Ferroelectric liquid crystal device and method of manufacturing the same

Abstract: A ferroelectric liquid crystal device (81) has transparent plates (83a, 83b), on which transparent electrodes (85a, 85b) are formed, arranged opposed to each other to form a space therebetween, with ferroelectric liquid crystals (95) sealed in the space. Black masks (89b) are arranged between the transparent electrodes (85b). Portions of the black masks (89b) extend over the transparent electrodes (85b). Black masks (89a) are arranged between the transparent electrodes (85a), with portions of the black masks (89a) extending over the transparent electrodes (85a). Since black masks (89a, 89b) are provided between the transparent electrodes (85a, 85b), respectively, state of display can be made uniform in non-pixel portions. Since the black masks (89a, 89b) on the transparent electrodes (85a, 85b) prevents undesired inversion of spontaneous polarization of the liquid crystal molecules in the pixel portions, the state of display of the pixel portions can be made stable.

Description: The present invention relates to a ferroelectric liquid crystal device and, more specifically, to the structures of its pixel portions and non-pixel portions. The present invention further relates to a method of manufacturing such a ferroelectric liquid crystal device. Fig. 5 is a perspective view showing schematically a conventional ferroelectric liquid crystal device. Transparent electrodes 3a are arranged spaced apart from each other on a main surface of a transparent plate 2a. Transparent electrodes 3b are arranged spaced apart from each other on a main surface of a transparent plate 2b. The transparent plates 2a and 2b are positioned opposing to each other to form a space. The transparent electrodes 3a and the transparent electrodes 3b intersect with each other in three dimensions. Areas at which the transparent electrodes 3a and 3b intersect with each other constitute pixels portions. The remaining portions are the non-pixel portions. Display patterns are formed by combining the pixel portions. Ferroelectric liquid crystal is sealed in the space formed by the transparent plates 2a and 2b. The ferroelectric liquid crystal is not shown in Fig. 5. The conventional ferroelectric liquid crystal device 1 will be further described with reference to Figs. 6 and 7. Fig. 6 is a cross sectional view taken in a direction of an arrow XXIV of Fig. 5. Fig. 7 is a cross sectional view taken in a direction of an arrow XXV of Fig. 6. As shown in Fig. 6, the ferroelectric liquid crystal device 1 has a structure that liquid crystal molecules 6 are sandwiched by the transparent plate 2a on which transparent electrodes 3a are formed and a transparent plate 2b on which transparent electrodes 3b are formed. The portion represented by 7a shows that the left end portion of the liquid crystal molecule 6 is projected upward from the surface of the sheet. The portion represented by 7b shows that the right end portion of the liquid crystal molecule 6 is projected upward from the surface of the sheet. The reference character 8 indicates spontaneous polarization of the liquid crystal molecule 6. The head of the arrow corresponds to the positive polarity, while the tail of the arrow corresponds to the negative polarity. The reference character 9 shows a line indicating a boundary between a layer of the liquid crystal molecule 6 and a layer of the liquid crystal molecule 6. The line represented by 9 will be hereinafter called as a boundary. An insulating film 4a is formed on the transparent electrode 3a. An alignment film 5a is formed on the insulating film 4a. An insulating film 4b is formed on the transparent electrode 3b. An alignment film 5b is formed on the insulating film 4b. The insulating films 4a, 4b and alignment films 5a and 5b are not shown in Fig. 5. The alignment films 5a and 5b serve to make the orientation of the liquid crystal molecules 6 parallel to the main surface of the transparent plates 2a and 2b. However, the boundaries 9 are not always made parallel to each other dependent on the alignment films 5a and 5b. Rubbing is done on the transparent plates 2a and 2b, so that the boundaries 9 are made parallel to each other. Fig. 8 shows rubbing on the transparent plate 2a on which the alignment film is formed. A rubbing cloth 11 is attached around a rubbing roller 12. The rubbing roller 12 is rotated in the direction of the arrow, and the transparent plate 2a is fed in contact with the rubbing cloth 11. Consequently, a plurality of linear grooves are formed on the transparent plate 2a. These grooves are called rubbings. The boundaries 9 are aligned with these grooves. The intensity of polarity of the alignment film is considered to be changed by the rubbings. Rubbing is also done on the transparent plate 2b on which the alignment film is formed. The ferroelectric liquid crystal device has the following characteristics. Namely, bistability, memory effect and high responsiveness. Bistability