Spoked wheel reflector employing encapsulated retroreflective tubing

Abstract: A retroreflective tubing adapted to be intertwined among spokes of a wheel, comprising a core material (40), retroreflective microspheres (42A) attached to an outer surface of the core material (40), and a protective encapsulating material (46) surrounding the microspheres (42A). In a preferred embodiment, the cross section of the core material (40) is U-shaped to maximize the retroreflective performance of the tubing, and the encapsulating material (46) provides a multiplicity of sealed airspaces between the outer surface of the retroreflective microspheres (42A) and the inner surface of the encapsulating material (46).

Description: Technical Field This invention relates to safety devices for spoked wheels, specifically those employing retroreflective materials to improve the visibility of bicycle wheels and thereby improve recognition of the bicycle at night. Background Retroreflective materials are widely used in a variety of situations involving vehicle and pedestrian traffic. Retroreflective materials promote safety by improving the visibility of objects illuminated by vehicle headlights or other sources of light. In one such application, the circumference of both of the spoked wheels or tires of a bicycle are retroreflective. The retroreflected image of two circles separated by a fixed distance is quite recognizable as a bicycle, even if the other portions of the bicycle are not retroreflective. Unless viewed perpendicularly to the wheel, the circles are seen as ellipses, but the image is still recognizable as a bicycle. Bicycle tires with retroreflective sidewalls are more expensive than conventional tires, and require replacement of existing non-retroreflective tires. Accordingly, products suitable for addition to bicycles with conventional tires have been developed. Objects which may be added to existing bicycles to create a circular image include those taught by U.S. Patent Nos. 3,834,765 (Trimble) and 4,285,573 (Stone); European Patent Office Publications 0 003 498 (Trimble) and 0 094 700 (Oskam); and German Offenlegungsschrift 27 50 200. Retroreflective materials generally have confined angularity, i.e., they brightly reflect light only within a narrow range of solid angles around a ray of incoming light. In many applications this is not a serious disadvantage, because the retroreflective material may be designed and placed so that the intended observers are always within the preferred narrow angular range. For example, many retroreflective materials are designed to retroreflect rays which lie very nearly on the line normal to the surface of the material. Traffic signs made with such materials may be placed to retroreflect light to the known positions of vehicles on a roadway. Bicycles, by contrast, may be travelling in a variety of directions when in the field of view of an observer. Thus, the circular image should be visible from all angles, including directly ahead of and behind the bicycle. The shapes of bicycle reflectors have been designed to complement the properties of retroreflective materials and thereby improve the visibility of the reflectors from all angles. For example, U.S. Patent 3,834,765 (Trimble) teaches an elongated tubular member which is intertwined among the spokes of the wheel. The curved outer surface of the member ensures that light coming from substantially any direction will strike some portion of the reflective surface within the most efficient angular range of the reflective material. U.S. Patent 4,025,159 (McGrath) teaches a flexible cellular retroreflective sheeting comprising glass microspheres, and employing a transparent encapsulating material to provide air spaces between outer surfaces of the glass microspheres and the inner surface of the encapsulating material. Narrow intersecting bonds support the encapsulating material in spaced relation away from the microspheres to maintain the air spaces. The disclosure of this document is used to form the preamble to the present claim 1. Disclosure of Invention According to this invention there is provided a retroreflective tubing comprising a core material, a retroreflective material comprising glass microspheres attached to an outer surface of the core material, an encapsulating material providing an air space between outer surfaces of said glass microspheres and the inner surface of the encapsulating material, and means for maintaining the air space between the retroreflective material and the inner surface of the encapsulating material, wherein the tubing is sufficiently flexible to be intertwined among spokes of a wheel and to assume a portion of the circular shape of the wheel, characterized in that: the means for maintaining the air space comprises at least two seals positioned between