Process of producing thermoplastic resin sheet and equipment therefor

Abstract: This invention relates to a process of producing a thermoplastic resin sheet and the like and a an equipment. The equipment includes a first extruder (3) of a high kneading type, a second extruder (5) of a low kneading type and an extrusion die (30). A film-shaped resin extruded from the extrusion die (30) is cooled by a cooling device (20), to thereby obtain the resin sheet (38) and the like. Furthermore, a difference between pressures at the outlets of the first and second extruders is detected, and, in response to this difference between the pressures thus detected, the operating conditions of the first extruder are automatically controlled.

Description: BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to a process of producing a resin sheet, from thermoplastic resin and to an equipment therefor. 2. Description of the Prior Art Crystalline thermoplastic resin such as polypropylene and polyethylene has been utilized in the various packaging fields and the like as sheets and containers due to its easiness in thermoforming process. In producing the crystalline thermoplastic resin sheet and the like represented by the polypropylene and the like as described above, to improve the transparency of this sheet, there has been practiced that the molten resin sheet (melt web) is quenched to control the crystalline structure. As a quenching process of this type, water cooling is the most efficient process. However, this process presents such a problem that it is difficult to cool uniformly a molten film-shaped resin (melt web) extruded from an extrusion die. Then, the inventors of the present invention have proposed a process of using a multi-stage slit, through which cooling water flows down, as the process of uniform water-cooling the molten film-shaped resin (Japanese Patent Kokai (Laid-Open) No. 58-203018). However, even if the cooling conditions and the like are controlled, the cooling effect thereof is naturally limited, whereby the transparency, surface uniformity and the like of the resin sheet, etc., as the molded items have not always been satisfactory. Then, as the result of the various studies conducted by the inventors of the present invention, it was found that conditions of extrusion give a great influence to a stage of molten film-shaped resin, where the molten film-shaped resin extruded is not yet coming into contact with the cooling water, i.e. at a stage covering a range from feeding a material to a resin extruder to an extrusion die. Based on this, a process of using an extruder provided at the forward end portion thereof with a stress relaxing section as one of the above-described conditions of extrusion is devised, and a process, in which the above-described conditions of extrusion are combined with a slit water cooling method in use, has been proposed (Patent Kokai (Laid-Open) No. 62-146611 and Patent Application No. 61-202146). These processes are outstanding ones, but, present such disadvantages that selection of the devices is limited, and it is difficult to combinedly satisfy the kneading properties (extensive mixing, dispersing), stress relaxing properties and extrusion stability. To solve the problems between the kneading properties and stress relaxing properties, and between the high speed molding properties and low temperature extrusion properties, there has been known a tandem extruder (cascade extruder) constituted by two extruders (Patent Kokai (Laid-Open) No. 59-5044). This tandem extruder is constructed such that a first and a second extruders are serially connected to each other through a connecting pipe, and pressure detectors are provided on an outlet side of the second extruder and the connecting pipe, respectively, whereby the screw speed of the first extruder is controlled so that a difference between pressures detected by these pressure detectors can be held at a predetermined relationship. With the above-described tandem extruder, in general, there are offered the advantages that the extruders can be designed such that the first extruder performs plasticization and kneading of the resin and the second extruder carries out mixing (distribution) resin temperature uniformity and metered extrusion, to thereby meet the respective functions of the extruders. However, the first extruder mainly aims at the plasticization and kneading, but, in actuality, the dispersing properties, kneading properties, resin temperature uniformity properties and the like cannot be expected so much therefrom. For this reason, the resin is extruded from the outlet of the first extruder in a state where the kneading (dispersion) and resin temperature uniformity are unsatisfactory, and, in order to produce a satisfactory sheet, it is necessary to further carry out the dispersion, kneading (dispersion), mixing (distribution) and resin temperature uniformity in the second extruder. Accordingly, in the