IMPROVED GLYPHOSATE FORMULATIONS

Abstract: This invention relates to agriculturally acceptable compositions containing N-phosphonomethylglycine for use in killing or controlling weeds, to a method for killing or controlling weeds and to a process for preparing these compositions. The compositions are dry and water soluble and comprise N-phosphonomethylglycine, an acid acceptor and optionally a solid or liquid surfactant.

Description: IMPROVED GLYPHOSATE FORMULATIONS Field of the Invention This invention relates to a substantially dry agriculturally acceptable composition(s) containing N- phosphonomethylglycine or a salt thereof, to a use of such a composition(s) in killing or controlling weeds and to a process for preparing such a composition(s) . Glyphosate (N-phosphonomethylglycine) is well known in the art as an effective herbicide. Glyphosate, an organic acid, is only slightly soluble in water. Glyphosate is typically commercially formulated and applied as a water-soluble salt, especially as the isopropylamine salt ( PA salt) . Various formulations of glyphosate, salts of glyphosate, methods for preparing salts of glyphosate, and methods of use thereof are disclosed in U.S. Patents 3,799,758 and 4,405,531 issued to John E. Franz on March 26, 1974 and September 20, 1983 respectively. Other U.S. patents which disclose salts of glyphosate include U.S. Patent 4,315,765 issued to George B. Large on February 16, 1982; U.S. Patent 4,507,250 issued to Izhak Bakel on March 26, 1985; U.S. Patent 4,397,676 issued to Izhak Bakel on August 9, 1983; U.S. Patent 4,481,026 issued to Michael P. Prisbylla on November 6, 1984; U.S. Patent 4,140,513 issued to Erhard J. Prill on February 20, 1979. Hungarian Patent Application No. 431/88 assigned to Alkaloida Vegyeszet discloses that water soluble plant-growth controlling solid active agents, N-phos¬ phonomethylglycine and its derivatives are mixed with carbonate and hydrogen carbonate salts and with customary plant protection additives. Sufficient initiating water is added to govern the extent of a double decomposition reaction between these compounds. The solid obtained is converted by colloid-chemical means into foams, creams, moist pastes and wet feel powders packaged as powders, granules or compressed briquettes. European Patent Application 0 127 773 Al assigned to Wellcome Foundation Limited, published 12/12/84 discloses a pesticidal composition comprising a pesticide, an emulsifier or dispersing agent for the pesticide, and a self-disintegrating agent capable of effervescing or swelling on being contacted with water. The composition is disclosed as being conveniently in the form of an effervescent pesticidal tablet. UK Patent Application GB 2 095 556 A published October 6, 1982 discloses a composition for controlling the presence of unwanted microorganisms comprising a probiocide that produce the biocide formaldehyde, an effervescent couple for evolving carbon dioxide and optionally a surfactant. UK Patent Specification 1 505 738 assigned to Kirby Pharmaceutical Limited, published March 30, 1978 discloses a process for the preparation of a water soluble chemical composition compounded in an effervescent tablet form, which comprises the direct pressing into tablet form by a direct compression process of a powder comprising a chemical compound, an alkali metal bicarbonate, an alkali metal carbonate and a solid, water soluble aliphatic carboxylic acid or an acid salt thereof. UK Patent Specification 1 516 682, assigned to SOGEMARIC, published July 5, 1978 discloses a mixture of one or more active phytosanitary materials (herbicides, growth regulators, insecticides, fungicides) in solid form, i.e. either the active material alone if it is solid, or impregnated on a solid, inert support if it is liquid, is mixed with the additives, wetting agents, dispersants of the type commonly used in the production of wettable powders,and with the non-hydrophilic filler and the disintegrating agent described therein. The mixture is homogenized and then compressed into tablets or pellets of the required shape under a pressure in the range from 50 to 1000 kg/cm 2 and preferably under a pressure in the range from 100 to 600 kg/cm 2 . DuPont PCT/US89/0272 discloses a tablet consisting essentially of about 20 to 75% of a pesticide melting about 100°C and having a water solubility of no more than about 5% and a delivery system consisting essentially of a dibasic or tribasic organic carboxylic acid, ammonium or alkali carbonate or bicarbonate, dispersant, PVP and an anionic or nonionic wetting agent whereby the dispersion of the pesticide in water is fine enough to pass a 50 mesh screen. Ciba Geigy AU-A-53042/90 discloses a pesticidal active ingredient concentrate in effervescent tablet form which disintegrates in water to form a sprayable suspension and consists essentially of a water insoluble active ingredient, surface-active agents, fillers and binders, flow regulators and a disintegrator, which concentrate contains the disintegrator in the form of an effervescent granulate comprising potassium carbonate and or potassium hydrogen carbonate, a solid water soluble acidic substance and a finely divided water- insoluble substance capable of binding water. DuPont EPO published patent application 0 360 441 discloses a water soluble granule and water dispersible granule composition whereby glyphosate is disclosed as a granular substrate along with potassium carbonate. Ciba Geigy AU-A-25886/88 discloses effervescent compressed pesticidal tablets comprising a sulfonyl urea, dispersion agent and a disintegrator further comprising a solid water soluble acidic substance, an alkali/alkaline earth metal/hydrogen carbonate, a gliding or flow regulating agent and optionally a filler or binder. Rhone Poulenc Published UK Patent specification GB 2 104 780 A discloses an effervescent herbicidal granule which is said to be a water soluble granule of an acid herbicide or plant growth regulator, alkaline carbonate/bicarbonate, impurities from the herbicide acid additives and surfactants or lubricants. EPO published patent application 0 204 146 discloses a herbicidal composition comprising (a) 2-(4- chloro-2-fluoro-5-propargyloxyphenyl)-5,6,7,8-tetra- hydro-lH-1,2,4-triazolo (1,2-s)pyridazine-1,3,-2H-dione (I) , with (b) glyphosate (i) glufosinate (ii) bialaphos (iii) and/or paraquat (l,l'-dimethyl-4,4'-bipyridiniu ion) (iv) or their salts and an inert carrier or diluent. EPO published patent application 0 255 760 discloses a granule shaped agricultural composition prepared by introducing to the top of a drying tower, a mixture of the agricultural chemical, an anionic surfactant and optionally one or more additives in the form of a concentrated solution or an aqueous slurry. Published Japanese patent applications J62175407 and J62175408 disclose a herbicide containing a solid carrier, additives, and a herbicidal component and having a particle size of 48-150 mesh. The disclosed herbicidal components are (3-amino-3-carboxy)propyl- l)methyl-phosphonic acid, N-(phosphonomethylglycine, (2- amino-4-methylphosphino-butyral) alanylalanine and their salts. Published European Patent Application 0 206 537 discloses a solid, substantially non-hygroscopic, phytoactive composition comprising an intimate mixture of a phytoactive N-phosphonomethyl-N-carboxymethyl compound and a surfactant which is solid at ambient temperatures. Published European Patent Application 0 256 608 discloses a method for the preparation of a solid, phytoactive composition comprising (a) reacting an acid form of a phytoactive N-phosphonomethyl-N-carboxymethyl compound with a liquid amine to form the amine salt of said N-phosphonomethyl-N-carboxymethyl compound (b) admixing said amine salt of said N-phosphonomethyl-N- carboxymethyl compound with a molten surfactant, the surfactant being solid at ambient temperature and (c) cooling said mixture to a temperature below the melting point of the surfactant to form a composition comprising said surfactant and said amine salt of N-phosphono- methyl-N-carboxylmethyl compound interdispersed in the matrix thereof and which is solid at ambient temperatures. Publication No. WO 87/04595 discloses a herbicidal water-soluble dry-particulate glyphosate formulation comprising the sodium salt of glyphosate and a surface active agent having the following formula: R 1 R 2 - N + - R 3 X~ wherein R 1 and R 2 are independently methyl or ethyl, R 3 is methyl, ethyl, benzyl or C 10 to C 18 alkyl, R 4 is C 10 to C 1g alkyl and X is chloro or bromo. Japanese LOP 145,205-88 discloses an aqueous concentrate herbicidal formulation comprising a water soluble glyphosate salt, ammonium sulfate and a quaternary ammonium salt. PCT/WO8704712 discloses a method of preparing a particulate alkali metal salt of N-phosphonomethyl¬ glycine, which comprises adding a solid alkali metal base with agitation to N-phosphonomethylglycine containing up to 25% water. Research Disclosure dated November 1986 discloses in publication 27161 a wettable powder formulation effective in control of weeds comprising N-phosphono¬ methylglycine, a non-ionic surfactant, diatomaceous earth, an inorganic salt (ammonium sulphate) and an antifoaming agent. Chemical Abstracts 103: 191395k (1985) Glyphosate preparations. Davydov, A.M.; Vechtomova, T.N. ; Bazunova, G. G. (USSR) . Zashch. Rast. (Moscow) 1985, (9), 40-l(Russ) discloses the 36% aq. soln. Utal (I) [96638-41-4] and the 50% wettable powder Fosulen (II) which are Soviet brands of glyphosate. SUMMARY OF THE INVENTION The invention comprises a substantially dry, water soluble or dispersible, agriculturally acceptable composition comprising substantially nonreacted N- phosphonomethylglycine, an acid acceptor and optionally a solid and/or liquid surfactant, the optional liquid surfactant if present preferably in the range from about 0.2 to about 15.0% by weight surfactant and more preferably in the range of 0.2 to 10.0% by weight surfactant although greater amounts of optional liquid surfactant may be employed depending on other formulation ingredients. The term agriculturally acceptable includes use of compositions of this invention in the homeowner, and apartment areas as well as industrial, residential and other similar areas where use may be convenient. Compositions of this invention optionally further comprise ammonium sulfate, alkali metal sulfates such as potassium sulfate, sodium sulfate, alkali metal chlorides such as potassium chloride, urea, mixtures thereof and the like. The composition may optionally include a synergist, a quick-burn additive, a humectant, a co-herbicide, a dye, a pigment, a corrosion inhibitor, a thickener, a dispersing agent, a calcium sequestrant, mixtures thereof and the like. In a process for preparing the composition of this invention, the substantially dry, water soluble, agriculturally acceptable composition is prepared by admixing substantially unreacted N-phosphonomethyl¬ glycine and an acid acceptor, and optionally a solid or liquid surfactant, optionally with pulverized ammonium sulfate and thereafter blending, tabletting, compacting, briquetting, or granulating, such as by wet extrusion, these illustrative ingredients and optional ingredients to form a composition(s) of this invention. Objects of the Invention It is an object of this invention to provide a dry, water soluble, agriculturally acceptable glyphosate composition for use including the homeowner and residential market. It is an object of this invention to provide a process for preparing a dry, water soluble powder or granular agriculturally acceptable composition optionally containing a surfactant. It is yet another object of this invention to provide a herbicidal method of use for killing and controlling weeds using a substantially dry, water soluble, agriculturally acceptable composition. It is a further object of this invention to provide the substantially dry, water soluble, agriculturally acceptable formulation which can be transported at a lower cost, which has increased content of herbicidally active ingredients (N-phosphonomethyl¬ glycine, acid acceptor, optional surfactant) , which can be mixed with various co-herbicides in compatible fashion to form a storage stable composition and which can be packaged, (combustible or recyclable or disposable) containers if desired and which is easy to use. These and other objects are achieved in this invention which is hereinafter described in more detail. Detailed Description of the Invention The invention comprises a substantially dry, water soluble, (preferably powder or granular) agricul¬ turally acceptable composition comprising N-phosphono¬ methylglycine, an acid acceptor and optionally a solid or liquid surfactant. If prepared as a substantially dry material as for example a powder, illustratively the powder is typically less than about minus 50 mesh and contains in the range from about 0.01% weight to about 10.0% weight and preferably less than about 2% weight percent water but more than about 0.2%, although greater or lesser amounts of moisture may be present depending on the formulation ingredients selected. If desired, a defoamer, a corrosion inhibitor, a thickener, a dispersing agent, a calcium sequestrant, a synergist, a quick burn down additive, a humectant, a co-herbicide, a dye or a pigment may be admixed individually or collectively in the composition. Certain co-herbicides which form water soluble salts may be used if desired. Such co-herbicides may be selected from the group consisting of 2,4-D (2,4- dichlorophenoxyacetic acid), dica ba (3,6-dichloro-o- anisic acid), piclora (4-amino-3,5,6-trichloro- pyridine-2-carboxylic acid) , MCPA (4-chloro-o- tolyloxyacetic acid), dalapon (2,2-dichloropropionic acid), dichlorprop 2-(2,4-dichlorophenoxy)propionic acid), MCPB (4-[ (4-chloro-o-tolyl)oxy]butyric acid), acifluorfen (5-[2-chloro-4-(trifluoromethyl)phenoxy]-2- nitrobenzoate) , chloramben (3-amino-2,5-dichlorobenzoic acid), endothall (7-oxabicyclo(2.2.1)-heptane-2,3- dicarboxylic