AN EXHAUST GAS OXYGEN SENSOR

Abstract: An exhaust gas oxygen sensor comprising: (a) a solid electrolyte oxygen diffusion conductor (91) divided to form separate electrically insulated portions, one side of both portions being exposed to ambient air and the other side of both portions being exposed to exhaust gases; (b) first and second electrodes (94, 95) on different portions of said electrolyte and each directed to an exposure of ambient air; (c) a highly catalytic third electrode (93) on one electrolyte portion directed to an exposure of exhaust gas; and (d) a low-to-noncatalytic fourth electrode (92) on the other of said electrolyte portions directed also to an exposure of exhaust gas.

Description: AN EXHAUST GAS OXYGEN SENSOR This invention relates to the art of using exhaust gas oxygen (EGO) sensors for detecting catalyst failure, such catalysts being of the type that converts automotive engine emissions to non-noxious gases and water vapour. There is growing concern that to improve air quality in the United States, emission related components, such as a catalyst, must be monitored on board the vehicle to determine any malfunction. Catalyst monitoring has been and still is the least understood, both conceptually and practically, of the emission related components. EGO sensors have been used in the past, in pairs, to monitor catalysts, one sensor being placed upstream from a catalyst and the other placed downstream of the catalyst, and the signals from each of such sensors were evaluated to determine any difference that would indicate the catalyst was degraded. It is presumed by such prior art that a properly operating catalyst would be capable of dampening the periodic rich to lean excursions resulting from the limit cycle A/F feedback control or intentionally generated in the exhaust stream and that a substantial loss in catalyst performance through loss in actual conversion activity and/or oxygen storage activity would result in a decrease in this dampening ability of the catalyst. This generalised approach to catalyst monitoring compares complex signal features from both devices, each of which is disposed in a different environment and exposed to different exhaust gas locations, and furthermore presumes that there is a correlation between catalyst oxygen storage, sensed signal features, and catalyst performance. Often there is no such correlation. However, since each sensor uses a similar construction, including a catalytic coating that acts as a microcatalyst, failure based on the inability of the main catalyst to convert emissions may be hidden or masked by the sensor itself. Patented variations of the two sensor catalyst monitoring system have utilised or compared many sensor signal characteristics, including voltage amplitude, phase shift, and frequency ratioing. In some cases, an artificial change in the sensor signal is created by modulation of the engine A/F ratio which, it is hoped, will more clearly show the onset of catalyst degradation, unfortunately, all of such prior art approaches have at least the following characteristics in common: they expose the electrodes of the sensors to different emission gases, the sensors inherently have construction variations in tolerances and ageing, and a decision as to catalyst degradation cannot be made without comparison to an artificial reference. Such prior art sensor system approaches are inaccurate not only due to such sensor differences but also are not able to sense a difference in oxygen between equilibrated and nonequilibrated oxygen conversion or combustion. What is needed is a system that more reliably monitors catalyst degradation or inadequate engine combustion. The invention uniquely deploys an EGO sensor's rapid ability to detect a gas mixture's difference from chemical equilibrium and not mask such ability by presuming the oxygen storage capability of a main catalyst must first be detected. This is a significant inversion of logic used by the prior art. The invention herein uses an approach different than prior art to detect either catalyst malfunction or engine misfire. The invention recognises that an engine or catalyst each are gas mixture equilibrators. That is, a properly functioning catalyst or engine burns combustible intake gases or fluids to near chemical equilibrium. However, a standard EGO sensor also is an equilibrator because it uses catalytic electrodes and coatings to more fully combust or "equilibrate" either engine or catalyst exhaust gases to improve its εtoichiometric control point sensing accuracy. If the sensed gases are already at or near equilibrium, catalytic electrode or coatings activity would not be necessary and would perform no function; it would be superfluous. The logic of this invention is based on controlled single factor variation. It follows below. Build nearly identical EGO sensor pairs which differ within a pair in that one sensor ds fully catalytic while the other has reduced or no catalytic activity at its electrode or coating. Place such a nearly identical sensor pair in a common operating flow and gas environment downstream of either an engine or catalyst. If sensed gases are at or near equilibrium, there will not be a difference between the respective sensor outputs because a sensor's catalytic activity is not needed. If sensed gases are not at or near equilibrium (due to catalyst degradation or engine malfunction) , there will be a difference between the sensors' outputs, because one sensor's catalytic activity is needed and is missing. The difference will occur because within a pair, one sensor's missing catalytic activity will actually be needed to bring gases to equilibrium. Thus, the invention places differentially catalysed electrodes of oxygen sensors in either the exhaust gas exiting from the engine or in the exhaust