Novel peroxy ester, and polymerization initiator and curing agent using the ester

Abstract: A 1-cyclohexyl-1-methylethyl peroxy ester, a novel compound, represented by the formula: wherein R¹ stands for one member selected from the group consisting of H and alkyl groups and R² and R³ independently stand for an alkyl group, provided that R² and R³ each stand for an alkyl group of 1 to 5 carbon atoms and the sum of the carbon atoms of R² and R³ is in the range of from 2 to 6 where R¹ is H and R¹, R², and R³ each stand for an alkyl group of 1 to 9 carbon atoms and the sum of the carbon atoms of R¹, R², and R³ is in the range of from 3 to 11 where R¹ is an alkyl group, a polymerization initiator for a vinyl group-containing compound monomer and a curing agent for an unsaturated polyester resin, which polymerization initiator and curing agent both contain as an active component thereof the ester mentioned above.

Description: This invention relates to novel peroxy esters, specifically 1-cyclohexyl-1-methylethyl peroxy esters. Such peroxy esters may be used in polymerization initiators having the peroxy esters as a principal component and used for vinyl monomers such as, for example, (meth)acrylic esters, methyl methacrylate, vinyl chloride and vinyl acetate; and in curing agents having the peroxy esters as a principal component and used for unsaturated polyester resins. Heretofore, methods for using various organic peroxides and azo compounds such as azo-isobutyronitrile ("AIBN") as polymerization initiators for vinyl monomers either alone or in combination with copolymerizable vinyl monomers or as curing agents for unsaturated polyester resins have been known to the art. As initiators of low-temperature polymerization of such a monomer as vinyl chloride or a derivative thereof, for example, the peroxy esters such as cumyl peroxy neodecanoate (CND) and paramenthane peroxy neodecanoate (PMND) whose carboxylic acid moiety has a tertiary α-carbon are disclosed in Japanese Patent Public Disclosure SHO 58(1983)-120611. As polymerization initiators in the polymerization of unsaturated monomers such as styrene and methyl methacrylate or in the copolymerization of these unsaturated monomers in combination with other copolymerizable unsaturated monomers and as curing agents for unsaturated polyester resins, benzoyl peroxide (BPO), t-butylperoxy-2-ethyl hexanoate (t-BO), pinane peroxy-2-ethyl hexanoate (PEO), or paramenthane peroxy-2-ethyl hexanoate (PMO) has been used either alone or in combination with a peroxide which is active at a higher temperature. AIBN has been used as a polymerization initiator for vinyl acetate. The method for polymerizing a monomer such as vinyl chloride or a derivative thereof by the use of CND and PMND as a polymerization initiator, however, imparts the produced polymer with the offensive odor of the polymerization initiator itself or the decomposition product thereof. The polymerization of styrene or methyl methacrylate and the curing of an unsaturated polyester resin by the use of BPO, t-BO, PEO, or PMO are inferior in productivity due to slow polymerizing and curing speeds and low in quality due to impregnation of the polymer or cured product with the offensive odor. The polymerization of vinyl acetate by the use of AIBN causes undesirable coloration of the produced polymer. There is thus a need for a polymerization initiator and a curing agent which produce high polymerizing and curing speeds and yield a polymer and a cured product which are not imparted with unwanted odor or color. The present invention aims to meet this need. The present invention relates to a 1-cyclohexyl-1-methylethyl peroxy esters, a novel compound not yet published in the literature, represented by the formula: wherein R 1 is H and R 2 and R 3 independently stand for an alkyl group, provided that R 2 and R 3 each stand for an alkyl group of 1 to 5 carbon atoms and the sum of the carbon atoms of R 2 and R 3 is in the range of from 2 to 6; or wherein said peroxy ester is one member selected from the group consisting of 1-cyclohexyl-1-methylethyl peroxy neo-hexanoate, 1-cyclohexyl-1-methylethyl peroxy neo-nonanoate, 1-cyclohexyl-1-methylethyl peroxy neo-decanoate and 1-cyclohexyl-1-methylethyl peroxy neo-tridecanoate. Such peroxy esters may be used in polymerization initiators for a vinyl monomer and curing agents for an unsaturated polyester resin