PROCESSES FOR PRODUCING HIGHLY WATER ABSORPTIVE RESINS

Abstract: The processes for producing highly water absorptive resins of the present invention comprise the folling steps: (A) suspending an aqueous solution of partially neutralized alkali metal acrylate and optionally partially neutralized acrylamido alkane sulfonate in a hydrocarbon solvent containing a surfactant having a HLB value of 3 SIMILAR 6 or 8 SIMILAR 12; (B) subjecting the mixture to inverse suspension polymerization in the presence of at least one water soluble radical polymerization initiator; (C) if necessary, separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 15 to 55 % by weight; (D) adding a crosslinking agent having two or more reactive groups such as epoxy groups, if desired, as a solution form to subject the surface of the polymer to crosslinking reaction; and optionally (E) subjecting to coagulation with the use of a coagulant in the presence of an inert solvent, whereafter drying the resultant coagulate to obtain the water absorptive resin.

Description: PROCESSES FOE POBUCING HIGHLY MATES ABSORPTIVE EESINS BACKvRQvNP QF THE IHYEHTIQH Field of the Invention The present invention relates to processes for producing highly water absorptive resins having excellent water absorbency and saline solution absorbency. More particularly, it relates to processes for producing highly water absorptive resins having a high water absorption rate and water absorptive capacity, and an excellent gel-strength. Description of the Prior Art Various water absorbing Materials such as sponge, pulp, paper and the like, are well known in the art. Also various synthetic products aade by graft polymerization of laterials containing a hydrophilic group, such as -OH, -NH 8 , -C00H, and the like, have been used conventionally. However, such water absorbing Materials, e.g. a sponge, a pulp, a paper are characterized with physical mechanise for absorbing water so that such Materials have defects in that the majority of the absorbed water can be easily squeezed out by the application of external pressure. In recent years, in order to solve these defects, synthetic water-absorptive products having particular physical and chemical mechanisms have been developed. The majority of such synthetic products are crosslinked polyacrylic acid salt, or polymethacrylic acid salt, crosslinked polyarcylic acid-methacrylic acid copolymer salt, crosslinked saponification products of starch-acrylonitrile graft copolymer, and cellulose and acrylate-grafted copolymer. Such grafted products are on the market as sanitary napkins, sanitary pads, diapers in the sanitary field, water absorbing containers in the civil and gardening field, and anti-dewdrop agents in the construction field. However, although saponificated products of starch-acrylonitrile graft copolymer has a relatively high deionized water-absorbency, the saline-solution thereof is poor. Also, it is impossible to be stored for a long time because its main component is starch. On the other hand, partially crosslinked polyacrylic acid salt has a high water absorption rate and capacity in saline solution as well as in deionized water, and it can be stored for a long period of time. Particulary, it is readily available commercially, therefore, alkali metal acrylate is used as a starting material to prepare a water absorptive resin in the present invention. As the process for polymerizing acrylic acid and alkali acrylate, there have been known various processes such as bulk polymerization, aqueous solution polymerization, spray polymerization, inverse emulsion polymerization, inverse suspension polymerization, and the like. But, in case of using the processes except for the inverse emulsion polymerization and the inverse suspension polymerization, it is difficult to remove the heat of polymerization, and the viscosity of polymerization mixture becomes too high to carry out the production of general polymers. Moreover, according to these processes it is difficult to obtain particulate polymer. An example of the inverse emulsion polymerization process is disclosed in US patent NO. 3,284,393. When, for example, acrylic acid is used as the starting material, the obtained polymer is insoluble in water and does not have such an absorbency that the polymer can be called a water absorptive resin even if it is neutralized with an alkali such as sodium hydroxide or the like. As a process for producing an acrylic acid-alkali metal acrylate polymer having a water absorbency, the inverse suspension polymerization process is mentioned in Japanese Patent Publication No. 79-30710. According to this process, a water absorptive polymer is prepared through a stable reaction by the use of a sorbitan fatty acid ester having a HLB(Hydrophilic-Lipophilic Balance) value of 3^6. The resin thus obtained has a high deionized water absorbency corresponding to 400~500 times its own weight, however, the saline solution-absorbency of said water absorptive resin is as low as 35~50 times its own weight. In US patent No.4,497,930, there is disclosed a method for producing a water absorbent polymer comprising the steps of subjecting acrylic acid and sodium acrylate to polymerzation in the presence of a sorbitan fatty acid ester having a HLB value of 3™6 as a dispersing agent, and adding a crosslinking agent with stirring in methanol to crosslink the surface of the resulting polymer. However, there is a disadvantage that the water absorptive resin prepared by this method is unsatisfactory in water absorptive capacity because the polymerization reaction is earried out at a low temperature of 70 to 75 β C to stabilize the reaction. In general, a highly water absorptive resin requires good water absorption rate, water absorptive capacity and gel-strength. These performances exhibite mutual opposing correlations with each other, therefore, other performances should be sacrificed to some extent in order to improve a certain performance. The foregoing three properties, namely the water absorptive capacity, the water absorption rate and the gel-strength in the water absorbent resin, are influenced by many factors such as polymer particle's size and shape, the kinds of crosslinking agent and dispersing agent used, CMC(Critical Micelle Concentration), polymerzation temperature, and so on. In the inverse emulsion polymerization and the inverse suspension polymerization W/0 systems, it is known that the use of a surfactant having a HLB value of 3~6 make a stable system. But according to these polymerization reactions, the resultant particles are too minute and have many hydrophobic groups in their surface, and then the particulate polymer has swollen too slowly when contacted with water. Consequently, the water absorption rate and the water absorptive capacity become deteriorated. To solve the foregoing problem when a surfactant having a HLB value of 8~12, which is known that it is much unstable in the inverse emulsion and suspension polymerization systems, is used, there is an another problem that the reaction control is difficult due to agglomeration. On the other hand, US patent No.4,340,706 discloses that a water absorbent resin suitable for usages requiring a stability in the fluid-absorbed state for a long period of time. However, even the resin obtained by said method is not sufficient in water absorption rate because it has not been surface-crosslinked. Especially, in case that the resin is prepared in a low temperature of 55~60 β C, in accordance with the said method there is a disadventage in that residual monomers are obtained in large quantities. Representative methods for improving the water absorption rate include methods by, for example, increasing the surface area of the resin(i.e. decreasing the apparent specific gravity), crosslinking the surface of particulate polymer after polymerization, or adding inorganic materials. Among the foregoing methods, the method of adding inorganic materials such as silica has an advantage in that the dispersing rate of particulate polymer is remarkably improved in accordance with preventing agglomeration of polymer particles. However, there is a disadvantage in that it is difficult to obtain the desired water absorption rate due to poor sedimentation rate of particulate polymer. Also, in case of using the method of crosslinking the surface of particulate polymer to improve the water absorption rate, there are some disadvantages in that the minute particles formed tend to blow off and to agglomerate together, and resultingly it is difficult to obtain satisfactory water absorption rate. foiOTarv nf the Invention Hereupon, the present inventors have conducted extensive studies for production of a highly water absorptive resin. As a result, it has surprisingly been found that the water absorptive resins having excellent water absorption properties can be obtained by carrying out the characteristic processes comprising the following steps : (A) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about 50 to 100% of the carboxyl group has been neutralized to its alkali metal salt and optionally partially neutralized acrylamido alkane sulfonate wherein about 50 to 100% of the sulfonic group has been neutralized to its alkali metal salt, in a hydrocarbon solvent containing a surfactant having a HLB value of 3~6 or 8~12 ; (B) subjecting the mixture to inverse suspension polymerization in the presence of at least one water soluble radical polymerization initiator ; (C) if necessary, separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 15 to 55% by weight ; (D) adding a crosslinking agent having two or more reactive groups such as epoxy groups, if desired, as a solution form dispersed, preferably in methanol, to subject the surface of the polymer to crosslinking reaction; and optionally (E) subjecting to coagulation with the use of a coagulant in the presence of an inert solvent which does not affect the water absorptive resin, whereafter drying the resultant coagulate to obtain the water absorptive resin. An object of the present invention is to provide improved processes for preparing highly water absorptive resin having excellent water absorption properties. BRIEF DESCRIPTION OF THE INVENTION In order to better understand the invention reference will be made to the accompanying drawing in which : Figure 1 is a microphotograph (X 200) of the water absorptive resin having irregular shape according to Example 27 ; and Figure 2 is a microphotograph (X 200) of the spherical water absorptive resin according to Comparative Example 26. DETAILED DESCRIPTION OF THE INVENTION According to the present invention, there are provided highly water absorptive resins and processes for preparing them. In the present invention, the polymer used includes, for example, polyacrylic acid, polymethacrylic acid, or a copolymer thereof with maleic acid, acrylamide, 2-acrylamido-2-methylpropylsulfonic acid, 2-methacryloylethane sulfonic acid, 2-hydroxyethyl methacylate, or the like in a certain proportion. The most preferred polymer is polyacrylic acid. The first preferred embodiment of the invention is a process for preparing a highly water absorptive resin, which