GELS

Abstract: Gels of hard-elastomer-hard block copolymers with at least 300 parts of extender liquid per 100 parts of the copolymer contain at least 50 parts (per 100 parts of copolymer) of a stabilising additive which resists migration of PVC plasticisers into the gel when in contact with a plasticised PVC article. Styrene-(ethylene-butylene)-styrene triblock copolymers with organic phosphate stabilisers are preferred, these stabilisers tending to raise the gel softening temperature.

Description: "GELS" This invention relates to a gel composition, by which is meant a liquid-extended polymer composition having a cone penetration value (measured by a modified version of AST D217, as described below) within the range from 50 to 400 (10-1 millimetres); and preferably an ultimate elongation (measured by ASTM D412 as described below) greater than 100%, with substantially elastic deformation to an elonga¬ tion of at least 100%; ultimate tensile strength (ASTM D412) less than 1 MegaPascal; and dynamic storage modulus (as hereinafter described) less than 50000 Pascals. The com¬ position may either contain a three-dimensional network of cross-linked molecular chains (gels) or may merely behave as if it contained such a network (gelloids). Oil-extended compositions of block copolymers are known, for example from U.S. Patents 3676387(Lindlof) , 3827999 (Crossland), 4176240 (Sabia), and 4369284 (Chen), and published International Patent Application O8800603, and it has previously been found necessary to subject copolymer-oil adhesive compositions to radiation cross-linking in order to modify their physical and adhesive properties, as described for example in European Published Patent Application 0224389 (Rayche , Gamarra), U.S. Patents 3845787 (Haefele) and 4151057 (St Clair) and in "Radiation Curing of PSA's Based on Thermoplastic Rubbers" by D.J. St. Clair, in Adhesives Age, March 1980, pages 30-36. The present invention improves the characteristics of gel or gelloid compositions(hereinafter referred to simply as "gels") without the problem of crosslinking. A further problem arises when gels are placed in surface contact with plasticised PVC articles, such as electrical cable jackets for example, since the PVC plasticiser tends to migrate into the gel, thus embrittling the PVC article. _ _. — and possibly also degrading the gel. The present invention is capable of alleviating this problem, and in some cases may furthermore improve the properties of the gel. The invention accordingly provides a gel or gelloia liquid- extended polymer composition having (i) an ASTM D217 cone penetration value within the range from 50 to 400 (10--- millimetres), (ii) an ASTM D412 ultimate elongation greater than 100% with substantially elastic deformation to an elongation of at least 100%, (iii) and ASTM D412 ultimate tensile strength of less than 1 MegaPascal, and (iv) a dyna¬ mic storage modulus at 23°C of less than 100000 Pascals; the composition comprising an intimate mixture of (a) at least one block copolymer containing relatively hard blocks and relatively elastomeric blocls; (b) at least 300 parts by weight of extender liquid per 100 parts by weight of the said copolymer(s) , which liquid extends and softens the said elastomeric blocks; and (c) at least 50 parts by weight per 100 parts by weight of the copolymer(s) (a), of a plasticiser-stabilising addi¬ tive (which preferably does not significantly depress the softening temperature of the composition), comprising (i) a stabilising material capable of either establishing substantial equilibrium with, : resisting migration into the composition of, one or more PVC plasticisers of a plasticised PVC article with which the composition in use is to be placed in surface contact, and either the stabilising material (i) raises or does not significantly depress the softening temperature of the composition, in which case the additive (c) may optionally include (ii) a temperature-raising material which raises the softening temperature of the composition. - 3 - or the stabilising material (i) significantly depresses the softening temperature of the composition, in which case the additive (c) includes a sufficient quantity of the temperature-raising material (ii) to compensate for at least 50% (preferaDly at least 75%, more preferably at least 90%, and especially substantially 100% or mor# ^ of the depression caused by the stabilising material. A "significant" depression of the softening point (hereinafter Ts) may be regarded as more than about 5°C for example, although this working guideline may vary in accor¬ dance with circumstances, such as the range of temperatures over which the gel is intended to operate. In its preferred emoodiments, the invention is particularly concerned with gel or gelloid