UNSATURATED ETHYLENE - NON CONJUGATED DIENE COPOLYMERS AND PREPARATION THEREOF BY RADICAL POLYMERIZATION

Abstract: The invention concerns an unsaturated ethylene copolymer, a method for producing the ethylene copolymer, and the use of the ethylene copolymer in compositions for producing cross-linked structures, such as material for electric cables. In the method, ethylene and at least one monomer which is copolymerisable with ethylene and includes a polyunsaturated comonomer having a chain of at least 8 carbon atoms and at least 2 non-conjugated double bonds, of which at least one is terminal, are polymerised at a pressure of about 100-300 MPa and a temperature of about 80-300 DEG C under the action of a radical initiator. The polyunsaturated comonomer preferably is an alpha , omega -alkadiene having 8-16 carbon atoms, most preferred 1,9-decadiene. Apart from the polyunsaturated comonomer, polymerisation may also involve another vinyl-unsaturated monomer, preferably containing at least one functional group selected from hydroxyl groups, alkoxy groups, carbonyl groups, carboxyl groups and ester groups. The ethylene copolymers produced have an increased degree of unsaturation, which can be used for cross-linking the ethylene copolymer or grafting reactive groups.

Description: UNSATURATED ETHYLENE - NON CONJUGATED DIENE COPOLYMERS AND PREPARATION THEREOF BY RADICAL POLYMERIZATION. The present invention relates to an unsaturated ethy lene copolymer and a method for the production thereof. More specifically, the invention concerns an unsaturated ethylene copolymer having an increased degree of unsatura tion and being producted by radical polymerisation throug a high-pressure process. Normally, polyethylene produced by radical polymeri¬ sation, so-called LDPE, has a low degree of unsaturation in the order of 0.1 double bonds/1000 carbon atoms. In many situations, it is desirable to use polymers having a higher degree of unsaturation, which may serve as seat for chemical reactions, such as the introduction of func¬ tional groups into the polymer molecule or the cross- linking of the polymer. It is known that an increased level of double bonds can be obtained in polyethylene produced by organometallic catalysis, i.e. involving a coordination catalyst, by introducing as comonomers com¬ pounds having several double bonds, in which case only one bond is used for polymerising the comonomer into the polymer chain. EP 0 008 528 and JP 0 226 1809, for instance, disclose such prior-art techniques. Further, EP 0 260 999 relates to copolymers of ethylene and dienes having 4-18 carbon atoms, such as 1,4-hexadiene, in which case polymerisation is performed by means of a so-called metallocene catalyst at a high pressure. Mention may also be made of WO 91/17194 which concerns copolymers of α-olefins, such as ethylene, and α,ω-dienes having 7-30 carbon atoms, preferably 8-12 carbon atoms, such as 1,9-decadiene, in which case polymerisation is coordina¬ tion-catalysed. Moreover, US 3,357,961 discloses the pro¬ duction of a copolymer of ethylene and 1, 5-hexadiene by coordination-catalysed low-pressure polymerisation. One may further mention Chemical Abstracts, Vol. 116, No. 4, 27th January 1992, p. 15, Abstract 21674b (JP 0 322 1508, published on 30th September 1991); Chemical Abstracts Vol. 101, No. 12, 17th September 1984, p. 42, Abstract 92065e (JP 595 6412 published on 31st March 1984); and Chemical Abstracts, Vol. 69, No. 74, 9th December 1968, Kiti, Itsuo: "Ethylene-l,4-hexadiene copolymers" p. 9135, Abstract 97310m. These abstracts relate to copolymers of ethylene and non-conjugated dienes, such as 1,4-hexa- diene, 1,7-octadiene and 1,9-decadiene, and involve the use of coordination-catalysed polymerisation. As already mentioned, the above references relate to coordination-catalysed polymerisation. Coordination-cata¬ lysed polymerisation and radical-initiated polymerisation are two fundamentally different types of polymerisation, resulting in different types of polymers. While coordina- tion-catalysed polymerisation essentially yields unbranch ed linear polymer molecules, radical-initiated polymerisa tion yields heavily branched polymer molecules with long side chains. Consequently, polymers produced by the two processes have- different properties. For instance, poly- mers produced by coordination-catalysed polymerisation have a higher density than those produced by radical-ini¬ tiated polymerisation. They also have a higher melt visco¬ sity at the same melt index, which means that the polymers produced by a radical-initiated high-pressure process are, in general, easier to process. It should be emphasised that the fact that coordina¬ tion-catalysed polymerisation and radical-initiated poly¬ merisation are two fundamentally different processes means that no conclusions about one process can be drawn from the other. If, in coordination-catalysed polymerisation involving the addition of diene, only one double bond of the diene reacts, one may thus not conclude that this is also the case in radical-initiated polymerisation. Whether the diene reacts or not in coordination-catalysed polyme- risation depends on the action produced by the coordina¬ tion catalysr employed. Since radical-initiated polymeri¬ sation does not involve any such catalyst, there is no reason to assume that the diene will react in the same wa in radical-initiated polymerisation. On the contrary, in FR 2,660,660, for instance, non- conjugated dienes are used as chain-transfer agents in radical-initiated polymerisation of ethylene. According to the FR specification, the purpose is to improve the stretchability and/or the "neck-in" of polymers intended for coating, by using a non-conjugated diene as chain- transfer agent