Flux cored wire for use in stainless steel welding

Abstract: Described herein is a flux cored wire for use in stainless steel welding, the wire having a flux filled in a stainless steel sheath, the flux containing, on the basis of the total weight of the wire, 4.7-8.5% of TiO₂, 0.5-3.5% of Al₂O₃ and 0.6-3.0% of SiO₂ and/or ZrO₂ in proportions satisfying the following formula TiO₂ > Al₂O₃ + SiO₂ + ZrO₂ and further 0.02-0.25% of metal fluoride (in terms of F conversion value) and 0.1-1.0% of Ti. Desirably, the flux contains slag-forming components in a restricted range of 8.5-13.5% and in proportions satisfying the following formula Al₂O₃+ SiO₂ + ZrO₂ ≦ 5.0%.

Description: 〈BACKGROUND OF THE INVENTION〉 Field of the Invention This invention relates to use of a flux cored wire in stainless steel welding, and more particularly to use of a flux cored wire which is applicable to welding operations in all positions under the same conditions including not only downhand, sideward, vertical and horizontal fillet welding operations but also overhead welding operations, and which is capable of forming a weld metal with excellent characteristics in terms of welding operation and X-ray property. 〈Prior Art〉 Because of handiness coupled with high efficiency and quality, the demand for flux cored wires (FCW) has been lately on a keen increase even in stainless steel welding processes. However, heretofore their application have been restricted mostly to downhand and horizontal fillet welding operations and to part of welding operations in horizontal and vertical positions, finding almost no applications in operations in the overhead position. More specifically, the stainless steels which have lower heat conductivity and solidification temperature as compared with carbon steels require higher welding techniques in the horizontal and vertical welding position which are more susceptible to dribbling of molten metal than the downhand welding position. Especially in the overhead welding, it has been difficult to obtain practically satisfactory X-ray property even by the use of specially designed power source and shielding gas. Under these circumstances, various attempts have been made to meet the increasing demand for a flux cored wire which permits all-position welding. For example, flux cored wires of this sort are proposed in Japanese Patent Publication 59-15757 and Japanese Laid-Open Patent Application 59-212192. The first mentioned Japanese Patent Publication 59-15757 describes a wire which is intended mainly for horizontal and vertical position welding, while the Japanese Laid-Open Patent Application 59-212192 discloses a flux cored wire which is applicable to welding operations in all of the downhand, horizontal and vertical positions although the welding condition differs greatly between the downhand and vertical positions. Besides, both of these prior art wires require low current welding condition in the vertical position as compared with the downhand position. Accordingly, in a case where a welding operation involves all welding positions in its sequence, it becomes necessary to use different wires in the downhand and vertical (or horizontal) positions or to use a wire under different conditions. More specifically, it becomes necessary to use in the vertical welding position a current which is about 50% lower than in the downhand welding position despite a material drop in efficiency, and the necessity of weaving makes it difficult to obtain beads with short legs, coupled with a problem that the wire is applicable only to plates having a thickness greater than 5 mm and not to plates of smaller thicknesses. In addition, in case of downward welding in the vertical position, the operation is often rendered unfeasible by instable arc condition and dribbling of molten metal which destabilizes the molten pool. Thus, owing to the problems arising in controlling welding operations or problems of efficiency in the vertical position welding, the conventional flux cored wires (FCW) have found only restricted applications, and therefore overhead welding operations have thus far relied on the covered arc welding or TIG welding without application of FCW. US-A-4,366,364 discloses a flux-cored wire for use in gas-shielded arc welding. The flux includes the following: Metal fluoride as fluorine 0.025-0.35 (wt %) Metal carbonate ≦0.5 One or more