PARTICULATE SOLIDS CRACKING APPARATUS AND PROCESS

Abstract: Process and apparatus for rapidly cracking a hydrocarbon feed followed by rapid separation of the cracked gases from the particulate solids including a cracking reactor having offset orifices and at least two opposed inlet nozzles in the same plane, an entrained bed heater having an array of fuel inlet nozzles in a plane at the bottom of the heater and axially directed air inlet nozzles, and a separator assembly for separating particulate solids from the gaseous products thus produced.

Description: This invention relates to a process and an apparatus for cracking hydrocarbon feedstocks by the use of heated solids, so as to produce useful hydrocarbons. The prior art has provided a number of processes for converting hydrocarbon feed to useful products, such as fuel, olefins and others: among the most recent conventional processes developed to crack crude hydrocarbons, pyrolysis and catalytic cracking processes using particulate solids as the heat source have been suggested. DE-B-1 036 217 provides a number of arrangements for contacting the hydrocarbon feedstock with particulate solids flowing downwardly by gravity flow. The lines used to convey the feedstock are either centrally disposed, or arranged at one side of the solids curtain, in an attempt to bring about a whirling movement of both the feedstock and the particulate solids and improving the contact between the two. EP-A-0 150 239 discloses an arrangement of catalyst particles flowing in an annular curtain, and the hydrocarbon feedstock is delivered radially from the axial centreline of the cracking reactor. The prior art mentioned above has the defect, in the first place, that the contact times between the hydrocarbon feedstock and the particulate solids are exceedingly long and the intimacy of the contact is unsatisfactory. In addition, a process and an apparatus have been recently developed by the present Applicants for efficiently and effectively separating the particulate solids from the cracked gas leaving a cracking reactor: US-A-4 443 984 is an example of such a separating technique. The present Applicants have also developed a process and apparatus for delivering particulate solids to a service which has no moving parts: they are described in US-A-4 459 071. US-A-4 338 187 describes a hydrocarbon feedstock and hot particulate solids feed system that achieves rapid Sixing of the feedstocks and the solids, and the desired rapid cracking as well. An object of the present invention is to provide a process and an apparatus which facilitate complete and rapid cracking of hydrocarbon feed, followed by a rapid separation of the cracked gases from the particulate solids. Another object is to provide a process and an apparatus of the kind referred to above, by which the cracking reactions are terminated by immediate quench of the cracked effluent. The present invention provides, therefore, a process for cracking hydrocarbons with hot particulate solids, comprising the steps of: (a) delivering a curtain of hot particulate solids to a cracking reactor through peripheral openings above a centrally disposed arcuate member; (b) delivering hydrocarbon feedstock to the curtain of hot particulate solids through oppositely disposed inlet nozzles directed toward each other in the same entry plane and directing the hydrocarbon feedstock streams and the entrained solids in a path defined by said arcuate member centrally disposed in the reactor, and (c) separating the cracked gas from the particulate solids, and terminating the cracking reactions in the cracked gas, the time which elapses from the introduction of the hydrocarbon feedstock into the reactor until the termination of the cracked gas reactions being from 0,1 s to 0,6 s. The invention accordingly provides, for performing the cracking process as defined above, a cracking reactor comprising: (a) centrally offset orifices for delivery of particulate solids to the reactor; (b) at least two hydrocarbon feed inlet nozzles facing each other located in the reactor sidewall in the same plane; (c) a centrally disposed arcuate-surfaced plug member in the reactor for the particulate solids to flow around upon entry in the reactor, the bottom of which plug member is at the elevation at which the hydrocarbon feed nozzles are located, and (d) a venturi shaped section between