acid), mecoprop ([2-(2-methyl-4- chlorophenoxy)propionic acid], 2,4,5-T (2,4,5- trichloroacetic acid), 2,3,6-TBA (2,3,6- trichloro- benzoic acid) , glufosinate-ammonium (3-amino-3- carboxypropyl)-methylphosphinate, imazapyr (2-[4,5- dihydro-4-methyl-4-(l-methylethyl)- 5-oxo-lH-imidazol- 2-yl]-5-ethyl-3-pyridinecarboxylic acid) , imazaquin, (2- [4,5-dihydro-4-methy1-4-(1-methylethyl)-5-oxo-lH- imidazol-2-yl]-3-quinolinecarboxylic acid) , bialaphos (DL-homoalanin-4-yl-methyl-phosphinate) , mixtures thereof and the like. If further desired, the co-herbicide salt may be blended in the composition instead of the acid form being included in glyphosate and acid acceptor, (optional surfactant) composition. It may be preferred to utilize a solid, water insoluble co-herbicide in a composition of this invention. In that embodiment, the co-herbicide is present in the composition as a fine powder: sulfonylureas such as sulfo eturon-methyl (2-[3-(4,6- dimethylpyrimidin-2-yl)ureidosulphonyl]benzoiσ acid) , and chlorsulfuron (l-(2-chlorophenylsulphonyl)-3-(4- methoxy-6- methyl-l,3,5-triazin-2-yl)urea) , diuron (N 1 - (3,4- dichlorophenyl)-N,N-dimethylurea) simazine (2- chloro-4,6-bis(ethylamino)-5-triazine) , metsulfuron- ethyl (methyl 2-[[[[4-methoxy-4-methyl-l,3,5-triazin- 2-yl)amino]- carbony1]-amino]sulfon 1]benzoate) , chlorimuron-ethyl (ethyl 2-[[[[(4-chloro-6-methoxy- pyrimidin-2-yl)amino]-carbony1]-amino]sulfonyl]- benzoate), linuron (N-(3,4-dichlorophenyl)-N-methoxy-N- methylurea) , atrazine (2-chloro-4-(ethylamino)-6- (isopropylamino)-s-triazine) , mixtures thereof and the like. It may be desirable to include a dispersing agent. For example, the water insoluble co-herbicide may also be a liquid or solid present in said composition as a water dispersible granule: alachlor (2-chloro-2•,6'- diethyl-N-methoxymethylacetanilide) , acetochlor (2- chloro-2*-ethyl-6*-methyl-N-ethoxymethyl-acetanilide) , atrazine (2-chloro-4-(ethylamino)-6-(isopropylamino)-s- triazine, metolachlor (2-chloro-6 l -ethyl-N-(2-methoxy- l-methylethyl)acet-o-toluidide) , fomesafen (5-[2- chloro-4-(trifluoro ethyl)phenoxy]-N-(methyl-sulfonyl)- 2-nitrobenzamide) , oxyfluorfen (2-chloro-l-(3-ethoxy-4- nitrophenoxy)-4-(trifluoromethyl)benzene) , fenoxaprop- ethyl ethyl 2-[4-(6-chloro-2-benzoxazolyloxy)- phenox ]propanoate) , diuron N'-(3,4-dichlorophenyl)- N,N-dimethylurea, metsulfuron-methyl, simazine 6- chloro-N-N'-diethyl-l,3,5-triazine 2,4-diamine, chlorimuron-ethyl, linuron, chlorsulfuron, sulfometuron- ethyl, mixtures thereof and the like. Suitable acid acceptors may be illustratively selected from the group consisting of ammonium and alkali metal carbonates, bicarbonates, meta borates, acetates, citrates, formates, oxalates, phosphates, propionates, pyrophosphates, metasilicates, orthosilicates, sulfites, thiosulfates, tetraborate, monoacid phosphates, tripolyphosphates, metaphosphates, sodium hydroxide, potassium hydroxide, tetrasodiu EDTA, mixtures thereof and the like. In this invention the composition comprises substantially nonreacted glyphosate (N-phosphonomethyl¬ glycine) , an acid acceptor and an optionally solid or liquid surfactant. A liquid surfactant can be used if present in small enough quantity or if a large quantity of an additive such as ammonium sulfate is present or if adsorbed on a high surface area carrier. Using sodium acetate as an example of an acid acceptor and without being bound by theory, the following reaction may occur upon dissolving a glyphosate/sodium acetate mixture in water. 0 II HOOCCH 2 NHCH 2 P (OH) 2 + CH 3 C00Na → O II [HOOCCH,NHCH,POH] ~ + Na+ + CH,C00H I Oθ The pKa's for glyphosate are 2.27, 5.58 and 10,25. In order for a basic salt to be useful for solubilizing glyphosate, it must be a salt of an acid with a pKa somewhat greater than 2.27. Also, unless it precipitates as a fine solid, e.g. oxalic acid, the acid should be water soluble. The pKa values for a number of acids and the equivalents of base available from their salts (i.e. sodium, potassium, ammonium, etc.) for solubilizing glyphosate are provided in Table I. TABLE 1 To solubilize glyphosate of a salt such as sodium, potassium, ammonium, amine, etc. ** Only two equivalents of base can be utilized because EDTA and its mono-and disodium salts have very low water solubility Suitable surfactants (optional) include nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric surfactants, mixtures thereof and the like, preferably ones that provide increased herbicidal 5 activity of N-phosphonomethylglycine or its salts. Examples of optional nonionic surfactants are polyoxyethylene polyoxypropylene block copolymers, polyoxyethylene alkyl phenols, polyoxyethylene oleyl 10 ethers, alkylglycosides, mixtures thereof and the like Examples of optional anionic surfactants are sodium lauryl sulfate, sodium mono- and di- alkyl naphthalene sulfonates, sodium alpha-olefin sulfonates, 15 sodium alkylbenzene sulfonates, sodium alkane sulfonates, mixtures thereof and the like, including sodium, potassium and amine salts. Examples of optional cationic surfactants are 20 ethoxylated fatty amines and their corresponding quaternary salts such as ethoxylated tallowamines, ethoxylated oleylamines, ethoxylated cocoamines and ethoxylated soyamines, mixtures thereof and the like. 25 Examples of other optional cationic surfactants include propoxylated quaternary ammonium surfactants. is an alkyl group) or i + j (in a compound in which R 3 is a group having the formula (AO) j -H) has a value of from 2 to 20; and X " is a suitable anion. A preferred composition of the invention comprises a glyphosate herbicide and a quaternary ammonium compound the latter having a structure represented by the formula: wherein -EO- is an ethylene oxide radical and -PO- is a propylene oxide radical, R 1 and R 2 are each independently an alkyl group having from 1 to 3 carbon atoms; R 3 is an alkyl group having from 1 to 3 carbon atoms, a group having the formula (EO) m -H or a group having the formula EO-(PO) m -H; n (in a compound in which R 3 is an alkyl group) or n + m (in a compound in which R 3 is a group having the formula E0-(P0) m -H), has a value of from 2 to 20; and X ~ is a suitable anion and n and m are each independently varying integers. Examples of optional suitable amphoteric surfactants are Monaterics, Miranols, betaines, Lonzaines, mixtures thereof and the like. Preferable agriculturally acceptable salts of N- phosphonomethylglycine include the ammonium, isopropylamine, trimethylsulfonium, iminourea salts, sodium, potassium salts, mixtures thereof and the like. In another embodiment the composition of this invention may further comprise ammonium sulfate, potassium sulfate, potassium chloride, sodium sulfate. urea, mixtures thereof and the like. If desired, the composition may include a defoamer. If desired, the composition may further include a synergist, a quick-burn additive, a humectant, a co- herbicide, a dye, a pigment, a dispersing agent, a corrosion