PROCESS FOR PRODUCING POLYMER BOUND HINDERED AMINE LIGHT STABILIZERS

Abstract: N-(2,2,6,6-tetraalkyl-4-piperidinyl)imide containing polymer is prepared by blending together a mixture of a polymer containing anhydride functions and a 4-amino-2,2,6,6-tetraalkylpiperidine or its 1-alkyl or 1-acyl derivatives and heating said materials in the blend, either prior to or during the blending step to the molten stage of the polymer; thereafter, heating said blend above 180°C for a sufficient time to form the product. All volatile by-products are removed either simultaneously or concurrently with the above 180°C heating step.

Description: This invention provides an improved process for preparing polymer bound hindered amine light stabilizers by reacting 4-amino-2,2,6,6-tetraalkylpiperidines or their 1-alkylated or acylated derivatives with anhydride containing polymers or copolymers in a melt blending step at a temperature high enough to form imidized copolymers containing hindered amine light stabilizing groups. The reaction can be carried out in the presence of primary monoamino-substituted C8 to C200 alkanes or poly(oxyalkylenes) of 8-200 carbons to form imidized or partially imidized anhydride copolymers where a portion of the imidized units contains polyalkylpiperidyl (HALS) substituents and another portion contains alkyl or poly(oxyalkylene) of 8-200 carbons substituents. The reaction can be carried out in any conventional melt mixing apparatus which applies sufficient heat (e.g. 180°C to 300°C) and shear to the ingredients to obtain a satisfactory blend. BACKGROUND OF THE INVENTION This invention provides an improved process for preparing polymer bound hindered amine light stabilizers by reacting 4-amino-2,2,6,6-tetraalkylpiperidines or their 1-alkyl or 1-acyl derivatives with anhydride containing polymers or copolymers in a melt blending step to form imidized copolymers containing pendant hindered amine light stabilizing groups. It is known in the prior art to attach 4-amino-2,2,6,6-tetramethylpiperidine and 4-amino-1,2,2,6,6-pentamethylpiperidine to maleic anhydride copolymers in solution. DE-A-3,024,525 describes the reaction of cationic maleic anhydride homo- and copolymers with 4-amino-2,2,6,6-tetramethylpiperidine in solution to form the corresponding imide containing polymers. Maleic anhydride modified polyolefins have been reacted with 4-amino-2,2,6,6-tetramethylpiperidine to form the corresponding N-substituted maleimide modified polyolefins (U.S. Patent 4,520,171). The reactions were all run by refluxing the amine and maleic anhydride copolymer in an aromatic solvent and removing water as it formed. GB 2,145,100A discloses the reaction of maleic anhydride copolymers with (polyalkyl)-piperidine derivatives. It is stated that reactions of copolymers of maleic anhydride with R¹⁵-NH₂ (where R¹⁵ is a polyalkylpiperidyl group) are preferably carried out in a solvent. The imidization of maleic anhydride copolymers with ammonia or primary amines is normally carried out in a solvent or in a suspension. Various solvents that have been used for the imidization step include toluene, xylene, chlorobenzene, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, methyl ethyl ketone and acetone. Imidizations have also been run by suspending the maleic anhydride copolymers in aqueous solutions. Imidizations have also been run by including anilines such as aniline in the polymerization system. One of the problems that occurs when the imidization is run in a solvent is the long reaction time required to complete the imidization step (generally about 5-12 hours at the reflux temperature of the solvent). (Jpn Kokai Tokyo Koho JP 57,125,242 and JP 57,125,141; CA 98 35543e and 35544f; JP 82,55,901; CA 97 93354j; U.S. Pat 3,998,907). Usually the imidized polymer is isolated by precipitating it into a non-solvent and filtering off the polymer. This requires the recovery and purification of a large amount of solvent. There are isolated cases known where the imidization step is carried out in a melt blending step. JP 82,100,104 (CA 97 199015g) states that rubber modified styrene-maleic anhydride copolymers can be imidized with NH₃ or primary amines at 80-350°C in solution, dispersion in hydrocarbon solvents or in the molten state. DE-A-3,430,802 describes the preparation of thermoplastic vinylaromatic/maleimide copolymers by reaction of vinylaromatic/maleic anhydride copolymers with ammonia or primary amines (one or more) in a molar ratio of 2:1 to 1:2 at temperatures between 150 and 300°C and a pressure of 100 to 300 bar with a residence time of 0.5 to 30 minutes. The document only mentions primary monoamines such as methyl, ethyl, n-propyl, isopropyl, n-butyl, t-butyl, hexyl and cyclohexyl amines, aniline, p-toluidine, bromoaniline and chloroaniline as well as mixtures of these amines. The document does mention the use of tertiary amines as catalysts and includes triethylenediamine in this group of catalysts. The tertiary amines are not considered reactants. Primary or secondary diamines were not reacted with the anhydride copolymers because the diamines would have crosslinked the copoylmer chains and the compositions would no longer be thermoplastic. Japanese Patent 83 180,506 discloses the attachment of primary amines (toluidine) to SMA in a first extruder and then feeding the extrudate to a second vented extruder. U.S. Patent 4,591,619 discloses a process for producing an imidized copolymer by reacting a rubber modified styrene-maleic anhydride copolymer with ammonia or a primary amine in the presence of a tertiary amine at a temperature of 80 to 350°C. U.S. Patent 4,544,682 describes the reaction of anhydride copolymers with a brominated, primary aliphatic amine to form a flame retardant composition. The polymeric composition was prepared by melt blending a copolymer of a monoalkenyl aromatic monomer and an ethylenically unsaturated anhydride with a brominated primary aliphatic amine. The melt blending occurred at a temperature at or above the melting point of the copolymer but below the temperature at which the copolymer significantly degrades. The brominated primary amine was suitably any brominated primary aliphatic amine having between 1 and 4 carbon atoms, such as 2-bromoethylamine, or brominated-aromatic substituted aliphatic primary amine having between about 7 and 12 carbon atoms. Preferably 2,4,5-tribromobenzyl amine was used because of its stability, availability and reactivity. No diamines or derivatives of diamines were used, presumably because one did not want to crosslink the polymer chains. The brominated amine imparted flame retardancy to the imidized polymer. U.S. Patent 4,246,374 describes a process of imidizing acrylic polymers by reacting an acrylic polymer with anhydrous ammonia or an anhydrous primary amine (or mixture thereof) in an extruder, without added water or solvent, and applying subatmospheric pressure to at least one vent port. The polymer is non-crosslinked and soluble in dimethylformamide. The substantially anhydrous ammonia or primary amine, or mixture thereof, is introduced to the reaction zone. Ammonia and methylamine were the most preferred amines. Other suitable amines included ethyl, n-propyl, n-butyl, heptyl, hexyl, octyl, nonyl, decyl, dodecyl, hexadecyl, octadecyl, isobutyl, sec-butyl, t-butyl, isopropyl, 2-ethylhexyl, phenethyl, allyl, benzyl, para-chlorobenzyl and dimethoxyphenetyl amines, alanine, glycine, 3'-aminoacetophenone, 2-aminoanthraquinone and p-aminobenzoic acid. Also included were cyclohexylamine, 2-amino-4,6-dimethylpyridine, 3-aminophthalimide, 2-aminopyrimidine, 2-aminopyridine, 2-aminothiazole, 5-amino-1-H-tetrazole, aniline, bromoaniline, dibromoaniline, tribromoaniline, chloroaniline, dichloroaniline, trichloro-aniline, p-phenetidine and p-toluidine. The only diamines in this list are 2-amino-4,6-dimethylpyrioine, 2-aminopyridine and 2-aminopyrimidine and all of these are diamines where one of the amino groups is a primary reactive aromatic amine and the other amine is a tertiary amine which is part of an aromatic heterocyclic ring. The tertiary amine is non-reactive. These amines were proposed and not actually used in any of the examples. In the examples, there were used ammonia, methylamine, cyclohexylamine, dodecylamine, aniline, N-vinylamine, isopropylamine, n-butylamine, ethylamine, trichloroaniline, ammonia and a blend of 5% ammonia and 95% butylamine. The imidized polymers had increased thermal stability. DE-A-3,430,802 and U.S. Patents 4,544,682 and 4,246,374 purposely do not use diamines because they do not want to crosslink the anhydride copolymers or the acrylic polymers. Primary and secondary amines react with anhydride groups of the polymers to form amic acids. If the amine is a primary amine, the amic acid upon further heating can imidize to form imide copolymers. On the other hand if the amine is a secondary amine, the amic acid will not cyclize to the imide and very polar copolymers are left which are generally undesirable. This is the reason why these prior art references only use primary amines. If a typical primary-secondary diamine was used the primary amine could react with one anhydride copolymer chain to form an imide and the secondary amine could react with another anhydride copolymer chain to form an amic acid. If many of these reactions occurred, one would end up with a crosslinked network and the product would no longer be thermoplastic. This could cause plugging of the extruder if the reaction was carried out in an extruder. This invention is directed to an improved process for the preparation of N-(2,2,6,6-tetraalkyl-4-piperidinyl)imide containing polymer by blending together: (a) a polymer containing anhydride functions either on