Semiconductor device with improved wiring structure

Abstract: A semiconductor device has a device region, and a device separation region formed on a semiconductor substrate doped with impurities. And, the device separation region has a metal wiring formed on the surface of the device region or the back surface of the substrate. An aluminum region extending in the longitudinal direction connected to the metal wiring is formed within the device separation region.

Description: This invention relates to a semiconductor integrated circuit such as memory, photoelectric converting device, signal processing device, etc. to be mounted on various electronic instruments and concerns the metal wiring structure thereof, in particular. It also concerns a method of producing such semiconductor integrated circuit. A metal wiring structure in a highly integrated semiconductor device has been known having an interlayer insulating film 52 comprising silicon oxide, etc. formed on the surface of a semiconductor substrate 51 comprising silicon and a metal wiring layer 53 comprising Al, Al-Si, etc. formed on the interlayer insulating film 52 as shown in Fig. 1. In the semiconductor device equipped with the metal wiring of such structure, the sectional area of wiring has been increased by enlargement of the width dimensions of the respective wirings, thereby ensuring necessary current tolerant capacities for the respective wirings, and therefore the flat area of wiring will be increased and improvement of wiring without making greater the device size is limited. For this reason, for improvement of wiring density, for example, a semiconductor device of a wiring structure having the respective wirings laminated in multiple layers as shown in Fig. 2 has been known. In this semiconductor device, two layers of metal wiring are laminated with an insulating film therebetween. In the following, the outline of the process for preparing the semiconductor device shown in Fig. 2 is described. First, after formation of various necessary functional devices such as bipolar transistor, MOS transistor, MOS diode, etc. on a part of the surface of the semiconductor substrate 1, on the remaining surface of the semiconductor substrate 51 is formed a first interlayer insulating film 52 comprising PSG (Phospho silicate glass), etc. according to the normal pressure CVD method with a thickness of 0.5 to 1.0 µm, and the first interlayer insulating film 52 is applied with annealing. Next, patterning by use of a resist is applied on the first interlayer insulating film 52 as described above to form openings 52a for taking out electrodes of various functional devices. Subsequently, according to the sputtering method, after deposition of a wiring material comprising, for example, Al-Si according to the sputtering method on the surface of the first interlayer insulating film 52 and internally of the openings 52a, the first wiring layer 53 is formed by patterning by use of a resist. Next, on the first wiring layer 53 and the first interlayer insulating film 52 are formed a second interlayer insulating film 54 comprising PSG with a thickness of about 0.5 to 1.0 µm according to the normal pressure CVD method, openings 54a for connecting the first wiring layer and the upper wiring layer as described below to a part of the second interlayer insulating film 54 corresponding to the upper portion of the first wiring layer 53 are formed. Next, on the second insulating film 54 and internally of the openings 54a, a wiring comprising, for example, Al-Si is deposited, followed by formation of the second wiring layer 55 for connecting the second wiring layer 55 for connecting the first wiring layer 52 through the portion of the openings 54a by patterning. Next, on the second interlayer insulating film 54 and the second wiring layer 55, a passivation film 56 can be formed with a thickness of 0.5 to 1.0 µm according to the plasma CVD method to prepare a semiconductor device with a metal double layer wiring structure shown in Fig. 2. In the semiconductor device having a multi-layer wiring structure of such constitution, a wiring with wiring density by far higher than the semiconductor device with the monolayer wiring structure shown Fig. 1 can be realized. However, in the semiconductor device having a multi-layer wiring structure as described above, since an interlayer insulating film is provided between the wiring at the lower part and the wiring at the upper part, the surface stepped difference due to the wiring portion will become greater as the number of the lamination is more, whereby the degree of freedom in design in the wiring structure is regulated because of movement of the position (migration) of the wiring portion relative to the semiconductor substrate at the wiring portion or the shape of the contact hole necessary for connection between the respective insulating layers. Thus, also in this case, improvement of wiring density is limited and it has been difficult to enhance wiring density more than a certain level. Further, in a semiconductor device with a multi-layer structure, surface unevenness increases as the number of layers increases, and therefore slippage in alignment becomes greater during mask registration in patterning when laminating further wiring, whereby wiring could not be formed with good precision at the predetermined position relative to the semiconductor substrate, thus involving the problem with respect to reliability of wiring. US 4044452 discloses the use of embedded metal to provide terminal electrode contacts to the electrode parts of a functional device. The terminal electrodes are embedded in a groove, the side walls of which are covered by an insulation layer. At the bottom of each groove the terminal electrodes come in direct contact with a diffusion region. The electrodes provide a connection between conventional wiring and a single device in the substrate. GB 2137019 discloses a semiconductor device having a lower collector series resistance which includes a collector, a base, and an emitter and also includes a layer made of a highly doped polycrystalline silicon, metal alloy or organic conductive material, that differs from that of the semiconductor layer. This document also discloses the use of embedded metal to provide terminal electrode contacts to electrode parts of a functional device, in this case the collector of a vertical structure bipolar transistor. It has been known to employ embedded conductors as a means of connecting the contact electrodes of functional devices. Particular reference is made to Patent Abstracts of Japan, vol.7, No.136 (E-181) and JP-A-58051537 and to Patent Abstracts of Japan, vol. 6, No. 160 (E-126) and JP-A-57079647. Those features of the present semiconductor integrated circuit which are known from each of these two references, are set out in the preamble of claim 1 attached as follows: a semiconductor substrate; a plurality of functional devices defined in the semiconductor substrate, the functional devices having respective contact electrodes; and wiring, including a wiring conductor interconnecting respective ones of the contact electrodes of at least two of the functional devices, which wiring conductor is embedded in the surface of the substrate and