A PROCESS FOR THE PRODUCTION OF CYCLIC SULFONIUM SALTS

Abstract: A process for the production of a 5-7 membered ring cyclic sulfonium salt compound, including a 5-7 membered ring cyclic sulfonium salt compound having a non-nucleophilic anion, is described. Members of the latter group are potentially useful as initiators for cationic polymerizations. The process comprises reacting a 1.4-, 1.5-, or 1.6-diol compound or a 5-7 membered ring cyclic ether compound with a mercapto compound and a strong protonic acid yielding the cyclic sulfonium salt compound. Some compounds described are also novel compounds per se.

Description: A PROCESS FOR THE PRODUCTION OF CYCLIC SULFONIUM SALTS The present invention relates to a process for the production of a 5-7 membered ring cyclic sulfonium salt compound, including a 5-7 membered ring cyclic sulfonium salt compound having a non-nucleophilic anion. Representatives of the latter group are potentially useful as initiators for cationic polymerizations. More specifically, the invention relates to a process comprising reacting a 1 ,4-, 1,5-, or 1,6-diol compound or a 5-7 membered ring cyclic ether compound with a mercapto compound and a strong protonic acid yielding the cyclic sulfonium salt compound . The process of the invention is general, efficient, and performable in one step resulting in a product in high yield and purity, and a wide variety of 5-7 membered ring cyclic sulfonium salt compounds can be produced by the invention. The invention further relates to some compounds which are novel compounds p e r se. These novel compounds were produced by the process of the invention. Background of the Invention Tris organo sulfonium salts is an important class of sulfur compounds. Sulfonium salts have received renewed interest since the discovery that some triaryl sulfonium salts could be utilized as latent initiators for cationic polymerization, as disclosed in US-patents 4,058,400 and 4,058,401. These salts were activated photochemically. More recently, it has been found that some benzylic sulfonium salts can be utilized as latent thermal initiators for cationic polymerization, see for example PCT-application SE 90/00179 (23 Mars 1989); US-patent 5,013,814 (16 January 1989); Japan-patent no. JP 63,221 ,1 1 1 (1 1 Mars 1987) Chem. Abstr. l9S8, 11 1 , 40092; Endo, T and Uno, H. /. Polym. Sci., Polym. Lett. Ed. 1985, ____, 359; Pappas S. P. and Hill, L. W. /. Coat. Technol. 1981, ____, 43. The latter have been shown to be thermally labile and decompose upon heating, leading to heterolytic cleavage of a sulfur-carbon bond yielding a sulfide and a carbocation capable of initiating the cationic polymerization. It has also been shown that the propagation rate of the cationic polymerization is very much dependent of the nature of the anion and, as a result, it is necessary that the sulfonium salt initiator has a non-nucleophilic anion X " , e.g. SbFβ " , PF6 " , AsFβ " , and BF4-, as disclosed in US-patents 4,058,400 and 4,058,401 , J. Appl. Polymer Sci. 1978, 41, 4826 and Makromol. Chem. 1985, 136. Prior art Methods for producing sulfonium salts have been extensively reviewed, see for example, Methoden der Organischen Chemie (Houben-Weyl) 1955, Volume IX, 171 ff , and 1985, supplement E 11, 405 ff; Lowe, P. A. The Chemistry of the Sulphonium Group, Ed. Stirling and Patai 1981 , 267-313. More specificially, synthetic routes for preparing cyclic sulfonium salts have also been described, see for example Dittmer, D.C. and Patwardhan, B.H. The Chemistry of the Sulphonium Group Ed. Stirling and Patai, 1981, 387-522. Some of the methods most frequently used include monoalkylation of a sulfide or dialkylation of a mercaptan with a powerful alkylating agent R-Y, such as an alkyl halide, whereby the leaving group of the alkyl halide becomes the counter ion of the sulfonium cation. However, these methods are suffer from a number of disadvantages; Firstly, there are limitations in alkylating agents which are reactive enough to succeed in alkylating a sulfide. Therefore, in the most cases, the structural scope of R is limited to methyl, primary alkyl, or benzylic groups. Among the alkyl halides, alkyl iodides are normally required and only in favorable cases bromides can be used. Secondly, due to the limited access of alkylating agent consisting of any of the anions above as the nucleofuge, Meerweϊn's salt (triethyl oxonium tetrafluoroborate; Et3θ + BF ") is an exception, an ion-exchanging step is required in order to prepare a cyclic or acyclic sulfonium salt having a non-nucleophilic anion, leading to additional process steps. The ion-exchange is achieved by addition of a salt A + X" (A is usually an alkali metal or silver) and from the mixture the desired cyclic or acyclic sulfonium salt has to be isolated. The efficiency of such a metathesis step relies on complete and selective extraction of the desired R3S + X" to a suitable organic solvent or finding a solvent system wherein R3S + Y" is soluble and R3S + X" precipitates. The conditions of a complete metathesis would more or less depend on the substrate since structural changes very often affects solubility properties and the conditions have to be optimized in each case. The use of a silver salt as a precipitating agent for removal of the halide is another drawback for economical reasons, see equ RSR' + R"-Y *- X" (eq 1) A much more attractive method for making a sulfonium salt having a non- nuclephilic anion is the acid-promoted al ylation of sulfur with alcohols or ethers whereby the anion of the strong acid becomes the counter-ion of the sulfonium ion. Methods for producing sulfonium salts having non-nucleophilic anions by alkylation of sulfides with alcohols or ethers promoted by protonic acids are previously known, such as those described in: Fichter, Sjostedt Chem. Ber. 1910 , 43 , 3422; Hinsberg Chem. Ber. 1929, 62, 127 and 1936, 69, 492; Milligan, Minor /. Org. Chem. 1963, 28., 235; Bosshard Helv. Chim. Acta 1970 , 53., 1271 ; Julia Tetrahedron Lett. 1979, 1101; Okuma et al, Heterocycles 1987, 2£, 2343; PCT-application SE 90/00179 (23 Mars 1989); US-patent 5,013,814 (16 January 1989). However, a general, convenient, and efficient method has not yet been developed starting from simple mercaptans. Syntheses of some cyclic sulfonium salts made by an intra-molecular alkylation of a mercaptan promoted by acid have been reported - Eastman, R. H. and Kritchevsky, G. /. Org. Chem. 1959, 24_. 1428. However, in these examples, very complicated mercaptans were used, which had to be synthesized prior to the cyclization. These examples lack generality. PCT-application SE 90/00179 describes some cyclic sulfonium salts having non- nucleophilic anions used as latent thermal initiators for cationically polymerizabl compounds. It was shown that the thermal stability of 2-aryl tetrahydrothiophenium sulfonium salts could be controlled by the the aryl group. All salts were synthesized by known methods utilizing strong electrophiles such as alkyl halides and Meerwein's salt for alkylation of cyclic sulfides. These methods suffer from the drawbacks mentioned above. Such salts can now be produced much more efficiently and in higher yields and purity using the process of the present invention. In addition, the present invention allows the synthesis of a wide variety of different 2-aryl tetrahydrothiophenium sulfonium salts allowing fine tuning of the initiator properties such as initiating temperature, solubility and "shelf life". Summary of the invention The present invention provides a novel and efficient process for the production of a 5-7 membered ring cyclic sulfonium salt compound, including a 5-7 membered ring cyclic sulfonium salt compound having a non-nucleophilic anion. Members o the latter group are potentially useful as initiators for cationic polymerizations. More specifically, the process comprises reacting a 1 ,4-, 1 ,5-, or 1 ,6-diol compound or a 5-7 membered ring cyclic ether compound with a mercapto compound and a strong protonic acid yielding the cyclic sulfonium salt compound having the desired anion. The invention also provides a general process for the production of a wide variety of structurally different cyclic sulfonium salt compounds. The structural plurality available by this invention includes the sulfur-containing heterocyclic ring, which is derived from the diol or the cyclic ether reactant, the "R"-substituent which is derived from the mercaptan reactant, and X " which is derived from the acid reactant. These three reactants can be varied independently allowing production of a large number of possible 5-7 membered ring cyclic sulfonium salts. In addition, by using either a di- or polyfunctional mercapto compound or a di- or polyfunctional diol or cyclic ether compound as the reactant it is possible . to produce a di- or polyfunctional sulfonium salt, i. e. a compound containing two or more cyclic sulfonium groups. The invention provides mild reaction conditions and room temperature or slightly above is generally applicable. The process is very efficient and substantially equimolar amounts (relative to the functional groups) of the diol/cyclic ether compound and the mercapto compound with a slight excess of the protonic acid is sufficient to form the sulfonium salt compound quantatively. Since the sulfonium salt compound is formed quantitatively (in most cases) the workup simply includes removal of excess protonic acid reactant followed by recrystallization of the crude product, thus making the process very easily adaptable for large scale production. It is well known to those skilled in the art that many diols and cyclic ethers are generally easily accessible, both as commercially available starting materials and also by the numerous organic transformations available for the production of diols and ethers. The invention allows synthesis of a wide variety of 5 to 7 membered cyclic sulfonium salts by simply varying the diol or ether reactant. The mercapto compound, according to this invention, can be selected from a wide variety of structurally different mercaptans such as methyl mercaptan, primary, secondary, tertiary alkyl mercaptans, aryl mercaptans, dimercaptans, and polymercapto compounds, consisting of both straight, cyclic and branched chain hydrocarbyl groups. According to this invention, any strong protonic acid can furnish the transformation of the diol/cyclic ether compound and the mercapto compound to the sulfonium salt compound. This implies that by selecting the protonic acid, structurally different sulfonium salt compounds having a wide variety of anions, i.e. anions of desired properties, can be produced, including sulfonium salt compounds having non-nucleophilic anions. The possibilities of producing pure and structurally different cyclic sulfonium salts having different anions are thereby markedly improved since the process does not introduce any other anions, than the corresponding base to the strong acid, that otherwise could contaminate the desired sulfonium salt. The structural scope of the alkylating agent according to the prior art , i.e. where a cyclic sulfide is alkylated intermolecularly, is in practice limited to methyl and primary alkyl halides. Synthesis of cyclic sulfonium salts having a secondary or tertiary hydrocarbyl group attached to the sulfur atom by alkylation of a sulfide with a secondary or a tertiary alkyl halide are not possible. There are no such limitations in the present invention, wherein the diol or the cyclic ether group, promoted by the strong protonic acid, alkylates the mercapto group. The cyclic sulfonium salts having the structures discussed above can easily be produced in high ^ yields and purity. As noted above, the mercaptan can be selected from methyl mercaptan, primary, secondary, or tertiary alkyl, or aryl mercaptans. According to the process of the invention, either a diol or the corresponding cyclic ether can be used as one of the reactants. The diol or the corresponding cyclic ether can be mono-, di- or polyfunctional. At an early stage of the reaction under the conditions of the invention, i.e. the presence of a strong protonic acid, the diol is first transformed to the corresponding cyclic ether, see figure 1. Such transformations are well known from the literature, see for example Schmoyer et al. Nature 1960. 1 87. 592, where 1 ,4-butanediol was transformed to tetrahydrofuran. However, under the specific conditions of the present invention, i.e. in the presence of a mercaptan and a strong protonic acid, the reaction proceeds directly to the sulfonium salt product via the intermediate cyclic ether product and an intermediate sulfidoalcohol. Consequently, there is an equivalence between a diol and the corresponding cyclic ether and either of them could be used as one of the reactants, see equation 2. C OH 0r RSH * ~ V S+"R X " (βq 2) The invention very efficiently utilizes the reactants since the wasted leaving group is one or two water molecule/s (18 or 36 grams per mole of formed sulfonium salt) when using a cyclic ether or a diol as the alkylating agent, as compared to the prior art where in the first step iodide (129 grams per mol of sulfonium salt) is wasted when utilizing an alkyl iodide as the alkylating agent. In order to obtain the desired non-nucleophilic anion, the necessary ion-exchange leads to an additional waste, usually an alkali metal such as sodium or potassium, or silver; 23, 39, and 108 atomic units, respectively. In summary, the two-step procedure: an alkyl iodide followed by sodium hexafluorophosphate would produce a waste of 152 g of sodium iodide, whereas the one-step diol route produces 32 g of waste per mole of sulfonium salt which in the latter case is water. Consequently, more of the reactants ends up in the sulfonium salt by employing the present invention. Other objectives and advantages will become apparent from the detailed description of the invention which follows. Detailed Description of the Invention The present invention relates to a process for the production of a 5-7 membered ring cyclic sulfonium salt compound comprising reacting a 1,4-, 1,5-, or 1,6-diol compound or a 5-7 membered ring cyclic ether compound with a mercapto compound and a strong protonic acid. The reaction is performed by adding the strong protonic acid to the mercapto compound and the resulting mixture is added to the diol or -cyclic ether compound, or the strong protonic acid is added to a mixture containing the mercapto compound and the diol or cyclic ether compound, in substantially equimolar amounts with respect to the functional groups involved. The reaction is thus performed . in the above preferred order of mixing of the