A METHOD OF DECONTAMINATING A LOCATION CONTAINING PYROPHORIC TETRAATOMIC PHOSPHORUS CONTAMINATION

Abstract: A method of decontaminating a location containing pyrophoric P₄-contamination is described. It comprises bringing to the location a portable vehicle which comprises at least one of the necessary items needed to accomplish the contacting of the P₄-contaminated material, while it is under a protective blanket of a nonflammable fluid, with an oxygen-containing gas, such as air, pure oxygen, or mixtures thereof. The portable vehicle may contain, for example, a scrubber, a source of oxygen, a pump, means to convey the oxygen-containing gas to the P₄-contaminated material, and means to convey any effluent resulting from the treatment to suitable recovery or treatment apparatus.

Description: This invention relates to a method of decontaminating a location containing pyrophoric P₄-contamination. Our EP-A-87306749.0 describes a method whereby pyrophoric P₄-containing material can be converted to a substantially less pyrophoric form while it is under a suitable blanketing layer of a nonflammable fluid (e.g., water or inert gas) with an oxygen-containing gas such as air, pure oxygen, or mixtures thereof. The action of the oxygen on the P₄-containing material while it is being blanketed with the nonflammable liquid reduces the pyrophoric nature of the P₄-material over time rendering it substantially less pyrophoric. Details concerning how the conversion of the pyrophoric P₄-material to a less pyrophoric form can be conducted in accordance with the invention described in that copending application are incorporated herein by reference. SUMMARY OF THE PRESENT INVENTION The present invention relates to a procedure for decontaminating a location which happens to contain pyrophoric P₄-contamination by the general process outlined in the above-mentioned copending application. The process is particularly directed to situations where the P₄-contamination is in a location such that it is inconvenient to transport the contaminated materials at the location to a suitable reactor to practice the process used in the foregoing, cross-referenced application. Hence, the present process comprises bringing to the location containing the P₄-contamination a portable vehicle which comprises at least one of the components needed to practice the aforementioned process. Included among these components is a scrubber, a source of oxygen, a pump, means to convey oxygen to the P₄-contaminated material, while such material is under a protective blanket of a nonflammable fluid, and means to convey the effluent resulting from the oxygen treatment of the P₄-contaminated material while it is blanketed with the nonflammable fluid to suitable treatment or recovery means. DESCRIPTION OF THE DRAWINGS The present invention will be more fully understood by reference to the drawings which form a portion of the present Specification wherein: Fig. 1 is a side view of a suitable portable vehicle for use in conjunction with the present method; and Fig. 2 is an overhead view of the type of portable vehicle shown in Fig. 1. DETAILED DESCRIPTION OF THE PRESENT INVENTION The present invention involves the decontaminating of a location containing pyrophoric P₄-contamination which comprises bringing to the location a portable vehicle which contains at least one of the necessary components for practicing the type of process described in the copending application. It is necessary and essential in regard to that process that the P₄-contaminated material is under an appropriate blanket of a nonflammable fluid, such as water, when the treatment with the oxygen-containing gas is used. In cases in which the pyrophoric P₄-containing material is in appropriate storage tanks or ponds already covered with water, a source of water need not be provided. In situations in which the P₄-contaminated material is buried underground, it may be necessary to flood the area prior to treatment with the oxygen-containing gas in order to avoid contact of air with the P₄-containing material which would give rise to spontaneous fire hazards. The type of apparatus shown in Figs. 1 and 2 is merely representative of one type of apparatus that can be used. It is to be understood that the environment in which the P₄-containing material is placed will largely dictate what particular components the portable vehicle needs to have thereon. A wide variety of portable vehicles can be used in conjunction with the present method including wheeled vehicles, such as trucks and railcars, and these vehicles can be transported to the job site over roads, over rails, or by air, or by a combination of these transportation methods. Fig. 1 illustrates a potential configuration for various components on a portable vehicle to be used in conjunction with the present invention. For example, a suitable gib crane 11 can be provided for the purpose of lifting and moving various components about, a scrubber 12 can be provided to effectively treat the effluent gases resulting from the process, and an oxygen tank 13 can also be provided to give a source of oxygen for use in the process. The oxygen-containing gas which is preferably employed with the method is substantially pure oxygen. If desired, a fabrication shop and material storage area 14 can also be provided on the portable vehicle. Other items which can be present include a circulating pump 15, an additional storage area 16, a boiler 17, and a generator 18.

Claims: 1. A method of decontaminating a location containing pyrophoric P₄-contamination which comprises: (1) bringing to said location a portable vehicle which comprises at least one of the following: a scrubber, a source of an oxygen-containing gas, a pump, means to convey an oxygen-containing gas to the P₄-contaminated material, when said material is under a protective blanket of a nonflammable fluid, and means to convey the effluent resulting from the treatment of said P₄-contaminated material with an oxygen-containing gas, while it is blanketed with a nonflammable fluid, to either suitable treatment or recovery means; and (2) contacting the P₄-contamination, while it is under a protective blanket of a nonflammable fluid, with an oxygen-containing gas to thereby render it less pyrophoric. 2. A method as claimed in Claim 1 wherein the vehicle is a wheeled vehicle. 3. A method as claimed in Claim 1 wherein the oxygen-containing gas is substantially pure oxygen. 4. A method as claimed in Claim 1 wherein the nonflammable fluid is water and the oxygen-containing gas is substantially pure oxygen.

Inventors: BIEDERMAN, DAVID L., ROBERTS, AUSTON K., TRAINER, WILLIAM EDWARD
Applicants: RHONE-POULENC BASIC CHEMICALS CO.
Application year: 1988
Main classification: A62D3
IPC codes: A62D3, A62D101