A preparation method of selective growth silicon layer doped with impurities

Abstract: A semiconductor substrate (31) having a surface region of P type and a surface region of N type is formed, then an insulating membrane is formed on the semiconductor substrate (31). The first contact hole which is formed in said region of P type and the second contact hole which is connected to said region of n type are formed by the same process to said insulating membrane. Non-doped silicon layer is grown in said first and second contact holes (35) by the same selec­ tive growth process, in a single reactive furnace. A diffuse source layer (37) containing impurities of P type is formed on said first contact hole and a diffuse source layer containing impurities of N type on said second contact hole. Impurities are diffused from said diffuse layers (37, 38) to said silicon layers (36), and said diffuse source layer is then removed. A metal wire layer is formed by connecting it to said silicon layer.

Description: This invention relates to a method of manufacturing a semiconductor device, specifically a doping method of doping impurities into a selective growth silicon layer. A selective growth process is utilized as an effective process for separating fine elements and for manufacturing a contact filling (including, for example, a self-aligning contact). A conventional example utilizing a selective growth process applied to the contact filling technique is described in reference to Fig. 1. An insulating layer 2 having an opening is formed on semiconductor substrate 1. The resultant structure is provided on a susceptor 5 in a reactive furnace 4 (a reactive chamber) for epitaxial growth. For example, by utilizing H₂ as a carrier gas and silicon chloride or hydrogenated silicon as a material gas, and adding HCℓ gas and doping gas (gaseous compounds containing impurity atoms in reactive gas), a gas growth process is conducted under reduced pressure. Consequently, silicon layer 3 containing impurities is grown in said opening. In said conventional method, the impurity atoms adhere to the inner surfaces of the reactive furnace 4 and the susceptor 5 during the growth of silicon layer 3. The adhered impurity atoms float again in the next selective growth process, and contaminate the next growing silicon layer. Therefore, in order to selectively grow a silicon layer containing P type impurities and a silicon layer containing N type impurities, both a reactive furnace for P type and for N type impurities are needed, which doubles facility costs. Therefore, a technique is desired, to obtain selective growth silicon layers doped with P type impurities and those doped with N type impurities, by utilizing a single reactive furnace for epitaxial growth. Although a technique is produced to dope impurities in a selective growth silicon layer by implanting ions therein, this technique adversely suffers from the reciprocal relation that a large implantation dose cannot result in a deep implantation, while a deep implantation cannot result in a large implantation dose. As a result it is very difficult to obtain a selective growth silicon layer, whose impurity concentration and depth are both large, by utilizing an ion implantation process. US-A- 4 714 686 concerns a contact according to the pre-characterising portions of independent claims 1 and 4. The object of the present invention is to provide a method for manufacturing semiconductor devices in which both of P type selective growth silicon layers and N type selective growth silicon layers can be formed, by means of a single reactive furnace for a selective growth. In order to attain the above object, a method for forming semiconductor devices has steps of: preparing a semiconductor substrate (31) having a region of a first conductivity type and a region of a second conductivity type; forming an insulating film on the semiconductor substrate (31); forming the first opening and the second opening in the insulating membrane, the first opening being connected to the region of the first conductivity type, and the second opening being connected to the region of the second conductivity type, and the first and second openings being substantially formed by the same process; selectively growing the first semiconductor layer in the first openings (35) and the second semiconductor layer in the second openings (35), the first semiconductor layer and the second semiconductor layer being substantially formed by the same process; forming the first diffusion source layer (37) of the first conductivity type on said first semiconductor layer, and the second diffusion source layer (38) containing impurities of the second conductivity type on said second semiconductor layer; diffusing impurities in the first semiconductor layer (36) and the second semiconductor layer (36) by utilizing the first and second