HERBICIDAL COMPOSITIONS

Abstract: Herbicidal compositions in which the pesticidal component is suspended in fine-grained form in a flowable, oil-containing liquid phase containing at least one component selected from the group of beet herbicides consisting of phenmedipham, ethofumesate and metamitron, so that the total quantity of herbicide constitutes 1 to 50 % by weight, calculated on the basis of the weight of the total composition or, if it is a ready-to-use mixture diluted by the user, calculated on the basis of the weight of the solids content of the use mixture as specified, and wherein the liquid phase contains one or more oils selected among specifically defined non-paraffinic carbon hydride oils and ester oils with one or two ester groups so that the total oil content of the defined oil components constitutes 4 to 85 % by weight, calculated on the basis of weight of the total composition or, if it is a ready-to-use mixture diluted by the user, is calculated on the basis of weight of the solids content of said mixture and wherein said herbicidal compositions optionally contain water and for instance a filler and wherein the liquid phase is capable of forming an oil-in-water emulsion when the composition is mixed with water. Said herbicidal compositions contain one or more emulsifiers in an amount of from 1 to 18 % by weight, calculated on the basis of the weight of the total composition or, if it is a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mmixture. A more stable and advantageous product is obtained by using a reduced amount of emulsifier component.

Description: Herbicidal compositions. The invention relates to a herbicidal prepara¬ tion, preferably in the form of a concentrate, con¬ taining at least one herbicide suspended in a finely ground form in a liquid, oily phase and selected from the group consisting of phenmedipham, ethofumesate and metamitron, wherein the total amount of the three her¬ bicides constitutes from 1 to 50% by weight, 4 to 85% by weight of oil, further one or more emulsifier com¬ ponents in an amount of 1 to 18% and possibly water and possibly a filler. A group of special oils are des¬ cribed as the preferred oils selected among carbon hydride oils with an aniline point of no more than 90°C, water insoluble carboxylic acid esters of monoalcohols and carboxylic acids and dicarboxylic acids, respectively, and water insoluble carboxylic acid esters and dicarboxylic acids and water insoluble carboxylic esters of dialcohols (glycols) and monocar- boxylic acids. Moreover, the invention relates to ana¬ logous mixtures ready for use. Solvent-based pesticides for use in agriculture are generally marketed as liquid, completely soluble concentrates to be diluted with water prior to the final use so as to be sprayed on the fields or plants by means of conventional spray equipments. During the dilution process with water prior to the final use and by stirring without particular precautions the dis¬ solved pesticide component may migrate from the oily phase into the added aqueous phase, the oil being at the same time emulsified in the water, thereby forming an oil-in-water emulsion. Shelf-life-stable, aqueous suspensions of pesti¬ cides (flowables) to be diluted with water are being increasingly used during recent years. Several environ¬ mental advantages are connected with products of that type. Compared to e.g. dispersable powdery products there are no problems with dust and compared to emul¬ sion concentrates, in which the pesticide is dissolved in a solvent that is emulsified in water by means of surfactants it is possible to avoid the use of toxic and unpleasant solvents. Another known, but not especially widespread type of pesticide concentrates is an oily pesticide suspension in which the oil may be emulsified in water. When such a composition is diluted in water for final use, the emulsifier must be capable of distributing the oil without forming gels or lumps and distribute the pesticide in the aqueous phase. It is important that the distribution in the aqueous phase is effected rapidly and without difficulties. In view of the facr that most of the field crop spray equipments nowadays include effective stirring means, it may be accepted that a minor separation of oil or pesticide occurs on standing, but it cannot be accepted that the oil is gradually separated in such a manner that the pesticide is agglomerated in greasy layers of precipitations. The emulsifier as used should also ensure that oil as well as pesticide are effectively distributed on the plants. On standing most of the suspension concentrates have a tendency to separate, thereby providing a clear upper layer. Normally, this does not entail any prac¬ tical consequences but if the suspension includes both oil and water in one or two phases, both of said phases as well as the suspended phase of the solid particles should be agitatable to a homogeneous suspension that is not separated at once into separate fractions. It is decisive that the emulsifier mixture in oily preparations is active under different conditions. The emulsifiers have to stabilize the pesticidal sus¬ pension concentrate. It is in particular difficult to optimize the surfactant system if the amount of emulsi¬ fier is small in which case it may be extremely dif¬ ficult to distribute the oily suspension in the aqueous phase withoutthe formation of greasy layers of precipi¬ tation comprising oil as well as pesticide particles. Oil-containing pesticidal dispersions may be advantageous compared to aqueous systems when the oil operates as an activator in relation to the biological effect. A non-aqueous system or a system containing a mixture of oil and water may be preferred under con¬ ditions where water has a deleterious effect on the stability, e.g. when water exerts an unfavourable effect on the chemical stability, promotes the develop¬ ment of toxic breakdown products and/or dissolves the finely suspended, pesticidally active substances. The disclosure of published EP-A2-142,670 deals with liquid herbicidal preparations containing as the active substance a herbicidally active amount of car- bamates, such as phenmedipham, optionally in admixture with metamitron wherein the active substance in a finely ground state is dispersed in a liquid phase including at least one oily component in an amount from 5 to 75% by weight, and at least one surfactant in an amount of 5 to 60% by weight and optionally water. The surprising feature of the latter invention is that phenmedipham in a non-dissolved form may have an optimal biological effect. Experience until then had shown that the phenmedipham had to be dissolved. However, none of the described formulations are optimal as regards storage stability and emulsifying proper¬ ties. The possibilities of tank mixing with other beet pesticides for the described formulations are unsatis- factory. The disclosure of published EP-A1-243,872 deals with stabilized, liquid pesticidal preparations, in which the active component in a finely ground condition in an amount of 1 to 55% by weight is dispersed in an aqueous phase comprising at least one oily component in an amount of 20 to 90% by weight and a surfactant in an amount of 1 to 45% by weight, the surfactant being characterized by containing a fatty alcohol and/or an amine-containing emulsifier. The advantage of the described emulsifier systems is that they offer more stable and homogeneous concentrate formulations that are rapidly distributed in the dilution water when the oil-containing suspension concentrate in a diluted form is to be sprayed on farmers' fields. This also applies to the described compositions containing phenmedipham and metamitron in mixture. However, the described com- bination formulations are not stable when stored. This applies particularly to the physical stability, the formulations (Examples l to 4) after being stored for about 2 to 6 months appear to be granular and only disperse with difficulty in the dilution water. None of the formulations described in the Examples of EP-Al-243,872 containing phenmedipham are appropriate for tank mixing with Nortron, which is an emulsifier concentrate wit 200 g/1 of ethofumesate from Schering AG. Ethofumesate is a very important com- binational partner for phenmedipham. It should be added, however, that KVK A/S, Denmark, in 1988 intro¬ duced their first oil-containing suspension concentrate containing 16% of phenmedipham and about 5% of fatty alcohol. The trade name was Betaflow. By tank mixing with Nortron by diluting with appropriate water quali¬ ties this product offered reasonably easily sprayable mixtures. Used under practical test circumstances and dependent on the used diluting water Betaflow could, nevertheless, involve certain spraying problems. Beta- flow has a pH value of 3.0 (measuered at a dilution of 10% by weight in deionized water) . With said pH value Betaflow is imparted the most optimal emulsifier pro¬ perties. However, a smaller pH change, e.g. to pH 3.4, causes for instance a decisive change of the emulsify- ing ability, e.g. by tank mixing with Nortron, and it is therefore also evident that the character of the diluting water in tank mixtures with emulsifier con- centrates, such as Nortron, as stated above may affect the emulsifier stability. Another property of Betaflow is its tendency to impart crystal growth to the formulation. Stored at 5 20°C the crystal growth is restricted, but when stored at 50°C for about ' 3 months a considerable crystal growth can be seen, which is an essential disadvantage if Betaflow is to be used and stored in warmer count¬ ries, e.g. France, that is the greatest sugar beet pro- 10 ducer of Europe. If the non-particularly optimized Examples in EP-A2-142,670 are ignored, approximately all the far more optimized formulations containing phenmedipham according to EP-A1-243,872 (except Example 19) apply a solvent refined mineral oil with a high 15 content of liquid paraffin (>60%). Said quality of oil is chosen becaue it exerts the least solubility to phenmedipham (less than e.g. aromatic or naphtenic oil) and is therefore expected to give the slightest ten¬ dency to crystal growth. Betaflow thus contains a 20 paraffin oil with 66% paraffins calculated on the total content of mineral oil corresponding to an aniline point of 95°C. In order to obtain reasonably good emulsifying properties, in particular by tank mixing with other beet pesticides, it has been necessary to 25 apply to Betaflow an emulsifier amount of about 20% by weight calculated on the total composition. This amount of emulsifier is on a line with the matter stated in the Examples of EP-Al-243,872 which merely contain phenmedipham. 30 The high amount of emulsifier in Betaflow and the Examples stated in said EP patent applications further entail that the viscosity of the preparations becomes undesirably high. A typical viscosity for Betaflow, measured with a Brookfield viscometer, gear 3520, spindle RV 4 (factor 100) is 2000 cP (mPa-s) and frequently even considerably higher. A high viscosity entails that the time of emptying the packaging (cans containing each 5 1) gets undesirably long and that it is difficult to completely empty the packaging. An enhanced environmental consciousness has resulted in that in future pesticide formulations it 5 is desired to make use of as gentle additives as possible. It is likewise desired that the amounts of pesticides as well as the adjuvants are reduced to a minimum. This also applies to the emulsifiers which are under suspicion of penetrating into the subsoil water 1o under disadvantageous circumstances. As a product type Betaflow has demonstrated that oil-containing suspension preparations of phenmedipham present a satisfactory, high biological activity. It has concurrently been recognized that Betaflow over and 15 above the previous, solvent-based products presents de¬ cisive environmental advantages. Thus, the Swedish environmental control authorities have prohibited the previous isophoron-based products (isophoron is the preferred solvent for phenmedipham) . It must simulta- 20 neously be concluded that there is a need for improving the formulation properties of Betaflow. A summary of the properties is as follows: 251. A better compatibility during tank mixing with other beet pesticides 2. A smaller crystal growth in the concentrate 3. A lower viscosity 4. Products with improved environmental safety 305. Combination flowables with ethofumesat (previous patent applications have not included Examples of such flowables) 6. Combination flowables with metamitron (the formulations in the Examples of previous appli- 35 cations deposit and the emulsifiability deteri¬ orates during storage) 7. Cheaper formulations (a general wish) In view of the fact that the entire oil compo¬ nent in hitherto optimized recipes is larger than the emulsifier fraction it has so far seemed to be natural to focus primarily on the mineral oil fraction in order to prevent crystal growth of the finely ground pesti¬ cide suspended in the oil-containing, liquid phase. Therefore, mineral oils with a high content of paraffin oil have so far been preferred because from a theo¬ retical point of view they should provide the lowest crystal growth of the pesticide. New stability tests have however revealed that this prerequisite is not correct. The composition of the mineral oil has shown not to be particularly decisive of the crystal growth. It has turned out that synthetic ester oils, e.g. those based on esters of natural, fatty acids in spite of their aggressive (solubilizing) ester groups do not particularly promote such crystal growth. It has also been observed that a more dissolving oil under certain circumstances is pre- ferable in respect of the crystal growth, probably because it exerts at the same time a more dissolving effect to the emulsifier components, thereby ensuring that the liquid phase does not separate into more frac¬ tions which have a varying influence on the suspended pesticide. The fact that the oil component also possesses a stronger solubility force implies that it more easily mixes with the emulsifier component, thereby facilitating the emulsification. The high emulsifier content in formulations preferred so far has been necessary to impart to the products a good emulsifying stability and to ensure that the suspensions rapidly disperse in the diluting water on spraying. One of the reasons of the necessary use of large quantities of emulsifiers is perhaps that it is rather the emulsifier component that dissolves the mineral oil than the contrary. A substantial feature of the present invention is that the oil com- ponents are preferably selected among those having a suitably high degree of resolution to the emulsifier component, meaning in the end that the amount of the emulsifier component may be reduced and that it has surprisingly turned out that a more stable and advan¬ tageous product is concurrently obtained. It is at the same time mentioned that the oil components comprised by the present invention are also included as oil components in various examples from the above mentioned patent applications. This applies to EP-A2-142,670, Examples 4, 5 and 6, in which the emulsifier amount in all the stated Examples exceeds 30% by weight. EP-Al-243,872 includes the described oil components in Examples 19 b to d, in which the lowest quantity of emulsifier amounts to 23% by weight calcul- lated on the entire composition. In all the Examples the emulsifiers are thus above the upper limit of 18% stated in the present application. It seems to appear from the EP patent specifications that it has not been desirable as regards the oil components concerned to reduce the amounts of emulsifier. It has only appeared to be expedient and has only be done in such situations where the oil component has consisted of paraffinic mineral oil and where the stated Examples in EP-A2-142,670 and EP-A1-243872 with a low emulsifier content, moreover, were characterized by having an unsatisfactory storage storability, because the con¬ centrates deposited or became viscous. As stated above it is important that phenmedi- pham preparattions are mixable in a tank with other beet pesticides. In cases where it has been attempted to mix Betaflow with other dispersable products, e.g. Goltix, containing 70% of metamitron, tank mixings have been effected without problems. On the other hand, large, sticky deposits have more or less had a tendency to precipitate, when Betaflow for instance had to be mixed in tank with Nortron or ICI's Fusilade, the latter containing as the active substance 250 g/1 Fluazifop-butyl. On the face of it, it could be imagined that using increased amounts of emulsifier in Betaflow would eliminate the problems of tank mixing with other emulsifier preparations. But this has turned out not to be correct. The reason why Betaflow is so badly mixable with other products must be that the emulsifiable phase chiefly consists of mineral oil. On the contrary, the products to be mixed with Betaflow are solvent-based. The emulsifier systems to be used for the emulsifying of mineral oil are decisively different from the types to be used for the emulsifying of solvents and their mixtures with dissolved pesticides. Briefly stated, the emulsifiers used for mineral oil must be considerably less soluble in water than the emulsifiers used for the emulsifying of solvents. This explains why problems of tank mixing arise but not how to solve the problems. Mixing experiments that have contributed to the optimizing of the recipes that form the basis of the present invention invalidate the theory that a high content of emulsifier in the oil-containing phenmedi- pham-suspension preparation is unambiguously advantage- ous to the tank-mixing properties with other emulsifi¬ able pesticidal preparations. The experiments rather seem to indicate that a lower content of emulsifier in the oily phenmedipham containing suspension preparation is to be preferred. The observation may be characterized as extreme¬ ly surprising. It has been possible, however, theoreti¬ cally to advance a theory supporting the described observations. If the oil suspension preparation A con¬ taining 60% of oil (0) and 20% emulsifier (El), (summarily expressed as AIQO = °60' E1 2θ)' is to be mixed in the ratio 1:1 with the emulsion preparation B containing 60% of solvent (S) and 4% of emulsifier (E2), (summarily expressed as BIQO = s 60' E2 4 ) ^ the mixture may be expressed as (A 50 B 50 = O 30 . S 30 , E1 10' E22)- It will thus appear that the oil-/solvent mixture (O30S30) is a uniform mixture of the emulsifiable pha- ses of the two products, but that the emulsifier phase (E1 ] _ Q , E22) of the mixed product is approximately complete dominated by the emusifier component of the oil product and therefore almost not adapted to the solvent (S) . If both products had contained 6% of the emulsifier component, the mixture AB in the ratio 1:1 would be: A50B50 = O 3 0. S3 0 . El 3 , E23, and it is readi¬ ly observed that in this situation there is the same ratio between the emulsifiable phases (oil and solvent) as between the emulsifier components El and E2, and that the ratios O/S and E1/E2 are the same independent¬ ly of the mixing ratio between A and B. The outlined theoretical explanation thus appears to confirm that a restriction of the emulsifier amounts in the oil-containing suspension preparations is desirable in cases where the preparations are to be admixed with traditional solvent-based preparations whose emulsifier content too is low. But as it has already been demonstrated above, it is advantageous to concurrently select the oil component. On the face of it, it appears to be difficult to reduce the content of the emulsifier component. Many laboratory experiments have shown that it becomes dif¬ ficult to reduce the emulsifier content and to ensure at the same time that the preparations emulsify satis¬ factorily in soft as well as in calcareous water. A possible solution to this problem is to add simultane¬ ously a calcium neutralizing substance. The most appropriate seems to be an acid salt of oxalic acid but nevertheless the solution suffers from various defien- cies, inter alia 5% on weight basis of the preparation does not appear to be completely sufficient, if the preparation is to be sprayed in low concentrations, e.g. 1% and below. Moreover, the salts are only soluble in water on a limited scale and are extremely dif¬ ficult to grind. International patent application No. WO 87/05778 describes herbicidal compositions comprising biscar- bamates, including PMP in an amount of 10 to 50% by weight, 20 to 60% by weight of vegetable oil, 5 to 40% by weight of