Crystalline aluminophosphates

Abstract: Crystalline aluminophosphates and related compounds having in the as-synthesized anhydrous form the chemical composition mR(X n Al q P x )O₂, wherein R represents 1,4 - diaminobutane as defined hereinbefore, X represents one or more elements which can be substituted for Al and/or P, wherein m = 0 - 0.33 n = 0 - 0.40 g = 0.30 - 0.60 x = 0.30 - 0.60 and wherein n + q + x = 1 and having an X-ray diffraction pattern containing at least the lines as given in Table A, B, C, D, E or F. The compounds can be prepared from a forming solution or gel comprising a source of alumina, a source of phosphorus, 1,4-diaminobutane and optionally a source of at least one component X wherein the various sources are present in certain specified molar ratios, by keeping the solution or gel at elevated temperature for a time sufficient to produce crystalline aluminophosphates or related compounds.

Description: The present invention relates to novel crystalline aluminophosphate compositions and a process for preparing such aluminophosphates. Crystalline aluminophosphate compositions are well known materials which find a promising reception in industry as new generations of molecular sieves, catalyst carriers as well as catalysts. For instance, in United States patent specification No. 4,310,440 the preparation of various crystalline aluminophosphates is described from reaction mixtures containing inter alia organic structure directing or templating agents including tetrapropylammonium hydroxide, quinuclidine, t-butylamine and ethylenediamine. Classes of these materials comprise compositions crystallised in the AlPO₄, SAPO₄ (siliconaluminophosphate), MeAPO₄ (metalloaluminophosphate) and ElAPO₄ (non-metal substituted aluminophosphate) families. It has now been found that novel crystalline aluminophosphates, e.g. of the AlPO₄-, SAPO₄ - and MeAPO₄-type can be prepared from reaction gels or solutions when use is made of the appropriate forming components and a certain organic diamine. The present invention thus relates to crystalline aluminophosphates having in the as-synthesized anhydrous form the chemical composition: mR(X n Al q P x )O₂, wherein R represents a 1,4-diaminobutane as defined hereinbelow, X represents one or more elements which can be substituted for Al and/or P, wherein 0 < m ≦ 0.33 n = 0 - 0.40 q = 0.30 - 0.60 x = 0.30 - 0.60 and wherein n + q + x = 1, and having an X-ray diffraction pattern containing at least the lines as given in Table A, B, C, D, E or F. d (A) Intensity 11.0 - 11.4 vw - m 9.0 - 9.4 m - vs 7.0 - 7.3 vw - m 4.7 - 4.9 vw - m 4.40 - 4.51 vw - vs 4.20 - 4.31 vw - s 3.80 - 3.90 vw - vs 3.53 - 3.59 vw - m 3.46 - 3.52 vw - m 3.09 - 3.15 vw - m 2.76 - 2.80 vw - m d (A) Intensity 12.0 - 12.4 w - m 10.9 - 11.4 s - vs 9.0 - 9.4 s - vs 4.4 - 4.6 w 4.41 - 4.51 w 3.69 - 3.79 w 3.52 - 3.58 w 3.43 - 3.50 w d (A) Intensity 9.6 - 10.2 m - vs 6.6 - 6.8 w - s 4.41 - 4.52 w - vs 3.81 - 3.91 w - s 3.56 - 3.63 m - s 3.45 - 3.51 w - vs 2.78 - 2.84 w - s d (A) Intensity 14.7 - 15.1 vw 12.2 - 12.6 vs 6.1 - 6.3 vw - w 4.7 - 4.9 vw 4.39 - 4.49 vw 3.77 - 3.87 vw 3.56 - 3.66 vw 3.14 - 3.20 vw 2.92 - 2.98 vw 2.71 - 2.75 vw 2.62 - 2.66 vw 2.44 - 2.48 vw 2.28 - 2.32 vw d (A) Intensity 19.5 - 19.9 vw 9.6 - 10.0 vs 4.8 - 5.0 m - s 4.45 - 4.55 vw 3.78 - 3.88 vw 3.56 - 3.66 vw - w 3.42 - 3.48 vw 3.23 - 3.29 w - m 2.77 - 2.83 vw 2.42 - 2.48 vw - w d (A) Intensity 6.6 - 6.8 w - s 5.8 - 6.0 vs 4.6 - 4.8 m 4.48 - 4.59 vw - m 3.68 - 3.78 vw - w 2.96 - 3.00 w - m 2.61 - 2.65 w - m In particular the present invention relates to crystalline aluminophosphates having the chemical composition as described hereinabove, wherein m = 0.005 - 0.30 n = 0 - 0.20 q = 0.40 - 0.60 and x = 0.40 - 0.60. As element X which can be substituted for aluminium and/or phosphorus in the crystalline aluminophosphates according to the present invention can suitably be used one or more of beryllium, magnesium, titanium, manganese, iron, cobalt, zinc, vanadium, nickel, chromium, silicon, lithium, boron, gallium, germanium and arsenic. Typically, said element will be one or more of