PNEUMATIC TIRES

Abstract: A radial ply pneumatic tire (10) has carcass plies (13,14,15) reinforced by cables comprising only yarns of aramid filaments, and belt plies (31-35) reinforced by cables comprising at least two yarns of aramid filaments and a core yarn consisting of at least one polyamide or polyester filament which have at least a partially oriented structure, said aramid yarns being adjacent to one another and twisted about said core yarn but not being twisted together with one another.

Description: The present invention relates to a pneumatic tire comprising a carcass ply which has a plurality of first cables oriented at 76° to 90° with respect to a mid-circumferential plane of the tire, each of said first cables comprising two or more first yarns twisted together with one another, each of said first yarns consists of a plurality of aramid filaments, two or more belt plies being disposed radially outwardly of said carcass plies in a crown region of the tire. Such a tire is known for example from FR-A-2 590 207. In EP-A-0 296 093 (published on 21.12.88 and cited under Art. 54(3)EPC) is disclosed a pneumatic tire comprising a carcass ply which has a plurality of first cables oriented at 75° to 90° with respect to a mid-circumferential plane of the tire, each of said first cables comprising two or more first yarns twisted together with one another, each of said first yarns consists of a plurality of aramid filaments, two or more belt plies being disposed radially outwardly of said carcass ply in a crown region of the tire, each of said belt plies comprising a plurality of second cables comprising at least two second yarns consisting of aramid filaments, and the first cables of the carcass ply having a twist multiplier in the range of 8 to 12 and a twist ratio in the range of 1 to 1.9. It is generally recognized in the tire art that tires suitable for use on aircraft must be capable of operating under conditions of very high speeds and large loads as compared to tires used on automobiles, busses, trucks or similar earthbound vehicles. As used herein and in the claims, a tire is "suitable for use on an aircraft" if the tire is of a size and load range, or ply rating, specified for an aircraft tire in either the YEARBOOK OF THE TIRE AND RIM ASSOCIATION , or the YEARBOOK OF THE EUROPEAN TYRE AND RIM TECHNICAL ORGANIZATION , for the year in which the tire is manufactured, or in the current U.S.A. military specification "MIL-T-5041". A tire in accordance with the characterizing portion of claim 1 is capable of operating under large loads at high speeds. To acquaint persons skilled in the art with the principles of the invention, certain presently preferred embodiments illustrative of the best mode now contemplated for the practice of the invention are described herein making reference to the attached drawings forming a part of the specifications and in which drawings: Fig. 1 is a cross-sectional view of a tire according to a preferred embodiment of the invention taken in a plane that contains the axis of rotation of the tire; Fig. 2 is an enlarged fragmentary view of a bead portion of the tire illustrated in Fig. 1; Fig. 3 is an enlarged view of an aramid cable suitable for use in a carcass ply of a tire according to the invention; Fig. 4 is a diagrammatic representation of the concept of twist ratio; Fig. 5 is a graph of cable fatigue performance as a function of twist multiplier for an aramid cable; Fig. 6 is a graph of cable breaking strength as a function of twist multiplier for an aramid cable; Fig. 7 is an enlarged view of a cable suitable for use in a belt ply of a tire according to the invention; and Figs. 8 and 9 are schematic representations of cross-sections of cables suitable for use in a belt ply of a tire according to the invention. With reference to Figs. 1 and 2, an aircraft tire 10 of size 46 x 16 R 20 according to a preferred embodiment of the invention has a pair of substantially inextensible annular bead cores 11,12 which are axially spaced apart with two or more carcass plies 13,14,15 extending between the bead cores. As used herein and in the claims, the terms "axial" and "axially" refer to directions which are parallel to the axis of rotation of a tire, and the terms "radial" and "radially" refer to directions that are perpendicular to the axis of rotation of a tire. Each of the carcass plies 13,14,15 comprises a plurality of first cables oriented at 76° to 90°, preferably 76° to 86°, with respect to a mid-circumferential plane (CP) of the tire. Put another way, a tire in accordance with the present invention is commonly referred to as a radial ply tire. As used herein and in the claims, the "mid-circumferential plane" of a tire is a plane that is perpendicular to the axis of rotation of the tire and is located midway between the sidewalls of a tire when the tire is not subjected to any load. In a preferred embodiment of the invention the carcass plies comprise two ore more turn-up carcass plies 13,14 