IRON POWDER AND MIXED POWDER FOR POWDER METALLURGY AND PRODUCTION OF IRON POWDER

Abstract: An iron powder and mixed powder for powder metallurgy as raw materials for producing sintered mechanical components by adding Cu powder and graphite powder to iron powder and rolling and sintering the mixture, 0.008 to 0.5 wt.% of at least one kind of element selected from elements having a value of oxide standard formation free energy of not greater than 120 kcal/mol o₂ at 1,000 °C is contained in the iron powder and not less than 20 % of the element(s) consists of an oxide, while 0.01 to 0.20 wt.% of at least one kind of oxide powder of an element having a value of oxide standard formation free energy of not greater than -120 kcal/mol o₂ at 1,000 °C is blended in the mixed powder. In this way, diffusion of C (carbon) from graphite added into iron powder particles is restricted at the time of sintering, and dimensional change accuracy of the sintered product is improved.

Description: TECHNICAL FIELD Iron powder used for powder metallurgy is roughly divided into two kinds of pure iron powder and alloying steel powder. This invention relates to iron powder and mixed powder for powder metallurgy belonging to the above former pure iron powder as well as a method of producing such iron powder. BACKGROUND ART The iron powder for powder metallurgy uses in the production of a sintered part having usually a density of 5.0-7.2 g/cm 3 by adding and mixing iron powder with Cu powder, graphite powder and the like, shaping into a green compact in a mold, sintering and, if necessary, sizing a sintered body for dimensional correction. However, the sintered body produced by adding Cu powder, graphite powder or the like to the iron powder is high in the strength, so that it has a drawback that the dimensional correction can not be conducted to a satisfactory extent due to spring-back of the sintered body even if the sizing for dimensional correction is conducted. As a method of ensuring a desired dimensional accuracy without sizing, therefore, JP-B-56-12304 proposes a technique of enhancing the accuracy of dimensional change by improving particle size distribution of starting powder, and JP-A-3-142342 proposes a technique of controlling a given size by predicting the dimensional change at the sintering from the shape of powder. However, the iron powder for powder metallurgy is added with Cu powder, graphite powder, lubricant and the like, or mixed for the uniformization of properties in the steps from powder formation to the shaping, or further transferred for replacement with a new vessel, so that the properties such as particle size distribution, shape and the like are apt to be changed at these steps and also the position change of ingredient due to segregation of Cu powder or graphite powder added occurs and consequently the dimensional accuracy can not necessarily be obtained to a satisfactory extent. DISCLOSURE OF INVENTION The invention is to advantageously solve the above problems and to provide iron powder and mixed powder for powder metallurgy capable of providing a dense sintered body with a high accuracy by enhancing an accuracy of dimensional change in the sintering (concretely green density: about 6.90 g/cm 3 , scattering width of dimensional change: within 0.10%, preferably 0.06%) without impairing compressibility as well as a method of advantageously producing such iron powder. The inventors have made various studies with respect to the composition of iron powder and the compounding ratio of additives in order to achieve the above object and found the following knowledges: (1) The dimensional change in the sintered body is strongly correlated to amount and particle size of graphite added to iron powder; (2) Even when the amount and particle size of graphite change, if an oxide of a particular element is existent on surface of iron powder at a constant quantity or more, the scattering width of dimensional change or the fluctuating width of dimensional change reduces; and (3) As the scattering width of the oxide quantity becomes small, the fluctuating width of dimensional change is small. The invention is defined in the claims 1, 6 and 8. Preferred embodiments are defined in claim 2-5, 7 and 9. The invention is based on the above knowledges. The invention will now be described in terms of the inventors' experimental findings. The inventors have found that the rate of dimensional change in the sintered body strongly correlates with the amount and particle size of the graphite added, and particularly, the scattering width of the dimensional change (i.e. the fluctuating width of the dimensional change) tends to become large as the amount of graphite becomes large. However, it is occasionally confirmed that the fluctuating width of dimensional change becomes small even though the amount of graphite added is large. As a result of investigations on such a cause that the fluctuating width of dimensional change is small even if the amount of graphite added is large, it has been confirmed that this is due to the fact that a relatively large amount of oxide is existent on surface of iron powder. However, when the oxide is existent on the surface of iron powder, the fluctuating width of dimensional change becomes not necessarily small. Then, there has been considered a common point that each oxide could control the fluctuating width of dimensional change to a small extent. As a result, it has been elucidated that a good result is obtained when using all of elements each having a value of standard free energy of formation of oxide at 1000°C of not more than -120 kcal/l mol of O 2 . In Table 1 are shown a value of standard free energy of formation of oxide at 1000°C of each element, a composition of the resulting oxide, and a judgment on accuracy of dimensional change when each oxide is formed on surface of iron powder (oxide quantity: 0.1-0.2 wt%). Element Standard free energy of formation of oxide at 1000°C (Kcal/l mol of O 2 ) Oxide Judgment Cu -37 Cu 2 O X Ni -57 NiO X Cr -126 Cr 2 O 3 ○ Mn -140 MnO ○ V -148 V 2 O 3 ○ Si -156 SiO 2 ○ Ti -165 TiO 2 ○ Al -203 Al 2 O 3 ○ ○ ... Fluctuating width dimensional change: slight X ... Fluctuating width of dimensional change: large As seen from Table 1, good accuracy of dimensional change is obtained when an oxide is made from an element having a value of standard free energy of formation of oxide at 1000°C of not more than - 120 kcal/l mol of O 2 . Although the reason why the accuracy of dimensional change is improved by existing the above oxide on the surface of iron powder is not yet clear, it is considered as follows. Namely, when the aforementioned oxide exists on the surface of iron powder to a certain extent, the diffusion of C (carbon) from graphite added to particles of iron powder during the sintering is controlled