Rotatable member for fixing apparatus and fixing apparatus using same

Abstract: An image fixing rotatable member includes an elastic layer into which filler material is mixed, the elastic layer having a surface provided with pores with a porosity of 3 - 50 %, and a resin layer applied and sintered on the elastic layer.

Description: This invention relates to an image fixing rotatable member and an image fixing apparatus having at least one image fixing rotatable member, which are usable with an electrophotographic apparatus, an electrostatic recording apparatus and the like in which an image is fixed. The invention also relates to a method of manufacturing an image fixing rotatable member, a method of fixing an image using an image fixing rotatable member and a use of an image fixing rotatable member. A widely used type of image fixing apparatus uses a pair of image fixing rotatable members (such as rollers) between which a recording medium bearing an unfixed toner image passes. The toner image is fixed due to pressure exerted by the image fixing members on the toner. Often heat is also applied as part of the fixing process. The image fixing members should preferably be durable and have good image fixing and releasing properties. Figure 11 of the accompanying drawings shows a prior art image fixing member. The member comprises a metal core 200 around which a silicone rubber layer 400 is positioned. A fluorine resin material is applied to the rubber layer 400 and is then sintered to form a layer 600. An image fixing member of this type is disclosed in DE-A-3 606 662. Image fixing members of the type referred to in the preceding paragraph are durable, convey the recording medium between them effectively and also have good image fixing and releasing properties. This is because the resin layer 600 can be made very thin, for example 15-20 microns, which means that it does not significantly reduce the elasticity of the rubber layer. However, although this type of image fixing member is durable in the sense that the surfaces do not readily wear, after long term use the resin layer has a tendency to peel from the rubber layer. When this happens the image fixing properties of the member become poor. According to the invention there is provided an image fixing rotatable member as claimed in claim 1, an image fixing apparatus as claimed in claim 11, a method of manufacturing an image fixing rotatable member as claimed in claim 14 and a method of fixing an image on an image supporting member as claimed in claim 22. The invention also relates to use of an image fixing rotatable member for fixing an image on an image supporting member. The depressions formed in the elastic layer allow the resin layer to be bonded thereto with a high bonding strength, which reduces any tendency for the resin layer to peel from the elastic layer. Because the depressions are formed by removing the filler material from the elastic layer, this may allow the number of depressions formed on a given area of the surface of the elastic layer to be controlled by varying the concentration of the filler material in the elastic layer during manufacture. Also, it is a fairly easy operation to form the depressions by removing the filler material from the elastic layer. For a better understanding of the invention embodiments of it will now be described by way of example with reference to the accompanying drawings in which:- Figure 1 is a sectional view of an image fixing apparatus according to an embodiment of the present invention. Figure 2 is an enlarged sectional view of a part of an image fixing roller according to an embodiment of the present invention. Figure 3 is a graph showing a relationship between peeling force and number of sheets processed by the image fixing apparatus. Figure 4 is a graph showing a relation between a porosity and peeling force. Figure 5 is a sectional view of a part of the fixing roller according to the embodiment of the present invention. Figure 6 is a sectional view illustrating the porosity. Figure 7 shows pores on the surface of the elastic layer of the image fixing rotatable member according to an embodiment of the present invention. Figure 8 illustrates pores on the elastic layer surface of an image fixing rotatable member according to a comparison example. Figure 9 is a sectional view of an apparatus for manufacturing the image fixing rotatable member according to an embodiment of the present invention. Figure 10 is a sectional view of an image fixing rotatable member according to another embodiment of the present invention. Figure 11 is a sectional view of an image fixing roller according to background art. Figure 12 is an enlarged sectional view of a part of the image fixing roller according to an embodiment of the present invention. Figure 13 is a sectional view of an apparatus used for manufacturing an image fixing rotatable member according to an embodiment of the present invention. Figure 14 is a perspective view of an apparatus of Figure 13. DESCRIPTION OF THE PREFERRED EMBODIMENTS Referring to the accompanying drawings, the preferred embodiments of the present invention will be described wherein like reference numerals are assigned to the elements having corresponding functions. Referring now to Figure 1, there is shown an image fixing apparatus according to an embodiment of the present invention. The image fixing apparatus comprises a heating image fixing roller 1, containing therein a heating source H, for contact with an unfixed toner image T carried on a recording sheet P and a back-up or pressing roller 10 for pressing the recording sheet P carrying the toner image to the fixing roller 1. The fixing roller 1 and the pressing roller 10 have similar structures, and include core metals 2 and 12, elastic layers 4 and 14 and resin layers 6 and 16, respectively. The fixing apparatus further comprises a temperature detecting and control means G for detecting the surface temperature of the fixing roller 1 and maintaining it at a predetermined level which is an optimum temperature for fusing the toner, 160 - 200 °C, for example, and off-set prevention liquid applying means C for applying off-set preventing liquid such as silicone oil or the like to the surface of the fixing roller 1 and for cleaning the surface thereof. The fixing roller 1 is comprised of the core metal 2 having a good thermal conductivity such as aluminum, the elastic layer 4 formed on the core metal 