TESTS FOR WEATHER RESISTANCE

Abstract: In a weather resistance test, a process for washing the surface of samples (6) with a cleaning agent using spray nozzles (11a,11b) is added at least between the condensing of the dew on the surface (6) of the sample by a humidifier (9) after ultraviolet radiation from a source (1) has been applied and again applying ultraviolet radiation after the condensing. Impurities adhered to the surface of the sample and substances extracted at the surface of the sample can be removed by washing with the cleaner so that the surface of the sample to which these impurities and substances were adhered can be protected from such impurities, etc. being baked in the ensuing ultraviolet radiation application. Consequently, generation of spot patterns and an excessive colour change of the surface of the sample during the test can be prevented.

Description: The present invention relates to a method of and apparatus for conducting weather resistance tests, and, more particularly to a method of and an apparatus for weather resistance testing of plastics, paint, ink, pigment, fibre and the like by which the results obtained can satisfactorily simulate outdoor natural deterioration. Hitherto, when it is intended to test the weather resistance of plastics and paint or the like, a weather meter in accordance with any of the Japanese industrial standards (JIS) B7751 to 7754 is generally used. Each of the weather meters of the types mentioned above comprise a light source, such as a carbon arc lamp or a xenon arc lamp, and beams from this light source are directed at the samples. As a result, this allows an accelerated weathering test to be carried out. However, the intensity of the ultraviolet radiation from the light source of the above-described type of weather meter to be applied to the samples is, in general, limited to an unsatisfactory level of substantially 6mW per 100 mm² of the surface of the sample to be tested. Therefore, it takes several hundred hours or longer to measure or evaluate the characteristics of the ultraviolet irradiation-enhanced deterioration which will occur to equate with the deterioration caused by the sun's rays in one year. Furthermore, a method in which all of the samples in each of the batches are subjected to the test has been so far employed in general. Therefore, it takes an excessively long time to complete the test and to evaluate the results, causing a problem in terms of efficiency. To this end, in order to overcome the above-described problems, weather meters described in Japanese Laid-Open Patent Applications Nos. 60-117128 and 60-117129, serve as a pre-weather meter for performing a pre-weather resistance test, which allows ultraviolet ray deterioration to be evaluated in a significantly shortened time, for example, in one tenth or less of the time taken in a conventional test period of time and which involves means for applying to the samples of each batch intense ultraviolet radiation of substantially 50mW or more per 100 mm² of the surface of the sample to be tested by using a metal halide lamp, before having the samples subjected to the weather meter. It is preferable for the weather resistance test to be conducted under physical conditions similar to the actual conditions to which the samples, such as plastics or paint are subjected. In particular at night, not only is the sample subjected to a state in which no sun rays are applied and of low temperatures but also it can be readily brought to a dew condensed state due to the low temperatures at night. Therefore, it is preferable for the weather resistance test or its pre-test to be made under such dew condensation conditions in order to obtain test results which can simulate the natural outdoor deterioration. Hitherto, in a method of producing such dew condensation conditions for samples, as described in Japanese Patent Publication No. 55-13541, samples are watered. However, such watering method cannot faithfully simulate actual dew condensation conditions and this is unsatisfactory. A method of providing an actual dew condensation state for samples by adjusting the temperature of the sample and both the temperature and the humidity of the ambient air surrounding it, has been conceived, as described in Japanese Laid-Open Patent Application No. 62-297744. The weather meter described in this publication is arranged in such a manner that temperature adjusting means is provided for a sample holder and a humidifier is disposed in a chamber of the region in which the thus-provided sample holder is disposed. By producing specific working conditions through control means, the temperature of the sample is lowered below its dew point during periods of stoppage of working of the ultraviolet radiation source, causing the sample to be brought to the dew condensed state which approximates to the natural dew condensation. As means to form dew condensation on the surface of the sample, a method of spraying cooling water onto the reverse side of the sample, has been disclosed, and another method is also described in Japanese Laid-Open Patent Application No. 58-90146 in which the sample is cooled down by thermoelectric cooling element. It has now been found that spot patterns appear on the surface of the sample and the colour of the surface of the sample considerably changes in accordance with time lapse as shown in Figs. 10A and 10B of the accompanying