Radiation shielding material with heat-transferring property

Abstract: This invention relates to a shielding material used as a radiation shield of a container containing radioactive wastes. A radiation shield with an excellent heat-transferring property is fabricated from composite particles (A) obtained by coating core particles (a) of radiation-shielding property with a metal (b) of high thermal conductivity. Composite particles are formed into a certain shape of radiation shield by hot-press forming or other forming or packed into the internal space of radioactive waste container or the shield container cavity to compose a radiation shield.

Description: FIELD OF THE INVENTION This invention relates to a radiation shield with an excellent heat-transferring property that covers a container containing radioactive wastes. Conventional shielding materials for neutrons and γ-rays, such as polyethylene and lead, generally have low thermal conductivity. When a container containing exothermic radioactive wastes is covered with these shielding materials, therefore, the heat in the container does not radiate outside and the temperature in the container rises, possibly damaging the soundness of the wastes. This has so far imposed various restrictions on the amount of wastes contained and the design of containers. Explanation is given here of examples of three kinds of known shields applied to casks for the transportation and storage of spent nuclear fuels. 1) A cylindrical container proper that contains a spent nuclear fuel assembly is externally covered with a neutron or γ-ray shield and the external surface of the shield, in turn, is covered with a shield cover. A large number of radiating fins whose ends are in contact with the external surface of the container body extend through the shield and shield cover up to the outside of the shield cover. 2) A cylindrical container body that contains a spent nuclear fuel assembly is externally covered with a neutron or γ-ray shield and the external surface of the shield, in turn, is covered with a shield cover. A large number of radiating fins whose ends are in contact with the external surface of the container body extend through the shield and shield cover up to the position of the shield cover. 3) A cylindrical container body that contains a spent nuclear fuel assembly consists of an internal cylinder and an external cylinder, and the space between the internal and external cylinders is filled with a neutron- or γ-ray-shielding material. For the radiation-shielding materials used in these examples, a powder of metal with high thermal conductivity (e.g. copper) is often contained in the shielding materials to improve their thermal conductivity, and/or the radiating fins are installed in or through the shield to enhance their heat-transferring property, as mentioned above. These techniques, however, have some problems; for example, it is difficult to uniformly distribute the metal powder in the shield; it takes much time and labor to work the radiating fins and to install them in the container body; and neutrons stream through the radiating fins. Furthermore, it is pointed out that the decontamination property (ease of removing radiation contamination) is bad in the case of radiating fins described in paragraph 1). US-A-4 253 917 discloses a thermomechanical process for manufacturing nuclear radiation shields, wherein boron carbide particles pre-encapsulated with copper (by a electroplating process) are consolidated into a unitary mass on the inner surface of a heated cylindrical substrate with or without the aid of a roller. Hereby, the size of the unprecoated boron carbide particles as the core particles should be at least 50 mesh, i.e. 0.30 mm or less. SUMMARY OF THE INVENTION Thus, the principal object of this invention is to provide a high-performance shielding material that combines the radiation-shielding function and an excellent heat-transferring property for the purpose of safely transporting and storing the exothermic radioactive wastes. This object is accomplished by providing composite particles obtained by coating core particles having radiation-shielding property with a metal coating of high thermal conductivity wherein the diameter of the core particles is 20 to 100 µm and the thickness of the metal coating is between 0.5 µm and 10 µm, and fabricating a radiation shield in a various shape from this composite particles. Included among methods of fabricating a radiation shield of excellent heat-transferring property from composite particles are, for example, a method involving forming composite particles into a wall-like body as a shield by hot-press forming (or cold-press forming), and a method involving closely packing the space between walls composing the shield body with composite particles. The core of a composite particle is made of a material selected from the group comprising polyethylene, polystyrene, polypropylene, bakelite, graphite, beryllium, oxides of beryllium, boron, compounds