Modular solar cell with protective member

Abstract: A solar cell is provided with a photovoltaic device, covering material for covering the photovoltaic device, and a frame for covering the end portions of the covering materials. The covering materials are provided, in the end portions thereof, with a recess or a penetrating hole. The frame is provided with a projection adapted to engage with the recess or penetrating hole.

Description: The present invention relates to a solar cell adapted for use in various electronic equipment or electric power supply devices, and more particularly to a modular solar cell with an improved protective member constituting protective means therefor. Because of recent forecast for the warming of entire earth by the greenhouse effect resulting from the increase of CO 2 , request has become stronger for clean energy without CO 2 discharge. However, the nuclear power generation which is free from CO 2 discharge is still associated with the problem of disposal of radioactive products, so that clean energy with improved safety is longed for. Among the future candidates of such clean energy, the solar cell is expected highly because of its cleanness, safety and easy handling. Among various solar cells, those based on non-monocrystalline semiconductors such as amorphous silicon or copper indium selenide are subject of intensive developmental works, as these materials can be prepared in a large area and with a low production cost. If impact resistance or flexibility is required, such solar cells are often formed on a metal substrate such as of stainless steel. For the purpose of reducing the weight of the solar cell formed on the stainless steel substrate, ensuring flexibility and providing weather resistance or impact resistance, such solar cell is sealed with resin such as fluorinated resin or ethylene vinyl acetate (EVA). After such resin sealing, the end portions of the solar cell is covered with a protective frame composed of a metal such as aluminum or a polymer such as polyvinyl chloride or synthetic rubber, for the purpose of protecting the end faces and providing a support member. Particularly if flexibility is required for the solar cell module, there is usually employed flexible polymer such as synthetic rubber of soft polyvinyl chloride. The fixation between the end portions of the sealed solar cell and the protective frame for example of polymer material is achieved by an adhesive material, after the contact faces are pre-treated with plasma, strong acid or strong alkali for facilitating the adhesion. Fig. 1 is a schematic cross-sectional view of a conventional solar cell. In Fig. 1 there are shown a solar cell device 401 formed on a conductive substrate; a resinous covering material 404 for sealing said solar cell device 401; a resin-sealed solar cell 402; and a protective frame 403 composed of flexible resin. The outermost layer of the resin 404 is usually composed of fluorinated resin, in consideration of weather resistance. Also the protective frame 403 is usually composed of synthetic rubber or soft polyvinyl chloride, in consideration of the weather resistance and flexibility. Since the fluorinated resin, employed for sealing the solar cell and the synthetic rubber or soft polyvinyl chloride constituting the protective frame are difficult to adhere, the adhesion with the adhesive material is executed after the contact faces of the resin 404 and the protective frame 403 are pre-treated with plasma, strong acid or strong alkali, for facilitating the adhesion. Although the solar cells are sometimes used indoors under the light of fluorescent lamps, those used outdoors are required to have sufficient durability to the influence of various ambient conditions such as high temperature, low temperature, high humidity, rain, wind etc. For this reason, the conventional solar cell module is usually composed of a seal portion 404 for the solar cell device and a frame portion 403. Fig. 2 is a schematic cross-sectional view of another conventional solar cell module. In a laminar member 21 constituting the solar cell module, the light-receiving face (upper face in the drawing) of a solar cell device 22 is covered, across an adhesive material 23, by a sheet-shaped surface protecting material composed of transparent resin, while the rear face (lower face) of the device 22 is covered, across an adhesive material 23, by a sheet-shaped rear face protecting material 25. Said coverings are provided by vacuum lamination, and the solar cell device 22 is hermetically sealed inside. The laminar member 21 is cut at positions outside the solar cell device 22, and the cut faces constitute the end faces 21c, 21d of said laminar member 21. Aluminum frames 26, 27 for supporting the laminate member 21 is respectively provided with grooves 26a, 27a, into which inserted respectively are the edge portions 21a, 21b of the laminate member 21. Fillers 26f, 27f for example of silicone rubber are provided in the gaps between the edges 21a, 21b and the grooves 26a, 27a, in order to prevent intrusion of water and vapor into the interior of the laminate member 21. The solar cell modules constructed as shown in Figs. 1 and 2 are positioned outdoors and used under various climate conditions such as high temperature, low temperature, high humidity, wind, rain etc. However the strength of adhesion is not still sufficiently high even with the above-mentioned pretreatment, and the frames 403, 26, 27 may be dismantled when a strong external force is applied. Enough reliability cannot be attained even when the strength of adhesion is increased by the above-mentioned pretreatment prior to the adhesion, the frames 403, 26, 27 may be dislodged from the solar cell module in a prolonged outdoor use or by a strong external force. Such dislodging of frames leads to the peeling of covering material of the solar cell from the end faces thereof, thus deteriorating the quality of the solar cell. Also the filler, for example of silicone rubber, filled in the gaps between the frame grooves and the edge portions of the covering material as in the solar cell module shown in Fig. 2, often does not have a sufficiently low moisture permeability though the water absorbability is low. Besides the complete filling of said gaps with the filler is difficult, and said gaps eventually remain incompletely filled. As a result, water or moisture enters the grooves in the course of use of the solar cell and eventually reaches the solar cell device through the cut end faces of the module, thereby causing shortcircuting of the solar cell device or destruction thereof by peeling of thin film thereof. According to the document DE-A-3 513 910, there is known a solar cell device comprising at least a solar cell embedded in a resinous covering material for sealing said solar cell. In the resinous material there are also embedded reinforcing frame elements, said elements being provided with penetrating holes for mounting said solar cell device at an appropriate place. An object of the present