the backbone, on grafted side chains, as pendant units or as combinations thereof, and (b) a 4-amino-2,2,6,6-tetraalkylpiperidine, its 1-alkyl or 1-acyl derivative, heating said materials, which may or may not have reacted to form the corresponding amic acids, to the molten state in a melt mixing apparatus, for a sufficient time and at a sufficient temperature above 180°C but below the degradation temperature of the copolymer or polymeric blend, so that essentially all of the amino-substituted polyalkylpiperidine in the product is present as pendant substituted imide groups and simultaneously or concurrently therewith removing all volatile by-products of the reaction to recover said product. The blending of components (a) and (b) is preferably carried out in the presence of an inert solvent. In a preferred embodiment ancillary primary monoamino-substituted 8-200 carbon alkanes or poly(oxyalkylenes) are blended together with the other components, so that essentially all of the amino-substituted polyalkylpiperidine and alkanes or poly(oxyalkylenes) in the product are present as pendant substituted imide groups. In another preferred embodiment inert polymers are blended together with the other components. Any inert solvents might be removed before heating the materials and the materials can be heated under an inert atmosphere. In a further preferred embodiment of the invention the anhydride containing polymer is a maleic anhydride copolymer, the molar ratio of the anhydride to the amine is greater than 1:1, the reaction is carried out in a vented extruder, plastograph or Banbury mixer in an inert atmosphere at a temperature above 180°C and below 300°C for a period of 30 seconds to 1 hour and the water of reaction is removed either under vacuum or in a post drying step or under reduced pressure through the vent in the extruder. Preferably, the maleic anhydride copolymer is a styrene-maleic or octadecene-maleic anhydride copolymer, the amine is 4-amino-2,2,6,6-tetramethylpiperidine and the amine is injected into the molten polymer in the extruder at a temperature above the softening point of the copolymer and the molten polymer is conveyed through the extruder at a temperature within the range of 240°C to 270°C. The invention is further directed to a composition prepared by blending together (a) a polymer containing anhydride functions either on the backbone, on grafted side chains, as pendant units or as combinations thereof, (b) a 4-amino-2,2,6,6-tetraalkylpiperidine, its 1-alkyl or 1-acyl derivative, and (c) ancillary primary monoamino-substituted 8-200 carbon alkanes or poly(oxyalkylenes), heating said materials, which may or may not have reacted to form the corresponding amic acids, to the molten state in a melt mixing apparatus, for a sufficient time and at a sufficient temperature above 180°C but below the degradation temperature of the copolymer or polymeric blend, so that essentially all of the amino-substituted polyalkylpiperidine and alkanes or poly(oxyalkylenes) in the product are present as pendant substituted imide groups and simultaneously or concurrently therewith removing all volatile by-products of the reaction to recover said product. Preferably 15-95% of the anhydride content of a maleic anhydride copolymer is imidized by the 4-amino-2,2,6,6-tetramethylpiperidine and 5-85% of the anhydride content is imidized by the monoamine-terminated poly(oxyalkylene) or monoamine-terminated alkane of 8-200 carbons. It is further preferred that the anhydride containing polymer is an octadecene-maleic anhydride alternating copolymer, the primary alkyl amine is dodecyl-amine and the primary monoamine-terminated poly(oxyalkylene) is a primary monoamine-terminated block copolymer of ethylene oxide and propylene oxide of molecular weight of approximately 300 to 600. The polymer (a) is a polymer containing anhydride functions either on the backbone, on grafted side chains, as pendant units or as combinations thereof with recurring units which may be selected from wherein x is 0 or 1 and R³ and R⁴ are independently selected from hydrogen, alkyl of 1-6 carbons, cycloalkyl of 5-7 carbons, phenyl, Cl or Br. Description of the Invention Cyclic anhydrides and primary amines react to give a product with both amide and carboxylic acid functional groups. This amide-carboxylic acid is called an amic acid. If an amic acid is heated sufficiently, further reaction occurs in which a molecule of water is lost and a ring is formed with two carbonyl groups attached to the amide nitrogen. This product is called an imide. Depending upon the substitution of the anhydride and amine, the formation of the amic acid and its conversion to imide occur under a wide range of reaction conditions, particularly reaction temperature and duration. Temperature is usually the dominant factor. Below a certain temperature (about 100°C) the amic acid will not convert to the imide without the aid of a coreactant. Above a certain temperature (about 175°C-200°C) an amic acid, once formed, will begin conversion to the imide immediately. Short reaction times, like those obtainable in a melt blender or extruder can yield mixtures of both amic acid and imide. At intermediate temperatures the reaction duration becomes important and mixtures of amic acid and imide result. In this invention it is important that essentially all the amic acid is converted over to the imide. The imidization process of this invention may be represented by the following sequential reactions: where R is and R₁ is hydrogen, an alkyl group of 1 to 20 carbons or an aliphatic acyl group of 1 to 10 carbons or an aromatic acyl group of 7 to 12 carbons. R₂ is hydrogen or lower alkyl of 1 to 4 carbons. R₃ and R₄ are independently selected from hydrogen, alkyl of 1 to 6 carbons, cycloalkyl of 5 to 7 carbons, phenyl, chlorine or bromine. The melt blending of the anhydride containing polymer or copolymer, preferably a maleic anhydride copolymer, and the amino substituted polyalkylpiperidine of general formula I where R₁ and R₂ are as previously defined, is carried out at temperatures at or above the melting point of the anhydride copolymer but below the temperature at which the copolymer significantly degrades. The temperature will generally be between about 180°C and about 300°C depending upon the particular anhydride copolymer. The melt blending is continued at a sufficiently high temperature for a length of time sufficient to convert essentially all the amic acid, formed from the reaction of the amino-substituted polyalkylpiperidine, to the imidized form. The imide group that forms from the sequential reactions has a 2,2,6,6-tetralkyl-4-piperidyl group or a 1-alkyl or acyl-2,2,6,6- tetraalkyl-4-piperidyl group substituted on the imide nitrogen. The polyalkyl-4-piperidyl group which will be referred to as the HALS group is a light stabilizing group and incorporates light stabilizing properties into the copolymer. The HALS group should be present in the copolymer in an amount sufficient to stabilize the copolymer against photooxidative degradation. Generally 0.1 to 5 weight percent of the HALS group is sufficient and in most cases 0.2 to 1.0 weight percent is sufficient. If the polymer is going to be used as a masterbatch or as a stabilizer for other polymers, copolymers, polymer alloys or blends, higher levels of the HALS group should be attached. Levels up to 58 weight percent of the HALS group are possible depending upon the composition of the anhydride copolymer. Since water is formed in the second step of the reaction, it is preferable to have a method of removing the water as it is formed. If the reaction is carried out on a melt blending apparatus there is open to the atmosphere (preferably under a nitrogen blanket) the water vaporizes off as it is formed. However, in a non-vented extruder the water has no way to escape so it stays in the polymer under pressure and upon exiting the extruder die the polymer foams. In this case the polymer is preferably ground up, dried and re-extruded to obtain a suitable extrudate. The second extrusion can be eliminated by removing the water under vacuum using a vented extruder or in a drying oven. The residence time in the melt blending step may vary from 30 seconds to 1 hour depending upon the reactivity of the anhydride copolymer, the melt blending temperature and the degree of mixing. Preferably the reaction is run above 200°C and the residence time is between 1 minute and 15 minutes and most preferably between 3 minutes and 10 minutes. At temperatures below 230°C the reaction may stop to some degree at the amic acid stage and imidization may be incomplete. This occurs to some degree with styrene-maleic anhydride copolymers (SMA). This may be overcome by raising the temperature or increasing the residence time. The degree of imidization of the anhydride copolymer is dependent upon the mole ratio of the 4-amino-polyalkylpiperidine to the initial anhydride content of the copolymer. If the mole ratio is less than 1 there will be residual anhydride in the product. If the mole ratio is greater than 1 there will be residual 4-amino-polyalkylpiperidine in the reaction mixture which will have to be removed in the devolatilization step. The mole ratio of the 4-amino-polyalkylpiperidine to the anhydride in the copolymer may vary from 0.01:1 to 1:1. However for economical reasons and ease of purification it is preferable to hold the mole ratio slightly below 1:1, most preferably from about 0.7:1 to about 0.95:1. This ensures that all the 4-amino-polyalkylpiperidine has reacted and extensive devolatilization techniques do not have to be employed to remove residual 4-amino-polyalkylpiperidine from the product. If a mixture of a 4-amino-polyalkylpiperidine and a