Moisture-curing, polyurethane hot-melt adhesive compositions

Abstract: A quick-setting, moisture-curing hot-melt polyurethane composition having a first polyether-based polyurethane prepolymer having a Tg above room temperature and a second polyurethane prepolymer with a Tg below room temperature. The first prepolymer is prepared from a low molecular weight polyether. Preferably the second prepolymer is also polyether based and prepared from a high molecular weight polyether.

Description: The present invention relates to moisture-curing, polyurethane hot-melt adhesive compositions based on polyethers. Hitherto hot-melt materials including eva, polyester or polyamide have been used for fast bonding processes and automatic adhesive application requiring quick setting bonds but these have usually been applied at temperatures of about 150°-200°C. For example, solvent-free reactive polyurethane hot-melt materials, such as are disclosed in German specification DOS 2609266, solve the problem of high application temperatures by application of a low-viscosity hot melt at 100°C which sets by crystallisation. Such adhesive systems exhibit good thermolytic and hydrolytic stability when chain-extended and cross-linked by atmospheric moisture. However, bonds provided by these crystallising polyurethane prepolymers have low elasticity before curing resulting in low initial peel strength immediately after bonding and have a lower setting rate which depends on the crystallisation rate of the polyester used. Other reactive crystalline polyurethane hot melts, such as the adhesive compositions disclosed in German specification DOS 3236313, do show a better elasticity in the uncured state but have an undesirably high application temperature (approaching those of conventional hot-melt materials) and exhibit pot life problems at application. It is accordingly an object of the present invention to provide quick-setting, hot-melt adhesive compositions comprising polyurethane pre-polymers which have improved flexibility immediately after bonding whilst being heat stable and resistant to hydrolytic and chemical attack after curing. Our copending European patent application 89 303 222.7 describes and claims a quick setting, hot-melt polyurethane adhesive composition comprising a mixture of at least two amorphous polyurethane prepolymers; each polyurethane prepolymer providing a different glass transition point for said composition. Preferably the first polyurethane prepolymer has a glass transition point above room temperature and a second polyurethane prepolymer has a glass transition temperature below room temperature. These products are fast setting with high elasticity, even before curing. Polyethers such as polypropylene have low glass transition temperatures and little if any crystallinity and thys so not seem to lend themselves to the preparation of hot-melt compositions. According to the present invention a quick-setting hot-melt polyurethane composition comprising a first polymer and a second polymer, wherein: the first polymer is a polyether based polyurethane prepolymer having a glass transition point above room temperature and is prepared from a polyisocyanate and a polyether, the polyether having a molecular weight between 200 and 1000, the mole ratio of the isocyanate groups to the hydroxyl groups of the polyisocyanate and the polyether being from 1.1 to 2.0; and the second polymer is a polyurethane prepolymer having a glass transition point below room temperature and is prepared from a polyisocyanate and a polyol wherein the mole ratio of the isocyanate groups to the hydroxyl groups is between 1.1 to 3. Polyurethane prepolymers with Tg above room temperature may be prepared from low molecular weight polyethers (MW less than 1000) and polyisocyanates. Polyurethane prepolymers with Tg below room temperature may be prepared from high molecular weight polyethers, polyesters of polybutadienes and polyisocyanates. Preferably the second polyurethane prepolymer is also polyether based and prepared from high molecular weight polyether (MW greater than 1000) and polyisocyanates. A prepolymer with Tg above room temperature sets quickly on cooling down from the application temperature but gives a brittle bond at room temperature. A prepolymer with Tg below room temperature may be applied at a relatively low temperature, even as low as room temperature but the applied film tends to remain tacky and to remain elastic when cured. Such bonds are flexible down to the low glass transition point and little or no cohesion is observed before curing. A composition according to the present invention provides an optimisation of these two sets of properties, giving a fast-setting adhesive curing with atmospheric moisture to give flexible bonding over a wide temperature range. The compositions according to the present invention also avoid the hydrolytic degradation to which polyester polyurethanes are susceptible. Compositions according to the present invention may be prepared by mixing two separately-prepared prepolymers. The first polyurethane prepolymer with a high Tg (above room temperature) is prepared from a polyether polyol and a polyisocyanate. The polyol has a molecular weight between approximately 200 and 1000, preferably 