Low-caloric sweetening composition of microcrystalline appearance

Abstract: A low-caloric sweetening composition of micro­ crystalline appearance comprises microcrystalline meso­ erythritol particles whose surface is coated with a sweetening component containing at least one nonsugar sweetener, the amount of which is adjusted to within range from 9.4 to 2.6, preferably 6.5 to 2.6, with respect to the product of the weight part of the nonsugar sweetener per weight part of the mesoerythritol as one and the relative sweetness of the nonsugar sweetener to sucrose. When plural nonsugar sweeteners are contained, the product is calculated as the sum of the products obtained in terms of each nonsugar sweetener.

Description: This invention relates to a low-caloric and non-cariogenic sweetening composition of microcrystalline appearance. Nonsugar sweeteners such as aspartame, stevioside, saccharin sodium, thaumatin, glycyrrhizin, acesulfam-K and sodium cylcamate, which are several hundreds of times as sweet as sucrose, are low-caloric and non-cariogenic. Thus the application ranges of these nonsugar sweeteners have been more and more extended as substitutes for sugar which is somewhat injurious to health. However each of these nonsugar sweeteners has an extremely high sweetness which makes it almost impossible to employ the same alone for home use. Therefore the nonsugar sweetener is generally blended with fillers to thereby give a powder, or is sometimes further molded into an appropriate shape together with excipients. However these products thus obtained are similar to powdered or granulated drugs in appearance and thus are not accepted as conventional sweeteners. On the other hand, sugar alcohols such as sorbitol, maltitol and xylitol having excellent sweetness characteristics are widely used as non-digestive, i.e., low-caloric and non-cariogenic sweeteners. There are known sweetening compositions comprising a mixture of these sugar alcohols with nonsugar sweeteners such as aspartame, stevioside or saccharin sodium. However, recent studies on rat, dog and human being suggest that these sugar alcohols would be decomposed and absorbed to a considerably high extent in vivo and thus the sugar alcohols are almost comparable to sucrose in caloric value. That is to say, these sugar alcohols are metabolized by enteric bacteria to thereby supply energy. In addition, these mixtures of sugar alcohols and nonsugar sweeteners have a drawback in appearance which shows similar to powdered or granulated drugs, as described above. The inventors have previously proposed an invention on a taste modifier for a nonsugar sweetener (JP-A-63-258557, the term "JP-A" herein used means unexamined Japanese patent application). According to the prior invention, one part by weight of mesoerythritol is preferably blended with, for example, 0.001 to 0.007 part by weight of stevioside, 0.001 to 0.004 part by weight of glycyrrhizin, 0.001 to 0.014 part by weight of aspartame or 0.0004 to 0.001 part by weight of saccharin sodium. The inventors have further proposed a low-caloric sweetening composition wherein the surface of microcrystalline particles off mesoerythritol is coated with a sweetening component containing at least one nonsugar sweetener (Japanese Patent Application Nos. 62-250756 and 62-256262). In the case of the two prior inventions, the mesoerythritol is preferably blended with a nonsugar sweetener at the same ratio as those defined above. Thus a sweetening composition similar to sucrose in sweetness characteristics can be obtained by blending mesoerythritol with a nonsugar sweetener at the ratio defined above. However, the inventors have subsequently found that the mesoerythritol contained in a large amount in a sweetening composition, which is obtained by blending mesoerythritol and a nonsugar sweetener so as to give a sweetness characteristics similar to those of sucrose, would require heat dissolution when added to hot coffee or hot tea, thereby resulting in a significant decreasing a temperature off the hot coffee or hot tea. Therefore the above sweetening composition is impossible to add to hot coffee or hot tea in the same manner as that employed in the case of sugar. The present invention aims at providing a low-caloric and non-cariogenic sweetening composition which has a beautiful microcrystalline appearance similar to that of granulated sugar (sucrose) and causes little decrease in temperature when added to hot coffee