A METHOD AND A PLANT FOR HEAT TREATMENT OF BIOLOGICAL MATERIAL

Abstract: Method and device for heat treatment of biomaterial, for example wood-chips, timber and the like in a plant including a treatment container, which forms a closed system with an external circulation conduit (7) connected to the opposite ends thereof via an inlet and an outlet, and where the biomaterial is input and after treatment is withdrawn from the treatment chamber through at least one opening with sluice (6), which prevents air penetration into the system, that during operation the system is held essentially filled with steam near atmospheric pressure, that the steam is brought to circulate in the system through the circulation conduit and the treatment chamber, an through indirect heat transmission from a heat carrier (9) holds the steam at a temperature slightly above the desired treatment temperature at the inlet of the treatment chamber, that an amount of the steam, corresponding to the moisture expelled from the biomaterial is drained and condensed and gases leaving the material are collected and burned in order to heat the heat carrier.

Description: A METHOD AND A PLANT FOR HEAT TREATMENT OF BIOLOGICAL MATERIAL. Background of the invention The present invention refers to a method for heat treatment of biomaterial, for example wood-chips, timber in a plant in¬ cluding a treatment chamber, which forms a closed system with an external circulation conduit, connected via an inlet and an outlet to the opposite ends thereof, and a plant for accom- pushing the method. Such heat treatment of biomaterial can be used for different purposes. An appropriate area of the kind is preprocessing of biofuel, such as wood-chips, peat, sawdust, and so on. With increasing fuel costs for conventional fuels, biofuels have become a still more interesting fuel alternative, in particular in district heating centrals and the like. In order not to obtain unfavourable utilization of the fuel energy content at combustion of such biofuel by moisture contained in the fuel having to be vaporized, a drying out of the biofuel, that is, a drying before further processing or use, can be economically motivated. Earlier there are developed processes for roasting, that is, drying and partial pyrolysis of biofuels and at first hand of wood-chips. A method thereby for the drying as well as for the roasting to use flue gases, by which however the drawback is that the fire hazard is great. Another method by a pure drying process has been the use of steam, as a drying medium, by which the drying material is surrounded by water vapour under over¬ pressure. This means that the plant has to be sealed against the environment, which implies price raising constructive solutions. Dryers which use fluidization techniques are available in several different designs, by which the basic principle is that drying takes place by direct blowing of air, flue gas or stea from below onto the drying material. At high speed enough ont the drying medium the bed, ie. the drying material in itsel begins to hover. Another suitable field of application fo heat treatment of biomaterial is that of rot-protection treat¬ ment of construction wood. Today construction wood is treated, as protection against mould fungus attack generally through pressure impregnation, which is an environmentally questioned method, which is fenced round with many constraints. Thus it is regarded that processing waste from pressure impregnated wood is so dangerous to the environment, that today it is safeguarded and is neutralized by a waste processing company. The object is now to offer a method of heat treatment by means of overheated steam to convert the material, so that at least the surface layer obtains hydrophobe characteristics, which prevents attack of mould fungus. The characteristics of the material for the rest become similar to those of normal pressu¬ re impregnated wood. Waste material from working and the wood as such can directly be utilized as fuel, and even for example spruce, which is difficult to impregnate under pressure can without problems be treated with this method. The object of the invention and important features The object of the present invention is to provide a method for heat treatment of biomaterial, e. g. wood-chips, timber and the like in a plant including a treatment container, which forms a closed system connected with an external circulation pipe at opposite ends thereof via an inlet and an outlet, by means of which an improved operation economy can be achieved, at the same time as above stated remaining drawbacks are eliminated and this has been achieved by the biomaterial being input and after treatment withdrawn from the treatment chamber through at least one opening with sluice, which prevents air penetra- tion into the system, that during operation the system is kept essentially filled with steam near