PROCESS FOR MAKING STRUCTURAL AGGREGATE PIGMENTS

Abstract: Process for manufacturing of structural aggregate pigment products with intrinsically built-in functional properties, from aqueous dispersions of particulate matter treated with in-situ formed complex functional microgels with rapid formation kinetics.

Description: PROCESS FOR MAKING STUCTURAL AGGREGATE PIGMENTS BACKGROUND OP THE INVENTION 1. Field of the invention This invention relates to complex (multi-component) func tional microgels synthesized in the presence of a foreign, quan titatively predominant, particulate matter which is essentiall non-reactive therewith. Specifically, this invention relates to a process for th manufacture of novel structural aggregate pigment products fro particulate matter treated with complex functional microgels. The complex functional microgels employed, characterized b instantaneous (ultrarapid) formation kinetics, are synthesize in situ from subcolloidal reactive silico-aluminate and simila hydrosols and bivalent and multi-valent inorganic salts and/o organic, cationically active, chemical compounds with at leas two reactive groups in each molecule. 2. Discussion of the Relevant Art The scope of prior art relating to the synthesis an practical applications both of continuous and discrete gel obtained by interaction of alkali-metal silicates with sodiu aluminate, soluble metal salts and/or free acids in differen proportions and combinations is simply enormous, involving many thousands of patented gel products. Most of these products differ from each other only in mino details, such as pH conditions, reagent concentrations, sequenc of reagent additions, thermal regimes or particular variation in the otherwise very similar preparation procedures. Yet these seemingly minor differences may bring about improved, o even novel, material or performance properties of the resultan end products, whose applications encompass such different field as catalysis, pharmaceuticals, adhesives, water treatment, io exchange, dehumidification of gases or soil conditioning. The above can probably be comprehended best by considerin that colloids are the lowest-rank systems known in nature equip ped with "memory." As such, they "remember" their history i chronological detail and react accordingly in terms of thei resultant properties and functional behavior. As a consequence any intentional or accidental deviation from an establishe synthesis procedure or reaction conditions will inescapabl cause certain differences, mostly quantitative but sometime profoundly qualitative, in the constitution and/or functiona properties of the resultant colloidal systems. In the following, certain general fields of manufacture an utilization of various types of gels shall be discussed in som detail using examples found in the literature. While continuou single and mixed gels (mechanical blends of two or more separat gels) are inherently foreign to the principal idea of the pres ent invention, they will be included in the general discussio for the sake of better clarity. In-situ formation of silica or εilico-alu inate gels i aqueous media for the purpose of surface coating of miner particles has been utilized commercially for many years. F example, virtually all titanium dioxide pigments on the mark are coated with a more or less dense layer of silica, or silic aluminate, gels deposited in situ by a controlled interacti between relatively highly concentrated solutions of sodi silicate and appropriate gel-setting agents such as sulfuric hydrochloric acids, ammonium sulfate, alum or sodium aluminat in aqueous dispersions of the pigment. However, the surface co tings mentioned represent continuous gels which are fundamenta ly different from the instantaneously in-situ formed micropart culate gels (microgels) used in practicing the present inventi developed by the Applicant and disclosed in co-pending pate application (Serial No. 07/350,468 ; Filed May 11, 1989 ) Moreover, because of the slow formation kinetics and continuo structure of gels used in surface coating of titanium dioxi pigments in accordance with the present art, excessive unco trollable cementation of individual particles into very abrasi oversized aggregates can not be avoided. This particle aggreg tion is by far the most undesirable side effect of surface coa ing with continuous gels, having as a rule strongly pronounc cementing properties, since too close a proximity of individu titanium dioxide particles is most detrimental to their ligh scattering efficacy. As a consequence, expensive fluid-ener comminution, and/or cumbersome ball milling, must be additiona ly employed. U.S. Patent 3,726,000 to * Wildt, relating to the use in-situ formed continuous alumino-silicate gels as intrins cements toward the preparation of composite pigments, may considered as typical of the general prior art in this area technology dating back for over half a century. Many oth intrinsic cementing media have also been used for the sa purpose, e.g., sodium silicate and aluminum chloride in U. Patent No. 2,176,876 to Alessandroni, aliphatic acid in U. Patent No. 3,453,131 to Fadner, ethylenediamine and citric ac in U.S. Patent No. 4,075,030 to Bundy, urea-formaldehyde U.S. Patent No. 4,346,178 to Econo ou, or silicon tetrachlo ide in WO 87/00544 to Jones. Wildt's composite pigments were intended for latex-pai applications in which the resultant excessive aggregate hardne (abrasiveness) , restricting or even prohibiting the use of the pigments in paper filling and coating, does not constitute real disadvantage. Principal gel compositions and experiment procedures for in-situ formation of continuous gel cements di closed in the patent to Wildt, are identical to those utiliz commercially for many decades toward surface coating of titani dioxide pigments mentioned previously. It should be pointed o in this context that while a certain controlled level of resid al particle cementation (permanent aggregation) is quite esse tial to synthesis of composite pigments, any permanent aggreg tion is totally undesirable when continuous gels are used f surface coating of titanium dioxide pigments. Unfortunatel all procedures of the present art relying on the use of contin ous gels toward pigment aggregation or surface coating are lac ing inherent mechanism allowing one to exercise effective co trol over the extent, or patterns, of the residual cementati of individual particles. Continuous gels with particle-immobilizing and cementi functions were synthesized according to Wildt by an interacti between sodium silicate and aluminum sulfate in aqueous dispe sions of particulate raw materials used for preparation of co posite pigments, using relatively high concentrations of g forming reagents. The particulate raw materials mentioned co sisted of titanium dioxide as the principal optically-active i gredient, as well as coarse-particle-size, very abrasive, ca cined clays (Engelhard's Satintone No.l or No.4) and/or coar delaminated clay as extenders. The procedure described involv several independent critical processing steps, such as heati of the reaction medium (to speed up the formation of continuo gel) , alkaline pH adjustments, and long digestion periods (las ing from 30 to 60 minutes) followed by additional acidic pH a justments. To convert the resultant reacted, dried, solidifie very hard "cake" into " particulate form suitable for use composite pigment in latex paints, expensive fluid-energy comm nution was again necessary. The concept of immobilization of individual particles titanium dioxide pigments and extenders (e.g., calcined clay relative to each other is unquestionably valid and advantageo for latex paints and other related applications. However, t detrimental fractionation of pigmentary components and selecti particle aggregation of Ti0 2 /Ti0 2 and extender/extender type c not be avoided in composite pigments prepared in accordance wit the patent to Wildt because of the slow kinetics of the floccu lation process employed. As a consequence, the resultant config urations of aggregated particles are not conducive to efficien light scattering. This has been indeed verified experimentally composite pigments made in accordance with procedures set fort in the patent to Wildt having significantly poorer optical per formance in paper filling and coating applications than analog ous blends of identical titanium dioxide and calcined clay use in loose (non-aggregated) state. Hoffmann, in U.S. Patent 3,476,692, describes the prepara tion of a "silicomagnesium-aluminate-hydrate" gel (antacid) fo use in treatment of gastric hyperacidity. In particular, th above invention pertains to a silicomagnesium-aluminate-hydrat gel certain properties of which are improved compared to thos of other patented antacid products of virtually identical compo sitions. It should be emphasized rather strongly, however, tha the terminology used routinely in colloidal-technologica descriptions leaves much to be desired. For example, Hoffmann' so-called silicomagnesium-aluminate-hydrate gel is factually mechanical blend of separately prepared silico-aluminate gel an a magnesium hydroxide gel, hence, fundamentally different fro true complex gels used in practicing the present invention. I specific terms, Hoffmann's antacid gel was prepared by mixin concentrated solutions of sodium silicate and an aluminum sal under alkaline conditions for extended periods of time, e.g., 3 minutes, to form a solidified silico-aluminate cogel. Thi cogel was subsequently crushed and homogenized into a flowabl pulp, into which a concentrated solution of magnesium sulfat was introduced gradually over a period of time lasting 3 hours As a consequence, the in-situ precipitated magnesium hydroxid hydrate became mechanically, though intimately, dispersed withi the previously fluidized pulp of the continuous silico-aluminat cogel. Inorganic anion-exchangers and a process for their synthesi are disclosed by Duwell in U.S. Patent No. 3,002,932. The abov ion exchangers are prepared by "coprecipitating mixe hydrated oxides of a pair of homolomorphic metals chosen fro the group consisting of aluminum, silicon, titanium, zinc, an zirconium, the lower-valent member of said pair being present i major amount, in an aqueous medium at a pH in the range of abou pH 5 to 7, drying the aqueous mixture at a temperature belo 150°C, and washing the dried mixture with water to remov soluble impurities therefrom." The above technology, as quoted is based again on physical mixtures of separately formed gel rather than true complex microgels made up of intrinsicall chemically bound complex macromolecules. U.S. Patent No. 4,239,615 to Tu is typical of a vast grou of patents pertaining to the manufacture and use of zeolites i catalytic cracking of hydrocarbon charges (crude oils) . Al such zeolite catalysts are based in principle on variou modifications and extensions of continuous silico-aluminat cogels described extensively in textbook literature. It i because of the "memory" effects associated with colloida systems, mentioned previously, that such endless varieties o related gel products with material or functional-performanc differences of practically significant magnitudes can b synthesized with the aid of only two principal ingredients namely, sodium silicate and sodium aluminate (or aluminu sulfate) . As documented amply in everyday industrial experience relatively small differences in the preparation, handling o post-treatment of such gels, the incorporation of variou transient or permanent adjuvants notwithstanding, will ofte result in significant modification of such important produc features as abrasion resistance, catalytic activity an selectivity, inhibition resistance or pore-size distribution. In addition to using silica-alumina cogels as cracking catalyst precursors, Tu also employed certain specific brand o anionic polyacrylamide (transient adjuvant) to modify th mechanical structure of catalyst matrix. Accordingly, after subsequent burnout of the organic substance occluded in th latter matrix, Tu was able.to obtain a more favorable pore-siz distribution. As far as purely chemical functions of th anionic polyacrylamide with regard to catalyst formation ar concerned, Tu cautiously offers the following hypothesi proposed also in other similar patents: "it is believed that th anionic form chemically react with the silica-alumina ge framework, rather than being physically dispersed in the gel and thus contributes to the desired pore structure formation. A well known fact is, however, that concentrated solutions o strongly alkaline reagents used without exceptions in th synthesis of silica-alumina gels for catalyst precurso immediately coagulate virtually all organic water-solubl polymers available commercially, indicated clearly by phas separation. The overwhelming likelihood is, therefore, that t polyacrylamide adjuvant mentioned above was de facto disperse mechanically in the gel, much in the same way though perhaps no as intimately as the in-situ formed molecularly precipitate magnesium hydroxide hydrate in Hoffmann's silico-aluminat antacid-gel matrix described in U.S. Patent No. 3,476,692. far as zeolites' reactivity on a molecular level is concerned small amounts of metallic cations such as magnesium or calciu ions can be accepted indeed into the zeolite matrix, albeit b reversible ion-exchange mechanism rather than (irreversible chemical reaction. Dumoulin in U.S. Patent No. 4,247,420 and Tu in U.S Patent No. 4,239,615, discussed previously, describe the use o auxiliary extraneous disperse phase(s) in the preparation o catalyst precursor gels. These particulate materials, us mainly as diluents or catalyst-matrix modifiers, are select from among natural or synthetic zeolite powders and/or kaol clays. Embedded in the continuous gel body, the relati proportion of these auxiliary particulates is restricted as rule to less than 25% of the total mass of the catalyst. Kaliski in U.S. Patent No. 3,484,271 describes the formati of functional (release) coatings on moving paper webs by in-situ interaction between consecutively applied separa solutions of organic anionic and cationic compounds with least two functional groups in each molecule. These releas coatings are made in the form of continuous, totally impervious gel films devoid of any particulate occlusions. As a matter o fact, a particulate matter embedded in such films would destro more or less completely these films' useful release properties. U.S. Patent No. 2,974,108 to Alexander discloses synthesis o stable alumino-silicate aquasols (hydrosols) with