Cleaning blade and producing method thereof

Abstract: A cleaning blade (20) comprising a base member composed of rubber, and a resin layer (25) formed on the base member. In the preferred arrangements discussed the rubber is a silicon rubber and the resin is a fluorinated resin, e.g. polyvinylidene fluoride. The resin (30) may be dispersed in the rubber in course of and to facilitate manufacture.

Description: BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to a cleaning blade for use in an image forming apparatus such as an electrophotographic copier, a printer, a facsimile apparatus or the like, and more particularly to a cleaning blade to be maintained in contact with the surface of an image bearing member to be cleaned thereby removing the toner remaining on said surface, and a producing method therefor. Related Background Art In an image forming apparatus designed to repeat a process of transferring a toner image, formed on the surface of an image bearing member, onto a transfer material such as paper, it is desirable to completely eliminate the untransferred toner remaining on said member after each transfer process, in order to prevent the smearing of the image by the remaining or residual toner at the next transfer process. For this purpose there is widely employed so-called blade cleaning method in which an edge of high precision formed with rubber elastomer is maintained in uniform contact with the surface of the image bearing member to slide on said member, thereby removing the toner remaining thereon. Said rubber elastomer is generally composed of urethane rubber, and thermosetting liquid urethanes are particularly preferred in consideration of the superior abrasion resistance thereof. However, the cleaning blade composed of urethane rubber generates, because of a high friction coefficient of the urethane rubber, a very high friction force between the blade and the image bearing member in the initial stage of sliding motion when the toner is absent therebetween. Consequently the cleaning blade of urethane rubber may be inverted as indicated by broken lines in Fig. 3 or may bounce on the image bearing member in the initial stage of sliding motion, thereby becoming unable to remove the remaining toner. In consideration of such situation, there has been proposed and employed a method of reducing the frictional force between the urethane rubber and the image bearing member in the initial stage of the sliding motion, by coating the end portion of the cleaning blade of urethane rubber or the surface of the image bearing member with lubricating powder of fluorinated resin such as polyvinylidene fluoride (PVDF) or polytetrafluoroethylene (PTFE) (hereinafter represented as "lubricant"). However, excessive use of such lubricant may result in smearing of the developing unit or the charging unit, or may deteriorate the image quality because of electrical properties of such lubricant. It is therefore necessary to obtain uniform coating with a minimum possible amount, but such coating is technically difficult to realize and the obtained blade cannot be fully reliable with respect to blade inversion or bouncing, due for example to fluctuation in the coating. In order to resolve this drawback, Japanese Laid-open Patent No. 61-48881 proposes to disperse the lubricant in the urethane rubber material. However, in a simple dispersion system, the lubricant only appears locally on the surface as shown in Fig. 4, and the inversion or bouncing of the blade cannot be completely prevented as the urethane rubber used as the matrix considerably influences the behavior. Besides this, thermosetting liquid urethanes are unsuitable for mass production, since they require a long reaction time for thermosetting and have high reactivity with moisture in the air. On the other hand, a rubber material of low friction resistance and short reaction time, for example silicone rubber with satisfactory stability in ambient conditions, is effective for preventing blade inversion or bouncing and is suitable for mass production. However silicone rubber is easily abraded and cannot be used for a long time, since the blade edge is abraded by the friction with the image bearing member or with the toner. Cleaning blades comprising coated rubber members are described in DE-A-2410842 and DE-A-2324749. These include blades of silicone rubber material and coatings including epoxy resin, polyvinylidene fluoride, or other resins. Cleaning blades comprising rubber material and dispersed resin are described in EP-A-0435342 and EP-A-0384354, each of which is mentioned with reference to Article 54(3)EPC. In particular, EP-A-0435342 describes blades of silicone rubber which may include a fine organic resin powder such as polyethylene, nylon, or fluorine-type resin. A process is described in which an inorganic silicon powder filler is mixed with rubber material, which is then moulded and cured. EP-A-0384354 describes cleaning blades of polyurethane rubber containing a dispersion of graphite fluoride powder. These are compared with blades of