and at least one turn-down carcass ply 15. Each of the turn-up carcass plies 13,14 is folded axially and radially outwardly about each of the bead cores 11,12 and the turn-down carcass ply 15 is folded radially and axially inwardly about each of the bead cores 11,12 and the turn-up carcass plies 13,14. Preferably the turn-down carcass ply 15 is folded around the bead core 12 to such a degree that the edge 50 of said turn-down ply is axially outwardly of the midpoint 51 of the axial extent of the bead core 12. Tires have been manufactured in which the cables of the first turn-down carcass ply 13 were oriented at 78° with respect to the mid-circumferential plane CP, the cables of the second carcass ply 14 were oriented at 79° with respect to the mid-circumferential plane CP, and the cables of the third carcass ply 15 were oriented at 80° with respect to the mid-circumferential plane CP, all of the cables of all of the carcass plies being inclined in the same sense with respect to the mid-circumferential plane. It is believed that in preferred embodiments of the invention the orientation of the cables in each carcass ply should be nearer to 90° than the orientation of the cables of the radially next innermost carcass ply and the included angles between the angles of radially adjacent carcass plies should not be greater than 10°, and preferably not greater than 2°. If the tire is of the tubeless variety a substantially air impervious layer 52 is disposed inwardly of all of the carcass plies 13,14,15. Most preferably a barrier ply (not shown) is disposed between the air impervious layer 52 and the innermost carcass ply 13. The barrier ply functions to separate the air impervious layer from the elastomeric material in which the cables of the carcass ply 13 are embedded. Tires have been manufactured according to the invention having a barrier ply comprising cables of 840/1 nylon. The cables of all of the carcass plies 13,14,15 are substantially the same, and an example of such a first cable is shown in Fig. 3. Each of the first cables 20 in the carcass plies comprises two or more first yarns 21,22,23 that are twisted together. Each of the yarns 21,22,23 in the cables 20 of each of the carcass plies 13,14,15 consists of a plurality of aramid filaments 24. As used herein and in the claims, "consisting of", or "consists of" is understood to mean that no filaments of any material other than that specified are present in a yarn. As used herein and in the appended claims "aramid" is understood to mean a manufactured fiber in which the fiber forming substance is generally recognized as a long chain synthetic aromatic polyamide in which at least 85% of the amide linkages are attached directly to two aromatic rings. Representative of an aramid is a poly(p-phenyleneterephthalamide). The cables 20 of all of the carcass plies 13,14,15 both turn-up and turn-down carcass plies, have a twist ratio in the range of 1 to 1.2 and a twist multiplier in the range of 8 to 10. The use of such aramid cables in a carcass ply of a tire is disclosed in commonly assigned United States Patent Application Number 061,364 filed on June 15, 1987, corresponding to EP-A-0 296 093. The concept of "twist ratio" can be explained by referring to Fig. 4. In a cable 20 used in practicing the present invention, each of the yarns 21,22,23 has its component aramid filaments twisted together a given number of turns per unit of length of the yarn (typically, the unit of length is 2.54 cm or 1 inch) and the yarns are twisted together a given number of turns per unit of length of the cable. In the practice of the present invention, the yarn twist (as indicated by arrows 21A,22A,23A) and the cable twist (as indicated by arrow 20A) are opposite in direction. As used herein the direction of twist refers to the direction of slope of the spirals of a yarn or cable when it is held vertically. If the slope of the spirals conforms in direction to the slope of the letter "S", then the twist is called "S" or "left hand". If the slope of the spirals conforms to the slope of the letter "Z", then the slope is called "Z" or "right hand". If, for example only, as shown in Fig. 3, the filaments are twisted together to form yarns 21,22,23, each of which have nine turns per unit of length in the directions indicated by arrows 21A,22A and 23A and the yarns are then twisted together in the direction indicated by arrow 20A at eight turns per unit of length, the resultant cable will have a "twist ratio" of 9/8 or 1.125. It is understood that as used herein and in the appended claims, the term "twist ratio" means the ratio of the number of turns per unit of length imparted to the yarns before they are twisted together to form a cable to the number of turns per unit of length imparted to the yarns when twisting the yarns together to form a cable. If, for example only, with reference to Fig. 4, the filaments in the yarns 21,22,23 each have ten turns per unit of linear length imparted thereto in the direction