Method of producing isoplanar isolated active regions

Abstract: A method is provided for forming isoplanar isolated regions in an integrated circuit, and an integrated circuit formed according to the same. According to a first disclosed embodiment, a first epitaxial layer is formed over a substrate, the substrate having a (100) crystal orientation. A first masking layer is formed over the first epitaxial layer. The first masking layer is patterned and the first epitaxial layer is etched to form openings. The sidewalls of these openings have a (111) crystal orientation. The first masking layer is then removed and a second masking layer is formed in the openings. The first epitaxial layer is anodized and oxidized. The second masking layer is removed and a second epitaxial layer is formed in the openings. According to an alternate embodiment, after the first epitaxial layer is anodized, the second epitaxial layer is formed in the openings and the first epitaxial layer is then oxidized. According to a further alternate embodiment, the first epitaxial layer is anodized and oxidized after the second epitaxial layer is formed in the openings.

Description: The present invention relates generally to semiconductor integrated circuit processing, and more specifically to producing isoplanar isolated active regions. EP-A-0,222,225 relates to a method of semiconductor device fabrication employing selective epitaxial growth, in which interdevice isolation is formed as an integral part of the process, rather than as a separate formation step. One aspect of this process is that at least one of the active elements of the resultant structure are formed before the isolation layer, and may exist both inside and outside the selective epitaxial growth regions. The method comprises: etching a plurality of crevices in a semiconductor substrate, which may be an epitaxial layer; growing oxide over the inner surface of the crevices and forming the devices within the crevices by selective epitaxial growth. US-4,975,759 relates to a method comprising: the formation of a moat in a silicon substrate; the growth of an oxide layer over the sidewalls and bottom of the moat; the removal of the oxide from the bottom of the moat to expose the silicon; and the growth of an epitaxial stalk (a recessed mesa) from the bottom of the moat to a height which makes its top at least coplaner with the top surface of the substrate. US-4,628,591 relates to a method of isolating epitaxial islands by oxidizing suitably porous silicon. The porous silicon is created by anodizing. FR-A-2189871 relates to a method of making a semiconductor device. The oxidation of exposed portions of a substrate forms ridges which extend into and above the surface of the substrate. An epitaxial layer is deposited on the substrate to make the top surface of the structure substantially planar. Devices are subsequently formed in the epitaxial layer. Patent Abstracts of Japan vol 6, no 132 (E-119) [1010], 17 July 1982 and JP-A-57, 056942 relates to an isolated semiconductor structure. A silicon substrate is anodically oxidized. A layer is deposited. This layer is masked and anodically oxidized. The trend to continue to miniaturize semiconductor integrated circuits to achieve submicron feature sizes and increase the number of devices fabricated on the integrated circuit has required faster downscaling of lateral dimension than vertical dimensions, resulting in larger aspect ratios in surface topography. With densely packed circuits, there is a need to isolate components which are adjacent to each other to prevent leakage current. As with MOS transistors, current flows along the surface between the source and drain. The MOS transistors formed adjacent to each other must be separated by an isolation film thick enough so that there is no field induced currents flowing under the film. Isolating adjacent components in such a manner as to minimize surface topography is known as isoplanar isolation. Before the introduction of local oxidation of silicon (LOCOS) processes, it was common to provide MOS field isolation by growing a thick layer of field oxide across the wafer, then masking and removing oxide where active areas were to be formed. Using a wet etch step, this process did not allow for the creation of vertical oxide sidewalls. However, potential step coverage problems were avoided with this process, but at the expense of layout space, thus limiting device performance. The introduction of LOCOS was a great technological improvement. However, several problems occurred with LOCOS. Nonuniform thermal oxidation of a wafer surface, in the original LOCOS form, always incurred lateral encroachment, or tapering of the field oxide in the active areas growing under a nitride mask. This tapering effect, called "birdbeaking" is a sacrifice of active areas that becomes significant for feature sizes less than 1.5 microns. Attempts to suppress birdbeaking caused stress-related defects in the nearby substrate. Process complexity then occurred in attempting to avoid these stress-related defects. To achieve submicron geometries, there can be little or no physical loss of the active areas as occurs with the birdbeaking phenomenon. Thus, it is necessary to reconsider the prior art approach where vertical walls are needed to manufacture devices with feature sizes less than 1.5 microns. Abrupt topography results from vertical walls, causing difficulty in subsequent patterning and etching of films deposited over the wafer. Moreover, vertical walls, or near vertical walls, can only be achieved by dry etching of oxide. Damage to the active areas may result from marginal overetching. For a number of years, various observers have noted the potential value of selective epitaxial refill of contact holes etched through field oxide in order to achieve a completely planar surface. Selective epitaxial refill may cause defects near the active area/field oxide interface because the epitaxial layer is unable to grow in the <111> direction. Anomalies