channel Waveguides and (Δβ) Electrodes"", a coupled Ti:LiNbO 3 cannel waveguide modulator with Δβ electrodes is described, the waveguide system of which is fabricated by coating a Z-cut LiNbO 3 wafer with a titanium layer, by etching the titanium through a photoresistive mask and by diffusion in air for a period of time. An SiO 2 layer is provided on the surface of the waveguides beneath the electrodes. From EP-A-0 444 209 a thin film of lithium niobate single crystal formed on a lithium tantalate substrate is known, wherein the lattice constant of the "a" axis of said substrate is matched to that of the "a" axis of said thin film. EP-A-0 444 290 does not disclose the application of this structure of a lithium niobate single crystal formed on a lithium tantalate substrate to an optical directional coupler. A directional coupler is known from the document "IEEE Transactions on Microwave Theory and Techniques, Vol. MTT-23, No. 1, pp. 75-70, I. P. Kaminov, "Optical waveguide modulators"". In this known directional coupler lithium niobate waveguides are formed on a lithium tantalate substrate, and it is mentioned in this document that a good match of the waveguide with the substrate will occur on a (001) interface at room temperature while the waveguides formed on (010), (102) faces tend to create cracks. For forming the waveguide, LiNbO 3 powder is placed on the substrate, heated at 1300°C and slowly cooled. Furthermore, this document describes films which are grown on cleavage planes of LiTaO 3 which means that the "c" axis makes an angle of 33° with the plane. It is the object of the present invention to provide a new optical directional coupler according to the preamble of claim 1 having improved characteristics. BRIEF DESCRIPTION OF DRAWINGS Fig. 1 is a perspective view showing an optical modulator comprising an optical directional coupler according to the present invention; and Figs. 2a ∼ 2f are cross-sectional views showing processes of manufacturing an optical modulator comprising an optical directional coupler according to the present invention. BEST MODE FOR CARRYING OUT THE INVENTION The present invention is an optical directional coupling characterized in that the LiTaO 3 single crystal substrate is provided, at least two optical waveguides consisting of the single crystal LiNbO 3 thin film are provided in the LiTaO 3 single crystal substrate close to and parallel to each other, and means for changing refractive index of the optical waveguide is provided on at least one of the close optical waveguides. Therefore, the lattice constant between the LiTaO 3 single crystal substrate and the LiNbO 3 monocrystalline thin film must be matched to each other. The matching of a lattice length (or the lattice constant) means that the lattice constant of the LiNbO 3 monocrystal thin film is adjusted and placed within a range of 99.92 to 100.03 % of the lattice constant of the LiTaO 3 monocrystal substrate. With such a construction, it can prevent a strain (or crystal defect, lattice defect) caused by growing the LiNbO 3 monocrystal with a liquid phase epitaxial method, thereby obtaining a LiNbO 3 monocrystal waveguide having an electro-optic effect equivalent to that of a bulk LiNbO 3 monocrystal. Therefore, when the directional coupler is constructed with such an optical waveguide, a stable amplitude modulation can be realized with very high efficiency. A method of effecting such a lattice matching may preferably be a method described in the International Patent Application Number PCT/JP/90/01207 proposed by the present inventors. There are (1) a method of containing Na and Mg into the LiNbO 3 monocrystal; (2) a method of varying a ratio of Li and Nb in a range of 41 / 59 to 56 / 44; (3) a method of reducing the lattice constant of the LiTaO 3 monocrystalline substrate by Ti doping or the like. In this case, the first method (1) is used, since the lattice constant of the LiTaO 3 monocrystalline substrate is larger than that of the LiNbO 3 monocrystal, so that the lattice constant of the LiNbO 3 monocrystal can be increased by containing Na and Mg thereinto. The Na and Mg are contained in the LiNbO 3 monocrystal, such that the contents thereof are Na of 0.1 to 14.3 mol%, and Mg of 0.8 to 10.8 mol%. The operating principle of the optical directional coupler according to the present invention is explained with reference to Fig. 1. Two optical waveguides 2-1, 2-2 of the LiNbO 3 monocrystal