COSMETIC CONTAINING FINE SOFT MICROCAPSULES

Abstract: A cosmetic composition on an external treatment agent containing microcapsules, with an average particle size of 0.1 to 2000 µm, enclosing a hydrophobic com­ ponent, wherein the microcapsules are composed of a gelatin film swollen with water.

Description: The present invention relates to cosmetic compositions which contain fine soft microcapsules and which can be used as external treatment agents. microcapsules. More specifically, it relates to cosmetic containing gelatin capsules enclosing a liquid and/or solid hydrophobic component or a water-in-oil type emulsion therein, in which the capsules are not broken during the preparation of external treatment agents such as cosmetics, drugs, quasi drugs, but can be broken easily without escape on the palms of the hands upon usage (i.e., the term "escape" refers to the stage wherein the capsules are rubbed through the fingers or palms without rupture when the fingers and palms of the hands are rubbed together, to uniformly mix the aqueous phase which is the base and the capsules with the fingers or palms), whereby the contents are leaked out to be mixed with the outer phase, and there is no feeling of foreign matter caused by portions of the capsule films remaining after breaking, which external treatment agents also have a good useability, and excellent luster imparting effect and skin wettability, or in which the unstable water-soluble substance and lipid-soluble substance enclosed within the capsules exhibit an excellent stability without deterioration for a long term, and have an excellent luster imparting effect and wettability of the skin, with a good useability. Generally speaking, so-called external treatment agents include cosmetics, drugs, and quasi drugs. Among the above, cosmetics are classified into basic make-up cosmetics and hair cosmetics, depending on the location at which they act or their purpose. The basic cosmetics include cosmetic water, emulsion, and cream, which are used for applying oily components having a good quality or a hydrophilic substance having a high humectant property with a good balance to the skin when the balance of the skin humectant mechanism in a human body is disturbed by various external conditions (wind, temperature, humidity, etc.) or inherent conditions (age, etc.). For example, a cosmetic water is a hydrophilic cosmetic having a transparent appearance, comprising a humectant component, an alcohol, and water, etc., and the emulsion and cream are cosmetics comprising an oily component and an aqueous component mixed in a suitable ratio. As make-up cosmetics, foundation, eyeshadow and lipsticks may be included. These are used for varying the skin color by the application of a color, affording a three-dimensional feeling to the skin, to emphasize the color of a part of or conceal a defect of the skin, thereby creating an attractive appearance while simultaneously conditioning the skin. The hair cosmetics include hair tonics, hair oils and hair creams, which are used as hair conditioners and as a nutrient for the hair. More specifically, the common function or purpose of these cosmetics is to maintain a healthy and normal stage (homeostasis) by applying a suitable oily component and humectant component or water, in accordance with the nature of the skin or hair, to thereby assist the natural humectant mechanism of skin or hair and alleviate deterioration of the skin or hair caused by changes in external environmental conditions, including natural conditions such as temperature and humidity and artificial conditions such as defatting by washing. For an improvement of these functions, various skin effective components such as vitamins and unsaturated fatty acids have been added in the prior art emulsion type cosmetics. As effective components, although water-soluble substances such as vitamin C, etc. and lipid-soluble substances such as vitamin A, linolenic acid, etc., are known, most of the water-soluble effective components are hydrolyzed when placed in contact with water, and thus the physiological activities thereof are lost. On the other hand, most of the lipid-soluble effective components are very susceptible to autooxidation and, after forming activated radicals through a loss of hydrogen atoms by light or heat, form peroxy radicals by an absorption of oxygen, and are decomposed or polymerized via hydroperoxide (peroxide) to thereby forming carbonyl compounds, lower aldehydes, lower fatty acids, ketones and other polymers, and thus the activities thereof are lost. Accordingly, when formulating these effective components in cosmetics or other external agents, oxidation must be prevented. As one means of preventing oxidation, a method in which the preparation of an external agent is preformed in an inert gas atmosphere such as nitrogen, and further, during filling of the product in a vessel, the air in the space in contact with the external agent is replaced with nitrogen or carbon dioxide, can be used. But this replacement with nitrogen has little effect unless not only the oxygen in the space portion but also the dissolved oxygen in the external agent are replaced with nitrogen, and the replacement with carbon dioxide may cause an undesirable rise in the acid value of the effective components, or an objectionable odor, with a lapse of time. Such preparation and storage can be performed at as low a temperature as possible, but this is practically almost impossible if the quality is to be guaranteed. Accordingly, a stabilization of external agents, for a long term has been effected by an addition of antioxidants, but since the properties and the effective concentration of antioxidants differ in accordance with the kind of effective skin component used, a drawback has arisen in that a thorough examination and much experimentation are required before practical use, which makes the method difficult to handle. Also, the method of enclosing water-soluble and lipid-soluble effective components within microcapsules, to separate them from water and oxygen, has been investigated. But, in the known methods, a simultaneous microcapsulation of water-soluble and lipid-soluble components has been considered impossible, and the method in which the respective components are prepared separately by microcapsulation methods entirely different from each other and thereafter mixed has been used, and therefore, the preparation must be performed at least twice, which greatly increases labor costs. Further, when microcapsules enclosing a water-soluble effective component therein are formulated in a base of a cosmetic water or cream, in which water is the medium, a problem has arisen in that the water readily passes through the inside and outside of a capsule film, whereby the contents leak into the outer phase base within a short time. In the prior art, microcapsules comprising a gelatin wall film swollen with water and enclosing liquid oil components have been formulated as an external agent, but these required an extremely strong breaking force because of the flexible wall films and contents therein when they are to be broken by compression by rubbing the palms of the hand together upon usage. Namely, when palms of the hands were rubbed together, the microcapsules were only slid over the skin surface or embedded in the skin pores, whereby sometimes breaking did not occur, and thus the efficacy of the oil components enclosed was not exhibited. For example, as mentioned above, a cosmetic water is prepared by solubilizing an oil component (i.e., emollient agent), a flavor, and a medicament, to obtain a transparent appearance, and an O/W type emulsion or cream is prepared as an emulsion containing a large amount of an emulsified oil component, thereby enhancing the humectant effect and the emollient effect on the skin. Namely, to enhance the emollient effect on the skin, a large amount of an oil component is formulated by solubilization or emulsification with a large amount of an emulsifier, but the emulsifiers generally used more or less irritate the skin, in spite of the surfactant ability thereof. Accordingly, from the viewpoint of safety, the amount of surfactant formulated therein is limited, and thus the amount of the oil component to be solubilized and emulsified must be limited. Namely, a problem has arisen in that the desired humectant effect or the emollient effect cannot be imparted to the skin. As a means for solving these problems, the formulation of microcapsules enclosing an oil component in a cosmetic has been considered. For example, Japanese Unexamined Patent Publication (KOKAI) No. 61-112897 discloses a surfactant solution containing capsules having an improved dispersibility provided by an adjustment of the specific gravity. Also, Japanese Unexamined Patent Publication (KOKAI) No. 59-73510 disclosed that, by formulating capsules comprising a polymerizable polymeric film enclosing a skin emollient component, a flavor, and a drug component in a cosmetic, the feeling during use of a make-up cosmetic can be improved. But, according to trace experiments by the present inventors, "escape" of the capsules disclosed by the former specification occurred during usage, and thus the capsules cannot be easily disintegrated by compression, whereby a leakage of the enclosed contents could not be realized. On the other hand, the capsules used in the latter specification, when formulated in a cosmetic water or cream, can be disintegrated by compression only with difficulty, due to extremely fine capsule particle sizes of 1 to 100 µm, and further, even if integrated the film substance of the capsules remained, thus having the drawback of a feeling of foreign matter on the skin. Furthermore, it is known to control the strength of the wall film by controlling the thickness of the wall film of a microcapsule or formulating a fine powder of mica and titanium into the wall film. But, in the former method of controlling the film thickness, the film must be made extremely thin so that the capsules are easily broken, and therefore, the capsules may sometimes break during the preparation of the product. Further, when microcapsules are to be prepared by the coacervation method, in which a gelatin film is formed after dispersing the oil component into water, the particle sizes of the capsules are nonuniform, and the breaking strength differs in accordance with the particle size even if the film thickness is the same, and therefore, the breaking strength must be based on both the film thickness and the particle size, and thus the preparation becomes extremely complicated. On the other hand, in the latter method of using a fine powder, the transparency of the gelatin film is impaired, depending on the kind of fine powder used, and therefore, the film cannot be applied to a product in which the color of the content is emphasized. Further, when the above coacervation method is utilized, since a fine powder is added into the outer phase, the amount precipitated together with the coacervate on the oil droplet surface is extremely small, and most of it is discarded together with the outer aqueous phase in the washing step, which is cost-disadvantageous, and even if the fine powder is contained in the wall film, the differences in breaking strength due to the size of capsule still remain as a disadvantage thereof. Many methods for microencapsulating hydrophobic substances are known, and of these methods, the coacervation method utilizing the phase separation phenomenon of hydrophilic polymer can be practiced relatively easily if a device for emulsifying and dispersing hydrophobic substances into water is used, and finished microcapsules having dense wall films with a high coverage ratio can be produced, and thus this is an industrially useful production method. In the prior art, when microcapsules are to be produced by the coacervation method, hydrophobic substances are dispersed or emulsified in an aqueous solution of a hydrophilic polymer to desired particle sizes, and then a hydrophilic polymer having opposite charges in the case of the complex coacervation method, or an electrolyte or a poor solvent are added in the case of the simple coacervation method, to effect microencapsulation. Such prior art methods are useful for the microencapsulation of one kind of hydrophobic substance, but are not suitable for the microencapsulation of two or more kinds of hydrophobic substances with different properties. When microcapsules are produced by coacervation after dispersion or emulsification by successively adding hydrophobic substances into an aqueous hydrophilic polymer solution, an agglomeration or mutual coalescence of the hydrophobic substances will occur during dispersion or emulsification, and thus microcapsules of mixed hydrophobic substances are formed and microcapsules enclosing separate hydrophobic substances can not be obtained. Accordingly, when several kinds of microcapsules enclosing different hydrophobic substances are to be formulated in a product, the number of steps must correspond to the number of kinds of microcapsules, and must be repeated to produce microcapsules enclosing different hydrophobic components, and thereafter, the respective microcapsules must be uniformly mixed into the product. Generally speaking, when producing microcapsules by coacervation, hydrophobic substances are enclosed with a water-soluble polymer, and thereafter the water-soluble polymer is hardened and made insoluble in water. Since a substance of higher reactivity such as aldehydes is used as the hardening agent, a washing operation must be carried out to completely remove excess hardening agent, e.g., by thoroughly washing the microcapsules after production with purified water. To accomplish this washing, a method in which the steps of removing the aqueous phase portion after complete separation of the microcapsules by standing and again adding the same amount of purified water are repeated, and a method in which the steps of adding the same amount of purified water after separation of the microcapsules from the aqueous phase with a filter are repeated, are known, but both require much time and labor. Therefore, in the above method in which the same number of steps as the kinds of capsules are repeated, too much time and labor are required for preparing one product, which