Process for the preparation of sodium chloride

Abstract: In a purification process for brine, impurities such as calcium, magnesium and/or sulphate are precipitated by the addition of calcium hydroxide (Ca(OH)₂) and sodium carbonate (Na₂CO₃). Following NaCl crystallisation by evaporation of the brine, a mother liquor is obtained which still contains among others sulphate, potassium and bromide ions. Further concentration of this motherliquor by evaporation results in the precipitation of both NaCl and Na₂SO₄ and a more strongly concentrated motherliquor with respect to both potassium and bromide remains. This concentrated motherliquor is drained off. Either the prcipitated naCl and Na₂SO₄ are dissolved in water or the Na₂SO₄ is dissolved in purified brine or crude brine and then returned to the brine purification process, thereby lowering both the potassium and bromide ion levels in the purified brine. As a consequence the contents of both potassium and bromide of the NaCl are reduced.

Description: The invention relates to a process for the preparation of sodium chloride comprising the purification of crude brine by precipitating and separating calcium and magnesium in the form of insoluble compounds, followed by evaporating water from the obtained purified brine and separating the sodium chloride crystallised in the process, followed by returning the sodium sulphate present in the mother liquor to the crude brine. A process of the above type is disclosed in US-A-2 764 472 and FR-A-2 538 263. In the US patent specification a process is described in which mother liquor containing sodium sulphate is returned to the crude brine. A drawback to this process is that it gives high-level concentrations of ions such as K + and Br - in the solutions undergoing the various treatments, and that because these ions have a tendency to be built into the crystal lattice of NaCl in the course of its crystallisation, the desired product NaCl will have relatively high potassium and bromide contents as a consequence. In the process disclosed in FR-A-2 538 263 the mother liquor, which contains the residual NaCl and the proportion of KCl and Na 2 SO 4 remaining in the solution during the evaporation, is withdrawn at an elevated temperature which corresponds to the processing temperature of the evaporation. It is then cooled in a cooler, preferably by flash evaporation, with the NaCl/KCl/Na 2 SO 4 -salt mixture being separated off by crystallisation and the mother liquor still containing residual amounts of those salts being returned to the crude brine. Said salt mixture is then carried to a deposition section, where through the addition of refrigerated water KCl and, particularly, NaCl are again dissolved and Na 2 SO 4 remains as residue in the range of the Glauber's salt phase and is separated off, whereas the parent solution containing the dissolved NaCl and KCl components is returned to the crude brine. A drawback to this known process consists in that the mother liquor is crystallised to such an extent that a complex salt mixture consisting of NaCl/KCl/Na 2 SO 4 is obtained, and that a parent solution containing not only the above salts but also a relatively high percentage of potassium and bromide ions is returned to the crude brine. The present invention provides a process which largely obviates the aforementioned drawbacks. The invention consists in that in a process of the type mentioned in the opening paragraph the sodium sulphate is crystallised by the evaporation of water without exceeding the solubility limit of the double salt K 3 Na(SO 4 ) 2 and separated from the mother liquor before it is returned to the crude brine. Surprisingly, it was found that by stopping the crystallisation process of NaCl and Na 2 SO 4 before a substantial amount of a complex salt mixture of NaCl/KCl/Na 2 SO 4 is formed, the solid salt mixture comprising the major part of the sodium sulphate may be returned to the crude brine. This is in sharp contrast with the known processes, where it is the mother liquor which is returned to the crude brine, optionally after purification. In the process of the present invention the concentrated mother liquor, which contains potassium and bromide ions, is drained off. In this manner the accumulation of potassium and bromide will be obviated, and at the same time a relatively pure Na 2 SO 4 /NaCl-salt mixture is obtained, which can be recycled to the crude brine. This process enables the extraction from crude brine of a very pure NaCl. The NaCl salt to be obtained by this process has a very low bromine content and so has been rendered suitable for use in a wide range of applications. Crude brine serves as raw