HEAT RESISTANT POLYMERS AND BLENDS OF HYDROQUINONE POLY(ISO-TEREPHTHALATES) CONTAINING RESIDUES OF p-HYDROXYBENZOIC ACID

Abstract: This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV), and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the description of the invention. The instant copolyesters display orientation in the molten state, good fiber ratings and high strength; they have melting points in the range of from about 340 to about 400 DEG C and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240 DEG C up to about 280 DEG C and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particularly they are easier to melt-fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures.

Description: HEAT RESISTANT POLYMERS AND BLENDS OF HYDROQUINONE POLY(ISO- ___R__?____IALATES) CONTAINING RESIDUES OF p-HYDROXYBENZOIC ACTD This is a continuation-in-part of USSN 255,670, filed October 11, 1988, and a continuation-in-part of USSN 255,632, filed October 11, 1988. Field of the Invention This invention pertains to novel copolyesters consisting essentially of units (I), (II), (HI), and (IV). and blends of these polymers and articles made from both. Units (I), (II), (HI), and (TV) are present in specified proportions as defined in the "Description of the Invention. " The instant copolyesters display orientation in d e molten state, good fiber ratings and high strength; they have melting points in the range of from about 340 to about 400°C and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240°C up to about 280°C and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particulaiiy they are easier to melt fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures. Background of the Invention Wholly aromatic polyester resins have long been known. For instance, 4-hydroxybenzoic acid homopolymer and copolymers have been described in the past and are co-αmeπήally available. Such polymers ∞mmonly are crystalline in nature and, when molten, frequently exhibit orientation in the melt; however, they have relatively high melting points or possess a decomposition temperature which is below the melting point, which leads to great difficulty in processing. The homopolymer of p-hydroxybenzoic acid is a very high melting, insoluble material and, hence, very difficult to fabricate. Melting points as high as 610°C were quoted - see W.J. Jackson, The British Polymer Journal, December 1980, p. 155. In order to depress the high melting point of the homopolymer so as to make it melt fabricable, a variety of materials incorporating different types of comonomers were prepared over the years. One such material is, for example, the resin made from p-hydroxybenzoic acid, isophthalic and/or terephthalic acids and 4,4'-biphenol as described in Cottis et al., U.S. Patents Nos. 3,637,595 and 3,975,487. The polymer has outstanding high temperature properties and can be molded to give articles of high modulus and strength. It is offered commercially by Amoco Performance Products, Inc. under the trademark of Xydar ® . The main drawback of the prior art p-hydroxybenzoic acid copolymers is the relatively high cost associated with the use of an expensive comonomer, such as 4,4'-biphenol, substituted hydroquinones (e.g., phenylhydroquinone), naphthalene diols, naphthalene dicarboxylic acids, and hydroxy-naphthoic acids. Efforts to replace these expensive monomers with the significantly less expensive hydroquinone, which is disclosed as an equivalent of biphenol in the aforementioned U.S. Patents Nos. 3,637,595 and 3,975,487, were made by several research groups; however, none of these investigations were successful. Study of the prior art shows that replacement of 4,4-biphenol with hydro¬ quinone leads to materials widi inferior properties. The problem created by the introduction of hydroquinone is basically the following: at high terephthalate contents, high melting generally intractable polymers are obtained; tractability may be achieved at higher isophthalate levels, but the polyesters are relatively low melting and often display low second order glass transition temperatures which lead to low moduli and low heat distortion ternpeiatures. For example, polyesters from p-hydroxybenzoic acid (PHB A) isophthalic acid (IA) and hydroquinone (HQ) were prepared by Deex, U.S. Patent No. 4,377,681. At mole ratios PHBA IA/HQ of 33.3/33.3/33.3 the material had a glass transition temperature of 110°C; when the above coreactants were used at ratios of 5025 25, a Tg of 115°C was obtained. The high melting points of a series of p-hydroxybenzoic acid terephthalic acid/hydroquinone copolymers are graphically illustrated in Figure 2 of the paper by G.W. Calundann, Industrial Development ofThermotropic Polyesters in High Performance Polymers: Their Origin and Development 235-249 (R.B. Seymour and G.S. Kirshenbaum, editors 1986). The publication shows clearly (in Figure 2) that hydroquinone polymers melt at considerably higher temperatures than their 4,4'-biphenol counterparts. The T m of the lowest melting composition shown is about 420°C. Figure 4 of the same publication (p. 243) indicates how one research group was able to depress the melting points of the subject polymers by incorporating naphthalene diols, naphthalene dicarboxylic acids, and hydroxy naphthoic acids into them. From a purely technical point of view, the latter approach was a success; however, the modified polymers were still expensive due to the high cost of the naphthalene-based monomers. The intractability of the hydroquinone-derived materials is discussed in Jackson et al., U.S. Patent No. 4,242,496. Column 2, lines 18-26, states: "U.S. Patent No. 3,637,595 discloses that aromatic liquid crystal polyesters prepared from terephthalic acid, hydroquinone and varying amounts of p-hydroxybenzoic acid melt in the general range of 800° to 900°F. Obviously, the melting point of these polymers is far too high and the thermal stability is insufficient to permit these polymers to be used in conventional melt-processing equipment" It is further stated (column 2, lines 33-40) that a solution to the above problem "was to incorporate a substituent on some of the aromatic rings of the polyester, preferably on the diol ring. For example, it is well known that use of chloro, methyl or ethyl hydroquinone lowers the melting point of the polyester. Although this approach can be used to lower the melting point, typically the mechanical properties are also substantially reduced." The patent goes on to propose the use of phenyl hydroquinone (an expensive comonomer) as the best way whereby the melting point can be reduced to obtain tractable resins, without adversely affecting the mechanical properties. As indicated earlier, pol esters forming oriented melts were made from a variety of substituted hydroquinones. See, for example, Lee et al., U.S. Patent No. 4,600,765; Hutchings et al., U.S. Patent Nos. 4,614,790 and 4,614,791; and Funakoshi et al., U.S. Patent No.4,447.593. Readily processible polyesters made from p-hydroxybenzoic acid, isophthalic and optionally terephthalic acid, hydroquinone and 3,4'- and/or 4,4'-biphenol, 3,4'- and/or 4,4 l -dihydroxydiphenyl ether, 3,4'- and/or 4,4 , -dihydroxydiphenyl sulfide are the subject of Dicke et al., U.S. Patent No. 4,603,190. It should be recognized that once again an expensive monomer is necessary to obtain tractable melts. Similar situations are encountered in a host of other U.S. and foreign patents. See, for example: Portugall et al., European Patent Appln. No. EP-257,558; Hisgen et al., European Patent Appln. No. EP-257,598; Hisgen et al., German Patent Appln. No. DE-3,629,208; Hisgen et al., German Patent Appln. No. DE-3,629,210; and Okamoto et al., World Patent Application No. WO-88 00,955. As pointed out above, tractable materials result at high isophthalic acid levels but the products typically display undesirably low glass transition temperatures. Deex, U.S. Patent No. 4,377,681 states (column 1, lines 31-38): 'Tor example, liquid crystal copolyesters have been prepared from the following fairly rigid molecular species: p-hydroxybenzoic acid, hydroquinone and isophthalic acid. However, when ratios of the monomers are selected to provide tractable polymers, the glass transition temperature is generally low and the high temperature mechanical properties are reduced." Attempts to increase the Tg of these products have been made. Thus, Deex, U.S. Patent No. 4,377,681, claims copolyesters prepared from p-hydroxybenzoic acid, isophthalic acid, hydroquinone and 2,2-bis(4-hydroxyphenyl) propane. The preferred compositions contain from about 20 to about 35 mole percent of p-hydroxybenzoic acid units, and from about 5 to about 12 mole percent of 2,2-bis(4-hydroxy phenyl)propane (bisphenol-A) based on the -total diphenol components. Glass transition temperatures of about 175 to about 190°C were observed in these polymers. These values represent an improvement when compared to the Tg's of the polyesters mentioned supra. However, they must be considered low as they lead to heat distortion temperatures (HDTs) which are, at best, of the order of about 120 to 140°C; moreover, the introduction of bisphenol-A lowers the degree of crystallinity and the rate of crystallization which we believe, as will be discussed infra, leads to lower HDTs. In addition, mold shrinkage of these copolymers is unsatisfactorily high. Park U.S. Patent No. 4,816,552 is directed to polymers prepared by heating a mixture of a 4-acetoxybenzoic acid derivatives hydroquinone diacetate dicarboxylic acid, and a 4-acetoxy-(4-acetoxyphenyl) benzoate derivative in two steps to remove generated acetic acid and form the polymer. This patent is directed specifically to block copolymers with a specific sequence of recurring units. It reportedly has improved spinning processability. Our present invention is produced in a manner well known in the an to produce a random copolymer. As shall be shown infra, our invention is produced by the acidolysis method as disclosed in U.S. Patent No. 3,637,595 which Park acknowledges produces a "partial block," i.e., a random copolymer. Park further states that polymers made by that method have no practical use due to high melting point, high viscosity, and inferior processability (U.S. Patent No. 4,816,552 col. 2, 1. 15-32). The dilemma facing those who have attempted the development of tractable, high HDT, hydroquinone/benzene dicarboxylic aαd/p-hydroxybenzoic acid copoly¬ esters is perhaps best illustrated by Example 1 of Cottis et al., U.S. Patent No. 3,975,487. A polyester having excellent properties, based upon a 1:3 molar ratio of isophthaliαterephthalic acids, p-hydroxybenzoic acid, and 4,4'-biphenol was prepared. When this example was repeated using hydroquinone in place of biphenol and all isophthalic acid as the dicarboxylic acid, a polymer having poorer properties (i.e., a lower flexural strength and a louver modulus) was obtained (column 10, lines 60-63). Copolyesters based on p-hydroxybenzoic acid (PHBA), hydroquinone (HQ), isophthalic (IA) and terephthalic (TA) acids are disclosed in Cottis et al., U.S. Patent No. 3,637,595. Cottis shows one example in which a resin incorporating all of the four monomers is described (Example 10). The polymer was formed from 1.0 mole of PHBA, 0.5 moles of IA, 0.5 moles of TA, and 1.0 moles of HQ. It was poorly characterized; weight loss in air, at 752°F was apparently high, indicating thermal stability problems. Our own characterization of the resin produced by the preferred process utilized in this invention (see Experimental, Comparative Example 2 also designated as X) showed that it possessed a low HDT (214°Q). Thus, the elusive goal of developing a low cost hydroquinone-based crystalline polymer which when filled with 30 percent by weight of glass fibers (1) has an HDT of at least 240°C and preferably 280'C and higher, (2) is melt-processible below the decomposition temperature of about 415°C (3) has a melting point in the range of 340 to 400°C a crystallization temperature of 300 to 340°C and a crystallization rate of at least 1,000 counts per minute, has not been achieved in the prior art In fact based on the prior art, it appears unlikely that polymers having these properties can be produced, particularly polymers consisting essentially of units (I), (H), (HI), and (TV). Furthermore, even though the overall combination of properties of the neat unblended polymers is outstanding, they may form molded parts that show undesirable blistering (i.e., raised areas). It has now been discovered that die addition of a first polyester polymer (a) comprising recurring moieties of dihydroxyarylene comprising hydroquinone, a noπvicinal benzene dicarboxylate (preferably terephthalic acid and mixtures of terephthalic acid and isophthalic acid) and p-oxybenzoate to a second polyester polymer (b) comprising recurring moieties of naphthalene based monomers and/or diphenol, nonvicinal benzene dicarboxylate and p-oxybenzoate, wherein said polymers and the moieties rαaking up the polymers are present in specified proportions, yields alloys in which the tendency to blister is substantially reduced or eliminated and also having increased