in the polymerisation, i.e. an agent for adjusting the molecular weight of the produced polymer. Thus, the diene molecular donates a hydrogen atom to the growing molecule chain, whose growth is thereby interrupt ed. The normally allylic radical simultaneously formed from the diene molecule may then initiate a new chain, which optionally receives a double bond from the diene molecule at its initial end. It should be observed that one diene molecule at the most is incorporated in each new chain according to this mechanism. This means that the double-bond content that can be incorporated is fairl restricted (about 0.1-0.2 double bonds/1000 carbon atoms at normal molecular weights) and that the -double-bond con tent of the resulting polymer cannot be varied indepen¬ dently of the desired MFR value (melt flow rate). Thus, the problem solved in FR 2,660,660 is completely differen from that on which the present invention is based. The polymers produced according to FR 2,660,660 are homopoly- mers of ethylene or copolymers of ethylene and at least one ester of acrylic or methacrylic acid. The only non- conjugated diene exemplified in FR 2,660,660 is 1,5-hexa- diene, but it is generally held that long-chain, non-con¬ jugated dienes having at least 6 carbon atoms, such as 1,5-hexadiene, 1,9-decadiene and 2-methyl-l,7-octadiene, may be used as chain-transfer agents. The use of non-conjugated dienes as chain-transfer agents according to FR 2,660,660 is contrary τo the prior- art technique in coordination-catalysed polymerisation described by way of introduction, and thus emphasises the difference between radical-initiated polymerisation and coordination-catalysed polymerisation. Further, the published International Patent Applica¬ tion WO 91/07761 discloses a cable sheathing composition prepared by radical-initiated high-pressure polymerisatio and containing ethylene, 30-60% by weight of a monofunc- tional ethylenically unsaturated ester, preferably vinyl acetate or methyl acrylate, and 1-15% by weight of a mul¬ tifunctional ethylenically unsaturated termonomer having at least two ethylenically unsaturated groups. The polyme has a melt index of 0.1-10, and the composition further contains a filler, a cross-linking agent and a stabiliser The multifunctional termonomer is a doubly unsaturated molecule containing -0- or C=0. Preferably, the termonome is obtained by esterification of a glycol and acrylic aci or a homologue thereof. It is most preferred that the ter monomer is ethylene glycol dimethacrylate (EDMA). Unlike aliphatic diene hydrocarbons, this acrylate-containing polyunsaturated termonomer is very reactive, and all the unsaturation of the termonomer will thus react in the polymerisation of the polymer. Consequently, polymerisa¬ tion does not yield any unsaturated polymer product, and the termonomer serves to adjust, i.e. lower, the melt index of the product, which it does by cross-linking pairs of polymer chains. It is worth noticing that the polymers obtained according to the W0 specification are, by con¬ taining a large amount of polar comonomers of ester type, unsuited for use as insulating cable material, since they involve high dielectric losses and probably give poor strippability compared with the materials normally used in the semiconductor layers of a power cable. It may here be mentioned that the art embraces the knowledge that increased double-bond contents can be obtained also in polyethylene produced by radical poly- merisation through a high-pressure process, by adding propylene as chain- ransfer agent, which has the limita¬ tions mentioned above with regard to FR 2,660,660. (This is described in, inter alia, Encyclopedia of Polymer Science and Technology, Rev. Ed., Vol. 6 (1986), p. 394, last par. - p. 395, first par. ) The level of double-bond content thus achieved in LDPE of about 0.3-0.4 double bonds/1000 carbon atoms is, however, insufficient in many contexts. In view of the prior art discussed above, it has now surprisingly been found that some, but not all, polyunsa¬ turated compounds having two or more non-conjugated doubl bonds do not act as chain-transfer agents, contrary to what is stated in FR 2,660,660, but can instead be used a comonomers in radical-initiated polymerisation of ethylen for introducing unsaturation in the polymer with excellen yield. More precisely, it has been found that, while short non-conjugated dienes, such as 1,5-hexadiene, and branche dienes, primarily in allyl position, such as 2-methyl-l,6 -octadiene, act mainly as chain-transfer agents in radi¬ cal-initiated polymerisation together with ethylene, straight-chain polyunsaturated compounds having a straigh carbon chain without heteroatoms and with at least two non-conjugated double bonds, of which at least one is terminal, and having at least 4 saturated carbon atoms between the double bonds, i.e. a total of 8 or more carbo atoms, preferably 8-16 carbon atoms, do not act in this way but as comonomers in which one double bond is polymer ised into the monomer chain while the other double bond o bonds do not react and instead increase the unsaturation of the polymer. This fact, which is surprising in view of FR 2,660,660, results in a polymer of a different struc¬ ture than that of the FR specification. If the polyunsa¬ turated compound had acted as a chain-transfer agent, the non-reacted double bonds would have had a terminal posi¬ tion in the polymer molecule. This would mean that the double-bond content would decrease in proportion to the increase of the chain length. Since the polyunsaturated compound according τo τhe invention acts as a comonomer, the non-reacted double bonds will instead be positioned a the end of short branches at the site in the polymer chai where