the ends of the tubing and extending between the retroreflective material or the core material and the encapsulating material, each seal being at least slightly spaced from said ends to provide at least one sealed section of tubing between the seals. Brief Description of the Drawing Figure 1 is a side view of an embodiment of the invention as applied near the rim of a bicycle wheel. Figure 2 is an enlarged view of a portion of the bicycle wheel of Figure 1. Figure 3 is an enlarged top view taken along lino 3-3 of Figure 2. Figure 4 is a cross-sectional view taken along line 4-4 of Figure 3. Figure 5 is a cross-sectional view of another embodiment of the invention. Figure 6 is a partial sectional side view of the embodiment of Figure 4. Figure 7 is a side view of another embodiment of the invention, with the retroreflective sheeting 71 partially stripped away. Detailed Description As shown in Figure 1, a bicycle 10 has a wheel 11. Wheel 11 comprises a plurality of spokes 12, rim 13, tire 14, and valve stem 15. An embodiment of the inventive retroreflective tubing 16 is intertwined among the spokes 12. A practical consideration in such an elongated tubular design is the placement of the reflector with respect to the spokes 12 and rim 13. For improved visibility, it is preferred to locate the retroreflective tubing 16 as near the inner circumference of rim 13 as possible, preferably in direct contact, as shown in Figure 1. By so locating the reflector, the retroreflected image will be more uniformly circular when viewed from the side of the wheel, and have a larger circumference, both of which improve visibility. As shown in Figures 2 and 3, at the innermost surface of rim 13, it is necessary to bend the tubing 16 in a slalom-like manner among the spokes. In the arrangement shown, the tension created by intertwining tubing 16 among spokes 12 and/or spoke nipples 17 holds tubing 16 in place. This requires materials flexible enough to allow the tubing to be woven among the spokes as shown. Optionally, the tubing 16 may, but need not, be adhered to rim 13 with external adhesive 18. This also helps maintain tubing 16 in place against rim 13, and additionally may deter theft of the tubing. Figure 4 shows tubing 16 in cross section. Retroreflective tubing 16 comprises core material 40; glass microspheres 42A, backed by reflective material 45 and embedded in bond material 42B; internal adhesive 42C, which adheres bond material 42B to core material 40; and encapsulating material 46. The outer radius of the layer of glass microspheres 42A is less than the inner radius of encapsulating material 46, thereby providing an airspace 44. In the embodiment shown in Figure 4, the cross sections of both the core material 40 and the encapsulating material 46 are circular, but this is not required. In general, the cross section of core material 40 should be such that the retroreflective material will operate efficiently in as large an angular range around the bicycle as possible. Preferably, at least some portion of the core material should be curved away from the inner surface of rim 13. Thus, at least some retroreflective material will be preferentially directed to incidence angles away from the directions perpendicular to the wheel. Furthermore, the cross sections of the encapsulating material and the core material need not be the same. Suitable materials for core material 40 include semirigid plastics which will resist excessive distortion or bending, thereby maintaining the circular shape along the inner circumference of rim 13. Polyolefins, polyvinylchlorides, and nylons are preferred materials. A standard extrusion process is suitable for the manufacture of core material 40. The core material may be solid, as shown in Figure 4, but a hollow construction is preferred to reduce material amount and weight of the final product. The preferred glass microspheres 42A have high refractive index, typically about 1.9. To assemble the microspheres 42A into the bond layer 42B, a procedure such as that taught in U.S. Patent 4,377,988 (Tung, et al.) is employed. The microspheres are first coated in a monolayer on a carrier web such as polyethylene coated paper. Heating the carrier web causes the microspheres to sink partially into the polyethylene, preferably to a depth of about 20 to 50 percent of the diameters of the microspheres. Then the exposed surfaces of the microspheres are covered with a reflective material 45, such as aluminum or silver by vapor deposition, silver by chemical deposition, or dielectric mirrors or coatings as taught in U.S. Patent 3,700,305 (Bingham). A bonding layer 42B, which is preferably a butyl rubber resin or alkyd resin, is applied over the reflective microspheres. Thus, the microspheres 42A are supported within the bonding layer 42B to a depth of about 