Olefin polymerization catalyst and process for the polymerization of olefins

Abstract: In accordance with the present invention, there are provided olefin polymerization catalysts comprising [A] a titanium catalyst component containing titanium, magnesium and halogen as its essential ingredients, [B-1] a transition metal compound containing a ligand having a cycloalkadienyl skeleton, [C] an organoaluminum oxy-compound and, if necessary, [D] an organoaluminum compound. Further, in accordance with the invention, there are provided olefin polymerization catalysts comprising [A] a titanium catalyst component containing titanium, magnesium and halogen as its essential ingredients, [B-2] a transition metal compound containing a ligand having a cycloalkadienyl skeleton and an anion compound containing boron, and [C] an organoaluminum oxy-compound and/or [D] an organoaluminum compound.

Description: This invention relates to an olefin polymerization catalyst and a process for the polymerization of olefins using said catalyst. It has heretofore been known that titanium based catalysts composed of a titanium compound and an organoaluminum compound are used as catalysts for the preparation of α-olefin polymers, for example, ethylene polymers or ethylene/α-olefin copolymers. Generally, olefin polymers obtained with titanium based catalysts have a broad molecular weight distribution and a broad composition distribution, but are poor in surface non-tackiness and transparency. On the one hand, there have recently been proposed processes for the preparation of the ethylene/α-olefin copolymers using catalysts composed of zirconium compounds and aluminoxanes as a new type of Ziegler catalyst for olefin polymerization. WO 89/501 950 and WO 89/502 036 disclose processes for the preparation of transition metal compound catalysts containing ligands having a cycloalkadienyl skeleton and anions containing elementary boron, and teach that the catalysts exhibit activities in olefin polymerization. Olefin polymers obtained with the above-mentioned new type of Ziegler catalysts for olefin polymerization usually have a narrow molecular weight distribution and a narrow composition distribution. However, olefin polymers which have a broad molecular weight distribution suitable for certain purposes and which have excellent moldability have ardently been desired. US-A-4 659 685 discloses a catalyst system which is a combination of a titanium compound supported on magnesium dichloride and at least one other metallic catalyst containing cyclopentadienil ligands supported on alumina and a cocatalyst such as aluminoxane. This catalyst yields polyolefins having broad and multimodal molecular weight distribution. Further, it is difficult to obtain olefin polymers having a high molecular weight by polymerization or copolymerization of olefins in the presence of transition metal compound catalysts containing ligands having a cycloalkadienyl skeleton. Accordingly, it has been desired that transition metal compound catalysts containing ligands having a cycloalkadienyl skeleton which are capable of giving olefin polymers having a high molecular weight be developed. The present invention seeks to provide olefin polymerization catalysts having excellent polymerization activities and capable of giving olefin (co)polymers which have well balanced physical properties such as a broad molecular weight distribution, excellent moldability and a narrow composition distribution. The invention also seeks to provide a process for the polymerization of olefins using said catalysts. The first olefin polymerization catalyst of the invention is obtainable by pre-polymerizing an olefin in a suspension containing [A] a titanium catalyst component containing titanium, magnesium and halogen as its essential ingredients, [B-1] a transition metal compound containing a ligand having a cycloalkadienyl skeleton, and [C] an organoaluminum oxy-compound. The pre-polymerization may be carried out in a suspension which also contains [D] an organoaluminum compound. The second olefin polymerization catalyst of the invention comprises (I) a solid catalyst s described above, and (II) [C] an organoaluminum oxy-compound and/or [D] an organoaluminum compound. The process for the polymerization of olefins of the present invention comprises polymerizing or copolymerizing olefins in the presence of an olefin polymerization catalyst as illustrated above. The olefin polymerization catalysts of the invention have excellent polymerization activities and are capable of giving high molecular weight olefin (co)polymers having a broad molecular weight distribution and excellent moldability. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a graph showing an IR spectrum of a benzene-insoluble organoaluminum oxy-compound used in the present invention. Fig. 2 is a graph showing an IR spectrum of a known benzene-soluble organoaluminum oxy-compound. In the present invention, the term "polymerization" is sometimes used in a sense that it includes not only homopolymerization but also copolymerization, and also the term "polymer" is sometimes used in a sense that it includes not only homopolymer but also copolymer. First, the titanium catalyst component as mentioned in [A] above is illustrated. This titanium catalyst component [A] contains titanium, magnesium and halogen as its essential ingredients, and it further contains, if necessary, an electron donor. The above-mentioned titanium catalyst component [A] may be prepared by bringing a magnesium compound, a titanium compound and, if necessary, an electron donor into contact with one another. Titanium compound useful for the preparation of the titanium catalyst component [A] includes tetravalent titanium compounds usually represented by the formula Ti (OR) g X 4-g (wherein R is a hydrocarbon group, X is halogen, and 0 ≦ g ≦ 4). More particularly, these titanium compounds include titanium tetrahalides such as TiCl₄, TiBr₄, and TiI₄; alkoxytitanium trihalides such as Ti(OCH₃)Cl₃, Ti(OC₂H₅)Cl₃, Ti(O n-C₄H₉)Cl₃, Ti(O iso-C₄H₉)Cl₃, Ti(OC₂H₅)Br₃, and Ti(O iso-C₄H₉)Br₃; alkoxytitanium dihalides such as Ti(OCH₃)₂Cl₂, Ti(OC₂H₅)₂Cl₂, Ti(O n-C₄H₉)₂Cl₂, and Ti(OC₂H₅)₂Br₂; trialkoxytitanium monohalides such as Ti(OCH₃)₃Cl, Ti(OC₂H₅)₃Cl, Ti(O n-C₄H₉)₃Cl and Ti(OC₂H₅)₃Br; and tetraalkoxytitanium such as Ti(OCH₃)₄, Ti(OC₂H₅)₄, Ti(O n-C₄H₉)₄, Ti(O iso-C₄H₉)₄ and Ti(O 2-ethylhexyl)₄. Of the useful titanium compounds as exemplified above, preferred are halogen containing titanium compounds, in particular, titanium tetrahalides and especially titanium tetrachloride. These titanium compounds may be used either singly or in admixture of two or more, and also they may be diluted, before use, with hydrocarbon compounds or halogenated hydrocarbon compounds. Further, trivalent titanium compounds such as TiCl₃ may be used. Magnesium compounds useful for the preparation of the titanium catalyst component [A] in the present invention include those having reducing ability and those having no reducing ability. The magnesium compounds having reducing ability as referred to herein include, for example, those having a magnesium-carbon bond or magnesium-hydrogen bond. Concrete examples of such magnesium compounds as having reducing ability include dimethylmagnesium, diethylmagnesium, dipropylmagnesium, dibutylmagnesium, diamylmagnesium, dihexylmagnesium, didecylmagnesium, ethylmagnesium chloride, propylmagnesium chloride, butylmagnesium chloride, hexylmagnesium chloride, amylmagnesium chloride, butyl ethoxy magnesium, ethyl butyl magnesium, octyl butyl magnesium, butylmagnesium halide, etc. The magnesium compounds exemplified above may be used singly, or may form complex compounds with organoaluminum compounds as will be mentioned later, and they also may be either liquid or solid. Concrete examples of magnesium compounds having no reducing ability include halogenated magnesium such as magnesium chloride, magnesium bromide, magnesium iodide or magnesium fluoride; alkoxy magnesium halide such as methoxy magnesium chloride, ethoxy magnesium chloride, isopropoxy magnesium chloride, butoxy magnesium chloride or octoxy magnesium chloride; aryloxy magnesium halide such as phenoxy magnesium chloride or methylphenoxy magnesium halide; alkoxy magnesium such