Planar type cold cathode with sharp tip ends and manufacturing method therefor

Abstract: A planar type cold cathode (1) for generating electron field emission which comprises a planar cold cathode having triangular convex portions (4) and an anode (5) confronting the triangular convex portions wherein each convex portion has a sharp tip end having a radius of curvature of 0.1 µm or less. Also, a manufacturing method therefor is disclosed. In this method, sharp tip ends of the cold cathode are formed by using a normal etching technique.

Description: BACKGROUND OF THE INVENTION FIELD OF THE INVENTION The present invention generally relates to an electron source using a planar type cold cathode having tip end portions of a minute radius of curvature. DESCRIPTION OF RELATED ART Conventionally, there have been proposed a large number of cold cathodes of thin-film field emission type. Among these cathodes, a planar type cold cathode as shown in Fig. 6 (see, for example, Japanese Patent Laid-open Publication No. SHO 63-274047/1988) is said to be capable of generating electron emission at a an applied voltage of 80 V or more. As shown in Fig. 4, this cold cathode is constituted by a cold cathode 24 arranged to confront an anode 25 on the surface of an insulating substrate 23. On the end face of the cold cathode confronting the anode, there are formed a large number of triangular convex portions each having a tip end portion of a minute radius of curvature by a microfabrication technique of submicron order. The distance between the tip end portion of the convex portion provided in said cold cathode and the anode is 0.1 µm. When a voltage of 100 V or more is applied between said cold cathode thus constituted and anode, because of a small radius of curvature of the tip end portion of the cold cathode, there is developed a strong electric field of 2 x 10⁷ V/cm at the tip end of the convex portion, resulting in field emission of electron at the tip end portion. Although said planar type cold cathode has such an advantage as described above, it is necessary to make the radius of curvature at the tip end portion of the cold cathode as small as possible and to form the electrodes at the distance of submicron order. At present, however, according to the microfabrication method using the conventional photoetching technique, about 0.7 µm is the limit. Therefore, in order to perform a more microfabrication, it is necessary to use a maskless etching technique such as FIB. According to this technique, however, it is difficult to form a cold cathode having a large area, and furthermore, this technique is not suitable for putting into the practical use from the cost view-point in the manufacturing process. SUMMARY OF THE INVENTION One object of the present invention is to provide a planar type cold cathode with sharp tip ends which is capable of generating an electron beam under a relatively low voltage. Another object of the present invention is to provide a method for manufacturing planar type cold cathodes having sharp tip and portions of a minute radius of curvature equal to or less than 0.1 µm easily. A further object of the present invention is to provide a method for manufacturing planar type cold cathodes having sharp tip end portions by using the isotropic etching technique. In order to achieve these objects, according to the present invention, there is provided a planar type cold cathode for generating electron field emission which includes a planar cold cathode and an anode being formed on an insulation substrate so as to confront each other, said cold cathode having substantially triangular convex portions projected toward said anode, being characterized in that at least one of two tip ends of said each convex portion defined by the principal planes of said cold cathode, respectively, has a radius of curvature of 0.1 µm or less, and that said one tip end of said each convex portion is formed so as to protrude toward said anode more than the other tip end thereof. Since the planar type cold cathode according to the present invention has very sharp tip end portions of a radius of curvature less than 0.1 µm, it becomes possible to generate electron emission at an applied voltage lower than 100 V. Further, according to the present invention, there is provided a manufacturing method for a cold cathode comprising the following steps; a step of forming a resist film on said film of a conductive material provided on an insulating film, said resist film being comprised of two portions separated from each other and having shapes similar to those of a cold cathode having substantially triangular convex portions and an anode to be formed, respectively; a step of etching said film of a conductive material, by using the isotropic etching technique, the side etching depth thereof becomes at least more than the radius of curvature of the tip end of each