emulsifier, 20 to 60% by weight of water and optionally 0.01 to 5% by weight of a heteropoly- saccharide biopolymer as a viscosity regulating agent. However, the emulsifying of vegetable oils require atypical emulsifier compositions that may only diffi¬ cultly conform to emulsifier systems used in tradition- al emulsifier preparations. This confines the farmer's possibilities of producing his own tank mixtures. A possible solution appears to consist in using various anionic emulsifiers in limited quantities. The optimizing work is extremely time-consuming but the result may be highly satisfactory. This complex of problems will be thoroughly explained later on in the specification. It has now surprisingly turned out that her¬ bicidal compositions may be obtained of the type in which the herbicidal compositions in a fine-grained form is suspended in a flowable, oil-containing liquid phase and is stabilized physically as well as chemi¬ cally and wherein the total composition is well suited for tank mixing with other herbicides. In accordance with the above the invention rela¬ tes to herbicidal compositions in which the herbicidal component is suspended in fine-grained form in a flow- able, oil-containing liquid phase containing at least one component selected from the group of beet herbi- cides consisting of phenmedipham (methyl-( 3-(3-tolyl- carbamoyloxy)phenyl)carba ate) , ethofumesate ( (±)-2- ethoxy-2,3-dihydro-3,3-dimethylbenzofuran-5-yl, methane sulphonate) and metamitron (4-amino-4,5-dihydro-3-me- thyl-6-phenyl-l,2,4-triazin-5-one) , so that the total quantity of herbicide constitutes 1 to 50% by weight, and wherein the liquid phase contains one or more emulsified, solubilized, dissolved or admixed oils with an initial boiling point of at least 210°C selected among carbon hydride oils with an aniline point deter¬ mined according to DIN 51775 not exceeding 90°C and preferably synthetic ester oils with one or two ester o groups per molecule so that the total oil content of the oil components constitutes 4 to 85% by weight, and wherein said herbicidal compositions optionally contain water and for instance a filler and wherein the liquid phase is capable of forming an oil-in-water emulsion or -microemulsion when the composition is mixed with water, said herbicidal compositions being characterized in that they contain one or more emulsifiers in an amount of 1 to 18% by weight, wherein all given expres¬ sions for the contents of the composition in % by weight are calculated on the basis of the weight of the total composition. In other embodiments of the present herbicidal compositions the total quantity of herbicide amounts to 1 to 45% by weight, and/or the total content of the oil components constitutes 8 to 85% by weight, in both cases calculated on the basis of the weight of the total composition. Moreover, the solubility of the oil or oils in water at 20°C is preferably below 1% by weight, and the solubility of phenmedipham in the actu- al oil(s) is preferably below 3% by weight, in part¬ icular below 2% by weight and especially below 1% by weight. In the present compositions the preferred amount of herbicide constitutes from 4 to 40% by weight, in particular 7 to 35% by weight and especially 10 to 30% by weight; the preferred oil content constitutes from 12 to 77% by weight, in particular 18 to 60% by weight and especially from 25 to 64% by weight; and the total emulsifier content preferably constitutes from 1 to 13% by weight, more preferably from 1.5 to 13% by weight, in particular 2 to 9% by weight and especially 2.5 to 5% by weight, all the above % by weight being calcul¬ ated on the basis of the weight of the total composi¬ tion. If the composition is available as a ready-to- use mixture diluted by the user himself, the expres- sions in % by weight for the contents of the composi¬ tion are calculated on the basis of the weight of the solids content of the ready-to-use mixture. The term "the solids content of the ready-to-use mixture" as stated above is in the present specifica- tion to be interpreted as the components of the mixture which are either solids or have a boiling point at 760 mm Hg exceeding 210°C, so that solvents with a boiling point below 210°C are not included in the calculation of the solids content. Particularly preferred herbicidal compositions according to the invention are characterized in that they are two- or multicomponent compositions containing phenmedipham in combination with ethofumesate and/or metamitron. Particularly preferred oils forming part of the above compositions are such selected among carbon hydride oils with an aniline point determined according to DIN 51775 which does not exceed 90°C, preferably no more that 87.5°C, particularly not exceeding 85°C and especially no more than 82.5°C, water insoluble car¬ boxylic acid esters preferably of aliphatic monoalco- hols and aliphatic or aromatic monocarboxylic acids or aliphatic or aromatic dicarboxylic acids, respectively, and of water insoluble carboxylic esters, preferably of aliphatic dialcohols (glycols) and aliphatic or aromatic monocarboxylic acids. By stating the combination of the mineral oil the characterization (the statements) refer to general- ly available distillates, such as they are purchased from the oil companies. The characteristic features of the mineral oil as described thus apply solely to base oil combinations that are not subsequently mixed further, such as generally delivered by the oil com¬ panies. In respect of the further description it is desired to state the following definitions: Hydrocarbyl (R-) refers to a straight-chained or branched group of alkyl, alkenyl or alkynyl, e.g. exemplified by ethyl (-CH 2 CH 3 ), ethenyl (-CH=CH 2 ) or ethynyl (-C≡CH). The hydrocarbylene (-R-) refers to a straight-chained or branched group of alkylene, alkenylene or alkynylene, e.g. exemplified by ethylene (-CH2CH2-), et enylene (-CH=CH-) or ethynylene (-C≡C-) . The word emulsifier embraces in the specifica¬ tion proper emulsifiers as well as dispersing agents. There is no clear limit between the definition of an emulsifier and a dispersant and a so-called emulsifier may frequently be used as a dispersing agent or vice versa. An emulsifier may either be a polymeric com¬ pound with a molecular weight which apart from the exceptions given below does not exceed 7.000 Dalton, comprising many hydrocarbyl or hydrocarbylene groups, or it must always contain at least one hydrocarbyl or hydrocarbylene group having at least 8 carbon atoms. As regards polycarboxylates and copolymerisates of oxyethylene and oxyprop lene with at least 80% by weight of polyox ethylene and polyoxypropylene, the upper limit of the molecular weight amounts anyhow to 50.000 Dalton. Moreover, the emulsifier must always contain at least one hydrophilic group, which may for instance be a polyoxyethylene group, an amine group, a sulfonic acid group, or a phosphate ester group, but this is not a sufficient condition of characterizing a substance as an emulsifier. In the present specification the definition of emulsifiers does not include polymers which preferably via an inherent dilatation at 20°C are stably mixable (soluble) in water and all of which have a molecular weight of at least 7.000 Dalton, with the exception that polycarboxylates and copolymerisates of oxyethy- lene and oxypropylene with at least 80% by weight of polyoxyethylene, must always be regarded as emulsifiers when the molecular weight is below 50.000 Dalton. Said polymers are later on described as an independently defined, optionally possible group of components in the herbicidal compositions and are referred to as polymer stabilizers. Emulsifiers are, moreover, such as described in the sales leaflets of emulsifier suppliers and in relevant catalogues and reference books. The following publications of Mc Cutcheon are stated as an example of reference books: Detergent & Emulsifiers International Edition, 1983, Glen Rock New Jersey 07452, U.S.A, and North American Edition, 1983, Glen Rock New Jersey 07452, U.S.A. In the present specification water insoluble esters with at least 8 carbon atoms obtained by esteri- fication of an alkoxylated alcohol and either a mono¬ carboxylic acid or a dicarboxylic acid, may be regarded either as an oil or as an emulsifier. If the number of alkoxy groups in the alkoxylated alcohol is not more than 3, it may merely be regarded as an oil. If the number of alkoxy groups is 4 or more it may only be regarded as an emulsifier. Water insoluble esters with at least 8 carbon atoms formed by esterification of an alkoxylated dialcohol (glycol) and a monocarboxylic acid, may in the same manner be regarded either as an oil or as an emulsifier. If the number of alkoxy groups in the alkoxylated dialcohol does not exceed 5, it may only be regarded as an oil. If the number of alkoxy groups is 6 or more, it may only be regarded as an emulsifier. Evaluated from the physical properties of the oils preferred oils forming part of the present com- positions are those which at 40°C have a kinematic viscosity of no more than 100 cSt, preferably no more than 78 cSt, in particular not exceeding 55 cSt and especially not exceeding 33 cSt. The starting boiling point must be at least 210°C, preferably at least 230°C and in particular at ' least 250°C. Preferred carbonhydride oils are mineral oils or synthetic carbonhydride oils solely composed of C and H. The distribution of carbon of the mineral oils calculated according to DIN 51378 or ASTM D 2140 must preferably be so that the procentual content of carbon, bound to paraffinic hydrocarbons, constitutes no more than 60%, preferably no moe than 57.5%, in particular no more than 55% and especially no more than 52.5% on weight basis, calculated on the total carbon content of the mineral oil so that the total content of carbon bound to naphthenic and aromatic rings of hydrocarbon constitutes at least 40%, preferably at least 42.5%, in particular at least 45% and especially at least 47.5% calculated on the total carbon content of the mineral oil. It is desirable that the content of carbon bound to naphthenic hydrocarbons determined according to DIN 51378 or ASTM D 2140 amounts at least to 34%, prefer- ably at least 37%, in particular at least to 40% and especially at least to 43% calculated on the total car¬ bon content of the mineral oil. Particularly preferred water insoluble ester oils forming part of the present compositions are those whose number of carbon atoms in the ester is 8 to 72, preferably 10 to 60, in particular 12 to 46 and espe¬ cially 14 to 44 per molecule. It is desirable that the ester oils have a solidification point of no more that 40 C, preferably no more that 30°C, in particular no more than 20°C and especially no more than 10°C. Highly preferred herbicidal compositions accord¬ ing to the invention in which the pesticidal component is suspended in fine-grained form in a flowable, oil- containing liquid phase and is stabilized physically as well as chemically and in which the total composition is well suited for tank mixing with other pesticides, are those containing at least one component selected from the following group of beet herbicides consisting of phenmedipham (methyl(3-(3-tolyl-carbamoyloxy)phenyl) carbamate), ethofumesate ( (±)2-ethoxy-2,3-dihydro-3, 3- dimethylbenzofuran-5-yl methanesulphonate) and meta- mitron (4-amino-4.5-dihydro-3-methyl-6-phenyl-l,2,4- triazine-5-on) , so that the total quantity of herbicide amounts to l to 50% by weight, preferably 1 to 45% by weight, more preferably 4 to 40% by weight, in part¬ icular 7 to 35% by weight and especially 10 to 30% by weight, and wherein the liquid phase contains one or more emulsified, solubilized, dissolved or admixed oils selected among carbonhydride oils, triglyceride ester oils, which may either be natural or synthetic and water insoluble ester oils with one or two ester groups per molecule, so that the total oil content thereof amounts to 8 to 85% by weight, preferably 12 to 77% by weight, in particular 18 to 70% by weight, and espe¬ cially 25 to 64% by weight, and wherein the herbicidal compositions optionally contain water and optionally fillers, and in which the liquid phase is capable of forming an oil-in-water emulsion or a micro-emulsion when the composition is mixed with water, said her¬ bicidal compositions being characterized in that the content of ester oils with one or two ester groups per molecule constitutes at least 4% by weight, rather at least 8% by weight, preferably at least 12% by weight, in particular at least 18% by weight, and especially at least 25% by weight, and in that the compositions con¬ tain one or more emulsifiers (as defined above) in an amount of 1 to 18% by weight, rather 1 to 13% by weight, preferably of 1.5 to 13% by weight, in par¬ ticular 2 to 9% by weight and especially 2.5 to 5% by weight, all of the stated percentage compositions being calculated on weight basis of the total composition or, in case of a ready-to-use mixture diluted by the user, calculated on weight basis of the solids content of the use mixture (as defined above) . In one aspect of the invention the fraction of alcohol of the ester is derived from a preferably ali¬ phatic monoalcohol of the formula I or II RiOH I R 2 θ-R 3 -(0-R 4 ) n -OH II wherein R]_ and R 2 per se designates a straight-chained or branched, saturated or unsaturated hydrocarbyl group having 1 to 30 carbon atoms, preferably l to 22 car¬ bon atoms and R3 and R4 individually designate a straight-chained or branched, saturated or unsaturated hydrocarbylene chain having from 1 to 22 carbon atoms, preferably 2 to 9 carbon atoms, in particular 2 to 4 carbon atoms and especially 2 or 3 carbon atoms, and n is either 0, 1 or 2. The following examples of alcohols of formula I and II are methanol, ethanol, propanol, isopropanol, butanol, isobutanol, amyl alcohol, hexyl alcohol, hep- tyl alcohol, isoheptyl alcohol, octyl alcohol, isooctyl alcohol, 2-ethyl-hexyl alcohol, nonyl alcohol, cetyl alcohol, isocetyl alcohol, ethoxy ethanol, butoxy etha¬ nol and unsaturated analogs thereto. Preferred alcohols are isopropanol, isobutanol, octyl alcohol, isooctyl alcohol, 2-ethylhexyl alcohol and nonyl alcohol. The acid part of the esters may be derived from a preferably aliphatic monocarboxylic acid of the for¬ mula R5COOH, wherein R5 is hydrogen or a straight- chained or branched, saturated or unsaturated aliphatic hydrocarbyl group with 1 to 30 carbon atoms, preferably 8 to 20 carbon atoms, or a straight-chained or branched, wholly or partly aromatic hydrocarbon group with 6 to 30 carbon atoms, preferably 6 to 20 carbon atoms, and wherein the aliphatic as well as the aromatic acid are optionally substituted by one or two hydroxy groups. Examples of such acids are butyric acid, caproic acid, caprylic acid, decanoic acid, 2-ethyl caproic acid, lauric acid, myristic acid, palmitic acid, stearic acid and hydroxy substituted stearic acid. Mixtures of technical fatty acids may further be used, such as Cis- and C]_8-fatty acids. Other examples are benzoic acid and salicylic acid. A preferred class of esters for use in the pre¬ sent compositions consists of esters selected from the group consisting of 2-ethyl-hexyl laureate, 2-ethyl- hexyl myristate, 2-ethyl-hexyl palmitate, 2-ethyl-hexyl stearate, isobutyl stearate, isopropyl myristate, iso¬ octyl esters of C15- and C ] _ 8 ~technical fatty acids and mixtures thereof. A further preferred class of acid parts is derived from unsaturated acids, such as oleic acid, ricinoleic acid, linoleic acid or linolenic acid. Examples of corresponding esters are 2-ethyl-hexyloleate and isobutyl oleate, isobutyl rici- noleate, isobutyl linolate and isobutyl linolenate. Particularly appropriate esters are C2-20~ mono ~ alcohol esters of oleic acic, C2-i2~ monoa lcohol esters of lauric acids and myristic acids and Cs-g-monoalcohol esters of palmitic acids and stearic acids. In a further aspect of the invention the acid part of the ester is derived from an acid of the general formula HOOC-(A) m -COOH, wherein m calculates 0 or 1, and wherein A designates a straight-chained or branched, saturated or unsaturated, aliphatic hydrocar¬ bylene chain having 1 to 24 carbon atoms, preferably 2 to 16 carbon atoms, optionally substituted by one or two hydroxy groups, or A designates a divalent hydro¬ carbon group containing one or more aromatic rings, so that the group in total contains 6 to 24 carbon atoms, preferably 6 to 16 carbon atoms, optionally substituted by one or two hydroxy groups. Examples of dicarboxylic acids are oxalic acid, succinic acid, 2-hydroxysuccinic acid, 2,3-dimethyl succinic acid, glutaric acid, adipic acid, pimelic acid, hexanecarboxylic acid, azelaic acid, sebacic acid and phthalic hexanedicarboxylic acid. An appropriate ester may also be derived from an acid of the formula HOOC-A'-COOH, wherein A 1 designates an unsaturated hydrocarbylene chain having 2 to 24 car¬ bon atoms, preferably 2 to 16 carbon atoms. When the acid part in the ester is a dicarboxyl¬ ic acid, both acid groups should preferably be esteri- fied, but one of the acid groups may also be wholly or partly on free acid form, or optionally wholly or partly be converted to a salt. Further examples of esters that may be used in the combinations according to the invention are esters, wherein the alcohol fraction is derived from a dialco- hoi of formula Ila, lib, lie or lid. R I 6_ R I 7 _ HO-C-(Y) -C=C-OH lib 1 <3 « R 8 H l0 - ( O- Rl1 ) - ( O-R l2 ) t -OH IIC R 6 ? HO-(R 12 -Oi t -C-(Zi_-C-O-R 10 -(O-R 11 ) s -OH "<* R 8 R 9 wherein Rg, R7, Rβ and Rg are the same or different, and wherein each is hydrogen, a straight-chained or branched alkyl or a straight-chained or branched, un¬ saturated hydrocarbyl chain, p is 0 or 1, q is 0 or 1, r is 0 or 1, s is 0, 1 or 2, t is 0, 1 or 2; X, Y and Z are the same or different, and each is a straight- chained or branched, saturated or unsaturated hydrocar¬ bylene chain having 1 to 15 carbon atoms, wherein the total number of carbon atoms in the dialcohol molecule exclusive of Rio, R11 and R12 does not exceed 22, pre¬ ferably no more than 12, and Rio, R11 and R12 indivi¬ dually are a straight-chained or branched, saturated or unsaturated hydrocarbylene chain with 2 to 10 carbon atoms, preferably 2 to 4 carbon atoms and especially 2 or 3 carbon atoms. When the alcohol part in the ester is a dialcohol (glycol), both alcohol groups should preferably be esterified, but the one alcohol group may as well be unesterified and free. Optionally the ester of the dialcohol may advantageously be a mixture of a monoester and a diester. A preferred class of esters of the above men¬ tioned class is the one wherein the alcohol part is derived from alcohols, selected from the group cons- istong of ethylene glycol, tetrapolyethylene glycol, propylene glycol, dipropylene glycol, hexylene glycol, dimethylpropane diol and 2,2,4-trimethylene pentane (-l,3)-diol. The acid part in esters, wherein the alcohol part is derived from a dialcohol of the formula iia, lib, lie or lid, is derived from monocarboxylic acids of the formula R13COOH, wherein R1 3 is hydrogen or a straight-chained or branched, saturated or unsaturated, aliphatic hydrocarbyl group having 1 to 30 carbon atoms, preferably 8 to 20 carbon atoms, or a straight- chained or branched, wholly or partly aromatic hydro¬ carbon group with 6 to 30 carbon atoms, preferably 6 to 20 carbon atoms, and wherein both the aliphatic or the wholly or partly aromatic carboxylic acid is optionally substituted by 1 or 2 hydroxy groups. This acid may preferably be selected from the group consisting of methanoic acid, acetic acid, propanoic acid, isopro- panoic acid, butyric acid, isobutyric acid, lactic acid, valeric acid, caproic acid, isoheptanoic acid, caprylic acid, isocaprylic acid, 2-ethylcaproic acid, nonanoic acid and decanoic acid and unsaturated variants thereof together with benzoic acid and sali- cylic acid and mixtures of technical C 1 2-. C 14 -, C 1 5- and Ci8 fatty acids, e.g. technical oleic acid. Various acids may be used for the esterification of the two alcohol groups of the dialcohol. Preferred esters for use in the compositions according to the invention are thus selected from the group consisting of ethylene glycol diisobutyrate, tetraethylene glycol dioleate, propylene glycol diiso¬ butyrate, propylene glycol dioleate, dipropylene glycol dioleate, hexylene glycol monoisobutyrate, hexylene glycol diisobutyrate, dimethylpropanediol monoisobu¬ tyrate, dimethylpropanediol diisobutyrate, 2,2,4-tri- methylpentane-(1,3)-diol monoisobutyrate and 2,2,4-tri- methylpentane-(1,3)-diol diisobutyrate. Examples of esters supposed to be particularly