Structure of light-shielding cloth and film container using the same

Abstract: Light-shielding cloths excellent in light-shielding ability, film drawing resistance, etc were developed, by increasing the pile yarn density in accordance with a special formula, by passing pile yarns (4) between the needle loop and the sinker loop of the ground fabric (3) or by using a combination of regular yarn and special yarn. The contamination of the film by the thermobleeding of the dye is prevented by using a particular dye. The generation of static marks is also prevented by treating the light-shielding cloth comprising synthetic fiber with a special antistatic agent or treatment.

Description: This invention relates to a film container, particularly a photographic film container, using a light-shielding cloth. Containers for photographic films comprise cassettes for sheet films, cartridges for roll films and the like. Said containers are provided with a light-shielding member at the slit for extending the film in order to prevent the photographic film from being exposed to light (see DE-A-3 835 305). When the light-shielding member is a cloth, it is called light-shielding cloth. In usual containers for a light-sensitive strip film, as shown in Figure 8, a wound light-sensitive strip film, such as a photographic film 11, is put in the film container body 13 in a rotatable state, and the slit 14 for extending the light-sensitive film 11 is formed. Light-shielding members, such as the light-shielding cloth 15 are attached to both of the upper and lower tongue portions 16 of the slit 14. The light-shielding cloth is usually colored black in order to ensure the light-shielding ability, and moreover, it is soft so as not to damage the photographic film at the time of extending and rewinding it. The film container disclosed in Japanese Utility model No. 46-20539 is provided with a light-shielding cloth composed of a ground fabric and a coreless pile yarn woven thereto at the slit. The coreless pile yarn is formed from a soft raw yarn having polar groups, such as viscose yarn, acetate yarn or nylon yarn, by crimp processing, and the reverse side of the ground fabric is impregnated with an adhesive in order to fix the pile yarn. Another film container is disclosed in Japanese Patent No. 54-36925 wherein the light-shielding cloth is forned by electrostatic flocking. However, in the case of a conventional light-shielding cloth fraying or falling out of pile yarns occurs during the manufacture of the light-shielding cloth and extending or rewinding the light-sensitive strip film. Dust from the pile yarn adheres to the surface of the light-sensitive material and causes trouble in exposure and development. It is also a problem that its manufacture process is complicated and manufacturing costs are expensive. In the case of a light-shielding cloth formed by electrostatic flocking, the workability in the production is inferior due to the use of an adhesive, and moreover, the flocked yarn easily falls out. The applicants developed an improved light-shielding cloth having less troubles, such as fray and falling out, capable of being produced by a relatively simple process with low costs (Japanese Utility Model No. 61-34526. The light-shielding cloth has a knitted structure shown in Figures 11 and 12, and is formed of a ground fabric 21 having a warp knitted structure formed of filament yarn 23 composed of chain yarn 25 and inlay yarn 26 and a pile portion 22 wherein pile yarn 24 is disposed in parallel to the chain yarn 24, looped and set up. The cross section in the direction perpendicular to the section of Figure 12 is shown in Figure 14. The light-shielding cloth is used, for example, in the form shown in Figure 13, wherein a filler layer 27 and an adhesive layer 28 are provided successively under the ground fabric 21. A light-shielding cloth structure disclosed in Japanese Patent No. 60-208751 uses a conjugate yarn (special yarn) spun of two kinds of polymers. In another light-shielding cloth disclosed in Japanese Patent No. 62-98347, the pile is formed using a highly bulky yarn (special yarn). In general, light-shielding cloths are dyed using a direct dye, an acid dye, a metal complex dye or the like, and the dye is strongly bound to the fiber of the light-shielding cloth through ionic bonds. Recently, polyester fibers improved in various fiber properties were used for improving the material cost, the light-shielding ability, the film drawing resistance and the like. The light-shielding cloth formed of a polyester fiber is dyed with a disperse dye. Recently cameras are provided with a high speed winding and rewinding mechanism. Cameras having a winding speed of more than 10 frames per second have been sold. Accompanied with the spreading of the high speed winding camera, a static mark problem occurred due to the generation of static electricity by the friction between the light-shielding cloth attached to the slit of the film container and the photographic film during the operation of the camera. The static electricity was discharged to form exposed spots, and they appeared as the contaminated part, i.e. static marks, by the development. Besides, recent photographic films have a high sensitivity and a high quality, and they are more liable to form static marks than conventional films. As the means to prevent the generation of the static mark, various means have been developed and disclosed in Japanese Patent Nos. 55-12917, 46-28218, 62-286041 and 62-286042. In the case of the knitted light-shielding cloth disclosed in Japanese Utility Model No. 61-34526, the light-shielding ability was unstable. Moreover, the drawing resistance of the film was relatively great, and the film surface, particularly the photographic emulsion surface, was occasionally damaged. Therefore, when the pile density was increased in order to improve the light-shielding ability, abrasion troubles increased, and the photographic film could not be delivered in the camera, in the extreme case. In the case of the light-shielding cloth using a conjugate yarn, the filament was thick, and its bounce impact elasticity was strong. Therefore, the drawing resistance was great. Furthermore, since the conjugate yarn was formed by spinning two kinds of polymers, it was expensive. The light-shielding cloth using the highly bulky yarn has a problem that, when it was strongly pressed during processing or continuously compressed at the exit, the plush was decreased to degrade the light-shielding ability. Moreover, the light-shielding cloth was expensive due to the price of the yarn. In the case of the light-shielding cloth formed of a polyester fiber, the dyeing mechanism is different from other conventional light-shielding cloths, and depends on physical bonds, mainly Van der Waals bonds. Therefore, the phenomenon occurred that the bonds of the dye are easily released by thermal energy and the like to suspend