Photomultiplier tube having grid type dynodes

Abstract: An electron multiplier tube including grid type of plural dynode arrays (6) arranged in a first direction with a multistage structure for successively multiplying electrons incident on them and an anode (4) provided below the multistage structure of dynode arrays (6) for collecting the multiplied electrons to output an amplified electrical signal. Each of the dynode arrays (6) includes plural rod-shaped dynode elements (9) arranged in a second direction and a mesh electrode (10) provided over each of the dynode arrays for providing an equipotential. The multistage structure of dynode arrays includes at least one group of neighbouring dynode arrays (6₄,6₅;6₆,6₇;6₈,6₉) whose dynode elements are arranged so as to be aligned with one another in the said first direction. Each of the dynode elements (9) has a substantially isosceles trapezoid section, both side legs of the trapezoid being slightly inwardly curved effectively to receive the incident electrons which have been emitted from an earlier dynode array.

Description: This invention relates to an electron multiplier tube such as a photomultiplier tube, a secondary electron multiplier tube or the like which has a grid dynode structure. A photomultiplier tube has been conventionally known as one of electron multiplier tubes , and utilized as a photodetector having a high sensitivity in various technical fields such as a medical field, a high-energy physics, photoanalysis, biotechnology and so on. Fig. 1 shows a typical photomultiplier tube, e.g. from JP-A-55 108 254, having a box and grid combination type of dynode structure (combination of a box dynode structure and a grid dynode structure), and comprises a transmission type of photocathode 1 serving as a negative electrode for converting light into a stream of photoelectrons, a focusing electrode 2 for converging the photoelectron stream, plural dynodes serving as electron multiplying means 3 for multiplying the photoelectrons emitted from the photocathode 1, an anode 4 for collecting the multiplied electrons and a vacuum envelope 5 for accommodating the above elements. In this case, the electron multiplying means 3 comprises a box type of dynodes 6₁ to 6₃ at a front stage (from a first stage to a third stage), and a grid type dynodes 6₄ to 6₉ at a rear stage (from a fourth stage to a ninth stage) which has a multistage structure. This type of photomultiplier tube is disclosed in Japanese Examined Published Patent Application No. 60-30063. In the this type of photomultiplier tube, each of the box type of dynodes 6₁ to 6₃ has a sector shape in sectional profile as shown in Fig. 2. This shape corresponds to one of four quadrants which are obtained by uniformly quartering a hollow cylinder in a longitudinal direction thereof. A mesh electrode 8 for providing an equipotential is further provided over an electron incident side of each of the box type of dynodes 6₁ to 6₃ as shown in Fig. 2. On the other hand, each of the grid type of dynodes 6₄ to 6₉ (hereinafter referred to as "dynode arrays") includes plural rod-shaped dynode elements 9 arranged in a predetermined direction (e.g. horizontally) and another mesh electrode 10 for providing an equipotential which is provided over an electron-incident side thereof. As shown in Fig. 3, the dynode element 9 is an isosceles triangle in section both side legs of the trapezoid being slightly inwardly curved. In other words, the dynode element 9 has a konide-like sectional shape having inwardly-curved (or concave) side walls(hereinafter referred to as "modified konide-shape"). The inwardly-curved side surfaces of each rod-shaped dynode element 9 enables an effective reception of electrons which are emitted from a dynode element at an upper stage. The grid type of dynode arrays thus constructed are laminated to form a multistage structure as shown in Fig. 3. Conventionally, the grid type of dynode arrays 6₄ to 6₉ are wobblingly arranged or offset in the laminating direction of the dynode arrays 6₄ to 6₉ (hereinunder referred to as "wobbling arrangement). In detail, dynode elements 9 at an upper (previous) stage are arranged in a direction vertical to the laminating direction (or horizontally) at a predetermined interval, and dynode elements at a lower (next) stage (located just below the previous stage) are horizontally disposed at positions corresponding to gaps between the dynodes at the previous stage. That is, the dynode array at the next stage is positionally displaced to the dynode array at the previous stage. This arrangement is applied to the subsequent grid type of dynodes at the subsequent stages. A plate-shaped dynode 6₁₀ is provided at the last stage, and an anode 4 for collecting electrons multiplied at the upper dynode stages is provided between the plate-shaped dynode 6₁₀ and the dynode array 6₉ located above the plate-shaped dynode 6₁₀. That is, the "wobbling arrangement" means that the dynode arrays at the neighboring stages are alternately positionally displaced to each other in the laminating direction at a distance (substantially at a half pitch of the dynode elements at each stage). This wobbling arrangement of the multistage dynodes has been conventionally required to attain the following objects. A first