PRIMER/MEMBRANE WATERPROOFING SYSTEM

Abstract: A waterproofing system including a water-based latex primer composition and a waterproofing adhesive membrane. The primer exhibits excellent adhesion to concrete and an excellent surface for adhesion by the waterproofing membrane. The primer is a latex emulsion including butyl acrylate, styrene and acrylonitrile.

Description: The present invention relates to a waterproofing system for construction surfaces, especially concrete construction surfaces, and more particularly relates to a waterproofing system including a water-based, adhesion-promoting primer and an adhesive waterproofing membrane. It is known to seal surfaces, particularly those of concrete, by forming thereon a membrane of a bituminous composition or the like which is substantially impermeable to moisture and water vapor. (The term "bituminous composition" as used herein refers to compositions containing asphalt, tar or pitch. The term "concrete" refers to portland cement concrete as well as other similar construction materials). Bituminous compositions can be spray applied in a heated, softened state. A much preferred alternative to these spray applied materials are the waterproofing membranes such as Bituthene (R) -brand waterproofing membranes of W. R. Grace & Co. Such membranes typically comprise a primary waterproofing layer of rubberized asphalt adhesive adhered to a carrier sheet of e.g. plastic film. The membranes are sold in roll form with a release sheet of silicone-coated Kraft paper covering the asphalt adhesive layer. It is known that adhesion of the rubberized asphalt to the concrete surface is greatly facilitated by the application of a primer to the concrete. Primers currently marketed for us in connection with Bituthene-brand membranes are Bituthene primers P-3000 and P-3100, also products of W. R. Grace & Co. These primers are mixtures of rubbers and resins dissolved in organic solvents. Primers based on aqueous carriers, rather than organic solvents, are desirable. The presence of organic solvents in the workplace is coming under increasing regulatory scrutiny. Unfortunately, water-based latex compositions, as a general rule, do not remain firmly adhered to construction surfaces when immersed in water; they tend to re-emulsify and lose their desired adhesive properties. Another drawback to latex compositions is their tendency to lose stability below a critical temperature of usually about 40°F. Further, the alkaline nature of concrete limits the choice of polymers in the latex to those that will not hydrolyze under these alkaline conditions. Accordingly, the objects of the invention are to provide a water-based primer composition that is highly compatible with both concrete surfaces as well as the rubberized asphalt adhesives employed in waterproofing membranes. The foregoing objects are attained by the present waterproofing system including a waterproofing membrane laminate and a water-based primer. Preferred waterproofing membranes are Bituthene-brand waterproofing membrane products of W. R. Grace & Co. These membranes consist of a carrier sheet, preferably an oriented, cross-laminated polyethylene sheet, adhered to a layer of a rubber-modified asphalt ("rubberized asphalt") pressure sensitive adhesive composition. The membranes are supplied in roll form and are easily applied to vertical or horizontal construction surfaces. The primer compositions of the present system are water-based acrylic latex compositions that can be brushed, rolled or sprayed onto concrete and other construction surfaces. The primer compositions comprise a polymeric component dispersed in a water phase, the polymeric component comprising mostly butyl acrylate (e.g. in an amount not less than 40 wt. %, preferably not less than 70 wt. %), plus styrene (e.g. in an amount not exceeding 60 wt. %, preferably 10 to 25 wt. %) and optionally acrylonitrile (e.g. in an amount not exceeding 10 wt. %, preferably not exceeding 5 wt. %). A suitable dispersant as known to those familiar with the latex emulsion art is employed. While the viscosity of the formulated primer can be predetermined by the formulator to fall within the range of 1 to 100 cps or even higher, room temperature, 50 RPM Brookfield viscosity, optimum penetration into the concrete surface and adhesion thereto has been found in the 5 to 20 cps viscosity range. A particularly preferred latex composition is UCAR (trademark of Union Carbide Corp.) Latex 123. This latex is supplied at a viscosity of approximately 150 cps, consequently, it should be thinned by the addition of water to the desired 5 to 20 cps range. Example UCAR Latex 123 is thinned to a viscosity of 5 to 20 cps and brushed onto concrete block and allowed to dry. A pressure sensitive waterproofing membrane consisting of a plastic carrier sheet and rubberized asphalt adhesive (Bituthene 3000) is adhered to the primer. After one month, both the adhesion of the primer to the concrete and the adhesion of the membrane to the primer remain excellent.

Claims: A waterproofing membrane and primer system comprising a) a waterproofing membrane comprising a carrier sheet and a rubberized asphalt adhesive thereon, and b) a primer composition, adapted to promote adhesion between a concrete construction surface and the waterproofing membrane, comprising a water-based emulsion of a polymeric component comprised of butyl acrylate and styrene. The system of claim 1 wherein said polymeric component comprises, by weight, butyl acrylate in an amount not less than 40%; styrene in an amount not exceeding 60%; and acrylonitrile in an amount not exceeding 10%. The system of claim 1 wherein said polymeric component comprises, by weight, butyl acrylate in an amount not less than 70%; 10 to 25% styrene; and acrylonitrile in an amount not exceeding 5%. A system of claim 1 wherein the primer composition has a viscosity of about 1 to 100 cps. A system of claim 2 wherein the primer composition has a viscosity of about 1 to 100 cps. A system of claim 2 wherein the primer composition has a viscosity of from about 5 to 20 cps. A system of claim 3 wherein the primer composition has a viscosity of from about 5 to 20 cps. A waterproofed concrete surface comprising a primer disposed on the surface and an adhesive waterproofing membrane comprising a carrier sheet and a rubberized asphalt adhesive thereon adhered to said primer, said primer comprising a water-based emulsion of a polymeric component comprised of butyl acrylate and styrene. The waterproofed wall of claim 8 wherein the primer comprises, by weight, butyl acrylate in an amount not less than 70%; 10 to 25% styrene; and acrylonitrile in an amount not exceeding 5%. A method of waterproofing a concrete wall comprising a. applying to the wall a primer composition comprising a water-based emulsion of a polymeric component comprised of butyl acrylate and styrene; b. allowing the primer to dry; and c. applying to the wall and over the primer an adhesive waterproofing membrane comprising a carrier sheet and a rubberized asphalt adhesive thereon. The method of claim 10 wherein the polymeric component comprises, by weight, butyl acrylate in an amount not less than 70%; 10 to 25% styrene; and acrylonitrile in an amount not exceeding 5%. A method of claim 11 wherein the primer has a viscosity of about 1 and 100 cps. A method of claim 11 wherein the primer has a viscosity of about 5 to 20 cps.

Inventors: WIERCINSKI, ROBERT ALAN
Applicants: W.R. GRACE & CO.-CONN.
Application year: 1989
Main classification: C04B41
IPC codes: C04B41, B32B11, B32B7, E04B1