Synchrotron radiation utilizing apparatus and method for utilizing synchrotron radiation

Abstract: A synchrotron radiation utilizing apparatus comprises a generator generating synchrotron radiation (4), a guide duct (5) for outwardly guiding the synchrotron radiation in a predetermined direction, a plurality of supporting members (13) each supporting one of a plurality of objects (9) which are targets to be irradiated with the synchrotron radiation, the supporting members being disposed at positions, distant substantially by an equal distance from the center of rotation of the apparatus, a support base (11) rotatably supporting the supporting members, a first rotating unit (29) rotating each of the supporting members in a predetermined direction, a first control unit (27, 26) applying a control signal to the first rotating unit, a second rotating unit (28) rotating the support base in the plane of the support base in a direction opposite to the direction of rotation of the object supporting members, and a second control unit (25, 26) applying a control signal to the second rotating unit.

Description: The invention relates to a synchrotron radiation utilizing apparatus and method according to the preambles of the independent claims. Such an apparatus and such a method are known from the Journal of Applied Physics, Vol. 47, No. 12, December 1976, pages 5450 and following: "Application of synchrotron radiation to x-ray lithography" by E. Spiller et al. More particularly, the invention relates to an apparatus and a method as described above in which synchrotron radiation is utilized for the purpose of, for example, SOR lithography for manufacturing semiconductor devices. Synchrotron radiation emitted from high energy electrons (charged particles) circulating in a beam duct of a synchrotron radiation generator (an electron accumulator ring) contains soft X-rays which have a wavelength as short as about 10⁻⁹ m (10 Å) having good directivity and which have a high beam intensity. Therefore, the synchrotron radiation is noted as, for example, a lithography light source for manufacturing ultra LSI's of the next generation, and researches and studies for providing a synchrotron radiation generator apparatus of a small size are now being made. Apparatuses of this kind are disclosed in, for example, JP-A-63-175400 and JP-A-63-202900. An X-ray exposure apparatus utilizing synchrotron radiation is disclosed in JP-A-62-291027. In this apparatus, synchrotron radiation radiated in an orbital plane is reflected to the outside of the orbital plane by the use of an oscillating reflection mirror thereby attaining the desired purpose of scanning. On the other hand, an ion beam lithography apparatus disclosed in JP-A-62-5548 is known as an apparatus in which a wafer to be processed is revolved around the central axis of the apparatus while rotating around its own axis. The ion beam used in the known ion beam lithography apparatus is converged to meet the size of the wafer and is devoid of beam uniformity. In this known apparatus, the wafer is merely rotated around its own axis regardless of the period of its revolution around the central axis of the apparatus so that the entire wafer can be uniformly exposed to the ion beam. In the prior art apparatus disclosed in JP-A-62-291027 cited above, a distance of about 5 m is required for reflecting and magnifying the soft X-rays, resulting in a large size of the apparatus. Further, because the synchrotron radiation is reflected by the reflecting mirror, the synchrotron radiation tends to be attenuated, resulting in an inevitable decrease in the quantity of the radiation that can be used for the exposure. Also, in the prior art apparatus disclosed in JP-A-62-5548 cited above, it is only necessary to merely rotate the wafer around its own axis because the beam used for the lithography is the ion beam. The synchrotron radiation differs from the ion beam in that it is converged into a very small diameter. Thus, when the synchrotron radiation is used in lieu of the ion beam, it is necessary to very precisely scan the wafer for the purpose of uniform exposure. The article "Application of synchrotron radiation to x-ray lithography" by E. Spiller et al. in Journal of Applied Physics, Vol. 47, No. 12, December 1976, pages 5450 and following discloses an experimental arrangement for using synchrotron radiation. It comprises a sample chamber in which a plurality of wafers are disposed on a sample holder wheel. This wheel may be turned around its axis so that various wafers are subsequently exposed to the synchrotron radiation. GB-A- 2 191 335 discloses a substrate support structure for an ion implantation device. It comprises a plurality of substrate holders supporting sample substrates wherein each sample substrate can be rotated around an axis perpendicular to its main surface and the angle of inclination of the main surface with respect to ion beams can be changed. In addition, a larger disk rotatably supports the substrate holders on the same circumference with the center at its rotary axis. With a view to solve the various prior art problems, it is an object of the present invention to provide a synchrotron radiation utilizing apparatus utilizing synchrotron radiation for uniform exposure of objects, in which a large area can be scanned without attenuation of the synchrotron radiation, so that the objects can be uniformly irradiated with