Paper towels having bulky layer

Abstract: A paper towel with improved water holding capacity and improved rate of absorption has a delaminated stratified structure comprising: a first layer of chemical fiber blend; and a second layer of an anfractuous high bulk softwood fiber blend, unitary with said first layer; said first layer being constructed of a chemical softwood and hardwood fiber blend, which blend is more dense than said second layer.

Description: This invention relates to paper towels and in particular to paper towels having an enhanced rate of absorption and water holding capacity. Hithertofore, paper towels have been constructed of a fiber blend material. Normally, creping of the fiber blend material provides an improvement in the absorbency attribute. However, the rate of absorption is often sacrificed for capacity. An absorbent paper towel using blended fibers which includes a denser top layer for strength and an exploded, or anfractuous, bottom layer for improved water absorption capacity without sacrificing rate of absorption has not hithertofore been developed. The present invention provides a paper towel with an improved structure for enhancing a rate of absorption and water holding capacity of the towel. According to the present invention, there is provided a delaminated stratified paper towel comprising: a first layer of chemical fiber blend; and a second layer comprising an anfractuous high bulk softwood fiber blend, unitary with said first layer; said first layer being constructed of a chemical softwood and hardwood fiber blend, which blend is more dense than said second layer; said second layer having approximately 30% to 43% of the anfractuous fiber and approximately 57% to 70% of long mechanical pulp fiber. Preferably the second layer is a blend of high bulk fiber and fiber derived from chemi-thermomechanical pulp. The anfractuous fiber may be formed by a fiber treatment which renders the fibers non-linear, curly or fluffy. In one preferred embodiment, the fiber is treated with citric acid. In one preferred embodiment the first layer comprises approximately 70% Kraft softwood and 30% Kraft hardwood, by weight. The invention also encompasses the inclusion of a third layer in the fiber blend, with the second layer disposed between the first layer and said third layer. Preferably, the third layer may have the same composition as the first layer. In another embodiment, the paper towel may have a back-to-back multiply structure: i.e. each ply comprises said first layer and said second layer and the plies are assembled with the said second layers adjacent, whereby the resultant structure comprises first layer/second layer/second layer/first layer. It is preferred that the second layer forms approximately 35% of the total weight of the towel. The invention also provides a method of forming a delaminated stratified web of said paper towel material, said method comprising: supplying a first aqueous furnish directly to a wire to form said first layer; supplying a second aqueous furnish onto the first furnish disposed on the wire to form said second layer; drying the assembly of layers formed from said first and second furnishes to form a web of paper towel material having a predetermined dryness; creping the paper towel material off of the drying means; and embossing the paper towel material to a predetermined emboss depth. The invention will now be described in greater detail with reference to preferred embodiments thereof and with the aid of the accompanying drawings, wherein, Figure 1 is schematic view illustrating an embodiment of the present invention wherein two furnishes are supplied to separate channels of a headbox forming a unitary stratified web which is thereafter, subsequently creped and embossed; Figure 2 illustrates data showing water holding capacity of four different paper towel structures; Figure 3A is a microscopic cross-sectional view of a control paper towel; Figure 3B is a schematic sectional illustration of the structure of the towel illustrated in Figure 3A; Figure 4A is a microscopic view of the chemi-thermomechanical pulp paper towel; Figure 4B is a schematic sectional illustration of the structure of the towel illustrated in Figure 4A; Figure 5A is a microscopic view of the high bulk fiber paper towel; Figure 5B is a schematic sectional illustration of the structure of the towel illustrated in Figure 5A; Figure 6A is a microscopic view of the chemi-thermomechanical pulp and high bulk additive paper towel; Figure 6B is a schematic sectional illustration of the structure of the towel illustrated in Figure 6A; The preferred towels of the present invention comprise a unitary stratified structure comprising a dense first layer of a chemical pulp hardwood-softwood fiber blend (more preferably about 70% Kraft softwood and about 30% Kraft hardwood fiber) and a second layer of bulky anfractuous fiber blend. The bulky anfractuous - fiber blend includes a combination of a stiff, long fiber high strength mechanical pulp and a high bulk softwood fiber. The stiff, long fiber high strength mechanical pulp may comprise any of the pretreated mechanical pulps such as thermomechanical pulp, chemi-mechanical pulp, but preferably a chemi-thermomechanical pulp. The high bulk fiber is preferably a softwood fiber which has been treated to render the fibers three dimensional, curly or fluffy (as opposed to the normally somewhat linear fiber configuration) and then "crosslinked" to "set" the three dimensional, curly or fluffy structure. As is understood in the art, the exact chemical nature of "crosslinking" or "setting" may not correspond precisely to crosslinking as that term is used in polymer science but rather comprehends several processes such as those described in U.S.