50 to 80 percent of their diameters. The internal adhesive 42C is applied to the side of the bonding layer 42B opposite the microspheres. A release liner may be used to protect the exposed adhesive. If the bonding layer 42B is added to core material 40 after the latter is cooled from the extrusion process, a suitable internal adhesive 42C is an acrylate adhesive such as type Y9469 available from the Minnesota Mining and Manufacturing Company. If bonding layer 42B is added immediately after extrusion of core material 40, adhesive 42C is preferably a polyurethane-based product such as type 5713 available from the B.F. Goodrich Company. The carrier web may be removed before or after the internal adhesive 42C is applied to the core material, exposing the surfaces of the microspheres 42A. If a release liner was used to protect the exposed internal adhesive, it is removed before the internal adhesive is applied to the core material. The result is a tubing which is substantially covered by a retroreflective layer. A factor affecting performance of the retroreflective microspheres 42A is whether they are in contact with water or air, which differ in their indices of refraction. The preferred glass microspheres 42A have index of refraction between about 1.8 and 2.0, and are designed to refract light which has passed through air immediately before entering the microspheres. However, traffic safety devices such as the present invention are exposed to a variety of weather conditions, including rain. Because the indices of refraction of air and water are different (1.0 and 1.33, respectively), the retroreflective performance of the microspheres is affected significantly when they are wet. Thus, in the preferred embodiment, an airspace 44 helps ensure that the glass microspheres 42A will function as designed even when the outermost surface of the encapsulating material 46 is wet. The encapsulating material 46 may be colorless or colored if desired, but must be transparent to the visible light of vehicle headlights. Like the core material 40, the encapsulating material 46 should resist excessive distortion or bending, so that tubing 16 will maintain the preferred shape and location against rim 13. Additionally, encapsulating material 46 should be abrasion resistant. Suitable materials include: (1) polyurethanes, such as type 58810 available from the B.F. Goodrich Company; (2) polymers of ethylene acrylic acids; or (3) thermoplastic materials produced from ionomer resins, such as "SURLYN" type 9910 available from the E.I. DuPont de Nemours Company. Polyvinylchlorides are also suitable but are not as resistant to abrasion. Standard extrusion techniques are suitable for the manufacture of encapsulating material 46. A preferred process employs an extrusion die with a circular center hole, through which the previously made microsphere-coated core material 40 passes. The center hole of the die is surrounded by a concentric annular hole through which the encapsulating material 46 is extruded. The circular and annular holes are separated by a radial amount sufficient to provide the airspace 44 in the final extruded construction. External adhesive 18, if used, preferably comprises a thin foam coated on both sides with pressure sensitive adhesives. An acceptable material is type 4032, available from the Minnesota Mining and Manufacturing Company. In general, the external adhesive 18 must adhere strongly to both the encapsulating material 46 and typical wheel rims. In the case of adhesion to the encapsulating material, the preferred process removes lengths of external adhesive, cut to proper width, from rolls and laminates them onto continuous lengths of tubing. Some means for maintaining the airspace should be provided, to prevent water and other contaminants from entering at the ends of the tubing. For example, U.S. Patent 3,834,765 (Trimble), at Column 3, lines 15-20 teaches the use of a plug or sleeve to connect ends of tubing, but does not suggest that the plug or sleeve could also seal the tubing. Such a plug or sleeve is suitable for hermetically sealing the inventive tubing, however, if manufactured to fit tightly in each end. Additionally, but not required, the plug or sleeve could incorporate a hole designed to fit around the valve stem. This is appropriate if the tubing is placed on the wheel so that the ends meet near the valve stem, as shown in Figure 1. The fitted plug or sleeve then helps keep the tubing in place around the wheel rim. If a hole is not provided in the plug or sleeve, the ends of the tubing may meet at any convenient location around the wheel. The plug or sleeve may also be retroreflective, but need not be. For the present invention, the airspace is maintained by hermetically sealing the encapsulating material to the layer of microspheres or core