the synchrotron radiation. This object is solved in accordance with the features of the independent claims. Dependent claims are directed on preferred embodiments of the invention. A plurality of objects which are targets to be irradiated with synchrotron radiation are mounted on a rotary support base having a perpendicular shaft in such a relation that the objects are arranged in equally spaced relation along an imaginary circle drawn around the shaft, and the synchrotron radiation is directed toward the objects while rotating the support base. That is, according to one aspect of the present invention, there is provided a synchrotron radiation utilizing apparatus comprising means for generating synchrotron radiation, means for guiding the synchrotron radiation generated from the synchrotron radiation generating means in a predetermined direction, a plurality of supporting members each supporting one of a plurality of objects which are targets to be irradiated with the synchrotron radiation, the supporting members being disposed at positions distant substantially by an equal distance from the center of rotation of the apparatus, a support base rotatably supporting the object supporting members, first rotating means for rotating each of the object supporting members in a predetermined direction, first control means for applying a control signal to the first rotating means, second rotating means for rotating the support base in the plane of the support base in a direction opposite to the direction of rotation of the object supporting members, and second control means for applying a control signal to the second rotating means. Suppose the case where the plural supporting members supporting the objects (for example, wafers of silicon, gallium arsenide, etc.) which are the targets to be irradiated with the synchrotron radiation are mounted on the support base having the perpendicular shaft in such a relation that the supporting members are arranged in equally spaced relation on an imaginary circle drawn around the shaft, and the synchrotron radiation is directed toward the objects while rotating both the support base and the supporting members. The radiation intensity distribution in the above case will now be discussed. When each of the supporting members is rotated at an angular velocity ω, the rotation velocity at a point spaced by a distance γ from the center of the support base is expressed as γω. The spot of the synchrotron radiation on each of the objects lies on a line, and the synchrotron radiation sweeps the object with the rotation of the supporting member. However, as described above, the rotation velocity of the object increases in proportion to the distance from the rotary shaft of the support base. This means that the quantity of the synchrotron radiation irradiating a unit area of the object per unit time decreases in inverse proportion to the distance from the rotary shaft of the support base. Thus, in the exposure apparatus having the above arrangement, such an undesirable non-uniform radiation intensity distribution results in which the intensity distribution is high at a radially inner area of the object but low at a radially outer area of the object. In the present invention which obviates such a disadvantage, means are provided so that the plural objects can be rotated at the angular velocity ω independently of each other in a direction opposite to the direction of rotation of the support base, so that the composite angular velocity becomes zero. Therefore, when the surface of the object is looked from the position of an observer who stands still (for example, the operator of the exposure apparatus), the spot of the synchrotron radiation makes substantially parallel movement on the surface of the object, so that the aforementioned problem of the non-uniform radiation intensity distribution attributable to the difference between the rotation velocities can be avoided. The synchrotron radiation utilizing apparatus, especially the objects are preferably maintained in an atmosphere of a reduced pressure. When the plural objects are maintained in such an atmosphere, the objects can be efficiently exposed to the synchrotron radiation within a short period of time, and a very fine circuit pattern can be uniformly formed on the object, so that the productivity of semiconductor devices can be greatly improved. Applicable fields of the present invention include, besides that described above, analysis of trace elements or microelements using light absorption, determination of the arrangement of atoms of non-crystalline substances by measurement of spectral fine structures near absorption edges of an X-ray region, observation of lattice defects on the basis of diffraction spot images, analysis of the structure of macromolecules based on the small angle scattering method utilizing the parallelism of synchrotron orbital radiation (SOR), and measurement of distances between component atoms in alloys by the anomalous scattering method. Fig. 1 shows schematically the general structure of an embodiment of the synchrotron radiation utilizing apparatus according to the present invention. Fig. 2 is a schematic plane view of the apparatus to show how the objects to be exposed to the synchrotron radiation are mounted on the supporting members which are rotatable around their own axes respectively and are supported on the support base which is rotatable around