object is to increase an effective area of the dynodes for receiving the electrons which have been emitted from the box type of dynodes 6₁ to 6₃ to prevent the electrons emitted from the box type of dynodes from passing through the grid type of dynodes without impinging on the dynode elements. A second object is to prevent an ion feedback affection. The electrons impinging on a dynode element 9 at a stage frequently produce ions such as oxygen ions, and the ions flight upwardly toward other dynode elements at other stages located above the stage. The impingement of the ions on the dynode elements causes emission of secondary electrons. Therefore, the electrons impinging on a dynode element 9 produce not only an output peak which is originated from themselves, but also another output peak which is originated from the ions. The latter output peak is produced with a delay time with respect to the production of the former output peak, and this delayed production of the electrons causes a noise. Further, a large amount of the ions damage the photocathode. The wobbling arrangement of the dynode arrays can prevent the produced ions from flying toward the dynode elements at upper stages because the produced ions at a stage, which fly to upper stages through gaps between the dynode elements, are shielded by bottoms of the dynode elements which are located above the stage and in the gaps. However, a sufficient multiplication has not been obtained in the conventional photomultiplier tube as described above because the grid type of dynodes 6₄ to 6₉ have a low multiplication factor (gain) for secondary electrons. In order to heighten the gain for the secondary electrons, a first proposal is to apply a high voltage between neighboring dynode arrays to heighten an emission factor of secondary electrons, and a second proposal is to increase a number of stages to be laminated to thereby raise the multiplication factor (gain) of the grid type of dynodes. The following disadvantages occur for the first proposal. The secondary electron emission factor is saturated if a voltage to be supplied to the dynode arrays is above a predetermined voltage, and in addition a high voltage damages a voltage-resistance capability of the dynodes. On the other hand, the following disadvantages occur for the second proposal. The multiplying portion or means must be wholly designed in large size, and thus a voltage to be supplied must be larger. Further, an interval between neighboring dynode stages is beforehand determined, and thus the number of the dynode arrays to be accommodated in the envelope 5 is limited to a predetermined number. Through various experimental processes, it has been found that the conventional photomultiplier tube having the wobbling arrangement as shown in Fig. 4 has the following characteristics. When dynode elements 9 at a next (just lower) stage are located so as to confront gaps 11 between dynode elements 9 at a previous (just upper) stage, respectively, as shown in Fig. 4, it is seemingly expected that most of secondary electrons emitted from each dynode element 9 at the previous stage would be caught by (impinge on) the dynode elements 9 at the next stage, and thus contribute to emission of secondary electrons at the next stage. However, according to an experiment, it is assured that the secondary electrons emitted from the dynode elements 9 at the previous stage frequently penetrate through the next stage without impinging on the dynode elements at the next stage, and impinges, for example, on the further lower stages subsequent to the next stage. Fig. 5 is a graph showing an experimental result of a distribution ratio of secondary electrons emitted from the dynode array at the fourth stage to the fifth and subsequent stages. A solid line (characteristic line) B of Fig. 5 represents an electron distribution ratio of the conventional grid type of dynodes having the wobbling arrangement in which dynode elements at even stages are disposed in such a manner as to confront gaps between dynode elements at odd stages. As is apparent from the characteristic line B, the secondary electrons emitted from the fourth dynode array 6₄ impinge on each of the dynode arrays 6₆ and 6₇ at the sixth and seventh stages in higher electron distribution ratio (electron-incidence rate) than on the dynode array 6₅ at the fifth stage. This result indicates that most of the secondary electrons do not impinge on the dynode elements at the next (just lower) stage, but penetrate therethrough to the dynode elements at the further lower stages, and thus the multiplication factor (gain) is lower in such a wobbling arrangement. This invention has an object to provide a photomultiplier tube having a sufficient multiplication factor (gain) for secondary electrons without applying a higher voltage to dynode elements and without increasing a number of dynode stages. According to this invention an electron multiplier tube comprising plural dynode arrays arranged at a first pitch in a first direction with a multistage structure for successively multiplying electrons incident thereto and an anode for collecting the multiplied electrons to output an amplified electrical signal, each of said dynode arrays comprising plural rod-shaped dynode elements arranged at a second