Apparatus for developing electrostatic latent image and developing roller therefor

Abstract: A developing apparatus for developing an electrostatic latent image includes a movable developer carrying member (8) for carrying one component developer to a developing zone (D) where the developer carrying member (8) is opposed to a latent image bearing member (1) for carrying the electrostatic latent image, the developer carrying member (8) being effective to triboelectrically charge the developer to a polarity for developing the latent image; a regulating member (2) for regulating a thickness of a layer of the developer to be carried to the developing zone (D); a voltage source (9) for applying a developing bias voltage to the developer carrying member (8); wherein the developer carrying member (8) comprises a base member (6') having a surface sandblasted to have an average surface roughness of 1.0 - 3.0 microns, and an outer layer (7) thereon in which fine graphite particles are dispersed in a binder resin material, and wherein the outer layer has an average surface roughness of 0.8 - 2.5 microns. In another embodiment an intermediate layer (6") comprising Pine particles dispersed in another binder is interposed between the base (6) and the outer layer (7).

Description: FIELD OF THE INVENTION AND RELATED ART The present invention relates to a developing apparatus for developing electrostatic latent images, more particularly to a developer carrying member therefor. A developing apparatus using one component developer is widely used in electrophotographic coping machines and printers. U.S. Patent Nos. 4,377,332 and 4,380,966 disclose that the surface of a developer carrying member is roughened to improve the developer conveying performance. In the developing apparatus used with a one component developer, the toner particles are triboelectrically charged by contact with the developer carrying member to the polarity suitable to develop the latent image. The roughened developer carrying member is effective to charge the toner particles to a proper degree. In such a region of the developer carrying member as corresponds to the non-image area of an image bearing member, the developer is not consumed. If the non-consuming situation continues, fine developer is strongly attached probably due to mirror force with the result that the developer is not easily consumed even when the area corresponds to the image area thereafter and that the amount of charge decreases. If this occurs, the ghost image is formed. Figure 6 explains this more in detail. The density difference occurs between a portion (a) (white continued) and portion (b) (black continued). The ghost image formation mechanism is significantly concerned with a fine particle layer formed on the developer carrying member. The particle size distribution of the bottom part of the developer layer is remarkably different depending on whether the toner is consumed or not. The fine particle layer is formed particularly in the toner non-consumed areas. Since a fine particle has a large surface area per unit volume, and therefore, it has larger amount of triboelectric charge per unit weight than a larger size particle. Therefore, the smaller size particles are more strongly deposited on the developer carrying member by the mirror force. The toner particles on the fine particle layer are not triboelectrically charged to a sufficient extent, with the result of degraded developing performance, and therefore, ghost image production. The recent demand for the high image quality in the electrophotographic apparatus requires that the toner size is reduced. In the case of electrophotographic laser beam printer, if the print density is increased from 300 dpi from 600 dpi (23.6 pel), the desired resolution, sharpness and therefore faithful development of an electrostatic latent image is relatively easily achieved if the toner having particle size of 9-4 microns is used. An example of such toner has a volume average particle size of 6.0 microns, and the particle size distribution on the basis of number is approx. 20 % or smaller for no greater than 3.5 microns of the volume average particle size, and the particle size distribution on the basis of the volume is approx. 