selected from the group consisting of A1, Ti, Zr, V and Ca ≦0.75 TiO₂ 3.5-7.4 SiO₂ ≦2.0 MgO and/or ZrO₂ 0.03-1.2 Al₂O₃ ≦1.5 C ≦0.15 Mn 1.2-3.0 Si 0.3-1.2 〈SUMMARY OF THE INVENTION〉 In view of these situations, the present invention has as its object the provision of a flux cored wire for use in stainless steel welding, which can be used in all welding positions including the overhead position with improved operability and under the same conditions and which can form a weld metal of sound properties including X-ray property and so forth. Conventional flux cored wires intended for use in stainless steel welding in most cases employ a flux of the TiO₂-SiO₂-ZrO₂ system which is added with suitable amounts of Al₂O₃, MgO, MnO and the like for adjustment of viscosity and slag solidification temperature. The flux cored wires of this sort have the following problems: (1) It is difficult to use them especially in an all-position welding operation including the overhead position and to secure satisfactory operability in all of the welding positions; (2) The dribbling of molten metal can be suppressed by increasing the contents of the slag-forming components in the wire to produce a large amount of slag as in covered welding, but such an increase of the contents of slag-forming components causes a marked degradation in the X-ray property; (3) The welding conditions have to be changed depending upon the welding position, e.g., in vertical and overhead positions in which high current welding is infeasible, coupled with the difficulty of downward welding in vertical position due to the necessity of weaving. In order to solve these problems, the inventor has conducted an intensive study to find an optimum wire composition through optimization of the amount of slag production, solidification temperature and viscosity from the standpoint of maintaining excellent arc stability and concentration over a broad range of welding conditions, especially in consideration of the differences in optimum physical properties of the slag between the overhead and downhand welding positions. The present invention has been achieved based on the finding that the above-discussed problems are solved by the use of a flux of a TiO₂-Al₂O₃ system which contains Al₂O₃ as a major component and which is rich in TiO₂, securing an optimum balance of TiO₂, Al₂O₃, SiO₂ and/or ZrO₂ components and restricting the amount of metal fluorides, and adding Ti and restricting the amounts of the slag-forming agent and preferably (Al₂O₃ + SiO₂ + ZrO₃). Namely, in accordance with the present invention, there is provided use of a flux cored wire in stainless steel welding, the wire having a flux filled in a stainless steel sheath, the flux containing, on the basis of the total weight of the wire, 8.5 to 13.5% of slag-forming components comprising on the basis of the total weight of said wire 4.7-8.5% of TiO₂, 0.5-3.5% of Al₂O₃ and 0.6-3.0% of SiO₂ and/or ZrO₂ in proportions satisfying the following formula TiO₂ > Al₂O₃ + SiO₂ + ZrO₂ and further 0.02-0.25% of metal fluoride (in terms of F conversion value) and 0.1-1.0% of Ti. The flux does not substantially contain CO₂ or a carbonate. In accordance with another aspect of the invention, the proportions of slag-forming components satisfy the following formula Al₂O₃ + SiO₂ + ZrO₂ ≦ 5.0%. The above and other objects, features and advantages of the invention are enumerated in claims 3-10 and will become apparent from the following particular description and the appended claims, taken in conjunction with the accompanying drawing. 〈BRIEF DESCRIPTION OF THE DRAWING〉 In the accompanying drawing: Figs. 1(a) to 1(d) are sectional views exemplifying a number of flux cored wires; and Figs. 2 and 3 are diagrammatic views of the shapes of joints employed in Examples which will appear hereinlater. 