PACKING

Abstract: This invention relates to a packing for sealing the joint between members. Expansive graphite (41) is bonded integrally to at least one of the surfaces of a plurality of reinforcing fiber yarns (40) disposed in a longitudinal direction by an adhesive to constitute knitted yarns (4) having high sealability, high tensile strength and high toughness. A plurality of such yarns (4) are bundled to form a core (2) and the outer periphery of the core (2) is covered with a knit assembly (3) of the knitted yarns (2), a plurality of knitted yarns (2) are bundled and knitted (square knitting), or a plurality of knitted yarns (2) are bundled and twist knitted so as to obtain a packing of a free length. Since this packing can be used by cutting in to a required length on site in accordance with the dimension of the member, it is no longer necessary to produce, based on a forecast, a variety of annular packings in accordance with the dimensions of members, unlike in the case of preformed packings.

Description: Technical Field The present invention relates to packing suitably used as gland packing to be used at a shaft sealing portion in a fluid apparatus. Background Art As the material of gland packing used at, for example, a shaft sealing portion in a fluid apparatus or the like, there is known a material using, as its base material, expanded graphite excellent in compression-restoring force and sealing properties. Gland packing of such material is made by a compression molding method of the laminate type, the die molding type, the tip molding type, the ribbon pack type or the like. Such gland packing should be previously made in the form of a ring having an inner diameter corresponding to the outer diameter of a shaft to be sealed. Accordingly, the gland packing cannot be used for a shaft of which outer diameter is not fit for the inner diameter of the ring-like packing. Thus, such packing lacks versatility. Further, the expanded graphite itself is poor in tensile strength and therefore fragil. This makes it difficult to take out, for replacement, such gland packing which has been mounted on a stuffing box or the like. Thus, the gland packing presents a problem in view of practical utility. In addition, the respective types of the compression molding present the following problems. In the laminate-type, the yield is low, leading to increase in production cost. In the die molding type and the tip molding type, gland packing is molded with the use of molds, causing the production cost to be increased. Further, such gland packing lacks versatility. The ribbon pack type presents poor workability. The problems above-mentioned may be solved by making the expanded graphite in the form of a string, so that the string-like expanded graphite may be used as cut into a predetermined length according to the diameter of a shaft to be sealed, likewise braided packing. However, the expanded graphite itself is apparently caterpillar-like particles, each of which is expanded in the direction of the C-axis of the crystal of a graphite particle. These caterpillar-like particles as agglomerated may be compression-molded into a sheet. However, the expanded graphite even made in such a sheet, is poor in tensile strength and therefore fragile. Accordingly, such a sheet cannot be cut into yarn with the use of which a braided body is to be made. It is therefore not possible to apply such expanded graphite to packing which may be used as cut to a predetermined length according to the diameter of a shaft to be sealed and wound around the outer periphery thereof, likewise braided packing. Disclosure of Invention In view of the background art above-mentioned, the present invention is proposed with the object of providing packing in the form of a string improved in practical utility and versatility. After hard study of the arrangement of a knitting yarn using expanded graphite, the inventor has found a way to make a knitting yarn of expanded graphite by bonding expanded graphite to a reinforcing fiber yarn with adhesives, so that the synergistic action of the reinforcing fiber yarn and the expanded graphite gives, to the resultant knitting yarn, a great compression-restoring force, excellent sealing properties, and strong tensile strength and toughness. A plurality of such knitting yarns may be put together to form a core member and the core member may be then covered, at the outer periphery thereof, with a braided body of the knitting yarns, thereby to make the assembly in the form of a string. A plurality of such knitting yarns as put together may be braided in the form of a string. A plurality of such knitting yarns as put together may be twisted in the form of a string. According to the packing of the present invention, the strong tensile strength