insulated therefrom. The present invention is provided as an improvement. In particular, it is characterised in that: the wiring conductor is of aluminium metal or of an aluminium metallic compound selected from: Al-Si,Al-Ti, Al-Cu, Al-Si-Ti or Al-Si-Cu; the wiring conductor is embedded in a groove the sidewalls of which are covered with an insulating layer; and the wiring conductor is in direct contact with a diffusion region, doped to opposite conductivity type to that of the substrate, at the bottom of the groove. Insofar as the wiring conductor is of metal and insulated by insulator material, it is acknowledged that it is known to provide tungsten metal in a groove the sidewall and bottom of which are coated with silicon oxide insulator material. This is disclosed in Patent Abstracts of Japan, vol.13, No. 201 (E-757) and JP-A-1022045. The embedded wiring conductor is preferably of an aspect ratio of depth to width greater than 1. The wiring conductor thus may be dimensioned so as to ensure tolerable high current without any necessary increase in the surface space occupied by the wiring conductor. This is thus compatible with high integration density. In the accompanying drawings: Figs. 1 and 2 are constitutional views for illustration of a semiconductor device of the prior art. Fig. 3 is a constitutional view of the pertinent portion of an illustrative example of a semiconductor device not forming a part of the present invention. Fig. 4 is a constitutional view of the pertinent portion of a further illustrative example of a semiconductor device not forming a part of the invention. Fig. 5 is a constitutional view of the pertinent portion of the semiconductor portion of another illustrative example of a semiconductor device not forming a part of the invention. Fig. 6A is a constitutional view of a further illustrative semiconductor device not forming a part of the invention. Fig. 6B is a circuit diagram of the same device. Figs. 7A to 7D are schematic views for the illustration of the film forming method suitable for the formation of the wiring layer in the semiconductor device according to the present invention. Fig. 8 is a schematic plan constitutional view of the device shown in Figs. 16 and 17. Fig. 9 is a schematic plan constitutional view with the movement order shown by arrow heads in Fig. 8. Figs. 10A and 10B are schematic views for illustration of the logic circuit according to the present invention. Fig. 11 is an upper view showing the logic circuit according to the present invention. Fig. 12 is a schematic sectional view showing the wiring structure intended to apply a positive potential. Fig. 13 is a schematic sectional view showing the wiring structure intended to apply a negative potential. Fig. 14 is a schematic sectional view showing an example of a multi-layer wiring structure that can be provided in a semiconductor integrated circuit of the present invention. Figs. 15A to 15C are schematic views for illustration of the preparation method of the wiring structure in Fig. 14. Figs. 16, 17 are schematic view showing an example of the film forming device to be used for practicing the film forming method suitable for formation of the wiring layer in the semiconductor device according to the present invention. Fig. 3 is a drawing of an illustrative example of a semiconductor device in which the symbol 1 is the device separation wiring formed in the longitudinal direction within the device separation region 5 as described below according to the Al-CVD method as described below, 2 the first device region, 3 the second device region, 4 the Si substrate doped with an impurity, 5 the device separation region doped with an impurity of the same type as in the substrate Next, the process ror preparing a semiconductor device having the device separation structure with the above constitution is described. i) On a mono-electroconductive semiconductor substrate, for example, a P-type Si substrate 4, an n-type epi-layer 2, 3 is formed by epitaxial growth as the layer having the impurity of the reverse conduction type to the substrate 4. ii) Next, after formation of the oxidized film to 0.5 to 1.0 µm on a surface of above-mentioned epi-layer 2, 3 by thermal oxidation, impurities (e.g. P type) with the reverse conduction type to the epi-layer 2, 3 are introduced to form the device separation region 5 by patterning by ion injection with the above-mentioned oxidized film as a mask. The diffusion layer is made so as to reach the underlying semiconductor substrate 4. iii) Next, after the oxidized films on the surfaces of the epi-layers are removed, again oxidized films with a thickness of 10 to 100 nm (100 to 1000 Å) are formed. Then, the above-mentioned device separation region 5 is internally opened by resist patterning, and the oxidized film and the epi-layer are etched in two steps with the resist as the mask to form grooves. In this case, the depth of the groove is made to reach the semiconductor substrate 4. After completion of etching, the resist is removed. iv) Next, by use of DMAH and hydrogen as the Al-CVD method , Al is buried in the grooves provided within the epi-layer 2, 3. Here, the material to be buried within the grooves is not limited to Al, but Al-Si, Al-Ti may be also used as the metal material as described above. Fig. 4 shows another illustrative example of a semiconductor device, wherein the symbol 1 is the device separation wiring of the buried type with a large aspect ratio, 2 the first device region, 3 the second device region, 4 the Si substrate doped with an impurity, 5 the device separation Si doped with the impurity of the same type as in 4, and 6 the back metal wiring. By fixing of the potential in the device separation region 5 with the device separation wiring 1 and the back metal wiring 6, no wiring from the chip upper surface will be required to result in reduction of chip area. Next, the process for preparing the semiconductor device having the device separation structure having the above-mentioned structure is described. The steps i) - ii) are practiced in the same manner as in Example 1, and hence description thereof is omitted. iii) Next, after formation of an oxidized film on the back surface of the semiconductor substrate 4 by thermal oxidation, patterning is effected so as to form openings only on the back surface of the semiconductor substrate 4 immediately below the above device separation region 5. Then, continuously to the oxidized film from the back surface of the semiconductor substrate 4, the semiconductor substrate 4 is etched to provide grooves on the back surface of the semiconductor substrate 4. The depth of the grooves is made to extend through the semiconductor substrate 4 until reaching the above-mentioned diffusion layer 5 for device separation. iv) Next, as the Al-CVD method, Al is deposited selectively at the groove portions similarly as in Example 1 to bury Al within the grooves. Then, according to the sputtering method of the non-selective mode, an Al film is formed on the whole back surface of the semiconductor substrate 4. Next, the semiconductor functional devices formed in the device region 2 or 3 is described by referring to Fig. 5 and Fig. 6. The semiconductor functional device is characterized by forming