ion-exchang capacities equivalent to those of better zeolites, and also ver good antisoiling properties. These aquasols are prepared wit the aid of rather intricate thermal regimes and time-consumin procedures, using silicic acid (rather than straight alkali metal silicate, or quaternary ammonium silicate, used in prac ticing the present invention) and sodium aluminate as the prin cipal reagents. According to Alexander, the end product contain preferably from 5% to 20% of substantially spheroidal porou particles suspended in an aqueous medium with pH ranging betwee 5 and 10, the preferred diameter of aquasol particles rangin from 10 to 50 milimicron (nanometer) and particle porosity fro 10% to 70%. Most importantly, however, the aquasols (hydrosols according to Alexander are end products in themselves and chemi cally non reactive, whereas the hydrosols used in practicing th present invention are short-lived intermediate products charac terized by a high level of chemical reactivity. Additional comparisons with the prior art will be mad hereinafter, wherever applicable. It should be noted, however that in reviewing the existing art Applicant is not aware of an references pertaining to systems that are true complex gels with all principal molecular constituents being chemically boun within the same complex macromolecules, as differentiated fro purely physical mixtures of two or more separate gels. In parti cular, no references have been found in the literature pertain ing to complex, multicomponent, rapidly forming, micro-particu late gels (microgels) used in practicing the present inventio or conditions under which these microgels can be synthesize and/or utilized. More specifically, no references whatsoeve were found in the literature regarding the use of complex micro gels toward the manufacture of structural aggregate, single component or multiple-component, pigment products for pape filling and coating, or any other application for that matter. SUMMARY OF THE INVENTION Process for the manufacture of single-component and multi ple-component structural aggregate pigment products made by procedure comprising the steps of: (a) blending separate aqueous solutions of hydrosol-formin reagents, one of which contains alkali-metal, or quaternar ammonium, silicate and the other one of which contains alkali metal aluminate and/or alkali-metal zincate, with an aqueou dispersion of quantitatively predominant particulate matter optionally containing water soluble functional adjuvants, t form in-situ a subcolloidal reactive (polymeric) hydrosol; (b) blending an aqueous solution containing at least one bi valent or multivalent inorganic salt and/or organic cationicall active chemical compound with two or more reactive groups i each molecule with the system obtained in step (a) to crosslin said hydrosol and form in situ complex functional microgel wherein all particulate matter present in the system become flocculated instantaneously, indiscriminately and completely t form a structural aggregate pigment product; and (c) optionally, dewatering the system from step (b) , e.g., b filtration, centrifugation, drying, or combination thereof, an pulverizing the resultant filter cake to obtain a structural ag gregate pigment product with the desired particle-size distribu tion. It is important to emphasize strongly the optional charac ter of the finishing operations in step (c) , such as filtration, drying and pulverization, in that the flocculated product fro step (b) can be used directly "as is," for example, as a fille for paper making. In a similar fashion, the flocculated produc from step (b) may be filtered and rinsed, to remove electrolyt by-products from microgel formation, and then repulped mechani cally for use in paper filling or special coating applications. With particulate matter being the quantitatively predominan phase, the relative weight content of the in-situ formed comple functional microgels in the resultant structural aggregate sing le-component and multiple-component pigment products synthesize with the aid of the above method ranges merely from 0.5% to 10%, as determined by ashing. DESCRIPTION OF THE PREFERRED EMBODIMENTS In the preferred form of practicing the present invention novel structural aggregate pigment products for paper filling paper coating, and many other applications, are manufactured by synthesizing in situ complex functional microgels in aqueou dispersions of quantitatively predominant particulate matter also containing water-soluble functional adjuvants. The princi pal particulate raw materials for the manufacture of structura aggregate pigments include a variety of mineral and organi pigment products of the present art, as well as ultrafine whit or colorless mineral and/or organic particles with dimension ranging from 0.01 Jim to 0.1 pm e.s.d. (equivalent spherica diameter) which are too small to be classified as white pigment in thέ conventional sense due to low light-scattering efficacy Upon practicing the present invention, however, these ultrafin particles become aggregated into assemblies with sufficientl large dimensions to render them optically active in a commercia sense. The- above, and other, particulate raw materials for th manufacture of structural aggregate pigments mentioned shall b described in more detail hereinafter. Structural aggregate pigments may be made from a singl principal particulate species, e.g., kaolin clay. Such pigment shall be called further on "simple aggregate pigments," i differentiation to "composite pigments" which shall relate t structural aggregate pigments made from two or more differen principal particulate mineral species. The primary purpose of the in-situ formed complex microgel is to induce instantaneous (ultrarapid) , indiscriminate an complete flocculation of all disperse phases present in th reaction medium. Flocculation phenomena play fundamental an indispensable roles in the manufacture of all structura aggregate pigments. The flocculation processes of the presen art, however, are slow, selective (rather than indiscriminate) , and incomplete. As a consequence, these processes are not wel suited for the manufacture of even simple structural aggregat pigment products free of significant performance deficiencies, and are even less suited for the manufacture of more exotic com posite aggregate pigments assembled from physically, chemicall and colloidally highly differentiated particulate components. Particulate raw materials for the manufacture of such exotic composite pigments encompass, for example, various naturally oc¬ curring and synthetic minerals with particle sizes ranging fro 0.01 um to 10 m e.s.d., non-film-forming (high glass-transition temperature) organic emulsion polymers with particle diameters ranging from 0.03 ^ιm to 1 ^i , latex adhesives with particle diameters ranging from 0.07 ^am to 0.3 ^ιm, and color pigments with particle diameters even smaller than 0.01 jum. The enormous quantitative and qualitative heterogeneity of above furnishes are realized best when considering that the linear dimensions of individual particles span over 3 orders of magnitude, hence, the corresponding volumes or weights of these particles may differ by a factor of one billion! Moreover, the relative densities of particulate matter may vary from about 1 g/cm 3 for certain lb plastics to 4.2 g/cm 3 for titanium dioxide pigments, while t surface-chemical properties of particulates may range from ve hydrophilic to extremely hydrophobic. It is not surprising, therefore, that the detrimental sep ration and selective fractionation of qualitatively and quant tatively highly differentiated particulate matter used for sy thesis of composite pigments can not be prevented with the a of slow, incomplete, and selective flocculation processes a inefficient flocculating agents of the present art. As a matt of fact, many ultrafine water-based colloidal systems can not flocculated (precipitated) at all with the use of means known the present art. In the Applicant's own diversified experime tation, on the other hand, no water-based colloidal system h yet been encountered, regardless how complex or difficult, ab to resist the overpowering instantaneous, indiscriminate, a complete, flocculating action of the in-situ formed compl functional microgels used in practicing the present invention. The secondary purpose of the complex microgels disclos herein is to provide an arbitrary level of intrinsic cementati to aggregated pigment particles upon subsequent drying, or oth finishing operations. The desired level of cementation can attained by varying composition and/or dosage of the function complex microgels, such as to provide structural aggregate pi ment products with sufficient mechanical integrity to withsta the customary shearing (loading) and/or comminution regimes which they may be exposed in practical handling and end-u operations. It should be pointed out in this context that the adhesiv action of above microgels is possible only due to the extremel small particle size, enabling the microgel particles to orien themselves effectively as discrete ultrathin formations at th interfaces between adjacent pigment particles to be cemented Although particles of above microgels are obviously larger tha those of silico-aluminate, silico-zincate, or silico-aluminate zincate hydrosols from which they were derived through cross linking (polycondensation) with bivalent or multivalent inorgan ic salts and/or organic cationically-active chemical compound with two or more reactive groups in each molecule, they coul not be detected visually under 50,000 X magnification in elec tronphotomicrographs of dried and pulverized composite pigment prepared with the aid of these microgels. Spheroidal hydroso particles with diameters ranging from 10 nm to 50 nm describe in U.S. Patent No. 2,974,108 to Alexander, on the other hand can be seen clearly in similar electronphotomicrographs. It is apparent that solid inorganic particles of the latte size, i.e., 10 nm to 50 nm, would not only be useless as inter facial cements or adhesives, but would actually interfere physi cally with the formation of adhesive joints between adjacen microparticulates. In-situ precipitated solid mineral particle of similar or larger dimensions have been found useful, however in synthesizing certain kinds of composite pigments, for exam ple, of coprecipitated/coaggregated type disclosed in U.S Patent No. 4,026,721 to Kurrle. According to this patent, soli spherical hydrous metal-silicate particles were precipitated o the surface of kaolin clay platelets improving the end product' optical performance. The tertiary purpose of the complex microgels disclos herein is to impart directly, by virtue of their inhere physical and surface-chemical properties, certain specif material and functional properties to the aggregated a cemented products, important from the standpoint of these pro ucts' end-use applications. The above effects can be realiz through purposeful modification of the chemical compositio and/or physical properties, of the complex functional microgel For example, surface-chemical modification providing enhanc compatibility with organic media may be attained by intrins incorporation of suitable organic polyelectrolytes, and/or oth specialized agents, into macromolecules which make up t complex microgels of the present invention. Composite pigmen synthesized with the aid of such microgels with built-in organ groups (functionalities) are especially well suited as fille for plastics, since they can be easily and uniformly dispers in oleophilic media. Anionic polyelectrolytes with microgel-modifying function encompassing, among other things, sodium salts of polyacryl acid or carboxymethyl cellulose, may be introduced into t system through the anionic stream, e.g., along with sodi silicate or sodium aluminate, or added directly to the partic late dispersion. Cationic modifying agents encompassing, amo other things, selected bivalent or multivalent inorganic salt as well as organic cationically-active compounds with at lea two reactive groups in each molecule, may be introduced into t system along with the solution of the principal bivalent multivalent inorganic salt(s) used for microgel formation. The indirect system-modifying action of complex microgel made possible by the indiscriminate and complete flocculati and retention of such powerful surface-chemical modifiers their own right as organic dyes and polymer-emulsion adhesive is also important. Other examples of functional modificati of inherent properties, or functional characteristics, of stru tural aggregate pigments through the in-situ precipitated com lex microgels used in practicing the present invention shall discussed hereinafter. The principal reagents of commercial significance for t in-situ synthesis of the complex functional microgels und discussion are: (1) alkali-metal silicates and quaterna ammonium silicates, preferably sodium silicate; (2) alkal metal aluminates, alkali-metal zincates, and blends thereof any proportions, preferably sodium aluminate; and (3) wate soluble, essentially colorless, bivalent and multi-vale inorganic salts, preferably calcium chloride and calcium nitra but equally well other similar salts of calcium, magnesiu barium, aluminum, zinc and zirconium, as well as cationically active organic compounds with at least two reactive groups i each molecule, capable of performing the same gel-settin functions as bivalent or multivalent inorganic salts. Of course both anionic and cationic organic additives used in the proces must be compatible with their respective anionic and cationi reaction streams, as indicated by absence of phase separatio clouding, or premature gelling. From a chemical standpoint the above complex microgels a made up of macromolecules of hybrid polymer-polycondensate typ the polymerization reaction being at the foundations of hydroε formation while polycondensation takes place during crosslin ing of the reactive hydrosols by cationic gel-setting agent Inorganic/organic hetero-macromolecules of the same polyme polycondensate type are formed when organic chemical compoun with at least two reactive groups in each molecule are built i trinsically into the microgel structure. Since the primarily auxiliary functions of the compl microgels are limited to flocculation, cementation and surfac chemical modification of disperse particulates, these gels a used as a rule at the smallest possible dosages needed to pe form the intended tasks, ranging from 0.5% to 10%, by weight, determined by ashing, of the total mass of