Detergent composition

Abstract: A detergent composition is disclosed, which comprises (A) 0.1 to 40% by weight of at least one kind of anionic or amphoteric surface active agents and (B) 0.05 to 4% by weight of at least one kind of quaternary amnonium salts represented by the following formula (I) or (II): wherein R₁ represents a mixture of (a) a branched alkyl group represented by and (b) a linear alkyl group represented by CH₃-(CH₂) n - (wherein R₇ represents a methyl or ethyl group, m is an integer to make the carbon atom content of the branched alkyl group to 8 to 16, and n is an integer of 7 to 15), with a ratio (a)/(a) + (b) being 0.1 to 1, R₂ and R₃ independently represent a benzyl group, an alkyl group having 1 to 3 carbon atoms, or a hydroxyalkyl group having 1 to 3 carbon atoms, R₄ and R₅ independently represent an alkyl group having 2 to 12 carbon atoms, R₆ represents a group or an alkyl group having 1 to 3 carbon atoms, and X⁻ represents a halogen ion or an organic anion. The detergent composition provides a shampoo with superb hair conditioning effects; softness and smoothness after washing, less sticky feeling, easy passage of comb through the hair, less hard or rough feeling as well as easy hair-set performance after drying. The detergent composition also provides a liquid detergent suitable for washing cloths made of wool or made of fine denier fibers.

Description: BACKGROUND OF THE INVENTION Field of the Invention: This invention relates to a detergent composition, and, more particularly, to a detergent composition comprising an anionic or amphoteric surface active agent and a branched quaternary ammonium salt. The detergent composition is suitable for use as a shampoo, which provides superb hair conditioning effects, including softness and smoothness after washing, easy hair-set after drying, less sticky feeling, easiness of comb or finger passage through the hair. The detergent composition also provides a liquid detergent for washing cloths, which ensures softness of the cloths, especially those made of keratin fibers such as wool or the like, or made of fine denier fibers, after washing. Description of the Background: US-A-3,892,669 describes a clear, homogeneous, aqueous fabric softening composition containing a solubilized tetraalkyl quaternary ammonium salt having two short chain alkyl groups and two long chain alkyl groups, together with a solubilizer comprising aryl sulfonates. GB-A-2,172,607 describes a rinse aid composition for use in association with mechanical type dishwashers. The composition comprises effective amounts of a quaternary ammonium compound, a hydrophilic polymer and an amphoteric surfactant. US-B-438,048 describes a shampoo creme rinse comprising anionic or amphoteric detergents and a quaternary ammonium compound having a benzyl radical. EP-A-0 150 433 describes a shampoo composition comprising an anionic surface active agent, an amino acid-type anionic surface active agent and an amphoteric surface active agent in a specified ratio. EP-A-0 247 832 describes a detergent composition comprising in an aqueous medium at least one amphoteric surfactant, at least one monoalkyl quaternary ammonium salt cationic surfactant and at least one carboxylate anionic surfactant. Many types of detergent compositions are commercially sold in recent years, which contain a cationic polymer such as a cationic cellulose, or a cationic surface active agent, in order to provide the washed hair with excellent conditioning effects or for the purpose of giving cloths an excellent soft feeling after washing. Most of these detergents can provide good softness to the hair or cloths after washing. These conventional detergents, however, have drawbacks of poor detergent capability and insufficient softness of the hair or the cloths after drying because of cationic polymers or cationic surface active agents used in the detergents. More specifically, detergents for cloths into which a cationic surface active agent is formulated exhibit rather poor dirt-elimination capability due to an adverse effect of the cationic surfactant. Even though such a cationic surface active agent is employed in an amount small enough not to impair the detergent capability of the composition, softness of the finished cloths is still to be improved. Shampoos containing a cationic surface active agent tend to impart a sticky feel when the hair is dried after washing and to adversely affect a smooth passage of comb through the hair. In