a device wiring 12 with a large aspect ratio for fixing the back gate of the MOS type transistor (P well region 10 of nMOS, and n-epi or n-well region 11 of pMOS) at any desired potential in the P-well region 10 the n-epi or n-well region in the longitudinal direction according to the Al-CVD method as described above. Fig. 6A is a sectional constitutional view of another semiconductor functional device, and Fig. 6B is the circuit diagram of the same device. The device is characterized by forming the device separation wiring 12 for reducing the resistance in the back gate when the P-well 10 which is the back gate of the MOS type transistor and the n-epi or n-well 11 are at the same potential as the source region (or drain region) in the source (or drain) region 13 according to the Al-CVD method as described above. Embodiments of the present invention have the metal wiring for connecting a plurality of devices formed not on the insulating film on the semiconductor substrate but within the groove formed on the semiconductor substrate. Fig. 10A is a circuit diagram showing a part of the logic circuit of the CMOS constitution, and Fig. 10B a schematic view showing the lay-out thereof. Thus, the power source line Vcc and the earthline GND are commonly arranged for the respective cells. In these lines, reduction of the impedance, avoidance of erroneous actuation and further avoidance of lowering in reliability by migration, etc. are particularly demanded. Hence, by use of buried wirings in these lines, in addition to functional aspect, improvements in physical aspect such as reduction of occupied area, reduction of stepped difference, etc. can be effected. Fig. 11 is a schematic view for illustrating in more detail Fig. 10B, and 63 is the same invertor as the CMOS in Fig. 6. Here, the line Vcc and the line GND are both buried wirings connected to the source region and the well region of the two MOSFET's, forming the common line for the both adjacent cells 61, 62. a is the polycrystalline gate electrode which becomes the input of the invertor, "out" is the drain wiring which becomes the output of the invertor. In this example, as different from the prior art, the power source lines Vcc and the earthline GND are wirings of the lower layers than the gate electrode a . In the semiconductor device of the present embodiment, since the metal wiring layer is provided within the substrate, a predetermined current tolerant capacity can be ensured by making larger the depth dimension without increasing the plan area of the metal wiring layer, and also the unevenness of the device surface can be inhibited minimum, whereby the relative movement of the wiring layer relative to the substrate can be removed to improve the precision of the formation position of the wiring layer. Fig. 12 and Fig. 13 are both Figures representing the characteristic portions of the wiring structures in the semiconductor devices of the present invention. Here, Fig. 12 shows the wiring structure constituted for the purpose of applying a positive voltage as the power source line, and Fig. 13 the wiring structure constituted for the purpose of applying a negative voltage as the earth line. These wiring structures are the embodiments of the present invention in that they are constituted on the basis of the technical thought of the present invention except that the kinds of the materials for forming the respective portions are different concerning the application method of voltage. Therefore, the constitution of the former and the preparation method thereof are described before description of the constitution and the preparation method thereof in difference from the former. In Fig. 12, the symbol 710 is a P - type semiconductor substrate comprising, for example, silicon, etc. On the surface of the substrate 710 is formed a groove 711 by conventional means such as etching, etc., and the inner surface excluding the bottom surface of the groove 711 and the surface of the substrate 710 is formed an insulation layer 712 comprising oxidized silicon, etc. formed by the thermal oxidation method or the CVD method, etc. continuously. From the bottom surface of the groove 711 to internally of the substrate 710 as described above, if necessary, an N + type diffusion layer 713 is provided, which is formed by thermal diffusion as the semiconductor region doped with an impurity of the opposite type to the conduction type of the semiconductor such as silicon forming the substrate 710. Internally of such groove 711, a metal wiring layer 714 comprising a metal such as Al, etc. is provided. The metal wiring layer 714 is formed by use of the Al-CVD method as described below. The Al-CVD method is a film forming method with good reproducibility which can form a metal film of Al, etc. selectively on the substrate 710, namely the bottom of the groove 711 in this case without formation on the insulation layer 712 comprising silicon oxide. The wiring film thus formed is used for connection between the predetermined contact electrodes mutually between two functional devices or, if necessary, 3 or more functional devices, to constitute an electrical circuit. For example, it may be used for connection between two source-drains of MOSFET or collectors of a bipolar transistor, or between MOSFET or a bipolar transistor and a diffusion resistance, between MOSFET or a bipolar transistor and a capacity device, etc. Next, an example for preparing the wiring structure with such constitution is described. First, as shown in Fig. 12, a P - type silicon substrate 710 is prepared as the semiconductor substrate. Subsequently, on the surface of the substrate 710, after application of a patterning by use of a resist, a groove 711 for formation of a wiring layer is formed by application of etching. Then, an insulation layer 712 with a film thickness of 0.5 to 1.0 µm is formed according to the thermal oxidation method or the CVD method on the surface of the substrate 710 and the inner surface of the groove 711. Next, after application of a patterning by use of a resist on the whole surface of the substrate 711 excluding the bottom of the groove 711, the oxidized film layer formed on the bottom of the groove 711 is removed by anisotropic etching such as RIE (reactive ion etching) to have the silicon portion of the substrate 710 exposed. Next, at the silicon exposed portion of the bottom of the groove 711, an impurity of the type opposite to the conduction type of the material for forming the substrate 710 is doped according to the ion injection method or the thermal diffusion method, followed by diffusion to form an N + type diffusion layer 713. Subsequently, on the N + type diffusion layer 713, according to the Al-CVD method, a metal wiring layer 714 comprising Al, etc. is formed. The metal wiring layer 714 should be desirably formed so that its upper surface may be coplanar with the upper surface of the insulation layer 712 formed on the surface of the substrate 710 around the groove 711 in accomplishing surface flattening of the semiconductor device. In such metal wiring layer 714, electrical separation is effected from the P - type silicon substrate 710 through the insulation layer 712 as the insulation film formed on the inner surface of the groove 711 