ADJUVANTS FOR USE WITH CROP PROTECTION AGENTS

Abstract: The invention relates to adjuvants for use with crop protection agents, especially herbicides which enhance the effectiveness of such herbicides. These adjuvants contain a low-foaming nonionic surfactant and an anionic surfactant, and optionally a lower alkanol ester of a fatty acid, and optionally a hydrocarbon oil component.

Description: The subject invention relates to adjuvants for crop protection agents which fall into the category of crop oil concentrates. More particularly, the subject invention relates to improved crop oil concentrates which enhance the efficacy of active ingredients, allowing greater or equal weed control while using less active ingredient. It is well established that a variety of adjuvants play important roles in the formulation and application of crop protection agents. These adjuvants are a diverse group of components with equally diverse functions which may often be determined from their generic names, i.e. "spreaders", "stickers", "solubilizers", "emulsifiers', "flow control agents", "drift control agents", and so on. Among the many useful adjuvants are the so-called "crop oil concentrates". Crop oil concentrates are often recommended by manufacturers and formulators for inclusion in crop protection agents to increase the efficacy of crop protection agents, especially herbicide formulations. Crop oil concentrates are available from a variety of sources, and generally consist of from 75-95 percent by weight of a hydrocarbon oil or solvent with the balance being a surfactant, although in certain cases the surfactant may comprise a majority of the composition, or even all of the composition. The hydrocarbons which form a major part of the crop oil concentrate may be derived from mineral (petroleum) or vegetable sources. When derived from mineral sources, the hydrocarbon component may be predominately paraffinic, or may be aromatic, particularly alkylated aromatic. Although the use of selected crop oil concentrates may enhance biological efficacy, it is well known that many of the proprietary concentrates available are not as effective as others. Some may even have a negative impact, for example on herbicidal efficacy. Thus there is a need in the agricultural sector for a crop oil concentrate which is capable of enhancing the efficacy of a broad spectrum of crop protection agents, and which gives reproducible results. It has now surprisingly been discovered that certain crop oil concentrates enhance as adjuvants the activity of crop protection agents, especially of a spectrum of herbicides over and above the efficacy obtained with other, commercial, adjuvants. These crop oil concentrates are useful with herbicides containing cyclohexenones, benzothiadiazinone dioxides, diphenyl ethers, quinoline carboxylic acids, (het)aryloxyphenoxypropionic acid derivatives, bipyridilium salts and imidazolinone derivatives, especially with cyclohexenone-type herbicides, increasing the overall effectiveness of formulations of such herbicides. The crop oil concentrates of the subject invention comprise a mixture of (a) a first active component which is a low-foaming nonionic surfactant; (b) a second active component which is an anionic surfactant derived from esterification of a polyoxyalkylene nonionic surfactant with a dihydric or trihydric inorganic acid or by carboxylation with an organic acid derivative; and (c) optionally and preferably a third active component which is a lower alkanol ester of a long chain fatty acid, or, when the low-foaming nonionic surfactant is a block surfactant containing oxyethylene and higher oxyalkylene residues, a polyoxyethylated aliphatic alcohol or mixtures of polyoxyethylated aliphatic alcohol and lower alkanol ester. As a fourth component (d), a hydrocarbon component ("oil") is preferably added. The low-foaming surfactants (a) are polyoxyalkylene nonionic surfactants initiated with long chain aliphatic alcohols which have little tendency to foam as measured, for example, by the Ross-Miles test. Preferably, the low-foaming surfactant should have a dynamic foam height, measured at 0.1 percent concentration and 50°C, of less than 10 