Radiation image storage panel

Abstract: Disclosed is a radiation image storage panel which comprises a support and a light-shielding layer, a light-­ scattering layer and a stimulable phosphor layer formed on the support in succession. According to this invention, a radiation image storage panel that can provide radiation images being high in radiation sensitivity and sharpness can be obtained.

Description: This invention relates to a radiation image storage panel having a stimulable phosphor layer, in particular, a radiation image storage panel that can provide radiation images which are high in radiation sensitivity and sharpness. Radiation images like X-ray images are often used in diagnosis of diseases. For obtaining the X-ray images, there have been devised X-ray image storage methods in which images are directly taken from a phosphor layer to replace a light-sensitive silver halide material. The methods include, for example, a method in which the radiation (generally X-ray) transmitted through a subject is absorbed by a phosphor, and thereafter this phosphor is excited by light or heat energy to bring the radiation energy stored by being absorbed as mentioned above to radiate as fluorescence, which fluorescence is detected and formed into an image. Specifically, U.S. Patent No. 3,859,527 and Japanese Unexamined Patent Publication No. 12144/1980 disclose radiation image storage methods in which a stimulable phosphor is used and visible light or infrared rays are used as stimulating light. This method employs a radiation image storage panel (hereinafter referred to as "storage panel") comprising a support formed thereon with a stimulable phosphor layer (hereinafter referred to simply as "stimulable layer"), where radiation transmitted through a subject is applied to the stimulable layer to store radiation energy corresponding to the radiation transmission degree of all areas of the subject to form a latent image. Thereafter this stimulable layer is scanned with the stimulating light to bring the radiation energy stored in the areas to radiate to convert this into light, thus obtaining an image according to signals based on the strength of this light. The image finally obtained may be reproduced as a hard copy, or may be reproduced on a CRT. Generally speaking, the radiation sensitivity of the storage panel has a tendency to be higher when the stimulable layer becomes thicker, and the sharpness of the storage panel has a tendency to be higher with decreased thickness of the stimulable layer. Prior art concerning the storage panel have been disclosed in, for example, Japanese Unexamined Patent Publication No. 11393/1981 in which a metal light-reflective layer is provided on one intersurface of a stimulable layer which is prepared by dispersing stimulable phosphors in binders. The metal light-reflective layer is provided replacing the inner part of the stimulable layer that is away from a surface of the stimulable layer to which the stimulating light incidents; in consequence the stimulable layer can be made thinner, whereby spread of the stimulating light into the stimulable layer can be suppressed, obtaining a radiation image with high sharpness. Although this method can suppress the spread or scattering of the stimulating light in the layer with a decrease in the thickness of the stimulable layer, the stimulating light which reaches the metal light-reflective layer scatters in said layer but with hardly any directivity, so that the stimulating light is reflected back in various directions to the stimulable layer side to repeat scattering in the stimulable layer and stimulate the stimulable phosphor widely, resulting in a low improvement of the sharpness of images. There has been disclosed, in US-A-4380702, a method in which a reflective layer of white pigments is provided, instead of the metal light-reflective layer as described in Japanese Unexamined Patent Publication No. 11393/1981, on one surface of a stimulable layer which is formed by dispersing stimulable phosphors into binders. By using the light-reflective layer of white pigments the thickness of the stimulable layer can be further decreased to enable the suppression of the spread of the stimulating light into the stimulable layer, resulting in the production of radiation images with high sharpness. However, the stimulable phosphor is a kind of white pigment. That is, this method is conducted by merely replacing a part of the stimulable layer which has been formed by dispersing the stimulable phosphor, i.e. a kind of white pigment, into the binder with the white pigment layer which is formed by dispersing the white pigments into the binders. For this reason, this method can suppress the spread or scattering of the stimulating light in the stimulable layer with decreased thickness of the stimulable layer. However, the stimulating light which reaches the light-reflective layer of white pigment