and hence the amount of C invaded and diffused into iron powder is held at an approximately constant value even if the amount and particle size of graphite added change, whereby a so-called Cu growth is stabilized to finally control the fluctuating width of dimensional change to a small range as compared with the fluctuating width of the amount of graphite added. The above state is illustrated as shown in Fig. 1. That is, when using the conventional iron powder existing no oxide on its surface, as shown by a curved line 1 ○ in the above figure, the quantity of dimensional change largely varies with the change of C amount, while when an adequate quantity of oxide is existed on the surface of iron powder, as shown by a curved line 2 ○, the inclination of the curved line becomes small, so that even if the C amount changes, the quantity of dimensional change is not so varied. Even when the amount of graphite added varies as mentioned above, in order to effectively reduce the rate of dimensional change, it is necessary that 0.008-0.5 wt% of an element having a value of standard free energy of formation of oxide at 1000°C of not more than -120 kcal/l mol of O 2 (hereinafter referred to as adequate element simply) is included into iron powder and not less than 20 wt% of the above element is rendered into an oxide. Because, when the amount of the adequate element is less than 0.008 wt%, the fluctuating width of dimensional change bin the sintered body can not be reduced to the fluctuating width of graphite added, while when it exceeds 0.5 wt%, the compaction in the shaping rapidly lowers. Further, when the quantity of oxide is less than 20 wt%, as shown in Fig. 1, the inclination of a curve between amount of graphite and quantity of dimensional change is still large and hence the fluctuating width of dimensional change in the sintered body to the fluctuating width of graphite added can not be reduced. As the adequate element, Cr, Mn, V, Si, Ti and Al are advantageously adaptable. Even in case of adding these elements alone or in admixture, when the amount is within a range of 0.008-0.5 wt% in total, the same effect can be obtained. Moreover, a preferable range of each element added alone is as follows: Cr: 0.05-0.5 wt%, Mn: 0.01-0.3 wt%, V: 0.008-0.5 wt%, Si: 0.008-0.5 wt%, Ti: 0.008-0.5 wt%, Al: 0.008-0.5 wt% Moreover, it is observed by EPMA that the oxide is dispersedly existent in the vicinity of the surface of iron powder (about 10 µm from the surface) and in particles thereof. In the invention, it has been confirmed that a desired effect is obtained when the oxide-forming ratio is not less than 20 wt%, and the effect becomes large when the position of existing the oxide is locally existent near to the surface. Furthermore, it is important to control the concentration of oxygen in iron powder to not more than 0.30 wt%. When oxygen is contained in an amount exceeding 0.30 wt%, the compressibility during the compact shaping lowers, which brings about the degradation of strength in the product. As mentioned above, when a given amount of the adequate element is included in iron powder and not less than 20 wt% thereof is rendered into an oxide, the fluctuating width of dimensional change in the sintered body can largely be reduced as compared with the conventional case. As a result of the inventors' further studies, it is elucidated that it is effective to reduce the scattering width of oxidation ratio of the adequate element to not more than 50% (preferably not more than 30%) in order to more improve the accuracy of dimensional change in the sintered body. That is, the quantity of dimensional change in the sintered body varies in accordance with the oxidation ratio of the adequate element as shown in Fig. 2. This tendency is conspicuous when the oxidation ratio is small. For example, in case of SiO 2 , when the oxidation ratio is not more than 20%, the fluctuating width of dimensional change becomes fairly large. Therefore, when the scattering width of the oxidation ratio is large (particularly the oxidation ratio is small), the scattering width of dimensional change becomes large accompanied therewith. Inversely, when the scattering width of the oxidation ratio is small, the fluctuating width of dimensional change is effectively mitigated. In Table 2 are shown results measured on fluctuating width of dimensional change and green density in the sintered body when Si as an adequate element is included into iron powder at various amounts and the scattering width of oxidation ratio of Si are variously varied. Symbol of iron powder Si content (wt%) Scattering range of oxidation ratio in Si content (%) Scattering width of oxidation ratio in Si content (%) Fluctuating width of dimensional change in sintered body (%) Green density (g/cm 3 ) A 0.004 5∼100 95 0.60 7.00 B 0.007 5∼95 90 0.56 6.99 C 0.008 30∼40 10 0.06 6.98 D 0.016 35∼45 10 0.06 6.98 E 0.025 45∼50 5 0.04 6.97 F 0.027 55∼65 10 0.06 6.92 G 0.050 25∼80 55 0.10 6.90 H 0.20 30∼50 20 0.05 6.89 I 0.50 20∼80 60 0.10 6.88 J 0.60 60∼80 20 0.06 6.77 As seen from this table, when Si is included within a proper range and the oxidation ratio thereof is not less than 20 wt% and also the scattering width of the oxidation ratio is controlled to not more than 50%, there is obtained a very good accuracy of dimensional change that the fluctuating width of dimensional change in the sintered body is not more than 0.06%. Moreover, all of the sintered bodies used in the above experiment are obtained by adding 2 wt% of Cu powder, 0.8 wt% of graphite powder and 1 wt% of zinc stearate as a lubricant to water-atomized iron powder reduced in a reducing atmosphere having a dew point of 10-60°C, shaping into a green compact having a density of 6.9 g/cm 3 and then sintering in RX gas having a CO 2 content of 0.3% at 1130°C for 20 minutes. The scattering of dimensional change is evaluated by a fluctuating width of dimensional change in the sintering based on the green compact having a given outer diameter with respect to 100 ring-shaped specimens having an outer diameter of 60 mm, an inner diameter of 25 mm and a height of 10 mm. Furthermore, the green density is measured when the same iron powder as mentioned above is added and mixed with 1 wt% of zinc stearate and shaped under a shaping pressure of 5 t/cm 2 . A preferable production method of the iron powder according to the invention will be described below. At first, the production method of iron powder is not particularly restricted, so that the conventionally well-known methods such as water atomizing method, a reducing method and, the like are adaptable. Among them, the water atomizing method is particularly advantageous in order to efficiently produce iron powder having a desired particle size, in which an average particle size of iron powder is preferably within a range