DISPOSABLE BODY-WARMER

Abstract: A disposable body-warmer comprising a heat generating composition enclosed in a flat bag, which composition oxidizes and generates heat in the presence of air. The flat bag is air permeable on at least one side thereof so that air pressure in the bag may be reduced with generation of heat in said heat generating composition and is provided with an adhesive layer on one of the both sides. Said heat generating composition contains high performance activated charcoal having an iodine adsorptive performance of 800 to 1200 mg/g and methylene blue decoloring power of 100 to 300 mg/g, whereby temperature rise is quicker and a warmth retaining period is longer than those in the conventional body-warmer.

Description: TECHNICAL FIELD The present invention relates to a disposable body warmer, and more particularly to a disposable body warmer which has a good rising (i.e. the rising in temperature is fast), can maintain a preferable duration, and can avoid the bulging of a bag and agglomeration of the heat-generating agent after the beginning of use, i.e. during use. BACKGROUND ART A disposable body warmer comprises an air-permeable bag, and a mixture contained in the bag and comprising metal powder such as iron powder available at a relatively low cost and assistants such as water, wood flour and sodium chloride. The disposable body warmer utilizes an exothermic reaction caused by supplying oxygen thereto, and is easy to carry and can be easily used by merely openning an outer bag, so that it occupies a major proportion of body warmers in these days. Further, in order to make application of the above-mentioned disposable body warmer to the human body easy and simple, there is proposed a disposable body warmer in which an intransferable self-adhesive layer functioning as a conventional attaching means such as an attaching band and a pocket is employed (refer to, for example, Japanese Examined Utility Model Publication No. 34735/1981). By the way, when the disposable body warmer of an adhesion type described above is applied to the human body, there are problems that distribution of contents in a bag becomes uneven (such uneven distribution is particularly remarkable when the body warmer is applied to the human body in a perpendicular or inclined state), and heat generation is completed at an early stage in one part of the heat-generating agent so that heat distribution of the body warmer becomes uneven. There are further problems that partial extreme increase in thickness of a bag, agglomerated heat-generating agent and the like deteriorates the touch and gives unpleasantness (gives inferior feeling in use) to a user. In order to solve the problems mentioned above, there is proposed a disposable body warmer in which air permeability of one surface of an inner bag containing the heat-generating agent is controlled to reduce the pressure in the bag (refer to, for example, Japanese Examined Utility Model Publication No. 30169/1989 The above-mentioned disposable body warmer, however, has problems that (1) there is scatter in performance of the body warmer because air permeability of the inner bag is evaluated based on air permeability per unit time (JIS P 8117), not water vapor permeability (JIS Z 0280) having a high accuracy, (2) usable inner bags are limited to those having air permeability of 5000 to 10000 sec/100 cc, (3) assistants for preventing agglomeration are not employed in the contents, so that agglomeration of the heat-generating agent cannot be avoided unless not less than 9 % by weight of water-holding material is added to the heat-generating agent, and (4) rise-time is long and duration is short. It is an object of the present invention to provide a disposable