Apparatus for manufacturing single silicon crystal

Abstract: An apparatus for manufacturing single silicon crystal comprises a quartz crucible (1) accomodated into a graphite crucible (2), a partition member (8) partitioning molten silicon material in the quartz crucible into a single silicon growing portion on the inner side and a material melting portion on the outer side, a heater (3) for maintaining the molten silicon material in the single silicon growing portion at a temperature appropriate for growing the single silicon crystal and for supplying heat for melting the raw materials fed into the material melting portion, and small holes (9) made in the partition member. The partition member is made of an opaque quartz glass. The material melting portion is replenished with the raw materials and single silicon crystal is pulled from the single silicon growing portion. Molten silicon material moves from the material melting portion into the single silicon growing portion through small holes made in the partition member.

Description: The present invention relates to an apparatus for manufacturing single silicon crystal by the use of Czochralski process, and more particularly, to an apparatus for pulling single silicon crystal while continuously feeding silicon materials. A method for pulling single silicon crystal by the use of the Czochralski process has previously been used and this method is a substantially completed technique. However,the yield of wafers being able to stand their use can be 50 % or less due to maldistribution of dopants and oxygen in case requirements to components are severe. As an effective method for solving the foregoing problem, there is known a method wherein a liquid surface of molten materials is maintained at a predetermined level by continuously or intermittently replenishing a crucible with silicon material. Particularly recently, high-quality granular polycrystal silicon has come to be able to be manufactured, and several inventions wherein this high-quality granular polycrystal silicon is used are disclosed. Those inventions are, for example, disclosed in Japanese Patent Publications Laid Open No.130195/83 and No.95195/88 and in a Japanese Utility Model Publication Laid Open No.141578/84. Only one or two examples of having manufactured single silicon crystal of a small diameter are seen in the method for manufacturing single silicon crystal by the use of the foregoing method, but micro defects or the like in the single silicon crystal are not described. It is understood that there are the following problems in the prior art apparatus for pulling single silicon crystal while continuously and directly replenishing a crucible with granular silicon when there is used a transparent quartz glass usually used for manufacturing semiconductor materials as a partition member partitioning molten silicon materials in the crucible into a single crystal growing portion on the inner side and a material melting portion on the outer side. (1) Even though a single silicon crystal is made to grow rapidly so that micro defects can be hard to be incorporated into the single silicon crystal, there occur a great amount of oxidation-induced stacking faults (OSF) in comparison with the conventional Czochralski process. (2) A vibration of the surface of molten silicon is large and this hinders crystallization of the molten silicon. It is an object of the present invention to provide an apparatus for manufacturing a single silicon crystal wherein in an apparatus for manufacturing a single silicon crystal in which a crucible having molten materials therein is continuously replenished with granular or lumpish materials, charged materials are steadily melted without hindering a growth of the single silicon crystal and the single silicon crystal having a substantially constant concentration of dopant and oxygen in the direction of pulling of the single silicon crystal, without any micro defects in the single silicon crystal. To accomplish the above-mentioned object, the present invention provides an apparatus for manufacturing single silicon crystal comprising: a quartz crucible accommodated into a graphite crucible, molten silicon being in said quartz crusible; a partition member partitioning molten silicon material in said quartz crucible into a single silicon growing portion on the inner side and a material melting portion on the outer side, said material melting portion being replenished with granular silicon and a single silicon crystal being pulled from said single silicon crystal growing portion; a heater for maintaining said molten silicon material in the single silicon growing portion at a temperature appropriate for growing the single silicon crystal and for supplying heat for melting said granular silicon fed into said material melting portion, said heater being arranged so that it can surround said graphite crucible; small holes made in said partition member, said molten silicon material moving from said material melting portion to said single silicon growing portion through said small holes; and opaque quartz glass, which said partition member is made of. The above objects and other objects and advantages of the present invention will become apparent from the detailed description which follows, taken in conjunction with the appended drawings. Fig.1 is a vertical sectional view schematically illustrating an apparatus for manufacturing a single silicon crystal in an example of the present invention; and Fig.2 is a graphical representation indicating a comparison of densities of oxidation-induced stacking faults (OSF) in the case of using an opaque quartz glass for a partition member and in the case of using a transparent quartz glass for the partition member pertinent to the present invention In the apparatus of the present invention, firstly, the material melting portion is maintained at a high temperature so that granular silicon material can be sufficiently melted and the single silicon growing portion on the inner side is maintained at a temperature just above a melting point of silicon. In the foregoing state, the material melting portion is replenished with an amount of granular material corresponding to an amount of pulled crystal. The silicon material melted in the material melting portion flows into the single silicon growing portion through small holes made in the partition member. In the present invention, an opaque quartz glass is used for the partition member. Densities of the oxidation-induced stacking faults in the single silicon crystal grown in the single silicon growing portion on the inner side are decreased with the use of the opaque quartz glass. The vibration of the surface of molten silicon is decreased and a hindrance to single crystallization of silicon is removed. A visible ray permeability of the opaque quartz glass is desired to be 0 % or more and 50 % or less. A decrease of the densities of the oxidation-induced stacking faults and of the vibration of the surface of molten silicon seems to relate to the fact that a ray of light and a ray of heat are prevented from passing through the partition member due to opaqueness of the partition member. That is, it is thought that a radiation and an input of heat in a portion where a molten silicon liquid contacts quartz glass are stabilized and a fluctuation of wettability is decreased. An opaque quartz glass is used as the partition member. A glass, which is made opaque by forming small irregularities on the surface of the glass, can be used. In this case, a roughness of the irregularities is desired to be 50 to 2000µm RMS. RMS means a root mean square value. The irregularities of said quartz glass are formed by causing particles of a quartz glass to deposit on the surface of the quartz glass. In this case, three sorts of the following opaque quartz glasses are used: (a) An opaque glass having irregularities on the surface thereof on the side of the material melting portion; (b) An opaque glass having irregularities on the surface thereof on the side of the single crystal growing portion; and (c) An opaque glass having irregularities on both surfaces thereof on the side of the material melting portion and single crystal growing portion. The opaque glass (a) is most desirable among said three sorts of the opaque glasses since there is not possibility of separation of quartz glass fragments from the surface of the the partition member on the side of the single silicon growing portion. The opaqueness of the partition member is required during the growth of the single crystal. That is, a glass, which is transparent before the use of it and which becomes opaque at the time of its use, can be used. Then, the effect of the present invention is produced. Fig.1 is a vertical sectional view schematically illustrating an example of the present invention. In the drawings, reference numeral 1 denotes a quartz crucible which is accommodated into graphite crucible 2. Reference numeral 7 denotes molten materials put into the quartz crucible 1, from which single silicon crystal 4 grown into a pillar is pulled. Reference numeral 3 denotes a heater surrounding the graphite crucible 2. The above-described apparatus is fundamentally the same as the apparatus for manufacturing single silicon crystal by the use of the ordinary "Czochralski process". Granular material 6 is fed from material feeding apparatus 5 into a material melting portion A. Reference numeral 8 denotes a partition member which is made of an opaque quartz glass and which is positioned concentrically with the crucible 1 in the crucible 1. Small holes 9 are made in the partition member 8. Molten materials in the material molten portion A flow into the single crystal growing portion through the small holes 9. A lower edge portion of the partition member 8 is previously fused with the crucible 1 or fused with the crucible under influence of heat produced by melting of the silicon material. High-temperature molten materials in the material melting poriton A flow into the single crystal growing portion B through only the small holes 9. Fig.2 is a graphical representation showing a comparison of densities of the oxidation-induced stacking faults (OSF) in the case of the use of the opaque quartz glass and in the case of the use of the transparent quartz glass. It is understood that the densities of the oxidation-induced stacking faults are apparently decreased in the case of the use of the opaque quartz glass. As described above, according to the present invention, in an apparatus for manufacturing single silicon crystal which comprises a crucible having molten silcon material therein and a partition member partitioning said molten silicon material into a single silicon growing portion on the inner side and a material melting portion on the outer side, since said partition member is made of an opaque quartz glass, oxidation-induced stacking faults due to a fluctuation of temperatures and a hindrance to a single crystallization are prevented. Reference signs in the claims are intended for better understanding and shall not limit the scope.