diffuse source layers (37, 38) as solid diffusion sources; and removing the first and said second diffuse source layers (37, 38). According to the above-identified method, although the final conductivity types of said first semiconductor layer and said second semiconductor layer are different from each other, only a single reactive furnace for selective growth is require. Process costs is accordingly reduced and, since the formation of contact holes which require high mask alignment accuracy is conducted in only one process, for example, the total process is simplified. Although formation of said semiconductor layer which is at least 0.4 µm in thickness and at least 10²⁰ cm⁻³ in its impurity concentration is conventionally difficult, it is easily obtained in the present invention. Therefore, this invention is particularly useful when both P type and N type selective growth semiconductor layers are formed which are at least 0.4 µm in thickness and at least 10²⁰ cm⁻³ in their impurity concentration. This invention can be more fully understood from the following detailed description when taken in conjunction with the accompanying drawings, in which: Fig. 1 is a sectional view showing a conventional process for forming a contact filling; Figs. 2A-2D are sectional views showing contact filling formation processes according to the first and second embodiments of the present invention; Fig. 3 is a sectional view showing a modified example of said first and second embodiments of the present invention; and Figs. 4A and 4B are sectional views showing a process for forming CMOS transistor of the third embodiment of the present invention. Descriptions of the first and second embodiments are as follows with reference to Figs. 2A-2D. The first embodiment shows formation of a selective growth silicon layer doped with N type impurities, and the second embodiment shows formation of a selective growth silicon layer doped with P type impurities. The first embodiment: P type silicon substrate (100) 11 whose specific resistance is for example 10 Ωcm is prepared. As ions are implanted into the substrate 11 to form diffusion layer 12 of N type whose impurity concentration is about 1 × 10²⁰ cm⁻³, SiO₂ layer 13 of 600 nm in thickness is formed by steam oxidation for 3 hours. Next, opening 14 is formed in the SiO₂ layer by means of the usual photoetching process (PEP). As a result, such a construction is formed as shown in Fig. 2A. A construction of Fig. 2A is mounted on susceptor 16 in the reactive furnace (reactive chamber) for an epitaxial growth. By utilizing SiH₂Cℓ₂ + HCℓ + H₂ gas and in an atmosphere of about 100 torr (1 torr = 133.3 Pa), non-doped silicon selective growth is conducted at 900°C. Consequently as shown in Fig. 2B, a non-doped silicon layer 17 (single-crystal silicon and/or polysilicon) of about 600 nm in thickness is formed in the opening 14. As shown in Fig. 2C, PSG layer 18 which contains N type impurities of about 5 × 10²⁰ ∼ 1 × 10²¹ cm⁻³ is formed on the silicon layer 17. The resultant structure is heated in an O₂ atmosphere at 900°C for 30 minutes, and N type impurities are diffused from the PSG layer 18 into the silicon layer 17. At the same time, impurities are also diffused from the impurity layer 12 into the selective growth silicon layer 17 so that, consequently, selective growth silicon layer 17 doped with N type impurities is formed. Next, PSG layer 18 is removed to form aluminum wiring 20. As a result, a contact filling is formed by utilizing selective growth silicon layer 17 doped with N type impurities. The second embodiment: N type silicon substrate (100) 11 whose specific resistance is 10 Ωm is formed. P type diffusion layer 12 is formed on the surface of the N type silicon substrate 11 by implanting BF₂ ions in the substrate 11, then steam oxidation is conducted for 3 hours to form SiO₂ layer 13, of 600 nm thickness, and the photoetching process is implemented to form opening 14 therein. Next, non-doped silicon layer is selectively grown at 900°C by utilizing SiH₂Cℓ₂ + HCℓ + H₂ gas. Consequently, non-doped silicon layer 17 of about 600 nm thickness is formed in the opening 14 as shown in Fig. 2B. As shown in Fig. 2C, BSG layer 18 is formed in the non-doped silicon layer 17. The resultant structure is heated in an O₂ atmosphere at 900°C for 30 minutes to diffuse P type impurities from the BSG layer 18 into the non-doped silicon layer 17. At the same time, P type impurities are also diffused from the impurity layer 12 into the silicon layer 17. Therefore, selective growth silicon layer 17 doped with P type impurities is formed. The BSG layer 18 is removed to form aluminium wiring 20. As a result, a contact-hole filling is formed by utilizing selective growth silicon layer 17 doped with N type impurities as shown in Fig. 2D. According to said method for doping impurities into a selective growth