cm, more preferably less than 6 cm, and most preferably 3 cm or less. The low-foaming surfactants typically have hydrophile/lipophile (hydrophile/lipophile balance; HLB) values of less than 12, preferably less than 8 and most preferably less than 6. The low-foaming surfactants (a) of the subject invention comprise two related types of surfactants or their mixtures. Both types of low foamers are initiated with long chain fatty alcohols having chain lenghts of from 6 to 22, preferably from 10 to 18, and particularly from 13 to 15 carbons in the aliphatic hydrocarbon portion of the molecule. One type of low foamer (a) is prepared by oxyethylating the previously described aliphatic alcohols with from 2-6 moles of ethylene oxide, preferably 3-5 moles. The second type of low foamer is prepared by oxyalkylating the aliphatic alcohol initiator with both ethylene oxide and a higher alkylene oxide, preferably propylene oxide, butylene oxide, or mixtures thereof. The oxyalkylation by the various alkylene oxides may take place substantially sequentially or may take place concurrently, the product having the low-foaming properties previously described. In this second type of low-foaming surfactant, from 2 to 20 moles of ethylene oxide and from 1 to 15 moles of higher alkylene oxide are utilized. Preferably, the oxyalkylation is sequential and involves the addition of preferably from 2 to 12, more preferably from 2 to 10 moles of ethylene oxide followed by the addition of from 1 to 15, preferably from 1 to 10, moles of higher alkylene oxide. When butylene oxide is the higher alkylene oxide, generally less higher alkylene oxide need be used than when propylene oxide is the higher alkylene oxide. From 1 to 4 moles of butylene oxide is preferred. When both alkylene oxides are added concurrently to form a low-foaming surfactant, from 2 to 18 moles, preferably 4 to 8 moles, of ethylene oxide are used with from 2 to 10, preferably 3 to 7, moles of higher alkylene oxide. The anionic surfactants (b) which are useful in the practice of the subject invention are preferably the partial sulfate and phosphate esters of polyoxyalkylene ethers. These partial esters are prepared by methods well known to those skilled in the art, for example by reacting one of the well known and commercially available monohydric polyoxyalkylene ethers with sulfuric acid or phosphoric acid or their chemical equivalents. The sulfate esters so obtained consist predominately of the half ester (monoester) while the phosphate esters generally contain both mono- and di-esters. Also useful are the carboxylate surfactants. The methods of preparation of such surfactants are well known to those skilled in the art. The sulfate esters may be prepared, for example, by reacting a suitable monofunctional polyoxyalkylene ether with sulfuric acid or its chemical equivalent, preferably sulfamic acid or sulfur trioxide. The phosphate esters may be prepared similarly by reaction of the monofunctional polyoxyalkylene ether with phosphoric acid, diphosphorus pentoxide, polyphosphoric acid, or phosphorus oxytrichloride. In a similar manner, difunctional polyoxyalkylene ethers may be reacted with the phosphate ester producing reagent to form a surfactant containing an internal polyoxyalkylene component terminated with phosphate ester groups. Methods of preparation are described in the treaties Nonionic Surfactants, Martin Schick, Ed., Marcel Dekker, New York, 1967, in Chapter 11, pp 372-394. The nonionic, monofunctional and difunctional polyoxyalkylene ethers used to prepare the sulfate and phosphate esters are also well known to those skilled in the art, and are available commercially from many sources. Preferred nonionic polyoxyalkylene ethers have molecular weights of from 400 to 3000 Daltons, more preferably from 600 to 1200 Daltons, and particularly about 800 Daltons. The preferred polyethers are prepared by oxyalkylating a monofunctional or difunctional initiator by known methods. Preferred initiators are the alkylphenols such as octyl- and nonylphenol, and the aliphatic alcohols, particularly the latter. The preferred aliphatic alcohols have from 6 to 30, more preferably from 10 to 20, and in particular from 