Heat-shrinkable article

Abstract: A heat shrinkable tubular article 14 e.g. for screening an electrical connector, is provided over a surface thereof with an electrically conductive continuous coating 16 of substantially pure indium. Upon recovery of the article 14, the indium coating 16 remains continuous and adhered to the surface of the article.

Description: This invention relates to a heat-shrinkable tubular article having an electrically conductive coating over a surface thereof, the article being intended to enclose the junction between an electric cable and a connector and the conductive coating serving as an electrical shield. The invention also relates to a method of forming such an article. It has been a problem with such articles to provide a lining which is of sufficient electrical conductivity for its shielding purpose, but which will maintain its integrity when the article shrinks or recovers. In particular, metal coatings of adequate thickness for the shielding function have broken up as the article recovers. EP 0 238 203 discloses a heat-shrinkable tubular article provided over a surface thereof with an electrically conductive continuous metal coating which exhibits a broad melting point so that the metal softens, without fully melting, during recovery of the article. The heat-shrinkable tubular article according to this invention is characterised in that the metal coating consists of pure indium having a distinct melting point of 156°C. We have found that although indium has the distinct melting point of 156°C, it is quite ductile over a range of temperatures below that melting point. Moreover, even over a range of temperatures above its melting point, indium does not flow readily. Therefore the heat-shrinkable tubular article can be heated to a temperature of 145 - 160°C for recovery and, upon recovery, the pure indium coating deforms without cracking: after recovery the indium coating remains continuous and adhered to the surface of the article. The indium coating may be sufficiently thick (e.g. 0.25mm) to achieve high values of electrical conductivity, yet because at the recovery temperature it is soft and deformable, it does not significantly resist shrinking of the article. The indium coating may be applied to the surface of the heat shrinkable article by means of any appropriate technique in accordance with known principles. It can enhance the adherence of the indium coating to the article to apply a priming layer to its surface before the indium coating is applied, the priming layer being thin compared with the indium coating. One material which may used for the priming layer comprises a polymeric material, e.g. polyvinyl acetate, and this may for example be applied in the form of a water-based emulsion which is then dried to result in a polymeric layer of e.g. 30 µm (microns) thickness. As another example, a metal e.g. silver may be used for a priming layer. Such a metal priming layer may be applied for example by sputter-coating (vacuum deposition) typically to a thickness of 1 µm (micron). One appropriate technique for applying the deformable metal coating comprises spraying. Embodiments of his invention will now be described by way of examples only and with reference to the accompanying drawings, in which: FIGURE 1 is a longitudinal section through a heat-shrinkable article or boot recovered about a cable and its connector; and FIGURE 2 is a similar section through an alternative embodiment of boot recovered about a cable and its connector. Referring to Figure 1, a cable 10 is terminated by a connector component 12. The details of the connector component and of the termination of the cable conductors are not shown and do not form part of the invention. It is sufficient to note that the cable insulation is cut back a certain distance to expose a length of the screen 11 of the cable. A heat-shrinkable boot 14 is shown recovered about the cable 10 and its connector component 12. The boot 14 is a tubular article of generally bottle-shape, with a narrower end recovered about the cable insulation and about a portion of the exposed cable screen 11, and a wider end recovered about the circumference or periphery of the connector component 12. In the example shown, the wider end of the boot is provided with an inturned rim or flange 15 which is received within a groove 13 formed around the periphery of the connector 12. The boot 14 is provided with an electrically conductive lining 16 on its inner surface, extending from adjacent the wider end of the boot, over the larger-diameter section and the transition section and over just a portion of the smaller-diameter section. The lining 16 comprises a continuous coating of pure indium having a distinct melting point of 156°C which deforms without cracking upon recovery of the boot so that, after recovery, the coating remains continuous and adhered to the inner surface of the boot. The indium coating 16 may have a thickness generally in the range of 0.2 to 2mm, but preferably in the range 0.3 to 0.8mm. Typically the boot 14 may have a wall thickness in the range of 0.5 to 2.5mm and may for example have a length of the order of 5.5cm, a diameter of 13 to 20mm at its narrower end and a diameter of 35-45mm at its wider end. The material of the boot may be selected from a number of known plastics appropriate for forming heat-shrinkable articles and in the example shown in Figure 1 comprises a cross-linked polyolefin. The boot is expanded in diameter, from its as-moulded condition, by a factor preferably in the range 2 to 2.5, although the expansion factor can be up to 4. The boot of Figure 1 has a layer 21 of polymeric matterial disposed over its inner surface, the indium coating 16 being applied over this priming and the priming layer being thin compared with the indium coating 16. The priming layer 21 may have a thickness generally up to 50 µm (microns). In order to manufacture the article shown in Figure 1, the boot 14 is moulded and then undergoes expansion according to known techniques to render it capable of heat-recovery. Then in its expanded condition, the inner surface of the boot 14 receives its priming layer 21. In the example shown in Figure 1 this comprises polyvinyl acetate and is applied in the form of a water-based emulsion for example by brushing, which is then dried to result in a polymeric layer of e.g. 30 µm (microns) thickness. Then the indium coating 16 is applied in one or more layers to the desired thickness using any appropriate technique in accordance with known principles. One appropriate technique comprises spraying using selective masking. Figure 2 shows a boot 14 which differs from the boot shown in Figure 1, only in that a metal priming layer 22 replaces the polymeric priming layer 21 shown in Figure 1. This priming layer preferably comprises a precious metal (for example silver or gold) which may be applied to the inner surface of the boot 14 by sputter-coating (vacuum deposition), typically to a thickness of 1 µm (micron), before the indium coating is applid as described with reference to Figure 1. In use of the boot 14 of Figure 1 or Figure 2, the boot is positioned with its narrower end around the cable 10 and its wider end around the connector component 12. Just prior to applying the boot, the user may apply electrically conductive adhesive 17, 17, for example a conductive epoxy adhesive, over a knurled part 19 of the connector and over the exposed screen 11 of the cable, and insulating adhesive 18, 18, for example a hot melt or epoxy adhesive, over the groove 13 of the connector component 12 and over the cable sheath. Once the boot 14 is in position, heat is applied to it to cause it to shrink or recover for its narrower end to embrace the cable and its wider end to embrace the connector component 12 as shown in each of Figures 1 and 2. The temperature at which the boots 14 recover may be below or above the melting point (156°C) of the indium. If the article is heated to 145 - 156°C, the indium will not melt but it is sufficiently ductile to deform without cracking as the article recovers. If the article is heated to above 156°C, say to 160°C, the indium melts but does not flow away, so again it deforms as the article recovers. In either case the indium coating retains its integrity and remains as a continuous layer adhered to the inner surface of the boot 14. The applied adhesive 17, 17 serves to adhere the cable screen 11 and connector to the coating 16 in order to enhance the electrical contact between the cable screen and connector, respectively, and the coating 16. The adhesive 18, 18 serves as a sealant between the cable insulation and connector, respectively, and the boot.