second extruder, shear stress and resin temperature become high, with the result that the resin being low in temperature and low in residual stress cannot be extruded, so that a sheet being excellent in transparency and glossiness, etc. cannot be obtained. From US-A-3 148 231, a process for producing a thermoplastic resin sheet is known comprising the steps of kneading the thermoplastic resin in a first extruder of a high kneading type, extruding the thermoplastic resin in a molten state, supplying the molten resin to a second extruder of low kneading type through a connecting pipe and extruding a molten film-shaped resin from said second extruder through a die located at the outlet of said second extruder. Furthermore, from this document there is also known an apparatus for producing a thermoplastic resin sheet comprising a first extruder, a second extruder serially connected to said first extruder through a pipe means located between said two extruders and a die provided on the extrusion side of said second extruder through which a molten film-shaped resin is extruded. The object underlying the present invention is the provision of a process and an apparatus therefore, wherein while satisfactory kneading (dispersion), mixing (distribution) and resin temperature uniformity of thermoplastic resin is secured, stress is relaxed at a low temperature, extrusion is carried out at high speed so that molded items being of high quality and excellent in characteristics such as transparency, can be produced daily and with high productivity. This object is achieved by the characterising features of claim 1 and claim 5, respectively. The producing process according to the present invention has been based on the facts that the transparency of the resin sheet is varied depending on a water-cooled state of the molten film-shaped resin and the limit of the water cooling effect is closely associated with conditions of extrusion at a stage of resin extrusion. While water cooling of the molten film-shaped resin is carried out such that the molten film-shaped resin is introduced and made to run through a slit, at the inlet of which the cooling water does not substantially stagnate, as the conditions of extrusion, kneading and stress relaxing are satisfactorily carried out. In order to achieve the satisfactory kneading and stress relaxing by use of one extruder, a special screw construction is needed, whereby the scope of selection of the device is limited. For this reason, according to the present invention, an extruder aiming at the satisfactory plasticization and kneading is separated from another extruder aiming at the satisfactory stress relaxing, whereby, without limiting the scope of selection of the equipment, a thermoplastic resin sheet having the satisfactory optical characteristics is obtainable. In consequence, in the producing process according to the present invention, to carry out satisfactory plasticization and kneading, a first extruder of a high kneading type having a compression ratio of 2 or more, preferably 3 or more, for example, is used, while, to perform the satisfactory stress relaxing, a second extruder of a low kneading type having a steady extrusion function of a compression ratio of less than 2, preferably 1.5 or less, and normally, a compression ratio of about 1, for example, is used. With the above-described arrangement, in the first extruder, thermoplastic resin is kneaded into a molten state, which is extruded through a connecting pipe into the second extruder, where, while the satisfactory stress relaxing is carried out, the resin is extruded from a die as a molten film-shaped resin having the excellent surface characteristics, and this molten film-shaped resin is introduced into a slit, through which the cooling water co-currently flows down without stagnating at the inlet of the slit, so as to cool said molten film-shaped resin, to thereby improve the optical characteristics such as the transparency. In the producing process according to the present invention, the kneading of said thermoplastic resin comprises kneading in a molten resin uniform kneading section which is provided in the intermediate portion and/or on the forward end portion of the screw of said first extruder. The equipment or apparatus for producing a thermoplastic resin sheet according to the present invention comprises a cooling device for cooling said molten film-shaped resin, said cooling device being provided with at least one slit through which said molten film-shaped resin passes and through which cooling water co-currently flows so as to cool said molten film-shaped resin. The first extruder according to the present invention is of the high kneading type and has a compression ratio of 2 or more and the second extruder is of the low kneading type and has a compression ratio of less than 2 and the molten resin uniform kneading section is formed of a torpedo, a Dulmage or the like which is provided