POLYDEXTROSE COMPOUNDS AS ANTI-PLEAT LOCK ADDITIVES FOR CELLULOSE CONTAINING CASINGS

Abstract: Polydextrose compound containing anti-pleat lock coatings, food casings containing said coatings, and a method for their production which comprises applying to the surface thereof an aqueous coating composition containing a polydextrose compound are disclosed. The coated food casings exhibit improved food release characteristics, improved resistance to strand breakage, and improved anti-pleat lock characteristics.

Description: This invention relates to anti-pleat lock compositions, to a method of imparting anti-pleat lock characteristics to improve food casings having a coating containing such anti-pleat lock additives, and more particularly to functional coatings for cellulosic containing food casings which contain anti-pleat lock characteristics without sacrificing strand strength characteristics. The packaging of items in flexible form fitting encasements is practiced worldwide with multifarious products. Such means of encasement is particularly suitable for consumer packaging and/or processing packaging of emulsified foods in casings, such as sausage meat products, processed dairy cheese products and other foods of similar consistency. In many such packaging applications, the speed and efficiency of the packaging process is particularly dependent upon the ability of the casing to withstand various folding and other stresses, where failure would render a casing unsuitable for stuffing. One typical type of casing which is subject to particularly stressful handling is the shirred, regenerated cellulose containing casing used in the production of sausages. In the manufacture of regenerated cellulose sausage casings, viscose is typically extruded through an annular die into a coagulating and regenerating bath to produce a tube of regenerated cellulose. The tube is subsequently washed, plasticized with glycerine, and dried while inflated under substantial air pressure. After drying, the casing is wound on reels and subsequently shirred on high-speed shirring machines, such as those described in US-A-2,010626; US-A-2,583,654; US-A-2,722,714; US-A-2,722,715; US-A-2,723,201; and US-A-3,451,827. In the shirring process, lengths of from 12.19 to 60.96 m (40 to 200 feet) of casing are typically compacted (shirred) into strands of between 10.16 and 76.2 cm. (4 and 30 inches). The shirred casing strands are packaged and provided to the meat processor wherein the casing strands are deshirred at extremely high speeds while stuffing with a meat emulsion. The meat can be subsequently cooked and the casing removed from the meat processed therein with high-speed peeling machines. It has been useful to lubricate and internally humidify cellulose casings during the shirring process by spraying a mist of water and a stream of lubricant through the shirring mandrel to increase the flexibility of the casing. Such method does reduce casing film failure and shirred strand breakage but has not proved commercially adequate. One particularly persistent type of casing failure is referred to in the art as "pinholing" and is believed to be caused by pleat-locking, an undesired adhesion of adjacent folds of a shirred casing, which tears the casing when expanded during unshirring and stuffing. Pinholing causes the tearing of the casing during the high speed stuffing thereof and can result in significant loss of time and production to the meat packer. In US-A-3,898,348, the coating of internal surfaces of cellulose sausage casings with a homogeneous mixture of a water soluble cellulose ether and an additive selected from animal, vegetable, mineral, and silicon oils and alkylene oxide adducts of partial fatty acid esters has been proposed. The coating is applied to the casing surface in a composition such that the additive is present in a proportion of about 0.1 times the weight of the water soluble cellulose ether and up to about 0.0775 mg/cm² (0.5 milligrams per square inch) of casing surface. While such materials have excellent meat release characteristics and can also effectively protect the casing from "pinholing" failures occasioned by pleat locking, the shirred strand strength characteristics have been less than desirable, tending to be fragile, often breaking on doffing or when the strand is stuffed. US-A-4,137,947 discloses a method of improving the meat release (peelability) of cellulose sausage casings by the application of a meat release coating to the internal surface thereof. The coating comprises a homogeneous admixture of a water soluble cellulose ether, the partial fatty acid ester of sorbitan or mannitan and a water soluble polyalkylene ether of the type R(-OC₂H₄O) n -H wherein R represents long chain alkyl radicals having 8 to 16 carbon atoms and n is an integer from 4 to 40. An aqueous coating composition containing the water soluble cellulose ether, partial fatty acid ester and polyalkylene ether is typically applied to the interior of the sausage casing prior to shirring. While this has been a successful meat release agent for stuffed casing, there are some commercial difficulties. Moisture level in the unstuffed strand must be carefully controlled or the composition may tend to provoke pleat lock and pinholing. The use of prior known anti-pleat lock agents though solving the