the solids orifices and the hydrocarbon feed inlets. The particulate solids discharged from the reactor are at a reduced temperature from the temperature at which te solids entered the reactor,and have become fouled with contaminants such as tar and coke from the hydrocarbon feedstock. The particulate solids, if so desired, are stripped of some of the impurities and then heated in an entrained bed heater by combusting fuel and air with the coke contaminants on the solids. The invention will be better understood when considered with the following drawings wherein: FIGURE 1 is an elevational view of the overall system of the present invention; FIGURE 2 is an enlarged sectional elevational view of the reactor and cracked gas-solids separator of the present invention; FIGURE 3 is a sectional elevational view through line 3-3 of FIGURE 2; FIGURE 4 is a plan view through line 4-4 of FIGURE 2. FIGURE 5 is a sectional plan view through line 5-5 of FIGURE 2; FIGURE 6 is a partial view of the solids inlet to the reactor shown in FIGURE 5; FIGURE 7 is a sectional plan view through line 7-7 of FIGURE 2; FIGURE 8 is a sectional view through line 8-8 of FIGURE 1; and FIGURE 9 is a schematic elevational view of the solids regeneration assembly. DESCRIPTION OF THE PREFERRED EMBODIMENT The process and apparatus of the present invention have application in the various cracking environments, in which solids are used whether the solids be inert or catalytic. However, the process and apparatus of the present invention will be described with reference to a catalytic cracking process for producing olefins from hydrocarbon feed. As best seen in FIGURE 1, the system 2 is comprised essentially of reactor system 4, a solids regeneration assembly 8 and a solids delivery System 10. The reactor system 4, best seen in FIGURE 2, includes of a convergent mixing section 11, an elongated reaction section 12, a divergent section 13 downstream of the elongated reaction section 12, a separator 6 and quench system 7 (Shown in FIGURE 7). The mixing sections 11 are formed with a plug section 14 shown in cross-section as having an arcuate lower surface 15. A horizontally disposed plate 17 is arranged over the plug section 14 in spacedrelationship with the plug section 14 to form solids inlet passages 19 to the interior of the mixing section 11. The solids inlet passages 19 are configured in cross-section with a right angle turn and terminate in rectangular openings 25 through which the particulate solids enter the mixing section 11, in the form a curtain of solids 26 as best seen in FIGURE 3. The horizontal openings 25 are directly above each hydrocarbon feed inlet. Venturi configured passages 3 extend from the solids inlet passages 19 to the hydrocarbon feed inlets 28. Steam plenums 21, best seen in FIGURES 5 and 6, are arranged along each longitudinal edge of the horizontal opening 25 to deliver pre-acceleration gas (steam) through nozzles 29 into the curtain of solids 26 passing through the horizontal openings 25. A gas delivery line 27 is provided to deliver gas, usually steam or light hydrocarbon, under pressure to the nozzles 29. The nozzles 29 are arranged at a downward angle of 45° to the horizontal. The pre-acceleration gas is delivered to the plenums 21 at pressures of 0,207 bar to 0,345 bar (1 bar = 10 ⁵Pa) (3 to 5 psi) above the pressure in the reactor and discharges through the nozzles 29 at that same relative pressure at a velocity of about 45,7 m/s (150 feet per second). The pre-acceleration gas accelerates the flow of solids through the horizontal openings 25 from a nominal three to 1,8 m/s to 15,2 m/s (six feet per second to approximately 50 feet per second) for the mix of solids and pre-acceleration gas. The hydrocarbon feed inlets 28 are located on the reactor wall 22 arranged either normal to the solids curtain 26 or at an angle upwardly of 30° into the solids curtain 26. The hydrocarbon feed is delivered to a manifold 23 through a line 24. The feed inlet nozzles 28 are fed with hydrocarbon from the manifold 23. As seen in FIGURE 2, the feed inlet nozzles 28 are diametrically opposed from each other in the same horizontal plane. The mixing zone 11 of the reactor is rectangular as seen in FIGURE 4 with the configuration making a transition to a tubular reactor at the elongated reaction section 12. The feedstock entering the mixing zone 11 through