will be described at first. As shown in Fig. 7, the liquid crystal molecule 6 is stable when the longitudinal axis thereof is inclined by ϑ from the normal 10 of the boundary 9 and when it is inclined by - ϑ. Namely, the liquid crystal molecule 6 is in a bistable state. How the liquid crystal molecule 6 is set in a bistable state will be described with reference to Figs. 6, 7, 9 and 10. In Fig. 9, only the orientation of the liquid crystal molecules 6 is different from that in the ferroelectric liquid crystal device 1 shown in Fig. 6. Fig. 10 is a cross sectional view taken along the direction of an arrow XXVIII of Fig. 9. As shown in Figs. 9 and 10, if the polarity of the alignment film 5a is different from that of the alignment film 5b, for example if the polarity of the alignment film 5a is negative and that of the alignment film 5b is positive, the liquid crystal molecules 6 will be as shown in Figs. 9 and 10, because the liquid crystal molecules 6 have spontaneous polarization 8. As shown in Fig. 10, the liquid crystal molecules 6 are stable with the longitudinal axes being inclined by ϑ from the normal 10. When a positive voltage is applied to the transparent electrode 3a and a negative voltage is applied to the transparent electrode 3b, the direction of the spontaneous polarization 8 of those liquid crystal molecules 6 positioned between the transparent electrodes 3a and 3b is inverted as shown in Fig. 6. Referring to Fig. 7, the liquid crystal molecules 6 on the transparent electrode 3b have their longitudinal axes inclined by - ϑ from the normal 10. However, when the application of the voltages is stopped, the state shown in Figs. 9 and 10 are regained. The reason for this is that the alignment film 5a has negative polarity and the alignment film 5b has positive polarity. Therefore, the liquid crystal molecules 6 are not stable when the longitudinal axes are inclined by - ϑ from the normal 10. In that case, the bistable state is not realized. If the polarity of the alignment film 5a and the polarity of the alignment film 5b are made the same and the intensities of the polarity are made approximately the same, then stable state as shown in Fig. 6 and 7 is realised even when a positive voltage is applied to the transparent electrode 3a and a negative voltage is applied to the transparent electrode 3b and thereafter the application of voltages is stopped, as shown in Figs. 6 and 7. In that case, even if the polarities of the alignment film 5a and of the alignment film 5b are the same, the liquid crystal molecules 6 are influenced by the stronger polarity after the application of voltages is stopped, when the intensity of polarity is different. Then, a negative voltage is applied to the transparent electrode 3a shown in Fig. 6 and a positive voltage is applied to the transparent electrode 3b. Then the liquid crystal molecules 6 will be at the state shown in Figs. 9 and 10. Even when the application of voltages is stopped, the state of the liquid crystal molecules 6 shown in Figs. 9 and 10 is maintained. Namely, the bistable state of the liquid crystal molecules 6 can be realized by making the polarity of the alignment film 5a the same as that of the alignment film 5b and by making the intensities of polarities approximately equal to each other. The ferroelectric liquid crystal device 1 has memory effect, since the orientation of the liquid crystal molecules 6 is maintained even after the application of voltages is stopped. In addition, since the liquid crystal molecule 6 has both positive and negative polarities called spontaneous polarization, the orientation of the liquid crystal molecule 6 is immediately changed when the voltage is applied thereto. Namely, the ferroelectric liquid crystal device 1 has high responsiveness. The operation of the ferroelectric liquid crystal device 1 will be described with reference to Figs. 6, 7, 9 and 10. Referring to Fig. 6, when a positive voltage is applied to the transparent electrode 3a and a negative voltage is applied to the transparent electrode 3b, the liquid crystal molecules 6 are arranged as shown in Figs. 6 and 7. Thereafter, at the state of Figs. 6 and 7, a negative voltage is applied to the transparent electrode 3a and a positive voltage is applied to the transparent electrode 3b. Then, orientation of those liquid crystal molecules 6 which are positioned between the transparent electrode 3a and the transparent electrode 3b is changed as shown in Figs. 9 and 10. The liquid crystal molecules 6 positioned on the non-electrode portion 18 are not influenced by the voltages, so that the orientation thereof is not changed. A deflecter (polarizer) transmitting light only in the direction shown by the arrow D of Fig. 7 is attached to the transparent plate 2a shown in Fig. 6, and a deflecter (polarizer) transmitting light only in the direction shown by the arrow E of Fig. 7 is attached below the transparent plate 2b. When light is projected from above, an area where