Method for recessed, self aligned, low base resistance structure

Abstract: A semiconductor device is manufactured with precisely formed base and emitter regions. This is accomplished by arranging a plurality of insulator layer portions to form a plurality of windows. A dopant is then applied to the semiconductor device between the windows in order to accurately position emitter regions relative to base regions. In this manner a base of controlled dimensions can be formed. Thus the parasitic resistance of the base can be reduced and the figure of merit (emitter periphery/base area) can be increased.

Description: The present invention relates to semiconductor devices, and more particularly, to a method of manufacturing a semiconductor device having automatically aligned structures. It is known in the semiconductor art that figures of merit may be used to describe the performance of a semiconductor device. One figure of merit of particular interest is defined as the numerical ratio between the emitter periphery (EP) and the base area (BA). By increasing the figure of merit, a device demonstrates improved current handling capability. Thus, a device is able to handle high power with low parasitic capacitance. In addition, such a device is highly suitable for high frequency applications (for example, at radio frequencies). One way of increasing a device's figure of merit is by decreasing the "pitch" or spacing between repetitive patterns, i.e.-emitters. Due to the fact that integrated circuits typically have a planar structure, current that flows from the emitter to the collector typically travels parallel to the surface of the wafer after being transported vertically through the base. This current then flows upward towards a contact located on the wafer surface. Due to the significant resistivity of current-flow paths within the device, parasitic series resistances exist. One such parasitic resistance is the so-called intrinsic base region (R BB ). This resistance is caused by the path length between the base contact and the edge of the injecting emitter region and is related to base sheet resistance. Thus, by decreasing the pitch, or spacing between emitters, the length of the aforementioned path is decreased, resulting in a decreased parasitic resistance in that region. The base area of a device may be readily decreased using appropriate photolithographic processes. However, current photolithographic processes are unable to produce device features smaller than 1 micron (1µm). Although a reduced base area results in an increased figure of merit, a base-area which is too small may lead to poor device performance. In particular, the spacings from base contact to emitter edge are large enough to allow a small amount of depletion so that proper device operation is obtained. Furthermore, if the spacing in selected portions of the device reaches zero, a short may occur, causing the device to become completely inoperative. As an alternative to varying the distances in the intrinsic base region, some investigators have attempted to reduce the parasitic resistance of this region by selectively adding dopants to this region. This has been done in order to increase this region's conductivity. However, if the intrinsic base is doped too heavily a low emitter-base breakdown voltage may result, since this breakdown is a strong function of the high resistivity side of the junction, in this case, the base. In T.Onai et al: 1992 Symposium on VLSI Technology, June 2-4, Seattle pages 54-55, a structure of a bi-polar transistor FRACS (Fully Radiative Current Path Structure) is described. The structures proposed are designed to increase cut-off frequencies which improves the high speed switching performance of the transistors. The maximum cut-off frequency of the transistor is increased by reducing the emitter size and the base width. 2D and 3D FRACS are described which have structures believed to be suitable for future sub 0.1um emitter devices. The devices are fabricated by thin epitaxial layer growth and shallow base formation. EP-A-438693 describes a method of manufacturing a high frequency bi-polar transistor. The semiconductor is made by forming a first oxide film on a semiconductor substrate, forming a nitride film on the oxide film, removing parts of the nitride and oxide films, forming a first polysilicon film of a first conductivity type on the exposed parts, forming a second oxide film on part of the nitride film and the first polysilicon film to surround the first polysilicon film, removing a portion of the nitride film not covered with the second oxide film and a portion of the first oxide film there below to expose a part of the substrate and finally forming a second polysilicon film of a second conductivity type on the second exposed part of the substrate. According to one aspect of the present invention, there is provided a method of manufacturing a semiconductor device, said method comprising the steps of: a) providing a semiconductor wafer which includes a surface region of a first conductivity type; b) providing an insulating layer over a first portion of said surface region; and c) introducing a dopant of a second conductivity type to second portion of said surface region, said second portion of said surface region being different from the first portion of said surface region, characterised by the steps of d) covering selected areas of said second portion of said surface region, wherein each of said selected areas is covered with a respective one of a plurality of insulating layer portions said plurality of insulating layer portions forming a plurality of windows for emitter implantation; e) isotropically etching said surface region to remove portions of said second portion of said surface region to create a plurality of recesses in said surface region such that after etching each of said plurality of recesses has overhanging sections of said insulating layer portions; f) introducing a dopant of said second conductivity type to form a plurality of base regions in said surface region, and g) implanting a further dopant of said first conductivity type exclusively through said plurality of windows to form a plurality of emitter regions, thus ensuring that each of said emitter regions positionally corresponds to one of said plurality of windows and is positionally aligned relative to one of said plurality of base regions, whereby continuous base regions are