TWO-PHASE COSMETIC COMPOSITION

Abstract: This invention refers to cosmetic compositions, particularly a skin treating preparation, comprising a transparent oil phase and a transparent aqueous phase, preferably with humectant effect, which permits a homogeneous mixture when being shaken, and which separates again in two transparent phases thereafter. These properties are achieved by the addition of 0.1 to 1.0% by weight of a C₁₂-C₁₈ fatty acid triglycerol ester.

Description: This invention refers to a liquid cosmetic composition consisting of two separate phases, especially a skin or hair care preparation. Two-phase skin care preparations, especially emulsions, are known per se, see for example DE-PS 3 627 313. These products are either available in an opaque form and/or are mixed by shaking before application onto the skin. If one or both phases are of transparent nature, they quickly separate again after shaking or application onto the skin so that the product cannot penetrate into the skin, or the phases remain permanently mixed in an opaque emulsion after application. The present invention starts from the problem to develop a cosmetic composition, particularly a skin care preparation consisting of two separate transparent phases which, when mixed and shaken, for a certain time form a homogeneous phase by partial emulsification, that may be applied homogeneously onto the skin and that separates again into two different transparent phases afterwards. The solution of this problem is the addition of a small quantity of a C₁₂-C₁₈ fatty acid monoester of triglycerol to a cosmetic composition, particularly a skin treatment preparation consisting of a transparent fat and oil phase and of a transparent aqueous phase, preferably containing one or more humectant substances. It was surprising and not foreseeable that, just by the use of these substances, a homogeneous but non-stable emulsion can be achieved by mixing the originally separate oil and water phases which completely disintegrate again after a short period of time (approx. 5 to 10 minutes). Particularly triglycerol monolaurate, triglycerol monostearate or isostearate, triglycerol monooleate or also fatty acid mixtures such as triglycerol monococoate, used in a proportion of 0.1 to 1%, especially 0.2 to 0.5 by weight, have proved to be suitable C₁₂-C₁₈ fatty acid monoesters of triglycerol. A particularly preferred monoester of triglycerol is triglycerol monolaurate (Polyglyceryl-3-laurate), The fat and oil phases whose proportion in the total skin treatment composition is 20 to 40% by weight, preferably approx. 25% by weight, may comprise those fats and oils usually applicable in skin care preparations. As such are mentioned: squalene and its synthetic substitutes, vegetable oils such as olive, avocado, jojoba, sesame, wheat germ, soybean, peanut, almond oils and also paraffin oil, fatty acid ester such as decyl oleate, isopropyl myristate or ethyl isostearate, fatty alcohols such as dodecanol, fatty acid diglycerides and triglycerides, silicones, etc. The aqueous phase of a skin treatment composition, whose preferred proportion then accordingly is from 80 to 60% by weight, contains one or more skin humectants besides the triglycerol monofatty acid esters, as defined above. These are wellknown to the expert, e.g., urea, amino carboxylic acids and their mixtures and compounds, e.g., the so-called "NMF" (natural moisturizing factor), protein hydrolyzates, pyrrolidone carboxylates, sugar-amino acid condensates and also special plant extracts. Humectants are usually added in a proportion of 1 to 5, preferably 2 to 4% by weight, with reference to the total skin treatment composition. The skin care preparations of this invention may comprise all usual agents and auxiliary substances which are, depending on their solubility, added either to the oil or fat phase or to the aqueous phase. Those substances familiar to an expert are, e.g., water-soluble and fat-soluble vitamins, plant extracts, ultraviolet absorbers, dyestuffs, blood circulation stimulating agents, preservatives, solvents and diluents such as glycerol and diols, buffer substances, refattening substances, surface-active substances, perfume oils, etc. The pH value of skin treatment compositions of the invention is preferably set within the slightly acidic range of between 5 and 7. The following is an example of the composition of a skin care preparation in accordance with this invention: 1. Oil phase: Squalene 14.00% by weight Silicone oil 2.00 Fatty alcohol 3.00 Fatty acid triglyceride 4.00 Jojoba oil 2.00 Blue dyestuff 0.005 UV absorber 0.01 2. Aqueous phase When filling into transparent bottles, the composition develops two separate, clear phases. By way of shaking, these phases mix to become homogeneous, and they disintegrate again after a standing period of approximately 8 to 10 minutes. A substitution of the triglycerol monolaurate by the same quantity of a) polyethylene glycol-7-glyceryl cocoate, b) polyethylene glycol-40 hydrogenated castor oil, c) polyethylene glycol-60 hydrogenated castor oil, d) polysorbate 80 e) polyethylene glycol-9 tridecylether, f) polyethylene glycol-5 octanoate, and g) polyethylene glycol-5 lauryl ethoxylate-7, which are also well-known standard emulsifiers or solubilizers, did not lead to phases that are homogeneously miscible, nor to those which disintegrate again into clear phases after having been mixed. A liquid hair treatment composition was prepared comprising two separate phases: Phase 1: Silicone oil 24.2% (by weight) Jojoba oil 0.4% Phase 2: Triglycerol monolaurate 0.1 - 0.5% (by weight) 0,2M Citric acid (in water) 3.9% 1M Sodium chloride (in water) 4.0% Water ad 100.00%

Claims: A two-phase cosmetic composition comprising two separate transparent phases that form a homogeneous phase when mixed by shaking and which separates thereafter again into two different transparent phases, consisting of a transparent fat or oil phase and of a transparent, aqueous phase, containing 0.1 to 1.0% by weight, calculated to the total composition, of a C₁₂-C₁₈ fatty acid monoester of triglycerol. Cosmetic composition according to claim 1, containing 0.1 to 1.0% by weight of the total composition of triglycerol monolaurate, triglycerol monococoate, triglycerol monostearate or triglycerol isostearate and/or triglycerol monooleate. Cosmetic composition according to claim 2, containing 0.2 to 0.5% by weight of the total composition of triglycerol monolaurate. Skin treatment composition according to one or more of the preceding claims, comprising 20 to 40% by weight of a transparent fat or oil phase and 80 to 60% by weight of a transparent, humectant-containing aqueous phase. Skin care composition according to claim 4, characterized by a pH value between 5 and 7.

Inventors: GOERING, STEFAN, DR., KOSS, CLAUDIA, Göring, Stefan, Dr.
Applicants: GOLDWELL AKTIENGESELLSCHAFT
Application year: 1991
Main classification: A61K7
IPC codes: A61K8, A61Q5, A61Q19