Process for the preparation of ethylene-propylene copolymers

Abstract: A process is described for the preparation of ethylene-propylene copolymers having density values from 0.880 to 0.915 g/ml, for the copolymerization of ethylene and propylene, at a high pressure and at a high temperature, in a reactor vessel or tubular reactor, in the presence of a catalyst consisting of an aluminium trialkyl and a solid catalyst component containing 0.4 to 4.0 wt% titanium on a microspherical magnesium chloride support, in which the titanium is present partially in the trivalent and partially in the tetravalent form. The copolymers thus obtained are used for the production of film or for mixing with other polymers or with bitumen, in the production of bituminous casings for waterproofing, in the expanded foam sector and as a blending material for modifying the rheological character­ istics of LLDPE.

Description: The present invention relates to a process for the production of ethylene-propylene copolymers having low to very low density values, for use in various application sectors. Ziegler catalysts are widely known in technology and used on an industrial scale for the polymerization of ethylene and α-olefins in processes carried out at a low temperature and at a low pressure. The use of these catalysts is also known in technology for the polymerization or copolymerization of ethylene in processes carried out at a high temperature (in general above 120°C) and at high pressures (in general above about 500 bar), in reactors of the vessel or tubular type, under conditions similar to those used for the preparation of low-density polyethylene by means of radical initiators. For details of this technique reference should be made to the descriptions in British patent 828,828, US Patent 3,723,403 and French patent application 8320009. A special catalyst active in the copolymerization of ethylene with an α-olefin, containing four or more carbon atoms, in a tubular reactor operating at a high pressure and at a high temperature, has been described in European patent application NO. 243,327. According to this patent application, in particular, ethylene and butene-1 copolymers are obtained, having a butene-1 content from about 4 to about 8 wt% and density values from 0.915 to 0.940 g/ml. It has now been found that the catalyst described in the European patent application referred to above is capable of copolymerizing ethylene and propylene, yielding copolymers with an unusually high propylene content, having low to very low density values, which are useful in various industrial applications. The present invention accordingly relates to a process for the preparation of 1-butene free ethylene-propylene copolymers having a density from 0.880 to 0.915 g/ml and a content of propylene from 10 to 30% by weight, by copolymerization of the ethylene and propylene at a pressure of from 800 to 2000 bar, in a reactor vessel at a temperature of from 90 to 280°C, or in a tubular reactor at a temperature or torn 140 to 280°C, in the presence of Ziegler catalyst consisting of: (a) an aluminium trialkyl cocatalyst, and (b) a solid titanium catalyst component supported on magnesium chloride, the said component being formed of spherical particles at least 70% of which have a diameter from 0.5 to 10 µ m, an apparent density from 0.3 to 0.5 g/ml, a porosity from 0.6 to 1.2 ml/g, a surface area from 20 to 120 m²/g, a hydroxy alcohol content below 2 wt% expressed as weight of ethanol, and a titanium content from 0.4 to 4.0 wt%, expressed as metallic titanium, the said titanium being present partially in the trivalent and partially in the tetravalent state, with a ratio between the said titanium in the trivalent state and the total titanium from 0.2/l to 0.5/l, the atomic ratio between the aluminum in the cocatalyst (a) and the titanium in solid component (b) ranging from 15/1 to 70/1; characterized in that: said reactor vessel or tubular reactor is supplied with a gas mixture containing ethylene and propylene in a weight ratio between 15:85 and 75:25, and possibly hydrogen in a quantity from 0 to 2000 parts by volume per million parts by volume of the gas mixture. In the preferred embodiment, the catalyst component (b) contains from 2 to 3 wt% titanium and less than 1 wt% hydroxy alcohol, again expressed as weight of ethanol. The solid component of the catalyst may be prepared by means of a process, already known, which provides for the preparation of a magnesium chloride spherical granular support containing ethanol hydroxy, the activation of the support by interaction with titanium tetrachloride to produce the activated support and the treatment of the activated support with aluminium