on the surface of the fiber, called thermobleeding phenomenon. The thermobleeding phenomenon correlates to the molecular weight of the dye molecule, and a dye molecule having a greater molecular weight induces a greater thermobleeding. Incidentally, disperse dyes are roughly divided into quinone dyes and azo dyes in view of the molecular structure. Quinone dyes are mainly used for light to medium colors because they have a relatively small molecular weight, a small absorption coefficient, a weak fastness of color and a great level dyeing ability, and azo dyes are mainly used for high concentration dyeing because they have a relatively large molecular weight, a great absorption coefficient, a strong fastness of color and a small level dyeing ability. Thus, azo dyes were mainly used as disperse dye for dyeing light-shielding cloths which were colored black, and thermobleeding occurred greatly due to the large molecular weight of the azo dye molecule. The released dye molecule due to the thermobleeding phenomenon transferred to contaminate the acetate film which was the base film of photographic films under particular environmental conditions, and remarkably affected the photographic properties. For example, when a photographic film cartridge was put in a car in a state loaded in a camera or packaged in a film case, the photographic film was exposed to high temperature, and the water dissolved in the gelatin of the photograhic emulsion layer was evaporated and then condensed. The released dye on the surface of the fiber of the light-shielding cloth was transferred to contaminate the photographic film through the condensed water. As mentioned above, in the case of a conventional light-shielding cloth using a black disperse dye, the contamination of the photographic film surface is unavoidable under particular conditions. In order to solve the above problems, various investigations have been made, but satisfied results were not obtained yet. As mentioned previously, although various means to prevent the generation of the static mark have been developed particularly for cameras provided with a high speed winding and rewinding mechanism, they were practically unsatisfactory because of losing the softness of the fiber, having a short durability of the antistatic effect or affecting adversely the light-sensitive face of the photographic film. Particularly, in the case of a light-shielding cloth formed of a polyester fiber, the treatment with an antistatic agent which is a usual surfactant disclosed in Japanese Patent Nos. 62-286041 and 62-286042 was inferior in the durability of the antistatic effect. Moreover, the surfactant was temporarily adhered due to the properties of the polyester fiber, and therefore, the surfactant was eluted from the surface of the fiber under an environment where water is present. The eluted surfactant reacted with the photographic emulsion on the film surface, and adversely affected the photographic properties. As an environment where water is present, for example, a photographic film cartridge put in a car as mentioned previously corresponds thereto. It is the object of the present invention to provide a film container comprising a light-shielding cloth having an increased pile density, a small drawing resistance with respect to a photographic film and being capable of drawing a photographic film out of a container without forming an abrasion, a small bounce impact elasticity and nevertheless being capable of ensuring a sufficient light-shielding ability. Said object is achieved by a film container (13) which is provided with a light-shielding cloth as a light-shielding member on the slit for extending a photographic film (11), sai cloth having a ground fabric (1) and a pile portion (2) formed of pile yarns (4) knitted thereto, characterized in that the pile density of the light-shielding cloth satisfies the following formula: A (1 - a) * B (1 - b) * n * f > 19995 filaments/cm 2 (129000 filaments/inch 2 ) * means a multiplication mark. wherein A: the number of stitches per cm(inch) in the longitudinal direction immediately after knitting B: the number of stitches per cm(inch) in the lateral direction immediately after knitting a: shrinkage ratio in the longitudinal direction of the ground fabric (1) b: shrinkage ratio in the lateral direction of the ground fabric (1) a,b=(x-y)/x x: the length before shrinking (the length immediately after knitting) y: the length after shrinking n: the number of pile yarns (4) per one root f: the number of filaments composing the pile yarn (4) said yarn forming said ground fabric (1) being a highly shrinkable yarn having a shrinkage percentage of more than 15% or being a multifilament yarn. Preferably the pile yarns have been set up by passing same between the needle loop and the sinker loop composing the group fabric. The pile portion may be a combination of regular yarn and special yarn entangled with each other. Preferably the light-shielding cloth comprises polyester yarn being dyed black with a blend dye containing a disperse dye as the principal component the thermobleeding rate of the blue component being less than 2.0 %. The light-shielding cloth preferably has a color density which is not more than 20. The light-shielding cloth may comprise a synthetic fiber being treated with an antistatic agent or by an antistatic treatment having a resistance to washing with warm water. Said synthetic fiber is preferably a polyester fiber and said resistance to washing with hot water is preferably such as to keep a fixation rate of more than 80% after washing at 60°C for 10 minutes. The film container is provided with the above light-shielding cloth as the light-shielding member on the slit for extending a photographic film. Figure 1 is a partial rear view of a light-shielding cloth used in the invention, and Figure 2 is a partial sectional view thereof. Figure 3 is a partial sectional view taken on line A-A of Figure 4, and Figure 4 is a partial plan view of another light-shielding cloth used in the invention. Figure 5 is a perspective view of another light-shielding cloth used in the invention, and Figure 6 is an enlarged section of the encircled portion B in Figure 5. Figure 7 is a partial plan view thereof. Figure 8 is a sectional view of a photographic film cartridge employing a light-shielding cloth used in the invention, and Figure 9 is a perspective view partially cutaway thereof. Figure 10 is a graph indicating the relation between the ratio of the pile amount of regular yarn to special yarn and drawing resistance or fogged length of photographic film. Figure 11 is a partial rear view of a conventional light-shielding cloth. Figure 12 is a partial sectional view of a conventional light-shielding cloth. Figure 13 is a perspective view of a conventional light-shielding cloth, and Figure 14 is a partial sectional view thereof. 