Semiconductor package connecting method and semiconductor package connecting wires

Abstract: A method of electrically connecting a semiconductor package to a substrate by using bump contacts formed by heating the tip of an alloy wire and directly joined to aluminum alloy wiring lines, an alloy wire for such a purpose, and a semiconductor device constructed by electrically connecting a semiconductor package to a substrate by such a method. The alloy wire is produced by drawing an alloy material produced by quench solidifying an alloy containing Pb, Sn or In as a principal element, and an additive element or additive elements. The tip of the alloy wire is heated to form a ball to be joined to the aluminum alloy wiring line as a bump contact. The Brinell hardness number of the ball is H B 6 or higher.

Description: Background of the Invention Field of the Invention The present invention relates to a semiconductor package connecting method and, more specifically, to a method of connecting a semiconductor package, such as a semiconductor chip, to a substrate by a wireless bonding process, particularly, a flip chip bonding process or a tape carrier bonding process, connecting wires for such a purpose. Description of the Prior Art A semiconductor package connecting method using bumps formed by a wire bonder and connecting materials for such a semiconductor package connecting method are disclosed in Japanese Patent Laid-open No. 63-301535. This known semiconductor package connecting method uses a fine alloy wire produced by quench solidifying an alloy containing Pb, Sn or In as a principal element. The tip of the alloy wire is heated to form a ball, the ball is attached to the wiring line of a semiconductor package or a substrate, and then the alloy wire is pulled off the ball to form a bump electrode on the wiring line. The semiconductor package and the substrate are connected by means of such bump electrodes. Recently, aluminium alloys, such as Al-Si and Al-Cu-Si, have become used widely as wiring materials for semiconductor chips for their capability of suppressing electromigration and of improving the reliability of semiconductor chips. In attaching the ball directly to the aluminium alloy wiring line of a semiconductor package of a substrate by this known semiconductor package connecting method, the aluminium alloy wiring line must be heated in a flux containing CuCl 2 , ZnCl 2 , NH 4 Cl, SnCl 2 or HCl to remove an oxide covering the surface of the aluminium alloy wiring line, which requires an additional process and time and increases the cost of the semiconductor device. Other prior art exists, and for example, in UK patent application No 2201545 A, there is described a method of electrically connecting a semiconductor package to a substrate, wherein a drawn, quenched solidified, fine alloy wire is used to provide a connecting ball which connects the semiconductor package to the substrate, but the wire used is of such a composition is not to provide the same bonding characteristics as does the wire and method of the present invention. In European Patent Application No 0264648 A1, bonding between conductors on a base film is achieved by providing on the conductors bonding metal layers, and by aligning the bonding metal layers with terminals of an electronic part and half melting the bonding metal layers. Again, this prior document does not disclose the use of a specific fine alloy of the composition as used in the present invention, with the advantages set forth herein, for performing the bonding. Summary of the Invention Accordingly, it is an object of the present invention to form a bump electrode by using an alloy wire produced by quench solidification and to bond the bump electrode directly to an aluminium alloy wiring line. In one aspect of the present invention there is provided a method for electrically connecting a semiconductor package to a substrate, said method comprising steps of heating the tip of a drawn, quench solidified, fine alloy wire containing Pb or Sn as a principal element and including, when Pb is a principal element also 1-10 weight % Sb and 0.05-3% weight Zn, and when Sn is a principal element also 0.01-10% weight Sb and 0.01-10% weight Zn, to form a ball having a Brinell hardness number HB6, or higher, joining the ball to an oxide film covered aluminium alloy wiring line on the semiconductor package or the substrate to destroy the oxide film on the aluminium alloy wiring line and to metallurgically bond the ball directly to the aluminium alloy wiring line by the diffusion between the ball and the aluminium alloy wiring line, followed by pulling the alloy wire away from the semiconductor package or the substrate to separate the alloy wire from the ball and to leave the ball as a bump contact on the aluminium alloy wiring line of the semiconductor package or the substrate, and electrically connecting the semiconductor package to the substrate through such bump contact. In another aspect of the present invention there is provided, a drawn, quenched solidified, fine alloy, semiconductor package connecting wire capable, by being heated at its tip, of forming balls of a Brinell hardness number HB6 or higher to provide bump contacts for electrically connecting a semiconductor package to a substrate, wherein the fine alloy wire