Claims: An apparatus for manufacturing single silicon crystal comprising: a quartz crucible (1) accomodated into a graphite crucible (2), molten silicon being in said quartz crusible; a partition member (8) partitioning molten silicon material in said quartz crucible into a single silicon growing portion on the inner side and a material melting portion on the outer side, said material melting portion being replenished with raw materials and a single silicon crystal (4) being pulled from said single silicon crystal growing portion; a heater (3) for maintaining said molten silicon material in the single silicon growing portion at a temperature appropriate for growing the single silicon crystal and for supplying heat for melting said raw materials fed into said material melting portion, said heater being arranged so that it can surround said graphite crucible; and small holes (9) made in said partition member, said molten silicon material moving from said material melting portion to said single silicon growing portion through said small holes; characterized in that said partition member is made of opaque quartz glass which is rendered opaque by small irregularities on the surface of the glass. The apparatus of claim 1, characterized in that said opaque quartz glass has a visible ray permeability of 0 to 50 %. The apparatus of claim 1 or 2, characterized in that said irregularities of the quartz glass are formed by causing particles of a quartz glass to deposit on the surface of the quartz glass. The apparatus of claim 1, 2 or 3, characterized in that said opaque quartz glass is a quartz glass made opaque by forming irregularities of 50 to 2000µm RMS. The apparatus of claim 4, characterized in that said roughness is on the surface of the side of the single crystal growing portion. The apparatus of claim 4 or 5, characterized in that said roughness is on the surface of the side of the material melting portion.

Inventors: ARAKI KENJI C O PATENT LICENSE, OHMURA MASANORI C O PATENT LIC, OHTANI AKIRA C O PATENT LICENS, SHIMA YOSHINOBU C O PATENT LIC, ARAKI, KENJI, OHMURA, MASANORI, OHTANI, AKIRA, SHIMA, YOSHINOBU, Araki, Kenji, c/o Patent &amp; License Department, Ohmura, Masanori, c/o Patent &amp; License Department, Ohtani, Akira, c/o Patent &amp; License Department, Shima, Yoshinobu, c/o Patent &amp; License Department
Applicants: NIPPON KOKAN KK, NKK CORPORATION
Application year: 1990
Main classification: C30B15
IPC codes: C30B15, C30B29, H01L21