Process for shortstopping an emulsion polymerization

Abstract: A process for shortstopping a free radical polymerization of a conjugated diene and optionally a vinyl-substituted aromatic in an aqueous emulsion, using a hydroperoxide as initiator and a redox activator, comprising a divalent transition metal, a reducing agent and optionally being carried out in the presence of a modifier, and being performed by using as sole shortstopping agent an alkali metal polysulphide, and polymeric products obtained therewith.

Description: This invention relates generally to the shortstopping (termination) of the polymerization of a conjugated diene optionally mixed with a vinyl-substituted aromatic in an aqueous emulsion free radical polymerization process conducted at from -20 to 70 °C, using a redox initiator and more particularly to the termination of the aqueous free radical emulsion polymerization of butadiene, optionally mixed with styrene (e.g. ESBR). The field of aqueous emulsion free radical polymerization constitutes a well established art. The systems now used were generally established in the 1940′s and the 1950′s. In emulsion polymerization processes, the monomer is emulsified in a medium such as water with the aid of emulsifying agents such as soaps and synthetic emulsifiers. Initially the monomer is present in the form of emulsion droplets dispersed in the continuous aqueous phase. According to the present conception the emulsion droplets play only a minor role and the polymerization in emulsion systems occurs primarily in the aqueous phase and not in monomer droplets. Considerable work published in the last decades has shown that the process of emulsion polymerization is more complicated and more subtle than previously believed and several theories have been developed in order to explain the experimentally found data, such as particle size, the conversion-time relationship, the dependence of particle size and molecular weight on conversion, and the influence of surfactant, initiator and monomer. The chain reaction in free radical emulsion polymerization is initiated by radicals that are generated either by decomposition of peroxides or diazo compounds or by an oxidation-reduction reaction (a redox couple). Early free radical emulsion polymerizations which were carried nut at 50 °C or higher (hot polymerization), reflected the temperature dependency of the formation rate of free radicals and therefore, of polymerizations. A subsequent research led to the discovery of oxidation-reduction reactions capable of generating radicals in sufficient numbers for adequate polymerization rates at temperatures as low as -40 °C (cold polymerization). Commonly employed dissociative initiators are potassium peroxydisulphate (K 2 S 2 O 8 ), benzoyl peroxide and azobisisobutyronitrile (AIBN), whereas cumene hydroperoxide and p-menthane hydroperoxide are oxidants for redox couples. The combination of potassium peroxydisulphate with a mercaptan, such as dodecyl mercaptan, is used to polymerize e.g. butadiene and styrene. In hot recipes the mercaptan furnishes free radicals by its reaction with the peroxydisulphate, and it limits the molecular weight of the polymer by reacting with and terminating the growing polymer chain; the resulting thiyl radical initiates the growth of another chain. This use of mercaptan as a chain transfer agent or modifier is of great commercial importance in the manufacture of emulsion SBR and polybutadiene, since the mercaptan allows control of the toughness of the product, which otherwise may limit further processing. The conversion rate to polymer at 50 °C is 5-6%/hr. Polymerization is terminated at 70-75% conversion or less since higher conversions lead to polymers with inferior physical properties, presumably because of cross-linking in the latex particle to form microgel or highly branched structure. A further improvement in SBR production could be reached by the use of more active radical initiating systems that permitted polymerization at 5 °C with high rates of conversion. These cold SBR polymers produced at lower temperature, but stopped at 60% conversion were found to have superior properties as to those of hot SBR. At 5 °C a 60% conversion to polymer occurs in about 8-12 h. In the persulphate hot recipe the mercaptan initiates and functions as a chain transfer agent, but in the cold redox recipes, the mercaptan is not essential to initiation. The main difference lies in the initiator systems. The usually