nozzles 28 immediately impinge the solids curtains 26 and the desired mixing of feed and hot particulate solids occurs. With the opposing set of nozzles 28, the opposing feed jets and entrained solids from the solids curtain 26 will be directed by the arcuate contour 15 of the plug section 14 and impact with each other at approximately the vertical centerline of the mixing zone 11. When a gas-liquid mixed phase hydrocarbon is fed through the nozzles 28, the nozzles 28 are arranged at an angle normal or 90° to the solids curtain 26. When the hydrocarbon feed is a gas, the nozzles 28 are arranged at an upwardly directed angle of 30° into the solids curtain. The quantity of solids entering the mixing zone 11 of the reaction system through the horizontal inlets 19 is controlled in large part by the pressure differential between the mixing zone 11 of the reaction system and the chamber 21 above the solids reservoir 18 in a solids control hopper 31 directly above the horizontal inlets 19. Pressure probes 33 and 35 are located respectively in the mixing zone 11 of the reaction system and the control hopper chamber 21 to measure the pressure differential. Gas (steam) under pressure is delivered through a line 30 to the control hopper chamber 21 to regulate the pressure differential between the mixing zone 11 of the reaction system and the control hopper chamber 21 to promote or interrupt flow of the solids from the solids control hopper 31 to the mixing zone 11 of the reaction system. A detailed description of the process of regulating the solids flow is found in US-A- 4,459,071 and US-A- 4,453,865. The hydrocarbon feed enters the mixing zone 11 of the reaction system at a temperature of 93°C to 593°C (200 to 1100°F) and is elevated to a cracking temperature of 538°C to 816°C (1000 to 1500°F). Cracking proceeds through the mixing zone 11 and elongated cracking zone 12. Thereafter, the combined cracked effluent and entrained particulate solids discharge to the separator 6. The residence time from hydrocarbon entry into the reaction system to entry into the separator 6 of the reaction system is 0.05s to 0.5s. This time represents the time of intimate contact between catalyst and hydrocarbon. As best seen in FIGURE 2, the separator 6 is comprised of a mixed phase inlet 32, a horizontal chamber section 34, a plurality of cracked gas outlets 36 and particulate solids outlets 38. The separator 6 is an improvement on the solids-gas separator described in US-A- 4,433,984. The basic principles relating to relative diameters (Di, Dog, Dos), chamber height (H) and length (L) recited in US-A- 4,433,984 again obtain. However, the separator 6 is arranged in combination with the elongated cracking zone 12 and divergent section 13 of the reaction system. The divergent section of the reaction 13 system terminates in the separator mixed phase inlet 32 which is centrally disposed at the top of the horizontal section 34. As a result of the configuration of the composite reaction system including the separator 6, a solids bed 42 develops on the floor 40 of the horizontal section 34 with the cross-sectional profile 43 of the bed 42 forming a curvilinear arc over which the mixed phase gas and solids travel. The expansion of solids and cracked gas in the divergent section 13 enhances heat transfer and limits the velocity of the solids-gas mixture entering the separator 6. The solids are sent to the lateral ends 46 of the horizontal section 34 and discharge downwardly through the solids outlets 38. The cracked gases follow a 180° path and after separation from the solids discharge through gas outlets 36 that are located on the top of the horizontal section 34 intermediate the lateral ends 46. The plurality of solids outlets 38 and gas outlets 36 provide simultaneously for both minimum time in the separation zone and maximum solids-gas separation. The separation system also includes a conventional cyclone separator 50 directly downstream of each gas outlet 36, best seen in FIGURE 7. The entry line 54 to each cyclone separator 50 is arranged at an angle of 90° to the gas outlet 36 with the cyclone separators 50 vertically disposed in the system. The cyxlone separators 50 serve to collect the remaining entrained particulate solids from the cracked gas discharged from the separator 6. A dipleg line 49, returns the particulate solids to the regeneration