material. Figure 6 shows a partial sectional side view of tubing 16 of Figure 4, with only the encapsulating material shown in cross section, and no external adhesive provided. The encapsulating material 46 may be sealed in any manner which fully surrounds the tubing in a substantially circumferential path, as accomplished for example by the circular seals 60. There must be at least two seals present after the tubing is cut to a suitable length, so that there will be at least one hermetically sealed section of tubing between the seals. Preferably, each of the minimum two seals will be as close to an opposite end of the cut length as possible, to maximize the amount of hermetically sealed retroreflective material. For a manufacturing process which produces continuously extruded tubing, this preference implies two closely positioned seals between which a cut must be accurately placed. Such close tolerance cutting is not desired in mass production processes. Thus, in the preferred embodiment, a multiplicity of somewhat regularly and closely spaced seals is provided, which allows for less precision in the locations of the cuts. Furthermore, should the encapsulating layer be damaged at a particular location between two closely spaced seals, water and contaminants are less likely to affect the retroreflective performance of the entire length of tubing. The seals may be created immediately after extruding encapsulating material 46 around the retroreflective core as described above. For example, seals 60 may be formed while encapsulating material 46 is still in a semifluid state by directly crimping the encapsulating material onto the microsphere-covered core tubing. Once the heat and/or pressure of forming are removed, e.g., by quenching in water, the crimped encapsulating material holds fast to the layer of microspheres in the crimped, sealed shape, as shown in Figure 6. The sealing method may affect the choice of preferred materials. For example, in process of producing the crimped, thermally formed seal of Figure 6, the freely-flowing encapsulating material 46 tends to surround the microspheres and thus also directly contact bond layer 42B. Therefore, compatibility of the encapsulating and bond materials should be considered. If either DuPont "SURLYN" type 9910 resin or a polymer of ethylene acrylic acid is used for encapsulating material 46, a compatible bond layer 42B is a polymer or ethylene acrylic acid designated by DuPont as "ELVAX" type 5950. If a polyvinlychloride (such as type 2222C available from Alpha Chemical and Plastics Company) is used, a suitable bond layer 42A is a mixture of 83.5 percent (by weight) polyurethane resin and 16.5 percent melamine formaldehyde polymer. Example 1 Two suitable lengths of tubing were constructed to compare the performance of a construction employing retroreflective microspheres (Sample A) with that of a construction employing a flexible cube-corner retroreflective material (Sample B). A conventionally extruded core material of hollow 5 mm diameter polyethylene was used in each sample. In Sample A, the embodiment of Figure 4 was used, and thus the core material 40 was coated with a layer of 65 micron diameter (average) glass microspheres 42A with a refractive index of 1.9. In Sample B, a type of flexible cube-corner retroreflective material, available commercially from Reflexite Corporation and designated as 147-1564 by that company, was used in lieu of a sheeting of retroreflective microspheres. To construct the retroreflective layer of Sample A, a flexible, adhesive-backed retroreflective material was created and wrapped around the core material. The glass microspheres 42A were coated in a monolayer on a carrier web of polyethylene coated paper and heated to sink partially into the polyethylene. The exposed surfaces of the microspheres were then covered first by vapor deposited aluminum layer 45, and next with bonding layer 42B. Bonding layer 42B was a mixture comprising (by weight) 55 percent of a high-acrylonitrile acrylonitrile-butadiene rubber ("HYCAR" 1001 supplied by B.F. Goodrich Company), 35 percent of a thermosetting penolic resin ("DUREZ" type 175 supplied by Hooker Chemical Corporation), and 10 percent of dioctylphthalate as a plasticizer. On the bonding layer 42B, type M41 aggressive acrylate PSA, available from the Minnesota Mining and Manufacturing Company, was applied to serve as internal adhesive 42C. Next, the carrier web was removed, leaving a layer of reflective microspheres embedded in one side of bonding layer 42B. Then the microsphere-embedded bonding layer 42B was adhered to the core material 40 by wrapping the combination around the core layer and applying pressure. To construct the retroreflective layer of Sample B, the flexible cube-corner material was simply wrapped around the core material. No