applied phosphates and ethylenediaminetetra acetic acid (EDTA) act as buffers and complex with ferrous ions, thereby maintaining a constant solubility and limiting its reactivity. This reaction is very rapid at 0 °C; the emulsion components are in separate phase and the reaction occurs only at the interface. In many cold recipes auxiliary reducing agents, such as sulphoxylates are used as components of a redox cycle, i.e. the ferric ion is reduced to the ferrous state. Reducing sugars are no longer in widespread use because of their cost and susceptibility to bacterial attack during storage. Although this initiator system is primarily used for so-called cold polymerizations, it will be appreciated that such system can also be applied with higher temperature polymerizations. For property control reasons, it is a well established practice, that the termination of the polymerization is effected by the addition of a shortstop, which reacts rapidly with radicals and oxidizing agents, thus destroying any remaining initiator and polymer free radicals and preventing the formation of new radicals. The unreacted monomers are then removed : first the conjugated diene and more particularly butadiene by flash distillation at atmospheric then at reduced pressure; second the styrene usually by steam stripping in a column. A dispersion of antioxidant is added to protect the product. The latex is optionally mixed with oil, and coagulated by the addition of dilute acid e.g. sulphuric acid and optionally a salt, e.g. aluminium sulphate or sodium chloride. In particular, shortstopping compositions should meet the requirements as disclosed in e.g. D.C. Blackley "Emulsion Polymerization", Theory and Practice 1975, p. 406 f.f. Such chemicals included for example mixtures of a water soluble sulphide, such as hydrogen sulphide, ammonium sulphide, or sulphides or hydrosulphides of alkali or alkaline earth metals and an organic compound possessing a quinonoid structure, such as quinone or an organic compound which may be oxidized to a quinonoid structure, such as hydroquinone; N-substituted dithiocarbamates; reaction products of alkylene polyamines with sulphur, containing presumably sulphides, disulphides, polysulphides and/or mixtures of these and other compounds; dialkylhydroxylamines, N,N′-dialkyl-N,N′-methylenebishydroxylamines, dinitrochlorobenzene, dihydroxydiphenyl sulphide and dinitrophenylbenzothiazyl sulphide. It will be appreciated that the efficiency of the selected shortstopping agent will be dependent on inter alia the type of the initiator to be used. More particularly US patent No. 2,469,017 disclosed a process for the polymerization of butadiene-1,3 in aqueous emulsion in the presence of a peroxygen compound, comprising supplying to the emulsion, at a monomer conversion degree of 20 to 80%, an organic compound possessing the quinone structure and a water soluble inorganic sulphide of the class consisting of hydrogen sulphide, ammonium sulphide and alkalimetal sulphides and hydrosulphides, the said compound of quinonoid structure being supplied to the emulsion at least as soon as the said sulphide and in an amount from 0.001 to 0.05% by weight based on the amount of monomeric material originally present in the emulsion before polymerization and the said sulphide being supplied to the emulsion in an amount from 0.01 to 0.2% by weight based on the amount of monomeric material originally present in the emulsion whereby further polymerization of monomers is immediately terminated. As suitable peroxygen compound were indicated hydrogen peroxide, an alkali metal or ammonium persulphate or perborate, and more particularly potassium persulphate, whereas as shortstopping co-component hydroquinone is preferably used. Especially from column 3, lines 19-21, it may be derived that when the sulphide is used without hydroquinone the polymerization proceeds to significantly higher conversion. From US patent No. 2,602,078 it was known to use N-substituted dithiocarbamates as effective shortstopping agents for emulsion polymerization reactions, and the use of which is providing substantially improved properties of the produced polymers, which are substantially snow white. Especially from column 1, lines 20-33 in relation to column 4, lines 62-68 of said patent, it may be derived that the employment of e.g. sodium sulphide and hydroquinone in emulsion polymerization should lead to difficulties and was not attractive. More particularly from example II of US patent