10 % or smaller for no less than 16 microns of the volume average particle size. However, such toner particles have larger surface areas per unit volume, and therefore, the amount of the triboelectric charge is larger per unit volume and weight. In addition, the resin content in the toner increases. For these reasons, the surface of the developer carrying member is more easily contaminated by the toner having high triboelectric charge. This promotes ghost image. U.S. Patent No, 4,989,044 and EPA-0,339,944 disclose a developer carrying member provided with a surface layer comprising carbon black fine particles and fine graphite particles dispersed in a resin binder. This is effective to prevent the ghost image. However, the surface layer is relatively easily peeled off partially, with long term use. The surface layer is worn with the result of poor charging and conveying performance, and therefore, non-uniform toner layer formation. Improvements in this respect is desired, in addition, improvements is desired in the easy production of the desired surface roughness. SUMMARY OF THE INVENTION Accordingly, it is a principal object of the present invention to provide a developing apparatus wherein the fine developer particles are prevented from strongly attach to the developer carrying member, so that good developed images are provided. It is another object of the present invention to provide a developing apparatus wherein triboelectric charging power and and the conveying power can be maintained in long term use, so that the developer carrying member can form a uniform developer layer in long term use. According to an aspect of the present invention, the developer carrying member has a base member having a sand-blast roughened surface having the surface roughness of 1.0-3.0 microns (Ra) and an outer layer applied thereon, comprising a binder resin and fine graphite particles dispersed therein, wherein the average surface roughness is 0.8-2.5 microns (Ra). Since the outer layer is applied on the roughened surface, it is strongly attached to the base, and therefore, not easily peeled off the base, and the change of the surface roughness of the outer layer can be suppressed. In addition, it is easy to provide a desired surface roughness. According to another aspect of the present invention, the surface of such a base member is coated with another binder resin comprising fine particles dispersed therein. The outer layer is further prevented from peeling off, and the change of the surface roughness of the surface can be suppressed. These and other objects, features and advantages of the present invention will become more apparent upon a consideration of the following description of the preferred embodiments of the present invention taken in conjunction with the accompanying drawings. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a sectional view of a developing apparatus according to an embodiment of the present invention. Figure 2 is a sectional view of a developing apparatus according to another embodiment of the present invention. Figure 3 is a sectional view of a developing apparatus according to a further embodiment of the present invention. Figure 4 is an enlarged partial sectional view of a developer carrying member according to an embodiment of the present invention. Figure 5 is an enlarged partial sectional view of a developer carrying member according to another embodiment of the present invention. Figure 6 illustrates a ghost image. DESCRIPTION OF THE PREFERRED EMBODIMENTS Figure 1 is a sectional view of a developing apparatus according to an embodiment of the present invention. The developing apparatus uses a one component magnetic developer to develop an electrostatic latent image on an image bearing member. First, the description will be made as to the one component magnetic developer. Binder resin of a one component magnetic developer used with the embodiments of the present invention may be the following or a mixture of the following polymer of styrene and substitute thereof such as polystyrene and polyvinyltoluene; styrene copolymer such as styrene-propylene copolymer, styrene-vinyltoluene copolymer, styrene-vinylnaphthalene copolymer, styrene-acrylic acid methyl copolymer, styrene-acrylic acid ethyl copolymer, styrene-acrylic acid butyl copolymer, styrene-acrylic acid octyl copolymer, styrene-acrylic acid dimethylaminoethyl copolymer, styrene-methacrylic acid methyl copolymer, styrene-methacrylic acid ethyl copolymer, styrene-methacrylic acid butyl copolymer, styrene-methacrylate dimethylaminoethyl copolymer, styrene-vinylmethylether copolymer, styrene-vinylethylether copolymer, styrene-vinylmethylketone copolymer, styrene-butadiene copolymer, styrene-isoprene copolymer, styrene-maleic acid, styrene-maleic acid ester copolymer; polymethylmethacrylate, polybutylmethacrylate, polyvinylacetate, polyethylene, polypropylene, polyvinylbutyral, polyacrylic acid resin, rosin, modified rosin, turpentine resin, phenolic resin aliphatic hydrocarbon resin, alicyclic hydrocarbon resin, aromatic petroleium resin, paraffin wax, carnauba wax. As for the coloring material added to the magnetic toner, they may be known carbon black, copper phthalocyanine, iron black or the like. The magnetic fine particles contained in the magnetic toner may be of the material magnetizable when placed in a magnetic field, such as ferromagnetic powder of metal such as iron, cobalt and nickel, powder of metal alloy or powder of compound such as magnetite, γ-Fe 2 O 3 and ferrite. The fine