Improved epoxide resin compositions and method

Abstract: A method of improving epoxy resin compositions to provide a cured resin having improved glass transition temperature and toughness characteristics is provided. The method includes providing in an epoxy resin composition an effective amount of a substituted fluorene unit in the composition. The fluorene component acts as a chain extension agent and provides for increased glass transition temperature and less cross-link density. As a result, improved toughness occurs. In preferred applications a toughening agent is provided in the resin composition, to further enhance toughness. Preferred resin compositions, cured resins and methods of providing improved cured resins are also provided.

Description: The present invention relates to epoxy adhesive resin compositions, and in particular to epoxy adhesive resin compositions which when cured exhibit preferred physical and chemical characteristics. Specifically, epoxy adhesive resin compositions according to the invention cure to exhibit relatively high glass transition temperatures and high ductility or toughness characteristics. Epoxy resins are monomers or pre-polymers that react with curing agents, through the epoxy functional ring, to yield high performance cured resins. Such resins, for example, are widely utilized as: protective coatings for electrical insulation; composite matrix resins; and, as structural adhesives, due to their combination of desired chemical and physical characteristics, such as thermal and chemical resistance, adhesion retention and abrasion resistance. Epoxy resins generally include a plurality of epoxy or oxirane groups. The epoxy groups can react to form a network, typically either through homopolymerization or through addition polymerization with an epoxy curing agent. As used herein, the term "epoxy curing agent" is meant to refer to an agent (or mixture of agents) having three or more reactive sites available for reaction with oxirane groups. As a result of such a structure, an epoxy curing agent can generate a network; i.e. a significantly cross-linked system. Epoxy curing agents are to be distinguished from compounds referred to herein as merely chain extension agents. As used herein, the term "chain extension agent" is meant to refer to a compound which has only 2 sites capable of reaction with oxirane groups. During polymerization, a chain extension agent will typically become lodged between epoxy resin chains, extending same. Little cross-linking occurs, however, since the chain extension agent does not include a third reactive site. As used herein, the term "catalyst" is meant to refer to a compound capable of catalyzing polymerization of a di-epoxy resin-compound with substantial networking or cross-linking. Generally, this occurs through generation of anionic or cationic polymerization reactions, typically involving the oxirane moiety. During polymerization in the presence of a catalyst, a di-epoxy compound is capable of reacting at four sites, and thus substantial cross-linking can result. An example of an epoxy curing agent is a diprimary amine, which is capable of reacting with four epoxy groups. Typical chain extension agents include diphenols, such as resorcinol or bisphenol A. Catalysts include Lewis acids, tertiary amines and imidazoles. Throughout this specification, "catalysts" and "epoxy curing agents" will be referred to collectively as "epoxy curatives" or "curatives". Frequently, it is desired that the cured product have a relatively high glass transition temperature (Tg). The glass transition temperature is the temperature at which the cured resin changes from a relatively strong, high modulus, hard, vitreous state to a low modulus, pliable, elastic state. In general, if it is intended that the cured resin be strong at relatively high temperatures, then a relatively high glass transition temperature will be necessary. A commonly used method of obtaining an improved or higher glass transition temperature is through preparation of a cured resin having a high concentration or degree of cross-linking, or a relatively high concentration of polar groups. A method of achieving high cross-linking is to use an epoxy curing agent having a high level or functionality, or an active homopolymerization agent. In U.S.-A-4,331,582, it is taught that bis[4-(N,N-diglycidylamino)phenyl]methane (TGDDM) may be cured with di(4-aminophenyl)sulfone (DDS), to yield a cured resin having a high cross-link density. Resins having a high cross-link density have several shortcomings. For example, such materials are typically very brittle, and thus are undesirable for many applications. That is, the materials are not very tough or ductile. Also, especially if a high concentration of polar groups is utilized to help obtain high glass temperature, the cured polymer may not be satisfactorily stable to moisture. Generally, to obtain a relatively tough cured resin, it is desired to utilize a composition which exhibits a high degree of cure, and for which, following curing for a reasonably short period of time, a very high percentage of epoxy resin will have reacted to form extended chains within the polymer network. Generally, a high concentration of chain extension agent, such as diphenol, can be utilized to accomplish a high degree of cure. Examples are indicated in U.S.-A-2,934,521 and 3,056,762, and EP-092336. A problem with such conventional uses of chain extension agents with conventional epoxy resins is that while the resulting resins exhibit a relatively high degree of curing and toughness or ductility, generally the glass transition temperature for the cured product is relatively low, because of low cross-link density. A substituted fluorene, in particular 9,9-bis(4,4'-hydroxyphenyl)fluorene, is known to react with conventional epoxy polymers, see for example Holloway, Jeffrey G., Low Flammability Epoxy Polymers Via 9,9-Bis(4,4'-Aminophenyl)Fluorene , p. 14, Master's Thesis, San Jose State U. (1984). A class of compounds which include the above-named substituted fluorene is used, is described below, in certain preferred embodiments of the present invention, to yield advantages in certain resin compositions. In particular, and as will become apparent from the below descriptions, provision in a resin composition polymer units of a formula corresponding to the residues of 9,9-bis-(4,4'-hydroxyphenyl) fluorenes, leads to advantage. What has been needed has been a readily curable epoxy resin adhesive composition for providing a cured resin having both high glass transition temperature and improved toughness or ductility; i.e. achievement of high glass transition temperature without high cross-link density or polarity which may cause brittleness and/or instability to water. Preferably, the desired features are attainable in a resin composition readily cured by a readily available and effective agent. Also, methods have been needed whereby: improved or higher glass transition temperature for a cured resin composite can be generated without substantial loss of toughness; and/or, improved or higher toughness can be obtained without substantial lowering of glass transition temperature. The present invention concerns the provision of epoxy resin adhesive compositions advantageously including fluorene units therein. According to the embodiments of the invention, the fluorene units are provided by means of a substituted fluorene diol component or a substituted fluorene di-epoxide component. The resulting compositions are improved, in general, with respect to glass transition temperature and ductility. Further, in preferred embodiments a toughener composition is provided for further improvement in the characteristics of the resulting cured material. According to a first embodiment of the invention there is provide an adhesive resin composition comprising: (a) a polyepoxide resin having reactive epoxide groups therein; (b) a 9,9-bis(hydroxyphenyl)fluorene chain extension agent reactive with the reactive epoxide groups of the polyepoxide resin, the chain extension agent having the formula wherein each R⁰ and each R¹ is independently selected from hydrogen and other groups inert to the polymerization of epoxide group-containing compounds; and (c) an effective amount of an elastomeric toughening agent. According to a second embodiment of the invention there is provided an adhesive resin composition comprising: (a) a polyepoxide resin having reactive epoxide groups therein; (b) a fluorene di-epoxide having reactive epoxide groups and having the formula: wherein: (i) each R⁰ is independently selected from the group consisting of hydrogen, the halogens, alkyl groups having 1-6 carbon atoms, phenyl, nitro, acetyl, and trimethylsilyl; (ii) each R¹ is independently selected from the group consisting of hydrogen, phenyl, the halogens, and alkyl groups having 1-6 