the polyunsaturated compound was incorporated by polymerisation, such that the unsaturation is uniformly distributed along the polymer chain in random copolymeri- sation. This was not to be expected in view of FR 2,660,660, and constitutes a fundamental difference which should hav become apparent if FR 2,660,660 had involved tests on e.g 1,9-decadiene. In addition to the surprising discovery that the defined polyunsaturated compounds do not act as chain- transfer agents but as comonomers, the invention involves the surprising finding that the other double bond of the polyunsaturated comonomer remains essentially intact in the polymerisation, i.e. without resulting in a chain transfer, initiating any growing side branches or being otherwise chemically transformed. Thus, it has been found that, if the unsaturation of the straight-chain polyunsa- turated comonomer consists of two or more non-conjugated double bonds, of which at least one is terminal, only one double bond in most of the comonomer molecules will react with the ethylene by copolymerisation, while the other double bond or bonds will remain intact. The invention thus provides an unsaturated ethylene copolymer which is characterised in that it comprises a polymer obtained by radical polymerisation through a high- pressure process of ethylene and at least one monomer which is copolymerisable with ethylene and includes a polyunsaturated comonomer having a straight carbon chain which is free from heteroatoms and has at least 8 carbon atoms and at least 4 carbon atoms between two non-conju¬ gated double bonds, of which at least one is terminal. The invention further provides a method for producing an unsaturated ethylene copolymer, which is characterised by polymerising, at a pressure of about 100-300 MPa and a te peraτure of about 80-300°C and under the action of a radical initiator, ethylene and at least one monomer whic is copolymerisable with ethylene and includes a polyunsa¬ turated comonomer having a straight carbon chain which is free from heteroatoms and has at least 8 carbon atoms and at least 4 carbon atoms between two non-conjugated double bonds, of which at least one is terminal. The invention also concerns the use of the unsatu¬ rated ethylene copolymer in compositions for producing cross-linked structures, such as insulating-layer mate- rial, semiconductor-layer material and sheath material for electric cables. Other distinctive features of the invention appear from the following description and the appended claims. To obtain an optimal result by the invention, there should be a certain distance between the non-conjugated double bonds of the polyunsaturated comonomer. Preferably, there are at least four carbon atoms without ethylenic unsaturation between the double bonds. In other words, the polyunsaturated comonomer molecule should have a cer- tain length, and alkadiene comonomers should contain at least 8 carbon atoms, preferably 8-16 carbon atoms, most preferred 10-14 carbon atoms. Further, the diene prefer¬ ably has a straight chain, since each tertiary or allylic hydrogen atom increases the risk of chain transfer. According to the invention, the polyunsaturated como nomer may essentially consist of any straight-chain poly¬ unsaturated compound containing at least two non-conju¬ gated double bonds, of which at least one is terminal, an comprising a chain with at least 8 carbon atoms and with- out heteroatoms. Preferred monomers are cr,ω-alkadienes having 8-16 carbon atoms. Preferably, the polyunsaturated comonomer is not substituted, i.e. it consists of an unsubstituted straight-chain hydrocarbon having at least two non-conjugated double .bonds. Owing to reactivity and commercial availability, the most preferred comonomers ar 1,7-octadiene, 1,9-decadiene and 1,13-tetradecadiene. The content of the polyunsaturated comonomer is such that the unsaturated copolymer contains 0.2-3% by weight thereof " , preferably 0.2-1.5% by weight, which corresponds to an unsaturation of, respectively, 0.2-3 and 0.2-1.5 double bonds/1000 carbon atoms for 1,9-decadiene. Apart from ethylene and at least one polyunsaturated comonomer, the ethylene polymer according to the inventio may contain up to 40% by weight of some other monomer which is copolymerisable with ethylene. Such monomers are well-known to the expert and need not be accounted for in greater detail here. Mention may, however, be made of vinyl-unsaturated monomers, such as C 3 ~C g ' α-olefins, e.g.- propylene, butylene, and so forth; and vinyl-unsaturated monomers containing functional groups, such as hydroxyl groups, alkoxy groups, carbonyl groups, carboxyl groups and ester groups. Such monomers may, for instance, consis of (meth)acrylic acid and alkyl esters thereof, such as methyl-, ethyl-, and butyl(meth)aer late; and vinyl-unsa¬ turated hydrolysable silane monomers, such as vinyl tri- methoxy silane, and so forth. Propylene and higher α-olefins may be regarded as a special case, since they also act as chain-transfer agents and create terminal unsaturation in the polymer (cf. the foregoing regarding the creation of increased double-bond contents by adding propylene as comonomer (Encyclopedia of Polymer Sciences and Technology, Rev. Ed., Vol. 6 (1986), pp 394-395) as well as the foregoing discussion of FR 2,660,660 on the limitations as to possible double-bond content and MFR-value associated with the use of molecule types acting as chain-transfer agents). Using propylene (or some other higher α-olefin) as comonomer in addition to the polyunsaturated comonomer defined above thus makes it possible to further increase the degree of unsaturation of the produced copolymer in a comparatively simple and inexpensive manner. As stated above, the unsaturated ethylene