PROCESS AND INSTRUMENT FOR A THREE COMPONENT MEASUREMENT

Abstract: A process and an instrument for determining the proportions of gas, water and oil in a gas/water/oil mixture. In the process the permittivity of the three-component mixture, during passing said mixture in a flow between two opposite electrodes, is measured by a capacitive non-penetrating first sensor, whereas the density of said flowing mixture is measured by a second sensor including a radioactive element and a gamma-radiation densitometer. The electronic signals received from said sensors being processed in a computer by incorporating specific equations therein and progressively determining the proportions of said three components in said three-component mixture. The instrument comprises an electrode capacitance sensor, including two opposite electrodes located at opposite sides of an intermediate concentrated mixture flow, a capacitance sensor head, a screen, a density meter including a radioactive element and a gamma-radiation densitometer, and a computer for processing the electronic signals and determining said proportions.

Description: PROCESS AND INSTRUMENT FOR A THREE COMPONENT MEASUREMENT. This invention relates to a process and an instrument for determining the proportions of the components of a three-compo¬ nent mixture and in particular to a process and an instrument f determining the proportions of gas, water and oil in a gas/ water/oil mixture. This invention is applicable on different types of three- phase mixtures, but will herein be described mainly with reference to a three-phase mixture containing gas (g), water (w and oil (o) . Accordingly, the equations stated herein are referring to a* three-phase mixture containing gas, water and oi and to the three specific components thereof. However, the equations stated herein are generic to different components, i. in general to three components stated as components g, w, and o respectively. In crude oil production, the fluid at the well head rarely if ever, involves single phase single component flow. Usually i will contain crude oil, gas (in the free state and/or dissolved in the oil) and possibly water with the proportion of the latte tending to increase as production continues. Measurements of the rates of hydrocarbon production from t wells in a field are required for reservoir management and production allocation. With such data, depletion of the reservo can be undertaken with the aim of optimising total production over the field life. In addition the metering of the total production rate of oil and gas from a field is required for fiscal purposes. This demands a much higher degree of accuracy. At present, crude oil production systems require separation of the gas, water and oil phases before satisfactory metering, for whatever reason, can be achieved. Offshore production platforms of today, e.g. those in the North Sea, have a manifold system which allows the flow from a production well to be directed either to the main separators or to a test separator. Thus at any time, although usually to a set cycle, the flow from a single well can be directed to a test separator where it is separated into gas, water and oil. Meanwhile the production from all other wells is manifolded together and processed in the main separation system. The flowrates of gas, water and oil are measured in the respective single phase lines from the test separator. All three flows are normally measured by using orific plates, turbine meters or other conventional equipment. A considerable proportion of remaining oil reserves is believed to lie offshore under water depths in excess of 200 metres, in relatively small oil fields, and in hostile environments. As any one of these conditions intensifies, and more particularly when two or more are present together, the cost of conventional offshore recovery systems wherein drilling and production facilities are mounted on surface platforms rises rapidly and soon becomes uneconomic. For this reason attention has been given to subsea systems where a favoured technique is to drill a number of wells close together and to mount the well head control equipment on the sea bed. In any design for a new production facility the need for metering of the flows from individual wells, and of the bulk output of the field, must be considered in detail. With the advent of alternative production system concepts such as those outlined above it has become apparent that new methods of flow measurement are desirable to improve both the technical and economic viability of such projects. One particular problem with multi-phase regimes is the variability of flow conditions in the line. Stratified flow, wa flow, bubble flow, plug flow, slug flow and annular flow can al occur at various times in horisontal lines. Vertical flow avoid stratification, however. The density of a three-component gas/water/oil mixture is given by : p = αp + 0 p + ( l-α- β ) p [l ] m g w o where p is the density of the three-component mixture, p is t gas density, p is the water density and p is the oil densit This p is the density that is measured by a gamma-radiation densitometer. If we somehow know the water fraction β , we can calculate the gas fraction α from Eq. 1 as follows: P m - S( p w - p o } - p o [2 ] < p g - p o> Conversely if the gas fraction is known, Eq. 1 can be used to compute the water fraction β . From this it is obvious that a gamma-radiation densitometer alone cannot be used to measure either the gas or water fraction. The permittivity of a three component mixture can be relat to the component volume fractions by the following relationship where α is the gas fraction, and ε is permittivity of the thre component mixture, ε is the permittivity of a two-component (oil/water component) of the three-component mixture, and is given by ^ = ^ [3a] '' " a - _ f ) 3 - 4"2 " »f 6 + 3 β f" where β ~ is the water concentration in the two-component (oil/water component). This formula is a slight modification of Bruggemans formula for two-component mixtures. The actual water fraction of the three-component mixture is given by: β = (1-α) [3b] According to the present invention there is provided a process for determining the proportions of the components of a three-component mixture, especially the proportions of gas, wat and oil in a gas/water/oil mixture. The process of the inventio is characterised in, during passing the three-component mixture in a flow through a spacing between two opposite electrodes, measuring the permittivity of said flowing mixture by a capacitive non-penetrating first sensor, measuring the density said flowing mixture by a second sensor (gamma densitometer) including a radioactive element and a gamma radiation detector, processing electronic signals received from said sensors in a computer by incorporating specific equations therein, and progressively determining the proportions of said three com¬ ponents in said three-component mixture. It is thus possible to determine in succession and with adequate accuracy the three components of the mixture flow at rather short intervalIs during the passage of the mixture flow the spacing between the electrodes. Further, according to the present invention there is provided an instrument for determining the proportions of the components in a three-component mixture, and especially the proportions of gas, water and oil in a gas/water/oil mixture. instrument is characterised by a first electrode capacitance sensor, including two opposite electrodes located at opposite sides of an intermediate concentrated flow of said three- component mixture for measuring the permittivity of said three component mixture, an capacitance sensor head for reducing or eliminating impedance between the electrodes and a screen, a density meter including a radioactive element and a gamma radiation detector for determining the density of the mixture, and a computer for processing the electronic signals and determining the proportions of said three components (gas, wat and oil) in said three-component mixture. The algorithm in the computer of the instrument of the present invention will be like this: 1. Choose a value for β . 2. Calculate α using β and the measured density of the mixt (Eq. 2 ) . 3. From a and the measured permittivity of the mixture, calc late a new value from β using the three-component permittivity formula (Eq.3) . 4. Go to step 2 and repeat the process a predetermined numbe of times, or use some convergence criteria to stop the iteratio The accuracy of the final result depends on a number of factors These are briefly discussed below. (a) The accuracy depends strongly on how accurate the densiti of the crude oil is known. The density depends on the temperatu and pressure, and therefore it will be necessary to compensate for temperature and pressure variations. The density changes wi pressure because of the compressibility of the oil, and also because of changing gas/oil-ratio with changing pressure. (b) The density of the water must also be known with high precision. The water density depends strongly on the salinity, and therefore it has to be measured in each case. For water the variation in density with respect to temperature and pressure probably can be ignored for reasonable temperature and pressure variations. (c) The density of the gas also has to be known, and also thi quantity depends on temperature, pressure and on its compositio At atmospheric pressure the gas density will only be about 3 lkg/m , and can be neglected compared to the densities of oil a water. At substantially higher pressures this can not be neglected and compensation must be made. (d) The permittivity of the crude oil should be known within in order to avoid significant errors because of this factor. (e) Finally the accuracy will depend on the accuracy of the