Purified solution containing iron and manganese, and method producing thereof

Abstract: A solution containing iron chloride and manganese chloride, whose phosphorus content is not higher than 0.007 wt.% with respect to the total content of iron and manganese. A method for producing the said solution comprises the steps of dissolving manganese containing raw material in hydrochloric solution; oxidizing the solution; adjusting the pH of the solution to 2.5 ∼ 4.5; separating the insolubles from the solution. This solution can be utilized to produce a mixed powder of an iron oxide and a manganese oxide. And the mixed powder is useful for producing a high-quality soft ferrite.

Description: BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to a purified solution containing iron chloride and manganese chloride and to a method producing thereof. The said purified solution is oxidized by roasting in order to produce a mixed oxide powder containing iron and manganese, thus being useful as a raw material for manufacturing a high-quality soft ferrite of excellent magnetic properties. Prior Art To manufacture soft ferrite, an iron oxide powder, a manganese oxide powder and other metal oxide powders, for example, zinc oxide powder are prepared. And a compounded powder with a compounding ratio of Fe₂O₃:MnO:ZnO, for example, 70.6:14.2:15.2 in weight is produced. The compounded powder is then sintered at about 1,300°C and soft ferrite is manufactured. To manufacture ordinary soft ferrite of ordinary magnetic properties, an iron oxide powder of ordinary grade is used. Stahl und Eisen, 17, Januar 1983 shows a process in which iron oxide powder of ordinary grade is produced by roasting a waste hydrochloric pickling solution of a steel. In the roasting furnace at about 700°C, iron chloride in the solution is oxidized according to the following formula (1). 2FeCl₂ + H₂O + O₂ → Fe₂O₃ + 2HCl (1) In the above process, a waste hydrochloric pickling solution is sprayed into the roasting furnace, powdered Fe₂O₃ is obtained from the roasting furnace. Gaseous HCl in the discharged gas is changed to aqueous hydrochloric acid by any of several known methods. In general this method is simple and the iron oxide powder produced is low in cost. Accordingly the iron oxide powder thus obtained is widely used for manufacturing ordinary soft ferrite with ordinary magnetic properties. However, the iron oxide powder produced by this process is not used for high-quality soft ferrite where more superior magnetic properties are required. This is because in this method, as explained, all impurities contained in the steel are dissolved in a waste hydrochloric pickling solution, and therefore are also included in the iron oxide powder. These impurities in the iron oxide powder impairs the magnetic properties of the soft ferrite. In manufacturing the high-quality soft ferrite, expensive oxide powders of high purity, i.e. a high purity iron oxide and a high purity manganese oxide, are exclusively used. Table 1 shows an example of the impurity content of iron oxide powder and manganese oxide powder for soft ferrite, as well as the impurity content of other materials which can be used as raw materials for both oxides. In Table 1, high-purity iron oxide A or B, and high purity manganese oxide are used for high-quality soft ferrite, and ordinary iron oxide is used for ordinary soft ferrite. In another prior art method shown in KAWATETSU NO JISEISAIRIO (Magnetic raw materials by KAWATETSU) published in 1986 by KAWASAKI Iron and Steel Co., high-purity iron oxide like A or B are produced by a crystal refining method. In producing KH-HP and KH-UP, iron sulphate is crystallized from the aqueous solution thereof, and these crystals are oxidized by roasting to obtain an iron oxide. In this method, however, it can be understood that the impurities are not reduced sufficiently by a single crystallization, because part of the impurities are mixed in the crystals. Thus the obtained crystals are dissolved again in water etc., and the crystallization treatments are repeated, thereby reducing the impurity content. According to this method, an iron oxide powder of high purity, such as the high-purity iron oxide A or B in Table 1, can be obtained. However, the crystal refining method is complicated and the production cost of the iron oxide