alkyl chloride to produce the solid component of the catalyst. More particularly, the support is prepared by the spray drying of an ethanolic magnesium chloride solution in a spray-drying apparatus. A typical technique is for a solution containing 40 parts by weight magnesium chloride per 100 parts by weight ethanol, maintained at about 130°C under a nitrogen pressure of about 5 bar, to be delivered to a spray-drying apparatus in a gaseous nitrogen countercurrent flow, the latter having an inlet temperature of the order of 350°C and an outlet temperature of the order of 230°C. Under these conditions a magnesium chloride support containing ethanol hydroxy is obtained, having the following general characteristics: spherical particles, at least 70 wt% of which have a diameter from 0.5 to 10 µm, an apparent density from 0.3 to 0.5 g/ml, a porosity from 0.6 to 0.8 ml/g, a surface area from 2 to 20 m²/g and a hydroxy alcohol content from 3 to 15 wt%, expressed as the weight of ethanol. A support of this type is activated by interaction with titanium tetrachloride and typically 70-80 parts by weight of the support are suspended in 100 parts by weight titanium tetrachloride and the suspension heated to 80-100°C for a period of 15 to 60 minutes. After separation and washing with liquid paraffin of the solid which has been treated in this way, an activated support is obtained having a shape, dimensions and apparent density similar to those of the support and the following other characteristics: a porosity from 0.7 to 1 ml/g, a surface area from 10 to 100 m²/g, a hydroxy alcohol content from 0.2 to 4 wt%, expressed as weight of ethanol, and a titanium content from 0.02 to 4 wt%, expressed as metallic titanium. The support,activated in this way, is then brought into contact with an aluminium alkyl chloride, selected from aluminium dialkyl chloride, aluminium alkyl dichloride and aluminium alkyl sesquichloride, having an atomic ratio between the aluminium (in the said aluminium alkyl chloride) and the titanium (in the said activated support) from 2/1 to 20/1, at a temperature from about 0 to about 100°C and for a period from about 100 hours to about 15 minutes. This treatment, which is preferably carried out in a liquid paraffin vehicle, enables the formation of the solid catalyst component having the characteristics specified above. The cocatalyst, used in combination with the solid component described above is an aluminium trialkyl containing from 2 to 4 carbon atoms in the alkyl portion. The preferred cocatalyst is aluminium triethyl. For preparation of the ethylene-propylene copolymers, a gas stream containing ethylene and propylene in a weight ratio from 15:85 to 72:25, and possibly hydrogen in a quantity from 0 to 2000 parts by volume per million parts by volume of the stream itself, is introduced, together with a stream of solid catalyst component and a cocatalyst stream, into a reactor vessel or tubular reactor, maintained at high temperature and pressure values and for relatively low residence times under polymerization conditions. In particular, the general operating conditions are as follows: reactor temperature: from 90 to 280°C (tubular reactor) from 140 to 280°C (reactor vessel) (with a gas inlet temperature of the order of 60°C) pressure: from 800 to 2000 bar residence time: from 15 to 60 s quantity of solid catalyst component: from 15 to 100 mg per kg monomers (ethylene and propylene) quantity of cocatalyst: from 0.2 to 1.0 mmoles per kg monomers (ethylene and propylene) atomic ratio between the aluminium (in the cocatalyst) and the titanium (in the solid from 15/1 to 70/1 and catalyst component): preferably from 15/1 to 45/1. The solid catalyst component is conveniently fed in in the form of a suspension in an inert hydrocarbon vehicle and the cocatalyst in the form of a solution in a liquid hydrocarbon solvent. The polymerization product is subjected at the reactor outlet to a multistage flash at progressively decreasing pressures to recover the copolymer and separate the unchanged monomers, which are recycled after purification and reintegration with fresh gases. The ethylene-propylene copolymer recovered in this way has typically characteristics within the following value ranges: - propylene content: (IR determination) (ASTM D-2238-69) from 10 to 30 wt% - density: (ASTM D-2839) from 0.880 to 0.915 g/ml - melting index: (ASTM D-1238, cond. E, proc. A) from 1 to 90 g/10′ - shear sensitivity: (ASTM D-1238) from 20 to 45 - haze: (ASTM D-1003) from 1.5 to 7.5% - dart drop test (impact): (ASTM D-1709) from 9 to 25 kJ/m - elongation at rupture (ASTM D-882B) longitudinal: from 350 to 700% transverse: from 700 to 800% Vicat test: (ASTM D-1525) from 