densitometer and the capacitance measurement. Situating the sensor inline in the production system means that very little pressure drop can be tolerated across the sensor. Furthermore in a riser, erosion can be very high and therefore the sensor should ideally be non-intrusive. Taking these factors into acount the electrodes of the sensor head are in the shape of arcuate electrode plates in¬ corporated in a tube forming sensor head each of said electrode facing the mixture flow in said sensor head. In the following t sensor is denoted as a surface plate sensor. The sensor head is ring shaped or sleeve shaped and in¬ corporate a pair of radially innermost electrodes and a radiall outermost screen and an intermediate volume containing electric insulating material. The screen is at earth potential. The arcuate electrode plates may be spaced from the mixture flow by layer of electrically insulated material. In the surface plate electrode sensor, the electrical fie penetrates through the whole measuring section, making the sens sensitive to the flow in the centre of the pipe as well as alo the pipe wall. Careful choice of the electrode opening angle ensures that every part of the measuring volume will have the same effect on total sensor impedance. It can be shown that with respect to homogeneity of the electric field, the optimum electrode opening angle is between 60° and 90°. The sensitivity of a surface plate sensor with su an opening anlge will also be good. In accordance with a preferred embodiment of the inventi the electrodes, circumferencially along the inner surface of t tube forming sensor head, are mutually spaced by an opening an of between approximately 60 to 90°. The sensor head also reduces or eliminates impedance be¬ tween the electrodes. One way of achieving this is by providin the sensor head in each spacing between the electrodes with a strip shaped guard with an extension of some few arcuate degre and by connecting said guard strips at the potential of said first electrode. It is preferred that said guard strips are incorporated a ring shaped guard surrounding the edges of one of said two electrodes. Suitable electrically insulating material is a ceramic o polyurethane or other material having good resistance to erosi and low thermal expansion. The electrodes are made of an electrically conducting material including stainless steel, conducting ceramic and oth suitable material. The present invention, i.e. the process as well as the instrument of the invention, has the following advantages: - non intrusive - - measure complete flow through pipe, no sampling - - real time - - no moving parts - - reliable with low maintenance. The invention is illustrated by, but not limited with reference to Figures 1 to 4 of the accompanying drawings where Figure 1 is a schematic representation of a system incorporating a capacitance sensor and a density sensor, i.e. gamma-densitometer to calculate the flow composition. Figure 2 is a capacitance measurement transmitter illustrated in Figure 1. Figure 3 is a section through a sensor. Figure 4 is a plane view of one of the electrodes and it associated guard. With reference to Figure 1, a three-component mixture of gas, water and oil flows through a line 10 incorporating a capacitance sensor 11, i.e. a first sensor, which measures the permittivity of the mixture. A transmitter 11a feeds signals f the first sensor 11 to a first data processing unit 12 and further to a second data processing unit 13 incorporated in a computer 14. Said units can incorporate a display of the relat proportions of the three-component mixture. A second sensor 15, i.e. a gamma densitometer, is in¬ corporated in the flowline 10 in the vicinity of the first sen 11. The gamma densitometer 15 include a gamma meter radioactiv source 16. Herein a σeasium isotope is selected, but other iso topes such as americium isotope could also be used. Further, t gamma densitometer 15 include a gamma meter detector 17. The gamma meter radioactive source 16 and the gamma meter detector are located at opposite sides of the flowline 10 clamped to a pipe forming sensor head of said second sensor 15. The output the gamma densitometer, in combination with the output of the first sensor 11, is used to calculate the fractions of the mixture and an accurate result may be obtained rather easily. The output frequency F from the capacitance measurement electronics is converted from a first data processing unit 12 into a digital value C, which represents the sensor capacitanc The relationship between C, and F is established through calibration of the measurement electronics, and the calibratio curve is stored in the computer memory. The computer also stor a calibration curve for the capacitance sensor 11. This is here used to convert the measured capacitance C, in a second data processing unit 13 into a value for the permittivity of the mixture, ε . The gamma