12 to 16 carbon atoms in the aliphatic residue. The alkylene oxides which may be used to prepare the nonionic monofunctional polyoxyalkylene intermediates include ethylene oxide, propylene oxide, and butylene oxide. Tetrahydrofuran may also be useful. Preferred alkylene oxides are ethylene oxide and propylene oxide. When both these oxides are utilized, they may be added simultaneously, in sequence, or in combinations of these modes of addition, the prepare block surfactants. Ethylene oxide may also be used alone to form homopolymeric polyoxyethylene polyethers. The carboxylate surfactants are derived from oxyethylated aliphatic alcohols by reaction with chloroacetic acid in the presence of base. The preparation is described in the Schick treatise, supra, at pages 388-89. Preferably, the aliphatic alcohol contains from 6 to 30, more preferably from 10 to 20, and particularly from 12 to 16, carbon atoms, and is oxyethylated with from 2 to 10, preferably from 3 to 8, moles of ethylene oxide. Preferred is the carboxylate formed from the reaction of chloroacetic acid and the four mole oxyethylate of lauryl alcohol. Reference in the specification and the claims to "carboxylates" of monohydroxyl functional polyoxyalkylene ethers is to this type of surfactant. The lower alkanol ester of the long-chain carboxylic acid (c) may be considered as derived from a lower alkanol having from 1 to 4 carbon atoms, such as methyl alcohol, ethyl alcohol, propyl alcohol, or butyl alcohol, and a long chain carboxylic acid. The methyl and ethyl esters are preferred. Most particularly, the methyl esters are utilized. The long-chain carboxylic acid preferably contains from 6-22 carbon atoms, more preferably from 14-18 carbon atoms. Most preferred are those carboxylic acids obtainable from natural sources such as fats and oils, for example lauric, myristic, stearic, linoleic, linolenic, palmitic, and oleic acids. Mixtures of these acids are also useful. Preferred are oleic and palmitic acids and their mixtures. Thus the most preferred alkanol esters are methyl oleate, methyl palmitate, and mixtures of these esters. In the remainder of the specification, such compounds will be referred to as lower alkanol esters. When the low-foaming nonionic surfactant (a) is not a polyoxyethylated aliphatic alcohol, then all or part of the lower alkanol ester (c) may be replaced by a low to moderate foaming type of surfactant. Examples are the greater than 3 mole, preferably 4-6 mole, oxyethylated alcohols. Such alcohols should contain from 6 to 22 carbon atoms and may be aliphatic, cycloaliphatic, aromatic or alkylaromatic in nature. Examples of preferred replacement surfactants are the 4 mole oxyethylates of long-chain aliphatic alcohols such as lauryl alcohol. Component (d) may be derived principally from vegetable or petroleum sources. Preferred are the aromatic solvents, particularly those containing alkylated aromatics such as the benzenes and naphthalenes. Component (d) may also be a paraffinic or aromatic "oil" or solvent derived from mineral sources. Such solvents are readily available from a number of sources, for example, the Shellsolve® (alkyl aromatic) solvents available from the Shell Oil Co., Houston, Texas, and the Aromatic® 150 and 200 (mixed aromatic) solvents available from Exxon Corporation. Suitable paraffinic hydrocarbons are preferably solvent-refined petroleum oil fractions composed of naphthenic as well as paraffinic hydrocarbons with less than 25 weight percent of aromatics. Such hydrocarbon "oils" generally have high flashpoints, i.e. above 200°F, preferably above 300°F. Mixtures of paraffinic and aromatic hydrocarbons may also be used. The hydrocarbon component (d) may also contain up to about 30 percent by weight, preferably from 10-30 percent by weight, of a solvent-soluble alcohol, for example n-hexanol or isooctanol, to maintain or enhance the physical properties of the blend. Other solvent-soluble alcohols which are suitable are those which generally contain from 5 to 18 carbon atoms, preferably from 5 to 10 carbon atoms. The term "hydrocarbon component" as used herein should be taken as including both aliphatic and aromatic solvents as weil as