compositions in which the gel- forming polymer mainly (more than 50%, preferably more than 90%, especially 95-100%, of the total polymer) comprises the block copolymer materials having relatively bard blocks and relatively elastomeric blocks (e.g. hydrogenated rubber blocks). Especially interesting block copolymers for the purposes of this invention are those wherein the hard blpcks comprise polystyrene. The weight ratio of the hard blocks to the elastomeric blocks in those (and other) copolymers is preferably within the range from 0.25:1 to 0.75:1. The elastomeric blocks preferably comprise a polyalkylene material, preferably a hy rogenated rubber. Examples of such styrene-alkylene block copolymers include styrene- alkylene-styrene triblock copolymers such as styrene-dieαe tri-block copolymers (linear or radial), for example styrene-butadiene-styrene or styrene-isoprene-styrene or styrene-(ethylene-butylene)-styrene triblock copolymers. Among such block copolymers useful in the present invention are the hydrogentated styrene-diene block copolymers in which the styrene blocks have a molecular weight within the range from 2000 to 50000 and the diene blocks have a molecu¬ lar weight within the range from 20000 to 300000. Preferred are those having at least two styrene end-blocks and at least one diene mid-block, the styrene end blocks comprising up to 55% by weight of the block copolymer. Examples include poly(styrene-ethylene-butylene-styrene) _ triblock copolymers generally referred to as SEBS triblock copoly¬ mers. These copolymers have styrene end blocks and ethylene and butylene centre blocks and are characterised by the ratio of styrene blocks to the combined ethylene-butylene blocks. Blends of two different SEBS triblock copolymers e.g. as described in European Published Patent Application 0224389 (Gamarra), the disclosure of which is incorporated herein by reference, can be used to provide oil-extended elastomeric gels according to this invention having certain desired cone penetration, elongation and tensile strength properties. Other styrene-diene block coploymers useful in compositions of this invention include poly(styrene-butadiene-styrene) block copolymers (SBS), polγ(styrene-isoprene-styrene) block copolymers (SIS) and similar known styrene-diene block copo¬ lymers. The SEBS block copolymers are preferred. The copo¬ lymer material (a) may comprise mixtures of two or more block copolymers. Additional polymers which may be mixed with styrene block copolymers are polyphenylene ethers (PPO), for example poly(2,6-dimethyl-l,4-phenylene)ether, which have substan¬ tially complete compatibility with the polystyrene blocks and may improve the temperature resistance of the gels. The advantages of such mixtures are described in the aforemen¬ tioned O8800603, the disclosure of which is incorporated herein by reference. Preferably at least one (preferably all) material of the additive (c), and preferably also of the extender liquid (b), is (are) substantially incompatible with the copolymer hard blocks. Preferably, at least one of the materials (i) and (ii) of the non-polymeric additive has a solubility parameter (calculated from Small's group molar attraction constants) of at least 9, preferably within the range* from 9.0 to 10.6, more preferably 9.58 to 10.55, and especially 10.00 to- 10.52, [cal/cm 3 ]- ' 5 . This preference is explained with reference to the following list of 24 additive materials ranked in order of their solubility parameters (S.P.) and showing the resulting gel softening temperature (Ts) in gels formed by methods hereinafter described from 7.5% by weight Kraton G1651 SEBS copolymer, 20.0% by weight additi e material, 1.0% by weight Irganox 1010 (TM, CIBA) antioxi- dant, and 71.5% by weight Fina Vestan A360B (TM, Fina Chemicals) paraffin/naphthene oil extender. Ts of the gel with the additive material replaced by more of the oil is 120°C. MATERIAL 1. Butyl carbitol adipate. 2. Epoxidised soybean oil (TM "Estabex 2381") 3. Epoxidised oil (TM "Kodaflex TXIB") 4. Trioctyl phosphate 5. Epoxidised oil (TM "Flexol 4GO") 6. Ester plasticiser (TM "Bisoflex DOP") 7. Ester plasticiser (TM "Bisoflex TOT") 8. Triethyl phosphate 9. Dibenzofuran 10. Diethylene glycol monobutyl ether 11. Tris(l-chloroprop-2-yl)phosphate 12. Triphenyl phosphate(s) 13. 2,2-oxybis(ethanol)dibenzoate 14. Tris(1-chloroethyl)phosphate 15. 2,2-bis(chloromethyl)-1,3-propylene-bis (2-chloroethyl)phosphate 16. Tris(1 ,3-dichloropropyl)phosphate 17. Polyethylene glycol 200 18. Glycerol monoacetate 19. Diphenyl sulphone 20 E-caprolactam - - 21. Propylene carbonate 13.30 145 22. Tetramethylene sulphone 13.40 148 23. Dimethyl sulphone 14.50 125 24. Ethylene carbonate 14.70 135 The commercially available materials used for some of these additives, which are thought to have the chemical content indicated above, are as follows: 1. Bisoflex 111 (TM) from British Petroleum. 