strength and good fabricability. The preferred mole ratios of monomers of the base polyester are depicted in the triangular diagrams and are described infra. The polymers melt in the range of from about 300 to about 420°C, preferably 340-400°C. Of particular interest are the polyesters falling into area A of Figure 1. With some known exceptions, mixtures of polymeric materials are generally immiscible. That is, they consist of domains of chemically distinct phases. Usually, one component forms a continuous phase, while the other component forms roughly spherical domains as inclusions. Under some circumstances, bi-continuous structures are also obtainable. Mixing two arbitrarily chosen polymers usually results in inferior materials having no utility, since in the absence of adhesion between phases, the dispersed phase merely weakens the continuous phase. Some polymeric products, such as the wholly aromatic polyesters, exhibit an ordered structure in at least some regions of the polymer. This order can exist in one, two or three dimensions. The incorporation into blends of polymers exhibiting an ordered structure leads to an increased tendency of the blends to separate into phases. This is believed to be due to the fact that the order found in certain regions of the resin causes a fairly sharp boundary between the domains of the molecules of the component polymers. Hence, blends including such polymers would be expected to exhibit a significant reduction in _- properties. It should be noted, however, that many useful blends whose morphology and phase interaction are favorable, are known. Cottis, U.S. Patent No. 4,563,508, is directed to the improvement of molding compounds based on wholly aromatic polyesters by the addition of a minor amount of a flow modifier. The flow modifier crystallizes poorly and improves the flow of the highly αystøllized base polymer it is added to. The flow modifier does not enhance the » end propeπies of the blerctcomposition. It is to be noted that the addition of the flow modifier decreases the HDT o__-he: * co__p___tion and does not increase the strength. T-akayaπagi et al, U.S. Patent No. 4,228,218, discloses a polymer composition comprisin .-Sy percent OT less, based upon the total weight of polymeric material, of a first rigid polymeri'with'.the balance being a second polymer composed substantially of flexible molecular chains;. The first polymeric material is dispersed in d e second polymeric material in a microscopic region of 1 μ or less. It is believed that wholly aromatic polyesters would be characterized by those skilled in the art as rigid molecules wid in the context of the above cited patent Hie patent does not disclose blends of two or more polymers having rigid chains with improved blister resistance as does the present invention. Blends of polymers exhibiting orientation in the melt with other polymers were investigated. Mixtures of liquid crystalline polyesters with poly(alkylene terephthalates), polycarbonates and polyarylates were described in Cincotta et al., U.S. Patent Nos. 4,408,022 and 4,451,611; Froix, U.S. Patent Nos. 4,489,190 and 4,460,735; and in Kiss, European Patent Application No. 169,947. Improved mechanical properties were found witii these materials. The addition of a particular liquid crystal polymer to poly(butylene terephthalate) or other thermoplastic polymers was described as a method to obtain compositions with enhanced resistance to melt dripping during burning (see Kim et al., U.S. Patent No. 4,439,578). In several instances, e.g., in alloys of liquid crystalline polyesters with an aromatic sulfone polymer (Froix et al., U.S. Patent No. 4,460,736) with an aromatic poly(ester amide) (Kiss, U.S. Patent No. 4,567,227), and with poly(arylene sulfides) (Froix, U.S. Patent No. 4,276,397) improved mechanical characteristics and improved processibility (lower viscosity) of the non-anisotropic resin were noted. Better properties were also obtained by blending two particular liquid crystalline polyesters (see, for example, Froix, U.S. Patent No. 4,267,289). Liquid crystalline materials, including polyesters, were used to decrease d e viscosity and improve the processibility of a number of other resins, including fluorinated polyolefins (see Bailey et al., U.S. Patent No. 4,417,020; Cogswell et al., U.S. Patent Nos. 4,429,078 and 4,438,236; and George et al., U.S. Patent No. 4,650,836). In one instance (Bailey et al., U.S. Patent No. 4,508,891), it was claimed that the addition of an isotropic resin to an anisotropic resin leads to a decrease of anisotropy in the corresponding molded articles. The fracture-surface morphology of thermotropic 6-hydroxy-2-naphdιoic acid- p-hydroxybenzoic acid copolymer blends with nylon 6, poly(butylene terephthalate), and polycarbonate prepared by screw injection molding, was studied by Beery et al. J. Mater . Sci. Lett. 1988. 7(10), pp. 1071-3. The morphology was found to be strongly dependent on d e flow history and on d e composition of me subject mixtures. A commonly assigned patent application entided ' lixtrusion-Grade Compositions Comprising Mixtures of Wholly Aromatic Polyesters," Serial No. 060,038, filed on June 9, 1987, in the names of Field et al., now U.S Patent 4,851,480, hereby incorporated by reference, describes alloys of a first polyester comprising recuπing moieties of 4,4'-biphenol, terephthalate, and p-oxybenzoate; with a second polyester comprising the same recurring moieties, but wherein the proportion of the p-oxybenzoate units is higher than in the first polyester. The application discloses d at while each individual polyester is difficult to extrude into acceptable products, their alloys provide good extrusion grade compositions. Molding compositions comprised of d e above first and second polyester, filler, and optionally a polymeric flow modifier are claimed in commonly assigned U.S. Patent Application entitled "Molding Compositions Comprising Mixtures of Wholly Aromatic Polyesters and Fillers," Serial No. 060,114 filed on June 9, 1987 in the name of JJ. Duska, hereby incorporated by reference. Thus, it is known from the prior art that it is possible to alloy two polyesters, wherein said polyesters are based on identical monomers but differ in the relative proportion of die monomers, wherein each of said polyesters has unsatisfactory molding and extrusion characteristics and obtain good molding and extrusion grade compositions. No reference is known which is directed to die improvement of surface properties (i.e., blistering) by blending two polymers having orientation in die melt A feature of the instant invention tiiat is totally unexpected and highly remarkable is the fact that compatible blends showing good mechanical and surface properties are achieved by alloying two crystalline wholly aromatic copolyesters prepared from monomers having totally different structures, e.g., phenylene versus naphthalene or biphenylene. The enhanced blister resistance is particularly astonishing. Indeed, while the blister phenomenon is not fully understood, it has been attributed to non-homogeneity in random copolymers. In any event, as indicated earlier, alloys of materials having ordered structures would be expected to have reduced properties. Hence, die instant discovery was highly surprising and totally unexpected- It is die general object of the present invention to provide novel, inexpensive, melt-processible hydroquinone poly(iso-terephthalates) containing residues of p-hydroxybenzoic acid polymers which form a highly tractable oriented melt phase, and which are capable of melt extrusion to form quality, high performance fibers, films, three-dimensional molded articles, etc. The polymers display high HDTs which are essential in certain high heat applications. They have good flexural strength and produce good fibers. When blended with other polymers they produce inexpensive high heat polymers capable of high HDTs and still produce an attractive blister- resistant surface. It is a further object of the present invention to provide novel, melt-processible hydroquinone poly(i-θ- terephthalates) containing residues of p-hydroxybenzoic acid, polymers which form a melt phase below 400°C in the substantial absence of polymer degradation, unlike many other polymers which include relatively high concentrations of the 4-oxybenzoyl moiety. These and other objects, as well as die scope, nature and utilization of d e invention will be apparent to those skilled in the art from the following detailed description. The Invention It was unexpectedly discovered diat copolyesters, consisting essentially of units (I), (II), (HI), and (IV) where p is approximately equal to q + r, die values of p, q, r and s are as hereinbelow defined; and having molecular weights in the range of from about 2,000 to. about 200,000, display an outstanding combination of properties. The subject polymers form a stable oriented melt phase at 340 to 400°C, preferably from 340 to 380°C; the melt phase is tractable and can be melt-extruded below its decomposition temperature to form quality, high performance fibers, films, molded articles, and d e like. Fabricated products show high strength as well as good retention of properties at high tempera¬ tures. Advantageously, materials filled with 30 percent by weight of glass have heat distortion temperatures of over 240 to about 280°C and higher, under a load of 264 psi. It is believed tiiat the higher die amount of crystallinity of the polymer the higher die heat distortion temperature (HDT) will be. The αystallization temperatures of the subject copolymers are in the range of from 300 to 340°C, preferably from 310 to 340°C; and tiieir crystallization rates are at least 1,000 and up to 3,500 counts per minute, preferably from 1,500 to 2,000 counts per minute. Some of me preferred novel copolymer compositions which combine the above- mentioned outstanding properties are plotted in the triangular phase diagram Figure I. The diagram shows die compositional area of interest, area A. The coordinates for each point of this area define a copolyester in terms of percentages of p-oxybenzoyl, hydroquinone terephthaloyl and hydroquinone isσphthaloyl units. Percentages for graph purposes of p, q, r and s can be calculated from the molar compositions by assuming p is constant at 1.0 mole and by adding die total moles of q r/s as the denominator and dividing tiiat into die moles of each monomer, thereby calculating the percentage of each constituent For example, if die molar concentration of q/r/s/p, respectively, are: 0.5 0.50.25/1.0, the percentages are &5Q + __ + c> 1 ___ = 100% 1.25 1.25 1.25 q r s As indicated above, the properties of the polymer are somewhat dependent on the method of synthesis. It should be noted tiiat the criterion for borderline compositions on the phase diagram is that die HDT as measured on 30 percent glass- filled products under a load of 264 psi is about 240 to about 280°C and higher. Accordingly, tiiose polymers which are melt-processible and which yield HDTs of from about 240°C to about 280°C are considered as falling within the scope of die instant invention. It is important to point out tiiat melting points, HDTs, crystallization temperatures and crystallization rates are basic property parameters that determine polymer performance. Thus, a very high melting point above 400°C results in materials that are either difficult to melt-fabricate or plain intractable (vide supra). Lower melting points lead to resins having lower HDT 's. High heat distortion temperatures are very important in certain applications since they indicate die upper temperature at which the particular polymer is useful, especially in structural applications. As indicated earlier, two additional useful characteristics of the instant copolyesters are their crystallization temperature and crystallization rate. By crystallization temperature is meant the temperature at which onset of crystallization takes place; it is generally in die range of from 300 to 340°C preferably from 310 to 340°C. The crystallization rate is expressed as an increase in counts per minute as measured by X-ray techniques (see below); this increase is of the order of at least 1,000 to 3,500 counts per minute, preferably of from 1,500 to 2,000 counts per minute. Crystallization temperatures and rates of crystallization are related to d e degree of crystallinity of the material. If tiiese two parameters are low, the high temperature characteristics of die polyester develop slowly. On die odier hand, if die above two parameters are too high, standard molding of d e polymer becomes difficult and more severe fabrication conditions (e.g., higher temperatures), or techniques such as compression molding, impact molding or plasma spraying have to be utilized. Melting points, crystallization temperatures and rates of crystallization were determined using X-ray techniques. A brief description of tiiese techniques follows. The crystalline melting point is measured by following the intensity of die X-ray diffraction of d e most intensive peak as a function of temperature. The most intensive diffraction peak is located at a spacing of about 4.5 