comprises the following steps ; (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about 50 to 100% by mole of the carboxyl group has been neutralized to its alkali metal salt and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant have a HLB value 8~12 ; (b) subjecting the mixture to inverse suspension polymerization at temperatures of 75 to 95 β C ; (c) separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 35 to 55% by weight, and removing the solvent fay filtration to obtain particulate polymer ; (d) adding a crosslinking agent having three or more reactive epoxy groups which is dissolved in methanol, wherein the amount of the crosslinking agent is 0.5~2.5% by weight based on the polymer, to subject to surface-crosslinking for 1 to 2 hours at temperatures of 70 to 85°C ; and (e) washing with methanol, filtering, and drying at temperatures of 90 to 175"C. The alkali metal acrylate can be obtained by neutralizing acrylic acid with an alkali metal hydroxide such as lithium hydroxide, sodium hydroxide, potassium hydorxide and calcium hydroxide. The degree of neutralization is preferably about 50~100% by mole, more preferably about 65~80% by mole. When the neutralization degree is lower than 50% by mole, the hydroxide concentration would be decreased and the electronic density in the water would also be small and further, the penetration intensity would be decreased. Thus the desired highly water absorptive resin would not be obtainable. The concentration of the monomer thus produced, i.e., the alkali metal acrylate and the unneutralized acrylic acid, is about 20~70% by weight based on the total weight of the composition and the preferred monomer concentration is about 40~60% by weight. As the surfactant used in this invention, any surfactant having a HLB value of 8~12 and containing many hydrophilic groups may be used, and preferably sorbitan monolaurate (SPAN 20, manufactured by ICI Americas Inc., HLB value = 8.6) and Ryoto Sugar Ester S-970 R (manufactured by Mitsubishi-Kasei Food Corporation(MFC), HLB value = 9), particulary Byoto Sugar Ester S-970 R give good results. In general, in case that a surfactant having a HLB value of 8~ 12, which has more hydrophilic groups than hydrophobic groups, is used in the polymerization of the water absorptive resin, the possibility to contact with the hydrophilic monomer of the starting material is increased. As a result, the inverse emulsion polymerization system and the inverse suspension polymerization system become very unstable, therefore, the viscosity is suddenly increased due to the Trommsdorff effect and the reaction is very rapidly progressed. Consequently, it causes agglomeration of particulate polymer because of the Weigenberg effect which is a characteristic in polymeric materials and also the heat of polymerization is emitted rapidly. However, according to the present invention the disadvantageous effects as described above can be prevented and then the polymerization system becomes stable. In addition, it is unnecessary to add separately a crosslinking agent during polymerizaton, and a self-crosslinking reaction and a pseudo- crosslinking reaction take place to improve greatly the absorbency of the polymer obtained. Also, the surface of the polymer thus obtained is crosslinked with the use of a crosslinking agent having three or more reactive groups such as epoxy group in the presence of an inert solvent such as methanol, and the polymer absorbs the methanol containing the crosslinking agent and is swollen somewhat. Therefore, the crosslinking agent permeates easily into the surface of particulate polymer and resultingly the surface-crosslinking reaction takes place well, whereby the water absorption rate and gel-strength of the resin becomes improved remarkably. The water soluble radical polymerization initiator used in this invention is one well known in the art of polymer chemistry, for example, ammonium persulfate, potassium persulfate, hydrogen peroxide, and the like. The preferred water soluble radical polymerization initiator is potassium persulfate. The above-mentioned polymerization initiator may be used alone or in admixture of two or more. The hydrocarbon solvent used in the present invention is an aliphatic or aromatic hydrocarbon, which has a boiling point of 30~ 200 * C. Examples thereof are n-hexane, n-heptane, cyclohexane, and the like, and the perferred solvent is cyclohexane. The surface-crosslinking agent used is one having at least three or more reactive groups such as epoxy groups, for example, glycerol polyglycidyl ether, trimethylol propane polyglycidyl ether and sorbitol polyglycidyl ether, preferably glycerol polyglycidyl ether. In crosslinking step(d), methanol as an inert solvent is preferably used for more improving the sur ace-crosslinking effect. The process for preparation of the highly water absorptive resin according to the first preferred embodiment of the present invention is described in detail as follows : (1) Preparation of the partially neutralized alkali metal acrylate Acrylic acid is charged in a reactor equipped with a condenser, a dropping funnel and a stirrer. An alkali metal hydroxide is dissolved in water in a beaker separately to form an alkali metal hydroxide solution. The alkali metal hydroxide solution is fed dropwise to the reactor through the dropping funnel while being kept at less than 30 β C and neutralizing 50~100% by mole of the acrylic acid to produce an equivalent amount of an alkali metal acrylate having the degree of neutralization of 50™100% by mole. When the neutralization step is conduct at a temperature of over 45 β C, one of reactants could be polymerized. (2) Inverse suspension polymerization step A surfactant and a hydrocarbon solvent are charged in a reactor with a condenser having a Dean-Stark equipment, a pressure-adjusting dropping funnel and a stirrer, and then the temperature is raised to 75~95 β C. A mixture of the partially neutralized alkali metal acrylate prepared in step(l) and a water-soluble radical polymerization initiator is fed to the reactor in a small portion and polymerized completely for about an hour. (3) Azeotropic distilling step The resultant polymer contains a large amount of water so that it is difficult for the crosslinking agent to react with the surface of the polymer. Therefore, the moisture contained in the polymer is separated therefrom by azeotropic distillation to reduce the water content of the polymer to about 35 to 55% by weight. At this time, when the water content is less than 35% weight, it is uneconomic. On the other hand, when the water content is over 55% by weight, it is decreased the effect of surface-crosslinking. After thus separating the water from the polymer, the temperature of the reactor is maintained room temperature. The solvent is removed by filtration. (4) Surface-crosslinking step The polymer produced by step(3) is crosslinked by the crosslinking agent so as to improve water absorption rate and gel-strength. The polymer and the crosslinking agent dissolved in methanol are charged to a reactor equipped with a condenser, a stirrer, and a dropping funnel. At a temperature of 75 to βO'C, the surface -crosslinking reaction is carried out for 1~2 hours. The polymer thus treated is cooled to room temperature and the methanol is removed by filtration. (5) Washing and drying step To remove residual monomers, the obtained polymer is washed twice with methanol and filtered. The filtered polymer is dried at a temperature of 90 to 175 * 0 and passed through a 50-mesh wire gauze to obtain the water absorptive resin having a uniform size. The obtained resin is provided to measure the water absorption rate and the water absorptive capacity by filtering method. The second preferred embodiment of the invention is a process for preparing a highly water absorptive resin, which comprises the following steps : (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about 50 to 100% by mole of the carboxyl group has been neutralized to its alkali metal salt and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 8™12 ; (b) subjecting the mixture to inverse suspension polymerization at temperatures of 55 to 60"C ; (c) separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 15 to 45% by weight ; (d) adding a crosslinking agent having three or more reactive expoxy groups which is dissolved in methanol of 10™30% by weight based on the polymer, to subject to surface-crosslinking for 1 to 2 hours at temperatures of 70 to δδ'ϋ ; (e) cooling down to room temperature and then filtering to obtain the surface-crosslinked polymer ; and (f) subjecting to coagulation with the use of a coagulant dissolved in methanol of 3™5 times by weight based on the polymer, wherein the amount of the coagulant is 0.5™3.0% by weight based on the polymer, whereafter drying the resultant coagulate. The alkali metal acrylate, the surfactant, the water soluble radical polymerization initiator, the hydrocarbon solvent and the surface-crosslinking agent are the same as described in the foregoing first preferred embodiment of this invention. The coagulant is a proton-releasing acid such as sulfuric acid, acetic acid, nitric acid, and hydrochloric acid. The preferred coagulant is sulfuric acid. The process for preparation of the highly water absorptive resin according to the second preferred embodiment of the present invention is decribed in detail as follows : (1) Preparation of the partially neutralized alkali metal acrylate Acrylic acid is charged in a reactor equipped with a condenser, a dropping funnel and a stirrer. An alkali metal hydroxide is dissolved in water in a beaker separately to form an alkali metal hydroxide solution. The alkali metal hydroxide solution is fed dropwise to the reactor through the dropping funnel while being kept at less than 30"C and neutralizing 50™100% by mole of the acrylic acid to produce an equivalent amount of an alkali metal acrylate having the degree of neutralization of 50™100% by mole. When the neutralization step is conduct at a temperature of over 45 β C, one of reactants could be polymerized. (2) Inverse suspension polymerization step A surfactant and a hydrocarbon solvent are charged in a reactor equipped with a condenser having a Dean-Stark equipment, a pressure -adjusting dropping funnel and a stirrer, and then the temperature is raised to 55™60"C. A mixture of the partially neutralized alkali metal acrylate prepared in step(l) and a water soluble radical polymerization initiator is fed to the reactor in a small portion, and polymerized completely for about 3 hours. (3) Azeotropic distilling and surface-crosslinking step The moisture contained in the resultant polymer is separated therefrom by azeotropic distillation to reduce the water content of the polymer to about 15 to 45% by weight. At this time, when the water content is less than 15% by weight, it is uneconomic. On the other hand, when the water content is over 45% by weight, it is decreased the effect of surface-crosslinking. After thus separating the water from the polymer, the solution of the crosslinking agent dissolved in 10™30% by weight, based on the polymer, of methanol is added to the water