which have the peroxy ester mentioned above as an active component thereof. The peroxy ester of the present invention can be produced in accordance with the conventional method as follows. Specifically, the peroxy ester can be synthesized by the reaction of a carboxylic acid chloride with 1-cyclohexyl-1-methylethyl hydroperoxide in the presence of an alkali. The alkalis which are effectively usable for the reaction mentioned above include inorganic bases such as potassium hydroxide and sodium hydroxide, water solutions of these inorganic bases, and amines such as pyridine, for example. When the synthesis is carried out in the presence of a solvent such as benzene, n-hexane, or dioxane, the reaction time for synthesis becomes shorter and the yield of the synthesis improves. The reaction temperature is approximately in the range of from -10°C to 30°C. The carboxylic acid chloride to be used in the production of the peroxy ester of the present invention can be produced by the reaction of carboxylic acid with a suitable chlorinating agent such as phosphorus trichloride, phosphorus oxytrichloride, or thionyl chloride and then isolating an acid chloride from the resultant reaction mixture. The carboxylic acids which are usable herein include iso-butyric acid, neo-hexanoic acid, neo-nonanoic acid, 2-ethylhexanoic acid, neo-decanoic acid, and neo-tridecanoic acid, for example. The 1-cyclohexyl-1-methylethyl hydroperoxide to be used in the production of the peroxy ester of the present invention can be produced by causing hexahydro-α-cumyl alcohol to react with an excess of hydrogen peroxide in the presence of a strong acid catalyst such as sulfuric acid, phosphoric acid, perchloric acid, p-toluenesulfonic acid, or a strong acid type ion-exchange resin. Specific examples of the peroxy ester of the present invention include 1-cyclohexyl-1-methylethyl peroxyisobutyrate, 1-cyclohexyl-1-methylethyl peroxy octoate, 1-cyclohexyl-1-methylethyl peroxy neo-hexanoate, 1-cyclohexyl-1-methylethyl peroxy neo-decanoate, and 1-cyclohexyl-1-methylethyl peroxy neo-tridecanoate. The peroxy esters of the present invention can be identified by the following method. The infrared absorption spectrum (IR spectrum) allows confirmation of the C=O bond and the O-O bond and the nucleus magnetic resonance spectrum (NMR spectrum) reveals the structures of CH 3 , CH 2 , and CH and they jointly enable determination of the overall chemical structure. Further, the peroxide group content can be ascertained by using iodometry to determine active oxygen. The peroxy ester of the present invention is useful as a polymerization initiator and a curing agent. The peroxy ester, when used as a polymerization initiator, accelerates the polymerization rate and improves the productivity. To be more specific, the peroxy ester of the present invention is useful as a polymerization initiator for such unsaturated monomers as vinyl chloride, styrene, methyl methacrylate, and vinyl acetate and for copolymerization of these unsaturated monomers with other copolymerizable unsaturated monomers such as butadiene, acrylonitrile, maleic anhydride, α-methyl styrene, and acrylic esters. The particular peroxy ester of the present invention to be used for the polymerization of a vinyl monomer is suitably selected, depending on the kind of the vinyl monomer and the polymerization temperature thereof. For the polymerization of a vinyl chloride monomer which has a polymerization temperature in the range of from 40°C to 50°C, 1-cyclohexyl-1-methylethyl peroxy neo-decanoate, for example, functions particularly desirably. For the polymerization of methyl methacrylate or derivative thereof having a polymerization temperature in the range of from 70°C to 90°C, 1-cyclohexyl-1-methylethyl peroxy octoate functions, for example, particularly desirably. For the polymerization of styrene or a derivative thereof having a polymerization temperature in the range of from 90°C to 110°C, 1-cyclohexyl-1-methylethyl peroxy isobutyrate, for example, functions particularly desirably. Further, the peroxy ester of the present invention is also useful as a curing agent for unsaturated polyester resins. Particularly, 1-cyclohexyl-1-methylethyl peroxy-secondary aliphatic esters of the present invention, in a range of medium to high curing temperatures from 70°C to 100°C), effect desired curing at a high speed, yield cured products having