Carbonylation process

Abstract: A process and novel catalyst for the carbonylation of one or more of alcohols, ethers and ether alcohols to esters and, optionally, to carboxylic acids. The reaction is effected in the vapor state over a solid catalyst comprising a polyoxometalate anion in which the metal is at least one taken from Group V and VI of the Periodic Chart of the Elements complexed with a cation from a member of Group VIIIA of the Periodic Chart of the Elements. Preferably, the catalyst is deposited on a support that is inert to the reaction. The preferred support is silica.

Description: Alcohols, ethers and ether alcohols are carbonylated to esters and, optionally, to carboxylic acids, by reaction in the vapor state over a solid catalyst comprising a polyoxometalate anion in which the metal is at least one taken from Group V and VI of the Periodic Chart of the Elements (such as molybdenum, tungsten, vanadium, niobium, chromium, and tantalum), complexed with at least one Group VIIIA (of the Periodic Chart of the Elements) cation, such as Fe, Ru, Os, Co, Rh, Ir, Ni, Pd and Pt. Preferably, the catalyst is deposited on a support that is inert to the reaction. The preferred support is silica. Carbonylation of alcohols and ethers to their corresponding esters is a well known art and is illustrated in Equations 1 and 2 below. (1) 2ROH + CO → RC(O)OR + H₂O (2) ROR' + CO → RC(O)OR' In addition, alcohols can be carbonylated to carboxylic acids as shown in Equation 3, below. (3) ROH + CO → RC(O)OH Carbonylation of methanol, equations 1 and 3, is a well known reaction and is traditionally carried out in the liquid phase with a catalyst. The catalyst typically comprises a Group VIII metal, a halide promoter (normally some form of iodide) and occasionally a ligand such as PR₃ or NR₃ (R being organic moiety). The most common catalyst for a liquid phase system is Rh in combination with HI/CH₃I. This catalyst is considered "state of the art' and is described in U.S. Patent No. 3,769,329. This technology/catalyst is utilized in many commercial processes that generate acetic acid via methanol carbonylation. The operating conditions are about 180 - 200°C. and about 3.1 MPa (450 psi)CO with > 95% selectivity to methyl acetate/acetic acid. Prior to the development of the Rh and HI/CH₃I system, the reaction was carried out in a liquid phase system with Co-I catalysts such as described in U.S. Patent No. 3,060,233. The operating conditions are about 200°C. and about 48.26-68.95 MPa (7,000-10,000 psi)CO. The product selectivity is about 93%. A number of researchers have described the use of Ni-based catalysts for the carbonylation reaction. An example is EP 18 927. The catalyst of that publication consists of Ni and a combination of ionic iodides (example: KI) and covalent iodides (example: CH₃I). The reaction is carried out at about 150°C. and about 5.5 - 6.9 MPa (800-1,000 psi)CO. All of the liquid phase catalysts that generate methyl acetate/acetic acid at commercially acceptable rates and selectivities require the use of an iodide promoter, typically CH₃I and/or HI, and high pressure (at least about 3.1 MPas 450 psi). The iodides are highly corrosive and necessitate the use of expensive corrosion resistant materials of construction. In addition, separation of the catalyst is a major problem and requires special equipment. Vapor phase carbonylation of methanol has the advantage of easy product separation from the catalyst. In most cases, patents describing homogeneous catalysts also claim that the reaction can be carried out in the vapor phase [e.g., methanol and an iodide containing compound (CH₃I) are co-fed] with the catalyst supported on a material such as silica (SiO₂) or