material for the process according to the present invention. Crude brine contains, in addition to Na + and Cl - , a great many other ions, e.g. those of calcium, magnesium, sulphate, potassium, and bromide. To remove calcium and magnesium ions from the brine sodium carbonate and calcium hydroxide may be added to form calcium carbonate and magnesium hydroxide, respectively, which are subsequently removed. However, it is also possible for calcium ions to be precipitated and removed in another effective manner by adding sulphate ions to form insoluble calcium sulphate. The brine from which the calcium and magnesium have been removed is referred to hereinafter as purified brine. Next, water is evaporated from the purified brine to the extent of NaCl crystallising, but without the Na 2 SO 4 solubility limit being exceeded, this to prevent the NaCl to be crystallised from being contaminated with sulphate. After the crystallised NaCl has been removed, mother liquor is left. If so desired, part of the mother liquor can be returned to the brine purification step to regulate the quality of the sodium chloride product. From the mother liquor not so returned further water is evaporated. In this evaporation step the Na 2 SO 4 solubility limit is exceeded and there is crystallisation of Na 2 SO 4 as well as of the NaCl still present in the mother liquor. As the mother liquor is concentrated further, the dissolved impurities' contents become higher. The evaporation can be continued until the solubility limit of the double salt K 3 Na(SO 4 ) 2 is reached. Exceeding this solubility limit might result in reduction of the yield of pure NaCl. The sodium sulphate crystals are separated from the liquid together with sodium chloride crystals. The remaining liquid obtained in this manner, which is referred to as "concentrated mother liquor" hereinafter, has a small volume but contains a high concentration of dissolved impurities. This concentrated mother liquor is removed from the process cycle. The water may be evaporated from the mother liquor at any temperature conventionally used for the evaporation of purified brine. Such a temperature is in the range of 35° to 160°C. In order to attain the highest possible use of sulphate in the precipitation of gypsum, the Na 2 SO 4 obtained during the evaporation of the mother liquor should preferably be returned to the cycle in the dissolved form. Practically, this can be effected in at least three ways. 1. The obtained Na 2 SO 4 and NaCl crystal mixture is dissolved in water. The resulting solution is fed to the brine purification process. 2. The obtained Na 2 SO 4 and NaCl crystal mixture is suspended in such an amount of purified brine that all of the Na 2 SO 4 is dissolved in it. Obtained in that case is a solution saturated with NaCl and having an Na 2 SO 4 content which, at most, equals the Na 2 SO 4 's solubility. Since, generally, the NaCl content of the purified brine is not very much lower than the NaCl solubility, only a minor portion of the NaCl crystals is dissolved in this process. After the remaining NaCl crystals have been separated as product, the resulting solution is fed to the brine purification process. This process is preferred, as it does not involve adding water to the cycle which later has to be evaporated and so does not bring about an extra increase in energy consumption. 3. The obtained Na 2 SO 4 and NaCl crystal mixture is suspended in such an amount of crude brine that all of the Na 2 SO 4 can be dissolved in it. Obtained then is a solution saturated with NaCl and having an Na 2 SO 4 content which, at most, equals the Na 2 SO 4 's solubility. Since the NaCl content of the purified brine often is not very much lower than the NaCl solubility, only a minor portion of the NaCl crystals is dissolved in this process. After the remaining NaCl crystals have been separated as product the resulting solution is fed to the brine purification process. Preferably, the amount of crude brine to which the mixture of NaCl and Na 2 SO 4 is added is chosen such that the brine's sulphate content after complete dissolving of the Na 2 SO 4 at room temperature does not exceed 0,22 gram-ion/litre. It was found that this will substantially accelerate the Na 2 SO 4 crystal's dissolving in the brine. According to a preferred embodiment, the product of the Ca 2+ ion content and the sulphate content of the brine after complete dissolution of the Na 2 SO 4 at room temperature does not exceed 7,5 x 10 -3 (gram-ion/litre) 2 . It was found that this will substantially extend the period of time before gypsum precipitates. Thus, it is possible to separate the NaCl crystals before the precipitation of CaSO 4 .2H 2 O, so preventing contamination of the NaCl crystals with said compound. The NaCl produced according to the now found process is highly suitable especially for the production of chlorine. On account of its very low bromine content this chlorine is particularly suited to be used in the production of chlorine derivatives. The invention will be further illustrated by the following figures and examples. These figures and examples are not to be construed as limiting in any manner the scope thereof. Figure 1 is a schematic depiction of a flow chart for the above-disclosed novel process. Crude brine (1) and a mixture containing Na 2 SO 4 and NaCl crystals (13) are fed to a dissolver (A), where the Na 2 SO 4 crystals are dissolved in the crude brine. The NaCl crystals (2) are removed from the dissolver (A), the crude brine enriched with Na 2 SO 4 (3) is passed from the dissolver (A) into one or more vessels (B), in which the crude brine is purified. As various compounds (4) are added, impuritities (5) precipitate and are separated and removed from (B). Purified brine (6) is fed to a brine evaporator (C). In the brine evaporator water (7) evaporates, while NaCl (8) crystallises and after separation is removed from the brine evaporator. If desired, part of the mother liquor (9) is returned to (B). The remaining mother liquor (10) is fed to a mother liquor evaporator (D). In the mother liquor evaporator (D) water (11) evaporates, while Na 2 SO 4 and NaCl (13) crystallise and are returned to the dissolver (A). The concentrated mother liquor (12) is drained off from the mother liquor evaporator (D). Figure 2 is a schematic depiction of a flow chart for another embodiment of the invention. This embodiment differs from the previous one essentially in that the sodium sulphate is dissolved in purified brine before being returned to the crude brine. Crude brine (14) and Na 2 SO 4 dissolved in purified brine (26) are fed to one or more vessels (E), in which the crude brine is purified. As various compounds (15) are added, impurities (16) precipitate and are separated and removed from (E). Part of the purified brine (17) is fed to a dissolver (H). The remaining purified brine (18) is fed to a brine evaporator (F). In the brine evaporator (F) water (19) evaporates, while NaCl (20) crystallises and after separation is removed from the brine evaporator (F). If desired, part of the mother liquor (21) is returned to (E). The remaining mother liquor (22) is fed to a mother liquor evaporator (G). In the mother liquor evaporator (G) water (23) evaporates, while Na 2 SO 4 and NaCl (24) crystallise and after separation are fed to the dissolver (H). The Na 2 SO 4 is dissolved in purified brine (17). The NaCl crystals (25) are removed from the dissolver (H). The concentrated mother liquor (27) is drained from the evaporator (G). Example 1 An example of the quantities employed in the process of the present invention is given below. According to the process depicted in Figure 1, 3,374 m 3 of crude brine (1) containing 17706 moles of chloride ions, 156,9 moles of sulphate ions, 116,4 moles of calcium ions, 8,4 moles of magnesium ions, 40,5 moles of potassium ions, 1,2 moles of bromide ions, and the balance being made up of sodium ions, are added to the dissolver (A) together with 1744 moles of NaCl, 0,4 moles of potassium, 0,1 mole of bromide, and 168,5 moles of sodium sulphate. 102 kg of salt (2) containing 1744 moles of NaCl, 0,4 moles of potassium and 0,1 mole of bromide are separated and removed from (A). The crude brine enriched with Na 2 SO 4 (3) is fed to vessel (B), to which are also added 19,9 moles of Na 2 CO 3 , 69,1 moles of Ca(OH) 2 , and 59,2 moles of CO 2 (4), as well as 1,362 m 3 of mother liquor (9) from brine evaporator (C) containing 6991 moles of chloride ions, 637,4 moles of sulphate ions, 12,4 moles of carbonate, 8,8 moles of hydroxide ions, 118 moles of potassium ions, 2,9 moles of bromide ions, the balance being made up of sodium ions. Separated and removed from (B) are 110,6 moles of CaSO 4 .2H 2 O, 74,9 moles of CaCO 3 , and 8,4 moles of Mg(OH) 2 . The brine so purified (6), comprising 24697 moles of chloride ions, 852,2 moles of sulphate ions, 16,6 moles of carbonate ions, 11,8 moles of hy d roxide ions, 158,5 moles of potassium ions, 4,1 moles of bromide ions, and the balance being made up of sodium ions, is fed to a brine evaporator (C). Water is removed by evaporation (7), whereupon 898 kg of salt containing 15 350 moles of NaCl, 0,8 moles of potassium ions, and 0,2 moles of bromide ions crystallise and are removed (8). Part of the mother liquor resulting from this evaporation is fed to vessel(s) (B) (9). The remaining