No. 2,616,875, it was known that sodium thiosulphate and sodium sulphide respectively could not be regarded as active ingredients of the shortstopping agents obtained by reaction of alkylene polyamines with sulphur. Moreover it was known from US patent No. 2,662,876, that the polymerization in aqueous emulsion of a butadiene-1,3 optionally mixed with other copolymerizable monomeric materials, could be efficiently terminated by the addition to the emulsion at any desired stage of polymerization, of a combination of substances consisting of : (1) a solution of an agent selected from the class consisting of sulphur, alkylthiuram polysulphides, alkyl xanthogen polysulphides and water-soluble inorganic polysulphides, and (2) an aqueous solution of a water-soluble salt of dithiocarbamic acid, wherein substance (1) being added in amounts equivalent to from 0.01 to 0.10% by weight of sulphur and substance (2) being added in amounts of from 0.01 to 0.10% by weight, based on the weight of monomer initially present in said emulsion. As a preferred inorganic, water-soluble polysulphide sodium polysulphide was proposed. However, especially from example 3 from said patent could be learnt that sodium sulphide alone as shortstopping agent was significantly less active as compared with the sulphur-carbamate stopping agent. Additional experimentation revealed that e.g. substantially pure sodium sulphide alone was not capable to stop aqueous emulsion polymerizations of butadiene-1,3 and styrene, at concentrations in the range of from 0.015 to 0.1 parts by weight per hundred parts by weight of the monomers. A shortstopping agent for an aqueous emulsion polymerization of butadiene-1,3 hydrocarbons and mixtures of butadiene-1,3 hydrocarbons and compounds, which contain a CH 2 = CH group and are copolymerizable with butadiene-1,3 hydrocarbons, e.g. styrene, comprising a combination of alkali metal-hydrosulphite, -hydroxide and -nitrite, wherein the amount of added alkali metal hydrosulphite being from 0.1 to 1 part by weight per 100 parts by weight of polymerizable monomeric material originally present, the added alkali metal hydroxide being from 0.5 to 3 mols per mol of added alkali metal hydrosulphite and the added alkali metal nitrate being from 0.1 to 2 mols per mol of added alkali metal hydrosulphite, was known from e.g. US patent No. 3,322,736. From US patent No. 4,242,477 is known an improved process for shortstopping the polymerization of butadiene and styrene in an emulsion, free radical polymerization process conducted at a temperature of from about 40 °C to about 60 °C, using potassium or ammonium persulphate as polymerization initiator, comprising the use of ascorbic acid or the sodium or potassium salts thereof, in a quantity of ascorbic acid or salts thereof of from about 0.1 to about 0.75 parts by weight per 100 parts by weight per 100 parts by weight of butadiene plus styrene charged in the polymerization system. Polymer produced does not discolour, does not have odour and appears not to contain chemicals detrimental to the use of the polymer in food- or drug-related applications. However, these shortstopping agents were indicated not to be used as shortstops in the cold redox or hot redox polymerization systems. A preferred, more optimized, shortstopping agent for a redox initiation system which has been widely used on an industrial scale for many years, comprises a combination of dithiocarbamate and sodium polysulphide optionally mixed with sodium nitrite, the latter ingredient of which was regarded as desired for prevention of undesired, uncontrolled polymerization of the non-converted monomers during the recovery of these monomers from the shortstopped polymerization reaction mixture. This so-called wild polymerization will give rise to an increase in molecular weight of the final polymer and production of undesirable cross-linked polymer (popcorn polymer), which may lead to fouling of butadiene distillation and flashing equipment and even to bursting of pipes, as was known from e.g. D.C. Blackley, "Emulsion Polymerization", Theory and Practice, 1975, p. 430-435. However, a disadvantage of such combinations is that dithiocarbamates and nitrites are precursors for the formation of nitrosamines which are suspected to be carcinogenic. It will be appreciated by a person skilled in the art, that according to the general conception of the prior art sulphides were only used, if any at all, as one of the ingredients of shortstopping agents