AQUEOUS DISPERSION USEFUL IN COATINGS CONTAINING HYDROLYZED CELLULOSE ESTER AND ACRYLIC RESIN

Abstract: A stable aqueous dispersion and process for making the dispersion are provided containing hydrolyzed cellulose ester, organic solvent, water and acrylic resin having free acid functionalities that are at least partially neutralized. The dispersion can also contain surfactant and cross-linking agent.

Description: AQUEOUS DISPERSION USEFUL IN COATINGS CONTAINING HYDROLYZED CELLULOSE ESTER AND ACRYLIC RESIN Field of the Invention The present invention relates to novel coating compositions containing hydrolyzed cellulose esters and acrylic resins. More particularly the present invention relates to aqueous dispersions that are stable over long periods of time containing a hydrolyzed cellulose ester and an acrylic resin that has free acid functionalities that are at least partially neutralized. Background of the Invention Cellulose esters are valuable polymers which are useful in many plastic, film, coating and fiber applications. In coatings applications, cellulose esters are generally applied from organic solvent solutions. Because of health and environmental concerns from volatile organic content (VOC) of solvent based coatings, water based coatings are becoming more in demand. There are waterborne coating formulation available containing polyesters and acrylics, but few contain cellulose esters due to their hydrophobic nature making them difficult to disperse or emulsify. When applied from organic solvent solutions as wood, leather, and metal coatings, cellulose esters impart desired properties such as, improved pigment dispersions, improved metallic flake orientation, improved solvent release, and higher gloss coatings. Cellulose esters also function as an excellent rheology control agent in solvent coating formulations. It would be very desirable to incorporate these excellent properties of cellulose esters into waterborne coating systems. Previous attempts to produce a water dispersible cellulose ester coatings system have involved oxidation of cellulose ester, grafting of acrylic acid to cellulose esters, and reaction of anhydrides such as phthalic anhydride or succinic anhydride with the hydrolyzed cellulose esters to provide modified cellulose esters containing free carboxyl groups such as disclosed in the following U.S. Patents; U.S. 4,435,531; U.S. 4,590,265; U.S. 4,960,814; U.S. 4,252,697. However, these processes are complicated resulting in expensive aqueous dispersion. It would, therefore, be very desirable to be able to easily produce aqueous dispersions containing unmodified cellulose esters. Other cellulose ester systems used in water based coating are disclosed in U.S. 3,318,714 (describing pigment dispersions in a cellulose acetate butyrate lacquer systems) and U.S. 3,220,865 (describing an emulsion coating composition based on cellulose acetate butyrate, and plasticizers) . In addition to low VOC, stability of the dispersion is an important feature for these aqueous dispersions to be useful in coatings applications. Many aqueous dispersions, including those of low VOC, are not able to be stored for long periods of time without constant stirring. It would, therefore, be very desirable to be able to produce stable aqueous dispersions of cellulose esters, particularly ones that are stable over long periods of time. It is even more desirable to be able to produce stable aqueous dispersions that are low in VOC. Summary of the Invention The dispersion composition of the present invention comprises: (a) 3 to 50 weight percent, hydrolyzed cellulose ester based on total solids, (b) 5 to 95 weight percent acrylic resin, based on total solids, having free acid functionality that is at least partially neutralized; (c) 0 to 10 weight percent surfactant based on total solids; (d) 50 to 200 parts organic solvent per 100 parts hydrolyzed cellulose ester; and (e) an amount of water to render the dispersion usable in coating applications; wherein the total solids content (a) , (b) , and (c) is 10 to 50 weight percent. The process for producing the aqueous dispersion according to the present invention comprises: (1) dissolving 100 parts hydrolyzed cellulose ester in 50 to 200 parts of a suitable organic solvent to form a solution, wherein the final amount of hydrolyzed cellulose ester is 3 to 50 weight percent of the total solids; and (2) vigorously mixing water into said solution to form a dispersion wherein the mixing and amount of water are sufficient to render the dispersion usable in coating applications; wherein 0 to 10 weight percent surfactant, based on total solids, is present in the solution prior to step (2) and 5 to 95 weight percent acrylic resin, based on total solids, is present in the dispersion having free acid functionality that is at least partially neutralized prior to contacting with water. Detailed Description of the Invention Applicants have discovered inexpensive aqueous dispersions containing