alumina (Al₂0₃). Rarely are examples given. The following descriptions refer to references which deal only with vapor phase carbonylation. A considerable amount of work has been carried out on heterogeneous versions of the Rh/CH₃I system described above, see for example, Journal of Catalysis ( 13 , p. 106, 1969 and 27 , p. 389, 1972). In a typical illustration, Rh is supported on activated carbon and a gaseous mixture of CO, CH₃OH, and CH₃I is passed over the catalyst at 175-250°C. and 2.07 MPa (300 psi).The catalyst is active and high yields of acetic acid/methyl acetate are obtained. In similar work, Rh is impregnated on Al₂O₃ ( Krzywicki et . al ., Bull. Soc. Chim. France , 5 , p. 1094, 1975), SiO₂ and TiO₂ ( Krzywicki et . al ., J. Mol. Cat. , 6 , p. 431, 1979) or zeolite-encapsulated (Schwartz et.al., J. Mol. Cat. , 22 , p. 389, 1984). In both cases CH₃OH and CH₃I are co-fed to the reactor containing the catalyst. It should be noted that in all these examples CH₃I is required in order for the carbonylation reaction to work. In JA 59139330, the carbonylation catalyst consists of Ni supported on activated carbon. The reaction is carried out at 200-300°C. and 1.03 MPa (150 psi) with a feed mixture of CO : CH₃OH : CH₃I = 5 : 1 : 0.01. At 300°C., the methanol conversion is 100% and the acetic acid/methyl acetate selectivity is > 95%. In JA 59172436 the same catalyst is utilized to carbonylate dimethyl ether. In DE 3323654 a CH₃OH/CH₃I feed mixture is carbonylated with a Pd-Ni catalyst supported on activated carbon. The reaction is carried out at 300°C. and 0.1 MPa (1 atm)CO. Gates , J. Mol. Cat ., 3 , p. 1, 1977, reports that Rh impregnated in crosslinked polystyrene is a vapor phase catalyst for the carbonylation of CH₃OH. Catalyst activity and stability are low. In JA 56104838 and JA 56104839 various Group VIII metals (Rh, Ni, Pd, Ru, Co) and rare earth metal oxides (Cs, La) are supported on silica. Methanol carbonylation is carried out at 150-200°C. and 0.1-0.5 MPa (1-5 atm)CO, and methyl acetate selectivity is high. In these examples, CH₃I is not utilized in the reaction feed. Vapor phase processes that need CH₃I as a promoter will be corrosive and require expensive materials of construction. In addition, extensive separation/purification procedures are required in order to remove iodides from the product. Heteropoly acids are well known compounds. The name "heteropoly acids" refers to a broad class of compounds of varying composition. A good general review of their physical properties is given by Tisgdinos in Climax Molybdenum Company, Bulletin Cdb-12a, 1969. The use of heteropoly acids in many areas of catalysis is well known including dehydration of alcohols, Friedel-Crafts type reactions, oxidative dehydrogenation and partial oxidation of organic compounds. For examples see Matveev, et. al., J. Mol. Cat. , 38 , 345, 1986, Dun, et. al., Applied Catalysis , 21 , 61, 1986, Nomiya, et. al., Bull. Chem. Soc. Jap. , 53 , 3719, 1980, and Izumi, et. al. J. Mol. Cat. , 18, 299, 1983. Recently, much attention has been given to heteropoly acids as a catalyst for the conversion of methanol into hydrocarbons: (4) xCH₃OH → CH₂=CH₂ + CH₃CH=CH₂ + other hydrocarbons See Moffat , et.al ., J. of Cat. , 77 , p. 473, 1982, Ono , et . al . Bull. Chem. Soc. Jap ., 55 , p. 2657, 1982, and Moffat , et . al ., J. of Cat. , 81 , p. 61 , 1983. This reaction is carried out in the vapor phase (300-375°C.) and the products include ethylene, propylene and saturated C₁₋₅ hydrocarbons. Reaction 4 dominates the known chemistry of reactions of methanol in the presence of heteropoly acids. It was therefore unexpected to find that methanol carbonylation could be carried out with heteropoly acids. Hetero