Automatic processing machine for silver halide photographic light-sensitive materials

Abstract: In an apparatus for processing a light-sensitive silver halide photographic material, there is provided a solid agent replenishing device to store a package in which a solid agent is packed, whereby the replenishing device releases the solid agent from the package so as to replenish the solid agents to the processing tank, whereby the opening coefficient of the processing tank being not larger than 12 cm 2 /l wherein the opening coefficient represents an air-containing area of the processing solution of the processing tank.

Description: The present invention relates to an apparatus for processing light-sensitive silver halide photographic materials, which is preferably used in an automatic processing machine for silver halide photographic light-sensitive materials, more specifically in a compact automatic processing machine offering markedly improved operability free of dissolving operation and remarkably improved chemical stability. Silver halide color photographic light-sensitive materials (hereinafter also referred to as light-sensitive materials or photographic materials) are processed in developing, desilvering, washing, stabilizing and other processes after exposure. Silver halide black-and-white photographic light-sensitive materials are developed and fixed after exposure. A black-and-white developer or a color developer, a bleacher or a bleach-fixer, a fixer, tap water or deionized water, a stabilizing solution and a dye stabilizer are used for development, desilvering, fixing, washing, waterless washing and dye stabilization, respectively. The liquids capable of performing these processes are called processing solutions. Each processing solution is usually kept at a temperature of 30 to 40°C, in which the light-sensitive material is immersed and processed. These processes are usually carried out by sequentially transporting the light-sensitive material through processing tanks containing the above processing solutions, using an automatic processing machine or another means. The automatic processing machine mentioned herein is generally a processing machine having a developing portion, a fixing portion, a desilvering portion, a washing or stabilizing portion and a drying portion, and a means for automatically sequentially transporting the photographic light-sensitive material to the processing tanks. In carrying out processing using such an automatic processing machine, the processing solution in each processing tank is supplemented with a processing agent to keep the activity of the processing solution in the processing tank constant. For this purpose, it is common to prepare a replenisher containing the processing agent dissolved therein. Specifically, processing is carried out while supplying the previously prepared replenisher from the replenisher tank to the processing tank as appropriate. In this case, it is the common practice to prepare the replenisher itself to be stored in the replenisher tank in a separate place, and in mini-labs etc., the replenisher is usually prepared in a given amount in a replenisher tank made within the processing machine at a time by manual dissolution or mixing dissolution using a mechanical mixer. The silver halide photographic light-sensitive material processing agent (hereinafter also referred to as photographic processing agent) is supplied in the form of powder or liquid; it is prepared as a solution in a given amount of water in the case of powder. In the case of liquid, it is prepared as a dilution in a given amount of water in the case of liquid, since it is supplied in a concentrated state. Replenisher tanks may be set by the automatic processing machine, requiring considerable space. Also, in recently-increasing mini-labs, replenisher tanks are housed in the automatic processing machine; in this case as well, sufficient space must be available for the replenisher tanks, each of which should contain at least 5 to 10 liter of replenisher. Any processing agent for replenishment is divided in some parts to ensure constantly good performance in photographic processing. For example, the color developer replenisher is divided in three or four parts, and the bleach-fixer replenisher for color photography is divided in two parts: a part of the oxidant ferric salt of organic acid and a part of the reducing agent thiosulfate. In preparing the replenisher, said dense part of ferric salt of organic acid and said dense part of thiosulfate are mixed together and diluted with a given amount of water before using. Said dense parts are placed in containers such as plastic containers, which containers are packed in outer packages, such as corrugated cardboard boxes, for one unit of commercial distribution. The processing agent for replenishment in a kit of part agents is dissolved, diluted, mixed and then diluted to a given volume before using. Said processing agent for replenishment has the following drawbacks: 'First, almost all conventional kits comprise dense aqueous solutions concentrated for improved operability, most of which are very dangerous because of high pH values of not more than 2.0 or not less than 12.0 in that they are harmful to the human body by skin contact etc. Also, many of them are strong oxidants or reducing agents, possessing very dangerous corrosivity in transport by ships or aircraft. The aqueous solution is subject to limitation as to solubility, being heavier and bulkier than in the case of solid. Since the concentrated solution is a dangerous article as stated above, its containers must be sufficiently tough to avoid destruction and spillage even if it is fallen; plastic container disposal poses a problem. Second, the part agents are separately contained in respective containers; some processing agents for replenishment comprise several bottles of part agents so that each unit of commercial distribution thereof involves a considerable number of containers, which requires much space for storage and transportation. For example, the color developer replenishing agent for CPK-2-20QA, a processing solution for color printing paper, is available in 10-liter units, wherein part A (a kit including a preservative), part B (a kit including a color developing agent) and part C (alkaline agent) are each contained in a 500-ml plastic container. Similarly, the bleach-fixer replenisher is available in 8-liter units, wherein three part agents are contained in respective bottles. The stabilizer replenisher is available in 10-liter units, wherein two part agents are contained in respective bottles. These replenishing agents are stored and transported in respective outer packages of various sizes. The outer package size ranges from about 17 × 14 × 16.5 cm for the stabilizer replenisher to about 18.5 × 30.5 × 22.5 cm for the bleach-fixer replenisher; it is not possible to pile packages of replenishers in storing or transporting them or in stocking them at dealer shops unless they are of the same kind, so that much space is required. The third drawback concerns with the problem of waste container disposal. In recent years, there has been strong demand for environmental conservation and saving resources mainly in Europe and the United States; in the photographic industry, plastic container disposal has been of major concern. Specifically, although plastic containers for photographic use are cheap, conveniently storable and transportable and excellent in chemical resistance, they pose problems of accumulation.in the environment because they are hardly biodegradable, and emission of large amounts of carbon dioxide upon burning, which contribute to global warming and acid rain. As for the problems posed on the user side, they include decrease in the available working area due to occupation of the narrow working space by crowding plastic containers, which are too tough to compress. The fourth drawback is poor chemical stability. Usually, the life time of a replenisher is at most 2 weeks even in the presence of a floating