Cosmetic formulations

Abstract: Conventionally, polyether pendant dimethyl polysiloxane and linear polyether-polysiloxane-polyether block copolymer have been frequently proposed and dominantly used in cosmetic formulations. In this invention, non-hydrolyzing block copolymers comprising a linear polysiloxane-polyoxyalkylene block as a repeating unit are used as a main component of cosmetic formulations used in skin care products and hair care products.

Description: This invention relates to cosmetic formulations comprising a specific polysiloxane-polyoxyalkylene copolymer. More specifically, this invention relates to cosmetic formulations useful in skin care and hair care products which are characterized by comprising a non-hydrolyzing block copolymer having as a repeating unit a linear polysiloxane-polyoxyalkylene block. There are many kinds of skin care products for different purposes, such as cleansing cream, cold cream, hand cream, powder, lotion, foundation, mascara, eye shadow, lipstick, manicure, anti-sunburn cream, etc. It is necessary that they have clean impression, good touch, good application, no makeup destruction, durability and retention, but easy removability from the skin when washed by face washing cosmetics, water or the like. Some of these properties are incompatible with each other. Skin care products having most or all of these properties are desired. As main components of these skin care products, liquid paraffin, paraffin wax, aliphatic acid, higher alcohol, animal fats and oils, and vegetable oils, synthetic esters, polyalkyleneglycol derivatives, silicone compounds, etc. are used. Silicone compounds have been noted because of their special properties, e.g., durability, water resistance, affinity with the skin, moisture retention, gloss imparting property, water repellency, flexibility, vapor permeability, gas permeability, film forming property, filler retaining property, lubricity, etc., and applications of various silicon compounds to skin care products have been proposed. What has been proposed, for example, includes dialkylpolysiloxane (JP-A-119036/1979), amino group-containing polysiloxane (JP-A-58605/1982), pendant polysiloxane-polyoxyalkylene copolymer (JP-A-131910/1983 and JP-A-197432/1984), silicone resin (JP-A-298518/1987), esterified polysiloxane (JP-A-150288/1988), dimethyl cyclopolysiloxane (JP-A-159489/1988), etc. Polysiloxanes having no hydrophilic groups are difficult to solvate in water-based solvents, and large amounts of emulsifying agents are needed which can impair the transparency of the emulsified liquids, irritate the skin, and lower water resistance. A disadvantage of the amino groups containing polysiloxanes is their tendency to yellow. A number of polyoxyalkylene group pendant dialkylpolysiloxanes have been proposed, but they have insufficient water resistance, retention, skin touch, gloss, etc. Silicone resin requires the use of low molecular weight cyclosiloxanes and isopentane, or other solvents, and its use is limited. Esterified polysiloxanes can have improved properties, but are considerably higher in cost. Accordingly, skin care products comprising cosmetic formulations which do not have the disadvantages of the conventional silicone compounds as described above, but retain the desired properties of water resistance, durability, retention, skin touch and gloss are desired. Hair is washed by shampoo, treated with rinse, protected by hair dressing, mousse and set by hair spray. In some cases, permanent liquid and hair dye are used. Compositions used for hair treatment contain cosmetic formulations and are often blended with vegetable oil, animal oil, mineral oil, synthetic oil, etc. to form hair care products. With the recent progress of silicone polymer technology, various polysiloxane polymers have been blended as main components of cosmetic formulations used in hair care products because of their desirable characteristics. Such hair care products are exemplified by: shampoos containing dimethyl silicone, diethyl silicone, methylphenyl silicone, to give rinse effect (US-A-2,826,551); a hair cosmetic containing a diol derivative or branched aliphatic alcohol and methyl polysiloxane (JP-A-47923/1977); a conditioning lotion containing vinyl pyrrolidone-silicone copolymer (JP-A 57337/1977); a cosmetic containing quarternary nitrogen-content cationic modified silicone (JP-A-66506/1980); a hair treatment composition comprising an anionic polymer compound, a cationic surfactant and oxyalkylene modified organopolysiloxane (JP-A-108811/1980); a hair conditioner composition comprising polyoxyalkylene modified organopolysiloxane and water-containing ethanol or absolute ethanol (JP-A-136214/1980); a hair cosmetic comprising water, ethanol, a phosphoric ester salt of polyoxypropylene multivalent-alcohol ether and polyoxyalkylene methylpolysiloxane (JP-A-16405/1981); a hair cosmetic containing organosiloxane polyoxyalkylene copolymer (JP-A-22712/1981); a hair conditioner composition comprising polysiloxane containing aminoalkyl groups and hydroxy groups, a cationic polymer and an aqueous carrier (JP-A-45406/1981); a shampoo composition comprising an anionic surface active agent, a cationic polymer and a silicone derivative (dimethyl polysiloxane, methylphenyl polysiloxane, polyether modified silicone oil, epoxy modified silicone oil, fluorine modified silicone oil, alcohol-modified silicone oil and alkyl-modified silicone oil) (JP-A-72095/1981); a hair cosmetic comprising an olefin liquid polymer, dimethyl polysiloxane, a polymeric chain emulsifying agent and water (JP-A-86113/1981); a hair cosmetic comprising quarternary ammonium salt, higher alcohol, and hydrophobic silicone (JP-A-92808/1981); an amphoteric acrylic resin, polyoxyalkylene modified organopolysiloxane, and polyethylene glycol (JP-A-92811/1981); a hair conditioner comprising as the main component organopolysiloxane having at least one aminoalkyl group, and at least one oxyalkylene group, polyoxyalkylene or hydroxyalkyl group (JP-A-74602/1983); a cosmetic containing an amphoteric silicone oil and polyoxyalkylene-modified polysiloxane (JP-A-1262O9/1985); a hair conditioning composition comprising a silicone conditioner, dimethyl silicone copolymer, a lipid vehicle formulation, a cationic surface active agent vehicle formulation and water (JP-A-6/1986); a hair coloring composition comprising a coloring agent component, silicone oil and water (JP-A-83111/1986); and a hair cosmetic comprising an organosilicon resin and volatile hydrocarbon oil (JP-A-158914/1986). Hair care products which contain dimethyl polysiloxane as one component often have problems in that the dimethyl polysiloxane does not solvate in aqueous solvents, and therefore, large amounts of emulsifying agents are needed which can impair the transparency of the emulsified liquids, irritate the skin, and degrade their water resistance after being applied to the hair. In addition, dimethyl polysiloxane tends to generate static which tends to attract dust and grime and cause the hair fly phenomenon. The polysiloxanes having aminoalkyl group and/or quarternary nitrogen-containing groups are considerably improved in antistatic effect, water resistance and durability, but do not have all these properties. A number of hair care products containing dimethyl polysiloxane having polyoxyalkylene groups have been proposed, and they have succeeded in preventing the generation of static, but their water resistance, combability, bulky finish, emulsification, foaming are not sufficient. Accordingly, hair care products comprising cosmetic formulations which reduce the disadvantages of the conventional dimethyl polysiloxane or various functional groups containing polysiloxanes and retain the desired hair antistatic effect, moisture retaining effect, combing, brilliant finish, voluminous finish, bulky finish, wetty finish, emulsification effect and foaming effect are desired. EP-A-150 603 describes organo-siloxane-polyoxyalkylene block copolymers for use in personal care compositions. Said block copolymers are prepared by reacting an organohydrogen polysiloxane with an olefinically substituted