aggregate pigment the particulate matter being quantitatively predominant phase the overall material balance. On the basis of extensive experi mentation with various simple, as well as most intricate comp site, structural aggregate pigment formulations, it has been es tablished that the relative weight content of complex microge in a vast majority of end products, determined by ashing aft washing out electrolyte by-products such as NaCl, NaN0 3 , Na 2 S0 4 , needs to approach 6% to 10% in only most demandi cases, e.g., those involving high levels of addition of organ particulates, dyes, and the like. In majority of practic applications, however, the relative weight content of comple functional microgels in structural aggregate pigment product ranging from 1% to 6%, as determined by ashing, will be suffi cient for adequate handling and end-use performance. In som less demanding applications, e.g., those which do not involv filtration and subsequent dewatering and comminution of th flocculated medium, a relative weight content of complex func tional microgels in the resultant pigment products as low a 0.5 %, as determined by ashing, is adequate. It should be emphasized that formation of intermediate hydro sols, and final micro'gels, used in practicing the present inven tion are not stoichiometric. The same hydrosols and/or microgel are synthesized each time, however, when the reagent concentra tions and proportions, as well as reaction conditions durin synthesis of these hydrosols and/or microgels, are the same. O the other hand, the principal qualitative and quantitative com positions of above hydrosols and microgels may be varied withi unusually broad ranges without detriment to these hydrosols' , o microgels', intended functional performance. For example, th ratio of sodium silicate to sodium aluminate, sodium silicate t sodium zincate, or sodium silicate to the combined mass o sodium aluminate and sodium zincate in forming the subcolloida reactive hydrosols (sodium-silico-aluminate, sodium-silico-zin cate, and sodium-silico-aluminate-zincate, respectively) ma rrr * from 10:1 to 1:10, by weight, the preferred ratio for mos applications pertaining to the synthesis of structural aggregat pigments being 1:1. The concentration of sodium silicate i aqueous slurries of particulate matter should vary optimall from 0.1% to 2%, by weight, the same pertaining also to sodiu aluminate, sodium zincate, or combination thereof. Reagen concentrations significantly higher than 2%, by weight, woul lead in a short period of time to formation of high-molecular weight hydrosols with reduced reactivity relative to crosslink ing agents, necessitating a drastic increase of throughput rate of the reaction medium through the reactors. As far as the formation of complex microgels is concerned, simple 1:1 ratio, by weight, of calcium chloride or equivalen crosslinking salts to the combined hydrosol mass is adequate fo a well balanced performance encompassing both flocculation an subsequent cementation of particulate matter used for synthesi of structural aggregate pigments of the present invention. I should be pointed out, however, that some excess of crosslinkin ions is necessary from the standpoint of process kinetics, par ticularly in plant operations employing large mixers-reactors As has been determined by chemical analysis, the concentratio of calcium, or equivalent, ions in the reaction medium shoul exceed by at least 50% the amount of such ions actually boun chemically by the reactive hyrosols. As a matter of fact, it i sometimes advantageous to use an even higher excess of bivalen and/or multivalent inorganic salts for hydrosol crosslinking e.g., by employing of up to 10%, by weight, of these salts o the total mass of particulate matter. Unlike with bivalent and multivalent inorganic crosslinkin salts, the ratio of organic, cationically active, crosslinkin agents to hydrosol mass must be determined empirically for ea individual compound and specific application. The reason f this is that the chemical properties of above organic materia are vastly more differentiated from the standpoint of the effect upon end-use properties of structural aggregate pigme products than are those of corresponding inorganic crosslinki agents. As a general rule, the relative proportion of the abo organic crosslinking agents should range from 0.1% to 5% of t mass of particulate matter. As is understood readily by those skilled in the art, t anionic and cationic streams in the process for synthesizi structural aggregate pigments of the present invention may reversed by blending solutions of bivalent and multivale inorganic salts and/or organic, cationically active, chemica compounds with at least two reactive groups in each molecul with aqueous dispersions of particulate matter in step (a) preparing subcclloidal reactive sodium-silico-aluminate (silic zincate or silico-aluminate-zincate) hydrosols independently i step (b) ; and blending in step (c) systems resulting fro steps (a) and (b) to form in situ complex functional microgel to flocculate the particulate matter instantaneously, indiscri inately and completely to synthesize structural aggregate pi ment products. It should be pointed out, however, that the abo reversion of process streams is feasible only in such instance in which the colloidal stability of dispersions of particulat matter is not impaired intolerably by a short period of contac with solutions of cationic agents employed. The pH of the flocculated structural aggregate pigment prod ucts from step (c) above ranges usually from 10 to 12. In case in which neutral, or slightly subneutral, pH is preferred, pre determined amounts of sulfuric acid, or other inorganic or or ganic acidifying agents, may be added to the dispersion of par ticulate matter in step (a) . The amount of agents necessary t lower pH to the desired level must be assessed independently, b titrating a sample of the alkaline medium from step (c) wit solutions of the acidifying agents to be employed. Though i principle the resultant pH of the flocculated medium in ste (c) could be lowered to 3.5, the colloidal stability of mos dispersions of particulate matter used for synthesis of struc tural aggregate pigments of the present invention will be im¬ paired intolerably below pH of 5, or even 5.5. The complex functional microgels used in practicing th present invention may also be prepared independently, in plai water, and then blended with a dispersion of particulate matte to flocculate the latter indiscriminately and completely, bu not instantaneously, to form a structural aggregate pigmen product. It should be emphasized, however, that the proces version in which subcolloidal reactive hydrosols are synthesize first in aqueous dispersions of particulate matter, followe by addition of cationic crosslinking agents, is preferred fo the synthesis of structural aggregate pigments according to th present invention. The above, almost boundless, latitude with respect t chemical composition of complex microgels used in practicing th present invention is very unique, in that practically al methods of gel synthesis known in the present art rely on ver strictly and narrowly defined compositions, both with regard t these gels' synthesis as well as end-use properties. Another uniquely broad latitude with regard to the reactio conditions in general pertains to the pH range, extending fro 3.5 to more than 12, under which the complex microgels of th present invention can both be synthesized and perform thei intended functions. As is typical of ultrafast reactions in aqueous media, th in-situ formation of the complex functional microgels mentione is virtually independent from temperature. This means that, i principle, the above microgels could be formed within the entir temperature interval in which water remains fluid, i.e., fro above the freezing point to below the boiling point. From purely practical standpoint, however, the temperature at whic composite pigments can be manufactured will be determined prima rily by the thermal stability of dispersions of particulate ra materials. The virtual independence from thermal conditions and regime is a very unusual and unique feature of above microgels, whic becomes readily apparent when comparisons are made with othe technologies of gel formation in accordance with the presen art. For example, countless patents pertaining to the manufac ture of catalysts, ion exchangers, pharmaceutical preparations and other products based on in-situ formed gels, sometimes of virtually identical compositions, frequently differ only with respect to small variations of the thermal regimes. The broad latitudes with respect to reaction condition mentioned above, constitute a clear indication of the incredib overriding power of the principal colloidal-chemical system us in practicing the present invention. It is worth noting th similar latitudes are intolerable with procedures of the prese art, according to which continuous gels and hydrosols, and pro ucts made with their use, must be manufactured always under ve strictly defined reagent concentrations and proportions, pH co ditions, as well as thermal and procedural regimes. The potential role of structural aggregate pigments of t present invention in future paper making technologies can perhaps illustrated best against a background of present indu trial practices relying on the use of conventional mineral pi ments. For use in paper making, the latter pigments are ma down as a rule in the form of concentrated, optimally dispers slurries. In their final destination, on the other hand, the pigments exist in a highly aggregated and/or flocculated stat e.g., encased within a paper-coating matrix or filled pap webs. This terminal aggregation/flocculation is particularl strongly pronounced in coatings, especially those made with t aid of highly poly-disperse and anisometric kaolin pigmen characterized by very fine particle size. The latter pigments are typified by No. 1 V.F. (Number O Very Fine) , high-glossing, hydrous coating clays which conta 95% - 100%, by weight, of particles smaller than 2 urn e.s. (equivalent spherical diameter), less than 10%, by weight, particles smaller than 0.1 urn e.s.d., and have an avera particle size ranging from 0.2 μm to 0.4 μ e.s.d. Briefly, the above clay products may be described as being manufactured from inherently very fine particle size crudes by blunging the latter in water, removing particulate impurities larger than 44 urn e.s.d. with the aid of appropriate screens, followed by centri- fugation to obtain a useful fraction with particles 95% to 98%, by weight, finer than 2 j e.s.d. The latter fraction is sub¬ sequently beneficiated by physical methods such as high-gradient magnetic separation, colloidal-chemical methods such as flota¬ tion and selective flocculation, and chemical methods such as oxidation and reduction bleaching important also from the stand¬ point of chemical stabilization of the end product. The above very fine particle size clays are used by them¬ selves almost exclusively for the manufacture of glossy printing papers, representing a relatively small market, and as feedstock for making fine particle size calcined clay pigments. In the state "as is," these clays are practically unusable toward paper filling applications due to poor retention on the paper machine, inferior optical efficacy, and strong fiber debonding action. At the present, very fine particle size clays are used main¬ ly as diluents for regular coating clays derived from substan¬ tially more valuable, coarser, more crystalline "white" clay crudes. The light-scattering coefficients of clay pigments made 100% from the latter crudes are about two to three times higher than those of very fine particle size, high-glossing clays. Un¬ fortunately, white crudes, particularly those having good Theo¬ logical properties, are progressively more scarce. As a conse- quence, admixing of up to 50% of optically inferior very fine particle size clays into commercial coating clay products has become a virtual necessity throughout the clay industry. It is not surprising, therefore, that the optical properties of such hybrid coating clays constituting the bulk of present market sales deteriorate progressively as the deposits of better crudes become depleted. Indeed, the light-scattering coefficients of clay products marketed some 15 years ago were an the average 40% to 50% higher than those of analogous products marketed today, the foregone conclusion being that the situation will only get worse in the future. The limited usefulness of very fine kaolin clay crudes is most unfortunate in that the vast majority of clay deposits in the United States belong to this category. Moreover, there are no realistic prospects for a broader utilization of such clays within the context of pigment manufacturing, or other commercial applications, relying on technologies of the present art. Hence, the technology of the present invention utilizing these abundant very fine particle size, low-value, crudes as a most valuable raw material toward the manufacture of high-performance, high- value added, structural aggregate pigments constitutes de facto a major breakthrough in the utilization of otherwise inferior, or even useless, raw materials. It is known from optical physics that the highest intensity of light scattering by a spherical particle is attained when the diameter of the particle is equivalent to one-half of the wave¬ length of impinging light, i.e., approximately 200 nm to 300 nm. With platy clay particles, the light is scattered by various solid irregularities, such as particle edges or corners, or surface protrusions. Under practical end-use conditions encountered in paper filling and coating, with the individual pigment particles being compacted (by way of flocculation and aggregation) into integral formations existing within filled webs or paper-coating matrices, the light is scattered both by internal as well as external structural (solid) details of these formations. The closer are the dimensions of these structural details to those needed for optimum light scattering, the better is the resultant optical performance of the entire formation.. It becomes apparent, therefore, that a method enabling one to effectively control the process of forming optimized aggre¬ gate pigment structures represents an enormous commercial potential. As demonstrated by Kaliski in the article entitled "Performance of Some Commercial Clays in Starch-Containing Paper Coating Films" - Part 1, appearing in The Journal of the Techni¬ cal Association of