invention is to resolve the above-mentioned drawbacks and to provide a highly reliable solar cell which is not destructed in the prolonged outdoor use or under a strong external force. This object is achieved by means of the features defined in claim 1. Preferable embodiments of the invention are defined in the subclaims. Another object of the present invention is to provide a solar cell module with an improved ability for preventing the moisture intrusion from the end faces of module edges, inserted into the frame grooves, into the interior of the module. Still another object of the present invention is to provide a solar cell provided with a photovoltaic device, covering materials covering said device, and a frame member covering the end portion of said covering materials, wherein said covering materials is provided, in the end portion thereof, with recess(es) or penetrating hole(s) while said frame is provided with projection(s) engaging with said recess(es) or penetrating hole(s). Still another object of the present invention is to provide a solar cell module provided with: a solar cell including a photovoltaic device, and a covering material for covering said photovoltaic device; a support member for supporting said solar cell; and a protective member for protecting the end portions of at least two adjacent support members in an array of plural support members; wherein said support member is composed of a plate-shaped deformable member, of which the end portion is so folded as to form a slit for accommodating the end portion of said covering material. Still another object of the present invention is to provide a solar cell module provided with: a solar cell including a photovoltaic device, and a covering material for covering said photovoltaic device; a support member for supporting said solar cell; and a protective member for protecting the end portions of at least two adjacent support members in an array of plural support members; wherein said support member is provided, at the end portion thereof, with another member so as to form a slit for accommodating the end portion of said covering material. The solar cell module of the present invention, including a solar cell sealed in a covering material and a protective frame for protecting the end portion of said solar cell by pinching the end portion thereof, is featured by a fact that said solar cell and said protective frame are respectively provided with penetrating holes, and are mutually fixed by engaging members penetrating through said holes. Said engaging member preferably has an external diameter a at least equal to 5 mm in a portion exposed from the solar cell module, and a ratio a/b, to the shaft diameter b in said penetrating hole, at least equal to 1.2. More preferably, said engaging member is composed of an eyelet having a penetrating hole in the center. The present invention allows to improve the strength by fixing the solar cell and the protective frame therefor with an engaging member passing through the penetrating hole, in comparison with the conventional structure in which fixing relies solely on the adhesive material. Strong fixation is achievable even in a combination of materials difficult to adhere with an adhesive material, such as a resin-sealed solar cell and a protective frame composed of resin. Fixation with a higher strength can be achieved by the use of an engaging member, having an external diameter of at least 5 mm in a portion exposed from said solar cell module and a ratio a/b to the shaft diameter b in said penetrating hole at least equal to 1.2. Also said engaging member is preferably composed of an eyelet, having a penetrating hole in the center, whereby said hole can be utilized for example for passing a rope after the completion of the solar cell module, and the fixation of said module can be facilitated. Also the foregoing objects can be attained, according to the present invention, by a solar cell module which is provided, on the internal faces of the frame grooves, with projections coming contact with the edge portion, other than end faces, of the laminate member, wherein the width of said grooves corresponding to the positions of said projections is smaller than the thickness of the edge portion of said laminate member. Because of said smaller width of the grooves, the edge portion inserted into said grooves is locally pressed in the areas coming into contact with said projections, whereby the moisture intruding from the end faces of the edge portion of the laminate member into the interior of said edge portion does not proceed further beyond thus pressed portions. In the following the invention is further illustrated by embodiments with reference to the enclosed figures. Figs. 1 and 2 are schematic cross-sectional views of conventional solar cell modules; Fig. 3 is a schematic cross-sectional view of a solar cell module of the present invention; Fig. 4 is a schematic view of an engaging member shown in Fig. 3; Fig. 5 is a schematic perspective view of a solar cell module of the present invention; Fig. 6 is a schematic cross-sectional view of a solar cell module constituting another embodiment of the present invention; Fig. 7 is a schematic plan view showing an example of the photovoltaic device adapted for use in the present invention; Fig. 8 is a cross-sectional view along a line A-A' in Fig. 7; Fig. 9 is an exploded view showing the structure of a covered solar cell adapted for use in the present invention; Fig. 10 is a schematic perspective view of a solar cell module of the present invention; Fig. 11 is a schematic perspective view of a frame adapted for use in the present invention; Fig. 12 is a schematic view showing an application of the solar cell module of the present invention; Figs. 13 to 15 are schematic cross-sectional views of solar cell modules constituting other embodiments of the present invention; Fig. 16 is a schematic cross-sectional view of a photovoltaic device adapted for use in the present invention; and Fig. 17 is a schematic external perspective view of the solar cell module of the present invention. In the following there will be given a detailed explanation on a photovoltaic device employed as the solar cell in the present invention. Fig. 16 is a schematic cross-sectional view of the photovoltaic device, in which a substrate 1301 with conductive surface can be composed, for example, of a conductive substrate such as stainless steel, aluminum, copper or carbon sheet, or of a glass substrate or a plastic sheet bearing thereon a transparent conductive film such as of ITO (indium tin oxide), SnO 2 , InO or ZnO. Although not illustrated, there may be further provided a surfacial conductive layer for example of Ti, Cr, Mo, W, Al, Ag or Ni. On said substrate there is provided a bottom photovoltaic cell consisting of an N-layer 1302, an I-layer 1303 and a P-layer 1304, and further provided thereon is a top photovoltaic cell consisting of an N-layer 1305, an I-layer 1306 and an N-layer 1307. A transparent electrode 1308, employed in the solar