or hot tea. According to the present invention, there is provided a low-caloric sweetening composition of microcrystalline appearance comprising microcrystalline mesoerythritol particles whose surface is coated with a sweetening component containing at least one nonsugar sweetener, the amount of which is adjusted to within the range of from 9.4 to 2.6, preferably 6.5 to 2.6 with respect to the product of the weight part of the nonsugar sweetener per weight part of the mesoerythritol as one and therelative sweetness of the nonsugar sweetener to sucrose. When plural nonsugar sweeteners are contained, the product of the weight part of the nonsugar sweetener per weight part of the mesoerythritol is defined as the sum of the products obtained in terms of each nonsugar sweetener. According to the invention the nonsugar sweetener is employed in such an amount that the product (a x b) of the ratio a of non sugar sweetener to mesoerythritol ( in parts by weight) and the relative sweetness b of the nonsugar sweeteners (relative to sucrose) is within the range of 2.6 to 9.4, preferably 2.6 to 6.5. The mesoerythritol to be used in the present invention is a tetrahydric sugar alcohol represented by the following formula: which has the form of white crystals, a molecular weight of 122 and m.p. of 119°C. The mesoerythritol is closely similar to granulated sugar in appearance, highly soluble in water, nondigestive and non-cariogenic and shows no browning in appearance. The mesoerythritol, which will be sometimes simply called erythritol hereinafter, occurs in natural algae and fungi, and is contained in a small amount in Japanese sake, wine and soy sauce. A panel test indicates that the sweetness of mesoerythritol is somewhat lower than that of sucrose and somewhat higher than that of glucose; the sweetness of mesoerythritol corresponds to approximately 75 to 80% of that of sucrose; and the sweetness characteristics of mesoerythritol are similar to those of sucrose but the former gives less aftertaste than the latter does. The particle size of the erythritol microcrystalline particles to be used in the present invention is not particularly restricted, and preferably ranges from approximately 0.1 to 1.0 mm. Erythritol microcrystalline particles whose particle size is similar to that of granulated sugar, i.e., 0.2 to 0.7 mm, to that of refined white sugar, i.e., 0.1 to 0.2 mm or to that of powdered sugar, i.e., 0.1 mm or below may be employed. The relative sweetness of a nonsugar sweetener described herein means the degree of the sweetness of the nonsugar sweetener based on that of sucrose. The value is calculated according to the following equation: wherein C represents the concentration in weight percent of an aqueous solution of the nonsugar sweetener which shows a sweetness comparable to that of a 7% by weight aqueous solution of sucrose. As described above, the low-caloric sweetening composition of the present invention satisfies the product of range from 9.4 to 2.6, which is obtained from the content (part by weight) of said nonsugar sweetener per part by weight of the mesoerythritol, and the relative sweetness of said nonsugar sweetener based on that of sucrose, and when two or more nonsugar sweeteners are employed, the product means the sum of the product of each nonsugar sweetener. The above product or the sum thereof ranging from 9.4 to 2.6 makes it possible to prevent any significant decrease in temperature of hot coffee or hot tea, generally speaking heated water or aqueous solution. When the product or the sum thereof exceeds 9.4, the resulting sweetening composition shows an excessively high sweetness which makes its application difficult. In addition, some nonsugar sweeteners would damage the vitrous appearance of the erythritol crystals to thereby injure the appearance of the sweetening composition. Examples of the nonsugar sweeteners to be used in the present invention are as follows. Values in parentheses indicate each the relative sweetness of the nonsugar sweetener based on that of sucrose as 1,00. aspartame (118), stevioside (233), saccharin sodium (240), thaumatin (2920), glycyrrhizin (160), acesulfam-K (150), sodium cyclamate (33) and rebaudioside (300). The sweetening component containing at least one nonsugar sweetener, which is to be used in coating erythritol microcrystalline particles in the present invention, may comprise nonsugar sweetener(s) optionally together with sugar sweetener(s) or