POROUS ARTICLE IMPREGNATION RESIN COMPOSITION, AND SYSTEM FOR TREATING IMPREGNATION PROCESS WASTE WATER

Abstract: A curable composition, useful for impregnating porosity of porous articles, comprising acrylate monomer, heat- and/or anaerobic-cure initiator, and non-peroxy, actinic radiation photoinitiator. A method of treating waste water produced by aqueous washing of a porous article to remove excess impregnant therefrom, wherein the impregnant comprises acrylate monomer and actinic radiation photoinitiator, includes the steps of exposing the waste water to actinic radiation polymerizingly effective for the monomer, and recovering the resulting polymer from the waste water to yield a polymer-depleted effluent which may be discharged to receiving waters.

Description: "P0R0US ARTICLE IMPREGNATION RESIN COMPOSITION, AND SYSTEM FOR TREATING IMPREGNATION PROCESS WASTE WATER" DESCRIPTION Technical Field This invention generally relates to a resin composition for impregnating porous articles, and to a system .for treating waste water from an impregnation process utilizing such resin composition. Background Art 0 Impregnation sealing of mi croporosi ty is a commonly used methodology in the art of forming a variety of articles, structural components, and assemblies, as for example castings, die castings, electronic components, powder metal parts, fiber-reinforced resin composites and other materials 5 which exhibit porosity. Originally, materials, manufactu ing techniques, and casting designs were specified to minimize the occurrence of porosity in formed objects, based on the hypothesis that mi croporosity was structurally and functionally undesirable and its presence in formed articles embodied poor .0 manufacturing. This approach severely limited design freedom, and resulted in significant rejection of parts exhibiting any substantial porosity characteris cs. This design strategy changed in the 1970 ' s as a result of the energy crisis, which resulted in a major switch to lighter metals for structural applications. During this period many -5 iron parts were changed to cast aluminum components, and many other parts were designed as die castings. This switch to lighter metals resulted in weight savings in many applications where energy consumption and power optimization were important, but created a new and persistent problem of mi croporosi ty in the light metal formed parts. The occurrence of mi croporosity is particularly acute in components formed from metal powder, and presents a significant obstacle to commercial utility, particularly when such porous parts are employed in fluid power systems and other liquid handling applications. In order to overcome the deficiencies attendant the presence of microporos ty in formed articles of the above-described types, impregnation sealing technology was developed, by which the porosity of the porous parts was impregnated with a sealant composition. Upon curing of the impregnated sealant, the resulting sealed part is suitable for use in fluid exposure applicat ons, as well as facilitating plating, coating, and further processing, of the formed ar icle. Among the impregnation sealing compositions which have been developed to date are self-curing anaerobic sealants and thermal curing sealants, as well as sealants which cure by both anaerobic and heat cure mechanisms. Electronic encapsulating sealant/coating compositions, curable both anaerobi cal ly and with exposure to UV light, have also been developed for vacuum impregnation of electrical components such as transformers, wherein the encapsulating sealant is anaerobical ly cured inside the device and is cured on the outside surface with UV light to encapsulate the device. To effect a thorough outer surface curing of the sealant, such compositions typically contain a UV photoinitiator in concentrations substantially in excess of 5% by weight, based on the weight of the curable component thereof. In addition, sealant/coating compositions have been developed for sealing of laminates, composite materials, and the like, containing macroscopic or gross voids into which the sealant/coating composition after surface application flows by capillary, or wi eking, action. Generally, sealant/coating compositions employed in such applications are highly viscous in character, having a viscosity substantially greater than 1000 centipoise, as measured by the Cannon-Fenske viscosity determination method. One such conventional formulation, having a Cannon-Fenske viscosity of 4200 centipoise, contains 3.4 weight percent of a UV photoinitiator, based on the weight of curable component in the seal ant/coa i ng composition, to effect surface cure of the composition under UV radiation, in combination with internal anaerobic curing of the composition. ' The high viscosities of, such compositions generally require long processing times for impregnation of mi roporos i ty. As a consequence of external surface UV cure employed for the above-described electronic encapsulating sealant/coating compositions and capillary action impregnant compositions, no washing or other removal of excess surface sealant is required in these impregnation systems. Among the previously developed impregnating compositions for sealing porous parts are the compositions disclosed in the patents identified and discussed below. U.S. Patent 3,672,942 to E. Neumann discloses an anaerobic impregnant comprising a free-radical polymeri zabl e acrylate ester monomer and a free-radical polymerization initiator therefor, e.g., a hydroperoxi de. The patent discloses utilizing an accelerator in the impregnant, such as al dehyde-a i ne condensation products, sulfur-containing free-radical accelerators, or organic compounds containing an oxidizable transition metal. This reference also discloses a vacuum impregnation process in which the porous article is placed in a vacuum vessel, followed by drawing of vacuum therein and covering the article with the disclosed anaerobic sealant so that upon release of vacuum, the sealant is forced into the evacuated porosity of the article. The surface of the impregnated article is then treated with the aforementioned d polymerization accelerator to cure the sealant at the outer surface of the porous article. U.S. Patent 3,969,552 describes a washing process for removing excess impregnant from the surfaces of the porous article after porosity impregnation. The disclosed impregnation composition comprises an acrylic anaerobic curing resin and a peroxy initiator therefor. The wash solution is an aqueous solution of a surfactant of specified formula. The patent further discloses that the aqueous surfactant solution may contain an accelerator to effect polymerization of the anaerobic sealant in the surface areas of the impregnated part being washed. U.S. Reissue 32,240 of J. DeMarco describes a self-emulsifying anaerobic composition for porosity impregnation appl cations, comprising an anaerobi cal ly curing monomer such as an acrylic ester, a peroxy initiator therefor, e.g,, a hydrop ' eroxide or perester, an anionic or nonionic surfactant which is dissolved in the composition and renders it self-emulsifying upon mixing with water, and optionally an accelerator for the anaerobic polymerization, e.g., a sulfimide. The impregnant composition of this patent is described as being readily removed from surface areas of porous parts by simple aqueous rinse, even in difficult areas such as small blind holes in complex castings, from which it is difficult to remove excess anaerobic impregnant even with an aσitated water rinse. U.S. Patent 4,632,945 to M. L. Garcia, et al , discloses an anaerobic sealant material comprising a (meth ) acryl ate monomer, a hydroperoxi de or perester initiator, an accelerator having -SO2NHCO- functionality, and a transition metal co-accelerator comprising a source of copper ion and an iron salt or ferrocenyl compound. J The above-described anaerobic sealant compositions are typically impregnated in the porosity of porous metal parts by wet vacuum impregna ion, wet vacuum/pressure impregnation, or dry vacuum/pressure impregnation. These methods are briefly described below with reference to impregnating of porous parts contained in a basket which is introduced into the impregnation chamber, which is the typical method of parts .0 containment if the parts are of suitably small size; in the case of larger parts, the same are typically mounted on or suspended from hoist or other carrier means which is successively translated through the process system including the impregnation chamber. In the wet vaccum impregnation process, the basket of .5 porous parts is submerged into a vacuum tank of sealant. A short-term, e.g., 10-12 minute, vacuum cycle removes air from the porosity of the parts. The chamber then is returned to ambient pressure, with sealant penetrating into the evacuated porosity. The basket of parts then may be spun briefly in the vaccum tank to allow centrifugal force to eliminate excess Z0 sealant waste. The wet vacuum/pressure impregnation process is similarly conducted, but with the impregnation chamber being pressurized at the end of the vacuum cycle to drive sealant further into small porosity passages. 25 In the dry vaccum/pressure impregnation method, the basket of porous Darts is placed directly in the dry vaccum chamber. Air is evacuated from the porosity in the parts for a selected length of time, e.g., 10 minutes. A transfer valve then is open, allowing sealant to enter the vaccum chamber from a storage reservoir. The chamber is automatically pressurized to force sealant into the parts. After impregnation, while the sealant is being returned to the reservoir, a centrifuge operation spins the basekt to remove excess surface sealant. Among the foregoing methods, wet vaccum impregnation techniques are generally more widely employed than the dry vacuum/pressure impregnation process. In the above-described impregnation systems, the anaerobic sealant, except during the imposition of vacuum, is continuously aerated to prevent polymerization thereof i n situ. Following the initial impregnation step, the impregnated parts are transferred to an agitated water rinse zone, for removal of any remaining surface sealant or sealant trapped in blind holes of the impregnated parts. The agitation of the water rinse zone may be effected by movement of the basket or suspended parts in such zone, and/or mechanical means for effecting circulation of water therein. In the case of small porous parts contained in a basket, it frequently is desirable to operate the water rinse zone in a "tumbling basket" mode to enhance the washing operation and prevent parts with surface sealant deposits which are in contact with one another from sticking together, as a result of polymerization of the con¬ tiguous surface sealant deposits.. Following the removal of excess impregnant, the impregnated and water-rinsed parts may be transferred in the carrier basket or by conveyor to an activator zone in which the impregnated parts are contacted w th a catalyst activator solution, to effect curing of the sealant material at the entrance to the pores in the parts. This creates a hardened plug or cap of sealant material in the outer portion of the pore, trapping the resin for anaerobic self-cure. Thereafter, the impregnated parts may be transferred to a final rinse zone for removal of the activator solution from the impregnated parts. This final rinse solution may be at elevated temperature, e.g., on the order of about 120°F, to warm the impregnated parts for quick drying, and to accelerate curing of the anaerobic impregnant within