polyoxyalkylene reactant both of which can be selected from linear, branched and/or cyclic structures. All of the block copolymers specifically described in said document are polysiloxanes having pendant polyoxyalkylene units. EP-A-331 833 and Patent Abstracts of Japan, Vol. 13, No. 427(C-639)[3775] and JP-A-1-163113 disclose (hair) cosmetic compositions comprising polysiloxanes having pendant polyoxyalkylene groups and/or block copolymers of the structure BAB wherein A represents a polysiloxane block and the units B represent polyoxyalkylene blocks. By this invention cosmetic formulations comprising a non-hydrolyzing block copolymer having a linear polysiloxane-polyoxyalkylene block as a repeating unit are provided which are suitable for use in skin care products and hair care products. Preferably, the block copolymer used in this invention is expressed by the general formula: ([Y(R₂SiO) a R₂SiYO][(C n H 2n O) b ]) c wherein: R represents a monovalent hydrocarbon radical containing substantially no unsaturated aliphatic series; n is an integer of 2 - 4; b is an integer of at least 4; c is an integer of at least 4; a is an integer of at least 5; Y represents a divalent organic group which is bonded with an adjacent silicon atom by a carbon-silicon linkage and with a polyoxyalkylene block by an oxygen atom; the average molecular weight of each siloxane block is 400 - 10,000; the average molecular weight of each polyoxyalkylene block is 300 - 10,000; the siloxane blocks are 10 - 90 weight % of the block copolymer; and the block copolymer has an average molecular weight of at least 3,000. Preferably the cosmetic formulation of the present invention contains said block copolymer in an amount of from 1 to 37 weight percent. It is also preferred that said block copolymer has an average molecular weight of at least 30,000. The cosmetic formulations of the present invention, when used in skin care products, can provide advantages in at least one of the following properties; smooth touch when applied to the skin, non-tackiness, wetness, brilliance, durability on the skin and retention of the beneficial effect of the other components. The cosmetic formulations of the present invention, when used in hair care products can provide advantages in at least one of the following properties; combing, smoothness, wetness, flexibility, brilliance, bulkiness, coating effect, durability, tackiness, texture, emulsification effect, hair fly, dust attraction and moisture retention. The R and R' in the above-described formulas are selected from alkyl, e.g., methyl, ethyl, propyl, isopropyl, butyl, pentyl, hexyl, octyl, decyl, dodecyl, octadecyl, eicocyl, etc., aryl, e.g., phenyl, naphthyl, etc., aralkyl, e.g. , benzyl, phenylethyl, etc., tolyl, xylyl, and cyclohexyl, and can be the same or different. The divalent organic group represented by Y in the above-described formula is exemplified by: -R''-, -R''-CO-, -R''-NHCO-, -R''-NHCONH-R'''-NHCO-, -R''-OCONH-R'''-NHCO- where R'' is a divalent alkylene group, e.g., ethylene, propylene, butylene, and R''' is a divalent alkylene group, e.g., R'' or a divalent arylene group exemplified by: -C₆H₄-, -C₆H₄-C₆H₄-, -C₆H₄-CH₂-C₆H₄-, -C₆H₄-C(CH₃)₂-C₆H₄- and preferably R''' is a phenylene group. More preferable examples of the divalent organic group are: -CH₂CH₂-, -CH₂CH₂CH₂-, -CH₂CH₂CH₂CH₂-, -(CH₂)₂CO-, -(CH₂)₃NHCO-, -(CH₂)₃NHCONHC₆H₄NHCO-, and -(CH₂)₃OCONHC₆H₄NHCO-. Most preferably, Y is a divalent alkylene group, specifically -CH₂CH₂CH₂-. The non-hydrolyzing copolymer can be produced by reacting a polyoxyalkylene compound having reactive end groups with dihydrocarbyl siloxane liquid having end groups which are reactive with the end groups of the polyoxyalkylene compound. The nature of these reactive end groups determines the structure of the divalent organic group represented by Y. Generally the nature of the end groups of a reaction product depends on the end groups of reactive substances. Such reactions are expressed by the following reaction formulas: wCH₂=CHCH₂O(C n H 2n O) b CH₂CH=CH + wHSiMe₂O(SiMe₂O) a