2 and made of silicone rubber, having a layer thickness t₁ of 0.3 - 0.8 mm and an impact resilience of 65 - 85 %, in this embodiment, and a resin layer 6 formed on the elastic layer 4. The resin layer 6 is made of a fluorine resin material such as PEA resin (copolymer of tetrafluoroethylene resin and perfluoroalkoxyethylene resin) and PTFE resin (tetrafluoroethylene resin) and has a layer thickness t₂ of 10 - 25 microns and a film strength of not less than 50 kg/cm², in this embodiment. The pressing roller 10 has a similar structure, but the core metal 12 is made of stainless steel or another steel, and the layer thickness t₃ of the silicone rubber elastic layer 14 is larger, for example, 4 - 10 mm, and an impact resilience thereof is 65 - 85 %. The resin layer 16 is made of, similarly to the fixing roller 1, fluorine resin material such as PFA and PTFE resins, but the layer thickness t₄ is 5 - 35 microns, and the film strength is not lower than 50 kg/cm². Each of the fixing roller 1 and the pressing roller 10 is symmetrical with respect to a longitudinal center thereof, and preferably, the fixing roller 1 (or the pressing roller 10) is reversely crowned, that is, the diameter thereof at the longitudinal center is slightly smaller than the diameters at the longitudinal ends. The image fixing rotatable member according to the present invention is applicable to an image fixing roller 1 contactable to the unfixed toner image and/or to the pressing roller 10 which is not contacted to the image. However, the present invention is particularly effective when it is applied to the rotatable member contactable to the unfixed toner image, and the following description will be made as to the fixing roller 1. Figure 2 is an enlarged sectional view of the fixing roller 1. The surface of the elastic layer 4 constituting a boundary between itself and the resin layer 6 is provided with numerous pores with the porosity of 3 - 50 %. Into the pores 30, the resin material of the resin layer 6 is projected into and locked therein so as to provide a so-called anchoring effect, by which the elastic layer and the resin layer are strongly bonded, and therefore, the resin layer is prevented from peeling off the elastic layer even with a long term use, thus significantly increasing the durability. More particularly, according to experiments and investigations, by the inventors, the durability of the fixing roller 1 is increased in proportion to the bonding strength between the elastic layer 4 and the resin layer 6, that is, the peeling force or strength. As shown in Figure 3, particularly when the peeling strength is not less than 130 g/20 mm, the durability of not less than 200,000 sheets can be accomplished with certainty. The definition and method of measurement of the peeling strength will be described hereinafter. On the basis of the finding, the inventors have made investigations as to the relation between the peeling strength and porosity of the roller according to the present invention, and have found that there is a relation as shown in Figure 4, and it has been found that the porosity of 3 - 50 is preferable. As will be understood from Figure 4, the peeling strength increases with increase of the porosity up to approximately 30 % of the porosity, but the peeling strength decreases beyond it. It is considered that with the increase of the porosity, the resin material of the resin layer 6 is projected more into the pores 30 of the elastic layer, thus increasing the anchoring effect, that with the porosity higher than 30 %, as shown in Figure 5, the anchoring effect between the resin layer 6 and the elastic layer 4 becomes larger than the strength of the material constituting the elastic layer 4, and therefore, although the peeling between the elastic layer 4 and the resin layer 6 is prevented, a part 4a of the surface of the elastic layer 4 is torn from the resin layer 6, and in effect, the peeling strength decreases. In view of this, the porosity is particularly preferably 3 - 30 %, since then the tearing hardly occurs. Referring to Figure 6, the porosity in this specification is defined as total opening (inlet) areas s1, s2, s3 ... sN of the pores (s) divided by the total surface area (S) of the elastic layer 4, that is, s/S. The description will be made as to the method of measurement for the porosity. Various methods of measurement are considered, but in this embodiment, it is measured in the following manner. The surface of the elastic layer 4 is photographed in a magnification of 500, in a direction of 90 ± 5 degrees relative to the elastic layer surface. The photograph is traced to produce a drawing for measurement, as shown in Figures 7 and 8, wherein the black portions indicate the pores 30. The drawing is read by a reading device using CCD and having a resolution of 50 microns. The reading is A/D-converted to provide binary data. On the basis of the data, the percentage of the black level picture elements is determined relative to the total picture elements (one picture elements is 50 microns x 50 microns). The percentage is the porosity in this specification. The actual measurement has revealed that the porosity of the example of Figure 7 is 7 %, and that of Figure 8 is 1.5 %. Figure 7 is obtained from the surface of the elastic layer of the roller according to a second example which will be described hereinafter, and Figure 8 is obtained from the surface in a second comparison example, which will also be described hereinafter. The fixing roller 1 (and the pressing roller 10) may be produced by various methods, but the preferable method of production will be described. Since the fixing roller 1 and the pressing roller 10 can be produced in the same method, and the description will be made only as to the fixing roller. First, a core metal 2 is produced so as to have a predetermined diameter from aluminum material, and the elastic layer 4 is formed thereon. The elastic layer 4 is usually formed by vulcanizing silicone rubber (having a thermal conductivity of 1.4x10⁻⁴ - 1.5x10⁻³). In this embodiment, when the elastic layer 4 is produced, the silicone rubber which is the material of the elastic layer 4 is mixed with a filler material which is quartz powder having a particle size of 1 - 7 microns, and then the silicone rubber layer is formed by the vulcanization into a silicone rubber roller having a desired configuration. Preferably, the silicone rubber roller is slightly