the interior porosity of the article, the rate of such cure increasing with 0 increasing temperature. The final rinse step may also incorporate in the rinse solution suitable rust inhibitor material, for application of a rust inhibiting f lm to the impregnated article. As a va iation on the above-described impregnation system, it is known to utilize a heat-curing resin in place .5 of the anaerobi cally-curing resin, whereby the activating and final rinsing steps previously described are eliminated in favor of a hot rinse final step. In the heat-curing resin impregnation system, the parts after impregnation and rinsing of excess surface material, are contacted with hot water at temperatures on the order of ' 90°C to cure the impregnant !0 resin. In all of the above-descr bed impregnation systems, the aqueous washing of the impregnated parts to remove excess surface sealant or sealant trapped in blind holes results in passage of the excess removed resin into the aqueous washing -5 medium. The anaerobic-cure and/or thermal-cure impregnation resins are substantially insoluble in the aqueous washing medium, resulting in the formation of a dispersion or emulsion of the impregnation resin monomer. tn order to maximize excess sealant removal action in the aqueous rinse step, clean make-up water is introduced to the rinse tank either continuously or in batch fashion, with corresponding discharge of monomer-containing water from such tank, as waste water eff1 uent. Tn conventional impregnation systems of the type described hereinabove, the monomer content of the waste water from the process system may be on the order of from about 0.1 percent up to about 8-10 weight percent (based on the total weight of waste water), or even higher, with concentrations of 0.1-3% being typically encountered. Heretofore, this monomer-containing waste water effluent of the impregnation process system has either been discharged directly to receiving waters, or else subjected to treatment via conventional biological effluent treatment processes, e.g., activated sludge processing, microbial digestion, etc. In some instances, the discharge of monomer-containing waste water has resulted in monomer accumulation in the effluent discharge passages and associated valves, tanks, etc., with the result that the agglomerated monomer may experience sufficient lack of oxygen, particularly in the interior of the agglomerated onomeric mass, to cause polymer zation to occur. Such build-up of monomer/polymer in the system, if not checked or removed by perodic maintenance, can result in constriction and eventually plugging of effluent water discharge means. Although the direct discharge or biological treatment of monomer-containing waste water from impregnation systems has been generally satisfactory from an environmental standpoint, there is nonetheless a continuing need to improve the effluent quality of discharge streams from such systems, under the impetus of increasing environmental awareness and legislative and regulatory constraints. Japanese Patent Application No. 50-47237 filed April 17, 1975 and published October 25, 1976, describes a method for treating eluted waste liquids containing high molecular weight photosensitive resins and low molecular weight reaction monomers, by adding a polymerization initiator to the eluted waste liquid, and subjecting the liquid to heat or light to cause the monomers therein to react (reaction time of 20-40 minutes is disclosed in the specification of this publication, with Example 4 thereof describing photopolymeri - zation by illuminating the waste liquid for one hour with a hi gh- pressure mercury lamp). The reaction product waste liquid then is passed to a concentration tank, from which it is repeatedly circulated through an ul trafi 1 trat i on apparatus, until concentrated by a factor of 10-15 in the concentration tank. During the ul trafi 1 tration processing of waste liquid, a filtrate is produced which is reused as eluent in the process. When the predetermined concentration in the concentration tank has been achieved, feeding of waste liquid to the concentration tank is discontinued and the ultrafi 1tration apparatus is shut down. Thereafter, the con¬ centrated waste liquid is mixed with heavy or ' light oil, and subjected to combustion treatment. The resins disclosed by the patent publication include polyvinyl alcohol, partially hydrolyzed polyvinyl acetate, carbonyl polyvinyl alcohol, hydroxyethyl cellulose, gelatine, and water-soluble nylon. The monomers disclosed therein include acrylates or methacryl ates with free hydroxyl groups in the alcohol moieties, half esters of acrylic or ethacrylic acids of polyethylene glycol, or ones in which the free hydroxyl groups are etherified or esterified. As thermal polymer zat on initiators, there are disclosed persulfates, redox catalysts, ammonium persulfate-sod urn thiol, cumene hydroperoxi de-cuprous salts, etc., and the disclosed photopoly eri zat on initiators include water-sol ble azo compounds and metal ion initiators. The polymerizat on initiators may be employed at concentra- tions of 0.05-0.2 parts by weight per 100 parts by weight of the waste liquid, and antifoaming agents such as silicone emulsions may be added to prevent foaming during the developing and eluting process steps. West Germany Offenl egungsschrift 27 05 169 published August 10, 1978, discloses a process for treating waste waters 0 containing from about 15% to about 80% by weight of emulsified polymerizabl e liquid substances, based on the total weight of waste water, wherein 0.1-10 weight percent polymerization initiators, based on the total weight of waste water, are added for polymerization of the polymerizable substances in the waste water. The polymerizat on is carried out at temperatures of between 0°C and 180°C and pressures of up to 5 10 bar, preferably between 50°C and 95°C under normal pressure, followed by separation of the polymerization products from the water. This publication discloses the use of polymerization initiators such as peroxides and/or hydroperoxides , and the use of polymerization accelerators 0 such as tertiary amines, organic cobalt, and vanadium salts. The disclosed process is described as applicable to treatment of waste water from impregnation of metal castings with unsaturated polyesters. (Meth)acryl esters are also disclosed as polymerizable emulsifiable monomers to which the disclosed 5 process- is applicable. The waste water treatment process disclosed in the West German patent publication described in the preceding paragraph is disadvantageous, insofar as it effects polymerization of _ the polymerizable substances therein at elevated temperature, since the resulting waste heat of the waste water must be dissipated so that the final effluent is at near-ambient temperature. This is generally required by environmental regulations, e.g., those promulgated by the U.S. Environmental Protection Agency and various state environmental agencies. . If these effluent requirements are not met, the resulting thermal pollution may seriously adversely effect the quality of receiving waters, damage or destroy marine life, etc. Accordingly, when polymerization treatment of monomer-containing waste water is conducted at elevated temperature levels, corresponding refrigeration requirements .0 are imposed on the process system, to achieve the requisite near-ambient final effluent discharge temperatures. It is therefore an object of the present invention to provide an impregnation system wherein the effluent waste water from the water washing removal of excess resin from the impregnation parts, is treated to be significantly depleted in ,.5 impregnant monomer content. It is another object of the invention to provide an impregnation composition for impregnating the porosity of porous articles, which when removed in excess amount from impregnated porous articles by aqueous washing, is readily 1Q removable from the aqueous washing/rinse medium. Other objects and advantages of the invention will be more fully apparent from the ensuing disclosure and appended claims. SUMMARY OF THE INVENTION 5 In one aspect, the present invention relates to a curable impregnant composition, having utility for impregnation of mi croporos i ty, comprising: (a) acrylate monomer; (b) initiator for heat-cure and/or anaerobic cure of said acrylic monomer; and (c) non-peroxy, actinic radiation photoinitiator. The actinic radiation photoinitiator in this composition may for example be present in an amount not exceeding about 5 percent by weight, based on the weight of the monomer. In another aspect, the invention relates to a method of treating waste water produced by aqueous washing of an 5 impregnated porous article to remove excess impregnant therefrom, wherein the impregnant is a curable composition including acrylate monomer and photoiniti tor, comprising the steps of: (i) exposing at least a portion of said waste water 10 to actinic radiation polymerizi ngly effective for the aforementioned monomer in the presence of the photoinitiator, thereby forming polymer of such monomer in the waste water; and (ii) recovering the polymer from the polymer-containing waste water to yield a 15 polymer-depleted waste water. Another aspect of the invention relates to a method of waste water treatment as described above wherein a composition agglomeratingly effective for the monomer and/or polymer is added to the waste water prior to the reco v ery step. Yet another aspect of the invention relates to apparatus 10. for impregnating porous articles and treating waste water resulting from aqueous washing of the impregnated articles to remove excess impregnant therefrom, such apparatus comprising: (a) an impregnation chamber for impregnation sealing of porous articles; 15 (b) means for drawing a vacuum on the impregnation chamber, to evacuate porosity of the porous articles therein; (c) means for contacting porous articles in the impregnation chamber with a curable impregnant composition at higher-than- acumm pressure; (d) an aqueous rinse chamber for contacting porous articles after their impregnation with an aqueous rinse medi urn; (e) means for introducing aqueous rinse medium to the aqueous rinse chamber; (f) an actinic radiation exposure chamber; (g) means for generating actinic radiation and transmitting same into the actinic radiation exposure chamber; (h) means for transferring effluent aqueous rinse medium from the rinse chamber to the actinic radiation exposure chamber; (i ) a filtration system; (j) means for transmitting effluent aqueous rinse medium, after actinic radiation exposure, from the actinic radiation exposure chamber to the filtration system; (k) means for discharging filtered solids from the filtration system; and (1 ) means for discharging sol ds-depleted aqueous rinse medium from the filtration system. A further aspect of the invention relates to a process for impregnating porosity of a porous article and treating waste water produced by aqueous rinse removal of excess impregnant therefrom, comprising: (a) impregnating porosity of the porous article with an impregnant comprising (i) acrylate monomer, (ii) ini tiator for initiating curing of said acrylate monomer upon exclusion of oxygen, and/or heating of said monomer, and (iii) non-peroxy, actinic ~ > radiation photoinitiator; (b) removing excess impregnant from the porous article by aqueous rinsing thereof to produce an effluent rinse water containing removed excess impregnant; (c) curing the impregnant impregnated in the porosity .0 of the porous article; (d) exposing the effluent rinse water containing