useful in herbicidal preparations are: hexyl acetate, 2-ethylhexyl acetate, octyl acetate, isooctyl acetate, cetyl acetate, dodecyl acetate, tridecyl acetate; butyl butyrate, isobutyl butyrate, amyliso but ate, hexyl butyrate, heptyl butyrate, isoheptyl butyrate, octyl butyrate, isooctyl butyrate, 2-ethylhexyl butyrate, nonyl butyrate, isononyl butyrate, cetyl butyrate, iso- cetyl butyrate; ethyl hexanoate, propyl hexanoate, iso- propyl hexanoate, butyl hexanoate, isobutyl hexanoate, amyl hexanoate, hexyl hexanoate, heptyl hexanoate, iso¬ heptyl hexanoate, octyl hexanoate, 2-ethylhexyl hexano¬ ate, nonyl hexanoate, isononyl hexanoate, cetyl hexa- noate, isocetyl hexanoate; methyl octanoate, ethyl octanoate, propyl octanoate, isopropyl octanoate, butyl octanoate, isobutyl octanoate, amyl octanoate, hexyl octanoate, heptyl octanoate, isoheptyl octanoate, octyl octanoate, isooctyl octanoate, 2-ethylhexyl octanoate, nonyl octanoate, isononyl octanoate, cetyl octanoate, isocetyl octanoate; methyl-2-ethyl hexanoate, ethyl-2- ethyl hexanoate, propyl-2-ethyl hexanoate, isopropyl-2- ethyl hexanoate, butyl-2-ethyl hexanoate, isobutyl-2- ethyl hexanoate, isoamyl-2-ethyl hexanoate, hexyl-2- -ethyl hexanoate, heptyl-2-ethyl hexanoate, isoheptyl-2 -ethyl hexanoate, octyl-2-ethyl hexanoate, isooctyl-2- ethyl hexanoate, 2-ethylhexyl-2-ethyl hexanoate, nonyl- 2-ethyl hexanoate, isononyl-2-ethyl hexanoate, cetyl-2 -ethyl hexanoate, isocetyl-2-ethyl hexanoate; methyl decanoate, ethyl decanoate, propyl decanoate, isopro¬ pyl decanoate, butyl decanoate, isobutyl decanoate, isoamyl decanoate, hexyl decanoate, heptyl decanoate, isoheptyl decanoate, octyl decanoate, isooctyl decano¬ ate, 2-ethylhexyl decanoate, nonyl decanoate, isononyl decanoate, cetyl decanoate, isocetyl decanoate; methyl laurate, methyl laurate, ethyl laurate, propyl laurate, isopropyl laurate, butyl laurate, isobutyl laurate, isoamyl laurate, hexyl laurate, heptyl laurate, isohep¬ tyl laurate, octyl laurate, isooctyl laurate, 2-ethyl- hexyl laurate, nonyl laurate, isononyl laurate, cetyl laurate, isocetyl laurate, methyl oleate, ethyl oleate, propyl oleate, isopropyl oleate, butyl oleate, isobutyl oleate, isoamyl oleate, hexyl oleate, heptyl oleate, isoheptyl oleate, octyl oleate, isooctyl oleate, 2-ethylhexyl oleate, nonyl oleate, isononyl oleate, cetyl oleate, isocetyl oleate; diethyl succinate, di- propyl succinate, diisopropyl succinate, dibutyl sue- cinate, diisobutyl succinate, diisoamyl succinate, di- heptyl succinate, diisoheptyl succinate, dioctyl suc¬ cinate, diisooctyl succinate, di-2-ethylhexyl suc¬ cinate, dinonyl succinate, diisononyl succinate, dice- tyl succinate, diisocetyl succinate; dimethyl adipate, diethyl adipate, dipropyl adipate, diisopropyl adipate, dibutyl adipate, diisobutyl adipate, diisoamyl adipate, dihexyl adipate, diheptyl adipate, diisoheptyl adipate, dioctyl adipate, diisooctyl adipate, di-2-ethylhexyl adipate, dinonyl adipate, diisononyl adipate, dicetyl adipate, diisocetyl adipate, isopropyl myristate, iso¬ butyl myristate, butyl myristate, amyl myristate, hexyl myristate, heptyl myristate, isoheptyl myristate, octyl myristate, 2-ethylhexyl myristate, nonyl myristate, isononyl myristate, cetyl myristate, isocetyl myri¬ state; isopropyl palmitate, isobutyl palmitate, butyl palmitate, amyl palmitate, hexyl palmitate, heptyl palmitate, isoheptyl palmitate, octyl palmitate, 2-ethylhexyl palmitate, nonyl palmitate, isononyl palmitate, cetyl palmitate, isocetyl palmitate; isopro¬ pyl stearate, isobutyl stearate, butyl stearate, amyl stearate, hexyl stearate, heptyl stearate, isoheptyl stearate, octyl stearate, 2-ethylhexyl stearate, nonyl stearate, isononyl stearate, cetyl stearate and isoce- tyl stearate. In a particular embodiment of the present compo¬ sitions the oily phase of said compositions includes at least two different ester oils. Preferred compositions are mixtures of carbon hydride oils and ester oils, in which the ratio of mineral oil/ester oil is 9:1-1:9, preferably 6:1-1:6, in particular 4:1-1:4, and especially 2:1-1:2. Other interesting herbicidal preparations con¬ taining phenmedipham in combination with ethofumesate and/or metamitron, are those containing both mineral oils and ester oils, in which the ratio mineral oil/ester oil is 19:1-1:2, preferably 9:1-9:11 and par¬ ticularly 5:1-2:1. Advantageous herbicidal preparations are those having a water content of at least 2%, rather at least 3%, preferably at least 4%, in particular at least 8% and especially at least 11%, and the quantity of water amounts to no more than 65%, rather no more than 52%, preferably no more than 42%, in particular no more than 37% and esepcially no more than 29%, and the interval quantities of water e.g. constitute 2 to 65%, rather 3 to 52%, preferably 4 to 43%, in particular 8 to 37% and especially 11 to 29% by weight of the total composi¬ tion. In view of the storage stability preferred com¬ positions in which the pesticidal component consists of phenmedipham in combination with ethofumesate and/or metamitron, and which contain water when the composi¬ tion contains ethofumesate are those in which the water amount constitutes 2 to 65%, rather 3 to 52%, prefer¬ ably 4 to 43%, in particular 8 to 37% and especially 11 to 29% on the basis of weight of the total composition, and when the composition contain metamitron, those in which the water amount constitutes 0.3 to 12%, rather 0.5 to 8%, preferably 1.5 to 6%, particularly 2 to 3.5%, an especially 2.2 to 3% on the basis of weight of the total composition. Interesting herbicidal preparations containing phenmedipham in combination with ethofumesate, are those in which the ratio of weight between phenmedipham and ethofumesate is in the range 6:1 to 1:6, preferably in the range 4:1 to 1:4, particularly in the range 3:1 to 1:3 and especially in the range 2:1 to 1:2. Interesting herbicidal preparations containing phenmedipham in combination with metamitron, are those in which the ratio of weight between phenmedipham and metamitron is in the range 1:1 to 1:10, preferably in the range 1:1.5 to 1:8, in particular in the range 1:2 to 1:6 and especially in the range 1:3 to 1:5. When the herbicidal preparation has a low emulsifier content, e.g. below 18%, preferably below 13%, particularly below 9% and especially below 5%, calculated on the basis of weight of the total com¬ position and the composition contains water in an amount of 0.3 to 65%, rather of 0.5 to 52%, preferably of 6 to 43%, in particular of 8 to 37% and especially of 11 to 29% on the basis of weight of the total com¬ position, it may probably be advantageous in dependence on the combination of oils that the formulation as sta- bilizer contains less than 1% calcium-, magnesium-or aluminium-silicate, preferably less than 0.7% of calci¬ um-, magnesium- or aluminium silicate and especially less than 0.4% calcium-, magnesium- or aluminium- silicate. Preferred particle sizes of the fine-grained suspended herbicide are those in which 90% on the basis of weight of the suspended herbicide has a particle size below lOμ, preferably below 7μ, rather below 5μ and especially below 3μ. If the oil phase by dilution with water is emusified as oil drops below lμ, the determination of the grain size may be effected with a Malvern particle meter type 3600 E. Advantageous compositions in accordance with the invention which contain phenmedipham and/or ethofume- sate, and which are characteristic in being easy to manufacture in a controllable manner and are long-time stable are those in which the herbicidal component has either been obtained in an aqueous phase in a finely dis persable form or has been ground in an aqueous dispersion, characterized in that the water content during manufacturing amounts at least to 30%, preferab¬ ly at least to 36%, and especially at least to 43% on the basis of weight of the total herbicidal dispersion, and in which the herbicide is obtained with a particle size, so that 90% by weight of the suspended herbicide measured with a Malvern particle meter of the type 3600 E has a particle size below lOμ, preferably below 7μ, in particular below 5μ and especially below 3μ, which generally is finer compared to what is normally obtainable if the grinding is effected in an oily phase. Grinding in water entails generally the advan- tage that the aqueous phase for humidifying reasons contains one or more emulsifiers. An admixture with oil and optionally emulsifier is effected after preparing in a finely ground form in water. The completed pesti¬ cidal composition must likewise be characterized by 10 containing water, rather in an amount in excess of 6%, preferably in excess of 8%, in particular in excess of 11% and especially in excess of 18% on the basis of weight of the total composition. The water content must constitute no more than 65%, preferably no more than 15 52%, in particular no more than 43%, and especially no more than 29%. Extremely active compositions are those containing simultaneously one of the above described water insoluble ester oils in an amount of 4 to 87%, rather of 8 to 77%, preferably in an amount of 12 to 20 70%, in particular of 18 to 64% and especially of 25 to 50% calculated on the basis of weight of the total composition. When optimizing emulsified preparations it is standard to adapt the emulsifier system to the solvent 25 and the dissolved substance. It is desirable in the described compositions also to be able to adjust the combination of oils. Besides containing carbon hydride oil and/or water insoluble ester oils and other tradi¬ tional oil components the particularly preferred her- 30 bicidal compositions also contain emulsion controlling oil components selected from the group consisting of aliphatic, unsaturated, straight-chained or branched c 17-25 hydrocarbyl carboxylic acids as Qleic acid, linoleic acid and linolenic acid and other aliphatic, 35 unsaturated Ci7_25 hydrocarbyl carboxylic acids subs¬ tituted by one or two hydroxy groups, e.g. ricinoleic acid; aliphatic, saturated and branched Ci7_25 hydro- carbyl carboxylic acids, e.g. isostearic acid and other aliphatic, saturated, branched C y_25 hydrocarbyl car¬ boxylic acids substituted by one or two hydroxy groups; aliphatic, saturated or unsaturated, straight-chained or branched Cy_i6 hydrocarbyl carboxylic acids, e.g. isononanoic acid and other aliphatic, saturated or un¬ saturated, straight-chained or branched Cγ-ig hydro¬ carbyl carboxylic acids substituted by one or two hydroxy groups, and finally aliphatic, saturated or unsaturated, straight-chained or branched Cg_25 hydro¬ carbyl alcohols, preferably C Q-21 hydrocarbyl alco¬ hols, wherein the total amount of the emulsion controlling oil components constitutes 0.5 to 20%, pre¬ ferably 1 to 15%, particularly 1.5 to 11% and espe- cially 2 to 8% on the basis of weight of the total com¬ position or, if it is a ready-to-use mixture diluted by the user, calculated on the basis of the weight of the solids content of said mixture. The grain size of the herbicidally active subs- tances dispersed in the composition affects the visco¬ sity. The amount of dispersed herbicide is also deci¬ sive of the viscosity. When the composition solely con¬ tains phenmedipham in a concentration of ≤160 g/1, and when phenmedipham has been ground/finely distributed so that a measuring of the particle size determined by a Malvern particle meter of the type 3600 E by using the low-effect laser light diffraction technique or an equivalent metering method indicates that 90% on the basis of weight of the total amount of phenmedipham has a grain size smaller than 3-4μ, the viscosity at 22°C in the descibed compositions, measured by a Brookfield viscometer, gear 20, with a spindle of the RV type, will be lower than 1500 cP (mPa«s), preferably lower than 1350 cP, in particular be lower than 1200 cP, and especially be lower than 1000 cP. Preferred compositions according to the inven¬ tion are those containing finely ground herbicide selected among phenmedipham, ethofumesate and meta¬ mitron in an amount of 1 to 35%, preferably in an amount of 10 to 30% on the basis of weight of the total composition which at 22°C measured by a Brookfield viseometer, gear 20, with a spindle of the RV type has a viscosity lower than 1500 cP (mPa'S), preferably lower than 1350 cP, in particular lower than 1200 cP, and especially lower than 1000 cP. Traditional solvent-based phenmedipham prepara- tions must have a specific emulsifier content if the biological effect should attain its optimum. Thus, the disclosure of SE patent publication No. 357 486, Schering, states that the ratio between phenmedipham and surfactant must be 2:1 to 1:2 corresponding to the fact that the emulsifier content in a 160 g/1 prepara¬ tion varies between 80 and 320 g/1. The equivalent, NL patent states a ratio of 1:1 to 1:2 corresponding to 160 to 320 g/1 emulsifier. Schering's emulsion con¬ centrate Betanal, containing 157 g/1 phenmedipham, has a content of about 200 g/1 emulsifier, and the pre¬ viously mentioned oil-containing suspension preparation Betaflow containing 160 g/1 phenmedipham and the corresponding product Betanal.- from Schering likewise has an emulsifier content of about 200 g/1. It is therefore surprising that the compositions which according to the invention have a low emulsifier con¬ tent when the active agent content is the same possess a biological activity on a level with that of Betanal. This also applies to preparations with an emulsifier content for instance lower than 50 g/1. In addition, it is possible to reduce the quantity of oil so that the preparation contains a certain amount of water and still obtain a good, biological effect. The described low-paraffinic mineral oils impart a good chemical sta- bility to the compositions. The described water in¬ soluble ester oils that are easily biologically degrad- able are to be preferred for ecological reasons and as regards effects. When the composition contains PMP its pH-value measured in a dilution of 10% in deionized water must range from neutral to moderately acidic. The pH-value should not exceed 6, preferably not exceed 5.5, in par- ticular not exceed 5.0 and especially not exceed 4.7 The pH-value must be' at least 2, preferably at least 3.2, in particular at least 3.5 and especially not exceed 3.8. If the composition contains water insoluble ester oils or esterified emulsifiers it is for storing reasons preferable that the pH-value (10% solution) amounts at least to 3.2 to 3.5. The emulsifier component of the composition must preferably consist of a mixture of one or more non- ionic emulsifiers and one or more ionic emulsifiers. Particularly preferred compositions are those in which the emulsifier component of the composition con¬ sists of one or more non-ionic emulsifiers and one or more anionic emulsifiers and optionally other stabili¬ zers such as aromatic acid stabilizers. The non-ionic emulsifier(s) should preferably constitute 50 to 99%, preferably 58 to 97%, in part¬ icular 65 to 95% and especially 25 to 90% on the basis of weight of the total emulsifier amount (emulsifier component) . The anionic emulsifiers should preferably constitute 1 to 50%, preferably 3 to 42%, in particular 5 to 35% and especially 10 to 25% on the basis of weight of the total emulsifier amount (emulsifier com¬ ponent) . Preferred compositions are those in which the total amount of anionic emulsifiers constitutes no more than 4.4%, rather constitutes no more than 3.8%, pre¬ ferably constitutes no more than 3%, in particular constitutes no more than 2.4%, and especially constitu¬ tes no more than 1.8%, and which simultaneously is at least 0.03%, rather is at least 0.05%, preferably is at least 0.07%, in particular is at least 0.1% and espe¬ cially is at least 0.14%, and in which the interval limits for instance constitutes 0.03 to 4.4%, rather constitutes 0.05 to 3,8%, preferably constitutes 0.07 to 3.0%, in particular constitutes 0.1 to 2.4% and especially constitutes 0.14 to 1.8%, all the above per- centages being on the basis of weight of the total com¬ position or, in case of a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. It is particularly advantageous when the com- position contains one or more anionic emulsifiers that it only to a limited extent or not at all contains amine containing emulsifiers (e.g. an ethoxylated amine or an amfolyte) , so that a possibly simultaneous con¬ tent of one or more amine containing emulsifiers is no more than 2.4%, preferably no more than 1.8%, in par¬ ticular no more than 1.2% and especially no more than 0.6% calculated on the basis of weight of the total composition or, in case of a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture, and in which the amine containing emulsifiers being available either on un-neutralized form or sodium chloride form as regards quantity must be calculated on the form in which they are available in the formulation. It is an advantage that the anionic emulsifier(s) does(do) not simultane¬ ously contain an amide group. Advantageous compositions containing a mixture of a non-ionic emulsifier and an anionic emulsifier and optionally an amine containing emulsifier are those, in which the total content of the anionic emulsifiers and the possible amine containing emulsifiers constitutes no more than 3.8%, preferably no more than 3%, part¬ icularly constitutes no more than 2.4%, and especially constitutes no more than 1.8%, and which simultaneously is at least 0.03%, rather at least 0.05%, preferably at least 0.07%, in particular is at least 0.1% and espe¬ cially is at least 0.14%, all the given percentages being on the basis of weight of the total composition or, in case of a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture, and wherein the ionic emulsi- fier being available in un-neutralized form or sodium chloride form as regards quantity must be calculated on the form in which it is available in the formulation. Preferred non-ionic emulsifiers are those selected among ethoxylated, propoxylated or co-ethoxyl- ated/propoxylated mono-, di-, tri- or tetra-Ci-ig-al- kylphenol, including in particular C4_i5-alkyl phenol and analog, unsaturated hydrocarbyl phenol; ethoxy¬ lated, propoxylated or co-ethoxylated/propoxylated mono-, di- or tri-styrylphenol (tri-(l-phenylethyl)- phenol), optionally substituted by one, two, three or four C _ 5-al l groups; ethoxylated, propoxylated or co-ethoxylated/propoxylated naphthol or mono-, di- or tri-styrylnaphthol, optionally substituted by one, two, three or four Cι_i5-al l groups; ethoxylated, pro- poxylated or co-ethoxylated/propoxylated mono- or di- cyclohexylphenol or mono-, di- or tri-styryl substitut¬ ed mono- or di-cyclohexylphenol, optionally further substituted by one, two, three or four Cι_i5-al yl groups; ethoxylated, propoxylated or co-ethoxyla- ted/propoxylated phenylphenol or mono-, di-or tristyryl phenylphenol, optionally substituted by one, two, three or four C _i5~alk l groups; ethoxylated, propoxylated or co-ethoxyleret/propoxylated mono-, di- or tri-benzylphenol, optionally substituted by one, two, three or four Cι_i5-al l groups; ethoxylated, propoxylated or co-ethoxylated/propoxylated mono-, di- or tri-benzyl phenylphenol, optionally substituted by one, two, three or four alkyl groups; ethoxylated, pro¬ poxylated or co-ethoxylated/propoxylated formalin con- densed phenol or naphthol, preferably consisting of maximally 8 phenol-/naphthol-units, and which optional¬ ly per aromatic core may be substituted by one, two or three alkyl groups; ethoxylated, propoxylated or co-ethoxylated/propoxylated C8-30~hydrocarbyl alcohol, preferably C9_22 _n ydrocarbyl alcohol, which further may optionally be methylated in the terminal OH-group of the polyalkoxylene; mono-carboxylic acid esters of polyethylene glycol, polypropylene glycol and co-poly¬ merized polyglycols of ethylene glycol (ethylene oxide) and propylene glycol (propylene oxide), in which it applies to all three types of polyglycol that the o number of alkoxy-units must be at least 4, and a c 8 -30"hydrocarbyl carboxylic acid, preferably a a_10-22~hydrocarbyl carboxylic acid; dicarboxylic acid esters of polyethylene glycol, polypropylene glycol and copolymerized polyglycols of ethylene glycol (ethylene 5 oxide) and propylene glycol (propylene oxide), in which it applies to all three types of polyglycol that the number of alkoxy-units must be at least 6, and two mutually independent C8-3o~hydrocarbyl carboxylic acids, preferably two Cιo-22 _n ydrocarbyl carboxylic acids which may, however, very well be identical; block polymers (copolymerisates) of ethylene oxide and styrene and of ethylene glycol (ethylene oxide) and propylene glycol (propylene