cell of the present invention, can be composed, for example, of In 2 O 3 , SnO 2 , In 2 O 3 -SnO 2 , ZnO, TiO 2 , Cd 2 SnO 4 or a crystalline semiconductor layer with high concentration impurity doping, and can be formed for example by evaporation by resistance heating, electron beam evaporation, sputtering, spraying, CVD or impurity diffusion. Grid electrodes 1309 are provided thereon. The filling material for resin sealing of the solar cell device of the present invention can be composed, for example, of ethylene-vinyl acetate copolymer, polyvinylbutyrol or silicone resin, but other materials may also be employed for this purpose. The covering material for covering the solar cell device is required to have light transmitting property and weather resistance against ultraviolet light or ozone, and is composed, for example, of a fluorinated resin film or silicone resin, but other materials may also be employed for this purpose. The protective frame, for pinching and protecting the end portion of the solar cell module of the present invention, can be composed for example of polyvinyl chloride or synthetic rubber in consideration of weather resistance and impact resistance. However polyvinyl chloride is preferred in consideration of weather resistance and ease of molding, and soft polyvinyl chloride is particularly preferred in order to provide the solar cell module with flexibility. On the other hand, if mechanical strength is required, a metallic material is preferred. The material for the projection and engaging member to be employed in the present invention is not particularly limited, but is selected in consideration of weather resistance, impact resistance and resistance to seawater. For example there may be employed a metallic member such as eyelet, rivet or screw, or a thermofusible resinous molded member of polypropylene, melamine resin or hard polyvinyl chloride. Among these, the eyelet is preferred in consideration of safety, fixing strength and cost. On the other hand, if an elevated strength is required in combination with simplicity of preparation, said member is preferably integrated with the frame. The semiconductor materials constituting the aforementioned N, I and P layers are preferably composed of amorphous, polycrystalline or microcrystalline materials. Specific examples of such materials include semiconductors of the group IV of the periodic table, such as silicon, germanium, silicon-germanium and silicon carbide, and compound semiconductors such as CuInSe, CdS, GaAs and ZnSe. The aforementioned layer of Ti, Cr, Mo, W, Al, Ag or Ni can be formed, for example, by evaporation by resistance heating, electron beam evaporation or sputtering. The amorphous silicon constituting PIN junction can be formed by plasma CVD employing silane gas. The polycrystalline silicon constituting PN junction can be formed by sheet formation with fused silicon, and the compound semiconductor such as CuInSe 2 /CdS can be formed by electron beam evaporation, sputtering or electrodeposition. [Example 1] Fig. 3 is a schematic cross-sectional view of the solar cell module of the present invention, wherein shown are a solar cell device 105 formed on a conductive substrate; a resinous covering material 110 for sealing said solar cell device 105; a resin-sealed solar cell module 101; a flexible resinous protective frame 102; and an engaging member 104 for mechanically fixing the sealed solar cell module 101 and the protective frame 102. Fig. 4 shows the details of the engaging member 104 in a plan view and a cross-sectional view along a line C-C'. Said member 104 of the present embodiment has a portion exposed from the solar cell module with an external diameter a at least equal to 5 mm, and a ratio a/b to the shaft diameter b in the penetrating hole at least equal to 1.2. In the present embodiment, the protective frame 102 may be easily dislodged from the engaging member 104 if the external diameter a thereof is less than 5 mm, or if the ratio a/b is less than 1.2. Said engaging member 104 preferably has an external diamter a at least equal to 5 mm, but it is more preferably at least equal to 7 mm. Also the ratio a/b of said diameter to the diameter of the shaft passing through the penetrating hole is preferably at least equal to 1.2, but said ratio is more preferably at least equal to 1.5. Also the end 105a of the solar cell device 105 is preferably positioned inside the internal end 102a of the protective frame 102. [Example 2] Fig. 5 is an external perspective view of the solar cell module of the present example, and Fig. 6 is a cross-sectional view along a line B-B' in Fig. 5. In Figs. 5 and 6 there are shown resin 110 for sealing a solar cell device 105; a resin-sealed solar cell module 101; a protective frame 102; eyelets 103 serving as engaging members; and a lead wire 109. In the following there will be given a detailed explanation on the manufacturing steps and materials of the solar cell module of the present example. Said module consists of a serial connection of plural solar cell devices shown in Fig. 7. Fig. 7 is a schematic plan view of a solar cell device before serial connection, and Fig. 8 is a cross-sectional view showing the laminar structure along a line A-A' in Fig. 7. In Figs. 7 and 8 there are shown a stainless steel substrate 201; an Al-Si layer 202; a non-monocrystalline silicon 203 with PIN structure; an ITO layer 204; Ag electrodes 205; a tin-plated copper bus bar 206; a device isolation area 207; adhesive silver ink 208; an exposed portion 209 of the stainless steel substrate for making serial connection; and an insulating tape 210 for preventing shortcircuiting. The above-explained solar cell device was prepared by sputtering Al, containing Si in 1 %, with a thickness of 5000 Å (10Å = 1 nm) in a roll-to-roll process on a washed and rolled stainless steel substrate, then forming silicon layers of N, I and P types of a thickness of 4000 Å by plasma CVD employing SiH 4 , PH 3 , B 2 H 6 and H 2 , and forming an ITO layer of 800 Å by resistance-heated evaporation. Then current-collecting electrodes for ITO were prepared by screen printing of silver paste. Then a bus bar electrode was placed perpendicularly to the silver electrodes, and adhesive silver ink was dropped to the crossing points, thereby connecting said silver electrodes with the bus bar electrode. In this example, seven solar cell devices shown in Fig. 7 were serially connected. The optimum voltage was 6 V. Then the serially connected solar cell devices were sealed as shown in Fig. 9. Fig. 10 schematically shows the solar cell after vacuum lamination. In Figs. 9 and 10 there are shown serially connected solar cell devices 105; glass fibers 301 for limiting the resin flow; ethylene vinyl acetate (EVA) resin 302; fluorinated resin 303; and a lead wire 109 connected to the solar cell. The resin sealing was conducted by fusing the EVA resin at 140°C with a vacuum laminator. The face of the fluorinated resin, to be adhered to EVA, was plasma treated in advance. Then a protective frame 102, molded in a recessed form with soft polyvinyl chloride, as shown in Fig. 11, was mounted on the end portion of thus vacuum laminated solar cell. In this operation, the mounted portion was temporarily adhered by silicone adhesive. Then holes for eyelets were opened in the solar cell and the protective frame 102, and twelve eyelets 103 with an external diameter of 7 mm and a shaft diameter of 4 mm were mounted as shown in Fig. 6. The solar cell module of this example, prepared as explained above, was subjected to a tensile test. In this test, the protective frame 102 was repeatedly given a tensile force of 5 kg for 5 seconds, and the charge in appearance of the solar cell module was observed. The tensile force was applied 100 times, and the obtained results are shown in Table. 