pleat lock problem can give fragile strands, particularly when the moisture content of the strand is at the higher end of typical commercial ranges. This tendency results in a commercial problem with broken strands during handling or during introduction of the closed end and gives rise to significant yield loss during the shirring process. US-A- 4,442,868 which claims a food colorant and flavorant coating composition, discloses a long list of typical materials which might have utility as release additives with the coatings of his invention when a peelable casing is desired. Arabinogalactin and polydextrose are disclosed in that list but no information or disclosure relating to an anti-pleat lock effect is made. US-A-4,489,114 and GB-A-2,137,901 disclose the use of arabinogalactan as a release agent and indicates such compound is an effective anti-pleat lock additive. This additive has been found effective but is obtained by extracting from wood gum, especially of the Western larch tree and thus is costly and not readily commercially available. Therefore, there remains a need for an anti-pleat lock composition with or without meat release characteristics that does not have the disadvantages of the prior compositions. An object of this invention is to provide new anti-pleat lock additives for cellulose containing food casings, especially for regenerated cellulose casing materials, which additives are less costly and result in improved release and anti-pleat lock characteristics, especially improved resistance to pinholing, good meat release properties and strand flexibility after long storage. These and other objects of the invention have been generally accomplished by providing a cellulose containing food casing having a coating thereon containing an anti-pleat lock amount of a water soluble, polydextrose compound comprising a condensation polymer of a simple sugar, an edible, organic polycarboxylic acid and a polyol. The polydextrose compounds are used in an aqueous composition with a water soluble cellulose ether. In a preferred form of the invention, the aqueous composition comprises an aqueous medium containing a cellulose ether, a polydextrose compound, and a polyalkylene glycol ether. The composition of the invention results in artificial regenerated cellulose casings having excellent peelability from meat products under high speed mechanical peeling conditions. The cellulose casings, having coatings of the invention, can be shirred on high speed shirring machines without a substantial frequency of strand breakage and the so shirred casings of the invention can be readily deshirred in high speed stuffing operations without substantial strand breakage, pinholing or other casing failure. The casing also has sufficient strand strength to withstand normal handling required for providing end closures in the casing and placement of the strands in high speed stuffing machines. The coating composition does not cause deterioration of the casing or sticking of the pleats during storage. The term polydextrose compound, as is generally used in the prior art, refers to a condensation polymer of a sugar with an acid catalyst. In the prior art, polydextrose compounds include compounds which are and are not co-polymers with the acid, and/or are co-polymers with or without a polyhydric alcohol. The polydextrose compounds preferred in this invention, are those formed from simple sugars such as glucose and maltose. They are the condensation product of a food grade, relatively non-volatile, edible, organic polycarboxylic acid, such as maleic, citric, fumaric, tartaric, succinic, adipic, itaconic, or terephthalic acids and the like. The food grade anhydrides of succinic, adipic, and itaconic acids are also meant to be included. The inclusion of a polyhydric alcohol is also preferred. Such polyols are added to the sugar/acid reaction mixture prior to polycondensation to act as an internal plasticizer to reduce viscosity and/or to improve color and taste. Suitable preferred polyols include sorbitan, glycerol, erythritol, xylitol, mannitol, and galactitol. The chemical and physical properties of polydextrose compounds generally, and methods for producing them, are described in the literature and patents which include US-A-3,766,165. Generally, polydextrose compounds are manufactured by a melt polymerization process wherein the sugars, are cross-linked or polymerized with any one or more of a series of acids. Polydextrose compounds generally can be water soluble or insoluble depending upon whether or not the polymer is cross-linked with the acid. A soluble polydextrose compound is preferred having a molecular weight below about 20,000, and which can tolerate temperatures up to between 121 and 149 °C. Polydextroses compounds have been utilized as a low-calorie sugar substitute for many foods and as a bulking agent. A particularly preferred polydextrose compound for purposes of this invention is manufactured from glucose and maltose using an edible polycarboxylic acid that is sold under the tradename Polydextrose and manufactured by Pfizer, Inc. In the practice of this invention, the polydextrose compound is in aqueous composition with a cellulose ether. Any suitable water soluable cellulose ether may be utilized for practicing the invention. Typical of such materials are methyl