meter detector 17 of the second sensor 15 gives out a signal V , which is proportional to the density of the mixture flowing inside the pipe. A data processing unit 18 of said computer is converting the signal V to the digital value y which is the measured density of the flowing mixture. This valu from unit 18 and the value , from unit 13 is further processed in a common unit 14 of the computer. The unit 14 contains a mathematical model relating measured permittivity and measured density of the flowing mixture, to the proportions of gas (α), water ( β) and oil ( γ) . The capacitance transmitter 11a is illustrated in further details in Figure 2. The sensor capacitance C, provides a triangular wave v, which is generated by integration of a squar wave v«. In turn this triangular wave v, is used as the input t a square wave generator. The illustrated closed loop constitute a sesonance system where the resonance frequency f is given by equation 5: C l wherein k is a constant determined by R, and zener diodes Z_ an Z. and C, is the sensor capacitance. With reference to Figure 3 there is illustrated a section of a sensor head 20 of the first sensor 11. This sensor head 20 comprises two electrodes 21 and 22 connected to terminals 21a a 22a and a guard 25 connected to a terminal 25a. An outer scree 26 made of steel is connected to earth and provides a housing the sensor head and surrounds an insulation 27 wherein there i incorporated the electrodes 21,22 and the guard 25. The insulation 27 is leaving a central cavity 28 for fluid flow. More detailed the electrodes 21,22 and the guard 25 are sulated from the fluid flow by means of a radially innermost i sulation layer 27a made of a first ceramic material, such as sintered alumina (aluminium oxyd) . In the spacing between said radially innermost insulation layer 27a and the radially outer¬ most screen 26 there is a main insulation layer 27b made of a second ceramic material, such as "Cera ite" delivered from Elke Materials A/S, Norway. In practice the insulation layer 27b, the electrodes 21,2 and the guard 25 is being enveloped between the inner insulatio layer 27a and the outer screen 26. As illustrated in Figure 3 connections 21a,22a,25a are passing from its associated electro 21,22 and guard 2*5 respectively via the insulation layer 27b to connecting box 26a at one side portion of the screen 26. In Figure 4 is illustrated the electrode 22 and the guard 25 in a plane folder position. The electrode 22 (as well as the electrode 21) is of rectangular shape. It is evident from Figur 4 that the guard 25 is rectangularly ring shaped and spaced fro the electrode 22 by a minor gap of say 5 mm. The electrodes 21, and the guard 25 is in a preferred embodiment during production thereof, applied in a rather thin walled layer directly at the radially outer surface of the radially innermost insulation lay 27a and is hence covered by the radially outermost insulation layer 27b.

Claims: AMENDED CLAIMS [received by the International Bureau on 13 February 1990 (13.02.90) original claim 2 amended; other claims unchanged (1 page)] 2. Instrument for determining the proportions of the components in a three-component mixture, and especially the proportions of gas, water and oil in a gas/water/oil mixture, c h a r a c t e r i s e d i n a non-intrusive measurement instrument comprising a) a first electrode impedance capacitance, including two opposite electrodes located at opposite sides of an intermediat concentrated flow of said three-component mixture for measuring the permittivity of said three-component mixture, b) an impedance sensor head for reducing or eliminating impedance between the electrodes and a screen, c) a density meter including a radioactive element and a gamma-radiation densitometer for determining the density of the mixture , and d) a computer for processing the electronic signals and determining the proportions of said three components (gas, wate and oil) in said three-component mixture. 3. Instrument according to claim 2, c h a r a c t e r i ¬ s e d i n that the electrodes of the sensor head are in the shape arcuate electrode plates incorporated in a tube forming sensor head, each of said electrodes facing the mixture flow in said sensor head. 4. Instrument according to one of claims 2 or 3, c h a r a c t e r i s e d i n that the sensor head is ring shaped or sleeve shaped and incorporate a pair of radially innermost electrodes and a radially outermost screen and an intermediate volume containin electrically insulating material. 5. Instrument according to one of claims 3 to 4, c h a r a c t e r i s e d i n that the screen is at earth potential. 6. Instrument according to one of claims 3 to 5, c h a r a c t e r i s e d i n

Inventors: DYKESTEEN EIVIND, HAMMER ERLING, DYKESTEEN, EIVIND, HAMMER, ERLING
Applicants: MICHELSENS CHR INST
Application year: 1989
Main classification: G01N27
IPC codes: G01N27, G01N33