lid. However, with the trend toward replenishing rate reduction, it has recently been often the case where a 10-liter replenisher is used over a period of more than 1 month in a mini-lab receiving an order of 30 rolls of color films daily on average. In this case, the replenisher in the replenishing tank is often much more frequently in contact with air than the processing solution in the processing tank; often, replenishing has no effect due to replenisher deterioration. Accordingly, attempts have been made to reduce the replenishing tank capacity to 5 liter or reduce the replenishing kit unit to 5 liter. However, this approach involves another drawback of the necessity of additional packing material. For example, in preparing a color developer replenisher for color printing paper, a given volume of water is placed in the replenisher tank, after which dense kit A, which contains a preservative, is added, followed by stirring, and dense kit B, which contains a color developing agent, is then added, followed by stirring, and dense kit C, which contains an alkaline agent, is then added, followed by stirring, and finally water is added to make a given volume. This series of procedures is liable to be accompanied by some problems. For example, in case of insufficient stirring or a failure to add the starting water, the color developing agent tends to crystalize, and the resulting crystal can stay in the bellows pump and fail to be supplied so that the photographic performance becomes labile or the bellows pump breaks. Also, the dense kits are not always used immediately after production; they may be used even 1 year after production; in some cases, performance becomes labile due to oxidation of the color developing agent or preservative. The color developer replenisher prepared from dense kits or powder is also known to pose some problems in the replenisher tank. For example, if the replenisher remains unused for a long time, crystals can deposit on the inside wall of the replenisher tank, the replenisher becomes susceptible to oxidation, and tar forms. Under some storage conditions, other problems arise, including separation of easily-crystallizing components of the replenisher, such as the color developing agent, at low temperatures; some makers specify replenisher storage conditions and instruct the users to keep their replenishers under those conditions. As stated above, when a replenisher, e.g., a color developer replenisher for color printing paper, is prepared using a commonly used dense kit or powder, the above-mentioned problems arise; similar problems arise in the case of bleach-fixer, bleacher and fixer. For example, the bleach-fixer is characterized by considerably poor storage stability. This is because the bleach-fixer is usually of high acidity and considerably low pH for neutralizing the alkalinity of the dye fixer carried over by the printing paper being processed because the bleach-fixing process immediately follows the process with a color developer of high pH. It is said that at low pH values, any bleach-fixer comprising a thiosulfate and an oxidant is considerably poor in storage stability and cannot be replenished at low replenishing rates. The same applies to the fixer and stabilizer. Another problem is that the replenisher becomes increasingly dense in answer to the recent trend toward replenishing rate reduction and rapid processing; it has recently been a common practice to concentrate the replenisher to the limit of solubility. This deteriorates replenisher storage stability, thus posing many practical problems such as crystal separation. On the other hand, in addition to the above method of preparing a replenisher using a dense kit or powder, another method is known wherein a dense kit is added as such. In this method, supplying means such as a bellows pump are used to supply the dense kit as such directly to the processing tank and'a given volume of replenishing water is added independently, to improve the low efficiency in dissolving operation. This method really obviates solution preparing operation and is free of the problem of poor storage stability because no replenisher solution is prepared, in comparison with the above method, wherein the replenisher is prepared from a dense kit or powder. However, this method also involves many problems. The major problem is the increased size of the automatic processing machine because of the necessity for a dense kit tank for supplying the dense kit and a pump for supplying the dense kit. For example, in the case of CPK-2-20, a processing solution for color printing paper, the dense kit of color developer replenisher is divided in three parts; the dense kit of bleach-fixer replenisher, three parts; and the dense kit of stabilizer replenisher, two parts. To supply all these dense kits, eight tanks and eight pumps are required. In the conventional replenishing method, three tanks and three pumps are sufficient, since each replenisher requires one tank and one pump. In short, more tanks and more pumps than in the conventional method are required for supplying the dense kits, and a pump for water used to prepare the replenisher is also required. Also, since bellows pump precision is not so high, it is difficult to accurately discharge a plurality of solutions simultaneously, which can result in an imbalanced composition. Moreover, dense kits are difficult to maintain due to proneness to crystallization near the outlet of replenisher nozzle because they are dense solutions. Another problem is that the bellows pump is insufficient in supplying accuracy so that replenishing accuracy fluctuates widely in supplying a dense replenisher, resulting in very labile photographic performance. Still another problem is that the amount of waste plastic containers remains unchanged, in comparison with the conventional replenishing method, even when dense kits are supplied. The present invention is totally different from the inventions described above in that processing agent replenishment is achieved solely by adding a separately weighed solid processing agent to the processing tank and dissolve it therein, whereby previous replenisher dissolving operation is obviated to ensure maintenance-free operation; the present invention is never expected from the above invention. EP-A-0 537 365 is disclosing an automatic processing machine for a light sensitive silver halide photographic material. This automatic processing machine is comprising: a processing tank containing a processing solution; means for stocking a solid processing agent; means for supplying the solid processing agent to said processing tank; means for detecting information on the amount of processing of said light-sensitive silver halide photographic material; and means for controlling said supplying means according to said information on the amount of processing of said light-sensitive silver halide photographic material. Although the stable photographic characteristics obtained by this automatic processing machine are acceptable, the photographic characteristies have to be improved. In a conventional automatic processing machine, drive for a light-sensitive material transport means as well drive for a circulation pump for processing solutions and operation of a heater for a processing solution preparation tank have been stopped upon termination of passing of a light-sensitive material, namely a termination of development processing. Accordingly, in an automatic processing machine employing solid processing agents such as tablets, in particular, a period of time from the moment of replenishment of solid processing agents to the moment when operations of the light-sensitive material transport means and the circulation pump are stopped after termination of passing of a light-sensitive material, namely termination of processing is short, and thereby circulation of solutions tends to be stopped with unsolved processing solutions remaining in a processing solution preparation tank and in a processing tank. In that case, extremely high concentration