hydrolyzed cellulose esters and acrylic resins that are relatively stable over long periods of time. Additionally, the applicants have discovered that these aqueous dispersions containing hydrolyzed cellulose esters and acrylic resins provide excellent coatings for many substrates such as metal, wood, plastics, etc. The dispersion compositions of the present invention generally have from 3 to 50 weight percent hydrolyzed cellulose ester, based on the total solids. The amount of hydrolyzed cellulose ester is preferably 5 to 30 weight percent with an amount of 10 to 20 weight percent being most preferred. An adequate amount of hydrolyzed ester is required to result in a dispersion that has good stability and good film forming ability. Adequate amounts of hydrolyzed cellulose ester also increase the drying characteristics and improve the gloss of the final coating. Thus amounts of hydrolyzed cellulose ester below 3 weight percent based on total solids do not significantly improve the quality of the dispersion whereas amounts much over 50 weight percent based on the total solids reduce the amount of acrylic resin present lowering the strength and hardness of the resulting dried and/or cured coating. Applicants have discovered that the hydroxyl content contributes to the solubility/dispersability of the hydrolyzed cellulose ester and contributes to the overall stability of the dispersion. The unsubstituted hydroxyl content of the hydrolyzed cellulose ester is generally within the range of 0.5 to 25 weight percent preferably 1 to 15 weight percent based on the unit molecular weight of the hydrolyzed cellulose ester (unit molecular weight means the molecular weight of an anhydroglucose unite of a cellulose ester containing the appropriate acyl substituents) . However, the hydrolyzed cellulose ester more preferably has a relatively high hydroxyl content. Hydrolyzed cellulose esters having a hydroxyl content greater than 3 unit molecular weight percent provide improved solubility and stability to the resulting dispersion. Higher unsubstituted hydroxyl content in the hydrolyzed cellulose ester are better in that the resulting dispersion is more stable. The most preferred hydroxyl content is between 6 and 9 weight percent. The higher amounts are preferred, however amounts much over 9 weight percent are impractical due to cost, longer reaction times, and yield. Hydrolyzed cellulose esters having good solubility in common organic solvents can be prepared as generally disclosed in U.S. Patent 2,834,776. Applicants have discovered that hydrolyzed cellulose esters having higher unit hydroxyl contents provide more stable aqueous dispersions. The higher unit hydroxyl content can be prepared by increasing the hydrolysis residence time thereby increasing the final unit hydroxyl content. The preparation of cellulose esters or mixed esters of cellulose such as cellulose acetate butyrate (CAB) , cellulose acetate propionate (CAP) etc. are known (C.J. Malm, G.D. Hiatt in E. ott, H.M. Spurlin, and M. W. Graffin, Ed., cellulose derivatives, Part II, 2nd Edition Interscience, New York, 1954, PP.763—824). Examples of suitable cellulose esters include CAP, CAB, cellulose acetate valerate (CAV) , cellulose acetate isovalerate (CAIV) , cellulose acetate propionate butyrate (CAPB) , and the like, with CAB being most preferred. The CAB preferably has a butyryl content of 17 to 57 unit molecular weight percent, more preferably 25 to 55, with a butyryl unit molecular weight percent content of 35 to 50 being most preferred. The higher butyryl contents are better, however amounts much over 50 unit molecular weight percent begin to reduce the content of the hydroxyl. The CAB can have various degrees of acetylation and the amount of acetyl can be 0 to 34 unit molecular weight percent depending on what remains after hydrolysis. However, this amount of acetyl is preferably 0.5 to 16, more preferably 0.5 to 7 unit molecular weight percent with an amount below 2 unit molecular weight percent being most preferred. Lower amounts of acetyl are preferred due to the desirability of having higher amounts of butyryl and hydroxyl, however amounts below 0.5 percent are difficult to obtain. A most preferred example of CAB used in the present invention is CAB—555—0.04 available from Eastman Chemical Company (ECC) . In this example of CAB the first two digits represent the degree of butyryl group content in unit molecular weight percent before hydrolysis (after hydrolysis the butyryl content is generally below 50 percent) , and the third digit represents the number of hydroxyl groups per four anhydroglucose units in the cellulose ester molecule. The number after the second hyphen indicates the viscosity in seconds measured by the method described in ASTM-D-1343-54T. The molecular weight of the cellulose esters used in the present invention preferably ranges from 10,000 to 80,000 polystyrene equivalents as determined by gel— permeation—chromatography method. The