Cemented carbide body with increased wear resistance

Abstract: According to the invention there is now provided a cemented carbide button for rock drilling comprising a core (a) and a surface zone (b,c) surrounding the core whereby both the surface zone and the core contains WC (alpha-phase) and a binder phase based on at least one of cobalt, nickel or iron and that the core in addition contains eta-phase. The invention is characterized in that the eta phase core (a) extends to the very top working surface of the button and as result longer life and higher drilling rate are obtained particularly for rotary crushing drilling, cutting drilling and percussive drilling in soft rocks.

Description: The present invention relates to cemented carbide buttons useful in tools for rock drilling, mineral cutting, oil drilling and in tools for concrete and asphalt milling. In EP-A-182759 cemented carbide buttons are disclosed with a core with finely and evenly distributed eta-phase embedded in the normal alpha + beta - phase structure, and a surrounding surface zone with only alpha + beta - phase. (Alpha = tungsten carbide, beta = binder-phase, e.g., cobalt and eta = M 6 C, M 12 C and other carbides, e.g., Co 3 W 3 C). An additional condition is that in the inner part of the surface zone situated close to the core the cobalt-content is higher than the nominal content of cobalt and that the cobalt-content in the outermost part of the surface zone is lower than the nominal and increases in the direction towards the core up to a maximum usually at the eta-phase core. Cemented carbide buttons according to the mentioned patent application have given increased performance for all cemented carbide grades normally used in rock drilling. When drilling with buttons according to the above mentioned patent the cobalt-poor surface layer is successively worn away. The cobalt-rich intermediate layer, when exposed, is worn more rapidly than the surrounding areas and a crater is formed, fig 1.3. As a result, the risk for spalling is increased and at the same time the drilling rate is decreased. At continued wear the eta-phase core is exposed and the button then assumes a more rounded cap shape, fig 1.5. The wearing through of the cobalt-rich intermediate zone is particularly critical in rotary crushing drilling with chisel shaped or conical buttons which are not reground. In order to avoid too deep a crater in the button the thickness of the etaphase free surface zone is kept to a minimum. The risk is then that the cobalt-poor surface zone peels off and expose the cobalt-rich part with a resulting rapid wear. The button thereby quickly loses several mm in protrusion height. The protrusion and shape of the button influence the drilling properties, in particular the penetration rate. According to the invention it has now turned out that buttons where the etaphase core extends out to the very top working surface of the button give longer life and increased drilling rate, particularly in rotary crushing drilling, percussive drilling in soft rocks and in mineral cutting. The etaphase core is not crushed due to that it is protected by the surface zone free of etaphase, whose outer part is under compressive stress. The invention is described with reference to the following figures in which a - etaphase core, b - cobalt-rich zone and c - cobalt-poor zone. Fig 1 shows a button made according to known technique, in which:. 1.1 Unworn button. 1.2 Wear only in the cobalt-poor etaphase free surface zone. 1.3 Wear through the cobalt-rich intermediate zone. 1.4 Continued wear - the button has changed shape. 1.5 The etaphase core clearly exposed. Fig 2 shows buttons according to the invention in various embodiments, namely: 2.1 Conical button, symmetrical etaphase core. 2.2 Spherical button, asymmetrical etaphase core. 2.3 Chisel-shaped button, symmetrical eta-phase core. The eta-phase core contains at least 2 % by volume, preferably at least 5 % by volume of eta-phase but at the most 60 % by volume, preferably at the most 35 % by volume. The eta-phase shall be finegrained with a grain size of 0.5 - 10 µm, preferably 1 - 5 µm, and be evenly distributed in the matrix of the normal WC-Co-structure. The width of the eta phase core shall be 10 - 95 %, preferably 25 - 75 % of the cross section of the cemented carbide body. The etaphase core extends to the very top (working) surface of the button. Normally, the position of the core is symmetrical, but for certain locations of the button in a drill, e.g., as peripheral button, the core may suitably be in an asymmetrical position in the button. The binder phase content in the zone free of eta-phase increases in the direction towards the eta-phase core up to a maximum usually at the eta phase core of at least 1.2 times, preferably at least 1.4 times, compared to the binder phase content in the centre of the eta phase core. In addition, the top surface of the button may have a thin surface layer 10-100 µm thick free of etaphase. The invention can particularly be used in grades with 10-25 % by weight cobalt for rotary crushing drilling, but