DENSIFICATION OF CERAMIC-METAL COMPOSITES

Abstract: Substantially dense, void-free ceramic-metal composites are prepared from components characterized by chemical incompatibility and non-wetting behavior. The composites have a final chemistry similar to the starting chemistry and microstructures characterized by ceramic grains similar in size to the starting powder and the presence of metal phase. A method for producing the composites requires forming a homogeneous mixture of ceramic-metal, heating the mixture to a temperature that approximates but is below the temperature at which the metal begins to flow and pressing the mixture at such pressure that compaction and densification of the mixture occurs and an induced temperature spike occurs that exceeds the flowing temperature of the metal such that the mixture is further compacted and densified. The temperature spike and duration thereof remains below that at which significant reaction between metal and ceramic occurs. The method requires pressures of 60-250 kpsi (413 to 1724 MPa) employed at a rate of 5-250 kpsi/second (34 to 1724 MPa).

Description: DENSIFICATION OF CERAMIC-METAL COMPOSITES The present invention relates to dense, ceramic-metal composites that approach theoretical density and methods for producing them. More particularly, the invention relates to ceramic-metal composites that are formed of chemically incompatible components that also may exhibit non-wetting behavior. Ceramic materials are combined with metals to form composite compositions that exhibit exceptional hardness and toughness yet are often light in weight in comparison with metals. Achieving the best potential characteristics for any ceramic-metal composite requires that the composite produced is substantially void-free and capable of achieving theoretical density for a given starting mixture. Also, since a key advantage of such ceramic-metal composites is hardness, it is desirable to maximize the ceramic component content. Preferably, at least 50 percent by volume of the composite composition is ceramic which composition has been difficult to fully densify heretofor. The metal component lends toughness to the ceramic-metal composite and is additionally a key element in obtaining void-free densification. It is also desirable that the finished densified compact is substantially similar chemically and in ceramic grain size to the starting mixture. Such similarity is important to achieving composites that have predictable and uniform characteristics. Obtaining fully densified ceramic-metal compo¬ sites for such mixtures has not been achieved in the 10 past because of the relatively difficult nature of combinations of the ceramics and metals of interest. Many of the metals and ceramics are non-wetting and thus difficult to fully densify by processes that -.,- require metal flow under influence of capillary forces into the voids between ceramic particles. Also, many of the ceramics and metals are "incompatible", in the sense that they react with one another during conventional densification processing that utilizes 20 higher temperatures as an aid to overcoming non- wettability difficulties. As a result of such reactivity the finished composite may include new components or phases, the presence of which generally adversely affects the character of the composite 25 product. The prior art discloses densification of cer¬ amic-metal composites by means of a number of techniques that include hot pressing, hot isostatic 30 pressing (HIP) and explosive compaction. Thus, Schwarzkopf in U.S. Patent 2,148,040 discloses a hot pressing process for densifying a ceramic-metal mixture involving heating the mixture to a presintering temperature that is defined as 10-15 percent below the melting temperature of the entire mixture. The resulting spongy, porous structure, preferably still hot, is then extruded through an orifice at 71.1-213.3 thousand pounds per square inch (kpsi) pressure (490- 1470 MPa). The pressure increase causes the lower melting point metal component to flow thus filling the interstices between the ceramic particles. A difficulty with the composites produced by Schwarzkopf was that they were not reliably fully dense or uniform because of inadequate temperature control. Also, the extrusion pressing step severely limited the types of composites that could be produce'd to simple shapes. A complexly shaped ceramic-metal composite is produced by making a homogeneous slurry mixture of the component powders which slurry is then, for example, cast upon a mold of desired complexity and dewatered to form a green body or compact. The compact is heated to a high temperature to produce a final densified compact but substantially below 100 percent of theoretical density. It was quickly recognized that the applica¬ tion of high pressure would aid in further compaction. It was also recognized that conventionally available pressures of up to a few thousand psi (about 10 to 15 MPa) were inadequate to achieve full density for a number of ceramic-metal compacts. Interest, therefore, turned to explosive compaction processes in which pressures could be applied to ceramic-metal composites on the order of many thousands of pounds per square inch applied in milliseconds. Thus, McKenna et al. in U.S. Patent 2,648,125 surrounds a ceramic-metal compact with a body of liquid and subjects the body of liquid to explosive pressure that isostatically applies 50-60 kpsi (345-413 MPa) pressure to the compact. McKenna notes that it is desirable that the pressure not be developed too rapidly and that maximum pressure is best achieved within 25 to 50 milliseconds. Brite et al, in U.S. 3,276,867 discloses a process for densifying a mixture of powdered uranium oxides or nitrides, etc. and a powdered metal such as tungsten, nickel, iron or the like. The process requires heating the mixture to a temperature that is below any reaction temperature between the powders followed by a high energy, high rate compaction, exerting pressures of 250 to 400 kpsi (1724 to 2758 MPa) over 2 to 6 milliseconds. Zernow et al. in U.S. Patent 3.157.498 employs an explosive technique in which the compact is subjected to short- -time high compression which induces a very large adiabatic temperature increase that may be on the order of several thousand degrees Kelvin in the compact. The explosive compaction processes were unsatisfactory for a number of reasons. Process temperatures utilized were difficult to control, often, as in Zernovw et al, resulting in such large increases that adverse phase formation occurred. Composites so processed were generally limited to small sizes and the extreme pressures often caused composite cracking. The industry therefore turned to elevated temperature pressing at somewhat lower pressures, as a means of attaining more uniformly formed composites. Lichti et al. in U.S. Patent 4,539,175 describes compacting powder material such as a ceramic- - etal body by heating the body to 926°C to 2204°C and isostatically pressing at 20 to 120 kpsi (138 to 827 MPa). In forming void-free metal parts from metal powders, Nyce in U.S. Patent 4,591,482 initially heats a metal compact to a temperature 10-20 percent lower than sintering temperature. A pressure of 1 to 2 kpsi (7 to 14 MPa) is applied to densify the compact and is said to cause a temperature spike that forms small amounts of liquid in the compact that assists in collapsing remaining voids to achieve a substantially fully dense finished part. The temperature spike is described as bringing the compact back to the sinter temperature but only for 5 to 10 minutes in order to avoid significant grain growth which leads to weakening of the product. These relatively lower pressure processes tend to employ relatively high temperatures that, in combination with duration of the process, produce multiple phases in incompatible, that is, reactive ceramic and metal systems. As noted earlier, the presence of these phases can be detrimental to finished products qualities. Recent work focuses more directly upon the mechanisms thought to be involved in the compaction process. Thus, Halverson et al. in U.S. Patent 4,605,440 teaches that in many ceramic-metal systems, densification is improved where a composite is subjected to sufficient temperature such that a liquid metal phase is formed that has a low contact angle of the liquid phase on the solid ceramic phase. This condition is termed wetting and satisfies the capillarity thermodynamic criterion for the