is extremely cost-disadvantageous. Also, in the coacervation method, microcapsules with extremely different size or of wall films states may be formed if slight changes in conditions occur, and therefore, when formulating many kinds of microcapsules enclosing different hydrophobic substances in a product, conventionally the sizing was made with a sieve, or the uniformity was disregarded, but the cost was disadvantageously high and a product having a satisfactory appearance could not be obtained. The known prior art includes US-A-2,800,457, which discloses gelatin capsules coating "oils" (olive oil, coconut oil, castor oil, fish oil, etc.) of 1-70 µm diameter. The coating is made by coacervation of gelatin and gum arabic, and/or sodium carbonate, potassium hydroxide and the ratio of oil to gelatin of 80:20. Chemical Abstracts Vol. 88, 1978, Page 275, No. 55023g discloses the microencapsulation of vitamin E in gelatin with a capsule diameter of 100 - 400 µm. SUMMARY OF INVENTION Accordingly, the objects of the present invention are to eliminate the above-mentioned disadvantages of the prior art and to provide an external treatment agent comprising microcapsules having a strength such that they are not broken by mixing during the preparation of cosmetics, drugs, quasi drugs but can be broken by rubbing the palms of the hands together upon usage, formulated therein, whereby the contents leak out and are thoroughly mixed with the outer phase, and thus a feeling of foreign matter caused by portions of the capsule films remaining after breaking does not occur, the external agent having a good useability and an excellent luster imparting effect and skin wettability. Another object of the present invention is to provide an external treatment agent containing an active component with an excellent stability, which agent will not deteriorate over a long term. A further object of the present invention is to provide a process for producing microcapsules at a low cost, in which microcapsules enclosing separate hydrophobic substances can be obtained simultaneously and in one step without a mutual mixing of the hydrophobic substances during production. In accordance with the present invention, there is provided:- (1) a cosmetic composition comprising gelatin capsules enclosing a hydrophobic component therein, the capsules being in an aqueous phase containing a water-soluble polymer, the weight ratio of the hydrophobic component to gelatin being 1:10 to 100:1, the average particle size of the gelatin capsules being 100 to 1000 µm, and the viscosity of the system being 100 to 20,000 mPa s(cps); and (2) a cosmetic composition comprising as essential ingredient (a) capsules composed of a gelatin film swollen with water and having particle sizes of 0.1 to 1000 µm, the capsules enclosing a hydrophobic component therein and having a breaking strength of from 1 to 30 kPa (10 to 300 g/cm²) and (b) a polyhydric alcohol. According to aspects of embodiment (2) there are provided (a) A cosmetic composition comprising microcapsules composed of a gelatin film swollen with water and having particle sizes of 0.1 to 50 µm, and enclosing a hydrophobic component therein and a polyhydric alcohol, formulated as the essential components therein, the microcapsules after formulation having a breaking strength of 1 to 30 kPa (10 to 300 g/cm²). (b) A cosmetic composition comprising microcapsules made of a gelatin film swollen with water and having particle sizes of 50 to 100 µm, and enclosing either a liquid or a solid hydrophobic component therein and polyhydric alcohol formulated as the essential components therein, the microcapsules after formulation having a breaking strength of 1 to 30 kPa (10 to 300 g/cm²). (c) A cosmetic composition comprising microcapsules made of a gelatin film swollen with water and having particle sizes of 100 to 1000 µm, and enclosing either a liquid or a solid hydrophobic component therein and a polyhydric alcohol formulated as the essential components therein, the microcapsules after formation having a breaking strength of 1 to 30 kPa (10 to 300 g/cm²) (3) The microcapsules for the cosmetic composition are formable as follows: (a) by the complex coacervation of hydrophilic polymers, which comprises previously obtaining a mutual mix of aqueous solutions of polymers having positive and negative opposite charges to form a complex coacervate, and then adding successively different several kinds of hydrophobic component, thereby obtaining microcapsules containing separate hydrophobic components, at the same time and in one step, (b) by the simple coacervation of hydrophilic polymers, which comprises previously adding an electrolyte or a poor solvent for the polymer into an aqueous solution of a hydrophilic polymer to form a simple coacervate, and then successively adding several different kinds of hydrophobic component, thereby obtaining microcapsules containing separate hydrophobic components, at the same time and in one step. BRIEF DESCRIPTION OF THE DRAWINGS The present invention will be better understood from the description set forth below with reference to the accompanying drawings, wherein Figure 1 is a graph showing the stability with a lapse of time of the vitamin A palmitate of Example 3-1 and Comparative Example 3-1; Fig. 2 is a graph showing the stability with a lapse of time of the vitamin A palmitate of Example 7-1 and Comparative Example 7-1; Fig. 3 is a graph showing the stability with a lapse of time of the L-ascorbic acid of Example 7-1 and Comparative Example 7-1; Fig. 4 is a graph showing the leakage characteristics of a cream base with a lapse of time of the L-ascorbic acid of Example 7-2 and Comparative Example 7-2. DESCRIPTION OF THE PREFERRED EMBODIMENTS According to the present invention capsules can be readily disintegrated by compression without "escape" by rubbing with the fingers or palms of the hands when applying than to the skin, by using gelatin as the film substance for the capsule enclosing a hydrophobic component, and further, restricting the weight ratio of the hydrophobic component to gelatin within the capsules, the particle size of the capsules, and the viscosity of the outer phase including the water-soluble polymer, to within specific ranges, and thus an excellent capsule-containing cosmetic that does not produce a feeling of foreign matter due to remaining portions of the capsule can be produced. Also, according to the present invention, by using gelatin swollen with water as the film substance of the capsule, and limiting the breaking strength of the capsules to a certain specific range, no breaking occurs at all during preparation of the cosmetic and compression disintegration can be effected easily without "escape" of the capsules during the application onto skin and without the feeling of foreign matter caused by remaining portions of the film. Further, by formulating microcapsules having a substantially equal strength over a wide range of particle sizes, a cosmetic substantially not affected by the particle sizes of the capsules, which have a transparent wall film, can be produced. Furthermore, according to the present invention, by enclosing lipid-soluble skin effective components in microcapsules comprising a gelatin film swollen with water and having particle sizes of 100 µm or less, and formulating the microcapsules in a water-in-oil type emulsified external agent, an excellent stability can be exhibited for a long term, to prevent deterioration thereof, and excellent specific features are obtained in that the microcapsules are not broken even under a high shear pressure during preparation of an external agent, and that the lipid-soluble effective components enclosed do not migrate to the outer oil layer by passing through the film. Furthermore, according to the present invention, by dispersing microcapsules using a gelatin swollen with water as the film substance in a base containing a polyhydric alcohol, even with a particle size of less than 100 µm, the breaking strength of the capsules can be easily controlled by varying the kind or composition of the polyhydric alcohol, and that if the breaking strength is limited to a certain specific range, an external agent formulated with transparent microcapsules can be prepared, these microcapsules being such that no breaking occurs at all in mixing during preparation of the external agent and compression disintegration can be effected easily without an escape of capsules during application onto the skin, and without a feeling of foreign matter caused by remaining portions of the film. Furthermore, according to the present invention, by dispersing microcapsules using a gelatin swollen with water as the film substance enclosing fluid oil components in a base containing a polyhydric alcohol, even including no water-soluble polymer with a particle size of 100 to 1000 µm, the breaking strength of the capsules can be easily controlled by varying the kind or composition of the polyhydric alcohol, and that if the breaking strength is limited to a certain specific range, an external agent formulated with transparent microcapsules can be prepared, the microcapsules being such that no breaking occurs at all in mixing during preparation of the external agent and compression disintegration can be effected easily without escape of capsules during application onto the skin and without a feeling of foreign matter caused by remaining portions of the film. Furthermore, according to the present invention, by formulating microcapsules comprising a gelatin film swollen with water enclosing a water-in-oil type emulsion formed of an aqueous phase portion having a water-soluble skin effective component dissolved or dispersed therein and an oil phase portion having a lipid-soluble skin effective component dissolved or dispersed therein in an external agent, an excellent stability can be exhibited through an inhibition of a deterioration of the water-soluble and lipid-soluble components, and since both components can be microencapsulated simultaneously, a cumbersome operation is not required, which is cost-advantageous, and further, an entirely novel function, appearance, and useability not found in the prior art can be imparted without migration of the enclosed water-soluble effective component by passing through the film. Furthermore, according to the present invention, extremely cost-advantageous microcapsules can be produced by successively adding hydrophobic substances with different properties after a previous formation of a coacervate, when microencapsulating hydrophobic substances according to a complex coacervation and a simple coacervation, by using a hydrophilic polymer. Embodiment (1) As the water-soluble polymer to be formulated in the aqueous phase of the cosmetic composition of this embodiment of the present invention, natural polymers, semi-synthetic polymers or synthetic polymers may be included, specific examples of which include natural polymers such as carrageenan, alginic acid, tragacanth, pectin, starch, xanthan gum, gelatin, casein agar and gum arabic, semi-synthetic polymers such as derivatives of starch, cellulose and alginic acid, and synthetic polymers such as polyvinyl alcohol, polyvinyl pyrrolidone, carboxyvinyl polymer, polyethylene glycol and sodium polyacrylate, but these are not limited in this invention, and any water-soluble polymer generally used in a cosmetic may be employed. In the present invention, one or more kinds of the above water-soluble polymers is formulated in the aqueous phase, and the viscosity value of the aqueous phase thus obtained must be within the range of 1000 to 20000 mPa s (cps) in terms of the value measured by a Brookfield type rotary viscometer. If lower than 1000 mPa s (cps), "escape" of the capsules from the fingers or the palms during application onto the skin will occur, and if higher than 20000 mPa s (cps), the feeling during use will be markedly degraded. Here, the viscosity measuring instrument used by the present inventors is specifically a B type viscometer Model B8L produced by Tokyo Seiki Co., Ltd., and the measurement was carried out using a rotor #4 at 12 rpm. As the method for preparing capsules of the gelatin film to be formulated in the cosmetic composition of the present invention, known methods may be used, such as the simple coacervation or the complex coacervation and other methods, but generally the complex coacervation method is employed. Next, as the hydrophobic component to be enclosed in the above gelatin film capsule, there may be included animal and vegetable oils, hydrocarbon oils, ester oils, silicone oils, higher fatty acids, higher alcohols, waxes, vitamins, vitamin-like acting substances and various flavors. Specific examples of these may include animal and vegetable oils such as mink oil, turtle oil, safflower oil, grape seed oil, soybean oil, sesame oil corn oil, rapeseed oil, sunflower oil, cottonseed oil, avocado oil, olive oil sasanqua oil, tsubaki (camellia) oil, persic oil, castor oil, jojoba oil, peanut oil and orange oil; hydrocarbon oils such as fluid paraffin, squalane, microcrystalline wax and petrolatum; ester oils such as isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, isononyl isononanate, isotridecyl notate, 2-ethylhexyl palmitate, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyldodecanyl myristate, di-2-hexyldecyl azipate, di-2-ethylhexyl succinate, diisostearyl malate, 2-octyldodecanol lactate, glycerine triisostearate and diglycerine triisostearate; silicone oils such as methylpolysiloxane, methylphenylpolysiloxane, fatty acid modified polysiloxane, fatty acid alcohol modified polysiloxane and polyoxyalkylene modified polysiloxane; higher fatty acids such as myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid and isostearic acid; higher alcohols such as cetanol, stearyl alcohol, oleyl alcohol and lanolin alcohol; waxes such as beeswax, candelilla wax, whale wax and carnauba wax; vitamins such as vitamin A, B₂ , D and E; vitamin-like acting substances such as α-lipoic acid and ferulic acid; sunscreening agents such as ethyl paraaminobenzoate and oxybenzone; and various natural and synthetic flavors. These however, are not limited in the present invention, and any lipid-soluble starting material generally applied to a cosmetic may be employed. The particle size of the capsules to be