and the N + type diffusion layer 713 as the P-N separation layer formed on the bottom of the groove 711. According to the selective Al-CVD method as described above, the Al film is deposited selectively on the N + type diffusion layer 713 comprising silicon as described above, but not on the insulation layer 712 comprising silicon oxide. Therefore, by use of the selective Al-CVD method, there is the advantage that no patterning with resist, etc. as required in the case of a conventional film forming method such as sputtering, etc. need be applied. Also, the depth dimension of the groove 711 as described above is relatively longer than the width dimension, and even in the case when the width dimension itself is short, there is the advantage that an Al film of good quality can be formed from the bottom of the groove 711. Therefore, it is sufficiently applicable to a fine structure with an aspect ratio of 1.0 or more as a matter of course, even 1.5 or more, further 2.0 or more. Further, because an Al film of good quality can be also formed internally of a deep groove 711 easily, the current tolerance of the metal wiring layer 714 can be easily increased by enlarging the depth dimension without enlarging the width dimension of the metal wiring layer 714. Next, the wiring structure shown in Fig. 13 is described. In Fig. 13, the same portions as the constitution in Fig. 12 are affixed with the same symbols for brevity of the description. In Fig. 13, the symbol 720 is an N - type semiconductor substrate comprising, for example, silicon, as the substrate. On the surface of the substrate 720 is formed a groove 711 by conventional means such as etching, etc. and on the inner surface excluding the bottom internally of the groove and the surface of the substrate 720 is formed continuously an insulation film 712 comprising silicon oxide, etc. according to the thermal oxidation method or the CVD method. Internally of the substrate of the substrate 720 from the bottom of the groove 711 as described above, an impurity of the conduction type opposite to that of the semiconductor such as silicon, etc. for forming the substrate 720 to provide a P + type diffusion layer 21 as the semiconductor region formed by thermal diffusion. Internally of such groove 711, a metal wiring layer 714 comprising a metal such as Al, etc. is provided. In such metal wiring layer 714, electrical separation is effected from the N - type silicon substrate 720 through the insulation layer 712 as the insulation film formed on the inner surface of the groove 711 and the P-N separation layer formed on the bottom of the groove 711. Therefore, substantially no leak current from the metal wiring layer 714 to the substrate will occur. The wiring structure of the present invention with such constitution can be utilized for all functional devices, namely field effect transistors, bipolar transistors, diffusion resistances, etc. Fig. 14 is an example of the wiring structure of the present invention, which is a schematic sectional view showing a wiring structure of two metal layers. In Fig. 14, the symbol 730 is an N - type semiconductor substrate comprising, for example, silicon. On the surface of the substrate 730 is formed a groove 731 according to conventional means such as etching, etc., and on the inner surface excluding the bottom internally of the groove 731 and on the surface of the substrate 730 are formed continuously an oxidized film layer 732 comprising silicon oxide, etc. according to the thermal oxidation method or the CVD method. From the bottom of the groove 731 as described above to internally of the substrate 730 is doped an impurity of the conduction type opposite to that of the semiconductor such as silicon, etc. forming the substrate 730 to provide a P + diffusion layer 733 formed by thermal diffusion. Internally of such groove 731, a first wiring layer 734 comprising, for example, Al, etc. is formed according to the selective Al-CVD method as described below. The first metal wiring layer 734 has its upper surface coplanar with the surface of the substrate 730. On a part of the oxidized film layer 732 as described above, openings 735 for taking out the electrode of the semiconductor device reaching the surface of the substrate 730 are formed. On the surface of the oxidized film layer 732 together with the inner portion of the openings 735 and the inner portion of the groove 731 at upper portion of the first metal wiring layer 734, a second metal wiring layer 736 comprising a metal such as Al, etc. is formed. A passivation film 737 comprising, for example, silicon nitride, etc. is formed on the second metal wiring layer 736 and the oxidized film 732. Referring next to Fig. 15A to Fig. 15C, a method for preparing a semiconductor device having the wiring structure with the constitution shown in Fig. 14. First, as shown in Fig. 15A, an N - type silicon substrate 730 is prepared. Next, after application of a patterning by use of a resist on the surface of the substrate 730, a groove 731 for formation of a first metal wiring layer is formed. Next, an oxidized film layer 732 with a film thickness of about 0.5 to 1.0 µm is formed on the surface of the substrate 730 the inner surface of the groove 731 according to the thermal oxidation method. Next, after application of a patterning by use of a resist on the whole surface of the substrate 730 excluding the bottom of the groove 731, the oxidized film layer formed on the groove 731 is removed by anisotropic etching of RIE (reactive ion etching) to have the silicon portion of the substrate 730 exposed. Next, the silicon exposed portion at the bottom of the groove 731 is doped with B as the impurity of the conduction type opposite to that of the material for forming the substrate 730 according to the ion injection method, followed by diffusion to form a P + diffusion layer 733. Next, on the P + type diffusion layer 733 is formed a first metal wiring layer 734 comprising Al, etc. according to the selective Al-CVD method as described above. The first metal wiring layer 734 is formed so that its upper surface became coplanar with the upper surface of the substrate 730 around the groove 731. The first metal wiring layer 734 is separated electrically from the N - type silicon substrate 730 through the oxidized film layer 732 as the insulation film formed on the inner surface of the groove 731 and the P + type diffusion layer 733 as the P-N separation layer formed on the bottom of the groove 731. And, it is confirmed that there is substantially no leak of current from the first wiring layer 734 to the substrate 730. Next, after application of a patterning by use of a resist on the surface of the oxidized film layer 732, openings 735 for taking out the electrode of the semiconductor devices reaching the surface of the substrate 730 are formed in a part of the oxidized film layer 732 (Fig. 15B). Next, internally of the openings 735 and internally of the groove 731 at the upper portion of the first metal wiring layer 734 is formed by depositing a second metal wiring lower layer 736a comprising Al utilizing DMAH and hydrogen as the Al-CVD method at a substrate surface temperature of 270 °C. The second metal wiring lower layer 736a is formed so that its surface may be