Optical fiber and process of producing same

Abstract: In the optical fiber, the concentration of fluorine doped in the core portion (2) is made nonuniform in the radial direction to be greater at the center portion of the core portion (2) and less at the outer circumferential portion of the core portion (2). As a result, the distribution of the refractive index of the core portion (2) and the cladding portion (4) before the process of transparent glassification becomes a profile which is high at the outer circumferential portion of the core portion (2) and which is low at the center portion. The reduction of the refractive index at the outer circumferential portion of the core portion (2) due to the dispersion of the GeO₂ etc., the oxide included in the core portion (2), in the cladding portion (4) in the transparent glassification processed is and as a result, the profile of the refractive index of the core portion (2) becomes one which sticks out in a step form with respect to the cladding portion (4).

Description: TECHNICAL FIELD The present invention relates to an optical fiber used, for example, in a long distance optical transmission system, more particularly relates to an optical fiber preform and an optical fiber formed from the preform which improves the profile of the refractive index of the core portion to an ideal shape and to a process of producing the same. BACKGROUND ART For long distance optical transmission systems, single mode optical fibers with a core portion with an extremely reduced amount of doping of GeO₂ by which the Rayleigh scattering coefficient is reduced, has been used. Usually fluorine is doped into a cladding portion of the fiber for the purpose of increasing the difference in refractive index with the core portion. A fibre of this type in which fluorine is also doped into the core portion is described in EP-A-0 191 202. In such a single mode optical fiber, the profile of the refractive index of the core portion desirably should have a step-like profile compared with the cladding portion. This is in particular to prevent an increase in the optical transmission loss with respect to bending of the optical fiber. However, in the conventional optical fibers and processes of production thereof, it was not possible to make the profile of the refractive index of the core portion the ideal step shape. As shown in Fig. 1, a core portion 2 ended up with a profile of the refractive index which sticks up in a gentle mountain form compared with a cladding portion 4. Then, the optical fiber suffers from the problem that the effective refractive index of the core portion dropped and the optical transmission loss with respect to bending of the fiber increased. Note that the reason why the profile of the refractive index as shown in Fig. 1 is obtained is considered to be because the GeO₂ included in the core portion vaporizes from the surface of the soot during dehydration step and diffuses to the cladding portion at the interface of the core portion and cladding portion during the transparent glassification step in the process of production of the optical fiber. Therefore, it is extremely difficult to dope GeO₂ uniformly in the core portion and obtain a step-like refractive index profile. Note that the dotted line portion A in Fig. 1 is a straight line corresponding to the refractive index in the case of SiO₂ alone without any doping. DISCLOSURE OF THE INVENTION An object of the present invention is to provide an optical fiber preform and a process of producing the same which enables the profile of the refractive index between a core portion and a cladding portion to be made the ideal profile and in particular which enables the prevention of an increase in the optical transmission loss with respect to bending of an optical fiber. According to the present invention there is provided an optical fiber preform including a core portion and a cladding portion provided on the outside of the core portion and having a refractive index smaller than the refractive index of the core portion, wherein at least the core portion is doped with fluorine and an oxide, characterized in that the core portion is is more highly doped with fluorine towards its center in the radial direction than the outer circumferential portion. Preferably, the oxide is at least one of GeO₂ and P₂O₅. Also, preferably, the concentration of the GeO₂ or P₂O₅ is up to 1 mol%. Also, according to the present invention, there is provided a process of producing an optical fiber preform comprising the steps of forming a core portion doped with an oxide by deposition of soot and heat treating the core portion in a fluorine gas atmosphere, characterized in that a higher bulk density is formed at the outer circumferential portion of the core portion compared with the center portion whereby the doping of the fluorine in the core portion is such that the concentration of fluorine at the center portion of the core portion becomes relatively larger compared with the outer circumferential portion. Further, according to the present invention, there is provided an optical fiber formed from the above optical fiber preform. Also, according to the present invention, there is provided a process for producing an optical fiber by using the above process, and further including forming a cladding portion provided on the outer circumference of the core portion so as to produce a fiber material, and transparent- glassifying the fiber material and drawing it so as to produce an optical fiber. In the optical fiber of the present invention, the concentration of the fluorine doped in the core portion is made larger in the center portion of the core portion and made smaller in the outer circumferential portion of the core portion, so the profile of the refractive index of the core portion and the cladding portion before the step of transparent glassification becomes a profile which is high at the outer circumferential portion of the core portion and which is low at the center portion. Therefore, the reduction of the refractive index at the outer circumferential portion of the