Hot electron transistor

Abstract: A semiconductor device or a hot electron transistor being constructed such that an InAs base layer (11) is sandwiched between a GaSb emitter barrier layer (12) and a GaInAsSb-system collector barrier layer (13), which results in preventing hot electrons of unnecessarily high energy from being injected into the collector and an avalanche current from being generated, thereby making it possible to improve the saturation characteristics of the device.

Description: BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to a semiconductor device, and more particularly to a hot electron transistor (HET). Description of the Prior Art Recently, enthusiastic research and development have been directed to an HET as an ultra-high speed element. An HET operable in a room temperature is disclosed in, for example, Applied Physics Letters Vol. 51, No. 13, pp 984 - 986, September 1987, which is constituted by disposing an emitter barrier layer 2 made of AℓSb 0.92 As 0.08 and a collector barrier layer 3 made of GaAs at opposite sides of a base layer 1 made of InAs respectively so as to sandwich the base layer 1 therebetween, as shown in Fig. 1 which is a band model diagram of its conduction band in a biasing state. Since an offset gap ΔE B-C of a conduction band between the base and the collector of the HET thus constructed is 0.8 eV, it is required that an offset gap ΔE B-E of a conduction band of the emitter barrier layer between the base and the emitter is to be selected larger than the offset gap ΔE B-C . Accordingly, the offset gap ΔE B-E of 1.3 ev is established for the HET. However, with the gap ΔE B-E between the base and the emitter being such a high value of 1.3 ev, an energy of a hot electron injected from the emitter into the collector is too high to neglect the ionization in the collector due to the hot electron. More specifically, the hot electrons of high energy injected in the collector eject electrons from a valence band in the collector to generate an avalanche current, which degrades the saturation characteristics of the transistor. Hatched portions in Fig. 1 show an energy level where electrons exist. In the transistor constructed as described above, a layer adjacent to the base layer 1 of In-system, that is, the emitter barrier layer 2 is made of Aℓ-system, which causes a difficulty in setting a selection ratio of etching between the layers of the Aℓ-system and the In-system. Accordingly, upon leading a base electrode from the base layer 1 of the In-system which forms this kind of HET in actual practice, there arises a problem that an etching process for partially removing the In-system emitter barrier layer or emitter layer on the base layer 1 in order to partially expose the base layer 1 is extremely difficult. OBJECTS AND SUMMARY OF THE INVENTION Accordingly it is an object of the present invention to provide an HET having an InAs base layer which is capable of improving the saturation characteristics and symplifying the fabrication process thereof. As an aspect of the present invention, a hot electron transistor is comprised of an InAs base layer, a GaSb emitter barrier layer deposited on one side of the InAs base layer, and a GaInAsSb collector barrier layer deposited on the other side of said InAs layer, whereby the InAs base layer is sandwiched between the GaSb emitter barrier layer and the GaInAsSb collector barrier layer the offset gap ΔE B-C of the conduction band between the base and the collector being selected more than 0.4 eV but less than 0.8 eV. The above, and other objects, features, and advantages of the present invention will become apparent from the following detailed description of illustrative embodiment thereof to be read in conjunction with the accompanying drawings, in which like reference numerals represent the same or similar parts. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a diagram showing a band model of a conventional semiconducter device; Fig. 2 is a graph showing the relationship among the composition of Ga x In 1-x Sb 1-y , the band gap and the lattice constant thereof; Fig. 3 is a cross-sectional view of an embodiment of a semiconductor device according to the present invention; and Fig. 4 is a band model diagram of the embodiment shown in Fig. 3. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT Before explaining a preferred embodiment of the present invention, reference will be made to the relationship between the band gap and the lattice constants of Ga x IN 1-x As y Sb 1-y which constitutes the principle of the present invention. Fig. 2 is a graph showing the relationship among the composition, the band gap and the lattice constant of Ga x In 1-x As y Sb 1-y shown on page 41 of "HETERO-STRUCTURE LASERS", Part B, by H. C. Casey, and Jr M. B. Panish, published by Academic Press. As is apparent from the graph, the GaInAsSb-system semiconductor has a band gap smaller than 0.8 eV. It is therefore possible to provide an offset gap ΔE B-C of the conduction band between the base and the collector sufficiently smaller than 0.8 ev, and accordingly it is possible to provide an offset gap ΔE B-E of the conduction band between the base and the emitter smaller than the conventional value of 1.3 eV, for example, 0.8 ev, by an emitter barrier layer made of GaSb. Now, an embodiment of a hot electron transistor (HET) according to the present invention will be explained with reference to Figs. 3 and 4. As shown in Fig. 3, on an n-type highly concentrated GaSb semiconductor substrate 9, there are sequentially formed an n-type GaSb collector layer 10 having a thickness of 200 nm, an intrinsic GaSb underlaying layer 13A having a thickness of 100 nm for a collector barrier layer, an intrinsic Ga x In 1-x As y Sb 1-y , for example, Ga 0.8 In 0.2 As 0.2 Sb 0.8 collector barrier layer 13 having a thickness of 10 nm, an n-type InAs base layer 11 having a thickness of 10 nm, an intrinsic GaAs emitter barrier layer 12 having a thickness of 100 nm, and an n-type highly concentration GaSb emitter layer 14 having a thickness of 200 nm. Thereafter, the emitter layer 14 and the emitter barrier layer 12 are partially etched away by an etching method which has selectively in stching Ga-system and In-system materials, for example, a reactive ion etching (RIE) method using a CCl₂F₂+He system to thereby partially expose a part of the base layer 11. A base electrode 15 is made in ohmic contact with the exposed surface of the base layer 11, and simultaneously an emitter electrode 16 is deposited on the emitter layer 14 in an ohmic contact therewith. Further, a collector electrode 17 is ohmicly deposited, for example, on the rear surface of the substrate 9. According to the invention, the offset gap ΔE B-E of the conduction band between the base and the emitter becomes 0.8 ev, while the offset gap ΔE B-C between the base and the collector falls in a range of more than 0.4 - and less than 0.8 eV, thereby making it possible for this device to operate as a transistor at room temperature. Incidentally, when atomic ratios x and y of the collector barrier layer 13 composed of Ga x In 1-x As y Sb 1-y are set in ranges of 0.8 ≦ x < 1.0 and 0 < y ≦ 0.2, respectively, the lattice constants thereof match or favorably match with the lattice constants of InAs constituting the base layer 11 to thereby make it possible to perform a good epitaxy. Further, it is possible to perform a good epitaxy of the GaSb emitter barrier layer 12 on this InAs base layer 11. Further, the offset gap ΔE B-C between the base and the collector can be fallen within a range of 0.4 eV - 0.8 eV while the offset gap ΔE B-E between the base and the emitter can be determined as 0.8 eV. The respective layers 10-13A-13-11-12-14 can be formed continuously and epitaxially as a series of works by the MOCVD (Metal Organic Chemical Vapor Deposition) method, MBE (molecular Beam Epitaxy) method and so on. Reference numerals 18 and 19 in Fig. 3 respectively designate insulating layers, each made of, for example, oxide materials or the like. While GaSb substrate 9 is used in the embodiment shown in Fig. 3, in some cases GaSb or InAs substrate of, for example, n-type having a high impurity concentration, i.e. low resistivity may be provided, and thereon the GaSb collector layer 10 may be epitaxially grown. Also in this case, the respective layers on the substrate 9 can be epitaxially grown successively by a series of works by the MOCVD method or the MBE method. According to the construction of the present invention having the band model shown in Fig. 4, when the collector barrier layer 13 is made of a compound semiconductor of GaInAsSb-system, the offset gap ΔE B-C of the conduction band between the base and the collector can be made smaller than 0.8 eV. Further, when the emitter barrier layer 12 is made of GaSb, the offset gap ΔE B-E of the conduction band between the base and the emitter of the emitter barrier layer 12 can be made such a relatively small value of 0.8 eV. Thus, it becomes possible to avoid such phenomena that hot electrons of unnecessarily high energy are introduced into the collector and that an avalanche current is generated, thereby making it possible to improve the saturation characteristics of the device. Further, the selective etching for the emitter layer 14 and the emitter barrier layer 12 in order to partially expose the base layer 11 is performed by using the CCl₂F₂+He-system etching gas which has different etching speeds between the Ga-system material and In-system material, so that one portion of the base layer 11 can be exposed outside easily.

