Method for producing a semiconductor device with gate structure

Abstract: A semiconductor device includes a field effect transistor provided with source and drain areas formed in the main surface side of a semiconductor substrate and a gate electrode provided on the main surface across a gate insulation film. The gate electrode comprises a first electrode portion having an electron donating surface; and a second electrode portion consisting of a metal formed on the electron donating surface.

Description: The present invention relates to a method for producing a semiconductor device such as a memory, a photoelectric converter device, a signal processing device or the like, for use in various electric appliances. In recent efforts toward the higher level of device integration, there has been desired the development of miniaturized functional devices such as MOS transistors with submicron gate length. On the other hand, an improvement in the voltage resistance characteristics is longed for, as such miniaturization tends to cause concentration of the electric field in the vicinity of drain. In order to prevent the avalanche breakdown in the vicinity of the drain when a high voltage is applied thereto, there has been employed a light doped drain (LDD) structure, in which a drain area of a low doping concentration is formed adjacent to the drain area, thereby relaxing the electric field around the drain. Figs. 1A to 1C schematically illustrate the conventional process for forming the drain area of low doping concentration. At first, as shown in Fig. 1A, a gate insulation film 2 is formed on a silicon substrate 1, then a polycrystalline silicon gate film 3 and a photoresist layer 4 are patterned, and phosphorus is implanted with a high concentration, utilizing the photoresist 4 as a mask. Then as shown in Fig. 1B, a photoresist pattern 5 is formed, and phosphorus is implanted with a low concentration, utilizing said photoresist 5 as a mask. Finally, as shown in Fig. 1C, an intermediate insulation film 6 is formed by an ordinary method, and an annealing treatment is applied. There are thus conducted formation of a source area 7, a high-concentration drain area 8, a low-concentration drain area 9, a channel area 10 and electrodes 11. In the above explained conventional example, however, the low-concentration drain area 9 is formed, after the impurity implantation into the silicon substrate 1 through the photoresist mask for forming the drain area 8, by implanting an impurity of the same conductive type as that of the drain area 8 into an area of the silicon substrate 1 between the drain area 8 and the channel area 10. Consequently, depending on the accuracy of alignment, the width of said low-concentration drain area 9, present between the channel area 10 and the drain area 8, fluctuates inevitably, so that a fluctuation in the drain voltage resistance has been unavoidable, as will be explained later. Figs. 2A and 2B show the relationship between the offset and the drain voltage resistance, wherein the offset L1 is, as shown in Fig. 2A, the distance from a lateral wall of a gate 3 to the boundary between the low-concentration drain area 9 and the high-concentration drain area 8. As shown in Fig. 2B, the drain voltage resistance increases linearly with said offset L1. In the conventional process, the standard deviation of the precision of alignment is 0,3µ m. Consequently the offset L1 inevitably involves a fluctuation of 0.3 µm, which brings about a fluctuation of about 5 V in the drain voltage resistance. On the other hand, for reducing the signal delay time, it has been proposed to form the gate electrode and its wiring with silicide (silicon metal alloy) or with a polycide structure (laminate structure of polycrystalline silicon and silicide film) thereby reducing the specific resistivities thereof. However, such silicide or polycide structure of the gate for achieving a high speed still requires improvements in the following points, in order to achieve production of the currently required miniaturized semiconductor devices of high-speed function with a high production yield. More specifically, the conventional silicide structure has been associated with the following drawbacks: (1) that the threshold voltage (V th ) of the MOS device varies depending on the work function of the silicide; and (2) that a metal from the silicide diffuses into the gate oxide film 5, thereby deteriorating the MOS transistor. On the other hand, the polycide structure has also been associated with the following drawbacks: (3) that the specific resistivity can only be reduced to ca. 3 Ω/□ ; and (4) that an insulation film or a precipitated impurity film, if present at the interface between the polycrystalline silicon and silicide, may result in a significant deterioration of the gate voltage resistance or a peeling of the silicide film, called pest phenomenon. It is mentioned that CVD deposition of refractory metal silicides for use as gate electrodes in place of polysilicon electrodes are described in Solid State Technology, vol. 32, No. 2, February 1989, pp 79-84, C. Bernard et al, "Chemical vapour deposition of refractory metal silicides for VLSI metallisation". A method of producing an MOS transistor of LDD structure is described in United States Patent US 4,597,824. This method comprises the steps of: forming a first gate electrode; forming a low impurity concentration region using the first gate electrode as a mask; forming a second gate electrode; and forming a high impurity concentration region using the second gate electrode as a mask. A specific example is given wherein the first gate electrode is of polysilicon and the second gate electrode formed thereon is of tungsten. The tungsten is deposited by a selective CVD process using hydrogen gas and tungsten hexafluoride gas as reagent gases. United Kingdom patent application GB-A-2195663 also describes a process in which a second gate electrode of aluminium, tungsten or molybdenum is formed on a first gate electrode of polysilicon. Subsequently contacts and wiring are produced by a two stage