neither offensive odor nor unwanted color, and provide cured products of high quality with high production efficiency. When the peroxy ester of the present invention is used as a polymerization initiator or a curing agent as described above, it may be used either alone or in combination with one or more other peroxides. The peroxide thus used additionally varies depending on the polymerizing or curing speed. Where the temperature is not higher than about 80°C, at least one member selected from the group consisting of peroxy esters, diacyl peroxides, and peroxy dicarbonates which have a 10-hour half-life temperature (T 10 ) in the range of from 30°C to 65°C is used. To be specific, usable peroxy esters include t-butyl peroxy pivalate (55°C), t-butyl peroxy neo-decanoate (46.5°C), and cumyl peroxy neodecanoate (36.6°C), for example, usable diacyl peroxides include isobutylyl peroxide (32.5°C), 3,5,5-trimethylhexanoyl peroxide (59.5°C), lauroyl peroxide (62°C), and octanoyl peroxide (62°C), for example, and usable peroxy dicarbonates include di(2-ethylhexyl) peroxy dicarbonate (43.4°C), di-n-propyl peroxy dicarbonate (40.5°C), and diisopropyl peroxy dicarbonate (40.5°C), for example. Peroxides whose T 10 temperatures are in the range of from 80°C to 110°C are used where the polymerizing or curing temperatures above 80°C. Specific peroxides answering this description include 1,1-bis(t-butylperoxy)-3,3,5-trimethyl cyclohexane (90°C), 1,1-bis(t-butylperoxy)-cyclohexane (91°C), t-butyl peroxyisopropyl carbonate (98°C), and t-butyl peroxybenzoate (104°C), for example. The amount of the polymerization initiator to be used in the present invention generally is in the range of from 0.001 to 1 part by weight as pure substance, preferably from 0.01 to 0.5 part by weight, based on 100 parts by weight of the vinyl monomer being used. If this amount is less than 0.001 part by weight, the polymerization rate is liable to be unduly slow. If the amount exceeds 1 part by weight, the disadvantage arises that the reaction of polymerization is difficult to control and the produced polymer is liable to acquire inferior physical properties. The amount of the curing agent to be used in the present invention is generally in the range of from 0.05 to 3 parts by weight as pure substance, preferably from 0.5 to 1 part by weight, based on 100 parts by weight of the unsaturated polyester resin to be cured. If this amount is less than 0.05 part by weight, the curing speed is slow, the curing does not proceed to its completion, and the produced cured substance lacks usefulness. Conversely, if this amount exceeds 3 parts by weight, the curing speed becomes too fast so that the cured substance sustains cracks and is consequently of poor quality. Though the amount of the peroxide to be additionally used for polymerization or curing may be suitably selected, it is generally in the range of from 1/4 to 4 times the amount of the 1-cyclohexyl-1-methylethyl peroxy ester to be used. In the polymerization or curing by the use of the peroxy ester of the present invention, a chain transfer agent such as, for example, a mercaptan, an α-methylstyrene dimer, or terpinolene may be used for the purpose of adjusting the polymerizing or curing speed or adjusting the molecular weight. The polymerization of a vinyl monomer by the use of a polymerization initiator including a peroxy ester of the present invention may be performed by the method of suspension polymerization, bulk polymerization or emulsion polymerization. The curing of an unsaturated polyester resin by the use of a curing agent including a peroxy ester of the present invention may be carried out by the method of casting or superposition. The temperature of the polymerization of a vinyl monomer or of the curing of an unsaturated polyester resin by the use of a polymerization initiator or a curing agent including a peroxy ester of this invention is generally in the range of from 30°c. The operation of polymerization or curing may be performed at a fixed temperature or at a gradually elevated temperature in the range of from 30°C to 120°C. If the polymerizing or curing temperature is below 30°C, the polymerizing or curing time is liable to be unduly long. Conversely, if this temperature exceeds 120°C, the polymerization initiator or the curing agent possesses only a short service life and it is difficult to realize high conversion