A. Based on literature data [J. Polymer Sci., Polym. Chem. Ed., H. 2207 (1976); J. Polymer Sci., Polym. Chem. Ed., 2 2249 (1983)], die subject peak has been tentatively assigned to the distance between the polymer chains. The point at which die intensity reaches a minimum is considered for the polymer melt temperature. The rate of temperature change is 100°C per minute. The onset of cry s-___i_ * ation is taken as the temperature at which there is a sharp increase in the intensity of tiie X-ray peak referred to above. Again, die rate of cooling is 100°C per minute. Crystallization rate is defined as die difference between die intensities of die above X-ray peak at the crystallization temperature and at 40°C below that temperature, the rate of cooling being 100°C per minute. A detailed description of die three methods is given in d e Experimental. Note that throughout this patent all melting and crystallization data refer to the second heating/cooling cycle of the sample (see Experimental). It is important to note that die instant invention does not reside in the use of novel monomers; the critical factor of the present invention is the discovery tiiat polymers having the particular combination of physical properties can be obtained when die four monomers, i.e., p-hydroxybenzoic acid (PHBA), hydroquinone (HQ), isophdialic acid (IA) and terephthalic acid (TA), are used in certain amounts and are produced by the preferred method. The metes and bounds of die present invention have been defined by die circumscribed area of A in Figure I in conjunction witii the aforementioned physical properties. While it is difficult to calculate a numerical range of monomer units, for convenience, the following ratios are given: The most preferred type of polymers are depicted in area A and have die following approximate monomer ranges based on moles: s * 0.25 to 0.55; q « 0.5 to 0.666; and r - 0.334 to 0.5. Particularly, area A is bound by die following: when s - 0.25 q - 0.5 to 0.6375 r - 0.5 to 0.3625; when s * 0.55; q - 0.5 to 0.666 r - 0.5 to 0.334 It is to be noted tiiat there may be polymers that fall within area A and in the above ranges that would be outside of die scope of the present invention as defined by die physical properties required (i.e., a melting point range of about 340 to 400 C C, a crystallization temperature of 300 to 340°C and crystallization rate of at least 1,000 counts/min and an HDT of about 240 to 280°C and higher under a load of 264 psi for 30 weight percent glass fiber filled). As indicated earlier, the compositional areas which cover the materials of tiiis invention are depicted on the attached triangular phase diagram Figure I. Clearly, tiieir existence was neitiier anticipated nor predicted by the existing prior art The syndiesis of the polyesters of the instant invention is described generally in Cottis et al., U.S. Patent No. 3,637,595 entitled "P-Oxybenzoyl Copolyesters," and in Finestone, U.S. Patent No.4,742,149 entitled "Production of Melt Consistent Aromatic Polyesters"; the disclosure of die aforementioned two patents is incorporated herein by reference. The bulk condensation of aromatic polyesters is described in die patent literature and broadly considered involves an alkanoylation step in which a suitable dicarboxylic acid, hydroxybenzoic acid and diol are reacted with an acid anhydride; a prepoly- merization step in which the reaction product of the first step is polycondensed to prepare a prepolymer, and die prepolymer is thereafter heated in a third step to produce a polycondensate of the desired degree of polymerization. Thus, in somewhat greater detail, die instant copolyesters are prepared by charging into d e reactor the required amounts of isophdialic and terephthalic acids, p-hydroxybenzoic acid and hydroquinone. An anhydride of a lower monocarboxylic acid, preferably an anhydride of a C 2 to C 4 monocarboxylic acid, is added in at least stoichiometric amounts. It is most preferred to use acetic anhydride; its amount is preferably from about 5 to about 20 mole percent over that required for the acetylation of all of the hydroxyl groups. The acetylation reaction takes place at about 140°C for a period of time of from about 2 to about 6 hours. The reaction mixture is then heated to about 240 to 320°C at a rate of about 10 to 40°C per hour, and is kept at about 240 to 320°C for approximately a few minutes to about 4 additional hours. The low molecular weight polymer obtained is then solid state advanced to die required high molecular weight by heating to a tetnperature of from about 265 to about 340°C, for a period of time of from about one to about 24 hours. A preferred variant as described in Finestone, U.S. Patent No. 4,742,149, comprises adding a salt particularly an alkaline earth metal salt cr an alkali metal salt preferably potassium sulfate, during die preparation of the resin and particularly to d e prepolymer melt prior to advancement of me final product -to the desired degree of polymerization. The incorporation of stabilizing amounts of phosphites, as described in Cottis, U.S. Patent No. 4,639,504 is also advantageous. The polyesters of die present invention commonly exhibit end groups depending upon the synthesis route selected. As will be apparent to those skilled in the art, the end groups optionally may be capped, e.g., acidic end groups may be capped with a variety of alcohols, and hydroxyl end groups may be capped with a variety of organic acids. For instance, end capping units such as phenyl ester or methyl ester optionally can be included at d e end of die polymer chains. The polymers can be annealed below dieir melting points for a period of time of the polymers may be oxidatively crosslinked to at least some degree, if desired, by heating in an oxygen-containing atmosphere (e.g., in air) while in bulk form or as a previously shaped article at a temperature below dieir melting points for a limited period of time (e.g., for a few minutes). The polyesters of the present invention tend to be substantially insoluble in all common polyester solvents such as hexafiuoroisopropanol and o-chlorophenol, and accordingly are not susceptible to solution processing. They can surprisingly be readily processed by known melt processing techniques as discussed hereafter. The polyesters of the present invention commonly exhibit weight average molecular weights of about 2,000 to about 200,000. The instant polyesters can be melt processed in the substantial absence of polymer degradation to form a variety of relatively stiff shaped articles, e.g., molded three-dimensional articles, fibers, films, tapes, etc. The polyesters are suitable for molding applications and may be molded via standard injection molding techniques commonly utilized when forming molded articles. Unlike die polyesters commonly encountered in the prior art it is not essential that more severe injection molding conditions (e.g., higher temperatures), compression molding, impact molding, or plasma spraying techniques be utilized. Fibers or films may be melt extruded. In some instances, as described in Cottis et al., U.S. Patent No. 4,563,508, melt fabrication may be facilitated by adding flow aids. The polymers of tiiis invention may contain up to 10 mole percent (based on total reactants) of carbonate linkages and/or aromatic comonomers other tiian (I)-(-V), such as biphenol, provided that the use of said carbonate linkages and/or comonomers does not unfavorably affect die very attractive properties of die instant copolyesters. As stated supra, the present invention provides also an improved blend of two wholly aromatic polyester polymers. As used herein, the term "blend" includes any physical blend, mixture, or alloy of die polymeric components. The aromatic polyesters are considered to be "wholly" aromatic in die sense tiiat each moiety present in the polyester contributes at least one aromatic ring to the polymer backbone. Blends comprising about 1 to about 19, preferably about 1.5 to about 9, parts by weight of a first polyester (a) comprising units (I), (H), (HI) and (IV): where p is approximately equal to q + r; q is in the range of from about 0.05 to about 0.76; r is in the range of from about 0.95 to about 0.24; s is in the range of from about 0.10 to about 9.0 moles per each mole of unit I; and where said first polyester has a melting point of from about 270 to about 420° C; and (b) one part by weight of a second polyester comprising units (IX), (X) and (XI): ( X ) wherein e is approximately equal to f; e is one; and g is in the range of from about 1.5 to about 5, preferably in the range of from about 2 to about 4 moles, per each mole of monomer corresponding to unit (DQ; where the molecular weight of said polyesters (a) and Ob) are in die range of from about 2,00 to about 200,000; are easy to melt fabricate, display vastly improved moldability, yield parts pleasing to the eye; and, surprisingly, show a reduced tendency to blister on molding. A totally unexpected and surprising feature of the instant blends is tiiat botii their moldability and die surface characteristics of the molded objects obtained from them, are better than the corresponding properties of the individual polyesters. In addition, the materials display improved mechanical properties over those of the constituent polymers. Heat distortion temperatures, both on neat or on 30 percent by weight glass fiber filled compositions, are at least 200 * C and may be as high as 350" C and higher under a load 264 psi. The novel copolyesters of the present invention yield particularly interesting blends comprising a first polyester comprising units derived from a dihydroxyarylene consisting essentially of dihydroxybenzene and dihydroxybiphenyl; nonvicinal benzene dicarboxylic acids and p-hydroxybenzoic acid; and a second polyester comprising units derived from at least one of a naphthalene-based monomer and units derived from a diphenol, a nonvicinal benzene dicarboxylic acid and p-hydroxybenzoic acid. More particularly, it was discovered tiiat blends comprising about 1 to about 19, preferably about 1.5 to about 9, parts by weight of a first polyester (a) to about 1 part by weight of a second polyester (b), and wherein (a) comprising units (I), (H), (HI) and (IV): where p is approximately equal to q + r, q is in the range of from about 0.05 to about 0.76; r is in the range of from about 0.95 to about 0.24; s is in the range of from about 0.10 to about 9.0 moles per each mole of unit p; and where said first polyester has a melting point of from about 270 to about 420° C; (b) comprising units (V), (VI), (VH) and (VHI): where a is approximately equal to b + c; b is in the range of from about 0.5 to about 0.8; c is in die range of from about 0.5 to about 0.2; and d is in the range of from about 1 to about 7, preferably from about 2 to about 4 moles per each mole of unit (V); where said polyesters (a) and (b) have molecular weights in the range of from about 2,000 to about 200,000, are easy to melt fabricate and yield injection molded parts tiiat surprisingly show a significantly decreased tendency to blister. In addition, the materials display improved mechanical properties over those of the constituent polymers, as well as improved processibility, composites containing about 30 weight percent of glass fibers, have heat distortion temperatures (HDTs) of at least 240°C, when measured under a load of 264 psi. Some of die compositions corresponding to the wholly aromatic polyesters of the first polyester (a) are plotted on the triangular diagram Figure 1 as discussed supra. The coordinates for each point of this area defines a copolyester in terms of molar percentages of monomer units. The polymers of area A (Figure 1) are characterized in that (1) tiiey are melt processible below dieir decomposition temperatures; (2) their melting points are in the range of 340 to 400°C; (3) their αystallization temperatures are in the range of 300 to 340°C; (4) their rates of crystallization are at least 1,000 counts per minute; and (5) tiiey yield composites having heat distortion temperatures under a load of 264 psi of about 240 to about 280°C and higher, when filled witii 30 percent by weight of glass fibers. Also, the instant invention comprises blends of from about 1 to about 19 to about 5 to about 95 parts by weight of a first polyester polymer (a) comprising units (DC), Qi), (XI) and (XII): where n is 1 or 1 and 2; die number of moles of units (IX) is approximately equal to the number of moles of units (X) and (XI); or a first polyester comprising units (DCb), ( Cc), (XIa), (XHa): wherein e' + e" is approximately equal to f + g; the ratio of e' to e" is from about 3: 1 to about 99: 1 ; the ratio of f to g is from about 0.42: 1 to about 10: 1 ; and die ratio of h to f + g is from about 0.15:1 to about 8.0:1; moles per one mole of monomers corresponding to d e sum of units (DCb) + (DCc); per one part by weight of a second polyester polymer (b) comprising at least one unit : — XJ - AΓ - XJ — (XΠD wherein Ar comprises at least one member selected from the group consisting of: Xι and X 2 are independently selected from the group consisting of oxy and carbonyl ; optionally in conjunction witii at least one unit comprising : — X ! - Ar - X 2 — (XVHD wherein X and X 2 are as previously defined, and die Ar group of die second polyester may also comprise a divalent aromatic radical comprising at least one phenylene group, such as phenylene, biphenylene and oxybiphenyl; botii polyesters having molecular weights of from about 2,000 to about 200,000. The instant blends are generally easier to melt fabricate, display improved moldability and yield parts pleasing to the eye with good surface characteristics. Unexpectedly, die materials have improved mechanical properties that are quite often superior to the properties of the two constituent polymers. Heat distortion temperatures, botii on neat and on 30 percent by weight glass filled blend compositions, are at least 175°C and may be as high as 300°C and even higher, when measured under a load of 264 psi. As indicated above, the first wholly aromatic polyester useful in die last series of blends of the instant invention comprises units (DC), (X), (XI), (XII), (DCb), (DCc), (Xa), (XIa) and (XHa). A vast number of materials can be prepared from said monomers; the following compositional ranges are of particular interest [where e, f, g and h denote die molar proportions of said units (TX), (X), (XI) and (XII), respectively]: (I) those wherein n = 1; e is approximately equal to f + g; f is in die range of from about 0.05 to about 0.76; g is in the range of from about .95 to about 0.24; h is in the range of from about 0.10 to about 9.0, based on die total number of moles of monomer 1 corresponding to units (EX); and (H) those wherein n is 1 and.2, i.e., which are based on hydroquinone and 4,4-biphenol as the dihydric phenol component; die total number of moles of hydroquinone and 4,4-biphenol (e") is approximately equal to the total number of moles of terephthalic and isophthalic acids (f + g); the ratio of f to g is in the range of about 0.42:1 to about 10: 1; the molar ratio of hydroquinone to 4,4-biphenol is from about 3:1 to about 99:1; and the ratio of h to f and g is 0.15:1 to 8:1. The second wholly aromatic polyester optionally has in its chain a naphthalene-based monomer. There are of course a great number of materials that meet this requirement Especially preferred, however, are d e copolyesters which are disclosed in U.S. Patent Nos. 4,161,470; 4,184,996; and 4,256,624, herein incorporated by reference. The polyester disclosed in U.S. Patent No. 4,161,470 is a melt processible wholly aromatic polyester which is capable of forming an anisotropic melt phase at a temperature below approximately 350°C apart from die blend. The polyester consists essentially of the recurring moieties (XK) and (XX) which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring: with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, and mixtures of the foregoing. The wholly aromatic polyester there disclosed comprises approximately 10 to 90 mole percent of moiety (XDC) and approximately 90 to 10 mole percent of moiety (XX). The polyester disclosed in U.S. Patent No. 4,184,996 is a melt processible wholly aromatic polyester which is capable of forming an anisotropic melt phase at a temperature below approximately 325°C apart from die blend. The polyester consists essentially of the recurring moieties (XX), (XXI), and (XXH): The wholly aromatic polyester there disclosed comprises approximately 30 to 70 mole percent of moiety (XX). The polyester preferably comprises approximately 40 to 60 mole percent of moiety (XX); approximately 20 to 30 mole percent of moiety (XXI); and approximately 20 to 30 mole percent of moiety (XXH). Each of die moieties of die polyester is free of ring substitution. The polyester disclosed in U.S. Patent No.4,256,624 is a melt processible wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 400°C apart from the blend. The polyester consists essentially of die recurring moieties (XDC),'(XXn_) and (XXIV) which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring: wherein Ar is as previously defined; with said optional substitution, if present, being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group and mixtures of the foregoing. The polyester comprises approximately 10 to 90 mole percent of moiety (XDC), approximately 5 to 45 mole percent of moiety (XXEQ), and approximately 5 to 45 mole percent of moiety (XXIV). The phenomenon of blistering is known. Blisters may occur near a surface or in the bulk of die sample. Here, we are mainly concerned with surface blisters; note, however, tiiat small internal blisters or voids may also be detrimental to material performance. Moldings based on polymers that show orientation in the melt display skin-core effects. Hence, phenomena observed in these systems are often analogous to those encountered in coatings and composites. In composites, for example, blistering and delamination occur especially between two layers of different composition. In coatings, blistering is known to be a localized delamination at an interface; it depends on the diffusion of chemicals such as water and degradation by-products. The difference in the tiiermal expansion coefficient between a - coating and die substrate can create stresses and may weaken die interface. A blister may then form with less pressure difference, due to volatiles, than in cases where these stresses are absent In summary thus, blistering is due to a surface layer delamination and can be caused eidier by trapped volatiles or by built-in stresses. Most probably both factors are at work. Two types of blistering are encountered witii polymeric materials: (1) molding blisters and (2) oven blisters. Blisters which occur during molding generally indicate die presence of degraded material. Quite often parts having acceptable surface characteristics are obtained upon molding. However, when tiiese parts are treated at high temperatures for a certain period of time, blisters ("oven blisters") often appear. These do not necessarily indicate die presence of degraded material as a result of molding. It is of paramount importance tiiat molding of the polymer does not yield parts having a blistered surface. It should be noted tiiat die configuration of a part is also quite often a factor in mold blistering. In any event, if molding blisters are detected upon visual examination, the part will generally blister to a considerably greater extent when exposed to heat treatment Thus, the particular molding compound is most probably of inadequate quality. If, on the other hand, a good looking molding part is obtained, there is no assurance as to what the results of "oven testing" will be. For high temperature applications, it is imperative that oven blistering be also either absent or significantly minimized. The oven test and the method of blister rating are described in the Experimental. The blends of the instant invention show a considerably decreased tendency to blister — both during molding and in the oven test Molding compounds and articles may be made from the subject copolyesters and blends by incorporating tiierein fillers; and/or reinforcing agents. One attractive application of the novel copolyesters of the instant invention is, for example, in ovenware. Both the neat polymer blends, or composites, as disclosed by Duska et al., U.S. Patent No.4,626,557 are useful in this application. Molding compounds of interest in ovenware are described in commonly assigned U.S. Patent application entitled "Novel Plastic Ovenware Compositions," Serial No. 255,753. Articles may also be molded from a molding compound which includes, as one component polymers or blends of die present invention. Such a molding compound incorporates into the present invention approximately 1 to 70 percent preferably approximately 10 to 55 percent, by weight based upon die total weight of die molding compound, of a solid filler and or reinforcing agent Representative agents which may serve as reinforcing media and fillers include glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool and wood cellulose fibers, etc., glass beads, calcium silicate, silica, clays, talc, mica, carbon black, titanium dioxide, wollastonite, polytetrafluoroethylene, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, etc. The molding compounds are useful in a variety of applications including high temperature applications, for example, in cookware and electrical articles, and d e like. The novel plastic compositions of die present invention can be fabricated into permanent ovenware capable of repeated use in conventional thermal and microwave ovens. It has been found in accordance witii tiiis invention tiiat a -uiuf σrm and pleasing appearance can be imparted to ovenware articles and any undesirable bubbling can be suppressed or mirdmized by the inclusion of talc in the oxybenzoyl compositions from which they are molded. The talc contains a minimum amount of materials decomposable at elevated temperatures, e.g., up to about 800°C, such as magnesium carbonate. Among such talcs are talcs which are of high purity, are selectively combined from various ores or have been calcined or subjected to acid treatment These talcs which are employed according to the present invention are characterized by a low weight loss on ignition, a low iron content analyzed as iron oxide, and a closely controlled particle size. The weight loss on ignition of the suitable talcs is not more than 6 percent or less at 950°C and is 2 percent or less at 800°C. The iron content analyzed as iron oxide O e^C^) will not be more an about 1 percent and tiiat of the particularly preferred talcs will not be more than about 0.6 percent and may be less. In addition, the particle size distribution of the talc must preferably be such that about 90 to 95 percent of the particles are less tiiat about 40 microns. Experiments and tests carried out have demonstrated quite conclusively that it is essential to use such talc. The use of otiier forms of talc does not provide satisfactory properties in the finished molding product However, such otiier forms of talc can be employed in conjunction with the specified talcs in amounts of from about 0.05 percent to about 20 percent of the required forms of talc. The talcs containing the minimum amounts of decomposable material will be present in amounts of from about 1 percent to about 60 percent based on die total composition weight with the preferred range being from about 35 percent to about 55 percent. Rutile. titanium dioxide can also be employed in conjunction with the talc material, including mixturcs of highly refined talcs and otiier talc. The rutile titanium dioxide-will ' bepresent in a proportion of from about 2 percent to about 20 percent based on the weight of die total composition. The preferred range is from about 2 percent to about 15 percent In die ovenware articles of the present invention, the resin will generally comprise from about 30 percent to about 85 percent and d e total inerts from about 70 percent to about 15 percent For optimum results, the inerts will comprise from about 40 percent to about 55 percent of the molding compositions. The inerts will comprise up to about 55 percent of highly refined talc and from about 0 to about 15 percent of titanium dioxide. The compositions of the present invention can be prepared by extrusion in accordance with generally known practice. For example, a twin screw extruder can be employed: witir. addition of die polymer, selected talc, and titanium dioxide at die feed throat and witii addition of die glass roving at both die vent and feed throat The compositions so prepared can tiien be injection molded according to general practice using techniques familiar to the injection molding field. Examples The following examples serve to give specific illustrations of die practice of this invention but they are not intended in any way to limit the scope of this invention. The examples and comparative examples are plotted on d e triangular phase diagram. Experimental Procedures The following procedures were used to obtain d e data given in the examples. A. X-rav Measurements 1. Apparatus X-ray diffraction data were obtained using a Philips XRG-3000 X-ray generator equipped with a vertical diffractometer, a long, fine focus copper X-ray tube, a Paar HTK-10 high temperature diffractometer attachment and a Paar HTK-heat controller. Diffractometer position is controlled by computer, which also measures and records radiation count rate produced by sample ca stallinity, and sample temperature. (a) Determination of the Polymer Melting Point A sample of the polymer is submitted to a preliminary X-ray diffraction scan between 15 and 25 degrees two-theta angle by increasing the temperature by increments of 60°C within a temperature range from about 200 to about 480°C. This allows de-termination of die approximate temperature at which die peak located at approx * imately 19.7 degrees two-theta (4.50 A d-spacing) reaches its minimum. valύe^Le., an approximate melting point A second-degree polynomial equation is derived from die above data; this polynomial equation now allows to follow die peak angle-as die sample temperature is varie The temperature