Injection molding of fiber reinforced articles

Abstract: A method for molding fiber reinforced articles with superior mechanical properties by injection molding. The method comprises heating a mixture of molding compound and chopped fiber to produce highly viscous substance. Pressure is applied to force the substance through an elongated injection slot oriented perpendicular to the major axial dimension of the finished article, causing the fiber planes to become oriented in a unique whorled, accordion like manner. The unusual fiber plane orientation reinforces the article such that it is resistant to crack propagation.

Description: The present invention concerns a die for forming an article from fiber reinforced molding compound according to the precharacterizing portion of claim 1 and a method for producing a fiber reinforced article according to the precharacterizing portion of claim 3 (EP-A-331860) The present invention relates to injection molding, especially to injection port geometry and related processing parameters for producing fiber reinforced articles possessing a unique whorled, accordion like fiber plane orientation. Fiber reinforcement is a known, commonly used method of increasing the mechanical properties of thermoplastic, glass, and glass ceramic materials. Hereafter referred to as molding compounds, these materials are described, for example, in US-A-4,314,852, 4,324,843, and 3,926,904. The fibers used for reinforcement vary according to the desired application. These fibers include: carbon base fibers, boron base fibers, glass fibers, silicon carbide fibers, metal fibers, and others. Carbon base fibers are light weight, strong, highly electrically conductive, and are easily oxidized, with a low upper temperature limit in oxidizing atmospheres. Boron base fibers are easily oxidized, similar to carbon fibers, yet have excellent heat-shock resistance and are noncombustible. Glass fibers, good insulators and noncombustible, can lose strength above about 315°C. Silicon carbide fibers can be resistant to oxidation at high temperatures, electrically conductive, noncombustible, and have excellent thermal conductivity. Metal fibers possess extremely high tensile strength, with other properties ranging between noncombustibility to oxidizing at low temperatures. The above mentioned fibers and others will hereafter be referred to as fibers. Critical factors affecting the composites' mechanical properties include fiber dispersion and orientation. For instance, composites containing unidirectionally oriented fibers possess high tensile strength in the direction of the fibers, and low tensile strength perpendicular to the fiber orientation; while randomly oriented fiber composites display a fairly uniform tensile strength in all directions. One fabrication method for producing fiber reinforced composites having complex shapes and desired fiber orientation involves hot press molding of glass infiltrating woven and/or non-woven fiber preforms as described in US-A-4,412,854. Related techniques that are suitable for complex shapes, used with matrix transfer molding are described in US-A-4,786,304 and 4,428,763. Transfer molding, a process similar to injection molding, consists of softening thermoplastic resin in a chamber with heat and pressure and forcing it by high pressure through an orifice into a closed mold. An injection molding technique, not requiring fiber pre-arrangement yet obtaining fiber dispersion, consists of injecting a discontinuous fiber/molding compound mixture into a die as disclosed in US-A-4,464,192 and 4,780,432. Injection molding, described in the above mentioned patents, consists of feeding a molding compound consisting of into a heating chamber and heating it to a viscous liquid, and then, via a plunger, forcing the material into a mold and keeping it under pressure until cool. Injection molding of fiber reinforced molding compounds, without pre-arranged fibers, fail to fully solve the problem of obtaining a controllable fiber orientation which will produce the optimum mechanical strength. For example, in cylindrical orifice injection molding, as described in US-A-4,780,432, fibers lie on paraboloidal shaped planes susceptible to crack propagation (Fig. 1B) between such planes. The object of this invention is to introduce an oscillatory flow of the molding compound into the mold cavity, to produce a shaped composite with desired fiber dispersion and orientation obtaining superior, quasi isotropic, mechanical strength. The die of the present invention is defined in claim 1 and the method for producing a fiber reinforced article is defined in claim 3. The present invention is directed to a method of forming fiber reinforced articles through injection molding. A mixture of molding compound and fibers are heated and pressurized to force the viscous mixture through an elongated slot-like injection port into a die. The injection port, a crucial aspect of the invention, is located essentially parallel to the major axial dimension of the article, is approximately the length of the article, is a fraction of the width of the article, and has a depth sufficient to orient the fibers with the flow. The injection port geometry and orientation relative to the mold cavity cause the fiber planes to form a whorled, accordion-like pattern within the article. The process results in the fiber planes becoming intertwined, creating superior tensile strength throughout the article. The foregoing and other features and advantages of the present invention will become more apparent from the following description and accompanying drawings. Fig. 1A shows the fiber plane orientation obtained by axial cylindrical port injection molding. Fig. 1B shows the fiber plane orientation obtained by edge slot port injection molding. Fig. 2 shows a molded article formed using the present invention and the fiber plane orientation created. Fig. 3 is a cross sectional view of an injection mold assembly useful with the present invention. Fig. 4 is a schematic of the invention process. A basic embodiment of the invention is shown in Fig. 2 where article (120) is the desired product produced using and injection port (130) of specific geometry and location; this being a crucial controlling factor of fiber plane orientation. The injection port's elongated slot-like geometry includes: a length (134) as close to the full length of the major axial dimension (124) as is practical to arrange, a thickness (138), usually, between about 30 and about 70 percent of the article thickness (122), a depth (136) sufficient to initially orient the fibers with the flow, and location essentially in a plane parallel to the major axial dimension (124) of the finished article. Any high temperature thermoplastic resin, glass ceramic, or glass matrix/fiber system may be used as the molding compound in this process. On the basis of flexure strength, and oxidation and wear resistance of hot pressed chopped fiber composites, a glass matrix/carbon fiber was chosen for the specific application of a gas turbine engine inner shroud. The molding compound formulation range lies between 18 and 36 % by volume, and especially between 25 and 30 % by volume for the 1.27 cm (1/2 inch)carbon fiber/glass used, and the optimum fiber length for the chosen article (Fig. 2) is 1.27 cm (1/2 inch). For finely detailed articles, the fiber length can be reduced to obtain the desirable fiber orientation throughout the article and good detailed surface replication. The optimum fabrication temperature ranged from 1200°C to 1275°C for the particular carbon fiber/glass matrix system used. The viscosity, another significant factor and a function of the temperature, is approximately 10⁶ - 10⁷ poise for HMU-3K fiber/7070 glass in this temperature range. Note, however, this is only the desired viscosity for the carbon fiber/glass used, different viscosity ranges may apply for the other viable thermoplastic resin, ceramic, or glass systems such as those described in US-A-4,314,852, 4,324,843, and 3,926,904. When the parameters mentioned above are satisfied, a unique, whorled, accordion like fiber plane orientation results (Fig. 2B; obtained from (2B) in Fig. 2). The viscosity, flow rate, and geometric relation between the injection port and mold cavity are presumed to create an oscillating flow pattern entering the die cavity (Fig. 4), which induces a folding of the fiber planes, causing them to become interlocked. Consequently, the article resists crack propagation on most planes. The invention will be clarified by reference to the following illustrative example. Example The following procedure can be used to prepare a fiber reinforced glass article. 1. A preconsolidated molding compound of 25 to 30 % by volume 1.27 cm (1/2 inch) Hercules Inc. HMU-3K carbon fiber/code 7070 low sodium borosilicate glass/colloidal silica (Ludox-) binder is placed in the reservoir (50) (Fig. 3), before inserting the plunger (40) into the injection mold assembly. 2. The mold assembly is placed below the ram (60) in a hot press furnace chamber; the two part mold assembly having a die which has a height of 2.54 cm, a length of 7.62 cm, and a thickness of 1.11 cm, and has an injection port which has a length of 6.51 cm, a width of 0.57 cm, and a depth of 3.05 cm. 3. The mold assembly is heated to furnace temperature set point of 1275°C. 4. The ram (60) and plunger (40) are used to apply 6.89 MPa (1000 psi)hydrostatic pressure when the thermocouple indicates 1100°C. The molding compound volume flow rate, linear flow rate through the slot, and the viscosity obtained were calculated to be approximately 0.615 cc/sec, 0.163 cm/sec, and 4 x 10⁶ poise respectively. Fig.s 1A and 1B show the results of this experiment as opposed to the prior art (test samples obtained as shown by (1) in Fig. 2); the flexure strengths of a cylindrical port injection molded composite (Fig. 1A) versus a slot port injection molded composite (Fig. 1B) (present invention). It can clearly be seen from the fiber plane orientation within the samples and the test results that (Fig. 1A) possesses a relatively low flexure strength throughout the structure, while (Fig. 1B) possess uniformly high flexure strengths with the desired fiber dispersion and fiber plane orientation.

