Electret filters

Abstract: An electret filter made of a resin whose angle of contact upon wetting with pure water is no smaller than 95 degrees, as well as an electret filter made of a resin whose angle of contact upon wetting with pure water has been adjusted to no smaller than 95 degrees by addition of silicone oil. Those electret filters have high trapping efficiency and their ability to trap particulates, especially cigarette smoke, will not deteriorate even if they are continuously used. Therefore, they can advantageously be used as filter media in many applications such as home and industrial air conditioners, air cleaners, fan heaters, vacuum cleaners, and air conditioning systems for common equipment.

Description: BACKGROUND OF THE INVENTION This invention relates to electret filters, more particularly, to electret filters that have high trapping capability, with the added advantage that their ability to trap cigarette smoke is retained in a consistent manner. Electret filters are used as filter media in many applications such as home and industrial air conditioners, air cleaners, vacuum cleaners, fan heaters and air conditioning systems for common equipment to clean ambient atmospheres by trapping the dust, smoke and other particulate contaminants. Such electret filters are conventionally prepared from nonwoven fabrics of polymers such as polypropylene by processing them into electrets. For example, FR-A-2357998 describes a method of preparing electret tapes made of various polymers such as polyethyleneterephthalate. However, the conventional electret filters have had the problem that they are not highly suitable for adsorbing cigarette smoke since their ability to trap it will drop markedly with the amount of adsorption and cannot be retained in a consistent manner. SUMMARY OF THE INVENTION The present invention has been achieved under these circumstances and has as an object providing an electret filter whose ability to trap particulates, especially cigarette smoke, will not deteriorate even if it is continuously used and which hence is capable of retaining the satisfactory trapping performance in a consistent manner. Having this advantage, the electret filter of the present invention is suitable for use as a filter medium in air conditioners, air cleaners and other applications. Cigarette smoke as suspended matter in air consists of liquid particles. When such liquid smoke particles are deposited on the surface of a filter, they cover the fibrous surfaces of the filter and interfere with the action of electric charges that have been formed on the surface of the filter as a result of processing into an electret. This would probably contribute to a sudden drop in the ability of the electret filter to trap cigarette smoke. Under the circumstances, the present inventor conducted intensive studies in order to obtain a filter which, unlike the conventional filters, would not experience a sudden drop in its ability to trap cigarette smoke. As a result, the present inventor found that this object can be achieved by an electret filter that is made of a resin whose angle of contact upon wetting with pure water has been adjusted to no smaller than 95 degrees by addition of silicone oil. In a preferred embodiment, the silicone oil may be added in an amount of 0.05-5 wt%. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a diagram illustrating the liquid droplet method for measuring the angle of contact upon wetting with pure water; Fig. 2 is a diagram showing schematically the apparatus used to test the cigarette smoke adsorbing capability of the filter samples prepared in Examples 1-13 and Comparative Examples 1-5; and Fig. 3 is a diagram showing schematically the apparatus used to measure the trapping efficiency of those filter samples. DESCRIPTION OF THE PREFERRED EMBODIMENT The present invention is described below in detail. The resins of which the electret filter of the present invention can be made are not limited to any particular types. The resins of the present invention are those whose angle of contact upon wetting with pure water is less than 95 degrees. Examples of such resins include homo-polypropylene, polyethyleneterephthalate, polymethacrylate, polycarbonate, etc. Such resins can be effectively used if their angle of contact upon wetting with pure water is adjusted to at least 95 degrees by addition of silicone oil. To this end, silicone is added in an amount of 0.05-5 wt%, preferably in the range of 0.1-1.0 wt%. Examples of useful silicone oil are dimethyl siloxane based silicone oil, methylhydrogen polysiloxane based silicone oil, amino-modified silicone oil, epoxy-modified silicone oil, and carboxy-modified silicone oil. If the addition of silicon oil is less than 0.05 wt%, its intended effect will not be achieved. If the addition of silicone oil exceeds 5 wt%, the film forming property of the blend deteriorates and the production rate of electret filters will decrease drastically. The voltage to be applied for electrification are variable with such factors as the shape of electrodes and the distance between electrodes. If the