gelatinizer(s). Various sugar sweeteners may be used together with the nonsugar sweetener(s) in the present invention. Particularly preferably examples thereof include those having high water holding properties such as reduced straight-chain oligosaccharides, branched oligosaccharide alcohols, sorbitol, coupling sugars, isomerized sugars and maltitol. Examples of the gelatinizer, binder, to be used together with the nonsugar sweetener(s) include gelatin, locustbean gum, carrageenan, xanthan gum, pullulan and soluble starch. In the present invention, the erythritol microcrystalline particles may be coated by various methods. For example, the coating may be effected by spraying an aqueous liquor (the term "aqueous liquor" used herein means an aqueous solution as well as an aqueous dispersion) comprising nonsugar sweetener(s) optionally together with gelatinizer(s) onto the surface of erythritol microcrystalline particles; or by kneading the abovementioned aqueous liquor of the sweetening component comprising nonsugar sweetener(s) and optionally gelatinizer(s) together with the erythritol microcrystalline particles in a kneader and the like. Subsequently the erythritol microcrystalline particles whose surface is thus coated with the sweetening component may be dried by, for example, vacuum-drying or air-drying preferably at a temperature of 50 to 110°C. In the low-caloric sweetening component of microcrystalline appearance of the present invention, it is not always required that the coating layer comprising the sweetening component is completely dried. When the sweetening component comprises nonsugar sweetener(s) together with the abovementioned sugar(s) of high water holding properties, in particular, moisture may remain in the coating layer to a certain extent. This is because such a sweetening composition as described above, wherein the coating layer comprises sugars having high water retention properties and contains some moisture, would never aggregate to form lump when packed in bags and piled in a storehouse. Furthermore it is sometimes observed that the presence of some moisture therein effectively prevents the erythritol microcrystals from being powdered when exposed to shaking or shock during the transportation of the product. In the present invention, the ratio between mesoerythritol and a nonsugar sweetener, which gives the product of the content (part by weight) of said nonsugar sweetener per part by weight of the erythritol and the relative sweetness of said nonsugar sweetener ranging from 6.5 to 2.6, may vary depending on nonsugar sweetener. For example, 0.055 to 0.022 part by weight of aspartame, 0.027 to 0.011 part by weight of stevioside, 0.027 to 0.011 part by weight of saccharin sodium, 0.0022 to 0.0009 part by weight of thaumatin, 0.041 to 0.016 part by weight of glycyrrhizin, 0.042 to 0.017 part by weight of acesulfam-K or 0.197 to 0.079 part by weight of sodium cyclamate may be used each per part by weight of erythritol. As an embodiment, mixtures of erythritol and stevioside at various ratios are dissolved in water to thereby give aqueous solutions each having a sweetness comparable to that of a 7% by weight or 14% by weight aqueous solution of sucrose. Then the decrease in the water temperature caused by the dissolution of each mixture is examined. Table 1 shows the results. The amount of a sweetener to be added to, for example, coffee or tea varies from person to person. However a sweetness comparable to that of a 14% by weight aqueous solution of sucrose is sufficient for even those prefer a strong sweet taste. A decrease in the temperature of hot coffee or hot tea by 1 to 2°c, caused by the dissolution of a sweetener added thereto, would offer significantly no problem. Accordingly the sample Nos. 1 to 3 in Table 1, each having the product of a and 233 within 6.5 to 2.6, satisfy these requirements. In contrast thereto, the sample Nos. 4 and 5, each having the product of a×233 less than 2.6, cause an undesirable decrease in the temperature, namely by 3°C or more. It is also undesirable that the ratio of a nonsugar sweetener to erythritol is excessively high. When the surface of erythritol crystals having 0.2 to 0.7 mm in particle size is coated with a large amount of powdered aspartame, for example, the vitreous and transparent appearance of the erythritol crystals is injured. As a result, the obtained sweetening composition looks like broken crystals. In addition, the sweetness of