coplanar with the upper surface of the oxidized film layer 732. Next, on the respective upper surfaces of the second metal wiring lower layer 736a and at the predetermined positions on the surface of the oxidized film layer 732 are formed the upper second metal wiring layer 736b comprising Al according to the sputtering method (see Fig. 15C). Further, on the second metal wiring layer 736 and the oxidized film layer 732, a passivation film 737 comprising silicon nitride with a film thickness of about 0.5 to 1.0 µm is formed according to the plasma CVD method to obtain a semiconductor device equipped with the metal double layer wiring structure as shown in Fig. 14. Also in the semiconductor device with such constitution, the first metal wiring layer 734 provided internally of the N - type silicon substrate 730 is separated from the N - type silicon substrate 730 through the oxidized film layer 732 as the insulation film on the inner surface of the groove 731 and the P + type diffusion layer 733 as the P-N separation layer at the bottom of the groove 731, and there will be substantially no leak current from the first metal wiring layer 734 to the substrate 730. In the first metal wiring layer 734, the desired current tolerance can be ensured by enlarging the depth dimension without enlarging its flat area. Also, since the unevenness of the surface of the semiconductor device can be inhibited minimum, there is no relative movement of the first metal wiring layer 734 to the substrate 730 to effect improvement of the precision of the formation position of the first metal wiring layer 734, and also the number of the multiple layers of wiring can be increased within the range of a limited thickness of the device. Further, since no interlayer insulation film is required between the first metal wiring layer and the second metal wiring layer, the surface stepped difference can be reduced in the case of providing wiring layers of the third metal wiring layer et seq, whereby reliability of the wiring layers of the third layer et seq can be improved. As described above, according to the present invention, a wiring structure capable of ensuring necessary current tolerance can even with a small wiring flat area and also capable of being formed at a high positional precision can be obtained. The film forming method suitable for the present invention is to form a deposited film by the surface reaction on an electron-donative substrate by use of a gas of an alkylaluminum hydride and hydrogen gas (hereinafter called the Al-CVD method). Particularly, by use of monomethylaluminum hydride (MMAH) as the starting gas or dimethylaluminum hydride (DMAH) as the starting gas, and H 2 gas as the reaction gas, and heating the substrate surface under the mixture of these gases, an Al film of good quality can be deposited. Here, during the selective deposition of Al, it is preferable to maintain the surface temperature at the decomposition temperature of the alkylaluminum hydride or higher and less than 450 °C, more preferably 260 °C to 440 °C. As the method for heating the substrate to the above-mentioned temperature range, there are direct heating and indirect heating. Particularly, by maintaining the substrate at the above-mentioned temperature by direct heating, an Al film of good quality can be formed at high deposition speed. For example, when the substrate surface temperature during Al film formation is made 260 °C to 440 °C which is more preferable temperature range, a film of good quality can be obtained at higher deposition speed of 30 nm to 500 nm/min (300 Å to 5000 Å/min) which is higher than in the case of resistance heating. As such direct heating method (substrate itself is heated by direct transmission of the energy from the heating means to the substrate), for example, lamp heating by means of halogen lamp, xenon lamp, etc. may be included. As the method for indirect heating, there is resistance heating, by which heating can be performed by use of a heat-generating body, etc. provided at the substrate supporting member for supporting the substrate to form deposited film arranged in the space for formation of the deposited film. By applying the CVD method to the substrate having the electron-donative surface portion and the non-electron donative surface portion co-present thereon, a single crystal of Al is formed under good selectivity only on the electron-donative substrate surface portion. The Al thus formed will have all of excellent characteristics desirable for the electrode/wiring material. That is, reduction of generation probability of hillock, reduction of generation probability of alloy spike will be accomplished. This may be considered to be due to the fact that substantially no or extremely small formation of alloy spike, etc. on account of the eutectic reaction with the subbing silicon, etc. is seen, because Al of good quality can be formed on the surface comprising a semiconductor or an electro-conductive member as the electron-donative surface, and also the Al is excellent in crystallinity. And, when employed for the electrode of a semiconductor device, an effect surpassing the concept of the Al electrode which has been contemplated in the prior art, and could not be even expected in the prior art can be obtained. Having described above about the fact that the Al deposited on an electron-donative surface, for example, within the opening with the semiconductor substrate surface exposed becomes to have a single crystalline structure, according to the Al-CVD method, a metal film composed mainly of Al as described below can be also selectively deposited, and its film quality also exhibits excellent characteristics. For example, in addition to a gas of an alkylaluminum hydride and hydrogen, a gas containing Si atoms such as SiH 4 , Si 2 H 6 , Si 3 H 8 , Si(CH 3 ) 4 , SiCl 4 , SiH 2 Cl 2 , SiHCl 3 , or the like. a gas containing Ti atoms such as TiCl 4 , TiBr 4 , Ti(CH 3 ) 4 , etc., a gas containing Cu atoms such as copper bisacetylacetonate Cu(C 5 H 7 O 2 ), copper bisdipivaloylmethanite Cu(C 11 H 19 O 2 ) 2 , copper bishexafluoroacetylacetonate Cu(C 5 HF 6 O 2 ) 2 , etc. may be introduced in a suitable combination to form a gas mixture atmosphere, thereby forming an electrode by selective deposition of an electroconductive material such as Al-Si, Al-Ti, Al-Cu, Al-Si-Ti, Al-Si-Cu, etc. The Al-CVD method as described above is a film forming method excellent in selectivity, and also the surface characteristic of the film formed has good surface characteristic. Hence, by application of a non-selective film forming method to the next deposition step, Al or a metal film composed mainly of Al can be also formed on the Al film selectively deposited as described above and SiO 2 , etc. as the insulating film, whereby a suitable metal film having high useability for general purpose as the wiring of semiconductor device can be obtained. Specific examples of such metal film include the following. There may be included combinations of Al, Al-Si, Al-Ti, Al-Cu, Al-Si-Ti, Al-Si-Cu, etc. deposited selectively with Al, Al-Si, Al-Ti, Al-Cu, Al-Si-Ti, Al-Si-Cu, etc. As the film forming method for non-selective deposition, there are other CVD methods than the Al-CVD method as described above, the