Claims: A hot electron transistor comprising: an InAs base layer (11); a GaSb emitter barrier layer (12) deposited on one side of said InAs base layer (11); and a collector barrier layer (13) deposited on the other side of said InAs base layer (11), whereby said InAs base layer (11) is sandwiched between said GaSb emitter barrier layer (12) and said collector barrier layer (13), characterized in that said collector barrier layer (13) is formed from GaInAsSb, the offset gap Δ E B-C of the conduction band between the base and the collector being selected more than 0.4 eV but less than 0.8 eV. A hot electron transistor according to claim 1 further comprising a GaSb substrate (9, 10) on which said collector barrier layer (13), said base layer (11) and said emitter barrier layer (12) are epitaxially deposited in sequence. A semiconductor device according to anyone of claims 1 to 2, wherein said base layer (11) is of an n-type conductivity, said emitter barrier layer (12) is of an i-type conductivity and said collector barrier layer (13) is of an i-type conductivity, respectively. A method for manufacturing a hot electron transistor according to claims 1 to 3, wherein said base layer (11), said emitter barrier layer (12) and said collector barrier layer (13) are formed by a metal organic chemical vapor deposition method. A method for manufacturing a hot electron transistor according to claims 1 to 3, wherein said base layer (11), said emitter barrier layer (12) and said collector barrier layer (13) are formed by a molecular beam epitaxy method.

Inventors: HASE ICHIRO, KAWAI HIROJI, TAIRA KENICHI, HASE, ICHIRO, KAWAI, HIROJI, TAIRA, KENICHI
Applicants: SONY CORP, SONY CORPORATION
Application year: 1991
Main classification: H01L29
IPC codes: H01L29, H01L21