addition, a complex of a surface active agent and a cationic polymer solidifies in the course of hair drying and causes hair-fly or hardens the hair, thus providing insufficient conditioning effects. The use of increased amount of cationic polymer to eliminate these drawbacks brings about more stickiness and damages a smoothness or softness of the finished hair. Because of this, there has been a strong desire for the development of a detergent which can provide an excellent conditioning effect to the hair or the cloths after washing and drying, specifically, providing softness, smoothness, and fine delicate feeling to the finished hair or the cloths. The present inventors have undertaken extensive studies for the resolution of the above drawbacks in the conventional detergents, and found that a detergent composition to which a branched quaternary ammonium salt is formulated, in addition to an anionic or amphoteric surface active agent, gives a delicate softness to cloths after washing and provides soft, smooth feeling to the hair, eliminating the drawbacks of conventional shampoo compositions to which a cationic polymer is formulated, e.g. imparting stickiness in the course of drying or producing hardened hair after drying. SUMMARY OF THE INVENTION The present invention provides a detergent composition comprising (A) 0.1 to 40 % by weight of at least one kind of anionic or amphoteric surface active agents selected from the following (1) to (5): (1) Alkyl-or alkenylether sulfates having a linear or branched, alkyl or alkenyl group of an average carbon atom content of 10 to 20 and having, in a molecule, 0.5 to 8 mols of ethylene oxide adduct, propylene oxide adduct, butylene oxide adduct, ethylene oxide-propylene oxide adduct with a ratio of ethylene oxide/propylene oxide being 0.1/9.9 to 9.9/0.1, or ethylene oxide-butylene oxide adduct with a ratio of ethylene oxide/butylene oxide being 0.1/9.9 to 9.9/0.1, (2) Alkyl- or alkenyl sulfates having an alkyl or alkenyl group of an average carbon atom content of 10 to 20, (3) Olefin sulfonates having an average carbon atom content of 10 to 20 in a molecule, (4) Saturated or unsaturated fatty acids having an average carbon atom content of 10 to 24, and (5) Imidazoline-type amphoteric surface active agents of α-position addition-type, secondary amido-type amphoteric surface active agents, or tertiary amido-type amphoteric surface active agents, having an alkyl, alkenyl, or acyl group of an 8 to 24 carbon atom content; (B) 0.05 to 4% by weight of at least one kind of quaternary ammonium salts represented by the following formula (I) or (II): wherein R₁ represents a mixture of (a) a branched alkyl group represented by and (b) a linear alkyl group represented by CH₃-(CH₂) n - (wherein R₇ represents a methyl or ethyl group, m is an integer to make the carbon atom content of the branched alkyl group to 8 to 16, and n is an integer of 7 to 15), with a ratio (a)/(a) + (b) being 0.1 to 1, R₂ and R₃ independently represent an alkyl group having 1 to 3 carbon atoms, or a hydroxyalkyl group having 1 to 3 carbon atoms, R₄ and R₅ independently represent an alkyl group having 2 to 12 carbon atoms, R₆ represents a group or an alkyl group having 1 to 3 carbon atoms, and X⁻ represents a halogen ion or an organic anion. Another object of this invention is to provide a detergent composition comprising, in addition to the above (A) and (B) components, (C) 0.05 to 2% by weight of at least one cationic polymer selected from the group consisting of cationized cellulose derivatives, cationic starch, copolymers of a diallyl quaternary ammonium salt and an acrylamide, quaternarized polyvinylpyrrolidone derivatives, and polyglycol-polyamine condensates. It is a more specific object of the present invention to provide a detergent composition, wherein 0.1 to 25% by weight, based on the detergent composition, of said (A) component is one or more amidoamine-type amphoteric surface active agents represented by the following formula (III) or (IV): wherein R₈ and R₁₀ each independently represent a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, R₉ and R₁₁ each independently represent a group -CH₂COOM or -CH₂CH₂COOM (wherein M stands for a hydrogen atom, an alkali metal, or an alkanol amine), R₁₂ represents a hydrogen atom, a group -CH₂COOM, or a group -CH₂CH₂COOM (wherein M has the same meaning as defined above). Other objects, features and advantages of the invention will hereinafter become more readily apparent from