and certainly not as sole shortstopping agent, as may also be derived from e.g. D.C. Blackley, "Emulsion Polymerization", Theory and Practice, 1975, p. 406-417, and particularly p. 416, and from the publications referred to. On the other hand efforts in present research and development in rubber industry have strongly increased to prevent the formation of N-nitroso compounds from possible precursors in shortstopping agents during emulsion SBR manufacture, which may clearly be derived from e.g. Japanese patent applications Nos. 58,005,349; 58,005,350; 58,002,337 and 57,212,243 and Russian patent No. 971,850. It is therefore an object of the present invention to provide an effective shortstopping agent, substantially free of co-ingredients which might be regarded as precursors for the formation of N-nitrosamines, and which still meets the hereinbefore specified requirements as much as possible when applied on emulsion polymerization reaction mixtures derived from a conjugated diene, optionally mixed with a vinyl-substituted aromatic, the polymerization of which was initiated by redox systems. Moreover another object of the present invention is formed by an economically attractive, more simple process, wherein such shortstopping agent aimed at is successfully applied. As a result of extensive research and experimentation, a process was surprisingly found for the manufacture of polymers derived from a conjugated diene, optionally mixed with a vinyl-substituted aromatic, by means of aqueous emulsion polymerization and more particularly ESBR, using an effective shortstopping agent aimed at. Accordingly the present invention is relating to a process for shortstopping a free radical polymerization of a conjugated diene, and optionally a vinyl-substituted aromatic, in an aqueous emulsion polymerization process conducted at a temperature of from -20°C to 70°C, using a hydroperoxide as initiator and a redox activator system, comprising a ferro compound, a reducing agent and optionally a chelating agent, the polymerization process optionally being carried out in the presence of a modifying agent, characterized in that as sole shortstopping agent an alkali metal polysulphide of the formula Me2Sx, wherein x has a value in the range of from 2.5 to 4.5 and wherein Me represents an alkali metal is used in an amount in the range of from 0.01 to 0.5 parts by weight per hundred parts by weight of the total monomers, initially charged to the polymerization system. The shortstopping agent is preferably used in an amount of from 0.04 to 0.06 parts by weight per hundred parts by weight of monomers. As ferro compound in the redox activator preferably ferrosulphate is used, and as preferred reducing agent sodium formaldehyde sulphoxylate is used. Most preferably x has a value of about 4. As suitable alkali metal polysulphides may be used the sodium or potassium salt, of which the sodium salts are preferred. As suitable reducing agents maybe used e.g. sodium formaldehyde sulphoxylate, sodium sulphite, sodium benzaldehyde sulphoxylate or a reducing sugar, of which sodium formaldehyde sulphoxylate is preferred. As a chelating agent may be used e.g. sodium ethylenediamine tetraacetate (EDTA), sodium silicate, sodium pyrophosphate or polyphosphate, of which EDTA is preferred. The shortstonpping agent may be applied according to the present invention for the manufacture of (homo)polymers of conjugated diene and more particularly butadiene-1,3, isoprene, chloroprene, piperylene, 2,3-dimethyl-1,3-butadiene and the like or mixtures thereof, of which butadiene-1,3 pure or mixed with minor amounts of other conjugated dienes is preferred, or of copolymers from such a conjugated diene and a vinyl-substituted aromatic, such as styrene, α-methyl styrene, vinyl naphthalene, 2,4-dichlorostyrene, p-methoxystyrene, p-methylstyrene, 3,4-dimethylstyrene, divinyl benzene, α-propyl styrene, o-hydroxystyrene, α-undecylstyrene, o-methyl-α-methyl styrene and the like or mixtures thereof, of which styrene, pure or optionally mixed with minor amounts of one or more other vinyl-substituted aromatic monomers, is the preferred monomer. According to the process of the present invention there may be prepared homopolymers as well as copolymers, the monomer ratio in which may vary in a wide range. The ratio by weight of the conjugated diene, e.g. butadiene, and the vinyl-substituted aromatic e.g. styrene, if any, may preferably vary in the range of from 80 : 20 to 50 : 50. The aqueous emulsion