and toughness of the reinforcing fiber yarns are given to the knitting yarns. Thus, the knitting yarns may be braided or twisted without the yarns cut. It is therefore possible to form a string-like packing in which the core member made of the knitting yarns is covered, at the outer periphery thereof, with a braided body of the knitting yarns. Further, the great compression-restoring force and excellent sealing properties of the expanded graphite are given to the core member and the braided body, thus assuring such sealing properties as inevitably required for packing. Further, a plurality of such knitting yarns provided with strong tensile strength and toughness may be put together and braided. It is therefore possible to form a braided body (as square-knitted) having strong tensile strength and toughness. The great compression-restoring force and excellent sealing properties of the expanded graphite are given to the braided body, thus assuring such sealing properties as inevitably required for packing. Further, a plurality of such knitting yarns having strong tensile strength and toughness may be put together and twisted. It is therefore possible to form a twisted string-like member having such strong tensile strength and toughness. In addition, the great compression-restoring force and excellent sealing properties of the expanded graphite are given to this string-like member, thus assuring such sealing properties as inevitably required for packing. Brief Description of Drawings Figure 1 is a perspective view, with portions broken away, of a first embodiment of packing in accordance with the invention; Figure 2 is a perspective view, with portions broken away, of an example of a knitting yarn; Figure 3 is a perspective view of a second embodiment of packing in accordance with the invention; Figure 4 is a perspective view of a third embodiment of packing in accordance with the invention; Figure 5 is a perspective view of another example of the knitting yarn; Figures 6 to 10 are views of various examples of a reinforcing fiber yarn; and Figures 11A, 11B and Figures 12A, 12B are views illustrating variations of the distances between knitting yarns fed from bobbins and a knitting point in circular knitting and square knitting, respectively. Best Mode for Carrying Out the Invention Fig. 1 is a perspective view, with portions broken away, of a first embodiment of packing in accordance with the invention. In Fig. 1, packing 1 comprises a core member 2 and a braided body 3 covering the outer periphery of the core member 2, the braided body 3 being made by, for example, circular-knitting. The core member 2 is formed by longitudinally arranging a plurality of knitting yarns 4 as put together. The braided body 3 is formed by circular-knitting the knitting yarns 4. As shown in Fig. 2, each knitting yarn 4 comprises a plurality of longitudinally arranged reinforcing fiber yarns 40 made of, for example, cotton, and caterpillar-like expanded graphite 41 integrally bonded to both surfaces of the yarns 40 with adhesives (for example, acrylic ester) (not shown). The cotton yarns used as the reinforcing fiber yarns 40 have, on the surfaces thereof, an infinite number of extremely short and fine fibers, i.e., so-called fuzz. This improves the adhesion of the adhesives. Accordingly, the reinforcing fiber yarns 40 and the expanded graphite 41 are securely bonded to each other to prevent the expanded graphite 41 from partially falling from the reinforcing fiber yarns 40. Thus, the knitting yarns 4 are formed by integrally bonding, with adhesives, the expanded graphite 41 to both surfaces of a plurality of longitudinally arranged reinforcing fiber yarns 40 made of, for example, cotton. The strong tensile strength and toughness of the reinforcing fiber yarns 40 are given to the knitting yarns 4. Accordingly, the knitting yarns 4 may be braided without the yarns 4 cut. It is therefore possible to form a string-like member 5 in which the outer periphery of the core member 2 made of the knitting yarns 4 is covered with the braided body 3 as obtained by circular-knitting the knitting yarns 4. This string-like member 5 has characteristics excellent in tensile strength and toughness. Thus, this string-like member 5 may be used, as the packing 1, as cut to a predetermined length according to, for example, the diameter of a shaft to be sealed. This improves the packing 1 in versatility and practical utility. Further, the great compression-restoring force and excellent sealing properties of the expanded graphite 41 are given to the core member 2 and the braided body 3 forming the packing 1. It is therefore assured that the packing 1 is provided with such excellent sealing properties as inevitably required for packing. Fig. 3 is a perspective view of a second