indicated by arrows 21A, 22A and 23A and then the yarns are twisted together in the direction indicated by arrow 20A at five turns per unit of linear length, then the resultant cable will have a twist ratio of 2.0. It is recognized in the art that a twist ratio of 2.0 yields what is referred to as a "0 torque" or "balanced" cable. In a cable which will be used in a carcass ply of a tire according to the invention, the twist ratio is in the range of 1.0 to 1.2. Twist ratio is important because it affects the degree of off-balance in a cable, and therefore, the handling of the cable during the various steps of manufacturing a tire, such as fabric weaving and/or calendering, fabric cutting, and tire building. Another important concept in cables used to reinforce pneumatic tires is "twist multiplier" which refers to a number that is an indicator of the helix angle that the yarns in a cable make with respect to a longitudinal axis of a cable. As used herein and in the claims, the twist multiplier of a cable is determined according to the following equation which is well known in the textile art: wherein TM is the twist multiplier; CT is the number of turns per 2.54 cm in the cable; and CD is the sum of the deniers of the yarns, and/or subgroups of the yarns, of the cable before any twist is imparted to the yarns. It is important to note that as used herein, all references to denier, of both yarns and cables, relate to the denier of a yarn, or yarns, before any twist is imparted to the yarn(s). Of course, when a twist is imparted to a yarn or cable, the actual weight per unit of length increases. "Denier" is understood to mean the weight in grams of 9,000 meters of a yarn, or subgroups of the yarn, before the yarn (or subgroups of a yarn) has any twist imparted thereto. For example, a 1500/3 cable comprises three yarns each of which has a denier of 1500 before any twist at all is imparted thereto, such that the cable denier (CD) is 4500. In reality though, twisting forces a cable to have more mass per unit of length so the actual cable denier is somewhat higher. Twist multiplier is an important characteristic of an aramid cable because a low twist multiplier gives high original tensile strength with low bending strength, while a higher twist multiplier gives better residual strength and better bending strength. It has been found that the handling of the aramid cables after the twisting operations are completed can be enhanced by using the lowest practical tension on the cables during the step of applying an adhesive coating (sometimes referred to as a "dip") to the cable. A tension of 0.5 to 2.0 kg (1 to 2 lbs.) per cable was found to work quite satisfactorily. Table I shows the effect on breaking strength and fatigue in a 1500/3 aramid cable of various twist multipliers (properties given are for dipped cables). The Mallory Test referred to in Table I refers to a well known test in which the cables being tested are subjected to cycles of tension and compression, and the number of cycles until failure is an indication of the fatigue characteristics of the cable. Fig. 5 is a graph based upon the data in Table I showing the square root of the average fatigue life in kilocycles of various cable structures as a function of the twist multiplier. (The square roots of the fatigue lifes are used in order to have a more convenient scale on the graph.) For twist multipliers in the range of 7 to 8, the graph has a very steep slope, and a very small deviation in the twist structure of a cable can have a very significant effect upon the durability of a tire containing the cable. In view of the inconsistencies that exist in currently used cable manufacturing processes, it is felt that twist multipliers in the range of 7 to 8 should be avoided regardless of whether the cable is intended for use in a belt ply or a carcass ply. It has been further noted that in cables having a twist multiplier greater than about 9, there can be kinking of the cables during manufacturing and this kinking problem can be controlled by using an appropriate twist ratio. It can be theorized, although it has not yet been proven, that in the past this same kinking problem occurred in tires during use and resulted in what was called a compression fatigue failure. In the practice of the present invention, it is necessary to use an aramid cable with construction features that yield desired mechanical characteristics to the carcass plies 13,14,15 of a tire. If a cable is to be used as a reinforcing element in a carcass ply of a tire, then its fatigue characteristics are very important because the sidewalls 16,17 of a radial ply tire go through cycles of tension and compression. As shown in Fig. 5, a twist multiplier in the range of 8 to 12 will result in an aramid cable having good fatigue characteristics. Accordingly, tires have been manufactured according to the preferred embodiment in which the cables of the carcass plies had a twist multiplier of 9 and a twist ratio of 