oxide) the molecular weight of which is in the interval from 1000 to approximately 20.000 Dalton, preferably from 1800 to 16.000 Dalton. Other preferred non-ionic emulsifiers are those selected among ethoxylated or co-ethoxylated/propoxyl¬ ated vegetable oils, e.g. castor oil; fatty acid esters of polyalcohol, e.g. sorbitol, which per se is an emul- sifier but which may also further be alkoxylated (etho- xylared, propoxylated or coethoxylated/propoxylate ) ; monoglyceride, diglyceride and polyalcoholate of natur¬ al fatty acid which may be further esterified with C _ 4 -monocarboxylic acid (e.g. acetic acid), Cι_ιo- i- carboxylic acid (e.g. adipic acid) and Cι_g-hydroxy- carboxylic acid (e.g. lactic acid) and which may further be alkoxylated. Further preferred non-ionic emulsifiers are those selected among N-C4_i6-alkyl-pyr- rolidone, in particular N-C8-i6 _ alkylpyrrolidone, hy¬ drocarbyl carboxylic amide and alkoxylated variants thereof; hydrocarbyl sulfonamide and alkoxylated vari- ants thereof; alkoxylated hydrocarbyl mercaptane, alkoxylated thiopheno'l and alkoxylated thionaphthol. Further relevant non-ionic emulsifiers are those selected among ethoxylated or co-ethoxylated/propoxyl¬ ated Cg-30-hydrocarbyl amine, preferably C8-22~ n ydro- o carbyl amine having at least 5 alkoxy groups, in part¬ icular with 5 to 15 ethoxy groups. It applies to the non-ionic emulsifiers that all co-ethoxylated/propoxylated emulsifiers have a molecul¬ ar weight up to 20.000 Dalton, preferably up to 16.00.0 5 Dalton and in particular up to 12.000 Dalton. Emulsifiers that are solely ethoxylated pre¬ ferably have a HLB-value of no more than 14, preferably of no more than 13, in particular no more than 12 and especially of no more than 11, and simultaneously of at least 3, preferably of at least 4, in particular of at least 5 and especially of at least 6, e.g. in the interval of 3 to 14, preferably in the interval of 4 to 13, in particular of 5 to 12 and especially from 6 to 11 (HLB = Hydrophilic-Lipophilic-Balance; H B-values are theoretically calculated values used in connection with ethoxylated, non-ionic emulsifiers. The HLB-value is directly proportional to the content of oxyethylene. HLB-values range between 0 and 20; a low HLB-value indicates an oil soluble emulsifier and the water solubility increases with the HLB-value. Examples of ionic emulsifiers that are cationic are C 8 -C3o-hydrocarbyl amine, C8-C3Q-hydrocarbyl-di- and -triamine, hydrocarbylene-di-amine and ethoxylated, propoxylated or co-ethoxylated/propoxylated C8_3o~hy- drocarbyl amine with no more than 4 alkoxy groups. Other relevante cationic emulsifiers are quaternary amines with at least one group of C8-30 hydrocarbyl- and/or hydrocarbylene. Another type of ionic emulsifiers is amphoteric emulsifiers,characterized by containing at least one group of C 8 -30 _n ydrocarbyl, preferably a Cιo- 22 -n y (3ro ~ carbyl group or at least one group of C8-30 _n ydro-car- bylene, preferably a Cιo-22 -n y drocarb y lene group and in any case at least One amino group and further an anionic group. The anionic group must preferably be selected among carboxylic acid, sulfonic acid and phos- phonic acid. Particularly preferred emulsifier components are those in which the emulsifier component consists of a mixture of a number of non-ionic emulsifiers and a number of anionic emulsifiers. It appears from the above referenced patent applications EP-A2-142670 and EP-A1-243872 that the preferred anionic emulsifier per¬ tains to the phosphate ester type, that is character¬ ized by being extremely effective. It appears from the various examples that the phosphate ester emulsifier always form part of the recipes in larger amounts. The lowest applied quantity of phosphate ester emulsifier is in Example 7, II, in EP-A2-142670. The phosphate ester is reacted with mono ethanol amine to form a salt and constitutes on the basis of weight about 5% of the total composition. It should further be observed that the composition is based on another type of oily com¬ ponent than those preferred in in the present applica¬ tion and that the composition described in Example 7, II, is difficultly emulsifiable and furthermore has a limited storage stability. The inconvenience of the phosphate ester emulsi¬ fiers is that they may form calcium salt with the calcareous content in the diluting water. In order to obtain a slighter sensitivity to calcium the phosphate ester emulsifiers in the previously described formula- tions of the above referenced applications have been used in larger quantities, up to about 15% on the basis of weight of the total composition. For other reasons a high phosphate ester content may be inadvantageous. As mentioned in the opening portion of the present speci¬ fication this might due to problems related to tank mixing reduce the possibility of tank mixing with other emulsifiable pesticide preparations. Another inconveni¬ ence consists in that the phosphate esters are good solvents and that the phosphate ester emulsifier con¬ tent to a small extent may dissolve the finely ground herbicide, thereby providing crystal growth in the pre- paration. It has turned out that an alternative manner of eliminating precipitation is to keep the phosphate ester emulsifier content low so as to limit or totally avoid calcium containing salt deposits. Advantageous emulsifier components are therefore those in which the anionic moiety consists of various types all of which are ingredients in restricted amounts. Very advantageous compositions are those in which the anionic emulsifiers and optionally other sta- bilizers as aromatic acid stabilizers wholly or partly are selected from the following types marked a, b, c, d, e, f, g, h og i: a_ Phosphate ester emulsifiers preferably selected among those containing at least one aliphatic C8- 0-fry- drocarbyl group, preferably a C o-3θ~ n ydrocarbyl group, or an aliphatic Cs-40-hydrocarbylene group, preferably a C o-30~hydrocarbylene group, or a monovalent or divalent, straight-chained or branched, wholly or partly aromatic hydrocarbon group having 8 to 40 car- bon atoms, preferably 10 to 30 carbon atoms, and in which the emulsifier contains at least one phosphate ester group, that is di- or monoesterified so as to concurrently provide one or two acid groups that may either be free or be wholly or partly converted to salt. Moreover, the hydrocarbon group(s) (hydrocar¬ bylene group(s)) of the phosphate ester emulsifier be substituted by at least one -OH group preferably alk- oxylated (ethoxylated or co-ethoxylated/-propoxylated) , and in which the alkoxy group via the terminating -OH group forms part of the phosphate ester group. Pre¬ ferred types of phosphate ester emulsifiers are mono- and diesters of phosphoric acid and of ethoxylated, propoxylated or co-ethoxylated/propoxylated mono-, di- or trialkylphenol, and of phosphoric acid and of ethoxylated, propoxylated or coethoxylated/propoxylated mono-, di- or tristyrylphenol (tri-1-phenylethyl)- phenol), optionally substituted by one, two, three or four alkyl groups, and of phosphoric acid and alkoxy¬ lated styrylnaphthol, alkoxylated dicyclohexylphenol or alkoxylated benzylphenol, and of phosphoric acid and ethoxylated, propoxylated or co-ethoxylated/ propoxy- lated C8-30 -n ydrocarbyl alcohol, preferably c 1 0-22~hydrocarbyl alcohol and of phosphoric acid and non-alkoxylated C8-22~ n ydrocarbyl alcohol, preferably Cιo-i8~hydrocarbyl alcohol. The number of alkoxy groups of the phosphate ester must not exceed 40 oxyalkylene units, preferably not exceed ' . 25 oxyalkylene units. b Sulfonic acids, preferably selected among ben¬ zene sulfonic acid, substituted by one, two or three Cι_3o-alkyl- and/or C2_30~al enyl groups, or benzene sulfonic acid, preferably substituted by one, two or three C4_i6~al yl- and/or C4_ιg-alkenyl-groups, or selected among Cs-so-alkyl sulfonic acid, Ce-so-alkenyl sulfonic acid or C8-50 -c hl° r ° lkyl sulfonic acid, preferably Cs-30-alkyl sulfonic acid, Cs- 30 - lkenyl sulfonic acid or C8-30 -cn l or °al yl sulfonic acid, in particular C o-22 _a lkyl sulfonic acid, Cιo-22~ al kenyl sulfonic acid or C o-2 2 _c hloroalkyl sulfonic acid, or selected among non-naphthalene-containing petroleum or oil with a carbon chain length of 8 to 60 atoms, pre¬ ferably 10 to 40 atoms that are mono-, di- or tri-sul- fonated, and in which all of the sulfonic acid groups are available as a free acid or are wholly or partly converted to salt. £ Esters or semi-esters of sulfosuccinic acid (sulfosuccinate) wherein the sulfonic acid group and optionally one of the carboxylic acid groups are available as free acid or are wholly or partly neutra- lized as salt, and wherein one or both carboxylic acid groups are esterified ' . The alcohol used in the esteri- fication may be selected among Cs-30 hydrocarbyl alco¬ hols, in particular a CIQ_22 hydrocarbyl alcohol; phe¬ nol substituted by one, two or three C2-3o~alkyl and/or alkylene groups; benzyl alcohol, optionally substituted by alkyl, (poly)phenylphenol, inter alia tristyrylphe- nol, wherein each aromatic ring may be substituted by one, two or three C2-30 _ al yl- and/or alkenyl groups; or formalin condensed phenol having up to 8 groups of formalin per molecule, and wherein each phenol ring may be substituted by one, two or three C2_30 _ lk l- and/or alkylene groups, and wherein preferably each phenol group is esterified with sulfosuccinic acid. Particularly preferred sulfosuccinic acids are those in which the above mentioned alcohols or phenols are at first alkoxylated with 1 to 40 oxyalkylene units, e.g. 1 to 40 oxyethylene units, 1 to 40 oxypropylene units or a combination of in total 1 to 40 oxyethylene units and oxypropylene units. d_ Mono-sulfate ester derivatives preferably selected among mono-sulfate esters of C8-20 -a lkyl al¬ cohol or C8-20~ a l^ en yl alcohol either non-ethoxylated or ethoxylated with 1 to 8 oxyalkylene units, e.g. l to 8 oxyethylene units; and selected amon monosulfate esters of phenylpolyalkylene glycolether alcohol, substituted by one, two or three C2-30~ lkyl- and/or alkenyl groups, and wherein the group of polyalkylene glycolether is constituted by 2 to 40 oxyalkylene units, preferably mono-sulfate esters of phenylpoly- ethylene glycolether alcohol, substituted by one, two or three C2-30 -a l k yl and/or alkenyl groups, and wherein the polyethylene glycol group is constituted by 2 to 40 oxyethylene units; and selected among mono-sulfate esters of benzyl-substituted poly-alkylene glycol¬ ether alcohol or polyphenyl polyalkylene glycolether alcohol and alkylated derivatives thereof, such as mono-sulfate ester of tristyrylphenol polyethylene glycolether, wherein each aromatic ring may be subs¬ tituted by one, two or three Cι_3o-alkyl- and/or alke¬ nyl groups, and wherein the polyethylene glycol group is composed of 2 to 40 oxyethylene units, and wherein all of the mono-sulfate esters are available as free acid or a wholly or partly converted to salt. e Naphthalene sulfonic acid derivatives preferably selected among naphthalene sulfonic acid, optionally substituted by one, two or three Cι_i2-alkyl- and/or C2_12-alkenyl groups, and which are available as free acid or wholly or partly converted to salt, and corres¬ ponding naphthalene sulfonic acid that is formalin con¬ densed. f Sulfonated carboxylic acid derivatives, prefer- ably selected among straight-chained or branched, saturated or unsaturated C8-30-hydrocarbyl carboxylic acid substituted by one or two sulfonic acid groups, or mono-, di-, or triglycerides of the same sulfonated carboxylic acids available as free acid or which are wholly or partly converted to salt. 2 Aliphatic C8_30-hydrocarbylene-dicarboxylic acids, preferably Cιo-20~hydrocarbylene dicarboxylic acid and aliphatic, chloro-substituted, C8-3o-hydro- carbylene-dicarboxylic acid, preferably chloro-substit- uted Cιo-22~hydrocarbylene-dicarboxylic acid. C 4 _20 -a lkyl- or C 4 _20 -a lkenyl substituted, straight-chained or branched, saturated or unsaturated Cι_ιo-hydrocarbylene-dicarboxylic acid is particularly preferred, and straight-chained or branched C8-i6- l- kyl-or C8-i6 -a lkenyl succinic acid is extremely pre¬ ferred, e.g. straight-chained or branched dodecyl or dodecenyl succinic acid. The dicarboxylic acids may preferably be available as acid or may wholly or partly be converted to salt. h Polycarboxylic acids preferably prepared by po¬ lymerization or copolymerization, and which are poly- merized from at least one of the following group of monomers consisting of acrylic acid, Cι_i5-alkylacrylic acid, maleic acid, maleic acid anhydride, mono- or di-C _ 5-alkyl maleic acid and mono- or di-Cι_ 5_alkyl maleic acid anhydride, and wherein the remaining mono- o mers optionally may be selected from the group consist¬ ing of vinyl pyrrolidone and ethylene, the latter one of which is either substituted by a straight-chained or branched, aliphatic Cι_20 alkyl or a wholly or partly aromatic hydrocarbon group with 6 to 20 carbon atoms, 5 and wherein the molecular weight of the polymer/co- polymer is in the interval from 1,000 to 50,000 Dalton, rather in the interval from 2,000 to 20,000 Dalton, preferably in the interval from 3,000 to 10,000 Dalton, and in particular in the interval from 5,000 to 8,000 Dalton, and wherein the polycarboxylic acid may be available as a free acid or may be wholly or partly converted to salt, and/or may optionally be partially esterified with polyalkylene glycol, e.g. polyethylene glycol and/or polypropylene glycol, the polyglycolene being moreover methylated in the terminating OH-gruppe. (The chemical stability increases, provided the composition further contains an acid, organic or inor¬ ganic, retaining the pH in the interval 3 to 5. The acid may be partially neutralized to salt. It has turned out that a group of aromatic carboxylic acids besides acting as buffers may stabilize the emulsion when the composition is diluted in water and prevent the formation of sticky precipitations. Said group of aromatic acid stabilizers or the salts thereof do not per se need to be emulsifiers or their salts do not need per se to be emulsifiers and are described under item i) . ά. Benzoic acid, hydroxybenzoic acid, dihydroxyben- zoic acid, mono-, di- or tri-Cι_g-hydrocarbyl-benzoic acid, mono-, di- or tri-Ci-g-hydrocarbyl-hydroxybenzoic acid, mono-, di- or tri-Cι_6-hydrocarbyldihydroxybenzo- ic acid, benzene dicarboxylic acid, benzene tri- carboxylic acid, benzene tetracarboxylic acid, mono-, di- or tri-Cι_6-hydrocarbyl-benzene dicarboxylic acid, mono-, di- or tri-Cι_6~hydrocarbyl-benzene tri- carboxylic acid or mono-, di- or tri-Cι_g-hydrocarbyl- benzene tetracarboxylic acid, in which the acids may be available as free acid or may be wholly or partly con¬ verted to salt. Preferred salts of the acids mentioned under items a to i are monovalent salts, e.g. salts of sodi- urn, potassium, lithium, ammonium, lower alkylamine, lower alkylalkanol amine and alkanol amine, preferably those having no more than 7 carbon atoms, in particular no more than 6 carbon atoms. Examples of the latter are methyl amine, ethyl amine, propyl amine, dimethyl amine, diethyl amine, diethylethanol amine, monoethanol amine, diethanol amine, triethanol amine and isopropa¬ nol amine. Advantageous compositions are those containing one ore more phosphate esters, described above under item a, and in which the total amount of phosphate ester according to the specification in total amounts to at least 0.03%, rather is at least 0.05%, preferably amounts at least to 0.07%, in particular is at least 0.1% and especially amounts to at least 0.14%, and which at the same time constitutes no more than 4.4%, rather constitutes no more than 3.8%, preferably constitutes no more than 3%, in particular constitutes no more than 2.4% and especially constitutes no more than 1.8%, and in which the amounts limits of interval for the amounts e.g. constitute from 0.03 to 4.4%, rather constitutes 0.05 to 3.8%, preferably constitutes from 0.07 to 3,0%, in particular constitutes 0.1 to 2,4% and especially constitutes from 0.14 to 1.8% on the basis of weight of the total composiition or, if it is actually a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. Other advantageous compositions are those con¬ taining one or more sulfonic acids as described above under item b_, and wherein the total amount of sulfonic acid would be specified as amounting at least to 0.03%, rather amounts at least to 0.05%, preferably is at least 0.07%, in particular is at least 0.1% and espe¬ cially is at least 0.14%, and which simultaneously constitutes no more than 4.4%, rather constitutes no more than 3.8%, preferably constitutes no more than 3%, in particular constitutes no more than 2,4% and espe¬ cially constitutes no more than 1.8%, and wherein the limits of intervals for said amounts e.g. constitute 0.03 to 4,4%, rather constitute 0.05 to 3,8%, pre¬ ferably constitute 0.07 to 3.0%, in particular consti- tute from 0.1 to 2,4%, and especially constitute from 0.14 to 1.8% on the bsis of weight of the total com¬ position or, if it is actually a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. Other advantageous compositions are those con¬ taining one or more sulfosuccinic acids described above under item c, and in which the total quantity of sul¬ fonic acid is specified as total amounts of no less than 0.03%, rather no less than 0.05%, preferably no less than 0.07%, particularly no less than 0.1% and especially no less than 0.14%, and which at the same time does not exceed 4.4%, rather does not exceed 3.8%, preferably does not exceed 3%, particularly does not exceed 2.4% and especially does not exceed 1.8%, and in which the limits for the intervals e.g. amount to 0.03 to 4.4%, rather amount to 0,05 to 3,8%, preferably constitute 0.07 to 3.0%, in particular amount to 0.1 to 2.4%, and especially amount to 0.14 to 1.8% on the basis of weight of the total composition or if it is a ready-to-use mixture diluted by the user, calculated on the weight basis of the solids content of said mixture. Other advantageous compositions are those con¬ taining one or more C8-30 _ hydrocarbylene-dicarboxylic acids and/or chloro-substituted C8-30 _ hydrocarbylene dicarboxylic acids, as described under item _, and in which the total quantity of dicarboxylic acid is speci- fied in total amounts of at least 0.03%, rather at least 0.05%, preferably at least 0.07%, in particular at least 0.1% and especially amounts to at least 0.14%, and which concurrently constitutes no more than 4.4%, rather no more than 3.8%, preferably constitutes no more than 3%, in particular no more than 2.4% and espe¬ cially constitutes no more than 1.8%, and in which the limits for the intervals e.g. constitute 0.03 to 4.4%, rather 0.05 to 3.8%, preferably constitutes 0.07 to 3.0%, particularly constitutes 0.1 to 2.4%, and especially constitutes 0.14 to 1.8% on the basis of weight of the total composition or, if it is a ready- to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. Other advantageous compositions are those con- taining one or more polycarboxylic acids as described under item h, and wherein the total quantity of poly¬ carboxylic acid is specified to be in total at least 0.03%, rather at least 0.05%, preferably amounts at least to 0.07%, particularly is at least 0.1% and espe- cially is at least 0.14%, and which concurrently does not exeed 4.4%, rather does not exceed 3.8%, preferably does not exceed 3%, particularly does not exceed 2.4% and especially does not exceed 1.8%, and in which the limits for the intervals e.g. constitute 0.03 to 4.4%, rather constitute 0.05 to 3.8%, preferably constitute 0.07 to 3.0%, particularly constitute 0.1 to 2.4%, and especially constitute 0.14 to 1,8% on the basis of weight of the total composition or, if it is a ready- to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. Other advantageous compositions are those con- taining one or more aromatic acid stabilizers as des¬ cribed under item i , and in which the total quantity of acid stabilizer is specified to be in total no less than 0.03%, rather no less than 0.05%, preferably no less than 0.07%, particularly no less than 0.1% and especially no less than 0.14%, and which at the same time does not exceed 4.4%, rather does not exceed 3.8%, preferably does not exceed 3%, particularly does not exceed 2.4% and especially does not exceed 1.8%, and in which the limits for the intervals e.g. amount to 0.03 to 4.4%, rather amount to 0.05 to 3.8%, preferably constitute 0.07 to 3.0%, in particular amount to 0.1 to 2.4%, and especially amount to 0.14 to 1.8% on the basis of weight of the total composition or, if it is a ready-to-use mixture diluted by the