at which die peak height reaches a minimum (i.e., touches die baseline), is considered to be d e melting point The polymer sample is now heated and cooled at a rate of 100°C per minute between die previously mentioned temperature limits, and its melting point is deter¬ mined Since the melting point of a crystalline material often changes on heating and cooling (due to recrystallization, further polymerization, etc.), the sample is cooled and reheated This-allows de-termination of die melting point on die second heating cycle. Generally, thessecond cycle yields a melting point which remains approximately constantif additional heating or cooling cycles are performed Therefore, the value obtained in die second heating cycle is taken as the polymer melting point (Jo) Crysta.1-i7.ation Temperature (onset of CTys gπ-ization') The onset of crystallization is measured in die same manner except that the scanning (for details,see above), is performed while die sample is cooled at 100°C per minute. The temperature at which die peak emerges from the baseline during die second cooling cycle is considered as the onset of crystallization. (c) Crvstallization Rate At every temperature below die sample melting point die intensity of X-ray diffraction of a crystalline material can be expressed as counts per second (or any unit of time). The increase in the number of counts per unit of time while the sample is being cooled at a certain rate (100°C per minute) is therefore proportional to die rate of crystallization. A temperature interval starting at the onset of crystallization and 40°C below tiiat temperature was arbitrarily chosen. Rates of crys__Uization are expressed as the increase in counts per minute for a sample cooled witiiin tiiese temperature limits during the second cooling cycle. B. DMA Flexural Modulus The measurement is performed using a Dupont Dynamic Mechanical Analyzer φMA), Model 982 in conjunction with a thermal analyzer, Model 1090. The DMA measures changes in the viscoelastic properties of materials as a function of time and temperature. Tests are conducted at a heating rate of 5°C per minute. When the run is complete, the stored data is analyzed; die storage modulus (very similar to d e flexural modulus) and die loss modulus are calculated and plotted as a function of temperature. The modulus is expressed in GPa's and die temperature in degrees Centigrade. Conversion into psi's is performed using die equation: Modulus (psi) = Modulus (GPa) x (1.45x10 s ) C. Compressive Flow (CF) The term "Compressive Flow" (CF) as used in this application is a measure of the flow of a weighed sample when pressed on a Carver press at 5,000 pounds. It is also an indirect measure of the polymer molecular weight; the higher the CF value at a given temperature, die lower is the molecular weight of the wholly aromatic polyester. CF is measured from die area of a disc obtained from a sample of powdered material of given weight usually 0.5 to 1.0 grams which has been pressed between two parallel plates. In carrying out the determination of this characteristic, a sample is pressed between two sheets of aluminum foil which in turn are backed by chromium-plated steel plates 6" x 6" x 1/4". A Carver 2112-X Model No. 150-C hydraulic press modified for 800°F is used to press the sample. The particular teroperature of die press is that indicated in each sample run. The sample material is allowed to stand for 5 minutes between the plates at holding pressure in order tiiat the temperature of the material can equilibrate with the press temperature. A load of 5,000 pounds is tiien applied for 2 minutes. The CF is then calculated on die following basis. The area of the pressed molding compound is measured by cutting an aluminum sandwich out of d e sample pressed between the two aluminum foil sheets. The aluminum foil has a known area/weight relationship called the foil factor. The area is normalized for the pressure of the applied load and tiiat number is multiplied by 100 to give a number greater than 1. The compressive flow is then calculated by means of the following equation: CF = X IOO Applied Load (Kg) X wt of sample D. Blister Rating Samples to be tested are preconditioned at 20 to 25°C 50 ± 5 percent relative humidity for 48 hours. Test sample lot normally includes five tensile bars (1/8" thick), five HDT bars (5" x 1/2" x 1/4" thick) and five flex bars (5" x 1 2" x 1/8" thick). The samples are carefully inspected and any existing cracks and/or blisters are circled. The samples are then annealed in an oven which has been equilibrated at 232°C (450°F) for a period of 4 hours. They are tiien removed, cooled and inspected Rating codes follow: 0 - no new blisters; 1 - very slight blistering (one or two very small blisters) 2 - slight blistering (three to six small blisters); 3 - moderate blistering (a few large blisters and/or many small blisters; and 4 - heavy blistering (many large or small blisters covering more than half of of the specimen surface. The numerical blister rating is calculated using the equation: n R = l/n ∑ X; 2 i = 1 where R - numerical blister rating (0-16); n = number of samples tested; X- = blister rating sample i (0-4). In the above calculation, the individual ratings for the entire set of test samples (tensile bars, HDT bars, flex bars) are generally treated as a single population. The ratings vary within the range of 0 (no blistering) to 16 (severe blistering, worst case). E. Determination of the Fiber Rating Fiber ratings were obtained using a hot bar apparatus widi a temperature range from 270 to 415°C. A 2 to 5 gram sample of polymer is thinly and evenly sprinkled on die upper portion of die hot bar using a spatula and is allowed to melt Using a large pair of tweezers, grab a small portion of material from tiie melted pool and slowly draw a fiber at a steady speed The following rating system is used: 0 - Material does not melt or does not draw a fiber 1 - Material draws a short fiber widi poor strength 2 - Material draws an intermediate length fiber with intermediate level of tenacity or material draws a long fiber widi poor strength 3 - Material draws a long fiber widi good strength L - An additional rating of L is added to the rating of 0-3 if a low melt temperature occurs which indicates low molecular weight A - An additional rating of A is added if the melted material is clear which indicates d e material is amorphous in the melt state F . VPS VPS or vapor phase soldering is an assembly technique used to solder components to a printed circuit board This technique involves heating a fluid to its boiling point so tiiat a vapor is produced tiiat is above the melting temperature of standard solder. The printed circuit assembly is placed into die vapor blanket The vapor condenses onto the printed circuit assembly and causes die solder to reflow. VPS Procedure 1. Samples were processed as received and preconditioned for 7-day intervals at 75% Relative H-umidity/Room Temperature. 2. The vapor phase unit used was Model No.912 H manufactured by HTC. 3. The primary vapor was FC-70 Fluorinert, an inert fluorochemical manufactured by 3M Company. The vapor was at a temperature of 428°F (220°C). 4. The secondary vapor was Genesolv D, a trichlortrifluoroediane manufactured by Allied Chemical Company. The vapor was maintained at a temperature of approximately 117°F (47°C). 5. The samples were lowered tiirough tiie secondary vapor into the primary vapor arid allowed to dwell for 4 minutes. 6. During the removal cycle, the samples were allowed to dwell for 30 seconds in the Genesolv D vapor and tiien removed totally. 7. Samples were examined for blistering. If no blistering is evident tiien the samples are considered passed. If blisters are evident the sample has failed G. Miscellaneous The flexural strength of the experimental samples was measured according to the procedure of ASTM D-790-84A; and HDT (DTUL) data were obtained using die mediod as described in ASTM D648. Tensile strength were measured in accord with ASTMD-638. Polymerizations Example P-l This is an example of die syntiiesis of a novel polyester based on terephdialic acid, isophdialic acid p-hydroxybenzoic acid, and hydroquinone in die nominal mole ratio of 0.6:0.4:0.5: 1. The following ingredients were combined in the manner described. Items A through F were charged to a 15-gallon, oil heated vessel equipped with an anchor type stiirer, reflux condenser, after condenser, injection port, and distillate receiver. After purging with nitrogen, the contents were heated widi stirring to 141°C and held under reflux at that temperature for 3 hours. Distillation was tiien started while increasing the temperature over a 4.8 hour period to 285°C. Item G was then injected into die vessel. After an additional 15 minutes the contents of the vessel were transferred to a sigma blade mixer that had been preheated to 320°C. After mixing for 4 hours at this temperature under an atmosphere of nitrogen, die mixer was cooled to near room temperature where the contents were removed as a granular solid The melting point of the polymer (X-ray) was 359°C; its crystallization temperature was 336°C widi a crystallization rate of 2,400. A sample of the polymer was melted extruded and pelletized with a twin screw extruder. The pellets were molded into test specimens. The resulting testing showed superior high temperature performance widi a heat distortion temperature of 250°C and a flexural modulus of 570,000 psi as measured at 250°C by DMA. A molding composition containing 70 weight percent of the above polymer and 30 weight percent of milled glass fiber was prepared by compounding on a twin screw extruder and molded into test specimens. The heat distortion temperature of the obtained composite was 264°C and its flexural modulus (by DMA) was 520,000 psi as measured at 250°C. (ASTM-D-4065) Example P-2 The ingredients were d e same as in Example P-l with die exception that the amount of item F was 14.16 grams, and tiiat item G was not used in the preparation. The equipment was the same as in example 1 and die operating procedure is described . below. After purging with nitrogen, the contents were heated widi stirring to 141°C and held under reflux at that temperature for 3 hours. Distillation was then started with increasing the temperature over a 3.6 hour period to 250°C. The reaction mixture was then stirred for 1 hour at 250-260°C. The contents of the vessel were transferred to a sigma blade mixer which had been preheated to about 250°C. The material was mixed while die temperature was increased to 300°C and mixing was continued for a total of 5 hours at that temperature. A molding composition containing 70 weight percent of the above polymer and 30 weight percent of milled glass fiber was prepared by compounding on a twin screw extruder and molded into test specimens. The heat distortion temperature of the obtained composite was 250°C and its flexural modulus (by DMA) was 420,000 psi as measured at 250°C. (ASTM-D-4065) Example P-3 The ingredients were the same as in Example P-2 with the exception of item F the amount of which was 7.08 grams; also, 16.00 grams of triphenyl phosphite were added prior to transfer of the reaction mixture to die sigma blade mixer. Odierwise, die procedure was the same as in Example P-2. The melting point of the polymer (X-ray) was 359°C; its crystallization temperature was 329°C with a caystallization rate of 2,500. A molding composition containing 70 weight percent of the above polymer and 30 weight percent of milled glass fiber was prepared by compounding on a twin screw extruder and molded into test specimens. The heat distortion temperature of the obtained composite was 268°C and its flexural modulus (by DMA) was 480,000 psi as measured at 250°C. (ASTM-D-4065) S ιrple P-4 This is an example of the syntiiesis of a novel polyester based on terephthalic acid, isophthalic acid, p-hydroxybenzoic acid and hydroquinone in die nominal mole ratio of 0.6:0.4:0.75:1. The following ingredients were combined in the manner described: These ingredients were processed as described in Example P-l. The melting point of the polymer (X-ray) was 353°C; its crystallization temperature was 331°C with a crystallization rate of 2,100. A molding composition containing 70 weight percent of the above polymer and 30 weight percent of milled glass fiber was prepared by compounding on a twin screw extruder and molded into test specimens. The heat distortion temperature of the obtained composite was 240°C. Additional polymers were examined in Tables I - IV. The polymers of the tables were prepared using die mole percentage of monomers delineated in the table and reacting diem in the same manner as P-l to P-4. Cc-mparative Example 1 This example describes die preparation of a polyester in the laboratory. It is to be noted tiiat the preferred metiiod is described in Comparative Example 2 wherein die polymers were produced in scaled-up size in the pilot plant There a continuous metiiod of in situ polymerization was utilized which is more demonstrative of scale-up production and economies. Unfortunately in scale-up production, physical and mechanical characteristics can be varied