Process for the preparation of epsilon-caprolactam by Deckamnn-rearrangement in the phase in the presence of a zeolite catalyst and nitrogen-containing compounds

Abstract: ε -Caprolactam is prepared by bringing cyclohexanone oxime into contact in gas phase with solid catalysts such as a zeolite catalyst in the presence of at least one nitrogen-containing compound selected from the group consisting of ammonia, methylamines and ε -caprolactam.

Description: The present invention relates to a process for producing ε-caprolactam from cyclohexanone oxime using pentasil zeolite solid catalysts under gas phase reaction conditions. ε-Caprolactam is an important raw material for nylon. The inventors have proposed processes for producing ε-caprolactam by rearrangement of cyclohexanone oxime (Beckmann rearrangement) using solid catalysts under gas phase reaction conditions in the presence of lower alcohols and/or ether compounds (Japanese Patent Kokai Nos. Hei 2-275850 and 2-250866). EP-A-0494535 discloses a process for converting cyclohexanone oxime to ε-caprolactam by gas phase reaction over a pretreated zeolite catalyst. The catalyst is pretreated with either a mixture of an aqueous solution of ammonium salts and a lower alkylamine or it is pretreated with ammonia water. The gas phase reaction mixture does not contain ammonia or methylamines. EP-A-0380364 discloses a process for converting cyclohexanone oxime to ε-caprolactam by gas phase reaction over a zeolite catalyst. The gas phase reaction mixture contains lower alcohols or ethers but does not contain ammonia or methylamines. The inventors have further conducted intensive research on a rearrangement reaction of cyclohexanone oxime and have found that when the rearrangement reaction is carried out in the presence of specific nitrogen-containing compounds in the gas phase reaction system, ε-caprolactam is obtained with a high selectivity and life of the catalysts are greatly prolonged even under such conditions that cyclohexanone oxime reacts with high conversion. As a result, the present invention has been accomplished. That is, the present invention provides an industrially superior process for producing ε-caprolactam which comprises bringing cyclohexanone oxime into contact in a gas phase with solid catalysts in the presence of at least one nitrogen-containing compound selected from ammonia and a methylamine. According to the present invention a process for producing ε-caprolactam comprises bringing cyclohexanone oxime together with a C 1 -C 6 alcohol into contact in the gas phase with solid catalysts at a reaction temperature of 250-500°C, and at a reaction pressure of 0.05-10 kg.cm 2 , characterised in that the solid catalyst is a zeolite of pentasil type structure and in that the reaction is carried out in the gas phase in the presence of at least one nitrogen-containing compound selected from the group consisting of ammonia, methylamine, dimethylamine and trimethylamine. The solid catalysts used in the present invention are preferably crystalline metallosilicates. The crystalline metallosilicates contain metals in addition to silicon and oxygen, such as those which have a ratio of the number of silicon atoms to that of metal atoms (Si/metal atomic ratio) of 5 or higher, preferably at least 500. As examples of the metals, mention may be made of at least one metal selected from Al, Ga, Fe, B, Zn, Cr, Be, Co, La, Ge, Ti, Zr, Hf, V, Ni, Sb, Bi, Cu and Nb. The Si/metal atomic ratio is obtained by usual analytical methods such as atomic absorption spectrometry and X-ray fluorescence analysis. The process of the present invention is characterized in that a specific nitrogen-containing compound is allowed to exist in the reaction system. The nitrogen-containing compounds include at least one compound selected from ammonia, monomethylamine, dimethylamine and trimethylamine. The amount of the nitrogen-containing compounds is usually 10 moles or less, preferably 1 mole or less, more