user, calculated on the weight basis of the solids content of said mixture. Other advantageous compositions are those con¬ taining at least one anionic emulsifier as defined above under items a, b, c, d_, e, f, g_, and h or an acid stabilizer, as defined under item i_, and in which the total quantity of emulsifier or acid stabilizer within each individual group amounts to at least 0.03%, rather at least 0.05%, preferably at least 0.07%, in particul¬ ar at least 0.1% and especially amounts to at least 0.14%, and which concurrently does not exceed 4.4%, rather does not exceed 3.8%, preferably does not exceed 3%, in particular does not exceed 2.4% and especially does not exceed 1.8%, and in which the limits for the intervals e.g. constitute 0.03 to 4,4%, rather 0.05 to 3.8%, preferably constitute 0.07 to 3.0%, particularly constitute 0.1 to 2.4%, and especially constitute 0.14 to 1.8% on the basis of weight of the total composition or, if it is a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. More advantageous compositions are those con¬ taining at least two components selected each from their respective group and comprising the anionic emulsifier components as defined above under items a, b, c, d, e, f, cf and h, and/or an acid stabilizer as defined under item i . and wherein the total quantity of emulsifier(s) and optionally acid stabilizer within each of said respective groups amounts at least to 0.03%, rather at least 0.05%, preferably amounts at least to 0.07%, particularly is at least 0.1% and espe¬ cially is at least 0.14%, and which concurrently does not exceed 4.4%, rather does not exceed 3.8%, pre- ferably does not exceed 3%, particularly does not exceed 2.4% and especially does not exceed 1.8%, and in which the limited for the intervals e.g. constitute 0.03 to 4.4%, rather constitute 0.05 to 3.8%, pre¬ ferably constitute 0.07 to 3.0%, particularly consti- tute 0.1 to 2.4%, and especially constitute 0.14 to 1,8% on the basis of weight of the total composition or, if it is a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. Specially preferred compositions are those con¬ taining at least three components selected each from a respective group and comprising the anionic emulsifier components as defined above under items a , b, c, d, e, f, cf, and h and/or an acid stabilizer, as defined under item j., and in which the total quantity of emulsifier and optionally acid stabilizer within each individual of said three groups amounts to at least 0.03%, rather at least 0.05%, preferably at least 0.07%, in par¬ ticular at least 0.1% and especially amounts to at least 0.14%, and which concurrently does not exceed 4.4%, rather does not exceed 3.8%, preferably does not exceed 3%, in particular does not exceed 2.4% and espe- cially does not exceed 1.8%, and in which the limites for the intervals e.g. constitute 0.03 to 4,4%, rather constitute 0.05 to 3.8%, preferably constitute 0.07 to 3.0%, particularly constitute 0.1 to 2.4%, and espe- cially constitute 0.14 to 1.8% on the basis of weight of the total composition or, if it is a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. Other preferred compositions are those in which the total quantity of anionic emulsifier components as defined above under items a, b, c, d_, e_, f, c[ and h, in total amount to at least 0.03%, rather at least 0.05%, preferably amounts at least to 0.07%, particularly is at least 0.1% and especially is at least 0.14%, and which concurrently does not exceed 4.4%, rather does not exceed 3.8%, preferably does not exceed 3%, par¬ ticularly does not exceed 2.4% and especially does not exceed 1.8%, and in which the limites for the intervals e.g. constitute 0.03 to 4.4%, rather constitute 0.05 to 3.8%, preferably constitute 0.07 to 3.0%, particularly constitute 0.1 to 2.4%, and especially constitute 0.14 to 1,8%, all percentages being on the basis of weight of the total composition or, if it is a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. Other compositions are those in which the anionic emulsifiers are wholly or partly selected among lignin sulfate, N-acrylsarkoside and alkyl sulfamido- carboxylic acid. Compositions stabilized in the moderately acidic pH-area with an acid component in which the acid com¬ ponent is either a free acid or as partailly neutral¬ ized salt is appropriate for stabilizing the composi¬ tion due to its buffer effect are such compositions containing myristic acid, acetic acid, propionic acid, chloroacetic acid, chloropropionic acid, lactic acid, malic acid, tataric acid, citric acid, oxalic acid, boric acid and/or phosphoric acid. Besides functioning as a buffer the oxalic acid may have a calcium-precipitating effect on the diluent water, thereby increasing the emulsifying stability in the calcareous water. Oxalic acid is therefore a part- icularly advantageous acid component. A group of polymer substances which at 60 C are solids and which preferably via a dilatation process is stably admixable in water, such as polyvinyl alco¬ hol, polyvinyl pyrrolidone compounds, methyl cellulose, (poly)hydroxyethyl-cellulose, (poly)hydroxypropyl-cel- lulose and (poly)hydroxypropyl methyl-cellulose may apparently coat the surface of the finely ground herbi¬ cide so that the polymer in the same manner as charged, anionic emulsifiers can prevent oil and herbicidal par- tides from conglutinating upon diluting the prepara¬ tion in water. The designation generally practised in chemical language usage for the above identified cellu¬ loses with the prefix (poly)hydroxyethyl- or (poly)- hydroxypropyl is without the prefix (poly)-, when using (poly)- in this description it is to specify that each glycose ring in the cellulose molecule to a certain, but restricted extent may be substituted by various groups of hydroxyethyl or hydxroxypropyl, which may possibly be in alignment of each other so as to be mutually interconnected via ether bindings. With the view of further improve the tank mixable properties of the compositions with other pesticides it is therefore also advantageous that they contain at least one polymer that is a solid at 60°C and which chiefly by dilatation by itself is stably dilutable (soluble) in water at 20°C and which at the same time has a molecular weight of at least 7.000 Dalton, preferably of at least 10.000 Dalton and in particular of at least 13.000 Dalton, in that neither does the polymer include polycarboxylates nor copoly- mers of oxyethylene and oxypropylene with at least 80% by weight of polyoxyethylene and polyoxypropylene or hydrophilic biopolymers, for which the polymerization is effected by an industrially controlled fermentation process (an example of this is xanthene rubber) and in which the total content of the polymeric compoun (s) amounts to 0.04 to 20% by weight, rather 0.05 to 15% by weight, preferably 0107 to 10% by weight, particularly 0.1 to 8% by weight and especially 0.15 to 5% by weight, calculated on the basis of weight of the total composition or, if it is a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. In the following the described polymers are designated polymeric stabilizers. Preferred polymeric stabilizers forming part of the compositions in amounts just mentioned above are selected among non-ionic ethers of cellulose, polyvinyl alcohol, polyvinyl alco¬ hol derivatives, polyvinyl pyrrolidone and pyrrolidone variants. Particularly preferred non-ionic ethers of cell- ulose are (C _2~alkyl) cellulose, ( (poly)hydroxy-C _g- alkyl) cellulose and ( (poly)hydroxy-C _ 6 -alkyl) (C _ 2 ~ -alkyl) cellulose, in particular (Cι~alkyl) cellulose, ( (poly)hydroxy*-Cι_ 4 -alkyl) cellulose and ((poly)hy- droxy-C _4-alkyl)-(Cι_3-alkyl) cellulose such as methyl-cellulose, (poly)hydroethyl cellulose, (poly)hy- droxypropyl cellulose, (poly)hydroxybutyl cellulose, (poly)hydroxy-ethyl-methyl cellulose, (poly)hydroxy- ethyl-ethyl cellulose, (poly)hydroxypropyl-methyl cel¬ lulose and (poly)hydroxybutyl-methyl-cellulose and hydrophobically modified variants thereof, e.g. reac¬ tion products, in which the defined cellulose ethers have reacted with aldehydes or difunktional aldehydes. Preferred polyvinyl alcohol derivatives are polyvinyl alcohol, in which up to 35%, preferably 1 to 30% and especially 8 to 25% of the alcohol groups of the polyvinyl alcohol are esterified with a Cι_ 4 hydro- carbylcarboxylic acid, e.g. with acetic acid to ace- tate. Moreover, the polyvinyl alcohol may be wholly or partly converted to methyl ether or ethyl ether. Such polyvinyl alcohols are preferred, wherein up to 30% of the alcohol groups of the polyvinyl alcohol is convert- ed to ether with methanol, ethanol, polyoxyethylene and/or polyoxypropylene. Other preferred copolymer- isates on the basis of polyvinyl alcohol are those in which at least 35% by mole, preferably at least 60% by mole of the copolymer is composed of vinyl alcohol and/or vinyl alcohol acetate. Copolymerisates are par¬ ticularly preferred in which the residual polymer is constituted by polyvinyl pyrrolidone. Preferred polyvinyl pyrrolidone derivatives are alkylated polyvinyl pyrrolidone and polyvinyl pyrroli- done copolymerisates, in which at least 25% by mole, preferably at least 40% by mole of the copolymer is composed of vinyl pyrrolidone. The number of carbon atoms in the alkyl groups of the polymeric stabilizer- must preferably be in the range from l to 12, in par- ticular 1 to 6 and especially from 1 to 3. At the same time the number of alkyl groups must not be so large that the polymer at 20°C is not still stably dilutable in water. In copolymers partially composed of vinyl pyrrolidone, the remaining monomer should preferably be selected among vinyl alcohol, vinyl acetate and styrene. The molecular weight of the polyvinyl alcohol or polyvinyl alcohol derivative is not particularly deci¬ sive of the effect. Polyvinyl alcohol is normally pre- ferred, the molecular weight of which is in the inter¬ val between 7.000 to 200.000 Dalton, preferably in the interval 10.000 to 175.000 Dalton and especially in the interval 13.000 to 125.000 Dalton, or polyvinyl alco¬ hol, which as a 4% solution in water at 20°C has a viscosity in the interval between 1 to 60 cP (mPa-s), preferably in the interval 2 to 40 cP (mPa-s), deter¬ mined by a Brookfield LVF viscosimeter. The viscosity of the water dilutable cellulose ethers, polyvinyl- pyrrolidone and polyvinylpyrrolidone compounds available in the composition should as solutions of 2% in water at 20 C be low, e.g. down to approximately 2 cP (mPa-s), preferably down to 5 cP (mPa«s). It applies generally that the upper limit to the viscosity is primarily defined for practical circumstances and as regards a solution of 1% in water it must not exceed approximately 10.000, rather not exceed 6.000, prefer- ably not exceed approximately 3.000, particularly not exceed approximately 1.000 and especially not exceed approximately 500 cP (mPa«s) determined by a Brookfield LVF viscosimeter, or a Brookfield viscosimeter accord¬ ing to the instructions given by the supplier of the raw materials. The molecular weight of the polymeric stabilizer may preferably not be below 800.000, rather not below 500.000, particularly no less than 175.000 and espe¬ cially no less than 125.000 Dalton. It has turned out that particularly advantageous polymeric stabilizers are those that are not stably admixable in water at 85°C, e.g. in a concentration of 1% by weight. If the polymeric stabilizer has been dissolved at a lower temperature it might upon heating form a gel that may possibly be stable. It may be desirable to add to the composition one or more glycol components in an amount of 0.5 to 12% by weight, preferably in an amount of 1 to 8% by weight and especially in an amount of 1.5 to 6% by weight, calculated on the basis of weight of the total composition, and in which the glycol component may for instance be selected among ethylene glycol, propylene glycol, hexylene glycol, polyglycols, such as di-, tri- and tetraethylene glycol and di-, tri- and tetra-propy- lene glycol, glycolmethyl ether, glycolethyl ether, butylglycol, butyldiethylene glycol, propylene gly¬ colmethyl ether, dipropylene glycol methyl ether and tripropylene glycol methyl ether. The glycol components may have a promoting effect on the emulsion stability of the diluted product, have a visosity modifying effect and prevent flocculation of the composition. Other adjuvants which are for instance added to improve the low temperature resistance are inorganic salts, such as sodium chloride and potassium nitrate and amine salts, such as monoethanolamine hydrochloride and triethanolamine phosphate, preferably in amounts of 1 to 5% by weight. In order to suppress the tendency to precipitate a compact pesticidal residue during the storage of the suspension it may be advantageous to add a filler. Examples of fillers are naturally available and syn- thetic types of clay and silicates, e.g. naturally available silicium dioxides, such as diatomaceous earth; magnesium silicates, e.g. talcum types; magne¬ sium aluminium silicates, e.g. attapulgites and ver- miculites; aluminium silicates, e.g. kaolinites, mont- morillonites and types of mica; synthetic, hydrated silicium oxide units and synthetic calcium silicates or aluminium silicates; natural resins and synthetic resins, e.g. coumarone resins, polyvinylchloride and styrene polymers and styrene copolymers; and fertil- izers as solids, e.g. superphosphates. Inorganic fillers are preferred. Fillers such as bentonite and hectorite and organic derivatives thereof, such as Bentone, are particularly preferred. If a filler is incorporated in the pesticide preparation, the amount thereof will be 0.1 to 15% by weight, preferably 0.2 to 10% by weight, in particular 0.5 to 5% by weight and especially 1 to 3% by weight. Besides the separation suppressing effect an added filler will frequently also improve the grinding of the pesticidal ingredient, in particular if the grinding is effected in a wet con¬ dition in a pearl mill. If the inorganic filler is added after the grinding process, it exerts a more sedimentation suppressing effect. This is particularly clear when the filler is constitited by needle-shaped crystals as is the case with attapulgite. Interesting herbicidal compositions according to the invention for use in beet fields and comprising an herbicide component suspended in a fine-grained form, a liquid oil-containing phase and an emulsifier part, in which the herbicidal component includes at least one herbicide selected from the following group of beet herbicides consisting of phenmedipham (methyl(3-(3-to- lylcarbamoyloxy)phenyl)carbamate) , ethofumesate ( (±)2- ethoxy-2,3-dihydro-3,3-dimethylbenzofurane-5-yl me¬ thane sulfonate) and metamitron (4-amino-4,5-dihydro- 3-methyl-6-phenyl-l,2,4-triazine-5-on) , so that the total quantity of herbicide amounts to 1 to 45% by weight, preferably 4 to 40% by weight, in particular 7 to 35% by weight, and especially 10 to 30% by weight, and in which the herbicide composition further contains an emulsifier component in an amount of 1 to 18% by weight, preferably of 1.5 to 13% by weight, in par¬ ticular of 2 to 9% by weight, and especially of 2.5 to 5% by weight, and wherein the emulsifier component con¬ tains at least a non-ionic emulsifier and at least an anionic emulsifier, in which the non-ionic emulsi- fier(s) is/are ethoxylated or co-ethoxylated/propoxyl¬ ated, and in which the hydrophobic parts preferably is selected from the group consisting of mono-, di- or tri-styryl phenol, naphthol, mono-, di- or tri-styryl naphthol, dicyclohexyl phenol, mono-, di- or tri-sty- ryl-dicyclohexyl phenol, phenyl phenol, mono-, di- or tri-styryl-phenyl phenol, benzyl phenol, mono-, di- or tri-styryl-benzyl phenol, formalin-condensed phenol or formalin-condensed naphthol, in which all of the above alkoxylated emulsifiers may further be substituted by one, two, three or four Cι_i5-al yl groups, and in which the hydrophobic part may as well be selected from mono-, di-, tri- or tetra-Cι_ιg-alkyl phenol and c 8-30~hydrocarbyl alcohol, and the group of non-ionic emulsifiers further includes mono-carboxylic acid esters of polyethylene glycol and co-polymerisated gly- cols of ethylene glycol (ethylene oxide) and propylene glycol (propylene oxide), in which it applies to both types of polyglycols that the number of alkoxylene units must be no less than 4, and a C8-3o~hydrocarbyl- carboxylic acid, dicarboxylic acid esters of polyethy¬ lene glycol and copolymerisated polyglycols of ethylene glycol (ethylene oxide) and propylene glycol (propylene oxide), in which it applies to both types of polygly¬ cols that the number of alkoxy units must be at least 6 and two mutually independent C8-30-hydrocarbylcarboxyl- ic acids, and further comprises the group of non-ionic emulsifiers, block polymers (copolymerisates) of ethy¬ lene glycol (ethylene oxide) and propylene glycol (propylene oxide), the molecular weight of which is in the range from 1.500 to 20.000 Dalton, preferably from 1.800 to 16.000 Dalton, in that it applies to all, non- ionic co-ethoxylated/propoxylated emulsifiers that they must have a molecular weight up to 20.000, preferably up to 16.000 and especially up to 12.000 Dalton, and that said ethoxylated emulsifiers have a HLB-value not exceeding 14, preferably not exceeding 13, in part- icular not exceeding 12 and especially not exceeding 11, and at the same time at least 3, preferably 4, in particular at least 5 and especially no less than 6, e.g. in the interval of 3 to 14, preferably in the interval of 4 to 13, in particular in the interval from 5 to 12 and especially in the interval from 6 to 11, and in which the mixture optionally contains water and optionally filler, and in which the liquid phase is able to provide an oil-in-water emulsion, when the com¬ position is mixed with water and in which the oil(s) that is/are part of the oil-containing phase and has/have an initial boiling point of at least 210° is/are wholly or partly selected from the group con- sisting of mineral oil having an aniline point deter¬ mined according to DIN 51775, that does not exceed 90°C, preferably does not exceed 87.5°C, in particular does not exceed 85% and especially does not exceed 82.5°C; water-insoluble ester oils having from 10 to 60 carbon atoms of an aliphatic, straight-chained or branched, saturated or unsaturated C _3 Q -hydrocarbyl alcohol optionally alkoxylated with up to 3 alkoxy groups which are preferably ethoxy- and/or propoxy groups, and a monocarboxylic acid, that may be formic acid or which is directly adhered on a straight-chained or branched, saturated or unsaturated, aliphatic hydro¬ carbyl group with from 1 to 30 carbon atoms, preferably 8 to 20 carbon atoms, optionally substituted by one or two hydroxy groups, or a straight-chained or branched, wholly or partly aromatic hydrocarbon group with from 6 to 30 carbon atoms, preferably from 6 to 20 carbon atoms; water insoluble esters with from 10 to 60 carbon atoms of a straight-chained or branched, saturated or unsaturated C _22 _ hydrocarbylene dialcohol (Cι_22~hy- drocarbylene glycol), optionally alkoxylated with up to 5 alkoxy groups, pre-ferably ethoxy- and/or propoxy groups, and a monocarboxylic acid, that may be formic acid, or which is directly adhered to a saturated or unsaturated hydrocarbyl group with from 1 to 30 carbon atoms, optionally substituted with one or two hydroxy groups, preferably from 8 to 20 carbon atoms, or a straight-chained or branched, wholly or partly aromatic hydrocarbon group with from 6 to 30 carbon atoms, pre- ferably 6 to 20 carbon atoms; water-insoluble esters having from 10 to 60 carbon atoms of a straight-chained or branched, saturated or unsaturated C _2 4 ~hydro- carbylene dicarboxylic acid, preferably a C2_i6- ydro- carbylene dicarboxylic acid optionally substituted by one or two hydroxy groups, or of a dicarboxylic acid containing a divalent hydrocarbon group containing one or more aromatic rings so that the group in total con- tains from 6 to 24 carbon atoms, preferably 6 to 16 carbon atoms, optionally substituted by one or two hydroxy groups, and a straight-chained or branched, saturated or unsaturated Cι_3 Q -hydrocarbyl alcohol, optionally alkoxylated with up to 3 alkoxy groups, pre¬ ferably ethoxy and/or propoxy groups, so that the total oil content of the described oils amounts to 8 to 85% by weight, preferably 12 to 77% by weight, in par¬ ticular 18 to 70% by weight, and especially from 25 to 64% by weight, and in which the total amount of anionic emulsifier does not exceed 4.4% by weight, rather does not exceed 3.8% by weight, preferably does not exceed 3% by weight, particularly does not exceed 2.4% by weight, and especially