Method of retrofitting a pre-existing plant for urea production including an ammonia stripping section

Abstract: A method of retrofitting a pre-existing plant for urea production including a first urea synthesis reactor (R) in fluid communication with an ammonia stripping section (SS), achieves substantial energy savings and production capacity increase by providing the steps of connecting a second urea synthesis reactor (ROT) of the "once through" type to and upstream of the ammonia stripping section (SS), and of distributing the overall production capacity of the plant to apportion from 50 to 95% thereof to the first (R) and from 5 to 50% to the second (ROT) urea synthesis reactor.

Description: The present invention relates to a method of retrofitting a pre-existing plant for urea production including a first urea synthesis reactor in fluid communication with an ammonia stripping section for separating free ammonia and carbamate leaving the reactor from an aqueous urea solution, which comprises the step of providing a second urea synthesis reactor of the "once through" type having a higher efficiency yield than said first urea synthesis reactor. As is well known, the need often arise of increasing the yield and urea production capacity of a pre-existing plant. To this end, various methods of enhancing the production capacity by retrofitting a pre-existing plant, have been proposed heretofore, such as that described in European Patent application EP-A-0 479 103 by the same applicant. EP-A-0 479103 discloses a urea production process wherein highly pure ammonia and carbon dioxide are reacted in a first reaction space, the reaction mixture thus obtained is fed to a recovery section and a synthesis reaction between less pure reagents, substantially recyded by the recovery section (recovery mixture), is carried out in a second reaction space. According to the above-mentioned European Patent application, a capacity increase of a pre-existing plant is achieved by adding a "once through" high-yield reactor (i.e. fed by pure reagents without recycle water) in parallel to a pre-existing one, which operates in accordance to the total recycle technology (i.e. fed not only by pure reagents, but also with an aqueous carbamate recycle solution). Even though a urea production capacity increase may accomplished in this way, a number of drawbacks still hinder an effective retrofitting of urea production plants including an ammonia stripping section. In accordance with EP-A-0 479 103, in fact, the reaction mixture leaving the added reactor cannot be treated in the ammonia stripping section but must by-pass the same with the consequent need of a capacity increase of the recovery section downstream of the two synthesis parallel reactors, and with a substantial increase of the overall energy consumption of the urea synthesis process. The problem underlying the present invention is therefore that of providing a method of retrofitting a urea production plant which allows a substantial capacity increase, while reducing at the same time the overall energy consumption required by the retrofitted plant thus obtained. This problem is solved, according to the invention, by a method of retrofitting as indicated in attached claim 1 and which is characterized in that it comprises the steps of: a) connecting said second reactor to and upstream of said ammonia stripping section and with means for feeding high purity ammonia and carbon dioxide; b) distributing overall production capacity to apportion from 50 to 95% of said capacity to said first urea synthesis reactor and from 5 to 50% to said second urea synthesis reactor c) reducing the production capacity of the pre-existing reactor. In accordance with a first advantageous aspect of the present invention, the required capacity increase and reduction of energy consumption are simultaneously achieved by reducing the load of the pre-existing reactor and by feeding the added reactor so as to reach with the latter the new, higher, value of production capacity. Most advantageously, the added reactor is of the "once through" type with partial removal of the reaction heat (non-adiabatic): the overall yield of the retrofitted plant may also be simultaneously enhanced in this way. Further aspects and advantages of the method according to the present invention will be better apparent from the following description of a non-limitative preferred embodiment thereof, given by way of illustration with reference to the attached drawings, in which: - Fig. 1 is a conventional schematic layout of a urea production plant including an ammonia stripping section according to the prior art: - Fig. 2 is a schematic layout representing a plant obtainable by retrofitting