created between respective emitter regions are remaining portions of said second portion of said surface region. A semiconductor device may thus be manufactured by placing an insulating layer over a portion of a surface region and introducing a dopant to a further portion of the surface region. Selected areas of the further portion of the surface region are covered with insulating layer portions while the uncovered portions of the surface region are isotropically etched to create a plurality of recesses. The insulating layer portions partially overhang the created recesses. A dopant is added to form a base. A further dopant is then added between the overhanging portions of the insulating layer to form a plurality of emitter zones. Figures 1-5, 6A and 7-9 are cross sectional views illustrating a process for forming a bilevel, self aligned, low base resistance structure in accordance with the present invention. Figure 6B is a top view of a semiconductor device at the stage of manufacture illustrated by Figure 6A. Figure 6B additionally indicates exemplary contact connections. Figure 6A is a cross sectional view of Figure 6B taken in the plane X-X'. An exemplary embodiment of the present invention will now be described more fully with reference to Figures 1-9, in which a semiconductor device is shown during successive stages of manufacture. Figures 1-6 show a side view of a relatively large portion of the semiconductor device. Figure 6B shows a top view of the semiconductor device. Figures 7-9 show a relatively close side view of the device, and in particular, provide a detailed view of a portion of the semiconductor device which includes a single emitter. These figures are purely schematic and are not drawn to scale. In particular, the dimensions in the direction of thickness are comparatively strongly exaggerated for the sake of clarity. A semiconductor device can be manufactured in accordance with an exemplary embodiment of the present invention, in the following manner. As shown in Figure 1, the starting material is a semiconductor wafer, in this example of n-type silicon, including n-type epitaxial silicon layer 2 having a thickness of about 5 microns (5µm) and a resistivity of about 1 ohm cm, which is grown on a substrate 1 of highly doped n-type silicon having a resistivity of, for example, .002 ohm cm. The epitaxial growth method is known in the art, and is not described. Other thicknesses and/or dopings are possible and will be chosen by those skilled in the art in accordance with existing conditions. Subsequently, an oxide layer 3 is formed on epitaxial layer 2. Oxide layer 3 in this embodiment is a silicon oxide layer having a thickness of, for example, 1/2 micron (.5µm) and which is formed, for example, by thermal oxidation. Openings 5 are then formed in oxide layer 3 by photolithographic etching. By means of the implantation of boron ions 7 (dose 5 x 10 12 atoms/cm 3 , energy 100 keV), P-minus doping 8 is provided. Oxide layer 3 selectively masks against this implantation. As shown in Figure 2, breakdown enhancement regions 9 are optionally formed inside silicon layer 2 and substrate 1 using well known diffusion techniques. In an exemplary embodiment of the present invention, the wafer is placed in a diffusion furnace so as to diffuse the low conductivity P- diffusion region into the wafer. This diffusion step is preferably performed in a nitrogen and an oxygen environment. During the diffusion step, an oxide coating 6 is formed in previously exposed openings 5. As shown in Figure 3, a photoresist 20 is formed over selected portions of oxide layer 3. The wafer is then subjected to an etching ambient, causing the exposed portions of oxide layer 3 to be removed. The wafer is then subjected to a P+ implant, such as boron-11 B 11 - 5 x 10 15 - 25 KeV, to form P+ region 10. Then, as shown in Figure 4, photoresist 20 is removed and another oxide layer 25 is deposited via low temperature (350 - 400°C) glass deposition. Oxide layer 25 is preferably formed with a thickness ranging from 1500 to 2500 angstroms (150-250nm). As shown in Figure 5, selected portions of oxide layer 25 are then removed, thus exposing the sites at which the emitters will be formed. Thus, selected portions of oxide layer 25 (portions 25 a-z) remain. With oxide portions 25 a-z being used as a plurality of masks, the wafer is subjected to isotropic etching. This is shown in Figure 6A. For the purpose of semiconductor manufacture, surface preparation for the etch is particularly desirable to the generation of a smooth silicon surface for the base and emitter implants. If the surface is damaged, poor radio frequency device performance as well as direct current parameter degradation may result. Furthermore, because it has been determined that the surface prior to etch is desirably exceptionally clean and free of oxide, oxide removal may be accomplished immediately prior to the dry etch step. By subjecting wafer 1 to isotropic etching, portions of P+ region 10 and substrate 2 are removed. Because the etching is isotropic, oxide portions 25 a-z each extend above portions of exposed substrate 1. Thus, oxide portions 25 a-z form a plurality of "overhanging shelves". These shelves define a plurality of windows through which ion implantation may occur. The inventor has found that the dimensions of these shelves can be tightly controlled by using an appropriate etchant. In an exemplary embodiment of the present invention, this etchant is a gas mixture comprising tetrafluoromethane (CF 4 ) halocarbon 13B1 and oxygen (O 2 ) in ratios of approximately 90:5:5 % (by weight). Furthermore, in an exemplary embodiment of the present invention, this etch is accomplished with a Tegal 700 etcher. Using the aforementioned gas mixture, a two part vertical for one part lateral etch ratio is obtained. It is extremely desirable to obtain this type of "sloped" edge to maintain good step coverage for later metalization. After completing the etching step, a base implant is provided to ensure that there is a continuous current path to the remaining portion of silicon layer 2. This continuous current path is extremely desirable because the current flow between the emitter and the base depends on the continuity of the base between the emitter and the P + implant. Furthermore, the base implantation energy is desirably chosen to allow at least partial penetration of the overhanging shelves formed by oxide portions 