portions are caused in the processing solution preparation tank and processing tank during the suspended circulation, and when such high concentration portions are circulated again in processing for the following light-sensitive material, they give remarkable concentration unevenness to processing solutions, adversely affecting light-sensitive materials in terms of photographic characteristics. Or, when a developing agent of the processing solution is paraphenylenediamine used for a color developing agent, chemical change such as oxidation tends to be caused on processing agents at the high concentration portions, and thereby, substances which are hardly dissolved in the following circulation started again are produced, reducing effective concentration of the processing solution, which is a problem. The object of the present invention is to provide an apparatus for processing light-sensitive silver halide photographic materials to be used in a compact automatic processing machine obviating the use of liquid chemicals the necessity of manual dissolving operation of chemicals and the necessity of liquid replenisher storage, offering improved processing stability, which does not require the use of plastic bottles for liquid chemicals. This object is solved in accordance with the present invention by an apparatus having the features of claim 1. Improvements of this apparatus are subject matter of the dependent claims. It has been found that the above object can be solved by an apparatus for an automatic processing machine for silver halide photographic light-sensitive materials having a processing tank for containing a processing solution for processing an exposed silver halide photographic light-sensitive material, a means for stocking a separately weighed solid processing agent and/or an immobilizing means for setting the package containing said processing agent, a means for supplying said separately weighed solid processing agent to said processing tank, a means for detecting information on the amount of processing of said silver halide photographic light-sensitive material, a means for controlling said supplying means according to said information on the amount of processing of said silver halide photographic light-sensitive material as detected by said detecting means to add said solid processing agent, wherein the opening coefficient of said processing tank (an air-contacting area of said processing solution of 1.0 l in said processing tank under a normal condition) is not larger tank 12 cm 2 /l. A limited numerical aperture of the processing tank that is 12 cm 2 /l and control of replenishing water in an automatic processing machine employing solid processing agents, are not known. The present inventors made extensive experiments concerning the direct addition of a solidified processing agent to a tank, and determined the optimum replenishing rate for each processing solution free of photographic performance fluctuation. Although this optimum replenishing rate was thought to depend on the size of the processing tank of the automatic processing machine, i.e., the volume of the processing solution, the inventors found that efficient use of a property of solid chemicals, i.e., practically low solubility, is advantageous that the concentration does not rise rapidly even if the chemical is added at a time, replenishing water can-be injected according to the dissolution, and very stable photographic performance is obtained. It was realized that dissolution before using is not an essential requirement. The amount of processing agent added at a time is preferably 0.1 to 50 g, more preferably 1 to 20 g for color developer, 5 to 50 g for fixer and bleach-fixer, 0.1 to 10 g for stabilizer, and 0.5 to 20 g for black-and-white developer. Even when a solid processing agent is added directly to the processing tank of an ordinary small-sized processing machine in this amount range and processing is carried out while dissolving gradually the solid processing agent, the photographic condition is not adversely affected. This is because the solid processing agent exhibits stable processing performance with its composition well balanced according to the amount of consumption while continuing the processing even when a large amount is added at a time because the solid processing agent dissolves gradually rather than rapidly, as stated above. It was found that photographic performance can also be kept constant by injecting replenishing water according to the dissolution. This is quite a surprising finding which has not been reported. Also, in the present invention, the solid processing agent is added directly-to the processing tank, wherein the processing solution is always kept almost constant at the processing temperature, i.e., dissolution speed is almost constant throughout the year, which makes it possible to obtain the desired preset balance of the addition of the solid processing agent and the composition. Another great advantage was found that the socalled non-dissolution phenomenon does hot occur as in dissolution in cold water. The non-dissolution phenomenon, named by the present inventors, is a solidifying phenomenon occurring upon addition of a solid processing agent to cold water at a time followed by slow or almost no stirring, resulting in vitrification of the solid processing agent. The solid processing agent, once vitrified, long remains undissolved even with vigorous stirring. In contrast, dissolution in warm water at the processing temperature for the automatic processing machine allows sequential dissolution of the solid processing agent even if it is added in large amounts at a time. The present inventors made further investigations based on these findings, and developed the present invention. In the present invention, it is preferable that a processing agent holding means which holds and/or fixes a processing agent package wherein a solid processing agent separately weighed in advance is moisture-proof-packaged and a feeding means which unpacks the processing agent package held and/or fixed by the processing agent holding means mentioned above'and feeds solid processing agents packaged in the processing agent package into the aforementioned processing tank are provided. In this way, it is possible to prevent, due to moisture-proof-package, that solid processing agents are deteriorated during the period from the moment they are loaded in an automatic processing machine to the moment they are replenished, and it is possible to make the automatic processing machine small because no moisture-proofing means is necessary to be provided in the automatic processing machine. It is desirable to provide a replenishing water supplying means, desirably under control by the photographic light-sensitive material processing amount detecting means necessary to control the addition of the solid processing agent. It should be emphasized, however, that the replenishing water is not for dissolving the solid processing agent, i.e., the solid processing agent and the replenishing water have totally reverse functions in that the former is for compensating the shortage of components consumed by processing, while the latter is for diluting the reaction inhibitory components dissolved upon processing to make photographic performance constant.. Traditionally, water has been used to dissolve chemicals. In contrast, in the present invention, as stated above, the primary purpose of the addition of replenishing water is to dilute the cumulative components dissolved upon reaction while compensating the water loss due to carry-over by the photographic material and evaporation via the tank surface. It is therefore preferable to control the replenishing water supplying means by the processing amount detecting means, since a sensor can be omitted, though it may be controlled separately from the addition of the solid processing agent. In the present invention, wherein a solid processing agent is added directly to the processing tank, water is therefore unnecessary merely for the