as ethoxy magnesium, isopropoxy magnesium, butoxy magnesium, n-octoxy magnesium or 2-ethylhexoxy magnesium; aryloxy magnesium such as phenoxy magnesium or dimethylphenoxy magnesium; and magnesium carboxylate such as magnesium laurate or magnesium stearate. The magnesium compounds having no reducing ability exemplified above may be compounds derived from the above-mentioned magnesium compounds having reducing ability or compound derived at the time of preparation of catalyst component. The magnesium compound having no reducing ability may be derived from the magnesium compounds having reducing ability, for example, by bringing said magnesium compounds having reducing ability into contact with polysiloxane compounds, halogen containing silane compounds, halogen containing aluminum compounds or compounds such as esters, alcohols, etc. The magnesium compounds used in the present invention may also be complex or composite compounds of the above-mentioned magnesium compounds with other metals, or mixtures thereof. Further, the magnesium compounds used herein may also be mixtures of two or more of these compounds mentioned above. Of these magnesium compounds exemplified above, preferred are those having no reducing ability, particularly halogen containing magnesium compounds. Of the halogen containing magnesium compounds, preferred are magnesium chloride, alkoxy magnesium halide and aryloxy magnesium halide. In preparing the titanium catalyst component [A], it is preferable to use an electron donor. Useful electron donors include alcohols, amines, amides, ethers, ketones, esters, nitriles, phosphines, stibines, arsines, phosphoramides, thioethers, thioesters, acid anhydrides, acid halides aldehydes, alcoholates, alkoxy(aryloxy)silanes and organic acids. Of these electron donors exemplified above, preferred are alcohols, amines, ethers, esters, acid anhydrides, alkoxy(aryloxy)silanes and organic acids. The titanium catalyst component [A] may be prepared by bringing the above-mentioned magnesium compound (or metallic magnesium), titanium compound and, if necessary, electron donor into contact with one another. In preparing the titanium catalyst components, there may be employed the known method for the preparation of highly active titanium catalyst components from magnesium compounds, titanium compounds and, if necessary, electron donors. The above-mentioned components may be brought into contact with one another in the presence of other reaction reagents, for example, silicon, phosphorus and aluminum. Briefly illustrated below are several examples of the process for the preparation of these titanium catalyst components. In the following processes for the preparation of the titanium catalyst component [A] as will be illustrated below, the electron donor is used, but the use of the electron donor is not always necessary. (1) A process wherein a magnesium compound or a complex compound comprising the magnesium compound and electron donor is allowed to react with the titanium compound in the liquid phase. In carrying out this reaction, each reactant may be pretreated with a reaction assistant such as the electron donor and/or an organoaluminum compound or a halogen containing silicon compound. In this process, the above-mentioned electron donor is used at least one time. (2) A process wherein a liquid magnesium compound having no reducing ability is allowed to react with a liquid titanium compound in the presence of an electron donor, thereby separating out a solid magnesium titanium composite. (3) A process wherein the reaction product obtained in the process (2) is allowed to react further with a titanium compound. (4) A process wherein the reaction product obtained in the process (1) or (2) is allowed to react further with an electron donor and a titanium compound. (5) A process wherein a solid product obtained by pulverizing a magnesium compound or a complex compound comprising a magnesium compound and an electron donor in the presence of a titanium compound is treated with any of halogen, a halogen compound and an aromatic hydrocarbon. In carrying out this process, the magnesium compound or the complex compound comprising the magnesium compound and the electron donor may be pulverized in the presence of a pulverized assistant. Further, after pulverizing the magnesium compound or the complex compound comprising the magnesium compound and the electron donor in the presence of the titanium compound, the solid product obtained thereby is pretreated with a reaction assistant, followed by treatment with halogen or the like. The reaction assistant used herein includes an organoaluminum compound or a halogen containing silicon compound. In this process, the electron donor is used at least one time. (6) A process wherein the compound obtained in the processes (1)-(4) is treated with halogen, a halogen compound or an aromatic hydrocarbon. (7) A process wherein a contact reaction product of a metallic oxide with dihydrocarbyl magnesium and a halogen containing alcohol is brought into contact with an electron donor and a titanium compound. (8) A process wherein a magnesium compound such as magnesium salt of an organic acid, alkoxy magnesium or aryloxy magnesium is allowed to react with an electron donor, a titanium compound and/or a halogen containing hydrocarbon. (9) A process wherein a catalyst component contained in a hydrocarbon solution at least comprising a magnesium compound, alkoxy titanium and/or an electron donor such as alcohol or ether are allowed to react with a titanium compound and/or a halogen containing compound such as a halogen containing silicon compound. (10) A process wherein a liquid magnesium compound having no reducing ability is allowed to react with an organoaluminum compound to separate a solid magnesium aluminum composite, followed by reaction with a titanium compound. Of the above-mentioned processes (1) to (10) for the preparation of the titanium catalyst component [A], preferred are the processes (1) to (4) and (10). Further, a mixed solution of a liquid magnesium compound having no reducing ability and a titanium compound may also be used. The amount of each of the above-mentioned components used in the preparation of the titanium catalyst component [A] cannot be indiscriminately defined, because it varies according to the process employed. For example, however, there may be used, based on 1 mole of the magnesium compound, the electron donor in an amount of about 0.01-20 moles, preferably 0.05-10 moles, and the titanium compound in an amount of about 0.01-500 moles, preferably 0.05-300 moles. The titanium catalyst component thus obtained contains magnesium, titanium, halogen and, if necessary, an electron donor, as its essential ingredients. In the titanium catalyst component [A], Halogen/Ti (atomic ratio) is about 4-200, preferably about 5-100, the above-mentioned electron donor/Ti (molar ratio) is about 0.1-50, preferably about 0.2-25, and Mg/Ti (atomic ratio) is about 1-100, preferably about 2-50. In comparison with commercially available halogenated magnesium, the titanium catalyst component [A], when it is in the solid form, contains halogenated magnesium having small crystal size whose specific surface area is usually larger than about 10 m²/g, preferably about 30-1000 m²/g and especially about 50-800 m²/g. This solid state titanium catalyst component [A] does not substantially change in composition when it is washed with hexane, because the above-mentioned components used in said titanium catalyst component [A] are integrated into an integrated catalyst component. The processes for the preparation of such highly active titanium catalyst components [A] as mentioned above are disclosed, for example, in Japanese Patent L-O-P Publns. Nos. 108385/1975, 126590/1975, 20297/1976, 28189/1976, 64586/1976, 2885/1976, 136625/1976, 87489/1977, 100596/1977, 147688/1977, 104593/1977, 2580/1978, 40093/1978, 40094/1978, 43094/1978, 135102/1980, 135103/1980, 152710/1980, 811/1981, 11908/1981, 18606/1981, 83006/1983, 138705/1983, 138706/1983, 138707/1983, 138708/1983, 138709/1983, 138710/1983, 138715/1983, 23404/1985, 195108/1985, 21109/1986, 37802/1986 and 37803/1986. Usually, the titanium catalyst components [A] obtained in the manner now described are desirably