Microcellular paintbrush bristles

Abstract: Synthetic microcellular paintbrush bristles (10) are produced having a generally consistent cross-sectional shape along their length and a rough and irregular surface. The bristles comprise 15 to 40% cells (12) on a volume basis, the cells (12) being predominantly closed in the interior of the bristle and being open (14)along the wall to provide the rough and irregular surface.

Description: Field of Invention The present invention relates to improved paintbrush bristles and to a method of making them, and more particularly to microcellular synthetic paintbrush bristles. Background of the Invention Although synthetic resin paintbrush bristles have been long known and have even acquired a substantial market in the manufacture of paintbrushes, many paintbrushes continue to be made from hogs' hair. However, hogs' hair presents many difficulties, including expense, fluctuating market supply, and handling difficulties by the paintbrush manufacturer. Advantages of hogs' hair are its naturally flagged tips and its scaly surface which helps hold wet paint in the paintbrush during use. A further disadvantage, in addition to those of high cost and inconsistent availability as pointed out above, is its irregular cross-section as shown in Fig. 2 which is a photomicrograph of a transverse cross-section of a group of hogs' hair bristles, and which clearly illustrates the noncircular cross-section. The circular cross-section is desirable to the paintbrush manufacturer during manufacturing of the brush. It has long been desired to provide a synthetic paintbrush bristle which has all the attributes of hogs' hair and none of its disadvantages, and the patent literature contains many examples including US-A-4,307,478; US-A-4,409,372; US-A-3,186,018; US-A-3,256,545; US-A-3,344,457; US-A-3,706,111; US-A-4,559,268; US-A-2,418,492; US-A-3,173,163; and US-A-2,697,009. From these prior patents, it will be seen that it has been proposed to make paintbrush bristles of a variety of cross-sectional shapes, level or tapered, hollow or solid, and formed of a variety of synthetic plastic materials. Hollow synthetic paintbrush bristles have become very popular and among these the tapered hollow bristle as shown in the aforementioned US-A-4,307,478 has achieved wide acceptance. Also see US-A-4,376,746. One problem, however, is that hollow bristles cannot be satisfactorily tipped, something which is desirable for paintbrush bristles. In addition, the surface of synthetic paintbrush bristles, whether hollow or solid, and whether tapered or level, tends to be relatively smooth, and these synthetic bristles therefore lack the wet paint holding properties of rough surfaced hogs' hair bristles. The manufacture of cellular or porous bristles or filaments is also known, although no microcellular paintbrush bristle has ever previously been successfully made, insofar as is known. In this regard, paintbrush bristles require a number of particular physical characteristics not necessary in, or contrary to, those of textile yarns and other types of brush bristles, e.g. a high stiffness to weight ratio. Patents which mention porous or cellular broom bristles or porous textile yarns useful for the manufacture of fabrics include US-A-3,411,979; US-A-3,577,839; US-A-4,552,810; US-A-2,907,096; US-A-4,485,141; US-A-3,785,919; US-A-3,893,957; US-A-3,723,240; US-A-4,144,371; and US-A-2,200,946. Textile filaments are very fine and limp, while broom bristles are coarse and very stiff. However, microcellular bristles especially adapted for paintbrush use and having the desired characteristics have either not been previously contemplated or have not been able to be successfully made. Monofilaments have also been prepared from synthetic materials so as to provide a surface which is rough and irregular. In this regard there may be mentioned