the following description. DETAILED DESCRIPTION OF THE INVENTION AND PREFERRED EMBODIMENTS Following anionic and amphoteric surface active agents can be used as the (A) component surfactant: Anionic surface active agent (1) Alkyl- or alkenylether sulfates having a linear or branched, alkyl or alkenyl group of an average carbon atom content of 10 to 20 and having, in a molecule, 0.5 to 8 mols of ethylene oxide adduct, propylene oxide adduct, butylene oxide adduct, ethylene oxide-propylene oxide adduct with a ratio of ethylene oxide/propylene oxide being 0.1/9.9 to 9.9/0.1, or ethylene oxide-butylene oxide adduct with a ratio of ethylene oxide/butylene oxide being 0.1/9.9 to 9.9/0.1. (2) Alkyl- or alkenyl sulfates having an alkyl or alkenyl group of an average carbon atom content of 10 to 20. (3) Olefin sulfonates having an average carbon atom content of 10 to 20 in a molecule. (4) Saturated or unsaturated fatty acids having an average carbon atom content of 10 to 24. Amphoteric surface active agent (4) Imidazoline-type amphoteric surface active agents of α-position addition-type, secondary amido-type amphoteric surface active agents, or tertiary amido-type amphoteric surface active agents, having an alkyl, alkenyl, or acyl group of an 8 to 24 carbon atom content. Given as counter-ions for the anionic residual group of these surface active agents are alkali metal ions such as sodium or potassium ion, alkali earth metal ions such as calcium or magnesium ions, ammonium ion, alkanol amine ions having 1 to 3 alkanol groups with a 2 or 3 carbon atom content such as monoethanolamine, diethanolamine, triethanolamine and tri-i-propanolamine. When these types of salts are used, the surface active agent tends to contain inorganic salts as contaminants. It is desirable that such inorganic salts be removed from the surface active agent so that the content of the inorganic salt contaminants in the final detergent product be less than 1 % by weight. Counter ions for cationic groups may be halogen ions such as chlorine, bromine, or iodine, methosulfate ion or succharinate ion. Given as specific examples of suitable anionic surface active agents are sodium polyoxyethylenelaurylether sulfate (ethylene oxide addition: 2 - 3 mols in average) triethanolamine lauryl sulfate, sodium α-olefin sulfonate (average carbon atom content: 12 - 14), sodium salt of tallow/coconut (80/20) oil fatty acids, and the like. Amido-amine type compounds represented by the following formula (III) or (IV) are given as examples of suitable amphoteric surface active agents. wherein R₈ and R₁₀ each independently represent a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, R₉ and R₁₁ each independently represent a group -CH₂COOM or -CH₂CH₂COOM (wherein M stands for a hydrogen atom, an alkali metal, or an alkanol amine), R₁₂ represents a hydrogen atom, a group -CH₂COOM, or a group -CH₂CH₂COOM (wherein M has the same meaning as defined above). Specific examples of suitable amido-amine type surface active agents represented by the formula (III) include N-lauroyl-N′-carboxymethyl-N′-(2-hydroxyethyl)ethylenediamine, N-lauroyl-N′-carboxyethyl-N′-(2-hydroxyethyl)ethylenediamine, N-myristoyl-N′-carboxymethyl-N′-(2-hydroxyethyl)ethylenediamine, N-myristoyl-N′-carboxyethyl-N′-(2-hydroxyethyl)ethylenediamine, N-palmitoyl-N′-carboxymethyl-N′-(2-hydroxyethyl)ethylenediamine and N-palmitoyl-N′-carboxyethyl-N′-(2-hydroxyethyl)ethylenediamine, as well as their salts. Given as specific examples of suitable amido-amine type surface active agents represented by the formula (IV) are N-lauroyl-N-(2-hydroxyethyl)-N′-carboxymethylethylenediamine, N-lauroyl-N-(2-hydroxyethyl)-N′,N′-bis(carboxymethyl)ethylenediamine, N-lauroyl-N-(2-hydroxyethyl)-N′,N′-bis(carboxyethyl)ethylenediamine, N-myristoyl-N-(2-hydroxyethyl)-N′-carboxymethylethylenediamine, N-myristoyl-N-(2-hydroxyethyl)-N′,N′-bis(carboxymethyl)ethylenediamine, N-myristoyl-N-(2-hydroxyethyl)-N′,N′-bis(carboxymethyl)ethylenediamine, N-palmitoyl-N-(2-hydroxyethyl)-N′-carboxymethylethylenediamine, N-palmitoyl-N-(2-hydroxyethyl)-N′,N′-bis(carboxymethyl)ethylenediamine and N-palmitoyl-N-(2-hydroxyethyl)-N′,N′-bis(carboxyethyl)ethylenediamine, as well as their salts. Surface active agents may be used either individually or in combination with one or more other surface active agents. Among the (B) components, branched quaternary ammonium salts represented by the general formula (I) are produced, for example, from oxo alcohols having an 8 to 