inhibitor, a thickener, a calcium sequestrant, a bittering agent, mixtures thereof and the like. The thickener is typically selected from the group consisting of sodium ligninsulfate, starches, cellulose derivatives, high molecular weight polyoxyethylenes, gums, mixtures thereof and the like. If desired, a dry, water soluble, agriculturally acceptable composition of this invention may be prepared in a process which comprises admixing pulverized ingredients, N-phosphonomethylglycine, acid acceptor, and optional solid or liquid surfactant, optionally with pulverized ammonium sulfate and thereafter blending these ingredients to form said composition. Optionally, the blended ingredients may be pulverized. After the blending operation, wet extrusion may be carried out, followed by an optional drying step. This invention also includes a method of killing or controlling weeds by applying a herbicidally effective amount of composition of this invention to the locus of the plant or weed to be killed or controlled as prepared if dew is present and the form of a composition of this invention is suitable for example a wettable powder, or preferably by adding diluent water and spraying the diluted composition on the weed. The preferred shape of a composition of this invention is that of a tablet wherein the tablet is about 2 inches (5.1 cm) long by about 1/2 inch (1.3 cm) wide by about 1/2 inch (1.3 cm) thick although greater or lesser individual measurements and sizes may be employed if desired. The preferred weight is in the range from about 1 to about 36 grams. Typically a pump-up type or hand trigger sprayer will be used for applying a diluted composition of this invention to weeds or plants. The sprayer will preferably be filled with about 12 ounces (340 grams) clear water and a tablet comprising a composition of this invention is added. The tablet is left to dissolve (about 1 to about 3 minutes) and then additional water (about 12 ounces) (340 grams) is added. The following examples are presented to illustrate the present invention as well as some of the various embodiments of the inventions. These examples are presented as being illustrative of the novel formulations and herbicidal use and are not intended to be a limitation of the scope of this invention. EXAMPLES EXAMPLE 1 Examples of Water Soluble Powder (WSP) formulations with illustrative acid acceptors and using an optional surfactant were prepared by blending the ingredients which had been previously ground to minus 50 mesh. An N-phosphonomethylglycine/optional surfactant weight ratio of 2:1 was used. A higher or lower ratio could be used. Five percent excess acid acceptor over theory was usually employed. The compositions are shown in this Example. EXAMPLE 1 GLYPHOSATE* SURFACTANT** SWS-131 Defoamer, ACID ACCEPTOR. WEIGHT % Weight % Weight % Weight % Trisodium phosphate, 25.75 Trisodium phosphate, 23.28 0.05 Potassium oxalate.H 2 0, 53.12 Sodium formate, 21.91 Sodium formate, 21.19 0.05 Sodium citrate, 28.17 Sodium propionate, 27.50 0.05 Sodium propionate, 28,39 Sodium tetraborate.lOH 2 0, 44.20 Sodium sulfite, 20.63 Sodium sulfite, 19.84 Sodium acetate, 24.48 0.50 Disodium EDTA.2H 2 0***, 42.53 Tetrasodiu EDTA, 42.76 Sodium oxalate, 29.31 Sodium oxalate, 22.15 0.50 Sodium tetraborate.5H 2 0, 36.63 0.05 Ammonium acetate, 24.12 Potassium acetate, 28.81 Tripotassiu phosphate, 25.55 0.05 EXAMPLE 1 ...Continued ACID ACCEPTOR. WEIGHT % Sodium carbonate, 17.25 Sodium carbonate, 17.80 Sodium ortho silicate, 15.28 Sodium meta silicate, 19.30 Sodium oxalate, 36.26 Sodium oxalate, 53.09 Sodium hydroxide (76%) 16.04 t * 99.6% glyphosate used. ** Witconate AOS, a liquid concentrate, was dried and powdered. The percentages given are for the dried material. Witconate AOK is a dry product. The composition of this surfactant can be found in Table II. *** EDTA, mono and di-sodium EDTA are insoluble in water; therefore, only two equivalents of tetrasodium EDTA are available for solubilizing glyphosate, EDTA precipitated when disodium EDTA was used as an acid acceptor. Water soluble powders (WSP) formulations were prepared for use in bioassay tests to determine the relative contributions of the various acid acceptors to the glyphosate herbicidal activity. The compositions of the WSP formulations are shown in this Example. EXAMPLE 2 FORMULATION COMPOSITIONS INGREDIENTS A B C D E F G H I J K L M N O Glyphosate 50.43 48.32 52.65 50.98 47.62 46.37 47.69 40.50 11.70 13.92 50.47 49.75 40.73 29.84 38.23 (99.5%) Witconate 27.88 24.48 29.10 28.18 26.34 25.63 26.26 22.37 6.47 7.70 27.90 27.60 22.51 16.57 19.01 AOK (90%)* SWS Q-131** 0.50 0.50 1.00 1.00 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Sodium 21.19 4.92 5.84 9.89 Formate Sodium 26.70 Acetate Sodium 27.50 Propionate Sodium 23.28 Phosphate Sodium 33.63 Tetraborate.5 H z O Tetra sodium EDTA 42.76 Sodium carbonate 17.25 Sodium sulfite 19.84 Potassium phosphate 25.55 EXAMPLE 2 . . . Continued FORMULATION COMPOSITIONS INGREDIENTS E F G H I M N Sodium oxalate 11.23 2.15 36.26 53.09 Ammonium sulfate 76.42 Ammonium chloride 72.03 Glyphosate assay 50.18 48.08 52.39 50.73 47.38 46.14 47.45 40.30 11.64 13.85 50.22 49.73 40.53 29.69 38.04 * Powder form of Witconate AOS ** Silicon defoamer on an inert carrier EXAMPLE 3 The results of the bioassay test of Example 2 formulations are shown below. Roundup herbicide was used as a comparative of the prior art. Comparing the results of formulation A versus formulation I shows the beneficial effect of ammonium sulfate (AS) . In all of the greenhouse bioassay tests provided in this specification, pot-grown weed species were sprayed with aqueous solutions of the glyphosate WSP formulations using a track sprayer calibrated to apply about 20 gallons/acre (187 liters/hectare) at about 30 psi (21 kilo Pascals) . BIOLOGICAL EVALUATION OF SEVERAL WATER-SOLUBLE POWDER HERBICIDE FORMULATIONS FORMULATION TREATMENT % INHIBITION* COMPARATIVE Roundup Herbic A HCOONa B CH 3 C00Na C Na 2 C0 3 D Na 2 S0 3 E Na 3 P0 4 F CH 3 CH 2 C00Na G K 3 P0 4 H Na 2 B 4 0 7 I HCOONa (NH 4 ) 2 S0 4 21.7 HCOONa NH 4 C1 7.1 K (C00Na) 2 15.4 0 Na A EDTA 25.4 P Untreated Check 0 * The mean of four rates (1/8, 1/4, 1/2 and 1 pounds glyphosate/acre) (0.14, 0.28, 0.56 and 1.12 kg/ha) on Johnsongrass as the weed species, four weeks after treatment. EXAMPLE 4 In order to determine the effect of various acid acceptors on glyphosate activity, WSP formulations were prepared without Witconate surfactant. The surfactant was tank mixed into the spray solutions for bioassays. Example 5 hereinafter shows the results when surfactant, an ethoxylated tallow amine was used and Example 6, when Witconate AOS was used. EXAMPLE 4 WSP FORMULATIONS WITHOUT SURFACTANT FORMULATION COMPOSITIONS INGREDIENTS B C D E F G K Glyphosate (99.5%) 70.41 64.41 74.57 71.99 67.17 62.77 65.11 52.51 62.28 75.47 70.72 47.20 SWS Q-131 1.00 A. Sodium formate 29.59 B. Sodium acetate 35.59 F. Sodium propionate 37.23 E. Sodium phosphate 32.83 Sodium tetraborate 4H 2 0 • 47.49 