ESTERIFIED STARCH COMPOSITION

Abstract: According to the present invention there is provided a composition as obtained from a melt comprising esterified starch, preferably having an amylose content of at least about 50 % by weight with respect to that of the starch, and being substituted to a degree of at least about 1.5. The starch ester may be of the kind obtained by reaction of a mixed acid anhydride with starch. The invention further provides the composition when shaped into articles, and the melt from which the composition is obtained.

Description: ESTERIFIED STARCH COMPOSITION Field of the Invention The present invention relates to degradable polymer compositions capable of being formed by heat and pressure into articles having good dimensional stability and physical properties. These compositions comprise an esterified starch preferably having a degree of substitution of at least about 1.5 and preferably an amylose content of at least about 50%. Background to the Invention It is known that starch may be heated under pressure to form a melt suitable for the production of shaped articles. Such starch-based shaped articles may exhibit the disadvantages of relatively poor physical properties under high relative humidity conditions and a relatively high tendency to embrittlement under relatively low humidity conditions. Attempts to overcome these problems by the replacement of the above mentioned starch by maize starch esters having a low degree of substitution, as commonly found in the starch industry, have generally been unsuccessful, often resulting in weak, brittle, hydrophilic materials having a poor balance of physical properties. It is an object of the present invention to overcome, at least in part, the above mentioned disadvantages. Summary of the Invention According to the present invention there is provided a composition as obtained from a melt comprising esterified starch having a degree of substitution of at least about 1.5. The esterified starch may be selected from the group consisting C 2 to C 22 -starch esters preferably from the group consisting of starch acetates, starch propionates, starch butyrates, starch pentanoates, and starch hexanoates, and mixtures thereof. The starch ester may be a mixed ester, i.e. having different kinds of ester groups attached to the same molecule, as are obtained for example by reaction of starch with a mixed acid anhydride or a mixture of different acid anhydrides. Such a mixed acid anhydride may be for example an acid anhydride made from acetic acid and propionic acid; a mixture of different acid anhydrides may be for example a mixture of acetic acid anhydride and propionic acid anhydride. The esterified starch as used in this invention may be made from a starch as obtained from potatoes, rice, tapioca, corn/ pea, rye, oats, and wheat with the respective known amylose content. However, the amylose content of the starch is preferably at least about 50% by weight with respect to that of the starch. The composition may further include one or more members selected from the group consisting of extenders; fillers; wood derived materials; oxides of magnesium, aluminum, silicon, and titanium; lubricants; mold release agents; plasticisers; stabilisers; colouring agents; flame retardants; boron-containing compounds; alkali and alkaline earth metal salts; thermal stabilisers; and melt flow accelerators; and mixtures thereof. The invention further provides the composition according to this invention when shaped into articles, for example bottles, strands, sheets, films, packaging materials, pipes, cups, rods, laminated films, sacks, bags, pharmaceutical capsules, foams, granulates and powders by a process including injection molding, compression molding, filming, blow molding, vacuum forming, thermoforming, extrusion, extrusion moulding, co-extrusion, foaming, profile extrusion and combinations thereof. The invention