powder is high because of the repeated crystallizations. Also in case of manganese oxide, impurities can be reduced by electrolysis as shown in DENKAI NISANKA MANGAN (Manganese Dioxide by Electrolysis) published by TOYO SODA KOGYO Co. or by crystal refining method, but the process is complicated and the cost is high as in the case of the high purity iron oxides. Thus, general knowledge about the kind of impurities as well as a permissible content level of the impure elements in the powdered oxide, which impair the magnetic properties of a high quality soft ferrite, has been insufficient. Another method to improve the powdered oxide of ordinary grades to a level sufficient for high-quality soft ferrite has not been found, and the very expensive oxide powders produced by the crystal refining method, where impurities are significantly decreased for the formation of high quality soft ferrite. Summary of the Invention It is therefore an objective of the present invention to produce a new hydrochloric solution which contains substantially higher contents of iron and manganese, and in which harmful impurities are selectively removed sufficiently and from which an oxide powder suitable for high quality soft ferrite can be obtained by the same roasting methods as those in the oxide powder of ordinary grades. According to the present invention, a purified solution is obtained by a dephosporizing treatment of a crude solution keeping a substantially high iron chloride and manganese chloride in the solution and whose phosphorus content is decreased to not higher than 0.007 wt.% with respect to the total content of iron and manganese. In the above, the crude solution means a solution in which ferromanganese, manganese ore or high manganese steel are dissolved respectively or together in a hydrochloric acid solution or waste hydrochloric pickling solution of steel. According to the present invention, phosphorus contained in the soft ferrite distinctly impair the magnetic properties, and by controlling phosphorus content of the hydrochloric solution as explained above, a mixed oxide powder of iron and manganese in which the phosphorus content is sufficiently decreased can be obtained by the ordinary roasting method. Soft ferrite manufactured by using this mixed oxide powder has excellent magnetic properties because the phosphorus content is sufficiently lowered. The purified solution of the present invention can be obtained according to the following steps. The 1st step is to oxidize the crude solution so that the phosphorus contained in the solution is oxidized to P⁵⁺ state. The 2nd step is to neutralize the solution to the pH of 2.5 ∼ 4.5 so that insoluble P⁵⁺ compounds are selectively formed in the solution. The 3rd step is to separate the insoluble compounds from the solution. From this a purified solution due to the present invention, containing the phosphorus as specified above, can be obtained. Brief Description of the Drawings Fig. 1 shows the relation between the P content of compounded powder and AC initial magnetic permeability µiac of the soft ferrite. Fig. 2 shows the relation between the P content of compounded powder and the relative loss factor tanδ/µiac of the soft ferrite. Detailed Description of the Preferred Embodiment of the Invention This invention relates to a purified solution containing iron chloride and manganese chloride wherein characterized by a phosphorus contents to be not higher than 0.007 wt.% with respect to the total content of iron and manganese. The reasons why the phosphorus contents of this invention is specified to be not higher than 0.007 wt.% is explained as follows: No. 1 ∼ No. 15 of Table 3 are compounded powders which the present inventors prepared so that Fe₂O₃:MnO:ZnO of each compounded powder is in the same weight ratio of 70.6:14.2:15.2. Compounded powders of Nos. 1 ∼ 15 are prepared by using powdered oxides of different kinds, and the phosphorus content of the compounded powders are in the range of 0.0023 ∼ 0.015 wt.