-A-No. 4,853,086 and EP-A-0213415. Treatments with citric acid as well can impart a three dimensional character to the fiber as will glyoxal treatments such as result in Procter and Gamble's HPZ fiber. By "unitary," we mean that the two layers in the sheet are essentially formed simultaneously as hereinafter described. By "stratified," we mean that layers corresponding to the specified fiber compositions can be observed in the finished towel even though the dividing line may not be distinct. As illustrated in Figure 1, paper forming device 10 is provided for forming stratified paper towel 18 according to the present invention. First, inside furnish 12 is supplied through lower headbox duct 14, direction to forming fabric 15. Second furnish 16 is supplied through upper headbox duct 17 to the layer previously formed by first furnish 12. Furnishes 12 and 16 are considered "wet furnishes" wherein the material comprises from approximately 15 to 40% solids when it reaches yankee dryer 19. Inside furnish 12 consists of a dense layer which in a preferred embodiment may be approximately 65% of the total weight of the paper towel, but less than 25% of the thickness. The inside layer preferably contains approximately 70% Kraft softwood and approximately 30% Kraft hardwood. The remaining approximately 35% of the paper towel is supplied by the portion of the sheet resulting from second furnish 16. For comparative testing, second furnish 16 was constructed from four different materials to compare the absorption and water holding capacity of each type of paper towel. As a control, a towel was formed in which second furnish 16 contained 100% Kraft softwood pulp. For comparative purposes, a second towel, referred to as the chemi-thermomechanical pulp towel (CTMP towel), included 100% Temcell CTMP (sold by Tembec, Inc.) on the air side of the stratified paper towel. This softwood pulp had an arithmetic average fiber length of 0.85 mm, a length weighted average fiber length of about 2 mm and a weight weighted average fiber length of about 2.6 mm. Approximately 1/3 of the fibers constituting however less than about 4% of the fiber weight were less than about 0.20 mm in length. A third comparative towel, designated the high bulk fiber towel (HBA towel) included, on the air side, approximately 57% Kraft hardwood and approximately 43% high bulk fiber commercially available as Weyerhaueser HBA fiber believed to be somewhat similar to those described in U.S.-A-4,853,086. A fourth towel, designated the chemi-thermomechanical pulp/high bulking fiber towel (CTMP/HBA towel), included, on the air side, approximately 57% CTMP and approximately 43% HBA. The construction of each ply of the four two ply towels, is set forth in Table 1 and is illustrated in Figures 3B, 4B, 5B and 6B. HBA is a bleached Kraft pulp available from Weyerhaueser which is chemically and mechanically modified to make it suitable for bulking in wet laid paper applications. Its Kajaani weighted average fiber length is about 2.7 mm while the coarseness is about 34 mg per 100M. It has been suggested that HBA be used as a substitute for CTMP in tissues and towels, but insofar as is known to us, the combination of one layer of CTMP/HBA with another layer of Kraft pulp in a unitary sheet has not heretofore been known to provide the surprising combination of strength, water holding capacity, and high rate of absorption. First furnish 12 and second furnish 16 form towel 18 which is supplied to the yankee dryer 19 wherein a substantial quantity of the water is removed. As the stratified towel reaches a dryness of approximately 60% to 95%, the stratified paper towel is creped off of the yankee dryer 19. Creping of the stratified paper towel increases the bulk and softness of the paper towel. Creping can take one of two forms. First, creping can produce a corrugated type of paper towel. In addition, creping can produce a loosening up of the fibers in the paper towel. This second form of creping, wherein the fibers are loosened up, is referred to in the present invention as a "delaminated" stratified paper towel. Subsequent to creping, the delaminated stratified paper towel 18 from the yankee dryer 19 may be combined with another ply by passing the two between embossing rollers with the layers containing the bulky anfractuous fiber blend adjacent to each other to form two ply towels having the structures illustrated in Figures 3B, 4B, 5B and 6B, respectively. The embossing rollers penetrate the paper