of about 50-100 µm. Then, it is necessary that at least 20 wt% of adequate element included is rendered into oxide by subjecting the iron powder to an oxidation treatment in a proper oxidizing atmosphere. For this purpose, it is important that the oxidation treatment is carried out at a temperature of 100-200°C in a nitrogen atmosphere having an oxygen concentration of 2.5-15.0 vol%. Because, when the concentration of oxygen in the atmosphere is less than 2.5 vol%, it is difficult to ensure the oxide of not less than 20%, while when it exceeds 15.0 vol%, the oxygen content in the iron powder can not be controlled to not more than 0.30 wt% even by a reduction treatment as mentioned later and the compressibility lowers. The reason why the essential ingredient of the atmosphere is oxygen is due to the fact that it is easy to control the oxygen concentration in the atmosphere and also there is no risk of explosion as in hydrogen or the like and the economical merit is large as compared with the case of using inert gas such as Ar or the like. Moreover, in order to control the scattering width of the oxidation ratio in the formation of the oxide by the above oxidation treatment to not more than 50%, it is enough to conduct the oxidation treatment under stirring of powder. As the stirring apparatus, a rotary kiln and an agitating dryer are advantageously adaptable. Now, not less than 20% of the adequate element is rendered into an oxide by the aforementioned oxidation treatment, during which iron itself is oxidized to form an iron oxide. Since such an iron oxide undesirably deteriorates the compressibility, it is necessary to reduce the iron oxide. In the method according to the invention, therefore, only the oxidized Fe is selectively reduced by subjecting to a reduction treatment in a reducing atmosphere at 800-1000°C after the above oxidation treatment. In the selective reduction treatment of the oxidized Fe, the reason why the treating temperature is limited to the range of 800-1000°C is due to the fact that when the treating temperature is lower than 800°C, it is difficult to reduce the oxygen content in the iron powder to not more than 0.30 wt%, while when it exceeds 1000°C, the oxide of the adequate element is also oxidized and it is difficult to ensure the adequate quantity of not less than 20 wt%. Moreover, the treating time is sufficient to be about 20-60 minutes. Although the above explains the technique of enhancing the accuracy of dimensional change in the sintered body by modifying the iron powder itself, even when ordinary iron powder is used, the accuracy of dimensional change in the resulting sintered body can be improved by the application of the above technique. That is, the aforementioned technique lies in that a given adequate element is included in the iron powder and a part thereof is rendered into an oxide. On the other hand, even if a given quantity of oxide powder of the adequate element is mixed with the ordinary iron powder as a starting powder for the sintered body, there is substantially no difference in view of the effect. As the oxide powder of the adequate element, Cr 2 O 3 , MnO, SiO 2 , V 2 O 3 , TiO 2 , Al 2 O 3 and the like are advantageously adaptable. The same effect as in case of modifying the iron powder itself can be obtained by adding at least one of these oxides at a quantity of 0.01-0.20 wt% in total. The reason why the quantity of the oxide powder is limited to the range of 0.01-0.20 wt% is due to the fact that when the quantity is less than 0.01 wt%, the fluctuating width of dimensional change in the sintered body is still large, while when it exceeds 0.20 wt%, the green density and hence the strength of the sintered body rapidly lower. In case of such a mixed powder, there is caused a fear of deteriorating the accuracy due to segregation of the oxide powder based on ununiform mixing. This is the same as in the scattering of oxidation ratio in the iron powder itself. Even if the segregation is somewhat caused, there is caused no segregation exceeding the upper limit of the oxidation ratio in the iron powder itself of 50%, so that there is substantially no problem. On the contrary, the quantity of the oxide can strictly be controlled in the mixed powder, so that if the uniform mixing is satisfied, the fluctuating width of dimensional change can be controlled with a higher accuracy and hence the quantity of dimensional change in the sintered body can freely be adjusted within a certain range. In Table 3 are shown green density, dimensional change rate of the sintered body and transverse rupture strength of the sintered body when Al 2 O 3 powder is added in various quantities as an oxide powder. Moreover, the dimensional change in the longitudinal direction of the sintered body is measured before and after the sintering on 100 sintered bodies, each of which bodies is produced by adding and mixing water-atomized iron powder with 1.5 wt% of Cu powder, 0.9 wt% of graphite powder, 1 wt% of a solid lubricant (zinc stearate) and 0.01-0.25 wt% of fine alumina powder, shaping into a green compact having a length of 35 mm, a width of 10 mm and a height of 5 mm at a green density of 7.0 g/cm 3 and then sintering in a propane-modified gas at 1130°C for 20 minutes. Furthermore, the green density is measured when the same iron powder as mentioned above is added and mixed with 1 wt% of zinc stearate and shaped under a shaping pressure of 5 t/cm 2 . Addition amount of Aℓ 2 O 3 powder Green density (g/cm 3 ) Quantity of dimensional change in sintered body (%) Fluctuating width of dimensional change (%) Transverse rupture strength of sintered body (Kgf/mm 2 ) 0 6.90 0.09 0.20 80 0.01 6.89 0.15 0.06 80 0.05 6.89 0.20 0.05 79 0.10 6.88 0.23 0.04 79 0.20 6.87 0.25 0.04 79 0.25 6.85 0.26 0.04 73 The quantity of dimensional change in the sintered body is based on the dimension of the green compact. As seen from this table, the dimensional change tends to expand with the increase in the quantity of fine Al 2 O 3 powder added. When the quantity is 0.1 wt%, the expansion of about 0.2% is caused as compared with the case of adding no fine powder, in which there is substantially no scattering of dimensional change. Thus, when the quantity of Al 2 O 3 powder added is within a range of 0.01-0.20 wt%, the quantity of dimensional change in the sintered body can exactly be changed by a given value in accordance with the quantity of Al 2 O 3 powder added without decreasing the strength of the sintered body. In such a mixed powder, therefore, when the quantity of the oxide powder added is properly adjusted, the dimension of the sintered body can optionally be adjusted. For instance, it is possible to produce plural kinds of the sintered bodies having different dimensions from a single shaping mold. