Exhaust apparatus for epitaxial growth system.

Abstract: An exhaust apparatus for an epitaxial growth system includes an exhaust pipe, a dust filter, and a liquid nitrogen trap. The exhaust pipe performs exhaustion of a reaction furnace in which a reaction gas is supplied to grow a thin film on a semiconductor wafer. The dust filter traps reaction products which have not been used for growing the thin film on the semiconductor wafer, and the dust filter is arranged in the exhaust pipe. The liquid nitrogen trap is arranged in the exhaust pipe in series with the dust filter.

Description: Background of the Invention The present invention relates to an extraction system for an epitaxial growth system used in manufacturing a semiconductor device. In a conventional epitaxial growth system, reaction gases such as AsH₃ (arsine), PH₃ (phosphine), SiH₄ (silane), and H₂ (hydrogen) are supplied to a reaction furnace, and a semiconductor wafer (to be referred to as a wafer hereinafter) is heated by induction heating or resistive heating to thermally decompose the supplied gases, thereby growing a thin film having a predetermined composition on the wafer. Products and non-reacted gases which are not used for growing the thin film on the wafer are exhausted from the reaction furnace through an exhaust pipe. In order to trap the products or the like in the exhaust pipe, the exhaust pipe has a dust filter consisting of a metal mesh, a Teflon filter, or the like. In the conventional exhaust apparatus of the epitaxial growth system, small reaction product particles and non-reacted gases are not sufficiently trapped. For this reason, these products pass through a rotary pump arranged near the distal end of the exhaust pipe to degrade exhausting ability. In addition, if arsenic or phosphorus reaches the rotary pump, problems in maintenance or safety are posed. For example, when phosphorus is mixed with oil of the rotary pump, the oil will burn when in contact with the air. Furthermore, when reaction products adhere to the inner portion of a pressure adjusting valve arranged near the distal end of the exhaust pipe, a degree of opening/closing the valve is changed during a pressure adjusting operation to degrade pressure control accuracy. When the size of the mesh in the dust filter is decreased (50 µm or less) to trap small reaction product particles, the exhausting ability is degraded. Solid State Technology Vol. 29, No. 9, Pp 143-149 discloses inter alia an epitaxial extraction system using a cold water trap upstream of a particulate filter. Patent Abstracts of Japan Vol. 9, No. 125 (C283) discloses an epitaxial extraction system using just a particulate filter. Summary of the Invention It is an object of the present invention to provide an exhaust apparatus for an epitaxial growth system capable of sufficiently trapping small reaction product particles and non-reacted gases. It is another object of the present invention to provide an exhaust apparatus for an epitaxial growth system designed to improve maintenance workability and safety. It is still another object of the present invention to provide an exhaust apparatus for an epitaxial growth system for preventing pressure control accuracy from degradation caused by allowing reaction products to adhere to a pressure adjusting valve. In order to achieve the above objects, according to one aspect of the present invention, there is provided a method of filtering reaction products or vapour phase reactants extracted from an epitaxial growth apparatus comprising extracting the gases by means of an exhaust pump, filtering out solid matter by means of a particulate filter upstream of the pump and characterised by passing the exhaust gases through a liquid gas trap between and in series with the particulate filter and the pump to condense and retain vapour phase reactants or reaction products in the gases. The invention also provides an exhaust system for epitaxial growth apparatus having a reaction chamber, the system comprising an exhaust duct leading to an exhaust pump for extracting vapour phase reactants and reaction products from the chamber, a particulate filter in the exhaust duct upstream of the pump and characterised by a liquid gas trap in the exhaust duct between and in series with the particulate filter and the pump. The preferred liquid gas is nitrogen but others, particularly those which do not react with the reactants or reaction products may be used, for example argon. Brief Description of the Drawings Fig. 1 is a view showing an arrangement of an exhaust apparatus for an epitaxial growth system according to the first embodiment of the present invention; and Fig. 2 is a view showing an arrangement of an exhaust apparatus for an epitaxial growth system according to the second embodiment of the present invention. Description of the Preferred Embodiments The present invention will be described below with reference to the accompanying drawings. Fig. 1 shows an arrangement of an exhaust apparatus for an epitaxial growth system according to the first embodiment of the present invention. An exhaust pipe 10 for exhausting reaction products or the like is connected to a reaction furnace 1 to which a reaction gas is supplied. A wafer 2 is loaded in the furnace 1. A control valve 8 for controlling exhaustion, a dust filter 3 for trapping reaction products, a liquid nitrogen trap 4, having an auxiliary tank 5, for trapping a non-reacted gas, a pressure adjusting valve 6 for adjusting a pressure of the reaction furnace 1, and a rotary pump 7 for performing exhaustion are sequentially arranged midway along the exhaust pipe 10 from the reaction furnace side. The reaction gas supplied to the reaction furnace 1 is thermally decomposed in the reaction furnace 1 to grow a thin film on the wafer 2. Reaction products which have not been used for growing the thin film on the wafer 2 flow in the exhaust pipe 10 except for reaction products adhering to the inner portion of the reaction furnace 1. Most of the reaction products flowing in the exhaust pipe 10 are trapped by the dust filter 3. However, reaction products having small particle sizes pass through a metal mesh (mesh: 50 to 100 µm) or the like in the dust filter 3. For this reason, the reaction products are adsorbed by a molecular sieve in the liquid nitrogen trap 4. The reaction gas which has not been reacted in the reaction furnace 1 directly flows into the exhaust pipe 10. This non-reacted gas is not trapped by the dust filter 3, but adsorbed by the liquid nitrogen trap 4 serving as a sorption pump. For this reason, the non-reacted gas does not flow into the pressure adjusting valve 6 and the rotary pump 7, and the reaction products do not adhere thereto, thereby obtaining a stable exhausting operation. At this time, the liquid nitrogen trap 4 has the auxiliary tank 5 so as to be always cooled, and liquid nitrogen is always supplied to the.auxiliary tank 5. That is, a molecular sieve is arranged inside the liquid nitrogen trap 4 to be cooled by liquid nitrogen (boiling point: -195.8°C), such that non-reacted PH₃ (boiling point: -87.7°C; melting point: -133°C) or AsH₃ (boiling point: -54.8°C; melting point: -113.5°C) can be trapped. After a thin film was actually grown by flowing AsH₃ or PH₃, the dust filter and the liquid nitrogen trap are observed for maintenance. At this time, powder-like black or brown dust particles are found in the dust filter 3, and the surface of the molecular sieve in the liquid nitrogen trap 4 is burnt with a flame in the air because a large amount of phosphorus is assumed to be trapped. In addition, when phosphorus and arsenic contained in oil in the rotary pump are analyzed, almost no phosphorus and arsenic are contained in the oil. Fig. 2 shows an arrangement of an exhaust apparatus for an epitaxial growth system according to the second embodiment of the present invention. In this arrangement, a high-pressure air line for switching exhausting systems is connected to a liquid nitrogen trap 40. The arrangements of Figs. 1 and 2 are different from each other in the following points. That is, in Fig. 2, a pair of stop valves 11a and 11b are arranged in an exhausting pipe 10 on the inlet and outlet sides of a liquid nitrogen trap 40. High-pressure air pipes 14a and 14b are connected to the exhaust pipe 10 on the inlet and outlet sides of the liquid nitrogen trap 40, and the high-pressure air pipes 14a and 14b have an air valve 12 and an exhaust valve 13, respectively. A high-pressure air line consists of the air valve 12, the high-pressure air pipe 14a, the liquid nitrogen trap 40, the high-pressure air pipe 14b, and the exhaust valve 13. Since the liquid nitrogen trap 40 has the high-pressure air line, non-reacted gases and small reaction product particles which are not decomposed in a reaction furnace 1 are trapped. Therefore, maintenance workability of the liquid nitrogen trap 40 can be improved. That is, according to the second embodiment, the products and non-reacted gases are concentratedly trapped by the liquid nitrogen trap 40. For this reason, an efficient and safe maintenance operation can be performed as follows. The gases and products trapped by the liquid nitrogen trap 40 are isolated from another system by closing the stop valves 11a and 11b, and the air valve and the exhaust valve 13 are opened to supply high-pressure air into the liquid nitrogen trap 40. In this manner, the gas and products are mixed and reacted with the air in the closed system. Especially, when phosphorus is trapped, the phosphorus is actively reacted with water or oxygen and burnt. Therefore, the present invention can be effectively applied. As described above, according to the present invention, since a dust filter and a liquid nitrogen trap are arranged in an exhaust pipe of an epitaxial growth system, reaction products and non-reacted gases can be effectively trapped, and the exhausting ability can be improved from several Torr to about 0.1 Torr. In addition, a growing pressure can be increased from ±667Pa to ±267Pa (±5 Torr to ±2 Torr). Although maintenance of a conventional exhaust system requires three or four days, maintenance of the exhausting apparatus according to the present invention requires only one or two days.