thin film are formed close to and parallel to each other on a (0001) face of the surface of the LiTaO 3 monocrystalline substrate 1. In this case, (0001) face of the optical waveguide of the LiNbO 3 monocrystal thin film must be laminated on the (0001) face of the LiTaO 3 monocrystalline substrate 1. In this case, the lattice constant of respective "a" axes must be matched. The optical directional coupler according to the present invention constitutes a Δβ inversion type directional coupler by providing electrodes 3-1, 3-2, 3-3, 3-4 of a suitable construction on the optical waveguides 2-1, 2-2 of the LiNbO 3 monocrystal thin film, so that it is desirable to induce refractive index change by an electro-optic effect of the optical waveguides 2-1, 2-2 of LiNbO 3 monocrystal thin film, to control the coupling state of the guided wave electrically, and to effect the modulation of the power intensity and exchange of the optical paths. It is advantageous to use a planar electrode. In order to decrease an effect of a DC drift or the like, a buffer layer such as SiO 2 is provided between the optical waveguide and electrodes. In this construction, it is assumed that the coupling portion necessary to transfer an optical power of 100% from one optical waveguide to the other optical waveguide is a coupling length L 0 of 0 dB. The coupling length L 0 is determined by the refractive index and a gap width of the optical waveguide, the wavelength of the laser light or the like. Moreover, when it is assumed that phase differences between two optical waveguides caused by the applied voltage (since electrostatic focusing is caused under the electrode and its signs are different, phase differences caused by changing in such a manner that the propagation constant of the optical waveguide is increased on the one hand and decreased on the other hand) is Δβ, and the length of close and parallel regions is made L, when a light 5 of unit intensity is incident on the optical waveguide 2-1, the light power intensities of both optical waveguides 2-1,2-2 are shown by following formulas as designated in Applied Physics Letters, Vol. 28, No. 503 (1976) by R. V. Schmidt et. al. P 1 = {1-2(χ/β c) 2 sin 2 [(1/2)β cL]} 2 wherein P 1 is light intensity χ is coupling factor β c is the value shown later Δβ is a difference of the propagation constant of two waveguides caused in case of applying voltage L is the complete coupling length ( =π/2χ ) P 2 = (2χ/β c) 2 sin 2 [(1/2)β cL] {cos 2 [1/2]β cL + (Δβ/2β c) 2 sin 2 [(1/2)β cL]} β c = [χ 2 + (Δβ/2)] 1/2 χ = π/2L 0 wherein P 2 is the light intensity As shown in the above formulas, if the phase difference Δβ is given by changing the voltage applied to the electrodes, it is found that the light intensity can be modulated. As explained above, the optical directional coupler according to the present invention may serve as an optical modulator and an optical switch. A method of producing the optical directional coupling according to the present invention will now be described as follows. As a method of producing the optical waveguide of the LiNbO 3 monocrystalline thin film, there are two methods as follows. (1) The waveguide is formed in the substrate: A method of forming an optical waveguide 2 in which a recess is formed in a waveguide formed portion of a LiTaO 3 monocrystalline substrate 1, a LiNbO 3 monocrystal thin film is grown while effecting lattice matching thereof, thereafter a surplus portion is removed and the LiNbO 3 monocrystal thin film is remained only in the recess, thereby forming the optical waveguide 2. (2) The waveguide is formed on the surface of the substrate: A method of forming an optical waveguide 2 in which the LiNbO 3 monocrystalline thin film is grown on the LiTaO 3 monocrystalline substrate 1, while effecting lattice matching, thereafter removing a surplus portion by masking using Ti or the like and by dry-etching on the waveguide formed portion, thus forming the waveguide 2. The method of forming the LiNbO 3 monocrystalline thin film, while effecting the lattice matching is achieved by contacting the LiTaO 3 monocrystalline substrate 1 with a melt consisted of lithium oxide - vanadium pentoxide - niobium pentoxide - sodium oxide - magnesium oxide. Electrode 3 is provided on the optical waveguide 2 of the thus formed LiNbO 3 monocrystalline thin film in order to change the refractive index. It is desirable to form the electrode 3 by coating a