2. Estabex 2381 (TM) from Akzo Chemie. 6. Bisoflex DUP (TM) from British Petroleum. 7. Bisoflex TOT (TM) from British Petroleum. 11. Tolgard TMCP (TM) from Tenneco Organics Ltd. 13. Benzoflex 245 (TM) from Velsicol Chemical Corporation. 14. Genemol P (TM) from Hoechst. 15. Tolgard V6 (TM) from Tenneco Organics Ltd. 16. Tolgard TDCP (TM) from Tenneco Organics Ltd. It is observed that materials 1 to 10, with the . exception of material 8, severely depressed Ts. Many of these materials are known as PVC plasticisers, and so may have a useful equilibrium-forming stabilising effect when used as material (i) of additives according to this invention, together with a temperature-raising material (ii). Materials 8 and 11 to 16 were all found, in separate tests, to have a stabilising effect due to their resistance to migration of PVC plastici¬ sers into the gel (hereinafter "plasticiser resistance") and could accordingly be used alone as the stabilising material (i) of the additive. Materials 8 and 11 had only an insignificant effect on Ts, whereas materials 12 to 16 significantly raised Ts and could thus also be used as material (ii) of the additive together with stabilising materials (i) for example equilibrium-forming plasticisers .such as materials 1 to 7, 9 and 10. Such material (ii) could compensate for the depression of Ts caused by the stabili¬ sers (i) or could raise Ts in cases where it is unaffected by the stabilisers. For example material 14 could be used to counteract the depressive effect of material 4 * Materials 17 and 18 do not significantly depress Ts, but were found on testing to lack stabilising effect-, and axe thus of no interest for the present invention. Materials 19 to 24 all raise Ts (No.23 barely significantly), but also lack stabilising effect. Materials 19 to 24 could therefore be used as the temperature-raising material (ii) of the addi¬ tive together with suitable stabilising materials (i) to compensate for depression of Ts, or to raise Ts, as afore¬ said. However, it is found in practice that materials 19 to 24, all of which are solids at room temperature, tend to separate out of the gel composition, with resultant effects on the appearance, and perhaps the performance, of the gels, which may be unacceptable for some end uses. It is accor¬ dingly preferred that at least one (preferably both) of the materials (i) and (ii) (when present) of the additive is (are) liquid at room temperature and miscible with the extender liquid (b). However, solid materials such as materials 19 to 24 may still be useful for some purposes, especially if they have good solubility in the extender liquid. It can thus be seen that aforementioned ranges of solubility parameter provide a useful guide to selection of additive materials, within which guideline suitability of materials is readily determined by simple trial-and-error testing of their effect on Ts and their stabilising effect compared w h a control containing no such additive. Plastic ser- cabilising effect can be tasted, for example, by encap¬ sulating weighed plasticised PVC samples in a gel containing the additive to be tested, for example in the aforementioned proportions, and maintaining the encapsulated samples at 70°C for suitable periods, e.g. a week or a fortnight or two. After removal from the gel, which usually peels cleanly from the sample surface, the samples are re-weighed, and any loss of weight may be compared with that of the control to see if the additive reduces the degree of loss of the PVC plasticiser into the gel. The additive materials having solubility parameter (S.P.) greater than 9 will not only preferably be liquids as afore¬ said but will also preferably exclude oxygen-heterocyclic aromatics (material 9); alkanols; and glycols and polyols and their mono-ethers and mono-esters (e.g. materials 10, 17, 18). Materials of S.P. below 9 tend to depress Ts (e.g. materials 1 to 7, 9, 10), while materials of S.P. above 10.6 may tend to have problems as indicated above for materials 17 to 24. Within the preferred range of S.P. from 9 to 10.6, S.P. of 9.58 to 10.55 excludes the short chain alkyl phosphate material 8, while the range of S.P. from 10.00 to 10.52 includes the most beneficial materials 12 to 16, most of which are organic phosphates, as is preferred. Halogenated (preferably chlorinated) or unhalogenated phosphates e.g. alkyl phosphates having up to 6, preferably up to 4 carbon atoms in each alkyl group, and aryl phospha¬ tes, are especially preferred. Materials containing polar carbonyl or sulpho groups may also be desirable for raising Ts, in view of the results achieved by materials 13 and 19 to 