Cosmetic composition

Abstract: A cosmetic composition comprising fine particles coated with Pyrrole Black.

Description: The present invention relates to a cosmetic composition comprising a specified black pigment and an oil component, for use as a composition for temporarily dyeing the hair or a make-up composition for the eyelashes, eyebrows and skin. Ordinary compositions for dyeing the hair and makeup compositions for the eyelashes, eyebrows and skin contain carbon black or a black or brown pigment mainly comprising a metal oxide such as an iron oxide. However, it is known that the carbon black contains highly carcinogenic benzpyrene and, in addition, the metal oxides have problems that the blackness thereof is low, that its covering effect is insufficient and that its specific gravity is high. Under these circumstances, there have been various attempts to develop a black pigment harmless to the human body and having a high blackness (i.e. high covering effect). For example, JP-A-92273/1989 discloses a cosmetic composition comprising fine inorganic particles coated with a black pigment prepared by oxidative polymerization of 5,6-dihydroxyindole which is a melanin Precursor with hydrogen peroxide, a periodate or a transition metal salt. US-A-4,806,360 discloses a synthetic melanin aggregate prepared by oxidative polymerization of a melanin precursor such as dopa in a polymer network of a porous polymer. However, the cosmetic composition disclosed in JP-A-92273/1989 is not easy to prepare in practice, since 5,6-dihydroxyindole used as the starting material for the black pigment is a quite unstable compound. The color tone of the synthetic melanin aggregate disclosed in US-A-4,806,360 is browny black or reddish black so that its blackness is low. It is therefore the object underlying the persent invention to provide a cosmetic composition which is harmless to the human body, has a sufficiently high blackness and can be relatively easily synthesized. According to the present invention this object is attained with a cosmetic composition comprising fine particles having a diameter of 0.01 to 200µm coated with a pyrrole homopolymer and an oil component. The inventors have found that a black pigment comprising fine particles coated with pyrrole which is negative in the mutagenicity test by oxidative polymerization has a sufficiently high blackness, is utterly harmless to the human bodies and is relatively easily synthesized. The inventors have found also that since the surface of the black pigment is made hydrophobic by the pyrrole homopolymer, i.e. Pyrrole Black, it has a high affinity for oil components which are usually accepted as cosmetic ingredients and, therefore, when the pigment is used in combination with the oil components, sufficiently high covering effect, smoothness and spreadability can be obtained. The cosmetic composition of the present invention comprising the black pigment which is harmless to the human body, has a sufficiently high blackness and can be relatively easily synthesized, is suitably usable as a composition for temporarily dyeing the hair or a makeup composition for the eyelashes, eyebrows and skin. It is smooth, highly spreadable and easily usable. The fine particles (black pigment) coated with pyrrole homopolymer (Pyrrole Black) to be used in the present invention can be produced by a process described in A. Yassar et al., Polymer Communications, 28 , 103-104 (1987). In particular, they can be produced by dissolving pyrrole in, for example, water or a lower alcohol, dispersing the fine particles in the solution and adding dropwise an aqueous solution of a ferric salt to form a Pyrrole Black layer which is difficult to dissolve on the fine particle surface. The black pigment thus produced is isolated by filtration, washing with water, washing with ethanol, washing with acetone, and drying. In this process for producing the black pigment, the weight ratio of pyrrole to the fine particles is preferably 0.05/1 to 10/1, still preferably 0.1/1 to 5/1, and that of the ferric salt to the fine particles is preferably 0.5/1 to 20/1, still preferably 1.0/1 to 10/1. The weight ratio of pyrrole to the ferric salt is preferably 5/1 to 1/5 and still preferably 3/1 to 1/3. When the content of the ferric salt is below the above-described range, no black pigment having a sufficient blackness can be obtained. On the contrary, even