the transparent electrode 3a intersect with the transparent electrode 3b in three dimensions is set to a dark state, while an area where the non-electrode portion 18 is positioned is set to a bright state. The reason for this will be described with reference to Fig. 7. Since the angle of light deflected in the direction D is the same as the angle of the liquid crystal molecules 6 between the transparent electrodes 3a and 3b, the light directly passes through the liquid crystal molecules 6. The light deflected in the direction D can not pass through the deflecter transmitting light only in the E direction, so that the area where the transparent electrodes 3a and 3b intersect three dimensionally is set to a dark state. Meanwhile, the angle of light deflected in the direction D is different from the angle of the liquid crystal molecules 6 positioned on the non-electrode portion 18. Therefore, the light is elliptically deflected when it passes through the liquid crystal molecules 6. Part of the elliptically deflected light passes through the deflecter transmitting light only in the direction E, so that the non-electrode portion 18 is set to the bright state. A method of driving the ferroelectric liquid crystal device 1 will be described in the following. Fig. 11 is a partial plan view showing pixel portions and non-pixel portions of the ferroelectric liquid crystal device. Electrodes 19a and 19b correspond to the transparent electrodes 3a shown in Fig. 5, while electrodes 21a and 21b correspond to transparent electrodes 3b shown in Fig. 5. Areas where the electrodes 19a, 19b and 21a and 21b intersect with each other are the pixel portions 23a, 23b, 23c and 23d, respectively. The remaining areas are the non-pixel portions 25. A pulse such as shown by 27a of Fig. 12 is applied to the electrode 19a. A pulse such as shown by 27b of Fig. 12 is applied to the electrode 19b. A pulse such as shown by 27c of Fig. 12 is applied to the electrode 21a. Then, a voltage having the pulse of 27d, that is, the voltage of the pulse 27a - the voltage of the pulse 27c, is applied to the pixel portion 23a, as shown in Fig. 12. The pulse 27d exceeds the threshold value 29. Therefore, the orientation of the liquid crystal molecules arranged in the pixel portion 23a is changed. A voltage of the pulse 27e, that is, the voltage of the pulse 27b - the voltage of the pulse 27c, is applied to the pixel portion 23b. The pulse 27e does not exceed the threshold value 29. Therefore, the liquid crystal molecules in the pixel portion 23b are kept as they are. As shown in Fig. 12, the pulse 27d applied to the pixel portion 23a does not always exceed the threshold value. Such a driving method is called multiplexing driving. The conventional ferroelectric liquid crystal device has the following two drawbacks. The first of these will be described with reference to Figs. 13, 14 and 15. Fig. 13 is a vertical sectional view of a conventional ferroelectric liquid crystal device. Fig. 14 is a cross section of the ferroelectric liquid crystal device shown in Fig. 13 taken from the direction of the arrow XXXII. Fig. 15 is a partial plan view of the display surface of the ferroelectric liquid crystal device shown in Fig. 13. The reference characters in Figs. 13 and 14 denote the same portions denoted by the same reference characters of Figs. 6 and 7. As shown in Fig. 6, the distance between the alignment films 5a and 5b positioned on the non-electrode portion 18 (portion where there is no electrode) is greater than that between the alignment films 5a and 5b on the transparent electrodes 3a and 3b, since the transparent electrodes 3a and 3b are not formed on the non-electrode portion 18. Therefore, the difference of intensity of the polarities between the alignment films 5a and 5b positioned on the non-electrode portion 18 is further reduced than the difference of intensity of polarities between the alignment films 5a and 5b on the transparent electrodes 3a and 3b. Consequently, as shown in Figs. 13 and 14, when liquid crystal is sealed, liquid crystal molecules 6 inclined by ϑ from the normal 10 and the molecules inclined by - ϑ from the normal 10 may possibly be mixed on the non-electrode portion 18. When such a ferroelectric liquid crystal device is used, there are portions 35a transmitting light and portions 35b not transmitting light are mixed on the non-pixel portion 31 which is the non-electrode portion, as shown in Figs. 15. Since there are portions 35a transmitting light and portions 35b not transmitting light mixed, the state of display on the non-pixel portion 31 will be uneven. The reference characters 33 represents pixel portions. The second drawback of the conventional ferroelectric liquid crystal device will be described with reference to Figs. 16, 17 and 18. The same reference characters in Figs. 16 and 17 represent the same portions as represented in Fig. 11. Referring to Fig. 16, the liquid crystal molecules in the pixel portions 23a and 23c are of the same