1. [Reference example] This reference example employed the conventional structure shown in Fig. 1. In this structure, the preparation was conducted in the same manner as in the example 1, until the vacuum lamination of the solar cell device 401. Then the surface of fluorinated resin was plasma treated only in a portion to be adhered to a protective frame 403 molded with soft polyvinyl chloride, and said frame 403 was mounted on the end portion of the solar cell 402 as shown in Fig. 11. At said mounting, silicone adhesive was coated on the mounting portion, in order to adhere the solar cell 402 and the protective frame 403. The obtained module was subjected to a tensile test in the same manner as in the example 1, and the obtained results are shown in Table. 1. [Example 3] Fig. 12 is an external perspective view of an example 3 of the present invention, wherein shown are a resin-sealed solar cell 101; eyelets 106; strings 107 for fixing the solar cell module; a protective frame 108; and a lead wire 109. The solar cell module of the present invention is safe in use, as it is flexible and is free from rigid frame such as of metal. For this reason said solar cell module can be used on a yacht or in camping. For these applications, there are generally required holes for passing strings for fixation. In this example, the eyelets with penetrating holes for passing said strings also serve as the engaging members for fixing the protective frame provided at the end portion of the solar cell. The example shown in Fig. 12 was prepared in the same manner as the example 1, except for the size of the eyelets 106 and the form of the protective frame 108 composed of polyvinyl chloride. The eyelets 106 employed in this example had an external diameter of 23 mm, a shaft diameter of 14 mm and a height of 6 mm. Said eyelets allow to pass the strings ordinarily used on the yacht. The form of the protective frame 108 composed of polyvinyl chloride was varied according to the size of the eyelets 106. The solar cell module of the present example was also subjected to the tensile test explained above, and the obtained results are shown in Table. 1. [Example 4] In this example, the solar cell module was prepared in the same structure and process as in the example 1 shown in Figs. 5 and 6, except that the external diameter of eyelets was selected as 3 or 5 mm and the ratio a/b of the external diameter a to the shaft diameter b was selected as 1.8, and was subjected to a tensile test in a similar manner. The obtained results are shown in Table. 1. [Example 5] In this example, the solar cell module was prepared and tensile tested in the same manner as in the example 1 shown in Figs. 5 and 6, except that the external diameter of eyelets was fixed at 7 mm and the ratio a/b of the external diameter a to the shaft diameter b of the eyelets was varied in a range of 1.0 - 1.8. The obtained results are shown in Table. 1. Table 1 shows the results obtained in the examples 1 - 4 and in the reference example. Five samples A - E were prepared under the same conditions described in each of said examples and reference example, but the quality showed certain fluctuation because of manual preparation of the samples. Table. 1 shows the number of repeated applications of tensile force, until the protective frame is dislodged from the solar cell module. In the examples 1 and 2, the protective frame was not dislodged from the module after 100 cycles of tensile force. On the other hand, in the reference example, the dislodging of protective frame took place within 10 cycles in all five samples. This result proved that the present invention significantly improved the performance of the solar cell module. Also the results of the example 3 indicate that the eyelets are particularly effective when the external diameter a is equal to or larger than 5 mm. Also the results of the example 4 indicate that the eyelets are particularly effective when the ratio a/b of the external diameter a to the shaft diameter b is equal to or larger than 1.2. As will be apparent from the foregoing, the solar cell modules of the examples 1 - 5, in which the resin-sealed solar cell and the resinous protective frame are fixed by engaging members passing through the penetrating holes provided in these components, is featured by excellent reliability, long service life and increased flexibility, as it is free from dislodging of the protective frame even under an external force. Also secure mechanical strength can be obtained by the use of engaging members which has an external diameter at least equal to 5 mm in a portion exposed from the solar cell module and a ratio of said external diameter to the diameter of a shaft portion passing through the penetrating holes, equal to or larger than 1.2. Also the engaging member can be composed of an eyelet having a penetrating hole therein, whereby said hole can be used for passing strings or support members for fixing the solar cell module. It is therefore rendered possible to simplify the steps of manufacture, and to increase the ratio of the photoelectric conversion area within the solar cell module, thus improving the conversion efficiency per unit area. Number of cycles of repeated tensile force application until dislodging of protective frame from solar cell module. "No change" indicates absence of dislodging after 100 cycles. Sample Example 1 Ref. ex. Example 2 Example 3 Example 4 a = 3 mm a = 5 mm a/b = 1.0 a/b = 1.2 a/b = 1.5 a/b = 1.8 A no change 4 no change 10 no change 7 no change no change no change B no change 2 no change 8 65 12 48 no change no change C no change 1 no change 8 81 4 94 no change no change D no change 6 no change 15 no change - - - - E no change 1 no change 12 no change - - - - [Example 6] Fig. 13 is a schematic cross-sectional view of the principal portion of a solar cell module constituting a 6th example of the present invention. In a laminate member 1 constituting a solar cell module, the light-receiving face (upper face in the drawing) of a solar cell device 2 composed for example of amorphous silicon is covered, across an adhesive material 3, by a sheet-shaped surface protecting material 4 composed of transparent resin, and the bottom (lower) face is also covered, across an