Blown film comprising destructured starch and a thermoplastic polymer

Abstract: Biodegradable composition comprising destructured starch, a thermoplastic polymer and a high-boiling plasticiser in an amount from 0.05 to 100% of the weight of the starch, where in the starch is obtained by destructuring starch as it is without the addition of water.

Description: The present invention relates to blown films obtainable from a destructured starch-based composition. In particular, the invention makes use of a starch composition which can easily be mixed with and is compatible with polymers having relatively high melting points, thus enabling the formulation of substantially biodegradable polymer mixtures which, by virtue of the presence of the plastics material with a high melting point, have mechanical, physical and chemical properties which have hitherto been unobtainable. It is known that the natural starch present in plant products can be treated in a closed container, in the presence of a variable water content, at high temperature and at high pressure (according to the water content) to form a fused thermoplastic material. If the same heat treatment is carried out in the absence of pressure and/or in the absence of water, it causes the cross-linking of the material and it is impossible to achieve fusion. As a result of the heat treatment carried out at a temperature higher than the glass transition temperatures and the melting points of the components, fusion occurs and the molecular structure of the starch granules become disordered, producing the socalled "destructured starch". According to conventional techniques, the destructuring of the starch is carried out in the presence of water added as appropriate and under a pressure which corresponds at least to the vapour pressure of the water present within the extruder. Published European patent application EP-A-0 304 401 describes a method for the production of moulded articles from destructured starch in which, in a first stage, the starch is destructured beforehand in an extruder with water and the composition thus obtained, which has a water content of the order of 10-20%, is reprocessed, in a second stage, in an extruder for subsequent injection moulding. The presence of water in the starch destructured in the first stage limits the workability of the composition which is difficult to mix with other polymers in order to form blends with the desired characteristics, particularly for the formation of films. In fact, the composition can be extruded only at relatively low temperatures and under high pressure, so that polymers blends can be produced with polymers which have low melting points. On the other hand, compositions of destructured starch alone obtained in this way are not suitable for filming processes. Published European patent application EP-A-0 282 451 describes a method for preparation of a destructurised starch composition by heating a chemically non-modified starch material having a water content in the range of about 5 to 25% by weight of the total weight of the composition in the presence of a chain scission catalyst such as sodium hydroxide, potassium hydroxide, magnesium hydroxide and a plasticiser. The above publication deals only with the problem of reducing the incidence of surface defect in moulded articles, obtained from destructured starch and does not address the problem of providing compositions suitable to be formed into films having mechanical properties. In order to provide compositions which can be converted into films, US patent No. 4,133,784 describes compositions of starch and a polymer compatible therewith, constituted by ethylene/acrylic acid (EAA). According to the method of preparation described therein, the starch is gelled by being heated in the presence of water until a viscous dispersion is formed. The EAA component is added to the starch during the gelling stage or thereafter. The compositions thus obtained are suitable for conversion into films only by means of expensive processes such as spreading (casting), simple extrusion or rolling (milling). In order to increase the gelling speed and thus reduce the quantity of water required, it has been proposed, in the publication Ind.Eng.Chem.Res. 1987, 26, pages 1659-1663, that urea be added to the starch and EAA copolymer composition. By virtue of the addition of urea, it is possible to extrude a semi-dry composition (water content approximately 16%), avoiding the need to mix starch and EAA in a mixer with a large excess of water. The same document describes the addition of polyols to the starch and EAA copolymer formulation with the addition of water, by a technique whereby the components are pre-mixed in a Brabender mixer and are then repeatedly extruded in order progressively to reduce the moisture content of the composition undergoing the process, so as to produce an extrusion suitable for filming by extrusion and blowing. The method described is obviously expensive from the point of view of the energy used, since it includes the wasteful addition of water and its subsequent removal by repeated extrusions. The subject of the invention is therefore constituted by a a blown film according to claims 1 to 10 . In a specific embodyment the method for the preparation of a destructured starch-based composition usable for the production of the blown films