polymer according to the invention is produced by high-pressure polymerisation with free-radical initiation. This poly¬ merisation process, which is well-known in the art and thus need not be accounted for in more detail here, is generally performed by reacting the monomers under the action of a radical initiator, such as a peroxide, a hydroperoxide, oxygen or an azo compound, in a reactor, e.g. an autoclave or a tube reactor, at a high pressure of about 100-300 MPa and an elevated temperature of about 80-300°C. When the reaction is completed, the temperature and the pressure are lowered, and the resulting unsaturated polymer is recovered. Further details of the production of ethylene polymers by high-pressure polymerisation with free-radical initiation can be found in the Encyclopedia of Polymer Science and Engineering, Vol. 6 (1986), pp 383-410, especially pp 404-407. As mentioned by way of introduction, the copolymers according to the invention are intended for use when a polymer with reactive sites in the form of ethylenic unsa turation is to be produced. Ethylenic unsaturation may be used for introducing functional groups, such as hydroxyl and carboxyl, in the polymer by a reaction with compounds containing such groups. The ethylenic unsaturation may also be used for cross-linking the polymer, which perhaps is its primary use. The cross-linking of polyethylene is of interest in many contexts, such as extrusion (e.g. of tubes, cable insulating material or cable sheathing), blo moulding, rotational moulding, etc. This technique is of special interest in cable tech¬ nology, for which reason this will be discussed in more depth here. In the extrusion of e.g. a power cable, the metallic conductor generally is first coated with a semi¬ conductor layer, then with an insulating layer, then with another semiconductor layer optionally followed by water barrier layers, and finally with a sheath layer. At least the insulating layer and the outer semi¬ conductor layer normally consist of cross-linked ethy¬ lene homopolymers and/or ethylene copolymers. Cross-link¬ ing substantially contributes to improve the temperature resistance of the cable, which will be subjected to con¬ siderable temperature stress when in operation. Cross- linking is brought about by adding free-radical-forming agents, mostly of peroxide type, to the polymer materials in the above layers prior to extrusion. This radical- forming agent should preferably remain stable during the extrusion but decompose in a subsequent vulcanisation step at an elevated temperature, thereby forming free radicals which are to initiate cross-linking. Premature cross-linking during extrusion will show as "scorch", i.e. as inhomogeniety, surface uneveness and possible discolouration, in the different layers of the inished cable. Consequently, the polymer material and the radi¬ cal-forming agent must not, in combination, be too reac¬ tive at the temperatures prevailing in the extruder (about 125-140°C). After the extruder, the cable is passed through a long multi-zone vulcanising tube where cross-linking should take place as rapidly and completely as possible; initiated by the heat emitted in one or more heated zones of the tube. A nitrogen-gas pressure is also applied in the tube, and contributes to prevent oxidation processes by keeping away the oxygen of the air and to reduce the formation of microcavities, so-called voids, in the poly¬ mer layers by reducing the expansion of the gases result- ing from the decomposition of the radical-forming agent. It is desirable that cross-linking is rapid but requires as little free-radical-forming agent as possible, since this reduces the risk of scorch in the extruder, results in minimum formation of microcavities as mentioned above, and is economically advantageous, peroxide being an expen¬ sive additive. Thus, the polymer material to be cross- linked should be as reactive as possible in the vulcanis- ing step. As illustrated in Example 19 below, the present invention substantially contributes to such reactive pro¬ perties. It appears from the foregoing that the unsaturated ethylene copolymer according to the invention can be used as material for semiconductor layers, insulating layers and/or sheath layers of electric cables. The following non-restricting embodiments and compa¬ rative Examples are meant to further elucidate the inven- tion. Examples 1-7 A 200-ml reactor for batch polymerisation was flushe with ethylene and then connected to a vacuum pump which generated a negative pressure in the reactor. This nega- tive pressure was used for drawing 20 ml of a mixture of polymerisation initiator, diene and isodecane (solvent) into the reactor. Then, ethylene was pumped into the reac tor at a pressure of about 130 MPa (isothermic condi¬ tions). At this point, the temperature was about 20-25°C. Thereafter, the reactor was heated to about 160-170°C, th pressure in the reactor rising to about 200 MPa and the polymerisation reaction began, which was indicated by a further increase in temperature to about 175°C. No ethy¬ lene was supplied to the reactor in the course of the reaction. The test continued until the reactor temperatur had passed a maximum value and started to drop, which indicated that the polymerisation reaction was completed. The reactor was then cooled to room temperature, blown of and opened for removal of the polymer formed, which was present in an amount of about 5-15 g. The degree of unsaturation of the polymer was analys¬ ed by means of IR spectrometry and indicated as the number of vinyl bonds per 1000 carbon atoms. The test results appear from Table 1 below. Table 1 Test Diene Melting Double bonds pe point 1000 carbon ato No. Name Mol% (°C) None 113.8 0.05 2 Com