orientation as the liquid crystal molecules 6 on the non-electrode portion 18 shown in Fig. 7. The liquid crystal molecules in the pixel portions 23b and 23d are of the same orientation as the liquid crystal molecules 6 on the electrode portion 3b shown in Fig. 7. Even if the voltage applied to the pixel portions 23a, 23b, 23c and 23d does not exceed the threshold value, regions 37 in which spontaneous polarization of the liquid crystal molecules is inverted are generated after a time lapse of a prescribed period, as shown in Fig. 17. The reason for this may be the fact that the pulse 27d or the pulse 27e shown in Fig. 12 is always applied to the pixel portions 23a, 23b, 23c and 23d. Inversion of the spontaneous polarization of the liquid crystal molecules spreads in the direction shown by the arrow A in Fig. 17. The reason will be described. Fig. 18 is a perspective view showing arrangement of liquid crystal layers in the pixel portion 23a. As shown in Fig. 18, a large number of liquid crystal layers 39 having lateral "V" shape are arranged in the pixel portion 23a. The liquid crystal layers 39 are arranged in the same direction. Since inversion of the spontaneous polarization starts from the liquid crystal molecule in the liquid crystal layer 39 near the side shown by the letter B, the inversion of the spontaneous polarization proceeds from B to C. The direction from B to C is the same as the direction shown by the arrow A in Fig. 17. A ferroelectric liquid crystal device in which the state of display of the pixel portions can be made stable is disclosed in EP-A-0 324 433 (published 19th July 1989). The ferroelectric liquid crystal device shown in EP-A-0 324 433 will be described with reference to Figs. 19, 20, 21 and 22. As shown in Fig. 19, a plurality of electrodes 43 are arranged spaced apart from each other on a main surface of a plate 41. A molybdenum film 45 is formed on one side edge of each of the electrodes 43. Two of such plates 41 are prepared for manufacturing the ferroelectric liquid crystal device. Figs. 21 and 22 are plan views of a plate used for manufacturing the ferroelectric liquid crystal device. As shown in Fig. 21, electrodes 43a are arranged spaced apart from each other on the main surface of the plate 41a. Molybdenum films 45a are formed on one side edge of each of the electrodes 43a. As shown in Fig. 22, electrodes 43b are arranged spaced apart from each other on the plate 41b. The direction of extension of the electrodes 43b is orthogonal to the direction of extension of the electrode 43a shown in Fig. 21. Molybdenum films 45b are formed on one side edge of the electrodes 43b. The plate 41b shown in Fig. 22 is arranged to be opposed to the plate 41a shown in Fig. 21. The edge portion represented by G of the plate 41b faces the edge portion represented by D of the plate 41a, while the edge portion represented by F of the plate 41b faces the edge portion represented by E of the plate 41a. Fig. 20 is a plan view of a pixel portion of the ferroelectric liquid crystal device. The region represented by B in Fig. 18 is on the right side of the pixel 47, and the region C of Fig. 18 is on the left side of the pixel portion 47. Therefore, recess of the lateral "V" shape of the liquid crystal layer 39 shown in Fig. 18 faces the side of the molybdenum film 45b. If the pixel portion 47 is structured in this manner, the liquid crystal molecules in the pixel portion 47 are not inverted unless the voltage applied to the pixel portion 47 exceeds the threshold value. The reason for this may be the fact that there is a molybdenum film 45b on the side B where the liquid crystal molecules tend to be inverted. However, the unevenness of display of the non-pixel portion, which was the first drawback, could not be eliminated by the ferroelectric liquid crystal device disclosed in EP-A-0 324 433. In addition, as shown in Fig. 19, the distance between the electrodes 43 is small, so that there is a possibility of short circuit between electrodes 43, as the molybdenum film 45 may possibly be in contact with the adjacent electrode 43. From US-A-4 744 639, there is known a ferroelectric liquid crystal device in which two plates carrying respective electrodes sandwich liquid crystal therebetween. A spacer element is disposed between adjacent ones of a plurality of strip electrodes on one of the plates. The spacer fills the gap between the two plates in the non-pixel areas of the device, which gap would otherwise contain liquid crystal. The present invention was made to solve the first of the above-described problems of the prior art. An object of the present invention is to provide a ferroelectric liquid crystal device having a structure capable of achieving a uniform display state of the non-pixel portions. Another object of the present invention is to provide a method of manufacturing a ferroelectric liquid crystal device having a structure capable of achieving a uniform display state of the non-pixel portions. In one aspect