embodiment of packing in accordance with the invention. In Fig. 3, like parts are designated by like numerals used in Fig. 1 and the detailed description of such like parts is here omitted. In Fig. 3, packing 1 is made in the form of a string-like member 5 made of a braided body 3A as obtained by square-braiding eight knitting yarns 4. The strong tensile strength and toughness of reinforcing fiber yarns 40 are given to the knitting yarns 4. Accordingly, the knitting yarns 4 may be braided (as square-knitted) without the yarns 4 cut. Thus, the string-like member 5 may be made of the braided body 3A having characteristics excellent in tensile strength and toughness. It is therefore possible to use, as the packing 1, this string-like member 5 as cut to a predetermined length according to, for example, the diameter of a shaft. This improves the packing 1 in versatility and practical utility. Further, the strong compression-restoring force and excellent sealing properties of the expanded graphite 41 are given to the braided body 3A forming the packing 1. Accordingly, the packing 1 may be provided with such sealing properties as indispensably required for packing. Fig. 4 is a perspective view of a third embodiment of packing in accordance with the invention. In Fig. 4, like parts are designated by like numerals used in Fig. 1 and the detailed description of such like parts is here omitted. In Fig. 4, packing 1 is made in the form of a string-like member 5 by roll-molding six knitting yarns 4 as bound while these knitting yarns 4 are being twisted 20 times/m. The strong tensile strength and toughness of the reinforcing fiber yarns 40 are given to the knitting yarns 4. Accordingly, the knitting yarns 4 may be twisted without the yarns 4 cut. It is therefore possible to form the string-like member 5 having strong tensile strength and toughness. Accordingly, this string-like member 5 may be used, as the packing 1, as cut to a predetermined length according to, for example, the diameter of a shaft to be sealed. This improves the packing 1 in versatility and practical utility. Further, the strong compression-restoring force and excellent sealing properties of the expanded graphite 41 are given to the twisted string-like member 5 forming the packing 1. Accordingly, the packing 1 may be provided with such sealing properties as indispensably required for packing. In the foregoing, the description has been made of the expanded graphite 41 in the form of caterpillar-like particles. Alternately, there may be used expanded graphite sheets each of which is so cut as to have a small width of, for example, 5 mm or less. Alternately, each knitting yarn 4 may be formed by bonding the expanded graphite 41 only on one surface of a plurality of reinforcing fiber yarns 40 with adhesives. Further, the knitting yarns 4 may be used after twisted as shown in Fig. 5. The reinforcing fiber yarns 40 forming the knitting yarns 4 may be made of, instead of cotton mentioned earlier, a single material which is selected from organic fibers such as rayon fibers, phenol fibers, aramid fibers, PBI fibers, PTFE fibers, PPS fibers, PEEK fibers and the like, which is selected from inorganic fibers such as glass fibers, carbon fibers, ceramic fibers and the like, or which is selected from metallic line members such as line members of stainless steel, Inconel, monel metal and the like. The inorganic fibers and the metallic line members present no fuzz on the surfaces thereof, and are therefore slightly inferior in adhesion of the adhesives to the organic fibers. However, the proper selection of the adhesives enables the reinforcing fiber yarns 40 and the expanded graphite 41 to be bonded to each other in a relatively secure manner. This prevents the expanded graphite 41 from partially falling from the reinforcing fiber yarns 40. In the knitting yarns 4 made of such inorganic fibers or metallic line members, the tensile strength is considerably improved as compared with the knitting yarns 4 made of the organic fibers. Figs. 6 to Fig. 10 respectively show modifications of the reinforcing fiber yarn 40. In Fig. 6, the reinforcing fiber yarn 40 is made by twisting a yarn 40A made of a single material selected from the organic fibers mentioned earlier (cotton or aramid), and a yarn 40B made of a single material selected from the inorganic fibers and metallic line members mentioned earlier (glass fibers, carbon fibers or stainless steel line members). This reinforcing fiber yarns 40 may be improved in toughness and adhesion of adhesives by the organic fibers, and also improved in tensile strength and toughness by the inorganic fibers or metallic line members. In Fig. 7, the reinforcing fiber yarn 40 comprises (i) a yarn 40B made of at least one material selected from the inorganic