polyacids and polyoxometalate anions constitute well recognized compositions. They embrace the well-known complexes called isopolyoxoanions and heteropolyoxoanions. They are represented by the general formulas [M m O y ] p- Isopolyanions [X x M m O y ] q- Heteropolyanions (x ≦ m) wherein M is at least one metal taken from Group V and VI of the Periodic Chart of the Elements (such as molybdenum, tungsten, vanadium, niobium, chromium, and tantalum) in their highest (d⁰, d¹) oxidation states, and X is a heteroatom from all groups of the Periodic Chart of the Elements with the possible exception of the rare gases. This invention relates to a novel vapor phase carbonylation process of alcohols and ethers which utilizes polyoxometalate anions as the catalysts and to the catalysts. The process involves the carbonylation of one or more of alcohols, ethers, and ether alcohols to esters and, optionally, to carboxylic acids, by reaction thereof in the vapor state over a solid catalyst comprising a polyoxometalate anion in which the metal is at least one taken from Group V and VI of the Periodic Chart of the Elements complexed with a cation from a member of Group VIIIA of the Periodic Chart of the Elements. The process of the invention, in a preferred embodiment, involves the carbonylation of one or more of alcohols, such as mono- and polyhydric alcohols, alkylethers, such as alkyl or alkylene mono- and polyethers, and alkyl ether alcohols to alkyl alkane monoesters and diesters and, optionally, to alkane monocarboxylic or dicarboxylic acids, by reaction in the vapor state over a solid catalyst comprising a polyoxometalate anion in which the metal is at least one taken from Group V and VI of the Periodic Chart of the Elements (such as molybdenum, tungsten, vanadium, niobium, chromium, and tantalum), complexed with at least one Group VIIIA (of the Periodic Chart of the Elements) cation, such as Fe, Ru, Os, Co, Rh, Ir, Ni, Pd and Pt. Preferably, the catalyst is deposited on a support that is inert to the reaction. The preferred support is silica, especially a high surface area silica. The invention is directed to a process of converting alcohols and ethers to carboxylic acids and esters by the carbonylation of the alcohols and ethers with carbon monoxide in the presence of a metal ion exchanged heteropoly acid supported on an inert support. The alcohols and ethers that may be carbonylated by the process of the invention include any alcohol and ether compound or combination of the two. They are preferably exemplified by alcohols and ethers in which an aliphatic carbon atom is directly bonded to an oxygen atom of either an alcoholic hydroxyl group in the compound or an ether oxygen in the compound. Such compounds may contain aromatic groups. The preferred alcohols and ethers that may be carbonylated by the process of the invention include alkanols of 1 to about 20 carbon atoms, alkane polyols of 2 to about 24 carbon atoms, alkyl monoethers of 2 to about 20 carbon atoms, alkyl alkylene polyethers of 4 to about 40 carbon atoms and alkoxyalkanols of 3 to about 20 carbon atoms. Illustrative of suitable alcohols and ethers that may be carbonylated according to the process of the invention are: The process of the invention involves providing the alcohol and/ether in the vapor state and passing the vapor over a bed containing the solid catalyst comprising a polyoxometalate anion in which the metal is at least one taken from Group V and VI of the Periodic Chart of the Elements (such as molybdenum, tungsten, vanadium, niobium, chromium, and tantalum), complexed with at least one Group VIIIA (of the Periodic Chart of the Elements) cation, such as Fe, Ru, Os, Co, Rh, Ir, Ni, Pd and Pt. The temperature