Asbestos-free brake lining

Abstract: Disclosed herein is an asbestos-free brake lining, which contains a base material, an auxiliary material and a filler, and is molded with a binder. The base material contains 2 to 30 volume percent of copper-containing fiber with respect to the brake lining. The auxiliary material contains 1 to 30 volume percent of talc with respect to the brake lining. The brake lining, which contains no asbestos, exerts no harmful influence on the human body and environment. In this brake lining, a static friction coefficient µs as well as the ratio µs/µd of the static friction coefficient ins to a dynamic friction coefficient µd are reduced, whereby occurrence of a low-frequency brake noise is suppressed in a braking operation, to give no unpleasant feeling to the driver etc.

Description: BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to a brake lining for a vehicle such as an automobile or a friction brake lining for an industrial machine, and more particularly, it relates to an asbestos-free brake lining which can prevent occurrence of a low-frequency brake noise. Description of the Background Art An asbestos lining, which is mainly composed of asbestos, has generally been applied to a brake for an automobile or the like. However, it has recently been discussed that asbestos exerts a harmful influence on the human body. To this end, there has been developed the so-called asbestos-free lining, which contains no asbestos, to take the place of the asbestos lining. The asbestos-free lining has been implemented by a semi-metallic lining with steel short fiber. Such a semi-metallic lining is obtained by adding large amounts of a graphite lubricant and metal powder to steel fiber, which serves as a reinforcing material, and hot-forming the mixture with a binder of phenol resin. In performance, the semi-metallic lining is excellent in wear resistance and fading resistance. However, it has been pointed out that such a semi-metallic lining ignites in a braking operation when it has been heated to high temperature because of frequent braking operations, and the steel short fiber, which is contained in the lining, causes significant wear of a counter-rotor. In the existing circumstances, therefore, an asbestos-free lining is implemented by a low-steel lining which contains steel in the minimum required amount, or a non-steel lining which contains absolutely no steel. The low-steel and non-steel linings can solve the aforementioned problems of ignition in a high-temperature braking operation and wear of a counter-rotor, which have been caused in the semi-metallic lining. However, the low-steel and non-steel linings are liable to cause low-frequency brake noises of not more than 1 KHz, as compared with the conventional asbestos lining. In an extreme case, the car body may vibrate in a braking operation, to give an extremely unpleasant feeling to the driver etc. EP 0 050 377 describes an asbestos-free brake lining providing low wear of the lining and the counter-rotor as well as high retardation values, wherein the material consists of 5 - 25 Wt % of a binder material, 1 - 70 Wt % reinforcing material and other additives, the reinforcing material comprising 7,5 - 12 Wt % aramid fiber, 6 - 25 Wt. % mineral fiber and 16 - 36 Wt % steel fiber. EP 0 250 615 describes a lining for a friction coupling, wherein the lining comprises mineral or organic fiber as well as auxiliary material. As auxiliary material 1 - 15 Wt % of talc is added to the bulk material. Summary of the invention An object of the present invention is to provide an asbestosfree brake lining, which can prevent occurance of a low-frequency brake noise in a braking operation. Another object of the present invention is to provide an asbestos-free brake lining, which is excellent in fading resistance and wear resistance. Still another object of the present invention is to provide an asbestos-free brake lining capable of preventing ignition in a braking operation and excess wear of a counter-rotor, which have been problematically caused in a conventional semi-metallic lining. The aforementioned objects are solved by the characterizing features of the independent claims. Preferred embodiments of the invention are characterized by the features of the dependent claims. An asbestos-free brake lining according to the present invention contains a base material, an auxiliary material and a filler, and is obtained by molding with a binder In one aspect of the present invention, the base material contains 2 to 30 volume percent of copper-containing fiber with respect to the brake lining. The auxiliary material contains 1 to 30 volume percent of talc with respect to the brake lining. In another aspect of the present invention, the base material contains 2 to 15 volume percent of copper-containing fiber with respect to the brake lining. The auxiliary material contains 2 to 25 volume percent of talc with respect to the brake lining. The brake lining has a static friction coefficient µs of 0.32 to 0.40. The ratio µs/µd of the static friction coefficient µs to a dynamic friction coefficient µd of the brake lining is 1.03 to 1.14. In still another aspect of the present invention, the base material contains at least 3 volume percent of aramid fiber with respect to the brake lining. The auxiliary material contains not more than 15 volume percent of talc with respect to the brake lining. The brake lining contains at least 1 volume percent of copper-containing fiber and/or copper-containing powder with respect to the brake lining. The content of the copper-containing fiber is less than 2 volume percent with respect to the brake lining. In a further aspect of the present invention, the base material contains 3 to 10 volume percent of aramid fiber with respect to the brake lining. The auxiliary material contains 3 to 15 volume percent of talc with respect to the brake lining. The brake lining contains 1 to 4 volume