1 ... Ground fabric 2 ... Pile portion 3 ... Filament yarn for the ground fabric 4 .. Pile yarn 5 ... Chain yarn 6 ... Insert yarn 7 ... Filler layer 8 ... Adhesive layer 9 ... Regular yarn 10... Special yarn 11... Photographic film 12... Spool 13... Container body 14... Slit 15... Teremp cloth 16... Tongue portion The relation between the pile density and the light-shielding ability at the slit of a film cartridge was investigated. First, several kinds of light-shielding cloth different in pile density were prepared by using a raschel machine, having a structure where two pile yarns were engaged per one root. Each light-shielding cloth was adhered to the slit having a slit width in the transverse direction of 2.1 mm of a JIS 135 type photographic film cartridge as the light-shielding member. A roll of ISO 100 color photographic negative film (manufactured by Fuji Photo Film Co., Ltd.) was loaded in each cartridge, and the cartridges were exposed to light of 70,000 luxes for 3 minutes at the slit side and both ends. Then, each film was developed, and the fogging degree was observed. The results are shown as follows: Pile Density (x 10 3 filaments/cm 2 ) 10 12 14 16 18 20 22 24 Fogged Portion B B B B B A A A A: Fogged portion is shorter than 10 cm from the slit. B: Fogged portion is not shorter than 10 cm from the slit. From the above results, it was found that, when the pile density is more than about 20,000 filaments/cm 2 , a good light-shielding can be achieved. In the case of conventional raschel fabrics, the limit of the number of pile roots is determined by the gauge. For example, when the maximum number in the cross direction is 9,4 roots/cm (24 roots/inch), that in the longitudinal direction is 25,6 roots/cm (65 roots/inch), and the number of the pile yarns per one root is two, the number of the pile yarn is 484 yarns/cm 2 (3120 yarns/inch 2 ). When a common 24 filament yarn is used as the pile yarn, the pile density is about 11,600 filaments/cm 2 . Thus, it is clear that a conventional light-shielding cloth does not have a sufficient light-shielding ability. The relation between the pile density and the light-shielding ability was further investigated, and the following conclusion was obtained. When Dp: pile density (number of filaments/cm 2 (inch 2 ) A: the number of stitches per cm(inch) in the longitudinal direction immediately after knitting B: the number of stitches per cm(inch) in the lateral direction immediately after knitting a: shrinkage ratio in the longitudinal direction of the ground fabric b: shrinkage ratio in the lateral direction of the ground fabric a,b=(x-y)/x x: the length before shrinking (the length immediately after knitting) y: the length after shrinking n: the number of pile yarns per one root f: the number of filaments composing the pile yarn, then the pile density is: Dp = A (1 - a) * B (1 - b) * n * f The pile density necessary for the light-shielding cloth is more than 20,000 filaments/cm 2 , and therefore, A (1 - a) * B (1 - b) * n * f > 20000 x 6,45 inch 2 (1 inch 2 = 6.45 cm 2 ) A good light-shielding ability can be obtained in the range satisfying the above inequality. The film container of the invention is provided with the above light-shielding cloth as the light-shielding member on the slit for extending a photographic film. As the means for satisfying the above inequality, there are the following methods: (1) The pile root density of A (1 - a), * B (1 - b) is increased. The pile root density can be increased by increasing the number of stitches A,B or increasing the shrinkage ratio a, b. However, since there is a limit for increasing the number of stitches, to increase the shrinkage ratio is effective. That is, a shrinkable yarn shrunk by heat or another energy is used as the chain yarn and the inlay yarn forming the ground fabric, and after knitting, the ground fabric is shrunk by adding the energy. (2) The number f of filament yarns composing the pile is increased. That is, a multifilament having a number of filaments per pile yarn of 40 to 100 is used as the pile yarn composing the pile. (3) The number of the pile yarns per one root is increased. (4) Combinations of the above (1) to (3). When a light-shielding cloth used in the invention is produced by shrinking the ground fabric, a knitted fabric containing pile yarn is formed. Then, the knitted fabric is shrunk in the longitudinal and lateral directions by an after-treatment of adding energy. Heat is used as the energy. In order to conduct appropriate heat treatment, it is necessary to select the heat-treating machine capable of shrinking the width of the ground fabric up to a prescribed width as well as shrinking in the longitudinal direction and capable of heat-setting so as to obtain a desired texture density and pile density of the ground fabric. As such a heat-treating machine, pin penter type heat setting machines are suitable. The temperature conditions for heat setting are set according to the properties of the fiber composing the ground fabric. For example, 160 to 190°C is suitable for a polyester fiber, and 150 to 180°C is suitable for a nylon fiber. In the case of shrinking the ground fabric by heat or the like, the yarn composing the ground fabric is be selected from multifilament yarns having a shrinkability to a certain degree which do not damage the light-sensitive membrane on the surface of the film. However, when the pile density is increased by shrinkage of the ground fabric alone, filament yarns having a shrinkage percentage in boiling water (JIS L-1073(1965) A methd) of more than 15 % are used. In the case of using a filament yarn having a shrinkage percentage of less than 15 %, the shrinking of the ground fabric is insufficient, and the object pile density cannot be obtained. As the filament yarn used for the ground fabric, those having a thickness of 30 to 150 denier is preferred, and the material may be a synthetic fiber or a chemical fiber. The multifilament yarn can be produced by a one step method wherein the filaments are made fine denier in the raw yarn process, a two step method wherein the filaments are made fine denier after the raw yarn process, such as by dissolving or by splitting, or the like. The knitting structure of the ground fabric may be any structure capable of forming set up piles on the surface of the ground fabric, including warp knitted structures, such as a pole tricot and a raschel fabric, and a weft knitted structure, such as a sinker pile. The pile yarn for forming the pile portion may be a conventional filament yarn, and a suitable thickness of the varn is 50 to 150 denier. The knitting machine for knitting the ground fabric is not necessarily a high gauge knitting machine, but a usual gauge knitting machine. The light-shielding cloth thus produced may be provided with a conventional after-treatment, such as dyeing, brushing and shearing, similar to conventional light-shielding cloths. The relation between the conventional light-shielding