the removed excess impregnant to actinic radiation which is curi.ngly effective for polymerization of acrylate monomer therein, to yield an effluent rinse water containing corresponding polymer; and .5 (e) recovering corresponding polymer from the effluent rinse water. Other features and advantages of the invention will be more fully apparent from the ensuing disclosure and appended cla s. BRIEF DESCRIPTION OF THE DRAWINGS .0 The single Figure is a schematic illustration of a process system according to one embodiment of the present invention for impregnating porosity of porous articles and treating waste water produced by aqueous rinse removal of excess applied impregnant from the impregnated porous articles. DETAILED DESCRIPTION OF THE INVENTION, AND PREFERRED EMBODIMENTS THEREOF The present invention is based on the discovery that anaerobic- and/or heat-curing, acrylate monomer-based sealant compositions utilized for impregnation of porosity of porous articles may advantageously be formulated with photoi niti ators . In use, effluent rinse water produced by aqueous washing removal of excess applied impregnant, may be treated by actinic radiation exposure which is curingly effective in the presence of the photoinitiator for monomer in the impregnant composition, followed by recovery of resultingly formed polymer from the waste water, to yield an .0 " effluent waste water depleted in monomer and polymer, suitable for discharge to rece ving waters. Thus, the impregnant composition of the invention comprises: (i) acrylate monomer; (ii) initiator which is effective for curing monomer upon exclusion of oxygen and/or LE heating of the monomer, via free-radical polymerization; and (iii) non-peroxy, actinic radiation photoinitiator which is effective for initiating photopolymeri zation of monomer under actinic radiation exposure conditions. Although, as previously described in the "Background of ZXD the Invention" section hereof, it has been conventional practice to utilize acrylate monomers in impregnant compositions containing peroxy initiators, for anaerobic- and/or heat-curing of such compositions, and although the aforementioned Japanese Patent Application 50-47237 discloses 15 to treat eluted waste liquids of photosensitive resins by thermal polymerization or photopolymen ' zation of the monomers in the waste liquid, using suitable thermal initiators or photoi niti ators, we are not aware of any previous utilization of acrylate monomer-based impregnant compositions comprising 310 (1) initiator for anaerobic- and/or thermal-cure of the i pregnated composition, in combination with (2) non-peroxy, actinic radiation photoinitiator, for actinic radiation polymer zation of monomer in effluent rinse water produced by aqueous washing of excess applied impregnant from impregnated porous parts. The acrylate "monomer" used in the impregnant composition of the invention may be a single acrylate component, or a mixture of different acrylate species. Preferably at least a portion of the acrylate monomer comprises a di- or other polyacrylate ester. These polyfunctional monomers produce cross-linked polymers, which serve as more effective and more durable sealants. While various acrylate monomers may be used, the most highly preferred are polyacrylate esters which have the following general formula: wherein R^ represents a radical selected from the group con¬ sisting of hydrogen, lower alkyl of from 1 to about 4 carbon atoms, hydroxyalkyl of from 1 to about 4 carbon atoms, and R3 is a radical selected from the group consisting of hydrogen, halogen, and lower alkyl of from 1 to about 4 carbon atoms; R5 is a radical selected from the group consisting of 15 hydrogen, hydroxyl, and m may be 0 to about 12, and preferably from 0 to about 6; n is equal to at least 1, e.g., 1 to about 20 or more, and preferably between about 2 to about 6; and p is 0 or 1. The polymerizable polyacrylate esters corresponding to the above general formula are exemplified by, but not restricted to, the following materials: di-, tri- and tetraethyl eneglycol dimethacryl ate, di propyl eneglycol dimethacryl ate ; polyethyl eneglycol dimethacryl ate; di ( pentamethyl eneg lycol ) dimethacryl ate; tetraethyleneglyco 1 diacrylate; tetraethyleneglycol di - (chl oroacry1 ate ) ; diglycerol diacrylate; diglycerol tetramethacryl ate; tetramethyl ene dimethacryl ate; ethylene dimethacryl ate; and neopentyl glycol di acryl ate . While polyacrylate esters, especially the polyacrylate esters described in the preceding paragraphs, have been found particularly desirable, monofunct i onal acrylate esters (esters containing one acrylate group) also may be advantageously used. The most common of these monofunct ional esters are the alkyl esters such as isobutyl methacryl ate . Many of the lower molecular weight alkyl esters are quite volatile and fre¬ quently it is more desirable to use a higher molecular weight homolog, such as decyl methacrylate or dodecyl methacryl ate . When dealing with monofunct i onal acrylate esters, it is preferable to use an ester which has a relatively polar alcoholic moiety. Such materials are less volatile than low olecular weight alkyl esters and, in addition, the polar group tends to provide i ntermolecul ar attraction in the cured polymer, thus producing a more durable seal. Most preferably the polar group is selected from the group consisting of labile hydrogen, heterocyclic ring, hydroxy, amino, cyano, and halogen polar groups. Typical examples of compounds within this category are cycl ohexylmethacryl ate, tetrahydrofurfuryl methacrylate, hydroxyethyl acrylate, hydroxypropyl methacryl ate, t-butyl mi noethyl methacrylate, cyanoethyl acryl ate, and chloroethyl methacrylate. Other acrylates can also be used. However, when other acrylates are used they preferably are used in combination with one or more members from either or both of the above-descri ed classes of acrylate monomers. In impregnant compositions comprising a mixture of mono- and di- acrylates, the mono-acryl ate monomer may suitably comprise from about 20 to about 80 percent by weight of the total weight of mono- and di-acrylate monomers. Most preferably, polyacr 1 ates having the chemical formula given above, comprise at least a portion, preferably at least about 50 percent by weight of the acry- 1 ates. The monomers described above are given anaerobic or heat-cure characteristics by incorporating therein an appropriate polymerization initiator system. The initiator must be capable of inducing polymerization of the monomer or monomers in the substantial absence of oxygen and/or under elevated temperature conditions. Acrylate monomers useful in the present invention may be conveniently cured through a free-radical mechanism, with an initiator system comprising a redox polymerization initiator, i.e., an ingredient or a combination of ingredients which produce an oxidation- reduction reaction, resulting in the production of free radicals. Suitable initiator systems of this type include peroxy materials which, under the appropriate conditions, decompose to form peroxy free radicals. A class of peroxy initiators which has been found particularly efficient when used in combination with the acrylate monomers described above, is the hydroperoxy . initiators. Of this class, the organic hydroperoxides are the most preferred. Cumene hydroperoxi de and t-butyl hydro- peroxide have been used with particular success in initiating anaerobic curing of acrylate monomers. Methyl ethyl ketone hydroperoxi de may likewise by employed. Inorganic peroxides and compounds such as peresters which decompose to form free LO radicals are also useful. In heat-curing acrylate monomer systems, initiators which may be satisfactorily employed include t-butyl perbenzoate, benzoyl peroxide, benzpinacol, and azo initiators such as those commercially available under the trademark Vazo ® (Vazo ® initiators 52, 64, 67 and 68) from 15 E. I. duPont de Nemours and Company, Inc., Wilmington, Del aware. As used herein, the term "peroxy" is intended to mean peroxides, hydroperoxides , and peresters, which are suitable fo preparing anaerobi cal ly- and/or heat-curing monomer systems. 20 For purposes of versatility, it frequently is desirable to incorporate in the curable impregnant compositions of the invention various initiator accelerators, for example, hydro- peroxide decomposition accelerators, when hydroperoxi des are used as cure initiators in the impregnated sealant material. Typical examples are tertiary amines such as tributyl amine, Z5 sulfimides such as benzoic sulfimide, formamide, and compounds containing transition metals such as copper octanoate. The impregnant compositions of the invention are suitably non-aqueous, i.e., substantially water-free, in character. The viscosity of the impregnant compositions of the invention suitably does not exceed about 1000 centipoise, and preferably such viscosity is less than about 100 centipoise, most preferably below about 50 centipoise. As used herein, viscosity values are those measured by the Cannon-Fenske method. While the amount of peroxy polyme ization initiator in the impregnant composition of the invention can vary over wide ranges, it usually is impractical for such initiator to comprise more than about 10 percent by weight of the composition, and it preferably does not comprise more than .0 about 5 percent of the composition by weight. Most preferably the peroxy polymerization initiator comprises from about 0.2 percent to about 3 percent by weight of the composition. The weight percent of the peroxy polymerization initiator should not be allowed to decrease below about 0.1 percent, since below that level the cure rate will be unduly slow. -E Frequently it may be desirable to add one or more comonomers to the acrylate system, e,g., to modify the viscosity, solvent resistance, or other characteristics of the cured or uncured composition. While a mixture of acrylates generally can be used successfully, other unsaturated comonomers can be used as well. These comonomers typically Q w ll be monomers capable of relatively rapid vinyl-type polymerization so that they can copolymerize, at least to a limited extent, with the reactive acrylate monomers. For example, acrylic functionality-containing resins, such as epoxy acrylate and urethane acrylate oligomers and prepolymers, 5 can be advantageously used. When such comonomers are used, they preferably should not be used in amounts which exceed about about 50 percent of the total weight of the acrylate monomer in the system. Other ingredients can be added as well , provided they do not adversely affect the sealing function of the impregnant composi t i on . In the impregnation process, the impregnant composition in the porosity of the porous article is cured under anaerobic- and/or heat-cure conditions to form a hard, durable 5 resin in the interior porosity of the article. In conventional impregnation processes, as previously described, the porous parts are typically subjected to vacuum either under "wet vaccum" or "dry vaccum" conditions, whereby contact with the impregnant at higher-than-vacuum pressure effects flow of the impregnant into the interior porosity of the 0 parts. Subsequently, the impregnated parts may be spun or otherwise translated in the impregnation chamber above the main resin volume therein, to drain the impregnant from the exterior surfaces of the porous parts. Even after such removal of gross surface accumulations of the impregnant, there is a significant amount of impregnant at the surface of the porous 15 articles, particularly in the vicinity of the pores. When