content adjusted polymer and the surface-crosslinking reaction is carried out for an hour. The amount of the crosslinking agent is 0.1™2.0% by weight. The reactor is maintained at room temperature, and then the solvent is removed by filtration to obtain the polymer. (4) Coagulating step After 0.5™3.0% by weight of sulfuric acid as a coagulant is dissolved in 3™5 times by weight, based on the polymer, of methanol, the polymer obtained in step(3) is added thereto and stirred at room temperature. The solvent is removed by filtration to collect the coagulate. ($) Drying step The resultant coagulate is dried at 120 β C for an hour and passed through a 40-mesh wire gauze to obtain the water absorptive resin. The obtained resin is provided to measure the water absorption rate by filtering method. The third preferred embodiment of this invention is a process for preparing a highly water absorptive resin, which comprises the following steps : (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about 50 to 100% by mole of the carboxyl group has been neutralized to its alkali metal salt and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 3~6 ; (b) subjecting the mixture to inverse suspension polymerization ; (c) separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 15 to 50% by weight ; (d) adding a crosslinking agent having three or more reactive epoxy groups in an amount of 0.01™5% by weight based on the polymer, to subject to surface-crosslinking ; and (e) subjecting the surface-crosslinked polymer to coagulation with the use of a coagulant in the presence of an inert solvent, wherein the amount of the coagulant is 0.01™5% by weight based on the polymer. The alkali metal acrylate and the water soluble radical polymerization initiator are the same as described in the foregoing first preferred embodiment. As the surfactant, there may be used any surfactant having a HLB value of 3™6, and includes, for example, sorbitan fatty acid esters such as sorbitan monostearate and sorbitan monolaurate, and cellulose esters such as ethyl cellulose, benzyl cellulose, ethylhydroxy cellulose, cellulose acetate, cellulose butyrate and cellulose acetate butyrate. Particulary, the sorbitan fatty acid esters give good results. The surfactant is preferably used in an amount of 0.5™15% by weight based on the monomer used. As the hydrocarbon solvent used in the inverse suspension polymerization, there may be used an aliphatic or aromatic hydrocarbon having a boiling point of 30™200"C, which includes n-hexane, n-heptane, cyclohexane, and the like. The preferred solvent is n-hexane. The above-mentioned solvents may be used alone or in admixture of two or more. The solvent is used in an amount of preferably 0.1™ 50 parts by weight, more preferably 0.5™30 parts by weight, based on 1 part by weight of the monomer used. The moisture-separating process may be carried out during or after polymerization. When the water content of the polymer is 20™50% by weight based on the polymer, it is advantageous in the surface-crosslinking reaction. On the other hand, when the water content is out of the range, the water absorptive capacity and the water absorption rate are lowered to a unsirable level. The surface-crosslinking agent used in this invention is water soluble, and has at least three or more reactive groups such as epoxy group which can react with the corboxyl or carboxylate in a molecule. As the crosslinking agent, there may be used polyglycidyl ethers, chloroepoxy compounds, polyaldehydes, or the like. The amount of the surface-crosslinking agent is generally 0.01~5% by weight based on the polymer. When the amount is less than 0.01% by weight, the effect of the surface-crosslinking agent is insignificant. On the other hand, the amount is over 5% by weight, the crosslinking density is increased and resultlingly the water absorptive capacity is decreased. Examples of the inert solvent used in the coagulation step(e) are a lower alcohol such as methanol, ethanol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, t-butyl alcohol or octyl alcohol, or a polyol such as ethylene glycol, propyleπe glycol, glycerin or diethylene glycol. The preferred inert solvent is methanol. The amount thereof is 50™500% by weight, preferably 100™300% by weight based on the polymer. As the coagulant, there may be used a proton-releasing acid, which includes, for example, sulfuric acid, acetic acid, nitric acid, hydrochloric acid, and the like. The preferred coagulant is sulfuric acid. The amount thereof depends on the kind of coagulant and the solvent used, and is generally 0.01™3% by weight based on the inert solvent used. The fourth preferred embodiment of this invention is a process for preparing a highly water absorptive resin, which comprises the following steps : (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about 50 to 100% by mole of the carboxyl group has been neutralized to its alkali metal salt and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant have a HLB value 3~δ ; (b) subjecting the mixture to inverse suspension polymerization ; (c) adding a crosslinking agent having two or more reactive groups in an amount of 0.01™5% by weight based on the polymer, to subject to surface-crosslinking ; and (d) subjecting the surface-crosslinked polymer to coagulation with the use of a coagulant in the presence of an inert solvent, wherein the amount of the coagulant is 0.01™3% by weight based on the solvent. The alkali metal acrylate, the surfactant, the hydrocarbon solvent, the water soluble radical polymerization initiator, the coagulant and the inert solvent used in the coagulation are the same as described in the foregoing third preferred embodiment. The surface-crosslinking agent used more reactive groups such as epoxy group which can react with the carboxyl or carboxylate groups in a molecule. Examples of the crosslinking agent are polyglycidyl ethers such as glycerol diglycidyl ether, chloroepoxy compounds such as epichlorohydrin and -methylchlorohydrin, polyaldehydes such as glyoxal and glutaraldehyde, polyols such as glycerol and ethylene glycol, polyamines such as ethylenediamine, and so on. The preferred crosslinking agent is polyglycidyl ethers. The amount thereof is the same as described in the forregoing third preferred embodiment. The fifth preferred embodiment of this invention is a process for preparing a highly water absorptive resin, which comprises the following steps : (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about 50 to 100% by mole of the carboxyl group has been neutralized to its alkali metal salt, which contains 1™5% by weight of partially neutralized acrylamido alkane sulfonate wherein about 50 to 100% by mole of the sulfonic group has been neutralized to its alkali metal salt, and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 8™12 ; (b) subjecting the mixture to inverse suspension polymerization at temperatures of 40 to 80"C ; (c) separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 15 to 45% by weight ; (d) adding a crosslinking agent having three or more epoxy groups which is dissolved in methanol, wherein the amount of the crosslinking agent is 0.1™2.0% by weight based on the polymer, to subject to surface-crosslinking for an hour ; and (e) subjecting to coagulation with the use of a coagulant in the presence of an inert solvent, whereafter drying the resultant coagulate to obtain the water absorptive resin. The alkali metal acrylate, the hydrocarbon solvent, the water soluble radical polymerization initiator, the surface-crosslinking agent, the coagulant and the inert solvent are the same as described in the foregoing first preferred embodiment, except that the amount of the crosslinking agent is preferably 0.1™2% by weight based on the polymer. According to this invention, the 50™100% by mole - neutralized acrylamido alkane sulfonate which is represented by the following formula CH 2 =CHCNHCZ2(CH 2 )nS0 3 Y(wherein Z is H or CE- ; n is an integer of 0 to 2 ; and Y is Na, K or Li) is used to improve the water absorption rate. The process for preparation of the highly water absorptive resin according to the fifth preferred embodiment of the present invention is described in detail as follows : (1) Preparation of the partially neutralized alkali metal acrylate Acrylic acid is charged in a reactor equipped with a condenser, a dropping funnel and a stirrer. An alkali metal hydroxide is dissolved in water in a beaker separately to form an alkali metal hydroxide solution. The alkali metal hydroxide solution is fed dropwise to the reactor through the dropping funnel while being kept at less than 30"C and neutralizing 50™100% by mole of the acrylic acid to produce an equivalent amount of an alkali metal acrylate having the degree of neutralization of 50™100% by mole. When the neutralization step is conduct at a temperature of over 45 * C, one of reactants could be polymerized. (2) Inverse suspension polymerization step A surfactant and a hydrocarbon solvent are charged in a reactor equipped with a condenser having a Dean-Stark equipment, a dropping funnel, a stirrer and a nitrogen gas inlet pipe, and then the temperature is raised to 40™80 * C. A mixture of the partially neutralized alkali metal acrylate prepared in step(l), a partially neutralized alkali metal arylamido sulfonate, and a water soluble radical polymerization is fed to the reactor in a small portion and polymerized completely. (3) Azeotropic distilling and surface-crosslinking step The moisture contained in the polymer is separated therefrom by azeotropic distillation to reduce the water content of the polymer to 15™45% by weight. After thus separating the water from the polymer, a solution of the crosslinking agent dissolved in a little methanol is added to the water content adjusted polymer and the surface-crosslinking reaction is carried out for an hour. At this time, the amount of the crosslinking agent is preferably 0.1™2.0% by weight based on the polymer. (4) Coagulating and Drying step The polymer obtained by filtration after the crosslinking reaction, is suspended in methanol, and sulfuric acid is dropped thereto, to coagulate the polymer. The coagulate is collected by filtration and dried to obtain the water absorptive resin. The obtained resin is provided to measure the water absorption rate by filtering method using a 80-mesh wire gauze. The sixth preferred embodiment of the invention is a process for preparing a highly water absorptive resin, which comprises the following steps : (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about 50 to 100% by mole of the carboxyl group has been neutralized to its alkali metal salt, which contains 1™5% by weight of partially neutralized acrylamido alkane sulfonate wherein about 50 to 100% by mole of the sulfonic group has been neutralized to its alkali metal salt, and at least one water soluble radical polymerzation initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 3™6 ; (b) subjecting the mixture to inverse suspension polymerization at temperatures of 40 to 80 β C ; (c) separating the moisture from the preduced polymer by azeotropic distillation to reduce the water content to about 15 to 