preferably 0.001-0.8 mole per mol of cyclohexanone oxime is used. Examples of the C 1 -C 6 alcohols are methanol, ethanol, n-propanol, isopropanol, n-butanol, sec-butanol, isobutanol, n-amyl alcohol and n-hexanol. Methanol and ethanol are preferred. In the reaction system, vapors of compounds inert to the reaction, such as benzene, cyclohexane and toluene or inert gases such as nitrogen and carbon dioxide may also be allowed to coexist as a diluent gas. The reaction in carrying out the present invention will be explained. The starting material cyclohexanone oxime is subjected to the catalytic reaction in the gas form. The reaction is carried out in either a fixed-bed or fluidized bed. The nitrogen-containing compounds may be mixed or not with cyclohexanone oxime before they are fed to a reactor. When the nitrogen-containing compounds are not mixed with cyclohexanone oxime before feeding, the nitrogen-containing compounds may be fed in portions. In the case of the fixed-bed reaction, it is preferred to pass a thorough mixture of the cyclohexanone oxime and the nitrogen-containing compounds through the catalyst bed. Space velocity of the starting material cyclohexanone oxime is usually WHSV=0.1-40 hr -1 (namely, feeding rate of cyclohexanone oxime per kg of the catalyst is 0.1-40 kg/hr), preferably 0.2-20 hr -1 , more preferably 0.5-10 hr -1 . The reaction temperature is 250-500°C, preferably 300-450°C, more preferably 300-400°C. When the temperature is lower than 250°C, reaction rate is not sufficient and selectivity of ε-caprolactam tends to decrease and when it is higher than 500°C, selectivity of ε-caprolactam tends to decrease. The present process is carried out under a pressure of 0.05-10 kg/cm 2 . The isolation of ε-caprolactam from the reaction mixture and purification thereof are carried out, for example, by cooling and condensing the reaction product gas, followed by extraction, distillation or crystallization. Ammonia and methylamines added to the reaction system are separated and recovered from the reaction product and reused. For example, ammonia and methylamines are recovered in a gaseous state in cooling and condensing the reaction product gas. The catalyst having small activity which is caused by use for long time is easily reactivated to the initial capacity by being calcined in molecular oxygen-containing gas, for example, air stream or a molecular oxygen-containing gas to which alcohols such as methanol are added. The reactivated catalyst is repeatedly used. According to the present invention, ε-caprolactam is obtained with high selectivity and life of the catalysts is greatly prolonged even under such conditions that cyclohexanon oxime reacts with high conversion. The following examples will illustrate the present invention. Reference Example 1 (Preparation of catalyst) In a stainless steel autoclave (1.5 ℓ) were charged tetraethylorthosilicate (Si(OC 2 H 5 ) 4 , 100 g, Al content: less than 10 ppm), 10% aqueous tetra-n-propyl-ammonium hydroxide solution (224.0 g) and ethanol (214 g) and were vigorously stirred for 30 minutes. The mixed solution had a pH of 13. The autoclave was sealed and then was dipped in an oil bath to keep the internal temperature at 105°C. Hydrothermal synthesis was effected for 120 hours with stirring at a revolution rate at least 400 rpm. Pressure in the autoclave reached 2-3 kg/cm 2 . The pH at the completion of the hydrothermal synthesis was 11.8. A white solid product was filtered off and washed continuously with distilled water until pH of filtrate reached about 7. The white solid was dried and calcined in an air stream at 500-530°C for 4 hours to obtain powdery white crystals (27 g) which were identified to be pentasil type zeolite by powder X-ray diffraction. Al content was 3 ppm according to atomic absorption spectroscopy assay. To this crystals (10 g) was added 5% aqueous ammonium chloride solution (100 g) to carry out an ion exchange treatment at 50-60°C for 1 hour. The crystals