process in which the contacts are formed by selective deposition using triisobutyl aluminium and wiring is produced by sputtering and patterning. In the case of tungsten deposition on polysilicon, hydrogen gas and tungsten hexafluoride are used as reagent gases. In initial stage of the second gate electrode growth a silicon reduction reaction occurs before the hydrogen reduction reaction occurs. This results in an initial erosion of the polysilicon first gate electrode. Brief reference is also made to thin solid films, Vol. 45, 1977, pp 257-263, H.O. Pierson "Aluminium coatings by the deposition of alkyls". This describes deposition of aluminium on steel based on the decomposition of either diethyl aluminium hydride or diisobutyl aluminium hydride in the presence of ethylene or isobutylene, respectively. Patent Abstracts of Japan, Vol. 10, No. 108 (E-398) (2165), 23 April 1986 and JP-A-60245281 describes a method of producing an MOS transistor having LDD structure in which second gate electrode material is grown by selective deposition and extends from the lateral faces of the first gate electrode. The second gate electrode is used as a mask during a first impurity doping step and then is removed prior to a second and light concentration doping step. The present invention is intended to provide a method for producing a semiconductor device in which the low impurity concentration region of an LDD drain structure can be produced with satisfactory precision in a self aligned manner and thus contributes to achieving better withstand voltage device performance and reduced variance therein. It is provided as an alternative to the method described in U.S. patent US-A-4597824 mentioned above. The method in accordance with the present invention is characterised in that: the step of forming the second gate electrode is performed by a selective CVD process using as reagent gases hydrogen gas and a gas selected from the following: TiCl₄, Cu(C₁₁H₁₉0₂)₂; Cu(C₅H₇0₂)₂; W(CH₃)₃; W(C₂H₅)₃; Mo(CO)₆; monomethyl aluminium hydride, dimethyl aluminium hydride, or other alkylaluminium hydride, wherein the first gate electrode is one of the following electroconductive materials: poly-silicon; amorphous silicon, monocrystalline silicon; tungsten; molybdenum; tantalum; copper; titanium; aluminium; titanium-aluminium; titanium nitride; aluminium-silicon-copper; aluminium-palladium; tungsten silicide; titanium silicide; aluminium silicide; molybdenum silicide and tantalum silicide. Notably polysilicon is included in the list of electron donative first gate electrode materials listed above. It is preferable that one of the metals Ti, Cu, W, Mo or Al is deposited to form the second gate electrode and that this metal is retained as metal, at least in part, during subsequent processing. The subsequent processing would ordinarily include a step of annealing during which the impurities are activated. The method above defined results in uniform and reproducible production of the second gate electrode material as a mask. This method does not rely on etch back so even a relatively complex LED structure can be manufactured stably and with high production yield. Where, as preferred, metal is deposited as the second gate electrode material, response speed is improved since the specific resistivity of the gate electrode is significantly reduced compared to e.g. polysilicon or metal silicide. The aforesaid method enables production of a transistor of LDD structure at low cost and at a high production yield. In the preferred embodiments described below improvement is found in threshold voltage, gate resistance and gate withstand voltage. To further understanding of the present invention specific embodiments will now be described and reference will be made to the accompanying drawings in which: Figs. 1A to 1C are cross-sectional views showing a conventional structure; Figs. 2A and 2B are views showing the relationship between the offset and the drain voltage resistance; Figs. 3A to 3D are schematic views showing the process for producing a semiconductor device of the present invention; Figs. 4A and 4B (deleted); Figs. 5 to 8 are views showing an example of the apparatus adapted for use in the producing method of the semiconductor device of the present invention; Figs. 9A to 9D are schematic perspective views showing the steps of forming a first wiring layer in a method for producing a semiconductor device according to the present invention; Figs. 10A to 10F (deleted); Fig. 11A is a schematic plan view of an inverter circuit; and Fig. 11C is a cross-sectional view, along a line A-A in Fig. 7A, showing an NMOS device. The following description of the preferred embodiments is given by way of example only. This method will be explained in greater details in the following with reference to Figs. 3A to 3D, in which a part of an N-channel MOS transistor is taken as the example, but the present invention is not limited to such example. At first, on a main surface of a silicon substrate, there are formed a P-well 501, an active area therein defined by a field oxide film 502, and a gate electrode 504 of polycrystalline silicon, provided on a gate oxide film 503, by means of ordinary thermal oxidation, LOCOS, thermal diffusion, polycrystalline deposition, photolithography etc. known in the semiconductor technology. Then impurity ions are implanted, utilizing the gate electrode 504 as the mask, to form a diffusion area 505 of a low impurity concentration (Fig. 3A). Subsequently a tungsten film 506 is selectively deposited solely on the upper and lateral faces of the polycrystalline silicon film 504, utilizing for example W(CH₃)₃ and H₂ as the reaction gases (Fig. 3B). Then ion implantation is conducted with the tungsten film 506 as the mask, thereby protecting an area 505′ covered by the tungsten film 506 from the impurity implantation and thus forming a high impurity concentration diffusion area 507 in a position retracted from the lateral face of the polycrystalline silicon film 504 (Fig. 5C). Then an interlayer insulation film 508 is deposited, and contact holes 509 are opened, at