triangular convex portion of said resist film; According to the present invention, the formation of said resist film can be made using the conventional microfabrication technique since it is possible to form sharp tip ends of the cold cathode having a radius of curvature of 0.1 µm or less even if tip ends of triangular convex portions of the resist film are not formed so sharp as those of the former. When the isotropic etching technique is used, the cold cathode material thin film under the resist film is etched from the both sides of the resist film tip end portion. Therefore, when side etching is effected so that the etching depth becomes at least more than the radius of curvature at the resist film tip end portion, at least the tip end portion of the upper side of the cold cathode formed under the resist film becomes of a minute radius of curvature, and by continuing the etching further, the tip end portion of the lower side thereof becomes also very minute. Further with respect to the curvature in the film thickness direction of the cold cathode tip end portion, since the tip end portion of the lower side thereof is formed projected relative to that of the upper side, the radius of curvature of the projecting portion becomes very minute in this direction. Accordingly, even without using a microfabrication technique of submicron order such as FIB, a cold cathode having a radius of curvature of less than 0.1 µm can be formed with the conventional etching technique, resulting in a planar type cold cathode markedly advantageous in respect of the manufacturing cost. When a voltage is applied between a cathode formed in this manner and an anode provided so as to confront said cathode, even with an electrode distance of more than 1 µm, there is developed a strong electric field at each sharp tip end portion of said cold cathode, resulting in a planer type cold cathode which is operable at a low voltage. BRIEF DESCRIPTION OF THE DRAWINGS These and other objects and features of the present invention will become clear from the following description taken in conjunction with the preferred embodiment thereof with reference to the accompanying drawings, in which: Fig. 1 is a perspective view of a planar type cold cathode according to a preferred embodiment of the present invention; Fig. 2 is a layout view for the cold cathode and the anode in the preferred embodiment of Fig. 1; Figs. 3 to 5 are an explanatory views for showing the manufacturing process for a planar type cold cathode in the preferred embodiment of Fig. 1; and Fig. 6 is a perspective view for the conventional planar type cold cathode. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT As shown in an enlarged scale therein, a planar cold cathode 1 has triangular convex portions 4 projected from one side edge thereof in a horizontal direction and each convex portion 4 has very sharp upper and lower tip ends 2 and 3 defined by the upper and lower principal plane thereof at the apex thereof. The upper tip end 2 is formed, according to the present invention, to have a radius of curvature of 0.1 µm or less when measured on the upper principal plane. The lower tip end 3 is formed projected more than the upper one in the forward direction. Fig. 2 is a partial perspective view showing a layout of said cold cathode 1 and an anode 5 arranged so as to confront said cathode 4. Both electrodes 1 and 5 are respectively formed on an insulation substrate 6 and both edges thereof are formed to overhang a concave portion of the substrate 6. When a voltage is applied between these electrodes with the anode side being made the higher potential, a strong electric field is generated at the tip end portion of each convex portion of the cold cathode 1 even with the electrode spacing of more than 1 µm, resulting in the field emission of electron. Figs. 3 through 5 show the manufacturing process for the planar cold cathode according to the present invention. After forming SiO₂ film 8 of 1 µm thickness on the surface of Si substrate as an insulation layer by thermal oxidization, a WSi₂ film 9 of 0.2 µm thickness for forming the electrodes 1 and 5 is deposited on the surface of said SiO₂ film 8. On the surface of this WSi₂ film 9, a resist film 11 having triangular convex portions 10 and a resist film 12 confronting said resist film 11 are formed by the photolithography technique (Fig. 3). The radius of curvature at the tip end portion of each convex portion 10 of the formed resist film 11 is about 0.5 µm. Subsequently, side etching is effected by immersing this substrate in nitro-fluoric acid for four minutes thus to conduct isotropic etching, whereby a thin film cold cathode 16 with a tip end portion 14 having a minute radius of curvature under the tip end portion 13 of the resist film 11 and having a shape of one projecting main surface 15 and a confronting anode 17 are formed simultaneously (Fig. 4). In the present preferred embodiment, a cold cathode having a tip end portion 15 of about 300 Å radius of curvature was formed. Subsequently, the resist film 18 remaining on the surface of the cold cathode 16 is removed and then, the substrate is immersed into a buffer etching solution (mixture solution of one part of HF and six parts of NH₄F) thus to effect isotropic etching of SiO₂ film 8, whereby a concave portion 20 is formed under the edge portions of the cold cathode and the anode and the tip end portions of both electrodes being formed in eaves (Fig. 5). When a voltage is applied between the cold cathode 21 and anode 22 thus formed, a strong electric field of more than 10⁷ V/cm is generated and the field emission of electron takes place from the tip end portion. It is to be noted here that the combination of electrode material and insulation material is not limited to that of WSi₂ and a material such as SiO₂, but W, Mo, W₂C, NbC, HfC which is of a high melting point and low work function and difficult to be solved in the buffer etching solution as an electrode material and a material such as glass sheet which is soluble in the buffer etching solution as an insulation substrate material may be combined. Furthermore, although the conventional photoresist material was used in the present embodiment, after depositing SiO₂ or Si₃N₄ on the surface of a cold cathode material, the material obtained by photoetching these materials may be used as a resist film. when these materials are used as resist film, it becomes possible to render the side etching amount to be 1 µm or more. When an electron source constituted so that a plurality of cold cathodes are confronted with an anode is made using the manufacturing method of the present embodiment, even with scatterings in the performance of respective cold cathodes, such scatterings are averaged on the whole, resulting in a stable electron source. EFFECT OF THE INVENTION According to the present invention, even without using a microfabrication technique of submicron order such as FIB, it becomes possible to form uniformly and reproducibly a cold cathode tip end portion having a radius of curvature of less than 0.1 µm, whereby an electron source capable of generating field emission of electron at a low voltage of less than 100 V can be obtained. By using this electron source, it becomes possible to manufacture at a low cost a high speed switching element and an image display device.

Claims: A planar type cold cathode (1) for generating electron field emission which includes a planar cold cathode (4) and an anode (5) being formed on an insulation substrate (6) so as to confront each other, said cold cathode (4) having substantially triangular convex portions projected toward said anode, being characterized in that at least one of two tip ends (2,3) of said each convex portion defined by the principal planes of said cold cathode (4) respectively, has a radius of curvature of 0.1 µm or less, and that said one tip end (2,3) said of each convex portion is formed so as to protrude toward said anode (5) more than the other tip end (2,3) thereof. A manufacturing method for a cold cathode comprising tho following steps; a step of forming a resist film (11) on a film (9) of a conductive material provided on an insulating film (8), said resist film (11) being comprised of two portions (10,12) separated from each other and having shapes similar to those of a cold cathode having substantially triangular convex portions and an anode to be formed, respectively; a step of etching said film (9) of a conductive material, by using the isotropic etching technique, the side etching depth thereof becomes at least more than the radius of curvature of the tip end of each triangular convex portion (10) of said resist film; and a step of removing said resist film. The manufacturing method as claimed in claim 2, in which each triangular convex portion of said cold cathode has two sharp tip ends (2,3) defined by the principal planes thereof, at least one of the two sharp tip ends (2,3) having a radius of curvature of 0.1 µm or less. The manufacturing method as claimed in claim 3, in which one of said two sharp tip ends (2,3) is formed so as to protrude toward said anode more than the other. The manufacturing method as claimed in claim 2. further comprising a step of removing portions of said insulation substrate (8) located under peripheries of respective triangular convex portions of said cold cathode by using the isotropic etching technique so as to make each tip end thereof overhang from the etched portion of said insulation substrate.

Inventors: KADO HIROYUKI, WATANABE MASANORI, KADO, HIROYUKI, WATANABE, MASANORI
Applicants: MATSUSHITA ELECTRIC IND CO LTD, MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
Application year: 1991
Main classification: H01J1
IPC codes: H01J3, H01J1, H01J21, H01J9