METHOD OF PRODUCING A SINTERED CARBONITRIDE ALLOY FOR INTERMITTENT MACHINING OF MATERIALS DIFFICULT TO MACHINE

Abstract: According to the invention there now is provided a method of producing a sintered titanium based carbonitride alloy with 3-25 weight-% binder phase with extremely good properties at intermittent machining of materials difficult to machine. The method relates to the use of a raw material comprising a complex cubic carbonitride containing the main part of the metals from groups IV and V of the periodic system and carbon and nitrogen to be found in the finished alloy whereby said alloy has the composition 0.86 </= XIV </= 0.97, 0.44 </= XC </= 0.55, where XIV is the molar ratio of the group IV elements of the alloy and XC is the molar ratio of carbon.

Description: Method of producing a sintered carbonitride allσv for intermittent machining of materials difficult to machine. The present invention relates to a method of produ¬ cing a sintered carbonitride alloy with titanium as main constituent particularly suited for intermittent machining of materials difficult to machine. Sintered carbonitride alloys based on mainly titanium usually referred to as cermets have during the last years increased their use at the expense of more tra¬ ditional cemented carbide i.e. tungsten carbide based alloys. US 3,971,656 discloses the production of an alloy with a duplex hard constituent where the core has a high content of Ti and N and the surrounding rim has a lower content of these two elements which is com- pensated for by a higher content of group VI metals i.e. in principle Mo and and by higher carbon con¬ tent. The higher content of Mo, and C has inter alia the advantage that the wetting against the bin- derphase is improved i.e. the sintering is facili- tated. As a raw material a carbonitride of titanium and a group VI metal is used. By changing the raw material it is possible to vary the core-rim-composition. In e.g. Swedish Patent Spe- cification 459 862 it is shown how it is possible to use (Ti,Ta)C as a raw material to get a duplex struc¬ ture with cores with a high content of titanium and tantalum but low content of nitrogen. The surrounding rims have higher contents of group VI-metals, i.e. molybdenum and tungsten and higher contents of nitro- SUBSTITUTE SHEET gen than the cores. This leads inter alia to an im¬ proved resistance against plastic deformation. Furthermore, it has in Swedish Patent Application 8902306-3 been shown how by mixing various types of core-rim structures in one and the same alloy advan¬ tages and drawbacks can be balanced out in such a way that optimized alloys are obtained. EP-A-259192 discloses a sintered alloy comprising a mixed carbonitride of titanium and at least one ele¬ ment from the group consisting of group IV, V and VI elements except titanium in a binder phase based on Co and/or Ni. The alloy is produced by mixing powders of the hard constituents, heating the mixture in a nitrogen atmosphere at a temperature of at least the sintering temperature to form a solid solution, mil¬ ling said solid solution to obtain a carbonitride powder which is mixed with Co and/or Ni and sintered. It has now turned out that if sintered titaniumbased carbonitride alloys are produced using complex cubic carbonitride raw material which contains the main part, preferably >90%, most preferably >95% of the metals at least two preferably at least three from the groups IV and V in addition to carbon and nitro¬ gen being part of the finished sintered carbonitride alloy unique structures as well as unique properties are obtained. Preferably all of the nitrogen shall be present in the mentioned carbonitride raw material. In particular of the above-mentioned metals all tita¬ nium and tantalum shall be present in the raw mate¬ rial according to the invention. Preferably also va- nadium, niobium and suitably also zirconium and haf- SUBSTITUTE SHEET nium are present if they are part of the finished sintered alloy. Metals from group VI, Cr, Mo and W, shall, if they are present, be added as multiple car¬ bides, single carbides and/or as metal+carbon, but they may also be part of the raw material according to the invention provided that the raw material re¬ mains cubic. The raw material acording to the invention is produ¬ ced directly by carbonitriding of the oxides of the metals or the metals themselves. As a result a carbo¬ nitride powder with essentially equiaxial grains and a narrow grain size distribution is obtained with a mean grain size of 0.8 - 3 μm, preferably 1 - 2 μm. As mentioned interesting properties of a sintered carbonitride alloy are obtained if the special raw materials according to this invention are used. Thus, it has turned out that a carbonitride alloy with ex- tremely positive properties at intermittent machining of materials difficult to machine which materials have a tendency to clad if a raw material with e.g. the composition (Tig # 93,TaQ.07^ c 0.48' N 0.52^ ^ s used. This effect is further increased if in addition vana- dium is added whereby the corresponding formula will be (τi 0.88, a 0.06' V 0.06> (C 0.51' N 0.49> • Corresponding inserts made from simple raw materials and in exactly the same equipment give considerably decreased pro¬ perties in toughness inter alia greater scatter at the same wear resistance. This means that the relia¬ bility of such inserts is considerably decreased which means that they are not as efficient when pro¬ ducing with limited manning a production form with increased importance due to increasing labour costs. SUB TlTUte SHEET One of the reasons for this positive behaviour has turned out to be that _a considerably lower porosity level is obtained with this complex raw material com¬ pared to conventional raw materials without having to use any other means such as HIP and this with even lower compaction pressure than for conventional mate¬ rial. This is a great advantage from production point of view inter alia due to reduced tool wear and con¬ siderably lower risk for unfavourable pressing cracks. The invention thus relates to a method of producing a titanium based carbonitride alloy with 3-25 % by weight binderphase based on Co, Ni and/or Fe using the above mentioned complex raw material. This raw material is milled together with carbides from group VI, if any, and binderphase elements and carbon addi¬ tion, if any, and minor additions of e.g. TiC, TiN, TaC, VC or combinations thereof due to small devia- tions in composition of the complex raw material whe¬ reafter compaction and sintering, preferably in an inert atmosphere, is performed according to known technique. Fig 1 shows the 'window' in the composition diagram for Group IV-Group V - C-N, expressed in molar ratio, of the complex raw material which shows the above mentioned advantages in high magnification, whereas fig 2 shows where in the total molar ratio diagram this small area is situated. Group IV metals are Ti, Zr and/or Hf and Group V me¬ tals are V, b and/or Ta. SUBSTITUTE SHEET As is evident from figure 1 the window comprises the composition area: 0.84< X IV < 0.97 0.44< X c < 0.55 and in particular: 0.86< X IV < 0.95 0.46< X c < 0.53 The latter restricted window can be divided into two, one without other group V metals than Ta: 0.905< X IV < 0.95 0.46< X c < 0.53 and another one with other group V elements than Ta i.e. V and Nb: 0.86< X IV < 0.905 0.46< X c < 0.53 Particularly good properties are obtained for the compositions 0.91< X IV < 0.95 0.46< X c < 0.50 respectively 0.86< X IV < 0.90 0.49< X c < 0.53 SUBSTITUTE SHEET For titanium the following applies x>pj_>0.7 preferably In the above given molar ratios for carbon and nitro- gen usual amounts of oxygen may be present i.e. sub¬ stitute carbon and nitrogen even if it is desirable to keep such amounts of oxygen low <0.8 %, preferably <0.5 %. The invention comprises εtoichiometric as well as usually substoichiometric carbonitrides. Example Titanium-based carbonitride alloys with 17.5 % Ni+Co binder phase were produced with the use of a complex raw material according to the invention ( in.βS'Tao.Oβ'Nko.Oβ) ( C 0.51' N 0.49> as wel1 as wi h the use of simple raw material: TiN, TiC and VC. In both cases also C and M02C were added in addition to Co and Ni. The following compaction pressure and po- rosity after milling and sintering to the same grain size were obtained: Porosity Compaction pressure, N/mm^ Alloy according to the invention A00 154 Simple raw materials A06-A08 206 BO4 SUBSTITUTE SHEET