still further provides the composition of the present invention in the form of a melt. The invention still further provides a process for forming said melt comprising heating an esterified starch having a degree of substitution of at least about 1.5, optionally in the presence of a plasticiser to an elevated temperature and plastifying the thus heated composition until a uniform melt is obtained. The present invention still further provides the use of an esterified starch having a degree of substitution of at least about 1.5, and preferably also an amylose content of at least about 50% by weight with respect to that of the starch, as a component in a thermoplastic melt. The present invention will be further apparent from the following description taken in conjunction with the accompanying examples and appended claims. Detailed Description of the Invention The present invention provides a composition as obtained from a melt comprising esterified starch having a degree of substitution of substitution of at least 1.5. The esterified starch is selected from the group consisting of C 2 to C 22 starch esters and preferably is a C 2 to C 8 starch esters. It is particularly preferred that the esterified starch is a starch acetate, starch propionate, starch butyrate, starch pentanoate, and/or a starch hexanoate, and/or a mixture thereof. Most particularly preferred are the esters having more than 2-carbon atoms in the alkylcarbonyl residue. The starch ester may be a mixed ester comprising at least two different types of alkylcarbonyl groups (i.e. of different lengths) in the same molecule and as such may be of the kind as obtained by reaction of starch with a mixed anhydride or with a mixture of different acid anhydrides. It is most preferred that such mixed starch esters comprise at least two members selected from the group consisting of acetate, propionate, butyrate, pentanoate, hexanoate, heptanoate and octanoate residues bound to the same molecule. Particularly preferred starch diesters comprise both acetate and propionate groups or both acetate and butyrate groups or both propionate and butyrate groups or both pentanoate and butyrate groups bound to the same molecule. In the case of starch diesters, the ratio of the types of ester groups comprised by the starch ester may vary greatly, but preferably is in the range of about 1:1 to about 1:20. The degree of the total substitution of the esterified starch is from about 1.5 to about 2.9, and it is more preferred that the degree of substitution is from about 1.8 to about 2.9, independent of the type of substitution. The most preferred degree of substitution is from about 1.8 to about 2.5. Examples of starch esters are given in Table 1, Table 1 * Hylon VII is a high amylose corn starch with an amylose content of about 70%, sold by National Starch and, Chemical Co, USA. Examples of mixed starch esters are given in Table 2, Table 2 * = degree of substitution pro'ate = propionate corn** = Hylon VII but'rate= butyrate Within the scope of this invention, any type of commercially available starch to produce the esterified starch may be used such as native starch selected from potatoes, rice, tapioca, corn, pea, rye, oats, maize, barley and wheat. However it is preferred that the amylose content of the starch is at least about 50% and preferably is higher than this, typically being in the range of about 70% by weight with respect to that of the starch. A highly suitable starch is the high amylose genetically modified corn starch, Hylon VII, having an amylose content of about 75%, available from National Starch and Chemical Company of Finderne Avenue, Bridgewater, New Jersey NJ 08807, USA. Such starch is subsequently esterified, e.g. acetylated or propionated to a degree of substitution of at least 1.5. and preferably 1.8. A particularly suitable esterified high amylose starch is Hylon . VII acetylated or propionated, preferably