SiMe₂H ―> [(CH₂)₃O(C n H 2n O) b (CH₂)₃― SiMe₂O(SiMe₂O) a SiMe₂] c wCH₂=CHO(C n H 2n O) b CH=CH₂ + wHSiMe₂O(SiMe₂O) a SiMe₂H ―> [(CH₂)₂O(C n H 2n O) b - (CH₂)₂(SiMe₂O) a SiMe₂] c wHO(C n H 2n O) b H + wOCN(CH₂)₃― SiMe₂O(SiMe₂O) a SiMe₂(CH₂)₃NCO ―> [(C n H 2n O) b CONH(CH₂)₃SiMe₂O― (SiMe₂O) a SiMe₂(CH₂)₃NHCOO] c wHO(C n H₂nO) b H + wClOC(CH₂)₂ - SiMe₂O(SiMe₂O) a SiMe₂(CH₂)₂-COCl ―> [(C n H 2n O) b CO(CH₂)₂SiMe₂O(SiMe₂O) a - SiMe₂(CH₂)₂COO] c +2CHCl wOCNC₆H₄NHCOO(C n H 2n O) b CONHC₆H₄NCO + wH₂N (CH₂)₃SiMe₂O(SiMe₂O) a SiMe₂(CH₂)₃NH₂―> [CONHC₆H₄NHCOO(CnH₂nO) b CONHC₆H₄― NHCONH(CH₂)₃SiMe₂ O(SiMe₂O) a SiMe₂(CH₂)₃NH] c wOCNC₆H₄NHCOO(C n H 2n O) b CONHC₆H₄NCO + wHO(CH₂)₃SiMe₂O(SiMe₂O) a SiMe₂(CH₂)₃OH―> [CONHC₆H₄NHCOO(CnH₂nO) b CONHC₆H₄ NHCOO(CH₂)₃-SiMe₂O(SiMe₂O) a SiMe₂(CH₂)₃O] c In these formulas, the polyoxyalkylene block includes polyoxyethylene, polyoxypropylene, polyoxybutylene, mixed polyoxyethylene/oxypropylene, etc. The most preferable example is the block copolymer which is produced by reacting a polyoxyalkylene compound having CH₂=C(CH₃)-CH₂- groups on both ends with dimethylpolysiloxane having HSi(CH₃)₂O- groups on both ends, and expressed by the formula; where; Me represents a methyl group; n is an integer of 2 - 4; a is an integer of at least 4; b is an integer of at least 4; and c is an integer of at least 4. The block copolymer used in the cosmetic formulations of this invention is used singly or solvated in various organic solvents, e.g., ethanol, isopropyl alcohol, ethylene glycol, propylene glycol, pentane, hexane, octane, nonane, decane, etc. Hair and skin care products can be prepared by blending the cosmetic formulations of this invention with known personal care ingredients, such as: an oil which is used as a component of the usual hair cosmetics, e.g., camellia oil, rapeseed oil, sesame oil, safflower oil, cottonseed oil, castor oil, soybean oil, coconut oil, palm oil, beewax, montanic wax, lanolin, squalane or silicone oil; a surface active agent, e.g., alkyl benzenesulfonate, polyoxyalkylene alkylsulfate ester, alkylsulfate ester, alkanesulfonate, alkyl ethoxycarboxylate, succinic derivatives, alkylamine oxide, imidazoline compounds, polyoxyethylene alkyl or alkenyl ether, polyoxyethylene alkyl phenyl ether, higher fatty acid alkanolamide or its alkylene oxide addition products; high-molecular weight compounds, e.g., cellulosic compounds, such as, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, methyl cellulose, cationic cellulose, cationic polymers, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymer, vinylpyrrolidone-vinyl acetate-alkyl aminoacrylate copolymer, lower alkyl half ester of methyl vinyl ether-maleic anhydride copolymer, vinyl acetate-crotonic acid copolymer, acrylic acid-acrylic ester-N-alkyl acrylamide copolymer; a moisture retaining agent, e.g., glycerol, ethylene glycols, propylene glycols, sorbitol, maltitol, pyrrolidone sodium carboxylate, polyoxyethylene methylglycoside, polyoxypropylene methylglycoside, glycol; an amino acid, e.g., glycine, serine, proline; a powder, e.g., (sericite, silica-alumina, silica gel, kaolin, talc, red iron oxide, ultramarine, mica, mica titanium, magnesium oxide, chromium oxide, antimony oxide, zinc monoxide, zinc dioxide, magnesium carbonate, calcium carbonate, calcium phosphate, barium sulfate, aluminum hydroxide, chromium hydroxide, magnesium metasilicate aluminate, magnesium silicate aluminate, polyethylene powder); and antioxidants, UV absorbers, perfumes, dyes, pigments, coloring matters, preservatives, vitamins, hormones, deodorants, binders, extinguishing agents etc. In the case the cosmetic formulations of this invention are used in aerosol-type sprays, a pressurizing agent, e.g., propane, butane, trichloromonofluoromethane, dichloro-difluoromethane, dichlorotetrafluoroethane, carbon dioxide or nitrogen gas, may additionally be present in the formulation. Typical examples of the use of the cosmetic formulations of this invention in the hair care products formulations include shampoo, rinse, hair lotion, hair oil, hair cream, pomade, hair