reactants. Reverse order of mixing, i.e. first mixing the strong protonic acid with the diol/cyclic ether compound in the absence of the mercapto compound, usually results in unwanted and rapid polymerization of the diol/cyclic ether compound. According to this invention the mercapto compound can be mono-, di-, or polyfunctional, with respect to the mercapto group. The diol or cyclic ether compound can be mono-, di-, or polyfunctional, with respect to the diol or cyclic ether group. Polyfunctionality relates to three or more groups, preferably 3-50 groups for the diol or cyclic ether compound and preferably 3-500 groups for the mercapto compound. The present invention also relates to the process above for the production of a cyclic sulfonium salt compound having a non-nucleophilic anion. Typically, a non- nucleophilic anion is characterized by a polyatomic molecule, MZ n " consisting of a central atom M symmetrically surrounded by 4 or 6 atoms Z which are more electronegative than the central atom. A non-nucleophilic anion have none or very little ability to form covalent bonds and usually they are the corresponding base to a very strong protonic acid. According to one embodiment of the invention the process comprises reacting: (a) a mercapto compound having the formula R -SH, wherein R in a monofunctional mercaptan represents methyl, primary, secondary, or tertiary alkyl or cycloalkyl; aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, phenyl, phenoxy or thiophenoxy; and naphthyl; arylalkyl, preferably benzyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, alkoxy or thioalkoxy; or R^ in a di- or a polyfunctional mercaptan represents -[A-SH] m . wherein m > 1 , and A independently represents alkylene, preferably Q2 -C20 - arylene, preferably phenylene, biphenylene or naphtylene; alkylenebisaryl preferably metylenebifenyl; or aralkylene, preferably xylylene, wi th (b) a diol compound selected from the group consisting of formula I: whe rei n n is 1 ,2, or 3, R2 independently represents hydrogen, alkyl, cycloalkyl, or aryl, preferably (R 7 ) v -σ. wherein y is an integer between 0 and 5, and R? independently represents alkyl, alkoxy, thioalkoxy, halogen, cyano, alkyl sulfonyl, aryl sulfonyl, preferably phenyl sulfonyl, aryl, aryloxy, or thioaryloxy, wherein the aryl group preferably is phenyl which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenoxy, thiophenoxy, cyano, alkyl sulfonyl, or aryl sulfonyl, preferably phenyl sulfonyl, R 3 independently represents hydrogen, alkyl, cycloalkyl, aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenoxy or thiophenoxy, R independently represents hydrogen, alkyl, cycloalkyl, aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenoxy or thiophenoxy, or R3 and R^ together form an aryl group fused with the corresponding carbon atoms integer between 0 and 4, and R° » independently represents alkyl, alkoxy, thioalkoxy, halogen or phenyl, R5 independently represents hydrogen, alkyl, cycloalkyl, aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenoxy or thiophenoxy, R > independently represents hydrogen, alkyl, cycloalkyl, aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenoxy or thiophenoxy, o r (c) a cyclic ether compound selected from the group consisting of formula II: wherein n, R^, R3, R t R5 ^ m & R6 are as defined above, (d) and a strong protonic acid having the formula HX, wherein X represents a halogen or a group of the formula MY r> wherein M represents Sb, P, B, As, or Cl; Y represents a halogen or oxygen; and r is an integer between 4 and 6, or X represents a group RSO3 wherein R is OH, alkyl, aryl or halogen substituted alkyl or aryl group, yielding a monofunctional cyclic sulfonium salt compound, when R- ≠ -[A-SH] m , having the following structural formula HI-1: wherein n, R , R^, R3 , R4 t R5 > R6 > an( j x are as defined above with the exception of that R* ≠ -[A-SH] m ; or a di- or polyfunctional cyclic sulfonium salt compound, when R l = -fA-SH] m , having the following structural formula III-2: wherein n, m, A, R^, R3 , R4 > R5 , R6 > aru j are as defined above. The reaction of the process involves displacement of the oxygen atom/s by the sulfur atom, yielding the cyclic sulfonium salt compound having the structural formulae above. The invention also comprises a rearrangement reaction, under the conditions of the process as defined above; When the diol compound of formula I) or the cyclic ether compound of II), when n=l and R^ and R^ together form a fused aryl group as defined, one R^ can additionally define an 1-alkenyl, (R9)2C=C(R 10)- , wherein R" and RΪ O independently represent hydrogen, alkyl, cycloalkyl, aryl, preferably phenyl, or a 5-7 membered ring formed by R^ and Rl O ; preferably hydrogen, i.e. a vinyl group, yielding a cyclic sulfonium salt compound having the following structural formula IV: wherein R 1 , R 2 , R 5 , R 6 , R 8 , and z are as defined, exept that R 1 ≠ -[A-SH] ni ' Mercapto compounds which are useful in this reaction can be selected from mono-, di- or polyfunctional mercaptans. Suitable monofunctional mercaptans can be selected from methyl mercaptan, primary, secondary, or tertiary alkyl or cycloalkyl mercaptans, in which the term "alkyl" includes both straight and branched chain saturated hydrocarbyl moieties and generally includes moieties having from 2 to 20 C-atoms, including ethyl, n-propyl, iso-propyl, n-butyl, iso- butyl, sec-butyl, t-butyl, n-pentyl, iso-pentyl, sec-pentyl, neo-pentyl, n-hexyl, iso- hexyl, n-heptyl, iso-heptyl, octyl, nonyl, decyl, undecyl, dodecyl, hexadecyl, and octadecyl moieties, preferably the moieties having 1 to 12 C-atoms, and the term "cycloalkyl "includes cyclic saturated hydrocarbyl moieties and generally includes moieties having from 3 to 7 C-atoms in the cyclic moiety, preferably 5 to 7, such as cyclopentyl, cyclohexyl, and cyclopheptyl in which the cyclic moiety can be directly bonded to the mercapto group or separated from the mercapto group by an alkylene group, such as methylene. Further monofunctional mercaptans which are useful in this reaction can be selected from aryl mercaptans, preferably phenyl mercaptans, which are unsubstituted or mono- or independently polysubstituted by alkyl, preferably Ci-Cg, cycloalkyl, preferably C5-C7, alkoxy, preferably Ci -Cs, thioalkoxy, phenyl, phenoxy, or thiophenoxy, or naphtyl mercaptan; arylalkyl mercaptans, preferably benzyl mercaptans, which are unsubstituted or mono- or independently polysubstituted by alkyl, alkoxy, or thioalkoxy. Preferred monofunctional mercaptans in the reaction are primary, secondary, and tertiary alkyl, aryl, and benzyl mercaptans, most preferably the primary, secondary, and tertiary C2-C12 alkyl mercaptans. Suitable di- and polyfunctional mercaptans in this reaction can be selected from compounds of the general formula HS-[A-SH] , wherein m > 1, and A independently represents alkylene which can be substituted, preferably C2-C2O. for example ethylene, propylene, butylene, pentylene, hexylene; arylene, preferably phenylene, bϊphenylene or naphtylene; alkylenebisaryl , preferably metylenebifeπyl; or aralkylene, preferably xylylene. Examples of dimercaptans are: 1,2-ethane-dithioI, 1,3-propane-dithiol, 1,4-butane-dithiol, 2,3-butane-dithiol, 1,6-hexane-dithiol, and α.α'-dimercapto-p-xylene. Polymercaptans can consist of an oligomeric or polymeric chain having pendant mercapto groups. Diol or cyclic ether compounds which are useful in this reaction can be selected from mono-, di- or polyfunctional diols or cyclic ethers. Suitable monofunctional ^rxnσ,- diols and cyclic ethers can be selected from 1,4-, 1,5-, 1,6-diols, or 5-7 membered ! r cyclic ether compounds (i.e. tetrahydrofurans, tetrahydropyrans, or hexahydrooxepins) respectively, which are i) unsubstituted, or ii) mono- or independently polysubstituted by alkyl, preferably C1 -C8, cycloalkyl, preferably C5-C7, l-alkenyl, preferably vinyl, aryl preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, preferably C1-C12, cycloalkyl, preferably C5-C7, alkoxy, preferably C1-C12. thioalkoxy, preferably C1 -C4, halogen, cyano, alkyl sulfonyl, preferably Ci -Cβ, aryl sulfonyl, preferably phenyl sulfonyl, aryl, preferably phenyl, aryloxy, preferably phenoxy, or thioaryloxy, preferably thiophenoxy; and/or iii) aryl fused, preferably benzo, which is unsubstituted or mono- or independently polysubstituted by alkyl, preferably C1 - C 12. cycloalkyl, preferably C5-C7, alkoxy, preferably C1 -C 1 2, thioalkoxy, preferably C1 -C4, halogen preferably chloro and bromo, phenyl, phenoxy, or thiophenoxy, or iv) cycloalkyl fused .which is unsubstituted or mono- or independently polysubstituted by alkyl, preferably Ci -Cs, The preferred non-fused 1 ,4-, 1,5-, and 1 ,6-diols and 5-7 membered ring cyclic eth compounds, respectively, are i) unsubstituted, or ii) mono- or independently polysubstituted by alkyl, preferably C1 -C 8 , aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, preferably C\ - C l 2. cycloalkyl, preferably C5-C7 , alkoxy, preferably C1 -C 12. thioalkoxy, preferabl C 1 -C4, halogen, preferably chloro and bromo, phenyl, phenoxy or thiophenoxy. The most preferred 1 ,4-, 1,5-, and 1 ,6-diols and 5-7 membered ring cyclic ether compounds, respectively, are aryl substituted. When having substitution by one or more aryl groups, one aryl substitutent is preferably at the 1-position of the 1 ,4-, 1 ,5-, and 1,6-diol and in the 2-position of th 5 -7 membered ring cyclic ether. The substituents on this aryl group preferably consist of any combination of alkyl or alkoxy including both straight and branche chain saturated hydrocarbyl moieties, preferably C1 -C 12. more preferably Ci -Cs, most preferably C1 -C4. When the aryl group is phenyl which is i) monosubstituted, the substitution is preferably in the 4-position, or ii) polysubstituted, the substitution is preferably in any combinations of the 2-, 4-, or 6-positions. Exampl of such phenyl substituents are 4-alkyl-, 2,4-dialkyl-, 2,4,6-trialkyl-, 4-alkoxy-, 2,4 dialkoxy-, 2,4,6-trialkoxy-, 2-alkyl-4-alkoxy-, 2-alkoxy-4-alkyl-, 2,6-dialkoxy-4- alkyl-, and 2,6-dialkyl-4-alkoxy-substituents. The diols discussed above are preferably selected from the 1 ,4-diols, and the cyclic ethers are preferably selected from the tetrahydrofurans. v or , The preferred fused 1,4-, 1 ,5-, and 1 ,6-diols' '5-7 membered ring cyclic ethers, respectively, are i) unsubstituted, or ii) mono- or independently polysubstituted b alkyl, preferably C1 -C8 , cycloalkyl, preferably C5 -C7 , vinyl, preferably in the 1- position, aryl, preferably phenyl, and iii) (2,3)-aryl fused, preferably (2,3)-benzo for the diols or (3,4)-aryl fused, preferably (3,4)-benzo for the cyclic ethers. Suitable di- and polyfunctional diols and cyclic ethers in this reaction can be selected from compounds of the general formula C-[B-C] W , wherein w > 1, C independently represents the 1,4-, 1,5-, and 1,6-diols, tetrahydrofurans, tetrahydropyrans, or hexahydrooxepions, respectively, defined as above, and B independently represents alkylene which can be substituated, preferably C2-C20. for example ethylene, propylene, butylene, pentylene, hexylene; arylene, preferably phenylene, bϊphenylene or naphtylene; alkylenebisaryl , preferably metylenebϊfenyl; or aralkylene, preferably xylylene. The C to B attachment is preferably via the 1 -position of the diol or via the 2-position of the cyclic ether. Strong protonic acids which are useful in this reaction can in principle be selected from any strong protonic acid. A strong acid (HX) is recognized by more or less complete dissociation in an aqueous solution to form a proton (H + ) and the corresponding base (X ~ ). Suitable strong protonic acids can be selected from: hydrohalogenic acids, such as hydrochloric, hydrobromic, and hydroiodic acid; perhalogenic acids, such as perchloric acid; tetrahaloboric acids, such as tetrachloroboric and tetrafluoroboric acid; hexahaloantimonic, -arsenic, and - phosphoric acids, such as hexachloroantimonic, hexafluoroantimonic, hexachloroarsenic, hexafluoroarsenic, hexachlorophosphoric, and hexafluorophosphoric acid; sulfonϊc and halogen-substituted alkyl or aryl sulfonic acids, such as p-toluensulfonic and triflic (trifluoromethane sulfonic) acid; phosphoric acid or sulfuric acid. Preferred strong protonic acids are perchloric, tetrafluoroboric, hexafluoroantimonic, hexafluoroarsenic, hexafluorophosphoric acid, p-toluensulfonic and triflic acid, most preferably tetrafluoroboric, hexafluoroantimonic, and hexafluorophosphoric acid. In the production of a cyclic sulfonium salt compound having a non-nucleophilic anion, the strong protonic acid is preferably selected from tetrafluoroboric, hexafluoroantimonic, hexafluoroarsenic, or hexafluorophosphoric acid, most preferably hexafluoroantimonic or hexafluorophosphoric acid. Since the corresponding base of the acid becomes the anion of the sulfonium salt compound, an ion-exchanging step is not necessary when using these preferred acids for producing a sulfonium salt compound having a non-nucleophilic anion. This results in a simplified one-step process. When using commercial hexafluorophosphoric acid, stabilized by about 10% w/w of hydrogen fluoride, the reaction is preferably performed in a reaction vessel which not consists of glass, but preferably a vessel consisting of plastic materials or mone alloy, most preferably a polyolefinic materials such as polyethylene, polypropylene, or teflon. The reaction can be carried out in an anhydrous protonic acid or a hydrous protonic acid solution. The term "protonic acid" refers to the strong protonic acids defined above. Preferably and conveniently the commercially available protonic acid solution is used, the concentration of which is dependent on the actual protonic acid. Examples of aqueous protonic acids are hexafluorophosphoric acid commercially available as 60% w/w solution, and hexafluoroantimonic acid available as the hydrate, HSbF6 -6 H2θ. If desired, the anhydrous protonic acid, the hydrous protonic acid or the hydrous protonic acid solution can also be diluted with water to any convenient concentration, dependent on the actual protonic acid. More concentrated protonic acid solutions are however preferred since lower concentration will result in decreased overall reaction rate of the process. The concentration of aqueous protonic acid reactant is preferably at least 25%, more preferably at least 40 %, or most preferably at least 50% w/w. The reaction can be carried out in the presence or absence of an inert organic solvent. The presence of an inert organic solvent usually but not necessary leads to a two-phase system. Examples of such inert solvents are