adhesive material 3, by a sheet-shaped bottom face protecting material 5. Said coverings are provided by vacuum lamination, whereby the solar cell device 2 is hermetically sealed inside the laminate member 1. Said laminate member 1 is cut, for example, in a rectangular form at positions outside the solar cell device 2, and the cut faces constitute the end faces 1c, 1d of the laminate member 1. The wirings and output terminals of the solar cell device 2 are not illustrated, but said output terminals are extracted from suitable positions on the end faces of the laminate member 1. Frames 6, 7 for example of aluminum, for supporting the laminate member 1, have an identical structure. Therefore, the following explanation will be concentrated on the frame 6 illustrated at the right-hand side. The frame 6 is provided with a slit-shaped groove 6a extending perpendicularly to the plane of drawing, and, on the mutually opposed internal faces 6b, 6c of said groove 6a, there are respectively provided projections 6d, 6e which are in mutually opposed positions and extend continuously from an end of the groove 6a to the other. The width of the groove 6a, or the distance between the internal faces 6b and 6c, is larger than the thickness of the edge portion 1a of the laminate member 1, while the distance between the peaks of the projections 6d and 6e is smaller than said thickness. In a gap between the groove 6a and the edge portion la inserted therein beyond the projections 6e, 6d, there is filled a filler material 6f composed for example of silicone rubber. Within the edge portion la, the surface protecting member 4 and the rear face protecting member 5, coming into contact with the projections 6d, 6e, are localled pressed and distorted by said projections, and the adhesive material 3 sandwiched between said protecting members is also pressed. As a result, the moisture entering from the end face lc of the laminate member 1 into the interior of the edge portion la cannot intrude the interior further beyond said pressed portion. The projections 6d, 6e are preferably formed without pointed end, for example spherically, in order to facilitate the insertion of the edge portion la and in order not to damage the surface protecting material 4 and the rear face protecting material 5 even after prolonged pressing thereon. Said projections 6d, 6e need not necessarily be continuous from an end of the groove 6a to the other, but may be intermittently provided. Said projections 6d, 6e may be formed as separate members and mounted on t-he frame 6. The material of the projections 6d, 6e and/or the frame 6 is not limited to aluminum but can be any other material as long as it can facilitate the insertion of the edge portion 1a and can press the edge portion 1a with a constant pressure over a prolonged period. [Example 7] Fig. 14 is a schematic cross-sectional view of the principal part of a solar cell module, constituting a 7th example of the present invention. The structure of this example is same as that of the example 6, except that the grooves 16a, 17a of the frames 16, 17 are respectively provided with projections 16d, 17d only on an internal face 16b, 17b of each groove. In Fig. 14, components equivalent to those in Fig. 13 are represented by same symbols added by 10. In the following there will be explained an experiment of placing the solar cell modules of the present invention and the conventional solar cell modules under high humidity and measuring the shortcircuit of the solar cell device resulting from moisture intrusion. [Example 8] A solar cell device 2 was prepared by laminating, on a stainless steel substrate, amorphous silicon films of N, I, P, N, I and P types in succession by RF glow discharge, then vacuum evaporating an ITO film as the transparent electrode, and finally printing silver paste as the grid electrodes. 13 units of such device, each 30 x 9 cm, were serially connected. Said stainless steel substrate was composed of SUS430 of a thickness of 0.2 mm, of which surface was annealed at ca. 1100°C in ammonia gas. The above-mentioned lamination of amorphous silicon films was conducted in the following manner. A gas serving as the raw material for example for an N-type amorphous silicon film was introduced into a discharge zone in a chamber in which the substrate was placed in advance, and the discharge was induced by controlling the pressure in the chamber at about 2 Torr and supplying the electrodes of the discharge zone with high-frequency electric power, thereby decomposing said gas and depositing an N-type amorphous silicon film on the substrate. Amorphous silicon films of N, I, P, N, I and P types were deposited in succession on the substrate, by repeating the above-explained procedure. The raw material gases for amorphous silicon film were Si 2 H 6 , H 2 and PH 3 for N-type, Si 2 H 6 and H 2 for I-type, and SiH 4 , H 2 and BF 3 for P-type. The substrate temperature at the deposition of said film was 350°C for N- and I-type, and 300°C for P-type. The vacuum evaporation of said transparent electrode was conducted in the following manner, employing a 50-50 alloy of indium and tin. Oxygen gas was introduced with a pressure of ca. 0.4 Pa (0.003 Torr) into a chamber in which the substrate with laminated amorphous silicon films and a crucible filled with said alloy were placed in advance, and a current was supplied to a tungsten wire wound around said crucible to fuse said alloy, thereby depositing indium tin oxide onto the surface of the amorphous silicon films laminated on the substrate. The substrate temperature was controlled at 225°C. The material of the transparent electrode is not limited to indium tin oxide employed in this example, but may be composed of other materials such as indium oxide. The transparent electrode may also be formed by sputtering, instead of vacuum evaporation. In the following there will be explained the laminate member 1 containing therein the solar cell device 2 thus prepared. The adhesive 3 was composed of sheet-shaped EVA (ethylene-vinyl acetate copolymer) which was relatively easily thermosettable. The surface protecting material 4 was composed of Tefzel (trade name of DuPont de Numeurs, Inc.), sheet-shaped transparent fluorinated resin with a thickness of 100 µm. The rear face protecting member 5 was composed of Tedler (trade name of DuPont de Nemours) which is white fluorinated resin, different from the surface protecting material and covered with aluminum foils on both sides. The rear face protecting material 5, sheet-shaped adhesive 3, solar cell device 2, sheet-shaped adhesive 3 and surface protecting material 4 were superposed in this order, subjected to vacuum lamination in a vacuum laminator at ca. 150°C, and were cut at positions about 2 cm outside the periphery of the solar cell device 2, whereby the laminate member 1 of rectangular shape was obtained. The cut end faces 1c, 1d were not particularly treated. In the following explained are frames 6, 7. For each laminate member 1, there were prepared four frames, each having