US-A-3,671,381; US-A-3,134,122; US-A-3,325,845; US-A-3,567,569; US-A-4,254,182; US-A-4,297,414; and US-A-4,522,884. For whatever the reason, a microporous paintbrush bristle having desirable characteristics including the desirable characteristics of the natural hogs' hair bristle, and further having addition advantages over natural hogs' hair bristle, has not previously been available. These characteristics include high "snap-back" stiffness, a high stiffness to weight ratio, cross-sectional uniformity, a rough paint-holding surface, flagged or tipped end, and low price. It is believed that while it might have been known that a cellular paintbrush bristle would be desirable, no one knew how to make such a bristle having the desired characteristics. Summary It is, accordingly, an aim of the present invention to overcome deficiencies of the prior art, such as indicated above. Another aim is to provide improved paintbrush bristles having a microcellular form which can be tipped or flagged and which have a rough surface, thereby simulating the good characteristics of natural hogs' hair bristles. Yet another aim of the invention is to provide a method of making satisfactory microcellular synthetic paintbrush bristles. It is a further aim of the invention to provide superior paintbrush bristles having surprisingly superior "snap-back" stiffness. It is a still further aim of the present invention to provide a synthetic bristle useful in the manufacture of paintbrushes and having reduced weight, microcellularity, high "snap-back" stiffnness, a high stiffness to weight ratio, good cross-sectional uniformity, a surface which holds wet paint well, an end which can be flagged or tipped, and low cost. These aims are achieved by a method having the features of claim 1 and by a bristle having the features of claim 6. Preferred features of the invention are indicated in the subsidiary claims. The superior paintbrush bristle according to the invention has a length of about 3.81 to 17.78 cm (1.5 to 7 inches) and a median diameter of about 0.127 to 0.3556 mm (5-14 mils); it can be tapered or level. It is formed from nylon, polyester, polyolefin or blends of these materials. It has a generally consistent cross-sectional shape along its length and a rough and irregular surface with one tip end thereof being flagged or tipped or capable of being flagged or tipped. On a volume basis, it comprises 15-40% cells, these cells being predominantly closed cells of generally elongated egg-shape in the interior of the bristle, but being open along the wall of the bristle to form a rough and irregular surface which holds wet paint well. The cells typically have a length of about 0.0254 to 0.1524 mm (1 to 6 mils) and a diameter of 0.00762 to 0.02286 mm (0.3 to 0.9 mils), and the bristle has a stiffness in the range of 5.1 to 21.1 m Kg/cm 3 (1.8 to 7.5 foot pounds per cubic inch), as measured in a bundle by the pendulum deflection method at a binding angle of 50°. Such a bristle is obtained by careful control of the extrusion process, including proper selection of starting materials and process parameters. In particular, selection of the blowing agent and amount thereof, and extruder zone temperatures are very important. The above and other aims and the nature and advantages of the instant invention will be more apparent from the following detailed description of embodiments, taken in conjunction with the accompanying drawings, wherein: Brief Description of Drawings Fig. 1 is an enlarged schematic view, partly in section, of a level bristle in accordance with the present invention; Fig. 2 is a photomicrograph of the end of a bundle of hogs' hair bristles; and Fig. 3 is a similar photomicrograph of the end of a bundle of microcellular bristles according to the present invention; Fig. 4 is a schematic tranverse cross-section of a polylobal paintbrush bristle in accordance with the present invention; Fig. 5 is a