those exhibiting an ethylene polymerization activity of 200 g-polymer/mmol-Ti x h x atm, preferably higher than 500 g-polymer/mmol-Ti x h x atm, when used in combination with an organoaluminum. The transition metal compound [B-1] containing a ligand having a cycloalkadienyl skeleton used in the present invention is represented by the formula ML x wherein M is a transition metal, L is a ligand coordinating to the transition metal, at least one of L is a ligand having a cycloalkadienyl skeleton, and when at least two or more ligands having a cycloalkadienyl skeleton are contained, at least two ligands having a cycloalkadienyl skeleton may be linked together via lower alkylene, substituted alkylene, silylene or substituted silylene, L other than the ligand having a cycloalkadienyl skeleton is hydrocarbon group of 1-12 carbon atoms, alkoxy of 1-12 carbon atoms, aryloxy, halogen or hydrogen, and x is a valence of the transition metal. In the above-mentioned formula, M which is a transition metal includes zirconium, titanium, hafnium, chromium or vanadium by preference, and particularly preferred are zirconium and hafnium. The ligands having a cycloalkadienyl skeleton include, for example, cyclopentadienyl, alkyl-substituted cyclopentadienyl such as methylcyclopentadienyl, ethylcyclopentadienyl, n-butylcyclopentadienyl, dimethylcyclopentadienyl and pentamethylcyclopentadienyl, and indenyl and fluorenyl. Two or more ligands having a cycloalkadienyl skeleton as mentioned above may coordinate to the transition metal and, in this case, at least two ligands having a cycloalkadienyl skeleton may be linked together via alkylene, substituted alkylene, silylene or substituted silylene. The alkylene group includes methylene, ethylene and propylene, the substituted alkylene includes isopropylidene, etc., and the substituted silylene includes dimethylsilylene and diphenylsilylene. The ligand other than those having a cycloalkadienyl skeleton is a hydrocarbon group of 1-12 carbon atoms, an alkoxy group, an aryloxy group, halogen or hydrogen. The hydrocarbon group having 1-12 carbon atoms mentioned above includes, for example, alkyl, cycloalkyl, aryl and aralkyl, and the alkyl group includes methyl, ethyl, propyl, isopropyl and butyl. The cycloalkyl group mentioned above includes, for example, cyclopentyl and cyclohexyl, the aryl group includes, for example, phenyl and tolyl, and the aralkyl group includes, for example, benzyl and neophyl. The alkoxy group mentioned above includes, for example, methoxy, ethoxy and butoxy, and the aryloxy group includes, for example, phenoxy. The halogen mentioned above includes, for example, fluorine, chlorine, bromine and iodine. Listed below are typical representatives of the transition metal compounds having a cycloalkadienyl skeleton, represented by the aforementioned formula ML x in which M is zirconium. Bis(cyclopentadienyl)zirconium monochloride monohydride, Bis(cyclopentadienyl)zirconium monobromide monohydride, Bis(cyclopentadienyl)methyl zirconium hydride, Bis(cyclopentadienyl)ethyl zirconium hydride, Bis(cyclopentadienyl)phenyl zirconium hydride, Bis(cyclopentadienyl)benzyl zirconium hydride, Bis(cyclopentadienyl)neopentyl zirconium hydride, Bis(methylcyclopentadienyl)zirconium monochloride hydride, Bis(indenyl)zirconium monochloride monohydride, Bis(cyclopentadienyl)zirconium dichloride, Bis(cyclopentadienyl)zirconium dibromide, Bis(cyclopentadienyl)methyl zirconium monochloride, Bis(cyclopentadienyl)ethyl zirconium monochloride, Bis(cyclopentadienyl)cyclohexyl zirconium monochloride, Bis(cyclopentadienyl)phenyl zirconium monochloride, Bis(cyclopentadienyl)benzyl zirconium monochloride, Bis(methylcyclopentadienyl)zirconium dichloride, Bis(n-butylcyclopentadienyl)zirconium dichloride, Bis(indenyl)zirconium dichloride, Bis(indenyl)zirconium dibromide, Bis(cyclopentadienyl)zirconium dimethyl, Bis(cyclopentadienyl)zirconium diphenyl, Bis(cyclopentadienyl)zirconium dibenzyl, Bis(cyclopentadienyl)zirconium methoxychloride, Bis(cyclopentadienyl)zirconium ethoxychloride, Bis(methylcyclopentadienyl)zirconium ethoxychloride, Bis(cyclopentadienyl)zirconium phenoxychloride, Bis(fluorenyl)zirconium dichloride, Ethylenebis(indenyl)dimethyl zirconium, Ethylenebis(indenyl)diethyl zirconium, Ethylenebis(indenyl)diphenyl zirconium, Ethylenebis(indenyl)methyl zirconium monochloride, Ethylenebis(indenyl)ethyl zirconium monochloride, Ethylenebis(indenyl)methyl zirconium monobromide, Ethylenebis(indenyl)zirconium dichloride, Ethylenebis(indenyl)zirconium dibromide, Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)dimethyl zirconium, Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)methyl zirconium monochloride, Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride, Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dibromide, Ethylenebis(4-methyl-1-indenyl)zirconium dichloride, Ethylenebis(5-methyl-1-indenyl)zirconium dichloride, Ethylenebis(6-methyl-1-indenyl)zirconium dichloride, Ethylenebis(7-methyl-1-indenyl)zirconium dichloride, Ethylenebis(5-methoxy-1-indenyl)zirconium dichloride, Ethylenebis(2,3-dimethyl-1-indenyl)zirconium dichloride, Ethylenebis(4,7-dimethyl-1-indenyl)zirconium dichloride, Ethylenebis(4,7-dimethoxy-1-indenyl)zirconium dichloride, Dimethylsilylenenbis(cyclopentadienyl)zirconium dichloride, Dimethylsilylenebis(indenyl)zirconium dichloride, Dimethylsilylenebis(methylcyclopentadienyl)zirconium dichloride, Isopropylidenebis(indenyl)zirconium dichloride, Isopropylidene(cyclopentadienyl-fluorenyl)zirconium dichloride. There may also be used transition metal compounds obtained by replacing the zirconium metal in the above-exemplified zirconium compounds with titanium metal, hafnium metal, or vanadium metal. The transition metal compounds [B-1] as exemplified above may be supported by an inorganic carrier such as silica or alumina, a polymer such as polyethylene or polystyrene, or a solidified organoaluminum oxy-compound, and also may be pre-polymerized with olefin. When the transition metal compound is supported by the solidified organoaluminum oxy-compound, the organoaluminum oxy-compound may be used or not at the time of polymerization of olefins. The processes for the preparation of such solid transition metal compounds are disclosed, for example, in Japanese Patent L-O-P Publns. Nos. 51405/1988, 51407/1988, 54403/1988, 61010/1988, 22804/1988, 89505/1988, 213504/1988, 260903/1988 and 280703/1988. In particular, when olefins are polymerized by gas phase polymerization or suspension polymerization, it is desirable to use the above-mentioned solid transition metal compounds as the [B-1] component. The organoaluminum oxy-compound [C] used in the present invention may be known aluminoxane or a benzene-insoluble organoaluminum oxy-compound first discovered by the present inventors. The above-mentioned aluminoxane may be prepared, for example, by the following procedures. (1) The procedure for recovering aluminoxanes as their solution in hydrocarbons which comprises reacting organoaluminum compounds such as trialkylaluminum with suspensions in hydrocarbon solvents of compounds having absorbed water or salts containing water of crystallization, for example, hydrates of magnesium chloride, copper sulfate, aluminum sulfate, nickel sulfate or cerous chloride. (2) The procedure for recovering aluminoxanes as their solution in hydrocarbons which comprises allowing organoaluminum compounds such as trialkylaluminum to interact directly with water, ice or water vapor in solvents such as benzene, toluene, ethyl ether and tetrahydrofuran. In this connection, the above-mentioned solution of aluminoxane may contain small amount of organometallic components. Furthermore, the solution of aluminoxane recovered by the above-mentioned procedures may be distilled to remove therefrom the solvent or unreacted organoaluminum compound, followed by dissolving again in solvents. The organoaluminum compounds used for preparing such solutions of aluminoxane as mentioned above include, for example, trialkylaluminum such as trimethylaluminum, triethylaluminum, tripropylaluminum, triisopropylaluminum, tri-n-butylaluminum, triisobutylaluminum, tri-sec-butylaluminum, tri-tert-butylaluminum, tripentylaluminum, trihexylaluminum, trioctylaluminum, tridecylaluminum, tricyclohexylaluminum, tricyclooctylaluminum; dialkylaluminum