in the intermediate portion and/or on the forward end portion of the screw of said first extruder. Further advantages and preferred embodiments of the present invention are described in the sub-claims. Preferrably, a gear pump is provided between the first and second extruders. In this case, even if the plasticised resin partially, more or less unsatisfactorily kneaded is present, the plasticised resin is satisfactorily and uniformily kneaded by rotation of the gear pump and pumped. out a constant flow rate. Furthermore, due to the operation of this gear pump, fluctuations in pressure at the outlet of the first extruder is minimized and control of screw speed of the first extruder comes to be easy. Subsequently, the molten resin is supplied to the second extruder, where the satisfactory stress relaxation, uniformity of the resin temperature, and further, cooling of the resin temperature are performed as necessary, the molten resin is extruded from the die, and the molten film-shaped resin thus extruded is cooled through the cooling device. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a general arrangement diagram showing a system constituted by an extrusion unit and a cooling device, which are applied to one embodiment of a process of producing a thermoplastic resin sheet according to the present invention; Fig. 2 is a sectional view showing an example of the first extruder used in the extrusion unit; Fig. 3 is a sectional view showing an example of the second extruder used in the extrusion unit; Fig. 4 is a sectional view partially showing a modification of the second extruder; and Fig. 5 is an arrangement diagram showing the extrusion unit other than the above. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT One embodiment of the present invention will hereunder be described with reference to the accompanying drawings. First, what fall under the thermoplastic resins used in the present invention are polypropylene group resins such for example as a homopolymer of propylene, a random copolymer of propylene with another α-olefin of 20 weight % or less, and a blend of these. A blend obtainable by multi-stage polymerization is included in this blend. Other thermoplastic resins utilized in the present invention include polyethylene group resins, a mixture of polypropylene group resins with polyethylene group resins or elastomer, polyester, polyamide and the like. Further, the resin analogous to the above-described resins such as maleic anhydride can be applied to a co-extrusion multi-layer sheet to be formed with adhesive resin such as graft-denatured polyolefin resin, easily welding resin such as a copolymer of ethylene-vinyl acetate, and gas barrier resins such as a copolymer of ethylene-vinyl alcohol, polyamide and polyethylene terephthalate. Fig. 1 shows the general arrangement of the system provided with an extrusion unit 1 and a cooling device 20. Referring to the drawing, the extrusion unit 1 includes a first extruder 3 being of a high kneading type, having a single or double screw shafts and provided with a hopper 2 for feeding the resin, and a second extruder 5 being of a low kneading type, having a single screw shaft and serially connected to the outlet side of the first extruder 3 through a connecting pipe 4. The first extruder 3 plasticizes resin pellets fed from a hopper 2 and rotationally drives a screw through a motor M₁ for driving the screw and a speed reducer 7 (provided that the motor is directly connected, the speed reducer may be dispensed with), so that the molten resin can be plasticized, kneaded (dispersed). In the second extruder 5, stress of the molten resin kneaded by the first extruder 3 is relaxed, so that a resin sheet being excellent in the characteristics of quality such as the transparency can be extruded at high speed. This second extruder 5 is provided with a motor M₂ and a speed reducer 9 similarly to the first extruder 3. An extrusion die 30 is connected to the outlet side of the second extruder 5 through a gear pump 10 for pumped out a constant flow rate. In the second extruder 5, the screw and/or a cylinder is regulated in temperature by use of a heat transfer medium for example, so that the resin temperature can be lowered. Pressure detectors P₁ and P₂ are provided in the intermediate portion of the connecting pipe 4 to connect the first extruder 3 to the second extruder 5, and between the second extruder 5 and the gear pump 10, respectively. Pressure values detected by these pressure detectors P₁ and P₂ are delivered to a controller C, which, in response to the detected results, controls speed of the motor M₁ for driving the screw of the first extruder 3. In this case, control of the motor M₁ by the controller C is performed such that a difference of (a value detected by the pressure detector P₂) - (a value detected by the pressure detector P₁) should be maintained at a constant value. The cooling device 20 includes: a top stage water tank 