polymerization process according to the present invention can be carried out at a temperature of from -20 °C to 70 °C, and more particularly as a so-called "cold polymerization", using temperatures in the range of from -20 °C to 10 °C, and as so-called "hot polymerization", using temperatures in the range of from 40 °C to 70 °C, as well. As suitable initiator to be applied for the process of the present invention may be used : paramenthane hydroperoxide, cumene hydroperoxide, pinane hydroperoxide, diisopropyl toluene hydroperoxide, diisopropylbenzene hydroperoxide, p-tert.butyl cumene hydroperoxide, hydrogen peroxide, 1,1-diphenylethane hydroperoxide and the like, or mixtures thereof, of which paramenthane hydroperoxide is being preferred. Said initiators are normally used in an amount of from 0.01-0.4 parts by weight per 100 parts by weight of initially charged monomers. Said hydroperoxides are combined with a ferrocompound/sulphoxylate/chelating agent combination as redox activator to be applied. A suitable example of such activator component is consisting of ferro compound, preferably ferrosulphate, in combination with a sulphoxylate component and more preferably sodium formaldehyde sulphoxylate, and EDTA. Said activators are normally comprising : ferrosulphate 0.001-0.04 parts by weight; sulphoxylate 0.01-0.2 parts by weight; and chelating agent 0.005-0.2 parts by weight per 100 parts by weight of initially charged monomers. More preferably a combination of ferrosulphate, sodium formaldehyde sulphoxylate and EDTA in the indicated ranges will be applied as activator of the polymerization to be shortstopped. As suitable modifier during the (co)polymerization can be used e.g. xanthogendisulphides, thioethers, thiophosphates and alkyl mercaptans containing 9 to 16 carbon atoms in the alkyl and more preferably tert.dodecyl mercaptan. Other suitable modifiers may be selected from n-dodecyl mercaptan, t-hexadecyl mercaptan. The modifier is normally used in an amount of from 0.05-0.6 parts by weight per 100 parts by weight of initially charged monomers. When operating according to the process of the present invention, temperatures may range from -20 °C to about 70 °C with temperatures from 0 °C to 50 °C being usually preferred. When polymerizations are carried out in aqueous emulsion in the absence of freezing point depressants, temperatures below the freezing point of water cannot be employed. It is generally preferred that the emulsion be of an "oil in water" type, with the ratio of aqueous medium to monomeric material in the range of from 0.5 : 1 to 5 : 1 and preferably from 1.5 : 1 to 2.75 : 1, in parts by weight. At low ratios the emulsions tend to have high viscosities and at high ratios the yield per unit volume of reactor per unit of time is low. In the practice of the present invention suitable means will be necessary to establish and maintain an emulsion and to remove reaction heat to maintain a desired reaction temperature. The emulsifier used is generally a fatty acid and/or rosin acid soap, di-tert.butyl benzoic acid or a derivative of Versatic acid (trade mark) and the polymerization recipe may contain a small amount of one or more electrolytes, such as trisodium phosphate or potassium chloride. Generally also a small amount of surfactant may be added, such as e.g. sodium salt of naphthalene sulphonic acids polymers. Moreover, if necessary, a base may be added to adjust the required alkaline environment such as sodium hydroxide or potassium hydroxide. A preferred pH value is in the range from 9-13 and most preferably in the range from 10 to 11. The polymerization may be conducted in batches, semi-continuously or continuously. The total pressure on the reactants is preferably at least as great as the total vapour pressure of the mixture, so that the initial reactants will be present in the liquid phase. After reaching the desired conversion of monomers to polymers normally being in the range of from 55 to 90%, the polymerization is stopped by addition of the shortstopping agent. In order to effectively prevent further formation of polymer during the removal of unreacted monomers, the shortstopping agent used according to the present invention is used in an amount of at least 0.01 parts by weight per hundred parts by weight of the total monomers, initially charged to the polymerization system, and preferably in an amount of from 0.02 to 0.5 and more preferably of from 0.04 to 0.06. The latex is passed to one or more, and