Thermosetting epoxy resin composition

Abstract: A new thermosetting resin composition is disclosed which comprises a Bisphenol A-type epoxy resin having a number average molecular weight of smaller than 650 but not smaller than 450 and a ratio of the weight average molecular weight thereof to the number average molecular weight thereof of in the range of 1.3-3.0; and a curing agent capable of cross-linking the epoxy resin. The curing agent is preferably a compound represented by the following general formula: wherein X is -CR₁R₂-, -CO-, -COO-, -SO₂-, -SO-, -S-, -O-, -NR₁-, -SiR₁R₂- or -POR₁- where R₁ and R₂ each stands for hydrogen, a lower alkyl or a phenyl; Y and Y′ each stands for hydrogen, a lower alkyl or an electron attractive group; R is a lower alkyl; and m and n each is an integer of 1-4, or a mixture thereof with a primary amine, a phenolic compound or an acid anhydride.

Description: This invention relates generally to a thermosetting epoxy resin composition and, more specifically, to a thermosetting composition containing a specific Bisphenol A-type epoxy resin and affording a cured resin product excellent in hardness, modulus, heat resistance and toughness. Because of their excellent resistance to heat and chemicals and excellent hardness and modulus, epoxy resins have been utilized for a wide variety of applications. For example, epoxy resins are known to be used as a matrix material for fiber-reinforced composite plastics. One problem associated with the use of an epoxy resin as a matrix of a fiber-reinforced plastic is directed to its low toughness. For example, Japanese Unexamined Patent Application (Tokkyo Kokai) No. 62-127,317 discloses an epoxy resin composition useful for the formation of a prepreg matrix resin, which includes a Bisphenol A-type epoxy resin having an epoxy equivalent of 2400-3300 and a number average molecular weight of 3750, and a curing agent. While such an epoxy resin composition can give improved moldability, the cured resin obtained therefrom fails to show satisfactory mechanical strength, particularly toughness. The present invention has been made in view of the above problem of conventional epoxy resin compositions. In accordance with the present invention there is provided a thermosetting composition comprising: a Bisphenol A-type epoxy resin having a number average molecular weight of smaller than 650 but not smaller than 450 and a weight average molecular weight to number average molecular weight ratio in the range of 1.3-3.0; and an epoxy resin curing agent capable of cross-linking the epoxy resin. The thermosetting resin composition according to the present invention can afford a cured product having high modulus, hardness and toughness and excellent resistance to heat and chemicals. Fiber-reinforced plastics containing a matrix resin obtained from such a thermosetting resin composition exhibit improved mechanical strengths such as impact strength, fracture strength, resistance to thermal shock and adhesion. Further, the thermosetting resin composition is excellent in tackiness, drape-formability, flowability and stability so that it is advantageously used for the formation of prepregs. The important characteristic of the epoxy resin composition of the present invention is that the above properties, especially the tackiness and drape-formability, are substantially independent of temperature, i.e. these properties are hardly changed with the change in temperature so that the prepregs exhibit excellent properties in a wide temperature range. The present invention will now be described in detail below. The term "Bisphenol A-type epoxy resin" used herein is intended to refer to an epoxy resin obtained by reaction of Bisphenol A with epichlorohydrin and having as its main ingredient oligomers of the following general formula: The term "epoxy equivalent", which is also generally called "weight per epoxide equivalent", refers to the weight of the epoxy resin per 1 gram equivalent of the epoxy group contained in the epoxy resin. For example, the epoxy equivalent of the epoxy resin of the above formula in which n is 1 is 312. The Bisphenol A-type epoxy resin to be used in the present invention is a