Liquid crystal apparatus

Abstract: A liquid crystal apparatus, comprising: a liquid crystal cell comprising a pair of substrates (11a,b), and a chiral smectic liquid crystal (1) showing at least two different optically stable states formed by cooling from a uniaxial alignment phase and disposed between the substrates (11a,11b); and a polarizer (P) and an analyzer (A) disposed to sandwiched the liquid crystal cell; wherein the chiral smectic liquid crystal (1), polarizer (P) and analyzer (A) are disposed to satisfy any one of the following sets of conditions I - IV characterized by combination of X, Y and Z directions shown below: X Y Z I clockwise counterclockwise perpendicular II clockwise clockwise parallel III counterclockwise counterclockwise parallel IV counterclockwise clockwise perpendicular with proviso that the chiral smectic liquid crystal (1) is disposed so that the long axes of the chiral smectic liquid crystal molecules are aligned with a twist in the X direction along the direction from the polarizer (P) toward the analyzer (A) to form an average molecular long axis proving one optically stable state, and when the average molecular long axis is switched to provide another optically stable state latched in the Y direction with respect to the direction from the analyzer (A) toward the polarizer (P), the polarizer (P) is disposed to have an electric vector transmission axis which is substantially in the Z direction with respect to the average molecular long axis.

Description: FIELD OF THE INVENTION AND RELATED ART The present invention relates to a display apparatus using a chiral smectic (SmC*) liquid crystal showing ferroelectricity, particularly a ferroelectric liquid crystal display apparatus with a suppressed coloring or tinging. In recent years, ferroelectric liquid crystal cells have been extensively developed in place of conventional nematic liquid crystal cells. A ferroelectric liquid crystal cell comprises a pair of substrates and a ferroelectric liquid crystal (FLC) disposed between the substrates disposed with a gap sufficiently small to suppress the formation of helical alignment structure of liquid crystal molecules in the chiral smectic phase in the bulk state, so that perpendicular molecular layers each composed of a plurality of liquid crystal molecules are aligned in one direction. Such a ferroelectric liquid crystal cell is characterized by a memory characteristic and high speed responsiveness attributable to a spontaneous polarization. An FLC display having a cell gap on the order of 1.0 - 2.0 microns and utilizing a so-called splay alignment state wherein molecules are aligned while being twisted, is approaching a level of practical utility. Such an FLC display developed heretofore is accompanied with a difficulty that its bright state is tinged with pale yellow or pale blue depending on the viewing angle or direction and thus has left a problem in respect of display quality. The US-A-4 709 discloses the presence of molecular twist at two stable states and refers to a disposition of a polarizer and an analyzer so as to provide a maximum contrast. Such a maximum contrast is given by aligning the polarizer axis and the analyzer axis so as to coincide with the projections of the liquid crystal molecules in the vicinity of the substrates onto the respective substrates. SUMMARY OF THE INVENTION In view of the above-mentioned problem of a known FLC display, an object of the present invention is to provide a ferroelectric liquid crystal apparatus, particularly a display apparatus, with a high display quality by suppressing coloring or tinging in the bright state. According to the present invention, there is provided a liquid crystal apparatus as represented by any one of the alternative embodiments according to claim 1, 2, 3 or 4. In the liquid crystal cell of the liquid crystall apparatus according to the present invention, the chiral smectic liquid crystal, polarizer and analyzer are disposed to satisfy any one of the following sets of conditions I - IV characterized by combination of X, Y and Z directions shown below: According to the arrangement of claim 1, 2, 3 or 4, the coloring of the whole panel is suppressed. Further, it is preferred to shift the electric vector transmission axis of the analyzer by an angle in the range of 0 - 20 degrees, preferably 1 - 10 degrees, in the direction of brightening the bright state from the position of the right angle cross nicols. These and other objects, features and advantages of the present invention will become more apparent upon a consideration of the following description of the preferred embodiments of the present invention taken in conjunction with the accompanying drawings. BRIEF DESCRIPTION OF THE DRAWINGS Figures 1A - 1D are a sectional view and schematic views for illustrating an ferroelectric display apparatus according to an embodiment (Example 1) of the present invention. Figures 2A - 2C are schematic views for illustrating a dextro-twist