magnetic particle preferably has BET specific surface area, obtained by nitrogen absorbing method of 1 - 20 m 2 /g, more particularly 2.5 - 12 m 2 /g, and a Moh's hardness of 5 - 7. The content of the magnetic particles is 10 - 70 % by weight on the basis of the weight of the toner. The toner may contain, as desired, a charge controlling agent, more particularly a negative charge controlling agent such as metallic complex salt of monoazo dye salicylic acid, alkyl salicylic acid, dialkyl salicylic acid or naphthoric acid or the like. Volume resistivity of the toner is preferably not less than 10 10 ohm.cm, further preferably not less than 10 12 ohm.cm from the standpoint of the triboelectric charge retention and the electrostatic image transfer. The volume resistivity here is defined as a value obtained in this method. The toner is caked with a pressure of 100 kg/cm 2 , and an electric field of 10 0 V/cm is applied, and then the current is measured after one minute from the electric field application. The resistivity is obtained from the current and the electric field, and is defined as the volume resistivity. The amount of triboelectric charge of the negatively chargeable toner is preferably -8 µC/g to -20 µC/g. If it is less than -8 µC/g, the image density is low, particularly under the high humidity conditions. If, on the other hand, it exceeds -20 µC/g, the charge of the toner is too high with the result of thin line images, so that the image is poor, particularly under low humidity conditions. The negatively chargeable toner particles are defined in this manner. Under the conditions of 25 °C of the temperature and 50 - 60 % of the relative humidity, 10 g of toner particles are left at rest one night. They are mixed with 90 g of carrier iron powder (for example, EFV 200/300 available from Nihon Teppun Kabushiki Kaisha, Japan) without resin coating and having a major particle size of 200 - 300 mesh under the above conditions, in an aluminum pot having a volume of 200 cm 3 . It is then shaked vertically by hand approximately 50 times. Then, the triboelectric charge amount of the toner particles is measured by a normal blow-off method using aluminum cell having a 400 mesh screen. If the triboelectric charge produced by this method is negative, the toner particles are negatively chargeable toner particles. As for the fine silica particles used for the purpose of increasing the fluidability of the developer, they may be dry silica produced from silica halogen compound by vapor phase oxidation, a dry silica called "fumed silica" or "wet silica" produced from water-glass or the like. However, the dry silica is preferable since the surface and inside thereof contain less silanol group and less residual materials. During the production of the dry silica, metallic halide such as aluminum chloride and titanium chloride together with the silica halide may be used, by which compound fine powder of silica and other metal oxide can be produced. The dry silica includes such material. The fine silica particle has preferably been treated to acquire hydrophobic nature. The method for this treatment may be one of known methods. For example, by the chemical treatment with organic silica compound reactable with, or physically attachable with fine silica particles, the hydrophobic nature is given. As a preferable method, fine silica particles produced by vapor phase oxidation of the silica halide are treated with silane coupling agent, and thereafter or simultaneously therewith, it is treated with an organic silica compound. The degree of the hydrophobic nature of the finally treated fine silica particles is 30 - 80 as a preferable range, since then triboelectric charge distribution of the developer containing such fine silica particles provides discrete and uniform negative electric property. Here, the degree of the hydrophobic nature is measured by titration test of methanol. The methanol titration test is to determine the degree of the hydrophobic nature of the silica fine particles having surfaces of hydrophobic nature. The methanol titration test is performed in this manner. In the water (50 ml) in conical flask having a capacity of 250 ml, 0.2 g of silica fine particles to be tested is added. Methanol is dropped from buret until all of the silica particles are wet. At this time, the liquid in the flask is always stirred by a magnetic stirrer. The end is determined by all of the silica particles becoming in suspended state. The degree of the hydrophobicity is expressed as a percentage of the methanol in the mixture of the methanol and the water. The amount of the silica fine particles to the toner is preferably 0.05 - 3 parts by weight based on by weight of the toner (100 parts), further preferably, it is 0.1 - 2 parts by weight, since then the developer exhibits stabilized charging property. It is preferable that 0.01 - 1 part, by weight