METHOD FOR REBURNING OF LIME SLUDGE IN FLUIDISED BED AND ARRANGEMENT FOR PERFORMANCE OF THE METHOD

Abstract: The invention relates to a method for lime sludge reburning in a fluidising bed. The method is characterized in that a cooling medium (10) is injected immediately above the fluidising bed (3). The invention also comprises means for performing the method. The arrangement which is known per se is provided with an injection device (10) for a cooling medium above the fluidising bed (3).

Description: TITLE: Method for reburning of lime sludge in fluidized bed and arrangement for performance of the metnoα TECHNICAL FIELD: The present invention relates to a method for reburning or calcining lime sludge in a fluidising bed, whereby the calcium carbonate which is formed when preparing pulping liquor for the production of paper pulp according to the sulphate method is calcined to calcium oxide. The invention also comprises an improved fluidising reactor for the performance of the method. STATE OF THE ART: Reburning or calcining of so-called lime sludge which has been formed during the preparation of pulping liquor for the production of paper pulp according the sulphate method is necessary for recovering the lime or the calcium oxide which is intended to be reused when preparing new batches of pulping liquor. This lime sludge reburning means that the lime sludge is heated to about 900°C whereby carbon dioxide is released and calcium oxide is formed. The heating usually occurs by direct contact with fumes from burning of liquid, solid or gaseous combustibles. The lime sludge reburning is normally carried out according to one of three technical methods, namely in a rotating tube-type furnace, in a fluidising bed or as suspension calcining. In a fluidising bed the lime sludge intended to be reburnt which is present as a very fine powder having a mean size of 20 μm, is fed into the hot bed where the calcining occurs, whereupon the thus formed calcium oxide particles bake into granules having a size of approximately 2-20 mm and sink down in the bed wherefrom they are taken out at the bottom level in a suitable way. The exiting hot calcium oxide granules are fed concurrently to the incoming combustion air to preheats the air to 300°C for example. THE PROBLEM: A part of the fine material which is fed into the fluidis¬ ing bed will not however be baked with other particles and will therefore follow the hot fumes upwards above the bed. There, some of these particles will come into contact with the walls of the reactor, which is somewhat cooler than the heating zone itself, and the particles will therefore bake to the walls. The temperature of these walls can be within the range 600-800°C, which is the critical baking range for calcium oxide which is the dominant part of the particle mass. This covering is very hard and must of course be removed from time to time. In the wall areas of the reactor bed itself, however no mentionable baking occurs on the walls due i.a. to the fact the granules which have been formed and move along the walls tend to keep these clean. There has therefore long been a strong desire to be able to perform the lime sludge reburning in a fluidised bed in such a way that these hard coverings above the bed itself are avoided. THE SOLUTION: According to the present invention the above problem has been solved by bringing about a method for lime sludge reburning in a fluidising bed using hot gases as a fluidising medium which is characterized in that a cooling medium is injected immediately above the fluidising bed. According to the invention, it is suitable that the fluidising gas consists of fumes. The cooling medium which ca suitably be used in accordance with the invention is lime sludge that is to be reburnt. It is forseeable that the whole amount of lime sludge which is to be reburnt is added as cooling medium. According to the invention, it is possible by means of the cooling medium to control the temperature in the area above the fluidising bed and keep this at a temperature below about 600°C, preferably at about 500°C. According to the invention the temperature in the fluidi¬ sing bed should be below 1000°C, preferably about 875°C. The solid material in the gases above the fluidising bed should according to the invention, be separated in for instance a cyclone and thereafter fed into the fluidising bed. The invention also comprises an arrangement for performing the above method, which arrangement comprises a fluidising reactor for lime sludge reburning which is known per se and which is characterized in that in the area above the fluidising bed it is provided with an injection arrangement for a cooling medium, preferably a so-called splash plate. FIGURE DESCRIPTION: The invention will be described in the following in more detail in connection with the attached figure which schematically shows a fluidising reactor according to the invention. PREFERRED EMBODIMENT: In the figure a fluidising reactor 1 for lime sludge reburning is shown. This reactor, which can have a height of 6-10 m, is provided in its bottom part with nozzles 2 for feeding of a fluidising medium. This medium can consist of hot fumes or oil and air whereby the oil is burnt in the fluidising reactor and the air creates the high temperature necessary which should be below 1000°C, preferably 875°C. Above the nozzles 2 a fluidising bed floats which consists of small and large pellets (2-20 mm) of calcium oxide and smaller freshly added particles which have not yet baked together. The large particles eventually sink and are removed at a suitable location through an opening 4 near the bottom part of the reactor 1. At the upper part, of the reactor 1 an outlet pipe 5 is provided for the fluidising medium and light calcined material. The light material is separated in the cyclone 6 and the fluidising medium leaves the cyclone at the exit 7. The separated material in the cyclone 6 is fed into the reactor 1 at its lower part directly into the fluidising bed through the supply pipe 8. Above the fluidising bed 3 in the so-called free board 9, a supply arrangement 10 for cooling medium has been arranged. This cooling medium can according to the inven¬ tion consist of non-treated lime sludge, but can also consist of some other material, both solid, liquid and gaseous material. The importance of the addition of this cooling medium is that the temperature above the fluidising bed 3 is quickly cooled down to a suitable temperature, in the present case about 500°C. The content of solid particles in the fumes which rise from the bed is namely in a dominating amount calcium oxide and these have a baking temperature of between 600°C and 800°C. By addition of a cooling medium, it is consequently possible to quickly lower the tempera¬ ture above the bed 3 so that it drops below the baking temperature, preferably down to about 500°C. In this manner baking of the fine particles on the walls of the reactor is avoided and instead they travel upwards and are then fed via the supply pipe 8 after the separation in the cyclone 6 into the fluidising bed. It is possible to add the whole amount of lime sludge which is to be reburnt as cooling medium at 10 but if it is desired to have a higher tempera- ture only a part can of course be added. The temperature can also be controlled by the temperature of the cooling medium itself. This temperature is about 150°C for non- treated lime sludge as the lime sludge comes from a drying arrangement. If only a part of this lime sludge is added above the bed at 10, the rest can be fed directly into the fluidising bed 3, for example through the pipe 8 which then also must be connected to some lime sludge container. The supply arrangement 10 for the cooling medium can be of a different kind but it is suitable that it consists of a so-called splash plate. The cooling medium is suitably sprayed into the free board 9 by means of air or some other gas. A disadvantage with lime sludge reburning in a fluidising bed compared to rotating tube type furnaces is that the lime sludge which is fed into the reaction zone is not preheated, which makes the consumption of combustion higher than for rotating furnaces. In the present case, when the lime sludge is wholly or completely injected in the free board, it will be heated and the lime sludge which has been separated in the cyclone and fed into the fluidising bed 3 will be heated to about 500°C. This implies a substantial decrease of the consumption of combustibles compared to reburning in a reactor having the whole amount of the lime sludge fed directly into the fluidising bed 3 without preheating. By means of the present invention it has accordingly by simple been posible to improve a method which is known per se measures and make this more economic partly by avoiding covering of the inner walls of the free board, partly by improved heat economy. The invention is not limited to the shown embodiments, but can be varied in different ways within the scope of the claims.

