One-pack type epoxide composition

Abstract: A one-pack type epoxide composition which has excellent storage stability and which can be rapidly cured at relatively low temperature is provided. It comprises as effective components (A) at least one epoxide having more than one, preferably more than 1.5 epoxy groups per a molecule, and (B) a curing agent prepared by heating and reacting (a) at least one N,N-dialkylaminoalkylamine, (b) at least one amine having one or two nitrogen atoms with active hydrogen and having a ring structure in its molecule, (c) at least one diisocyanate, or (C) a curing agent prepared by heating and reacting (a) at least one N,N-dialkylaminoalkylamine, (b) at least one amine having one or two nitrogen atoms with active hydrogen and having a ring structure in its molecule, (d) at least one epoxide having one or more epoxy groups in a molecule, and (c) at least one diisocyanate.

Description: Background of the Invention Field of the Invention The present invention relates to a one-pack type epoxide composition. Epoxides having more than one epoxy groups in their molecule, when combined and mixed with various curing agents, may be cured at ambient temperature or elevated temperature. Since the cured epoxides have excellent adhesion to various materials, they have been used in variety of fields of application such as adhesives and coatings, and in injection, dipping, casting and potting. The present invention is to provide, in the fields relating to epoxides, epoxide compositions which can be easily handled and have excellent curable characteristics. More concretely, the present invention is to provide one-pack type heat-curable epoxide compositions which have excellent storage stability and can be cured in a short period of time at relatively low temperature. Description of the Prior Art Most of the conventionally used epoxide compositions are of two-pack type, and they have to be used immediately after mixing an epoxide and a curing agent or a curing accelerator. Although two-pack type epoxide compositions may be cured at room temperature or at low temperature, they have to be precisely weighed and mixed just prior to use. When wrong amounts are weighed relative to the correct amounts of the epoxide and the curing agent, or subsequent mixing is not sufficient even if correct amounts are weighed, there is a problem that the performance of the cured material is insufficient. Also, limited pot life of conventional two-pack type epoxide compositions makes their adaptability to automated machines difficult. Thus, it is desired to produce one-pack type heat-curable epoxide compositions to eliminate these drawbacks. One-pack type heat -curable epoxide compositions need a latent-type curing agent which has a property of not reacting with an epoxide at room temperature but starting reaction to cure upon heating. Some latent-type curing agents have been proposed so far, and typically, there may be mentioned dicyandiamide, dibasic acid dihydrazides, boron trifluoride amine complex salts, guanamines, melamine and imidazoles. Although, mixtures of dicyandiamide, melamine or a guanamine with an epoxide are excellent in storage stability, they have a drawback of necessitating a curing condition at high temperature above 150 °C for a long period of time. Although, it has been widely done to shorten the curing time by the use of a curing accelerator, this accompanies a drawback that storage stability is extremely damaged. Also, dibasic acid dihydrazides and imidazoles have poor storage stability even though they cure the epoxide at relatively low temperature. Boron trifluoride amine complex salts have advantages of excellent storage stability and short curing time. But the cured materials have poor resistance to water and cause corrosion of metals. Thus, each of curing agents has a drawback. Under such circumstances, it has been desired to develop an epoxide composition which has excellent storage stability, can be cured at low temperature in a short period of time, and yet exhibits good performance when cured. To eliminate the drawback, it has been proposed to use as a curing agent for polyepoxides a reaction product between a dialkylamine and an epoxide in Japanese Unexamined Patent Publications Sho 56-155222 and Sho 57-100127 and a reaction product between an alcohol or phenol having a tertiary amino group and a polyepoxide in Sho 59-53526. However, these synthesized curing agents actually did not have good storage stability, and the performance of the cured material was not satisfactory. Japanese Unexamined Patent