Stirring reactor for viscous materials

Abstract: A stirring reactor for a viscous material. The reactor comprises a stirring vessel; a revolvable shaft provided in the vessel; a surface layer stirring vane provided on the revolvable shaft in the vicinity of the gas-liquid interface; a stirring vane having at least a pair of multiple blades which extend radially twords the inner wall, one of which is fastened on the revolving shaft below the upper layer stirring vane and the other of which extends close to the inner wall of the vessel and baffle plates provided on the inner side wall at a position opposite the surface layer stirring vane, and at a staggered position with respect to the stirring vanes having plural blades.

Description: The present invention concerns a stirring type reactor, e.g., stirred tank, for viscous liquids particularly a reactor for efficiently carrying out reactions under stirring of liquids having low and moderate viscosity, for example, not higher than 10 kg/m·sec. (10,000 centipoises). Hitherto, as a stirring type apparatus for viscous liquids, a stirring vane having multiple blades, one end of which is secured on a rotating shaft and the other end of which extends in the radial direction of the interior of the stirring vessel, has been proposed. In the stirring vessel, the viscous liquid is liable to be stirred along a convection current of the liquid caused by revolution of the vane and a shearing force created in the space between the inner wall of the vessel and the stirring vane. Thus, generally the stirring vessel provided with the stirring vane having multiple blades is advantageously used since a strong shearing force is easily generated. For example, a specific combination of multiple vanes which are provided on the rotating shaft at different heights, and baffle plates which are provided on the inner wall of the vessel at different heights, the positions of the vanes being different than the positions of the baffle plates, has been widely adopted as well. In the prior at stirring vessel, when the uppermost vane is positioned at around the gas-liquid interface, a vibration is liable to be caused in the vessel and stirring vanes and the vessel thereby suffers from difficulty in speed-up of revolutions. On the other hand, when the uppermost vane is positioned away from the gas-liquid interface, a so-called dead spot appears in the area of the gas-liquid interface and no stirring occurs at or near the surface of the solution. Accordingly, the prior art stirring reactor has disadvantages that efficiency of a stirring reaction cannot be improved and stirring is required for a long period of time due to insufficient stirring. SUMMARY OF THE INVENTION An object of the present invention, which has been developed in consideration of the above disadvantages, is to provide a stirring reactor which generates sufficient convection mixing and shear mixing simultaneously and, particularly, renews the solution at around the gas-liquid interface. Another object of the present invention is to provide a stirring reactor which is capable of providing a uniform stirred reaction of a viscous liquid having from low to medium viscosity without suffering from hazardous vibration in the vessel. According to the present invention, there is provided a stirring reactor which comprises a stirring vessel, a revolvable shaft placed therein, a stirring vane fastened on the shaft at a position near the gas-liquid interface of the viscous material to be provided in the vessel, stirring vanes fastened at lower positions of the shaft and having multiple blades, these blades extend radially toward and close to the inner wall of the vessel and baffle plates placed on an interior surface of the vessel at different positions with respect to the positions of the vanes having multiple blades. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 shows a vertical sectional view of one embodiment of a stirring reactor according to the present invention. Fig. 2 shows a plane view of one embodiment of the stirring vanes for surface stirring and the composite stirring vanes fastened on a revolvable shaft. Fig. 3 shows a vertical sectional view of one embodiment of the stirring vessel. Fig. 4 is an oblique view showing one embodiment of the fastened state of the surface layer stirring vane. Fig. 5 is an oblique view showing one embodiment of the fastened state of the composite stirring vanes. In the figures, the following symbols denote components as follows: (1): Stirring vessel, (2): Revolving shaft, (3): Surface layer stirring vane, (4): Composite stirring vane and (5): Buffle plate. DETAILED DESCRIPTION OF THE INVENTION In the stirring reactor according to the present invention there is provided a combination of a surface layer stirring vane and baffle plate which is placed in the stirring vessel at a position corresponding to the position of the blades of said vane, and multiple combinations of composite vanes and baffle plates. The combinations of the latter are provided below the combination of the former to further enhance convection mixing and shearing mixing. Mixing time for viscous material according to the present invention is remarkably shortened compared with that required for a prior art reactor without the specific combination according to the present invention since a renewal of liquid at around gas-liquid interface where the