core portion due to the dispersion of the GeO₂ etc., the oxide included in the core portion, into the cladding portion in the transparent glassification step is corrected and as a result, the profile of the refractive index of the core portion becomes one which sticks out in a step form with respect to the cladding portion. BRIEF DESCRIPTION OF THE DRAWINGS The above and other objects and the above and other features of the present invention will be described in detail with reference to the accompanying drawings, in which; Figure 1 is a graph showing the profile of the refractive index of a conventional optical fiber preform, Figures 2a and 2b are graphs showing the profile of the refractive index in the process of production of an optical fiber preform in accordance with an embodiment of the present invention, Figure 3 is a schematic view showing the process of production of an optical fiber preform according to an embodiment of the present invention, and Figure 4 is a graph showing the distribution of the bulk density of the core portion. DESCRIPTION OF THE PREFERRED EMBODIMENTS The optical fiber preform according to the present invention has a core portion 2 comprised of silica based glass which is doped with an oxide and wherein the amount of the doping of fluorine is smaller at the outer circumferential portion compared with the center portion of the core portion. At the outer circumference of the core portion 2 a cladding portion 4 comprised of silica based glass with a lower refractive index compared with the core portion is provided. To lower the refractive index of the cladding portion 4, the cladding portion 4 is doped uniformly with fluorine etc., for example. The oxide to be doped in the core portion 2 is not particularly limited so long as it is an oxide where the refractive index of the core portion 2 is made higher compared with the cladding portion 4, but for example mention may be made of GeO₂, P₂O₅, etc. The amount of doping of these oxides is preferably not more than 1 mol% from the viewpoint of preventing optical loss due to Rayleigh scattering. By making the amount of doping of the fluorine in the core portion 2 nonuniform and by reducing the amount of doping of the fluorine in the outer circumferential portion of the core portion 2 compared with the center portion, as shown in Fig, 2a, the profile of the refractive index of the core portion 2 and the cladding portion 4 before the transparent glassification process comes to have a profile higher at the outer circumferential portion of the core portion 2 and lower at the center portion. By doping the fluorine, the refractive index at that portion falls in accordance with the amount of doping. Therefore, the reduction in the refractive index at the outer circumferential portion of the core portion 2 due to the dispersion of the GeO₂ etc., serving as the oxide included in the core portion 2, in the cladding portion 4 in the process of transparent glassification is corrected. As a result, as shown in Fig. 2b, the profile of the refractive index of the core portion 2 becomes a profile sticking out in a step form with respect to the cladding portion 4. The means for reducing the amount of fluorine doped at the outer circumferential portion compared with the center portion of the core portion 2 is not particularly limited, but the following method may be considered. When producing a core portion 2, the soot density is changed at the center portion and the outer circumferential portion of the core portion 2 so as to make the soot density higher at the outer circumferential portion of the core portion 2 compared with the center portion. After this, by the heat treatment under a fluorine gas atmosphere in the dehydration process or the transparent glassification process, fluorine is doped so as to make the concentration higher at the center portion of the core portion 2. As a result, the profile of the refractive index of the core portion 2 as shown in Fig. 2a is obtained. The following method may be illustrated as a means for causing a change in the soot density of the core portion 2. As shown in Fig. 3, when producing a silica based glass particulate soot (preform) 10 for forming the core portion 2 by the VAD method, two burners 6 and 8 are used. A first burner 6 is directed to the lower tip portion of the soot for forming the core portion, and, is supplied with silicon chloride (SiCl₄), germanium chloride (GeCl₄), hydrogen gas (H₂), oxygen gas (O₂) and argon gas (Ar) and emits a flame including glass particles. A second burner 8 is directed to the outer circumferential portion of the soot 10 for sintering use, and, is supplied with hydrogen gas (H₂) and oxygen gas (O₂) and emits a flame. By this VAD method, the density of the porous body comprising the soot 10 becomes larger the more to the circumferential portion of the core portion 2. Therefore, regarding the density of the soot forming the core portion 2, the density at the outer circumferential portion becomes larger than at the center portion. Due to the heat treatment, including fluorine gas (F), at the subsequent processes, a core portion 2 is formed where more fluorine (F) is doped the more to the center portion of the core portion 2. Below, the present invention will be explained with reference to a more specific example, but the present invention is not limited to this example. Example 1 By the method shown in Fig. 3, silica based glass particulate soot 10 for forming the core portion 2 is prepared Material gas such as shown in Table 1 is passed to silica based glass four-layer-tube burners 6 and 8. Note that in Table 1, the center tube of the four-layer-tube burner is made the first layer and the surrounding tubes are successively made the second, third, and fourth layers. First burner 6 Second burner 8 1st layer SiCl₄ (43° C) 115 [cc/min] GeCl₄ (-3° C) 120 [cc/min] 2nd layer H₂ 5.9 [ℓ/min] H₂ 5.9 [ℓ/min] 3rd layer Ar 1.7 [ℓ/min] Ar 1.7 [ℓ/min] 4th layer O₂ 6.4 [ℓ/min] O₂ 6.4 [ℓ/min] Investigating the density of the obtained soot 10 in the radial direction, as shown in Fig. 4, it was confirmed that the soot density of the porous body was larger the more to the outer circumferential portion of the core portion 2. Therefore, when doping fluorine under the conditions of Table 2, it is recognized that the fluorine is easier to dope the more to the center portion. The soot 10 was subjected to transparent glassification process under the conditions of Table 2 in a heating furnace (or electric furnace) for dehydration and transparent glassification. 