45% weight ; (d) adding a crosslinking agent having three or more reactive epoxy groups which is dissolved in methanol, wherein the amount of the crosslinking agent is 0.1™2.0% by weight based on the polymer, to subject to surface-crosslinking for an hour ; and (e) subjecting to coagulation with the use of a coagulant in the presence of an inert solvent, whereafter drying the resultant coagulate to obtain the water absorptive resin. The alkali metal acrylate, the hydrocarbon solvent, the surfactant solvent, the water soluble radical polymerization initiator, the coagulant and the inert solvent are the same as described in the foregoing third preferred embodiment. And, the acrylamido alkane sulfonate is the same as described in the foreoging fifth preferred embodiment. As the surface-crosslinking agent, there may be used one that has three or more reactive epoxy groups, for example, glycerol polyglycidyl ether, trimethylol propane polyglycidyl ether or sorbitol polyglycidyl ether. The amount of the crosslinking agent is 0.1~2% by weight based on the polymer. water absorptive resin according to the sixth preferred embodiment is the same as described in the foregoing fifth preferred embodiment. The seventh preferred embodiment of the invention is a process for preparing a highly water absorptive resin, which comprises the following steps : (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about 50 to 100% by mole of the carboxyl group has been neutralized to its alkali metal salt and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 8™12 ; (b) subjecting the mixture to inverse suspension polymerization while raising the internal temperature of the reactor successively to 70 * 0, to 60™67"C, to 70°C, and then to 75"C, to undergo phase-transition ; (c) during or after the polymerization, separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 15 to 55% by weight, and then filtering to remove the solvent ; (d) adding a crosslinking agent having three or more reactive epoxy groups which is dissolved in methanol, wherein the amount of the crosslinking agent is 0.005™15% by weight based on the produced polymer, to subject surface-crosslinking for 1~2 hours at temperatures of 70 to 85 * C ; and (e) washing with methanol, filtering, and drying at temperatures of 90 to 175"C to obtain the water absorptive resin. The present inventors have found a surprising fact that a highly water absorptive resin can be obtained in an irregular shape by carrying out polymerization with use of a surfactant having a HLB value of 8~12 which is generally considered to be unsuitable for inverse suspension polymerization system and inverse emulsion polymerization system, while raising the reaction temperature successively to 70°C, to 60™67 β C, to 70 β C and to 75"C, t undergo phase-transition. Irregular shape resin thus prepared has an increased-surface area, and then its water absorption rate and gel-strength become improved. Also, in this polymerizing system the viscosity of resin is suddenly increased by developing the Trommsdorff effect to conduct phase-transition. It is possible to explain this phenomenon, as follows : (1) one by first occuring phase-transition from a system having greater mechanical force by agitation than viscous force to another system wherein mechanical force and viscous force are balanced, and followed by phase-transition to the system having greater mechanical force by agitation than viscous force again. (2) one by first occuring phase-transition from a system (namely W/0 system) wherein main phase is hydrophobic, to a water and oil equilibrium phase system, and followed by phase-transition to the hydrophobic system (W/0 system) again. As a result of this phase-transition effect the water absorptive capacity is further improved due to chemical self-crosslinking in particles during polymerization, and physical pseudo-crosslinking by trapped entanglement of main chain. Moreover, as a result of raising the polymerization temperature successively as mentioned above the shape of polymer is not spherical but irregular. In this preferred embodiment, the alkali metal acrylate, the hydrocarbon solvent, the water soluble radical polymerization initiator and the surface-crosslinking agent are the same as described in the foregoing first preferred embodiment and the crosslinking agent is preferably 0.005™15% by weight based agent on the polymer. The process for preparation of the highly water absorptive resin according to the seventh preferred embodiment of the present invention is described in detail as follows : (1) Preparation of the artially neutralized alkali metal acrylate Acrylic acid is charged in a reactor equipped with a condenser, a dropping funnel and a stirrer. An alkali metal hydroxide is dissolved in water in a beaker separately to form an alkali metal hydroxide solution. The alkali metal hydroxide solution is fed dropwise to the reactor through the dropping funnel while being kept at less than 30"C and neutralizing 50™i00% by mole of the acrylic acid to produce an equivalent amount of an alkali metal acrylate having the degree of neutralization of 50™100% by mole. When the neutralization step is conduct at a temperature of over 45 β C, one of reactants could be polymerized. (2) Inverse suspension polymerization step A surfactant and a hydrocarbon solvent are charged in a reactor with the condenser having a Dean-Stark equipment, a presure-adjusting dropping funnel and a stirrer, and then the temperature of the reactor is raised to 70™80 * C. A mixture of the partially neutralized alkali metal acrylate prepared in step(l) and a water soluble radical polymerization initiator is incrementally charged to the reactor. The temperature is raised successively to 70 β C, to 60™67'C, to 70 β C, and then to 75 β C to form a clot of gel and consequently irregular shapes are obtained due to phase-transition. (3) Azeotropic distilling step The resultant polymer contains a large amount of water so that it is difficult for the crosslinking agent to react at the surface of the polymer. Therefore, the moisture contained in the polymer is separated therefrom by azeotropic distillation to reduce the water content of the polymer to about 15 to 55% by weight. At this time, when the water content is less than 15% weight, it is uneconomic. On the other hand, when the water content is over 55% by weight, it is decreased the effect of surface-crosslinking. After thus separating the water from the polymer, the internal temperature of the reactor is maintained room temperature. The solvent is removed by filtration to obtain the polymer. (4) Surface-crosslinking step The water content adjusted polymer produced by step(3) is crosslinked by the crosslinking agent so as to improve water absorption rate and gel-strength. The polymer having a water content of 15™55% by weight and the solution of the crosslinking agent and methanol are charged to a reactor equipped with a condenser, a stirrer, and a dropping funnel. At a temperature of 75 to 80°C, the surface-crosslinking reaction is carried out for 1™ 2 hours. The polymer thus treated is cooled to room temperature and the methanol is removed by filtering method. (5) Washing and drying step To remove residual monomers, the obtained polyier is washed twice with methanol and filtered. The filtered polymer is dried at a temperature of 90 to 175 β C and passed through a 40-mesh wire gauze to obtain the water absorptive resin in particles having a uniform size. The obtained resin is provided to measure the water absorption rate and the water absorptive capacity by filtering method. The present invention is described in detail by the following examples, but it should be noted that the invention is not limited by these examples. The term "the water absorptive capacity used in the present invention means a value determined according to the following procedure : To 2,000g of deionized water is added lg of the dried water absorptive resin, and water is absorbed by the polymer for 30 minutes, after which the polymer is collected by filtration with a 80-mesh metallic wire gauze, the volume of the swollen polymer obtained is measured, and the value is taken as the deionized water absorption capacity. The saline solution-absorption rate is a value (g/g) calculated from the weight of the saline solution(0.9% by weight aqueous sodium chloride solution) which is absorbed by the polymer for, respectively, 1, 3 and 5 minutes. Example 1 200g of cyclohexane and 2.0g of Ryoto Sugar Ester S-970* (manufactured by Mitsubishi-Kasei Food corporation) were charged in a 1jβ four-necked round-bottomed flask equipped with a stirrer, a condenser having a Dean-Stark equipment, a pressure adjusting -dropping funnel and a nitrogen gas inlet pipe. The nitrogen gas was introduced into the flask, so as to exhaust oxygen in the flask, and then the flask was heated to 85*C. Separately, 36g of acrylic acid was charged in another 1Jβ four- necked round-bottomed flask equipped with a stirrer, a condenser and a dropping funnel. While cooling the flask to room temperature, 65g of an aqueous sodium hydroxide solution prepared by dissolving 15g of sodium hydroxide in 50g of distilled water was slowly fed dropwise thereto to prepare an aqueous solution of 75% neutralized sodium acrylate. After 0.32g of potassium persulfate was dissolved thoroughly in 3.88g of distilled water in a lOOrafi beaker, it was mixed with the previously prepared sodium acrylate solution and stirred. The mixture was slowly fed dropwise to the flask containing cyclohexane and the surfactant through the pressure adjusting-dropping funnel over 20 minutes, and then the reaction mixture was held at 85 β C for an hour to conduct the polymerization. At the completion of the polymerization, 28g of water was removed from the produced polymer by azeotropic distillation to reduce the water content to 40% by weight. After cooling it to room temperature, the cyclohexane was removed by filtration, and the resulting polymer was charged in a flask equipped with a condenser, a stirrer and a dropping funnel. 