based on the weight of the developer, of the silica fine particles are deposited on the surface of the toner particle. The developer may contain, as long as no adverse affect is given, another or other materials, for example, a lubricant such as tetrafluoroethylene resin and zinc stearate, an agent for assisting image fixing (for example, low-molecular-weight polyethylene resin) or an agent for providing electric conductivity such as metal oxide such as tin oxide, or the like. As for the method of producing the toner, the constituting materials are kneaded by a heat-kneader such as heated roll, extruder or other kneader. Then, the product is mechanically pulverized and classified. Alternatively, the materials are dispersed in binder resin liquid, and then it is sprayed and dried. Further alternatively, the desired materials are mixed into the monomeric material constituting the binder resin, and then it is emulsified, and thereafter, polymerized. The description will now be made as to the embodiment of the developing apparatus. Referring to Figure 3, an image bearing member, that is, an electrophotographic photosensitive drum 1 having an electrostatic latent image formed through a known process, in this embodiment, rotates in the direction indicated by an arrow B. A developer carrying member, that is, a developing sleeve 8 in this embodiment, carries a one component magnetic developer 4 supplied from the hopper 3, and rotates in the direction A to carry the developer into a developing zone D where the sleeve 8 and the drum 1 is opposed to each other. In order to magnetically attract and retain the developer on the sleeve 8, a magnet 5 is disposed in the sleeve 8. In order to regulate the thickness of the layer of the developer conveyed to the developing zone D, a regulating blade 2 made of a ferromagnetic metal is opposed to the developing sleeve 8 surface with a gap of 200 - 300 microns. By concentration of magnetic lines of force from a magnetic pole N1 of the magnet 5 onto the blade 2, a thin layer of the magnetic developer is formed on the sleeve 2. In place of the magnetic blade 2, a non-magnetic blade is usable. The thickness of the thin developer layer formed on the sleeve 8 is preferably smaller than the minimum clearance between the sleeve 8 and the drum 1 in the developing zone D. The present invention is particularly effective when used with the above-described type developing device, that is, a non-contact type developing device wherein the layer of the developer has such a thickness. However, the present invention is also applicable to a contact-type developing device wherein the thickness of the developer in the developing zone is larger than the clearance between the sleeve 8 and the drum 1. The following descriptions will be made with respect to the non-contact type developing device for simplicity. The sleeve 8 is supplied with a developing bias voltage from the voltage source 9 so as to transfer the developer from the developer layer carried on the sleeve to the drum 1. If a DC voltage is used for this bias voltage, the voltage applied to the sleeve 8 is preferably between the potential of the image area of the latent image (the area to which the developer is to be deposited, and therefore, to be visualized) and the potential of the background area. In order to increase the image density of the developed image or in order to improve the tone reproducibility, an alternating bias voltage may be applied to the sleeve 8 to form a vibrating electric field in the developing zone D. In this case, it is preferable that the alternating voltage is provided by superimposing an AC voltage with a DC voltage having a level between the image portion potential and the background potential (U.S. Patent No. 4,292,387). In a regular development wherein the toner is deposited to a high potential portion of the latent image constituted by the high potential portion and a low potential portion, the toner used is chargeable to a polarity opposite to the polarity of the latent image, whereas in a reverse-development wherein the toner is deposited to the low potential area of the latent image, the toner used is chargeable to the polarity which is the same as the polarity of the latent image. Here, the high potential and low potential is on the basis of an absolute value of the potential. In any event, the toner is electrically charged by the friction with the sleeve 8 to the polarity for developing the latent image. The added fine silica particles are also electrically charged by the friction with the sleeve 8. Figure 2 shows a developing apparatus according to another embodiment of the present invention, and Figure 3 shows a further embodiment of the present invention. In Figures 2 and 3, the developing apparatus comprises a member for regulating the magnetic toner 4 layer thickness on the developing sleeve 8. The regulating member is