60 to 90°C - colour: from A to B - odour on the polymer and film surface: none The colour values are determined by the modified ASTM D-1725 method, comparing the ethylene-propylene copolymer under examination with polyethylenes having a known colour and obtained by the standard method indicated above. The reference polyethylenes are assigned conventional colour values on a scale from A to D, where A represents the better colour. It is therefore possible according to the invention to obtain ethylene-propylene copolymers with low density values (from 0.905 to 0.915 g/ml) to very low density values (from 0.880 to 0.905 g/ml) depending on the operating range. These copolymers are of particular use in film production, in particular film cast and materials for mixing with other polymers and with bitumen in the production bituminous casings for waterproofing of buildings and building sites. They have also found uses in the expanded foam sector and as blending products for modifying the rheological properties of LLDPE. The experimental examples below have been given as a clearer illustration of the invention. Example 1 40 kg magnesium chloride with a water content of less than 0.7 wt% is dissolved in 100 kg anhydrous ethanol (with a water content below 0.2 wt%) at 130°C and under a nitrogen pressure of 5 bar. This solution is introduced, at the same temperature and at the same pressure, into a spray-drying apparatus of the "closed cycle drying" type from the firm NIRO, operating on an equiflow regime and with total recovery of the evaporated organic solvent. In this apparatus the solution is reduced to droplet form, operating at an inlet temperature of the nitrogen gas flow of 350°C and an outlet temperature of the nitrogen gas flow of 225-235°C. Under these conditions a solid granular material having the following characteristics is formed at the bottom of the spray-drier: particle shape and dimensions: spherical with about 90% particles having a diameter from 0.5 to 10 µm; hydroxy alcohol content: 10 wt%, expressed as weight of ethanol; apparent density: 0.4 g/ml; porosity: 0.7 ml/g; and surface area: 3 m²/g. 45 kg of the support obtained as described above are suspended in 60 kg titanium tetrachloride. The mixture is heated for 30 min at 100°C. At the end of this period it is cooled, the unchanged titanium tetrachloride is filtered off and the solid washed with n-decane until no further chlorine is present in the washing liquid. This yields an activated support having the following characteristics: shape and dimensions of the particles: similar to those of the support; hydroxy alcohol content: 2.5 wt%, expressed as weight of ethanol; titanium content: 2.3 wt%, expressed as metallic titanium; apparent density: similar to that of the support; porosity: similar to that of the support; and specific surface area: 18 m²/g. 45 kg of the activated support, obtained as described above, are suspended in 100 l isoparaffin C10-C12 (the commercial product ISOPAR G from the firm EXXON). The material is heated at 70°C and 18 kg aluminium diethyl chloride added gradually over the course of 1 hour, under constant stirring. On conclusion of the addition process, the material is maintained under constant stirring for a further hour at 70°C. This yields the solid catalyst component in the form of particles suspended in the liquid vehicle. The solid component in particle form has the following characteristics: shape and particle size: similar to those of the support; hydroxy alcohol content: 0.8 wt%, expressed as weight of ethanol; titanium content: 2.3 wt%, expressed as metallic titanium; ratio between titanium in the trivalent state and the total titanium in the trivalent and tetravalent states: 0.31/1; apparent density: similar to that of the support; porosity: 0.8 g/ml; and surface area: 26 m²/g. Example 2 Use is made for the polymerization test of a reactor vessel having a capacity of 0.5 l, fitted with a turbine stirrer, wave-breakers and a thermostatic control system. The following elements are fed in continuously at the top of the reactor vessel: an ethylene and propylene stream (in a weight rato of 64:36) at an overall flow rate of 30 kg/h, an aluminium triethyl solution in hexane (concentration: 6-7 mM/l), containing about 0.3 mM aluminium triethyl per kg total gas (ethylene and propylene), and a vaseline suspension (supplied by Carlo Erba) of the solid catalyst component prepared in Example 1, in an amount (dry weight) of 18.6 mg per kg total gas (ethylene and propylene). The operations are carried out at a reagent inlet temperature of 60°C, a polymerization temperature of 220°C, a stirring speed of 1700 revolutions/s and a residence time of about 30 s. The