Solid-state radiation sensors

Abstract: A solid state radiation sensor array panel (10) comprising a thick deposited radiation detector layer (16) capable of generating electron-hole pairs in response to being irradiated, and a matrix array of transistors comprising source and drain electrode elements, a charge-transport layer (22), and a dielectric layer (34) disposed over one surface of the detector layer. Means are provided for establishing an electric field across the detector layer, which field is collapsible to establish a higher field in irradiated areas so as to establish a current path, between the source and drain electrode elements, through pixel areas of the charge-transport layer. The currents passing through pixel areas are passed to a readout circuit for processing the radiation image information.

Description: This invention relates to a large area sensor array panel for direct detection of image-wise radiation patterns and the pixel-by-pixel electronic read-out thereof. For example, the sensor array panel is capable of providing electrical image information representative of input patterns of visible or UV light, X-rays, gamma rays, high energy ionizing particles and even sound waves. Sensor arrays are commonly used for diagnostic imaging, in medical and scientific applications. Conventionally these have outputs which may be visual, resulting in a film image, or digital, resulting in electrical data for transmission to a suitable data-processing unit. In order to be useful, good spatial and energy resolutions are required, i.e. the number of pixels per unit area resolved and the sensitivity to the expected energy spectrum, must be coincident with the task requirements. A one-dimensional digital detector array is disclosed in US-A-4,303,860, wherein a narrow fan beam of X-rays is passed through an object to be imaged and is received by a scintillation crystal which generates light, in proportion thereto. The light in turn, is received by an array of photodiodes, in intimate contact with the crystal, which generate a current in proportion to the intensity of illumination. The current may be detected by any suitable means, such as an array of CCDs or other sensor. Relative movement between the object and the radiation source with its detector array is required in order to image the object completely. By using a two-dimensional detector array, a single divergent X-ray beam may be directed through an object onto a large area panel, which may be of any arbitrary size. In US-A-4,626,688 and in Figures 1 and 2 of US-A-4,707,608 both one-dimensional and two-dimensional arrays are shown. As in ′860, ′688 discloses a radiation-sensitive material responsive to incident radiation to produce light, and an adjacent array of photodiodes responsive to the light to produce an analog electrical signal indicative of radiation intensity. In ′608 primary radiation (X-rays) produces secondary radiation (electron-ion pairs) within a detector which, in turn, produces charge carriers in a detector. Recent progress in amorphous silicon fabrication techniques has enabled this material to be deposited and patterned over large areas so as to create page-size integrated electronics. Typically, for most electronic applications, as well as for optical sensing applications, this material is no more than a few µm thick. When used with a radiation-detecting phosphor screen, X-rays impacting the phosphor cause it to emit visible light which will generate a current normally through the adjacent amorphous silicon detector layer which, in turn, must be picked up by a suitable detection circuit. A major shortcoming of devices of this type is their extremely low detection efficiency. Because the phosphor screen typically has an efficiency generally below 10% in generating light in response to incident radiation, even with a highly efficient optical sensor coupled thereto, devices of this type can be no more than about 10% efficient. While thin amorphous silicon layers are highly efficient in detecting visible light, it is known that thick amorphous silicon layers (on the order of 10 to 50µm) may detect high energy radiation (i.e. radiation with high energy photons or particles) with an efficiency of greater than 90%. In US-A- 4,785,186 a thick amorphous silicon layer in a p-i-n doped configuration, with electrically-biased upper and lower metal electrodes, will pass current therethrough, thereby detecting the existence of high energy radiation. Particle position detection can be accomplished by an array of such devices connecting the output currents to the inlets of amplifiers. The direct detection of radiation-induced electron-hole pairs passing through the detector layer is much simpler than the arrangement afforded by scintillation systems in which the high energy radiation is converted to visible light which is detected by an adjacent sensor. In a paper entitled "A New Type of Field-Effect Image Storage Panel with a Photoconductive Charging Layer" (Kazan et al ), Proceedings of the IEEE, Vol. 56, No. 11, pp. 2057-2059, November 1968 there is taught an electroluminescent imaging panel in which local charging or discharging of an adjacent semiconductor layer (ZnO) is controlled by an adjacent photoconductive layer. Thus, in areas irradiated by an image of UV radiation, the resultant currents through the photoconductive layer produce trapped charges at the interface with a ZnO layer which, in turn, controls the local conductivity of the ZnO layer. In accordance with these variations in conductivity, local currents are allowed to flow through an electroluminescent phosphor across which voltage is