% as shown in Table 3. Each compounded powder is sintered at a temperature of 1,350°C to make test piece of ring shaped soft ferrite having an outer diameter of 25 mm, an inner diameter of 15 mm and a thickness of 5 mm, and measured an A.C. initial magnetic permeability µiac and a relative loss factor tanδ/µiac at 1 KHz and 25°C in accordance with JIS C2561. The magnetic properties of each test piece are shown in Table 3 and in Fig. 1 and Fig. 2. As shown in Table 3 and in Fig. 1 and Fig. 2, the phosphorus contained in the compounded powder distinctly impairs the magnetic properties of soft ferrite. By controlling the phosphorus content of the compounded powder to be not more than 0.005 wt.%, soft ferrite of excellent magnetic properties can be obtained. The purified solution of the present invention contains phosphorus not higher than 0.007 wt.% with respect to the total content of iron and manganese. By roasting the purified solution, iron and manganese contained in the purified solution are oxidized into an iron oxide and manganese oxide, and then the phosphorus content with respect to the total content of iron oxide and manganese oxide is diluted. Further in preparing the compounded powder, ZnO powder is introduced and the phosphorus content with respect to the compounded powder is diluted. Thus by using the purified solution, containing phosphorus not higher than 0.007 wt.% with respect to the total content of iron and manganese, the compounded powder containing phosphorus of not higher than 0.005 wt.%, can be obtained. This invention relates to a purified solution containing iron chloride and manganese chloride and characterized by a manganese content that is higher than 0.45 wt.% with respect to the total content of iron and manganese. The present inventor et al. invented an iron oxide containing 0.1 ∼ 0.3 wt.% of manganese and having a lower phosphorus content, and therefore applied for patent previously in European Patent Application No. 88121025.6. Herein, the manganese content of 0.1 ∼ 0.3 wt.% of the previous application is less than 0.45 wt.% with respect to the total content of iron and manganese. Accordingly in the present invention manganese content is specified to be higher than 0.45 wt.%. The purified solution of the present invention is produced by removing phosphorus from the crude solution. In this description, the crude solution means the solution being produced by dissolving ferromanganese, manganese ore or high manganese steel respectively or together in a hydrochloric acid solution. Further, since the waste hydrochloric pickling solution of steel contains. free hydrochloric acid, the crude solution of the present invention can be also obtained by adding ferromanganese, manganese ore or high manganese steel respectively or together thereto. The crude solution also include a solution where metallic manganese and/or steel scrap is further dissolved to the above explained crude solution. The manganese content as well as iron content in the crude solution is not specified because it has no particular effect on the removal of the phosphorus from the crude solution. Furthermore, the concentration of hydrochloric acid in the crude solution and the temperature of the crude solution may sufficiently be the concentration and the temperature at which said materials can be dissolved, and are not specified in particular. Ferromanganese usually contains 0.03 ∼ 0.12 wt.% of phosphorus, manganese ore usually contains 0.05 ∼ 0.12 wt.% of phosphorus and steel usually contains 0.02 wt.% of phosphorus. In producing the crude solution, all of the phosphorus contained in the raw materials also dissolve into the hydrochloric acid solution and is contained in the crude solution. Accordingly, the crude solution contains not less than 0.02 wt.% of phosphorus with respect to the total contents of iron and manganese. Thus the crude solution contains phosphorus exceeding the permissible amount for high-quality soft ferrite. The 1st step of the present method is the oxidation of the crude solution. During oxidation, the P contained in the crude solution is oxidized and becomes P⁵⁺, wherein P⁵⁺ forms more easily an insoluble compound in following steps than P³⁺ or other states. The oxidation of the crude solution can be attained by bubbling air, but more effectively, it is desirable to add an oxidizer to the crude solution. For example as an oxidizer, nitric acid solution, chloric acid solution, permanganic acid solution, or manganese dioxide, etc. can be used. For example, by adding 20 lit. of nitric acid with a concentration of 60% in 1 m³ of the crude solution, and boiling for an hour, P in the crude