cellulose, carboxymethyl cellulose, ethylhydroxy ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl hydroxyethyl cellulose, and hydroxy-propylmethyl cellulose. A preferred material is carboxymethyl cellulose as it combines to provide superior release properties at low concentrations and is easy to process. Normally, the cellulose ethers are available as salts, particularly the sodium salts. For purposes of this invention, reference to a water soluble cellulose ether is intended to encompass the alkali and alkaline earth metal salts thereof. Generally, the molecular weight of the ether is not a limiting factor except that it must not be so great as to act as an adhesive in the coating composition. In one embodiment of the invention, cellulose ethers of low molecular weight having from about 5 to about 15 carboxy methyl groups per 10 anhydroglucose units is preferred. The cellulose ethers may be supplemented by other casing coating agents such as hemi-cellulose, carboxyl oxidized dextrin, and carboxymethylated starch. The coating compositions of the invention may also include other materials such as plasticizers, lubricants, an antimicrobial compound, especially 1,3-butanediol, or materials which will aid in the storage, coloring, meat release, anti-pleat lock characteristics, and the like of the coating. A preferred additional additive is one or more of the polyalkylene glycol ethers, which are incorporated primarily for their plasticizing properties. The polyalkylene glycol ethers are the condensation products of long chain fatty alcohols and alkylene oxides, generally of the type R(-OC₂H₄O) N -H wherein R represents long chain alkyl radicals having 8 to 16 carbon atoms and N is an integer from 4 to 40. Preferred polyalkylene glycol ethers are the polyoxyethylene ethers of higher fatty alcohols such as lauryl alcohol and oleyl alcohol and which have high solubility in water. Illustrative of commercially available polyethers useful in the practice of the present invention include those sold under the designation "Brij." by Atlas Chemical Industries of Delaware, for example, "Brij 35" (polyoxyethylene [23] lauryl ether). "Brij 76" (polyoxyethylene (10) stearyl ether) "Brij 56" (polyoxyethylene (10) cetyl ether), and "Brij 58" (polyoxyethylene (20) cetyl ether). In a further preferred embodiment of the invention the coating also includes a partial fatty acid ester of sorbitan or mannitan. Such ester is included primarily for its lubricant properties. The term "partial fatty acid ester of sorbitan of mannitan" includes within its meaning the palmitic, oleic, and stearic acid esters. In a preferred embodiment of the invention, the partial fatty acid ester is a sorbitan ester, namely sorbitan trioleate. Preferably, the coating comprises sorbitan trioleate, a carboxymethyl cellulose, and said polydextrose compound, and comprises especially water and a mineral oil lubricant and/or an antimicrobial compound, preferably 1,3-butanediol. The polydextrose compound may be utilized in the coating compositions of the instant invention in any amount which provides an effective improvement in release and/or anti-pleat lock characteristics. Any suitable amount of the polydextrose compound may be utilized in the practice of the instant invention. Generally, an amount of the polydextrose compound between 0.10 percent and 5.0 percent by weight of the coating composition has been found to be suitable. A preferred formulation comprises from 0.5 to 1.5 percent polydextrose compound by weight of the aqueous coating solution. The amount of water soluble cellulose ether utilized may be any amount which gives suitable peeling properties of the casing from the meat product. Typically, the range is between 0.25 and 2.5 percent by weight of the coating composition. A preferred amount of between 0.5 and 1.5 percent by weight of the coating composition has resulted in good release properties without an excessive amount of material being utilized to produce an undesirably thick coating on the casing. The amount of plasticizer utilized in the composition depends upon the efficiency of the plasticizer and may be any suitable amount. The preferred polyalkylene glycol plasticizers have been found effective in amounts of as little as about 0.025 percent by weight and typically are used in amounts of from 0.05 to 0.25 percent by weight to provide sufficient plasticizing without promoting breakage of the strand. The amount of fatty acid ester utilized in the composition of this invention depends upon its efficiency and any suitable amount can be used. Typical amounts are from 0.25 to 5.0% by weight of the composition with amounts in the range of 0.5 to 2.5% by weight being preferred. Preferably the coating composition comprises from about 0.1 - 1.5 % carboxymethyl cellulose, from about 0.1 - 5.0 % sorbitan trioleate, from about 0.1 - 5.0 % of saisd polydextrose compound and up to about 10 % 1,3-butandediol. The coating compositions of the invention are typically homogeneous and are typically applied by spraying into the casing immediately prior to shirring. However, it should be understood that it is also within the scope of the instant invention to apply the coatings by other means such as slug coating or dip coating with or without reversal of the casing after it is coated. The amount of coating