Detergent composition

Abstract: A detergent composition comprises (A) a nonionic surfactant represented by the general formula (I): R₁-O-(CH₂ ) x -(CH₂CH₂O) y -H (I) and having an HLB value of 3 or above but below 8, and (B) a phosphate surfactant represented by the general formula (II) or (III): or at least one lowly irritant anionic surfactant selected from among (i) N-acylglutamate surfactants, (ii) isethionate surfactants, and (iii) sulfosuccinate surfactants.

Description: The present invention relates to a novel detergent composition. Particularly, it relates to a body detergent composition which exhibits high detergency towards smear from makeup cosmetics such as lipstick or foundation or dirt due to sebum and exhibits low irritancy towards the skin or the hair. Smear from makeup cosmetics such as lipstick, foundation, eye shadow or mascara contains a lot of oil or solid fat, so that it cannot be removed with a conventional face cleansing foam mainly comprising a soap, because such a foam has insufficient solubilizing and emulsifying ability. Therefore, smear due to makeup cosmetics has been removed with a cleansing cream, oil or gel mainly comprising an oily base material. Dirt such as fat or keratinous protein enters the follicular orifices and solidifies therein to cause inflammation such as acne. Such solid dirt clogging the follicular orifices cannot be sufficiently removed with a conventional face cleansing preparation owing to its poor detergency, so that the simultaneous use of such a detergent with a keratolytic agent such as salicylic acid or sulfur has been the general practice. As described above, smear due to makeup cosmetics, solid fat such as sebum or hard oily dirt cannot be removed with a conventional face cleansing preparation mainly comprising a fatty acid soap or an anionic or nonionic surfactant, because such a detergent is poor in detergency. On the other hand, a cleansing cream mainly comprising an oily base material has another disadvantage in that moisture tends to break down the emulsion state of the cream, resulting in phase separation and lowered detergency when it is used in a high-temperature and high-humidity atmosphere such as in the bathroom. We have now found that a foaming detergent composition which exhibits high detergency against makeup smear and oily or fatty dirt and low irritancy towards the skin and which remains stable even in a high-humidity atmosphere can be obtained by combining a specified nonionic surfactant with a phosphate surfactant or at least one low irritant anionic surfactant selected from N-acylglutamate surfactants, isethionate surfactants and sulfosuccinate surfactants. Thus, the present invention provides a detergent composition comprising (A) a nonionic surfactant represented by the general formula (I): wherein R₁ stands for a branched, saturated or unsaturated hydrocarbon group having 4 to 30 carbon atoms; x stands for an integer from 0 to 30 and y stands for an integer from 0 to 30 with the proviso that x + y ≧ 1 , and having an HLB value of 3 or above but below 8, and (B) a phosphate surfactant represented by the general formula (II) or (III): wherein R₂, R₃ and R₄ each independently represents a straight-chain or branched alkyl or alkenyl group having 8 to 18 carbon atoms; X and Y each independently represents a hydrogen atom, an alkali metal, ammonium or an alkanolamine group having a hydroxyalkyl group having 2 to 3 carbon atoms and ℓ, m and n are independently integers from 0 to 10 or at least one low irritant anionic surfactant selected from among (i) N-acylglutamate surfactants, (ii) isethionate surfactants, and (iii) sulfosuccinate surfactants, or a mixture of any two or more of said surfactants. The nonionic surfactant represented by the general formula (I) to be used as the component (A) in the present invention must have both in HLB value of 3 or above but below 8, and a branched chain. In this specification, all HLB values are calculated according to the following equation of Oda and Teramura from organicity and inorganicity: If the HLB of the nonionic surfactant is below 3, the hydrophobic nature will be so strong that the surfactant will increase in oiliness to exhibit a remarkably lowered ability to foam, while if the HLB thereof is 8 or above, the hydrophilic nature will be so strong that the detergency and emulsifying power towards smear from makeup cosmetics will be poor. Thus, the HLB of the nonionic surfactant must be 3 or above but below 