ZONE STIFFENED COMPOSITES, WITH TWO DIFFERENT RESINS

Abstract: A method of moulding a composite article which comprises providing a mould adapted to receive a first matrix component for moulding the article, inserting a membrane (3) in the mould so as to define at least two contiguous volumes (1, 2) separated thereby, injecting a first component system on one side of the said membrane and injecting a second matrix system on the other side of the membrane and curing the system. Preferably the membrane is arranged to allow the two matrix systems to partially diffuse into one another before curing to give a bond between the two.

Description: Zone stiffened composites, with two different resins , This invention relates to a method of moulding and in particular to a method of moulding fibre-reinforced resin composite materials. Products and components made from high strength composites consisting of reinforcing fibres bonded in a matrix material system -such as synthetic resin are continually finding new applications as their strength-to-weight advantages are realised and exploited. However, there are certain applications where the surface properties of the product cannot be achieved by the matrix . material system employed in forming the component. Secondary coating processes, such as in-mould coating, can be used but in general these are restricted to thin coatings and they always complicate the production process and therefore add cost. An example of such a product is an access chamber cover of the type described in European Patent No 1047050. For this type of cover to be suitable for use in the highway it must have a top surface of sufficient thickness to contain a tread pattern and this surface must have exceptional wear and high friction properties . Such a surface coating requires the use of special resins in conjunction with the inclusion of aggregates, and it is very difficult to apply the secondary coating. The method of the invention seeks to provide an improved manufacturing process which will allow the injection of two or more matrix material systems within a single moulding cycle of a component. Each matrix material system may, independently, have the ability to incorporate fibre reinforcement, aggregates, various fillers and the like. According to the present invention there is provided a method of moulding a composite article which comprises providing a mould adapted to receive a first matrix component for moulding the article, inserting a membrane in the mould so as to define at least two contiguous volumes seperated thereby, injecting the first matrix system one side of the said membrane and injecting a second matrix system on the other side of the membrane. Preferably the first matrix system has the characteristics required for the surface and, in effect, provides the surface coating on the finished composite article. It will preferably be a curable resin system and may contain fibre reinforcement, aggregates, various fillers and the like to give the necessary wear and surface friction properties. The membrane acts as a boundry between the two volumes and allows injection of one matrix material system into the chosen volume confining it to that predetermined volume within the mould. The second matrix material may be injected into the other contiguous volume and the membrane is preferably adapted to allow one of the matrix systems to diffuse into the other so as to fuse, chemically combine or otherwise bond prior to or as part of the curing process for the article. The second matrix system may be a curable plastics resin system as used in our above mentioned European patent . The matrix component may be a cloth or batt of fibres, e.g. glass fibres, and may contain one or more foam inserts. A membrane suitable for use on the method of the invention may be made in a number of different ways and the most suitable membrane will depend on the product and matrix material systems employed. Examples of suitable membrane systems are described below. 1) A membrane is formed from a woven, knitted or non-woven fabric with pore sizes of a predetermined value intended for use with matrix material systems of different viscosities. One volume can be injected with higher viscosity material which would be contained by the membrane after which the second volume is injected with the lower viscosity material which would penetrate the membrane and come into direct contact with the first material. 2) A membrane similar to that in paragraph 1 above maybe be coated and hence sealed with a thin film of material but the membrane or coating is dissolved by the second matrix material injected, thereby allowing direct contact between the two matrix materials. 3) A membrane may be made from a pre- impregnated reinforement material normally used in the moulding system, such as a resin impregnated glass fibre cloth or batt, which on contact with the injected matrix materials integrates with them and proceeds to cure as part of the curing process. 4) A membrane may be made from a fabric such that the first matrix material system coming into contact with one side of the fabric has the effect of "blinding" the fabric and hence blocking the matrix material from penetrating through it. The second matrix material injected from the opposite side can penetrate the membrane and make direct contact with the first injected material. Naturally other forms of membrane could be employed as could combinations of the forms described above. The invention will now be described, by way of example, with reference to the accompanying drawings, in which: Figure 1 is a sectional view of a mould for producing a manhole cover of the type described in European Patent No 1047050; and Figure 2 is a similar view to figure 1 after injection has been completed. Referring to the drawings, a mould generally designated (10) is illustrated for producing a manhole cover suitable for highway installation which will therefore have an upper surface portion of- sufficient thickness to contain a tread pattern which will also have exceptional wear properties and high friction properties. As described in our PCT publication no. D89/00495 the basic product comprises foam insert (12) about which reinforcing fibres (14) are arranged. The central gallery (16) gives access to the upper and lower fibre layers and a nozzle (5) is inserted directly into the gallery (16) to inject a matrix system, in this case a curable synthetic resin, into the fibres (14) whereby to produce the composite manhole cover. The cover is more fully described in our above mentioned European Patent, and in our PCT patent publication no. O89/00495. As modified in accordance with the method of the present invention, a membrane (3) is provided above the upper layer of fibres (14) effectively dividing the interior mould space into two volumes (1) and (2) respectively. The nozzle (5) , as already described, penetrates into the gallery (16) in the volume (2) passing through the membrane (3) and being arranged to sealingly engage with it. A second nozzle (4) is provided communicating with the volume (1) . In operation, the matrix material systems of the surface layer may be injected in a precise quantity, through the nozzle (4) into volume (1) . The air in volume (1) would then escape through the membrane into volume (2) and out to atmosphere through vents (6) . The matrix material would be confined in volume(l) by the membrane (3) . An even hydraulic pressure would be applied onto the membrane by the matrix material thus applying an even pressure onto the fibres (14) and foam core (12) of the basic composite structure. This could be arranged to force the structure to occupy its designed volume. The resin employed as the second matrix material system for the volume (2) would be injected through nozzle (5) . The air in the volume 2 would vent via the vents (6) once again. On completion of the injection cycle nozzles (4 & 5) are withdrawn and the holes plugged with plugs (18), (20) (as illustrated in figure 2) after which the resin systems within the mould are cured or allowed to cure. On completion of the curing process of the two matrix systems, the component would be demoulded. For thin surface coatings it may prove beneficial to inject volume (2) first and allow the injection into volume (1) to force excess matrix material from volume (2) out through the vent (6). It is preferable to inject volumes (1 & 2) from the same side of the mould as this simplifies the moulding equipment required. If there were more than two, for example three, volumes then penetration of a nozzle through one volume and a membrane may prove the only method of injection possible. It will be appreciated that other combinations of injection sequences may be employed to suit individual circumstances. The method of this invention, especially when combined with the direct injection system described in our PCT patent publication no. WO89/00495 provides an exceptionally versatile process for the manufacture of advanced complex composite components for diverse applications.