reverse-crowned wherein the longitudinal central portion has a slightly smaller diameter than the longitudinal end portions. Then, the surface of the silicone rubber roller is rotated, while an abrasive cloth is pressed thereto under a predetermined pressure, 1 kg/cm² for example over the entire longitudinal length by longitudinally reciprocating it, the abrasive cloth having a roughness sufficient to remove the quartz powder projected from the surface of the elastic layer without substantially abrading the elastic layer surface. By doing so, the quartz powder on the surface is forced to be removed, so that a number of pores 30 are provided on the roller surface. The porosity can be controlled by controlling amount of removal of the filler material such as the quartz powder mixed into the silicone rubber. The amount of removal is controlled by, for example, controlling the amount of the filler material mixed thereinto, the roughness and/or material of the abrasive cloth and/or the pressure thereof to the elastic layer. The quartz powder can be removed from the surface of the silicone rubber roller by a strong sand blasting treatment, but the removal by the abrasive cloth is preferable. The surface of the rubber roller now having the desired porosity in the manner described above is coated with unsintered fluorine resin material, such as fluorine resin dispersion (the fluorine resin powder is dispersed in water with a surface active agent), or the fluorine resin in the form of enamel or powder, over the entire length of the rubber layer by spray painting, electrostatic painting, powder painting or the like, to provide a uniform thickness layer. At this time, a part of the dispersion enters the pores 30 formed on the surface of the rubber roller. The average particle size of the fluorine resin powder in the dispersion is not more than 1 micron, preferably not more than 0.5 micron. On the other hand, the average particle size of the quartz powder mixed into the elastic layer is larger than that of the fluorine resin particle, more particularly, preferably 1 - 7 microns, and further preferably not less than 3 microns. By selecting the sizes of the fluorine resin particles and the quartz particles, the pores 30 provided by removing the quartz particles from the surface of the elastic layer is sufficiently larger than the size of the flourine resin particle, and therefore, the fluorine resin particle easily enter the pores 30, by which the anchoring effect, that is, the bonding effect is sufficiently provided. The dispersion or the like of fluorine resin applied in a uniform thickness in the manner described above becomes a resin coating film by being heated up to a temperature not less than the crystalline melting point of the fluorine resin, 327 °C, for example. Therefore, it is desirable that the silicone rubber roller on which the unsintered fluorine resin is applied is heated to a crystalline melting temperature (327 °C for PTFE resin, and 306 °C for PFA resin). Although the silicone rubber itself has excellent rubber properties such as an impact resilience and compression set, it is smoked or depolymerized if it is heated above 300 °C, or particularly, higher than 306 °C or 327 °C. This obstructs formation of good fluorine resin layer, and deprives the rubber properties of the silicone rubber. In consideration of this, the sintering method is preferably such that the applied fluorine resin is heated up to the crystalline melting point, while maintaining the silicone rubber roller at a temperature not producing the smoking or the depolymerization (not higher than 300 °C at maximum). More particularly, examples of preferable methods are the one wherein the rubber layer is strongly cooled from the inside of the core metal, while quickly heating the unsintered surface fluorine resin, and a dielectric heating method wherein the use is made with the fact that the dielectric loss tangent of the liquid fluorine resin (dispersion) is larger than the dielectric loss constant of the rubber layer. In this method, a thermal gradient is substantially produced in the silicone rubber layer in the direction of the thickness thereof, but the silicone rubber is heated up to 260 - 280 °C approximately, whereas the unsintered fluorine resin is heated up to 340 - 380 °C which is not lower than the crystalline melting point which is 327 °C for the PTFE resin for approximately 5 - 10 min. After the sintering, the roller is quickly cooled. By the cooling, a sintered fluorine resin surface layer having such resin properties that the degree of crystallinity is not more than 95 %, that the tensile strength is not less than 50 kg/cm² and that the contact angle relative to the water is not less than 100 degrees, is formed on the silicone rubber roller and is strongly bonded thereto with sufficiently large thickness. Simultaneously, the fluorine resin layer in the pores 30 on the surface of the rubber roller is sintered with strong bonding strength to the rubber roller so as to provide the strong anchoring effect. Therefore, the back-up silicone rubber layer exhibits the same rubber properties as before formation of the resin layer, whereas the surface fluorine resin layer exhibits the completely sintered resin properties, and in addition those layers are strongly bonded by the resin material in the pores of the elastic layer. By adding to the elastic layer a material which shows good affinity with the resin material constituting the resin layer, more particularly, by adding in the elastic layer the fluorine resin of the resin layer when the resin layer is of the fluorine resin, the fluorine resins contained in the resin layer and the elastic layer are melted in the pores during the sintering, and therefore, they are combined with complete contactness therebetween, thus enhancing the anchoring effect between the elastic layer and the resin layer. In the manner described above, the strong bonding strength can be provided between the elastic layer and the resin layer without a bonding layer. More particularly, even if a shearing stress is locally applied between the elastic layer and the resin layer by separating pawls press-contacted to the fixing roller to separate the recorded recording sheet from the fixing roller, the resin layer is prevented from being peeled off the elastic layer. Therefore, the image fixing roller according to the embodiments of the present invention is so durable that 200,000 