silicon layer, only one reactive furnace for epitaxial growth is needed, irrespective of the type of final requisite silicon layer, i.e., P type, N type or non-doped. Moreover, since the depth of the PSG layer or BSG layer 18 and the impurity concentration contained therein can be arbitrarily set, this invention can be applied to a silicon layer 17 which has both a high impurity concentration and substantial depth. Also, since the selective growth gas includes no doping gas, the silicon layer growth shows stability and good reproductivity. (When the amount of doping gas is large, the selectivity of silicon growth decreases, of so, a silicon layer may be deposited on the SiO₂ layer 13, and the reproductivity of the growth rate decreases, which eventually leads to serviceability deterioration.) In said first and second embodiments, impurities are doped into the selective growth silicon layer 17 in an O₂ atmosphere at 900°C for 30 minutes. However, as shown in Fig. 3, boundaries between the layer 17 and the layer 18 and its peripheral area (an area surrounded with broken lines in Fig. 3) may be irradiated by light, e.g. laser light L within 10 minutes, for example, for 2 minutes and partly heated at 800-1200°C, to form diffuse impurities in the silicon layer 17 (rapid anneal). In order to confirm effects obtained from the methods with reference to said first and second embodiments, semiconductor devices of the same construction were respectively produced according to said first embodiment, second embodiment, first conventional example, and second conventional example both of which are described as follows, and their features are verified. The features verified are contact characteristics between silicon layer 17 and Aℓ wiring 20, and impurity concentration distribution in selective growth silicon layer 17, assayed by secondary ion mass spectrometric analysis. The first conventional example: Instead of post selective growth processes according to said first embodiment, P doping selective growth is conducted by utilizing SiH₂Cℓ₂ + HCℓ + PH₃ + H₂ gas. Si layer 17 is then formed, and Aℓ wire 20 is formed. The second conventional example: Instead of post selective growth processes according to said second conventional embodiment, SiH₂Cℓ₂ + HCℓ + B₂H₆ + H₂ gas is utilized to give N dope selective growth. Si layer 17 is then formed, and Aℓ wire 20 is formed. As a result of comparison, contact characteristics between silicon layer 17 and aluminium wiring layer 20 were found to be almost equal in both the embodiments and conventional examples. Also, it was found that both the embodiments and conventional examples can realize about 1 × 10²⁰ cm⁻³ (peak value). Therefore, contact filling having sufficiently good characteristics can be obtained from both the conventional examples and the embodiments, with the exception that the selective silicon layer growth is heavily unstable and reproductivity is poor in the conventional examples. For example, since silicon is deposited on SiO₂ layer 13 in some cases, and the growth rate is different for each deposition sequence, the yield of the selective growth silicon layer is low. In conclusion, conventional examples are not practical. Moreover, since the first and second conventional examples implement doping of impurities during selective growth, two reactive furnaces are needed for both P type and N type impurities, while embodiments of the present invention necessitate only a single reactive furnace for selective growth. Although the embodiments need several processes after selective growth, introduction of only a single reactive furnace reduces conventional process costs to about less than 60%. Moreover, in the semiconductor device obtained by the first and second conventional methods, impurities are diffused from the selective growth silicon layer 17 to the substrate 11 through the diffusion layer 12 during the growth of silicon layer 17. Therefore, a shallow junction is difficult to obtain. By contrast, in said first and second embodiments, the impurities of the non-doped or low-concentration doped selective growth silicon layer 17 do not diffuse into the substrate 11, resulting in a shallow junction. In the embodiments which utilize rapid anneal, a shallow junction, whose depth is at least 70% of that in the conventional examples is obtained. Next, the third embodiment is described with reference to Fig. 4A and Fig. 4B. P channel MOS transistor 32 is formed on N type substrate 31, and N channel MOS transistor 34 is formed in P type well 33 which is formed on the substrate 31. Contact holes 35 are formed on source regions and drain regions, thus forming the construction shown in Fig. 4A. The resultant structure is mounted in a reactive furnace, and silicon layers 36 are selectively grown in all contact holes 35. On the P channel MOS transistor, BSG layer 37 is formed