a pair of mutually opposed projections 6d, 6e, 7d, 7e as shown in the example 6 and matching the thickness and length of the four edge portions 1a, 1b of the laminate member 1. The paired projections formed in the groove of each frame was continuous from an end of said frame to the other, so that, when the edge portions of four sides of the laminate member 1 were inserted in respective frames, said end portions were pressed over the continuous entire periphery by the paired projections on said frames. When the four edge portions of four sides of the laminate member 1 are inserted into the grooves of the frames 6, 7, the ends of neighboring frames were mutually fixed by a screw. The solar cell module of the present invention was prepared by inserting the edge portions 1a, 1b of four sides of the laminate member 1 into the grooves 6a, 7a of the four frames 6, 7, filling the gap between the edge portions and the grooves with silicone rubber filler 6f, 7f, pressing each frame in the portion of the groove thereof from the light-receiving side and from the rear side, connecting the ends of neighboring frames with screws, mounting a waterproof terminal box in a part of the frame at the side of the rear face protecting material 5, positioning the output terminals of the colar cell device extracted from an end face of the laminate member 1 in said terminal box, and leaving thus obtained module for three days for completely drying said filler. At the insertion of said edge portions, it was confirmed that the surface protecting material 4 and the rear face protecting material 5 of the edge portion on each side of the laminate member 1 were recessed by about 0.2 mm by the pressure of the paired projections 6d, 6e, 7d, 7e. 10 units of the solar cell module were prepared in this manner. Separately there were prepared 10 units of the conventional solar cell module, which was identical, in structure and manufacturing process, with the module of the present invention, except that the groove of each frame lacked the paired projections. The solar cell modules of the present invention and the conventional modules, each 10 units, were placed under a high humidity, in a commercial weather testing apparatus, having a chamber of 1.5 x 1.0 x 1.0 m and capable of controlling the relative humidity in said chamber within a range from 0 to 100 %. The solar cell modules of the present invention and the conventional modules, each 10 units, were horizontally placed, with the surface protecting material 4 at the top, in said chamber of the weather testing apparatus, with a mutual spacing of 10 cm. The output terminals of each solar cell device 2 were left open in the waterproof terminal box. In such state, the modules were left for 1000 hours at a temperature of 50°C and a relative humidity of 85 % in said chamber, without light irradiation to the solar cell devices. After standing for 1000 hours, each solar cell module was taken out from the weather testing apparatus, and, after the dews and moisture on the surface were wiped with cloth, the module was subjected to the measurement of electric performance at room temperature, employing a commercial artificial solar light generator, emitting artificial solar light of AM 1.5 global, 100 mW/cm 2 . In 10 conventional modules, a reduction of shunt resistance to 1/10 or lower in comparison with that before standing in high humidity or a shortcircuiting of the entire module was observed in 6 units. On the other hand, in 10 modules of the present invention, a similar shortcircuiting was observed in 1 unit, but the remaining 9 units were intact. The effect of the paired projections 6d, 6e, 7d, 7e was proved in this manner. [Example 9] In this example, in the grooves 6a, 7a of the frames 6, 7 employed in the solar cell modules of the present invention, the mutually opposed projections 6d, 6e, 7d, 7e were formed in intermittent manner, with each continuous length of 10 cm and a spacing of 10 cm. Other conditions were taken same as in the example 8. In the experimental results, in 10 units of the conventional solar cell modules, a reduction of shunt resistance of the solar cell device to 1/10 or lower in comparison with that prior to standing under high humidity or a shortcircuiting of the entire solar cell module was observed in 7 units. On the other hand, in 10 units of the modules of the present invention, a similar reduction of shunt resistance or a shortcircuiting was observed only in 3 units. Thus the effect of the paired projections 6d, 6e, 7d, 7e was proved even when they were formed intermittently. [Example 10] In this example, the conditions were identical with those in the example 8, except that, in the groove of each frame 16 or 17 shown in Fig. 14, a projection 16d or 17d is formed continuously only on the upper internal face 16b or 17b. In the experimental results, in 10 units of the conventional solar cell modules, a reduction of shunt resistance of the solar cell device to 1/10 or lower in comparison with that prior to standing under high humidity or a shortcircuiting of the entire solar cell module was observed in 7 units. On the other hand, in the modules of the present invention, such reduction of shunt resistance or shortcircuiting was observed only in 4 units. Thus the effect of the projection was proved even when it was formed only on one internal face of the groove of the frame. In the above-explained examples 6 to 10, a groove or grooves formed on the internal faces of the groove of the frame locally press a contact area of the edge portion of the laminate member, inserted into said groove, thereby preventing the intrusion of the moisture, entering said edge portion from the end face thereof, into the interior beyond said pressed area, and thus improving the resistance against moisture intrusion into the interior of the laminate member. As a result, the breakdown of the solar cell device resulting from such moisture intrusion can also be prevented. In the following there will be explained the method of installation of the solar cell module shown in the foregoing examples 1 - 10. The colar cell is usually installed on a rack fixed on the ground or on the rood of a building, or adhered on the wall of a building. In case of installation on the roof, the solar cell may also be integrated with the roofing material and placed on the roof without the rack. As an example of such method, a solar cell device sealed in resin sheets or EVA is adhered with an adhesive material, to a rear face protecting metal plate. The end portions of said protecting metal plate are folded upwards to form sealing portions for said solar cell, then a plurality of such sealing portions are adhered to the roof surface, and a batten-seam is placed over the end portions, parallel to the slanting direction of the roof, for protecting the seal portions of the solar cells and the end faces of the protecting metal plates. This method has an advantage of dispensing with the cost for rack, in comparison with the installation with a rack on the roof . The conventional