system. Halverson describes fully dense boron carbide aluminum composites that are prepared by sintering at a temperature of 1180°C to 1200°C where wetting of the ceramic component via the aluminum metal component occurs. However, the products produced by Halverson include a number of ceramic phases that differ from the starting materials, including AIB2, Alj j BC, AIB-12C2, A1B- | 2 and that adversely affect the mechanical properties of the composite product. These undesirable ceramic phases develop because of the incompatibility between boron carbide and aluminum at the sintering temperature and appear because the reaction rates of aluminum with B^C are higher than the rate of the densification process. Pyzik et al. in U.S. Patent 4,702,770 focuses upon the reactiveness or "incompatibility" characteristics of many ceramic-metal systems at elevated temperatures, particularly those temperatures related to achieving wettability. Pyzik produces composites that consist chiefly of boron carbide, aluminum and minor amounts of other ceramic phases, generally avoiding the multiphase results of Halverson. In Pyzik's process, the kinetics of the chemical reaction between Bi j C and Al are reduced by sintering the Bj j C ceramic component at above 2100°C. For example, a porous green body of the B^C is formed, sintered at 2100°C and then infiltrated with aluminum at a temperature above 1150°C. The method permits some control over the rate of reaction, but does not avoid formation of all undesirable ceramic phases. Additionally, if the metal used is an alloy, the high temperature required for infiltration typically completely changes the composition of the metal found in the composite, e.g., an aluminum alloy of Al, Zn, Mg would change composition at an infiltration temperature of greater than 900 to 1000°C through evaporative losses of Zn and Mg. In summary, the technologies of densification of ceramic-metal composites by pressing techniques, particularly for chemically incompatible and non- wetting ceramic-metal systems, fail to reliably produce fully densified composites. Predictability of product characteristics is low where the pressing techniques involve higher temperatures. The failure in the art is due to a lack of understanding of how the results achieved in the densification process are influenced by interaction between the wettability characteristics and the incompatibility characteristics of the ceramic and metal components sought to be densified. The more recent work of Halverson et al. teaches the necessity for achieving wetting of ceramic by metal by employing high temperature processing. However, the results achieved at these high temperatures due to chemical reaction between the incompatible components generally causes fast depletion of the metal and often formation of undesirable new phases. The Pyzik et al. process achieves wetting while reducing formation of multiple ceramic phases but requires separate processing steps at high temperatures for the ceramic phase. The present invention solves the difficulties of the prior art teachings by recognizing the criticality of: (1) heating a ceramic-metal mixture or compact to a temperature that produces a liquid metal phase but does not produce unwanted ceramic-metal phases; (2) applying sufficiently high external pressure to the system such that, in combination with heating, liquid metal is forced between ceramic grains while avoiding temperatures that enhance undesirable ceramic phase formation, and; (3) using a sufficient amount of metal for each particular ceramic-metal system such that voids between ceramic grains are filled. The present invention provides a method for forming dense ceramic-metal composites that achieves a final composition that is substantially similar to the starting chemistry of the ceramic-metal mixture and is further characterized by microstructures wherein the size of the ceramic grains is similar or identical to the starting powder. The composites include a continuous or discontinuous metal phase. The method of the invention produces dense, substantially void-free composites that are generally more than 95 percent of the theoretical density of the starting mixture. In contrast to the prior art, processing is conducted at conditions wherein liquid metal flows into interstices between ceramic grains but does not subject the compact to such conditions whereby incompatibility between the ceramic and metal results in unwanted ceramic phases that adversely affect finished product quality. Where ceramic phases are desired, the method of the invention permits controlling the type of phases formed and their kinetics. The composites of the invention, having a chemistry close to the starting composition, can then be elevated to higher temperatures to form desired ceramic phases or treated at lower temperatures to achieve other metallurgical characteristics. The method of the invention of densifying a ceramic and metal mixture or composite includes first forming a substantially homogeneous mixture of one or more ceramic materials and one or more metal materials. Typically, the mixture is formed into greenware by 10 conventional casting or pressing techniques. The mixture or compact is heated to a first temperature that approximates but is below that temperature at which the metal begins to flow. Such temperature may « r be higher than the pure metal melting temperature depending upon the degree of oxidation of the metal powder utilized. The method then requires pressing the mixture or compact at such pressure that compaction and densification of the mixture or compact occurs. The 0 pressing step induces a second temperature in the compact wherein the second temperature equals or exceeds the temperature at which the metal components melt and flow such that the mixture is further compacted and densified, achieving substantially 5 void-free compacts that are at least near 100 percent of theoretical density with respect to the initial mixture. The second temperature, in absolute value and duration, remains below those conditions which would 0 cause a significant undesired reaction between the metals and ceramics of the mixture. The pressing pressure is applied at such a high rate of increase and for such a short duration that the temperature profile of the compact includes a spike increase of about 10°C to 200°C that is sufficient to improve densification but minimizes exposure of the mixture to temperature conditions at which significant adverse reaction between the metal and ceramic occurs. The pressing step requires at least about 60 kpsi (413 MPa), applied at a rate of at least about 5-250 kpsi per second (34-1724 MPa per second). A practical upper pressure limit is about 250 kpsi (1724 MPa). However, where the first temperature has been properly selected, pressures as high as 700 kpsi (4827 MPa) may be used. The method of the invention requires careful selection of the initial heating temperature of the compact in order to insure that the induced temperature by the pressing step does not exceed temperatures where adverse reactions may occur between the ceramic and metal components. The induced second temperature is chosen such that no adverse reactions between the ceramic and metal occur. The increase in temperature for a given compo¬ sition and pressure may be calculated utilizing thermo- dynamic and physical characteristics of the components and system. This calculation establishes the first temperature achieved by the initial heating step. The pressing step may utilize any means which applies pressure to the ceramic-metal composite com¬ pact. A preferred method requires isostatic pressing. A greenware compact, typically at 50 to 70 percent of theoretical density, is encapsulated in a non-reactive pressure transmitting fluid or fluidizable medium that is contained such that applying a pressure to the medium applies pressure to the compact isostatically, thereby densif ing the compact. The compact can be prepared using methods known in the art for greenware preparation including, for example, cold isostatic pressing, which is preferred. The method of the invention may include a first, compact forming, pressing step wherein the compact is encapsulated in the pressure transmitting medium and pressed at less than 60 kpsi (413 MPa) such that the partially densified compact has a density of at least about 50 percent by weight of theoretical density. The compact then remains encapsulated in the pressure transmitting medium