their mixtures, including also the solvent-soluble alcohol component described immediately above. The hydrocarbon component is believed to exert a minor biochemical effect in concert with that of the remaining ingredients, and hence may be considered an active ingredient. When utilized as a crop oil concentrate without the hydrocarbon component, the composition generally contains, in percent by weight relative to the total weight of the concentrate, from 20 to 90 percent low-foaming surfactant (a), 4 to 40 percent anionic surfactant (b), and 0 to 30 percent lower alkanol ester (c). Preferably, the composition contains 30 to 80 percent low-foaming surfactant, 4 to 20 percent anionic surfactant, and 2 to 16 percent lower alkanol ester. Most preferably it contains 70 to 80 percent low-foaming surfactant, 5 to 10 percent anionic surfactant, and 4 to 12 percent lower alkanol ester. The preferred hydrocarbon component-containing crop oil concentrates generally contain, in percent by weight relative to the total weight of the crop oil concentrate, from 10 to 60 percent of low-foaming surfactant, from 2 to 20 percent anionic surfactant, from 0 to 20 percent lower alkanol ester, and from 70 to 30 percent hydrocarbon component. More preferably, the crop oil concentrate contains from 25 to 45 percent low-foaming surfactant, 2 to 10 percent anionic surfactant, 2 to 8 percent lower alkanol ester, and 60 to 40 percent hydrocarbon component. Most preferably, the crop oil concentrate contains from 35 to 40 percent low-foaming surfactant, from 5 to 10 percent anionic surfactant, from 4 to 7 percent lower alkanol ester, and from 80 to 20, preferably 40 to 50, percent hydrocarbon component. The hydrocarbon component may optionally contain up to 30 percent, preferably from 10 to 20 percent, and most preferably about 18 percent, of a solvent-soluble alcohol. The crop oil concentrates of the subject invention may be incorporated in crop protection agents in such amounts which result in ranges of from 0.25 to 8 l/HA, preferably from 1 to 5 l/HA, particularly 1 to 3 l/HA. Crop protection agents are compositions (formulations) comprising active ingredients and commonly used inert additives in the form of emulsion concentrates, suspension concentrates (flowables), wettable powders or water-dispersible granules. Depending on the active ingredient, such a composition may also be an aqueous solution. These compositions are usually applied as tankmixes, the compositions being adjusted to a certain use concentration by diluting with water. The subject invention crop oil concentrates may also be used in conjunction with a nitrogen source such as urea, ammonium sulfate, ammonium nitrate, ammonium phosphate and the like. The crop oil concentrates of the subject invention have been found effective with crop protection agents containing active ingredients of diverse chemical structure, for example with herbicides from the classes of cyclohexane-1,3-diones, the benzothiadiazinone dioxides, the diphenyl ethers, quinolinecarboxylic acids, (het)aryloxyphenoxypropionic acid derivatives, including quinoxalinyloxyphenoxy herbicides, bipyridilium salts and imidazolinone derivatives and with plant growth regulators, for example thiadiazuron. The crop oil concentrates are especially effective with cyclohexenone-type herbicides. The cyclohexenone herbicides with which the subject invention crop oil concentrates may be used are well known. Examples of their preparation and use may be found in U.S. patents 3,950,420; 4,011,256; 4,249,937; and 4,666,510. Specific mention may be made of certain of the more common cyclohexenones, including alloxydim (2-[1(allyloxyamino)-butylidene]-5,5-dimethyl-4-methoxycarbonyl-cyclohexane-1,3-dione and its sodium salt), sethoxydim (2-[1-ethoxyamino)-butylidene]-5-(2-ethylthio-propyl)-cyclohexane-1,3-dione), cycloxydim (2-[1-ethoxyamino)-butylidene]-5-(3-thianyl)-cyclohexane-1,3-dione), clethodim (2-[1-(3-chloro-2-propenyl-oxyimino)-propyl]-5-(2-ethylthio-propyl)-cyclohexane-1,3-dione), and cloproxydim (2-[1-(3-chloro-2-propenyl-oxyimino)-butyl]-5-(2-ethylthiopropyl)-cyclohexane-1,3-dione). A representative of benzothiadiazinone dioxides is bentazon (3-(1-methylethyl-1H-2,1,3-benzothiadiazin-4(3H)-one-2,2-dioxides; U.S. patent 3,708,277). The diphenyl ether herbicides and their analogues are likewise well known. These herbicides are described, for example, in chapter 14 of Herbicides, P.C. Kearney et al., published by Marcel Dekker, Inc., New York 1976. Representatives of this class are acifluorfen (5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoate sodium salt), bifenox (5-(2,4-dichlorophenoxy)-2-nitro-benzoic acid methyl ester), fluoroglycofen (5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoic acid (2-ethoxycarbonyl-ethyl)-ester), lactofen (5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoic acid (1-ethoxycarbonyl-ethyl)ester) and fomesafen (5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-N-methanesulfonyl-benzamide. Examples of quinolinecarboxylic acids are quinclorac (3,7-dichloro-8-quinoline-carboxylic acid; U.S. patent 4,497,651) and quinmerac (3-methyl-7-chloro-8-quinoline-carboxylic acid; U.S. patent 4,715,889). Examples of (het)aryloxyphenoxypropionic acid derivatives are diclofopmethyl (methyl-2-[4-(2,4-dichloro-phenoxy)-phenoxy]-propionate), fluazifop (butyl-2-[4-(5-trifluoromethyl-2-pyridyloxy)-phenoxy]-propionate, haloxyfop (methyl-2-[4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)-phenoxy]-propionate, quinofop-ethyl (ethyl-2-[4-(6-chloro-2-quinoxanyloxy)-phenoxy]-propionate, fenoxaprop-ethyl (ethyl-2-[4-(6-chloro-2-benzoxazolyloxy)-phenoxy]-propionate). Representatives of bipyridilium salts are diquat (1,1′-ethylene-2,2′-bipyridilium dibromide), paraquat (1,1′-dimethyl-4,4′-bipyridilium dichloride) and morfamquat (1,1′-bis(3,5-dimethyl-morpholino-carbonyl methyl)-4,4′-bipyridilium dichloride). Examples of imidazolinone derivatives are imazaquin (2-[4,5-dihydro-4-methyl-4-(1-methyl-ethyl)-5-oxo-1H-imidazol-2-yl]-3-pyridine-carboxylic acid) and imazethapyr (2-[4,5-dihydro-4-methyl-4-(1-methyl-ethyl)-5-oxo-1H-imidazol-2-yl]-5-ethyl-3-pyridinecarboxylic acid). In addition to the use of the crop oil concentrates as herbicide adjuvants, they are also useful in promoting the biological activity of various other pesticides such as fungicides, mildewcides, defoliants, and insecticides and plant growth regulators. In the examples which follow, herbicidal and plant growth regulating compositions are tested for their efficacy against a variety of common weeds. In many cases, comparisons are made to similar tankmix compositions but containing other crop oil concentrates. The "standard" crop oil concentrate used for comparison purposes is "Booster Plus E", a product of Agway Corporation. This product has been widely used in herbicide applications and appears to have consistent formulation and product quality. In the examples, this "Standard" crop oil concentrate is labeled "OC". In all the tables showing efficacy of the crop oil concentrate/herbicidal compositions against various species of weeds, the numerical value in the tables represent the percentage of weed control, or percent kill of the various species. Examples 1-6 Adjuvants (crop oil concentrates) according to the invention were prepared in accordance with the formulations presented in Table I. The ingredients were mixed in the order indicated, all parts being by weight. To compare the efficacy of the subject-invention crop oil concentrates with alternative crop oil concentrates, the respective concentrates were added at levels of generally from 0.25 to 5 l/HA to tankmixes containing the active ingredients and agitated to prepare a uniform mixture. Standard abbreviations for the various weed species found in the text which follows are listed below: ABUTH Abutilon theophrasti velvet leaf AVEFA Avena fatua wild oats BRAPP Brachiaria platyphylla broadleaf signal grass BROSE Bromus secalinus cheatgrass CYNDA Cynodon dactylon bermudagrass DATST Datura stramonium jimsonweed DIGSA Digitaria sanguinalis large crabgrass ECHGG Echinochloa crus-galli barnyardgrass HORVX Hordeum vulgare barley (volunteer) IPOSS Ipomoea spp. morningglory species LEFFI Leptochloa filiformis red sprangletop LOLMU Lolium multiflorum annual ryegrass SETLU Setaria lutescens yellow foxtail SETVI Setaria viridis green foxtail SORHA