sheets can be processed. The description will be made as to the Examples of embodiment and Comparison Examples. Example 1 The image fixing roller 1 according to this embodiment was manufactured in the following manner. First, an aluminum core metal 2 was prepared which was finished to have a central diameter of 48.435 mm with the amount of reverse-crown of 125 microns and to have a thickness of 5 mm. The surface thereof was sand-blasted, degreased and dried. A silicone primer was applied on the core metal 2 with a thickness of 7 microns and was heated at 120 °C for 20 minutes. Then, a sheet of vulcanized silicone rubber was wrapped and was press-vulcanized at 160 °C for 30 min. It was machined to a thickness of 0.5 mm of the rubber layer, whereby the silicone rubber roller was produced. The vulcanized silicone rubber contained 100 parts by weight of methyl vinyl silicone rubber, 70 parts by weight of quartz particles having an average particle size of approximately 50 microns and 10 parts by weight of aerosol silica having an average particle size of 0.015 micron, and it exhibits the hardness of 80 degrees (JIS A). The surface of the silicone rubber roller after the vulcanization was sand-blasted, so that the quartz particles on and adjacent the roller surface were beaten out of the elastic layer. The quartz particles were removed from the surface of the roller using an abrasive cloth made of Normex fibers coated with PTFE (tetrafluoroethylene resin). More particularly, the abrasive cloth was press-contacted to the entire length of the roller under the pressure of 1 kg/cm², while the roller was rotated at 4 rpm, and while the abrasive cloth is reciprocated for 30 min. at 50 mm/sec, thus forcedly removing the quartz particles from the roller surface. Then, the roller surface was cleaned by water and was dried. Numerous pores 30 were formed on the roller surface, and the porosity was 7 %. Unsintered PTFE (tetrafluoroethylene resin) dispersion, which was available from Daikin Kabushiki Kaisha, Japan under the name of tetrafluoroethylene resin dispersion D-1, was coated on the entire length of the rubber roller having the above porosity, with a thickness of 20 microns by a roll coater at a low temperature of 13 °C. The fluorine resin dispersion applied with uniform thickness was sintered by a dielectric heating apparatus. The used dielectric heating apparatus was as shown in Figure 9, which uses both of the dielectric heating and an external infrared heating. The apparatus comprises a magnetron 105, a waveguide 106 for propagating a high frequency wave (950 MHz - 2450 MHz) produced by the magnetron 105, an openable resin container 102 connected with the waveguide and having a metal high frequency wave reflecting plate 103 at its inside, and two external infrared lamps 111 with reflecting shades at each of the upper and lower positions. In the resin container 102, there are a fan 100 for producing an air flow in the central bore of the image fixing roller 1, a fan 101 for producing an air flow in the container 102, both of which are driven by an external driving means. The container is openable about a hinge 108, and the upper part thereof is provided with a grip, and the lower part is provided with an arm 107 for positioning a flange 1A of the roller 1. The driving means 104, the magnetron 105 and the infrared lamp 111 are controlled by control means 110. Since the fixing roller 1 has a back-up silicone rubber layer 2 and a surface fluorine resin dispersion, and therefore, the high frequency wave is absorbed more in the dispersion than in the silicone rubber layer, since the dielectric constant of the dispersion is larger than the other. Therefore, the fluorine resin dispersion is quickly heated by the heating by the high frequency wave, by the infrared rays and by the constant temperature container. More particularly, it is heated at 340 °C for 15 min. to be completely sintered. During the heating, the silicone rubber layer having a smaller absorption rate for the high frequency wave is not so heated as the dispersion, more particularly, it is heated at approximately 280 °C. In this manner, the thermal gradient is substantially produced in the silicone rubber in the direction of the thickness thereof, and is heated up to 260 - 280 °C approximately, but the unsintered fluorine resin is heated for approximately 5 - 10 min. at a temperature not less than the crystalline melting point, more particularly at the sintering temperature of 340 - 380 °C which is not less than 327 °C, for PTFE resin. After the sintering, the roller was quickly cooled. By the cooling, a sintered fluorine resin layer 6 exhibiting such resin properties that the crystallinity was 92 %, that the tensile strength was 120 kg/cm² and that the contact angle relative to the water was 110 degrees, was formed on the silicone rubber roller with high bonding strength and with sufficient thickness, more particularly 20 microns, the final diameter of the fixing roller 1 was 49.475 mm. The pressing roller 10 was produced in the similar manner with the exception that the core metal was made of steel, and the thicknesses of the elastic layer 14 and the resin layer 16 were 6 mm and 25 microns, respectively. The final outside diameter of the pressing roller 10 was the same as the fixing roller 1. The porosity of the elastic layer of the heating roller 10 was 7 %. Evaluation Using the image fixing roller 1 and the pressing roller 10, test runs were performed to investigate the fixing, releasing and bonding properties and the durability. The testing conditions were such that the surface temperature of the fixing roller 1 was controlled to be maintained at 180 °C, that A4 size sheets were processed at 270 mm/sec, and that 40 sheets were processed per minute. The image fixing properties were evaluated on the basis of the fixation rate of nine solid black circular images each having a diameter of 24 mm on a A4 size (JIS) transfer sheet having a basis weight of 80 g/m² at 10 °C ambience. The fixation rate was determined on the basis of the image density D0 of the circular image, and an image density D1 after being rubbed through 10 reciprocation under the pressure of 40 g/cm² with Kojin wiper which was unwoven cloth available from Kabushiki Kaisha Kojin, Japan under the trade name of "paper waste" which was disposable wiping paper having a crepe rate of 32 ± 3 %, weight of 35 ± 3 g/m², a tensile strength in the