25 a-z. In a further exemplary embodiment of the present invention, the wafer is treated with a P type doping impurity to diffuse a P-type region 30 into the base site. By diffusing the P-type region, a continuous base is automatically created from the P+ region to the emitter. Furthermore, by using diffusion instead of implantation, a deeper base may be formed in the area not shielded by the shelf. This treatment is particularly desirable for low frequency devices. A top view of the semiconductor device at the stage of manufacture corresponding to Figure 6A is illustrated by Figure 6B. Figure 6B additionally indicates exemplary contact connections. Figure 6A is a cross sectional view of Figure 6B taken in the plane X-X'. Corresponding letters in Figures 6A and 6B are used to refer to corresponding structures. As a next step, n-type (arsenic) ions are implanted to form emitter region 40. This is shown in Figure 7. The portion of the wafer shown in Figure 7 is an enlarged view of the wafer shown in Figure 6. As previously described, the overhanging shelves of oxide layers 25a-z shown in Figure 7 ensure precise positioning (self-alignment) of the emitter peripheries in P + region 30. After removing oxide portions 25 a-z by a dip etch, another oxide layer 50 is deposited. This is shown in Figure 8. Selected portions of oxide layer 50 are then removed (using, for example, photolithography) as shown in Figure 9. In this manner, device isolation is achieved. The base, emitter and P + regions are then driven simultaneously. In another exemplary embodiment of the present invention, the base and P + regions are partially driven prior to implantation of the emitter region. In a still further exemplary embodiment of the present invention, oxide portions 25 a-z are not removed and oxide layer 50 is deposited directly on oxide portions 25 a-z. This is because, for example, discontinuities may result in metalization layers applied above oxide portions 25a-z. In some devices, however, (for example, overlay devices) the non-removal of oxide portions 25 a-z does not substantially effect device performance. By forming a semiconductor device in this manner, the various structures within this device can be carefully aligned. Thus, the intrinsic base region can be formed with a length of approximately 1000 angstroms (100nm), thus resulting in a 40% increase in the maximum frequency capabilities over prior art devices. In addition, the figure of merit of a device formed using the above described method can be as high as 15. This results in an additional 40% increase in maximum frequency capabilities over prior art devices. These increases in frequency capabilities may result in a doubling of gain in the device. This results in a half-octave-improvement in frequency capability (i.e. increasing maximum frequency of operation from 4 GHZ to 6 GHZ for silicon technology). In addition, because of the self alignment features, improved injection uniformity is achieved. Furthermore, the processing steps of the present invention are significantly simplified over that of many prior art devices, thus reducing the number of photoresist, process and high temperature steps. While the invention has been described in terms of an exemplary embodiment, it is contemplated that it may be practiced as outlined above with modifications within the scope of the appended claims.

Claims: A method of manufacturing a semiconductor device, said method comprising the steps of: a) providing a semiconductor wafer which includes a surface region (2) of a first conductivity type; b) providing an insulating layer (3) over a first portion of said surface region; and c) introducing a dopant (10) of a second conductivity type to second portion of said surface region, said second portion of said surface region being different from the first portion of said surface region, characterised by the steps of d) covering selected areas of said second portion of said surface region, wherein each of said selected areas is covered with a respective one of a plurality of insulating layer portions (25a-z) said plurality of insulating layer portions (25a-z) forming a plurality of windows for emitter implantation; e) isotropically etching said surface region to remove portions of said second portion of said surface region to create a plurality of recesses in said surface region such that after etching each of said plurality of recesses has overhanging sections of said insulating layer portions; f) introducing a dopant of said second conductivity type to form a plurality of base regions (30) in said surface region, and g) implanting a further dopant of said first conductivity type exclusively through said plurality of windows to form a plurality of emitter regions (40), thus ensuring that each of said emitter regions (40) positionally corresponds to one of said plurality of windows and is positionally aligned relative to one of said plurality of base regions (30), whereby continuous base regions are created between respective emitter regions and remaining portions of said second portion of said surface region. The method of claim 1 wherein in step e) said etching step is performed using a gas mixture. The method of claim 1 or 2, further comprising the step of removing each of said insulating layer portions (25a-z). The method of any one of claims 1 to 3, further comprising the step of depositing a layer (50) over selected areas of semiconductor device to provide device isolation. The method of any one of claims 1 to 4, wherein in step f) the dopant is introduced by implantation to provide said base regions. The method of claim 5, wherein the dopant is introduced by implantation through said insulating layer portions and through said plurality of windows and the base implantation energy is selected so as to allow at least partial penetration of the portions of said insulating portions (25a-z) overhanging said recesses. The method of any of claims 1 to 4, wherein in step f) semiconductor wafer is treated with a doping impurity of the second conductivity type to diffuse regions of said second conductivity type into base regions. The method of any one of the preceding claims, wherein said plurality of insulating layer portions consist of oxide.

Inventors: IMHAUSER WILLIAM P, IMHAUSER, WILLIAM P.
Applicants: ST MICROELECTRONICS INC, STMICROELECTRONICS, INC.
Application year: 1993
Main classification: H01L21
IPC codes: H01L29, H01L21