the positions of source/drain electrodes, by an ordinary patterning method used in the semiconductor process. Subsequentlyaluminium is selectively deposited into the contact holes 509, utilizing for example alkylaluminium hydride such as DMAH and H₂ gas (Fig. 3D). The MOS transistor with the LDD structure can be completed by thereafter forming wiring for example by sputtering. (Description of Al-CVD method) The Al-CVD method will be explained in the following, principally for the metal deposition in an aperture, but this method is applicable within the technical concept of the present invention, and the following description will be effective in understanding the superiority of the film quality obtained by said method. (Film forming method) This film forming method also is suitable for forming the metal mask of the above-explained structure. This method consists of forming a deposited film by a surface reaction on an electron donating substrate, utilizing alkylaluminium hydride gas and hydrogen gas (hereinafter called Aℓ-CVD method). An aluminium film of satisfactory quality can be deposited by heating the surface of the substrate in the presence of a gaseous mixture particularly consisting of alkylaluminium hydride such as monomethylaluminium hydride (MMAH) or dimethylaluminium hydride (DMAH) as the raw material gas and hydrogen gas as the reaction gas. At the selective deposition of aluminium, the surface temperature of the substrate is preferably maintained, by direct or indirect heating, within a range from the decomposition temperature of alkylaluminium hydride to 450°C, more preferably from 260° to 440°C. The heating of the substrate in the above-mentioned temperature range may be achieved by direct or indirect heating, but formation of an Aℓ film of satisfactory quality can be achieved with a high deposition speed, particularly by direct heating. For example, with the more preferred temperature range of 260° - 440°C, a satisfactory film can be obtained with a deposition speed of 300 - 5000 Å/min. which is higher than in the resistance heating. Such direct heating (substrate being heated by direct transmission of energy from the heating means) can be achieved by heating with a lamp such as a halogen lamp or a xenon lamp. Also indirect heating may be achieved for example by resistance heating, conducted by a heat generating member provided in a substrate support member, for supporting the substrate to be subjected to film deposition, provided in a film deposition space. This method, if applied to a substrate having both an electron donating surface area and an electron non-donating surface area, allows to form single crystal of aluminium with satisfactory selectivity solely on the electron donating surface area. Such aluminium is excellent in all the properties required for the electrode/wiring material, including a low hillock frequency and a low alloy spike frequency. The electron donating surface means a surface formed by an electron donating material, and the electron non-donating surface means a surface formed by an electron non-donating material. These materials will be explained in detail in the following. The electron donating material means a material in which free electrons are present or intentionally generated and which has a surface capable of accelerating a chemical reaction by electron transfer with the molecules of raw material gas deposited onto said surface. In general metals and semiconductive materials fall into this category. Also metals and semiconductors having a thin oxide film on the surface belong to the electron donating materials of the present invention since a chemical reaction can take place by electron transfer between the substrate and the deposited molecules of the raw material. Examples of such electron donating material include III-V compound semiconductors of two-, three- or multiple-element system obtained by combining element(s) of the group III such as Ga, In, Aℓ etc. and element(s) of the group V such as P, As, N etc.; P, I and N-type semiconductors such as monocrystalline silicon and amorphous silicon; and metals, alloys and silicides such as tungsten, molybdenum, tantalum, copper, titanium, aluminium -titanium-aluminium, titanium nitride, aluminium -silicon-copper, aluminium-palladium, tungsten silicide, titanium silicide, aluminium silicide, molybdenum silicide and tantalum silicide. On the other hand, the electron non-donating material is a material forming a surface not causing selective deposition of Aℓ or Aℓ-Si, and examples of such material include silicon oxide formed by thermal oxidation or CVD; glasses, oxide films and thermal nitride films such as BSG, PSG and BPSG; and silicon nitride formed by plasma CVD, low pressure CVD or ECR-CVD. Such excellent properties are obtained presumably because the semiconductive or conductive surface constituting an electron donating surface can selectively develop an aluminum film of satisfactory quality, and excellent crystalline character of said Aℓ film excludes or significantly reduces the alloy spike formation etc. resulting from an eutectic reaction with the underlying silicon. Such Aℓ film, when employed as an electrode of a semiconductor device, provides the advantages far exceeding the concept of the conventional Aℓ electrode and not anticipated in the prior art. As explained above, the Aℓ deposited in an aperture with an electron donating surface, for example an aperture formed in an insulating film and exposing the surface of a semiconductor substrate therein, has a monocrystalline structure. Besides said Aℓ-CVD method can achieve selective deposition of following metal films principally composed of aluminium with similarly satisfactory quality. For example, the electrode may be formed by selective deposition of various conductive materials such as Aℓ-Si, Aℓ-Ti, Aℓ-Cu, Aℓ-Si-Ti or Aℓ-Si-Cu by the use of a mixed gaseous atmosphere employing, in addition to alkylaluminium hydride gas and hydrogen, a suitable combination of: Si-containing gas such as SiH₄, Si₂H₆, Si₃H₈, Si(CH₃)₄, SiCℓ₄, SiH₂Cℓ₂ or SiHCℓ₃; Ti-containing gas