mother liquor so obtained (10), containing 2356 moles of chloride ions, 214,8 moles of sulphate ions, 4,2 moles of carbonate ions, 3,0 moles of hydroxide ions, 39,7 moles of potassium ions, 1 mole of bromide ions, the balance being made up of sodium ions, is fed to evaporator (D), in which water is evaporated (11). Whereas the crystallised NaCl, Na 2 SO 4 , potassium, and bromide (13) are added to the crude brine (A), 0,105 m 3 of concentrated mother liquor (12) containing 612 moles of chloride ions, 46,3 moles of sulphate ions, 4,2 moles of carbonate ions, 3,0 moles of hydroxide ions, 39,3 moles of potassium ions, 0,9 moles of bromide ions, the balance being made up of sodium ions, are drained off from evaporator (D). It is clear from this example that the salt product obtained (8) has a very low bromide and potassium content. Comparative Example A flow chart for a process for the preparation of NaCl according to the prior art is depicted schematically in Figure 3. An example of the quantities employed in the process according to the prior art is given below. 3,365 m 3 of crude brine (27) containing 17659 moles of chloride ions, 156,5 moles of sulphate ions, 116,1 moles of calcium ions, 8,4 moles of magnesium ions, 40,4 moles of potassium ions, 1,2 moles of bromide ions, and the balance being made up of sodium ions, are fed, together with 1,814 m 3 of mother liquor (34) containing 9490 moles of chloride ions, 879,8 moles of sulphate ions, 17,1 moles of carbonate ions, 12,2 moles of hy d roxide ions, 621,5 moles of potassium ions, 9,8 moles of bromide ions, and the balance being made up of sodium ions, to a vessel (I) in which the crude brine is to be purified. As 73,5 moles of calcium hydroxide, 21,8 moles of sodium carbonate, and 64,7 moles of carbon dioxide (28) are added, 104,1 moles of gypsum, 85,5 moles of calcium carbonate, and 8,4 moles of magnesium hydroxide (29) precipitate and are removed from (I). Purified brine (30) comprising 27149 moles of chloride ions, 932,2 moles of sulphate ions, 18,1 moles of carbonate ions, 12,9 moles of hydroxide ions, 661,9 moles of potassium ions, 11,0 moles of bromide ions and the balance being made up of sodium ions, is fed to a brine evaporator (J). In the brine evaporator (J) water (31) evaporates, while 1000 kg of salt (32) containing 17094 moles of NaCl, 3,4 moles of potassium, and 0,6 moles of bromide crystallise and are removed from the brine evaporator (J). Drained off from the brine evaporator (J) are 0,108 m 3 of the mother liquor (33) containing 565 moles of chloride ions, 52,4 moles of sulphate ions, 1,0 mole of carbonate ions, 0,7 moles of hydroxide ions, 37,0 moles of potassium ions, 0,6 moles of bromide ions, and the balance being made up of sodium ions. The remaining mother liquor (34) is returned to (I). The Comparative Example shows that the bromide content of the salt thus obtained (32) is over 2,5 times as high as that of the salt (8) obtained by the process of the present invention. It was found impossible to remove the potassium and bromide impurities by washing the obtained salt.

Claims: A process for the preparation of sodium chloride comprising the purification of crude brine by precipitating and separating calcium and magnesium in the form of insoluble compounds, followed by evaporating water from the obtained purified brine and separating the sodium chloride crystallised in the process, followed by returning sodium sulfate present in the mother liquor to the crude brine, characterised in that the sodium sulfate is crystallised by the evaporation of water without exceeding the solubility limit of the double salt K 3 Na(SO 4 ) 2 and separated from the concentrated mother liquor before it is returned to the crude brine. A process according to claim 1, characterised in that the crystallised sodium sulfate is dissolved in water or an aqueous solution before adding it to the crude brine to be purified. A process according to claim 2, characterised in that the crystallised sodium sulfate is dissolved in purified brine. A process according to claim 2, characterised in that the crystallised sodium sulfate is dissolved in crude brine to be purified and that the sulfate ion content of the crude brine after addition of the sodium sulfate does not exceed 0,22 gram-ion/litre. A process according to claim 4, characterised in that the product of the calcium ion content and the sulfate ion content of the brine after complete dissolution of the sodium sulfate does not exceed 7,5 x 10 -3 (gram-ion/litre) 2 .

Inventors: JONGEMA PIETER, JONGEMA, PIETER
Applicants: AKZO NOBEL NV, AKZO NOBEL N.V.
Application year: 1991
Main classification: C01D3
IPC codes: C01D3, C01D5