the plant shown in Fig. 1 in accordance with the present invention; and Fig. 3 is a schematic layout of the plant shown in Fig. 2 with a non-adiabatic "once through" reactor. In Fig. 1, wherein a plant according to the prior art is shown, R indicates a urea synthesis reactor, fed by conventional means 2, 3 with pure carbon dioxide and ammonia respectively, which is in fluid communication with an ammonia stripping section SS provided with a stripper S. In the stripper S a large part of the carbamate contained in the urea solution leaving the reactor R and part of the free ammonia present are stripped and recycled to the reactor, while a urea solution SU is obtained having a relatively low residue carbon dioxide content (5÷7% by weight), and a relatively high ammonia content (22÷25% by weight). The stripping section SS is in turn in fluid communication with a urea recovery section RE, including a medium pressure distillation stage SMP, operating at 18÷20 bar, a rectifying column CR and a low pressure distiller LP operating at about 4 bar. In the rectifying column CR, a highly pure ammonia stream NEP is separated from a carbamate solution SC. Pump means P, P' are respectively provided for feeding pure ammonia, obtained by mixing the ammonia stream NEP with a fresh stream NA, and for recycling the carbamate solution SC to a carbamate condenser CC and to the synthesis reactor R. The main technical characteristics of the isobaric ammonia stripping process implemented by the aforementioned plant can be summarized as follows: - synthesis pressure 140 - 150 bar - NH3/CO2 mol in the reactor 3.2÷3.4 - H20/CO2 mol in the reactor 0.6÷0.8 - temperature of the reactor 180 - 190°C - yield 62÷63% - steam consumption about 900 kg/MT urea The above mentioned values were quite consolidated and great improvements to the process appeared not to be possible. According to the present invention, the plant shown in Fig. 1 is retrofitted by: i) providing, upstream of the ammonia stripping section SS, a second urea synthesis reactor ROT of the "once through" type having a higher efficiency yield than the first urea synthesis reactor R; ii) connecting reactor ROT with the ammonia stnpping section SS by means of conduit means C and with means 4, 5 for feeding high purity ammonia and carbon dioxide respectively; iii) distributing the overall production capacity to apportion from 50 to 95% thereof to the first urea synthesis reactor R and from 5 to 50% to the second urea synthesis reactor ROT, and iv) reducing the production capacity of the pre-existing reactor R. The urea synthesis plant thus obtained is shown in Fig. 2. According to the present invention, the parallel reactor of the "once through" type ROT, which is connected upstream of the stripper S, may be a reactor of adiabatic type or with partial removal of the reaction heat. For the purpose of the present invention, the operating pressure and temperature of the "once through" reactor ROT, range from 230 to 270 bar and from 190 to 205°C respectively. In any event, in the preferred embodiment of this invention, the use of the "once through" reactor ROT with partial reaction heat removal results particularly suitable for the retrofitting of ammonia stripping plants. In Fig. 3 is shown a retrofitted urea plant, wherein the parallel reactor ROT comprises two sections: a "primary" section ROT.AC with reaction heat removal; a "secondary" section ROT.CC of conventional type. The ROT.AC section preferably comprises a reactor of the so-called "Kettle" type. In this regard, it should be noted that the use of a "Kettle" type urea synthesis reactor in the method of the present invention, affords the additional advantage of a notable reduction of investment costs, since this kind of reactor may be fed by the pre-existing ammonia pumps, having a maximum delivery pressure higher than the operating pressure of the reactor (260 bar against 240 bar). According to another aspect of this invention, it is possible to obtain, by distributing the load between the pre-existing reactor R and the added "once through" one ROT, an average conversion yield notably higher than that of the original plant. Most advantageously, it ensues a greater overloading margin for the key plant equipment, such as the stripper S, the carbamate condenser CC, the medium pressure distillation stage SMP, as well as a considerable "debottlenecking" (i.e. no modification of the key plant equipment) of the plant itself. In accordance with the present invention, the overall production capacity of the pre-existing plant is distributed so as to apportion from 50 to 95% thereof to the pre-existing urea synthesis reactor R and from 5 to 50% to the added urea synthesis reactor ROT. Most