spray, setting lotion, permanent wave liquid, mousse, dye, shaving foam, etc. The hair cosmetic formulations are suitable for use on the hair, beard, underarm hair, chest hair, artificial hair, as of wigs, etc., hair and features of pets, e.g., dogs, cats, monkeys, macaws, canaries, etc. When the cosmetic formulations are used in hair care products, these resultant cosmetics are superior to the conventional hair cosmetics in combing, smoothness, wetness, flexibility, brilliance, voluminousness (bulkiness), coating effect, durability, tackiness, texture, emulsification effect, hair fly, dust attraction, moisture retention, etc. Typical examples of the use of these cosmetic formulations of this invention in skin care products include cleansing cream, cold cream, hand cream, powder, lotion, foundation, mascara, eye shadow, lipstick, manicure, anti-sunburn creams etc. When these cosmetic formulations are used in skin care products, the resultant cosmetics are superior to the conventional ones in smooth touch when applied to the skin, non-tackiness, wetness, brilliance, durability on the skin, retention of the beneficial effects of the other components, etc. Examples The following examples are provided for illustrative purposes and are not intended to limit the scope of the claims that follow. Example 1: Synthesis One hundred (100) g of dimethallylpolyether (CH₂=C(CH₃)CH₂O(C₂H₄O)₁₈ (C₃H₆O)₃₃ CH₂C(CH₃) =CH₂), 35O g of toluene, and 20 ppm of platinum as chloroplatinate were put in a 500 ml-three neck flask having a mechanical agitator, a condenser, a thermometer and a port for feeding nitrogen. One hundred nine (109) g of dihydropolydimethyl polysiloxane (HMe₂SiO(MeSiO)₄₀ SiMe₂H) was gradually added to the mixture at such a rate that the temperature was retained at 80 - 100 °C. The end of this reaction was judged when an AgNO₃ test on SiH became negative. Then the reacted mixture was neutralized by NaHCO₃ and filtered, and the solvent was removed at 50 °C/0.133 kPa (1 mmHg) by a rotary evaporator. Two hundred and three (203) g of the block copolymer having the following repeating unit and a molecular weight of 95,000 was prepared. [(Me₂SiO)₄₁Me₂SiCH₂CH(CH₃)CH₂-O(C₂H₄O)₁₈- (C₃H₆O)₃₃CH₂CH(CH₃)CH₂] 16.1 Example 2: Synthesis Using the same conditions as in Example 1, 70 g of dimethallyl polyether CH₂=C(CH₃)CH₂O(C₂H₄O)₂₀(C₃H₆O)₂₉CH₂C(CH₃)=CH₂, 61 g of dihydropolydimethylsiloxane HMe₂SiO(MeSiO)₃₀SiMe₂H, 35O g of toluene, and 20 ppm of platinum as an addition catalyst were reacted. One hundred and twenty-six (126) g of the block copolymer having a molecular weight of 67,000 and having the following repeating unit was prepared. [(Me₂SiO)₃₁Me₂SiCH₂CH(CH₃)CH₂-O(C₂H₄O)₂₀- (C₃H₆O)₂₉CH₂CH(CH₃)CH₂] 13.3 Example 3: Synthesis Using the same conditions as in Example 1, 150 g of dimethallyl polyether CH₂=C(CH₃)CH₂O(C₂H₄O)₂₀(C₃H₆O)₂₉CH₂C(CH₃)=CH₂, 43 g of dihydropolydimethyl siloxane HMe₂SiO(MeSiO)₈-SiMe₂H, 340 g of toluene, and 20 ppm of platinum as an addition catalyst were reacted. One hundred and eighty-six (186) g of the block copolymer having the following repeating unit and a molecular weight of 90,000 was prepared. [(Me₂SiO)₉Me₂SiCH₂CH(CH₃)CH₂-O(C₂H₄O)₂₀- (C₃H₆O)₂₉CH₂C(CH₃)CH₂] 26.3 Example 4: Synthesis Using the same conditions as in Example 1, 120 g of dimethallyl polyether CH₂=C(CH₃)CH₂O(C₂H₄O)₁₈(C₃H₆O)₂₀CH₂C(CH₃)=CH₂, 72 g of dihydropolydimethyl siloxane HMe₂Si(MeSiO)₁₅SiMe₂H, 330 g of toluene, and 20 ppm of platinum as an addition catalyst were reacted. One hundred and eighty-four (184) g of the block copolymer having the following repeating unit and a molecular weight of 71,000 was prepared. [(Me₂SiO)₁₆Me₂SiCH₂CH(CH₃)CH₂- O(C₂H₄O)₁₈(C₃H₆O)₂₀CH₂C(CH₃)CH₂] 21.5 Example 5: Synthesis Using the same conditions as in Example 1, 180 g of dimethallyl polyether CH₂=C(CH₃)CH₂O(C₂H₄O)₅CH₂O(CH₃)=CH₂, 95 g of dihydropolydimethyl siloxane HMe₂SiO(MeSiO)₈SiMe₂H, 350 g of toluene, and 20 ppm of platinum as an addition catalyst were reacted. Two hundred and sixty-one (261) g of the block copolymer having the following repeating unit and a molecular