generally two, tanks in which the pressure is finally reduced to about 20 cm of mercury and in which a major proportion of the unreacted conjugated diene (e.g. butadiene) is vapourized and removed as an overhead vapour stream. In the beforementioned tanks an agent to prevent the formation of popcorn may optionally be introduced. Preferably a colloidal sulphur suspension is used for this purpose. According to one of the usual embodiments of the manufacturing processes, the latex is then passed to a stripping column in which any remaining butadiene and the unreacted styrene is removed. From such a stripping column, the latex is passed to either chemical and/or mechanical coagulation and recovery facilities for the final recovery of dry polymer or to concentrating facilities for production of latex having from about 45 to about 65 per cent polymer solids. According to another embodiment, the latex from which butadiene has substantially been removed by stripping, is chemically and/or mechanically coagulated and the coagulated rubber is dried in a mechanical dryer, whereby the free vinyl-substituted aromatic (styrene) monomer is recovered during the drying operation. It will be appreciated that the efficient results achieved by the shortstopping agent used according to the process of the present invention, certainly could not be predicted or even expected by a person skilled in the art, having in mind the hereinbefore discussed state of the prior art and in particular the inactivity of pure sodium sulphide as stopping agent. The process of the present invention provides rubbers, in which during manufacturing and subsequent compounding and additional processing steps the formation of carcinogenic nitrosamines from compounds, occurring in said rubbers is avoided. Moreover, the rubbers thus produced also show a more reproducible quality due to the fact that a reduced amount of chemicals is used as compared with the conventional shortstopping compositions, containing several ingredients, and due to the absence of compounds, such as sodium dimethyldithiocarbamate, which may lead to incorporation of varying amounts of vulcanization accelerators in the rubber product, the amounts varying with actual manufacturing conditions. It will be appreciated that another aspect of the present invention is formed by a polymeric product, obtained according to the hereinbefore specified process of the present invention. Said polymeric product is substantially free of compounds from which during manufacturing and subsequent compounding and additional processing steps, carcinogenic nitrosamines may be formed. It will be appreciated that this feature forms an additional advantage of the process of the present invention. The following examples illustrate the present invention, however without restricting the scope to these embodiments. Example 1 Styrene and butadiene are polymerized into polymer having a 23/77 ratio, in a 10 l reactor in an aqueous emulsion prepared by means of a 50/50 mixture of fatty acid/rosin acid soap (concentration 4% by weight on monomers). As initiator system ferrosulphate/sodium formaldehyde sulphoxylate/paramenthane hydroperoxide is used in amounts of : ferrosulphate 0.007 phm; sodium formaldehyde sulphoxylate (SFS) 0.04 phm; paramenthanehydroperoxide (PMHP) 0.03 phm; calculated relative to the 100 parts by weight of initially charged monomers. As modifier is used tert.dodecyl mercaptan (0.11 phm) and the polymerization is carried out at 5 °C until 60% conversion. Then 0.05 parts by weight of sodium polysulphide Na 2 S x wherein x has a value of about 4, per 100 parts by weight of monomers are added to a part of said polymerization mixture, (A), whereas to another part of said mixture a conventional shortstopping agent is added, comprising : 0.015 phm sodium polysulphide 0.04 phm sodium nitrite 0.10 phm sodium dimethyldithiocarbamate (SDD) (B). The polymerization mixture still containing the non-converted monomers, is subsequently heated to 50 °C. For both recipes no increase in Mooney viscosity (MV) of the rubber or increase in solid content (i.e. conversion) is observed, as may be derived from the following Table 1 : → hrs after addition of shortstop recipe shortstop 0 3 6 9 12 MV 118 122 124 127 124 A 0.10 phm SDD % solids 23.7 23.4 23.4 23.6 23.1 0.015 phm Na 2 S 4 0.04 phm NaNO 2 MV 121 125 125 128 122 B 0.05 phm Na 2 S 4 % solids 23.9 23.6 23.5 23.6 23.7 The respective nitrosamine content of rubber produced appear to be A 500 