maintained. A stored visible image is thus produced by the electroluminescent phosphor layer, corresponding to a transient image. A transistor-photodiode array with mutiplexed scanning is taught in "Advances in Image Pickup and Display", Vol. 6. pp. 184, 185, 1983, in the chapter entitled "Image Sensors for Television and Related Applications" (Weimer et al ). As schematically illustrated in Figure 4, each pixel location is provided with a photosensor and a transistor. None of the above arrangements satisfies the high resolution requirements of present day diagnostic imaging (on the order of several hundred spots per inch) with a relatively inexpensive and simply fabricated structure. Two-dimensional sensor arrays are known to have been fabricated incorporating a sensor and a transistor at each pixel location, using known thinfilm lithographic techniques. However, in these devices the sensors and transistors lend themselves to fabrication integration because they have generally the same thickness dimensions (i.e., transistors having an overall thickness of about 0.5 µm and sensors having an overall thickness dimension of about 1µm). It would be virtually impossible to form two-dimensional sensor arrays integrating at each pixel location very thick detectors (about 20 to greater than 100µm) and very thin transistors (about 1µm). It is believed that thick films of photoconductive materials, such as amorphous selenium, polycrystalline zinc sulfide, arsenic selenide and other chalcogenide glasses, because of their high atomic mass, would be desirable as X-ray or other high energy particle detectors. Organic photoconductors may also be used to detect high energy radiation but, because of their low atomic mass, may not function as well. However, these materials by and large have no body of photolithographic technology associated with them to allow the producing of a pattern of small elements. If the detector material is piezoelectric, such as polyvinylidene difluoride, it is possible to detect ultrasound or other pressure waves. Therefore, it is the primary object of this invention to provide a direct radiation detection and readout device employing a thick radiation detector, which does not need to be patterned, and incorporating therewith a large area thin-film transistor (TFT) array for generating analog electrical output signals responsive to the amount of radiation impinging upon each pixel location. Accordingly the present invention provides a solid-state radiation sensitive array panel as defined in claim 1. The panel comprises a thick deposited radiation detector layer capable of generating electron-hole pairs when irradiated, and a matrix array of transistors comprising source and drain electrode elements, a charge transport layer, and a dielectric layer disposed over one surface of the detector layer. Means is provided for establishing an electric field across the detector layer, which field is collapsible in irradiated areas thus establishing a higher field across the dielectric, and allowing current to flow between the source and drain electrode elements, through the charge transport layer in pixel areas. The currents passing through the pixel areas are then passed to a readout circuit for processing the radiation image information. The present invention will now be described by way of example with reference to the accompanying drawings, wherein: Figure 1 is a side sectional view taken through a solid-state image sensor array of the present invention; Figure 2 is a plan view of the sensor array of Figure 1, with the passivation layer having been removed, showing the readout matrix of thin film transistors; Figure 3 is a side sectional view, similar to that of Figure 1, showing a modified form of the image sensor array, including metal gate electrodes; Figure 4 is a schematic plan view showing a gate electrode discharge network, and Figure 5 is a side sectional view, similar to that of Figure 1, showing a modified form of a sensor array including a piezoelectric detector and charge stroage means. Turning now to Figure 1, there is illustrated a large-area image sensor panel 10 which can be used to detect any radiation that results in the excitation of electron-hole pairs, such as X-rays, gamma rays, or high energy ionizing particles. The panel may be fabricated in any suitable size, such as would be required for medical or other diagnostic imaging. It includes a substrate 12, such as glass, which must be able to withstand the fabrication temperatures of the layers to be deposited thereon (on the order of 300°C), upon which is deposited a thin (about 50 nm thick), continuous, planar, conductive layer 14 of chromium or aluminum. If the detector panel is used in a manner in which the radiation must pass through the conductive layer, the conductive layer must be made of a material which will allow such passage. The next adjacent layer is a thick, continuous, planar, detector layer 16, which can be any semiconduction material having an appropriate absorption coefficient and thickness for the type of radiation to be sensed, and which will generate electron-hole pairs in response to the radiation. For high energy radiation, a material with a high atomic number is most suitable. Presently, amorphous silicon thick films have a practical fabrication limit of about 50 µm, while the practical thickness limitation for chalcogenide glasses may be about 100 to 200 µm. Grown directly upon the detector layer is a multi-layer matrix array 18 of thin film transistors comprising: a thin (about 300 nm thick), continuous, planar, gate dielectric layer 20, typically made of silicon nitride; an undoped, or