alignment structure. Figures 3A and 3B are schematic views for illustrating a method of examining the dextro-twist alignment structure. Figures 4A and 4B are a graph showing the panel color intensity of the display apparatus of Example 1 and a schematic view illustrating a viewing angle. Figures 5A and 5B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 1. Figures 6A and 6B are graphs showing polarizing plates directions and the panel color intensity according to Example 2. Figures 7A and 7B are graphs showing polarizing plates directions and the panel color intensity according to Example 3. Figures 8A and 8B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 2. Figures 9A and 9B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 3 Figure 10 is a sectional view and schematic view for illustrating an ferroelectric display apparatus according to an embodiment (Example 4) of the present invention. Figures 11A and 11B are a graph showing the panel color intensity of the display apparatus of Example 4 and a schematic view illustrating a viewing angle. Figures 12A and 12B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 4. Figures 13A and 13B are graphs showing polarizing plates directions and the panel color intensity according to Example 5. Figures 14A and 14B are graphs showing polarizing plates directions and the panel color intensity according to Example 6. Figures 15A and 15B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 5. Figures 16A and 16B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 6. Figure 17 is a sectional view and schematic views for illustrating an ferroelectric display apparatus according to an embodiment (Example 7) of the present invention. Figures 18A - 18C are schematic views for illustrating a levo-twist alignment structure. Figures 19A and 19B are a graph showing the panel color intensity of the display apparatus of Example 7 and a schematic view illustrating a viewing angle. Figures 20A and 20B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 7. Figures 21A and 21B are graphs showing polarizing plates directions and the panel color intensity according to Example 8. Figures 22A and 22B are graphs showing polarizing plates directions and the panel color intensity according to Example 9. Figures 23A and 23B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 8. Figures 24A and 24B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 9. Figure 25 is a schematic view for illustrating an ferroelectric display apparatus according to an embodiment (Example 10) of the present invention. Figures 26A and 26B are a graph showing the panel color intensity of the display apparatus of Example 10 and a schematic view illustrating a viewing angle. Figures 27A and 27B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 10. Figures 28A and 28B are graphs showing polarizing plates directions and the panel color intensity according to Example 11. Figures 29A and 29B are graphs showing polarizing plates directions and the panel color intensity according to Example 12. Figures 30A and 30B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 11. Figures 31A and 31B are graphs showing polarizing plates directions and the panel color intensity according to Comparative Example 12. DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of the present invention will now be described with reference to drawings. Example 1 Figure 1A is a sectional view of a ferroelectric chiral smectic liquid crystal display apparatus according to an embodiment of the present invention. Referring to Figure 1A, an analyzer A is disposed as a polarizing plate closer to an observer's eye 4 and remoter from a light source 5, and a polarizer P is disposed as a polarizing plate closer to the light source 5 and remoter from the observer's eye 4. An ferroelectric liquid crystal 1 is disposed in a dextro-twisted (clockwise rotatory) alignment structure along the direction from the polarizer P toward the analyzer A and sandwiched between a pair of transparent substrates 11a and 11b respectively having thereon electrodes 12a, 12b, transparent insulating films 13a, 13b of, e.g., SiO 2 , and alignment films 14a, 14b. In a particular embodiment, the light source 5 was a three-wavelength type light source (trade name "Mellowlook Akari-chan", available from Thoshiba K.K.) which was known as a bright backlight source. Figure 1B is a schematic view for illustrating a relationship of the positions of the analyzer A and polarizer P and a rubbing axis (which is substantially identical to the extension of the liquid crystal molecular long axis in a uniaxial anisotropic (or alignment) phase, such as nematic phase or smectic A phase). Figure 1B shows characteristics of this embodiment that the electric vector transmission axis P of the polarizer is set to a direction perpendicular to the average molecular long axis when it is latched in the counter-clockwise direction with respect to the direction from the analyzer A to the polarizer P (i.e., the left average molecular long axis 2), and the electric vector transmission axis A of the analyzer is shifted from the position of the right angle cross nicols by an angle in the range of 0 - 20 degrees in the direction of providing a brighter bright state. In this particular example, the analyzer axis A is shifted by 5 degrees in the direction of brightening the bright state given by right-angle cross nicols. Figure 1C is a view for illustrating the definitions of angles  P ,  A and  R from a reference axis (arbitrary X-axis) of the electric vector transmission axis P of a polarizer, the electric vector transmission axis A of an analyzer, and rubbing axis R, respectively. In this embodiment, various angles are defined as angles from the X-axis as shown in Figure 1C. In terms of angles from the X-axis, the relative positions among the electric vector transmission axis P 0 of the polarizer, the electric vector transmission axis A of the analyzer and the rubbing axis R are explained by:  R = 135 degrees,  P = 52 degrees and  A = 147 degrees. Figure 1D further shows a right average molecular axis 3 which is the average molecular axis when it is latched in the clockwise direction with respect to the direction from the analyzer A to the polarizer P. As a result, an angle 2a shown in Figure 1D represents an angle between the left average molecular axis 2 and the right average molecular axis 3, and a represents a tilt angle. Figures 2A - 2C are schematic views for illustrating a dextro-twist alignment structure of a ferroelectric chiral smectic liquid crystal used in this embodiment. More specifically, Figure 2A is a schematic view showing that the relationship between the liquid crystal molecular long axis 23 at the lower boundary (with the lower substrate) and the liquid crystal molecular long axis 22 at the upper boundary (with the upper substrate) is such that the molecular axes are twisted in the dextro-rotatory direction with respect to the direction 24 from the lower substrate 11a toward the upper substrate 11b. Figure 2B is a schematic view showing states of change of C-directors of liquid crystal as viewed from bottoms of cones of chiral smectic liquid crystal ranging from the lower substrate 11a to the upper substrate 11b with respect to a first stable state providing the right (D) average molecular axis 3 and a second stable state providing the left (L) average molecular axis 2. It is also shown that a dextro-twist occurs from the molecules 23 at the lower boundary to the molecules 22 at the upper boundary. Further, Figure 1C is a schematic view showing a chevron-type layer structure of a chiral smectic liquid crystal including Sm*C layers 25, molecules 21 in a central part which are aligned parallel to substrate boundaries, and rubbing directions R. In order to obtain the above-mentioned dextro-twist alignment structure, it is effective to use a ferroelectric liquid crystal having a negative Ps (spontaneous polarization) and a polar alignment film having a dipole moment directed generally inward of the cell, or to use a ferroelectric liquid crystal having a positive Ps and a polar alignment film having a dipole moment directed generally outward of the cell. In a particular example of the above embodiment, a dextro-twist alignment state was attained by injecting a ferroelectric liquid crystal "CS 1011" (trade name, available from Chisso K.K.) characterized by a negative Ps into a 1.5 microns-thick FLC cell having polyimide alignment films. In addition, it was confirmed that such a dextro-twist alignment state could also be formed by ferroelectric liquid crystal's "CS 1013" (trade name), "CS 1014" (trade name) (available from Chisso K.K.), etc., having a negative Ps in FLC cells with thicknesses of 1.0 - 2.5 microns having organic alignment films, such as films of polyimide and polyethylene oxide. Figures 3A and 3B are views for illustrating a method of examining such a dextro-twist state. These figures show color differences accompanying dextro-twist alignment and levo-twist alignment in chiral smectic liquid crystal cells with a thickness of about 1.0 - 2.5 microns. More specifically, as shown in Figure 3B, a chiral smectic liquid crystal cell in a dextro-twist alignment provides, (1) colors of purple - blue purple - pale blue in the second stable state having the left average molecular axis 2, e.g., at  A = 105 degrees,  P = 0 degree and  R = 90 degrees, and (2) colors of pale brown - pale yellow in the first stable state having the right average molecular axis 3, e.g., at  A = 75 degrees,  P = 0 degree and  R 90 degrees. From the above, a dextro-twist alignment can be identified. On the other hand, a chiral smectic liquid crystal cell in a levo-twist alignment, as shown in Figure 3A, provides, (1) colors of pale brown - pale yellow in the second stable state having the left average molecular axis 2, e.g., at  A = 105 degrees,  P = 0 degree and  R 90 degrees, and (2) colors of purple - blue purple - pale