carbon atoms; and (iii) each R² is a terminal epoxy-functionalized alkyl group having 2-6 carbon atoms; (c) a non-fluorene containing diol chain extension agent reactive with the reactive epoxide groups of the polyepoxide resin and the fluorene di-epoxide; and (d) an effective amount of an elastomeric toughening agent. First Embodiment According to this embodiment of the invention, fluorene-containing bisphenols are provided in an adhesive resin composition with a polyepoxide to form, upon curing, a cured resin exhibiting either improved glass transition temperature; improved toughness; or both. This is accomplished through use of fluorene-containing bisphenol(s) in the presence of a conventional epoxy curative. The terms "high glass transition temperature" or "improved glass transition temperature" as used herein are generally intended to refer to cured compositions whose Tg has been increased through application of the present invention. The terms "high" or "improved" toughness are meant to refer to cured compositions exhibiting increased shear strength and/or peel strength, relative to unimproved compositions. That is, typically conventional methods of improving glass transition temperature involve loss of toughness. When, according to the present invention, an epoxy resin composition is provided with an improved glass transition temperature, through inclusion of a chain extension agent therein, without substantial loss of toughness, i.e. no greater than 20% lowering in shear strength, at ambient temperature and pressure, the resin composition will be understood to be "improved". In the alternative, when an epoxy resin is provided with an improvement in toughness, through inclusion of a chain extension agent therein, without substantial lowering of Tg (< typically a 25° C drop), the resin composition will also be understood to have been "improved". In preferred application of the present invention a toughening agent is used in combination with a chain extension agent to achieve a unique improvement in toughness, along with a improvement in glass transition temperature. This will be further understood from examples described herein. For preferred compositions according to the present invention, the glass transition temperature is at least 120°C, and the fracture energy at least 100 Joules/m². An improvement in Tg of at least 25° C without any substantial (typically greater than 20%) loss in toughness as evidenced by peel strength and/or fracture energy generally defines a noticeably improved composition according to the invention. In the alternative, an improvement of at least 20 Joules/m² in fracture energy at ambient temperature and pressure, without any substantial loss (typically greater than 25° C) in Tg also generally defines a noticeably improved composition according to the invention. It will be understood that the amount of Tg and fracture energy change which indicated a "substantial" change will, in part, depend upon the absolute values of the Tg or fracture energy in the unimproved composition. The above stated figures are intended to be representational for what are expected to be commonly used systems. A variety of epoxy resins may be utilized in improved resin compositions according to the present invention, including both aromatic and aliphatic epoxy resins. Also, a variety of fluorene-containing bisphenol compositions (including mixtures) may be utilized, generally including compounds according to the following formula: wherein: each R⁰ and R¹ is independently selected from hydrogen and other groups substantially inert to the polymerization of epoxide group-containing compounds; for example R⁰ is preferably selected from the group comprising: H (hydrogen); the halogens (F, Cl, Br and I); linear and branched alkyl groups having 1-6 carbon atoms; phenyl groups; nitro groups; acetyl groups; and trimethylsilyl groups; and, each R¹ is preferably independently selected from the group comprising: hydrogen (H); phenyl: the halogens; and, linear and branched alkyl groups having 1-6 carbon atoms. When it is said that R⁰ and R¹ are "independently" selected, it is meant that there is no requirement that all R⁰ be the same, or that all R¹ be the same. The terms "fluorene-containing bisphenol composition", "9,9-bis(hydroxyphenyl)fluorene composition" and variants thereof are meant to refer to single compounds and mixtures of compounds according to the above general formula I. It is noted that the diamine-analogue to the above described compound is also a chain-extension agent. This compound and its use to improve epoxy resins is the subject of U.S.-A-4,684,678. That patent is owned by the assignee of the present invention, Minnesota Mining and Manufacturing Co., St. Paul, Minnesota. The di-hydroxy compound is less reactive with epoxy compounds than is the diamine. That is, the resin composition is more readily stored, handled, and applied, prior to cure, when the di-hydroxy agent is used. Also, the di-hydroxy compound generally dissolves better in the resin composition mixture. Further, when the resulting fluorene residue in the resin is a "di-oxy" rather than a "di-amino" residue, the resin will tend to be more stable. There is no universal agreement on the terminology to be utilized in the field of epoxy resins. The term "epoxy resin" has been used to indicate both: any molecule containing at least one group having a 3-member oxirane ring; and, also, both uncured and cured compositions. That is, the cured resin is often referred to as an "epoxy resin" even though the epoxy groups may have been reacted and destroyed during the curing process. Herein, the term "polyepoxide resin" refers to a molecule that contains, or contained prior to reaction, more than one oxirane ring. Generally, herein the term "epoxy resin composition" refers to the uncured composition which, upon curing, cures to a "cured epoxy resin". The term "epoxy resin composition" may be used to refer to resin prior to cross-link; and, to non-reacted or partially reacted material, prior to final reaction and cross-link. When it is said herein that an epoxy resin composition "includes" or "comprises" it is meant that the composition either: comprises a mixture that includes the named components unreacted; or, includes resulting polymer or polymer material formed from polymer-forming reaction(s) of those components, to leave residue(s) therefrom in the polymer; or, the composition includes both. The epoxy resin compositions according to the present invention include an effective amount of a toughening agent therein. A variety of toughening agents are well-known. They generally comprise elastomer molecules and similar compounds which are incorporated into the resin composition but which do not necessarily become chemically involved in the curing process. That is, the compounds may sometimes remain independent in the matrix defined by the cured resin. The presence of the compounds imparts preferred physical characteristics to the cured resin, relating generally to decreased brittleness and increased toughness. In some instances, the toughening agent may be chemically incorporated into the epoxy resin itself, for example as a substituent on the epoxy-containing component. An "effective" amount of a toughening agent is an amount effective to impart an improvement in toughness to the cured resin composition. This may be characterized as an improvement of at least 20% in the peel strength, at ambient temperature and pressure. The term "toughening agent" and variants thereof, as used herein, will be understood to include mixtures containing a plurality of such agents. According to the first embodiment of the present invention, a method of improving an epoxy resin composition, whereby a resulting cured epoxy resin is provided with improved glass transition temperature and improved toughness, comprises provision of a chain extension agent comprising a 9,9-bis(hydroxyphenyl) resin composition. An "effective amount" or the 9,9-bis(hydroxyphenyl)fluorene is an amount sufficient to impart improvement in Tg and/or toughness of the cured resin composition, as above defined. A toughening agent is also provided. As previously indicated, in certain applications of the present invention an epoxy resin composition is provided with both: a 9,9-bis(hydroxyphenyl)fluorene component; and, an epoxy curative component. In this manner, the difunctional fluorene component may be used to increase epoxy resin chain length, without introduction of increased cross-linking. The curative, on the other hand, is used to introduce sufficient cross-linking to result in strength and integrity of cured resin. Typically, the amount of 9,9-bis(hydroxyphenyl)fluorene utilized is such that 5-90% and preferably 9-70%, of reactive oxirane rings in the epoxy resin will react with active hydroxy-groups provided by the substituted fluorene component. Preferably