purpose of preparing replenishers as in the prior art. This feature results in a major secondary effect of overflow volume reduction. Traditionally, because of the common idea that replenishing solutions must be prepared in advance, as dense replenishing solutions as possible have been used to compensate the shortage of components. Although it has been realized that replenishing rates can be reduced by increasing the solution concentration, whereby the volume of overflow waste liquid, which poses an environmental problem, can be reduced, this has been impossible due to the limitation of the solubility of processing chemicals. In the present invention, the processing chemicals do not become more dense than the tank solution concentration, there is no high concentration state exceeding the tank solution, and replenishment is necessary for desired processing chemicals only; therefore, even overflow-free replenishment is possible. However, as stated above, it is preferable to use replenishing water to lower the concentrations of accumulated reaction inhibitory components, particularly halide ions in the developer and silver ions in the fixer and bleach-fixer. This replenishing water serves to dilute these reaction inhibitory components and to separately compensate the water loss from each processing solution due to carry-over by the photographic material and evaporation via the tank surface, thus making a marked contribution to the improved processing stability of the present invention. Therefore, the controlling information used to supply replenishing water includes the amount (e.g., area) of processing of the photographic material, acting time, warming time, stopping time, installation site ambient temperature and relative humidity, and solid processing agent dissolution speed. Controlling the amount of replenishing water added based on these information parameters will make it possible to manage the chemical components in the processing tank in an ideal condition; this may be an epoch-making method of photographic processing management as viewed from the viewpoint of photographic performance. This is because conventional methods have a major problem in which the processing agent components become increasingly dense due to evaporation via each tank as the replenishing rate decreases. Generally, the most preferable for correction for evaporation loss is to dilute the replenisher and supply it in large amounts, but this has a drawback of environmentally undesirable increase in overflow waste. For this reason, the trend has.been toward lower replenishing rates. The use of replenisher to compensate the evaporation loss leads to its entry into the processing tank even in the absence of processing, resulting in an imbalanced composition. Thus, it has been a common practice to compensate the water loss by supplying water to reach the starting level every morning but this is merely the addition of water to the processing solution in the tank whose volume has decreased due to temperature change, rather than compensation of the water loss. due to evaporation with water, offering no real solution. Appropriate compensation for the water loss due to evaporation is to keep the component balance constant except for component change due to consumption by the photographic material, or to supply water according to the amount of water loss due to evaporation caused by the tank solution temperature and tank surface vapor pressure, irrespective of the presence or absence of processing. Accordingly, in the present invention, replenishing water is supplied for three purposes: 1) To dilute the accumulating harmful inhibitory components dissolving upon reaction in light-sensitive material processing to keep a constant concentration, 2) to dilute the undesirable chemicals carried over by the processed photographic material or by the previous solution, and 3) to compensate the water loss due to evaporation via the tank surface. Information required to accomplish these purposes is detected, based on which the preset water supplying means is controlled to perform the tasks. This is a new method made feasible by the present invention. This water replenishing means for the present invention proved to offer marked improvement in processing stability. In the present invention, the solid processing agent is separately weighed in a given amount, preferably a specified amount. This ensures very accurate replenishment in the automatic processing machine of the present invention, offering very stable continuous processing performance. The phrase "previously separately weighed" mentioned herein means that before charging the processing agent to the automatic processing machine of the invention or before setting the package containing the processing agent to the immobilizing means, the processing agent was separately weighed in a given amount, involving embodiments wherein tablets or pills of a given size are formed and embodiments where granules or powder is packaged in a given amount. However, the scope of the invention does not include the embodiments wherein powder or granules are placed in a stocking means and an amount corresponding to a single addition is weighed out upon supply. In the conventional replenisher supplying system, a bellows pump is used, but its precision is not constant so that it is unsuitable to precise control of replenishment. On the other hand, in the present invention, the solid processing agent is weighed in a specified amount at, for example, the factory where it is produced, and replenishment is controlled on an ON/OFF basis by determining whether the solid processing agent is added or not, thus involving no dispersion among replenishing operations. Processing agent supply accuracy is therefore markedly high, which is also conducive to stable processing performance. The solid processing agent of the present invention may take any form, including powder, granules, tablets and pills, and even mixtures thereof are acceptable. Also, the objects of the present invention can be accomplished even when using the solid processing agent in combination with liquid, as long as it is safe, such as water. Tablets and pills are preferred for separate weighing. In the case of powder, it is preferable to separately package it in an alkali-soluble film, plastic film or paper after separate weighing. Accordingly, tablets and pills permit supply in accurately separately weighed portions, and powder and granules are separately weighed and separately packaged, whereby the solid processing agent of the present invention is completed. Tablets and pills can be given moisture resistance by coating with a water-soluble moisture-resistant polymer or by using a moisture-resistant packaging material. Powder and granules can be given moisture resistance by using a moisture-resistant packaging material. The scope of solid processing agent mentioned herein includes powdery processing agents and solid processing agents in the form of tablets, pills, granules and others, which may be subjected to a moisture resistance treatment as necessary. Pasty or slurry processing agents are in the form of semiliquid and poor in storage stability, and those of any shape subject to legal regulation because of danger in transport are not included in the scope of the solid processing agent of the present invention. The powder for the present invention is defined as an aggregate of microcrystals. The granule for the present invention is defined as a particle having a grain size of 50 to 5000 µm, prepared by powder granulation. The tablet for the present invention are defined to be formed by compressing a powder or granule into a given shape. With regard to factors for fluctuation of photographic characteristics, it is effective that a solution numerical aperture of a color developing solution in an automatic processing machine is made small. It was found that when an aperture area is not more than 12 cm 2 /l, in particular, fluctuation of photographic characteristics can be improved remarkably only in the structure