blue in the first stable state having the right average molecular axis 3, e.g., at  A = 75 degrees,  P = 0 degree and  R 90 degrees. Thus, a levo-twist alignment can be identified. Figure 4A is a view showing a viewing angle-dependence of the color intensity in the bright state of the above embodiment. Herein, as shown in Figure 4B, the viewing angle is defined as an angle from a reference axis (an arbitrary selected X-axis) when a point of viewing a chiral smectic liquid crystal panel 41 is changed along an orbit 42 like a conical rim with a fixed incident angle H in (H in is fixed at 40 degrees). In Figure 4A, the viewing angle corresponds to an angle of rotation along four concentric circles. Further, in Figure 4A, a distance from the center of the concentric circles represents a color intensity in terms of a distance between the chromaticity coordinates of the observed panel and the chromaticity coordinates of the standard light C on the color coordinate system (x, y) according to JIS Z8701. Further, some representative hues depending on observation directions are also shown together with arrows indicating the observation directions. Comparative Example 1 A display apparatus of Comparative Example 1 was prepared in the same manner as in the above Example 1 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 142 degrees and  A = 57 degrees as shown in Figure 5A. Figure 5B shows a viewing angle-dependence of color intensity according to Comparative Example 1. In view of Figure 5B and Figure 4A in comparison, it is understood that the coloring of the liquid crystal display apparatus of Example 1 was remarkably improved compared with that of Comparative Example 1. Example 2 A display apparatus of Example 2 was prepared in the same manner as in Example 1 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 57 degrees and  A = 142 degrees as shown in Figure 6A. At this time, the viewing angle-dependence of color intensity as shown in Figure 6B was attained. Example 3 A display apparatus of Example 3 was prepared in the same manner as in Example 1 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 52 degrees and  A = 142 degrees as shown in Figure 7A. At this time, the viewing angle-dependence of color intensity as shown in Figure 7B was attained. Comparative Example 2 A display apparatus of Comparative Example 2 was prepared in the same manner as in Example 1 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 147 degrees and  A = 52 degrees as shown in Figure 8A. At this time, the viewing angle-dependence of color intensity as shown in Figure 8B was attained. Comparative Example 3 A display apparatus of Comparative Example 3 was prepared in the same manner as in Example 1 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 142 degrees and  A = 52 degrees as shown in Figure 9A. At this time, the viewing angle-dependence of color intensity as shown in Figure 9B was attained. Example 4 Figure 10 is a schematic view for illustrating a positional relationship among the analyzer A, polarizer P and rubbing axis R according to another embodiment of the present invention. Except for the positional relationship, this embodiment is the same as the one of Example 1. More specifically, Figure 10 shows characteristics of this embodiment that the electric vector transmission axis P of the polarizer is set to the direction of the right average molecular long axis 3, and the electric vector transmission axis A of the analyzer is shifted from the position of right-angle cross nicols by an angle in the range of 0 - 20 degrees in the direction of providing a brighter bright state. In this particular example, the analyzer axis was shifted by 5 degrees in the direction of further brightening the bright state given by right-angle cross nicols. In this example,  R ,  P and  A as defined above were set to satisfy:  R = 135 degrees,  P = 128 degrees and  A = 33 degrees. The chiral smectic liquid crystal used at this time showed a tilt angle a of 7 degrees. Figure 11A is a view showing a viewing angle-dependence of the color intensity in the bright state of the above embodiment. Herein, as shown in Figure 11B, the viewing angle is defined as an angle from a reference axis (an arbitrary selected X-axis) when a point of viewing a chiral smectic liquid crystal panel 41 is changed along an orbit 42 like a conical rim with a fixed incident angle H in (H in is fixed at 40 degrees). In Figure 11A, the viewing angle corresponds to an angle of rotation along four concentric circles. Further, in Figure 11A, a distance from the center of the concentric circles represents a color intensity in terms of a distance between the chromaticity coordinates of the observed panel and the chromaticity coordinates of the standard light C on the color coordinate system (x, y) according to JIS Z8701. Further, some representative hues depending on observation directions are also shown together with arrows indicating the observation directions. Comparative Example 