the Pulp and Paper Industry (TAPPI) Vol. 53, No. 11, page 2077 (1970), the light-scattering coefficients • of coating formations consisting of kaolin clay pigments and starch adhesives initially increase, and after passing through a maximum decrease, with increasing levels of the adhesive. The explanation of this phenomenon given by Kaliski is that under¬ sized pigment particles, which are incapable of efficient light scattering individually, become progressively aggregated by incremental additions of the adhesive into formations whose structural details are dimensionally closer to those needed for optimum light scattering. After certain critical level of th adhesive in the coating is exceeded, however, the progressiv coarsening of structural details of the resultant coatin formation by additional adhesive increments becomes excessive, thus reducing the overall light-scattering efficacy of th system. This progressive intrinsic coarsening of the interna structural details with increasing adhesive levels, wa demonstrated clearly with the aid of the "rho" factor develope by Kaliski and described in the above-mentioned TAPPI article. The aggregation and flocculation processes occurring i paper filling and coating are not amenable to effective control within the scope of technologies of the present art, thoug attempts to develop such controls have been reported in th literature for more than five decades. The most attractive o these approaches were directed towards development of so-calle bulking pigments intended to at least duplicate the optica performance of old-fashioned satin white pigments, without th latters' numerous undesirable features. From the standpoint o optical performance and printability, satin white admixed t conventional coating clays has indeed a unique ability to induc favorable intrinsic structures in the resultant coating forma tions. The preparation, handling and application of coatin colors containing satin white, however, are rather cumbersom and difficult. New concepts relating to the improvement of pigment perfor mance in paper coatings were developed by Kaliski and describe in the article entitled "Performance of Some Commercial Clay in Starch-Containing Paper-Coating Films" - Part 2 appearing i TAPPI, Vol. 55, No.. 1, page 102 (1972), as well as in Chapter 13 of "Physical Chemistry of Pigments in Paper Coating" (copyright 1977 by TAPPI) in which he pointed out the importance of "early setting of transient coating structures in freshly applied coat¬ ing films." Such early setting arrests progressive deteriora tion of the initial, statistically uniform, transient coatin structures in wet coating films and eliminates the detrimenta separation and selective fractionation of individual coatin ingredients. Hereinafter shall be demonstrated how structural aggregat pigments of the present invention, as well as scientific con cepts discussed above, can be used to obtain many practical results superior to those attainable with the aid of filling an coating pigments of the present art. The in-situ formed complex functional microgels mentioned above make possible to synthesize new types of structural aggre¬ gate pigment products uniquely suited toward paper coating and filling applications, filling of plastics, and many other prac¬ tical uses. The optical performance of such structural aggregate pigments synthesized from a variety of commercial pigment prod¬ ucts and other mineral and organic particulates, as well as sol¬ uble components, is substantially better than that of the origi¬ nal raw materials used in non-aggregated form. Many unique per¬ formance properties, as well as structural and surface-chemical features, can be imparted to these aggregate pigments almost at will by purposeful a-priori design. One of such unique perfor- mance properties is, for example, ultrahigh bulking which brings about spectacularly rapid setting of coating films on paper sur¬ face. The above setting is fully independent of dewatering, such * as is normally indispensable to setting of wet films containing standard coating pigments or conventional bulking pigments. By contrast, coating formations containing ultrahigh bulking pigments of the present invention become immobilized (set) rapidly without dewatering, yielding smoother and more uniform coatings with higher gloss, brightness and opacity, as well as better glueability and printability, than analogous coating for¬ mations containing pigments of the present art. Special types of structural aggregate pigments equipped pur¬ posely with maximum bulking properties (very high level of thixotropy) are extremely valuable in paper filling applica¬ tions. A complete, but totally reversible, gelling can be ob¬ tained with aqueous slurries of such specialized pigments even upon dilution to 20% solids, or even lower. Accordingly, these pigments begin to display structure-forming (bulking) tendencies during web consolidation on the paper machine even before water drainage on the forming wire is completed. The practical effects of this heretofore unknown ultrahigh bulking are manifested in substantially increased levels of filler retention, vastly im¬ proved uniformity of spatial distribution of pigment particles within consolidating paper webs, and drastic reduction of the normally difficult-to-avoid detrimental web two-sidedness. Surface-chemical modification of structural aggregate pig¬ ments of the present invention can be affected by building in organic groups into macromolecules making up the microgels and through incorporation of organic particulates into the aggregate pigment structure, thus imparting controlled levels of affinity toward organic (non-polar) media in addition to the inherent affinity of (polar) mineral pigments toward water. In the above manner, the structural aggregate pigments acquire intrinsic dual-matrix surface characteristics of hydrophilic/organophilic type well suited, for example, toward uniform and efficient dissipation both of water and ink solvents in offset printing. There are hundreds of anionic and cationic organic polymers in daily use by the paper and pigment industries identified only by trade names, molecular weights, and ionic type, which can be employed toward microgel formation if they are compatible with the respective ionic streams. For example, anionic polymers such as sodium salts of polyacrylic acid or carboxymethyl-cellulose are compatible with the anionic process stream if they are not coagulated, or salted out, by strongly alkaline solutions of sodium silicate, aluminate or zincate. Similarly, cationic poly¬ mers, e.g., polyacrylamides, are compatible with the cationic stream if they are not coagulatedj- or salted out, by solutions of bivalent and mutivalent inorganic salts. A vast number of organic monomolecular anionic and cationic chemical compounds with two or more reactive groups in each molecule can be used in addition to, or instead of, organic ionic polymers mentioned above. Examples of such anionic compounds are sodium salts of N-(l,2-dicarboxyethyl)-N-alkyl sulpho-succinamate (Aerosol 22), or ethylenediamine tetraacetic acid, while methyl-dodecylbenzyl- trimethyl ammonium chloride-methyldodecylxylene bis(trimethyl) ammonium chloride (Hyamin 2389) is representative of organi cationic compounds with two reactive groups in each molecule. Depending on the intended end-use applications of structural aggregate pigments synthesized with the aid of polymeric o monomeric organic adjuvants, addition levels of the latter ma vary from 0.1% to 5%, on the total mass of mineral particulates. Lower addition levels of these agents may suffice, for example, with structural aggregate pigments intended for coating of pape for offset printing, higher levels of addition being preferre with composite pigments intended for filling of plastics, o paper substrates to be saturated with solutions of organi resins. Of course, organic particulates, e.g., polystyren pigments or polymer-emulsion adhesives, incorporated into th aggregate pigment structure modify the surface chemistry of th resultant pigments in an indirect fashion by forming a dua matrix of polar/non-polar type. Carbon black and organic color dyes can be incorporated int structural aggregate pigments at levels ranging from 0.001% t 0.25% and 0.001% to 5%, by weight, respectively. Although bot above materials have notoriously poor affinity toward polar sur faces, such as mineral pigments or cellulosic fibers, they ar retained and distributed uniformly within aggregate structure of pigments made with the aid of in-situ synthesized comple functional microgels used in practicing the present invention. Very low levels of addition of carbon black and/or organi color dyes, e.g., ranging from 0.001% to 0.01%, by weight, are often sufficient to correct the inherent "yellowness" typical virtually all mineral raw materials used for synthesis of stru tural aggregate pigments. Somewhat higher levels of additio e.g., ranging from 0.1% to 0.3%, by weight, for color dyes, a from 0.005% to 0.12%, by weight, for carbon black, yield high opacifying structural aggregate filler pigments which can al be used to mask the inherent yellowness of groundwood papers. similar level of dye addition, i.e., 0.1% to 0.3%, by weigh eventually in combination with up to 0.03%, by weight, of carb black, will mask the pronounced yellowness of unbeneficiat kaolin clay making possible to use the latter as is, or aft only inexpensive magnetic beneficiation, toward the manufactu of economical structural aggregate pigments for paper filli and coating. Still higher levels of color-dye addition, e.g., of up 5%, by weight, make possible to synthesize intensively color aggregate filler pigments for the manufacture of most uniform colored papers devoid of objectionable two-sidedness, such as common with color papers of the present art. The above, approa relies on easily controllable mechanical retention of colore filler, particles in the web, eliminating the need for difficult to-control quantitative and qualitative balancing of loose dye in recirculating furnishes on the paper machine. The outstandin economy of the above approach should also be pointed out in tha retention of mineral fillers in the sheet is from 10 to 40 time higher than that of loose, incomparably more expensive, dyes. Decorative gray papers, totally opaque for all practica purposes, can be manufactured with the aid of structural aggr gate filler pigments containing up to 0.25%, by weight, o carbon black. Very attractive, "metallised" appearance o paper surface can be obtained by incorporation both of metalli and color pigments into structural aggregate filler pigments. It should be borne in mind also that most organic dyes an carbon black, particularly the latter, are pronouncedly hydro phobic while the in-situ formed complex functional microgels o the present invention are very hydrophilic unless cured abov 220°c In the course of the manufacturing process structura aggregate pigments are exposed to drying temperatures whic rarely exceed 150°C, hence, the microgel cement retains a hig degree of hydrophilicity not conducive to a total immobilizatio of hydrophobic dyes or carbon black. Since even traces of abov colorants dispersed or dissolved in water can be noted readil at concentrations as low as one part per billion, the need fo complete (100%) permanent attachment of these agents to the sur face of structural aggregate pigments is rather obvious. Suc irreversible attachment (immobilization) can be obtained by in corporation of suitable latex adhesives, along with organic dye and carbon black, into the structural aggregate pigments. Th most effective immobilizing agents for carbon black and organi dyes were found to be the novel ultrafine polymer-emulsio adhesives to be discussed in more detail hereinafter. In th absence of immobilizing adhesives, traces of carbon black an organic dyes detach from the mineral (polar) surface when con centrated slurries of structural aggregate pigments are expose to intensive shearing, becoming noticeable especially aft subsequent dilution and aging of the slurries. Broadly diversified functional properties were imparted structural aggregate pigments of the present invention by inco poration of the above-mentioned novel polymer-emulsion adhesiv developed by the Applicant and disclosed in co-pending pate application (Serial No. 07/333,435 i Filed April 4 1989 These adhesives, encompassing acrylic, vinylacetate and styren butadiene polymers and copolymers, have ultrafine particles wi diameters ranging from 20 nm to 55 nm, and glass-transition te peratures ranging from +20°C to -60°C. Coated papers for offs printing made with the aid of structural aggregate pigments co taining from 0.25% to 5%, by weight, of the ultrafine polyme emulsion adhesives were found to have better dry and wet coati pick, as well as higher blistering resistance, than analogo coatings made with the aid of conventional pigments. Furth Furthermore, structural aggregate filler pigments containi these adhesives cause much less fiber debonding than conventio al fillers, this positive effect being amplified by hot cale dering of the filled paper. The above ultrafine polymer-emulsion adhesives, along wi relatively fine particle size (essentially 100% finer than 5 J e.s.d.), high specific surface area (at least 50 m 2 /g) , strong gelling minerals such as montmorillonite and bentonite, are t primary functional constituents of ultrahigh bulking pigmen mentioned previously. The latter pigments are uniquely suit as fillers for uncoated printing papers, particularly newspri and papers for ink- et printers, as well as size-press coati pigments, because of spectacular ink holdout resulting in exce lent print gloss. Furthermore, these pigments are ideal carrier for ink-curing promoters (driers) , such as manganese, cobalt, o lead naphthenates, which should be incorporated into these pig ments in proportions ranging from 0.1% to 5%, by weight. Calcium-silico-aluminate, and other related, microgels use in practicing the present invention exert by themselves a pro nounced surface-chemical activity. For example, cellulosic web filled with structural aggregate pigments made with the aid o above microgels are virtually immune to aging phenomena relate to intrinsic acidity and light exposure. The instantaneous, indiscriminate and complete flocculatin action of the complex functional microgels of the present inven tion makes possible to synthesize multiple-component structura aggregate pigments of virtually any arbitrary morphology an chemical composition, with all particulate