magnesium, titanium, manganese, iron, cobalt, zinc, nickel, silicon, gallium or germanium, and preferably one or more of magnesium, titanium, manganese, iron, cobalt and silicon. It should be noted that the expression 1,4-diaminobutane as used throughout the specification is meant to include compounds having the basic 1,4-diaminobutane structure of four carbon atoms linearly bridging two nitrogen atoms which nitrogen atoms preferably carry both two hydrogen atoms but which may each also carry a third hydrogen atom or each up to three lower alkyl groups, preferably methyl groups. In the case of three moieties (hydrogen atoms and/or lower alkyl groups) attached to a nitrogen atom a cation is obtained which necessitates the presence of an anion to cause electroneutrality. In the event that n > 0 it will be appreciated that the as-synthesized anhydrous form also contains an appropriate charge-balancing cation such as a proton or a protonated form of R. An example of a novel crystalline aluminophosphate according to the present invention and belonging to the AlPO₄-class has in the as-synthesized form the following chemical composition: 0.25 R (Al 0.5 P 0.5 )O₂ having an X-ray diffraction pattern containing at least the lines as given in Table 1. A further example of a novel crystalline aluminophosphate according to the present invention and belonging to the AlPO₄-class has in the as-synthesized form the following chemical composition: 0.28 R (Al 0.5 P 0.5 )O₂ having an X-ray diffraction pattern containing at least the lines as given in Table 2. A further example of a novel crystalline aluminophosphate according to the present invention and belonging to the AlPO₄-class has in the as-synthesized form the following chemical composition: 0.16 R (Al 0.5 P 0.5 )O₂ having an X-ray diffraction pattern containing at least the lines as given in Table 3. A further example of a novel crystalline aluminophosphate according to the present invention and belonging to the AlPO₄-class has in the as-synthesized form the following chemical composition: 0.24 R (Al 0.5 P 0.5 )O₂ having an X-ray diffraction pattern containing at least the lines as given in Table 4. A further example of a novel crystalline aluminophosphate according to the present invention and belonging to the AlPO₄-class has in the as-synthesized form the following composition: 0.18 R (Al 0.5 P 0.5 )O₂ having an X-ray diffraction pattern containing at least the lines as given in Table 5. A further example of a novel crystalline aluminophosphate according to the present invention and belonging to the AlPO₄-class has in the as-synthesized form the following composition: 0.01 R (Al 0.5 P 0.5 )O₂ having an X-ray diffraction pattern containing at least the lines as given in Table 6. It should be understood that the anhydrous form referred to in this specification may also contain chemically bound water as the case may be. The present invention also relates to novel crystalline aluminophosphates having in the calcined substantially R-free form the general chemical composition: (X n Al q P x )O₂, wherein X, n, q and x have the meaning as described hereinabove and wherein n + q + x = 1 . The present invention also relates to a process for preparing novel crystalline aluminophosphates as defined hereinbefore from a forming solution or gel comprising a source of aluminium, a source of phosphorus, 1,4-diaminobutane and optionally a source of at least one component X, which mixture is kept at elevated temperature for a period of time sufficient to produce a crystalline aluminophosphate or related compound followed by separating off the crystalline product obtained and drying, in which solution or gel the various components are initially present in the following molar ratios: R : Al₂O3 = 0.1 - 3 X : Al₂O₃ = 0 - 2 P : Al₂O₃ = 0.3 - 1.3 H₂O : Al₂O₃ = 30 - 500. The crystalline aluminophosphates according to the present invention are preferably prepared from a forming solution or gel in which the various components are initially present in the following molar ratios: R : Al₂O₃ = 0.15 - 2 X : Al₂O₃ = 0 -2 P : Al₂O₃ = 0.4 - 1.25 H₂O : Al₂O₃ = 35 - 320. Crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray diffraction pattern containing at least the lines as given in Table A or B are suitably prepared whilst keeping the temperature below 140 °C, in particular at a temperature in the range of from 110 °C to 140 °C. Crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray diffraction pattern containing at least the lines as given in Table A, C or D are suitably prepared whilst keeping the temperature in the range of from 140 °C to 180 °C, in particular at a temperature in the range between 150 °C and 170 °C. Crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray diffraction pattern containing at least the lines as given in Table E or F are suitably prepared whilst keeping the temperature above 180 °C, in particular at a temperature in the range of from 190 °C to 210 °C. The use of aqueous forming solutions or gels is preferred. The process according to the present invention can be carried out at autogenous pressure as well as at elevated pressure. Normally, the novel crystalline aluminophosphates will be produced when the forming solution or gel has been kept under the appropriate conditions for a period of time allowing the proper structure to be formed. Preferably, the process according to the present invention is carried out for a period of time ranging between 18 and 144 hours, in particular between 24 and 96 hours. Examples of suitable aluminium sources comprise aluminium oxides, such as gibbsite, boehmite, pseudo-boehmite and aluminium alkoxides, such as aluminium isopropoxide and mixtures of various aluminium sources. It has been found that novel crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray pattern containing at least the lines as given in Table A are suitably prepared whilst using aluminium isopropoxide as aluminium source whilst keeping the temperature below 180 °C. Crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray diffraction pattern containing at least the lines as given in Table B are suitably prepared whilst using boehmite or pseudo-boehmite as aluminium source whilst keeping the temperature below 140 °C. Crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray diffraction pattern containing at least the lines as given in Table C are suitably prepared whilst using aluminium isopropoxide or boehmite as aluminium source whilst keeping the temperature in the range between 140 °C and 180 °C. Crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray diffraction pattern containing at least the lines as given in Table D are suitably prepared whilst using pseudo-boehmite as aluminium source whilst keeping the temperature between 140 °C and 180 °C. Crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray diffraction pattern containing at least the lines as given in Table E or F are suitably prepared whilst using aluminium isopropoxide, boehmite or pseudo-boehmite as aluminium source whilst keeping the temperature above 180 °C. Suitable phosphorus sources comprise phosphorus acids and derivatives thereof such as esters, phosphorus oxides, phosphates and phosphites, preferably ortho-phosphoric acid and mixtures of various phosphorus sources. Examples of suitable sources of X comprise the appropriate chlorides, iodides, bromides, nitrates, sulphates and acetates, preferably acetates as well as oxides. If desired, the crystalline aluminophosphates produced can be calcined after drying to produce the desired calcined substantially R-free aluminophosphates and related compounds. It has been found that agitation can be applied advantageously to produce the desired crystalline aluminophosphates from the forming solution or gel. The novel crystalline aluminophosphates according to the present invention can suitably be used as molecular sieves, catalysts or as catalyst carriers in the operation of various catalytic processes. If desired, one or more (catalytically) active species, in particular protons and/or precursors thereof and/or one or more metal(s) compounds of Group III and/or the Transition Metals and/or Rare Earth metals and/or precursors thereof, can be incorporated into the crystalline aluminophosphates according to the present invention. They can be