hydrocarbons, such as n- pentane, n-hexane, n-heptane, cyclohexane; aliphatic nitriles such as acetonitrile; dimethyl sulfoxide; and halogenated hydrocarbons, such as carbon tetrachloride, methylene chloride, chloroform, tetrachloro ethane, dichloro ethane, and ethylene dichloride. Of these, halogenated hydrocarbons, particularly methylene chloride, are preferred. When an inert solvent is present in the reaction, the amount of the solvent can be varied depending on the type of solvent, the type and amount of the mercapto compound, strong protonic acid, and the diol/cyclic ether compound, etc. The amount of the solvent is preferably small since if the amount is too large, the overall reaction rate decreases. A preferred amount of solvent is less than about 2000, suitable about 200 ml per mole of the diol/cyclic ether compound. The amount ot the strong protonic acid the reaction is at least 0.5 equivalents (eq), more preferably at least 1.0 eq, most preferably at least 1.2 eq, and at most 10 eq, preferably at most 5 eq, most preferably at most 2 eq, based on the diol/cyclic ether compound. The amount of the mercapto compound in this reaction is at least 0.5 eq, preferably at least 0.9 eq, most preferably at least 1.0 eq, and at most 10 eq, preferably at most 5 eq, most preferably at most 2 eq, based on the diol/cyclic ether compound. The reaction can be carried out with equimolar amounts of the diol/cyclic ether compound and the mercapto compound with a slight excess of the protonic acid reactant. The relevant stochiometry of the reactants discussed herein refers to the reacting functional groups. Concequently, total conversion of, for example, 1 mole of a difunctional mercaptan (2 eq -SH) theoretically requires 2 moles of a monofunctional diol/cyclic ether and 2 moles of a protonic acid. The excess of acid required depends on the reactivity of the acid and the diol/cyclic ether compound. In some cases, an excess of the acid of 0.2 equivalents can be sufficient to carry the reaction to completion. However, use of larger excess of acid leads to higher reaction rate with almost no additional workup problems. Since the diol/cyclic ether compound in most cases is the most expensive of the reactants, it is economically desirable to achieve high conversion of the diol/cyclic ether compound into the cyclic sufonium salt compound. This implies that the diol/cyclic ether compound should be the limiting component. It is, however, possible to reduce the amount of the mercapto compound to 1 equivalent relative to the diol/cyclic ether compound and still produce the sulfonium salt compound in high yield and purity. This is of great importance and value since minimizing the excess of the mercapto compound will, in addition to improved economy, decrease the bad smell, caused by unreacted mercapto compound, from the effluents from the workup. It is also possible to perform the reaction with less than 1 eq, for example 0.95 eq, of the mercapto compound, resulting in total conversion of the mercapto compound into the sulfonium salt compound, thus almost eliminating any mercaptan smell from the workup. The reaction is preferably performed at a temperature from about 0 to about 70° C , more preferably from about 20 to about 50° C, particularily at room temperature. Higher reaction temperature may be useful in some cases due to sluggish reactants. Mixing the reactants require cooling due to exothermic ring-opening of the cyclic ether which is either added as a reactant or formed in situ from the corresponding diol. The temperature of the coolant should in some cases be subzero, lower than - 10°C, more preferably lower or equal to 0°C, most preferably lower than 10°C. The reaction can be performed at pressures ranging from sub-atmospheric pressure to super-atmospheric pressure , preferably at atmospheric pressure. Super- atmospheric pressure may be caused by voilatile or gaseous reactants such methylmercaptan or hydrochloric acid. The reaction can be performed under an air atmosphere. When long reaction times are needed, the atmospheric oxidation of the mercaptan to a disulfide may be a problem. The oxidation can simply be avoided by performing the reaction under an inert gas atmosphere, preferably nitrogen o argon . Some cyclic sulfonium salts of the invention are novel compounds per se . They all have benzylic substituents with respect to the sulfur atom, i.e. all are 2-aryl substituted. Such compounds are useful as latent thermal initiators for cationic polymerization, wherein the thermal latency primarily depends on the ability of the aryl substituent to stabilize positive charge at a benzylic position. The invention provides a tool for producing sulfonium salt initiators with improved solubility in polymerizable compounds which often are caracterized of hydrophobic and non-polar properties. The increased hydrophobicity was achieve by using long chain hydrocarbyl mercaptans, exemplified among the novel compounds per se . The flexibility of the reaction allows this fine tuning which constitutes a important technical contribution since solubility is problem associate with previously developed sulfonium salt initiators. Also, by the process of the invention, these novel compounds are produced in higher purity compared to previously known compounds of this type, leading to a more well-defined product and more uniform initiating characteristics. The compounds which are novel per se are aryl-substituted or aryl-fused cyclic sulfonium salt compounds having the structural formula V, VI, and VII which are: S-butyl-2-(phenyl)-tetrahydrothiophenium hexafluoroantimonate, S-butyl-2-(4-methylphenyl)-tetrahydrothiophenium hexafluorophosphate, S -butyl -2-(4-methoxyphenyl)-tetrahydrothiophenium hexafluoroantimonate, S-dodecyl-2-(4-methoxyphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(4-methoxyphenyl)-tetrahydrothiophenium tetrafluoroborate, S-butyl-2-(4-methoxyphenyl)-tetrahydrothiophenium perch lorate, S-butyl-2-(4-methoxyphenyl)-tetrahydrothiophenium tri fl ate, S-butyl-2-(4-isopropylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(4-tert-butylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(2,4-dimethylphenyl)- tetrahydrothiophenium hexafluorophosphate, S-tert-butyl-2-(2,4-dimethylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-iso-butyl-2-(2,4-dϊmethyIphenyl)-tetrahydrothiophenium hexafluorophosphate, S-iso-propyl-2-(2,4-dimethylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-dodecyI-2-(2,4-dimethylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-phenyI-2-(2,4-dimethyiphenyl)-tetrahydrothiophenϊum hexafluorophosphate, S-butyI-2-(2,4-dimethylphenyl)-tetrahydrothiophenium hexafluoroantimonate, S-butyI-2-(2-methyI-4-methoxyphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(2,4-dimethoxyphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(2,4,6-trimethylphenyI)-tetrahydrothiophenium hexafluorophosphate, S-butyI-2-(2,6-dimethyl-4-methoxy phenyl) -tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(4-methoxyphenyl)-pyranium hexafluorophosphate, S,S'-ethylene-l,2-bis[2-(4-methoxyphenyl)-tetrahydrothiophenium hexaf Iuorophospate] , S,S'-hexylene-l ,6-bis[2-(4-methoxyphenyI)-tetrahydrothiophenium hexaf iuorophospate], S,S'-p-xylylene-b is [2-(4-methoxyphenyl) -tetrahydrothiophenium hexafluorophospate], and S-Butyl-2-phenyl-[3,4]-benzo-2,5-dihydro-thiophenium hexafluorophosphate, S-Butyl-2-ι-vø-propyl-[3,4]-benzo-2,5-dihydrothiophenium hexafluorophosphate, S-Butyl-2,2-dimethyl-[3,4]-benzo-2,5-dihydrothiophenium hexafluorophosphate, S-Butyl-2-metyl-2-phenyl-[3,4]-benzo-2,5-dihydrothiophenium hexafluorophosphate, S-Butyl-2,2-diphenyI-[3,4]-benzo-2,5-dihydrothiophenϊum hexafluorophosphate, and S-Butyl-5-methyI-[3,4]-benzo-2,7-dihydrothiepinium hexafluorophosphate, S-Butyl-5-phenyl-[3,4]-benzo-2,7-dihydrothiepinium hexafluorophosphate. Best mode of operation The best mode of operation of the process according to the the present invention is to react an alkyl mercaptan, such as for example n-butyl-, iso-butyl-, sec-butyl-, o t-butyl mercaptan, with a 1-aryl substituted 1 ,4-diol or a 2-aryl substituted tetrahydrofuran, preferably the diol since the diols generally are more easily accessible, and a strong protonic acid, in which the corresponding base is non- nucleophilic. Examples of non-nuclephilic anions are: hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, and tetrafluoroborate, preferably hexafluorophosphate and hexafluoroantimonate. The aryl substituent is preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by C1 -C4 alkyl and/or C1 -C4 alkoxy. Examples of suc aryl substituens are phenyl, 4-methylphenyl, 4-methoxyphenyl, 2,4- dimethylphenyl, 2-methyl-4-methoxyphenyl, and 2,6-dimethyl-4-methoxyphenyl. The reaction is performed by slowly adding aqueous HPF6 (60% w/w, 1.5eq) to an ice-cooled mixture of the diol (l.Oeq) and the mercaptan (l .Oeq). The reaction mixture is stirred (2-24h) at room temperature (20-30°C) under a N2-atmosphere . Then water (200mL/mol diol) is added and the resulting slurry is filtrated. The crystals are washed with water (200 mL/mol in portions) and aqueous NaHCC-3 (100 mL/mol diol in portions). The crude material is recrystallized in ethanol (99.5%, 0. 1 1/kg crude material). Description of the figures The invention is illustrated by the enclosed figures 1 and 2. Figure 1 shows the intermediates of the cyclization-reaction of l-(2,4- dimethylphenyl)- l ,4-butanediol 6f with n-butyl mercaptan in the presence of 31 w/w of HPF6 at 25 °C, as studied by * H-NMR as the conversion vs time. Figure 1 clearly shows the transformation of 6f to the corresponding sulfonium salt S- butyl-2-(2,4-dimethylphenyl)-tetrahydthiophenium hexafluorophosphate l f-(S - B u)-PF6 via the intermediate tetrahydrofuran 7f and sulfidoalcohol 8f. (For further experimental details, see examples 36 and 37). This means, as previously described herein, that either a diol or the corresponding cyclic ether can be used one of the reactants in the reaction according to the process of the present invention. The transformation of the diol to the cyclic ether is momentaneous under the present conditions. Figure 2 shows how the rate of formation of lf-(S-Bu)-PF(j is affected by dilution of HPF6 with water. As expected the overall reaction rate is very dependant on the proton activity. A two-fold dilution result in a 400-fold decrease of the reaction rate. The process according to the invention is further demonstrated by the following examples. It should be understood that the examples are illustrative and not limitative. Percentage are given by weight unless otherwise specified. Examples The cyclic sulfonium salts synthesized using the process of this invention in the R 2(1) R 2(2) (R ? )y 5A Me 5B Ph X= PF 6 and For compoundsl R = primary, secondary, for2 R 1 =BenzyI and tertiary alkyl, phenyl, -(CH-)--, , and p-xylylene Synthesis of cyclic sulfonium salts of type 1. l-Aryl-l,4-butane-diols 6a-| and l-(p-MeO-phenyI)-l,5-pentandioI 6k were transformed to S-alkyl-2-aryl-tetrahydrotiofenium salts 1 by reaction with a mercaptane in the presence of between 1.2-5 equivalents of the acid HX ( where X= PFg, SbF6, BF4, CIO4, and CF3SO3). The reaction was performed at 25°C or slightly above utilizing the commercial acid as the solvent or a two-phase system consisting of the commercial acid and methylene chloride. When using commercially hexafluorophosphoric acid, which is stabilized by approximative 10% w/w of hydrogen fluoride, the reactions were performed in polyethylene or polypropylene bottles. Utilizing glassflasks results in partial formation of sulfonium salts having fluorosilicates as the counter ion, see for example Christie et. al. J. Am. Chem. Soc. 1990. 1 12. 7619. The results are summarized in table 1. The salts 1 are crystallinic materials isolated as mixture of diastereomers typically in a 1:1.5 ratio. The workup was achieved by either diluting the reaction mixture with water followed by filtration of the crystallinic sulfonium salt or by extraction with methylene chloride. The reactions proceed very cleanly and usually yield pure crude products. Most of the salts however, are easily recrystallized from ethanol and in several cases crystallization afforded pure diastereomers where the trans- isomer precipitates first. The major diastereomer l c( S - M e) - PF6 was unambigously determined bye differential NOE-NMR techniques to the trans-isomer. Irradiaton of the Me-S group in the major isomer resulted in 21 % enhancement whereas irraditon of the Me-S group in the minor gave less than 3% enhancement. The reaction is general with respect to the substituent R^ including dimercaptans allowing synthesis of bis-sulfonium salts, see table 2. The reaction was also examined for a number of different mineral acids and the results are shown in table 3. The mechanism (scheme 1) of the reaction is a multistep event and includes an immediate formation of the tetrahydrofuran derivative 7 which after protonation regioselectively reacts at the benzylic position to form the sulfido alcohol 8. The isomeric sulfidoalcohol 9 has not been observed in any of the cases we studied. The reaction can easily be followed by ΪH-NMR and the methine protons on 6, 7, and 1 together with the methylene group CH2O in 8 are easily distinguished. Scheme 1 X=PF 6 , SbF 6 , BF 4 , CIO 4J CF 3 S O 3 Synthesis of the diols 6 was achieved by a two-step procedure, scheme 2, These methods are literature procedures starting with AICI3 -catalyzed Friedel-Crafts acylation of the appropriate aromatic compound 10 with succinic anhydride or glutaric anhydride to form the ω-aroyl-carboxylic acids 11, see Olah, G. A. Friedel- Crafts Chemistry John Wiley 1973 91 ff and Olah, G. A. Friedel-Crafts and Related Reactions John Wiley 1964, 1, 551 ff; Tamura, Y., Yakura, T., Yoshiaki, Y, Haruta, J. Chem. Pharm. Bull. 1985, 21. 1097. Friedel-Crafts acylations are often performed in solvents such as nitrobenzene, CS2, and chlorinated hydrocarbons. We have used the aromatic hydrocarbon 10 as the solvent for the acylation, see Fieser, L. F. and Seligman, A. M. /. Am. Chem. Soc. 1938, OH, 170. The acids 11 were then reduced to the diols 6 with LiAlH4 applying standard methodology, see for example Fieser, L. F. and Fieser, M. Reagents for Organic Synthesis John Wiley 1967, 1, 584. Scheme 2 Synthesis of benzofused cyclic sulfonium salts of type 3, 4 and 5. Substituted benzenedimethanols 12 and 13 reacted smoothly with BuSH (n- butylmercaptan= n-butanethiol) in hexafluorophosphoric acid to the sulfonium salts 3, 4, and 5, see eqation 3. The results are summarized in table 4. The diols 12 were synthesized via a general organometallic route starting from ftalide, eq 4. Grignard reagents were utilized for preparation of compounds 1 2 (R2( 1 ) = R2(2)) analogously to the procedures reported in : Smith, J. G. and Wikman, R. T. Tetrahedron 1974, 0., 2603 and Rickborn, B et. al. J. Org. Chem. 1989, ≤4_, 4253. The diols 8 (R2( 1 )≠R (2)) were prepared by mono addition of an organolithium compound to ftalid followed by reaction with a grignard reagent (R2(2 ) ≠ H) or LiAlH4 (R2(2)=H). These two steps were performed in a one-pot procedure. Mono addition of R-Li to lactones to form lactoles have been shown previously, see for example Rickbom, B et. al. J. Org. Chem. 1989, ___., 4253 and Bihovsky, R. and Rosenblum, S. B. /. Am. Chem. Soc. 1990, ill, 2746. 