metal film such as aluminum or the like onto the optical waveguide 2 by vapor-deposition or sputtering techniques. A buffer layer of SiO 2 is provided between the optical waveguide 2 and the electrode 3. Example 1: (1) Two mol% of MgO with respect to a theoretical quantity of LiNbO 3 which could be separated out from a melt composition was added to a mixture consisting of Na 2 CO 3 22 mol%, Li 2 CO 3 28 mol%, V 2 O 5 40 mol% and Nb 2 O 5 10 mol%, a resultant mixture material was put into a platinum crucible, the mixture within which was heated up to 1100°C and melted under an air atmosphere within an epitaxial growth furnace. The resultant obtained melt in the crucible was stirred over 12 hours at a rotating speed of 100 rpm with a platinum propeller. (2) A (0001) surface of a LiTaO 3 monocrystal substrate 1 (a lattice constant 5.1538 Å of "a" axis) with a thickness of 2 mm was polished optically, and thereafter a chemical etching was performed. Then, a portion where the waveguide 2 was formed as shown in Fig. 1 was patterned by a photolithography technique and then two grooves 7 with a width of 5 µm, a depth of 1.2 µm and a space of 6 µm has been formed by a dry-etching technique. Then, the melt is gradually cooled down to 915 °C at a cooling rate of 60 °C per hour, and thereafter the substrate 1 was preliminarily heated at 915 °C over 30 minutes, and dipped into the melt while rotating it at 100 rpm during 8 minutes. In this case, a growth rate of LiNbO 3 was 1 µm per minute. (3) The substrate 1 was taken up from the melt, and a surplus melt was shaken away by rotating at 1000 rpm during 30 seconds, and then gradually cooled to a room temperature at a cooling rate of 1 °C per minute, thereby obtaining an LiNbO 3 monocrystalline thin film 8 with Na and Mg contents of about 8 µm thickness on the substrate material. (4) The Na and Mg contents contained in the thus obtained LiNbO 3 monocrystalline thin film 8 were 3 mol% and 2 mol% respectively. A lattice constant "a" axis of the thin film 8 was 5.156 Å , and a refractive index measured by an guided light with a wavelength of the coupled light of 1.15 µm was 2.235 ± 0.001. (5) Further, a surplus portion was removed by etching the LiNbO 3 monocrystalline thin film 8 with ion beam, thereby forming optical waveguides 2 of the LiNbO 3 monocrystalline thin film. (6) SiO 2 buffer layers 6 were formed on the optical waveguides 2 by a sputtering technique and aluminum electrodes 3 were formed on the waveguides by the vapor deposition method and by patterning technique so as to obtain an effective length of 15 mm. (7) The optical waveguide device thus produced was coupled to a laser beam of a wavelength of 1.3 µm at TM mode and an AC voltage of 4 GHz was applied thereto, and thereafter the properties of the device was estimated. In this case, extinction ratio of 17 dB was obtained at an operating voltage of 3 V. It has been found as a result of measurement with aging of an emitting light that the modulating voltage and the optical power were not changed at least during the time of 24 hours. These measurements were performed according to JIS-C5931. Example 2: (1) The optical waveguide 2 was formed by the same method as the case of Example 1, but the effective length of the aluminum electrode 3 was 10 mm. (2) The optical waveguide device thus produced was coupled to a laser beam of a wavelength of 1.3 µm at TM mode and an AC voltage was applied thereto, and thereafter the properties of the device was estimated. In this case, extinction ratio of 20 dB was obtained at an operating voltage of 8.4 V. It has been found as a result of measurement with aging of an emitting light that the switching voltage and the optical power were not changed at least during the time of 24 hours. These measurements were performed according to JIS-C5931. Example 3: (1) Two mol% of MgO with respect to a theoretical quantity of LiNbO 3 which could be separated out from a melt composition was added to a mixture consisting of Na 2 CO 3 22 mol%, Li 2 CO 3 28 mol%, V 2 O 5 40 mol% and Nb 2 O 5 10 mol%, a resultant mixture material was put into a platinum crucible, the mixture within which was heated up to 1100°C and melted under an air atmosphere within an epitaxial growth furnace. The resultant obtained melt in the crucible was stirred over 12 hours at a rotating speed of 100 rpm with a propeller. (2) A (0001) surface of a LiTaO 3 monocrystal substrate 1 (a lattice constant 