incorporated by well-known techniques such as, for instance, impregnation and ion-exchange. The invention will now be illustrated by means of the following Examples. Example I A crystalline AlPO₄, referred to as SCS-15, was prepared by mixing 27.2 grammes of Al (iOPr)₃, 15.4 grammes of 85% H₃PO₄, 5.9 grammes of 1,4-diaminobutane (C₄DN) and 48.1 grammes of water giving a reaction gel composition on a molar basis of 1 Al₂O₃ : 1 P₂O₅ : 1 C₄DN : 45 H₂O. The mixture was kept at 120 °C for a period of 72 hours until a crystalline product was obtained. After synthesis the crystalline compound produced was separated from the reaction mixture by filtration, water washed and dried at 120 °C. The crystalline compound obtained had in the anhydrous form the following chemical composition: 0.25 C₄DN (Al 0.5 P 0.5 )O₂ and an X-ray diffraction pattern containing at least the lines as given in Table 1 below: d(A) Intensity 11.2 vw 9.2 vs 7.1 vw 4.8 vw 4.45 vw - w 4.25 vw - w 3.85 vw - w 3.56 vw - w 3.49 vw 3.12 vw 2.80 vw 2.78 vw Example II The experiment described in Example 1 was repeated but maintaining a reaction temperature of 160 °C during the formation of the crystalline AlPO₄. After working up SCS-15 was obtained having essentially the same lines in its X-ray diffraction pattern as already described in Table 1. Example II I The experiment described in the previous Example was repeated but using a molar ratio C₄DN : P₂O₅ of 1.25. After working up SCS-15 was obtained having essentially the same lines in its X-ray diffraction pattern as already described in Table 1. Example IV The experiment described in Example II was repeated but using a molar ratio H₂O : Al₂O₃ of 320. After working up SCS-15 was obtained having essentially the same lines in its X-ray diffraction pattern as already described in Table 1. Example V The experiment described in Example II was repeated but keeping the reaction mixture at a temperature of 160 °C for a period of 24 hours. After working up SCS-15 was obtained having essentially the same lines in its X-ray diffraction pattern as already described in Table 1. Example VI The experiment as described in Example I was repeated but using 9.2 grammes of boehmite as the aluminium source and 45.7 grammes of water. A novel AlPO₄, referred to as SCS-17, was obtained after the standard working up procedure together with a small amount of SCS-15. The crystalline product obtained had in the anhydrous form the following molar composition: 0.28 C₄DN (Al 0.5 P 0.5 )O₂ and an X-ray diffraction pattern containing at least the lines as given in Table 2. d (A) Intensity 12.2 w - m 11.2 vs 9.2 s - vs 4.6 w 4.46 w 4.40 vw - w 3.74 w 3.55 w 3.46 w Example VII The experiment described in the previous Example was repeated but using 9.8 grammes of pseudo-boehmite as the aluminium source and 45.1 grammes of water. After working up the same compound as described in Example VI was obtained having an X-ray diffraction pattern containing at least the lines given in Table 2. Example VIII The experiment described in Example II was repeated but using 9.2 grammes of boehmite as the aluminium source and 45.7 grammes of water. After working up a crystalline AlPO₄, referred to as SCS-18, was obtained. The crystalline product obtained had in the anhydrous form the following chemical composition: 0.16 C₄DN (Al 0.5 P 0.5 )O₂ and had an X-ray diffraction pattern containing at least the lines as given in Table 3. d (A) Intensity 9.8 vs 6.7 vw - w 4.47 w - m 3.86 w - m 3.60 m - s 3.48 w - m 2.81 w - m Example IX The experiment described in the previous Example was repeated but using 27.2 grammes of Al (iOPr)₃ as the aluminium source and 50.4 grammes of water as well as using a C4DN:P₂O₅ molar ratio of 1.67. After working up SCS-18 was obtained having an X-ray diffraction pattern containing at least the lines given in Table 3. Example X The experiment described in Example VII was repeated but the reaction mixture was kept at a temperature of 160 °C. After working up a crystalline AlPO₄, referred to as SCS-19 was obtained together with a small amount of another crystalline AlPO₄ material as described in European patent