1.0-1.2. In said tires, there were about 4 to 5 cables per cm of width of the ply. It is important to note aramid cables with the twist multipliers used in carcass plies according to the invention will not have the maximum possible breaking strength BS, as is evident from Fig. 6, which is a graph showing the breaking strength BS of various cable structures in Table I as a function of the twist multiplier. However, it is believed that the useful strength of the cables will be greater throughout the tire life due to the good fatigue characteristics of the cables. A belt structure 30 comprising two or more belt plies 31-35 is disposed radially outwardly of all of the carcass plies 13,14,15 in a crown region of the tire. A ground engaging tread portion 37 is disposed radially outwardly of the belt structure 30, and a sidewall portion 16,17 extends radially inwardly from each axial edge of the tread portion to a respective bead portion 18,19. In the preferred embodiment illustrated in Fig. 1 one of the belt plies 31 is folded and the remainder of the belt plies 32-35 are unfolded. Each of the belt plies comprises a plurality of second cables oriented at 10° to 20° with respect to a mid-circumferential plane CP of the tire. Tires have been manufactured according to this preferred embodiment with the cables of the folded belt ply 31 oriented at 16° with respect to the mid-circumferential plane CP and the cables of the unfolded belt plies 31-35 oriented at 14° with respect to the mid-circumferential plane CP. One or more wraps 39 of a restricting band of nylon cords oriented at 0° to 25° with respect to the mid-circumferential plane CP is interposed between the belt structure 30 and the tread portion 37. It is understood that the particular belt structure illustrated in Fig. 1 and described herein is merely an example used in a preferred embodiment and that a tire designer may employ any arrangement of folded or unfolded belt plies in accordance with the performance requirements of a particular tire while still practicing the present invention. In a tire according to a preferred embodiment of the invention, each of the belt plies 31-35 comprises second cables 70 comprising (as shown in Figs. 7 and 8) at least two second yarns 71,72,73 consisting of aramid filaments and one core yarn 74 disposed such that each of the aramid yarns 71,72,73 is adjacent to at least one other aramid yarn and is twisted about the core yarn, but the aramid yarns are not twisted about one another. That is to say, the aramid yarns completely surround the core yarn. The core yarn consists of at least one filament selected from the group consisting of polyamides which have at least a partially oriented structure and polyesters which have at least a partially oriented structure. As used herein and in the claims, a "core yarn" is understood to be a yarn that is not twisted together with or twisted around, any other yarn, although the filaments of a core yarn may be twisted together with one another. In a preferred embodiment the core yarn consists of at least one filament of at least partially oriented nylon, and in a most preferred embodiment the core yarn consists of at least two, (usually more than one hundred), filaments of a nylon which has a structure that is at least partially oriented, said nylon filaments being twisted together with one another. "Orientation" and "oriented" refer to the degree of parallelism of the chain molecules of a polyamide or polyester. It is a common practice in the production of man-made textiles to subject the filaments thereof to a drawing process after the spin process. For the purposes of describing and claiming the present invention a polyamide or polyester is understood to have a structure which is at least partially oriented if it requires a force of at least 4 grams per denier to elongate it to a length which is 107% of its original length. Each of the aramid yarns 71,72,73 of the cables of the belt plies may comprise either a single group of aramid filaments or more than one subgroup of filaments, with the subgroups twisted together with one another to form a yarn. This feature of the invention can best be illustrated by referring to Figs. 8 and 9. Fig. 8 is a schematic cross-sectional view of the cable 70 of Fig. 7 looking in the direction indicated by arrows 8-8 of Fig. 7. Fig. 9 is a similar cross-sectional view of an alternative embodiment wherein each of the aramid yarns 71,72,73 of the cable 70 are replaced by a number of subgroups 71a,71b,71c; 72a,72b,72c; 73a,73b,73c which are twisted together to form a yarn having about the same denier as the yarns 71,72,73 of a cable that does not have its yarns divided into subgroups. Cables of the type used in a belt ply of a tire according to the invention are disclosed in commonly owned U.S. Patent Application No. 156,621 which was filed at the U.S. Patent Office February 17, 1988. There are several variables which contribute to the physical properties of the cables used in a belt