8, while it is particularly preferably from 6 to 7.5. Further, a nonionic surfactant having a straight-chain hydrocarbon group is too poor in detergency to attain the object of removing oily or fatty dirt according to the present invention, even if it has an HLB value falling within the above range. That is, only a nonionic surfactant having a branched hydrocarbon group and an HLB value falling within the range defined above can exhibit detergency enough to remove makeup smear or hard fatty dirt due to sebum. In the compound represented by the general formula (I) to be used as the component (A) in the present invention, preferred examples of the branched hydrocarbon group include secondary branched alkyl groups each having 4 to 30 carbon atoms or those selected from among 2-ethylhexyl, 2-ethyloctyl, 2-ethyldecyl, 2-ethyldodecyl, 2-butyloctyl, 2-butyldecyl, 2-butyldodecyl, 2-butyltetradecyl, 2-hexyldecyl, 2-hexyldodecyl, 2-hexyltetradecyl, 2-hexylhexadecyl, 2-octyldecyl, 2-octyldodecyl, 2-octyltetradecyl, 2-octylhexadecyl, 2-octyloctyldecyl, 2-decyltetradecyl, 2-heptylundecyl and methyl-branched isostearyl groups. Among them, branched secondary alkyl groups each having 10 to 14 carbon atoms and 2-hexyldecyl, 2-ethylhexyl, 2-octyldodecyl and 2-heptylundecyl groups are still preferred. Further, in the nonionic surfactant represented by the general formula (I), the numbers of the propylene oxide and ethylene oxide units added, x and y, may be each selected within the range 0 to 30. It is preferred that x be 0 to 30 and y be 1 to 20. It is particularly preferred that x be 0 to 4 and y be 3 to 10. It is preferred that the phosphate surfactant represented by the general formula (II) or (III) to be used as the component (B) in the present invention contain 0 to 3 ethylene oxide units added. It is particularly preferred that it contains no added ethylene oxide units and has an alkyl group having 12 to 14 carbon atoms. Preferred examples of the component (B) include sodium mono- or di-lauryl phosphate, potassium mono- or di-lauryl phosphate, diethanolamine mono- or di-lauryl phosphate, triethanolamine mono- or di-lauryl phosphate, sodium mono- or di-myristyl phosphate, potassium mono- or di-myristyl phosphate, diethanolamine mono- or di-myristyl phosphate and triethanolamine mono- or di-myristyl phosphate. Further, it is preferred to simultaneously use a compound represented by the general formula (II) and a compound represented by the general formula (III) in a weight ratio of between 10 : 0 and 5 : 5, particularly between 10 : 0 and 7 : 3, as the component (B). Among the surfactants to be used as the component (B) in the present invention, the N-acylglutamate surfactant includes compounds represented by the general formula: wherein R₂ stands for an alkyl or alkenyl group having 7 to 21 carbon atoms and M₁ and M₂ each stand for H, an alkali metal or a cationic group derived from an alkanolamine. Although the compounds represented by the general formula (IV) include L-form, D-form and racemic mixtures, any of them may be used in the present invention. Preferred examples thereof include N-lauroylglutamic acid, N-miyristoylglutamic acid, N-palmitoylglutamic acid, N-stearoylglutamic acid, N-cocoylglutamic acid and salts thereof with sodium, potassium, triethanolamine, monoethanolamine and diethanolamine. Among the surfactants to be used as the component (B) in the present invention, the isethionate surfactant includes compounds represented by the general formula: R₃-COOCH₂CH₂SO₃M (V) wherein R₃ stands for an alkyl or alkenyl group having 7 to 21 carbon atoms and M stands for H, an alkali metal or a cationic group derived from an alkanolamine. In the compound represented by the general formula (V), the fatty acid residue R₃-COO- includes those derived from lauric, myristic, oleic and coconut oil fatty acids, while examples of the counter cation represented by M include potassium, sodium, triethanolamine, diethanolamine and monoethanolamine. Among the surfactants to be used as the component (B) in the present invention, the sulfosuccinate surfactant includes sulfosuccinates of higher alcohols or their ethoxylates and sulfosuccinates derived from higher fatty acid amides, represented by the general formula (VI) or (VII): wherein R₄ stands for R₅O-(CH₂CH₂O) m - or R₆CONH-(CH₂CH₂O) m - (wherein R₅ stands for a straight-chain or branched alkyl or alkenyl group having 8 to 22 carbon atoms; R₆ stands for a straight-chain or branched alkyl or