preferably, the production capacity apportioned to reactor R ranges from 55 to 65%, while the "once through" reactor ROT is apportioned with a corresponding production capacity of from 45 to 35%. In order to better illustrate the present invention, a non-limitative example of the retrofitting of a pre-existing 1500 MTD urea plant with ammonia stripping is given hereinbelow. EXAMPLE A urea production plant with ammonia stripping having a capacity of 1500 MTD and including a synthesis reactor R operating at 145 bar, a stripping section SS and a recovery section RE including medium pressure (SMP) and low pressure (LP) distillers operating at 18 and 4 bar respectively, was retrofitted so as to have a new capacity of 1500 x 1.5 = 2250 MTD urea. In order to reduce the thermal load of the pre-existing stripping section SS and recovery section RE (but excluding the vacuum section), the load between the two reactors R, ROT was distributed as follows: - Pre-existing reactor (R) 1350 MTD urea - added reactor (ROT) 900 MTD urea - TOTAL 2250 MTD urea The operating conditions of the reactors were: a) Before retrofitting Pre-existing reactor R: capacity 1500 MTD NH3/CO2 mol 3.6 H20/CO2 mol 0.68 Yield 62% P 145 bar T 190°C b) After retrofitting b.1 pre-existing Reactor R: Capacity 1350 MTD NH3/CO2 mol 3.6 H2O/CO2 mol 0.75 Yield 61 % P 145 bar T 190°C b.2. "once through" Reactor RC - Capacity 900 MTD NH3/CO2 mol 3.6 H2O/CO2 mol 0 Yield 75% P 242 bar T 193°C The weighed yield of the two reactors operating in parallel was: 1350 x 61 + 900 x 75 2250 =66.6% i.e. 4.6% higher than the yield of the plant before retrofitting. This involved a steam consumption decrease of about 100÷130 Kg/MT urea despite the capacity increase of the plant. Upon retrofitting, the pre-existing stripper S, the recovery section RE including the medium pressure stage SMP and the low pressure distiller LP, and the carbamate condenser CC, did not require any modification in order to be adequate to the increased production capacity.

Claims: A method of retrofitting a pre-existing plant for urea production according to a isobaric ammonia stripping process including a first urea synthesis reactor (R) in fluid communication with an ammonia stripping section (SS) for separating free ammonia and carbamate leaving the reactor from an aqueous urea solution (SU), the free ammonia and carbamate being recycled to said reactor (R), the stripping section (SS) is in turn in fluid communication with a urea recovery section (RE), including a medium pressure distillation stage (SMP), a rectifying column (CR) wherein highly pure ammonia stream (NEP) is separated from a carbamate solution (SC), the pre-existing plant also comprising pump means (P, P') for feeding pure ammonia, obtained by mixing the ammonia stream (NEP) separated from the carbamate solution (SC) with a fresh ammonia stream (NA), and for recycling the carbamate solution (SC) to a carbamate condenser (CC) and to the synthesis reactor (R), respectively, said method including the step of providing a second urea synthesis reactor (ROT) of the once-through type having a higher efficiency yield than said first urea synthesis reactor (R), characterized in that it further comprises the steps of: a) connecting said second reactor (ROT) to and upstream of said ammonia stripping section (SS) and with means (4, 5) for feeding high purity ammonia and carbon dioxide; b) distributing overall production capacity to apportion from 50 to 95% of said capacity to said first urea synthesis reactor (R) and from 5 to 50% to said second urea synthesis reactor (ROT); c) reducing the production capacity of the pre-existing reactor (R). A process according to claim 1, characterized in that urea synthesis in the first urea synthesis reactor (R) is carried out at a pressure of about 150 bar and at a temperature of about 190°C. A process according to claim 1, characterized in that urea synthesis in the second urea synthesis reactor (ROT) is carried out with a partial removal of reaction heat. A process according to claim 3, characterized in that the second urea synthesis reactor (ROT) comprises a primary section (ROT.AC) wherein reaction heat is removed in part and a secondary section (ROT.CC). A process according to claim 4, characterized in that said primary section (ROT.AC) comprises a Kettle-type reactor. A process according to claim 1, characterized in that urea synthesis in the second urea synthesis reactor (ROT) is carried out at a pressure of about 240 bar and at a temperature of from 190 to 195°C.

Inventors: PAGANI GIORGIO, ZARDI UMBERTO, PAGANI, GIORGIO, ZARDI, UMBERTO
Applicants: UREA CASALE SA, UREA CASALE S.A.
Application year: 1993
Main classification: C07C273
IPC codes: C07C273, B01J12