A METHOD FOR DRAWING-OFF LOW BOILING MEDIA FROM A PRESSURE SYSTEM AND ARRANGEMENT FOR CARRYING OUT THE METHOD

Abstract: In order to enable the drawing-off of residual vapours of a low-boiling liquid from a pressure system (1) into a storage vessel (2), the pressure between said system and the storage vessel is first equalized, whereafter the presure in the storage vessel is reduced and the pressure in the pressure system increased, enabling thus passage of the low-­ boiling liquid with its vapours in the liquid state into the storage vessel. This process can be repeated in order to draw-off liquid with its vapours from the pressure system.

Description: The invention relates to a method for drawing-off low-boiling medium from a pressure system into a storage vessel, and it also relates to an arrangement for carrying out said method. By the term "pressure system" can be understood for instance a cooling circuit of a cooling device, a collector of a liquid cooling medium of a cooling circuit and also any vessel for a low-boiling medium, for instance a transport vessel of a liquid cooling medium, a storage vessel of a low-boiling medium for filling of fire extinguishers and the like. By the expression "low-boiling medium" can be understood fluorinated and chlorinated hydrocarbons used as cooling agents and sold under the name freon, furthermore halogenized hydrocabons used for fire extinguishers, liquefied gases and all other liquids having a low boiling point lower than 80°C at normal barometric pressure. In various industrial branches, in business and services, health service, agriculture and households, arrangements are used, the working agent of which consists of a low-boiling medium contained within a pressure system. In many cases said agents are objectionable for hygienic reasons and sometimes also for ecologic reasons. Said media have to be frequently drawn-off from the pressure systems. These media are in many cases discharged into the atmosphere or specially designed pumping devices are used, while residual vapours of the cooling agent which remain after pumping-off the liquid cannot be easily removed. For instance in cases where for some reason the cooling agent from condensation cooling units and cooling circuits has to be removed or pumped-off, this agent is mostly discharged into the surrounding atmosphere. It is a known fact that fluorinated and chlorinated hydrocarbons which are used as cooling agents affect the protective ozone envelope of the atmosphere, which substantially influences the global environmental conditions. Therefore ways of preventing leakage of said cooling agents into the atmosphere are looked for. In known arrangements serving for the drawing-off of cooling agents as for instance described in DE-OS No.3 001 224 this problem of drawing-off vapours of cooling agents from cooling circuits and condensation units has been tackled, however with low pumping effect and unfavourable undercooling of the cooling unit and due to a realized distillation of the cooling agent a substantial part of contaminations contained in the liquid cooling agent have remained in the circuit. This concerns particularly products from built-in electric motors which have been damaged due to short circuiting, of semi-hermetic and hermetic compressors, contaminated oil and other contaminations which have at prevailing conditions a higher boiling temperature than the used cooling agent. As practically the whole cooling agent is pumped-off by way of a suction filter and a compressor which is mostly of a hermetic design, the life time of the compressor is reduced, the consumption of electric power is increased and a frequent exchange of the suction filter is required. Known arrangements of this kind have usually an overall weight of around 50 kg, are costly, and manipulation with them is difficult and physically demanding. International application WO 89/02567 relates to a method for rapid emptying of refrigerants from large-scale refrigerant and heat pump units by a pressure difference generated by a compressor, in which, however, the pressure difference is kept constant until the pressure system is emptied. Known prior art includes also DE 3616591 which discloses the transport of a refrigerant from a cooling circuit, i.e. from a pressure system, into a storage vessel for the refrigerant. In order to prevent uncontrolled leakage of the refrigerant into the ambient atmosphere during this action, the device is so arranged that the refrigerant in the form of a vapour is drawn-off from the pressure system and liquefied refrigerant is fed into the storage vessel. The drawing-off device for carrying out this method comprises a compressor and an air-cooled condenser connected in series. The purpose of the device disclosed is merely the drawing-off of the refrigerant vapours and their additional liquefying. However, in the cooling circuits of the condensation type, i.e. containing a condenser, a considerable amount of the refrigerant in the form of a liquid is present. The drawing-off rate is limited by the vaporisation rate in the pressure system. It is at the same time impossible and prohibited to increase this vaporisation rate by heating this pressure system so that the total drawing-off rate is limited by the natural vaporization of the refrigerant. In addition the described device does not allow the transport of liquid refrigerant from one storage vessel into the other. In contrast to the last mentioned prior art a method and an arrangement according to the invention allow the transport of the liquid refrigerant and the refrigerant vapours independently of the vaporization process in the pressure system. The invention provides a method for drawing-off low boiling media from a pressure system into a storage vessel, comprising the following steps: a) periodically generating a pressure difference between the pressure system and the storage vessel by sucking-off vapours from the storage vessel, compressing the vapours and feeding the same into the pressure system, thereby reducing the pressure in the storage vessel and increasing the pressure above the liquid level in the pressure