percent of copper-containing fiber and/or copper-containing powder with respect to the brake lining. The content of the copper-containing fiber is 1 to 2 volume percent with respect to the brake lining. The brake lining has a static friction coefficient µs of 0.32 to 0.40. The ratio µs/µd of the static friction coefficient µs to a dynamic friction coefficient µd of the brake lining is 1.03 to 1.14. The term "asbestos-free" means that no asbestos is contained. The term "copper-containing fiber" indicates fiber which contains copper, i.e., copper fiber and/or copper alloy fiber, in more concrete terms. The term "copper-containing powder" indicates powder which contains copper, i.e., copper powder and/or copper alloy powder, in more concrete terms. It is generally said that a brake noise is caused by the so-called stick-slip phenomenon, which takes place between a brake lining and a counter-rotor. This stick-slip phenomenon is conceivably liable to occur in a brake lining which has a large static friction coefficient and a small dynamic friction coefficient, i.e., a brake lining which has a large ratio R (µs/µd) of the static friction coefficient to the dynamic friction coefficient. In this point of view, the inventors have calculated friction coefficient ratios R as to the conventional asbestos, low-steel and non-steel linings. As the result, it has been recognized that the asbestos lining, which hardly causes a low-frequency brake noise, has a small static friction coefficient, and hence its friction coefficient ratio R is reduced. It has also been recognized that the low-steel or non-steel lining, which easily causes a low-frequency brake noise, has a large static friction coefficient, and hence its friction coefficient ratio R is increased. The inventive brake lining contains one or both of prescribed amounts of copper-containing fiber and copper-containing powder, as well as a prescribed amount of talc. The static friction coefficients of copper-containing fiber, copper-containing powder and talc are smaller than that of steel fiber. Therefore, the overall static friction coefficient of the inventive brake lining, which contains copper-containing fiber and/or copper-containing powder as well as talc, is reduced as compared with that of the conventional low-steel or non-steel lining. It is conceived that the friction coefficient ratio R of the overall brake lining is reduced as the result, to suppress occurrence of a low-frequency brake noise. The inventive brake lining, which contains no asbestos, exerts no harmful influence on the human body and environment. Further, this brake lining suppresses occurrence of a low-frequency noise in a braking operation, to give no unpleasant feeling to the driver etc. In addition, the inventive brake lining is excellent in fading resistance and wear resistance. The copper-containing fiber is high-priced. In one aspect of the present invention, therefore, the brake lining contains only a small amount of or absolutely no such high-priced copper-containing fiber, to reduce the cost. The inventive brake lining effectively solves the problems of ignition in a braking operation and excess wear of the counter-rotor, which have been problematically caused in the conventional semi-metallic lining. DESCRIPTION OF THE PREFERRED EMBODIMENT In order to confirm effects of the present invention, the inventors have prepared samples of an asbestos lining and the inventive asbestos-free brake lining respectively, and made performance tests on these samples. As to Example of the inventive asbestos-free brake lining, five samples were prepared in compounding ratios shown in Table 1. As to Comparative Example, four samples were prepared in compounding ratios shown in Table 2. Referring to Tables 1 and 2, the numerals denote values of volume percentage. The volume percentage values are multiplied by true density values of the respective raw materials, in terms of compounding weight ratios. The brass fiber as employed was in a composition ratio of 70 percent by weight of copper to 30 percent by weight of zinc. The bronze fiber was defined as PBC2C under JIS (Japanese Industrial Standards). The copper-containing fiber as employed was 60 µm in diameter and 3 mm in length. Four additional samples were prepared in compounding ratios shown in Table 3, as Example of the inventive asbestos-free brake lining. Further, two additional samples were prepared in compounding ratios shown in Table 4, as Comparative Example. Referring to Tables 3 and 4, the numerals denote values of volume percentage. The volume percentage values are multiplied by true density values of the respective raw materials, in terms of compounding weight ratios. As to the item of "copper powder and/or copper-containing fiber" in Table 3, the samples Nos. A-6 and A-8 contained only copper powder, while the sample No. A-7 contained only copper fiber. The sample No. A-9 contained 1.5 volume percent of brass fiber and 2.0 volume percent of copper powder. The brass fiber as employed was in a composition ratio of 70 percent by weight of copper and 30 percent by weight of zinc. The copper-containing fiber was 60 µm in thickness and 3 mm in length. Components of a brake lining are classified into a base material, an auxiliary material and a filler. Referring to Tables 1 to 4, copper fiber, brass fiber, bronze fiber, aramid fiber, glass fiber, steel fiber, rock wool and asbestos serve as base materials, and barium sulfate and cashew dust (cashew nut shell oil friction particles) serve as fillers, while copper powder, talc and artificial graphite powder serve as auxiliary materials. Phenolic resin serves as a binder. The respective samples were prepared by mixing the raw materials in the compounding ratios shown in Tables 1 to 4, moulding the mixtures, and curing the same. The raw materials were mixed in an Irich mixer. In the moulding process for each sample, prescribed amounts of raw materials were