primary monoamino-substituted 8-200 carbons alkane or poly(oxyalkylene) is employed, the mole ratio of the combined amines to the anhydride in the copolymer may vary from 0.015:1 to 1:1. However, it is preferable to hold the combined mole ratio of the amines to the anhydride content of the copolymer slightly below 1:1. Most preferably, the mole ratio of the 4-amino-polyalkylpiperidine to the anhydride will be 0.5:1 to about 0.9:1 and the mole ratio of the C₈ to C₂₀₀ amine to the anhydride will be 0.005:1 to about 0.45:1. The pressure can be varied throughout the range of 0.5 to 300 bar. Generally the pressure will be around the partial pressure of the 4-amino-polyalkylamine at the reaction temperature if the reaction is not run at atmospheric pressure. The reaction can be carried out in the presence of a tertiary amine catalyst such as triethylamine but this is usually not necessary and complicates the devolatilization step. The reaction can be carried out in any conventional melt mixing apparatus such as a plastograph, Banbury mixer, two roll mill, single or twin screw extruder, static mixer, plug flow reactor or any other method which applies sufficient heat (e.g. 180°C to 300°C) and shear to the ingredients to obtain a satisfactory blend. Preferably, the reaction is carried out in an extruder. The 4-amino-polyalkylpiperidine and the primary monoamino-substituted 8-200 carbons alkanes or poly(oxyalkylenes) may be absorbed onto the surface of the anhydride containing polymer prior to adding it to the extruder or preferably the amine may be injected into the molten polymer under pressure in the first or second zone of the extruder. The water that forms in the reaction as well as any excess amine or other volatile compounds are removed either upon exiting the extruder or preferably by a vent near the end of the extruder which is under reduced pressure. The devolatilization step may also take place by running the extrudate through the extruder again, through a second vented extruder, or through a thin film evaporator. Sufficient mixing must take place in the melt blending step to obtain a uniform distribution of the amines in the anhydride containing polymer or copolymer. Preferably, this is accomplished by metering the amine(s) into the molten polymer in the first or second zone of an extruder at a temperature above the softening point of the polymer. Since the imidization of the anhydride containing polymer or copolymer normally raises the softening point of the polymer, it is preferable to run the reaction above the softening point of the product as well. Since the hindered amines rapidly react with oxygen at elevated temperatures, the addition of the amine, the reaction and the cooling and isolation of the product should be carried out in an inert atmosphere, e.g., nitrogen, argon, helium, etc. to prevent degradation or discoloration of the product. Preferably, the reaction is run continuously by continuously feeding the anhydride polymer or copolymer into the melting zone of an extruder where the 4-amino-polyalkylpiperidine or its mixture with the 8-200 carbons amines is continuously injected into the molten polymer in the proper mole ratio and the uniform mixture is conveyed down the extruder at a temperature sufficient to imidize all the amine for a length of time sufficient to convert any residual amic acid to imide, past a vent under reduced pressure where all the water formed as well as any other volatile components are continuously removed and the product continuously flows out of a die head, is cooled and pelletized. The reactions may be monitored by the water evolution (vented extruder) or by infrared spectroscopy of chloroform solutions of the product, following the conversion of the anhydride band around 1780 cm⁻¹ to an imide band at 1680 cm⁻¹. Thus, it is quite easy to monitor the process and manipulate the process variables to obtain essentially complete imidization. The optimum reaction temperatures and residence times vary with the particular anhydride copolymer and melt processing equipment. When the reaction is carried out in a mixer or on a roll mill under an inert atmosphere, the modified polymer is cooled under an inert atmosphere, ground up in a grinder and dried in an oven at elevated temperatures, preferably under vacuum or an inert atmosphere. When the reaction is carried out in an extruder, the extrudate is cooled, either by an inert gas or by a cooling bath, dried if necessary, pelletized or ground up and, if necessary, dried in an oven. If the hot polymers are exposed to the air they discolor quite readily. Since 4-amino-2,2,6,6-tetramethylpiperidine and its lower alkyl 1-substituted derivatives are quite volatile, it is preferable to run the melt blending with these amines in an extruder to minimize loss of the starting amines through volatilization and it is most preferable to inject these amines into the molten polymer under pressure along the extruder barrel rather than adding them through the hopper. If the anhydride containing polymer of copolymer contains a high percentage of anhydride and most of the anhydride is to be imidized in an extrusion step it may be advantageous to attach the amines of this process in a series of extrusions instead of all in one step. It is also within the scope of this invention that the anhydride polymers or copolymers may be partially imidized with other functional amines or hydrazides which will add advantageous properties to the polymers or copolymers. For example, reaction of the anhydride polymers or copolymers either before, after or during the attachment of the amino-substituted polyalkylpiperidine with trialkoxysilylalkylamines such as aminomethyltrimethoxysilane, 3-aminopropyltriethoxy- silane or 3-aminopropyltriethoxysilane or 3-aminopropyltris (n-propyloxy)silane (see U.S. Patent 3,755,354) will enhance the ability of the polymer or copolymer system to accept fillers. Likewise, reaction of chlorinated or brominated primary amines or hydrazides will contribute flame retardant properties to the polymers or copolymers. Antistatic properties can be introduced in a similar manner. For example, the anhydride copolymers may be partially reacted with 3-dimethylaminopropylamine to form the 3-dimethylaminopropylimide and then in a subsequent step the dimethylaminopropyl group may be quarternized with an alkyl halide such as methyl iodide (U.S. Patent 3,555,001). A particularly preferred embodiment of this invention is to partially imidize the anhydride containing polymer or copolymer with a medium or high molecular weight primary monoamino-substituted alkane or poly- (oxyalkylene), either before, after or during the attachment of the amino-substituted polyalkylpiperidine. The attachment of such supplementary amines to the copolymers lowers the Tg of the polymeric composition allowing lower processing temperatures and energy requirements. In addition the attachment of such supplementary amines increases the compatibility of the polymer bound hindered amine light stabilizers produced in the invention with various polymeric compositions such as polyolefins. For example, the attachment of primary monoamino substituted 8-200 carbons alkanes or poly(oxyalkylenes) increase the compatability of the polymer bound hindered amine light stabilizers in polymeric compositions derived from polyolefins such as ethylene polymers and copolymers. Particularly preferred are the mono-amine-terminated poly(oxyalkylenes) of molecular weight 250-2500 (for example mono-amine-terminated block copolymers of ethylene oxide and propylene oxide sold commercially under the trade name Jeffamine™, products of Texaco Chemical Company). Useful primary alkylamines are for, example, n-octyl, t-octyl, dodecyl, undecyl, tetradecyl, hexadecyl and octadecylamines. These compositions derived from the imidization of anhydride containing polymers or copolymers, preferably maleic anhydride copolymers, by a combination of an amino-substituted polyalkylpiperidine and 8-200 carbons mono primary alkylamines or mono amine-terminated poly(oxyalkylenes) or mixtures thereof, have lower Tg's, process easier, and are more compatible with other polymeric compositions such as polyolefins than the corresponding anhydride containing polymers imidized with the amino-substituted polyalkylpiperidine alone. The large alkyl substituent on the imide may in some cases also contribute plasticizing, lubricating or mold release properties or combinations thereof to the ultimate polymeric compositions to be stabilized. Generally, the polymer bound hindered amine light stabilizers produced by this invention can be processed at lower temperatures if the anhydride portion of the starting polymer or copolymer is partially imidized with one of the above higher molecular weight mono primary alkyl amines or poly(oxyalkylene)amines and the greater the partial imidization with these amines and/or the greater the size of the alkyl or poly(oxyalkylene) group the more the processing temperature may be decreased. The partial imidization of the anhydride containing polymer or copolymer with a monoamine-terminated Jeffamine™ has a beneficial effect on the compatibility and mold release properties of a maleic anhydride copolymer imidized with an amino-substituted polyalkylpiperidine. Preferably 15-95% of the anhydride content of the copolymer should be imidized with the amino-substituted polyalkylpiperidine and 5-85% of the anhydride content imidized with ancillary mono primary alkyl or poly(oxyalkylene)amines. It is also within the scope of this invention that the amines, either the amino-substituted polyalkylpiperidine, the ancillary amines or both may be preblended with the anhydride containing copolymer prior to the melt