system; and b) drawing-off, after each pressure difference generation, the low-boiling medium from the pressure system and emptying it into the storage vessel by means reducing the pressure difference. The invention also provides an arrangement for carrying out the method comprising a drawing-off conduit and by a return conduit both having a first end for connection to a pressure system and a second end for connection to a storage vessel, a compressor in the return conduit having its suction side connected with the second end and its discharge side connected with the first end and a first flow control device in the drawing-off conduit, wherein the first ends of both conduits are formed in a first single duct for communication with the pressure system and the second ends of both conduits are formed in a second single duct for communication with the storage vessel. According to this invention, after obtaining a pressure equilibrium between the pressure system and the storage vessel from which pressure system the cooling agent has to be pumped off into the storage vessel, the pressure in the storage vessel is reduced and the pressure in the pressure system is increased. Vapours from the storage vessel are sucked-off into the pressure system and due to a now established pressure difference, the low-boiling medium is drawn-off from the pressure system into the storage vessel. The result of this action is that due to the obtained high pressure difference between the pressure system and the storage vessel a relatively high speed increase of the pumped-off medium is achieved. This effect is obtained by introduction of a drawing-off conduit connecting the pressure system with the storage vessel and furthermore of a return conduit, to which a compressor is connected. The major part of the low-boiling medium is pumped-off by way of the drawing-off conduit in liquid state beyond the compressor, which is therefore exposed only to a slight degree to vapours of the low-boiling medium and this prolongs the life of the compressor. In addition in the course of this process of drawing-off of the liquid no unwelcome undercooling of the pumped-off pressure system is experienced, its temperature is on the contrary increased and the storage vessel is undercooled. Another advantage is that the pumped-off low-boiling liquid takes along the major part of unwelcome materials (contaminations) which are dissolved in the liquid phase. By the introduction of a condenser into a separate conduit the drawing-off of residua of the low-boiling medium as vapours can be achieved. The arrangement for carrying out the method for drawing-off according to this invention achieves a speed of drawing-off the low-boiling medium five times higher than arrangements according to the present state of the art. The weight of the arrangement according to the invention is thereby less than half of the known arrangements, so that it is easily transportable and can be used directly on site, for instance at the damaged cooling unit. For a prototype of an arrangement operating according to this invention used for the pumping off of a liquid cooling agent known under the commercial name "freon R12" from a pressure system in the form of a collector of a condensation cooling unit of a content of 15 kg to a storage vessel of a utilizable content of 7 kg, a pumping-off rate of 70 kg of cooling agent per hour has been achieved. The weight of the arrangement was only 21 kg. Arrangements used for the same purpose which achieve a maximum pumping-off rate of 10 kg per hour have weight of about 50 kg. Three embodiments of an arrangement according to the invention will now be described, by way of example, with reference to the accompanying diagrammatic drawings, in which: Fig.1 is a circuit arrangement showing the connection of the pressure system and the storage vessel by way of a drawing-off conduit and a return conduit, and Fig.2 is an arrangement having a separate conduit with a condenser. With reference to Fig.1 a pressure system 1 is shown, connected to a storage vessel 2 by means of a drawing-off conduit 3 provided with a closing device 10. A return conduit 4 incorporating a compressor 5 is connected at its ends to the drawing-off conduit 3. The pressure system 1 is provided with its own closing device 8 and the storage vessel 2 with a closing device 9. For the elimination of the pressure difference between the pressure system 1 and the storage vessel 2 the closing device 8 of the pressure system 1, the closing device 9 of the storage vessel 2 and the closing device 10 are opened. After the pressure difference has been eliminated, the closing device 10 is closed and the compressor 5 is started which, by way of the return conduit 4, sucks-off vapours of the low-boiling medium from the storage vessel 2 and forces them back into the pressure system 1, reducing thereby simultaneously the pressure in the storage vessel 2 and increasing the pressure in the pressure system 1. After a required pressure difference has been obtained, the compressor 5 is stopped and the closing device 10 is again opened. Due to the established pressure difference the low-boiling medium flows in a liquid state by way of the drawing-off conduit 3 into the storage vessel 2 until again the pressure difference is eliminated, whereafter the compressor 5 is again started, the first closing device 10 closed and the whole cycle repeated until all low-boiling medium is drawn-off. The remaining vapours of the low-boiling medium from the pressure system 1 are sucked-off by exchanging the pressure system 1 for the storage vessel 2, the first closing device 10 is closed and the compressor 5 started. The closing device 8 of the pressure system 1 and the closing device 9 of the storage vessel 2 remain for the whole time of drawing-off opened. Fig.2 shows a pressure system 1 connected to a storage vessel 2 by way of the drawing-off conduit 3 and a retain conduit 4 incorporating a compressor 5 and connected at its ends to the drawing-off conduit 3. The pressure system 1 is provided with its own closing device 8 and the storage vessel 2 with its closing device 9. In this embodiment