while scattering in the stimulable layer is reflected irregularly on the surface of the light-reflective layer of white pigments, or scattered in the light-reflective layer of white pigments and reflected to the stimulable layer side, so that it is scattered in the stimulable layer again to stimulate the stimulable phosphor widely, resulting in less improvement of sharpness of images. Document US-A-4621 196 discloses a storage panel comprising a support on which is placed a light reflecting layer on this being placed an intermediate coloured layer and then a phosphor layer on the top. A stimulable layer containing no binder as described in Japanese Unexamined Patent Publication No. 73100/1986 can improve not only the charge ratio of the phosphor - significantly, but also the directivity of the stimulating light and stimulated emission in the stimulable layer, resulting in improvement of the sensitivity of the storage panel to radiation and, at the same time, in improvement of sharpness of images. Since the vapor deposition and sputtering methods are appropriate for the preparation of the stimulable layer containing no binder, the support to be used must have heat-resistance. For this reason, crystallized glasses, chemically reinforced glasses and the like an preferably used as a support. However, these supports have to have a significant thickness for satisfying the mechanical properties, so that a part of the stimulating light is scattered violently in the support, resulting in a lowering of sharpness. Further, we have proposed a storage panel in which a light-reflective layer is provided on an intersurface on either side of the stimulable layer in Japanese Unexamined Patent Publication No. 133399/1987 and a storage panel in which a light-scattering layer is provided on an intersurface on either side of the stimulable layer in Japanese Unexamined Patent Publication No. 133400/1987. Although these storage panel have excellent radiation image sensitivity and sharpness of images, there is room for improvement to obtain a better storage panel. As mentioned above, there have never been found a storage panel which has both excellent radiation sensitivity and sharpness. Accordingly, an object of this invention is to provide a storage panel which is excellent in both radiation sensitivity and sharpness. The radiation image storage panel of this invention comprises a support and a light-shielding layer having a light transmittance of 5% or less for light having a wavelength of 500nm to 900 nm, a light-scattering layer having a light reflective index of 40 % or more for light having a wavelength of 300 nm to 900nm and a stimulable phosphor layer that does not contain a binder formed on the support in succession. Fig. 1 is a schematic cross-sectional view of a storage panel of this invention. Fig. 2 is a schematic cross-sectional view of a storage panel of this invention. Fig. 3 is a illustrative view of a radiation image converting method. Fig. 4 is a view showing radiation sensitivity and MTF characteristics of the storage panels of examples and comparative examples. The construction of the storage panel of this invention will be described hereinbelow by referring to the drawings. Fig. 1 and Fig. 2 are schematic cross-sectional views showing an example of the storage panel of this invention. In these drawings, the numeral 1 denotes a support, 2, a stimulable layer, 3, a light-shielding layer, 4, a light-scattering layer, and 5, a protective layer, respectively. The storage panel of this invention comprises the stimulable layer 2 on the support 1 as shown in Figs. 1 and 2, and further comprises a light-shielding layer 3 and a light-scattering layer 4. The light-shielding layer 3 and light-scattering layer 4 are provided between the support 1 and stimulable layer 2, in order of the light-shielding layer 3 and light-scattering layer 4 from the side of the support 1. The storage panel of this invention may include a protective layer 5 provided on the stimulable layer 2 for protecting the stimulable layer 2 from external chemical and physical stimulations. The stimulable phosphor constituting the stimulable layer in the storage panel of this invention is a phosphor exhibiting a stimulated emission corresponding to the dose of the first light or high energy radiation by optical, thermal, mechanical chemical or electrical stimulation (stimulating excitation) after irradiation of the first light or high energy radiation, preferably a phosphor exhibiting stimulated emission by a stimulating light of 500 nm or longer. Such a stimulable phosphor may include, for example, those represented by BaSO₄:Ax as disclosed in Japanese Unexamined Patent Publication No. 80487/1973; those represented by SrSO₄:Ax as disclosed in Japanese Unexamined Patent Publication No. 80489/1973; those such as Li₂B₄O₇:Cu, Ag, etc. as disclosed in Japanese Unexamined Patent Publication No. 39277/1978; those