a- 0.04 0.08 0.13 0.12 0.34 1.96 The amount of diene indicated in mol% relates to the content of the gas mixture, not of the polymer formed. The density of the polymers formed in the tests was 3 about 0.926 g/cm , and the crystallinity was about 40%. The tests show that, while the yield of double bonds is very low for 1,5-hexadiene, 1,9-decadiene gives a substan tial contribution thereof. Indirectly, this also shows that 1,5-hexadiene acts as a chain-transfer agent, while 1,9-decadiene instead acts as a comonomer and thus gives a substantial contribution of double bonds to the polymer formed. Example 8 In this test, use was made of a continuous autoclave reactor having a recycling system. The reactor volume was about 51. Ethylene was supplied to the reactor through two inlet ducts; 50% of the ethylene was pumped to the reactor via the motor housing (for cooling), and the remainder was supplied directly. A double-acting hydraulic pump was used for supplying the ethylene. The total flow rate was 25-30 1/h. An initiator was added through two injection systems to an upper and a lower injection nozzle. The diene, here 1,9-decadiene, was supplied through the upper nozzle. The addition of 1,9-decadiene was begun about 11 h 15 min after start-up. The 1,9-decadiene content was 1.5%. At start-up, heat exchangers on the ethylene ducts were used for heating the reaction mixture. The heat exchangers were turned off as soon as the reaction had started. The polyethylene/ethylene mixture was removed from the reactor through a product valve. Ethylene was remove in gaseous form from the mixture in a high-pressure and low-pressure separator and was recycled to the reactor. The polyethylene was removed from the low-pressure separa tor and pressed through a nozzle out into a water bath, where it was recovered. Residual products were removed by opening a drain valve after the return-gas cooler. Sample were taken intermittently and analysed for the content of different double bonds. These contents appear from Fig. 1 As appears from the Figure, the content of vinyl groups increases continuously in the course of the test towards a state of equilibrium. This is so because unreacted 1,9-decadiene is recycled, which gradually increases the concentration thereof in the gas mixture up to a level of equilibrium. The main part of the double bonds found in the copolymer are terminal vinyl groups on short side chains, but also vinylidene groups and trans- vinylene groups occur. In the given Examples, the comonomers have two termi nal double bonds, which means that the unsaturation of th copolymers will mainly be present in the form of terminal vinyl groups on side chains. It is to be understood that if a double bond of the comonomer is not terminal, the side chains of the copolymer will contain double bonds which are not terminal. Example 9 A terpolymer of ethylene, butyl acrylate and 1,9- decadiene was produced by using a tube reactor. A mixture of air and tert-butyl peroxyethyl hexanoate was used as initiator, and methyl ethyl ketone (MEK) was used as chain-transfer agent. The reactor was supplied with abou 20 tons of ethylene/h, about 1801 of butyl acrylate/h, and about 481 of l r 9-decadiene/h. The pressure in the reactor was 220 MPa, and the temperature was 180-220°C. Unreacted 1,9-decadiene in the reactor was separated in a cooler. Polymerisation yielded about 6 tons of polymer product/h. The chain-transfer agent (MEK) was added in such an amount that the terpolymer formed had a melt flow rate (MFR) of 2 g/10 in. When analysed, the terpolymer was found to have a butyl acrylate content (BA) of about 2% by weight and a vinyl unsaturation originating from 1,9-decadiene of about 0.35 vinyl groups/1000 C. Example 10 Two polymerisation tests were carried out, using an agitated continuous 800-litre autoclave reactor divided into two sections. In the first test, ethylene was polymerised by being supplied to the reactor in an amount of about 35 tons/h. The temperature in the upper reactor section was 172°C, and that in the lower reactor section was 270°C. The pres sure in the reactor was 165 MPa. Tert-butyl pivalate was used as polymerisation initiator in the upper section, an tertbutyl benzoate was used in this capacity in the lower section. Propylene was added as a chain-transfer agent to give the prepared polymer a melt flow rate (MFR) of 0.35 per 10 min. In the test, about 7 tons of polyethylene was formed per hour. The unsaturation of the polyethylene was found to be 0.30 vinyl groups/1000 C. In the second test, the conditions were the same apart from an extra addition of 1,9-decadiene, which yielded a copolymer having an unsaturation of 0.50 vinyl groups/1000 C. The transformation of 1,9-decadiene was estimated at about 25% per reactor passage. The melt flow rate (MFR) of the polymer was adjusted to 0.35 g/10 min by adding the same amount of propylene as in the first test. This Example illustrates not only that propylene creates terminal unsaturation of the polymer in addition to acting as a chain-transfer agent (as mentioned above), but also that an addition of non-conjugated diene in the form of 1,9-decadiene effectively increases the degree o unsaturation of the polymer at the same time as it does not act as a chain-transfer agent. Example 11 A copolymer comprising 91% by weight of ethylene an 9% by weight of vinyl acetate was produced by means of t reactor employed in Example 10. The pressure in the reac tor was 180 MPa. The temperature in the upper section wa 150-160°C, and that in the lower section was 195-220°C. Tert-butyl perneodecanoate was added as polymerisation initiator in the upper section, and tert-butyl pivalate was added in the lower section. Propylene was added as chain-transfer agent