of biodegradable plastics material, is characterised in that it includes the step of mixing starch as it is, in a heated extruder, with a high-boiling plasticiser as defined in the claims and a destructuring agent formed of urea for a time sufficient to bring about the destructuring, and at a temperature below the boiling point of the plasticiser and between 120 and 170°C, preferably between 140 and 170°C. The starch used in the method comprises in general all starches of natural or plant origin which are composed essentially of amylose and/or amylopectin. They can be extracted from various plants, such as for example potatoes, rice, tapioca, maize and cereals such as rye, oats, and wheat. Maize starch is preferred. Chemically-modified starches and starches of different genotypes can also be used. The starch is used as it is, without being dried beforehand and without the addition of any water (the intrinsic bound water content of the commercial products is of the order of 10-13% by weight). At destructuring treatment temperatures above 120°C, the water which is present, bound to the starch, does not generate a vapour pressure such as to require high pressures. This constitutes a further advantage of the method according to the invention. The plasticiser used in the composition of the invention is preferably selected from the group consisting of glycerine, polyethylene glycol, preferably with a molecular weight of from 220 to 4000, ethylene glycol, propylene glycol and sorbitol. Plasticisers belonging to the group of polyols having boiling points of at least 150°C can generally be used. The quantity of plasticiser added to the starch as it is, is from 20 to 100% of the weight of the starch. Urea is used in a quantity of from 2 to 20% of the weight of the starch. The destructuring operation can be carried out with the addition to the composition of a quantity of ethylene/acrylic acid (EAA) of up to 15% of the total weight of the composition. The use of EAA copolymer, which is compatible with the starch, facilitates the extrusion. If EAA copolymer is used, the use of ammonia is advantageous in a quantity which is not critical, but is generally equivalent to at least half of the acid groups in the EAA copolymer. The added ammonia is substantially removed to a residual content of less than 0.5% by weight during the extrusion of the composition. During the course of the destructuring operation, other additives, either polymeric or monomeric, which do not interfere with the destructuring process, may be added to the starch. However, these additives may also be added to the destructured starch composition at a subsequent blending stage preceding the conversion of the composition into the blown films. For example, polyvinyl alcohol may be added to change the behaviour of the films with water; UV stabilisers, such as for example carbon black, may be added to improve the resistance of the articles to sunlight; flameproofing agents may be added if the films need to have this property. Other additives include the conventional additives generally incorporated in starch-based moulding compositions, such as fungicides, herbicides, antioxidants, fertilisers and cross-linking agents such as formaldehyde, paraformaldehyde and the like. As a result of the method, a destructured starch composition is obtained which can be processed at a temperature higher than 120°C and which can therefore be extruded without problems due to the formation of bubbles and without the liberation of volatile agents at low pressure. The composition is particularly suitable for mixing with polymers which have relatively high melting points, such as ethylene/vinyl alcohol, particularly as described in the co-pending patent application in the name of the applicant and filed on the same date as the present application. Examples 1-4 The starch-based-compositions shown in Table 1, were processed by extrusion with different extrusion temperatures. CERESTAR GLOBE 03401 starch (bound water content 11%), % wt. EX1 EX2 EX3 EX4 63 63 63 63 GLYCERINE % wt. 25 25 25 25 COPOLYMER EAA 5981 (DOW CHEMICAL) (acrylic acid content 20%), % wt. 5 5 5 - Extrusion Temperature 100 120 140 140 The components of the molding compositions of Examples 1-4 were supplied by a Licoarbo DC-10 batcher to a Baker Perkins MPC/V-30 extruder. The double-screw extruder was constituted by a screw unit which was divided into two regions with a screw diameter of 30 mm and a screw length/diameter ratio of 10, and was connected to a single-screw extruder press having a capillary head and a screw of 30 mm diameter with a length/diameter ratio of 8:1 and divided into three regions. The capillary nozzle used had a diameter of 4.5 mm. The extrusions obtained were made into pellets. A small amount of the pellets resulting from experiments 1 to 4 was compression moulded at the temperature of 140°C in. order to obtain films having the thickness of about 20 microns. The same films were analysed by optical microscopy with polarised light (250 X enlargement) and microphotographs were taken in order to ascertain the destructuring of the starch. From the microphotograph relating to comparative experiment 1, it is apparent that the extrusion temperature of 100°C is too low and does not allow the destructuring of the starch; the microphotograph shows the presence of a large number of still