pitch in a second direction and a mesh electrode provided over each of said dynode arrays for providing an equipotential, is characterised in that the multistage structure of dynode arrays includes at least one group of neighbouring dynode arrays whose dynode elements are aligned with one another in the said first direction. Preferably each of the dynode elements has a substantially isosceles trapezoid section, both side legs of the trapezoid being slightly inwardly curved to effectively receive the incident electrons which have been emitted from a dynode array at an upper stage. The dynode elements of each of the dynode arrays may be arranged in the second direction in a grid form, a mesh form, or a honeycombed form. Particular embodiments will now be described and contrasted with the prior art with reference to the accompanying drawings; in which:- Fig. 1 is a schematical view of a conventional photomultiplier tube; Fig. 2 is a perspective view of a box type of dynode; Fig.3 is a schematic view of a grid type of dynode arrays; Fig. 4 shows a wobbling arrangement of dynode arrays which is adopted in the conventional photomultiplier tube; Fig. 5 is a graph showing an electron distribution ratio to each dynode array; Fig. 6 shows a first embodiment of a modified wobbling arrangement which is adopted in the photomultiplier tube according to this invention; Fig. 7 shows a second embodiment of the modified wobbling arrangement which is adopted in the photomultiplier tube according to this invention; Fig. 8 shows a third embodiment of the modified wobbling arrangement which is adopted in the photomultiplier tube according to this invention; and, Fig. 9 is a schematic view of another photomultiplier tube having only a grid type of dynode arrays according to this invention. Fig. 6 shows a fist embodiment of a grid type of dynodes serving as a part of the electron multiplying means used in a photomultiplier tube according to this invention. This grid type of the dynodes are structurally the same as those of Fig. 4 except for a specific arrangement of the dynodes. Therefore, the detailed description of the same elements are eliminated from the following description. The photomultiplier tube according to this invention has substantially the same construction as that of Fig. 1, and includes a transmission type of photocathode 1, a focusing electrode 2, a box type of dynodes 6₁ to 6₃ at the front stage, a grid type of dynode arrays 6₄ to 6₉, an anode 4, a plate-shaped dynode 6₁₀ and a vacuum envelope 5. Like the grid type of the dynodes having the wobbling arrangement as shown in Fig. 4, the dynode arrays 6₄ to 6₉ at fourth to ninth stages, the anode 4 and the plate-shaped dynode 6₁₀ at the last stage are arranged at predetermined intervals in the laminating direction of the dynode arrays. In addition, each dynode array at each stage also comprises plural rod-shaped dynode elements 9 arranged at a predetermined pitch in a predetermined direction (horizontally) and a mesh electrode 10 for providing an equipotential. Each dynode element 9 has an isosceles trapezoid in sectional profile, both side legs (lines) of the trapezoid being slightly inwardly curved to effectively receive incident electrons which have been emitted from a dynode array at an upper stage. In other Words, the dynode element 9 has a konide-like sectional shape having inwardly-curved (or concave) side lines (a modified konide-like shape). However, unlike the wobbling arrangement of the dynode arrays as shown in Fig. 4, the grid type of dynodes according to this embodiment includes at least one pair of neighboring dynode arrays whose dynode elements are arranged so as to be aligned with each other without displacement in the laminating direction thereof. In the first embodiment of the grid type of dynodes as shown in Fig. 6, both groups of dynode elements 9 of the fourth and fifth dynode arrays 6₄ and 6₅ are disposed substantially on the same columns (on the same vertical lines), respectively. Similarly, two pairs of neighboring dynode arrays 6₆ and 6₇, and 6₈ and 6₉ are disposed such that the dynode elements 9 of each pair are disposed substantially on the same columns (on the same vertical lines), respectively. These arrangement of the dynode elements of the neighboring dynode arrays are hereinafter referred to as "straight arrangement". On the other hand, the dynode arrays 6₅ and 6₆ (and 6₇ and 6₈) are wobblingly arranged such that the dynode elements 9 thereof are displaced to each other like the conventional grid type of dynodes. When the photomultiplier tube including the grid type of dynodes thus constructed (that is, the grid type of dynodes having a modified wobbling arrangement) are actuated, the photocathode 1, the focusing electrode 2, the first to tenth dynodes (or dynode arrays) 6₁ to 6₁₀ and the anode 4 are supplied with, for example, 0, 200, 300, 400, 500, 600, 700, 800, 900, 1000, 1100, and 1200 volts, respectively. A photomultiplying operation of the photomultiplier tube of this embodiment will be described hereunder. Upon incidence of light into a position on the photocathode 1, photoelectrons are emitted from the incident position on the photocathode 1. The photoelectrons are convergently directed to the first dynode 6₁ of the box type of dynodes by