Claims: CLAIMS: 1. Method for lime sludge reburning in a fluidising bed using hot gases as a fluidising medium, c h a r a c ¬ t e r i z e d i n that a cooling medium (10) is injected immediately above the fluidising bed (3) . 2. Method according to claim 1, c h a r a c t e ¬ r i z e d i n that the fluidising gas consists of fumes. 3. Method according to claim 1, c h a r a c t e ¬ r i z e d i n that the cooling medium (10) consists of lime sludge which is to be reburnt. 4. Method according to any of the claims 1-3, c h a r a c t e r i z e d i n that the whole amount of lime sludge which is to be reburnt is added as a cooling medium (10) . 5. Method according to any of the claims 1-4, c h a r a c t e r i z e d i n that the temperature in the area (9) above the fluidising bed (3) is cooled to a temperature of below about 600°C, preferably about 500°C. 6. Method according to any of the claims 1-5, c h a r a c t e r i z e d i n that the temperature in the fluidising bed (3) is below 1000°C, preferably about 875°C. 7. Method according to any of the claims 1-6, c h a r a c t e r i z e d i n that the solid material in the gases above the fluidising bed (3) is separated in for example a cyclone (6) and is fed into the fluidising bed (3). 8. Arrangement for performing the method according to any of the claims 1-7, comprising a fluidising reactor (1) for lime sludge reburning which is known per se, c h a r a c t e r i z e d i n that in the area (9) above the fluidising bed (3) it is provided with an injection device (10) for the cooling medium, preferably a so-called splash plate.

Inventors: HANSON CHARLOTTA, WIMBY MARTIN, HANSON, CHARLOTTA, WIMBY, MARTIN
Applicants: GOETAVERKEN ENERGY AB, HANSON CHARLOTTA, WIMBY MARTIN, HANSON, CHARLOTTA, WIMBY, MARTIN
Application year: 1993
Main classification: D21C11
IPC codes: D21C11, F23G5, F23G7