mixture of various different molecular weight oligomers. It is important that the Bisphenol A-type resin to be used in the present invention have a number average molecular weight of less than 650 but not less than 450 and that the ratio Mw/Mn of the weight average molecular weight thereof (Mw) to the number average molecular weight thereof (Mn) is in the range of 1.3-3.0. In case where the number average molecular weight of the Bisphenol A-type epoxy resin to be used in the present invention is lower than 450, the tackiness and drape-formability of prepregs containing the thermocurable resin composition become poor. Further, the fluidity of the epoxy resin composition during its curing stage becomes so high that it becomes difficult to produce cured products having satisfactory toughness. Too high a number average molecular weight in excess of 650, on the other hand, is disadvantageous because the tackiness becomes poor at room temperature or below so that lamination of prepregs fails to be effected satisfactory. The number average molecular weight of the epoxy resin is preferably smaller than 650 but not smaller than 500. When the ratio Mw/Mn is below 1.3, the amount of low molecular weight components becomes so large that there are caused defects such as seen in the case of using a Bisphenol A-type epoxy resin having a number average molecular weight of less than 450. On the other hand, a ratio Mw/Mn of above 3.0 also causes defects such as seen in the case of using a Bisphenol A-type epoxy resin with a number average molecular weight of 650 or more because the content of high molecular weight components becomes high. The Bisphenol A-type epoxy resin to be used in the present invention can be obtained by blending two or more commercially available Bisphenol A-type resins. Examples of suitable resins include Epicoat 815, 827, 828, 834, 1001, 1002, 1004, 1007, 1009, 1010 (Trademarks of Yuka-Shell Kabushiki Kaisha) whose epoxy equivalents and molecular weights are shown below: Epicoat Epoxy Equivalent Number Average Molecular Weight 815 181 - 191 330 827 180 - 190 828 184 - 194 380 834 230 - 270 470 1001 450 - 500 900 1002 600 - 700 1060 1004 800 - 900 1600 1007 1750 - 2200 2900 1009 2400 - 3300 3750 1010 3000 - 5000 5500 The Bisphenol A-type epoxy resin may be obtained, for example, by blending a first resin having an epoxy equivalent of 180-195 with a second resin having an epoxy equivalent of greater than 195, the amount and the molecular weight of the second resin being such as to provide a ratio Mw/Mn and a number average molecular weight of the blend of 1.3-3.0 and 450-650, respectively. The first resin may be Epicoat 815, 827, 828 or a mixture thereof while the second resin may be Epicoat 834, 1001, 1002, 1004, 1007, 1009, 1010 or a mixture thereof. When an improvement in heat resistance is desired at the sacrifice of toughness, an epoxy resin which is not a Bisphenol A-type epoxy resin can be incorporated into the thermosetting epoxy resin composition. However, the amount of such an additional epoxy resin should not exceed 50 % by weight based on the total weight of the Bisphenol A-type epoxy resin and the additional epoxy resin, since otherwise there is caused a considerable reduction in toughness. Examples of such additional epoxy resins include glycidyl ether-type epoxy resins such as Bisphenol F-type, Bisphenol S-type, novolac type and brominated Bisphenol A-type epoxy resins; alicyclic epoxy resins; glycidyl ester-type epoxy resins; glycidylamine-type epoxy resins; and heterocyclic epoxy resins. Any curing agent may be used in the present invention. The curing agent is generally used in a schiometric amount with respect to the epoxy resin. Examples of the curing agents include: (A) Amine curing agent: (A-1) aliphatic primary amines such as diethylenetriamine, triethylenetetramine, tetraethylenepentamine, dipropylenetriamine, trimethylhexamethylenediamine, a polyether diamine, diethylaminopropylamine, menthendiamine, methaxylylenediamine and 3,9-bis(3-aminopropyl)-2,4,8,10-tetraspiro[5,5]undecane; (A-2) aromatic primary amines such as methaphenylenediamine, diaminodiphenylmethane, diaminodiphenylsulfone, and aromatic diamine eutectic