Room temperature-curable organopolysiloxane composition

Abstract: Room temperature-curable compositions made from an organopolysiloxane having at least two silicon-bonded alkoxy groups per molecule, an alkoxysilane having three or four alkoxy groups per molecule, a mercapto group-containing alkoxysilane, and a curing catalyst produce cured materials under sealed storage stability, reversion resistance.

Description: The present invention relates to a room temperature-curable organopolysiloxane composition, and, more particularly, relates to a room temperature-curable organopolysiloxane composition which evidences an excellent adhesion for various and diverse substrates while having an excellent Storage stability under seal. Various types of room temperature-curable organopolysiloxane compositions which cure to the elastomer at room temperature upon contact with atmospheric moisture are already familiar to the art. Above all, because they are not accompanied by disagreeable odors and do not corrode metal with which they may be in contact, those types which cure with the release of alcohol are used as sealants, adhesives, and coatings for electrical and electronic devices and instruments. However, this type of room temperature-curable organopolysiloxane composition suffers from the problem of a poor adhesion for various substrates, such as glasses, metals, plastics, etc. FR-A 2 086 452 discloses a room temperature curable silicone composition which contains a polydiorganosiloxane with alkoxy groups as component (A) and alkoxysilane as component (B) and titanium and particulate talc with a catalyst. Moreover, US-A 4 579 636, GB-A 2 039 287 and DE-A 3 635 719 teach compositions which are curable at room temperature with moisture and/or high energy radiation. These compositions contain an hydroxy terminated polyorganosiloxane and a vinyl group containing siloxane together with a mercaptosilane. Thus, these compositions cure according to another mechanism than the composition known from FR-A 2 086 452. Problem to Be Solved by the Invention The present inventors achieved the invention under consideration as the result of extensive research directed at a solution to the aforementioned problem. The invention takes as its object the introduction of a room temperature-curable organopolysiloxane composition which has both an excellent adhesiveness for various and diverse substrates as well as an excellent storage stability under seal. The present invention relates to a room temperature-curable organopolysiloxane composition comprising (A) 100 weight parts organopolysiloxane having at least 2 silicon-bonded alkoxy groups in each molecule and having a viscosity of 20 to 500,000 mPa·s 25°C, excluding a material as defined for component (B) and (C) (B) 0.5 to 15 weight parts organosilane represented by the general formula R¹ a Si(OR²) 4-a wherein R¹ is a monovalent hydrocarbon group as defined in claim 1, R² is a monovalent hydrocarbon group as defined in claim 1 or alkoxy-substituted hydrocarbon group, and a is zero or one, or a partial hydrolysis condensate thereof, (C) 0.01 to 15 weight parts mercapto group-containing alkoxysilane represented by the general formula wherein R³ is a divalent organic group as defined in claim 1, R⁴ and R⁵ are substituted or unsubstituted monovalent hydrocarbon groups as defined in claim 1, and b is zero or one, or partial hydrolysis condensate thereof, and (D) 0.01 to 10 weight parts curing catalyst. Considering the preceding in greater detail, the component (A) used by the present invention is the base or principal material of the composition under consideration, and it is essential that it contain at least two silicon-bonded alkoxy groups in each molecule in order to obtain an excellent storage stability. Preferred among such components (A) are straight-chain organopolysiloxanes having the silicon-bonded alkoxy group at the molecular terminals as represented by the general structure wherein R⁶ is a monovalent hydrocarbon group; R⁷ is a monovalent hydrocarbon group or alkoxy-substituted hydrocarbon group; R⁸ is a group selected from among monovalent hydrocarbon groups, halogenated hydrocarbon groups, and cyanoalkyl groups; Y is an oxygen atom or a divalent hydrocarbon group; c is one, two, or three; and n is a positive number which gives a viscosity of 20 to 500,000 mPa·s at 25°C. Furthermore, it is also possible to use organopolysiloxane in which such a straight-chain organopolysiloxane comprises the basic structure, but which additionally contains