during the subsequent heating step and the pressing step wherein the second temperature is quasiadiabatically induced in the compact. Following the pressing step, the pressure is released and the compact cools before significant reaction between the metals and ceramics occurs. The method of the invention is particularly useful in producing fully densified compacts from ceramics and metals that are chemically incompatible or reactive and are non-wetting below reactive temperatures. The invention includes densified ceramic-metal compositions that comprise a ceramic in an amount of at least about 50 percent by volume of the composition wherein the ceramic is B^C, SiC, SiB , SiBi A1B 2 , A1B 12 . A1B 1 C 2 , A1 4 BC, TiB, TiB 2 , TiC, A1 2 0 3 , MgO, mullite, Zr0 2 , MgSi0 3 , Mg 2 Si0i j , MgAl 2 0n, Mg 2 Al 2 Si 5 0 l8 , TiN, WC, A1N, SigN j or mixtures thereof. The composition includes a metal such as Al, Mg, Ti, Fe, Ni, Co, Mn, Cu, Si or their alloys. A preferred densified ceramic and metal com¬ position comprises a silicon boride in an amount of 50-80 percent by volume of the composition wherein the silicon boride is SiBi j , SiBg, SiB- j ^, SiB x or their mixtures and a metal such as Al, Cu, Fe, Co, Ni or their alloys. A most preferred composition of silicon boride includes SiBj j and SiB in an amount of 60-70 volume percent of the composition. Preferred metals include aluminum and copper or an aluminum alloy. These ceramic-metal composites are characterized by compositions and ceramic grain size that are substantially similar to the initial homogeneous mixture of the ceramic and metal components. Of particular interest in the invention are cermets made of highly chemically incompatible and non- -wetting ceramics and metals such as B^C-Al and B^C-Al alloy materials. Other such systems include SiC, SiBg and SiBj j with aluminum; B^C with Mg, Fe; SiC with Cu. Particularly interesting non-wetting systems include A1B2, A1B 12 . TiB 2 . A1N, or AI2O3 with aluminum. Figure 1 shows an induced temperature that exceeds the melting temperature, TM, of a metal phase, in accord with the method of the invention. Figure 2 is a Differential Thermal Analysis of the Bi j C-Al system. Figure 3 shows the effect of compact composition and greenware density on pressing temperature increase for the B| } C-A1 system. Figure 4 is a diagram useful for determining the amount of metal content necessary for densification of a ceramic-metal compact. Figure 5 is a graph showing the effect of the amount of metal content on densification of the Bi j C-Al system. Figure 6 shows the effect of metal content at initial heating temperatures on induced temperature, T 2 , for the B^C- Al system. Figure 7 depicts ΔT for the B^C-Al system as a function of metal content and initial heating temperature. Figure 8 shows ΔT as a function of pressing pressure for initial heating temperatures. Figure 9 is a scanning electron photo¬ micrograph (SEM) of a B]C-30 volume percent Al composite of the invention. Figure 10 is a SEM of a SiB6/SiB4 - 30 volume percent Al composite of the invention. Figure 11 is a SEM of a SiC - 50 volume percent Al composite of the invention. A ceramic-metal system to be densified, applying classical models of liquid phase sintering, must satisfy thermodynamic criteria of capillarity and compatibility. Densification takes place in three stages: (1) rearrangement; (2) solution- reprecipitation; and (3) solid phase sintering. Very often, however, ceramic-metal systems deviate from this model and are characterized by mutual insolubility and/or strong chemical reactivity. Where both constituents are thermodynamically compatible, i.e., non-reactive, the main densification mechanism is phase rearrangement caused by capillary forces. Where the solid and liquid are in a state of thermodynamic incompatibility, the ceramic and metal components react to complete depletion of one of them. For many ceramic-metal systems, the kinetics of the chemical reaction are faster than the kinetics of densification. As a result, difficulties have been encountered in developing many potential ceramic-metal composites. For example, as the reaction proceeds, newly formed ceramic phases bridge ceramic grains such that further rearrangement becomes impossible. The rate of chemical reaction for many ceramic- metal systems may be reduced by processing at lower temperatures. However, as a consequence, wetting may then be very difficult to achieve, which explains the general lack of success of the prior art lower temperature pressing processes in achieving 100 percent densified composites. Drastically higher pressures often employed as described in the prior art noted above also did not succeed in fully densif ing ceramic-metal composites. When a ceramic-metal mixture or composite of two or more constituents or phases is dynamically compacted and only one phase, such as a metal phase is deformable, the density change of the composite observed in response to pressure is due only to the deforming phase. If a major constituent present, such a ceramic phase, is substantially non-deformable, applied pressure causes densification through rearrangement to a point where a rigid skeleton forms and then rearrangement stops. The rigid skeleton formed by particles of hard ceramics, makes deformation of any soft metal located in the ceramic interstices impossible and the system has lost its driving force to shrink further. Further densification will not take place even where a deformable metal phase is present 10 and high pressures are exerted upon the compact, unless the pressures exceed those at which ceramic grains fragment. Further densification of ceramic-metal systems - t - will occur, however, in accord with the method of the invention, where there is a significant liquid metal phase present in the compact. The prior art densification processes rely upon pressure forces alone or capillary forces alone or some combination of the 0 two forces that does not account for their interaction. It is a key element of the present invention to replace or supplement the internal capillary forces of a given, particularly non-wetting, system with a carefully selected and interrelated pressure-temperature regime 5 that first, creates a substantial liquid metal phase and, secondly, pushes the liquid metal into ceramic grain interstices to achieve fully dense products. Careful selection of the regime insures that unwanted 0 grain growth and multiple ceramic phases are not generated. Thus, densification of the ceramic-metal mixture takes place through plastic deformation of ceramic (generally very limited) and through rearrangement of the ceramic grains. Final rearrangement of the ceramic grains is controlled by the behavior of the liquid metal phase, which in turn is affected by such factors as wettability, solid in liquid solubility and kinetics of chemical reactions. Liquid appearance in the composite system drastically changes ceramic-metal densification behavior under applied pressure. For example, it was discovered through compaction experiments with B4C-3O volume percent Al composites that densities ranging between 73 and 99 percent of theoretical density are 10 possible where there is absence or presence, respectively, of a liquid metal phase in the composite during compaction. The difference in results is thought to be due to the liquid metal phase causing ιr - extensive surface lubrication of the ceramic grains, wherein the grains slip by one another in the densification process forming a more compact, more dense product. The extent of this effect depends upon interaction between solid ceramic particles and liquid 20 metal. Even though compaction may last only a few seconds, liquid may remain in contact with the ceramic particles much longer depending upon the size of the compact, the processing method employed, compaction temperature and other system parameters. 