mixtures; (A-3) modified amines such as amine adducts and cyanoethylated polyamines; (A-4) secondary and tertiary amines such as tetramethylguanidiene, pyperidine, pyridine, picoline, benzyldimethylamine, 2-(dimethylaminomethyl)phenol; and (A-5) polyamides such as condensation products of a dimer acid with a polyamine; (B) acid anhydrides: (B-1) aromatic acid anhydrides such as phthalic anhydride, trimellitic anhydride, ethylene glycol bis(anhydrotrimellitate), glycerol tris(anhydrotrimellitate), pyromellitic anhydride and 3,3′,4,4′-benzophenone tetracarboxylic anhydride; (B-2) alicyclic acid anydrides such as maleic anhydride, succinic anhydride, tetrahydrophthalic anhydride, methyltetrahydrophthalic anhydride, methylnadic anhydride, alkenylsuccinic anhydride, hexahydrophthalic anhydride, methylhexahydrophthalic anhydride, and methylcyclohexene tetracarboxylic anhydride; (B-3) aliphatic acid anhydrides, halogenated acid anhydrides, polycarboxylic anhydride and chloreside anhydride; (C) polyamide resins such as N,N′-bis(6-aminohexyl)adipamide; (D) imidazoles such as 2-methylimidazole, 2-ethyl-4-methylimidazole, 2-undecylimidazole, 2-heptadecylimidazole, 2-phenylimidazole, 1-benzyl-2-methylimidazole, 1-cyanoethyl-2-methylimidazole, 1-cyanoethyl-2-undecylimidazolium trimellitate, 2,4-diamino-6-[2-methylimidazolyl-(1)]-ethyl-S-triazine, 1-dodecyl-2-methyl-3-benzylimidazolium chloride, 2-phenylimidazolium isocyanulate, and 2-phenyl-4-methyl-5-hydroxymethylimidazole; (E) boron trifluoride-amine complexes; (F) dicyanodiamide and its derivatives such as o-tolyl biguanide and α-2,5-dimethylbiguanide; (G) organic acid hydrazides such as succinic acid hydrazide and adipic acid hydrazide; (H) diaminomaleonitrile and its derivatives; (I) melamine and its derivatives such as diallylmelamine; (J) amine imides; (K) polyamines; (L) oligomers such as novolac phenol resins, novolac cresol resins and poly-p-vinylphenols. When the thermosetting epoxy resin composition of the present invention is to be used for the formation of molded articles such as mechanical parts, the use of diaminodiphenylmethane, diaminodiphenylsulfone and dicyanodiamide as the curing agent is preferred for reasons of obtainability of suitable toughness, heat resistance and machinability. When the thermosetting epoxy resin composition is intended to be used for a carbon fiber-reinforced prepreg matrix, the use of dicyanodiamide, diaminodiphenylmethane and diaminodiphenylsulfone is also preferred for reasons of obtainability of suitable tackiness, drape-formability, flowability, workability and stability. It is especially preferable to use as the curing agent at least one compound represented by the following general formula (I): wherein X is -CR₁R₂-, -CO-, -COO-, -SO₂-, -SO-, -S-, -O-, -NR₁-, -SiR₁R₂- or -POR₁- where R₁ and R₂ each stands for hydrogen, a lower alkyl or a phenyl; Y and Y′ each stands for hydrogen, a lower alkyl or an electron attractive group; R is a lower alkyl; and m and n each is an integer of 1-4. Preferably, in the above formula (I), R is an alkyl having 1-3 carbon atoms, X is -CH₂-, -SO₂-, -CO-, -O-, -C(CH₃)₂- or -CHC₆H₅, Y and Y′ each is hydrogen, a lower alkyl, a halogene, a nitro group or trifluoromethyl, R₁ and R₂ each is an alkyl having 1-3 carbon atoms, and m and n each is 1 or 2. Illustrative of suitable compounds of the formula (I) are as follows: The use of the compound of the formula (I) can give a cured epoxy resin product having an improved toughness. It is desirable to use the compound of the formula (I) in conjunction with another curing agent selected from primary amines such as aliphatic amines, aromatic amines, polyamidoamines and dicyanopolyamides; phenolic compounds such as bisphenols, phenolic resins, vinylphenol polymers; acid anhydrides such as maleic anhydride, succinic anhydride, methyltetrahydrophthalic anhydride, methylnadic anhydride and methylhexahydrophthalic anhydride; and mixtures thereof. Of these, the use of diaminodiphenylsulfone, diaminodiphenylmethane, dicyanodiamide or methylhexahydrophthalic anhydride is particularly preferred. By using the compound (I) with the above curing agent, the resulting cured product exhibits such