its control axis. Fig. 3 is a schematic side elevational view of another embodiment of the present invention in which object mounting jigs, each of which is formed by object supporting members and a support base, are supported on a frusto-conical block whose rotary shaft does not extend in parallel to the direction of synchrotron radiation. Fig. 4 is a partly sectional, schematic side elevational view of the object mounting jig shown in Fig. 3 to illustrate how the support base and object supporting members tend to incline due clearances between their rotary shafts and bearings in which the shafts are journalled. Fig. 5 is a schematic plan view of still another embodiment of the present invention in which object mounting zigs, each of which is formed by object supporting members and a support base, are mounted on a large-diameter disc so as to be rotatable around the central axis of the disc. Fig. 1 shows a first embodiment of the synchrotron radiation utilizing apparatus according to the present invention. Referring to Fig. 1, synchrotron radiation 4 emitted from an electron beam 2 circulating at a high velocity in an electron accumulation ring 8 of a synchrotron radiation generator (not shown) is radiated in a direction tangential with respect to the orbit of the electron beam 2. The synchrotron radiation 4 is guided by a beam duct 5 whose end is closed so as to maintain a vacuum thereinside. The synchrotron radiation guided through the beam duct 5 penetrates a window (made of a metal, for example, Be) provided at the closed end of the beam duct 5. Objects 9 which are targets to be exposed to the radiated synchrotron radiation 4 are fixedly mounted on supporting members 13 respectively, and these object supporting members 13 are disposed so as to be rotatable relative to a support base 11 supporting the object supporting members 13. Each of the object supporting members 13 is provided with an integral rotary shaft 14, and the support base 11 is combined with an integral rotary body 10 which is provided with an integral rotary shaft 12. In the apparatus having the structure described above, the rotary body 10 is rotated by rotation of the rotary shaft 12, so that the objects 9 can be moved in a direction of 90° relative to the electron orbital plane while maintaining such an angular relation. Therefore, when the rotation velocity of the rotary body 10 is suitably selected, the synchrotron radiation 4 can be directed toward the entire surface of each of the objects 9 in a quantity suitable for exposure. Thus, the apparatus is suitable for semiconductor lithography in which accurate circuit patterning through a mask over a wide area of the objects 9 is especially required. A rotation angle sensor 25 is associated with the rotary shaft 12, and its detection output signal is transmitted to means 26, for example a controlled power supply unit. A rotation angle sensor 27 is also associated with each of the rotary shafts 14, and its detection output signal is also transmitted to the controlled power supply unit 26. A rotation drive unit 28 is provided for the rotary shaft 12, and a rotation drive unit 29 is also provided for each of the rotary shafts 14. Controlled power is supplied from the controlled power supply unit 26 to the drive control units 28 and 29 so as to rotate the rotary shafts 12 and 14 at required angular velocities respectively. For example, the rotation drive units 28 and 29 are stepping motors, and the controlled power supply unit 26 supplies controlled power in pulse form. The operation of the drive units 28 and 29 is such that the rotary shafts 12 and 14 are rotated in directions opposite to each other at the same angular velocity. Thus, the object supporting members 13 do not rotate in the horizontal plane but merely make parallel movement in the horizontal plane. On the other hand, the synchrotron radiation 4 is directed to scan the objects 9 at a predetermined angle with respect to the horizontal plane (commonly in a relation parallel to the foundation). Therefore, the objects 9 fixedly mounted on the respective supporting members 13 are uniformly exposed to the synchrotron radiation 4. Fig. 2 shows that the objects 9 to be exposed to the synchrotron radiation 4 are fixedly mounted on the supporting members 13 combined with their rotary shafts 14 respectively. In Fig. 2, the supporting members 13 fixedly mounting the respective objects 9 thereon are thus revolvable relative to the support base 11. Because the object supporting members 13 revolve around the rotary shaft 12 of the support base 11, and the peripheral velocity of the area of the object supporting members 13 remote from the rotary shaft 12 of the support base 11 differs from that of the area near the shaft 12, the area of each of the objects 9 located near the shaft 12 is exposed to a greater quantity of the synchrotron radiation 4 than that of the area located remote from the shaft 12. For example, in the case of semiconductor lithography, the diameter of each object/water 9 is about 10 cm. Therefore, when the distance between the shaft 12 of the support base 11 and the center of each supporting member 13 supporting the wafer 9 is 25 cm, the velocity difference on the wafer 9 is calculated to be 33% at a maximum, as follows: The rotation velocity at a point on the wafer 9 is proportional to the distance between that point and the shaft 12 of the support base 11. Thus, the