FLUORINATION OF ACETALS, KETALS AND ORTHOESTERS

Abstract: This invention pertains to perfluoropolyethers and perhalogenated chlorofluoroether polymers that can be prepared by fluorinating polymers made by the polymerization of acetals, ketals, polyacetals, polyketals and orthoesters with elemental fluorine.

Description: II.!J21?.INAΪI2N__OF_ACETALS J ._KETALS AND ORTHOESTERS Perfluoropolyethers are highly regarded in the specialty lubricant field because of their wide liquid ranges, low vapor pressures and high thermal and oxidative stabilities. Because of these properties (many of which are unique to fluorocarbons) , they are excellent high performance lubricants, superior base stocks for greases, ex ellen lubricating oils, and heat transfer fluids. In addition, because of these uniquely outstanding properties, saturated perfluoropolyethers are of current interest as specialty sealants, elastomers and plastics. In spite of their unlimited potential, only three perfluoropolyethers are commercially available to date because of the lack of fluorocarbon intermediates which are suitable for preparing the polymers. They are: 1. DuPont's Krytox™ fluid which is made by polymerizing hexafluoropropylene oxide. 2. Deπmum™ fluid, a product of Daikin Industries, is obtained by ring opening polymerization of 2 , 2 , 3 , 3- etrafluoro- oxetane using a catalyst with subsequent treatment of the highly fluorinated polyether with fluorine gas to give a perfluorinated product. 3. Montedison's Fomblin Z w and Fomblin Y™ fluids which are prepared by pho ooxidizing tetrafluoroethylene and hexafluoropropylene oxide, respectively, in the presence of oxygen. A process has been described for preparing perfluoropolyethers by reaction of a hydrocarbon polyether with elemental fluorine in the presence of a hydrogen fluoride scavenger. See U.S. Patent No. 4,755,567. ^ mmary__ f_the ^ I_n e_ 3 .£n This invention relates to perf luoropolyether and perhalogenated chloro luoroether polymers that can be prepared by fluorinating polymers made by the polymerization of acetals , ketals , polyacetals, polyketals and orthoesters with elemental fluorine. The products formed by the present invention have essentially the following formula: ^3 X- [O-C ■0-Y] [0 -c- n 0-Y'l i m -oz R R 4 wherein Y and Y' are the same or different and are selected from the group consisting of linear and branched perfluoroalkylenes having at least 2 carbon atoms; perfluoroalkyleneoxyalkylene and perfluoro- pol (alkyleneoxyalkylene) each having alkylene groups containing at least two carbon atoms wherein in Y or Y' one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine; wherein X and Z are the same or different and are selected from the group consisting of -(CF_) COT , -(CF ) OCF -(CF ) COOH and C F Cl , wherein r λ r 6 r r __r+l-q q is an integer from 1 to 12 and q is an integer from 0 to 25 wherein R, , and R. are the same or different and are selected from the group consisting of -F, -Cl, -CF j Cl, -CFC1 2 , -CClg, perfluoroalk 1 of one to ten carbon atoms and perfluoroalkoxyalky1 of nπp t-o ten carbon atoms wherein one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine; wherein n is an integer from 2 to 1,000; and wherein m is an integer from 0 to 1,000; provided that when R. , R- , R, and R together are F then Y or Y' comprises an ethylene group having at least one fluorine atom which is substituted by a halogen other than fluorine. This invention also relates to perhalogenated polyethers of the formula: X-[0- fCi] -0Z II wherein R- , R„ , X and Z are defined above and n is an integer from 2 to 1000; provided that R. and R_ cannot both be fluorine atoms. The perfluoropolyethers and the perhalogenated chlorofluoropolyethers of this invention can be used as lubricants , hydraulic fluids , thermal shock luids, vapor phase soldering fluids and in numerous other applications in which an inert, nonflammable, oxidatively stable fluid is required. The low molecular weight perfluoropolyethers of the present invention have many useful applications in the electronics industry. D t ^l. d_D s_£r^£^^£ _o_f_the__I_ ve £^ n. In general, the perfluoropolyether and perhalogenated chloro luoropolyether polymers have the formula: R- R X-[0-C-0-Y] - [O-C-0-Y'j - OZ I R R R 2 R 4 wherein Y and Y' are the same or different and are selected from the group consisting of linear and branched perfluoroalkylenes having at least 2 carbon atoms, preferrably having 2 to 6 carbon atoms; perfluoroalkyleneoxyalkylene and perfluoropoly- (alkyleneoxyalkylene) each having alkylene groups containing at least two carbon atoms, preferably having from 2 to 30 carbons and most preferably having 4 to 8 carbons; wherein in Y or Y' one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine. Y and Y' can be isotactic perfluoropolyethers or atactic perfluoro¬ polyethers, such as -CF 2 CF 2 CF 2 , -CF 2 CF 2 CF 2 CF 2 - , CF 2 CF 2 OCF 2 CF 2 - , -CF 2 (CF 3 )CFOCF(CF 3 )CF 2 and CF 2 CF 2 OCF 2 CF 2 OCF 2 CF 2 - X and Z are the same or different and are selected from the group consisting of -(CF 2 ) r C0F, -(CF 2 ) r OCF 3 , -(CF^COOH and C F„ , . Cl , wherein r is an integer from 1 to 12 r 2r+l-q q ° and q is an integer from 0 to 25 1 ' ? ' R_ and R. 3 4 are the same or different and are selected from the group consisting of -F, -Cl, -CF.C1, CFC1 2 , -CC1 3 , perfluoroalkyl of one to ten carbon atoms , such as -CF 3 , -C.F " C - J F 7 and *C Δ F Q and perfluoroalkoxy- alkyl of one to ten carbon atoms, such as -0CF_ and -0CF , wherein one or more of the fluorine atoms in said perfluoroalkyl and perfluoroalkoxyalky1 may be substituted by a halogen atom other than fluorine. Preferably R. to R, are F and -CF_ groups. n is an integer from 2 to 1,000; and m is an integer from 0 to 1,000; provided that when R- , R_ , R„ and R, together are F then Y or Y' comprises an ethylene group having at least one fluorine atom which is substituted with a halogen atom other than fluorine, preferrably by chlorine. The n and m subscripts of formula I are average indices of composition such that when m is zero the polyether is referred to as an alternating copolymer of When m and n are greater than zero, the polyether is a terpolymer containing groups having random OY and OY' units along the polymer chain. The simplest member of this class of compounds is a 1:1 copolymer of difluoromethylene oxide and tetrafluoroethylene oxide which is the subject of U.S. Patent No. 4,760,198. This invention also relates to perfluoro¬ polyethers and perhalogenated chloro luoropolyethers of Formula I where Y and Y' are polyethers and have the average formula: X-[0-C-(0-CF 2 -CF) ] - [0-C-(0-CF 2 -CF) ] -0Z III R 2 R 5 4 R 6 wherein R- , R„ , R-, , R, , R_. and R fi are the same or different and are selected from the group consisting of -F, -Cl, -CF 2 C1, -CFC1 2 , -CC1 3 > perfluoroalkyl of one to ten carbon atoms and perfluoroalkoxyalky1 of one to ten carbon atoms wherein one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine; wherein X and Z are the same or different and are selected from the group con¬ sisting of -(CF 2 ) r C0F, -(CF 2 ) r OCF 3 , -(CF 2 ) COOH and C F- , Cl wherein r is an integer from 1 to r 2r+l-q q twelve and q is an integer from 0 to 25; wherein n is an integer from 2 to 1000, m is an integer from 0 to 1000; and p and t are the same or different and are integers from 1 to 50, provided that when p and t are one and R , R , R_ and R, together are fluorine, then R-. or R, is a group other than fluorine. Preferrably, p and t are integers from 1 to 10. Examples of perfluoropolyethers where m in formula I is zero and p is an integer between 2 and 50 are shown below: X- [0-CF 2 -(0-CF 2 -CF 2 ) p ] n -OZ X-[0-CF 2 -(0-CF 2 -CF 2 -CF 2 ) p ] n -OZ X- [0-CF- (0-CF o -CF„) ] -0Z 1 i 2 2 p -n CF, CF, X- tO-C-(O-CF.