introduced into a mold, which was heated to a temperature of 160°C, and subjected to venting (degassing) at appropriate timing. A pressure was applied in a constant pressurizing system for 10 minutes. The pressure value was so properly selected that the as-formed brake lining was provided with pores of 10 % in calculation. The porosity of each sample was calculated by difference between true density and apparent density of the sample, as expressed in the following equation: (true density) = (apparent density) (100- porosity) /100 True density values of the respective raw materials were measured in an inert gas replacement system such as a pycnometer, to calculate true density of the sample in accordance with a recipe. Apparent density was evaluated by the weight of the sample and volume measurement through outside dimensions. The curing process was carried out at 230°C for 13 hours. The 15 samples shown in Tables 1 to 4 were prepared through the aforementioned steps. The as-formed samples were subjected to visual inspection for presence/absence of cracking. As the result, cracks were observed in the samples Nos. C-4, C-5 and C-6 according to Comparative Example. Although degassing timing in the thermoforming process was changed in various ways in order to eliminate such cracks, it was impossible to obtain effective linings. Then, static and dynamic friction coefficients µs and µd were measured as to the remaining 12 samples, excluding the aforementioned samples Nos. C-4 to C-6. For the measurement of such values, the samples were pressed against counter-rotors, which were at temperatures of 50°C, with surface pressures of 10 Kg/cm². Table 5 shows the results. Table 5 shows the static friction coefficients µs and ratios R of the static friction coefficients µs to the dynamic friction coefficients µd. As understood from Table 5, the static friction coefficients µs and the ratios R of the samples Nos. A-1 to A-9 according to Inventive Example and the sample No. C-1 (asbestos lining) according to Comparative Example were smaller than those of the samples Nos. C-2 and C-3 according to Comparative Example. The sample No. C-2 is a conventional non-steel lining, and the sample No. C-3 is a conventional low-steel lining. Thereafter the samples were applied to actual vehicles, and subjected to brake noise tests. Table 6 shows a braking schedule. Brake noises, which were caused during braking operations, were measured with accelerometers, and vibration was separated in a range of 20 Hz to 1 KHz through bandpass filters. The brake noises were counted upon generation of vibration in excess of a constant frequency, while such brake noises, which were caused during test braking, were separated into low-frequency noises and general brake noises, to calculate the rates of occurrence of the low-frequency brake noises. Table 7 shows the results. Comparing Table 7 with Table 5, it is recognized that the rates R of friction coefficients of the brake linings substantially correlate to the rates of occurrence of low-frequency brake noises. Namely, it has been proved that the rates of occurrence of brake noises are reduced with reduction of the rates R of friction coefficients. As shown in Table 7, the rates of brake noise occurrence of the inventive samples Nos. A-1 to A-9, which are equal or slightly inferior to that of the asbestos lining (sample No. C-1), are extremely lower than those of the conventional non-steel lining (sample No. C-2) and low-steel lining (sample No. C-3). Thus, it is clearly understood that the inventive samples are effective for reduction of low-frequency brake noises in braking operations. Among the inventive samples, the samples Nos. A-4 and A-6 contained particularly smaller amounts of talc and exhibited larger rates of brake noise occurrence as compared with the remaining ones. On the other hand, the samples Nos. A-1, A-2 and A-9, which contained the largest amounts of talc among the inventive samples, exhibited lower rates of brake noise occurrence as compared with the remaining ones. From the results of the aforementioned performance tests for the brake lining samples, the following facts have been ascertained: As to Inventive Samples Nos. A-1 to A-5 : 1) The amount of copper fiber or copper alloy fiber contained in the brake lining is preferably in a range of 2 to 30 volume percent, and more preferably, in a range of 2 to 15 volume percent. Strength of the brake lining is insufficient if the content of such copper-containing fiber is less than 2 volume percent, while the brake lining is excessively increased in thermal conductivity and manufacturing cost if the content exceeds 30 volume percent. 2) The amount of talc contained in the brake lining is preferably in a range of 1 to 30 volume percent, and more preferably, in a range of 2 to 25 volume percent. The effect of suppression of a low-frequency brake noise is reduced if the content of talc is less than 1 volume percent, while it is difficult to mould the brake lining if the content exceeds 30 volume percent. As to Inventive Samples Nos. A-6 to A-9 : 1) The brake lining must contain at least 1 volume percent of copper-containing fiber and/or copper-containing powder. If the content is less than 1 volume percent, thermal conductivity is reduced and the brake lining is deteriorated in fading resistance etc. The content of copper-containing fiber is less than 2 volume percent. 2) The brake lining must contain less than 15 volume percent of talc. If the content exceeds 15 volume percent, a compact prepared in a molding step is cracked, and strength of the brake lining is insufficient. 3) The brake lining must contain at least 3 volume percent of aramid fiber. If the content is less than 3 volume percent, strength of the brake lining is insufficient. The copper-containing fiber used in Example of the present invention preferably has an aspect ratio of at least 20 and a fiber diameter of not more than 200 µm.