such as Li₂0·(B₂0₂) x :Cu and Li₂O·(B₂O₂) x :Cu,Ag, etc. as disclosed in Japanese Unexamined Patent Publication No. 47883/1979; those represented by SrS:Ce,Sm, SrS:Eu,Sm, La₂O₂S:Eu,Sm and (Zn,Cd)S:Mn,X as disclosed in U.S. Patent No. 3,859,527. Also, ZnS:Cu,Pb phosphors, barium aluminate phosphors represented by the formula BaO·xAl₂O₃:Eu and alkaline earth metallosilicate type phosphors represented by the formula M II O·xSiO₂:A as disclosed in Japanese Unexamined Patent Publication No. 12142/1980. Additional examples of phosphors include, as disclosed in Japanese Unexamined Patent Publication No. 12143/1980, alkaline earth fluorohalide phosphors represented by the following formula: (Ba l-x-y Mg x Ca y )FX:Eu²⁺; phosphors as disclosed in Japanese Unexamined Patent Publication No. 12144/1980 which corresponds to U.S. Patent No. 4,236,078: LnOX:xA; phosphors as disclosed in Japanese Unexamined Patent Publication No. 12145/1980: (Ba 1-x M II x )FX:yA; phosphors as disclosed in Japanese Unexamined Patent Publication No. 84389/1980: BaFX:xCe,yA; rare-earth elements activated divalent metallic fluorohalide phosphors as disclosed in Japanese Unexamined Patent Publication No. 160078/1980: M II FX·xA:yLn; phosphors represented by any of the formulas shown below: ZnS:A, CdS:A, (Zn,Cd)S:A, ZnS:A,X and CdS:A,X; phosphors as disclosed in Japanese Unexamined Patent Publication No. 38278/1984, represented by any of the formulas shown below: xM₃(PO₄)₂·NX₂:yA and M₃(PO₄)₂:yA; phosphors as disclosed in Japanese Unexamined Patent Publication No. 155487/1984, represented by any of the formulas shown below: nReX₃.mAX′₂:xEu and nReX₃.mAX′₂:xEu,ySm; alkali halide phosphors as disclosed in Japanese Unexamined Patent Publication No. 72087/1986, represented by the formula shown below: M I X·aM II X′₂:bM III X″₃:cA; and bismath activated alkali halide phosphors disclosed in Japanese Unexamined Patent Publication No. 228400/1986 represented by the formula: M I X:xBi and the like. Particularly, alkali halide phosphors are preferable, because such stimulable phosphor layers can be formed easily by vapor deposition or sputtering, for example. However, the stimulable phosphor to be used in the radiation image storage panel of this invention is not limited to those as described above, but any phosphor which can exhibit stimulated fluorescence when irradiated with a stimulating light after irradiation of radiation may be useful. The stimulate layer of the storage panel of this invention may take the form of a group of stimulable layers containing one or two or more stimulable layers comprising at least one of the stimulable phosphors as mentioned above. The stimulable phosphors to be contained in the respective stimulable phosphor layers may be either identical or different. As a method of forming the stimulable layer, there may be applied coating methods as described in Japanese Unexamined Patent Publication No. 12600/1981, and also a physical vapor deposition method such as vapor deposition. The stimulable layer formed by physical vapor deposition method generally has a higher charge ratio of the phosphors than that of the stimulable layer formed by the coating method, resulting in higher sensitivity to radiation. The thickness of the stimulable layer of the storage panel according to this invention may differ depending on the sensitivity of the radiation image storage panel to the radiation used and the nature of the stimulable phosphor, for example, but is preferably, in the case where no binder is present, from 10 to 1,000 µm, more preferably 30 to 800 µm. The support to be used for the storage panel of this invention may be made of various kinds of polymer materials, glasses such as a crystallized glass, ceramics or metals, for example. The polymeric materials include films made of, for example, cellulose acetate, polyesters, polyethyleneterephthalate, polyamides, polyimides, triacetate, and polycarbonate. The metals include metallic sheets or metal plate made of aluminum, iron, copper or chromium, for example, or metallic sheets or metal plates having a coated film of oxides of said metals thereon. The glasses include chemical reinforced glass and crystallized glass, for example. Also, the ceramics may be sintered plates of alumina or zirconia, for example. In the case where the stimulable layer is formed by the vapor phase build-in method, a preferred support is crystallized glass. The thickness of these supports, which vary depending on the quality of the support to be used, may generally be in the range of 80 µm to 5 mm, preferably, in view of ease of handling, 200 µm to 3 mm. The surface of these supports may be smooth or, alternatively, may be a mat surface for the purpose of enhancement of adhesiveness with an upper layer. The surface of the supports may also be made to have a concave-convex surface; alternatively they may have a surface structure on which a dense, closely