propionated, to a degree of 2.3. Whilst the substituted high amylose starches present in the inventive compositions are thermoplastic per se, ie in the absence of an added plasticiser, the composition may advantageously further comprise a plasticiser by which the melting temperature of the esterified starch may be reduced and the processability thereof improved. The plasticiser may have a molecular weight of less than 2,000, and it is preferred that the molecular weight is between about 100 and about 1,000. Some preferred plasticisers may be summarized by the formula: A(COOR) m (OOCR 1 ) n (I) wherein: A is a saturated or unsaturated aliphatic or alicyclic residue; n is an integer from zero to 8; m is an integer from zero to 6; whereby the sum of m + n is an integer from 1 to 6, and R and R-^ are, independently of each other, a saturated or unsaturated aliphatic or alicyclic residue having from 1 to 20 carbon atoms. In one embodiment of compound (I) , A is a saturated aliphatic residue having 2 to 8 carbon atoms; m is an integer from zero to 4; n is 0, 1, 2 or 3; the sum of m + n is 2 to 4; and R, and R-^ are independent of each other and are alkyl residues having from 1 - 6 carbon atoms. In a more preferred embodiment of compound (I) , A is a saturated aliphatic residue having 2, 3, or 4 carbon atoms; m is an integer from zero to 4; n is 0, 1 or 2; the sum of m + n is 2 to 4; and R and R-^ are independent of each other are alkyl residues having 1, 2 , 3 or 4 carbon atoms. Compound (I) may be an ester derivative of at least one of the following members: i) OH-CH 2 - (C(COOH)H) _-CH 2 OH ii) H00C-CH 2 - (C(COOH)H) r -CH 2 -COOH iii) H00C-CH 2 - (C(COOH)OOCR 2 ) ) -CH 2 -COOH iv) HOOC-CH 2 -CH( (COOH) (COOH)H) v) C(CH 2 COOH) 4 i) (HOCH 2 ) 3 C-0-C(CH 2 OH)3 vii) HO-CH 2 -(CHOH) q -CH 2 OH wherein: q and r are independently of each other 1, 2, 3 or 4 and R 2 is methyl or propyl. Compound (I) may be a methyl, ethyl, propyl, or butyl carboxylate ester of a member selected from the group consisting of: ii) HOOC-CH 2 -(C(COOH)H) r -CH 2 -COOH iii) H00C-CH 2 -(C(C00H) (00CR 2 ) ) -CH 2 -C00H iv) H00C-CH 2 -CH((C00H) (COOH)H) where R 2 is methyl or propyl. In one embodiment of compound (I) it is preferred that the carboxylate ester is a tri-ethyl or tri-butyl carboxylate ester of : HOOC-CH 2 - (C(COOH)OOCR 2 ) -CH 2 -COOH where R is methyl or propyl, and it is most preferred that compound (I) is selected from the group consisting of H 5 C 2 -OOC-CH 2 - (C(COOC 2 H 5 )OOCCH 3 ) -CH 2 -COOC 2 H 5 . and H 9 C 4 -OOC-CH 2 - (C(COOC 4 H 9 )OOCCH3) -CH 2 -COOC H g . Such most preferred compounds are known, and are, for example, sold under the Tradename of Citroflex A-2 plasticisers by Pfizer AG of Fluelastrasse 7, Postfach 2, 8048 Zuerich, Switzerland. Another embodiment of compound (I) takes the form of a mono, di or tri ester of: HO-CH 2 -CHOH-CH 2 OH, viz the mono-, di-, or tri- acetate of glycerol. ■ It is most particularly preferred that compound (I) is the tri-acetate of glycerol, viz: CH 3 C00CH 2 - (CH(OOCCH 3 ) ) -CH 2 OOCCH 3 Compound (I) may also be a diacetate-monopropionate or dipropionate-monoacetate of glycerol or the diacetate or dipropionate of OH-CH 2 -C(COOH)H-CH OH, or it may be selected from the trimethyl ester and tripropyl ester of: HOOC-CH 2 -CH(COOH)COOH. A further preferred plasticiser has the general formula: (II) wherein A is a saturated aliphatic residue having 2 to 8 carbon atoms; x is one or two; y is an integer from zero to 4; z is an integer from zero to 4; the sum of y+ z is 2 to 4; and R and R-^ are independent of each other and are alkyl residues having from 1 - 6 carbon atoms. In a more preferred embodiment of compound (II) , A is a saturated aliphatic residue having 2, 3, or 4 carbon atoms; x is one or two; y is an integer from zero to 4; z is an integer from zero to 4; the sum of y+ z is 2 to 4; and R and R-L are independent