25 Thus, a proposed densification mechanism applicable to the method of the invention is: (1) formation of a liquid metal phase; (2) collapse of the ceramic phase structure under applied load; and 30 (3) injection of molten metal between ceramic grains. An important factor in achieving 100 percent, void-free densification is also the presence of a sufficient amount of metal to completely fill all the voids and interstices of the ceramic material. The amount of metal required for densification depends upon specific system characteristics and must be determined for each system. In the method of the invention a most essential part of the invention is that the metal phase of the ceramic-metal mixture or composite must form a melt which, under the influence of rapidly applied high pressure, is injected between the ceramic grains, caus¬ ing the ceramic structure to collapse and densify. A second critical component of the invention is that the temperature increase of the composite during densifica¬ tion is limited both in absolute value and duration such that no significant chemical reaction occurs between the ceramic and metal materials present. By "no significant reaction" it is meant that any newly formed phases are not present in an amount sufficient to bridge ceramic grains making their further rearrangement impossible or to undesirably affect product characteristics or to deplete liquid metal such that full, substantially void-free density cannot be achieved. The method of the invention requires that the limited temperature increase is induced by a rapid application of high pressure for a few seconds followed by release of pressure and cooling of the finished, fully densified composite.- Referring to* Figure 1 , the method requires first heating the ceramic-metal mixture or compact to a temperature T-- that approximates but is below the tem¬ perature T M at which the metals present in the system begin to melt and flow. The mixture or compact is then subjected to a pressing step wherein the application of high pressure causes a change in volume of the composite that results in an quasiadiabatic temperature increase ΔT to temperature T 2 that exceeds the temperature T M . The formation of the liquid metal phase acts as a lubricant that aids in the final densification. The temperature T 2 is held only momentarily and the composite then is cooled. Prefer¬ ably, the area in the triangle above T*^ is minimized to avoid the opportunity of adverse reactions between the metal and ceramic phases which is particularly impor¬ tant for chemically incompatible systems. It is also an advantage to minimize the duration of the tempera¬ 10 ture spike for non-wetting ceramic-metal systems in order to minimize liquid migration after densification. Determination of the temperature parameters T-*, 2 » ΔT and T M of the method of the invention requires - c - care, particularly where incompatible ceramic-metal composites are to be formed. Of initial concern is the determination of T » the peak temperature of the pro¬ cess. T2 is selected such that it does not reach tem¬ peratures where significant adverse reactions between 20 ceramic and metal components occurs. Selection of T 2 is preferably based upon knowledge of the reactivity of the particular ceramic-metal system. Such information is obtainable from the literature or by employing techniques such as high temperature X-ray diffraction 25 or differential thermal analysis (DTA) . Referring to Figure 2, a DTA for B C-30 volume percent Al is shown. The DTA shows that a strong exothermic reaction takes place at about 700°C. System 30 densification is known to be slower than the kinetics of the chemical reactions between ceramic and metal. If held at 700°C, up to 3 different ceramic phases will form that are detrimental to finished product quality of the boron carbide ceramic. It is also well-known that the Bi j C- l system is a non-wetting system below 1150°C. Thus, to achieve densification at temperatures below wetting temperatures the method of the invention employs high pressure to assist capillary forces in forcing the metal component into the interstices between the ceramic grains. Based upon an examination of Figure 2, one notes a T M of about 660°C and a first reaction at about 700°C. Consideration of these factors leads to selection of T2 at less than 700°C in order to avoid forming undesirable ceramic phases. It is noted that the boron carbide-aluminum system is extremely difficult to process by conventional methods and that densification of this system by the method of the invention demonstrates that other such difficult to densify systems may also be densified. Having determined and selected the peak temperature T2 for the system it is now possible to calculate the increase in the temperature ΔT for a given system and pressure and, hence, determine the initial heating temperature T-*. The determination of ΔT utilizes a model based on the fact that, in order to change the volume of a compact under pressure, work has to be done in the system. As contemplated herein the system approaches an adiabatic process or is "quasi¬ adiabatic" since there may be minor heat losses, depending upon the particulars of the system. In such a quasiadiabatic system, work (W) performed in compaction may be defined by the expression: W = p(Vf-Vo) where: p is applied pressure Vf is composite volume after compaction V 0 is composite volume before compaction. The temperature of the ceramic-metal system increases due to the work expended upon two components, plastic and elastic deformation of the system. The total temperature increase ΔT is the sum of ΔTE and ΔTp. ΔTE » due to elastic deformation, can be calculated from the following equation: 10 3a p T-, ΔTE = QT C 0 where: a is the linear coefficient of thermal expansion for the ceramic/metal system -,- p is applied pressure T- j is initial heating temperature Q-- is theoretical density of the ceramic/metal system Co is the heat capacity of the 20 ceramic/metal system. Assuming quasiadiabatic behavior of the composite- pressing system, wherein the composite is typically embedded in a glass pressure-transmitting medium, all 25 work done on the system goes into heat. Then, temperature increase due to a plastic deformation,ΔTp, can be described by the following equation: where: p is applied pressure, Qo is green density, Qf is final density, Co is heat capacity of the ceramic/metal system, T m is melting temperature of the metal, T- j is initial heating temperature of the system, Lm is latent heat of the metal, Wm is weight percent of the metal, and Co' is heat capacity of the composite wherein metal is molten. ΔT is affected by a number of system character¬ istics that must be taken into account in estimating ΔT. For example, Figure 3 shows final temperature T2 plotted against metal content for ceramic-metal compacts of different initial or green densities, ranging between 50 and 90 percent of theoretical density. T-- in this B4C-AI example is 625°C. The curves suggest that the lower the metal content and the lower the green density, the higher will be the temperature increase. The calculations employed in generating Figure 3 assume that the final density of the system is equal to the theoretical density. It is impossible to densify a Bj j C-Al system, or any other ceramic-metal system, unless there is a sufficient amount of metal present. Establishing the temperature parameters for the method of the invention thus also requires determination of the amount of metal required for full densification. Assuming that sufficient pressure is available, that the ceramic phase does not deform significantly and that a sufficient liquid phase appears in the system, it is possible to predict composite behavior during compaction and approximate the amount of metal required for full densification. Generally, the determination requires a knowledge of the wettability of the metal- -ceramic system, the degree of compatibility between the components and the ability of the ceramic phase to deform. Wettability can be determined by measuring the actual contact angle of the liquid phase metal on the solid ceramic phase, as taught by Halverson et al, cited above. Evidence of compatibility of particular ceramic metal systems is generally available in the literature. From these elements, assuming no significant deformation of the ceramic system, processing a map or diagram can be established for densification of ceramic-metal composites. Referring to Figure 4, such a map is presented. At the zero point of the diagram, ceramic-metal mixtures are characterized by non-wetting conditions (contact angles greater than 90°C) and by chemical compatibility, permitting a prolonged contact between phases without chemical reactions occurring. B^C/Cu or C/Cu are typical examples, characterized by contact angles greater than 90° over a wide temperature range. Moving up on the diagram, still in the region of the vertical or yaxis, ceramic-metal systems with improved wetting (as a function of temperature) but negligible solubility, e.g., TiB 2 -Ni, TiB 2 /Al