Tunnel junction type Josephson device and method for fabricating the same

Abstract: A tunnel junction type Josephson device includes a pair of superconductor layers (2,4) formed of a compound oxide superconductor material and an insulator layer (3) formed between the pair of superconductor layers (2,4). The insulator layer (3) is formed of a compound oxide which is composed of the same constituent elements as those of the compound oxide superconductor material of the superconductor layers but with an atomic ratio which does not present a superconductivity characteristics. In addition, the superconductor layers and the insulator layer are continuously formed while supplying oxygen.

Description: Background of the Invention Field of the invention The present invention relates to a tunnel junction type Josephson device and a method for fabricating the same, and more specifically to a novel tunnel junction type Josephson device which utilizes an excellent property of compound oxide superconductor material and a method for fabricating the same. Description of related art Josephson devices have been constituted of a weak link or junction between a pair of superconductors. In order to form the weak link, some constructions have been conventionally proposed. The most typical construction is a tunnel junction type Josephson device, in which an extremely thin insulating layer is interposed between a pair of superconductors. In tunnel junction type Josephson devices which have been actually fabricated in the prior art, a superconductor has been formed of Nb, NbN, Pb and others, and an insulator layer is formed of an oxide film formed on a surface of a Nb or Pb superconductor, or a deposited film of MgO or a-Si. However, these metal type superconductors generally have a very low critical temperature of superconductivity, and therefore, cannot effectively exhibit its superconduction characteristics unless they are cooled by using a greatly expensive liquid helium. In 1986, on the other hand, it was discovered that a sintered compound oxide such as (La, Ba) 2 CuO 4 and (La, Sr) 2 CuO 4 is a superconduction material having a high critical temperature Tc. Following on this discovery, it has been found that a compound oxide having a composition expressed by Y 1 Ba 2 Cu 3 O 7-x presents an effective superconductivity in a temperature range not less than a liquid nitrogen temperature. The superconductor material capable of assuming the superconductivity at a high temperature as mentioned above makes it possible to use an inexpensive liquid nitrogen as a cooling agent, and therefore, an actual application of a superconduction technology has been studied. Under this circumstance, various attempts are made in order to realize a Josephson device formed of compound oxide superconductor materials. However, it has been known that conventional Josephson devices formed as an experiment by using the above mentioned compound oxide superconductor materials did not exhibit a satisfactory characteristics even at 4.2K which is a temperature of the liquid helium. Summary of the Invention Accordingly, it is an object of the present invention to provide a Josephson device which efficiently utilizes an excellent property of compound oxide superconductor material, by overcoming the above mentioned defect of the conventional one, and a method of fabricating the same. According to the present invention, there is provided a tunnel junction type Josephson device as claimed in Claim 1. According to another aspect of the present invention, there is provided a method of fabricating a tunnel junction type Josephson device as defined in Claim 4. The compound oxide layers of the above mentioned Josephson device can be formed by a physical deposition or a chemical deposition, both of which are well known to persons skilled in the art. In particular, a sputtering or an ion plating can be advantageously utilized. The insulator layer is formed of Y 2 Ba 1 Cu 1 O 5-y or Y 1 Ba 3 Cu 2 O z and the superconductor layers are formed of YBa 2 Cu 3 O 7-x . Furthermore, a substrate on which the above mentioned Josephson device is formed is constituted of a SrTiO 3 single crystal or a MgO single crystal. The thickness of the superconductor layers is on the order of 1,000Å to 3,000Å, and the thickness of the insulator layer is 20Å to 100Å, and preferably 50Å to 100Å (10Å=1nm). As seen from the above, the tunnel junction type Josephson device in accordance with the present invention as claimed is characterized in that the insulator layer is formed of a compound oxide which is composed of the same constituent elements as those of the compound oxide superconductor material which forms the superconductor layers. A conventional method of forming an insulator layer by a surface oxidation of a superconductor is not effective for a compound oxide superconductor material which is originally an oxide. In the prior art, it has been proposed to form between