inter-electrode distance is 8 mm, a voltage of at least 5 kV, preferably 6-10 kV, may be applied to the specimen. Charges may be applied in various ways such as, for example, passing the specimen between a pair of electrodes under DC voltage, applying corona discharge or a pulsed high voltage to the surface of the specimen, applying a DC high voltage to both surfaces of the specimen as they are retained by a suitable dielectric material, and applying voltage to the specimen under illumination with light. The thickness of the electret filter of the present invention may be selected as appropriate for such factors as the intended use and the required trapping performance. Usually, the filter has a thickness that generally ranges from ca. 10 to ca. 300 g/m 2 , preferably from ca. 20 to ca. 150 g/m 2 . The amount of electric charges to be possessed by the electret filter of the present invention can also be adjusted as appropriate for the intended use and other factors; usually, the filter has electric charges of ca. 10-50 x 10 -9 C/cm 2 . The angle of contact, upon wetting with pure water, of the resin from which the electret filter is made can be measured by the liquid droplet method as depicted in Fig. 1; with the aid of an angle plate and a movable cross within an optical mirror, the apex 13 of a droplet of pure water 12 on a resin sheet 11 is determined graphically and the value of /2 is read directly; that angle is doubled to determine the contact angle  which the resin sheet 11 forms with the line 14 which is tangent to the droplet 12. The following examples are provided for the purpose of further illustrating the present invention but are in no way to be taken as limiting. EXAMPLES Filter Production The electrificated fibers were cut to a shorter length of 90 mm and made fluffy with an opening card. The fluffy fibers were supplied into a web forming machine and shaped into a web. The web was then needle-punched with a machine of Feller, Inc. to prepare an electret filter sample (30 x 30 cm) having an aerial density of 100 g/m 2 and a thickness of 2 mm. This filter sample was subjected to cigarette smoke adsorption test in the manner described below and, after adsorbing the smoke of 10 or 20 cigarettes, the percent retention of the smoke trapping efficiency was determined. The results are shown in Table 1. Cigarette Smoke Adsorption Test The test apparatus had the layout shown in Fig. 2; it consisted of a box 1 (capacity: 1 m 3 ) containing an aspirator 3 fitted with a filter sample 2 (150 mm x 150 mm). A predetermined number of cigarettes was puffed within the box 1 to fill it with the cigarette smoke. At the same time, the aspirator 3 was activated so as to trap the cigarette smoke with the filter sample 2 at an aerial velocity of 0.5 m/sec until the dust density in the box 1 increased to 0.1 mg/m 3 as measured with a digital dust meter 4 (P5H of Sibata Scientific Technology, Ltd.) The trapping efficiency of the filter sample 2 was measured by the following method both before and after the adsorption of cigarette smoke, and the percent retention of the trapping efficiency was calculated as E 1 /E 0 x 100 (%) , where E 0 is the efficiency before the adsorption and E 1 is the efficiency after the adsorption. Measuring The Trapping Efficiency The basic layout of the apparatus for measurement is shown in Fig. 3. Sodium chloride (NaCl) particles (size: 0.3 µm) 5 as produced with an aerosol generator (Nihon Kagaku-Kogyo K.K., not shown) were supplied into a chamber 6 with clean air being used as a carrier. When the concentration of NaCl in the chamber 6 leveled off at 2-6 x 10 6 /cm 3 , vacuum was drawn by means of an aspirator (not shown) in the direction of arrow A through a filter sample 7 placed on the bottom of the chamber 6. When the velocity of air passing through the filter became constant (v=50 cm/sec), the concentrations of NaCl particles, C IN and C OUT , at the positions upstream 8 and downstream 9, respectively, of the filter sample 7 were measured with a particle counter (KC-01B5 of Rion Co., Ltd.) and its trapping efficiency E was calculated by the following formula: E = (1 - C OUT C IN ) x 100 (%) Comparative Example 1-5 Filter samples were prepared as above using inflated films of homopolypropylene (melt index as measured by ASTM D1238-65T: 0.5), polyethylene terephthalate (PET), polymethyl methacrylate (PMMA), polycarbonate (PC) and a composition consisting of polypropylene/meleic anhydride modified polypropylene/polycarbonate (90/5/5 in wt%), which had angles of contact upon wetting with pure water as listed in Table 1. Those samples were subjected to a cigarette smoke adsorption test and the percent retention of their trapping efficiency was determined as above. The results are shown in Table 1. Example 1 Polypropylene (MFR by ASTM D 1238: 0.5 g/10 min, density: 0.91 g/cc; homopolypropylene B200 of Mitsui Petrochemical Industries, Ltd.) 90% Maleic anhydride modified polypropylene (GR-2 of Mitsui Petrochemical Industries, Ltd., not available on the market) 5% Polycarbonate (Lexan #101 of General Electret Inc.) 5% Dimethyl siloxane (SH-200 of Toray Silicone Co., Ltd.) 0.1 part by weight A mixture having this formula was fed into a uniaxial extruder (screw dia. : 40 mm), where it was melted, mixed and shaped into pellets. A film produced from the pellets was used. This filter sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. In comparison with Comparative Example 5, addition of dimethyl siloxane changed up the angle of contact upon wetting with pure water from 89 degrees to 97 degrees, resulting in improvement of the trapping efficiency from 30%, 19% in Comparative Example 5 to 46%, 32% in Example 1. Example 2 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Dimethyl siloxane (SH-200 of Toray Silicone Co., Ltd.) 0.3 part by weight A filter sample was prepared from a mixture of this formula repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of this trapping efficiency was determined. The results are shown in Table 1. Example 3 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Dimethyl siloxane (SH-200 of Toray Silicone Co., Ltd.) 0.5 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. Example 4 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Dimethyl siloxane (SH-200 of Toray Silicone Co., Ltd.) 1.0 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. Example 5 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Epoxy-modified silicone oil (SF-8413 of Toray Silicone Co., Ltd.) 0.1 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. Example 6 Polypropylene (homopolypropylene with ASTM D 1238 MRF of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Epoxy-modified silicone oil (SF-8413 of Tray Silicone Co., Ltd.) 0.3 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. Example 7 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Amino-modified silicone oil (SF-8417 of Toray Silicone Co., Ltd.) 0.1 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. Example 8 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Amino-modified silicone oil (SF-8417 of Toray Silicone Co., Ltd.) 0.3 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1 Example 9 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Carboxy-modified silicone oil (SF-8418 of Toray Silicone Co., Ltd.) 0.1 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. Example 10 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Carboxy-modified silicone oil (SF-8418 of Toray Silicone Co., Ltd.) 0.3 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. Example 11 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Carboxy-modified silicone oil (SF-8418 of Toray Silicone Co., Ltd.) 0.5 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. Example 12 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Fluorine-modified silicone oil (FS-1265 of Toray Silicone Co., Ltd.) 0.1 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. Example 13 Polypropylene (homopolypropylene with ASTM D 1238 MFR of 0.5 g/10 min and a density of 0.91 g/cc) 90% Maleic anhydride modified polypropylene 5% Polycarbonate 5% Fluorine-modified silicone oil (FS-1265 of Toray Silicone Co., Ltd.) 0.3 part by weight A filter sample was prepared from a mixture of this formula by repeating the procedure above. The sample was subjected to a cigarette smoke adsorption test as above and the percent retention of its trapping efficiency was determined. The results are shown in Table 1. Sample No. Angle of contact upon wetting with pure water,  (°) Retention of trapping efficiency (%) 10 cigarettes 20 cigarettes 1 97 46 32 2 99 51 37 3 103 55 42 4 103 57 45 5 95 45 31 6 97 48 37 7 96 46 31 8 99 50 41 9 96 44 30 10 100 52 42 11 102 54 41 12 96 43 32 13 101 49 41 1 88 27 16 2 71 23 12 3 66 20 11 4 83 24 13 5 89 30 19 The electret filter of the present invention has high trapping efficiency and its ability to trap particulates, especially cigarette smoke, will not deteriorate even if it is continuously used. Therefore, it can advantageously be used as a filter medium in many applications such as home and industrial air conditioners, air cleaners, fan heaters, vacuum cleaners, and air conditioning systems for common equipment.

Claims: An electret filter made of a material having an angle of contact upon wetting with pure water no smaller than 95 degrees, which material is a mixture of a resin whose angle of contact upon wetting with pure water is smaller than 95 degrees and a silicone oil. An electret filter according to claim 1 wherein said resin is propylene homopolymer, polyethyleneterephthalate, polymethacrylate or polycarbonate. An electret filter according to claim 1 or 2 wherein said mixture contains 0.05 to 5 wt% silicone oil. An electret filter according to claim 3 wherein said mixture contains 0.1 to 1.0 wt% silicone oil.

Inventors: KISHIBA TSUNEO, MATSUURA SATOSHI, SHINAGAWA YOSHIO, KISHIBA, TSUNEO, MATSUURA, SATOSHI, SHINAGAWA, YOSHIO, KISHIBA, TSUNEO, C/O MITSUI PETROCHEM. IND., LTD, MATSUURA, SATOSHI, C/O MITSUI PETROCHEM. IND., LTD, SHINAGAWA, YOSHIO, C/O MITSUI PETROCHEM. IND., LTD
Applicants: MITSUI CHEMICALS INC, MITSUI CHEMICALS, INC.
Application year: 1991
Main classification: B03C3
IPC codes: B01D39, B03C3