gas exiting from the catalyst, and then compares signals generated by each of the electrodes and, if a predetermined difference is present, makes indication, respectively, of engine malfunction or catalyst degradation. Monitoring, while on board an automotive vehicle, can be carried out for one or more of catalyst performance, engine misfire, and combustion quality, the vehicle having an internal combustion engine equipped with a catalyst for converting noxious emissions of the engine. The catalyst may be a three-way catalyst or an oxidation catalyst. The sensors may be of the EGO, HEGO, or UEGO types. The sensors are used in pairs, a first pair being placed substantially immediately upstream of the catalyst and the second pair being placed substantially immediately downstream of the catalyst, the pairs of EGO sensors being incorporated into a closed-loop feedback control of the engine fuel control system. Both amplitude comparison, frequency change, or phase shift comparison may be used in detection of the difference in equilibrated and nonequilibrated gases passing by the sensors. » This invention can be used when operating the engine under closed-loop control, first with one sensor of a pair in the feedback control, and then the other during a short monitoring period, i.e., less than 20 seconds; a change in the feedback signal is observed to obtain a determination of catalyst degradation. The change from one sensor to the other may be cyclically controlled at a repeating frequency to enhance reliability of the system. A correlation is made between resulting changes in the signal with switching frequency. .Another aspect of this invention is the construction of a single sensor body having dual electrodes, one electrode being highly catalytic and the other being low-to-noncatalytic. The construction may have a common solid electrolyte zoned for two sensors by use of a barrier and two pairs of platinum electrodes, one of the pairs being exposed to an air reference cell and the other pair exposed to exhaust gases. One pair has the exhaust exposed electrode highly catalytic by use of a thin overcoating of porous platinum, and the other pair has the exhaust exposed electrode devoid of such coating or deactivated by lead or silver to produce a low-to- noncatalytic electrode. To simplify and make less expensive, the air reference may be eliminated from the construction and the differentially catalysed electrodes placed on opposite sides of a non-zoned electrolyte thereby immersing the entire device in the exhaust gas. The invention will now be described further, by way of example, with reference to the accompanying drawings, in which : Figure 1 is a block diagram of the essential steps of the method of this invention. Figure 2 is a schematic illustration of one usage of sensors of this invention with electrodes having significantly different catalytic activity, the usage here being for catalyst monitoring in a closed-loop feedback engine control having upstream and downstream control sensors (with respect to the catalyst) for feedback A/F control. Figure 3 is a schematic illustration of another usage of sensors with electrodes having differing catalytic activity but using only the downstream highly catalytic electrode sensor for feedback A/F control while the pair provides catalyst monitoring. Figure 4 is an alternative system like that in Figure 3, but using the downstream sensor pair in open loop while using an independent upstream sensor for feedback A/F control. Figure 5 is still another usage of sensors with electrodes having different catalytic activity but using the upstream highly catalysed electrode sensor for feedback A/F control while the pair provides engine misfire or slow or late burn detection. Figure 6 is a schematic illustration of yet still another usage of sensors with electrodes having differing catalytic activity, the usage here being for monitoring both engine misfire/combustion malfunction and catalyst degradation by the use of two pairs of sensors. Figure 7 is a composite of graphical illustrations of EGO signal voltage as a function of time, the first row of views respectively are for a highly catalytic electrode exposed to upstream exhaust gases, a highly catalytic sensor exposed to downstream exhaust gases, and a low-to-noncatalytic electrode exposed to downstream exhaust gases; the upper boxed group of signal views illustrating the effect of a good main catalyst and the lower boxed group of signal views illustrate the effect of a bad main catalyst. Figure 8 is a graphical illustration of oxygen sensor voltage plotted as a function of A/F signal. Figure 9 is a graphical illustration of main catalyst conversion efficiency plotted as a function of A/F signal. Figure 10 is a graphical illustration of pre- catalyst gas species content plotted as a function of A/F signal. Figure 11 is a plot of voltage signal taken prior to the P-I controller, such signal being plotted as a function of time for both a highly catalysed electrode and a low-to-noncatalyzed electrode exposed to both a good and bad catalyst. Figure 12 is a plot of A/F signal as a function of time for both a highly catalysed electrode and for a low-to-noncatalyzed electrode. Figures 13 and 14 are respectively plots of (LAMBSE) voltage signal as a function of time for a highly catalysed electrode and for a low-to-noncatalyzed electrode, the plots being marked to show when a misfire intentionally occurred. Figure 15 is a graphical illustration of A/F shift as a function of catalyst conversion efficiency, the difference in A/F signal between catalysed and noncatalyzed sensors placed downstream of three catalysts, of known but varied catalyst efficiency, was plotted. Figure 16 is a composite schematic view of two oxygen sensor constructions, one with a highly