Claims: An asbestos-free brake lining containing a base material, an auxiliary material, containing 1 to 30 volume percent of talc with respect to the brake lining and a filler and being molded with a binder, characterized in that said base material contains 2 to 30 volume percent of copper-containing fiber with respect to said brake lining. A brake lining in accordance with claim 1, wherein the content of said copper-containing fiber with respect to said brake lining is 2 to 15 volume percent. A brake lining in accordance with claim 1, wherein the content of said talc with respect to said brake lining is 2 to 25 volume percent. A brake lining in accordance with claim 1, wherein said copper-containing fiber has an aspect ratio of at least 20 and a fiber diameter of not more than 200 µm. A brake lining in accordance with claim 1, wherein said base material contains 5 to 20 volume percent of aramid fiber with respect to said brake lining. An asbestos-free brake lining containing a base material, an auxiliary material containing 2 to 25 volume percent of talc with respect to said brake lining and a filler, and being molded with a binder, characterized in that said base material contains 2 to 15 volume percent of copper-containing fiber with respect to said brake lining, that said brake lining has a static friction coefficient µs of 0,32 to 0,40, and that the ratio of µs/µd of that static friction coefficient µs to a dynamic friction coefficient µd of the brake lining is 1,03 to 1,14. An asbestos-free brake lining containing a base material, said base material containing at least 3 volume percent of aramid fiber with respect to the brake lining, an auxiliary material containing not more than 15 volume percent of talc with respect to the brake lining and a filler, and being molded with a binder, characterized in that said brake lining contains at least 1 volume percent of copper-containing fiber and/or copper-containing powder with respect to the brake lining, and the content of said copper-containing fiber with respect to said brake lining is less than 2 volume percent. A brake lining in accordance with claim 7, wherein the content of said aramid fiber with respect to said brake lining is 3 to 10 volume percent. A brake lining in accordance with claim 7, wherein the content of said talc with respect to said brake lining is 3 to 15 volume percent. A brake lining in accordance with claim 7, wherein the content of said copper-containing fiber and/or said copper-containing powder with respect to said brake lining is 1 to 4 volume percent. A brake lining in accordance with claim 7, wherein the content of said copper-containing fiber with respect to said brake lining is 1 to 2 volume percent. A brake lining in accordance with claim 7, wherein said base material contains 3 to 10 volume percent of aramid fiber with respect to said brake lining. A brake lining in accordance with claim 7, wherein said copper-containing fiber has an aspect ratio of at least 20 and a fiber diameter of not more than 200 µm. An asbestos-free brake lining containing a base material containing 3 to 10 volume percent of aramid fiber with respect to the brake lining, an auxiliary material containing 3 to 15 volume percent of talc with respect to the brake lining and the filler and being molded with a binder, characterized in that the brake lining contains 1 to 4 volume percent of copper-containing fiber and/or copper-containing powder with respect to the brake lining, that the content of the copper-containing fiber with respect to the brake lining is 1 to 2 volume percent, that the brake lining has a static friction coefficient µs of 0,32 to 0,40, and the ratio of µs/µd of the static friction coefficient µs to a dynamic friction coefficient µd of the brake lining is 1,03 to 1,14.

Inventors: IBUKI MASANORI, KISHIMOTO HIROYA, NAKAGAWA MITSUHIKO, YAMASHITA YUKINORI, IBUKI, MASANORI, KISHIMOTO, HIROYA, NAKAGAWA, MITSUHIKO, YAMASHITA, YUKINORI
Applicants: SUMITOMO ELECTRIC INDUSTRIES, SUMITOMO ELECTRIC INDUSTRIES, LTD.
Application year: 1991
Main classification: F16D69
IPC codes: C09K3, F16D69