longitudinal direction of not less than 0.4 kg/15 mm and a thickness of approximately 200 microns. More particularly, the fixation rate was determined as (D1/D0) x 100 %. The densities D1 and D2 were measured by MacBeth reflection densitometer, and the density D0 was controlled so as to be not less than 1.0 and not more than 1.1. The releasing properties were determined by continuously forming 100 whole surface solid black images on the transfer sheets under the same conditions, and subsequently, passing a blank sheet, and observing the contamination of the blank sheet. The bonding strength between the elastic layer and the resin layer was determined in the following manner. The fluorine resin surface layer was partly peeled with a width of 20 mm, and the peeled portion was gripped by a tension gauge having a full scale of 100 - 300 g, and it was peeled in the direction of 90 degrees from the circumferential direction, and the reading of the tension gauge was deemed as the bonding strength. During this test, the surface temperature of the fixing roller was maintained at 25 ± 2 °C. The durability was determined in the following manner. The surface temperature was maintained at 180 °C, and A4 size sheets were continuously passed through the fixing apparatus at the sheet feeding speed of 270 mm/sec and at a speed of 40 sheets/min, and the number of the total sheets passed until the resin layer starts to be peeled off the elastic layer was deemed as the durability. The fixing, releasing and bonding properties were investigated for the image fixing roller 1 according to Example 1. The results were: Fixing property: 91 % at worst 94 % on the average (nine portions) Releasing property: no contamination observed Bonding property: 340 g/20 mm Durability: no damage was observed in the fixing roller and in the pressing roller after 200,000 sheets were processed; and they are further usable Therefore, it has been confirmed that the rollers according to Example 1 have practically sufficient performance in all of the evaluation items. Comparison Example 1 An image fixing roller and a pressing roller were produced in the similar manner as in Example 1. In this Comparison Example, the process of removing the quartz particles from the surface of the silicone rubber layer (elastic layer) was not performed, and therefore, the resin layer was directly formed. Therefore, the porosity of the elastic layer surface prior to formation of the resin layer was approximately 1.5 %. Under the same conditions as the Example 1, the fixing, releasing, bonding properties and the durability were investigated for the image fixing roller 1 and the pressing roller 10 according to this Comparison Example. The results were: Fixing property: 90 % at worst 94 % on the average (nine portions) Releasing property: no contamination observed Bonding property: 100 g/20 mm Durability: the resin layer of the fixing roller was partly removed from the elastic layer at a portion where it is contacted to the separating pawl after 300,000 sheets were processed; and the resin layer of the pressing roller was partly removed from the elastic layer at a portion corresponding to the lateral end of the sheet after 400,000 sheets were processed. Each of the rollers of the Example 1 shows the properties equivalent to the rollers of Example 1 with respect to the image fixing and releasing properties, but it is inferior in the bonding strength and the durability as compared with the roller according to the embodiments of the present invention since the anchoring effect can not be expected. Example 2 The image fixing roller and the pressing roller were produced in the same manner as in Example 1. The Example 2 is different from the Example 1 only in that the vulcanized silicone rubber constituting the elastic layer contains 100 parts by weight of methyl vinyl silicone rubber, 55 parts by weight of the quartz particle having an average particle size of approximately 8 microns and 10 parts by weight of aerosol silica having an average particle size of approximately 0.015 micron, and it had a hardness of 65 degrees (JIS A). Therefore, the porosity of the surface of the elastic layer before the resin layer was formed was 7 %, the same as in Example 1. The image fixing, releasing and bonding properties and durability were investigated for the fixing roller 1 and the pressing roller 10 of Example 2 under the same conditions as in Example 1. The results were: Fixing property: 93 % at worst 95 % on the average (nine portions) Releasability: no contamination observed Bonding strength: 350 g/20 mm Durability: no damage was observed in the fixing roller and the pressing roller after 200,000 sheets were processed, and further operation was possible. It has been confirmed, therefore, each of the rollers according to Example 2 has practically sufficient performance in each of evaluation items. As compared with Example 1, the elasticity of the elastic layer is increased because of the lower hardness of the elastic layer, and the image fixing properties are improved. With the increase of the elasticity, the damper effect can be expected against the impact provided by the pawls or the like, and the impact absorbing power is improved, with the improvement of the durability. When the silicone rubber is used for the elastic layer, the rubber hardness is preferably not less than 30 degrees and not more than 80 degrees, and further preferably, the elongation is not less than 120 %, and the stress for 100 % elongation is not less than 10 kg/cm² with sufficient rubber elasticity. Comparison Example 2 Image fixing roller and pressing rollers are produced in the same manner as in Example 2. In this Comparison Example, the process for removing quartz particles from the surface of the silicone rubber layer (elastic layer) was not performed, but the resin layer was directly formed thereon. The porosity on the surface of the elastic layer prior to formation of the resin layer was approximately 1 %. Under the same conditions as in Example 1, the image fixing, releasing, bonding properties and durability were investigated for the fixing roller 1 and the pressing roller 10 for the Comparison Example 2. The results were: Fixing property: 93 % at worst 95 % on the average (nine portions) Releasing property: no contamination observed Bonding property: 100 g/20 mm Durability: The resin layer of the fixing roller was partly removed from the elastic layer at a portion where