A METHOD AND APPARATUS FOR DRY PROCESSING OR ETCHING A SUBSTRATE

Abstract: The patterning of substrates necessarily involves selective etching of some material. The present invention provides a method for dry processing or etching a substrate, in which the substrate is brought into a processing area; a vacuum is applied over the processing area; and an audio frequency signal is applied at electrodes of the processing area, such as to create a plasma at the processing area, having a power density substantially above 0.01 Watt/cm<3>. Further an apparatus for carrying out this method comprises a self-DC-bias on the electrode.

Description: A method and apparatus for dry processing or etching a substrate This invention relates to a method of plasma processing, more particularly to the dry processing of polymers and other materials and the dry development of photoresist for use, e.g. in the microelectronics industry. Many different plasma systems are known: reactive ion etching; high pressure plasma etching; magnetron ion etching; microwave etching; and electron-cyclotron resonance. The patterning of substrates necessarily involves selective etching of some material. This is typically done using a masking layer (such as photoresist) which has been previously patterned (e.g. using conventional photolitho¬ graphy and wet development) and which will be used to mask the substrate during the subsequent etch. Also, as more and more polymers are used in manufacturing, the need for fast and clean processing of those materials becomes important. In many cases, and this is specially true in the micro¬ electronics industry, the dimensional control becomes more and more stringent due to the decreasing minimum linewidths. Also, the defect densities need to be reduced to increase the yield of the processes. To achieve this, it is often decided to replace the wet chemical processing steps by dry processes. In general, the etching of a material by use of plasma is carried out in a specially configured chamber at reduced pressure. An etchant gas (or gaseous liquid) is introduced in the reaction vessel. The gas as such mostly is not reactive and will have no effect on the substrate to be etched. To make the gas reactive, it is ionized by powering electrodes located in the reaction vessel. The ionization is often done using microwaves (GHz) or radio-frequencies (RF)(MHz). From US-A-4.253907 it is known to use etching at audio-frequencies; this known etching method has no practical use as a power density of lower than 0.01 Watt/cm 3 is used. The present invention has for its object to provide a method for dry processing or etching, that is fast and shows a high degree of anisotropy; an apparatus designed for this method can be kept simple. Therefor the present invention provides a method for dry processing or etching a substrate, in which: the substrate is brought into a processing area; a vacuum is applied over the processing area; a audio frequency signal is applied at electrodes of the processing area, such as to create a plasma at the processing area, having a power density substansally above 0.01 Watt/cm 3 . Further an apparatus for carrying out this method comprises a self-DC-bias on the electrode. The matching network of the power system of the apparatus according to the prevent invention is designed such as to obtain a self-DC-bias on the cathode. The matching unit together with the plasma, will provide an equivalent load which matches the generators output impedance, resulting in an optimal power transfer to the plasma. The self-DC-bias will sustain the plasma at those low frequencies so that a stable working regime can be obtained. In a specific embodiment, the volume power densities can be much higher (typically ranging from 0.03 to 1 Watt/cm 3 ), resulting in a highly ionized plasma. The combination of the audio¬ frequencies and the self-DC-bias of the plasma results in a high density plasma, well suited for advanced processes of different types of materials such as polymers, oxides, nitrides, polycrystalline materials, etc. Indeed, as the ions can follow the audio frequency alternating electrical field (with radio-frequency plasmas (13.56 MHz), the ions cannot follow the alternating field due to their low mobility), they will be forced to strike the substrate perpendicularly, having an energy which is approximately proportional to the DC-self-bias (if no collisions occur in the dark sheath). This means that the ions will also have a sputtering effect, enhancing the anisotropy by promoting the directional sputter assisted etch component. In a practical system, the DC-self- bias voltages range from several volts to several hundreds of volts while the ionization - being defined as the number of ionized particles per cm 3 - ranges from 5.10 I 1 to IO 12 at a pressure of eg. 100 mTorr. The ionization degree - defined as the ratio of the number of ionized particles to the total number of particles at that specific pressure - can thus be as high as 10 -3 . These figures are typically a decade higher than for other existing plasma processes. Experiments carried out on a prototype using the above mentioned combination of audio frequency and matching network have shown that this plasma can be favorably applied to the etching of polymeric materials, including organo- metallics, with high etchrate. A clean, very fast and aniso¬ tropic etch can be performed showing a high power efficiency, resulting in a good definition of the patterned structures. A specific application of this process is its use for dry development of resists and the patterning of multilayer- structures in the micron and sub-micron region. Preliminary experiments have shown that plasmas created with the above method can be successfully used for treatments of large areas, such as printed circuit boards, displays and plates of glass (up to several square meters). The impedance of the audio frequency plasma (strongly resistive as opposed to capacitive for high frequency etching) and the flexibility of our proposed matching network makes this possible and easy to implement. Further details, advantages and features of the present invention will be clearified in the following description, in which references are made to the drawing, in which show: Fig. 1 a diagramatic view of an apparatus for carrying out a method according to the present invention and fig. 2 a more detailed view of the matching of the apparatus of fig. 1. As mentioned above, due to the further decrease of the minimal dimensions, the wet processing of photoresist can be replaced by dry processing for accurate linewidth control and reproducibility. This of course is also true for other materials. To obtain a high enough etchrate, and thus a high enough throughput, a highly ionized plasma should be used so as to have as much reactive species as possible contributing to the etching process. A possible way to achieve this is to use audio frequencies to generate the plasma which will attack the substrate thereby forming volatile products which will be pumped away by the vacuum system. The pressure in such a system typically ranges from 1 mTorr up to several mTorr. In our application the optimal pressure range seems to start at 20 mTorr and goes up to 500 mTorr. The pressure will impact on the anisotropy of the process. From the prior art it is clear that high etchrates using state of the art etching processes requires high power densities - even if magnetic confinement is used -, possibly resulting in damage to the structures to be etched. The use of audio frequencies enables one to achieve high etchrates and good anisotropy with low power densities and medium pressures. An embodiment of an apparatus 1 for carrying out the method according to the present invention (fig. 1) comprises a top electrode 2, in the present example used as connection to the gas-inlet 3 (shower-head) for supplying gas - in this embodiment oxygen (O2)- into the apparatus or reaction vessel 1 through a not shown mass flow meter. A substrate 5 is placed on a bottom electrode 4 (the cathode) which can be heated or cooled depending on the process. An audio frequency alternating signal from a source 7 (fig. 1) or generator 9 (fig. 2) is applied on the cathode through a matching network 6 (fig. 1,2) containing a transformer 13 and a capacitor 11. Typically the plasma 12 (fig. 2) between the electrodes in the apparatus 1, is fed with a voltage of eg 1200 - 1400 Volt (peak - peak- alue) . The matching at audio frequencies is very simple; a simple transformer substantial¬ ly matches the impedances between generator and plasma. The capacitor has a typical value of l μF and provides the DC- bias at the cathode (eg 1000 - 2000 Volt), because of differences in mobility in ions and electrons in the plasma. The gas is ionized and a negative bias voltage develops on the cathode as a result of the charging of the capacitor. The DC-bias attracts positive ions out of the bulk of the plasma accelerating them to the substrate. Those reactive species strike the plasma perpendicularly and with enough energy to promote the directional sputter assisted etching component. In the prototype, dry development of photoresist (see EP-A-85.870.142.8) has extensively been studied. Etchrates higher than 1 /m/min for power densities of 0.3 to 1 Watt/cm 2 and pressures ranging from 50 to 300 mTorr. A limited amount of physical sputtering - as introduced by the present invention - is beneficial in removing residues upon development. In the case of etching other polymers such as polyimides, PVDF, kapton etc., the same increase in etchrate compared to state of the art technologies is seen. Also, in the case of etching silicon oxide, etchrates of 7000 A/min have been observed for power densities of 0.5 Watt/cm 2 . Although detailed etching experiments on other materials have not yet been done, it is expected that these other materials will also exhibit increased etchrates and good anisotropy. As a conclusion, it is clear that the use of the audio-frequencies combined with the matching network consisting of a transformer and a blocking capacitor result in a high rate etch with good anisotropy without having to build a more complex system such as Magnetron confinement or Electron-Cyclotron systems.