blending step. The preblending step may be carried out neat, in solution or in the presence of an inert polymer. An especially preferred method is to add the amine(s) to a pulverized grade of the anhydride copolymer in a twin shell blender to obtain uniform distribution of the amine(s) on the anhydride copolymer. The preblending step may or may not result in reaction of the amine(s) with the anhydride to form the corresponding ammonium salts or amic acids. If the mixing is carried out in a solvent, the majority of the solvent is removed before proceeding to the melt processing step. If partial or no reaction occurred during the preblending step, the unreacted components will react to first form amic acid(s) and then will subsequently cyclize to the imide structure(s) with the evolution of water. If reaction occurred during the preblending step, the preformed salts or amic acids will cyclize to the desired imides during the melt processing step. The process of this invention can be practiced in the presence of inert polymers such as HIPS, ABS, MBS, ASA, polystyrene, polyolefins, various copolymers of polystyrene and rubbery materials, PPO, PPE and various combinations thereof. Starting Materials The process of this invention can be conducted using various hindered amines containing primary amino substituents which react with the anhydride containing polymers or copolymers. A non-limiting list of these includes: 4-amino-2,2,6,6-tetramethylpiperidine 4-amino-1,2,2,6,6-pentamethylpiperidine 4-amino-1-butyl-2,2,6,6-tetramethylpiperidine 4-amino-2,6-diethyl-2,3,6-trimethylpiperidine 4-amino-2,2,3,6,6,-pentamethylpiperidine 4-amino-1-octyl-2,2,6,6-tetramethylpiperidine 4-amino-1-dodecyl-2,2,6,6-tetramethylpiperidine 4-amino-2,6-diethyl-2,3,6-trimethylpiperidine 4-amino-2,6-diethyl-1,2,3,6-tetramethylpiperidine 4-amino-1-ethyl-2,2,6,6-tetramethylpiperidine 4-amino-1-acetyl-2,2,6,6-tetramethylpiperidine Examples of supplementary 8-200 carbons amines include the following list of primary amines: n-octylamine, nonylamine, decylamine, undecylamine, dodecylamine, tridecylamine, tetradecylamine, hexadecylamine, octadecylamine and Jeffamines™ M-300, M-360 and M-600. The Jeffamines™ are products of Texaco Chemical Co. M-300 and M-600 are predominantly poly(propylene oxide) of molecular weights 300 and 600 respectively containing one terminal amino functionality. M-360 is a mixed polyethylene oxide polypropylene oxide polymer with a ratio of two moles of propylene oxide to 3 moles of ethylene oxide. It has an approximate molecular weight of 360 and one terminal amino functionality. Anhydride Containing Polymers and Copolymers In general, any polymer or copolymer containing cyclic anhydride groups, either on the polymer backbone, on grafted side chains, as pendant units or as combinations thereof is suitable for attachment of the amino substituted polyalkylpiperidine to form the polymer bound hindered amine light stabilizers. Due to cost and ease of preparation, the anhydride containing polymers are preferably polymers or copolymers of maleic anhydride. The polymer bound stabilizers are prepared in a melt blending step from anhydride polymers or copolymers with recurring units selected from in which the units occur either on the polymer backbone, on grafted side chains, as pendant units or as combinations thereof and amino substituted polyalkylpiperidines, wherein x is 0 or 1 and R₃ and R₄ are as previously defined. Suitable anhydride containing copolymers useful for use in this invention include but are not limited to: (a) styrene-maleic anhydride copolymers; (b) alternating copolymers of maleic anhydride and alpha-olefins; (c) copolymers of alkyl vinyl ethers and maleic anhydride; (d) maleic anhydride modified polyolefins; (e) maleic anhydride adducts of hydrogenated polymers or copolymers; (f) maleic anhydride adducts of EPDM; and other anhydride copolymers. (a) Styrene-maleic anhydride copolymers These copolymers are a general class of compounds of the alternating copolymers of styrene and maleic anhydride, or the non-equimolar copolymers containing less than about 50 mole percent of the anhydride monomer. The styrene may be replaced in whole or in part by other vinylaromatic monomers such as alpha-methylstyrene, nuclear methylstyrenes, ethylstyrene, isopropylstyrene, t-butylstyrene, chlorostyrenes, dichlorostyrenes, bromostyrenes, dibromostyrenes, vinylnaphthalene and the like. Similarly, the maleic anhydride can be replaced in whole or in part by another alpha, beta - unsaturated cyclic dicarboxylic acid anhydride such as itaconic, aconitic, citraconic, mesaconic, chloromaleic, bromomaleic, dichloromaleic, dibromomaleic, phenylmaleic and the like. The preferred alpha, beta - unsaturated cyclic anhydride is maleic anhydride. The copolymer may also contain a termonomer such as a 1-3 carbons alkyl acrylate or methacrylate, acrylonitrile, methacrylonitrile, acrylamide, methacrylamide, acrylic acid or methacrylic acid. Suitable copolymers may be prepared by any of the several methods available for the preparation of styrene-maleic anhydride copolymers or they may be purchased commercially. Non-equimolar copolymers may be prepared by solution polymerization directly from the respective monomers by the incremental addition of the reactive monomer as taught by U.S. Patent 2,971,393; by a continuous recycle polymerization process such as described in U. S. Patents 2,769,804 and 2,989,517; by the suspension polymerization process described in U. S. Patent 3,509,110 or by numerous known variations. Also suitable are the rubber-modified copolymers where 5 to 40 percent by weight of one of the known elastomers has been incorporated into the vinylaromatic-alpha, beta - unsaturated dicarboxylic acid anhydride copolymer. The elastomers may be incorporated into the anhydride copolymers by blending, mixing or copolymerizing the monomers in the presence of the rubber. Suitable rubbers, or elastomers, include conjugated 1,3-diene rubbers, styrene-diene copolymer rubbers, acrylonitrile-diene copolymer rubbers, ethylene-propylene copolymer rubbers, ethylene-propylene-diene terpolymer rubbers, acrylate-diene copolymer rubbers, and mixtures thereof. Preferred rubbers are diene rubbers such as homopolymers of conjugated dienes such as butadiene, isoprene, chloroprene, and piperylene and copolymers of such dienes with up to 50 mole percent of one or more copolymerizable mono-ethylenically unsaturated monomers, such as styrene, substituted styrenes, acrylonitrile, methacrylonitrile and isobutylene. Preferably, the elastomers are incorporated into the monomer mixture prior to polymerization using, for example, the method of U.S. Patent 4,097,551 or U. S. Patent 4,486,570 in which a mixture of at least two rubbery additives are present during the polymerization. Particularly suitable for use are the non-equimolar copolymers of styrene and maleic anhydride designated Dylark™ copolymers, commercially available from ARCO Chemical Company, division of Atlantic Richfield Company. Suitable Dylark™ copolymers include those of the 200 series and the 300 series and Dylark™ 600 and 700. Those copolymers designated Dylark™ 250, Dylark™ 350 and Dylark™ 700 are impact modified and are especially useful. The SMA™ resins are low molecular weight styrene-maleic anhydride copolymers (MW 700-1900) and are also useful in this invention. The low molecular weight SMA resins SMA™ 1000, 2000 and 3000 available from ARCO are also useful in this invention. Also suitable are the styrene-maleic anhydride copolymers or rubber modified styrene-maleic anhydride copolymers where a portion of the maleic anhydride groups are converted to maleimide groups or the N-substituted maleimide groups. The partially imidized copolymers can be prepared by treating the SMA polymer with a primary amine in a post polymerization step as described in U. S. Patent 3,998,907 or during the polymerization as described in U. S. Patent 4,381,373. The molar ratio of the amine to the maleic anhydride in the copolymer should be less than 0.8 to allow attachment of the amino substituted polyalkylpiperidines. The formation of the maleimide groups that don't contain stabilizer groups may be formed before, during or after the formation of the maleimide groups containing stabilizer groups. Suitable amines for this purpose are ammonia, primary alkyl amines and primary aryl amines. Long chain primary alkyl amines will beneficially aid in flow properties of the system while primary aryl amines will increase the thermal stability and heat distortion properties of the system. Aniline is the preferred aromatic amine for increasing the thermal stability of the polymer system. Brominated or chlorinated primary amines will increase the fire retardancy of the system. The SMA copolymer may optionally contain a termonomer such as a 1-3 carbons alkyl acrylate or methacrylate, acrylonitrile, methacrylonitrile, acrylamide, methacrylamide, acrylic acid or methacrylic acid. Rubber modified terpolymers of styrene, maleic anhydride and alkyl (1-3) methacrylates are described in U. S. Patent 4,341,695. Incorporation of the methacrylate comonomer at specific levels (2 to 20% by weight) increases the heat distortion temperature of the polymer, raises the tensile strength and increases the gloss of the rubber-modified polymer. The polymeric composition is conveniently prepared by dissolving the rubber in a solution of the monoalkenyl aromatic component and the methacrylate ester in a suitable solvent and then polymerizing the solution with the anhydride component in the manner described in, for example, U. S. Patents 2,971,939, 3,336,267 and 3,919,354. The Cadon™ resins (Monsanto Chemical Company) are a commercial series of styrene-maleic