of each other are alkyl residues having 1, 2, 3 or 4 carbon atoms. Compound (II) may be an ester derivative of at least one of the following members: i) OH-CH 2 - (CHOH) q -CH 2 OH ϋ) HOOC-CH 2 - (CHOH) r -CH 2 -COOH iii) HOOC-CH 2 - (C(COOH)OH) -CH 2 -COOH iv) HOOC-CH 2 -CH(COOH)OH v) C(CH 2 0H) 4 vi) (H0CH 2 ) 3 C-0-C(CH 2 0H) 3 wherein: q and r are independently of each other 1, 2, 3 or 4. It is preferred that compound (II) is a methyl, ethyl, propyl or butyl carboxylate ester of a member selected from the group consisting of: ii) HOOC-CH 2 - (CHOH) r -CH 2 -COOH iii) HOOC-CH 2 - (C(COOH)OH) -CH 2 -COOH iv) HOOC-CH 2 -CH(COOH)OH It is more preferred that the carboxylate ester is an ethyl or butyl ester, and it is most preferred that the compound is a tri-ethyl or tri-butyl carboxylate ester of: HOOC-CH 2 - (C(COOH)OH) -CH 2 -COOH. Accordingly, the most preferred compounds of formula (II) have the formulae: H 5 C 2 -OOC-CH 2 - (C(COOC 2 H 5 )OH) -CH 2 -COOC 2 H 5 or H 9 C 4 -OOC-CH 2 - (C(COOC 4 H 9 )OH) -CH 2 -COOC 4 H g . Such most preferred compounds are known, and are, for example, sold under the Tradename of Citroflex plasticisers by Pfizer AG of Fluelastrasse 7, Postfach 2, 8048 Zuerich, Switzerland. Other forms of compound (II) for use according to the present invention include the diacetate and dipropionate of: OH-CH 2 -CHOH-CH 2 OH, and the monoacetate-dimethyl ester and mono-acetate • dipropyl ester or mono-propionate-dipropyl ester of: HOOC-CH 2 -CH(COOH)OH. The plasticiser, whether of formula (I) or (II) is present in the composition in an amount of from about 3% to about 60% by weight based on the weight of the composition. It is more preferred that the concentration of such plasticiser is from about 5% to about 30%, and most preferred that the said concentration is from about 8% to about 18% by weight based on the weight of the composition. Other suitable plasticisers include dimethyl phthalate, diethyl phthalate, dibutyl phthalate, dihexyl phthalate, di-2-ethylhexyl phthalate, di-n-octyl phthalate, di- isooctyl phthalate, di-isonyl phthalate, di-isodecyl phthalate, dicyclohexylphthalate, dimethylcyclhexyl phthalate, dimethylglycol phthalate, trichloroethyl phosphate, cresyl di phenyl phosphate, triphenyl phosphate, tri-cresyl phosphate, triacetyl citrate, triethyl acetyl citrate, triethylene glycol di (2-ethylbutyrate) , diacetin, butyl phthalylbutyl glycolate. acetylated monoglycerides, triethyl citrate, diethyl succinate, dimethyl sebacate, tributyl phosphate, di-n-hexyl azelate, di-isooctyl azelate, di- (2-ethylhexyl) azelate, dicapryl adipate, n- ethyl-o,p-toluenesulfonamide, diethyleneglycoledibenzoate, dipropylene glycol dibenzoate and mixtures thereof. Particularly suitable plasticisers are glycerol triacetate, dimethyl sebecate, diethyl succinate, acetyl triethyl citrate, or mixtures thereof, which may be present in the composition in an amount of from about 5 to about 45% by weight with respect to that of the starch ester. The composition may further contain extenders; fillers; wood derived materials; oxides of magnesium, aluminum, silicon, and titanium; lubricants; mold release agents; plasticisers; stabilisers; colouring agents; flame retardants; boro -containing compounds; alkali and alkaline earth metal salts; thermal stabilisers; and melt flow accelerators; and mixtures thereof. The preferred thermal stabiliser and mold release agent are respectively butylated hydroxy toluene and stearyl stearamide which may be present in the composition in amounts respectively of from about 0.01 to about 5% and from about 0.01 to about 2%, by weight with respect to the starch ester component of the composition. In one embodiment of the invention, the composition further comprises a native or chemically modified (non esterified) starch selected from potatoes, rice, tapioca, corn, pea, rye, oats, and wheat. A method of preparing the melt from which