1 2 i) R 2C1) Lϊ, THF, -78°C, 1 h. ii) R 2(2) MgX, THF, RT or LAH for R 2(2) =H Table 2. Synthesis of 1 f-PF<; a n j c-PFc by variation of the mercaptan^ Mercap tan Reaction timeb Yield % (trans/cis) n-Butylmercaptan c 1 h 95 (1.5/1) n-Dodecylmercaptan c 20h 73 (1.6/1) ϊ-Butylmercaptanc,d 24h 94 (1.2/1) i-PropylmercaptanC.d 24h 87 (6.0/1) t-Butylmercaptanc,d 5 h 96 (>39/l) Phenylmercaptanc.e lOOh 88 (2/1) 1,2-Dimercaptoethanef.g 1 h 99 1,6-Dϊmercaptohexanef.g 2 h 83 p-Xylyleπe-α.α'-dithiolf.g 4 h 86 a)The reactions were performed in aqueous HPFβ (60% w/w; 1.5 eq) at 25°C using 1.0 eq of mercaptan relative to the diol 6f. b) Refers to the time to workup. c) The product was a lf-PFg sulfonium salt, d) >95% conversion after 1 h. e) 65% conversion after 0.5h. f) The cyclic ether 7c was used. The bis-salts are a mixture of theoretically 8 diastereomers. g) The product was a lc-PF sulfonium salt. Table 3. Synthesis of 1 cfS-Bu)-X from 7c by variation of the acid (HX)a HX (7H+l)b ConditionsC Yield % (trans/cis) HPF 6 (60%, 7.4M) 3h, 25°Cd.g 95 (1.5/1) HSbF6-6H2θ (5.8M) 20h, 50°Ce 95 (5.3/1) HBF4 (50%, 7.6M) 23h, 50°Cf-g 88 (2.2/1) HCIO4 (70%, 10.5M) 24h, 25°C 95 (2/1) CF3SO3H (98%, 3.9M) 24h, 50°C 95 (2/1) a) The reactions were performed in aqueous HX (1.5 eq) using 1.0 eq of BuSH relative to the ether 7c. b) Formal molarity of the commercial acid HX. c) Refers to the time to workup. d) 89% conversion after 1 h. e) 65% conversion after 0.5 h. f) 72% conversion after 24h. g) The diol 6c was employed as the starting material. Table 4. Synthesis of the benzo-fused sulfonium salts 3, 4, and 5. R 2 ( l ) R 2 ( 2 ) D i o l 1 2 A 12 B 12C 12D 12E 12 F 12 G 1 2J 1 3 a) Conditions: BuSH (2.0 eq), HPF6 (3.5 eq) reactions were performed at 25°C and worked up after the time shown in the table, b) The crude product contained 8% of 3a and was 2.2/1 mixture of diastereomers. c) The product was obtained as 3.3/1 mixture of two diastereomers. d) The starting material was isochromane 13. Experimental section including examples G e n er a l NMR-spectra were recorded on a 200MHz Bruker ACE spectrometer equipped with a ^ H/l ^ C-dual probe. Shifts are reported in ppm δ units relative to tetramethylsilane (internal standard) and were recorded in CDCI3 not otherwise noted. Melting points were recorded on a Electrothermal Digital Melting Point Apparatous and are uncorrected. IR spectra were obtained with a Perkin Elmer 1760 (FT1R) spectrometer. HPF6 (60% in H2O) and HSbF6-H2θ came from Ozark-Mahoning (Tulsa, Oklahoma, 74107 USA). HBF4 (48% in H2O), glutaric anhydride (98%), BuSH and MeMgCl (2M in diethylether) came from Merck. 3-Benzoylpropionic acid (11a), 2- (Hydroxymethyl)-benzylalcohol (12a ) and all other chemicals were purchased from Aldrich Chemical Co. The cyclization reactions were performed in screw- capped polypropylene plastic bottles. Elemental analysis were performed by Mikrokemi AB, Uppsala, Sweden. The following abbreviations have been used: milliliter=mL, equivalents=eq, grams---g, tetrahydrofuran=THF. General procedure for synthesis of sulfoniumsalts of type 1. General procedure A The acid (1.2-4.0eq) was added slowly to an ice-cooled solution of diol or cyclic ether (leq) and BuSH (1.0-1.5eq) in CH2CI2 (200- l OOOmL/mol diol). The reaction mixture was stirred at the indicated time and temperature under a N2-atmosphere. Water (200-1000mL/mol diol) was added, the layers were separated and the aqueous-layer was extracted with CH2CI2 (typically 3x50mL/mol diol). The combined organic layers were washed with water (typically lOOmL/mol diol) and aqueous NaHC03 (saturated, lOOmL/mol diol), then dried (MgSθ4) and concentrated by rotary evaporation. Crude crystallinic products were recrystallized in EtOH (99.5%, 0.7- lL kg crude material). Sulfonium salt obtained as oils were purified by: dissolving the crude oil in a small volume of CH2CI2 and extracted 5-10 times with petroleumether (5 times the CH2CI2 volume). Traces of mercaptan the product was removed by washing with a H2θ2-solution [H2O2 (35% w/w)/NaOH (2M) 1:4]. General procedure B The reaction is performed by slowly adding the acid (1.2-4.0eq) to an ice-cooled mixture of the diol (l.Oeq) and the mercaptan (l.Oeq). The reaction mixture is stirred at the indicated time and temperature (20-50°C) under a N2-atmosphere. Then water (200mL/mol diol) is added and the resulting slurry is filtrated. The crystals are washed with water (200 mL/mol in portions) and aqueous NaHC03 (100 mL/mol diol in portions). The crude material is recrystallized in ethanol (99.5%, 0.7- 1 1/kg crude material). Example 1: S-Butyl-2-(phenyl)-tetrahydrotiopheniiιm hexafluorophosphate [la(S-Bu)-PF6] The diol 6a (415.5g, 2.5moI) was reacted with BuSH (316g, 3.5mol) and aqueous HPF6 (60%, 912g, 3.75g) in CH2CI2 (550mL) for 24 h at RT (room temperature). Workup according to the general procedure A and recrystallization in EtOH (700mL) gave 860g (94%) white crystals of la(S-Bu)-PF6 as a 1.8/1 mixture of diastereomers. Mp: 75-80°C X H-NMR (aceton-d6): 7.75-7.40 (m, Ar-H); 5.61 (dd, IH, J=12.5 and 5.3Hz, S-CiL minor isomer); 5.32 (dd, IH, J=10.4 and 6.5Hz, S-CH, major isomer); 4.19-4.02 (m, CH2-S); 3.92-3.58 (m, CH2-S); 3.25-2.30 (m, CH-CH2-CH2); 2.00-1.80 (m, CH2-CH2-CH3); 1.58-1.15 (m, CH2-CH3); 0.91 (t, 3H, J=7.3Hz, CH3, major isomer); 0.72 (t, 3H, J=7.2Hz, CH3, minor isomer). 13 C-NMR (aceton-d6): 135.30; 130.69; 130.02; 129.92; 129.79; 128.80; 68.02; 64.65; 45.50; 44.30; 43.34; 39.10; 38.42; 31.47; 29.37; 28.05; 27.41; 27.11; 21.67; 13.17; 13.03; Anal. Calcd for C14H21SPF6: C, 45.90; H, 5.78; S, 8.75 Found: C, 45.8; H, 5.8; S, 8.2. Exa mple 2 : S-B utyI -2-(phenyl)-tetrahyd rotiopheni u m hexafluroa nti mona te [ l a (S -B u) -S bF6 ] HSbF6-6H2θ (876.5g, 2.5mol) was added to a mixture of diol 6a (208g, 1.25mol) and BuSH (135mL, 1.25mol) kept at 10°C. The reaction temperature was raised to 50°C and the mixture was stirred for 60 h. H2O (300mL) was added and two layers were formed. The aqueous-layer (+ lOOmL H2O) was extracted with CH2CI2 (2xl00mL). CH2CI2 (400mL) was added to the organic layer and the layer was washed with H2O (lOOmL), Aqueous NaHC03 (sat., 3xl00mL) and dried (MgS04). Evaporation gave 467.3g (82%). Recrystallisation in EtOH (2.6L) gave 369g (65%) of white crystals la(S-Bu)-SbF6_as a 2.7/1 mixture of diastereomers. Mp: 57.2-59.1 °C. i H-NMR: Major isomer 7.43 (s, 5H, Ar-H); 5.01 (dd, IH, J=11.3 and 5.6Hz, CH-S); 3.86-3.73 (m, IH, S- CH2); 3.63-3.52 (m, IH, S-CH2); 3.40 (t, 2H, J=8Hz, S-CH2CH2); 2.90-2.29 (m, 4H, CH2); 1.84-1.69 (m, 2H, CH.2). 1.52-1.35 (m, 2H, CH.2). 0.89 (t, 3H, J=7.3Hz, CH3); Minor isomer (distinguishable peaks in mixture with major isomer) 7.49 (s, 5H, Ar-Hj; 5.34 (dd, IH, J=11.3 and 5.6Hz, CH-S); 4.02-3.89 (m, IH, S-CH2); 1.30-1.17 (m, 2H, CK2); 0.72 (t, 3H, J=7.1Hz, CH3). 13 C-NMR: major isomer 132.91; 129.92; 129.73; 127.89; 68.97; 43.81; 43.50; 38.74; 28.87; 27.15; 21.40; 13.11 ; Minor isomer 130.82; 129.82; 129.24; 127.55; 65.30; 44.90; 38.64; 31.17; 28.06; 26.64; 21.34; 13.00. IR: 1462; 1233; 730; 703; 659 cm " 1 . Anal. Calcd for Ci4H2l SSbF6: C, 36.79; H, 4.63; S, 7.01. Found: C, 36.9; H, 4.7; S, 7.1. Example 3: S-Butyl-2-(4-methylphenyl)-tetrahydrotiophenium hexafluorophosphate [ lb(S-Bu)-PF6 ] Aqueous HPF6 (60%, 94.6g, 0.39mol) was added slowly to a mixture of diol 6b (50g, 0.28mol) and BuSH (25.06g, 0.28mol) kept at 0°C and under N2 -atmosphere. The reaction mixture was stirred for 24 h at 25°C. H2O (500mL) and CH2CI2 (lOOmL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (2x20mL). The combined organic layers were washed with aqueous NaHC03 (sat., 2x20mL) and dried (MgSθ4). Evaporation gave 89g (84%) colorless oil of l b(S-Bu)- PFό as a 1.4/1 mixture of diastereomers. ' H-NMR: Major isomer 7-34-7.19 (m, 4H, Ar- H); 5.04 (dd, IH, 1=11.1 and 6.3Hz, CH-S); 3.88-3.75 (m, IH, CH2-S); 3.70-3.57 (m, IH, CH2-S); 3.45 (t, 2H, J=7.5Hz, S-CH2CH2); 2.89-2.78 ( , IH, CH2); 2.68-2.49 (m, 2H, CH2); 2.49-2.22 (m, IH, CH2); 2.35 (s, 3H, CH3-Ar); 1.85-1.65 (m, 2H, Cfl2); 1.50-1.32 (m, 2H, CH2); 0.89 (t, 3H, J=7.2Hz, CH3); Minor isomer (distinguishable peaks in mixture with major isomer) 5.50 (dd, IH, CH-S); 2.37 (s, 3H, CH3-Ar); 0.73 (t, 3H, CH3). ^C-NMR: Major isomer 140.00; 130.28 (2C); 129.95; 127.81 (2C); 66.72; 43.83; 43.18; 38.64; 28.71; 27.14; 21.34; 21.18; 13.13;Minor isomer (distinguishable peaks in mixture with major isomer) 141.05; 130.37 (2C); 129.12 (2C); 124.58; 65.20; 45.56; 38.23; 31.20; 27.91; 26.62; 21.09; 13.06. Example 4: S-Butyl-2-(4-methoxyphenyl)-tetrahydrotiophenium hexafluorophosphate [lc(S-Bu)-PF6l The cyclic ether 7c (601g, 3.37moI) was reacted with BuSH (426g, 4.72mol) and aqueous HPF6 (60%, 1.23kg, 5.05mol) in CH2CI2 (750mL) for 24 h. Workup according to the general procedure A gave 1.33kg (100%) of crude lc(S-Bu)-PF$ as a 1.5/1 mixture of diastereomers. Recrystallisation in EtOH (IL) gave 1.038kg (78%) white crystals of lc(S-Bu)-PF6 as a 6.7/1 mixture of diastereomers. Mp: 83.7°C. ! H-NMR: Major isomer 7.38 (d, 2H, J=8.8Hz, Ar); 6.91 (d, 2H, J=8.8Hz, Ar); 5.08 (dd, IH, J=ll and 6Hz, CK-S); 4.0-3.7 (m, IH, CH2-S); 3.80 (s, 3H, MeO); 3.65-3.5 (m, IH, CH2-S); 3.42 (t, 2H, J=7.2Hz, S-CH2CH2CH2CH3), 2.9-2.25 (m, 4H, CH2); 1.75 (m, 2H, CH2); 1-43 (m, 2H, CH2); 0.89 (t, 3H, J=7.3Hz, CH3); Minor isomer 7.43 (d, 2H, J=8.8Hz, Ar); 6.95 (d, 2H, J=8.8Hz, Ar); 5.38 (dd, IH, J=ll and 6Hz, CH-S); 4.0-3.7 (m, IH, CH2-S); 3.83 (s, 3H, MeO); 3.65-3.5 (m, IH, CE2-S); 3.42 (t, 2H, J=7.2Hz, S-CH2CH2CH2CH3), 2.9-2.25 (m, 4H, CH2); 1.5-1.0 (m, 4H, CH2); 0.75 (t, 3H, J=7.3Hz, CH3). 13 C-NMR: Major isomer 160.64; 129.38 (2C); 124.55; 114.99 (2C); 69.05; 55.37; 43.43; 43.08; 38.49; 28.64; 27.15; 21.35; 13.14; Minor isomer 161.29; 130.68 (2C); 119.19; 115.05 (2C); 65.61; 55.43; 44.49; 38.17; 31.45; 27.93; 26.64; 21.35; 13.08. IR (KBr, major +minor isomer): 1518; 1260; 1186; 832 (PF6' 1 ) cm" 1 . Anal. Calcd for C15H23OSPF6: C, 45.45; H, 5.85; S, 8.09.Found: C, 45.3; H, 5.9; S, 7.7. Example 5: S-ButyI-2-(4-methoxyphenyI)-tetrahydrotiophenium hexafluorophosphate [lc(S-Bu)-PFg] The diol 6c was reacted with BuSH (1 eq) and aqueous HPF6 (60%, 1.5 eq) at 25°C for 3h according to procedure B. Extractive workup with CH2CI2 according to procedure A afforded 95% of lc(S-Bu)-PFβ as a 1.5/1 mixture of diastereomers. Example 6: S-ButyI-2-(4-methoxyphenyl)-tetrahydrotiophenium hexafluoroantimonate [lc(S-Bu)-SbF6l HSbF6*H2θ (106g, 307.5mmol) was added slowly to an ice-cooled solution of cyclic ether 7c (27.4g, 153.7mmol) and BuSH (16.5mL, 153.7mmol). The temperature was raised to 50°C and the reaction mixture was stirred for 24 h. H2O (50mL) and CH2CI2 (50mL) was added and the layers were separeted. The aqueous-layer was extracted with CH2CI2 (2x40mL). The combined organic layers were washed with aqueous NaHC03 (sat., 2x50mL) and dried (MgS04). Evaporation gave 61.6g (82%) of lc(S- Bu)-SbFg as a colorless oil that crystallized slowly (diastereomer mixture 2.5/1). Recrystallization in EtOH (50mL) gave 49.4g (66%) white crystals of lc(S-Bu)-SbF6 as a 3/1 mixture of diastereomers.. Mp: 75-77.1°C. !H-NMR: Major isomer 7.37 (d, 2H, J=8.8Hz, Ar-H); 6.93 (d, 2H, J=8.8Hz, Ar-fl); 5.00 (dd, IH, J=11.0 and 6.2Hz, S-CH); 3.86- 3.69 (m, IH, S-CH2); 3.80 (s, 3H, OCH3); 3.59-3.49 (m, IH, S-CH2); 3.43-3.34 (m, 2H, S- CH2); 2.84-2.26 (m, 4H, CH2); 1.85-1.69 (m, 2H, CH2); 1.55-1.35 (m, 2H, CH2); 0.90 (t, 3H, J=7.2Hz, CH3); Minor isomer (distinguishable peaks in mixture with major isomer) 7.43 (d, 2H, Ar-H); 6.96 (d, 2H, Ar-H); 5.33 (dd, IH, J---11.7 and 6.0Hz; S-CH); 3.82 (s, 3H, OCH3); 0.75 (t, 3H, J=7.3Hz, CH3). 13 C-NMR: Major isomer 160.72; 129.35 (2C); 124.29; 115.06 (2C); 69.47; 55.38; 43.51; 43.31; 38.46; 28.73; 27.19; 21.38; 13.11; Minor isomer 161.37; 130.69 (2C); 118.95; 115.12 (2C); 65.47; 55.44; 44.65; 31.53; 28.09; 26.64; 21.41; 13.05. IR: 1612; 1517; 1469; 1258; 1233; 1185; 1029; 834; 655 cm" 1 - Anal. Calcd for Cl5H23θSSbF6: C, 36.98; H, 4.76; S, 6.58. Found: C, 37.0; H, 4.8; S, 6.6. Example 7: S-Butyl-2-(4-methoxyphenyl)-tetrahydrotiophenium hexafluoroantimonate [lc(S-Bu)-SbF6l The cyclic ether 7c was reacted with BuSH (1 eq) and HPSb6-6H2θ (1.5 eq) at 50°C fo 20h according to procedure B. Extractive workup with CH2CI2 according to procedure A afforded 95% of lc(S-Bu)-SbF6 as a 5.3/1 mixture of diastereomers. Example 8: S-DodecyI-2-(4-methoxyphenyI)-tetrahydro-tiophenium hexafluorophosphate [lc(S-dodecyI)-PF6] Aqueous HPFβ (60%, 7.3g, 30mmol) was added slowly to a solution of diol 6c (2.94g, 15mmol) and 1-dodecylmercaptan [1-dodecanthiol] (4.55g, 22.5mmol) in CH2CI2 (20mL). The reaction mixture was stirred for 24 h. Workup according to the general procedure A gave 3.79g (50%) of lc(S-dodecyl)-PF6 as a 2/1 mixture of diastereomers. ΪH-NMR: 7.53-7.45 (dd, 2H, Ar-H.); 6.95 (t, 2H, Ar-H.); 5.45 (dd, IH, CH-S, minor isomer); 5.20 (dd, IH, CH-S, major isomer); 4.08-3.44 (m, 4H, CH2-S); 3.83 (s, 3H, OCH3, minor isomer); 3.81 (s, 3H, OCH3, major isomer); 3.05-2.55 (m, 4H, CH-CH2-CH2- S); 1.87-1.7 (m, CH2); 1.5-0.9 (m, 20H, CH2); 0.87 (t, 3H, CH3-CH2) Example 9: S-Butyl-2-(4-methoxyphenyl)-tetrahydrotiophenium tetrafluoroborate [lc(S-Bu)-BF4] Aqueous HBF4 (50%, 8.23g, 45mmol) was added to a mixture of diol 6c (5.89g, 30mmol) and BuSH (2.71g, 30mmol). The reaction mixture was stirred for 3 h at RT and for 20 h at 50°C. CH2CI2 (10mL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (10mL). The combined organic layers wer washed with aqueous NaHCθ3 (sat., lOmL), H2O (5mL) and dried (MgS04). Evaporation gave 8.9 lg (88%) of lc(S-Bu)-BF4 as a 2.2/1 mixture of diastereomers. ^-NMR: Major isomer 7.43 (d, 2H, Ar-HJ; 6.91 (d, 2H, Ar-HJ; 5.22 (dd, IH, CH-S); 4.05- 3.40 (m, 7H, including CH_2-S(ring), 2H, 3.80 (s, 3H, CH3O), and 3.50 (t, 2H, CH2S)); 3.06-2.20 (m, 4H, C__2 (ring)); 1.78 (m, 2H, CH2CH2CH3 ); 1.44 (m, 2H, CH2CH3); 0.89 (t, 3H, CH2CH3); Minor isomer (distinguishable peaks in mixture with major isomer) 7.48 (d, Ar-H); 6.95 (d, Ar-H); 5.47 (dd, CH2-S); 3.82 (s, CH3O); 0.75 (t, CH2CH3). 