packed fine tile-shaped plate pattern is provided. The principal feature of the storage panel according to this invention is to provide the light-shielding layer and light-scattering layer in succession from the support side between the support and stimulable layer. Here, in the case of the light-shielding layer only, the sensitivity of images becomes lower, and, in the case of the light-scattering layer only, sharpness of images becomes lower, both resulting in no success in accomplishing the object of this invention. The effect of the storage panel of this invention is particularly high when the support has a property that can scatter a part of the stimulating light therein, for example the above-mentioned crystallized glass, chemical reinforced glass and ceramic sintered plates. The light-shielding layer of the storage panel according to this invention is a layer which acts to prevent transmission of the stimulating light by absorbing or reflecting it on the surface of the layer. The light-shielding layer used in this invention has a light transmittance of 5 % or less, more preferably 1 % or less for the purpose of prevention of transmission of the stimulating light having a wavelength of 500 to 900 nm, particularly 600 to 800 nm, by mainly reflecting or absorbing it. Also, the light-shielding layer preferably has a light reflective index of 70 to 200 % to the stimulating light for the purpose of reflection of the stimulating light, and 70 % or less for the purpose of absorption of the stimulating light. Here, the light reflective index is measured by defining a standard white board (MgO) as 100 %, and the light transmittance, defining air as 100 %. In both cases, measurement was conducted by use of a spectrometer S57 model produced by Hitachi K.K using a cell of 10 mm in thickness. The device is similarly used hereinbelow. The light transmittance and light reflective index are indicated by the values measured by using the layer of which the thickness is practically used, respectively. Materials constituting the light-shielding layer may include, for example, metals such as aluminum, nickel, chromium, silver, copper, platinum and rhodium, black-type ceramics such as titanium oxide (TiO x ; 1 ≦ x ≦ 2), chromium oxide (Cr₂O₃) and a mixture of aluminum oxide and titanium oxide (Al₂O₃·xTiO y ; 0.1 ≦ x ≦ 0.5, 1 ≦ y ≦ 2). The method for forming the light-shielding layer is appropriately selected depending on the materials. For example, in the case where the above-mentioned metals are used, there may be applied the vapor deposition method, sputtering method, ion plating method, plating method or flame-spraying method, for example. In the case where the black type ceramics are used, the coating method or flame-spraying method, for example, are applied. The flame-spraying method may include the gas-type flame-spraying method in which a high temperature gas flame is used as a heat source, the electric-type flame-spraying method in which arc or plasma is used as a heat source, etc. The gas-type flame-spraying method has an advantage that the production cost is low, and the electric-type flame-spraying method has an advantage that films having high density and good adhesiveness can be obtained thereby. The thickness of the light-shielding layer is preferably 0.01 to 0.5 µm in the case of methods such as the vapor deposition and sputtering, and 10 to 100 µm in the case of methods such as the plating method and flame-spraying method. When the thickness of the light-shielding layer is thinner than the lower limit, the transmission of the stimulating light becomes undesirably large. When it is over the upper limit, there may be caused a lowering of adhesiveness, warpage, distortion, etc. The light-scattering layer of the storage panel according to this invention acts to reflect and scatter the stimulating light and/or stimulated emission having wavelength of 300 to 900 nm therein. The storage panel with desired sensitivity and sharpness can easily be obtained by controlling the degree of scattering of light by appropriately increasing or decreasing the thickness of the light-scattering layer. The light-scattering layer has a light reflective index of 40 % or more, preferably 60 % or more. As a material for constituting the light-scattering layer, there may be included white pigments such as white lead, zinc oxide and titanium oxide; ceramics such as aluminum oxide (Al₂O₃) and zirconium oxide (ZrO2), or a mixture thereof with at least one of titanium oxide (TiO₂), silicate dioxide (SiO₂), magnesium oxide (MgO), calcium oxide (CaO) and calcium carboxide (CaCO₃), e.g. aluminum oxide - titanium oxide (Al₂O₃·xTiO₂; 0.01 ≦ x ≦ 0.05), aluminum oxide - silicate dioxide (Al₂O₃·xSiO2; 0.01 ≦ x ≦ 0.5) and zirconium oxide - magnesium oxide (ZrO₂·xMgO; 0.01 ≦ x ≦ 0.5); and glasses. Among them, preferred are those having excellent heat-resistance which are not deteriorated by heat applied