when it is above the above-described range, the blackness can no more be improved. The fine particles to be coated with pyrrole homopolymer (Pyrrole Black) may be a powder of an inorganic substance or an organic substance. Examples of the inorganic substances include clays such as talc and kaolin, calcium carbonate, titanium oxide and silica. The organic substances are preferably synthetic polymers, more specifically hydrocarbon polymers such as polyethylene, polypropylene and polystyrene; polyamide polymers such as nylon; vinyl polymers such as polyvinyl chloride, polyacrylonitrile, polyacrylic acid, polyacrylic esters, polymethacrylic acid, polymethacrylic esters and polyvinyl acetate; polyester polymers, and polyurethane polymers, as well as copolymers and crosslinked polymers of them. The diameter of the fine particles before the coating is 0.01 to 200 µm under an electron microscope. Since pyrrole is coated into a pyrrole homopolymer (Pyrrole Black) by the oxidative polymerization to form a black coating on the surface of an arbitrarily selected fine particle, it is capable of forming a useful black pigment from an inorganic powder usually used as a cosmetic powder or from a synthetic polymer which can be shaped into any desired shape. Thus a black pigment having any desired specific gravity can be produced. The fine particle (black pigment) having a surface coated with the pyrrole homopolymer (Pyrrole Black) has a strong covering effect and a hydrophobic surface and is highly compatible with oil components usually contained in cosmetics. Accordingly, when according to the present invention this pigment is used in combination with these components, a Cosmetic having a sufficiently high covering effect, high smoothness and excellent spredability can be obtained. The amount of the black pigment used varies depending on the use and type of the cosmetic composition. It is usually preferably 0.1 to 50% by weight, still preferably 0.3 to 30% by weight, based on the cosmetic composition. The oil components used in the present invention include oils and waxes usually incorporated into cosmetics. The oils include hydrocarbons such as liquid paraffin, squalane, isopropyl myristate and isopropyl palmitate; animal oils such as mink oil; vegetable oils such as cotton seed oil, olive oil, tsubaki oil, coconut oil, soybean oil, sesame oil, cacao butter and castor oil; silicone derivatives such as methylpolysiloxane, methylphenylpolysiloxane, silicone polyether copolymer, amino-modified silicone, methylpolycyclosiloxane, cyclic silicone and silicone polymer; ester oils such as octyldodecyl myristate; and ether oils such as isostearyl glyceryl ether. The waxes include solid oils such as beeswax, spermaceti, lanolin, solid paraffin, microcrystalline way, vaseline, Japan wax, carnauba wax and candelilla wax. They are heat melted and mixed with the fine particles. The amount of the oil component which varies depending on the type of the final product is preferably 0.1 to 70% by weight, still preferably 0.2 to 50% by weight, based on the cosmetic composition. The weight ratio of the oil component to the black pigment is preferably 100/1 to 1/100 and still preferably 50/1 to 1/50. The cosmetic composition of the present invention is usable as a hair dyeing composition such as a temporary hair dye of mascara type, spray type of foam type; or as a makeup composition for the eyelashes, eyebrows and skin, such as an eye shadow, cheek rouge, eye liner and mascara for the eyelashes or eyebrows. The cosmetic composition of the present invention is usable in the form of a lotion, thickened lotion, gel, cream, powder, compressed powder or stick. If desired, it is usable in combination with a propellant to form a spray or foam. The cosmetic composition of the present invention may contain additives which can be usually added to such cosmetics depending on the use so far as the effect of the present invention is not impaired. The additives include anionic, nonionic, cationic and amphoteric surfactants, organic solvents, thickening agents, emollients, flavors, preservatives, antioxidants, fillers, sequestering agents, anionic, cationic, nonionic and amphoteric polymers and mixtures of them, alkalinizing agents or acidifying agents, and other pigments usually used for cosmetics, particularly, pearly pigments capable of changing the color tone. The cosmetic composition