-CF-) ] -0Z I p n CF 3 Examples of perfluorinated polyethers of formula I where m is zero, p is defined above and Y is an isotactic perfluoropolyether or atactic perfluoropolyether are: X-[0-CF 2 -(0-CF 2 -CF) p ] n -0Z cτ 3 X-[0-CF 2 -(0-CF 2 * CF) ] -OZ I I PP n C 2 F 5 X[0-CF„ (0-CF_CF) 1 -OZ 1 2 2 i p J n CF 2 C1 Examples of random copolymers of formula I in which m and n are greater than zero, and p is defined above, include: X-[0-CF 2 -(0-CF 2 -CF 2 ) p ] n -[0-CF 2 -(0-CF 2 -CF) t ] m -OZ CF, m-OZ Perfluoropolyethers and perhalogenated chloro- fluoropolyethers can also be prepared which have the average formula: FC[(OCF 2 -CF) n -OX] 3 IV R or C[(0CF 2 -CF) n -0X] 4 R wherein X is selected from the group consisting of -(CF 2 ) r C00H, -(CF 2 ) r OCF 3 , -(CF^COF, and C F„ , Cl where r is an integer from 1 to 12 and r 2r+l-q q ° q is an integer from 0 to 25. Preferably X is -CF,, -C 2 F 5 , -CF 2 C0OH, -CF 2 OC 3 and CF 2 C0F; wherein n is an integer from 1 to 50; and wherein R is selected from the group consisting of -F, -CF„C1, -CFC1_, CC1_ and perfluoroalkyl of one to ten carbons. This invention further pertains to perfluoro¬ polyethers and perhalogenated chlorofluoropolyethers having the average formula: X-[0-C] n -0Z II R 2 wherein R. , R,. , X and Z are defined above, and n is an integer from 2 to 1000; provided that R and R„ cannot both be fluorine atoms. This invention further pertains to a method of making perhalogenated formal, acetal, ketal and orthocarbonate compounds and perfluoropolyether and perhalogenated chlorofluoropolyether polymers thereof. The compounds are made by fluorination of acetal, ketal, formal or othocarbonate hydrocarbon percursors . The reaction of a diol with either an aldehyde, acetal, ketal or trialkyl orthoesters can be used to give a polyether if the starting materials and reaction conditions are carefully chosen. For example, if an aldehyde such as formaldehyde, acetaldehyde or butyraldehyde is reacted with a diol, a linear polyether can be made. Such a reaction is shown in Equation (1) below: H0( + H_0 (1) R Suitable diols include ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, other higher polyethylene glycols , propylene glycol, dipropylene glycol, tripropylene glycol, 2,2-di- methyl 1 , 3-propanediol , 1 ,4-butanediol, 1,5- pentanediol, 1 , 6-hexanediol , 1 , 7-heptanediol , 1 , 8-octanediol , 1 , 9-nonanediol , and 1 , 10-decanediol . Suitable aldehydes include formaldehyde, para- formaldehyde, 1 , 3 ,5-trioxane , ace aldehyde and its tri er , butyraldehyde and its trimer, pentanal, hexanal, 2-ethyl butanal, chloroacetaldehyde , dichloroacetaldehyde and trichloroacetaldehyde . An alternative means of preparing the same polymer involves the reaction of an acetal with a diol. The synthesis involves the initial prepara¬ tion of an acetal by reaction of an alcohol with the aldehyde as shown in Equation (2) below: RCHO + 2R'0H → (R'0) 2 C(R)H + H 2 0 (2) The acetal interchange is followed by a smoothly reversible reaction in acid media giving rise to the polyacetal. This reaction is given in Equation (3) below: (R'0) 2 C(R)H + H0 CH 2 ) n 0H → H0[(CH 2 ) n 0C(R)H0] χ H + 2R'0H (3) S itable acetals include the diethyl, dipropyl, dibutyl, dipentyl and diphenyl acetals of all of the previously mentioned aldehydes. A well known reaction which is particularly well suited for preparing copolymers of acetaldehyde involves the reaction of divinyl ethers with diols . For example, ethylene glycol divinyl ether will react with ethylene glycol in the presence of H at -10°C to give a 1:1 copolymer of ethylene glycol and acetaldehyde. Similarly, the divinyl ether of 1,5- pentanediol will react with 1 , 5-pentanediol to give a copolymer of pentanediol and acetaldehyde: CH 2 -CHOCH 2 CH 2 CH 2 CH 2 CH 2 OCH-CH 2 + HOCH 2 CH 2 CH 2 CH 2 CH 2 OH H [CH 2 CH 2 CH 2 CH 2 CH 2 OCHO] n CH. 2 N 2 [CF 2 CF 2 CF 2 CF 2 CF 2 OCHO] n (4) I CF. Terpolymers can be prepared by reacting a divinyl ether of one diol with a diol of a different structure. For example, the divinyl ether of ethylene glycol will react with 1 , 3-propanediol to yield a polyether after fluorination having the following structure: [OCF 2 CF 2 OCFOCF 2 CF 2 CF 2 _ n CF„ The divinyl ethers are conveniently formed by reacting a dihydroxyl terminated compound with acetylene at 160 β C in the presence of KOH as shown below in Equation (5). KOH HOCH 2 CH 2 OH + HC=CH ^ L CH 2 * -CHOCH 2 CH 2 OCH-CH CH 2 -CHOCH 2 CH 2 OCH-CH 2 + HOCH 2 CH 2 CH 2 OH H+ > [0CH-CH_0CH0CH_CH_CH-] 2 2 j 2 2 2 J n CH 3 F 2 /N 2 = ■ > [0CF 2 CF 2 0CF0CF 2 CF 2 CF 2 ] n (5) CF 3 A variety of aldehydes can be polymerized and fluorinated to give perfluoropolyethers that have unique and often useful properties. For example, chloroacetaldehyde can be polymerized and fluori¬ nated to give perfluoropolychloroacetaldehyde . Similarly, dichloroacetaldehyde and trichloro- acetaldehyde can be polymerized and fluorinated to give the perfluorocarbon analog of the polyethers. Chlorofluoroethers such as these are potentially useful, nonflammable aircraft hydraulic fluids. Their relatively high oxidative stability and low compressibility make them attractive candidates. Other aldehydes such as acetaldehyde, trifluoro- acetaldehyde and propanal can be polymerized and fluorinated to give stable polymers. Ketals undergo a facile reversible metathesis reaction with alcohols to give polyketals as shown below in Equation (4): (R'0) 2 C(R)R' H0(CH„) OH → 2 n HO[(CH ) 0C(R)(R")0]_H +2ROH (6) The list of useful ketals would include 2,2-dime- thoxypropane , 2 , 2-dimethoxybutane , 2 , 2-dimethoxy- pentane, 2 , 2-dimethoxyhexane , 3 , 3-dimethoxypentane , 3 , 3 -dimethoxyhexane as well as the diethoxy, dipropoxy, dibutoxy and diphenoxy analogues of the previously mentioned ketals. The direct reaction of. a ketone with an alcohol, a reaction analogous to the reaction of an aldehyde with an alcohol, generally works only for several isolated ketones. For this reason, the ketal is normally used. The reaction of a trialkyl or triaryl ortho- ester with alcohols gives formates according to the reaction presented in Formula (5) : OH 0 I (R0),CH + 3H0(CH„) OH → HC-0(CH„) OH + 3ROH (7) 3 2 n | 2 n N / 0 - 14 - Useful orthoesters include trimethylorthoformate , triethylorthoformate, tripropylorthoformate , tri- butylorthoformate , triphenylorthoformate , trimethyl- orthoacetate , triethylorthoacetate , tripropylortho- acetate, tributylorthoacetate , triphenylortho- acetate, trimethylorthopropionate , triethylortho- propionate, tripropylorthopropionate , tributylortho- propionate, triphenylorthopropionate , trimethyl- orthobutyrate , triethylorthobutyrate , tripropyl- orthobutyrate , tributylorthobutyrate and triphenyl- orthobutyrate . It should be clear from the preceeding discus¬ sions that a wide variety of linear as well as highly branched polyethers can be made using these interchange reactions. By carefully choosing the appropriate diol and aldehyde it is possible to prepare cyclic acetals which can often be poly¬ merized to give polyethers. For example, formalde¬ hyde reacts with diethylene glycol to give 1,3,6- trioxocane which can be polymerized to give linear polyacetals as shown in Formula (6) below: ( Similarly, the cyclic products formed by the re- action of trimethylene glycol with dibutyl formal and the reaction of hexamethylene glycol with propionaldehyde polymerize in the presence of an acid to given linear polymers as described in U.S. Patent No. 2,071,252. In general, if the glycol is 1 , -butanediol or ' higher a linear polymer is formed whereas glycols having fewer carbons generally form rings. If the glycol used is a polyether glycol, such as diethylene glycol or triethylene glycol, the linear polymer represents a thermodynamically more stable structure. However, it is often possible to convert the linear polyether to the cyclic ether by vacuum pyrolysis. Conversion of the hydrocarbon polyether to a perfluoropolyether can be accomplished by reacting the polyether with elemental fluorine. Because of the reactive nature of elemental fluorine, it is preferably to dilute the fluorine with an inert gas such as nitrogen or helium. Typically, the fluorine is diluted with nitrogen and as higher degrees of fluorination are achieved, the concentration of fluorine is usually increased. Due to the extreme exothermicity of the reaction, the fluorination must be carried out slowly unless provisions have been made for rapidly removing the heat of reaction. Submersion of the reactor in a cooled liquid bath is usually adequate for achieving commercially acceptable rates of reaction. Fluorine gas is the preferred fluorinating agent and is commercially available at sufficiently high purity levels and at an acceptable cost. The fluorination reaction is generally carried out at a temperature between -40 and +150°C, preferably between -10 and +50°C. It can be carried out in a reactor containing an ultraviolet radiation source or in the dark. Using the preferred temperature range, it is not necessary to have an ultraviolet light source since the fluorine Is sufficiently reactive. If an ultraviolet light source is used, however, a wavelength between 250 and 350 nm is preferred. When the reactor is irradiated with an external light source, a transparent window is needed which does not react with either fluorine or hydrogen fluoride. A quartz lens coated with a thin film of fluorinated ethylene-propylene copolymer works well. The fluorination reaction can be carried out In a variety of ways. The polyether can be coated on sodium fluoride powder to give a free-flowing powder which can be fluorinated in either a stationary tube, in a rotating drum-type reactor, or in a fluidized bed. See U.S. Patent No. 4,755,567 and U.S. Application Serial No. 07/198,154, filed May 24, 1988, the teachings of which are incorporated herein by reference. Alternatively, the polyether, if soluble, can be dissolved in a solvent inert to fluorine and can be fluorinated while in solution using a liquid phase fluorination reactor. See U.S. Patent Application Serial No. 07/250,376, entitled "Liquid Phase Fluorination" , by Thomas R. Bierschenk, Timothy Juhlke, Haj i u Kawa and Richard J. Lagow, filed September 28, 1988, and U.S. Serial No. , entitled "Liquid Phase Fluorination", Attorney's Docket No. EXF86-06A, filed concurrently herewith, the teachings of each are incorporated by reference herein. A typical laboratory-size reactor for example ' , has a volume of about 10 liters and contains approximately 2 to 8 liters of a suitable solvent. Perhalogenated chlorofluorocarbons are typically used as the fluorine-inert fluorination medium. However, perfluorocarbons , such as Fluorinert™ FC75 [ 3M Corporation; mixture of per- fluoro (2-butyltetrahydrofuran) and perfluoro(2-n- propyltetrahydropyran) ] and perhalogenated chloro- fluoropolyethers may also be used as the liquid phase fluorination medium. One preferred fluori¬ nation medium is 1 , 1 , 2- richlorotrifluoroethane since it does not react appreciably with fluorine when the preferred temperature range is used (above the melting point of the material and below the temperature at which the fluorine reacts with it) . Other fluorinated solvents can be used, such as perfluoroamines , perfluoroalkanes , low molecular weight polyethers, etc. During a typical reaction, the polyether is fed into the reactor at a rate of 10 to 60 grams per hour. Fluorine gas is delivered to the vigorously stirred reactor at a rate sufficient to react with all of the organic feed plus an additional 5 to 10 percent. Typically the fluorine gas is diluted with an inert gas such as nitrogen. This is of particular importance if a liquid flororination medium such as 1 , 1 , 2-trichlorotrifluoroethane is used. It is imperative to keep the fluorine concentration low so that the liquid fluorination medium and fluorine in the vapor space do not form a flammable mixture. The flammability limits of various solvents in fluorine' gas can be determined by spark testing. In a typical reaction, a fluorine concentration of 10 to 40% works well. If operating properly, the fluorine concentration in the exit gas will be between 2 and 4%. Fluorination can be carried out either in a batch mode where all of the polyether is dissolved in a solvent prior to fluorination or in a continuous mode where the polyether is continuously being pumped into the solvent as fluorine is being bubbled through the solution. Generally speaking, the continuous operation gives a preferred yield, better product quality and improved rates . If the polyether is insoluble in the liquid fluorination medium it can still be fluorinated in high yield as an emulsion in the liquid phase reactor. An emulsified solution of the polyether and the luorine-inert liquid fluorination medium can either be pumped into the reactor or the reactant can be emulsified in the reactor with the fluorination medium prior to the reaction. An alternative method for fluorinating poly¬ ethers which are insoluble in the liquid fluorination medium involves adding a solvent to the polyether which allows limited solubility of polyether in the liquid fluorination medium. For clarity, 1 , 1 , 2-trichlorotrifluoroethane has been selected as the liquid fluorination medium; however, other