weight of 5,000 was prepared. [(Me₂SiO)₉Me₂SiCH₂CH(CH₃)CH₂- O(C₂H₄O)₅CH₂CH(CH₃)CH₂] 4.8 Example 6: (Control) Using the same conditions as in Example 1, 27 g of dimethyl polysiloxane containing hydrosilyl groups Me₃SiO[SiMe₂O]₁₀₀[SiMeHO]₁₃SiMe₃, 94 g of allyl polyether CH₂=CHCH₂O(C₂H₄O)₁₈(C₃H₆O)₂₀CH₃, 330 g of toluene, and 20 ppm of platinum as an addition catalyst were reacted. One hundred and twenty (120) g of the block copolymer having the following chemical structure and a molecular weight of 35,000 was prepared. Example 7: (Control) Using the same conditions as in Example 1, 97 g of dihydropolydimethyl siloxane HMe₂Si[Me₂SiO]₂₀₀SiMe₂H, 43 g of allyl polyether CH₂=CHCH₂O(C₂H₄O)₂₇(C₃H₆O)₃₀CH₃, 320 g of toluene, and 20 ppm of platinum as an addition catalyst were reacted. One hundred and thirty-three (133) g of the block copolymer having the following chemical structure and a molecular weight of 21,000 was prepared. CH₃(C₂H₄O)₂₇(C₃H₆O)₃₀OC₃H₆(Me₂SiO)₂₀₁- SiMe₂C₃H₆O(C₂H₄O)₂₇(C₃H₆O)₃₀CH₃ Example 8: (Hand cream) A hand cream was prepared by mixing the following ingredients: Alternating block copolymer according to Example 1 10 weight parts Cyclosiloxane 24 Squalane 5 Lanolin 3 Microcrystalline wax 3 Propyleneglycol 5 Citric acid 0.8 Preservative 0.2 Refined water 48 Perfume 1 Polyoxyethylene stearic ester 3 Evaluation : The hand cream was applied to hands but did not feel sticky. The hands did not feel rough after 30 minutes of dish washing. Example 9: (Hand Cream Control) A hand cream was prepared having the same composition as in Example 8 except that the alternating block copolymer was replaced by polyether pendant dimethyl polysiloxane prepared in Example 6. Evaluation : Compared with Example 8, the hand cream felt tacky on the hands. After 30 minutes of dish washing, the hand cream was completely removed, and the hands felt coarse and were defatted. Example 10: (Anti-Sunburn Cream) An anti-sunburn cream was prepared by mixing the following ingredients: Alternating block copolymer according to Example 2 10 weight parts Cyclosiloxane 40 Squalane 3 Microcrystalline wax 1 Silica 5 Anti-UV agent 0.5 Citric acid 0.8 Uroganin acid 1.0 Preservative 0.4 Refined water 30.3 Polyoxyethylene stearic acid 3 Glycerol 5 Evaluation : The anti-sunburn cream was applied to a back. The cream exhibited good flow and did not feel tacky sticky. After 10 minutes of swimming in sea water, 50% of the application amount remained. Example 11: (Lipstick) A lipstick was prepared by mixing the following ingredients: Alternating block copolymer according to Example 3 37 weight parts Microcrystalline wax 20 Citric acid 0.5 Titanium oxide fine powder 8 Siconin 0.01 Preservative 0.2 Refined water 34.29 Evaluation : The lipstick was applied to the skin. The gloss was good. The skin with the lipstick applied to was rinsed with water for 3 minutes, but the purple of Siconin remained. Example 12: (Lipstick Control) A lipstick was prepared having the same composition as in Example 11 except that the alternating block copolymer was replaced by polyether pendant dimethylpolysiloxane prepared in Example 6. Evaluation : The lipstick was applied to the skin. The gloss was inferior to that of Example 11. After 3 minutes of water rinse shower, the Siconin purple was substantially washed off. Example 13: (Lotion) A lotion was prepared by mixing the following ingredients: Alternating block copolymer according to Example 4 3 weight parts Stearic acid 0.2 Cetanol 1.5 Vaseline 3.0 Lanolin alcohol 2.0 Fluid paraffin 7.0 Polyoxyethylene monooleic acid (10 E.O.) 2.0 Perfume 0.5 Preservative 0.3 Glycerol 3.0 Propyleneglycol 5.0 Triethanolamine 1.0 Refined water 72.0 Evaluation : The lotion could be very smoothly applied to the skin and prevented smearing of makeup due to sweating. The lotion did not undergo phase separation. Example 14: (Lotion Control) A lotion was prepared having the same composition as in Example 13 except that the alternating block copolymer was replaced by polyether polysiloxane-polyether linear block copolymer prepared in Example 7. Evaluation : This