cloth and the drawing resistance of the film was also investigated, and it was found that, in the case of a conventional light-shielding cloth having a knitted structure, since the pile yarn was disposed in parallel to the upper and lower chain yarns, the ground fabric was rendered thick. The slit width was usually fixed, and therefore, the thickness of the pile portion was rendered small. This was a cause to increase the drawing resistance. Then, a further investigation was made,and it was found that the thickness of the ground fabric could be made thin by engaging the pile yarn with a sinker loop. Thus, a light-shielding cloth having a large ratio of the thickness of the pile portion could be obtained, and by using this light-shielding cloth, the drawing resistance could be reduced ensuring light-shielding ability. In the above light-shielding cloth, it is sufficient that the pile yarn passes between the needle loop and the sinker loop and is set up, i.e. the pile yarn is knitted only into the sinker loop in the form of a loop. The number of pile yarns passing the same part between the needle loop and the sinker loop may be one or plural yarns. The knitted structure may be various warp knitted structures or weft knitted structures as mentioned previously. In the case of a conventional warp knitted structure where the needle loop of the ground yarn is combined with the pile yarn, two or more needle loop portions of the ground fabric are necessary. However, in the case of the above knitted structure used in the invention, the needle loop portion of the ground fabric portion may be one. Therefore, the size of the loop can be made small, and as a result, a high density knitted structure is possible which is impossible in the case of a conventional structure. The fiber yarns composing the ground fabric portion and the pile portion may be made of various synthetic fibers, such as polyamide fibers, such as nylon fibers, polyester fibers, such as polyethylene terephthalate fibers, polyvinyl chloride fibers, polyacrylonitrile fibers, polyvinylidene chloride fibers, polyolefin fibers, such as polyethylene fibers and polypropylene fibers, and polyvinyl alcohol fibers, and natural or regenerated fibers, such as rayon fibers, cupra fibers, acetate fibers, cotton fibers, silk fibers and wool fibers, and various combinations of the above fibers. The fiber composing the ground fabric may be identical with or different from the fiber composing the pile portion. The above light-shielding cloth is dyed in a light-shielding color usually black by various known method. In the case of forming the pile portion by a combination of regular yarn and special yarn, the special yarn includes all yarns other than the regular yarn. Representative special yarns are described below: (1) Conjugated yarns wherein two components different in shrinkage percentage are made into one filament. (2) The yarns called highly bulky yarn, including the highly bulky yarns disclosed in Japanese Patent No. 62-9837 and the yarns formed in loops by twisting a thermally shrunk filament with an unshrunk filament followed by a shrinking treatment. (3) Loop yarns which are spun yarns forming a loop by winding a yarn in spiral on wadding, and setting by a twist setting yarn. (4) Fancy yarns such as chain yarns set a thick soft spiral yarn in chain by two yarns. (5) Knitted-deknitted yarns formed by once knitting the thermoplastic fiber for a pile, heat-treating and unlacing impart the fiber with crimps. Since the piles composed of the above special yarn described in (1) and (5) are entangled with surrounding piles formed of regular yarn by the crimp and setted up, each pile is resistant to falling down. Moreover, the piles are loosened to improve the light-shielding ability. In the cases of piles composed of the above special yarn described in (2), (3) and (4), when the piles are cut into a uniform thickness in the shearing process, each yarn is directed at random and loosened from the root. Therefore, the light-shielding ability is improved. The entangled form and the entangling method are not restricted; however, the following entangling methods are preferred. (1) Sufficiently brushed, and then heat-set with brushing or immediately after brushing. (2) In the dyeing process, thrown in the direction opposite to the liquid flow in a jet dyeing machine. By entangling through the above methods, the regular yarn is entangled with the special yarn, and set up. The entangled fabric has a small drawing resistance, and is excellent in light-shielding ability. A preferred blend ratio of the regular yarn to the special yarn is 3 : 1 to 9 : 1 in view of the fiber drawing resistance and the light-shielding ability. The fiber yarn composing the ground fabric and the pile portion can be selected from the aforementioned synthetic fibers, regenerated fibers, natural fiber and combinations thereof. Moreover, the fibers disclosed in Japanese Patent Nos. 62-286042 and 2-15254 can also be selected. The fiber composing the ground fabric may be identical with or different from the fiber composing the pile portion. The above light-shielding cloth is dyed in a light-shielding color usually black by various known method. Dense arrangement of the piles in the knitting direction of the ground fabric is preferred, because the light-shielding ability is improved. In order to prevent the contamination of photographic films from the dye used in the light-shielding cloth, after various investigations, it was found that, when the thermobleeding rate of the blue component is less than a particular value, i.e. 2.0 %, a contamination can be prevented. In this specification, the thermobleeding rate is determined as follows. A fabric woven using the same polyester fiber is dyed at 130°C for 60 minutes, and then completely reduced with washing. This fabric is used as the standard fabric, and the dyed amount of the dye is measured by solvent extraction from the standard fabric. Subsequently, the standard fabric is heat-treated at 160°C for 3 minutes, and the amount of the dissolved dye by washing with acetone is measured. The above amount of the dissolved dye is used as the amount of thermobleeding dye. The thermobleeding rate is (the amount of thermobleeding dye)/(the dyed amound of the dye). In general, black disperse dyes for dyeing black are composed of three components of a blue disperse dye, a red disperse dye and a yellow disperse dye, and the blending ratio of them is usually about 8 : 1 : 1. As the blue disperse dye having a thermobleeding rate of less than 2.0 %, there are C.I. Disperse Blue 120 having a thermobleeding rate of 1.6 %, C.I. Disperse Blue 60 having a thermobleeding rate of 1.8 % and the like. As to the dye components other than the blue disperse dye having a thermobleeding rate of less than 2.0 %, since the total amount is small compared with the amount of the blue disperse dye, the bleeding amount by