Preproofed, frozen croissants

Abstract: Excellent, preproofed, frozen croissants are obtained, when a flour is used, that shows the following characteristics: 1. resistance against stress of a lean dough made from the flour is nearly independent on the resting time. 2. it imparts to a lean dough that is kneaded and rested during 40 mins an SDS-insoluble fraction that is less than 50% compared with the SDS insoluble fraction of the flour. 3. Protein content of at least 13 wt%. 4. HMW-sub-units of glutenin fraction, according to Payne: nos. 2*, 7+9, 5+10.

Description: In literature many attempts to come to a preproofed, frozen croissant with good product properties are described. E.g. in EP 114 450 a method is given in which a yeast-containing dough is prepared at ambient temperature, the dough is prefermented at 20-30°C for a short period, the dough is separated in portions, which are formed, after which the formed dough portions are fermented in such a way, that when the frozen dough is heated a volume increase of the dough is obtained, however the specific volume of the dough should remain less than 3.08 cm³ per gram, than the dough is frozen and stored. In EP 114 451 it is disclosed, that including an exogenous quantity of a water-soluble C₁-C₃ monohydric alcohol in the dough before freezing leads to a better preproofed, frozen product. In EP 115 108 it is stated, that the protein content of the flour after adding of gluten or wheat-protein, used for preparing the dough, should be at least 16 wt% based on a flour with 14% moisture. In US 4 406 911 it is said, that it is important that the specific volume of the dough portions is 1.98-3.08 cm³/g, whereas the freezing is performed in such a way, that the core temperature reaches -1.0 to - 25.0°C within 1-6 hours. According to US 4 450 177 it is only essential to reach the right core temperature during freezing (-1 to -25°C). In US 4 839 178 the use of skim milk and acid whey solids is prescribed, when the starting flour has a protein content of 11.5-12.5 wt%. In EP 353 036 a process is described for the preparation of dough, wherein a prefermentation (resting step) is carried out at temperatures ranging from 0-16°C. All processes, described above, however do not lead to products, which show the required properties for a preproofed, frozen croissant. And in case the properties of the preproofed, frozen croissants are close to what is considered as desirable, a very specific process with all its limitations must be carried out. We have looked for a process and products that overcome the above mentioned disadvantages. We have found, that the quality of the flour is the most important factor, that is decisive for the properties of the desired preproofed frozen dough. In fact we have found, that the best results are obtained when a flour is used, that meets the following four requirements: 1) it gives a lean dough, made from that flour, a resistance against stress D r (in Brabender units Bu) that is after 90 mins resting time less than 20% greater than the D r -value after 45 mins resting time. This D r -value is measured according to ICC-standard No. 114. A flour, that provides a dough in which D r increases less than 20%, when comparing the D r -values at resting times of 45 and 90 minutes gives excellent results. Preferably this increase in D r is less than 15%, more preferably less than 5%. 2) The protein content of the flour must be at least 13 wt%, preferably 13-16 wt%, more preferably 14-15 wt%, based on a flour with 14% moisture. 3) Another important characteristic of the flour, that can be used according to the invention, is the amount of glutenin protein, that becomes insoluble in an SDS-solution after kneading of a lean dough made from this flour after increasing resting times of the dough. During the kneading of the dough a breakdown of the glutenins occur. During the resting time of the dough after kneading part of these (broken) glutenin fragments reassemble. We have found, that the best preproofed, frozen croissants are obtained, when the reassembly of the glutenins is not too high. Therefore the preferred flours, that we use impart to a lean dough that is kneaded and rested for about 40 mins an SDS-insoluble fraction that is less than 50% compared with the SDS insoluble fraction in the flour, in particular less than 30%, most preferably less than 15%, but more than 10%. The SDS-insoluble fraction is measured according to the method of A. Graveland, c.s. Biochem and Biophys. Res. Comm. 93 (4) 1980, pages 1189-1190. 4) The glutenin fraction of the flour must contain the following HMW-sub-units: 2*, 7+9, 5+10 according to the classification method described by Payne and coworkers in Phil. Trans. R. Soc. London B (1984) 304 , 359-371. According to this method an SDS-polyacrylamide electrophoresis is made and the bands that appear are numbered in accordance with Payne's numbering system. An example of a flour that is in accordance with the above mentioned requirements is a Canadian flour derived from Canadian Western Red Spring wheat (CWRS). Although the dough making ingredients, that can be used according to our invention, comprise the known ingredients, we have found, that the best results are obtained when we use a bread improver-composition that is free of cysteine. The particle size distribution of the flour particles is such, that less than 45% of the particles is more than 100 µm, preferably less than 35% of the particles is more than 100 µm, whereas 35-50% of the particles have a particle size of 60-100 µm, preferably 40-45% of the particles have this size. The particle size is measured according to sieve methods. The flour preferably has a dry gluten content of more than 14%. The preproofed frozen croissant according to the invention can be made by any known croissant making process. However, the best results are obtained, when a dough is made at about 14-18°C from the normal dough making ingredients including yeast, but using a flour according to the invention. The ingredients are mixed at 14-18°C. The dough is subjected to an initial fermentation for a short time, preferably 5-15 mins. To the dough up to 15% of scrap dough (based on the flour present) can be added. The dough is laminated, using a fat that matches the consistency of the dough at 18°C. The lamination is carried out at about the same temperature as applied during the preproof step. The laminated dough is cut and formed into the desired shape. The formed dough portions are fully proofed at 25-36°C during 20-120 min. and 70-90% humidity. The products so obtained are frozen at a temperature of less than -10°C, preferably using a cooling rate of more than 0.5°C per minute. The frozen, preproofed croissants are packed and stored at less than -18°C. The frozen, preproofed croissants so obtained can be baked in an oven without the necessity of thawing. The croissants obtained after baking show an excellent specific volume and a very homogeneous layered structure. The dough can contain normal ingredients used in the dough making for croissants. Examples of such ingredients are: breadimprover composition containing e.g. ascorbid acid, DATA-esters and/or enzymes, but also salt, sugar, egg, flavours etc. Examples: A. Samples of the flour types mentioned in table I were analysed for the composition of high mol. weight sub (= HMW) we used the numbering system described by Payne. We found that good preproofed frozen croissants could only be obtained from flours, wherein the following HMW-sub-units are present: 2*, 7+9, 5+10. B. Lean doughs were made using the flours mentioned in table I. The resistance against stress (Dr in BU) of those lean doughs were measured after resting times of 45 and 90 min. Herefore the method according to ICC standard No. 114 was used. From the data so obtained the increase in Dr was calculated as a function of the resting time. The results are mentioned in table II. C. Lean doughs were made using the flours mentioned in table I. The SDS-insoluble glutenin fractions of the doughs and the flour were measured after a resting period of 40 min. Herefore the method of A. Graveland c.s., Biochem and Biophys. Res. Comm. 93 (4) 1980, pages 1189-1190 was used. From the data so obtained the ratios between the SDS-insoluble glutenin fractions were calculated. The results are mentioned in table III. D. Preproofed, frozen croissants were made using the flours mentioned in table I. Herefore the components mentioned in table IV were mixed at 16°C. The dough was prefermented during 10 min. This initially prefermented dough was laminated with fat (28% on dough) at 18°C. The laminated dough was cut and formed in the shape of a croissant. The shaped product was fully proofed at 32°C for 90 min (Rel. Hum 80%). The products so obtained were frozen at -18°C and stored at this temperature for a week. After this week the frozen croissants were baked without thawing. The results mentioned in table V were obtained.