alkenyl group having 7 to 21 carbon atoms and m is 0 to 20) and M′ stands for H or a water-soluble salt forming cation selected from among alkali metals, alkaline earth metals, ammonium and organic ammonium derivatives. Among the compounds represented by the general formula (VI) or (VII), the sulfosuccinate of a higher alcohol or its ethoxylate includes disodium salts of sulfosuccinates of ethoxylates of secondary alcohols having 11 to 13 carbon atoms (for example, softanol MES-3, 5, 7, 9, 12; products of Nippon Shokubai Kagaku Kogyo Co., Ltd., each figure stands for the average number of ethylene oxide units added), disodium salts of sulfosuccinates of lauryl alcohol or lauryl alcohol ethoxylate (EO: 3, 6, 9, 12), disodium salts of sulfosuccinates of synthetic primary alcohols having 12 to 15 carbon atoms or their ethoxylate (EO: 2 to 4). Further, the sulfosuccinate derived from higher fatty acid amide includes disodium salts of sulfosuccinates of lauric polyethylene glycol (EO: 1, 2) amide, disodium salts of sulfosuccinates of oleic polyethylene glycol (EO: 1, 2) amide and sodium salts of sulfosuccinates of polyethylene glcyol (EO: 4) amide of coconut oil fatty acid. According to the present invention, the total content of the components (A) and (B) in the detergent composition is preferably 10 to 90% by weight, still preferably 20 to 60% by weight. Further, although the weight ratio of (A) to (B) may be arbitrarily selected in the range between 1 : 9 and 9 : 1, it is preferably between 1 : 9 and 4 : 6. In addition to the above low irritant anionic surfactant, the detergent composition of the present invention may further contain a conventional detergent such as fatty acid soap, alkyl sulfate or alkylethoxy sulfate, provided that the low irritancy and high detergency properties of the present invention are not adversely affected. Further, for the purpose of enhancing the ability to foam, the detergent composition of the present invention may further contain an anionic, amphoteric or nonionic surfactant in addition to the above essential components, provided that the effectiveness of the present invention is not affected adversely. Furthermore, it may further contain a thickener such as an anionic or nonionic polymer or other conventional additives, for example stabilizers, perfumes or dyestuffs. As described above, according to the present invention, a cleansing foam for the face or body which exhibits detergency high enough to remove makeup smear can be provided by combining a specified branched nonionic surfactant with at least one lowly irritant component selected from a phosphate surfactant, N-acylglutamate surfactants, isethionate surfactants, sulfosuccinate surfactants and their mixtures. The invention detergent imparts moistness to the skin and exhibits low irritancy towards the skin in spite of its high detergency. Further, the detergent composition can be used even in a high-humidity bathroom though it has been problematic to use conventional cleansing creams under such conditions. Furthermore, it can effectively remove the dirt clogging follicular orifices of the skin which causes acne. The present invention will be described in more detail by referring to the following non-limiting Examples: Example 1 Detergent compositions of the formulations given in Table 1 were prepared and tested according to the following methods. The results are also shown in Table 1. (1) Detergency test A. Artificially stained cloth method (a) Preparation of artificially stained cloth Artificial oily and fatty dirt were homogeneously dispersed in a solvent. A cotton cloth was brought into contact with the obtained dispersion and dried to make the dirt adhere uniformly to the cloth. The resulting cloth was cut into test pieces (10 cm x 10 cm) and used in the following test. (b) Conditions and method of cleansing A detergent composition was dissolved in hard water having a hardness of 4° DH to obtain 500 ml of a 3% (by weight) aqueous solution of the composition. The above test pieces were washed with this solution in sets of five in a Terg-O-Tometer under stirring at the rate of 100 rpm at 30°C for 5 minutes, rinsed with flowing water and pressed with an iron. The resulting cloths were examined for reflectance to determine the rate of cleansing. The evaluation was carried out according to the criteria which will be described. B. Pigskin method A lipstick was uniformly applied to a pigskin (2 cm x 2 cm) within a circular area having a diameter