〈PARTICULAR DESCRIPTION OF THE INVENTION〉 According to the invention, the respective flux components are contained respectively in the above-mentioned restricted ranges for the reasons as follows. In this regard, it is important to note that the desired effect or effects which are discussed below are produced not by one flux component alone but synergistically by a number of components which are incorporated into the flux composition in balanced proportions. (1) Optimization of TiO₂, Al₂O₃, SiO₂ & ZrO₂ Contents TiO₂ as a slag-forming component has the effects of improving slag covering and slag defoliation and as an arc stabilizing agent has the effects of improving the concentration of the arc and suppressing spattering. However, a TiO₂ content less than 4.7% is insufficient to secure these effects, while its content in excess of 8.5% will conversely invite deteriorations in slag covering, impairing the bead appearance and X-ray property. Accordingly, the content of TiO₂ should be in the range of 4.7-8.5% based on the total weight of the wire, preferably in the range of 5.8-8.2%. Al₂O₃ is a major component of the flux system according to the invention, and as a slag-forming component has an effects of raising the slag solidification temperature without changing its viscosity, along with an effect of improving the slag defoliation. MgO and ZrO₂ also serve to raise the solidification temperature but they are not suitable as a major component in consideration of the variation in slag viscosity which would be brought about by them. An Al₂O₃ content less than 0.5% is insufficient to obtain the desired effects, while a content in excess of 3.5 % will result in defective X-ray property. Consequently, the content of Al₂O₃ should be in the range of 0.5-3.5% based on the total weight of the wire, preferably in the range of 0.7-2.7%. SiO₂ and ZrO₂ which as a slag-forming component have the effects of improving the slag covering and raising the slag viscosity to ameliorate the bead shape, and are added solely or jointly. A content of SiO₂ and ZrO₂ smaller than 0.6% is insufficient to obtain the intended effects, while a content in excess of 3.2% will result in a bead of a defective convex shape and deteriorated X-ray property. Accordingly, the content of SiO₂ and/or ZrO₂ should be in the range of 0.6-3.2% based on the total weight of the wire, preferably in the range of 1.0-3.0%. The above-described flux components, however, should be added in proportions satisfying the condition of the following formula TiO₂ > Al₂O₃ + SiO₂ + ZrO₂ It is essential to comply to this condition for optimization of the slag solidification temperature and viscosity, improving the arc stability and concentration and broadening the range of appropriate condition to permit all-position welding operations under the same condition. (2) Metal Fluorides The metal fluoride is an essential component for improving the anti-porous property (X-ray property), and has an effect of adjusting the fluidity of the slag. It is important to determine the additive amount of the metal fluoride in such a manner as to balance other slag-forming components such as TiO₂. A metal fluoride content less than 0.02% is insufficient for securing the intended effects, while its content in excess of 0.25% will result in increased amounts of hume and spatters. Accordingly, the content of the metal fluoride should be in the range of 0.02-0.25% in terms of the value of F-conversion based on the total weight of the wire, preferably in the range of 0.02-0.15% from the standpoint of the welding operability (especially the slag covering). (3) Addition of Ti As an arc stabilizer, Ti has the effects of improving the arc concentration and reducing the spattering. In addition, as a deoxidizer Ti has the effect of improving the X-ray property. More importantly, Ti which is in an easily fusible form acts as a slag-forming agent through molten oxidation. Namely, in case of a FCW with an excessive content of an oxide slag-forming component, the welding current flows only through the sheath portion of the wire, delaying the meltdown of the inner flux which has a higher melting point than a metal and as a result giving rise to unmelted flux residues which deteriorate the X-ray property. Accordingly, the content of the slag-forming components in the wire has a limit. On the other hand, in order to prevent dribbling of molten metal in vertical and overhead welding positions, the slag-forming components need to be added in a large amount. According to the invention, in order to solve this problem, the wire of the invention incorporates TiO₂ and Al₂O₃ in appropriate balanced proportions which will be free of unmelted residues, while adding TiO₂ as a major component in a metal form which will hardly make unmelted residues. Easily meltable Ti forms TiO₂ through molten oxidation, taking part in the slag production to prevent dribbling of molten metal. However, a Ti