anhydride polymer alloys with ABS. Rubber-modified versions are also available and are also suitable for this invention. Also suitable are the rubber modified styrene maleic anhydride resins described in U. S. Patent 4,522,983 where a minor amount of a nuclear substituted methylstyrene is included in the composition to increase the impact strength of the composition. The styrene-maleic anhydride polymers may be further modified by copolymerizing the monomers in the presence of other monomers. In addition to the acrylates, methacrylates, acrylonitrile and methacrylonitrile previously mentioned, other suitable monomers include the ethlenically unsaturated carboxylic acids, preferably acrylic and methacrylic acids, acrylamide and methacrylamide, dialkylamino alkyl (1-6 carbons) acrylates or methacrylates such as dimethylaminoethyl acrylate or methacrylate, and vinyl esters derived from saturated carboxylic acids of 2 to 22 carbon atoms such as vinyl acetate or vinyl propionate. Further modification of the styrene-maleic anhydride copolymers can be accomplished by carrying out the copolymerization in the presence of crosslinking monomers having two or more ethylenically unsaturated double bonds such as divinylbenzene, 1,4-butadiene, divinyl ether, ethylene glycol dimethacrylate, butanediol dimethacrylate, triallyl cyanurate and similar type compounds. The crosslinking monomers are employed in amounts of from 0.01 to 5, preferable from 0.1 to 2 mole percent based on maleic anhydride. (b) Alternating copolymers of maleic anhydride and alpha-olefins These are exemplified by U.S. Patents 3,553,177, 3,560,455, 3,560,456 and 3,560,457. Each of these patents describes a copolymer of maleic anhydride with a specific alpha-olefin such as 12-30 carbons alpha-olefins. The copolymers of 6-10 carbons alpha-olefins are known as shown by U. S. Patent 3,488,311. Terpolymers of maleic anhydride and at least one lower alpha-olefin and at least one higher alpha-olefin are also known, as shown by Canadian Patent 1,180,497. The alternating copolymers may be prepared by conventional polymerization processes including those described in U. S. Patents 3,553,177, 3,560,455, 3,560,456, 3,560,457 and 3,488,311. PA-18 is an example of a commercially available alternating copolymer of maleic anhydride and octadecene-1 (product of the Chevron Chemical Company). Also suitable for this invention are the terpolymers disclosed in U. S. Patents 4,522,992 and 3,723,375. These are basically terpolymers of cyclic alpha, beta - unsaturated dicarboxylic acid anhydrides, aromatic mono-alkenyl monomers and higher 1-alkenes. Preferably they are terpolymers of styrene, maleic anhydride and alpha-olefins having 10 or more carbon atoms. Both pure alkenes and mixed alkenes can be utilized in preparing the terpolymers. (c) Copolymers of alkyl vinyl ethers and maleic anhydride These copolymers are readily prepared in bulk or solution using free radical initiators (e.g. lauroyl peroxide) (British Patent 1,117,515). Low, medium and high molecular weight grades are commercially available. Commercial grades include the Gantrez™ resins (General Aniline and Film). Suitable alkyl vinyl ethers for copolymerization include methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, amyl, isoamyl, hexyl, heptyl, octyl, 2-ethylhexyl, nonyl, decyl, dodecyl, hexadecyl and octadecyl vinyl ethers. (d) Maleic anhydride modified polyolefins These polymers have the general following formula: where P- represents an olefin polymer residue which is based on a preponderance of ethylene, propylene or 1-butene, and having a valence of p and R³ and R⁴ are as previously defined. It can be either a high or low density polyethylene residue, a polypropylene residue or a residue of a copolymer of ethylene with 1-butene, a residue of a copolymer of ethylene and propylene, a residue of a propylene-butene copolymer or a residue of such a propylene copolymer with an olefin having up to about six carbon atoms. The maleic anhydride-modified polyolefins are materials containing about 0.2 to 9% by weight of combined maleic anhydride, preferably about 2 to 5%. One embodiment of these materials is a commercially available product, sold under the trademark "Hercoprime™" by Hercules Incorporated. Polyethylene or polypropylene modified with maleic anhydride is available commercially from Enron Chemical Co. under the trademark "Plexar™". Any polymer or copolymer of ethylene, propylene, or 1-butene can be modified via the maleic anhydride moiety to form the substrate molecule, including polyethylene, polypropylene, ethylene-propylene copolymer, propylenebutene-1 copolymer, or butene-1-ethylene copolymer. The most frequently encountered and the preferred maleic anhydride modified polyolefin is that based on polypropylene. The preparation of maleic anhydride modified polypropylene is described in U.S. Patent 3,483,276. Briefly, the preparation consists of exposing the olefin polymer to a material or condition which will induce the formation of active, free radical sites thereon with which maleic anhydride can react. Active centers can be induced, e.g., by subjecting the polymer to the action of high energy ionizing radiation such as gamma rays, X-rays, or high speed electrons; by contacting it, either as a solid or a solution in a solvent, with a free radical producing material such as dibenzoyl peroxide, dilauroyl peroxide, dicumyl peroxide or t-butyl perbenzoate; or by simply milling it in the presence of air. The preferred method is the reaction of the polyolefin with maleic anhydride in solvent solution in the presence of a free radical initiator. The graft modification of EPDM by maleic anhydride in the presence of dicumyl peroxide and benzoyl peroxide is described by DeVito and co-workers (G. DeVito, N. Lanzetta, G. Maglio, M. Malinconico, P. Musta, R. Palumbo, J. Polym. Sci., Polym. Chem, Ed., 22, pp 1335-47 (1984)). U. S. Patent 4,506,056 describes a process for grafting maleic anhydride onto molten polymers or copolymers using a free radical catalyst in which crosslinking or degradation of the polymers is controlled or eliminated in the presence of scavengers which inhibit the homopolymerization of maleic anhydride. (e) Maleic anhydride adducts of hydrogenated polymers or copolymers There are polymeric products containing pendant succinic anhydride groups which are formed by reacting maleic anhydride with hydrogenated polymers of conjugated dienes or hydrogenated copolymers of conjugated dienes and vinyl aromatic hydrocarbons containing a residual unsaturation level of from 0.5 to 20 percent of their original unsaturation level prior to hydrogenation. The reaction, which is conducted by heating a mixture of the maleic anhydride and hydrogenated polymer or copolymer containing residual unsaturation, proceeds by means of a reaction mechanism referred to as an "ENE" type reaction. The maleic anhydride adds to the unsaturation of the polymer to form the polymer product containing the pendant succinic anhydride groups. This polymer, by virtue of the pendant anhydride groups, can be reacted with amine substituted polyalkylpiperidines in a melt blending process to form the polymer bound hindered amine light stabilizers of this invention. The amounts of maleic anhydride employed in the reaction can vary considerably depending on the specific nature of the hydrogenated polymer and the properties desired in the final product. In general, the amount of maleic anhydride employed may range from 0.1 to about 25 percent by weight based on total weight of maleic anhydride and hydrogenated polymer with a preferred amount being from 0.2 to 5 percent by weight. Various polymers of conjugated dienes and copolymers of conjugated dienes and vinyl aromatic hydrocarbons may be hydrogenated for use in preparing the maleic anhydride adduct component of the compositions of the invention. Polymers of conjugated dienes which may be hydrogenated include polymers derived from one or more conjugated diene monomers. Thus, polymers derived from a single conjugated diene such as 1,3-butadiene (i.e., a homopolymer) or polymers derived from two or more conjugated dienes such as, for example, 1,3-butadiene and isoprene or 1,3-butadiene and 1,3-pentadiene (i.e., a copolymer) and the like may be utilized. Copolymers which may be hydrogenated include random copolymers of conjugated dienes and vinyl aromatic hydrocarbons and block copolymers of conjugated dienes and vinyl aromatic hydrocarbons which exhibit elastomeric properties. (f) Maleic anhydride adducts of EPDM These polymers are prepared by the thermal addition of maleic anhydride to elastomeric copolymers of ethylene and propylene which have a substantially saturated hydrocarbon backbone chain and unsaturated hydrocarbon side-chains. The preparation of these adducts is described in U.S. Patent 3,884,882. (g) Other anhydride copolymers Examples of these copolymers are as follows: 1) vinyl acetate-maleic anhydride copolymer 2) ethylene-vinyl acetate-maleic anhydride terpolymer 3) isobutylene-maleic anhydride copolymer 4) graft polyols containing styrene-maleic anhydride copolymer in the grafted chain 5) styrene-maleic anhydride-2,4,6-tribromophenyl acrylate terpolymer 6) maleic anhydride-divinylbenzene-styrene terpolymer 7) ethylene-maleic anhydride-styrene graft copolymer 8) methyl methacrylate-maleic anhydride copolymers 9) butyl methacrylate-maleic anhydride-styrene copolymer. 