ingredients bein statistically and spatially uniformly distributed within th resultant aggregate structures, not attainable with the aid o technologies of the present art. The selection of raw material suitable for the manufacture of structural aggregate pigments i extremely broad, encompassing, for example, virtually all type of conventional "hydrous" kaolin clay products, as well as fin particle size calcined clay pigments derived from very fine par ticle size kaolin clay feeds; precipitated calcium carbonate calcium silicate, calcium aluminate, calcium sulfate, hydrate alumina, hydrated silica, and silico-aluminates, with equivalen spherical diameter ranging from 0.01 um to 10 μm; naturall occurring calcium carbonate, gypsum, talcum, montmorillonite and bentonite, with equivalent spherical diameter ranging fro 0.1 um to 5 um; conventional (commercially available) titaniu dioxide pigments, as well as titanium dioxide products obtaine by special intensive comminution of commercial materials to in crease substantially the relative proportion of particles wit diameters between 0.2 px& and 0.4 u , and reduce the largest par ticles to a diameter essentially smaller than 0.9 um, but pref erably finer than 0.7 jm or even 0.6 um. ; naturally occurrin rutile and anatase minerals comminuted intensively to an averag particle size essentially finer than 1 um; organic polymeri pigments; synthetic and natural (cellulosic) microfibrils; conventional latexes as well as novel ultrafine polymer-emulsio adhesives; ink-curing promoters; color dyes and carbon black; and particulate phenolic resins of the type used in the manufac¬ ture of carbonless paper. Interesting steric effects of practical significance can be obtained if a proportion of particulate mineral raw materials for the manufacture of structural aggregate pigments are very fine, or even ultrafine (i.e., 0.01 um to 0.1 um e.s.d.). For example, with composite pigments consisting of 30% conventional titanium dioxide pigment and 70% ultrafine precipitated calcium silicate, by weight, each individual particle of titanium diox¬ ide immobilized in the resultant aggregate structure may be sur¬ rounded by up to 20,000, or even 30,000, particles of calcium silicate. The net effects of such unique steric configurations are manifested by vastly increased light-scattering efficacy of titanium dioxide particles independent of crowding conditions in a filled sheet, or a coating, excellent first-pass retention the paper machine, highly increased oil absorption, and oth important performance advantages. The use of functional complex microgels of the present inven tion toward manufacture of structural aggregate pigments wit vastly improved optical and other performance properties shal be illustrated hereinafter by way of laboratory examples. T following Example I demonstrates the preparation of a simpl structural aggregate pigment from a very fine particle siz centrifugal fraction (100% finer than 2 um e.s.d.) of a low quality Georgia clay crude, using specially developed laborator batch process intended to simulate continuous synthesis proces to be used preferably in large-scale plant operations. EXAMPLE I A 100 g batch of the above-mentioned very fine particle siz kaolin clay fraction was made down 'into a slurry of about 70 solids, by weight. The batch of concentrated slurry was dilut subsequently to about 20% solids, by weight, and divided in two equal portions. A 5%-solids solution containing 2 g (d basis) of sodium silicate was added under agitation into o portion of above clay slurry. Similarly, a 5%-solids soluti containing 2 g (dry basis) of sodium aluminate was added in the second portion of the above slurry. In the subsequent step both above portions of clay slur were recombined rapidly under vigorous agitation, whereby a su colloidal reactive sodium-silico-aluminate hydrosol (anionic polyelectrolyte) was formed instantly by the interaction between sodium silicate and sodium aluminate. Immediately afterwards, a 5%-solids solution containing 4 g (dry basis) of calcium chloride was added, under very strong agitation, into the recombined clay slurry containing the above- mentioned hydrosol. Instantaneous flocculation of the slurry manifested by a total disappearance of vortex in the agitated medium was observed upon the introduction of the very first por¬ tion of calcium chloride solution into the system. It thus was necessary to increase the agitation rate promptly and steadily to restore the vortex without which a useful distribution of the remaining portion of calcium chloride solution (the whole process of addition lasting from start to end about 2 seconds) would not be possible. The instantaneous flocculation of the system could be recog¬ nized immediately by immersing a spatula in the slurry, with the pigment floes being clearly visible in the thin layer of liquid retained on the spatula. A narrow layer of clear supernatant above the bulk of flocculated slurry formed after a couple of minutes, while a thick crystal-clear layer of supernatant was observed after a couple of hours. The flocculated slurry could be filtered right away, though a controlled period of aging enhances the filtration rate almost invariably with all flocculated particulate systems. Dewatering of the above slurry on a Buechner funnel at filter-cloth loading of 2000 g/m 2 was extremely fast. As a matter of fact, 20%-solids slurry of above pigment having pH of 12 needed under above con¬ ditions about 30 minutes for complete filtration and rinsing as compared to 30 hours for a 20% solids slurry of non-aggregate raw material flocced with sulfuric acid to pH of 2.5. It is worth noting that filtration of alkaline slurry of a very fin particle size kaolin clay pigment would be totally impractical. To obtain the final product (simple structural aggregate pig ment) , the rinsed and dried filter cake was pre-crushed and com minuted with the aid of conventional pulverizing equipment use routinely in the clay industry. The comminution regime, define by the number of passes through the pulverizer and the size o screen openings, was chosen so as to maintain the dimensions o largest particles in the resultant pigment product only slightl larger than they were in the raw material employed, limiting the permanent aggregation effectively to the finer particulate frac¬ tions present in the starting material. The optical performance of the structural aggregate pigment product obtained was rather impressive. The light-scattering coefficients of binderless coating films on black glass plates, determined with the aid of techniques described by Kaliski in TAPPI 53(11)1970, were 0.170 m 2 /9 f° r the aggregate pigment as compared with 0.050 m 2 /g for the starting material (very fine particle size kaolin clay) . Similar results were obtained when sodium aluminate in the reactive hydrosol was replaced partially or totally with equiva¬ lent amounts of sodium zincate, or when calcium chloride was re¬ placed with calcium nitrate. Dosages of microgel-forming reagents employed in Example are preferable both with simple, as well as many composite structural aggregate pigments made according to the present in vention. One can comprehend readily, however, that other reagen dosages and/or proportions will often be called for considerin the virtually countless types of structural aggregate pigmen products which can be synthesized by the described method fo various specific uses. It should be pointed out also that the flocculated slurry i Example I was dewatered by vacuum filtration (Buechner funnel) In plant operations, however, the vacuum filtration/rinsing com bination intended to remove electrolyte by-products of microge formation should be followed up preferably by a pressure-filtra tion step. Attaining highest possible filtercake solids leve in the latter step is helpful in eliminating "fine-end tail" i the resultant pigment products, encompassing the optically les efficient but strongly debonding aggregates smaller than 0.2 um or so. It has also been established experimentally that flash drying, in which both the drying and pulverizing operations ar intrinsically combined, is advantageous in large scale manufac turing of structural aggregate pigment products of the presen invention, from the standpoint of ease of dispersion, reductio of detrimental screen residue, and overall process economy. As is readily understood by those skilled in the art, th laboratory batch manufacturing process described in Example I i applicable also to plant-scale manufacturing. As far as produc quality and versatility of product design are concerned, how ever, best results are obtained with the aid of continuous ma facturing processes which provide optimum control of the cri cal crosslinking step and allow one to use higher concentrati of hydrosol-forming reagents in the reaction medium. One of m possible versions of continuous processes for the manufacture structural aggregate pigments of the present invention, invo ing continuous passage of the reaction medium through a ser of in-line mixers reactors (stations) , is described below i simplified fashion as consisting of the following process steps: (a) metered quantities of slurries of mineral particula are introduced continually into first station to obtain compl homogenization of the medium at high shearing rates; (b) metered quantities of dilution water, soluble (anion organic agents, polymer-emulsion adhesives, soluble and dispe dyes, and the like, are injected continually into the in-com reaction stream and homogenized at lower shearing rates t those employed in the previous station; (c) metered quantities of hydrosol forming reagents are jected into the reaction stream entering a third station, form the subcolloidal reactive hydrosol; and (d) metered quantities of crosslinking agent(s) are injec into the in-coming stream of the hydrosol-containing react medium at a forth station under precisely controlled shear regime, to form in-situ continually and reproducibly the desi complex functional microgel, thus flocculating the react medium instantaneously, indiscriminately and completely obtain a structural aggregate pigment product. Even moderate admixtures of simple structural aggregate pi ment products to conventional coating clays improve substantia ly the latters' optical performance, as shall be demonstrated the following example: EXAMPLE II A pigment blend containing 75 parts, by weight, of comme cial delaminated clay and 25 parts, by weight, of the simp structural aggregate pigment from Example I, was made down in a 55%-solids coating formulation of the type used in the man facture of gravure papers. A styrene-butadiene latex was us as the coating adhesive in proportion of 5 parts (dry weigh per 100 parts of total pigment. Analogous control coating fo mulation was prepared using above delaminated clay as the so pigment. Both above formulations were applied separately onto typical commercial lightweight publication paper base sheet wi a basis weight of 28 lbs/3300 sq.ft., at a rate of 5 lbs/33 sq.ft., CIS (coated one side). The coated paper was dried a supercalendered under conditions such as to impart a gloss approximately 50% to the control sample. It was established by means of visual inspection that pap coated with the formulation containing 25/75 blend of structur aggregate pigment and delaminated clay had better surface cove age, coating lay, and K&N ink-stain uniformity than paper coat with c ntre*1 containing delaminated clay as the so pigment. It was further established with the aid of instrument measurements that gloss, brightness and opacity of paper coat with formulation containing 25% of the experimental aggrega pigment were higher by 5; 2.5; and 1.5 percentage-points, res pectively, than corresponding values obtained with paper coat with the control formulation. The make-down of aqueous slurries of structural aggrega pigments, e.g., those described in Examples I and II, diffe fundamentally from that of the high-glossing, very fine partic size, clays from which they were derived. For example, mo coating clay products made from Georgia crudes can be made do with the aid of phosphate and/or polyacrylate dispersants in 70%-solids slurries, characterized by a more or less pronounc dilatancy. The structural aggregate pigments mentioned requi up to five-times higher levels of dispersants, yet, can be ma into slurries with a maximum solids content only slightly high than 60%. The slurries in question are highly thixotropic, fl most readily under shearing, and gel immediately when the shea ing forces are removed. This unique rheological behavior can sustained if above slurries are made down into properly form lated coating colors, or even relatively low-solids pigment sizepress formulations, which is not possible with the coati pigments of the present art. The practical consequences of the above unique rheologic behavior are quite significant. For example, coating formula tions containing shear-thinning structural aggregate pigments the present invention can be applied at highest speeds atta able with the fastest, most advanced, coaters of the pres art. Indeed, coating formulations of the above-mentioned t have been applied on a commercial coater at speeds of nea 5000 feet per minute, the empirical indications being that coating speed could yet be increased very considerably. Mo over, since rapid setting (immobilization) of freshly appl coating films containing above structural aggregate pigments be obtained without dewatering, the normally unavoidable dis rangement of the initial, more uniform, coating-film structur caused by water drainage currents and contour-following pheno na taking place during setting of wet films, is nearly tota eliminated. The important practical consequences of this ra setting are lack of objectionable coating mottle, better fi coverage and smoother'coating surface. A simple structural aggregate pigment similar to that p pared in Example I, but containing additionally 2 parts of ultrafine polymer-emulsion adhesive (polybutylaerylate with average particle size below 55 nm and glass-transition t perature of -50°C) per 100 parts of pigment, by weight, evaluated in a paper filling experiment described in the foll ing example: EXAMPLE III Handsheets with dimensions of 30 cm x 30 cm and basis wei of 60 g/m 2 were prepared with the aid of laboratory mold us furnish consisting of a 50:50 softwood/hardwood combination The system was flocculated with alum at a rate of 20 lbs. pe ton of furnish, with a high-moite-wulax- eignr-. polyacrylamid being used as the retention