thermobleeding is very small. Therefore, usual disperse dyes can be used as the other dyes. The blend ratio of the blue component: the yellow component: the red component is preferably 60-100 % : 20-0% : 20-0 %, and 90-98 % : 0.1-5 % : 0.1-5 % is particularly preferred. Suitable polyester fibers composing the light-shielding cloth include polyethylene terephthalate fibers, polybutylene terephthalate fibers, conjugate fibers of polyethylene terephthalate fiber and polybutylene terephthalate fiber, and the like. Other fibers suitable for composing the light-shielding cloth include silk, cotton, viscose rayon, cupra rayon, nylon and acetate. The light-shielding cloth is dyed black, and the color density value (L value) is preferably not more than 20 in order to ensure the light-shielding ability more completely. The above disperse dye can be applied to various woven and knitted fabrics having piles, such as velvet woven fabrics, raised tricot fabrics, sinker pile knitted fabrics and double raschel fabrics. The form of the filament composing the light-shielding cloth is also not limited, and filaments having various denier numbers and filament numbers, modified cross section yarns conjugated yarns, separated yarns, core shell yarns containing a dissimilar component and Sea Island fibers are applicable. A suitable thickness of the yarn is 50 to 200 denier, and a suitable thickness of a single yarn is 0.1 to 5 denier. A suitable number of filaments is 10 to 500 filaments. Dyeing and finishing of the light-shielding cloth may be conventional. In the case of a light-shielding cloth the entire or parts of which is formed of a synthetic fiber treated at least with an antistatic agent or an antistatic treatment having a resistance to washing with warm water, suitable antistatic agents having a resistance to washing with warm water include hydrophilic polymer compounds having a ionic group or a polyoxyalkylene group including: (1) Polyacrylate complex products containing quaternary ammonium. (2) Condensation products of sulfoisophthalic acid and an alkylene glycol. (3) Block copolymers of terephthalic acid or isophthalic acid and an alkylene glycol and a polyalkylene glycol. (4) Copolymers of a polyalkylene glycol dimethacrylate or a polyalkylene glycol diacrylate and polyamide diacrylate. The treatment of the light-shielding cloth with an antistatic agent is conducted so that the antistatic agent is fixed on the surface of the synthetic fiber. The treatment with the antistatic agent may be conducted at any process for manufacturing the light-shielding cloth, and the final process is preferred in order to obtain the greatest effect. As the treating method, there are the following two methods. or the like. Subsequently, the light-shielding cloth is heat-treated at a high temperature to fix the antistatic agent onto the fiber surface of the light-shielding cloth. A suitable heat treatment temperature is different according to the kind of antistatic agent and the like, and usually, about 150 to 190°C is preferred. The excess antistatic agent not being fixed is removed together with other components by washing. The washing is preferably conducted at 60 to 90°C for 5 to 10 minutes. If the washing treatment is omitted, the excess amount of the antistatic agent extracted with warm water and other components remain on the surface of piles. In the case that such a light-shielding cloth is provided on the slit, the antistatic agent not being fixed or other components are eluted by water evaporated and condensed during standing in a closed container at 40°C at 80 % RH for a long period through the contact of the piles with the photographic film, and reacted with the photographic emulsion on the film to form traces, called adhesion marks, after the development. As the actual procedure of the submerged exhaustion, the light-shielding cloth is immersed rotating in a prepared solution of the antistatic agent, and heated at 80 to 140°C for 10 to 70 minutes to fix the antistatic agent onto the fiber surface with exhaustion. A suitable fixed amount of the antistatic agent is about 0.1 to 5 % per the weight of the light-shielding cloth. As the antistatic treatment having a resistance to washing with warm water, there is a method of polymerizing a hydrophilic monomer directly to the polymer of polyester fiber by graft polymerization. Suitable hydrophilic monomers include acrylic acid, methacrylic acid, polyoxymethylene metacrylate ester and the like. The graft polymerization can be conducted using a prepared solution containing the hydrophilic monomer and a suitable catalyst by the following method: (i) Immersing or spraying-steaming polymerization or low temperature plasma polymerization-washing (ii) Submerged exhausion The actual procedure of the above methods conforms to the aforementioned procedures. Polymerization conditions are set such that the polymerization rate is maximum. A preferable polymerization degree is about 0.5 to 5 % as the weight increase rate per light-shielding cloth. Suitable synthetic fibers include polyester fibers, such as polyethylene terephthalate fibers and various modified fibers thereof, polybutylene terephthalate fibers and various modified fibers thereof, blend fibers of them and conjugated fibers of them, polyamide fibers and polyacryl fibers. The light-shielding cloths used in the invention are used as light-shielding members provided on the slit of various film containers. the inner linings for light-shielding of devices directing photosensitive materials. The film container has a structure capable of containing various films in a light-shielding state and extending the film from a slit, and preferred containers are those for containing various photographic photosensitive materials in the form of a sheet or a roll, such as color photograph printing papers, films and printing papers for computerized type-setting systems, JIS 135 type photographic films, heat-sensitive papers, photosensitive resin films and microfilms. As the method of attaching the light-shielding cloth to the film container, the light-shielding cloth is treated with filling, and a hot melt adhesive is coated. Then, the light-shielding cloth is cut into a prescribed size, and put on the position to adhere it. So, the light-shielding cloth is adhered by heat, ultrasonic wave, high frequency wave or the like. Other methods include using a filling adhesive having both roles of filler and adhesive, using a double face adhesive tape, and the like. In the light-shielding cloth satisfying the aforementioned formula, the pile density is more than a prescribed value, and leak of light through the slit can be prevented completely. In the light-shielding cloth wherein the pile yarn is passed between the needle loop and sinker loop of the ground fabric, the ground fabric can be made thin, and the thickness of the pile portion is made thicker. Therefore, the bounce impact force is