16 carbon atom content. Specific examples are dialkyldimethylammonium salt or dialkylmethylhydroxyethylammonium salt, all having an alkyl group derived from an oxo alcohol. Counter ions for these ammonium salts may be a halogen ion such as chlorine ion, bromine ion, or iodine ion, or an organic anion such as methosulfate, ethosulfate, methophosphate or ethophosphate. The alkyl group, R₁ in formula (I), is a group comprised of (a) a group represented by (wherein R₇ represents a methyl or ethyl group) and (b) a group represented by CH₃-(CH₂) n -, both having an 8 to 18 carbon atom content. "Branched ratio" for R₁, (a)/(a) + (b), is in the range of 0.1 to 1, and particularly preferably in the range of 0.1 to 0.5. Although the total carbon number of the alkyl group R₁ is 8 to 16, preferable groups are those having a certain distribution of the carbon atom content. C₈ - C₁₁: less than 5% C₁₂: 10 - 35% C₁₃: 15 - 40% C₁₄: 20 - 45% C₁₅: 5 - 30% C₁₆: less than 5% Specific examples of particularly preferably branched quaternary ammonium salts represented by formula (I) are dialkyldimethylammonium chloride in which the alkyl group R₁ has 8 to 16 carbon atoms and the branched ratio is 0.1 to 0.5. A branched quaternary ammonium salt represented by formula (II), which is the (B) component of the present invention, can be synthesized, for example, using as a raw material a Guerbet alcohol Given as preferably examples of this branched quaternary ammonium salt are monoalkyl-type quaternary salts such as alkyltrimethylammonium salt and alkyldimethylhydroxyethylammonium salt; dialkyldimethylammonium salt, dialkylmethylhydroxyethylammonium salt, and the like, all having an alkyl group derived from Guerbet alcohol. Given as counter-ions for the ammonium salts are halogen ions such as chlorine ion, bromine ion, or iodine ion, or organic anions such as methosulfate, ethosulfate, methophosphate or ethophosphate. Examples of alkyl groups derived from Guerbet alcohols include 2-hexyldecyl group, 2-octyldodecyl group, 2-decyltetradecyl group and 2-dodecylhexadecyl group. Particularly preferable examples of branched quaternary ammonium salts of formula(II) are 2-decyltetradecyltrimethylammonium chloride, 2-dodecylhexadecyltrimethylammonium chloride, di-2-hexyldecyldimethylammonium chloride and di-2-octyldodecylammonium chloride. These branched quaternary ammonium salts represented by formula (I) or (II) can be employed either individually or in combination. In view of reduced stickiness of the detergent composition quaternary ammonium salts represented by formula (II) are generally preferable. The amount of the (A) component to be formulated into the detergent composition of this invention is in the range of 0.1 to 40% by weight, and preferably 10 to 25% by weight. The amount of the (B) component is 0.05 to 4%, with a preferable range being 0.1 to 1% by weight. Besides the above two essential components, various components commonly known for use in a detergent composition can be formulated. Such components to be added into a shampoo include, for example, nonionic surface active agents, moisturizing agent such as propylene glycol and glycerin, pH adjustment agents such as phosphoric acid and citric acid, viscosity adjustment agents such as ethanol, higher alcohols, hydroxyethyl cellulose and methyl cellulose, conditioning agent such as oils or fats of plants or animals origin, UV ray absorbers, antioxidants, anti-dandruff agents, antifungals and agents for modifying outward appearance such as pearling agents. Additives for cloth detergent compositions include foaming agents, de-foaming agents, dirt-reattachment inhibitors, metal ion sealing agents, fluorescents and enzymes. In addition, antiseptics, coloring agents and perfumes are formulated as required. Among the above-mentioned optional ingredients, (C) one or more cationic polymers selected from the group consisting of cationized cellulose derivatives, cationic starch, copolymers of a diallyl quaternary ammonium salt and an acrylamide, quaternarized polyvinylpyrrolidone derivatives, and polyglycol-polyamine condensates, when formulated into the detergent composition, provide even superior conditioning effects. The compounds represented by the following formula (V) is desirable for use as cationized cellulose derivatives: wherein A represents an anhydrous glucose unit residue, a denotes an integer of 50 to 20,000, and each R₁₃ individually represents a group represented by the following formula (VI): wherein