contains Pb or Sn as a principal element and also Sb and Zn in the following amounts:- a) when Pb is the principal element, 1-10 weight % Sb and 0.05-3 weight % Zn; and b) when Sn is the principal element, 1-10% weight Sb and 0.01-10 weight % Zn. Preferably, the alloy forming the fine wire contains one or some of additive elements among Be, B, C, Mg, Al, Si, P, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Se, Zr, Nb, Mo, Pd, Ag, Cd, In, Sn, Pb, Sb, Te, Ir, Pt, Au, Tl and Bi. The ball of the alloy of a hardness of H B 6 or higher destroys an oxide film of a hardness in the order of H B 6 and covering the surface of the aluminium alloy wiring line, and the ball and the aluminium alloy wiring line are bonded metallurgically by the diffusion between the fresh ball and the fresh surface of the aluminium alloy wiring line. Brief Description of the Drawings The above and other objects, features and advantages of the present invention will become more apparent from the following description taken in connection with the accompanying drawings, in which: Figure 1 is a longitudinal sectional view of a semiconductor device made according to a method of a preferred embodiment of the present invention; Figures 2 to 5 are enlarged fragmentary longitudinal views showing steps of connecting a semiconductor package to a substrate; and Figure 6 is a longitudinal sectional view of a semiconductor device in another embodiment not forming part of the claimed invention. Description of the Preferred Embodiments Referring to Fig. 1, a semiconductor device A is of a so-called flip-chip mount type constructed by disposing a semiconductor chip (semiconductor package) 2 in the central area of the upper surface of a substrate 1, electrically connecting the aluminium alloy wiring lines 2a, ie, wiring lines of an Al-Si alloy or an Al-Cu-Si alloy, of the semiconductor chip 2 to those of the wiring lines 1a, ie, Cu lines plated with Sn or Au, arranged on the upper surface of the substrate 1 with bump contacts 3b, and sealing the semiconductor chip 2 and part of the wiring lines 1a of the substrate 1 with a protective resin 6, such as a silicone resin. The bump contacts 3b are formed previously by bonding balls 3a formed by heating the tip of an alloy wire 3, ie, a connecting material, to the alloy wiring lines 2a of the semiconductor chip 2 through a procedure shown in Figs. 2 to 5. The alloy wire 3 is formed of an alloy consisting of Pb or Sn as a principal element, and additive elements and produced by a quench solidifying process. The alloy wire 3 may contain one or some additive elements among Be, B, C, Mg, Al, Si, P, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Se, Zr, Nb, Mo, Pd, Ag, Cd, Sb, Te, Ir, Pt, Au, Tl and Bi. An alloy not containing Pb or Sn as the principal element may contain Pb, Sn or In as an additive element. When quenched, many lattice defects are formed in the alloy forming the alloy wire 3, minute crystals grains develop in an unequilibrated phase to produce a forced solid solution of the component elements. When the alloy is drawn to produced the alloy wire 3, lattice defects are formed by work hardening, and the structure of the alloy is solution-hardened by the additive elements. As shown in Fig. 2, the alloy wire 3 thus produced is passed through a capillary tube 4, and then the tip of the alloy wire 3 is heated with an electric torch 5 to form a ball 3a having a hardness of H B 6 or higher. Then, as shown in Fig. 3, the capillary tube 4 is lowered to attach the ball 3a formed at the tip of the alloy wire 3 to the aluminium alloy wiring line 2a formed on the semiconductor chip 2. The ball 3a having a hardness of H B 6 or higher destroys an oxide film coating the surface of the aluminium alloy wiring line 2a having a hardness on the order of H B 12, and the ball 3a is bonded directly to the aluminium alloy wiring line 2a by the diffusion between the new surface of the ball 3a and the new surface of the aluminium alloy wiring line 2a. Subsequently, as shown in Fig. 4, the capillary 4 is raised to separate the ball 3a from the alloy wire 3 to leave the ball 3a as a bump contact 3b on the aluminium alloy wiring line 2a. When the tip of the alloy wire 3, namely, the ball 3a is heated, the unequilibrated phase disappears and the crystal grains grow large in the junction of the alloy wire 3 and the ball 3a to reduce the tensile strength of the junction, so that the junction yields and breaks readily when the alloy wire 3 is raised by the capillary. Then, as shown in Fig. 5, semiconductor chip 2 is placed on the substrate 1 with the bump contacts 3b attached to the aluminium alloy wiring lines 2a in contact with the wiring lines 1a of the substrate 1, and then heat and pressure are applied to the bump contact 3b to connect electrically the aluminium alloy wiring lines 2a of the semiconductor chip 2 and the wiring lines 1a of the substrate and also to bond the semiconductor chip 2 to the substrate 1. Although the sphericity of the balls 3b can be improved by heating the balls 3b in the atmosphere of a flux of a chloride or an iodide before placing the balls 3b in contact with the wiring lines 1a of the substrate 1, the balls 3b may be attached to the wiring lines 1a without causing then to reflow. Fig. 6 shows another semiconductor device A not