Silver halide photographic material

Abstract: The improved silver halide photographic material contains a compound of the general formula (I) which is capable of releasing a development restrainer upon reaction with the oxidation product of a developing agent: where Cp is a coupler residue that is capable of entering into a coupling reaction with the oxidation product of a color developing agent; TIME is a timing group bound to Cp at the coupling site; is 0 or 1; X is a linkage group; Y is a hydrolyzable group; and m is 0 or 1. (The remaining space is left blank.)

Description: BACKGROUND OF THE INVENTION This invention relates to a silver halide photographic material more particularly to a silver halide color photographic material having improved photographic characteristics and keeping quality. The development of color photographic materials having high sensitivity, good sharpness and high fidelity of color reproduction is one of the objectives in modern photographic industry. A known method of improving sharpness is to use DIR compounds which release development restrainers upon reaction with the oxidation product of color developing agents. As is well known, incorporating these DIR compounds in emulsions is effective for enhancing the sharpness of color image by the edge effect and further for improving the fidelity of color reproduction by the interimage effect. However, the conventional DIR compounds have the disadvantage that development restrainers released during color development dissolve and diffuse from photographic materials into the developing solution which will eventually exhibit a development inhibiting action in the presence of accumulated restrainers. With a view to solving this problem, improved methods have been proposed in JP-A-57-151944 (the term "JP-A" as used herein means an "unexamined published Japanese patent application"), JP-A-58-205150, JP-A-60-218644, JP-A-60-221750, JP-A-61-11743 and U.S. Patent No. 4,782,012. The methods described in these patents are based on using couplers that exhibit a development inhibiting action when leaving groups are eliminated from the coupling site of a coupler and which, when released into the developing solution, will be decomposed into compounds that cause no adverse effects on the photographic performance of the light-sensitive material in which they are used. As a matter of fact, light-sensitive materials using those couplers could be subjected to continuous processing in large quantities with smaller reduction in sensitivity and with the contamination of the developing solution being markedly reduced. However, the light-sensitive material containing those couplers experience not only increased fog but also deterioration in sensitivity, sharpness and color reproduction during storage. Further, the couplers themselves are not considered to be satisfactory from the viewpoint of achieving the edge effect and the interimage effect at the same time. EP-A-0252376 discloses a light-sensitive material package unit having exposure function, wherein a light sensitive emulsion layer comprises a compound having a timing group therein. SUMMARY OF THE INVENTION An object, therefore, of the present invention is to provide a color light-sensitive material that achieves good sharpness and high fidelity of color reproduction and which also is improved in storage stability. This object of the present invention can be attained by a silver halide photographic material containing a compound of the following formula (I) which is capable of releasing a development restrainer upon reaction with the oxidation product of a developing agent: where Cp is a coupler residue that is capable of entering into a coupling reaction with the oxidation product of a color developing agent; X is a linkage group; Y is a hydrolyzable group; and m is O or 1. DETAILED DESCRIPTION OF THE INVENTION The coupler residue represented by Cp in the general formula (I) may either be a residue that generates a yellow, magenta or cyan dye or a residue that generates a substantially colorless product. Typical examples of the yellow coupler residue represented by Cp are described in U.S. Patent Nos. 2,298,443, 2,407,210, 2,875,057, 3,048,194, 3,265,506, 3,447,928, and Farbkuppler eine Literaturübersicht Agfa Mitteilung (Band