33 having a slit 31, through which the cooling water for quenching a molten film-shaped resin 38 flows down, and porous flow regulating members 32 for preventing stagnation of the cooling water at an inlet of the slit 31 to smooth the flow; a bottom stage water tank 36 positioned at a stage downwardly of the top stage water tank 33 and having a slit 35 positioned immediately beneath the slit 31; a water tank 37 positioned further downwardly of the bottom stage water tank 36; clamping rolls 39 and 40 for clamping a cooled film-shaped resin 48 under pressure to maintain the running speed of the film-shaped resin 48 at a constant value; rolls 41 and 42 for taking up the film-shaped resin 48 passed through the water tank 37; a group of rolls 43 for heat-treating (annealing) the film-shaped resin 48 in a predetermined manner; and a pump 45 for circulating the cooling water, which has flowed down through the water tank 37 to be cooled by a cooler 44, through the top stage water tank 33 and the bottom stage water tank 36. In the cooling device 20, the molten film-shaped resin 38 extruded from the extrusion die 30 is introduced into the slits 31 and 35 of the top stage water tank 33 and the bottom stage water tank, through which the cooling water flows down, passed through the cooling water in the water tank 37 through the clamping rolls 39 and 40, taken up by the take-up rolls 41 and 42, and thereafter, heat-treated in the predetermined manner by the group of rolls 43 as necessary, to thereby complete the molding of the resin sheet. In this case, the flow-down speed of the cooling water from the slits 31 and 35 is made larger than the running speed of the molten film-shaped resin 38, whereby the quantity of the cooling water being in contact with the molten film-shaped resin 38 is increased, so that the cooling effect can be improved. The cooling water is prevented from stagnating at the inlet of the slit 31 when the cooling water flows into the top stage slit 31. For this purpose, the water level in the top stage water tank 33 is needed to be held low. If the stagnation takes place, then, ununiform cooling of the molten film-shaped resin occurs, so that the sheet being low in haze on the outer surface thereof cannot be obtained. Fig. 1 has shown a preferable case of the cooling in the two-stage slits, however, the top stage slit 31 suffices depending on the thickness of the sheet or the like, the molding speed, etc. Fig. 2 shows one example of the first extruder 3 having a single shaft as used in this embodiment. This extruder 3 includes: a cylinder 13 having the hopper 2 and a filter 12; and a screw 14 provided in this cylinder 13. As the screw 14 of the first extruder 3, there is no limit in its form and the like in particular, for example, there may be adopted a commonly used screw of the high kneading type having a resin feed section, a compression section and a metering section. As necessary, a portion for facilitating the kneading or mixing such as a torpedo or a Dulmage head may be provided in the intermediate portion and/or the forward end portion of the screw. The specifically, in the first extruder 3, there is no need of lowering the residual stress of the resin in particular, the uniform kneading and extrusion at high speed will suffice, and the screw of high compression and at high shear rate is commonly used. The screw 14 is provided at the forward end thereof with a uniform kneading improving section 15 formed of a torpedo, whereby, as the screw 14 rotates, the resin pellets fed from the hopper 2 are satisfactorily kneaded while being plasticated, passed through the filter 12 by a propulsive force of the screw 14 and delivered under pressure to the connecting pipe 4. In the first extruder 3 of the high kneading type, the channel depth of the screw 14 is progressively made smaller from the side of the resin supply to the side of the resin extrusion, whereby the compression ratio is increased. This compression ratio is made 2 or more and preferably 3 or more, so that the molten resin can be satisfactorily kneaded by the first extruder 3. In this case, if the compression ratio is less than 2, then, it is not preferable because unnecessary stagnation of the resin is caused and insufficient kneading at the beginning occurs. Any type of the screw 14 may be adopted, i.e. either a type having a equi-pitch (a typical single flighted square pitch) and a varied channel depth or a type having a constant channel depth and a varied pitch is usable. The uniform kneading improving section 15 may be the aforesaid torpedo or a modified torpedo which is a Dulmage head formed at the peripheral surface thereof with axial channels, where resistance is given to the flow of the resin, so that uniform plasticizing and kneading of the resin are performed by shearing. A clearance formed between this uniform kneading improving section 15 and the inner wall of the cylinder 13 is made small, so that a high