µg dimethylnitrosamine (DMNA)/kg copolymer B <10 µg DMNA/kg copolymer. Example 2 A styrene/butadiene mixture is polymerized in a continuous process in a series of reactors into a polymer containing 23% by weight of styrene and 77% by weight of butadiene, at 5 °C until a conversion degree of 60% is reached, using as initiator system and as emulsifier those ones specified in Example 1. After addition of shortstop the latex (still containing non-converted monomers) is kept at ambient temperature (25 °C) for several days, and the Mooney viscosity and solids content are measured as summarized in Table 2: → hrs after addition of shortstop recipe 0 2 0.10 phm SDD MV 124 122 A 0.015 phm Na 2 S 4 % solids 25.6 26.3 0.04 phm NaNO 2 B 0.015 phm Na 2 S 4 MV 124 120 % solids 25.6 26.5 C 0.15 phm DSEC MV 124 143 % solids 25.6 32.4 Example 3 A styrene/butadiene polymer containing 23.5% by weight styrene and 76.5% by weight 1,3-butadiene based on the total weight of the polymer and 27.5% by weight extender oil (based on copolymer weight) is prepared by a continuous polymerization at 5 °C using the emulsifier, initiator system and modifier as specified in Example 1. After a conversion of 60% the polymerization is shortstopped according to the present invention and according to prior art and the unconverted butadiene and styrene monomers are removed at 25 °C and 70 °C respectively; finally the rubber was recovered from the latex after mixing with extender oil. The Mooney viscosity and nitrosamine content of the product have been summarized in Table 3. recipe latex MV at shortstop dosing latex MV after removal of monomers MV end product end product nitrosamine content DMNA 0.16 phm SDD 125 120 50 700 0.015 phm Na 2 S 4 µg/kg 0.04 phm NaNO 2 0.05 phm Na 2 S 4 127 122 48 <10 µg/kg Conclusion: No differences in shortstopping efficiency occur, whereas the nitrosamine content is reduced to below 10 µg/kg. Example 4 In a rather similar way as described for Example 3 (excepted the use of extender oil), a styrene/butadiene copolymer, containing 22.5% by weight styrene and 77.5% by weight butadiene, is produced, using a pure rosin acid soap emulsifier. The polymerization reaction is shortstopped at a conversion degree of 64%, by using the two shortstopping recipes given in Table 4 for different parts of the same batch. The respective Mooney viscosities and nitrosamine contents of the obtained products have been indicated in Table 4. recipe latex MV at shortstop dosing latex MV after removal of monomers MV end product DMNA content µg/kg 0.24 phm SDD 55 53 51 8000 0.015 phm Na 2 S 4 0.04 phm NaNO 2 0.05 phm Na 2 S 4 54 51 51 <10 Conclusion: No differences in shortstopping efficiency occur; the DMNA content is largely reduced. Example 5 In a rather similar way as described in Example 3, a styrene/butadiene copolymer, containing 31% by weight styrene and 69% by weight of butadiene, based on the weight of the copolymer and 27.5% extender oil based on copolymer weight, is produced. The polymerization reaction is shortstopped at a conversion degree of 60%, by using two different shortstopping agents for different parts of the same batch. The respective Mooney viscosities and nitrosamine contents of the obtained products have been listed in Table 5: recipe latex MV at shortstop dosing latex MV after removal of monomers MV end product DMNA content µg/kg 0.16 phm SDD 140 137 51 425 0.015 phm Na 2 S 4 0.04 phm NaNO 2 0.05 phm Na 2 S 4 136 136 52 <10 Conclusion: No differences in shortstopping efficiency of the two recipes can be noticed whereas the DMNA content is largely reduced. Example 6 In a rather similar way as described in Example 3 a styrene/butadiene copolymer, containing 23% by weight styrene and 77% by weight of butadiene, is prepared. After a conversion degree of 64%, the copolymerization is shortstopped by using several agents known from prior art and one according to the present invention, and the latex (still containing the non-converted monomers), was stored at 25 °C for several days. The respective Mooney viscosities at the beginning and after 48 hours are listed in the subsequent Table 6: MV MV recipe 0 hrs 48 hrs SDD 0.09 phm A Na 2 S 4 0.015 phm 47 50 NaNO 2 0.04 phm B SDD 0.20 phm 47 51 C Na 2 S 4 0.015 phm 47 49 D Na 2 S 2 O 4 0.20 phm 47 88 E Na 2 S 2 O 4 0.10 phm 47 95 NaHSO 3 0.10 phm From these data it may be concluded that the recipes A, B and C are equally efficient and that recipes D and E do not show adequate shortstopping of the reaction.

