Copper base alloy, containing manganese and aluminium, and objects made of said alloy

Abstract: An alloy based on copper and containing the following elements with less than 7% of Zn, replacing the Al in the alloy, and an amount of impurities not exceeding 0,5% by weight.

Description: Alloy based on copper, manganese and aluminium, and objects made of said alloy. The invention relates to an alloy based on copper, manganese and aluminium. The invention furthermore relates to objects made of such alloys. Such an alloy is known from DE-C-343739 an alloy of copper, zinc and manganese is known which may contain up to 33% zinc, to which the elements aluminium, nickel, manganese and titanium are added. A typical example of such an alloy contains 61% copper, 10.7% manganese, 2.3% iron, 0.37% nickel, 3.6% aluminium, 0.5% titanium, the balance being 21.9% is zinc. The resistance to corrosion of said zinc-containing alloy is comparatively poor. Dutch Patent No. 124,966, discloses an alloy that besides copper contains 1 - 9% iron, 0 - 7% nickel, 3 - 9% aluminium and 10 - 16% manganese. It has become apparent that the mechanical properties of said alloy, in particular its embrittlement, can be improved, so that it is possible to make objects of said alloys, at lower temperatures than have been usual so far. Also from British Patent Specification 727,021 a copper-manganese-aluminium alloy is known that contains 10 - 15% manganese, 6.5 - 9% aluminium, 2 - 4% iron and 1.5 - 6% nickel, the balance being copper. Such an alloy is also known as an aluminium bronze alloy and also with this alloy it appeared to be possible to improve the embrittlement, so that objects can be formed of said alloys at lower temperatures. The alloy according to the invention is characterized in that said alloy contains 10 - 55% by weight manganese, 4 - 10% by weight aluminium, 0.5 - 5% by weight iron, 2 - 8% by weight nickel and 0.5 - 2.5% by weight titanium, the balance being copper with less than 7% by weight zinc and that the titanium content is at least equal to half the iron content, and the nickel content is higher than the iron content. Furthermore aluminium may be partially replaced by zinc. From an article by S.W. Frost et al: "Thermal embrittlement in an Mn-Ni-Al bronze Casting Alloy", AFS Transactions, vol.146, pages 653 - 659 (1980) it is known that with copper-manganese-aluminium alloys signs of embrittlement may occur, leading to premature fracture, especially with dynamically loaded parts in corrosion causing environments, as a result of which objects made of said alloys are less suitable for use in corrosive conditions. Said signs of embrittlement are considerably reduced when objects are made of the alloy according to the invention. Because of the presence of titanium in manganese- and aluminium-containing copper alloys the resistance to corrosion and oxidation and the corrosion fatigue properties are at the same time considerably improved. Objects made of said alloy have a very high resistance to wear, good mechanical properties and a high damping force when the manganese content is higher than 45% by weight. By adding titanium to the manganese- and aluminium-containing copper alloys the precipitation of an impure, brittle phase in the structure of the material during cooling may be prevented. The occurrence of said impure, brittle phase in the structure, and the effect on the properties of the material is indicated in more detail in the following Tables A en B. It has been determined that dependent on the composition and cooling rate of the material a manganese-rich phase of the type Mn(β) is precipitated. Mn (β) is an allotropic modification of the element manganese with a complex, cubic structure, which occurs at high temperatures in the manganese-rich part of the system copper-manganese. With copper-manganese alloys Mn (β) does not occur before a complete state of equilibrium is reached, with very slow cooling of the material. The addition of small amounts of aluminium and/or zinc and large amounts of iron and nickel has a stabilizing effect on the formation of Mn (β). Thus a phase of the type Mn (β) already occurs with slow cooling of a manganese- and aluminium-containing copper alloy containing more than 13% by weight manganese and 6% by weight aluminium, to which a maximum amount of 5% by weight iron and nickel is added. This phase of the type Mn (β) is formed as a result of the interaction of aluminium, iron and manganese, which elements are precipitated during cooling, as a result of oversaturation of the solution area. When the local concentrations of iron, manganese and aluminium are exceeded a brittle phase of the type Mn (β) is formed, which contains more than 60% by weight manganese, and which greatly affects the properties of the alloys, especially after relatively slow cooling, being lower than 250 °C/hour. The presence of iron and nickel in the manganese- and aluminium-containing copper alloys is essential in connection with the strength and corrosion properties of the material. As a result of the addition of the indicated amount of titanium to the manganese- and aluminium-containing copper alloy, also containing iron and nickel, there will be no precipitation of a brittle phase of the type Mn (β). The presence of titanium in the alloy causes the formation of a separate, ductile phase with iron, nickel, aluminium and maximally 10% by weight manganese, which provides a considerable improvement of the properties of the alloy. For this purpose it is necessary that the elements titanium, iron and nickel are present in certain amounts and preferably in a certain ratio. In that case the titanium content is at least equal to half the iron content, in order to effect the formation of a separate, ductile phase. The nickel content is higher than the iron content, in order to be able to offset the amount of nickel extracted from the matrix as a result of the occurrence of said phase. Besides the above-mentioned elements the alloy may also contain a certain amount of zinc. This makes it possible for the alloy to be melted in an oven in which previously brass was present. Thus an easy changeover is possible from aluminium bronze, via the alloy in question, to brass, and vice versa. In case zinc is present in the alloy an aluminium equivalent of about 0.3% must be taken into account. The alloys according to the invention are suitable for producing objects by heat-moulding processes. The heat-moulding temperatures are on average 100 °C lower than with the known nickel-aluminium bronze alloys having comparable properties. Within the composition range of the alloy according to the invention a number of test pieces were cast and cooled at varying rates. Various mechanical properties of said test pieces were measured, which were compared with similar alloys to which no titanium was added, and which were cooled under similar conditions. The results are shown in Table A, wherein the alloys 1, 2, 7, 12 and 13 are comparative alloys. From this Table it follows that the titanium-containing alloys have a higher elongation than the alloys that do not contain titanium, which indicates that titanium-containing alloys are not brittle by nature, compared with the alloys that do not contain titanium. In Table A the alloy 18 has a high manganese content. Said alloy has a high specific damping capacity of 15 - 20%. The alloy 14 on the contrary has a specific damping capacity of about 3%. The corrosion resistance properties of a number of these alloys, cooled at a rate of 40 °C/hour, were measured, Said properties are indicated by the number of reversals until fracture occurs at a given load condition of a test bar in a 3% sodium chloride solution. The results are shown in Table B. From this table it can be derived that with dynamic loads in a corrosive environment the life of titanium-containing alloys (alloys 20 and 21) is considerably longer than in the case of alloys that do not contain titanium (alloy 19).