and A1B- | 2-A1, are indicated. In the direct neighborhood of the zero coordinates, obtaining highly consolidated materials is very difficult. As a result, large amounts of metal are required, on the order of 40-50 volume percent of the composition. Movement along the horizontal or x-axis in either right- or left-hand directions indicates changing solubility of solid ceramic in the liquid metal. The fundamental difference between the left and right halves of the diagram is the composition of the reaction products that form. In systems located on the lefthand portion of the diagram, the metal dissolves ceramic. However, precipitating phases have similar or identical chemistry to the starting composition. The . amount of liquid present depends on the solubility limit and can exceed the amount of the introduced metal by many times. In systems appearing on the righthand portion of the diagram, the formation of binary and ternary phases of new chemical compositions takes place. The amount of liquid is always lower than the amount of metal introduced and in extreme cases complete liquid depletion can take place. The closer the location of the ceramic-metal system to the upper left-hand corner of Figure 4, the easier it is to obtain high density with a small quan- tity of metal. For example, WC/Co, WC/Fe or TiC/Ni-Mo can be fully consolidated with 2-10 percent of metal. Those compositions appearing higher on the y-axis, in the right hand corner of the diagram, generally require 20-30 volume percent of metal in order to attain full density. The advantage of this type of chemical compatible ceramic-metal system is that wetting is possible to achieve without significant change in material composition and precise determination of the heating temperature T- j is not as critical as in the case of chemically incompatible systems. The closer the ceramic-metal composite is situated to the bottom right-hand corner of Figure 4, the more difficult it is to obtain highly densified materials. This is especially true for systems con- taining more than 60 volume percent of a ceramic phase. Therefore, many of these composites have never been obtained heretofore. Lack of wetting combined with fast chemical reactions create an ideal situation for the application of the method of the present invention. The method of the invention can be used to consolidate all types of ceramic-metal compositions to form composites or cermets. However, its advantage over other techniques is best illustrated by the consolidation of the ceramic-metal systems shown in the right-bottom triangle of Figure 4. Figure 5 shows, for the non-wetting, incompa¬ tible systems of interest, here Bi j C-Al, final compact density as a function of metal content. Figure 5 indicates that at an initial temperature of 625°C and the application of 120 kpsi (827 MPa) , boron carbide ceramic alone can be densified to only 67 percent of theoretical density. By adding a molten aluminum metal phase, density increases to reach, at 30 volume percent, 99.2 percent of theoretical density. Referring to Figure 6, calculations for the B^C-Al system show the effect of metal content on the temperature T2 attained, for various indicated initial heating temperatures. Figure 6 shows that for the B4C-AI system pressed at 120 kpsi (827 MPa), a maximum temperature peak is induced at about 20 percent by volume metal content. Below and above this metal content, the temperature increase is lower. It is important to note that even though the material is heated only to 625°C initially, the compact experiences a temperature that exceeds the melting point of the metal. The same compaction conditions can result in differing ΔT and, as a result, the ceramic-metal system may have a liquid phase present or absent which in turn gives completely different microstructures and final densities. From a processing standpoint, presence of a liquid phase is required. For boron carbide-aluminum composites, the highest ΔT is at 20 percent of the metal. However, 30 percent metal is required in order to attain full density as shown in Figure 5. By increasing the metal content or changing green density, as shown in Figure 3, ΔT and T 2 can be controlled to 10 stay above but close to the metal melting point. The important mechanism of densification under pressure, i.e., plastic deformation, is not very effective for boron carbide-aluminum composites. At * c - about 600°C boron carbide is hard to deform and a large part of aluminum metal remains enclosed in cavities between boron carbide grains and does not experience any pressure. When the metal melts and liquid appears, the situation changes but factors such as wetting, 0 solubility and rate of chemical reactions must be considered. Solubility of boron carbide in liquid metal increases as a function of temperature. Wettability 5 increases (i.e., contact angle decreases) which usually helps in grain packing because the liquid phase acts as a lubricant. However, it has been found that at 625°C, density of the composite is 99.2 percent of theoretical density while at 900°C only 85 percent density is 0 achieved. This is so because the B^C-Al system is highly reactive. At higher temperature new phases are formed to such an extent that liquid metal is depleted. New phases bridge B^C grains creating a rigid skeleton and further rearrangement becomes impossible. At 660°C solubility of B^C and Al is low and the system is sub- stantially non-wettable (contact angle is greater than 90°C) and plastic deformation of the ceramic does not take place. Therefore, one needs to use metal in an amount required to fill all existing voids. With good packing of boron carbide this amount of metal is substantially close to 30 percent. Referring to Figure 7, the temperature increase ΔT, for the B] j C-Al system is shown as a function of metal content and a number of initial heating tempera¬ tures T- j ranging between 58θ°C to 640°C. The figure shows that the lower the initial heating temperature T- ] , the less sensitive the system is to composition change. At 58θ°C no practically usable adiabatic heating effect is attained. At 600°C there is only a narrow range of metal content where high density mater¬ ials can be achieved, i.e., at about 30 volume percent of metal. At 620°C and 640°C, the potential composition range is wider, i.e., above 30 volume percent. The higher the amount of B^C desired in the composite, the narrower the processing range where the boron carbide- aluminum composite can be successfully compacted. However, as the initial heating temperature T-- is increased, the longer the liquid phase will be in contact with ceramic and subject to undesirable phase formation. Thus, there is only very narrow processing range where the boron-aluminum composite can be successfully compacted. Referring to Figure 8, the induced temperature increase ΔT is shown as a function of pressing pressure for curves indicating various initial heating temperatures, T-*. Figure 8 shows that the quasiadiabatic compaction effect, i.e., the induced change in temperature from Ti to T2 leading to complete metal melting as a result of application of pressure, cannot be obtained at pressures lower than about 60 kpsi (413 MPa). By increasing applied pressure from 120 kpsi to 200 kpsi (827-1379 MPa) one can increase ΔT from 70°C to 150°C. At 300 kpsi (2069 MPa), ΔT is as high as 28θ°C. Therefore, from a ceramic-metal processing standpoint, limiting pressure is a significant consideration in establishing the limits of the method of the invention. In preparing the ceramic-metal mixtures for densification by means of the method of the invention, the ceramic and metal may be in the form of particles, platelets, whiskers or chopped fibers. The mixture should be mixed to a homogeneous composition in order to achieve a uniform microstructure in the finished composite. In general, the better the mixing, the less metal that must be used to achieve the same final density. Preferably, the ceramic and metal are in powder form that is first blended together by using colloidal mixing techniques, dry mixing or wet mixing. The blended mixture is then slip-cast and/or isostatically pressed to form a greenware that is a partially densified compact. The greenware is then heated to a temperature that is close to the metal melting point. The temperature to which material needs to be heated must be high enough to assure that after applying pressure the metal will form a maximum amount of liquid that is injected