Microwave ion source

Abstract: Disclosed is a microwave ion source suitable for an apparatus which requires ions of an element of high reactivity such as oxygen, fluorine, etc., the microwave ion source being arranged to transmit a microwave (21) through a coaxial line (2). According to the present inven­ tion, an ion extraction electrode (13) is formed of a low magnetic permeability material while an accelera­ tion electrode (11) is formed of a high magnetic permeability material. However, the acceleration electrode (11) is not wholly formed of a high magnetic permeability material but it has a structure in which a low magnetic permeability material of a certain thickness is stacked on the high magnetic permeability material at a plasma chamber (7) side and openings (12a) of ion exit holes (12) are formed in the portion of the low magnetic permeability material. A permanent magnet (9) constituting a magnetic field generating means is provided to surround the microwave lead-in coaxial line (2). The direction of magnetiza­ tion of the permanent magnet (9) is made to coincide with the axial direction of the coaxial line (2). The end surface of the permanent magnet (9) at the microwave lead-in side is coupled with the periphery of the high magnetic permeability material of the acceleration electrode through another high magnetic permeability material to form a magnetic path. The plasma chamber (7) is formed of a dielectric insulator which may well transmit the microwave (21). The permanent magnet (9) is provided above the plasma chamber (7) and the coaxial line (2) is arranged so as to project into the plasma chamber (7). In such a configuration, it is possible to realize an ion source in which ions can be extracted with a high electric field and high current ion beam can be extracted for a long time.

Description: BACKGROUND OF THE INVENTION The present invention relates to an ion working machine for performing ion implantation, ion beam sputtering, surface reforming with ions, and so on, and particularly relates to a microwave ion source suitable for use in an apparatus which requires ions of an element of high reactivity such as oxygen, fluorine, etc. Conventionally, there have been three kinds of methods for transmitting microwave energy as follows: (1) Transmission through a rectangular waveguide; (2) Transmission through a hollow cylindrical waveguide; and (3) Transmission through between outer and inner conductors of a coaxial cable. The above method (3) using a coaxial waveguide has been widely used because of its various advantages as follows: (a) The microwave energy can be guided even if a microwave ion source is made small in size; (b) The microwave ion source can be made small in size with the impedance unchanged; and (c) Such a coaxial cable as generally sold can be used as the coaxial waveguide. In such a conventional microwave ion source having a coaxial structure as disclosed in JP-A-59-96632, US-A-4 393 333, EP-A-0 209 469 and Patent Abstracts of Japan, Vol. 10, No. 104 (E-397) [2161], 19 April 1986, JP-A-60 243 955, a permanent magnet for generating a magnetic field is arranged to surround a plasma chamber (discharge chamber) and a coaxial line for supplying the plasma chamber with microwave energy is exposed or projected (US-A4 393 333, EP-A0 209 469) in the plasma chamber. R.N. Hall describes in his article "High frequency proton source" (The Review of Scientific Instruments, Vol. 19, No. 12, December 1948, pages 905 to 910) a microwave ion source where the magnetic generation means comprises a solenoid. FR-A-2 147 497 also discloses an ion source using a metallic cavity and an iron header plate for composing the acceleration electrode. Accordingly, some of the above prior art embodiments have problems in the three points as follows. 1) Since there exists an intensive magnetic field of an order of 0.1 T in the space exerted with an electric field between an acceleration electrode and a deceleration electrode (ion extraction electrode), it is impossible to make a discharge-resistant voltage accross the acceleration and deceleration electrodes high and therefore this technique is not suitable for large-current extraction. 2) Since a permanent magnet or a solenoid is arranged to surround a plasma chamber, it is difficult to two-dimensionally enlarge the plasma chamber in its section. 3) Since a microwave coaxial line is exposed in a plasma chamber, metal elements such as copper, titanium etc., sputter from the coaxial line mix in the plasma chamber to thereby lower the purity of the plasma. Further, the metal elements may attach onto the surface of a dielectric insulator interposed between the inner and outer conductors of the coaxial line to thereby make it impossible to supply the plasma chamber with a microwave. SUMMARY OF THE INVENTION It is therefore an object of the present invention to realize a microwave ion source in which ion extraction with a high electric field can be performed and a large current ion beam can be extracted. It is another object of the present invention to realize a large area plasma chamber having a desirable extension in the horizontal direction. The above objects can be achieved by the means of a microwave ion source comprising a microwave source; a coaxial line for supplying a microwave from said microwave source into a plasma chamber; sample gas lead-in hole means for leading in a sample gas so as to generate plasma; a permanent magnet means for generating a magnetic field in said plasma chamber; and an acceleration electrode, a deceleration electrode and an earth electrode for exerting an ion extraction electric field to