sputtering method, etc. (Film Forming Apparatus) Next, a suitable film forming apparatus for forming the electrode according to the present invention is described. Figs. 16, 17, and 8 show schematically a sequential metal film forming apparatus suitable for applying the film forming method as described above. The sequential metal film forming apparatus, as shown in Fig. 16, is constituted of loadlock chamber 311 connected mutually communicated under shielding from outer air through the gate valves 310a to 310f, a CVD reaction chamber 312 as the first film forming chamber, an Rf etcing chamber 313, a sputtering chamber 314 as the second film forming chamber and a loadlock chamber 315, and the respective chambers are constituted reducible in pressure by evacuation with the evacuation systems 316a to 316e. Here, the above loadlock chamber 311 is a chamber for replacing the substrate atmosphere before deposition treatment with H 2 atmosphere after evacuation in order to improve the throughput characteristic. The next CVD reaction chamber 312 is a chamber for selective deposition on the substrate according to the Al-CVD method as described above under normal pressure or reduced pressure, in which a substrate holder 318 having a heat-generating member 317 which can heat the substrate to be formed to a range of 200 °C to 450 °C is provided internally, and starting gases such as alkylaluminum hydride bubbled and gasified in the bubbler 319-1 are introduced into the chamber through the starting gas introducing line 319 for CVD, and also hydrogen gas as the reactive gas is introduced through the gasline 319'. The next Rf etching chamber 313 is a chamber for carrying out cleaning of the substrate surface after selective deposition (etching) under Ar atmosphere, and internally thereof are provided at least a substrate holder 320 capable of heating the substrate to a range of 100 °C to 250 °C and an electrode line for Rf etching 321, and also an Ar gas feeding line 322 is connected. The next sputtering chamber 314 is a chamber for depositing non-selectively a metal film by sputtering under Ar atmosphere on the substrate surface, and internally thereof are provided a substrate holder 323 heated within a range of 200 °C to 250 °C and a target electrode 324 for mounting a sputter target material 324a, and also an Ar gas feeding line 325 is connected. The final loadlock chamber 315 is a control chamber before taking out the substrate after completion of the metal film deposition into the outer air, and constituted so that the atmosphere may be replaced with N 2 . Fig. 17 shows another constitutional example of a sequential metal film forming apparatus suitable for applying the film forming method as described above, and the same portions as described above in Fig. 16 are made the same symbols. The difference of the apparatus in Fig. 17 from that in Fig. 16 resides in that a halogen lamp 330 is provided as the direct heating means and the substrate surface can be directly heated, and for that purpose, the substrate holder 312 is provided with a nail 331 for holding the substrate under suspended state. By heating directly the substrate surface with such constitution, the deposition speed can be further improved as described above. The sequential metal film forming apparatus with the above constitution, as shown in Fig. 8, is substantially equivalent to one with the structure having the above loadlock chamber 311, the CVD reaction chamber 312, the Rf etching chamber 313, the sputtering chamber 314, the loadlock chamber 315 connected mutually to one another with the conveying chamber 326 as the relay chamber. With this constitution, the loadlock chamber 311 functions also as the loadlock chamber 315. In the above conveying chamber 326, as shown in the Figure, an arm 327 as the conveying means reversibly rotatable in the AA direction and stretchable in the BB direction is provided, and with the arm 327, as shown in the arrowhead in Fig. 9, the substrate can be moved following the steps successively from the loadlock chamber 311 to the CVD chamber 312, the Rf etching chamber 313, the sputtering chamber 314, the loadlock chamber 315 without exposure to outer air. (Film Forming Procedure) The film forming procedure for forming the electrode and wiring according to the present invention is described. Fig. 7 is a schematic perspective view for illustration of the film forming procedure for formation of the electrode and wiring according to the present invention. First, the outline is described. A semiconductor substrate having openings formed on an insulating film is prepared, which substrate is arranged in a film forming chamber, and its surface is maintained at, for example, 260 °C to 450 °C to deposit selectively Al at the portion where the semiconductor is exposed according to the hot CVD method in a mixed atmosphere of DMAH as the alkylaluminum hydride and hydrogen gas. Of course, as described above, a metal film composed mainly of Al such as Al-Si, etc. may be also deposited selectively by introducing a gas containing Si atoms, etc. Next, on the Al selectively deposited by the sputtering method and the insulating film, Al or a metal film composed mainly of Al is non-selectively formed. Then, by patterning of the metal film non-selectively deposited to a desired wiring shape, electrodes and wirings can be formed. Referring next to Figs. 15, 16, 17, 7, 8 and 9, description is made in more detail. First, a substrate is prepared. As the substrate, for example, a single crystalline Si wafer having an insulating film provided with openings with respective apertures provided thereon is prepared. Fig. 7A is a schematic view showing a part of the substrate. Here, 401 is a single crystalline silicon substrate as a conductive substrate, 402 a thermally oxidized silicon film as the insulating film (layer). 403 and 404 are openings (exposed portions), having apertures different from each other. 410 is the groove bottom with Si exposed. The procedure for forming Al film which becomes the electrode as the first wiring layer on the substrate is as follows with Fig. 7. First, the substrate as described above is arranged in the loadlock chamber 311. Hydrogen is introduced into the loadlock chamber 311 to make it under hydrogen atmosphere. And, the reaction chamber 312 is internally evacuated to approximately 1.33 x 10 -6 Pa (1 x 10 -8 Torr) by the evacuation system 316b. However, Al film can be formed even if the vacuum degree within the reaction chamber 312 may be worse than 1.33 x 10 -6 Pa (1 x 10 -8 Torr.) And, the gas of DMAH bubbled from the gas line 319 is fed. For the carrier gas for the DMAH line, H 2 is employed. The second gas line 319' is for H 2 as the reaction gas, and by flowing H 2 through the second gas line 319' and controlling the opening degree of the slow leak valve not shown to adjust the pressure within the reaction chamber 312 to a predetermined value. A typical pressure in this case is preferably about 1.995 x 10 2 Pa (1.5 Torr). Through the DMAH line, DMAH is introduced into the reaction tube. The total pressure is made about 1.995 x 10 2 Pa (1.5 Torr), and the DMAH pressure 6.666 x 10 -1 Pa (5.0 x 10 -3 Torr). Then, current is passed to the halogen lamp 330 to heat directly