also in grades with 5-10 % by weight cobalt for percussive drilling in softer rocks and in grades with 6-13 % by weight cobalt for mineral tools. The WC-grain size can vary from 1.0 µm up to 10 µm preferably 2-8 µm. The cobalt-portion in the eta-phase can completely or partly be replaced by one of the metals iron or nickel i.e. the etaphase itself can contain one or more of the iron group metals in combination. Up to 15 % by weight of tungsten in the alfaphase can be replaced by one or more of the metallic carbide former Ti, Zr, Hf, V, Nb, Ta, Cr and Mo. Cemented carbide bodies according to the invention are manufactured according to powder metallurgical methods: milling, pressing and sintering. By starting from a powder with substoichiometric composition with respect to carbon an etaphase containing cemented carbide is obtained during the sintering. This is after the sintering given a carburizing heat treatment. The top surface of the button is protected from carburisation by a thin layer of, e.g., Al 2 O 3 . The invention also relates to a method of rock drilling at which a cemented carbide button having an etaphase core is brought in contact with rock and the button moves relative to the rock, whereby material is removed from the rock. According to the invention the etaphase core is already from the beginning of the drilling in contact with the rock. Example 1 Buttons with a conical top were pressed using a WC-10 wt% cobalt powder with 0.2 % by weight substoichiometric carbon-content (5.3 % by weight carbon instead of 5.5 % by weight). These were sintered at 1450°C under standard conditions. After sintering the diameter of the buttons was 14 mm. The top surface of the buttons was covered by a CVD-layer of Al 2 O 3 . The buttons were then heat treated in a furnace containing CO/H 2 atmosphere at 1400°C for 4 hours. The buttons manufactured in this way comprised a 4 mm wide surface zone free of eta-phase and a core with a diameter of 6 mm containing finely dispersed eta-phase. The core extended to the top surface of the button, (fig. 2.1). The cobalt-content at the surface of the cylindrical part was measured to be 5 % by weight and just outside the eta-phase-core 16 % by weight. Example 2 Buttons with a chisel-shaped top were pressed using a WC-15 wt% cobalt powder with a 0.4 % by weight substoichiometric carbon-content (4.8 % carbon instead of 5.2 %). The buttons were sintered at 1410°C under standard conditions. After sintering the diameter of the buttons was 12 mm. The buttons were covered by a thin layer of graphite-slurry except from the top surface which was coated with a thin layer of Al 2 O 3 -slurry. The buttons were then heat treated in a furnace containing H 2 atmosphere at 1400°C for 2 hours. The buttons manufactured in this way comprised a 3 mm wide surface zone free of eta-phase and a core with a diameter of 6 mm containing finely dispersed eta-phase. The core extended to the top surface of the button, (fig. 2.3). The cobalt-content at the surface of the cylindrical part of the button was measured to be 7 % and just outside the eta-phase-core 25 %. Example 3 Drilling in an open pit mine with roller bits. Machine: Bucyrus Erie 45R. Feeding pressure was 30 ton and rotation 60-85 rpm. Holes with a depth of 20 m were drilled. Bit: 9 7/8" CS 3. Rock: Biotite gneiss-mica slate. Variant 1. Buttons according to Example 1. Variant 2. Buttons according to EP-A-182759 with an average cobalt-content of 10%. Result: Variant Life length m Index Rate of penetration m/h Index 1 1210 106 18 139 2 1145 100 13 100 The bit according to the invention has reached longer life but above all higher penetration rate. Example 4 In raise boring, rolls equipped with cemented carbide buttons are used. The buttons have a chisel shaped top and the rolls are scrapped when the buttons are worn flat. On a raise-head (diameter 2.5 m) a roll with cemented carbide buttons (diameter 22 mm) according to the invention was tested. A test-roll with standard buttons was placed diametrically to the former roll. Rig Robbins 71R. Drilled shaft 155 m. Rate of penetration 0.9 m/h. Variant 1. Buttons according to the invention with a diameter of 22 mm and a surface zone free of eta-phase of 5 mm. The cobalt-content close to the outer surface of the button was 8 % and in the cobalt-rich part of the surface zone it was 22 %. The nominal cobalt-content was 15 %. Variant 2. Standard buttons with a cobalt-content of 15 %. Variant 3. Buttons according to EP-A-182759 with an average cobalt-content of 20 %. The thickness of the eta-phase free surface zone was 4 mm. Result: The remaining button-protrusion for variant 1 was 6 mm and for variant 2 was 3.5 mm. The buttons according to variant 2 had in addition a more rounded top. The surface zone free of eta-phase of the buttons according to variant 3 was spalled in an early stage and the remaining button-protrusion was 3 mm. Example 5 Test with oil drill bits on an "on shore rig". The bits were tested in an area with abrasive formations containing sandstone and limestone. Bit dimension : 7 7/8". Type of buttons : Chisel shaped. Variant 