the invention provides a ferroelectric liquid crystal device comprising: first and second plates arranged opposing to each other to form a space; a second electrode portion formed on a surface of said second plate facing said first plate; a second alignment film formed on said second electrode portion; a plurality of first electrode portions arranged spaced apart from each other on a surface of said first plate facing said second plate; a first alignment film formed on said first electrode portions; and ferroelectric liquid crystal sealed between said first and second alignment films; characterised by: a first filling member positioned between adjacent ones of said first electrode portions and formed of an electrically insulating material, said first alignment film also covering said first filling member; and the thickness of said first filling member being such that the spacing between said alignment films is reduced at the filling member compared with the spacing at the first electrode portions. In another aspect the invention provides a method for manufacturing a ferroelectric liquid crystal device, comprising steps of: forming a plurality of first electrode portions spaced apart from each other on a first plate; forming a photosensitive filling member on said first electrode portions and on a space between adjacent ones of said first electrode portions so as to be thicker than the thickness of said first electrode portions; exposing said photosensitive filling member such that said photosensitive filling member on the space between adjacent ones of said first electrode portions is hardened; removing said photosensitive filling member on said first electrode portions; forming a first alignment film on said first electrode portions and on said photosensitive filling member; forming on a second plate a second electrode portion and a second alignment film on said second electrode portion; arranging said first plate and said second plate so as to oppose each other to form a space between said first alignment film and said second alignment film, including a space between said alignment films at said filling member between the first electrode portions; and sealing ferroelectric liquid crystal in said space. The thickness of the first filling member is made greater than that of the first electrode portions. Therefore, the distance between the first alignment film formed on the first filling member and the second alignment film formed on the second electrode portion is smaller than the distance between the first alignment film formed on the first electrode portions and the second alignment film formed on the second electrode portion. Therefore, the difference of intensity of polarity of the first and second alignment films is large on the first filling member, which is the non-pixel portion, even if the difference between intensity of polarity of the first and second alignment films is small. Accordingly, the orientation of the liquid crystal molecules positioned at the non-pixel portions can be made uniform, so that the display state can be made uniform in the non-pixel portions. An embodiment of the invention will now be described in detail, by way of example only, with reference to the accompanying drawings, in which: Fig. 1 is a perspective view schematically showing an embodiment of the present invention; Fig. 2 is a cross sectional view taken along the direction of the arrow II of Fig. 1; Fig. 3 is a cross sectional view taken along the direction of the arrow III of Fig. 2; Figs. 4A to 4F are cross sectional views showing, in this order, the method of forming a transparent resin layer included in the embodiment of Fig. 1; Fig. 5 is a perspective view schematically showing a conventional ferroelectric liquid crystal device; Fig. 6 is a cross sectional view taken along the direction of the arrow XXIV of Fig. 5 in a first state; Fig. 7 is a cross sectional view taken along the direction of the arrow XXV of Fig. 6; Fig. 8 shows rubbing of a plate; Fig. 9 is a cross sectional view taken along the line XXIV of Fig. 5 in a second state; Fig. 10 is a cross sectional view taken along the direction of the arrow XXVIII of Fig. 9; Fig. 11 is a partial plan view showing pixel portions and non-pixel portions of a conventional ferroelectric liquid crystal device; Fig. 12 is a diagram of waveforms of pulses applied to the electrode portion; Fig. 13 is a cross sectional view of a conventional ferroelectric liquid crystal device in which the display state of non-pixel portions is uneven; Fig. 14 is a cross sectional view taken along the direction of the arrow XXXII of Figs. 13; Fig. 15 is a plan view of non-pixel portion in which the display state is uneven; Figs. 16 and 17 are partial plan views showing pixel portions and non-pixel portions of a conventional ferroelectric liquid crystal device; Fig. 18 is a perspective view showing arrangement of liquid crystal layers in a pixel portion 23a; Fig. 19 is a perspective view of a plate