of a rubber elastic material such as urethane rubber, silicone rubber or the like or elastic metal such as phosphor bronze, stainless steel or the like. The member is in the form of elastic plate 20 which is press-contacted counterdirectionally to the developing sleeve 8 with respect to the movement direction of the sleeve surface in Figure 2, and codirectionally in Figure 3. With such a structure, the produced toner layer is further thinner. The other structures of the developing apparatus of Figure 2 or Figure 3 are the same as those of Figure 1 apparatus, and therefore, the detailed description thereof is omitted by assigning the same reference numerals as in Figure 1 to the element having the corresponding functions. The developing apparatus of Figures 2 and 3 wherein the toner layer is formed on the developing sleeve 8 is suitable for the use with a one component magnetic developer mainly comprising magnetic toner and a one component magnetic developer mainly comprising non-magnetic toner. In either case, the toner is rubbed between the elastic plate 20 and developing sleeve 8, the toner is sufficiently charged, so that the image quality is improved. This is preferable under the high humidity conditions tending to decrease the triboelectric charge. In this embodiment, the developing sleeve 8 (roller) has a base member 6 comprising a roughened surface having fine pits and projections and has a resin coating 7 in which at least graphite particles are dispersed. The magnetic toner 4 is triboelectrically charged by the resin coating 7 to the polarity suitable to develop the electrostatic latent image. The fine graphite particles are exposed on the resin coating 7. The fine graphite particles are effective to leak the overcharge of the toner, and exhibit good solid lubricating effects so that they are effective to decrease the deposition force of the fine toner particles onto the developing sleeve 8. The base member 6 may be of aluminum, stainless steel, brass or the like roughened by the sand blasting. It may be of metal cylinder 6′ made of aluminum, stainless steel, brass or the like coated with an intermediate layer 6″ comprising a material different from the graphite, preferably hard inorganic fine particles which are dispersed in a resin material different from the resin material of the resin coating 7, preferably a material exhibiting stronger binding force to the cylinder than the binder resin material of the resin coating 7. Figure 4 shows a part of the developing sleeve 8 comprising former base member 6, and Figure 5 shows developing sleeve 8 comprising the latter base member 6. These embodiment will be described. [Embodiment 1] As shown in Figure 4, the surface of the base member 6 is sand-blasted with irregular abrading particles (shape of the particles are irregular, and has plural sharp edges) to provide roughened surface 10. The resin coating 7 is formed on the roughened surface, and developing sleeves No. 2 - 4 are produced according to the embodiment of the present invention. For comparison, sleeve No. 1 Was produced without the sandblasting for the surface. The base member 6 was made of a drawn aluminum alloy (3003), and was sandblasted with alundum particles. The blasting machine used of usual air jet type (Newma blaster, available from Fuji Seisakusho, Japan). The blasting period was 60 sec, and the base member 6 was rotated at 20 rpm. Table 1 below shows the blasting conditions and the average surface roughness (Ra) for the base members Nos. 1 - 4. SLEEVE Nos. 1 2 3 4 BLASTING PARTICLES NON #200 #100 #100 AIR PRESSURE (kg/cm 2 ) 2 2 4 SURFACE ROUGHNESS (Ra) (microns) 0.5 1.0 2.0 3.0 The average surface roughness (Ra) is expressed as a center line average roughness defined in JIS B-0601 (microns). The resin coating 7 was made of resin materials given in Table 2, comprising graphite particles and carbon black particles. They were dispersed in a paint shaker with glass beads for 3 hours into a form of paint. The solid content of the paint was adjusted to be 25 %, and was applied to the surface of the base member 6 to provide the resin coating 7. BINDER RESINS GRAPHITE GRAPHITE SOLVENT PHENOL AVE. SIZE 7 MICRONS AVE. SIZE 0.2 MICRON IPA (ISOPROPYL ALCOHOL) 20 PARTS BY WT. 9 PARTS 1 PARTS 20 PARTS Table 3 shows weight applied on the resin coating 7 and the average surface roughness (Ra) for each of the sleeves Nos. 1 - 4. It is given as roughness (after) together with the surface roughness (before) given in Table 1. SLEEVE Nos. 1 2 3 4 ROUGHNESS (BEFORE) MICRONS 0.5 1.0 2.0 3.0 WEIGHT APPLIED (G/M 2 ) 8.0 8.0 8.0 8.0 ROUGHNESS (AFTER) MICRONS 0.6 1.2 1.8 2.4 The developing sleeves Nos. 1 - 4 were incorporated in the developing apparatus and, image forming operations were performed. The used image forming apparatus was a laser beam printer LBP-SX (available from Canon Kabushiki Kaisha, Japan). Image forming operations