schematic perspective view of a tapered paintbrush bristle having a flagged tip; Fig. 6 is a xerographic enlargement of a 100X photomicrograph of a microcellular bristle according to the invention showing its surface roughness; Fig. 7 is an enlarged xerographic copy of a 200X photomicrograph of a longitudinally cut bristle according to the present invention showing its internal microcells; and Fig. 8 is a xerographic enlargement of a 200X photomicrograph of a cross-section of microcellular bristle according to the invention. Detailed Description of Embodiments Fig. 1 schematically shows a paintbrush bristle 10 in accordance with the present invention, the left part of the figure showing the bristle 10 in axial cross-section. Also see the photomicrographs of Figs. 6-8. The bristle is formed of a thermoplastic material typically used in the manufacture of paintbrush bristles, e.g. nylon, polyester, a polyolefin, or blends thereof, e.g. blends of polyester and polyolefin, of nylon and polyester, or of nylon and polyolefin. The bristle 10 will normally have a length in the range of 3.81 to 17.78 cm (1.5 to 7 inches), depending on the intended size of the paintbrush in which the bristle is to be used. It is preferred that the bristle 10 have a circular cross-section as shown in Figs. 1 and 3, and this is one of the main advantages of the present synthetic bristle compared with natural hogs' hair which has an inconsistent or irregular cross-section as shown in Fig. 2. The round or circular cross-section is advantageous to the brush manufacturer during the brush manufacturing process because it is typical to mix different sizes of bristles, and it requires less mixing when the bristles are circular thereby reducing manufacturing costs and providing the brush manufacturer with greater control to provide the best mixture of different bristles to maximize desirable brush characteristics. For level, i.e. non-tapered, bristles the diameter is generally in the range of 0.127 to 0.3556 mm (5 to 14 mils), and preferably 0.2032 to 0.3048 mm (8 to 12 mils). For tapered bristles, the range is desirably 0.1778/0.1016 mm (7/4 mils) to 0.4572/0.254 mm (18/10 mils), it being understood that the first figure of each pair is the diameter at the large or butt end and the second figure is the diameter at the small or tip end. As shown in Figs. 1, 7 and 8, the bristle 10 of the present invention is particularly characterized in having a large number of microvoids or microcells 12 throughout its interior. These microcells 12 are predominantly closed cells throughout the interior of the bristle 10, except that such bristle also has a pocked or open-celled skin with open surface cells 14 so as to give the bristle 10 a rough and irregular surface which holds wet paint in a superior manner compared to previous synthetic bristles. The total void space in the bristle 10 according to the present invention is about 15-40% on a volume basis. Preferably, the bristle is about 70% solid having about 30% by volume of the microcells 12 and 14. The microcells 12 and 14 typically have a length of about 0.0254 to 0.1524 mm (1 to 6 mils) and a diameter of about 0.00762 to 0.02286 mm (0.3 to 0.9 mils). The cells are generally of an elongated egg-shaped configuration with a length: diameter ratio of about 3-6:1 and having an axial cross-sectional area (see Fig. 7) of about 9.03 - 21.9 x 10 -5 cm 2 (1.4 - 3.4 x 10 -5 in 2 ). Fig. 4 schematically shows that a bristle 10' of the present invention may have a cross-section other than circular, e.g. in the case of Fig. 4 a tetralobal cross-sectional configuration. The microcellular bristle can also be hollow. In Fig. 5 a bristle 10'' is shown having a tapered configuration and having its end 16 flagged. It will be understood that the bristle 10 of Fig. 1 may also have its end flagged or tipped, as well as the bristle 10'' of Fig. 4, and also that a polylobal