content less than 0.1% is insufficient to secure the desired effects, while a Ti content in excess of 1.0% will increase spattering in the downhand welding position and result in a defective bead shape and an undercut. Therefore, the Ti content should be in the range of 0.1-1.0% based on the total weight of the wire, preferably in the range of 0.3-0.8%. Ti may be added in the form of a metal titanium or ferrotitanium. Although the invention has been described with regard to its essential points, it is desirable to add the following restrictions, if necessary, for broadening the range of applicable conditions in all welding positions, especially in vertical and overhead welding positions, and for realizing welding operations in a higher current region. (4) Contents of Slag-Forming Components & (Al₂O₃ + SiO₂ + ZrO₃) The content of the slag-forming components needs to be 8.5% or larger in order to prevent dribbling of molten metal. However, unmelted residues of the slag-forming components occur if its content is larger than 13.5%, impairing the X-ray property. Accordingly, the content of the slag-forming agent should be in the range of 8.5-13.5% based on the total weight of the wire, preferably in the range of 9.0-13.5%. Further, from the standpoint of the arc stability and concentration in a high current region and improvement of the X-ray property, it is desirable to hold the content of (Al₂O₃ + SiO₂ + ZrO₂) 5.0% or less based on the total weight of the wire, preferably in the range of 1.1-5.0%. Further, in view of the importance of the arc concentration (intensity) especially in vertical and overhead welding of thin plates, it is desirable to adjust the ratio of Ti/F (converted) to a value greater than 3.8, inclusive. By so doing, the "impingement" of molten droplets becomes stronger at a given current level especially in the overhead welding position, permitting straight wire motions and ensuring excellent welding operability. On the contrary, if the ratio of Ti/F exceeds 30, the intensification of the arc impingement which is obtained in the vertical and overhead welding positions becomes too strong in the downhand position and causes spattering to an objectionable degree. Therefore, the ratio of Ti/F should be smaller than 30. With regard to optional additives other than the components mentioned above, suitable amounts of the following substances may be added provided that substantially they do not contain CO₂ or a carbonate. Namely, the flux may be added with suitable amounts of: MgO, MnO or the like for fine adjustment of the physical properties of the slag; Bi₂O₃ for improving the slag defoliation; Na or K for improving the arc stability; and Ni, Cr, Mo, Mn, Si, Nb, C, N, Fe, Al, V, W, Cu or the like for adjustment of the weld metal composition. The metal sheath of the wire is of a stainless steel which is subject to no particular restrictions with regard to its composition and has a composition determined depending upon the purpose of use. For example, it may be a ferritic or austenitic stainless steel. There are no restrictions on the sectional shape of the wire, which may be of any one of the shapes exemplified in Fig. 1. Hereafter, the invention is illustrated more particularly by the following Examples. [Examples] The flux cored wires of Tables 2 and 3 were produced by the use of 0.7 mm(t) x 12 mm(w) stainless steel sheaths of the chemical compositions shown in Table 1. In these tables, the contents of the flux components are indicated by percentage in the total weight of the wire, and the contents of metal fluoride are indicated in terms of the F conversion values. The respective wires were examined by a welding test in various positions under the conditions shown in Table 4. The welding test was conducted by way of a welding operation including downhand, vertical and overhead positions for a butt joint as shown in Fig. 2, and a horizontal fillet welding operation as shown in Fig. 3. In case of the joint of Fig. 2, the test was conducted by way of multi-pass welding using a backing B, plates with a thickness T of 16mm, a bevel angle ϑ of 60°, a route face F of 1mm, and a route gap G of 3mm. In case of the joint of Fig. 3, the test was conducted by way of 1-pass welding using plates with a thickness T. The plates used in the tests were stainless steel plates as prescribed in JIS G4304 or G4305 and of a composition