assembly 8 and the cracked gas is sent for downstream processing through the gas outlet 51. In practice, the separator 6 separates 95 to 99% of the solids from a gas solids mixtures having dust loadings of 3,2 g dm² (0.2 to 0.3 pounds of solid per cubic foot) of gas where the average particle size of the solids is 90 µm. Each cyclone entry line 54 extending from the cracked gas outlet 36 to the cyclone 50 is provided with a direct quench line 52. Quench oil, usually the 38°C-204°C (100-400°F) cut from a downstream distillation tower is introduced into the cyclone 50 through the direct quench line 52 to terminate the reactions of the cracked gas. 0,1716 litres to 0,515 litres (0.1 to 0.3 gallons) of quench oil are introduced upstream of the cyclone 50 for every kg (pound) of cracked gas. In practice, it has been found that the cracking time; i.e. effective kinetic residence time is the time that elapses from the introduction of feed into the reaction system until the termination of cracked gas reactions in the cyclone 50. The effective kinetic residence time includes the time during which the hydrocarbon and catalyst are in intimate contact and the time from separation until quench. This effective kinetic residence time is 0.1s to 0.6s As best seen in FIGURE 9, the regeration assembly 8 is comprised of a stripper 53, control hopper 55, entrained bed heater 58, a lift line 57, and a regenerated solids vessel 60. The stripper 53 is a tubular vessel into which the particulate solids from the separator 6 are delivered through solids outlet legs extending from the separator solids outlets 38 and from the cyclone diplegs 49. A ring 62 best seen in FIGURE 9, having nozzle openings 64 is provided at the bottom of the stripper 53. A stripping gas, typically steam, is delivered to the ring 62 for discharge through the nozzles 64. The stripping steam passes upwardly through the bed of particulate solids to remove impurities from the surface of the particulate solids. 0,454 kg to 1,362 kg (1.0 to 3.0 pounds) of steam at 93°C to 260°C (200°F to 500°F) temperature and 1,38 bar to 13,8 bar (20 to 200 psig) pressure are delivered to the stripper for each 4 54 kg (0.5 ton) of particulate solids. The stripping steam and entrained impurities pass upwardly through the particulate solids in the stripper 53 and discharge through a vent line (not shown) to the cracked gas line. The stripped solids are accumulated in the control hopper 55 for eventual delivery to the entrained bed heater 58. The control hopper 55 is a collection vessel in which solids enter through the standpipe 66 and from which an outlet line 73 extends to deliver solids to the entrained bed heater 58. The assembly of the control hopper 55 and standpipe 66 provides for a slumped bed solids transport system as described in US-A- 4,459,071 and US-A-4,453,865. The pressure differential maintained between the slumped bed surface 68 in the control hopper 55 and the exit 70 of the outlet line 73 determine the solids flow rate between the control hopper 55 and the entrained bed heater 58. A line 72 is provided to selectively introduce steam under pressure into the control hopper 55 to regulate the pressure differential. Probes 67 and 69 are placed respectively in the control hopper 55 and entrained bed heater 58 to monitor the pressure differential and regulate the valve 65 in the steam line 72. The entrained bed heater 58 is essentially tubular in configuration. An array of distinct fuel nozzles 61 fed by fuel lines 63 are arranged essentially symmetrically on the lower inclined surface 75 of the entrained bed heater 58. Air under pressure enters the entrained bed heater 58 through a nozzle77 arranged to direct the air axially upwardly through the entrained bed heater 58. The air jet provides both the motive force to lift the solids particles upwardly through the entrained bed heater 58 to the regenerated solids vessel 60 and the air necessary for combustion. The fuel is ignited by contact with the hot solids in the presence of air. The combustion gas/solids mixture moving upwardly through lift line 57 enters the regenerated solids vessel 60 tangentially, preferably, perpendicular to the lift line to separate the combustion gases from the solids. As shown in FIGURE 1, the vessel 60 has a distube 85 in the gas outlet nozzle 86 to provide cyclonic movement which improves the separation