0.375g of Epok 812 (commercial name, glycerol polyglycidyl ether) was dissolved in 200g of methanol in a 300m-. beaker and stirred, and the resulting solution was added to the flask containing produced polymer through a dropping funnel. After heating it to 80 β C, the solution was reacted for an hour. And then, the flask was cooled to reduce the inside temperature of the flask to room temperature, and the solvent was removed by filtration. The resulting polymer was washed twice with 40g of methanol, filtered, and dried at 120 β C. The dried polymer was passed through a 20-mesh wire gauze to obtain a highly water absorptive resin in particles having a uniform size. The results are shown in Table 1. Example 2 A water absorptive resin was prepared in the same manner as described in Example 1 except that 0.25g of Epok 812 was used as the crosslinking agent. The results are shown in Table 1. Example 3 A water absorptive resin was prepared in the same manner as described in Example 1 except that 0.425g of Epok 812 was used as the crosslinking agent. The results are shown in Table 1. Example 4 A water absorptive resin was prepared in the same manner as described in Example 1 except that 0.625g of Epok 812 was used as the crosslinking agent. The results are shown in Table 1. Coiparative Exanple 1 A water absorptive resin was prepared in the same manner as described in Example 1 except that the polymer was directly dried without removing of water. The results are shown in Table 1. Comparative Exanple 2 A water absorptive resin was prepared in the same manner as described in Example 1 except that 28g of water was seperated from the polymer to reduce the water content to 40% by weight, followed by the drying step. The results are shown in Table 1. Comparative Example 3 A water absorptive resin was prepared in the same manner as described in Example 1 except that the crosslinking agent was not used in the surface-crosslinking step. The results are shown in Table 1. T g-bl g 1 < Note > * : O : Excellent : Normal Poor Example 5 150g of cyclohexane and 2.0g of Ryoto Sugar Ester S-970 R were charged in a 1J6 four-necked round-bottomed flask equipped with a stirrer, a condenser having a Dean-Stark equipment, a pressure adjusting-dropping funnel and a nitrogen gas inlet pipe. The nitrogen gas was introduced into the flask so as to remove oxygen in the flask, and then the flask was heated to 60°C. Separately, 36g of acrylic acid was charged in another 1£ four- necked round-bottomed flask equipped with a stirrer, a condenser and a dropping funnel. While cooling the flask to room temperature, 65g of an aqueous sodium hydroxide solution prepared by dissolving 15g of sodium hydroxide in 50g of distilled water was slowly fed dropwise thereto to prepare 75% neutralized sodium acrylate aqueous solution. After 0.32g of potassium persulfate was dissolved thoroughly in 3.88g of distilled water in a lOOmfi beaker, it was lixed with the previously prepared sodium acrylate solution and stirred. The mixture was slowly added to the flask containing cyclohexane and the surfactant through the pressure adjusting-dropping funnel over an hour, and then it was held at 60 β C for 3 hours to conduct the polymerization. At the completion of the polymerization, 28g of water was separated from the produced polymer by azeotropic distillation to reduce the water content to 40% by weight. 0.2g of Epok 812 was dissolved in lOg of methanol in another lOOmβ beaker, the resulting solution was added to the polymer through the pressure adjusting-dropping funnel, and then the reaction was conducted for an hour. After cooling it to room temperature, the solvent was removed to obtain the polymer. 350g of methanol and 1.25g of sulfuric acid were charged in a δOOmfi beaker and stirred. The polymer was added thereto, and stirred to coagulate. After the coagulation, methanol was removed by filtration. The obtained product was dried at 120°C for an hour, and passed through a 20-mesh wire gauze to obtain a water absorptive resin in particles having a uniform size. The results are shown in Table 2. Example 6 A water absorptive resin was prepared in the same manner as described in Example 5 except that 2.0g of sulfuric acid was used in the coagulation step. The results are shown in Table 2. Example 7 A water absorptive resin was prepared in the same lanner as described in Example 5 except that 200g of methanol was used in the coagulation step. The results are shown in Table 2. Example 8 A water absorptive resin was prepared in the same manner as described in Example 5 except that 0.3g of Epok 812 was used as the crosslinking agent. The results are shown in Table 2. Comparative Example 4 A water absorptive resin was prepared in the same method as described in Example 5 except that 28g of water was first separated from the polymer to reduce the water content to 40% by weight, followed by the drying step. The results are shown in Table 2. Comparative Example 5 A water absorptive resin was prepared in the same method as described in Example 5 except that sulfuric acid was not used in the coagulation step. The results are shown in Table 2. Comparative Example 6 A water absorptive resin was prepared in the same method as described in Example 5 except that Epok 812 was not used. The results are shown in Table 2. Tab le 2 Exampl s 9~12 200m. of n-hexane and 1.5g of sorbitan monostearate were charged in a 500m£ of four-necked round-bottomed flask equipped with a stirrer, a condenser having a Dean-Stark equipment, a dropping funnel and a nitrogen gas inlet pipe, and the flask was heated to 65"C. Separately, 30g of acrylic acid was charged in another flask and neutralized with aqueous sodium hydroxide solution prepared by dissolving 13.4g of sodium hydroxide in 39g of water. The concentration of the aqueous monomer in the solution was 45% and the amount of water contained was 55%. After O.lg of potassium persulfate was dissolved therein, the solution was slowly fed dropwise to the previously prepared reaction flask through a dropping funnel over 30 minutes. The nitrogen gas was introduced into the flask during the polymerization. Thus obtained polymer was dehydrolyzed by azeotropic distillation to reduce the water content to 20%, 30%, 40% and 50% respectively, and then an aqueous solution prepared by dissolving 0.08g of polyglycerol polyglycidyl ether in lmfi of water was added thereto, and stirred at 70"C for 3 hours. At the completion of the polymerization, n-hexane was removed from the polymer, and 200g of methanol and 0.2g of sulfuric acid were added thereto to coagulate the polymer. After coagulation, methanol was removed, and the polymer was dried in vacuum over at 80°C to obtain a highly water absorptive resin. Example 13 A highly water absorptive resin was prepared in the same manner as described in Example 9 except that as follows : 1.5g of ethyl cellulose T-50(manufactured by Hercules Incorporated) was used instead of sorbitan monostearate. After the polymerization, the content of water was reduced to 40% by azeotropic distillation. And then, O.lg of polyglycerol polyglycidyl ether dissolved in lmfi of water was added the reaction flask, and stirred for 2 hours at 70"C. At the completion of the reaction, n-hexane was removed from the polymer, and 230g of methanol and 0.5g of sulfuric acid were added thereto to coagulate the polymer. Example 14 A highly water absorptive resin was prepared in the same manner as described in Example 13 except that as follows : The concentration of aqueous monomer was 35%. After the polymerization, 0.15g of polyglycerol polyglycidyl ether dissolved in lmfi of water was added to the reaction flask and stirred for 3 hours at 75"C. n-Hexane was removed from the polymer, and 250g of methanol and 0.4g of sulfuric acid were added thereto to coagulate the polymer. Comparative Examples 7™10 Comparative samples were prepared in the same manner as described in Example 9 except that as follows : The content of water was reduced to 10%(Comparative Example 7), 15%(Comparative Example 8), 55%(Comparative Example 9) and 60%(Comparative Example 10) by weight, respectively. After the polymerization, O.lg of polyglycerol polyglycidyl ether dissolved in lmfi of water was added to the reaction flask, and stirred for 2 hours at 70"C. n-Hexane was removed from the polymer, and 200g of methanol and 0.4g of sulfuric acid were added thereto to coagulate the polymer. Comparative Example 11 Comparative sample was prepared in the same manner as described in Example 9 except that as follows : The content of water was reduced to 30% by weight. O.lg of polyglycerol polyglycidyl ether dissolved in lmfi of water was added to the reaction flask, and stirred for 3 hours at 70"C. Comparative Example 12 Comparative sample was prepared in the same manner as described in Example 13 except that as follows : The concentration of an aqueous monomer was 35%, and the content of water after polymerization was 40% by weight. O.lg of polyglycerol polyglycidyl ether dissolved in lmfi of water was added to the reaction flask, and stirred for 3 hours at 75"C. The absorption characteristics of the highly water absorptive resins obtained in Examples 9™14 and the comparative samples obtained in Comparative Examples 7™12 are shown in Table 3. Table 3 obviously shows that the polymer of the present invention has excellent resistance to salts, and a high absorption rate in saline solution. Tat)le 3 Examples 15™17 200mfi of n-hexane and 15g of sorbitan monostearate were charged in a 500mfi four-necked round-bottomed flask equipped with a stirrer, a condenser having a Dean-Stark equipment, dropping funnel and a nitrogen gas inlet pipe, and the flask was heated to 65"C. Separately, 30g of acrylic acid was charged in another flask and neutralized with an aqueous sodium hydroxide solution prepared by dissolving 13.4g of sodium hydroxide in 39g of water. The concentration of the aqueous monomer in the solution was 45% by weight and the amount of water contained was 55% by weight. O.lg of potassium persulfate was dissolved therein, and the resulting solution was added to the reaction flask through the dropping funnel over about 30 minutes. The nitrogen gas was introduced to the reaction flask through the dropping funnel during polymerization, and then the obtained solution was standed for 2 hours at 65 β C to complete the polymerization. 0.08g of ethylene glycol diglycidyl ether dissolved in lmfi of water was added to the reaction flask and standed for 2 hours at 70"C. After the reaction was completed, n- hexane was removed. The obtained polymer was chagred in the beakers containing, respectively, 200g/0.2g, 200g/0.5g and 200g/1.0g of methanol and sulfuric acid to coagulate the polymer. After coagulation, methanol was removed, and the resulted polymer was dried in vacuum oven at 80"C to obtain a highly water absorptive resin. Example 18 A water absorptive resin was prepared in the same manner as described in Example 15 except that l.Og of ethyl cellulose T-50 was used instead of sorbitan monostearate. After polymerization was completed, 0.05g of glycerol diglycidyl ether dissolved in lmfi of water was added to the reaction flask, and stirred for 2 hours at 70"C. n-Hexane was removed, and the obtained polymer was added to the beaker containing 250g of methanol and 0.4g of sulfuric acid to coagulate the polymer. Methanol was removed, and the resulting polymer was dried in vacuum oven at 80"C to obtain a highly water absorptive resin. Example 19 A water absorptive resin was prepared in the same manner as described in Example 18 except that the concentration of monomer in aqueous monomer solution was adjusted to 35%. After polymerization, 0.2g of polyethylene glycol diglycidyl ether (n=9) dissolved in lmfi of water was added to the reaction flask and stirred over 3 hours at 75 β C. n-Hexane was removed, and the polymer was added to the beaker including 230g of methanol and O.