applied in this embodiment of the present invention is 100 to 1000 µm. If the capsule particle size if smaller than 100 µm, a high wall film strength will occur and breaking of the capsules only by pressure of the fingers or palms of the hands when used as the cosmetic such as a cosmetic water or cream, can be done only with difficulty (sometimes the enclosed contents cannot be released), and if the particle size exceeds 1000 µm, "escape" of the capsule from the fingers or palms of the hands during application to the skin becomes marked. Further, the capsules enclosing various hydrophobic components therein can be formulated in the cosmetic preferably within the range of 0.1 to 95% by weight. The weight ratio of the hydrophobic components forming the capsules to gelatin is within the range of 1 : 10 to 100 : 1. If the weight ratio of the hydrophobic components to gelatin is greater than 1: 10, the wall film of the capsules becomes too thick, "escape" of the capsules becomes marked, the capsules cannot be easily broken, and further, even if broken, portions of the wall film remain to give a feeling of foreign matter to the skin. On the other hand, if the weight ratio is greater than 100 : 1, the strength of the capsule film is remarkably lowered, and thus the capsules may be broken during preparation of the product, and therefore are not suitable for practical application. The above gelatin capsule film of the present invention is amorphous per se and is transparent, and further, has a sufficient non-transmissivity relative to the contents enclosed therein. The present invention can obtain an effect not found in the prior art, by formulating the microcapsules obtained as described above in cosmetic compositions such as cosmetic water and emulsion creams, etc. Embodiment 2a As the polyhydric alcohol to be formulated in the cosmetic compositions in this embodiment of the present invention, any starting material generally used for cosmetics, drugs, quasi drugs, etc., may be employed, such as diethylene glycol monoethyl ether, polyethylene glycol, propylene glycol, polypropylene glycol, 1,3-butylene glycol, glycerine, polyglycerine, pentaerythritol, sorbitol, glucose, sucrose, xylitose, and mannitol. The amount of the polyhydric alcohol according to this embodiment of the present invention formulated in the external treatment agent is preferably within the range of 0.1 to 98% by weight. As the method for preparing microcapsules of gelatin film according to this embodiment of the present invention, known methods may be used, such as simple coacervation, complex coacervation and other methods, but generally the complex coacervation method is employed. As the hydrophobic substance to be enclosed within the microcapsules according to the present invention, there may be included the animal and vegetable oils, hydrocarbon oils, ester oils, silicone oils, higher fatty acids, higher alcohols, vitamins, vitamin-like acting substances, sunscreening agents and various flavors mentioned above. However, these are not limited in the present invention, and any lipid-soluble starting material which can be generally applied to cosmetics, drugs, quasi drugs, etc., may be employed. The particle size of the microcapsules according to this embodiment of the present invention is 0.1 to 50 µm. Capsules with particle size smaller than 0.1 µm are not preferable, because they are extremely difficult to produce. Further, the amount of the capsules according to this embodiment of the present invention is preferably within the range of 0.1 to 95% by weight. The weight ratio of the hydrophobic substance forming the capsules to gelatin film is preferably within the range of 1 : 0.01 to 1 : 10. If the weight ratio of the hydrophobic substance and gelatin is smaller than 1 : 0.01, the strength of the capsule coating is remarkably lowered, whereby capsules breaking may occur during preparation of the product. On the other hand, if the weight ratio is greater than 1 : 10, due to an increased thickness of the wall film in the capsules, the wall film may sometimes remain after breaking to give a feeling of foreign matter to the skin. By permitting the microcapsules to be co-present with the above polyhydric alcohol, the breaking strength of the microcapsules can be controlled to the range of 1 to 30 kPa (10 to 300 g/cm²) for formulation into the external agent. If the breaking strength of the capsules is lower than 1 kPa (10 g/cm²), capsule destruction may occur during preparation of the product, and if higher than 30 kPa (300 g/cm²), destruction of capsules can be effected only with difficulty when applied onto the skin, whereby the feeling during use will be remarkably degraded. The instrument for measuring breaking strength used by the present inventors is specifically a creepmeter Rheoner RE-3305 model (produced by Yamaden Co. Ltd.), and the measurement method was carried out by compressing the capsules laid in a dense mass of a glass flat plate with a Teflon 8 mm⊘ columnar rod mounted on the measuring instrument under a load of 1 g per 1 second, and the breaking strength was determined by calculating the amount of the load upon rupture, calculated per 1 cm². The outer phase of the cosmetic composition according to this embodiment of the invention may be a water-in-oil emulsion comprising the polyhydric alcohol. As the aqueous phase portion constituting the water-in-oil emulsion, other than pure water, there may be included one or more kinds selected from lower alcohols such as methanol, ethanol, isopropanol: polyhydric alcohols such as ethylene glycol, propylene glycol, dipropylene glycol, glycerine, 1,3-butylene glycol, sorbitol, glucose, either alone or in combination with water; inorganic acids such as sodium chloride, potassium carbonate, sodium metaphosphate, potassium dihydrogen phosphate, sodium sulfate; acids such as hydrochloric acid, phosphoric acid, acetic acid; and bases such as sodium hydroxide, potassium hydroxide, ammonia water, but these are not limited in the present invention but can be selected depending on the purpose of use. As the water-soluble skin effective component to be formulated in the aqueous phase portion, there may be included vitamins, hormones, and amino acids, and specific examples of these further include vitamins such as thiamine hydrochloride, pyridoxin hydrochloride, nicotinic acid amide, calcium pantothenate, biotin, inositol, ascorbic acid, sodium ascorbate, rutin; hormones such as estradiol, cortizone, prednizolone; and alanine, glycine, lysine, pyrrolidone carboxylic acid, but these are not limited in the present invention, and any water-soluble starting materials which can be employed generally for external agents such as cosmetics, drugs, quasi drugs, etc., may be used. The above gelatin capsule film according to this embodiment of the present invention is amorphous per se and is transparent, and further has a sufficient non-transmissivity relative to the materials enclosed therein. The cosmetic composition of this embodiment of the present invention is an external agent used for cosmetics, drugs, quasi drugs, etc., and has extremely excellent use characteristics in that a strong force is not needed when it is to be broken by compression during usage, and that there is no feeling of foreign matter due to remaining portions of the capsule film. Therefore, it is preferably used particularly for cosmetics having characteristics which are emphasized. For example, by formulating microcapsules with particle sizes of 0.1 to 50 µm having hydrophobic components enclosed therein in cosmetics such as cosmetic water, emulsions, creams, shampoos, rinses, etc., a cosmetic which can impart effects not found in the prior art can be obtained. Embodiment 2b As the polydydric alcohol to be formulated in the cosmetic compositions of this embodiment of the present invention, any starting material generally used for cosmetics, drugs, quasi drugs, etc., mentioned above may be employed. The amount of the polyhydric alcohol according to this embodiment of the present invention formulated in the external agent is preferably within the range of 0.1 to 98% by weight. As the method for preparing microcapsules of gelatin film according to this embodiment of the present invention, known methods may be used, such as simple coacervation, complex coacervation and other methods, generally the complex coacervation method is employed. Next, as the liquid hydrophobic component to be enclosed within the above gelatin film microcapsules, there may be included the animal and vegetable oils, hydrocarbon oil, ester oils, silicon oils, higher fatty acids, higher alcohols, vitamins, vitamin-like acting substances, various perfumes, as mentioned above, but these are not limited in the present invention, and any lipid-soluble starting material having a liquid appearance with a melting point lower than normal temperature (25°C) which can be generally applied to cosmetics, drugs or quasi drugs, may be employed. Also, as the solid hydrophobic component to be enclosed in the gelatin film microcapsules, there may be included the animal and vegetable oils, hydrocarbon oils, exter oils, higher fatty acids, higher alcohols, waxes, sunscreening agents, flavors, etc., as mentioned above, but these are not limited in the present invention, and any lipid soluble starting material having a solid or semi-solid appearance which can be applied to cosmetics, drugs, quasi drugs in general, and has a melting point higher than normal temperature, may be employed. Among the above, those having melting points not higher than normal temperature are classified as liquid hydrophobic components and those having melting points not lower than normal temperature are classified as solid hydrophobic components. Specific examples of the liquid oil component and solid oil component mentioned above may include liquid oils such as avocado oil, tsubaki (camellia) oil, turtle oil, macademia nut oil, corn oil, mink oil, olive oil, rapeseed oil, yolk oil, sesame oil, persic oil, wheat germ oil, sasanque oil, castor oil, linseed oil, safflower oil, cottonseed oil, perilla oil, soybean oil, peanut oil, teaseed oil, kaya oil, rice bran oil, China wood oil, Japan wood oil, jojoba oil, germ oil, triglycerine glycerine trioctanoate, glycerine triisopalmitate; solid fats such as cacao butter, coconut oil, horse fat, hardened coconut oil, palm oil, tallow sheep fat, hardened tallow, palmkernel oil, lard, cattle born fat, woodwax kernel oil, hardened oil, cattle leg fat, woodwax, hardened castor oil; waxes such as beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, insect wax, whale wax, montan wax, rice bran wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugarcane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol POE hydrogenated lanolin alcohol ether; hydrocarbons such as fluid paraffin, ozocerite, squalene, pristane, paraffin, ceresine, squalane, petrolatum, microcrystalline wax; synthetic esters such as isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 1,2-hydroxystearate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, N-alkylglycol monoisostearate, neopentylglycol dicaprylate, diisostearyl malate, glycerine di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexylate, trimethylolpropane triisostearate, pentane-erythritol tetra-2-ethylhexylate, glycerine tri-2-ethylhexylate, trimethylolpropane triisostearate, cetyl-2-ethylhexanoate, 2-ethylhexyl palmitate, glycerine trimyristate, tri-2-heptylundecanoic acid glycerin, castor oil fatty acid methyl ester, oleic acid oil, cetostearyl alcohol, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl azipate, N-lauroyl-L-glutamate-2-octyldodecyl ester, di-2-hepthylundecyl azipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl azipate, diisopropyl sebacate, 2-ethylhexyl succinate, ethyl acetate, butyl acetate, amyl acetate, triethyl citrate; higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic (behenyl) acid, oleic acid, 12-hydroxystearic acid, undecylenic acid, thoric acid, lanolin fatty acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenic acid; straight or branched higher alcohols such as lauryl alcohol, cetyl alcohol, steryl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, monostearyl glycerine ether (bathyl alcohol), 2-decyltetradecynol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, octyldodecanol; sunscreening agents such as ethyl paraaminobenzoate, oxybenzone, etc.; and natural and synthetic flavors. Among the above, those having a melting point not higher than normal temperature are classified as liquid oil components, and those having a melting point higher than normal temperature are classified as solid oil components. The proportion of the liquid oil component and the solid or semi-solid oil component to be enclosed in the gelatin film microcapsules may be such that the melting point of the mixture is slightly higher than normal temperature, namely 35 to 70°C, preferably 40 to 60°C. If the melting point is lower than 35°C, the mixture is melted to become liquid because such a temperature can be generally reached during the application and, therefore, the capsules become elastic so that the breaking of the capsules become difficult with palms. If the melting point exceeds 70°C, since it is necessary to liquefy the oil phase during preparation of the capsules, the temperature of the system must be made higher than the melting point, whereby heat denaturation of the gelatin, which is the material of the capsule films, occurs and a good wall film cannot be formed on the oil droplets, which is cost-disadvantageous. The particle size of the microcapsules according to this embodiment of the present invention is 50 to 100 µm. Further, the amount of the capsules according to this embodiment of the present invention formulated in the external agent is preferably within the range of 0.1 to 95% by weight. The weight ratio of the hydrophobic substance forming the capsules to gelatin film in this embodiment is preferably within the range of 1 : 0.01 to 1 : 10. If the weight ratio of the hydrophobic substance and gelatin is smaller than 1 : 0.01, the strength of the capsules coating is remarkably lowered, whereby capsule breaking may occur during preparation of the product. On the other hand, if the weight ratio is greater than 1 : 10, due to an increased