10) ethylene-maleic anhydride copolymers (Monsanto) Other suitable maleic anhydride copolymers include the terpolymers of anhydrides, aromatic mono-alkenyl monomers and higher 1-alkenes described in U.S. Patent 4,522,992, the tribromophenyl acrylate-epichlorohydrin-maleic anhydride-styrene copolymer described in U. S. Patent 4,108,943, and the methyl methacrylate-maleic anhydride-styrene copolymers disclosed in Japanese Patent 59/221,314 and 59/221,315 (CA102: 150317x and 150318y), divinyl ether-maleic anhydride copolymers from Adica Labs (Pivan), a polybutadiene-polystyrene-maleic anhydride terpolymer referred to as Ricon™ 184/MA, a product of Colorado Chemical Specialties, Inc., and ethylene/vinyl acetate copolymer grafted with maleic anhydride such as Modic E 310 K a product of Mitsubishi Chemical Industries Co. Anhydride polymers containing glutaric anhydride units can also be used in this invention. Such polymeric anhydrides are available from polymers and copolymers of acrylic and methacrylic acid by heating under dehydrating conditions, with or without a catalyst (European Patent 76,691). In addition poly(maleic anhydride) such as Belcene, a product of Ciba-Geigy, is also suitable in this invention. EXAMPLES The following maleic anhydride copolymers were used in the preparation of the polymer bound stabilizers of the examples. Cadon™ resins are a commercial series of styrene-maleic anhydride polymer alloys with ABS and were obtained from the Monsanto Chemical Co. PA-18 is a copolymer of 1-octadecene and maleic anhydride and was obtained from Chevron Chemical Co. It has a molecular weight of about 50,000. The Dylark™ resins are high molecular weight non-equimolar copolymers of styrene and maleic anhydride commercially available from Arco Chemical Company. Dylark™ 250 and 700 are rubber modified while Dylark™ 232 is not. Dylark™ 250 is prepared by polymerizing about 92% by weight styrene monomer and about 8% by weight maleic anhydride, in the presence of about 18 parts by weight Stereon™ Rubber 720 (Firestone Synthetic Rubber and Latex Co.) per 100 parts of combined styrene and maleic anhydride. 4-Amino-2,2,6,6-tetramethylpiperidine and dodecylamine were purchased from Aldrich Chemical Co. Jeffamine™ M-360 and M-600 were obtained from the Texaco Chemical Co. The HIPS used was Dow Styron 489W. The poly(phenylene oxide) was purchased from Aldrich Chemical Co. The polypropylene was Profax 6501 purchased from Himont. EXAMPLE I Attachment of 4-Amino-2,2,6,6-tetramethylpiperidine to Maleic Anhydride Copolymers in a Plastograph A. Dylark™ 232 (200 grams) was melted in a Brabender Prep Center Mixer (R.E.E.G.) at 200°C under a nitrogen atmosphere while mixing at a speed of 30 rpm. To the molten polymer were added 16 grams of 4-amino-2,2,6,6-tetramethylpiperidine dropwise over approximately 5 minutes. The temperature of the molten polymer rose to 220°C during the addition. The molten polymer was mixed to additional 5 minutes after the addition was complete. The mixing temperature was approximately 215°C ± 3°C. The hot polymer was removed from the mixer, cooled and ground up in a grinder. A 0.5 gram sample of the modified polymer was stirred with 20 ml of warm chloroform for 1 hour. The sample was not completely soluble and formed a viscous jelly with the chloroform. An infrared scan of the jelly indicated that an imide band had formed at 1680 cm⁻¹ and the residual anhydride band at 1770 cm⁻¹ had decreased in intensity and was about 2/3 as intense as the imide band. B. The reaction was repeated only this time the Dylark™ 232 was heated to 220°C prior to the addition of the 4-amino-2,2,6,6-tetramethylpiperidine. The temperature of the molten polymer rose to 228°C during the addition and held around 227°C ± 3°C during the 5 minute mixing period. During the addition there were some puffs of white vapor when the amine hit the hot polymer indicating some volatilization of the volatile amine was occurring before it could react. The 0.5 gram sample of the ground up product dissolved to a greater extent in the warm chloroform to give a viscous solution. An infrared scan of the solution again showed that the residual anhydride peak was only about 2/3 as intense as the imide peak. C. The reaction was repeated a third time only the Dylark™ 232 was heated to 235°C prior to the addition of the amine. The temperature of the molten polymer rose to 242°C during the addition and held around 245°C during the mixing period. There was more obvious vaporization of the amine during the addition at this temperature. The 0.5 gram sample of the ground up product dissolved almost completely in the warm chloroform to give a slightly viscous solution. Due to the volatilization of some of the amine during the addition, the residual anhydride peak was almost as intense as the imide peak that formed. D. The reaction was repeated a fourth time only the Dylark™ 232 was heated to 250°C prior to the addition of the amine. The temperature of the molten polymer rose to 256°C during the addition and held around 256°C during the mixing period. More volatilization of the amine occurred at this temperature and more water vapor evolved during the mixing period. The 0.5 gram sample of the ground up product dissolved completely in the warm chloroform to give a clear non-viscous solution. Due to the volatilization of some of the amine during the addition, the residual anhydride peak was slightly greater than the imide peak that formed. EXAMPLE II Attachment of 4-Amino-2,2,6,6-tetramethylpiperidine to Dylark™ 232 in an Extruder Samples of 40 grams of 4-amino-2,2,6,6-tetramethylpiperidine were absorbed onto 500 grams of Dylark™ 232 by adding the amine to the Dylark pellets in a glass jar and rotating the jar for several minutes and then allowing the mixture to stand overnight. The next morning the liquid coated pellets were added to a Brabender Prep Center Extruder and extruded at a screw speed of 30 rpm. A. In the first run the five zones of the extruder were set at 220°C. The polymer melt had a temperature of 212°C at the die head and the maximum pressure built up was 22.1 bar (320 psi). Since there wasn't a vent on the extruder the extrudate was partially foamed by the water vapor generated. The extrudate was pale yellow in color. It was cooled and ground up in a grinder. A 0.5 gram sample of the modified polymer was stirred with 20 ml of warm chloroform for 1 hour. The product did not completely dissolve in the chloroform and formed a viscous gel. An infrared scan of the gel indicated that an imide band had formed at 1680 cm⁻¹ and the residual anhydride band at 1770-1780 cm⁻¹ was about 1/2 as intense as the imide band. The modified polymer was re-extruded a second time at the same temperature but there wasn't any noticeable change in the solubility of the product in chloroform or of the relative intensities of the carbonyl bands in the IR scans. B. The reaction was repeated on another batch of Dylark™ 232 containing the amine absorbed on the surface only this time all the heating zones were set at 240°C. The polymer melt had a temperature of 232°C at the die head and the maximum pressure built up was 15.2 bar (220 psi). The foamed extrudate was lighter yellow in color. The 0.5 gram sample of the ground up product dissolved to a greater extent in the chloroform to give a cloudy viscous solution. An IR scan of the viscous solution was similar to the IR scans of the first run. The modified polymer was re-extruded a second time at 240°C. The 0.5 gram sample of the ground up product almost completely dissolved to give a clear slightly viscous solution. There was no obvious difference in the IR scans from the first extrusion. C. The reaction was repeated on a third batch of Dylark™ 232 containing the amine absorbed on the surface, only this time all the heating zones were set at 260°C. The polymer melt had a temperature of 252°C at the die head and the maximum pressure built up was 18.6 bar (270 psi). The highly foamed extrudate was white in color. The 0.5 gram sample of the ground up product dissolved completely in the 20 ml of warm chloroform to give a clear non-viscous solution. An IR scan of the solution was similar to the IR scan of the run made at 220°C. Thus, there was no loss of amine upon extruding at the higher temperature as there was in Example I using the Plastograph. The modified polymer was re-extruded a second time. The extrudate was no longer foamed and only contained a few air bubbles. Again the 0.5 gram sample of the product dissolved completely to give a clear non-viscous solution. EXAMPLE III Attachment of 4-Amino-2,2,6,6-tetramethylpiperidine to Dylark™ 250 in an Extruder Samples of 20 grams of 4-amino-2,2,6,6-tetramethylpiperidine absorbed on 500 grams of Dylark™ 250 were prepared similar to the Dylark™ 232 samples prepared in Example II. One sample containing 40 grams of the amine on Dylkark™ 250 was also prepared but the amine did not completely absorb on the pellets and a few grams of amine remained on the sides of the jar. The extrusions were carried out similar to the extrusions carried out in Example II. The samples containing 20 grams of the amine were extruded at A) 220°C (melt temperature 212°C - max. pressure 22.1 bar (320 psi)), B) 240°C (melt temperature 231°C - max. pressure 15.9 bar (230 psi)) and 260°C (melt temperature 251°C - max. pressure 11 bar (160 psi)). The extrudates were cooled, ground up and re-extruded at the same temperature. The results were similar to the results in Example I. Since Dykark™ 250 is a rubber modified styrene-maleic anhydride copolymer, none of the chloroform solutions were clear. The solutions of the modified polymer made at 220°C were cloudy and viscous. The IR scan of the gel indicated an imide band had formed at 1680 cm⁻¹. The chloroform solution of the modified polymer extruded at 240°C was a cloudy viscous solution containing a few insoluble particles. An IR scan of the viscous solution showed the residual anhydride peak was slightly more intense than the imide band. The chloroform solution of