a branched, cyclic, or network portion or moiety. Considering the above organopolysiloxane represented by general structure (1), examples of the monovalent hydrocarbon groups are alkyl groups such as methyl, ethyl, propyl, butyl, hexyl, octyl, decyl, and octadecyl; cycloalkyl groups such as cyclopentyl and cyclohexyl; alkenyl groups such as vinyl and allyl; aryl groups such as phenyl, tolyl, and naphthyl; and aralkyl groups such as benzyl, phenylethyl, and phenylpropyl. The halogenated hydrocarbon groups are exemplified by chloromethyl, trifluoromethyl, chloropropyl, 3,3,3-trifluoro-propyl, chorophenyl, dibromophenyl, tetrachlorophenyl, and difluorophenyl. Examples of cyanoalkyl groups are beta-cyano-ethyl, gamma-cyanopropyl, and beta-cyanopropyl. The group R⁷ is exemplified by alkyl groups such as methyl, ethyl, propyl, butyl, hexyl, and octyl, and by alkoxy-substituted alkyl groups such as methoxyethyl, ethoxyethyl, methoxypropyl, and methoxybutyl. It is preferred that R⁷ and R⁸ in each case contain 1 to 3 carbon atoms, and in fact the methyl group is particularly preferred. Y is to be an oxygen atom or a divalent hydrocarbon group, and examples of divalent hydrocarbon groups in this regard are alkylene groups such as -CH₂CH₂-, -CH₂CH₂CH₂-and -CH₂CH(CH₃)-. The viscosity of component (A) at 25°C should fall within the range of 20 to 500,000 mPa·s. Good physical properties, and particularly softness and a high elongation, cannot be imparted to the cured elastomer when this value falls below 20 cps. On the other hand, at values in excess of 500,000 mPa·s, the composition will have a high viscosity, and its workability during application becomes extremely poor. Accordingly, values within the range of 100 to 500,000 mPa·s are particularly preferred. The organopolysiloxane comprising component (A) can be prepared by various methods known to the art. For example, when Y in the above general structure (1) is an oxygen atom, synthesis can take the form of condensation between an alkoxy-silane and the corresponding silanol-terminated organopoly-siloxane in the presence or absence of catalyst. Catalysts usable in this regard are amines and the metal salts of carboxylic acids such as the zinc, tin, and iron salts of carboxylic acids. When the condensation reaction is conducted in the absence of catalyst, the reaction mixture is preferably heated to the reflux temperature of the alkoxysilane. When a catalyst is used, synthesis may be carried out by running the condensation reaction within the temperature interval from room temperature to the reflux temperature of the alkoxysilane. The molar ratio between the silanol groups in the organopolysiloxane and the alkoxy groups in the alkoxysilane in this condensation reaction should be at least 1 and preferably falls within the range of 5 to 15. Other condensation reaction methods for the preparation of the organopolysiloxane of component (A) comprise, for example, the reaction of the corresponding silanol-terminated organopolysiloxane and chlorosilane represented by the formula R¹ m SiCl(OR²) 3-m wherein R¹ and R² are defined as above, and m is zero, one, or two in the presence of a hydrogen halide binder such as pyridine, alpha-picoline, or other tertiary amines, as well as the condensation reaction between organopolysiloxane having silicon-bonded halogen at the molecular chain terminals and monovalent alcohol represent by the formula R²OH (R² is defined as above) in the presence of a hydrogen halide binder as above. When Y in the above general structure (1) is an alkylene group, component (A) can be prepared by the addition reaction, in the presence of a platinum catalyst, of the corresponding alkenyl-terminated organopolysiloxane and alkoxysilane represented by the formula wherein R⁶, R⁷, and c are defined as above, or by the addition reaction of the corresponding SiH-terminated organopolysiloxane and wherein R⁹ is an alkenyl group and R⁶, R⁷, and c are defined as above. Component (B) used by the present invention is a crosslinker for the composition of the invention under consideration, and it is the essential component for converting the composition of the present invention into a rubbery elastic substance by curing. This component comprises organosilane represented by the general formula R¹ a Si(OR²) 4-a wherein R¹ is a monovalent hydrocarbon group, R² is a monovalent hydrocarbon group or alkoxy-substituted hydrocarbon group, and a is zero or one, with the monovalent hydrocarbon groups and alkoxy-substituted hydrocarbon groups