1. In row 1 buttons according to the invention with a nominal cobalt-content of 8%. In the other rows buttons according to EP-A-182759 with a nominal cobalt-content of 15 %. Variant 2. In row 1 buttons according to EP-A-182759 with a nominal cobalt-content of 8%. In the other rows buttons according to EP-A-182759 with a nominal cobalt-content of 15%. Variant 3. Standard buttons with a cobalt-content of 8% in row 1 and 15% in the other rows. Result: Variant Number Drilled meters Index Rate of penetration m/h Index 1 3 485 178 8.3 184 2 3 389 143 6.4 142 3 5 273 100 4.5 100 The distinctly better result of variant 1 is a consequence of the increased wear resistance thus leading to a maintained chisel shaped top of the buttons in row 1. Example 6 Trenching in tarmac road for laying gas pipe line. Machine: Rivard 120. 12 ton band tractor with one trenching wheel, diameter 2 m, equipped with totally 80 cutting tools. Wheel width 0.25 m. Rotation speed of the tool 10 m/s. Trench depth 1 m. Tool positioning: The standard- and the test variants were placed in such a way that a fair judgement of properties could be made. Type of button: Diameter 18 mm with a conical top and a length of 30 mm, brazed into standard tools. Variant 1. Cemented carbide according to the invention. A nominal cobalt-content of 11%, the same zone distribution as in variant 2 but the eta-phase reached the top surface of the button. Variant 2. Cemented carbide according to EP-A-182759. Nominal cobalt-content 11%, the surface zone free of eta phase was 5 mm in which the cobalt-poor part was 3 mm and the cobalt-rich part was 2 mm. Variant 3. Standard cemented carbide with 11% cobalt and the WC-grain size 4 µm. About 100 m 3 road was cut, the asphalt was 0.1 m thick, the intermediate layer containing bricks, sand and limestones was 0.3 m thick and the ground below contained sand, pebbles and some parts of limestone. Result: Variant Height wear mm Index Failures Number of tools 1 4.2 250 0 20 2 5.4 182 3 20 3 9 100 4 40 Example 7 Drifting in a limestone mine with drill bits, diameter 55 mm, equipped with buttons, diameter 11 mm. Drilling machine COP 1038 HB. Feeding pressure 60 bar. Rotation pressure 60 bar. Hole depth 4.4 m. Variant 1. Buttons according to the invention. Nominal cobalt-content 6%. The diameter of the eta-phase core was 6 mm and the core reached the top surface of the button. The button had a conical top. Variant 2. Buttons according to EP-A-182759 with the same size of the eta-phase core as in variant 1. Nominal cobalt-content 6% and a conical top. Variant 3. Standard buttons with 6% cobalt and a spherical top. Result: Variant Life length m Index Rate of penetration m/min Index 1 1685 131 2.3 153 2 1320 116 1.9 127 3 1142 100 1.5 100

Claims: Cemented carbide button for rock drilling having a working surface and comprising a core and a surface zone surrounding the core whereby both the surface zone and the core contain wolfram carbide and a binder phase based on at least one of cobalt, nickel or iron and that the core in addition contains eta-phase (a) characterized in that the eta phase (a) core extends to the very top working surface of the button from the beginning of the first use of the button. Cemented carbide button according to claim 1 characterized in that the eta phase (a) core is asymmetrically located in the button. Cemented carbide button according to claim 1 or 2 characterized in that the binder phase content in the zone free of eta-phase increases in the direction towards the eta-phase (a) core up to a maximum of at least 1.2 times, preferably at least 1.4 times, the binder phase content in the centre of the eta phase core. Method of manufacturing a cemented carbide button having a working surface for rock drilling by powder metallurgical methods such as milling, pressing and sintering whereby a powder with substoichiometric content of carbon is sintered to an etaphase (a) containing body which after the sintering is given a partially carburizing heat treatment whereby an eta-phase containing core surrounded by an eta-phase free surface zone is obtained characterized in that the eta-phase core which extends to the very top working surface of the button is protected from carburization. Method of rock drilling at which a cemented carbide button having a working surface and comprising a core and a surface zone surrounding the core, whereby both the surface zone and the core contains wolfram carbide and a binder phase based on at least one of cobalt, nickel or iron and that the core in addition contains eta-phase, is brought in contact with rock and the button moves relative to the rock whereby material is removed from the rock characterized in that from the beginning of the first use of the buttom the etaphase (a) core extending to the working surface of said button is in contact with the rock.

Inventors: AKERMAN JAN, FISCHER UDO, HARTZELL TORBJOERN, AKERMAN, JAN, FISCHER, UDO, HARTZELL, TORBJOERN, Hartzell, Torbjörn
Applicants: SANDVIK AB, SANDVIK AKTIEBOLAG
Application year: 1992
Main classification: E21B10
IPC codes: E21B10, E02F9, B22F7, B28D1