to give the polymer a melt flow rat (MFR) of 0.5 g/10 min. The test yielded about 6 tons of polymer product/h, and the unsaturation of the polymer w found to be 0.1 vinyl groups/1000 C. In a second test under otherwise identical condi¬ tions, 15-20 kg of 1,9-decadiene was added per hour and copolymerised with ethylene and vinyl acetate so as to yield a terpolymer having an unsaturation of 0.3 vinyl groups/1000 C. The degree of transformation of the 1,9- -decadiene was about 25% per reactor passage. Example 12 A copolymer of ethylene and 1,9-decadiene was pro¬ duced by means of the reactor employed in Example 9. The supply of 1,9-decadiene to the reactor was about 15-20 1/h, and methyl ethyl ketone (MEK) was added as chain-transfer agent to give the polymer a melt flow rate (MFR) of 1.9 g/10 min. A mixture of air and tert-butyl peroxyethyl hexanoate was used as polymerisation initia- tor. The test yielded about 6 tons/h of a polymer product having an unsaturation of 0.25 vinyl groups/1000 C. Example 13 Example 12 was repeated, but with an addition of 1,9-decadiene of about 1401/h. This yielded a copolymer of ethylene and 1,9-decadiene having an unsaturation of 0.7 vinyl groups/1000 C. Example 14 Example 13 was repeated, but with an increase of the MEK addition to give an MFR of 4 g/10 min. The unsatura¬ tion remained unchanged, i.e. 0.7 double bonds/1000 C. This Example shows that the MRF value for the polymer can be varied in the invention, regardless of the desired degree of unsaturation. Example 15 In a two-stage tube reactor, ethylene was polymerise at a pressure of 230 MPa and a temperature of 239°C in th first stage and 325°C in the second stage. An addition of 220 1 of methyl ethyl ketone (MEK) per hour gave the ethy lene polymer a melt flow rate (MFR) of 1.9 g/10 min. In a second run, the pressure and temperature condi- tions were maintained unchanged, and ethylene was supplie to the reactor in the same amount as before. The only dif ference was that about 50 1 of 1,9-decadiene/h was added to the first stage of the reactor. To obtain a polymer material having a melt flow rate (MFR) of 1.9, as in the first run, the same amount of methyl ethyl ketone (MEK) as in the first run had to be added in the second run. The resulting copolymer had a degree of unsaturation of 0.35 double bonds/1000 C. The fact that the same amount of the conventional chain-transfer agent (MEK) is required in both runs indi¬ cates that 1,9-decadiene does not act as a chain-transfer agent. Example 16 In order to show that the non-co jugated dienes according to the invention (here 1,9-decadiene) do not act as chain-transfer agents but as comonomers and that they form copolymers with ethylene, the following test w performed on the polymer of Example 15. Samples of the polymer were fractionated in differe molecular-weight fractions, and the number of vinyl doub bonds per 1000 carbon atoms was determined for the diffe rent fractions. The employed fractionation method is described in detail by W. Holtrup in "Zur Fraktionierung von Polymeren durch Direktextraktion", Macromol. Chem. 1 (1977), pp 2335-2349, and was performed as follows. Prior to fractionation, the sample (5 g) was dissol ed in 400 ml of xylene having a temperature of about 120°C, and was precipitated after cooling in 800 ml of acetone. The solution was filtered, and the polymer was dried at room temperature. In fractionation, use was made of an apparatus whic consisted of a double-walled glass vessel. The vessel wa heated by oil circulating between the walls. The sample was mixed by an agitator, and the temperature of the solution was controlled by a thermometer. The sample was fractionated in mixtures of two dif¬ ferent solvents (xylene and oxitol). The solvents were heated to 114°C, whereupon the sample was poured and agi tation began. After 15 min, the solution was removed fro the vessel while the undissolved part of the sample had been collected in glass wool provided on the bottom of t vessel and covered by a metal netting. The dissolved par of the sample was precipated by acetone, filtered off, washed with acetone that had been stabilised by Irganox 1010, and dried. Then, the undissolved part of the sampl was treated by a new preheated mixture of solvents of a different composition, and so forth, until the entire sample had dissolved. The results of fractionation and t used solvent mixtures of xylene (stabilised by 1 g of Irganox 1010 per litre) and oxitol, appear from Table 2 below. After fractionation of the polymer samples, the viny content of the fractions was determined with the aid of I spectroscopy by measuring the absorbance at 910 cm " . The distribution (D) of molecular weight as well as the aver¬ age molecular weight (Mn, Mw) of the different fractions were determined by means of high-temperature GPC with an on-line viscometer. The column used was 3x Toyosoda mixed bed, the solvent was trichlorobenzene, and the temperatur was 135°C. The results appear from Table 3 below. Table 3 Fraction Mn Mw D Vinyl unsaturation No. per 1000 C 0,29 0,26 0,24 0,28 0,25 0,23 0,29 As appears from Table 3, the vinyl unsaturation per 1000 C is essentially the same for the different frac¬ tions. If decadiene had acted as chain-transfer agent, the content would instead have been inversely proportional to the Mn of the fraction. This shows that the added diene (1,9-decadiene) had been polymerised in a substantially homogeneous and uniform fashion into the molecular chain of the polymer, i.e. 1,9-decadiene acts as a comonomer. To conclude, this Example illustrates that the non- conjugated dienes having at least 8 carbon atoms in the chain according to the invention (here 1,9-decadiene) act as comonomers and not as chain-transfer agents in