PROCESS FOR THE CONVERSION AND WORKING UP OF A MIXTURE OF ORGANIC MATTER, ANORGANIC MATTER AND WATER TO A NEARLY DRY PRODUCT, AS WELL AS AN INSTALLATION FOR THE EXECUTION OF THE PROCESS AND APPLICATION THEREOF BY THE CONVERSION OF MANURE SLURRY

Abstract: Process for the conversion and working up of a mixture of organic matter, anorganic matter and water to a nearly dry product, whereby the mixture is contacted with an oxygen containing gas and put to reaction in a reaction section (9) at temperatures between 200 and 320 degrees Celsius, pressures between 40 and 125 bar and reaction times between 300 and 5400 seconds. After reaction the mixture and gas are separated on the one side in a slurry phase and on the other side water vapour containing gas-phase. The heat in the latter is used for heating of the mixture and for evaporation of water from the slurry phase. Therefor the latter is led to an evaporation section, which is equipped with evaporation means and which may consist of various units, of which at least one unit contains a fluidized bed (16). Organic matter and inorganic matter, emanated from the slurry phase are caught in this bed. The evaporation section is operated at lower temperatures and pressures than the temperature and pressure of the slurry phase and gas phase immediately after reaction. Parts of the fluidized bed mass are discharged periodically or continuously as a nearly dry matter.

Description: PROCESS FOR THE CONVERSION AND WORKING UP OF A MIXTURE OF ORGANIC MATTER, ANORGANIC MATTER AND WATER TO A NEARLY DRY PRODUCT, AS WELL AS AN INSTALLATION FOR THE EXECUTION OF THE PROCESS AND APPLICATION THEREOF BY THE CONVERSION OF MANURE SLURRY. The invention relates to a process for the conversion and working up of a mixture of organic matter, anorganic matter and water to a nearly dry product, which in case of the conversion of manure slurry can be used as a high value natural fertilizer .Also an installation for the execution of said process will be described in the following text. Intensive live-stock farming has assumed large proportions in certain countries, notably the Netherlands, Belgium and West-Germany. Some recent figures for The Netherlands are illustrative. In 1984 the numbers of cattle, pigs and poultry in The Netherlands were 5.5, 11 and 83 million respectively. By modern industrial techniques these quantities are produced mainly as manure slurries. These manure quantities have led to manure surplusses, which are determined by manure standards for grassland and agricultural soils. On the basis of the current agricultural phosphate standards, as mentioned in the Dutch law on fertilizers, the total manure surplus amounts to about 12 million tonnes per year. According to more severe environmental phosfate standards the surplus is estimated at 30 million tonnes per year. The problems, which result from the above can be summarized in main lines as follows: 1. The aforementioned surplusses lead to too large quantities of nutritious matter in the environment, by which ecological processes are disturbed and supplies, such as the delivery of good drinking water, are jeo¬ pardized. 2. Ammonia, originating from manure, contributes to the acidification of the environment. 3. Stench nuisance. 4. Pathogenic micro-organisms and weed seeds make animal manure less acceptable for manuring of grassland and agricultural soils. 5. Too high concentrations of metals, such as copper and cadmium from manure, can give rise to poisoning symptoms in animals and men via grass and crops from agricultural soils. Aforementioned problems can be emphasized by the fact, that transport of manure slurries from areas with large surplusses to areas with shortages is relatively expensive, so that accu¬ mulation may occur in the areas first mentioned. The object of the invention is to offer a solution for said problems. In recent press publication various experimental plants and installations for the working-up of manure have been mentioned, such as for example in the 'NRC Handelsblad', dated June 19, 1987, the experimental plant of 'Promest B.V.' an the 'compactor' of de 'Verenigde Heymans Bedrijven'. In de 'Volkskrant', dated May 13, 1987, the manure conversion system of 'Waste Treatment Systems'has been discussed. In the periodical 'Toegepaste Techniek', dated April 1986 'TNO' presented a blue print for a large scale experimental plant for the conversi- on/working-up of manure slurry. As far as known, in such cases it concerns mainly plans, some of which are in an advanced stage and furthermore these experimental plants and installations are based on other processes and installa¬ tions than those mentioned in current invention. The invention relates to the process mentioned in the beginning, in which the mixture according tot the said application