molecular weight is more preferably 10,000 to 30,000 with a molecular weight of 10,000 to 20,000 being most preferred. The aqueous dispersion composition of the present invention has a acrylic resin content of 5 to 95 wt. % based on the total weight of solids. This amount of acrylic resin is preferably 30 to 70 weight percent with an amount of 40 to 60 weight percent being most preferred. Suitable examples of acrylic resins that are useful in the present invention are copolymers containing acrylic acid, methacrylic acid, hydroxyethylmethacrylate, and the like, including vinyl monomers thereof. The acrylic resins used in the dispersion composition of the present invention have free acid functionalities. However, these free acid functionalities are at least partially neutralized in the final dispersion composition. The acrylic resins are partially neutralized to be able to form ionic dispersions in the resulting dispersion composition. Acrylic resins preferably have an acid number prior to partial neutralization of 10 to 80, more preferably 40 to 60 with an acid number of 50 to 60 being the most preferred. The acrylic resins are preferably neutralized by 5 to 100 %, preferably 10 to 80 % with a neutralization percent of 10 to 30 being most preferred. The acrylic resins are preferably neutralized using amines. Suitable amines include diethylaminoethanol, dimethylaminoethanol, N,N-dimethylethylamine, 2— dimethylamino—2-methyl—1-propanol, triethyla ine, and the like, with dimethylaminoethanol being most preferred due to availability and effectiveness. The amount of surfactant used in the present invention is 0 to 10 t. , based on the total solids. The amount of surfactant used in the present invention is preferably at least 0.1 weight percent, more preferably 1 to 8 weight percent, with a surfactant content of 3 to 5 weight percent, based on total solids, being most preferred. Surfactants used in the present invention include ionic and nonionic surfactants. The ionic surfactants include anionic and cationic surfactants which are well known in the art. The more preferred surfactants are the nonionic surfactants. Suitable examples of nonionic surfactants include ethoxylated mono— and polyhydric alcohols and ethylene oxide/propylene oxide block copolymers. A cross—linking agent can also be included in the dispersion of the present invention to improve the coating properties of the final cured coating such as film toughness, scratch resistance, water resistance, and solvent resistance. The preferred cross—linking agents used in the aqueous dispersions of the present invention include methylolated urea and triazine derivatives, and expoxide and formaldehyde—containing compounds, more preferably methylolated cyclic urea and aminotriazine compounds, with Cymel 373(a melamine cross—linking agent produced by American Cyahamid Company) being most preferred. The preferred cross- linking agent concentrations are 5 to 60 weight percent, more preferably 20 to 50 weight percent, with 30 to 40 weight percent, based on the solids content of the dispersion being, the most preferred. The amount of organic solvent and any cosolvent used in the dispersion composition of the present invention is 50—200 parts organic solvent per 100 parts hydrolyzed cellulose ester, preferably 50 to 150 parts, more preferably a concentration of 50 to 100 parts organic solvent per 100 parts hydrolyzed cellulose ester. In certain instances, it is desirable to include a cosolvent with the solvent to form a mixture of solvent and cosolvent. The amount of cosolvent is preferably 10 to 80 parts, more preferably 20 to 60 parts, with 30 to 50 parts per 100 parts solvent or solvent mixture being most preferred. Suitable solvents include cyclohexanone, methylethylketone, acetone, methylamylketone, ethylacetate, propylacetate, butylacetate, ethylene glycol onobutylether, ethylene glycol monopropylether, ethylene glycol monoethylether, propylene glycol monomethylether and the like. The more preferred solvents are ethylene glycol monobutylether, cyclohexanone, methylethylketone and combinations of two or more of these solvents. Suitable cosolvents used include xylene, ethyl—3—ethoxypropionate, and alcohols such as 2—propanol, butanol, and 2—methyl—1—propanol. The water content in the dispersion of the present invention depends upon the desired viscosity of the dispersion. The amount of water is the amount of water sufficient to render the dispersion usable in the particular coating application. This amount of water is generally within the range of 100 to 300 parts, more preferably 100 to 200 parts, with 100 to 150 parts per 100 parts of organic solvent being most preferred. The overall total solids content of the dispersion composition of the present invention including hydrolyzed cellulose ester, acrylic resin, surfactant, and cross—linking agent is 10 to 50 weight percent. The overall solids content, based on the total dispersion, is more preferably 10 to 30 weight