4 A display apparatus of Comparative Example 4 was prepared in the same manner as in the above Example 4 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 38 degrees and  A = 123 degrees as shown in Figure 12A. Figure 12B shows a viewing angle-dependence of color intensity according to Comparative Example 4. In view of Figure 12B and Figure 11A in comparison, it is understood that the coloring of the liquid crystal display apparatus of Example 4 was remarkably improved compared with that of Comparative Example 4. Example 5 A display apparatus of Example 5 was prepared in the same manner as in Example 4 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 123 degrees and  A = 38 degrees as shown in Figure 13A. At this time, the viewing angle-dependence of color intensity as shown in Figure 13B was attained. Example 6 A display apparatus of Example 6 was prepared in the same manner as in Example 4 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 128 degrees and  A = 38 degrees as shown in Figure 14A. At this time, the viewing angle-dependence of color intensity as shown in Figure 14B was attained. Comparative Example 5 A display apparatus of Comparative Example 5 was prepared in the same manner as in Example 4 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 33 degrees and  A = 128 degrees as shown in Figure 15A. At this time, the viewing angle-dependence of color intensity as shown in Figure 15B was attained. Comparative Example 6 A display apparatus of Comparative Example 6 was prepared in the same manner as in Example 4 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 38 degrees and  A = 128 degrees as shown in Figure 16A. At this time, the viewing angle-dependence of color intensity as shown in Figure 16B was attained. Example 7 Figure 17 is a schematic view for illustrating a positional relationship among the analyzer A, polarizer P and rubbing axis R according to another embodiment of the present invention. More specifically, Figure 17 shows characteristics of this embodiment that the electric vector transmission axis P of the polarizer is set to the direction of the left average molecular long axis 2, and the electric vector transmission axis A of the analyzer is shifted from the position of right-angle cross nicols by an angle in the range of 0 - 20 degrees in the direction of providing a brighter bright state. In this particular example, the analyzer axis was shifted by 5 degrees in the direction of further brightening the bright state. In this example,  R ,  P and  A as defined above were set to satisfy:  R = 135 degrees,  P = 142 degrees and  A = 57 degrees. The chiral smectic liquid crystal used at this time showed a tilt angle a of 7 degrees. Figures 18A - 18C are schematic views for illustrating a levo-twist alignment structure of a ferroelectric chiral smectic liquid crystal used in this embodiment. More specifically, Figure 18A is a schematic view showing that the relationship between the liquid crystal molecular long axis 123 at the lower boundary (with the lower substrate) and the liquid crystal molecular long axis 122 at the upper boundary (with the upper substrate) is such that the molecular axes are twisted in the levo-rotatory direction with respect to the direction 124 from the lower substrate 11a toward the upper substrate 11b. Figure 18B is a schematic view showing states of change of C-directors of liquid crystal as viewed from bottoms of cones of chiral smectic liquid crystal ranging from the lower substrate 11a to the upper substrate 11b with respect to a first stable state providing the right average molecular axis 13 and a second stable state providing the left average molecular axis 12. It is also shown that a dextro-twist occurs from the molecules 123 at the lower boundary to the molecules 122 at the upper boundary. Further, Figure 18C is a schematic view showing a chevron-type layer structure of a chiral smectic liquid crystal including Sm*C layers 125, molecules 121 in a central part which are aligned parallel to substrate boundaries, and rubbing directions R. In order to obtain the above-mentioned levo-twist alignment structure, it is effective to use a ferroelectric liquid crystal having a positive Ps (spontaneous polarization) and a polar alignment film having a dipole moment directed generally inward of the cell, or to use a ferroelectric liquid crystal having a negative Ps and a polar alignment film having a dipole moment directed generally outward of the cell. In a particular example of the above embodiment, a dextro-twist alignment state was attained by injecting a ferroelectric liquid crystal "ZLI-3488" (trade name, available from Merck K.K.) characterized by a positive Ps into a 1.5 microns-thick FLC cell having polyimide alignment films. In addition, it was confirmed that such a levo-twist alignment state could also be formed by a ferroelectric liquid crystal "ZLI-3489" (available from Merck K.K.), etc., having positive Ps in FLC cells with thicknesses of 1.0 - 2.5 microns having organic alignment films, such as films of polyimide and polyethylene oxide. Figure 19A is a view showing a viewing angle-dependence of the color intensity in the bright state of the above embodiment. Herein, as shown in Figure 9B, the viewing angle is defined as an angle from a reference axis (an arbitrary selected X-axis) when a point of viewing a chiral smectic liquid crystal panel 41 is changed along an orbit 42 like a conical rim with a fixed incident angle H in (H in is fixed at 40 degrees). In Figure 19A, the viewing angle corresponds to an angle of rotation along four concentric circles. Further, in Figure 19A, a distance from the center of the concentric circles represents a color intensity in terms of a distance between the chromaticity coordinates of the observed panel and the chromaticity coordinates of the standard light C on the color coordinate system (x, y) according to JIS Z8701. Further, some representative hues depending on observation directions are also shown together with arrows indicating the observation directions. Comparative Example 7 A display apparatus of Comparative Example 7 was prepared in the same manner as in the above Example 7 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 52 degrees and  A = 147 degrees as shown in Figure 20A. Figure 20B shows a viewing angle-dependence of color intensity according to Comparative Example 7. In view of Figure 20B and Figure 19A in comparison, it is understood that the coloring of the liquid crystal display apparatus of Example 7 was remarkably improved compared with that of Comparative Example 7. Example 8 A display apparatus of Example 8 was prepared in the same manner as in Example 7 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 147 degrees and  A = 52 degrees as shown in Figure 21A. At this time, the viewing angle-dependence of color intensity as shown in Figure 21B was attained. Example 9 A display apparatus of Example 9 was prepared in the same manner as in Example 7 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 142 degrees and  A = 52 degrees as shown in Figure 22A. At this time, the viewing angle-dependence of color intensity as shown in Figure 22B was attained. Comparative Example 8 A display apparatus of Comparative Example 8 was prepared in the same manner as in Example 7 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 57 degrees and  A = 142 degrees as shown in Figure 8A. At this time, the viewing angle-dependence of color intensity as shown in Figure 23B was attained. Comparative Example 9 A display apparatus of Comparative Example 9 was prepared in the same manner as in Example 7 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 52 degrees and  A = 142 degrees as shown in Figure 24A. At this time, the viewing angle-dependence of color intensity as shown in Figure 24B was attained. Example 10 Figure 25 is a schematic view for illustrating a positional relationship among the analyzer A, polarizer P and rubbing axis R according to another embodiment of the present invention. Except for the positional relationship, this embodiment is the same as the one of Example 7. More specifically, Figure 25 shows characteristics of this embodiment that the electric vector transmission axis P of the polarizer is set to a direction perpendicular to the right average molecular long axis 3, and the electric vector transmission axis A of the analyzer is shifted from the position of right-angle cross nicols by an angle in the range of 0 - 20 degrees in the direction of providing a brighter bright state. In this particular example, the analyzer axis was shifted by 5 degrees in the direction of further brightening the bright state. In this example,  R ,  P and  A as defined above were set to satisfy:  R = 135 degrees,  P = 38 degrees and  A = 123 degrees. The chiral smectic liquid crystal used at this time showed a tilt angle a of 7 degrees. Figure 26A is a view showing a viewing angle-dependence of the color intensity in the bright state of the above embodiment. Herein, as shown in Figure 26B the viewing angle is defined as an angle from a reference axis (an arbitrary selected X-axis) when a point of viewing a chiral smectic liquid crystal panel 41 is changed along an orbit 42 like a conical rim with a fixed incident angle H in (H in is fixed at 40 degrees). In Figure 26A, the viewing angle corresponds to an angle of rotation along four concentric circles. Further, in Figure 26A, a distance from the center of the concentric circles represents a color intensity in terms of a distance between the chromaticity coordinates of the observed panel and the chromaticity coordinates of the standard light C on the color coordinate system (x, y) according to JIS Z8701. Further, some representative hues depending on observation directions are also shown together with arrows indicating the observation directions. Comparative Example 10 A display apparatus of Comparative Example 10 was prepared in the same manner as in the