halides such as dimethylaluminum chloride, diethylaluminum chloride, diethylaluminum bromide and diisobutylaluminum chloride; dialkylaluminum hydrides such as diethylaluminum hydride and diisobutylaluminum hydride; dialkylaluminum alkoxides such as dimethylaluminum methoxide and diethylaluminum ethoxide; and dialkylaluminum aryloxides such as diethylaluminum phenoxide. Of the organoaluminum compounds as exemplified above, particularly preferred is trialkylaluminum. Furthermore, there may also be used as the organoaluminum compound isoprenylaluminum represented by the general formula (i-C₄H₉) x Al y (C₅H₁₀) z wherein x, y and z are each a positive number, and z ≧ 2x. The organoaluminum compounds mentioned above may be used either singly or in combination. Solvents used in the solutions of aluminoxane include aromatic hydrocarbons such as benzene, toluene, xylene, cumene and cymeme; aliphatic hydrocarbons such as pentane, hexane, heptane, octane, decane, dodecane, hexadecane and octadecane; alicyclic hydrocarbons such as cyclopentane, cyclohexane, cyclooctane and methylcyclopentane; petroleum fractions such as gasoline, kerosene and gas oil; or halides, particularly chloride and bromides, of the above-mentioned aromatic, aliphatic and alicyclic hydrocarbons. In addition thereto, there may also be used ethers such as ethyl ether and tetrahydrofuran. Of these solvents as exemplified above, particularly preferred are aromatic hydrocarbons. The benzene-insoluble organoaluminum oxy-compounds of the present invention contain Al component which dissolves in benzene at 60°C in an amount of less than 10%, preferably less than 5% and further desirably less than 2% in terms of Al atom, and they are insoluble or sparingly soluble in benzene. Solubility in benzene of such organoaluminum oxy-compounds as mentioned above is obtained by suspending in 100 ml of benzene said organoaluminum oxy-compound in an amount corresponding to 100 mg atoms in terms of Al atom, mixing the resulting suspension at 60°C for 6 hours, filtering the resulting mixture with G-5 glass filter equipped with a jacket kept at 60 °C, and washing four times the solids portion separated on the filter with 50 ml of benzene at 60°C to measure the amount (x mmol) of Al atoms present in the whole filtrate. When the benzene-insoluble organoaluminum oxy-compounds of the present invention are analyzed by infrared spectrophotometry (IR), a ratio (D₁₂₆₀/D₁₂₂₀) of an absorbance (D₁₂₆₀) at around 1260 cm⁻¹ to an absorbance (D₁₂₂₀) at around 1220 cm⁻¹ is less than 0.09, preferably less than 0.08 and particularly in the range of from 0.04 to 0.07. Infrared spectrophotometric analysis of the organoaluminum oxy-compounds as referred to in the present specification is carried out in the following manner. First, the organoaluminum oxy-compound is ground, together with nujol, in an agate mortar in a nitrogen box to paste. Next, the paste-like sample thus obtained is put between KBr plates, and IR spectrum is measured in a nitrogen atmosphere by means of IR-810 manufactured and sold by Nippon Bunko K.K. IR spectrum of the organoaluminum oxy-compound of the present invention as obtained is shown in Fig. 1. From the thus obtained IR spectrum, a D₁₂₆₀/D₁₂₂₀ ratio is sought, and a value of said ratio is obtained in the following manner. (a) A line connecting a maximum point at around 1280 cm⁻¹ and a maximum point at around 1240 cm⁻¹ is taken as a base line L₁. (b) A transmittance (T %) of an absorption minimum point at around 1260 cm⁻¹ and an transmittance (T₀ %) of a point of intersection are read, said point of intersection being obtained by drawing a vertical line from said absorption minimum point to a wave number abscissa axis (abscissa) and crossing said vertical line with said base line L₁, whereby an absorbance ( D 1260 =log T 0 /T ) is calculated. (c) Similarly, a line connecting maximum points at around 1280 cm⁻¹ and at around 1180 cm⁻¹ is taken as a base line L₂. (d) A transmittance (T′ %) of an absorption minimum point at around 1220 cm⁻¹ and a transmittance (T′₀ %) of a point of intersection are read, said point of intersection being obtained by drawing a vertical line from said absorption minimum point to a wave number abscissa axis (abscissa) and crossing said vertical line with said base line L₂, whereby an absorbance ( D 1220 =log T′ 0 /T′ ) is calculated. (e) From these values as obtained, D₁₂₆₀/D₁₂₂₀ is calculated. IR spectrum of a known benzene-soluble organoaluminum oxy-compound is shown in Fig. 2. As can be seen from Fig. 2, the benzene-soluble aluminum oxy-compound has a value of D₁₂₆₀/D₁₂₂₀ of being virtually 0.10-0.13, and thus the benzene-insoluble organoaluminum oxy-compound of the present invention is apparently different in the value of D₁₂₆₀/D₁₂₂₀ from the known benzene-soluble organoaluminum oxy-compound. The benzene-insoluble organoaluminum oxy-compounds of the present invention are presumed to have an alkyloxyaluminum unit represented by the formula wherein R¹ is a hydrocarbon group of 1 to 12 carbon atoms. In the above-mentioned alkyloxyaluminum unit, R¹ includes, for example, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, pentyl, hexyl, octyl, decyl, cyclohexyl and cyclooctyl. Of these hydrocarbon groups exemplified above, preferred are methyl and ethyl, and particularly preferred is methyl. In addition to the alkyloxyaluminum unit of the formula the benzene-insoluble organoaluminum oxy-compounds of the present invention may contain an oxyaluminum unit represented by the formula wherein R¹ is as defined above, and R² is a hydrocarbon group of 1 to 12 carbon atoms, an alkoxyl group of 1 to 12 carbon atoms, an aryloxy group of 6 to 20 carbon atoms, a hydroxyl group, halogen or hydrogen, provided that R¹ and R² are different from each other. In that case, the organoaluminum oxy-compounds desirably contain the alkyloxyaluminum unit in a proportion of at least 30 mol%, preferably at least 50 mol% and particularly at least 70 mol%. The processes for preparing the benzene-insoluble organoaluminum oxy-compounds of the present invention are illustrated below in detail. The first process for preparing the benzene-insoluble organoaluminum oxy-compounds of the present invention is characterized by bringing a solution of aluminoxane into contact with water or active hydrogen containing compounds. The active hydrogen containing compounds used in the present invention include alcohols such as methanol, ethanol, n-propanol and isopropanol; diols such as ethylene glycol and hydroquinone; and organic acids such as acetic acid and propionic acid. Of these compounds, preferred are alcohols and diols, and especially preferred are alcohols. Water or the active hydrogen containing compounds with which the solution of aluminoxane is brought into contact may be used as solutions or dispersions in hydrocarbon solvents such as benzene, toluene and hexane, ether solvents such as tetrahydrofuran or amine solvents such as triethylamine, or may be used in the form of vapor or solid. The water with which the solution of aluminoxane is brought into contact may be water of crystallization of salts such as magnesium chloride, magnesium chloride, magnesium sulfate, copper sulfate, nickel sulfate, iron sulfate and cerous chloride, or absorbed water absorbed to inorganic compounds such as silica, alumina and aluminum hydroxide or polymers. Reaction of the solution of aluminoxane with water or the active hydrogen containing compounds is carried out usually in solvents, for example, hydrocarbon solvents. The solvents used in this case are aromatic hydrocarbons such as benzene, toluene, xylene, cumene and cymene; aliphatic hydrocarbons such as pentane, hexane, heptane, octane, decane, dodecane, hexadecane and octadecane; alicyclic hydrocarbons such as cyclopentane, cyclohexane, cyclooctane and methylcyclohexane; petroleum fractions such as gasoline, kerosene and gas oil; halogenated hydrocarbons such as halides of the above-mentioned aromatic hydrocarbons, aliphatic hydrocarbons and alicyclic hydrocarbons, particularly, chlorides and bromides; and ethers such as ethyl ether and tetrahydrofuran. Of these solvents as exemplified above, particularly preferred are aromatic hydrocarbons. In the