Claims: An alloy based on copper, manganese, and aluminum, said alloy contains 10-55% by weight manganese, 4-10% by weight aluminium, 0,5-5% by weight iron, 2-8% by weight nickel and 0,5-2,5% by weight titanium, the balance being copper with less than 7% by weight zinc and that the titanium content is at least equal to half the iron content and the nickel content is higher than the iron content. An alloy according to claim 1, characterized in that the alloy consists of 5-8% by weight aluminium, 10-25% by weight manganese, 0.5 - 3% by weight iron, 2-6% by weight nickel, 0.5-2% by weight titanium, 0-5% by weight zinc, the balance being copper, with the amount of impurities not exceeding 0.5% by weight. An alloy according to claim 1, characterized in that the alloy consists of 4-6% by weight aluminium, 45-55% by weight manganese, 0.5-3% by weight iron, 2-6% by weight nickel, 0.5-2% by weight titanium, 0-5% by weight zinc, the balance being copper, with the amount of impurities not exceeding 0.5% by weight. Objects produced from an alloy according to claims 1-3, characterized in that the temperature of the heat moulding processes is on average 100 °C lower than with nickel-aluminium bronze alloys that do not contain titanium.

Inventors: WENSCHOT PETRUS, WENSCHOT, PETRUS
Applicants: BOLIDEN LDM NEDERLAND BV, BOLIDEN LDM NEDERLAND B.V.
Application year: 1990
Main classification: C22C9
IPC codes: C22C9, C22C22