SUPERCONDUCTING Bi-Sr-Ca-Cu OXIDE COMPOSITONS AND PROCESS FOR MANUFACTURE

Abstract: Compositions having the nominal formula BiaSrbCacCu3Ox, wherein a is from about 1 to 3, b is from about 3/8 to 4, c is from about 3/16 to 2, x = (1.5a + b + c + y) where y is from about 2 to 5, with the proviso that ''b + c'' is from about 3/2 to 5, containing a metal oxide phase of the formula Bi, Sr3-z, Caz, Cu2, O8+w, wherein z is from about 0.1 to 0.9, w is greater than zero but less than 1, are superconducting. Processes for manufacturing such compositions and for using them are disclosed.

Description: TITLE SUPERCONDUCTING Bi-Sr-Ca-Cu OXIDE COMPOSITIONS AND PROCESS FOR MANUFACTURE. BACKGROUND OF THE INVENTION CROSS-REFERENCES TO RELATED APPLICATION This application is a cσntinuation-in- part application of Serial No. (CR-8641) filed on February 4, 1988. Field of the Invention This invention relates to novel bismuth-strontium-calcium-copper oxide compositions which are superconducting and to a process for making them. References Bednorz and Muller, Z. Phys. B64, 189 (1986), disclose a superconducting phase in the La-Ba-Cu-0 system with a superconducting transition temperature of about 35 K. This disclosure was subsequently confirmed by a number of investigators [see, for example, Rao and Ganguly, Current Science, 56, 47 (1987), Chu et al., Science 235, 567 (1987), Chu et al., Phys. Rev. Lett. 58, 405 (1987), Cava et al., Phys. Rev. Lett. 58, 408 (1987), Bednorz et al. , Europhyε. Lett. 3, 379 (1987)]. The superconducting phase has been identified as the composition La 1 _ χ (Ba,Sr,Ca) χ 0 4 _ with the tetragonal K 2 NiF 4 -type structure and with x typically about 0.15 and y indicating oxygen vacancies. u et al., Phys. Rev. Lett. 58, 908 (1987), disclose a superconducting phase in the Y-Ba-Cu-0 system with a superconducting transition temperature of about 90 K. Cava et al., Phys. Rev. Lett. 58, 1676 (1987), have identified this superconducting Y-Ba-Cu-0 phase to be orthorhombic, distorted, oxygen-de icient perovskite YBa,Cu,O β . where δ is about 2.1 and present the powder x-ray diffraction pattern and lattice parameters. C. Michel et al., Z. Phys. B - Condensed Matter 68, 417 (1987), disclose the introduction of Bi into the sup c erconductor La2,- _.Sr*CuOi -y to form the oxides La, Bi , Sr . CuO. . The study ~ was limited to compositions co esponding to the range where superconductivi y was mainly observed, x - x' « 0.1-0.2. Single phases were obtained when x < 3 and x' < 2. One sample of composition La 1.. -7Bi0- .1. Sr„0. ,2CuO'. — has a superconducting 0 transition temperature of about 42 K as determined from resistivity measurements as compared with about 38 K for La 1, . ,βSr.0 . 2, CuO.« - y C. Michel et al., Z. Phys. B - Condensed Matter 68, 421 (1987), disclose a novel family of - ~ superconducting oxides in the Bi-Sr-Cu-0 system with composition close to Bi 2 Sr. Cu 2 0 7 + .. A pure phase was isolated for the composition Bi 2, Sr2,Cu2,O,7 ■•*• £, . The X-ray* diffraction p c attern for this material exhibits some similarity with that 20 of perovskite and the electron diffraction pattern shows the perovskite subcell with the orthorhombic cell parameters of a = 5.32 A (0.532 nm), b = 26.6 A (2.66 nm) and c «= 48.8 A (4.88 nm) . The material made from ultrapure oxides has a 5 superconducting transition with a midpoint of 22 as determined from resistivity measurements and zero resistance below 14 K. The material made from commercial grade oxides has a superconducting transition with a midpoint of 7 K. 0 SUMMARY OF THE INVENTION This invention provides novel superconducting compositions having the nominal formula Bi • SrbCacCu3,0 % wherein a is from about 1 5 to about 2, b is from about 3/8 to about 4, c is from about 3/4 to about 2 and x » (1.5 a + b + c + y) where y is from about 2 to about 5, " with the proviso that b + c is from about 3/2 to about 5, said compositions having superconducting transition temperatures of about 70 K or higher. Preferably, a is from about 3/2 to about 2, b is from about 3/2 to about 4, c is from about 1 to about 3/2 and b + c is about 3-5. The superconducting transition temperature of the preferred composition will be from at least 77 K (liquid nitrogen) up to about 115 K. This invention also comprises a definition of the metal oxide phases that provides superconductivity for the composition of the nominal formula previously given. Specifically, this