thickness of the wall film in the capsules, the wall film may sometimes remain after breaking to give a feeling of foreign matter to the skin. By permitting the microcapsules to be co-present with the above polyhydric alcohol, the breaking strength of the microcapsules can be controlled to the range of 1 to 30 kPa (10 to 300 g/cm²) for formulation into the external agent. If the breaking strength of the capsules is lower than 1 kPa (10 g/cm²), capsule destruction may occur during preparation of the product, and if higher than 30 kPa (300 g/cm²), breaking of capsules can be effected only with difficulty when applied onto the skin, whereby the feeling during use will be remarkably degraded. The instrument and measurement for measuring breaking strength used by the present inventors is as specified in Embodiment 2a. The outer phase of the cosmetic composition according to this embodiment of the invention may be a water-in-oil emulsion. The aqueous phase portion and water-soluble component in it may be as in Embodiment 2a. The above gelatin capsule film according to this embodiment of the present invention is amorphous per se and is transparent, and further, has a sufficient non-transmissivity relative to the materials enclosed therein. The cosmetic composition of this embodiment of the present invention is an external treatment agent used for cosmetics, drugs, quasi drugs, etc., and has extremely excellent use characteristics in that a strong force is not required when it is to be broken by compression during usage, and that there is no feeling of foreign matter due to remaining portions of the capsule film. Therefore, it is preferably used particularly for cosmetics having characteristics which are emphasized. For example, by formulating microcapsules with particle sizes of 50 to 100 µm having hydrophobic components enclosed therein in cosmetics such as cosmetic water, emulsions, creams, shampoos, rinses, etc., a cosmetic imparting the effects not found in the prior art can be obtained. Embodiment 2c The remarks made about Embodiment 2b above also apply to Embodiment 2c with the exception that the particle size of the microcapsules according to this embodiment of the present invention is 100 to 1000 µm. Embodiment 3a In the complex coacervation method according to the present invention, gelatin is employed as the cationic hydrophilic polymer material, and the anionic hydrophilic polymer material, be any materials but those conventionally used are preferably employed. These may include gum arabic, sodium alginate, carboxymethyl cellulose alkali metal salts, carrageenan, maleic anhydride copolymer and acrylic anhydride copolymer. The method for producing microcapsules according to the present method comprises adding an aqueous solution of a hydrophilic polymer material having opposite charges into an aqueous solution of a heated cationic hydrophilic polymer substance to effect a complex coacervation, and then successively adding one or a mixture of two or more kinds of hydrophobic substances to effect dispersion and emulsification. Further, the emulsion is cooled according to a conventional method, and the capsule films are gelled, and thereafter, hardened with a hardening agent generally used, to be denatured into a substance which cannot be dissolved in water or other solvents. Embodiment 3b In the simple coacervation method according to the present invention, gelatin is used as the hydrophilic polymeric material. As the substance for inducing coacervation, various electrolytes and organic compounds may be employed. As the electrolyte, inorganic and organic electrolytes in general may be included. For example, inorganic electrolytes may include water-soluble metal salts and ammonium salts of sulfuric acid, hydrochloric acid, phosphoric acid, boric acid, hydroiodic acid, carbonic acid, silicic acid, nitric acid or hydrobromic acid, and organic electrolytes may include organic acids and water-soluble metal salts or ammonium salts of organic acids, amino acids and water-soluble metal salts or quaternary ammonium salts of amino acids, which can be employed singly or as a mixture of two or more thereof. As the organic compound, methanol, ethanol, phenol, resorcin, ethyl acetate, ethyl urethane, acetone or dioxane, for example may be included, and these may be employed singly or as a mixture of two or more thereof. In the method for producing microcapsules, after a simple coacervation is caused by an addition of the above electrolyte or organic compound into a heated aqueous solution of a hydrophilic polymer material, one or two or more kinds of mixed hydrophobic substances are successively added to effect dispersion and emulsification. The emulsion is cooled according to conventional method, and the capsule films are gelled, followed by hardening with a hardening agent generally employed, to be denatured into a substance not soluble in water or other solvents. The weight ratio of the water-soluble polymeric material for forming wall films with a hydrophobic substance should be desirably 1 : 100 or less. If the weight ratio of the hydrophobic substances to the water-soluble polymer is greater than 1 : 100, the strength of the microcapsule wall film will be remarkably lowered, whereby destruction may occur during capsule preparation, and further, hydrophobic substances not enclosed may be sometimes formed. The hardening agent for making the capsule film after gellation of the capsule film may include, aldehydes such as glutaraldehyde or glyceraldehyde: tannic acid or gallic acid; or alums such as potassium alum or iron alum may be employed, but these are not limited in the invention, and any of hardening agents generally employed can be used. The microcapsules obtained according to the present production method have particle sizes which are determined depending substantially on the sizes of the capsule core substances, and are, for example, about 1 to 1000 µm in diameter. According to the present invention, the following effects can be advantageously obtained. (1) The capsule-containing cosmetic of Embodiment (1) of the present invention has the advantages that there is no "escape" of the capsules during usage, whereby the capsules can be easily broken and the contents leaked, that the oil component can be easily spread onto the skin, and that there is no feeling of foreign matter through remaining portions of the capsule film after breakage, and it is also a cosmetic having a good usability, and an excellent luster imparting effect and skin wettability. (2) The cosmetic compositions of Embodiments 2a, 2b and 2c of the present invention comprise microcapsules formulated therein, which have the advantage of being extremely stable without breaking during preparation of the external agent observed at all, and can be broken easily without "escape" during usage to leak the enclosed components, whereby the oil components can be easily spread onto skin, and have no feeling of foreign matter due to remaining portions of the capsule film after breaking, and thus have a good useability and an excellent luster imparting effect and skin wettability. (3) According to the microcapsule production methods of Embodiments 3a and 3b of the present invention, in the complex coacervation method and the simple coacervation method, many kinds of hydrophobic substances with different properties can be microencapsulated in one step, whereby the operations of production, washing, etc., can be carried out at one time, which is extremely effective for reducing the time and labor required. Also, even if a large number of different kinds of hydrophobic substances are added, microcapsules enclosing separate hydrophobic substances can be produced, and therefore, a simultaneous preparation of substances having a high reactivity is possible and applications over a wide range can be expected. Examples The present invention will now be further illustrated by, but is by no means limited to, the following Examples, wherein all parts and percentages are expressed on a weight basis unless otherwise noted. Example 1-1 To a solution of 10 g of acid-treated gelatin and 10 g of gum arabic dissolved in 200 g of purified water of 40°C was added 150 g of squalane, and the mixture was stirred by a propeller stirring machine at 300 rpm. Further, a 10% aqueous acetic acid was dropwise added to the oil droplet dispersion, the pH was adjusted to 4.3, and the solution was diluted by an addition of 600 g of purified water at 40°C. Subsequently, cooling was effected externally of the vessel, while stirring, and 20 g of 10% aqueous potassium alum solution was added at a liquid temperature of 8°C, followed by stirring for 2 hours to harden the capsule film. The product thus obtained was separated from the aqueous phase by decantation, and by repeating the water washing, capsules with an average particle size of 700 µm and a weight ratio of gelatin to squalane of 1 : 30 were obtained. The capsules were formulated according to the recipe as shown below to obtain a transparent gel-like cosmetic water having a viscosity of 3000 cps. The viscosity was measured by a B type viscometer Model B8L manufactured by Tokyo Seiki Co., Ltd. using a rotor #4 at 12 rpm, and the following method was employed. Glycerine 5% Propylene glycol 4 Gelatin capsules 5 Ethanol 10 Sodium polyacrylate 1 Preservative q.s. Purified water 75 As a Comparative Example, the amount of sodium polyacrylate formulated in the above recipe was lowered to 0.2%, the viscosity was lowered to 800 mPa s (cps) to give a gel-like cosmetic water (Comparative Example 1-1), and with the same recipe, a gel-like cosmetic water having capsules with a particle size of 100 µm comprising a film of methyl methacrylate prepared according to the in situ polymerization method described in Japanese Unexamined Patent Publication (KOKAI) No. 59-73510 was obtained (Comparative Example 1-2), and a gel-like cosmetic water having only the same amount of squalane of Example 1-1 dispersed in the recipe without formulation of the capsules (Comparative Example 1-3) was prepared, respectively, and comparative evaluations with the above Example were conducted. The results are shown in Table 1-1. As shown in the Table, the evaluation of Example 1-1 was excellent in all items, compared with the other Examples. Example 1-1 Comparative Example 1-1 Comparative Example 1-2 Comparative Example 1-3 Appearance (transparency) o ○ o ○ x x Stability at 50° o ○ o ○ o x Escape of capsules o ○ x ▵ - Fracturability of capsules o ○ o x - Leak of squalane during application o ○ o x - Smoothness during application (no foreign matter feeling) o ○ o ○ x - Wetness of skin o ○ o ▵ ▵ Considerably good o ○ Good o Common ▵ Bad x Example 1-2 Emulsion Capsules prepared according to the same method as in Example 1-1 and enclosing oil components at a ratio of methylphenylsiloxane : vitamin E = 1 : 0.1 (gelatin : enclosed material = 1 : 20, average particle size: 500 µm) were formulated according to the following recipe to obtain a gel-like emulsion having a viscosity of 1500 mPas cps. Stearic acid 2% Cetanol 2 Petrolatum 3 Lanolin alcohol 2 Liquid paraffin 10 Polyoxyethylene monooleic acid ester (10EO) 2 Preservative, antioxidant q.s. Glycerine 3 Propylene glycol 5 Triethanolamine 1 Gelatin capsules 8 Sodium polyacrylate 0.5 Purified water 61.5 Example 1-3 Cream Two kinds of gelatin capsules enclosing γ-linoleic acid prepared according to the same method as in Example 1-1 (gelatin : enclosed material = 1 : 30, average particle size: 600 µm) and gelatin capsules enclosing the oily components at a ratio of liquid paraffin : flavor = 1 : 0.1 (gelatin : enclosed material = 1 : 25, average particle size: 600 µm) were formulated according to the following recipe to obtain a cream having a viscosity of 18000 mPa s (cps). Beeswax 2% Stearyl alcohol 5 Stearic acid 8 Squalane 10 Self-emulsification type propylene glycol monostearate 3 Polyoxyethylene cetyl ether (20EO) 1 Preservative, antioxidant q.s. Propylene glycol 8 Glycerine 4 Triethanolamine 1 Gelatin capsules (enclosed material: γ-linoleic acid) 2 Gelatin capsules (enclosed material: liquid paraffin: flavor = 1 : 0.1) 10 Polyethylene glycol 0.6 Purified water 45.4 Example 2-1 To a solution of 10 g of acid-treated gelatin and 10 g of gum arabic dissolved in 200 g of purified water at 60°C was added 150 g of a hydrophobic component, and the mixture was stirred by a propeller stirring machine at 600 rpm. Further, a 10% aqueous acetic acid was added dropwise to the dispersion, to adjust the pH to 4.3, followed by dilution with an addition of 600 g of purified water at 40°C. Subsequently, cooling was effected externally of the vessel, while stirring, and 10 g of a 25% aqueous glutaraldehyde was added at a liquid temperature of 8°C and the mixture was stirred for 2 hours to harden the capsule film. The product thus obtained was separated from the aqueous phase by decantation, and water washing was repeated, and thereafter, excess water was removed by a 200 mesh sieve to obtain capsules with an average particle size of 300 µm. The three kinds, A to C, shown below were used as the hydrophobic components enclosed within the capsules, and the capsules prepared had breaking strengths of 1.6, 6.9 and 16.7 kPa (16, 70, and 170 g/cm²) respectively. Also, the capsules enclosing the hydrophobic components D to F, shown below, and having breaking strengths of 96.5, 67.2 and 40.0 kPa (984, 685 and 408 g/cm²) respectively, were prepared according to the same method, for comparison. For seven such capsules, a comparative evaluation was conducted of the breaking by mixing in a viscous base and the presence of a feeling of foreign matter during application onto the skin. The results are shown in Table 2-1. Hydrophobic components enclosed A. Liquid paraffin : cetostearyl alcohol = 94 : 6 B. Liquid paraffin : beeswax = 92 : 8 C. Liquid paraffin : solid paraffin = 94 : 6 D. Liquid paraffin E. Liquid paraffin : petrolatum = 80 : 20 F. Liquid paraffin : petrolatum = 60 : 40 Method of measuring hardness of enclosed material An M-301AR model cardmeter (produced by Iio Denki) was used as the measuring instrument, and the measurement was conducted by imposing a load of 200 g on a penetration needle having a diameter of 8 mm. Method for measuring breaking strength The capsules were laid on a glass flat plate and were