less than 50% of the oxirane units are reacted with the substituted fluorene, for many applications. Generally, both the substituted fluorene and the epoxy resin are di-functional with respect to this reaction, thus the ratio of reactive epoxy resin molecules to reactive fluorene compound should be between 1:0.05 and 1:0.9, and typically 1:0.09 - 1:0.7. By "di-functional" it is meant that each epoxy resin molecule includes only two reactive oxirane moieties, and each 9,9-bis(hydroxyphenyl)fluorene molecule includes only two reactive hydroxy groups. The amount of curative used will depend on its degree of reactivity and in some instances its relative reactivity with respect to the fluorene component. Generally, it should be selected and used in an amount sufficient or effective for reaction with a substantial amount of remaining reactive oxirane moieties in the epoxy resin, i.e. those epoxy or oxirane moieties in excess of the reactive hydroxy-moieties on the fluorene component. The term "a substantial amount" as used herein, in this context, is meant an amount sufficient to generate enough cross-linking to result in a cured polymer having the desired Tg and toughness. As an example, if a curative capable of reacting with 3 oxirane units were selected, it could be used in a molecular ratio of about 2:3 with the excess epoxy resin; i.e. that amount of epoxy resin in excess over the fluorene component. It is noted that mixtures of curatives may be used, including mixtures of components having differing reactivities or available reactive sites for cross-linking. The term "curative" as used herein is meant to include mixtures of curatives. The result of the above is generally improved cured resins. Also, the resin composition is made particularly susceptible to the enhancement by toughening agents. A reason for this may be that the lengths of epoxy-chain units, or polymer backbone, between cross-links is generally increased, by comparison to non-improved resins, due to the presence of the bis(phenyl-substituted) fluorene residue. A result is that the polymer can arguably distort around the toughener, leading to better or enhanced incorporation of the toughener with resulting beneficial effects therefrom. In a typical process according to the present invention, the epoxy resin composition is prepared and is heated to the appropriate curing temperature, for a length of time sufficient to substantially completely cure the composition. Generally, preparation of the composition involves a pre-dispersing of toughening agent in the epoxide compound, followed by mixing of the resulting toughener/epoxide mix with the chain extension agent (i.e. the 9,9-bis(hydroxyphenyl)fluorene composition) and curative. Preferred compositions according to the present invention can be cured between the temperatures of 50° C and 300° C. In conventional manners curing temperature cycles may be applied, to facilitate curing in a desired manner and at a selected rate. Typically, it is desired to have complete curing within a time period of 10 minutes to 12 hours (overnight). The cured resin is effectively used as a bonding film or film adhesive in a variety of applications. Typically, they will be used as adhesive films between first and second substrates, to form a film/substrate arrangement. For example, the adhesive might be used to attach aluminum skins to an airplane framework. In general, the resin compositions can be readily applied as films, and then cured. Preferably, the bonding film is made 0.0005-0.030 inches (.001-.007 cm) thick. For typical applications, a composite is formed comprising a film (preferably 0.001-0.007 cm thick) of the uncured or partially cured resin on a substrate such as a conventional release liner. The release liner may be utilized to apply the adhesive film to location or situs at which an adhesive bond is to be formed. The release liner is then stripped away, exposing the adhesive film in position on the first substrate. A second substrate to be adhered to the first substrate is then brought into contact with the adhesive film, and the composite is heated to complete cure. Typical materials useable as the release liner include: silicone treated flexible substrates such as treated paper or plastic. A typical polyepoxide usable in compositions according to the present invention is 2,2-bis-[4-(2,3-epoxypropoxy)phenyl]propane, compound II below: Upon curing in the presence of a fluorene composition according to the present invention an epoxide resin including such units as III below will result. By formula III it is not meant to suggest that the cured resin comprises only alternating epoxy unit residue and fluorene unit residue, but rather that both are included in the cured resin, generally in the alternating manner. As indicated previously, a substantial amount of the epoxy resin oxirane units will have reacted to form cross-linking, as a result of the curative. The amount of oxirane units linked to substituted fluorene may be varied considerably. However generally, for typical applications 5-90%, and preferably 9-50%, of the oxirane units will have been linked to a substituted fluorene compound as indicated at III above. It will be apparent from a review of formula III above, that many of the advantages of the present invention are derived from the fact polymer units or residues according to the general formula IV below, are provided in a epoxide resin, in a preferred and effective amount. Units according to IV below will be sometimes generally referred to herein as oxy-terminated substituted fluorene units or residues. Preferred epoxide resins (according to formula IV below wherein R⁰ and R¹ are both H) of the present invention include 2 to 78 weight percent, and more preferably 4 to 60 weight percent, of such moieties or units, for achievement of preferred characteristics as described. Formula IV is as follows: wherein: each R⁰ and R¹ is independently selected from hydrogen and other groups substantially inert to the polymerization of epoxide group-containing compounds; for example R⁰ is preferably independently selected from the group comprising: H (hydrogen); the halogens (F, Cl, Br and I); linear and branched alkyl groups having 1-6 carbon atoms; phenyl groups; nitro groups; acetyl groups; and, trimethylsilyl groups; each R¹ is preferably independently selected from the group comprising: hydrogen (H); phenyl; the halogens; and linear and branched alkyl groups having 1-6 carbon atoms. When it is said that R⁰ and R¹ are "independently" selected, it is meant that there is no requirement that all R⁰ be the same, or that all R¹ be the same. When R¹ and R⁰ are not all H, the weight percent of the units will possibly be higher, preferably within the range of 2 to 90%. The Second Embodiment An alternate method of providing resin or polymer units according to IV above in resin compositions or epoxide resins possessing the advantageous characteristics described herein, comprises reaction, during resin formation, of material or extension agent according to general formula V as follows: wherein: each R⁰ and R¹ is independently selected from hydrogen and other groups substantially and inert to the polymerization of epoxide group-containing compound; for example R⁰ is preferably independently selected from the group comprising: H (hydrogen); the halogens (F, Cl, Br and I); linear and branched alkyl groups having 1-6 carbon atoms; phenyl branched alkyl groups having 1-6 carbon atoms; phenyl groups; nitro groups; acetyl groups; and, trimethylsilyl groups; and, each R¹ is preferably independently selected from the group comprising: hydrogen (H); phenyl; the halogens; and linear and branched alkyl groups having 1-6 carbon atoms; and, each R² is an epoxy- functionalized alkyl group capable of reacting through the epoxy group to form epoxy resins, preferably wherein each R² is, independently, a terminal epoxy-functionalized alkyl group having 1-6 carbon atoms. Most preferably each R² is a 2,3-epoxypropyl group. When it is said that R⁰, R¹ and R² are "independently" selected it is meant that there is no requirement that all R⁰ be the same, or that all R¹ be the same, or that all R² be the same. It will be understood that a mixture of materials may be utilized as this component, which is generally referred to herein as the "fluorene di-epoxy" or "fluorene di-epoxide" component. Preferably the resin composition, or bonding film formed therefrom, includes 5 to 97% by weight of the di-epoxide V. Thus, while in the first embodiment the fluorene units IV were incorporated into the resin through reaction of a bisphenol chain extension agent according to general formula I, for the alternate embodiment the units IV are incorporated into the resin Thus, while in the first embodiment the fluorene units IV were incorporated into the resin through reaction of a bisphenol chain extension