atmospheric pressure, that the steam is brought to circulate in the system through the circulation pipe and the treatment chamber, and through indirect heat transmission from a heat carrier holds the steam at a temperature somewhat above the desired treatment tempera¬ ture at the inlet in the treatment chamber, that the amount of steam corresponding to the moisture expelled from the biomaterial is drained and condensed, and gases leaving the material are collected and burned for heating of the heat carrier. The invention also includes a plant of appropriate design to accomplish the method, the feature of which in main is evident from the patent claim 8. Specification of drawings In the following the invention will be described in closer detail with reference to embodiments of two plants according to the invention illustrated in the enclosed drawings. Fig. 1 discloses diagrammatically a basic view of a first embodiment of a drying plant according to the invention. Fig. 2 is a corresponding view of a second embodiment of the invention. Specification of preferred embodiments In Fig. 1 the heat treatment plant according to the invention shown in vertical section in principle is intended to be used for drying and subsequent roasting of pulverized biomaterial, such as preferably wood-chips, and includes a vertical fluidi¬ zation tower 1 with a grate 2 applied at the bottom. At the top of the tower there is provided feed pocket 4 for biofuel and at the bottom of the tower is connected a discharge pipe 5 for the roasted product. As well the input pipe 3 as the discharge pipe 5 are connected to the tower inside via sluices 6, whic to a substantial degree prevents air from entering into th tower. Between the top of the tower and the bottom is connecte an external circulation pipe 7 with a fan unit 8 arranged t forward drying medium through the circulation pipe, so tha this is input at the bottom of the fluidization tower 1 throug the grate 2 and the biofuel lying thereon, only indicated i the figure, and discharged from the tower at the top thereof. In the circulation pipe there is further provided an over heating battery 9 arranged to overheat the drying medium, whic is made up by water vapour of atmospheric pressure, so tha this for a first drying step has a temperature of between 150 and 250°C, preferably maximum of about 200°C and for a roasting step has a temperature of at least 260°C at its entry at the bottom of the fluidization tower 1. The overheater 9 is connec¬ ted to a heat generator, for example in the shape of a boiler 10. In the embodiment shown the overheater 9 connected to a boiler dome 11 on the boiler 10, but as a heat medium alterna¬ tively can be used furnace water, flue gases or possibly hot oil. Between the upper part fluidization tower and the cir¬ culation pipe there is provided a particle separator in the shape of a cyclone 12, in which small fractions of input biofuel and particles that accompany the steam and the pyroly- sis gas stream is separated. From the cyclone 12 such separated particles are conveyed via a dust conduit 13 to the boiler 10 where dust burning takes place. Alternatively such as is indicated at 26 in Fig. 1 particles separated in the cyclone wholly or partly are returned to the treatment chamber. Between the cyclone 12 and the fan 8 a drain pipe 14 is connected to the circulation pipe for the surplus of steam, which by the roasting is generated through fluid loss from the biofuel. This pipe 14 leads to a condenser 15 from which condensate is discharged, possibly as furnace water. Not condensable gases are drained at coldest end of the condenser and are conveyed via a conduit 16 to the boiler 10 for combustion. Outgoing heat exchanger medium from the heat exchanger 17 of the condenser passes preferably a heat exchanger 18 connected intermediate the boiler dome 11 of the boiler 10 and the input side, where the medium is heated further before it is discharged via a conduit 19 to a heat system not shown, for example a district heating system. The boiler 10 has an outgoing conduit 20 for a heat medium, which as well can be supplied to a heat system or the like. Moreover, there is provided a fluegas outlet 21. From the boiler dome 11 a steam conduit 22 provided with a closeable valve runs to the circulation pipe 7, into which it discharges before the overheater 9. In the discharge pipe 5 for the roasted product there may be provided a heat exchanger 23, which can be used for prehea¬ ting of the biofuel in the feed pocket 4, which is illustrated by the dashed the line 24. After discharging of the roasted product it is cooled preferably through water pouring at 25 to prevent spontaneous ignition. The plant operates in the following way: Biofuel, preferably in the form of wood-chips are input in the fluidization tower 1 via the feed pocket 4, the sluice 6 and the conduit 3 so that they will end up