such as TiCℓ₄, TiBr₄ or Ti(CH₃)₄; and/or Cu-containing gas such as copper bisacetylacetonate Cu(C₅H₇O₂)₂, copper bisdispivaloylmethanite Cu(C₁₁H₁₉O₂)₂, or copper bishexafluoroacetylacetonate Cu(C₅HF₆O₂)₂. Also since said Aℓ-CVD method is excellent in selectivity and provides satisfactory surface characteristics on the deposited film, there can be obtained a metal film suitable and widely usable for the wirings of a semiconductor device, by employing a non-selective film forming method in a next deposition step to form a metal film composed solely or principally of aluminium not only on the selectively deposited aluminium film mentioned above but also on the SiO₂ insulation film. Examples of such metal films include combinations of selectively deposited Aℓ, Aℓ-Si, Aℓ-Ti, Aℓ-Cu, Aℓ-Si-Ti or Aℓ-Si-Cu and non-selectively deposited Aℓ, Aℓ-Si, Aℓ-Ti, Aℓ-Cu, Aℓ-Si-Ti or Aℓ-Si-Cu. Said non-selective film deposition may be achieved by CVD other than the aforementioned Aℓ-CVD, or by sputtering. (Film forming apparatus) In the following there will be explained a film forming apparatus suitable for the electrode formation. Figs. 5 to 7 schematically illustrate a continuous metal film forming apparatus suitable for executing the film forming method explained above. As shown in Fig. 5, said apparatus is composed of a load lock chamber 311, a CVD reaction chamber (first film forming chamber) 312, an Rf etching chamber 313, a sputtering chamber (second film forming chamber) 314 and a load lock chamber 315, which are rendered sealable from the external atmosphere and mutually communicatable by means of gate valves 310a - 310f and can be respectively made vacuum or reduced in pressure by vacuum systems 316a - 316e. The load lock chamber 311 is used for eliminating the atmosphere of substrate and replacing it with H₂ prior to the deposition, in order to improve the throughput. The next CVD reaction chamber 312, for selective deposition onto the substrate under normal or reduced pressure, is provided therein with a substrate holder 318 with a resistance heater 317 for heating the substrate surface subjected to film formation at least within a temperature range of 200° - 450°C, and receives the raw material gas such as of alkylaluminium hydride, which is gasified by bubbling with hydrogen in a bubbler 319-1, through a raw material gas supply line 319, and hydrogen as the reaction gas through a gas line 319′. The Rf etching chamber 313, for cleaning (etching) of the substrate surface in Ar atmosphere after the selective deposition, is provided therein with a substrate holder 320 capable of heating the substrate at least within a range of 100° - 250°C and an Rf etching electrode line 321, and is connected to an Ar gas supply line 322. The sputtering chamber 314, for non-selective deposition of a metal film by sputtering in Ar atmosphere, is provided therein with a substrate holder 323 to be heated at least within a range of 200° - 250°C and a target electrode 324 for mounting a sputtering target 324a, and is connected to an Ar gas supply line 325. The final load lock chamber 315, for adjustment of the substrate after metal film deposition and prior to the exposure to the external atmosphere, is designed to be capable of replacing the atmosphere with N₂. Fig. 6 shows another example of the continuous metal film forming apparatus, wherein same components as those in Fig. 5 are represented by same numbers. The apparatus in Fig. 6 is different from that in Fig. 5 in that the substrate surface is directly heated by halogen lamps 330, and, for this purpose, the substrate holder 312 is provided with projections 331 for supporting the substrate in a floating state. Direct heating of the substrate surface with such structure further increases the deposition speed as explained before. The continuous metal film forming apparatus of the above-explained structure is equivalent, in practice, to a structure shown in Fig. 7, in which the load lock chamber 311, CVD reaction chamber 312, Rf etching chamber 313, sputtering chamber 314 and load lock chamber 315 are mutually combined by a transport chamber 326. In this structure, the load lock chamber 311 serves also as the chamber 315. In said transport chamber 326, there is provided an arm 327 constituting transport means, rotatable in both directions A-A and extendable and retractable in directions B-B, whereby the substrate can be transferred in succession from the load lock chamber 311 to the CVD reaction chamber 312, Rf etching chanmber 313, sputtering chamber 314, and finally to the load lock chamber 315 without exposure to the external atmosphere, as indicated by arrows in Fig. 8. (Film forming process) Now there will be explained the film forming process for forming the electrodes and wirings according to the present invention. Figs. 9A to 9E are schematic perspective views showing a film forming procedure for forming electrodes and wiring. At first the outline of the procedure will be described. A semiconductor substrate with an insulating film, having apertures therein, is placed in the film forming chamber, and the surface thereof is maintained for example at 250° - 450°C. Thermal CVD conducted in a mixed atmosphere of DMAH gas as alkylaluminium hydride and hydrogen gas causes selective deposition of Aℓ on the semiconductor exposed in the apertures. There may naturally be conducted selective deposition of a metal film principally composed of Aℓ, for example Aℓ-Si, by introduction for example of Si-containing gas, as explained before. Then a metal film composed solely or principally of Aℓ is non-selectively formed by sputtering, on the selectively deposited Aℓ and on the insulation film. Subsequently the non-selectively deposited metal film is patterned into the shape of desired wiring, thereby obtaining the electrodes and the wiring. This procedure will be explained in greater detail with reference to Figs. 6 and 9A to 9E. At first prepared is a substrate, consisting for example of a monocrystalline silicon wafer bearing thereon an insulation film, in which apertures of different sizes are formed. Fig. 9A