Metallic coolant for a metallurgical bath, method of cooling using the coolant, method of manufacture thereof

Abstract: A metallic coolant for a metallurgical bath, the composition of the coolant substantially corresponding to that of the bath consists of ball-shaped bodies of sizes not less than 12 mm and not more than 60 mm, the ball-shape factor B of the coolang having a value of at least 0.57. The ball shape factor (herein defined) relates the shape to that of spherical balls. The coolant can be made, using a hammer mill, from scrap.

Description: The invention relates to a method of producing a metallic coolant made of steel for a metallurgical bath, the composition of the coolant essentially corresponding to that of the bath. In metallurgical processes the desired composition of the metal bath is often reached at a temperature which is higher than the temperature at which the metal is to be processed further or at which the liquid metal is to be cast. So in order to achieve the desired temperature, a coolant is fed into the bath in a quantity which corresponds with the desired fall in temperature. Various demands are made on the coolant, such as: Its composition must be known and lie between the desired limits so that it corresponds adequately with the composition limits of the bath, in order to prevent the compositional analysis of this bath altering undesirably. The coolant must have an adequately high dispensed weight to prevent any undesired inclusions. The dimensions of the coolant particles must lie between set limits so that the coolant is sufficiently manageable. The coolant must be capable of being dosed smoothly and of being dispensed accurately. The coolant must be as free as possible from grease, dust, oxide and clinging dirt. Often shredded metal scrap is used as coolant, for example for steel baths. The scrap may or may not be greatly or slightly deformed in order to make it more manageable. However, it has been found that there is a need for a metallic coolant which can be dispensed faster and more accurately and has a more dependable cooling effect. For the last requirement it can be noted that if the coolant contains too many small parts, then there is a risk that these stay floating on the bath and provide insufficient cooling effect. On the other hand one of the drawbacks of metal scrap of over-large sizes is that they can block off feed systems which may then become clogged and be unable to be used. This means that other additions essential to the process may not be added to the bath, the bath will not reach the correct composition and the charge will have to be downgraded. Here it should be noted that the dimensions of the feed system have to be kept limited in the case where the coolant is supplied to an installation of which the bath is treated under vacuum, thereby increasing the susceptibility of the installation to clogging. The object of the invention is to provide a method of producing a metallic coolant made of steel which avoids or mitigates the drawbacks mentioned. This object is achieved by the manufacturing method of claim 1. Claim 2 is describe preferred embodiments of the method. The coolant obtained by the invention mainly consists of ball-shaped bodies of sizes between 5 and 60 mm, and more in particular between 12 and 60 mm, the ball-shape factor B (as defined below) of the coolant bodies having a value of at least 0.57. The body size here mentioned is the sieve pass size of the bodies, not their average size. The ball-shape factor B is the quotient (ratio) between (a) the occupied volume per unit of bulk volume of the bodies of the coolant when poured, and (b) the occupied volume per unit of bulk volume of spherical balls of one size when poured. The unoccupied volume is thus the total void space between the poured bodies (or balls). The bodies (or balls) are poured so as to achieve a random, not settled, packing. It has been found that the factor B is a measure of the closeness of the coolant bodies and at the same time of the flow behaviour and the suitability for accurate dispensing of the coolant. A value for B of more than 0.57 is found to be necessary to keep the coolant free from unduly large openings. Moreover, it has been found that at such values the coolant may be dispensed very accurately and flows extremely regularly and reproducibly from bunker outlets. Good results are particularly obtainable with a factor B of between 0.60 and 0.65. If the coolant consists of an ultra-low carbon steel, (e.g. steel below 0.1% C, preferably below 0.05% C) it is found that a good approximation of ball shape is possible. For such material a dispensing weight of between 3.5 and 4.0 ton/m 3 has been found to be achievable. Good results in a conventional steel mill are in this case, and generally, obtained with a steel coolant with a ball-shape factor having a value of between 0.58 and 0.62 in combination with coolant body sizes between 20 and 60 mm. Although various ways may be conceived for giving steel elements sufficient density and an adequate ball-shape approximation, it has been found that one of these methods leads to an inexpensive and reproducible production process. The invention consists in that strip or bar shaped steel waste or scrap, which may be pre-cut, is processed a plurality of times in a hammer mill with an anvil grid of square grid holes of size in the range 30 to 70 mm, preferably about 50 x 50 mm in size, in which during hammering the hammer mill is kept filled to a level of at least 85% of the mill volume of the hammer mill. In practice the amount to which the hammer mill is filled can be controlled by measuring the power used by the hammer mill drive means and keeping the hammer mill filled to a level such that at least 90% of the peak power capacity of the nominal drive means of the mill is required. Hammer mills with grids of this type are in general known (see for example, DE-B-1 151 717). Indeed these are also used to reduce and somewhat compact sheet shaped metal scrap, of which, however, up to now approximately ball-shaped elements have not been obtained of the required density and with the required ball-shape factor for good dosing behaviour. It has even been found that when processing strip shaped cut waste a large portion of the material disappears through the grid holes in strip shapes or in the shape of shavings, from which a hammered material is obtained which cannot be dispensed sufficiently accurately and pours irregularly. It has been found that, if the hammering is repeated a plurality of times under the condition described above, an entirely satisfactory product can be obtained. Surprisingly, this material also becomes completely free of clinging grease, dirt residue and oxide. For this it is essential that the mill be kept filled to an adequate level. If the load level of the mill is less, it is found that even on repeated hammering a significant portion of the load may be insufficiently compacted. The number of hammering treatments is at least two, preferably three. A further refinement of the new method consists in that the hammered material being is sieved after every processing in the hammer mill for the removal of fine material, and that after at least the second (preferably the third) processing it is sieved to select the desired bodies of sizes between 12 and 60 mm. The fine material consists of particles with sizes in the order of magnitude from 1 - 12 mm which during hammering tend to be rubbed off from the scrap. On final selection, it is possible to select the coolant within narrower size limits, if this is desired. However, for the bulk of applications it has been found that coolant body sizes between 12 and 60 mm, preferably 12 and 50 mm, produce and entirely satisfactory result. For the manufacture of the abovementioned coolant of the invention with a ball-shape factor between 0.58 and 0.62 in combination with sizes between 20 and 60 mm, it has been found useful to start with sheet shaped material of appropriate composition with a thickness of between 1 and 12 mm, preferably 1 to 8 mm. This material can have surface dimensions, i.e. size, not exceeding 1.2 x 0.5 m, for example 0.5 x 1 m. It has already been mentioned that it is important in the manufacturing method that the hammer mill should reamin well filled. This can be achieved by providing the hammer mill with an automatic supply system which is activated if the effective power taken becomes less than 90% of the peak capacity of the drive means. Hammer mills typically have a drum on a drive axle and around its circumference the drum carries a plurality of axles on which hammer heads swing. When the drum is rotating the hammer heads swing along the anvil. It has been found that the method in accordance with the invention can be influenced by the way the hammer mill is configurated and the way it is driven. In particular it has been found that it is preferable to provide the hammer axles with at least 18 hammers per 10 square metres of drum surface, and that the mill is driven at approximately 600 revolutions per minute, i.e. between 550 and 650 rpm. It is to be noted that as a rule it is possible with hammer mills to vary the number of hammers per hammer axle, and in many cases it is preferable not to equip the hammer axles fully with hammers. In the case of the present method, however, as a rule the hammer axles should be fully equipped with hammers. To give one example of the invention, good results were achieved when using a hammer mill made by the firm Lindemann, model "Zerdirator". This mill is driven with 14 hammers per 7.7 square metre of drum surface. Six hammer axles are fitted into the drum at a radius from the drive axle of 57.5 cm. The mill is driven at a speed of 585 revolutions per minute. The anvil has grid apertures of about 50 x 50 mm. The filling level is maintained at a level corresponding to over 90% of the rated peak power capacity of the nominal drive of the mill. Under these conditions the mill volume enclosed between the drum and the anvil grid is filled to an adequate level. The starting steel material was cut material which originated from side trimmings in a hot strip mill. The thickness of this material varied between approximately 2 and 12 mm, while the edge shearings were cut into lengths of approximately 10 to 20 cm. Under the conditions described a good coolant could be obtained with this having a ball-shape factor B of approximately 0.63 and a dispensing weight which varied between 3.6 and 3.8 ton/m 3 . As a result of the heat generated during the hammering and the processing of the material in the mill, the coolant was completely free from grease, dirt and mill scale.