during preparation of the storage panel (for example, in the case where the stimulable layer is formed by the vapor deposition method) such as ceramics. The forming method of the light-scattering layer is not particularly limited, but is preferably the flame-spraying method because it can form a layer with even thickness over a large area. Accordingly, as the light-scattering layer, preferred are those formed by using the above-mentioned ceramics, particularly white type ceramics according to the flame-spraying method. As the flame-spraying material, there may be used a powdery shape or rod-like shape, for example. The average particle size of the powdery flame-spraying materials is preferably 50 µm or less, more preferably 30 µm or less. The thickness of the light-scattering layer, which is appropriately determined depending on the degree of reflection and scattering as mentioned above, is preferably 5 to 200 µm, more preferably 20 to 100 µm. An overly small thickness of the light-scattering layer may cause a decrease of ratio of the stimulated emission which is reflected and scattered in the light-scattering layer and returned to the stimulable layer, resulting in a lowering of sensitivity. An overly large thickness thereof may cause excessive spread of the stimulated emission in the light-scattering layer, resulting in a lowering of sharpness. In this invention, it is also possible to change the storage panel with a sensitivity corresponding to the pattern of the dose of radiation absorbed in the subject as described in Japanese Unexamined Patent Publication No. 214700/1988 by utilizing the feature of this invention that the sensitivity can be varied with a change of the thickness of the light-scattering layer. Also, the surface and/or internal portion of the light-scattering layer may be colored by use of the dyes and pigments described in the specification of the above application. The surfaces of the light-shielding layer and light-reflective layer may be smooth or uneven (concave-convex pattern). In the storage panel of this invention, an undercoat layer may be provided between layers constituting the storage panel for the purpose of enhancement in adhesiveness of the respective layers. In the storage panel of this invention, at least one protective layer may be further provided on the stimulable layer for the purpose of protecting the stimulable layer from chemical stimulation from external atmosphere, particularly moisture. As the material forming such protective layer, preferred are those having good transparency and capable of being formed in a sheet. Also, the protective layer is preferably one showing high transparency in the wide wavelength range for transmitting efficiently the stimulating light and stimulated emission, preferably those having a transparency of 80 % or more. As such protective layers, there may be included, for example, plate glasses of quartz glass, borosilicate glass, chemical reinforced glass or organic polymeric compounds such as PET, OPP, polyvinylchloride. Here, the borosilicate glass shows a transmission of 80 % or more in the wavelength region of 330 nm to 2.6 µm, and the quartz glass shows high transmission in an even shorter wavelength region. As those forming the protective layer, preferred is plate glass in view of the fact that it shows moisture-inhibiting properties as well as light transmittance. The thickness of the protective layer is generally 10 µm to 3 mm, preferably 100 µm or more for obtaining good water vapor barrier properties. In the case where the thickness of the protective layer is 500 µm or more, a storage panel with excellent durability and lifetime can be obtained. In the storage panel of this invention, a layer of which the light reflective index is lower than that of the protective layer may be provided between the stimulable layer and the protective layer. Further, between the stimulable layer and the above-mentioned layer having lower light reflective index, there may be provided a layer having a higher light reflective index than that of the above-mentioned low light reflective index layer. By using the above construction of the protective layers, the durability and lifetime of the storage panel can be enhanced without impairing sharpness of images. The provision of a reflection preventing layer such as MgF₂ on the surface of the protective layer can provide efficient transmission of stimulating light and stimulated emission as well as suppression of a lowering in sharpness. The light reflective index of the protective layer, which is not particularly limited, may be generally in the range of 1.4 to 2.0. The protective layer may comprise two or more layers, if desired. Particularly, preferred is the construction as disclosed in Japanese Unexamined Patent Publication No. 15500/1987 in which two or more layers which are different from each other in regain are combined in view of their water