compressed under a load of 1 g per 1 second by a Teflon 8 mm columnar rod mounted on a creepmeter Rheoner RE-3305 model (manufactured by Yamaden Co., Ltd.), and the breaking strength was determined by calculating the amount of load upon fracture, calculated per 1 cm². Evaluation of breaking by mixing in a viscous base Into 100 g of a highly viscous base (500 mPa s (cps) in terms of the value measured by a Brookfield type rotatary viscometer) obtained by neutralization of a 1% aqueous sodium polyacrylate, 10 g of capsules were formulated and the occurrence of capsule breaking after stirring and mixing by a propeller stirring machine for 5 minutes was observed and evaluated by an optical microscope. The evaluation method was conducted by rating in the three ranks: o: no breaking observed ▵: slight breaking observed x: substantially all capsules broken Evaluation of feeling of foreign matter by application onto the skin Each sample was applied on the skin at the innerside portion of forearm, feeling of foreign matter during rubbing with palms was represented by overall evaluation according to organoleptic test by a panel of 10 members. The evaluation was conducted at the 3 ranks shown below: o: no feeling of foreign matter at all ▵: slight feeling of foreign matter x: extreme feeling of foreign matter A B C D E F Hardness of enclosed matter (g) 6 6 5 0 1 6 Breaking strength of capsules (g/cm² = kPa x 10.2) 16 70 170 984 685 408 Capsule breaking by mixing o o o o o o Foreign matter feeling during application onto skin o o o x x ▵ A shown in Table 2-1, upon evaluation, the capsules A to C having breaking strengths in the range of 1 to 30 kPa (10 to 300 g/cm²) were found to be excellent in all of the items, compared with the other capsules D to F. Example 2-2 Five kinds of capsules, A to F, obtained in Example 2-1 were formulated according to the recipe as shown below to prepare a transparent gel-like cosmetic water, and each sample was applied on the skin at the innerside portion of the forearm, and the difficulty of escape of the capsules during rubbing with the palms of the hands, fracturability of the capsules, leakage of the enclosed material during application, smoothness during application, and skin wetness were evaluated overall, according the organoleptic test by a panel of 10. The evaluation was divided into the 4 rankings shown below. o ○ : very good o : good ▵ : average x : poor Glycerine 5% Propylene glycol 4 Gelatin capsules 5 Ethanol 10 Sodium polyacrylate 1 Preservative q.s. Purified water 75 A B C D E F Escape of capsules o ○ o ○ o ○ x x ▵ Fracturability of capsules o ○ o ○ o ○ x x ▵ Leakage of enclosed matter during application o ○ o ○ o ○ x ▵ ▵ Smoothness during application (no foreign matter feeling) o ○ o ○ o #CIR# x x ▵ Wetness of skin o ○ o ○ o ○ ▵ ▵ o As apparent from Table 2-2, the three samples A, B and C were found to be excellent in all of the items, compared with the others. Example 2-3 Emulsion Capsules prepared according to the same method as in Example 2-1 enclosing the oil components of liquid paraffin : cetanol : vitamin A palmitate = 92 : 7 : 1 (average particle size: 200 µm, breaking strength: 2.5 kPa (25 g/cm²)) were formulated according to the recipe shown below to obtain an emulsion. Stearic acid 5% Cetanol 2 Lanolin alcohol 3 Liquid paraffin 2 Polyoxyethylene monooleic acid ester (10ED) 10 Preservative, antioxidant q.s. Glycerine 3 Propylene glycol 5 Triethanolamine 1 Gelatin capsules 8 Purified water balance Example 2-4 Cream Two kinds of gelatin capsules A prepared according to the same method as in Example 2-1 enclosing oil components of cetyl isooleate : microcrystalline wax : γ-linoleic acid = 90 : 9 : 1 (average particle size: 700 µm, breaking strength: 3.9 kPa (40 g/cm²)) and gelatin capsules B enclosing oil components of neopentylglycol didecanoate : glycerine trimyristate : flavor = 60 : 30 : 10 (weight ratio) (average particle size: 150 µm, breaking strength: 18.2 kPa (186 g/cm²)) were formulated according to the following recipe to obtain a cream. Beeswax 2% Stearyl alcohol 5 Stearic acid 8 Squalane 10 Self-emulsification type propylene glycol monostearate 3 Polyoxyethylene cetyl ether (20EO) 1 Preservative, antioxidant q.s. Propylene glycol 8 Glycerine 4 Triethanolamine 1 Gelatin capsules A 2 Gelatin capsules B 10 Polyethylene glycol 0.6 Purified water balance An evaluation was made of the gelatin capsule formulations prepared as described above. The samples used for evaluation were respectively those of Examples 2-3 and 2-4, and of Comparative Examples 2-1 and 2-2 shown below. The evaluation was conducted by applying each sample on the skin at the inner side of the forearm, and the escape of the capsules when rubbed with the palms of the hands, fracturability of the capsules, leak of the enclosed material during application, smoothness during application and, skin wetness were evaluated overall according to an organoleptic test, by a panel of 10. The evaluation was divided into the four rankings shown below: o ○ : very good o : good ▵ : average X : poor Comparative Example 2-1 Capsules in which the cetanol in the gelatin capsules in Example 2-3 was replaced with the same amount of fluid paraffin (breaking strength: 96.1 kPa (980 g/cm²)) were formulated into the emulsion recipe. Comparative Example 2-2 Capsules in which the microcrystalline wax in the gelatin capsules A in Example 2-4 was replaced with the same amount of cetyl isooleate (breaking strength: 48.2 kPa (492 g/cm²)) and the capsules in which the glycerine trimyristate in the gelatin capsules B was replaced with the same amount of neopentylglycol didecanoate (breaking strength: 118.7 kPa (1210 g/cm²)), were formulated into the cream recipe. Example Comparative Example 2-3 2-4 2-1 2-2 Escape of capsules o ○ o ○ x x Fracturability of capsules o ○ o x x Leakage of enclosed matter during application o ○ o ○ x x Smoothness during application (no foreign matter feeling) o ○ o x x Wetness of skin o ○ o ○ ▵ ▵ As apparent from Table 2-3, the cosmetics containing capsules having a breaking strength of 1 to 30 kPa (10 to 300 g/cm²), obtained by mixing a solid or semi-solid oil component into the gelatin capsules formulated therein, were found to be excellent in all of the items, compared with the others. Example 3-1 To a solution of 5 g of acid-treated gelatin and 10 g of gum arabic dissolved in 200 g of purified water of 50°C was added 100 g of mixed oil components of liquid paraffin : cetyl isooleate : vitamin A palmitate = 60 : 35 : 5, and the mixture was stirred by a homomixer emulsifying machine at 7000 rpm. Further, to this oil droplet dispersion was added a 10% aqueous acetic acid to adjust the pH to 4.3, followed by dilution with an addition of 600 g of purified water at 50°C. Subsequently, cooling was effected externally of the vessel, while stirring, and 5 g of an aqueous 25% Glutaraldehyde was added at a liquid temperature of 8°C, followed by stirring for 2 hours to harden the capsule film. The product thus obtained was separated from the aqueous phase by decantation, and by repeating the water washing, capsules with particle sizes of 10 to 50 µm were obtained. The capsules were formulated according to the recipe shown below to prepare a water-in-oil type emollient lotion. Microcrystalline wax 1.0 (part) Beeswax 2.0 Lanolin 2.0 Liquid paraffin 20.0 Squalane 10.0 Sorbitan sesquioleic acid ester 4.0 Polyoxyethylene (20 mole) sorbitan monooleic acid ester 1.0 Flavor 0.4 Preservative q.s. Vitamin A palmitate enclosing microcapsules 10.0 Propylene glycol 8.0 Purified water balance Preparation method: vitamin A palmitate enclosing microcapsules and propylene glycol were added to purified water, and the aqueous phase portion maintained at 70°C by heating was added to the oil phase portion maintained at 70°C by mixing and heating and dissolving other components, to effect a preliminary emulsification, followed by homogeneous emulsification by a homomixer. After the emulsification, the emulsion was stirred while being cooled. Also, as a Comparative Example, an emollient lotion having the same amount of mixed oil components as the enclosed amount formulated in the oil phase without a formulation of microcapsules according to the above recipe (Comparative Example 3-1) was prepared, and a comparative evaluation was conducted with the above Example 3-1 with respect to the stability with a lapse of time of the vitamin A palmitate. The experiments were conducted by storing the vessels containing the respective emollient lotions in a thermostat at 50°C, and the amount of vitamin A palmitate remaining after 7, 14, 30, and 60 days was determined. The results are shown in Fig. 1, from which it can be seen that the reduction of vitamin A palmitate was slower in Example 3-1, compared with that in Comparative Example 3-1. Example 3-2 The microcapsules (particle size: 20 - 80 µm) prepared according to the same method as in Example 3-1, except for changing the acid-treated gelatin to 10 g, using the oil components of squalane : cetanol : flavor (llnalool) = 85 : 10 : 5 as the hydrophobic components to be enclosed within microcapsules, and changing the stirring speed of the homomixer to 5000 rpm, were formulated according to the following recipe to obtain an water-in-oil type cream. Microcrystalline wax 9.0 (part) Paraffin 2.0 Beeswax 3.0 Petrolatum 5.0 Reduced lanolin 8.0 Squalane 34.0 Hexadecylazipic acid ester 10.0 Hydrophilic glycerine monooleate 3.5 Polyoxyethylene (20 mole) sorbitan monooleic acid ester 1.0 Preservative q.s. Flavor enclosing microcapsules 20.0 Propylene glycol 2.0 Purified water balance Preparation method: To purified water were added flavor-enclosing microcapsules and propylene glycol, and an aqueous phase portion heated to 70°C was added to the oil phase portion maintained at 70°C by mixing and dissolving, by heating other components to effect a preliminary emulsification, followed by homogeneous emulsification by a homomixer, and the emulsion was adjusted to 30°C by a heat-exchanger. Also, as in the Comparative Example, a water-in-oil type cream having the same amount of mixed oil components as the enclosed amount without formulation of the microcapsules according to the above recipe in the oil phase (Comparative Example 3-2) was prepared, and a comparative evaluation of the above Example was conducted with respect to the stability of the flavor with a lapse of time. The experiments were conducted by storing the vessels containing the respective water-in-oil type creams in a thermostat of 0°C, 25°C and 50°C, and the change in flavor after 60 days when stored at 0°C, with the Comparative Example as the standard, was represented by an overall evaluation, by the organoleptic test, by a panel of 10. The evaluation method was divided into the following 3 rankings: o : no change in flavor ▵ : slight change in flavor x : extreme change in flavor 0°C 25°C 50°C Example 3-2 o o ▵ Comparative Example 3-2 o ▵ x As shown in Table 3-1, Example 3-2 having a flavor microencapsulated was found to exhibit substantially no change in flavor at the respective temperatures, compared with the Comparative Example. In the following, other Examples are shown which have the same excellent effects as obtained in Examples 3-1 and 3-2. Example 3-3 Skin lotion Microcapsules with particle sizes of 30 to 80 µm prepared according to the same method as in Example 3-1 enclosing the oil components of avocado oil : estrone = 95.5 : 0.5 were formulated according to the following recipe to obtain a skin lotion. Oil Phase Macademian nut oil 10.0 (part) Jojoba oil 15.5 Lanolin 2.0 Polyoxyethylene (10 mole) polyoxypropylene (15 mole) 2-dodecylhexadecyl ether 3.0 Butyl paraoxybenzoate 0.1 Flavor 0.1 Aqueous Phase Oil components enclosing microcapsules 15.0 Glycerine 5.0 Purified water balance Preparation method: The oil phase portion was dissolved homogeneously at 70°C, and separately, the aqueous phase portion was mixed homogeneously at 70°C. The aqueous phase portion was added to the oil phase portion, while stirring, and after further emulsification by a homomixer, the emulsion was cooled, while stirring, to room temperature and filled in a vessel. Example 3-4 Cosmetic base cream Microcapsules (particle size: 30 to 70) prepared according to the same method as in Example 3-1 containing the oil components of orange oil : riboflavin butyric acid ester = 90 : 10 were formulated according to the following recipe to obtain a cosmetic base cream. Oil Phase Squalane 23.0 (part) Cyclic silicone 5.0 Organophilic clay mineral obtained by treating 0.5 g of bentone-38 with 0.1 g of myristoyl lecithin 0.6 Microcrystalline wax 2.0 Butyl parahydroxybenzoate 0.1 Flavor 0.1 Titanium oxide 1.0 Coloration pigment 0.1 Aqueous Phase Oil components enclosing microcapsules 5.0 Dipropylene glycol 5.0 Purified water balance Preparation method: The aqueous phase portion dissolved at 70°C was gradually added, while stirring, by a disper into the oil phase, and mixed and dispersed at 70°C to be emulsified therein, followed by cooling. Example 3-5 Night cream Microcapsules (particle size: 25 to 80 µm) prepared according to the same method as in Example 3-1 enclosing the oil components of isocetyl oleate : arachidonic acid : pyridoxyl dipalmitate = 80 : 15 : 5 were formulated according to the following recipe to obtain a night cream. Oil Phase Squalane 25.0 (part) Ceresine 3.0 Microcrystalline wax 1.5 Lanolin 0.5 Petrolatum 6.0 Flavor q.s Preservative q.s Amino Acid W/O Gel Glycerine monooleate 4.0 Monosodium L-glutamate 12.8 Aqueous Phase Oil components enclosing microcapsules 7.0 Propylene glycol 5.0 Purified water balance Preparation method: To purified water heated to 70°C was added monosodium L-glutamate to be dissolved therein, and the solution was added to glycerine monooleate at 70°C to prepare an amino acid W/O gel by a homomixer. Then, the oil phase portion and the aqueous phase portion dissolved by heating at 70°C were added and homogeneously emulsified by a homomixer, followed by cooling by a heat-exchanger. Example 3-6 Lipstick Microcapsules (particle size: 2 to 20 µm) prepared according to the same method as in Example 3-1 enclosing the oil components of safflower oil : decyl oleate = 75 : 25 were formulated according to the following recipe to obtain an emulsified lipstick. Oil Phase Castor oil 47.0 (part) Diglyceride