included in another example of a conventional ferroelectric liquid crystal device; Fig. 20 is a plan view of a pixel portion of the other example of a conventional ferroelectric liquid crystal device; Fig. 21 is a plan view of one plate included in the other example of the conventional ferroelectric liquid crystal device; and Fig. 22 is a plan view of the other plate included in the other example of the conventional ferroelectric liquid crystal device. DESCRIPTION OF THE PREFERRED EMBODIMENT Fig. 1 is a perspective view schematically showing an embodiment of the ferroelectric liquid crystal device in accordance with the present invention. Fig. 2 is a cross sectional view of the ferroelectric liquid crystal device 51 of Fig. 1 taken along the direction of the arrow II. Fig. 3 is a cross sectional view of the ferroelectric liquid crystal device 51 shown in Fig. 2 taken along the direction of the arrow III. As shown in Fig. 1, the ferroelectric liquid crystal device 51 comprises transparent plates 53a and 53b, and transparent resin layers 57a and 57b. The transparent plates 53a and 53b are arranged opposed to each other. The transparent plates 53a and 53b are formed of glass. A plurality of transparent electrodes 55a are arranged spaced apart from each other on the main surface of the transparent plate 53a. A plurality of transparent electrodes 55b are arranged spaced apart from each other on the main surface of the transparent plate 53b. The transparent electrodes 55a and 55b are formed of NESA glass. The transparent electrodes 53a and 53b intersect with each other in three dimensions. Transparent resin layers 57a are arranged between the transparent electrodes 55a. Transparent resin layers 57b are arranged between the transparent electrodes 55b. The transparent resin layers 57a and 57b are acrylic transparent resin. In the first embodiment, RFG-7 produced by SEKISUI Fine Chemical Corporation is used as the transparent resin layers 57a and 57b. Ferroelectric liquid crystal is sealed in a space formed by the transparent plates 53a and 53b. The ferroelectric liquid crystal is not shown in Fig. 1. The type of the ferroelectric liquid crystal is chiral smectic C. The first embodiment of the ferroelectric liquid crystal device in accordance with the present invention will be further described with reference to Fig. 2. Transparent electrodes 55a are formed on the transparent plate 53a. An insulating film 59a is formed on the transparent electrode 55a. The insulating film 59a is formed of SiO₂. An alignment film 61a is formed on the insulating film 59a. The alignment film 61a is formed of Nylon-6. A plurality of transparent electrodes 55b are arranged spaced apart from each other on the transparent plate 53b. Transparent resin layers 57b are formed on non-electrode portions 67 between the transparent electrodes 55b. The thickness of the transparent resin layers 57b is larger than that of the transparent electrodes 55b. An insulating film 59b of SiO₂ is formed on the transparent electrodes 55b. An alignment film 61b of Nylon-6 is formed on the insulating film 59b. Layers of liquid crystal molecules 63 are arranged between the alignment films 61a and 61b. The reference numeral 73 denotes a line indicating boundary between layers. The line 73 will be hereinafter referred to as a boundary. The portion represented by 65b indicates that the right end portion of the liquid crystal molecule 63 is projected upward from the surface of the sheet. The portion represented by 65a indicates that the left end portion of the liquid crystal molecule 63 is projected upward from the surface of the sheet. The reference numeral 67 represents spontaneous polarization of the liquid crystal molecule 63. The direction of the head of the arrow corresponds to the positive polarity, and the opposite direction corresponds to negative polarity. As shown in Fig. 3, the liquid crystal molecules 63 positioned on the transparent electrodes 55b have their longitudinal axes inclined by ϑ from the normal 71 of the boundary 73. The liquid crystal molecules 63 on the non electrode portions 67 have their longitudinal axes inclined by -ϑ from the normal 71. In order to realize bistable state of the liquid crystal molecules 63, the difference of intensity of the polarities of the alignment films 61a and 61b is made small in the following manner. As to the transparent plate 53a on which the alignment film 61a is formed, a rubbing roller is brought into contact with the transparent plate 53a, and the rubbing roller is pressed onto the transparent plate 53a by 0.7mm to carry out rubbing. As to the transparent plate 53b on which the alignment film 61b is formed, the rubbing roller is pressed to 1mm. The difference between the intensity of polarities of the alignment films 61a and 61b was made the smallest when rubbing was carried out in this manner on the alignment films 61a and 61b. A method of manufacturing the first embodiment of the ferroelectric liquid crystal device in accordance