being exemplified as above or partial hydrolysis condensate thereof. Examples of component (B) are as follows: tetrafunctional alkoxysilanes such as tetramethoxysilane, tetraethoxysilane, and methyl Cellosolve orthosilicate; trifunctional alkoxysilanes such as methyltrimethoxysilane, methyltriethoxysilane, ethyltrimethoxysilane, vinyltrimethoxysilane, phenyltrimethoxysilane, and methyltrimethoxyethoxysilane; alkenyloxysilanes such as methyltrivinyloxysilane, methyltri(isopropenyloxy)silane, vinyltri(isopropenyloxy)silane, phenyltri(isopropenyloxy)silane, and tetra(isopropenyloxy)silane; and their partial hydrolysis condensates. These may be used individually, but it is also allowable to use mixtures of two or more species. Furthermore, the supplementary addition of difunctional alkoxysilane, such as diphenyldimethoxysilane, dimethyldimethoxysilane, etc., is permissible for the purpose of equipping the cured rubbery elastomer with a low modulus. The quantity of addition of component (B) should fall within the range of 0.5 to 15 weight parts and preferably falls within the range of 1 to 10 weight parts per 100 weight parts component (A). When this quantity of addition is too low, the composition of the present invention will not adequately cure, and during storage will suffer from an increase in viscosity and will readily gel. An excessive addition leads to slow curing and is uneconomical. The mercapto group-containing alkoxysilane (or partial hydrolysis condensate thereof) comprising component (C) used in the present invention is the crucial component for providing adhesion to various types of substrates. R³ in the general formula given above is a divalent organic group, and examples in this regard are methylene, ethylene, propylene, butylene, chloroethylene, fluoroethylene, phenylene, -CH₂OCH₂CH₂CH₂-, -CH₂CH₂OCH₂CH₂-, -CH₂OCH(CH₃)CH₂-, -CH₂OCH₂CH₂OCH₂CH₂-, and divalent organic groups comprising combinations of two or more of the preceding groups. R⁴ and R⁵ are substituted or unsubstituted monovalent hydrocarbon groups, and examples in this case are methyl, ethyl, propyl, octyl, phenyl, vinyl, and 3,3,3-trifluoropropyl. Alkyl and alkoxyalkyl are particularly preferred among these. Examples of the mercapto group-containing alkoxysilanes under consideration are as follows: gamma-mercaptopropyltrimethoxysilane, gamma-mercaptopropylmethyldimethoxysilane, gamma-mercaptopropyltriethoxysilane, gamma-mercaptobutyltrimethoxysilane, gamma-mercaptobutyltris(methoxyethoxy)silane, HSCH₂CH₂O(CH₂)₃Si(OCH₃)₃, and The addition of component (C) should fall within the range of 0.01 to 15 weight parts and preferably 0.05 to 10 weight parts per 100 weight parts component (A). When too little is added, adhesion to the substrate becomes inadequate from the standpoint of practical applications. On the other hand, an excessive addition is economically disadvantageous. Component (D) is a catalyst which promotes the curing reaction of the composition of the present invention. Operable curing catalysts are the tin, titanium, zirconium, iron, antimony, bismuth, and manganese salts of organic acids, as well as organotitanate esters and organotitanium chelate compounds. Concrete examples of useful curing catalysts are tin compounds such as dibutyltin dilaurate, dibutyltin dioctoate, stannous octoate, etc., and titanium compounds such as tetrabutyl titanate, tetraisopropyl titanate, diisopropoxybis(acetylacetone)titanium, diisopropoxybis(ethyl acetoacetate)titanium, etc. The preferred quantity of addition for this component is 0.1 to 5 weight parts per 100 weight parts component (A). The composition of the present invention, in addition to the preceding components (A) through (C), can also optionally contain microparticulate inorganic filler in order to improve the physical properties of the cured product and improve the flow properties prior to curing. Here, the quantity of addition should fall within the range of 1 to 200 weight parts and preferably 5 to 100 weight parts per 100 weight parts component (A). Examples of such inorganic fillers are dry-method silicas, wet-method silicas, quartz powder, calcium carbonate, titanium dioxide, diatomaceous earth, aluminum hydroxide, and microparticulate alumina, magnesia, zinc oxide, and zinc carbonate, as well as the preceding after surface treatment with, for example, silane, silazane, polysiloxane with a low degree of polymerization, or organic compounds. The composition of the present invention can include further components like organic