very lightly doped, thin (about 100 to 300 nm thick), continuous, planar, semiconductor channel layer 22 typically made of amorphous silicon; a patterned array of generally orthogonal n + source electrodes 24 and n + drain electrodes 26 (about 20 to 50 nm thick), each being provided with metal contact lines 28 and 30, of comparable thickness, thereon; and a silicon nitride insulation layer 32 (about 300 nm thick) located between the source and drain electrodes and overlying the drain metal contact line 30, protects the crossovers from shorting. A final passivating insulation layer 34 (about 10 to 300 nm thick), such as polyimide or silicon nitride, protects the device. As illustrated in Figure 2, the source metal contact lines 28 extend generally horizontally and overlie and interconnect the source electrode segments 24 (shown in Figure 1) in a comb-like structure, wherein the segments are the teeth of the comb. These source electrode segments 24 are vertically arranged in columns and, together with intermediate vertical stripes of the drain electrodes, define the individual pixels of the panel a 1 to a n through e 1 to e n (each represented as a broken line rectangle). Spacing of the source and drain elements will determine the desired resolution of the array as dictated by its use. For many diagnostic applications high resolution, such as 12 spots per mm or greater may be desirable, while for therapy applications 4 spots per mm may be perfectly adequate. It should be noted that a single pixel may be defined as extending from a single source electrode segment to the next adjacent drain electrode line, or may be defined as extending from one source electrode segment to the next horizontally adjacent source electrode segment, in which case each source electrode segment passes current to the intermediate drain electrode line. In the fabrication of the sensor array panel, most of the layers require only direct planar deposition upon the substrate with no subsequent patterning. This results in an extremely simple and inexpensive construction. The only patterning required is to form the thin film transistor array. Typical patterning steps would be: a) depositing an n + layer; b) patterning and etching the n + layer so as to form the source electrode segments 24 and the drain electrode stripes 26; c) depositing a drain metal layer; d) patterning and etching the drain metal lines 30 so that they overlie the drain electrode stripes 26; e) depositing a nitride insulation layer 32; f) patterning and etching the insulation layer so as to expose the source electrode segments while burying the drain electrode and its metallization; g) depositing the source metal layer; h) patterning and etching the source metal lines 28 so that portions thereof overlie the source electrode segments; and i) depositing the top nitride insulation layer 34. Although the illustration in Figure 1 is not to scale, it should be noted that the cumulative thickness of the several layers comprising the thin film transistors 18 is about 1 µm, or less, whereas the detector layer 16 itself may be deposited to a thickness as great as 20 µm, or more. Clearly it would be impractical, if not impossible, to define a fabrication process which requires the integration of such a thick detector and such a thin transistor side-by-side at each pixel location. The conductive layer 14 is selectively coupled to high potential source 36, on the order of 100 volts, or ground, via a switch 38. Each of the drain electrode lines 30 is connected to a suitable readout circuit (not shown) maintained close to ground potential, and each of the source electrode lines 28 is connected via a switch 40 to either a reference potential source 42, such as ground, or to a potential read-out source 44, on the order of 10 volts. In operation, in the absence of radiation, the high potential (shown having a positive sign) applied to the conductive layer 14, coupled with the matrix network (source and drain electrode lines) maintained at about ground potential, establishes an electric field across the panel 10 and, in particular, through the thick detector layer 16. The high potential is selected so that the electric field will be insufficient to turn on the transistors in the absence of radiation. As the panel is imaged by an irradiation source, such as by X-rays (indicated by arrow A) the semiconductor detector layer 16 becomes conductive by the excitation of electron/hole pairs therein. The charge carriers move through the semiconductor detector layer under the influence of the electric field, collapsing the field across the detector and establishing a much higher localized electric field across the dielectric layer 20. As indicated in Figure 1, holes will be collected at the nitride/detector interface and electrons will be collected at the conductive layer 14. The holes at the interface will not migrate laterally because the detector material is a poor conductor in the non-irradiated areas. After imaging, the switch 38 is opened and the image information remains stored as positive charges at the nitride/detector interface, which may be viewed as a floating gate because it is not electrically connected to a potential source. The floating gate potential in turn induces a negative charge, by means of electron accumulation, across the semiconductor channel 22 (as shown), thus turning the transistor ON. When a single pixel is irradiated (arrow B) the gate will extend from a single source electrode segment to the drain electrode line, whereas when two horizontally adjacent pixels are irradiated (arrow A), including a common source electrode line, the gate will