Claims: A die for forming an article (120) from fiber reinforced molding compound, said die having walls defining a cavity, said article (120) having a major axial dimension (124) and a thickness dimension (122) perpendicular to the axial dimension (124), which comprises: a cavity essentially having the shape of the desired article (124); characterized in having an elongated slot shaped injection port (130), said port (130) i. being located parallel to the major axial dimension (124); ii. having a thickness (138) between 30 to 70 % of the article thickness (122) in the vicinity of the port (130); iii. having a depth (136) sufficient to orient the fiber with the flow; whereby when the fiber reinforced molding compound is injected into the die, a whorled, accordion like fiber plane orientation results. A fiber reinforced article (120) characterized in having fibers on planes, said planes oriented in a whorled, accordion like manner which is resistant to crack propagation. A method for producing a fiber reinforced article (120), said article (120) having a major axial dimension (124), a thickness dimension (122) perpendicular to the axial dimension (124); starting with a mixture of a molding compound and fibers; using a hot press assembly, said assembly having a die with a slot shaped injection port (130), said injection port (130) having a width and depth, characterized in that it comprises: a. orienting the injection port (130) such that the thickness (138) of the injection port (130) is parallel to the thickness (122) dimension of the article (120); b. orienting the injection port (130) such that the flow of the material enters the article in a plane parallel to the major axial dimension (124); c. causing the depth (136) of the injection port (130) to be sufficient to orient the fibers with the flow of the material; d. heating the thermoplastic-fiber mixture to a point where it will flow under pressure; e. applying pressure to force the heated mixture through the injection port (130) into the die; whereby the fiber planes become oriented in a unique whorled, accordion like manner. A method according to claim 3 characterized in that the fiber content is approximately 18 to 36 % by volume. A method according to claim 3 characterized in that the matrix is selected from the group consisting of thermoplastic resin, glass, glass ceramic, and ceramic material. A method according to claim 3 characterized in that the fibers are selected from the group consisting of graphite base, silicon carbide, mullite, boron base, alumina base, and zirconia base.

Inventors: LAYDEN GEORGE K, LAYDEN, GEORGE K.
Applicants: UNITED TECHNOLOGIES CORP, UNITED TECHNOLOGIES CORPORATION
Application year: 1990
Main classification: C03B11
IPC codes: B29C45, C03B11, B29K105, C03C14, C03C10, C04B35