reaction as mentioned above, water or the active hydrogen containing compound is used in an amount of 0.1-5 moles, preferably 0.2-3 moles to 1 mole of Al atoms present in the solution of aluminoxane. A concentration in terms of aluminum atom in the reaction system is desirably 1 x 10⁻³ - 5 gram atom/l, preferably 1 x 10⁻² - 3 gram atom/l, and a concentration of water in the reaction system is desirably 2 x 10⁻⁴ - 5 mol/l, preferably 2 x 10⁻³ - 3 mol/l. The solution of aluminoxane may be brought into contact with water or the active hydrogen containing compound, for example, by the following procedures. (1) The procedure which comprises bringing the solution of aluminoxane into contact with a hydrocarbon solvent containing water or the active hydrogen containing compound. (2) The procedure which comprises blowing vapor of water or the active hydrogen containing compound into the solution of aluminoxane, thereby bringing the aluminoxane into contact with the vapor. (3) The procedure which comprises bringing the solution of aluminoxane into contact directly with water, ice or the active hydrogen containing compound. (4) The procedure which comprises mixing the solution of aluminoxane with a suspension of an absorbed water containing compound or a water of crystallization containing compound in hydrocarbon, or with a suspension of a compound, to which the active hydrogen containing compound has been absorbed, in hydrocarbon, thereby bringing the aluminoxane into contact with the absorbed water or water of crystallization. The solution of aluminoxane may contain other components so long as they do not exert adverse effects on the reaction of aluminoxane with water or the active hydrogen containing compound. The above-mentioned reaction of the solution of aluminoxane with water or the active hydrogen containing compound is carried out usually at -50 to 150°C, preferably 0-120°C and more desirably at 20-100°C. The reaction time employed is usually 0.5-300 hours, preferably 1-150 hours, though said reaction time varies largely depending upon the reaction temperature used. The benzene insoluble organoaluminum oxy-compound may also be prepared by direct contact of organoaluminum with water. In the reaction mentioned above, water is used in such amount that the organoaluminum atom dissolved in the reaction system is less than 20 %, based on total organoaluminum atom. Water with which the organoaluminum compound is brought into contact may be used as solutions or dispersions in hydrocarbon solvents such as benzene, toluene and hexane, ether solvents such as tetrahydrofuran or amine solvents such as triethylamine, or may be used in the form of vapor or solid. The water with which the organoaluminum compound is brought into contact may be water of crystallization of salts such as magnesium chloride, magnesium chloride, magnesium sulfate, copper sulfate, nickel sulfate, iron sulfate and cerous chloride, or absorbed water absorbed to inorganic compounds such as silica, alumina and aluminum hydroxide or polymers. Reaction of the organoaluminum compound with water is carried out usually in solvents, for example, hydrocarbon solvents. The solvents used in this case are aromatic hydrocarbons such as benzene, toluene, xylene, cumene and cymene; aliphatic hydrocarbons such as pentane, hexane, heptane, octane, decane, dodecane, hexadecane and octadecane; alicyclic hydrocarbons such as cyclopentane, cyclohexane, cyclooctane and methylcyclohexane; petroleum fractions such as gasoline, kerosene and gas oil; halogenated hydrocarbons such as halides of the above-mentioned aromatic hydrocarbons, aliphatic hydrocarbons and alicyclic hysrocarbons, particularly, chlorides and bromides; and ethers such as ethyl ether and tetrahydrofuran. Of these solvents as exemplified above, particularly preferred are aromatic hydrocarbons. A concentration of organoaluminum compound in the reaction system in terms of aluminum atom is desirably 1 X 10⁻³ - 5 gram atom/l, preferably 1 X 10⁻² - 3 gram atom/l, and a concentration of water in the reaction system is desirably 1 X 10⁻³ - 5 mol/l, preferably 1 X 10⁻² - 3 mol/l. In the reaction mentioned above, the organoaluminum atom dissloved in the reaction system is less than 20 %, preferably less than 10 %, more preferably 0 to 5 % based on total organoaluminum atom. The organoaluminum compound may be brought into contact with water, for example, by the following procedures. (1) The procedure which comprises bringing the hydrocarbon solution of organoaluminum into contact with a hydrocarbon solvent containing water. (2) The procedure which comprises blowing vapor of water into the hydrocarbon solution of organoaluminum, thereby bringing the organoaluminum into contact with the vapor. (3) The procedure which comprises mixing the hydrocarbon solution of organoaluminum with a suspension of an absorbed water containing compound or a water of crystallization containing compound in hydrocarbon, thereby bringing the organoaluminum into contact with the absorbed water or water of crystallization. (4) The procedure which comprises bringing the hydrocarbon solution of organoaluminum into contact directly with ice. The hydrocarbon solution of organoaluminum may contain other components so long as they do not exert adverse effects on the reaction of organoaluminum with water. The above-mentioned reaction of the organoaluminum with water is carried out usually at -100 to 150 °C, preferably -70 to 100°C and more desirably at -50 to 80°C. The reaction time empolyed is usually 1 to 200 hours, preferably 2 to 100 hours, though said reaction time varies largely depending upon the reaction temperature used. The organoaluminum compounds [D] used in the present invention may be represented, for example, by the formula R⁶ n AlX 3-n wherein R⁶ is hydrocarbon of 1-12 carbon atoms, X is halogen and n is 1-3. In the above-mentioned formula, R⁶ is hydrocarbon of 1-12 carbon atoms, for example, alkyl, cycloalkyl or aryl, including concretely methyl, ethyl, n-propyl, isopropyl, isobutyl, pentyl, hexyl, octyl, decyl, cyclopentyl, cyclohexyl, phenyl, tolyl, etc. The above-mentioned organoaluminum compounds will be exemplified below. Trialkylaluminum such as trimethylaluminum, triethylaluminum, triisopropylaluminum, triisobutylaluminum, trihexylaluminum, trioctylaluminum, tri-2-ethylhexylaluminum, etc. Alkenylaluminum such as isoprenylaluminum, etc. Dialkylaluminum halides such as dimethylaluminum chloride, diethylaluminum chloride, diisopropylaluminum chloride, diisobutylaluminum chloride, dimethylaluminum bromide, etc. Alkylaluminum sesquihalides such as methylaluminum sesquichloride, ethylaluminum sesquichloride, butylaluminum sesquichloride, ethylaluminum sesquibromide, etc. Alkylaluminum dihalides such as methylaluminum dichloride, ethylaluminum dichloride, isopropylaluminum dichloride, ethylaluminum dibromide, etc. Alkylaluminum hydrides such as diethylaluminum hydride, isobutylaluminum hydride, etc. Furthermore, there may also be used other organoaluminum compounds represented by the formula R⁶ n AlY 3-n wherein R⁶ is as defined previously, Y is -OR⁷, -OSiR⁸₃, -OAlR⁹₂, -NR¹⁰₂, -SiR¹¹₃ or n is 1-2, R⁷, R⁸, R⁹ and R¹³ are each methyl, ethyl, isopropyl, isobutyl, cyclohexyl or phenyl, R¹⁰ is hydrogen, methyl, ethyl, isopropyl, phenyl or trimethylsilyl, R¹¹ and R¹² are each methyl or ethyl. The organoaluminum compounds as mentioned above include, in concrete, such compounds as enumerated below. (i) Compounds of the formula R⁶ n Al(OR⁷) 3-n such as dimethylaluminum methoxide, diethylaluminum ethoxide, diisobutylaluminum methoxide, etc. (ii) Compounds of the formula R⁶ n Al(OSiR⁸₃) 3-n such as Et₂Al(OSiMe₃), (iso-Bu)₂Al(OSiMe₃), (iso-Bu)₂Al(OSiEt₃), etc. (iii)Compounds of the formula R⁶ n Al(OAlR⁹₂) 3-n such as Et₂AlOAlEt₂, (iso-Bu)₂AlOAl(iso-Bu)₂, etc. (iv) Compounds of the formula R⁶ n Al(NR¹⁰₂) 3-n such as Me₂AlNEt₂, Et₂AlNHMe, Me₂AlNHEt, Et₂AlN(Me₃Si)₂, (iso-Bu)₂AlN(Me₃Si)₂, etc. (v) Compounds of the formula R⁶ n Al(SiR¹¹₃) 3-n such as (iso-Bu)₂AlSiMe₃, etc. (vi) Compounds of the formula such as etc. Of the organoaluminum compounds as exemplified above, preferred are those of the formula R⁶₃Al, R⁶ n Al(OR⁷) 3-n and R⁶Al(OAlR⁹₂) 3-n , particularly those in which R⁶ is isoalkyl and n=2 are desirable. These