fibers and metallic line members mentioned earlier (glass fibers, carbon fibers or stainless steel line members), and (ii) short fibers 6 made of a single material selected from the organic fibers mentioned earlier (cotton or aramid), the short fibers 6 covering the surface of the yarn 40B. This reinforcing fiber yarn 40 may be improved in toughness and adhesion of adhesives by the covering layer of the short fibers 6, and also improved in tensile strength and toughness by the yarn 40B made of at least one material selected from the inorganic fibers and the metallic line members. The short fibers 6 forming the covering layer may be made of a composite short fiber yarn containing, in combination, fibers made of two or more types selected from the organic fibers. In Fig. 8, the reinforcing fiber yarn 40 comprises a yarn 40B made of at least one material selected from the inorganic fibers and metallic line members mentioned earlier (glass fibers, carbon fibers or stainless steel line members), this yarn 40B being covered with, for example, pulp sheet-form 7. This reinforcing fiber yarn 40 may be improved in toughness and adhesion of adhesives by the covering layer of the pulp sheet-form 7, and also improved in tensile strength and toughness by the yarn 40B made of at least one material selected from the inorganic fibers and the metallic line members. In Fig. 9, the reinforcing fiber yarn 40 is made by knitting either a yarn 40A made of a single material selected from the organic fibers mentioned earlier (cotton or aramid) or a yarn 40B made of a single material selected from the inorganic fibers and metallic line members mentioned earlier (glass fibers, carbon fibers or stainless line members). This reinforcing fiber yarn 40 may be improved in adhesion of adhesives by the concavo-convex knitted portions in the knit structure thereof. Further, the stretching properties of the knit structure itself may absorb a tensile force. This results in increase in tolerance for stretching, thus improving the toughness. In Fig. 10, the reinforcing fiber yarn 40 comprises (i) a plurality of longitudinally arranged fibers 40B in parallel to one another, made of a single material selected from the inorganic fibers and metallic line members mentioned earlier (glass fibers, carbon fibers or stainless steel line members), and (ii) fibers 40A made of a single material selected from the organic fibers mentioned earlier (cotton or aramid), the fibers 40A being entangled with the fibers 40B so that the fibers 40B are maintained in parallel with one another. This reinforcing fiber yarn 40 may be improved in toughness and adhesion of adhesives by the organic fibers, and also improved in tensile strength and toughness by the inorganic fibers or the metallic line members. The strong tensile strength and toughness of the reinforcing fiber yarns 40 are given to the knitting yarn 4. Thus, the knitting yarns 4 may be readily braided or twisted without the yarns 4 cut. More specifically, when carrying out circular-knitting while drawing out the knitting yarns 4 from a plurality of bobbins 9 adapted to be moved along loci shown by broken lines as shown in Figs. 11A and 11B, there is produced a small difference between the distance 1a between a knitting point P and each of the bobbins 9 as located in the mostouter parts of one locus, and the distance 1b between the knitting point P and each of the bobbins 9 as located in the mostinner parts of the other locus. In this case, a relatively small tensile force is applied to the knitting yarns 4, so that the yarns 4 may be readily braided. On the other hand, when carrying out square-knitting while drawing out the knitting yarns 4 from a plurality of bobbins 9 adapted to be moved along diagonal loci shown by broken lines as shown in Figs. 12A and 12B, there is produced a great difference between the distance 1a between a knitting point P and each of the bobbins 9 as located in the mostouter parts of one locus, and the distance 1b between the knitting point P and each of the bobbins 9 as located in the center parts of the other locus. In this case, a relatively great tensile force is applied to the knitting yarns 4. Even in this case, the yarns 4 may be braided. Industrial Applicability In packing using expanded graphite as a base material, the present invention eliminates a need for provision of a variety of annular packings according to the diameters of shafts to be sealed, as conventionally required for molded packing made of expanded graphite. The packing of the present invention has not only such sealing properties as inevitably required for packing, but also strong tensile strength and toughness. Thus, the packing of the present invention may be suitably used as gland packing or a sealing member for static members.