extend from one source electrode segment to the other. Information readout is accomplished conventionally in a line-by-line manner, by sequentially addressing each source electrode line with the application thereto of a drive voltage (on the order of 10 volts) and simultaneously reading out the currents from all the drain electrode lines. As each source line is addressed (for example source line b), the irradiated pixel locations, having gate voltages thereon, will have active transistors, and current will flow from a single source electrode segment or two adjacent source electrode segments to and along the appropriate drain electrode line to the read-out electronics. Since the current that flows through the transistor is a very sensitive function of the gate voltage, amplified analog signals, proportional to the irradiation energy, will be transmitted to a suitable memory device and information processor. After the entire array has been read out, holes will still remain at the nitride/detector interface, and it will be necessary to remove them in order to reuse the panel. This occurs spontaneously over time because once the voltage on the conductive layer has been switched off, the separated electrons and holes across the thick detector layer will induce a field in the opposite direction and will seek to recombine. The time involved will depend upon the conductivity of the detector layer and its thickness. For an amorphous silicon detector layer about 20 µm thick, this would occur in a few seconds. However, the interface charge may be removed more rapidly by reversing the polarity of the high voltage source connected to the conductive layer and simultaneously flooding the entire panel with radiation which penetrates the photoconductor. In Figures 3 and 4 there is illustrated a modified form of detector panel wherein metal gate pads 46 are provided at each pixel location for holding the charge thereon. Additionally, a rapid charge dissipation circuit is shown in Figure 4. These gate pads 46 and the charge dissipation circuit, which includes pass transistors 48, discharge lines 50 and addressing lines 52, would be deposited between the detector layer 16 and the dielectric layer 20. The discharge lines are selectively coupled to ground via switch 54 and the addressing lines are selectively connected to a low potential source 56 (on the order of 5 volts) sufficient to turn all the pass transistors ON, via a switch 58. After imaging has been completed (with switch 54 open), both switches 54 and 58 are closed, resulting in all the pass transistors 48 being turned ON, and allowing the charge upon the gate pads to pass to ground. A constraint upon the thick detector material 16 is that it must withstand the temperature of the TFT fabrication, which for amorphous silicon is about 350° C. If the detector material cannot withstand such a temperature, then an alternative which is not part of the invention would be an inverted structure wherein tne patterned transistors layers are initially deposited upon the substrate and the thick detector layer is deposited thereon. In addition to the direct detection of radiation intensity afforded by our invention, it has another advantage over fluorescent screen devices in that there is virtually no spreading of image details. When a phosphor layer is employed as a fluoroscope screen, it emits light isotropically so that a cone of light emanates from each irradiated region This results in intrinsic blurring because the minimum lateral resolution of a spot is comparable to the thickness of the phosphor layer. Since tne sensitivity of the phosphor layer is proportional to its thickness, a balance must be struck between sensitivity of the device and resolution One method of overcoming this effect has been the fabrication of collimation structures upon or within the phosphor layer to constrain the light, but such devices are more expensive to produce. By comparison, in the present invention the gate charge (in Figure 1) is field-constrained and virtually does not spread, regardless of the detector layer thickness. Lateral diffusion of excited carriers at room temperature is given by the expression: where K is Boltzmann's constant, T is the temperature, e is the electronic charge, d is the detector layer thickness and E is the electric field, and the expression KT/e at room temperature is about 1/40. For a thickness of 100µm and high voltage potential of 100 volts, the field would be 1 volt/µm, or 10,000 volts/cm, resulting in a lateral diffusion of less than 2 µm. The equivalent lateral diffusion distance in a fluorescent screen would be about 100 µm. Another advantage of our invention is its simplicity of use in the important "subtraction" diagnostic technique for enhancing a digitally represented image. Two images are taken, separated by the introduction of a radio-opaque contrast-enhancing agent into a patient (such as the ingestion of a barium-containing fluid), in order to highlight affected regions relative to an interfering background. In conventional techniques, the two discrete images may be compared, or representative data from each image is stored, manipulated and compared. With the present invention it is possible to obtain a direct differential (subtractive) output. This may be accomplished merely by imaging the subject a first time with one polarity of the high potential source applied to the conductive layer 14, and then reimaging the subject at the opposite polarity of the high potential source. The resultant gate potential, either with or without the metal gate pads 46, automatically will represent the subtractive image, and the transistors