shear rate can be obtained. For example, when the torpedo is used, the length of the uniform kneading improving portion 15 is 0.1 - 2 times the diameter D of the screw and preferably 0.2 - 1.5 times. The clearance between the torpedo and the cylinder 3 may be 0.1 - 6mm and preferably 0.3 - 4mm, for example. Although a clearance formed between the torpedo and the cylinder wall is varied specifically depending on the length of the torpedo portion, the clearance should be 1/150 - 1/20 and preferably 1/100 - 1/30 times the diameter D of the screw. However, it is necessary to select the optimal ones as the above-described values in accordance with the type of the resin, lengths of the sections and the like. In this case, when the uniform kneading improving section 15 is a torpedo, the construction is the simplest. Fig. 3 shows one example of the second extruder 5 used in this embodiment. This second extruder 5 includes: a cylinder 17 having a filter 16; and a screw 18 provided in this cylinder 17. As the screw 18, the one of moderate (low) compression and low shear rate, having a relatively deep channel depth is used. This screw 18 is rotatably driven by the motor M₂ through the speed reducer 9, as the screw 18 rotates, the molten resin fed through the connecting pipe 4 and satisfactorily kneaded is passed through the filter 16 by the propulsive force of the screw 18 while being relaxed in stress, delivered to the gear pump 10, where the extrusion flow rate is made constant, and the molten resin is extruded by the die to form the molten film-shaped resin 38. The screw 18 of this second extruder 5 of the low kneading type had the compression ratio of less than 2, and preferably 1.5 or less. Normally, a straight screw of the compression ratio 1 is used, and further, the one of the compression ratio 0.5 may be adopted. Metering of the molten resin (regulation of the discharge flow rate) is performed and shear stress remaining in the molten resin is relaxed, and further, cooling of the molten resin is made uniform as necessary. In this cooling for example, the cylinder 17 and the screw 18 are forcedly cooled. Removal of residual shear stress is mainly aimed by this second extruder 5, in which high kneading and high shear rate do not take place. There is no particular limit on a ratio L/D between the total length L and the diameter D of the screw in the first and second extruders 3 and 5, and it is designed that L/D in the first extruder 3 is 10 - 30 and L/D in the second extruder 5 is 5 - 40. Furthermore, in the first and second extruders 3 and 5, the screw diameter of the first extruder 3 is relatively small and that of the second extruder 5 is relatively large screw speed of the first extruder 3 is large and that of the second extruder 5 is small, and further, the molding temperature including the screw shear, namely an amouont of heat by viscous dissipation of the first extruder 3 is high and that of the second extruder 5 is low. The second extruder 5 may adopt the construction shown in Fig. 4 for example. In the second extruder 5 shown in Fig. 4, an extended cylinder 19 is flange-to-flange connected to the forward end of the cylinder 17, whereby a non-kneading section 21 having no screw is formed on the forward end of the screw 18, so that shear stress of the resin can be satisfactorily relaxed more than ever. The compression ratio described in this specification means "(channel depth at the resin flow-in end) / (channel depth at the resin extrusion end)" in the case where the pitch of screw is constant in respective construction portions. Action of this embodiment will hereunder be described. The resin pellets fed from the hopper 2 are satisfactorily kneaded while being plasticated by the rotation of the screw 14, and thereafter, fed into the cylinder 17 of the second extruder 5. In this second extruder 5, the molten resin is relaxed in stress, and thereafter, fed to the gear pump 10 where the flow rate of the molten resin is set at a constant value, through the filter 16. In this case, the motor M₁ of the first extruder 3 is controlled to take a suitable operating balance by the speed controller C. More specifically, outlet pressures of the first and second extruders 3 and 5 are detected by the pressure detectors P₁ and P₂ and speed of the motor M₁ of the first extruder 3 is controlled such that the difference between these pressures detected becomes constant. The molten film-shaped resin 38 extruded from the extrusion die 30 is passed by the take-up operation of the rolls through the slits 31, 35 and the water tank 37, in which the cooling water flows down, so that the resin characteristics such as the transparency can be improved. According to this embodiment with the above-described arrangement, for extruding the molten film-shaped resin 38, the extrusion unit is divided into two including the first extruder 3 of the high kneading type which aims at the uniform plasticizing and kneading