efficiency of the system. In operation, the solids slide down the inside edge of the entrained bed heater 58 and are picked up by the central air jet which operates at a velocity of 24,4 m/s to 45,75 m/s (80 to 150 feet per second). The superficial velocity in the main body of the entrained bed heater 58 is 2,44 m/s to 4,575 m/s (8 to 15 feet per second). The reduction in velocity and the use of a single central jet creates a circulation in dilute phase within the expanded portion of the bed. The entrained solids fall to the side and are re-entrained in the jet. The velocities are such that there is a net transport of solids up the lift line 57 with the wide spot in the line creating a zone of recirculation and hence higher solid density and residence time. Practice shows that the solids on the average recirculate about 10 to 15 times compared to the net throughput. The characteristics and advantages of the entrained bed heater 58 include a recirculation system that creates a higher solids density that minimizes peak temperatures that could damage catalysts or solid. In addition, the combustion in the entrained bed heater 58 occurs in the gas phase. The solids are suspended in the gas and thus the combustion is rapid and the gas and fuel are intimately mixed in the combustion zone. The combustion reaction in the entrained bed heater includes the coke coating the particulate solids. Thus, the feed to air ratio is maintained for a nominal 10% excess of air over fuel and insures that all the coke on the particulate solids is burned and contributes to the solids heating process. The reaction is of a type similar to CH x + O₂ → H₂O + CO₂. The regenerated solids vessel 60 is a cylindrical vessel provided with a standpipe 71, seen in FIGURE 2, extending to the reactor hopper 31. Again the structure of the regenrated solids vessel 60 provides for accumulation of a slumped bed 81, seen in FIGURE 9 above which pressure can be regulated to enable controlled delivery of the regenerated particulate solids to the reactor hopper 31. The upper solids collection vessel 60 seen in FIGURES 1, 2 and 9 contains a stripping section as the lower portion with a stripping ring 79 and forms a part of the solids deliver system 10. Above ring 79, the solids are fluidized; below the ring 79 the solids slump and are fed to the standpipe 71. The standpipe 71 feeds the slumped bed in the control hopper 31 as best seen in FIGURE 2. Solids flow into the reactor hopper 31 through the standpipe 71 to replace solids that have flowed into the reactor 4. Unearated solids (slumped solids) will not continue to flow into the reactor hoppper 31 once the entrance 82 to the hopper 31 has been covered. Thus the position of the entry 82 defines the solids level in hopper 31. As solids flow from hopper 31 via pressure differential between the vapor space in the chamber 21 above the bed 18 and the mixture zone 11, the entry 82 is uncovered allowing additional solids to flow into the hopper 31. The solids flow from the rectangular orifices or solids inlet passages 19 is what can be described as extrusion flow. The solids are in dense phase until picked up by the pre-acceleration gas. A pressure drop of 0,0345 bar to 0,345 bar (0.5 to 5.0 psi) is used to control the rate of solids flow to the reactor mixing section 11. The process of the invention proceeds by delivering pre-acceleration gas feed such as steam at a temperature of 204°C to 593°C (400 to 1100°F) through the pre-acceleration inlets and hydrocarbon feed at a temperature of 149°C to 593°C (300 to 1100°F) such as, LPG, naphtha, gas oil, or resid through the feed nozzles 28 to the reactor 4. The hot particulate solids are delivered to the reactor 4 through the rectangular orifices at a temperature of 649°C to 927°C (1200 to 1700°F). The hydrocarbon feed mixes with the hot particulate solids and is cracked at a cracking temperature of 593°C to 816°C (1100 to 1500°F). The pressure in the reactor is 0,414 bar to 4,14 bar (6 to 60 psi) and the residence time or contact time from hydrocarbon feed entry to quenched cracked gas effluent is 0.1s to 0.6s. The hot particulate solids are cooled from a temperature of 649°C to 927°C (1200 to 1700°F) to 593°C to 816°C (1100 to 1500°F) and spend 0.1s to 0.6s from passage through the rectangular orifice to discharge from the separator solids outlet. The cracked gases are quenched by