body warmer capable of solving the above-mentioned drawbacks. That is, an object of the present invention is to provide a disposable body warmer which requires short time to raise its temperature up to a predetermined temperature just from the beginning of heat generation, has long duration, and is free from bulging and agglomeration of the heat-generating agent after the beginning of use thereof. DISCLOSURE OF INVENTION In accordance with the present invention in claim 1, there is provided a disposable body warmer comprising a heat-generating agent which oxidizes and generates heat by the presence of air, a flat inner bag containing the heat-generating agent and an airtight outer bag containing the flat inner bag, wherein at least one surface of the flat inner bag is made air permeable so that pressure in the flat inner bag is reduced by exothermic reaction of the heat-generating agent, a self-adhesive layer is provided on either surface of the flat inner bag, characterized in that the heat-generating agent contains high performance activated carbon having an iodine adsorption of 800 to 1200 mg/g and a methylene blue decoloring power of 100 to 300 mg/g. EP-A-0 376 490 forms the preamble of claim 1. Water vapor permeability of the air permeable surface of the flat bag is preferably from 340 to 1000 g/m 2 ·24h, and more preferably from 350 to 700 g/m 2 ·24h. Further, the heat-generating agent preferably contain 2 to 6 % by weight of silica gel and/or alumina. BRIEF DESCRIPTION OF DRAWINGS Fig. 1 is a sectional explanatory view of an embodiment of a disposable body warmer of the present invention; Fig. 2 is a sectional explanatory view of another embodiment of a disposable body warmer of the present invention; and Fig. 3 is a view showing a pattern of temperature change of a disposable body warmer. BEST MODE FOR CARRYING OUT THE INVENTION A disposable body warmer of the present invention is explained in detail hereinafter. In Figs. 1 to 2, symbol A is an embodiment of a disposable body warmer of the present invention. The body warmer A is composed of a flat inner bag 1, heat-generating agent 2 contained in the inner bag 1, a self-adhesive layer formed on one surface of the inner bag 1, and an airtight outer bag 4 containing the inner bag 1. One surface of the flat bag 1 is air permeable while the other surface thereof is air impermeable. In the embodiment shown in Figs. 1 to 2, the under surface of the inner bag 1 is made air permeable. In producing the inner bag 1, both surfaces thereof might be made of air permeable material and one surface might be made air impermeable or air adjustable by forming a self-adhesive layer 3 entirely or partially on one surface. There might also be employed an inner bag in which one surface thereof is made air permeable while the other surface thereof is made air impermeable and a self-adhesive layer is formed on the air impermeable surface entirely or partially. In short, at least one surface of the inner bag is air permeable, and a self-adhesive layer is formed on either surface entirely or partially. With respect to air permeability of the inner bag 1, it is possible to select material for the inner bag 1 based on air permeability per unit time (sec/100 mℓ : time (sec) required for a given amount of air (100 mℓ ) to pass through an unit area (645 mm 2 ) under pressure, JIS P 8117). Evaluation based on air permeability per unit time, however, has drawbacks that there is a large scatter in results due to features of test method employing forced air passage, resulting in an inferior accuracy, and it requires expensive analysis cost and a long test time. Accordingly, it is preferable, instead of air permeability per unit time, to employ water vapor permeability (g/m 2 ·24h: An amount of water vapor passing through a film of an unit area in a given period of time. According to condition B in JIS Z 0208, a vaporproof package material is used as a boundary surface. The relative humidity of air on one side is kept 90 % while air on the other side is kept dry by moisture-absorbing agent at 40°C. The mass (g) of water vapor passing through the boundary surface in 24 hours is converted into the mass per 1 m 2 .). Preferable water vapor permeability is from 340 to 1000 g/m 2 ·24h, and more preferable water vapor permeability is from 350 to 700 g/m 2 ·24h. Though the other factors have influence, in general, when water vapor permeability is less than 340 g/m 2 ·24h, there are disadvantages that sufficient exothermic reaction cannot be obtained, i.e. the temperature of body warmers is not raised. On the other hand, when water vapor permeability is more than 1000 g/m 2 ·24h, there are disadvantages that body warmers become too hot, duration is short, and body warmers inflate during or after use. Though materials for the inner bag 1 are not limited in the present invention, it is preferable to use such materials that have good fitness to the human body, underwears and the like, stable quality, applicability for heat sealing, and are soft and strong, not nappy. Usable concrete examples are, for example, plastic-like or rubber-like flexible thermoplastic sheet or film comprising polyurethane, polypropylene or polyethylene, or modifications thereof; and a single layer or complex layer of non woven fabric, polyvinyl chloride, polyester or polystyrene. As a method for controlling air permeability of an air permeable surface of an inner bag 1, there is a method wherein appropriate heat welding treatment is applied to a sheet or film on which minute continuous holes are formed. Concretely speaking, the air permeability can be controlled, for example, by uniformly distributing or entirely applying heat welding agent which is heated appropriately on a sheet or film having uniform continuous holes of 1 to 50 µm in diameter. The air permeability can be also controlled by laminating a resin film, on which minute air permeable holes are formed, to a non woven fabric. Though the size of the inner bag 1 is not particularly limited in the present invention, inner bags of a size from 4 x 6 cm to 15 x 20 cm can be usually employed. Numeral 2 is a heat-generating agent comprising iron powder, activated carbon, water, a water-holding material (wood flour, vermiculite, diatomaceous earth, pearlite, silica gel, alumina, water-absorbing resin and the like), and sodium chloride. In the present specification, the term "heat-generating agent" means all compositions contained in the body warmer. With respect to iron powder, water-holding material, sodium chloride and the like, those which are used in the usual disposable body warmers can be used. The proportion thereof is not limited in the present invention, and accordingly usual proportion might be employed. Concretely speaking, 47 to 70 % (% by weight, hereinafter the same) of iron powder, 15 to 35 % of water, 3 to 9 % of water-holding material, 5 to 12 % of activated carbon, 0.5 to 4 % of sodium chloride and the like are used. They are so adjusted as to have maximum exothermic reaction temperature by oxidation thereof of, preferably, 53 to 57°C The inventive feature is to use, as the above-mentioned activated carbon, high performance activated carbon having specific properties. That is, in the disposable body warmer of the present invention, high performance activated carbon having an iodine adsorption of 800 to 1200 mg/g and a methylene blue decoloring power of 100 to 300 mg/g is used. The iodine adsorption is determined, as