as compared to laboratory production. The polyester had the molar composition: terephthalic arid isophtiialic acid/p-hydroxybenzoic acid hydroquinone 0.5/0.5/1.0/1.0 (see Cottis et al., U.S. Patent No. 3,637,595; example no. 10, noted as designation"x" on Figure 1). The properties of this polymer do not meet die requirements of the polyesters of the instant invention. A 5 liter resin flask equipped widi a stirrer, condenser system designed botii for reflux and distillation, and a heating mantle was charged widi the following: 1,092.5 g of p-hydroxybenzoic acid; 657.1 g of terephthalic acid; 657.1 g of isophthalic acid; 871.0 g of hydroquinone; and 2,786.0 g of acetic anhydride. The above mixture was heated at reflux for a period of 3 hours; vigorous stirring was maintained tiiroughout die reaction. At die end of the reflux period collec¬ tion of distillate was started The reaction mass was then heated at a rate of about 30°C per hour to 311°C at which point 98.2 percent of the theoretical distillate was collected The molten material was poured into an aluminum pan and allowed to cool to room temperature. The solid was pulverized and ground to pass a 2 -millimeter screen. The powder was placed in a drum and was heated in a nitrogen stream, while rotating, to a temperature of 330°C; and held at tiiat temperature for two hours. The product was removed from the drum after cooling. The melting point of the polymer (X-ray) was 325°C; its crystallization temperature (onset of crystallization) and crystallization rate (both measured via X-ray techniques) were 299°C and 2,242, respectively. A portion of the product was pelletized and injection molded into test specimens. The neat polymer had a HDT of 226°C, a flex strength of 16,000, a flex modulus of 1.85 X 10 6 and a blister rating of 16. Another portion of die product was compounded with milled glass fiber to prepare a pelletized material containing 30 percent glass. Injection molding yielded test specimens which were very brittle. Therefore, to run HDT analyses, 1/8" Flex Bars were used The HDT was 233°C. Comparative Example 2 This example describes die preparation of a polyester having the mole ratio of 0.5/0.5/1.0/1.015. The following ingredients were combined in die manner described: Items A through F were charged to a 15-gallon, oil heated vessel equipped widi an anchor type stirrer, reflux condenser, after condenser, injection port, and distillate receiver. After purging widi nitrogen, the contents were heated with stirring to 141°C and held under reflux at that temperature for 3 hours. Distillation was then started while increasing die temperature 30°C/hour to 273°C. Item G was then injected into the vessel. After the reactor reached 277°C the contents of the vessel were transferred to a sigma blade mixer that had been preheated to 285°C. After mixing for 5 hours at this temperature under an atmosphere of nitrogen, the mixer was cooled to near room temperature where the contents were removed as a granular solid The melting point of the polymer (X-ray) was 349°C; its crystallization temperature was 331°C with a crystallization rate of 1667. A sample of me polymer was blended widi glass, melted extruded, and pelletized with a twin screw extruder. The pellets were molded into test specimens. The resulting testing showed lower temperature performance with a 264 psi heat distortion temperature of only 214°C. Preparative Exajppfcs, Example B-l Preparation of polyester having the following molar composition: 0.25 moles isophthalic acid 0.75 moles terephthalic acid 3.0 moles p-hydroxybenzoic acid 1.0 mole 4,4'-biphenol. A mixture of: 184 lbs of terephthalic acid; 61 lbs of isophthalic acid 612 lbs of low ash p-hydroxybenzoic acid; 275 lbs of 4,4'-biρhenol; 868 lbs of acetic anhydride; and 40.1 grams (88.5 ppm) of magnesium acetate tetrahydrate was placed in a 325 gallon rector and heated with stiiring until distillation started The rector was held at tiiis temperature for 3 hours. Distillation was started and the temperature increased until 400 pounds of distillate has been collected The contents were pressured into a 200 gallon reactor and die temperature was increased at a rate of 30°C per hour until die contents reached 313°C. Then the contents were poured into a mechanical mixer and mixed at 290 to 300°C for 5 hours. Six batches of polymers were made with compressive flows at 330°C from 55 to 74, and polymer had very good color. Example B-2 Preparation of polyester having the following molar composition: 1 mole terephthalic acid/3.7 moles p-hydroxybenzoic acid 1 mole 4,4-biphenol. The following ingredients were combined in die manner described: Items A through E were charged into die rector and heated to 307°C over a period of 10 hours with distillation of acetic acid Item F was then added and heating was continued for 6 minutes to a melt temperature of 310°C. The contents of the vessel were transferred to a sigma blade mixer that had been preheated to 335°C. The temperature was raised to 350°C and mixing was continued at 350°C for 9.5 hours under an atmosphere of nitrogen. The mixer was cooled to near room temperature where the contents were removed as a granular solid having a compressive flow of 52. Example B-3 The naphthalene-based polyester used in die instant blends was Vectra® A950, produced by die Hoechst-Celanese Corporation and composed of about 73 mole percent 4-oxybenzoyl moieties (XX) and 27 mole percent of 6-oxy-2-naphthoyl moieties (XDC): Preparation of Polyester Blends General Polyesters prepared as described in preparative examples B-l and B-2 were formulated into a 30 percent glass filled composition, compounded and pelletized The blends contained as a percentage of die resins phase, eitiier 0, 10, 21 or 40 weight percent of polymer (B). The formulations were compounded and pelletized on a 25 mm diameter Berstorff twin screw extruder. The barrel profile temperature for compounding was: Barrel zone 1 = 320 to 325°C Barrel zone 2 • 355 to 362°C Barrel zone 3 = : 355 to 376°C Barrel zone 4 ■ ■ = 365 to 395°C Barrel zone 5 * ■ 380 to400°C Barrel zone 6 - ■ 370 to 380°C Barrel zone 7 * - 360 to 370°C Die = 355 to 380°C The screw rpm was 170 to 175; die output was 12 to 15 pounds per hour. The above materials were molded on a 75 ton, 3 ounce Newbury injection molding machine. The barrel profile was: Rear zone about 377°C Front zone about 382°C Nozzle about 388°C The mold temperature was set at 121°C and die injection pressure was in the range of 1,000 to 1,360 psi. The molding machine screw rpm was about 330. The formulations of Table VH were compounded and pelletized on a 25 mm diameter Berstorff twin screw extruder. The barrel profile temperature for compounding was: Barrel zone 1 = 293 to 320°C Barrel zone 2 = 360 to 376°C Barrel zone 3 = 375 to 400°C Barrel zone 4 = 395 to 405°C Barrel zone 5 = 390 to 400°C Barrel zone 6 = 370 to 385°C Barrel zone 7 = 375 to 387°C Die = 370 to 387°C The screw rpm was 175 with an output of about 10 to 13 pounds per hour. The above materials were molded on a 75 ton, 3 ounce Newbury injection molding machine having the following barrel temperature profile: Rear zone about 377°C Front zone about 382°C Nozzle about 388°C The mold temperature was set at 120°C for composition no.7 and at 66°C for all otiier compositions. The injection pressure was 1,000 psi and die molding machine screw rpm was about 330. Blends of Table XI (test nos. 21-32): Barrel zone 1 = 150 to 176°C Barrel zone 2 = 270 to 345°C Barrel zone 3 = 285 to 365°C Barrel zone 4 = 275 to 370°C Barrel zone 5 = 270 to 370°C Barrel zone 6 = 280 to 365°C Barrel zone 7 = 275 to 360°C Die = 270 to 355°C Blends of Table XI (test nos. 33-40): Barrel zone 1 = 185 to 301°C Barrel zone 2 = 370 to 385°C Barrel zone 3 = 385 to 400°C Barrel zone 4 = 390 to 400°C Barrel zone 5 = 385 to 390°C Barrel zone 6 = 375 to 380°C Barrel zone 7 = 370 to 376°C Die = 370 to 374°C Blends of Table XI (test nos. 41-44): Barrel zone 1 = 320°C Barrel zone 2 = 355 to 360°C Barrel zone 3 - 370 to 375°C Barrel zone 4 = 390 to 395°C Barrel zone 5 = 390°C Barrel zone 6 = 370°C Barrel zone 7 = 370 to 376°C Die = 350 to 375°C The screw rpm was in the range of 120 to 175 for all the blends; die output was about 10 to 13 pounds per hour. The above materials were molded on a 75 ton 3 ounce Newbury injection molding machine having the following barrel temperature profile: Blends of Table XI (test nos. 21-32): Rear zone = 376 to 337°C Front zone = 271 to 337°C Nozzle = 282 to 348°C Blends of Table XI (test nos. 33-40): Rear zone = 337 to 388°C Front zone = 332 to 382°C Nozzle = 343 to 393°C Blends of Table XI (test nos. 41-44): Rear zone = 299 to 371°C Front zone = 288 to 377°C Nozzle = 299 to 382°C The mold temperature was set at 66°C for compositions 21 to 32 and 36; it was 99°C for no.44 and 120°C in all other examples. The injection pressure was: 1,000 psi in examples: Table XI, 21,27,28,29,30,31,32,35,36,37 and 38; 1,400 psi in all otiier blend examples. The molding machine screw rpm was set at 330. Examinations of tiie table shows that the blends can generally be fabricated at lower temperatures than the corresponding controls; dierefore there is less chance of decomposition and concurrendy less blistering. Summary of Tables Tables I - V: Properties of Neat and Glass-Filled Polymers Tables I - HI Table I lists some polyesters whose properties meet the specifications of the polymers of tiie instant invention as far as melting point crystallization temperature and crystallization rate are concerned Table H lists other polyesters which are borderline resins, i.e., those where (a) at least one of the tiiree basic properties (melting point crystallization temperature and crystallization rate — all as measured by X-ray techniques) is witiiin the required range, die otiier two properties being outside of die range, but very close to it; or (b) where all tiiree properties are in the required range, but the HDT does not satisfy the requirements and/or the material is not moldable. Table HI lists still otiier polymers whose properties are outside of die specifications of this invention. The data clearly show that well defined ratios of monomers are critical if one wants to achieve polyesters having the outstanding characteristics as described in this application. Table IV: Polymers Table IV shows other polymers derived from die monomers and %'s shown and the mechanical properties of these polymers. It depicts tiiat die A region (which corresponds to the triangular diagram Figure 1) has a higher HDT tiian die X region (Cottis U.S. Patent No. 3,637,595) and also an improved blister rating, tensile strength, and % elongation. Table V: Polymer Fiber Rating Table V depicts polymers derived from die monomers and %'s as listed It shows an improved fiber rating of the A region over the other non- designated regions of die phase diagram. It is noteworthy that region C (which is the subject of another application filed concurrendy herewith) has even more favorable fiber ratings. Tables VH - XHI: Blends of Polyesters (a. and (b . and dieir properties Table VH discloses blends of tiiree different polyesters. The properties of these blends are shown in Tables VHI - X. Table XI depicts otiier blends and Table XH depicts die properties of blends of Table XL The blends have lower injection molding temperatures than the base polymer showing they can be fabricated at lower temperatures. The data clearly show that the blends display improved mechanical properties-see, for example, flexural strengtiis and blister ratings of Table VHI tests 4-6. The high HDTs of the novel blends are noteworthy; tiiey are intermediate between those of die constituent polymers of the blends. This in turn could be interpreted as a result of compatibility for the instant highly crystalline polyesters. DMA modulus data show tiiat stiffness is maintained up to quite high temperatures, making die present materials useful at elevated temperatures. In conclusion, therefore, the blends of this invention possess a combination of toughness, surface, and high temperature properties that could not be anticipated beforehand. (a) The polymers were prepared via methods similar to that used in comparative Example 2 In all of the examples, p is one. (b) Counts per minute. TABLE H PROPERTIES Melting Cryst. Example Composition ( c Point Temp. Crys No. (a) CC) CO Rate (e) Remarks W) 14 0.30 0.70 7.00 393 359 3100 15 0.20 0.80 7.00 393 359 3100 16 0.10 0.90 7.00 370 343 2600 17 0.00 1.00 7.00 353 323 2100 Poor processibility HDT=219 * C 18 0.40 0.60 5.00 389 352 2800 (b) 0.30 0.70 5.00 373 341 2700 20 ' 0.50 0.50 1.50 343 313 2500 Neat polymer fused at 450 * C with decomposition (smoke) when compounding was attempted 21 (b) 387 347 2810 22 ' 361 335 2700 Same as Example 20 23 334 300 1794 24 389 341 3200 25 362 291 2000 26 333 311 1510 27 381 344 3860 28 400 351 2500 29 334 294 2110 30 366 304 820 31 387 309 430 (a) Prepared in a manner similar to that of Comparative Example 1 , except where otherwise indicated. (b) Prepared in a manner similar to that of Example P- 1. (c) In all examples p is equal to one. (d) HDT measured on 30 percent by weight milled glass filled compositions. (e) Counts per minute. 0<7 Example Composition^) No. ( a ) q r s Remarks ( d) 84 0.20 0.80 0.75 85 0.00 1.00 0.75 86 0.462 0.538 0.538 87 1.00 0.00 0.50 88 0.30 0.70 0.50 89 0.00 1.00 0.50 90 0.80 0.20 0.25 91 0.70 0.30 0.25 92 0.50 0.50 0.25 93 0.30 0.70 0.25 94 0.00 1.00 0.25 95 0.61 0.39 0.22 96 0.41 0.59 0.18 97 0.70 0.30 0.10 98 0.50 0.50 0.10 99 0.30 0.70 0.10 100 0.80 0.20 0.00 101 0.70 0.30 0.00 102 0.10 0.90 0.00 (a) Polymers were prepared in a manner similar to that of Comparative Example 1, except where noted. (b) Prepared as described in Example P-l . (c) In all Examples p is equal to 1. (d) Measured on a 37 weight percent talc filled composition. (e) Measured on a 30 weight percent milled glass filled composition. (f) Counts per minute. TABLEVH BLENDSOFPOLYESTERS(a)and(b) ( i ) Heniy and Frick (now Fibeπec) untreated 3016 (1/16") milled glass fiber. ( 2 ) Based on OC497 glass roving (Cwens-Corning). TABLE Vm 1 Blister rating: 0 = best; 16 = worst. 2 Value at 30°C B E I ( ' ) Blister rating: 0 = best; 16 = worst. IΔ__I__L__ ROOM TEMPERATURE IZOD DATA OF BLENDS OF POLYESTERS OF TABLE VH T LE X BLENDS OF POLYESTERS () Henry and Frick, 1/16" -milled glass fiber. TABLE XII PROPERTIES OF BLENDS OF TABLE XI