solution can be satisfactory oxidized to the P⁵⁺ state. The 2nd step of the present method is adjusting the pH of the crude solution to 2.5 ∼ 4.5. This adjustment of pH is performed so that P⁵⁺ in the crude solution forms insoluble compounds. As explained in the 1st step, P in the crude solution has an oxidation number of 5+, and P⁵⁺ in the crude solution behaves as in the following formulas (2) ∼ (4). H₃PO₄ ⇄ H⁺ + H₂PO₄⁻ (2) H₂PO₄⁻ ⇄ H⁺ + HPO₄²⁻ (3) HPO₄²⁻ ⇄ H⁺ + PO₄³⁻ (4) When the crude solution is acidic and has a low pH, the dissociation of formulas (3) and (4) does not take place, and H₃PO₄ and H₂PO₄⁻ are only formed in the solution. Then the P cannot be removed as precipitate from the solution because H₃PO₄ and the metallic salts of H₂PO₄⁻ are water soluble. When the pH of the crude solution is raised. to 2.5 or above, dissociation of formulas (3) and (4) take place whereby HPO₄²⁻ and PO₄³⁻ ion are produced. HPO₄²⁻ and PO₄³⁻ ions may combine with metallic ions in the solution and form metallic salts of HPO₄²⁻ and PO₄³⁻, where metallic salts of HPO₄²⁻ and PO₄³⁻ are insoluble in the crude solution, and they can be separated as insolubles from the crude solution. This adjustment of pH may be performed by using, for example, an alkali compound such as aqueous ammonia. It also can be performed by dissolving, for example, a steel scrap into the crude solution, where H⁺ ions of the crude solution are exhausted and the pH is adjusted thereby. The 3rd step of the present method is a separation of the insolubles from the solution. The insolubles formed in the 2nd step of the present method are separated from the solution and the purified solution of the present invention can be obtained. However, in this separation of insolubles it should be understood that the insoluble phosphoric compounds formed in the 2nd step of the present method are very fine in size and they can be separated only by an ultrafiller treatment. The insoluble phosphoric compounds become large by agitating the solution after the pH of the solution is adjusted. Accordingly the insoluble phosphoric compounds can also be separated by usual filter paper or filter cloth when the solution is subjected to the filtration after being agitated. Mechanical stirring of the solution for about 5 hrs or more, or bubbling air of the solution for about 20 minutes or more are suitable for the agitation of the solution. In these treatments, a greater part of phosphorus contained in the solution is held in the precipitate, and a greater part of iron and manganese are held in the filtrate. Thus the purified solution of the present invention which contains iron chloride and manganese chloride and whose phosphorus content is not higher than 0.007 wt.% with respect to the total content of iron and manganese can be obtained. The present inventor et al. produced the crude solutions having the compositions shown in Nos. 1 ∼ 5 of Table 2 by using various kinds of iron materials and manganese materials. No. 1 is the crude solution obtained by dissolving ferromanganese A of Table 1 in hydrochloric acid solution. No. 2 is the crude solution obtained by dissolving ferromanganese B of Table 1 in hydrochloric acid solution. No. 3 is the crude solution obtained by dissolving ferromanganese C of Table 1 in hydrochloric acid solution. No. 4 is the crude solution obtained by dissolving ferromanganese A of Table 1 in waste hydrochloric pickling solution of steel. No. 5 is the crude solution obtained by dissolving austenitic high-manganese steel and ordinary steel is hydrochloric acid solution. Each of these solutions has a phosphorus content of 0.02 wt.% or above with respect to the total content of iron and manganese. These solutions are sprayed into the roasting furnace whose fluidized bed has a temperature of about 700°C, thereby obtaining a mixed oxide powder as shown in Nos. 1 ∼ 5 of Table 2. These mixed oxide powders contain not less than 0.015% of phosphorous and cannot be used for high-quality soft ferrite. Nos. 11 ∼ 15 of Table 2 represent the purified solution being dephosphorized according to the present invention. The purified solution No. 11 was obtained from the crude solution No. 1 of Table 2, No. 12 from No. 2, No. 13 from No. 3, No. 14 from No. 4, and No. 15 from No. 5. These purified solution have remarkably lowered phosphorus contents, and as shown in Nos. 11 ∼ 15 of Table 2, being not higher than 0.007 wt.