direct quench oil in the cyclone to 538°C to 649°C (1000 to 1200°F degrees). Thereafter, additional quench cooling is performed to reduce the cracked effluent temperature to 149°C to 371°C (300 to 700°F) for fractionation. The solids are stripped of surface impurities in the stripper by steam at temperatures of 593°C to 816°C (1100 to 1500°F). The stripped particulate solids are then delivered to the entrained bed heater at a temperature of 593°C to 816°C (1100 to 1500°F) Fuel having a BTU content of 17 928 KJ /kg to 23201 KJ /kg (17,000-22,000 BTU/LB) and 12 to 17 weight units (pounds) of air per weight unit (pound) of fuel and coke are continuously fed to the entrained bed heater and combusted with the coke (carbon) on the particulate solids at temperatures of 649°C to 927°C (1200 to 1700°F) and a pressure of 0,414 bar to 4,14 bar (6 to 60 psi). Hot particulate solids are delivered to the regenerated solids vessel at a temperature of 649°C to 927°C (1200 to 1700°F) where the combustion gases are separated in the separator and cyclones and exhausted as flue gas. The flue gas has no heat (BTU) content and is used to preheat feedstock or generate steam. The hot solids are returned to the reactor 4 through the reactor hopper and rectangular orifices at a temperature of 649°C to 816°C (1200 to 1500°F). A projected material balance is as follows: naphtha feed 22700 kg/h (50,000 lb/hr) secondary feed only dilution steam 726,4 kg/h (1600 lb/hr) 1362 kg/h (3000 lb/hr) primary 5902 kg/h (13000 lb/hr) secondary solid circulation 385.900 kg/h (850,000 lb/hr) naphtha preheat temp 482°C (900°F) dilution steam preheat temp 593°C (1100°F) reactor outlet temperature 727°C (1340°F) solid inlet temperature 866°C (1590°F) air flow 34050 kg/h (75000 lb/hr) preheated to 371°C (700°F) (by flue gas) fuel required coke on solid from reaction 113,5 kg/h (250 lb/hr) 4108,104 kCal/h (3.9 MMBTU/hr) external fuel 2120,2 kg/h (4670 lb/hr) 81108,72 kCal/h (77 MMBTU/hr) In practice it has been found that the particulate solids loss is 0.005% of circulation in the practice of the present invention. The yield from the 22700 kg/h (50,000 lb/hr) of naphtha is as follows: Product Yield (Weight %) H₂ 0.67 CH₄ 13.05 C₂H₂ 0.39 C₂H₄ 27.47 C₂H₆ 3.52 C₃H₄ 0.51 C₃H₆ 15.01 C₃H₈ 0.49 C₄H₆ 3.82 O-C₄'s 4.58 C₅'s 5.08 Benzene 5.09 Toluene 3.98 EB+X 3.17 Styrene 1.02 O-C₆ 2.05 O-C₇ 2.45 O-C₈ 1.34 C₉- 204°C (400°F) 2.72 LFO 3.05 HFO 0.05 Coke 0.49

Claims: A process for cracking hydrocarbons with hot particulate solids, comprising the steps of: (a) delivering a curtain of hot particulate solids to a cracking reactor through peripheral openings above a centrally disposed arcuate member; (b) delivering hydrocarbon feedstock to the curtain of hot particulate solids through oppositely disposed inlet nozzles directed toward each other in the same entry plane and directing the hydrocarbon feedstock streams and the entrained solids in a path defined by said arcuate member centrally disposed in the reactor, and (c) separating the cracked gas from the particulate solids, and terminating the cracking reactions in the cracked gas, the time which elapses from the introduction of the hydrocarbon feedstock into the reactor until the termination of the cracked gas reactions being from 0,1 s to 0,6 s. Process according to claim 1, wherein an additional step is comprised of delivering pre-acceleration gas into the solids curtain to accelerate the flow of the curtain of hot solids. Process according to Claim 1, wherein an additional step is comprised of delivering hot particulate solids to the reactor through a path comprising offset orifices arranged normal to the reactor centreline and thereafter parallel to the reactor centreline. Process according to Claim 3, wherein the additional step is comprised of delivering the curtain of solids to the reactor along the reactor wall. Process according to Claim 1, wherein the additional steps are comprised of passing the separated cracked gas to a cyclone separator and injecting quench oil, immediately upstream of he cyclone, to terminate the cracking reactions in the cracked gas. Process according to claim 4, wherein the additional steps are comprised of delivering the cracked gas and particulate solids to a separator through a single inlet, separating the cracked gas and particulate solids in the separator, discharging the cracked gas upwardly