were continued for 5000 sheets under normal temperature and humidity conditions. Table 4 below shows the results: SLEEVE Nos. 1 2 3 4 IMAGE DENSITY NG G E G GHOST F G E G DENSITY NON-UNIFORMITY F G E G PEELING NU E E E E:Excellent G:Good F:Practically usable NG: No good NU:Non-usable. The same results as in Table 4 were confirmed under the low temperature and low humidity conditions and under the high temperature and low humidity conditions (5000 sheets). The results will be evaluated. (a) Image Density Only the sleeve No. 1 showed low image density. The Sleeves Nos. 2 - 4 have the base member 6 with properly roughened surface (Ra=1.0-3.0), and therefore, the surface of the resin coating 7 thereon has proper roughness. Thus, the developer conveying force is strong to provide sufficient toner layer. But, the sleeve No. 1 Does not have the above nature because the surface roughness is too small. Table 5 shows Sm value of the sleeve surface (average intervals between pits and projections of the resin surface) together with the surface roughness (before) given in Table 1. SLEEVE NOS. 1 2 3 4 SURFACE ROUGHNESS (BEFORE) 0.5 1.0 2.0 3.0 Sm (MICRONS) 20 30 0 70 From the standpoint of the Sm value, in order to increase the toner coat quantity, it has been found that the proper Sm value is 30 - 70 on the developing sleeve. The average interval Sm is defined in ISO 4287/1-1984, Section 6.4. (b) Ghost and Uniformity of Image Density Sleeves Nos. 1 - 4 are all practically good in the ghost and uniformity of the image density. It has been found that Sleeve No. 3 Is the best. This is because the coating layer functions to properly leak the charge of fine particles and to prevent the formation of the fine particle layer by the solid lubrication. (c) Peeling of the Coat In sleeve No. 1 The peeling was remarkable, but not in the sleeves Nos. 2-4, because of the provision of roughened surface on the surface of the base member 6 which is effective to improve the bonding between itself and coating layer 7. In the foregoing, the base member 6 was made of aluminum, but copper alloy, stainless steel were usable. The surface roughness of the base member 6 is preferably 1.0 - 3.0, as described hereinbefore. The surface roughness of the resin coating 7 on the roughened surface of the base member 6 was preferably 1.2 - 2.4 microns. The inventors have found that Ra=0.8 - 2.5 microns is preferable. [Embodiment 2] As shown in Figure 5, a surface of cylindrical base member 6′ made of drawn aluminum which corresponds to the base member 6 of Table 1, was not blast-treated, and instead, resin layer 6″ comprising titanium oxide as filler material was applied with the following contents: SLEEVE NO. 5 6 7 8 BINDER RESIN (PARTS) 100 100 100 100 TITANIUM OXIDE (PARTS) 100 100 200 200 AVE.PART.SIZE (MICRON) 20 30 20 30 CARBON BLACK (PARTS) 30 30 30 30 AVE.PART.SIZE (M- MICRONS) 50 10 10 10 (PARTS: BY WEIGHT) In the surface of the resin layer 6′′, the fine particle filler is dispersed in the resin, so that finely rough surface 12 is provided. The weight of the application of the intermediate resin layer is 4.0 g/m 2 in the sleeves Nos. 5-8. On the rough surface 12, the resin paint of the composition of the following Table 7 was applied to provide the resin coating 7 as the developing sleeves Nos. 5 - 8. BINDER RESIN GRAPHITE CARBON BLACK SOLVENT PHENOL AVE.PART.SIZE 10 MICRONS AVE.PART.SIZE 0.1 MICRONS METHANOL 20 WT.PARTS 9 WT.PARTS 1 WT.PARTS 20 WT.PARTS Table 8 shows natures of Sleeves Nos. 5 - 8. The weight of the applied coating was 8.0 g/cm 2 for all. SLEEVE NO. 5 6 7 8 SURFACE ROUGHNESS (INT. LAYER) Ra (MICRONS) 0.6 1.0 1.7 2.5 SURFACE ROUGHNESS (OUTER LAYER) (MICRONS) 1.0 1.5 2.0 3.0 OUTER LAYER Sm (MICRONS) 40 50 60 70 The sleeves Nos. 5 - 8 were incorporated in the developing apparatus of the image forming apparatus as in Embodiment 1, and the image forming operation was carried out. The evaluation of the sleeves is as shown in Table 9. SLEEVE NO. 5 6 7 8 IMAGE DENSITY G G E G GHOST G G E G DENSITY UNIFORMITY G G E G PEELING G G E G G: GOOD E: EXCELLENT In the case of resin coating 7 applied on the resin layer 6'', as will be understood from sleeve No. 8, the good results are obtained even if the surface roughness is 3.0 microns (Ra). The reason for this is considered as being that the profile of the surface of the resin coating 7 is different in Figure 5 case than in Figure 4 case. It will be readily understood that sufficient toner conveyance and triboelectric charge when the surface roughness is 1.0 - 3.0 microns. From the standpoint of Sm value, it is preferably 40 - 70 microns to provide good toner conveying power. In Figure 5, it is preferable that the bonding strength between the cylindrical base member 6' and the bonding resin (first resin) for the resin layer 6'' comprising fine particle filler (titanium oxide in Table 6) functioning as a primer