1 3 C- NMR: Major isomer 160.47; 129.50 (2C); 124.97; 114.85 (2C); 68.54; 55.32; 43.57; 42.99; 38.54; 28.59; 27.18; 21.35; 13.18; Minor isomer (distinguishable peaks in mixture with major isomer) 161.13; 130.76 (2C); 119.62; 114.90 (2C); 65.36; 55.39; 44.53; 37.90; 31.48; 27.92; 26.69; 21.35; 13.11. Example 10: S-Butyl-2-(4-methoxyphenyl)-tetrahydrotiophenium perchlorate [lc(S-Bu)-Clθ4] Aqueous HCIO4 (70%, 2.153g, 15mmol) was added to a mixture of cyclic ether 7 c (1.782g, IOmmol) and BuSH (0.902g, lOmmol). The temperature was raised to 50°C and the reaction mixture was stirred for 24 h. H2O (5mL) and CH2CI2 (lOmL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (2x5mL). The combined organic layers were washed with aqueous NaHC03 (sat., 5mL), H2O (5mL) and dried (MgSθ4). Evaporation gave 3.34g (95%) oil of lc(S-Bu)- CIO4 as a 2/1 mixture of diastereomers. iH-NMR: Major isomer 7.42 (d, 2H, Ar-H); 6.93 (d, 2H, Ar-H); 5.27 (dd, IH, CHS); 4.10-3.50 (m, 7H, including CH2S (ring), 2H, 3.81 (s, 3H, CH3θ), and 3.57 (t, 2H, CH2S)); 3.10-2.30 (m, 4H, CH2(ring)); 2.80 (m, 2H, CH2CH2CH3); 1.47 <m, 2H, CH2CH3); 0.91 (t, 3H, CH2CH3); Minor isomer (distinguishable peaks in mixture with major isomer) 7.48 (d, Ar-H); 6.97 (d, Ar-H); 5.51 (dd, CHS); 3.83 (s, CH3O); 1.25 (m, CH2CH3); 0.76 (t, CH2CH3). 13 C-NMR: Major isomer 160.41; 129.41 (2C); 124.73; 114.80 (2C); 68.52; 55.26; 43.71; 43.07; 38.53; 28.66; 27.13; 21.31; 13.06; Minor isomer (distinguishable peaks in mixture with major isomer) 161.05; 130.67 (2C); 119.44; 114.79 (2C); 65.44; 55.31; 44.60; 38.00; 31.55; 27.98; 26.61; 21.31; 13.15. Example 11: S-Butyl-2-(4-methoxyphenyl)-tetrahydrotiophenium trϊflate [lc(S-Bu)-CFaS 03] CF3SO3H (98%, 2.25g, 15mmol) was added to a mixture of cyclic ether 7c (1.782g, lOmmol) and BuSH (0.902g, lOmmol). The reaction temperature was raised to 50°C and the mixture was stirred for 24 h. H2O (5mL) and CH2CI2 (lOmL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (2x5mL). The combined organic layers were washed with aqueous NaHCθ3 (sat., 5mL), H2O (5mL) and dried (MgS04). Evaporation gave 3.80g (95%) oil of lc(S-Bu)-CF3S03 as a 2/1 mixture of diastereomers. *H-NMR: Major isomer 7.42 (d, 2H, Ar-H); 6.92 (d, 2H, Ar-H); 5.30 (dd, IH, CHS); 4.05-3.50 (m, 7H, including CH2S(ring), 2H, 3.81 (s, 3H, CH3), and 3.57 (t, 2H, CH2S)); 3.10-2.20 (m, 4H, CH2(πng)); 1.76 (m, 2H, CH2CH2CH3); 1.44 (m, 2H, CH2CH3); 0.90 (t, 3H, CH2CH3); Minor isomer (distinguishable peaks in mixture with major isomer) 7.48 (d, Ar-H); 6.96 (d, Ar-H.); 5.53 (dd, CH2S); 3.83 (s, CH3O); 0.76 (t, 3H, CH2CH3). 13 C-NMR: Major isomer 160.36; 129.27 (2C); 124.63; 123.71 (triflate); 114.72 (2C); 68.22; 55.16; 43.57; 42.86; 38.38; 28.40; 27.05; 21.17; 12.92; Minor isomer (distinguishable peaks in mixture with major isomer) 160.98; 130.56 (2C); 119.41; 117.34 (triflate); 114.72 (2C); 65.33; 52.21; 44.45; 37.81; 31.44; 27.83; 26.49; 21.17; 13.00. Example 12: S-Butyl-2-(4-isopropylphenyI)-tetrahydrotiophenium hexafluorophosphate [ld(S-Bu)-PF6l Aqueous HPFζ (60%, 2.92g, 12mmol) was added slowly to a solution of diol 6d (1.25g, 6mmol) and n-butylmercaptan (0.81g, 9mmol) in CH2CI2 (8mL). The reaction mixture was stirred for 24 h. Workup according to the general procedure A gave 1.42g (58%) brown oil of ld(S-Bu)-PF6 as a 1.5/1 mixture of diastereomers. lOOmg of ld(S-Bu)-PF6 was washed with a H2θ2-solution and to give a colorless oil. ^H- NMR: 7.50-7.13 (m, 4H, Ar-H); 5.40 (dd, IH, CH-S, minor isomer); 5.16 (dd, IH, CH-S, major isomer); 4.13-3.45 (m, CH2-S); 3.06-2.20 (m, CH-CH2-CH2 and CH(CH3)2); 1.85-1.1 (m, CH2-CH2-CH3); 1.24 (d, 6H, (CH3)2CH); 0.91 (t, 3H, CH3-CH2, major isomer); 0.71 (t, 3H, CH3-CH2, minor isomer). Example 13: S-ButyI-2-(4-tertbutyIphenyl)-tetrahydro-tiophenium hexafluorophosphate [le(S-Bu)-PF6l Aqueous HPFβ (60%, 2.92g, 12mmol) was added slowly to a solution of diol 6e (1.33g, 6mmol) and BuSH (0.81g, 9mmol) in CH2CI2 (8mL) kept at 0°C. The reaction mixture was stirred for 24 h. Workup according to the general procedure A gave 1.28g (51%) yellow oil of le(S-Bu)-PF<j as a 2/1 mixture of diastereomers. H-NMR: 7.53-7.17 (m, 4H, Ar-H); 5.47 (dd, IH, CH-S, minor isomer); 5.20 (dd, IH, CH-S, major isomer); 4.16-3.46 (m, CH2-S); 3.12-2.24 (m, CH-CH2-CH2); 2.02-0.8 (m, CH2-CH2-CH3); 1.31 (s+s, 9H, (CH3)3C); 0.91 (t, 3H, CH3-CH2, major isomer); 0.70 (t, 3H, CH3-CH2, minor isomer). Example 14: S-Butyl-2-(2,4-dimethylphenyl)-tetrahydrotiophenium hexaf uorophosphate [lf(S-Bu)-PF6l The cyclic ether 7f (476g, 2.7mol) was reacted with BuSH (341 g, 3.78mol) and aqueous HPFζ (60%, 985g, 4.05mol) in CH2CI2 (600mL) and the reaction mixture was stirred for 17h at RT. Workup according to the general procedure A gave 1.065kg (100%) of crude lf(S-Bu)-PF6- Recrystallization in EtOH (920mL) gave 745 (70%) white crystals of lf(S-Bu)-PF6 as a 1/1 mixture of diastereomers. ^H-NMR (aceton- d6): 7.63 (d, IH, Ar-H. major isomer); 7.49 (d, IH, Ar-H, minor isomer); 7.27-7.13 (m, 2H, Ar-H); 5.65 (dd, IH, J=12.5 and 5.0Hz, CH-S, major isomer); 5.54 (dd, IH, J=10.2 and 6.8Hz, CH-S, minor isomer); 4.24-3.62 (m, CH2-S); 3.20-2.25 (m, CH-CH2-CH2); 2.47 (s, 3H, Ar-CH3, major isomer); 2.45 (s, 3H, Ar-CH3, minor isomer); 2.35 (s, 3H, Ar-CH_3, major isomer); 2.31 (s, 3H, Ar-CH3. minor isomer); 1.90 (m, CH2); 1.6-0.8 (m, CH2-CH2- CH3); 0.95 (t, 3H, CH2-CH3, minor isomer); 0.74 (t, 3H, CH2-CH3, major isomer). 13 C- NMR: 131.98; 128.00; 127.89; 127.52; 64.95; 62.46; 44.61; 43.55; 42.81; 38.50; 38.31; 31.40; 28.56; 27.34;.26.56; 21.25; 20.93; 19.34; 13.03. Anal. Calcd for C16H25SPF6: C, 48.73; H, 6.39; S, 8.13. Found: C, 48.8; H, 6.5; S, 7.8 Example 15: S-tert-Bu tyl-2-(2,4-dimethylp henyI)- tetrahydro- tiophenium hexafuorophosphate [lf(S-tert-B u)-PF<i] Aqueous HPFβ (60%, 10.95g, 45mmol) was added to a mixture of diol 6f (5.82g, 30mmol) and t-BuSH (2.71g, 30mmol). After 2 hours' stirring, crystallization started. H2O (15mL) was added, the crystals were filtrated and washed with H2O (2xl0mL), aqueous NaHC03 (sat., 2xl0mL) and H2O (lOmL). The crystals were dried to give 10.59g (90%) white crystals of lf(S-tBu)-PF6 as a >30/l mixture of two diastereomers. Ϊ H-NMR: 7.36 (d, IH, Ar-H); 7.06 (d, IH, Ar-H), 7.02 (s, IH, Ar-H); 5.06 (dd, IH, CHS); 3.86-3.52 (m, 2H, CH2S); 2.82-2.05 (m, 10H, including CH2(πng), 4H, 2.42 (s, 3H, CH3Ar), and 2.28 (s, 3H, CH3Ar)); 1.54 (s, 9H, t-Bu). 13 C-NMR: 137.79; 136.24; 135.65; 131.11; 126.98; 126.68; 48.49; 38.68; 33.19; 30.88; 20.97; 19.69. Example 16: S-ι-so-Butyl-2- (2,4-dimethyl phenyI)-tetrahydro- tiophenium hexafuorophosphate [lf(S-i-?ø-Bu)-PF6] Aqueous HPF6 (60%, 10.95g, 45mmol) was added to a mixture of diol 6f (5.82g, 30mmol) and i-BuSH (2.71g, 30mmol). The reaction mixture was stirred for 24 h. H2O (lOmL) was added and crystallization started. The crystals were filtreted and washed with H2O (2x5mL), aqueous NaHCθ3 (2x5mL) and H2O (5mL). Drying gave 11.14g (94%) of lf(S-iso-Bu)-PF6 as a 1.2/1 mixture of diastereomers. iH-NMR: Major isomer 7.39 (d, IH, Ar-H); 7.10 (s, IH, Ar-H); 7.07 (d, IH, Ar-H); 5.34 (dd, IH, CHS); 4.12-3.35 (m, 4H, including CH2(ring), 2H, and 3.38 (d, 2H, CHCH2S)); 2.96-2.54 (m, 4H, CH2(ring)); 2.43 (s, 3H, CH3Ar); 2.34 (s, 3H, CH3Ar); 1.33 (m, IH, CH3CH); 0.92 (d, 3H, CH3CH); 0.78 (d, 3H, CH3CH); Minor isomer (distinguishable peaks in mixture with major isomer) 7.25 (d, Ar-H); 5.22 (dd, CHS); 2.39 (s, CH3Ar); 2.30 (s, CH3Ar); 2.06 (m, CH3CH); 1.08 (d, CH3CH); 1.01 (d, CH3CH). 13 C-NMR: Major isomer 141.00;137.96; 132.27; 128.18; 127.73; 123.12; 63.04; 46.98; 45.31; 31.63; 27.41; 26.42; 25.52; 21.11; 21.04 (2C); Minor isomer (distinguishable peaks in mixture with major isomer) 139.56; 135.93; 132.18; 128.45; 128.09; 127.47; 66.17; 51.76; 44.02; 38.57; 28.74; (25.52); 21.39; 20.91; 19.31 (2C). Example 17: S-ι ' sσ-Propyl-2-(2,4-dimethylphenyl)- tetrahydrotiophenium hexafuorophosphate [lf(S-i..o-Pr)-PF6] Aqueous HPFβ (60%, 10.95g, 45mmol) was added to a mixture of diol 6f (5.82g, 30mmol) and i-PrSH (2.28g, 30mmol). The reaction mixture was stirred for 24 h. H2O (lOmL) and CH2CI2 (50mL) was added and the layers were separated. The aqueous- layer was extracted with CH2CI2 (2xl0mL). The combined organic layers were washed with aqueous NaHC03 (sat., 2xl0mL) and dried (MgSθ4). Evaporation gave 9.92g (87%) of lf(S-iso-Pr)-PF6 as a 6/1 mixture of diastereomers. ! H-NMR: Major isomer 7.26 (d, IH, Ar-H); 7.07 (d, IH, Ar-H); 7.04 (s, IH, Ar-H); 5.25 (dd, IH, CHS(ring)); 4.06-3.57 (m, 3H, CH2S and CH3CH); 2.93-2.14 (m, 10H, including CH2(ring), 4H, 2.42 (s, 3H, CHjAr), and 2.30 (s, 3H, CH3Ar)); Minor isomer (distinguishable peaks in mixture with major isomer) 7.50 (d, Ar-H); 5.36 (dd, CHS(ring)); 3.35 (m, CH3CH); 2.45 (s, CH3Ar); 0.56 (d, CH3CH). 13 C-NMR: Major isomer 139.45; 135.54; 132.21; 128.58; 128.14; 127.97; 64.37; 48.76; 41.29; 38.89; 28.66; 20.85; 19.69; 19.20; 18.76; Minor isomer (distinguishable peaks in mixture with major isomer) 141.05; 138.24; 123.55; 64.09; 44.11; 41.65; 32.21; 27.00; 19.32; 19.02; 18.92. Example 18: S-DodecyI-2-(2,4-dimethylphenyl)-tetrahydro-tiophenium hexafuorophosphate [lf(S-dodecyl)-PF6l Aqueous HPF6 (60%, 7.30g, 30mmol) was added to a mixture of diol 6f (3.89g, 20mmol) and n-dodecylmercaptan (4.05g, 20mmol). The reaction mixture was stirred for 24 h. H2O (lOmL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (2xl0mL), the combined organic layers were washed with H2O (5mL) and aqueous NaHC03 (sat., 5mL) and dried (MgS04). Evaporation and extractions with petroleumether gave 7.38g (73%) colorless oil of lf(S-dodecyl)- PF(J as a 1.6/1 mixture of diastereomers. J H-NMR: Major isomer 7.39 (d, IH, Ar-H); 7.10 (s, IH, Ar-H); 7.07 (d, IH, Ar-H); 5.34 (dd, IH, CΗS(ring)); 4.09-3.40 (m, 4H, CH2S); 2.90-2.20 (m, 10H, inclusing CH2(ring), 4H, 2.44 (s, 3H, CHjAr), and 2.34 (s, 3H, CHjAr)); 1.45-1.00 (m, 18H, CH2); 0.87 (d, 3H, CH3CH2); Minor isomer (distinguishable peaks in mixture with major isomer) 7.24 (d, Ar-H); 5.20 (dd, CHS(ring)); 2.41 (s, CH3Ar); 2.31 (s, CH3Ar). 13 C-NMR: 140.72; 139.38; 137.90; 135.72; 132.01; 128.29; 127.95; 127.82; 127.60; 127.46; 122.99; 65.49; 62.62; 44.60; 43.39; 38.92; 38.34; 31.65; 31.29; 29.33; 29.17; 29.08; 28.85; 28.79; 28.62; 28.48; 27.83; 27.21; 25.29; 24.61; 22.43; 20.85; 20.74; 19.20; 13.85. Example 19: S-PhenyI-2-(2,4-dimethylphenyI)-tetrahydro-tiophenium hexafuorophosphate [lf(S-Ph)-PFβ] Aqueous HPF6 (60%, 10.95g, 45mmoI) was added to a mixture of diol 6f (5.82g, 30mmol) and thiophenol (3.3 lg, 30mmol). The reaction mixture was stirred for 100 h. H2O (15mL) was added and the layer was decanted and extracted with CH2CI2 (2x3mL). The combined organic layers were dissolved in CH2CI2 (80mL), washed with aqueous NaHC03 (sat., 2xl0mL) and dried (MgSθ4). Evaporation gave 10.88g (88%) of lf(S-Ph)-PF6 as a 2/1 mixture of diastereomers. X H-NMR (CDCI3+DMSO- D6): Major isomer 7.90-6.43 (m, 8H, Ar-H); 5.69 (dd, IH, ArCHS); 4.47-3.93 (m, 2H, CH2S); 3.11-2.46 (m, 7H, including CH2(ring), 4H, and 2.52 (s, 3H, CH3Ar)); 2.20 (s, 3H, CH_3Ar); Minor isomer (distinguishable peaks in mixture with major isomer) 5.56 (dd, ArCHS); 2.31 (s, CH3Ar); 1.98 (s, CH3Ar). Example 20: S-ButyI-2-(2,4-dimethyIphenyl)-tetrahydro-tiophenium hexafuoroantimonate [lf(S-Bu)-SbF6] HSbF6-H2θ (535g, 1.545moI) was added to a mixture of diol 6f (200g, 1.03mol) and BuSH (lllmL, 1.03mol) kept at 20-25°C. The reaction temperature was raised to 50°C and the mixture was stirred for 24 h. H2O (150mL) was added and the aqueous-layer decanted. CH2CI2 (500mL) was added to the organic layer, washed with H2O (400mL), aqueous NaHC03 (200mL) and dried (MgSθ4). Evaporation gave 346,8g (69%) of lf(S- Bu)-SbF6 as a 1/1 mixture of diastereomers. Recrystallisation in EtOH (IL) gave 256.5g (51%) white crystals of lf(S-Bu)-SbFg as a 4/1 mixture of diastereomers. Mp: 99!-101°C. ^-NMR: Major isomer 7.39 (d, IH, J=8.5Hz, Ar-H); 7.12 (s. 2H, Ar-H); 5.31 (dd, IH, J=12.2 and 4.8Hz, SCH); 4.05-3.94 (m, IH, SCH2CH2CH2CH3); 3.50-3.32 (m, IH, SCH2); 2.89-2.59 (m, 4H, CH2); 2.43 (s, 3H, Ar-CH3); 2.34 (s, 3H, Ar-CH3); 1-50-1.10 (m, 4H, CH2); 1.01-0.82 (m, 4H, CH2); 0.73 (t, 3H, J=7Hz, CH3); Minor isomer (distinguishable peaks in mixture with major isomer) 7.24 (d, IH, J=7.3Hz, Ar-H); 7.15 (s, 2H, Ar-H); 5.18 (dd, IH, J=10.3 and 6.5Hz, SCH); 3.90-3.72 (m, IH, SCH2); 2.40 (s, 3H, Ar-CH3); 2.31 (s, 3H, Ar-CH3). 13 C-NMR: Major isomer 141.11; 137.96; 132.27; 127.98; 127.84; 122.86; 63.09; 44.73; 38.92; 31.49; 27.59; 26.61; 21.41; 21.34; 19.33; 13.16; Minor isomer (distinguishable peaks in mixture with major isomer) 139.75; 135.89; 128.24; 128.18; 127.54; 65.89; 43.53; 43.28; 38.36; 28.79; 27.37; 21.41; 20.42; 13.16. IR: 1615; 1466; 1451; 820; 658 cm" 1 . Anal. Calcd for Ci6H25SSbF6: C, 39.61; H, 5.19; S, 6.61. Found: C, 39.3; H, 5.2; S, 6.6. Example 21 : S-Bu tyl-2-(2-methyl ,4- methoxyphenyl) - tetrahydrotiop heniu m hexafuo rop hosphate [ l g(S -B u )- PF6 ] Aqueous HPF6 (60%, 5.8mL, 39mmol) was added to a mixture of diol 6g (5.54g, 26mmol) and BuSH (3.9mL, 36.4mmol) kept at 0°C and under N2-atmosphere. The temperature was raised to RT and the mixture was stirred for 17 h. H2O (lOmL) and CH2CI2 (lOmL) was added, the layers were separated and the aqueous-layer was extracted with CH2CI2 (2x20mL). The combined organic layers were washed with H2O (lOmL), aqueous NaHC03 (sat., lOmL) and dried (MgSθ4). Evaporation gave 9.309g (76%) of l fS-Bu PF^ as a 1/1 mixture of diastereomers. Recrystallization in EtOH (45mL) gave 4.43g (42%) of lg(S-Bu)-PF6 as white crystals. ! H-NMR: Major isomer 7.47 (s, IH, Ar); 7.42 (s, IH, Ar); 6.85-6.76 (m, IH, Ar); 5.39-5.29 (m, IH, Ar-CH), 4.08-3.91 (m, 2H, CH2); 3.82 (s, 3H, OCH3); 3.5-3.4 (m, 2H, CH2); 2.90-2.62 (m, 2H, CH2); 2.44 (s, 3H, CH3); 1.80-1.20 (m, 6H, CH2); 0.74 (t, 3H, J=7Hz, GH3); Minor isomer (distinguishable peaks in mixture with major isomer) 7.30 (s, IH, Ar); 7.27 (s, I H, Ar); 5.25-5.15 (m, IH, Ar-CH); 3.80 (s, 3H, OCH3); 2.42 (s, 3H, CH3); 0.91 (t, 3H, J=7Hz, CH3)r Exa mp le 22 : S-B utyl-2 - (2,4-d i m eth oxyp hen I )-tetra hydrotioph eni u m hexafuorophosphate [ l h(S-Bu)-PF6 l Aqueous HPF6 (60%, 3.9mL, 26.52mmol) was added to a mixture of diol 6h (4g, 17.68mmoI) and BuSH (2.7mL, 24.75mmol) kept at 0°C and under N2-atmosphere. The mixture turn red under the addition of HPF6. The temperature was raised to RT and the reaction mixture was stirred for 16 h. H2O (30mL) and CH2CI2 (50mL) was added, the layers were separeted and the aqueous-layer was extracted with CH2CI2 (2x25mL). The combined organic layers were was washed with H2O (30mL), aqueous NaHCθ3 (sat., 2x25mL) and dried (MgSθ4). Evaporation gave 4.96g (66%) yellow oil of lh(S-Bu)-PF<; as a 3.7/1 mixture of diastereomers. * H-NMR: Major isomer 7.4-7.15 (Ar-H); 6.55-6.45 (Ar-H); 5.02-4.92 (dd, IH, CH-S); 3.90 (s, 3H, OCH3); 3 -79 (s, 3H, OCH3); 3.65-3.55 (m, 2H, CΗ.2); - 3 0 (t, 2H, S-CH2CH2CH2CH3); 2.80-2.40 (m, 4H, CH2); 1.85-1.65 (m, 4H, CH?); 0.94 (t, 3H, J=7.3Hz, CH3); Minor isomer (distinguishable peaks in mixture with major isomer) 5.29-5.18 (dd, IH, CH-S); 4.05-3.95 (t, 2H, S- CH2CH2CH2CH3); 0.66 (t, 3H, J=7.3Hz, CH3). Example 23 : S -But l-2-(2,4,6-tri methyl phenyl )-tetra hydro-tiopheniu m hexafuorophosphate [ li (S-Bu)-PF<j ] Aqueous HPF6 (60%, 2.92g, 12mmol) was added slowly to a solution of diol 6i (1.25g, 6mmol) and BuSH (0.81g, 9mmol) in CH2CI2 (8mL) kept at 0°C. The reaction mixture was stirred for 24 h. Workup according to general procedure A gave 1.46g (59%) uellow oil of li(S-Bu)-PF6 as a >10/1 mixture of diastereomers. Ϊ H-NMR: 6.91 (s, 2H, Ar-H); 5.44 (dd, IH, CH-S); 3.98-3.35 (m, 4H, CH2-S); 2.9-2.2 (m, 4H, CH-CH2-CH2); 2.43 (s, 6H, 0-CH3); 2.28 (s, 3H, p-CH3); 1.73 (m, 2H, CH2-CH2-CH3); 1.46 (sext, 2H, CH2-CH3); 0.91 (t, 3H, CH2CH3). Example 24: S-Butyl-2-(2,6-dimethyI,4-methoxyphenyl)- tetrahydrotiophenium hexafuorophosphate [lj(S-Bu)-PF6] Aqueous HPFζ (60%, 4.9mL, 33.44mmoI) was added to a mixture of diol 6j (5g, 22.29mmol) and BuSH (3.4mL, 31.21mmol) in CH2CI2 (5mL) kept at 0°C and under N2- atmosphere. The reaction mixture was stirred for lh 45min at 0°C and for 3h at RT, H2O (5mL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (2x5mL). The combined organic layers were washed with H2O (5mL), aqueous NaHC03 (sat., 2x5mL) and dried (MgS04). Evaporation gave 9.24g (98%) of lj(S-Bu)-PF6- Recrystallization in EtOH gave 4.11g (43%) white crystals of lj(S-Bu)-PF6 as a >10/1 mixture of diastereomers. iH-NMR: 6.69 (s, IH, Ar); 6.64 (s, IH, Ar); 5.09-5.01 (m, IH, Ar-CH); 3.89 (s, 3H, OCH3); 3.65-3.61 (m, 2H, CH2); 3.28- 3.19 (m, 2H, CH2); 2.73-2.65 (m, 2H, CH2); 2.39 (s, 3H, Ar-CH3); 2.32 (s, 3H, Ar-CH_3); 1.80-1.65 (m, 2H, CH2); 1.55-1.40 (m, 2H, CH2): 0.92 (t, 3H, J=7.2Hz, CH3). 