polyurethane rubber containing fluorocarbon resin. The latter are prepared by mixing fluorocarbon resin powder in heat melted urethane prepolymer, adding curing agents, casting in a mould and curing by heating. SUMMARY OF THE INVENTION The present invention is intended as a solution to the problems aforesaid. In accordance with a first aspect of the present invention there is provided a cleaning blade comprising: a base member of rubber in which a resin powder is dispersed; characterised by: a resin layer disposed on at least the end face and contact face of said base member, which resin layer consists of said resin powder fused at the surface of said base member. In accordance with a second aspect of the present invention there is provided a method for producing the cleaning blade of claim 1, which method comprises the following steps: (a) dispersing resin powder in a rubber material; (b) moulding said rubber material containing dispersed resin powder; and (c) vulcanising the moulded rubber material; which method is characterised in that: said step (c) of vulcanising the moulded rubber material is performed at a temperature higher than the melting point or the softening point of said resin powder thereby to produce a resin layer of resin powder fused at the surface of the moulded rubber. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional view of a cleaning blade embodying the present invention; Fig. 2 is a chart showing the relationship between the contact pressure of the blade and the friction resistance thereof; Fig. 3 is a schematic view showing an inversion phenomenon of the blade; Fig. 4 is a schematic view showing fine particles dispersed in the blade; and Fig. 5 is a schematic view showing a contacting part between the blade and the image bearing member. DESCRIPTION OF THE PREFERRED EMBODIMENTS Now the present invention will be clarified in detail by preferred embodiments thereof. The present inventors have found that the friction coefficient between the contacting surface of the image bearing member with the cleaning blade and an edge forming surface of said blade has a significant influence on the aforementioned inversion or bouncing of the blade, and also on the abrasion or chipping-off of the edge of the blade. More specifically, referring to Fig. 5, if an edge portion 20 of the cleaning blade tends to be turned over while the image bearing member 1 is in motion, a face 22 adjacent to a contacting face 21 of said blade comes into direct contact with said image bearing member 1, thus leading to blade inversion or blade bouncing. Also abrasion or chipping-off of the edge 20 is principally caused by stress concentration on the face 22 showing such turning-over. Consequently, in order to prevent inversion, bouncing, abrasion and chipping-off of the blade, in addition to the prevention of the above-mentioned turning-over phenomenon by a reduction in the friction coefficient of the contact face 21, it is also very effective to reduce the friction coefficient of the face 22 which comes into contact with the image bearing member when the blade tends to be turned over. The present invention is based on the novel concept mentioned above. In an embodiment of the present invention, fine particles of lubricating resin, which is not mutually soluble with rubber, are dispersed in a normally liquidous rubber material, and then a rubber member of a desired shape is produced from said rubber material by moulding the same in a mould Said moulding of the rubber material is conducted in a condition where said fine particles are not molten but remain dispersed, under a temperature condition T1 < T10 < T2, wherein T1 is the primary vulcanizing temperature at which the moulding is conducted, T2 is the heat resistance of the rubber member (corresponding to the decomposition temperature of the constituent molecules, determined in DSC (differential scanning calorimetry) measurement), and T10 is the melting point or softening point (measured by ring-ball method) of the fine particles. The condition T1 < T10 is preferred for maintaining the uniformly dispersed state of the resin particles in the rubber at the molding operation, since, if the rubber moulding temperature T1 is selected equal to or higher than T10, the fine particles dispersed in the rubber material are fused at the moulding operation so that the mixing state becomes undefined for example depending on stress during the moulding operation. Thus a moulded rubber member, containing fine particles dispersed therein, can improve the abrasion resistance when said member is composed of easily abraded silicon rubber. Therefore improved cleaning ability can be achieved in comparison with the case without such fine particles. Then thus obtained rubber member is subjected to a secondary vulcanizing, by heating in an oven at a temperature T20, satisfying a condition T10 < T20 < T2. In this operation, the fine particles 30 dispersed at the surface or in the vicinity thereof are fused, thus covering the surface as shown in Fig. 1 because of the lack of mutually