with the present invention will be described in the following with reference to Figs. 4A to 4F. First, as shown in Fig. 4A, a photo hardening transparent resin is applied by using a spin coater on a transparent plate 53 on which the transparent electrodes 55 are arranged spaced from each other, to form the transparent resin layers 57. The thickness of the transparent electrodes 55 is 2000Å. The thickness of the transparent resin layer 57 positioned on the transparent electrodes 55 is 2000Å. The thickness of the transparent resin layer 57 positioned on the non-electrode portion 67 is 4000Å. The transparent resin layer 57 is prebaked for 30 minutes at 90°C. Thereafter, as shown in Fig. 4B, a photomask 69 is placed above the transparent resin layer 57, and the transparent resin layer 57 is exposed with a high pressure mercury lamp. The photomask 69 is structured such that the transparent resin layer 57 positioned on the transparent electrode 55 is not exposed to light. Therefore, as shown in Fig. 4C, only the portions of the transparent resin layer 57 positioned on the non-electrode portions 67 are hardened by light. Thereafter, the transparent plate 53 is subjected to ultrasonic washing in a butyl cellosolve acetate solution, whereby the transparent resin layers positioned on the transparent electrodes 55 are removed, as shown in Fig. 4D. The transparent resin layers 57 on the non-electrode portions 67 are postbaked for 30 minutes at 180°C. Then, as shown in Fig. 4E, a SiO₂ film 59 is formed by using a spin coater on the transparent plate 53 on which the transparent resin layers 57 are formed. The SiO₂ film is baked. Then, as shown in Fig. 4F, a Nylon-6 film 61 is formed by spin coater on the SiO₂ film 59. The Nylon-6 film 61 is baked. Rubbing was carried on two transparent plates manufactured in this manner. If CS-1014 produced by CHISSO Corp. is used as the ferroelectric liquid crystal, orientation of the liquid crystal layers can be made uniform by carrying antiparallel rubbing. If CS-1013 produced by CHISSO Corp. is used as the ferroelectric liquid crystal, the orientation of the liquid crystal layers can be made uniform by carrying out parallel rubbing. By arranging the two rubbed transparent plates opposing to each other and by sealing ferroelectric liquid crystal in the space formed by the two transparent plates, a ferroelectric liquid crystal device 51 is provided. Cell thickness of the ferroelectric liquid crystal device 51 is 2.0µm. The cell thickness is the distance from the transparent plate 53a to the transparent plate 53b, as represented by J in Fig. 1. As shown in Fig. 2, in the first embodiment of the ferroelectric liquid crystal device in accordance with the present invention, a transparent resin layer 57b thicker than the transparent electrode 55b is provided on the non-electrode portion 67. Therefore, the distance between the alignment films 61a and 61b positioned on the non-electrode portions 67 is shorter than the distance between the alignment films 61a and 61b on the transparent electrodes 55a and 55b. Therefore, on the non-electrode portions 67, the difference between intensity of the polarities of the alignment films 61a and 61b can be enlarged. Accordingly, as shown in Fig. 3, the orientation of the liquid crystal molecules 63 can be made uniform on the non-electrode portions 67. The same can be applied to the liquid crystal molecules positioned on the non-electrode portions 68 shown in Fig. 1. Therefore, in accordance with the first embodiment of the ferroelectric liquid crystal device of the present invention, the state of display of the non-pixel portions can be made uniform. It is preferred that the difference between the height of the transparent resin layer and the transparent electrode is not less than 1/10 of the cell thickness. If the difference is small, the difference between intensities of the polarities of the alignment films positioned on the non-electrode portions becomes small. In accordance with the embodiment, the alignment film positioned on the non-electrode portion is made higher than the alignment film positioned on the electrode portions by providing transparent resin layer on the non-electrode portions. However, the present invention is not limited thereto, and other insulating material may be used instead of the transparent resin layers. Although an insulating film is provided in the first embodiment, the insulating film may not be formed provided that the cell thickness is thick enough to eliminate possibility of short circuit between electrodes. If the electrode portion on one of the plates consists of one electrode layer, then a transparent resin layer may be provided between the electrodes on the plate on which a plurality of electrodes are formed. Although the present invention has been described and illustrated in detail, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, the scope of the present invention being limited only by the terms of the appended claims.