for the developing sleeve, is higher than the bonding strength between the cylindrical base member 6′ and bonding resin (second resin) for the outer layer 7, since then the outer layer is not easily peeled off from the sleeve as compared with the case in which the outer layer is directly applied on the cylindrical base member 6′. Since the outer layer and the intermediate layer are made of resin materials, the bonding strength therebetween is high. Therefore, as compared with the case of Figure 4, the outer layer 7 is more surely bonded to the sleeve even if the surface roughness (Ra) of the surface coated with the outer layer 7 is smaller. Since the bonding strength to the cylindrical base member 6′ is enhanced by the first resin constituting the resin layer 6′′, the second resin constituting the outer layer 7 preferably has the hardness higher than the first resin. Then, the wearing of the outer layer 7 is prevented. In order to provide the outer layer 7 with the proper surface roughness Ra, the volume average particle size of the fine particle filler (titanium oxide in Table 6) dispersed in resin layer 6″ is preferably larger than the volume average particle size of the fine graphite particles dispersed in the outer layer 7. In Table 6, ,the carbon black is added in the resin layer 6″ to decrease the electric resistance of the resin layer 6″ as compared with the case wherein only the fine particles filler is dispersed, whereby the overcharge on the toner from the outer layer can be easily leaked to the metal base 6′, and in addition, the effect of the developing bias voltage is enhanced. The surface roughness of the resin layer 6″ is mainly provided by the fine particle filler such as titanium oxide, and therefore, the carbon black fine particles dispersed in the resin layer 6″ preferably has a smaller average particle size. The material usable as the fine particle filler of the resin layer 6″ include silica, potassium titanate, barium titanate or the like as well as the titanium oxide. The volume average particle size of the filler is preferably 1.0 - 20.0 microns. The amount of applied resin layer 6″ to the metal cylindrical base member 6′ is preferably 2 - 8 g/m 2 . In the embodiments of Figures 4 and 5, the resin coating layer 7 contains graphite fine particles and carbon black fine particles (carbon black is contributable to leak the overcharge of the toner 4). It was also effective to contain graphite particles only. The volume average particle size of the graphite particles was preferably 0.5 - 15 microns, and that of the graphite particles was preferably 5 - 300 microns. Since the graphite particles also functions as the solid lubricant, the average particle size is preferably larger than the carbon black particles. The ratio of the resin to graphite particles plus carbon black in the outer layer 7 was preferably 1/1 - 3/1 by weight. The amount of resin layer 7 was 8.0 mg/m 2 . The preferable range is 4 - 12 mg/ 2 . The resin binder used in the foregoing example was phenol, but other usable resins include epoxy resin, melamine resin, polyamide resin, silicone resin, polytetrafluoroethylene resin, polyvinylchloride resin, polycarbonate resin, polystyrene resin, polymetacrylate resin or the like. The materials for the binder resin for the resin layer 6″ include phenol resin, teflon, epoxy resin, melamine resin, urea resin and the like as well as the polyester resin shown in Table 6. The resin materials of the resin layer 6″ and the resin coating 7 preferably satisfy the above described natures in connection with one another. When the resin layer 6″ contains the carbon black fine particles in addition to the fine particle filler, the volume average particle size of the carbon black fine particles is preferably 5 - 300 microns. The ratio (weight) of the resin to fine particle filler plus carbon black was preferably 1/5 - 3/1. The present invention is applicable to a developing apparatus using a one component non-magnetic developer. In such a case, the magnet 5 is not necessary in Figures 1 - 3. According to the present invention, the ghost image is effectively prevented, and therefore, it is particularly effective to the developing apparatus using one component developer containing file particle toner having an average particle size of 4 - 9 microns. When an electrostatic latent image is developed using developer particles triboelectrically charged by the developing sleeve (roller) surface, the minimum clearance between the developing sleeve and the latent image bearing member in the developing zone is preferably 50 - 500 microns. While the invention has been described with reference to the structures disclosed herein, it is not confined to the details set forth and this application is intended to cover such modifications or changes as may come within the purposes of the improvements or the scope of the following claims.