agent according to general formula I, for the alternate embodiment the units IV are incorporated into the resin through reaction of the said diepoxide compound, which can polymerize with other chain extenders such as diol chain extenders including copolymerization with other epoxy compounds. A preferred such fluorene di-epoxide compound is the diglycidyl ether, epoxide of 9,9-bis (4-hydroxyphenyl) fluorene, VI, (for example available under the Tradename EPON RSS 1079, from Shell Chemical Co.). Epoxide resin compositions containing specific diepoxides within Formula V are disclosed in US-A-4 707 534 but only in cross-linked compositions not chain extended compositions. Formula VI is as follows: wherein: R⁰ and R¹ are H. In general, similar principles, procedures, features and advantages are of concern when the fluorene di-epoxide compounds V are used, as those which were of concern and were described above for the fluorene bis-hydroxy chain extension materials. For example a variety of epoxy resins may be utilized to copolymerize with the material, including both aromatic and aliphatic epoxy resins. Also, the compositions include an effective amount of a toughening agent therein, for the development of preferred physical characteristics in the cured resin, generally relating to improved Tg and/or toughness. Preferably, the amount of fluorene di-epoxide V (when R⁰ and R¹ are H and R² is 2,3-epoxypropyl) utilized is such that 2 to 78%, by weight, of the resulting resin comprises the fluorene residue units IV. In general, this is readily achieved by providing a ratio of molecules of reactive non-fluorene copolymers and reactive non-fluorene chain extenders to diepoxy fluorene of between 1:0.05 and 1:0.9 and preferably between 1:0.09 and 1:0.7. In preferred compositions a substantial amount of diol chain extender is used. Preferably the ratio of reactive epoxy molecules (including diepoxide fluorene materials), to diol chain extenders should also be between 1:0.05 and 1:0.9, and preferably at 1:0.09 to 1:0.7. Detailed Description of the Preferred and Alternate Embodiments As required, detailed embodiments of the present invention are described in detail herein. FIRST EMBODIMENT - Bis(hydroxphenyl) Fluorene Chain Extension Agent Preferred improved epoxy resin compositions according to a first embodiment of the present invention include: polyepoxides or residue therefrom; a chain extension agent composition, or residue therefrom (i.e. the fluorene-containing bisphenol component); tougheners; and, curative, or residue therefrom (curing agent and/or catalyst), as follows: The Epoxide Constituent For preferred compositions according to the present invention, the epoxide constituent comprises any of a variety of polyepoxides, and may include mixtures. It will be understood that the scope of the terms used herein in discussion of this component, and other components, in the resin composition are meant to include residues from reaction or partial reaction with other components to form polymeric (or oligomeric) structures. Polyepoxides are well known. Preferred aromatic polyepoxides for use according to the present invention include: the polyglycidyl ethers or polyhydric phenols; glycidyl esters of aromatic carboxylic acids; N-glycidylaminobenzenes; and, glycidylamino-glycidyloxybenzenes. Examples of N-glycidylaminobenzenes suitable for use in the epoxy resin compositions of the present invention include the di-and polyglycidyl derivatives of: benzeneamine; benzene diamines; napthylenamine; and, naphthylene diamines. Such compounds include: N,N-diglycidylbenzeneamine; N,N-diglycidylnaphthalenamine; 1,4-bis(N-glycidylamino)benzene; and, 1,3-bis(N,N-glycidylamino)benzene. The polyglycidyl derivatives of aromatic aminophenols are described in U.S.-A-2,951,825. An example of these compounds is N,N-diglycidyl-4-glycidyloxy-benzeneamine. Aliphatic polyepoxides may also be used, and are well known. Most preferably, the aromatic polyepoxides used in resin compositions according to the invention are the polyglycidyl ethers of polyhydric phenols. The preferred aliphatic epoxides are the diglycidylethers of cyclohexane dimethanol. The polyepoxides are exemplified by the following: vinyl cyclohexene dioxide; epoxidized mono-, di- and triglycerides; butadiene dioxide; 1,4-bis(2,3-epoxypropoxy)benzene; 1,3-bis(2,3-epoxypropoxy)benzene; 4,4′-bis(2,3-epoxypropoxy)diphenyl ether; 1,8-bis(2,3-epoxypropoxy)octane; 1,4-bis(2,3-epoxypropoxy)cyclohexane; 4,4′-bis(2-hydroxy-3,4-epoxybutoxy)diphenyl dimethyl methane; 1,3-bis(4,5-epoxypentoxy)-5-chlorobenzene; 1,4-bis(3,4-epoxybutoxy)-2-chlorocyclohexane; diglycidyl thioether; diglycidyl ether; 1,2,5,6-diepoxy-hexyne-3; and, 1,2,5,6-diepoxyhexane. Other usable epoxides are found in Handbook of Epoxy Resins , Lee and Neville, McGraw-Hill, New York (1967), and U.S.-A-3,018,262. Some compounds include epoxides listed in U.S.-A-3,298,998. These compounds include: bis[p-(2,3-epoxypropoxy)phenyl]cyclohexane; 2,2-bis[p-(2,3-epoxypropoxy)phenyl]norcamphane; 5,5-bis[(2,3-epoxypropoxy)phenyl]hexahydro-4,7-methanoindane; 2,2-bis[4-(2,3-epoxypropoxy)-3-methylphenyl]hexahydro-4,7-methanoindane; and, 2-bis[p-2,3-epoxypropoxy)phenyl]-methylene-3-methylnorcamphane. The Chain Extension Agent The chain extension agent usable according to the first embodiment of the present invention is a 9,9-bis(hydroxyphenyl)fluorene composition and preferably includes at least one compound of the general formula VII, as follows: wherein: each R⁰ and R¹ is independently selected from substituents non-reactive with epoxy groups in the resin; for example: each R⁰ is preferably independently selected from the group comprising hydrogen (H); the halogens (F, Cl, Br and I); linear or branched alkyl groups having 1-6 carbon atoms; phenyl-; nitro-; acetyl-; and trimethylsilyl-; and, each R¹ is independently selected from the group comprising: hydrogen (H); phenyl-; the halogens; and, alkyl groups having 1-6 carbon atoms. The 9,9-bis(hydroxyphenyl)fluorene composition may include more than one compound according to formula VII. When it is herein said that R⁰ and R¹ are "independently" selected, it is meant that there is no requirement that all groups R⁰ be the same group, or that all groups R¹ be the same group. Examples of chain extension agents (bisphenol fluorenes) according to formula IV include: 9,9-bis(4-hydroxyphenyl)fluorene, 9,9-bis(3-methyl-4-hydroxyphenyl)fluorene, 9,9-bis(3-chloro-4-hydroxyphenyl)fluorene, 9,9-bis(3-ethyl-4-hydroxyphenyl)fluorene, 9,9-bis(3,5-dimethyl-4-hydroxyphenyl)fluorene, 9,9-bis(3,5-dichloro-4-hydroxyphenyl)fluorene, 2-iodo-9,9-bis(4-hydroxyphenyl)fluorene, 3-bromo-9,9-bis(4-hydroxyphenyl)fluorene, 1-chloro-9,9-bis(4-hydroxyphenyl)fluorene, 2-methyl-9,9-bis(4-hydroxyphenyl)fluorene, 2,6-dimethyl-9,9-bis(4-hydroxyphenyl)fluorene, 1,5-dimethyl-9,9-bis(4-hydroxyphenyl)fluorene, 2-fluoro,9-9-bis(4-hydroxyphenyl)fluorene, 1,2,3,4,5,6,7,8-octafluoro-9,9-bis(4-hydroxyphenyl)-fluorene, 2,7-dinitro-9,9-bis(4-hydroxyphenyl)fluorene, 2-chloro-4-methyl-9,9-bis(4-hydroxyphenyl)fluorene, 2,7-dichloro-9,9-bis(4-hydroxyphenyl)fluorene, 2-acetyl-9,9-bis(4-hydroxyphenyl)fluorene, 2-chloro-9,9-bis(4-hydroxyphenyl)fluorene, and 2- t -butyl-9,9-bis(4-hydroxyphenyl)fluorene. Mixtures of hydroxyphenyl fluorenes may be utilized as the chain extension agent, in compositions according to the present invention. Mixtures may be preferred in some instances because they often have a melting point that is lower than the melting point of an individual hydroxyphenyl fluorene, and thus facilitate curing of the epoxy resin composition at a temperature lower than might otherwise be possible. The amount of chain extension agent used in resin compositions according to the present invention may be varied somewhat. Preferably, the amount of chain extension agent used is based on the amount of reactive epoxide functionality in the polyepoxy resin, generally according to the formula: 1 reactive hydroxy equivalent or less of bis(hydroxyphenyl)fluorene per equivalent of epoxide group present in the polyepoxide component. A wide range is possible in applications of the present invention. A range of 0.5 to 0.9 is preferable, as it permits a significant amount of epoxide group to react in cross-linking. A most preferred range of ratios of fluorene hydroxy equivalent to reactive epoxy or oxirane equivalent is 0.09-0.5. The term "hydroxy equivalent" when used with respect to the fluorene-containing bisphenol is meant to refer to equivalents of reactive hydroxy groups, i.e. the 9-hydroxy groups. Reference to equivalents of epoxy group in the polyepoxide is meant to refer to reactive epoxy groups. Curing Agents and Catalysts (Curatives) The epoxy curatives, curing agents and/or catalysts suitable for use in compositions according to the present invention include those conventionally used for curing epoxy resin