prescribed in JIS K 1474, as follows. That is, iodine solution is added to sampels and a supernatant liquid is separated after adsorption is carried out. Then, a starch solution as an indicator is added to the separated supernatant liquid to titrate with a sodium thiosulfate solution. The iodine adsorption is determined by the concentration of the remaining iodine. The methylene blue decoloring powder is determined, as prescribed in JIS K 1470, as follows. That is, methylene blue solution A is added to samples and filteration is carried out after shaking by a shaker. The chromaticity of filtrate is compared with that of methylene blue solution B, and the methylene blue decoloring power is determined by the amount of added methylene blue solution A required for making the chromaticity of filtrate coincide with that of methylene blue solution B. Both factors relate to adsorption performance of activated carbon. By using activated carbon having a specific range of adsorption performance, it becomes possible to shorten the time required for raising temperature of disposable body warmers up to a predetermined temperature just from the beginning of heat generation, and to lengthen duration. Further, by adding 2 to 6 % of silica gel and/or alumina to the above-mentioned heat-generating agent 2, the bulging of the inner bag and agglomeration of the heat-generating agent after the beginning of use mentioned above can be effectively prevented. When the proportion of silica gel and/or alumina is less than 2 %, the heat-generating agent agglomerates after the beginning of use. On the other hand, when the proportion is more than 6 %, the amounts of other components such as iron powder, water-holding agent, activated carbon, sodium chloride and the like are not suitable, so that the heat-generating agent becomes bulky and effects of the other components are lessened. That is, the time required for raising temperature of the heat-generating agent up to a predetermined temperature just after the beginning of heat generation is lengthened and duration is shortened. Numeral 3 is a self-adhesive layer compiring usual self-adhesive materials including rubber and the like as a main material. The self-adhesive layer 3 is provided on one surface of the inner bag 1. The self-adhesive layer 3 might be provided entirely on one surface of the inner bag 1, or might be provided partially so as to form suitable patterns such as fringe pattern, grid pattern and polka dots. The self-adhesive layer 3 is formed after the above-mentioned heat-generating agent 2 is charged into the inner bag 1. In the embodiment shown in Fig. 1, a released paper 5 covers the surface of the self-adhesive layer 3. In use the released paper 5 is peeled off, and the inner bag 1 is adhered to a desired portion using the self-adhesive layer 3. Numeral 4 is an airtight outer bag comprising a holeless film made of polyethylene, polypropylene and the like. In the embodiment shown in Fig. 2, the released layer 5 is formed on the inner surface of the outer bag, whereby covering and protecting the self-adhesive layer 3 formed on the inner bag. In this case, the outer bag 4 functions also as a released paper in the conventional body warmer, so that the inner bag 1 can be fixed to a desired portion by merely opening the outer bag 4. Next, the disposable body warmer of the present invention is explained based on Examples. The present invention is not, however, limited thereto. The experiments were carried out by suitably varying iodine adsorption (mg/g) of activated carbon, with maintaining water vaper permeability constant. Measurement was performed on the basis of JIS S 4100, and the rise-time (minute) and duration (hour) were examined. Further, content