the impregnant is anaerobically cured, the aforementioned surface accumulations as well as the outermost layer of the impregnant in the pores of the article, particularly shallow surface pores are in contact with oxygen, 20. so that such surface quantities of the impregnant are uncured or only partially cured. For this reason, the impregnated article is subsequently contacted with an activator for curing of the monomer. The resultiπgly formed polymer present in shallow surface pores or otherwise accumulated on the surface 25 of the article is highly undesirable, since it can readily contaminate the environment of the porous part, being removable by normal abrasion or by contact with various liquids. In addition, such surface polymer deposits may, by virtue of their thickness, cause the impregnated product part to vary from the desired dimensional specifications, thus rendering the part deficient or even useless for its intended function in applications requiring close dimensional tolerances. Further, such surface polymer deposits may interfere with subsequent painting, plating, or assembly operations which frequently are performed on porous articles subsequent to their impregnation. Specif c al ly, such surface polymer deposits may be removed during painting or plating operations, resulting in contamination of the baths used in such operations, and may interfere with the adhesion of paint, plating, etc., to the impregnated part. When the acrylate monomer is heat-cured, any residual surface accumulations of impregnant are likewise highly undesirable since they produce localized surface asperities which may interfere with subsequent painting or plating operations, or cause delamination of applied paint or plated fi 1ms . Based on the desirability of removing residual surface accumulations of the impregnant after the impregnation step (such residual surface accumulations herein termed "excess" impregnant), it is conventional practice to subject the porous parts after impregnation to an aqueous washing step, or "water rinse." The washing step removes the excess impregnant, and the washed porous parts from which excess impregnant has been removed, then may be transferred to subsequent treatment steps, such as activation (immersion of the impregnated parts in an activator solution), heating, final rinsing, drying, application of rust inhibitor, etc. The aqueous washing for removal of excess impregnant from the impregnated porous parts, results in the formation of impregnant- contai ni ng rinse water. The acrylate monomer, being organic and substantially insoluble in the aqueous wash medium, is dispersed along with the other impregnant constituents, in the wash water. The aqueous washing medium is typically aerated by an air sparger or otherwise agitated to maximize washing efficiency, so that the impregnant becomes finely dispersed in the aqeuous wash medium. Further, it has become conventional practice to utilize in the aqueous medium, and/or the impregnant composition, surfactant materials which facilitate the water wash removal of excess impregnant. The use of surfactants and specific surfactant materials utilized for such purpose are more fully described in U.S. Patent No. 3,969,552, and U.S. Reissue Patent No. 32,240, the disclosures of which are hereby incorporated by reference herein. The use of such surfactants in the rinse medium and/or impregnant composition, enables higher concentrations of acrylate monomer in the rins-e water to be achieved, and results in the formation of an emulsion of acrylate monomer in the rinse water. A specific feature of the impregnant composition of the present invention is the incorporation therein of a suitable non-peroxy photoinitiator, which is curingly effective for the acrylate monomer in the composition, to initiate polymerization thereof under actinic radiation exposure conditions. As a result of this incorporation of photoi nti ator , the waste water which is produced by aqueous washing removal of excess impregnant, may be treated by subjecting the waste water to actinic radiation exposure conditions causing polymerization of acrylate monomer therein. Under such actinic radiation exposure conditions, polymerization of the monomer depletes the waste water in acrylate monomer content, and produces a polymer-containing waste water, from which polymer may be recovered to yield a final waste water effluent of reduced monomer and polymer content, for discharge to receiving waters. A preferred mode of recovering polymer from the actinic radiation-treated waste water effluent is filtration thereof. With regard to the polymerization and reco very treatment of the present invention, it is to. be noted that precursor acrylate monomer is typically of sub-micron size in aqueous 'dispersion. At such size, the dispersed liquid monomer moieties change shape and pass through conventional porous filter media, so that the monomer is not recoverable by filtration processes, even by ultrafi 1trat on . The solid polymer, by contrast, is readily recovered from the waste water A combined actinic radiation exposure and filtration apparatus having utility for effecting such acrylate monomer polymer zation and filtration removal of resulting polymer from the waste water is disclosed and claimed in copending U.S. Patent Application Serial No. (P.P. 87-17) filed concurrently herewith on January 11, 1988 in the name of Charles M. Muisener, and entitled "Water Purification System." As an alternative to utilizing the photoi nit ator- containing impregnant composition of the present i-nvention, a suitable photoinitiator may be separately introduced to the impregnated part aqueous washing chamber, and/or or to the rinse water effluent withdrawn therefrom, for subsequent actinic radiation exposure and polymer reco very treatment in accordance with the invention. Such separate introduction of photoinitiator to the aqueous washing chamber and/or the rinse water effluent therefrom, is generally less desirable than simply incorporating such photointiator in the sealant composition, since the amount of photoinitiator required for effective waste water treatment is typical ly significantly increased. However, it may be feasible to utilize, for such separate introduction to the rinse chamber and/or rinse water withdrawn therefrom, a hydrophobic photoinitiator or other photoinitiator having a greater affinity for the aqueously dispersed impregnant than for the aqueous medium. This should allow for minimizing the dosage of photoinitiator required for such separate addition operat i on ( s ) . Even so, it is not believed to be as effective as direct incorporation of the Q photoinitiator in the impregnant composition. The photoini iator employed in the impregnant composition or otherwise separately added to effect polymerization of the acrylate monomer content of the aqueous washing effluent waste water may comprise any suitable photoinit ator which is effective to induce polymerization of the monomer under E appropriate actinic radiation exposure conditions. Chemical classes of photoi ni ti ators which may potentially be useful in the broad practice of the present invention for this purpose include, but are not limited to, benzoin ethers, alpha dicarbonyl derivatives, chloroacetophenones, alpha hydroxyketones, acyl phosphi ne oxides, aromatic ketones, ionium LQ " salts, and tertiary amines. The suitability of specific initiator species from the foregoing classes may be readily determined without undue experimentation by the simple expedient of exposing an aqueous dispersion of the monomer containing the photoinitiator to actinic radiation, IE determining a suitable concentration by corresponding tests at varying initiator concentrations. Preferred photoi ni ti ators from the aforementioned classes include the benzoin ether commercially available under the trademark Vicure ® 10 from Stauffer Chemical Company (Westport, CT); the al phadi arbonyl photoinitiator commercially available under the trademark Irgacure ® 651, from Ciba-Geigy (Ardsley, New York); di ethoxyacetophenone; and the alpha hγdroxy- ketone initiator available under the trademark Irgacure ® 184 from Ciba-Geigy (Ardsley, New York). When the photoinitiator is employed as a component of the impregnant composition, the concentration of the photoinit ator desirably should not exceed about 5 percent by weight, based on the weight of the acrylate monomer. Typically, concentrations of the photo nitiator may suitably range from about 0.05 to 5 percent by weight, based on the weight of monomer, preferably from about 0.1 to about 2 percent by weight, and most preferably from about 0.5 to about 1 percent by weight, on the same basis. As indicated hereinabove, larger amounts of the photoinitiator may be employed and gnerally are required where the photoinitiator is added directly to the washing medium in the rinse chamber, and/or to monomer-containing waste water discharged from such chamber. A highly advantageous impregnant composition containing a peroxy initiator and a non-peroxy photoinitiator in accordance with the present invention, may suitably comprise 70-75 percent of a dimethacrylate ester and 25-30 percent of a monomethacrylate ester, wherein the amounts of acrylate monomers are by weight, and the respective weight percentages of the dimethacrylate and the monomethacrylate esters total to 100 percent, in combination with 0.25 percent peroxy initiator, 0.5-1 percent non-peroxy photoinitiator, 0.3 percent polymerization accelerator (e.g., beπzosulfimide) , and 0.05 percent inhibitor, e.g., hydroquinone, wherein the non-acrylate component concentrations are by weight, based on the weight of total monomer. Such preferred impregnant composition may also utilize a small amount of a suitable fluorescent additive, e.g., about 0.02 percent by weight, based on the weight of total monomer, of a fluorescent indicator such as the fluorescent composition commercially available under the tradename Natmar Scanning Compound No. 5 (Angstrom Technology, Florence, Kentucky). In use, the impregnant composition may be conventionally employed in an impregnation chamber of typical construction, wherein a "wet" or "dry" vaccum is imposed on the porous parts to be impregnated, and the evacuated porous parts contact the impregnant composition at higher, e.g., ambient, pressure, whereby the impregnant composition passes into the porosity of the porous parts to effect impregnation thereof. The impregnant composit on, when of anaerob ' ic curing character, is typically aerated or otherwise maintained in an aerobic state up until the vacuum is applied in the course of the impregnation step, to minimize the occurrence of premature curing or gellation in the impregnation apparatus. It may be suitable in some instances to add catalyst or accelerator species, such as the copper and iron salts/complexes disclosed in U.S. 4,632,945, to the impregnant composition. Stabilizer additives such as dilute sulfuric or phosphoric acid or pyridinyl chelator species may also be added to the impregnant composition. Referring now to the single Figure, there is shown a schematic depiction of a process system for "dry vacuum" impregnation of porosity of porous articles, and treatment of monomer-containing waste water formed by water rinse removal of excess impregnant from the porous articles, together with subsequent illustrative treatment steps for the impregnated porous parts. While the invention is shown with respect to a "dry vaccum" arrangement, it will be recognized that this description is for illustrative purposes only, and that the impregnant composition and