compositions and forming cross-linked polymer networks. Such agents include aliphatic and aromatic primary amines, for example: di(4-aminophenyl)-sulfone; di-(4-aminophenyl)ethers; and 2,2-bis(4-aminophenyl)propane. Such compounds also include aliphatic and aromatic tertiary amines such as dimethylaminopropyl-amine and pyridine, which may act as catalysts to generate substantial cross-linking. Further, boron trifluoride complexes such as BF₃-monoethanolamine; imidazoles such as 2-ethyl-4-methylimidazole; hydrazides such as aminodihydrazide; guanidines such as tetramethyl guanidine; and, dicyandiamide are useful as curing agents or catalysts. The amount of curing agent and/or catalyst needed will vary from resin to resin and is generally to be provided in such an amount as to be effective in causing substantially complete curing within a desired length of time. A typical composition according to the present invention includes 1-30%, by weight, of curing agent. It will be understood that the final properties of the cured resin composition will be greatly influenced by the relative amounts of cross-linking and epoxy chain extension caused respectively by the curative and chain extension agent. Generally, this is set by selecting the amount of equivalents of substituted fluorene(s) as the chain extension agent, and then using an appropriate amount of curative to achieve curing at a selected rate. The Toughening Agent Toughening agents for use in compositions of the present invention generally comprise: elastomer molecules, separate elastomer precursor molecules; combination molecules that include epoxy-resin segments and elastomeric segments; and, mixtures of such separate and combination molecules. The combination molecules may be prepared by reacting epoxy resin materials with elastomeric segments; the reaction leaving reactive functional groups, such as unreacted epoxy groups, on the reaction product. The general use of tougheners in epoxy resins is well-known, and is described in the Advances in Chemistry Series No. 208 entitled "Rubbery-Modified Thermoset Resins", edited by C.K. Riew and J.K. Gillum, American Chemical Society, Washington, 1984. The amount of toughening agent to be used depends in part upon the final physical characteristics of the cured resin desired, and is generally determined empirically. For a typical preferred embodiment, the toughening agent comprises 2-40% and preferably 4-20% by weight of the resin composition. Some useful toughening agents include: carboxylated acrylonitrile/butadiene vulcanizable elastomer precursors (such as Hycar® CTBNX and Hycar® 1072, B.F. Goodrich Chemical Co.); butadiene polymer (Hycar® CTB, B.F. Goodrich Chemical Co.); amine functional polyethers such as: HC1101 (a 10,000 MW, primary amine-terminated, compound; Minnesota Mining and Manufacturing Co.; St. Paul, Minn.), Jeffamine® (Texaco Chemical Co.); and isocyanate-functional polyethers such as: Adiprene® (Uniroyal Chemical Co.); functional acrylic rubbers including acrylic core/shell material, such as Acryloid® KM330 and 334, Rohm & Haas; and core/shell polymers, such as methacrylate-butadiene-styrene (MBS) copolymer wherein core is cross-linked styrene/butadiene rubber and shell is polymethylacrylate (Acryloid® KM653, Acryloid® KM680; Rohm and Haas). As used above, for acrylic core/shell materials "core" will be understood to be acrylic polymer having Tg<0° C and "shell" will be understood to be an acrylic polymer having Tg>25° C. Tougheners may include epoxy-terminated compounds, which can be incorporated into the polymer backbone. A typical, preferred, list of tougheners comprises: acrylic core/shell polymers; styrene-butadiene/methacrylate core/shell polymers; polyether polymers; carboxylated acrylonitrile/butadienes; and, carboxylated butadienes. An advantage could be obtained from the provision of the chain extension agent in a composition with an epoxy resin even in the absence of a toughening agent as described above. However, in the composition of the invention, particular advantage is achieved from the presence of the toughening agent, as indicated by Example 2, and as previously suggested. It is a feature of the present invention that improved adhesive resins as disclosed herein are enhanced with respect to, the beneficial effects of tougheners. Adjuvants Various adjuvants may be added to compositions according to the present invention, to alter the characteristics of the cured composition. Included among useful adjuvants are: thixotropic agents such as fumed silica; pigments such as ferric oxide, brick dust, carbon black, and titanium oxide; fillers such as silica, magnesium sulfate, calcium sulfate, and beryllium aluminum silicate; and, clays such as bentonite. Amounts of up to 200 parts of adjuvant per 100 parts of epoxy resin composition may be effectively utilized. Formation and Use of the Epoxy Resin Compositions Generally, the toughening agent is pre-dispersed in the epoxide compound. The toughener-containing epoxide is then mixed with a curative and the chain extension agent to form a substantially uniform mixture. The mixture is cured upon heating for an appropriate length of time. While the curing reaction may take place slowly at room temperature, it is preferably brought about by heating the mixture to 50°C to 150°-300° C for an appropriate length of time. Often heating cycles may be utilized, such as, for example, 50°C for 0.25-1.0 hours, 150-200° C for 0.5-2.0 hour and 175-250⁰ C for 1.0-5.0 hours. In some instances it may be preferred to react all of the chain extension agent with the resin, before curing is initiated. This will, in part, depend on the percent of chain extension agent to be incorporated. It is observed that compositions according to the present invention are particularly advantageous, by comparison to the compositions of U.S.-A-4,684,678. Generally, this results from greater stability of the di-hydroxy compound relative to the diamine. The adhesive resin compositions of the invention are especially valuable when the operating temperature of the article or material is expected to be substantially elevated over room temperature. THE SECOND EMBODIMENT - FLUORENE DIEPOXIDE EXTENSION AGENT As described above, in the alternative embodiment the oxy-terminated substituted fluorene units IV are introduced into the polymer resin through reaction of a diepoxy compound (or extension agent) including the fluorene residue therein, rather than through a dihydroxy chain extension agent. Preferred improved epoxy resin compositions according to this embodiment of the present invention include: a fluorene di-epoxide component, or residue therefrom; a non-fluorene containing diol chain extension component; an epoxy curative component; toughener; and, curative or residue therefrom (curing agent and/or catalyst), as follows: The Fluorene Di-epoxy Constituent As previously described, for compositions according to the alternate embodiment of the present invention, the fluorene di-epoxy constituent comprises any of a variety of di-epoxides, including mixtures, of the following general formula V: wherein: each R⁰ and R¹ is independently selected from hydrogen and other groups substantially and inert to the polymerization of epoxide group-containing compound; for example R⁰ is preferably independently selected from the group comprising: H (hydrogen); the halogens (F, Cl, Br and I); linear and branched alkyl groups having 1-6 carbon atoms; phenyl groups; nitro groups; acetyl groups; and, trimethylsilyl groups; and, each R¹ is preferably independently selected from: hydrogen (H); phenyl; the halogens; and linear and branched alkyl groups having 1-6 carbon atoms; and, each R² is an epoxy- functionalized alkyl group capable of reacting through the epoxy group to form epoxy resins, preferably wherein each R² is, independently, a terminal epoxy-functionalized alkyl group having 1-6 carbon atoms. Most preferably each R² is a 2,3-epoxypropyl group. When it is said that R⁰, R¹, and R² are "independently" selected it is meant that there is no requirement that all R⁰ be the same, or that all R¹ be the same, or that all R² be the same. It will be understood that a mixture of materials may be utilized as this component, which is generally referred to herein as the "fluorene di-epoxy" or "fluorene di-epoxide" component. Preferably, the fluorene diepoxide is a diglycidyl ether epoxide of bis(hydroxyphenyl) fluorene, and more preferably it is the diglycidyl ether epoxide of a 9,9-bis(hydroxyphenyl) fluorene. Most preferably, it is 9,9-bis(4,4′-(2,3-epoxypropoxy)phenyl) fluorene: wherein: R⁰ and R¹ are H. Chain Extension Agents If the substituted fluorene residue IV is incorporated into the resin by means of a fluorene di-epoxide V, according to the second embodiment described herein, a non-fluorene containing diol chain extension agent is necessary. A variety of