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a graph showing a relation between amount of graphite added and quantity of dimensional change in sintered body; and Fig. 2 is a graph showing a relation between oxidation ratio and quantity of dimensional change in sintered body. Example 1 Various iron powders having a composition as shown in Tables 4-1 to 4-3 (average particle size: 50-100 µm) are produced through water atomization method and subjected to an oxidation treatment and further to a reduction treatment under conditions shown in Table 5. The resulting iron powder is added and mixed with 2.0 wt% of Cu powder, 0.8 wt% of graphite powder and 1.0 wt% of zinc stearate as a lubricant, shaped into a green compact under a shaping pressure of 5.0 t/cm 2 and then sintered in a propane-modified gas at 1130°C for 20 minutes. The oxidation ratio of the added element after the reduction treatment, scattering width of oxidation ratio, green density and the fluctuating width of dimensional change and tensile strength of the resulting sintered body are measured to obtain results as shown in Tables 4-1 to 4-3. Moreover, the fluctuating width of dimensional change is evaluated by a scattering width of dimensional change rate in the sintering on 100 ring-shaped specimens having an outer diameter of 60 mm, an inner diameter of 25 mm and a height of 10 mm based on the green compact having the same outer diameter. On the other hand, the green density is measured when the same iron powder as mentioned above is added and mixed with 1 wt% of zinc stearate and shaped under a shaping pressure of 5 t/cm 2 . Oxygen Oxidation Reduction Treating conditions concentration (vol%) temperature (°C) temperature (°C) Reducing atmosphere Stirring Acceptable Example 1 3 150 950 H 2 (Dry) none Acceptable Example 2 5 150 970 H 2 (Dry) none Acceptable Example 3 2.8 150 850 H 2 (Dry) none Acceptable Example 4 10 150 880 H 2 (Dry) conducted Acceptable Example 5 7 150 1000 H 2 (Dry) conducted Acceptable Example 6 12 150 950 H 2 (dew point= 30°C) none Acceptable Example 7 5 150 830 H 2 (dew point= 30°C) none Acceptable Example 8 5 130 920 H 2 (Dry) none Acceptable Example 9 3 170 950 H 2 (dew point= 30°C) conducted Acceptable Example 10 3 170 950 H 2 (Dry) conducted Acceptable Example 11∼13 3 150 950 H 2 (Dry) none Acceptable Example 14∼15 3 150 950 H 2 (Dry) conducted Acceptable Example 16∼18 5 170 900 H 2 (Dry) none Acceptable Example 19∼20 5 170 900 H 2 (Dry) conducted Acceptable Example 21∼23 3 170 970 H 2 (Dry) none Acceptable Example 24∼25 3 170 970 H 2 (Dry) conducted Acceptable Example 26∼28 5 170 970 H 2 (Dry) none Acceptable Example 29∼30 5 170 970 H 2 (Dry) conducted Comparative Example 1,4,7 1 170 950 H 2 (Dry) conducted Comparative Example 10, 13, 16 3 150 1050 H 2 (Dry) conducted other comparative examples 3 150 950 H 2 (Dry) none As shown in Table 4, all of iron powders containing a given range of an adequate element and subjected to the oxidation treatment and the reduction treatment according to the invention contain not less than 20% of oxide of the added adequate element. When the sintered body is produced by using such an iron powder, the fluctuating width of dimensional change in the sintered body is not more than 0.1%, which is considerably excellent as compared with the conventional one. Furthermore, the green density and tensile strength are as high as about 6.9 kg/mm 3 and about 40 kg/mm 2 , respectively. When the stirring is particularly conducted in the oxidation treatment (Acceptable Examples 4-5, 9-10, 14-15, 19-20, 24-25, 29-30), the scattering width of oxidation ratio of the added adequate element is suppressed to not more than 50% and hence the fluctuating width of dimensional change is not more than 0.05%, whereby a more excellent accuracy of dimensional change is obtained. On the contrary, in Comparative Examples 1, 4 and 7, the oxygen concentration in the atmosphere for the oxidation treatment is 1%, so that the oxidation ratio of the added adequate element is less than 10%, while in Comparative Examples 10, 13 and 16, the temperature in the reduction treatment exceeds 1000°C, so that the oxidation ratio of the added adequate element is less than 20%. In these Comparative Examples, a good accuracy of dimensional change is not obtained. In Comparative Examples 2, 5, 8, 11, 14 and 17 in which the amount of the adequate element added is less than the lower limit, even if the production conditions are adequate, the fluctuating width of dimensional change is as large as about 0.20%, while in Comparative Examples 3, 6, 9, 12, 15 and 18 in which the amount of the adequate element added is excessive, rapid decrease of compressibility and hence the decrease of strength in the sintered body are observed. Moreover, when the oxygen concentration in the atmosphere for the oxidation treatment exceeds 15%, or when the temperature of the oxidation treatment exceeds 200°C, the oxygen content after the treatment becomes too large and a long time is taken in the reduction treatment. Further, when the temperature in the reduction treatment is lower than 800°C, a long reducing time is undesirably taken. Example 2 Iron powders having a composition as shown in Table 6 (average particle size: 50-100 µm) are produced through water atomization method and then subjected to an oxidation treatment and reduction treatment under conditions shown in Table 7. Then, green compacts and sintered bodies are produced in the same manner as in Example 1. The oxidation ratio of the added adequate element after the reduction treatment, scattering width of oxidation ratio, green density and the fluctuating width of dimensional change and tensile strength of the resulting sintered body are measured to obtain results as shown in Table 6. Treating conditions Oxygen concentration (vol%) Oxidation temperature (°C) Reduction temperature (°C) Reducing atmosphere Stirring Acceptable Example 31 4 150 950 H 2 (Dry) none Acceptable Example 32 3 150 970 H 2 (Dry) conducted Acceptable Example 33 3 150 850 H 2 (Dry) conducted Acceptable Example 34 8 150 880 H 2 (Dry) none Acceptable Example 35 5 150 1000 H 2 (Dry) none Acceptable Example 36 5 150 950 H 2 (dew point= 30°C) none Acceptable Example 37 5 150 830 H 2 (dew point= 30°C) conducted Acceptable Example 38 5 130 920 H 2 (Dry) none Acceptable Example 39 5 170 950 H 2 (dew point= 30°C) conducted As shown in Table 6, even when a mixture of various adequate elements is added, if the amount of the mixture added is proper and the oxidation and reduction treatments are conducted according to the invention, not less than 20% of each added adequate element in the resulting iron powder is rendered into an oxide. When such iron powder is used to form a sintered body, the fluctuating width of dimensional change in the sintered body is as small as not more than 0.1%, and the green density and tensile