METHOD FOR DEPOSITING A LAYER ON A SUBSTRATE AND ALSO A PROCESSING SYSTEM FOR THAT PURPOSE

Abstract: Method and apparatus for the batchwise simultaneous treatment of several substrates by chemical vapour deposition. The method is carried out in a closed system and before the deposition treatment, the substrates are subjected to a cleaning treatment in the same system.

Description: Method for depositing a layer on a substrate and also a processing system for that purpose The present invention relates to a method for depositing a layer on a substrate by receiving it in a treatment system which can be sealed with respect to the environment, comprising the introduction of the substrate into said system, the deposition of at least one layer on the substrate and the removal of the substra¬ te from said system. Such a method is known from US-A-*!,717,461. The latter des¬ cribes a method for depositing a layer on a substrate by sputter¬ ing. After being introduced into a loading/unloading station, the substrate is transferred to a treatment chamber. After a layer has been deposited, it is then subjected to an etching procedure in order to achieve the required configuration. Characteristic is the fact that the treatment stations can hold and treat only one sub¬ strate at the same time. Sputtering has a number of advantages and disadvantages. Characteristic of sputtering is the ballistic nature of the pro- cess. As a result of this, it is ultimately impossible to provide deep narrow holes and grooves, which are typical of the structure in, for example, megabit patterns, uniformly with a layer or to remove a layer. For this reason, chemical vapour deposition of materials at elevated temperature is also used in the prior art. Such a method is described, for example, in GB-A 2,190,345. In that case, the substrates are transferred directly into a processing furnace. In doing so, however, problems arise in relation to con¬ taminants present on the surface. Metal ion contaminants left behind may be regarded in the first place as contaminants, but the substrate oxide, which is always produced when the substrate is exposed to the air, must also be perceived as such. A final conta¬ minant is represented by molecules adsorbed on the substrate (pri¬ marily hydrocarbons). In the case of sputtering, any contaminants present are removed from the surface by a bombardment with high-energy (50 eV and higher) atoms before the sputtering treatment is started, the so-called sputter etch. A disadvantage of this etching process is the production of damage to, and defects in, the crystal lattice of the substrate as a result of the incidence of the bombarding atoms. The incident atoms penetrate the substrate and, together with a certain fraction of the contaminants, are trapped in the top layer of the substrate. The more the technology advances and increasingly higher requirements have to be imposed on the inte¬ grity of the increasingly thinner layers, the more the above-men¬ tioned sputter etch is increasingly inadequate and a search has to be made for methods in which the substrate oxide and the atoms adsorbed on the substrate are removed without undesirable atoms being incorporated in the top layer of the substrate and without defects in the crystal lattice of the substrate being the result of the cleaning process. In addition, it is necessary to ensure that the cleaned surface is not exposed to the air again. In the case of chemical vapour deposition, there is the advantage that structures can be uniformly provided with a layer, but there is the disadvan¬ tage that such a cleaning does not take place in the same appara¬ tus. This is one of the big disadvantages of chemical vapour deposition in which use has hitherto been made of separate appara¬ tuses for the removal of contaminants and the application of layers. The object of the present invention is to provide a method of the type described above which can be applied to chemical vapour deposition (CVD). This object is achieved with a method described above in that the deposition method comprises the batchwise simultaneous treatment of several substrates by chemical vapour deposition of a layer of material at elevated temperature, and in that the sub¬ strates are subjected to a cleaning treatment before the deposition treatment in the treatment system. Cleaning the substra- te in the closed system and then submitting it, in the still closed system, to a treatment apparatus ensures that the substrate is subjected to the method of chemical vapour deposition of materials without any contamination. Such a cleaning step may comprise plasma cleaning, chemical cleaning without exposure to high-energy (more than 5 eV as is usual in sputtering) atoms and to chemical clean¬ ing such as with HF and as described in the Application Serial no. 31,1^9 filed on 3rd November, 1989 in the USA, or by means of exposure to vapour containing ozone. Such a cleaning step must be distinguished from the etching step as is known from the abovemen- tioned US-A-4,717,46l. In that case, the etching is carried out as a treatment for obtaining the final substrate. That is to say, said treatment is essential for the substrate, while the cleaning in the case of the present application is necessary for removing any surface contaminants. Carrying out the deposition treatment for several substrates simultaneously improves the efficiency of the method. In contrast to sputtering, chemical vapour deposition is a comparatively slow process. The average substrate throughput time can be limited by simultaneously treating a number of substrates. The invention also relates to a processing system for carrying out the method