aid at a rate of 1 lb. per ton o furnish. The acidity of the system was maintained at pH of 4. with the aid of sulfuric acid. A set of filled handsheets was prepared with the aid of th simple structural aggregate pigment mentioned above, furthe referred to as the "principal" system, an analogous contro system being prepared with the aid of a delaminated clay. The brightness of unfilled handsheets was about 86% and di not change appreciably with increasing filler levels both fo the principal as well as control systems. The opacity o unfilled handsheets was 71%, increasing to 84.4% with the con trol system and 85.1% with the principal system at a filler loading level of 10%, by weight. Since optical properties o filled sheets should be compared at equal sheet strength, th much stronger principal sheets had to be brought up to a filler loading level of 16.5%, by weight, to reduce their strength t the level of the control sheets containing only 10% of delami nated clay. At the increased filler content of 16.5%, th opacity of principal sheets was 88.2%, i.e., 3.8 percentage points higher than that possible to obtain with control sheet of acceptable strength (i.e., containing 10%, by weight, o delaminated-clay filler) . The additional advantage realize with the aid of the simple structural aggregate filler mentione was replacement of 130 lbs. of expensive chemical fibers per to of paper product with incomparably less expensive and ecologi cally preferable mineral matter. The goal of maximizing the use of mineral fillers in pape has been pursued by the paper industry for many years. The mai obstacles to the above goal have been progressive deterioratio of sheet strength and decay of fillers' opacifying efficacy wit increasing filler loading level, as well as filler abrasiveness There is obviously no realistic chance that the above obstacle can be overcome in foreseeable future with the aid of material and technologies of the present art. No such limitations ar connected with the use of structural aggregate pigments of th present invention, however, which offer immediately a variety o performance features and advantages going a long way toward attaining of substantial increases of filler-loading levels i paper webs above the current industrial practice. As is wel known, one of the main culprits in fiber debonding are free pig ment fines present abundantly in all conventional mineral fille products. These fines are eliminated effectively in structura aggregate pigments made with the use of the complex functiona microgels, especially with pressure filtration used as one o the intrinsic elements of aggregate-pigment manufacturin process. All types of structural aggregate filler pigments of th present invention have, without exception, lower fiber-debondin tendency than conventional filler pigments because of effectiv elimination of mineral fines. The above performance advantag can be enhanced still further with the use of the novel ultr fine polyacrylic emulsion adhesives, which are capable of exer ing a distinct filler/fiber cementing action when incorporat into the structure of aggregate filler pigments. This cementi action is manifested first, however, when the adhesive conte reaches at least 2% of the total mass of aggregate pigment--- * -" of very fine particle size kaolin clays. The above indicat that an intrinsic "sink capacity" of the aggregate pigments wi respect to the adhesive must be exceeded for some adhesive "su plus" to become available for external use, such as formation microscopically sized adhesive joints between aggregate pigme particles and cellulosic fibers in the surrounding paper we With structural aggregate pigments consisting primarily of fi particle size calcined clay and/or synthetic ultrafine precip tated minerals characterized by high oil absorptivity, the i trinsic demand (sink capacity) for the above ultrafine polyme emulsion adhesives is usually higher than 2%, by weight. As understood readily, the latter sink-capacity inherent to hig specific-surface-area minerals, such as montmorillonite or be tonite, is considerably higher than that of any other minera and may require adhesive levels of up to 5%, by weight, of t total mass of structural aggregate pigments. It should be not that the filler/fiber cementing action of the ultrafine polyme emulsion adhesives seems to be very unique and could not be d plicated thus far with the use of conventional latex adhesives. The low fiber-debonding characteristics of structural aggr gate pigments used in Example III can be used to full advanta in "high-ash" filling applications, referring to filler-loadin levels in excess of 30%, by weight, due to these pigments' ex tremely low abrasiveness. Multiple assays carried out with th aid of Einlehner's tester have shown that the abrasiveness men tioned ranges from 0 (zero) mg to 0.5 mg, qualifying thes pigments as perhaps the softest mineral fillers ever used in th paper industry. The importance of low abrasiveness can perhap be illustrated best by the fact that fine particle size calcine clay, without question the most attractive single filler pigmen of the present art from the standpoint of opacifying efficac and overall economy, is rarely used at loading levels exceedin 4% of the total mass of paper, by weight, primarily because o the prohibitive abrasiveness. The manufacture of high-ash papers is hampered by many othe problems in addition to fiber debonding and filler abrasiveness. For example, it is necessary as a rule to preflocculate the fil ler system before adding it to the paper furnish, in order t obtain satisfactory first-pass retention when using high filler loading levels in the sheet. Unfortunately, the detrimenta side effects of the above-mentioned filler preflocculation ar invariably overall excessive flocculation of the furnish, whic causes the deterioration of sheet formation quality, as well a essentially total decay of the opacifying efficacy of the fille manifested by lack of sheet opacity increase when the filler loading level in the sheet is increased above certain critica level. The structural aggregate pigments of the present inventio have significantly higher first-pass retention potential on th paper machine, thus eliminating the need for preflocculation i high-ash paper filling applications. Moreover, ultrahigh level of first-pass retention, well in excess of 90%, can be attaine with the aid of 0.1% to 5%, by weight, of synthetic and/o cellulosic microfibrils incorporated into structural aggregat filler pigments. Cellulosic microfibrils suitable for the abov purpose can be obtained with the aid of new technology develope by the Applicant and disclosed in co-pending patent applicatio (Serial No.: 07/165,759 »' Filed: March 9, 1988). The latte technology involves cascade processing of cellulosic fibers preferably cotton and well-fibrillating cellulosic pulps, th sequential processing steps consisting of: (a) dry or wet chopping of fibers to a length preventin hydraulic spinning in subsequent wet processing; (b) very high consistency (30% to 40% solids, by weight refining, preferably in the presence of sodium silicate, Cong red, and/or other inorganic and organic adjuvants enhancing fib rillization; (c) precision finishing refining with the aid of colloida mills; and (d) processing of the system resulting from step (c) wit the aid of Gmolin homogenizer or equivalent equipment employin very-high-compression/rapid-decompression (adiabatic expansion cycles to separate residual bundles of fibrils without furthe appreciable reduction of fibril length. Fibrils up to 10 um long, or so, can be built into th structural aggregate filler pigments to provide extra-high fir pass retention on the paper machine, in addition to considerab web reinforcement badly needed in high-ash paper filling appl cations. It is apparent that synthetic fibrils used instead cellulosic ones will provide extra-high first pass filler rete tion without contributing appreciably to web reinforcement. Opacifying characteristic of structural aggregate pigmen of the present invention differs fundamentally from that of t pigments of the present art. The opacifying efficacies of t latter pigments, including such powerful opacifiers as titani dioxide and calcined clay, deteriorate rapidly with increasi filler loading, at any level of filler addition. The reason f above performance deterioration is progressively denser crowdi of filler particles leading to avalanche-like flocculation, pa ticularly in the presence of abundant mineral fines with dime sions below 0.2 to 0.25 im e.s.d. By contrast, the opacifyi efficacy of structural aggregate filler pigments, essential devoid of free fines and thus not prone to excessive floccul tion even in crowded high-ash paper furnishes, deteriorates mu more slowly with increasing filler loading levels. The most pronounced decay of opacifying efficacy wi increasing filler-loading level has been observed with inheren ly very fine titanium dioxide pigments. Thus, the opacity handsheets prepared under conditions similar to those describ in Example III increased by 4.8 percentage-points above th of unfilled control sheets when the relative content of titani dioxide in the sheet was increased from 0% to 1%, by weight, b only by 0.6 percentage-points when above relative content w increased from 9% to 10%, by weight. In graphical terms th means that a curve representing opacity of Ti0 2 -filled shee as a function of loading level ascends initially very steepl but then flattens rapidly, as the filler-loading level of t sheet increases. The latter is understandably the chief reas why this expensive pigment is rarely used at loading levels excess of 2 or 3 %. By comparison, analogous curves represen ing the opacity of handsheets filled with structural aggrega filler pigments of the present invention as a function of fill loading level ascend initially at significantly lower rates th those obtained with titanium dioxide, but retain steeper slop at higher filler-loading levels, particularly those exceedi considerably 10 or 15%. This slow decline of opacifying pow with increasing filler-loading level combined with low fib debonding, very low abrasiveness and high first-pass retentio make above structural aggregate pigments suited f high-ash filling applications directed toward manufacture very opaque, high-quality, paper products such as could not manufactured heretofore with the aid of pigments and technol gies of the present art. Outstanding results with respect to optical performance ha been obtained with the use of structural composite pigments sy thesized from blends of fine particle size calcined clay a very fine particle size "hydrous" kaolin clays. This can illustrated well with a single example of a composite fill pigment, consisting of 25% fine particle size calcined clay a 75% very fine particle size kaolin clay, by weight, having nea ly the same opacifying power as the fine particle size calcin clay used by itself. "Synergistic" effects with respect to t opacifying power of very-fine-particle-size hydrous clay/fin particle-size calcined clay blends used for the manufacture above composite pigments have been observed with ratios of the two materials ranging from 95:5 to 5:95, by weight. Most i portantly, however, composite pigments made of blends of hydro and calcined clays have considerably lower abrasiveness a fiber-debonding tendency than straight calcined clay, hence, m be employed at considerably higher filler-loading levels th the latter pigment by itself, especially with ultrafine polyme emulsion adhesives being built in into aggregate structure. It should be pointed out in this context that aggregation fine particle size calcined clay as the sole mineral compone of structural aggregate pigments is counterindicated. The reas for this is that the above fine particle size calcined clay derived from very fine particle size kaolin clay feeds, ha been exposed already to thermal aggregation during the calcini process, in which the "very fine" particles of the feed beco sintered-on to larger platelets, or sintered to each other in "fine" aggregates. This is comprehended readily by consideri that a typical very fine particle size calcining feed has average particle size ranging from 0.2 u to 0.4 im e.s.d. a virtually no particles larger than 2 jm e.s.d., whereas typic fine particle size calcined clay product has, after the therm aggregation, an average particles size ranging from 0.6 um 0.8 e.s.d. and contains from 2% to 12%, by weight, of part cles larger than 2 um e.s.d., and less than 10%, by weight, particles smaller than 0.2 μm e.s.d. Incomparably more favorable circumstances emerge when inhe ently very fine particle size titanium dioxide pigments beco interspaced ("extended") by, and co-aggregated with, relative much coarser fine particle size calcined clays mentioned abov Hence, composite pigments of the present invention whose miner fraction consists of 2% to 50%, by weight, of titanium dioxi pigments with the balance provided by the above-mentioned fi particle size calcined clays, were found to have excellent opt cal performance in paper filling and coating applicatio demonstrating enormous advantages of the instantaneous, indi criminate and complete flocculation (aggregation of fines) well as subsequent irreversible cementation, obtained with t aid of in-situ formed complex functional microgels used in pra ticing the present invention. Particularly outstanding results with respect to optic performance and economy were obtained with composite pigmen consisting of 40% titanium dioxide and 60% fine particle si calcined clay, by weight. The application of this composi pigment, referred to in the following Example IV as "composi pigment (40/60)". as a full-fledged titanium-dioxide substitu in coating formulations for lightweight publication paper is i illustrated below: EXAMPLE IV Two coating formulations were prepared at 60% solids havi compositions shown in Table 1. Table 1 Formulation Ingredients, Control Composite Pig¬ Parts by Weight Formulation ment Formulatio Delaminated Clay 44 44 No. 2 Coating Clay 44 44 Titanium Dioxide (loose) 12 Composite Pigment 40/60 12 Starch 9 The above formulations were applied to a lightweight publicatio base sheet with a basis weight of 32 lb per 3300 sq.ft. using laboratory coating machine. The coated sheets were passed fou times through a laboratory supercalender at 300 pli and 140° F. The resultant data are listed in Table 2. Printing properties of sheets obtained with both above for¬ mulations, such as smoothness, print gloss, optical density and ink show-through, were identical for all practical purposes duplicating the parity of optical properties tabulated above. Example IV shows clearly that titanium dioxide pigment can be substituted on "one-for-one" basis with composite pigments of the present invention containing only a fraction of the expen¬ sive high-refractive index material. Similar one-for-one sub¬ stitution of titanium dioxide with the same composite pigment has been obtained in paper filling applications in a variety of paper products. Still better optical performance has been obtained with identically formulated composite pigment (40:60 Ti02:calcined clay) in which the commercial titanium dioxide component was first subjected to intensive comminution, e.g., with the aid of attrition grinder and zirconia balls with a diameter of approx. 