R′ and R″ individually represents an alkylene group having 2 or 3 carbon atoms, b is an integer of 0 to 10, c is an integer of 0 to 3, d is an integer of 0 to 10, R″' represents an alkylene group or a hydroxyalkylene group each having 1 to 3 carbon atoms, R₁₄, R₁₅, and R₁₆ may be the same or different and represent alkyl groups, aryl groups, aralkyl groups, each having not more than 10 carbon atoms, or may form a heterocycle together with the nitrogen atom, and X₁ represents an anionic ion (chlorine, bromine, iodine, sulfuric acid, sulfonic acid, methyl sulfate, phosphoric acid and nitric acid). A preferable range of the cation substitution degree of cationized cellulose is 0.01 to 1, i.e., in terms of the average value of c for anhydrous glucose 0.01 to 1, and preferably 0.02 to 0.5. The average of b plus d is 1 to 3. A substitution degree of below 0.01 is not sufficient. The value not more than 1 is preferable in view of the reaction yield, although the value above 1 can be acceptable. The molecular weight of the cationic cellulose used is between 100,000 and 3,000,000. The compounds represented by the following formula (VII) are preferable cationic starches. B represents a starch residual group, R₁₇ represents a alkylene group or a hydroxyalkylene group, R₁₈, R₁₉, and R₂₀ may be the same or different and represent alkyl groups, aryl groups, aralkyl groups, each having not more than 10 carbon atoms, or may form a heterocycle together with the nitrogen atom, X₂ represents an anionic ion (chlorine, bromine, iodine, sulfuric acid, sulfonic acid, methyl sulfate, phosphoric acid, nitric acid, and the like), and e is a positive integer. A preferable range of the cation substitution degree of cationic starch is 0.01 to 1. Specifically, cationic starches having 0.01 to 1, preferably 0.02 to 0.5, cationic group per anhydrous glucose unit are desirable. A substitution degree of below 0.01 is not sufficient. The value not more than 1 is preferable in view of the reaction yield, although the value above 1 can be acceptable. The compounds represented by the following formula (VIII) or (IX) are preferable as a cationic diallyl quaternary ammonium salt/acryl amide copolymer. wherein R₂₁ and R₂₂ may be the same or different and represent hydrogen atoms, alkyl groups having 1 to 18 carbon atoms, phenyl groups, aryl groups, hydroxyalkyl groups, amidoalkyl groups, cyanoalkyl groups, alcoxyalkyl groups, or carboalcoxyalkyl groups, R₂₃, R₂₄, R₂₅, and R₂₆ may be the same or different and represent hydrogen atoms, lower alkyl groups having 1 to 3 carbon atoms, or phenyl groups, X₃ represents an anionic ion (chlorine, bromine, iodine, sulfuric acid, sulfonic acid, methyl sulfate and nitric acid), f is an integer of 1 to 50, g is is an integer of 1 to 50, and h is an integer of 150 to 8,000. The molecular weight of a diallyl quaternary ammonium salt/acryl amide copolymer is in the range of 30,000 to 2,000,000, and preferably of 100,000 to 1,000,000. The compounds represented by the following formula (X) are preferable as a quaternarized polyvinylpyrrolidone derivative. wherein R₂₇ represents a hydrogen atom or a lower alkyl group having 1 to 3 carbon atoms, R₂₈, R₂₉, and R₃₀ may be the same or different and represent hydrogen atoms, alkyl groups having 1 to 4 carbon atoms, hydroxyalkyl groups, amidoalkyl groups, cyanoalkyl groups, alcoxyalkyl groups, or carboalcoxyalkyl groups, Y represents an oxygen atom or the NH group of an amide bond, X₄ represents an anionic ion (chlorine, bromine, iodine, sulfuric acid, sulfonic acid, alkyl sulfate of a C₁₋₄ carbon atom content, phosphoric acid and nitric acid), k is an integer of 1 to 10, i and j are integers satisfying i + j = 20 to 8,000. A molecular weight of a quaternarized polyvinylpyrrolidone derivative is between 10,000 and 2,000,000, with particularly preferable range being between 50,000 and 1,500,000. The content of the cationic nitrogen originating from cationic polymer in the above vinyl polymer is 0.004 to 0.2%, and preferably 0.01 to 0.15% based on the vinyl polymer. A sufficient effect cannot be expected from the nitrogen atom content of less than 0.004%. On the other hand, the content of above 0.2% causes the vinyl polymer becoming colored and is disadvantageous in view of economy, even though a good performance can be obtained. Compounds represented by the formula (XI) are preferable as a polyglycol-polyamine condensate. wherein R₃₁, R₃₃, R₃₄, and R₃₆ represent hydroxyalkylene groups