in the operation of polymerization or curing. Now, the present invention will be described more specifically below with reference to working examples and comparative experiments. EXAMPLE 1 [Synthesis of 1-cyclohexyl-1-methylethyl peroxy isobutyrate (C-isobutyrate)] In a four-neck flask having an inner volume of 1 liter and provided with a stirrer and a thermometer, 336.7 g (1.2 mols) of an aqueous 20% potassium hydroxide solution and 179.4 g (1.1 mols) of 1-cyclohexyl-1-methylethyl hydroperoxide (CMEH) having a purity of 97% were stirred while being kept at an internal temperature of from 10°C to 15°C by an external ice bath and 106.6 g (1.0 mol) of isobutyric acid chloride was added dropwise thereto over a period of 30 minutes. Thereafter, the ensuing reaction was continued at 15°C to 20°C for two hours. The stirring was discontinued. The contents of the flask were transferred into a separation funnel for phase separation. The organic layer consequently formed was washed twice with 300 g of an aqueous 5% sodium hydroxide solution then washed with water until it was neutralized and finally dried with anhydrous magnesium sulfate. Consequently, 202 g of a liquid product was obtained. When this liquid product was tested by iodometry, the active oxygen content was found to be 6.92%, the purity of the product to be 98.7%, and the yield of polymerization to be 87.3%. This liquid product showed the following characteristic properties. IR O-O stretching vibration 855 cm -1 C=O stretching vibration 1,780 cm -1 NMR (CDCl 3 ) 1.08 to 1.16, m, 5H H a ○ 1.18 , s, 6H H b ○ 1.40 to 1.77, m, 6H H c ○ 1.61 , d, 6H H d ○ 4.85 to 5.17, m, 1H H e ○ From the data, the product was confirmed to be an organic peroxide possessing the following chemical structure. EXAMPLE 2 [Synthesis of 1-cyclohexyl-1-methylethyl peroxy octoate (C-octoate)] A liquid product was obtained in the amount of 246 g by following the procedure of Example 1, except that 162.7 g (1.0 mol) of 2-ethylhexanoic acid chloride was used in place of isobutyric acid chloride. When this liquid product was tested by iodometry, the active oxygen content was found to be 5.55%, the purity of the product to be 98.6%, and the yield of the polymerization to be 85.3%. This liquid product showed the following characteristic properties. IR O-O stretching vibration 860 cm -1 C=O stretching vibration 1,770 cm -1 NMR (CDCl 3 ) 0.75 to 0.95, m, 6H Ha ○ 1.02 to 1.14, m, 5H H b ○ 1.20 , s, 6H H c ○ 1.18 to 1.85, m, 8H H d ○ 1.37 to 1.75, m, 6H H e ○ 2.21 to 2.23, m, 1H H f ○ From the data, the product was confirmed to be an organic peroxide possessing the following chemical structure. EXAMPLE 3 [Synthesis of 1-cyclohexyl-1-methylethyl peroxy neo-decanoate (C-neodecanoate)] In a four-neck flask having an inner volume of 200 ml and provided with a stirrer, 28.3 g of an aqueous 35% potassium hydroxide solution was placed and kept stirred at a liquid temperature of 20°C and a mixture of 17.9 g of 95% 1-cyclohexyl-1-methylethyl hydroperoxide with 10 g of hexane was added thereto. The resultant mixture was further kept stirred at a liquid temperature of 20°C and 19.1 g of neo-decanoic acid chloride was added dropwise thereto over a period of 10 minutes. The resultant mixture was kept stirred at a liquid temperature of 20°C for three hours and subsequently stirred with 20 g of cold water added thereto over five minutes. The resultant mixture was subjected to phase separation and then deprived of the aqueous phase. The residual phase was washed with 20 g of an aqueous 5% sodium hydroxide solution and then washed three times with water. The resultant solution was dried over anhydrous magnesium sulfate and left standing under a vacuum to expel the remaining hexane. Consequently, 24.1 g of a colorless liquid product was obtained. The active oxygen content was found to be 4.83%, the purity of the product to be 94.3%, and the yield of polymerization to be 73 mol%. This substance was identified from the IR and NMR spectra. The results are shown in Table 1. It was further tested for speed of thermal decomposition with benzene as a solvent (concentration: 0.1 mol/liter). As a result, the 10-hour half-life temperature (T 10 ) of this peroxy ester was found to be 41.4°C. EXAMPLE 4 [Synthesis of 1-cyclohexyl-1-methylethyl peroxy neo-hexanoate (C-neo-hexanoate)] A colorless liquid product, C-neo-hexanoate, was synthesized by following