catalysed electrode exposed to exhaust gases, and the other a low- to-noncatalyzed electrode so exposed. Figure 17 is a schematic view of an integrated oxygen sensor construction that provides essentially two separate oxygen sensors in one device, one being highly catalytic and the other not. Figure 18 is an oxygen sensor with differentially catalytic electrodes but having no air reference, both electrodes being exposed to the exhaust gases. Figure 19 is a view similar to Figure 17, but showing still yet another sensor construction. It is conventional wisdom in the art that an oxygen sensor will be able to detect a change in oxygen storage capacity of a catalyst and thereby presumably detect catalyst efficiency. Attempts to implement this wisdom have used a conventional oxygen sensor placed downstream of the main catalyst, but it also functions as a catalyst, more accurately a microcatalyst, because its electrode, exposed to the exhaust gases, is highly catalytic in accordance with conventional construction. It is theorised that when the main catalyst degrades, it cannot cyclically store oxygen. Thus, the EGO sensor will provide a switching signal increased in frequency and/or increased in amplitude. However, the actual signal must be compared to a reference signal or library of reference signals to judge whether the main catalyst is degraded. Matching reference signals properly may lead to erroneous results because of the variable instantaneous conditions within the system. Amplitude changes are unreliable as an indicator of catalyst degradation because such changes are caused by changes in the oxygen storage of the catalyst, not necessarily by changes in its conversion efficiency. Also, some change in sensor output could be caused by changes in the response of the sensor itself. Frequency change may not be an indicator of a degraded catalyst for the same reasons given above. To avoid the need for reference signals, it has also been theorised that an artificial fuel pulse be used to exceed the storage capacity of the main catalyst; analysis of the sensed signal, before and after the pulse, tends to more clearly indicate a degraded catalyst without the need for reference signals. This approach may be difficult to implement because of the need to use the downstream sensor in a closed-loop engine control and maintain the exhaust gases within a desired window of air/fuel ratio optimum for main catalyst conversion efficiency. The invention herein avoids any reliance on a correlation between oxygen storage of the main catalyst and its efficiency. In the preferred embodiment, two differentially catalysed EGO sensor electrodes, whether integrated along one common electrolyte or used in separate electrolyte constructions, are substituted for the conventional EGO sensor downstream of the main catalyst; simultaneous and instantaneous comparison of the actual signals from each of such electrodes provides very reliable proof as to the efficiency of the main catalyst. Unreliable reference signals are avoided, the engine control system is not disrupted to accommodate catalyst monitoring, and false conclusions from reliance on the catalyst's ability to store oxygen is avoided. Essentially, the method of this invention comprises two main steps. The first step is to expose differentially catalysed electrodes of an oxygen sensing system to essentially the exhaust gases rom an engine (both being either upstream or downstream of the main catalyst, designed to convert all of such exhaust gases) . The second step compares the signal outputs from such electrodes for an indication of a specific malfunction with respect to engine misfire, combustion deficiency, or main catalyst degradation (see Figure 1) . System Usage A first aspect of this invention is concerned with how the differentially catalysed sensor electrodes, exposed to the exhaust gases, are used in a catalyst monitoring system. As shown in Figure 2, a closed-loop feedback control can be employed having a primary feedback loop 10(a) and an enhancement feedback loop 10(b) . In the primary feedback loop, a conventional EGO sensor 11 is disposed in the emission flow 12 from an engine 13 (upstream of the catalyst) , the signal from the EGO sensor 11 being connected to a feedback controller 14 which in turn supplies control information to an on-board computer or base fuel calculation means 16. Means 16 transmits a command signal to a fuel injector driver 17, the command signal controlling the pulse-width converter of the injector driver. There may be several injector drivers to accommodate each of the combustion cylinders of the engine, each of which must receive fuel pulses to carry out combustion therein within the engine in combination with inlet air 18 supplied to the engine. The signal from the first EGO sensor 11 may be modified by voltage follower (comparator) 15 which reshapes the signal from a sine-like wave to essentially a square wave thereby alleviating the very high impedance of the sensor output. To enhance the feedback control loop, it may further contain adaptive tables 20 to provide more precise calculation of A/F ratios during dynamic conditions where the feedback system cannot respond rapidly enough. The on-board computer or fuel calculation means 16 also receives information of mass airflow from a device 19. The controller 14 is preferably a proportional-integral type wherein the coefficients of proportional-integral terms of a control algorithm are adjusted to a different gain. Gain is the slope of the signal output to the signal input (essentially its strength) . The gain of the signal directly from the sensor is extremely high at the switch point and thus would lead to erratic adjustments if such signal was not modified with respect to its gain. To provide for enhanced feedback control