does not exceed 1.8% by weight, and in which said total amount is no less than 0.03% by weight, rather no less than 0.05% by weight, preferably no less than 0.07% by weight, particularly no less than 0.1% by weight, and especially is no less than 0.14% by weight, and in which the limits for the intervals for said amounts e.g. constitute 0.03 to 4.4% by weight, rather constitute 0.05 to 3.8% by weight, preferably constitute 0.07 to 3.0% by weight, in particular cons¬ titute 0.1 to 2.4% by weight and especially constitute 0.14 to 1.8% by weight, and in which a possibly con- current content of one or more amine containing emulsi¬ fiers does not exceed 2.4% by weight, preferably does not exceed 1.8% by weight, in particular does not exceed 1.2% by weight and especially does not exceed 0.6% by weight, in which all the indicated percentages are calculated on the basis of weight of the total com¬ position or, if it is a ready-to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. The composition may optionally further include benzoic acid, hydroxybenzoic acid, dihydroxybenzoic acid, mono-, di- or tri-Cι_g-hydrocarbylbenzoic acid, mono-, di- or tri-Cι_6-hydrocarbyl-hydroxybenzoic acid, mono-, di- or tri-Cι_g-hydrocarbyl-dihydroxyben- zoic acid, benzene dicarboxylic acid, benzene tricar- boxylic acid, benzene tetracarboxylic acid, mono-, di- or tri-C _g-hydrocarbyl-benzene dicarboxylic acid, mono-, di- or tri-Cι_g-hydrocarbyl-benzene tricarboxyl- ic acid or mono-, di- or tri-C _g-hydrocarbylbenzene tetracarboxylic acid, and in which the acid may be available as a free acid or be wholly or partly neu¬ tralized as a salt, and in which the total content of acid-/acidsalt constitutes from 0.04 to 6% by weight, rather 0.05 to 3.8% by weight, preferably 0.07 to 3.0% by weight, in particular 0.1 to 2.4% by weight, and especially 0.14 to 1.8% by weight on the basis of weight of the total composition or, if it is a ready- to-use mixture diluted by the user, calculated on the basis of weight of the solids content of said mixture. Corresponding interesting herbicide preparations analogous to the compositions just stated above are those containing phenmedipham in combination with either ethofumesate and/or metamitron, and in which content and quantities in all respects are identical with the compositions just stated above. The compositions are used in diluting with water to the use concentration which normally constitutes from 0.2 to 10% by weight, preferably 0.5 to 4% by weight, calculated on the final use mixture. The dosage quantities of the use mixtures of the diluted products normally constitute 20 to 500 1/ha, preferably 80 to 200 1/ha. The spraying is carried out in spring shortly after sprouting. General dosage quantities of the active substances per ha will for phenmedipham normally constitute 100 to 1.500 g, preferably 200 to 1.000 g, for ethofumesate 100 to 1.500 g, preferably 200 to 1.000 g and for metamitron 300 to 5.000 g/ha, preferab- ly 500 to 3.000 g/ha. It is also the diluted use mixtures that present favourable properties. Said use mixtures may optionally by mixing be prepared by the user from a non-oily sus¬ pension preparation containing one, two or three of the active beet herbicides and an emulsifiable oil concent¬ rate. The invention thus also includes ready-to-use mixtures diluted by the user and in which the ingredi¬ ents of the composition in this situation are calcul¬ ated on the basis of the solids content of said mix¬ ture, wherein only such components are included, as also stated above, which are either solids or have a boiling point at 760 mm Hg at more than 210°C, so that solvents having a boiling point below 210°C are not taken into account when calculating the solids content. List of Chemicals of Used Components. 1) Viscosity 15 cSt at 40°C, carbon distribution according to ASTM D2140: C_ (aromatic carbon) = 1% C jj (naphthenic carbon) = 45% Cp (paraffinic carbon)= 54%. Aniline point: 90 C. 2) Solvent-refined paraffin oil (Norsk Hydro), vis¬ cosity at 40°C: 20 cSt. Carbon distribution according to ATM D2140: C A = 4%, CN = 30%, Cp = 66%. Aniline point: 95 C. 3) Solvent-refined paraffin oil (Shell), Viscosity at 40°C: 27 cSt. Carbon distribution according to ASTM D 2140: CA = 5%, CN = 33 %, Cp = 62%. Aniline point: 99 C. 4) High-boiling petroleum, flash point 65 to 70°C. 5) Ethoxylated dinonyl phenol (9 oxyethylene units per molecule) (Berol) . t 6) Ethoxylated nonyl phenol (4 oxyethylene units per molecule) (Berol) . 7) Co-ethoxylated/propoxylated fatty alcohol (Hoechst) . 8) Ethoxylated coconut alkyl amine (10 oxyethylene units per molecule) (Hoechst) . 9) 70% solution of coconut-alkyl-β-aminopropanoic acid in an alcoholic mixture (Kenogard). 10) 64% Sodium-oleyl-N-methyl-tauride (Hoechst). 11) Attapulgite clay (Chemie Mineralien G.M.B.H.). 12) Hydro-treated naphtenic oil from Shell, viscosi¬ ty at 20°C: 22 cSt. Carbon distribution accord- ing to ASTM D 2140: C^ = 12%, CJJ = 43 %, Cp = 45%. Aniline point 71°C. 13) Technical 2-ethylhexyl oleate (Oleofina) . 14) Technical 2-ethylhexyl stearate (Oleofina). 15) Ethoxylated nonylphenol (6 oxyethylene units per molecule) (Berol). 16) Ethoxylated nonylphenol (8 oxyethylene units per molecule) (ICI) 17) Co-ethoxylated/-propoxylated nonylphenol (Berol), 18) Ethoxylated castor oil (40 oxyethylene units per molecule) (Hoechst) . 19) Polyethoxylated triglyceride HLB = 14,4) (ICI). 20) Dodecenyl succinic acid anhydride from BP. Converted in all recipes to salt by reaction with base, e.g. monoethanol amine in the pre¬ sence of water. 21) Mixture of alkylnaphthalene sulfonates (DeSoto) . 22) Acidic phosphoric ester of ethoxylated alkyl phenol (Berol) . 23) Acidic phosphoric ester of ethoxylated alkyl phenol (GAF) . 24) Acidic phosphoric ester of ethoxylated alkyl phenol (GAF) . 25) Sodium salt of copolymerised 2,4,4-trimethyl- 1-penten and maleic acid anhydride (molecular weight: 5.000-7.000 Dalton) (Rhδne-Poulenc) . 26) Technical dodecylbenzene sulfonic acid (Berol). 27) 40% sodium polyacrylate (molecular weight: 3.000-8.000 Dalton) (Protex) . 28) Ci2-i8-al yl sulfonate, 60% (Hoechst). 29) Polyvinyl alcohol, degree of hydrolysis: appr. 83%, viscosity of 4% solution at 20°C: appr. 3 cP (mPa-s), estimated molecular weight appr. 20.000 Dalton (Hoechst). 30) Polyvinyl alcohol, degree of hydrolysis: appr. 73%, viscosity of 4% solution at 20°C: appr. 10 cP, estimated molecular weight: appr. 68.000 Dalton (Hoechst). 31) Polyvinyl alcohol, degree of hydrolysis: appr. 80%, viscosity of 4% solution at 20°C: appr. 4 cP, estimated molecular weight: appr. 27.000 Dalton (Hoechst). 32) Polyvinyl alcohol, degree of hydrolysis: appr. 98,5%, viscosity of 4% solution at 20 C: appr. 3 cP, estimated molecular weight: appr. 15.000 Dalton (Hoechst). 33) Polyvinyl alcohol, degree of hydrolysis: appr. 88%, viscosity of 4% solution at 20°C: appr. 40 cP, estimated molecular weight: appr. 120.000 Dalton (Hoechst). 34) Cetyl ether of hydroxyethyl cellulose (Aqualon) 35) (Poly)hydroxyethyl cellulose, viscosity of 1% solution in water at 20°C: appr. 2000 to 2500 cP (Aqualon) . 36) Low-viscous methyl cellulose, molecular weight: appr. 13,000 to 15,000 Dalton, viscosity of 2% solution in water: appr. 15 cP (DOW) . 37) Low-viscous (poly)hydroxypropyl methyl cellulose, viscosity of 2% solution in water: appr. 450 cP, (Courtaulds Chemicals & Plastics). 38) Methyl-cellulose, viscosity of 2% solution in water: appr. 450 cP (DOW). 39) Partially ethoxylated copolymerisate of C 2- 14 - alkylethylene/maleic acid (maleic acid-anhy- dride) , molecular weight: appr. 20.000 Dalton (Akzo) . 40) Ethoxylated castor oil (appr. 90 oxyethylene units per molecule) (Berol). 41) Technical propylene glycol dioleate (Oleofina) 42) Technical ricinoleic acid (Oleofina). 43) Hydrophobic-modified (poly)hydroxyethyl cellu¬ lose (Berol) . 44) Phosphate ester triethanol amine salt of tri- styry1-phenolpol (15)oxyethylene alcohol (Rhόne-Poulenc) . 45) 40% Lauryl alcohol polyoxyethylene alcohol sul¬ fonated succinic acid ester salt (monoester) (Rhόne-Poulenc) . 46) Kerosene, boiling point 190 to 205 C, aromatic content <0,1%. 47) 70% sodium lauryl-trioxyethylene alcohol sul- fate (Albright of Wilson) . 48) Formalin-condensed naphthalenesulfonic acid: Na-salt (84%) (Harcros). 4 ) Fatty acid sulfonate neutralized to salt (Harcros) . 50) 62% Petroleum sulfonate with an average mole¬ cular weight of 520 Dalton (Witco). 51) Polyphenol ether sulfate (Berol). 52) Tristyrylphenol poly(15)oxyethylene alcohol sulfate (Harcros). 53) 2-Ethylhexyl sebacate (diester). 54) Dioleic acid ester of polyethylene glycol (M=200 Dalton) containing 2% free oleic acid (KVK AGRO) . 55) Technical n-butyl oleate (Oleofina). 56) Ethoxylated nonyl phenol (10 oxyethylene units per molecule) (Berol). 57) Ethoxylated branched C9_n-al yl alcohol (5-oxy- ethylene units per molecule) (Berol). 58) Ethoxylated branched Cg_n-alkyl alcohol (7 oxy¬ ethylene units per molecule) (Berol). 59) Ethoxylated castor oil (18 oxyethylene units per molecule) (Berol). 60) Acidic phosphoric ester of ethoxylated alkyl alcohol (Harcros). 61) Water-soluble vinylpyrrolidone/vinylacetate copolymer in a molar ratio of 60/40 (GAF) . 62) Water-soluble alkylated vinylpyrrolidone polymer (GAF) . 63) Sodium sulfosuccinic acid octyl ester (Cyan- amide) . Concurrently with the present patent application an equivalent patent application is filed, relating to oily suspension concentrates containing PMP, etho¬ fumesate and/or metamitron, in which the examples pri¬ marily show the definition of the used polymeric stabi¬ lizers. The examples illustrated in the parallel appli- cation may be used as a supplement to the present application. In order to facilitate the clearness the same list of chemicals has been used with the same num¬ bering in the two applications. On the other hand the lists of chemicals may include chemicals that do not form part of the examples described in the application concerne . Example 1 The Examples deal with suspensions containing metamitron and phenmedipham, in which the detergent content is simultaneously low. All previous examples of such compositions are based on paraffinic mineral oil, see Example 7 in patent application EP 142,679 and Examples 1 to 4 in patent application EP 243,872. The compositions lb and lc in Table I are optimized as regards the emulsion property, and as regards emulsion ability as well as storage stabiity they are on a level with the properties described in the above referenced patent applications. The compositions la, lb and lc are obtained by mixing at first mineral oil and petroleum. Subsequent¬ ly, the emulsifiers have been added in the stated order, and a thorough stirring has been effected prior to the addition of the perchloric acid, following which phenmedipham (PMP) and metamitron were added and stirred into the preparation. The grinding has been effected three times at a periphery velocity of appr. 10 m/sec. on a 0.6 1 Dyno-Mill at a dosing ratio of appr. 3 1/h. After the grinding the Attagel is stirred in, thereby offering the best, physical storage stability. Post-mixing has been effected on a high-speed-mixer to a homogeneous, liquid paste. The dilution emulsion test was carried out by preparing 3 vol% solutions (100 ml) in deionized water and municipal tap water. A stirring was effect for one hour on a magnetic stirrer in a 150 ml beaker. Then the emulsions were allowed to rest for one hour and were visually compared to each other. All tests showed a limited tendency to liberate oil. But all the eva- luations showed that sample la clearly offered the most stable emulsions. Tank mixing experiments with beet pesticides have not been carried out because none of the recipes has been optimized in this respect. The sedimentation test was effected with a plain spatula which was slowly inserted into the undiluted storage samples that had being standing at 25°C in a 100 ml test glass without being shaken. Sample la gave a clear, hard glass sound as the spatula impinged on the bottom. This was not the case with samples lb and lc and showed clearly that a coherent sedimentation layer had settled on the bottom of said glasses. The Examples show that the replacement of paraf- finic mineral oil by naphthenic mineral oil offers an increase emulsifying stability as well as an increased storage stability which latter feature is extremely surprising. The 10% high-boiling petroleum available in all three samples is added to impart to the compositions a reasonably low viscosity and is for this reason desirable. From a toxilogical point of view petroleum is undesired in the products. Conclusion: Naphthenic mineral oil offers an increased emulsifying stability as well as an increase storage stability. Table 1 la lb lc Raw material component Composition in % by weight Active component: PMP, tekn. 97% Metamitron, 97 Oil: Aromatic-free oil ) Hydropar 19 2) Shell HVI 60 3) Petroleum 4) Emulsifier component: Berol 269 5) 2.6 2.6 2.6 Non-ionic Berol 26 6) 2.4 2.4 2.4 Non-ionic Genapol 2909 7 ) 0.8 0.8 0.8 Non-ionic Genamine C100 8) 0.6 0.6 0.6 Containing Amine Ampholyt SKKP-70 9) 1.9 1.9 1.9 Containing Amine Arkopon T, pulv 1° ) 0.6 0.6 0.6 Anionic emulsifier Perchloric acid, 70% 1 1 1 Partially converted to salt inorganic filler: Attagel 40 H ) Summed recipe: Active content, techn. 31.5 31.5 31.5 Emulsifier comp. 8.8 8.8 8.8 Miscellaneaous 1.1 1.1 1.1 Inorganic filler 5 5 5 Tabel 1 continued Emulsifiability after 6 months 3% dilution D.W. a) : T.W. b) : Sedimentation after 6 months at 25°C none clear clear tendency tendency a) D.W. = Deionized water p) T.W. = Tap water, 20-25°C Example 2 The examples show a biological screening com¬ parison test carried out as field experiments between 160 g/1 oil-containing PMP-suspension concentrates with only 4% emulsifier, and the oil-containing suspension concentrate actually marketed by Schering, marketed under the trade name Betanal+ containing 160% PMP and 19% emulsifier. (Experience as regards emulsion pre¬ parations in which the PMP is dis-solved in the oily phase shows that a specific quantity of the emulsifier component is necessary to obtain a sufficiently good biological effect (cf. SE patent publication No. 357,486). The optimum quantity of emulsifier amounts to appr. 20% by weight, corresponding to what is normal in all commercial preparations. The compositions 2b, 2c, 2d and 2e were prepared by firstly admixing the PMP in the oily phase and sub¬ sequently adding the emulsifier components and water obtained as a pre-mixing by mixing at first water + monoethanol amine and DDSA. The remaining ionic emusi- fiers are then added and finally the non-ionic emulsi¬ fiers in the indicated order. Formic acid and Attagel are subsequently added. The grinding was effected three times on a 0.6 1 Dyno-mill at a circumferential velo¬ city of appr. 10 m/sec. and at a dosing velocity of appr. 3 1/h, or until appr. 90% of the particles had a grain size not exceeding 5μ. As regards samples 2d and 2e a past-grinding was performed by adding oxalic acid, monoethanol amine salt and oxalic acid-K-salt which was not completely con¬ verted to salt. The purpose of the additions is to pre¬ vent calcium from the diluting water from reacting with the anionic emulsifiers and forming hard-ly soluble Ca- salts. The oxalic acid salts react with the calcium ions in the water and form hardly soluble calcium oxalate. This contributes to improving the longlife emulsion stability in hard water. The biological testing was effected in lots of 2 x 12 meter with 4 repetitions. In experiment 9032 the beet type was Amethyst sown on 31 March 1990, and in experiment 9033 the beet type was Matador sown on 8 April 1990. In experiment 9032 the beets were sprayed first time on 2 May and second time on 8 May. In experiment 9033 the beets were sprayed first time on 1 May and second time on 9 May. All dosages were of 3 1/ha. A non-treated lot and lots treated completely as the experimental lots were included as reference, treated with Betanal (160 g/1 PMP-containing emulsion concentrate) and Betanal+ (160 g/1 PMP-containing suspension concentrate) . Experiment 2a indicates the summed recipe of Betanal+. Recipe compositions of Betanal are not included in the scheme, the formulation type being totally different. The biological effect in % is calculated according to the following formula: 100 x g weed per m 2 of treated lot g weed per m 2 of untreated lot The quantity of weed of the untreated lot is stated uttermost to the left in the scheme. In both experiments Betanal and Betanal-. had the same biological effect, so that column 2a states both the biological effect of Betanal as well as of Betanal+. Conclusion: Even though there have been great differences in the content of emulsifiers of the prepa¬ rations, all of the preparations have presented a satisfactory biological effect. Table 2 continued % biological effect: Experiment 9032 Effect: 100% 100% 100% 99% 99? (untreated: 2828 g/m 2 ) Experiment 9033 Effect: 99% 100% 100% 98% 99? (untreated: 2102 g/cm 2 ) Example 3 The examples show comparison testing between Betanal+ (charge No. 902), sample 3a and a composition, sample 3b, described in accordance with this invention. The composition 3b is obtained by preparing at first a 50% aqueous dispersion of PMP in water. The aqueous PMP-slurry further contained 1.25% of Berol 02, 0.625% of Berol 922 and 0.625% of Berol 724. After mix- ing to obtain sample 3b it corresponds to 4 g/1, 2 g/1 and 2 g/1, respectively. The grinding was effected three times on a 0.6 1 Dyno-mill at a circumferential velocity of appr. 10 m/sec. and at a dosing velocity of appr. 3 1/h, or until at least 90% of the particles had a grain size not exceeding 5 μ. The salicylic acid was subsequently dissolved in Radia 7131. The remaining oils were added and mixing was effected. A little water and the emulsifiers which had not been used for the preparation of the PMP-suspension were then mixed and subsequently added to the oil mixture, and agitation was effected. Then the ground PMP-suspension was added, Mowiol was added as a 30% solution and finally the remaining amount of water and Attagel was added. The composition 3b was thoroughly stirred on a high-speed-mixer, and a final, not particularly effect¬ ive grinding on a "Mini-mill" was effected, manu¬ factured by Eiger Engineering LTD Warrington, Cheshire, England, Model M 50 VSE TFV, filled with appr. 35 ml 1 mm Zirconium balls. The purpose of the grinding was primarily to split agglomerated Attagel. Betanal+ (charge nr. 302) was used as reference 3a-I. Since the product was comparatively coarse¬ grained, a sample of Betanal+ was ground on a 0.6 1 Dyno-mill, so that the grain size of the larger par- tides was reduced from about 20μ to 5μ corresponding to sample 3b. This sample was named 3a-ll. The storing experiments were carried out for a period of 40 days, during which the samples were alternately stored at room temperature (25 C) and at 55°C. The switching was effected manually every day and no samples were switched at week-ends. The measurings of the particle size were effected on evaluation by micro-examination and appear from the scheme. Sample No. 3b differed completely from samples 3a-I and 3a-II, which were not substantially different, even though the particle size of the samples initially had been very unequal. The accelerated testings correspond to a storage for several years under normal storing con¬ ditions and are much harder compared to what a product is generally subjected to. Conclusion: Sample 3b was decisively better than samples 3a-I and 3a-II. The observed, restricted crystal growth in sample 3b does not appear to involve problems, neither as regards the storage stability nor the biological effect. Table 3 3a 3b Raw material Component Composition in % Active component: PMP, techn. 