Superconductive Strip containing internal stressabsorber

Abstract: A superconductor according to the present invention contains an internal stress absorbing substance of a copper oxide and/or a barium oxide distributed over the superconductive oxide, so that the superconductor is free from cracks due to thermal stresses produced in a heat treatment.

Description: This invention relates to a superconductor and, more particularly, to the structure of a superconductive strip which is less liable to have internal stresses after a heat treatment. Various formation processes such as sputtering techniques or physical evaporation techniques are used for forming superconductive strips on substrates. However, the deposited superconductive material is usually covered with a certain surface film which tends to suppress the superconductivity. The superconductive strip is then subjected to a heat treatment in an oxidation ambient between about 800 degrees and about 950 degrees in centigrade for about an hour, and the heat treatment aims at refining the undesirable surface film. However, a problem is encountered in the prior art refining technique in that cracks tend to take place in the superconductive strips due to thermal stress. This is because of the fact that the superconductive strips are usually different in thermal expansion coefficient from the substrate. The cracks deteriorate the production yield of the superconductive strips. A superconductor according to the preambles of claims 1 and 2 is disclosed in "Progress in high temperature superconductivity", volume 8, 20th-24th February 1988, "World Congress on Superconductivity", pages 460-475, Houston US; C. PERSDA et al.: "Consolidation of powders of the oxide superconductor YBa2CU30x by high energy - high rate processing". In this superconductor among others copper is used as an internal stress absorbing substance. However, it is reported in this paper that upon annealing the copper regions transform to copper oxides and that these oxides appear to inhibit a transition to complete superconductivity. It is therefore an object of the invention to provide a superconductive material which withstands the internal stress produced in the heat treatement for refining the surface film. It is an other object of the invention to provide a superconductive material which is elastic enough to absorb the thermal stress. These objects are achieved by a superconductive strip as defined in claims 1 and 2, respectively. The internal stress absorbing substance may range from about 0.12 % by volume to about 7.9 % by volume. In one implementation, the internal stress absorbing substance is selected from the group consisting of a copper oxide and a barium oxide, however, both of the copper oxide and the barium oxide constitute the internal stress absorbing substance in another implementation. Description is made for a process of forming superconductive strips on substrates. The process starts with preparation of powders of various superconductive oxides, a powder of a copper oxide, and a powder of a barium oxide. Each of the superconductive oxides is represented by the molecular formula shown in Table 1, and the powder of each superconductive oxide has an average diameter of about 5 µm. The copper oxide and the barium oxide serve as internal stress absorbing substance, and, for this reason, each of these powders is hereinunder referred to as "absorbing powder". The powder of each superconductive oxide and each or both of the absorbing powders are mixed in a proportion indicated in Table 1 to produced a mixed powder. Each mixed powder is shaped into a disk configuration, and, then, sintered in a high temperature atmospheric ambient for about 3 hours to produce a target. The high temperature atmospheric temperature ranges from about 850 degrees to about 1000 degrees in centigrade, and the target is about 100 millimeters in diameter and about 5 millimeters in thickness. In this manner, a plurality of targets are produced and different in composition from one another. The targets are substantially identical in composition with the mixed powders, respectively, and have respective structures each having grains of the copper oxide and/or grains of the barium oxide distributed over the superconductive oxide. Each of the targets thus produced is installed in a high-frequency sputtering system and faced to a substrate of a single crystal magnesium oxide with 〈100〉 orientation. The substrate is spaced apart from the target by about 90 millimeters and has a square surface of about 10 millimeters x about 10 millimeters. The sputtering chamber is filled with a gaseous mixture with the argon/oxygen ratio of about 3 : 1, and the gaseous mixture is adjusted to about 0.655 Pa (5 x 10⁻³ torr). The substrate is heated to about 650 degrees in centigrade, and the sputtering is carried out at about 200 watts for about 8 hours. A plurality of superconductive strips are thus deposited to a thickness of about 2 µm on the substrates, respectively, and, then, subjected to a heat treatment in an oxygen ambient at about 910 degrees in centigrade for about an hour. The compositions of the superconductive strips are indicated in Table 1 with reference numerals 1 to 9 and have the grains of the copper oxide and/or the grains of the barium oxide distributed over the superconductive oxides, respectively. For comparison use, prior-art superconductive strips 10 to 14 are produced and also indicated in Table 1. The prior-art superconductive strips are formed of respective superconductive oxides without any grains of the copper oxide or the grains of the barium oxide. All of the superconductive strips 1 to 14 are observed whether or not cracks are produced therein, and critical current densities as well as critical temperatures are respectively measured. The results are indicated in Table 2. In Table 1, S.C. stands for the word "superconductive", and CuO and BaO represent the copper oxide and the barium oxide, respectively. Specimen Cracks Critical current density (A/cm²) Critical Temperature (degrees in Kelvin ) 1 none 6.0 x 10⁴ 76 2 none 2.2 x 10⁴ 75 3 none 8.5 x 10⁴ 78 4 none 5.5 x 10⁴ 75 5 none 1.3 x 10⁴ 74 6 none 6.0 x 10⁴ 76 7 none 7.2 x 10⁴ 75 8 none 9.0 x 10⁴ 78 9 none 1.8 x 10⁴ 76 10 Observed 7.2 x 10³ 77 11 Observed 5.8 x 10³ 77 12 Observed 9.2 x 10³ 74 13 Observed 9.5 x 10³ 76 14 Observed 6.3 x 10³ 77 As will be understood from Table 2, the grains of the copper oxide and/or the grains of the barium oxide effectively absorb the thermal stress produced in the heat treatment stage. The stress absorber content of the superconductive strip is fallen within the range between about 0.12 % by volume and about 7.9 % by volume. If the stress absorber content is less than 0.1 % by volume, the cracks are hardly suppressed due to insufficient absorption. On the other hand, if the stress absorber content exceeds about 8.0 % by volume, the strip tends to deteriorate in superconductivity.

Claims: A superconductive strip containing a superconductive oxide and an internal stress absorbing substance dispersed over the superconductive oxide, characterized in that said stress absorbing substance is copper oxide represented by the chemical formula of CuO ranging from about 0.12 % by volume to about 7.9 % by volume. A superconductive strip containing a superconductive oxide and an internal stress absorbing substance dispersed over the superconductive oxide, characterized in that said stress absorbing substance comprises barium oxide represented by the chemical formular BaO. A superconductive strip as said forth in claim 2, in which said internal stress absorbing substance ranges from about 0.12 % by volume to about 7.9 % by volume. A superconductive strip as claimed in claims 2 or 3, characterized in that said internal stress absorbing substance further comprises CuO.

Inventors: FUJINO SHUICHI C O MITSUBISHI, SUGIHARA TODASHI C O MITSUBISH, TAKESHITA TAKUO C O MITSUBISHI, FUJINO, SHUICHI C/O MITSUBISHI METAL CORPORATION, SUGIHARA, TODASHI C/O MITSUBISHI METAL CORPORATION, TAKESHITA, TAKUO C/O MITSUBISHI METAL CORPORATION
Applicants: MITSUBISHI MATERIALS CORP, MITSUBISHI MATERIALS CORPORATION
Application year: 1989
Main classification: H01L39
IPC codes: C01B13, H01L39, C04B35, C01G1, H01B12, C01G3