of a C₂₋₄ carbon atom content, R₃₂ and R₃₅ represent alkylene groups of a C₂₋₃ carbon atom content, l and p are individually an integer of 10 to 20, q is an integer of 2 to 4, r is an integer of 2 to 6, s is an integer of 1 to 50, R₃₇ represents a linear or branched alkyl group of a C₆₋₂₀ carbon atom content. A copolymer of adipic acid and dimethylaminohydroxypropyldiethylenetriamine (Cartaretine®, produced by Sandoz Co., U.S.A.) may also be used as a cationic polymer. Cationic polymers mentioned above may be used either individually or in combination. The amount of the (C) component formulated into the detergent composition of this invention is 0.05 to 2% by weight, and particularly preferably 0.1 to 0.8% by weight. The detergent composition of this invention, when used as a shampoo provides superb hair conditioning effects, such as softness and smoothness after washing, less sticky feeling, easy passage of comb through the hair, less hard or rough feeling as well as easy hair-set performance after drying. The detergent composition also provides a liquid detergent suitable for washing cloths made of keratin fibers such as wool or the like, or made of fine denier fibers, which ensures softness of the cloths after washing. Other features of the invention will become apparent in the course of the following description of the exemplary embodiments which are given for illustration of the invention and are not intended to be limiting thereof. EXAMPLES In the examples below the following test methods were applied to study the performance of detergent compositions. (1) Organoleptic evaluation: Onto a bundle of hair (weight: 20 g, length: 15 cm) of a healthy Japanese woman 1 g of a shampoo was applied. After the shampoo was foamed for 1 minute, the hair bundle was rinsed in a stream of water for 30 seconds. Water was removed from the hair bundle with towel to serve it for organoleptic evaluation with respect to softness and stickiness according to the following criterion: (2) Passage of comb through the hair Human hair weighing 30 g was washed in 10 cc of an aqueous solution of a shampoo composition (concentration: 10%) at 40°C for 30 seconds under shaking. The hair was washed in a water stream for 1 minute, squeezed to remove water, and set to a strain gauge to measure the force applied when combed to obtain a combing force at moistured conditions. Another bundle of hair treated with the same shampoo composition was washed in a water stream, squeezed to remove water, dried with a dryer, and left for overnight in a thermostat container at 25°C and 65% relative humidity. This bundle of hair was et to a strain gauge to measure the force applied when combed to obtain a combing force at dried conditions. The smaller the load, is easier the combing. (3) Hair-fly The same hair used for the measurement of combing force at dried conditions was used for the test, in which the state of hair under electrostatic conditions was observed by naked eyes. AAA: No hair-fly was occurred BBB: Occurrence of hair-fly was observed Example 1 Shampoo compositions listed in Table 1 were prepared and submitted to organoleptic evaluation, evaluation of combing easiness, and of hair-fly. The results are shown in Table 1, in which figures for the composition formulation designate % by weight. Each composition contained, besides components listed in the table, following components: As evident from Table 1, shampoos to which cationic polymers or linear quaternary ammonium salts are formulated exhibited only insufficient conditioning effects, while, on the other hand, shampoos to which branched quaternary ammonium salts according to the present invention are formulated exhibited superior performances. Example 2 Shampoo compositions listed in Table 2 were prepared and submitted to organoleptic evaluation, and evaluation of hair-fly. The results are shown in Table 2, in which figures for the composition formulation designate % by weight. Each composition contained, besides components listed in the table, following components: As evident from Table 2, branched quaternary ammonium salts contributed to superior performances of shampoos, exhibiting excellent mutual solubility with various anionic or amphoteric surface active agents. Example 3 Shampoo compositions listed in Table 3 were prepared and their performances were evaluated. The results are shown in Table 3, in which figures for the composition formulation designate % by weight. Each composition contained, besides