highly fluorinated solvents can also be used. Typically, a mixture containing one part polyether, 19 one part solvent and one part 1,1,2 trichlorotri- fluoroethane will give a homogeneous solution. A solvent is selected which readily dissolves the polyether. Often it is possible to choose a solvent which will consume little, if any, of the fluorine gas. Trifluoroacetic anhydride, trifluoroacetic acid, chloroform, 1 , 1 , 2-trichloroethylene and 1 , 1 , 2-trichloroethane work especially well and have high solvating power. The polyether/solvent/1 , 1 , 2-trichlorotri- fluoroethane solution is metered into a vigorously stirred fluorination reactor. As the polyether solution contacts the 1 , 1 , 2- richlorotrifluoroe hane in the reactor, an emulsion is formed. The polyether droplets in the solution are in most cases sufficiently small and react quickly with the fluorine gas with negligible side reactions. When carrying out the reaction in a liquid fluorination medium, a hydrogen fluoride scavenger such as sodium fluoride or potassium fluoride may or may not be present in the solution to scavenge the by-product hydrogen fluoride. However, the prefer¬ red mode of carrying out the fluorination reaction is with a sufficient quantity of sodium fluoride being present to complex with all of the hydrogen fluoride formed. When fluorinating ethers in the presence of sodium fluoride, improved yields are obtained while chain cleavage and rearrangements are minimized. See U.S. Patent No. 4,755,567, the - 20 - teachings of which are incorporated herein by reference. Products produced using the methods just described usually have a residual hydrogen content of 0.001% or less. In order to obtain a fluid which is essentially free of residual hydrogen and void of any reactive terminal groups such as acyl fluoride groups resulting from chain degradation reactions , a final fluorination near 175 β C with 30% fluorine for several hours works well. The following examples will further Illustrate the invention, but are not to be construed as limiting its scope. Examp_l _l ^ A mixture of 1060 g diethylene glycol (10 mol) , 210 g paraformaldehyde (7 mol) , 500 ml benzene and 10 g acidic ion exchange resin was refluxed for 6 hours in a 2 liter flask equipped with a water separator and a reflux condenser. The solution was filtered to remove the acid catalyst and the benzene was removed by distillation. Upon removal of all of the benzene, several drops of sulfuric acid were added to the polymer and the temperature was raised to approximately 140°C. The entire contents of the flask were distilled at 160 β C with a reduced pres¬ sure (25 mm) . Redistillation of the high boiling fraction gave 463 grams of 1, 3 , 6-trioxocane (78% conversion) . 21 - Polymerization of 450 g of 1 , 3 , 6- trioxocane was carried out at room temperature in 1 liter dry methylene chloride using 0.04 ml of trifluoromethane sulfonic acid as a catalyst. The polymerization was complete in 24 hours at which time 1 g of sodium methoxide dissolved in 50 ml of dry methanol was added to neutralize the acid catalyst. 3600 g sodium fluoride powder was added to the polymer along with an additional 1 liter of methylene chloride. The mixture was stirred, the methylene chloride was allowed to evaporate and the remaining solids were ground to a powder. The polymer-coated sodium fluoride was placed in a 20 liter rotating drum reactor and dried under a stream of inert gas (e.g. , nitrogen) for a period of 12 hours. The mixture was then exposed to 500 cc fluorine diluted with 2 liters of nitrogen for approximately 30 hours at 25 β C. Next, the nitrogen flow was reduced to 1 liter/min and the reaction was allowed to continue for an additional 12 hours after which time the reactor was slowly warmed to 70"C over a 6 hour period. Treatment with pure fluorine for several hours at 70"C gave a product which contained very few hydrogen atoms . Extraction of the reaction product with 5 liters of 1 , 1 , 2-trichlorotrifluoro¬ ethane gave 386 grams of fluid (34%) . Washing of the solids with 100 liters of water resulted in the isolation of 430 grams of an elastomeric solid (38% yield) . The crude fluid was treated with 30% fluorine at 260°C for 12 hours to remove the last remaining hydrogens. The fluid was distilled to give the following fractions: 22 - Kinematic b.p. Weight viscosity (cst.) ^. KΑ-LIQ.1 fraction (g) %._£f_t£tal 20^C 80"C <200°C at 100 mm 120 31 3.2 1.07 >200°C at 100 mm 126 33 11.8 2.83 <245°C at 10 mm >245°C at 10 mm 62 16 38.9 7.06 <288°C at 0.05 mm >288°C at 0.05 mm 39 10 83.3 13.1 <370°C at 0.05 mm >370°C at 0.05 mm 39 10 290.3 39.5 19 The F data and elemental analysis were consistent with the structure: fCF 2 CF 2 0 CF 2 CF 2 0 CF 2 0] n Exam£le_2_ 15 In this example the fluid prepared in Example 1 was prepared using an alternate method which was better suited for preparing fluids while the method described .in Example 1 yields a considerable amount of polymeric solids. 20 Into a 1 liter stirred flask equipped with a water separator were placed 500 g diethylene glycol (4.7 mol), 90 g diethylene glycol methyl ether (10.75 mol) , 225 g paraformaldehyde (7.5 mol), 150 ml toluene and 5 g ion exchange resin (H form) . 25 The mixture was refluxed for several hours to remove the water formed during the reaction. The solution was first filtered to remove the ion exchange resin, then distilled to 150 β C at 0.05 mm/Hg to remove the toluene and other lights. A nearly quantitative yield of polymer having an average molecular weight of 1500 was obtained. 320 g of polymer, mixed with 170 g chloroform and 300 g 1 , 1 , 2- trichlorotrifluoroethane were slowly pumped over a 23 hour period into a 15 liter stirred fluorination reactor containing 6 liters of 1,1,2- trichlorotrifluoroethane and 1300 g of sodium fluoride powder. 20% fluorine was bubbled through the liquid fluorination medium at a rate 15% higher than that required to theoretically replace all of the hydrogen on the hydrocarbon being pumped into the reactor. The reactor temperature was maintained between 0 and +10 β C throughout the reaction. Following the reaction, the reactor contents were filtered and the liquid fluorination medium (1, 1, 2- trichlorotrifluoroethane) was removed from the filtrate via an atmospheric distillation to 120°C to give 535 g of crude fluid (66%) . Fluorination of the fluid at 260°C gave a clear, colorless fluid 19 which was shown by elemental analysis and F NMF have the following structure: [CF 2 CF 2 OCF 2 CF 2 OCF 2 0] n Examρle_ 3 100 g triethylene glycol (0.67 mol) , 28.5 g paraformaldehyde (0.95 mol) , 100 ml benzene and 1 g ion exchange resin (H form) were placed in a 500 m. stirred flask equipped with a water separator and a reflux condenser. The solution was allowed to reflux for 6 hours while the water was continuously removed. Upon removal of the water, the solution was filtered to remove the acid catalyst. At- mospheric distillation of the filtrate followed by a reduced pressure distillation (100 mm Hg) to 120 β C was