at which the reaction is effected is not seen to be narrowly critical. A temperature between about 100°C. and about 350°C. is usable. Preferably, the temperature of the reaction is between about 125°C. and about 325°C., and temperatures between about 150°C. and about 300°C. are most preferred. The reaction pressure accommodates the requirement that the reactants be fed to the reactor in the vapor state. However, the pressure at which the reaction may be carried out may range from about 0.1 - 101.3 MPa (1 - 1000 atm), with pressures of greater than 0.1 MPa (1 atm) to about 0.35 MPa (35 atm) being preferred. The particular reactants and the rate of reaction will impact on the pressure of the reaction zone. The reaction zone is where the catalyst is located. The reaction may be carried out in a tubular reactor using a fixed bed of the catalyst. The reactants may be fed to the catalyst by feeding down or up, or a combination of both, to a fixed bed located in an upright tubular reactor. It is preferred to use a reactor design that operates by plug flow and causes the minimal turbulence in the reaction zone. The reaction may be effected in a dynamic bed of the catalyst. In such a reaction, the bed of catalyst is moving such as in the case of a fluid bed of the catalyst. The gas hourly space velocity of the reactants through the reaction zone may be over a broad range. For example, the GHSV may range from about 50 to about 50,000 hr.⁻¹, preferably from about 900 to about 25,000 hr.⁻¹. The liquid hourly space velocity to the reactor when the feed is vaporized within the reactor may range from about 0.01 to about 10 hr.⁻¹. Where the alcohol, ether and/or the ether alcohol reactant is a higher boiling material not easily vaporized it can be diluted with a lower boiling nonreactive solvent or diluent and thus transported over the solid catalyst. The degree of dilution in some cases can be quite extreme and of course, such conditions will adversely affect the cost of carbonylation. Suitable solvents and diluents include aliphatic and aromatic hydrocarbons, halogenated hydrocarbons, esters, ketones, and the like. The invention involves a new family of catalysts for carrying out the carbonylation reactions herein described such as the carbonylation of methanol or dimethyl ether to methyl acetate/acetic acid. The general formula of a preferred form of the heteropoly acid used in the practice of the invention is M[Q₁₂ PO₄₀] where M is a Group VIII metal or a combination of Group VIII metals, Q is one or more of tungsten, molybdenum, vanadium, niobium, chromium, and tantalum, P is phosphorus, and O is oxygen. In a particularly preferred embodiment of the invention, Q is tungsten or molybdenum or a mixture of the two. The preferred catalyst is derived from heteropoly acids of the formula H₃W₁₂PO₄₀xH₂O. They are acids and generate H⁺. (5) H₃W₁₂PO₄₀ → W₁₂PO₄₀⁻³ + 3H⁺ The preferred catalysts comprise metal ion exchanged heteropoly acids of the general formula M[W₁₂PO₄₀] where M is as defined above, W is tungsten, and P and O are as defined above supported on a SiO₂ support. The carbonylation reaction is carried out in the vapor phase. A wide variety of catalysts were screened. The preferred catalysts are those where M is Rh, Rh/Pd combinations, Ir, Ir/Rh combinations, Ir/Pd combinations and Ir/Co combinations. H₃W₁₂PO₄₀ can be chemically modified in several ways. The most straight forward approach is to exchange the acidic protons with a metal ion: (6) H₃W₁₂PO₄₀ + M⁺ → M₃W₁₂PO₄₀ + 3H⁺ Any metal ion M⁺ or a combination of ions capable of satisfying the heteropoly acid valence requirements can be utilized. Removal of all the H+ is not required. For example, the reaction with Co⁺² would yield: (7) H₃W₁₂PO₄₀ + Co⁺² → H[CoW₁₂PO₄₀] + 2H⁺ These catalyst compositions are based on idealized stoichiometries such as that shown by equation (7) immediately above. The exact structure and composition of the ultimate catalyst (i.e., the composition effecting the catalytic activity as contrasted with the starting heteropoly acid) is not known. The catalyst structure may exist as monomers, dimers and so forth. The waters of hydration are not known and are not included in the catalyst formulas. All of the M[W₁₂PO₄₀]/SiO₂ catalysts utilized herein as catalyst precursors here prepared in a similar manner, a typical example is as follows: Under N₂ at room temperature, RhCl₃H₂O (0.47 g., 1.8 mmoles) was dissolved in 50 milliliters of methanol and stirred for 0.5 hr. H₃W₁₂PO₄₀ (15-20 wt.% water, 6.5 g., 1.8 mmoles) was added and this solution was stirred for 1.0 hour. To the solution was added 3.9 g. of grade 12 silica gel (SiO₂) and the resulting slurry was stirred for a additional 4.0 hours. The methanol was then removed at 80°C. under vacuum yielding a red powder. If needed, the flask was further heated with a heat gun until the powder was free flowing. The material was placed in a vial and stored under N₂. The empirical formula of the composition is Rh[W₁₂PO₄₀]/SiO₂. Some of the M[W₁₂PO₄₀] catalysts were prepared with metal nitrate salts. No difference in catalytic activity was seen between Rh[W₁₂PO₄₀] prepared from chloride, nitrate or AcAc (acetylacetonate) containing Rh salts. H₃[Mo x W y PO₄₀] acids were prepared by the procedure of J. Bailar , Inorganic Synthesis , 1 , p. 132, (1939) and Na₈[Rh₂W₁₂O₄₂] was prepared by procedures analogous to Na₈[Co₂W₁₂O₄₂] as reported by L. Baker and T. McCutcheon , J. Am.Chem. Soc. , 78 , p. 4503, (1956). As illustrated above, the heteropoly acid is impregnated on the support using conventional procedures. The choice of the support is not appreciated to be limiting factor in the operation of the invention. The limited experience with the selection of supports relative to the supports effect on the activity of the catalyst suggests that the support should have a reasonably high surface area. It is preferred that the heteropoly acid be deposited on an inorganic support that has a relatively high surface area, such as a surface area of at least about 100 square meters per gram determined by the BET method. In the preferred embodiment of the invention, the surface area of the support onto which the heteropoly acid is deposited and in contact with, has a surface area of at least about 200 square meter per gram, most preferably at least about 250 square meter per gram Typical support materials suitable for the invention are the silicas, the gamma-aluminas, the titanias, the alumina silicates, the high surface area clays, and the like. Particularly desirable are the mixed composite supports in which the high surface area support is deposited over a lower surface area support. For example, a silica gel deposited and cured on the surface of an alpha-alumina provides the high surface area for the subsequent deposition of the heteropoly acid onto the silica gel coating and the thermal stability provided by the low surface area alpha-alumina. The impregnation step simply involves the coating of the support with the heteropoly acid and then drying the coating on the support to fix it. The drying temperature is not narrowly critical and can range from about 100°C to about 600°C. for a period of about 5 seconds to about 8 hours. The lower the temperature, the longer will be the heating period and the higher the temperature, the shorter will be the beating period. The most commercially interesting reactants are methanol and dimethyl ether. The products