of boron, aluminum, oxides of aluminum, iron, ferroalloys, lead, lead alloys, gadolinium, oxides of gadolinium, cadmium, cadmium alloys, indium, indium alloys, hafnium, hafnium alloys, depleted uranium, and so on. The coating metal of high thermal conductivity is made of a material selected from the group comprising aluminum, aluminum alloys, beryllium, beryllium alloys, copper, copper alloys, iron, ferroalloys, silver, silver alloys, magnesium, magnesium alloys, molybdenum, molybdenum alloys, zinc, zinc alloys, tin, tin alloys, tungsten, tungsten alloys, iridium, iridium alloys, gold, and so on. The coating metal does not necessarily need to cover the whole surface of the core particle. It is desirable, however, to cover the whole surface in order to increase the thermal conductivity among composite particles by ensuring a large contact area of composite particles. It is recommended that the packing density of particles be 1 to 3 g/cm³, for example. According to the former method, i.e., the press forming method, composite particles are pressed to form a unit wall of appropriate size and this wall is attached to the container body. The deformation rate of composite particles, which depends on the materials used, is not very high because composite particles are minute. In a shield obtained by the press forming of composite particles or a shield obtained by packing the space between walls with composite particles, core particles shield radiations, such as neutrons and γ-rays, emitted from exothermic radioactive wastes. On the other hand, the heat released from the radioactive waste in the container is transmitted through the container wall to the coating metal of composite particles which are in close contact with one another, and is released through this coating metal of high thermal conductivity to the external environment that surrounds the radioactive waste container. In other words, the radioactive shield on the basis of this invention is a high-performance shield that combines the radiation-shielding function and an excellent heat-transferring property. These and other features of this invention will become apparent from the description of the following embodiments with reference to the accompanying drawings. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a sectional view of a composite particle A; Figure 2 and Figure 3 are sectional views showing two examples in which the composite particle A is applied to a neutron and γ-ray shield of a cask for transporting and storing spent nuclear fuels. DESCRIPTION OF THE PREFERRED EMBODIMENT In this invention, composite particles A are used as the material for a shield that is required to provide the heat release function; they are obtained by coating core particles with an excellent radiation-shielding property of organic or inorganic materials, various kind of metals, and so on. The core particles are about 20 to 100 µm in diameter and a thickness of the coating metal with high thermal conductivity is between 0.5 and 10 µm, as shown in Figure 1. Methods of applying the composite particles A to a radiation shield include a) a method that involves filling a shield container of prescribed shape with composite particles A, b) a method that involves fabricating a shield by closely packing the space in a container containing radioactive wastes, and c) a method that involves forming composite particles A into a prescribed shape by hot-press forming (press forming at elevated temperature) or other forming processes. Using these methods makes it possible to provide an excellent radiation shield with excellent heat-transferring property for a container containing exothermic radioactive wastes. The two examples in which these methods are applied to a cask for transporting and storing spent nuclear fuels are described in the following with reference to Figures 2 and 3. Figure 2 is a sectional view of the cask in which the cylindrical cask body 2 contains the spent nuclear fuel assemblies 1. The container body 2 is covered with a neutron shield 9 made of composite particles A according to this invention and this neutron shield is surrounded by neutron shield cover 4. In the example shown in Figure 3, a neutron and gamma (γ) ray shield 10 composed of composite particles A is formed on the basis of this invention between an internal cylinder 6 and an external cylinder 8 of the cask body. In these shields, coated core particles a have the function of shielding radiations, such as neutron and gamma (γ) rays, and the coating metal b has the function of heat transfer and heat release; thus composite particles A serve as a shielding material with the function of heat transfer and heat release. Concerning combinations of a core particle a and a coating metal b that compose a composite particle A, materials as shown below are selected depending on the service conditions. Materials for the core particle a include: polyethylene, polystyrene, polypropylene, bakelite, graphite, beryllium, oxides of beryllium, boron, compounds