lotion was slightly inferior to that according to Example 13 in flow when applied to the skin and allowed smearing of makeup due to sweating. Example 15: (Cosmetic Liquid) A cosmetic liquid was prepared by mixing the following ingredients: Alternating block copolymer according to Example 5 3.0 weight parts Glycerol 2.0 Propyleneglycol 6.0 Dipropyleneglycol 1.0 Ethanol 20.0 Refined water 68.0 Evaluation : This cosmetic liquid had good flow and feel when applied to the skin, made the skin brilliant (glossy) and was felt to tighten the skin. Example 16: (Cosmetic Liquid Control) A cosmetic liquid was prepared having the same composition as in Example 15 except that the alternating block copolymer was replaced by polyether pendant dimethyl polysiloxane according to Example 6. Evaluation : This cosmetic liquid lacked flow in application to the skin, and gave the skin less brilliance and less tightening feel. Example 17: (Shampoo) A shampoo was prepared by mixing the following ingredients: C14-α-olefin sodium sulfonate 15.0 weight parts Glycerin monostearate 1.0 Alternating block copolymer according to Example 1 1.0 Polyethylene glycol (molecular weight : 9,000) distearate 0.5 Sodium benzoate (germicide) 1.0 Perfume 0.5 Yellow No .203 (coloring matter) 0.01 Citric acid ph 5.8 Purified water Balance Example 18: (Shampoo Control) A shampoo was prepared having the same composition as that according to Example 17 except that the alternating block copolymer was replaced by the polyether pendant dimethyl polysiloxane in Example 6. Evaluation : Foaming: The shampoo of Example 17 was superior to Example 18 in that the foam felt creamy and was more stable. Foam extinction: Substantially the same. Squeaking during rinse: The shampoo of Example 17 squeaked less than Example 18. Dry condition after hair is dried: The shampoo of Example 17 was less dry. Example 19: (Hair Spray) A hair spray was prepared by mixing the following ingredients: Alternating block copolymer according to Example 2 12.0 weight parts Ethanol 16.0 Perfume 0.5 Trichloromonofluoromethane 40.0 Dichlorodifluoromethane 40.0 Example 20: (Hair Spray Control) A hair spray having the same composition as that according to Example 2 was prepared except that the alternating block copolymer was replaced by the polyether pendant dimethyl polysiloxane in Example 6. Evaluation : The spray was applied evenly to the hair of a woman (25 cm in length), and the hair was brushed 100 times with a polyethylene brush. The composition according to Example 19 was superior to the composition according to Example 20 in brilliance, flexibility, smoothness, wetness, brushing, dust attraction and moisture-retention. Example 21: (Hair Treatment) A hair treatment was prepared by mixing the following ingredients: Alternating block copolymer according to Example 3 10.0 weight Lanolin 1.0 parts Liquid paraffin 2.0 Self-emulsifiable glyceride monostearate, 5.0 Cetyl alcohol 0.5 Dimethyl benzylammonium chloride 3.0 Antiseptics 0.2 Perfume 0.1 Purified water 75.4 Example 22: (Hair Treatment Control) A hair treatment having the same composition as that according to Example 21 was prepared except that the alternating block copolymer was replaced by the polyetherpolysiloxane-polyether linear block copolymer in Example 7. Evaluation : Example 21 was superior to Example 22 in combing, smoothness, wetness, flexibility, brilliance, voluminousness (bulkiness), moisture-retaining ability and coating effect durability. Example 23: (Hair Liquid) A hair liquid was prepared by mixing the following ingredients: Alternating block copolymer according to Example 4 5.0 weight parts Polyoxypropylene (30) butyl ether 10.0 Polyethylene glycol 6000 5.0 Ethanol 44.0 Water 36.0 Example 24: (Hair Liquid Control) A hair liquid having the same composition as that according to Example 23 was prepared except that the alternating block copolymer was replaced by the polyether pendant dimethyl polysiloxane in Example 6. Evaluation : Example 24 is superior to Example 23 in tackiness, combing, wetness, smoothness and voluminousness (bulkiness).