schematically illustrates a part of said substrate, wherein shown are a monocrystalline silicon substrate 401 constituting a conductive substrate; a thermal silicon oxide film 402 constituting an insulation film; and apertures 403, 404 of different sizes. The formation of Aℓ film, constituting a first wiring layer, on the substrate is conducted in the following manner, with the apparatus shown in Fig. 6. At first the above-explained substrate is placed in the load lock chamber 311, in which hydrogen atmosphere is established by introduction of hydrogen as explained before. Then the reaction chamber 312 is evacuated by the vacuum system 316b approximately to 10⁻⁶ Pa (1x10⁻⁸ Torr), though Al film formation is still possible at a higher pressure. Then DMAH gas obtained by bubbling is supplied from the gas line 319, utilizing H₂ as the carrier gas. Also hydrogen as the reaction gas is introduced from the second gas line 319′, and the interior of the reaction chamber 312 is maintained at a predetermined pressure, by the adjustment of an unrepresented slow leak valve. A typical pressure is about 2.0x10² Pa (1.5 Torr). DMAH is introduced into the reaction chamber from the DMAH line, with a total pressure of about 2.0x10²Pa (1.5 Torr). Then the halogen pressure of about 6.7x10⁻¹ Pa (5.0 x 10⁻³ Torr). Then the halogen lamps 330 are energized to directly heat the wafer, thereby causing selective Aℓ deposition. After a predetermined deposition time, the DMAH supply is interrupted. Said deposition time is so selected that the Aℓ film on Si (monocrystalline silicon substrate 1) becomes equally thick as SiO₂ (thermal silicon oxide film 2), and can be experimentally determined in advance. In this process, the substrate surface is heated to ca. 270°C by direct heating, and the procedure explained above causes selective deposition of an Aℓ film 405 in the aperture, as shown in Fig. 9B. The foregoing is called a first film forming step for forming an electrode in an aperture. After said first film forming step, the CVD reaction chamber 312 is evacuated, by the vacuum system 316b, to a pressure not exceeding 6.7x10⁻¹ Pa (5x10⁻³ Torr). Simultaneously the Rf etching chamber 313 is evacuated to a pressure not exceeding 6.7x10⁻⁴Pa (5x10⁻⁶ Torr ). After confirmation of said evacuations of the chambers, the gate valve 310c is opened, then the substrate is moved from the CVD reaction chamber 312 to the Rf etching chamber 313 by the transport means, and said gate valve is closed. The Rf etching chamber 313 is evacuated to a pressure not exceeding 10⁻⁴ Pa (10⁻⁶ Torr), and is then maintained in an argon atmosphere of 10-10⁻¹ Pa (10⁻¹-10⁻³ Torr) by argon supply from the supply line 322. The substrate holder 320 is maintained at ca. 200°C, and an Rf power of 100 W is supplied to the Rf etching electrode 321 for about 60 seconds to generate an argon discharge in said chamber 313, whereby the substrate surface is etched with argon ions and the unnecessary surfacial layer of the CVD deposited film can be elimianted. The etch depth in this case is about 10 nm (100Å), corresponding to the oxide film. Said surface etching of the CVD deposited film, conducted in the Rf etching chamber, may be dispensed with since said surfacial layer is free from oxygen etc. as the substrate is transported in vacuum. In such case, the Rf etching chamber 313 may serve for varying the temperature within a short time if there is a significant temperature difference between the CVD reaction chamber 312 and the sputtering chamber 314. After said Rf etching, the argon supply is terminated, and the Rf etching chamber 313 is evacuated 6.7x10⁻⁴ Pa to 5x10⁻⁶ Torr. Then the sputtering chamber is also evacuated 6.7x10⁻⁴ Pa to 5x10⁻⁶ Torr or lower, and the gate valve 310d is opened. The substrate is transferred from the Rf etching chamber 313 to the sputtering chamber 314 by the transport means, and said gate valve 310d is closed. Subsequently the sputtering chamber is maintained at argon atmosphere of 10-10⁻¹ Pa (10⁻¹-10⁻³ Torr) as in the Rf etching chamber 313, and the substrate holder 323 is maintained at 200° - 250°C. Argon discharge is induced by a DC power of 5 - 10 kW to scrape the target of Aℓ or Aℓ-Si (Si: 0.5%) with argon ions, thereby depositing Aℓ or Aℓ-Si onto the substrate with a deposition speed of ca. 1000 nm/min (10000 Å/min). This is a non-selective deposition step, and is called a second film forming step for forming wirings connected to the electrodes. After the formation of the metal film of about 500 nm (5000 Å) on the substrate, the argon supply and the DC power application are terminated. The load lock chamber 311 is evacuated to a pressure of 6.7x10⁻¹ Pa (5x10⁻³ Torr) or lower, then the gate valve 310e is opened and the substrate is moved. After the gate valve 310e is closed, the load lock chamber 311 is supplied with nitrogen gas to the atmospheric pressure. Subsequently the gate valve 310f is opened and the substrate is taken out. The second Aℓ film deposition step explained above forms an Aℓ film 406 on the SiO₂ film 402, as shown in Fig. 9C. Subsequently said Aℓ film 406 is patterned as shown in Fig. 9D to obtain the wirings of desired shape. (Experimental examples) In the following there will be shown experimental results indicating the superiority of the above-explained Aℓ-CVD method and the satisfactory quality of the Aℓ film deposited by said method in the apertures. There were prepared plural substrates, each consisting of an N-type monocrystalline silicon wafer, provided thereon with a thermally oxidized SiO₂ film of a thickness of 800 nm (8000 Å), in which apertures of different sizes from 0.25 x 0.25 µm to 100 x 100 µm were formed by patterning to expose the underlying monocrystalline silicon (samples 1-1). These samples were subjected to the Aℓ film formation by the Aℓ-CVD method, employing DMAH as the raw material gas and hydrogen as the reaction gas, with a total pressure of 2.0x10² Pa (1.5 Torr) and a DMAH partial pressure of 6.7x10⁻¹ Pa (5.0x10⁻³ Torr), and with the substrate surface temperatures selected in a range of 200° - 490°C by direct heating