of the present invention is used as a temporary hair-dyeing composition or as a makeup composition for the eyelashes, eyebrows and skin. The composition has excellent smoothness and spreadability and is harmless and highly safe. It dyes the hair, eyelashes and eyebrows black to exhibit a high covering effect. The following Synthesis Examples for the black pigment as the constituent of the present invention and Examples will further illustrate the present invention. Synthesis Example 1 3 g of pyrrole were dissolved in 70 g of a 40% aqueous ethanol solution. Then 1 g of titanium oxide was dispersed in the solution and 30 g of a 20% aqueous ferric chloride solution were added dropwise thereto under thorough stirring for 15 min. After the completion of the addition, the stirring was continued for an additional 1. After filtration followed by washing with water, washing with ethanol, washing with acetone and drying, 2.1 g of a black powder (black pigment)(secondary particle diameter: 5 to 10 µm) were obtained. Synthesis Example 2 3 g of pyrrole were dissolved in 70 g of a 40% aqueous ethanol solution. Then 1 g of a styrene/stearyl methacrylate/divinylbenzene copolymer was dispersed in the solution and 30 g of 20% aqueous ferric chloride solution were added dropwise thereto under thorough stirring for 15 min. After the completion of the addition, the stirring was continued for an additional 1 h. After filtration followed by washing with water, washing with ethanol, washing with acetone and drying, 2.0 g of a black powder (black pigment)(secondary particle diameter: 5 to 10 µm) were obtained. Each of the black pigments obtained in Synthesis Examples 1 and 2 was incorporated into liquid paraffin and placed in a frame having a diameter of 3 cm to evaluate the blackness with the naked eyes. For comparison, the blackness of each of black iron oxide (Comparative Example 1) and a black pigment (Comparative Example 2) produced in the same manner as that described in Example 3 of US-A-4806360 was also determined in the same manner. The results are given in the following Table. Example 1 The following temporary hair dyeing composition of the mascara type was prepared. [Formulation] The composition thus obtained sufficiently covered the grey hair. Example 2 The following temporary hair dye composition of the spray type was prepared: [Formulation] The composition thus obtained sufficiently covered the grey hair. Example 3 The following temporary hair dye composition of foam type was prepared: [Formulation] The composition thus obtained sufficiently covered the grey hair. Example 4 The following eyeliner composition of the pencil type was prepared: [Formulation] The composition thus obtained had excellent smoothness and spreadability and a sufficient blackness. Example 5 The following solid mascara composition was prepared: [Formulation] The composition thus obtained had excellent smoothness and spreadability and a sufficient blackness.

Claims: A cosmetic composition comprising fine particles having a diameter of 0.01 to 200µm coated with a pyrrole homopolymer and an oil component. The cosmetic composition according to claim 1 wherein the fine particles comprise a powdery inorganic substance selected from the group consisting of talc, kaolin, calcium carbonate, titanium oxide and silica. A cosmetic composition according to claim 1 wherein the fine particles comprise a powdery organic substance selected from the group consisting of polyethylene, polypropylene, polystyrene, nylon, polyvinylchloride, polyacrylonitrile, polyacrylic acid, polyacrylic ester, polymethacrylic acid, polymethacrylic ester, and polyvinyl acetate; and a copolymer and cross-linked polymer thereof. The cosmetic composition to claim 1 wherein the amount of the fine particles coated with the pyrrole homopolymer is 0.1 to 50% by weight based on the cosmetic composition. The cosmetic composition according to claim 1 wherein the amount of the oil component is 0.1 to 70% by weight based on the cosmetic composition. The cosmetic composition according to claim 1 wherein the weight ratio of the oil component to the fine particles coated with the pyrrole homopolymer is 100/1 to 1/100.

Inventors: KAWASE JIRO C O KAO CORP, YOSHIHARA TORU, KAWASE, JIRO, C/O KAO CORP., YOSHIHARA, TORU
Applicants: KAO CORP, KAO CORPORATION
Application year: 1991
Main classification: A61K7
IPC codes: A61K8, A61Q5, A61Q1