excellent toughness, heat resistance, rigidity, mechanical strengths and other properties that are not expected from the use of them separately. Such a synergetic effect is considered to result from a unique structure of the cured product. That is, when an epoxy resin is reacted with the mixed-type curing agent at an elevated temperature, there are formed, at an early stage of the curing, high molecular weight, linear polymers as a result of the reaction of the epoxy resin and the second curing agent having two secondary amino groups, which is considered to contribute to improvement in toughness of the resulting cured product. The hydroxyl groups of the linear polymers thus formed further react, at a later stage of the curing, with the glycidyl groups of the epoxy resin. At the same time, the first curing agent reacts with the epoxy resin. These two cross-linking reactions are considered to contribute to improvement in regidity and mechanical strengths of the cured product. Thus, the curing involves at least the above three types of cross-linking reactions which proceed homogeneously and continuously to give a cured product having complicated cross-linkages and uniform morphology. The proportion of these two types of curing agents may be arbitrary. Preferably, these two curing agents are used in amounts so that the compound of the formula (I) accounts for 15 to 95 %, preferably 25 to 75 %, of a total of the amounts of active hydrogen of the two curing agents. The amount of the mixed curing agent is preferably such as to provide a ratio of equivalents of the active hydrogen of the mixed curing agent per equivalent of the epoxy group of the epoxy resin in the range of 0.6-1.4, more preferably 0.8-1.2. For preparing the thermosetting composition according to the present invention, the curing agent may be mixed as is or in the form of a solution in a solvent with the Bisphenol A-type epoxy resin. The solvent may be, for example, a ketone such as acetone, methyl ethyl ketone or methyl isobutyl ketone; a cellosolve such as methyl cellosolve or ethyl cellosolve; or an amide such as dimethyl formamide. The mixing may be performed at room temperature or, to facilitate homogeneous mixing, at elevated temperatures. If desired, one or more additives may be incorporated into the resin mixtures. Illustrative of such additives are a reactive diluent such as olefin oxide, glycidyl methacrylate, styrene oxide or phenylglycidyl ether, a curing accelerator such as phenol, a tertiary amine, imidazole, a boron trifluoride complex salt, pyrazole or aminotriazole, and a filler such as silica powder, alumina powder, mica or calcium carbonate. Amounts of these additives may generally range up to 15 % by weight for the reactive diluent, up to 5 % by weight for the curing accelerator, and up to 70 % by weight for the filler based on the total weight of the epoxy resin and the curing agent. The curing is generally performed at temperatures of 100-140 °C for 1-3 hours. This may be followed, if desired, by a post curing treatment which may be performed at 150-220 °C for 1-3 hours. The thermosetting composition according to the present invention can provide a matrix resin, for example, for civil engineering and construction materials, coatings, lining materials, adhesives, molded materials, for electrical appliances (for example, mechanical parts, jigs and tools), fiber reinforced plastic composite materials and the like. The cured, epoxy resin articles obtained using the thermocurable composition of the present invention have excellent heat resistance, modulus, hardness, chemical resistance, toughness, flexibility, rigidity, strength, anti-cracking property, impact strength and rupture strength. The thermosetting composition is especially suited as an FRP matrix resin for the production of composite articles with high mechanical strength. The following examples will further illustrate the present invention. Preparation Example 1: Into 276g (1 mole) or diaminodiphenylsulfone (DDS) in 1000 ml of a mixed solvent of water/ethanol (50/50) were charged 284g (2 moles) of methyl iodide (CH₃I), and the mixture was reacted at 60°C for 2 hours. The resulting crude product was purified