5.1538 Å of "a" axis) with a thickness of 2 mm was polished optically. Then, the melt is gradually cooled down to 915 °C at a cooling rate of 60 °C per hour, and thereafter the substrate 1 was preliminarily heated at 915 °C over 30 minutes, and dipped into the melt while rotating it at 100 rpm during 8 minutes. In this case, a growth rate of LiNbO 3 was 1 µm per minute. (3) The substrate 1 was taken up from the melt, and a surplus melt was shaken away by rotating at 1000 rpm during 30 seconds, and then gradually cooled to a room temperature at a cooling rate of 1 °C per minute, thereby obtaining an LiNbO 3 monocrystalline thin film 8 with Na and Mg contents of about 8 µm thickness on the substrate material. (4) The Na and Mg contents contained in the thus obtained LiNbO 3 monocrystalline thin film 8 were 3 mol% and 2 mol% respectively. A lattice length ("a" axis ) of the thin film 8 was 5.156 Å , and a refractive index measured by an guided light with a wavelength of a coupled light of 1.15 µm was 2.235 ± 0.001. (5) A portion of the optical directional coupling was patterned and Ti mask was formed, and a ridge type channel waveguide was produced by Ar plasma etching. (6) SiO 2 buffer layers 6 were formed on the optical waveguides 2 by a sputtering technique and aluminum electrodes 3 were formed on the waveguides by the vapor depositing and by patterning so as to obtain an effective length of 15 mm. (7) The optical waveguide device thus produced was coupled to a laser beam of a wavelength of 1.3 µm at TM mode and an AC voltage of 4 GHz was applied thereto, and thereafter the properties of the device was estimated. In this case, extinction ratio of more than 17 dB was obtained at an operating voltage of 2.55 V. It has been found as a result of measurement with aging of an emitting light that the modulating voltage and the optical power were not changed at least during the time of 24 hours. Example 4: (1) The optical waveguide 2 was formed by the same method as the case of Example 1, but the effective length of the aluminum electrode 3 was 25 mm. (2) The optical waveguide device thus produced was coupled to a laser beam of a wavelength of 1.3 µm at TM mode and an AC voltage was applied thereto, and thereafter the properties of the device was estimated. In this case, extinction ratio of more than 20 dB was obtained at an operating voltage of 3.3 V. It has been found as a result of measurement with aging of an emitting light that the switching voltage and the optical power were not changed at least during the time of 24 hours. Comparative Example 1: (1) Ti was formed by a vapor deposition technique with a thickness of approximately 100 Å on a Z surface of a LiNbO 3 monocrystalline substrate having a C axis as a thickness direction and having a size of substantially 5 × 15 mm with a thickness of 0.5 mm and at the same position as the place on which the optical waveguide was formed in the Example 1. Thereafter, Ti was patterned and thermally treated at 1000 °C during few hours, thereby thermal-diffusing Ti into the LiNbO 3 monocrystalline substrate resulting a formation of an optical waveguide. (2) Buffer layer of SiO 2 was formed on the optical waveguide by a sputtering technique and aluminum electrodes were formed on the waveguide by the vapor deposition technique and by patterning technique so as to obtain an effective length of 15 mm. (3) The optical waveguide device thus produced was coupled to a laser beam of a wavelength of 1.3 µm at TM mode and an AC voltage of 4 GHz was applied thereto, and thereafter the properties of the device was estimated. In this case, extinction ratio of more than 17 dB was obtained at an operating voltage of 3.5 V. It has been found as a result of measurement with aging of an emitting light under the applied AC voltage that the modulating voltage was changed within 10 minutes and thus the optical power become unstable. Comparative Example 2: (1) A (001) surface of an LiTaO 3 monocrystal having a thickness of 2 mm was polished. (2) Then, a mixture material consisting of Li 2 CO 3 50 mol%, V 2 O 3 40 mol%, and Nb 2 O 5 10 mol% was heated to 1000 °C , thereby forming a melt. Thereafter, this melt was gradually cooled to 915 °C at a cooling rate of 60 °C per hour, concurrently the substrate 1 was preliminary heated at 915 °C during 30 minutes , then dipped into the melt during 8 minutes while rotating at 100 rpm. A growth rate of LiNbO 3 was 1 µm per