ratio (%: ratio to heat-generating agent) of silica gel was varied to 0, 0.5, 1, 1.5, 2, 2.5, 3, 3.5 or 4. The state of agglomeration of the heat-generating agent after use was judged in three stages (agglomerated, more or less agglomerated, not agglomerated). The number of samples tested was 10, and the maximum temperature, rise-time and duration were obtained as follows. Maximum temperature Average of measured maximum temperatures of all samples. Refer to a in Fig. 3. Rise-time Average of measured times of eight samples required for raising temperature of samples up to 40°C from the beginning of heat generation, wherein the maximum value and minimum value are excluded (provided that only one value of plural miximum values or minimum values is excluded when there are plural maximum values or minimum values). Duration Average of measured durations of eight samples from the beginning of heat generation to the passage of maximum temperature, wherein the maximum value and minimum value are excluded (provided that only one value of plural maximum values or minimum values is excluded when there are plural maximum values or minimum values, and that a fraction less than one hour is omitted). Refer to t in Fig. 3. Examples 1 to 17 and Comparative Examples 1 to 5 (water vapor permeability: 210 g/m 2 ·24h). There were prepared inner bags (length: 130 mm, width: 95 mm, sealed width: 6 mm) wherein a lamination of porous polyethylene and nylon non woven fabric which was heat welded to controll air permeability was used as an air permeable surface, and polyethylene having thereon an acrylic self-adhesive layer was used as an air impermeable surface. 36 g of heat-generating agent obtained by mixing 56 parts of iron powder, 27 parts of 10 % brine, 9 parts of high performance activated carbon, 3 parts of vermiculite, 2 parts of water-absorbing resin and 3 parts of silica gel was charged into each inner bag. The heat generation performance of thus prepared warmers was measured according to JIS S 4100 as mentioned above. The results are summarized in Table 1. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 1 880 100 32 * * Ex. 2 880 200 33 * * Ex. 3 910 100 33 * * Ex. 4 910 140 33 * * Ex. 5 910 160 35 * * Ex. 6 910 200 35 * * Ex. 7 910 300 35 * * Ex. 8 1000 100 35 * * Ex. 9 1000 140 35 * * Ex. 10 1000 160 36 * * Ex. 11 1000 200 40 19 27 Ex. 12 1000 300 40 19 27 Ex. 13 1200 100 40 19 27 Ex. 14 1200 140 40 19 27 Ex. 15 1200 160 41 19 27 Ex. 16 1200 200 41 19 27 Ex. 17 1200 300 41 19 27 Com. Ex. 1 500 100 30 * * Com. Ex. 2 500 200 30 * * Com. Ex. 3 700 100 31 * * Com. Ex. 4 700 200 32 * * Com. Ex. 5 910 80 31 * * Note: Symbol * means that measurement based on JIS was impossible. Example 18 to 34 and Comparative Examples 6 to 10 (water vapor permeability: 340 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 340 g/m 2 ·24h. The results are summarized in Table 2. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 18 880 100 35 * * Ex. 19 880 200 36 * * Ex. 20 910 100 36 * * Ex. 21 910 140 38 * * Ex. 22 910 160 38 * * Ex. 23 910 200 38 * * Ex. 24 910 300 39 * * Ex. 25 1000 100 40 18 25 Ex. 26 1000 140 40 18 25 Ex. 27 1000 160 42 18 25 Ex. 28 1000 200 43 18 25 Ex. 29 1000 300 43 18 25 Ex. 30 1200 100 43 17 25 Ex. 31 1200 140 43 17 25 Ex. 32 1200 160 43 17 25 Ex. 33 1200 200 43 17 25 Ex. 34 1200 300 43 17 25 Com. Ex. 6 500 100 32 * * Com. Ex. 7 500 200 32 * * Com. Ex. 8 700 100 33 * * Com. Ex. 9 700 200 34 * * Com. Ex. 10 910 80 33 * * Note: Symbol * means that measurement based on JIS was impossible. Example 35 to 51 and Comparative Examples 11 to 15 (water vapor permeability: 360 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 360 g/m 2 ·24h. The results are summarized in Table 3. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 35 880 100 38 * * Ex. 36 880 200 39 * * Ex. 37 910 100 40 17 25 Ex. 38 910 140 40 17 25 Ex. 39 910 160 41 17 25 Ex. 40 910 200 41 17 24 Ex. 41 910 300 41 17 24 Ex. 42 1000 100 43 17 24 Ex. 43 1000 140 44 16 24 Ex. 44 1000 160 45 16 24 Ex. 45 1000 200 45 16 24 Ex. 46 1000 300 45 16 24 Ex. 47 1200 100 45 15 24 Ex. 48 1200 140 45 15 24 Ex. 49 1200 160 45 15 24 Ex. 50 1200 200 45 15 24 Ex. 51 1200 300 45 15 24 Com. Ex. 11 500 100 32 * * Com. Ex. 12 500 200 33 * * Com. Ex. 13 700 100 35 * * Com. Ex. 14 700 200 36 * * Com. Ex. 15 910 80 35 * * Note: Symbol * means that measurement based on JIS was impossible. Example 52 to 68 and Comparative Examples 16 to 20 (water vapor permeability: 400 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 400 g/m 2 ·24h. The results are summarized in Table 4. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 52 880 100 50 15 20 Ex. 53 880 200 51 15 19 Ex. 54 910 100 51 15 19 Ex. 55 910 140 51 15 19 Ex. 56 910 160 52 14 18 Ex. 57 910 200 52 14 18 Ex. 58 910 300 52 14 18 Ex. 59 1000 100 52 13 18 Ex. 60 1000 140 52 13 18 Ex. 61 1000 160 53 13 17 Ex. 62 1000 200 53 13 17 Ex. 63 1000 300 53 13 17 Ex. 64 1200 100 54 12 17 Ex. 65 1200 140 54 12 17 Ex. 66 1200 160 54 12 17 Ex. 67 1200 200 54 12 17 Ex. 68 1200 300 54 12 17 Com. Ex. 16 500 100 45 20 26 Com. Ex. 17 500 200 46 19 26 Com. Ex. 18 700 100 47 19 24 Com. Ex. 19 700 200 48 19 24 Com. Ex. 20 910 80 47 19 24 Example 69 to 85 and Comparative Examples 21 to 25 (water vapor permeability: 450 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 450 g/m 2 ·24h. The results are summarized in Table 5. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 69 880 100 50 15 20 Ex. 70 880 200 51 14 19 Ex. 71 910 100 51 13 19 Ex. 72 910 140 52 13 18 Ex. 73 910 160 52 13 18 Ex. 74 910 200 52 13 18 Ex. 75 910 300 53 12 17 Ex. 76 1000 100 53 12 17 Ex. 77 1000 140 53 12 17 Ex. 78 1000 160 53 12 17 Ex. 79 1000 200 54 12 17 Ex. 80 1000 300 55 12 16 Ex. 81 1200 100 55 11 16 Ex. 82 1200 140 55 11 16 Ex. 83 1200 160 55 11 16 Ex. 84 1200 200 55 11 16 Ex. 85 1200 300 55 11 16 Com. Ex. 21 500 100 47 19 24 Com. Ex. 22 500 200 48 19 24 Com. Ex. 23 700 100 49 17 23 Com. Ex. 24 700 200 50 17 22 Com. Ex. 25 910 80 49 17 23 Example 86 to 102 and Comparative Examples 26 to 30 (water vapor permeability: 500 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 500 g/m 2 ·24h. The results are summarized in Table 6. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 86 880 100 52 12 17 Ex. 87 880 200 52 12 17 Ex. 88 910 100 52 10 17 Ex. 89 910 140 53 10 17 Ex. 90 910 160 54 10 17 Ex. 91 910 200 54 10 17 Ex. 92 910 300 54 10 16 Ex. 93 1000 100 54 9 16 Ex. 94 1000 140 54 9 16 Ex. 95 1000 160 54 9 16 Ex. 96 1000 200 55 9 16 Ex. 97 1000 300 55 9 15 Ex. 98 1200 100 55 8 15 Ex. 99 1200 140 55 8 15 Ex. 100 1200 160 56 8 16 Ex. 101 1200 200 56 8 15 Ex. 102 1200 300 56 8 15 Com. Ex. 26 500 100 48 19 22 Com. Ex. 27 500 200 50 18 22 Com. Ex. 28 700 100 51 14 19 Com. Ex. 29 700 200 52 14 19 Com. Ex. 30 910 80 51 14 19 Example 103 to 119 and Comparative Examples 31 to 35 (water vapor permeability: 550 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 550 g/m 2 ·24h. The results are summarized in Table 7. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 103 880 100 52 11 16 Ex. 104 880 200 52 11 16 Ex. 105 910 100 52 10 15 Ex. 106 910 140 52 10 15 Ex. 107 910 160 53 10 15 Ex. 108 910 200 53 10 15 Ex. 109 910 300 53 10 14 Ex. 110 1000 100 54 9 14 Ex. 111 1000 140 54 9 14 Ex. 112 1000 160 55 9 14 Ex. 113 1000 200 55 9 14 Ex. 114 1000 300 55 9 13 Ex. 115 1200 100 55 8 14 Ex. 116 1200 140 56 8 13 Ex. 117 1200 160 56 8 13 Ex. 118 1200 200 56 8 13 Ex. 119 1200 300 56 8 13 Com. Ex. 31 500 100 48 16 20 Com. Ex. 32 500 200 49 16 20 Com. Ex. 33 700 100 51 16 18 Com. Ex. 34 700 200 52 14 18 Com. Ex. 35 910 80 51 16 18 Example 120 to 136 and Comparative Examples 36 to 40 (water vapor permeability: 600 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 600 g/m 2 ·24h. The results are summarized in Table 8. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 120 880 100 54 8 16 Ex. 121 880 200 54 8 16 Ex. 122 910 100 54 8 16 Ex. 123 910 140 54 8 16 Ex. 124 910 160 55 8 15 Ex. 125 910 200 55 8 15 Ex. 126 910 300 56 8 15 Ex. 127 1000 100 56 7 14 Ex. 128 1000 140 56 7 14 Ex. 129 1000 160 57 7 13 Ex. 130 1000 200 58 7 13 Ex. 131 1000 300 58 7 13 Ex. 132 1200 100 58 6 13 Ex. 133 1200 140 58 6 13 Ex. 134 1200 160 59 6 12 Ex. 135 1200 200 59 6 12 Ex. 136 1200 300 59 6 12 Com. Ex. 36 500 100 49 14 19 Com. Ex. 37 500 200 50 13 19 Com. Ex. 38 700 100 51 10 17 Com. Ex. 39 700 200 52 10 17 Com. Ex. 40 910 80 51 10 17 Example 137 to 153 and Comparative Examples 41 to 45 (water vapor permeability: 650 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 650 g/m 2 ·24h. The results are summarized in Table 9. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 137 880 100 55 8 14 Ex. 138 880 200 56 8 14 Ex. 139 910 100 56 8 14 Ex. 140 910 140 56 8 14 Ex. 141 910 160 58 8 12 Ex. 142 910 200 58 8 12 Ex. 143 910 300 58 8 12 Ex. 144 1000 100 58 7 12 Ex. 145 1000 140 58 7 12 Ex. 146 1000 160 59 7 11 Ex. 147 1000 200 59 7 11 Ex. 148 1000 300 59 7 11 Ex. 149 1200 100 59 6 11 Ex. 150 1200 140 59 6 11 Ex. 151 1200 160 60 6 11 Ex. 152 1200 200 60 6 11 Ex. 153 1200 300 60 6 11 Com. Ex. 41 500 100 50 12 17 Com. Ex. 42 500 200 51 12 17 Com. Ex. 43 700 100 52 9 15 Com. Ex. 44 700 200 53 9 15 Com. Ex. 45 910 80 52 9 15 Example 154 to 170 and Comparative Examples 46 to 50 (water vapor permeability: 700 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 700 g/m 2 ·24h. The results are summarized in Table 10. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 154 880 100 57 7 13 Ex. 155 880 200 58 7 12 Ex. 156 910 100 58 7 12 Ex. 157 910 140 58 7 12 Ex. 158 910 160 60 6 11 Ex. 159 910 200 60 6 11 Ex. 160 910 300 60 6 11 Ex. 161 1000 100 60 6 11 Ex. 162 1000 140 60 6 11 Ex. 163 1000 160 61 5 11 Ex. 164 1000 200 62 5 11 Ex. 165 1000 300 62 5 10 Ex. 166 1200 100 62 5 10 Ex. 167 1200 140 62 5 10 Ex. 168 1200 160 62 5 10 Ex. 169 1200 200 62 5 10 Ex. 170 1200 300 62 5 10 Com. Ex. 46 500 100 51 12 16 Com. Ex. 47 500 200 52 12 16 Com. Ex. 48 700 100 54 8 14 Com. Ex. 49 700 200 55 8 14 Com. Ex. 50 910 80 54 8 14 Example 171 to 187 and Comparative Examples 51 to 55 (water vapor permeability: 740 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 740 g/m 2 ·24h. The results are summarized in Table 11. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 171 880 100 57 7 12 Ex. 172 880 200 58 7 12 Ex. 173 910 100 58 7 12 Ex. 174 910 140 58 7 12 Ex. 175 910 160 60 6 11 Ex. 176 910 200 60 6 11 Ex. 177 910 300 61 6 11 Ex. 178 1000 100 61 5 11 Ex. 179 1000 140 61 5 11 Ex. 180 1000 160 62 5 11 Ex. 181 1000 200 62 5 11 Ex. 182 1000 300 62 4 11 Ex. 183 1200 100 62 4 11 Ex. 184 1200 140 63 4 10 Ex. 185 1200 160 63 4 10 Ex. 186 1200 200 63 4 10 Ex. 187 1200 300 63 4 10 Com. Ex. 51 500 100 51 12 15 Com. Ex. 52 500 200 52 12 15 Com. Ex. 53 700 100 54 8 14 Com. Ex. 54 700 200 55 8 14 Com. Ex. 55 910 80 54 8 14 Example 188 to 204 and Comparative Examples 56 to 60 (water vapor permeability: 1000 g/m 2 ·24h) Body warmers were prepared and predetermined measurements were carried out in the same manner as Example 1 except that water vapor permeability of air permeable surfaces of inner bags was changed into 1000 g/m 2 ·24h. The results are summarized in Table 12. No. Iodine adsorption (mg/g) Methylene blue decoloring power (mg/g) Maximum Temp. (°C) Rise-time (min.) Duration (hour) Ex. 188 880 100 57 6 12 Ex. 189 880 200 58 6 12 Ex. 190 910 100 59 6 11 Ex. 191 910 140 60 6 11 Ex. 192 910 160 62 5 11 Ex. 193 910 200 62 5 11 Ex. 194 910 300 62 5 11 Ex. 195 1000 100 63 4 10 Ex. 196 1000 140 63 4 10 Ex. 197 1000 160 63 4 10 Ex. 198 1000 200 63 4 10 Ex. 199 1000 300 63 4 10 Ex. 200 1200 100 63 4 10 Ex. 201 1200 140 63 4 10 Ex. 202 1200 160 64 4 9 Ex. 203 1200 200 64 4 9 Ex. 204 1200 300 64 4 9 Com. Ex. 56 500 100 52 9 15 Com. Ex. 57 500 200 53 9 14 Com. Ex. 58 700 100 55 7 14 Com. Ex. 59 700 200 56 7 14 Com. Ex. 60 910 80 55 7 14 Samples were prepared and measurements were performed similarly in the case of water vapor permeability of 1450 g/m 2 ·24h, however, inner bags bulged due to gas generation and clogging thereof to make measurements based on JIS impossible. Further, with respect to all Examples and Comparative Examples, the heat-generating agents agglomerated when the amount of silica gel was 0 or 0.5 %, they more or less agglomerated when the amount of silica gel was 1 %, 1.5 % or 2 %, and they did not agglomerate when the amount of silica gel was 2.5 %, 3 %, 3.5 % or 4 %. Some body warmers were prepared using alumina instead of silica gel and similar experiments were carried out. The same effects were obtained in the case silica gel. In the Tables 1 to 12, in general, the maximum temperature is preferably from 53 to 57°C, the rise-time is preferably from 5 to 8 minutes, and the duration is preferably from 13 to 16 hours. As is clear from Tables 1 to 12, the rise-time of disposable body warmers of the present invention is short, and duration can be maintained long. Further, it is understood that agglomeration of body warmers after use can be prevented by adding 2 to 6 % of silica gel to heat-generating agent. As explained above, according to the present invention, there can be obtained a disposable body warmer having short rise-time and long duration. Further, by adding 2 to 6 % of silica gel and/or alumina to the heat-generating agent, the bulging of the bag and agglomeration of the heat-generating agent after use can be prevented. INDUSTRIAL APPLICABILITY A disposable body warmer of the present invention is useful as a portable body warmer because it raises its temperature in a short time and maintains warm condition for a long time.

Claims: A disposable body warmer (A) comprising a heat-generating agent (2) which oxidizes and generates heat by the presence of air, a flat inner bag (1) containing the heat-generating agent (2) and an airtight outer bag (4) containing the flat inner bag (1), wherein at least one surface of the flat inner bag (1) is made air permeable so that pressure in the flat inner bag (1) is reduced by exothermic reaction of the heat-generating agent (2), a self-adhesive layer (3) is provided on either surface of the flat inner bag (1), characterized in that the heat-generating agent (2) contains high performance activated carbon having an iodine adsorption of 800 to 1200 mg/g and a methylene blue decoloring power of 100 to 300 mg/g. The disposable body warmer (A) of Claim 1, wherein water vapor permeability of the air permeable surface of the flat inner bag (1) is from 340 to 1000 g/m 2 ·24h. The disposable body warmer (A) of Claim 1, wherein water vapor permeability of the air permeable surface of the flat inner bag (1) is from 350 to 700 g/m 2 ·24h. The disposable body warmer (A) of any one of Claims 1 to 3, wherein the heat-generating agent (2) contains 2 to 6 % by weight of silica gel and/or alumina.

Inventors: UEKI AKIO, UEKI, AKIO, UEKI, Akio, Kiribai Chemical Industry Co., Ltd.
Applicants: KIRIBAI KAGAKU KOGYO KK, KIRIBAI CHEMICAL INDUSTRY CO., LTD.
Application year: 1991
Main classification: A61F7
IPC codes: A61F7