II), pp. 112-126, 1961, etc. Among the compounds described in these references, acyl acetanilides such as benzoyl acetanilide and pivaloyl acetanilide are preferred. Typical examples of the magenta coupler residue represented by Cp are described in U.S. Patent Nos. 2,369,489, 2,343,703, 2,311,182, 2,600,788, 2,908,573, 3,062,653, 3,152,896, 3,519,429, 3,725,067, 4,540,654, JP-A-59-162548, Agfa Mitteilung (Band II), ibid , pp. 126-156, 1961, etc. Among the compounds described in these references, pyrazolones and pyrazoloazoles (e.g. pyrazoloimidazole and pyrazolotriazole) are preferred. Typical examples of the cyan coupler residue represented by Cp are described in U.S. Patent Nos. 2,367,531, 2,423,730, 2,474,293, 2,772,162, 2,395,826, 3,002,836, 3,034,892, 3,041,236, 4,666,999 and Agfa Mitteilung (Band II), ibid , pp. 156-175, 1961. Among the compounds described in these references, phenols and naphthols are preferred. Typical examples of the coupler residue represented by Cp which forms a substantially colorless product are described in U.K. Patent No. 861,138, U.S. Patent Nos. 3,632,345, 3,928,041, 3,958,993, 3,961,959, etc. Among the compounds described in these patents, cyclic carbonyl compounds are preferred. Preferred examples of the yellow coupler residue represented by Cp in the general formula (I) are represented by the following general formulae (II) and (III): where R 1 and R 2 each represents an alkyl group, a cycloalkyl group, an aryl group, a hetero ring or a halogen atom, with the alkyl, cycloalkyl, aryl and hetero ring being optionally bound via at least one member of the group consisting of an oxygen atom, a nitrogen atom and a sulfur atom; the alkyl, cycloalkyl, aryl and hetero ring may also be bound via one or more of the following bonding groups, namely, acylamino, carbamoyl, sulfonamido, sulfamoyl, sulfamoylcarbonyl, carbonyloxy, oxycarbonyl, ureido, thioureido, thioamide, sulfone, sulfonyloxy, etc. The alkyl, cycloalkyl, aryl and hetero ring may further contain one or more of the following substituents, namely, a halogen atom, nitro, cyano, alkyl, alkenyl, cycloalkyl, aryl, alkoxy, aryloxy, alkoxycarbonyl, aryloxycarbonyl, carboxy, sulfo, sulfamoyl, carbamoyl, acylamino, ureido, urethane, sulfonamido, hetero ring, arylsulfonyl, alkylsulfonyl, arylthio, alkylthio, alkylamino, anilino, hydroxyl, imido, acyl, etc. When more than one each of R 1 and R 2 is present, two or more R 1 's or R 2 's may be the same or different. Preferred examples of the magenta coupler residue represented by Cp in the general formula (I) are those represented by the following general formulae (IV), (V), (VI) and (VII): where R 1 and R 2 are the same as defined for R 1 and R 2 in the general formulas (II) and (III). Preferred examples of the cyan coupler residue represented by Cp in the general formula (I) are those represented by the following general formulae (VIII), (IX) and (X): where R 1 and R 2 are the same as defined for R 1 and R 2 in the general formulae (II) and (III). Preferred examples of the coupler residue which forms a substantially colorless product as represented by Cp in the general formula (I) are those represented by the following general formulae (XI) - (XIV): where R 3 may be a hydrogen atom, an alkyl group, an aryl group, a halogen atom, an alkoxy group, an acyloxy group or a heterocyclic group; X is an oxygen atom or =NR 4 (where R 4 is an alkyl group, an aryl group, a hydroxyl group, an alkoxy group or a sulfonyl group); and Z is the nonmetallic atomic group necessary to form a 5- to 7-membered carbon ring (e.g. indanone, cyclopentanone or cyclohexanone) or a 5- to 7-membered hetero ring (e.g. piperidone, pyrrolidone or hydrocarbostyryl); where R 3 and X are the same as defined for R 3 and X in the general formula (XI); R 5 is an alkyl group, an aryl group, a heterocyclic group, a cyano group, a hydroxyl group, an alkoxy group, an aryloxy group, a heterocycloxy group, an alkylamino group, a dialkylamino group or an anilino group; where R 6 and R 7 which may be the same or different each represents an alkoxycarbonyl group, a carbamoyl group, an acyl group, a cyano group, a formyl group, a sulfonyl group, a sulfinyl group, a sulfamoyl group, an ammoniumyl group or (where A is nonmetallic atomic group necessary to