vapor barrier properties. In the storage panel of this invention, the protective layer can also function as the support. The storage panel of this invention can be used for the radiation image converting method schematically indicated in Fig. 3. In Fig. 3, the numeral 41 denotes a radiation generator; R, radiation generated from the radiation generator; 42, a subject; RI, radiation transmitted through the subject; 43, a storage panel according to this invention; 44, a stimulating light source; 45, a photoelectric transducer to detect stimulated emission radiated from the storage panel; 46, a unit to reproduce as an image the signals detected by 45; 47, a unit to display a reproduced image; 48, a filter to separate the stimulating light and stimulated emission and to pass only the stimulated emission. The units posterior to the unit 45 may be any of those which can reproduce light information from the storage panel 43 as an image in any form, and are by no means limited to the above-identified. As shown in Fig. 3, the radiation from the radiation generator 41 is made incident on the storage panel 43 through the subject 42. This radiation thus made incident is absorbed in the phosphor layer of the storage panel 43, where its energy is stored and a stored image of the radiation-transmitted image is formed. Next, this stored image is excited by the stimulating light from the stimulating light source 44 and emitted as stimulated emission. The strength of the stimulated emission thus radiated is proportional to the amount of stored radiation energy. Accordingly, this light signal may be subjected to photoelectrical conversion by means of the photoelectric transducer 45 as exemplified by a photomultiplier tube, reproduced as an image by the image-reproducing unit 46, and may be displayed by the image display unit 47, so that the radiation-transmitted image of the subject can be viewed. This invention will be described below by giving Examples. Example 1 A support, crystallized glass plate 1 mm thick, was subjected to sandblasting treatment. Next, onto the surface of the plate, a light-shielding layer with a thickness of 40 µm, a light transmittance of 0 % and a light reflective index of 14 % was formed by flame-spraying Al₂O₃·40%TiO₂ by use of Lokide rod spray apparatus. Then, onto the light-shielding layer was formed a light-scattering layer with a thickness of about 50 µm and a light reflective index of 73 % by flame-spraying 99%Al₂O₃ powders with a particle size of 5 to 20 µm by use of a gas blast flame-spraying apparatus. Next, the light-scattering layer was subjected to vapor deposition of alkali halide stimulable phosphor (RbBr: lxlO⁻⁴ Tl) by use of the electron beam vapor deposition method to a thickness of about 300 µm to obtain Storage panel A of this invention. Example 2 The same procedure of Example 1 was repeated excepting that a light-shielding layer with a thickness of about 25 µm, a light transmittance of 0 % and a light reflective index of 32 % was formed by flame-spraying Ni-20%Cr powders with a particle size of 5 to 20 µm instead of the provision of the light-shielding layer prepared by flame-spraying Al₂O₃·40%TiO₂ to obtain Storage panel B of this invention. Example 3 A crystallized glass plate with a thickness of 1 mm was roughened by dipping in 20 % hydrogen fluoride solution for 20 seconds and washing. Onto the roughened surface was formed a light-shielding layer with a light transmittance of 0.3 % and a light reflective index of 75 % by vapor depositing Al to a thickness of 0.25 µm according to the resistance-heating method. Then, a light-scattering layer and stimulable phosphor layer were provided on the light-shielding layer in the same manner as in Example 1 to obtain Storage panel C of this invention. Example 4 The same procedure of Example 1 was repeated excepting that the thickness of the light-scattering layer was 20 µm and the light reflective index thereof was 52 % to obtain Storage panel D of this invention. Example 5 The same procedure of Example 1 was repeated excepting that the thickness of the light-scattering layer was 70 µm and the light reflective index thereof was 80 % to obtain Storage panel E of this invention. Example 6 The same procedure of Example 1 was repeated excepting that the thickness of the light-scattering layer was 100 µm and the light reflective index thereof was 88 % to obtain Storage panel F of this invention. Comparative example 1 The same procedure of Example 1 was repeated excepting that no light-shielding layer was formed to obtain Storage panel P for comparison. Comparative example 2 The same procedure of Example 1 was repeated excepting that no light-scattering layer was formed to obtain Storage panel Q for comparison. Comparative example 3 The same procedure of Example 2 was repeated excepting that no light-scattering layer was formed to obtain Storage panel R for comparison. Comparative example 4 