of the invention. When the numerical aperture exceeds 12 cm 2 /l, undissolved solid processing agents and thick solution immediately after dissolution are subject to air oxidation, resulting in generation of undissolved substances and scum which cause a problem of contaminating an automatic processing machine or a light-sensitive material to be processed. When the numerical aperture is not more than 12 cm 2 /l, however, the problems mentioned above can be solved. The numerical aperture as defined here is represented by an area of contact between a unit volume of a processing solution and air. Its unit is represented by cm 2 /l. In the invention, the numerical aperture is not more than 12 cm 2 /.l and that ranging within 2 to 10 cm 2 /l is more preferable. The most preferable is 3 to 5 cm 2 /l. It is possible to make the numerical aperture small generally by using a floating lid made of resin or the like which intercepts air, or by using a developing unit of a slit type described in JP-A-131138/1988, JP-A-216050/1988 and JP-A-235940/1988. Further, in the automatic processing machine of the invention, even when a transport means for a light-sensitive material stops running after completion of development processing of the light-sensitive material, a pump is driven to continue working for circulation of a processing solution for a predetermined period of time from the stop of the transport means. Therefore, when circulation of the processing solution is stopped after the predetermined period of time for the pump to continue operating which is set to be short as far as possible but is sufficient for replenished processing agents to be dissolved, no undissolved processing agents remain in a tank for preparing processing solution, resulting in neither clogging of a filter section nor deterioration of a processing solution, realizing stable processing and less requirement of electric power. The period of time of 2 hours for the pump to continue working after an end of development processing is preferable, and more preferable is that of 10 minutes to 70 minutes wherein a range of 15 minutes to 50 minutes is especially preferable. When this period of time is too long, it causes deterioration of a processing solution, while, when it is too short, solid processing agents are not dissolved sufficiently. Therefore, the ranges mentioned above are preferable. Furthermore it should be mentioned the following features, namely that the oxygen permeable rate of a packaging material of the package of the solid agent is not higher than 50 ml/m 2 •24hr •1atm, particularly not higher than 10 ml/m 2 •24hr•1atm. Furthermore the water replenishing means includes a replenishing water tank and mold-prevention means which is one of chelating agent adding means, mold-prevention agent adding means, deionizing processing means, ultraviolet ray irradiating means, magnetic processing means, ultrasonic processing means, electrolytic sterilization means, silver ion dicharging means and air foaming means. Furthermore circulation means are provided to continue the circulation of the processing solution for a predetermined time period after the processing for the photographic material has been completed. Additionally a heater is provided to heat the processing solution so as to maintain the temperature of the processing solution within a predetermined range while the circulating means is continuing the circulation. In the drawings examples of the apparatus of the present invention are shown, wherein Figure 1 is a schematic diagram of a printer processor in which an automatic processing machine and a photographic printer are unified. Figure 2 is a cross-sectional view of the processing agent receiving portion and processing agent supplying means for an automatic processing machine. Figure 3 is a cross-sectional view of the processing agent receiving portion, processing agent supplying means and replenishing water supplying means for an automatic processing machine. Figure 4 is a plan of the automatic processing machine A described above. Figure 5 is a block diagram showing the control means for an automatic processing machine, and Figure 6 is a block diagram showing the control means with a dissolution table of an automatic processing machine. In the drawings an example of an automatic processing machine to which the present invention is applicable is shown and is described by means of the drawings, wherein Figure 1 is a schematic diagram of a printer processor in which an automatic processing machine and a photographic printer are unified. In Figure 1, in the lower left of the photographic printer B is set a magazine M housing a roll of printing paper which is an unexposed silver halide photographic light-sensitive material. The printing paper drawn from the magazine is cut into a sheet of printing paper of given size via roller R and cutter portion C. This sheet of printing paper is transported by transporting belt B' to exposure portion E, where it is subjected to exposure for original image O. The thus-exposed sheet of printing paper is further transported by a number of pairs of feed rollers R to the automatic processing machine A. In the automatic processing machine A, the sheet of printing paper is sequentially transported through color developing tank 1A, bleach-fixing tank 1B and stabilizing tanks 1C, 1D and 1E (comprising substantially three tanks) by a transporting roller (no reference symbol given), where it is subjected to color development, bleach-fixation and stabilization, respectively. The sheet of printing paper thus processed is dried at a drying portion 35 and then discharged out of the automatic processing machine. In Figure 1, the dashed line indicates the transportation path for silver halide photographic light-sensitive material. Also, although the light-sensitive material is introduced to automatic processing machine A in cut form in this example, it may be introduced to the automatic processing machine in band form. In such a case, processing efficiency can be improved by providing an accumulator for transient retention of the light-sensitive material between the automatic processing machine A and the photographic printer B. Also, the automatic processing machine relating to the present invention may be unified with photographic printer B or may stand alone. The silver halide photographic light-sensitive material processed by the automatic processing machine relating to the present invention is not limited to exposed printing paper; it may be an exposed negative film or the like. Although the following description of the present invention concerns with an automatic processing machine which comprises substantially three tanks, namely a color developing tank, a bleach-fixing tank and a stabilizing tank, it is not to be construed as limitative; the invention is applicable to automatic processing machines which comprise substantially four tanks, namely a color developing tank, a bleaching tank, a fixing tank and a stabilizing tank. The invention may also be applied to an automatic processing machine wherein a developing tank, a bleaching tank, a bleach-fixing tank and a stabilizing tank are provided in the order of processing a light-sensitive material. Further, the invention may be applied also to an automatic processing machine wherein a developing tank and a fixing tank are provided in the order of processing a light-sensitive material. Even in the aforementioned cases, each processing tank is structured as indicated below. Figure 2 is a schematic diagram of color developing tank 1A of automatic processing machine A of Figure 1, as viewed on the I-I cross-section thereof. Bleach-fixing tank 1B and stabilizing tanks 1C, 1D and 1E are of the same configuration as color developing tank 1A; processing tank 1 mentioned hereinafter means any of color developing tank 1A, bleach-fixing tank 1B and stabilizing tanks 1C, 1D and 1E. In the figure, light-sensitive material transporting means etc. are not illustrated for simple representation. Also, the present example concerns