minute. (3) The substrate 1 was taken up from the melt, and a surplus melt was shaken away on the melt while rotating at 1000 rpm during 30 seconds, and then gradually cooled to the room temperature at a cooling rate of 1 °C per minute, resulting in an LiNbO 3 monocrystalline thin film of about 8 µm thickness formed on the substrate material. (4) A surplus portion of the LiNbO 3 monocrystalline thin film was removed by an ion beam etching, thereby forming a ridge type LiNbO 3 monocrystalline waveguide. (5) An alumina buffer layer was formed on the optical waveguide 2 by sputtering, and aluminum electrodes were formed on the waveguide by the photolithography and vapor deposition techniques. (6) The optical waveguide device thus produced was coupled to a laser beam of a wavelength of 1.3 µm at TM mode and a DC voltage was applied thereto, and thereafter the properties of the device was estimated. In this case, extinction ratio of more than 20 dB was obtained at an operating voltage of 10 V. However, it has been found as a result of measurement with aging of an emitting light under the applied AC voltage that the modulating voltage was changed within 10 minutes and thus the optical power become unstable. The measuring method was performed according to JIS-C5931. Table 1 shows measured results of the respective propers of the examples 1, 2, 3 and 4 as well as the comparative examples 1 and 2. Example (1) Example (2) Example (3) Example (4) Comparative Example 1 Comparative Example 2 Width of Waveguide (µm) 5 5 5 5 5 5 Effective length of electrode 15 10 20 25 15 10 Driving voltage (mm) 3 8.4 2.5 3.3 3.5 10 Electrode interval (mm) 6 6 6 6 6 6 Extinction ratio (dB) 17 20 17 20 17 20 Modulating frequency (GHz) 4 DC 4 DC 4 DC Aging Change (Output fluctuation) Non Non Non Non Presence Presence As is found from numerical value shown in Table 1, the optical directional coupler according to the present invention can exhibit superior characteristics than the conventional optical waveguide. Moreover, in the optical directional coupler according to the present invention, since the lattice length is matched between the optical waveguide of the LiNbO 3 monocrystalline thin film and the LiTaO 3 monocrystal substrate, then lattice distortion is not formed in the optical waveguide of the LiNbO 3 monocrystalline thin film, and even if the refractive index change due to the electric field is repeated, the refractive index of the optical waveguide of the LiNbO 3 monocrystalline thin film is not largely changed from its initial value, so that a lifetime of the optical directional coupler can be lengthened as compared with the conventional optical directional coupler. INDUSTRIAL APPLICABILITY As described above, the optical directional coupler according to the present invention has superior characteristics than the conventional optical directional coupler and is an optical switch and an optical modulator with a long lifetime, so that it can be preferably used in a field of an optical communication system, an optical information system and an optical sensing system.

Claims: An optical directional coupler comprising a substrate (1) of a LiTaO 3 monocrystal substrate (1), two optical waveguides (2) formed on a surface of or in a recess in the substrate (1) and arranged close to and parallel to each other to form a coupling region, and an electrode (3) formed on at least one of the waveguides in the coupling region for changing the optical waveguide's refractive index, characterized in that said waveguides (2) consist of an LiNbO 3 monocrystal thin film, an SiO 2 buffer layer (6) is arranged between the electrode (3) and the optical waveguide (2) of LiNbO 3 monocrystal, and the lattice constant of the "a" axis of the LiNbO 3 monocrystal is adjusted to lie in the range of 99.92 - 100.03% of the lattice constant of the "a" axis of the LiTaO 3 monocrystal by including 0.1-14.3 mole % of Na and 0.8-10.8 mole % of Mg into the LiNbO 3 monocrystal, whereby the thin film of LiNbO 3 monocrystal is lattice-matched on the (0001) surface of the LiTaO 3 monocrystal substrate (1). An optical directional coupling as claimed in claim 1, wherein the optical waveguide (2) is formed in a recess provided on the surface of the substrate (1).

Inventors: NAKUMURA MASANORI, NAKUMURA, MASANORI, NAKUMURA, MASANORI, IBIDEN CO., LTD.
Applicants: IBIDEN CO LTD, IBIDEN CO., LTD.
Application year: 1993
Main classification: G02F1
IPC codes: G02F1