97% 17.0 Oil: Gravex 921 12) Radia 7131 14) Isononanoic acid Oleic acid Emulsifier component: Berol 02 I 5) Berol 922 i7) Emulsogen EL 18) DDSA 20) Berol 724 22) Gafac RE 410 23) Sulfosoft 26) *Acrylon All 27) Monoethanol amine Acid stabiliser: Salicylic acid Polymer stabilizer: Mowiol 3/83 29 ) 0.3 Water and filler: Water Attagel Summed recipe: Active content, 97% 17.5 Oil 58 Emulsifier component 19 Acid stabilizer Polymer stabilizer Water, acid and filler 5.5 *Delivered as an aqueous solution, but stated on the basis of the solids content. The Example illustrates the stability of ester oil in the described composition. Sample 3b was stored for 42 days constantly at 55°C. The content of liberated 2-ethylhexyl alcohol was analyzed both before and after the storing to 0.03% and 0.05%, resp., and corresponds to an increase of 0.02% absolute. The content of esterified 2-ethylhexyl alcohol in Radia 7131 (2-ethylhexyl stearate) was appr. 33% corresponding to appr. 10.5% in sample 3b. The decompo¬ sition of 0.02% absolute corresponds to a relative decomposition of appr. 0.2%, which is extremely low. A storage at 55°C for 42 days corresponds to a storage of several years under normal conditions. Example 5 The examples show comparison tests between dif¬ ferent suspensions containing appr. 100 g/1 PMP and 100 g/1 ethofumesate. In the actual systems the influ¬ ence of the water content and the pH on properties, such as stability of active substances, physical stabi¬ lity, emulsion stability and the tendency to crystal growth was examined. The patent literature shows apparently no examples of analogous products, in which both PMP and ethofumesate have been suspended in an oil containing, liquid phase. In comparison with the samples provided in accordance with the present invention a formulation has been prepared which corresponds to the marketed product Betaren+, from which appr. 4% mineral oil has been removed, thereby providing space for appr. 100 g/1 PMP and 100 g/1 ethofumesate. This product was ground on a Dyno-mill so that 90% of the particles had a par- tide size not exceeding 5 μ. Moreover, a total of 25 different samples have been prepared for mutual comparison. All the recipes are included in the chief recipe in Table 5, wherein the amount of water, Gravex 921 oil, oleic acid and isononoic acid in total constitutes 70.3% by weight. Six sets of samples have been prepared for which the water quantity was being varied from 2% to 49%, and for each set of samples four sub-samples were prepared with pH-values of 3, 3.7, 4.5 and 5.5, respectively. The fine tunings were effected with very small amounts of concentrated hydrochloric acid or monoethanol amine. All samples are prepared according to the same principle as described in Example 2. The samples have been stored at 45°C. The eva- luation was effected after 45 and 87 days and appears from the Tables. After 45 days the samples with a water content of 2% and 49% were discarded, because they had a tendency either to sediment or to gelatinize. Conclusion: Samples with a small water content have a tendency to sediment. Samples with a large water content has a ten¬ dency to gelatinize. A low pH may in unison with a higher water con¬ tent cause the product to become viscous by storing. The emulsifiability appears to be dependent on the pH but is of course also dependent on the formula¬ tion proper. An initiating instability of PMP is noticed at pH 5.5. The decomposition may, however, not be charac¬ terized as unacceptable and particularly not if the water content is high (39%). A limited tendency to crystal growth is noticed after 87 days of storage, independent of pH. The crystal growth decreases at increasing water content. It is a characteristic feature that all samples have a fairly high content of fine-grained active substance. In comparison, the "Betanal-. "-copy shows a pro- nounced tendency to crystal growth after 45 days of storage at 45°C. At the same time the sample had become rather viscous and could only after thorough agitation be homogenized again. The emulsifiability could after the 45 days merely be characterized as reasonable, but not good. A tendency to decomposition of ethofumesate was observed. Table 5a Raw material Composition by % component Active component: PMP, techn. 97% Ethofumesate, techn.' 97 Oil + water in total: Emulsifier component: Berol 02 I 5) Non-ionic emuls, Berol 269 5) Non-ionic emuls. Synperronic NX 16 ) Non-ionic emuls. Berol 922 17 ) Non-ionic emuls. Berol 192 40) Non-ionic emuls. Emulsogen EL i8) Non-ionic emuls. Atlox 1285 I 9) Non-ionic emuls. DDSA 2 ° ) Emulsif. type g Morwet EFW 21 ) Emulsif. type e Berol 724 22) Emulsif. type a Gafac RE 410 23) Emulsif. type a Sulfosoft 26) Emulsif. type b *Acrylon All 27) Emulsif. type h Monoethanolamin Polymer stabilizer: Mowiol 3/83 26) 0.3 Filler of inorganic acid: Attagel % H ) 1. Formic acid, 85% 1, Summed recipe: Active content, 97% 20.6 Emulsifier component 6.45 Polymer stabilizer 0.3 Filler and inorg. acid 2.35 Oil and water 70.30 *Delivered as an aqueous solution, but indicated on the basis of the solids content. Table 5b Storage at 45 C Composition No, pH Evaluation after 45 days Evaluation after 87 days Appearance Appearance Emulsifiabilit Water 2.05% 1 3 Gravex 921 63.25% 2 3.7 Oleic acid 2 % 3 4.5 Isononanoic acid: 3 5.5 Gravex 921 19 % 22 3.7 Oleic acid 0.85% 23 4.5 Isononanoic acid 1.25% 24 5.5 Table 5c Example 6 The examples show comparison tests between the marketed product Betanal-. and the composition sample 3b, described in Example 3. The purpose of the compari- son is to evaluate the tank mixing properties of the products with other pesticides. Traditional testing methods of evaluating the emulsion stability are based on agitating the samples in different qualities of water and letting the samples rest in sedimentation glasses and to effect at dif¬ ferent times a visual evaluation of precipitated material both at the top and at the bottom. If tank mixing experiments with the above mentioned two pro¬ ducts are carried out according to the same principle, the testing frequently shows that the products in the tank mixture with other pesticides do not provide inconvenient precipitations. In practical circumstances oily suspension pre¬ parations frequently behave in another way, since there is a non-unimportant risk that a more or less intense contact between the suspended oil drops and solid part¬ icles by the dissolution of the emulsifier component in the water phase results in an adhesion between oil and particles. When carrying out a relevant testing it is therefore necessary that the mixtures are stirred constantly. In the described tank mixing experiments that appear from Table 6, the agitation is effected in a 150 ml beaker by stirring moderately quickly with a magnet. In all experiments the quantity of water amounts to 100 ml. The tank mixture is effected by dispersing at first the oil-containing PMP-preparation in water, following which the second pesticidal pre¬ paration is added while stirring. The samples were eva- luated after - hour, 1 hour and 2 hours, after the agi¬ tation had been stopped for two minutes, Conclusion: The experiments show unambiguously that preparattion 3b is better suited for tank mixing with Nortron and Ethofumesate than the nowadays marketed product Betanal-i-. It appears that Betanal+ in a tank mixture with Nortron preferably has to be as acidic as possible. It appears, however, to be unreal- istic to lower the pH-value of Betanal-i-. Preparation Dilution water Stirring with magnet for 2 without mixing with product 1% PMP preparation + 1% Nor tron ) and stirring for 2 4) PMP cone, not adjusted 5) PMP cone, adjusted with HC1 6 ) PMP cone, adjusted with monoethanol amine 1% PMP preparation + 1% Fusilade 3) and stirring for 2 h 1) Oil containing suspension concentrate with 160 g/1 PMP from Schering AG 2 ) Emulsion concentrate with 200 g/1 ethofumesate from Schering AG 3 ) Emulsion concentrate with 250 g/1 fluazifop-butyl from ICI Sample 3b Betanal+ 4) with no pH-setting, pH (1:10) 3.8 3.1 5) +0,2 g/1 cone. HC1, pH (1:10) 3.4 2.9 6) +0,1-0,2 g/1 MEA, pH (1:10) 4.4 3.5 Example 7 The purpose of this series of experiments is to illustrate the importance of the polymeric stabilizer in connection with oil-containing PMP-preparations ' with Fusilade. Composition 7 was prepared as the basic recipe of the tested formulations. The composition appears from Table 7 and the preparing procedure was corres- pondingly as described for composition 3b in Example 3. 920 parts by weight of composition 7 were agi¬ tated with different quantities of 30% by weight of Mowiol 3/83 solution varying from 10 and up to 600 parts by weight. In case the total amount of mixture did not exceed 1000 parts by weight it was diluted with water up to 1000. The emulsion stability of the samples was tested under thorough stirring with a magnet in 150 ml beaker containing 100 ml liquid. The samples were evaluated after 2 hours. The agitation was effected in deionized water and tap water, pure water and in mixture with Fusilade, respectively. All concentrations were at 1% by volume. Conclusion: The samples to which no solution of Mowiol was added, provided within one hour by stirring in tank mixing with Fusilade distinct, precipitated coatings at the bottom and on the magnet. In contradic¬ tion thereto, none of the other mixtures showed a ten¬ dency to cause precipitations. It should, however, be observed that certain admixtures corresponding to " that the Mowiol amount of the concentrate varied from 5.3 to 9.1% by weight, on standing had a tendency at the top of the beakers to precipitate very small amounts of oil. But it was an essential cosmetic problem without any practical importance. The mixtures which in the concentrate contained 11.8% by weight of Mowiol, did not show the same tendency and offered very stable emulsions. The same was the case when the Mowiol amount varied from 0.3 to 2.4% by weight. Table 7a Raw material component composition in parts by weight Non-ionic emuls, Emuls. type a Emuls. type a Emuls. type b Emuls. type b Emuls. type h pH (1:10) : 3,9 *Delivered as an aqueous solution but indicated on the basis of solids content. Table 7b Stirrin on ma net stirrer for 2 hours Example 8 The examples in this series of experiments illustrate the influence exerted by various, selected polymeric stabilizers by tank mixing of oil containing PMP-preparations with Fusilade. A pre-concentrate corresponding to composition 7 in Table 7 was used as the basis of the recipes. 80 parts by weight of various, water-based polymeric solu- tions were added to 920 parts by weight of said com¬ position, so that the compositions in total attained an amount of 1000 parts by weight. The final compositions appear from Table 8. Tank mixing with Fusilade was effected so that the concentrations of the PMP-prepara- tions and Fusilade in all mixtures constituted 1% by volume of each preparation. The tank mixtures were eva¬ luated after stirring for two hours in deionized water and in tap water. The results appear from Table 8. Conclusion: The experiments clearly show that the tested polymers present a stabilizing effect and that they hamper the precipitation of conglutinated material of finely ground pesticide and oil in the pre¬ pared use solutions. Table 8 Stirring on magnet stirrer 1% + 1% Fusilade Sample Polymer % by Deionized Tap water weight water in pre- paration 1 none % h: fc h: coating coating 2 Mowiol 10/74 3 ° ) 0.3 2 h: neat 2 h: neat 3 Mowiol 4/80 3i) 0.3 4 Mowiol 3/98 32) 0.3 5 Mowiol 40/88 33) 0.3 6 Natrosol 250/HR 5) 0.2 7 Natrosol 250/HR 35) 0.5 8 Natrosol 250/HR 35) 0.8 9 Methocel A 15LW 36) 0.5 10 Celacol HPM 450 37) 0.5 11 " 4 Example 9 The examples in this series of experiments illustrate the influence exerted on the emulsifying stability by various, selected anionic emulsifiers. The recipes 'of the compositions appear from Table 9. The samples were prepared according to the same principle as composition 3b i example 3. Conclusion: Already between composition 9a and 9b, both of which merely contain two anionic emulsi¬ fiers the emulsion testings show great differences. Sample 9a presents a too inferior emulsifying stabili¬ ty, hereas the emulsion stability of sample 9b is close to the acceptable. Samples 9c and 9e have presented an optimum stability in the emsulsions experiments. Stirring for six hours in tank mixing is a very hard testing. It appears to indicate acceptability if the samples after stirring for 2 to 3 hours together with Fusilade do not provide deposits on the magnet. Table 9 9a 9b 9c 9d Raw material Composition in % Emulsifier component type Active component: PMP, techn. 97% 17 17 17 17 Oil: *Delivered as an aqueous solution but is indicated on the basis of the solids content. Table 9 (continued) 9a 9b 9c 9d Raw material Composition in % component Summed recipe Active content, 97% Oil Emulsifier comp. Acid stabilizer Polymeric stabilizer Water and filler pH-setting (1:10) with MEA/HCl to 3.9 3.9 3.8 3.8 Stirring with magnet in 1% dilution Deionized water: lh: 3h:neat 6h:neat 6h:neat deposit 6h:greasy Tap-water: lh: 6h:neat 6h:neat 6h:neat deposit stirring with magnet in 1% dilution + 1% Fusilade. Example 10 The examples in this series of experiments illustrate the influence exerted by a selected, anionic emulsifier on the emusifying stability. A pre-concentrate corresponding to composi¬ tion 7, Table 7, was used as the basis of the recipes. 80 parts by weight of water in which a little anionic detergent was dissolved was added to 920 parts by weight of this composition, so that the compositions in total were constituted by 1000 parts by weight. As the detailed composition by and large appears from Table 7, the illustrated composition 10 in Table 10 is a part¬ ially summed recipe, in which only the emulsifier com- position is specified. Conclusion: The anionic emulsifier type h exerts in the illustrated composition a clear effect on the emulsifying stability in tank mixture with Fusilade. pH adjusted (1:10) with HCl/MEA to 3.9 3.9 Stirring with magnet in 1% dilution. Deionized water: 3h:neat 3h:neat Tap water: 3h:neat 3h:neat Stirring with magnet in 1% dilution +1% Fusilade. Deionized water: il:deposit 3h:neat Tap water: _ ■ _!_:deposit 3h:neat * Delivered as an aqueous solution, but is indicated on the basis of solids content. Example 11 This series of experiments shows examples of optimized recipes with different oil compositions and a somewhat different emulsifier composition. The preparing ' procedure was the same as that described for Composition 3b in Example 3. Conclusion: All the compositions 11a to lid pre- sent a high emulsifying stability, both in dilutions alone and in admixture with Fusilade. *Delivered as an aqueous solution but is indicated on the basis of the solids content. 11a lib 11C lid Summed recipe: Active content, 97% 17 17 17 17 Oil 43.2 45.8 45.8 45.8 Emulsifier component '3.6 3.5 2.9 3.4 Acid stabilizer 1 1 1 1 Polymeric stabilizer 0.3 0.3 0.6 0.6 Water and filler 34.9 32.4 32.7 32.2 pH-adjusted (1:10) with HC1/MEA to 3.7 3.8 4.1 3.9 Stirring with magnet in 1% dilution Deionized water: 4h:neat 4h:neat 4h:neat 4h:neat Tap water: 4h:neat 4h:neat 4h:neat 4h:neat Stirring with magnet in 1% dilution +1% Fusilade. Deionized water: 4h:neat 4h:neat 4h:neat 4h:neat Tap water: 4h:neat 4h:neat 4h:neat 4h:neat Example 12 This series of experiments show examples of optimized recipes containing both PMP and ethofumesate. The preparing procedung was similar to that des- cribed for composition 3b in example 3. The ethofume¬ sate was ground separately as an aqueous dispersion containing 515 g techn ethofumesate, 10 g Berol 02 and 475 g water. The grinding was effected on a 0.6 1 Dyno- mill with a circumferential velocity of appr. 10 m/sec. This pre-mixture was an ingredient of the final com¬ position in the same manner as the aqueous pre-mixed PMP suspension. Conclusion: The compositions 12a and 12b are well suited for tank mixing with Fusilade. Table 12 12a 12b Raw material component Composition in % Emulsifier type Active component: PMP, techn., 97% Ethofumesate, techn. 97% Oil: Gravex 921 12 ^ Radia 7131 14) Radia 7204 4i > Isononanoic acid Oleic acid Emulsifier component: Berol 02 15 > Berol 922 17) Berol 26 6 > Berol 192 40 > Emulsogen El 18) DDSA 20) Berol 724 22 > Gafac RE 410 23) Sulfosoft 26 > *Acrylon All 27) Monoethanol amine Acid stabilizer: Salicylic acid Polymeric stabilizer: Mowiol 3/83 29 > Water and filler: Water 25.8 29.1 Attagel 40 -- 1 ' 1.0 *Delivered as an aqueous solution but indicated on the basis of the solids content. Table 12 continued pH adjusted (1:10) 4.0 4.0 with HC1/MEA to Stirring with magnet in 1% dilution. Deionized water: 4h: neat 4h: neat Tap water: 4h: neat 4h: neat Stirring with magnet in 1% dilution + 1% Fusilade. Deionized water: 4h: neat 4h: neat Tap water: 4h: neat 4h: neat Example 13 This series of experiments show examples of optimized recipes with different anionic emulsifier compositions. The compositions 13a, 13b and 13c were prepared by grinding at first 50% aqueous dispersion of PMP in water. The aqueous PMP-slurry further contained 1,25% Berol 02, 0.625% Berol 922 and 0.625% Berol 724. After mixing to samples 13a to 13c it corresponds to 4 g/1, 2 g/1, 2 g/1, respectively. Grinding was carried out three times on a 0.6 1 Dyno-mill at a circumferential velocity of appr. 10 m/sec. and at a dosing velocity of appr. 3 1/h, or till at least 90% of the particle had a grain size not exceeding 4 μ. The methocel was prepared as a 5% pre-con- centrate in water. The remaining amount of water was used for diluting the aqueous PMP slurry. An optional content of Acylon All and DDSA was subsequently added separately while stirring, the DDSA having at first been reacted with monoethanol amine and water as stated under Example 2. The methocel pre-concentrate was admixed therein. The residual emulsifier amount, exclusive from the monoethanol amine, was admixed to a pre-concentrate and then diluted in the aqueous PMP slurry. Under thorough agitation the Attagel was slurried into the PMP-slurry to form a homogeneous paste. The monoethanol amine was then added. The oil components plus salicylic acid and ben- zoic acid were dissolved to obtain an oily pre-con¬ centrate and while stirring the the aqueous paste slurry was added. Finally the pH value was set by a supplementary addition of monoethanol amine. Conclusion: All the compositions 13a to 13c pre- sent a great emulsifying stability, both in dilutions alone and in admixture with Fusilade. Table 13 13a 13b 13c Raw material comp. Composition in % Emulsifier type Active component: PMP, techn. , 97% 17 17 17 Oil: *Delivered as an aqueous solution but indicated on the basis of the solids content. Summed recipe: Active.content, 97% Oil Emulsifier comp. Acid stabilizer Polymeric stabilizer Water and filler pH adjusted (1:10) with HC1/MEA 3.9 3.9 3.9 Stirring with magnet in 1% dilution. Deionized water: 3h:neat 3h:neat 3h:neat Tap water: 3h:neat 3h:neat 3h:neat Stirringwithmagnet in 1% dilution + 1% Fusilade. Deionized water: 3h:neat 3h:neat 3h:neat Tap water: 3h:neat 3h:neat 3h:neat Example 14 This series of experiments shows examples of optimized recipes with different anionic emulsifier compositions. The compositions 14a to 14f have been prepared in a similar manner as the compositions from Example 13. However, the amount of Berol 02 which has not be used for the grinding of the PMP, has been added to the oily mixture which was admixed in the water slurry while in Example 13 it was together with the remaining emulsifier components dissolved directly in the water phase. Conclusion: Al the compositions 14a to 14f pre¬ sent a high emulsifying stability, in dilutions alone as well as in admixture with Fusilade. Table 14 14a 14b 14c Raw material comp. Composition in % Emulsifier type Table 14 continued Stirring with magnet in 1% dilution Deionized water: 3h:neat 3h:neat 3h:neat Tap water: 3h:neat 3h:neat 3h:neat Stirringwithmagnetin 1% dilution + 1% Fusilade. Deionized water: 3h:neat 3h:neat 3h:neat Tap water: 3h:neat 3h:neat 3h:neat Table 14 (2) 14d 14e 14f Raw material comp. Composition in % Emulsifier type Table 14 (2) continued Stirring with magnet in 1% dilution. Deionized water: 3h:neat 3h:neat 3h:neat Tap water: 3h:neat 3h:neat 3h:neat Stirring with magnet in 1% dilution + 1% Fusilade. Deionized water: 3h:neat 3h:neat 3h:neat Tap water: 3h:neat 3h:neat 3h:neat Example 15 This series of experiments show examples of optimized recipes with different compositions of oils. Moreover, the exemplified compositions have been sub- jected to storage stability testings and control of the emulsifying stability while stirring with other avail¬ able beet herbicides which by experience are difficult to mix in tank with PMP-preparations. The compositions 15a to 15h have been prepared by grinding at first a 50% aqueous dispersion of PMP in water, in the same manner as stated under Example 13. 0.15% of xanthane rubber was, however, further added to the aqueous PMP slurry in order to prevent sedimenta¬ tion during grinding, corresponding to about 0.05% in the final product. After the grinding supplementary amount of 0.1% xanthane rubber was added in example 15b and after dilution with water in order to thicken the product and thereby preventing separation during stor¬ age. Testing: The emulsifying stability was tested under thorough agitation in a 150 ml beaker containing 100 ml water which was either deionized (designated by 0 a D) or was municipal 20 to 25 dH hard tap water (designated by a H) . The reason of this testing is that suspended particles together with emulsified oil in diluted, aqueous solutions have a tendency to preci¬ pitate greasy deposits due to the affinity between oil and slurried solids (in this respect see further Example 6 and the patent specification) . 