are methyl acetate and acetic acid. The methyl acetate selectivity can be at least 95% at 225°C. and 0.1 MPa (1 atm.) total operating pressure. (8) 2CH₃OH + CO → CH₃C(O)OCH₃ + H₂O (9) CH₃OCH₃ + CO → CH₃C(O)OCH₃ In addition, methanol can be carbonylated to acetic acid as shown in Equation 10, below. (10) ROH + CO → RC(O)OH In the case of the carbonylation of methanol, dehydration occurs as a side reaction due to the acidic nature of the heteropoly acid catalysts of the invention, e.g., the M[W₁₂PO₄₀] catalysts. Dehydration results in the formation of dimethyl ether as shown by equation 11. (11) 2CH₃OH → CH₃OCH₃ + H₂O Since dimethyl ether is carbonylated to methyl acetate (equation 6) it can be recycled back to the reactor with no loss in methanol efficiency. Thus, the feed to the reactor can comprise methanol, dimethyl ether or a combination of both. In the examples which follow, the GHSV = 900 hr¹ and the LHSV = 0.15 hr¹. The reactor was a clean 1/4" stainless steel tube packed with glass wool, 2 milliliter of catalyst and additional glass wool. The tube was placed in an aluminum block surrounded by a heater and connected to the feed and exit lines. The CO flow was started, the temperature of the feed/exit lines adjusted to 160°C. and the reactor taken to the desired temperature. At temperature the methanol feed was started and the system was allowed to equilibrate 0.5 hr. Each experiment was normally carried out for 6 hr. The gas stream exiting the reactor was analyzed with a HP 5830 gas chromatograph equipped with a TC detector and a 10' x 1/8" column packed with Poropak Super Q. The following program was used: temp 1 = 50°C., time 1 = 0 min., rate = 15 degrees/min., temp 2 = 225°C., time 2 = 20 min. Examples 1-9 The various MW₁₂PO 40/ SiO₂ compounds listed in Table 1 below were prepared on a silica support having a surface area of about 683 m² /gram according to the procedure described above and examined as catalysts for the carbonylation of methanol. The experiments were carried out at 225°C. and 0.1 MPa (1 atm.) with LHSV = 0.15 hr⁻¹ and GHSV = 900 hr⁻¹. The results are listed in Table 1. The reported catalyst compositions are idealized stoichiometries. Ex. No. Catalyst Product Yield MeOH DME MeOAc 1 IrW₁₂PO₄₀ 8.0 52.0 40.0 2 RhW₁₂PO₄₀ 17.0 49.0 34.0 3 HPdW₁₂PO₄₀ 0.0 92.0 8.0 4 HMnW₁₂PO₄₀ 0.0 96.0 4.0 5 HCoW₁₂PO₄₀ 5.0 92.0 3.0 6 HNiW₁₂PO₄₀ 7.0 90.0 3.0 7 FeW₁₂PO₄₀ 7.0 92.0 1.0 8 HZnW₁₂PO₄₀ 0.0 99.0 1.0 9 ThW₁₂PO₄₀ 6.0 93.0 1.0 Example 10 The catalyst of Example 2 (RhW₁₂PO₄₀) was supported on alumina, florisil, and alundum supports instead of SiO₂. The carbonylation reaction was carried out exactly as Examples 1-9. Small amounts of methyl acetate were formed. Examples 11-18 Bimetallic compounds, M1M2W₁₂PO₄₀ deposited on SiO₂, where M1M2 is a combination of two metals (M1 + M2), were examined as catalysts. The catalysts were prepared such that the mole ratio of M1 : M2 : H₃W₁₂PO = 1 : 1 : 2. The exact composition of these materials was not determined. The carbonylation reaction was carried out as described in Examples 1-9. The results are given in Table 2 below. Ex. No. M1 M2 Product Yield MeOH DME MeOAc 11 Rh Ir 4.0 52.0 44.0 12 Rh Mn 3.0 62.0 35.0 13 Rh Pd 3.0 38.0 59.0 14 Rh Co 5.0 68.0 26.0 15 Ir Co 3.0 39.0 58.0 16 Ir Mn 5.0 41.0 54.0 17 Ir Pd 2.0 40.0 58.0 18 Pd Mn 8.0 84.0 8.0 Examples 19-23 In these example, Na₈[Rh₂W₁₂O₄₂] without deposition on silica support (catalyst "A") and deposited on silica support (catalyst "B") were examined as carbonylation catalysts. The runs were carried out similar to Example 1-9. The result are reported in Table 3 below. Ex. No. Catalyst Temp.