components listed in the table, following components: Table 3 demonstrates that with the amount of formulation of a branched quaternary ammonium salt at less than 0.05% by weight, the conditioning effect is low, while the amount exceeding 4.0% by weight caused stickiness and impaired passage of fingers through the hair. Example 4 Shampoo compositions listed in Tables 4-1 and 4-2 were prepared and their organoleptic feeling, passage of comb, and hair-fly were evaluated. The results are shown in Tables 4-1 and 4-2, in which figures for the composition formulation designate % by weight. Each composition contained, besides components listed in the table, following components: Example 5 Shampoo compositions of the following formulations ware prepared and subjected to organoleptic evaluation by ten women with long hairs. The results are shown in Table 5. Shampoo A (Invention Product): Component % by weight Sodium N-lauroyl-N'-carboxymethyl -N'-(2-hydroxyethyl)ethylenediamine 15 Diethanolamide laurate 3 Cationic polymer (Polymer JR-400®; manufactured by Union Carbide Corp.) 0.3 2-Dodecylhexadecyltrimethyl ammonium chloride 0.2 Antiseptics 0.1 Perfumes 0.4 Coloring agent small amount Water balance pH 7 Shampoo B (comparative Product): Component % by weight Sodium N-lauroyl-N'-carboxymethyl -N'-(2-hydroxyethyl)ethylenediamine 15 Diethanolamide laurate 3 Cationic polymer (Polymer JR-400®; manufactured by Union Carbide Corp.) 0.3 Antiseptics 0.1 Perfumes 0.4 Coloring agent small amount Water balance pH 7 Shampoo A was better Shampoo B was better Could not tell difference Amount of foam 3 2 5 Finger passage through the hair 6 2 2 Smoothness after rinse 8 2 0 Softness after rinse 7 3 0 Brushing easiness while blow drying 9 1 0 Easiness of hair-set after drying 9 1 0 Comb passage through the hair after drying 8 1 1 Example 6 - 7 Shampoo compositions having following formulations were prepared. All these compositions produced abundant foam, removed dirt efficiently, and provided an excellent soft feeing after hair-washing. Example 6 Shampoo: Component % by weight Triethanolamine lauryl sulfate 16 Sodium lauroylsarcosine 3 Diethanol amide laurate 2 2-Decyltetradecyltrimethylammonium 0.5 chloride Antiseptics 0.1 Perfumes, Coloring agents (appropriate amount) Water balance 100 Example 7 Shampoo: Component % by weight Sodium polyoxyethylene (3.0) lauryl sulfate 7 Carbobetaine 5 Sodium lauroyl-N-methyl-β-alanine 2 Cationic polymer (Polymer JR-400®; manufactured by Union Carbide Corp.) 0.2 2-Dodecylhexadecyltrimethylammonium chloride 0.4 Antiseptics 0.1 Perfumes, Coloring agents (appropriate amount) Water balance 100 Examples 8 - 11 Shampoos having the following formulations exhibited only very weak stimulus to the skin and provided a soft finished feeling after washing. Example 8 Component % by weight Sodium N-lauroyl-N-(2-hydroxyethyl)-N',N'-bis(carboxyethyl) ethylenediamine 12 Sodium polyoxyethylene (2.5) laurylether sulfate 5 Diethanolamide laurate 3 Cationic polymer (Marcoat 550®; produced by Merck Co.) 0.2 2-Decyltetradecyltrimethylammonium chloride 0.2 Antiseptics 0.1 Perfumes, Coloring agents (appropriate amount) Water balance 100 Example 9 Component % by weight N-lauroyl-N'-carboxymethyl-N'-(2-hydroxyethyl)-ethylenediamine triethanolamine 3 Laurylether sulfate triethanolamine 15 Diethanolamide laurate 2 Cationic polymer (Polymer JR-400®; manufactured by Union Carbide Corp.) 0.6 Dialkyldimethylammonium chloride 0.1 Antiseptics 0.1 Perfumes, Coloring agents (appropriate amount) Water balance 100 Example 10 Component % by weight N-lauroyl-N'-carboxymethyl-N'-(2-hydroxyethyl)-ethylenediamine triethanolamine 18 Polyoxyethylene (2.5) laurylether sulfate triethanolamine 5 Ethanolamine salt of 1-hydroxy-4-methyl-6-(2,4,4-trimethylphenyl)-2(1H)-pyridinone (Octopyrox®) 1 Cationic polymer (Polymer JR-400®; manufactured by Union Carbide Corp.) 0.1 2-Dodecylhexadecyltrimethylammonium chloride 0.2 Methyl cellulose 0.3 Antiseptics 0.1 Perfumes, Coloring agents (appropriate amount) Water balance 100 Example 11 Component % by weight Sodium N-lauroyl-N-(2-hydroxyethyl)-N',N'-bis(carboxyethyl) ethylenediamine 0.8 Sodium polyoxyethylene (3.0) laurylether sulfate 18 Cationic polymer (Gafcoat 755N®, produced by Guf Co.) 0.4 2-Dodecylhexadecyltrimethylammonium chloride 0.3 Antiseptics 0.1 Pearling agents 5 Perfumes, Coloring agents appropriate amount Water balance 100 Obviously, numerous modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described herein.