specification 344,837. The cyrstalline material obtained had in its anhydrous form the following chemical composition: 0.24 C₄DN (Al 0.5 P 0.5 )O₂ and had an X-ray diffraction pattern containing at least the lines as given in Table 4. d (A) Intensity 14.9 vw 12.4 vs 6.2 vw - w 4.8 vw 4.44 vw 3.82 vw 3.61 vw 3.58 vw 3.17 vw 2.99 vw 2.95 vw 2.73 vw 2.64 vw 2.46 vw 2.30 vw Example XI The experiment described in Example I was repeated but the reaction mixture was kept at a temperature of 200 °C. After working up a crystalline AlPO₄, referred to as SCS-20, was obtained. The crystalline product obtained had in its anhydrous form the following chemical composition: 0.18 C₄DN (Al 0.5 P 0.5 )O₂ and had an X-ray diffraction pattern containing at least the lines as given in Table 5. d (A) Intensity 19.7 vw 9.8 vs 4.9 m - s 4.5 vw 3.83 vw 3.61 vw - w 3.45 vw 3.26 w - m 2.80 vw 2.45 vw - w Example XII The experiment described in the previous Example was repeated but using 9.2 grammes of boehmite as the aluminium source and 45.7 grammes of water. After working up a crystalline AlPO₄, referred to as SCS-21, was obtained. The crystalline product obtained had in its anhydrous form the following chemical composition: 0.01 C₄DN (Al 0.5 P 0.5 )O₂ and had an X-ray diffraction pattern containing at least the lines as given in Table 6. d (A) Intensity 6.7 s 5.9 vs 4.7 m 4.55 w - m 4.18 w 3.73 w 3.02 w - m 2.99 w - m 2.97 w - m 2.95 w 2.83 w - m 2.66 w - m 2.63 w - m Example XIII The experiment described in the previous Example was repeated but using pseudo-boehmite as the aluminium source. After working up SCS-21 was obtained together with a very small amount of an unknown material. The crystalline material obtained had an X-ray diffraction pattern containing at least the lines as given in Table 6.

Claims: Crystalline aluminophosphates having in the as-synthesized anhydrous form the chemical composition mR(X n Al q P x )O₂, wherein R represents 1,4 - diaminobutane, including compounds having the basic 1,4-diaminobutane structure of four carbon atoms linearly bridging two nitrogen atoms which nitrogen atoms preferably carry both two hydrogen atoms but which may each also carry a third hydrogen atom or each up to three lower alkyl groups, preferably methyl groups, wherein in the case of three moieties (hydrogen atoms and/or lower alkyl groups) attached to a nitrogen atom a cation is obtained which necessitates the presence of an anion to cause electroneutrality, X represents one or more elements which can be substituted for Al and/or P, wherein 0 < m ≦ 0.33 n = 0 - 0.40 q = 0.30 - 0.60 x = 0.30 - 0.60 and wherein n + q + x = 1 and having an X-ray diffraction pattern containing at least the lines as given in Table A, B, C, D, E or F. Crystalline aluminophosphates according to claim 1, wherein m = 0.005 - 0.30 n = 0 - 0.20 q = 0.40 - 0.60 and x = 0.40 - 0.60. Crystalline aluminophosphate according to claim 1 having an X-ray pattern containing at least the lines as given in Table 1. Crystalline aluminophosphate according to claim 1 having an X-ray pattern containing at least the lines as given in Table 2. Crystalline aluminophosphate according to claim 1 having an X-ray pattern containing at least the lines as given in Table 3. Crystalline aluminophosphate according to claim 1 having an X-ray pattern containing at least the lines as given in Table 4. Crystalline aluminophosphate according to claim 1 having an X-ray pattern containing at least the lines as given in Table 5. Crystalline aluminophosphate according to claim 1 having an X-ray pattern containing at least the lines as given in Table 6. Crystalline aluminophosphates according to one or more of claims 1-8, wherein X represents one or more of beryllium, magnesium, titanium, manganese, iron, cobalt, zinc, vanadium, nickel, chromium, silicon, lithium, boron, gallium, germanium and arsenic, preferably one or more of magnesium, manganese, titanium, iron, cobalt and silicon. Crystalline aluminophosphates according to any one of claims 1-9 having in the calcined substantially R-free form the formula: (X n Al q P x )O₂, wherein X, n, q and x have the meanings as described