this could be manure slurry, is contacted with an oxygen containing gas and an exothermic reaction is started in a reactionsection at temperatures between 200 to 320 degrees Celsius, pres¬ sures between 40 to 125 bar and reaction times between 300 to 5400 seconds. In the first instance the start of the reaction occurs in a usual way by prehe¬ ating of the mixture for example. The said technique is known on its own and in literature it is indicated by the term 'wet oxidation'. The distribution in residence times of the slurry phase elements and the gas phase is kept as narrow as possible by installing -at some distance from each other- perforated baffles perpendicular to the direction of flow of the phase in. the reaction sec¬ tion, which comprises at least one vessel. After reaction, gas, which contains water vapour is separated from the slurry phase, which contains remaining organic matter and anorganic matter. This slurry phase is carried to an evapo¬ ration section, of which at least one unit contains a fluidized bed of particles of solid matter. In the first instance this fluidized bed may consist of sand particles or another suitable matter. The particles of solid matter can be cho- sen in such a way with respect to density and particle size, that these parti¬ cles will be fluidized by the flow of vapour, which develops from the slurry phase. This flow of vapour will develop, because the evaporation section and thus the evaporation unit with the fluidized bed are operated at lower tempe¬ ratures and pressures than the temperature and pressure of the slurry phase and gas phase directly after reaction and heat is supplied via evaporation means. Such a fluidized bed may be operated at a temperature and pressure, which are between for example 60 to 240 degrees Celsius and 0.2 to 40 bar. The heat, which is supplied via the evaporation means, can be emanated from the gas phase, which is carried to the evaporation means after separation from the slurry phase. The evaporation means are in practice indirect heat excan- gers and heat for evapoaration is notably the latent heat, which releases through condensation of water vapour present in the gas phase. However heat may be supplied also in another way, for example via electrical spirals. Extra gas may be used for fluidization of the particles of solid matter in the fluidi¬ zed bed and discharge of water vapour. For this purpose, as an example, the gas can be used, which remains after the condensation of water vapour and emanates from the heatexchangers in the evaporation section. In the evaporation section water in the slurry phase is evaporated largely or completely and the remaining organic matter and anorganic matter will be deposited on the particles of solid matter or participate as individual particles in the fluidized bed. Parts of the fluidized bed mass may be discharged perio¬ dically or continously to product storage.In case of the conversion of manure slurry this mass consist of a high value fertilizer, which is rich in nitrogen, phosphorus and potassium. If necesarry, particles of solid matter may be added periodically or continously to the fluidized bed. Water vapour out of the fluidi- zed bed is carried through a separation apparatus - for example a cyclone - , in which possible entrained particles of solid matter are separated and subse¬ quently discharged to a product storage. The water vapour, in which extra gas may occur also, is condensed subsequently partially or totally in a heatexchan- ger, whereby the released heat is used for heating up of the incoming mixture. Also condensate from the evaporation means in the evaporation section may be used for heating up of the mixture. Heat from the gas phase flow after the reaction section may be used as well for further heating of the mixture. The rest heat of water vapour, condensate and gas, which remains after execution of the process, described above, may be used for heating of for instance live- stock houses, horticultural houses (greenhouses) and dwellings. In conclusion it is mentioned, that there is also the possibility in the process to carry an extra amount of mixture to the evaporation section and notably fluidized bed, while circumventing the reaction section. This becomes possible, if a surplus of heat exists in the evaporation section. The capacity of an installation for the execution of said process is enlarged by this option. An embodiment for the execution of said process will be described with the help of figure 1. The mixture is supplied through pipe 1 and through pump 2 via heatexchangers 3, 4 and 5 and gas-slurry phase distributor 8 pumped to reaction section 9. An oxygen containing gas, for example air, is als put into reaction section 9 via pipe 6, compressor 7 and distributor 8. The dispersion of gas in