drawings. These figures are microphotographs of the surface of the sample when the above-described dew condensation process is added to the accelerated weathering test in which the sample is irradiated with ultraviolet light. Fig. 10A is a metallurgaical microphotograph, enlarged by 200 times, of the surface of the sample which has not been subjected to the test as yet, while Fig. 10B is a microphotograph, enlarged by 200 times, of the surface of the same sample which has been subjected to the weather resistance test for 50 hours. In addition, it has now been found that the above-described phenomenon occurs particularly significantly when this dew condensation process is added to the above-described accelerated weathering test in which the intensity of the ultraviolet radiation to be applied is considerably strong. Such a spot pattern or the significant colour change does not appear to occur in the case wherein the sample is placed outdoor so as to weather naturally. Therefore, this phenomenon poses a serious problem in taking the simulation between the natural deterioration and the results of the weather resistance test. Such spot patterns can be caused for the following reason: impurities are contained in the condensed dew and appear on the surface of the sample during the dew condensation process or substances extracted from the sample due to the dew condensation adhere to the surface of the sample; and then the extraneous matter on the surface of the sample is baked on this surface of the sample due to the lens effect of the residual condensed dew during the application of the ultraviolet radiation after the dew condensation process; as a result, the above-described spot pattern can be generated. In order to prevent the spot pattern, it might be considered feasible to employ a method in which the sample is inclined or stood erect for the purpose of causing the residual dew on the surface of the sample to run away, a method in which air is blown for the purpose of blowing off the dew, or a method in which the residual dew on the surface of the sample is dried up as to be readily removed. However, none of these methods can achieve a satisfactory effect. To this end, an object of the present invention is to provide a method of and an apparatus for conducting a weather resistance test capable of overcoming the above-described problems experienced with the previously described weather resistance tests in which the dew condensation process is added, whereby no spot pattern or colour change can be generated, and satisfactory test results, which satisfactorily simulate the outdoor natural deterioration results, can be obtained even if the dew condensation process is added to the weather resistance test. A method of conducting weather resistance tests according to the present invention includes a process for applying to a sample, ultraviolet rays from an artificial light source, a process for condensing dew on the surface of this sample, and a process for again applying ultraviolet rays to the above-described sample after the process for condensing dew, the method comprising: a process for washing the surface of the sample with a cleaner which is added at least between the process for condensing the dew on the surface of the sample after the process for applying ultraviolet rays and the process for again applying ultraviolet rays after the process for condensing dew. As described above, impurities adhered to the surface of the sample or substances extracted on the surface of the sample during the dew condensation process can be washed and removed by the cleaner since the process for washing the surface of the sample with a cleaner is added at least between the process for condensing dew on the surface of the sample after the process for applying ultraviolet rays and the process for again applying the ultraviolet rays after the process for condensing dew. Therefore, these substances cannot be baked onto the surface of the sample in the ensuing process of applying ultraviolet rays. As a result, generation of the spot pattern on the surface of the sample can be effectively prevented, and thereby the excessive colour change on the surface of the sample can be prevented. An apparatus for weather resistance tests according to the present invention comprises means for holding a sample, means for applying ultraviolet rays to the sample, means for condensing dew on the surface of the sample, means for washing the surface of the sample with a cleaner, and means for controlling the operation of each of the above-described means. As described above, generation of the spot pattern and the significant colour change of the surface of the sample can be effectively prevented by a simply structured apparatus for which only means for washing the surface of the sample with a cleaner is additionally provided. Consequently, test results which satisfactorily simulate the natural deterioration can be readily obtained. The invention is further described, by way of example, with reference to the accompanying drawings, in which:- Fig. 1 is a schematic view of an embodiment of an apparatus for conducting weather resistance tests according to the present invention; Fig. 2 is a graph which illustrates change in gloss retention rate in an outdoor exposure test; Fig. 3 is a graph which illustrates changes in gloss retention rates in the test of conventional examples 1 and 2; Fig. 4 is