solubility with the rubber material, and form a surfacial layer 25 upon subsequent cooling. As a sufficiently thick resinous coating layer is formed particularly on the face 22′ which comes into contact with the image bearing member when the blade starts to turn-over, abrasion or chipping-off of the blade can be prevented even if the blade does turn over. As the surface coating of the cleaning blade is achieved by the fine particles present therein as explained above, it is possible to form a sufficiently thick coating also on the edge portion, which is most difficult to coat when instead the coating is formed from outside. In Fig. 1, three faces of the blade are coated by the fine particles 30, but practically acceptable performance can be obtained if the coating is formed at least on the face 21′ contacting the image bearing member and the face 22′ adjacent thereto. In such a cleaning blade 20, the surface characteristics are principally governed by the properties of the initially dispersed fine particles as shown in Fig. 1, so that inversion, bouncing, abrasion and chipping-off of the blade can be prevented by the selection of suitable lubricating particles. On the other hand, the elasticity of the entire blade is ensured by the rubber material constituting the matrix. The matrix rubber material, not coming into direct contact with the image bearing member, can be arbitrarily selected from various materials, and can be composed of silicone rubber which is superior in mass producibility and in elastic property. If the cleaning blade is cut, after the removal thereof from the mould at the edge position (portion to contact the image bearing member) in order to improve the precision of the edge, there will be obtained a section face on which is exposed a number of fine particles dispersed uniformly in the rubber material. Thus there is securely obtained a thicker coating layer so that the cleaning operation can be achieved in improved manner. In the following there are shown and evaluated examples of the present invention and reference examples for comparison. [Example 1] Rubber material: addition type liquid silicone rubber Fine particles: PVDF (particle size 10 µm or less) (melting point 170°C), 50 parts by weight to 100 part by weight of rubber moulding conditions: Moulding was conducted in a rubber injection moulder in which was inserted a support member subjected in advance to an adhesion treatment: Moulding temperature: 140°C Moulding time: 150 seconds After removal from the mould the edge portion was cut in a shape shown in Fig. 4, and the secondary vulcanizing was conducted under the following conditions: Secondary vulcanizing temperature: 200°C Secondary vulcanizing time: 4 hours moulded product: rubber hardness JISA 73. The surfaces were covered with PVDF as shown in Fig. 1, particularly thicker in the cut portion (heat resistance of rubber material: ca. 270°C). [Example 2] Moulding, removal from the mould and cutting of edge portion were conducted with the same materials and conditions as in the example 1. Then the secondary vulcanizing was conducted by heating for 60 seconds at 250°C, and then for 4 hours at 200°C. Moulded product: rubber hardness JIS 73 Because of the treatment at high temperature (250°C), the PVDF particles present relatively deep in the surfacial area emerged to the surface and contributed to the formation of layer, so that the obtained PVDF layer was thicker than in the example 1. [Example 3] Rubber material: addition type liquid silicon rubber (same as in the example 1). Fine particles: crystalline polypropylene; 50 parts by weight to 100 parts by weight of rubber (melting point: 145°C). Moulding conditions: Moulding was conducted in a rubber injection moulder in which was inserted a support member subjected in advance to an adhesion treatment: Moulding temperature: 120°C Moulding time: 10 minutes After the removal from the mould, the edge portion was cut in the same shape as in example 1, and the secondary vulcanizing was conducted under the following conditions: Secondary vulcanizing temperature: 200°C Secondary vulcanizing time: 4 hours moulded product: rubber hardness JISA 71 A polypropylene layer was formed on the surface in a similar manner as in the example 1. [Example 4] Rubber material: same as in the example 3 Fine particles: same as in the example 3 moulding conditions: Moulding was conducted in a rubber injection moulder in which was inserted a support member subjected in advance to an adhesion treatment: Molding temperature: 170°C Molding time: 60 seconds After the removal from the mould the edge portion was cut in the same shape as in the example 3, and the secondary vulcanizing was conducted under the following conditions: Secondary vulcanizing temperature: 200°C Secondary vulcanizing time: 4 hours. Molded products: rubber hardness JISA 71 Because the molding temperature was higher than the melting point of the fine particles, the dispersion state thereof became unstable, and the obtained surfacial polypropylene layer showed fluctuation in thickness. [Reference