during pressurization between the grains causing densification and low enough to assure that the peak temperature attained is lower than the temperature at which extensive reaction takes place between the ceramic and metal phases. As noted above, the peak temperature T 2 for a given ceramic and metal system can be determined by using high tempera¬ ture X-rays diffraction or differential scanning calor- imetry techniques (as shown in Figure 2). When a reaction temperature for a given ceramic and metal system Is very close to the metal melting temperature, i.e., within less than 50°C to 8θ°C, then the initial heating temperature must be below the temperature of first liquid appearance. Exact heating temperatures for given pressures can be calculated from 10 thermodynamic pressure-volume-density data, as shown above, knowing the heat capacity of the ceramic, latent heat of the metal, material chemical composition, density of the greenware and heat capacity of the -.,- surrounding sample medium. When temperatures at which reaction between ceramic and metal phases takes place is higher than the metal melting point by more than 50°C to 80°C, the greenware can be heated at the metal melting point or above. The critical condition here is 20 that if substantial liquid metal movement takes place, then uniformity of microstructure is lost. Usually, fine metal particles are strongly oxidized on the surface. A layer of oxide provides 25 protection from direct contact between ceramic and fresh metal surfaces and also prevents liquid flow. With such metals the initial heating temperature depends to some extent on the degree of metal oxidation. Typically, for a metal like aluminum, the 30 temperature at which liquid flows for the oxidized material can exceed the pure metal melting temperature by 100°C to 250°C. When the greenware compact has achieved a uniform temperature, pressure is applied to the compact. The pressing step requires a rapid application of pressure to 60 to 250 kpsi, (4B-1724 MPa) applied at a rate of 5 to 250 kpsi/second (34 to 1724 MPa/sec. Fresh liquid metal appears in the mate¬ rial and acts as a lubricant assisting in compaction of the ceramic particles. The particles rearrange and the rigid ceramic structure collapses. Densification is achieved in a matter of seconds. After the desired density is achieved, the composite material may be cooled. The time from applying pressure to metal solidification depends on the magnitude of the pressure and initial heating temperature employed. The intent of the method of the invention is to reduce to a minimum the time in which there is direct contact between the metal and ceramic at a elevated temperature. The pressing step may employ any pressure technique that can apply the required high pressure and high rate of application to the greenware compact to be densified. A preferred method of pressing is the isostatic application of pressure that permits near net shape ceramic-metal composites of complex geometry. In one technique, ceramic-metal greenware is placed directly or indirectly, i.e., enclosed by protective foil or capsule, in a pressure-transmitting medium that is a gas, inorganic material, glass, ceramic, organic, plastic, oil or the like, wherein the medium is non- reactive or isolatable from the metal-ceramic composite. The ceramic-metal powder mixture is typically formed into a greenware compact by means of convention¬ al casting and the like techniques. The pressing step is preferably an isostatic means in which the greenbody composite is placed in an incompressible pressure transmitting medium and heated to a temperature slightly below the melting temperature of the metallic phase. The pressure transmitting medium and the green¬ body contained therein are rapidly adiabatically com- _5 pressed by the application of external forces to the pressure transmitting medium. The rate of application of the external forces should be sufficiently fast that quasiadiabatic conditions are achieved throughout the 10 body of the greenware. As a result of the work per¬ formed by the external forces on the compact during its densification, from 50 to 60 percent to 100 percent dense material, the temperature of the compact rises above the melting temperature of the metal, the metal 15 melts and under influence of the applied pressure penetrates into all small voids in the material completing densification of the compact to 100 percent of theoretical density. After pressing, the system is quickly cooled down and the liquid phase solidifies. 20 The method of the invention has distinct advantages over the conventional techniques. The cer¬ amic-metal compact spends only a few seconds to a few minutes above the melting temperature of the metallic 25 phase instead of several hours as required by the conventional techniques. This advantage permits densification of ceramic-metal systems that are characterized by incompatibility and fast reaction 30 rates between the ceramic and metals. Application of high pressure utilized in this method makes it possible to process ceramic-metal systems that are characterized by poor wetting between the molten phase and the ceramic The following examples demonstrate various aspects of the method and ceramic-metal components of the invention. The examples are for illustrative pur¬ poses only and are not intended as limiting. Example 1 - B^C-Al Composites Compositions of Bj j C-Al at 100-65 volume percent Bi j C and 0-35 volume percent Al metal were made and densified. The B^C was "1500 grit", manufactured by ESK of West Germany. The boron carbide was characterized by a density of 2.52 g/cm**--, a thermal expansion coefficient of 4.5 x 10~° ("K)" 1 , a heat capacity of 1.7 Joules/°K-g and an average particle size of 3 micrometers. The aluminum powder, having an average particle size of 6 micrometers, was obtained from Alcoa and was characterized by a density of 2.7 gm/crn^, a heat capacity C( solid )=0.9 Joules/°K-g and C( liquid )=1.1 Joules/°K-g, thermal expansion α=25 x 10~ 6 (°K)~ 1 , a latent heat of 95 calories/g and a melting temperature of 660°C (933 °K). The ceramic and metal powders were mixed in ethanol forming a homogeneous slurry that was cast on a plaster mold in the conventional manner to form a greenware compact. The greenware was then dried. The density of the greenware was 55 percent of theoretical. The Bi j C-Al greenware was encapsulated in a rubber bag and pressed isostatically at 45 kpsi (310 MPa) forming a greenware that was partially densified to about 65 weight percent of theoretical density. The partially densified Bj j C-Al compact was wrapped in Al foil, embedded in a glass pressure transmitting medium, heated to 625°C and dynamically pressed to 120 kpsi (827 MPa). Maximum pressure was reached in 3 seconds and held for 5 seconds. Table I reports metal percent by volume of the composition and percent of theoretical density achieved. The data of Table I is shown graphically in Figure 5. The effect of composition on peak tempera¬ ture T 2 is shown in Figure 6 for selected initial heating temperatures, T-]. Varying soaking temperature T- | for the B^C-A1 system produced the results shown in Table II for the Bi j C-30 volume percent Al system. The results indicate that a drastic change in density occurs between 600°C and 610°C when the liquid phase appears in the material. Thus, to maximize amounts of molten metal present in the composite during compaction, a temperature above 620°C needs to be employed during the initial heating step. On the other hand to minimize the amount of formation of undesirable ceramic phases, the maximum temperature T2. should be as close as possible to 660°C. ΔT, and, as a result, maximum temperature T 2 can be controlled by changing green density of the composite and/or metal content. Several processing regions, leading to high density B4C-AI cermets can be selected, as shown in Table III. Green 60-70 65-70 60-70 50-60 Density, % Temp. Ti, °C 625 635 640 625 Final 99.0 99.2 99.1 99.3 density, % *827 MPa By using higher soaking temperatures (T-*) dense Bi j C-Al composites can still be obtained. However, the composition of the compact will change because ceramic phases such as A1B 2 and Al^BC will form. Example 1 illustrates that very reactive, non- -wetting composites now exist. These composites are produced by the method of the present invention. Example 2 - B4C-30 Volume Percent Al The Bj | C and Al powders of Example 1 were uti¬ lized to produce a homogeneous 70 volume