Method and apparatus for storing cryogenic fluids

Abstract: Method and apparatus for preventing loss of liquid cryogen due to heat infiltration into the cryogen stored in a dewar. At least one transient heat shield (34) disposed in the vacuum space between the inner (12) and outer (14) vessels of the dewar in heat exchange with normal cryogenic liquid, cold gas, or supercritical fluid withdrawal means (22, 23) of the stored cryogen, intercepts heat transfer into the stored cryogen.

Description: FIELD OF THE INVENTION This Invention pertains to cryogenic transportation or storage dewars, tanks or containers of the vacuum-jacketed type suitable for transporting or storing cryogenic fluids such as liquid hydrogen or liquid helium. Storage dewars at a user location are subject to withdrawal of the liquid cryogen according to the needs of the user. BACKGROUND OF THE INVENTION Transportation, storage and/or distribution of industrial gases such as oxygen, nitrogen, helium, hydrogen, argon, neon and the like with atmospheric pressure condensation temperatures in the cryogenic range, e.g. below -130°F (-90°C) becomes most economical when the gases are maintained in the liquid phase. In the ordinary course of liquefying the gases, large quantities of refrigeration are necessary. When the liquid is brought to a user's location and placed in a cryogenic storage dewar, the liquid is generally converted to a gas for use by the customer thus releasing refrigeration. Conventional storage dewars dump the refrigeration produced by vaporation of the stored cryogen to the atmosphere. In the case of long term storage of cryogen on a customer site there is the possibility, if the withdrawal rate is not very large, that due to infiltration of heat, stored cryogen will be vaporized inside the dewar and the vapor vented to the atmosphere, thus causing loss of cryogen available for use by the user (customer). For example, when liquid hydrogen is stored in a conventional 5685 dm3 (1500 gallon) cryogenic dewar comprising an inner vessel and an outer vessel with a vacuum space between the inner and outer vessel and the vacuum space containing a conventional multi-layer insulation, in order to prevent loss of stored cryogen by venting, the user must draw off a minimum of approximately 2264 m 3 (80,000 ft 3 ) per month of vapor in order to utilize all of the delivered cryogen. One approach to maintaining liquid Inventory and prevent venting of vaporized cryogen inside the tank is disclosed and daimed in U.S. Patent 3,698,200. Patentees' invention relies upon a heavy radiation shield disposed between the Inner and outer vessel which is cooled by the product as the inner vessel is filled. This technique is used in combination with the conventional multi-layer insulation, vacuum jacketing, and a liquid nitrogen reservoir inside the tank and is particularly adapted for storage of liquefied helium which vaporizes at approximately 4°K. Precooling of the radiation shield according to Patentees is accomplished by allowing a portion of the fluid stored inside the tank to vent during filling to thus precool the radiation shield. DE-A-2,042,869 discloses a dewar for storing or transporting cryogenic fluid of the type containing an outer vessel and an inner vessel disposed therein, said inner vessel including means to admit and withdraw cryogenic fluid from the interior thereof, and insulation between said inner and outer vessels, disposing at least one metallic transient heat shield between said inner and outer vessels, said heat shield containing means to retain refrigeration, said means to retain refrigeration adapted to be contacted by vaporized cryogenic as it is withdrawn from said inner vessel said means to retain refrigeration also include a heat sink in heat exchange with said cryogenic fluid withdrawal means. A similar dewar is disclosed in CH-A-486,662. According to the present invention a dewar for storing or transporting cryogenic fluid of the type containing an outer vessel and an inner vessel disposed therein, said inner vessel including means to admit and withdraw cryogenic fluid from the interior thereof, insulation between said inner and outer vessels, and a metallic heat shield (34) disposed between said inner and outer vessels (12, 14) is characterised by a heat sink (40, 42) in heat-exchange relationship with said shield (34), said heat sink being of metal of high specific heat and high thermal conductivity and of greater mass than the heat shield (34), and withdrawal conduits (22, 23) for withdrawing cryogen from said inner vessel (12), which conduits are in direct heat exchange relationship with said shield (34) and with said heat sink (40, 42); whereby the refrigeration capacity of the cryogen withdrawn from the inner vessel (12) is extracted by said solid heat sink (40, 42) through heat transfer and by lowering of its enthalpy, thereafter, when cryogen flow stops, a major portion of heat leaking through the outer vessel wall is absorbed by the heat shields (34) and the heat sink. In order to achieve a cryogenic dewar that will result in no loss or minimum loss of product during storage at a user location, it has been discovered that a transient heat shield should be disposed between the inner and outer vessels in the vacuum space of the dewar. Furthermore, the transient heat shield should be constructed so that it can be put in heat exchange with the cryogenic liquid, vapor or supercritical fluid (individually and collectively referred to as cryogenic fluid) which is normally drawn off the bottom or top of the vessel so that as product is withdrawn, it cools the transient heat shield to prevent influx of heat into the inner vessel of the dewar. When the transient heat shield includes a heat sink that is in heat exchange relationship with the withdrawal