a pair of superconductor layers an insulator layer composed of insulating material, and it has been actually attempted to form the insulator layer with MgO, Al 2 O 3 , ZrO 2 , and others (cf. JP-A-63-306 676 or J. Phys. D. Appl. Phys., vol.20, 1987, pages 1330-1335). However, none of the conventionally fabricated Josephson devices could present a satisfactory result. According to a study of inventors of the present invention, the causes for presenting no satisfactory result are as follows: (1) A compound oxide superconductor material requires a heat treatment in the process of formation. At the time of the heat treatment, however, elements, which constitutes an insulator layer, will diffuse into a superconductor layer in proximity of an interface between the insulator layer and the superconductor layer. As a result, the superconductivity is lost. (2) In environment of a high temperature and a low oxygen partial pressure, such as in a deposition apparatus used for depositing each layer of the Josephson device, oxygen contained in the compound oxide superconductor material is absorbed by an insulator layer, so that the superconductor layer deteriorates. (3) Since the insulator and the high temperature superconductor are greatly different in lattice constant, in thermal expansion coefficient and in other factors, a distortion is generated in an interface between the insulator and the superconductor. In the Josephson device in accordance with the present invention as claimed, the above mentioned problems will be overcome by utilizing the fact that if a compound oxide superconductor material is changed in atomic ratio of constituent elements, the material loses its superconductivity and therefore becomes an insulator. If the insulator layer of the Josephson device is formed of a compound oxide very similar to the superconductor material, superconductor layers and an insulator layer, which constitute the Josephson device, can be continuously formed without changing a layer deposition condition as claimed. In addition, the differences in lattice constant and in thermal expansion coefficient between the superconductor layers and the insulator layer are reduced, and therefore, a deterioration of characteristics caused by the interface distortion is restrained, and the layers can easily become a epitaxial crystal. Furthermore, since the insulator layer itself is a compound oxide, the insulator layer will not absorb oxygen from the superconductor layer, and accordingly, the characteristics of the superconductor layer will not be lost. In a preferred embodiment, the formation of the superconductor layers and the insulator layer is advantageously performed while supplying oxygen by use of an oxygen nozzle or an oxygen ion gun. With this treatment, oxidation of the layers is facilitated, and even if a heat treatment which would be performed after deposition of the layers were omitted, a superconductor layer having an excellent characteristics can be obtained. The above and other objects, features and advantages of the present invention as claimed will be apparent from the following description of a preferred embodiment of the invention with reference to the accompanying drawings. However, it should be noted that the following disclosure is merely one embodiment for making it easier to understand the present invention, and the present invention is in no way limited to the details of the illustrated structures. Brief Description of the Drawings Figure 1 is a diagrammatically perspective view of an embodiment of the tunnel junction type Josephson device in accordance with the present invention; and Figure 2 is a graph illustrating a voltage/current characteristics of the tunnel junction type Josephson device fabricated in accordance with the present invention. Description of the Preferred embodiment Referring to Figure 1, there is shown a diagrammatically perspective view of an embodiment of the tunnel junction type Josephson device in accordance with the present invention. As shown in Figure 1, the Josephson device is formed of a first superconductor layer 2, an insulator layer 3 and a second superconductor layer 4 stacked in the named order on a substrate 1. The insulator layer 3 and the superconductor layer 4 are partially cut out so as to expose a portion of the superconductor layer 2, and a pair of electrodes 5a and 5b are formed on the exposed portion of the superconductor layer 2 and the remaining superconductor layer 4. Each of the superconductor layers 2 and 4 is formed of YBa 2 Cu 3 O 7-x , and has a thickness on the order of 1,000Å to 3,000Å (10 Å =1 nm). On the other hand, the insulator layer 3 is formed of Y 2 Ba 1 Cu 1 O 5-y and has a thickness of 50Å to 100Å. Thus, the superconductor layer 2, the insulator layer 3 and the superconductor layer 4 form a SIS Josephson junction structure. The Josephson device as mentioned above can be fabricated in the following manner. The first superconductor