and catalyst monitoring, the secondary control loop 10(b) deploys a second EGO sensor 30, having a highly catalytic electrode 30(a) exposed to the exhaust gases, and a third EGO sensor 31, having a low-to-noncatalytic electrode 31(a) exposed to the exhaust gases; sensors 30 and 31 are arranged for alternate connections to the feedback controller 14. The second and third EGO sensor electrodes that are exposed to the exhaust gases may be combined as a single split sensor construction placed after the catalyst to perform the monitoring. Such a split EGO sensor would actually be two EGO sensors in one; one of the EGO sensors would have a highly catalytic coating and the other would have no or little catalytic coating. Each signal from the second and third sensor electrodes 30(a) and 31(a) are respectively modified by a separate voltage follower or comparator 32, 33. The voltage follower is useful because the signal emanating from the sensor itself has very high impedance. The signal from the follower is then subjected to a low-gain modifier 34 or integrator. Thus, the signal is developed at an output that increases with time at a constant rate or that decreases at a constant rate to vary the pulse width of the air/fuel ratio controller in a closed-loop manner. The low-gain modifier switches from an increasing ramp to its decreasing ramp and back again in response to the output of the follower or comparator, which can be either one of two levels. The comparator changes or switches levels at a point where the waveform voltage of an oxygen sensor exceeds a reference voltage input to the comparator. The reference voltage input to the comparator is preferably known to be a voltage that will provide a uniform result even in conditions where the sensor waveform ages. The signal may further be modified by a bias adjust 35. The bias adjust is useful to compensate for dislocation of the air/fuel ratio signal to the lean side due to a slow change of partial pressure of oxygen, even when at the stoichiometric point of the sensor. This bias adjust moves the air/fuel ratio back to the proper window. The enhanced feedback system uses the highly catalytic electrode 30(a) (or second sensor) in normal mode to provide the enhanced feedback control. The low- to-noncatalytic electrode 31(a) (or third sensor) is alternately switched into the enhanced feedback system control and a comparison is made between the signals from such differentially catalysed electrode(s) (sensors). A switch 36 is interposed into the enhanced feedback loop preferably after the comparators 32, 33. Although the switch 36 may be disposed at other locations in the signal connection between the sensors and the controller, it is desirable at this location because it minimises the use of redundant components. Comparison may be carried out by use of a detector 38 connected to the signal output of the controller 14 (sensing the A/F signal-LAMBSE) which in turn is interpreted by an indicator block 39 to alert the driver to the desired malfunction of the catalyst. Comparison of the signal output from the controller is advantageous because it allows a more accurate determination of the degree of degradation of the catalyst as will be discussed later. Alternate usage schemes for the differentially catalysed electrodes of an oxygen sensor are shown in Figures 3-6. In Figure 3, the use of an upstream sensor to provide primary feedback control is eliminated (either during the detection test or during all engine operations) . The highly catalytic electrode 40 of the downstream split sensor (or pair of sensors) may be used as the normal mode for feedback A/F control and the low- to-noncatalytic electrode 41 is used only during catalyst interrogation. It may be desirable to cyclically switch back and forth between the highly catalysed and noncatalyzed sensor electrodes at some suitable frequency (rather than just switching once) ; the resulting changes in the feedback A/F signal are correlated with the switching signal frequency. This can be done by use of a repeater device 42 which promotes the cyclical switching. Such switching is done in order to obtain a catalyst monitoring signal that alternates between two values (during the catalyst testing interval) rather than a signal which just switches once. The potential advantage in doing this is that the procedure may provide more reliability in identifying marginally defective catalysts. The cyclical switching operation would only be performed during a designated catalyst monitoring interval such as for about 20 seconds. When the catalyst monitoring is not being performed, the highly catalysed electrode or sensor 40 (rather than the low-to-noncatalyzed electrode or sensor 41) would be used in the feedback A/F control or feedback trimming enhancement to provide the maximum air/fuel control accuracy. The other elements modifying the A/F control signal may be the same as in Figure 2 or simplified as shown in Figure 3. Detection of a signal difference is here made prior to the low gain adjust 34 and bias adjust 35. Detection is by way of block 44 (which simply compares the difference between output from sensors 40 and 41 and produces a malfunction indication signal to malfunction indicator 45 when the difference is greater than a preset value corresponding to a bad catalyst. Preset value could be a function of speed and torque. As shown in Figure 4, differentially catalysed electrodes (or sensors) 46 and 47 may be placed downstream of the catalyst in open loop, with upstream sensor 48 operating in closed loop to feed back oxygen sensing information for A/F control. A switching device 49 may be cyclically controlled by repeater as shown. Detection and indication of malfunction is made similar to Figure 3. The broad concept of this invention does not depend on