waste water treatment method of the present invention are equally applicable to process systems including "wet vacuum" impregnation of porous parts, the choice of "wet" or "dry" vacuum impregnation depending on the composition and porous character of the porous parts, and their intended end use application. The porous part impregnation and waste water treatment system in this illustrative embodiment comprises an impregnation chamber 10 having an interior volume 12 in which is disposed basket 14 containing porous metal parts (not shown for clarity). The impregnation chamber 10 is joined in flow communication via conduit 16 with a vacuum generating means 18, for selectively drawing a vacuum on the impregnation chamber, so that the air therein is withdrawn to evacuate the porosity of the porous parts in the basket and de-aerate the i pregnant. Subsequent to evacuation of the interior volume 12 of the impregnation chamber 10, impregnant composition stored in reservoir 20 and maintained therein in an aerobic state, at higher pressure than the evacuated chamber, is flowed in line 22 into the interior volume of the impregnation chamber. The anaerobic impregnant in reservoir 20 may also be deaerated by means of conduit 16a joining the reservoir with the vacuum generating means, just prior to transferring the impregnant from the reservoir to the impregnation chamber. The vacuum drawn by the vacuum generating means 18 is discontinued once the impregnant fills the impregnation chamber to the desired extent. As a result, the impregnant penetrates into the porosity of the porous parts in basket 14. Such hydrostatic impregnation may be further assisted by reversing the vacuum generating means 18 to pressurize the interior volume of the impregnation chamber, to force the impregnant composition further into small porosity passages. Subsequent to this impregnation, the impregnant composition is returned via line 22 to the impregnant reservoir 20. W ile the sealant is being returned to the reservoir, the basket 14 is spun briefly (by means not shown for clarity) to allow centrifugal force to remove the major portion of the impregnant on the exterior surfaces of the porous parts. Subsequent to this impregnation, the basket containing the impregnated porous parts is removed from the impregnation cha Der and transferred, via a suitable support 24 joined to the basket, to the aqueous washing chamber 26, for water rinse .0 removal of excess impregnant from the impregnated porous arti cl es . The aqueous washing chamber 26 is furnished with clean rinse water by a clean water source 28, from which rinse water is flowed in line 30 into the aqueous wash chamber 26. -5 The aqueous wash chamber 26 may suitably receive sparged air in a lower portion of the liquid 32 therein, by a sparger 34 joined by air feed line 36 to a source 38 of compressed air, e.g., a conventional air compressor. The purpose of such air sparging operation is to induce circulatory flow within the wash liquid volume so that residual surface sealant and IQ sealant in shallow surface pores is efficiently removed from the impregnated porous articles in basket 14. Alternatively, or in addition to the utilization of sparging means as described above, there may be employed in the aqueous washing chamber 26 suitable oscillating and/or ZE tumbling means (not shown) of known conventional type, to maximize the efficiency of removal of the excess impregnant. As a result of the removal of excess impregnant in the aqueous washing chamber, the wash liquid becomes mixed with the removed impregnant composition. The resulting acrylate monomer-contaiπi ng liquid is discharged from the aqueous washing chamber 26 by means of overflow weir 40, or other suitable discharge means, into effluent line 42. Alternative¬ ly, a bottom or intermediate withdrawal of the monomer- containing liquid could be effected. The flow rate of effluent aqueous washing medium waste water in line 42 may be E monitored or otherwise controlled consistent with the rate of introduction of clean rinse water in line 30, as desired, to maintain a highly efficient aqueous washing removal of excess impregnant from the impregnated porous articles in the washing chamber . The impregnant-contai ni ng waste water discharged in line 1Q 42 from the aqueous washing chamber typically contains from about 0.1 up to about 8-10 weight percent, or more, of the acrylate monomer, based on the total weight of waste water comprising same, and preferably from about 0.1 to about 3 weight percent, on the same basis. As indicated, the impregnant is in dispersed form, typically in emulsified form IE where the impregnant is self-emulsifying in character or where surfactants or other e u! sifi cati on-produci ng components have been added to the impregnant, and/or to the aqueous washing medium in the aqueous wash chamber 26, and/or to the waste water effluent therefrom. Z0 The impregnant-contai ni ng waste water from the washing chamber 26 is passed in line 42 to the actinic radiation expo¬ sure chamber 44, constructed with an actinic radiation transmissive wall, window, or other portion through which actinic radiation from the actinic radiation source 46 can pass to irradiate the monomer-containing waste water therein. ZE It may be suitable in this respect to fabricate the entire actinic radiation exposure chamber 44 of an actinic radiation- transmissive material, optionally with the provision of multiple circumferential ly spaced-apart actinic radiation sources, to maximize the irradiation of the waste water in the chamber 44, by way of minimizing the size and retention time characteristics of such chamber. With regard to the operation of the actinic radiation exposure chamber, monomer-containing waste water may be processed therein in any convenient flow mode, e.g., batch, semi-batch, or continuous flow. In general, however, continuous flow processing is preferred, wherein monomer-containing waste water is continuously withdrawn from the aqueous washing chamber and flowed through the actinic radiation exposure chamber for conversion of monomer in the waste water to . polymer. The size and configuration of the actinic radiation exposure chamber may be varied widely depending on the volumetric flow rate of waste water being processed, its monomer concentration, the actinic radiation wavelength and intensity, etc., with the specifi c ' character and dimensions being readily determi neabl e without undue experiment by those skilled in the art, to achieve a specific desired level of monomer conversion efficiency. In general, the maximum depth of actinic radiation penetration in the monomer-containing waste water may be on the order of several inches. In an exposure chamber presenting a larger depth of waste water to the actinic radiation, it may be desirable to mix or otherwise induce sufficient circulation of the liquid volume in the chamber, in order to ensure a desired high level of actinic radiation exposure and conversion of monomer throughout the liquid vol u e. Consistent with the foregoing consideration, when the actinic radiation exposure chamber is properly dimensioned in relation to the depth of penetration of the actinic radiation and to the extent of circulatory flow of liquid in the chamber, it is generally feasible to obtain substantially complete conversion of monomer to polymer with a retention time of waste water in the chamber on the order of about 5 minutes or less, and preferably about 1 minute or less, particularly when "thin film" irradiation processing of waste water, as described hereinafter in greater detail, is employed. Using an actinic radiation exposure chamber of square shape having a transverse dimension of 10 inches and a longitudinal dimension of 12 inches, by way of illustration, the depth of waste water may vary from about 0.25 inch to about 3 inches, or more. In this illustrative system, the volumetric flow rate of monomer-containing waste water through the actinic radiation exposure chamber may range from about 1 to about 12 gallons per minute, and more typically from about 3 to about 7 gallons per minute. In full-scale waste wa ' ter treatment systems, the volumetric flow rate of waste water will widely vary, and may be as large as several hundred gallons of waste water per hour or even thousands of gallons of waste water per hour, depend¬ ing on the specific impregnant composition, the number, type, and intensity of actinic radiation source means, the type of parts being impregnated, the excess sealant washing requirements, etc. As used herein, "actinic radiation" means electromagnetic radiation having a wavelength of about 700 nanometers (nm) or less which is capable, in the presence of the photoinitiator component, of curing the acrylate monomer in the waste water. The photoiniti tor is present in an amount effective to respond to the actinic radiation and to initiate and induce curing of the acrylate monomer by polymerization thereof, but low enough in amount so that the photoinitiator does not initiate substantial polymerization of the impregnated sealant composition in the impregnation tank or during transfer of the impregnated porous parts to subsequent treatment steps, under incandescent, fluorescent, or mercury vapor illumination, or sunlight conditions, as typically encountered in porosity impregnation process environments. The reason that the amount of photoinitiator is below such ambient light polymerization concentration is to avoid "skinning" or surface 5 cure of the impregnant composition on the porous metal parts, prior to the aqueous washing removal of excess impregnant therefrom. Accordingly, it generally is desirable to maintain the concentration of photoinitiator in the impregnant composition of the invention below about 5% by weight, based on the weight of acrylate monomer, e.g., below about 4 weight LO percent, on the same basis. Preferably, the actinic radiation generated by actinic radiation source 46 is ultraviolet (UV) radiation, and the photoinitiator is a UV initiator. Suitable photoi ni ti ators useful with UV radi ' ation curing IE of acrylate monomers in the process of the invention include free-radical generating UV initiators such as benzophenone, di ethoxyacetophenone, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, di ethoxyxanthone, ch 1 orothi oxanthone, azo-bi s-i sobutyroni tri 1 e , N-methyl di ethanol ami ne benzophenone, and mixtures thereof. ZOl When the actinic radiation includes visible light, suitable photoi ni ti tors may include camphoroqui none used with an aromatic amine; and fluorenone peresters of the type disclosed in U. S. Patent 4,604,295. Visible light-activated photoi ni ti ators are, however, in general much less preferred than UV initiators, due to the practical problems associated ZE with controlling the visible light exposure of the acrylate monomer-containing waste water in an ambient process environment . Thus, the acrylate monomer-containing waste water is exposed to actinic radiation in chamber 44 to at least partially polymerize the monomer content of the waste water stream. It is generally desirable to maintain the waste water in chamber 44 in a highly mixed condition, to maximize 5 polymerization efficiency when the waste water is polymerized in bulk volume. For this purpose, the actinic radiation exposure chamber 44 may contain static mixer means, wall-mounted turbulence promotors, mechanical mixing means, etc. (not shown for clarity). 