described above which comprises a number of chambers connected via at least one distribution chamber incorporating substrate transfer means, which system comprises at least one loading and unloading chamber which can be sealed off with respect to the distribution chamber and at least one treatment chamber which can be sealed off with respect to the distribution chamber, the distribution chamber being equipped to handle one substrate in each case. According to the invention, said treatment system is characterized in that the treatment chamber comprises an apparatus for depositing a layer of material from a gas at elevated temperature, and in that a cleaning chamber is provided between the loading chamber and the treatment chamber. In this manner, the sub¬ strate can be subjected to a cleaning treatment before the treat- ent. Because the treatment of depositing a layer takes place at elevated temperature, as described above, and said temperature (up to 1000°C) may be appreciably higher than that required in sputter deposition, with the result that the thermal stressing is many times greater than for the apparatus mentioned in US-A-4,174,461, a problem arises in coupling a distribution chamber such as is known from US-A-4,717.46l to a vertical treatment tower such as is known from GB-A-2,190,345. As a result of the exposure to heat, both the lift mechanism provided in the chamber below the furnace and the handling apparatus provided in the distribution chamber will fail if, after the deposition of the layer, the substrates are unloaded immediately by means of the above-mentioned handling apparatus without a lengthy cooling period. According to a further advanta¬ geous embodiment of the invention, a heat lock is provided between the treatment chamber and the distribution chamber, which heat lock ensures that only a minimum heat flow is able to reach the distri¬ bution chamber, incorporating the handling apparatus provided, during the treatment. This may comprise a heat shield, but also an assembly of thermally insulating materials. Such a problem exists to a much lesser degree in a conventional vertical furnace (GB-A- 2,190,345) owing to the fact that the lift is in that case not situated in a vacuum chamber. The treatment apparatus according to the invention may, moreover, be equipped for the subsequent treat- ment of the substrates after one another in the vertical direction and, at the same time, the substrate transfer means in the distri¬ bution chamber may be constructed for moving the substrates in the horizontal direction. In this manner, use is made of available space in as expedient a manner as possible. As a result of the vertical treatment, thermal and chemical control over the substra¬ tes can be obtained in a very well regulated manner. Because the substrates have to be additionally heated in certain processes during the treatment, separate means are present for heating substrates in the treatment apparatus and, in particu- lar, the treatment chamber. In conditioning processes, in particular, in which material is deposited from the surrounding gas, a concentration gradient will frequently occur over the different substrates. In that case, it is advantageous to provide a compensating temperature gradient. If conditioning gases are used, it is frequently also advantageous to pre-heat. The treatment chamber described above may occur several times in the treatment system described above. The invention will be explained in more detail below with reference to some exemplary embodiments shown in the drawing. In the drawings: Figure 1 diagrammatically shows a processing system according to the invention in plan view, Figures 2a and 2b diagrammatically show a further embodiment of the processing system according to the invention in side eleva- tion. Figures 3a and 3* show in more detail in section parts of the processing vessel depicted in Figures 2a and 2b on different scale, and Figure 4 shows a cross section along the line IV-IV in Figure 3b. Figure 1 depicts a processing system according to the inven¬ tion which is indicated as a whole by 1. This comprises an inlet port 2 for introducing substrates, such as wafers, to be treated. These may be introduced separately or in magazines. The prlcessing system 1 comprises, in addition, an outlet port 3 for removal therefrom. After the inlet port 2, a cleaning apparatus 4 is provided, followed by reaction chambers 5. 6, 7. 8, 9 - The referen- ce numeral 10 indicates an adjustment station. To transport the substrates from the inlet port to the various processing chambers, handling apparatuses 11 are present which are capable of transport¬ ing the wafers (not shown) from the inlet port 2 piece by piece to the various chambers. Between the two handling apparatuses 11, a transfer apparatus indicated diagrammatically by 13 is present. Such a processing system can be used, for example, for depositing a so-called 0N0 configuration on a wafer. For certain integrated circuits, such an oxide layer/nitride layer/oxide layer sequence is of importance. However, it was difficult to achieve such layers in the prior art because it was possible for oxidation to occur in an uncontrolled manner on removing the substrate from the processing vessel, with all the disadvantageous consequences thereof. With the present invention it is now possible to avoid these disadvantages. At the same time, the wafers to be treated are introduced into the inlet port 2 in magazines. These are then removed one by one by the handling apparatus 11 and transferred to the cleaning apparatus 4. In this process cleaning and, in particular, removal of oxides is achieved, for example, with hydrogen fluoride. The