containing P type impurities. On the N channel MOS transistor, PSG layer 38 containing N type impurities is formed by a process which is different from that for BSG layer 37. Boundaries between the silicon layer 36 and the BSG layer 37 and between the silicon layer 36 and the PSG layer 38 and those peripheral regions, are irradiated with laser light L and partly heated. Referring to the result as shown in Fig. 4B, broken lines typically indicate that impurities are diffused into the silicon layer 36 not only from the BSG layer 37 and the PSG layer 38, but also from the source regions and the drain regions. Next, BSG layer 37 and PSG layer 38 are removed, followed by formation of metal (e.g., aluminium) wiring which is connected to the silicon layer 36. In this manufacturing method of a CMOS semiconductor, formation of selective growth silicon layer 36 needs only a single reactive furnace for selective growth. As stated above, manufacture costs can be duly reduced. In this manufacturing method of a CMOS transistor, additional processes are needed to form layers 37 and 38 in comparison with the conventional preparation method of a CMOS transistor. However, formation of layers 37 and 38 allows relatively rough mask alignment, for example, a mask alignment accuracy of about 1 µm is sufficient, in contrast to the formation of 1.0 µm contact holes, which necessitate highest mask alignment accuracy in manufacturing a transistor, for example, mask alignment of about 0.2 µm accuracy is needed. This embodiment allows formation of all contact holes by means of only one mask alignment process, and the total processes can be accordingly simplified, in comparison with a conventional preparation method of a CMOS transistor which necessitates two mask alignment processes, one for formation of the contact holes for P type silicon layer, and another for formation of the contact holes for N type silicon layer. In a procedure of selectively growing a silicon layer under the condition that the silicon layer is doped, insitu, with impurity concentration of more than 10²⁰ cm⁻³, the concentration of doping gas must increase, and the growth condition such as selectivity become less stable. Therefore, silicon is adversely deposited not only in the inner area of openings (contact holes), but also in other regions, for example, on an insulating membrane, which leads to deteriorated stability and reproductivity. Contrarily, since a silicon layer of non-doping or of low doping is formed in the present invention, stability and good reproductivity are obtained. The present invention is thus eminently useful for formation of a selective growth silicon layer containing impurities of more than 10²⁰ cm⁻³ concentration. Moreover, ion implantation in a non-doped selective growth silicon layer shows a reciprocal relation between implantation dose and implantation depth, and it is therefore difficult to form a layer containing impurities of more than 10²⁰ cm⁻³ such that the layer has a constant depth. For example, an implantation dose of about 1 × 10¹⁵ - 1 × 10¹⁶cm⁻² is needed to obtain an impurity concentration of about 10²⁰ cm⁻³ by means of ion implantation. To ensure the implantation dose, accelerated voltage must usually be about 60 keV or less. If the accelerated voltage is about 60 keV, Rp of implantation depth is at most 0.2 µm, depending on the atom species implanted. Therefore, the doping silicon layer which is formed by ion implantation is at most 0.4 µm in depth, even if it is considered that the ion implanted is diffused by heating after ion implantation, and that impurities in the semiconductor substrate are diffused into the selective growth silicon layer. The present invention sets no restrictions in implanted impurity concentration and silicon layer depth. From the above considerations, this invention is found to be eminently effective for the formation of the selective growth silicon layer which is more than 0.4 µm in depth, is more than 10²⁰ cm⁻³ in impurity concentration, and is doped with both P type and N type impurities. Although said descriptions of the embodiments show selective growth of a silicon layer, this invention is not restricted to silicon and can be applied to, for example, selective growth of a chemical semiconductor, such as GaAs. Although said descriptions of the embodiments show selective growth of silicon layers 17 and 36 of non-doping, this invention is not restricted to this non-doped selective growth and can be applied to formation of a selective growth silicon layer doped with impurities of relatively low concentration, for example, under 1 × 10¹⁸ cm⁻³, followed by doping of high concentration utilizing, for example, a diffuse source as described in the embodiments. The material of the diffusion source is not limited to the SiO₂ layer. It can be amorphous silicon layer, poly-silicon, or silicon nitride.