in epitaxial growth may also result due to any etching damage of the starting surface before the epitaxial refill. It would be desirable for a semiconductor process to produce isoplanar isolated active and field regions. It is a further object of this invention to provide such a semiconductor fabrication process by anodizing and oxidizing the field oxide regions and refilling the remaining areas with epitaxial silicon. It is yet another object of this invention to provide such a semiconductor fabrication process for making isoplanar active regions separated by isoplanar field oxide isolated regions which are suitable for use with small device geometries. Other objects and advantages of this invention will be apparent to those of ordinary skill in the art having reference to the following specification, together with its drawings. According to a first aspect of the present invention there is provided a method of producing isoplanar isolated regions in an integrated circuit comprising the steps of: forming a first epitaxial layer over a substrate having a (100) crystal orientation; patterning and etching the first epitaxial layer to form isolated regions having sloped sidewalls, said sloped sidewalls having a (111) crystal orientation; and said method further comprises the steps of: anodically rendering porous the isolated regions of first epitaxial layer; oxidizing the first epitaxial layer after said rendering step; and forming a second epitaxial layer in the openings between the isolated regions. According to a second aspect of the present invention there is provided an integrated circuit structure, comprising: a silicon substrate having a (100) crystal orientation and having a planar upper surface; a plurality of oxide regions, having planar upper surfaces, formed on the substrate upper surface and separated by spaces, wherein the oxide regions have sidewalls sloped at a (111) crystal orientation and which are wider at a bottom portion in contact with the substrate than at the planar upper surfaces, and wherein the oxide regions have physical characteristics of an oxide material formed from thermal oxidation or porous silicon; and a plurality of epitaxial regions in contact with the oxide regions, wherein the epitaxial regions, which have an inverted trapezoidal volume, are wider at an upper portion spaced from the substrate than at a lower portion in contact with the substrate and have upper surfaces coplanar with the oxide region upper surfaces. The invention may be incorporated into a method for forming an integrated circuit, and the integrated circuit formed thereby, by producing isoplanar isolated regions on the surface of a wafer having a (100) crystal orientation. A first epitaxial layer is formed over the substrate and then patterned and etched to form openings in the layer. This first epitaxial layer is anodized and oxidized. A second epitaxial layer is then formed in the openings. The second epitaxial layer may be formed after the first layer is anodized but before the first layer is oxidized. The second epitaxial layer may also be formed before the first layer is anodized and oxidized. The novel features believed characteristic of the invention are set forth in the appended claims. The invention itself, however, as well as a preferred mode of use, and further objects and advantages thereof, will best be understood by reference to the following detailed description of illustrative embodiments when read in conjunction with the accompanying drawings, wherein: Figures 1-5 are cross-sectional views of the fabrication of an integrated circuit, at various steps, according to one embodiment of the invention. Figures 6-10 are cross-sectional views of the fabrication of an integrated circuit, at various steps, according to an alternative embodiment of the invention. The process steps and structures described below do not form a complete process flow for manufacturing integrated circuits. The present invention can be practiced in conjunction with integrated circuit fabrication techniques currently used in the art, and only so much of the commonly practiced process steps are included as are necessary for an understanding of the present invention. The figures representing cross-sections of portions of an integrated circuit during fabrication are not drawn to scale, but instead are drawn so as to illustrate the important features of the invention. Referring to Figure 1, an integrated circuit is to be formed on a silicon substrate 10. The substrate must be a wafer which has a single crystal structure with the proper crystal orientation. The planes of the specific orientation are known in the art as the Miller indices, identified by a series of three numbers. The two most common crystal orientations for a silicon wafer are the (100) and (111) planes. In this invention the substrate is from a wafer having the (100) orientation. The substrate may be doped with a p-type dopant as known in the art to act as an etch stop during subsequent anisotropic etch processes. A first epitaxial layer of silicon 12 is then grown on the substrate 10 as known in the art. The epitaxial layer will conform to the same (100) crystal orientation as that of the underlying substrata. The epitaxial layer may be doped with an n-type dopant as known in the art to improve its etching properties. A first masking layer 14 is then deposited on the first epitaxial layer 12 as known in the art. The first masking layer is preferably silicon dioxide (SiO2) or silicon nitride (Si 3 N 4 ). Referring to Figure 2, the integrated circuit is then patterned to form openings in the first masking layer. The first epitaxial layer 12 is etched to form openings in the layer as shown in Figure 3. The etch process is an anisotropic etch which results in the sidewalls of the first epitaxial layer having a (111) crystal orientation or a nearly 54.74 degree slope. Among the alternative anisotropic etchants that may be used for this process depending upon the masking layer used may include