c. Sodium carbonate 24.43 D. Sodium sulfite 28.10 G. Potassium phosphate 34.89 I. Potassium acetate 37.72 J. Sodium hydroxide (76%) 24.53 K. Sodium oxalate 29.98 . Tetrasodium EDTA 52.80 Glyphosate (100%) 70.37 64.38 74.53 71.95 67.14 62.74 65.08 52.48 62.25 75.43 70.68 47.18 EXAMPLE 5 EVALUATION OF WSP FORMULATIONS (ACID ACCEPTORS) USING AN ETHOXYLATED AMINE SURFACTANT HAVING A DEGREE OF ETHOXYLATION IN THE RANGE FROM ABOUT 15 TO ABOUT 18 * On Johnsongrass, mean of four rates (1/4, 1/2, 3/4 and 1 pound glyphosate/acre) (0.28, 0.56, 0.84 and 1.12 kg/ha), 4 weeks after treatment. ** 0.25 % an ethoxylated amine surfactant present in all spray solutions. Comparing the bioassay results with the ethoxylated amine surfactant (Example 5) with those of Example 3, shows that the inhibitions are highly surfactant dependent. EXAMPLE 6 EVALUATION OF WSP ACID ACCEPTORS USING WITCONATE AOS SURFACTANT TREATMENT**** % INHIBITION* SJG** MG*** Isopropylamine salt of glyphosate 49.3 42.8 Sodium Sulfite 36.1 40.6 Sodium propionate 41.7 40.6 Potassium Phosphate 30.0 31.7 Potassium Acetate 28.3 45.6 I Sodium Hydroxide 41.3 23.3 t I Sodium oxalate 54.5 50.0 Tetrasodium EDTA 47.2 35.6 Untreated Check 0 0 * Mean of 3 rates (1/4,1/2, 1 pound glyphosate per acre) (0.28, 0.56, 1.12 kg/ha), on Johnsongrass and 3 rates (1/2,1,1.5 pound glyphosate/acre) (0.56, 1.12, 1.68 kg/ha) on morning glory. ** Seedling Johnsongrass *** Morning glory **** Sprays containing sodium oxalate and sodium EDTA were best against Johnsongrass, whereas those containing sodium oxalate and potassium acetate were best against morning glory. Thus, the acid acceptor giving the best results depends on the weed species and from other tests (see Examples 5, 6 and 12), the surfactant. EXAMPLE 7 Glyphosate WSP formulations were prepared and shown to be water soluble using various surfactants at several ratios to glyphosate. WSP WITH DIFFERENT SURFACTANTS 99.6% GLYPHOSATE GLYPOSATE/SURFACTANT ACID ACCEPTOR, % SURFACTANT*. % RATIO sodium ortho silicate, 15.38 Witconate AOK (90%) 15.38 4:1 20.30 42.11 1:1 14.36 1:2 sodium formate. 20.19 2:1 20.19 2:1 21.65 2:1 21.65 2:1 21.21 2:1 21.21 2:1 21.88 2:1 21.21 2:1 20.41 2:1 19.44 2:1 In all solubility tests the glyphosate/water ratio was 1:30 unless otherwise stated. * See Table II for composition of the surfactants. Comments: Example 3 - surfactant dissolved slowly. Example 9 and 10 solution milky in 60 parts water. Example 13 - 60 parts water required. Acid herbicides such as picloram (4-amino-3,5,6- trichloropyridine-2-carboxylic acid), dicamba (3,6- dichloro-o-anisic acid), 2,4-D (2,4-dichloro phenoxy)- acetic acid) , Bialaphos, MCPA (4-chloro-o-tolyloxyacetic acid) are especially suitable for WSP package mixes with glyphosate since they can also be solubilized by the acid acceptor as is glyphosate. Optionally, a water soluble salt of the acid actives could be blended with the glyphosate WSP formulation. The compositions of package mix WSPs prepared are found in EXAMPLE 8. Included are the straight package mixes and ones with dicamba (3,6-dichloro-o-anisic acid), 2,4-D (2,4-dichlorophenoxy)acetic acid) and picloram (4-amino-3,5,6-trichloropyridine-2-carboxylic acid) also containing ammonium sulfate, which are common tank mix combinations. A defoamer and an anti-drift agent may also be included. The ratios of ingredients can be varied greatly as long as sufficient acid acceptor is present. EXAMPLE 8 GLYPHOSATE WSP PACKAGE MIXES CO-HERBICIDE , % ACID ACCEPTOR, % Dicamba ( 88% ) , 18. 54 sodium hydroxide (76%) Dicamba (84%) 26.69 trisodium phosphate, Dicamba (86%) 11.45 sodium tetraborate.10 H 2 Dicamba (86%), 15.10 sodium hydroxide (76%) 2,4-D (97%), 28.28 trisodium phosphate 13.54 25.46 sodium tetraborate.10H 2 O 18.14 sodium hydroxide (76%) 32.43 Picloram (92%) 1.18 tripotassium phosphate 5.29 Witconate AOS is a 39% aqueous product which was dried down and powdered. AOK is the commercial dry powder. Both are approximately 90% active. EXAMPLE 9 An important advantage of glyphosate WSP formulations over the commercially available aqueous Roundup formulation is the ability to incorporate solid additives including illustrative types which have been enumerated previously. Water-insoluble liquid additives, in small quantity or absorbed on a carrier can also be used. Example 9 also shows a number of examples of additives combined with WSP containing various acid acceptors. EXAMPLE 9 GLYPHOSATE WSP CONTAINING ADDITIVES ADDITIVE , % ACID ACCEPTOR. % % GLYPHOSATE(99.6%. SURFACTANT. % ammonium sulfate, 76.14 sodium acetate, 5.85 11.65 Sellogen HR (75%), 6.36 77.75 sodium carbonate, 3.86 11.90 Witconate AOS***, 6.49 76.57 sodium thiosulfate.5 H 2 0 5.31 11.72 6.40 76.03 sodium bicarbonate, 5.98 11.63 6.35 76.14 tripotassium phosphate, 7.54 11.44 6.25 77.14 sodium sulfite 4.62 11.80 6.44 75.85 trisodium phosphate, 6.22 11.60 Witconate AOS 6.33 76.42 sodium formate, ** 4.92 11 .70 6.47 69.81 sodium hydroxide (76%), 5.12 16. 36 AOK 8.71 ammonium chloride 72.03 5.85 13.92 7.70 oxalic acid'HgO 32.84 trisodium phosphate 17.75 3322..9999 6.42 * H 2 S odor present indicating decomposition of the thiosulfuric acid formed. ** Formulation contains 0.5% SWS-131 defoamer. Dried to give 90% powder. Combinations of glyphosate WSPs and water insoluble co-herbicides can be accomplished using finely powdered co-herbicides or co-herbicides as WDG formulations. Co-herbicides could be either liquids or solids as WDGs and could include alachlor, atrazine, MON 097, Dual, Goal, Whip, actives, etc. Solid actives such as Oust, Glean, diuron, simazine, atrazine, Wily, Classic, etc. could be incorporated in the WSP as fine powders. A glyphosate/alachlor formulation was prepared by blending an alachlor water dispersible granule (67%) with glyphosate WSP based upon sodium hydroxide and Witconate AOK or Sellogen HR. Combinations of glyphosate WSPs and water insoluble co-herbicides can be accomplished using finely powdered co-herbicides or co-herbicides as WDG (water dispersible granules) formulations. Co-herbicides can be either liquids or solids as WDGs and can include alachlor, atrazine, MON-097, Dual, Flex, Goal, Whip, actives, etc. Solid actives such as Oust, Glean, diuron, simazine, atrazine, Ally, Classic, etc. can be incorporated in the WSP as fine powders. A dispersing agent may be beneficial in the latter formulations. A glyphosate/alachlor formulation was prepared by blending an alachlor WDG (67% active) with WSPs based upon sodium hydroxide and witconate AOK or Sellogen HR. The formulations were as follows: INGREDIENTS A B Glyphosate (95.8%) 54.19 51.23 Sodium hydroxide (76%) 16.79 16.04 Witconate AOK (90%) 28.84 Sellogen HR (75%) 32.73 The following blends were prepared and added to 40 ml of water, stirred and poured into small diameter, 50 ml Nessler tubes and inverted 10 times to give the following results: SAMPLE INITIAL APPEARANCE 1 Hr 24 Hr REDISPERSE D. 1.55 g A Homogeneous Trace 4mm sed. , 2 inversions required 2.00 g WDG Sediment clear solution E. 1.63 