Publication Hei 1-254731 discloses that a curing agent prepared by heating and reacting N,N-dialkylaminoalkylamine, an amine having two amino groups and urea is effective as a latent type curing agent. The synthesis of this curing agent is based on a reaction wherein ammonia is removed from the amino-containing substance and urea. Thus, a large amount is lost as ammonia during this reaction and this process is economically disadvantageous because the yield of the objective material is low. It is desired to solve this problem and there is need to develop a synthesis method in which there is no volatile component during the reaction. Thus, it is an object of the present invention to provide a latent type curing agent which is economically advantageous and which, when mixed with an epoxide, provides an epoxide composition that can be cured in a short period of time at relatively low temperature, i.e. from 80 to 120°C while maintaining good storage stability. Summary of the Invention The present invention relates to one-pack type heat-curable epoxide compositions which comprise as effective components (A) at least one epoxide having more than one epoxy group in a molecule, and (C) a curing agent which is the reaction product of (a) at least one N,N-dialkylaminoalkylamine represented by the general formula wherein R is an alkyl group of 1 to 4 carbon atoms, and n is 2 or 3; (b) at least one amine having one or two nitrogen atoms with active hydrogen and having a ring structure in its molecule; (c) at least one diisocyanate; and (d) at least one epoxide having more than one epoxy group in the molecule, wherein: the molar ratio of (b) to a mole of (a) is 0.5 mole ≤ (b) ≤ 5.0 moles; the ratio of (c) is such that the chemical equivalent of diisocyanate in (c) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 0.15 chemical equivalents ≤ 1 chemical equivalent diisocyanate ≤ 1.35 chemical equivalents; the ratio of (d) is such that the chemical equivalent of epoxide in (d) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 0.3 chemical equivalents ≤ 1 chemical equivalent epoxide ≤ 0.9 chemical equivalents; and the sum of the chemical equivalent of diisocyanate in (c) and the chemical equivalent of epoxide in (d) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 1.0 chemical equivalent ≤ sum of chemical equivalents of diisocyanate and epoxide ≤ 1.8 chemical equivalents; and wherein the reaction order of said addition reaction is such that a reaction is carried out at 60 to 120°C between a part of or all of (b) and epoxide (d) having more than one epoxy groups in a molecule, then (a), the rest of (b) and (c) are added to the reaction mixture, and the reactants are heated and reacted at room temperature to 160°C. More particularly, it relates to one-pack type heat-curable epoxide compositions which have excellent storage stability and can be rapidly cured at relatively low temperature. Detailed Description of the Invention The epoxide which is one of the essential components of the present invention has more than one, preferably more than 1.5 epoxy groups per a molecule and includes, for example, glycidyl ethers obtained by reacting epichlorohydrin with a polyhydric phenol such as bisphenol A, bisphenol F, bisphenol S, hexahydrobisphenol A, tetramethylbisphenol A, catechol, resorcinol, cresol, novolak, tetrabromobisphenol A, trihydroxybiphenyl, benzophenone, bis-resorcinol, bisphenol hexafluoroacetone, hydroquinone, tetramethylbisphenol A, tetramethylbisphenol F, triphenylmethane, tetraphenylethane and bixylenol; polyglycidyl ethers obtained by reacting epichlorohydrin with an aliphatic polyhydric alcohol such as glycerin, neopentyl glycol, ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol; glycidyl ether esters obtained by reacting epichlorohydrin with a hydroxycarboxylic acid such as p-hydroxybenzoic acid, beta-hydroxynaphthalene carboxylic acid; polyglycidyl esters obtained from a polycarboxylic acid such as phthalic, methylphthalic, isophthalic, telephthalic, tetrahydrophthalic, hexahydrophthalic, endomethylenetetrahydrophthalic, endomethylenehexahydrophthalic, trimellitic, and polymerized fatty acid; glycidylaminoglycidyl ethers obtained from aminophenol or aminoalkylphenol; glycidylaminoglycidyl ester obtained from aminobenzoic acid; glycidylamines obtained from aniline, toluidine, tribromoaniline, xylylenediamine, diaminocyclohexane, bisaminomethylcyclohexane, 4,4'-diaminodiphenylmethane, 4,4'-diaminodiphenyl sulfone or the like; and mono-epoxy compounds exemplified by epoxypolyolefin, glycidylhydantoin, glycidylalkylhydantoin, triglycidyl