Claims: A developing apparatus for developing an electrostatic latent image, comprising: a movable developer carrying member (5, 6, 7, 8) for carrying one component developer to a developing zone where said developer carrying member (5, 6, 7, 8) is opposed to a latent image bearing member (1) for carrying the electrostatic latent image, said developer carrying member (5, 6, 7, 8) being effective to triboelectrically charge the developer to a polarity for developing the latent image; a regulating member (20) for regulating a thickness of a layer of the developer to be carried to the developing zone; a voltage source (9) for applying a developing bias voltage to said developer carrying member (5, 6, 7, 8); wherein said developer carrying member (5, 6, 7, 8) comprises a base member (6) and an outer layer (7) thereon in which fine graphite particles are dispersed in a binder resin material, characterized in that said base member (7) has a surface sandblasted to have an average surface roughness of 1.0 - 3.0 microns, and in that said outer layer (7) has an average surface roughness of 0.8 - 2.5 microns. An apparatus according to Claim 1, wherein the binder resin of said outer layer (7) contains fine carbon black particles dispersed therein. An apparatus according to Claim 2, wherein 4 - 12 g of said outer layer is applied on said base member (6) per unit area (m 2 ). An apparatus according to Claim 2, wherein an average spacing between pits and projections on a surface of said outer layer is 30 - 70 microns. An apparatus according to any one of Claims 1 - 4, wherein said base member (6) is of a metal roller sandblasted with irregular particles. An apparatus according to any one of Claims 1 - 4, wherein said voltage source (9) applies an oscillating bias voltage to said developer carrying member (5, 6, 7, 8). An apparatus according to Claim 6, wherein said regulating member (20) regulates the thickness so that the thickness is smaller in the developing zone (D) than a clearance between said developer carrying member (5, 6, 7, 8) and the image bearing member (1). A developing roller (5, 6, 7, 8) for triboelectrically charging a one component developer to a polarity for developing an electrostatic latent image and for supplying the developer to an electrostatic latent image bearing member (1), comprising: a base roller (6) having a sandblasted surface and an outer layer (7) on said base roller comprising fine graphite particles dispersed in a resin binder, characterized in that said sand blasted surface has a surface roughness of 1.0 - 3.0 microns; and in that said outer layer (7) has an average surface roughness of 0.8 - 2.5 microns. A roller according to Claim 8, wherein the binder resin of said outer layer (7) contains fine carbon black particles dispersed therein. A roller according to Claim 9, wherein 4 - 12 g of said outer layer is applied on said base roller (6) per unit area (m 2 ). A roller according to Claim 10, wherein an average spacing between pits and projections on a surface of said outer layer is 30 - 70 microns. A roller according to any one of Claims 8 - 11, wherein said base roller (6) is of a metal roller sandblasted with irregular particles. A method for developing an electrostatic latent image which comprises applying a developer to the image by means of apparatus as claimed in any of claims 1 to 7 or by means of a developing roller as claimed in any of claims 8 to 12.

Inventors: ARAHIRA FUMIHIRO, HASEGAWA HIROTO, UNNO AKIRA, ARAHIRA, FUMIHIRO, HASEGAWA, HIROTO, UNNO, AKIRA, ARAHIRA, FUMIHIRO, CANON KABUSHIKI KAISHA, HASEGAWA, HIROTO, CANON KABUSHIKI KAISHA, UNNO, AKIRA, CANON KABUSHIKI KAISHA
Applicants: CANON KK, CANON KABUSHIKI KAISHA
Application year: 1991
Main classification: G03G15
IPC codes: G03G15