24. Mixtures of materials (i) and mixtures of.materials (ii) may be used if desired. Although the present invention does not necessitate cross- linking, cross-linking of the composition may still be effected if desired, and may produce further improvements in properties. Within -the specified range of properties for the gels and gelloids according to this invention, those having an ulti- mate elongation of at least 200% are preferred. Substantially elastic deformation (or substantially no hysteresis) up to an elongation of at least 200% is also preferred. Mixtures comprising less than 300 parts, especially 2QQ parts or less, of the extender liquid, e.g. as in the hot. melt adhesives described in US Patents 4141876 and 4104323, per 100 parts of block copolymer, generally do not behave as gel or gelloid compositions. Such mixtures tend to be too hard and to have too high an ultimate tensile strength arid dynamic storage modulus, especially when tackifyihg resirfe are added. Preferred gel or gelloid compositions according to the pre¬ sent invention either have a cone penetration value within the range from 200 to 400 (10-1 millimetres ) ( "soft" gels ) , and comprise preferably at least 567, and preferably not more than 5000 parts by weight of the extender liquid per 100 parts by weight of the polymer; or have a cone penetra¬ tion value within the range from 50 to 199 (10" *1 milli¬ metres) ("hard" gels), and comprise pre*^rably 300-566 parts by weight of the extender liquid per 10C parts of the polymer. The extender liquid preferably has a boiling point higher than the softening or melting temperature of the gel copo¬ lymer, and the extender liquid is preferably mixed with the copolymer at a temperature not less than its melting or sof¬ tening temperature. Mastication or otijer mixing techniques at lower temperatures, perhaps with the aid of volatile solvents, may however be used if the resulting composition is acceptable for the intended end use. The extender liquids useful in the compositions of this invention comprising the block copolymer and plasticiser- stabilising additive as aforesaid may be selected from oils conventionally used to extend elastomeric materials. The oil may be a hydrocarbon oil such as paraffinic or naphthe- nic oils, synthetic oils such as polyoutene or polypropεne oils, and mixtures thereof. The preferred oils are substan¬ tially non-aromatic mixtures of paraffins and naphthenic hydrocarbon oils. The oils should have a minimum boiling point higher than the softening point of the block copolymer(s) . Examples of suitable oils include those available from Fina Chemicals under the Trade mark "Fina Vestan" in grade A360B (preferred), " Drakeol 34" from Penreco, and "Witco 380PO" from Witco. The ratio of polymer to the oil will generally range from 2 to 30 parts polymer mixture to 70 to 98 parts oil. In general, for "soft" gels, it is preferred to use 3 to 15 parts of the block copolymer with 97 to 85 parts oil and most preferred for many applications to use from 4 to 12 parts of the block copolymer, with 96 to 88 parts oil. For "hard" gels, a ratio of 15 to 30 parts of the block copo¬ lymer, most preferably from 18 to 25 parts, with the balance oil, is preferred. The compositions of this invention are preferably prepared by mixing the oil with a blend of the polymer(s) and the additive material(s) at a temperature not less than the glass transition temperature of the hard blocks in the said block copolymer. The glass transition temperature of the hard blocKs may have been raised by blending with PPO as described in the aforementioned W08800603). In order to achieve adequate mixing and for the polymer(s) to melt fully and disperse in the oil, sufficiently high temperatures and sufficient mixing shear are preferably used. The mixing at the elevated temperature should be continued until the mix¬ ture is uniform and all of the polymers are evenly dispersed or blended in the oil. After sufficient mixing, the com¬ position is then moulded into the desired shapes and allowed to cool. The resulting elastomeric composition can be re- melted and again cooled without any significant change in physical properties. The oils useful in the radiation-cross-linked versions of the compositions of this invention can, for example, be the same oils as above. The cross-linking agents useful in the el* 'tron beam radiation cross-linking of the polymer-oil composition, the amount of cross-linking agent, and the electron beam radiation dosage will depend on the com¬ position, its con iguration and the degree of cros-3-1inking desired, and may be selecteα by the usual criteria, for example along the lines disclosed in the aforementioned European Published Patent Application 0224389. It will be useful to use various additives « $or varϋus pur¬ poses in any of the compositions of this invention. Such additives may be stabilisers, antioxidants, flame retar- dants, tackifiers, corrosion inhibitors and the ' like It is useful to use antioxidants in all the compositions of this invention. The compositions of this invention can be made having a wide range of physical properties, such as cone penetration, ultimate elongation, and tear strength, desirable for par¬ ticular end use applications. The compositions have numerous uses as elastomeric materials and in particular 'may be used as sealing materials, for example as illustrated ^ in published European Published Patent Applications 0108518 and 0191609, although the compositions of this invention will have many and varied uses depending on the properties desired and the temperatures to be encountered. Gel compositions within the scope of this invention are pre¬ ferably defined by the following criteria (1) to (8), of which preferably not more than one criterion (not (1) or (2)) will be outside the specified ranges. These criteria are derived from Tests I to V described in the aforemen¬ tioned W08800603, the disclosure of which is incorporated herein by reference. I. Cone Penetration (1) Cone penetration value in the range 50-400 (1/10 mm). II Tensile Testing (2) Ultimate Elongation greater than 100%. (3) Ultimate Tensile Strength Less than lMPa. III Dvnamic Viscoelastic Properties (23°C). (4) Dynamic Storage Modulus, G' , less than 100,000 Pa at 1Hz, preferably less than 50000 Pa, more preferably 5000 to 15000 Pa at 1Hz. (5) Dynamic Mechanical Damping, Tan Delta, less than 1.00 at frequencies less than 5Hz. IV Dynamic Viscoelastic Properties (80°C). (6) Dynamic Storage Modulus, G', greater than 10 Pa at 1Hz. (7) Dynamic Mechanical Damping, Tan Delta, less than 1.00 at frequencies less than 5Hz. V Stress Relaxation. (8) Relaxation Time greater the 900 seconds. The softening point (Ts) of the gel compositions increases as the proportion of temperature - raising additive increases. Preferably, the amount of additive is at least 3%, preferably at least 5%, and not more than 25% by weight of the whole gel composition, more preferably 10 to 15 weight per cent. Softening point of the gel compositions is determined by standard Thermal Mechanical Analysis Techniques, such as the duPont TMA using a load of 5 grammes and a heating rate of 5°C per minute. By way of illustration the general method of preparation of the gels using the listed additive materials according to this invention will now be described. MATERIALS - 150g containing: 7.5% w/w Kraton G1651 copolymer 20.0% plasticiser 1.0% Irganox 1010 antioxidant 71.5% A360B paraffin oil extender. The materials were stirred cold, under nitrogen, for at least 30 minutes in order to flush the flask of air and allow the copolymer to absorb some of the oil. Heat was applied steadily until considerable swelling occurred and the mixture became very viscous (depending on the plasti¬ ciser this could occur at any temperature in the range 80-180°C). Heat was then applied with caution and was main¬ tained until a homogeneous, molten gel containing no undissolved copolymer was observed or up to a maximum tem¬ perature of 220°C. Heating and stirring were stopped and after the gel had become cold and set, the flask was unco¬ vered and the gel removed intact. The gels of this invention may be especially useful when used as a sealant in an electrical connection terminal enclo¬ sure, cable splice, or cable termination, or in a kit or com¬ ponent for making such an enclosure, splice, or termination. Examples of gel compositions specifically formulated for such purposes will now be described in percentages by weight. Example A Example B Kraton G1651 8.5 8.5 Indopol H300 20 20 (polybutene-isoprene tackifier) Fina A360 oil 54.88 54.88 Genemol P 5 5 (phosphate) Bisoflex TOT 10 5 (ester-type plasticiser) Bisoflex 234 - 5 (ester-type plasticiser) Irganox 1010 0.12 0.12 (anti-oxidant) Irganox 1076 1.0 1.0 (anti-oxidant) Tinuvin 327 0.5 0.5 (UV Stabiliser) "Indopol H300" (TM) is available from Amoco Chemicals. "Bisoflex 234" (TM) is available from British Petroleum. "Irganox 1076" (TM) , and "Tinuvin 327" (TM) are available from Ciba-Geigy. The other materials have been referred to earlier herein. The Ts of these gels was 128°C for example A and 124°C for the example B, compared with Ts of 125°C for the same gel replacing the Genemol and Bisoflex additives with a corresponding additional amount of the oil. The gels preferably contain at least 75 parts by weight (more preferably at least 100 parts by weight, especially at least 150 parts by weight, and in some cases even 200 or more parts by weight) of the said additive per 100 parts by weight of the block copolymer material (a).