used to remove the benzene solvent as well as any lights present. Twenty grams of the viscous polymer were mixed with approximately 100 ml of methylene chloride and 120 g sodium fluoride powder (200 mesh) . The resulting paste was " dried In a vacuum oven at 60°C for several hours prior to grinding to a coarse powder (approximately 30 mesh) . The powder was placed in a 1 liter rotating brass reactor and was purged with 200 cc of dry nitrogen for several hours prior to the luorination. The reactor was cooled to 0°C, the nitrogen flow was reduced to 150 cc/min and the fluorine flow was set at 20 cc/min. These conditions were maintained for approximately 30 hours after which time the nitrogen flow was reduced to 100 cc/min and the reactor was allowed to slowly warm to 45 β C over a 4 hour period. Next, the nitrogen flow was turned off and the reactor was slowly warmed to 70°C over a 3 hour period. Upon heating to 70 β C, the polymer was exposed to pure flourine for an additional hour. Extraction of the sodium fluoride/polymer mixture with approximately 1 liter of 1, 1, 2- richlorotrifluoroethane gave 23 g of fluid (45% yield) having the following structure which has been confirmed spectroscopicall : [ CF 2 CF 2 OCF 2 CF 2 OCF 2 CF 2 OCF 2 0 ] n Exam£l _4 400 g tetraethylene glycol (2.06 mol), 109 g paraformaldehyde (3.62 mol), 17 g triethylene glycol methyl ether (0.103 mol), 150 ml benzene and 5 g ion exchange resin were allowed to react in a 1 liter flask containing a water separator. After 6 hours, the contents of the flask were filtered and the lights were removed via a vacuum filtration. A 265 g sample of the polymer was mixed with 160 g chloroform and 285 g 1 , 1 , 2-trichlorotrifluoroethane . The polymeric solution was metered, over a 22 hour period, into a stirred 10 liter fluorination reactor which contained 1150 g sodium fluoride powder and 4.5 liters of 1 , 1 , 2-trichlorotrifluoroethane . The reactor was maintained at 7°C while 20% fluorine (diluted with nitrogen) was metered into the reactor at a rate sufficient to react with all of the organic entering the reactor. Upon completion of the reaction, the solution was filtered and the liquid fluorination medium was removed via a dis¬ tillation yielding 422 g (62% yield) of a clear, stable fluid. The product was fractionated into three samples, one which boiled below 200°C at 0.05 mm Hg (40%) , a second which boiled between 200 and 300°C at 0.05 mm (35%) and a third having a boiling point above 300°C at 0.05 mm Hg (25%). The inter¬ mediate fraction had a viscosity of 33.1 cst. at 20°, 6.3 cst. at 80° and 2.13 cst. at 150°C. The pour point was -79°C. The analysis was consistent with the formula: -26* [CF 2 CF 2 0CF 2 CF 2 0CF 2 CF 2 0CF 2 CF 2 0CF 2 0] n 19 F NMR (δ ppm vs CFC1 3 ) -51.8:CF 2 0; -56.0:CF 3 O; -88.8, -90.6:CF CF 0. Anal. Calcd. for C 9 F 18 0 5 : 20.4, C; 64.5, F. Found. 21.0, C ; 65.1, F. Example 5 A mixture of 400 g dipropylene glycol (3.0 mol) , 358 g paraformaldehyde (12 mol) , 150 ml toluene and 10 g ion exchange resin was refluxed for 5 hours In a stirred 1 liter flask equipped with a water separator. The ion exchange resin was removed prior to distillation of the mixture to 150°C under a full vacuum to remove any low molecular weight polymer. Approximately 200 g of polymer remained in the flask which was shown by gel permeation chromatography to have an average molecular weight of approximately 3000. The polymer (280 g) was mixed with 340 ml 1, 1, 2- richlorotrifluoroethane and was slowly pumped Into a 15 liter stirred reactor over a 24 hour period. The reactor, which contained 5.5 liters of 1, 1 , 2-trichlorotri luoroethane and 1220 g sodium fluoride powder, was maintained at 10°C throughout the reaction while 20% fluorine was bubbled through the liquid fluorination medium at a rate just exceeding that required to react with all of the starting material being pumped into the reactor. The reactor contents were filtered and distilled to give 587 g of fluid which was further treated with 50% fluorine at 270°C to give a fluid which was essentially free of hydrogen. The purified product was fractionated into three samples. The first fraction boiled below 200°C at 0.05 mm Hg, the second distilled over between 200 and 300 β C at 0.05 mm and the distillation bottoms had a boiling point above 300 β C at 0.05 mm Hg. The second fraction comprised approximately 20% of the total fluid with the majority of the sample having a boiling point below 200 β C at 0.05 mm. The viscosity of the second fraction at 20°C was 72.2 cst. (ASTM slope of 0.644). The pour point was -62°C. 19. F NMR (.. ppm vs CFC1.. ) : -47.3 , -49.3 , -51.4 : C 2 0 ; -54.0, -55.8:CF 3 0; -79.7 : 0CF(CF_ 3 )CF 2 0 ; -81.8,-82.8 -84.7:OCF(CF 3 )CF 2 0; -87.3 : CF 3 CF 2 0 ; -130.0 : CF CF 0 ; -140.3 , -144.8 , -146.0:OCF 2 CF(CF 3 )0. Anal. Calcd. for CF_0 [ CF„CF(CF, )0CF„CF(CF_ )OCF.O] ■ -> 2 o 2 j 2 n CF CF 3 : C, 21.02; F, 67.02. Found. C, 21.08; F, 67.08. I£xam£^e_(> Using techniques similar to those described in the previous examples, 350 g 1,4 butanediol, 43 g n-propanol and 200 g paraformaldehyde were reacted in benzene to give a fluid which was treated with 85g acetic anhydride to give 325 g of a polymeric material having a viscosity of 162 cst. at 30°C. Fluorination of 305 g of the fluid in a typical 40°C fluorination reaction gave 577 g of fluid of which approximately 30% boiled between 200° and 300°C at 0.05 mm/Hg. 19 F NMR (S ppm vs CFC1 3 ) : -51.7 (f) , -82.1(a), -85.4(d), -86.5(c), -125.9(e) and -130.3(b) CF 3 C 2 CF 2 0[CF 2 CF 2 CF 2 CF 2 OCF 2 0] n CF 2 CF 2 CF 3 a b c d e e d f c b a Examp_l _2 Into a 1 liter stirred flask were placed 350g 1,5 pentanediol (3.4 mol), 23g n-butanol (0.3 mol) , 175g paraformaldehyde (5.8 mol) and 200 ml benzene. Upon refluxing the mixture for approximately 3 hours with an acid catalyst present, 390g of a polymeric fluid was obtained which had a viscosity of 450 cst. at 100°F. Fluorination of 310g of the fluid in a typical fluorination reaction at 14°C gave 708g of fluid (80% yield) of which approximately 30% boiled between 200 and 300 β C at 0.05 mm Hg. 19 F NMR (5 ppm vs CFC1 3 ) -51.3 (g) , -55.7(c), -81.7(a), -85.0(d), -122.3(f) , -125.5(e) and -126.7(b) CF 3 CF 2 CF 2 CF 2 0[CF 2 CF 2 CF 2 CF 2 CF 2 OCF 2 0] n CF 2 CF 2 CF 2 CF 3 a b b e d e f e d g c b b a Exam£l _JB Using techniques similar to those described in the previous examples, 350g 1 , 6-hexanediol (3.0 mol) 49.3g n-pentanol (0.56 mol), 134g paraformaldehyde (4.46 mol) were reacted in benzene to give 425g of a polymeric material having a viscosity of 600 cst. at 100 β F. Fluorination of 628g of the fluid in a typical reaction at 10°C gave 628g of fluid (71% yield) , of which approximately 30% boiled between 200 and 300°C at 0.05 mm Hg. 19 F NMR ( δ ppm vs CFC1..) : -51.3 (i) , -56.0(b) , -81.7(a) , -85.0(f), -85.3(e) , -122.7(h) , -123.0(c) , -125.5(g) and -126.3(d) CF 3 CF 2 CF 2 CF 2 CF 2 0[CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 OCF 2 0] n CF 2 CF 2 CF 2 a b c d e f g h h g f i e d c CF 2 CF 3 Exam£l _9_ Into a 500 ml flask were placed 100 g diethylene glycol (0.94 mol) , 55.7 g acetaldehyde diethyl acetal (0.47 mol) , 200 ml benzene and 2.5 g acidic ion exchange resin. Attached to the flask was an apparatus designed to continuously extract the by-product ethanol from the refluxing benzene. After approximately 6 hours , the refluxing benzene was essentially free of ethanol and the reaction was assumed to be complete. Filtration of the crude reaction product gave a solution free of the ion exchange resin. Removal of the benzene was accom¬ plished using a rotary evaporator (70 β C bath with a nitrogen purge through the solution) . 