Claims: We claim: 1. A high modulus, high strength melt-processible copolyester consisting essentially of recurring units (I).(π). (HI) and (IV): wherein said polyester has a melting point in the range of from about 340 to 400°C, a crystallization temperature of from about 300 to 340°C, and a crystallization rate of at least 1,000 counts/minute. 2. The polyester of claim 1 having a heat distortion temperature of about 240 to about 280°C under a load of 264 psi when filled with 30 weight percent glass fiber. 3. The polyester of claim 1 wherein the sum of die number of units of (II) and (HI) is approximately equal to the number of unit (I); and unit (IV) ranges from about 0.25 to 0.55 mole per each mole of unit (I). 4. A high modulus, high strength melt-processible polyester consisting essentially of recurring units (I), (II), (ID), and (IV): having a melting point in the range of from about 340 to 400°C, a crystallization temperature of 300 to 340°C, a crystallization rate of at least 1,000 counts/minute; and when filled with 30 percent by weight glass fibers, has a HDT of at least 240°C under a load of 264 psi. 5. The polyester of claim 4 wherein the percentage of units (I), (II), (Dl) and (TV) falls within area A circumscribed on die triangular phase diagram Figure 1. 6. The polyester of claim 4 wherein die sum of die number of units of (II) and (HI) is approximately equal to (I); and unit (IV) ranges from about 0.25 to 0.55 moles per each mole of unit I. 7. The me od of preparing the copolyester of claim 1 which comprises reacting hydroquinone, isophdialic acid, terephthalic acid and hydroxybenzoic acid in a solvent comprising an anhydride of a lower monocarboxylic acid. 8. The process of claim 7 wherein said reaction is carried out in the presence of a salt selected from the group consisting of an alkaline earth metal salt and an alkali metal salt 9. The metiiod of preparing the polyester of claim 4 which comprises reacting hydroquinone, isophthalic acid, terephthalic acid and hydroxybenzoic acid in a solvent comprising an anhydride of a lower monocarboxylic acid. 10. A high modulus, high strength melt-processible polyester consisting essentially of recurring units (I), (II), (HI) and (IV) falling -within the area A on the triangular phase diagram Figure 1. 11. Fully aromatic polyester blends comprising 1 to 19 parts by weight of a polyester polymer (a) comprising recurring moieties of dihydroxyarylene comprising hydroquinone, a nonvicinal benzene dicarboxylate and p-oxybenzoate to 1 part by weight of a polyester polymer (b) comprising recurring moieties of diphenol, nonvicinal benzene dicarboxylate and p-oxybenzoate; said polyester polymer (a) having a melting point in the range of about 340° C to about 400° C a crystallization temperature of from about 300 to about 340° C, and a crystallization rate of at least 1,000 countsAninute and heat distortion temperature of at least 240 * C under a load of 264 psi 12. A melt-processible composition comprising from about 1 to 19 parts by weight of the polyester (a) of claim 11 per 1 part by weight of a polyester comprising recurring units (V), (VI), (VII) and (Vm): where a is approximately equal to b + c; b is in the range of from about 0.5 to about 0.8; c is in the range of from about 0.50 to about 0.2; d is in the range of from about 1 to about 7, preferably from about 2 to about 4 moles per each mole of unit a; and where the molecular weight of said polyesters is from about 2,000 to about 200,000. 13. A melt-processible composition comprising from about 1 to 19 parts by weight of the polyester polymer (a) of claim 4 per 1 part by weight of the polyester comprising recurring units (V), (VI), (VII) and (Vm): where a is approximately equal to b + c; b is in the range of from about 0.5 to about 0.8 ; c is in die range of from about 0.5 to about 0.2; d is in the range of from about 1 to about 7, preferably from about 2 to about 4 moles per each mole of unit a; and where the molecular weight of said polyesters is from about 2,000 to about 200,000. 14. The polyester blend of claim 11 wherein the ratio of units (a) to (b) is approximately 1.5 to 9 parts by weight of (a) to 1 part by weight of (b). 15. The polyester blend of claim 11 wherein (a) and (b) comprise the following recurring units: (a) (b) 16. The polyester blend of claim 15 wherein die sum of the number of units (IT) and (ID) is approximately equal to the number of units (I); and units (IV) ranges from about 0.18 to about 9.0 moles per each mole of unit (I). 17. The polyester blend of claim 16 wherein the ratio of units (a) to (b) is approximately 1.5 to 9 parts by weight of (a) to 1 part by weight of (b). 18. The polyester blend of claim 15 wherein the sum of me number of units (VI) and (VII) is approximately equal to the number of units (V); and units (Vm) ranges from about 1 to about 7 moles per each mole of unit (V). 19. The polyester blend of claim 11 wherein the mole ratios of monomer units of polyester (a) fall within the area cit-iiπiscribed in area A in die triangular phase diagram, Figure 1. 20. Fully aromatic polyester blends comprising 1 to 19 parts by weight of a polyester (a) comprising die following recurring moieties: wherein d e sum of the number of units (TJ) and (ID) is approximately equal to the number of unit (I); and unit (IV) ranges from about 0.18 to about 9.0 moles per each mole of unit (I); and which has a melting point in the range of from about 340 to about 400° C, a crystallization temperature of from about 300 to about 340° C, and a crystallization rate of at least 1,000 counts minute; to one part by weight of a polyester (b) comprising recurring moieties: (V ) ( VI ) wherein the sum of the number of units (VI) and (VII) is approximately equal to the number of unit (V); and unit (VHI) ranges from about 1 to about 7 moles per each mole of unit (V); and said blend, when filled widi 30 weight percent glass fibers has an HDT of at least 240° C when measured under a load of 264 psi. 21. Blends comprising from about 1 to about 19 parts by weight of a first polyester polymer (a) comprising units (I), (IT), (ffl) and (IV): where (I) is approximately equal to (H) + (ID); q is in the range of from about 0.05 to about 0.76; r is in die range of from about 0-95 to about 0.24; s is in the range of from about 0.10 to about 9.0 moles per each mole of unit (I); per one part by weight of a second polyester polymer (b) comprising units (DC), (X) and (XI): wherein e is approximately equal to f; e is 1; and g is in the range of from about 1.5 to about 5 moles per each mole of unit (DC); die molecular weights of said polyesters being in die range of from about 2,000 to about 200,000. 22. The blend of claim 21 wherein die mole ratios of monomer units of polyester (a) fall within the areas circumscribed in area A of the triangular phase diagram, Figure 1. 23. Blends consisting essentially of about 1 to about 95 parts by weight of a first polyester (a) comprising units (I), (H), (in) and (TV): where (I) is approximately equal to (H) + (TH); q is in the range of from about 0.05 to about 0.76; r is in the range of from about 0.95 to about 0.24; s is in the range of from about 0.10 to about 9.0 moles per each mole of unit (I); per one part by weight of a second polyester (b) comprising units (DC), (X) and (XI); wherein e is approximately equal to f; e is 1 mole; g is in the range of from about 1.5 moles to about 5 moles per each mole of e; die molecular weights of said polyesters being in die range of from about 2,000 to about 200,000. 24. Blends as defined in claim 21 which have heat distortion temperatures of at least about 200 * C when measured under a load of 264 psi, and which yield fabricated articles having good surface characteristics. 25. Blends as defined in claim 21 wherein the component first and second polyesters are each prepared by reacting die aromatic dicarboxylic acids(s), the p- hydroxy benzoic acid, and the aromatic diol with an anhydride of a lower monocarboxylic acid to yield a prepolymer, followed by a solid state advancement of said prepolymer to the required final molecular weight 26. Blends as defined in claim 21 wherein s is about 0.25 mole to about 0.55 mole per each mole of unit (I); q is about 0.50 mole to about 0.70 mole; and r is about 0.30 mole to about 0.50 mole. 27. Blends as defined in claim 21 wherein s is about 0.55 mole to about 9.0 moles per each mole of unit (I); q is about 0.05 to about 0.80 mole; and r is about 0.95 mole to about 0.20 mole. 28. Blends as defined in claim 21 wherein when e is one mole g is in the range of from about 2 to about 4 moles. 29. Blends as defined in claim 21 wherein when unit (I) is one mole s is about 0.25 mole to about 0.55 mole per each mole of unit (I); q is about 0.50 mole to about 0.70 mole; r is about 0.30 mole to about 0.50 mole; e is 1 mole; and g is in die range of from about 2 to about 4 moles. 30. Blends as defined in claim 21 wherein when unit (I) is 1 mole s is about 0.55 mole to about 9.0 mole per each mole of unit (I); q is about 0.050 to about 0.80 mole; r is about 0.95 mole to about 0.20 mole; e is one mole; and g is in the range of from about 2 to about 4 moles. 31. Fully aromatic polyester blends comprising a first polyester comprising units derived from a dihydroxyarylene consisting essentially of dihydroxybenzene and dihydroxybiphenyl; nonvicinal benzene dicarboxylic acids and p-hydroxybenzoic acid; and a second polyester comprising units derived from at least one naphthalene-based monomer, a nonvicinal benzene dicarboxylic acid and p-hydroxybenzoic acid. 32. Blends comprising from about 1 to about 19 parts by weight of a first polyester polymer comprising units (DC), (X), (XI), (XH): where n is 1 or 1 and 2; the number of moles of units (DC) is approximately equal to the number of moles of units (X) + (XI); to one part by weight of a second polyester polymer comprising at least one unit: - X1 - AT - X2 - (xm) wherein Ar comprises at least one member selected from the group consisting of: Xl and X2 are independendy selected from die group consisting of oxy and carbonyl. 33. The blend of claim 32 wherein die Ar group of the second polyester also comprises a divalent aromatic radical comprising at least one phenylene group. 34. Blends consisting essentially of from about 1 to 19 parts by weight of a first polyester comprising units (IX), (X), (XI), (XH): where n is 1 or 1 and 2; die number of moles of units (EX) is approximately equal to the number of mole of units (X) and (XI); to one part by weight of a second polyester comprising at least one unit: - Xi - Aτ - X2 - wherein Ar comprises at least one member selected from the group consisting of: Xl and X2 are independentiy selected from the group consisting of oxy and carbonyl. 35. The blend of claim 34 wherein die Ar group of the second polyester also comprises a divalent aromatic radical comprising at least one phenylene group. 36. Blends as defined in claim 32 comprising from about 1 to 19 parts by weight of a first polyester comprising units (DC), (X), (XI), (XII): where n is 1; (DC) is approximately equal to (X) + (XI); (X) is in die range of from about 0.05 to about 0.76; (XI) is in the range of from about 0.95 to about 0.24; (XII) is in the range of from about 0.10 to about 9.0 moles per each mole of unit (DC); to one part by weight of a second polyester comprising at least one unit - Xι -Aτ - X2- cxno wherein Ar, Xi and X2 are as previously defined in claims 32 and 33. 37. The blend of claim 36 wherein the Ar group of the second polyester also comprises a divalent aromatic radical comprising at least one phenylene group. 