plasma generated by microwave discharge in said plasma chamber, characterized in that there are provided one microwave source and one acceleration electrode, respectively, and in said microwave source there are provided a plurality of coaxial line means connected to said coaxial line for supplying the microwave from said microwave source to said plasma chamber, and that said sample gas lead-in hole means consists of a plurality of sample gas lead-in holes, and that said permanent magnet means consists of a plurality of permanent magnets, and that there is provided a plurality of exit holes, formed in said acceleration electrode, said deceleration electrode and said earth electrode, each of said plurality of sample gas lead-in holes and ion exit holes corresponding to a respective plurality of microwave lead-in sets, each set further including one of said plurality of coaxial line means and a respective said permanent magnet provided around said one coaxial line means of this set; and in that at least a part of said acceleration electrode is composed of a high magnetic permeability member; and in that the end surface of each said permanent magnet at the microwave lead-in side is coupled with the periphery of said high magnetic permeability member through another high magnetic permeability material means to form a magnetic circuit, said high magnetic permeability material means and said high magnetic permeability member both surrounding said plasma chamber and all said permanent magnets, said high magnetic permeability member being adapted to absorb the magnetic fields generated by said permanent magnets in said plasma chamber. As the acceleration electrode formed of a high magnetic permeability material absorbs the great part of a magnetic field of an order of 0.1 T generated in the plasma chamber to thereby reduce leakage of the magnetic field into a space exerted with an ion extraction electric field. Accordingly, the influence of the leaking magnetic field on charged particles in the space of ion extraction can be reduced and the discharge-resistant voltage at this place can be made high. It is possible to form the plasma chamber of a dielectric insulator, the coaxial line member is not exposed to plasma, so that the contamination of plasma with metal elements can be prevented and continuous operation for a long time can be performed. BRIEF DESCRIPTION OF THE DRAWINGS Examples, useful for understanding the present invention, and a preferred embodiment of the present invention will now be described in conjunction with the accompanying drawings, in which: Fig. 1 is a section showing the relationship between the electric field and magnetic field generated in the plasma chamber of the microwave ion source Fig. 2 is a section illustrating a first example of the microwave ion source; Fig. 3 is a detailed section showing the portion of III of Fig. 2; Fig. 4 is a plan viewed in the direction IV - IV in Fig. 3; Fig. 5 is a section illustrating an embodiment of the microwave ion source according to the present invention; Fig. 6 is a section viewed in the direction VI - VI in Fig. 5; Fig. 7 is a section viewed in the direction VII - VII in Fig. 5; and Fig. 8 is a section illustrating a second example of the microwave ion source. DESCRIPTION OF THE PREFERRED EMBODIMENTS Prior to the description of the embodiment of the present invention, the principle of operation of the microwave ion source according to the present invention will be described hereunder. Fig. 1 is a section for explaining the relationship between the electric field and magnetic field generated in the plasma chamber of the microwave ion source according to the present invention. In Fig. 1, an electric field 31 due to a microwave 21 is an alternating field and generated between an inner conductor 5a of a coaxial line projected into a plasma chamber 7 and a coaxial discharge box 6. On the other hand, magnetic force lines 32 due to a magnetic field generating means 9 constituted by a permanent magnet are generated between the magnetic field generating means 9 and a high magnetic permeability material high magnetic permeability material lla of an acceleration electrode 11. Since the acceleration electrode 11 is provided with a low magnetic permeability material 11b at the plasma chamber 7 side, the magnetic force lines 32 can pass through ion exit holes 12 formed in the low magnetic permeability material 11b. In this condition, if there exist electrons in the plasma chamber 7, the electrons are subject to acceleration and deceleration by the microwave electric field while turning so as to twist about the magnetic force lines 32. Such electrons collide with molecules of a sample gas 22 led into the plasma chamber 7 to thereby generate plasma. Although ions in thus generated plasma are subject to interaction between the microwave electric field and the magnetic field generated by the magnetic field generating means 9, the ions cannot follow the change of the alternating electric field of the microwave and moves along the magnetic force lines 32 so as to twist about the magnetic force lines 32. Then, the ions reached the ion exit holes 12 are extracted as an ion beam 23. The reference numerals 8 and 10 designate a dielectric insulator and a magnetic path respectively. As described above, the magnetic field generating means 9 provided above the plasma chamber 7 and the acceleration electrode 11 having a lamination structure of the low magnetic permeability material llb and the high magnetic permeability material lla constitute a configuration which operates as a microwave ion source. Next, referring to Fig. 2, a first