g B 2 mm 15 inversions required 3.00 g WDG Sediment F. 3.00 WDG Very 9 mm No redispersion in 15 Flocculated Loose Sediment inversions TABLE II COMPOSITION OF SURFACTANTS Morwet B (75%) sodium n-butylnaphthalene sulfonate Morwet DB (75%) sodium dibutylnaphthalene sulfonate Morwet EFW (94%) blend of alkylnaphthalene sulfonate and a sulfonated carboxylate Morwet IP (75%) sodium diisopropylnaphthalene sulfonate Morwet M (96%) sodium mono and dimethylnaphthalene sulfonate Sellogen HR (75%) sodium diisopropylnaphthalene sulfonate Witconate KAS-10 (90%) - Witco EXP 5093-15C, Potassium decyl sulfonate Sodium dodecyl sulfonate (90%) - prepared from the corresponding IPA salt (Witco EXP 4896-9) Potassium tetradecyl sulfonate(90%)-prepared from the corresponding IPA salt(Witco EXP 4896-10) Sodium tetradecyl sulfonate(90%) - prepared from the corresponding IPA salt (Witco EXP 4896-10) Witconate NAS-1416 (90%) - Witco EXP 5093-15D, (mixture of sodium tetradecyl and hexadecyl sulfonate) Witconate KOAS-10 (90%) - Witco EXP 5093-15A, potassium decyl alpha-olefin sulfonate Witconate AOS-12 (90%) - Witco EXP 5042-87B, sodium dodecyl alpha-olefin sulfonate Witconate KOAS 14-16 (90%) - Witco EXP 5093-15B, potassium tetradecyl and hexadecyl-alpha- olefin sulfonate Witconate AOK (90%) - sodium tetradecyl and hexadecyl alpha-olefin sulfonate (dry form of Witconate AOS) Aerosol 0TB (100%) - Na dioctylsulfosuccinate/benzoic acid complex Igepon T-77 (67%) - Sodium N-methyl-N-oleyl taurate EXAMPLE 11 The following master batches were prepared from minus 50 mesh ingredients. INGREDIENTS A B Glyphosate (99. ,5%) Sodium oxalate Sodium hydroxide (76%) % glyphosate present Spray solutions for bioassays to compare the effectiveness of the various surfactants were prepared by adding the desired weights of master batch and surfactant to give an N-phosphonomethylglycine surfactant ratio of 2:1. The bioassay results are provided in Example 12. EXAMPLE 12 BIOLOGICAL EVALUATION OF DRY SURFACTANTS FOR USE WITH WSP FORMULATIONS % INHIBITION* Means of 3 rates (1/4, 1/2, 3/4 pound per acre of glyphosate) (0.28, 0.56, 0.84 kg/ha) against Johnsongrass four weeks after treatment. ** All surfactants were added to give 0.5% of 100% surfactant. *** % inhibition for formulations based on sodium oxalate as the acid acceptor. **** % inhibition for formulations based on sodium hydroxide as the acid acceptor. EXAMPLE 13 Witconate AOK and Sellogen HR were used as surfactants for field testing glyphosate WSP formulations. Field test plots of 10x25 ft. (3.05 x 7.62 meters) replicated three times using a randomized complete block design at 10 locations were sprayed using a tractor-mounted sprayer calibrated to apply 10 gallons/acre (94 liters/hectare) of the aqueous solutions of the WSPs at several concentrations of glyphosate. The components of the formulations field tested were as follows: CO-HERBICIDE ADDITIVE Ammonium sulfate 2 , 4-D II Ammonium sulfate Dicamba II Ammonium sulfate EXAMPLE 14 The composition of the field test formulations follow: WEIGHT/ CODE INGREDIENTS % GRAMS 0.5 245 Glyphosate (95.8%) 51.79 142 Sodium oxalate 20.64 566.2 Witconate AOK (90%) 27.57 756.0 246 Glyphosate (95.8&) 49.08 1420.6 Sodium oxalate 19.56 566.2 Sellogen HR (75%) 31.36 907.4 247 Glyphosate (95.8%) 54.19 1420.5 Sodium hydroxide (76%) 16.79 444.7 Witconate AOK (90%) 28.84 756.0 248 Glyphosate (95.8%) 51.23 1420.5 Sodium hydroxide (76%) 16.04 444.7 Sellogen HR (75%) 32.73 907.4 249 Glyphosate (95.8%) 16.36 1420.5 Sodium hydroxide (76%) 5.12 444.7 Witconate AOK (90%) 8.71 756.0 Ammonium sulfate 69.81 6059.8 250 Glyphosate (95.8%) 18.47 1420.5 2,4-D (97%) 32.43 2494.0 Witconate AOK (90%) 34.95 2688.0 Sodium hydroxide (76%) 14.15 1088.0 251 Glyphosate (95.8%) 10.33 1420.5 2,4-D acid) (97%) 18.14 2494.0 Witconate AOK (90%) 19.55 2688.0 Sodium hydroxide (76%) 7.91 1088.0 Ammonium sulfate 44.07 6059.8 252 Glyphosate (95.8%) Dicamba (88%) Witconate AOK (90%) Sodium hydroxide (76%) 253 Glyphosate (95.8%) Dicamba (88%) witconate AOK (90%) Sodium hydroxide (76%) Ammonium sulfate 312 Glyphosate (95.8%) Sodium hydroxide (76%) Witconate AOS-12 (90%) Summaries of the field test data are presented in EXAMPLES 15 AND 16. The WSPs based on Witconate AOK and sodium oxalate are equivalent to commercial Roundup. The sodium hydroxide /Witconate AOK/ammonium sulfate WSP was equivalent to the Roundup/ammonium sulfate tank mix. The glyphosate/2,4-D WSP was less active than Landmaster whereas when both formulations contained ammonium sulfate, they were equivalent. Similar results were obtained with the dicamba systems. EXAMPLE 15 FIELD TEST RESULTS FOR GLYPHOSATE WATER SOLUBLE POWDER (WSP) FORMULATIONS TREATMENT % CONTROL* Grasses Broadleaves Roundup (As Comparative) 74 61 Glyphosate/Sellogen Sellogen/sodium oxalate WSP 71 59 Glyphosate/AOK/ sodium oxalate WSP 79 66 Glyphosate/ Sellogen/NaOH WSP 58 43 Glyphosate/ AOK/NaOH WSP 69 58 Roundup/AS** 82 75 (As Comparative) Glyphosate/ AOK/NaOH/AS WSP 82 77 * Average of plots at multiple locations ** Ammonium sulfate was added to a tank mix of Roundup. EXAMPLE 16 FIELD TEST DATA FOR PACKAGE MIX WSP FORMULATIONS TREATMENT LANDMASTER** GLYPHOSATE/2,4-D WSP LANDMASTER/AS GLYPHOSATE/ 2,4-D/AS/WSP MON-8778*** GLYPHOSATE/DICAMBA WSP MON 8778/AS GLYPHOSATE/DICAMBA/AS WSP * Average of plots at multiple locations ** Commercial aqueous formulation of glyphosate and 2,4-D *** Aqueous Roundup herbicide/dicamba tank mix EXAMPLE 17 A premix powder formulation was prepared according to the following formulation: Glyphosate acid was substantially unreacted. This means that glyphosate is applied to plants as glyphosate acid if no water is added to the formulation of this invention. If water is added, it is believed that glyphosate reacts with the acid acceptor and some glyphosate salt is formed. This premix powder was processed into water soluble granules (WSG) by first compacting the pre-mix powder into wafer shape using a roller compactor called a Chilsonator. This roller compactor employed pressures of about 4000 pounds per square inch (27.6 x 10 3 kilo Pascals) . The wafers from this Chilsonator were then ground to about 12 mesh or less using a Straub 4E grinder (similar to a grist mill, although a Fitz mill is preferred) . The powder from the Straub grinding process was screened off and recycled again through the Chilsonator. The process of using the Chilsonator and the Straub grinder was repeated until a desired amount of granules were made. The powder prepared in the immediately described process above was fed into a hopper and then using a volumetric feed system was fed into a dye/punch/moId arrangement for formation into tablets. Pressure was applied to the punch and dye and tablets were formed. The pressure was removed and the tablets were ejected. The tablets weighed about 4.5 grams plus or minus 0.2 gram. The tablets were about 0.75 inch (1.91 cm) in diameter and about 0.5 inch (1.27 cm) in height. Tablets of different weights and configurations can also be made