Claims: Packing comprising knitting yarns, each of said knitting yarns (4) including a plurality of longitudinally arranged reinforcing fiber yarns (40) and expanded graphite (41) integrally bonded to at least one side of said reinforcing fiber yarns (40) with adhesives, a plurality of said knitting yarns (4) being put together to form a core member (2), and a plurality of said knitting yarns (4) being put together to form a braided body (3) covering said core member (2), at the outer periphery thereof. Packing comprising knitting yarns, each of said knitting yarns (4) including a plurality of longitudinally arranged reinforcing fiber yarns (40) and expanded graphite (41) integrally bonded to at least one side of said reinforcing fiber yarns (40) with adhesives, and a plurality of said knitting yarns (4) being put together and braided. Packing comprising knitting yarns, each of said knitting yarns (4) including a plurality of longitudinally arranged reinforcing fiber yarns (40) and expanded graphite (41) integrally bonded to at least one side of said reinforcing fiber yarns (40) with adhesives, and a plurality of said knitting yarns (4) being put together and twisted. Packing according to Claim 1, 2 or 3, wherein the expanded graphite (41) is in the form of caterpillar-like graphite powder. Packing according to Claim 1, 2 or 3, wherein the expanded graphite (41) is in the form of a sheet having a narrow width. Packing according to Claim 1, 2, 3, 4 or 5 wherein each of the knitting yarns (4) includes a plurality of longitudinally arranged reinforcing fiber yarns (40) and expanded graphite (41) integrally bonded to at least one side of said reinforcing fiber yarns (40) with adhesives, and said knitting yarns (4) are twisted. Packing according to Claim 1, 2 or 3, wherein the reinforcing fiber yarn (40) is made of at least one material selected from organic fibers such as cotton fibers, rayon fibers, phenol fibers, aramid fibers, PBI fibers, PTFE fibers, PPS fibers, PEEK fibers and the like. Packing according to Claim 1, 2 or 3, wherein the reinforcing fiber yarn (40) is made of at least one material selected from inorganic fibers such as glass fibers, carbon fibers, ceramic fibers and the like. Packing according to Claim 1, 2 or 3, wherein the reinforcing fiber yarn (40) is made of at least one material selected from metallic line members such as stainless steel, Inconel, monel metal and the like. Packing according to Claim 1, 2 or 3, wherein the reinforcing fiber yarn (40) comprises a composite fiber yarn made of (i) at least one material selected from the organic fibers and (ii) at least one material selected from the inorganic fibers and the metallic line members. Packing according to Claim 1, 2 or 3, wherein the reinforcing fiber yarn (40) comprises a fiber yarn or a composite fiber yarn made of at least one material selected from the inorganic fibers and the metallic line members, said fiber yarn being covered, at the surface thereof, with short fibers (6) or composite short fibers made of at least one material selected from the organic fibers. Packing according to Claim 1, 2 or 3, wherein the reinforcing fiber yarn (40) comprises a fiber yarn or a composite fiber yarn made of at least one material selected from the inorganic fibers and the metallic line members, said fiber yarn or said composite fiber yarn being covered, at the surface thereof, with pulp sheet-form (7). Packing according to Claim 1, 2 or 3, wherein the reinforcing fiber yarn (40) comprises a yarn as obtained by twisting organic fibers and inorganic fibers or metallic line members. Packing according to Claim 1, 2 or 3, wherein the reinforcing fiber yarn (40) is a yarn as obtained by knitting the organic fibers, the inorganic fibers or the metallic line members. Packing according to Claim 1, 2 or 3, wherein the reinforcing fiber yarn (40) comprises a plurality of longitudinally arranged inorganic fibers or metallic line members in parallel with one another, and organic fibers entangled with said inorganic fibers or said metallic line members so that said inorganic fibers or said metallic line members are maintained in parallel with one another.

Inventors: UEDA TAKAHISA, UEDA, TAKAHISA
Applicants: NIPPON PILLAR PACKING, NIPPON PILLAR PACKING CO., LTD.
Application year: 1990
Main classification: F16J15
IPC codes: F16J15