above Example 10 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 128 degrees and  A = 33 degrees as shown in Figure 27A. Figure 27B shows a viewing angle-dependence of color intensity according to Comparative Example 10. In view of Figure 27B and Figure 26A in comparison, it is understood that the coloring of the liquid crystal display apparatus of Example 10 was remarkably improved compared with that of Comparative Example 10. Example 11 A display apparatus of Example 11 was prepared in the same manner as in Example 1 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 133 degrees and  A = 128 degrees as shown in Figure 28A. At this time, the viewing angle-dependence of color intensity as shown in Figure 28B was attained. Example 12 A display apparatus of Example 12 was prepared in the same manner as in Example 10 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 38 degrees and  A = 128 degrees as shown in Figure 29A. At this time, the viewing angle-dependence of color intensity as shown in Figure 29B was attained. Comparative Example 11 A display apparatus of Comparative Example 11 was prepared in the same manner as in Example 1 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 123 degrees and  A = 38 degrees as shown in Figure 30A. At this time, the viewing angle-dependence of color intensity as shown in Figure 30B was attained. Comparative Example 12 A display apparatus of Comparative Example 12 was prepared in the same manner as in Example 10 except that the positions of the analyzer axis A, the polarizer axis P and the rubbing axis R were changed to provide  R = 135 degrees,  P = 128 degrees and  A = 38 degrees as shown in Figure 31A. At this time, the viewing angle-dependence of color intensity as shown in Figure 31B was attained. As described above, the apparatus according to the present invention (Examples 1- 12) provided a better display quality as represented by suppressed coloring in the bright display state in comparison with apparatus outside the invention (Comparative Examples 1 - 12). Further, it is also shown that coloring was more remarkably suppressed in cases where the analyzer A was shifted from the position of right-angle cross nicols by 5 degrees in the direction of providing a brighter bright state than in cases of right angle nicols and than in cases where the polarizer P was shifted from the position of right-angle cross nicols by 5 degrees in the direction of providing a brighter bright state.

Claims: A liquid crystal apparatus, comprising: a liquid crystal cell comprising a pair of substrates (11a, 11b), and a chiral smectic liquid crystal (1) showing at least two different optically stable states formed by cooling from a uniaxial alignment phase and disposed between the substrates (11a, 11b), the molecular long axis of the liquid crystal (1) being aligned in one direction (R) in the uniaxial alignment phase and the liquid crystal (1) cooled from the uniaxial alignment phase being aligned to form either one of two averages molecular long axes (2, 3; 22, 23) corresponding to the two optically stable states on a left side and a right side of said one direction (R) as a central axes as viewed in a direction normal to the substrates; and a polarizer (P) and an analyzer (A) disposed to sandwiched the liquid crystal cell; wherein the chiral smectic liquid crystal, polarizer (P) and analyzer (A) are disposed to satisfy a set of conditions that the molecular long axes (2, 3; 22, 23) of the chiral smectic liquid crystal (1) are aligned (i) with a twist in a clockwise direction as viewed from the analyzer side toward the polarizer side in any one of the two optically stable states, and that, (ii) with respect to a leftward one of the two average molecular long axes (2,3; 22, 23) as viewed from the analyzer side toward the polarizer side, (iii) the polarizer (P) is disposed to have an electric vector transmission axis which is substantially perpendicular to the leftward one of the two average molecular long axes. A liquid crystal apparatus, comprising: a liquid crystal cell comprising a pair of substrates (11a, 11b), and a chiral smectic liquid crystal (1) showing at least two different optically stable states formed by cooling from a uniaxial alignment phase and disposed between the substrates (11a, 11b), the molecular long axis of the liquid crystal (1) being aligned in one direction (R) in the uniaxial alignment phase and the liquid crystal (1) cooled from the uniaxial alignment phase being aligned to form either one of two averages molecular long axes (2, 3; 22, 23) corresponding to the two optically stable states on a left side and a right side of said one direction (R) as a central axes as viewed in a direction normal to the substrates; and a polarizer (P) and an analyzer (A) disposed to sandwiched the liquid crystal cell; wherein the chrial smectic liquid crystal, polarizer (P) and analyzer (A) are disposed to satisfy a set of conditions that the molecular long axes (2, 3; 22, 