1st step 2nd step 3rd step Temperature (° C) 1100 900 1430 He flow rate (ℓ/min) 30 30 30 Cl₂ flow rate (ℓ/min) 0.3 0.3 0.3 SiF₄ flow rate (ℓ/min) 0 0.03 0 Falling rate (mm/hr) 150 450 150 This glass rod was drawn to a diameter of 10 mm, then silica based glass particulate was deposited on the outside of the silica based glass rod by the external deposition method (OVD method) and thereafter the process of transparent glassification under conditions of Table 3 in an electric furnace was repeated. The deposition of silica based glass particulates and the transparent glassification were performed until the cladding ratio of the core portion became 12.5. The resultant material was drawn at a rate of 180 m/min by a drawing furnace. An ultraviolet ray curing resin was immediately coated on it to give a single mode optical fiber including a core having a diameter of 10 µm and a cladding having a 125 µm, and a covering outer diameter of 250 µm. 1st step 2nd step Temperature (° C) 1000 1350 He flow rate (ℓ/min) 30 15 Cl₂ flow rate (ℓ/min) 0.3 0.15 SiF₄ flow rate (ℓ/min) 0 2.0 Falling rate (mm/hr) 450 150 Comparative Example 1 On the other hand, the same process as in Example 1 was used to prepare a single mode optical fiber except that the core soot was prepared without using the four-layer-tube burner 2 in Fig. 3. The two single mode fibers were wound on a 15 mm⊘ and 20 mm⊘ mandrel and compared as to the increase in loss due to bending. The results are shown in Table 4. Single mode optical fiber Increase in loss (dB/km) λ c (µm) Δ⁻ (%) 15 mm⊘ 20 mm⊘ Example 1 Profile of refractive index shown in Fig. 1(B) 1.1 0.1 1.47 0.36 Comp. Ex. 1 Profile of refractive index shown in Fig. 1 4.0 0.4 1.47 0.35 As shown in Table 4, Example 1 was confirmed to have a smaller increase in loss with respect to bending compared with the conventional optical fiber shown in Comparative Example 1. Note that in the above-mentioned embodiment, an example of a single-mode optical fiber was shown, but the present invention may be applied to a multiple-mode optical fiber and a constant polarized light optical fiber as well. Further, the core may be doped with P₂O₅ instead of GeO₂. However, if too much is doped, the optical loss due to Rayleigh scattering becomes significant. Therefore, it is preferable that the concentration of the GeO₂ or the P₂O₅ be made not more than 1 mol%. As explained above, according to the present invention, there is provided an optical fiber doped with a small amount of an oxide at the core which has the superior effects of enabling the distribution of the refractive index of the core portion and the cladding portion to be made the ideal profile and enabling a reduction of the optical transmission loss with respect to bending of the optical fiber. Many widely different embodiments of the present invention may be constructed without departing from the scope of the present invention, and it should be understood that the present invention is not restricted to the specific embodiments described above.

Claims: An optical fiber preform including a core portion (2) and a cladding portion (4) provided on the outside of the core portion (2) and having a refractive index smaller than the refractive index of the core portion (2), wherein at least the core portion (2) is doped with fluorine and an oxide, said optical fiber preform being characterized in that the core portion (2) is is more highly doped with fluorine towards its center in the radial direction than its outer circumferential portion. An optical fiber preform as set forth in claim 1, wherein the oxide is at least one of GeO₂ and P₂O₅. An optical fiber preform as set forth in claim 2, wherein characterized in that the concentration of the GeO₂ or P₂O₅ is up to 1 mol%. A process of producing an optical fiber preform comprising the steps of forming a core portion (2) doped with an oxide by deposition of soot and heat treating the core portion (2) in a fluorine gas atmosphere, characterized in that a higher soot density is formed at the outer circumferential portion of the core portion (2) compared with the center portion whereby the doping of the fluorine in the core portion (2) is such that the concentration of fluorine at the center portion of the core portion (2) becomes relatively larger compared with the outer circumferential portion. An optical fiber including a core and a cladding provided on the outside of the core and having a refractive index smaller than the refractive index of the core, wherein at least the core portion (2) is doped with fluorine and an oxide, said optical fiber being characterized in that the core is is more highly doped with fluorine towards its center in the radial direction than its outer circumferential portion. An optical fiber as set forth in claim 5, wherein the oxide is at least one of GeO₂ and P₂O₅. An optical fiber as set forth in claim 6, wherein characterized in that the concentration of the GeO₂ or P₂O₅ is up to 1 mol%. A process of producing an optical fiber characterized by forming a preform according to the process of claim 4, forming a cladding portion (4) provided on the outer circumference of the core portion (2) so as to produce a fiber material, and transparent- glassifying the fiber material and drawing it so as to produce an optical fiber including a core formed by said core portion (2) and a cladding formed by said cladding portion (4).

Inventors: IINO AKIRA, KUWABARA MASAHIDE, IINO, AKIRA, KUWABARA, MASAHIDE
Applicants: FURUKAWA ELECTRIC CO LTD, THE FURUKAWA ELECTRIC CO., LTD.
Application year: 1992
Main classification: G02B6
IPC codes: G02B6, C03C13, C03B37, C03C25, C03B8, C03B20