δg of sulfuric acid to coagulate the polymer. Methanol was removed, and the resulting polymer was dried in vacuum oven at 80"C to obtain a highly water absorptive resin. Example 20 A water absorptive resin was prepared in the same manner as described in Example 18 except that the 1.2g of ethyl cellulose N- 100 (manufactured by Hercules Incorporated) was used instead of ethyl cellulose T-50. After polymerization, 0.09g of ethylene glycol diglycidyl ether dissolved in lmfi of water was added to the reaction flask, and stirred for 2 hours at 70"C. n-Hexane was removed, and the polymer was added to the beaker including 200g of methanol and l.Og of sulfuric acid to coagulate the polymer. Methanol was removed, and the resulting polymer was dried in vacuum oven at 80°C to obtain a highly water absorptive resin. Comparative Examples 13™16 Water absorptive resins were prepared in the same manner as described in Example 15 except that as follows. After polymerization, 0.08g of ethylene glycol diglycidyl ether dissolved in lmfi of water was added to the reaction flask, and the concentration of monomer was adjusted to 35%. After polymerization, 0.3g of polyethylene glycol diglycidyl ether (n=9) dissolved in lmfi of water was added to the reaction flask, and stirred for 3 hours at 75"C. Comparative Example 17 A water absorptive resin was prepared in the same manner as described in Example 20 except that O.Olg of ethylene glycol diglycidyl ether dissolved in lmfi of water was added to the reaction flask, and stirred for 2 hours at 75°C. The absorption characteristics of the highly water absorptive resins obtained in Examples 15™20 and the samples obtained in Comparative Examples 13™17 are shown in Table 4. Table 4 obviously shows that the polymer of the present invention has excellent resistance to salts and the high absorption rate in saline solution. Table 4 Example 21 160g of cyclohexane and 2.4g of Ryoto Sugar Ester S-970 R (HLB = 9) were charged in a four-necked round-bottomed flask equipped with a stirrer, a condenser having a Dean-Stark equipment, a dropping 5 -funnel and a nitrogen gas inlet pipe, and the flask was heated to 60°C. 80g of 7δ% neutralized aqueous sodium acrylate solution (4δ% by weight) was mixed with the aqueous solution neutralized 2g of 2-acrylamido-2-methyl-l-propanesulfonic acid by 0.44g of sodium hydroxide and the aqueous solution including O.lg 10 of potassium persulfate, and the resulting solution was slowly fed dropwise in the reaction flask. And then polymerization was held for about 2 hours at 70"C. The water was separated from the produced polymer to reduce the water content to 40% by weight. 0.12g of Epok 812 R dissolved lδ in a little methanol was added to the polymer and refluxed for an hour. Thus obtained polymer was filtered and again dissolved in methanol. A little sulfuric acid was fed to coagulate the polymer. The coagulated polymer was filtered again, dried, and passed through 20 a 20-mesh wire gauze to obtain a highly water absorptive resin in particles having a uniform size. Example 22 A water absorptive resin was prepared in the same manner as described in Example 21 except that 2g of 2-acrylamido-2-methyl-l- propane sulfonic acid neutralized by 0.22g of sodium hydroxide was used. Example 23 A water absorptive resin was prepared in the same manner as described in Example 21 except that 3g of 2-acrylamido-2-methyl-l- propane sulfonic acid neutralized by 0.66g of sodium hydroxide was used. Comparative Example 18 A water absorptive resin was prepared in the same manner as described in Example 21 except that 2-acrylamido-2-methyl-l-propane sulfonic acid was not used. Comparative Example 19 A water absorptive resin was prepared in the same manner as described in Example 21 except that the polymer was not coagulated by sulfuric acid. Comparative Example 20 A water absorptive resin was prepared in the same manner as described in Example 21 except that 2-acrylamido-2-methyl-l-propane sulfonic acid was not used and the polymer was not coagulated by sulfuric acid. The absorptive capacities (in a 0.9% sodium chloride aqueous solution for 1 minute) of the water absorptive resins prepared in Examples 21™23 and Comparative Examples 18™20 are shown in Table 5. Table (g/g polymer) Example 24 160g of n-hexane and 1.4g of Ryoto Sugar Ester S-370F R (HLB value=3) were charged in a four-necked round-bottomed flask equipped with a stirrer, a condenser having a Dean-Stark equipment, a δ9 - dropping funnel and a nitrogen gas inlet pipe, and the flask was heated to δO°C. 80g of 7δ% neutralized aqueous sodium acrylate solution (4δ% by weight) was mixed with aqueous solution from neutralizing 2g of 2-acrylamido-2-methyl-l-propane sulfonic acid by 0.44g of sodium hydroxide and aqueous solution including O.lg of potassium persulfate, and the resulting solution was slowly fed dropwise in the reaction flask. Polymerization was conducted for about 2 hours. Water was separated from the produced polymer to reduce the water content to 40% by weight. After 0.12g of EPOK 812 R dissolved in a little methanol was added to the reaction flask, and the solution was refluxed for an hour. The obtained polymer was filtered, again dissolved in methanol, and coagulated by dropping of sulfuric acid. The coagulated product was filtered, dried, and passed through a 20-mesh wire gauze to obtain a water absorptive resin. Example 25 A water absorptive resin was prepared in the same manner as described in Example 24 except that 2g of 2-acrylamido-2-methyl-l- propane sulfonic acid neutralized by 0.22g of sodium hydroxide was used. Example 26 A water absorptive resin was prepared in the same manner as described in Example 24 except that 3g of 2-acrylamido-2-methyl-l- propane sulfonic acid neutralized by 0.66g of sodium hydroxide was used. Comparative Example 21 A water absorptive resin was prepared in the same manner as described in Example 24 except that 2-acrylamido-2-methyl-l-propane sulfonic acid was not used. Comparative Example 22 A comparative sample was prepared in the same manner as described in Example 24 except that the polymer was not coagulated by sulfuric acid. Comparative Example 23 A Comparative sample was prepared in the same manner as described in Example 24 except that 2-acrylamido-2-methyl-l-propane sulfonic acid was not used and the polymer was not coagulated by sulfuric acid. The absorptive capacities (in a 0.9% sodium chloride aqueous solution for 1 minute) of the resins prepared in Examples 24™26 and Comparative Examples 21™23 is shown in Table 6. Table (g/g polymer) Example 27 200g of cyclohexane and 2.0g of Ryoto Sugar Ester S-970 R were charged in a II four-necked round-bottomed flask equipped with a stirrer, a condenser having a Dean-Stark equipment, a pressure adjusting-dropping funnel and a nitrogen gas inlet pipe. The nitrogen gas was introduced into the flask so as to remove oxygen in the flask, and then the flask was heated to 75"C in oil bath. Separately, 36g of acrylic acid was charged in another 1£ four-necked round-bottomed flask equipped with a stirrer, a condenser and a dropping funnel. While cooling it to room temperature, 6δg of aqueous sodium hydroxide solution prepared by dissolving lδg of sodium hydroxide in 50g of distilled water was slowly fed dropwise thereto to prepare an aqueous solution of 7δ% neutralized sodium acrylate. After 0.12g of potassium persulfate was dissolved thoroughly in 3.88g of distilled water in a lOOmfi beaker, it was mixed with the previously prepared sodium acrylate solution and stirred. The mixture was rapidly added to the flask containing cyclohexane and the surfactant through the pressure adjusting-dropping funnel over about 10 minutes. After keeping the internal temperature of the flask to 70 * C, the temperature was changed successively to 64 β C, to 70"C again, and to 75"C(The temperature of the oil both was as follows : 85"C → 73 * 0 → 85"C → 88 β C), to undergo phase-transition. Thereafter, the temperature of the oil bath was held to 90"C for an hour to complete the polymerization, 28g of water was separated from the produced polymer by azeotropic distillation to reduce the water content to 40% by weight. After cooling the flask to room temperature, cyclohexane was filtered off, and the polymer was introduced to the flask equipped with a condenser, stirrer and dropping funnel. 0.375g of Epok 812 and 200g of methanol were mixed in a 300mfi beaker. After the mixture was added to the flask containing the polymer through a dropping funnel, it was reacted at 80"C for an hour. Thereafter, the temperature was cooled to room temperature, and the solution was filtered to obtain the polymer. The obtained polymer was washed with 40g of methanol, filtered, and dried to obtain a water absorptive resin having an irregular shape. And the dried water absorptive resin of irregular shapes was passed through a 20-mesh wire gauze to obtain a water absorptive resin in particles having a uniform size. The results are shown in Table 7. The microphotograph of Example 27 is shown in Figure 1. Exa ple 28 A water absorptive resin was produced in the same manner as described in Example 27 except that 0.25g of Epok 812 was used. The results are shown in Table 7. Example 29 A water absorptive resin was produced in the same manner as described in Example 27 except that 0.425g of Epok 812 was used. The results are shown in Table 7. Example 30 δ A water absorptive resin was produced in the same manner as described in Example 27 except that 0.62δg of Epok 812 was used. The results are shown in Table 7. Example 31 10 A water absorptive resin was produced in the same manner as described in Example 27 except that 36g of acrylic acid was neutralized to 70% by adding 14g of sodium hydroxide and 47.Ig of distilled water in the polymerization step. The results are shown in Table 7. lδ Example 32 A water absorptive resin was produced in the same manner as described in Example 27 except that 36g of acrylic acid was neutralized to 6δ% by adding 13g of sodium hydroxide and 46.9g of 20 distilled water in the polymerization step. The results are shown in Table 7. Example 33 A water absorptive resin was produced in the same manner as described in Example 27 except that 36g of acrylic acid was neutralized to 60% by adding 12g of sodium hydroxide and 46.6g of distilled water in the polymerization step. The results are shown in Table 7. Comparative Example 24 A comparative sample was produced in the same manner as described in Example 27 except that 28g of water was first separated from the polymer to reduced the water content to 40% by weight, followed by the drying step. The results are shown in Table 7. Comparative Example 25 A comparative sample was produced in the same manner as described in Example 27 except that 28g of water was first separated from the polymer to reduced the water content to 40% by weight, and the polymer was washed twice with 40g of methanol, followed by the drying step. The results are shown in Table 7. Comparative Example 26 A comparative sample was produced in the same manner as described in Example 27 except that the temperature of oil bath was maintained to 65 * C during the polymerization step, The results are shown in Table 7 and the microphotograph is shown in Figure 2. Comparative Example 27 A comparative sample was produced in the same manner as described in Example 33 except that 28g of water was first separated from the polymer to reduce the water content to 40% weight, followed by the drying step. The results are shown in Table 7.