Claims: A process for shortstopping a free radical polymerisation of a conjugated diene and optionally a vinyl-substituted aromatic, in an aqueous emulsion polymerisation process conducted at a temperature of form -20°C to 70°C using a hydroperoxide as initiator and a redox activator system, comprising a ferro compound, a reducing agent and optionally a chelating agent, the polymerisation process optionally being carried out in the presence of a modifying agent, characterised in that as sole shortstopping agent an alkalimetal polysulphide of the formula Me2Sx, wherein x has a value in the range of from 2.5 to 4.5, and wherein Me represents an alkali metal, is used in an amount of from 0.01 to 0.5 parts by weight per hundred parts by weight of the total monomers, initially charged to the polymerisation system. A process according to claim 1, characterised in that the shortstoppping agent is used in an amount of from 0.04 to 0.06 parts by weight per hundred parts by weight of monomers. A process according to claims 1 and 2, characterised in that the copolymerization of butadiene 1,3 and styrene is shortstopped. A process according to claim 1, characterised in that x has a value of about 4. A process according to claim 1, characterised in that Me represents sodium. A process according to claim 1, characterised in that ferrosulphate is used. A process according to claims 1-6, characterised in that sodium formaldehyde sulphoxylate is used as reducing agent. A process according to claims 1-7, characterised in that a chelating agent is used selected from the group consisting of sodium ethylenediamine tetraacetate (EDTA), sodium silicate, sodium pyrophosphate or sodium polyphosphate. A process according to claim 8, characterised in that the chelating agent is EDTA. A process according to claim 1, characterised in that an activator system is used, comprising; from 0.001 to 0.04 parts by weight ferrosulphate; from 0.01 to 0.2 parts by weight of a sulphoxylate; and from 0.005 to 0.2 parts by weight of a chelating agent, per 100 parts by weight of initially charged monomers. A process according to claim 14, characterised in that a combination of ferrosulphate, sodium formaldehyde sulphoxylate and EDTA is used. A process according to claim 1, characterised in that for the polymerisation an initiator is selected from the group consisting of paramenthane hydroperoxide, diisopropyl toluene hydroperoxide, cumene hydroperoxide, pinane hydroperoxide, diisopropylbenzene hydroperoxide, p-tert. butyl cumene hydroperoxide, hydrogen peroxide, 1,1-diphenylethane hydroperoxide or mixtures thereof. A process according to claim 12, characterized in that the initiator has been used in an amount of from 0.01 to 0.4 parts by weight per 100 parts by weight of monomers. A process according to claims 12 and 13, characterised in that paramenthane hydroperoxide is used. A process according to claim 1, characterised in that as modifier for the preceding (Co)polymerisation process to be shortstopped is used a compound selected from tert.dodecyl mercaptan, n-dodecyl mercaptan, tert.hexadecylmercaptan, xanthogendisulphides, thioethers and thiophosphates. A process according to claim 15, characterised in that tert.dodecyl mercaptan is used as modifier. A process according to claims 1 to 16, characterised in that copolymers of conjugated diene and vinyl-substituted aromatic in a monomer weight ratio in the range of from 80 : 20 to 50 : 50, are prepared. A polymeric product when obtained according to the process of claims 1 to 17, being substantially free of compounds, from which during manufacturing and subsequent compounding and additional processing steps carcinogenic nitrosamines may be formed.

Inventors: DE VRIES SIJTSKE MINNIE, WILLEMSEN JOHANNES ARNOLDUS MA, DE VRIES, SIJTSKE MINNIE, WILLEMSEN, JOHANNES ARNOLDUS MARIA
Applicants: SHELL INT RESEARCH, SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
Application year: 1991
Main classification: C08F2
IPC codes: C08F2, C08F36