hereinabove and wherein n + q + x = 1 . Crystalline aluminophosphates according to any one of claims 1-10, wherein one or more (catalytically) active species have been incorporated, preferably protons and/or precursors thereof and/or one or more metal(s) (compounds) of Group III and/or the Transition Metals and/or Rare Earth metals and/or precursors thereof. A process for preparing crystalline aluminophosphates as claimed in claim 1 from a forming solution or gel comprising a source of aluminium, a source of phosphorus, 1,4-diaminobutane and optionally a source of at least one component X, which mixture is kept at elevated temperature for a period of time sufficient to produce a crystalline aluminophosphate followed by separating off the crystalline product obtained and drying, in which solution or gel the various components are initially present in the following molar ratios: R : Al₂O₃ = 0.1 - 3 X : Al₂O₃ = 0 - 2 P : Al₂O₃ = 0.3 - 1.3 H₂O : Al₂O₃ = 30 - 500. A process according to claim 12, wherein the various components in the forming solution or gel are initially present in the following molar ratios: R : Al₂O₃ = 0.15 - 2 X : Al₂O₃ = 0 - 2 P : Al₂O₃ = 0.4 - 1.25 H₂O : Al₂O₃ = 35 - 320. A process according to claim 12 or 13, wherein crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray pattern containing at least the lines as given in Table A or B are produced whilst keeping the temperature below 140 °C. A process according to claim 12 or 13, wherein crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray pattern containing at least the lines as given in Table A, C or D are produced whilst keeping the temperature between 140 and 180 °C. A process according to claim 12 or 13, wherein crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray pattern containing at least the lines as given in Table E or F are produced whilst keeping the temperature above 180 °C. A process according to claim 14 or 15, wherein crystalline aluminophosphates having in the as-synthesized anhydrous form an X-ray pattern containing at least the lines as given in Table A are produced whilst using aluminium isopropoxide as aluminium source. A process according to claim 14, wherein crystalline aluminophosphates having in the as-synthesized form an X-ray pattern containing at least the lines as given in Table B are prepared whilst using boehmite or pseudo-boehmite as aluminium source. A process according to claim 15, wherein crystalline aluminophosphates having in the as-synthesized form an X-ray pattern containing at least the lines as given in Table C are prepared whilst using aluminium isopropoxide or boehmite as aluminium source. A process according to claim 15, wherein crystalline aluminophosphates having in the as-synthesized form an X-ray pattern containing at least the lines as given in Table D are prepared whilst using pseudo-boehmite as aluminium source. A process according to claim 16, wherein crystalline aluminophosphates having in the as-synthesized form an X-ray pattern containing at least the lines as given in Table E or F are prepared whilst using aluminium isopropoxide, boehmite or pseudo-boehmite as aluminium source. A process according to one or more of claims 12-19, wherein use is made of phosphorus acids, phosphorus oxides, phosphates or phosphites as source of phosphorus, in particular of phosphoric acid. A process according to one or more of claims 12-22, wherein use is made of components X in the form of the appropriate chlorides, iodides, bromides, sulphates, nitrates, acetates or oxides, in particular in the form of the acetates. A process according to one or more of claims 12-23, wherein the crystalline product obtained is calcined. Use of crystalline aluminophosphates as claimed in any one of claims 1-11 as a molecular sieve, catalyst or catalyst carrier.

Inventors: CLARK DAVID MICHAEL, DOGTEROM RONALD JAN, KRAUSHAAR-CZARNETZKI BETTINA, CLARK, DAVID MICHAEL, DOGTEROM, RONALD JAN, KRAUSHAAR-CZARNETZKI, BETTINA
Applicants: SHELL INT RESEARCH, SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
Application year: 1990
Main classification: C01B25
IPC codes: C01B37, C01B25, C01B39, B01J29