% with respect to the total content of iron and manganese. The mixed oxide powders of No. 11 ∼ 15 of Table 2, obtained by spraying the purified solution of Nos. 11 ∼ 15 into the roasting furnace of 700°C showed phosphorus content of not higher than 0.005 wt.%. As shown in No. 1 and No. 11 of Table 2, for example, FeCl₂ content and MnCl₂ content of No. 1 solution are almost the same with the FeCl₂ content and MnCl₂ content of No. 11 solution. This means that a greater part of iron and manganese in the crude solution are still in the purified solution after the treatment of the present method, and a loss of iron and manganese during the present method is very small. The present inventor et al. used the mixed oxide powder of No. 1 ∼ No. 15 of Table 2, supplied a shortage of iron oxide content or manganese oxide content with the high purity iron oxide or high purity manganese oxide of Table 1, added further high purity zinc oxide thereto so that the compounded powders of Nos. 1 ∼ 15 each containing Fe₂O₃:MnO:ZnO in the weight ratio of 70.6:14.2:15.2. The mixed oxide powders of Nos. 1 ∼ 15 are used for making the compounded powders of the corresponding No. respectively. Compounded powders of Nos. 1 ∼ 15 were sintered at a temperature of 1,350°C to make test piece of ring shape having an outer diameter of 25 mm, an inner diameter of 15 mm and a thickness of 5 mm, and measured an A.C. initial magnetic permeability µiac and a relative loss factor tanδ/µiac at 1 kHz and 25°C in accordance with JIS C 256, as explained earlier. In Table 3 the compounding ratio of the mixed oxide powder of Table 2, the phosphorus content of the compound powders, µiac and tanδ/µiac are shown. Nos. 1 ∼ 5 of Table 3 used the mixed oxide powder obtained by roasting the crude solutions without the dephosphorizing treatment of the present method, a higher phosphorus content of a compounded powder results when a high compounding ratio of the mixed oxide powders is used, and accordingly the sintered test piece will not have superior magnetic properties. Consequently, mixed oxide powders of Nos. 1 ∼ 5 cannot be used in large amount for manufacturing high-quality soft ferrite. In Table 3, Nos. 11 ∼ 15 represent the embodiments wherein the mixed oxide powders are produced by roasting the purified solution of the present invention. These embodiments have a low phosphorus content of not higher than 0.005 wt.% and always show excellent magnetic properties. Thus the mixed oxide powders produced from the purified solutions of the present invention do not raise the phosphorus content of the compounded powders, and therefore can be used as a mixed oxide powders suitable for high-quality soft ferrite of excellent magnetic properties. Using the purified solution of the present invention, a mixed oxide powder of iron oxide and manganese oxide, whose phosphorus content is sufficiently low can be obtained. This oxide powders can be produced at a lower cost than those obtained by crystal refining method. The high-quality soft ferrite produced by using the mixed oxide powders produced from of the present invention has the same excellent magnetic properties as those produced by using expensive high-purity oxide powders by the crystal refining method.

Claims: A purified solution containing iron chloride and manganese chloride, whose P-content is not higher than 0.007 wt.% with respect to the total content of iron and manganese, and whose Mn-content is higher than 0.45 wt.% with respect to the total content of iron and manganese. A method for producing a purified solution of claim 1 comprising the following steps: obtaining a crude solution by dissolving ferromanganese, manganese ore or high manganese steel respectively or together in hydrochloric solution or waste hydrochloric pickling solution of steel; oxidizing the crude solution by blowing air and/or adding an oxidizer; adjusting the pH of the solution to 2.5 ∼ 4.5; separating the insolubles from the solution.

Inventors: HIRAI NAOE, MORI TERUO, MURASE TOHORU, OKUTANI KATSUNOBU, HIRAI, NAOE, MORI, TERUO, MURASE, TOHORU, OKUTANI, KATSUNOBU
Applicants: CHEMIRITE LTD, TDK CORP, CHEMIRITE, LTD., TDK CORPORATION
Application year: 1989
Main classification: C01G49
IPC codes: C22B47, C01G49, C22B3, C04B35