°C. Product Yield MeOH DME MeOAc 19 A 225 99.0 0.0 1.0 20 A 250 98.0 0.0 2.0 21 A 275 96.0 0.0 4.0 22 B 225 87.0 0.0 13.0 23 B 275 85 0.0 15.0 Examples 24-27 Heteropoly acids containing both W and Mo were synthesized according to the following reaction: 6Na₂WO₄ + 6Na₂MoO₄ + Na₂HPO₄ + 26HCl - H₃Wo₆Mo₆PO₄₀ + 26Nacl + 12H₂O The reaction is general therefore H₃W x Mo y PO₄₀, where x + y = 12 , were prepared by adjusting the ratios of the reagents. The H₃W x Mo y PO₄₀ acids were then exchanged with Rh and deposited onto SiO₂ to give RhW x Mo y PO₄₀/SiO₂ catalysts. The catalysts were examined at 225°C, 0.1 MPa (1 atm)CO and GHSV = 900 hr⁻¹. The results are given in Table 4 below. Catalyst Example No. RhW x Mo y PO₄₀ Example No. x y 24 8 4 16.0 25 6 6 11.0 26 4 8 8.0 27 2 10 4.0 Examples 28-33 In these examples methanol was replaced by dimethyl ether. The reaction was carried out at 225°C. and 0.1 Mpa (1 atm.)CO with the catalysts reported in Table 5 below. Each of the catalysts were deposited and supported on high surface area silica, as characterized above. Ex No. Catalyst Product Yield MeOH DME MeOAc 28 IrW₁₂PO₄₀ 0.0 87.0 13.0 29 RhW₁₂PO₄₀ 0.0 84.0 16.0 30 HCoW₁₂PO₄₀ 1.0 98.0 1.0 31 HNiW₁₂PO₄₀ 2.0 96.0 1.0 32 Ir-Pd[W₁₂PO₄₀] 0.0 89.0 11.0 33 Rh-Pd[W₁₂PO₄₀] 0.0 99.0 1.0 In the above: 1. "Me" stands for methyl and "Ac" stands for acetate. 2. "Product yield": Unless otherwise noted, the only products observed in the off gas stream were methanol (MeOH), dimethyl ether (DME), and methyl acetate (MeOAc). The product yield for each component is given by Product Yield = P/Combined weight of MeOH + MeOAc + DME where P is is the weight of methanol, methyl acetate or dimethyl ether. Note that this is not product selectivity. Since methanol and dimethyl ether can be recycled back to methyl acetate the selectivity to methyl acetate approaches 100%.

Claims: A process for the carbonylation of one or more of alcohols, ethers and ether alcohols to esters and, optionally, to carboxylic acids, by reaction thereof in the vapor state over a solid catalyst comprising a polyoxometalate anion in which the metal is at least one taken from Group V and VI of the Periodic Chart of the Elements complexed with a cation from a member of Group VIIIA of the Periodic Chart of the Elements. The process of claim 1 wherein the Group V and VI metal is one or more of molybdenum, tungsten, vanadium, niobium, chromium, and tantalum. The process of claim 1 or 2 wherein the cation from Group VIIIA is one or more of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd and Pt. The process of any of claims 1 to 3 wherein the catalyst is deposited on a support that is inert to the reaction. The process of claim 4 wherein the support is silica, preferably a high surface area silica. The process of claim 5 wherein the surface area of the silica is at least about 100, preferably at least about 200, and more preferably at least about 250 square meter per gram. The process of claim 4 wherein the support is selected from silicas, the gamma-aluminas, the titanias, the alumina silicates, and the high surface area clays. The process of claim 4 wherein the support is a mixed composite support in which a high surface area support is deposited over a lower surface area support. The process of any of claims 1 to 8 wherein methanol or dimethyl ether are carbonylated to methyl acetate and, optionally, acetic acid. The process of any of claims 1 to 9 wherein the temperature of the reaction is about 100 to 350°C.

Inventors: WEGMAN RICHARD WILLIAM, WEGMAN, RICHARD WILLIAM
Applicants: UNION CARBIDE CHEM PLASTIC, UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (A NEW YORK CORPORATION)
Application year: 1989
Main classification: C07C67
IPC codes: C07C67, C07B61, C01B25, B01J27, C07C51, C07C31, C07C53, B01J23, C07C69, C07C27