the wafer. Thus, Al is selectively deposited. After elapse of a predetermined deposition time, feeding of DMAH is once stopped. The predetermined deposition time of the Al film deposited in this process is the time until the thickness of the Al film on the Si (single crystalline silicon substrate 1) becomes equal to the film thickness of the SiO 2 (thermally oxidized silicon film 2), and can be determined previously by experimentation. The temperature of the substrate surface by direct heating at this time is made about 270 °C. According to the steps up to this stage, the Al film 405 is selectively deposited within the openings and the grooves as shown in Fig. 7B. All of the steps as described above are referred to as the first film forming step for formation of electrode within contact hole. After the above first film forming step, the CVD reaction chamber 312 is evacuated until reaching a vacuum degree of 6.666 x 10 -1 Pa (5 x 10 -3 Torr) or lower by the evacuation system 316b. At the same time, the Rf etching chamber 313 is evacuated to 6.666 x 10 -4 Pa (5 x 10 -6 Torr) or lower. After confirmation that the both chambers have reached the above vacuum degree, the gate valve 310c is opened, the substrate moved from the CVD reaction chamber 312 to the Rf etching chamber 313 by the conveying means, and the gate valve 310c closed. The substrate is conveyed to the Rf etching chamber 313, and the Rf etching chamber 313 is evacuated by means of the evacuation system 316c until reaching a vacuum degree of 10 -6 Torr or lower. Then, argon is fed through the argon feeding line 322 for Rf etching, and the Rf etching chamber 131 maintained under an argon atmosphere of 1.333 x 10 1 Pa to 1.333 x 10 -1 Pa (10 -1 to 10 -3 Torr). The substrate holder 320 of Rf etching is maintained at about 200 °C, Rf power of 100 W supplied to the electrode for Rf etching 321 for about 60 seconds, and discharging of argon is caused to occur within the Rf etching chamber 313 for about 60 seconds. By doing so, the surface of the substrate can be etched with argon ions to remove unnecessary surface layer of the CVD deposited film. The etching depth in this case is made about 10 nm (100 Å) in terms of the oxide. Here, surface etching of the CVD deposited film is effected in the Rf etching chamber, but since the surface layer of the CVD film of the substrate conveyed through vacuum contains no oxygen, etc., no Rf etching may be effected. In that case, the Rf etching chamber 313 function as the temperature changing chamber for effecting temperature change within a short time, when the temperatures in the CVD reaction chamber 12 and the sputtering chamber 314 are greatly different. In the Rf etching chamber 313, after completion of Rf etching, flowing of argon is stopped, and the argon within the Rf etching chamber 313 is evacuated. After the Rf etching chamber 313 is evacuated to 6.666 x 10 -4 Pa (5 x 10 -6 Torr) and the sputtering chamber 314 to 6.666 x 10 -4 (5 x 10 -6 Torr) or lower, the gate valve 310d is opened. Then, the substrate is moved from the Rf etching chamber 313 to the sputtering chamber 314 by means of a conveying means, followed by closing of the gate valve 310d. After the substrate is conveyed to the sputtering chamber 314, the sputtering chamber 314 is made under an argon atmosphere of 1.333 x 10 1 Pa to 1.333 x 10 -1 Pa (10 -1 to 10 -3 Torr) similarly as in the Rf etching chamber 313, and the temperature of the substrate holder 323 for mounting the substrate set to about 200 to 250 °C. And discharging of argon is effected at a DC power of 5 to 10 KW to cut a target material such as Al or Al-Si (Si: 0.5 %) and effect film formation of a metal such as Al, Al-Si, etc. at a deposition speed of about 1000 nm/min (10000 Å/min) on the substrate. This step is a non-selective deposition step. This is called the second film forming step for formation of the wiring to be connected to the electrode. After formation of a metal film of about 500 nm (5000 Å), flowing of argon and application of DC power are stopped. After evacuation of the loadlock chamber 311 to 6.666 x 10 -1 Pa (5 x 10 -3 Torr) or lower, the gate valve 310e is opened and the substrate moved. After the gate valve 310e is closed, N 2 gas is permitted to flow into the loadlock chamber 311 until reaching atmospheric pressure, the gate valve 310f opened and the substrate taken out of the apparatus. According to the second Al film deposition step as described above, the Al film 406 can be formed on the SiO 2 film 402. And, by patterning the Al film 406 as shown in Fig. 7D, a wiring with a desired shape can be obtained. (Experimental Examples) In the following, how excellent the above-described Al-CVD method is and how good of the quality the Al film deposited within the openings is are described based on the experimental results. First, as the substrate, a plurality of N-type single crystalline silicon wafers were prepared, which are thermally oxidized on the surface to form SiO 2 of 800 nm (8000 Å), and have various openings with various apertures from 0.25 µm x 0.25 µm square to 100 µm x 100 µm square patterned to have the subbing Si single crystal exposed (Sample 1-1). These are subjected to formation of Al films according to the Al-CVD method under the conditions as described below. Under the common conditions by use of DMAH as the starting gas, and hydrogen as the reaction gas, a total pressure of 1.995 x 10 2 Pa (1.5 Torr), a DMAH partial pressure of 6.666 x 10 -1 Pa (5.0 x 10 -3 Torr), the power amount passed through the halogen lamp is adjusted and the substrate surface temperature set within the range of 200 °C to 490 °C to form films. The results are shown in Table 1. As can be seen from Table 1, at a substrate surface temperature by direct heating of 260 °C or higher, Al is deposited selectively at a high deposition speed of 300 to 500 nm/min (3000 to 5000 Å/min) within the openings. When the characteristics of the Al film within the openings at substrate surface temperature range of 260 °C to 440 °C are examined, they are found to be excellent such that no carbon is contained, with resistivity being 2.8 to 3.4 µΩcm, reflectance 90 to 95 %, hillock density of 1 µm or higher 0 to 10 and substantially no spike generation (destruction probability of 0.15 µm junction). In contrast, at substrate surface temperatures of 200 °C to 250 °C, the film is found to be considerably good as compared with the prior art although the film quality is slightly worse as compared with the case of 260 °C to 440 °C, but the deposition speed is 100 to 150 nm/min (1000 to 1500 Å/min), which can never be said to be sufficiently high. When the substrate surface temperature becomes 450 °C or higher, the characteristics of the Al film with the openings are lowered with the reflectance becoming 60 % or less, hillock density of 1 µm or more 10 to 10 4 cm -2 , alloy spike generation 0 to 30 %. Next, description is made about how suitably the method as described above can be used openings such as contact hole or thru-hole. That is, it can be also preferably applied to the contact hole/thru-hole structure comprising the material as described below. On the Sample 1-1 as described above, an Al film is formed on a substrate (sample) as described below under