with the use of tablet 13 as a solid processing agent. Processing tank 1 has a processing portion 2 for processing a light-sensitive material and a solid processing agent receiving portion 11 which is unified outside the separating wall of said processing portion 2 and to which tablets 13 are supplied. Processing portion 2 and solid processing agent receiving portion 11 are mutually separated by separating wall 12 having a communicating window, which allows passage of the processing solution. Because receiving portion 11 has processing agent receiving section 14 formed therein, the processing agent never moves to processing portion 2 while remaining solid. Cylindrical filter 3, provided under solid processing agent receiving portion 11 in an exchangeable state, functions to remove insoluble substances, such as paper rubbish, from the processing solution. The inside of filter 3 communicates to the aspiration side of a circulatory pump 5 (means for circulation) via circulatory pipe 4 set through the lower wall of solid processing agent receiving portion 11. The circulatory system is configured with circulatory pipe 4 forming a solution circulating path, circulatory pump 5, processing tank 1 and other elements. The other end of circulatory pipe 4 communicating to the discharge side of circulatory pump 5 passes through the lower wall of processing portion 2 and communicates to said processing portion 2. By this configuration, upon activation of circulatory pump 5, the processing solution is aspirated via solid processing agent receiving portion 11 and discharged to processing portion 2, where it is mixed with the processing solution in processing portion 2 and then returns to solid processing agent receiving portion 11; this circulation is repeated in cycles. The flow rate of this circulatory flow is preferably 0.5 to 2.0 rotations (1 rotation = circulatory volume/tank capacity), more preferably 0.8 to 2.0 rotations per minute and further preferably 1.0 to 2.0 rotations. Also, the direction of circulation of the processing solution is not limited to the direction shown in Figure 2; it may be opposite. Waste liquid discharge pipe 6, which is for overflowing the processing solution in processing portion 2, serves not only to keep the liquid level constant but also to prevent retention and concentration of the components carried over with the light-sensitive material from the processing solution in the processing portion and the components oozing out from the light-sensitive material. Bar heater 7 is arranged in such manner that it passes through the upper wall of solid processing agent receiving portion 11 and is immersed in the processing solution in solid processing agent receiving portion 11. This heater 7 is for heating the processing solution in processing tank 1, i.e., it is a temperature controlling means for retaining the processing solution in processing tank 1 in an appropriate temperature range (e.g., from 20 to 55°C). Processing amount information detecting means 8, provided at the inlet of the automatic processing machine, is used to detect information on the amount of processing of the light-sensitive material. This processing amount information detecting means 8 comprises a plurality of left-right arranged detecting elements and functions to detect the width of the light-sensitive material and count the detection time. Because the transportation rate of the light-sensitive material is pre-set mechanically, the area of light-sensitive material processed can be calculated from information on the width and the time. This processing amount information detecting means may be any one, as long as it is capable of detecting the width and transportation time of light-sensitive material. Examples of such processing amount information detecting means include an infrared sensor, a microswitch and an ultrasonic sensor. In the case of the printer processor of Figure 1, the processing amount information detecting means may be such that the area of light-sensitive material processed is indirectly detected, e.g., the amount of light-sensitive material printed, or the number of pre-set area of light-sensitive material units processed may be detected. Detection timing, which is before processing in the present example, may be after processing or during immersion in the processing solution (these can be achieved by properly changing the position of processing amount information detecting means 8 to another position allowing information detection after or during processing). The information detected is not limited to the area of light-sensitive material processed as in the above description; any information can serve for the purpose, as long as it is a value in proportion to the amount of light-sensitive material which is to be processed, which was processed or which is being processed; it may be the concentration of the processing solution in the processing tank or the change therein. Processing amount information detecting means 8 need not always be provided for each of processing tanks 1A, 1B, 1C, 1D and 1E; it is preferable to provide one processing amount information detecting means 8 for each automatic processing tank. Processing agent supplying means 17 for adding the solid processing agent, stocked in cartridge 15, to the processing tank, arranged above filtering portion (section) 14 described below, has cartridge 15 containing tablet 13 (solid processing agent), and pusher 10 for pushing out one or more pieces of tablet 13. This processing agent supplying means 17 is controlled by processing agent supply controlling means 9 described later, and upon supplying signal reception from processing agent supply controlling means 9, it pushes out waiting tablet 13 by means of pusher 10 to filtering portion (section) 14 in solid processing agent receiving portion 11. In the present invention, solid processing agent 13 is supplied to filtering portion (section) 14 in solid processing agent receiving portion 11, but it may be supplied to any portion in processing tank 1. In other words, with respect to the position to which the solid processing agent is added, the present invention requires merely the capability of dissolving the solid processing agent using the processing solution; it is necessary to add the components according to the information on the amount of processing of light-sensitive material and keep the processing performance of the processing solution in processing tank 1 constant. More preferably, the solid processing agent is supplied to the circulatory path for the processing solution. Preferably, this processing agent supplying means 17 is arranged to avoid contact of the solid processing agent before being supplied to the processing tank with moisture in the processing tank of the automatic processing machine, atmospheric moisture and the spilled processing solution. Filtering means (section) 14, immersed in the processing solution in solid processing agent receiving portion 11, removes the substances which originate from tablet 13 and other types of solid processing agent and which can cause flaws in the finished image, poor processing in the portion to which they adhere, and other undesirable things, if they adhere to the light-sensitive material, such as insoluble substances from tablet 13 supplied by processing agent supplying means 17, e.g., insoluble contaminants in tablet 13, and lumps of tablet 13 resulting from its disintegration. This filtering means (section) 14 is coated with resin. The filtering portion need not always be provided in solid processing agent receiving portion 11; it may be provided at any position, as long as tablet 13 supplied by processing agent supplying means 17 does not enter the light-sensitive material transporting path illustrated in Figure 1 or the processing solution in processing portion 2. Processing agent supply controlling means 9 controls processing agent supplying means 17; when the information on the amount of processing of light-sensitive material (processing area, in the present example), as detected