metal oxide phase has the formula Bi 2, Sr.3 - t Car Cu2, O•. ♦ w wherein z is from about 0.1 to about 0.9, preferably 0.4 to 0.8 and most preferably 0.6 to 0.7; and w is greater than zero but less than about 1. Thus, the nominal formula for these superconducting compositions that contain substantial amounts of the above-mentioned metal oxide phase that provides superconductivity becomes Bi * S bCacCu 3,0x wherein a is from about 1 to about 3, b is from about 3/8 to about 4, c is from about 3/16 to about 2 and x = (1.5a + b+ c + y) where y is from about 2 to about 5, with the proviso that b + c is from about 3/2 to about 5. This invention also provides a process for making these compositions, the process consisting essentially of heating a mixture comprised of stoichiometric quantities of the metal oxides, for example, Bi.O. , SrO or SrO. , CaO, and CuO, or precursors of the metal oxides, e.g., carbonates such as CaCO- , nitrates such as Sr(NO- )- , etc. at about 775°C to about 900°C for about 8 to about 48 hours or more in air. Preferred are heating temperatures of about 850°C to about 900°C. DETAILED DESCRIPTION OF THE INVENTION The superconducting compositions of this invention have the nominal formula Bia S bCacCu3,0x wherein a is from about 1 to about 3, b is from about 3/8 to about 4, c is from about 3/16 to about 2 and x » (1.5 a + b + c + y) where y is from about 2 to about 5, with the proviso that b + c is from about 3/2 to about 5. These compositions have superconducting transition temperatures of at least 70 K up to about 120 K. Preferred are the compositions wherein a is from about 3/2 to about 3, b is from about 3/2 to about 4, c is from about 1/2 to about 3/2 and b + c is about 3-5. These preferred compositions have superconducting transition temperatures above 77 K, the temperature of liquid nitrogen. The sup r erconducting — Bi< Sr.bCacCu3.O__ compositions can be prepared by the following process. Stoichiometric quantities of Bi 2 0 3 , SrO, CaO, and CuO are mixed, for example, by grinding them together in a mortar. Precursors of the oxides such as carbonates can be substituted for one or more of the oxides. Alternatively, an intimate stoichiometric mixture of precursors of the oxides can be prepared from a solution of precursors such as nitrates or acetates, either by precipitation from such a solution or by drying such a solution by evaporation of the solvent or by spray- or freeze-d ying. The mixture of oxides or precursors in the form of a powder or a pressed pellet is then placed in a container made of a non-reactive material such as alumina or gold. The container is then placed in a furnace and heated at about 775°C to about 900°C for about 8 to about 48 hours in air, preferably from about 850°C to about 900 β C. The superconducting transition temperature is generally higher if the heating temperature is in the preferred range. Melting should be avoided. Since melting occurs at heating temperatures of about 900°C and higher, reaction must occur below these temperatures. Cooling can be done slowly by either turning off the power to the furnace and allowing the container to furnace-cool or by programming the furnace to cool at a slow rate, e. g., at 2°C per minute. When the temperature is below 100 β C, e.g. ambient temperature (about 20°C) the container is removed from the furnace and the black crystalline product is recovered. Cooling can also be accomplished by quenching at ambient temperature the material which had been heated to 850-900°C. A superconducting Bi Sr Ca Cu, 0 composition can be produced even when the relative amounts of reactants are chosen outside of the stoichiomeric limits dictated by the ranges enumerated above for a, b and c. The superconducting composition would then be composed of at least one superconducting phase along with other non-superconducting phases. Superconductivity can be confirmed by observing magnetic flux exclusion, i.e. , the Meissner effect. This effect can be measured by the method described in an article by E. Polturak and B. Fisher in Physical Review B, 36, 5586(1987). The superconducting compositions of this invention can be used to conduct current extremely efficiently or to provide a magnetic field for magnetic imaging for medical purposes. Thus, by cooling the composition in the form of a wire or bar to a temperature below the superconducting transition temperature, e.g., at or below about 10 115 