using this process. EXAMPLE 18 Glyphosate acid technical (43% w/w) , a propoxylated quaternary ammonium surfactant (15% w/w) known as Dodigen 4022 and ammonium sulfate 97% (30% w/w) are mixed in a planetary mixing equipment until a homogeneous dough is obtained. Sodium carbonate (12% w/w) is then added to the dough which is quickly homogenized and immediately pelleted by an extruder before being dried in a fluid bed dryer. The final composition of the extruded granules obtained after the extrusion step contains 1% w/w of water. The extruded granules are poured into the spray tank filled with water. The neutralization of glyphosate by sodium carbonate, then occurs and the effervescence due to the release of C0 2 in the solution makes the extruded granules dissolve in less than 1 minute with no external agitation. As a matter of comparison, similar granules with no effervescence do not really dissolve with no external mixing and under agitation take between 2 to 4 minutes to dissolve the actual time taken depending on the turbulence in the spray tank. An important advantage of these glyphosate WSP formulations is their ability to include solid additives. One of the most important solid additives is ammonium sulfate which can be included in the WSP at any desired level. Ammonium sulfate contributed increased biological activity as is shown in Examples 15 and 16. Ammonium sulfate is only compatible to a low degree in an aqueous glyphosate/surfactant formulation. Ammonium sulfate is also an effective solid additive in glyphosate WSP package mixes with co-herbicides which form water soluble salts as shown in Example 16. Particle size of the WSP or WSG products of this invention can be varied as long as the product is completely dissolved prior to application by spraying. The preferred mode of manufacture of the glyphosate WSPs involves grinding the individual ingredients using conventional equipment and blending using such equipment as a ribbon-or V-blender or grinding the blended ingredients. Since many of the surfactants and some of the acid acceptors are very hygroscopic, all operations are preferably carried out in closed equipment and moisture-proof packaging is required such as polyethylene or polyethylene laminated paper bags or the like. A particularly preferred type of packaging is a water soluble bag within an outer moisture proof container or bag. If desired, the powdered products of this invention may be compacted by various means as further exemplified in Example 17 and then ground and sieved to give a granular product. It may be desirable to incorporate a gas-forming ingredient to give more rapid disintegration and solution of the granular product. If desired, alternate carbonates may be employed such as potassium bicarbonate, sodium or potassium carbonate, mixtures thereof and the like or alkaline earth metal carbonates or bicarbonates, mixtures thereof and the like. If desired alternate sulfites may be employed such as potassium sulfite or an alkaline earth metal sulfite. Alternate lubricants may be employed including PEG's of varying molecular weight, methyl stearate or magnesium stearate, mixtures thereof and the like. Alternate defoamers may be employed such as AntiFoam® 30 IND. A binder can be employed, such as PVP, if desired although such use is optional. The use of a small percentage of a carbonate- based acid acceptor (a carbonate such as sodium bicarbonate/sodium carbonate, ammonium bicarbonate, mixtures thereof and the like) in the WSG formulation which in the presence of water will give off carbon dioxide which will increase the rate of solution by rupturing granules. The WSP or WSG compositions of this invention may vary widely with regard to the ratios of ingredients. If a surfactant is employed a glyphosate/surfactant ratio of about 4:1 to about 1:2 is a preferred range; however, other ratios, including a 1:0 may be used. The latter formulation may find utility where the presence of a surfactant is unnecessary or undesirable. The ratio of glyphosate to acid acceptor depends on the useable equivalent weight of the acceptor as shown in Table I. One useable equivalent of acid acceptor to one mole of glyphosate is required to provide for solution of the glyphosate. Usually, a 2-5% excess of acid acceptor is employed since acidic by-products in commercial glyphosate necessitate a slight excess. Depending on the use of the WSP or WSG, that is, the volume of water used in the spray, less than the theoretical quantity of useable equivalent of acid acceptor may be sufficient since glyphosate is soluble in water to the extent of about 1.0 wt. % at 25 β C. WSP and WSG formulations generally are not detrimentally affected by pressure and/or temperature variations. As mentioned previously, moisture is a major concern in processing and storage of dry glyphosate formulations because of the hygroscopic nature of some of the ingredients, especially the surfactant. In practicing the present method of-use of a dry glyphosate-containing formulation to kill or control weeds the best mode involves addition to water of a herbicidally effective amount of the composition of this invention followed by application via spraying or one of the many known wiping techniques to the locus of the plants to be killed or controlled. Addition of water may not be required (but is recommended) when application is made to plants having excessive dew. Application of a composition of this invention is made so that the plant is contacted with a herbicidally effective amount of N-phosphonomethylglycine. Many acid acceptors are operable in the present invention, however, sodium oxalate and sodium bicarbonate are preferred and sodium bicarbonate is most preferred. Many solid surfactants can be used in glyphosate WSPs or WSG's, however, sodium tetradecyl/hexadecyl alpha-olefin sulfonate (Witconate AOK) is preferred. In formulations with low surfactant content, say about 2-5%, a liquid ethoxylated tallow amine surfactant is preferred due to its high potentiating effect on glyphosate activity. With the propoxylated quaternary ammonium surfactants, one may use up to 15% by weight. In summary, the advantages of the dry glyphosate based formulations over the current aqueous formulations include higher active (glyphosate) content, compatibility with solid or water-insoluble liquid additives, compatibility with solid and liquid water insoluble co-herbicides as powders or water soluble granules, use of lower cost packaging and eliminating the necessity of manufacturing a glyphosate salt prior to formulation of the final commercial product. Although this invention has been described with respect to specific embodiments, the details hereof are not to be construed as limitations, for it will be apparent that various equivalents, changes and modifications may be resorted to without departing from the spirit and scope of this invention. It is understood that such equivalent embodiments are intended to be included within the scope of this invention.