250 and 800, most preferably approximately 400. Prepolymers of such products have a Tg above room temperature if NCO/OH ratio is kept sufficiently low. Reducing molecular weight of polyols and NCO/OH-ratio of prepolymers increases the Tg of prepolymers. Such products require higher application temperatures, are faster setting and give bonds which are more brittle. Prepolymers based on typical chain extenders such as propylene glycol are not suitable for the present invention. The polyols used may be any type of polyetherpolyols such as polypropylene oxide, polyethylene oxide polyoxybutylene or copolymers. Polyethyleneglycol-based products are less suitable because of their high water absorption. The polyisocyanate is preferably an aromatic diisocyanate such as 4.4'-diphenylmethane- or 2.4'-toluene-diisocyanate. Derivates with functionalities higher than two may also be used if NCO/OH-ratios for synthesis are kept sufficiently high. Aliphatic polyisocyanates can also be used but are generally found to be less suitable. The prepolymer with the high (above room temperature) glass transition point is prepared at a NCO/OH ratio of 1.1 to 2.0, preferably 1.15 to 1.5 and at temperatures above the application temperature of the final product, preferably between 80° and 140°C. For prepolymer synthesis, no catalyst is required but for faster curing of the final product any catalyst suitable for one part polyurethanes can be added in a quantity of 10 - 10,000 ppm, preferably 100 - 1000 ppm. For prepolymer synthesis from polyethers special stabilization is recommended. A variety of stabilizers like acids, β-dicarboxylic compounds and reactive isocyanates, as well as antioxidants, may be used. The polyurethane prepolymer with the low (below room temperature) glass transition point is also a reaction product of a polyol and a polyisocyanate. The polyol may be a linear or slightly branched polyether, polyester, polybutadiene or another OH-terminated polyol. Again polypropylene oxide, polyethylene oxide polyoxybutylene or copolymers are suitable polyethers and these have a molecular weight of more than 800, preferably more than 1000. Although polyether based polyurethanes are preferred, polyurethane prepolymers with Tg below room temperature based on polyesters or polybutadienes can be used for the present invention as well as non reactive polymers with low Tg like polyolefins and their copolymers, high molecular weight polyesters, polyethers or polyurethanes. Generally we prefer to use diols in the compositions of the invention, but the use of polyols with higher functionality can result in superior final bonding properties due to crosslinking facilities (for details see examples described hereafter). The polyisocyanate used to prepare the compositions of the invention is preferably an aromatic diisocyanate such as 4.4'-diphenylmethane diisocyanate or 2.4-toluene diisocyanate or derivates with functionality higher than two but aliphatic diisocyanates may also be used. The prepolymer is prepared at a NCO/OH ratio between 1.1 and 3, preferably 1.2 and 2.5 and at temperatures between room temperature and 140°C, preferably between 60° and 100°C using stabilization as mentioned above, and with or without typical catalysts. The final product properties depend significantly on the types and mixing ratio of high and low Tg -prepolymers. If more prepolymer with high glass transition point is used, the adhesive is more viscous and initial strength is superior. Bonds are tougher but they are more inclined to be brittle at lower temperatures. By using more prepolymer with a lower Tg, the adhesive becomes less viscous, initial strength is lower and bonds are softer and more flexible. After application of the adhesive, the curing reaction with atmospheric moisture starts. Isocyanate reacts with water and carbon dioxide is formed. This often leads to unwanted foaming of the adhesive during curing. The degree of foaming depends on the quantity of carbon dioxide liberated, the reaction rate and the diffusion characteristics of the polymer system. The quantity of carbon dioxide can be controlled by NCO/OH ratio of prepolymers and molecular weight of polyols. The final product may also include usual and ingredients such as fillers, tackifying resins or plasticizers. The resulting mixture is usually transparent at room temperature and applied above the high Tg, preferably between 90° and 140°C. In order that the invention may be better understood preferred Examples will now be described in greater detail. EXAMPLE I Prepolymer A1 (Low Tg) 800 g (428 mVal) polypropylene oxide of molecular weight 4000 and 4.5 g toluolsulfonyl isocyanate are placed in a closed reactor at 60°C, 107 g (855 mVal) methylene diphenyl diisocyanate (MDI) are added and the temperature raised to 110°C for two hours. 1.8 g dibutyl tin dilaurate (DBTL) are added and stirred for further 15 minutes at 110° - 115°C under vacuum. The prepolymer has a viscosity of 620 mPas at 130°C, a NCO-content of 406 mVal/kg and a glass transition point of approximately -60°C. Prepolymer B (High Tg) 351.3 g (2806 mVal) MDI are melted at approximately 40°C in a closed reactor. 