strength are as high as about 6.9 kg/mm 3 and about 40 kg/mm 2 , respectively. Particularly, when the stirring is conducted in the oxidation treatment (Acceptable Examples 32-33, 37, 39), the scattering width of oxidation ratio of the added adequate element is suppressed to not more than 50% and hence the fluctuating width of dimensional change is 0.03% and a very excellent accuracy of dimensional change is obtained. Example 3 Iron powder (purity: 99.9%, particle size: 80 µm) is added with a given quantity of an oxide shown in Table 8 and added and mixed with 2.0 wt% of Cu powder, 0.8 wt% of graphite powder and 1.0 wt% of zinc stearate as a lubricant, shaped into a green compact under a shaping pressure of 5 t/cm 2 and then sintered in a propane-modified gas at 1130°C for 20 minutes. The fluctuating width of dimensional change and tensile strength of the resulting sintered body and the green density of the green compact are measured to obtain results as shown in Table 8. Moreover, the fluctuating width of dimensional change is evaluated by a scattering width of dimensional change in the sintering on 100 ring-shaped specimens having an outer diameter of 60 mm, an inner diameter of 25 mm and a height of 10 mm based on the green compact having the same outer diameter. And also, the green density is measured when the same iron powder as mentioned above is added and mixed with 1 wt% of zinc stearate and shaped under a shaping pressure of 5 t/cm 2 . No. Addition amount of oxide (%) Fluctuating width of dimensional change (%) Green density (g/cm 3 ) Tensile strength (kg/mm 2 ) Remarks 1 Cr 2 O 3 0.02 0.05 6.91 40 Acceptable Example 1 2 Cr 2 O 3 0.18 0.03 6.90 40 Acceptable Example 2 3 Cr 2 O 3 0.005 0.19 6.92 42 Comparative Example 1 4 Cr 2 O 3 0.30 0.11 6.77 34 Comparative Example 2 5 SiO 2 0.02 0.04 6.90 40 Acceptable Example 3 6 SiO 2 0.18 0.04 6.89 39 Acceptable Example 4 7 SiO 2 0.005 0.19 6.90 42 Comparative Example 3 8 SiO 2 0.30 0.11 6.75 29 Comparative Example 4 9 MnO 0.02 0.05 6.92 41 Acceptable Example 5 10 MnO 0.18 0.04 6.90 40 Acceptable Example 6 11 MnO 0.005 0.19 6.92 42 Comparative Example 5 12 MnO 0.30 0.10 6.77 34 Comparative Example 6 13 Al 2 O 3 0.02 0.04 6.91 40 Acceptable Example 7 14 Al 2 O 3 0.18 0.02 6.89 39 Acceptable Example 8 15 Al 2 O 3 0.005 0.18 6.91 41 Comparative Example 7 16 Al 2 O 3 0.30 0.10 6.78 30 Comparative Example 8 17 TiO 2 0.02 0.05 6.91 41 Acceptable Example 9 18 TiO 2 0.18 0.03 6.90 39 Acceptable Example 10 19 TiO 2 0.005 0.19 6.91 42 Comparative Example 9 20 TiO 2 0.30 0.10 6.78 35 Comparative Example 10 21 V 2 O 3 0.02 0.04 6.91 41 Acceptable Example 11 22 V 2 O 3 0.18 0.03 6.90 40 Acceptable Example 12 23 V 2 O 3 0.005 0.19 6.90 42 Comparative Example 11 24 V 2 O 3 0.30 0.10 6.78 33 Comparative Example 12 25 Cu 2 O 0.1 0.18 6.90 42 Comparative Example 13 26 NiO 0.1 0.20 6.91 41 Comparative Example 14 As shown in Table 8, when the sintered body is produced by using the mixed powder according to the invention in which the adequate elements are added at a given amount, the fluctuating width of dimensional change in the sintered body is not more than 0.05% and is considerably lower as compared with the conventional one, and also the green density and tensile strength are as high as about 6.9 kg/mm 3 and about 40 kg/mm 2 , respectively. On the contrary, when the quantity of the oxide powder added exceeds the range defined in the invention, rapid decrease of compressibility and hence decrease of strength in the sintered body are observed as in Comparative Examples 2, 4, 6, 8, 10 and 12. Further, when the the quantity of the oxide powder added is less than the adequate quantity, the fluctuating width of dimensional change is as large as about 0.2% as in Comparative Examples 1, 3, 5, 7, 9 and 11. In Comparative Examples 13 and 14 using Cu 2 O or NiO powder having a value of standard free energy of formation of oxide at 1000°C of not less than -120 kcal/l mol of O 2 , the fluctuating width of dimensional change is not small. Example 4 Table 9 shows a chemical composition of iron powder used. The iron powder is obtained by water-atomizing molten steel to form a green powder, subjecting the green powder to an oxidation treatment in a nitrogen atmosphere containing 3 vol% of oxygen at 140°C for 60 minutes, reducing in a hydrogen containing atmosphere at 750-1050°C for 20 minutes and then pulverizing and sieving it. In the analysis of Cr, Mn as an oxide, these elements are extracted as an inclusion through the alcoholic iodine method and calculated in the form of Cr 2 O 3 and MnO. The fluctuating width of dimensional change and tensile strength when the sintered body is produced by using the above iron powder, the oxidation ratio of the added adequate element after the reduction treatment and the green density of the green compact are measured to obtain results as shown in Table 10. As to the dimensional change of the sintered body, an influence of graphite amount is examined by a difference between Fe-2.0% Cu-0.8% graphite (hereinafter abbreviated as Gr) and Fe-2.0% Cu-1.0% Gr obtained by mixing graphite powder and copper powder with iron powder. The difference between both is measured with respect to 20 specimens. Each specimen has a ring shape having an outer diameter of 60 mm, an inner diameter of 25 mm and a height of 10 mm and is obtained by shaping into a green compact having a green density of 6.85 g/cm 3 and then sintering in a nitrogen atmosphere at 1130°C for 20 minutes. Furthermore, the compressibility is evaluated by a green density when the iron powder is added with 1 wt% of zinc stearate (Fe-1.0% ZnSt) and shaped into a tablet of 11 mm⊘ x 10 mm under a shaping pressure of 5 t/cm 2 . Moreover, the strength is evaluated by a tensile strength when the iron powder is mixed with graphite powder and copper powder so as to have a composition of Fe-2.0% Cu-0.8% Gr, shaped into a JSPM standard tensile testing specimen (green density: 6.85 g/cm 3 ) and sintered in a nitrogen atmosphere at 1130°C for 20 minutes. No. Reduction temperature (°C) Reducing atmosphere Composition iron powder of (%) Remarks Mn Cr O 1 950 H 2 (Dry) 0.15 0.10 0.22 Acceptable Example 1 2 970 H 2 (Dry) 0.18 0.15 0.20 Acceptable Example 2 3 850 H 2 (Dry) 0.20 0.26 0.19 Acceptable Example 3 4 880 H 2 (Dry) 0.10 0.18 0.26 Acceptable Example 4 5 1000 H 2 (Dry) 0.10 0.40 0.15 Acceptable Example 5 6 950 H 2 (dew point = 30°C) 0.14 0.35 0.21 Acceptable Example 6 7 830 H 2 (dew point = 30°C) 0.14 0.20 0.20 Acceptable Example 7 8 920 H 2 (dew point = 45°C) 0.13 0.21 0.28 Acceptable Example 8 9 950 H 2 (dew point = 45°C) 0.10 0.15 0.18 Acceptable Example 9 10 1050 H 2 (Dry) 0.19 0.21 0.11 Comparative Example 1 11 1040 H 2 (Dry) 0.16 0.11 0.10 Comparative Example 2 12 970 H 2 (Dry) 0.003 0.003 0.12 Comparative Example 3 13 970 H 2 (Dry) 0.17 0.60 0.24 