under the regulation of electric power supplied to the halogen lamps. The obtained results are summarized in Table 1. As will be apparent from Table 1, aluminium was deposited in the apertures with a deposition speed as high as 300-500 nm/min (3000-5000 Å/min) at the substrate surface temperature of 260°C or higher obtained by direct heating. The Aℓ film in the apertures, obtained in a substrate surface temperature range of 260° - 440°C, showed satisfactory characteristics, with no carbon content, a resistivity of 2.8 - 3.4 µΩ cm, a reflectance of 90 - 95 %, a hillock (≧ 1 µm) density of 0 - 10 cm⁻², and an almost zero spike formation (frequency of destruction of 0.15 µm junction). On the other hand, though the film quality obtained in a surface temperature range of 200° - 250°C was somewhat inferior to that obtained in the temperature range of 260° - 440°C, it is considerably better than that obtainable with the conventional technology, but the deposition speed could not exceed 100-150 nm/min (1000-1500 Å/min) and the throughput was in a relatively low range of 7 - 10 wafer/hr. At the substrate surface temperature equal to or higher than 450°C, the quality of the Aℓ film in the apertures were deteriorated, with a reflectance of 60 % or lower, a hillock (≧ 1 µm) density of 10 - 10⁴ cm⁻² and an alloy spike formation of 0 - 30 %. In the following there will be explained how the above-explained method can be advantageously applied to apertures such as contact holes or through-holes. Said method can be advantageously applied to to the contact holes or through-holes composed of the materials explained in the following. The Aℓ film formation was conducted on the following substrates (samples) under the same conditions as in the Aℓ film formation on the above-mentioned samples 1-1. Samples 1-2 were prepared by forming, on monocrystalline silicon constituting a first substrate surface material, a silicon oxide film constituting a second substrate surface material by means of CVD method, and forming apertures by a photolithographic process to locally expose the surface of monocrystalline silicon. The SiO₂ film was 800 nm (8000 Å) thick, and the apertures were sized from 0.25 x 0.25 µm to 100 x 100 µm. (Such sample will hereinafter be represented as "CVD SiO₂ (or simply SiO₂)/monocrystalline silicon".) There were also prepared: a sample 1-3 of boron-doped oxide film formed by normal pressure CVD (hereinafter written as BSG)/monocrystalline silicon. a sample 1-4 of phosphorus-doped oxide film formed by normal pressure CVD (PSG)/monocrystalline silicon; a sample 1-5 of boron- and phosphorus-doped oxide film formed by normal pressure CVD (BSPG)/monocrystalline silicon; a sample 1-6 of nitride film formed by plasma CVD (P-SiN)/monocrystalline silicon; a sample 1-7 of thermal nitride film (T-Sin)/monocrystalline silicon; a sample 1-8 of nitride film formed by low pressure CVD (LP-SiN)/monocrystalline silicon; and a sample 1-9 of nitride film formed by ECD (ECR-SiN)/monocrystalline silicon. Further, samples 1-11 to 1-179 were prepared by taking all the combinations of the first surface materials of 18 kinds and the second surface materials of 9 kinds shown in the following. (It is to be noted that the sample numbers 1-10, 20, 30, 40, 50, 60, 70, 80, 90, 100, 110, 120, 130, 140, 150, 160, and 170 are lacking.) The first surface materials employed were monocrystalline silicon (mono-Si), polycrystalline silicon (poly-Si), amorphous silicon (a-Si), tungsten (W), molybdenum (Mo), tantalum (Ta), tungsten silicide (WSi),titanium silicide (TiSi), aluminium (Aℓ), aluminium silicon (Aℓ-Si), titanium aluminium (Aℓ-Ti), titanium nitride (Ti-N), copper (Cu), aluminium silicon copper (Aℓ-Si-Cu), aluminium, palladium (Aℓ-Pd), titanium (Ti), molybdenum silicide (Mo-Si), and tantalum silicide (Ta-Si). The second substrate surface materials employed were T-SiO₂, SiO₂, BSG, PSG, BPSG, P-SiN, T-SiN, LP-SiN and ECR-SiN. In all these samples, there could be obtained satisfactory Aℓ films comparable to those in the aforementioned samples 1-1. Subsequently, the Aℓ was non-selectively deposited by sputtering on the substrates subjected to the selective Aℓ deposition as explained above, and was then patterned. The Aℓ film obtained by sputtering and the selectively deposited Aℓ film in the apertures showed electrically and mechanically satisfactory contact, because of the improved surface state of the Aℓ film in the apertures. The Al-CVD method has been explained in relation to the deposition of a conductive material in a contact hole, but such selective deposition is not limited toaluminium and can also be conducted with other metals shown in Table 2. For example, in case of formation of a tungsten film on the substrate with W(CH₃)₃ gas and hydrogen gas, the surface temperature of the substrate is preferably maintained within a range from the decomposition temperature of W(CH₃)₃ to 700°C, more preferably from 350° - 400°C. A tungsten film of satisfactory quality can be obtained with a high deposition speed, by heating the substrate surface with lamps in the presence of a mixture of such gases. In such case, with the substrate surface temperature maintained in the more preferred range of 350° - 400 °C for W film formation, a film of satisfactory quality can be obtained with a deposition speed as high as 300-500 nm/min. (3000-5000 Å/min), which is higher than in the case of resistance heating. The above-explained selective depositing method is usable not only in the filling of the contact hole, but also advantageously in the formation of the above-explained gate electrode structure, since it can selectively deposit, utilizing its excellent selectivity, a metal on the upper and lateral faces of the first electrode portion. The metal film thus deposited by this method shows, like the metal film in the contact hole, excellent characteristics desirable for the electrode wirings of the semiconductor device. In the following there will be explained examples of the present invention, but it is to be understood that the present invention is by no means limited by such