bristle such as the bristle 10'' of Fig. 4 can be tapered as shown in Fig. 5 rather than being level as shown in Fig. 1. A particular advantage of the non-hollow bristle of the present invention is its ability to have its end tipped; this is not possible with hollow bristles. Particularly important and surprising characteristics of the bristles 10, 10' and 10'' of the present invention are their stiffness properties. The bristles of the present invention have a stiffness which in diameters of about 0.2286 mm (9 mils) and above is not. merely just as good as solid synthetic bristles, but actually is superior. For example, a stiffness comparison according to the pendulum deflection test at 50° rotation was made between tapered bristles in accordance with the present invention made of polyester and having a diameter at the butt end of 0.3048 mm (12 mils) and a diameter at the tip of 0.2032 mm (8 mils), and otherwise identical bristles made of the same polyester blend, but not microcellular. In this test, the solid round bristles according to the prior art had a stiffness of 0.0161 m Kg/cm 3 (1.9 foot pounds per cubic inch), while the microcellular round bristles of the present invention had a stiffness of 0.0271 m Kg/cm 3 (3.2 foot pounds per cubic inch). Bristles according to the present invention have many advantages over those of the prior art as already pointed out above. In addition, there is a significant yield advantage due to a reduced usage of polymer to provide an equal volume of bristles. In terms of specific gravity, the following comparison is typical: conventional polyester bristles 1.31 g/cc microcellular polyester bristles 0.92-1.03 g/cc hogs' hair bristles 1.18 g/cc Therefore the microcellular bristle not only simulate hogs' hair but it is better than hogs' hair because it is rounder, more consistent and offers a yield advantage to the brush manufacturer. Thus, advantages include: 1) Increased yield to the brush maker, e.g. more brushes per kilogram or pound of bristle. 2) An irregular, rough or orange peel like surface which is similar to natural bristle and yet is a polymeric material. 3) In a solid round configuration, the yield of a hollow bristle is obtained yet the bristles can be tipped like solid round bristles. Hollow bristles cannot be tipped. Processing is critical to obtain the microcellular bristles of the present invention. The chemical blowing agent 15 introduced with the different polymers into the extruder. Using specific extrusion temperatures that control the rate of blowing, the chemical blowing agent is extruded with the polymer through a die or spinneret which determine the size and cross-section of the bristle. As in normal monofilament production the bristles are quenched in a water bath, oriented in a single or double stage oven arrangement and then annealed. The product is then cut or wound on different types of packages. Particularly important are the proper selection of a blowing agent and the extruder temperature profile. Thus, the microcellular bristles of the invention are formed during the extrusion process by disassociation of a chemical blowing agent. A number of these have been tried and many were unsatisfactory including Hostatron P1941 (Hoechst) and PBT blowing agent (General Electric). Other unacceptable blowing agents are those based on azo compounds such as azodicarbonamide and diisopropyl hydrazo dicarboxylate. Other blowing agents were unsatisfactory because of poor compatibility, e.g. poor dispersibility in the polymer melt, including Expandex 175 (barium salt of 5-phenyl tetrazole) and Expandex 5PT (5-phenyl tetrazole), both products of Olin. Blowing agents were unsuccessful because, among other reasons, some would not activate at the processing temperatures of the polymers, and/or resulted in processing problems with downstream conditions so that required physical properties such as flex, draw