K, preferably at or below about 85 K, by exposing the material to liquid nitrogen in a manner well known to those in this field; and initiating a flow of electrical current, one can obtain such flow without any electrical resistive - ~ losses. To provide exceptionally high magnetic fields with minimal power losses, the wire mentioned previously could be wound to form a coil which would be exposed to liquid helium before inducing any current into the coil. The 20 superconducting compositions of this invention can also be used to provide diamagnetic fields that are extremely persistent. Such fields are obtained by exposing the compositions in the form of a sheet or similar construction to an external 25 magnetic field, the sheet being cooled to a temperature below the superconducting transition temperature, e.g. cooled to between 77 K and 115 K, by exposure to liquid nitrogen. Such fields can be used to levitate objects as large as ~ ~ railroad cars. These superconducting compositions are also useful in Josephson devices such as SQUIDS (superconducting quantum interference devices) and in instruments that are based on the Josephson effect such as high speed sampling 5 circuits and voltage standards. These compositions appear to be more stable, especially in the presence of water, than prior superconductive compositions having transition temperatures in the same range. The compositions are also more easily processed than prior art compositions. EXAMPLES OF THE INVENTION EXAMPLE 1 A compositon of nominal formula BiSrCaCu-O^ was prepared in the following manner. Bi 2 0 3 (2.3298 g), Sr0 2 (1.1692 g), CaCO. (1.0009 g) and CuO (2.3862 g) were mixed and ground together in an agate mortar for thirty minutes. The powder was placed in an alumina container and the container placed in a furnace and heated in air at a rate of 10°C per minute to 800°C and then held at 800*C for 12 hours. The power was then turned off and the furnace allowed to cool to a temperature below about 100°C before the container was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the powder product to have an onset of superconductivity at about 75 K. EXAMPLE 2 A compositon of nominal formula Bi J/2 Sr -/2 Ca- /2 Cu.O )( was prepared in the following manner. Bi.O- (4.6596 g), SrO. (2.3924 g), CaCO- (2.0018 g) and CuO (3.1816 g) were mixed and ground together in an agate mortar for thirty minutes. The powder was placed in an alumina container and the container placed in a furnace and heated in air at a rate of 10°C per minute to 800 β C and then held at 800°C for 12 hours. The 8 power was then turned off and the furnace allowed to cool to a temperature below about _r00°C before the container was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the powder product to have an onset of superconductivity at about 75 K. EXAMPLES 3A AND 3B A compositon of nominal formula Bi 2 Sr 2 CaCu 3 O χ was prepared in the following manner. Bi 2 0- (4.6596 g), Sr0 2 (2.3924 g), CaC0 3 (1.0009 g) and CuO (2.3865 g) were mixed and ground together in an agate mortar for thirty minutes. The powder mixture was used to press 10 pellets, each 10 mm in diameter and about 2 mm thick. In Example 3A, the pressed pellet was placed on an alumina tray and the tray placed in a furnace and heated in air at a rate of 10°C per minute to 800°C and then held at 800°C for 8 hours. The power was then turned off and the furnace allowed to cool to a temperature below about 100°C before the tray was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the pellet to have an onset of superconductivity at about 83 K. In Example 3B, another pressed pellet was placed on an alumina tray and the tray placed in a furnace and heated in air at a rate of 10°C per minute to 900°C and then held at 900°C for 8 hours. The furnace was then cooled at the rate of 2°C per minute to a temperature below about 100°C before the tray was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the pellet to have an onset of superconduct vity at about 85 K. EXAMPLES 4A AND 4B A compositon of nominal formula BiSrCa 2 Cu.0 ^ was prepared in the following manner. Bi 2 0 3 (2.3298 g), Sr0 2 (1.1962 g), CaCO- (2.0018 g) and CuO (2.3865 g) were mixed and ground together in an agate mortar for thirty minutes. The powder mixture was used to press 10 pellets, each 10 mm in diameter and about 2 mm thick. In Example 4A, the pressed pellet was placed on an alumina tray and the tray placed in a furnace