solvents, diorganopolysiloxane with trimethylsilylated molecular chain terminals, flame retardants, plasticizers, thixotropic agents, general adhesion promoters, antimolds, etc. The composition of the present invention is obtained by mixing components (A) through (C) and the various optional additives while excluding moisture. The obtained composition is then stored as such in a sealed container, and cures to give a rubbery elastic substance upon exposure to atmospheric moisture when applied. It can be used as a so-called single-package room temperature-curable organopolysiloxane composition. The present invention will be explained in greater detail through the following illustrative examples. In the examples, comparison examples, and reference examples, parts = weight parts in all cases and the viscosity is the value at 25 degrees Centigrade. EXAMPLE 1 100 Parts alpha,omega-bis(trimethoxysilyl)dimethylpoly siloxane with a viscosity of 15,000 mPa·s and 12 parts dry-method silica (surface treated with hexamethyldisilazane, specific surface area = 110 m²/g by the BET method) were mixed at room temperature for 30 minutes. This was then further mixed at 5.3 KPa (40 mmHg) while heating to 180°C until homogeneous. In order to prepare the room temperature-curable organopolysiloxane compositions reported in Table 1, the following were then mixed to homogeneity into the obtained mixture while excluding moisture: 5 parts methyltrimethoxysilane, 1.5 parts diisopropoxybis(ethyl acetoacetate)titanium, and 0.5 parts gamma-mercaptopropyltrimethoxysilane or 0.5 parts gamma-mercaptopropylmethyldimethoxysilane. The products were then placed in aluminum tubes and stored under seal. The adhesion of these room temperature-curable organopolysiloxane compositions to various substrates was then measured, and the measurement results are reported in Table 2. Adhesion testing was conducted as follows. The room temperature-curable organopolysiloxane composition as described above was extruded in bead-form (width 15 mm x length 40 mm x thickness 5 cm) on the particular substrate according to the tab adhesion test method, and this was cured by standing for 7 days at 20°C and 55% RH. The obtained cured bead was pulled in order to separate it from the substrate surface, and the resulting peel surface was examined. The proportion of rupture in the cured layer is reported as the % cohesive rupture. For comparison, a room temperature-curable organopolysiloxane composition was prepared as above with the exception that the aforementioned mercapto group-containing alkoxysilane was not used. The result of adhesion measurement on this composition were as reported in Table 2. EXAMPLE 2 Room temperature-curable organopolysiloxane composition prepared as in Example 1 was extruded from an aluminum tube into a metal mold for sheet molding. A 2.5 mm-thick sheet was prepared by curing by standing for 7 days at 20°C and 55% RH. The physical properties of this sheet were then measured according to JIS K 6301. In addition, the aforementioned aluminum tube was placed in an oven maintained at 50°C, and thermal aging was carried out by allowing this to stand as such for 4 weeks. The physical properties of the thermally aged room temperature-curable organopolysiloxane composition were then measured as above. The various measurement results were as reported in Table 3. For comparison, a room temperature-curable organopolysiloxane composition was prepared as in Example 1 with the modification that an alpha,omega-bis(dihydroxy)dimethylpoly-siloxane with a viscosity of 15,000 mPa·s was used in place of the alpha,omega-bis(trimethoxysilyl)dimethylpolysiloxane with a viscosity of 15,000 mPa·s of Example 1. The physical properties of this composition were measured as described above, and these results were as reported in Table 3. EXAMPLE 3 A room temperature-curable organopolysiloxane composition was prepared as in Example 1 with the exception that gamma-mercaptopropylmethyldimethoxysilane was used in place of the gamma-mercaptopropyltrimethoxysilane of Example 1. The adhesion or bonding of this room temperature-curable organopolysiloxane composition for various substrates was measured as in Example 1, and these results were as reported in Table 4. SUBSTRATE ADHESION (% cohesive rupture) Aluminum 70 Copper 100 Glass 100 Epoxy resin 90 Polycarbonate resin 70 EXAMPLE 4 Room temperature-curable organopolysiloxane compositions as reported in Table 5 were prepared by the same procedures as in Example 1 and Example 2 with the exception that 100 