Method of forming a photographic colour image

Abstract: Method of forming a photographic colour image which comprises imagewise exposing a photographic silver halide colour material and processing it with an alkaline processing solution in the presence of a sulphonhydrazide colour developing agent and a 3-pyridinol colour coupler optionally containing in the 2-position a ballasting group of such size and configuration as to render the coupler non-diffusible in photographic materials thus forming a dye image by reaction of the oxidised colour developing agent and the colour coupler.

Description: The present invention relates to methods for the formation of photographic colour images in photographic silver halide colour materials. Existing commercial photographic silver halide colour materials form dye images by the reaction of oxidised p -phenylenediamine colour developers with a colour coupler. The colour developing solutions employed contain the colour developing agent and used developer solutions need to be disposed of safely. Attempts have been made to incorporate p -phenylenediamine colour developing agents into silver halide photographic materials but these have had little success largely due to the pronounced staining produced. US Patent 4 481 268 describes the use of certain aryl- and heterocyclic-sulphonhydrazides to produce metallisable azo or azomethine dyes which are subsequently metallised to form light-stable dye images. The use of sulphonhydrazides as colour developers in aqueous colour developer solutions which form an azo dye on coupling with a colour coupler are also described in US Patent 2 424 256 and European Patent O 545 491. A problem encountered with this system is that it is difficult to obtain the desired hue for the magenta image, for example 1-naphtholic couplers give a violet hue. European Patent Specification 0 331 185 A describes a class of 3-pyridinol colour couplers which form cyan dyes with conventional phenylenediamine colour developing agents. There is no suggestion that they will couple with sulphonhydrazide colour developers of any sort. The present invention provides a process in which a class of couplers are used with sulphonhydrazide colour developers to form image dyes of desirable magenta hue. According to the present invention there is provided a method of forming a photographic colour image which comprises imagewise exposing a photographic silver halide colour material and processing it with an alkaline processing solution in the presence of a sulphonhydrazide colour developing agent and a 3-pyridinol colour coupler, thus forming a magenta azo dye image by reaction of the oxidised colour developing agent and the colour coupler, wherein the pyridinol colour coupler has the general formula: wherein R is an alkyl, alkoxy, alkylthio, hydroxy, -NHCONHR 3 , -NHCOOR 3 , alkylamino, arylamino, acylamino, -NHSO 2 R 3 , -SO 2 NHball, -COO-alkyl or -CONHball, any of which may contain further substituents, R 1 and R 2 are each hydrogen or a substituent or together complete a carbocyclic or heterocyclic ring which may be substituted, R 3 is an alkyl or aryl group which may be substituted, ball is a ballast group, and wherein at least one of R, R 1 and R 2 optionally contains a ballasting group of such size and configuration as to render the compound non-diffusible in photographic materials. Advantages of the present invention include being able to photographically generate image dyes of desirable magenta hue without the use of p -phenylenediamine developers and allowing both the coupler and the colour developer to be incorporated in the photographic material. The present invention further provides a colour photographic material comprising at least two colour-forming units sensitive to different regions of she spectrum each comprising a silver halide emulsion layer characterised in that the material contains in or adjacent said layer, a ballasted photographic colour coupler and a ballasted sulphonhydrazide colour developing agent incorporated therein in droplets of a high boiling solvent and wherein the colour coupler is a magenta azo dye-forming 3-pyridinol having the general formula as above. In a preferred embodiment the invention provides a colour photographic material in which the material is a multicolour photographic material comprising a support bearing a yellow dye image-forming unit comprised of at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow azo dye-forming coupler, at least one magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, at least one cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, wherein the magenta dye-forming coupler is an azo dye-forming 3-pyridinol having the general formula as above. Specific examples of substituent groups for R in the above general formula are methyl, trifluoromethyl, ethyl, t-butyl, octadecyl, benzyl and phenyl. Examples of groups that R 1 and R 2 may represent are halogen (eg Cl, Br, F, I), alkyl, aryl, alkylaryl, arylalkyl, heterocyclic, amido, sulphonamido, carbamoyl, sulphamoyl any of which may be substituted, or together complete a benzene, naphthalene, pyridine or thiophene ring, which may be substituted. All the substituents referred to above should, as the skilled man will readily recognise, be compatible with the function of the compound. The azo dye is formed as illustrated below: wherein R 4 -NHNHSO 2 R 5 represents the sulphonhydrazide developing agent. The sulphonhydrazide colour developing agent may have the formula: R 4 -NHNH-SO 2 -R 5 wherein R 4 is an aryl or heterocyclic group which may be substituted, and R 5 is an alkyl or aryl group, either of which may be substituted, and wherein R 4 or R 5 contains a ballasting group of such size and configuration as to render the compound non-diffusible. A preferred group of developing agents of formula (2) are those in which R 4 is a heterocyclic group. Examples of R 4 are benzoxazole, benzothiazole, benzimidazole, naphthoxazole, naphthothiazole, naphthimidazole, quinoline and quinoxaline radicals, and preferably a 4-quinazolinyl group. Examples of R 5 include alkyl, aryl, alkylaryl, arylalkyl or heterocyclic any of which