Claims: CLAIMS 1. A method for dry processing or etching a substrate, in which the substrate is brought into a processing area; a vacuum is applied over the processing area; and a audio frequency signal is applied at electrodes 5 of the processing area, such as to create a plasma at the processing area, having a power density substantially above 0.01 Watt/cm 3 . 2. A method of claim l, in which the power density is between 0.3-1 Watt/cm 3 and the vacuum pressure ranges from 10 50 to 300 mTorr. 3. A method according to claim 1, in which the audio frequency signal is modulated such as to influence the degree of anisotropy of the etching. 4. A method according to claim 1, 2 or 3 pattering 15 polymeric materials - such as to polyimides, organo-metallics, PVDF, teflon and epoxy resins - (plain layers, multi-layers, ... ) . 5. The use of the method as under (1) for silicon trench etching, polysilicon etching, silicon nitride and 20 silicon dioxide etching for application to the fabrication of integrated circuits. 6. An apparatus for carrying the method of the claims 1 - 5 in which a matching network between an electrode and a audio frequency signal source comprises a self-DC-bias 25 on the electrode.

Inventors: BRASSEUR GUY JEAN JACQUES, BRASSEUR, GUY, JEAN, JACQUES
Applicants: COBRAIN NV, COBRAIN N.V.
Application year: 1988
Main classification: H01L21
IPC codes: G03F7, H01L21