the procedure of Example 3, except that neo-hexanoic acid chloride was used instead as a carboxylic acid chloride. The produced substance was identified from the IR and NMR spectra. The results are shown in Table 1. This substance was tested for speed of thermal decomposition in the same manner as in Example 3. As a result, the 10-hour half-life temperature of this peroxy ester was found to be 46.2°C. EXAMPLE 5 [Synthesis of 1-cyclohexyl-1-methylethyl peroxy neo-nonanoate)] A colorless liquid C-neo-nonanoate was synthesized by following the procedure of Example 3, except that neo-nonanoic acid chloride obtained by chlorinating neo-nonanoic acid (produced by Idemitsu Petro-Chemical Co., Ltd. and marketed as "Equacid 9") was used instead as a carboxylic acid chloride. The results are shown in Table 1. This substance was tested for speed of thermal decomposition in the same manner as in Example 3. As a result, the 10-hour half-life temperature of this peroxy ester was found to be 40.5°C. EXAMPLE 6 [Synthesis of 1-cyclohexyl-1-methylethyl peroxy neo-tridecanoate(C-neotridecanoate)] A colorless liquid C-neo-tridecanoate was synthesized by following the procedure of Example 3, except that neo-tridecanoic acid chloride obtained by chlorinating neo-tridecanoic acid (produced by Idemitsu Petro-Chemical Co., Ltd. and marketed as "Equacid 13") was used instead as a carboxylic acid chloride. The results are shown in Table 1. This substance was tested for speed of thermal decomposition in the same manner as in Example 3. As a result, the 10-hour half-life temperature of this peroxy ester was found to be 40.9°C. From the results, it is clear that the 1-cyclohexyl-1-methylethyl peroxy neo-alkanoates of the present invention have shorter decomposition half lines than t-alkylper acid esters of the prior art derived from the same carboxylic acids. EXAMPLE 7 (Use of peroxy ester for polymerization of vinyl chloride) In an autoclave of stainless steel having an inner volume of 400 ml, 0.1 part by weight of polyvinyl alcohol was dissolved in 100 ml of deionized water. Then, the resultant solution and 0.07 part by weight as pure substance of the 1-cyclohexyl-1-methylethyl peroxy neodecanoate (C-neo-decanoate) obtained in Example 3 added thereto were cooled to below -80°C. To the cooled mixture, 100 parts by weight of vinyl chloride monomer was added. The air in the empty space of the autoclave was thoroughly displaced with nitrogen gas and then the autoclave was airtightly stoppered. The autoclave was kept immersed in a constant temperature water bath maintained at 45°C to effect polymerization of the monomer therein. The contents of the autoclave was stirred by rotating the autoclave at the rate of 32 r.p.m. in the water bath. The resultant polymerization mixture was cooled to expel the unaltered vinyl chloride monomer and obtain a white powder. The white powder was washed twice with 100 ml of water and then dried in a vacuum. From the weight of the white powder thus produced, the yield of the vinyl chloride polymer was found to be 84% and the average polymerization degree thereof to be 2,020. The vinyl chloride polymer was subjected to the following coloring test to determine thermal stability. It was also tested for odor. The results are shown in Table 2. [Coloring test and odor] A mixture consisting of 100 parts by weight of a given vinyl chloride polymer, 2.5 parts by weight of dibutyl tin malate, and 80 parts by weight of dioctyl phthalate as a plasticizer was kneaded with a rolling mill at 160°C for 10 minutes to yield a sheet 1 mm in thickness. The sheet was visually examined as to degree of coloration. The sheet issuing from the rolling mill was examined for odor. COMPARATIVE EXPERIMENTS 1 AND 2 Vinyl chloride monomer was polymerized by following the procedure of Example 7 , except that CND and PMND were each used in a fixed amount of 0.07 part by weight in place of 0.07 part by weight of C-neo-decanoate as a polymerization initiator. The results are shown in Table 2. EXAMPLES 8 AND 9 Polymerization of vinyl chloride monomer was carried out by following the procedure of Example 7 , except that the amount of C-decanoate added as a polymerization initiator and the polymerization temperature were varied. The results are shown in Table 2. EXAMPLE 10 Polymerization of vinyl chloride monomer was carried out at a polymerization temperature by following the