examples. (Example 1) This example describes an N-channel MOS transistor in an inverter circuit. Fig. 11A is a plan view of the inverter circuit, Fig. 11B is a circuit diagram thereof, and Fig. 11C is a cross-sectional view, along a line A-A in Fig. 11A, of an NMOS transistor portion in said inverter circuit. The NMOS transistor is formed in an area surrounded by a P-well 501 and a field oxide film 502. Low impurity concentration areas 505 are formed below and adjacent to a first electrode portion 504, composed for example of polycrystalline silicon and positioned on a gate oxide film 503 between the source and drain area. On the upper and lateral faces of said first electrode portion, a metal film 506 consisting of tungsten (W) is deposited by selective CVD to constitute a gate electrode. Below said metal film 506 there are formed high impurity concentration areas 507, and each of the source and drain areas is composed of a low impurity concentration area 505 and a high impurity concentration area 507. Corresponding to said areas of different impurity concentrations constituting the source and the drain, there are provided the first electrode portion 504 constituting the gate electrode and the metal film 506 covering said gate electrode and constituting a second electrode portion. The transistor surface is covered by an interlayer insulation film 508, and is connected to metal wiring 511 by conductive members 510 for example of aluminium filled in contact holes 509 for electrode contact with the source and the drain. In order to prevent formation of recesses in aluminium above such contact holes in the above-explained structure, it is effective to selectively deposit aluminium solely in the contact holes by the aforementioned CVD method, thereby filling the contact holes, then depositing the wiring material over the entire surface of the substrate, and patterning said wiring material to complete the wirings. In the following there will be explained the function of said MOS transistor, in which the conductance of a channel portion 512 between the source and the drain is controlled by the gate electrode 504, 506. With a voltage V G applied to the gate electrode and a voltage V D between the source and drain electrodes, a current I D flows therebetween according to the following equation: I D = C ox ·µ· W L {(V G - V th )V D - 1 2 V D ²} if V D < V G - V th′ or I D = 1 2 C ox ·µ· W L (V G - V th )² if V D > V G - V th′ wherein C ox is the gate capacitance, µ is the carrier mobility, W is the channel width, L is the channel length, V th is the threshold voltage, and V D is the voltage applied to the drain. Requirements for such MOS transistor are: 1) to relax the electric field intensity between the source and the drain, thereby suppressing the generation of hot electrons; 2) to achieve high-speed transistor functions; and 3) to enable stable manufacture of the transistor satisfying the foregoing requirements. In the present example, because of the selective deposition of the W film 506 with a uniform thickness of 150 nm (1500 Å) on the upper and lateral faces of the polycrystalline Si, the low impurity concentration area 505 produces from the high impurity concentration area 507 toward the channel portion 512, by a uniform width of ca. 0.15 µm, so that the production yield of the integrated circuit can be drastically improved in comparison with the conventional process utilizing an etch-back step. Also the gate electrode and the wirings practically have a three-layered structure of polycrystalline Si, WSi₂ and W, and the presence of the W film finally remaining with a thickness of about 120 nm (1200 Å) reduces the resistance of the gate electrode to about half. In the following the method for producing the NMOS transistor of the present example will be explained in greater detail, with reference to Figs. 3A to 3D. On a silicon substrate, there were formed the P-well 501, an active area surrounded by the field oxide film 502, the gate oxide film 503, and the gate electrode 504 of polycrystalline silicon, by ordinary methods such as thermal oxidation, LOCOS, thermal diffusion, polycrystalline deposition, photolithography etc. Then implantation of impurity ions was conducted, utilizing said gate electrode 504 as the mask, thereby forming the low impurity concentration area 505. The implantation was conducted with phosphorus a concentration of 2 x 10¹³ cm⁻², with thermal treatment of 15 minutes at 1000°C (Fig. 3A). Then the aforementioned selective deposition was conducted to deposit the W film 506 solely on the upper and lateral faces of the polycrystalline Si film 504, by employing W(CH₃)₃ and H₂ as the reaction gases with respective partial pressures of 3x10⁻² Pa (2x10⁻⁴ Torr) and 2x10² Pa (1.5 Torr) and heating the substrate at 380°C in the presence of said gases. The thickness of said W film 506 was 150 nm (1500Å) and uniform on the upper and lateral faces of the polycrystalline Si film 504, and showed little fluctuation among different substrates (Fig. 3B). Then ordinary ion implantation was carried out to form the high impurity concentration areas 505 in positions retracted by about 150 nm (1500Å) from the low impurity concentration areas 505, without impurity introduction ion the area covered by the W film 506. More specifically, arsine ions were implanted with a concentration of 5 x 10¹⁵ cm⁻², and rapid thermal annealing was conducted for 20 seconds at 1000°C for electric activation (Fig. 3C). A part of tungsten was converted into WSi₂ by this heat treatment, but the final profile, analyzed with SIMS, consisted of a polycrystalline Si film of 310 nm (3100Å), a WSi₂ film of 50 nm (500Å) and a W film of 120 nm (1200 Å). Then a BPSG film 508 was deposited with a thickness of 800 nm (8000 Å) as an interlayer insulation film, and contact holes 509 were opened in the positions of source and drain electrodes, by a method usually employed in the manufacture of semiconductor devices. Subsequently aluminium was selectively deposited solely in the contact holes 509, by means of the aforementioned selective deposition method utilizing DMAH