the present inventive composition is obtained comprises heating an esterified starch, having a degree of substitution of at least about 1.5, and " preferably having an amylose content of at least about 50% by weight with respect to that of the starch, optionally in the presence of a plasticiser The invention will be further apparent from the following Examples. Example 1 The following formulation is prepared: 1000 grams of Hylon VII starch acetate having a degree of substitution of 2.0; 300 grams of glycerol triacetate; 5 grams of butylated hydroxy toluene and 3 grams of Stearyl Stearamide. The mixture is thoroughly blended in an intensive mixer of the Henschel variety such as is known to the skilled man. Following blending, the mixture is allowed to rest for at least 24 hours. The thus blended mixture is then extruded on a Berstorff twin screw extruder on which a stock temperature of 160°C (320 F) is maintained. The extrudate is then cooled and pelletised. The thus cooled pellets are then placed in the hopper of a 170 CMD Arburg injection moulding machine. The temperature zones are set as follows: Zone 1: 127°C (260 F) Zone 2: 154°C (310 F) Zone 3: 154°C (310 F) and tensile test pieces are produced at an injection molding pressure of about 550 bar. The thus produced test pieces are translucent and exhibit excellent flexibility and toughness. Example 2 The above Example is repeated except that the formulation contains the thermal stabiliser (butylated hydroxy toluene) at a concentration of between 0.05 and 2.0% by weight based on the weight of the starch ester. Similar tensile test pieces likewise having improved properties are produced. Example 3 Example 2 is repeated except that the amount of plasticiser (glycerol triacetate) is varied from 5 to 45% by weight with respect to that of the starch ester in the composition. Similar tensile test pieces likewise having improved properties are produced. Example 4 Example 2 is repeated except that the mold release agent (stearyl stearamide) concentration is increased to 1% by weight with respect to that of the total composition. Example 5 Examples 1 to 4 are repeated except that the degree of substitution of the starch acetate is varied from 1.5 to 2.9. Similar tensile test pieces likewise having improved properties are produced. The above Examples demonstrate the extrusion and injection mouldability of the present inventive compositions, which may be shaped into articles such as bottles, strands, sheets, films, packaging materials, pipes, cups, rods, laminated films, sacks, bags, pharmaceutical capsules, foams, granulates and powders by processes which include injection molding, compression molding, filming, blow molding, vacuum forming, thermoforming, extrusion, extrusion moulding, co-extrusion, foaming, profile extrusion and combinations thereof. It will be appreciated that it is not intended to limit the invention to the above examples only, many variations thereto and modifications thereof being possible to one skilled in the art without departing from scope of the invention, which is defined by the appended claims.

Claims: What We Claim Is: 1. A composition as obtained from a melt comprising esterified starch having a degree of substitution of at least about 1.5. 2. A composition according to claim 1, in which the esterified starch is selected from the group consisting of C 2 to C 22 starch esters. 3. A composition according to either of claims 1 or 2, in which the esterified starch is selected from the group consisting of C 2 to Cg starch esters. 4. A composition according to any preceding claim, in which the esterified starch is selected from the group consisting of starch acetates, starch propionates, starch butyrates, starch pentanoates, and starch hexanoates, and mixtures thereof. 5. A composition according to any preceding claim, in which the starch ester has more than 2 carbon atoms in its alkyl-carbon residue. 