percent B^C-30 volume percent Al mixture. The powders were mixed in ethanol to form a slurry. One percent by weight of an organic binder was added to the slurry. Mixing was continued for one hour followed by drying, crushing and sieving the powder mixture through a 60 mesh (250 micrometers) sieve. The homogeneous mixture was next cold-pressed at 5 kpsi and then isostatically pressed at 45 (310 MPa) kpsi to form --inch diameter by έ-inch thick (1.27 cm x 0.61 cm) disks. The pressed samples were heated at 450°C for one hour in flowing argon to burn off the organic binder. The sample compacts were then wrapped in aluminum foil and placed in a castable ceramic open-shell purged with argon and filled with low viscosity lead-containing glass. The system was heated with temperatures registered by thermocouples placed in the glass next to the sample compacts. Separate sample compacts were heated to 58θ°C, 625°C, 800°C, 1025°C and 1180°C soaking temperatures (T- | ) for an average heating time of 2 hours. After the soaking temperature stabilized the sample compacts were removed from the furnace and placed into a press where the sample composites were compacted to 120 kpsi (827 MPa). The time required to reach maximum pressure was about 3 seconds and the time to achieve maximum temperature was 3-10 seconds. After cooling, the samples were removed from the glass and sandblasted. Densities obtained were as follows: The data show that a sudden density increase occurs when the liquid phase appears in the system. After reaching maximum density, further increasing of the soaking temperature results in a density decrease. The density decrease is due to the fast kinetics of chemical reactions of the B^C-Al system that leads to metal depletion and formation of new phases. These new phases bridge B^C grains making rearrangement of the grains under pressure impossible, thus resulting in lower density products. Example 3 - B^C-30 volume percent Al and Prior Art Processes Because the kinetics of chemical reactions between B^C and Al are so fast, the densification pro¬ cess has to be finished in a very short time. As a consequence, prior art techniques such as isostatic pressing do not result in high density composites. The method of the invention is the only technique that provides high density materials with chemistry and ceramic grain sizes close to the starting mixture c,harac_t.eri.st__i-cs. TABLE V Initial Final Final Aluminum Aluminum Density Techni ue used Content Content Percent of ® Method and composites of the invention Figure 9 is a scanning electron photo¬ micrograph of the Bi j C-30 volume percent composite of the invention. Example 4 - B^C-Cu Bj j C-Cu mixtures are characterized as extremely non-wetting with contact angles much higher than 90°. A composite was prepared by first coating the boron car¬ bide particles with nickel. The nickel coating, having a higher melting temperature than copper, permitted achieving sufficiently high temperatures without adverse reactions where good wetting of the ceramic particles by copper could be achieved. B^C powder of 15-25 micrometers was coated with nickel by the method of electro-less deposition. The deposition method required first cleaning the B4C material with HCL. Bi*C surfaces were then activated with a Pd catalyst. The activated B^C was mixed in a c- Ni bath at pH 9, resulting in complete Ni deposition on the B^C particles. The Ni coated B^C was mixed with Cu and formed into a greenware that was then placed in a die containing a glass pressure-transmitting medium. The system was heated to 1025°C and then dynamically compacted at 120 kpsi (827 MPa). A rapid temperature increase was induced in the compact sufficient to melt - c , the copper phase whereby the copper penetrated the coated boron carbide grains forming a densified product. The nickel layer was retained on the boron carbide particles and overall density was substantially higher than conventional compositions. The results 20 achieved are shown in Table VI. 25 30 ® Not an example of the invention 0 The method of the invention permitted achievement of 94 percent of theoretical density with a metal content substantially lower than the 40 volume percent required by conventional hot isostatic pressing processes. 5 Example 5 - SiBg/SiBi j -Al Compositions of SiB4/SiB6-Al at 100 to 50 volume percent SiB4/SiB6 and 0 to 50 volume percent of 0 Al were made and densified. A powder having a SiB6/SiBi ratio of 86/14 is employed and was produced by Cerac Co. The silicon borides mixture was characterized by a density of 2.42 g/cm3, an average particle size of 8 μm, and a heat capacity of 1.92 -*-* Joules/(°K) * g at a temperature range of 600 to 700°C. The Al powder, having an average particle size of 6 μm was obtained from Alcoa and was characterized by a density 2.7 g/cm3. 0 The ceramic and metal powders were mixed to form an ethanol slurry. A binder and dispersant was added to the slurry. The slurry was cast on a plaster mold, dried and isostatically pressed cold at 45 kpsi (310 MPa). Density of the greenware ranged between 57 to 63 percent of theoretical. After that composites were heated in flowing argon at 400°C to remove the binder. The SiBg/SiB^-Al composites were wrapped in aluminum foil and placed in the glass fluid die. The die was heated to 625°C and dynamically compacted at 120 kpsi (827 MPa). Table VII reports metal percent by volume of the composition and percent of theoretical density achieved. A summary of preferred conditions leading to producing dense, tough and strong silicon boride based cermets are as follows: Composition 25-35 vol % Al Mixing colloidal in ethanol Heating temp. H 625-635°C Pressure 120 kpsi (827 MPa) Time at pressure 5-10 seconds Green density 60-655& of theoretical Maximum temp. T2 <700°C Essentially fully dense composites were obtained with a metal content equal to or higher than 30 volume percent. The maximum temperature T observed was for composites with 30 volume percent of metal. ΔT can be controlled by varying metal content, green density and the initial heating temperature, T-*. Examples of final density, depending on green density and T-* temperature are shown in Table VIII, for SiB /SiBi - 30 volume percent Al. *greenware density The microstructure of the SiBg/SiBj j - Al composites produced is characterized by a homogenous distribution of SiBg and SiBj j in a continuous aluminum matrix, as shown in Figure 10. SiBg/SiB^ 30 volume percent Al composites have a density of 2.5 g/cm**** (100 percent theoretical), fracture toughness (measured by Chevron Notch technique) of 10.4 to 10.9 MPa»m , fracture strength (measured by 4 point bend test) of 80 to 90 kpsi (552 to 621 MPa) and hardness (Tukon microhardness tester with Knoop indentor) of 350 to 450 kg mm2. Example 6 - SiC-Al SiC platelets from American Matrix Co. were used. The SiC material was characterized by particle sizes of 50 to 100 μm and a specific gravity of 3.2 g/cm3. Al powder, having an average particle size of 6 μm (Alcoa) was characterized by a density of 2.7 g/cm3. The ceramic and metal powders were mixed mechanically by a dry mixing process. The powder mixture was cold pressed at 5 ksi (34 MPa) and isostatically pressed to 58 percent green density. The SiC - 50 volume percent Al composite was encapsulated in an Al container under vacuum and heated to 610°C. The temperature was stabilized for 10 minutes and then a pressure of 120 ksi was applied for 5 seconds. A density of 99.9 percent of theoretical composites were obtained. X-Ray diffraction did not show presence of Al^C . Figure 11 shows the microstructure of the densified composite. The method described above was repeated utilizing a mixture of SiBg and 30 volume percent Cu. The SiBg-30 volume percent Cu greenware was heated to 1232°C. In this case Cu melted before the dynamic pressing step. The resulting composite had a density of 99.9 percent of theoretical. A scanning photomicrograph shows large copper lakes suggesting that wetting must be poor for this system. The presence of the large copper lakes suggests that a more homogeneous structure could be achieved by heating and dynamically pressing such that lower temperatures result. The above-described method was repeated with a mixture of SiBg and 30 volume percent Si. Initial heating was to 1400°C followed by the dynamic pressing step. Calculated density for the fully densified com¬ posite is 2.37 g/cm3. Actual density was 2.38 g/cm**--. Grain sizes ranged from 30 to 40 micrometers.