Claims: AMENDED CLAIMS [received by the International Bureau on 10 December 1990 (10.12.90); original claim 1 amended; other claims unchanged (3 pages)] 1. A method of moulding a composite article which comprises providing a mould adapted to receive a first matrix component for moulding the article, inserting a membrane in the mould so as to define at least two contiguous volumes separated thereby, injecting a first matrix system on one side of the said membrane and injecting a second matrix system on the other side of the membrane and curing the system, at least one of said volumes being completely filled with reinforcing fibres. 2. A method as claimed in claim 1 in which the first matrix system has the characteris ics required for the surface and provides a surface coating on the finished composite article. 3. A method as claimed in either of claims 1 or 2 in which the membrane acts as a boundry between the two volumes. 4. A method as claimed in claim 3 in which the membrane is adapted to allow one of the matrix systems to diffuse into the other so as to fuse, chemically combine or otherwise bond prior to or as part of the curing process for the article. 5. A method as claimed in any of claims 1 to 4 in which the membrane is formed from a woven, knitted or non-woven fabric with pore sizes of a predetermined value intended for use with matrix material systems of different viscosities, one volume is injected with higher viscosity material which is contained by the membrane after which the second volume is injected with the lower viscosity material which penetrates the membrane and comes into direct contact 6. A method as claimed in any of claims 1 to 4 in which the membrane is formed from a woven, knitted or non-woven fabric which is coated and hence sealed with a thin film of material, the coating being dissolved by the second matrix material injected, thereby allowing direct contact between the two matrix materials. 7. A method as claimed in any of claims 1 to 4 in which the membrane is made from a pre-impregnated reinforement material normally used in the moulding system, which on contact with the injected matrix materials integrates with them and proceeds to cure as part of the curing process. 8. A method as claimed in claim 7 in which the material is a resin impregnated glass fibre cloth or batt. 9. A method as claimed in any of claims 1 to 4 in which the membrane is made from a fabric such that the first matrix material system coming into contact with one side of the fabric has the effect of "blinding" the fabric and hence blocking the matrix material from penetrating through it, and the second matrix material injected from the opposite side penetrates the membrane and makes direct contact with the first injected material. 10. A method as claimed in any of claims 1 to 9 in which the matrix material is injected into one volume by means of a nozzle passing through the mould into that volume, and the matrix material is injected into the other volume or volumes by another nozzle passing through the first volume and the membrane. 11. A method as claimed in claim 10 in which the said another nozzle sealingly engages with the membrane as it passes therethrough. 12. A method as claimed in any of claims 1 to 11 in which each matrix system is a curable plastics material resin system, which may incorporate fillers or reinforcement.

Inventors: NEWTON JOHN, NEWTON, JOHN
Applicants: 3 D COMPOSITES LTD, 3-D COMPOSITES LIMITED
Application year: 1990
Main classification: B29C67
IPC codes: B29C44, B29C45, B29C70, B29D31, B29K105