the focusing electrode 2. Upon incidence of the photoelectrons to the first dynode 6₁, secondary electrons are emitted from an incident position on the first dynode 6₁ to the next (second) dynode 6₂ to be mulitiplied with an secondary electron emission effect of the dynodes. The secondary electron emission (multiplying) process is repeated in the further next (third) dynode 6₃, and the electrons thus multiplied are supplied to the grid type of dynodes (dynode arrays) 6₄ to 6₁₀, and then outputted from the anode 4. As described above, the grid type of dynodes of this embodiment includes three pairs of neighboring dynode arrays, the dynode elements 9 of each pair being arranged on the same columns (on the same vertical lines). This modified wobbling arrangement effectively performs the incidence of the secondary electrons from the fourth dynode array 6₄ to the fifth dynode array 6₅, the incidence of the secondary electrons from the sixth dynode array 6₆ to the seventh dynode array 6₇, and the incidence of the secondary electrons from the eighth dynode array 6₈ to the ninth dynode array 6₉, and thus improves the multiplication factor (gain) more sufficiently. A one-dotted line A in Fig. 5 represents an electron distribution (incidence) ratio of the grid type of dynodes having a modified wobbling arrangement in which the dynode elements 9 of the fourth and fifth dynode arrays 6₄ and 6₅ are disposed so as to be confronted to each other (that is, with no displacement). According to the line A, most of the secondary electrons which have been emitted from the fourth dynode array 6₄ are incident to the dynode elements 9 of the fifth dynode array 6₅, and thus there is little possibility that the secondary electrons emitted from the fourth dynode array 6₄ are passed through the fifth dynode array 6₅ without impinging on the fifth dynode array 6₅ and incident to the sixth or subsequent dynode array. In this case, the dynode arrays 6₅ and 6₆ (6₇ and 6₈) are wobblingly arranged, so that the ion feedback affection is prevented. In the first embodiment, three pairs of dynode arrays each of which has two dynode arrays having the straight-line arrangement, are wobblingly arranged (alternately displaced to one another). That is, the dynode elements of each pair are arranged with no displacement, but the pairs themselves are wobblingly arranged. This arrangement is hereinafter referred as "two-two wobbling arrangement". The arrangement of the grid type of dynodes according to this invention is not limited to the "two-two wobbling arrangement", but any modification may be made. Fig. 7 shows a second embodiment of the grid type of dynodes according to this invention. In this embodiment, one dynode array is provided between two pairs of neighboring dynode arrays each of which has two dynode arrays having the "straight arrangement" in such a manner as to be displaced (wobblingly disposed) with respect to each of the pairs of the dynode arrays. This arrangement is hereinafter referred to as "two-one wobbling arrangement". Fig. 8 shows a third embodiment of the grid type of dynodes according to this invention. In this embodiment, all of the dynode arrays 6₄ to 6₉ are arranged with no displacement, that is, the dynode elements 9 of all the dynode arrays are disposed substantially on the same columns (on the same vertical lines). In this case, there occurs a problem that the ion feedback can not be prevented. However, the secondary electrons are most effectively multiplied. This arrangement is hereinafter referred to as "matrix arrangement". In addition to the "two-two wobbling arrangement", "two-one wobbling arrangement", and "matrix arrangement" as described above, for example, "three-one wobbling arrangement", "four-one wobbling arrangement",..., "three-three wobbling arrangement", "four-four wobbling arrangement",.., "n-m wobbling arrangement" may be adopted where n and m are integers. That is, at least one pair of neighboring dynode arrays are arranged straightforwardly in a laminating direction of the dynode arrays (electron multiplying direction) such that the dynode elements of these dynode arrays seems to be overlapped to one another when seen along the laminating direction of the dynode arrays. In the above embodiments, the first to third dynodes serving as a box type of dynodes and the fourth to ninth dynode arrays serving as a grid type dynodes are used in combination. However, the electron multiplying means of this invention is not limited to the above embodiments. For example, as shown in Fig. 9, only a grid type of dynodes can be used as the electron multiplying means. Further, a combination of a grid type and one or more of a circular cage type, a line focusing type and a Venetian blind type may be adopted. The number of the dynode stage of the dynode arrays are not limited to that of the above embodiments, and may be two or more dynode stages two of which are arranged with no displacement. Further, the photocathode may be of a transmission type or a reflection type. In the above embodiments, each dynode array comprises plural rod-shaped dynode elements which are parallel arranged at a predetermined pitch, however, the horizontal arrangement of the dynode elements of each dynode array is not limited to this embodiment. These dynode