it is contacted to the separation pawl, after 400,000 sheets were processed; and the resin layer of the pressing roller was partly removed from the elastic layer at a portion which corresponds to the lateral edge of the sheets, after 300,000 sheets were processed. Each of the rollers according to the Comparison Example 2 has the properties equivalent to that of Example 2 with respect to the fixing property and the releasing property, but the roller according to this Comparison Example wherein the anchoring effect can not be expected is inferior to the roller according to Example 2 in the bonding strength and the durability. In the foregoing description, a heat-fixing apparatus has been taken as an Example of preferable applications of the elastic rotatable member according to the present invention. However, the present invention is applicable to a pressure-fixing apparatus or the like wherein the toner image is pressure-fixed with light pressure or wherein the image is simultaneously transferred and fixed. In the foregoing embodiment, the image fixing apparatus is constituted by two rollers. However, it may be constituted by one or three or more rollers. In addition, the present invention is applicable to a heating roller or to a pressing roller in various types of apparatus. As shown in Figure 10, the rotatable member according to the present invention is not limited to the form of a roller, but may be in the form of a belt, for example, an intermediate belt for simultaneous image transfer and fixing. Particularly, when the fluorine resin is used for the resin layer, the rotatable member is provided with the releasing property and the elasticity, and with therefore, the good image transfer property, good cleaning property (easy to clean) and good durability to wear, and therefore, it is preferable. As for the elastic layer, fluorine rubber or the like is usable as well as the silicone rubber, and as for the resin layer, silicone resin material or the like can be used as well as the fluorine resin material. The description will be made as to the filler material in the elastic layer 4. As shown in Figure 12, a filler material having a diameter larger than the resin particles applied on the elastic layer 4 is mixed into the elastic layer. On the surface of the elastic layer 4 which is to be contacted to the resin layer 6, the filler material 50 fixed in and dispersed in the elastic layer is partly exposed. By partly exposing the filler material on the surface of the elastic layer, the affinity between the elastic layer 4 and the resin layer 6 is improved, so that the bonding strength therebetween is increased. In addition, by the filler material 50 on the surface of the elastic layer being naturally removed during the manufacturing process of the rubber roller, or by the filler material 50 being forcibly removed, pores 30 are formed on the surface of the elastic layer 4, whereby the bonding strength between the elastic layer and the resin layer is further increased. That is, the resin material of the resin layer 6 formed on the elastic layer 4 is anchored into the pores 30. In an embodiment which will be described hereinafter, the resin material as well as the filler material 50 is mixed into the elastic layer. Therefore, the fluorine resin constituting the elastic layer 6 enters the pores 30, and therefore, during the sintering of the resin layer, the resin in the elastic layer and the resin in the resin layer are fused together on the surface of the elastic layer, and in addition, in the pores 30, the resin in the elastic layer and the resin in the resin layer are fused together, whereby the elastic layer and the resin layer are more strongly bound. As a result, the layers are not separated for a long term use, and therefore, the durability is significantly improved. The resin material mixed into the elastic layer is similar to the resin material of the resin layer applied thereon, more particularly, when the resin applied and sintered is a fluorine resin, the resin mixed into the elastic layer is also a fluorine resin, preferably. The strongest bonding strength can be obtained when the materials are same, that is, if the resin of the resin material is PTFE resin, the resin mixed into the elastic layer is also PTFE resin; and if the resin material of the resin layer is PFA, the resin contained in the elastic layer is also PFA. In order to make it easier for the fluorine resin particles constituting the resin layer to enter the pores 30, the particle size the size of the pores 30 is made larger than the particle size of the fluorine resin particles for the resin layer. If the particle size of the filler material is too large, the surface of the rubber layer becomes rough with the result of easy non-uniformness of the image fixing, or loss of sufficient rubber elasticity. According to the investigation and experiments by the inventors, the limit is 20 microns. Therefore, the filler material mixed into the elastic layer preferably has an average particle size of 1 - 2 microns, and the material thereof is one or more selected from quartz particles, diatomaceous earth, metal powder, metal oxide powder and ceramic, and 30 - 120 parts by weight, preferably 40 - 90 parts by weight, are mixed to 100 parts by weight of rubber material. This is because the peeling strength between the elastic layer and the resin layer is increased with increase of amount of the filler material, and sufficient bonding strength can be obtained when it is not less than 30 parts by weight, but if it is not less than 120 parts, by weight the hardness of the elastic layer is too large with the result of problems in the sheet conveying and image fixing properties. The fluorine resin mixed and dispersed in the elastic layer is 3 - 30 parts by weight, preferably 5 - 25 parts by weight. With the increase of the porosity of the pores 30, more of the resin material of the resin layer 6 enters the pores 30 of the elastic layer 4, and therefore, the anchoring effect is increased, and therefore, it is preferable. Example 3 The image fixing roller 1 according to this embodiment was manufactured in the following manner. First, an aluminum core metal 2 was prepared which was finished to have a central diameter of 48.435 mm with the amount of reverse-crown of 125 microns and to have a thickness of 5 mm. The surface thereof was sand-blasted, degreased and dried. A silicone primer was applied on the core metal 