on the grate 2. At the start of the process a small amount steam is supplied via the conduit 22 to the circulation pipe, where it is overheated in the overheater 9 and through impact of the fan 8 is driven with such a speed that it by the entry of the fluidization tower through the grate has a temperature of preferably ca 260°C and such a speed that the input chips begin to fluidize, that is, hovers in a steam flow of essentially atmospheric pressure. Hereby is introduced a mild pyrolysis, which gives the product roasted wood, which is a something between untrea¬ ted wood and charcoal, after relatively short dwelling time. As soon the process has been initiated, the steam supply is shut off via the conduit 22. At the upper end of the tower the steam as well as pyrolysis gases leave, whereby particles accompanying therein are separated in the cyclone 12. The steam surplus, which is obtained by moisture leaving the wood in th fluidization tower 1, is discharged through the conduit 14 an is condensed in the condenser 15. Uncondensable gases are lea by means of a pipe 16 to a boiler 10 in which they are burned together with dust, which is supplied from the cyclone 12. The heat for overheating of the steam in the circulation of the tower 1 and the circulation pipe 7 is obtained from this boiler 10. The heat medium, which leaves the condenser 15 passes preferably a further heat exchanger 18, which is connected to the boiler, and subsequently is used preferably with hot water from the boiler in an external heat system. Gases, which are driven off through the prepyrolysis as stated can be used to operate the process and/or a gas driven motor located at another place. In the discharge pipe 5 for the roasted product a heat ex¬ changer 23 is provided, the outgoing heat medium of which was used to preheat the biomaterial in the feed pocket 4. The roasted product produced from wood-chips is used as substitute material for charcoal, and the exchange of roasted wood is 3 to 4 times larger with the economic advantages as an additional positive factor. By the plant shown in Fig. 2, the purpose is to treat con¬ struction wood, such as sawed plank and ribs, so as to give the same hydrophobe characteristics, which prevents attack of mould fungus. This plant to its basic structure corresponds to that according to Fig. 1, but instead of the fluidization tower the plant here is provided with a horizontal furnace chamber, which can be a batch oven or a tunnel furnace, in which the material, which is going to be treated is pushed into or through on a vehicle or other suitable transporter. Since the plant is operated at atmospheric pressure troublesome supply problems will be avoided and there is only need for one sluice with a reasonable gas seal. In contrast to the previously known so called pneumatic counter pressure dryer in this case one works with a high relative velocity between the heat medium and the material, which implies that one does not as in this older dryer, which works with low relative velocity, need to elevate the pressure to bridge the external thermal transmission resistance. The plant according to this embodiment corresponds to the rest; the embodiment according to Fig. 1, with the exception that the particle separator or cyclone, which is present at the embodiment according to Fig. 1 is not necessary at this embodiment, even if it may be present. An advantage with the method and the plant according to the invention is that one can work with system integration, whereby one can first dry the material at a heat level of between 160 and 220°C and thereafter, possibly in a series connected plant one can achieve the roasting by a temperature of about 260°C. Hereby one can preferably use the energy in series, whereby for example in a heating plant one can borrow energy on a level of ca 180°C and redeliver it on a level immediately below 100°C, that is, enough for the return water in a district heating plant, in a combined power and heating plant or as preprocess for the gasifying process. In the corresponding way, at saw¬ mills, which have very great heat requirements at the level 60 C C for their wood dryers, one can first heat treat the wood products on a high temperature level and subsequently use the residual heat in the conventional wood dryer. Thereby one should first dry in a conventional way at 60°C and then let the material run through steam drying and roasting. By a plant including different treatment parts it is advanta¬ geous if these are arranged in series, or that one has two parallel parts in which the treatment occurs in batch and where the heat is tapped down alternately. The invention is not limited to the embodiment of the method and the plant diagrammatically illustrated in the enclosed drawing and described in connection thereto but modification and variants are possible within the scope of the subsequen patent claims.