and H₂, with a DMAH partial pressure of 2.0x10⁻² Pa (1.5x10⁻⁴ Torr), a total pressure of 2.0x10² Pa (1.5 Torr) and a substrate temperature of 270°C (Fig. 3D). Then the MOS structure was completed by forming the wirings by sputtering. The characteristics of thus obtained MOS transistor are as follows: (Example 2) The tungsten film in the foregoing example shown in Fig. 3 was replaced by a film of Ti, Cu, W or Mo by the aforementioned selective deposition method respectively utilizing TiCℓ₄ + H₂, Cu(C₁₁H₁₉O₂)₂ + H₂, W(C₂H₅)₃ + H₂ or Mo(Co)₆ + H₂. These metal films provided satisfactory results similar to that in the example shown in Fig. 3. (Example 3) The tungsten film in the foregoing example shown in Fig. 3 was replaced by an Aℓ film. More specifically, the Aℓ film was deposited with a thickness of 200 nm (2000 Å), under the conditions with a DMAH partial pressure of 2.0x10⁻²Pa (1.5x10⁻⁴), a H₂ partial pressure of 2.0x10² Pa (1.5 Torr) and a substrate temperature of 270°C. Then conducted was ion implantation as in the example 1 for forming a high impurity concentration area, and heat treatment was conducted for 10 minutes at 850°C in a diffusion furnace. Though the deposited aluminium was partly converted into alloy and partly evaporated, but the high impurity concentration area and the low impurity concentration area were mutually separated by a distance of about 1.5 µm at the interface, so that the MOS transistor with an LDD structure enough for preventing the deterioration by hot electrons could be obtained in stable manner. As explained in the foregoing, the present embodiment allows to form the lateral wall films, which are important components in the LDD structure, in uniform and stable manner without the conventional etch-back step, by selectively depositing a metal on the upper and lateral walls for example of a polycrystalline silicon electrode. It is therefore rendered possible to produce the LDD structure, as a countermeasure for hot electrons, in stable manner and with a high production yield, and also to obtain devices with improved surface flatness. Besides, a semiconductor device with improved response speed can be obtained, since the laminate structure of polycrystalline silicon and metal film significantly reduces the specific resistivity of the gate electrodes and the wiring therefor. Furthermore, compactization of the device can be achieved by the use of selection deposition in the deposition of metal on the gate electrodes and in the filling of the contact holes with a conductive material.

Claims: A method of producing a semiconductor device comprising a semiconductor substrate having source and drain regions defined therein, said drain region being of light doped drain structure and having thus a lower impurity concentration region (505′) and a higher impurity concentration region (507), a gate insulation film (503) on the semiconductor substrate, and a gate electrode of composite structure comprising a first gate electrode (504) located on said gate insulation film and a second gate electrode (506) on the upper and lateral faces of said first gate electrode (504), which method comprises the steps of: forming the gate insulation film (503) forming the first gate electrode (504); forming the low impurity concentration region (505′) using the first gate electrode (504) as a mask; forming the second gate electrode (506); and forming the high impurity concentration region (507) using the second gate electrode (506) as a mask; which method is characterised in that: the step of forming the second gate electrode (506) is performed by a selective CVD process using as reagent gases hydrogen gas and a gas selected from the following: TiCl₄, Cu(C₁₁H₁₉0₂)₂; Cu(C₅H₇0₂)₂; W(CH₃)₃; W(C₂H₅)₃; Mo(CO)₆; monomethyl aluminium hydride, dimethyl aluminium hydride, or other alkylaluminium hydride, wherein the first gate electrode is one of the following electroconductive materials: poly-silicon; amorphous silicon, monocrystalline silicon; tungsten; molybdenum; tantalum; copper; titanium; aluminium; titanium-aluminium; titanium nitride; aluminium-silicon-copper; aluminium-palladium; tungsten silicide; titanium silicide; aluminium silicide; molybdenum silicide and tantalum silicide. A method as claimed in claim 1 wherein the first gate electrode (504) is of polysilicon. A method as claimed in claims 1 or 2 wherein one of the metals Ti, Cu, W, Mo or Al is deposited by the selective CVD process. A method as claimed in any preceding claim comprising further steps of forming an insulation film (508) having an opening over said drain and an opening over said source; and filling each opening with metal by selective deposition. A method as claimed in claim 4 comprising a further step of: forming wiring on said metal and on said insulation film (508). A method as claimed in either of claims 4 or 5 wherein the step of filling by selective deposition is performed using hydrogen gas and an alkyl aluminium hydride gas as CVD reagent gases. A method as claimed in claim 5, or claim 6 depending from claim 5, wherein the filling by selective deposition is performed within a first chamber (312) and the forming of wiring is performed by non-selective deposition in a second chamber (314). A method as claimed in claim 7 wherein the substrate is transferred from the first chamber (312) to the second chamber (314) without it being exposed to the atmosphere. A method as claimed in claim 3 depending from claim 2 wherein at least part of said metal of said second gate electrode (506) is retained as metal following annealing processing.

Inventors: INOUE SHUNSUKE C O CANON KABUS, MATSUMOTO SHIGEYUKI C O CANON, MIYAWAKI MAMORU C O CANON KABU, NAKAYAMA JUN C O CANON KABUSHI, YUZURIHARA HIROSHI C O CANON K, INOUE, SHUNSUKE, C/O CANON KABUSHIKI KAISHA, MATSUMOTO, SHIGEYUKI, C/O CANON KABUSHIKI KAISHA, MIYAWAKI, MAMORU, C/O CANON KABUSHIKI KAISHA, NAKAYAMA, JUN, C/O CANON KABUSHIKI KAISHA, YUZURIHARA, HIROSHI, C/O CANON KABUSHIKI KAISHA
Applicants: CANON KK, CANON KABUSHIKI KAISHA
Application year: 1991
Main classification: H01L21
IPC codes: H01L21, H01L29