materials may be utilized as the non-fluorene containing diol chain extension agent, including mixtures of materials. For example, the non-fluorene containing chain extension agent may include conventional bisphenols such as bisphenol A, bisphenol F, bisphenol S, resorcinol, catechol, hydroquinone and mixtures thereof. Copolymerizing Epoxide Constituent In some applications, according to the alternate embodiment, compositions according to the invention may include polyepoxides or mixtures of polyepoxides copolymerizable with the fluorene di-epoxide. It will be understood that the scope of the terms used herein, with respect to this component, as with other components, in the resin composition is meant to include residues from reaction or partial reaction with other components to form polymeric structures. Polyepoxides are well known. Preferred aromatic polyepoxides for use as this component, in compositions according to the present invention, include: the polyglycidyl ethers of polyhydric phenols; glycidyl esters of aromatic carboxylic acids; N-glycidylaminobenzenes; and, glycidylaminoglycidyloxybenzenes. In general, the non-fluorene containing, copolymerizable epoxide constituent maybe generally as described for the "epoxide constituent" of the previously described embodiment. Curing Agents and Catalyst (Curatives) The epoxy curatives, curing agents and/or catalysts suitable for use in compositions according to this embodiment include those materials conventionally used for curing epoxy resins compositions and forming cross-linked polymer networks. The agents include primary aminos including both aliphatic and aromatic primary amine, for example: di(4-aminophenyl)sulfone; di-(4-aminophenyl) ether; and, 2,2-bis(4-aminophenyl)propane. Such compounds also include aliphatic and aromatic tertiary amine such as dimethylaminopropylamine and pyridine, which may act as catalyst to generate substantial cross-linking. Further, boron trifluoride complexes such as BF₃-monoethanolamine; imidazoles such as 2-ethyl-4-methyl-imidazole; hydrazides such as aminodihydrazide; guanidines such as tetramethyl guanidine; and, dicyandiamide are useful as curing agents or catalysts. In general, the curing agents are catalysts (curatives) may be as previously described for the embodiment utilizing bis(hydroxyphenyl) fluorene chain extension agents, and the curatives may be utilized in a same manner and a similar amount by weight. The Toughening Agent Toughening agents for use in compositions according to the embodiment of the present invention involving the fluorene di-epoxide component as the component for introducing of substituted fluorene residue IV into the resin, may be the same toughening agents as those usable with the first embodiment described, wherein bis(hydroxyphenyl) fluorene was utilized to introduce the residue IV. As previously described, in general such toughening agents comprise: elastomer molecules, separate elastomer precursor molecules; combination molecules that include epoxy-resin segments and elastomeric segments; and, mixtures of such separate and combination molecules. Adjuvants Various adjuvants maybe utilized in compositions according to the second embodiment. Generally they may be as described above for the first embodiment. Formation and Use of the Epoxy Resin Adhesive Compositions of the Second Embodiment In general, epoxy resin adhesive compositions prepared from constituents according to the second embodiment may be formed and used in manners generally analogous to those described above for epoxy resin compositions formed according to the first embodiment. That is, generally the toughening agent is pre-dispersed in the epoxide compound(s). It is noted, however, that in the case of the second embodiment the epoxide compound(s) includes the fluorene di-epoxide compound. The toughener-containing epoxide is then mixed with a curative, and chain extension agent utilized, to form a substantially uniform mixture. It is noted that the diol chain extension agent, for the second embodiment, will generally comprise any conventional diol chain extension agents, such as those described above. The composition or mixture is cured upon heating for an appropriate length of time. While the curing reaction may take place slowly at room temperature, it is preferably brought about by heating the mixture to 50° C to 150°-300° C for an appropriate length of time. In some instances heating cycles may be utilized, such as, for example, 50° C for 0.25 to 1.0 hours, 150 to 200° C for 0.5.to 2.0 hours and 175° to 250° C for 1.0 to 5.0 hours. In some instances, it maybe preferred to react substantially all of the chain extension agents with the resin, before curing is initiated. This will, in part, depend upon the percent of chain extension agent to be incorporated. In general, compositions prepared according to the alternate embodiment will exhibit similar properties to those compositions prepared according to the first embodiment described, and will be analogously useful. They may, for example, be formed into films applied by means of a release liner or substrate, to a site for use. EXAMPLES The following examples illustrate specific embodiments and applications of the present invention. In all examples all parts and percents are by weight, and temperatures are in degrees Centigrade unless otherwise noted. In the examples, the overlap shear strength and floating roller peel strength of cured resins is given. This is generally as determined and described in ASTM D-3167-7b and MMM-A-132, unless otherwise noted. Results are typically calculated in megapascals (MPa) and/or kilograms per centimeter (kg/cm). Peel strength and fracture energy relate to toughness and ductility in that the higher the peel strength and fracture energy, the greater the toughness of the material. This is interpreted herein as improved toughness or ductility. FORMATIONS ACCORDING TO THE FIRST EMBODIMENT EXAMPLE 1 The 9,9-bis(4-hydroxyphenyl)fluorene chain extension agent was prepared as follows: A 500 ml 3-necked flask was equipped with a thermometer and means for introducing hydrogen chloride. To the flask were added: 90.0 g fluorene; 282.0 g phenol; and, 3.1 g 3-mercaptopropionic acid. The mixture was heated to 55° C, with stirring. Anhydrous chloride (9.0 g) was flushed through the reaction flask over about a 30 minute period. The mixture was reacted for about 6 hours at 55° C, and was poured into 3 liters of methanol. The precipitate was collected and recrystallized from 1,2-dichloroethane to yeild 130 g of white crystals, melting pt. 224.5-225.5°C. Conventional analysis indicated that the crystals were 9,9-bis(4-hydroxyphenyl)fluorene. This material is referred to herein as monomer F. EXAMPLE 2 Polymerization of an epoxy resin with 9,9-bis(4-hydroxyphenyl)fluorene. To a resin flask fitted with a mechanical stirrer and a thermometer: 49 g of diglycidyl ether of bisphenol A, epoxide (equivalent weight 193-293) (Epon® 829, Shell Chemical Co.); and, 12.25 g 9,9-bis(4-hydroxyphenyl)-fluorene (monomer F), prepared as above, were added. The mixture was heated to about 121° C with continuous stirring, and was maintained at 115-127° C until a uniform mixture was obtained, i.e. 15-30 minutes. Polytetramethylene oxide diprimary amine, 12.5 g, Mw about 12,000 (HC 1101, 3M Co.), which had been melted at about 82° C was added slowly to the reaction flask with stirring. The mixture was heated at about 177-204° C for about 120 minutes, was dumped and cooled at about 25° C silicone treated kraft paper, and was then dissolved in an 85-15 mixture of methyl ethyl ketone and toluene. This mixture is referred to herein as "Component A". A "Component B" was prepared by milling together: 8.1 g of diglycidyl ether of bisphenol A, epoxide equivalent weight about 182-200 (Epon® 828, Shell Chemical Co.); 4.5 g dicyandiamide (Aero®, American Cyanamid Co.) and 1.8 g of a reaction product of toluenediisocyanate and dimethylamine (TDI Urea), on a 3-roll paint mill to a fineness of NS 4+. NS 4+ indicates a particle size ≦0.005 cm. The grinding is done until when film of the material is viewed at grazing incidence 5-10 particles within a 3 mm band appear through the surface. The following were added to a double tite tin: 2.5 g Epon® 828; 10.0 g condensation polymer of epichlorohydrin and Bisphenol A, epoxide equivalent weight about 230-280 (Epon® 834, Shell Chemical Co.); 12.25 g 9,9-bis(4-hydroxyphenyl)fluorene; Component A; and, Component B. A double tite is a can having a friction top which seals against both an inside and outside lip, for example a typical paint can. The mixture was blended on a roller mill. For testing purposes a dry film was prepared by coating the mixture on a silicone treated polyethylene coated paper backing at a wet thickness of about 0.25 mm, with a drying of the film for about 60 minutes at about 24° C followed by treatment