Claims: CLAIMS 1. Method for heat treatment of biomaterial, for example wood- -chips, timber and the like in a plant including a treatment container, which forms a closed system with an external cir¬ culation conduit (7), connected via an inlet and an outlet to the opposite ends thereof, c h a r a c t e r i z e d t h e r e i n, that the biomaterial is input into and after processing is withdrawn from the treatment chamber through at least one opening with a sluice (6,103), which prevents air penetration in the system, and where the system during operation is held essentially filled with steam near atmospheric pressure, which steam is brought to circulate in the system through the cir- culation conduit and the treatment chamber, and in addition a part of the steam, which corresponds the moisture expelled from the biomaterial is drained and condensed, that the steam through indirect heat transmission from a heat carrier (9) at the inlet (2,102) in the treatment chamber is held at a temperature slightly above desired treatment tempera¬ ture, and that a part of the steam is drained and condensed which corresponds to the misture expel from the biomaterial and gases escaping from the material is collected and burned for heating of the heat carrier. 2. Method according to the patent claim 1 , c h a r a c t e r i z e d t h e r e i n, that a particle separator (12) is provided in the circulation conduit (7), connectable to the device (10) for combustion of separated material for heating of the heat carrier (9). 3. Method according to the patent claim 1 or 2, by roasting of decomposed biofuel in the form of wood-chips or the like and where the treatment chamber is constituted by a fluidiza- tion tower (1) where the inlet and outlet of the circulation conduit in the fluidization tower are provided at the bottom and the top of the tower respectively, c h a r a c t e r i z e d t h e r e i n, that the biomaterial is input through a first opening, provided with a sluice (6) at the top of the fluidization tower (1), in which the biomaterial by means of the circulating steam is brought to fluidize and the roasted product is withdrawn through a second opening, provided with sluice (6) at the bottom of the tower, and that the steam is held at a temperature of at least 260°C at the inlet of the fluidization tower (1). 4. Method according to the patent claim 3, c h a r a c t e r i z e d t h e r e i n, that it material to be roasted is first dried in the same or another apparatus at a temperature of approx. 200°C. 5. Method according to the patent claim 3 or 4, c h a r a c t e r i z e d t h e r e i n , that the biomaterial is pre-dried before further treatment or use by using of heat, which is obtained in connection with refrigeration of the roasted material withdrawn. 6. Method for heat treatment of wood according to patent claim 1, c h a r a c t e r i z e d t h e r e i n, that the circulating steam is given a high flow velocity and that the steam temperature is held at least at 260 °C at the inlet (102) of the circulation pipe in the treatment chamber. 7. Method according to any of preceeding claims, c h a r a c t e r i z e d t h e r e i n , that treatment container (1,101) of the plant is system integ¬ rated by several containers being connected, whereby drying of the material is carried out in a first container and steam roasting in a second container at higher temperature, whereby the heat medium after lowering the temperature of the second container with lower temperature is input to the inlet (2,102) of the first container. 8. Plant for heat treatment of biomaterial, comprising a treatment chamber (1) and a circulation conduit (7) connected to opposite sides of this, to carry out the method according to claim 1, and c h a r a c t e r i z e d i n, at least one opening with sluice (6) to essentially prevent air penetration and intended for input of biomaterial and/or withdrawal of a heat-treated product from the chamber, means (22) to supply steam to the system at start-up of the plant, means (14,15) to condense and drain during operation the amount of steam, which corresponds to the moisture expelling from the biomaterial, so that mainly atmospheric pressure prevails in the system, a heat exchanger (9) provided in the circulation conduit (7) dimensioned to overheat the steam at the inlet of the chamber and hold it at a desired temperature level, a fan unit (8) to circulate steam from one side of the chamber to the other, as well as means (16,10) to separate and burn gases which escape at the heat treatment. 