4.3 g toluolsulfonyl isocyanate and 500 g (2375 mVal) polypropylene oxide of molecular weight 400 are added. After heating one hour at approximately 60°C and one hour at 120°C, 0.9 g DBTL are added and stirring at 120°C is continued for 20 minutes. The prepolymer has a viscosity of 22 Pas at 130°C, a NCO content of 520 mVal/kg and a glass transition point of approximately +22°C. Formulation of Adhesive Composition (I) 93.7 g of the prepolymer A1 are added to 856.5 of the prepolymer B at 120-125°C and stirred for approximately one hour. The mixture is a colourless, transparent liquid at 130°C with a viscosity of 12 Pas and a NCO-content of 485 mVal/kg. Differential Scanning Calorimetry (DSC) shows a glass transition point of approximately +7°C. The adhesive sets quickly and has good bond strength over a wide range of temperatures. (See the following tables). Foaming during curing is negligible if the thin layers of adhesive are applied. EXAMPLE II Prepolymer A2 (Low Tg) 80.4 g (642 mVal) MDI are melted at 44°C 2.4 g toluolsulfonyl isocyanate and 400 g (257 mVal) polypropylene oxide (triol) added. The temperature is raised to 117°C for approximately 1 hour. The prepolymer has a viscosity of 375 mPas at 130°C and a NCO-content of 829 mVal/kg. Formulation of Adhesive Composition (II) 860.6 g prepolymer B from Example I are placed in a reactor at 130°C, 107.7 g prepolymer A2 are added and stirring is continued for 2 hours. The mixture is a colourless, transparent liquid at 130°C with a viscosity of 12 Pas and a NCO content of 554 mVal/Kg. The adhesive sets quickly and has good bond strength over a wide range of temperatures. High temperature strength is improved (see following tables). Foaming is avoided by applying the adhesive thinly. EXAMPLE III Prepolymer A3 (Low Tg) 800 g (507 mVal) of an amorphous polyester from 1.6 hexane diol and a mixture of adipic acid and isophthalic acid with a molecular weight of 3500 sulfonyl isocyanate 4.6 g p-toluol are placed at 80°C in a reactor with 127 g (1015 mVal) MDI are added under stirring and the temperature raised to 80°C for 30 min and then to 127°C for 45 min. After degassing under vacuum, a prepolymer A3 with a viscosity of 9 Pas at 130°C and a NCO content of 555 mVal/kg is obtained. Formulation of Adhesive Composition (III) 855 g prepolymer B according to example I are placed in a reactor of 130°C and 92.7 g prepolymer A3 are added and stirred for 1.5 hours at 130°C. The mixture is a colourless, transparent liquid at 130°C with a viscosity of 20 Pas and a NCO content of 500 mVal/kg. The adhesive sets quickly and has good bond strength to a variety of plastics. (see following tables) Foaming during curing is avoided by applying the adhesive thinly. Initial Strength (measured after 10 minutes) Tensile shear strength Wood (N/mm²) Peel strength canvas (N/mm) EXAMPLE I 1.8 2.8 EXAMPLE II 1.0 3.0 EXAMPLE III 1.5 0.8 Final Bond Strength Tensile shear strength (wood) (N/mm²) r.t. 100°C 150 EXAMPLE I 7.8 1.6 1.3 EXAMPLE II 8.4 1.9 1.4 EXAMPLE III 10.2 0.8 0.7

Claims: A quick-setting hot-melt polyurethane composition comprising a first polymer and a second polymer, wherein : the first polymer is a polyether based polyurethane prepolymer having a glass transition point above room temperature and is prepared from a polyisocyanate and a polyether, the polyether having a molecular weight between 200 and 1000, the mole ratio of the isocyanate groups to the hydroxyl groups of the polyisocyanate and the polyether being from 1.1 to 2.0 ; and the second polymer is a polyurethane prepolymer having a glass transition point below room temperature and is prepared from a polyisocyanate and a polyol wherein the mole ratio of the isocyanate groups to the hydroxyl groups is between 1.1 to 3. A hot-melt polyurethane composition according to claim 1, wherein said first prepolymer is prepared from polypropylene oxide, polyethylene oxide or polyoxybutylenes. A hot-melt polyurethane composition according to claim 1 or 2, wherein said second polyurethane prepolymer is also polyether based. A hot-melt polyurethane composition according to claim 1 or 3, wherein said second polyurethane prepolymer is prepared from linear or slightly branched polyethers, polyesters, polybutadienes or other OH-terminated polyols. A hot-melt polyurethane composition according to one of claims 1 to 4, wherein the prepolymers are prepared from aromatic diisocyanates. A hot-melt polyurethane composition according to one of claims 1 to 5, comprising said first prepolymer and said second prepolymer in a ratio between 99:1 and 1:99. A hot-melt polyurethane composition according to one of claims 1 to 6, further comprising at least one additional ingredient selected from fillers, tackifying resins and plasticizers. Use of a polyurethane composition according to one of claims 1 to 7 as an adhesive. Use of a polyurethane composition according to claim 8 wherein the said composition is applied above the glass transition point of the first polymer. Use of a polyurethane composition according to claim 9 wherein the said composition is applied between 90° and 140°C.

Inventors: GILCH HEINZ GERHARD, RATH WALTER, GILCH, HEINZ GERHARD, RATH, WALTER
Applicants: BOSTIK FRANCE, BOSTIK GMBH, BOSTIK LTD, BOSTIK FRANCE SA, BOSTIK LIMITED
Application year: 1989
Main classification: C08G18
IPC codes: C08G18, C09J175