slurry phase flows through openings in baffles 10. Reactions take place and after a certain reaction time water vapour and gas are separated from the slurry phase in space 11. The slurry phase flows into draw-off tray 12 and subsequently it flows via pipe 13 to evaporation section 15, which consists here of a vessel containing a fluidized bed 16. Thrown up particles of solid matter are separated from vapour and possible gas in space 18, after which vapour and possible gas leaves via pipe 21 the evaporation section. Possible entrained solid matter is caught in cyclone 22 and carried to a product storage via pipe 23. Subsequently vapour and possible gas flows via pipe 24 to heatex- changer 3, in which heat is transferred to the mixture. The condensate with possible vapour, which has not been condensed, may be used for heating of houses and subsequently drained, as it concerns comparatively clean water. After that water vapour and gas have been separated from the slurry phase, this gas stream flows via pipe 14 and heatexchanger 5, in which heat is trans- f erred to the mixture, if necesarry, to heatexchanger 17. In the latter heat is transferred to the fluidized bed and ultimately used to evaporate water from the slurry phase. Condensate flows via pipe 25 to heatexchanger 4, in which heat is transferred to the mixture in pipe 1. The remaining heat may be used for heating of houses, after which the condensate can be drained. Gas releases from heatexchanger 17 via pipe 26 and heat in this stream may also be used for heating of houses. Via pipe 20 solid matter is discharged regularly from the fluidized bed and carried to a product storage. Possible addition of solid matter into the fluidized bed may take place via inlet 19. The invention offers a solution notably for said problems with respect to manure slurry as may become evident from the following remarks. First it must be mentioned, that from a technical and economical point of view the process may be executed on large scale as well as on a small scale. As a comparative small installation may be situated near the live-stock houses, transport costs of manure slurry to the installation may be eliminated almost entirely. As the product may be considered as high value fertilizer, which can be transported comparatively cheap, this produkt could be sold in areas with manure shorta- ges, by which high concentrations nutritious matter and metals, such as copper and cadmium, could be avoided on grassland and agricultural soils. Ammonia •* ** > emission and stench nuisance may be reduced significantly, if produced manure slurry can be 'converted and worked up nearly immediately. The latter becomes 5 a possibility by situating the installation near the live-stock houses. Pathogenic micro-organisms and weed seeds will not survive the comparatively long times, during which they are exposed to high temperatures. An extra advantage of this invention are the relatively large amounts of 'low temperature 1 heat, which can be used for heating of houses. 10 The invention will be illustrated with the help of an example. An installation, in which said process may be executed, is situated on a farm with a live-stock of 3000 pigs. The manure production amounts to 4500 tonnes of manure slurry per year. The installation is operated continously during 330 days per year, which means a throughput of about 0.16 kilogram 15 manure slurry per second. Also 0.06 kilogram air per second is supplied. The manure slurry contains in this example 10 % by weight solid matter and the chmical oxygen demand (COD) amounts to 100 kilogram per cubic meter. In the reaction section the degree of conversion amount to 80 % after 1800 seconds of reaction time. The temperature of the slurry phase and gas 20 immediately after reaction amounts to 255 degrees Celsius and the pressure is 60 bar. After reaction more than 50 % of the water, which was present in the supplied manure slurry, has been evaporated. After separation of water vapour on the one side and slurry phase on the other side, notably the latent heat of the vapour is used via indirect heatexchange in the fluidized bed to evaporate 25 water in the slurry phase largely or entirely. The fluidized bed is operated at 100 degrees Celsius. The production of solid matter is roughly 12.5 kilogram per hour, which contains roughly 4 kilogram per hour total nitrogen, 2.3 kilogram per hour phosphorus, calculated as P205, and also 2.3 kilogram per hour potassium, 30 calculated as K20. The heat, present in notably vapour and condensate streams of roughly 100 degrees Celsius and emanated from the installation, may be used to heat live-stock houses and greenhouses nearby. In this example this rest heat corresponds with the heat of combustion value of about 100,000 cubic meter of natural gas per year.