surface stirring vane is provided, cannot be sufficiently achieved in the prior art reactor. Further, since sufficient aeration at the gas-liquid interface is caused, volatile matter in the viscous liquid is easily evaporated, and a gaseous material can be easily dissolved into the viscous liquid. The present invention is hereinafter described in detail with reference to various embodiments, which are not to be construed as limiting the scope thereof. In Fig. 1, a stirring vessel denoted as (1) is provided with a revolvable shaft (2) which is driven by a driving means such as a motor (not shown). The revolvable shaft (2) is provided with a surface mixing vane (3) composed of, for example, a blade having a plate form at a upper side of the vessel, particularly at or around the gas-liquid interface of the viscous liquid to be stirred in the vessel, and also with a composite vane (4) composed of an inner blade (4a) and an outer blade (4b) at a lower portion of the vessel. The surface layer stirring vane (3) may be placed at or near the gas-liquid interface as seen in Fig. 1 or may be positioned so that a part of the blade is exposed above the surface of the liquid. The surface layer stirring vane (3) has two pairs of blades which are symmetrically positioned with respect to the revolvable shaft (2) as a center as shown in Figs. 2 and 4, however, the plane of these blanes may be positioned either vertically or at an angle with respect to the plane of revolution of the stirring vanes. Further, the surface layer stirring vane, in which the blades may be freely selected with respect to the placement of their positions and their radii, is preferably designed to provide appropriate mixing according to the type and amount of the viscous liquid to be processed. In the figures, the surface layer stirring vane is shown as a flat plate type, however, the vane may be of a single-axis or multi-axis screw blade or other type of mixing blade. The composite stirring vanes (4) are composed of two pairs of blades each of which is symmetrically positioned with respect to the axis of revolution as seen in Figs. 2 and 5, and are placed on a lower portion of the revolvable shaft (2) in several steps as seen in Fig. 1. When plural composite stirring vanes (4) are provided, each set of vanes may be placed so that its phase is shifted relative to each other. For example, the phase is shifted 90 degrees as seen in Figs. 1 and 2. An inner blade (4a) of the composite stirring vane (4) is in the form of, for example, a trapezoid, and is inclined at a specific angle with respect to the horizontal plane of revolution so that one side of the trapezoid is positioned in an upper portion of the revolvable shaft (2) with respect to the revolution direction (D) as shown in Fig. 5. On the other hand, an outer blade (4b) which is connected to the inner blade (4a) at its end, is inclined in an opposite direction to the inner blade (4a). The viscous liquid contained in the stirring vessel (1) is forced downwardly as shown in Fig. 1 in the vicinity of the revolving shaft (2) by the inner blade (4a) and is forced upwardly as shown in Fig. 1 at the inside of the wall face in the vessel by the outer blade (4b), when the revolvable shaft (2) is rotated, along a flow pattern depicted by arrow (A). In the stirring vessel (1) the baffle plates (5) are provided on the inner wall of the vessel along a line parallel to the axis of the revolvable shaft (2) at a plurality of positions, for example, four baffle plates at various heights, as shown in Figs. 1 and 3, and are provided at a plurality of positions along the circumferential direction. The baffle plates (5) are aligned vertically with respect to the horizontal plane of revolution or in the same inclined direction as the outer blade (4b) so that the outer blade (4b) of the composite stirring vanes may pass over two or three spaces occupied by the baffle plates. Among the baffle plates (5), the upper most baffle plate is positioned along the extension line of the surface layer stirring vane (3), and the other baffle plates (5) and the composite stirring vanes (4) are positioned so that the outer blade (4b) of the composite stirring vane (4) is situated in an area between two baffle plates (5) whereas the inner blade is situated outside of this area. The stirring reactor of the present invention is used for stirring the viscous liquid as follows. The liquid is charged into the vessel (1). On rotating the revolvable shaft (2), the whole liquid moves along the rotating direction of rotation of the revolving shaft (2) and some portions of the liquid in the vicinity of the revolving shaft (2) are moved forward along the line of the surface layer stirring vane and are pushed downwardly at the same time by the movement of the surface layer stirring vane. Subsequently the material is further pushed downwardly with the inner blade (4a) of the composite vane (4). The viscous material on the inner wall of the vessel (1) is forced upwardly by the outer blade (4b). Thus, the viscous liquid in convection flow is stirred along the flow pattern shown by the arrow (A) in Fig. 1. Simultaneously, with respect to the viscous liquid ascending along the inner side wall of the vessel (1), a part of the material impinges on the baffle plate (5) thereby converting its flowing direction towards nearly horizontal. Thus, shear mixing is sufficiently carried