9. Plant according to the patent claim 8, c h a r a c t e r i z e d i n, that the heat exchanger is dimensioned to maintain a temperatu¬ re of 260 °C at the inlet (2,102) end of the container (1,101). 10. Plant according to any of the patent claims 8 or 9, c h a r a c t e r i z e d i n , that the circulation conduit (7) contains a particle separator (12) with connection (13) to means (10) for combustion of separated material. 11. Plant according to any of the preceding patent claims, c h a r a c t e r i z e d i n, a heat exchanger (23) in connection to the sluice (6) at the discharge pipe (5) for the roasted product and arranged for pre-drying of biomaterial supplied. 12. Plant according to any of the patent claims 8 to 11, c h a r a c t e r i z e d i n, that the treatment container is constituted by a fluidization tower (1) with a grate (2) at its bottom and with an inlet (3) for treament material, such as wood-chips, at the upper part of the tower and an outlet (5) for the roasted product just above the grate (2). 13. Plant according to any of the patent claims 8 to 11, c h a r a c t e r i z e d i n, that the the treatment container is a horizontally provided chamber (101) with at least one opening (103) provided with a sluice for input and witdrawal of material and with an inlet (102) for overheated steam at one of its sides and with an outlet (104) for lowered temperature steam outgoing from the treatment chamber at the opposite side thereof. [received by the International Bureau on 7 September 1992 (07.09.92); original claims 1-13 replaced by amended claims 1-11 (4 pages)] 1. Method for roasting of biomaterial, for example wood-chips timber and the like in a plant including a treatment chamber which forms a closed system with an external circulatio conduit (7), connected via an inlet and an outlet to t opposite ends thereof, where the biomaterial is input into an after treatment is withdrawn from the treatment chamber throug at least one opening with a sluice (6,103), which prevents ai penetration in the system, and where the system during opera tion is held essentially filled with steam near atmospheri pressure, which steam is brought to circulate in the syste through the circulation conduit and the treatment chamber, an in addition a part of the steam, which corresponds the moistur expelled from the biomaterial is drained and condensed, c h a r a c t e r i z e d t h e r e i n, that the steam through indirect heat transmission from a hea carrier (9) at the inlet (2,102) in the treatment chamber i held at a temperature of at least 260°C, that is, slightl above desired treatment temperature, and that gases escapin from the material is collected and burned for heating of th heat carrier. 2. Method according to the patent claim 1 , c h a r a c t e r i z e d t h e r e i n, that particles that are separated from the biomaterial ar collected in a particle separator (12) provided in the cir culation conduit (7), connectable to the device (10) fo combustion of separated material for heating of the hea carrier (9). 3. Method according to the patent claim 1 or 2, by roastin of decomposed biofuel in the form of wood-chips or the lik and where the treatment chamber is constituted by a fluidiza tion tower (1) where the inlet and outlet of the circulatio conduit in the fluidization tower are provided at the botto and the top of the tower respectively, c h a r a c t e r i z e d t h e r e i , that the biomaterial is input through a first opening, provide with a sluice (6) at the top of the fluidization tower (1) in which the biomaterial by means of the circulating steam i brought to fluidize and the roasted product is withdraw through a second opening, provided with sluice (6) at th bottom of the tower, and that the steam is held at a temperatu re of at least 260°C at the inlet of the fluidization towe (1). 4. Method according to the patent claim 3, c h a r a c t e r i z e d t h e r e i n, that the material to be roasted is first dried in the same o another apparatus at a temperature of approx. 200°C. 5. Method according to the patent claim 3 or 4, c h a r a c t e r i z e d t h e r e i n, that the biomaterial is predried before further treatment or use by using of heat, which is obtained in connection wit refrigeration of the roasted material withdrawn. 6. Method according to any of preceding claim, c h a r a c t e r i z e d t h e r e i , that treatment container (1,101) of the plant is system integ- rated by several containers being connected, whereby drying of the material is carried out in a first container and steam roasting in a second container at higher temperature, whereby the heat medium after lowering of temperature in the second container is input at the inlet (2,102) of the first container of lower temperature. 