Claims: An exhaust system for epitaxial growth apparatus having a reaction chamber (1), the system comprising an exhaust duct (10) leading to an exhaust pump (7) for extracting vapour phase reactants and reaction products from the chamber, a particulate filter (3) in the exhaust duct upstream of the pump and characterised by a liquid gas trap (4) in the exhaust duct between and in series with the particulate filter and the pump. An exhaust system according to Claim 1, wherein the liquid gas trap contains liquid nitrogen. An exhaust system according to Claim 1 or Claim 2, wherein the liquid gas trap includes a molecular sieve. A system according to any preceding claim, further comprising a pair of stop valves (11a,11b) arranged in said exhaust duct on the inlet and outlet sides of said liquid gas trap, and a compressed air line for supplying compressed air to said liquid gas trap when the stop valves are closed. A system according to Claim 4, wherein said compressed air line comprises a pair of compressed air pipes (14a,14b) connected to the inlet and outlet sides of said liquid gas trap, an air valve (12) and an exhaust valve (13), respectively arranged in said compressed air pipes, for controlling circulation of compressed air in said liquid gas trap. A system according to any preceding claim, wherein said exhaust duct has a pressure adjusting valve (6) for adjusting the pressure in said reaction furnace. A method of filtering reaction products or vapour phase reactants extracted from an epitaxial growth apparatus comprising extracting the gases by means of an exhaust pump (7), filtering out solid matter by means of a particulate filter (3) upstream of the pump and characterised by passing the exhaust gases through a liquid gas trap (4) between and in series with the particulate filter and the pump to condense and retain vapour phase reactants or reaction products in the gases. A method according to Claim 7, comprising sealing the liquid gas trap to form a closed volume, and introducing compressed air into the trap to react with the reactants or products trapped therein.

Inventors: NAKANO TOMOIKU C O NEC CORPORA, NAKANO, TOMOIKU, C/O NEC CORPORATION
Applicants: NIPPON ELECTRIC CO, NEC CORPORATION
Application year: 1992
Main classification: C30B25
IPC codes: C30B25, C23C16, H01L21