and heated in air at a rate of 10°C per minute to 800°C and then held at 800°C for 8 hours. The power was then turned off and the furnace allowed to cool to a temperature below about 100°C before the tray was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the pellet to have an onset of superconductivity at about 75 K. In Example 4B, another pressed pellet was placed on an alumina tray and the tray placed in a furnace and heated in air at a rate of 10 β C per minute to 900 β C and then held at 900°C for 8 hours. The furnace was then cooled at the rate of 2°C per minute to a temperature below about 100°C before the tray was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the pellet to have an onset of superconductivity at about 75 K. EXAMPLE 5 A compositon of nominal formula Bi 2 SrCaCu 3 O κ was prepared in the following manner. Bi 2 0 3 (2.3298 g), Sr0 2 (0.5981 g), CaCO- (0.5005 g) and CuO (1.1933 g) were mixed and ground together in an agate mortar for thirty minutes. The powder mixture was used to press 10 pellets, each 10 mm in diameter and about 2 mm thick. One of the pressed pellets was placed on an alumina tray and the tray placed in a furnace and heated in air at a rate of 10°C per minute to 800 β C and then held at 800°C for 8 hours. The power was then turned off and the furnace allowed to cool to a temperature below about 100°C before the tray was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the pellet to have an onset of superconductivity at about 72 K. EXAMPLES 6A AND 6B A compositon of nominal formula Bi 3,/,2, Sr.3/,2, Ca3./,,2Cu_30x was p r rep ~~ ared in the following' manner. Bi 2 0 3 (2.3298 g), Sr(N0. ) 2 (2.1163 g), CaC0 3 (1.0009 g) and CuO (1.5910 g) were mixed and ground together in an agate mortar for thirty minutes. The powder mixture was used to press 10 pellets, each 10 mm in diameter and about 2 mm thick. in Example 6A, the pressed pellet was placed on an alumina tray and the tray placed in a furnace and heated in air at a rate of 10°C per minute to 800°C and then held at 800°C for 30 hours. The power was then turned off and the furnace allowed to cool to a temperature below about 100°C before the tray was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the pellet to have an onset of superconductivity at a temperature below 77 K. This is consistent with the results found in Example 2. In Example 6B, another pressed pellet was placed on an alumina tray and the tray placed in a furnace and heated in air at a rate of 10 β C per minute to 850 β C and then held at 850 β C for 12 hours. The power was then turned off and the furnace allowed to cool to a temperature below about 100°C before the tray was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the pellet to have an onset of superconductivity at about 85 K. EXAMPLE 7 A compositon of nominal formula Bi 3,/,,2 Sr3,/„4 . Ca3,/,4. Cu3, 0x was p r rep c ared in the following 3 manner. Bi 2 0 3 (4.6596 g), Sr0 2 (1.1962 g), CaC0 3 (1.0009 g) and CuO (3.1816 g) were mixed and ground together in an agate mortar for thirty minutes. The powder was placed in an alumina container and the container placed in a furnace and heated in air at a rate of 10°C per minute to 850°C and then held at 850°C for 12 hours. The power was then turned off and the furnace allowed to cool to a temperature below about 100°C before the container was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the powder product to have an onset of superconductivity at about 70 K. EXAMPLE 8 A compositon of nominal formula Bi J/2 Sr j /β Ca β Cu 3 ° x was prepared in the following manner. Bi 2 0 3 (4.6596 g), Sr0 2 (0.5981 g), CaC0 3 (1.5014 g) and CuO (3.1816 g) were mixed and ground together in an agate mortar for thirty minutes. The powder was placed in an alumina container and the container placed in a furnace and heated in air at a rate of 10°C per minute to 850°C and then held at 850°C for 12 hours. The power was then turned off and the furnace allowed to cool to a temperature below about 100°C before the container was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the powder product to have an onset of superconductivity at about 70 K. EXAMPLE 9 A compositon of nominal formula Bi 3,/,,2 Sr3,/,2, Ca,3 /,2,Cu3, 0x was p creprared in the following - » manner. Bi 2 ° 3 (4.6596 g), Sr0 2 (2.3924 g), CaC0 3 (2.0018 g) and CuO (3.1816 g) were mixed and ground together in an agate mortar for thirty minutes. The