ratio, bristle size control, blowing, could not be achieved. Blowing agents found to be most satisfactory are based on a solid acid and solid base, such as citric acid and basic sodium bicarbonate. Most satisfactory was Hydrocerol CF 70, (Boehringer Ingelheim) which comprises a mixture of citric acid and basic sodium carbonate. Blowing agents of this type are unique because, even though full activation does not occur until 266°C (510°F), the blowing agent begins to be activated at a much lower temperature, i.e. about 160°C (320°F). Unsatisfactory blowing agents, on the other hand, have either a fixed activation temperature or an initial activation temperature which is much greater, e.g. 243°-271°C (470-520°F). The quantity of blowing agent is also very important. Thus, the quantity of blowing agent must not exceed 2% by weight based on the total composition, and the preferred range is 0.4-1% by weight, with the most preferred quantity being about 0.7%. Quantities less than about 0.3% give insufficient blowing, while quantities above about 2.0% give an uncontrolled open cellular product with unsatisfactory properties. As a result of the use of the preferred blowing agents, the resultant bristle contains the reaction products of the blowing agent components, e.g. carbon dioxide and sodium citrate, as well as in some cases a very small quantity of unreacted blowing agent; it is unknown whether or not these residues in the final product contribute to its superior properties. With regard to processing parameters, in general there is considerably more latitude in processing polymers without blowing agents than those with blowing agents. In particular, specific extrusion temperatures are required to achieve the desired cell structure inside the bristle and to achieve the desired surface characteristics. In general it has been found that in order to make satisfactory bristles according to the invention, the beginning zones in the extruder must be cooler than normal. For example, where the polymer is nylon 6,12 or polyolefin, the first two zones of the extruder should be kept at about 254°C (490°F) when manufacturing microcellular bristles, whereas a temperature of 260°C (500°F) in these two zones is usual when making noncellular bristles. Similarly, when making polybutylene terephthalate bristles and bristles of polyester/nylon blends, the first and second extruder zones are normally kept at 316°C (600°F) and 310°C (590°F), respectively, for the manufacture of noncellular bristles, whereas use of the same polymers to make microcellular bristles requires that the first and second extruder zones be maintained at only 271°C (520°F). The following examples of the invention are offered illustratively: Example 1 Microcellular nylon 6,12 bristles in accordance with the present invention are made in both level and tapered forms using the standard extrusion equipment normal in the manufacture of noncellular paintbrush bristles. As blowing agent there is used the above-mentioned Hydrocerol CF 70 in an amount of 0.7 weight percent. The temperature profile in the extruder, in comparison with the temperature profile for the standard noncellular bristle, is set forth in Table 1 below: Standard With Blowing Agent Extruder Zone #1 260°C (500°F) 254°C (490°F) Extruder Zone #2 260°C (500°F) 254°C (490°F) Extruder Zone #3 260°C (500°F) 260°C (500°F) Extruder Zone #4 260°C (500°F) 274°C (525°F) Transition Zone 260°C (500°F) 279°C (535°F) Transition Zone 260°C (500°F) 279°C (535°F) Spin Pump 260°C (500°F) 266°C (510°F) Transition Zone 260°C (500°F) 266°C (510°F) Die 260°C (500°F) 266°C (510°F) The resultant microcellular bristles have excellent properties in both level and tapered bristles, and the tip ends thereof are easily flagable or tipable. Example 2 Example 1 is repeated using nylon 6,10, nylon 6 and nylon 6,6. In all cases, excellent quality microcellular bristles are