2 with a thickness of 7 microns and was heated at 120 degrees for 20 minutes. Then, a sheet of vulcanized silicone rubber was wrapped and was press-vulcanized at 160 °C for 30 min. It was machined to a thickness of 0.5 mm of the rubber layer, whereby the silicone rubber roller was produced. The vulcanized silicone rubber contained 100 parts by weight of methyl vinyl silicone rubber, 15 parts by weight of PTFE particles having an average particle size of approximately 0.2 micron, 55 parts by weight of quartz particles having an average particle size of approximately 8 microns and 10 parts by weight of aerosol silica having the average particle size of 0.015 micron, and it exhibits the hardness of 65 degrees (JIS A). Then, the roller was cleaned by water and was dried. Unsintered PTFE (tetrafluoroethylene resin) dispersion, which was available from Daikin Kabushiki Kaisha, Japan under the name of tetrafluoroethylene resin dispersion D-1, containing PTFE particles having a particle size of approximately 0.2 micron, was coated on the entire length of the rubber roller, with a thickness of 20 microns by a roll quarter at a low temperature of 13 °C. The fluorine resin dispersion applied with uniform thickness was sintered by a dielectric heating apparatus shown in Figure 9. The sintering and quick cooling steps, and the roller diameter and others are the same as in Example 1. A pressing roller 10 was produced in the similar manner with the exception that the core metal was made of steel, and that the thicknesses of the elastic layer 14 and the resin layer 16 were 6 mm and 25 microns, respectively. The final roller diameter thereof was the same as the fixing roller. Evaluation The fixing, releasing and bonding properties were investigated for the image fixing roller 1 according to Example 1 under the same conditions as in Example 1. The results were: Fixing property: 90 % at worst 94 % on the average (nine portions) Releasing property: no contamination observed Bonding property: 300 g/20 mm Durability: no damage was observed in the fixing roller and in the pressing roller after 200,000 sheets were processed; and they are further usable. Therefore, it has been confirmed that the rollers according to Example 3 have practically sufficient performance in all of the evaluation items. Comparison Example 3 An image fixing roller and a pressing roller were produced in the similar manner as in Example 3. This Comparison Example was different from Example 3 in that the silicone rubber contained 100 parts by weight of methyl vinyl silicone rubber and 20 parts by weight of aerosol silicon having an average particle size of 0.015 microns without PTFE particles and large size quartz paraticles added. The rubber had a hardness of 50 degrees (JIS A hardness). The resin layer was made of PTFE dispersion having a paraticle size (0.3 micron on the average) layer than that of the aerosol silica. Under the same conditions as the Example 1, the fixing, releasing, bonding properties and the durability were investigated for the image fixing roller 1 and the pressing roller 10 according to this Comparison Example. The results were: Fixing property: 92 % at worst 94 % on the average (nine portions) Releasing property: no contamination observed Bonding property: 600 g/20 mm Durability: the resin layers of the fixing roller at the pressing roller were partly removed from the elastic layer at a portion where it was contacted to the separating pawl, after 300,000 sheets were processed. Each of the rollers of the Comparison Example 1 shows the properties equivalent to the rollers of Example 1 with respect to the image fixing and releasing properties, but it is inferior in the bonding strength and the durability as compared with the roller according to embodiments of the present invention. Example 4 The image fixing roller and the pressing roller were produced in the same manner as in Example 3. The Example 2 is different from the Example 3 in that a predetermined amount of the vulcanized silicone rubber constituting the elastic layer was removed, to forcibly form pores 30, and then the resin layer was formed. The surface of the silicone rubber roller after the vulcanization was sand-blasted to heat the quartz partaicles on or adjacent the surface of the roller out of the elastic layer. Then, an abrasive cloth which is Normex fibers coated with PTFE resin as press-contacted to the entire length of the roller under the pressurse of 1 kg/cm², while the roller was being rotated at 4 rpm, and while reciprocating the abrasive cloth at a speed of 50 mm/sec, for 30 min. to forcibly remove the quartz paraticles from the roller surface. The roll surface was them cleaned by water and dryed. Numerous pores 30 were formed. The fluorine resin was applied and sintered in the same manner as the Example. The image fixing, releasing and bonding properties and durability were investigated for the fixing roller 1 and the pressing roller 10 of Example 4 under the same conditions as in Example 3. The results were: Fixing property: 90 % at worst 93 % on the average (nine portions) Releasability: no contamination observed Bonding strength: 370 g/20 mm Durability: no damage was observed in the fixing roller and the pressing roller after 200,000 sheets were processed, and further operation was possible. It has been confirmed, therefore, each of the rollers according to Example 4 has practically sufficient performance in each of evaluation items. As compared with Example 3, the image fixing properties are equivalent, but the durability has greatly been improved. This is because the filler material is forcibly removed from the surface of the elastic layer, so that the anchoring effect is enhanced. The description will be made as to the steps of removing the filler material from the surface of the elastic layer in Examples 1, 2 and 4. Figures 13 and 14 are sectional and perspective views of the filler removing apparatus 40 usable in producing the rotatable members according to the present invention. The removing apparatus 40 includes a housing 41 which contains a supply roll 43 on which an abrasive cloth 42 is wound, a pressing roll 44 for pressing the abrasive cloth 42 supplied from the supply roll 43 to the surface of the rubber roller 1 over the entire length thereof and a take-up roll 45 for taking up the used abrasive cloth 42. Those rollers are rotatable. The pressing roll 44 is preferably made of rubber having a hardness