the same conditions as when the Al film is formed. On a single crystalline silicon as the first substrate surface material is formed a silicon oxide film according to the CVD method as the second substrate surface material, and patterning effected according to the photolithographic steps to have the single crystalline silicon surface partially exposed. The film thickness of the thermally oxidized SiO 2 film has a film thickness of 800 nm (8000 Å), the exposed portion of the single crystalline silicon a size of 0.25 µm x 0.25 µm to 100 µm x 100 µm. Thus, Sample 1-2 is prepared (hereinafter such samples are represented as "CVD SiO 2 (hereinafter abbreviated as SiO 2 )/single crystalline silicon"). Sample 1-3 is boron doped oxide film formed by normal pressure CVD (hereinafter abbreviated as BSG)/single crystalline silicon, Sample 1-4 phosphorus doped oxide film formed by normal pressure CVD (hereinafter abbreviated as PSG)/single crystalline silicon, Sample 1-5 phosphorus and boron doped oxide film formed by normal pressure CVD (hereinafter abbreviated as BSPG)/single crystalline silicon, Sample 1-6 nitride film formed by plasma CVD (hereinafter abbreviates as P-SIN)/single crystalline silicon, Sample 1-7 hot nitride film (hereinafter abbreviated as T-SiN)/single crystalline silicon, Sample 1-8 nitride film formed by low pressure CVD (hereinafter abbreviated as LP-SiN)/single crystalline silicon, Sample 1-9 nitride film formed by means of an ECR apparatus (hereinafter abbreviated as ECR-SiN)/single crystalline silicon. Further, according to all combinations of the first substrate surface materials (18 kinds) and the second substrate surface materials (9 kinds), Samnples 1-11 to 1-179 (note: Sample Nos. 1-10, 20, 30, 40, 50, 60, 70, 80, 90, 100, 110, 120, 130, 140, 150, 160, 170 are lacking) are prepared. As the first substrate surface material, single crystalline silicion (single crystalline Si), polycrystalline silicon (polycrystalline Si), amorphous silicon (amorphous Si), tungsten (W), molybdenum (Mo), tantalum (Ta), tungsten silicide (WSi), titanium silicide (TiSi), aluminum (Al), aluminum silicon (Al-Si), titanium aluminum (Al-Ti), titanium nitride (Ti-N), copper (Cu), aluminum silicon copper (Al-Si-Cu), aluminum palladium (Al-Pd), titanium (Ti), molybdenum silicide (Mo-Si), tantalum silicide (Ta-Si) are employed. As the second substrate surface material, T-SiO 2 , SiO 2 , BSG, PSG, BPSG, P-SiN, T-SiN, LP-SiN, ECR-SiN are employed. For all of the samples as described above, good Al films comparable with the Sample 1-1 could be formed. Next, on the substrate having Al deposited selectively as described above, Al is deposited non-selectively according to the sputtering method as described above, followed by patterning. As the result, the Al film formed according to the sputtering method, and the Al film selectively selected within the openings are found to be under the contact state with both electrically and mechanically high durability due to good surface characteristic of the Al film. (Experimental Examples) Samples of semiconductor device are trially made according to the methods as described in Examples, and as the result of experimentation, good characteristics as expected can be obtained.

Claims: A semiconductor integrated circuit comprising: a semiconductor substrate (11;720); a plurality of functional devices (61-63) defined in said semiconductor substrate, said functional devices having respective contact electrodes (12); and wiring (Vcc,GND;714), including a wiring conductor (714) interconnecting respective ones of said contact electrodes of at least two of said functional devices, which wiring conductor is embedded in the surface of said substrate (720) and insulated therefrom; characterised in that : said wiring conductor (714) is of aluminium metal or of an aluminium metallic compound selected from: Al-Si,Al-Ti, Al-Cu, Al-Si-Ti or Al-Si-Cu; said wiring conductor is embedded in a groove (711) the sidewalls of which are covered with an insulating layer (712); and said wiring conductor is in direct contact with a diffusion region (721), doped to opposite conductivity type to that of said substrate (720), at the bottom of said groove (711). A integrated circuit as defined in claim 1 wherein one of the functional devices (63) is a CMOS inverter and said wiring conductor (714) is a part of either a power source line (Vcc) or an earth line (GND) which passes through the source region of said inverter (63) and extends into the substrate thereunder, said wiring not being insulated from the source region or the substrate at the source region location, the wiring thus constituting the source contact electrode and connecting the source to the substrate. An integrated circuit as defined in claim 1 wherein said wiring conductor (714) is of monocrystalline aluminium. An integrated circuit as defined in any one of the preceding claims wherein said at least two functional devices (61-63) comprise logic circuit component devices (61,62,63). An integrated circuit as defined in claim 1, constituting a memory, a photoelectric converting device or a signal processing device. An integrated circuit as defined in any preceding claim wherein said groove (711) is deeper than it is wide. A method of producing the semiconductor integrated circuit defined in claim 1 comprising steps of: providing a semiconductor substrate (11;720) having a plurality of functional devices (61-63) defined therein; forming a groove in said substrate, which groove has sidewalls covered by an insulating layer and a bottom portion exposing the substrate material, which groove extends between at least two of said functional devices; injecting or diffusing a dopant into the substrate material exposed at the bottom of said groove, for producing a diffusion region of opposite conductivity type to that of said substrate; and embedding in said groove a wiring conductor of aluminium metal or of an aluminium metallic compound selected from Al-Si, Al-Ti, Al-Cu, Al-Si-Ti or Al-Si-Cu, respectively, by selective deposition of aluminium from a chemical vapour of an alkyl aluminium hydride and hydrogen or by selective deposition of said aluminium metallic compound from a chemical vapour of an alkyl aluminium hydride, hydrogen and one or more of a decomposable Si containing gas, a decomposable Ti containing gas, and a decomposable Cu containing gas, respectively. A method as defined in claim 7 wherein one of the functional devices (63) is a CMOS inverter and said selective deposition is performed to produce an embedded power source line (Vcc) or an embedded earth line (GND) of which said wiring conductor (714) is a part and which part passes through the source region of said inverter (63) and extends into the substrate thereunder, said wiring not being insulated from the source region or the substrate at the source region location, the wiring thus constituting the source contact electrode and connecting the source to the substrate.

Inventors: ICHISE TOSHIHIKO, ISHIZUKA KEIJI, KATAOKA YUZO, OHZU HAYAO, TAKAHASHI HIDEKAZU, ICHISE, TOSHIHIKO, ISHIZUKA, KEIJI, KATAOKA, YUZO, OHZU, HAYAO, TAKAHASHI, HIDEKAZU
Applicants: CANON KK, CANON KABUSHIKI KAISHA
Application year: 1991
Main classification: H01L23
IPC codes: H01L21