20 grams of the polymeric product were mixed with 100 ml of methylene chloride and 120 g sodium fluoride powder. On drying the paste, 140 g of a free-flowing powder was obtained. Using the fluor¬ ination procedures of Example 3 , a 50% yield of the following fluorinated fluid was obtained: [CF 2 CF 2 0CF 2 CF 2 0CF(C 3 )0] n 19 F NMR ( δ ppm vs CFC1 3 ): -56.0:CF 3 O; -86.3 :OCF(CF 3 )0; -87.3 : CF_ 3 CF 2 0; -87.7:CF 3 CF 2 0; -88.7 :OCF^CF^O ; -96.3 : 0CF(CF 3 )0. Example 10 Using the procedures detailed in the previous examples, 400g tetraethylene glycol (2.06 mol) was reacted with 243.5g acetaldehyde diethyl acetal (2.06 mol) in 250ml benzene to give 250g of a polymeric fluid upon refluxing for 6 hours . The julyωeric liquid (350g) was coated on 3555 g of sodium fluoride and placed in a 22 liter rotating drum reactor. After purging for several hours, the reactor was cooled to -10 β C and the fluorine and nitrogen flow rates were set at 350 cc/min and 2 liters/min, respectively. After 25 hours, the nitrogen flow was decreased to 1.5 liter/min. After an additional 14 hours , the nitrogen flow was further reduced to 1 liter/min and the reactor was allowed to slowly warm to 35 β C over a 4 hour period. Upon reaching 35°C, the nitrogen was turned off and the reactor was further warmed to 65 β C prior to terminating the fluorine flow. An oil (371g) was extracted from the sodium fluoride with 1 , 1 , 2- trichlorotrifluoroethane which was determined to have the following structure: [CF 2 CF 2 OCF 2 CF 2 OCF 2 CF 2 OCF 2 CF 2 OCF(CF 3 )0] n 19 F NMR (5 ppm vs CFC1 3 ) -56.0:CF 3 0; -86.7 : 0CF(CF 3 )0 ; -87. : CF 3 CF 2 0 ; -80.0:CF 3 CF_ 2 O; -88.7 :OCF^CF^O ; -96.7 : 0CF(CF )0. Exam l ^ _^l A mixture of 600g 1 , 5-pentanediol and 30g potassium hydroxide was heated to 160°C in a 1 liter flask. Acetylene gas was bubbled through the solution as it was rapidly stirred. The reaction was stopped after 40 hours and the product was washed with water and distilled to give an 85% yield of pentanediol divinyl ether (b.p. 192°C) . A 1 liter flask cooled to -12 β C was charged with 104g pentanediol and a trace of methane sulfonic acid. To this solution was added 156g pentanediol divinyl ether. The solution was stirred rapidly for 2 hours. Then slowly warmed to room temperature over a 6 hour period to give a viscous polymer having viscosity of 650 cst. at 100°F. The product from the above reaction can be fluorinated in a liquid phase reactor containing 1, 1, 2-trichlorotrifluoroethane and a sufficient amount of fluorine to complex with all of the hydrogen fluoride formed during the reaction. A perfluoropolyether having the following structure is obtained: CF 3 CF 2 CF 2 CF 2 0[CF 2 CF 2 CF 2 CF 2 CF 2 OCF(CF 3 )0] n CF 2 CF 2 C 2 CF 3 Exam£le__12_ Chloroacetaldehyde (50 to 55 wt % in water) was distilled to give a fraction boiling between 87 and 92°C. A 3 liter stirred flask containing 1281 g of the chloroacetaldehyde distillate was placed in a room temperature water bath. While maintaining a temperature below 55 β C, 500 ml of concentrated sulfuric acid was slowly added over a one hour period. The mixture was stirred for an additional 3 days at 53°C, then allowed to separate into two phases. The lower phase, containing sulfuric acid, was removed with a separatory funnel while the upper phase was placed into a 3 liter flask equipped with a mechanical stirrer. Concentrated sulfuric acid (200 ml) was carefully added to the solution while the temperature was held below 60"C with a water bath throughout the addition. The flask was held at 50°C for an additional 20 hours resulting in a viscous oil being formed. The polymeric product was dissolved in 1 liter methylene chloride and the solution was washed with water several times fol- lowed by a rinse with dilute sodium bicarbonate solution. The organic phase was isolated, dried over magnesium sulfate and concentrated to give a dark, viscous product (719 g polychloroace- taldehyde) . The product was dissolved in 450 g chloroform and 305 g 1 , 1 , 2- richlorotrifluoroethane to give a solution which was metered over a 22 hour period into a 20 β C fluorination reactor containing 5.5 liters of 1 , 1 , 2-trichlorotrifluoroethane . Following the reaction, the solvent was removed leaving behind a fluid with the following structure [CFO] I n CF 2 C1 T m£ ra:ur_ _j[_F Vi_s_££s_i£y ^ _^£ t._ : _ -65 1240 100 2.53 176 1.14 Exam£l _13_ A mixture of 392 g 1 , 4-cylcohexanedimethanol (2.72 mol) , 140 g paraformaldehyde (4.7 mol) , 200 ml benzene and 10 g of a H ion exchange resin was refluxed for several hours in a flask containing a water separator. A nearly quantitative yield of a sticky solid was obtained after removal of the solvent by distillation. Fluorination of 263 g of the polymer, diluted with 220 g chloroform and 340 g 1 , 1 , 2-trichlorotri- fluoroethane in a reactor (10 β C) containing 4.8 liters 1 , 1 , 2- richlorotrifluoroethane and 1300 g sodium fluoride power, gave 440g of a perfluoro- polyether having the following structure: -34- CF 2 CF 2 [CF 2 CFCF 2 CF 2 CF CF 2 OCF 2 0] n E am l ^ _l i 4 Into a 1 liter flask were placed 350 g tetraethylene glycol (1.8 mol) , 300 ml benzene, and 1U g ion exchange resin. The mixture was refluxed for 1 hour to remove any moisture present. To the mixture was added 200 ml dimethoxypropane . The distillate was continuously removed over a 2-hour period in 50 ml increments, which were extracted with water to remove the ethanol formed in the reaction. After drying, the distillate was returned to the flask. An additional 200 ml dimethoxypropane was added and the distillate was collected, extracted, dried, and returned to the flask for an additional 3 hours. Removal of the resin and solvent yielded 410 g of a polymeric fluid having a viscosity of 560 cst. at 30 β C. Fluorination of 336 grams of the polyether in a 10°C reactor containing 5 liters of 1, 1, 2-trichloro¬ trifluoroethane and 1420 g sodium fluoride powder gave 642 g of a perfluoropolyether (69.8% yield) . 19 F NMR: (5 ppm vs CFC1.