Claims: 1. A method of densifying a ceramic and metal mixture or composite, comprising: forming a substantially homogeneous mixture of a ceramic and metal; heating said mixture to a first temperature that approximates but is below that temperature at which said metal begins to flow; and pressing said mixture at such pressure that compaction and densification of said mixture occurs and an induced, second temperature of said mixture results, wherein said second temperature exceeds the flowing temperature of said metal such that said mixture is further compacted and densified, said second temperature and duration thereof remaining below that at which significant reaction between said metal and ceramic occurs. 2. The method of Claim 1, further comprising: forming said mixture, before said heating step, into a partially densified compact or greenware. 3. The method of Claim 1 wherein said pressing pressure is applied at such a high rate of increase and for such a short duration that said second temperature profile is a spike of about 10°C to 200°C that is sufficient to improve densification but minimizes exposure of said mixture to temperature conditions at which significant reaction between said metal and ceramic occurs. 4. The method of Claim 3 wherein said temperature spike is 30 to 70°C. 5. The method of Claim 1 wherein said pressing is at least about 60 kpsi (413 MPa). 6. The method of Claim 1 wherein said pressing is at a rate of at least about 5 to 250 kpsi/second (34 to 1724 MPa/second). 7. The method of Claim 5 wherein said pressing is 60 to 250 kpsi (413 to 1724 MPa). 8. The method of Claim 2 wherein said pressing is achieved isostatically. 9. The method of Claim 8 wherein said pressing is characterized by encapsulating said partially densified compact in a non-reactive pressure transmitting fluid or fluidizable medium that is contained such that applying a pressure to said medium applies said pressure to said compact isostatically whereby said compact is further densified. 10. The method of Claim 9 wherein a first pressure is applied to said pressure transmitting medium at less than 60 kpsi (413 MPa) and said compact is partially densified. 11. The method of Claim 10 wherein said par¬ tially densified compact has a density of at least about 50 percent by weight of the theoretical density. 12. The method of Claim 10 wherein said par¬ tially densified compact remains encapsulated in said pressure transmitting medium for said heating and pressing steps to said second temperature. 13- The method of Claim 1, further comprising: cooling said densified compact, after pressing, such that no significant reaction between metals and ceramics occurs. 14. The method of Claim 1 wherein said mixture includes more than one ceramic and/or more than one metal. 15. The method of Claim 1 wherein said ceramic is Bi | C, SiC, SiBg, SiBj j , A1B 1 , A1B 2 . A1B-,2C 2 . AI BC, TiB, TiB 2 , TiC, 1 2 0 3 , MgO, mullite, Zr0 2 , MgSiθ3 » Mg 2 Siθ4, MgAl 2 0i j , M 2Al 2 Si5θ l8 . A1N, TiN, Si 3 Ni or mixtures thereof. 16. The method of Claim 1 wherein said metal is Al, Mg, Ti, Fe, Ni, Co, Mn, Si or their alloys. 17. The method of Claim 1 wherein said ceramic is at least 50 percent by volume of said mixture. 18. The method of Claim 1 wherein said mixture is characterized by ceramics and metals that are chemi¬ cally incompatible or reactive and are non-wetting. 19. The method of Claim 18 wherein said ceramic-metal is B^C-Al, A1B 12 -Cu, A1B"| 2 -Fe, SiC-Cu, or SiC-Al. 20. The method of Claim 18 wherein said ceramic is B^C and said metal is Al, Mg, or Fe. 21. • The method of Claim 1 wherein said mixture is characterized by ceramics and metals that are chemi¬ cally compatible or non-reactive and are wetting, wherein said ceramic-metal is TiB 2 -Al or WC-Co. 22. The method of Claim 1 wherein said mixture is characterized by ceramics and metals that are chemically compatible and non-wetting, wherein said ceramic-metal is B^C-Cu, A1N-A1 or AI2O3-AI. 23- The method of Claim 1 wherein said mixture is characterized by ceramics and metals that are chemically incompatible and wetting, wherein said ceramic-metal is B4C-Si. 24. The method of Claim 1 wherein said ceramics and metals are particles, platelets, whiskers or chopped fibers in physical form. 25. The method of Claim 1 wherein said heating and pressing steps are adjusted such that said second temperature and its duration is sufficient to achieve a desired reaction between said metal and ceramic. 26. The method of Claim 1, further comprising: selecting a first temperature and a metal content for said compact such that said pressing step achieves a second temperature that densifies said compact but is not sufficient to cause undesired reaction between said ceramics and metals. 27. The method of Claim 26 wherein said first temperature is selected by calculation from applied pressure, thermodynamic and physical characteristics of said ceramics and metals. 28. The method of Claim 2 wherein said compact comprises a metal content at least sufficient to achieve substantially theoretical density but ensures that said second temperature is insufficient to cause undesired reactions between said ceramics and metals. 29. A densified ceramic and metal composition, comprising: a ceramic, in an amount of at least 50 percent by volume of said composition, wherein said ceramic is B^C, SiC, SiBg, SiB^, AIB- ]2 , A1B 2 , A1B 12 C 2 . AI4BC, TiB, TiB 2 , TiC, A1 2 0 3 , MgO, mullite, A1N, or mixtures thereof; and a metal, wherein said metal is Al, Mg, Ti, Fe, Ni, Co, Mn, Cu, Si, or their alloys, and said composition is substantially fully dense. 30. A densified ceramic and metal composition, comprising: a silicon boride in an amount of 50 to 80 percent by volume of said composition, said silicon boride comprising at least one of SiB^, C - SiBg, SiB-ji j or their mixtures; and a metal, said metal comprising at least one of Al, Cu, Fe, Co, Si, Ni or their alloys. 31. The composition of Claim 30 wherein said 0 ceramic is SiB^ and SiBg in an amount of 50 to 75 volume percent of said composition. 32. The composition of Claim 31 wherein said metal is Al and said composite is of a desired density, approaching 100 percent of theoretical density. 33. The composition of Claim 32 wherein said metal is an aluminum alloy. 34. The composition of Claim 31 wherein said metal is Cu and said composite is substantially 100 percent of theoretical density. 0 35. A method of densifying a ceramic metal mixture or composite, comprising: forming a compact of a homogeneous mixture of ceramics and metals; 5 pressing said compact to a density of 50 to 65 percent by volume of the theoretical density for said mixture; 0 heating said compact to a first temperature that approximates but is below that temperature at which said metals begin to flow; pressing said compact substantially adiabati- c cally at a pressure of 60 to 250 kpsi (413 to 1724 MPa), at a rate of 5 to 250 kpsi/second (3*4 to 1724/sec) such that said compact is heated to a second temperature that exceeds said temperature at which said metals begin to 0 flow under pressure and said compact is densified; and releasing said pressure and cooling said com¬ pact sufficiently rapidly after said second temperature is achieved such that said ceramics and metals do not significantly react one with the other. 36. A ceramic-metal composite produced by the method of Claim 32, said densified composite having a composition and ceramic grain size substantially similar to the initial homogeneous mixture of ceramic and metal. 37. A ceramic-metal composite produced by the method of Claim 1 , said densified composite having a composition and ceramic grain size substantially similar to the initial homogeneous mixture of ceramic and metal. 38. The method of Claim 6 wherein said pressing is 60 to 250 kpsi (413 to 1724 MPa). 39. The method of Claim 14 wherein said ceramic is at least 50 percent by volume of said mixture.

Inventors: MCDONALD ROBERT R, PECHENIK ALEXANDER, PYZIK ALEKSANDER J, SNYDER IRVING G JR, MCDONALD, ROBERT, R., PECHENIK, ALEXANDER, PYZIK, ALEKSANDER, J., SNYDER, IRVING, G., JR.
Applicants: DOW CHEMICAL CO, THE DOW CHEMICAL COMPANY
Application year: 1989
Main classification: B22F1
IPC codes: B22F3, C22C1, C22C29, C22C32