powder mixture was used to press 10 pellets, each 10 mm in diameter and about 2 mm thick. One of the pressed pellets was placed on a gold tray and the tray placed in a furnace and heated in air at a rate of 10 β C per minute to 850°C and then held at.850°C for 48 hours. The pellet was then removed from the furnace, quenched in air and the black crystalline product recovered. Measurement of the Meissner effect showed the product to have an onset of superconduc i ity at about 115 K. EXAMPLE 10 A compositon of nominal formula Bi 2 Sr 2 CaCu 3 0^ was prepared in the following manner. Bi 2 0. (4.6596 g), SrO. (2.3924 g), CaC0 3 (1.0009 g) and CuO (2.3865 g) were mixed and ground together in an agate mortar for thirty minutes. The powder mixture was used to press 10 pellets, each 10 mm in diameter and about 2 mm thick. One of the pressed pellets was placed on a gold tray and the tray placed in a furnace and heated in air at a rate of 10°C per minute to 850°C and then held at 850°C for 48 hours. The pellet was then removed from the furnace, quenched in air and the black crystalline product recovered. Measurement of the Meissner effect showed the product to have an onset of superconducti ity at about 115 K. EXAMPLE 11 A compositon of nominal formula Bi 3 Sr. CaCu 3 O χ was prepared in the following manner. Bi 2 0. (4.6596 g), Sr0 2 (2.3924 g), CaC0 3 (0.6800 g) and CuO (1.5910 g) were mixed and ground together in an agate mortar for thirty minutes. The powder mixture was used to press 10 pellets, each 10 mm in diameter and about 2 mm thick . In Example 3A, the pressed pellet was placed on an alumina tray and the tray placed in a furnace and heated in air at a rate of 10°C per minute to 800°C and then held at 800°C for 8 hours. The power was then turned off and the furnace allowed to cool to a temperature below about 100°C before the tray was removed. The black crystalline product was recovered. Measurement of the Meissner effect showed the pellet to have an onset of superconductivity at about 72 K. EXAMPLE 12 A compositon of nominal formula Bi 2 Sr 2 CaCu.0^ was prepared in the following manner. Bi 2 0 3 (4.6596 g), Sr0 2 (2.3924 g), CaCO. (1.0009 g) and CuO (2.3865 g) were mixed and ground together in an agate mortar for thirty minutes. The powder mixture was used to press 10 pellets, each 10 mm in diameter and about 2 mm thick. One of the pressed pellets was placed on a gold tray and the tray placed in a furnace and heated in air at a rate of 10°C per minute to 875°C and then held at 875°C for 36 hours. The furnance was then cooled at the rate of 1°C per minute to a temperature below about 100°C before the tray was removed. Plate-like crystals which exhibited cleavage in the basal plane were predominant in the melt. They were mechanically separated and used for further characterization and structure determination. Both flux exclusion and electrical resistivity measurement on the single crystals revealed a sharp superconducting transition at T c of about 95 K. The superconducting metal oxide phase of this composition was identified as B i 2 S r 3 - c C a I CU 2 °. * where "z" was about 0.65 and "w" was less than 1 but greater than zero. The stru-cture based on an A-centered orthorho bic cell with a - 5.409$, b - 5.414& and c = 30.914A was determined by using single crystal x-ray diffraction data. The structure was made up of alternating double copper-oxygen sheets and double bismuth-oxygen sheets. There were Ca* * and Sr 2* cations between the adjacent Cu-0 sheets; Sr 2* cations were also found between the Cu-0 and Bi-0 sheets. High resolution transmission electron microscopy studies showed that the b axis is actually 27.07 A, an increase of a factor of five over the subcell dimension. This superstructure can also be observed by x-ray diffraction on single crystals but twinning can make it appear that the superstructure is along both the a and b axes. It should be understood that when "z" in the formula for the metal oxide superconducting phase is anywhere from about 0.1 to 0.9, "a" and "b" are both about 5.4A and "c" is about 31A, while** , β andY(the angles associated with the unit cell as known to those skilled in the art) are about 90°. Furthermore, as shown in this example, one or two of the subcell dimensions (a or b or c) can be multiplied by an integer of from about 2 to about 10 to obtain a cell exhibiting the superstructure of the superconducting phase of this invention.