conduit, refrigeration of the transient heat shield is more adequately facilitated and a better product loss prevention device is effected. Alternatively, a fluid heat sink can be used in combination with the transient heat shield to achieve the same effect. BRIEF DESCRIPTION OF THE DRAWING Figure 1 is a schematic representation of a cryogenic storage dewar according to the present invention. Figure 2 is an enlarged representation of the top portion of a cryogenic storage dewar according to the present invention. DESCRIPTION OF THE PREFERRED EMBODIMENT Referring to Figure 1, there is shown a dewar 10 for storing cryogenic fluid of the type to which the instant invention is applicable. Such cryogenic storage dewars or customer stations 10 as they are known in the trade are used for holding a cryogenic fluid, e.g. nitrogen, oxygen, hydrogen, argon, helium or the like, in liquid form for use by a user or customer in their everyday operations. Customer stations such as 10 can be either portable or stationary. The conventional dewar shown as 10 includes an inner vessel or tank 12 and an outer vessel or tank 14, the inner tank being covered by a suitable insulation such as a multi-layer composite of metal and plastic and supported in the outer shell 14 by means of tubes or trunions 18 and 20 dosed by suitable vacuum tight covers 19 and 21, respectively. Inner tank 12 includes a fluid conduit 22 which passes outwardly of the outer tank 14 to deliver cryogen vaporized inside the inner vessel to the point of use. Inner tank 12 can also utilize a fluid conduit 23 which passes outwardly of its outer tank 14 to utilize liquid cryogen in the practice of the invention. In the event the customer wishes to withdraw liquid for dient use, a suitable withdrawal device which does not refrigerate the transient shield, is placed at the bottom of the tank (not shown) as is well known in the art. Outer tank 14 indudes lower passages 24 and 26 closed by suitable covers 25 and 27 to permit conduit 22 and instrumentation (not shown) to be passed inside the outer vessel 14 to the inner vessel 12. Outer vessel 14 indudes an upper passage 23b dosed by suitable cover 23a to permit conduit 23 to be passed inside the outer vessel 14 to the inner vessel 12 and a suitable relief conduit 30 and a relief valve 31 associated therewith. The storage dewars or tanks of this type generally provide for evacuation of the space between the inner tank 12 and the outer tank 14 to thus provide additional insulation and slow down heat infiltration from the atmosphere to the inner tank 12. Outer tank 14 can indude a plurality of supports shown generally as 28 so that the vessel can be installed in a vertical position, thus providing for vaporized cryogen to accumulate near the top of the inner vessel 12. Aseries of stiffening rings 32 can be included around the circumference of outer tank 14 depending upon the capacity of the dewar 10. Dewar 10 can also be constructed for horizontal installation as is well known in the art. According to the present invention at least one transient heat shield 34 which is fabricated from a suitable conductive material such as aluminum or copper is disposed in the vacuum space between the inner vessel 12 and the outer vessel 14. Heat shield 34 is attached to a pair of high heat conductive supports 36 and 38 which are in turn fastened to the inner vessel supports 18 and 20 which are low heat conductive (e.g. fiberglass). As shown in Figure 2 heat shield 34 preferably is covered by a layer of conventional multi-layer insulation. Disposed on supports 36 and 38 are a pair of heat sinks 40 and 42 which are fabricated from a metal having a high specific heat and high thermal conductivity (e.g. aluminum or copper) and preferably, but not necessarily of a greater mass than the transient heat shield 34. Heat sinks 40, 42 can be fabricated from individual segments or cast as a solid piece depending upon the type of dewar being fabricated. The vapor withdrawal conduit 22 and liquid conduit 23 communicating with the interior of inner vessel 12 are fixed in heat exchange relationship with the heat sinks 40 and 42, respectively, and the heat shield 34 prior to exiting outer vessel 14 through passages 24 and 23b, respectively. Referring to Figure 2, the transient heat shield 34 can have disposed on its outer surface insulation 35 of the same type used to insulate the inner vessel 12 and shown as 16. As shown in Figure 2, heat sink 40 can be fastened to support 36 as by bolting shown generally as 41. Additional conduit 44 leading to the normal safety relief device (not shown) is fixed in heat exchange relationship with the heat sinks 40, 42 to derive additional refrigeration, in case fluid flow occurs through this conduit because of overpressurization of inner vessel 12. The tank according to Figures 1 and 2 utilizes the refrigeration capacity of the stored cryogenic fluid in the form of vaporized gas, liquid cryogen, or supercritical fluid to intercept heat leak into the container to thus prolong the storage time of the liquid cryogen and reduce losses due to vapors passing into the atmosphere through the normal relief valve system (not shown). The cryogenic fluid (e.g.liquid cryogen, cold gas or supercritical fluid) drawn out of the tank to be warmed up and used by the customer in gaseous form will provide refrigeration to the transient heat shield 34 by lowering of its temperature. The refrigeration is stored in the transient heat shield 34 and the heat sinks 40 and 42 to intercept heat leaking into the container when cold fluid flow through the withdrawal conduits 22, 23 has been terminated. In intercepting heat leak into the container, thermal energy level of the transient shield 34 will increase thus depleting the stored refrigeration capacity of the transient heat shield 34. When liquid