layer 2 is deposited on a (001) plane of a SrTiO 3 single crystal substrate by a RF sputtering. A Target used is one composed of powdered carbonate of each of Y and Ba and powdered oxide of Cu mixed with a proportion which allows a deposited layer to have a composition of YBa 2 Cu 3 O 7-y . The sputtering is carried under the following conditions: a substrate temperature of 600°C, a deposition rate of 5Å/sec and a high-frequency power of 600W. This sputtering is continuously performed until the superconductor layer 2 is deposited to have a thickness of 1,000Å to 3,000Å. In addition, in the process of sputtering, oxygen and oxygen ion are blown onto the substrate by means of an oxygen nozzle and an oxygen ion gun so that oxidation of the deposited layer is facilitated. The layer of YBa 2 Cu 3 O 7-y thus formed was analyzed by an X-ray diffraction method. Only diffraction peaks of (00m) inherent to the (001) orientation were observed. This means that it was confirmed that the formed layer is a crystal film having an orientation of (001). After the deposition of the superconductor layer 2 having the thickness of 1,000Å to 3,000Å, the insulator layer 3 is deposited. The deposition condition for the insulator layer 3 is the same as that for the superconductor layer 2, but a target used is one composed of powdered carbonate of each of Y and Ba and powdered oxide of Cu mixed with a modified proportion which causes a deposited layer to have a composition of Y 2 Ba 1 Cu 1 O 5-y . Thus, the insulator layer 3 of Y 2 Ba 1 Cu 1 O 5-y having a thickness of 50Å to 100Å is formed on the superconductor layer 2 of YBa 2 Cu 3 O 7-y . In this process of sputtering for the insulator layer 3, oxygen and oxygen ion are also blown onto the substrate by means of the oxygen nozzle and the oxygen ion gun so that oxidation of the deposited layer is facilitated. On the insulator layer thus formed, the second superconductor layer 3 is deposited to have a thickness of 1,000Å to 3,000Å. In this process of formation of the second superconductor layer 3, the target which enables to form a deposited layer having a composition of YBa 2 Cu 3 O 7-y is used again, and the sputtering is performed under the same condition, while similarly supplying oxygen. Thus, the tunnel type Josephson junction is formed in a continuous process without breaking a vacuum condition of a sputtering apparatus, by previously setting within the sputtering apparatus a target which enables to form a deposited layer having a composition of YBa 2 Cu 3 O 7-y and another target which enables to form a deposited layer having a composition of Y 2 Ba 1 Cu 1 O 5-y and by selectively using one of the two targets. The layered structure thus formed, which is composed of the superconductor layers and the insulator layer to form a SIS tunnel junction, is selectively dry-etched until the lower superconductor layer is partially exposed, and thereafter, Au is evaporated on each of the two superconductor layers so as to form an electrode on an upper surface of each of an exposed portion of the lower superconductor layer 2 and the remaining upper superconductor layer 4. Thus, the tunnel junction type Josephson device as shown in Figure 1 is obtained. Referring to Figure 2, there is shown a graph illustrating a measured voltage/current characteristics of the tunnel junction type Josephson device in accordance with the present invention fabricated in the process as mentioned above. The measurement was made at a temperature of 4.2K. It is observed from Figure 2 that an electric current flowing through the tunnel junction type Josephson device abruptly drops in the neighborhood of 11mV corresponding to an energy gap. Namely, it is confirmed that an excellent tunnel Josephson junction is formed. As mentioned above, the Josephson device in accordance with the present invention as claimed such that the insulator layer is formed of a compound oxide which is composed of the same constituent elements as those of the compound oxide superconductor material. Therefore, an excellent junction is formed at an interface between each superconductor layer and the insulator layer. In the process of fabrication, since the insulator layer itself is composed of a compound oxide, the insulator layer will not ahsorb oxygen from the compound oxide superconductor layers, and therefore, the quality of the superconductor layer is not deteriorated. Thus, the Josephson device in accordance with the present invention as claimed is constituted of a compound oxide superconductor material having a high critical temperature, and accordingly, makes it possible to economically utilize the Josephson devices. The invention has thus been shown and described with reference to the specific embodiment. However, it should be noted that the present invention is in no way limited to the details of the illustrated structures but changes and modifications may be made within the scope of the appended claims.