a graph which illustrates changes in gloss retention rates in a test according to the present invention, a conventional example 3, and referential example 2; Fig. 5 is a graph which illustrates changes in colour difference ΔE* in the outdoor exposure test, and in the test according to the conventional examples 1 and 2; Fig. 6 is a graph which illustrates changes in colour difference ΔE* in the test according to the present invention, the test according to the conventional example 3 and the referential example 2; Fig. 7A is a graph which illustrates change in lightness value L* in the outdoor exposure test; Fig. 7B is a graph which illustrates changes in value L* in the conventional examples 1 and 2; Fig. 7C is a graph which illustrates changes in value L* in the test according to the present invention and the tests according to the conventional example 3 and referential example 2; Fig. 8 is a graph which illustrates changes in chromacity value b* in the outdoor exposure test, and the tests according to the conventional examples 1 and 2; Fig. 9 is a graph which illustrates changes in value b* in the test according to the present invention, the tests according to the conventional example 3, and the referential example 2; Fig. 10A is a metallurgaical microphotograph (200 times) of the surface of the sample before start of the test; and Figs. 10B, 10C and 10D are metallurgical microphotographs (200 times) which illustrates the state of deterioration of the surface of the sample due to the tests according to the conventional example, according to the present invention, and the outdoor exposure test, respectively. Fig. 1 is a schematic view which illustrates an embodiment of an apparatus for conducting weather resistance tests according to the present invention. A light source 1 comprises a metal halide lamp exhibiting considerably great energy in the wavelength range for example, from 300 to 450nm, a filter for restricting the wavelength region to 300 to 450 nm, a water cooling jacket, and so on. This light source 1 is accommodated in a reflecting plate comprising a dome-shaped main reflecting plate 2 for parallel beams and a sub-reflecting plate 3 for parallel beams. A shield plate 4 is made of quartz glass through which ultraviolet rays can pass and which is capable of separating the sample chamber 5 from the light source portion. A sample holder 7 to which a sample 6 is attached is disposed in the sample chamber 5, and a temperature adjusting means (omitted from illustration), such as a water cooling means or thermoelectric cooling means is also provided for this sample holder 7. An air blowing nozzle 8 maintains the temperature of the sample at a predetermined value by blowing air at a predetermined temperature onto the sample 6 attached to the sample holder 7. A humidifying tank 9 humidifies the sample chamber 5 in which a heater 10 for heating the humidifying tank 9 is provided. Spray nozzles 11a and 11b are for spraying a cleaning agent on to the sample 6 attached to the sample holder 7. Water, a surface active agent, water containing air, alcohol or the like can be employed as a cleansing fluid to serve as the cleaning agent. The sample holder 7 is disposed such that it is inclined by, for example at 15°, for the purpose of preventing stagnancy of sprayed cleaning agent and of making the sprayed cleansing fluid flow downwards. Also the light source portion 1 is inclined and is attached to the sample chamber 5. The sample chamber 5 is further provided with a temperature detector and so on (omitted from illustration). Pipes 12 are arranged to be connected to the spray nozzles 11a and 11b. An electromagnetic valve 13 controls the delivery of cleansing fluid supplied to a cleansing supply port. A control device 15 controls the light source 1, the air blowing nozzle 8, the heater 10 in the humidifying tank 9, the electromagnetic valve 13, and the temperature adjusting means provided for the sample holder 7 in accordance with a predetermined process. In the thus-structured apparatus for conducting weather resistance tests, the sample 6 is placed on the sample holder 7, the light source 1 is turned on and the sample is first subjected to ultraviolet radiation for a predetermined time, for example, for 4 hours. In this case, the temperature of the sample 6 is maintained at a predetermined value (40° to 100°C ± 1.0°C) by air injected by the blowing nozzle 8 in response to a detection signal supplied from the temperature detector (omitted from the illustration). When the application of ultraviolet radiation is stopped by turning off the action of the light source 1, the temperature of the sample holder 7 is lowered by the temperature adjusting means (omitted from illustration) provided for the sample holder 7 to a value below its dew point in response to the detection signal supplied from the temperature detector. Furthermore, steam is generated by heating the humidifying tank 9 as to humidify the sample chamber 5 to a predetermined humidity. As a result, dew condenses on the surface of the sample 6 held by the sample holder 7. After the continuation of this dew condensation state for a predetermined period of time, for example, substantially one hour, the electromagnetic valve 13 is actuated by a control signal supplied from the control device 15, and the spray nozzles 11a and 11b are operated to inject the cleansing fluid on to the sample 6. As a