The same procedure of Example 3 was repeated excepting that no light-scattering layer was formed to obtain Storage panel S for comparison. These storage panels were subjected to evaluations in sensitivity and sharpness. First, the panels were exposed to 10 mR of X-rays having a tube voltage of 80 KVp, and thereafter subjected to stimulating excitation using a semiconductor laser beam (780 nm), where the stimulated emission radiated from the stimulable layer was subjected to photoelectric conversion with use of a photoconductor (a photomultiplier tube), and the resulting signals were reproduced as an image by use of an image-reproducing unit, which was then analyzed. The sensitivity of the storage panel was examined from the size of the signals and a modulation transfer function (MTF) of the images was examined from the images obtained to obtain the results as shown in Fig. 4. In Table 4, the abscissae indicate sensitivity and the ordinates indicate the MTF. The sensitivity to X-rays is indicated as a relative value assuming that of Storage panel P of Comparative example 1 as 100. The MTF value was a value at a spatial frequency of 2 cycles/mm. As will be clear from Fig. 4, Storage panels A to F of this invention show enhancement of sharpness without lowering the sensitivity as much as compared with Storage panel P of Comparative example 1 having the light-scattering layer only. Also, Storage panels A to F show enhancement of sensitivity to a great extent without lowering sharpness so much as compared with Storage panels Q to S of the comparative examples having the light-shielding layer only. Further, as will be clear from the result of measurements of Storage panels A, D, E and F, storage panels of this invention can be made having various sensitivities - MTF characteristics such as a high sensitivity type, high sharpness type, etc., by changing layer thickness of the light-scattering layer and leaving other constituting elements as such. As described above, the storage panel of this invention is excellent in both radiation image sensitivity and sharpness of images. Also, a storage panel having desired sensitivity - MTF characteristics (sharpness) can be obtained by appropriately selecting the thickness of the light-scattering layer.

Claims: A radiation image storage panel which comprises a support and, in order, a light-shielding layer having a light transmittance of 5% or less for light having a wavelength of 500 um to 900 um, a light scattering layer having a light reflective index of 40% or more for light having a wavelength of 300 um to 900 um and a stimulable phosphor layer that does not contain a binder, on the support. The radiation image storage panel according to claim 1, wherein the light-shielding layer has a light reflective index ranging from 70% to 200%, and 40% or less for the purpose of absorption of the stimulating light. The radiation image storage panel according to claim 1 or 2 wherein the light-shielding layer comprises at least one of aluminum, nickel, chromium, silver, copper, platinum, rhodium, titanium oxide, chromium oxide, or a mixture of aluminum oxide and titanium oxide. The radiation image storage panel according to any one of claims 1 to 3, wherein the light-shielding layer is formed by a physical vapor deposition method and has a thickness from 0.01 to 0.5 µm. The radiation image storage panel according to any one of claims 1 to 3 wherein the light-shielding layer is formed by a plating method and has a thickness from 10 to 100 µm. The radiation image storage panel according to any one of claims 1 to 5, wherein the light-scattering layer has a light reflective index of 60% or more. The radiation image storage panel according to any one of claims 1 to 6, wherein the light-scattering layer comprises white lead, zinc oxide, titanium oxide, aluminium oxide or zirconium oxide or a mixture of aluminum oxide and zirconium oxide with at least one of titanium oxide, silicon dioxide, magnesium oxide, calcium oxide and calcium carbonate. The radiation image storage panel according to any one of claims 1 to 7, wherein the light-scattering layer has a thickness of 5 to 200 µm. The radiation image storage panel according to claim 8 wherein the light-scattering layer has a thickness of 20 to 100 µm. The radiation image storage panel according to any one of claims 1 to 9, which further comprises a protective layer on the stimulable phosphor layer. The radiation image storage panel according to any one of claims 1 to 10, wherein the support comprises chemically reinforced glass and/or crystallized glass. The radiation image storage panel according to any one of claims 1 to 11, wherein the stimulable phosphor layer comprises alkali phosphor.

Inventors: HONDA SATOSHI, KANO AKIKO, NAKANO KUNIAKI, KANO, AKIKO, NAKANO, KUNIAKI
Applicants: KONISHIROKU PHOTO IND, KONICA CORPORATION
Application year: 1989
Main classification: G21K4
IPC codes: G21K4