10. It has also been found highly advantageous and is preferred to continuously flow the acrylate monomer-conta ning waste water in a thin film, e.g., not exceeding about 3 inches in thickness, preferably not more than about 1 inch thick, and most preferably from about 0.25 to about 0.50 inch thickness, 201 through the actinic radiation exposure zone. Such "thin film" irradiation of the monomer-containing waste water eliminates the need for mixing, which is otherwise necessary if a bulk volume of the monomer-containing waste water is to be efficiently exposed to actinic radiation. ZE As indicated, the actinic radiation is preferably UV radiation. The UV radiation may for example have a wavelength of 365 nanometers at an intensity of from about 80,000 to about 350,000 microwatts per square centimeter. The actinic radiation exposure results in polymerization of monomer in the waste water, to produce polymer-containing, ) monomer-depleted waste water which is discharged from the actinic radiation exposure chamber 44 in discharge line 48, and passed to the filtration system 50. The filtration system may be of any suitable type, wherein the polymer-conta ning waste water is subjected to filtration to recover a polymer-depleted filtrate, which may be discharged from the filtration system in line 52 and passed to receiving waters. Optionally, at least part of the final effluent waste water from line 52 may be diverted in line 54 and passed to rinse water feed line 30, as additional make-up water for the aqueous was ing step. The filtration system is preferably of a type as disclosed and claimed in U.S. application Serial No. (87-17 ) filed concurrently herewith on January 11, 1988 in the name of Charles M. Muisener and entitled "Water Purification System." In the filtration system disclosed in this concurrently filed application, a solids-containing liquid is contacted with a continuously translated web of filter paper, and the resulting solids-bearing web is discharged from the filtration zone. As shown in the Figure hereof, filter web 52, of a character which is filteringly effective for the polymer in the waste water, is discharged from the filtration system 50 in the direction indicated by arrow A and wound on a take-up roller 54 rotated in the direction indicated by arrow R (by suitable motive means not shown). The resulting roll 56 of filter paper bearing the recovered polymer may then be suitably disposed of, or processed for recovery of the polymer from the filter web, and subsequent reuse of the filter web. Alternatively, in lieu of roll take-up of the polymer-bearing filter web, the effluent filter web may simply be discharged into a receiving box or other container, for further treatment and/or disposition, as desired. The above-referenced concurrently filed application discloses a combined apparatus for photopoly erization of the acrylate monomer in the waste water, and filtration re co very of the resultant formed polymer, in a unitary apparatus construction, which may be suitably employed as a constitutent part of the impregnation and waste water treatment system of the present invention. As an optional feature of the process system shown in the Figure, it may be advantageous in the broad practice of the invention to provide a source reservoir 60 of a suitable composition or material capable of aggregating or agglomerating the acrylate monomer and/or corresponding polymer, for enhancing the effectiveness of the process. While any suitable material of such type may usefully be employed, polyelectrolytes which are aggl omerati ngly effective for the acrylate monomer and/or correspond ng polymer in aqueous medium are preferred. The ensuing discussion of the illustrative embodiment of the invention will thus refer to polyelectrolyte materials for carrying out such function, it being understood that such reference is merely illustrative, and that any other suitable materials useful for such purpose may be advantageously employed. Depending on the opened or closed character of valves 62 and 64 in the respective feed lines 66 and 68, the polyelectrolyte is flowed from the source reservoir 60 for mixing with the acrylate monomer-contain ng waste water in line 42, or the polymer-containing, monomer-depleted waste water in line 48, or both, as desired. Such addition of polyelectrolyte to the waste water stream may be advantageous in coalescing the dispersion of monomer and/or polymer, to enhance the efficacy of the respective actinic radiation exposure and polymer recovery steps. Any suitable polyelectrolyte material which is generally effective for coalescing the monomer- and/or polymer-containing dispersion may be employed for this purpose. Examples of illustrative polyelectrolyte materials which may be potentially useful in the broad practice of the invention include an oil-water emulsion of a cationic polyacrylamide, commercially available under the trademark Magnifloc ® I596C from American Cyanamid Company, Wayne, New ersey. Subsequent to the aqueous washing step conducted in aqueous washing chamber 26, in which the retention time of the basket of impregnated porous parts may be on the order of 1-2 minutes, the basket of parts is removed from the aqueous washing chamber and transferred to subsequent treatment steps, as may be desirable or required to complete curing of the impregnant composition and/or further processing of the porous articles for their intended end use. The Figure depicts two such additional illustrative treatment steps - activation treatment, and final rinse application of a rust inhibitor to the porous parts. It will be recognized that the subsequent treatment steps (after the aqueous washing removal of excess impregnant) are intended to be illustrative only (for an exemplary anaerobic impregnant composition of the present invention), and not to be limitingly construed with respect to the impregnation, aqueous washing, and waste water treatment process and apparatus of the present invention. It will be appreciated in the practice of the invention utilizing heat-curing impregnant compositions, activation treatment is not employed; instead the porous parts after washing of excess impregnant therefrom are passed to a chamber containing hot water at elevated temperature, e.g., 90°C, to complete the curing of ' the heat-cure impregnant. Accordingly, the ensuing description with reference to the Figure is in respect of an anaerobic-cu ing impregnant composition. The Figure shows a first (post-aqueous washing) subsequent step, in which the basket 14 of porous parts coupled with support 24, after the rinse removal of excess impregnant as previously described, is introduced into activation chamber 70. The activation chamber 70 contains an aqueous solution 72 of an activator material, as supplied from activator reservoir 74 to the chamber in line 76, to cure the impregnant composition at the entrance to the pores in the porous parts. This creates a hardened plug or cap in the outer portion of the pores, trapping the remaining curable composition in the interior pore volume of the porosity, for anaerobic self-cure, in the case of impregnant compositions which are anaerobi cal ly curing in character. The activator may be any suitable material which is effective to cure the impregnant at the surface of each porosity. Illustrative of suitable activator species which may be potentially usefully employed in combination with anaerobically-cur ng impregnant compositions, are erythorbic acid, sodium erythorbate, ascorbic acid and ascorbic acid derivatives, thiourea, and sodium metabi sulfite. The concentration of activator in the aqueous solution 72 may suitably be up to about 2 percent by weight, based on the weight of water in the solution, with concentrations on the order of 1 percent by weight, on the same basis, being generally usefully employed. Subsequent to the activation step, the basket 14 of impregnated porous parts is removed from the activator chamber, and transferred to the final rinse chamber 80 containing aqueous rinse solution 82, to remove residual activator solution from the impregnated porous parts and warm the parts for quick drying. In the rinse chamber as illustrated, the application of a rust inhibiting coating to the rinsed porous impregnated articles may also be effected by transferring a water-soluble rust inhibitor from reservoir 84 to the chamber 80 in feed line 86. In this manner the final rinse removes activator solution, as described, and also effects the coating of the impregnated porous article with a film of a suitable rust inhibitor, on the outer surfaces of the impregnated article. The final rinse solution is typically maintained at a temperature of from about ambient temperature up to elevated temperatures on the order of about 120°F. The rust inhibitor which is introduced from reservoir 84 into the aqueous rinse solution 82 must be compatible with the impregnation resin, since after the basket of final treated parts is removed from chamber 80 and the impregnated porous parts removed therefrom, the basket is returned to the head of the process system, filled with new porous parts to be impregnated, and passed to the impregnation chamber 10 for processing in the successive treatment chambers previously described. If the final rinse solution carried over to the impregnation chamber 10 on the basket surfaces is reactive with the impregnant composition, the impregnation process and subsequent treatment steps may be adversely affected. For this reason, nitrite-based rust inhibitors are to be avoided in anaerobic-cure impregnant systems, since the nitrite-based rust inhibitors are generally reactive therewith. Nitrite-based rust inhibitors may, however, be generally advantageously utilized in heat-curing impregnant compositions of the. invention. Illustrative of rust inhibitor compositions which may be usefully employed in the final ' rinse chamber are the materials commercially available under the trademarks Van Straaten 4171 (Van Straaten Corporation, Chicago, Illinois), and Rust Veto 65 (E. F. Houghton & Company, Philadelphia, Penns lvania). Although the preceding discussion with respect to the application of rust inhibitor has been described in application to an anaerobic-cure impregnant composition, as applied in a final rinse chamber following the application of activator to the impregnated porous parts, it will be appreciated that rust inhibitor compositions may be correspondingly applied to porous parts after their impregnation with heat-cure impregnant compositions. For example, the rust inhibitor may be added to the liquid volume in the hot water curing tank wherein the heat-cure impregnant is exposed to elevated temperatures for curing thereof. The porous parts or articles to which the impregnant composition and technology of the present invention are applicable include castings, die castings, electronic compo¬ nents, powder metal parts, plastic composites such as fiber- reinforced resin assemblies, as well as any other porosity-containing articles which are advantageously porosity-sealed. The porosity-containing articles with which the invention may advantageously be practiced, may be formed of any suitable materials, such as for example metals, glass, plastics, ceramics, etc., and including combinations, alloys, aggregates, and composites thereof. The features and advantages of the invention are more fully shown by the following non-limiting examples, wherein all parts and precentages are by weight, unless otherwise expressly stated. EXAMPLE I A base impregnant composition was made up having the formulation set out in Table I. TABLE I Component Concentration, Wt . % Triethylene glycol dimethacryl ate 71.4 Lauryl methacrylate 15.0 Hydroxypropyl methacrylate 10.0 Surfactant 2.5 Fluorescent dye 0.51 Quinone* 0.04 Benzosulfimi de 0.30 T-butyl hydroperoxide 0.25 Total 100.0 *includes quinone content of quinone chelator in triethylene glycol dimethacrylate component. Using the above-described impregnant composition, five aqueous solution samples thereof were made up. Samples 1, 2 and 5 comprised two percent solutions of the impregnant composition, based on the total weight of solution. Samples 3 and 4 were five percent aqueous solutions of the impregnant composition, on the same total solution weight basis. As the photoinitiator, each of the above-described samples contained one weight percent, based on weight of the acrylate monomer, of a substituted acetophenone UV initiator (Irgacure ® 184, Ciba Geigy, Ardsley, New York) . 