6. A composition according to any preceding claim, in which the starch ester been obtained by reaction of starch with a mixed acid anhydride or with a mixture of different acid anhydrides. 7. A composition according to claim 6, in which the starch ester comprises at least two members selected from the group consisting of acetate, propionate, butyrate, pentanoate, hexanoate, heptanoate and octanoate. 8. A composition according to the preceding claim, in which the starch ester comprises both acetate and propionate groups bound to a common starch molecule. 9. A composition according to claim 7, in which the starch comprises both acetate and butyrate groups bound to a common starch molecule. 10. A composition according to claim 7, in which the starch comprises both propionate and butyrate groups bound to a common starch molecule. 11. A composition according to claim 7, in. which the starch comprises both pentanoate and butyrate groups bound to a common starch molecule. 12. A composition according to any one of claims 7 to 11, in which the ratio of the members is about 1:1 with respect to the members. 13. A composition according to any one of claims 7 to 11, in which the ratio of the members is about 1:2 with respect to the members. 14. A composition according to any one of claims 7 to 11, in which the ratio of the members is about 1:3 with respect to the members. 15. A composition according to any one of claims 7 to 11, in which the ratio of the members is about 1:20 with respect to the members. 16. A composition according to any preceding claim, in which the degree of substitution is from about 1.5 to about 2.9. 17. A composition according to any preceding claim, in which the degree of substitution is from about 1.8 to about 2.9. 18. A composition according to any preceding claim, in which the degree of substitution is from about 1.8 to about 2.5. 19. A composition according to any preceding claim, in which the amylose content is at least about 50%. 20. A composition according to any preceding claim, in which the amylose content is at least about 70%. 21. A composition according to any preceding claim, in which the amylose content is at least about 80%. 22. A composition according to any preceding claim, in which the amylose content is at least about 90%. 23. A composition according to any preceding claim, in which the esterified starch has a molecular weight within three orders of magnitude of that of like starch but un- esterified. 24. A composition according to any preceding claim, which further includes a member selected from the group consisting of extenders; fillers; wood derived materials; oxides of magnesium, aluminum, silicon, and titanium; lubricants; mold release agents; plasticisers; stabilisers; colouring agents; flame retardants; boron-containing compounds; alkali and alkaline earth metal salts; thermal stabilisers; and melt flow accelerators; and mixtures thereof. 25. A composition according to any preceding claim, in which a plasticiser is present in an amount of from 5 to 60% by weight with respect to that of the starch ester. 26. A composition according to the preceding claim, wherein the plasticiser has the formula: A(COOR) m (OOCR 1 ) n (I) wherein: A is a saturated or unsaturated aliphatic or alicyclic residue; n is an integer from zero to 8; m is an integer from zero to 6; whereby the sum of m + n is an integer from 1 to 6, and R, and R^ are, independently of each other, a saturated or unsaturated aliphatic or alicyclic residue having from 1 to 20 carbon atoms. 27. A composition according to claim 26, wherein A is a saturated aliphatic residue having 2 to 8 carbon atoms; m is an integer from zero to 4; n is 0, 1, 2 or 3; the sum of m + n is 2 to 4; and R, and R-^ are independent of each other and are alkyl residues having from 1 - 6 carbon atoms. 