analogue of internal adhesive 42C was used, as the encapsulating layer (described below) sufficiently held the flexible sheeting in place. Each sample was concentrically encapsulated with a layer of 0.38 mm thick ionomer resin, "SURLYN" type 9910 available from E.I. DuPont de Nemours Company. No hermetic seals between sections of tubing were created in either sample for test purposes, although to form tubing according to the invention seals would be required. Retroreflective measurements were made using standard calibrated equipment designed to measure the retroreflected brightness of visible light striking the samples at 4 degrees incidence angle and 0.2 degrees observation angle. The measured brightness of the average of 12 measurements for Sample A was approximately three times greater than that of the average of 12 measurements for Sample B. Figure 5 is a cross-sectional view of another embodiment of the invention. Retroreflective tubing 50 comprises a core material 56, glass microspheres 52A, bond material 52B, support layer 52C, and specular reflectors 55. Because of the substantially "U-shaped" cross section of this embodiment, the core material 56 also serves to encapsulate the retroreflective glass microspheres 52A, thereby providing an airspace 54. Tubing 50 is attached to rim 53 by external adhesive 58. To produce tubing 50 in a continuous extrusion process, it is preferable to construct the layer of embedded retroreflective microspheres on support layer 52C as a separate step, prior to the extrusion of the U-shaped core material 56 around support layer 52C. A common heavyweight paper is a suitable material for support layer 52C, because it adheres well to the preferred bond materials and thermally sets into the preferred core materials. In other respects, the preferred materials for this embodiment are the same as for analogous members of the embodiment of Figure 4. The embodiment of Figure 5 is preferred because the retroreflective material is used efficiently, and the amount of retroreflective material is decreased. The two substantially flat side portions of the U-shaped configuration exploit the ability of the microspheres to retroreflect light of fairly large incidence angle. These portions thus operate much like the flat sheetings known in the art. The curved portion presents at least some retroreflective material to substantially all directions between perpendicular to the wheel and the direction of travel. Thus, the retroreflected image is visible from a greater range of directions around the bicycle. Also, the U-shape reduces the amounts of materials required, because the portion of the tubing facing the rim does not have microspheres, bonding layer, or internal adhesive.

Claims: A retroreflective tubing (16) comprising a core material (40), a retroreflective material (42a, 45) comprising glass microspheres attached to an outer surface of the core material, an encapsulating material (46) providing an air space (44) between outer surfaces of said glass microspheres (42a) and the inner surface of the encapsulating material (46), and means for maintaining the air space between the retroreflective material and the inner surface of the encapsulating material, wherein the tubing is sufficiently flexible to be intertwined among spokes (12) of a wheel (11) and to assume a portion of the circular shape of the wheel, characterized in that: the means for maintaining the air space comprises at least two seals positioned between the ends of the tubing and extending between the retroreflective material or the core material and the encapsulating material, each seal being at least slightly spaced from said ends to provide at least one sealed section of tubing between the seals. The retroreflective tubing of claim 1 in which a multiplicity of regularly spaced seals (60) maintains multiple spaces (44) between the retroreflective material and the inner surface of the encapsulating material. The retroreflective tubing of any preceding claim in which the tubing (16) has a circular cross section. The retroreflective tubing of any of claims 1 to 3 in which the tubing (16) has a substantially "U-shaped" cross section. The retroreflective tubing of any preceding claim further comprising an adhesive (18) located in the outermost surface of the tubing (16). The retroreflective tubing according to any preceding claim in combination with a spoked wheel (11) such that the retroreflective tubing (16) is intertwined among the spokes (12) of the wheel (16).

Inventors: BACON CHESTER A JR C O MINNESO, CODERRE JAMES C C O MINNESOTA, BACON, CHESTER A., JR. C/O MINNESOTA MINING AND, CODERRE, JAMES C. C/O MINNESOTA MINING AND
Applicants: MINNESOTA MINING & MFG, MINNESOTA MINING AND MANUFACTURING COMPANY
Application year: 1989
Main classification: B62J6
IPC codes: B62J6, B60B7