1 C-NMR: 140.9; 138.0; 132.2; 128.0; 127.8; 123.1; 62.8; 44.6; 38.7; 31.4; 27.4; 26.5; 21.3; 21.0; 19.3; 13.0. Example 25: S-Butyl-2-(4-methoxyphenyl)-pyranium hexa¬ fluorophosphate [lk(S-Bu)-PF6l Aqueous HPF6(60%, 2.92g, 12mmol) was added slowly to a solution of diol 6k (0.63g, 3mmol) and BuSH (0.14g, 4.5mmol) in CH2CI2 (3mL) kept at 0°C. The reaction mixture was stirred for 120 h. Workup according to the general procedure A gave 0.38g (32%) brown oil of Ik (S-Bu)-PF6 as a >10/1 mixture of diastereomers. *H - NMR:7.43 (d, 2H, Ar-H); 6.95 (d, 2H, Ar-H); 5.45 (brd, IH, CH-S); 4.00-2.96 (m, 4H, CH2- S); 3.83 (s, 3H, CH3-O); 2.6-0.9 (m, 10H, CH2); 0.80 (t, 3H, CH3-CH2). Example 26: S-Butyl-[3,4]-benzo-2,5-dihydrothiophenium hexafluorophosphate (3A) Aqueous HPFβ (60%, 3.8mL, 25.97mmol) was added to a mixture of diol 12A (Ig, 7.42mmoI) and BuSH (1.6mL, 14.48mmol) kept at 0°C and under N2-atmosphere. The temperature was raised to RT and the reaction mixture was stirred for 66 h. H2O (lOmL) and CH2CI2 (50mL) was added and the layers were separated. The aqueous- layer was extracted with CH2CI2 (20mL). The combined organic layers, were washed with aqueous NaHC03 (sat., lOmL) and dried (MgS04). Evaporation gave 1.41g (56%) of 3A. iH-NMR 7.5-7.15 ( , 4H, Ar); 5.03 (d, 2H, J=17Hz, CH2S); 4.60 (d, 2H,J=17Hz,CH2S); 3.16 (t, 2H, J=7HZ, S-CH-.); 1.8-1.6 (m, 2H, SCH2CH2); 1-6-1.25 (m, 2H, SCH2CH2CH2); 0.92 (t, 3H, J=7Hz, S(CH2)3CH3). 1 C-NMR 133.18; 129.0; 125.93; 46.34; 39.94; 25.91; 21.44; 13.19 IR: 3632; 2962; 2876; 1826; 1585; 1490; 1459; 1409; 1286; 1246; 1212; 1055; 961; 916; 888; 753; 692; 521; 425. Example 27: S-ButyI-2-phenyI-[3,4]-benzo-2,5-dihydro-thiophenium hexafluorophosphate (3B) Aqueous HPF6 (60%, 2.4mL, 16.34mmol) was added to a mixture of diol 12B (lg, 4.67mmol) and BuSH (lmL, 9.3mmol) kept at 0°C and under N2 -atmosphere. After 30 minutes stirring, CH2CI2 (1.5mL) was added and the temperature was raised to RT. The reaction mixture was stirred for 7 h. H2O (lOmL) and CH2CI2 (50mL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (20mL) The combined organic layers were washed with aqueous NaHC03 (sat., 15mL) and dried (MgSθ4). Evaporation gave 1.385g (69%) of 3B (containig 8% of 3A) as a 2.2/1 mixture of diastereomers. ^H-NMR d=7.6-7.2 (m, 18H, Ar-H. major+minor); 7.05 (s, I Ar-CH-S, minor); 6.49 (s, IH, Ar-CH-S, major); 5.1 (d, IH, J=17Hz, CH2-S, minor); 5.0 (d 2H, J=17Hz, CH2-S, major); 4.83 (d, 2H, J=17Hz, CH2-S, major); 4.74 (d, 2H, J=17Hz, CH2-S minor); 3.65-3.5 (m, IH, S-CH2. major); 3.4-3.3 (m, 2H, S-CH2, major); 2.95-2.8 (m, IH, S-CH2. minor); 2.65-2.5 (m, IH, S-CH2, minor); 1.9-1.7 (m, 4H, SCH2-CH2, major+minor); 1.5-1.3 (m, 4H, SCH2CH2-CH2, major+minor); 0.91 (t, 3H, J=7Hz, S(CH2)3CH3, major); 0.68 (t, 3H, J=7Hz, S(CH2)3CH3, minor). IR: 2963; 2875; 2360; 1488; 1456; 1414; 1287; 1055; 753; 706; 601; 522; 430. Example 28: S-ButyI-2-/so-prop I-[3,4]-benzo-2,5-dihydrothiophenium hexafluorophosphate (3C) Aqueous HPF6 (60%, 1.15mL, 7.8mmol) was added to a mixture of diol 12C (0.4g, 2.23mmol) and BuSH (0.5mL, 4.46mmol) kept at 0°C and under N2-atmosphere. The temperature was raised to RT and the reaction mixture was stirred for 6 h. H2O (6mL) and CH2CI2 (30mL) was added and the layers were separated. The aqueous- layer was extracted with CH2CI2 (10mL). The combined organic layers were washed with aqueous NaHCθ3 (sat., lOmL) and dried (MgS04). Evaporation gave 0.37g (38%) of 3C as a 3.3/1 mixture of diastereomers. ^H-NMR 7.53-7.4 (m, 8H, Ar, major+minor 5.46 (d, IH, J=7Hz, (CH3)2CHCH. minor), 4.93 (s, IH, (CH3)2CHCH, major); 4.90 (d, IH, J=17Hz, CH2-S, minor); 4.90 (d, IH, J=17Hz, CH2-S, major); 4.75 (d, IH, J=17Hz, CH2-S, major); 4.58 (d, IH, J=17Hz, CH2-S, minor); 3.45-3.1, 3-2.85, 2.7-2.45 (m, 6H, SCH2. major+minor samt (CH3)2CH. major+minor); 1.88-1.73 (m, 4H, SCH2CH2, major+minor); 1.61-1.46 (m, 4H, SCH2CH2CH2, major+minor); 1.35 (d, 3H,J=7Hz, CH3, inor); 1.33 (d, 3H,J=7Hz, CH3- minor); 1.26 (d, 3H,J=7Hz, CH3, major); 0.98 (d, 3H,J=7Hz, CH3, major); 0.97 (t, 3H, J=7Hz, S(CH2)3CH3, major); 0.93 (t, 3H, J=7Hz, S(CH2)3CH3, minor). 1 C-NMR 130; 129.5; 126.1; 73.2; 46.2; 41.3; 33.8; 26.3; 21.5; 20.7; 18.1; 13.3. IR: 3636; 2965; 2877; 1631; 1468; 1417; 1394; 1374; 1286; 1056; 759; 522; 440. Example 29: S-Butyl-2,2-dimethyl-[3,4]-benzo-2,5-dihydrothiophenium hexafluorophosphate (3D) Aqueous HPF6 (60%, 3mL, 21mmol) was added to a mixture of diol 12D (lg, 6mmol) and BuSH (1.3mL, 12mmoI) kept at 0°C and under N2-atmosphere. The reaction mixture was stirred for 1 hour at 0°C and for 49 h at RT. H2O (lOmL) and CH2CI2 (lOmL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (3xl0mL). The combined organic layers were washed with aqueous NaHCOs (sat., lOmL) and dried (MgSθ4). Evaporation and extractions with petroleumether gave 1.1 g (43%) of 3D as yellow crystals. iH-NMR 7.55-7.4 and 7.3- 7.05 (m, 4H, Ar-H); 5.04 (d, IH, J=16Hz, CH2-S); 4.7 (d, IH, J=17Hz, CH2-S); 3.42-3.25 (m, IH, S-CH2); 3.08-2.9 (m, IH, S-CH2); 2.03 (s, 3H, CH3); 1-88 (m, 3H, CH3); 1-9-1.7 (m, 2H, SCH2-CH2); 1.6-1.4 (m, 2H, SCH2CH2CH2); 0.94 (t, 3H, J=7Hz, S(CH2)3CH3). 1 C-NMR 142.4; 132.2; 129,9; 126.6; 123.1; 71.6; 42.3; 36.9; 29.3; 26.6; 22.4; 21.8; 13.3. IR: 2971; 2878; 1485; 1468; 1456; 1410; 1376; 1103; 838; 766; 735; 558; 437. Example 30: S-ButyI-2-metyl-2-phenyI-[3,4]-benzo-2,5- dihydrothiophenium hexafluorophosphate (3E) Aqueous HPF6 (60%, 3mL, 21mmoI) was added to a mixture of diol 12E (600mg, 2.63mmoI) and BuSH (1.3mL, 12mmol) kept at 0°C and under N2-atmosphere. The temperature was raised to RT and the reaction mixture was stirred for 4.5 h. H2O (lOmL) and CH2CI2 (10mL) was added and the layers were separated. The aqueous- layer was extracted with CH2CI2 (3xl0mL). The combined organic layers were washed with aqueous NaHCθ3 (sat., lOmL) and dried (MgSθ4). Evaporation gave L135g (73%) of 3E. iH-NMR 7.55-7.4 and 7.3-7.05 (m, 4H, Ar-H); 5.04 8d, IH, J=16Hz, CH2-S); 4.7 (d, IH, J=I7Hz, CH2-S); 3.42-3.25 (m, IH, S-CH2); 3.08-2.9 (m, IH, S-CH2); 2.03 (s, 3H, CH3); 1.88 (s, 3H, CH3); 1.9-1.7 (m, 2H, S-CH2-CH2); 1-6-1.4 (m, 2H, S-CH2- CH2-CH2); .94 (t, 3H, J=7Hz, S-(CH2)3CH3). i3 C-NMR 139.7; 137.5; 134.5; 130.6; 130.1, 129.5; 127.64; 127.4; 125.6; 78.3; 41.4; 37.1; 26.5; 22.9; 21.9; 13.4. IR: 2946; 2878; 1493; 1456; 1407; 1392; 1289; 1215; 1191; 1061; 782; 762; 737; 703; 650; 613; 561; 522. Example 31 : S-B u tyl -2,2-d i phen yI - [ 3 ,4 ] -benzo -2 ,5 - d ih yd roth iopheni u m hexafluorophosphate (3F) Aqueous HPF6 (60%, 1.8mL, 12mmol) was added to a mixture of diol 12F (lg, 3.44mmol) and BuSH (0.74mL, 6.9mmol) kept at 0°C and under N2 -atmosphere. After lhours stirring at 0°C, CH2CI 2 (0.5mL) was added and the reaction mixture was stirred for 21 h at RT. H2O (6mL) and CH2CI2 (30mL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (lOmL). The combined organic layers were washed with aqueous NaHC03 (sat., 6mL) and dried (MgSθ4). Evaporation gave 1.208g (60%) of 3F. ! H-NMR 7.6-7.35 (m, 14H, Ar-H); 5.02 (s, 2H, CH2-S); 3.25-3.1 (m, IH, S-CH2); 2.7-2.5 (m, IH, S-CH2); 1.6-1.35 (m, 2H, SCH2CH2); 1.35- 1.1 (m, 2H, SCH2CH2CH2); 0.7 (t, 3H, J=7Hz, S(CH2)3CH3). 1 C-NMR 131.1; 130.5; 130.3; 129.6; 129.4; 127.4; 127.6; 127.2; 45.8; 40.1; 26.3; 21.67; 13.0. IR= 3436; 2964; 1495; 1451; 1410; 1285; 1241; 1056; 769; 757; 744; 698; 634; 623; 521; 437. Example 32 : S-Butyl-5 - methyl - [3,4 ) - benzo-2,7- d ihydroth iephi ni u m hexafluorophosphate (5A) The diol 12G (50mg, 0.281mmol) was added to a mixture of aqueous HPF6 (60%, 144μL , 0.98mmol), BuSH (60μL, 0.56mmol) and CH2CI2 (500μL) kept at 0°C. The reaction mixture was stirred for 6 h at RT. H2O and CH2CI2 was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 and the combined organic layers were washed with aqueous NaHC03 (sat.) and dried (MgSθ4). Evaporation and extractions with petroleumether gave 50mg (47%) of 5 A . ' H-NMR 7.6-7.3 (m, 4H Ar- H); 6.1 (t, IH, C=CH); 4.45 (d,lH, J=13Hz, ArCH2S); 4.16 (d, IH, J=13Hz, A1CH2S); 3.75-3.62 (m, IH, SCH2), 3.45-3.15 (m, 3H, SCH2 + C=CHCH2S); 1.88-1.72 (m, 2H, SCH2CH2); 1.6-1.4 (m, 2H, SCH2CH2CH2); 0.95 (t, 3H, J=7Hz, S(CH2)3CH3)- 13 C-NMR 148.5; 141.1; 131.5; 130.7; 129.1; 127.8; 125.6; 114.7; 39.2; 38.7; 35.2; 25.9; 23; 21.6; 13.1. IR: 3629; 2963; 2875; 1636; 1490; 1424; 1285; 1056; 769; 521. Example 33 : S- Butyl-5-phenyl - [3,4 ] -ben zo-2,7-di hydrothiephini u m hexafluorophosphate (5B ) Aqueous HPF6 (60%, 2.4mL, 16.34mmol) was added to a mixture of diol 121 (lg, 4.67mmol) and BuSH (lmL, 9.3mmol)kept at 0°C and under N2-atmosphere. After 30 minutes stirring at RT CH2CI2 (1.5mL) was added. The reaction mixture was stirred for 6 more h. H2O (lOmL) and CH2CI2 (50mL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (20mL). The combined organic layers were washed with aqueous NaHC03 (sat., 15mL) and dried (MgSθ4). Evaporation gave 1.385g (60%) of 5B. iH-NMR 7.65-7.15 (m, 9H, Ar-H); 6.52- (t, IH, J=7Hz, C=CH); 4.54 (d, IH, J=14Hz, ArCH2S); 4.21 (d, IH, J=14Hz, ArCH2S); 3.48-3.18 (m, 3H, SCH2 and C=CHCH2S); 1.92-1.73 (m, 2H, SCH2CH2); 1.63-1.41 (m, 2H, SCH2CH2CH2); 0.96 (t, 3H, J=7Hz, S(CH2)3CH3). 13 C-NMR 151.3; 139.6; 138.5; 131.7; 131; 129.9; 129.6; 128.7; 128.2; 127.4; 114.7; 39.6; 39.2; 21.8; 13.3. IR: 3414; 2961; 1617; 1447; 1059; 766; 700; 634; 522. Example 34: S-Butyl-isothiochromanium hexafluorophosphate [4a(S- Bu)-PF6] Aqueous HPFβ (60%, 7.30g, 30mmol) was added slowly to a mixture of isochromanone (13) (2.68g, 20mmol) and BuSH (1.80g, 20mmol). The reaction mixture was stirred for Iweek at RT and for 2days at 50°C. H2O (lOmL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (2x20mL). The combined organic layers were washed with aqueous NaHC03 (sat., 2xl0mL) and dried (MgS04). Evaporation gave 5.95g (85%) of 4a(S-Bu)-PF6- ! H-NMR: 7.53-7.10 (m, 4H, Ar-H); 4.44 (dd, 2H, ArCH2S); 4.08-2.80 (m, 6H, CH2); 1.73 (m, 2H, CH2CH2S); 1.46 (m, 2H, CH2CH3); 0.92 (t, 3H, CH3). 1 3 C-NMR (DMSO-D6): 135.64; 129.57; 129.34; 128.97; 127.62; 126.55; 39.57; 35.65; 35.31; 25.27; 25.10; 20.96; 13.14. Example 35: S-Benzyltetrahydrothiophenium hexafluorophosphate (2) Aqueous HPF6 (60%, 13.99g, 57.5mmol) was added to a mixture of THF (2.07g, 28.55mmoI) and benzylmercaptan (5g, 28mmol). The reaction mixture was stirred for 21 h. H O (13mL) and CH2CI2 (13mL) was added and the layers were separated. The aqueous-layer was extracted with CH2CI2 (2x20mL). The combined organic layers were washed with H2O (20mL), aqueous NaHCθ3 (sat., 2x20mL) and dried (MgS04). Evaporation gave 3.633 (40%) of 2. iH-NMR (aceton-dό): 7.67-7.63 (m, 2H, Ar-H); 7.52-7.50 (m, 3H, Ar-H); 4.76 (s, 2H, ArCH2S); 3.75-3.66 (m, 2H, CH2); 2.51-2.41 (m, 2H, CH2). 