by recrystallization with a water/ethanol (50/50) mixed solvent in duplicate. The resulting product is identified by infrared absorption spectrum (IR) and gel permeation chromatography (GPC) and confirmed to be a pure product of an epoxy resin curing agent represented by the following formula: Preparation Example 2: Into 198g (1 mole) of diaminodiphenylmethane (DDM) in 1000 ml of a mixed solvent of water/ethanol (50/50) were charged 284g (2 moles) of methyl iodide (CH₃I), and the mixture was reacted at 60°C for 2 hours. The resulting crude product was purified by recrystallization with a water/ethanol (50/50) mixed solvent in duplicate. The resulting product is identified by IR and GPC and confirmed as a pure product of an epoxy resin curing agent represented by the following formula: Preparation Examples 3-5: In place of diaminodiphenyl sulfone (DDS) used in Preparation Example 1, the process of Preparation Example 1 was followed in the same manner with the exception that there were used compounds of the following general formula: (in which X is -CO-, -S- or -C(CH₃)₂-), yielding the following compounds: Preparation Example 6: In place of diaminodiphenylsulfone (DDS) used in Preparation Example 1, the process of Preparation Example 1 was followed in the same manner with the exception that there was used a compoundof the following general formula: yielding a compound of the formula: Preparation Example 7: Into a solution of 198g (1 mole) of N,N-diaminodiphenylmethane (DDM) in 1,000 ml of a water/ethanol (50/50) mixed solvent were charged 312g (2 moles) of ethyl iodide (C₂H₅I), and the mixture was reacted at 60 °C for 3 hours. The resulting crude product was recrystallized twice from a water/ethanol (50/50) mixed solvent. The resulting reaction product was identified by means of IR and GPC to have the following formula: Preparation Example 8: In place of diaminodiphenylsulfone (DDS) used in Preparation Example 1, the process of Preparation Example 1 was followed in the same manner with the exception that there was used a compound of the following general formula: yielding a compound of the formula: Example 1 Epoxy resins were blended in amounts shown in Table 1 below and the resulting blend was heated to 150 °C to obtain a homogeneous mixture. After cooling to 80 °C, dicyanodiamide was added to the mixture in a stoichiometric amount, thereby to obtain a thermosetting composition. The composition was poured into a mold composed of two glass plates spaced apart from each other by a Teflon spacer, heated at 100 °C for 2 hours, and then cured at 200 °C for 2 hours in an oven. The cured product was sliced into test pieces with a size of 30 cm x 30 cm x 3 mm and the test pieces were subjected tested for Izod strength (IZOD) and glass transition temperature (Tg) to obtain the results summarized in Table 1. A prepreg was also prepared by impregnating carbon fibers (tensile strength: 350 kg/mm², modulus: 32 t/mm²), arranged in parallel with each other, with the above epoxy resin composition. Workability for the fabrication of the prepreg was good. The prepreg showed the tackiness (TAC) at 23 °C as shown in Table 1. Temperature dependency (TDP) of the tackiness was tested at several temperatures in the range of 15-30 °C to reveal that no substantial change in tackiness was caused with the change in temperature. Similar prepregs (12 sheets) were laminated and the laminate was cured under the same conditions as above to obtain carbon fiber-reinforced composite material whose compression after impact (CAI) was as shown in Table 1. The tackiness (TAC) and temperature dependency (TDP) were evaluated according to the following ratings: TAC (at 23 °C) A: good B: relatively bad C: poor TDP (15-30 °C) A: no substantial change B: significant change Examples 2-5 Example 1 was repeated in the same manner as described except the compositions of the epoxy resin blends were changed as shown in Table 1. The results were as summarized in Table 1. The workability for the fabrication of the prepreg was good in the case of Examples 2-4. In Example 5, an epoxy resin (Epicoat 152 manufactured by Yuka Shell Inc., epoxy equivalent: 172-179, number average molecular weight: 