example, useful for understanding the present invention, will be described hereunder. The ion source according to the present invention is constituted by a microwave generator 1, a coaxial line or coaxial waveguide 2, another coaxial line constituted by an inner conductor (microwave lead-in portion) 5, a coaxial discharge box 6, a plasma chamber 7, a dielectric insulator 8, a magnetic field generating means constituted by a permanent magnet 9, a magnetic path of a high magnetic permeability material 10, an acceleration electrode 11, a deceleration electrode or ion extraction electrode 13, an earth electrode 14, insulators 15 and 16, and a sample gas lead-in pipe 17. The first example has features as follows. (1) The deceleration electrode 13 is formed of a low magnetic permeability material and the acceleration electrode 11 has a lamination structure of a high magnetic permeability material and a low magnetic permeability material. (2) The permanent magnet 9 arranged so as to surround the coaxial line 5 is cylindrical and magnetized in the axial direction. The permanent magnet 9 has no limit in polarity and either end of thereof may be made to be the N pole. The microwave lead-in side end surface of the permanent magnet 9 is coupled with the high magnetic permeability material of the acceleration electrode 11 through a high magnetic permeability material so as to form the magnetic path 10, so that loss of the magnetic field can be prevented. Thus, the permanent magnet 9 may be reduced in size. (3) The plasma chamber 7 is formed of the di-electric insulator 8. The intensity of the magnetic field in the plasma chamber 7 is controlled so as to be about 0.05 to 0.1 T. In this ion source, a microwave 21 and a sample gas 22 such as BF 3 , Ar, O 2 , N 2 , or the like, are led into the plasma chamber 7 so as to generate plasma and positive and negative voltages are applied to the acceleration electrode 11 and the deceleration electrode 13 respectively, so that the ion beam 23 can be extracted from the plasma. Fig. 3 is a detailed sectional view showing the portion of III around the plasma chamber 7 in Fig. 2, and Fig. 4 is a plan viewed in the direction IV - IV in Fig. 3. In Figs. 3 and 4, ion exit holes 12 are composed of six openings 12a formed on the same circumference so that those six holes are separated from each other. Each of the ion exit holes 12 has a substantially conical shape which is gradually widened from the plasma chamber 7 to the outside in the direction of ion extraction. The acceleration electrode 11 has a structure of lamination of the high magnetic permeability material 11a and the low magnetic permeability material 11b. The thickness h of the low magnetic permeability material 11b is selected to be substantially equal to the diameter d of each of the ion outgoing holes 12 at the plasma chamber 7 side, that is, h ≒ d (equal to about 3 mm). In this first example, it is possible to realize the ion source in which high current ion beam of about 20 mA can be obtained, with a small sized configuration having a diameter of about 100 mm and a length of about 100 mm as shown in Fig. 2 and with a low electric power consumption. Further, as seen in Fig. 4, the ion exit holes 12 are formed at positions displaced from a position E on the extension of the inner conductor of the coaxial line 2. Next, referring to Fig. 5, an embodiment of the present invention will be described hereunder. The ion source of this embodiment is suitable for a case in which a uniform, large-area, and high current ion beam is to be extracted for a long time. A microwave 21 is divided through a coaxial branching line 3 into a plurality of lines of, for example, nine lines of microwaves which are led into a plasma chamber 7 through coaxial cables 4 respectively. The plasma chamber 7 is formed to be a single room. A permanent magnet 9 which is a cylindrical one similarly to that of the first example is disposed on each of the nine microwave lead-in portions in a manner so that the corresponding one of the coaxial cables 4 is passed through the inside of the permanent magnet 9. All the nine permanent magnets 9 are arranged so as to have the same polarity. Fig. 6 shows the relationship between the microwave lead-in positions and the plasma chamber 7. In order to produce plasma at a large area uniformly, the microwave lead-in positions as well as the sample-gas lead-in pipes 17 are arranged symmetrically. Fig. 7 shows the relationship between the ion exit holes 12 and the plasma chamber 7. Each of the ion exit holes 12 has the same structure as that in the first example. The ion exit holes 12 are arranged at regular intervals and grouped into a plurality of sets each including a plurality of, for example, four ion exit holes 12 for every microwave lead-in system. This is a measure to make the characteristics of the ion beams 23 extracted from the respective ion exit holes 12 coincide with each other so as to obtain a uniform and large-area ion beam 23. Thus, according to the second embodiment, it is possible to obtain an ion beam of about 120 mA in total which is large in area and which is uniform in characteristics. Although the permanent magnets 9 are arranged so that all the permanent magnets 9 have the same polarity in Fig. 5, the same effect as the second embodiment can be obtained even in the case where the permanent magnets 9 are arranged so that any adjacent two of those magnets 9 have different polarity so as to make the magnetic field coming out from one permanent magnet comes into permanent magnets adjacent to the one permanent magnet. Although the above second embodiment is intended to obtain