Claims: Method of manufacture of a metallic coolant for a metallurgical bath which is made of steel, the composition of the coolant substantially corresponding to that of the bath, wherein the coolant mainly consists of ball-shaped bodies of sizes not less than 5 mm and not more than 60 mm, the ball-shape factor B (as herein defined) of the coolant having a value of at least 0.57 and wherein material in the form of strip and/or bar shaped steel waste or scrap is processed a plurality of times in a hammer mill which has an anvil grid with square holes of side length in the range 30 to 70 mm, the hammer mill being kept filled during the hammering to a level of at least 85% of the mill volume of the hammer mill. Method according to claim 1 wherein after each processing in the hammer mill the material is sieved to remove fine material and after at least the second said processing is sieved to select the bodies of desired sizes in the range 12 to 60 mm. Method according to claims 1 or 2 wherein the said scrap material has the form of sheet material of thickness in the range 1 to 12 mm and sizes not exceeding 120 x 50 cm, and in the coolant material produces 0.58 ≤ B ≤ 0.62 and the ball-shaped bodies are of sizes not less than 20 mm and not more than 60 mm. Method according to any one of claims 1 to 3 wherein the hammer mill is provided with a supply system for addition of fresh scrap material which system is actuated automatically if the power supplied to the drive means of the mill falls below 90% of the peak capacity of the drive means. Method according to any one of claim 1 to 4 wherein the hammer mill has a rotating drum and hammer-carrying axles distributed over the drum surface, there being at least 18 hammers per 10 m 2 of drum surface and the drum rotation speed being in the range 550-650 revolutions per minute.

Inventors: GROOTHOFF JAN A IR, GROOTHOFF, JAN A., IR.
Applicants: HECKETT HOLLAND BV, HECKETT HOLLAND B.V.
Application year: 1988
Main classification: C21C5
IPC codes: C21C5, C22B1