for about 60 minutes at 66° C in a fresh air circulating oven. This material is identified herein as "Film A". The shear strength was determined according to Federal Specification MMM A-132A and peel strength was determined according to ASTM D-3167-7b using 2024 T-3 aluminum panels which had been first degreased by exposing panel to hot (about 138° C) vapors of perchloroethylene for about 15-20 minutes, drying in air, immersing in alkaline degreaser ("Oakite Aluminum Cleaner 164", Oakite Products Inc., Berkeley Heights, N.J.) at about 82° C for about 10 minutes, and rinsing with tap water and then deoxidizing by immersing in a 71° C bath of concentrated sulfuric acid, sodium dichromate and water for about 10 minutes (this is known as Forest Lake Products Etch Systems or FPL Etch System) followed by rising with deionized water and finally anodized by immersion in phosphoric acid at 22° C with applied voltage of 15 volts for 20-25 minutes followed by rinsing with tap water (test for water break) and air drying 10 minutes at 22° C and 10 minutes at 71° C. The total area to be bonded on both panels was primed with corrosion inhibiting primer for aluminum (3M EC-3924B). Test bonds were assembled using a single layer of film, and assemblies were cured in an autoclave at a pressure of about 20.7 N/cm² for 90 minutes at about 132° C - 138° C. Glass transition temperature was determined using a Differential Scanning Calorimeter (DSC). Test results are presented in Table I below. For a comparative example, an adhesive film was analogously prepared using Bisphenol A in place of Monomer F. In particular, using an analogous procedure to that described above, a "Film B" was prepared using the following: Ingredient Amount Component A: Epon® 829 44.3 g Bisphenol A 8.0 HC-1101 12.4 Component B: Epon® 828 8.1 g Dicyandiamid 4.5 TDI Urea 1.8 Epon® 828 7.2 Epon® 834 10.0 Bisphenol A 8.0 Film B was tested as described above, and the results are also presented in Table I below. Property Cure Temp. °C Test Temp. °C Test Results Film A Film B Tg (C) 127.5 109.7 Peel (kg/cm) 135 22 13.0 12.9 Overlap Shear (MPa) 135 22 38.5 34.5 Overlap Shear (MPa) 94 26.1 18.8 Overlap Shear (MPa) 121 21.2 11.3 Overlap Shear (MPa) 149 13.7 3.0 Overlap Shear (MPa) 177 3.1 1.7 The data of Table I indicates the replacement of bisphenol A with Monomer F produces substantial increase in glass transition temperature (Tg), and hence a higher (improved) temperature performance, without a detraction from peel and shear strengths. That is, Monomer F results in higher glass transition temperature without any high density cross-linking. It is noted that at higher temperatures, improvement in shear strength (i.e. ductility) was observed. EXAMPLE 3 Comparative Formulations The following examples concern comparisons between formulations and demonstrate increased Tg and ductility attainable using epoxy compositions of the present invention. Six epoxy compositions were prepared using the formulations outlined in Table II below, by mixing the combined ingredients in a container and heating in an oven for 150° C for about 30 minutes, followed by heating at 177° C for about 240 minutes. The six compositions are identified as A, B, C, D, E and Ex. 2′. The cured resins were allowed to cool at 25° C, were cut into suitable sample sizes and were tested for fracture energy, determined by compact tension according to ASTM E-399-83. They were also tested for glass transition temperature (Tg), as measured by Differential Scanning Calorimeter. The results were as follows: Table II demonstrates several embodiments of the invention. The addition of the diphenol in B and C demonstrates that the use of chain extension agent (Monomer F or bisphenol A) in place of a portion of the curative used in comparative Example A will significantly increase the toughness of the cured resin, see Comparative Examples B and C. However, when bisphenol A is used as a chain extension agent (Comparative Example C), a drastic and undesirable reduction in the glass transition temperature results. When the fluorene bisphenol, Monomer F, is used the toughness is increased as much as it was for bisphenol A; but a much higher glass temperature results. The data also demonstrates the beneficial effects of the addition of a rubber toughening agent to the epoxy compositions. When a toughening agent was added to the highly cross-linked composition (Comparative Example D), the improvement in toughness energy was minimal. However, when the toughener was added to the chain-extended compositions, the effect on toughness was much more pronounced, see Example 2′ and comparative Example E. Again, when Monomer F was used as the chain extension agent, the glass transition temperature is much higher than were bisphenol A was used. Formulation According to the Alternate Embodiment EXAMPLE 4 This example shows an alternate chemical route to achieve a cured adhesive resin composition similar to film A of Example 2 or Example 2′ above. The composition of Example 2, was shown to have an advantageous balance of relatively high glass transition temperature and high toughness. The alternate chemical route, generally corresponding to the second embodiment of the invention described in detail above, involves utilization of a fluorene di-epoxide, in place of the bis(hydroxyphenyl) fluorene chain extension agent. To a resin flask fitted with a mechanical stirrer and a thermometer: 21.8 gm. of "Epon" 829; and 22.5 gm. diglycidyl ether of 9,9-bis(4-hydroxyphenyl) fluorene, epoxide (equivalent weight approximately 242) ("Epon RSS 1079, Shell Chemical Company) were added. The mixture was heated to about 121° C. with continuous stirring, and was maintained at 115°-127° C until a uniform mixture was obtained (15 to 30 minutes). Then, 11.8 gms. of 2,2-bis(p-hydroxyphenyl)propane (BPA-154, Shell Chemical Company) were added and blended until dissolved. HC 1101, 11.0 grams., which had been melted at about 82° C was added slowly to the reaction flask, with stirring. The mixture was heated at about 135°-163° C, for about 120 minutes, was dumped and cooled at 22° C on silicone treated kraft paper, and was then dissolved in an 80-20 mixture of methyl ethyl ketone (MEK) and toluene, by placing in a double tite tin and rolling the mixture on a roller mill. When dissolved, the following ingredients were added to the mixture: 12.0 g. "Epon" RSS 1079; 4.2 g. BPA-154; 18.8 g. diglycidyl ether of bisphenol A, epoxide (equivalent weight approximately 174)(DER 332, Dow Chemical Company); 3.0 g. diglycidyl ether of 1,4-cyclohexane dimethanol (equivalent weight approximately 165)(MK 107, Willmington Chemical Corp.); 2.0 g. carboxy-functional liquid copolymer of acrylonitrile and butadiene (Hycar 1300 x 31, B.F. Goodrich Company); 4.5 g. dicyandiamide pre-ground to an average particle size of about 10 microns; 1.4 g. TDI urea pre-ground to a average particle size of about 10 microns, and tetrahydrofuran (THF), blending with mechanical stirring ro form a resin solution of about 69.5% solids content and about 3.9:1.0:3.8 MEK:toluene:THF. For testing purposes a dry film was prepared by coating the mixture on a silicone treated polyethylene coated paper backing, at a wet thickness of about 0.25 mm., with a drying of the film for about 60 minutes to about 90 minutes, at about 22° C followed by treatment for about 60 minutes at 66° C in a fresh air circulating oven. The material is identified herein as "film 5A". The blister detection shear strength was determined according to United States Federal Specification MMM A-132A (incorporated herein by reference) and peel strength was determined according to ASTM D-3167-7b (incorporated herein by reference) using aluminum panels described in Example 2 above. The panels were prepared as in Example 2 above, except they were not subjected to the anodizing step of immersion in phosphoric acid followed by tap water rinse. The total area to be bonded on both panels was primed with corrosion inhibiting primer for aluminum (3M EC-3960). Test bonds were assembled using a single layer of "film 5A" and assemblies were cured in an autoclave at a pressure of 20.7 N/cm² for 90 minutes at about 132° C to 138° C. Test results are presented in Table III below. Property Cure Temp. C Test Temp. C Test Results Film 5A Peel (kg/cm) 135 22 16.2 Blister Detection Overlap Shear (MPa) 135 22 39.4 Blister Detection Overlap Shear (MPa) 121 28.8 Blister Detection Overlap Shear (MPa) 149 18.8 The date of Table III indicates that the introduction of fluorene-containing moieties as di-epoxide component (instead as diol chain extension agent) also produces a high (improved) temperature shear performance, without a detraction from peel strength. Glass transition temperature (Tg) was not measured, but would be expected to be similar as that for film A of Example 2 above. Comparative Formulations EXAMPLE 5 The