example 1] Rubber material: thermosetting liquid urethane rubber Fine particles: none Moulding conditions: Moulding temperature: 130°C Moulding time: 30 minutes Secondary vulcanizing temperature: 130°C Secondary vulcanizing time: 4 hours After secondary vulcanizing, the edge portion was cut in the same shape as in the foregoing examples. Moulded product: rubber hardness JISA 65 [Reference example 2] Rubber material: same as in the example 1 Fine particles: none Moulding conditions: same as in the example 1 Moulded product: rubber hardness JISA 62. [Evaluation conditions] The blades obtained in the foregoing examples and reference examples were mounted in a copying machine, and subjected to the evaluation of inversion, bouncing, cleaning ability and abrasion resistance under the following conditions: Image bearing member: organic photosensitive member Process speed: 50 mm/sec. Performance was evaluated by a durability test of 5,000 copies. With respect to blade inversion in the initial stage, since reliability cannot be evaluated in several tests, there was conducted a measurement of the friction resistance between each blade and the organic photosensitive member. [Result of evaluation] Table 1 summarizes the results of evaluation, and Fig. 2 summarizes the results of measurement of friction resistance. As shown in Table 1, the examples 1 to 4 exhibit satisfactory initial imaging ability, and are improved in the durability. However, the example 4 showed fluctuation in the thickness of the surfacial resin layer, with locally thin parts, so that the improvement in durability is less than that in the examples 1 to 3. Consequently the rubber molding temperature should preferably satisfy the condition T1 < T10 as explained before. On the other hand, in the reference example 1, absence of lubricant on the blade or on the photosensitive member caused inversion of blade, while use of excessive lubricant caused smearing of the charger or the developing unit, leading to a defective image. Also the reference example 2 exhibited frequent abrasion or chippings of the blade, resulting in unsatisfactory cleaning. The reliability of the blade with respect to inversion can be judged from the friction resistance shown in Fig. 2, which shows the friction resistance between the blade and the organic photosensitive member in ordinate, as a function of contact pressure in abscissa. The friction resistance in ordinate is represented by a relative value in arbitrary scale. In Fig. 2, the reference example 1 "without lubricant" corresponds to a level of causing inversion, as will be apparent from the above-explained results. On the other hand, the reference example 1 "with excessive lubricant" employs a large amount of lubricant for preventing inversion, thus causing defects in the image. The examples 1, 2 and 3 are comparable to the reference example 1 with excessive lubricant, indicating that they are sufficiently reliable with respect to blade inversion. The friction resistance of the example 4 is higher than that of the examples 1, 2 and 3 but is lower than that of reference example 1 (no lubricant) or reference example 2. Reference example 2 showed a lower friction resistance than in reference example 1 without lubricant and did not show inversion during evaluation, but reliability cannot be said to be sufficient. The fine particles of resin to be dispersed need not necessarily be crystalline but can be those with a sharp molecular weight distribution having a well defined softening point. Nevertheless crystalline particles having a melting point are preferable. In case crystalline resin powder is employed, the rubber moulding temperature is preferably selected lower than the melting point and the vulcanizing temperature is preferably selected higher than said melting point as in the foregoing examples. In case non-crystalline resin powder is employed, the rubber moulding temperature is preferably selected lower than the softening point of said resin, and the vulcanizing temperature is preferably selected higher than said softening point. The fine particles in the foregoing examples are composed of PVDF or polypropylene, but there may also be employed other materials such as polyethylene or polyester. Also the rubber material is not limited to silicone rubber, but there may be employed any other rubber material on which surface coating is possible by the secondary vulcanizing. Nevertheless silicone rubber is preferred in consideration of superior mass producibility and elastic characteristics. The content of the resin particles is preferably within a range from 20 to 80 parts by weight with respect to 100 parts by weight of the rubber, since an amount less than 20 parts leads to an excessively thin surface coating, while an amount in excess of 80 parts will deteriorate the elasticity of the rubber matrix. The present invention has been explained by examples thereof, but the present invention is not limited by such examples and is subject to any variation within the scope of the invention as defined by the appended claims.