wafers are then treated in the various chambers. In chamber 5, for example, dry oxidation may take place. Subsequent thereto, the nitride layer may be deposited in chamber 7, while wet oxidation is then used in chamber 8 or 6. During transfer between the different chambers, the substrate to be treated is always in a conditioned environment, i.e. ambient oxygen cannot affect the substrate. As a result, it is not necessary to clean the substrate every time. Because the wet oxidation and nitriding processes described above are comparatively lengthy, it is advantageous to load several substrates into one of the chambers, to seal it off and to treat them simultaneously so that the average treatment time per wafer is shortened. Chamber 9 then serves to apply an undoped polysilicon layer, while chamber 10 serves to cool the substrate from the high temperature at which it is treated. The substrate is then removed via the outlet port 3« Figures 2a and 2b diagrammatically show in section a part of a similar treatment system according to the invention. This compri¬ ses an inlet port 2, a distribution vessel 16 and a processing vessel indicated as a whole by 15. It is clear that this is an incomplete reproduction because in practice further treatment apparatuses are connected to the distribution vessel 16. In the embodiment shown here, the substrates indicated by 17 are introduc¬ ed into the inlet port 2 in magazines 18. The handling apparatus 11 for the substrates handles only one substrate simultaneously, with the result that one of the substrates 17 is transferred in each case from the magazine 18 to a point in front of the opening of the distribution vessel by means of the indexing mechanism 19. The processing vessel 15 comprises a processing chamber 20 with a magazine 23, a loading and unloading chamber 21 and a storage chamber 22 provided therein. At the same time, the storage chamber 22 is provided with means, which are not shown, for raising and lowering the magazine 23. This chamber can also be uncoupled from the rest of the apparatus. The treatment chamber 20 is surrounded by a diagrammatically shown heating device 29. The inlet port 2 is provided with a mechanism 19 for bringing the substrates in the magazine 18 into the correct position for the handling device 11 to be able to act on them. From Figure 2b, it is evident that, if the wafers 17 are introduced in the manner indicated in Figure 2a, magazine 23 is raised. Treatment chamber 20 is separated from the rest of the treatment system by the diagrammatically shown sealing means 25, with the result that products used and/or produced during the treatment cannot penetrate the rest of the processing system. If heating is used during the processing, it is desirable to provide thermal insulation 24. To clean the magazine 23, it is introduced into the storage chamber 22 after which the store 22 is separated from the rest of the processing system. Then the magazine 23 is raised upwards out of the storage chamber 22 for further cleaning. Figures 3a and b show a processing vessel suitable, in parti- cular, for the deposition of material on a substrate from a reacti¬ ve vapour. Because this is frequently a comparatively lengthy process (not less than several hours), it is necessary to carry it out batchwise to achieve an adequate production efficiency. For this purpose, the magazine 23 indicated as a whole comprises car¬ rier plates 30 (Figure 3a). These may be manufactured from various materials. In the embodiment described here, it is necessary to heat the substrates (not shown) subsequently deposited on the carrier plates, with the result that the carrier plates 30 are composed of a heat-conducting material. Such heating is usually an auxiliary heating, the heating, not depicted here, on the outside of the vessel (see Figure 2) being the main heating. Preferably, graphite is used for the plates. Said plates are fitted at the ends in tubes 31, two of the four being visible in Figure 3« Diagramma- tically depicted heating elements 32 and also temperature sensors 33 are provided in said tubes 31. Because various temperature sensors and heating elements are present, it is possible to achieve a temperature gradient over the various carrier plates 30. The processing vessel 20 is provided with a gas inlet 34 and also an outlet 35. Because it is necessary to preheat the gas for the method described above, heating means 36 are provided for this purpose. Because the gas becomes increasingly depleted as it passes through the vessel 20 towards the outlet, it is necessary for the reactivity of the gas to be greater in the vicinity of the outlet 35 than at the bottom of the vessel in order to obtain a uniform deposit on the various substrates. This is achieved by choosing the temperature of the carrier plates 30 higher at the top of the vessel than the temperature at the bottom of the vessel. In order to be able to clean the vessel, electrodes 37, with the aid of which cleaning can be provided at high frequency, are present. The loading and unloading chamber 21 (Figure 3b) is connected to the processing vessel 20. The cross sectional view shown in Figure 4 illustrates the operation thereof. From this it is evident that four fingers 40, which are able to rotate inwards into the position shown by broken lines by means of a linkage system 4l, are present. Normally, the fingers 40 will be in the position shown by full lines. The carrier plates 3 are provided, in a manner not shown, with slots in a manner such that, if the fingers 4θ are in the state shown by broken lines, they are able to move through the slots in the car¬ rier plates 30. In order to remove a substrate 30 situated