procedure of Example 7 , except that 0.07 part by weight of the 1-cyclohexyl-1-methylethyl peroxy neo-nonanoate (C-neo-nonanoate) obtained in Example 5 was used in place of 0.07 part by weight of C-neo-decanoate as a polymerization initiator. The results are shown in Table 2. COMPARATIVE EXPERIMENT 4 For the purpose of comparison, polymerization of vinyl chloride monomer was carried out by following the procedure of Example 10, except that 0.07 part by weight of cumyl peroxy neo-nonanoate (CNH) was used in place of the C-neo-nonanoate as a polymerization initiator. The results are shown in Table 2. EXAMPLE 11 [Copolymerization of vinyl chloride with vinyl acetate] Polymerization was carried out by following the procedure of Example 7, except that 90 parts by weight of vinyl chloride monomer and 10 parts by weight of vinyl acetate monomer were used in place of 100 parts by weight of vinyl chloride monomer and the polymerization temperature was changed to 50°C. The results are shown in Table 2. From the results, it is clear that the methods using polymerization initiators of the present invention produced polymers of satisfactory physical properties in higher yields than the methods using the conventional polymerization initiators for vinyl chloride monomer. EXAMPLE 12 [Polymerization of MMA] In a glass ampoule having an inner volume of 20 ml, 10 g of methyl methacrylate and 0.0046 g (2 x 10 -5 mol) of the C-isobutyrate synthesized in Example 1 were placed. The ampoule was vacuumized, fused, and sealed. In a constant temperature oil bath, the monomer was polymerized at 80°C for five hours and then further polymerized at 100°C for two hours. The ampoule was opened and the resultant polymerization mixture was tested by gas chromatography to determine the residual monomer content. Consequently, the conversion of polymerization was found to be 96.6%. The polymer was odorless. COMPARATIVE EXPERIMENTS 6 AND 7 Polymerization was carried out by following the procedure of Example 12 except that the various polymerization initiators indicated in Table 3 were individually used in an amount of 2 x 10 -5 mol in place of the C-isobutyrate. The results are shown in Table 3. Comparative Experiment Polymerization initiator Conversion of polymerization (%) Odor of polymer 6 BPO 89.7 none 7 PMO 91.5 odor of terpene COMPARATIVE EXPERIMENT 8 For the purpose of comparison, polymerization was carried out by following the procedure of Example 6, except that 0.05 part by weight of paramenthane peroxy pivalate (PMPV) was used in place of the C-pivalate as a polymerization initiator. The produced sheet was colorless. It smelled of terpene. EXAMPLE 13 In a glass ampoule having an inner volume of 20 ml, 9.9 g of methyl methacrylate, 0.1 g of butyl acrylate, 0.02 g of n-dodecyl mercaptan, and 0.0057 g (2 x 10 -5 mol) of the C-octoate synthesized in Example 2 were placed. The ampoule was vacuumized, fused, and airtightly sealed. The ampoule was then left standing in a constant temperature oil bath at 90°C for seven hours to polymerize the monomer therein. The produced polymer was removed from the ampoule. The conversion of polymerization was found to be 97.4%. COMPARATIVE EXPERIMENT 9 Polymerization was carried out by following the procedure of Example 13 , except that 0.0045 g (2 x 10 -5 mol) of t-butyl peroxy octoate (t-BO) was used in place of the C-octoate. As a result, the conversion of polymerization was found to be 90.1%. EXAMPLE 14 [Polymerization of styrene] In an autoclave of stainless steel having an inner volume of 500 ml, 0.1 g of polyvinyl alcohol was dissolved in 200 ml of deionized water. To the resultant solution were added 200 g of styrene and 0.228 g (0.001 mol) of the C-isobutyrate synthesized in Example 1. The air in the empty space of the autoclave was thoroughly displaced with nitrogen gas and then the autoclave was airtightly stoppered. The autoclave was heated in a constant temperature oil bath at 100°C for 10 hours to polymerize the monomer. The monomer inside the autoclave was stirred by rotating the autoclave at the rate of 32 r.p.m. in the oil bath. The resultant polymer was cooled, thrown into methanol to be reprecipitated, separated by filtration, and dried. Based on the weight of the produced white powder, the conversion of polymerization was found to be 78.1%. This polymer was odorless. COMPARATIVE EXPERIMENTS 10 AND 11 Polymerization was