parts calcium carbonate (average particle diameter = 2.2 µm) was used in place of the hexamethyldisilazane-treated silica of Example 1. For comparison, a room temperature-curable organopolysiloxane composition was similarly prepared as reported in Table 5 with the exception that mercapto group-containing silane, component (C) above, was not added. These compositions were subjected to adhesion testing as in Example 1, and these results were as reported in Table 6. EXAMPLE 5 100 Parts alpha,omega-bis(methyldimethoxysilyl)dimethyl polysiloxane with a viscosity of 13,000 mPa·s and 11 parts dry-method silica with a specific surface area of 200 m²/g (BET) were mixed for 30 minutes at room temperature, followed by additional mixing at 5,3 KPa (40 mmHg) to homogeneity. A room temperature-curable organopolysiloxane composition was prepared by mixing the following into this mixture to homogeneity while excluding moisture: 4 parts vinyltrimethoxysilane, 1.5 parts tetrabutyl titanate, and 0.5 parts gamma-mercaptomethyltrimethoxysilane. This composition was then subjected to adhesion testing as in Example 1, and these results were as reported in Table 7. For comparison, a room temperature-curable organopolysiloxane composition was prepared as above with the exception that the 0.5 parts gamma-mercaptopropyltrimethoxysilane was not added. This was also subjected to adhesion testing, and these results were as reported in Table 7. Because the room temperature-curable organopolysiloxane composition of the present invention comprises components (A) through (C), and particularly because it contains the organopolysiloxane comprising component (A) and the mercapto group-containing silane or partial hydrolysis condensate thereof comprising component (C), it is characterized by an excellent adhesion or bonding for various substrates and by an excellent storage stability under seal. Accordingly, it can be used as a construction sealant; as a sealant, adhesive, or anti-moisture coating for electrical and electronic components; and as a coating or adhesive for fibers and fibrous articles, glass articles, metal articles, and plastic articles, etc.

Claims: A room temperature-curable organopolysiloxane composition comprising (A) 100 weight parts of an organopolysiloxane having at least 2 silicon-bonded alkoxy groups in each molecule and having a viscosity of 20 to 500 000 mPa·s at 25°C, excluding a material as defined for component (B) and (C) (B) 0,5 to 15 weight parts organosilane represented by the general formula R¹ a Si(OR²) 4-a wherein R¹ is an alkyl, cycloalkyl, alkenyl, aryl or aralkyl group, R² is an alkyl, cycloalkyl, alkenyl, aryl or aralkyl group or alkoxy-substituted hydrocarbon group, and a is zero or one, or a partial hydrolysis condensate thereof and (D) 0,01 to 10 weight parts curing catalyst, characterized in that it further comprises (C) 0,01 to 15 weight parts mercapto group-containing alkoxysilane represented by the general formula wherein R³ is a methylene, ethylene, propylene, butylene, chloroethylene, fluoroethylene, phenylene, -CH₂OCH₂CH₂CH₂-, -CH₂CH₂OCH₂CH₂-, -CH₂OCH(CH₃)CH₂-, -CH₂OCH₂CH₂OCH₂CH₂- group or combinations of two or more of the preceding groups, R⁴ and R⁵ are substituted or unsubstituted alkyl, cycloalkyl, alkenyl, aryl or aralkyl groups, and b is zero or one, or partial hydrolysis condensate thereof. The room temperature-curable organopolysiloxane composition according to claim 1 in which the organopolysiloxane as represented by the general structure wherein R⁶ is an alkyl, cycloalkyl, alkenyl, aryl or aralkyl group; R⁷ is an alkyl, cycloalkyl, alkenyl, aryl or aralkyl group or alkoxy-substituted hydrocarbon group; R⁸ is a group selected from the group consisting of an alkyl, cycloalkyl, alkenyl, aryl or aralkyl group, chlormethyl, trifluoromethyl, chloropropyl, 3,3,3-trifluoropropyl, chlorophenyl, dibromophenyl, tetrachlorophenyl or difluorophenyl group and cyanoalkyl groups; Y is an oxygen atom or an alkylene group; c is two or three; and n is a positive number which gives a viscosity of 100 to 500 000 centipoise at 25°C. The room temperature-curable organopolysiloxane composition according to claim 2 in which the mercapto group-containing alkoxysilane is gamma-mercaptopropyltrimethoxysilane or (gamma-mercaptopropyl)methyldimethoxysilane.

Inventors: FUKAYAMA MIYOJI, ONISHI MASAYUKI, FUKAYAMA, MIYOJI, ONISHI, MASAYUKI
Applicants: TORAY SILICONE CO, TORAY SILICONE COMPANY, LIMITED
Application year: 1989
Main classification: C08L83
IPC codes: C08K5, C08L83