Comparative Example 4 14 970 H 2 (Dry) 0.40 0.20 0.19 Comparative Example 5 15 750 H 2 (dew point = 30°C) 0.16 0.15 0.40 Comparative Example 6 As seen from Table 10, all of iron powders satisfying the requirements according to the invention exhibit an accuracy of dimension change having a fluctuating width of not more than 0.12%. Furthermore, in the acceptable examples, there are shown good values on the compressibility (evaluated by green density under the shaping pressure of 5 t/cm 2 ) and the strength (evaluated by tensile strength). On the contrary, in Comparative Examples 1 and 2, the quantity of oxidized Cr among Cr content is not more than 20%, so that the fluctuating width exceeds 0.15% and the properties are deteriorated. In Comparative Example 3, the quantities of Cr and Mn are 0.006%, which are below the lower limit of the adequate range, so that the fluctuating width of dimensional change in the sintered body to the fluctuation of the amount of graphite added exceeds 0.15%. In Comparative Example 4, the quantity of Cr+Mn exceeds 0.5 wt%, so that the compressibility is poor and the strength is low. Similarly, since the quantity of Cr+Mn exceeds 0.5 wt% in Comparative Example 5 and the oxygen concentration exceeds 0.3 wt% in Comparative Example 6, the compressibility lowers and the strength is low. Example 5 Water-atomized green iron powder having a composition of 0.05-0.5 wt% of Cr, 0.01-0.3 wt% of Mn and the reminder being Fe and inevitable impurity is subjected to an oxidation treatment in a nitrogen atmosphere by varying an oxygen concentration and then reduced in a pure hydrogen atmosphere at 930°C for 20 minutes, and thereafter a relation between oxygen concentration in the atmosphere and ratio of oxidized Cr is measured to obtain results as shown in Table 11. No. Composition of green powder (%) Oxygen concentration in nitrogen (vol%) Composition of finished iron powder (%) Remarks Mn Cr O ratio of oxidized Cr 16 0.22 0.20 5 0.21 54 Acceptable Example 10 17 0.20 0.15 14 0.25 65 Acceptable Example 11 18 0.19 0.20 1 0.17 12 Comparative Example 7 19 0.20 0.15 21 0.41 73 Comparative Example 8 As seen from this table, in all acceptable examples in which the oxygen concentration in the nitrogen atmosphere satisfies the range defined in the invention, the oxygen content in the finished iron powder is not more than 0.3 wt% and the oxidation ratio of Cr per total Cr is not less than 20%. On the other hand, in Comparative Example 7 in which the oxygen concentration in the nitrogen atmosphere does not satisfy the lower limit according to the invention, the oxygen content in the finished iron powder is not more than 0.3 wt%, but the ratio of oxidized Cr is not more than 20%, while in Comparative Example 8 in which the oxygen concentration in the nitrogen atmosphere exceeds the upper limit according to the invention, the oxygen content in the finished iron powder exceeds 0.3 wt%. Example 6 Each of iron powders containing various contents of Si as shown in Table 12 is added and mixed with 1.5 wt% of Cu powder, 0.5 wt% of graphite powder and 1 wt% of zinc stearate as a lubricant, shaped into a ring-shaped green compact having an outer diameter of 60 mm, an inner diameter of 25 mm and a height of 10 mm and a green density of 6.9 g/cm 3 , and then sintered in an RX gas having a CO 2 content of 0.3% at 1130°C for 20 minutes. The fluctuating width of dimensional change in the resulting sintered body is measured to obtain results as shown in Table 12 together with results measured on the oxidation ratio of elementary Si in the iron powder and the scattering width of the oxidation ratio. The fluctuating width of dimensional change is evaluated by a scattering width of dimensional change in the sintering on 100 specimens based on the green compact having the same outer diameter. As seen from this table, in all acceptable examples according to the invention containing an adequate amount of Si, not less than 20% of which being rendered into an oxide, good accuracy of dimensional change is obtained, while in the comparative examples, the fluctuating width of dimensional change in the sintered body is still large. Symbol of iron powder Si content (wt%) Oxidation ratio of Si (%) Scattering width of oxidation ratio in Si content (%) Fluctuating width of dimensional change in sintered body (%) Remarks A 0.004 15∼85 70 0.56 Comparative Example 1 B 0.007 17∼80 63 0.52 Comparative Example 2 C 0.008 25∼40 15 0.04 Acceptable Example 1 D 0.016 30∼40 10 0.04 Acceptable Example 2 E 0.025 35∼45 10 0.02 Acceptable Example 3 F 0.027 55∼75 20 0.04 Acceptable Example 4 Example 7 According to the same manner as in Example 6, each of iron powders having various amounts of Si shown in Table 13 is added and mixed with 2.0 wt% of Cu powder, 0.8 wt% of graphite powder and 1 wt% of zinc stearate as a lubricant, shaped into a ring-shaped green compact having an outer diameter of 60 mm, an inner diameter of 25 mm and a height of 10 mm and a green density of 6.9 g/cm 3 , whereby 100 specimens are produced. Then, these specimens are sintered in an AX gas at 1130°C for 20 minutes, and the quantity of dimensional change in the sintering based on the green compact having the same outer diameter is measured to examine the fluctuating width thereof. The results measured on the fluctuating width of dimensional change in the sintered body are also shown in Table 13 together with results measured on the oxidation ratio of elementary Si in the iron powder and the scattering width of the oxidation ratio. As seen from this table, in all acceptable examples according to the invention containing an adequate amount of Si, not less than 20% of which being rendered into an oxide, good accuracy of dimensional change is obtained, while in the comparative examples, the fluctuating width of dimensional change in the sintered body is still large. Symbol of iron powder Si content (wt%) Oxidation ratio of Si (%) Scattering width of oxidation ratio in Si content (%) Fluctuating width of dimensional change in sintered body (%) Remarks A 0.004 15∼85 70 0.50 Comparative Example 3 B 0.007 17∼80 63 0.46 Comparative Example 4 C 0.008 25∼40 15 0.02 Acceptable Example 5 D 0.016 30∼40 10 0.02 Acceptable Example 6 E 0.025 35∼45 10 0.02 Acceptable Example 7 F 0.027 55∼75 20 0.04 Acceptable Example 8 Example 8 Each of green powders obtained by water atomizing molten steels having various amounts of Si and Mn is subjected to an oxidation treatment in a nitrogen atmosphere having different oxygen concentrations at 140°C for 60 minutes and then subjected to a reduction treatment in a pure hydrogen atmosphere at 930°C for 20 minutes to produce iron powders (average particle size: 80 µm) having a chemical composition, quantity of oxide and scattering width of oxidation ratio shown in Table 14. Then, the fluctuating