38. Blends as defined in claim 32 consisting essentially of from about 5 to about 95 parts by weight of a first polyester comprising units (IX), (X), (XI), (XII): where n is 1; (DC) is approximately equal to (X) + (XI); (X) is in the range of from about 0.05 to about 0.76; (XI) is in the range of from about 0.95 to about 0.24; (XII) is ire die range of from about 0.10 to about 9.0 moles per each mole of unit (IX); and from a&out 95 to about 5 parts by weight of a second polyester comprising at least one unit: - Xι - Aτ - X2 - (XID) wherein Ar, Xi and X2 are as previously defined in claims 32 and33. 39. The blend of claim 38 wherein the Ar group of the second polyester also comprises a divalent aromatic radical comprising at least one phenylene group. 40. Blends as defined in claim 32 comprising from about 5 to about 95 parts by weight of a first polyester comprising units (DCb), (DCc), (Xa), (XIa), (XHa): wherein e' + e" is approximately equal to f + g; the ratio of e 1 to e" is from about 3: 1 to about 99: 1 ; the ratio of f to g is from about 0.42: 1 to about 10: 1 ; and the ratio of h to f + g is in the range of from about 0.15: 1 to about 8.0: 1 moles per one mole of monomers corresponding to the sum of units (DCb) + (DCc); and from about 95 to about 5 parts by weight of a second polyester comprising at least one unit: - Xi - Aτ - X2 - CXΠD wherein Ar, Xi and X2 are as previously defined in claims 32 and 33. 41. The blend of claim 40 wherein die Ar group of the second polyester also comprises a divalent aromatic radical comprising at least one phenylene group. 42. Blends as defined in claim 32 consisting essentially of from about 5 to about 95 parts by weight of a first polyester comprising units (DCb), (DCc), (Xa), (XIa), (XHa): wherein e'+e" is approximately equal to f+g; the ratio of e' to e" is from about 3:1 to about 99:1; die ratio of f to g is from about 0.42:1 to about 10:1; and die ratio of h to f + g is in die range of from about 0.15: 1 to about 8.0: 1 moles and from about 95 to about 5 parts by weight of a second polyester comprising at least one unit: - Xi - Aτ - X2 - (xm\ wherein Ar, Xi and X2 are as previously defined in claims 32 and33. 43. The blend of claim 42 wherein the Ar group of the second polyester also comprises a divalent aromatic radical comprising at least one phenylene group. 44. Blends as defined in claim 32 having heat distortion -temperatures of at least 175° C when measured under a load of 264 psi 45. Blends as defined in claim 32 having heat distortion temperatures of at least 200° C when measured under a load of 264 psi. 46. Blends as defined in claim 32 wherein die first polyester is comprised of units (DC), (X), (XI), (XII): where n is 1; (DC) is approximately equal to (X) + (XT); (X) is from about 0.50 to about 0.70; (XI) is from about 0.30 to about 0.50; and (XII) is from about 0.25 to about 0.55 mole per each mole of unit (DC). 47. Blends as defined in claim 32 wherein die first polyester is comprised of units (DC), (X), (XI), (XII): . where n is 1; (DC) is approximately equal to (X) + (XI); (X) is from about 0.05 to about 0.80; (XI) is from about 0.20 to about 0.95; and (XD) is from about 0.55 to about 9.0 moles per each mole of unit (DC). 48. The polyester blend of claim 32 wherein the mole ratios of monomer units of the first polyester fall within the area circumscribed in area A in die triangular phase diagram, Figure 1. 49. Blends as defined in claim 32 wherein the first polyester is comprised of units (DCb), (DCc), (Xa), (XIa), (XHa): wherein e' + e" is approximately equal to f + g; me ratio of e' to e" is from about 3.0: 1 to about 99:1; the ratio of f to g is from about 0.42:1 to about 10:1; and the ratio of h to f + g is from about 0.15: lto about 8.0: 1 moles. 50. Blends as defined in claim 32 wherein die second polyester consists essentially of the recurring units (XDC) arid (XX) which may be substituted by one or more Ct to C 4 alkyl groups, to C 4 alkoxy groups or halogen atoms; and wherein said second polyester comprises from about 10 to about 90 mole percent of units (XDC) and from about 90 to about 10 mole percent of units (XX). 51. Blends as defined in claim 32 wherein die second polyester consists essentially of the recurring units (XX), (XXI), (XXII): and wherein said second polyester comprises from about 40 to about 60 mole percent of units (XX); from about 20 to about 30 mole percent of units (XXI); and from about 20 to about 30 mole percent of units (XXD). 52. Blends as described in claim 51 wherein the second polyester consist- essentially of the recurring units (XDC), (XXHI), (XXTV): which may be substituted by one or more Cl to C4 alkyl groups, Cl to C4 alkoxy groups, halogen atoms, orphenyl groups; wherein the group Ari is as previously defined in claims 32 and 33; and wherein said second polyester comprises from about 10 to about 90 mole percent of units (XDC); from about 5 to about 45 mole percent of units (XXm); and from about 5 to about 45 mole percent of units (XXIV). 53. Molding compounds comprising die polyester of claim 1 and from about 1 to about 50 percent by weight, based upon the total weight of the molding compound, of at least one material selected from the group consisting essentially of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wood cellulose fibers, calcium silicate, silica, clays, talc, mica, carton black, titanium dioxide, wollastonite, polytetrafluoroethylene, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, and glass beads. 54. Molding compounds comprising the polyester of claim 4 and from about 1 to about 50 percent by weight, based upon the total weight of the molding compound, of at least one material selected from the group consisting essentially of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, alurαinum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wood cellulose fibers, calcium silicate, silica, clays, talc, mica, carbon black, titanium dioxide, wollastonite, polytetrafluoroethylene, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, and glass beads. 55. Molding compounds comprising the polyester of claim 7 and from about 1 to about 50 percent by weight based upon die total weight of the molding compound, of at least one material selected from the group consisting essentially of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wood cellulose fibers, calcium silicate, silica, clays, talc, mica, carbon black, titanium dioxide, wollastonite, polytetrafluoroethylene, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, and glass beads. 56. Molding compounds comprising the polyester of claim 10 and from about 1 to about 50 percent by weight, based upon the total weight of the molding compound, of at least one material selected from the group consisting essentially of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wood cellulose fibers, calcium silicate, silica, clays, talc, mica, carbon black, titanium dioxide, wollastonite, polytetrafluoroethylene, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, and glass beads. 57. Molding compounds comprising the blends of claim 11 and from about 1 to about 50 percent by weight based upon the total weight of the molding compound, of at least one material selected from the group consisting essentially of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, syndietic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wood cellulose fibers, calcium silicate, silica, clays, talc, mica, carbon black, titanium dioxide, wollastonite, polytetrafluoroethylene, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, and glass beads. 58. Molding compounds comprising the blends of claim 15 and from about 1 to about 50 percent by weight based upon the total weight of the molding compound, of at least one material selected from the group consisting essentially of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wood cellulose fibers, calcium silicate, silica, clays, talc, mica, carbon black, titanium dioxide, wollastonite, polytetrafluoroethylene, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, and glass beads. 59. Molding compounds comprising the blends of claim 21 and from about 1 to about 50 percent by weight, based upon the total weight of the molding compound, of at least one material selected from the group consisting essentially of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, syndietic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wood cellulose fibers, calcium silicate, silica, clays, talc, mica, carbon black, titanium dioxide, wollastonite, polytetrafluoroethylene, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, and glass beads. 60. Molding compounds comprising the blends of claim 31 and from about 1 to about 50 percent by weight, based upon the total weight of the molding compound, of at least one material selected from the group consisting essentially of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wood cellulose fibers, calcium silicate, silica, clays, talc, mica, carbon black, titanium dioxide, wollastonite, polytetrafluoroethylene, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, and glass beads. 61. Molding compounds comprising die blends of claim 32 and from about 1 to about 50 percent by weight based upon die total weight of the molding compound, of at least one material selected from the group consisting essentially of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wood cellulose fibers, calcium silicate, silica, clays, talc, mica, carbon black, titanium dioxide, wollastonite, polytetrafluoroethylene, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, and glass beads. 62. An ovenware article comprising one or more of the compound of claim 53. 63. An ovenware article comprising one or more of the compounds of claim 54. 64. An ovenware article comprising one or more of the compounds of claim 55. 65. An ovenware article comprising one or more of the compounds of claim 56. An ovenware article comprising one or more of the compounds of An ovenware article comprising one or more of the compounds of An ovenware article comprising one or more of the compounds of An ovenware article comprising one or more of the compounds of An ovenware article comprising one or more of the compounds of A molded article of permanent ovenware, comprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and (C) about 0-20% titanium dioxide, such tiiat the ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising the polyester of claim 1. 72. A molded article of permanent ovenware, comprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and (Q about 0-20% titanium dioxide, such that the ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising die polyester of claim 4. 73. A molded article of permanent ovenware, comprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and (C) about 0-20% titanium dioxide, such tiiat the ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising die polyester of claim 7. 74. A molded article of permanent ovenware, comprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and (C) about 0-20% titanium dioxide, such that the ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising the polyester of claim 10. 75. A molded article of permanent ovenware, comprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and (C) about 0-20% titanium dioxide, such tiiat die ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising the blends of claim 11. 76. A molded article of permanent ovenware, comprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and (C) about 0-20% titanium dioxide, such mat the ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising the blend of claim 15. 77. A molded article of peπnanent ovenware, comprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and (C) about 0-20% titanium dioxide, such tiiat the ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising die blend of claim 15. 78. A molded article of permanent ovenware, comprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and (C) about 0-20% titanium dioxide, such tiiat the ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising the blends of claim 21. 79. A molded article of permanent ovenware, comprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and ( about 0-20% titanium dioxide, such tiiat the ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising die blend of claim 22. 80. A molded article of permanent ovenware, comprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and (C) about 0-20% titanium dioxide, such that the ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising the blends of claim 31. 81. A molded article of permanent ovenware, cc αprising: (A) 35-85% by weight of a wholly aromatic polyester resin; (B) about 15-65% by weight of a talc ccmtaining a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950°C and 2% by weight at 800°C and having an iron content of not more than about 1.0% by weight analyzed as iron oxide; and (C) about 0-20% titanium dioxide, such that the ovenware is not blistered or bubbled or cracked during molding or oven use; said aromatic polyester resin (A) comprising the blends of claim 32.

Inventors: CLEARY JAMES WILLIAM, FRAYER PAUL DAVID, HUSPENI PAUL JOSEPH, LAYTON RICHARD, MATZNER MARCUS, CLEARY, JAMES, WILLIAM, FRAYER, PAUL, DAVID, HUSPENI, PAUL, JOSEPH, LAYTON, RICHARD, MATZNER, MARCUS
Applicants: AMOCO CORP, AMOCO CORPORATION
Application year: 1989
Main classification: C08L67
IPC codes: A47J36, C08G63, C08K3, C08K7, C08L67