applied to the casing may vary greatly. Generally, however, as small an amount as possible is applied to obtain the desired release and anti-pleat lock characteristics. Typically the amount of coating material composition applied to the casing is from about 0.00155 mg/cm² (0.01 mg/in²) to about 0.0775 mg/cm² (0.5 mg/in²) of casing. It has also been unexpectedly found that the use of a polydextrose compound as an anti-pleat lock additive in cellulosic ether containing release coatings appears synergistic in that it allows an unexpected reduction of the amount of cellulosic ether used in the coating composition. Further, the viscosity of the coating material in its aqueous medium is appreciably lower than other coating materials of the prior art. This reduction in viscosity appears to be beneficial in spray systems in that it produces a superior spray pattern with very fine droplet size and allows reasonably low pressure differentials across the spray jet. The use of lower pressures in the coating system reduces maintenance problems such as seal leakage and the like. The following examples are provided to illustrate the invention. All percentages are expressed as weight percentages and all temperatures are in degrees Centigrade unless otherwise indicated. The examples and disclosures thereof are intended to be illustrative and nonexhaustive. The compositions of this invention can include ingredients having functions other than release, anti-pleat lock or plasticizing. For instance, lubricants, flavorants, colorants, and/or anti-bacterial agents can be added to the compositions of the invention. Similarly, multiple various additives can be utilized with the compositions of the invention providing they do not deleteriously effect the function thereof. Examples 1-8 Each of Examples 1-8 demonstrates the comparative effect of various coatings on coating cohesive strength at varying concentrations. In the experiments, aqueous coating compositions containing different amounts of lubricant (Span 85 - a sorbitantrioleate from Atlas Chemical), surfactant (tx100, an octylphenoxypolyethoxyeuhanol from ROHM & HAAS), carboxymethyl cellulose (CMC 7LF) and Polydextrose (PD-a terpolymer of glucose, citric acid, and sorbitol sold under the name Polydextrose by Pfizer Chemical Division) were tested on Code 25, 3.2cm flat width, flat stock cellulosic casing to determine their effect upon cohesive peel strength. In each instance a slug of the aqueous coating composition was introduced into the casing at ambient temperature and passed through a nip padder at 2.105 Pa (30lbs/in²) to produce a sandwiched film having a coating add-on of approximately 0.00775 mg/cm² (0.05 mg/sq.in.). The slug coated casing was then cut into strips parallel to the axis of the casing, which were then allowed to equilibrate for approximately twelve (12) weeks at 60% relative humidity and a temperature of 25°C. The so equilibrated, coated, sandwiched casing was then "T" peeled with an Instron table model Universal testing machine at 25 cm/min peel speed. The aforesaid testing procedure is a very harsh test of adhesiveness/cohesiveness and is considered equivalent to a 12 % moisture content casing test. Average cohesive peel is calculated by measuring the average force (g/1.27 cm) (g/0.5in.) necessary to peel the film apart. Average cohesive peel of less than 20.00 is desirable. The results can be found in Table I. 60% RH Cohesive Peel Strength Example Composition (in water) Avg. Cohesive Peel (g/1.27 cm) (g/0.5in) (1) 1.0% CMC 7LF 50.0 ± 2.0 (2) 1.0% Span 85 1.5 (3) 0.5% PD 1.2 ± 0.2 (4) 2.0% PD 0.8 ± 0.04 (5) 1.0% PD 3.8 ± 1.8 1.0% Span 85 (6) 1.0% CMC 7LF 31.3 ± 11.0 0.9% Span 85 0.1% tx100 (7) 1.0% CMC 7LF 13.0 ± 3.0 0.9% Span 85 0.1% tx100 1.0% PD (8) 1.0% CMC 7LF 12.6 ± 2.6 0.9% Span 85 0.1% tx100 33.0% Propylene Glycol 1.0% PD (9) 0.5% CMC 7LF 2.0 ± 0.2 2.0% Span 85 0.2% tx100 0.5% PD As can be seen from the tabulated results, the addition of a polydextrose compound (PD) to a coating composition containing very adhesive // CMC 7LF // is particularly effective in reducing the cohesive peel strength of the coating. Examples 10-19 Each of the experiments in Examples 10-19 demonstrates the comparative anti-pleat lock effect of a polydextrose compound modified commercial coatings on cellulosic casings. Various coating compositions, were applied to code 21, 24, and 27 cellulosic casing, at ambient temperature, by spraying on a shirring machine during a shirring operation at the rate of about 4.26 m/sec (14 feet/sec). Several shirred strands were produced for each coating composition. The coated and shirred strands were stuffed with a meat emulsion, twisted into links, cooked, and then peeled by means of a high speed Ranger Appollo automatic peeling apparatus operating at between about 1.82 and 3.65 m/sec (6 and 12 feet per second). During the stuffing phase the strands were carefully observed for pinholes or defects of any sort which could be attributable to pleat locking or adhesion. The peeling of the stuffed and cooked casing was evaluated by observing the average incidence of casing failure. An acceptable level is at least 95-97% failure free; a good level is from 97% - 99.5%; an excellent level is from about 99.5% to 100% failure free. The results of the aforementioned testing is tabulated in Table II.