velocity difference between two points remotest from and nearest to the shaft 12 is expressed as follows: 1 - (25 - 10/2)/(25 + 10/2) = 0.33 However, when, in the arrangement shown in Fig. 2, the object 9 is rotated in one direction around the shaft 14 through the same angle as that of the revolution in the other direction around the shaft 12, the same angle is maintained between an imaginary line 15 drawn on the object 9 and the orbital plane of the electrons. Because the rotation velocity of the object 9 is maintained constant, the exposure quantity of the synchrotron radiation 4 on the object 9 can be maintained constant regardless of the position and time. Further, the synchrotron radiation 4 is very finely converged so that it can accurately scan all over the wafer 9 to ensure uniform exposure. Therefore, while revolving the wafer supporting member 13 around the shaft 12 of the support base 11, the wafer supporting member 13 is rotated around its own shaft 14 in a direction opposite to the revolving direction and at the same angular velocity as that in the revolving movement, so that undesirable non-uniform exposure may not result from the tangential velocity difference between the radially inner and outer areas of the wafer 9 due to the revolution of the wafer supporting member 13 around the shaft 12 of the support base 11. Fig. 3 shows a second embodiment of the present invention, and in Fig. 3, like reference numerals are used to designate like parts appearing in Fig. 1. Referring to Fig. 3, a support block 19 in the form of a frustum of a right cone is mounted at its central axis on a rotary shaft 17. A plurality of object mounting jigs 18 each including a support base 11 and a rotary shaft 12 are perpendicularly mounted on the side surface of the frusto-conical support block 19, and each of the object mounting jigs 18 is rotatable around the axis of the rotary shaft 12. In the apparatus shown in Fig. 3, the combination of the support block 19 and the rotary shaft 12 acts to successively feed the object mounting jigs 18 to a predetermined exposure position, and, when each object mounting jig 18 is fed to the predetermined exposure position, the jig 18 is rotated around the axis of the rotary shaft 12, so that objects 9 can be successively exposed to synchrotron radiation 4. In this case, objects 9 mounted on any one of the object mounting jigs 18 not located at the predetermined exposure position can be replaced as desired. In the apparatus shown in Fig. 3, the side surface of the support block 19 mounted on the rotary shaft 17 is inclined relative to the direction of the synchrotron radiation 4 by an angle equal to the vertical angle of the cone. Therefore, the rotary shaft 17 need not be disposed in parallel to a beam duct 5, and this is desirable from the viewpoint of design in that there is an increased freedom for the layout of the exposure apparatus. Fig. 4 is a partly sectional, side elevational view of the support base 11 shown in Fig. 3 to illustrate how the support base 11 and object supporting members 13 are mounted on their rotary shafts. Referring to Fig. 4, the rotary shaft 12 supporting the support base 11 is rotatably journalled in two bearings 22 and 23, while each of the rotary shafts 14 supporting the object supporting members 13 is rotatably journalled in two bearings 20 and 21. When each of the bearings 20, 21, 22 and 23 has the same clearance of 12.5 µm between it and the associated shaft, and the distance between the bearings 20 and 21 and that between the bearings 22 and 23 are more than 10 cm, the ratio between the clearance of the bearings and the distance between the bearings is given by less than 1/8000. A paper (reported in Applied Physics, Vol. 53, No. 1, 1984, pp. 17-25) describes that, in the case of lithography in which the line width is 0.5 µm, and the spacing between masks and wafers is 20 µm, the dimensional error is to be less than 0.01 µm. when the ratio between the clearance of the bearings and the distance between the bearings is 1/8000 as described above, a maximum inclination of 1/4000 = 2.5 x 10⁻⁶ radians is caused due to the clearances of the left and right two bearings. This angle produces, together with the spacing of 20 µm between the masks and the wafers, an error which is calculated as 20 µm x 2.5 x 10⁻⁶ = 0.005 µm. This error may be 0.005 x 2 = 0.01 µm even when all the clearances of the bearings 20, 21, 22 and 23 are combined. The ratio between the clearance of the bearings and the distance between the bearings can be decreased to less than 1/8000 by employing, for example, angular ball bearings and selecting the distance between the bearings to be more than 10 cm. In this case, the clearance of the angular ball bearings is to be selected to be less than 12.5 µm. In the synchrotron radiation utilizing apparatus of the present invention, the rotary shafts are expected to be rotated at a very low speed lower than one revolution per minute. Therefore, the clearance of the angular ball bearings can be easily set at a value less than 12.5 µm. Even when the clearance of the angular ball bearings cannot be set to be less than 12.5 µm, the distance between the bearings can be easily set at a value more than 10 cm. Displacement of the objects 9 caused by the clearance of the bearings may be parallel movement, besides that attributable to the inclination described above. However, such parallel movement will