the conduit 3 is provided with two closing devices, namely a first closing device 10 and a second closing device 11. The storage vessel 2 is by way of a separate conduit 6 incorporating a condenser 7 and a third closing device 12 connected to the pressure outlet of the compressor 5. The return conduit 4 is provided with a fourth closing device 13. The arrangement according to Fig.2 operates so that for the establishment of the pressure equilibrium between the pressure system 1 and the storage vessel 2 the first closing device 10 and the second closing device 11 are opened. After the pressure difference has been eliminated, the first closing device is closed and the fourth closing device 13 is opened, while the second closing device 11 remains opened. The compressor 5 is started which sucks-off over the return conduit 4 vapours of the low-boiling medium from the storage vessel 2 and forces them back into the pressure system 1, creating simultaneously a pressure reduction in the storage vessel 2 and a pressure increase in the pressure system 1. After the required pressure difference has been obtained, the compressor 5 is stopped and the first closing device 10 is again opened; the fourth closing device 13 can either be closed or reamin opened. Due to the established pressure difference the low-boiling medium flows in liquid state through the drawing-off conduit 3 until again the pressure difference is eliminated, whereafter the compressor 5 is again started, the first closing device 10 is closed, the fourth closing device 13 (if it did not remain opened) is opened and the whole cycle is repeated until all low-boiling medium is drawn off. The remaining vapours of the low-boiling medium are sucked-off by opening the first closing device 10, closing the closing devices 11 and 13, starting the compressor 5, opening the third closing device 12 and by way of the condenser 7 the liquefied low-boiling medium is forced into the storage vessel 2. Closing devices, the function of which is not mentioned in the course of the individual stages, are supposed to be closed, the closing device 8 of the pressure system 1 and the closing device 9 of the storage vessel 2 are in the course of drawing-off of the low-boiling medium opened. The drawing-off of the low-boiling medium can also be obtained by opening the third closing device 13 by way of the condenser 7 over the separate conduit 6. The compressor 5 is thereby at standstill and the first closing device 10 is closed. The arrangement can also be used for instance for pumping off low-boiling media, particularly cooling agents from transport vessels to pressure transport vessels, for pumping over from one vessel to another, for instance in order to regenerate cooling agents where, if needed, the liquid cooling agent is pumped over by way of a regenerating filter either directly, in which case the vessel with the contaminated cooling agent connection to the suction part of the arrangement according to this invention is turned over with its closing device downwards, thus realizing a direct pumping-over of the liquid medium while the arrangement operates as has been described, or in case a distillation of the cooling agent is required, the arrangement is operated at conditions of sucking-off vapours and the vessels with the contaminated cooling agent serves in this case as an improper evaporator, being in its fundamental position, i.e. with the valve upwards. The whole arrangement can be very easily be automated by using electrically controlled closing elements, pressure pick-ups and pick-ups of the passage of liquid.

Claims: Method for drawing-off low boiling media from a pressure system into a storage vessel, comprising the following steps: a) periodically generating a pressure difference between the pressure system and the storage vessel by sucking-off vapours from the storage vessel, compressing the vapours and feeding the same into the pressure system, thereby reducing the pressure in the storage vessel and increasing the pressure above the liquid level in the pressure system; and b) drawing-off, after each pressure difference generation, the low-boiling medium from the pressure system and emptying it into the storage vessel by means reducing the pressure difference. Arrangement for carrying out the method of Claim 1, comprising a drawing-off conduit (3) and a return conduit (4) both having a first end for connection to a pressure system (1) and a second end for connection to a storage vessel (2), a compressor (5) in the return conduit (4) having its suction side connected with the second end and its discharge side connected with the first end and a first flow control device (10) in the drawing-off conduit (3), wherein the first ends of both conduits (3,4) are formed in a first single duct for communication with the pressure system (1) and the second ends of both conduits (3,4) are formed in a second single duct for communication with the storage vessel (2). Arrangement according to Claim 2, wherein the pressure system (1) is provided with a closing device (8) and the storage vessel (2) is provided with a closing device (9), a second flow control device (11) is arranged between the first flow control device (10) and the closing device (9) of the storage vessel (2), and a separate conduit (6) incorporating a condenser (7) and a third flow control device (12) is branched off from the second single duct between the second flow control device (11) and the closing device (9) of the storage vessel (2) for communication with the return conduit (4) at the discharge side of the compressor (5). Arrangement according to Claim 3, comprising a further flow control device (13) incorporated into the return conduit (4) between the closing device (8) of the pressure system (1) and the point of communication of the separate conduit (6) with the return conduit (4).

Inventors: FENCL ZDENEK, JANDA FRANTISEK, KOVARIK KAREL, SARA JIRI, TATOUN ANTONIN, FENCL, ZDENEK, JANDA, FRANTISEK, KOVARIK, KAREL, SARA, JIRI, TATOUN, ANTONIN
Applicants: KOVOSLUZBA, NARODNI PODNIK HL.M. PRAHY
Application year: 1988
Main classification: F25B45
IPC codes: F25J1, F25B45, F17C7