small, and the film drawing resistance can be reduced with securing the light-shielding ability. The light-shielding cloth does not damage the film during extending and rewinding it. In the case of a light-shielding cloth using a combination of regular yarn and special yarn, the pile portion where the special yarn is entangled with the regular yarn reduces the bounce impact elasticity with securing the light-shielding ability. Therefore, the film drawing resistance can be reduced, the light-shielding cloth does not damage the film during extending and rewinding it. In the case of a light-shielding cloth using the special dye, the thermobleeding amount of the dye is little, and the film is not contaminated by the dye. In the case of a light-shielding cloth treated with the antistatic agent or treatment, the durability of antistatic ability is improved to prevent the generation of static marks for a long period without adversely affecting the photographic film. EXAMPLES Example 1 An example of the light-shielding cloth structure of the invention is illustrated in Figures 1 and 2. The light-shielding cloth was formed of a ground fabric 1 and a pile portion 2 knitted thereto. The ground fabric 1 was formed in a knitted structure of filament yarn 3 for the ground fabric composed of chain yarn and inlay yarn, and the pile yarn 4 of the pile portion 2 was knitted into the filament yarn 3 of the ground fabric 1. The raw yarn for the ground fabric 1 employed was a highly shrinkable filament yarn of 30 denier/18 filament polyester yarn having a shrinkage percentage in boiling water of 17 %. The raw yarn for the pile portion 2 was a semidull filament yarn of 100 denier/48 filament polyester yarn. They were knitted by a 22 gauge double raschel machine, and cut the pile portion 2 by the center to obtain a pile knitted fabric with plush on one side having 22 vertical rows (wales) and 46 horizontal rows (courses). Subsequently, the knitted fabric was heat-set by a pin tenter type heat setting machine. The machine conditions, such as the distance between pins and the delivery speed of the fabric, were set so that the knitted fabric can be shrunk freely in the longitudinal and lateral directions, and the heat set treatment was conducted at 190°C for 20 seconds. Then, the fabric was treated by usual processing, such as dyeing and shearing, to obtain a double raschel fabric having a total thickness of 1.5 mm, a pile length of 1.2 mm, 30 wales and 52 courses. In Figure 1, the distance between the wales was 0.85 mm, and the distance between the courses was 0.49 mm. Comparative Example 1 The raw yarn for the base fabric 1 employed was a semidull filament yarn of 30 denier/18 filament polyester yarn having a shrinkage percentage in boiling water of 6 %. The raw yarn for the pile portion 2 was a semidull filament yarn of 100 denier/48 filament polyester yarn. They were knitted and treated in the same manner as in Example 1, and a double raschel fabric having a total thickness of 1.5 mm, a pile length of 1.2 mm, 24 wales and 44 courses was obtained. In Figure 11, the distance between the wales was 1.05 mm, and the distance between the courses was 0.58 mm. Evaluation of Light-Shielding Ability The light-shielding cloths obtained in Example 1 and Comparative Example 1 were adhered to the slit of a container for a 35 mm photographic film by a conventional method, and the light-shielding ability was evaluated. The results are shown in Table 1. Texture Density Pile Density Light-Shielding Ability Example 1 52 courses/30 wales 46,400 filaments/cm 2 A Comparative 1 44 courses/24 wales 31,400 filaments/cm 2 B A: Fogged portion is shorter than 5 cm from the slot. B: Fogged portion is 5-10 cm from the slot. C: Fogged portion is longer than 10 cm from the slot. Examples 2-5 and Comparative Example 2 The light-shielding cloth of Example 2 was formed by using a heat shrinkable filament as the chain yarn and the inlay yarn and a general yarn as the pile yarn. The light-shielding cloth of Example 3 was formed by using a general yarn as the chain yarn and the inlay yarn and a multifilament yarn as the pile yarn. The light-shielding cloth of Example 4 was formed by using a heat shrinkable filament as the chain yarn and the inlay yarn and a multifilament yarn as the pile yarn. The light-shielding cloth of Example 5 was formed by using the same yarn as in Example 2, and the number of piles per one root was increased. Details of Examples 2-5 and Comparative Example 2 are shown in Table 2. Comparative Example 2 Pile Yarn 50 d/24 f Polyester Chain Yarn 75 d/24 f Shrinkable Polyester Inlay Yarn 75 d/24 f Shrinkable Polyester Knitting Machine Raschel Machine Gauge Number 22 Ground Density 8,7 wales/cm (22 wales/inch) at Knitting 23,6 courses/cm (60 courses/inch) Ground Density 9,4 wales/cm (24 wales/inch) after Drying 25,6 courses/cm (65 courses/inch) Pile Yarn Number/Root 2 Pile Density 11609 filaments/cm 2 Dye Black Disperse Dye 8 % owf d: denier f: filament Evaluation of Light-Shielding Ability JIS 135 type photographic film cartridges were prepared using the light-shielding cloths obtained in Examples 2-5 and Comparative Example 2 which were adhered to the slit, and a roll of a ISO 100 photographic color negative film (manufactured by Fuji Photo Film Co., Ltd.) was loaded in each cartridge. The slit width in the transverse direction was 2.1 mm. Each cartridge was exposed to light of 70,000 luxes for 3 minutes to the slit and both ends of the cartridge. The film was then developed, and the fogging degree was evaluated. The results are shown in Table 3. Light-Shielding Ability Example 2 B Example 3 B Example 4 A Example 5 B Comparative 2 C Example 6 An example of the light-shielding cloth structure used in the invention is illustrated in Figures 3 and 4. The light-shielding cloth was formed of a ground fabric 1 and a pile portion 2 knitted thereto. The ground fabric 1 was formed of a warp knitted structure composed of chain yarn 5 corresponding to the warp of knitted fabric and inlay yarn 6 combining chain yarns 5 corresponding to the weft of knitted fabric. The pile yarn 4 forming the pile portion 2 passed between the chain yarn 5 on the side of the pile portion 2 and the inlay yarn 6 to be formed in a loop, and it was projected from the ground fabric upward and set up. That is, the pile yarn 4 was fixed by the chain yarn 5. The pile yarn employed was 50 denier polyester yarn, and the chain yarn and the inlay yarn were 75 denier polyester yarn. A light-shielding cloth having a warp knitted structure shown in Figures 3 and 4 was prepared using a double raschel machine, and adhered to the slit of a JIS 135 type photographic film cartridge as the light-shielding member. Various properties of the light-shielding cloth are as follows: Total thickness: 1.7 mm Ground fabric thickness: 0.3 mm Pile density: 24,000 filaments/cm 2 A roll of a ISO 400 photographic film was loaded in the cartridge. The