1 mm. As the result of above comminution the diameter of largest particles was reduced to about 0.7 μ , bringing the dimensions of the entire pigment population closer to those needed for optimum light scattering. By contrast, titanium dioxide pigments of the present art contain from 1.5% to 2%, by weight, of par¬ ticles larger than 1 μa. in diameter. It should be emphasized that, the fundamental differences in the method of synthesis itself notwithstanding, there are prin- cipal differences in the composition of matter between titanium dioxide/calcined clay composite pigments disclosed by Wildt in U.S. 3,726,700 and analogous pigments of the present invention. Composite pigments prepared according to Wildt were based on Engelhard's Satintones No. 1 and No. 4, which are substantially coarser and 5 to 10 times more abrasive than fine particle size calcined clays used for synthesis of analogous composite pig¬ ments according to the present invention. Unlike fine particle size calcined clays derived from very fine particle size, poorly crystallized, "gray" clay crudes, Satintone products used by Wildt, intended primarily for paint applications, are obtained by calcining of feeds derived from relatively coarse, highly crystalline, "white" clay crudes. As it is understood readily, other high brightness extender products of appropriate particle size, e.g. synthetic precipi¬ tated minerals, can be used in addition to, or instead of, fine particle size calcined clay for synthesizing titanium dioxide- containing structural composite pigments of the above-described type. It is further advantageous to incorporate at least 2%, by weight, of precipitated calcium carbonate into all composite filler pigments intended for alkaline papermaking applications. Esthetically very pleasing, cream-colored, ultraopaque paper has been obtained with the aid of composite filler pigments con¬ sisting of fine particle size calcined clay and naturally ocur- ring rutile or anatase minerals comminuted intensively to an average particle size smaller than 1 μm. Very best results were obtained, however, with composite pigments containing naturally occurring rutile or anatase comminuted to a particle size 100% finer than 0.7 u , or even 0.6 um, whose opacifying power was found to be 5 to 6 times higher than that of commercial white titanium dioxide pigments. Because of their extraordinary color¬ ing power, intensively comminuted naturally occurring rutile an anatase incorporated into structural aggregate pigments becom practically useful at concentrations lower tv-»n 1%, by weight. For applications which require both very high level of opacification and intensive coloring, the relative content o intensively comminuted rutile and anatase in structural compos ite pigments may be increased to 50%, by weight. The highest levels of opacifying efficacy have been obtaine thus far by incorporation of specially prepared dispersions o carbon black, along with suitable combinations of blue and re (violet) dyes, into the aggregate pigment structure. With man important paper products, such as newsprint, lightweight publi cation paper, or the groundwood-containing portion of No. merchant papers, the brightness requirements range merely fro 58% to 75%, whereas the brightness of most commercial filler ranges from 85% to 99%. The superfluous sheet brightness re sulting from application of fillers which are much brighter tha the cellulosic fibers is now routinely toned down with the us of black dyes, such as nigrosine. The use of latter dyes pro vides some limited improvement of sheet opacity but often lead to objectionable hue of the end product and other technical pro¬ blems, e.g., poor ink holdout resulting in excessive ink strike- through during printing. By contrast, structural aggregate pig- ents containing built-in carbon black and properly balance blue and red dye combinations provide considerably higher opaci fying effects at equivalent levels of sheet brightness and, a the same time, make possible to control precisely the hue, a well as improve ink holdout, of the end product. Elementary particle dimensions of the finest commerciall available carbon black products are on the order of 9 nm, bu even the best carbon black dispersions of the present art con tain these elementary particles in the form of "undispersable multi-particle aggregates. According to paper industry's commo experience, aqueous dispersions of such fine carbon black used for opacifying purposes in combination with white pigment are from 100 to 150 times more opacifying than titanium dioxid pigments. By contrast, specially prepared dispersions of carbo black incorporated into structural aggregate pigments of th present invention are from 2000 to 5000 times more opacifyin than titanium dioxide pigments. To attain above levels of opaci fying efficacy, commercially available aqueous dispersions o carbon black must be de-agglomerated into elementary particle with the use of a special method developed by the Applicant, re ferred to in the following Claims as the "masterbatch." Accord ing to this masterbatch method, an auxiliary aqueous dispersio of mineral pigment, such as hydrous or calcined clay, or preci pitated silicate, is first prepared at highest possible solid attainable with the aid of "heavy-duty" industrial mixing o kneading equipment. For example, aqueous slurries of kaolin cla should be prepared at solids levels ranging from 78% to 82%, b weight, which generates excessive heat and requires jacket coo ing of mixing vessels. Conventional aqueous dispersions of ca bon black, such as are possible to prepare by procedures of t present art, are then incorporated under maximum shearing in the auxiliary concentrated pigment slurries mentioned to bre down aggregates of elementary carbon black particles and fo completely uniform pastes. Since these auxiliary slurries m become fluid upon introduction of the conventional carbon bla dispersions, some additional dry pigment must be added to t system to restore its consistency to the previous level. The r sultant, de-agglomerated, carbon black masterbatch is used the preparation of structural aggregate pigments in essential the same manner as other predispersed pigmentary raw materials The opacifying power of structural aggregate pigments con¬ taining carbon black de-agglomerated by the above-described ma terbatch method is demonstrated in the following example: EXAMPLE V A set of control handsheets, designated as Sheets A-l a A-2, filled with titanium dioxide pigment was prepared usi a conventional acidic papermaking process. A parallel set of handsheets, designated as Sheets B-l a B-2, was filled with a composite pigment, synthesized by t procedure described in Example I, consisting of 40 parts tita ium dioxide, 60 parts calcined clay, 0.12 parts carbon bla (active basis) , and 2 parts ultrafine polybutylacrylate emulsi adhesive. The handsheets B-l and B-2 were prepared with the a of the alkaline papermaking process developed by the Applican and disclosed in co-pending patent application (Serial No. 0.7/165,759 ? Filed: March 9, 1988 ). Optical data obtained with both above sets of handsheets intended for satutation with melamine-resin solutions, are pre sented in Table 3. Table 3 SHEET DESIGNATION SHEET PROPERTIES MEASURED A-l A-2 B-l B-2 Basis Weight, lb/3000 sq.ft. 54.3 57.0 54.2 54.8 Filler Content in the sheet, percent by weight 42.0 40.1 37.2 37.5 Net Lbs. of Filler per 3000 sq.ft. 22.8 22.9 GE Brightness, % 93.8 92.3 HUNTER L*a*b: L 97.4 96.8 *a -0.3 -0.4 *b 1.1 1.3 TAPPI Opacity, % Before Saturation 97.2 96.5 99.6 99.0 TAPPI Opacity, % After Saturation 90.9 89.5 98.5 98.6 Opacity Reduction upon Saturation, %-point 7.3 7.0 1.1 0.4 The differences between Sheets B-l and B-2 and control sheet regarding opacity reduction brought about by saturation of th 63 sheets with melamine-resin solutions are striking on the basi of numerical data alone. To appreciate fully the enormous ga between opacity of 99.6% or 99.0% for unsaturated Sheets B-l an B-2 containing the composite filler, and opacity of 97.2% o 96.5% for corresponding control sheets A-l and A-2, listed i Table 3, an additional demonstration will be helpful. Hence, another set of titanium-dioxide filled sheets, equivalent to th control sheets designated as A-l and A-2 in Table 3, was pre- prepared to assess quantitatively the spectacularly high level of difficulty in obtaining even a minute incremental opacity in¬ crease within the range of very high opacity values. Since tita¬ nium dioxide is the principal opacifier in the above, highl loaded, sheets, its concentration has been expressed directl in terms of net content in lbs. per 3000 sq. in the following Table 4. Table 4 Basis Weight, Net Ti0 2 Content, TAPPI Opacity, lbs/3000 ft 2 llbbss//33000 ft 2 % opacity increase: (+ l.nn -t-prvth) As shown by data in Table 4, doubling (folding) of Sheet A with opacity of 98.38% provides an incremental opacity increase of a mere 1.06 percentage-point, analogous doubling of Sheet B with opacity of 98.24% providing similarly an incremental opaci¬ ty increase of a mere 1.0 percentage-point. With a triple stack of sheets obtained by doubling Sheet A and adding a single ply of Sheet B, with a combined basis weight of 182.9 lbs/3000 sq. ft., and a net Ti0 2 content of 94.8 lbs/3000 sq.ft, the incre¬ mental opacity increase was still lower, namely, 0.12 percentage point above the opacity of doubled Sheet A (to a resultant level of 99.56%), demonstrating clearly the enormous difficulties, mentioned previously, associated with gaining incremental opac¬ ity increase within the interval of high opacity values. Shown clearly by data in Table 3, on the other hand, a single sheet (A-l) with a basis weight of 54.2 lbs/3000 sq.ft., with a net content of 20.1 lbs/3000 sq.ft. of composite filler pigment con¬ sisting of only 40% titanium dioxide (amounting to 8 lbs. Ti0 2 per 3000 sq. ft) had an unusually high opacity of 99.6% combined with a brightness of 62.7%, such as would be considered respec¬ table with even high quality newsprint. The enormous opacifying power of the type of composite pigments described in Example V makes it particularly well suited for newsprint filling applications. As is well known by those skil¬ led in the art, the basis weight of newsprint is declining steadily from a 36 lbs/3000 sq.ft. standard prior to 1973 to 30 lbs/3000 sq.ft., and even 28 lbs/3000 sq.ft., in recent years. Extensive research work is going on worldwide to lower this basis weight still further, preferably to 26 lbs/3000 sq.ft. The principal difficulty in reaching the latter goal is that newsprint opacity should range optimally from 92% to 95% for adequate printing results, yet such high levels of opacity are difficult to maintain systematically even with present newsprint of heavier basis weight. A significant relaxation of newsprint opacity specifications is unthinkable, however, in that this would necessitate a gigantic task of developing entirely new printing technology. The general consensus is that future, ultralightweight, generation of newsprint will rely on the use of the most opacifying filler systems available, at substantial¬ ly higher loading levels than are employed presently. The best such filler system of the present art, both from the standpoint of opacifying power and economy, consists of 30 % titanium dio¬ xide and 70 % calcined clay, by weight. The above system is highly abrasive and debonding, however, and almost 35 %-point brighter than present-day newsprint whose brightness ranges from 59% to 62%. Using Ti0 2 /calcined clay blend would thus necessi¬ tate extensive dying-back of the sheet with the aid of organic dyes which, as previously mentioned, drastically reduce news¬ print's ink holdout when deposited on cellulosic fibers, the detrimental esthetic side effects notwithstanding. Realistically, however, the opacifying power of Ti0 2 /calcined clay blend is simply too low to compensate effectively for the reduction of basis weight with ultralightweight newsprint, even if used above practically acceptable filler-loading levels. It should be borne in mind, though, that many newsprint mills do not have water treatment facilities, hence, are not capable of using fillers at loading levels above 2% of the fiber mass. The problem is compounded further by the fact that newsprint inks, which are immobilized by absorption, require a certain minimum of fiber/filler bulk, i.e., minimum adequate sink capacity for containment of ink, such as may be expressed in terms of surface area and pore volume per unit of newsprint mass. In the absence of adequate sink capacity, a disastrous ink strike-through will occur. There appears to be nothing within the scope of materials and technologies of the present art capable of dealing with the above-mentioned problems. Experimental data obtained during evaluation of structural aggregate pigments of the present in¬ vention indicate clearly, however, that a satisfactory solution to these problems can be obtained with the aid of appropriately formulated composite fillers, e.g., such whose mineral portion consists of 40% titanium dioxide and up to 25% high-specific- surface-area bentonite (montmorillonite) with fine particle size calcined clay making up the mineral balance, further containing appropriate dose of built-in cellulosic microfibrils along with up to 0.12 parts of specially de-agglomerated carbon black, and up to 5 parts of ultrafine polymer-emulsion adhesives, per 100 parts of mineral components. While certain preferred practices and embodiments of the present invention have been set forth in the foregoing specifi¬ cation, it is understood readily by those skilled in the art that other variations and modifications may be employed withi the scope of the claims to follow.