28. A composition according to claim 26 in which A is a saturated aliphatic residue having 2, 3, or 4 carbon atoms; m is an integer from zero to 4; n is 0, 1, or 2; the sum of m + n is 2 to 4; and R, and R-^ are independent of each other are alkyl residues having 1, 2, 3 or 4 carbon atoms. 29. A composition according to claim 26, in which the plasticiser is an ester derivative of at least one of the following members: i) OH-CH 2 - (C(C00H)H) q -CH 2 0H ii) H00C-CH 2 _ (C(COOH)H) r -CH 2 -COOH iii) HOOC-CH 2 - (C(C00H)00CR 2 ) ) -CH 2 -COOH iv) HOOC-CH 2 -CH( (COOH) (COOH)H) v) C(CH 2 COOH) 4 vi) (HOCH 2 ) 3 C-0-C(CH 2 OH) 3 vii) HO-CH 2 - (CHOH) q -CH 2 OH wherein: q and r are independently of each other 1, 2, 3 or 4 and R 2 is methyl or propyl. 30. A composition according to the preceding claim, in which the plasticiser is a methyl, ethyl, propyl, or butyl carboxylate ester of a member selected from the group consisting of: ii) HOOC-CH 2 - (C(COOH)H) r -CH 2 -COOH iii) HOOC-CH 2 - (C(COOH) (OOCR 3 ) ) -CH 2 "COOH iv) HOOC-CH 2 -CH((COOH) (COOH)H) where R 2 is methyl or propyl. 31. A composition according to the preceding claim, in which the plasticiser is a tri-ethyl or tri-butyl carboxylate ester of: HOOC-CH 2 - (C(COOH)OOCR 2 ) -CH 2 -COOH where R is methyl or propyl. 32. A composition according to the preceding claim , in which the plasticiser is selected from the group consisting of H 5 C 2 -OOC-CH 2 -(C(COOC 2 H 5 )OOCCH 3 ) -CH 2 -C00C 2 H 5 . and H 9 C 4 -00C-CH 2 - (C(COOC 4 H 9 )OOCCH 3 ) -CH 2 -COOC 4 H 9 . 33. A composition according to claim 26, in which the plasticiser is a mono, di or tri ester of: HO-CH 2 -CHOH-CH 2 OH, 34. A composition according to claim 33, in which the plasticiser is the tri-acetate of glycerol, viz: CH 3 C00CH 2 - (CH(OOCCH 3 ) ) -CH 2 OOCCH 3 35. A composition according to claim 26, in which the plasticiser is a diacetate-monopropionate or dipropionate- monoacetate of glycerol or the diacetate or dipropionate of OH-CH 2 -C(COOH)H-CH 2 OH, or the trimethyl ester or tripropyl ester of: HOOC-CH 2 -CH(COOH) COOH. 36. A composition according to claim 25, in which the plasticiser has the formula: A(OH) χ (COOR) y (OOCR 1 ) z (II) wherein: A is a saturated or unsaturated aliphatic or allicyclic residue; x is 1 or 2; y is an integer from zero to 4; z is an integer from zero to 4, whereby the sum of y + z is 2 to 4 and R and R^ are, independently of each other, a saturated or unsaturated aliphatic or alicyclic residue having from 1 to 6 carbon atoms. 37. A composition according to claim 36, in which A is a saturated aliphatic residue having 2, 3, or 4 carbon atoms; x is one or two; y is an integer from zero to 4; z is an integer from zero to 4; the sum of y + z is 2 to 4; and R and R-^ are independent of each other are alkyl residues having 1, 2, 3 or 4 carbon atoms. 38. A composition according to claim 36, in which the plasticiser is an ester derivative of at least one of the following members: i) OH-CH 2 - (CHOH) q -CH 2 OH ii) HOOC-CH 2 - (CHOH) r -CH 2 -COOH iii) HOOC-CH 2 - (C(COOH)OH) -CH 2 -COOH iv) HOOC-CH 2 -CH(COOH)OH v) C(CH 2 OH) 4 vi) (HOCH 2 ) 3 C-0-C(CH 2 OH) 3 wherein: q and r are independently of each other 1, 2, 3 or 4. 39. A composition according to the preceding claim, wherein the plasticiser is a methyl, ethyl, propyl or butyl carboxylate ester of a member selected from the group consisting of: ii) HOOC-CH 2 - (CHOH) r -CH 2 -COOH iii) HOOC-CH 2 - (C(COOH)OH) -CH 2 -COOH iv) HOOC-CH 2 -CH(COOH)OH 40. A composition according to the preceding claim, wherein the plasticiser is a tri-ethyl or tri-butyl carboxylate ester of: HOOC-CH 2 - (C(COOH)OH) -CH 2 -COOH. 41. A composition according to claim 40, wherein the plastiiser has the formula: H 5 C 2 -OOC-CH 2 - (C(COOC 2 H 5 )OH) -CH 2 -COOC 2 H 5 42. A composition according to claim 31, wherein the plasticiser has the formula: H 9 C 4 -OOC-CH 2 - (C(COOC 4 H 9 )OH) -CH 2 -COOC 4 Hg. 43. A composition according to claim 36, in which the