form, taken together with the nitrogen atom, a 5- to 7-membered hetero ring such as phthalimido, triazole or tetrazole); where R 8 is an alkyl group, an aryl group, an anilino group, an alkylamino group or an alkoxy group; and B is an oxygen atom, a sulfur atom or a nitrogen atom. In the general formula (I), X represents alkylene, cycloalkylene, phenylene, alkenylene, -O-, -S- (where R 14 may be a hydrogen atom, an alkyl group, a cycloalkyl group or an aryl group) or combinations of these groups. Among these, alkylene, and combinations of these groups are preferred. Examples of the hydrolyzable group represented by Y in the general formula (I) include -COOR 15 , -OCOR 15 , -OSO 2 R 15 and with -COOR 15 being preferred. Examples of the group represented by R 15 include an alkyl group (e.g. methyl, ethyl, propyl, isopropyl, butyl, sec-butyl or n-hexyl), a cycloalkyl group (e.g. cyclopentyl or cyclohexyl), an aryl group (e.g. phenyl or naphthyl), and a heterocyclic group (e.g. pyridinyl, imidazolyl or pyrrolyl). These groups may have substituents such as a halogen atom, nitro, cyano, alkyl, alkenyl, cycloalkyl, aryl, alkoxy, aryloxy, alkoxycarbonyl, aryloxycarbonyl, carboxyl, sulfo, sulfamoyl, carbamoyl, acylamino, ureido, urethane, sulfonamido, hetero ring, arylsulfonyl, alkylsulfonyl, arylthio, alkylthio, alkylamino, anilino, hydroxyl, imido and acyl. A substituted alkyl group and an aryl group are preferred an R 15 , with aryl being more preferred. Typical examples of the compound of the general formula (I) are listed below but it should be understood that the present invention is by no means limited to these examples. One example of the synthesis of a compound represented by the general formula (I) is described below. Synthesis 1 (synthesis of illustrative compound 6) Compound 1 (7.4 g), compound 2 (2.2 g) and triethylamine (2.0 g) were dissolved in 20 ml of methylene chloride and the solution was stirred for 2 h. The reaction solution was washed with 50 ml of 1 N HC1 and 150 ml of water, followed by concentration under vacuum. The residue was recrystallized from methanol to obtain 7.0 g of illustrative compound 6. In the synthesis, the compound obtained was identified as the desired product by taking NMR, MS and IR spectra. The compound represented by the general formula (I) may be incorporated in any layers, such as silver halide emulsion layers and/or non-light-sensitive hydrophilic colloidal layers, in a photographic material. Preferably, the DIR coupler of formula (I) is incorporated in silver halide emulsion layers. More preferably, the DIR coupler of formula (I) is incorporated in a blue-sensitive silver halide emulsion layer and/or a red-sensitive silver halide emulsion layer. The DIR couplers of formula (I) may be incorporated in hydrophilic colloidal layers in a color photographic material by the following procedure: the DIR couplers of formula (I), taken either individually or in combination, are dissolved in a mixture of a known high-boiling point solvent such as dibutyl phthalate, tricresyl phosphate or dinonyl phenol and a known low-boiling point solvent such as butyl acetate or propionic acid; the solution is then mixed with an aqueous gelatin solution containing a surfactant, followed by dispersion using a high-speed rotary mixer, a colloid mill or an ultrasonic disperser, with the resulting dispersion being directly added to a silver halide emulsion; alternatively, the dispersion is allowed to set, shredded into noodles, which are then washed with water and added to a silver halide emulsion. The DIR couplers of formula (I) are used in amounts that preferably range from 0.005 ∼ 10 mol%, more preferably from 0.01 ~ 5 mol% of silver halide. The DIR couplers of formula (I) may be used either individually or as admixtures. Any customary silver halide emulsions may be used in the photographic material of the present invention. Such emulsions may be chemically sensitized in the usual manner, or they may be optically sensitized with spectral sensitizers to have sensitivity in a desired wavelength region. Antifoggants, stabilizers, etc. may be added to silver halide emulsions. Gelatin is advantageously used as a binder for silver halide emulsions. Emulsion layers and other hydrophilic colloidal layers may be hardened. Plasticizers