width of dimensional change when the sintered body is produced by using these powders and the green density of the green compact are measured to obtain results as shown in Table 14. The fluctuating width of dimensional change in the sintered body is evaluated as a scattering width determined from a quantity of dimensional change in the sintering based on the green compact having the same outer diameter with respect to 100 sintered specimens obtained by adding and mixing iron powder with 1.5 wt% of copper powder, 0.5 wt% of graphite powder and 1 wt% of zinc stearate as a lubricant, shaping into a ring-shaped green compact having a density of 6.9 g/cm 3 , an outer diameter of 60 mm, an inner diameter of 25 mm and a height of 10 mm and sintering in a propane-modified gas having a CO 2 content of 0.3% at 1130°C for 20 minutes. And also, the green density is measured when the same iron powder as mentioned above is added and mixed with 1 wt% of zinc stearate and shaped under a shaping pressure of 5 t/cm 2 . Moreover, the scattering width of oxidized Si ratio in the Si content is determined from a scattering width obtained by dividing the iron powder into 10 parts and analyzing a ratio of SiO 2 quantity to total Si amount per each part. As seen from this table, all of Acceptable Examples 1-7 contain adequate amounts of Si and Mn, in which not less than 20% of Si and Mn amounts is rendered into an oxide and the scattering width thereof is not more than 50%, so that there is obtained an excellent accuracy of dimensional change of not more than 0.06%, which is lower than the typical lower limit of the dimensional accuracy after the correction of dimensional change through the conventional sizing. Further, the compressibility is very good. On the contrary, all of the comparative examples are the case that the chemical composition, ratio of Si+Mn amount as an oxide and further oxygen concentration in the atmosphere do not satisfy the adequate ranges defined in the invention, so that the satisfactory results are not obtained in the accuracy of dimensional change in the sintered body and the compressibility. Example 9 Each of green powders obtained by water atomizing molten steels having various amounts of Si and Mn is subjected to an oxidation treatment in a nitrogen atmosphere having different oxygen concentrations at 140°C for 60 minutes and then subjected to a reduction treatment in a pure hydrogen atmosphere at 930°C for 20 minutes to produce iron powders (average particle size: 70 µm) having a chemical composition, quantity of oxide and scattering width of oxidation ratio shown in Table 15. Then, the fluctuating width of dimensional change when the sintered body is produced by using these powders and the radial crushing strength are measured to obtain results as shown in Table 15. The state of Si oxide on the particle surface of iron powder is observed by Auger analysis. The fluctuating width of dimensional change in the sintered body is determined from a quantity of dimensional change before and after the sintering when pure iron powder is added and mixed with 0.8 wt% of two kinds of graphites having average particle sizes of 34 µm and 6 µm, shaped into a ring-shaped green compact of Fe-2% Cu-0.8% graphite having an outer diameter of 60 mm, an inner diameter of 25 mm, a height of 10 mm and a green density of 6.80 g/cm 3 and sintered in a propane-modified gas having a CO 2 content of 0.3% at 1130°C for 20 minutes. Moreover, the radial crushing strength of the sintered body is measured with respect to a sintered body obtained by sintering a ring-shaped green compact having the same composition and green density as mentioned above and an outer diameter of 38 mm, an inner diameter of 25 mm and a height of 10 mm in a propane-modified gas having a CO 2 content of 0.3% at 1130°C for 20 minutes. As seen from this table, when using the iron powder according to the invention (Acceptable Examples 1-5), the fluctuating width of dimensional change is not more than 0.1%. Particularly, when Si oxide is distributed on the particle surface of the iron powder in form of island (Acceptable Examples 1-4), even if the average particle size of graphite powder added is largely different between 34 µm and 6 µm, the fluctuating width of dimensional change in the sintered body is as very low as not more than 0.06%, and also the radial crushing strength is as high as not less than 700 N/mm 2 . On the other hand, all of the comparative examples are the case that the chemical composition and the ratio of Si quantity as an oxide do not satisfy the adequate ranges defined in the invention, so that a good accuracy of dimensional change in the sintered body is not obtained as mentioned below. In Comparative Examples 1 and 2, the Si+Mn amount is not less than 0.50% exceeding the defined upper limit, so that the radial crushing strength is lower than 700 N/mm 2 . In Comparative Example 3, the oxygen concentration in the atmosphere when water-atomized powder is dried is 2.0 vol% lower than the defined value, so that the fluctuation of dimensional change is large. In Comparative Examples 4 and 5, the O content is 0.34 wt% and the Si content is 0.62 wt%, which exceed the defined upper limits, respectively, so that only the radial crushing strength of lower than 700 N/mm 2 is obtained. Example 10 Water-atomized iron powder (average particle size: 70 µm) is added with not more than 0.3 wt% of various oxide powders shown in Table 16 (average particle size: 5 µm) and added and mixed with 1.5 wt% of electrolytic copper powder (average particle size: not more than 44 µm), 0.9 wt% of graphite powder (average particle size: not more than 10 µm) and 1 wt% of a solid lubricant, shaped at a green density of 7.0 g/cm3 into a test specimen for transverse rupture strength having a length of 35 mm, a width of 10 mm and a height of 5 mm and then sintered in a propane-modified gas at 1130°C for 20 minutes. The fluctuating width of dimensional change in the longitudinal direction of the sintered body before and after the sintering and the transverse rupture strength are measured to obtain results as shown in Table 16. No. Oxide added Addition amount (wt%) Green density (g/cm 3 ) Dimensional change of sintered body based on green compact Fluctuating width of dimensional change (%) Transverse rupture strength (kgf/mm 2 ) Remarks 1 - 0 6.90 0.09 0.21 80 Comparative Example 1 2 Al 2 O 3 0.01 6.89 0.15 0.07 80 Example 1 3 " 0.05 6.89 0.20 0.06 79 Example 2 4 " 0.10 6.88 0.25 0.05 79 Example 3 5 " 0.20 6.87 0.25 0.04 75 Example 4 6 " 0.30 6.85 0.26 0.04 73 Comparative Example 2 7 TiO 2 0.01 6.89 0.14 0.10 82 Example 5 8 " 0.05 6.88 0.19 0.07 80 Example 6 9 " 0.10 6.88 0.25 0.07 79 Example 7 10 " 0.20 6.86 0.25 0.05 73 Example 8 11 " 0.30 6.84 0.26 0.05 71 Comparative Example 3 12 SiO 2 0.01 6.89 0.15 0.09 80 Example 