and the second extruder 5 of the low kneading type which aims at the stress relaxing, whereby, without using one extruder provided with the screw of the special shape, the extrusion stability can be improved and the best designs in accordance with the aims can be rendered to the extruders 3 and 5, so that the selectivity of the systems can be widened and the scope of selection of the operating conditions can be widened. Furthermore, incompatible problems raised between the kneading properties and the stress relaxing and between the high speed molding properties and the low temperature extrusion can be solved simultaneously and the stable molding at high speed can be realized, so that low manufacturing cost and energy saving can be achieved. The kneading properties are satisfactory and the stress is relaxed satisfactorily, whereby the sheet being excellent in the surface characteristics can be extruded, so that the sheet being satisfactory in the optical characteristics such as the transparency and glossiness can be obtained in cooperation with the quick and satisfactory cooling by the cooling device. Fig. 5 shows another embodiment of the system for producing the thermoplastic resin sheet with the cooling device being omitted. Referring to this drawing, such an arrangement is adopted that a gear pump 23 is provided in the intermediate portion of the connecting pipe 4 for connecting the first extruder 3 to the second extruder 5, whereby the gear pump 23 is controlled by a controller C₁ such that a difference in pressures detected by the pressure detector P₁ provided on the outlet side of this gear pump 23 and the pressure detector P₂ provided on the outlet side of the second extruder 5 becomes constant. Furthermore, a pressure detector P₃ is provided between the first extruder 3 and the gear pump 23, so that the speed of motor M₁ can be regulated through a controller C₂ such that a pressure value detected by the pressure detector P₃ is maintained at a predetermined value. Further, a filter 24 is provided between the outlet of the second extruder 5 and the gear pump 10. When the above-described arrangement is adopted, the gear pump 23 is provided between the first extruder 3 and the second extruder 5, whereby, even when the insufficiently kneaded a little resin remains in the extrudate from the first extruder 3, complete kneading can be achieved by the gear wheel rotation of the gear pump 23, so that such an advantage can be added that the problem of unkneaded resin being fed to the second extruder 5 can be obviated. Accordingly, the molding stability and transparency of the resin extruded from the second extruder 5 are not affected at all. The controller C₁ controls the speed of gear pump 23 such that the difference between the pressures of the pressure detectors P₁ and P₂ becomes constant, so that the first and second extruders 3 and 5 can be regulated automatically and in association with each other. Further, such an arrangement is adopted that a pressure detector P₃ is provided in front of the gear pump 23, i.e. on the outlet side of the first extruder 3, whereby the controller C₂ controls the speed of motor M₁ to control a pressure value thus detected to a predetermined value, so that the operating conditions of the first extruder 3 can hold the delivery of the molten resin to the gear pump 23 at a predetermined requirement. Incidentally, the number of the gear pump 23 provided on the connecting pipe 4 between the first and second extruders 3 and 5 need not necessarily be limited to one and may be two or more. Further, the number of devices other than the extruders 3 and 5 need not necessarily be limited to one in the arrangement as shown. For example, the gear pump 10 provided on the outlet side of the second extruder 5 is not necessarily required, and, as necessary, a static mixer may be provided on the outlet side of the second extruder 5. An extrusion example The raw material resin was homopolypropylene (density: 0.91g/cm³, MI(Melt Index): 2g/10min, manufactured by Idemitsu Petrochemical Co., Ltd., trade name: IDEMITSU POLYPRO F200S). The melt web was extruded from a T-die by use of an extrusion equipment having the following screws under the condition of resin termperature of 240°C and die temperature of 250°C. First extruder diameter D=65mm L/D=24 compression ratio 3.5 screw speed 680 r.p.m. Second extruder diameter D=90mm L/D=26 compression ratio 2.0 screw speed 120 r.p.m. Option: Gear pump provided between the first and second extruders. gear pump speed 14 r.p.m. Extrusion flow rate 290kg/h The melt web was the excellent transparency. The present invention with the above-described arrangement can offer the advantages of providing a process of producing the thermoplastic resin sheet and an equipment therefor, in which the system having wide selectivity can be used and the thermoplastic resin sheet having more improved transparency and glossiness can be produced than in the past.

