PREPARATION OF STRONG BETA-ALUMINUM BODIES

Abstract: Seeding of beta type alumina compositions in which the alumina in the raw batch is microcrystalline boehmite results in significant increase in hardness, density and strength, as compared to unseeded beta alumina, when fired under similar conditions. The method comprises providing a selected beta alumina composition including a microcrystalline boehmite gel, an oxide or a precursor of an oxide of sodium, potassium, lithium, magnesium, or calcium, and submicron seed particles of beta alumina or alpha alumina, said seed particles being present in an amount of at least 0.1% by weight of the final solids content of said body, shaping said gel and drying and firing at a temperature of from 1200°C. to 1500°C., whereby the body is converted to beta alumina, said seed particles being present in said gel in an amount at least equivalent to 10⁶ particles per cubic centimeter of finished, fired, product.

Description: This invention relates to the manufacture of beta-type aluminas for use as solid electrolyte conductors of small ions. Such materials are used as electrodes in fuel cells and in cells for electrical power generation such as sodium-sulfur cells. Beta type aluminas are crystalline materials of the formula Na₂O-11Al₂O₃ or Na₂O-6Al₂O₃ where the Na may be substituted in whole or in part by other alkali or alkaline earth elements. In the sodium sulfur cell the beta alumina electrode forms a barrier between molten sulfur and molten sodium. The electrode permits the flow through it of sodium ions, whereby Na₂S is formed, generating power when a load is applied to output electrodes in contact with opposite sides of the cell. It is desirable that the beta alumina for application on a solid electrolyte be strong and dense. In the past such products have been formed by classical sintering techniques where powder of the desired beta alumina composition is compacted into the desired shape by molding and then fired to produce the final product. The present invention provides a method by which bodies of superior strength and low porosity can be made. Beta alumina bodies of superior hardness (density) and strength are produced in the present invention by providing a mix containing an alumina sol or gel together with the stoiciometric amounts of alkali and/or alkaline earth oxides or oxide precursors. Seed particles for nucleation of the beta alumina are added, and the composition is formed to shape in the gel form by molding, casting, or extruding. In a sol form, water is removed from the mix to produce the desired consistency for the forming step. If the material is to be cast, a higher water content will be desirable than in the case where it is to be extruded. In accordance with the present invention, there is provided a method of making a strong beta alumina body comprising: (a) providing a composition consistent with the formation of beta alumina upon sintering, said composition comprising (i) an alumina sol or gel, and (ii) an oxide or a precursor of an oxide of sodium, potassium, lithium, magnesium, or calcium; (b) shaping said composition in the gel form after removal of water from the composition to produce the desired consistency where a sol is used; (c) drying the shaped gel from step (b); and (d) firing the dried shaped gel from step (c) at a temperature of from 1200°C. to 1500°C. to produce said beta alumina body; characterized in that said composition further comprises submicron seed particles of beta alumina or alpha alumina, said seed particles being present in an amount of at least 0.1% by weight of the final solids content of said body, said amount being sufficient for nucleation of said sol or gel to produce said beta alumina body. Seeds for nucleation of the beta alumina may be beta alumina itself, or preferably, may be alpha alumina, since alpha alumina is readily ground into appropriate size for use as seed material, and, for reasons not clearly understood at this time, is an effective nucleant for the growth of beta alumina crystals. One possibility is that the surface of the alpha seed reacts with the alkali or alkaline earth components in the mix to form beta alumina prior to that point in the firing of the shaped body at which any significant autogenous nucleation of the composition to beta alumina takes place. Thus the nucleation takes place in a controlled and uniform manner. When beta alumina seed is employed it is not necessary that it be of same composition, in terms of alkali or alkaline earth ions as the overall composition. Thus a lithium beta alumina can act as a seed for a potassium or sodium beta composition. A method of producing beta-alumina bodies is known from GB-A-1 386 244 which is acknowledged in the preamble of claim 1. U.S. Patent 4,623,364 to Cottringer, Van de Merwe, and Bauer, teaches various methods of producing fine alpha alumina seed to be used in the manufacture of alpha alumina bodies. Such seed is the preferred seed in the present invention. However it is produced, it should be finer than one micrometer (micron) in size and preferably much finer. The alpha alumina seed should have surface area of 40m²/g or greater. Typical preferred seed has a surface area of about 40m²/g, equivalent to a particle diameter of 0.04 micrometers (microns). An arbitrary composition of 1.0 Na₂O-0.16Li₂0-6.33 Al₂O₃ was chosen to illustrate the invention. In a large stainless steel vessel was put condea NG (Registered T.M.) microcrystalline boehmite in the amount of 215 grams. In a separate 400 ml beaker 26.5 grams of anhydrous sodium carbonate was dissolved in 100 ml of water and 30 ml of concentrate (14% HNO₃) nitric acid which was slowly added. In another container 3.0 grams of lithium carbonate was dissolved in 50 ml of water and 7 ml of concentrated nitric acid (slowly added). To the stainless steel vessel containing the microcrystalline boehmite were added 1.5 liters of water and all the sodium and lithium solutions. The mixture was stirred and an additional 100 ml of concentrated nitric acid was added. The mixture was thoroughly stirred and then separated into two portions. The first half was dried in the form of a plate and broken into several pieces. Prior to drying the second half was seeded by the addition of 13 grams of water which had been milled in a vibratory mill with 12.7mm x 12.7mm (1/2"x1/2") alumina grinding cylinders until it contained 6.33% of fine solids from the alumina media. The gel was then dried as a flat plate and broken into several pieces. The following results were obtained upon firing the samples for 4 minutes: Firing Temperature Hardness in GPa Seeded (invention) Not Seeded 1300 7.9 4 1400 8 4.6 1500 7.7 5 All of the samples were shown to be beta (beta double primed) by X-ray diffraction. The results show a very significant increase in hardness and strength and density for the seeded samples.

Claims: A method of making a strong beta alumina body comprising: (a) providing a composition consistent with the formation of beta alumina upon sintering, said composition comprising (i) an alumina sol or gel, and (ii) an oxide or a precursor of an oxide of sodium, potassium, lithium, magnesium, or calcium; (b) shaping said composition in the gel form after removal of water from the composition to produce the desired consistency where a sol is used; (c) drying the shaped gel from step (b); and (d) firing the dried shaped gel from step (c) at a temperature of from 1200°C. to 1500°C. to produce said beta alumina body; characterized in that said composition further comprises submicron seed particles of beta alumina or alpha alumina, said seed particles being present in an amount of at least 0.1% by weight of the final solids content of said body, said amount being sufficient for nucleation of said sol or gel to produce said beta alumina body. A method according to claim 1, characterized by the fact that the seed material is alpha alumina. A method as in claim 2, characterized by the fact that the alpha alumina seed has a surface area of 40 square meters per gram or greater. A method according to any one of the preceding claims, characterized by the fact that the seed material is produced by wet grinding of high alumina-containing grinding media. A method according to any one of the preceding claims, characterized by the fact that said alumina sol or gel consists essentially of microcrystalline boehmite gel.

Inventors: BAUER, RALPH, FRANKLIN, RUFUS M.
Applicants: NORTON COMPANY
Application year: 1989
Main classification: C04B35
IPC codes: C01F7, C04B35