Claims: WHAT IS CLAIMED IS ! 1. A process for producing a highyl water absorptive resin, which comprises (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about δO to 100% by mole of the carboxyl group has been neutralized to its alkali metal salt and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 8™12 ; (b) subjecting the mixture to inverse suspension polymerization at temperatures of 7δ to 95°C ; (c) separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 35 to 5δ% by weight, and removing the solvent by filtration to obtain particulate polymer ; (d) adding a crosslinking agent having three or more reactive epoxy groups which is dissolved in methanol, wherein the amount of the corsslinking agent is 0.5™2.5% by weight based on the polymer, to subject to surface-crosslinking for 1 to 2 hours at temperatures of 70 to 85 β C ; and (e) washing with methanol, filtering, and drying at temperatures of 90 to 17δ β C. 2. The process according to Claim 1, wherein the surfactant is sorbitan monolaurate or Ryoto Sugar Ester S-970 R . 3. The process according to Claim 1, wherein the hydrocarbon solvent is selected from the group consisting of n-hexane, n-heptane and cyclohexane. 4. The process according to Claims 1 or 3, wherein the hydrocarbon solvent is cyclohexane. 5. The process according to Claim 1, wherein the water soluble radical polymerization initiator is selected from the group consisting of ammonium persulfate, potassium persulfate and hydrogen peroxide. 6. The process according to Claims 1 or 5, wherein the water soluble radical polymerization initiator is potassium persulfate. 7. The process according to Claim 1, wherein the crosslinking agent is selected from the group consisting of glycerol polyglycidyl ether, trimethylol propane polyglycidyl ether and sorbitol polyglycidyl ether. 8. The process according to Claim 1, wherein the partially neutralized alkali metal acrylate is prepared fay addition of an alkali metal hydroxide such as sodium hydroxide, lithium hydroxide or potassium hydroxide. 10 9. The process for producing a highly water absorptive resin, which comprises (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about δO to 100% by mole of the carboxyl lδ group has been neutralized to its alkali metal salt and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 8™12 ; (b) subjecting the mixture to inverse suspension polymerization at temperatures of 55 to 60"C ; 20 (c) separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 15 to 45% by weight ; (d) adding a crosslinking agent having three or more reactive epoxy groups which is dissolved in methanol of 10™30% by weight based on the polymer wherein the amount of the crosslinking agent is 5 0.1™2.0% by weight based on the polymer, to subject to surface- crosslinking for 1 to 2 hours at temperatures of 70 to 8δ"C ; (e) cooling down to room temperature and then filtering to obtain the surface-crosslinked polymer ; and (f) subjecting to coagulation with the use of a coagulant 10 dissolved in methanol of 3™5 times by weight based on the polymer, wherein the amount of the coagulant is 0.δ™3.0% by weight based on the polymer, whereafter drying the resultant coagulate to obtain the water absorptive resin. lδ 10. The process according to Claim 9, wherein the surfactant is sorbitan monolaurate or Ryoto Sugar Ester S-970 R . 11. The process according to Claim 9, wherein the hydrocarbon solvent is selected from the group consisting of n-hexane, n-heptane 0 and cyclohexane. 12. The process according to Claims 9 or 11, wherein the hydrocarbon solvent is cyclohexane. 13. The process according to Claim 9, wherein the water soluble δ radical polymerization initiator is selected from the group consisting of ammonium persulfate, potassium persulfate and hydrogen peroxide. 14. The process according to Claims 9 or 13, wherein the water 0 soluble radical polymerization initiator is potassium persulfate. lδ. The process according to Claim 9, wherein the crosslinking agent is selected from the group consisting of glycerol polyglycidyl ether, trimethylol propane polyglycidyl ether and sorbitol polyglycidyl 5 ether. 16. The process according to Claim 9, wherein the partially neutralized alkali metal acrylate is prepared by addition of an alkali metal hydroxide such as sodium hydroxide, lithium hydroxide 0 or potassium hydroxide. 17. The process according to Claim 9, wherein the coagulant is a proton-releasing acid selected from the group consisting of sulfuric acid, acetic acid, nitric acid, and hydrochloric acid, preferably sulfuric acid. δ 18. A process for producing a highly water absorptive resin, which comprises (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about δO to 100% by mole of the 0 carboxyl group has been neutralized to its alkali metal salt and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 3™6 ; (b) subjecting the mixture to inverse suspension polymerization ; (c) separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 20 to 50% by weight ; (d) adding a crosslinking agent having three or more reactive epoxy groups in an amount of 0.01™5% by weight based on the polymer, to suject to surface-crosslinking ; and (e) subjecting the surface-crosslinked polymer to coagulation with the use of a coagulant in the presence of an inert solvent, wherein the amount of the coagulant is 0.01™5% by weigt based on the polymer. 5 19. The process according to Claim 18, wherein the surfactant is selected from the group consisting of sorbitan monostearate, sorbitan monolaurate, ethyl cellulose, benzyl cellulose, ethylhydroxy cellulose, cellulose acetate, cellulose butyrate and cellulose acetate butyrate. 10 20. The process according to Claims 18, wherein the hydrocarbon solvent is selected from the group consisting of n-hexane, n-heptane and cyclohexane. 21. The process according to Claims 18 or 20, wherein the lδ hydrocarbon solvent is n-hexane. 22. The process according to Claim 18, wherein the water soluble radical polymerization initiator is selected from the group consisting of ammonium persulfate, potassium persulfate and hydrogen peroxide. 20 23. The process according to Claims 18 or 22, wherein the water soluble radical polymerization initiator is potassium persulfate. 24. The process according to Claim 18, wherein the crosslinking agent is polyglycidyl ether, chloroepoxy compound or polyaldehyde. 25. The process according to Claim 18, wherein the partially neutralized alkali metal acrylate is prepared by addition of an alkali metal hydroxide such as sodium hydroxide, lithium hydroxide or potassium hydroxide. 26. The process according to Claim 18, wherein the coagulant is a proton-releasing acid which is selected from the group consisting of sulfuric acid, acetic acid, nitric acid, and hydrochloric acid, preferably sulfuric acid. 27. The process according to Claim 18, wherein the inert solvent is a lower alcohol such as methanol, ethanol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, t-butyl alcohol or octyl alcohol, or a polyol such as ethylene glycol, propylene glycol, glycerin or diethylene glycol, preferably methanol, and the amount thereof is 50™500% by weight based on the polymer. 28. A process for producing a highly water absorptive resin, which comprises (a) suspending an aqueous monomer solution of partially neutralized alkali metal acrylate wherein about 50 to 100% by mole of the 5 carboxyl group has been neutralized to its alkali metal salt and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 3™6 ; (b) subjecting the mixture to inverse suspension polymerization ; (c) adding a crosslinking agent having two or more reactive groups 10 in an amount of 0.01™δ% by weight based on the polymer, to subject to surface-crosslinking ; and (d) subjecting the surface-crosslinked polymer to coagulation with the use of a coagulant in the presence of an inert solvent, wherein the amount of the coagulant is 0.01™3% by weight based on the solvent. lδ 29. The process according to Claim 28, wherein the surfactant is selected from the group consisting of sorbitan monostearate, sorbitan monolaurate, ethyl cellulose, benzyl cellulose, ethylhydroxy cellulose, cellulose acetate, cellulose butyrate and cellulose acetate butyrate. 30. The process according to Claim 28, wherein the hydrocarbon solvent is selected from the group consisting of n-hexane, n-heptane and cyclohexane. δ 31. The process according to Claims 28 or 30, wherein the hydrocarbon solvent is n-hexane. 32. The process according to Claim 28, wherein the water soluble radical polymerization initiator is selected from the group consisting of ammonium persulfate, potassium persulfate and hydrogen peroxide. 33. The process according to Claims 28 or 32, wherein the water- soluble radical polymerization initiator is potassium persulfate. 34. The process according to Claim 28, wherein the crosslinking agent is glycerol polyglycidyl ether, chloroepoxy compound, polyaldehyde, polyamine or polyol. 35. The process according to Claim 28, wherein the partially neutralized alkali metal acrylate is prepared by addition of an alkali metal hydroxide such as sodium hydroxide, lithium hydroxide or potassium hydroxide. 