Claims: CLAIMS 1. A gel or gelloid liquid-extended pc ymer composition having (i) an ASTM D217 cone penetration value within the range from 50 to 400 (10 _1 millimetres), (ii) an ASTM D412 ultimate elongation greater than 100% *.ith substantially elastic deformation to an elongation of at least 100%, (lii) and ASTM D412 ultimate tensile strength of less than 1 MegaPascal, and (iv) a dynamic storage modulus at 23 Q C of less than 100000 Pascals; the composition comprising an intimate mixture of (a) at least one block copolymer containing relatively hard blocκs and relatively elastomeric Dlbcks; (b) at least 300 parts by weight of extender liquid per 100 parts by weight of the said copolymer(s) , which liquid extends and softens the said elastomeric blocks; and (c) at least 50 parts by weight per 100 parts by weight of the copolymer(s) (a), of a plasticiser-stabilising addi¬ tive comprising (i) a stabilising material capable of either establishing substantial equilibrium with, σr resisting migration into the composition of, one or more PVC plasticisers of a plasticised PVC article with which the composition in use is to be placed in surface contact, and either the stabilising material (i raises or does not significantly depress the softening temperature of the composition, in which case the additive (c) may - optionally include (ii) a temperature-raising material which raises the softening temperature of the composition, or the stabilising material (i) significantly depresses the softening temperature of the composition, in which case the additive (c) includes a sufficient quantity of the temperature-raising material (ii) to compensate for at least 50% (preferably at least 75%, more preferably at least 90%, and especially suostantially 100% or more) of the depression caused by the stabilising material. 2. A composition according to Claim 1, wherein the copo¬ lymer hard blocks comprise polystyrene. 3. A composition according to claim 1 or 2, wherein the copolymer elastomeric blocks comprise a polyalkylene material, preferably a hydrogenated ruboer. 4. A composition according to Claims 2 " and 3, wherein the copolymer is a styrene-alkylεne block copolymer. 5. A composition according to any of the preceding claims, wherein at least one (preferably all) material of the addi¬ tive (c), and preferably also of the extender liquid (b), is (are) substantially incompatible with the copolymer hard blocks. 6. A composition according to any of the preceding claims, wherein at least one of the materials (i) and (ii) of the said additive has a solubility parameter (calculated from Small's group molar attraction constants) of at least 9. 7. A composition according to claim 6, wherein the said solubility parameter is within the range from 9.0 to 10.6 preferably 9.58 to 10.55, more preferably 10.00 to 10.52. 8. A composition according to claim 6 or 7, wherein at least one (preferably both) of the materials (i) and (ii) (when present) of the said additive is (are) liquid at room temperature and miscible with the extender liquid (b). 9. A composition according to any of the preceding claims, wherein the stabilising material (i) of the said additive is a PVC plasticiser and the additive includes the said temperature-raising material (ii). ID. A composition according to claim 7, 8 or 9 wherein either of the materials (i) and (ii) (if present) of the said additive is 2,2-oxybis(ethanol)dibenzoats. 11. A composition according to claim 7, 8, or 9, wherein either of the materials (i) and (ii) (if present) of the said additive is an organic phospnate. 12. * A composition according to claim 11, wherein the phosphate is an alkyl phosphate having up to 6, preferably up to 4, carbon atoms in each alkyl group. 13. A composition according to claim 11, wherein the phosphate is an aryl phosphate. 14. A composition according to claim 11, 12, or 13, wherein the phosphate is a halogenated, preferably chlorinated, phosphate. 15. A composition according to claim 11, wherein the phosphate is triphenyl phosphate, tris(1-chloroethyl)phosphate, 2,2-bis(chloromethyl)-1,3-propylene-(bis(2-chloroethyl)phosphat or, tris(1,3-dichloropropyl)phosphate. 16. A composition according to claim 11, wherein e phosphate is triethyl phosphate or tris(l-chloroprop-2-yl) phosphate. 17. A composition according to any of the preceding claims, comprising 5 to 25, preferably 10 to 15, weight percent of the additive, based on the weight of the whole composition. 18. A composition according to any of the preceding claims whose softening temperature is higher than that of the corresponding gel composition without the said additive. 19. A composition according to any of the preceding claims when used as a sealant in an electrical connection terminal enclosure, cable splice, or cable termination, or in a kit or component for making such an enclosure, splice or ter¬ mination. - IS - 20. A composition according to any of the preceding claims, having an ASTM D217 cone penetration value within the range (a) from 200 to 400 (10"1 millimetres), or (o) from 50 to 199 (10" 1 millimetres). * * * * * * * * * *

Inventors: HUDSON JOHN MICHAEL, SUTHERLAND ALISTAIR ALFRED PRE, HUDSON, JOHN, MICHAEL, SUTHERLAND, ALISTAIR, ALFRED, PRESTON
Applicants: RAYCHEM LTD, RAYCHEM LIMITED
Application year: 1990
Main classification: C08L53
IPC codes: C08K5, C08L27, C08L53, C08L91, C09K3, H01R13