forming part of the claimed invention. This semiconductor device A is of a so-called tape carrier bonding type, in which bump the contacts 3b are formed on the aluminium alloy wiring lines 2a of a semiconductor chip 2, and the film leads 7 formed for example, by plating strips of a Cu foil with Sn or Au, are bonded to the bump contacts 3b, and the wiring lines 1a of a substrate 1. In the foregoing embodiments, the aluminium alloy wiring lines 2a are formed on the semiconductor chip 2 and the balls 3a are bonded to the aluminium alloy wiring lines 2a as the bump contacts 3b. The wiring lines 1a of the substrate 1 may be formed of an aluminium alloy and the balls 3a may be bonded to the wiring lines 1a of the substrate 1 as the bump contacts 3b. Tables 1 to 27 show the properties of alloys in comparison with those of controls in terms of the respective compositions of alloys forming alloy wires, the ball forming property of the alloy wires, the hardness of balls formed by heating the alloy wires, and the capability of bonding to the Al-Si alloy wiring lines. The ball forming property is evaluated by the shape of a ball formed by arc discharge between the tip of a sample alloy wire passed through a ceramic capillary tube and an electrode disposed near the tip of the sample alloy wire in an argon gas atmosphere containing 5% in volume hydrogen gas. In the tables, a circular mark indicates that the ball has satisfactory sphericity and smooth surface morphology. Thus, the present invention has the following advantages. The ball of a hardness of H B 6 or higher formed on the tip of the alloy wire produced by drawing a quench solidified alloy destroys an oxide film coating the surface of the aluminium alloy wiring line, and the ball and the aluminium alloy wiring line are bonded together metallurgically by mutual diffusion between the new surface of the aluminium alloy wiring line and the new surface of the ball, and hence the ball formed on the tip of the alloy wire can be directly joined as a bump contact to the aluminium alloy wiring line. Thus, the present invention enables the omission of a step of removing the oxide film coating the surface of the aluminium alloy wiring line, which reduces time and cost for assembling the semiconductor device.

Claims: A method for electrically connecting a semiconductor package to a substrate, said method comprising steps of heating the tip of a drawn, quench solidified, fine alloy wire containing Pb or Sn as a principal element and including, when Pb is a principal element also 1-10 weight % Sb and 0.05-3% weight Zn, and when Sn is a principal element also 0.01-10% weight Sb and 0.01-10% weight Zn, to form a ball having a Brinell hardness number HB6, or higher, joining the ball to an oxide film covered aluminium alloy wiring line on the semiconductor package or the substrate to destroy the oxide film on the aluminium alloy wiring line and to metallurgically bond the ball directly to the aluminium alloy wiring line by the diffusion between the ball and the aluminium alloy wiring line, followed by pulling the alloy wire away from the semiconductor package or the substrate to separate the alloy wire from the ball and to leave the ball as a bump contact on the aluminium alloy wiring line of the semiconductor package or the substrate, and electrically connecting the semiconductor package to the substrate through such bump contact. A semiconductor package connecting method according to Claim 1, wherein the alloy wire is passed through a capillary tube employed in a wire bonder, and the balls are joined to the aluminium alloy wiring lines by a wire bonding method. A semiconductor package connecting method according to Claim 1, wherein the alloy forming the alloy wire contains, as an additive element or additive elements one or some elements among Be, B, C, Mg, Al, Si, P, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Se, Zr, Nb, Mo, Pd, Ag, Cd, In, Sn, Pb, Sb, Te, Ir, Pt, Au and Bi. A semiconductor package connecting method according to Claim 1, wherein the Brinell hardness number of the ball is in the range of H B 6 to H B 26. A drawn, quench solidified, fine alloy, semiconductor package connecting wire capable, by being heated at its tip, of forming balls of a Brinell hardness number HB6 or higher to provide bump contacts for electrically connecting a semiconductor package to a substrate, wherein the fine alloy wire contains Pb or Sn as a principal element and also Sb and Zn in the following amounts:- a) when Pb is the principal element, 1-10 weight % Sb and 0.05-3 weight % Zn; and b) when Sn is the principal element, 1-10% weight Sb and 0.01-10 weight % Zn. A semiconductor package connecting wire according to Claim 5, wherein the alloy contains one or some elements among Be, B, C, Mg, Al, Si, P, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Se, Zr, Nb, Mo, Pd, Ag, Cd, In, Sn, Pb, Sb, Te, Ir, Pt, Au, Tl and Bi. A semiconductor package connecting wire according to Claim 5, wherein the Brinell hardness number of the ball is in the range of H B 6 to H B 26.

Inventors: OGASHIWA TOSHINORI, OGASHIWA, TOSHINORI, OGASHIWA, TOSHINORI, C/O MITAKA FACTORY OF TANAKA
Applicants: TANAKA ELECTRONICS IND, TANAKA DENSHI KOGYO KABUSHIKI KAISHA
Application year: 1990
Main classification: H01L21
IPC codes: B23K35, H01L21, H01L23