polymerisation with ethylene. Example 17 (comparative) A polymerisation test was performed with the same equipment and in a similar manner as in Example 8. Thus, about 30 kg of ethylene/h, but no diene to begin with, was pumped into the autoclave reactor. The pressure in t reactor was maintained at 125 MPa. The temperature in th upper zone was 180°C, while that in the lower zone was adjusted to 210°C. Thus, MFR was about 6 g/10 min. After obtaining stable operation conditions, pumping of 0.4 1 of 7-methyl-l,6-octadiene/h into the reactor began. This addition corresponds to about 1% by weight of this diene in the gas mixture. As a result, MFR rose quickly to 120 +/- 20 g per 10 min without the addition of another chain-transfer agent. After about 2 h, the addition of diene was increased to 1.15 1/h. The resulting polymer w a viscous liquid at room temperature and had an MFR valu above 1000 g/10 min. This Example shows that 7-methyl-l,6 -octadiene is a strong chain-transfer agent and cannot b used as comonomer according to the invention. Example 18 One of the advantages of the invention is that the unsaturation introduced by the non-conjugated diene according to the invention makes the ethylene polymer more reactive in cross-linking. This means that less cross-linking catalyst (peroxide) is required to achieve a certain cross-linking when using the unsaturated poly¬ ethylene polymer according to the invention. To illustrate this advantage, the following test was performed. The following unsaturated polyethylene polymers were used. Polymer composition Vinyl groups/1000 C A. Ethylene/1,9-decadiene 0.7 B. " 0.35 C. " 0.25 D. Ethylene/1,9-dekadiene/butyl- acrylate (Exemple 9) 0.35 E. Ethylene 0.12 To each ethylene polymer was then added 0.2% by weight of Santonox (4,4'-thio-bis(2-tert-butyl-5-methyl phenol)) as stabiliser by compounding on a Buss kneader of the type PR46B-11D/H1. The stabilised ethylene polymer was then divided into three batches, to each of which was added a cross-linking catalyst (dicumyl peroxide; "dicup") in varying concen- trations ranging from 0.9% by weight to 2.1% by weight. Pellets were made from the ethylene polymers, and plates were then made from the pellets by preheating at 120°C for 2 min and compacting at 9.3 MPa for 2 min. The resulting plates were then tested in a Gottfert elastograph measuring the changes of the shear modulus of cross-linkable polyethylene when the peroxide is decom¬ posed and cross-links the polymer chains at 180°C after 10 min. This testing method corresponds to ISO-6502. The results appear from Table 4 below. It is evident from the Table that the peroxide content required to attain a certain degree of cross-linking, measured as a change of 0.67 Nm of the shear modulus, decreases as the unsaturation of the ethylene polymer increases. Table 4 Gottfert elastograph at 180°C, 10 min. Stabilised base resins. Number of Dicup- Gδttfert Dicup co vinyl groups content elastograph to attai Sample /1000 C [%] (max) [Nm] 0.67 Nm 1.3 1.6 1.8 1.6 2.0 Cross-linking was also checked by measuring the the 2 mal deformation at 200°C and a load of 20 N/cm . This method corresponds to IEC-811-2-1-9 (hot set method). IEC-811 prescribes measurements on sample bars from cabl insulation having a thickness of 0.8-2.0 mm, but in this case measuring was performed on sample bars punched out cross-linked plates by the punch DIN 53504-S2. Three sam pie bars per material were punched out of the plates. Th bars were suspended in a Heraeus oven, and their elonga¬ tion was determined after 15 min at 200°C. The maximum permissible elongation for peroxide-cross-linkable poly¬ ethylene is 175% according to IEC-811. The results appea from Table 5 below, from which it is evident that the pe oxide content can be reduced and controlled by the choic of the content of vinyl groups, i.e. the unsaturation of the polymer. It is further apparent that the elongation values (hot set) according to the Table are improved proportionally more than the shear modulus according to Table 4 for the same addition of peroxide. This effect is surprising, and means that the peroxide addition can be further reduced in the context of cables, when polymers o a high degree of unsaturation are used. The most importan value in the quality control of cables is the elongation value, whereas the change of shear modulus may be of more importance in other applications. Table 5 Elongation measured according to IEG-811. Requirement: 2 mmaaxxiimmuumm elongation of 175% at 200°C, 20 N/cm , after 15 min. To the different polymer resins of the foregoing Example which had been stabilised by 0.2% by weight of Santonox by compounding on a Buss kneader of PR46B-11D/H1 type was added peroxide in an amount required to achieve one and the same cross-linking measured by the Gδttfert elastograph (cf. Table 4). Then, 20 kV cables were made from these different cross-linkable polymers on a pilot cable line from Nokia-Maillefer at three different line velocities: 1.6 m/min, 1.8 m/min and 2.0 m/min. These cables had a metallic conductor in the form o 2 seven wires having a total cross-section of 50 mm and a common diameter of 8.05 mm. This conductor was surrounde by an inner semiconductor layer having a thickness of 0.5 mm, an insulating layer consisting of the diene copo lymer at issue and having a thickness of 5.5 mm, and finally a semiconductor layer having a thickness of 1.4 mm. Thus, the total cable diameter was 22.8 mm. The inner semiconductor layer consisted of a thermoplastic LDPE containing 39% of carbon black, while the outer semi conductor was EVA-based and contained 0.5% of peroxide. I should here be mentioned that the strippability of the outer semiconductor was satisfactory, owing to the mate¬ rial