of boron, aluminum, oxides of aluminum, iron, ferroalloys, lead, lead alloys, gadolinium, oxides of gadolinium, cadmium, cadmium alloys, indium, indium alloys, hafnium, hafnium alloys, depleted uranium, and so on. Materials for the coating metal b include: aluminum, aluminum alloys, beryllium, beryllium alloys, copper, copper alloys, iron, ferroalloys, silver, silver alloys, magnesium, magnesium alloys, molybdenum, molybdenum alloys, zinc, zinc alloys, tin, tin alloys, tungsten, tungsten alloys, iridium, iridium alloys, gold, and so on. Examples of typical combination of these materials for composite particles A and particle sizes are shown in the following. Incidentally, particles are coated according to the electroplating process, spattering process, and so on. 1) In the case of neutron shielding materials: Polyethylene (including superhigh-molecular polyethylene) or boron carbide (B₄C) is used for core particles a , and copper or aluminum is used for the coating metal b . 2) In the case of gamma-ray-shielding materials: Lead or depleted uranium is used for core particles a , and copper or depleted uranium is used for the coating metal b . 3) In terms of the balance between the shielding performance and the heat release function, diameters of core particle a are 20 to 100 µm and thicknesses of coating metal b are about 0.5 to 10 µm. The composite particles in accordance with this invention can also be applied to the neutron-shielding and blanket material of nuclear fusion reactors, neutron absorber for nuclear criticality safety control or neutron reflector of reactors in addition to the above application. To sum up this invention, composite particles obtained by coating particles of a substance having an excellent radiation-shielding property with a metal of high thermal conductivity are used as a radiation-shielding material with an excellent heat-transferring property. As a result, it has become possible to obtain a high-performance shielding material that combines the radiation-shielding performance and an excellent heat-transferring property. As will be apparent from the above, it has become possible to save the time and labor hitherto required for installing radiating fins in a shield and to obtain an excellent radioactive-substance-shielding material of good decontamination property without the problem of neutron streaming from the fins. In addition, it has become possible to eliminate the difficulty which has so far been encountered in uniformly mixing metal powder of high thermal conductivity into a shield and to achieve the high thermal conductivity which has not so far been obtained.

Claims: A radiation-shielding material which is made of composite particles consisting of a.) a core particle having radiation shielding property made of at least one material selected from polyethylene, polystyrene, polypropylene, bakelite, graphite, beryllium, oxides of beryllium, boron, compounds of boron, aluminum, oxides of aluminum, iron, ferroalloys, lead, lead alloys, gadolinium, oxides of gadolinium, cadmium, cadmium alloys, indium, indium alloys, hafnium, hafnium alloys or depleted uranium and of b.) a metal coating of high thermal conductivity made of at least one material selected from aluminum, aluminum alloys, beryllium, beryllium alloys, copper, copper alloys, iron, ferroalloys, silver, silver alloys, magnesium, magnesium alloys, molybdenum, molybdenum alloys, zinc, zinc alloys, tin, tin alloys, tungsten, tungsten alloys, iridium, iridium alloys and gold, wherein the diameter of the core particles is 20 to 100 µm and the thickness of the metal coating is between 0.5 and 10 µm. A radiation-shielding material as claimed in Claim 1, wherein the typical packing or forming density of the composite particles is in the range from 1 to 3 g/cm³. A radiation-shield containing a material as claimed in Claims 1 or 2. A radiation-shield of claim 3, wherein said composite particles are formed into a certain shape by a forming process. A radiation-shield of claim 4, wherein said forming process is a hot-press forming process. A radiation-shield according to claims 3 to 5, which is formed of composite particles of the same kind. A radiation-shield according to claims 3 to 5, which is formed of composite particles of a different kind. A radiation-shield according to claims 3 to 7, wherein said composite particles are packed within the internal space of a radioactive waste container or shield container cavity. Use of a radiation-shielding material or radiation-shield according to any one of claims 1 to 8 for safely transporting and storing exothermic radioactive wastes.

Inventors: ASANO NORIO ITOPIA GOTANDA -, HOZUMI MASAHIRO, TAKATSU KIYOSHI, TAKESHIMA EIKI, ASANO, NORIO ITOPIA GOTANDA 404, 10-14, HOZUMI, MASAHIRO, TAKATSU, KIYOSHI, TAKESHIMA, EIKI
Applicants: NISSHIN STEEL CO LTD, SUMITOMO HEAVY INDUSTRIES, NISSHIN STEEL CO., LTD., SUMITOMO HEAVY INDUSTRIES, LTD
Application year: 1990
Main classification: G21F3
IPC codes: G21F5, G21F1, G21F3