of 1 cm. After 30 minutes, 5 droplets of a 20% (by weight) aqueous solution of the composition were let to fall in the circle. The resulting pigskin was massaged with a flat glass rod for 20 seconds, rinsed with flowing water and dried. The lipstick remaining in the pigskin was extracted with hexane, followed by the UV spectrophotometry. Thus, the rate of cleansing was determined and evaluated according to the following criteria: Evaluation criteria O ○ : 80% or above ○ : 70% or above but below 80% ▵ : 60% or above but below 70% X : below 60% (2) Sensory evaluation Each of the detergent compositions was suitably diluted with tap water to prepare a foam. Seven expert panelits each washed the hands and face with this foam to evaluate the composition sensuously. A. Foaming Evaluation criteria O ○ : excellent foaming ○ : medial foaming ▵ : slightly poor foaming X : poor foaming B. Moistness and tenseness of the skin after the washing Evaluation criteria O ○ : moist without tenseness ○ : medial ▵ : less moist with tenseness X : no moist with tenseness Example 2 (1) monoethanolamine N-lauroylglutamate 35 (% by weight) (2) polyoxypropylene (PO 2) polyoxyethylene (EO 2) 2-ethylhexyl ether 15 (3) ethylene glycol distearate (Emanon 3201M) 3 (4) polytriethanolammonium acrylate (Carbopol 941) 0.5 (5) ethanol 5 (6) perfume a slight amount (7) ion-exchanged water the balance The above components (1) to (4) were dissolved in heated water, followed by cooling. The components (5) and (6) were added to the solution to obtain a face cleansing preparation. This preparation was effective in removing makeup smear and in cleansing the face to give a feeling of moistness. Example 3 (1) monotriethanolamine N-lauroylglutamate 10 (% by weight) (2) polyoxyethylene (EO 3.0) sec-tetradecyl ether 20 (3) triethanolamine myristate 10 (4) glycerin 8 (5) ethylene glycol distearate (Emanon 3201M) 3 (6) butylhydroxytoluene 0.2 (% by weight) (7) ethanol 3 (8) perfume a slight amount (9) ion-exchanged water the balance The components (1) to (6) were dissolved in heated water, followed by cooling. The components (7) and (8) were added to the resulting solution to obtain a face cleansing preparation. This preparation was effective in removing makeup smear and in cleansing the face to give a feeling of moistness. Example 4 (1) sodium cocoylisethionate 20 (% by weight) (2) polyoxypropylene (PO 5) polyoxyethylene (EO 5) 2-hexyldecyl ether 10 (3) myristic acid 1 (4) ethylene glycol distearate (Emanon 3201M) 3 (5) ethanol 2 (6) perfume a slight amount (7) ion-exchanged water the balance The components (1) to (4) were dissolved in heated water, followed by cooling. The components (5) and (6) were added to the resulting solution to obtain a face cleansing preparation. This preparation was effective in removing makeup smear and in cleansing the face to give a feeling of moistness. Example 5 (1) lauryl disodium sulfosuccinate 20 (% by weight) (2) polyoxyethylene (EO 4.0) 2-hexyldecyl ether 10 (3) myristic acid 1 (4) lauric acid 4 (5) ethylene glycol distearate 3 (6) ethanol 4 (7) α-tocophenrol 0.2 (8) perfume a slight amount (9) dyestuff a slight amount (10) ion-exchanged water the balance The components (1) to (5), (7) and (9) were dissolved in heated water, followed by cooling. The components (6) and (8) were added to the resulting solution to obtain a face cleansing preparation. This preparation was effective in removing makeup smear and in cleansing the face to give a feeling of moistness. Example 6 (1) sodium N-lauroylglutamate 10 (% by weight) (2) sodium cocolyisethionate 10 (3) lauryl disodium sulfosuccinate 10 (% by weight) (4) polyoxyethylene (EO 3.0) sec-tetradecyl ether 8 (5) myristic acid 5 (6) polyoxyethylene (EO 120) distearate 0.5 (7) salt 8 (8) polyethylene glycol 200 1 (9) perfume a slight amount (10) ion-exchanged water the balance The components (1) to (8) were dissolved in heated water, followed by the addition of the component (9). Thus, a pasty face cleansing preparation was obtained. This preparation was effective in removing makeup smear and in cleansing the face to give a feeling of moistness. Example 7 Detergent compositions of the formulations given in Table 2 were prepared and examined for performance according to the example 1. Results are also shown in Table 2. Example 8 (1) ditriethanolamine lauryl phosphate 30 (% by weight) (2) polyoxyethylene (EO 3.0) sec-tetradecyl ether 12 (3) ethylene glycol distearate (Emanon 3201M) 3 (4) ethanol 2 (5) perfume a slight amount (6) ion-exchanged water the balance The components (1) to (3) were dissolved in heated water. The obtained solution was cooled, followed by the addition of the components (4) and (5). Thus, a face cleansing preparation was prepared. This preparation was effective both in removing the smear due to makeup cosmetics and in cleansing the face to give a feeling of moistness. Example 9 (1) diethanolamine lauryl phosphate 35 (% by weight) (2) polyoxyethylene (PO 2) polyoxyethylene (EO 2) 2-ethylhexyl ether 15 (3) ethylene glycol distearate (Emanon 3201M) 3 (4) polytriethanolammonium acrylate (Carbopol 941) 0.5 (5) ethanol 5 (6) perfume a slight amount (7) ion-exchanged water the balance The components (1) to (4) were dissolved in heated water. The obtained solution was cooled, followed by the addition of the components (5) and (6). Thus, a face cleansing preparation was prepared. This preparation was effective both in removing the smear due to makeup cosmetics and in cleansing the face to give a feeling of moistness. Example 10 (1) diethanolamine lauryl phosphate 10 (% by weight) (2) polyoxyethylene (EO 3.3) sec-tetradecyl ether 20 (3) triethanolamine myristate 10 (4) glycerin 8 (5) ethylene glycol distearate (Emanon 3201M) 3 (6) butylhydroxytoluene 0.2 (7) ethanol 3 (8) perfume a slight amount (9) ion-exchanged water the balance The components (1) to (6) were dissolved in heated water. The obtained solution was cooled, followed by the addition of the components (7) and (8). Thus, a face cleansing preparation was prepared as in the preceding Examples. This preparation was effective both in removing the smear due to makeup cosmetics and in cleansing the face to give a feeling of moistness.

Claims: A detergent composition comprising (A) a nonionic surfactant represented by the general formula (I): wherein R₁ stands for a branched, saturated or unsaturated hydrocarbyl group having 4 to 30 carbon atoms; x stands for an integer from 0 to 30 and y stands for an integer from 0 to 30 with the proviso that x + y ≧ 1 , and having an HLB value of 3 or above but below 8, and (B) a phosphate surfactant represented by the general formula (II) or (III) wherein R₂, R₃ and R₄ each independently represents a straight-chain or branched alkyl or alkenyl group having 8 to 18 carbon atoms; X and Y each independently represents a hydrogen atom, an alkali metal, ammonium or an alkanolamine group having a hydroxyalkyl group having 2 to 3 carbon atoms and ℓ , m and n are independently integers from 0 to 10 or at least one low irritant anionic surfactant selected from among (i) N-acylglutamate surfactants, (ii) isethionate surfactants, and (iii) sulfosuccinate surfactants, or a mixture of two or more of said surfactants. A detergent composition as set forth in claim 1, wherein the total content of the components (A) and (B) in the detergent composition is from 10 to 90% by weight and the weight ratio of (A) to (B) is from 1 : 9 to 9 : 1. A detergent as set forth in claim 1, wherein said N-acylglutamate surfactant is a compound selected from among those represented by the general formula (IV): wherein R₂ represents an alkyl or alkenyl group having 7 to 21 carbon atoms and M₁ and M₂ each independently represents H, an alkali metal or a cationic group derived from an alkanolamine. A detergent composition as set forth in claim 1, wherein said isethionate surfactant is a compound selected from among those represented by the general formula (V). R₃-COOCH₂CH₂SO₃M (V) wherein R₃ represents an alkyl or alkenyl group having 7 to 21 carbon atoms and M represents H, an alkali metal or a cationic group derived from an alkanolamine. A detergent composition as set forth in claim 1, wherein said sulfosuccinate surfactant is a compound selected from among those represented by the general formula (VI) or (VII). wherein R₄ represents R₅O-(CH₂CH₂O) m - or R₆CONH-(CH₂CH₂O) m - (wherein R₅ represents a straight-chain or branched alkyl or alkenyl group having 8 to 22 carbon atoms; R₆ represents a straight-chain or branched alkyl or alkenyl group having 7 to 21 carbon atoms and m is 0 to 20) and M′ represents H or a water-soluble salt-forming cation selected from alkali metals, alkaline earth metals, ammonium and organic ammonium derivatives.

Inventors: ARISAWA MASATOSHI, KAJIHARA YASUSHI, KAMEGAI JUN, ARISAWA, MASATOSHI, KAJIHARA, YASUSHI, KAMEGAI, JUN
Applicants: KAO CORP, KAO CORPORATION
Application year: 1989
Main classification: C11D1
IPC codes: C11D1