cyanulate, butylglycidyl ether, phenylglycidyl ether, alkylphenylglycidyl ether, glycidyl ester of benzoic acid, stylene oxide and the like; as well as mixtures of one or more of these compounds. The other essential component of the present invention, the curing agent may be obtained by reacting (a) at least one N,N-dialkylaminoalkylamine, (b) at least one amine having one or two nitrogen atoms with active hydrogen and having a ring structure in its molecule, (d) at least one epoxide having one or more epoxy groups in a molecule, and (c) at least one diisocyanate. The N,N-dialkylaminoalkylamine used herein is represented by the general formula wherein R is alkyl of 1 to 4 carbon atoms and n is 2 or 3. As examples of this amine, there may be mentioned dimethylaminopropylamine, diethylaminopropylamine, dipropylaminopropylamine, dibutylaminopropylamine, dimethylaminoethylamine, diethylaminoethylamine, dipropylaminoethylamine, dibutylaminoethylamine, and the like. Among others, dimethylaminopropylamine and diethylaminopropylamine are preferred, As the amine having one or two nitrogen atoms with active hydrogen and having a ring structure in its molecule, there may be mentioned polyamines and monoamines such as metaxylylenediamine, 1,3-bis-aminomethylcyclohexane, isophoronediamine, diaminocyclohexane, phenylenediamine, tolylenediamine, diaminodiphenylmethane, diaminodiphenyl sulfone, piperazine, N-aminoethylpiperadine, benzylamine, cyclohexylamine, and the like. Of these amines, methaxylylenediamine, 1,3-bis(aminomethyl)cyclohexane, isophoronediamine, N-aminoethylpiperadine, cyclohexylamine and benzylamine are particularly preferred. Of these amine components, the polyamines act as a molecular chain extender and the monoamines act as a molecular weight regulator for a curing agent molecule. As the diisocyanate, there may be mentioned isophorone diisocyanate, methaxylylene diisocyanate, 1,3-bis-(isocyanatomethyl)cyclohexane, 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, 1,5-naphthylene diisocyanate, 1,4-phenylene diisocyanate, diphenylmethane-4,4'-diisocyanate, 2,2'-dimethyldiphenylmethane-4,4'-diisocyanate, hexamethylene diisocyanate, trimethylhexamethylene diisocyanate, and the like, of which diisocyanates having a ring structure are particularly preferred. As the epoxide in the raw material components of the curing agent which is a component of the present invention, the above-mentioned epoxides, namely, one of the essential components of the present invention may be used. Of these epoxides, bisphenol A type epoxide having an epoxy equivalent weight of about 190, bisphenol F type epoxide having an epoxy equivalent weight of about 175, glycidylaniline, and glycidylorthotoluidine, as well as monoepoxides such as phenylglycidylether, methylphenylglycidylether and butylphenylglycidylether are particularly preferred. Of these epoxides, diepoxides act as a molecular chain extending material and monoepoxides act as a molecular weight adjusting material for a curing agent molecule. The curing agent of the present invention is synthesized basically as follows: an addition reaction is carried out between a part or all of the amine (b) having one or two nitrogen atoms with active hydrogen and having a ring structure in its molecule, and epoxide (d) having more than one epoxy groups in the molecule with or without a solvent such as aromatic hydrocarbons, alcohols and ketones at 60°C to 120°C, and (a), the rest of (b) and (c) are added to them, the reactants are heated and reacted at room temperature to 160°C, preferably 50°C to 150°C, and then the solvent is removed. It is also possible to use diisocyanate (c) preliminarily blocked with oxime, alcohol or the like. In the case of curing agent (C) prepared by reacting (a) at least one N,N-dialkylaminoalkylamine, (b) at least one amine having one or two nitrogen atoms with active hydrogen and having a ring structure in its molecule, (c) at least one diisocyanate, and (d) at least one epoxide having one or more epoxy groups in a molecule, the molar ratio of (b) to a mole of (a) is 0.5 mole≤(b)≤5.0 moles. When used amount of (b) is smaller than 0.5 mole, the product has a low melting point and poor storage stability. When the amount of (b) is greater than 5.0 moles, the product has poor curing property at low temperature. The ratio of (c) is such that the chemical equivalent of diisocyanate in (c) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 0.15 chemical equivalent ≤ diisocyanate ≤1.35 chemical equivalents. When the amount of (c) in which the chemical equivalent