organoaluminum compounds may be used in combination of two or more. In the practice of polymerization of olefins with the above-mentioned olefin polymerization catalyst as mentioned above, it is desirable to use the titanium catalyst component [A] in an amount of usually 10⁻⁸ - 10⁻³ gram atom-Ti/l, preferably 10⁻⁷ - 10⁻⁴ gram atom-Ti/l, the transition metal compound [B-1] containing a ligand having a cycloalkadienyl skeleton in an amount of usually 10⁻⁸ - 10⁻³ mol/l, preferably 10⁻⁷ - 10⁻⁴ mol/l, and the transition metal compound [B-1] containing a ligand having a cycloalkadienyl skeleton in an amount, based on 1 gram Ti atom of titanium catalyst component [A] of usually 0.02-10 moles, preferably 0.05-5 moles. The organoaluminum oxy-compound [C] is desirably used in an amount of usually 10⁻⁶ - 10⁻² gram atom-Al/l, preferably 10⁻⁵ - 3x10⁻³ gram atom-Al/l. The organoaluminum compound [D] is desirably used in an amount of usually 5 X 10⁻⁵ - 5x10⁻² mol/l, preferably 10⁻⁴ - 10⁻² mol/l. Further, a ratio (atomic ratio) of aluminum/total transition metal is desirably 10-5000, preferably 20-2000, and a ratio (in terms of Al) of the organoaluminum oxy-compound [C] to the organoaluminum compound [D] is desirably in the range of from 0.1 to 20, preferably from 0.2 to 10. The pre-polymerization may be carried out by polymerizing α-olefin in a polymerization amount, based on 1 g of the olefin polymerization catalyst, of 0.1-500 g, preferably 0.3-300 g and especially 1-100 g. Usually, the pre-polymerization is carried out in the manner described below. In carrying out the pre-polymerization, the solid titanium catalyst component [A], the transition metal compound [B-1] containing a ligand having a cycloalkadienyl skeleton, the organoaluminum oxy-compound [C] and, if necessary, the organoaluminum compound [D] are mixed together so as to bring them into contact with one another, followed by introducing the olefin thereinto. In this case, the components [A], [B], [C] and [D] may be mixed together at once or may be mixed one after another. The temperature at which the above-mentioned components are mixed and brought into contact with one another is in the range of usually from -50 to 100°C, preferably from -20 to 50°C, and the mixing-contacting time is in the range of usually from 0.2 to 50 hours, preferably from 0.5 to 20 hours, though it varies according to the reaction temperature or the order of mixing. The pre-polymerization temperature employed is in the range of usually from -20 to 60°C, preferably from 0 to 50°C, and the pre-polymerization time is in the range of usually from 0.5 to 100 hours, preferably from 1 to 50 hours, though it varied according to the pre-polymerization amount or temperature. In carrying out the pre-polymerization, it is possible to use the catalyst in a concentration considerably higher than that used in the system of the main polymerization. In the pre-polymerization, it is desirable to use the solid titanium catalyst component [A] in a concentration, based on 1 L of an inert hydrocarbon medium as will be mentioned later, of usually about 0.01-200 mg atom-Ti, preferably about 0.1-100 mg atom-Ti and especially 1-50 mg atom-Ti. Further, in carrying out the pre-polymerization, the transition metal compound [B-1] containing a ligand having a cycloalkadienyl skeleton is desirably used in an amount, based on 1 gram atom of titanium in the titanium catalyst component, of 0.02-10 moles, preferably 0.05-5 moles. Similarly, the organoaluminum oxy-compound [C] is desirably used in an amount, based on 1 mole of the transition metal atom in the transition metal compound [B-1], of 10-500 gram atom-Al, preferably 20-200 gram atom-Al. Furthermore, the organoaluminum compound [D], when used if any, is desirably in an amount, based on 1 mole of the transition metal atom in the component [B-1], of 1-200 moles, preferably 2-100 moles. The pre-polymerization is desirably carried out by using a mixture of olefin, the above-mentioned catalyst components and an inert hydrocarbon medium in a suspension state under mild conditions. The inert hydrocarbon medium used herein includes aliphatic hydrocarbons such as propane, butane, pentane, hexane, heptane, octane, decane dodecane and kerosine; alyciclic hydrocarbons such as cyclopentane, cyclohexane and methylcyclopentane; aromatic hydrocarbons such as benzene, toluene and xylene; halogenated hydrocarbons such as ethylene chloride and chlorobenzene; or mixtures thereof. Further, the pre-polymerization may be carried out by using the olefin itself as a solvent, or may be carried out in a state substantially free from the solvent. The olefin used in the pre-polymerization may be the same as used in the main polymerization as will be mentioned later or different therefrom. Of the olefins mentioned above, preferred is ethylene, in particular. In the pre-polymerization, a molecular weight modifier such as hydrogen may also be used. The molecular weight modifier mentioned above is desirably used in such an amount that an intrinsic viscosity [η], as measured in decalin at 135°C, of the resulting polymer from the pre-polymerization becomes higher than about 0.2 dl/g, preferably about 0.5-10 dl/g. The pre-polymerization is desirably carried out so that the amount, based on 1 g of the above-mentioned solid catalyst, of the polymer formed is about 0.1-500 g, preferably about 0.3-300 g and especially 1-100 g. If the pre-polymerization amount of the olefin is preset to become excessively large, the production efficiency of the desired olefin polymers sometimes decreases. In the pre-polymerized solid catalyst thus obtained, the amount of titanium atom derived from the component [A], based on 1 gram atom of the transition metal atom derived from the component [B-1], is desirably in the range of 0.05-20 gram atom, preferably 0.1-10 gram atom and especially 0.2-5 gram atom, and similarly the total sum of aluminum atoms derived from the components [C] and [D] is 15-500 gram atom, preferably 20-200 gram atom. The olefin polymerization solid catalysts as prepared in the manner mentioned above exhibit by themselves excellent polymerization activities in the polymerization of olefins. The second olefin polymerization catalyst of the present invention comprises (I) the solid catalyst described above, and (II) an organoaluminum oxy-compound [C] and/or an organoaluminum compound [D]. When polymerizing an olefin with the second catalyst, it is desirable to use the solid titanium catalyst component [A] in an amount of 10⁻⁸ - 10⁻³ gram atom-Ti/l, preferably 10⁻⁷ - 10⁻⁴ gram atom-Ti/l; the transition metal atom of transition metal compound [B-1] in an amount of 10⁻⁸ - 10⁻³ gram atom, preferably 10⁻⁷ - 10⁻⁴ gram atom; and the aluminum atoms derived from the organoaluminum oxy-compound [C] and the organoaluminum compound [D] in an amount of 10⁻⁶ - 10⁻² gram atom, preferably 10⁻⁵ - 3x10⁻³ gram atom. Similarly, it is desirable to use the organoaluminum oxy-compound [C] and/or the organoaluminum compound [D] in an amount of usually 10⁻⁷ - 5x10⁻³ gram atom-Al/l, preferably 10⁻⁶ - 2x10⁻³ gram atom-Al/l. Olefins which can be polymerized with the above-mentioned olefin polymerization catalysts include ethylene and α-olefins having 3 to 20 carbon atoms, for example, propylene, 1-butene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-hexadecene, 1-octadecene, 1-eicosene, cyclopentene, cycloheptene, norbornene, 5-methyl-2-norbornene, tetracyclododecene and 2-methyl-1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a- octahydronaphthalene. In addition to those exemplified above, there may also be used styrene, vinyl cyclohexane and diene, etc. In the present invention, such olefins as exemplified above may be polymerized or copolymerized either by liquid phase polymerization such as solution or suspension polymerization or vapor phase polymerization. The polymerization temperature employed in polymerizing the olefins with the above-mentioned olefin polymerization catalysts is in the range of usually from -50° to 200°C, preferably from 0° to 150°C. The polymerization pressure employed is usually from atmospheric pressure to 100 kg/cm², preferably from atmospheric pressure to 50 kg/cm², and the polymerization reaction may be carried out by any of the