similar to the wires used. The results of the welding tests are shown in Tables 5 and 6, in which the assessment of the operation quality is indicated by O ○ (extremely good), ○ (good), ▵ (a little defective) and X (defective), and the assessment of the X-ray property was conducted according to JIS Z 3106. As clear from Table 6, the examples of the invention are all capable of welding in all positions and possess excellent operation quality along with satisfactory X-ray property. On the other hand, the Comparative Examples shown in Table 5 are mostly incompetent to the all-position welding, and the X-ray property is inferior even if the operation quality of all-position welding is satisfactory (No. 9). Chemical Composition of Sheath Metal Metals C Si Mn P S Ni Cr Mo A 0.010 0.48 1.04 0.021 0.004 10.03 19.25 - B 0.014 0.52 0.93 0.025 0.008 12.46 17.58 2.13 C 0.009 0.36 0.83 0.016 0.010 0.17 17.39 - Welding Conditions Welding Conditions Welding Positions Downhand Vertical Overhead Horizontal Fillet Current (A) 200 200 200 200 Voltage (V) 28 28 28 28 Speed (cm/min) 25-30 6-9 25-30 35 Note) Wire diam.: 1.2 mm Power source: DC-EP Shielding gas: CO₂, 20 ℓ /min As clear from the foregoing description, the present invention provides a flux cored wire suitable for use in stainless steel welding, employing a flux of a TiO₂-Al₂O₃ system which contains Al₂O₃ as a major component and which is rich in TiO₂, securing appropriate balancing of TiO₂, Al₂O₃, SiO₂ and/or ZrO₂ contents and restricting the content of a metal fluoride, or additionally adding Ti or restricting the contents of slag-forming agent and (Al₂O₃ + SiO₂ + ZrO₂), to permit all-position welding including the overhead position without changing the welding condition from one position to another while ensuring excellent welding operation quality to produce a weld metal with favorable X-ray property. Besides, the wire used in accordance with the invention has advantages that the vertical and overhead position welding operations are feasible with the same high current as in the downhand position, and straight wire feed is possible in upward or downward welding operations in vertical position, permitting formation of beads of short legs and application to thin plates.

Claims: Use of a flux cored wire in stainless steel welding, said wire having a flux filled in a stainless steel sheath, said flux containing, on the basis of the total weight of said wire, 0.1-1.0% of Ti, 8.5 to 13.5% of slag-forming components, and does not substantially contain CO₂ or a carbonate, wherein said slag-forming components comprise, on the basis of the total weight of said wire, 4.7-8.5% of TiO₂, 0.5-3.5% of Al₂O₃ and 0.6-3.2% of SiO₂ and/or ZrO₂ in proportions satisfying the following formula TiO₂ > Al₂O₃ + SiO₂ + ZrO₂ and further 0.02-0.25% of metal fluoride (in terms of F conversion value). Use according to Claim 1, wherein the slag-forming components include Al₂O₃, SiO₂ and ZrO₂ in proportions satisfying the following formula Al₂O₃ + SiO₂ + ZrO₂ ≦ 5.0%. Use according to Claim 1 or 2, wherein said flux contains 5.8-8.2% of TiO₂ based on the total weight of said wire. Use according to any of Claims 1 to 3, wherein said flux contains 0.7-2.7% of Al₂O₃ based on the total weight of said wire. Use according to any of Claims 1 to 4, wherein said flux contains 1.0-3.0% of SiO₂ and/or ZrO₂ based on the total weight of said wire. Use according to any of Claims 1 to 5, wherein said flux contains 0.02-0.15% of metal fluoride in F-conversion value, based on the total weight of said wire. Use according to any of Claims 1 to 6, wherein said flux contains 0.3-0.8% of Ti based on the total weight of said wire. Use according to any of Claims 1 to 7, wherein the ratio of Ti/F (F-conversion value) is in the range of 3.8 ≦ Ti/F ≦ 30. Use according to Claim 2, wherein said flux contains 9.0-13.5% of slag-forming components based on the total weight of said wire. Use according to Claim 2, wherein said flux contains Al₂O₃, SiO₂ and ZrO₂ in the range of 1.1-5.0% based on the total weight of said wire.

Inventors: KUROKAWA TSUYOSHI, MARUYAMA TOSHIHARU, NISHIKAWA YUTAKA, OGAWA TSUNESHI, KUROKAWA, TSUYOSHI, MARUYAMA, TOSHIHARU, NISHIKAWA, YUTAKA, OGAWA, TSUNESHI
Applicants: KOBE STEEL LTD, KABUSHIKI KAISHA KOBE SEIKO SHO ALSO KNOWN AS KOBE STEEL LTD.
Application year: 1990
Main classification: B23K35
IPC codes: B23K35