ply including, but not limited, to aramid denier, aramid vs nonaramid content, twist levels of yarns and cables, the manner in which the twist is imparted to the yarns or subgroups making up the yarns, and the application of coatings to the cables to facilitate their adhesion to a polymeric matrix. The denier of the nonaramid core yarn 74 should preferably be in the range of 5% to 30% of the sum of the deniers of the aramid yarns 71,72,73. This ratio is important because the tenacity and elongation properties of the cables are dependent thereon, and these properties could be adversely affected by ratios outside of the preferred range in some practical applications. A cable according to the invention preferably has a twist multiplier in the range of 5 to 12. In a preferred embodiment of the invention the ratio of the twist imparted to the aramid yarns 71,72,73 before they are assembled with a core yarn, to the twist imparted to the structure during the cabling operation is in the range of 1.0 to 2.0. This twist ratio is an important feature of a cable according to the invention because for a given twist multiplier the twist ratio determines the residual torque in a cable and the fatigue characteristics are highly dependent upon the twist multiplier in conjunction with the twist ratio. It has been observed that in order to improve the properties of the cables used in a belt ply it is preferred, but not always necessary, to twist the aramid filaments into yarns in a two step process. Such a two step twisting process is described in RESEARCH DISCLOSURES 276-103-A. In such a two step process about 30-40% of the total twist is imparted in the first step and the remainder of the twist is imparted in the second step. Increases in tensile strength of about 10% have been experienced by the two step process over the one step process. In the application of an adhesive promoting coating to the belt ply cables the tension, (stretching) on the cables can be varied to attain desired elongation and modulus characteristics in the cable. It is understood that a fabric engineer may in accordance with good engineering practice determine the tension necessary to attain the desired properties in a particular embodiment of the invention. Laboratory tests of cables used in a belt ply of a tire according to the invention have exhibited tensile strength and fatigue resistance that is at least equal to, and often greater than prior art belt ply cables when the overall diameters of the cables was about equal to one another. Cables of this type are desirable in the belt plies of tires which are subjected to extraordinary levels of deflection (such as aircraft tires), because these cables can better dissipate the energy encompassed in the tire as the belt structure passes through the tire footprint, that is to say, the belt structure has to support the deformations required to carry the load placed on the tire. It would take about twice as many nylon cables of the same diameter to provide comparable strength and that would require undesirably thick belt structures. Cables comprising only aramid filaments provide adequate strength but do not have the desired energy dissipating characteristics for high deflection applications. The disposition of reinforcing strips of nylon cords in the bead portions of tires according to the preferred embodiment is believed to contribute to the product performance. In a preferred embodiment of the invention having both turn-up carcass plies 13,14 and at least one turn-down carcass ply 15 there are several reinforcing strips of nylon cords disposed in each bead portion 18,19. The arrangement of the reinforcing strips can best be described by referring to Fig. 2. At least one reinforcing strip 45,46 of nylon cables is folded about each of the bead cores 12 and the turn-up carcass plies 13,14 such that at least a portion of each of the reinforcing strips 45,46 is interposed between the radially innermost turn-up carcass ply 13 and the turn-down carcass ply 15. Preferably, the radially outermost edges of each of these first reinforcing strips 45,46 are disposed radially outwardly of the axial edges of all of the turn-up carcass plies. If desired, a single strip of nylon cords could be substituted for the two strips 45,46 so long as it is disposed in substantially the same manner. Put another way, at least one reinforcing strip 45,46 of nylon cables is folded about each bead core 11,12 such that it is interposed between the radially innermost turn-up carcass ply 13 and the turn-down carcass ply 15. Most preferably at least one reinforcing strip 47,48,49 of nylon cords is disposed such that the portion of the turn-down carcass ply 15 which is folded about and disposed radially inwardly of the bead core 12 is interposed between nylon reinforcing strips 45,46,47. The nylon cables of the reinforcing strips 45-49 should be disposed at angles of not more than 30° with respect to circumferential lines of the tire, preferably at 25° to 30°.