or dispersions (latices) of synthetic polymers that are either insoluble or slightly soluble in water may also be contained in emulsion layers and other hydrophilic colloidal layers. Couplers are used in emulsion layers in a color photographic material. Also usable are colored couplers which are capable of color correction, competing couplers, as well as those compounds which, upon coupling with the oxidation product of developing agents, release photographically useful fragments such as a development accelerator, a bleach accelerator, a developing agent, a silver halide solvent, a toning agent, a hardener, a foggant, an antifoggant, a chemical sensitizer, a spectral sensitizer and a desensitizer. The photographic material of the present invention may have a filter layer, an anti-halo layer, an anti-irradiation layer, etc. These layers and/or emulsion layers may contain dyes that will dissolve out of the photographic material during photographic processing or which are bleachable. The photographic material of the present invention may also contain a matting agent, a lubricant, an image stabilizer, a surfactant, an anti -color fog agent, a development accelerator, a development retarder or a bleach accelerator. Supports that can be used in the present invention include paper laminated with a resin such as polyethylene, a polyethylene terephthalate film, baryta paper, a triacetyl cellulose film, etc. In order to produce dye image using the photographic material of the present invention, it may be subjected to known procedures of color photographic processing. The following examples are provided for the purpose of further illustrating the present invention but are in no way to be taken as limiting. In the following examples, the amounts of components or additives in silver halide photographic materials are based on one square meter unless otherwise noted. The amounts of silver halides and colloidal silver are calculated for silver. Example 1 Multi-layered color photographic material (sample 1) was prepared by forming the following layers in the order written on a triacetyl cellulose film base. Sample 1 (comparison): First layer: Anti-halo layer (HC-1) Gelatin layer containing black colloidal silver Second layer: Intermediate layer (IL) Gelatin layer containing an emulsified dispersion of 2,5-di-t-octylhydroquinone Third layer: Less red-sensitive silver halide emulsion layer (RL-1) Fourth layer: Highly red-sensitive silver halide emulsion layer (RH-1) Fifth layer: Intermediate layer (IL) Same gelatin layer as the second layer Sixth layer: Less green-sensitive silver halide emulsion layer (GL-1) Seventh layer: Highly green-sensitive silver halide emulsion layer (GH-1) Eighth layer: Yellow filter layer (YC-1) Gelatin layer containing yellow colloidal silver and an emulsified dispersion of 2,5-di-t-octylhydroquinone Ninth layer: Less blue-sensitive silver halide emulsion layer (BL-1) Monodispersed emulsion (emulsion III) composed of AgBrI grains (6 mol/% AgI) having an average grain size of 0.48 µm 0.9 g Spectral sensitizer V 1.3x10 -5 moles per mole of silver Yellow coupler (Y-1) 0.29 moles per mole of silver Tenth layer: Highly blue-sensitive silver halide emulsion layer (BH-1) Eleventh layer: First protective layer (Pro-1) Gelatin layer containing silver iodobromide grains (1 mol% AgI; r = 0.07 µm silver deposit, 0.5 g), as well as uv absorbers UV-1 and UV-2 Twelfth layer: Second protective layer (Pro-2) Gelatin layer containing polymethyl methacrylate particles (diameter, 1.5 µm) and formaldehyde scavenger (HS-1) Besides the compounds mentioned above, a gelatin hardener (H-1) and a surfactant were also added to each layer. The following compounds were incorporated in the respective layers of sample 1. Spectral sensitizer I: Anhydro-5,5'-dichloro-9-ethyl-3,3'-di(3-sulfopropyl)thiacarbocyanine hydroxide Spectral sensitizer II: Anhydro-9-ethyl-3,3'-di(sulfopropyl)-4,5,4',5'-dibenzothiacarbocyanine hydroxide Spectral sensitizer III: Anhydro-5,5'-diphenyl-9-ethyl-3,3'-di(3-sulfopropyl) oxacarbocyanine hydroxide Spectral sensitizer IV: Anhydro-9-ethyl-3,3'-di(3-sulfopropyl)-5,6,5',6'-dibenzoxacarbocyanine hydroxide Spectral sensitizer V: Anhydro-3,3'-di(3-sulfopropyl)-4,5-benzo-5'-methoxythiacyanine hydroxide Samples 2 and 3 were prepared