carried out by following the procedure of Example14 , except that 0.001 mol of various polymerization initiators shown in Table 4 were individually used in place of the C-isobutyrate. The results are shown in Table 4. Comparative Experiment Polymerization initiator Conversion of polymerization (%) Odor of polymer 10 BPO 54.0 none 11 PEO 72.3 odor of terpene EXAMPLES 15 AND 16 AND COMPARATIVE EXPERIMENTS 12 AND 13 In the same apparatus as used in Example 14 , 0.1 g of polyvinyl alcohol was dissolved in 200 ml of deionized water. To the resultant solution were added 200 g of styrene and 4 x 10 -4 mol of one of the polymerization initiators indicated in Table 5. In a constant temperature oil bath, the monomer in the autoclave was continuously heated so as to elevate the temperature at a fixed rate from 80°C to 120°C over a period of 10 hours to polymerize the monomer. Thereafter, polystyrene was produced by following the procedure of Example 18. The results are shown in Table 5. Polymerization initiator Conversion of polymerization (%) Odor of polymer Example 15 C-octoate DBM 98.7 none 16 C-octoate TBZ 99.0 " Comparative Experiment 12 HPO DBM 91.8 " 13 t-BO TBZ 93.1 " EXAMPLE 17 [Copolymerization of styrene and acrylonitrile] In the same apparatus as used in Example 14, 0.1 g of polyvinyl alcohol was dissolved in 200 ml of deionized water. To the resultant solution were added 140 g of styrene, 60 g of acrylonitrile, and 0.456 g (0.002 mol) of the C-isobutyrate synthesized in Example 1. Thereafter, the procedure of Example 14 was followed. The conversion of polymerization was found to be 90.6%. The produced polymer was odorless. COMPARATIVE EXPERIMENT 14 Polymerization was carried out by following the procedure of Example 17 , except that 0.488 g (0.002 mol) of BPO was used in place of the C-isobutyrate. The conversion of polymerization was found to be 81.7%. From the results indicated above, it is clear that in the polymerization and copolymerization of methyl methacrylate, styrene, and vinyl acetate, the methods using polymerization initiators conforming to the present invention produced polymers of better quality than the methods using the conventional polymerization initiators. EXAMPLE 18 [Curing of unsaturated polyester resin] In a beaker having an inner volume of 50 ml, 50 g of an unsaturated polyester resin (produced by Nippon Shokubai Hagaku Kogyo Co., Ltd. and marketed as "Eporack G110A1") and 0.25 g of the C-isobutyrate synthesized in Example 1 were thoroughly mixed by the use of a glass bar until a homogeneous solution was formed. The resultant resin solution was placed to a depth of 100 mm in a double-wall test tube 18 mm in diameter. The test tube was placed in a constant temperature bath set at 80°C, The sample gelling time (time required for the test tube temperature to rise to between 65°C and 85°C with the test tube set in an 80°C constant temperature bath) and the minimum curing time (time required for the test tube temperature to rise from 65°C to the maximum temperature) were checked and found to be 5.6 minutes and 7.2 minutes, respectively. COMPARATIVE EXPERIMENTS 16 AND 17 The curing of an unsaturated polyester resin was carried out by following the procedure of Example 18, except that 0.25 g of a one of the curing agents indicated in Table 6 was used in place of the C-isobutyrate of Example 18. The results are shown in Table 6. Comparative Experiment Curing agent Gelling time (min.) Minimum curing time (min.) Odor of cured produced 16 BPO 6.8 8.4 none 17 PEO 6.1 7.9 odor of terpene

Claims: A 1-cyclohexyl-1-methylethyl peroxy ester represented by the formula: wherein R 1 is H and R 2 and R 3 independently stand for an alkyl group, provided that R 2 and R 3 each stand for an alkyl group of 1 to 5 carbon atoms and the sum of the carbon atoms of R 2 and R 3 is in the range of from 2 to 6; or wherein said peroxy ester is one member selected from the group consisting of 1-cyclohexyl-1-methylethyl peroxy neo-hexanoate, 1-cyclohexyl-1-methylethyl peroxy neo-nonanoate, 1-cyclohexyl-1-methylethyl peroxy neo-decanoate and 1-cyclohexyl-1-methylethyl peroxy neo-tridecanoate.

Inventors: KATOH MITSUKUNI, NISHIKAWA TOORU, SUYAMA SHUJI, KATOH, MITSUKUNI, NISHIKAWA, TOORU, SUYAMA, SHUJI
Applicants: NIPPON OILS & FATS CO LTD, NIPPON OIL AND FATS COMPANY, LIMITED
Application year: 1991
Main classification: C07C409
IPC codes: C07C409, C08F4