Claims: A ferroelectric liquid crystal device (51), comprising: first and second plates (53b, 53a) arranged opposing to each other to form a space; a second electrode portion (55a) formed on a surface of said second plate facing said first plate; a second alignment film (61a) formed on said second electrode portion; a plurality of first electrode portions (55b) arranged spaced apart from each other on a surface of said first plate facing said second plate; a first alignment film (61b) formed on said first electrode portions; and ferroelectric liquid crystal (63) sealed between said first and second alignment films; characterised by: a first filling member (57b) positioned between adjacent ones of said first electrode portions (55b) and formed of an electrically insulating material, said first alignment film (61b) also covering said first filling member (57b); and the thickness of said first filling member (57b) being such that the spacing between said alignment films (61a, 61b) is reduced at the filling member (57b) compared with the spacing at the first electrode portions (55b). A ferroelectric liquid crystal device according to claim 1, wherein: said second electrode portion comprises a plurality of second electrode portions (55a) arranged spaced apart from each other and crossing said first electrode portions (55b). A ferroelectric liquid crystal device according to claim 2, wherein: a second filling member (57a) is positioned between adjacent ones of said second electrode portions (55a) and formed of an electrically insulating material, said second alignment film (61a) also covering said second filling member (57a); and the thickness of said second filling member (57a) is such that the spacing between said alignment films (61a, 61b) is reduced at the second filling member (57a) compared with the spacing at the second electrode portions (55a). A ferroelectric liquid crystal device according to claim 1, wherein the height of the step between said first filling member (57b) and said first electrode portion (55b) is not less than 1/10 of the cell thickness (J) of said ferroelectric liquid crystal device. A ferroelectric liquid crystal device according to claim 3, wherein the height of the step between said second filling member (57a) and said second electrode portion (55a) is not less than 1/10 of the cell thickness (J) of said ferroelectric liquid crystal device. A method for manufacturing a ferroelectric liquid crystal device, comprising steps of: forming a plurality of first electrode portions (55) spaced apart from each other on a first plate (53); forming a photosensitive filling member (57) on said first electrode portions and on a space between adjacent ones of said first electrode portions so as to be thicker than the thickness of said first electrode portions; exposing said photosensitive filling member such that said photosensitive filling member on the space between adjacent ones of said first electrode portions is hardened; removing said photosensitive filling member on said first electrode portions; forming a first alignment film (61) on said first electrode portions and on said photosensitive filling member; forming on a second plate a second electrode portion and a second alignment film on said second electrode portion; arranging said first plate and said second plate so as to oppose each other to form a space between said first alignment film and said second alignment film, including a space between said alignment films at said filling member between the first electrode portions; and sealing ferroelectric liquid crystal in said space.

Inventors: ITOH NOBUYUKI, NARUTAKI YOZO, SHINOMIYA TOKIHIKO, ITOH, NOBUYUKI, NARUTAKI, YOZO, SHINOMIYA, TOKIHIKO
Applicants: SHARP KK, SHARP KABUSHIKI KAISHA
Application year: 1990
Main classification: G02F1
IPC codes: G02F1