solar cell modules, particularly those in which the solar cell device is vacuum laminated in surface protecting materials consisting of sheet-shaped transparent resin, are usually trimmed to a predetermined shape by cutting the surface protecting material, adhesive material and rear face protecting material at positions outside the solar cell device. It is therefore necessary to suitably treat the end portions formed by such cutting, in order to protect the internally sealed solar cell device and electric circuits from the stress, water and moisture (vapor) coming out from the ambient conditions. In case the seal portion of the solar cell is adhered, with an adhesive material, to a rear face protecting metal plate, the end face of said seal portion may be treated in the following manner, as the aforementioned frame is absent in this case. There was firstly conceived a method of protecting the end portion by covering with an adhesive material or a filler such as silicone rubber, prior to the adhesion of the seal portion of solar cell to the rear face protecting metal plate. However, the surface protecting material of said seal portion, enclosing a solar cell device employing a conductive substrate such as a stainless steel substrate, is often composed of fluorinated resin or the like, for which effective adhesive or filler is scarcely known. The fluorinated resin is used for such surface protecting material because of high light transmittance and high durability to stress caused by the ambient conditions. The fluorinated resin also provides low dust deposition and high water repellent property, required for the surface protecting material, but this fact also signifies the absence of a suitable adhesive therefor. Since the fluorinated resin and EVA cannot be adhered satisfactorily, the adhesion is often improved by applying corona discharge to the entire adhered surface of the fluorinated resin. However, the corona discharge, if applied to the entire top surface of the fluorinated resin, will deteriorate the dust and water repellent properties mentioned above. Also such corona discharge, if applied only to the end portion, will require an increased precision of the sealing operation and elevate the process cost. Another conceivable method consists of heating the end portion, thereby fusing and expelling the adhesive material, such as EVA, from the seal portion, and thermally adhering the surface protecting resin material and the rear face protecting resin material under pressure, prior to the adhesion of the seal portion of the solar cell to the rear face protecting metal plate. However, such thermal adhesion, experimented by the present inventors at various temperatures, has not provided sufficient adhesion strength. As explained in the foregoing, various difficulties arise in the treatment of end portion, in case the seal portion of the solar cell is to be adhered to the rear face protecting metal plate. In consideration of the foregoing, another object of the present invention, differrent from those of the foregoing examples 1 - 10, in a solar cell module which includes plural seal portions of solar cells each at least including a solar cell device and a rear face protecting metal plate serving as a support member, and a batten-seam member for protecting vertically positioned ones among the neighboring end portions of said rear face protecting metal plates when they are installed on the roof, wherein said seal portions are integrated with the roofing material, is to prevent the deformation or destruction of said end portions of seal portion by external stress or the intrusion of water vapor from said end portions to the solar cell device, thereby avoiding failure of the solar cell device or shortcircuiting of internal wirings caused by such intruding water vapor. The above-mentioned object can be achieved, according to the present invention, by a solar cell module which includes plural seal portions of solar cells each at least including a solar cell device and a rear face protecting metal plate, and a batten-seam member for protecting vertically positioned ones among the neighboring end portions of said rear face protecting metal plates when they are installed on the roof and in which said seal portions are integrated with the roofing material, wherein said rear face protecting metal plate is provided, at the end portions thereof, with slit-shaped grooves formed by folding said metal plate. The solar cell module of such structure allows to prevent deformation or destruction of the end portions of said solar cell seal portion by external stress and intrusion of water vapor from said end portions to the solar cell device, thereby avoiding failure of said device or shortcircuiting of internal wirings caused by such intruding water vapor. [Example 11] Fig. 15 is a schematic cross-sectional view of an amorphous solar cell module, best representing the feature of the present example. There are illustrated an amorphous solar cell device 31; a rear face protecting metal plate 32; an adhesive layer 33; a surface protecting material 34; a rear face protecting material 35; filler 36; a batten-seam member 37; and a slit-shaped groove 38 formed by folding said metal plate. The solar light hν enters the module from above. The amorphous solar cell device 31 is composed, for example, of a serial connection of the devices each formed, on a stainless steel substrate, by laminating amorphous silicon films of N, I, P, N, I and P types in succession by RF glow discharge, then evaporating indium tin oxide as a transparent electrode, and finally printing silver paste as grid electrodes. The solar cell module of this example is formed by inserting the seal portion of the solar cell into the slit-shaped groove 38, formed by folding the protecting metal plate 32 at the end portion thereof. In Fig. 15, the wirings and output terminals of the solar cell device are omitted. The form and dimension of said slit-shaped groove 38 are preferably so selected that said groove does not induce deformation nor damage on the end portion of seal portion at the insertion thereof or after a prolonged inserted state and that suitable filler 36 can be easily filled into the gap between the groove 38 and the end portion. As an example, the groove 38 is formed deeper, as shown in Fig. 15, than the inserted length of the end portion thereby leaving a gap for filling with the filler, but such configuration is not limitative. Also said groove 38 is preferably formed without interruption over the entire length of longer and shorter sides of the end portions of solar cell seal portion. The rear face protecting metal plate 32 is preferably composed of a material which is so surface treated as to have sufficient durability required for the roofing material against ambient conditions and allows easy formation of the slit-shaped groove 38 by folding. An example of such material is galvanized steel plate, but such example is not limitative. A non-limitative example of the adhesive layer 33 is EVA. Also