cartridge was exposed to light of 100,000 luxes for 10 minutes, and had a sufficient light-shielding ability. The drawing resistance was small, i.e. 120 g, and the surface of the photographic film was not damaged. The photographic film could be delivered smoothly in a camera. Moreover, the adhesion of fallen yarn and pile yarn dust to the photographic emulsion surface was rare. Conventional Example 1 The pile yarn, the chain yarn and the inlay yarn were the same polyester yarns as in Example 6. A light-shielding cloth having a knitted structure shown in Figure 12 was prepared using a double raschel machine, and adhered to the slit of a JIS 135 type photographic film cartridge as the light-shielding member. Various properties of the light-shielding cloth are as follows: Total thickness: 1.7 mm Ground fabric thickness: 0.5 mm Pile density: 24,000 filaments/cm 2 The same photographic film as in Example 6 was loaded in the cartridge, and the cartridge was exposed to light of 100,000 luxes for 10 minutes. Although the cartridge had a sufficient light-shielding ability, the drawing resistance was more than twice that of Example 6, i.e. 250 g and the surface of the photographic film was occasionally damaged. Sometimes, the photographic film could not be delivered in a camera. The results are summarized in Table 4. Examples 7-11 and Comparative Examples 3-6 An example of the light-shielding cloth structure used in the invention is illustrated in Figures 5 to 7. The light-shielding cloth was formed of a ground fabric 1 and a pile portion 2 knitted thereto. A filler layer 7 was provided under the ground fabric 1 for preventing the adhesive of an adhesive layer 8 from permeating the pile portion 2 as well as for preventing the yarns of the pile portion 2 from falling out of the ground fabric 1. The adhesive layer 8 was provided under the filler layer 7 for adhering the light-shielding cloth to the slit of the film container. The ground fabric 1 was, as shown in Figures 6 and 7, composed of chain yarn 5 corresponding to the warp of knitted fabric and inlay yarn 6 combinig chain yarns 5 corresponding to the weft of knitted fabric. The pile yarn 4 was knitted with the chain yarn 5 and set up to form the pile portion 2, and regular yarn 9 and special yarn 10 were used as the pile yarn 4. The row of the regular yarn 9 was provided in parallel to the row of the special yarn 10 in the knitting direction, and the ratio of the regular yarn 9 to the special varn 10 was about 3:1. The special yarn 10 was entangled with adjacent regular yarn 9. A JIS 135 type photographic film cartridge is shown in Figures 8 and 9. A roll of a photographic film 11 was wound around a spool 12, and loaded in the container body 13. A slit 14 was formed in parallel to the axial direction, and light-shielding cloth 15 was adhered to both insides of the tongue portions 16,16 of the slit 14 as the light-shielding member. The light-shielding cloths of Examples 7-11 and Comparative Examples 3-6 were prepared by a double raschel knitting machine using the pile yarns, the chain yarns and the inlay yarns shown in Table 5. Each light-shielding cloth was cut and attached to the JIS 135 type photographic film cartridge. Various properties of the light-shielding cloth are as follows: Total thickness: 1.7 mm Pile density: 38,000 filaments/cm 2 Slit width: 2.0 mm A roll of ISO 400 photographic film was loaded in each cartridge, and the drawing resistance and the light-shielding ability were measured in the same manner as the evaluation in Example 6. The developing agent used was "CN-16" manufactured by Fuji Photo Film Co., Ltd., and the light-Shielding ability was indicated as the round number of fogged part of the roll film evaluated by visual inspection. As shown in Table 5, in the cases of the light-shielding cloths of Examples 7-11, the drawing resistance was less than 200 g, and the round number of the fogged part was 0 or 1. Thus, by using the light-shielding cloth employed in the invention, inexpensive photographic film cartridges having a small drawing resistance and being excellent in light-shielding ability could be obtained. On the other hand, In the cases of Comparative Examples 3 and 5, although the round number of the fogged part was one, the drawing resistance was 300 g or 410 g. As a result, the photographic film could not be delivered, and abrasion occurred on the film surface. In the cases of Comparative Examples 4 and 6, the light-shielding ability was insufficient, and the round number of the fogged part was 3 or 4. The above results were graphed in Figure 10. In the figure, the abscissa indicates the ratio of the pile amount of the regular yarn to the pile amount of the special yarn, and the ordinate indicates the drawing resistance and the fogged length. The full line indicates the graph of the drawing resistance, and the broken line indicates the length of the fogged part. The oblique line part indicates a practically possible range wherein the drawing resistance was not more than 180 g and the fogged part was not more than 1 round. In this range, it does not occur that the photographic film cannot be delivered in a camera or that the photographic film is damaged. As shown in Figure 10, the light-shielding cloths of Examples 7-11 are within the above practical range, whereas, the light-shielding cloths of Comparative Examples 3-6 are out of the range. Example 12 A light-shielding cloth composed of polyester fiber was immersed in a treating solution containing 10 g/ℓ of 15 % aqueous suspension of terephthalic acid/ethylene glycol/polyethylene glycol copolymer and 0.1 g/ℓ of anionic dispersing agent, and treated at 120°C for 30 minutes. The light-shielding cloth added with the above antistatic agent was adhered to the slit of a JIS 135 type photographic film cartridge in the conventional manner, and a roll of a ISO 400 photographic film was loaded in the cartridge. The cartridge was allowed to stand at 80°C for 20 hours, and the film was developed in a conventional method. An abnormality in the light sensitivity of the film portion contacted with the light-shielding cloth was observed. Example 13 A light-shielding cloth composed of a polyester fiber was impregnated with an aqueous suspension composed of 4.0 % methacrylic acid/0.1 % redox catalyst/2.0 % fiber swelling agent uniformly in an amount of 70 % by weight of the light-shielding cloth, and a steaming polymerization was conducted at 100°C for 10 minutes. Then, the light-shielding cloth was washed at 80°C for 10 minutes. The light-shielding cloth treated with the antistatic finish was incorporated into a photographic film cartridge similar to Example 12, and exposed to a high temperature similar to Example 12. Then, the abnormality in the light sensitivity of the film portion contacted with the light-shielding cloth was observed. Comparative Example 7 A light-shielding cloth composed of a polyester fiber was