ethylene diamine, pyrocatechol ("EDP"), sodium hydroxide ("NaOH"), potassium hydroxide ("KOH") or hydrazine ("N 2 H 4 "). The first masking layer 14 is then removed by known methods. An alternative etch process consists of a wet/dry etch combination as known in the art to produce the same (111) crystal orientation. Because the wet/dry etch process may result in defects in the crystal orientation of the sidewalls of the first epitaxial layer 12, passivation of the layer, such as a boron implant, may be required to eliminate such defects. Referring to Figure 4, a second masking layer 16 is deposited across the wafer surface and then patterned in the openings between the isolated first epitaxial layer 12 regions. The patterning of layer 16 involves a non-critical photolithographic alignment. This second masking layer 16 is preferably Si 3 N 4 . A thin layer of approximately 10nm - 20nm (100-200 Angstroms) of oxide may be grown or deposited under layer 16 before layer 16 is deposited to protect the underlying first epitaxial layer 12 and the substrate 10 during deposition and subsequent removal of layer 16. The first epitaxial layer 12 is then anodized converting the n-type doped layer to porous silicon. The n-type doped epitaxial layer will anodize faster than the p-type doped substrate. Layer 12 is subsequently oxidized to form isolated regions of oxide having sidewall angles of 54.73 degrees or the (111) crystal orientation. Anodization of the isolated regions of layer 12 before oxidation allows layer 12 to retain its same volumetric size. The oxide expands to fill substantially the original space occupied by the anodized epitaxial silicon, thus creating little or no deformation of the integrated circuit. This anodization process of converting silicon to dioxide, known in the art, is described more filly in United States Patent US-A-4 628 591, issued December 16, 1986, Method For Obtaining Full Oxide Isolation Of Epitaxial Islands In Silicon Utilizing Selective Oxidation Of Porous silicon, of E.J. Zorinsky and D.B. Spratt. The second masking layer 16, used as an anodization mask, is subsequently removed. Referring to Figure 5, a second layer of epitaxial silicon 18 is then grown in the active regions between the isolated regions of the first epitaxial layer 12. The regions of epitaxial layer 18 are now suitable for fabrication of MOS devices isolated by the epitaxial regions 12. An alternative embodiment includes growing and etching the first epitaxial layer 12 as above, again preferably having been doped with an n-type dopant. The second masking layer 16 is deposited. After layer 12 is anodized, the second masking layer 16 is removed. The second epitaxial layer 18 is then grown between the remaining isolated regions of the first epitaxial layer 12. Layer 12 is then oxidized to form insulating regions around layer 18 as shown in Figure 5. A further alternative embodiment to the above process includes growing and etching the first epitaxial layer 12 as above. The second masking layer 16 is not deposited. The second epitaxial layer 18 is grown in between the isolated regions of layer 12. Layer 12 is subsequently anodized and oxidized to form the insulating regions around the epitaxial regions 18 as shown in Figure 5. Because the isolated regions of layer 12 are doped with an n-type dopant, these regions will anodize at a faster rate than the second epitaxial layer 18 used to refill the active regions between the regions of layer 12. Referring to Figure 6, an additional alternative method is shown. The process steps are the same as above to grow a first epitaxial layer 32 over a substrate 30, deposit and pattern a first masking layer 34 and etch layer 32. The crystal orientations are the same as those described above. Again, epitaxial layer 32 may be doped with an n-type dopant to improve its etching and anodizing properties. Next, a second masking layer 36 is conformally formed over the first masking layer 34. This second masking layer 36 is preferably silicon nitride or silicon nitride over a thin layer of oxide. The oxide may be grown or deposited while the silicon nitride is deposited by methods known in the art. If a thin layer of oxide is first formed under the silicon nitride, it generally will have a thickness between 10nm-20nm (100 and 200 Angstroms). A polymer layer 38 is then non-conformally spun onto the surface of the wafer. Layer 38 may be typically a polyimide or photoresist. Referring to Figure 7, the second masking layer 36 and polymer layer 38 are then etched, preferably by a plasma etch. One of the advantages of this process is that the etch step, after layer 38 is spun onto the wafer, becomes self-aligning. Referring to Figure 8, the first masking layer 34 is removed. The first epitaxial layer 32 is then anodized. Referring to Figure 9, the polymer layer 38 is preferably removed after anodization but before oxidation of layer 32. Layer 32 is then oxidized. The second masking layer 36 is removed. At this stage of the process, there are isolated regions of oxide formed from the first epitaxial layer 32. Referring to Figure 10, a second epitaxial layer 40 is grown in the active regions between the isolated regions of oxide. These regions of layer 40 are now suitable for fabrication of MOS devices isolated by the epitaxial regions 32. This process may also be used for any device which needs to be isolated laterally by oxide. For example, thick epitaxial layers may make this process suitable for use in manufacturing high-voltage semiconductor devices. Growth of the two epitaxial layers 12 and 18 as shown in Figure 5 and layers 32 and 40 as shown in Figure 10, forms a planar surface for subsequent processes. Anodizing and oxidizing epitaxial silicon forms isoplanar insulating regions of oxide around the active areas. The epitaxial silicon growth or epitaxial refill between the insulating regions of oxide provides for isolated active regions for fabrication of devices without sacrificing device performance or usable layout space.