the sweetening composition is several ten times as high as that of sugar, which makes the application thereof difficult. In contrast thereto, according to the sweetening composition of the present invention, when the content of the nonsugar sweetener is relatively small and thus the product defined above is 6.5 or below, erythritol crystals coated with the powdery aspartame maintain the vitreous and transparent appearance and shows a relatively low sweetness. Thus it is highly preferable. The sweetening composition of the present invention is particularly suitable as a sweetener for hot drinks such as hot coffee or hot tea. Further, the sweetening composition is available as a material in the production of a molded sugar product which has been priorly applied for a patent by us (cf. Japanese Patent Application No. 62-262709). The sweetening composition of the present invention has a beautiful microcrystalline appearance just like granulated sugar (sucrose) and is low-caloric and non-cariogenic. Further it causes little decrease in temperature when added to a hot drink. To further illustrate the present invention, the following Examples will be given. Unless otherwise indicated, all parts, percents and ratios are by weight. Example 1 An aqueous liquor obtained by dispersing/dissolving 15 g of a saccharin sodium powder in 50 g of water was added to 1 kg of erythritol microcrystalline particles having a particle size of 0.1 to 1 mm. The resulting mixture was thoroughly kneaded in a kneader to thereby coat the surface of the erythritol microcrystalline particles with the saccharin sodium. In this case, the product of the content (by weight) of the saccharin sodium per part by weight of the erythritol and the specific sweetness thereof to that of sucrose having specific sweetness of 240 was 3.6. The kneaded mixture was air-dried at 80°C. The sweetening composition thus obtained had a beautiful microcrystalline appearance just like granulated sugar (sucrose) and was low-caloric and non-cariogenic. 1.52 g of this sweetener was dissolved in 98.50 g of a solution of instant coffee at 70°C. Thus a sweetness comparable that of a 7% by weight aqueous solution of sucrose was achieved accompanied by little decrease in the temperature of the coffee. Example 2 35 g of aspartame was thoroughly kneaded together with 25 g of a solution of a reducing straight-chain oligosaccharide (concentration: approximately 70% by weight). Then 1 kg of microcrystalline erythritol particles of 0.1 to 0.2 mm in particle size were added thereto. The resulting mixture was thoroughly kneaded in a kneader. The sweetening composition thus obtained, which comprised erythritol microcrystalline particles coated with the mixture of aspartame and the reducing straight-chain oligosaccharide, had a beautiful microcrystalline appearance and was low-caloric and non-cariogenic. 15.5g of this sweetening composition was dissolved in 98.5 g of a solution of instant coffee at 70°C. Thus a sweetness comparable to that of a 7% by weight aqueous solution of sucrose was achieved accompanied by little decrease in the temperature of the coffee.

Claims: A low-caloric sweetening composition of microcrystalline appearance comprising microcrystalline mesoerythritol particles whose surface is coated with a sweetening component containing at least one nonsugar sweetener, wherein the product of the weight part of the nonsugar sweetener per weight part of the mesoerythritol and the relative sweetness of the nonsugar sweetener to sucrose is within the range of from 9.4 to 2.6. A sweetening composition according to claim 1, wherein the product falls within ranges of from 6.5 to 2.6. A sweetening composition according to claim 1 or 2 comprising, plural nonsugar sweeteners. A sweetening composition according to any one of claims 1 to 3, wherein the composition has a microcrystalline appearance and is low-caloric and non-cariogenic. A sweetening composition according to any one of claims 1 to 4, wherein the sweetening component contains saccharin sodium as a nonsugar sweetener. A sweetening composition according to any one of claims 1 to 4, wherein the sweetening component contains aspartame as a nonsugar sweetener.

Inventors: KONDOU TSUTOMU, KONDOU, TSUTOMU
Applicants: MITSUBISHI CHEM IND, NIKKEN CHEMICALS CO LTD, MITSUBISHI KASEI CORPORATION, NIKKEN CHEMICALS CO., LTD.
Application year: 1988
Main classification: A23L1
IPC codes: C07C29, C07C27, A23L1, C07C67, A23F5, C07C31