out according to a flow pattern depicted by arrow (B) in Fig. 1. In particular, by sufficiently carrying out the shear stirring with the surface layer stirring vane (3) and the corresponding baffle plate (5) depicted as flow pattern (B) in the vicinity of gas-liquid interface, the convection stirring depicted as flow pattern (A) is improved so as to be free from a dead spot of mixing in the vessel (1). The viscous liquid stirred in the vessel of the present invention is forced to circulate along the flow patterns A, B and C, which comprise convection mixing at a center and lower part of the vessel, and both convection and shear mixing in the vicinity of the gas-liquid interface, thereby effectively mixing the liquid uniformly and in a short time, particularly for medium viscous material which is liable to suffer from the dead spot discussed beforehand. In the stirring reactor of the present invention, in which a passive shear mixing of the material is carried out between the baffle plates (5) and the surface stirring vane (3) and composite stirring vane (4), since the stirring mixing can be efficiently conducted not only for low viscous material but also for medium viscous liquid, a liquid which may be changed from low viscosity to medium viscosity due to, for example, polymerization with the stirring, can be continuously treated. Similarly, when a medium viscous liquid is dissolved and diluted with a solvent to form a uniformly viscous liquid, the stirring reactor of the present invention can be effectively used due to its shear stirring phenomenon. According to the specific construction of the stirring reactor of present invention, a local shear stirring takes place throughout the entire vessel because of the combinations of baffle plates (5) and the surface layer stirring vane (3) and composite stirring vanes (4), and the reactor, therefore, is not only free from a dead spot of stirring in the vicinity of the gas-liquid interface, but is also capable of conducting a required stirring reaction in a short time. Further, according to the specific construction, since aeration at the gas-liquid interface is sufficiently caused due to the surface stirring vane, the reactor can be used for easily evaporating a volatile matter from the viscous liquid or easily dissolving or reacting a gaseous matter in the viscous liquid. Since the stirring reactor of the present invention can achieve an uniform and highly efficient stirring reaction, it can be used in the treatment of a viscous liquid to form uniform products in a short time. Further, the stirring reactor is also suitable for treatment of a medium viscous liquid.

Claims: A stirring-type reactor for viscous liquids comprising a stirring vessel (1) for receiving a viscous reaction material; a revolvable shaft (2) provided in the vessel (1); a surface layer stirring vane (3) having at least a pair of stirring blades provided on the revolvable shaft (2) at a position at or near the gas-liquid interface of the viscous liquid to be provided in the vessel (1); a composite stirring vane (4) having at least a pair of multiple stirring blades which extend radially toward the inner wall, an inner blade (4a) of each multiple blade being fastened on the revolvable shaft (2) below the surface layer stirring vane (3) and an outer blade (4b) of each multiple blade extending radially close to the inner wall of the vessel (1); and baffle plates (5) provided on the inner wall of the vessel, at least one baffle plate being provided at a position in the vessel corresponding to the position of the surface layer stirring vane (3) and at least one baffle plate being provided at a staggered position relative to the composite stirring vane (4); wherein the inner blade (4a) and the outer blade (4b) are inclined opposite to each other and wherein the outer blade (4b) is located in an area between two baffle plates (5) and the inner blade (4a) is located outside of this area. The stirring-type reactor of claim 1 wherein the surface layer stirring vane (3) has two pairs of stirring blades in the form of plates positioned symmetrically on the revolvable shaft (2), and wherein the planes of plates are aligned vertically or obliquely with respect to their plane of revolution around the revolvable shaft (2). The stirring-type reactor of claim 1 or 2 wherein a stirring blade of the surface layer stirring vane (3) is a single axis screw or multi-axis screw. The stirring-type reactor of claim 1, 2, or 3 wherein each multiple stirring blade consists of two blades which are aligned opposite angles relative to their plane of revolution around the revolvable shaft. The stirring-type reactor of any one of claims 1 to 4 wherein each baffle plate (5) has a rectangular or square shape. The stirring-type reactor of any one of claims 1 to 5 wherein a plurality of baffle plates (5) is provided on the inner wall of the vessel (1) along a line parallel to the axis of the revolvable shaft (2) The stirring-type reactor of claim 6 wherein a plurality of plates are provided in a circumferential direction along the inner wall of the vessel (1).

Inventors: IKEDA YOSHIHIRO, KAMIWANO MITSUO, KAWANAMI NORIO, IKEDA, YOSHIHIRO, KAMIWANO, MITSUO, KAWANAMI, NORIO
Applicants: KANEGAFUCHI CHEMICAL IND, KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA
Application year: 1990
Main classification: B01F7
IPC codes: B01F15, B01F7, B01J19, B01J10