obtained. Example 3 The process of Example 1 is again repeated using polypropylene as the polymer, and with the same temperature profile as shown above in Table 1. Again, microcellular paintbrush bristles of excellent quality are obtained. Example 4 The process of Example 1 is again carried out, this time using polybutylene terephthlate, and tapered microcellular bristles are produced using the temperature profile shown in Table 2 below (again in comparison with the standard temperature profile used in the manufacture of noncellular bristles): Standard With Blowing Agent Extruder Zone #1 316°C (600°F) 271°C (520°F) Extruder Zone #2 310°C (590°F) 271°C (520°F) Extruder Zone #3 293°C (560°F) 266°C (510°F) Extruder Zone #4 293°C (560°F) 274°C (525°F) Transition Zone 282°C (540°F) 277°C (530°F) Transition Zone 282°C (540°F) 274°C (525°F) Spin Pump 288°C (550°F) 288°C (550°F) Transition Zone 266°C (510°F) 266°C (510°F) Die 266°C (510°F) 266°C (510°F) Again the results are excellent and the resultant microcellular polyester bristles are of excellent quality. Example 5 The process of Example 4 is repeated using a blend predominantly of polyester with a small amount of nylon 6,12. Again, the results are highly satisfactory with excellent quality microcellular tapered paintbrush bristles resulting. Example 6 Microcellular polyester level bristles according to the present invention were comparatively tested with otherwise equal non-cellular polyester bristles for stiffness. Three different sizes were tested, namely 0.2032 mm (8 mil) circular, 0.254 mm (10 mil) circular and 0.3048 mm (12 mil) circular. Stiffness was tested according to the pendulum deflection method wherein a bundle of bristles with a measured bundle cross-sectional area is rotated against a bending bar. The pressure of the bristles against the bar moves a pendulum, and the difference in rotation angles of the bristle bundle base and the pendulum is a measure of the stiffness or flexibility of the bristles. The results were as set forth below in Table 3: 8 mil Standard 7.62cm (3") 8 mil level microcellular 7.62cm (3") 0.0186 m Kg/cm 3 @ 50° (2.2 ft.lbs/in 3 ) 0.0195 m Kg/cm 3 @ 50° (2.3 ft.lbs/in 3 ) 0.0169 m Kg/cm 3 @ 50° (2.0 ft.lbs/in 3 ) 0.0169 m Kg/cm 3 @ 50° (2.0 ft.lbs/in 3 ) 0.0186 m Kg/cm 3 @ 50° (2.2 ft.lbs/in 3 ) 0.0186 m Kg/cm 3 @ 50° (2.2 ft.lbs/in 3 ) 0.0186 m Kg/cm 3 @ 50° (2.2 ft.lbs/in 3 ) 0.0186 m Kg/cm 3 @ 50° (2.2 ft.lbs/in 3 ) 0.0186 m Kg/cm 3 @ 50° (2.2 ft.lbs/in 3 ) 0.0186 m Kg/cm 3 @ 50° (2.2 ft.lbs/in 3 ) 10 mil Standard 7.62cm (3") 10 mil level microcellular 7.62cm (3") 0.0322 m Kg/cm 3 @ 50° (3.8 ft.lbs/in 3 ) 0.0381 m Kg/cm 3 @ 50° (4.5 ft.lbs/in 3 ) 0.0347 m Kg/cm 3 @ 50° (4.1 ft.lbs/in 3 ) 0.0466 m Kg/cm 3 @ 50° (5.5 ft.lbs/in 3 ) 0.0347 m Kg/cm 3 @ 50° (4.1 ft.lbs/in 3 ) 0.0424 m Kg/cm 3 @ 50° (5.0 ft.lbs/in 3 ) 0.0347 m Kg/cm 3 @ 50° (4.1 ft.lbs/in 3 ) 0.0424 m Kg/cm 3 @ 50° (5.0 ft.lbs/in 3 ) 0.0347 m Kg/cm 3 @ 50° (4.1 ft.lbs/in 3 ) 0.0424 m Kg/cm 3 @ 50° (5.0 ft.lbs/in 3 ) 0.0347 m Kg/cm 3 @ 50° (4.1 ft.lbs/in 3 ) 0.0424 m Kg/cm 3 @ 50° (5.0 ft.lbs/in 3 ) 12 mil Standard 7.62cm (3") 12 mil level microcellular 7.62cm (3") 0.0381 m Kg/cm 3 @ 50° (4.5 ft.lbs/in 3 ) 0.0576 m Kg/cm 3 @ 50° (6.8 ft.lbs/in 3 ) 0.0381 m Kg/cm 3 @ 50° (4.5 ft.lbs/in 3 ) 0.0644 m Kg/cm 3 @ 50° (7.6 ft.lbs/in 3 ) 0.0381 m Kg/cm 3 @ 50° (4.5 ft.lbs/in 3 ) 0.0644 m Kg/cm 3 @ 50° (7.6 ft.lbs/in 3 ) 0.0381 m Kg/cm 3 @ 50° (4.5 ft.lbs/in 3 ) 0.0644 m Kg/cm 3 @ 50° (7.6 ft.lbs/in 3 ) 0.0381 m Kg/cm 3 @ 50° (4.5 ft.lbs/in 3 ) 0.0576 m Kg/cm 2 @ 50° (6.8 ft.lbs/in 3 ) 0.0644 m Kg/cm 3 @ 50° (7.6 ft.lbs/in 3 ) It will be evident to those skilled in the art that various other changes and modifications may be made without departing from the scope of the invention as defined in the claims and the invention is not to be considered limited to what is shown in the drawings and described in the specification.