on the carrier plates, it is necessary to move the carrier plate 30 con- cerned into the loading and unloading chamber 21 in a suitable manner. In this process, the carrier plates concerned are lowered or raised to an extent such that the fingers 40 can just move through them. Then the fingers 40 are moved to the position shown with broken lines. If the carrier plates are then allowed to drop, the substrate is freed from the carrier plate, as a result of which it can be taken out of the loading and unloading chamber 21 by handling apparatus 11. During loading, the substrate can be laid on the fingers in this position, after which the carrier plate is raised further. Figure 3 indicates that the processing vessel is provided with a sealing edge 3 at the bottom. This can be acted on by a 0- seal 39 to provide a seal. In this manner, the processing chamber can be separated completely from the rest of the processing system. Plate 42 can be raised and lowered with all the apparatus provided thereon, comprising in particular the carrier plates 30, by means of coupling 43 which is connected to a jacking apparatus provided in storage chamber 22. As is evident from Figure 3b, the diameter of said storage chamber 22 is substantially larger than that of the magazine 23 present in the treatment vessel 20. As a result, it is possible to allow the magazine 23 to move downwards between the heat shields 44 provided in the storage chamber 22. Coupling part 43 is connected to flange 45 which then acts on table 46 in which three threaded spindles 47 are provided for raising and lowering. The position shown with broken lines indicates the lowest position. The threaded spindles 7 are driven by means of motor 48 and trans¬ mission 49, sealing means 50 being present in order to provide vacuum-tight lead-through of the drive. Although the invention has been described above, in particu¬ lar, with reference to deposition on substrates from gases, it must be understood that the invention is not limited thereto and that it also extends to processes in which other reactive gases, or no reactive gases, are used at temperatures which may either be elevated or lowered. An example thereof is an embodiment in which the consecutive carrier plates are insulated with respect to one another and an RF field is applied between the plates. Such a method is used in a different apparatus described in US-A-4,6lO,748. In addition, it is possible to construct the magazine as a so-called quartz boat with slots, as a result of which the structu¬ res described above and having fingers become unnecessary because the wafers can be acted on at the edges. Only the characteristics such as those for which protection is claimed in the following claims are essential.

Claims: CLAIMS 1. Method for depositing a layer on a substrate by receiving it in a processing system which can be sealed with respect to the environment, comprising the introduction of the substrate into said system, the deposition of a layer on the substrate and the removal of the substrate from said system, characterized in that the depo¬ sition method comprises the batchwise simultaneous treatment of several substrates by chemical vapour deposition of a layer of material at elevated temperature, and in that the substrates are subjected to a cleaning treatment before the deposition treatment in the processing system. 2. Method according to Claim 1, wherein the cleaning treatment comprises cleaning the substrate before exposure to plasmas, the constituents of which have an energy of less than 50 eV. 3. Method according to Claim 1, wherein the cleaning treatment comprises a chemical cleaning. 4. Processing system for carrying out the method according to one of Claims 1-3, which comprises a number of chambers connected via at least one distribution chamber incorporating substrate transfer means, which system comprises at least one loading and unloading chamber which can be sealed off with respect to the distribution chamber and at least one processing chamber which can be sealed off with respect to the distribution chamber, the dis¬ tribution chamber being arranged to handle one substrate in each case, characterized in that the processing chamber comprises an apparatus for depositing a layer of material from a gas at elevated temperature, and in that a cleaning chamber is provided between the loading chamber and the processing chamber. 5. Processing system according to Claim 4, wherein a thermal seal is provided between the processing chamber and the distribution chamber. 6. Processing system according to Claim 4 or 5, wherein the thermal seal comprises a heat shield. 7. Processing system according to one of Claims 4-6, wherein the processing apparatus is arranged for the sequential treatment of the substrates in the vertical direction and wherein the substrate transfer means in the distribution chamber are constructed for moving the substrates in the horizontal direction. 8. Processing system according to one of Claims 4-7, wherein the processing chamber is arranged for simultaneously treating several substrates and wherein heating means are present therein which are provided in a manner such that the various substrates undergo a different temperature. 9- Processing system according to one of Claims 4-8, wherein heating means are present for the processing gas.

Inventors: CORSIUS HUBERTUS ARNOLDUS, GRANNEMAN ERNST HENDRIK AUGUST, PIEKAAR HANS WILLEM, SLUIJK BOUDEWIJN GIJSBERT, CORSIUS, HUBERTUS, ARNOLDUS, GRANNEMAN, ERNST, HENDRIK, AUGUST, PIEKAAR, HANS, WILLEM, SLUIJK, BOUDEWIJN, GIJSBERT
Applicants: ASM EUROP, ASM EUROPE B.V.
Application year: 1990
Main classification: H01L21
IPC codes: H01L21