Claims: A method of producing isoplanar isolated regions in an integrated circuit comprising the steps of: forming a first epitaxial layer (12;32) over a substrate having a (100) crystal orientation; patterning and etching the first epitaxial layer (12;32) to form isolated regions having sloped sidewalls, said sloped sidewalls having a (111) crystal orientation; and said method further comprises the steps of: anodically rendering porous the isolated regions of first epitaxial layer; oxidizing the first epitaxial layer (12;32) after said rendering step; and forming a second epitaxial layer (18;40) in the openings between the isolated regions. The method of claim 1, wherein said step of patterning and etching the first epitaxial layer comprises: forming a first masking layer (14;34) over the first epitaxial layer (12;32); patterning the first masking layer (14;34); etching the first epitaxial layer (12;32) and removing the first masking layer (14;34) after the first epitaxial layer (12;32) is etched. The method of claim 2, wherein the first masking layer (14) is silicon dioxide. The method of claim 2, wherein the first masking layer (14) is silicon nitride. The method of any preceding claim, further comprising the steps of forming a second masking layer (16) in the openings, before the step of anodically rendering porous the first epitaxial layer; and removing said second masking layer before said step of forming the second epitaxial layer in the openings. The method of claim 5, wherein the second masking layer is silicon nitride. The method of claim 2, further comprising, after the step of etching the first epitaxial layer (32) and before the step of removing the first masking layer (34), the steps of: forming a polymer layer (38); and etching the polymer layer to expose the first masking layer (34). The method of claim 7, wherein a second masking layer (36) is formed before the polymer layer (38) is formed and is removed from the surface of the first masking layer 34)during said step of etching the polymer layer. The method of claim 8, wherein the second masking layer is silicon nitride. The method of claim 8, wherein the second masking layer is a layer of silicon nitride over a layer of oxide. The method of any one of claim 8 to 10, wherein the polymer layer (38) is removed before anodically rendering porous the first epitaxial layer. The method of any preceding claim, wherein the substrate is doped with a p-type dopant. The method of any preceding claim, wherein the first epitaxial layer is doped with an n-type dopant. The method of any preceding claim, wherein the etching step is an anisotropic etch. The method of claim 15, wherein the anisotropic etchant is ethylenediamine-pyrocatechol. The method of any one of claims 1 to 13 wherein the etching step is a combination wet/dry etch which provides sidewalls having a (111) crystal orientation. The method of claim 16 further comprising the step of passivating the sidewalls. The method of claim 17 wherein the passivating step is a boron implant. The method of claim 2, in which the first epitaxial layer is doped with an n-type dopant further comprising the steps of: forming said second epitaxial layer prior to said step of oxidising the first epitaxial layer; and anodizing the first and second epitaxial layers such that the n-type first epitaxial layer regions anodize at a faster rate than the second epitaxial layer. An integrated circuit structure, comprising: a silicon substrate having a (100) crystal orientation and having a planar upper surface; a plurality of oxide regions, having planar upper surfaces, formed on the substrate upper surface and separated by spaces, wherein the oxide regions have sidewalls sloped at a (111) crystal orientation and which are wider at a bottom portion in contact with the substrate than at the planar upper surfaces, and wherein the oxide regions have physical characteristics of an oxide material formed from thermal oxidation or porous silicon; and a plurality of epitaxial regions in contact with the substrate upper surface and filling the spaces between the oxide regions, wherein the epitaxial regions, which have an inverted trapezoidal volume, are wider at an upper portion spaced from the substrate than at a lower portion in contact with the substrate and have upper surfaces coplanar with the oxide region upper surfaces. The integrated circuit structure of claim 20 wherein the substrate is doped with P-type impurities, and the epitaxial regions are doped with N-type impurities.

Inventors: MILLER ROBERT OTIS, MILLER, ROBERT OTIS
Applicants: ST MICROELECTRONICS INC, STMICROELECTRONICS, INC.
Application year: 1992
Main classification: H01L21
IPC codes: H01L21