1% by vol. of the PMP preparation was used in all the experiments re the emulsifying stability. In the tank mixing experiments 1 and ._% by vol., res¬ pectively, of the mixture preparation were used. Apart from the mixture with Goltix WG the PMP-product was emulsified at first in the water. After 1 to 2 minutes the mixture prepara-tion was added undiluted while stirring. The samples were inspected after 1, 2 and 3 hours. In the cases where precipitations occurred (including the formation of light-dispersable fine¬ grained granules) the time has only been marked in the very few situations where the precipitations were observed within 3 hours, in the remaining cases it is implicit that the precipitation was observed after 3 hours (3 h) . The particle size may be measured electronically by laser light but the measuring must then be effected prior to adding the oil, the measuring instrument being not able to distinguish satisfactorily between oil drops and herbicidal particles. After the addition of oil the. determination of the particle size is effected by microexamination and the observations were compared to previous observations, in which an electronical measuring of the particle size had been effected beforehand. Storage: The Cipac metod 46.1.3 (Emulsifiable Concentrates (Cipac Handbook I, p. 952) is used for the storing test. α o The storage temperature was at 54 C ± 2 C. Two sets of measuirngs have been carried out. The first set has been evaluated after a fortnight as the method prescribes. The second set has been evaluated after 28 days corresponding to the double loading. Conclusion: The chemical stability is satis¬ factory for all samples. For all the sample the tendency to crystal growth is very small and decicively lower compared to the observations of Betanal+. (see e.g. experiment 5). The tank mixing testings present by and large fine results. In most cases there has not occured any form of precipitations. In the few cases of precipita¬ tions, these precipitations have consisted in very fine-grained, voluminous particles in which the quan¬ tity of precipitation has been very small (designated small light-dispersable granules) . Said observations could be described as slight imperfections which do not involve practical problems. The products show in relation to comparable, marketed products decisive advantages as regards tank mixing, which for beet herbicides must be held to constitute a very important parameter. Biological effect: The Examples 15a to I5h have been tested biolo¬ gically with Betanal as reference. Two treatment by spraying were practised with an interval of appr. 10 days. There was a dosage of 480 g/1 PMP in each spray¬ ing. For all samples the effect in relation to Betanal were in the interval: satisfactory to extremely satis¬ factory. Table 15 15a 15b 15c Raw material comp . Composition in % Emulsifier type Active component: PMP, techn., 97% 17 16.5 12.7 Oil: Gravex 921 12) Radia 7131 1 ) Radia 7204 1) Oleic acid Emulsifier componen Berol 02 15) Berol 922 17) DDSA 20 > Berol 724 22) Gafac RE 410 23) Sulfosoft 26 > Monoethanol amine Acid stabilizer Salicylic acid Benzoic acid Polymeric stabilize Mowiol 10/74 Methocel A15 LV Water + adjuvant: Water Attagel 40 Xanthane rubber Table 15(1) continued pH adjusted (1:10) with HC1/MEA to Density Viscosity at 22°C Specifications: Active content P Particle size Emulsion stability by 1% +1% Fusilade +1% Nortron +1% Goltix WG +7_% Ava ex BW Table 15(1) (continued) Specifications Example 15b Table 15 ( 2 ) 15d 15e 15f Raw material comp . Composition in % Emulsifier type Active component : PMP , techn. , 97% 17 17 17 Oil : Gravex 921 12 ^ Radia 7131 14 ) Reomol DDS 53 ) Isononanoic acid Oileic acid Radiacid 0198 42) Emulsifier component Berol 02 15 > Berol 922 i7) DDSA 2 ° ) Berol 724 22 > Gafac RE 410 23 > *Hostapur SAS 60 28 > Sulfosoft 26 > *Acrylon A 11 27) Monoethanol amine Acid stabilizer: Salicylic acid Benzoic acid Polymeric stabilizer Mowiol 10/74 Methocel A15 LV Water + adjuvant: Water Attagel Xanthane rubber * Delivered as an aqueous solution but indicated on the basis of the solids content. Table 15(2) continued) pH adjusted (1:10) with HC1/MEA to Density Viscosity (Brookfield) at 22°C Specifications: Start 14 days 28 days Active content Particle size Emulsion stability by 1% +1% Fusilade +1% Nortron +1% Goltix WG +_•% Avadex BW Example 15(2) (continued) Specifications: Example 15e Start 14 days 28 days Table 15(3) _ι__2 15h Raw material comp. Composition in % Emulsifier type Active component: PMP, techn., 97% 17 16.2 Oil: Gravex 921 12 ) 8 Radia 7040 55) 24 Radia 7204 1 ) 10 Ester oil 911014 5 > Oleic acid 1.4 Emulsifier component: Berol 02 15) 1.55 Berol 922 17 ) 0.6 Berol 26 6) 0.15 Berol 09 56) Berol 535 57) Berol 537 58 > Berol 196 59) DDSA 20 ) 0.3 Berol 724 22 > 0.4 Gafac RE 410 23) 0.3 Phospholan PDB3 60 ) Sulfosoft 26 ) 0.2 Monoethanol amine 0.2 0.2 Acid stabilizer: Salicylic acid 0.4 Benzoic acid 0.6 Polymeric stabilizer: Mowiol 10/74 0.1 0.15 Methocel A15 LV 0.15 0.15 Water + adjuvant: Water Propylene glycol Attagel 40 Xanthane rubber Manganchelate solu¬ tion 6% Mn as PH adjusted (1:10) with HC1/MEA to 4.0 3.9 Density 0.99 1.03 PMP i g/1 160 161 Viscosity o Brookfield at 22 C 800 cP 700 cP Specifications: Example 15g Start 14 days 28 days Active content PMP 16.1% 16.0% 16.1% Table 15 3 continued Example 16 This series of experiments is a continuation of Example 15 in which the oil compositions have been varied. The compositions are, however, prepared in another manner as the water content thereof is small. The compositions 16a, 16b and 16c have been prepared by mixing at first all the oil components and optionally acid stabilizers to an oily solution. Then, the emulsifier components have been prepared as a pre- mixture and have been mixed with the oily phase. After¬ wards the PMP was mixed therein. The polymeric stabili¬ zers have been admixed individually as 5% aqueous solu- tions. Finally, Attagel and optionally formic acid have separately been added. The mixture has been ground on a pearl mill through three passes, so that the particle size on an average did not exceed 5μ, which was controlled on eva- luation in microscope. The samples were tested in the same manner as in Example 15. Conclusion: the PMP stability and the tank mix- ing properties are held to be satisfactory. Moreover, the tendency to crystal growth is slight. Biological effect: The Examples 16a, 16b and 16c have been biologically tested with Betanal as reference. Two treatments by spraying were practised with an internal of approximately 10 days. A dosage of 480 g/1 PMP was used for each spraying. For all samples the effect in relation to Betanal in the interval was extremely satisfactory. Table 16 16a 16b 16c Raw material comp. Composition in % Emulsifier type Active component: PMP, techn., 97% 17 17 17 Oil: Gravex 921 12) Radia 7131 14 > Isononanoic acid Oleic acid Radiacid 0198 42) Emulsifier component: Berol 02 15) Berol 922 17) Berol 26 6) Synperonic NX 16) Atlox 1285 19) Emulsogen EL 18) DDSA 20) Berol 724 22 > Gafac RE 410 23) *Hostapur SAS 60 28) Sulfosoft 26 > Morwet EFW 21) *Acrylon A 11 27 > Monoethanol amine Acid stabilizer: Salicylic acid Benzoic acid Polymeric stabilizer: Mowiol 10/74 Methocel A15 LV ^Delivered as an aqueous solution but indicated on the basis of solids content. Table 16 continued Example 17 This series of experiments show two examples of optimized recipes containing both PMP and Etho- fumesate. The compositions 17a and 17b are prepared by preparing at first 50% dispersions of PMP and Etho¬ fumesate, respectively, in water. The aqueous etho¬ fumesate dispersion contained 51.5% of 97% etho- fumesate, 46.8% water, 1% Berol 0.2, 0.5% Berol 724 and 0.2% monoethanol amine. (pH of 5% solution: 7). Grinding was effected on a pearl mill so that the 90% ≤7μ. PMP dispersion was prepared as referenced in Example 15. The PMP dispersion was diluted by mixing with the remaining amount of water. Then the Ethofumesate dispersion was added and agitation was effected. The remaining mixture was carried out according to the pro¬ cedure as described under Example 13. The samples have been tested in the same manner as in Example 15. It is added that Ethofumesate liquefies at rather more than 50°C. Instead of storing at (54 ± 2) C the samples have therefore been stored double as long as prescribed, and at (45 ± 1)°C. Conclusion: The stability of PMP and of Etho¬ fumesate is satisfactory. Likewise, the tank mixing properties are evaluated to be satisfactory. The ten¬ dency to crystal growth is acceptable. Biological testing: The products have been tested biologically by 2 dosages a 1.8 1 per ha corres¬ ponding to a dosage each time of 180 g/ha of PMP as well as of Ethofumesate. Betaron* from Schering con¬ taining 100 g/1 Ethofumesate and 80 g/1 PMP was used as reference, and which was further sprayed two times in a dosage of 2 1 per ha corresponding to a dosage each time of 200 g/1 Ethofumesate and 160 g/1 PMP. Examples 17a and 17b of these experiments showed a better effect than Betaron which contains solvent. Table 17 17a 17b Raw material comp. Composition in % Emulsifier type Active component: Ethofumesate, techn. , 97% PMP, techn., 97% Oil: Gravex 921 i2) Radia 7131 i4) Radia 7204 4i) Isononanoic acid Oleic acid Emulsifier component: Berol 02 I 5) Berol 922 I 7) Emulsogen EL I 8) Berol 192 40) DDSA 2 ° ) Berol 724 22) Gafac RE 410 23) Sulfosoft 26) AeryIon A 11 7 ) Monoethanol amine Acid stabilizer: Salicylic acid Benzoic acid Polymeric stabilizer: Mowiol 10/74 Methocel A15 LV Water + adjuvant: Water Attagel 40 Xanthane rubber Table 17 ( continued ) 17a 17b Summed recipe: Active content, 97% 20.6 20, Oil 34.8 36, Emulsifier comp. 3.9 3, Acid stabilizer 1 1 Polymeric stabilizer 0.3 0, Water + adjuvant 39.4 38, pH adjusted (1:10) Example 18 An example of a recipe is shown which both con¬ tains PMP and Metamitron and which both alone and in tank mixing with Fusilade has good emulsifiability. The composition has been prepared analogously with Example 16. All the oil components have at first been mixed to form a clear oil solution. Then the emulsifier components were prepared as a pre-mixture and mixed with the oily phase. Then PMP and Metamitron were added. The polymeric stabilizers have been agitat¬ ed as an aqueous pre-solution containing both 10% Mowi¬ ol 10/74 and 10% Methocel A15 LV. Subsequently, Attagel was admixed and finally the remaining water amount that was not contained in the emulsifiers and in the solu¬ tion of the polymeric stabilizer. The samples were tested for storage stability (full and double testing period after the Cipac method 46.1.3.), in which the active content, the tendency to crystal growth and the emulsifiability unmixed without and with Fusilade have been tested. Conclusion: The PMP-stability, the Metamitron stability and the emulsifiability are satisfactory. The tendency to crystal growth is slight. The product dif¬ fers as regards the emulsion stability decisively from the examples described in EP-0,142,670-A2 and EP-0,243,872-Al, including both PMP and Metamitron. Moreover, the composition in Example 18 may be mixed in tank with Fusilade. Conclusion: The PMP-stability, the Metamitron stability and the emulsifiability are satisfactory. The tendency to crystal growth is small. As regards the emulsion stability the product differs decisively from the examples described in EP-142,670-A2 and EP-243,872-Al which contain both PMP and Metamitron. Moreover, the composition in Example 18 is mixed in tank with Fusilade. mulsifier type Non- ion. Non- ion . Non- ion. Non- ion. type g type a type a type b type b type e type h * Delivered as an aqueous solution but indicated on the basis of the solids content . Table 18 (continued) 18 pH adjusted (1:10) with HC1/MEA til 3.9 Storing experiments at (54 ± 2°C) Start 14 days 28 days Active content PMP 6.2 Metamitron 21.5 Particle size 5-15μ Stirring with magnet in 1% dilution: Deionized water neat neat neat Tap water neat neat neat Stirring withmagnet in 1% dilution + 1% Fusilade: Deionized water neat neat neat Tap water neat neat neat

Claims: P A T E N T C L A I M S 1. Herbicidal compositions in which the her¬ bicidal component is suspended in fine-grained form in a flowable, oil-containing liquid phase containing at least one component selected from the group of beet herbicides consisting of phenmedipham (methyl-(3-(3-to- lylcarbamoyloxy)phenyl)carba ate) , ethofumesate {(±)-2- ethoxy-2,3-dihydro-3,3-dimethylbenzofuran-5-yl, methane sulfonate) and metamitron (4-amino-4.5-dihydro-3-me- thγl~6-phenyl-l,2.4-triazin-5-one) , so that the total quantity of herbicide constitutes 1 to 50% by weight, and wherein the liquid phase contains one or more emulsified, solubilized, dissolved or admixed oils with an initial boiling point of at least 210°C selected among carbon hydride oils with an aniline point deter¬ mined according to DIN 51775 not exceeding 90°C and ester oils with one or two ester groups per molecule so that the total oil content of the oil components constitutes 4 to 85% by weight, and wherein said her- bicidal compositions optionally contain water and for instance a filler and wherein the liquid phase is cap¬ able of forming an oil-in-water emulsion or -microemul- sion when the composition is mixed with water, said herbicidal compositions being characterized in that they contain one or more emulsifiers in an amount of from 1 to 18% by weight, wherein all given expressions for the contents of the composition in % by weight are calculated on the basis of the weight of the total com¬ position. 2. Herbicidal compositions according to claim 1, characterized in that the total quantity of herbicide amounts to 1 to 45% by weight, calculated on the basis of the weight of the total composition. 3. Herbicidal compositions according to claims 1 to 2, characterized in that the total content of the oil components constitutes 8 to 85% by weight, calcul¬ ated on the basis of the weight of the total composi¬ tion. 4. Herbicidal compositions according to claims 1 to 3, characterized in that the solubility of the oil or oils in water at 20°C is preferably below 1% by weight and that the solubility of phenmedipham in the actual oil(s) is preferably below 3% by weight. 5. Herbicidal compositions according to claim 4, characterized in that the solubility of phenmedipham in the actual oil(s) is below 1% by weight. 6. Herbicidal compositions according to claims 1 to 5, characterized in that they are two- or multicom- ponent compositions containing phenmedipham in com¬ bination with ethofumesate and/or metamitron. 7. Herbicidal compositions according to claims 1 to 6, characterized in that the ester oils with one or two ester groups per molecule have from 8 to 72 carbon atoms, preferably 10 to 60 and in particular 12 to 46 carbon atoms per molecule. 8. Herbicidal compositions according to claims 1 to 7, characterized in that the content of ester oils with one or two ester groups per molecule constitutes at least 4% by weight, calculated on the basis of the weight of the total composition. 9. Herbicidal compositions according to claims 1 to 8, characterized in that the total quantity of herbicide amounts to 4 to 40% by weight, in particular 7 to 35% by weight and especially 10 to 30% by weight, calculated on the basis of the weight of the total com¬ position. 10. Herbicidal compositions according to claims 1 to 8, characterized in that the total oil content constitutes 12 to 77% by weight, in particular 18 to 60% by weight and especially 25 to 64% by weight, calculated on the basis of the weight of the total com¬ position. 11. Herbicidal compositions according to claims 1 to 8, characterized in that the total emulsifier con- tent constitutes 1 to 13% by weight, preferably 1.5 to 13% by weight, in particular 2 to 9% by weight and especially 2.5 to 5% by weight, on the basis of the weight of the total composition. 12. Herbicidal compositions according to claims 1 to 11, characterized in that the carbon hydride oil or oils has/have an aniline point determined according to DIN 51775 which does not exceed 90°C, in particular 0 does not exceed 85 C and especially does not exceed 82.5°C. 13. Herbicidal compositions according to claims l to 12, characterized by containing, besides the car¬ bon hydride oil and/or ester oils as defined in claim 1, from 0.5 to 20% by weight, calculated on the basis of the weight of the total composition, of emulsion controlling oil components selected from the group of aliphatic, unsaturated, straight-chained or branched c 7-16 hydrocarbyl carboxylic acids, aliphatic, saturated and branched C 17 _ 2 5 hydrocarbyl carboxylic acids and aliphatic, saturated and branched 17 _ 2 5 hydrocarbyl carboxylic acids and aliphatic, unsa¬ turated, straight-chained or branched C 7 _ 2 5 hydrocar¬ byl carboxylic acids, said hydrocarbyl carboxylic acids being optionally substituted by one or two hydroxy groups, and aliphatic, saturated or unsaturated, straight-chained or branched C 9 _ 2 5. preferably C 10 _ 2 ι hydrocarbyl alcohols. 14. Herbicidal compositions according to claims 1 to 13, characterized in that the emulsifiers include at least one non-ionic emulsifier and at least one anionic emulsifier. 15. Herbicidal compositions according to claim 14, characterized in that the total amount of anionic emulsifier constitutes from 0.03 to 4.4% by weight, and at the same time an optional content of one or more amine containing emulsifiers does not exceed 2.4% by weight, the percentages being calculated on the basis of the total composition. 16. Herbicidal compositions according to claim 15, characterized in that the anionic emulsifier(s) is/are selected among ethoxylated, propoxylated or co-ethoxylated/propoxylated mono-, di-, tri- or tetra- including in particular C 4 _ 15 -alkyl phenol and analog, unsaturated hydrocarbyl phenol; ethoxylated, propoxylated or co-ethoxylated/propoxyl- ated mono-, di- or tri-styrylphenol (tri-(l-phenyl- ethyl)phenol) , optionally substituted by one, two, three or four C 1 _ 15 -alkyl groups; ethoxylated, pro¬ poxylated or co-ethoxylated/propoxylated C 8 _3 -hydro- carbyl alcohol, preferably C g _22~hydrocarbyl alcohol, which further may optionally be methylated in the ter¬ minal OH-group of the polyalkoxylene group; mono¬ carboxylic acid esters of polyethylene glycol, polypro¬ pylene glycol and co-polymerized polyglycols of ethy¬ lene glycol (ethylene oxide) and propylene glycol (pro- pylene oxide) , in which it applies to all three types of polyglycol that the number of alkoxy-units must be at least 4, and a Cg_ 30 -hydrocarbyl carboxylic acid, preferably a C 1Q _ 2 2"~hydrocarbyl carboxylic acid; dicar¬ boxylic acid esters of polyethylene glycol, polypro- pylene glycol and copolymerized polyglycols of ethylene glycol (ethylene oxide) and propylene glycol (propylene oxide) , in which it applies to all three types of polyglycol that the number of alkoxy-units must be at least 6, and two mutually independent C 8 _ 3Q -hydrocarbyl carboxylic acids, preferably two C 10 _22-hydrocarbyl carboxylic acids and block polymers (copolymerisates) of ethylene glycol) (ethylene oxide) and propylene gly¬ col (propylene oxide) the molecular weight of which is in the interval from 1000 to approximately 20.000 Dalton. 17. Herbicidal compositions according to claims 1 to 16, characterized by containing from 0.04 to 20% by weight, calculated on the basis of the weight of the total composition, of at least one polymer which at 60 C is a solid and which preferably via a dilatation by itself becomes stably dissolvable/dilutable in water at 20°C and which at the same time has a molecular weighr of at least 7000 Dalton, in that neither does the polymer include pdycarboxylates nor copolymers of oxyethylene and oxypropylene with at least 80% by weight of polyoxyethylene and polyoxypropylene or biopolymers, for which the polymerization is effected by an industrially controlled fermentation process. 18. Herbicidal compositions according to claims 1 to 17, characterized in that they are available as a ready-to-use mixture diluted by the user, all the stated percentages being calculated on the basis of weight of the solids content of said mixture, as defined in the specification.

Inventors: NIELSEN ERIK, NIELSEN, ERIK
Applicants: KVK AGRO AS, KVK AGRO A/S
Application year: 1991
Main classification: A01N43
IPC codes: A01N25