cryogen, cold gas or supercritical fluid is withdrawn at a subsequent time, the flow of fluid will again lower the thermal energy level of the transient shield 34 and thus refrigeration will be accumulated in the shield and the heat sinks (34, 40 and 42). Interception of the heat leak by the transient shield 34 when the fluid flow is absent reduces the net heat transfer into the cryogen container and thus prolongs storage time and saves energy. For example, in a conventional dewar or storage tank such as shown in Figure 1, without the transient heat shield 34 used to store 5685 dm 3 (1500 gallons) of liquid hydrogen and unless the user withdraws approximately 2264 m 3 (80,000 ft 3 )per month from the vapor space in the vessel, the tank will, after reaching the set relief pressure due to warming of the stored cryogen, continuously vent through its normal venting system 44 and thus product will be lost. Taking this tank and installing a transient heat shield according to the present invention gives the customer the option of withdrawing less than 20,000 ft 3 per month of vapor in an intermittent pattern over the month without loss of vapor through the normal venting apparatus. Thus while in both instances the user can vary his demand over the month, the necessary demand in order to prevent loss of any stored product is reduced from approximately 2264 m 3 (80,000 ft 3 ) a month to less than 566 m 3 (20,000 ft 3 ) a month, thus giving the user more flexibility in his product usage. A particularly effective transient heat shield according to the present invention can be fabricated from aluminum having a thickness less than 0.32 cm (0.125"). The heat sinks 40, 42 should each have a total weight of approximately 150 pounds in order to provide additional storage capacity of the refrigeration obtained from the withdrawn vapor. The solid heat sinks 40 and 42 extract and store refrigeration from the exiting cryogenic fluid through heat transfer and by lowering of their enthalpy. When the cryogen flow stops, temperature of the transient heat shield 34 will rise due to the heat leaking into the tank or dewar 10. The solid heat sinks 40 and 42 will absorb a major part of this heat leak through the release of stored refrigeration themselves and to the heat shield 34, thus reducing the net heat leak into the stored cryogen. Different materials can be used for the transient heat shield and solid heat sinks in order to optimize performance of the transient heat shield system. The solid heat sinks 40 and 42 can be positioned at appropriate locations to optimize the design and operation of the tank 10 and can result in utilization of thin shielding to provide the optimum refrigeration transfer. Since the solid heat sink material can be positioned at various locations, it can be more efficiently cooled by the cryogenic liquid, vaporized cryogen or supercritical fluid, particularly when fluid is drawn off at a high rate for only a short period of time. Thermal gradients between the fluid and most remote parts of the solid heat sink can be minimized, thus improving the extraction and storage of refrigeration. It is also possible to utilize more than one transient heat shield and heat sink combination to intercept more heat leak into the dewar 10.

Claims: A dewar for storing or transporting cryogenic fluid of the type containing an outer vessel and an inner vessel disposed therein, said inner vessel including means to admit and withdraw. cryogenic fluid from the interior thereof, insulation between said inner and outer vessels, and a metallic heat shield (34) disposed between said inner and outer vessels (12, 14), characterised by a heat sink (40, 42) in heat-exchange relationship with said shield (34), said heat sink being of metal of high specific heat and high thermal conductivity and of greater mass than the heat shield (34), and a withdrawal conduit (23) for withdrawing liquid cryogen from said inner vessel (12), which conduit is in direct heat exchange relationship with said shield (34) and with said heat sink (40, 42); whereby the refrigeration capacity of the cryogen withdrawn from the inner vessel (12) is extracted by said solid heat sink (40, 42) through heat transfer and by lowering of its enthalpy, thereafter, when cryogen flow stops, a major portion of heat leaking through the outer vessel wall is absorbed by the heat shields (34) and the heat sink. A dewar according to daim 1 where in the metal of said sink is aluminium. A dewar according to daim 1 where in the metal of said sink is copper. A dewar according to daim 1 wherein said sink includes means for circulating a heat extracting fluid through conduits. A dewar according to claim 4 wherein said heat extracting fluid is of high specific heat or high latent heat. A dewar according to claim or 4 or claim 5 wherein said heat extracting fluid is helium, hydrogen, nitrogen, argon, oxygen and/or neon. A dewar according to any of claims 4 to 6 wherein there is a vacuum space between said inner and outer vessels and said heat extracting fluid is stored in said vacuum space. A method for preventing loss of cryogen stored in a vacuum jacketed dewar due to infrequent withdrawal causing the stored cryogen to warm and vaporize due to heat infiltration into said dewar comprising the steps of: disposing a solid heat sink (40, 42) in heat exchange relationship with liquid cryogen as it is withdrawn from the dewar for use; and providing a metallic transient heat shield (34) in said vacuum jacket, said heat shield being in heat exchange relationship with said heat sink.

Inventors: HERRING ROBERT HENRY, VARGHESE ALEXANDER PANDAYATHU, HERRING, ROBERT HENRY, VARGHESE, ALEXANDER PANDAYATHU
Applicants: AIR PROD & CHEM, AIR PRODUCTS AND CHEMICALS, INC.
Application year: 1990
Main classification: F17C3
IPC codes: F17C13, F17C3