Claims: A cosmetic formulation comprising a personal care ingredient and an effective amount of a non-hydrolyzing block copolymer having a linear polysiloxane-polyoxyalkylene block as a repeating unit to enhance at least one of the brilliance, durability or smoothness of the formulation. A cosmetic formulation according to claim 1, wherein the linear polysiloxane-polyoxyalkylene block copolymer has the general formula: ([Y(R₂SiO) a R₂SiYO][(C n H 2n O) b ]) c wherein; R represents a monovalent hydrocarbon radical containing substantially no unsaturated aliphatic series; n is an integer of 2 - 4; b is an integer of at least 4; c is an integer of at least 4; a is an integer of at least 5; Y represents a divalent organic group which is bonded with an adjacent silicon atom by a carbon-silicon linkage and with a polyoxyalkylene block by an oxygen atom; the average molecular weight of each siloxane block is 400 to 10,000; the average molecular weight of each polyoxyalkylene block is 300 to 10,000; the siloxane blocks comprise 10 - 90 weight % of the block copolymer; and the block copolymer has an average molecular weight of at least 3,000. The cosmetic formulation of claim 1 or 2 wherein the effective amount of the block copolymer is from 1 to 37 weight percent. The cosmetic formulation of any of claims 1-3 wherein the personal care ingredient is selected from a wax, an oil, cyclosiloxane, a surface active agent, a cellulosic compound, a moisture retaining agent, an amino acid, or mixtures thereof. The cosmetic formulation of any of claims 1-4 used in a skin care product. The cosmetic formulation of any of claims 1-4 used in a hair care product. The cosmetic formulation of any of claims 1-6 wherein the block copolymer has an average molecular weight of at least 30,000. The cosmetic formulation of any of claims 1-7 wherein the block copolymer is selected from: [(Me₂SiO)₄₁Me₂SiCH₂CH(CH₃)CH₂-O(C₂H₄O)₁₈- (C₃H₆O)₃₃CH₂CH(CH₃)CH₂] 16.1 [(Me₂SiO)₃₁Me₂SiCH₂CH(CH₃)CH₂-O(C₂H₄O)₂₀- (C₃H₆O)₂₉CH₂CH(CH₃)CH₂] 13.3 [(Me₂SiO)₉Me₂SiCH₂CH(CH₃)CH₂-O(C₂H₄O)₂₀- (C₃H₆O)₂₉CH₂C(CH₃)CH₂] 26.3 [(Me₂SiO)₁₆Me₂SiCH₂CH(CH₃)CH₂- O(C₂H₄O)₁₈(C₃H₆O)₂₀CH₂C(CH₃)CH₂] 21.5 [(Me₂SiO)₉Me₂SiCH₂CH(CH₃)CH₂- O(C₂H₄O)₅CH₂CH(CH₃)CH₂] 4.8 The cosmetic formulation of claim 2 wherein Y is selected from: -CH₂CH₂-, -CH₂CH₂CH₂-, -CH₂CH₂CH₂CH₂-, -(CH₂)₂CO-, -(CH₂)₃NHCO-, -(CH₂)₃NHCONHC₆H₄NHCO-, -(CH₂)₃OCONHC₆H₄NHCO-. The cosmetic formulation of claim 2 wherein said block copolymer is the product of the reaction of a compound A having the general formula: HR₂SiO(R₂SiO) a SiR₂H with a compound B having the general formula: wherein R represents a monovalent hydrocarbon radical, R' represents a monovalent hydrocarbon radical which may be the same or different from R, n is an integer of 2 - 4, a is an integer of at least 4 and b is an integer of at least 4.

Inventors: NODA ISAO, TSUBAKI SUGURU, NODA, ISAO, TSUBAKI, SUGURU
Applicants: NIPPON UNICAR CO LTD, NIPPON UNICAR COMPANY LIMITED
Application year: 1991
Main classification: A61K7
IPC codes: A61Q19, A61Q3, A61Q5, A61Q17, A61K8, C08G77, A61Q1