polymerization product is continuously discharged at the bottom of the reactor and subjected to a first flash in a high pressure separator (280 bar), followed by a second flash in a low pressure separator (1-1.5 bar). Diethylene glycol is injected at the site of discharge from the reactor, to deactivate the catalyst. Unreacted monomers, after separation of the flash treatment, are recycled after purification and reintegration with fresh monomers. The polymer is recovered by means of an extruder connected to the low pressure separator. The process is operated under these conditions for 48 h with the following results: monomer conversion: 11.0 wt%; mean hourly output of ethylene-propylene copolymer: 3.3 kg; propylene (C3) content in the copolymer: 13 wt%; melting index (MFI) of the copolymer: 22 g/10′; density of the copolymer: 0.910 g/ml; copolymer yield in g per g titanium (g/gTi): 256,000. The polymerization conditions are set out in Table I and the polymerization results in Table II. Examples 3-6 The procedure is similar to that described in Example 2, with variation of one or more of the reaction parameters, as shown in Table I. The polymerization results are shown in Table II. Example No. Inlet temperature °C Polymerization temperature °C Gas delivery (C2+C3 ; kg) Weight ratio (C2/C3) 2 60 220 30 64/36 3 60 236 30 63/37 4 60 247 30 62/38 5 60 238 30 70/30 6 60 254 30 69/31 Example No. Conversion (%) Output (kg) C3 bound (wt%) MFI (g/10′) Density (g/ml) Yield (g/gTi) 2 11.0 3.3 13 22 0.910 256,000 3 13.3 4.0 14 32 0.908 153,000 4 14.9 4.5 15 42 0.905 95,000 5 13.6 4.1 19 55 0.895 153,000 6 15.8 4.8 21 90 0.892 88,000 Example 7 Use is made of a steel tubular reactor of an industrial type having an internal diameter of 1 inch (25.4 mm) and a length of 600 m. Ethylene, propylene, hydrogen and 20 l/h of a suspension containing 30 g/l solid catalyst component, prepared as in Example 1, in a mixture of C10-C12 isoparaffin (ISOPAR G) are fed in at one end of the reactor. 8-12 l/h 13 wt% aluminium triethyl solution in heptane are fed in a few metres upstream from the site of introduction of the suspension. This ensures that the atomic ratio between the aluminium, in the said aluminium triethyl, and the titanium in the solid catalyst component is about 30-40/l. Polymerization is carried out under the following conditions: - C2+C3 feed to the reactor: 11,900 kg/h - C2/C3 weight ratio in the feed: 35/65 - hydrogen supply (based on total gas): 1800 vpm - pressure at the reactor inlet: 1260 bar - temperature at the reactor inlet: 60°C - polymerization priming temperature: 100°C - peak temperature: 265°C - residence time: 42-44 s A polyhydroxylated compound is introduced at the reactor outlet in order to deactivate the catalyst and the polymer is recovered via a multistage flash with direct feed to the extruder. The recovered gases are recycled to the reactor inlet after purification and reintegration with fresh gases. Under the operating conditions specified above, the conversion rate, based on ethylene, is about 60% and the output about 2.9 t/h ethylene propylene (mean catalytic yield: 210,000 g copolymer per g titanium), with a propylene content of 15 wt%, having the following characteristics: - density: 0.905 g/ml - melting index: 30 g/10′ - colour: A/B - odour (on the polymer): none Example 8 The procedure is similar to that described in Example 7 with the following differences: - C2+C3 feed to the reactor: 12,200 kg/h - C2/C3 weight ratio in the feed: 28/72 - hydrogen supply (based on total gas): 1,100 vpm - pressure at the reactor inlet: 1,280 bar - polymerization priming temperature: 95°C - peak temperature: 248°C Under these conditions the conversion rate, based on ethylene, is about 70% and the output about 3.0 t/h ethylene-propylene copolymer (mean catalytic yield: 165,000 g copolymer per g titanium) with a propylene of 20 wt% having the following characteristics: - density: 0.895 g/ml - melting index: 30 g/10′ - colour: A/B - odour (on the polymer): none Example 9 The procedure is similar to that described in Example 7 with the following differences: - C2+C3 feed to the reactor: 12,500 kg/h - C2/C3 weight reactor in the feed: 22/78 - hydrogen supply: none - pressure at the reactor inlet: 1,280 bar - polymerization priming temperature: 88°C - peak temperature: 250°C Under these conditions the conversion rate, based on ethylene, is about 68% and the output about 2.5 t/h ethylene-propylene copolymer (mean catalytic yield: 170,000 g copolymer per g titanium) with a propylene content of 25 wt%, having the following characteristics: - density: 0.880 g/ml - melting index: 7.0 g/10′ - colour: A/B - odour (on the polymer): none Example 10 The procedure