36. The process according to Claim 28, wherein the coagulant is a proton-releasing acid selected from the group consisting of sulfuric acid, acetic acid, nitric acid, and hydrochloric acid, preferably sulfuric acid. 37. The process according to Claim 28, wherein the inert solvent is a lower alcohol such as methanol, ethanol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, t-butyl alcohol or octyl alcohol, or a polyol such as ethylene glycol, propylene glycol, glycerin or diethylene glycol, preferably methanol, and the amount thereof is 50™500% by weight based on the polymer. 38. A process for producing a highly water absorptive resin, which comprises (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherien about 50 to 100% by mole of the carboxyl group has been neutralized to its alkali metal salt, which contains 1™5% by weight of partially neutralized acrylamido alkane sulfonate wherein about 50 to 100% by mole of the sulfonic group has been neutralized to its alkali metal salt, and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 8™12 ; (b) subjecting the mixture to inverse suspension polymerization at temperatures of 40 to 80°C ; (c) separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 15 to 45% by weight ; (d) adding a crosslinking agent having three or more epoxy groups which is dissolved in methanol, wherein the amount of the crosslinking agent is 0.1™2.0% by weight based on the polymer, to subject to surface-crosslinking for an hour ; and (e) subjecting to coagulation with the use of a coagulant in the presence of an inert solvent, whereafter drying the resultant coagulate to obtain the water absorptive resin. 39. The process according to Claim 38, wherein the surfactant is sorbitan monolaurate or Ryoto Sugar Ester S-970 R . 40. The process according to Claim 38, wherein the hydrocarbon solvent is selected from the group consisting of n-hexane, n-heptane and cyclohexane. 41. The process according to Claims 38 or 40, wherein the hydrocarbon solvent is cyclohexane. 42. The process according to Claim 38, wherein the water soluble radical polymerization initiator is selected from the group consisting of ammonium persulfate, potassium persulfate and hydrogen peroxide. 43. The process according to Claims 38 or 42, wherein the water soluble radical polymerization initiator is potassium persulfate. 44. The process according to Claim 38, wherein the crosslinking agent is selected from the group consisting of glycerol polyglycidyl ether, trimethylol propane polyglycidyl ether and sorbitol polyglycidyl ether. 4δ. The process according to Claim 38, wherein the partially neutralized alkali metal acrylate is prepared by addition of an alkali metal hydroxide such as sodium hydroxide, lithium hydroxide or potassium hydroxide. 46. The process according to Claim 38, wherein the coagulant is a proton-releasing acid selected from the group consisting of sulfuric acid, acetic acid, nitric acid, and hydrochloric acid, preferably sulfuric acid. δ 47. The process according to Claim 38, wherein the inert solvent is a lower alcohol such as methanol, ethanol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, t-butyl alcohol or octyl alcohol, or a polyol such as ethylene glycol, propylene glycol, glycerin or diethylene glycol, preferably methanol, and the amount thereof is δ0™500% by weight based on the polymer. 48. The process according to Claim 38, wherein the acrylamido alkane sulfonate is represented by the following formula wherein Z is H or CH 8 ; n is an integer of 0 to 2 ; and Y is Na, K or Li. 49. A process for producing a highly water absorptive resin, which comprises (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about 50 to 100% by mole of the carboxyl group has been neutralized to its alkali metal salt, which contains 1™5% by weight of partially neutralized acrylamido alkane sulfonate wherein about 50 to 100% by mole of the sulfonic group has been neutralized to its alkali metal salt, and at least one water soluble radical polymerzation initiator, in a hydrocarbon solvent containing a surfactant having HLB value of 3™6 ; (b) subjecting the mixture to inverse suspension polymerization at temperatures of 40 to 80 * C ; (c) separating the moisture from the preduced polymer by azeotropic distillation to reduce the water content to about 15 to 45% weight ; (d) adding a crosslinking agent having three or more reactive epoxy groups which is dissolved in methanol, wherein the amount of the crosslinking agent is 0.1™2.0% by weight based on the polymer, to subject to surface-crosslinking for an hour ; and (e) subjecting to coagulation with the use of a coagulant in the presence of an inert solvent, whereafter drying the resultant coagulate to obtain the water absorptive resin. 50. The process according to Claim 49, wherein the surfactant is selected from the group consisting of sorbitan monostearate, sorbitan monolaurate, ethyl cellulose, benzyl cellulose, ethylhydroxy cellulose, cellulose acetate, cellulose butyrate and cellulose acetate butyrate. 51. The process according to Claim 49, wherein the hydrocarbon solvent is selected from the group consisting of n-hexane, n-heptane and cyclohexane. 52. The process according to Claims 49 or 51, wherein the hydrocarbon solvent is n-hexane. 53. The process according to Claim 49, wherein the water soluble radical polymerization initiator is selected from the group consisting of ammonium persulfate, potassium persulfate and hydrogen peroxide. 54. The process according to Claims 49 or 53, wherein the water soluble radical polymerization initiator is potassium persulfate. 55. The process according to Claim 49, wherein the crosslinking agent is selected from the group consisting of glycerol polyglycidyl ether, trimethylol propane polyglycidyl ether and sorbitol polyglycidyl ether. 56. The process according to Claim 49, wherein the partially neutralized alkali metal acrylate is prepared by addition of an alkali metal hydroxide such as sodium hydroxide, lithium hydroxide or potassium hydroxide. 5 57. The process according to Claim 49, wherein the coagulant is a proton-releasing acid selected from the group consisting of sulfuric acid, acetic acid, nitric acid, and hydrochloric acid, preferably sulfuric acid. 10 58. The process according to Claim 49, wherein the inert solvent is a lower alcohol such as methanol, ethanol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, t-butyl alcohol or octyl alcohol, or a polyol such as ethylene glycol, propylene glycol, glycerin or diethylene glycol, preferably methanol, and the amount lδ thereof is δ0™500% by weight based on the polymer. 59. The process according to Claim 49, wherein the acrylamido alkane sulfonate is represented by the following formula 20 wherein Z is H or CH 3 ; n is an integer of 0 to 2 ; and Y is Na, K or Li. 60. A process for producing a highly water absorptive amorphous resin, which comprises (a) suspending an aqueous solution of partially neutralized alkali metal acrylate wherein about 50 to 100% by mole of the carboxyl 5 group has been neutralized to its alkali metal salt and at least one water soluble radical polymerization initiator, in a hydrocarbon solvent containing a surfactant having a HLB value of 8™12 ; (b) subjecting the mixture to inerse suspension polymerization while raising the internal temperature of the reactor successively to 70 β C, 10 to 60~67 * C, to 70"C, and then to 75"C, to undergo phase-transition ; (c) during or after the polymerization, separating the moisture from the produced polymer by azeotropic distillation to reduce the water content to about 15 to 5δ% by weight, and filtering to remove the solvent ; lδ (d) adding a crosslinking agent having three or more reactive epoxy groups which is dissolved in methanol, wherein the amount of the crosslinking agent is 0.00δ™lδ% by weight based on the produced polymer, to subject surface-crosslinking for 1~2 hours at temperatures 70 to 85 * C ; and 0 (e) washing with methanol, filtering, and drying at temperatures of 90 to 17δ"C to obtain the water absorptive resin. 61. The process according to Claim 60, wherein the surfactant is sorbitan monolaurate or Ryoto Sugar Ester S-970 R . 62. The process according to Claim 60, wherein the hydrocarbon solvent is selected from the group consisting of n-hexane, n-heptane and cyclohexane. 63. The process according to Claims 60 or 62, wherein the hydrocarbon solvent is cyclohexane. 10 64. The process according to Claim 60, wherein the water soluble radical polymerization initiator is selected from the group consisting of ammonium persulfate, potassium persulfate and hydrogen peroxide. lδ 6δ. The process according to Claim 60, wherein the water soluble radical polymerization initiator is potassium persulfate. 66. The process according to Claim 60, wherein the crosslinking agent is selected from the group consisting of glycerol polyglycidyl 20 ether, trimethylol propane polyglycidyl ether and sorbitol polyglycidyl ether. 67. The process according to Claim 60, wherein the partially neutralized alkali metal acrylate is prepared by addition of an alkali metal hydroxide such as sodium hydroxide, lithium hydroxide or potassium hydroxide.

Inventors: CHANG TAE HWAN, CHOI SOO BUM, KIM MYUNG JOONG, LEE HYUNG MAN, CHANG, TAE, HWAN, CHOI, SOO, BUM, KIM, MYUNG, JOONG, LEE, HYUNG, MAN
Applicants: LUCKY LTD, LUCKY, LTD.
Application year: 1990
Main classification: C08F2
IPC codes: A61L15, C08F2, C08F8, C08F20, C08F120, C08F220