which type of combusting device is upstream of the differentially catalysed electrodes (sensors) . The concept can be used to detect misfire and slow or late burn of each of the cylinders contributing to improper engine combustion, which improper combustion may damage the main catalytic converter. Two sensors or one split sensor device can be located upstream of the main catalyst converter 21 but downstream of the engine exhaust manifold of the engine 13. One EGO sensor (having only one type of catalysed electrode) , regardless of position in the exhaust stream, cannot readily detect improper combustion. But, differentially catalysed sensors (electrodes) of this invention can do so readily. It has been discovered that the low-to-noncatalyzed sensor (electrode) will exhibit a decided change in frequency when there is an ignition misfire (that is to say, the noncatalyzed sensor will product an output signal having high frequency components corresponding to the rate of the misfire) ; a low-to- noncatalyzed sensor (electrode) will also exhibit a change in amplitude when slow or late cylinder burn occurs. As shown in Figure 5, sensor 50, having a highly catalytic electrode, and sensor 51, having a low-to- noncatalytic electrode, are placed downstream of engine 13 but upstream of catalyst 21. The sensor 50 is normally connected in closed-loop feedback A/F control of the engine. The signal from each of the sensors is fed to a detection block 52 which is effective in determining when there is a sufficient difference in frequency or amplitude to alert a malfunction indicator 53 of misfire or slow or late burn. The use of differentially catalysed sensors (electrodes) may be used to detect both misfire and combustion malfunction as well as provide interrogation of the main catalyst for proper functioning (see Figure 6) . In this embodiment, the highly catalysed electrode (sensor) 55 acts to provide the normal oxygen sensing for closed-loop feedback A/F control. The low-to-noncatalyzed sensor (electrode) 56 is continuously compared by way of a detecting block 57 to trigger a malfunction indicator 58 if justified. The downstream differentially catalysed sensors (electrodes) 59 and 60 are used the same as in the embodiment of Figure 2 to periodically interrogate the main catalyst 21 as to its efficiency. A repeater device 61 may be utilised to switch between each of the sensors (electrodes) 59 and 60 to make the comparison. Detector 62 and malfunction indicator 63 receive and operate on the signal received upstream of low gain block 34 and bias adjust 35. Comparinσ Signals This invention uses differentially catalysed electrodes (sensors) that allow the monitoring system to be specific to combustion (whether performed by the engine or by the catalyst) while eliminating temperature and flow sensitivity and eliminating the distortion and interference inherent in absolute measurement from a single device. For catalytic monitoring, a standard oxygen sensor with a highly catalytic electrode exposed to the exhaust flow downstream of a main catalyst can exhibit a voltage signal that shows little change from the signal sensed by an upstream sensor with a highly catalytic electrode when the main catalyst is bad (see Figure 7) . Each sensor is seeing essentially the same type of unconverted exhaust gas and each sensor equilibrates such gas in essentially the same way. However, when the catalyst is good, there is a substantial difference in signal between the highly catalytic upstream and downstream sensors. This substantial change in signal may be attributed to the fact that a good main catalyst fully equilibrates the exhaust gases prior to the downstream sensor seeing such gases. However there is a decided change in signal in the downstream sensor, when highly catalytic, depending on whether the main catalyst is good or bad. Even more clear is the fact that a highly catalysed sensor (electrode) characteristic is shifted rich compared to the noncatalyzed sensor (electrode) (see Figure 9) . A rich shift herein means that the catalytic sensor will produce a certain mid-range output voltage at an A/F ratio which is richer than the A/F ratio required for the noncatalytic sensor to produce the same output voltage. The amount of A/F shift is dependent on the catalytic activity (i.e., on the conversion efficiency) of the main catalyst. A goal of this invention is to be able to operate the engine under closed-loop control with first one sensor in the feedback control and then the other in the feedback control and observe the change in the engine A/F feedback signal (LAMBSE) while doing so. Since the two sensors will produce the same output voltage at a different A/F value, there will be a difference in the A/F feedback signal of the engine depending on which sensor is in control (see Figure 9) . The reason there is a shift in the A/F, depending on whether the catalysed or low-to- noncatalyzed electrode is used, can best be understood by reference to Figure 10. But a low-to-noncatalystic sensor, placed downstream of the main catalyst, will exhibit little amplitude change in signal between a good and bad catalyst. The exhaust gases are passing through the main catalyst equilibrated in the case of a good catalyst but essentially unconverted in the case of a bad catalyst. But since the sensor cannot itself equilibrate the gases, there is a saturation of the sensor and the signal appears as a stretched form of the good catalyst signal, possibly at different levels due to a different mean A/F of the modulating A/F signal. Thus, when a sensor is capable of equilibrating itself, it will exhibit a greater signal amplitude and/or frequency. Therefore, since the difference between the two sensor characteristics is a function of the catalyst conversion efficiency, the magnitude of the