of diisocyanate is smaller than 0.15 chemical equivalent is used, the product is a tacky solid which can hardly be crushed and the epoxide composition has poor storage stability. When the amount of (c) in which the chemical equivalent of diisocyanate is greater than 1.35 chemical equivalents is used, the product has a high melting point and poor low temperature curing properties. The ratio of (d) is such that the chemical equivalent of epoxide in (d) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 0.3 chemical equivalent ≤epoxide ≤0.9 chemical equivalent. When the chemical equivalent of epoxide is smaller than 0.3 chemical equivalent or greater than 0.9 chemical equivalent, both low temperature curing properties and storage stability of the product are poor. Also, the sum of the chemical equivalent of diisocyanate in (c) and the chemical equivalent of epoxide in (d) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 1.0 chemical equivalent ≤sum of chemical equivalent of diisocyanate and epoxide ≤1.8 chemical equivalents. When the sum is smaller than 1.0 chemical equivalent, the product has tackiness and poor storage stability, and when the sum is greater than 1.8 chemical equivalents, molecular weight of the product is increased and gelation occurs. The composition of the present invention can be obtained by mixing and dispersing powder of the curing agent with the epoxide. When the epoxide is a liquid, it is preferred to blend a curing agent therewith in predetermined ratio and further mix and disperse it sufficiently by using a device like a mortar. When the epoxide is a solid, it is preferred to use preliminarily finely crushed epoxide and mix it sufficiently with a curing agent. The blending amount of the curing agent to the epoxide differs depending on the type of the epoxide, particularly the concentration of the epoxy groups in the epoxide, and is within the range of 1 to 40 parts relative to 100 parts of the epoxide. It is also possible to use concurrently various conventional curing agents known to be a latent-type curing agent such as acid anhydrides, dicyandiamide, melamine, guanamines, dibasic acid hydrazides, imidazoles, and the like. Also, other additives may optionally be added as necessary to the one-pack type heat curing epoxide composition of the present invention. As such additives, there may be mentioned inorganic powdery materials such as alumina, silica, silica powder, talc, bentonite, calcium carbonate, and cement; asbestos, glass fibers, synthetic fibers, mica, metal powder, as well as thixotropic agent or similar materials. Also, if necessary, other diluent and flame retardants may be added. Examples Followings are examples of the present invention. The present invention is not limited to the range of the working examples. Curing Agent Preparation 1 In a four necked flask equipped with a thermometer, a reflux condenser, a stirrer, a nitrogen inlet device and a dropping funnel, were charged 39,3g (0.231 mole) of isophoronediamine, 10.9g (0.11 mole) of cyclohexylamine, and 98.7g of xylene. While blowing nitrogen into them, they were heated to 120°C. While maintaining the temperature and mixing them, was added dropwise from the dropping funnel 59.4g (0.44 equivalent) of GOT (diglycidylorthotoluidine, Nippon Kayaku K.K., epoxy equivalent weight about 135). After addition was complete, they were kept standing at 120°C for two hours to complete the reaction. Then, was added 33.7g (0.33 mole) of dimethylaminopropylamine, and they were heated to 130°C. While maintaining this temperature and vigorously mixing them, was added dropwise from the dropping funnel a mixture of 40.2g (0.231 mole) of toluene diisocyanate and 20.1g of xylene. After addition was complete, reaction was carried out while refluxing xylene until free isocyanate is confirmed to be absent. Thereafter, xylene was removed in vacuo. The obtained product is a transparent pale yellow solid which can be readily crushed. This obtained curing agent is designated as E. Curing Agent Preparation 2 In a four necked flask equipped with a thermometer, a reflux condenser, a stirrer, a nitrogen inlet device and a dropping funnel, were charged 30.0g (0.221 mole) of methaxylylenediamine, 10.4g (0.105 mole) of cyclohexylamine, and 97.1g of xylene. While blowing nitrogen into them, they were heated to 120°C. While maintaining the temperature and mixing them, was added dropwise from the dropping funnel 56.7g (0.42 equivalent) of GOT. After addition was complete, it was kept standing at 120°C for two hours to complete the reaction. Then, was added 32.1g (0.315 