Claims: What is claimed is: 1. A process for the manufacture of single-component an multicomponent structural aggregate pigment products fro particulate matter treated with complex functional microgels comprising the steps of: (a) preparing, in-situ, a subcolloidal reactive hydroso by blending aqueous solutions, one of which contains at leas one compound selected from the group consisting of alkali-meta silicates and quaternary ammonium silicates, and the other o which contains at least one compound selected from the grou consisting of alkali-metal aluminates and alkali-metal zincates each in an aqueous dispersion of quantitatively predominan particulate matter; (b) blending an aqueous solution containing at least on gel-setting agent selected from the group consisting of bivalen and multivalent inorganic salts and organic cationically-activ chemical compounds with at least two reactive groups in eac molecule with the resultant system from step (a) to crosslin the in-situ formed subcolloidal reactive hydrosol and synthesiz said complex functional microgels, wherein the particulat matter floculates instantaneously, indiscriminately an completely to form a structural aggregate pigment product; and (c) recovering said structural aggregate pigment produc from step (b) . 2. The process according to Claim 1, further including th step of dewatering said structural aggregate pigment product. 3. The process according to Claim 2, further includin the step of comminuting said structural aggregate pigmen product. 4. The process according to Claim 1, wherein the silicat is selected from the group consisting of sodium and potassiu silicates and quaternary ammonium silicates, the aluminate i selected from the group consisting of sodium and potassium alu minates, and the zincate is selected from the group consistin of sodium and potassium zincates. 5. The process according to Claim 1, wherein the bivalen and multivalent inorganic salts employed are selected from th group consisting of water-soluble, essentially colorless, salt of calcium, magnesium, barium, aluminum, zinc and zirconium. 6. The process according to Claim 1, wherein the compoun selected from the group consisting of alkali-metal silicates an quaternary ammonium silicates is present in the reaction mediu at concentrations ranging from 0.1% to 2.0%, by weight. 7. The process according to Claim 1, wherein the at leas one compound selected from the group consisting of alkali-meta aluminates and alkali-metal zincates is present in the reactio medium at concentrations ranging from 0.1% to 2.0%, by weight. 8. The process according to Claim 1, wherein sai bivalent and multivalent inorganic salts are introduced into th system resulting from step (a) , to crosslink the in-situ forme subcolloidal reactive hydrosol, in amounts ranging from 0.5% to 10.0% of the total mass of particulate matter. 9. The process according to Claim 1, wherein sa organic, cationically-active, chemical compounds with at lea two reactive groups in each molecule are introduced into t system resulting from step (a) , to crosslink the in-situ form subcolloidal reactive hydrosol, in amounts ranging from 0.1% 5.0% of the total mass of particulate matter. 10. The process according to Claim 1, wherein the dispe sion of particulate matter contains from 0.1% to 5.0%, weight, of organic, alkali-compatible, anionic polyelectrolyte 11. The process according to Claim 1, wherein carbon bla and color dyes are incorporated into the aqueous dispersion particulate matter in step (a) together with at least o material selected from the group consisting of convention polymer-emulsion (latex) adhesives. 12. The process according to Claim 11, wherein the adhe sive is an ultrafine polyacrylic-e ulsion adhesive. 13. The process according to Claim 1, wherein resultant p of the flocculated aqueous dispersion of particulate matter after completion of step (c) , ranges from 3.5 to 12. 14. The process according to Claim 1, wherein the ratio o silicate to at least one compound selected from the group con sisting of aluminates and zincates in step (a) ranges from 10: to 1:10, by weight. 15. A continuous process employing in-line mixers-reactor for synthesizing structural aggregate pigments from particulat matter treated with functional complex microgels according t Claim 1, comprising the steps of: (a) blending and homogenizing component aqueous disper sions of particulate matter; (b) injecting soluble adjuvants continuously into th in-line stirred system resulting from step (a) ; (c) continuously metering-in solutions of reagents int the in-line stirred system resulting from step (b) to form subcolloidal reactive hydrosol, said reagents being selecte from a first group consisting of alkali-metal silicates an quaternary ammonium silicates and a second group consisting o at least one reagent selected from the group consisting o alkali-metal aluminates and alkali-metal zincates. (d) continuously metering-in a solution of at least on gel-setting agent selected from the group consisting of bivalen and multivalent inorganic salts and organic cationically-activ chemical compounds with at least two reactive groups in eac molecule into the in-line stirred system resulting from step (c to form a structural aggregate pigment product; and (e) continuously recovering said structural aggregat pigment product from step (d) . 16. A process for the manufacture of single-component an multiple-component structural aggregate pigment products fro particulate matter treated with functional complex microgels comprising the steps of: (a) adding a solution of at least one gel-setting agen selected from the group consisting of bivalent and multivalen inorganic salts and organic cationically-active chemica compounds with at least two reactive groups in each molecul into an " aqueous dispersion of quantitatively predominan particulate matter; (b) preparing a subcolloidal reactive hydrosol b blending an aqueous solution of a compound selected from the group consisting of alkali-metal silicates and quaternary ammo¬ nium silicates with an aqueous solution containing at least one compound selected from the group consisting of alkali-metal aluminates and alkali-metal zincates; (c) blending the systems resulting from steps (a) an (b) to synthesize in situ said complex microgels, wherein th particulate matter flocculates instantaneously, indiscriminatel and completely to form a structural aggregate pigment product; and (d) recovering said structural aggregate pigment pro duct from step (c) . 17. The process according to Claim 16, further includin the step of dewatering said structural aggregate pigmen product. 18. The process according to Claim 17, further includin the step of comminuting said structural aggregate pigmen product. 19. The process according to Claim 16, wherein predeter mined amounts of acidifying agents are added to the aqueou dispersion of particulate matter in step (a) , such as t maintain the final pH of said dispersion flocculated in step (c) by addition of subcolloidal reactive hydrosol from step (b) at a level of from 3.5 to 12. 20 The process according to Claim 16, wherein th bivalent and multivalent inorganic salts employed are selecte from the group consisting of water-soluble, essentially color less, salts of calcium, magnesium, barium, aluminum, zinc an zirconium. 21. The process according to Claim 16, wherein sai bivalent and multivalent inorganic salts employed are present i the reaction medium in amounts ranging from 0.5% to 10.0% o the total mass of particulate matter. 22. The process according to Claim 16, wherein sai organic, cationically-active, chemical compounds employed ar present in the reaction medium in amounts ranging from 0.1% t 5.0% of the total mass of particulate matter. 23. The process according to Claim 16, wherein sai hydrosol-forming reagents employed are selected from a firs group consisting of sodium, potassium and quaternary ammoniu silicates and a second group consisting of sodium and potassiu aluminates and sodium and potassium zincates. 24. The process according to Claim 16, wherein the compoun selected from the group consisting of alkali-metal silicates an quaternary ammonium silicates is present in the reaction mediu at concentrations ranging from 0.1% to 2.0%, by weight. 25. The process according to Claim 16, wherein the at leas one compound selected from the group consisting of alkali-meta aluminates and alkali-metal zincates is present in the reactio medium at concentrations ranging from 0.1% to 2.0%, by weight. 26. The process according to Claim 16, wherein the rati of silicate to the at least one compound selected from the gro consisting of aluminates and zincates in step (b) ranges fr 10:1 to 1:10, by weight. 27. The process according to Claim 16, wherein carb black and color dyes are incorporated into the aqueous dispe sion of particulate matter in step (a) together with at lea one material selected from the group consisting of convention polymer-emulsion (latex) adhesives. 28. The process according to Claim 27, wherein the adhesi is an ultrafine polyacrylic-emulsion adhesive. 29. The process according to Claims 11, 12, 27 or 2 wherein the carbon black dispersion employed is de-agglomerat by the masterbatch method. 30. The process according to Claim 16, wherein the resu tant pH of the flocculated dispersion of particulate matt after completion of step (c) ranges from 3.5 to 12. 31. A process for the manufacture of single-component a multicomponent structural aggregate pigment products from pa ticulate matter treated with functional complex microgels, co prising the steps of: (a) preparing a subcolloidal reactive hydrosol by blen ing a first aqueous solution of a reagent selected from t group consisting of alkali-metal silicates and quaterna ammonium silicates with a second aqueous solution containing least one reagent selected from the group consisting of alkal metal aluminates and alkali-metal zincates; (b) blending an aqueous solution containing at least o gel-setting agent selected from the group consisting of bivale and multivalent inorganic salts and organic cationically-acti chemical compounds with at least two reactive groups in ea molecule with the subcolloidal reactive hydrosol from step (a to synthesize in situ said complex microgels; (c) blending the system resulting from step (b) wi an aqueous dispersion of quantitatively predominant particula matter, wherein said dispersion flocculates indiscriminately a completely to form a structural aggregate pigment product; an (d) recovering said structural aggregate pigment produ from step (c) . 32. The process according to Claim 31, further includi the step of dewatering said structural aggregate pigme product. 33. The process according to Claim 32, further includi the step of comminuting said structural aggregate pigme product. 34. The process according to Claims 1, 15, 16 or 31 where the flocculated structural aggregate pigment products are fi tered by a combination of vacuum and pressure filtration and a processed by a combination of flash drying and comminution.

Inventors: KALISKI ADAM F, KALISKI, ADAM, F.
Applicants: IND PROGRESS INC, INDUSTRIAL PROGRESS, INC.
Application year: 1990
Main classification: C04B20
IPC codes: B01J2, C09B67, C09C1, C09C3, D21H17, D21H19