Claims: WHAT IS CLAIMED IS: 1. A substantially dry, water soluble or dry, water dispersible agriculturally acceptable composition comprising a herbicidally effective amount of substantially non reacted N-phosphonomethylglycine, and an acid acceptor. 2. The composition of Claim 1, which further comprises a solid or liquid surfactant in an amount of about 0.2 to about 15.0% by weight. 3. The composition of Claim 2 wherein said dry composition is a water soluble or dispersible powder, a water soluble or dispersible granule, a water soluble or dispersible tablet or a water soluble or dispersible briquette. 4. The composition of Claim 1 wherein the amount of water in said dry composition is in the range from about 0.01 to about 10.0 percent by weight of the total composition. 5. The composition of Claim 4 wherein said amount of water in said dry composition is in the range from about 0.2 to about 2.0 percent by weight of the total composition and said composition is in a granular form. 6. The composition of Claim 1 wherein said acid acceptor is selected from the group consisting of ammonium and alkali metal carbonates, bicarbonates, acetates, eta borates, citrates, formates, oxalates, phosphates, propionates, pyrophosphates, metasilicates, orthosilicates, sulfites, thiosulfates, tetraborates, tripolyphosphates, metaphosphate, sodium hydroxide, potassium hydroxide, tetrasodium EDTA, and mixtures thereof. 7. The composition of Claim 1 which further comprises a co-herbicide. 8. The composition of Claim 1 or Claim 7 which further comprises a dispersing agent or a corrosion inhibitor. 9. The composition of Claim 1 or Claim 7 which further comprises a thickener. 10. The composition of Claim 1 or Claim 7 which further comprises a calcium sequestrant and/or a defoamer. 11. The composition of Claim 1 or Claim 7 which further comprises an agriculturally acceptable ammonium salt or other synergist. 12. The composition of Claim 1 or Claim 7 which further comprises a quick-burn additive. 13. The composition of Claim 1 or Claim 7 which further comprises a humectant. 14. The composition of Claim 1 or Claim 7 further comprises a dye or pigment. 15. The composition of Claim 6 or Claim 7 wherein said co-herbicide forms a water soluble salt. 16. The composition of Claim 7 wherein said co-herbicide is selected from the group consisting of 2, 4-D (2,4-dichlorophenoxy)acetic acid), dicamba, (3,6- dichloro-o-anisic acid), picloram (4-amino-3,5,6-tri- chloropyridine-2-carboxylic acid) , MCPA (4-chloro-g- tolyloxyacetic acid) , bialaphos (DL-homoalanin-4-yl- methylphosphinate) , imazaquin, (2-[4,5-dihydro-4-methyl- 4-(1-methylethyl)-5-oxo-lH-imidazol-2-yl]-3-quinoline- carboxylic acid), dalapon (2,2-dichloropropionic acid), dichlorprop 2-(2,4-dichlorophenoxy)propionic acid), MCPB (4-(4-chloro-o-tolyloxy)butyric acid, acifluorfen (5- (2-chloro-4-(trifluoromethyl)phenoxy-2-nitrobenzoate) , chloramben (3-amino-2,5-dichlorobenzoic acid), endothall (7-oxabicyclo(2.2.1)heptane-2,3-dicarboxylic acid), 2,4,5-T (2,4,5-trichloroacetic acid), 2,3,6-TBA (2,3,6- trichlorobenzoic acid) , glufosinate-ammonium (3-amino- 3-carboxypropyl)-methylphosphinate) , imazapyr (2-[4,5- dihydro-4-methyl-4-(1-methylethyl)-5- oxo-lH-imidazol- 2-yl]-3-pyridinecarboxylic acid) , and mixtures thereof. 17. The composition of Claim 7 wherein said co-herbicide is essentially water insoluble. 18. The composition of Claim 17 wherein said water insoluble co-herbicide is present in said water dispersible composition as a fine powder. 19. The composition of Claim 17 wherein said water insoluble co-herbicide is a liquid or a solid present in said composition as a water-dispersible granule and selected from alachlor (2-chloro-2' ,6'- diethyl-N-methoxymethylacetanilide) , atrazine (2- chloro-4-ethylamino)-6-(isopropyla ino)-s-triazine, simazine (6-chloro-N,N'di-ethyl-l,3,5-triazine-2,4- diamine, acetochlor (2-chloro-2'-ethyl-6 , -methyl-N- ethoxy-methylacetanilide) , metolachlor (2-chloro-6'- ethyl-N-( 2-methoxy-l-methylethyl)acet-o-toluidide) , fomesafen (5-[2-chloro-4-(trifluoromethyl)phenoxy]-N- (methylsulfonyl)-2-nitrobenzamide) , oxyfluorfen (2- chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoro¬ methyl)benzene) , fenoxaprop-ethylethyl 2, [4-(6-chloro- 2-benzoxazolyloxy)phenoxy]propanoate) , diuron (N'-(3,4- dichlorophenyl)-N,N-dimethylurea) , metsulfuron-methyl (methyl 2-[[[[ (4-methoxy-6-methyl-l,3,5-triazin-2- yl)amino]carbonyl]amino]sulfonyl]benzoate) , chlorimuron- ethyl ethyl 2-[ (4-chloro-6-methoxypyrimidin-2-yl)- amino]carbonyl]amino]sulfonyl]benzoate) , linuron 3- (3,4-dichlorophenyl)-l-methoxy-l-methylurea) , sulfometuron-methyl (2-[3-(4,6-dimethyl-pyrimidin-2- yl)ureidosulphonyl]benzoic acid), chlorsulfuron (l-(2- chlorophenylsulphonyl)-3-(4-methoxy-6-methyl-l,3,5- triazin-2-yl)urea) , and mixtures thereof. 20. The composition of Claim 7, wherein said co-herbicide as a water soluble salt is blended with said composition of Claim 1. 21. The composition of Claim 1 wherein said surfactant comprises a nonionic surfactant, an anionic surfactant, a cationic surfactant, an amphoteric surfactant, or mixtures thereof. 22. The composition of Claim 21 wherein said nonionic surfactant is a polyoxyethylene polyoxy- propylene block copolymer, an alkyl phenol polyoxy- ethylene ether, a polyoxyethylene oleylether, or mixtures thereof. 23. The composition of Claim 21 wherein said anionic surfactant is sodium laurylsulfate, a sodium alpha-olefin sulfonate, a potassium alpha-olefin sulfonate, a sodium alkane sulfonate, a potassium alkane sulfonate, an ammonium alkane sulfonate, an isopropylammonium alkane sulfonate, a sodium alkyl, or dialkyl naphthalene sulfonate or mixtures thereof. 24. The composition of Claim 21 wherein said cationic surfactant is an ethoxylated fatty amine, an a ine oxide, such as lauryl dimethylamine oxide, N,N- bishydroxyethylcocoa ine oxide, a propoxylated quaternary ammonium compound, or mixtures thereof. 25. The composition of Claim l wherein N- phosphonomethylglycine is in the form of a water soluble salt selected from the group consisting of the ammonium, isopropylamine, trimethylsulfonium, iminourea, potassium, sodium salts, or mixtures thereof. 26. A dry water soluble composition comprising said composition of Claim 25 and further comprising ammonium sulfate, potassium suifate, potassium chloride, sodium sulfate, urea, mixtures thereof and the like. 27. A process for preparing a dry, water soluble agriculturally acceptable composition which comprises admixing ingredients N-phosphonomethylglycine, an acid acceptor, optionally a solid or liquid surfactant, and thereafter blending said admixed ingredients to form said composition or compacting or tabletting said composition to form a granule. 28. A method of killing or controlling weeds using the composition of Claim 1 by applying a herbicidally effective amount of glyphosate to the locus of the plant or weed to be killed or controlled. 29. The process of Claim 28 wherein a co-herbicide is admixed with said N-phosphonomethyl¬ glycine, said acid acceptor, and optionally said solid or said liquid surfactant. 30. The method of killing or controlling weeds of Claim 29, which further comprises admixing said composition in the form of a tablet, briquette, powder or granule or mixture thereof with water and applying a herbicidally effective amount to the locus of the plant or weed to be killed or controlled. 31. A tablet, briquette, powder or granule having the composition of Claim 1. 32. A tablet of Claim 31, wherein said tablet is water soluble and is about 2 inches (5.08 centimeters) long by about 1/2 inch (1.27 centimeters) wide by about 1/2 inch (1.27 centimeters) thick.

Inventors: PRILL ERHARD JOHN, RICHARDSON RONALD OWEN, PRILL, ERHARD, JOHN, RICHARDSON, RONALD, OWEN
Applicants: MONSANTO CO, MONSANTO COMPANY
Application year: 1992
Main classification: A01N57
IPC codes: A01N57