23) of the chiral smectic liquid crystal (1) are aligned (i) with a twist in a clockwise direction as viewed from the analyzer side toward the polarizer side in any one of the two optically stable states, and that, (ii) with respect to a rightward one of the two average molecular long axes (2, 3; 22, 23) as viewed from the analyzer side toward the polarizer side, (iii) the polarizer is disposed to have an electric vector transmission axis which is substantially parallel to the rightward one of the two average molecular long axes. A liquid crystal apparatus, comprising: a liquid crystal cell comprising a pair of substrates (11a, 11b), and a chiral smectic liquid crystal (1) showing at least two different optically stable states formed by cooling from a uniaxial alignment phase and disposed between the substrates (11a, 11b), the molecular long axis of the liquid crystal (1) being aligned in one direction (R) in the uniaxial alignment phase and the liquid crystal (1) cooled from the uniaxial alignment phase being aligned to form either one of two averages molecular long axes (2, 3; 22, 23) corresponding to the two optically stable states on a left side and a right side of said one direction (R) as a central axes as viewed in a direction normal to the substrates; and a polarizer (P) and an analyzer (A) disposed to sandwiched the liquid crystal cell; wherein the chiral smectic liquid crystal, polarizer (P) and analyzer (A) are disposed to satisfy a set of conditions that the molecular long axes (2, 3; 22, 23) of the chiral smectic liquid crystal (1) are aligned (i) with a twist in a counter-clockwise direction as viewed form the analyzer side toward the polarizer side in any one of the two a optically stable state, and that, (ii) with respect to a leftward one of the two average molecular long axes (2, 3; 22, 23) as viewed from the analyzer side toward the polarizer side, (iii) the polarizer ist disposed to have an electric vector transmission axis which is substantially parallel to the leftward one of the two average molecular long axes. A liquid crystal apparatus, comprising: a liquid crystal cell comprising a pair of substrates (11a, 11b), and a chiral smectic liquid crystal (1) showing at least two different optically stabel states formed by cooling from a uniaxial alignment phase and disposed between the substrates (11a; 11b), the molecular long axis of the liquid crystal (1) being aligned in one direction (R) in the uniaxial alignment phase and the liquid crystal (1) cooled from the uniaxial alignment phase being aligned to form either one of two averages molecular long axes (2, 3; 22, 23) corresponding to the two optically stable states on a left side and a right side of said one direction (R) as a central axes as viewed in a direction normal to the substrates; and a polarizer (P) and an analyzer (A) disposed to sandwiched the liquid crystal cell; wherein the chiral smectic liquid crystal, polarizer (P) and analyzer (A) are disposed to satisfy a set of conditions that the molecular long axes(2, 3; 22, 23) of the chiral smectic liquid crystal (1) are aligned (i) with a twist in a counter-clockwise direction as viewed form the analyzer side towared the polarizer side in any one of the two optically stable states, and that, (ii) with respect to a rightward one of the two average molecular long axes (2, 3; 22, 23) as viewed from the analyzer side toward the polarizer side, (iii) the polarizer is disposed to have an electric vector transmission axis which is substantially perpendicular to the rightward one of the two average molecular long axes. An apparatus according to any one of claims 1-4, wherein the electric vector transmission axis of the analyzer is shifted from the position of right angle cross nicols by an angle in the range of 0 - 20 degrees in a direction of providing a brighter bright state. An apparatus according to any one of claims 1-4, wherein said uniaxial alignment phase is smectic A phase. An apparatus according to any one of claims 1-4, wherein said pair of substrates have been subjected to mutually parallel rubbing treatments. An apparatus according to any one of claims 1-4, which comprises a light source behind the polarizer. An apparatus according to any one of claims 1-4, wherein said chiral smectic liquid crystal has a chevron structure. An apparatus according to any one of claims 1-4, wherein said chiral smectic liquid crystal has a positive spontaneous polarization. An apparatus according to any one of claims 1-4, wherein said chiral smectic liquid crystal has a negative spontaneous polarization.

Inventors: IWAMOTO HIROFUMI, KAWAGISHI HIDEYUKI, MIHARA TADASHI, TSUBOYAMA AKIRA, IWAMOTO, HIROFUMI, KAWAGISHI, HIDEYUKI, MIHARA, TADASHI, TSUBOYAMA, AKIRA, IWAMOTO, HIROFUMI, C/O CANON K.K., KAWAGISHI, HIDEYUKI, C/O CANON K.K., MIHARA, TADASHI, C/O CANON K.K., TSUBOYAMA, AKIRA, C/O CANON K.K.
Applicants: CANON KK, CANON KABUSHIKI KAISHA
Application year: 1990
Main classification: G02F1
IPC codes: G02F1