may be substituted. The coupler and the colour developer may be incorporated in the photographic silver halide material or the developer. If incorporated in the material, the compound should have a ballasting group of such size and configuration to render it non-diffusible in the photographic material or be in the form of a polymeric coupler. The ballast group may be attached to couplers of formula (1) by forming part of R, R 1 or R 2 . The ballast group in the sulponhydrazides of formula (2) may be attached by forming part of either R 4 or R 5 . As is conventional with colour couplers, the coupler and the developing agent may be incorporated in the photographic material in droplets of high boiling coupler solvent. The high boiling solvent used to incorporate the coupler and/or colour developer in the photographic material may be any solvent known as a coupler solvent (and used for incorporating couplers into photographic materials). Many such solvents are listed in Research Disclosure Item 308119, December 1989 published by Kenneth Mason Publications, Emsworth, Hants, United Kingdom. The coupler and colour developer may be incorporated in the same or different droplets of coupler solvent. The pyridinol couplers used in the present invention may be prepared as described in "Pyridine and its Derivatives", Supplement Parts 1 and 3 (1974), ed. R A Abramovitch, Wiley Interscience, New York. Examples of 3-pyridinol couplers of formula (I) are listed in the following table: The fastness of the image dyes may be increased by coating a tertiary or quaternary amine at 25-50% molar laydown of coupler. An exemplary compound has the formula: Many examples of suitable sulphonhydrazide colour developers are listed in European Patent O 545 491. Specific examples include the following: The present photographic materials, after imagewise exposure, may be processed by treatment in an alkaline solution. In such a process oxidised colour developer forms in areas of silver halide development and the oxidised form of the developer couples with the coupler to form image dye. In a preferred embodiment, the alkaline solution contains an electron transfer agent (ETA), for example a pyrazolidinone. A specific ETA that may be used is 4-hydroxymethyl-4-methyl-1-phenylpyrazolidin-3-one. The following Examples are included for a better understanding of the invention. EXAMPLE 1: Synthesis of Coupler 1 2-Amino-3-pyridinol (2.2g, 0.02 mole) was dissolved in THF (200m) together with a small quantity of DMF (15ml) to aid solubility. Pyridine (5ml) was added followed by the dropwise addition of freshly prepared ballast acid chloride (Compound 1) (10.0g, 0.02 mole) dissolved in THF (30ml). After stirring for 1 hour at room temperature, THF was removed under reduced pressure and the residual oil extracted into ethyl acetate (250ml). The solution was washed successively with dilute hydrochloric acid and a solution of sodium hydrogen carbonate. After drying the ethyl acetate solution over magnesium sulphate, solvent was removed in vacuo to give the crude product. Silica gel column chromatography eluting with a 3:2 60/80 petrol-ethyl acetate mixture, gave Coupler 1 as a colourless oil which crystallised on standing to an off-white solid. Trituration with 60/80 petrol gave the coupler as a white solid, 6.5g (60%). Found: C, 63.5; H, 8.0; N, 7.7; S, 5.7% C 29 H 45 N 3 O 5 S Req: C, 63.6; H, 8.3; N, 7.7; S, 5.9% HPLC gave 100% purity Mass gave the desired MH + at 548 m/z. Both IR and NMR were also consistent. The other couplers listed in Example 2 may all prepared in a similar manner. EXAMPLE 2 In this Example, the testing was done as described below. Dispersions The coupler dispersions used contained (w/w) 6.0% gelatin, 8.8% coupler, 1 molar equivalent of developer, and coupler solvents in the ratio coupler: tricresylphosphate : 2-(2-butoxyethoxy)ethyl acetate 1.0 : 0.5 : 1.5. The dispersions were washed for 6 hours at 4°C. Coatings The coupler/developer dispersions were coated with a (green-sensitised) silver bromoiodide emulsion in the following format: Gel supercoat Gelatin 1.5gm -2 Emulsion Layer Silver bromoiodide 1.61gm -2 Coupler (+dev) 1.04mmol m -2 Gelatin 2.42gm -2 Bis(vinylsulphonyl)methane (hardener) 0.06gm -2 Support Cellulose Acetate The coatings were slit and chopped into 30cmx35mm strips and exposed (0.1 sec, DL V + WR 9 filters) and processed through the following sequence, using an activator solution of the given composition: Processing Sequence at 37.8°C Activator 2.5 min Wash 1.0 min Bleach 4.0 min Wash 2.0 min Fix 4.0 min Wash 2.0 min Base Dip 1.0 min Activator Solution Na 2 CO 3 26.5 g/l NaHCO 3 6.3 Na 2 SO 3 2.0 NaBr 1.0 4-hydroxymethyl-4-methyl-1-phenylpyrazolidin-3-one 0.2 Water to 1.0 l pH = 10.4 The post-process base dip (pH 10.4 solution - Na 2 CO 3 26.5 g/l and NaHCO 3 6.3g/l) is required to obtain the full-coloured anionic form for the magenta azo dye. A coating was made as described above using the Couplers identified below (with reference to Table 1) with developer D3 described above. In the table of results below, D max is the Status M green density, λ max, and λ 1/2 are in nm. λ 1/2 is measured at the mid point of a horizontal line drawn inside the absorption curve at the half bandwidth (Hbw) level and indicates the symmetry of the curve; the size of the difference between λ max and λ 1/2 , indicates increasing asymmetry. The control coupler had the formula: Coupler D max λ max λ 1/2 Hbw Hue 1 1.05 546 527.5 146 Magenta 2 0.68 530 532 141 Magenta 3 0.60 530 528 136 Magenta 4 1.30 542 525.5 148 Magenta 5 0.33 552 -- -- Magenta 6 0.58 558 521 149 Magenta Control 1.35 566 546 145 Violet It can be seen from the table that couplers of the present invention provide useful magenta azo dye images when oxidatively coupled with quinazoline sulphonhydrazide developers. The wavelength of maximum absorption (λ max ) and (λ 1/2 ) show that the dyes formed have much more desirable spectral properties than the control. In addition with a tertiary amine of the formula: at 35% molar laydown of the coupler a more stable dye image was obtained, although the 1 min post-process base dip was still required.