370) of non-Bisphenol A-type was additionally used. Comparative Examples 1-5 Example 1 was repeated in the same manner as described except the compositions of the epoxy resin blends were changed as shown in Table 1. The results were as summarized in Table 1. The toughness is poor in Comparative Examples 1, 2 and 4. In the case of Comparative Examples 3 and 5, good prepreg was not obtained. Examples 6, 7, 9 and 10 Examples 1, 2, 4 and 5 were repeated in the same manner as described except that the compound obtained in Preparation Example 2 was used as the curing agent in place of dicyanodiamide. The results are summarized in Table 2. Example 8 Example 2 was repeated in the same manner as described except that the compound obtained in Preparation Example 1 was used as the curing agent in place of dicyanodiamide. The results are summarized in Table 2. Comparative Examples 6 and 9-11 Comparative Examples 1 and 3-5 were repeated in the same manner as described except that, as the curing agent, the compound obtained in Preparation Example 2 was used in place of dicyanodiamide. The results are summarized in Table 2. Comparative Example 7 Comparative Example 1 was repeated in the same manner as described except that, as the curing agent, the compound obtained in Preparation Example 1 was used in place of dicyanodiamide. The results are summarized in Table 2. Comparative Example 8 Comparative Example 6 was repeated in the same manner as described except that a mixed Bisphenol A-type resin having the composition shown in Table 2 was used. The results are summarized in Table 2. Examples 11-15 Example 2 was repeated in the same manner as described except that various mixed curing agents as shown in Table 3 were each used in place of dicyanodiamide. The results were as summarized in Table 3. Examples 16-17 Examples 4 and 5 were repeated in the same manner as described except that a mixed curing agent as shown in Table 3 was used in place of dicyanodiamide. The results are shown in Table 3. Comparative Examples 13-15 Comparative Examples 8, 9 and 11 were repeated in the same manner as described except that a mixed curing agent as shown in Table 3 was used in place of the compound of Preparation Example 2. The results are shown in Table 3. Details of the results of the temperature dependency tests for the prepregs of Examples 3, 7 and 15 and Comparative Examples 2, 5, 8, 10 and 13 are summarized in Table 4. The tackiness value was measured in the following manner. Paper was coated with molten epoxy resin composition to be tested with a thickness of about 30 um. The coated paper was cut into strips having a width of 10 mm. The resulting strip was attached to each of upper and lower holders of a tackiness measuring device (PICMATAC manufactured by Toyo Seiki Co., Ltd.). The two paper strips were then contacted by moving the holders with a predetermined pressure for a predetermined period of time at various temperatures (15°C, 23 °C and 30 °C). Thereafter, the holders were moved backward at a speed of 20 mm/minute. The stress required for separating the contacted strips from each other was measured. This stress (g) represents the tackiness value of the sample at that temperature. Example No. Mn Mw/Mn Tackiness value (g) 15 °C 23 °C 30 °C 3 617 1.9 215 270 235 Comp. 2 534 1.2 380 320 115 Comp. 5 760 2.2 70 170 385 7 582 2.4 220 230 250 Comp. 8 430 1.1 280 150 110 Comp. 10 760 2.2 30 160 250 15 582 2.4 250 270 270 Comp. 13 430 1.1 290 160 115 As will be appreciated from the results shown in Table 4, with the epoxy resin composition according to the present invention, the tackiness values are maintained in the optimum range of 200-300 g irrespective of the temperature change. On the other hand, with the epoxy resin compositions having a number average molecular weight Mn greater than 650 (Comparative Examples 5 and 10), the tackiness considerably increases with the increase of the temperature. When the Mn is lower than 450 (Comparative Examples. 8 and 13) or when the Mw/Mn is below 1.3 (Comparative Example 2), the tackiness considerably decreases with the increase of the temperature. Such temperature dependency causes much difficulty in the preparation of prepregs.