Claims: 1. A pneumatic tire (10) comprising a carcass ply (13,14,15) which has a plurality of first cables (20) oriented at 76° to 90° with respect to a mid-circumferential plane (CP) of the tire, each of said first cables (20) comprising two or more first yarns (21,22,23) twisted together with one another, each of said first yarns (21,22,23) consists of a plurality of aramid filaments (24), two or more belt plies (31-35) being disposed radially outwardly of said carcass ply (13,14,15) in a crown region of the tire, each of said belt plies (31-35) comprising a plurality of second cables (70) comprising at least two second yarns (71,72,73) consisting of aramid filaments and at least one core yarn (74) consisting of at least one polyamide or polyester filament having a structure which is at least partially oriented, said second aramid yarns (71,72,73) being twisted about and completely surrounding said core yarn (74) but not being twisted together with one another, and the first cables (20) of the carcass ply (13,14,15) having a twist multiplier in the range of 8 to 10 and a twist ratio in the range of 1 to 1.2. 2. A pneumatic tire (10) according to claim 1 characterized by said tire comprising three of said carcass plies (13,14,15), the two radially innermost carcass plies (13,14) each having a pair of axial edge portions each of which are folded axially and radially outwardly about an annular bead (11,12), the third carcass ply (15) having a pair of edge portions each of which is folded axially inwardly about the first two carcass plies (13,14) and the annular bead (11,12). 3. A pneumatic tire (10) according to claim 2 characterized by a plurality of strips (45-49) of nylon cables disposed in each bead portion (18,19) of the tire such that the portion of said third carcass ply (15) which is folded about the bead core (11,12) is interposed between strips (45-49) of nylon cables. 4. A pneumatic tire (10) according to any of the preceding claims characterized by one of said belt plies (31) having folds therein and the remainder of the belt plies (32-35) not having any folds therein. 5. A pneumatic tire (10) according to any of the preceding claims characterized by said second cables (70) of said belt plies (31-35) having a twist multiplier in the range of 5 to 12. 6. A pneumatic tire (10) according to any of the preceding claims characterized by said second cables (70) of said belt plies (31-35) having a ratio of twist in the second aramid yarns (71,72,73) to the twist in the second cable in the range of 1.0 to 2.0. 7. A pneumatic tire (10) according to any of the preceding claims characterized in that for each second cable (70) of said belt plies (31-35) the denier of the core yarn (74) is in the range of 5% to 30% of the sum of the deniers of said second aramid yarns (71,72,73) of the same second cable. 8. A pneumatic tire (10) according to any of the preceding claims characterized in that for at least one second cable (70) of one of said belt plies (31-35) at least one of said second aramid yarns (71,72,73) comprises at least two subgroups (71A,71B,71C;72A,72B,72C;73A,73B,73C) of aramid filaments, said subgroups being twisted together with one another to form a second yarn. 9. A pneumatic tire (10) according to any of the preceding claims characterized by the tire being suitable for use on an aircraft.

Inventors: WELTER, THOMAS NICOLAS HUBERT
Applicants: THE GOODYEAR TIRE & RUBBER COMPANY
Application year: 1989
Main classification: B60C9
IPC codes: B60C9, B60C15, B60C19, D02G3, B64C25