MONOCRYSTALLINE MNZN-FERROFERRITE MATERIAL HAVING A HIGH CONTENT OF ZN, AND A MAGNETIC HEAD MANUFACTURED FROM SAID MATERIAL

Abstract: A monocrystalline MnZn-ferroferrite material for use is a magentic head is described. The material corresponds to the formula Mn a Zn b Fe c II Fe₂ III O₄, wherein 0.25 < a < 0.48; 0.50 < b < 0.60; 0.02 < c < 0.15; a + b + c = 1. The magnetostriction constants of this material are particularly small.

Description: The invention relates to a monocrystalline MnZn-ferroferrite material notably suitable for use in a magnetic head. The invention also relates to a magnetic head manufactured from the said material. This type of magnetic heads is used for recording, erasing and playing-back information, for example, in audio and video apparatus. MnZn-ferroferrite material is known from European Patent Application, publication number 86005. The magnetic material described in said Application corresponds to the formula Mn a Zn b Fe c II Fe₂ III O₄, wherein 0 ≦ a < 0.55; 0.06 ≦ b < 0.4 and 0.25 ≦ c < 0.9 while it further holds that a + b + c = 1. This known material has a number of good soft-magnetic properties, for example, a high saturation magnetisation B₈ and a high magnetic permeability µ. It has been established, however, that this material suffers from the disadvantage that the absolute value of the two magnetostriction constants λ₁₀₀ and λ₁₁₁ is high (λ₁₁₁ > 15.10⁻⁶ and λ₁₀₀ < -5.10⁻⁶). The magnetostriction constributes to the so-called "rubbing noise: via the inverse magnetostriction effect. This contribution to the rubbing noise is proportional to the magnitude of the absolute values of the magnetostriction constants. The frequency-dependent rubbing noise is considerable in the MHz-range. Video heads are used in said frequency range (4 -30 MHz). It is an object of the invention to provide a monocrystalline MnZn-ferroferrite material the absolute values of the two magnetostriction constants of which are as small as possible, and that preferably substantially zero. Another object of the invention is to provide a monocrystalline MnZn-ferroferrite having a sufficiently high permeability in the MHz-range. A further object of the invention is to provide a monocrystalline MnZn-ferroferrite material which has a sufficiently high saturation magnetisation. These and other objects are achieved by means of the magnetic material mentioned in the opening paragraph which is characterised according to the invention in that the material corresponds to the formula Mn a Zn b Fe c II Fe₂ III O₄, wherein 0.25 < a < 0.48; 0.50 < b < 0.60; 0.02 < c < 0.15; a + b + c = 1. The magnetostriction constants λ₁₀₀ and λ₁₁₁ of the material according to the invention both have an absolute value which is smaller than or equal to 5.10⁻⁶. The saturation magnetisation and the permeability of the said materials are amply sufficient for use in magnetic heads. The Zn-content in the material according to the invention is of particular importance. If this content is higher than the said upper limit of 0.6, materials are obtained the saturation magnetisation of which is considerably lower than in the materials according to the invention. In the case in which the Zn-content is lower than the said lower limit of 0.5, it appears that the absolute value of at least one of the two magnetostriction constants λ₁₀₀ and λ₁₁₁, and that in particular of λ₁₀₀, increases considerably compared with the material according to the invention. It has been found that the Fe(II)-content is decisive of a number of important magnetic properties to a considerable extent. If the Fe(II)-content is smaller than 0.02, a material is obtained in the Curie temperature (T c ) of which is relatively low, and in which the permeability µ and the saturation magnetisation B₈ are also smaller than those of the material according to the invention. In materials having an Fe(II)-content which is larger than 0.15, the permeability µ has been found to be considerably smaller than in the materials according to the invention, while furthermore the absolute value of λ₁₁₁ in this range increases considerably. The Mn(II)-content of the compounds according to the invention is determined by both the Fe(II)-content and the Zn(II)-content in that the sum of the bivalent elements (a + b + c) must be equal to 1. A preferred embodiment of the invention is characterised in that 0.30 < a < 0.40; 0.50 < b < 0.55; 0.10 < c < 0.15; a + b + c = 1. It has been found that the highest saturation magnetisations