Claims: A thermosetting resin composition comprising: a Bisphenol A-type epoxy resin having a number average molecular weight of smaller than 650 but not smaller than 450 and a weight average molecular weight to number average molecular weight ratio in the range of 1.3-3.0; and an epoxy resin curing agent capable of cross-linking the epoxy resin. A composition as set forth in claim 1, wherein the Bisphenol A-type epoxy resin has a number average molecular weight of smaller than 650 but not smaller than 500 and a weight average molecular weight to number average molecular weight ratio in the range of 1.5-2.7. A composition as set forth in claim 1 or claim 2, further comprising an additional epoxy resin other than a Bisphenol A-type epoxy resin in an amount 50 % by weight or less based on the total weight of said Bisphenol A-type epoxy resin and said additional epoxy resin. A composition as set forth in any preceding claim, wherein said Bisphenol A-type epoxy resin is a blend of a first, Bisphenol A-type epoxy resin having an epoxy equivalent in the range of 180-195 with a second, Bisphenol A-type epoxy resin having an epoxy equivalent of greater than 195, the amount and the molecular weight of said second epoxy resin being such that the blended Bisphenol A-type epoxy resin has a number average molecular weight of smaller than 650 but not smaller than 450 and a weight average molecular weight to number average molecular weight ratio in the range of 1.3-3.0. A composition as set forth in any preceding claim, wherein said curing agent is at least one compound represented by the following general formula: wherein X is -CR₁R₂-, CO-, -COO-, -SO₂-, -SO-, -S-, -O-, -NR₁-, -SiR₁R₂- or -POR₁- where R₁ and R₂ each stands for hydrogen, a lower alkyl or a phenyl; Y and Y' each stands for hydrogen, a lower alkyl or an electron attractive group; R is a lower alkyl; and m and n each is an integer of 1-4. A composition as set forth in claim 5, wherein R is an alkyl having 1-3 carbon atoms, X is -CH₂-, -SO₂-, -CO-, -O-, -C(CH₃)₂- or -CHC₆H₅-, Y and Y' each is hydrogen, a lower alkyl, a halogene, a nitro group or trifluoromethyl, R₁ and R₂ each is an alkyl having 1-3 carbon atoms, and m and n each is 1 or 2. A composition as set forth in claim 5 or claim 6, wherein said curing agent comprises a first element which is at least one member selected from primary amines, phenolic compounds and acid anhydrides, and a second element which is at least one compound represented by the following general formula: wherein X, Y, Y', m and n are each as defined in claim 5 or claim 6. A composition as set forth in claim 7, wherein said first and second elements are used in amounts so that said first and second elements account for 85 to 5 % and 15 to 95 %, respectively, of a total of the amounts of active hydrogen of said first and second elements. A composition as set forth in claim 7 or claim 8, wherein said first element is at least one member selected from aliphatic primary amines, aromatic primary amines, polyamido primary amines, dicyanopolyamides, bisphenols, phenolic resins, vinylphenol polymers, maleic anhydride succinic anhydride, methyltetrahydrophthalic anhydride, methylnadic anhydride and methylhexahydrophthalic anhydride. A composition as set forth in claim 9, wherein said first element is diaminodiphenyl sulfone, diaminodiphenyl methane, dicyanodiamide or methylhexahydrophthalic anhydride. A composition as set forth in any one of claims 7-10, wherein R is an alkyl having 1-3 carbon atoms, X is -CH₂-, -SO₂-, -CO-, -O-, -C(CH₃)₂- or -CHC₆H₅-, Y and Y' each is hydrogen, a lower alkyl, a halogene, a nitro group or trifluoromethyl, R₁ and R₂ each is an alkyl having 1-3 carbon atoms, and m and n each is 1 or 2. A composition as set forth in any one of claims 7-11, wherein the curing agent is used in an amount providing 0.6-1.4 equivalents of active hydrogen per epoxy equivalent.

Inventors: INOUE HIROSHI, MURAKAMI SHINKICHI, WADA SADAHISA, WATANABE OSAMU, INOUE, HIROSHI, MURAKAMI, SHINKICHI, WADA, SADAHISA, WATANABE, OSAMU
Applicants: TONEN CORP, TONEN CORPORATION
Application year: 1989
Main classification: C08G59
IPC codes: C08G59