Claims: A method of forming a CMOS transistor contact filling comprising steps of preparing a semiconductor substrate (31) of a first conductivity type; forming a source region of a second conductivity type and a drain region of the second conductivity type of a MOS transistor (32) of the second conductivity type in said semiconductor substrate (31), and forming a source region of the first conductivity type and a drain region of the first conductivity type of a MOS transistor (34) of the first conductivity type in a well region (33) of the second conductivity type of said semiconductor substrate (31), forming an insulating layer on said semiconductor substrate, forming contact holes (35) with a first positioning accuracy wherein each contact hole (35) is connected to a corresponding source region or drain region; by substantially the same process in said insulating layer, characterized by selectively growing non-doped silicon layers (36) of at least 0.4 µm depth, as electrodes in said contact holes (35); forming a first diffusion source layer (38) containing impurities of the first conductivity type above said MOS transistor (34) of the first conductivity type with a lower positioning accuracy than said first positioning accuracy, such that the first diffusion source layer (38) is connected to said silicon layers (36), and forming a second diffusion source layer (37) containing impurities of the second conductivity type above said MOS transistor (32) of the second conductivity type with a lower positioning accuracy than said first positioning accuracy, such that the second diffusion source layer (37) is connected to said silicon layers (36); diffusing impurities into said silicon layers (36), such that peak impurity concentrations are at least 1 × 10²⁰ cm⁻³, utilizing said first diffusion source layer (38) and said second diffusion source layer (37) as solid diffusion sources; removing said first diffusion source layer (38) and said second diffusion layer (37); and forming metal wire layers which are connected to said silicon layers (36). A method according to claim 1, characterized in that diffusion of impurities is conducted by a rapid anneal at 800°C to 1200°C within 10 minutes from said first and second solid diffusion source layers into said silicon layers. A method according to claim 1, characterized in that said step of selectively growing has a process for forming said silicon layers in a single reactive furnace for selective growth. A method of manufacturing a semiconductor device, characterized by comprising steps of: preparing a semiconductor substrate (31) having a region of the first conductivity type and a region of the second conductivity type; forming an insulating film on said semiconductor substrate (31); forming a first opening and a second opening in said insulating film, said first opening being connected to said region of the first conductivity type, and said second opening being connected to said region of the second conductivity type characterized by selectively growing the first semiconductor layer in said first openings (35) and the second semiconductor layer in said second openings (35), said first semiconductor layer and said second semiconductor layer being formed by substantially the same process; forming the first diffusion source layer (37) of the first conductivity type on said first semiconductor layer and the second diffusion source layer (38) containing impurities of the second conductivity type on said second semiconductor layer; diffusing impurities in said first semiconductor layer (36) and said second semiconductor layer (36) by utilizing said first diffusion source layer (38) and said second diffusion source layer (37) as solid diffusion sources; and removing said first diffusion source layer (38) and said second diffusion source layer (37). A method according to claim 4, characterized in that said step of forming said first opening and said second opening (35) is to form said first opening and said second opening, by substantially the same process; said selective growth step is to form said first semiconductor layer and said second semiconductor layer by substantially the same process; and said step of forming said first and second diffusion source layers (37, 38) is to form said first and second diffusion layers, with less positioning accuracy than that in said step of forming openings. A method according to claim 4, characterized in that said step of forming semiconductor layer is to form said semiconductor layer to a thickness of at least 0.4 µm in thickness by utilizing a selective growth process, and said impurities diffusion step of diffusing impurities into said semiconductor layer (17) is such that the peak impurity concentration is at least 1 × 10²⁰ cm⁻³. A method according to claim 4, characterized in that said growing step is to form said semiconductor layer by selectively growing a non-doped silicon layer (36). A method according to claim 4, characterized in that said growing step is to form said first and second semiconductor layers in a single reactive furnace for a selective growth. A method according to claim 4, characterized in that diffusion of impurities is conducted by a rapid anneal at 800°C to 1200°C within 10 minutes from said first and second solid diffuse source layers into said silicon layers.

Inventors: MATSUSHITA YOSHIAKI INTELLECTU, SAMATA SHUICHI INTELLECTUAL PR, MATSUSHITA, YOSHIAKI INTELLECTUAL PROPERTY DIV., SAMATA, SHUICHI INTELLECTUAL PROPERTY DIV.
Applicants: TOSHIBA KK, KABUSHIKI KAISHA TOSHIBA
Application year: 1989
Main classification: H01L21
IPC codes: H01L21