B₈ are found in material compositions corresponding hereto. Another preferred embodiment of the invention is characterised in that 0.32 < a < 0.40; 0.57 < b < 0.60; 0.03 < c < 0.08; a + b + c = 1. It has been found that the absolute values of both magnetostriction constants are smallest in material compositions corresponding hereto. It is to be noted that it is surprising that in the MnZn-ferroferrites of a given composition the values of both magnetostriction constants simultaneously are substantially zero. From the work by Ohta which is guiding in this field, it may be derived from Figures 6 and 7 as published in Jap.J.Appl.Phys. 3 (10) 576 (1964) that it is impossible in MnZn-ferroferrites to choose a composition in which both constants simultaneously are substantially zero. This prejudice is overcome by the present invention. The invention will now be described in greater detail with reference to specific examples and the drawing, in which Figure 1 shows a magnetic head the core parts of which consist of material according to the invention. Specific examples Single crystals of MnZn-ferroferrites having different compositions were manufactured by means of the Bridgman method known per se for these uses by melting the composing metal oxides and/or carbonates, in a quantity which corresponds substantially to the indicated mol.fractions of the compound to be manufactured, at 1650°C in an oxygen atmosphere and then crystallising the melt. The growth direction of the crystals was [100], while the growth rate was 2 mm/hour. In this manner single crystals were obtained having a length of 6 cm and a diameter of 2 cm. In the table a number of data are recorded of twelve monocrystalline MnZn-ferroferrites manufactured in the manner described hereinbefore. The reference numerals 1-8 indicate compositions of material according to the invention, while the reference numerals 9-12 denote compositions of materials which do not belong to the invention and serve as comparative examples. It will be obvious from the table that the absolute values of both magnetostriction constants are small to very small in the compounds according to the invention, namely to values smaller than 1.10⁻⁶ (example 2). It may further be derived from the table that the highest saturation magnetisations are generally found in materials according to the invention for which it holds that 0.50 < b < 0.55. As appears from the table, the lowest magnetostriction constants are found in those materials according to the invention for which it holds that 0.57 < b < 0.60. The material of comparative example 9 in which the Zn-content is comparatively high and the Fe(II)-content is comparatively low, shows magnetic properties such as a saturation magnetisation, a permeability and a Curie temperature which are considerably worse than those in the materials according to the invention. In the materials having reference numerals 10-12, in which the Zn-content is comparatively low, the absolute values of both magnetostriction constants appear to be comparatively high. This applies in particular to λ₁₀₀. Figure 1 shows a video head. It is constructed from two core parts 1, 2 of the material according to the invention. At the area of the gap 4 the tape contact surface is narrowed. Coils 5, 6 are wound around both core parts and a write, read or erase signal can be sent through said coils. The use of the magnetic material according to the invention, however, is not restricted to this type of magnetic head.

Claims: A monocrystalline MnZn-ferroferrite material notably suitable for use in a magnetic head, characterised in that the material corresponds to the formula Mn a Zn b Fe c II Fe₂ III O₄, wherein 0.25 < a < 0.48; 0.50 < b < 0.60; 0.02 < c < 0.15; a + b + c = 1. A monocrystalline MnZn-ferroferrite material as claimed in Claim 1, characterised in that 0.30 < a < 0.40; 0.50 < b < 0.55; 0.10 < c < 0.15; a + b + c = 1. A monocrystalline MnZn-ferroferrite material as claimed in Claim 1, characterised in that 0.32 < a < 0.40; 0.57 < b < 0.60; 0.03 < c < 0.08; a + b + c = 1. A magnetic head comprising at least a core part and a coil, characterised in that the core part consists of a monocrystalline MnZn-ferroferrite as claimed in any of the preceding Claims.

Inventors: CILLESSEN, JOHANNES FRANCISCUS MARIA, JOHNSON, MARK THOMAS, PISTORIUS, JOHANNES ADRIANUS
Applicants: N.V. PHILIPS' GLOEILAMPENFABRIEKEN
Application year: 1989
Main classification: C30B29
IPC codes: C30B11, G11B5, C30B29, H01F1