Claims: Cellulose containing food casing having a coating thereon containing an anti-pleat lock amount of a water soluble, dextrose compound comprising a condensation polymer of a simple sugar, an edible, organic polycarboxylic acid and a polyol. The casing of Claim 1 wherein said coating comprises from 0.00155 mg/cm² (0.01 mg/sq.in) to 0.0775 mg/cm² (0.5 mg/sq.in) of the casing. The casing of Claim 1 wherein said coating further comprises a water soluble cellulosic ether. The casing of Claim 3 wherein said coating further comprises as water soluble cellulosic ether one from the group consisting of methyl cellulose, carboxymethyl cellulose, ethylhydroxy ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl hydroxyethyl cellulose, and hydroxypropylmethyl cellulose. The casing of Claim 1 wherein said coating further comprises a plasticizer. The casing of Claim 5 wherein said coating comprises as plasticizer polyalkylene glycol ether. The casing of Claim 3 wherein the coating comprises in addition a lubricant and/or sorbitan trioleate. The casing of Claim 7 wherein the coating comprises sorbitan trioleate, a carboxymethyl cellulose, said polydextrose compound, as well as water and a mineral oil lubricant and/or an antimicrobial compound, preferably 1,3-butanediol. The casing of Claim 8 wherein the coating composition comprises 0.1 - 1.5 % carboxymethyl cellulose, 0.1 - 5.0 % sorbitan trioleate, 0.1 - 5.0 % of said polydextrose compound and up to 10 % 1,3-butanediol. A method of imparting anti-pleat lock characteristics to a cellulose containing food casing comprising applying thereto an anti-pleat lock amount of a water soluble polydextrose compound comprising a condensation polymer of a simple sugar, an edible organic polycarboxylic acid and a polyol, according to claims 1-9. The method of Claim 10 wherein said polydextrose compound is applied in an aqueous composition which contains a cellulosic ether, which is selected from the group consisting of methyl cellulose, carboxymethyl cellulose, ethylhydroxy ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl hydroxyethyl cellulose, and hydroxypropylmethyl cellulose, and/or a plasticizer, which is a polyalkylene glycol ether, and/or a lubricant and/or an antimicrobial compound, which is 1,3-butanediol. The method of Claim 11 wherein the coating comprises sorbitantrioletate, carboxymethyl cellulose, and said polydextrose compound and additionally 1,3-butanediol. A coating composition comprising an anti-pleat lock amount of a water soluble polydextrose compound comprising a condensation polymer of a simple sugar, an edible organic polycarboxylic acid and a polyol, said polydextrose compound being preferably in aqueous composition, according to claims 1-9. The composition of Claim 13 additonally comprising a cellulose ether and/or a plasticizer and/or a lubricant and/or an antimicrobial compound. A flexible form encasement having a coating thereon containing an anti-pleat lock amount of a water soluble polydextrose compound comprising a condensation polymer of a simple sugar, an edible organic polycarboxylic acid and a polyol, according to claims 1-9.

Inventors: BRIDGEFORD, DOUGLAS J., HINE, RODNEY J.
Applicants: TEEPAK, INC.
Application year: 1988
Main classification: A22C13
IPC codes: A22C13