Claims: A cleaning blade comprising: a base member (3) of rubber in which a resin powder (30) is dispersed; characterised by: a resin layer (25) disposed on at least the end face (22′) and contact face (21′) of said base member (3), which resin layer (25) consists of said resin powder (30) fused at the surface of said base member (3). A cleaning blade according to claim 1, wherein said rubber is a silicone rubber. A cleaning blade according to claims 1 or 2, wherein said resin layer (25) is of fluorinated resin. A cleaning blade according to any of claims 1 to 3 wherein said resin powder (30) is crystalline. A cleaning blade according to claim 3 wherein said resin layer (25) is of polyvinylidene fluoride. A cleaning blade according to any preceding claim wherein said base member (3) comprises 100 parts by weight of rubber and 20 to 80 parts by weight of resin powder (30). Use of a cleaning blade according to any one of claims 1 to 6 for removing toner remaining on an image bearing member (1) for bearing toner image, wherein said resin layer (25) is arranged in contact with said image bearing member (1). A method for producing the cleaning blade of claim 1, which method comprises the following steps: (a) dispersing resin powder (30) in a rubber material; (b) moulding said rubber material containing dispersed resin powder; and (c) vulcanising the moulded rubber material; which method is characterised in that: said step (c) of vulcanising the moulded rubber material is performed at a temperature higher than the melting point or the softening point of said resin powder (30) thereby to produce a resin layer (25) of fused resin powder (30) at the surface of the moulded rubber. A method according to claim 8 wherein said moulded rubber produced in step (b) is cut at one end prior to performing step (c). A method according to either claim 8 or 9 wherein said step (b) of moulding is performed at a temperature which is lower than the softening point or the melting point of said resin powder (30). A method according to any preceding claim 8 to 10 wherein said rubber material is a silicone rubber. A method according to any preceding claim 8 to 11 wherein said resin powder (30) is crystalline. A method according to claim 12 wherein said resin powder (30) is of polyvinylidene fluoride. A method according to any preceding claim 8 to 13 wherein in step (a) 20 to 80 parts by weight of said resin powder (30) is dispersed in 100 parts by weight of said rubber material.

Inventors: ADACHI HIROYUKI C O CANON KABU, SASAME HIROSHI C O CANON KABUS, SHOJI TAKEO C O CANON KABUSHIK, TSUKIDA SHINICHI C O CANON KAB, WATABE MASAHIRO C O CANON KABU, YANAI NORIYUKI C O CANON KABUS, ADACHI, HIROYUKI, C/O CANON KABUSHIKI KAISHA, SASAME, HIROSHI, C/O CANON KABUSHIKI KAISHA, SHOJI, TAKEO, C/O CANON KABUSHIKI KAISHA, TSUKIDA, SHINICHI, C/O CANON KABUSHIKI KAISHA, WATABE, MASAHIRO, C/O CANON KABUSHIKI KAISHA, YANAI, NORIYUKI, C/O CANON KABUSHIKI KAISHA
Applicants: CANON KK, CANON KABUSHIKI KAISHA
Application year: 1991
Main classification: G03G21
IPC codes: C08L83, G03G21, B05C1