1 3 C-NMR (aceton-d6): 131.31 (2C); 130.75; 130.46 (2C); 46.58; 43.55; 29.17. Example 36: Kinetic study of formation of S-ButyI-2-(2,4- dimethylphenyl)-tetrahydrotiophenium hexafluorophosphate [lf(S- Bu)-PF 6 ] Aqueous HPF6 (31%, 1.5eq) was added to a mixture of diol 6f (leq) and BuSH (leq). The reaction mixture was stirred at 25°C and monitored by H-NMR analysis. Samples of 0.2mL were diluted with CDCI3 (ImL) and neutralized with K2CO3 followed by filtration through cotton. Cyclic ether 7f: H-NMR: 7.32 (d, IH, Ar-H); 7.00 (d, IH, Ar-H); 6.95 (s, IH, Ar-H): 5.05 (t, IH, J=7.0Hz, CH-O); 4.13 (q, IH, CH2-0); 3.92 (q, IH, CH2); 2.42-2.24 (m, IH, CH2); 2.30 (s, IH, CH3-Ar); 2.27 (s, IH, CH3-Ar); 1.99 (quint, 2H, CH2CH); 1.76-1.57 (m, IH, CH2). Sulfido alcohol, 8f(S-Bu): iH-NMR: 7.31 (d, IH, Ar- HJ; 6.99 (d, IH, Ar-H); 6.94 (s, IH, Ar-H); 4.05 (t, IH, J=7.5Hz, CH-S); 3.58 (t, 2H, J=6.4Hz, CH2-0); 2.31 (s, 3H, CH3-Ar); 2.28 (s, 3H, CH3"Ar); 2.0-1.8 (m.2H, CH2); 1.7-1.2 (m, 4H, CH2); 0.83 (t, 3H, CΗ3). Example 37: Transformation of the diol 6c to the cyclic ether 7c To a ether solution (50 mL) of the diol 6c (2.94g, 15mmol) was added concentrated sulfuric acid (4 drops, 80 mg). The reaction mixture was stirred att 25°C for 2h. Saturated NaHC03 (aqueous 2 L) was added and the organic phase was collected, dried and concentrated to yield 2.6 g (97%) of 7c as a colorless liquid. *H-NMR: 7.26 (d, 2H, J=8.6, Ar-H); 6.87 (d, 2H, J=8.7, Ar-H); 4.87 (t, IH, J---7.0, CH-S); 4.20-3.89 (m, 2H, CH2S), 3.84 (s, 3H, MeO), 2.40-1.77 (m, 4H, C-CH2-CH2-C). Example 38: Synthesis of S,S'-ethyIene-l,2-bis[2-(4-methoxyphenyl)- tetrahydrothiophenium hexafluorophospate] lc(S,S'-ethylene)-PF6 To a mixture of cyclic ether 7c (712 mg, 4 mmol) and 1,2-dimercaptoethane (188 mg, 2 mmol) was slowly added aqueous HPF6 (1.1 mL, 60% w/w, 8 mmol). After stirring for 1 h -at 25°C water (2 mL) was added and the slurry was filtrated. The crystals were washed with water and aqueous NaHC03 and dried yielding 1.40 g (99%) of lc(S,S'-ethylene)-PF6 as yellow crystals, mp = 118-122°C. iH-NMR (acetone-d6) 7.6-7.0 (m, 4H, Ar-H); 5.9-5.3 (m, IH, CH-S); 4.4-3.7 (8H, including MeO); 3.0-2.4 (m, 4H). Anal. Calcd for C24H32S2 2F12: C, 40.8; H, 4.56; S, 9.10; P, 8.7. Found: C, 40.3; H, 4.6; S, 9.2; P, 8.3. Example 39: Synthesis of S,S'-hexylene-l,6-bis[2-(4-methoxyphenyl)- tetrahydrothiophenium hexafluorophospate] [lc(S,S'-hexylene)-PF6l HPF6 (1.47 mL, 10 mmol) was added to a solution of THF-derivative 7c (890 mg, 5 mmol) and 1,6-dimercaptohexane (375 mg, 2.5 mmol). The reaction mixture was stirred for 2 h at 25°C. Water (3 mL) was added and the reaction mixture was extracted with CH2CI2 (3x2 mL) and the combined organic layers were washed with aqueous NaHC03 (sat., 2x1 mL). Drying with MgS04 and evaporation gave the disalt as white crystals, 1.9 g (83%). mp=56-62°C. iH-NMR(aceton-d6): 7.64-7.50 (m, 2H, Ar- HJ; 7.12-6.96 (m, 2H, Ar-H); 5.69-5.57 (m, 0.5 H, CH-S); 5.40-5.22 (m, 0.5H, CH-S); 4.18- 3.48 (m, 14H, CH2-S and); 3.90-3.48 (m, CH2-S and OCH3); 3.20-1.05 (m,16H, -CH2-). Example 40: Synthesis of S-S'-p-xylylene-bis[2-(4-methoxyphenyl)- tetrahydrothiophenium hexafluorophospate] [lc(S,S'-p-xylylene)-PF6] HPF6 (0.5 mL, 3.5 mmol) was added to a solution of cyclic ether 7c (155 mg, 0.87 mmol) and p-xylene-α,α'-dithiol (74 mg, 0.43 mmol). The reaction mixture was stirred for 4 h at 25°C. Water (3 mL) was added and the slurry was filtrated. The crystals were washed with NaHCθ3 (aq) and dried to yield 280 mg (86%) of lc(S,S'- p-xylylene)-PF6 as yellow crystals. mp=96-103°C.lH-NMR(acetone-d6): 7.80-6.74 (m, 12H, Ar-H); 5.82-5.66 and 5.50-5.30 (m, 2H, CH-S); 5.07 and 5.01 (two s, benzylic); 4.59-3.52 (m, 10H, CH2-S and CH3O); 3.00-2.33 (m, 8H, -CH2-). Example 41: Synthesis of lc(S-Bu)-PF6 by addition of diol/ether to acid /me reap tan -mixture Cyclic ether 7c (155 mg, 0.87 mmol) was added dropwise to a mixture of HPF6 (0.25 mL, 1.74 mmol) and BuSH ( 79 mg, 0.87 mmol) and the reaction mixture was stirred for 4h at 25°C. Workup according to the general procedure A yielded 254 mg (95%) of lc(S-Bu)-PF6 as white crystals. General procedure for the synthesis of ketoacids (11) AICI3 (95%, 2eq) was added to an ice-cooled slurry of succinic anhydride (99%, 1 eq) in the aromatic compound __Q. (4.3-6 eq). The reaction mixture was stirred at RT for the indicated time and than cooled with ice. HCI (2M) was added in small portions. The resulting crude product was filtrated and dried. For most cases the crude product was used in the proceeding step. The acids was in some cases purified by the following procedure: the crystals were dissolved in NaOH (2M) and the solution was extracted with diethylether. The aqueous phase was acidfied with HCl (cone.) to pH<l and the acid pricipitates. The crystals were filtrated, washed with HCl (2M) and H2O and dried to give _____ 3-(4-MethylbenzoyI)-propionic acid (lib) Toluene l()b (99.9%, 5.5eq) was reacted with succinic anhydride (99%, leq) and AICI3 (95%, 2eq) for 24 h according to the general procedure. Yellow crystals of l i b were obtained in 75% yield. iH-NMR: 7.88 (d, 2H, J=8.2Hz, Ar-H); 7.26 (d, 2H, J=4.8Hz, Ar-H); 3.29 (t, 2H, J=6.6Hz, CH2CH2COOH); 2.80 (t, 2H, J=6.6Hz, CH2CH2COOH); 2.41 (s, 3H, CH3). 1 3 C-NMR: 192.44; 178.70; 144.13; 133.91; 129.29; 128.14; 33.02; 28.06; 21.63. 3-(4-MethoxybenzoyI)-propionic acid (lie) Anisole 10c (4L, 99%, 37 mol) was reacted with succinic anhydride (670 g, 99%, 6.7 mol) and AICI3 (1.88 kg, 95%, 14.1 mol) for 20 h according to the general procedure. Fluid bed drying of the crude product afforded 1.0 kg (72%) yellowish crystals of lie. iH-NMR: 7.97 (d, 2H, J=8.9Hz, Ar-H); 6.94 (d, 2H, J=8.9Hz, Ar-HJ; 3.87 (s, 3H, OCH3); 3.27 (t, 2H, J=6.7Hz; CH2CH2COOH); 2.74 (t, 2H, J=6.7Hz, CH2CH2COOH). i3 C-NMR (CDCl3+DMSO-d6): 196.22; 174.29; 162.95; 129.68 (2C); 129.21; 113.19 (2C); 54.95; 32.67; 27.70. IR (KBr): 2973; 1702; 1655; 1598; 1486; 1439; 1289; 1260; 1246; 757 cm- 1 . 3 - (4 - ι ' -vø-Propylbenzoyl)-prop ionic aci d ( l i d) Cumene l Ori (99%, 4.8eq) was reacted with succinic anhydride (99%, leq) and AICI3 (95%, 2eq) for 120 h according to the general procedure. Extractive purification of the crude product afforded white crystals of l i d were obtained in 83% yield. i H - NMR: 7.92 (d, 2H, Ar-H); 7.32 (d, 2H, Ar-H); 3.30 (t, 2H, CH2CH2COOH); 2.97 (sept., 1H,CH(CH3)2); 2.81 (t, 2H, CH2CH2COOH); 1.27 (d, 6H, CH(CH3)2). 3- (4 - tert-Butylbenzoyl)-propionic acid (l ie) tert-Butylbenzene l Oe (99%, 4.3eq) was reacted with succinic anhydride (99%, leq) and AICI3 (95%, 2eq) for 120 h according to the general procedure. Extractive purification of the crude product afforded white crystals of l i e in 68% yield. i H - NMR: 7.93 (d, 2H, Ar-H); 7.48 (d, 2H, Ar-H); 3.30 (t, 2H, CH2CH2COOH); 2.81 (t, 2H, CH2CH2COOH); 1.34 (s, 9H, CH3). 3-(2,4-DimethyI benzoyl)-propionic a ci d (1 If ) m-Xylene lOf (98%, 5.5eq) was reacted with succinic anhydride (99%, leq) and AICI3 (95%, 2eq) for 42 h according to the general procedure. Extractive purification of the crude product afforded white crystals of 11 f were obtained in 92% yield. iH-NMR: 7.66 (d, IH, Ar-HJ; 7.07 (d, 2H, Ar-HJ; 3.22 (t, 2H, CH2CH2COOH); 2.77 (CH2CH2COOH); 2.49 (s, 3H, CH3); 2.35 (s, 3H, CH3). 3-(2-Methyl -4-methoxybenzoyI )-propi on ic acid ( U g) 3-Methylanisole lOg (99%, 6eq) was reacted with succinic anhydride (99%, leq) and AICI3 (95%, 2eq) for 20 h according to the general procedure. White crystals of 2 isomers were obtained: 3-(2-methyl-4-methoxybenzoyl)-propionic acid (53%) and 3-(2-methoxy-4-methylbenzoyl)-propionic acid (27%). The crude product was recrystallized in EtOH to give pure β-(2-methyl-4-methoxybenzoyl)-propionic acid (llg) in 24% yield. iH-NMR: 7.80 (d, IH, J=9.4Hz; Ar-HJ; 6.79-6.75 (m, 2H, Ar-H); 3.85 (s, 3H, OCH3); 3.24 (t, 2H, J=6.3Hz, CH2CH2COOH); 2.77 (t, 2H, J=6.3Hz, CH2CH2COOH); 2.55 (s, 3H, CH3). 1 3 C-NMR: 199.16; 178.33; 162.04; 142.35; 131.67; 117.54; 110.67; 110.62; 55.30; 35.02; 28.39; 22.47. 3-(2,4-Dimethoxybenzoyl)-propionic acid ( l l h) 1 ,3-Dimethoxybenzene lOh (99%, 6eq) was reacted with succinic anhydride (99%, leq) and AICI3 (95%, 2eq) for 19 h according to the general procedure. Recrystallization in EtOH gave white crystals of l l h in 68% yield. i H-NMR: 7.89 (d, IH, J=8.7Hz, Ar-HJ; 6.55 (dd, IH, J=8.7 and 2.3Hz, Ar-H); 6.46 (d, IH, J=2.3Hz, Ar-H); 3.91 (s, 3H, OCH3); 3.86 (s, 3H, OCH3); 3.30 (t, 2H, J=6.6Hz, CH2CH2COOH); 2.73 (t, 2H, J=6.6Hz, CH2CH2COOH). 1 C-NMR: 197.62; 164.79; 161.23; 132.96; 105.29; 98.31; 55.54; 55.47; 38.42; 28.67. 3-(2,4,6-TrimethyIbenzoyI)-propionic acid (Hi) Mesitylene lOi (99%, 4.8eq) was reacted with succinic anhydride (99%, leq) and AICI3 (95%, 2eq) for 72 h according to the general procedure. Extractive purification of the crude product afforded white crystals of Hi in 54% yield. i H - NMR (DMSO-d6): 6.63 (s, 2H, Ar-HJ; 2.84 (t, 2H, CH2CH2COOH); 2.22 (s, 3H, p-CH3); 2.18 (t, 2H, CH2CH2COOH); 2.13 (s, 6H, 0-CH3). 3-(2,6-DimethyI-4-methoxybenzoyl)-propionic acid (llj) 3,5-Dimethylanisol lOj (99%, 6eq) was reacted with succinic anhydride (99%, leq) and AICI3 (95%, 2eq) for 20 h according to the general procedure. Extractive purification of the crude product afforded white crystals of llj in 93% yield. iH - NMR: 6.63 (s, IH, Ar-H); 6.56 (s, IH, Ar-H); 3.79 (s, 3H, OCH3); 3.11 (t, 2H, J=6.7Hz, CH2CH2COOH); 2.75 (t, 2H, J=6.7Hz, CH2CH2COOH); 2.32 (s, 3H, CH3); 2.19 (s, 3H, CH3). 1 3 C-NMR: 205.32; 178.97; 156.41; 140.41; 136.05; 127.36; 123.73; 109.01; 55.41; 38.84; 28.04; 21.49; 18.85. 3-(4-Methoxybenzoyl)-butanoic acid (Ilk) Anisole 10k (99%, 6.1eq) was reacted with glutaric anhydride (98%, leq) and AICI3 (95%, 2eq) for 120 h according to the general procedure. Extractive purification of the crude product afforded 66% of ilk. as a black oil. iH-NMR (Aceton-d6): 7.99 (d, 2H, Ar-H); 7.02 (d, 2H, Ar-HJ; 3.89 (s, 3H, CH3); 3.06 (t, 2H, CH2CO); 2.42 (t, 2H, CH2COOH); 1.97 (quint, 2H, CH2CH2COOH). General procedure for the synthesis of l-Aryl-l,4-butandiols (6) The ketoacid, J L (leq, as crystals or dissolved in THF) was added slowly to an ice- cooled slurry of LΪAIH4 (1.3eq, 5.2eq hydride) in THF (1.5-2mL/mmol ketoacid) under a N2-atmosphere. The reaction mixture was stirred for 24 h at RT and then cooled with ice. Water (lmL/g LiAlELj.) was added, followed by aqueous NaOH (15% w/w, lmL/g L1AIH4) and H2O (3mL/g LΪA1H4). CH2CI2 (2-3mL/mmol ketoacid) and MgSθ (5-6 spoones) was added. The slurry was filtrated with a glass filter funnel and the precitate was washed with CH2CI2 (3 times). The filtrate was evaporated to give the diol 6. l-Phenyl-butane-l-4-diol (6a) 3-Benzoylpropionic acid 11a dissolved in THF was reacted with LiAlH4 according to the general procedure. The following workup procedure was used: H2O was added and THF was evaporated. Diethylether and HCl (2M) was added. The aqueous layer was extracted with diethylether and the combined organic layers were washed wit H2O, aqueous NaHC03 (saturated) and H2O. Drying (MgSθ4), filtration and evaporation gave 80% yield of 6a. ! H-NMR: 7.35-7.22 (m, 5H, Ar-H); 4.70 (t, IH, CH- OH); 3.64 (t, 2H, CH20H); 3.10 (brs, IH, CH-OH); 2.60 (brs, IH, CH2-OH); 1.84 (q, 2H, CH2- CHOH); 1.72-1.61 (m, 2H, CH2CH2OH). l-(4-Methylphenyl)-butane-l,4-dioI (6b) The acid lib was reduced according to the general procedure. Recrystallization in petroleumether/EtOAc afforded 6b 70% yield. iH-NMR: 7.29-7.10 (m, 4H, Ar-HJ; 4.61 (t, IH, J=6.1Hz, Ar-CH-OH); 3.63-3.55 (m, 2H, ArCH-CH2); 3.52 (brs, 2H, OH); 2.32 (s, 3H, Ar-CH3); 1-77 (t, 2H, J=6.5Hz, CH6CH2OH); 1.64-1.56 (m, 2H, CH2CH2CH2OH).1 3 C-NMR: 141.67; 136.98; 129.00 (2C); 125.71 (2C); 74.06; 62.62; 36.15; 29.12; 21.03. l-(4-Methoxyphenyl)-butane-l,4-dioI (6c) The acid lie was reduced according to the general procedure and yellowish crystals of 6c were obtained in 63% yield. iH-NMR: 7.28-7.24 (m, 2H, Ar-H); 6.89-6.84 (m, 2H, Ar-H); 4.65 (t, IH, J=6.2Hz, Ar-CH-OH); 3.79 (s, 3H, ArOCH3); 3.67-3.62 (m, 2H, CH2); 2.90 (brs, OH); 2.60 (brs, OH); 1.91-1.80 (m, 2H, CH2); 1.75-1.60 (m, 2H, CH2). 1 - (4- iso -Pro pylphenyl)-butane-l,4-dio I (6d) The acid lid was reduced according to the general procedure and 6d was obtained in 84% yield as acolorless oil. iH-NMR: 7.21 (q, 4H, Ar-HJ; 4.64 (t, IH, Ar-CH-OH); 3.60 (m, 2H, CH2-OH); 3.3 (brs, IH, OH); 3.1 (brs, IH, OH); 2.90 (sept., IH, CH-(CH3)2); 1.81 (q, 2H, CH-CH2): 1-63 (m, 2H, CH2CH2OH); 1.23 (d, 6H, CH3). l-(4-t.2rt-Butylphenyl)-butane-l,4-diol (6e) The acid He was reduced according to the general procedure and 6e was obtained in 92% yield white crystals. iH-NMR: 7.32 (dd, 4H, Ar-H); 4.70 (t, IH, Ar-CH-OH); 3.68 (t, 2H, CH2-OH); 2.6 (brs, IH, OH); 2.2 (brs, IH, OH); 1.85 (q, 2H, CHCH2); 1.67 (m, 2H, CH2CH2OH); 1.31 (s, 9H, CH3). l-(2,4-Dimethylphenyl)-butane-l,4-diol (6f) The acid llf was reduced according to the general procedure and 6f was obtained in 94% yield. iH-NMR: 7.34 (d, IH, Ar-HJ; 7.02 (d, IH, Ar-H); 6.94 (s, IH, Ar-HJ; 4.90 (dd, IH, CH); 3-75-3.55 (m, 2H, CH20H); 2.8 (brs, 2H, OH); 2.29 (s, 3H, CH3); 2.28 (s, 3H, CH3); 1-86-1.60 (m, 4H, CHCH2CH2). l-(2-Methyl-4-methoxypheηyI)-butane-l,4-dioI (6g) The acid 11 g was reduced according to the general procedure and __g. was obtained in 86% yield as yellowish crystals. iH-NMR: 7.37 (d, IH, J=8.5Hz, Ar-H); 6.76 (dd, IH, J=8.5 and 2.5Hz, Ar-HJ; 6.68 ( d, IH, J=2.5Hz, Ar-HJ; 4.91 (t, IH, Ar-CH(OH)); 3.79 (s, 3H, OCH3); 3.55-3.45 (m, 2H, CH2-OH); 2.32 (s, 3H, CH ); 1.85-1.65 (m, 4H, CH2CH2). 13 C- NMR: 126.42; 115.93; 111.33; 70.47; 62.96; 55.18; 35.14; 29.56; 19.24. l-(2,4-Dimethoxyphenyl)-butane-l,4-diol (6h) The acid llh was reduced according to the general procedure and white crystals of 6h were obtained in 85% yield. iH-NMR: 7.23 (d, IH, J=9Hz, Ar-H); 6.51-6.46 (m, 2H, Ar-HJ; 4.88 (t, IH, J=6Hz, Ar-CH2-OH); 3.83 (s, 3H, 0CH3); 3.81 (s, 3H, OCH3); 3.70 (t, 2H, J=5.7Hz, CH2-CH2-OH); 1.93-1.80 (m, 2H, CH2-CH2-OH); 1.78-1.63 (m, 2H, Ar-CH(OH)- CH2)- 13 C-NMR: 159.69; 157.10; 127.06; 125.02; 103.91; 98.28; 69.24; 62.50; 55.12; 55.06; 34.15; 29.23. l-(2,4,6-TrimethyIphenyl)-butane-l,4-diol (6i) The acid H i was reduced according to the general procedure. The crude 6i was obtained in 85% yield. Recrystallization in EtO Ac/petroleum ether (40/60) gave 61 in 52% yield as white crystals. iH-NMR: 6.80 (s, 2H, Ar-H); 5.11 (dd, IH, CHJ; 3.66 (q, 2H, CH20H); 2.7 (brs, 2H, OH); 2.2-1.6 (m, 4H, CHCH2CH2)- l-(2,6-Dimeth l-4-methoxyphenyl)-butane-l,4-dioI (6j) The acid llj was rduced according to the general procedure and white crystals of 6j were obtained in 77% yield. iH-NMR: 6.59 (s,2H, Ar-HJ; 4.87-4.78 (m, IH, Ar-CH-OH); 3.84 (s, 3H, OCH3); - 62 ft, 2H, J=5.7Hz, CH2-OH); 2.27 (s, 3H, CH3); 2.24 (s, 3H, CH3); 2.00- 1.60 (m, 4H, CH2CH2). 13 C-NMR: 157.36; 137.45; 135.68; 126.92; 124.29; 110; 71.04; 67.86; 62.68; 55.25; 34.10; 30.05; 25.52; 21.23; 21; 19.69. l-(4-MethoxypheπyI)-pentane-l,4-dioI (6k) The acid Ilk was reduced according to the general procedureand a yellow oil of 6 k was obtained in 91% yield. iH-NMR: 7.25 (d, 2H, Ar-HJ; 6.67 (d, 2H, Ar-HJ; 4.6 (t, IH, Ar-CH-OH); 3.80 (s, 3H, CH3); 3.61 (t, 2H, CH2-OH); 2.1 (brs, IH, OH); 1.9-1.2 (m. 7H, CH2OH). General procedure for diols (12) R2(l )Li (l.l-1.2eq) was added to a solution of phtalid ( leq) in THF ( l-2mL/mmol phtalid). The reaction mixture was stirred for 0.5- lh at -78°C and under N2- atmosphere followed by addition of R2(2) gX (2.4eq) or LiAlH4 to the dryice-cooled reaction mixture. The cooling bath was removed and the reaction mixture was stirred for indicated time at ambient temperature followed by addition of aqueous NH4CI (saturated). The aqueous layer was extracted with CH2CI2 and the combined organic layers were washed with H2O, dried (MgSθ4) and concentrated to give the diol 12. α -Phenyl-benzene dimethanol ( 12B) Phtalid was reacted with PhLi (leq, 2M in cyklohexane/diethylether 75/25) according to the general procedure. The reaction mixture was then transferred to a slurry of LiAlH4 in THF kept at 0°C and under N2 -atmosphere. The temperature was raised to RT and the reaction mixture was stirred for 1.5 hour. H2O was added very slowly at 0°C, followed by NaOH (15%) and H2O. CH2CI2 and MgS04 was added. The mixture was filtrated with a glass filter funnel and the filtrate was evaporated to give 74% of 12B. iH-NMR: 7.65-7.15 (m, 9H, Ar-H); 5.99 (s, IH, CH(Ph)-OH); 4.63 (s, IH, OH); 4.63 (s, IH, OH); 4.59 (d, IH, J=12Hz, CH2-OH); 4.42 (d, IH, J=12Hz, CH2-OH). α-i-. ø-Propylbenzene dimethanol (12C) Isopropylmagnesiumchlorid (2.4eq, 2M in diethylether) was added to a solution of phtalid (leq) in THF according to the general procedure. The reaction mixture was stirred for at ambient temperature for 5h . Workup gave a mixture of α-isopropyl benzene dimethanol (12C) (74%) and α,α-diisopropyl benzene dimethanol (26%). The products were separated by flash chromatography (petroleumether/EtOAc 3/2). 