Claims: A stacked SIS tunnel junction type Josephson device including a pair of oxide superconductor layers formed of YBa 2 Cu 3 O 7-x and an insulator layer formed between the pair of oxide superconductor layers, all layers forming a continuous structure and said insulator layer being formed of Y 2 Ba 1 Cu 1 O 5-y or Y 1 Ba 3 Cu 2 O z which is composed of the same constituent elements as those of the compound oxide superconductor material of said oxide superconductor layers but with an atomic ratio which does not present a superconductivity characteristics, wherein said insulator layer has the thickness of 2 x 10 -9 m (20A) to 10 -8 m (100 Å). A tunnel junction type Josephson device claimed in claim 1 wherein each of said pair of superconductor layers has the thickness of 10 -7 m (1,000 Å) to 3x10 -7 m (3,000 Å). A tunnel junction type Josephson device claimed in any of claims 1 to 2 wherein one of said pair of superconductor layers is formed on a SrTiO 3 single crystal substrate or a MgO single crystal substrate. A method of fabricating a tunnel junction type Josephson device including a pair of oxide superconductor layers formed of YBa 2 Cu 3 O 7-x and an insulator layer formed between the pair of superconductor layers, wherein all layers form a continuous structure and the insulator layer has the thickness of 2 x 10 -9 m (20Å) to 10 -8 m (100Å) and is formed of Y 2 Ba 1 Cu 1 O 5-y or Y 1 Ba 3 Cu 2 O z which is composed of the same constituent elements as those of the compound oxide superconductor material of the superconductor layers, and wherein the superconductor layers and the insulator layer are continuously formed while supplying oxygen. A method claimed in claim 4 wherein each of said pair of superconductor layers is formed by a physical deposition using a target having a composition enabling to form a deposited layer having superconductivity, and said insulator layer is formed by a physical deposition using a target having a composition enabling to form an insulative deposited layer. A method claimed in claim 4 wherein each of said pair of superconductor layers is formed by a physical deposition using a target composed of a powdered carbonate of each of Y and Ba and a powdered oxide of Cu mixed with a proportion which allows a deposited layer to have a composition of YBa 2 Cu 3 O 7-y and said insulator layer is formed by a physical deposition using a target composed of a powdered carbonate of each of Y and Ba and a powdered oxide of Cu mixed with a proportion which enables to form a deposited layer having a composition of Y 2 Ba 1 Cu 1 O 5-y . A method claimed in any of claims 4 to 6 wherein said insulator layer is formed to have the thickness of 2x10 -9 m (20Å) to 10 -8 m (100Å), and each of said pair of superconductor layers is formed to have the thickness of 10 -7 m (1,000Å) to 3.10 -7 m (3,000Å). A method claimed in any of claims 4 to 7 wherein one of said pair of superconductor layers is formed on a SrTiO 3 single crystal substrate or a MgO single crystal substrate.

Inventors: ITOZAKI HIDEO, NAKANISHI HIDENORI, TANAKA SABURO, YAZU SHUJI, ITOZAKI, HIDEO, NAKANISHI, HIDENORI, TANAKA, SABURO, YAZU, SHUJI
Applicants: SUMITOMO ELECTRIC INDUSTRIES, SUMITOMO ELECTRIC INDUSTRIES, LTD.
Application year: 1990
Main classification: H01L39
IPC codes: H01L39