were filtered off. The ion exchange treatment was carried out four times and then the crystals were washed with distilled water until no Cl - ion was detected in the filtrate. Subsequently, the crystals were dried at 120°C for 16 hours. The resulting crystals of ammonium salt form were shaped under pressure and sifted to obtain particles of 24-48 meshes (US Sieve Series which have openings 710 micrometres to 297 micrometres across), which were calcined at 500°C for 1 hour in a nitrogen gas stream to obtain a catalyst. Example 1 In a quartz glass reaction tube (1 cm inner diameter) was packed the catalyst (0.375 g, 0.6 ml) prepared in Reference Example 1 and was preheated in a nitrogen gas stream (4.2 l/hr) at 350°C for 1 hour. Then, the nitrogen gas was replaced with a mixed gas (4.2 l/hr) of nitrogen (95 vol%)-ammonia (5 vol%). Then, to the reaction tube was fed a mixed solution of cyclohexanone oxime/methanol (1/1.8 in weight ratio) at a rate of 8.4 g/hr under feeding the above mixed gas to carry out a reaction. At this time, the space velocity WHSV of cyclohexanone oxime was 8 hr -1 and temperature of the catalyst bed (reaction temperature) was 350°C. After the reaction was allowed to proceed for 6.25 hours, feeding of all materials was stopped to terminate the reaction. The reaction product was trapped and collected under water cooling and was analyzed by gas chromatography. The space velocity WHSV of cyclohexanone oxime, the conversion of cyclohexanone oxime and the selectivity of ε-caprolactam were calculated by the following formulas. WHSV (hr -1 )=O/C Conversion of cyclohexanone oxime (%)=[(X-Y)/X] × 100 Selectivity of ε-caprolactam (%)=[Z/(X-Y)] × 100 wherein O=Feeding rate (kg/hr) of cyclohexanone oxime, C=Weight of catalyst (kg), X=Mole number of the fed cyclohexanone oxime, Y=Mole number of unaltered cyclohexanone oxime and Z =Mole number of ε-caprolactam in the product. After the reaction was over, the catalyst bed was heated to 430°C under feeding to the reaction tube a mixed gas of nitrogen, air and methanol (methanol concentration 3.8 vol%: saturated concentration at 0°C) obtained by bubbling a mixed gas of nitrogen gas (2.5 l/hr) and air (2.5 l/hr) in methanol kept at 0°C. The catalyst bed was treated at that temperature for 23 hours, thereby to remove carbonaceous materials formed on the catalyst. Then, the temperature was lowered to 350°C under feeding nitrogen gas (4.2 l/hr). Successively, the reaction and the removal of carbonaceous materials were repeated totally 30 times under the same conditions as above. The results at each time are shown in Table 1. Number of repetition Elapsed time of reaction (hr) 1.25 3.25 6.25 1st time Conversion (%) 97.7 96.6 95.5 Selectivity (%) 95.7 96.3 95.7 2nd time Conversion (%) 97.0 95.1 93.8 Selectivity (%) 95.9 96.2 96.2 10th time Conversion (%) 89.9 85.7 82.9 Selectivity (%) 95.4 95.5 95.2 20th time Conversion (%) 87.0 81.9 77.9 Selectivity (%) 94.0 94.0 94.3 30th time Conversion (%) 84.0 78.4 74.9 Selectivity (%) 94.7 94.9 94.9 Comparative Example 1 Reaction and removal of carbonaceous materials were carried out totally 30 times under the same conditions as in Example 1 except that the replacement of nitrogen with the mixed gas of nitrogen-ammonia was not effected. Results of reaction at each time are shown in Table 2. Number of repetition Elapsed time of reaction (hr) 1.25 3.25 6.25 1st time Conversion (%) 98.0 98.6 97.6 Selectivity (%) 96.1 96.2 96.7 2nd time Conversion (%) 99.3 97.9 97.1 Selectivity (%) 95.2 95.4 95.2 10th time Conversion (%) 95.7 91.5 89.1 Selectivity (%) 93.3 93.4 92.8 20th time Conversion (%) 88.9 81.5 77.3 Selectivity (%) 91.3 91.7 91.6 30th time Conversion (%) 83.6 74.5 68.6 Selectivity (%) 90.8 90.9 90.8 Example 2 In a quartz glass reaction tube (1 cm inner diameter) was packed the catalyst (0.375 g, 0.6 ml) prepared in Reference Example 1 and was preheated in a nitrogen gas stream (4.2 l/hr) at 350°C for 1 hour. Then, the nitrogen gas was replaced with a mixed gas (4.2 l/hr) of nitrogen (95 vol%)-trimethylamine (5 vol%). Then, to the reaction tube were separately but simultaneously fed a mixed solution of cyclohexanone oxime/methanol (1/1.2 in weight ratio) at a rate of 6.6 g/hr and methanol at a rate of 1.8 g/hr under feeding the above mixed gas to carry out a reaction. At this time, the space velocity WHSV of cyclohexanone oxime was 8 hr -1 and temperature of the catalyst bed ( reaction temperature) was 350°C. After the reaction was allowed to proceed for 45. 