towel to a depth of 0.0508 cm to 0.2286 cm (0.02 to 0.09 inches). The pattern of embossing of the paper towel may be similar to that shown in U.S. Design Patent No. 231,018. The four towels identified in Table 1 were made according to a method utilizing a paper forming device 10 as discussed hereinabove. To make meaningful comparisons possible between the four towels produced, the first furnish 12 and the second furnish 16 for each towel were selected to produce towels having approximately an equal dry strength as measured by the geometric of the cross direction and machine direction breaking lengths. In this art, we consider a dry breaking length of 668 to 762 meters to be approximately equal. The average physical properties of the stratified paper towel are set forth in Table 2. The calipers and breaking lengths reported have been normalized to a basis weight of 6.8 kg/270 m² (15.0 lbs/3000 sq ft) ream. After embossing each towel to emboss depths ranging from 0.0508 cm to 0.2286 cm (0.02 to 0.09 inches), the strength and water holding properties of the towels at each emboss depth were determined. The water holding properties were compared at equal towel strength levels to determine the gain and water holding capacity (WHC) due to the presence of the unique fibers added to the second furnish 16. As used herein, WAT is an abbreviation for "water absorption time" which is specified as the time (in seconds) required for a 0.1 ml drop of water placed on the towel surface to be absorbed into the towel; WHC is an abbreviation for "water holding capacity" which is the amount of water retained in a sample immersed in water for one minute, then drained on a horizontal screen for 15 seconds. At equal wet breaking lengths, the CTMP towel had a water holding capacity approximately 1.2 grams of water per gram of fiber higher than that of the control towel. The increase in WHC was approximately constant across the range of wet strengths resulting from the change in emboss depths. For the third towel, the HBA towel, the water holding capacity was about 2.5 grams of water per gram of fiber higher than the control towel. The fourth towel, containing both CTMP and HBA, maintained an increase in WHC of approximately 3.5 grams of water per gram of fiber over the WHC of the control towel throughout the range of wet strengths obtained. As an example, the water holding capacities obtained from the four towels at an emboss depth of 0.2286 cm (0.09 inches) are shown in Table 3. At this emboss depth, the wet strengths for all four towels were approximately equal. The dry strength and water absorption rate for the towels at the emboss depth of 0.2286 cm (0.09 inches) are also shown in Table 3. The caliper and breaking length values are normalized to 6.8 kg/270 m² (30 lbs/3000 sq. ft.) ream converted towel. Figure 2 illustrates the data for the range of embossed penetrations for the four towels identified hereinabove. At a given wet strength, the blend of approximately 15% HBA and approximately 20% CTMP yields a towel structure that produced a better water holding capacity as compared to the control towel, CTMP towel and HBA towel. Figure 3A is a light microscopy cross-sectional view of the embossed, converted and finished control towel magnified by 50 times. As illustrated in Figure 3B, the control towel is constructed of two plies, each ply including two layers. As each ply is constructed on the paper machine, the layer A is the inside furnish comprising approximately 70% Kraft softwood and 30% Kraft hardwood. The other layer of the control towel is 100% Kraft softwood pulp which is applied as the outside furnish on the paper machine. The ply consisting of the layer A and the other layer is formed as a two layer sheet, and thereafter, joined together with an additional identical two layer sheet to create a two ply towel with the A layers forming the exterior surfaces of the towel and the other layers being joined to each other. Similarly, Figure 4A is a 50X light microscopy cross-sectional view of the CTMP towel. Layer A is again constructed of 70% Kraft softwood and 30% Kraft hardwood. The CTMP layer is constructed of 100% softwood Temcell CTMP. A two layer sheet including a layer A and a layer of CTMP material are constructed as a unitary sheet. Thereafter, a second identical sheet is joined together with the first sheet to create a composite towel as illustrated in Figure 4B. Figure 5A is a 50X light microscopy cross-sectional view of the HBA towel. A sheet including a layer A consisting of approximately 70% Kraft softwood and 30% Kraft hardwood is joined together in a single unitary sheet with a layer of HBA material which includes approximately 57% Kraft hardwood and 43% HBA. This sheet is joined together with a second identical sheet to create the two ply towel illustrated in Figure 5B. Figure 6A is a 50X light microscopy cross-sectional view of the CTMP/HBA towel. As illustrated in Figure 6B, each unitary ply comprises layer A including approximately 70% Kraft softwood and approximately 30% Kraft hardwood, as well as a layer of HBA plus CTMP including approximately 57% CTMP and