batchwise, semi-continuous and continuous methods. Further, the polymerization may be carried out at two or more stages under different reaction conditions. The molecular weight of the olefin polymer resulting the polymerization may be modified by allowing hydrogen to exist in the polymerization system or by changing the polymerization temperature employed. The olefin polymerization catalysts of the present invention formed from the components as mentioned hereinbefore have excellent polymerization activities and are capable of giving olefin polymers having a broad molecular weight distribution and excellent moldability. In the present invention, the olefin polymerization catalysts may also contain other components useful for olefin polymerization in addition to such components as mentioned hereinbefore. The olefin polymerization catalysts of the present invention exhibit excellent polymerisation activities when used in the polymerization of olefins and also are capable of giving olefin (co)polymers having a broad molecular weight distribution and excellent moldability. The present invention is illustrated below with reference to examples, but it should be construed that the invention is in no way limited to those examples. The molecular weight distribution ( M w/ M n) and composition distribution (amount of n-decane soluble portion) referred to in the examples of the invention were obtained by the following manner. The value of M w/ M n is determined by the following procedure in accordance with Takeuchi, "Gel Permeation Chromatography", Maruzen, Tokyo. (1) Using a standard polystyrene having a known molecular weight (mono-dispersed polystyrene produced by Toyo Soda Mfg. Co., Ltd.), a molecular weight M and its GPC (Gel Permeation Chromatograph) count are determined to prepare a correlation diagram calibration curve of the molecular weight and EV (evolution volume). At this time, the concentration is preset to 0.02% by weight. (2) GPC chromatograph of a sample is prepared by GPC measurement, and a number average molecular weight M n and a weight average molecular weight M w in terms of polystyrene are calculated on the basis of the above-mentioned (1) to obtain a value of M w/ M n. In that case, the conditions under which the sample is prepared and the GPC measurement is conducted are as in the following. [Preparation of sample] (a) The sample together with o-dichlorobenzene solvent are dispensed by Erlenmeyer flask so that the sample content becomes 0.1% by weight. (b) The flask is heated to 140°C and stirred for about 30 minutes to dissolve the sample in the solvent. (c) The solution is filtered, and the filtrate is subjected to GPC. [GPC measurement conditions] The measurement was carried out under the following conditions. (a) Equipment: 150C-ALC/GPC mfd. by Waters Co. (b) Column: GMH Type mfd. by Toyo Soda Mfg. Co., Ltd. (c) Amount of sample: 400 µ liters (d) Temperature: 140°C (e) Flow rate: 1 ml/min The measurement of the amount of n-decane-soluble portion (the smaller amount of soluble portion means the narrower composition distribution) was conducted by adding about 3 g of a copolymer of 450 ml of n-decane, dissolving the copolymer in n-decane at 145°C, followed by cooling to 23°C. Thereafter, the n-decane-insoluble portion was removed by filtration, and the n-decane-soluble portion was recovered from the filtrate, thereby measuring the amount of the n-decane-soluble portion. Further, MFR of the copolymer was measured at 190°C under a load of 2.16 kg. Example 1 (Preparation of solid titanium catalyst component [A]) A miture of 4.8 g of commercially available anhydrous magnesium chloride, 23.1 ml of 2-ethylhexyl alcohol and 27 ml of decane was allowed to undergo reaction by heating for 3 hours at 140 °C, whereby a homogeneous solution containing magnesium chloride was obtained. To this solution, 200 ml of decane was added and further, with stirring at 20 °C, 52 ml of a solution of triethylaluminum in decane (Al = 1.0 mol/l) was added dropwise over a period of 30 minutes, followed by reaction for 1 hour. Successively, the temperature of the reaction mixture was elevated to 80 °C over a period of 1 hour, and the reaction was continued further at that temperature for 1 hour. After completion of the reaction, 60 ml of a solution of diethylaluminum chloride in decane (Al = 1 mol/l) was added dropwise at 80 °C over a period of 30 minutes, followed by reaction for 1 hour. After completion of the reaction, a solids portion was separated by filtration. The solids portion thus obtained was suspended in 200 ml of decane, and thereto, 3.75 ml of a solution of 2-ethylhexoxytitanium trichloride in decane (Ti = 1 mol/l) was added, followed by reaction at 80 °C for 1 hour. Filtration and washing of the reaction product gave a solid titanium catalyst component containing 1.3 % by weight of titanium, 11 % by weight of magnesium, 33 % by weight of chloride, 2.4 % by weight of aluminum and 45 % by weight of a 2-ethylhexoxy group. (Preparation of organoaluminum oxy-compound [C]) A 400 ml flask thoroughly purged with nitrogen was charged with 37.1 g of Al₂(SO₄)₃ 14H₂O and 133 ml of toluene, cooled to -5°C, and 47.9 ml of trimethylaluminum diluted with 152 ml of toluene was added dropwise over a period of 1 hour. After a 1-hour reaction at a temperature of from 0° to -5°C, the temperature was elevated up to 40 °C over a period of 3 hours, and the reaction was further continued at that temperature for 72 hours. After completion of the reaction, the reaction mixture was subjected to solid-liquid separation by filtration, and the toluene was removed from the filtrate, whereby a white solid organoaluminum oxy-compound was obtained. (Pre-polymerization) A 400 ml glass flask thoroughly purged with nitrogen was charged with 20 ml of hexane, 5 ml of a slurry of the solid titanium catalyst [A] in hexane (Ti = 0.0338 mol/l), 7.5 ml of a solution of triisobutylaluminum in toluene (Al = 1.0 mol/l) and 27.8 ml of a solution of the organoaluminum oxy-compound [C] in toluene (Al = 0.9 mol/l), and stirred at room temperature for 10 minutes. To the flask, 10.4 ml of a solution of bis(methylcyclopentadienyl)zirconium dichloride in toluene (Zr = 0.048 mol/l) was then added, followed by stirring at room temperature for 15 minutes. Thereafter, 50 ml of hexane was added additionally to the flask, and ethylene was introduced into the system to initiate pre-polymerization. The pre-polymerization was carried out at 25 - 30 °C for 5 hours while feeding ethylene continuously under ordinary pressure. After completion of the pre-polymerization, the hexane was removed by decantation from the reaction mixture, and the resulting reaction mixture was washed with hexane to obtain a pre-polymerized catalyst containing 32 g of polyethylene per 1 g of the solid titanium catalyst component [A]. The atomic ratio (Zr/Ti) of zirconium to titanium in this pre-polymerized catalyst was 1.9. Example 2 (Pre-polymerization) The pre-polymerization of Example 1 was repeated except that no triisobutylaluminum was used, and the amount of the organoaluminum oxy-compound was changed to 69.5 ml, whereby a pre-polymerized catalyst containing 27 g of polyethylene and having the zirconium/titanium atomic ratio (Zr/Ti) of 1.6 was obtained. Example 3 (Pre-polymerization) A 400 ml galss flask thoroughly purged with nitrogen was charged with 35 ml of hexane, 21.1 ml of a slurry of the solid titanium catalyst component [A] in hexane (Ti = 0.0338 mol/l), 7.5 ml of a solution of triisobutylaluminium in toluene (Al = 1.0 mol/l) and 55.6 ml of a solution of the organoaluminum oxy-compound [C] in toluene (Al = 0.9 mol/l), and stirred at room temperature for 25 minutes. To the autoclave, 10.4 ml of a solution of bis(methylcyclopentadienyl)zirconium dichloride in toluene (Zr = 0.048 mol/l) was then added, and stirred at room temparature for 5 minutes. The flask was then cherged with 50 ml of hexane, and ethylene was introduced into the system to initiate pre-polymerization. The pre-polymerization was carried out at 25 - 30 °C for 5 hours while feeding ethylene continuously into the system under ordinary pressure. After completion of the pre-polymerization, the hexane was removed by decantation from the reaction mixture, and the resulting reaction mixture was washed