change in the A/F feedback signal (LAMBSE) , which occurs when switching from one sensor to the other, can be used as an indicator of the catalyst condition. Although this invention comprehends detecting the signal of the differentially catalysed electrodes (sensors) anywhere along the closed-loop circuit, it is preferred to detect the A/F ratio feedback signal (LAMBSE) . This preference can be understood by reference to Figures 12 and 13. During use of the highly catalysed sensor (electrode), shown to the left of line 60 in Figure 11, the voltage signal is relatively steady at a predetermined plateau 61. When the low-to-noncatalyzed electrode (sensor) is made operative by switching, the voltage signal (to the right of line 60) will exhibit a difference if the main catalyst is bad. The voltage will abruptly rise to a new plateau 62 and gradually recede to its original plateau as the A/F controller readjusts the A/F ratio. To see a decided difference in signal, using the voltage data of Figure 11, the comparison must be made rather quickly at a moment when the voltage has made a sharp move, which leads to inaccuracy because of its rapid change. If the comparison is made too slowly, i.e., about 10-15 seconds, the voltage will have receded and little difference will remain. Furthermore, the plateau 62 will saturate at some limiting value for all catalysts having conversion efficiency below a certain value. In Figure 12, a preferred signal comparison is illustrated. The A/F feedback signal is sensed. This may be accomplished by taking the signal at a location 63 (A/F feedback signal), as shown in Figure 2, as opposed to taking the voltage signal at a location 64, as shown in Figure 3. As shown in Figure 12, the feedback signal, using a low-to-noncatalyzed electrode, will gradually rise to a new plateau 65 over a period of 5-10 seconds if the main catalyst is bad. In the case of a good catalyst, the A/F feedback signal will remain substantially at the original plateau 66, essentially the same as for the highly catalysed sensor (electrode) . This enables an interrogation scheme whereby after about 5-10 seconds, from the time the highly catalysed electrode is switched to the low-to-noncatalyzed electrode, a clear, definite signal comparison can be made, free from inaccuracies. An additional virtue of using the A/F feedback signal for detection (i.e., taken at 63) is that it permits determination of a degree of malfunction or efficiency. The amount of A/F shift (or A/F) is indicative of the degree of hydrocarbon conversion efficiency degradation of the main catalyst. Engine/dynamometer tests were performed using the system of Figure 2. Specifically, closed-loop A/F measurements were made with first the highly catalytic sensor and then the noncatalytic EGO sensor in control, and the differences between the closed-loop A/F for each situation was determined. The tests were repeated using three different catalysts and the results were plotted as a function of hydrocarbon conversion efficiency as shown in Figure 15. Examination of the results shown in Figure 15 verify that the invention concept works as anticipated for the catalysts examined. However, when using the voltage signal, such as taken at location 64, the amplitude or frequency gives no clue as to the degree of efficiency of the catalyst. The voltage signal obtained from the sensor when placed upstream and used to detect misfire of combustion malfunction, is illustrated in Figures 13 and 14. A highly catalysed electrode (sensor) , as shown in Figure 13, will exhibit a voltage variation that is roughly sinusoidal (for normal limit cycle operation) for both signals 67 and 68 during normal combustion and cylinder misfire conditions, respectively. However, when the low- to-noncatalyzed electrode (sensor) is activated, the voltage variation 70, 71 differs significantly from the normal combustion (to the left of line 69) and cylinder misfire (to the right of line 69) as shown in Figure 15. The frequency is highly increased when a misfire occurs. Slow or late burn (other combustion malfunctions) will give rise to an amplitude change in the voltage signal of the low-to-noncatalyzed sensor (electrode) . Sensor Construction Figure 16 shows a consolidated view of both a highly catalysed sensor construction on the left-hand side 16(a), and on the right-hand side 16(b),a sensor construction having a low-to-noncatalyzed electrode exposed to the exhaust gases. The construction of Figure 16(a) has a thimble-like structure positioned in the exhaust system of the engine. The exhaust gases 70 from the manifold, including unburned hydrocarbons, oxides of nitrogen, and carbon, along with 0 2 , are passed in proximity to the oxygen sensor. The oxygen sensor 79 has a reference port 71 located within an insulator base 72 that receives ambient atmospheric gases comprised essentially of 79% nitrogen and 21% oxygen in the form of 0 2 . The oxygen sensor 79 further comprises a solid electrolyte oxygen ion conductor 73 of Zr0 2 or the like which has an inner electrode 74 of some noble metal, preferably platinum. On the outer surface of the solid electrolyte 73 is a highly catalytic electrode 75 comprised preferably of a noble metal solid strip, such as platinum, with a painted dot of porous platinum 75(a). A protective oxide covering 76, in the preferred form of a porous coating of MgO.Al 2 0 3 spinel, overlays the entire outside active surface of the sensor 70. All the layers 73/74/75/76 are porous either to molecules or ions of oxygen; the two platinum conduction layers 74/75 and • terminals 77/78 are interconnected thereto for the collection of electron current respectively. Theoretically, the operation of such oxygen sensors occur by 0 2 molecules becoming oxygen ions with the addition of four electrons at the