-): -55.8(a), -76.3(e) , -87.3(d), -88.6(c) and -90.5(b) CF 3 0 [C 2 (CF 2 OCF 2 ) 3 CF 2 OC(CF 3 ) 2 0]__ . a b c c d e Example_ 15 A mixture of 300 g pentanediol (2.88 mol) , 450 g chloroacetaldehyde/water mixture having a boiling point between 87 and 92°C and 150 ml benzene was refluxed in a flask containing a water separator. Approximately 5 grams of an acidic ion exchange resin was added to catalyze the reaction. After refluxing for approximately five hours the solution was filtered and the benzene was removed by distillation to leave a residue (approximately 400 g) having .a viscosity of 9,700 cst. at 100 β F. Fluorination of 318 g of the polymer, diluted with 235 g chloroform and 375 g 1 , 1 , 2- trichlorotri- fluoroethane , in a 12°C reactor containing 5 liters of 1 , 1 , 2- trichlorotrifluoroethane and 1200 g sodium fluoride powder gave 623 g (84% yield) of the fluorinated polyether in a 22-hour reaction. 19 F NMR (δ ppm vs CFC1 3 ) -73.4(h) , -74.3(c) , -81.6(a) , -82.3(d) , -87.1(g) , -122.1(f) , -125.3(e) and -126.3(b) CF 3 CF 2 CF 2 CF 2 O[CF 2 CF 2 CF 2 CF 2 CF 2 OCF(CF 2 Cl)0] n CF 2 CF 2 a b b e d e f e d g h c b CF 2 CF 3 Those skilled in the art will recognize or be able to ascertain using no more than routine experimentation many equivalents to the specific embodiments of the invention described herein. Such equivalents are intended to be encompassed by the following claims:

Claims: CLAIMS 1. A perhalogenated polyether having an average formula : R, I X[0-C-0-Y] [0-C-O-Y' l -OZ I m R, R 4 wherein Y and Y' are the same or different and are selected from the group consisting of linear and branched perfluoroalkylenes having at least 2 carbon atoms; perfluoroalk lene- hypheratehereoxyalkylene and perfluoropoly- (alkyleneoxyalkylene) each having alkylene groups containing at least two carbon atoms wherein in Y or Y' one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine; wherein X and Z are the same or different and are selected from the group consisting of -(CF 2 ) r COF, -(CF ) OCF., , -(CF ) COOH and C F„ , . Cl , wherein r is an 2 r r 2r+l-q q integer from 1 to 12 and q is an integer from 0 to 25; wherein R- , R„ , R-, and R, are the same or different and are selected from the group consisting of -F, -Cl, -CF 2 C1, -CFC1 _ccl 3 » perfluoroalkyl of one to ten carbon atoms and perfluoroalkoxyalkyl of one to ten carbon atoms wherein one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine; wherein n is an integer from 2 to 1,000; and wherein is an integer from 0 to 1,000; provided that when R R R and R together are F, then Y or Y' comprises an ethylene group having at least one fluorine atom which is substituted by a halogen other than fluorine. 2. A perhalogenated polyether of Claim 1, wherein Y and Y' are selected from the group consisting of -C 2 F -; -C 3 F 6 -; -C^-; -CgF^-; CgF^-; -CF 2 CF(CF 3 )-; -CF 2 CF(C 2 F 5 ) - ; and -CF 2 CF(CF 2 C1)-. 3. A perhalogenated polyether having an average formula: -R 1, 1 R \,3 X- [O-C- (0-CF_-CF) ] -[0-C- (CF.-CF) 1 -OZ I 2 | 'p J n t | 2 | t J m R 2 R 5 R 4 R 6 wherein - , R_ , R, , R, , R_. and R fi are the same or different and are selected from the group consisting of -F, -Cl, -CF 2 C1, -CFC1 2 , -CC1 3 , per luoroalkyl of one to ten carbon atoms and perfluoroalkoxyalkyl of one to ten carbon atoms wherein one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine; wherein X and Z are the same or different and are selected from the group consisting of -(CF 2 ) r C0F, -(CF 2 ) r 0CF 3 , -(CF 2 ) COOH and c r F 2r+ ι_. α C1 wherein r is an Integer from 1 to 12 and q is an Integer from 0 to 25; wherein n is an integer from 2 to 1000; m is an integer from 0 to 1000; p and t are the same or different and are integers from 1 to 50, provided that when p and t are one and R , R ? , R_ and R, together are F, then R_. or R fi is a group other than fluorine 4. A perhalogenated polyether of Claim 3, wherein m is zero; R. , R„ , and R,. are F and p is an integer between 2 and 50. 5. A perhalogenated polyether having an average formula: FC[ (0-CF, •CF) ■OX] R wherein X is selected from the group consisting of -(CF 2 ) r COOH, - CF 2 ) r OCF 3 , -(CF^COF and C F- • - Cl where r is an integer from 1 to 12 r 2r+l-q q •*** and q is an integer from 0 to 25; wherein n is an integer from 1 to 50; and wherein R is selected from the group consisting of -F, -CF 2 C1, -CFC1 2 , CC1 3 and perfluoroalkyl of one to ten carbons . 6. A perhalogenated polyether having an average formula: C[(0-CF 2 -CF) n -0X] 4 wherein X is selected from the group consisting of -(CF 2.) rOCF3, , -(CF2)rCOF and C F_ , Cl where r is an integer from 1 to 12 r 2r+l-q q ° and q is an integer from 0 to 25; wherein n is an integer from 1 to 50; and wherein R is selected from the group consisting of -F, -CF 2 C1, -CFC1 2 , CC1 3 and perfluoroalkyl of one to ten carbons . A perhalogenated polyether having an average formula: wherein X and Z are the same or different and one selected from the group consisting of -(CF 2 ) r C0F, -(CF 2 ) r OCF 3> -(CF^COOH and CrF„2r+-l-qClq, wherein r is an integ °er from 1 to 12 and q is an integer from 0 to 25 ; wherein R- and R„ are the same or different and are selected from the group consisting of -F, -Cl, -CF^Cl, -CFCl-, -CCl-., perfluoroalkyl of one to ten carbon atoms and perfluoroalkoxyalkyl of one to ten carbon atoms wherein one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine, provided that R- and R- together are not F; wherein n is an integer from 1 to 1000; provided that R. and R„ together are not F. 8. A perhalogenated polyether of Claim 7, wherein R., is F, R„ is -CF 2 C1 and n is greater than 20. A method of perparing a perhalogenated formal, acetal, ketal or orthocarbonate, comprising the steps : a) reacting a formal, acetal, ketal or ortho- ester with an alcohol under conditions suitable to form a polyether hydrocarbon analog ; b) placing the polyether hydrocarbon analog into a fluorine reactor; c) fluorinating the polyether hydrocarbon analog by establishing a flow of gas mixture of fluorine gas and an inert gas into the reactor under conditions sufficient for perfluorination of the polyether; and d) after the fluorination reaction is com¬ pleted to desired degree, removing the perfluorinated polyether from the reactor. 10. A method of Claim 9, wherein the reactor is a stationary metal tube, rotating drum reactor fluidized bed reactor, or solvent reactor. 11. A method of Claim 10, wherein the polyether is mixed with a hydrogen fluoride scavenger or coated on the hydrogen fluoride scavenger, the amount of the hydrogen fluoride scavenger in relation to the amount of polyether being sufficient to react with most of the hydrogen fluoride formed during fluorination. -42 - 12. A method of preparing a perhalogenated polyether having an average formula: X[0- -OZ wherein Y and Y' are the same or different and are selected from the group consisting of linear and branched perfluoroalkylene , perfluoroalkyleneoxyalkylene and perfluoro- poly(alkyleneoxyalkylene) wherein one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine; wherein X and Z are the same or different and are selected from the group consisting of -(CF_) COF, -(CF_) 0CF_ , -(CF„) COOH and C F_ _.. Cl , 2 r 3' 2'r r 2r+l-q q' wherein r is an integer from 1 to 12 and q is an integer from 0 to 25 ; wherein R.. , R„ , R_ and R. are the same or different and are selected 4 from the group consisting of -F, -Cl, -CF„C1, -CFC1_, -CC1_, perfluoroalkyl of one to ten carbon atoms and perfluoroalkoxyalkyl of one to ten carbon atoms wherein one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine; wherein n is an integer from 2 to 1,000; and wherein m is an integer from 0 to 1,000; provided that when R. , R- , R_ and R, together are F, then Y or Y' comprises an ethylene group having at least one fluorine atom which is substituted by a halogen other than fluorine; comprising the steps of: •43 - a) placing a polyether hydrocarbon analog of the above formula into a fluorine reactor; b) fluorinating a polyether hydrocarbon analog by establishing a flow of gas mixture of fluorine gas and an inert gas into the reactor under conditions sufficient for perfluorination of the polyether; and c) after the fluorination reaction is com- pleted to desired degree, removing the perfluorinated polyether from the reactor. 