25 hours, feeding of all materials was stopped to terminate the reaction. The reaction product was trapped and collected using water cooling and was analyzed by gas chromatography. Carbonaceous materials formed on the catalyst were removed in the same manner as in Example 1 except that the treating time was 96 hours in place of 23 hours. Then, the temperature was lowered to 350°C under feeding nitrogen gas (4.2 l/hr). Successively, the reaction and the removal of carbonaceous materials were repeated totally three times under the same conditions as above. The results at each time are shown in Table 3. Number of repetition Elapsed time of reaction (hr) 1.25 13.25 25.25 37.25 45.25 1st time Conversion (%) 99.3 97.6 96.3 95.4 94.5 Selectivity(%) 95.5 95.6 96.1 96.1 96.2 2nd time Conversion (%) 98.9 97.3 96.2 95.0 94.3 Selectivity(%) 95.8 96.2 96.1 96.1 96.1 3rd time Conversion (%) 99.5 98.7 97.7 97.0 96.2 Selectivity(%) 95.8 96.2 96.3 96.3 96.1

Claims: A process for producing ε-caprolactam which comprises bringing cyclohexanone oxime together with a C 1 -C 6 alcohol into contact in the gas phase with solid catalysts at a reaction temperature of 250-500°C, and at a reaction pressure of 0.05-10 kg/cm 2 , characterised in that the solid catalyst is a zeolite which has a pentasil type structure, and in that the reaction is carried out in the gas phase in the presence of at least one nitrogen-containing compound selected from the group consisting of ammonia, methylamine, dimethylamine and trimethylamine. A process as claimed in claim 1, characterised in that the zeolite is a crystalline metallosilicate. A process as claimed in claim 2, characterised in that the crystalline metallosilicate has a Si/metal atomic ratio of 5 or more. A process as claimed in claim 3, characterised in that the metal is at least one element selected from Al, Ga, Fe, B, Zn, Cr, Be, Co, La, Ge, Ti, Zr, Hf, V, Ni, Sb, Bi, Cu and Nb. A process as claimed in claim 2, characterised in that the zeolite is a crystalline silica. A process as claimed in any one of claims 1 to 5, characterised in that the amount of the nitrogen containing compounds is 10 moles or less per mole of the cyclohexanone oxime. A process as claimed in any one of claims 1 to 6, characterised in that the alcohol is selected from methanol, ethanol, n-propanol, isopropanol, n-butanol, sec-butanol, isobutanol, n-amyl alcohol, and n-hexanol. A process as claimed in any one of claims 1 to 7 characterised in that the alcohol is methanol or ethanol. A process as claimed in any one of claims 1 to 8, characterised in that the space velocity of cyclohexanone oxime is 0.1-40 hr -1 . A process as claimed in any one of claims 1 to 9, characterised in that the zeolite catalyst having a low activity which is caused by use for a long time is activated by being calcined in a molecular oxygen-containing gas. A process as claimed in claim 10, characterised in that the molecular oxygen-containing gas is air. A process as claimed in claim 10 or claim 11, characterised in that the molecular oxygen-containing gas contains alcohols. A process as claimed in claim 12, characterised in that the alcohol is methanol.

Inventors: ICHIHASHI HIROSHI, KAJIKURI HIROSHI, KITAMURA MASARU, TASAKA EIJI, ICHIHASHI, HIROSHI, KAJIKURI, HIROSHI, KITAMURA, MASARU, TASAKA, EIJI
Applicants: SUMITOMO CHEMICAL CO, SUMITOMO CHEMICAL COMPANY LIMITED
Application year: 1992
Main classification: C07D201
IPC codes: B01J29, C07D201