will pass that current information directly to the readout circuit. In the art of xeroradiography a selenium plate is exposed to X-rays which have passed through an object. The selenium plate is typically comprised of about 150µm of vacuum-deposited amorphous selenium on an aluminum substrate (about 250 X 250 mm), overcoated with a thin protective polymer layer. It is usually charged to a surface potential of about 1500 volts, establishing a field thereacross. After X-ray exposure, the field collapses in the irradiated areas to form an electrostatic latent image on the plate which is subsequently made visible by being toned. A logical application for the present invention would thus be to provide electronic readout of such plates and storage of the information. This would represent a significant advance in the art of radiography. By depositing adjacent to the selenium plate a multi-layer matrix array of thin film transistors, comparable to that designated as 18 in Figure 1, coupled to readout electronics, a gray scale image is readily obtainable, as set forth above. In another form of our invention, which relies upon the detector layer developing a voltage across it in response to suitable excitation energy, the detector layer may be made of a piezoelectric material, which will develop a voltage across it when strained. If the detector layer is excited with an ultrasound image, its strained areas would develop an AC charge on the transistor gate areas which would address the transistor matrix array to generate DC signals responsive thereto because the transistors only switch ON in response to a single polarity. It should be noted that since the AC charge results in no net charge being stored on the gate areas, it is possible to obtain a readout of image information only while the input image is being maintained. In Figure 5, there is illustrated an alternative form of a sensor array panel 10′ which incorporates a piezoelectric layer 60. A rectifying layer 62, such as made from doped amorphous silicon layers, for example p-n, p-i or n-i (p-n shown), is placed between the piezoelectric layer 60 and the dielectric layer 20′, charge storage would occur and the imaging information would be held after the input was removed.

Claims: A solid state radiation-sensitive array panel (10) comprising: a substrate (12); a relatively-thick, generally planar detector layer (16) of radiation-detector semiconductor material deposited on the substrate, the material being capable of generating electron-hole pairs in response to the incidence of radiation on the layer; a relatively thin dielectric layer (20) of dielectric material deposited on the detector layer; a relatively thin charge-transport layer (22) of semiconductor material deposited on the dielectric layer; a matrix (18) of source (24) and drain (26) electrodes disposed over the surface of the charge-transport layer, the electrodes being separated from each other by an intervening body (32) of electrical insulation material, and means (36, 38) for establishing an electric bias field across the detector layer, and for forming biasing floating gates in the detector layer relative to the source and drain electrodes when the electric field collapses in the irradiated areas so as to permit current to flow between the source and drain electrodes through the charge-transport layer in areas corresponding to the irradiated areas. The panel as claimed in claim 1, in which the cumulative thickness of the matrix, the charge-transport layer, and the dielectric layer is at least an order of magnitude thinner than the thickness of the detector layer. The panel as claimed in any preceding claim, including means for reading out currents flowing between the source and drain electrodes. The panel as claimed in claim 2 or 3, in which the matrix comprises orthogonally-disposed source (28) and drain (30) lines, and in which the read-out means comprises means for sequentially energising the source lines and for detecting, one line at a time, the current flowing along the drain lines. The panel as claimed in any preceding claim, in which the biasing means comprises a planar layer (14) of conductive material disposed over the surface of the detector layer remote from the dielectric layer, and means (38) for connecting the layer to a source (36) of electric potential. The panel as claimed in any preceding claim, in which the matrix comprises orthogonally-disposed source and drain lines, and in which the source lines include the source electrodes disposed normal to the source line and parallel to the drain lines. The panel as claimed in claim 6, in which each drain line is disposed between two adjacent source electrodes, whereby a current path extends from a single source electrode to an adjacent drain line, or from two adjacent source electrodes to an intermediate drain line. The panel as claimed in any preceding claim, including an array of conductive gate pads (46) in the detector layer, each pad being associated with a source and drain electrode. The panel as claimed in claim 8, including a source of reference potential, and a conductive path connecting the gate pads to the reference source. The panel as claimed in any preceding claim, in which the detector layer comprises a photoconductive material (10). The panel as claimed in any preceding claim, including a rectifying layer (62) for allowing the panel to store on it charge representative of transient images.

Inventors: KAZAN BENJAMIN, STREET ROBERT A, KAZAN, BENJAMIN, STREET, ROBERT A.
Applicants: XEROX CORP, XEROX CORPORATION
Application year: 1990
Main classification: H01L27
IPC codes: H01L27, H01L31