percent, with an overall solids content of 15 to 25 weight percent being most preferred. The VOC is preferably low, below 40 weight Percent, more preferably below 25 weight percent, with a low of below 20 weight percent being most preferred. The aqueous dispersions of the present invention are prepared by the following process: (1) dissolving 100 parts hydrolyzed cellulose ester in 50 to 200 parts of a suitable organic solvent to form a solution, (2) vigorously mixing water into the solution to form a dispersion wherein the mixing and amount of water are sufficient to render the dispersion usable in coating applications. The acrylic resin can be present in the hydrolyzed cellulose ester/organic solvent solution prior to incorporation of the water, or the acrylic resin can be dispersed into the water prior to being introduced into the hydrolyzed cellulose ester organic solvent solution. The acrylic resin can be present in the solvent prior to introducing the hydrolyzed cellulose ester or it can be added after the hydrolyzed cellulose ester has been 5 solubilized. However, the acrylic resin is preferably dissolved in the organic solvent after the addition of the hydrolyzed cellulose ester. Surfactant and cross- linking agent can be added at any point prior to the addition of the water to the hydrolyzed cellulose ester 10 organic solvent solution but are preferably added while the hydrolyzed cellulose ester ' is being mixed into the organic solvent. Other materials including conventional additives can be added to the dispersion of the present invention 15 by conventional methods. Suitable examples of additives include polymer thermal stabilizers, UV stabilizers, antioxidants, colorants, carbon black, metal flake (including aluminum flake) , and pigments. Preferred pigments include titanium dioxide, chromium oxide, 20 chromium yellow, and cadmium red. The amount of pigments and additives depends upon each particular end— - - use application. Common thermal stabilizers include epoxide— containing compounds such as glycidyl ether of aromatic 25 hydrocarbons and, alcohols, for example, EPON 828, a Bisphenol—A type epoxy compound produced by Shell Chemical Company. Other suitable epoxide—containing compounds include epoxidized soybean oil or epoxidized tallate. Antioxidants generally used in the dispersion 30 composition of the present invention include hindered phenol—type compounds, for example, 4—methyl—2,6— i— tert—butylphenol and tetrakis[methylene(3,5— i—tert— butyl—4—hydroxyhydrocinnamate) ]methane (Irganox 1010 by Ciba—Geigy Corporation) . Other compounds such as Tinuvin 770, a hindered amine, are also effective as antioxidants. Ultraviolet stabilizers commonly used include 2,— (2'—hydroxyphenyl)benzotriazoles and 2— hydroxybenzophenones. The dispersion of the present invention is preferably prepared at a temperature of 25 to 100°C, more preferably 25 to 60°C, with a temperature of 25 to 40°C being most preferred. The higher the temperature, the faster the dispersion will be formed, however, temperatures much above 100°C are not very practical. The dispersion preparation time or mixing time is generally between 5 minutes and 2 hours, more preferably between 5 minutes and 50 minutes, with a time between 20 and 30 minutes being most preferred. Times shorter than 5 minutes are possible but do not adequately form a homogeneous dispersion and times longer than 2 hours do not significantly increase the homogeneity of the dispersion. The preparation can be conducted at atmospheric pressure or pressurized. The dispersions can also be made either in batch or continuous operations. The dispersions according to the present invention are generally low viscosity and milky in appearance. When coated on wood, metal, leather, and the like, they have good adhesion and dry to form clear, transparent films with good appearance and hardness. The dispersion of the present invention can be applied to any suitable substrate by standard methods such as spraying, rolling, and brushing. Among the more useful substrates are metal, wood, leather, plastics, paper, fabrics, and glass. After the aqueous dispersion of the present invention is applied to a suitable substrate, it is solidified by evaporation of the liquid component or other solidification methods known in the art of coatings and film forming. After solidification the coating can then be cured at elevated temperatures. The curing or drying temperature can vary depending upon the application but is preferably 60 to 160°C, more preferably 90 to 150°C with a curing temperature of 110 to 150°C being most preferred. EXAMPLES The following examples are to illustrate the present invention but are not intended to limit the reasonable scope thereof. Example 1 In a 16 ounce wide mouth jar, 10.20 grams of CAB powder (CAB—555—0.04, from ECC having a ball drop viscosity of 0.04 sec,an acetyl content of 0.30%, a butyryl content of 42.97%, a hydroxyl content of 7.64%, and a number average molecular weight