Claims: A process for producing a thermoplastic resin sheet comprising the steps of: kneading the thermoplastic resin in a first extruder (3) of a high kneading type; extruding the thermoplastic resin in a molten state; supplying the molten resin to a second extruder (5) of a low kneading type through a connecting pipe (4); extruding a molten film-shaped resin from said second extruder (5) through a die located at the outlet of said second extruder (5); characterized by introducing said molten film-shaped resin through at least one slit (31) at an inlet of which a cooling water is so co-currently flowed through the slit (31) for preventing a stagnation of the cooling water, so that said molten film-shaped resin is cooled, in that said first extruder (3) of the high kneading type has a compression ratio of 2 or more and said second extruder (5) of the low kneading type has a compression ratio of less than 2, and that said kneading of said thermoplastic resin comprises kneading in a molten resin uniform kneading section which is provided in the intermediate portion and/or on the forward end portion of the screw (18) of said first extruder (3). A process for producing a thermoplastic resin sheet as set forth in claim 1, characterized by supplying the molten resin and introducing same into a gear pump (23) in which the molten resin is additionally kneaded. A process of producing a thermoplastic resin sheet as set forth in claim 1 or 2, wherein said first extruder (3) has a compression ratio of 3 or more and the second extruder (5) has a compression ratio of 1.5 or less. A process for producing a thermoplastic resin sheet according to one of the claims 1 to 3, wherein pressures at the outlets of said first (3) and second (5) extruders are detected, respectively, and a screw speed of said first extruder (3) is controlled in response to the results of detections. An apparatus for producing a thermoplastic resin sheet comprising: a first extruder (3); a second extruder (5) serially connected to said first extruder (3) through a pipe means (4) located between said two extruders; a die provided on the extrusion side of said second extruder (5) through which a molten film-shaped resin is extruded; characterized by a cooling device for cooling said molten film-shaped resin, said cooling device being provided with at least one slit (31) through which said molten film-shaped resin passes and through which cooling water co-currently flows so as to cool said molten film-shaped resin, in that said first extruder (3) of the high kneading type has a compression ratio of 2 or more and said second extruder of the low kneading type has a compression ratio of less than 2, and that a molten resin uniform kneading section formed of a torpedo, a Dulmage head or the like is provided in the intermediate portion and/or on the forward end portion of the screw (18) of said first extruder (3). An apparatus for producing a thremoplastic resin sheet as set forth in claim 5, wherein said first extruder (3) has a compression ratio of 3 or more and said second extruder (5) has a compression ratio of 1.5 or less. An apparatus for producing a thermoplastic resin sheet as set forth in claim 5, wherein said first and second extruders (3,5) each include a screw (14,18) and a cylinder (13,17), and a ratio L/D between the total length L and the diameter D of the screw (14) of said first extruder (3) is 10-30 and a ratio L/D between the total length L and the diameter D of the screw (18) of said second extruder (5) is 5-40. An apparatus for producing a thermoplastic resin sheet as set forth in claim 7, wherein a clearance formed between said uniform kneading section and said cylinder is 1/150 - 1/20 times the diameter of said screw. An apparatus for producing a thermoplastic resin sheet as set forth in claim 5, wherein pressures at the outlets of said first (3) and second (5) extruders are detected, respectively, and a screw speed of said first extruder (3) is controlled in response to the results of detections. An apparatus for producing a thermoplastic resin sheet as set forth in one of the claims 5 to 9 wherein at least one gear pump (23) is provided between said first and second extruder (3,5). An apparatus for producing a thermoplastic resin sheet as set forth in claim 10, wherein pressure detectors are provided between said gear pump (23) and said second extruder (5), and at the outlet of resin extrusion of said second extruder (5) and further, a controller (4) maintaining a difference between pressures detected by said pressure detectors at a constant value is provided.

Inventors: FUJII ATSUSHI C O IDEMITSU PET, TAKUBO TOYOKAZU IDEMITSU PETRO, FUJII, ATSUSHI C/O IDEMITSU PETROCHEMICAL CO. LTD., TAKUBO, TOYOKAZU IDEMITSU PETROCHEMICAL CO. LTD.
Applicants: IDEMITSU PETROCHEMICAL CO, IDEMITSU PETROCHEMICAL CO. LTD.
Application year: 1988
Main classification: B29C47
IPC codes: B29C47