400 milliliters of each sample aqueous solution was placed in a container. Samples 1-3 were placed in a plated aluminum dish, in which the liquid depth was 1/8 inch. Samples 4 and 5 were placed in a Pyrex ® glass bowl 8 inches in diameter and 3 inches in depth, wherein the liquid depth was 3/8 inch. Samples 4 and 5 were maintained in a stirred condition by placing the Pyrex ® glass bowl on a magnetic stirrer plate with a stir bar in the solution, to induce turbulence therein. A UV light source L/C chamber with a 12 inch lamp set at 300 watts per inch was employed as an actinic radiation exposure source for each of the above-described acrylate monomer-contai ni ng aqueous solutions. The temperature of each sample was measured before UV irradiation, together with the distance between the aqueous solution surface and the shutter of the UV light source. After UV exposure, the aqueous solution was filtered through a conventional coffee filter to determine whether any of the emulsified monomer had been polymerized, as evidenced by particulate polymer solids collected on the filter. Data for the various samples tested are set forth in Table II below. TABLE II Solution Distance Wt.% Impregnant Temperature of solution UV Intensity, UV Exp in Aqueous Before UV from UV Lamp microwatts time Sample Solution Exposure, °F shutter, in. per cm£ secon 1 77 8 125,000 30 74 125,000 60 72 125,000 60 In samples 1-3, UV exposure resulted in plating of the aluminum dish surfaces with the polymer product of the polymerization of acrylate monomer. Sample 4 after UV exposure evidenced good separation of polymer from the aqueous liquid. Sample 5 after UV exposure was cloudy due to the polymer formed therein. EXAMPLE II An acrylate monomer-contain ng solution of waste water, containing 2 percent Resiπol ® RTC acryl ate-based anaerobic curing formulation (Loctite Corporation, Newington, Connecticut), representative of the waste water from a commercial m croporosi ty impregnation system, was employed. The monomer-containing waste water was treated with 0.5 percent diethoxy acetophenone (DEAP), to yield a waste water comprising approximately 98 percent by weight water and 2 percent by weight of the acrylate sealant composition, including therein 0.5 percent by weight DEAP, based on the weight of the acrylate sealant composition. Corresponding waste water formulations were evaluated at varying DEAP concentrations, with the various formulations being exposed to UV radiation for 5, 10, and 15 seconds in the various test runs, and with the UV intensity being varied from 25,000- 100,000 microwatts per square centimeter in the various runs. From these comparative test runs, the DEAP photoinitiator concentration of 0.5 percent by weight, based on the weight of impregnant, was determined to provide the best results. In a second set of tests, the 0.5 percent DEAP-containi ng waste water was subjected to UV exposure using various UV light sources, including a Type H bulb, a Type D bulb (Fusion Systems Corporation, Rockville, Maryland), and a "standard" bulb (Technacure Systems) having an output of 300 watts per inch. In the test runs, UV exposure times of 15, 30, and 60 seconds were variously employed. The depth of liquid exposed to UV radiation was 3 inches, and the spacing of the UV bulb from the waste water surface was varied between 4 inches and 8 inches in the various tests. Best results were achieved using an H bulb positioned 4 inches from the waste water surface, at an exposure time of 5 15-30 seconds. The D bulb was utilized most effectively at a bulb-to-1 iquid spacing of 4 inches, at an exposure time of 30 seconds. The standard bulb, when used at a bulb-to-liquid spacing of 4-8 inches, generally required 60 seconds exposure to effect polymerization. 10 Although the optimum UV exposure time varied depending on the specific UV radiation source employed, in all instances effective conversion of acrylate monomer to polymer was achieved. In all tests, the waste water solution after UV exposure was filtered by gravity through Whattman 41 filter IE paper, with best results being indicated by a "clean" filtrate solution. However, even in instances where the filtrate effluent was cloudy, substantially complete conversion of monomer to polymer was determined to have been achieved. EXAMPLE III Z0 The use of polyelectrolyte materials for agglomerating polymer in sealant-containing waste water after actinic radiation exposure thereof was evaluated, utilizing 1 percent by weight aqueous solutions of the following polyelectrolyte materi al s : Z5 Magnifloc ® 573C (Sample I) Magnifloc ® 1596C (Sample II) Magnifloc ® 1906N (Sample III) Magnifloc ® 1820A (Sample IV) The waste water subjected to treatment with the 30 aforementioned polyelectrolyte solutions, contained Resi nol ® -X-RTC acryl ate-based sealant composition (Loctite Corporation, Newington, Connecticut), which after UV exposure treatment contained about 2 percent polymer by weight, based on the weight of waste water. After a control sample of the polymer-conta ning waste water had been established, four beakers, each containing 500 5 milliliters of the polymer-containing waste water, were respectively injected with the polyelectrolyte solution samples. Additional mixing was then carried out using a magnetic stir bar to assure complete blending of the polyelectrolyte. Afterward, the treated solutions were passed 10 through American .Scientifi c Number 517 fluted filter paper (coarse) and- observations were made, as set out in Table III below. TABLE III Sample Tumidity Before Turbidity After Ranking Fi 1tration IE Removed Some Polymer 2 Water White 1 Cloudy - No Change 3 Cloudy - No Change 4 As shown by the tabulated observations and appertaining 20 ranking, the Sample II polyelectrolyte performed the best of all polyelectrolytes tested, producing a water white filtration eff1 uen . In general, polyelectrolyte materials, depending on their specific type, may be used at widely varying concentrations, as desirable or necessary to achieve a selected extent of coalescence of monomer and/or polymer in the waste water being 5 treated. For example, the polyelectrolyte concentrat on may usefully range from about 0.01 to about 5% by weight, based on the weight of the waste water being treated. A preferred agglomeraπt dosage concentration may be on the order of from 0.05 to about 1% by weight, based on the total weight of waste water undergoing treatment, depending on the type, amount, etc. of the monomer and/or polymer in the waste water, which it is desired to agglomerate for recovery of polymer from the waste water. EXAMPLE IV The actinic radiation exposure treatment of monomer-containing waste water and r eco v ery of resultingly formed polymer from the irradiated waste water was evaluated in a process system generally simi lar to that schematically shown in the single Figure hereof, except that a wet vacuum impregnation step was used in place of the dry vacuum impregnation described in connection with the Figure. The actinic radiation exposure of the monomer-containing waste water was carried out using a Type 0 Fusion Systems UV Curing bulb (Fusion Systems Corporation, Rockville, Maryland), to irradiate a thin film of the waste water having a volumetric flow rate on the order of about 4.75 gallons per minute and an acrylate monomer content on the order of 2-3 percent by weight, based on the weight of the monomer- containing waste water. The actinic radiation exposure chamber was 10 inches wide and 12 inches long. The aforemen¬ tioned UV bulb was rated at 300 watts/inch output, with the wavelength of the radiation produced thereby being on the order of 200-450 nanometers. The filtration operation was carried out with a Serfilco bed filter (Serfilco, Ltd., Glenview, Illinois), provided with a 1 micron (paper) filter medium. Continuous operation of the above-described system, with thicknesses of the waste water film flowed through the actinic radiation exposure chamber on the order of 3 inches in a first test and 0.50 inch in a second test, yielded substantially complete conversion of monomer to polymer, with a high level of removal of polymer from the irradiated waste water on the filter paper in the filtration step. Best Mode for Carrying Out The Invention In a preferred aspect, the present invention relates to a curable resin composition for impregnating porous articles and to a system for treating waste water from an impregnation process utilizing such resin composition. The preferred resin composition comprises an acrylate monomer, an initiator for heat-cure and/or anaerobic cure of said acrylic monomer and a non-peroxy, actinic radiation photoinitiator. The actinic radiation photoinitiator is preferably present in an amount not exceeding about 5% by weight of the monomer. The preferred method of treating waste water produced by aqueous washing to such an impregnation porous article comprises exposing at least a portion of the waste water to actinic radiation polymeri zi ngly effective for the acrylic monomer in the presence of the photoinitiator to form a polymer, and then removing the polymer. The preferred apparatus for impregnating the porous article and removing the monomer comprises an impregnation chamber, a means of drawing a vaccum on the impregnation chamber to evacuate porosity of the porous articles therein, a means for contacting the porous articles with the preferred impregnating composition at a pressure higher than vaccum, an aqueous rinse chamber having a means of introduction of the rinse medium, an actinic radiation exposure chamber, a means to generate said radiation and transmit it to the actinic radiation chamber, a means to transfer effluent from the rinse chamber to the actinic radiation chamber, and a filtration system for filtering the rad ation-treated effluent and means for discharging the solids and solid-depleted liquid from the filtration system. Industrial Applicability The porous items that may be impregnated by the resin composition of the invention include castings, die castings, electronic components, powder metal parts, plastic composites, as well as any other porosity-containing articles that are advantageously porosity-sealed, such as items of metal, glass, plastics and ceramics. This impregnation helps in overcoming the deficiencies attendant the presence of mi croporosi ty in formed articles so that the impregnated article may be suitably employed in fluid exposure applications, as well as facilitating plating, coating and further processing of the formed article. While the invention has been described with reference to specific detailed embodiments and features, it will be recognized that numerous variations, modifications, and embodiments are possible, and accordingly, all such variations, modifications, and embodiments are to be regarded as being within the spirit and scope of the invention.