Claims: A method of manufacturing a synthetic microcellular bristle (10) for use in brushes which includes the formation of a plurality of closed cells (12) in the interior of the bristle by adding a blowing agent to the melted synthetic material whereby the cells are produced by the gas bubbles of the blowing agent, characterised in that , to ensure that the cells comprise 15 to 40% of the bristle on a volume basis and that the bristle is given a generally consistent cross-sectional shape along its length with the external surface of the bristle being substantially straight throughout its length and with the cells along its wall surface being made open to provide a rough and irregular surface along that wall surface, the following steps are included in the method : (a) 0.3 to 2% by weight of a blowing agent based on the total composition is fed to an extruder, the blowing agent comprising a mixture of a solid base and a solid acid and having an initial activation temperature lower than the temperature within the extruder; and (b) the beginning zones in the extruder are maintained at a lower temperature than the temperature normally used for a bristle of said synthetic material when not using the blowing agent, for example, 6 to 45°C (10 to 80°F) lower. A method according to claim 1, wherein the blowing agent is present in an amount of 0.4 to 1% and comprises a mixture of citric acid and basic sodium carbonate, the blowing agent having an initial activation temperature of about 160°C (320°F) and a normal activation temperature of about 266°C (510°F). A method according to claim 1 or claim 2 which comprises melting one or more materials selected from the group consisting of (a) a synthesized polymer, (b) a co-polymer, (c) an alloy, or (d) a mixture of synthetic polymers, to a temperature appropriate for a hot melt extrusion through small-diameter orifices, adding blowing agent material to the melted material or materials to create gaseous bubbles throughout the entire mass of the latter in its subsequent extruded form in order to generate a multiplicity of randomly-located cells resulting from the action of the blowing agent within and throughout the synthetic material and to elongate the cells in the axial direction of the bristle, and drawing the melted material or materials to form a bristle having a substantially uniform cross-sectional shape. A method according to any one of claims 1 to 3, in which the blowing agent creates a scaly exterior wall surface on the bristle derived from randomly-located craters formed when bubbles generated by the blowing agent material rupture the exterior surface and randomly-located peaks formed from the action of gas bubbles which are near, but do not rupture, the exterior surface. A method according to any one of claims 1 to 4, in which the bristle is substantially circular in cross-section. A synthetic microcellular bristle (10) made by the method of claim 1 or any claim appendant thereto, the bristle having a plurality of closed cells (12) formed in the interior thereof as a result of the action of the gas bubbles of a blowing agent added to the melted synthetic material, characterised in that (a) the bristle is a paintbrush bristle having a generally consistent cross-sectional shape along its length and a rough and irregular wall surface, the bristle comprising 15 to 40% cells on a volume basis and having open cells along its wall to provide the rough and irregular surface with the external surface of the bristle being substantially straight throughout its length; (b) the bristle has a length of about 3.81 to 17.78 cm (about 1.5 to 7 in.) and a median diameter of about 0.127 to 0.3556 mm (5 to 14 mils); (c) the bristle is formed of a thermoplstic material selected from the group consisting of nylon, polyester, polyolefin and blends thereof and having one end thereof flagged or tipped; (d) the cells have a length of about 0.0254 to 0.1524 mm (1 to 6 mils) and a diameter of about 0.00762 to 0.02286 mm ((0.3 to 0.9 mils); and (e) the bristle has a stiffness in the range of 5.1 to 21.1 m kg/cm 3 (1.8 to 7.5 ft. lbs./in 3 ). A synthetic microcellular bristle according to claim 6 which is tapered along its length. A synthetic microcellular bristle according to claim 6 or claim 7 having a circular cross-section. A synthetic microcellular bristle according to any one of claims 6 to 8 having a multi-lobal cross-section. A synthetic microcellular bristle according to any one of claims 6 to 9 formed of nylon 6,12. A synthetic microcellular bristle according to any one of claims 6 to 9 formed of a blend of polyester and polyolefin. A synthetic microcellular bristle according to any one of claims 6 to 9 formed of a blend of nylon and polyester. A synthetic microcellular bristle according to any one of claims 6 to 9 formed of a blend of nylon and polyolefin. A synthetic microcellular bristle according to any one of claims 6 to 13 which comprises a small amount of sodium citrate and wherein the cells contain predominantly carbon dioxide. A synthetic microcellular bristle according to any one of claims 6 to 14, in which the exterior of the bristle has an irregular scale-like surface finish derived from randomly-located craters formed when a gas bubble ruptures the exterior surface and randomly-located peaks formed by the action of gas bubbles which are near, but do not rupture, the exterior surface.

Inventors: O'BRIEN TIMOTHY D, WAGNER WILLIAM H, O'BRIEN, TIMOTHY D., WAGNER, WILLIAM H.
Applicants: NEWELL OPERATING CO, NEWELL OPERATING COMPANY
Application year: 1990
Main classification: A46D1
IPC codes: A46D1, D01D5