elements may be arranged in a mesh form or a honeycombed form such that rod-shaped members serving as dynode elements are intersected to one another. The above embodiments are described in a case where the grid type of dynodes having a modified wobbling arrangement is applied to the photomultiplier tube, however, the same effect can be obtained in a case where they are applied to other types of electron multiplier tubes such as a secondary electron multiplier tube. As described above, the grid type of dynodes according to this invention includes at least one pair of neighboring dynode arrays whose dynode elements are disposed straightforwardly in the multiplication direction without displacement, so that the electron multiplication factor(gain) can be improved without increasing voltages to be supplied to the dynodes and without incrementing the number of dynode arrays. In a comparative experiment using a photomultiplier tube to which the grid type of dynodes having the wobbling arrangement as shown in Fig. 4 and the grid type of dynodes having the two-two wobbling arrangement as shown in Fig. 6 are provided, the photomultiplier tube of this invention has an increase of the multiplication factor (gain) by 3.18 times in comparison with the conventional photomultiplier tube. Further, in another comparative experiment using a photomultiplier tube to which the grid type of dynodes having the wobbling arrangement as shown in Fig. 4 and the grid type of dynodes having the matrix arrangement as shown in Fig. 8 are equipped, the photomultiplier tube of this invention has an increase of the multiplication factor (gain) by 5.04 times. Here, an experimental data for each of the photomultiplier tubes of this invention and the prior art is an average value of 10 samples which are manufactured under the same condition. In this experiment, the dimension of a Konide-like section of each dynode element 9 is as follows: the top width is 0.13 to 0.18 mm; the bottom width,0.48 to 0.5 mm; and the height, 0.25 mm. Further, a pitch between neighboring dynode elements is 0.5 mm, and a gap interval between neighboring dynode arrays is 1.25 mm. Distances between the bottom of each dynode element 9 and a mesh electrode 10 just below the dynode element 9 and between the top of each dynode element 9 and a mesh electrode 10 just above the dynode element 9, are 0.87 mm and 0.25 mm, respectively.

Claims: An electron multiplier tube comprising plural dynode arrays (6) arranged at a first pitch in a first direction with a multistage structure for successively multiplying electrons incident thereto and an anode (4) for collecting the multiplied electrons to output an amplified electrical signal, each of said dynode arrays (6) comprising plural rod-shaped dynode elements (9) arranged at a second pitch in a second direction and a mesh electrode (10) provided over each of said dynode arrays (6) for providing an equipotential, characterised in that the multistage structure of dynode arrays includes at least one group of neighbouring dynode arrays whose dynode elements (9) are aligned with one another in the said first direction. An electron multiplier tube as claimed in claim 1, wherein each of said dynode elements (9) has a substantially isosceles trapezoid section, both side legs of the trapezoid being slightly inwardly curved effectively to receive the incident electrons which have been emitted from a dynode array at an earlier stage. An electron multiplier tube as claimed in claim 1 or 2, further comprising a plate-shaped dynode (6₁₀) provided behind said anode (4). An electron multiplier tube as claimed in claim 3, wherein each of said dynode arrays (6), said anode (4) and said plate-shaped dynode (6₁₀) are supplied with stepwisely-increased voltages in this order. An electron multiplier tube as claimed in any preceding claim, wherein said at least one group of dynode arrays (6) are disposed at the front of the multistage structure. An electron multiplier tube as claimed in any one of the preceding claims, wherein all of said dynode arrays (6) are arranged such that their dynode elements are aligned with one another in the said first direction. An electron multiplier tube as claimed in any preceding claim, wherein said dynode elements of each of said dynode arrays (6) are arranged in the second direction in a grid form, a mesh form, or a honeycombed form. An electron multiplier tube as claimed in any preceding claim, further comprising box type dynodes, circular cage type dynodes, line focus type dynodes or Venetian type dynodes which are provided in front of said multistage structure of dynode arrays. An electron multiplier tube as claimed in any preceding claim, wherein said one group of neighbouring dynode arrays comprises two dynode arrays. An electron multiplier tube as claimed in any preceding claim, further comprising a photocathode (1) for converting light into photoelectrons, a focusing electrode (2) for converging the photoelectrons onto the dynode arrays (6), thereby to convert the light into an amplified electrical signal.

Inventors: KIMURA SUENORI, KIMURA, SUENORI, KIMURA, SUENORI, C/O HAMAMATSU PHOTONICS K.K.
Applicants: HAMAMATSU PHOTONICS KK, HAMAMATSU PHOTONICS K.K.
Application year: 1991
Main classification: H01J43
IPC codes: H01J43