isostearate 10.0 Candelilla wax 8.0 Solid paraffin 10.0 Polyoxyethylene (20 mole) polyoxypropylene (20 mole) 2-tetradecyloctadecyl ether 4.0 Pigment Red No. 202 1.0 Red No. 204 0.5 Titanium oxide 1.0 Red iron oxide 1.5 Yellow iron oxide 1.0 Aqueous Phase Oil components enclosing microcapsules 5.0 Glycerine 3.0 Purified water balance Preparation method: The oil phase portion was homogeneously dissolved at 80°C, and the pigments were added thereto to be dispersed therein, and further, the aqueous phase was added to effect emulsification. Then, while stirring, the emulsion was filled into a molding vessel and cooled. Example 3-7 Emulsified cheek rouge Microcapsules (particle size: 8 to 50 µm) prepared according to the same method as in Example 3-1 enclosing the oil components of macademia nut oil : pantothenyl ethyl ether = 95 : 5 were formulated according to the following recipe to obtain an emulsified face rouge. Oil Phase 2-ethylhexanoic acid triglyceride 20.0 (part) Hydrogenated lanolin 15.0 Microcrystalline wax 5.0 Polyoxyethylene (15 mole) polyoxypropylene (30 mole) 2-octyldodecyl ether 3.0 Pigment Talc 20.0 Titanium oxide 5.0 Red iron oxide 3.0 Yellow iron oxide 1.0 Black iron oxide 0.1 Red No. 201 1.0 Butyl paraoxybenzoate 0.1 Aqueous Phase Oil components enclosing microcapsules 5.0 Glycerine 5.0 Preparation method: The oil phase was dissolved homogeneously at 80°C, the pigments were added to be dispersed therein, and further, the aqueous phase was added to effect emulsification. While stirring, the emulsion was cast into a vessel and cooled. Next, an evaluation was made of the cosmetics having microcapsules formulated therein and prepared as described above. The samples used for the evaluation were, respectively, samples of Example 3-3 to 3-7 and the following Comparative Examples 3-3 to 3-7. The evaluation method was conducted by observing the destruction of microcapsules during the cosmetic preparation by an optical microscope, and evaluated according to the following four rankings: o ○ : no breakage o : slight breakage ▵ : substantial breakage and broken film observed x : complete breakage and no trace of film. Also, each sample was applied on the skin at the inside portion of the forearm, and the feeling of foreign matter through remaining portions of the capsule film when rubbed by the palms of the hands was subjected to an overall evaluation, by an organoleptic test by a panel of 10, according to the following three rankings: o : no feeling of foreign matter ▵ : slight feeling of foreign matter x : extreme feeling of foreign matter. Comparative Example 3-3 The microcapsules of Example 3-3 were prepared by propeller stirring at 600 rpm (particle size: 200 to 400 µm) and formulated according to the skin lotion recipe. Comparative Example 3-4 The microcapsules of Example 3-4 were prepared by propeller stirring at 300 rpm (particle size: 500 to 1000 µm) and formulated according to the cosmetic base cream recipe. Comparative Example 3-5 The microcapsules of Example 3-5 were prepared by propeller stirring at 350 rpm (particle size: 400 to 800 µm) and formulated according to the night cream recipe. Comparative Example 3-6 The microcapsules of Example 3-6 were prepared by propeller stirring at 750 rpm (particle size: 150 to 350 µm) and formulated according to the lipstick recipe. Comparative Example 3-7 The microcapsules of Example 3-7 were prepared by propeller stirring at 550 rpm (particle size: 200 to 400 µm) and formulated according to the emulsified check rouge recipe. Breakage during preparation Breakage during usage Example 3-3 o ○ o 3-4 o ○ o 3-5 o ○ o 3-6 o ○ o 3-7 o ○ o Comparative Example 3-3 o ▵ 3-4 ▵ x 3-5 ▵ x 3-6 x ▵ 3-7 x x As apparent from Table 3-2, the cosmetics having microcapsules with particle sizes of 100 µm or less were found to be excellent in all of the items, compared with the cosmetics having capsules larger than 100 µm. Example 4-1 To a solution of 10 g of acid-treated gelatin and 10 g of gum arabic dissolved in 200 g of purified water of 60°C was added 150 g of squalane, and the mixture was stirred by a propeller stirring machine at 1300 rpm. Further, 10% aqueous acetic acid was added dropwise to the dispersion to adjust the pH to 4.3, followed by dilution with an addition of 600 g of purified water of 40°C. Subsequently, cooling was effected externally of the vessel, while stirring, and 10 g of 25% aqueous glutaraldehyde was added at a liquid temperature of 8°C and the mixture was stirred for 2 hours to harden the capsule film. The product thus obtained was separated from the aqueous phase by decantation, and water washing was repeated, and thereafter, excess water was removed by screening to obtain capsules with an average particle size of 40 µm. The microcapsules were dispersed to 10% in terms of weight ratio in solutions with seven kinds of compositions of glycerine : water = 0 : 100, 10 : 90, 20 : 80, 30 : 70, 40 : 60, 60 : 40, 80 : 20, and then formulated according to the recipes shown below to prepare emollient lotions, and the breakage by stirring during preparation and feeling of foreign matter when applied onto the skin were then evaluated, by comparison. Also, microcapsules were removed from the emollient lotion and the breaking strength thereof measured. Oil Phase Squalane 5.0 parts Petrolatum 2.0 Beeswax 0.5 Sorbitane sesquioleic acid ester 0.8 Polyoxyethylene (20 mol) oleyl ether 1.2 Flavor 0.5 Preservative q.s. Aqueous Phase Microcapsule dispersion 20.0 Preparation method: To purified water were added the microcapsule dispersion and ethanol, the mixture was heated to 70°C, and to this mixture was added the oil phase portion dissolved at 70°C to effect preliminary emulsification, followed by homogeneous emulsification by a homomixer with an addition of the carboxyvinyl polymer and potassium hydroxide, and thereafter, the emulsion was cooled to 30°C by a heat-exchanger. The respective experiments were conducted according to the following methods. Evaluation of breakage during lotion preparation Breakage of capsules in the emollient lotion prepared according to the above recipe and method was observed by an optical microscope. The evaluation method was conducted according to the three ranks: o : no breakage observed ▵ : slight breakage observed x : breakage of all capsules Evaluation of feeling of foreign matter upon application to the skin The emollient lotions formulated with the respective capsules were applied onto the skin on the inner side portion of the forearm, and feeling of foreign matter when rubbed with the palms of the hands was represented in terms of overall evaluation, by an organoleptic test by a panel of 10. The evaluation was divided into the three rankings: o : no foreign matter feeling ▵ : slight foreign matter feeling x : extreme foreign matter feeling Take-out of capsules The emollient lotion was centrifugated at 5000 rpm and the microcapsules floating in the upper portion were taken out. Method for measuring breaking strength The same method as mentioned above. Glycerine 0 10 20 30 40 60 80 Water 100 90 80 70 60 40 20 Capsule breakage during preparation o o o o o o o Foreign matter feeling during application on skin x x ▵ o o o o Breaking strength of capsules (g/cm² = kPa x 10.2) 1056 867 472 205 121 73 49 As shown in Table 4-1, the microcapsules having a breaking strength in the range of 1 to 30 kPa (10 to 300 g/cm²) were found to be excellent in all of the items, compared with other microcapsules. Example 4-2 Microcapsules enclosing a liquid paraffin with an average particle size of 32 µm were prepared according to the same method as in Example 4-1, except that the stirrer was replaced by a homomixer and the stirring speed was made 1200 rpm. The microcapsules were dispersed to 15% in terms of weight ratio in solutions with 7 kinds of compositions of propylene glycol : water = 0 : 100, 10 : 90, 20 : 80, 30 : 70, 40 : 60, 60 : 40, 80 : 20, and then formulated according to the recipes shown below to prepare transparent gel-like cosmetic waters, and the difficulty of escape of capsules, ease of rupture of capsules, ease of leakage of enclosed matter during application, smoothness during application and skin wetness when the respective samples were applied onto the skin on the innerside of the forearm were represented by an overall evaluation, by an organoleptic test, by a panel of 10. The evaluation was divided into the following 4 rankings: o ○ : very good o : good ▵ : average x : poor The breaking strength of microcapsules taken out of the gel-like cosmetic water was measured at the same time. Microcapsule dispersion 20.0 parts Oleyl alcohol 4.0 Polyoxyethylene (20 mol) sorbitane monolauric acid ester 1.5 Polyoxyethylene (20 mol) lauryl ether 0.5 Ethanol 10.0 Sodium polyacrylate 1.0 Flavor 0.1 Preservative q.s. Purified water balance Propylene glycol 0 10 20 30 40 60 80 Water 100 90 80 70 60 40 20 Difficulty of escape of capsules x x ▵ o o ○ o ○ o ○ Ease of rupture of capsules x x o o o ○ o ○ o ○ Ease of leakage of enclosed matter during application x x ▵ o o #CIR# o ○ o ○ Smoothness during application (no foreign matter feeling) x x x o o ○ o #CIR# o ○ Skin wetness x x ▵ o o ○ o ○ o ○ Breaking strength of capsules (g/cm² = kPa x 10⁻²) 1145 899 504 261 158 97 55 As shown in Table 4-2, the capsules having a breaking strength within the range of 1 to 30 kPa (10 to 300 g/cm²) were found to be excellent in all the items, compared with other capsules. Example 4-3 Cream Microcapsules (average particle size 6 µm) enclosing oil components at a ratio of fluid paraffin : vitamin A palmitate = 92 : 8 prepared by the same method as in Example 1, but changing the stirring speed by a homomixer to 4000 rpm, were dispersed to a weight ratio of 40% in a solution with a composition of propylene glycol : glycerine water = 50 : 20 : 30, and formulated according to the following recipe to obtain a cream. The breaking strength of the microcapsules taken out of the cream was found to be 23.7 kPa (242 g/cm²). Beeswax 2.0 parts Stearyl alcohol 5.0 Stearic acid 8.0 Squalane 10.0 Self-emulsification type propylene glycol monostearate 3.0 Polyoxyethylene cetyl ether (20 EO) 1.0 Preservative, antioxidant q.s. Triethanolamine 1.0 Microcapsule dispersion 20.0 Polyethylene glycol 0.6 Purified water balance Example 4-4 Shampoo Microcapsules (average particle size 22 µm) enclosing oil components at a ratio of dimethylpolysiloxane : liquid paraffin = 60 : 40 (weight ratio) prepared according to the same method as in Example 4-1, but changing the stirring speed by a homomixer to 1800 rpm, were dispersed to 15% in a solution with a composition of 1,3-butylene glycol : water = 40 : 60, and formulated according to the following recipe to obtain a shampoo. The breaking strength of the microcapsules taken out of the shampoo was found to be 23.1 kPa (236 g/cm²). AES-Na 16.0 parts Lauric acid diethanolamide 4.0 Microcapsule dispersion 18.0 Preservative, dye, flavor q.s. Purified water balance Example 4-5 Rinse Microcapsules (average particle size 15 µm) enclosing oil components at a ratio of squalane : vitamin E = 95 : 5 (weight ratio) prepared according to the same method as in Example 1, but changing the stirring speed by a homomixer to 2500 rpm, were dispersed to 40% in a solution with a composition of propylene glycol : polyethylene glycol : water = 45 : 5 : 50, and formulated according to the following recipe to obtain a rinse. The breaking strength of the microcapsules taken out of the rinse was found to be 15.5 kPa (158 g/cm²). Stearyl trimethyl ammonium chloride 2.0 parts Cetostearyl alcohol 3.0 Glyceryl monostearate 1.5 Sodium chloride 0.2 Microcapsule dispersion 25.0 Purified water balance Example 4-6 Microcapsules (average particle size 10 µm) enclosing oil components at a ratio of fluid paraffin : vitamin C stearate = 96 : 4 (weight ratio) prepared according to the same method as in Example 4-1, but changing the stirring speed by a homomixer to 3000 rpm, were dispersed to 15% in a solution with a composition of glycerine : sucrose : water = 70 : 5 : 25, and formulated according to the following recipe to obtain a foundation. The breaking strength of the microcapsules taken out of the foundation was found to be 14.2 kPa (145 g/cm²). Stearic acid 5.0 parts Lipophilic glycerine monostearate 2.5 Cetostearyl alcohol 1.0 Propylene glycol monolaurate 3.0 Fluid paraffin 4.0 Isopropyl myristate 9.0 Butyl p-oxybenzoate q.s. Flavor q.s. Titanium oxide 8.0 Kaolin 5.0 Talc 2.0 Bentonite 1.0 Colored pigment q.s. Microcapsule dispersion 12.0 Triethanolamine 1.2 Sorbitol 3.0 The cosmetics formulated with the microcapsules as prepared above were evaluated. The samples used for evaluation were the respective samples of Examples 4-3 to 4-6 and the following Comparative Examples 4-1 to 4-4. The evaluation method was based on the difficulty of escape of the capsules, ease of rupture of the capsules, ease of leakage of enclosed matter during application, smoothness during application and skin wetness when the respective samples were applied to the skin on the innerside of the forearm, by an overall evaluation, by an organoleptic test, by a panel of 10. The evaluation was divided into the following 4 rankings: o ○ : very good o : good ▵ : average x : poor Comparative Example 4-1 A formulation of a cream recipe was obtained by replacing propylene glycol and glycerine with an equal amount of water in the solution for dispersion of the microcapsules in Example 4-3. (The breaking strength of the microcapsules taken out of the cream was 208.6 kPa (2127 g/cm².) Comparative Example 4-2 A formulation of a shampoo recipe was obtained by changing the composition for dispersing the microcapsules in Example 4-4 to 1,3-butylene glycol : water = 25 : 75. (The breaking strength of the microcapsules taken out of the shampoo was 53.3 kPa (543 g/cm².) Comparative Example 4-3 A formulation of the rinse recipe was obtained by changing the composition of the solution for dispersing the microcapsules in Example 4-5 to propylene glycol : polyethylene glycol : water = 20 : 5 : 75. (The breaking strength of the microcapsules taken out of the rinse was 59.6 kPa (608 g/cm².) Comparative Example 4-4 A formulation of a foundation recipe was obtained by replacing glycerine and sucrose in the solution for dispersing the microcapsules in Example 4-6 with an equal amount of water. (The