Claims: A heat-shrinkable tubular article provided over a surface thereof with an electrically conductive continuous metal coating (16) characterised in that said metal coating consists of pure indium having a distinct melting point of 156°C. A heat shrinkable tubular article as claimed in claim 1, characterised in that a priming layer (21 or 22) is disposed over said surface and said indium coating (16) is disposed over said priming layer, said priming layer being thin compared with the indium coating. A heat-shrinkable tubular article as claimed in claim 2, characterised in that the priming layer (21) comprises a polymeric material, for example polyvinyl acetate. A heat-shrinkable tubular article as claimed in claim 3, characterised in that said polymeric material priming layer (21) has a thickness up to 50 µm. A heat shrinkable tubular article as claimed in claim 2, characterised in that the priming layer (22) comprises a precious metal preferably to a thickness of substantially 1 µm. A heat shrinkable tubular article as claimed in any preceding claim, characterised in that said indium coating (16) has a thickness in the range of 0.2 to 2mm and preferably in the range 0.3 to 0.8mm. A heat recoverable article as claimed in any preceding claim, characterised in that said indium coating (16) is disposed over the inner surface of the article. A method of forming a heat shrinkable tubular article provided over a surface thereof with an electrically conductive continuous metal coating (16), comprising taking an expanded, heat shrinkable tubular article (14) then applying a metal to a surface of said article to form a continuous coating (16) thereon characterised in that the metal coating consists of pure indium having a distinct melting point of 156°C. A method as claimed in claim 8, characterised by the step of applying a priming layer (21 or 22) to said surface of the article before the pure indium coating (16) is applied. A method as claimed in claim 9, characterised in that said priming layer comprises a polymeric material (21) which is applied in the form of an emulsion and then dried, or a precious metal (22) which is applied by sputter coating.

Inventors: GREGORY NIGEL JAMES, LEE PETER IAN, STEVENS MICHAEL JOHN, GREGORY, NIGEL JAMES, LEE, PETER IAN, STEVENS, MICHAEL JOHN
Applicants: BOWTHORPE HELLERMANN LTD, BOWTHORPE-HELLERMANN LIMITED
Application year: 1990
Main classification: H01R4
IPC codes: C23C18, C08J7, C22B58, H01R4, H01R13, H05K9, C23C14, B29L31, B29C61