Claims: A detergent composition characterized in that it comprises: (A) 0.1 to 40 % by weight of at least one kind of anionic or amphoteric surface active agents selected from the following (1) to (5): (1) Alkyl-or alkenyl ether sulfates having a linear or branched, alkyl or alkenyl group of an average carbon atom content of 10 to 20 and having, in a molecule, 0.5 to 8 mols of ethylene oxide adduct, propylene oxide adduct, butylene oxide adduct, ethylene oxide-propylene oxide adduct with a ratio of ethylene oxide/propylene oxide being 0.1/9.9 to 9.9/0.1, or ethylene oxide-butylene oxide adduct with a ratio of ethylene oxide/butylene oxide being 0.1/9.9 to 9.9/0.1, (2) Alkyl- or alkenyl sulfates having an alkyl or alkenyl group of an average carbon atom content of 10 to 20, (3) Olefin sulfonates having an average carbon atom content of 10 to 20 in a molecule, (4) Saturated or unsaturated fatty acids having an average carbon atom content of 10 to 24, and (5) Imidazoline-type amphoteric surface active agents of α-position addition-type, secondary amido-type amphoteric surface active agents, or tertiary amido-type amphoteric surface active agents, having an alkyl, alkenyl, or acyl group of an 8 to 24 carbon atom content; (B) 0.05 to 4% by weight of at least one kind of quaternary ammonium salts represented by the following formula (I) or (II): wherein R₁ represents a mixture of (a) a branched alkyl group represented by and (b) a linear alkyl group represented by CH₃-(CH₂) n - (wherein R₇ represents a methyl or ethyl group, m is an integer to make the carbon atom content of the branched alkyl group to 8 to 16, and n is an integer of 7 to 15), with a ratio (a)/(a) + (b) being 0.1 to 1, R₂ and R₃ independently represent an alkyl group having 1 to 3 carbon atoms, or a hydroxyalkyl group having 1 to 3 carbon atoms, R₄ and R₅ independently represent an alkyl group having 2 to 12 carbon atoms, R₆ represents a group or an alkyl group having 1 to 3 carbon atoms, and X⁻ represents a halogen ion or an organic anion. A detergent composition according to Claim 1, comprising in addition to said components (A) and (B) (C) 0.05 to 2% by weight of at least one cationic polymer selected from the group consisting of cationized cellulose derivatives, cationic starch, copolymers of a diallyl quaternary ammonium salt and an acrylamide, quaternarized polyvinylpyrrolidone derivatives, and polyglycol-polyamine condensates. The detergent composition according to Claim 2, wherein 0.1 to 25% by weight, based on said detergent composition, of said (A) component is one or more amidoamine-type amphoteric surface active agents represented by the following formula (III) or (IV): wherein R₈ and R₁₀ each independently represent a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, R₉ and R₁₁ each independently represent a group -CH₂COOM or -CH₂CH₂COOM (wherein M stands for a hydrogen atom, an alkali metal, or an alkanol amine), R₁₂ represents a hydrogen atom, a group -CH₂COOM, or a group -CH₂CH₂COOM (wherein M has the same meaning as defined above).

Inventors: HIROTA HAJIME, IGARASHI SAHOKO, OGINO HIDEKAZU, HIROTA, HAJIME, IGARASHI, SAHOKO, OGINO, HIDEKAZU
Applicants: KAO CORP, KAO CORPORATION
Application year: 1988
Main classification: C11D1
IPC codes: C11D1