breaking strength of the microcapsules taken out of the foundation was 129.1 kPa (1316 g/cm².) Example Comparative Example 4-3 4-4 4-5 4-6 4-1 4-2 4-3 4-4 Difficulty of escape of capsules o ○ o ○ o ○ o #CIR# x ▵ x x Ease of rupture of capsules o o ○ o ○ o x x x x Ease of leakage of enclosed matter during application o o ○ o #CIR# o x x x x Smoothness during application (no foreign matter feeling) o ○ o ○ o #CIR# o ○ x x x x As apparent from Table 4-3, the cosmetics formulated with the capsules controlled to a breaking strength of 1 to 30 kPa (10 to 300 g/cm²) by mixing microcapsules and polyhydric alcohol were found to be more excellent in all of the items, compared with others. Example 5-1 To a solution of 10 g of acid-treated gelatin and 10 g of gum arabic dissolved in 200 g of purified water of 60°C was added 150 g of squalane, and the mixture was stirred by a propeller stirring machine at 1000 rpm. Further, 10% aqueous acetic acid was added dropwise to the dispersion to adjust the pH to 4.3, followed by dilution with an addition of 600 g of purified water at 40°C. Subsequently, cooling was effected externally of the vessel while stirring, and 10 g of 25% aqueous glutaraldehyde was added at a liquid temperature of 8°C and the mixture was stirred for 2 hours to harden the capsule film. The product thus obtained was separated from the aqueous phase by decantation, and water washing was repeated, and thereafter, excess water was removed by screening to obtain capsules with an average particle size of 70 µm. The microcapsules were dispersed to 10% in terms of weight ratio in solutions with seven kinds of compositions of glycerine : water = 0 : 100, 10 : 90, 20 : 80, 30 : 70, 40 : 60, 60 : 40, 80 : 20, and then formulated according to the recipes shown below to prepare transparent gel-like cosmetic waters, and breakage by stirring during preparation and a feeling of foreign matter when applied onto the skin were evaluated, by comparison. Also, microcapsules were taken out of the transparent gel-like cosmetic water and the breaking strength thereof measured. Microcapsule dispersion 20.0 parts Oleyl alcohol 4.0 Polyoxyethylene (20 mol) sorbitane monolauric acid ester 1.5 Polyoxyethylene (20 mol) lauryl ether 0.5 Ethanol 10.0 Sodium polyacrylate 1.0 Flavor 0.1 Preservative q.s. Purified water balance The respective experiments were conducted according to the following methods. Evaluation of breakage during cosmetic water preparation The breakage of capsules in the transparent gel-like cosmetic water prepared according to the above recipe was observed by an optical microscope. The evaluation was divided into the following three rankings: o : no breakage observed ▵ : slight breakage observed x : all capsules broken Evaluation of feeling of foreign matter upon application to the skin The cosmetic waters formulated with the respective capsules were applied onto the skin on the inner side portion of the forearm, and a feeling of foreign matter was represented in terms of an overall evaluation, by an organoleptic test by a panel of 10. The evaluation was divided into the following three rankings: o : no foreign matter feeling ▵ : slight foreign matter feeling x : extreme foreign matter feeling Take-out of capsules The transparent gel-like cosmetic water was centrifugated at 4000 rpm and the microcapsules floating at the upper portion were taken out. Method for measuring breaking strength The same method as mentioned above. Glycerine 0 10 20 30 40 60 80 Water 100 90 80 70 60 40 20 Capsule breakage during preparation o o o o o o o Foreign matter feeling during application on skin x x ▵ o o o o Breaking strength of capsules (g/cm² = kPa x 10.2) 1080 606 368 185 103 59 28 As shown in Table 5-1, the microcapsules having a breaking strength in the range of 1 to 30 kPa 10 to 300 g/cm² were found to be excellent in all of the items, compared with other microcapsules. Example 5-2 Microcapsules enclosing a liquid paraffin with an average particle size of 85 µm were prepared according to the same method as in Example 5-1, except the stirrer was replaced by a homomixer and the stirring speed changed to 850 rpm. The microcapsules were dispersed to 15% in terms of weight ratio in solutions with 7 kinds of compositions of propylene glycol : water = 0 : 100, 10 : 90, 20 : 80, 30 : 70, 40 : 60, 60 : 40, 80 : 20, and then formulated according to the recipe shown below to prepare emollient lotions, and the difficulty of escape of capsules, ease of rupture of capsules, ease of leakage of enclosed matter during application, smoothness during application and skin wetness when the respective samples were applied onto the skin on the innerside of the forearm were represented by an overall evaluation, by an organoleptic test, by a panel of 10. The evaluation was divided into the following 4 rankings: o ○ : very good o : good ▵ : average x : poor The breaking strength of the microcapsules taken out of the gel-like cosmetic was measured at the same time. Squalane 5.0 parts Petrolatum 2.0 Beeswax 0.5 Sorbitane sesquioleic acid ester 0.8 Polyoxyethylene (20 mol) oleyl ether 1.2 Flavor 0.5 Preservative q.s. Microcapsule dispersion 20.0 Ethanol 5.0 Carboxyvinyl polymer (1.0% aqueous solution) 20.0 Potassium hydroxide 0.1 purified water balance The breaking strength of the microcapsules taken out of the emollient lotion was measured at the same time. Propylene glycol 0 10 20 30 40 60 80 Water 100 90 80 70 60 40 20 Difficulty of escape of capsules x x ▵ o ○ o ○ o ○ o ○ Ease of rupture of capsules x x o o ○ o ○ o ○ o ○ Ease of leakage of enclosed matter during application x x o o ○ o ○ o ○ o ○ Smoothness during application (no foreign matter feeling) x x ▵ o ○ o #CIR# o ○ o ○ Skin wetness x x o o o o o Breaking Strength of capsules (g/cm² = kPa x 10.2) 1020 602 334 178 108 43 27 As shown in Table 5-2, the capsules having a breaking strength within the range 1 to 30 kPa (10 to 300 g/cm²) were found to be excellent in all the items, compared with other capsules. Example 5-3 Cream Microcapsules (average particle size 58 µm) enclosing oil components at a ratio of liquid paraffin : vitamin A palmitate = 92 : 8 prepared according to the same method as in Example 5-1, but changing the stirring speed by a homomixer to 1150 rpm, were dispersed to a weight ratio of 40% in a solution with a composition of propylene glycol : glycerine : water = 50 : 20 : 30, and formulated according to the following recipe to obtain a cream. The breaking strength of the microcapsules taken out of the cream was found to be 11.0 kPa (112 g/cm²). Beeswax 2.0 parts Stearyl alcohol 5.0 Stearic acid 8.0 Squalane 10.0 Self-emulsification type propylene glycol monostearate 3.0 Polyoxyethylene cetyl ether (20 EO) 1.0 Preservative, antioxidant q.s. Triethanolamine 1.0 Microcapsule dispersion 20.0 Polyethylene glycol 0.6 Purified water balance Example 5-4 Shampoo Microcapsules (average particle size 92 µm) enclosing oil components at a ratio of dimethylpolysiloxane : liquid paraffin = 60 : 40 (weight ratio) prepared according to the same method as in Example 5-1, but changing the stirring speed by a homomixer to 800 rpm, were dispersed to 25% in a solution with a composition of 1,3-butylene glycol : water = 40 : 60, and formulated according to the following recipe to obtain a shampoo. The breaking strength of the microcapsules taken out from the shampoo was found to be 24.8 kPa (253 g/cm²). AES-Na 16.0 parts Lauric acid diethanolamide 4.0 Microcapsule dispersion 12.0 Preservative, dye, flavor q.s. Purified water balance Example 5-5 Rinse Microcapsules (average particle size 63 µm) enclosing oil components at a ratio of squalane : vitamin E = 95 : 5 (weight ratio) prepared according to the same method as in Example 1, but changing the stirring speed by a homomixer to 1050 rpm, were dispersed to 40% in a solution with a composition of propylene glycol : polyethylene glycol : water = 45 : 5 : 50, and formulated according to the following recipe to obtain a rinse. The breaking strength of the microcapsules taken out of the rinse was found to be 20.7 kPa (211 g/cm²). Stearyl trimethyl ammonium chloride 2.0 parts Cetostearyl alcohol 3.0 Glyceryl monostearate 1.5 Sodium chloride 0.2 Microcapsule dispersion 18.0 Purified water balance Example 5-6 Microcapsules (average particle size 80 µm) enclosing oil components at a ratio of liquid paraffin : vitamin C stearate = 96 : 4 (weight ratio) prepared according to the same method as in Example 1, but changing the stirring speed by a homomixer to 920 rpm, were dispersed to 15% in a solution with a composition of glycerine : sucrose : water = 70 : 5 : 25, and formulated according to the following recipe to obtain a hair cream oil. The breaking strength of the microcapsules taken out of the hair cream oil was found to be 6.1 kPa (62 g/cm²). Liquid paraffin 30.0 parts Microcrystalline wax 3.0 Polyoxyethylene (8 mol) polyoxypropylene (8 mol) 2-octyldodecyl ether 5.0 Butyl benzoate 0.1 Flavor 0.1 Oil component enclosing microcapsules 15.0 Purified water balance The cosmetics formulated with the microcapsules as prepared above were evaluated. The samples used for evaluation were the respective samples of Examples 5-3 - 5-6 and the following Comparative Examples 5-1 - 5-4. The evaluation method was based on the difficulty of escape of capsules, ease of rupture of capsules, ease of leakage of enclosed matter during application, smoothness during application and skin wetness when the respective samples were applied onto the skin on the innerside of the forearm by an overall evaluation, by an organoleptic test, by a panel of 10. The evaluation was divided into 4 rankings: o ○ : very good o : good ▵ : average x : poor Comparative Example 5-1 A formulation of the cream recipe was obtained by replacing propylene glycol and glycerine with an equal amount of water in the solution for dispersion of the microcapsules in Example 5-3. (The breaking strength of the microcapsules taken out of the cream was 109.1 kPa (1113 g/cm².) Comparative Example 5-2 A formulation of a shampoo recipe was obtained by changing the composition for dispersing the microcapsules in Example 5-4 to 1,3-butylene glycol : water = 25 : 75. (The breaking strength of the microcapsules taken out from the shampoo was 48.8 kPa (498 g/cm².) Comparative Example 5-3 A formulation of a rinse recipe was obtained by changing the composition of the solution for dispersing the microcapsules in Example 5-5 to propylene glycol : polyethylene glycol : water = 20 : 5 : 75. (The breaking strength of the microcapsules taken out from the rinse was 52.6 kPa (636 g/cm².) Comparative Example 5-4 A formulation of a foundation recipe was obtained by replacing glycerine and sucrose in the solution for dispersing the microcapsules in Example 5-6 with the equal amount of water. (The breaking strength of the microcapsules taken out from the foundation was 102.6 kPa (1046 g/cm².) Example Comparative Example 5-3 5-4 5-5 5-6 5-1 5-2 5-3 5-4 Difficulty of escape of capsules o ○ o o ○ o ○ x x x x Ease of rupture of capsules o ○ o ○ o ○ o ○ x ▵ ▵ x Ease of leakage of enclosed matter during application o ○ o ○ o ○ o ○ x x x x Smoothness during application (no foreign matter feeling) o ○ o o ○ o ○ x x x x As apparent from Table 5-3, the cosmetics formulated with the capsules controlled to a breaking strength of 1 to 30 kPa (10 to 300 g/cm²) by mixing microcapsules and polyhydric alcohol were found to be more excellent in all of the items, compared with other capsules. Example 6-1 To a solution of 10 g of acid-treated gelatin and 10 g of gum arabic dissolved in 200 g of purified water of 60°C was added 150 g of squalane, and the mixture was stirred by a propeller stirring machine at 600 rpm. Further, 10% aqueous acetic acid was added dropwise to the dispersion to adjust the pH to 4.3, followed by dilution with an addition of 600 g of purified water of 40°C. Subsequently, cooling was effected externally of the vessel while stirring, and 10 g of 25% aqueous glutaraldehyde was added at a liquid temperature of 8°C and the mixture was stirred for 2 hours to harden the capsule film. The product thus obtained was separated from the aqueous phase by decantation, and water washing was repeated, and thereafter, excess water was removed by screening to obtain capsules with an average particle size of 300 µm. After the microcapsules were dispersed to 10% in terms of weight ratio in solutions with seven kinds of compositions of glycerine : water = 0 : 100, 10 : 90, 20 : 80, 30 : 70, 40 : 60, 60 : 40, 80 : 20, and then formulated according to the recipes shown below to prepare cosmetic waters, and the breakage by stirring during preparation and feeling of foreign matter when applied onto the skin were evaluated, by comparison. Also, microcapsules were taken out of the cosmetic water and the breaking strength thereof measured. Microcapsule dispersion 20.0 parts Oleyl alcohol 4.0 Polyoxyethylene (20 mol) sorbitane monolauric acid ester 1.5 Polyoxyethylene (20 mol) lauryl ether 0.5 Ethanol 10.0 Flavor 0.1 Preservative q.s. Purified water balance The respective experiments were conducted according to the following methods. Evaluation of breakage during cosmetic water preparation The breakage of capsules in the cosmetic water prepared according to the above recipe was observed by an optical microscope. The evaluation was divided into three rankings: o : no breakage observed ▵ : slight breakage observed x : all capsules broken Evaluation of feeling of foreign matter upon application to skin The cosmetic waters formulated with the respective capsules were evaluated in the same manner as mentioned above. Take-out of capsules As mentioned above. Method for measuring breaking strength As mentioned above. Glycerine 0 10 20 30 40 60 80 Water 100 90 80 70 60 40 20 Capsule breakage during preparation o o o o o o o Foreign matter feeling during application to skin x x o o o o o Breaking strength of capsules (g/cm² = kPa x 10.2) 984 509 281 158 92 41 18 As shown in Table 6-1, the microcapsules having a breaking strength in the range of 1 to 30 kPa (10 to 300 g/cm²) were found to be excellent in all of the items, compared with other microcapsules. Example 6-2 Microcapsules enclosing a liquid paraffin with an average particle size of 200 µm were prepared according to the same method as in Example 6-1, except that the stirrer