is similar to that described in Example 7, with the following differences: - C2+C3 feed to the reactor: 12,500 kg/h - C2/C3 weight ratio in the feed: 22/78 - hydrogen supply (based on total gas): 800 vpm - pressure at the reactor inlet: 1,250 bar - polymerization priming temperature: 96°C - peak temperature: 255°C Under these conditions the conversion rate, based on ethylene, is about 73% and the output about 2.8 t/h ethylene-propylene copolymer (mean catalytic yield: 165,000 g copolymer per g titanium) with a propylene content of 28 wt%, having the following characteristics: - density: 0.880 g/ml - melting index: 30g/10′ - colour: A/B - odour (on the polymer): none Example 11 The procedure is similar to that described in Example 7, with the following differences: - C2+C3 feed to the reactor: 11,500 kg/h - C2/C3 weight ratio in the feed: 44/56 - hydrogen supply: none - priming temperature: 95°C - peak temperature: 240°C Under these conditions the conversion rate, based on ethylene, is about 35% and the output about 2.0 t/h ethylene-propylene copolymer (mean catalytic yield: 280,000 g copolymer per g titanium), with a propylene content of 11 wt%, having the following characteristics: - density: 0.9157 g/ml - melting index: 1.07 g/10′ - shear sensitivity: 37 - dart drop test (impact): 9.5 kJ/m - haze: 7.1% - elongation at rupture longitudinal: 560% transverse: 880% - Vicat: 85°C - colour: A/B - odour (on the polymer): none - no odour in the filming phase. Example 12 The procedure is similar to that described in Example 7, with the following differences: - C2+C3 feed to the reactor: 11,500 kg/h - C2/C3 weight ratio in the feed: 45/55 - hydrogen supply: none - priming temperature: 105°C - peak temperature: 255°C Under these conditions the conversion rate, based on ethylene, is about 39-40% and the output about 2.25 t/h ethylene-propylene copolymer (mean catalytic yield: 225,000 g copolymer per g titanium), with a propylene content of 13 wt%, having the following characteristics: - density: 0.910 g/ml - melting index: 2.27 g/10′ - shear sensitivity: 40 - dart drop test (impact): 9.6 kJ/m - haze: 2% - elongation at rupture longitudinal: 450% transverse: 810% - Vicat: 71°C - colour: A/B - odour (on the polymer): none - no odour in the filming phase.

Claims: Process for the preparation of 1-butene free ethylene-propylene copolymers having a density from 0.880 to 0.915 g/ml and a content of propylene from 10 to 30% by weight, by copolymerization of the ethylene and propylene at a pressure of from 800 to 2000 bar, in a reactor vessel at a temperature of from 90 to 280°C, or in a tubular reactor at a temperature of from 140 to 280°C, in the presence of Ziegler catalyst consisting of: (a) an aluminium trialkyl cocatalyst, and (b) a solid titanium catalyst component supported on magnesium chloride, the said component being formed of spherical particles at least 70% of which have a diameter from 0.5 to 10 µ m, an apparent density from 0.3 to 0.5 g/ml, a porosity from 0.6 to 1.2 ml/g, a surface area from 20 to 120 m²/g, a hydroxy alcohol content below 2 wt% expressed as weight of ethanol, and a titanium content from 0.4 to 4.0 wt%, expressed as metallic titanium, the said titanium being present partially in the trivalent and partially in the tetravalent state, with a ratio between the said titanium in the trivalent state and the total titanium from 0.2/l to 0.5/l, the atomic ratio between the aluminum in the cocatalyst (a) and the titanium in solid component (b) ranging from 15/1 to 70/1; characterized in that: said reactor vessel or tubular reactor is supplied with a gas mixture containing ethylene and propylene in a weight ratio between 15:85 and 75:25, and possibly hydrogen in a quantity from 0 to 2000 parts by volume per million parts by volume of the gas mixture. Process according to Claim 1, characterized in that the cocatalyst is an aluminium trialkyl containing 2 to 4 carbon atoms in the alkyl portion and is preferably aluminium triethyl. Process according to Claim 1, characterized in that the solid catalyst component contains 2 to 3 wt% titanium and less than 1 wt% ethanol. Process according to Claim 1, characterized in that it is carried out with a residence time from 15 to 60 s, using a quantity of solid catalyst component from 15 to 100 mg per kg monomers (ethylene and propylene), a quantity of cocatalyst from 0.2 to 1.0 mmoles per kg of the said monomers.

Inventors: INVERNIZZI RENZO, LANGIANNI ELIO, MASI FRANCESCO, MASINI SERGIO, MIRRA MAURO, INVERNIZZI, RENZO, LANGIANNI, ELIO, MASI, FRANCESCO, MASINI, SERGIO, MIRRA, MAURO
Applicants: ENICHEM SPA, ENICHEM S.P.A.
Application year: 1990
Main classification: C08F210
IPC codes: C08F210, C08F4