Sorghum halepense Johnson grass TRZAX Triticum aestivum wheat (volunteer) TRFSS Trifolium spp. Clover species ZEAMX Zea mays corn (volunteer) Table II shows the greater effectiveness of the crop oil concentrate of Example 3 when used with a defoliation agent, thidiazuron, in preventing regrowth of cotton. The comparative adjuvant is surfactant "WK", a Product of E.I. Dupont de Nemours & Company. Cotton Defoliation and Regrowth at 150 g active/HA Adjuvant Defoliation, % Regrowth Crop oil concentrate of Example 1 100 0.2 Surfactant WK 100 2.4 Table III summarizes the increased effectiveness of cycloxydim in combating volunteer oats, barley, and wheat in peas (var. "Progress 9"). In Table IV, the greater effectiveness of the subject invention over the standard concentrate is demonstrated against various grass species in alfalfa. Table V summarizes the effectiveness of a crop oil concentrate of the subject invention as compared to the standard concentrate when added to sethoxydim formulations for grass control in peas. In Table VI, weed control in soybeans was assessed 29 DAT using sethoxydim at 150 g/HA and various crop oil concentrates at 2 ℓ/HA. Table VII indicates the greater effectiveness of the crop oil concentrates of the subject invention in controlling volunteer corn using sethoxydim at a rate of 100 g/HA and various adjuvants at ca. 2 ℓ/HA. Volunteer Corn Control Using 100 g/HA Sethoxydim and Various Adjuvants Adjuvant ZEAMX (30 DAT) ZEAMX (40DAT) OC 40 46 Example 1 75 79 Example 2a 73 65 Example 2 82 89 Example 3 85 86 In Table VIII, sethoxydim control of grass species in peas is assessed with various adjuvants. Sethoxydim was applied as a tankmix at a rate of 100 g/HA with adjuvant at 2 l/HA. Table IX demonstrates the greater control of bermudagrass and johnsongrass by cycloxydim at 200 g/HA in the presence of various adjuvants at 1.0 weight percent in the tankmix. Table X demonstrates the increased herbicidal activity of bentazon [3-(1-methylethyl-1H-2,1,3-benzothiadiazin-4(3H)-one-2,2-dioxide] in broadleaf weed control in soybeans during greenhouse trials. Bentazon was used at a rate of 480 g/HA. Table XI demonstrates the greater effectiveness of the subject invention crop oil concentrate as compared to a crop oil concentrate Assist® (an emulsifiable mineral oil). Control of three weed species 41-43 days after treatment averaged from 4-5 locations is presented. The herbicide is sethoxydim used at 150 g/HA. Table XII demonstrates the increased effectiveness of the subject invention crop oil concentrates on volunteer barley and wheat 42 DAT. The herbicide is sethoxydim used at 200 g/HA. The adjuvant is used at 2 l/HA. Tables XIII and XIV demonstrate the greater effectiveness of the subject invention crop oil concentrates wich Quinclorac. In rice, in particular, the crop oil concentrate at 4ℓ/HA causes no damage to the crop. In contrast, other commercial crop oil concentrates were both less effective against barnyard grass and exhibited crop damage. Grass Control With Quinclorac at 280 g/HA Adjuvant Adjuvant Rate, ℓ/HA % Grass Control none ---- 40 OC 2.3 55 DASH™ 2.3 48 Example 3 2.3 66 Grass Control in Rice with Quinclorac at 60 g/HA Adjuvant Rate Rice Damage ECHCG Control Atplus® 411 1ℓ/HA 0 68 4ℓ/HA 10 85 Citowett 1ℓ/HA 10 68 4ℓ/HA 20 72 Example 3 1ℓ/HA 0 85 4ℓ/HA 0 96

Claims: Use of an adjuvant for increasing the effectiveness of herbicidal agents which comprises, in percent by weight, a) from 20 to 90 percent of a low-foaming nonionic surfactant selected from the group consisting of i) alkylpolyoxyethylene polyethers wherein the alkyl group contains from 6 to 22 carbon atoms and the polyoxyethylene moiety is derived from 2 to 6 moles of ethylene oxide; and ii) alkylpolyoxyalkylene polyethers wherein the alkyl group contains from 6 to 22 carbon atoms and the polyoxyalkylene moiety is derived from ethylene oxide and a higher alkylene oxide, and wherein the polyether has an HLB of less than 12; and iii) mixtures thereof; and b) from 4 to 40 percent of an anionic surfactant selected from the group consisting of i) the partial surface and phosphate esters and carboxylates of monohydroxylfunctional polyoxyalkylene ethers; and ii) the