approximately 43% HBA. This two layer sheet is combined with an additional identical two layer sheet to form the towel illustrated in Figure 6B. The light microscopy cross-sectional view of the embossed, converted and finished paper towel as illustrated in Figure 6A, indicates a structure which contains a denser outer layer with a finer pore size and pore size distribution and an inner layer of CTMP/HBA containing a unique fiber bend. This inner layer exhibits a surprisingly "exploded", or anfractuous, structure. The extent of anfractuousness or delamination in the CTMP/HBA towel did not occur in the three other paper towels. The blend of CTMP/HBA produces an anfractuous structure which is distinct in water absorbency values and water capacity as compared to the control and the CTMP or HBA paper towels. A delaminated stratified paper towel according to a first embodiment of the present invention has a first layer and a second layer. The first layer is a denser layer with a finer pore size and pore size distribution. The second layer contains a unique fiber blend of approximately 57% CTMP and approximately 43% HBA. The second layer is an anfractuous or delaminated layer for enhancing the rate of absorption and water capacity of said paper towel. A delaminated stratified paper towel according to a second embodiment of the present invention has a first layer, second layer and third layer. The first layer is a denser layer with a finer pore size and pore size distribution. The second layer contains a unique blend of approximately 57% CTMP and approximately 43% HBA. The third layer is a denser layer with a finer pore size and pore size distribution. The second layer is an anfractuous or delaminated layer for enhancing the rate of absorption and water capacity of said paper towel. For those applications in which more absorbency is required while strength is less important, towels may be constructed wherein the ratio of the weight of the Kraft layer to the weight of the HBA/CTMP layer is from about 3:2 to about 1:1, the ratios of Kraft to HBA/CTMP from about 3:2 to about 2:1 or higher being preferred for applications where more strength is required. With a towel incorporating such a 1:1 blend, a wet strength of at least equivalent to a towel described herein as the HBA towel is obtained together with at least equivalent water holding capacity. Measurement of the water absorption time of a single ply resulted in a value of 13.8 sec. while the water absorption time of a two-ply towel was about 0.8 sec. both of which times are at least substantially equivalent to those obtained for the HBA towel despite a less expensive pulp having been used.

Claims: A delaminated stratified paper towel comprising: a first layer of chemical fiber blend; and a second layer comprising an anfractuous high bulk softwood fiber blend, unitary with said first layer; said first layer being constructed of a chemical softwood and hardwood fiber blend, which blend is more dense than said second layer; said second layer having approximately 30% to 43% of the anfractuous fiber and approximately 57% to 70% of long mechanical pulp fiber. A delaminated stratified paper towel as claimed in claim 1, wherein said second layer is a fiber blend of anfractuous fiber and a fiber derived from chemi-thermomechanical pulp. A delaminated stratified paper towel as claimed in claim 1 or claim 2 wherein the anfractuous fiber is a fiber which has been treated to render the fibers non-linear, curly or fluffy. A delaminated stratified paper towel as claimed in claims 1 to 3 wherein the anfractuous fiber is a citric acid treated fiber. A delaminated stratified paper towel as claimed in any one of claims 1 to 4 wherein the first layer includes approximately 70% Kraft softwood and approximately 30% Kraft hardwood by weight. A delaminated stratified paper towel as claimed in any one of claims 1 to 5 further including a third layer of fiber blend and wherein said second layer is disposed between said first and third layers. A delaminated stratified paper towel as claimed in claim 6 wherein the third layer and the first layer have the same composition. A delaminated stratified paper towel as claimed in any one of claims 1 to 7 wherein the second layer forms approximately 35% by weight of the total weight of the towel. A method of forming a delaminated stratified web of paper towel material as claimed in any one of claims 1 to 8 comprising: supplying a first aqueous furnish directly to a wire to form said first layer; supplying a second aqueous furnish onto the first furnish disposed on the wire to form said second layer; drying the assembly of layers formed from said first and second furnishes to form a web of paper towel material having a predetermined dryness; creping the paper towel material off of the drying means; and embossing the paper towel material to a predetermined emboss depth.

Inventors: AWOFESO ANTHONY O, HARPER FRANK D, AWOFESO, ANTHONY O., HARPER, FRANK D.
Applicants: JAMES RIVER CORP, JAMES RIVER CORPORATION OF VIRGINIA
Application year: 1991
Main classification: D21H27
IPC codes: D21H11, D21F11, D21H25, D21H27