Moisture proof thermally actuated binding tape for books

Abstract: A moisture proof binding tape for edge binding pages to form a book consisting of a non-permeable temperature resistant foil layer (50) covering one side of the backing strip (12) forming a moisture barrier, a high temperature steam resistance adhesive (54) between the foil layer and the backing strip to secure the foil layer to the backing strip, and a relatively thick central stripe (14) of high tack heat activated adhesive flanked by relatively thin side stripes (21) of low tack heat activated adhesive on the foil layer.

Description: The invention relates to a binding tape for adhesively binding pages together to form a 'perfectly bound' book or pamphlet, and more particularly, to a binding tape for application to the spine of a book to bind together the pages that comprise said book, said tape having a backing strip with at least one stripe of hot melt adhesive on said tape, application of heat to said tape actuating said adhesive to form a bond between said tape and said book spine. It is often desirable to bind pages together permanently to form a 'perfectly bound' book, pamphlet, or the like. While numerous arrangements for doing this are known and available, one well known and popular method is to use an adhesive bearing binding strip or tape which when attached to the edge or spine of the assembled pages, binds the pages and the tape together to form the book. Binding tapes of this type typically employ either heat activated adhesive or a pressure sensitive adhesive, or combination thereof. The adhesive formulations used are many and varied. Binding tapes employing heat activated adhesives generally use a heavy paper stock for the tape substrate or backing strip. However, paper has an inherent disadvantage in that paper is largely made up of cellulose fibers which are hygroscopic. When heated to activate the adhesive(s), any water in the paper is also heated, and since the binding temperatures typically used are normally above the boiling point of water, any water in the backing strip will be turned into steam. Water is undesirable from at least two standpoints. First, the water imposes an additional thermal load during the binding process, especially during the period when the water changes from liquid to gas. Secondly, the steam produced from the water has a deleterious effect on the adhesive used. In the case of the latter, when the water reaches the boiling point and is converted into steam, the steam that results will try to exit the binding strip. Since escape from the non-adhesive bearing side of the backing strip is normally blocked or seriously impeded by the binding apparatus itself, the steam must escape at the interface between the strip and the adhesive. If the viscosity of the adhesive is low enough, the steam will bubble through the adhesive and escape to the atmosphere via this route. This bubbling however causes the viscosity of the adhesive to be mechanically lowered, changing the adhesive's properties and binding performance. If the viscosity of the adhesive is high, release of the steam from the binding strip is inhibited until the adhesive reaches a viscosity where the steam can penetrate it. The steam is usually in the form of small bubbles of a size that is probably determined by the fiber structure of the paper. But, as the steam enters the adhesive, it collects and forms larger and larger bubbles. These larger bubbles are forced upwards by the pressure below and the effect of gravity, and as the bubbles rise, they lift the layer of adhesive above them. This changes the heat transfer relation from the more efficient conduction through the adhesive to the less efficient convection through the steam bubbles. This causes premature cooling and thickening of the adhesive, trapping the steam permanently inside the matrix of the book. Where binding takes place in moderate humidity conditions, there typically results undesirable and unsightly 'bumps' in the spine of the book. On the other hand, where binding takes place in high humidity conditions, the binding may not take, resulting in separation of the backing strip from the spine of the book, either immediately after binding or at some later point in time. In the prior art, US-A-3,847,718 to Watson discloses a binding means employing a relatively thick central stripe of low tack heat activated adhesive on a substrate such as paper flanked by relatively thin side stripes of high tack heat activated adhesive. A related patent, US-A-4,244,069 to Hale, discloses a binding material in which the substrate comprises a heat shrinkable plastic covered with a pressure sensitive adhesive bearing a relatively thick heat activated adhesive stripe along the center thereof. US-A-3,825,963 to Abildgaard et a discloses a combined mechanical/adhesive binding apparatus in which rivets or studs are used along with a binding tape to make books, the binding tape using a pressure sensitive adhesive to attach the tape to the spine of the book. And, US-A-4,686,133 to Nakabayashi et al, discloses a material for sealing the mouths of glass containers in which a metal foil with a thermal adhesive layer bonded thereto by a polyester-isocyanate type two component adhesive is employed. DE-A-2 937 238 discloses binding tapes for books comprising a liquid-impermeable layer between the adhesive layer and the carrier in order to prevent transfer of the liquid hot adhesive to the carrier. It is an object of the present invention to overcome the problem of moisture and the deleterious effect that such moisture has on the effectiveness of the binding that is made. The present invention accordingly provides a binding tape of the kind specified in the introductory paragraph hereof, characterised by a non-permeable layer of temperature resistant barrier material 51, between said backing strip 12 and said adhesive stripe, whereby upon application of heat to said binding tape, said barrier material layer prevents