a uniform and large-area ion beam, if means for controlling microwave energy to be transmitted to the branched targets, for example, attenuators 24 are additionally provided in the coaxial branching line 3 in the second embodiment, it is made possible to control the distribution of density of the plasma in the plasma chamber 7 to thereby control the distribution of intensity of the large-area ion beam. Further, the same effect can be obtained even in the case where the quantities of the sample gas 22 supplied to the plasma chamber 7 through the respective gas-lead-in pipes 17 are controlled independently of each other. Next, referring to Fig. 8, a second example of the present invention will be described hereunder. Similarly to the embodiment, the ion source of this second example is suitable for extracting a large-area and high current ion beam for a long time. This third embodiment is different from the embodiment in the shape of the plasma chamber 7. In the second example, plasma chambers 7a, 7b, 7c, ... and sample gas lead-in pipes 17a, 17b, 17c, ... are provided so as to respectively correspond to microwave lead-in coaxial lines 5a, 5b, 5c, ..., while the plasma chamber 7 in the embodiment is constituted by a single large room. The manner how to divide a microwave 21, the manner how to provide a magnetic field generating means 9, and the structure of an acceleration electrode 11 are the same as the embodiment. According to the second example, it is possible to obtain an ion beam of about 120 mA in total which is large in area and which is uniform in characteristics, similarly to the embodiment. Further, it is possible to desirably control the existence of plasma, the kind and density of ions, etc. to be generated in the respective plasma chambers 7a, 7b, 7c, ... As a result, it is possible to extract an ion beam which can be varied in characteristics in a various manner to thereby widen the field of utility of the ion source. Thus, the present invention has remarkable effects as follows. (1) Since the magnetic force lines coming out from the permanent magnet comes into the acceleration electrode, there exists no intense magnetic field in the space between the acceleration electrode and the deceleration electrode. Accordingly, it becomes possible to extract an ion beam with a high electric field to thereby obtain high current ion beam easily. (2) Since the permanent magnet is arranged above the plasma chamber, it is possible to voluntarily widen a plasma chamber in a horizontal direction and to realize a large-area ion beam.

Claims: Microwave ion source comprising a microwave source (1); a plasma chamber (7); a coaxial line (2) for supplying a microwave (21) from said microwave source (1) into said plasma chamber (7); sample gas lead-in hole means (17) for leading in a sample gas (22) so as to generate plasma; a permanent magnet means (9) for generating a magnetic field in said plasma chamber (7); and an acceleration electrode (11), a deceleration electrode (13) and an earth electrode (14) for exerting an ion extraction electric field to plasma generated by microwave discharge in said plasma chamber (7), characterized in that there are provided one microwave source (1) and one acceleration electrode (11) respectively, and in said microwave source (1) there are provided a plurality of coaxial line means (4) connected to said coaxial line (2) for supplying the microwave from said microwave source (1) to said plasma chamber (7), and that said sample gas lead-in hole means (17) consists of a plurality of sample gas lead-in holes (17), and that said permanent magnet means (9) consists of a plurality of permanent magnets (9), and that there is provided a plurality of exit holes (12), formed in said acceleration electrode (11), said deceleration electrode (13) and said earth electrode (14), each of said plurality of sample gas lead-in holes (17) and ion exit holes (12) corresponding to a respective plurality of microwave lead-in sets, each set further including one of said plurality of coaxial line means (4) and a respective said permanent magnet (9) provided around said one coaxial line means (4) of this set; and in that at least a part of said acceleration electrode (11) is composed of a high magnetic permeability member (11a); and in that the end surface of each said permanent magnet (9) at the microwave lead-in side is coupled with the periphery of said high magnetic permeability member (11a) through another high magnetic permeability material means (10) to form a magnetic circuit, said high magnetic permeability material means (10) and said high magnetic permeability member (11a) both surrounding said plasma chamber (7) and all said permanent magnets (9), said high magnetic permeability member (11a) being adapted to absorb the magnetic fields generated by said permanent magnets (9) in said plasma chamber. Microwave ion source according to claim 1, further characterized in that there is provided in said coaxial line (2) a microwave energy control means (24) for independently controlling microwave energy applied to each of said plurality of sets. Microwave ion source according to claim 1, further characterized in that there is provided in each sample gas lead-in hole (17) a gas flow-rate controller for independently controlling gas flow-rate of each said sample gas lead-in hole (17).

Inventors: AMEMIYA KENSUKE, KOIKE HIDEMI, SAKUDO NORIYUKI, SEKI TAKAYOSHI, TOKIGUCHI KATSUMI, AMEMIYA, KENSUKE, KOIKE, HIDEMI, SAKUDO, NORIYUKI, SEKI, TAKAYOSHI, TOKIGUCHI, KATSUMI
Applicants: HITACHI LTD, HITACHI, LTD.
Application year: 1989
Main classification: H01J27
IPC codes: H01J27