result, dew condensed on the surface of the sample is removed and this sample itself is washed. Next, the light source 1 is again turned on so that the sample 6 is again subjected to ultraviolet radiation. Then, the above-described process is repeated. By conducting the weather resistance test in the manner as described above, the conditions which significantly simulate the dew condensation state at night in the outdoor exposure state can be made for the sample. In addition, the generation of the spot pattern on the surface of the sample and the excessive change in colour of the surface of the sample can be prevented. As a result, the results of weather resistance tests which can significantly simulate the natural deterioration can be obtained in a significantly short time period. In the above-described embodiment, although the washing process is added between the dew condensation process and the ensuing ultraviolet irradiation process, it may be further added after the application of ultraviolet radiation but before the ensuing next dew condensation process. In this case, a further significant effect in prevention of generation of the spot pattern and in prevention of the significant colour change can be obtained. In addition, this washing process may be effectively added in the dew condensation process. In the above-described embodiment, although two spray nozzles for injecting the cleaner are provided on the right and left hand sides above the sample, the number and the positions of the spray nozzles are not so limited. The number and distribution of the nozzles may be optionally determined on the basis of the shape, size or the like of the sample holder. As the means for cleaning the sample, a means arranged to spray the surface of the sample with hot steam can be employed. Alternately, an ultrasonic washer may also be used. Then, the results of tests conducted simultaneously with weather resistance tests according to the conventional test method will be described for the purpose of confirming the effects of the method of conducting weather resistance tests according to the present invention. (1) Test conditions according to the present invention: light source used: metal halide lamp 4 kW; irradiation wavelength: 300 to 450 nm; temperature of the black panel (when ultraviolet rays are applied): 63°C ± 3°C; intensity of ultraviolet radiation on the surface of the sample: 100 ± 5mW per 100 mm²; humidity in the sample chamber at the time of dew condensation: 95% or higher; temperature of the sample at the time of dew condensation: 30°C; application of ultraviolet radiation and dew condensation cycle: ultraviolet radiation is applied for 4 hours, dew condensation for 1 hour; washing period: 30 seconds after the application of ultraviolet radiation and 30 seconds after the dew condensation; cleaning agent: ion exchange water; temperature of the cleaning agent: 20°C; quantity of the cleaning agent to be sprayed: 9 ml per 100 mm² of the surface of the sample; pressure of the cleaner injected: 1.47 bar (1.5 kg/cm²). (2) Test conditions for conventional example 1 (sunshine weather-meter) light source used: sunshine carbon arc lamp; irradiation wavelength: 280 to 1400 nm; temperature of the black panel: 63 ± 3°C; intensity of ultraviolet radiation at the surface of the sample: 5 mW per 100 mm². (3) Test conditions for conventional example 2 (xenon weather-meter) light source used: zenon arc lamp 3.5 kW; irradiation wavelength: 300 to 1400 nm; temperature of the black panel: 63 ± 3°C; intensity of ultraviolet radiation on the surface of the sample: 2.3 mW per 100 mm². (4) Test conditions for conventional example 3 (only dew condensation process is added, but no washing process is added) light source used, application of ultraviolet radiation and the dew condensation cycle are the same as those for the test according to the present invention (5) Test conditions for reference example 1 (outdoor exposure) time period: 12 months from May 1987 to April 1988; location: Matsudo city, Chiba prefecture, Japan. (6) Test conditions for reference example 2 (a process for water is added after the ultraviolet ray irradiation process) light source used: metal halide lamp 4 kW; irradiation wavelengh: 300 to 450 nm; temperature of the black panel: 63°C ± 3°C; intensity of ultraviolet radiation on the surface of the sample: 100 ± 5mW per 100 mm²; temperature of the liquid in which the sample is dipped: 24°C; application of ultraviolet radiation and dipping cycle: application for 4 hours, dipping for 1 hour; As the sample, hard vinyl chloride prepared under the following conditions was used. Conditions for preparing the sample (a) Composition (unit: PHR) (b) Moulding conditions Powder mixed in accordance with the above-described composition manner was kneaded in a heat roll at 160 to 170°C for 5 minutes. The thus obtained raw sheet was pressed at 190 to 195°C for 10 minutes. After the thus-obtained pressed sheet had been cooled down, the same was made into a sheet substantially 1.0 mm thick to serve as samples. The samples thus-prepared were subjected to each of the tests under the above-described test conditions so that results of the following factor were tested: 60°-gloss retention rate (this is a factor for measuring change in the reflectance of the surface of the sample); value L* (this is a factor for measuring change in the lightness of the surface of the sample), value