by replacing the DIR compound (D-1) in the third and fourth layers of sample 1 with equimolar amounts of the compounds shown in Table 1 below. Each of the thus prepared samples 1 - 3 was divided into two lots, one of which was left to stand at 55°C for 7 days at 20% r.h. before exposure. The samples including the untreated lots were exposed to white light through an optical wedge and processed by the scheme shown below. The sensitivity of the red-sensitive layers and the fog that occurred were measured. At the same time, the sharpness of image was also measured and the results were shown in terms of the relative values of MTF at a resolution of 30 lines/mm, with the value for sample 1 taken as 100. The results of the measurements are shown in Table 1 below. Processing scheme (38°C) Color development 3 min and 15 sec Bleaching 6 min and 30 sec Washing with water 3 min and 15 sec Fixing 6 min and 30 sec Washing with water 3 min and 15 sec Stabilization 1 min and 30 sec Drying The processing solutions used in the color developing, bleaching, fixing and stabilizing steps had the following compositions. Color developing solution 4-Amino-3-methyl-N-ethyl-N-(β-hydroxyethyl)aniline sulfate 4.75 g Anhydrous sodium sulfite 4.25 g Hydroxylamine hemisulfate 2.0 g Anhydrous calcium carbonate 37.5 g Sodium bromide 1.3 g Nitrilotriacetic acid trisodium salt (monohydrate) 2.5 g Potassium hydroxide 1.0 g Water to make 1,000 ml Bleaching solution Ethylenediaminetetraacetic acid iron (III) ammonium salt 100 g Ethylenediaminetetraacetic acid diammonium Salt 10.0 g Ammonium bromide 150.0 g Glacial acetic acid 10 ml Water to make 1,000 ml pH adjusted to 6.0 with aqueous ammonia Fixing solution Ammonium thiosulfate 175.0 g Anhydrous sodium sulfite 8.6 g Sodium metasulfite 2.3 g Water to make 1,000 ml pH adjusted to 6.0 with acetic acid Stabilizing solution Formaldehyde (37% aq. sol.) 1.5 ml Konidax (product of Konica Corp.) 7.5 ml Water to make 1,000 ml Sample No. DIR compound in layers 3 and 4 Untreated Treated at 55°C Sharpness specific sensitivity fog specific sensitivity fog 1(comparison) D-1 100 0.16 92 0.30 100 2(comparison) D-4 99 0.16 93 0.31 101 3(invention) 4 101 0.15 99 0.20 113 As is clear from Table 1, the sample prepared in accordance with the present invention was markedly improved in image sharpness and further experienced less thermal fogging and reduction in sensitivity during storage. Reduction in sensitivity was also negligible even when the sample of the present invention was subjected to continuous processing. Example 2 A basic sample was prepared by coating multiple layers in superposition on a triacetate base in the order indicated below. (1) Red-sensitive silver halide emulsion layer containing 0.5 g of cyan coupler (C-2), 2.4 g of gelatin and 1.6 g of silver halide; (2) Intermediate gelatin layer containing 0.5 g of gelatin and 0.1 g of 2,5-di-t-octylhydroquinone; (3) Blue-sensitive silver iodobromide emulsion layer containing 1.70 g of yellow coupler (Y-1), 2.4 g of gelatin and 1.6 g of silver halide; and (4) Protective layer containing 0.8 g of gelatin. Additional samples 4-6 were prepared by adding specific DIR couplers (see Table 2) to the yellow coupler containing third layer in an amount of 3.0 x 10 -4 mol/m 2 . Each of these samples was divided into two lots, one being exposed to white light through an optical wedge and the other exposed to red light through an optical wedge. Each lot of the samples were then processed as in Example 1. Gamma values were determined from the characteristic curves of cyan dye as obtained for each sample by color development and the gamma by exposure to red light (r R ) was divided by the gamma by exposure to white light (r W ). The results are shown in Table 2 below. Sample No. DIR compound r R /r W 4 (comparison) D - 5 1.20 5 (comparison) D - 6 1.22 6 (invention) 1 1.55 As is clear from Table 2, the sample using the DIR compounds of formula (I) provided large r R /r W values and obviously produced a greater inter image effect than when the conventional DIR couplers were used. The advantage of the present invention is that it provides a silver halide color photographic material that achieves good sharpness and high fidelity of color reproduction and which is also improved in storage stability.