the transfer of moisture in the form of steam from said backing strip to said adhesive stripe. A binding tape in accordance with the invention will now be described, by way of example, with reference to the accompanying drawings, in which: Figure 1 is an isometric view showing the moisture proof binding tape of the present invention; Figure 2 is a cross sectional view of the binding tape shown in Figure 1 applied to a book; and Figure 3 is a cross sectional view of the binding tape shown in Figure 1 illustrating details of the tape moisture barrier. Referring to the drawings, numeral 10 designates generally the moisture proof binding tape of the present invention. In the exemplary arrangement shown, tape 10 comprises a length or strip 12 of formable backing or substrate material consisting of relatively heavy paper stock bearing heat activated adhesive coatings with a moisture barrier between the backing and the adhesives. Typically, tape 10 is in the form of a roll (not shown) that is cut to desired length at the time of use. Normally, the length L to which tape 10 is cut when binding is substantially equal to the length of the pages 11 of the book 15 being bound although other lengths may be contemplated. The width W of the backing strip 12 is somewhat greater than thickness T of book 15 to allow the sides or flanks 18 of tape 10 to partially wrap around and be secured to the outer pages or covers of the assembled book 15 as will appear. Binding strip 12 may be of any desired thickness. Backing strip 12 has a central elongated stripe 14 of high tack heat activated adhesive 13 along the centerline thereof. Adhesive stripe 14 is relatively thick, a thickness of from 0.51 to 0.56 mm, for example, having been found to be suitable. The width of adhesive stripe 14 is less than the width W of backing strip 12 and approximates or is slightly greater than the thickness of the assembled pages 11 that when bound together form book 15. As a result, sides 18 of strip 12 extend along each side of stripe 14. Sides 18 of backing strip 12 bear a relatively thin coating or layer of low tack heat activated adhesive 21. As a result, there is provided a stripe 19 of low tack heat activated adhesive 21 on each side of the central stripe 14 of high tack heat activated adhesive. The layer of adhesive 21 on sides 18 has a thickness of 0.04 to 0.05 mm. A high tack adhesive such as adhesive 13 comprises an adhesive material or formulation which when heated remains highly viscous and somewhat immobile so that a definite amount of pressure and/or heat is necessary to wet-out the surface being adhered. A low tack adhesive such as adhesive 21 comprises an adhesive material or formulation which when heated becomes fairly molten or fluid thereby providing a high degree of surface wet-out with minimum application of pressure or heat. In binding systems, and particularly in binding systems which comprise an integral part of a book making machine, such as the Xerox 5090 (Xerox and 5090 are registered Trademarks of Xerox Corporation, Stamford, CT), high speed binding is essential if high machine throughputs are to be achieved. To effect this and maintain the binding cycle as short as possible, relatively high binding temperatures on the order of 218°C are used. However, the paper that is used for backing strip 12 is largely made up of cellulose fibers which are hygroscopic. As a result, when backing strip 12 is heated during the binding process to activate the adhesives, water present in the paper is also heated. When the water reaches the boiling point, steam is formed which will try to escape from the backing strip. At the interface between the backing strip and the adhesives, if the viscosity of the adhesive is low enough, the steam will bubble through the adhesive and escape to the atmosphere. Such bubbling causes the viscosity of the adhesive to be mechanically lowered, changing the adhesive properties and the binding performance achieved. When the viscosity of the adhesive is high, release of the steam from the paper will be inhibited until the adhesive reaches a viscosity where the steam is able to penetrate the adhesive. The steam usually enters the adhesive in the form of small bubbles, the size of which is probably determined by the fiber structure of the paper used for the backing strip. As the steam enters the adhesive, the steam will collect to form larger and larger bubbles. As these bubbles are forced upwards by the pressure below and the effect of gravity, the bubbles lift the adhesive layer, allowing the layer of adhesive above to cool as a result of the change in heat transfer mode from conduction through the adhesive to convection through the steam bubbles. The raised adhesive quickly cools and thickens, thus trapping the steam permanently within the binding. The result can be a poor quality binding with 'bumps' and roughness evidenced along the spine. Or, where binding is performed in an environment where the humidity is high, complete separation of the binding tape from the pages that comprise the book can occur. The effect of the foregoing is dependent upon the amount of water in the backing paper which in turn is dependent principally upon the type and thickness of the paper and the relative humidity in the environment that the binding tape is exposed to. It can be understood that at relatively low (e.g. 20%) relative humidity, the effect of steam is relatively small, whereas at relatively high (e.g. 80%) relative humidity levels, total failure of the binding can occur. In order to prevent binding degradation and failure as a result of moisture, a non-permeable layer of temperature resistant barrier material (51) is provided between backing strip 12 and the adhesives 13, 21. Layer 51 preferably comprises an aluminum foil, which may be of standard commercial thickness (i.e., 0.009 mm) or a polyester film of about 0.013 to 0.025 mm thickness. Other thickness foil and polyester film may, however, be envisaged as well as other