of 17,000 in polystyrene equivalents as determined by gel permeatrion chromatography in N,N-dimethylformamide solvent) were dissolved by heating at 50°C for 30 min. in 43.68 grams of Acryloid WR—97 from Rohm & Haas (a viscous liquid containing 70 weight percent acrylic resin, having an Acid #40, in a solvent mixture of isopropanol/ethylene glycol monobutylether) and 21.18 grams of Cymel 373 from American Cyanamid (a methylated melamine—formaldehyde resin which is 85% solids in water) . Then 1.22 grams of Igepal CO—897 from Rhone—Poulenc (a nonionic surfactant containing 70% nonylphenoxypoly—(ethyleneoxy) ethanol in water, having an HLB of 17.8) were added to the solution and rapidly stirred using an Omni high shear mixer. The acid functionality of the acrylic resin was partially neutralized by adding 1.94 grams of 2—Dimethylamino¬ ethanol (DMAE) forming a high viscosity solution. The viscosity was reduced by heating. High speed agitation was continued and 158.85 grams of demineralized water was added dropwise (~5 mL/min) to the solution. During water addition 1.20 grams of octyl alcohol was added to reduce foaming. As the water was added the dispersion remained viscous until the dispersion broke and water was continuously added until a low viscosity milky dispersion was obtained. This dispersion was stable for several weeks with any sedimentation being easily redispersed with gentle agitation. A 10 mil wet film of the above dispersion was cast on a glass plate and dried overnight in a 55 degree centigrade oven. The resulting film was smooth and clear and it had good adhesion to the glass plate. When cured at 150 degrees centigrade, the film was clear, tough, solvent resistant, and scratch resistant. Example 2 The procedure of Example l was repeated except that a CAB having a hydroxyl content of 9.1 % was used. The dispersion was more stable than the dispersion of Example 1 and the resulting cured film was clear, tough, solvent resistant, and scratch resistant. Example 3 The procedure of Example 1 was repeated except that a CAB having a hydroxyl content of 11.2% was used. The dispersion was more stable than the dispersion of Example l and the resulting cured film was clear, tough solvent resistant, and scratch resistant. Example 4 The procedure of Example 1 was repeated except that the Cymel 373 melamine component was omitted. A stable, low viscosity, milky dispersion was obtained. Films cast from this dispersion have good clarity and adhered well to glass plate on which they were cast but did not have as good solvent and scratch resistant as Example l. Example 5 The procedure of Example 1 was repeated except that an additional 10 grams of ethylene glycol monobutylether solvent was added and CAB—555—0.04 was substituted with CAB—551—0.01 (having an acetyl content of 2%, a butyryl content of 53%, a hydroxyl content of 1.5%, and a number average molecular weight of 16,000 in polystyrene equivalents as determined by gel permeation chromatography in tetrahydrofuran solvent) . A low viscosity, milky dispersion was formed. When cast on glass plates, the resulting film had good clarity and adhesion but the dispersion was less stable than that of example 1. Example 6 To a 16 ounce wide mouth jar were added 78.57 grams of Rohm & Haas Acryloid WR—97 and 0.5 gram of DMAE was stirred in. Then 35.29 grams of Cymel 373 was mixed in. This solution was then diluted with 4.0 grams of Ektasolve EB solvent (an ethylene glycol monobutylether from ECC) , 3.5 grams of Ektasolve EP solvent (an ethylene glycol monopropylether from ECC) and 7.5 grams of Ektapro EEP solvent (an ethyl 3—ethoxypropionate from ECC) . To this solution was then added 15 grams of CAB powder, CAB—555—0.04, used in Example 1. Then 5.0 grams of Igepal CO—897 was added. When a uniform solution was formed mixing was begun with a Silverson high shear mixer. The high speed agitation was continued and 149.86 grams of demineralized water was added dropwise (~5 mL-_ιιin) to the solution. As the water was added the dispersion remained viscous until the last 25—30% of the water was added. At this point, the viscosity of the dispersion broke and a low viscosity milky dispersion was obtained. This dispersion was stable for several weeks with any sedimentation being easily redispersed with gentle agitation. A 10 mil wet film was cast on a glass plate and dried overnight in a 55 degree centigrade oven as in Example 1. The resultant film was smooth and clear and it had good adhesion to the glass plate. When cured at 150 degrees centigrade, the film was clear, tough, solvent resistant, and scratch resistant. Similarly good coating results were obtained using CAB's having hydroxyl contents below 3 weight percent except that the dispersions were not as stable. The invention has been described in detail with particular reference to preferred embodiments thereof, but it will be understood that variations and modifications can be effected within the spirit and scope of the invention.