mole) of dimethylaminopropylamine and they were heated to 130°C. While maintaining this temperature and vigorously stirring them, was added dropwise from the dropping funnel a mixture of 49.0g (0.221 mole) of isophorone diisocyanate and 24.5g of xylene. After addition was complete, reaction was carried out while refluxing xylene until free isocyanate is confirmed to be absent. Thereafter, xylene was removed in vacuo. The obtained product is a transparent yellow solid which can be readily crushed. This obtained curing agent is designated as F. Curing Agent Preparation 3 In a four necked flask equipped with a thermometer, a reflux condenser, a stirrer, a nitrogen inlet device and a dropping funnel, were charged 28.4g (0.22 mole) of N-aminoethylpiperadine, 10.4g (0.105 mole) of cyclohexylamine, and 95.5g of xylene. While blowing nitrogen into them, they were heated to 120°C. While maintaining the temperature and mixing them, was added dropwise from the dropping funnel 56.7g (0.42 equivalent) of GOT. After addition was complete, they were kept standing at 120°C for two hours to complete the reaction. Then, was added 32.1g (0.315 mole) of dimethylaminopropylamine and they were heated to 130°C. While maintaining this temperature and vigorously stirring them, was added dropwise from a dropping funnel a mixture of 49.0g (0.221 mole) of isophorone diisocyanate and 24.5g of xylene. After addition was complete, reaction was carried out while refluxing xylene until free isocyanate is confirmed to be absent. Thereafter, xylene was removed in vacuo. The obtained product is a transparent brown colored solid which can be easily crushed. This obtained curing agent is designated as G. Curing Agent Preparation 4 In a four necked flask equipped with a thermometer, a reflux condenser, a stirrer, a nitrogen inlet device and a dropping funnel, were charged 39.1g (0.23 mole) of isophoronediamine and 93.1g of xylene. While blowing nitrogen into them, they were heated to 120°C. While maintaining the temperature and vigorously mixing them, was added dropwise from the dropping funnel 54.0g (0.4 equivalent) of GOT. After addition was complete, they were kept standing at 120°C for two hours to complete the reaction. Then, was added 40.8g (0.4 mole) of dimethylaminopropylamine and they were heated to 130°C. While maintaining this temperature and vigorously stirring them, was added dropwise from the dropping funnel a mixture of 51.1g (0.23 mole) of isophorone diisocyanate and 25.5g of xylene. After addition was complete, reaction was carried out while refluxing xylene until free isocyanate is confirmed to be absent. Thereafter, xylene was removed in vacuo. The obtained product is a transparent pale yellow solid which can be readily crushed. This obtained curing agent is designated as H. Curing Agent Preparation 5 In a four necked flask equipped with a thermometer, a reflux condenser, a stirrer, a nitrogen inlet device and a dropping funnel, were charged 33.2g (0.195 mole) of isophoronediamine, 8.4g (0.085 mole) of cyclohexylamine, and 97.8g of xylene. While blowing nitrogen into them, they were heated to 120°C. While maintaining the temperature and mixing them, was added dropwise from the dropping funnel 64.6g (0.34 equivalent) of ARALDITE GY-260 (bisphenol A type epoxide, Japan Ciba Geigy, Epoxy equivalent weight of about 190). After addition was complete, they were kept standing at 120°C for two hours to complete the reaction. Then, was added 26.0g (0.255 mole) of dimethylaminopropylamine and they were heated to 130°C. While maintaining this temperature and vigorously stirring them, was added dropwise from the dropping funnel a mixture of 43.4g (0.195 mole) of isophorone diisocyanate and 21.7g of xylene. After addition was complete, reaction was carried out while refluxing xylene until free isocyanate is confirmed to be absent. Thereafter, xylene was removed in vacuo. The obtained product is a transparent pale yellow solid which can be readily crushed. This obtained curing agent is designated as I. Curing Agent Preparation 6 In a four necked flask equipped with a thermometer, a reflux condenser, a stirrer, a nitrogen inlet device and a dropping funnel, were charged 35.2g (0.207 mole) of isophoronediamine, 8.9g (0.09 mole) of cyclohexylamine, and 97.5g of xylene. While blowing nitrogen into them, they were heated to 120°C. While maintaining the temperature and mixing them, was added dropwise from the dropping funnel 63.0g (0.36 equivalent) of EPICRON 830 (bisphenol F type epoxide, Dainippon Ink Chemical Industries K.K., epoxy equivalent weight about 