suitable temperature resistant non-permeable materials such as fluorinated polymers, silicones, and the like. To retain layer 51 in place on backing strip 12, a suitable high temperature steam resistant adhesive 54 is used. Preferable adhesive materials for this purpose comprise Latex type adhesives. Other suitable high temperature steam resistant adhesives such as thermosetting type adhesives may, however, be used. In use, the loose pages comprising the book are placed, spine edge first on binding tape 10. Sides 18 are turned upwardly to bring the adhesive 21 into contact with the outside pages or covers of the book 15. Heat and pressure may then be applied, either simultaneously or in stages, to the bottom and sides of strip 12 to activate, i.e., melt, the adhesives 13,21 and bind the pages of book 15 to one another and to strip 12. The application of heat and pressure to the bottom of strip 12 activates the adhesive 13, the relatively large quantity of adhesive that comprises stripe 14 flowing or wicking between and among the edges of the book pages and being absorbed intimately therewith to bond the pages together to one another and to strip 12. The application of heat and pressure to sides 18 of strip 12 activates the adhesive 21 to establish a tight bond between the sides 18 of strip 12 and the outer pages or covers of book 15. This prevents sides 18 from unfolding away from the outer pages or covers of book 15 when the source of heat and pressure is removed and the binding is completed. Any steam generated as a result of moisture in backing strip 12 is prevented from passing into the adhesives 13, 21 by the barrier 51, and instead remains trapped within the backing strip. In one embodiment, backing strip 12 consisted of an Acrylic Latex treated paper of approximately 0.15 mm thickness with heat activated adhesive 13 comprising a polyamide material and adhesive 21 comprising an EVA material. The thickness of adhesive 13 was 0.56 mm while that of adhesive 21 was 0.051 mm. Layer 50 was formed from an aluminum foil of 0.009 mm thick with adhesive 54 comprising a Caslen-Neoprene adhesive. Other binding tape configurations and assemblies may be contemplated. For example, adhesive 13 may instead comprise a suitable low tack adhesive while adhesive 21 comprises a suitable high tack adhesive. Further, the layer of adhesive 21 may extend over the entire surface of backing strip 21 and between foil layer 51 and adhesive 13. Stripe 14 may, instead of being continuous, comprise a series of discrete adhesive formations or blocks. And while adhesive stripe 14 is described and shown as being thicker than side stripes 19 of adhesive 21, the adhesive stripes 14, 19 may be substantially the same thickness. Further, the various substrate, adhesive, and moisture barrier thicknesses provided herein are understood to be examples only and the present invention is not intended or to be construed as limited to the specific dimensions and dimensional ranges described. While the invention has been described with reference to the structure disclosed, it is not confined to the details set forth, but is intended to cover such modifications or changes as may come within the scope of the following claims.

Claims: A binding tape (10) for application to the spine of a book (15) to bind together the pages (11) that comprise said book, said binding tape having a backing strip (12) with at least one stripe (14) of hot melt adhesive on said binding tape, application of heat to said binding tape actuating said adhesive to form a bond between said tape and said book spine, characterised by: a layer of non-permeable temperature resistant barrier material (51), between said backing strip and said adhesive stripe, whereby upon application of heat to said binding tape, said barrier material layer prevents the transfer of moisture in the form of steam from said backing strip (12) to said adhesive stripe (14). The binding tape according to claim 1 in which said barrier material (51) comprises a metal foil. The binding tape according to claim 1 in which said barrier material (51) comprises a plastics material. The binding tape according to claim 3 in which said barrier material (51) comprises a polyester film. The binding tape according to any one of claims 1 to 4 including a high temperature steam resistant layer of adhesive between said backing strip and said barrier material to retain said barrier material in place on said backing strip. The binding tape according to any one of claims 1 to 5 wherein said adhesive stripe (14) extends longitudinally of said backing strip (12) substantially along the center thereof, said adhesive stripe having a width less than the width of said backing strip whereby side portions of said backing strip extend along each side of said adhesive stripe; said tape further comprising a relatively thin second stripe (19) of heat activated adhesive (21) on each of said side portions; and said moisture barrier layer extending between said backing strip (12) and said second adhesive stripes. The binding tape according to any one of claims 1 to 6 wherein said backing strip (12) has a minimum width greater than the thickness of the book to be bound to permit said substrate to overlay not only the book end but also at least that portion of the outer pages of said book immediately adjoining said book end; said first adhesive stripe being of a width sufficient to accommodate the thickness of the pages to be bound. The binding tape according to claim 6 or claim 7 wherein said first adhesive is a high tack adhesive and said second adhesive is a low tack adhesive. The binding tape according to claim 6 or claim 7 wherein said first adhesive is a low tack adhesive and said second adhesive is a high tack adhesive.

Inventors: LIN LUKE C, MCNAMEE JOHN A, VANBORTEL DAVID P, LIN, LUKE C., MCNAMEE, JOHN A., VANBORTEL, DAVID P.
Applicants: XEROX CORP, XEROX CORPORATION
Application year: 1989
Main classification: C09J7
IPC codes: B42C11, C09J7, B42C9