Claims: A method of forming a photographic colour image which comprises imagewise exposing a photographic silver halide colour material and processing it with an alkaline processing solution in the presence of a sulphonhydrazide colour developing agent and a 3-pyridinol colour coupler thus forming a magenta azo dye image by reaction of the oxidised colour developing agent and the colour coupler, wherein the pyridinol colour coupler has the general formula: wherein R is an alkyl, alkoxy, alkylthio, hydroxy, -NHCONHR 3 , -NHCOOR 3 , alkylamino, arylamino, acylamino, -NHSO 2 R 3 , -SO 2 NHball, -COO-alkyl or -CONHball, any of which may contain further substituents, R 1 and R 2 are each hydrogen or a substituent or together complete a carbocyclic or heterocyclic ring which may be substituted, R 3 is an alkyl or aryl group which may be substituted, ball is a ballast group, and wherein at least one of R, R 1 and R 2 optionally contains a ballasting group of such size and configuration as to render the compound non-diffusible in photographic materials. A method as claimed in claim 1 in which said substituents are methyl, trifluoromethyl, ethyl, t-butyl, octadecyl, benzyl or phenyl. A method as claimed in either of the preceding claims wherein a ballasting group is contained in R. A method as claimed in any of claims 1 to 3 in which R 1 and R 2 are each halogen, alkyl, aryl, alkylaryl, arylalkyl, heterocyclic, amido, sulphonamido, carbamoyl, sulphamoyl any of which may be substituted or, together complete a benzene, naphthalene, pyridine or thiophene ring which may be substituted. A method as claimed in any of claims 1 to 4 in which the sulphonhydrazide developing agent has the general formula: R 4 -NHNH-SO 2 -R 5 wherein R 4 is an aryl or heterocyclic group which may be substituted, and R 5 is an alkyl, aryl or heterocyclic group, any of which may be substituted, and wherein R 4 or R 5 contains a ballasting group of such size and configuration as to render the compound non-diffusible. A method as claimed in any of claims 1 to 5 in which both the coupler and the developing agent are incorporated in the photographic material. A method as claimed in any of claims 1 to 6 in which the coupler and the developing agent are incorporated in the photographic material in droplets of a high boiling coupler solvent. A method as claimed in claim 7 in which both the coupler and the developing agent are co-dispersed in the same coupler solvent droplets. A colour photographic material comprising at least two colour-forming units sensitive to different regions of the spectrum each comprising a silver halide emulsion layer characterised in that the material contains in or adjacent said layer, a ballasted photographic colour coupler and a ballasted sulphonhydrazide colour developing agent incorporated therein in droplets of a high boiling solvent and wherein the colour coupler is a magenta azo dye-forming 3-pyridinol of general formula as defined in claim 1. A colour photographic material as claimed in claim 9 wherein the colour coupler is as defined in any of claims 2 to 4. A colour photographic material as claimed in either of claims 9 and 10 wherein the sulphonhydrazide developing agent has the general formula (2) as defined in claim 5. A colour photographic material as claimed in any of claims 9 to 11 in which the material is a multicolour photographic material comprising a support bearing a yellow dye image-forming unit comprised of at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, at least one magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler at least one cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, wherein the magenta dye-forming coupler is an azo dye-forming 3-pyridinol of general formula as defined in claim 1.

Inventors: CLARKE DAVID, STANLEY PAUL LOUIS REGINALD, CLARKE, DAVID, STANLEY, PAUL LOUIS REGINALD, Clarke, David, c/o Kodak Limited, STANLEY, PAUL LOUIS REGINALD, C/O KODAK LIMITED
Applicants: EASTMAN KODAK CO, KODAK LTD, EASTMAN KODAK COMPANY, KODAK LIMITED
Application year: 1993
Main classification: G03C7
IPC codes: G03C7, G03C1