7. Plant for roasting of biomaterial, comprising a treatment chamber (1) and a circulation conduit (7) connected to opposite sides of this, to carry out the method according to claim 1, and c h a r a c t e r i z e d i , that it includes the following in itself partly known distinctive features: at least one opening with sluice (6) to essentially prevent air penetration and intended for input of biomaterial and/or withdrawal of a heat-treated product from the chamber, means (22) to supply steam to the system at start-up of the plant, means (14,15) to condense and drain during operation the amount of steam, which corresponds to the moisture expelling from the biomaterial, so that mainly atmospheric pressure prevails in the system, a heat exchanger (9) provided in the circulation conduit (7) dimensioned to overheat the steam at the inlet of the chamber and hold it at a desired temperature level of at least 260°C, a fan unit (8) to circulate steam from one side of the chamber to the other, as well as means (16,10) to separate and burn gases that escape at the heat treatment. 8. Plant according to any of the patent claims 7, c h a r a c t e r i z e d i n, that the circulation conduit (7) contains a particle separator (12) with connection (13) to means (10) for combustion of separated material. 9. Plant according to any of the patent claims 7 or 8, c h a r a c t e r i z e d i n, a heat exchanger (23) in connection to the sluice (6) at the discharge pipe (5) for the roasted product and arranged for predrying of supplied biomaterial. 10. Plant according to any of the patent claims 7 to 9, c h a r a c t e r i z e d i , that the treatment container is constituted by a fluidization tower (1) with a grate (2) at its bottom and with an inlet (3) for treatment material, such as wood-chips, at the upper part of the tower and an outlet (5) for the roasted product just above the grate (2) . . 11. Plant according to any of the patent claims 7 to 9, c h a r a c t e r i z e d t h e r e i , that the treatment container is a horizontally provided chamber (101) with at least one opening (103) provided with a sluice for input and withdrawal of material and with an inlet (102) for overheated steam at one of its sides and with an outlet (104) for lowered temperature steam outgoing from the treatment chamber at the opposite side thereof. STATEMENT UNDER ARTICLE 19 Claim 1 has been limited to take full account of the references cited in the International Search Report and partuicularly to applicant's elder invention according to SE-B-450 971, whereby the contents of original claim 6 have been introduced in amended claim 1. New claim 7 corresponds to a partly reworded original claim 8, with the contents of original claim 9 included therein. The other claims correspond materially to those originally filed such that new claims 2-5 correspond to original claims 2-5, whereas new claims 8-11 correspond to original claims 10-13. Claims 1 to 6 refer to a method for roasting of biomaterial. Such a treatment process incorporates such part processes as heating stage, drying stage, i.e. expelling of moisture from the product and thermic expelling of first pyrolysis products, intended to give a desired final product irrespective of if the product is construction timber, when the roasting is used for eliminating impregnation, which is less desirable from environmental aspects, or if the final product is roasted tree, intended to be used as a substitute for charcoal. It also has been found that a desired balance between gas yield and product yield is obtained at operation temperature of about 260°C. It is an incontestable fact that none of the references, neither separately or in different combinations describe roasting of tree in vapour, and already this is a new approach, which is conside¬ red to fullfil the criteria of patentability. Claim 7 has been written as a combination claim, as a plant for roasting of bio products is novel even if some of the part features thereof are partly known in similar planst, such as drying plants. It is ascertained that no new matter has been added to the application when amendming the claims.

Inventors: KULLENDORFF ANDERS, KULLENDORFF, ANDERS
Applicants: KULLENDORFF ANDERS, KULLENDORFF, ANDERS
Application year: 1992
Main classification: F26B17
IPC codes: F26B3, F26B23