through a plurality of cracked gas outlets, and discharging the particulate solids downwardly through a plurality of solids outlets. Process according to claim 6, wherein the additional steps are comprised of delivering the separated particulate solids to a stripper and passing stripping steam through the particulate solids to remove surface impurities from the particulate solids. Process according to claim 7, wherein the additional steps are comprised of delivering the stripped solids to a hopper, accumulating a slumped bed of particulate solids in the hopper, and passing a continuous flow of solids from the slumped bed through a standpipe to the bottom of an entrained bed heater. Process according to Claim 8, wherein the additional steps are comprised of delivering fuel through an array of fuel nozzles at the bottom of the entrained bed heater in a plane completely across the entire cross-section of the entrained bed heater and a jet of air axially through the bottom of the entrained bed heater to produce hot combustion gases intimately mixed with the solids. Process according to claim 9, wherein the fuel in the entrained bed heater has a heat content of from 17928,2 kJ/kg (17.000 BTU/lb) to 23201,2 kJ/kg (22.000 BTU/lb) and 12 to 17 weight units of air per weight unit of fuel and coke from the particulate solids is delivered to the entrained bed heater. Process according to claim 10, wherein the additional steps are comprised of transporting the hot particulate solids and combustion gases through the entrained bed heater to a regenerated solids vessel and separating the hot particulate solids from the combustion gases in the regenerated solids vessel. Process according to claim 11, wherein the additional steps are comprised of accumulating a slumped mass of solids in the regenerated solids vessel, and passing the hot regenerated solids through a standpipe to a slumped mass of particulate solids in a reactor hopper in which the discharge end of the standpipe is immersed in the slumped bed of solids in the reactor hopper. Process according to claim 12, wherein the slumped bed of solids in the reactor hopper rests on the offset orifices of the reactor and the pressure differential between the zone above the slumped bed of solids in the reactor hopper and the cracking reactor is regulated. A cracking reactor (4) for performing the process according to Claim 1, comprising: (a) centrally offset orifices (19) for delivery of particulate solids to the reactor (4); (b) at least two hydrocarbon feed inlet nozzles (28) facing each other located in the reactor sidewall in the same plane; (c) A centrally disposed arcuate-surfaced plug member (14) in the reactor (4) for the particulate solids to flow around upon entry in the reactor, the bottom of which plug member (14) is at the elevation at which the hydrocarbon feed nozzles (28) are located, and (d) a venturi shaped section (3) between the solids orifices (19) and the hydrocarbon feed inlets (28). Cracking reactor according to claim 14, wherein the offset orifices (19) are configured with a horizontally disposed channel and a vertical channel immediately downstream of the horizontal channel, rectangular openings (25) at the end of the vertical channels, the hydrocarbon feed nozzles being vertically aligned with the rectangular openings (25). Cracking reactor according to claim 14, further comprising pre-acceleration gas nozzles (29) located at the edges of the rectangular openings (25) for solids (26) to enter the reactor (4). Cracking reactor according to claim 16, further comprising a rectangular mixing section (11), an elongate tubular reaction section (12) and a divergent section (13) immediately after the elongate tubular reaction section (12). Cracking reactor according to claim 17, further comprising a separator (6) having a centrally disposed gas-solids inlet (32) in communication with the reactor divergent section (13). Cracking reactor according to claim 18, further comprising a reactor hopper (55) above the reactor in which a slumped bed of stripped solids is accumulated, said reactor hopper (55) being in direct communication with the horizontal channels of the offset orifices (19).

Inventors: GARTSIDE, ROBERT J., NORTON, RICHARD C.
Applicants: STONE & WEBSTER ENGINEERING CORPORATION
Application year: 1988
Main classification: C10G9
IPC codes: B01D45, C10G9, C10G11, B01J8