175). After addition was complete, they were kept standing at 120°C for two hours to complete the reaction. Then, was added 27.5g (0.27 mole) of dimethylaminopropylamine and they were heated to 130°C. While maintaining this temperature and vigorously stirring them, was added dropwise from the dropping funnel a mixture of 46.0g (0.207 mole) of isophorone diisocyanate and 23.0g of xylene. After addition was complete, reaction was carried out while refluxing xylene until free isocyanate is confirmed to be absent. Thereafter, xylene was removed in vacuo. The obtained product is a transparent yellow solid which can be readily crushed. This obtained curing agent is designated as J. Curing Agent Preparation 7 In a four necked flask equipped with a thermometer, a reflux condenser, a stirrer, a nitrogen inlet device and a dropping funnel, were charged 47.5g (0.279 mole) of isophoronediamine, 16.7g (0.169 mole) of cyclohexylamine, and 100.8g of xylene. While blowing nitrogen into them, they were heated to 120°C. While maintaining the temperature and mixing them, was added dropwise from the dropping funnel 70.2g (0.52 equivalent) of GOT. After addition was complete, they were kept standing at 120°C for two hours to complete the reaction. Then, was added 9.3g (0.091 mole) of dimethylaminopropylamine and they were heated to 130°C. While maintaining this temperature and vigorously stirring them, was added dropwise from the dropping funnel a mixture of 33.2g (0.15 mole) of isophorone diisocyanate and 16.6g of xylene. After addition was complete, reaction was carried out while refluxing xylene until free isocyanate is confirmed to be absent. Thereafter, xylene was removed in vacuo. The obtained product is a transparent yellow-orange colored solid which can be readily crushed. This obtained curing agent is designated as K. Curing Agent Preparation 8 In a four necked flask equipped with a thermometer, a reflux condenser, a stirrer, a nitrogen inlet device and a dropping funnel, were charged 32.1g (0.3 mole) of benzylamine and 72.6g of xylene. While blowing nitrogen into them, they were heated to 120°C. While maintaining the temperature and mixing them, was added dropwise from the dropping funnel 40.5g (0.3 equivalent) of GOT. After addition was complete, they were kept standing at 120°C for two hours to complete the reaction. Then, was added 30.6g (0.3 mole) of dimethylaminopropylamine and they were heated to 130°C. While maintaining this temperature and vigorously stirring them, was added dropwise from the dropping funnel a mixture of 83.2g (0.375 mole) of isophorone diisocyanate and 41.6g of xylene. After addition was complete, reaction was carried out while refluxing xylene until free isocyanate is confirmed to be absent. Thereafter, xylene was removed in vacuo. The obtained product is a transparent yellow solid which can be readily crushed. This obtained curing agent is designated as L. Examples 1 to 15 Curing agents E to L obtained in Curing Agent Preparations 1 to 8, respectively, were each finely divided and added to and dispersed in ARALDITE GY-260 together with AEROSIL 300 (a product of Nippon Aerosil K.K.; a particulate silica), and these compositions were tested for curing property and storage stability. Evaluation of curing property: A sample of about 0.1 to 0.2 g was placed on a hot plate which was set to predetermined temperature, and the time until gelation of the sample was determined. Evaluation of storage stability: A sample was placed in a thermostatic chamber at 45°C and days until fluidity loss of the sample were recorded. The test results for these properties are shown in the table. BLENDING RATIOS AND RESULTS OF EXAMPLES 1 TO 23 Ex. Epoxide composition curing agent epoxide AE.300 Curing time (min) Storage stability symbol (parts) (parts) (parts) 120°C 100°C 80°C (days) 1 E 10 1 100 3.0 5.7 15.0 30< 2 E 20 1 100 1.5 3.3 8.4 16 3 F 10 1 100 3.8 14.9 60< 30< 4 F 20 1 100 1.8 4.6 20.9 22 5 G 10 1 100 3.1 6.1 21.0 30< 6 G 20 1 100 1.8 4.0 12.0 4 7 H 10 1 100 2.5 6.5 25.9 30< 8 H 20 1 100 1.5 3.5 14.0 18 9 I 10 1 100 2.9 13.3 60< 30< 10 I 20 1 100 1.7 5.2 33.2 30< 11 J 10 1 100 2.9 12.8 60< 30< 12 J 20 1 100 1.6 5.5 37.6 30< 13 K 20 1 100 4.0 8.4 30.8 30< 14 L 10 1 100 4.2 7.9 37.8 30< 15 L 20 1 100 2.3 4.2 16.7 30< Ex.= Examples AE.300=AEROSIL 300 It is apparent from above that the present invention provides an epoxide composition which utilizes a curing agent free from volatile by-product generation during its synthesis, has excellent storage stability, and can be cured rapidly at a relatively low temperature region when heated.