a non-limitative example of the surface protecting material 34 is fluorinated resin. In this example, the sealing is achieved by vacuum lamination of sheet-shaped fluorinated resin, but the surface protecting material 34 may also be formed, for example, by coating liquid fluorinated resin. The rear face protecting material 35 is composed of a material capable of electrically insulating the solar cell device from the rear face protecting metal plate 32. A non-limitative example of such material is sheet-shaped nylon. Non-limitative examples of the filler 36 are silicone rubber and butyl rubber. Sealing is achieved in accordance with the invention by forming a projection 38b in the groove 38, as in the foregoing examples 6 - 10 (see (A) in Fig. 15). Also penetrating holes may be provided in the protecting materials 34, 35 as in the examples 1 - 5. In the present example, the solar cell module prepared by vacuum lamination of the amorphous silicon solar cell device 31 with the surface protecting material 34, rear face protecting material 35 and adhesive layer 33 was left in a high humidity condition, and was subjected to the investigation of frequency of failures such as peeling of end portions of the solar cell seal portion, and failure of the solar cell device and shortcircuiting of entire module caused by water vapor intrusion. The amorphous solar cell 31 employed in this example was prepared, on a stainless steel substrate, by laminating amorphous silicon films of N, I, P, N, I and P types in succession by RF glow discharge method, then evaporating indium tin oxide as the transparent electrode, and printing silver paste as current-collecting grid electrode, and 13 units of such cell, each ca. 30 x 9 cm, were connected serially. The adhesive layer 3 consisted of sheet-shaped EVA, while the surface protecting material 4 consisted of sheet-shaped Tefzel of a thickness of 100 µm, and the rear face protecting material 5 consisted of a sheet in which an aluminum foil was sandwiched between white Tedler sheets. The above-mentioned materials were superposed in succession, from the bottom, in the order of the rear face protecting material 35, adhesive layer 33, amorphous silicon solar cell device 31, adhesive layer 33 and surface protecting material 34, and were laminated at 100°C in a vacuum laminator. The obtained laminate member was cut into a rectangular form at positions 2 cm outside the external periphery of the solar cell device. The cut faces were not particularly treated. The rear face protecting metal plate 32, consisting of a galvanized steel plate of a thickness of ca. 0.3 mm and having weather resistant treatment on one side thereof, was cut into a size of 1.5 x 0.45 m and folded in the following manner. At first the mutually opposed longer sides of the steel plate were folded over the entire width to form slit-shaped grooves 38 of a width of ca. 4 mm and a depth of 1 cm as shown in Fig. 15. Then each end portion of about 4 cm was folded upwards, and finally each end portion of about 1 cm was folded diagonally downwards. Fig. 17 is a schematic view showing the final form of the solar cell modules of the present invention, wherein shown are solar cells 2001 each including a photovoltaic device covered with convering materials; a support member 2003 therefor, provided at the ends thereof with slits for accommodating the end of the solar cells 2001; and protective members 2002 covering the ends of the support member for neighboring two solar cells. These members are constructed as already explained in the examples 1 - 11. As explained above, the solar cell is provided with a photovoltaic device, covering material for covering the photovoltaic device, and a frame for covering the end portions of the covering materials. The covering materials are provided, in the end portions thereof, with a recess or a penetrating hole. The frame is provided with a projection adapted to engage with the recess or penetrating hole.

Claims: A solar cell provided with a photovoltaic device (105; 31; 12, 2), covering material (110; 3, 4; 13, 14; 33, 34) in which said photovoltaic device is sealed, and a frame (102; 6; 16, 38) in which the end portions of said covering material are inserted; wherein said covering material is provided, in the end portions thereof, with a recess or a penetrating hole, and said frame is provided with a projection (104; 103; 6d; 6e; 16d; 38b) engaging with said recess or penetrating hole. A solar cell according to claim 1, wherein said projection is composed of an engaging member (104; 103) which passes through a penetrating hole provided in said frame (102) and engages with said penetrating hole of the end portions of said covering materials (110). A solar cell according to claim 2, wherein said engaging member (104; 103) has an external diameter a equal to or larger than 5 mm in an externally exposed portion, and has a ratio a / b of said external diameter a to a shaft diameter b in said penetrating hole equal to or larger than 1.2. A solar cell according to claim 2, wherein said engaging member (103) is composed of an eyelet having a penetrating hole in the center. A solar cell according to claim 1, wherein said projectin (6d, 6e, 16d, 38b) is provided integrally with a groove (6a, 16a, 38) of said frame (6,16) for accomodating the end portions (1c,11c) of said covering materials (3,4,13,14,33,34), and the width of said groove is larger than the thickness of the end portions of said covering materials. A solar cell according to claim 1, wherein a plurality of projections (6d,6e,7d,7e) is provided, in mutually opposed relationship in a groove (6a,7a) of said frame (6,7). A solar cell according to claim 1, wherein the thickness of a portion containing said photovoltaic device (105; 31; 12, 2) is smaller than that of the end portions of said covering materials (33, 34), and the thickness of said covering materials in a portion engaging with said projections is smaller than said thickness of the end portions of said covering materials. A solar cell according to claim 1, wherein said photovoltaic device (105; 31; 12, 2) includes a non-monocrystalline semiconductor layer. A solar cell according to claim 1, wherein said photovoltaic device (105; 31; 12, 2) includes an amorphous silicon layer. A solar cell according to claim 1, wherein said photovoltaic device is provided in plural units, which are serially connected. A solar cell according to claim 1, wherein said frame (38) is composed of a deformable plate-shaped member (32) of which end portions are so folded as to form a slot (38) for accomodating the end portions of said covering material, and said slot (38) is provided with said projection (38b) adapted to engage with a recess provided in said covering material (33, 34).

Inventors: INOUE YUJI, YAMAMOTO HIROSHI, INOUE, YUJI, YAMAMOTO, HIROSHI, Inoue, Yuji, c/o Canon Kabushiki Kaisha, Yamamoto, Hiroshi, c/o Canon Kabushiki Kaisha
Applicants: CANON KK, CANON KABUSHIKI KAISHA
Application year: 1992
Main classification: H01L31
IPC codes: H01L31