b* (this is a factor for measuring change in the chromaticity in the direction from yellow to blue on the surface of the sample), and colour difference ΔE* (this is a factor for measuring change in the hue on the surface of the sample) in accordance with CIE1976L*, a*, b* space colorimetric system. The results thus obtained are shown in Figs. 2 to 9, and states of generation of spot patterns on the surface of the sample are shown by microphotographs in Figs. 10A to 10D. Curve a shown in Fig. 2 illustrates change in the gloss retention rate in the outdoor exposure test. As is shown, it is rapidly lowered to 20% in 8 months from the start of the test, whereafter it does not display any further significant change. On the other hand, with the sunshine weather-meter (conventional example 1), a tendency similar to that of the outdoor exposure test is displayed as designated by curve b shown in Fig. 3. With the zenon weather-meter (conventional example 2), a substantially straight change is displayed as designated by curve c in the same drawing. It is apparent that it takes 600 to 800 hours for both of the above-described tests to have the gloss retention rate lowered to 20%. On the other hand, in the case of the conventional example 3 in which only the dew condensation process is added, the gloss retention rate does not display any significant change after it has been lowered to 50% in a relatively short time of substantially 20 hours after the start of the test as designated by curve d shown in Fig. 4. However, with the method according to the present invention, the retention rate is lowered to 20% prior to lapse of test time period of 50 hours as designated by curve e shown in the same figure. As is shown, with the method according to the present invention, it takes only substantially one tenth or less of time taken in the conventional examples 1 and 2 for the gloss retention rate of the sample to experience the degree of deterioration which simulates the degree of deterioration realized by 8 months of outdoor exposure. In the referential example 2 in which the water dipping proces is additionally provided, although the tendency of lowering of the gloss retention rate during the test is different, a deterioration results similar to the deterioration results realized by the present invention can be obtained as designated by curve f shown in Fig. 4. Then, as for colour difference ΔE*, as designated by curve a shown in Fig. 5, it rises substantially linearly in the outdoor exposure case, and the value ΔE* reaches 20 after 12 months have elapsed. Then, it tends to rise rapidly. However, with the conventional examples 1 and 2, even if the testing period reaches 1000 hours, the value ΔE* does not reach 10 since a saturated state is realized as denoted by curves b and c . On the other hand, with the conventional example 3, although value ΔE* reaches 20 or more in a relatively short time (substantially 30 hours) as designated by curve d shown in Fig. 6, it is then brought to a saturated or asymtotic state. Value ΔE* according to the present invention reaches, as designated by curve e shown in this drawing, substantially 15 in 50 hours, and then this curve rises rapidly, displaying a similar tendency to the curve according to the outdoor exposure test. As for referential example 2, value ΔE* reaches, as designated by curve f shown in this figure, substantially 10 at most. Then the results of measurement of lightners value L* are shown in Figs. 7A, 7B, and 7C. Curve a shown in Fig. 7A illustrates change of value L* in the outdoor exposure test, wherein it gradually rises in accordance with time lapse, and value L* reaches 70 in 12 months. On the other hand, as designated by curves b and c shown in Fig. 7B, although value L* does not display a significant change in accordance with testing time lapse in the conventional examples 1 and 2, it is slightly lowered. As is shown, the completely different tendency from the results obtained in the outdoor exposure test is displayed. On the other hand, as designated by curve d shown in Fig. 7C, value L* displays a gradual decrease tendency in the conventional example 3. Although value L* according to the present invention is temporarily lowered in accordance with time lapse as designated by curve e in this drawing, it again rises, and, as is shown, it reaches a deterioration state similar to the same after 12 months of the outdoor exposure in a significantly shorter time period of 50 hours. The referential example 2 displays, similarly to the conventional examples 1 and 2, a tendency in which there is no significant change. Then, the results of measurement of chromaticity value b* will be described. As designated by curve a shown in Fig. 8, value b* shows negative values (blue) at first. Then, it temporarily changes to a value in the vicinity of zero, and shows a tendency towards greater negative values. On the other hand, as designated by curves b and c , value b* is changed to the positive values (yellow) in both the conventional examples 1 and 2. As is shown, a tendency in which the degree of colour change to yellow on the surface of the sample is raised in accordance with time lapse. On the other hand, as designated by curve d shown in Fig. 9, value b* is changed to an extremely large positive value in a short time in accordance with the conventional example 3. Value b* obtained by the method according to the present