plasticiser is the diacetate or dipropionate of: OH-CH 2 -CHOH-CH 2 OH, or the monoacetate-dimethyl ester or mono-acetate-dipropyl ester or mono-propionate-dipropyl ester of: HOOC-CH 2 -CH(COOH)OH. 44. A composition according to claim 25, wherein the plasticiser is selected from the group consisting of dimethyl phthalate, diethyl phthalate, dibutyl phthalate, dihexyl phthalate, di-2-ethylhexyl phthalate, di-n-octyl phthalate, di-isooctyl phthalate, di-isonyl phthalate, di- isodecyl phthalate, dicyclohexylphthalate , dimethylcyclhexyl phthalate, dimethylglycol phthalate, trichloroethyl phosphate, cresyl di phenyl phosphate, triphenyl phosphate, tri-cresyl phosphate, triacetyl citrate, triethyl acetyl citrate, triethylene glycol di (2- ethylbutyrate) , diacetin, butyl phthalylbutyl glycolate, acetylated monoglycerides, triethyl citrate, diethyl succinate, dimethyl sebacate, tributyl phosphate, di-n- hexyl azelate, di-isooctyl azelate, di- (2-ethylhexyl) azelate, dicapryl adipate, n-ethyl-o,p-toluenesulfonamide, diethyleneglycole dibenzoate, dipropylene glycol dibenzoate and mixtures thereof. 45. A composition according to claim 44, in which the plasticiser is dimethyl sebecate, diethyl succinate, acetyl triethyl citrate, or mixtures thereof. 46. A composition according to either of claims 43, 44 or 45, in which the thermal stabiliser and mold release agent are present in the composition in amounts respectively of from about 0.01 to about 5% and from about 0.01 to about 2%, by weight with respect to the starch ester component of the composition. 47. A composition according to any preceding claim, further comprising a native or chemically modified (non esterified) starch selected from potatoes, rice, tapioca, corn, pea, rye, oats, and wheat. 48. The composition of any one of claims 1 to 47, when shaped into articles. 49. Articles, according to claim 48, selected from the group consisting of bottles, strands, sheets, films, packaging materials, pipes, cups, rods, laminated films, sacks, bags, pharmaceutical capsules, foams, granulates and powders. 50. A process for making the articles of claim 49, selected from the group consisting of injection molding, compression molding, filming, blow molding, vacuum forming, thermoforming, extrusion, extrusionmoulding, co-extrusion, foaming, profile extrusion and combinations thereof. 51. The melt from which the composition of any one of claims 1 to 50 is obtained. 52. A melt comprising esterified starch having a degree of substitution of at least about 1.5. 53. A process for forming the melt of claims 51 or 52 comprising heating an esterified starch having a degree of substitution of at least about 1.5, optionally in the presence of a plasticiser to an elevated temperature and plastifying the thus heated composition until a uniform melt is obtained. 54. The use of an esterified starch having a degree of substitution of at least 1.5 as a component in a thermoplastic melt. 55. The use according to the preceding claim, in which the starch has an amylose content of at least about 50% by weight with respect to that of the starch. 56. The use according to either of claims 54 or 55, in which the starch ester has been obtained by reaction of starch with a mixed acid anhydride, or with a mixture of acid anhydrides.

Inventors: BORCHERS GERD, DAKE INGO, DINKELAKER ALBRECHT, LOOMIS GARY, MAUZAC OLIVIER, RIMSA STEPHEN BENEDICT, SACHETTO JEAN-PIERRE, TATARKA PAUL DAVID, ZDRAHALA RICHARD, BORCHERS, GERD, DAKE, INGO, DINKELAKER, ALBRECHT, LOOMIS, GARY, MAUZAC, OLIVIER, RIMSA, STEPHEN, BENEDICT, SACHETTO, JEAN-PIERRE, TATARKA, PAUL, DAVID, ZDRAHALA, RICHARD
Applicants: BORCHERS GERD, DAKE INGO, DINKELAKER ALBRECHT, LOOMIS GARY, MAUZAC OLIVIER, PARKE DAVIS & CO, RIMSA STEPHEN BENEDICT, SACHETTO JEAN PIERRE, TATARKA PAUL DAVID, ZDRAHALA RICHARD, PARKE-DAVIS & COMPANY
Application year: 1993
Main classification: C08B33
IPC codes: C08B33, C08K5, C08L3