the modified polymer extruded at 260°C was a slightly cloudy non-viscous solution. An IR scan of the solution was similar to the IR scan of the sample extruded at 240°C. D) The sample containing approximately 40 grams of the amine was extruded at 260°C (melt temperature 251°C - max. pressure 13.1 bar (190 psi)), cooled, ground up and re-extruded at 260°C. A chloroform solution of the ground up product after the first extrusion was cloudy and non-viscous. The IR scan indicated the imide peak was about twice as intense as the residual anhydride peak. EXAMPLE IV Attachment of 4-Amino,2,2,6,6-tetramethylpiperidine to Maleic Anhydride Copolymers in an Extruder Samples of 20 grams of 4-amino-2,2,6,6-tetramethylpiperidine were absorbed on 500 grams of various maleic anhydride copolymers using the procedure described in Example I. The extrusions were then carried out similar to the extrusions carried out in Example III. A) A sample of 20 grams of the amine on Dylark™ 600 was extruded at 260°C (melt temperature 251°C - max. pressure 8.3 bar (120 psi)). The first extrudate was blistered but not foamed. A chloroform solution (20 ml) of 0.5 gram of the ground up extrudate was cloudy but non-viscous. In the IR scan of the solution, the anhydride peak was slightly more intense than the imide band. The ground up extrudate was re-extruded at 260°C. The second extrudate was smooth and only had a few air bubbles. B) A sample of 20 grams of the amine on Dylark™ 700 was extruded at 260°C (melt temperature 251°C - max. pressure 8.3 bar (120 psi)). The first extrudate was highly blistered but not foamed. A chloroform solution (20 ml) of 0.5 gram of the ground up extrudate was cloudy but non-viscous. In the IR scan of the solution the anhydride peak was slightly more intense than the imide band. The ground up extrudate was re-extruded at 260°C. The second extrudate was smooth and only had a few air bubbles. C) A sample of 20 grams of the amine on Cadon™ 127 was extruded at 240°C (melt temperature 231°C - max. pressure 23.4 bar (340 psi)). The first extrudate was quite insoluble in chloroform. The extrudate was ground up and re-extruded at 240°C. The second extrudate contained a lot of blisters. The IR scan of the chloroform solution of the partially dissolved extrudate contained an anhydride peak at 1775 cm⁻¹ and weaker carbonyl peaks at 1720 cm⁻¹ and 1695 cm⁻¹ (imide band). D) A sample of 20 grams of the amine on Cadon #127 was extruded in a similar fashion at 260°C (melt temperature 251°C - max. pressure 10.3 bar (150 psi)). The ground up extrudate was not completely soluble in the warm chloroform. The IR scan of the chloroform solution contained the carbonyl peaks and the same relative intensities as in the extrusion run at 240°C. EXAMPLE V Attachment of 4-Amino-2,2,6,6-tetramethylpiperidine to Maleic Anhydride Copolymers in an Extruder at Use Levels Samples of 8 grams of 4-amino-2,2,6,6-tetramethylpiperidine were absorbed on 500 grams of various maleic anhydride copolymers using the procedure described in Example II. The extrusions were then carried out similar to the extrusions carried out in Example III. A) A sample of 8 grams of the amine on 500 grams of Dylark™ 232 was extruded at 220°C (melt temperature 215°C - max. pressure 27.6 bar (400 psi)). There was some bubbling of the extrudate. The middle portion of the extrudate was ground up and re-extruded at 220°C. One gram of the second extrudate was dissolved in 20 ml of warm chloroform. A clear solution was not formed. The IR scan of the chloroform solution contained a small imide band at 1680 cm⁻¹. B) A sample of 8 grams of the amine on 500 grams of Dylark™ 250 was extruded at 220°C. The middle portion of the extrudate was ground up and re-extruded at 220°C. One gram of the second extrudate was dissolved in 20 ml of warm chloroform. A clear solution was not formed. The IR scan of the chloroform solution contained a small imide band at 1680 cm⁻¹. C) A sample of 8 grams of the amine on 500 grams of Cadon™ 140 was extruded at 220°C. The middle portion of the extrudate was ground up and re-extruded at 220°C. There was some blistering of the extrudate. One gram sample of the ground up extrudate was not completely soluble in 20 ml of chloroform. A distinct imide was not observable in the IR scan of the chloroform solution because the starting Cadon™ 140 has a strong carbonyl band centered at 1710 cm⁻¹ which masks the small imide band. EXAMPLE VI Attachment of 4-Amino-2,2,6,6-tetramethylpiperidine to Octadecene-Maleic Anhydride Copolymer in an Extruder A blend of 1000 grams of octadecene-maleic anhydride (PA-18) and 150 grams of 4-amino-2,2,6,6-tetramethylpiperidine was prepared by adding the amine to the PA-18 in small portions in a polyethylene jug. The lumps that formed upon absorption of the amine onto the PA-18 were broken up in a Waring blender and added back to the polyethylene jug. The jug was shaken well to obtain uniformity and then transferred to the hopper of a Brabender Prep Center Extruder Model No. 1340 having a 3.18cm (1-1/4 inch) screw diameter with a length to diameter ratio of 25:1. A vent was attached to the barrel which was connected to a vacuum pump through a vacuum trap. The extruder had been purged with PA-18. It was operating at a screw speed of 30 rpm and the following temperature profile was employed: Zone One 220°C Zone Two 220°C Zone Three 225°C Zone Four 230°C Die 230°C The first 100 grams of extrudate were discarded. The remaining extrudate was air cooled and ground up in a Waring blender into a fine powder. During the extrusion water vapor formed both in the trap and at the die head. The extrudate was in a foamed condition and could easily be crushed into a powder. A solution of 0.5 gram of the extrudate in 20 ml of chloroform was prepared and an IR scan run on the solution. The IR scan had a strong peak at 1780 cm⁻¹ (anhydride) a weak carbonyl peak at 1740 cm⁻¹ and a strong peak at 1695 cm⁻¹. The blend had been prepared in a ratio such that 35% of the anhydride would have been converted to the HALS substituted imide and/or amic acid. EXAMPLE VII Attachment of 4-Amino-2,2,6,6-tetramethylpiperidine to Dylark™ 250 in the Presence of HIPS A blend of 75 grams of Dylark™ 250 and 225 grams of HIPS was prepared in a gallon jug (1 gallon ≈ 3.79 liters). After the blend was shaken well to ensure uniformity, 250 grams of the blend were added to a Brabender Prep Center Mixer. The blend was mixed under a nitrogen atmosphere for approximately 5 minutes at 200°C at 20 rpm. To the molten blend was added 9.8 grams of 4-amino-2,2,6,6-tetramethylpiperidine dropwise over about 3 minutes. The molten mixture was mixed an additional 15 minutes at 200°C under a nitrogen atmosphere and then removed as quickly as possible from the mixer and cooled in a water bath. The modified polymer was dried of superficial water and dried 4 hours at 60°C in an oven. The polymer was then ground up in a grinder and re-dried overnight at 60°C. The ground up product was partially dissolved in chloroform and an IR scan run on the chloroform soluble material. The IR scan indicated that about 90% of the anhydride had been converted to the imide (strong band at 1680 cm⁻¹) or the amic acid (weak band at 1660 cm⁻¹). EXAMPLE VIII Stabilization of a Poly(phenylene oxide) Blend with a Polymer Bound Hindered Amine Light Stabilizer A poly(phenylene oxide) blend was prepared by weighing 75 grams of the masterbatch of HIPS and the modified Dylark™ 250 from Example VII, 75 grams additional HIPS, 150 grams poly(phenylene oxide) and 3 grams tridecyl phosphite into a gallon (1 gallon ≈ 3.79 liters) jug and shaking it until a uniform mixture was obtained. The blend was extruded through a Brabender Prep Center Extruder at 260°C. The extrudate was cooled in a water bath and dried. The extrudate was smooth but contained a few air bubbles. The extrudate was ground up and dried overnight in an oven at 60°C. The product was permanently stabilized against photooxidative degradation and the light stabilizer did not leach out of the polymer blend when in contact with solvents or volatilize out at high temperatures. EXAMPLE IX Tgs of Polymer Bound Hindered Amines The Tgs of the various polymer bound hindered amine light stabilizers were determined on a Perkin-Elmer 7 Series Thermal Analysis System. The results are summarized in the following table. EXAMPLE # MALEIC ANHYD. COPOLYMER g. MA COPOLYMER g. AMINE REACTOR TEMP °C Tg OF EXTRUDATE °C IA DYLARK™ 232 200 16 200 126.1 IB DYLARK™ 232 200 16 220 126.3 IC DYLARK™ 232 200 16 235 126.2 ID DYLARK™ 232 200 16 250 124.1 IIA DYLARK™ 232 500 40 220 126.5 IIB DYLARK™ 232 500 40 240 127.5 IIC DYLARK™ 232 500 40 260 124.0 IIIA DYLARK™ 250 500 20 220 128.0 IIIC DYLARK™ 250 500 20 260 124.6 IIID DYLARK™ 250 500 40 260 126.1 IVA DYLARK™ 600 500 20 260 123.0 IVB DYLARK™ 700 500 20 260 124.8 VA DYLARK™ 232 500 8 220 121.0 VB DYLARK™ 250 500 8 220 124.3 VC CADON™ 140 500 8 220 140.2 CONTROL DYLARK™ 232 120.6 CONTROL DYLARK™ 250 122.7 CONTROL DYLARK™ 600 114.0 CONTROL DYLARK™ 700 117.9 Observations: In general the Tg's of the modified copolymers increased in direct proportion to the amount of amine attached under the same reaction conditions. The Tg's of the polymers modified at 260°C were lower than those modified at lower temperatures because complete imidization occurred at 260°C eliminating any ionic crosslinking and thereby lowering the Tg by a few degrees. EXAMPLE X Preparation of an Octadecene/N-(2,2,6,6-tetramethyl-4-piperidinyl)maleimide Copolymer in Polypropylene in an Extruder A blend of 20% 4-amino-2,2,6,6-tetramethylpiperidine on PA-18 was prepared by adding the 4-amino-2,2,6,6-tetramethylpiperidine to the PA-18 in a rotating twin shell blender containing an intensifier