Claims: Preproofed frozen croissant, made from a dough in which the normal dough making ingredients are present, characterised by the presence of a flour in the dough making mixture that meets the following requirements: 1) it gives a lean dough a resistance against stress (D r in BU) that is after 90 mins resting time less than 20% greater than the D r -value after 45 mins resting time. 2) it contains at least 13 wt% protein (based on flour with 14% moisture), 3) it imparts to a lean dough, that is kneaded and rested during about 40 mins an SDS-insoluble fraction, that is less than 50% compared with the SDS-insoluble fraction of the flour. 4) the glutenin-fraction of the flour contains the following high molecular weight sub-units, according to Payne: 2*, 7+9, 5+10. Preproofed frozen croissant according to claim 1, wherein the flour is a flour that gives a lean dough a D r -value at 90 mins resting time that is less than 15%, preferably less than 5% greater than the D r -value at 45 mins resting time. Preproofed frozen croissant, according to claim 1, wherein the dough is made from a flour with a protein content of 13-16 wt%, preferably 14-15 wt%. Preproofed, frozen croissant, according to claim 1, wherein the dough is made from a flour with a particle size distribution, so that less than 45%, preferably less than 35% has a particle size of more than 100 µm, whereas 35-50%, preferably 40-45% of the particles have a size of 60-100 µm. Preproofed, frozen croissant, according to claim 1, wherein the dough is made of a flour with a dry gluten content of more than 14%. Preproofed frozen croissant according to claim 1, wherein the flour imparts to a lean dough that is kneaded and rested during about 40 mins an SDS-insoluble fraction, that is less than 30%, in particular less than 15%, but more than 10% compared with the SDS-insoluble fraction of the flour. Preproofed, frozen croissant according to claim 1, wherein the dough is made from a Canadian Western red spring flour (= CWRS). Preproofed, frozen croissant according to claim 1, wherein the dough is made from dough making ingredients, that do not contain cysteine. Process for the preparation of preproofed, frozen croissants according to claim 1 consisting of the following steps: mixing of the normal dough ingredients, including yeast at 14-18°C, but using a flour as mentioned in claim 1. giving an initial fermentation to the dough for a short time at a maximum temperature of 18°C. laminating and forming the dough at nearly the same temperature. proofing the formed dough portions at 25-36°C during 20-120 mins. freezing the dough portion below -10°C, using a cooling rate of more than 0.5°C per min. storing the frozen, preproofed croissants below - 20°C. Baked croissants, obtainable after baking of the preproofed, frozen croissants of claims 1-8.

Inventors: ARMFIELD DUNCAN JAMES, GRAVELAND ARIS VLAARDINGEN LAB, KING DAVID MICHAEL, ARMFIELD, DUNCAN JAMES, GRAVELAND, ARIS, VLAARDINGEN LAB., KING, DAVID MICHAEL
Applicants: UNILEVER NV, UNILEVER PLC, UNILEVER N.V.
Application year: 1991
Main classification: A21D6
IPC codes: A21D6, A21D13, A21D10, A21D2