Claims: CLAIMS The Invention Being Claimed Is: 1. A superconducting composition having the nominal formula Bi ■ SrbCacCu3,0x wherein a is from about 1 to 2, b is from about 3/8 to 4, c is from about 3/4 to 2 , x ■= (1.5a + b + c + y) where y is from about 2 to 5 with the proviso that "b + c" is from about 3/2 to 5, said composition having a superconducting transition temperature of at least 70 K. 2. A superconducting composition as in Claim 1 wherein "a" is from about 3/2 to 2, "b" is from about 3/2 to 4, "c" is from about 1 to 3/2, and "b + c" is about 3-5. 3. A superconducting composition as in Claim 2 wherein "a" is 2, "b" is 2 , and "c" is 1. 4. A superconducting composition having the nominal formula Bia SrbCacCu3, 0x wherein a is from about 1 to 3, b is from about 3/8 to 4, c is from about 3/16 to 2, x -* (1.5a + b + c + y) where y is from about 2 to 5 with the proviso that "b + c" is from about 3/2 to 5, said composition having a superconducting transition temperature of at least 70 K. 5. A superconducting composition as in Claim 1 wherein "a" is from about 3/2 to 3, "b" is from about 3/2 to 4, " c" is from about 1/2 to 3/2, and "b + c" is about 3-5. 6. A superconducting composition containing a metal oxide phase of the formula Bi 2, Sr I_ - l Ca i Cυ2,0.. ♦ u wherein z is a value from about 0. " 1 to about 0.9; w is a value greater than zero and less thant 12. 7. A superconducting composition as in Claim 6 wherein "z" is from about 0.4 to about 0.8. 8. A superconducting composition as in Claim 6 wherein "z" is 0.6 to 0.7 and wherein the said metal oxide phase has the structure based on o an A-centered orthorhombic cell with a « 5.409A, b ■= 5.414A and c = 30.914A. 9. A process for making superconducting compositions consisting essentially of mixing stoichiometric quantities of oxides or oxide precursors to provide the composition of Claim 1 or 4 or 6; heating the mixture in air to a temperature of about 775°C to 900°C and maintaining said temperature for about 8 to 48 hours to form said composition; cooling said composition to a temperature below 100°C. 10. A process as in Claim 4 wherein said heated composition is cooled by quenching at a temperature below 100°C. 11. A process as in Claim 4 wherein the stoichiometric quantities of the oxides or oxide precursors are selected to provide the composition of Claim 5. 12. A method for conducting an electrical current within a conductor material without electrical resistive losses comprising the steps of: cooling a conductor material composed of a composition of Claim 1, 4 or 6 to a temperatu e of at least 77 K up to 115 K; initiating a flow of electrical current within said conductor material while maintaining said material within said temperature . 13. An improved Josephson-effeet device wherein the superconductive material comprises the composition of Claim 1, 4 or 6.

Inventors: GOPALAKRISHNAN JAGANNATHA, SLEIGHT ARTHUR WILLIAM, SUBRAMANIAN MUNIRPALLAM APPADO, GOPALAKRISHNAN, JAGANNATHA, SLEIGHT, ARTHUR, WILLIAM, SUBRAMANIAN, MUNIRPALLAM, APPADORAI
Applicants: DU PONT, E.I. DU PONT DE NEMOURS AND COMPANY
Application year: 1989
Main classification: C01F11
IPC codes: C01G29, C04B35, C30B1, H01L39