bar. A mixture of 37 grams of the resulting PA-18 blend, 563 grams of Himont's Profax™ 6501 polypropylene and 1.5 grams of Irganox™ 1076 (a hindered phenol antioxidant of Ciba-Geigy) were dry blended in a gallon container and then extruded at 220°C and a screw speed of 20 RPM in the Brabender Prep Scale Extruder described in Example VI. The first 100 grams of extrudate were used to purge out the extruder and were discarded. The extrudate was partially foamed due to the water evolved during the imidization. The remaining extrudate was air cooled and pelletized. The pelletized extrudate (495 grams) was let down with an additional 1200 grams of polypropylene and 4.2 grams of Irganox™ 1076. The letdown blend was shaken well to obtain uniformity and extruded at 220°C and a screw speed of 30 RPM. The extrudate was not foamed indicating that complete imidization occurred during the first extrusion. The extrudate was cooled, the first 100 grams discarded and the remaining extrudate (1540 grams) pelletized. The concentration of the 2,2,6,6-tetramethyl-4-piperidyl group (HALS Group) in the composition was approximately 0.3% and the Irganox 1076 concentration was approximately 0.25%. The pellets were injection molded in a Newbury 25 ton injection molding machine at 204°C (400°F) into 18.73 cm x 1.91 cm x 0.32 cm (7-3/8" x 3/4" x 1/8") tensile bars. EXAMPLES XI-XIV Imidization of Octadecene/Maleic Anhydride Copolymers with Mixtures of 4-Amino-2,2,6,6-tetramethylpiperidine and Supplementary Amines in an Extruder Four blends of PA-18 and mixtures of 4-amino-2,2,6,6-tetramethylpiperidine and a supplementary amine were prepared. The 4-amino-2,2,6,6- tetramethylpiperidine was mixed with the supplementary amine (total moles amine = 0.8) and added in small portions to 350 grams (1.0 mole) of PA-18 in a 1 gallon (3.79 liters) poly jug. The mixture was shaken well in the jug between each addition. After all the amine mixture was added, the blend was transferred to a Waring blender and all the lumps were ground up. The ground up portions were recombined in the jug and shaken well again to insure uniformity. See Table I for weights and moles of reagents. The four blends were extruded on the Brabender Extruder described in Example VI at a screw speed of 30 RPM. Extrusion temperatures are listed in Table I. The samples were extruded one after the other without purging the extruder between runs. The extrudates were in a highly foamed state. The extrudates were cooled and the first 100 grams of each run were discarded to prevent cross contamination. The remaining extrudates were pelletized and used in Examples XV-XVIII. EXAMPLES XV-XVIII Extrusion of Polypropylene with Polymer Bound HALS from Examples XI-XIV Dry blends of Profax™6501 polypropylene, 0.25% Irganox™ 1076 antioxidant and enough of the polymer bound HALS compounds from Examples XI-XIV to provide a 1.5% concentration of the 2,2,6,6-tetramethyl-4-piperidyl group were prepared in a 1 gallon (3.79 liters) poly container and were shaken well to obtain a uniform dispersion (For composition see Table I). The blends were then extruded on the Brabender Extruder described in Example VI at a temperature of 220°C and a screw speed of 30 RPM. The first 100 grams of extrudate were used to purge out the extruder and were discarded. The remaining extrudate was air cooled and pelletized. The pelletized extrudates (150 g) were let down with 600 grams of additional Profax™ 6501 polypropylene and 1.9 grams Irganox™1076, mixed well and re-extruded at 220°C and 30 RPM. The first 100 grams of extrudate were used to purge out the extruder and were discarded. The remaining extrudate was air cooled and pelletized. (For compositions see Table II). The final compositions were injection molded in a Newbury 25 ton injection molding machine at 204°C (400°F) into 18.73 cm x 1.91 cm x 0.32 cm (7-3/8" x 3/4" x 1/8") tensile bars. Control samples containing 0.25% Irganox™1076 alone (Control 1) as well as samples containing 0.25% Irganox™1076 and Tinuvin™770 (conc. 0.3% of 2,2,6,6-tetra-methyl-4-piperidyl groups) (Control 2) were also extruded twice at 220°C and injection molded. A control sample of unadulterated and unextruded Profax™6501 was also injection molded (Control 3). EXAMPLE XIX Evaluation of the Polymer Bound HALS from Examples X-XIV in the Stabilization of Polypropylene The tensile bars from Examples X, XV-XVIII and Controls 1, 2 and 3 were placed in a QUV Accelerated Weathering Tester (Q Panel Company) for various exposure times. The QUV operated with an 8 hour light cycle (UV-B) at 60°C and a 4 hour condensation cycle at 50°C. Samples were placed in the QUV and withdrawn at approximately the same time each day. Samples withdrawn from the QUV were evaluated for change in yellowing (ΔE) on a Colorgard System/05 (Pacific Scientific) colorimeter. Control samples without any UV stabilizer or additional antioxidant (Control #3) as well as extruded controls containing Irganox™1076 (Control #1) and Irganox™ 1076 with Tinuvin™770 (Control #2) were included in the study. The results are summarized in Table III. After measuring the color, the tensile bars were pulled on an Instron and the % elongation determined. By comparing the % elongation of the unexposed samples with the exposed samples, the % retention of elongation was calculated for the various exposure periods. The appearance of crazing, cracking or haziness on the exposed surface was also noted. The results are summarized in Table III.

Claims: An improved process for the preparation of N-(2,2,6,6-tetraalkyl-4-piperidinyl)imide containing polymer by blending together: (a) a polymer containing anhydride functions either on the backbone, on grafted side chains, as pendant units or as combinations thereof, and (b) a 4-amino-2,2,6,6-tetraalkylpiperidine, its 1-alkyl or 1-acyl derivative, heating said materials, which may or may not have reacted to form the corresponding amic acids, to the molten state in a melt mixing apparatus, for a sufficient time and at a sufficient temperature above 180°C but below the degradation temperature of the copolymer or polymeric blend, so that essentially all of the amino-substituted polyalkylpiperidine in the product is present as pendant substituted imide groups and simultaneously or concurrently therewith removing all volatile by-products of the reaction to recover said product. The process of Claim 1 wherein the blending of components (a) and (b) is carried out in the presence of an inert solvent. The process of Claims 1 or 2 wherein ancillary primary monoamino-substituted 8-200 carbon alkanes or poly(oxyalkylenes) are blended together with the other components, so that essentially all of the amino-substituted polyalkylpiperidine and alkanes or poly(oxyalkylenes) in the product are present as pendant substituted imide groups. The process of any one of Claims 1 to 3 wherein inert polymers are blended together with the other components. The process of any one of Claims 1 to 4 wherein any inert solvents are removed before heating said materials. The process of any one of Claims 1 to 5 wherein the said materials are heated under an inert atmosphere. A process of Claim 1 wherein the anhydride containing polymer is a maleic anhydride copolymer, the molar ratio of the anhydride to the amine is greater than 1:1, the reaction is carried out in a vented extruder, plastograph or Banbury mixer in an inert atmosphere at a temperature above 180°C and below 300°C for a period of 30 seconds to 1 hour and the water of reaction is removed either under vacuum or in a post drying step or under reduced pressure through the vent in the extruder. A process of Claim 7 wherein the maleic anhydride copolymer is a styrene-maleic or octadecene-maleic anhydride copolymer, the amine is 4-amino-2,2,6,6-tetramethylpiperidine and the amine is injected into the molten polymer in the extruder at a temperature above the softening point of the copolymer and the molten polymer is conveyed through the extruder at a temperature within the range of 240°C to 270°C. A composition prepared by blending together (a) a polymer containing anhydride functions either on the backbone, on grafted side chains, as pendant units or as combinations thereof, (b) a 4-amino-2,2,6,6-tetraalkylpiperidine, its 1-alkyl or 1-acyl derivative, and (c) ancillary primary monoamino-substituted 8-200 carbon alkanes or poly(oxyalkylenes), heating said materials, which may or may not have reacted to form the corresponding amic acids, to the molten state in a melt mixing apparatus, for a sufficient time and at a sufficient temperature above 180°C but below the degradation temperature of the copolymer or polymeric blend, so that essentially all of the amino-substituted polyalkylpiperidine and alkanes or poly(oxyalkylenes) in the product are present as pendant substituted imide groups and simultaneously or concurrently therewith removing all volatile by-products of the reaction to recover said product. A composition of Claim 9 wherein 15-95% of the anhydride content of a maleic anhydride copolymer is imidized by the 4-amino-2,2,6,6-tetramethylpiperidine and 5-85% of the anhydride content is imidized by the monoamineterminated poly(oxyalkylene) or monoamine-terminated alkane of 8-200 carbons. A composition of Claim 10 wherein the anhydride containing polymer is an octadecene-maleic anhydride alternating copolymer, the primary alkyl amine is dodecylamine and the primary monoamine-terminated poly(oxyalkylene) is a primary monoamine-terminated block copolymer of ethylene oxide and propylene oxide of molecular weight of approximately 300 to 600.

Inventors: MACLEAY, RONALD EDWARD
Applicants: ATOCHEM NORTH AMERICA, INC.
Application year: 1988
Main classification: C08F8
IPC codes: C08K5, C08F8