of the insulating layer being a pure hydrocarbon polymer. If an ethylene/acrylate terpolymer according to W091/07761 had instead been used, the polarities of the insulating and the semiconductor layers would have become too similar, and adhesion would thus have been too high. A 60 mm/24D extruder was used for the insulating material of the cables. The extruder temperature was set at 110°C, 115°C, 120°C, 120°C, 125°C, 125°C and 125°C. Nitrogen gas at a pressure of 1 MPa was used in the vulca nising tube, which had a length of 26 m. In this tube, a first zone of 3.7 m was maintained heat-neutral, a second zone of 3 m was maintained at 400°C, a third zone of 3 m was maintained at 370°C, and a fourth zone of 4.3 m was maintained neutral, as the first zone. The tube ended by a 11.6-m cooling zone which was cooled by cold water at a temperature not exceeding 40°C. At the most, the cable temperature was 135°C at " the inlet of the vulcanising tub and 90°C at the outlet of the tube. Thereafter, the degree of cross-linking of the cable insulation was determined according to IEC-811 (hot set method). Three lengths of 10 cm were taken from the cable insulation closest to the inner semiconductor and at the same distance by means of a splitting machine. Then, three sample bars were punched out from these lengths by the punch DIN 53504-SA2. The thermal deformation at 200°C an 2 a load of 20 N/cm was then measured on the sample bars after 15 min, in accordance with ICE-811. The results appear from Table 6 below, which clearly shows that the amount of peroxide can be reduced as a function of an increased amount of vinyl groups, i.e. an increased unsa¬ turation of the ethylene polymer. Alternatively, the advantage of the increased rate of cross-linking may ser to give a higher production speed on the line, or a combi nation of both. Table 6 Elongation measured according to IEC-811. Requirement: 2 maximum elongation of 175% at 200°C, 20 N/cm , after 15 min. Number of Dicup Line Elonga¬ Base vinyl groups/ content speed tion resins 1000 C [%3 [m/min] [%] A+0.2% Sx 0.7 1.3 1.6 62 A+0.2% Sx 0.7 1.3 1.8 70 A+0.2% Sx 0.7 1.3 2.0 127 B+0.2% Sx 0.35 1.6 1.6 93 B+0.2% Sx 0.35 1.6 1.8 100 B+0.2% Sx 0.35 1.6 2.0 153 C+0.2% Sx 0.25 1.8 1.6 87 C+0.2% Sx 0.25 1.8 1.8 98 C+0.2% Sx 0.25 1.8 2.0 155 D+0.2% Sx 0.35 1.6 1.6 70 D+0.2% Sx 0.35 1.6 1.8 87 D+0.2% Sx 0.35 1.6 2.0 148 E+0.2% Sx 0.12 2.1 1.6 80 E+0.2% Sx 0.12 2.1 1.8 105 E+0.2% Sx 0.12 2.1 2.0 143

Claims: CLAIMS 1. An unsaturated ethylene copolymer, c h a r a c - t e r i s e d in that it comprises a polymer obtained by radical polymerisation through a high-pressure process of ethylene and at least one monomer which is copolymerisabl with ethylene and includes a polyunsaturated comonomer having a straight carbon chain which is free from hetero- atoms and has at least 8 carbon atoms and least 4 carbon atoms between two non-conjugated double bonds, of which a least one is terminal. 2. An unsaturated ethylene copolymer as set forth in claim 1, c h a r a c t e r i s e d in that the polyunsa- turated comonomer is an α,ω-alkadiene having 8-16 carbon atoms, preferably selected from 1,7-octadiene, 1,9-deca¬ diene and 1,13-tetradecadiene. 3. An unsaturated ethylene copolymer as set forth in claim 2, c h a r a c t e r i s e d in that the polyun- saturated comonomer is 1,9-decadiene. 4. An unsaturated ethylene copolymer as set forth in any one of claims 1-3, c h a r a c t e r i s e d in that it has been obtained by polymerisation of ethylene and two monomers which are copolymerisable with ethylene and one of which is a vinyl-unsaturated monomer. 5. An unsaturated ethylene copolymer as set forth in claim 4, c h a r a c t e r i s e d in that the vinyl- unsaturated monomer is a 3 -C 8 α-olefin or contains at least one functional group selected from hydroxyl groups, alkoxy groups, carbonyl groups, carboxyl groups and ester groups. 6. A method for producing an unsaturated ethylene copolymer, c h a r a c t e r i s e d by polymerising, at a pressure of about 100-300 MPa and a temperature of about 80-300°C and under the action of a radical initia¬ tor, ethylene and at least one monomer which is copolymer¬ isable with ethylene and includes a polyunsaturated como- nomer having a straight carbon chain which is free from heteroatoms and has at least 8 carbon atoms and at least 4 carbon atoms between two non-conjugated double bonds, of which at least one is terminal. 7. A method as set forth in claim 6, c h a r a c ¬ t e r i s e d by the polyunsaturated comonomer being an α,o-alkadiene having 8-16 carbon atoms, preferably select¬ ed from 1,7-octadiene, 1,9-decadiene and 1,13-tetradeca- diene. 8. A method as set forth in claim 7, c h a r a c ¬ t e r i s e d by the polyunsaturated comonomer being 1,9-decadiene. 9. A method as set forth in any one of claims 6-8, c h a r a c t e r i s e d by polymerising ethylene with a polyunsaturated comonomer and a vinyl-unsaturated mono¬ mer. 10. A method as set forth in claim 9, c h a r a c ¬ t e r i s e d by the vinyl-unsaturated monomer being a C -C R α-olefin or containing at least one functional group selected from hydroxyl groups, alkoxy groups, car¬ bonyl groups, carboxyl groups and ester groups. 11. Use of the unsaturated ethylene copolymer as set forth in any one of claims 1-5 in compositions for produc¬ ing cross-linked structures. 12. Use as set forth in claim 11 in compositions for insulating layer material, semiconductor-layer material or sheath material for electric cables.

Inventors: ALHA KARI, GUSTAFSSON BILL, MAGNUSSON TORBJOERN, RYDIN PETER, ALHA, KARI, GUSTAFSSON, BILL, MAGNUSSON, TORBJOERN, RYDIN, PETER
Applicants: NESTE OY
Application year: 1992
Main classification: C08F210
IPC codes: C08F10, C08F210, H01B3, H01B7