Claims: Claims 1. Method of producing a sintered titanium based car¬ bonitride alloy with 3-25 weight-% binder phase by milling, pressing and sintering according to known technique c h a r a c t e r i z e d in that a raw ma¬ terial is used comprising a complex cubic carboni¬ tride containing the main part of the metals from groups IV and V of the periodic system and carbon and nitrogen to be found in the finished alloy whereby said alloy has the composition 0.86< X IV < 0.97 0.44< X C < 0.55 where X y is the molar ratio of the group IV elements of the alloy and Xc is the molar ratio of carbon. 2. Method according to claim 1 c h a r a c t e r i z e d in that the carbonitride raw material comprises essentially equiaxial grains with a narrow grain size distribution with a mean grain size of 0.8 - 3 μm, preferably 1 - 2 μm. 3. Method according to claim 1 or 2 c h a r a c t e r i z e d in that the composition of the complex raw material is 0.86< X IV < 0.95 0.46< X c < 0.53 4. Method according to any of the preceding claims c h a r a c t e r i z e d in that said raw material is produced directly by carbonitriding of the oxides of the metals or the metals themselves. SUBSTITUTE SHEET

Inventors: OSKARSSON ROLF, WEINL GEROLD, OSKARSSON, ROLF, WEINL, GEROLD
Applicants: SANDVIK AB
Application year: 1991
Main classification: C22C29
IPC codes: C01B21, C22C1, C22C29