9 13 " 0.05 6.89 0.19 0.07 79 Example 10 14 " 0.10 6.88 0.25 0.06 78 Example 11 15 " 0.20 6.86 0.25 0.03 76 Example 12 16 " 0.30 6.84 0.25 0.03 72 Comparative Example 4 17 V 2 O 3 0.01 6.90 0.15 0.11 81 Example 13 18 " 0.05 6.89 0.20 0.07 81 Example 14 19 " 0.10 6.88 0.26 0.07 79 Example 15 20 " 0.20 6.87 0.26 0.05 77 Example 16 21 " 0.30 6.85 0.26 0.05 74 Comparative Example 5 No. Oxide added Addition amount (wt%) Green density (g/cm 3 ) Dimensional change of sintered body based on green compact Fluctuating width of dimensional change (%) Transverse rupture strength (kgf/mm 2 ) Remarks 22 MnO 0.01 6.89 0.14 0.11 82 Example 17 23 " 0.05 6.88 0.20 0.08 81 Example 18 24 " 0.10 6.88 0.26 0.06 81 Example 19 25 " 0.20 6.87 0.26 0.06 72 Example 20 26 " 0.30 6.85 0.26 0.05 75 Comparative Example 6 27 Cr 2 O 3 0.01 6.89 0.14 0.09 82 Example 21 28 " 0.05 6.89 0.21 0.07 82 Example 22 29 " 0.10 6.89 0.25 0.06 80 Example 23 30 " 0.20 6.87 0.25 0.06 78 Example 24 31 " 0.30 6.85 0.25 0.04 74 Comparative Example 7 32 NiO 0.01 6.89 0.02 0.21 80 Comparative Example 8 33 " 0.05 6.89 0.00 0.20 84 Comparative Example 9 34 " 0.10 6.88 -0.03 0.20 80 Comparative Example 10 35 " 0.20 6.88 -0.09 0.21 79 Comparative Example 11 36 Cu 2 O 0.01 6.89 0.12 0.20 73 comparative Example 12 37 " 0.05 6.88 0.14 0.20 82 Comparative Example 13 38 " 0.10 6.88 0.18 0.21 83 Comparative Example 14 39 " 0.20 6.87 0.25 0.20 79 Comparative Example 15 As seen from this table, in all acceptable examples adding adequate amounts of oxides, the quantity of dimensional change in the sintered body is constant and the scattering thereof is very small. Further, the transverse rupture strength is substantially constant up to 0.1 wt%. On the other hand, when using Cu 2 O powder or NiO powder (average particle size: 5 µm) in which a value of standard free energy of formation of oxide at 1000°C is smaller than -120 kcal/l mol of O 2 , the dimension tends to expand with the increase of the amount of Cu 2 O added, or NiO tends to contract the dimension. In any case, the fluctuating width of dimensional change is little difference to the case of changing no dimension. Furthermore, when the addition amount is less than 0.01 wt%, the quantity of adjusting dimensional change is small, while when it exceeds 0.20 wt%, the green density and the transverse rupture strength of the sintered body rapidly lower. INDUSTRIAL APPLICABILITY The iron powder for powder metallurgy and mixed powder thereof according to the invention considerably reduce the fluctuating width of dimensional change in the sintered body irrespectively of the amount of graphite added and particle size in the sintering after the addition of Cu and graphite as compared with the conventional iron powder for powder metallurgy, whereby there can be obtained the accuracy of dimensional change equal to or more than that after the conventional sizing step and also the radial crushing strength of the sintered body is stably obtained. Therefore, the design and production of sintered parts having a high strength can easily be attained without conducting the sizing. Particularly, the oxidation ratio can strictly be controlled in the mixed powder, whereby the dimensional fluctuating width can be controlled with a higher accuracy. Moreover, the quantity of dimensional change of the sintered parts can freely be adjusted by adjusting the quantity of the oxide added.

Claims: A mixed powder for powder metallurgy formed by adding iron powder with a mixture of 0.5-1 wt.% graphite powder and 1.5-2 wt.% Cu powder, characterised in that the iron powder comprises 0.008-0.5 wt% in total of at least one element having a value of standard free energy of formation of its oxide at 1000°C of not more than -120 kcal/1 mol of 0 2 and not more than 0.30 wt% of oxygen, with the reminder being Fe and inevitable impurities, wherein not less than 20% of the above element is an oxide. A mixed powder according to claim 1, wherein the iron powder has a scattering width of oxidation ratio of not more than 50%. A mixed powder according to claim 1, wherein the element having a value of standard free energy of formation of its oxide at 1000°C of not more -120 kcal/1 mol of 0 2 is selected from: Cr, Mn, V, Si, Ti and Al. A mixed powder as claimed in claim 3, wherein the range of concentrations for each element having a value of standard free energy of formation of its oxide at 1000°C of not more than -120 kcal/1 mol of 0 2 , when present in the mixed powder, are: Cr: from 0.05 to 0.5 wt%, Mn: from 0.01 to 0.3 wt%, V: from 0.008 to 0.5 wt%, Si: from 0.008 to 0.5 wt%, Ti: from 0.008 to 0.5 wt%, and Al: from 0.008 to 0.5 wt%. A mixed powder as claimed in any preceding claim, wherein the powder comprises an amount of Cu of not more than 2.0 wt% and an amount of graphite of not more than 0.8 wt%. A mixed powder for powder metallurgy formed by adding iron powder with a mixture of 0.5-1 wt.% graphite powder and 1.5-2 wt.% Cu powder, characterised in that the iron powder the mixed powder includes 0.01-0.20 wt% in total of oxide powder of at least one element having a value of standard free energy of formation of its oxide at 1000°C of not more than -120 kcal/1 mol of 0 2 . A mixed powder according to claim 6, wherein the oxide is selected from: Cr 2 0 3 , MnO , SiO 2 , V 2 0 3 , TiO 2 and Al 2 0 3 . A method of producing a mixed powder for powder metallurgy according to any one of claims 1-5, characterised in that iron powder having a composition comprising 0.008-0.5 wt% in total of at least one element having a value of standard free energy of formation of its oxide at 1000°C of not more than -120 kcal/ 1 mol of 0 2 and not more than 0.30 wt% of oxygen, with the reminder being Fe and inevitable impurities, is subjected to an oxidation treatment at a temperature of 100-200°C in a nitrogen atmosphere having an oxygen concentration of 2.5-15.0 vol% and then subjected to a selective reduction treatment for oxidised Fe in a reducing atmosphere at 800-1000°C prior to the addition of a mixture of graphite powder and Cu powder. A method according to claim 8, wherein the oxidation treatment of iron powder is conducted with stirring.

Inventors: ISHIKAWA HIROYUKI, MAEDA YOSHIAKI, NITTA MINORU, OGURA KUNIAKI, OHTUBO HIROSHI, OMURA TAKEO, YOSHII HIROSHI, ISHIKAWA, HIROYUKI, MAEDA, YOSHIAKI, NITTA, MINORU, OGURA, KUNIAKI, OHTUBO, HIROSHI, OMURA, TAKEO, YOSHII, HIROSHI, ISHIKAWA, HIROYUKI, KAWASAKI STEEL CORPORATION, MAEDA, YOSHIAKI, KAWASAKI STEEL CORPORATION, NITTA, MINORU, KAWASAKI STEEL CORPORATION, OGURA, KUNIAKI, KAWASAKI STEEL CORPORATION, OHTUBO, HIROSHI, KAWASAKI STEEL CORPORATION, OMURA, TAKEO, KAWASAKI STEEL CORPORATION, YOSHII, HIROSHI, KAWASAKI STEEL CORPORATION
Applicants: KAWASAKI STEEL CO, KAWASAKI STEEL CORPORATION
Application year: 1993
Main classification: B22F1
IPC codes: C22C33, C22C32