partial phosphate esters of dihydroxyfunctional polyoxyalkylene ethers; and optionally c) 0 to 30 percent of a third component selected from the group consisting of i) the lower alkanol esters of 6 to 22 carbon carboxylic acids; and ii) when component a)ii) is not present, the alkylpolyoxyethylene polyethers wherein the alkyl group contains 6 to 22 carbon atoms and the polyoxyethylene moiety is derived from 3 to 8 moles of ethylene oxide. Use of an adjuvant as set forth in claim 1 which comprises components a), b) and c) in amounts of from 10 to 90 percent by weight of a), from 2 to 40 percent by weight of b) and 0 to 30 percent by weight of c) and additionally from 80 to 20 percent by weight of a hydrocarbon component containing from 100 to 70 weight percent based on the total weight of the (b) component of a hydrocarbon oil selected from the group consisting of i) an aromatic hydrocarbon component; ii) an aliphatic hydrocarbon component, iii) mixtures thereof; and from 0 to 30 weight percent of a solvent-soluble alcohol component. Use of an adjuvant as set forth in claim 1 wherein the low-foaming surfactant a) is an alkylpolyoxyalkylene polyether containing from 2 to 20 oxyethylene moieties and from 1 to 15 higher polyoxyalkylene moieties selected from the group consisting of polyoxypropylene and polyoxybutylene, and wherein said alkyl group has from 10 to 18 carbon atoms. Herbicidal compositions containing an adjuvant according to claim 1 and a herbicidally active ingredient selected from the group consisting of cyclohexane-1,3-diones, benzothiadiazinone dioxides, diphenyl ethers, quinoline carboxylic acids, (het)aryloxy-phenoxypropionic acid derivatives, bipyridilium salts and imidazolinone derivatives. Herbicidal compositions containing an adjuvant according to claim 2 and a herbicidally active ingredient selected from the group consisting of cyclohexane-1,3-diones, benzothiadiazinone dioxides, acids, (het)aryloxy-phenoxypropionic acid derivatives, bipyridilium salts and imidazolinone derivatives. A herbicidal composition according to claim 4, where the herbicidally active ingredient is a cyclohexane-1,3-dione. A herbicidal composition according to claim 4, where the herbicidally active ingredient is a benzothiadiazinone dioxide. A herbicidal composition according to claim 4, where the herbicidally active ingredient is a quinolinecarboxylic acid. A process for increasing the effectiveness of herbicidal agents, comprising incorporating in such agents the adjuvant of claim 1 in amounts which result in ranges of from 0.25 to 5.0 l/HA. A process for increasing the effectiveness of herbicidal agents, comprising incorporating in such agents the adjuvant of claim 2 in amounts which result in ranges of from 0.25 to 5.0 l/HA. A postemergent herbicide adjuvant suitable for use in tankmixes, comprising, in percent by weight, a) from 20 to 90 percent of a low-foaming nonionic surfactant selected from the group consisting of i) alkylpolyoxyethylene polyethers wherein the alkyl group contains from 6 to about 22 carbon atoms and the polyoxyethylene moiety is derived from 2 to 6 moles of ethylene oxide; and ii) alkylpolyoxyalkylene polyethers wherein the alkyl group contains from 6 to 22 carbon atoms and the polyoxyalkylene moiety is derived from ethylene oxide and a higher alkylene oxide, and wherein the polyether has an HLB of less than 12; and iii) mixtures thereof; and b) from 4 to about 40 percent of an anionic surfactant selected from the group consisting of i) the partial sulfate and phosphate esters and carboxylates of monohydroxylfunctional polyoxyalkylene ethers; and ii) the partial phosphate esters of dihydroxyfunctional polyoxyalkylene ethers; and optionally (c) 0 to 30 percent of a third component selected from the group consisting of i) the lower alkanol esters of 6 to 22 carbon carboxylic acids; and ii) when component a) ii) is not present, the alkylpolyoxyethylene polyethers wherein the alkyl group contains 6 to 22 carbon atoms and the polyoxyethylene moiety is derived from 3 to 8 moles of ethylene oxide.

Inventors: HAZEN, JAMES LYLE
Applicants: BASF CORPORATION
Application year: 1989
Main classification: A01N25
IPC codes: A01N25