Superconducting wire

Abstract: A superconducting wire comprises a flexible base material of yttria stabilized zirconia containing less than 0.1 percent by weight of an Al₂O₃ impurity and an oxide superconducting layer formed on the base material.

Description: BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to a superconducting wire, and more particularly, it relates to a superconducting wire which comprises a base material and an oxide superconducting layer formed on the base material. Description of the Background Art Metal, compound and ceramic materials have been generally known as superconductors, and study has been made to apply such superconductors to various uses. A superconductor loses all resistance to electric current when the same is maintained at a temperature lower than its critical temperature, and attempts have been made for applying such property to generation of a high magnetic field, high-density bulk power transmission and the like. A ceramic superconductive material has been recently highlighted in such a point that its critical temperature for a superconducting phenomenon can be increased. Such a superconductive material can be worked into an elongated linear member, for example, for application to power transmission/distribution, electrical connection of various types of devices or elements, line winding or the like. In order to work a conventional compound superconductive material into such a wire rod, there has been proposed a method of forming a layer of the superconductive material on a base material of stainless steel etc. or an alloy tape by sputtering or the like. Excellent flexibility can be easily attained by forming the superconducting layer on such a tape-type base. If a layer of a ceramic superconductive material is formed on a general metal or ceramic tape, however, it is impossible to attain good superconductivity particularly when the superconducting layer has a small thickness of not more than 1 µm. For example, Japanese Patent Laying-Open Gazette No. 271816/1988 discloses a superconducting wire which comprises an oxide single crystal fiber member and a layer of an oxide superconductor formed on the oxide single crystal fiber member. Such an oxide superconducting layer can be formed by a vapor-phase thin film forming method such as vapor deposition, sputtering, CVD or the like. In order to attain high critical current density in such a superconducting wire, however, it is generally necessary to perform heat treatment at a high temperature. Also when a layer of an oxide superconductor is formed on a single crystal member of MgO, SrTiO₃ or the like, which can provide a film of excellent crystallinity, it is necessary to keep a substrate temperature of 600 to 700 o C during film formation and to further perform heat treatment at a temperature of at least 900 o C after film formation. When a layer of an oxide superconductor is formed on a substrate of a flexible metal, ceramic material or glass, heat treatment must be performed at a higher temperature for a longer time to compensate for inferior crystallinity. If such high-temperature heat treatment is performed for a long time, however, diffusion reaction is caused between the superconducting layer and the substrate, to deteriorate superconductivity of the oxide superconductor layer. In order to prevent such diffusion reaction, an intermediate layer may be formed between the substrate and the oxide superconductor layer. However, such an intermediate layer must be at least 1 µm in thickness to withstand the high-temperature heat treatment which is performed for a long time, and hence the cost for forming the intermediate layer is increased. SUMMARY OF THE INVENTION An object of the present invention is to improve superconductivity of a superconducting wire, which comprises a base material and an oxide superconducting layer formed on the base material. Another object of the present invention is to provide a superconducting wire which is improved in superconductivity, by reducing influence exerted by diffusion reaction caused in heat treatment. A superconducting wire according to the present invention comprises a flexible base material which is formed of yttria stabilized zirconia containing less than 0.1 percent by weight of an Al₂O₃ impurity, and an oxide superconducting layer formed on the base material. The amount of the Al impurity, which is contained in yttria stabilized zirconia forming the base material, is less than 0.1 percent by weight, and more preferably, less than 0.05 percent by weight. Throughout the specification, the term "the amount of the Al impurity" indicates the impurity content of Al₂O₃. In the present invention, yttria stabilized zirconia forming the base material contains less than 0.1 percent by weight of the Al impurity, since Al is most diffusible within impurities which are contained in yttria stabilized zirconia. Thus, it is possible to suppress deterioration of superconductivity, particularly the critical temperature T C , by reducing diffusion reaction of Al. If a YBaCuO oxide superconducting layer is formed on a base material of yttria stabilized zirconia containing at least 0.1 percent by weight of the Al impurity, an oxide, particularly that consisting of Y₂Ba₁Cu₁O₅, is easily formed. Due to formation of the oxide having such composition, the critical temperature T C and critical current density J C are reduced. The present invention has been achieved with discovery of such a phenomenon that a different phase such as Y₂Ba₁Cu₁O₅ is easily formed when the Al impurity content exceeds 0.1 percent by weight. In the oxide superconducting wire according to the present invention, the oxide superconducting layer is formed on the base material of yttria stabilized zirconia containing less than 0.1 percent by weight of an Al impurity. Thus, the base material contains a small amount of the most diffusible Al according to this aspect, and hence it is possible to suppress diffusion reaction during heat treatment, thereby suppressing deterioration in superconductivity caused by heat treatment. These and other objects, features, aspects and advantages of the present invention will become more apparent from the following detailed description of the present invention. Y-Ba-Cu-O oxide superconducting layers were formed by RF magnetron sputtering on tape-type members of yttria stabilized zirconia, containing 3 percent by weight of Y, of 0.1 mm in thickness having different values of Al impurity concentration as shown in Table 1. Film forming conditions were as follows: Target: Y₁Ba₂Cu 3.5 O x Target Diameter: 100 mm Substrate Temperature: 680 o C RF Power: 100 W Gas Pressure: 6.65 Pa (50 mTorr) Oxygen Partial Pressure (O₂/(O₂ + Ar)): 50 % Spacing between Target and Substrate: 45 mm Film Forming Time: 6 h. Film Thickness: 0.8 to 1.2 µm Samples provided with the oxide superconducting layers were subjected to heat treatment in an oxygen atmosphere at 950 o C for 0.5 h. Table 1 shows values of critical current density T C , at which the oxide superconducting layers lost resistance R. Sample No. Al Impurity Concentration (wt.%) T C (R = 0) (K) Example 1 0.01 92 2 0.03 91 3 0.06 86 4 0.08 83 5 0.09 80 Ref. Example 1 0.10 60 2 0.20 38 3 0.30 21 As understood from Table 1, the oxide superconducting layers of Examples 1 to 5 exhibited high critical temperatures. On the other hand, reference examples 1 to 3, which contained excessive amounts of Al impurities beyond the scope of the present invention, exhibited extremely low critical temperatures as compared with Examples 1 to 5. Although tape-type members of yttria stabilized zirconia were used in the above Example , the base material employed in the present invention is not restricted to a tape-type one but may be provided in the form of a round wire, for example, with no particular restriction in sectional configuration.

Claims: A superconducting wire comprising: a flexible base material of yttria stabilized zirconia containing less than 0.1 percent by weight of an Al₂O₃ impurity; and an oxide superconducting layer formed on said base material. A superconducting wire in accordance with claim 1, wherein the content of said Al₂O₃ impurity is less than 0.05 percent by weight. A superconducting wire in accordance with claim 1 and/or 2, wherein the oxide superconductor layer is a thin film layer.

Inventors: HAYASHI NORIKI C O OSAKA WORKS, TAKANO SATOSHI C O OSAKA WORKS, HAYASHI, NORIKI, C/O OSAKA WORKS, TAKANO, SATOSHI, C/O OSAKA WORKS
Applicants: SUMITOMO ELECTRIC INDUSTRIES, SUMITOMO ELECTRIC INDUSTRIES, LIMITED
Application year: 1992
Main classification: C04B35
IPC codes: C04B35, H01L39