impregnated with an aqueous solution of 1.0 % quaternary ammonium cationic surfactant being a common antistatic agent, and dried at 100°C for 3 minutes. Then, the light-shielding cloth was heat-treated at 150°C for 3 minutes. The light-shielding cloth added with the antistatic agent was incorporated into a photographic film cartridge similar to Example 12, and exposed to a high temperature under similar conditions. Then, the abnormality in the light sensitivity of the film portion contacted with the light-shielding cloth was observed. The results of the above evaluation tests are summarized in Table 6. Example 14 A double raschel fabric pretreated with conventional treatments, such as degumming and heat treatment, was dyed it a disperse dye of C.I Disperse Orange 30-0.3 %, C.I Disperse Red 167-0.1 % and C.I. Disperse Blue 120 (bleeding rate of 1.6 %)-8.0 % owf using 0.4 g/ℓ of a dispersing agent of "Sunsoft RM-340" (manufactured by Nikka Kagaku K.K.) in a bath ratio of 1 : 30 at 130°C for 60 minutes, followed by washing and then drying. The dyed fabric was treated by conventional treatments, such as brushing and spearing, to obtain a light-shielding cloth colored black having a color density value (L value) of 18.3 and a high pile density on the surface. The light-shielding cloth thus obtained was adhered to the slit of a JIS 135 type photographic film cartridge in a conventional manner, and a roll of a ISO 400 photographic film was loaded in the cartridge. The cartridge was allowed to stand at 80°C for 20 hours, and the film was developed in a conventional method. The contamination of the film portion contacted with the light-shielding cloth was observed. A part of the cartridge samples was divided, and the contamination of the film portion contacted with the light-shielding cloth was observed prior to the development. Another part of the cartridge samples was exposed to light of 100,000 luxes for 10 minutes, and the light-shielding ability (fogged degree) was evaluated after the development. Example 15 Using C.I. Disperse Orange 30-0.3 %, C.I. Disperse Red 167-0.1 % and C.I. Disperse Blue 60 (bleeding rate of 1.8 %)-10.0 % owf, a light-shielding cloth colored black having a color density value (L value) of 19.0 and a high pile density on the surface was obtained in a method similar to Example 14. As to the above light-shielding cloth, the film contamination and the light-shielding ability were measured by the same method as in Example 14. Comparative Example 8 Using C.I. Disperse Orange 30-0.3 %, C.I. Disperse Red 167-0.1 % and C.I. Disperse Blue 139 (bleeding rate of 3.8 %)-6.0 % owf, a light-shielding cloth colored black having a color density value (L value) of 16.0 and a high pile density on the surface was obtained in a method similar to Example 14. As to the above light-shielding cloth, the film contamination and the light-shielding ability were measured by the same method as Example 14. Comparative Example 9 Using C.I. Disperse Orange 30-0.3 %, C.I. Disperse Red 167-0.1 % and C.I. Disperse Blue 60 (bleeding rate of 1.6 %)-3.0 % owf, a light-shielding cloth colored gray having a color density value (L value) of 31.0 and a high pile density on the surface was obtained in a method similar to Example 14. As to the above light-shielding cloth, the film contamination and the light-shielding ability were measured by the same method as in Example 14. The results of the above evaluation tests are summarized in Table 7. In the case of Examples 14 and 15, the thermobleeding rate of the blue component of the disperse dye was less than 2.0, and the color density value (L value) was less than 20. The light-shielding ability as well as the contamination were very good. Whereas, in the case of Comparative Example 8, the thermobleeding rate of the blue component was beyond 2.0, and contamination traces were observed in the samples irrespective of before or after the development. In the case of Comparative Example 9, the color density value (L value) was beyond 20. and the light-shielding ability was insufficient.

Claims: A film container (13) which is provided with a light-shielding cloth as a light-shielding member on the slit for extending a photographic film (11), said cloth having a ground fabric (1) and a pile portion (2) formed of pile yarns (4) knitted thereto, characterized in that the pile density of the light-shielding cloth satisfies the following formula: A (1 - a) * B (1 - b) * n * f > 19995 filaments/cm 2 (129000 filaments/inch 2 ) wherein A: the number of stitches per cm(inch) in the longitudinal direction immediately after knitting B: the number of stitches per cm(inch) in the lateral direction immediately after knitting a: shrinkage ratio in the longitudinal direction of the ground fabric (1) b: shrinkage ratio in the lateral direction of the ground fabric (1) a,b=(x-y)/x x: the length before shrinking (the length immediately after knitting) y: the length after shrinking n: the number of pile yarns (4) per one root f: the number of filaments composing the pile yarn (4) said yarn forming said ground fabric (1) being a highly shrinkable yarn having a shrinkage percentage of more than 15% or being a multifilament yarn. The film container (13) of claim 1 wherein said pile yarns (4) have been set up by passing same between the needle loop and the sinker loop. The film container (13) of claim 1, wherein said pile portion (2) is formed of regular yarn and special yarn entangled with each other. The film container (13) of claim 1 wherein said light-shielding cloth comprises polyester yarn being dyed black with a blend dye containing a disperse dye as the principal component, the thermobleeding rate of the blue component being less than 2.0%. The film container (13) of claim 4, wherein the light-shielding cloth has a color density L which is not more than 20. The film container (13) of claim 1, wherein the light-shielding cloth comprises a synthetic fiber being treated with an antistatic agent or by an antistatic treatment having a resistance to washing with warm water. The film container (13) of claim 6, wherein said resistance to washing with hot water is such as to keep a fixation rate of more than 80% after washing at 60°c for 10 minutes. The film container (13) of claim 6, wherein said synthetic fiber is a polyester fiber.

Inventors: ISE JUN, MIZUNO KAZUNORI, SUEHARA KAZUYOSHI, SUZUKI TOKIHIDE, TAKAHASI KOICHI, TOMODA MASAZUMI, ISE, JUN, MIZUNO, KAZUNORI, SUEHARA, KAZUYOSHI, SUZUKI, TOKIHIDE, TAKAHASI, KOICHI, TOMODA, MASAZUMI, ISE, JUN, C/O FUJI PHOTO FILM CO., LTD., MIZUNO, KAZUNORI, C/O FUJI PHOTO FILM CO., LTD., SUEHARA, KAZUYOSHI, C/O FUJI PHOTO FILM CO., LTD., SUZUKI, TOKIHIDE, C/O SEIREN CO., LTD., TAKAHASI, KOICHI, C/O FUJI PHOTO FILM CO., LTD., TOMODA, MASAZUMI, C/O SEIREN CO., LTD.
Applicants: FUJI PHOTO FILM CO LTD, FUJI PHOTO FILM CO., LTD.
Application year: 1991
Main classification: D04B21
IPC codes: G03C3, D04B21, G03B17