Claims: Claims We claim: 1. A dispersion composition comprising: (a) 3 to 50 weight percent, hydrolyzed cellulose ester based on total solids; (b) 5 to 95 weight percent acrylic resin, based on total solids, having free acid functionality that is at least partially neutralized; (c) 0 to 10 weight percent surfactant based on total solids; (d) 50 to 200 parts organic solvent per 100 parts hydrolyzed cellulose ester; and (e) an amount of water to render the dispersion usable in coating applications; wherein the total solids content (a) , (b) , and (c) is 10 to 50 weight percent. 2. The dispersion composition according to Claim 1 containing 0.1 to 10 weight percent surfactant. 3. The dispersion composition according to Claim 2 containing 10 to 20 weight percent hydrolyzed cellulose ester, 40 to 60 weight percent acrylic resin, 1 to 8 weight percent nonionic surfactant, and 30 to 40 weight percent crosslinking agent, based on total solids. 4. The dispersion composition according to Claim 1 wherein said hydrolyzed cellulose ester has a hydroxyl content of at least 3 weight percent based on the unit molecular weight of the hydrolyzed cellulose ester and is selected from cellulose acetate butyrates, cellulose acetate propionates, cellulose acetate valerates, cellulose acetate isovalerates, and cellulose acetate propionate butyrates. 5. The dispersion composition according to Claim 4 wherein said hydroxyl content is between 6 and 9 unit molecular weight percent. 6. The composition according to Claim 4 wherein said hydrolyzed cellulose ester is a cellulose acetate butyrate. 7. The dispersion composition according to Claim 6 wherein said cellulose acetate butyrate has a butyryl content of 35 to 50 unit molecular weight percent and ah acetyl content of less than 2 unit molecular weight percent. 8. The dispersion composition according to Claim 1 wherein said acrylic resin has an acid number of 40-60 prior to partial neutralization. 9. The dispersion composition according to Claim 8 wherein said acrylic resin is partially neutralized by 10 to 80 percent. 10. A process for producing an aqueous dispersion comprising: (1) dissolving 100 parts hydrolyzed cellulose ester in 50 to 200 parts of a suitable organic solvent to form a solution, wherein the final amount of hydrolyzed cellulose ester is 3 to 50 weight percent, based on total solids; and (2) vigorously mixing water into said solution to form a dispersion wherein the mixing and amount of water are sufficient to render the dispersion usable in coating applications; wherein 0 to 10 weight percent surfactant, based on total solids, is present in the solution prior to step (2) and 5 to 95 weight percent acrylic resin based on total solids, is present in the dispersion having free acid functionality that is at least partially neutralized prior to contacting with water. 11. The process according to claim 10 wherein said hydrolyzed cellulose ester is dissolved into said suitable solvent prior to dissolving in the acrylic resin. 12. The process according to Claim 10 wherein steps (1) and (2) are carried out at a temperature of 25 to 100°C at a time between 5 minutes and 2 hours. 13. The process for coating a substrate comprising: (I) dissolving 100 parts hydrolyzed cellulose ester in 50 to 200 parts of a suitable organic solvent to form a solution, wherein the final amount of hydrolyzed cellulose ester is 3 to 50 weight percent, based on total solids; (II) vigorously mixing water into said solution to form a dispersion wherein the mixing and amount of water are sufficient to render the dispersion usable in coating applications and wherein 0 to 10 weight percent surfactant, based on total solids, is present in the solution prior to step (II) and 5 to 95 weight percent acrylic resin based on total solids, is present in the dispersion having free acid functionality that is at least partially neutralized prior to contacting with water; (III) coating on a suitable substrate; and (IV) solidifying to form a hard coating. 14. The coating process according to Claim 13 wherein the aqueous dispersion contains a crosslinking agent. 15. The process according to Claim 14 further comprising curing the hard coating at a temperature between 60—160°C.

Inventors: CURTIS LARRY GERALD, KUO CHUNG MING, LUCAS PAUL LEE, CURTIS, LARRY, GERALD, KUO, CHUNG, MING, LUCAS, PAUL, LEE
Applicants: EASTMAN KODAK CO, EASTMAN KODAK COMPANY
Application year: 1993
Main classification: C09D133
IPC codes: C08L1, C09D101, C09D133