by processing amount information detecting means 8, reaches a given level, it passes a processing agent supplying signal 16 to processing agent supplying means 17. Processing agent supply controlling means 9 controls processing agent supplying means 17 so that the required amount of processing agent according to the information on the amount of light-sensitive material processed is supplied to solid processing agent receiving portion 11. Next, the action of the present invention is described by means of Figure 2. With respect to the exposed light-sensitive material, information on the amount of processing is detected by processing amount information detecting means 8 at the inlet of automatic processing machine A. Upon reach of the integrated area of light-sensitive material processed to a given level, processing agent supply controlling means 9 passes a supplying signal to processing agent supplying means 17 according to the information on the amount of processing detected by processing amount information detecting means 8. Upon supplying signal reception, processing agent supplying means 17 pushes out and supplies tablet 13 by means of pusher 10 to filtering portion (section) 14 in solid processing agent receiving portion 11. Tablet 13 thus supplied is dissolved in the processing solution in solid processing agent receiving portion 11, wherein its dissolution is facilitated by the processing solution being circulated by a means for circulation in the cycle of solid processing agent receiving portion 11 → circulatory pump 5 → processing portion 2 → communicating window → solid processing agent receiving portion 11. The detected light-sensitive material is sequentially transported by a transporting roller through color developing tank 1A, bleach-fixing tank 1B and stabilizing tanks 1C, 1D and 1E (see automatic processing machine A in Figure 1). Here, carry-over time during which a light-sensitive material emerges from a processing solution in a processing tank and enters a processing solution in the following processing tank is normally 5 seconds or less and preferably 1 second or less. Color developing tank 1A, bleach-fixing tank 1B and stabilizing tanks 1C, 1D and 1E may be equipped with processing agent supplying means 17A, 17B, 17C, 17D and 17E, respectively, for simultaneously supplying the processing agent thereto. Supplying timing may be different among these supplying means. The given area based on which the processing agent supplying means is controlled by processing agent supply controlling means 9 may be constant among processing tanks 1A, 1B, 1C, 1D and 1E or not. Another embodiment of the present invention is described below. Bleach-fixing tank 1B and stabilizing tanks 1C, 1D and 1E are of the same configuration as color developing tank 1A; processing tank 1 mentioned hereinafter means any of color developing tank 1A, bleach-fixing tank 1B and stabilizing tanks 1C, 1D and 1E. Since the same numbers as in Figure 2 are used for corresponding components having the same function, they are not described here. Also, light-sensitive material transporting means etc. are not illustrated for simple representation. In this example, a filtering means has been mentioned as a preferred example, the desired effect of the present invention can be sufficiently obtained even in the absence of such a filtering means. As stated above, the present invention is excellently effective in that a compact automatic processing machine is realized because replenisher tanks are unnecessary, which are necessary for conventional automatic processing machines, and hence no space therefor is required, that solution preparing operation is unnecessary because a solid processing agent is supplied to the processing tank so that there is no fear of solution spillage or adhesion to, and contamination of, the human body, clothing and peripheral equipment during solution preparation, and handling is easy, and that processing solution replenishing accuracy improves so that stable processing performance is obtained without deterioration of the processing agent replenisher components. As another embodiment of the present invention. Figure 3 shows a schematic diagram of color developing tank 1A of automatic processing machine A of Figure 1, as viewed on the I-I cross-section. Figure 4 is a schematic diagram of automatic processing machine A of Figure 1, as viewed from above (for the sake of explanation, the path for the replenishing water supplying means is illustrated). Figure 5 is a block diagram of the control relating to this example. Figure 6 is a block diagram of a combination of the controlling means and a programmed evaporated water replenishing setting means 23. Figures 3 and 4 illustrate replenishing water tank 43 for storing replenishing water. In this example, tablet 13 is used as a solid processing agent. With respect to Figures 3 and 4, the parts different from Figure 2 are first described below. Replenishing water supplying means 42 is for supplying replenishing water from replenishing water tank 43 for storing replenishing water to processing agent receiving portion 11, having warm water supplying apparatus 32, which comprises a pump, a temperature controller, etc., electromagnetic valve 33 and replenishing water supplying pipe 36. This replenishing water supplying means 42 serves to dilute the accumulated inhibitory components which dissolve upon reaction while compensating the water loss due to carry-over by the photographic material and evaporation via the tank surface. Although processing tanks 1A, 1B, 1C, 1D and 1E may be each 'provided with a water replenishing tank and a water replenishing pump, size reduction in the automatic processing machine is possible when the same replenishing water is used for all tanks, i.e., a single water replenishing tank alone is used. It is more preferable to arrange only one water replenishing tank and one water replenishing pump and provide an electromagnetic valve in the water replenishing path (pipe etc.) so that the required amount is supplied to each processing tank where necessary, or adjust the diameter of the water replenishing pipe to regulate the replenishing rate, whereby further size reduction is realized with only one water replenishing tank and only one water replenishing pump provided in the automatic processing machine. With respect to stabilizing tanks 1C and 1D, it is possible to remove the replenishing water supplying means by supplying the stabilizer overflow from stabilizing tanks 1D and 1E, respectively. It is also preferable to warm the replenishing water in the water replenishing tank. Waters for this replenishment include not only ordinary waters such as well water and tap water but also those containing fungicides such as isothiazoline and chlorine-releasing compounds, a small amount of sulfite chelating agent, and ammonia or inorganic salt, as long as it does not affect photographic performance. This replenishing water supply control means controls the replenishing water supplying means 42 by programmed evaporated water replenishing setting means 23 and/or controls the replenishing water supplying means 42 according to the information on the amount of processing detected by processing amount information detecting means 8. The base of control by this replenishing water supply control means is not confined to the information on the amount of processing detected by processing amount information detecting means 8; it may be the information of supply of the processing agent by processing agent supplying means 17. The parts of Figure 3 different from Figure 2, other than those described above, whose function etc. are the same as in Figure 2, are described below. Heater 7, arranged in the bottom portion of processing portion 2, heats the processing solution in processing portion 2, i.e., it is a means for temperature control for retaining the processing solutions in processing portion 2 and solid processing agent receiving portion 11 in an appropriate temperature range (e.g., from 20 to 55°C). As means for