hardly occur in view of the very low rotation speed of the rotary shafts in the apparatus. Even when such parallel movement may occur, it does not pose any practical problem. This is because light emitted from a point light source disposed distant by 5 m from an object makes a very small angle of 12.5 x 10⁻⁶/5 = 2.5 x 10⁻⁶ radians with the object making parallel movement of 12.5 µm = 12.5 x 10⁻⁶ m. Fig. 5 shows a third embodiment of the present invention, and, in Fig. 5, like reference numerals are used to designate like parts appearing in Figs. 1 and 3. Referring to Fig. 5, a large-diameter support disc 16 is mounted on a rotary shaft 17 at its central axis. A plurality of object mounting jigs 18 each including a support base 11 and a rotary shaft 10 are mounted on the support disc 16, so that each object mounting jig 18 is rotatable around the axis of the rotary shaft 12 relative to the support disc 16. In the apparatus shown in Fig. 5, the combination of the support disc 16 and the rotary shaft 17 acts to successively feed the object mounting jigs 18 to a predetermined exposure position, and, when each object mounting jig 18 is fed to the predetermined position, the jig 18 is rotated around the axis of the rotary shaft 12, so that objects 9 can be successively exposed to synchrotron radiation. In this case, objects 9 mounted on any one of the object mounting jigs 18 not located at the predetermined exposure position can be replaced as desired. Therefore, the desired replacement operation can be continued without discontinuing the exposure of the objects. It will be understood from the foregoing detailed description of the present invention that a plurality of objects can be efficiently exposed to synchrotron radiation within a short period of time, and a very fine circuit pattern can be uniformly formed on the objects, so that the productivity of semiconductor devices can be greatly improved.

Claims: A synchrotron radiation utilizing apparatus comprising means for generating synchrotron radiation (4); means (5) for outwardly guiding said synchrotron radiation generated from said synchrotron radiation generating means in a predetermined direction, a plurality of supporting members (13) each supporting one of a plurality of objects (9) which are targets to be irradiated with said synchrotron radiation, said supporting members being disposed at positions distant substantially by an equal distance from the center of rotation of said apparatus, a support base (11) supporting said object supporting members, and first rotating means (28) for rotating said support base (11), characterized in further comprising second rotating means (29) for rotating each of the rotatable object supporting members (13) in a predetermined direction in a rotation plane parallel to that of the support base (11), and means (26) for applying a control signal to said first and second rotating means (28, 29) such that they turn in opposite directions with the same angular velocity. An apparatus according to claim 1, characterized in further comprising: first rotation angle sensor means (25) for detecting the rotation of said support base (11), second rotation angle sensor means (27) for detecting the rotation of each of said object supporting members (13), wherein said means (26) for applying a control signal to said first and second rotating means (28, 29) does so on the basis of the detection output signal from said rotation angle sensor means (25, 27). An apparatus according to claim 1 or 2, characterized in that a plurality of object mounting jigs (18) each including the combination of said support base (11) and said object supporting members (13) are mounted on the side surface of a block (19) in the form of a frustum of a right cone mounted on a rotary shaft (17), and each of said object mounting jigs is rotatable around a shaft (10) extending in perpendicular relation to the side surface of said block. An apparatus according to claim 3, characterized in that said rotary shaft (10) of said support base (11) and said rotary shaft (14) of each of said object supporting members (13) are rotatably journalled in two bearings (22, 23) and two bearings (20, 21) respectively, and the ratio of the clearance between said rotary shaft and said bearing to the distance between said two bearings is selected to be less than 1/8000. A method for utilizing synchrotron radiation comprising the steps of outwardly guiding synchrotron radiation (4) generated from synchrotron radiation generating means in a predetermined direction, supporting a plurality of objects (9), which are targets to be irradiated with said synchrotron radiation, on a plurality of supporting members (13), said supporting members being supported on a support base (11) and disposed at positions distant substantially by an equal distance from the center of rotation of the support base, and rotating the support base (11), characterized in further comprising the step of - rotating each of the object supporting members in a rotation plane parallel to that of the support base in a direction opposite to that of the support base with the same angular velocity.

Inventors: KITAMURA MASASHI, KOBAYASHI TAKASHI, MAKI NAOKI, YAMAGUCHI KIYOSHI, KITAMURA, MASASHI, KOBAYASHI, TAKASHI, MAKI, NAOKI, YAMAGUCHI, KIYOSHI
Applicants: HITACHI LTD, HITACHI, LTD.
Application year: 1990
Main classification: G21K5
IPC codes: H01L21, H05H13, G03F7, G21K5