Claims: CLAIMS. 1. Process for the conversion and working up of a mixture of organic matter, anorganic matter and water to nearly dry matter, whereby the mixture is contacted with an oxygen containing gas and put to reaction in a reaction section at temperatures between 200 and 320 degrees Celsius, pressures between 40 and 125 bar and reaction times between 300 and 5400 seconds with the feature, that after reaction mixture and gas are separated on the one side in slurry(fluid) phase, which contains dissolved and not dissolved organic matter and anorganic matter and on the other side water vapour containing gasphase, of which heat is used for heating of the mixture and for evaporation of water from the slurry phase, which therefor is led to an evaporation secti¬ on, which is equipped with evaporation means and which may consist of vari¬ ous units and which is operated at lower temperatures and pressures than the temperature and pressure of the slurry phase and gas phase immediately after reaction and of which at least one unit contains a fluidized bed of particles of solid matter, which covers evaporation means entirely or partially and in which organic matter and organic matter, emanating from the slurry phase are caught and form part of the fluidized bed, after which parts of the fluidized bed mass may be discharged periodically or continously as a nearly dry matter. 2. Process according claim 1 with the feature, that heat from the gas phase, obtained after reaction by separation from slurry phase, is transferred via the walls of an heatexcanger to a fluidized bed, which is operated at a temperature and pressure between 60 and 240 degrees Celsius and 0.2 and 40 bar respectively and in which water from slurry phase is evaporated largely or entirely, while organic and anorganic matter is caught in the fluidized bed. 3. Process according claims 1 and 2 with the feature, that the fluidized bed contains in the first instance a suitable solid matter, such as for example sand with such particle sizes and density, that the particles are fluidized by the gas stream in. the bed and whereby gradually the concentrations of organic matter and anorganic matter can increase by deposition on particles of solid matter as well as in the form of particles, which form part of the fluid bed, so that in principle the fluidized bed largely or even entirely may consist of organic and anorganic matter, while, if necessarry, said suitable solid matter can be added periodically or continuously and furthermore care is taken of the periodical or continuous discharge of the fluidized bed mass. 4. Process according to claims 1,2 and 3 with the feature, that additional A gas is used to fluidize the particles of solid matter in the bed and to dischar¬ ge water vapour, whereby possibly gas from the heatexchanger in the fluidized 5 bed is to be used. 5. Process according to claim 1 with the feature, that after by-passing the reaction section an extra stream of mixture is fed to the evaporation section, where after partial or total evaporation of water extra organic matter and anorganic matter is caught in the fluidized bed. 10 6. Installation for the execution of the process according to claims 1,2,3,4 and 5 with the feature, that this installation consists of one or more reaction vessels, equipped with perforated baffles installed at some distance from each other and a provision for the separation of gas phase and slurry phase, moreo¬ ver there are one of more evaporators, of which at least one evaporator con- 15 tains a fluidized bed and these are equipped with evaporation means, while furthermore comρressor(s), pump(s) and heatexchangers as well as solids-gas separation apparatus form part of the installation. 7. Application of the process according to claim 1 with the feature, that the mixture consists largely of manure slurry. 20 8. Application of the process according to claim 1 with the feature, that the mixture consists largely of fluid sewage.

Inventors: BUKKEMS FRANCISCUS HENRICUS JO, BUKKEMS, FRANCISCUS, HENRICUS, JOSEPHUS
Applicants: FHJ PROCESS BV, FHJ PROCESS B.V.
Application year: 1988
Main classification: C05F3
IPC codes: B01J2, C05F3, C05F7, C05F17