circulation, circulatory pipe 4 and circulatory pump 5 are provided in the same manner as in Figure 2, but the direction of processing solution circulation is opposite, i.e., the processing solution is circulated in the cycle of processing portion 2 → circulatory pump 5 → solid processing agent receiving portion 11 → communicating window → processing portion 2. Processing agent supplying means 17 supplies solidified processing agent 13, enclosed in cartridge 15, to filtering means (section) 14 in solid processing agent receiving portion 11 by means of pusher claw 18. It is different from Figure 2 in that cum 19 is driven by an axial rotation stopping mechanism to activate pusher claw 18, whereby waiting tablet 13 is supplied to processing tank 1, while the next tablet 13 quickly becomes in a waiting state since it is under pressure exerted by tablet pushing spring 21 from above to below. Processing agent supplying means 17 may also be based on the side or upward method; it may be any one, as long as it is capable of adding the solid processing agent to processing tank 1. Next, the action of the present invention is described by means of Figures 1, 3, 4 and 5. With respect to the exposed light-sensitive material, information on the amount of processing is detected by processing amount information detecting means 8 at the inlet of automatic processing machine A. Processing agent supply controlling means 9 sends a supplying signal to processing agent supplying means 17 according to the information on the amount of processing detected by processing amount information detecting means 8 upon reach of the integral area of light-sensitive material processed to the preset level. Upon supplying signal reception, processing agent supplying means 17 pushes out and supplies tablet 13 by means of pusher 10 to filtering portion (section) 14 in solid processing agent receiving portion 11. Tablet 13 thus supplied is dissolved in the processing solution in solid processing agent receiving portion 11, wherein its dissolution is facilitated by the processing solution being circulated by the means for circulation in the cycle of processing portion 2 → circulatory pump 5 → solid processing agent receiving portion 11 → communicating window → processing portion 2. On the other hand, the replenishing water supplying means passes a water replenishing signal to replenishing water supplying means 42 (warm water supplying apparatus 32 and electromagnetic valve 33) according to the information on the amount of processing detected by processing amount information detecting means 8 upon reach of the integral area of light-sensitive material processed to the preset level. Upon water replenishing signal reception, replenishing water supplying means 42 controls warm water supplying apparatus 32 and electromagnetic valve 33 to supply a given or required amount of replenishing water, stored in replenishing water tank 43, to each or an appropriate processing tank. In this case, the given area is equal to that for processing agent supply controlling means 9, but this is not limitative; the given areas may be different from each other. The detected light-sensitive material is sequentially transported through color developing tank 1A, bleach-fixing tank 1B and stabilizing tanks 1C, 1D and 1E by means of a transporting roller. A control unit stops circulation of processing solutions in color developing tank 3 and others after the predetermined period of time from the moment when the control unit stops pressure-contact transport rollers. As the predetermined period of time, there is adopted a fixed period of time during which processing agents replenished simultaneously in processing solutions can be dissolved completely, or a time period that varies corresponding to replenishing time for the processing agent to be replenished last so that a time period from the last replenishment of processing agents to the stop of circulation of processing solutions may be the same as that during which processing agents replenished simultaneously can be dissolved completely. Owing to this, it can be avoided that circulation of processing solutions is stopped before replenished processing agents are dissolved completely. An automatic processing machine equipped with various kinds of processing tanks has been described above. It should be noted, however, that an automatic processing machine for color negative films equipped with a developer tank, a bleacher tank, a bleach-fixer tank, a fixer tank and a stabilizer tank wherein at least the above stocking means and/or immobilizing means, the above supplying means and the above controlling means are provided for each of the above processing tanks, and an automatic processing machine for black-and-white silver halide photographic light-sensitive materials equipped with a developer tank and a fixer tank wherein at least the above stocking means and/or immobilizing means, the above supplying means and the above controlling means are provided for each of the above processing tanks, proved to have the effect of the present invention.

Claims: Apparatus for processing light-sensitive silver halide photographic materials, comprising: a processing tank (1; 1A to 1E) for containing a processing solution to process the photographic material, the opening coefficient of the processing tank being not larger than 12 cm 2 /l, wherein the opening coefficient represents an air-contacting area per 1,0 liter of the processing solution of the processing tank; solid agent replenishing means (15) for storing a solid agent (13) and replenishing solid agent to the processing tank; detection means (8) for detecting the amount of the processed photographic materials; and control means (9) for controlling the solid agent replenishing means so as to replenish the solid agent in accordance with the detected amount of the processed photographic material. The apparatus of claim 1, wherein the amount of the solid agent (13) supplied at one time is 0,1 to 50 g. The apparatus of claim 1 or 2, wherein the solid agent is granules produced by a granulating process or tablets (13) produced by a tablet-making process. The apparatus of one of claims 1 to 3, wherein the processing tank (1) includes a processing section (2), a solid agent receiving section (11) communicating with the processing section, and circulating means (5) for circulating the processing solution between the processing section (2) and the solid agent receiving section (11). The apparatus of claim 4, wherein the processing tank (1; 1A to 1 E) further includes a separation means (3) for separating between the processing section (2) and the solid agent receiving section (11) so that insoluble components of the solid agent (13) are prevented from entering into the processing section. The apparatus of claim 5, wherein the separation means (3) is a filter. The apparatus of one of claims 1 to 3, wherein the processing section (2) includes a developing tank (1A) a bleaching tank (1B), a fixing tank (1 C) and a stabilizing tank (1D, 1E), and each of the tanks is provided with the solid agent replenishing means (17; 17A to 17E) and the control means (9). The apparatus of one of claims 1 to 3, wherein the processing section (2) includes a developing tank (1A), a bleach-fixing tank (1 B), and a stabilizing tank (1C, 1D, 1E), and each of the tanks is provided with the solid agent replenishing means (17; 17A to 17E) and the control means (9). The apparatus of claim 7 or 8, wherein the opening coefficient of the developing tank (1; 1A to 1E) is not larger than 12 cm 2 /l.

Inventors: ISHII HIDEO, ISHIKAWA MASAO, KOBOSHI SHIGEHARU, KOMATSU YOSHIMASA, MIYAZAWA YORIKATSU, OHKUBO HITOSHI, SAITO KANEO, SHIBAZAKI OSAMU, TSUBAKI YOSHIFUMI, YOSHIMOTO HIROSHI, ISHII, HIDEO, ISHIKAWA, MASAO, KOBOSHI, SHIGEHARU, KOMATSU, YOSHIMASA, MIYAZAWA, YORIKATSU, OHKUBO, HITOSHI, SAITO, KANEO, SHIBAZAKI, OSAMU, TSUBAKI, YOSHIFUMI, YOSHIMOTO, HIROSHI
Applicants: KONISHIROKU PHOTO IND, KONICA CORPORATION
Application year: 1993
Main classification: G03D3
IPC codes: G03C5, G03D3