13. A method of Claim 12, wherein the reactor is a stationary metal tube, rotating drum reactor fluidized bed reactor, or solvent reactor. 14. A method of Claim 12, wherein the polyether is mixed with a hydrogen fluoride scavenger or coated on the hydrogen fluoride scavenger, the amount of the hydrogen fluoride scavenger in relation to the amount of polyether being sufficient to react with most of the hydrogen fluoride formed during fluorination. 15. The method of Claim 14, wherein the hydrogen fluoride scavenger is sodium fluoride or potassium fluoride. 16. The method of Claim 12, wherein the polyether hydrocarbon analog is first prepared by reacting a formal, acetal, ketal or orthoester with an alcohol under conditions suitable to form the polyether hydrocarbon analog. 17. The method of Claim 13, wherein the polyether hydrocarbon analog is first prepared by reacting a formal acetal, ketal or orthoester with an alcohol under conditions suitable to form the polyether hydrocarbon analog. 18. A method of preparing a perhalogenated poly¬ ether having an average formula: R l X-[0-C] -OZ I R 2 wherein X and Z are the same or different and one selected from the group consisting of -(CF 2 ) r C0F, -(CF 2 ) r 0CF 3 , -(CF^COOH and C F„ , . Cl , wherein r is an integer from 1 to r 2r+l-q q & 12 and q is an integer from 0 to 25; wherein R n and R. are the same or different and are selected from the group consisting of -F, -Cl, -CF„C1, -CFC1 2 , -CC1 3 , perfluoroalkyl of one to ten carbon atoms and perfluoroalkoxyalkyl of one to ten carbon atoms wherein one or more of the fluorine atoms may be substituted by a halogen atom other than fluorine, provided that R- and R_ together are not F; wherein n is an integer from 1 to 1000; provided that when n is less than or equal to 20 and R. is fluorine then R_ is a group other than -CF_ or -CF„C1; comprising the steps of: a) placing a polyether hydrocarbon analog of the above formula into a fluorine reactor; b) fluorinating the polyether hydrocarbon analog by establishing a flow of gas mixture of fluorine gas and an inert gas into the reactor under conditions sufficient for perfluorination of the polyether; and c) after the fluorination reaction is com- pleted to desired degree, removing the perfluorinated polyether from the reactor. 19. A method of Claim 18, wherein the reactor is a stationary metal tube, rotating drum reactor fluidized bed reactor, or solvent reactor. 20. A method of Claim 18, wherein the polyether is mixed with a hydrogen fluoride scavenger or coated on the hydrogen fluoride scavenger, the amount of the hydrogen fluoride scavenger in relation to the amount of polyether being sufficient to react with most of the hydrogen fluoride formed during fluorination. 21. The method of Claim 20, wherein the hydrogen fluoride scavenger is sodium fluoride or potassium fluoride. ■ 46 22. A method of preparing a perhalogenated poly¬ ether having an average formula: FC[(0-CF, •CF) • OX] I n R 05 wherein X is selected from the group consisting of -(CF 2 ) r C00H, -(CF 2 ) r OCF 3 , -(CF^COF and C F„ , - Cl where r is an integer from 1 to 12 r 2r+l-q q , b and q is an integer from 0 to 25; wherein n is an integer from 1 to 50; and 10 wherein R is selected from the group consisting of -F, -CF 2 C1, -CFC1 2 , CC1 3 and perfluoroalkyl of one to ten carbons; and comprising the steps of: a) placing a polyether hydrocarbon analog of 15 the above formula into a fluorine reactor; b) fluorinating the polyether by establishing a flow of gas mixture of fluorine gas and an inert gas into the reactor under conditions sufficient for perfluorination 20 of the polyether; and c) after the fluorination reaction is completed to desired degree, removing the perfluorinated polyether from the reactor. 23. A method of Claim 22, wherein the reactor is a 25 stationary metal tube, rotating drum reactor , fluidized bed reactor, or solvent reactor. 24. A method of Claim 22, wherein the polyether is mixed with a hydrogen fluoride scavenger or coated on the hydrogen fluoride scavenger, the amount of the hydrogen fluoride scavenger in relation to the amount of polyether being sufficient to react with most of the hydrogen fluoride formed during fluorination. 25. The method of Claim 24, wherein the hydrogen fluoride scavenger is sodium fluoride or potassium fluoride. 26. A method of preparing a perhalogenated polyether having an average formula: C[ (0-CF 2 -CF) n - OX] A wherein X is selected from the group consisting of -(CF 2 ) r C00H, - CF 2 ) r OCF 3 , -(CF^COF and C F_ , . Cl where r is an integer from 1 to 12 r 2r+l-q q ° and q is an integer from 0 to 25; wherein n Is an integer from 1 to 50; and wherein R is selected from the group consisting of -F, -CF 2 C1, -CFC1 2 , CC1 3 and perfluoroalkyl of one to ten carbons; comprising the steps of: a) placing a polyether hydrocarbon analog of the above formula into a fluorine reactor; b) fluorinating the polyether by establishing a flow of gas mixture of fluorine gas and an inert gas into the reactor under conditions sufficient for perfluorination of the polyether; and c) after the fluorination reaction is completed to desired degree, removing the perfluorinated polyether from the reactor. 27. A method of Claim 26, wherein the reactor is a stationary metal tube, rotating drum reactor, fluidized bed reactor, or solvent reactor. 28. A method of Claim 26, wherein the polyether is mixed with a hydrogen fluoride scavenger or coated on the hydrogen fluoride scavenger, the amount of the hydrogen fluoride scavenger in relation to the amount of polyether being sufficient to react with most of the hydrogen fluoride formed during fluorination. 29. The method of Claim 28, wherein the hydrogen fluoride scavenger is sodium fluoride or potassium fluoride.

Inventors: BIERSCHENK THOMAS R, JUHLKE TIMOTHY, KAWA HAJIMU, LAGOW RICHARD J, BIERSCHENK, THOMAS, R., JUHLKE, TIMOTHY, KAWA, HAJIMU, LAGOW, RICHARD, J.
Applicants: EXFLUOR RES CORP, EXFLUOR RESEARCH CORPORATION
Application year: 1989
Main classification: C08G65
IPC codes: C07C41, C07C43, C07C69, C08G2, C08G4, C08G65