Claims: A silver halide photographic material comprising a compound of the following general formula (I) which is capable of releasing a development restrainer upon reaction with the oxidation product of a developing agent: where Cp is a coupler residue that is capable of entering into a coupling reaction with the oxidation product of a color developing agent, X is a linkage group, Y is a hydrolyzable group and m is 0 or 1. A silver halide photographic material according to claim 1 wherein the coupler residue represented by Cp in the general formula (I) is a yellow coupler residue represented by the following general formula (II) or (III): where R 1 and R 2 each represents an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group or a halogen atom, provided that the alkyl, cycloalkyl, aryl or heterocyclic group may be bound via at least one member of the group consisting of an oxygen atom, a nitrogen atom, a sulfur atom, an acylamino group, a carbamoyl group, a sulfonamido group, a sulfamoyl group, a sulfamoylcarbonyl group, a carbonyloxy group, an oxycarbonyl group, a ureido group, a thioureido group, a thioamido group, a sulfone group and a sulfonyloxy group. A silver halide photographic material according to claim 1 wherein the coupler residue represented by Cp in the general formula (I) is a magenta coupler residue represented by either one the following general formulae (IV) - (VII): where R 1 and R 2 each represents an alkylgroup, a cycloalkyl group, an aryl group, a heterocyclic group or a halogen atom, provided that the alkyl, cycloalkyl, aryl or heterocyclic group may be bound via at least one member of the group consisting of an oxygen atom, a nitrogen atom, a sulfur atom, an acylamino group, a carbamoyl group, a sulfonamido group, a sulfamoyl group, a sulfamoylcarbonyl group, a carbonyloxy group, an oxycarbonyl group, a ureido group, a thioureido group, a thioamido group, a sulfone group and a sulfonyloxy group. A silver halide photographic material according to claim 1 wherein the coupler residue represented by Cp in the general formula (I) is a cyan coupler residue represented by either one of the following general formulae (VIII) - (X): where R 1 and R 2 each represents an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group or a halogen atom, provided that the alkyl, cycloalkyl, aryl or heterocyclic group may be bound via at least one member of the group consisting of an oxygen atom, a nitrogen atom, a sulfur atom, an acylamino group, a carbamoyl group, a sulfonamido group, a sulfamoyl group, a sulfamoylcarbonyl group, a carbonyloxy group, an oxycarbonyl group, a ureido group, a thioureido group, a thioamido group, a sulfone group and a sulfonyloxy group. A silver halide photographic material according to claim 1 wherein the coupler residue represented by Cp in the general formula (I) is a coupler residue that forms a substantially colorless product and which is represented by either one of the following general formulas (XI) - (XIV): where R 3 is a hydrogen atom, an alkyl group, an aryl group, a halogen atom, an alkoxy group, an acyloxy group or a heterocyclic group; X is an oxygen atom or =NR 4 (where R 4 is an alkyl group, an aryl group, a hydroxyl group, an alkoxy group or a sulfonyl group); and Z is the non-metallic atomic group necessary to form a 5- to 7-membered carbon ring; where R 3 and X are the same as defined for R 3 and X in the general formula (XI); R 5 is an alkyl group, an aryl group, a heterocyclic group, a cyano group, a hydroxyl group, an alkoxy group, an aryloxy group, a heterocycloxy group, an alkylamino group, a dialkylamino group or an anilino group; where R 6 and R 7 which may be the same or different each represents an alkoxycarbonyl group, a carbamoyl group, an acyl group, a cyano group, a formyl group, a sulfonyl group, a sulfinyl group, a sulfamoyl group, an ammoniumyl group or (where A is the non -metallic atomic group necessary to form, taken together with the nitrogen atom, a 5- to 7-membered hetero ring); and where R8 is an alkyl group, an aryl group, an anilino group, an alkylamino group or an alkoxy group; and B is an oxygen atom, a sulfur atom or a nitrogen atom. A silver halide photographic material according to any preceding claim, wherein the linkage group represented by X in the general formula (I) is an alkylene group, a cycloalkylene group, a phenylene group, an alkenylene group, -O-, -S- or a combination thereof, and R 14 is a hydrogen atom, an alkyl group, a cycloalkyl group or an aryl group. A silver halide photographic material according to any preceding claim, where the hydrolyzable group represented by Y in the general formula (I) is -COOR 15 , -OCOR 15 , -OSO 2 R 15 or wherein R 15 is an aryl group, a heterocyclic group, an alkyl group, or a cycloalkyl group. A silver halide photographic material according to any preceding claim wherein the compound represented by the general formula (I) is incorporated in a silver halide emulsion layer. A silver halide photographic material according to any preceding claim wherein the compound represented by the general formula (I) is incorporated in either a blue-sensitive silver halide emulsion layer or red-sensitive silver halide emulsion layer or both. A silver halide photographic material according to any preceding claim wherein the compound represented by the general formula (I) is contained in an amount of 0.005 ∼ 5 mol% of silver halide. A silver halide photographic material according to claim 10 wherein the compound represented by the general formula (I) is contained in an amount of 0.01 ∼ 5 mol% of silver halide.

Inventors: KIDA SHUJI, SUGITA SHUICHI, KIDA, SHUJI, SUGITA, SHUICHI
Applicants: KONISHIROKU PHOTO IND, KONICA CORPORATION
Application year: 1991
Main classification: G03C7
IPC codes: G03C7, G03C1