surface of electrode 74. The oxygen ions then diffuse into the solid electrolyte 73. Since the partial pressure of oxygen is higher on surface 74 than on surface 76, the net oxygen ions will move freely through the solid electrolyte to the outer catalytic electrode 75. At this point, the oxygen ions will give up electrons and combine to form 0 2 molecules once more. A net voltage will thus develop between electrode 74 and electrode 75 in response to the difference of partial pressure of 0 2 between the exhaust gas and the ambient atmosphere. Increasing the difference in partial pressures between the electrodes will, as a rule, increase the voltage created. Generally, a net partial pressure of 0 2 in the exhaust gas of about 10~ 22 atmospheres (corresponding to rich A/F mixtures) will cause the sensor to output a voltage in the order of 1.0 volts. When the net pressure of oxygen increases, the sensor output voltage decreases, becoming less than 0.1- 0.2 volts when the new partial pressure of 0 2 in the exhaust gas is 10 atmospheres or more (corresponding to lean A/F mixtures) . It has been discovered that a sensor without the thin platinum overlayer 75(a) , equivalent to the structure in Figure 16(b), cannot equilibrate the exhaust gas behind a bad three-way catalyst; the sensor is essentially a low- to-noncatalytic electrode sensor. Such construction merely has an outer platinum electrode 99 in the form of a long, thick platinum strip but absent a thin porous platinum overlayer. It is the platinum overlayer that promotes the high catalytic activity. An integrated closed-loop sensor construction is shown in Figure 17 as an improved and alternative embodiment. Using two separate EGO sensors to implement the method of this invention, differences might arise due to sensor location, local flow, different heater temperature, etc. These differences could be minimised by carefully engineering, but are largely eliminated by constructing the two sensors on a single substrate as shown in Figure 17. This will enhance the accuracy of the monitoring over that performed using two sensors. The proposed device of Figure 17 incorporates two oxygen sensors on a single oxygen conductive substrate 80. Both devices would then be subjected to nearly identical location, flow, temperature, and ageing conditions to lower output differences because of these interfering factors. The electrolyte is separated into two portions 80(a) and 80(b) by a material 84 to prevent cross-talk (0 2 transfer between two sensors) . Alumina (A1 2 0 3 ) may be used as such insulating material 87. The portion of the sensor which would carry out highly catalysed equilibration has an electrode 81 formed of a thin platinum strip accompanied by a highly catalytic overcoating of the electrolyte. To complete one part of the dual sensor, an electrode 83 is formed either of highly catalytic or noncatalytic material subjected to the air reference interior of the construction. On the other side of the construction is a low-to-noncatalyzed electrode 82 which is exposed to the exhaust gases and accompanied by its other electrode 84 subjected to the air reference side, which electrode may be either catalysed or noncatalyzed. To improve the accuracy of the device, a heating element 85 may be disposed to maintain the air reference temperature at an elevated level. Leads are connected to each of the electrodes as shown in Figure 18 and respectively are labelled Gl, VI, G2, and V2. Both air reference side electrodes could be of identical 5 material. Both devices would be mounted inside a housing containing a heater, although this might not be essential in the case of devices used for catalyst monitoring only. The insulating layer 87 (A1 2 0 3 ) can be eliminated if the alternative construction of Figure 19 is utilised. 10 Electrodes 83 and 84 (of Figure 17) are formed as a common inner electrode 88. The two differentially catalysed electrodes (81, 82 of Figure 17) are shifted laterally to become electrodes 86 89; cross-talk is minimised. This construction is desirable for mechanical reasons because 15 l 2 0 3 can have a different thermal expansion coefficient than Zr0 2 (which can result in cracking) . Still another alternative embodiment within the concept of this invention is a simplified open-loop type sensor 90 (as shown in Figure 18) that eliminates the air 20 reference and provides a differential measurement of the exhaust gas between a highly catalytic electrode 93 and a low-to-noncatalytic electrode 92. It consists of a single block or piece 91 of Zr0 2 electrolyte having one side 94 adapted to receive a highly catalysed electrode by 25 utilising the conventional platinum strip/platinum overlayer combination, the overlayer providing the porous film that is necessary to provide the high catalytic activity. The opposite side 95 contains only a narrow, solid strip of platinum which operates low-to- 30 noncatalytically. Alternatively, a thin silver layer may displace the solid platinum strip to operate as a noncatalytic electrode. The device is immersed completely in exhaust gases which makes the whole structure simpler and less expensive than a conventional EGO sensor. A 3.5 central bored hole 97 completes the ability to immerse the entire electrolyte in exhaust gas. ' . This type of sensor functions because the partial pressure between an equilibrated gas and a nonequilibrated gas promotes a difference in voltage. When the main catalyst is not functioning properly, this difference in voltage will be readily apparent. However, when the main catalyst is operating properly, the difference in voltage will be relatively minor. Since this type of sensor will not operate as a switch type about stoichiometry, it cannot be used in a closed-loop fuel control system in addition to acting as a catalyst monitor.