with hexane to obtain a pre-polymerized catalyst containing 10 g of polyethylene per 1 g of the solid catalyst component [A]. The zirconium/titanium atomic ratio (Zr/Ti) in this pre-polymerized catalyst was 0.45. Example 4 (Polymerization) A 2-liter stainless steel autoclave thoroughly purged with nitrogen was charged with 150 g of sodium chloride (a special grade product of Wako Junyaku K.K.), and vacuum dried at 90 °C for 1 hour. The system was then cooled to 65 °C, and charged with the organoaluminum oxy-compound in an amount of 0.75 mg atom in terms of Al atom and the pre-polymerized catalyst as prepared in Example 1 in an amount of 7.8 X 10⁻³ mg atom in terms of Ti atom. Into the autoclave, 1.3 litre of hydrogen and then ethylene were introduced at 65 °C, whereby polymerization was initiated under the total pressure of 8 kg/cm²-G. The polymerization was then carried out at 80 °C for 1 hour while feeding ethylene thereinto and maintaining the total pressure at 8 kg/cm²-G. After completion of the polymerization, the sodium chloride was removed by water washing, and the remaining polymer was washed with ethanol, followed by vacuum drying at 80 °C overnight. As the result, there was obtained 82.0 g of polyethylene having a bulking density of 0.39 g/cm³, MFR of 0.03 g/10 min and M w/ M n of 5.8. Example 5 (Polymerization) The polymerization of Example 4 was repeated except that the pre-polymerised catalyst as prepared in Example 2 was used in an amount of 7.5 X 10⁻³ mg atom in terms of Ti atom, whereby 90.5 g of polyethylene having a bulking density of 0.40 g/cm³, MFR of 0.09 g/10 min and M w/ M n of 6.3 was obtained. Example 6 (Polymerization) The polymerization of Example 4 was repeated except that the pre-polymerized catalyst as prepared in Example 3 was used in an amount of 3.3 X 10⁻² mg atom in terms of Ti atom, the amount of hydrogen added was changed to 0.5 litre, and no triisobutylaluminum was used, whereby 211.0 g of polyethylene having a bulking density of 0.42 g/cm³ and MFR of not more than 0.01 g/10 min was obtained. Example 7 (Polymerization) A 2-liter stainless steel autoclave thoroughly purged with nitrogen was charged with 150 g of sodium chloride (a special grade product of Wako Junyaku K.K.), and vacuum dried at 90 °C for 1 hour. The system was then cooled to 65 °C, and the autoclave was charged with the organoaluminum oxy-compound in an amount of 0.6 mg atom in terms of Al atom and the pre-polymerized catalyst as prepared in Example 1 in an amount of 1 X 10⁻² mg atom in terms of Ti atom. Into the autoclave, hydrogen at a pressure of 1.5 kg/cm² and a mixed gas of ethylene and 1-butene (containing 5.8 mol% of 1-butene) at 65 °C were introduced, and polymerization was initiated under the total pressure of 8 kg/cm²-G. The polymerization was then carried out at 80 °C for 40 minutes while feeding the above-mentioned mixed gas into the system and maintaining the total pressure at 8 kg/cm²-G. After completion of the polymerization, the sodium chloride was removed by water washing, and the remaining polymer was washed with methanol, followed by vacuum drying at 80 °C overnight. As the result, there was obtained 107.6 g of an ethylene/1-butene copolymer having a bulking density of 0.37 g/cm³, MFR of 1.82 g/10 min, a density of 0.925 g/cm3, M w/ M n of 6.0 and an amount of decane-soluble portion of 2.5 % by weight. Comparative Example 1 (Pre-polymerization) A 400 ml flask thoroughly purged with nitrogen was charged with 3.05 g of silica (average particle diameter 70 µm, specific surface area 260 m²/g, pore volume 1.65 cm³/g), which had been calcinated at 700 °C for 6 hours, and 20 ml of decane, and the contents of the flask were brought to a suspension state. The flask was then charged with 7.61 ml of a solution of triisobutylaluminum in decane (Al = 1 mol/l), and stirred at room temperature for 30 minutes, and successively charged with 12.8 ml of a solution of the organoaluminium compound in toluene (Al = 1.99 mol/l), followed by stirring at room temperature for 30 minutes. The flask was then charged with 11.0 ml of a solution of bis(methylcyclopentadienyl)zirconium dichloride in toluene (Zr = 0.046 mol/l), and stirred for 30 minutes. After the addition of 100 ml of decane, ethylene gas (ordinary pressure) was introduced continuously into the system, whereby pre-polymerization was carried out at 30 °C for 4.5 hours. The decane was then removed by decantation, followed by hot washing (60 °C) four times with hexane and washing (room temperature) for four times with hexane. By virtue of this operation, there was obtained a solid catalyst containing Zr in an amount, based on 100 g of silica, of 12.0 X 10⁻³ gram atom, Al of 0.71 gram atom and 570 g of polyethylene. (Polymerization) The polymerization of Example 4 was repeated except that there were used 2.25 mmol of triisobutylaluminum and the pre-polymerized catalyst as prepared above in an amount of 1.5 X 10⁻² mg atom in terms of Zr atom, the amount of hydrogen added was changed to 0.2 litre, and polymerization was carried out for 2 hours, whereby 155 g of polyethylene having a bulking density of 0.42 g/cm³, MFR of 0.25 g/10 min and M w/ M n of 3.2 was obtained.

Claims: Claims for the following Contracting States : AT, BE, CH, DE, DK, FR, GB, GR, IT, LI, LU, NL, SE An olefin polymerization catalyst obtainable by pre-polymerizing an olefin in a suspension containing [A] a titanium catalyst component containing titanium, magnesium and halogen as its essential ingredients, [B-1] a transition metal compound containing a ligand having a cycloalkadienyl skeleton, and [C] an organoaluminium oxy-compound. An olefin polymerization catalyst according to claim 1 obtainable by pre-polymerizing an olefin in a suspension as defined in claim 1 further containing [D] an organoaluminum compound. An olefin polymerization catalyst comprising (I) a solid catalyst as claimed in claim 1 or 2, and (II) [C] an organoaluminum oxy-compound and/or [D] an organoaluminum compound. A process for the polymerization of olefins, which comprises polymerizing or copolymerizing olefins in the presence of an olefin polymerization catalyst as claimed in any one of the preceding claims. Claims for the following Contracting State : ES A process for preparing an olefin polymerization catalyst, which comprises pre-polymerizing an olefin in a suspension containing [A] a titanium catalyst component containing titanium, magnesium and halogen as its essential ingredients, [B-1] a transition metal compound containing a ligand having a cycloalkadienyl skeleton, and [C] an organoaluminum oxy-compound. A process according to claim 1 wherein the olefin is pre-polymerised in a suspension as defined in claim 1 further containing [D] an organoaluminum compound. A process according to claim 1 or 2, which further comprises mixing (I) a solid catalyst prepared by a process as claimed in claim 1 or 2, and (II) [C] an organoaluminum oxy-compound and/or [D] an organoaluminum compound. A process for the polymerization of olefins, which comprises polymerizing or copolymerizing olefins in the presence of an olefin polymerization catalyst obtainable by pre-polymerizing an olefin in a suspension containing [A] a titanium catalyst component containing titanium, magnesium and halogen as its essential ingredients, [B-1] a transition metal compound containing a ligand having a cycloalkadienyl skeleton, and [C] an organoaluminum oxy-compound. A process according to claim 4 wherein the olefin polymerization catalyst is obtainable by pre-polymerizing an olefin in a suspension as defined in claim 4 further containing [D] an organoaluminum compound. A process according to claim 4 or 5 wherein the olefin polymerization catalyst comprises (I) a solid catalyst as defined in claim 4 or 5, and (II) [C] an organoaluminum oxy-compound and/or [D] an organoaluminum compound.

Inventors: SUGIMURA KENJI C O MITSUI PETR, TSUTSUI TOSHIYUKI C O MITSUI P, UEDA TAKASHI C O MITSUI PETROC, SUGIMURA, KENJI, C/O MITSUI PETROCHEM. IND. LTD., TSUTSUI, TOSHIYUKI, C/O MITSUI PETROCHEM. IND. LTD, UEDA, TAKASHI, C/O MITSUI PETROCHEM. IND. LTD.
Applicants: MITSUI PETROCHEMICAL IND, MITSUI PETROCHEMICAL INDUSTRIES, LTD.
Application year: 1990
Main classification: C08F4
IPC codes: C08F4, C08F210, C08F10, C08F110