Claims: * THE CLA IMS What is Claimed is: 1. In a curable impregnant composition having utility for impregantion of mi croporosity and including acrylate E monomer, and initiator which is effective for initiating curing of said acrylate monomer upon exclusion of oxygen and/or heating of said monomer, the improvement comprising non-peroxy, actinic radiation photoinitiator being present in said composition. 10 2. A curable composition according to Claim 1, wherein said photoinitiator is present in an amount not exceeding about 5 percent by weight, based on the weight of the monomer. 3. A curable composition according to Claim 1, wherein said acrylate monomer comprises a mixture of mono-acryl ate and IS di-acrylate monomers. 4. A curable composition according to Claim 1, wherein said peroxy initiator is selected from the group consisting of hydroperoxides and peroxy esters. 5. A curable composition according to Claim 1, wherein Z0 said photoinitiator is selected from the group consisting of benzoin ethers, alpha dicarbonyl derivatives, chloroaceto- phenones, alpha hydroxyketones, acyl phosphi ne oxides, aromatic ketones, ionium salts, tertiary amines, and mixtures thereof. 25 6. A curable composition according to Claim 1, wherein said photoinitiator is a UV photoinitiator selected from the group consisting of benzophenone, di ethoxyacetophenone, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, diethoxyxanthone, chl orothi oxanthone, 30 azo-bi s-i sobutyroni tri 1 e, N-methyl dietha.no! ami ne benzophenone, and mixtures thereof. 7. A curable composition according to Claim 1, wherein said photoinitiator has a concentration of from about 0.05 to about 5 by weight, based on weight of the acrylate monomer. 8. A curable composition according to Claim 1, wherein said photoinitiator has a concentration of from about 0.1 to about 2 by weight, ' based on weight of the acrylate monomer. 9. A curable composition according to Claim 1, wherein said photoinitiator has a concentration of from about 0.5 to about 1 percent by weight, based on weight of the acrylate monomer. 10. A non-aqueous curable composition according to Claim -1. 11. A method of treating monomer-containing waste water produced by aqueous washing of an impregnated porous article to remove excess impregnant therefrom, wherein the impregnant is a curable composition comprising acrylate monomer, initiator for initiating curing of said acrylate monomer upon exclusion of oxygen and/or heating of said monomer, and actinic radiation photoinitiator, comprising the steps of: (i) exposing at least a portion of said monomer- containing waste water to actinic radiation polyme i zi ngly effective for said monomer in the presence of said photoinitiator, thereby forming a polymer-containing waste water; and (ii ) recovering said polymer from the polymer-containing waste water to yield a polymer-depleted waste water. 12. A method according to Claim 10, wherein an aggl omerati ngl y effective material is added to the waste water prior to said recovery step, to coalesce said monomer and/or said polymer, and enhance the efficacy of said recovery step. 13. A method according to Claim 11, wherein said agglomerati ngly effective material is a polyelectrolyte. 14. A method according to Claim 12, wherein said polyelectrolyte comprises a cationic polyacryl ami de . 15. A process for impregnating porosity of a porous article and treating waste water produced by aqueous rinse removal of excess impregnant therefrom, comprising: (a) impregnating porosity of the porous article with an impregnant comprising acrylate monomer, initiator for initiating curing of said acrylate monomer upon exclusion of oxygen and/or heating of said monomer, and actinic radiation photoinitiator; (b) removing excess impregnant from said porous article by aqueous rinsing thereof to produce an effluent rinse water ' contai ni ng removed excess impregnant; (c) curing the impregnant impregnated in the porosity by the porous article; (d) exposing the effluent rinse water containing removed excess impregnant to actinic radiation which is curingly effective for polymerization of acrylate monomer therein, to yield an effluent rinse water containing corresponding polymer; and (e) recovering the corresponding polymer from the effluent rinse water. 16. A process according to Claim 15, wherein said actinic radiation is UV radiation. 17. A process according to Claim 15, wherein said recovery comprises filtration of the -effluent rinse water. 18. A process according to Claim 15, further comprising adding an aggl omerat i ng ly effective material to the effluent rinse water prior to said re c o ve ry step. 19. A process according to Claim 15, wherein said impregnant is anaerobi cal ly curable, comprising the further step of contacting the impregnated porous article with an activator curingly effective for said impregnant. 20. A process according to Claim 19, comprising contacting said porous part after being contacted with said activator, with a rinse solution for removal of activator therefrom. 21. A process according to Claim 20, wherein said rinse solution is at elevated temperature to accelerate curing of said impregnant . 22. A process according to Claim 20, wherein said rinse solution contains a rust inhibitor, for forming a rust inhibiting coating on said impregnated porous article. 23. A process according to Claim 15, wherein said impregnant is heat- curabl e. 24. A process according to Claim 23, comprising the further step of contacting the impregnated porous article with an aqueous solution at an elevated temperature curingly effective for said impregnant. 25. A process according to Claim 15, wherein said exposure of effluent rinse water containing removed excess impregnant to actinic radiation comprises radiation exposure of a thin film of the effluent rinse water to said radiation. 26. A process according to Claim 18, wherein said agglomeratingly effective material comprises a polyelectrolyte. 27. A process according to Claim 26, wherein said polyelectrolyte comprises a cationic po lyacrylami de. 28. A method according to Claim 11, wherein steps (i), and (ii) are continuous in character. 29. A continuous process according to Claim 15. 30. A method according to Claim 11, wherein a thin film of said monomer-containing waste water is exposed to said actinic radiation. AMENDED CLAIMS [received by the International Bureau on 9 June 1989 (09.06.89); original claims 1,4 and 5 amended; new claims 31-36 added; other claims unchanged (5 pages)] 1. In a curable impregnant composition having utility for impregnation of microporosity and including acrylate monomer, and initiator which is effective for initiating curing of said acrylate monomer upon exclusion of oxygen and/or upon heating of said monomer, the improvement comprising: said initiator for initiating curing of said acrylate monomer being selected from the group consisting of inorganic peroxides and organic hydroperoxides; and non-peroxy, actinic radiation photoinitator being present in said composition in an amount effective under actinic radiation in initiate and induce curing of the acrylate monomer by polymerization thereof, with said amount being • below an ambient light polymerization concentration such that the photoinitiator does not initiate substantial polymerization of the impregnant composition when impregnated in microporosity, under ambient light exposure conditions selected from the group consisting of incandescent, fluorescent, mercury vapor illumination, and sunlight exposure. 2. a curable composition according to Claim 1, wherein said photoinitiator is present in an amount not exceeding about 5 percent by weight, based on the weight of the monomer. 3. A curable composition according to Claim 1, wherein said acrylate monomer comprises a mixture of mono- acrylate and di-acrylate monomers. 4. A curable composition according to Claim 1, wherein said initiator is an organic hydroperoxide initiator. 5. A curable composition according to claim l, wherein said photoinitiator is selected from the group consisting of benzoin ethers, alpha dicarbonyl derivatives, chloroacetophenones, alpha hydroxyketones, acylphosphine oxides, aromatic ketones, ionium salts, photoinitiatingly effective tertiary amines, and mixtures thereof. 6. A curable composition according to Claim 1, wherein said photoinitiator is a UV photoinitiator selected from the group consisting of benzophenone, diethoxyacetophenone, bezoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, diethoxyxanthone, chlorothioxanthone, azo-bis-isobutyronitrile, N-methyl diethanolamine benzophenones, and mixtures thereof. 27. A process according to Claim 26, wherein said polyelectrolyte comprises a cationic polyacrylamide. 28. A method according to Claim 11, wherein steps (i), and (ii) are continuous in character. 29. A continous process according to Claim 15. 30. A method according to Claim 11, wherein a thin film of said monomer-containing waste water is exposed to said actinic radiation. 31. A curable composition according to Claim 4, wherein said organic hydroperoxide is selected from the group consisting of cumene hydroperoxide and t-butyl hydroperoxide. 32. A curable composition according to Claim 1, wherein said initiator is an inorganic peroxide. 33. A curable composition according to Claim 1, wherein said photoinitiator is selected from the group consisting of benzoin ethers, diethoxyxanthone , chlorothioxanthone, azo-bis-isobutyronitrile, N-methyl diethanolemine benzophenones, and mixtures thereof. 34. A curable impregnant composition having utility for impregnation of microporosity, comprising: acrylate monomer; azo initiator effective for initiating curing of said acrylate monomer upon heating thereof; and non-peroxy, actinic radiation photoinitiator in an amount effective under actinic radiation conditions to initiate and induce curing of the acrylate monomer by polymerization thereof, with said amount being below an ambient light polymerization concentration such that the photoinitiator does not initiate substantial polymerization of the impregnant composition when impregnated in microporosity, under ambient light exposure conditions selected from the group consisting of incandescent, fluorescent, mercury vapor illumination, and sunlight exposure conditions. 35. A curable impregnant composition having utility or impregnation of microposity, comprising: acrylate monomer; initiator effective for initiating curing of said acrylate monomer upon exclusion of oxygen and/or upon heating of said monomer; non-peroxy, actinic radiation photoinitiator; and a fluorescent indicator. 36. An aqueous impregnant composition dispersion, comprising: acrylate monomer; initiator effective for initiating curing of said acrylate monomer upon exclusion of oxygen and/or upon heating of said monomer; non-peroxy, actinic radiation photoinitiator; and water in sufficient amount relative to said acrylate monomer, initiator, and photoinitiator to form an aqueous dispersion thereof. STATEMENTUNDERARTICLE 19 Claim 1 has been amended to recite that the initiator is selected from the group consisting of inorganic peroxides and organic hydroperoxides, and that the photoinitiator is present in amount effective under actinic radiation to initiate and induce curing of the acrylate monomer by polymerization thereof, with said amount being below an ambient light polymerization concentration, as is disclosed in the description at page 18, lines 16-20; page 32, line 27 to page 33, line 7; and page 33, line 13. Claim 4 has been amended to state that the initiator is an organic hydroperoxide initiator, consistent with claim 1. Claim 5 has been amended to state that the group includes photoinitiatingly effective tertiary amines making express what was inherent in claim 5 as filed. Claims 31 through 33 have been added, are dependent from claim 1, and are consistent with disclosure of the description as filed (page 19, lines 6-8; page 19, line 8; and page 33, lines 16-19, respectively). Claim 34 has been added and recites a curable impregnant composition, comprising: acrylate monomer; azo initiator for initiating curing of the acrylate monomer upon heating of the monomer; and non-peroxy, actinic radiation photoinitiator, recited in terms generally consistent with the disclosure (claim 1 as amended; page 9, lines 10-13, and page 32, line 27 to page 32, line 7). Claim 35 has been added and recites a curable impregnant composition, comprising: acrylate monomer; initiator effective for initiating curing of the acrylate monomer upon exclusion of oxygen and/or upon heating of monomer; non-peroxy actinic radiation photoinitiator; and fluorescent indicator (disclosed at page 26, lines 27 to page 27, line 4) . Claim 36 has been added to claim the aqueous dispersion resulting from washing away excess impregnant composition that comprises: acrylate monomer; initiator effective for initiating curing of said acrylate monomer upon exclusion of oxygen and/or heating of said monomer; and non-peroxy, actinic radiation photoinitiator (disclosed at page 30, lines 9-19).

Inventors: MUISENER CHARLES M, WELCH EDWARD K II, MUISENER, CHARLES, M., WELCH, EDWARD, K., II
Applicants: LOCTITE CORP, LOCTITE CORPORATION
Application year: 1989
Main classification: C08F2
IPC codes: B01D61, C02F1, C02F9, C08F2, C08F20, C08F220, C08F290, C08F299, C09D4