Claims: A heat-curable epoxide composition which comprises (A) at least one epoxide having more than one epoxy group in a molecule, and (C) a curing agent which is the reaction product of (a) at least one N,N-dialkylaminoalkylamine represented by the general formula wherein R is an alkyl group of 1 to 4 carbon atoms, and n is 2 or 3; (b) at least one amine having one or two nitrogen atoms with active hydrogen and having a ring structure in its molecule; (c) at least one diisocyanate; and (d) at least one epoxide having more than one epoxy group in the molecule, wherein: the molar ratio of (b) to a mole of (a) is 0.5 mole ≤ (b) ≤ 5.0 moles; the ratio of (c) is such that the chemical equivalent of diisocyanate in (c) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 0.15 chemical equivalents ≤ 1 chemical equivalent diisocyanate ≤ 1.35 chemical equivalents; the ratio of (d) is such that the chemical equivalent of epoxide in (d) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 0.3 chemical equivalents ≤ 1 chemical equivalent epoxide ≤ 0.9 chemical equivalents; and the sum of the chemical equivalent of diisocyanate in (c) and the chemical equivalent of epoxide in (d) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 1.0 chemical equivalent ≤ sum of chemical equivalents of diisocyanate and epoxide ≤ 1.8 chemical equivalents; and wherein the reaction order of said addition reaction is such that a reaction is carried out at 60-120°C between a part of or all of (b) and epoxide (d) having more than one epoxy groups in a molecule, then (a), the rest of (b) and (c) are added to the reaction mixture, and the reactants are heated and reacted at room temperature to 160°C. A composition according to claim 1 wherein at least one epoxide of (A) or of (C)(d) is selected from polyglycidyl ethers, polyglycidyl ether esters, polyglycidyl esters, glycidylaminoglycidyl ethers, glycidylamino-glycidyl ester, polyglycidylamines and mono-epoxide and mixtures of these epoxides. A composition of claim 1 wherein at least one N,N-dialkylaminoalkylamine of (C)(a) is dimethylaminopropylamine or diethylaminopropylamine. A composition of claim 1 wherein at least one amine of (C) (b) is selected from metaxylylenediamine, 1,3-bis(aminomethyl)cyclohexane, isophoronediamine, N-aminoethylpiperadine, cyclohexylamine and benzylamine. A composition of claim 1 wherein at least one diisocyanate of (C)(c) has a ring structure. A curing agent for a heat-curable epoxide composition which is the reaction product of (a) at least one N,N-dialkylaminoalkylamine represented by the general formula wherein R is an alkyl group of 1 to 4 carbon atoms, and n is 2 or 3; (b) at least one amine having one or two nitrogen atoms with active hydrogen and having a ring structure in its molecule; (c) at least one diisocyanate; and (d) at least one epoxide having more than one epoxy group in the molecule, wherein: the molar ratio of (b) to a mole of (a) is 0.5 mole ≤ (b) ≤ 5.0 moles; the ratio of (c) is such that the chemical equivalent of diisocyanate in (c) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 0.15 chemical equivalents ≤ 1 chemical equivalent diisocyanate ≤ 1.35 chemical equivalents; the ratio of (d) is such that the chemical equivalent of epoxide in (d) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 0.3 chemical equivalents ≤ 1 chemical equivalent epoxide ≤ 0.9 chemical equivalents; and the sum of the chemical equivalent of diisocyanate in (c) and the chemical equivalent of epoxide in (d) per one nitrogen atom with active hydrogen in (a) and (b) is in the range of 1.0 chemical equivalent ≤ sum of chemical equivalents of diisocyanate and epoxide ≤ 1.8 chemical equivalents; and wherein the reaction order of said addition reaction is such that a reaction is carried out at 60-120°C between a part of or all of (b) and epoxide (d) having more than one epoxy groups in a molecule, then (a), the rest of (b) and (c) are added to the reaction mixture, and the reactants are heated and reacted at room temperature to 160°C. Use of the reaction product of claim 6 as a curing agent or a curing accelerator of dicyandiamide, acid anhydrides, and dibasic acid dihydrazides for epoxides.

Inventors: CHIBA YASUO, KUBOTA MASAO, NAGABUCHI RITARO, CHIBA, YASUO, KUBOTA, MASAO, NAGABUCHI, RITARO, CHIBA, YASUO, FUJI KASEI KOGYO CO., LTD., KUBOTA, MASAO, FUJI KASEI KOGYO CO., LTD., NAGABUCHI, RITARO, FUJI KASEI KOGYO CO., LTD.
Applicants: FUJI KASUI KOGYO KK, FUJI KASEI KOGYO CO., LTD.
Application year: 1991
Main classification: C08G59
IPC codes: C08G18, C08G59, C08L63