intact starch granules. The analysis of the product obtained from example 2 (extrusion temperature 120°C) shows that the number of intact starch granules has been substantially reduced, although some are still present. On the other hand, a complete destructuring of the starch is obtained according to example 3 with extrusion temperature of 140°C. The microphotographs obtained from the material of example 3 does not show intact starch granules. The product of example 3 may also be made into pellets without any difficulty. The analysis of the product of example 4 which was extruded under the same condition of example 3, but does not include the EAA-5981 copolymer, shows that satisfactory results are obtained also in the absence of such a copolymer, however some difficulties may be encountered in making pellets from this compositions. Example 5 60% of destructured starch pellets and 40% by weight of CLARENE R20 ethylene/vinyl alcohol copolymer were extruded at 160°C in the same extruder. The final blend was blown by a Haake Reomex model 252 extruder with an L/D ratio of 19, a screw diameter of 19 mm and a compression ratio of 1:3, operating with the screw revolving at 40 rpm and provided with a film-blowing head. Rectangular test pieces for tensile testing according to ASTM 882 were formed from the film which were approximately 100 microns thick. The test pieces were conditioned at 23 ± 1°C and 55 ± 5% relative humidity for 24 hours and gave the following average results: Young's modulus 3861 kg/cm 2 yielding strain 43% yielding stress 164 kg/cm 2 breaking strain 207% breaking stress 210 kg/cm 2 . The product obtained was characterised by a melting point of 135°C and a glass transition temperature of 70°C. The films obtained were particularly suitable for use as packaging materials, especially for the production of disposable bags. Even after ageing for prolonged periods, there was no substantial loss of plasticiser and the film produced remained plastic and flexible and was little affected by ambient conditions.

Claims: A blown film obtainable from a biodegradable composition comprising, as essential components, destructurised starch obtained by destructurisation of starch having its intrinsic content of bound water without the addition of water, a thermoplastic polymer other than starch and a plasticizer having a boiling point higher than 150°C in an amount from 20 to 100% by wt. on the weight of starch. A film according to claim 1, obtained by mixing in a heated extruder in the absence of added water: a) a destructured starch prepared by destructuring starch as it is, without the addition of water; b) a thermoplastic polymer; and c) a high-boiling plasticiser, wherein the quantity of the high-boiling plasticiser is from 0.05 to 100% of the weight of the destructured starch. A film according to claims 1 to 2, the biodegradable composition comprising a destructured starch-based composition and a thermoplastic polymer, the biodegradable composition being produced by contacting the destructured starch-based composition with the thermoplastic polymer, wherein, prior to contacting the destructured starch-based composition with the thermoplastic polymer, the destructured starch-based composition is produced by a method comprising: mixing in the absence of added water and in a heated extruder: a.1) starch that is not dried beforehand; c.1) a high-boiling plasticiser, wherein the quantity of high-boiling plasticiser is from 0.5 to 100% of the weight of the starch; and d) urea as destructuring agent for a time sufficient to bring about destructuring of the starch and at a temperature below the boiling point of the plasticiser, comprised between 120°C and 170°C. A film according to claims 1 to 3, wherein the starch prior to being destructured contains less than 13% by weight of water. A film according to claim 4, wherein the starch prior to being destructured contains from 10 to 13% by weight of water. A film according to claims 1 or 2, wherein the plasticiser is selected from the group consisting of polyols having boiling point of at least 150°C. A film according to claim 1, wherein the plasticiser is selected from the group consisting of glycerine, polyethylene glycol, ethylene glycol, propylene glycol, sorbitol and mixtures thereof. A film according to claim 3, wherein the destructured starch-based composition further comprises a copolymer selected from the group consisting of ethylene/acrylic acid, polyvinyl alcohol and mixtures thereof, and wherein the quantity of the copolymer is up to 15% of the total weight of the destructured starch-based composition. A film according to claim 3, wherein the urea destructuring agent is present in an amount of from 2 to 20% of the weight of the starch. A film according to claim 3, wherein the destructured starch-based composition further comprises additives selected from the group consisting of UV stabilisers, flameproofing agents, fungicides, herbicides, antioxidants, fertilisers, opacifiers and stabilisers which do not interfere with the destructuring of said starch.

Inventors: BASTIOLI CATIA, DEL TREDICI GIANFRANCO, GUANELLA ITALO, LOMBI ROBERTO, BASTIOLI, CATIA, DEL TREDICI, GIANFRANCO, GUANELLA, ITALO, LOMBI, ROBERTO
Applicants: NOVAMONT SPA, NOVAMONT S.P.A.
Application year: 1990
Main classification: C08L3
IPC codes: C08L3, C08B30, C08B31, C08L101, B29C47