invention is, as designated by curve e shown in this figure, changed temporarily to positive values which display colour change to yellow. However, it again returns to negative vlues after 50 hours have elapsed. As is shown, a similar tendency to that of the outdoor exposure is displayed. Referential example 2 shows a tendency, as designated by curve f of this figure, in which value b* is changed, in a short time, to positive values, and then it comes closer to zero. Fig.10A is, as described above, a 200 times metallurgical microphotograph of the surface of the sample which has not been subjected to the test as yet. Fig.10B is a 200 times metallurgical microphotograph of the surface of the sample which has been subjected to the weather resistance test according to the conventional example 3 for 50 hours. Fig.10C is a 200 times metallurgical microphotograph of the surface of the sample which has been subjected to the weather resistance test according to the present invention. Fig.10D is a 200 times metallurgical microphotograph of the surface of the sample after it has been subjected to the outdoor exposure test for 12 months. Although a spot pattern is formed on the surface of the sample, according to the conventional example 3, such spot pattern is avoided on the surface of the sample according to the present invention. As is shown, a similar surface of the sample to that according to the outdoor exposure is obtained. As can be clearly seen from data of results of each of the tests, when the weather resistance test is performed in accordance with the method of the present invention, a deterioration state which simulates extremely closely to that obtained by the outdoor exposure test which takes a long time can be realized in a short time. Therefore, a fact that a satisfactorily correlative test results to the natural deterioration can be obtained is confirmed. Although the material of the sample used in the tests in accordance with each of the above-described test methods comprises a hard vinyl chloride plate, substantially the same results were obtained by both the test method according to the present invention and the test method according to the conventional example 3 even if a soft vinyl chloride plate or a plate to which is applied an acrylic paint is used as the sample. Consequently, the method of performing weather resistance tests according to the present invention displays an advantage that generation of spot patterns and excessive colour change on the surface of the sample can be avoided. In the above-described embodiments, although a metal halide lamp with an irradiation wavelength of 300 to 450 nm and with an intensity of ultraviolet radiation of 100 ± 5 mW applied to the surface of the sample is used as the artificial light source, an artificial light source capable of radiating light including ultraviolet radiation of the same intensity as that of the metal halide lamp and including visible radiation and/or infrared radiation may be used. A similar effect can be obtained even if the above-described light source of the second type is used.

Claims: A method of conducting a weather resistance test in which a sample is irradiated with ultraviolet light from an artificial light source, dew is then condensed onto the surface of said sample, and the sample is then again irradiated with ultraviolet light, characterized in that the surface of said sample is washed with a cleaning agent at least after condensing dew on to said surface of said sample and before again irradiating the sample with ultraviolet light. A method according to claim 1, wherein the surface of the sample is also washed after irradiating the sample with ultraviolet light but before condensing dew on to the surface of the sample. A method according to claim 1 or 2, wherein the surface of the sample is washed during condensing dew. A method according to claim 1, 2 or 3, wherein the surface of the sample is washed by spraying the cleaning agent from spray nozzles on to said surface of said sample. An apparatus for conducting weather resistance tests comprising a holder (7) for holding a sample (6); a device (1) for subjecting said sample (6) to ultraviolet radiation; and a device (9) for condensing dew on to the surface of said sample (6); characterised by a device (11a, 11b) for washing said surface of said sample (6) with a cleaning agent; and a controller (15) for controlling the operation of the washing device (11a, 11b) as well as the irradiating device (1) and the dew-forming device (9). An apparatus according to claim 5, wherein said irradiating device (1) comprises a metal halide lamp displaying great energy in a wavelength region from 300 to 450 nm and a filter for restricting said wavelength region to substantially 300 to 450 nm. An apparatus according to claim 5 or 6, wherein said holder (7) is designed to be inclined with respect to a horizontal plane. An apparatus according to claim 5, 6 or 7, in which said controller (15) also controls said holder (7). An apparatus according to any of claims 5 to 8, wherein said washing device comprises spray nozzles (11a, 11b) disposed to oppose said holder (7).

Inventors: GOTO, HITOSHI C/O DEVELOPING CENTER, IWANAGA, TERUO C/O DEVELOPING CENTER, KISHIMA, YOSHIO C/O DAINIPPON PLASTICS CO., LTD.
Applicants: DAINIPPON PLASTICS CO., LTD., IWASAKI ELECTRIC CO., LTD.
Application year: 1989
Main classification: G01N17
IPC codes: G01N17