12C was obtained in 61% yield. i H-NMR: 7.45-7.2 (m, 4H, Ar-H); 4.69 (s, 2H, CH2-OH); 4.5 (d, IH, J=8Hz, HO-CH-CH(CH3)2); 2.8 (brs, 2H, OH); 2.2-2 (m, IH, CH(CH3)2); 1.11 (d, 3H, J=7Hz, CH3); 0.76 (d, 3H, J=7Hz, CJJ.3). 1 3 C-NMR: 141.81; 137.65; 129.02; 127.73; 127.26; 127.13; 76.60; 62.39; 33.98; 19.34; 18.94. α-Dimethylbenzene dimethanol (12D) MeMgCl (2.4eq, 2M in diethylether) was added to solution of phtalid (leq) in THF according to the general procedure. After stirring for 3 h at RT and workup. 1 2 D was isolated in 95% yield. i H-NMR: 7.25-7.15 (m, 4H, Ar-HJ; 4.84 (s, 2H, CH2-OH); 1.69 (s, 6H, CH3). 1 3 C-NMR: 145.33; 137.85; 131.66; 127.78; 127.02; 126.15; 74.35; 65.09; 32.20 (2C). IR: 3270; 3083; 3068; 2988; 2974; 2963; 2945; 2880; 1484; 1452; 1437; 1380; 1363; 1214; 1163; 1115; 1056; 1031; 1031 ; 937; 873; 763; 722. α-Methyl-α-phenylbenzeπe dimethanol (12E) Phtalid was reacted with MeLi (l.leq, 1.6M in diethylether) for lh and then with PhMgCl (2M in THF) according to the general procedure. Sirring for 1.5 h at ambient temperature and workup gave acrude product in 80% yield which was purified by bulb-to-bulb destination affording 12E in 74% yield. iH-N R: 7.7-7.2 (m, 9H, Ar-H); 4.48 (t, IH, J=5Hz, OH); 4.31 (dd, IH, J=13 and 5Hz, CH2-OH); 4.12 (dd, IH, J=13 and 5Hz, CH2-OH); 2.86 (s, IH, OH); 1.84 (s, 3H, CH3). 1 C-NMR: 150.51; 146.62; 141.00; 131.20; 128.26 (2C); 127.96; 127.57; 126.95; 126.71; 125.56;.76.84; 63.71; 33.06. α.α-Diphenylbenzene dimethanol (12F) PhMgCl (2.5eq, 2M in THF) was reacted with phtalid according to the general procedure. Stirring for 3 h at ambient temperature and workup gave 2F in 94% yield. iH-NMR: 7.6-7 (m, 13H, Ar-H); 6.66 (d, IH, J=7Hz, Ar-H); 4.28 (s, 2H, CH2-OH). 13 C-NMR (CDCI3 DMSO): 146.69; 146.53; 139.30; 131.87; 129.75; 127.56; 127.44; 127.39; 126.61; 126.60; 82.37; 64.24. IR: 3430; 3255; 3058; 3034; 2966; 2894; 1597; 1488; 1447; 1424; 1269; 1201; 1180; 1161; 1099; 1080; 1056; 1031; 1011; 1002; 955; 931; 898; 765; 702; 640; 610. α-Methyl-α-vinylbenzene dimethanol (12G) Phtalid was reacted with MeLi (1.6M in diethylether) for 1 hour and then with vinylmagnesiumbromid (IM in THF) according to the general procedure. Stirring for 3.5 h at ambient temperature and workup gave a crude product in 95% yield. Purification by buib^to-bulb destination afforded 12G in 80% yield. iH-NMR: 7.45- 7.20 ( , 4H, Ar-HJ; 6.16 (dd, IH, J=ll and 17Hz, CH=CH2); 5.26 (d, IH, J=17Hz, trans in CH2=CH); 5.14 (d, IH, J=llHz, cis in CH2=CH); 4.93 (d, IH, J=12Hz, Ar-CH2-OH); 4.59 (d, IH, J=12Hz, Ar-CH2-OH); 1.74 (s, 3H, CH3). i3 C-NMR: 144.98; 143.83; 138.67; 131.85; 127.83; 127.62; 126.62; 112.14; 76.06; 64.54; 29.65. α-Phenyl-α-vinylbenzene dimethanol (121) Phtalid was reacted with PhLi for 2.5 h and then with vinylmagnesiumbromid according to the general procedure. Stirring for 3 h at ambient temperature, workup, followed by bulb-to-bulb destination gave 121 in 75%. yield. iH-NMR: 7.6- 7.2 (m, 9H, Ar-H); 6.32 (dd, IH, J=ll and 17Hz, CH=CH2); 5.3 (d, IH, J=llHz, CH=CH2); 5.14 (d, IH. J=17Hz, CH=CH2); 4.3 (AB, 2H, J=12Hz, CH2-OH). 13 C-NMR: 145.38; 144.40; 143.77; 138.84; 132.02; 128.57; 127.98; 127.82; 127.72; 127.51; 127.07; 126.96; 126.85; 126.20; 114.05; 80.37; 64.25.

Claims: CLAIMS 1. A process for the production of a 5-7 membered ring cyclic sulfonium salt compound comprising reacting a 1,4-, 1,5-, or 1 ,6-diol compound or a 5-7 membered ring cyclic ether compound with a mercapto compound and a strong protonic acid. 2. Process according to claim 1 , wherein the strong protonic acid is added to the mercapto compound and the resulting mixture is added to the diol or cyclic ether compound, or the strong protonic acid is added to a mixture containing the mercapto compound and the diol or cyclic ether compound, in substantially equimolar amounts with respect to the functional groups involved. 3. Process according to any of claims 1 and 2, wherein the mercapto compound is a monounctional mercaptan. 4 Process according to any of claims 1 and 2, wherein the mercapto compound is a di- or polyfunctional mercaptan. 5. Process according to claim 3 or 4, wherein the mercapto compound is selected from i) a monofunctional mercaptan which is methyl mercaptan, a primary, secondary, or tertiary alkyl or cycloalkyl mercaptan, an aryl mercaptan, preferably phenyl mercaptan, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, phenyl, phenoxy, or thiophenoxy, and naphthyl mercaptan, an arylalkyl mercaptan, preferably benzyl mercaptan, which is unsubstituted or mono- or independently polysubstituted by alkyl, alkoxy, or thioalkoxy; or ii) a di- or polyfunctional mercaptan of the general formula HS-[A-SH]m . wherein m > 1 , and A independently represents alkylene, preferably C2 -C20. arylene, preferably phenylene, biphenylene or naphtylene; alkylenebisaryl preferably metylenebifenyl; or aralkylene, preferably xylylene. 6. Process according to any of claims 1 to 5, wherein the diol or cyclic ether compound is a monofunctional diol or cyclic ether compound. 7. Process according to any of claims 1 to 5, wherein the diol or cyclic ether compound is a di- or polyfunctional diol or cyclic ether compound. 8. Process according to claim 6 or 7, wherein the diol compound is selected from j) a monofunctional diol which is a 1,4-, 1 ,5-, or 1 ,6-diol, which is i) unsubstituted, or ii) mono- or independently polysubstituted by alkyl, cycloalkyl, 1-alkenyl, preferably vinyl, aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, cyano, alkyl sulfonyl, aryl sulfonyl, preferably phenyl sulfonyl, aryl, preferably phenyl, aryloxy, preferably phenoxy, or thioaryloxy, preferably thiophenoxy; and/or iii) aryl fused, preferably benzo, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenyl, phenoxy, or thiophenoxy, or iv) cycloalkyl fused, which is unsubstituted or mono- or independently polysubstituted by alkyl or cycloalkyl; or jj) a di- or polyfunctional diol of the general formula C-[B-C] W , wherein w 1, C independently represents a 1,4-, 1,5-, or 1,6-diol as defined above, and B independently represents alkylene, preferably C2-C20, arylene, preferably phenylene, biphenylene or naphtylene; alkylenebisaryl , preferably metylenebifenyl; or aralkylene, preferably xylylene. 9. Process according to claim 6 or 7, wherein the 5, 6, or 7 membered ring cyclic ether compound is selected from j) a monofunctional 5-7 membered ring cyclic ether, which is a tetrahydrofuran, a tetrahydropyran, or a hexahydrooxepin, which is i) unsubstituted, or ii) mono- or independently polysubstituted by alkyl, cycloalkyl, vinyl, aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, cyano, alkyl sulfonyl, aryl sulfonyl, preferably phenyl sulfonyl, aryl, preferably phenyl, aryloxy, preferably phenoxy, or thioaryloxy, preferably thiophenoxy; and/or iii) aryl fused, preferably benzo, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenyl, phenoxy, or thiophenoxy, or iv) cycloalkyl fused, which is unsubstituted or mono- or independently polysubstituted by alkyl or cycloalkyl; or jj) a di- or polyfunctional cyclic ether of the general formula C-[B-C] W , wherein w > 1, C independently represents a tetrahydrofuran, a tetrahydropyran, or a hexahydrooxepin as defined above, and B independently represents alkylene, preferably C2-C20. arylene, preferably phenylene, biphenylene or naphtylene; alkylenebisaryl , preferably metylenebifenyl; or aralkylene, preferably xylylene. 10. Process according to claim 1 to 9, wherein the strong protonic acid is selected from hydrohalogenic, perhalogenic, tetrahaloboric, hexahaloantimonic, hexahaloarsenic, hexahalophosphoric, sulfonic, halogen-substituted alkyl or aryl sulfonic, phosphoric or sulfuric acid. 11 Process according to claim 10, wherein the strong protonic acid is selected from such acids which produce a 5-7 membered ring cyclic sulfonium salt compound having a non-nucleophilic anion . 12. Process according to claim 11 , wherein the strong protonic acid is selected from perchloric, tetrafluoroboric, hexafluoroantimonic, hexafluoroarsenic, hexafluorophosphoric, p-toluensulfonic or triflic acid. 13. Process according to any of claim 1 to 6 and 8 to 12, comprising reacting (a) a mercapto compound having the formula Ri -SH, wherein R - in a monofunctional mercaptan represents methyl, primary, secondary, or tertiary alkyl or cycloalkyl; aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, phenyl, phenoxy or thiophenoxy; and naphthyl; arylalkyl, preferably benzyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, alkoxy or thioalkoxy; or R- in a di- or a polyfunctional mercaptan represents -[A-SH] m , wherein m > 1, and A independently represents alkylene, preferably C2-C20. arylene, preferably phenylene, biphenylene or naphtylene; alkylenebisaryl , preferably metylenebifenyl; or aralkylene, preferably xylylene, wi th (b) a diol compound selected from the group consisting of formula I: wherein n is 1,2, or 3, R^ independently represents hydrogen, alkyl, cycloalkyl, or aryl, preferably (R 7 )v r. wherein y is an integer between 0 and 5, and R^ independently represents alkyl, alkoxy, thioalkoxy, halogen, cyano, alkyl sulfonyl, aryl sulfonyl, preferably phenyl sulfonyl, aryl, aryloxy, or thioaryloxy, wherein the aryl group preferably is phenyl which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenoxy, thiophenoxy, cyano, alkyl sulfonyl, or aryl sulfonyl, preferably phenyl sulfonyl, R 3 independently represents hydrogen, alkyl, cycloalkyl, aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenoxy or thiophenoxy, R4 independently represents hydrogen, alkyl, cycloalkyl, aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenoxy or thiophenoxy, or integer of between 0 and 4, and R^ independently represents alkyl, alkoxy, thioalkoxy, halogen or phenyl, R5 independently represents hydrogen, alkyl, cycloalkyl, aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenoxy or thiophenoxy, R6 independently represents hydrogen, alkyl, cycloalkyl, aryl, preferably phenyl, which is unsubstituted or mono- or independently polysubstituted by alkyl, cycloalkyl, alkoxy, thioalkoxy, halogen, phenoxy or thiophenoxy, o r (c) a cyclic ether compound selected from the group consisting of formula II: wherein n, R2, R 3 , R4, R5, and R6 are as defined above, (d) and a strong protonic acid having the formula HX, wherein X represents a halogen or a group of the formula MYr, wherein M represents Sb, P, B, As, or Cl; Y represents a halogen or oxygen; and r is an integer between 4 and 6, or X represents a group RSO3 wherein R is OH, alkyl, aryl or halogen substituted aryl group, yielding a monofunctional cyclic sulfonium salt compound, when Ri ≠ -[A-SH] m , having the following structural formula III-l: wherein n, Ri , R , R 3 , R4, R , R6 t and X are as defined above with the exception of that Ri ≠ -[A-SH] m ; or a di- or polyfunctional cyclic sulfonium salt compound, whe R i = -[A-SH] m , having the following structural formula III-2: wherein n, m, A, R , R 3 , R 4 , R5 , R6 t and X are as defined above. 14. Process according to claim 13, wherein R and n are as defined in claim 13, one of R 2 =H and the other is aryl as defined in claim 13, R 3 =H, R 4 =H, R 5 =H, R6----H, and X represents SbF6, PF6, BF4, CIO4, or CF3SO3. 15. Process according to claim 13, wherein in the diol compound of I) or the cyclic ether compound of II), when n=l and R 3 and R 4 together form a fused aryl group as defined, one R2 can additionally define an 1-alkenyl, (R9)2C=C(R l O)-, wherein R^ and Rl O independently represent hydrogen, alkyl, cycloalkyl, aryl, preferably phenyl, or a 5-7 membered ring formed by R' and Rl O; preferably hydrogen, i.e. a vinyl group, yielding a cyclic sulfonium salt compound having the following structural formula IV: wherein Ri, R2, R5, R6, R8 I __ and x are as defined in claim 10, except thatRi ≠ -[A- SH] m . 16. An aryl-substituted or aryl-fused cyclic sulfonium salt which is: S-butyl-2-(phenyI)-tetrahydrothiophenium hexafluoroantimonate, S-butyl-2-(4-methyIphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(4-methoxyphenyl)-tetrahydrothiophenium hexafluoroantimonate, S-dodecyl-2-(4-methoxyphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyI-2-(4-methoxyphenyl)-tetrahydrothiophenium tetrafluoroborate, S-butyl-2-(4-methoxyphenyl)-tetrahydrothiophenium perchlorate, S-butyl-2-(4-methoxyphenyl)-tetrahydrothiophenium triflate, S-butyl-2-(4-isopropylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(4-tert-butylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(2,4-dimethylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-tert-butyl-2-(2,4-dimethylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-iso-butyl-2-(2,4-dimethylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-iso-propyl-2-(2,4-dimethylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-dodecyl-2-(2,4-dimethylphenyl)-tetrahydrothϊophenium hexafluorophosphate, S-phenyl-2-(2,4-dimethylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(2,4-dimethyIphenyl)-tetrahydrothiophenium hexafluoroantimonate, S-butyI-2-(2-methyl-4-methoxyphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(2,4-dimethoxyphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(2,4,6-trimethylphenyl)-tetrahydrothiophenium hexafluorophosphate, S-butyl-2-(2,6-dimethyl-4-methoxyphenyl)-tetrahydrothiophenϊum hexafluorophosphate, S-butyl-2-(4-methoxyphenyl)-pyranium hexafluorophosphate, S,S'-ethylene-l,2-bis[2-(4-methoxyphenyl)-tetrahydrothiophenium hexafluorophospate] , S,S , -hexylene-l ,6-bis[2-(4-methoxyphenyI)-tetrahydrothiophenium hexafluorophospate] , S,S'-p-xyIylene-bis[2-(4-methoxyphenyl)-tetrahydrothiophenium hexafluorophospate] , S-Butyl-2-phenyl-[3,4]-benzo-2,5-dihydro-thiophenium hexafluorophosphate, S-Butyl-2-;"jro-propyl-[3,4]-benzo-2,5-dihydrothiophenium hexafluorophosphate, S-Butyl-2,2-dimethyI-[3,4]-benzo-2,5-dihydrothiophenium hexafluorophosphate, S-Butyl-2-metyl-2-phenyl-[3,4]-benzo-2,5-dihydrothiophenium hexafluorophosphate, S-Butyl-2,2-diphenyl-[3,4]-benzo-2,5-dihydrothiophenium hexafluorophosphate, S-Butyl-5-methyl-[3,4]-benzo-2,7-dihydrothiephinium hexafluorophosphate, S-Butyl-5-phenyl-[3,4]-benzo-2,7-dihydrothiephinium hexafluorophosphate.

Inventors: BEIERLEIN KATARINA, ELMAN BJOERN, ENGELHARDT PER, NYLOEF MARTIN, NYSTROEM JAN-ERIK, SELLEN MIKAEL, VAAGBERG JAN, BEIERLEIN, KATARINA, ELMAN, BJOERN, ENGELHARDT, PER, NYLOEF, MARTIN, NYSTROEM, JAN-ERIK, SELLEN, MIKAEL, VAAGBERG, JAN
Applicants: CIBA GEIGY AG, CIBA-GEIGY AG
Application year: 1991
Main classification: C07D335
IPC codes: C07D333, C07D335, C07D337