Claims: CLAIMS 1. An exhaust gas oxygen sensor comprising: (a) a solid electrolyte oxygen diffusion conductor (91) divided to form separate electrically insulated portions, one side of both portions being exposed to ambient air and the other side of both portions being exposed to exhaust gases; (b) first and second electrodes (94,95) on different portions of said electrolyte and each directed to an exposure of ambient air; (c) a highly catalytic third electrode (93) on one electrolyte portion directed to an exposure of exhaust gas; and (d) a low-to-noncatalytic fourth electrode (92) on the other of said electrolyte portions directed also to an exposure of exhaust gas. 2. A sensor as claimed in claim 1, in which said oxygen diffusion conductor is (i) hollow, (ii) closed to form an air reference cell, and (iii) divided by a plane of nonconductive material. 3. A sensor as claimed in claim 2, in which said one side is the interior directed to ambient air and the other side is the exterior directed to exhaust gases, the exterior being protected by a porous coating of MgO.Al 2 0 3 spinel. 4. A sensor as claimed in claim 1, in which the first, second, and fourth electrodes are each a solid strip of noble catalytic metal, and the third electrode is a porous coating of noble catalytic metal. 5. A sensor as claimed in claim 1, which further comprises means for heating the sensor. 6. An exhaust gas oxygen sensor comprising: (a) a solid electrolyte oxygen ion diffusion conductor divided to form separate electrically insulated portions, one side of both portions being exposed to ambient air, and the other side of both portions being exposed to exhaust combustion gases; (b) first and second electrodes on different divided portions of said electrolyte, both exposed to ambient air, and electrically connected to a source of electrons to promote iσnisation of oxygen through the electrolyte; (c) a highly catalytic third electrode on one of said electrolyte portions, exposed to exhaust gas, and electrically connected to ground to remove electrons from the oxygen ions; and (d) a low-to-noncatalytic fourth electrode on the other of said electrolyte portions, exposed to exhaust gases, and electrically connected to ground to remove electrons from conducted oxygen ions thereat also, the connection of said third and fourth electrodes functioning to complete a flow of electron current in response to a difference in partial pressure of 0 2 found in the exhaust combustion gases relative to the 0 2 partial pressure found in the ambient air. 7. An exhaust gas oxygen sensor for use in catalyst monitoring, comprising: (a) a solid, undivided oxygen ion conductor; (b) a highly catalytic electrode disposed on the outer surface of one side of said conductor; and (c) a low-to-noncatalytic electrode disposed on the outer surface at the other side of said conductor, both electrodes being immersed in exhaust combustion gases with said electrodes functioning to generate a voltage in response to a difference in partial pressure of 0 2 found at the noncatalytic electrode relative to the 0 2 partial pressure of the gases found at the low-to-noncatalytic electrode. 8. An exhaust gas oxygen sensor comprising: (a) means to sense combustibility of exhaust gases at, at least, two sensor stations, such means being immersed in the same exhaust gases having essentially the same combustion characteristic and such means having combustion augmentation at only one of said sensor stations; and (b) means to transduce such characteristic to provide at least two electrical signals specific to combustion and dependent on the augmentation difference between said sensor stations. 9. A sensor as claimed in claim 8, in which said means to transduce comprises a common electrolyte. 10. A sensor as claimed in claim 6, in which said diffusion conductor is undivided, formed as a hollow thimble, with said first and second electrolytes being in common on the interior thereof exposed to ambient air, said third and fourth electrodes being on the exterior thereof exposed to exhaust gases, said latter electrodes being uncovered without the superimposition of a spinel overlayer.

Inventors: HAMBURG DOUGLAS RAY, LOGOTHETIS ELEFTHERIOS MILTIAD, SOLTIS RICHARD EDWARD, VISSER JACOBUS HENDRIK, HAMBURG, DOUGLAS, RAY, LOGOTHETIS, ELEFTHERIOS, MILTIADIS, SOLTIS, RICHARD, EDWARD, VISSER, JACOBUS, HENDRIK
Applicants: FORD FRANCE, FORD MOTOR CANADA, FORD MOTOR CO, FORD WERKE AG, FORD FRANCE S.A., FORD MOTOR COMPANY, FORD MOTOR COMPANY LIMITED, FORD MOTOR COMPANY OF CANADA LTD., FORD WERKE A.G.
Application year: 1992
Main classification: G01N27
IPC codes: F01N11, G01N27