was replaced by a homomixer and the stirring speed changed to 650 rpm. The microcapsules were dispersed to 15% in terms of weight ratio in solutions with 7 kinds of compositions of propylene glycol : water = 0 : 100, 10 : 90, 20 : 80, 30 : 70, 40 : 60, 60 : 40, 80 : 20, and then formulated according to the recipe shown below to prepare emollient lotions, and the difficulty of escape of capsules, ease of rupture of capsules, ease of leakage of enclosed matter during application, smoothness during application and skin wetness when the respective samples were applied to the skin on the innerside of the forearm were represented by an overall evaluation, by an organoleptic test, by a panel of 10. The evaluation was divided into 4 rankings: o ○ : very good o : good ▵ : average x : poor The breaking strength of the microcapsules taken out of the gel-like cosmetic water was measured at the same time. Squalane 5.0 parts Petrolatum 2.0 Beeswax 0.5 Sorbitane sesquioleic acid ester 0.8 Polyoxyethylene (20 mol) oleyl ether 1.2 Flavor 0.5 Preservative q.s. Microcapsule dispersion 20.0 Ethanol 5.0 Purified water balance The breaking strength of the microcapsules taken out of the emollient lotion was also measured at the same time. Propylene glycol 0 10 20 30 40 60 80 Water 100 90 80 70 60 40 20 Difficulty of escape of capsules x x ▵ o ○ o ○ o ○ o ○ Ease of rupture of capsules x x o o ○ o ○ o ○ o ○ Ease of leakage of enclosed matter during application x x o o ○ o ○ o ○ o ○ Smoothness during application (no foreign matter feeling) x x ▵ o ○ o #CIR# o ○ o ○ Skin wetness x x o o ○ o ○ o ○ o ○ Breaking strength of capsules (g/cm²) 980 551 328 166 98 44 23 As shown in Table 6-2, the capsules having a breaking strength within the range of 1 to 30 kPa (10 to 300 g/cm²) were found to be excellent in all items, compared with other capsules. Example 6-3 Cream Microcapsules (average particle size 700 µm) enclosing oil components at a ratio of liquid paraffin : vitamin A palmitate = 92 : 8 prepared according to the same method as in Example 1, but changing the stirring speed by a homomixer to 350 rpm, were dispersed to a weight ratio of 40% in a solution with a composition of propylene glycol : glycerine : water = 50 : 20 : 30, and formulated according to the following recipe to obtain a cream. The breaking strength of the microcapsules taken out from the cream was found to be 4.2 kPa (43 g/cm²). Beeswax 2.0 parts Stearyl alcohol 5.0 Stearic acid 8.0 Squalane 10.0 Self-emulsification type propylene glycol monostearate 3.0 Polyoxyethylene cetyl ether (20 EO) 1.0 Preservative, antioxidant q.s. Triethanolamine 1.0 Microcapsule dispersion 20.0 Polyethylene glycol 0.6 Purified water balance Example 6-4 Shampoo Microcapsules (average particle size 500 µm) enclosing oil components at a ratio of dimethylpolysiloxane : liquid paraffin = 60 : 40 (weight ratio) prepared according to the same method as in Example 6-1, but changing the stirring speed by a homomixer to 450 rpm, were dispersed to 25% in a solution with a composition of 1,3-butylene glycol : water = 40 : 60, and formulated according to the following recipe to obtain a shampoo. The breaking strength of the microcapsules taken out from the shampoo was found to be 20.4 kPa (208 g/cm²). AES-Na 16.0 parts Lauric acid diethanolamide 4.0 Microcapsule dispersion 18.0 Preservative, dye, flavor q.s. Purified water balance Example 6-5 Rinse Microcapsules (average particle size 400 µm) enclosing oil components at a ratio of squalane : vitamin E = 95 : 5 (weight ratio) prepared according to the same method as in Example 6-1, but changing the stirring speed by a homomixer to 500 rpm, were dispersed to 40% in a solution with a composition of propylene glycol : polyethylene glycol : water = 45 : 5 : 50, and formulated according to the following recipe to obtain a rinse. The breaking strength of the microcapsules taken out from the rinse was found to be 13.9 kPa (142 g/cm²). Stearyl trimethyl ammonium chloride 2.0 parts Cetostearyl alcohol 3.0 Glyceryl monostearate 1.5 Sodium chloride 0.2 Microcapsule dispersion 18.0 Purified water balance Example 6-6 Microcapsules (average particle size 850 µm) enclosing oil components at a ratio of fluid paraffin : vitamin C stearate = 96 : 4 (weight ratio) prepared according to the same method as in Example 6-1, but changing the stirring speed by a homomixer to 250 rpm, were dispersed to 15% in a solution with a composition of glycerine : sucrose : water = 70 : 5 : 25, and formulated according to the following recipe to obtain a hair cream oil. The breaking strength of the microcapsules taken out of the hair cream oil was found to be 2.3 kPa (23 g/cm²). Liquid paraffin 30.0 parts Microcrystalline wax 3.0 Polyoxyethylene (8 mol) polyoxypropylene (8 mol) 2-octyldodecyl ether 5.0 Butyl benzoate 0.1 Flavor 0.1 Oil component enclosing microcapsules 15.0 Purified water balance The cosmetics formulated with the microcapsules as prepared above were evaluated. The samples used for evaluation were the respective samples of Examples 6-3 to 6-6 and the following Comparative Examples 6-1 to 6-4. The evaluation method was based on the difficulty of escape of capsules, ease of rupture of capsules, ease of leakage of enclosed matter during application, smoothness during application and skin wetness when the respective samples were applied to the skin on the innerside of forearm an overall evaluation, by an organoleptic test, by a panel of 10. The evaluation was divided into 4 rankings: o ○ : very good o : good ▵ : average x : poor Comparative Example 6-1 A formulation of a cream recipe was obtained by replacing propylene glycol and glycerine with the equal amount of water in the solution for dispersion of the microcapsules in Example 6-3. (The breaking strength of the microcapsules taken out from the cream was 49.2 kPa (502 g/cm².) Comparative Example 6-2 A formulation of a shampoo recipe was obtained by changing the composition for dispersing the microcapsules in Example 6-4 to 1,3-butylene glycol : water = 25 : 75. (The breaking strength of the microcapsules taken out from the shampoo was 47.4 kPa (483 g/cm².) Comparative Example 6-3 A formulation of a rinse recipe was obtained by changing the composition of the solution for dispersing the microcapsules in Example 6-5 to propylene glycol : polyethylene glycol : water = 20 : 5 : 75. (The breaking strength of the microcapsules taken out from the rinse was 33.8 kPa (345 g/cm².) Comparative Example 6-4 A formulation of a foundation recipe was obtained by replacing glycerine and sucrose in the solution for dispersing the microcapsules in Example 6-6 with the equal amount of water. (The breaking strength of the microcapsules taken out from the foundation was 41.0 kPa (418 g/cm².) Example Comparative Example 6-3 6-4 6-5 6-6 6-1 6-2 6-3 6-4 Difficulty of escape of capsules o ○ o ○ o ○ o #CIR# x x x x Ease of rupture of capsules o ○ o ○ o ○ o ○ x x ▵ x Ease of leakage of enclosed matter during application o ○ o ○ o ○ o ○ x x x x Smoothness during application (no foreign matter feeling) o ○ o ○ o #CIR# o ○ x x x x As apparent from Table 6-3, the cosmetics formulated with the capsules controlled to a breaking strength of 1 to 30 kPa (10 to 300 g/cm²) by mixing microcapsules and polyhydric alcohol were found to be more excellent in all of items, compared with other microcapsules. Example 7-1 With 600 g of an aqueous solution of 40°C containing 10 g of acid-treated gelatin dissolved therein was mixed 600 g of an aqueous solution of 40°C containing 10 g of gum arabic dissolved therein, and the pH was adjusted to 4.3 by dropwise adding 10% aqueous acetic acid, and then 150 g of water-in-oil type emulsion (W/O type emulsion) prepared according to the following recipe was added, followed by stirring at 400 rpm by a propeller stirring machine. Subsequently, cooling was effected externally of the vessel while stirring, and 10 g of aqueous 25% glutaraldehyde solution was added at a liquid temperature of 8°C, followed by stirring for 2 hours to harden the capsule film. The product thus obtained was separated from the aqueous phase by decantation, and by repeated water washing, capsules with an average particle size of 500 µm with a weight ratio of gelating film and the W/O type emulsion enclosed of 1 : 60 were obtained. Oil Phase Squalane 21.0 (part) Vitamin A palmitate 2.0 Cyclic silicone 5.0 Organic modified clay mineral obtained by treating 0.5 g of bentone-38 with 0.1 g of dimyristoyl lecithin 0.6 Microcrystalline wax 2.0 Butyl parahydroxybenzoate 0.1 Aqueous Phase L-ascorbic acid 2.0 Dipropylene glycol 5.0 Purified water balance Preparation method: While stirring the aqueous phase portion dissolved at 70°C with a disper, the oil phase dispersed by mixing at 70°C was gradually added to be emulsified, followed by cooling. The capsules were formulated according to the following recipe to prepare an O/W type emollient lotion. Oil Phase Squalane 5.0 (part) Petrolatum 2.0 Beeswax 0.5 Sorbitan sesquioleic acid ester 0.8 Polyoxyethylene (20 mole) oleyl ether 1.2 Flavor 0.5 Preservative q.s. Aqueous Phase Microcapsules enclosing W/O type emulsion 10.0 Propylene glycol 5.0 Ethanol 5.0 Carboxyvinyl polymer (1.0% aqueous solution) 20.0 Potassium hydroxide 0.1 Purified water balance Also, as a Comparative Example, an emollient lotion having the same amounts of squalane and vitamin A palmitate as the enclosed amounts in the oil phase and L-ascorbic acid in the aqueous phase without formulation of microcapsules in the above recipe (Comparative Example 7-1) was prepared, and a comparative evaluation with the above Example was conducted of the stability with a lapse of time of the vitamin A palmitate and L-ascorbic acid. The experiments were conducted by storing the vessels containing the respective emollient lotions in a thermostat at 50°C, and the amounts of vitamin A palmitate and L-ascorbic acid remaining after 7, 14, 30 and 60 days were determined. The results are shown in Fig. 2 and Fig. 3. In each figure, the amount immediately after preparation of the emollient lotion is represented as 100%. Example 7-1 shows a slower reduction of vitamin A palmitate and L-ascorbic acid with a lapse of time, and thus shows an excellent in stability. Example 7-2 The W/O type emulsion enclosing microcapsules prepared in Example 7-1 were formulated according to the following recipe to obtain a cream. Oil Phase Squalane 5.0 (part) Reduced lanolin 2.0 Stearic acid 2.0 Stearyl alcohol 7.0 Octyldodecanol 6.0 Polyoxyethylene (25 mole) cetyl ether 3.0 Lipophilic type glycerine monostearate 2.0 Flavor 0.3 Preservative q.s. Aqueous Phase Microcapsules 10.0 Propylene glycol 5.0 Purified water balance The cream was left to stand at room temperature for 10, 30, 60, 120, 180 and 360 days, and the amount of L-ascorbic acid migrated (leaked out) to the outer phase (cream base) of microcapsules was determined. The experiment method was conducted by separating each sample after a lapse of time into the cream base layer and the microcapsule layer by centrifugation at 5000 rpm (with the microcapsule being the upper layer), and quantitatively determining the L-ascorbic acid contained in the cream base. As a Comparative Example, the same investigations were made for the microcapsules of nylon film enclosing L-ascorbic acid (Comparative Example 7-2). The microcapsules of nylon film were prepared by an interfacial polymerization of ethylenediamine and terephthalic acid chloride, as generally practised in the art. The results are shown in Fig. 4, from which it can be seen that Example has a low level of leakage of L-ascorbic acid from the microcapsule for a long term, compared with the Comparative Example.

Claims: A cosmetic composition comprising as essential ingredients (a) capsules composed of a gelatin film swollen with water and having particle sizes of 0.1 to 1000 µm, the capsules enclosing a hydrophobic component therein and having a breaking strength after formation of from 1 to 30 kPa (10 to 300 g/cm²), and (b) a polyhydric alcohol. A cosmetic composition as claimed in claim 1, wherein the capsules have particle sizes of 0.1 to 50 µm. A cosmetic composition as claimed in claim 1, wherein the capsules have particle sizes of 50 to 100 µm. A cosmetic composition as claimed in claim 1, wherein the capsules have particle sizes of 100 to 1000 µm. A cosmetic composition as claimed in claim 2 or 3, wherein the polyhydric alcohol outer phase is in the form of a water-in-oil emulsion. A cosmetic composition as claimed in any of claims 1 to 5, wherein the weight ratio of the hydrophobic component to gelatin is 1:0.01 to 1:10. A cosmetic composition comprising gelatin capsules enclosing a hydrophobic component therein, the capsules being in an aqueous phase containing a water-soluble polymer, the weight ratio of the hydrophobic component to gelatin being 1:10 to 100:1, the average particle size of the gelatin capsules being 100 to 1000 µm and the viscosity of the system being 1000 to 20,000 mPa s (cps). A cosmetic composition as claimed in any one of claims 1 to 7, where said hydrophobic component is in the form of a liquid oil, a solid oil, a water-in-oil emulsion, or any mixture thereof. A cosmetic composition as claimed in any one of claims 1 to 8, wherein said microcapsules are formable according to a complex coacervation of gelatin by a method which comprises previously mixing mutually aqueous solutions of gelatin having positive and negative opposite charges to form a complex coacervate and then successively adding several different kinds of hydrophobic component, to thereby obtain microcapsules containing separate hydrophobic components at the same time in one step. A cosmetic composition as claimed in any one of claims 1 to 8, wherein said microcapsules are formable according to a simple coacervation of gelatin by a method which comprises previously adding to an aqueous solution of gelatin an electrolyte or a non-solvent for gelatin to form a simple coacervate, and then successively adding several different kinds of hydrophobic component, to thereby obtain microcapsules containing separate hydrophobic components at the same time in one step.

Inventors: AIZAWA, MASANORI, KUMANO, YOSHIMARU, NODA, AKIRA, YAMAGUCHI, MICHIHIRO
Applicants: SHISEIDO COMPANY LIMITED
Application year: 1988
Main classification: A61K9
IPC codes: A61Q5, A61Q19, A61K8, A61Q1