following Examples concern comparisons between formulations with and without fluorene-containing component (provided by means of a fluorene di-epoxy) and demonstrate increased hot strength obtainable without loss of toughness (as measured by peel strength of the cured adhesive). Three toughened epoxy compositions were prepared using the formation outlined in Table IV below, by first melting the epoxide components, in the amounts stated, in a resin flask fitted with a mechanical stirrer. HC 1101, which has been melted at about 82° C was added slowly to the reaction flask, with stirring. The mixture was heated to about 115°-135° C for about 60 minutes, cooled to about 25° C, and then ethyl acetate was added with stirring until a uniform mixture resulted. Diaminodiphenylsulfone, which had been jet milled to about 5 to 10 micron particle size, was added to the mixture with stirring to yield a final coating solution of about 83-87% solids content. For testing purposes, a dry film was prepared by coating the mixture on a silicone treated polyethelene coated paper backing at a wet thickness of about 0.23 mm., with a drying of the film for about 60-90 minutes at about 22° C, followed by treatment for about 60 minutes at about 60° C under fresh air circulating oven. The blister detection shear strength was determined as in Example 4, except that the panels for determining shear strength were primed with 3M EC-3917 in place of 3M EC-3960. Test bonds were assembled using a single layer of the film as prepared above, cured in an autoclave at a pressure of about 13.8 N/cm² for about 120 minutes at about 177° C (174°-180° C). Test results are presented in Table V below. Ingredient Amount Ex. 4A Ex. 4B Ex. 4C "Epon" 828 50 50 25 diglycidyl ether of bisphenol A, epoxide 50 25 25 "Epon" RSS 1079 ---- 25 50 HC 1101 14.4 15.4 15.1 diaminodiphenylsulfone 29.5 38.9 35.9 Property Cure Temp. C Test Temp. C Test Results 4A 4B 4C Peel (N/25 mm) 177 22 56.9 61.3 96.3 Blister Detection Overlap Shear (MPa) 177 149 6.2 13.2 15.0 Blister Detection Overlap Shear (MPa) 177 4.0 10.5 14.3 Blister Detection Overlap Shear (MPa) 204 1.9 3.5 7.8 Blister Detection Overlap Shear (MPa) 232 1.4 2.4 4.1 The data of Table V indicates that increasing amounts of fluorene-containing component produces corresponding increases in shear strength at high test temperatures and peel strength (toughness). Although glass transition temperatures were not measured, based on the high temperature shear performance 4C would be expected to be of highest Tg, and 4A would be expected to be of lowest Tg, analogously to Example 2. Further General Statements of the Invention From the previous examples, it will be understood that generally according to the present invention an improvement in the cured product of an epoxy resin adhesive is accomplished through provision of an agent containing a selected fluorene residue IV as an extension agent in the epoxy resin composition to be cured or cross-linked. The agent may be provided as a diol chain extension agent or as a chain extending diepoxide. Specifically, improvement is obtained through the utilization of a 9,9-bis(hydroxyphenyl)fluorene compound as chain extension agent, or of di-epoxide derivative, thereof (such as a diglycidyl ether, epoxide) as all or part of the epoxide together with a diol extension agent. The improvements generally relate to: improvement in glass transition temperature (i.e. raising of glass transition temperature) without substantial loss of toughness or ductility; or improvement in Tg without any substantial loss of toughness; or, improvement in toughness and/or ductility without loss of high Tg. In some instances both Tg and toughness can be improved. Significantly, the present invention also involves improvement, through provision, in addition to the extension agent, of a toughening agent in the resin composition. As illustrated in the Examples, a significant overall improvement is achieved when both the 9,9-fluorene residue and the toughening agent are present. In addition to a method of improving the epoxy resin compositions, or the physical characteristics of cured epoxy resin compositions, the present invention also concerns a particular, preferred, epoxy resin composition according to the above general features.

Claims: An adhesive resin composition comprising: (a) a polyepoxide resin having reactive epoxide groups therein; (b) a 9,9-bis(hydroxyphenyl)fluorene chain extension agent reactive with the reactive epoxide groups of the polyepoxide resin, the chain extension agent having the formula wherein each R⁰ and each R¹ is independently selected from hydrogen and other groups inert to the polymerization of epoxide group-containing compounds; and (c) an effective amount of an elastomeric toughening agent. An adhesive resin composition according to claim 1 comprising from 0.05 to 0.9 hydroxy equivalents of the 9,9-bis(hydroxyphenyl) fluorene chain extension agent per reactive epoxide group of the polyepoxide resin. An adhesive resin composition according to claim 1 comprising from 0.09 to 0.7 hydroxy equivalents of the 9,9-bis(hydroxyphenyl) fluorene chain extension agent per reactive epoxide group of the polyepoxide resin. An adhesive resin composition according to claim 1 wherein each R⁰ is independently selected from the group consisting of hydrogen, the halogens, alkyl groups having 1-6 carbon atoms, phenyl, nitro, acetyl, and trimethylsilyl and, further wherein each R¹ is independently selected from the group consisting of hydrogen, phenyl, the halogens, and alkyl groups having 1-6 carbon atoms. An adhesive resin composition according to any preceding claim, the composition further comprising a curative for crosslinking a substantial amount of the reactive epoxide groups in the polyepoxide resin which are in excess of the hydroxy equivalents of the 9,9-bis(hydroxyphenyl) fluorene chain extension agent. An adhesive resin composition comprising; (a) a polyepoxide resin having reactive epoxide groups therein; (b) a fluorene di-epoxide having reactive epoxide groups and having the formula: wherein: (i) each R⁰ is independently selected from the group consisting of hydrogen, the halogens, alkyl groups having 1-6 carbon atoms, phenyl, nitro, acetyl, and trimethylsilyl; (ii) each R¹ is independently selected from the group consisting of hydrogen, phenyl, the halogens, and alkyl groups having 1-6 carbon atoms; and (iii) each R² is a terminal epoxy-functionalized alkyl group having 2-6 carbon atoms; (c) a non-fluorene containing diol chain extension agent reactive with the reactive epoxide groups of the polyepoxide resin and the fluorene di-epoxide; and (d) an effective amount of an elastomeric toughening agent. An adhesive resin composition according to claim 6 wherein the adhesive resin comprises from 5% to 97% by weight of the fluorene di-epoxide. An adhesive resin composition according to claim 6 comprising from 2% to 78% by weight of the fluorene di-epoxide. An adhesive resin composition according to claim 6 wherein each R⁰ and each R¹ is hydrogen and further wherein each R² is a 2,3-epoxypropyl group. An adhesive resin composition according to claim 6 comprising from 0.05 to 0.9 hydroxy equivalents of the dial chain extension agent per total reactive epoxide groups of the polyepoxide resin and the fluorene di-epoxide. An adhesive resin composition according to claim 10 comprising from 0.09 to 0.7 hydroxy equivalents of the diol chain extension agent per total reactive epoxide groups of the polyepoxide resin and the fluorene di-epoxide. An adhesive resin composition according to claim 6 further comprising a curative for crosslinking a substantial amount of the reactive epoxide groups of the polyepoxide resin and the fluorene di-epoxide which are in excess of the hydroxy equivalents of the diol chain extension agent. An adhesive resin according to any preceding claim wherein the elastomeric toughening agent is selected from the group consisting of acrylic core/shell polymers, styrene-butadiene/methacrylate core/shell polymers, polyether polymers, carboxylated acrylonitrile/butadienes, carboxylated butadienes, and mixtures thereof. An adhesive bonding film comprising the cured product of an adhesive resin according to any preceding claim. An adhesive bonding film/substrate arrangement comprising: (a) a first substrate; (b) a second substrate; and (c) an adhesive bonding film between the first and second substrates, the adhesive bonding film comprising the cured product of an adhesive resin according to any of claims 1 to 13.

Inventors: ALMER CARL J C O MINNESOTA MIN, SCHULTZ WILLIAM J C O MINNESOT, ALMER, CARL J. C/O MINNESOTA MINING AND, SCHULTZ, WILLIAM J. C/O MINNESOTA MINING AND
Applicants: MINNESOTA MINING & MFG, MINNESOTA MINING AND MANUFACTURING COMPANY
Application year: 1988
Main classification: C08G59
IPC codes: C08G59, C09J163, C08L63, C09J7