of 30 degrees (JIS A). As shown in Figure 14, the take-up roll 45 is rotated in the direction indicated by an arrow through a driving gear 46 driven by a driving motor M1 and a gear 47 mounted to the take-up roll 45. The pressing roll 44 is rotated in the direction indicated by an arrow through a gear 48 meshed with the above-described gear 47 and mounted to the pressing roll 44. The direction of the pressing roll 44 rotation is opposite to the rotational direction of the silicone rubber roller 1 press-contacted to the pressing roll 44. According to the Example of the removing apparatus, the housing 41 is supported for swinging about a pivot 49. By actuating the supporting arm 50 by a solenoid 51, the housing 41 is pivoted about the pivot 49, the pressing roll 44 is press-contacted to the silicone rubber layer 1 under a predetermined pressure, or it is moved away therefrom. In this example, the housing 41 is reciprocable in a direction of an axis of the silicone rubber roller 1 by driving an operating element 52 fixedly secured to the housing by a swash plate cam 53 driven by the driving motor M2. In operation, when the driving motors M1 and M2 are driven, and the solenoid 51 is energized, the abrasive cloth 42 supplied from the supply roll 43 to the surface of the silicone rubber roller is pressed to the surface of the roller by the pressing roll 44 over the entire length of the roller and a predetermined pressure, 1 kg/cm², for example. At this time, the roller 1 is rotated, and simultaneously, the pressing roll 44, and therefore, the abrasive cloth 42 having a roughness sufficient to remove the quartz particles projected from the surface of the elastic layer without scraping the elastic layer, are reciprocated in the direction of the axis of the roller, by which the quartz particles on the roller surface is forcibly and properly removed. Thus, a number of pores 30 is formed on the surface of the roller. The amount of the removed filler can be controlled by changing amount of the filler material, material of the abrasive cloth and the pressure or the like. As for the method of removing the quartz particles from the silicone rubber roller, they may be removed by a very strong sand-blasting treatment or the like, but the removal using the abrasive cloth is preferable, since it is capable of removing them with certainty. While the invention has been described with reference to the structures disclosed herein, it is not confined to the details set forth and this application is intended to cover such modifications or changes as may come within the scope of the following claims.

Claims: An image fixing rotatable member, comprising an elastic layer (4, 14), and a resin layer (6, 16) on said elastic layer (4, 14) derived by sintering particles of resin in situ on the elastic layer, characterised in that the elastic layer (4, 14) contains filler material (50) having a particle size larger than that of the resin particles, and said elastic layer (4, 14) is provided with a surface having depressions (30) resulting from removal of said filler material (50). A member according to claim 1, wherein the total of the areas (s1, s2, s3 .... sN) of the openings of said depressions (30) is 3-50% of the total surface area of said elastic layer (4, 14). A member according to claim 1 or 2, wherein said elastic layer (4, 14) is of silicone rubber, and said resin layer (6, 16) is of fluorine resin. A member according to any preceding claim, wherein said elastic layer (4, 14) contains resin material. A member according to claim 4, wherein the resin material in said elastic layer (4, 14) is a fluorine resin. A member according to any preceding claim, wherein the bonding strength between said elastic layer (4, 14) and said resin layer (6, 16) on said elastic layer (4, 14) is not less than 130 g/20 mm. A member according to claims 4 or 5, wherein said filler material (50) has a particle size larger than that of the resin material contained in said elastic layer (4, 14). A member according to any preceding claim, wherein said filler material consists of quartz particles or silica particles. A member according to claim 8, wherein said quartz particles have an average size of 1-15 microns. A member according to any preceding claim, wherein said elastic layer (4, 14) contains 100 parts by weight of rubber material and 30-200 parts by weight of filler material. An image fixing apparatus, comprising: a pair of rotatable members (1, 10) cooperable with each other to fix an unfixed image (T) when an image supporting member (P) supporting the unfixed image is passed through a nip formed between the rotatable members, at least one of said rotatable members being an image fixing rotatable member as claimed in any preceding claim. An apparatus according to claim 11, wherein said at least one of said rotatable members (1) is contactable to the unfixed image (T). An apparatus according to claim 11 or 12, wherein said at least one of said rotatable members is heated by a heating source (H) for fusing the unfixed image (T). A method of manufacturing an image fixing rotatable member, the method comprising the steps of applying a resin layer (6, 16) to an elastic layer (4, 14), and sintering the resin in situ on the elastic layer, characterised in that the method further comprises mixing a filler material (50) having a particle size larger than that of the resin particles into said elastic layer (4, 14), and providing said elastic layer (4, 14) with a surface having depressions (30) formed therein by removing said filler material. A method according to claim 14, wherein said elastic layer (4, 14) contains 100 parts by weight of rubber material and 30 - 200 parts by weight of the filler material. A method according to claim 14 or 15, wherein said filler material has an average particle size of 1 - 15 microns. A method according to claim 14, 15 or 16, wherein said elastic layer (4, 14) is vulcanized after formation. A method according to any of claims 14 to 17, wherein the elastic layer (4, 14) is rubber material consisting of silicone rubber or fluorine rubber, and wherein said filler is of quartz particles or silica particles. A method according to any of claim 14 to 18, wherein the resin material is fluorine resin and is sintered at a temperature not lower than its melting point. A method according to any one of claims 14 to 19, wherein said filler material is removed by the action of an abrasive material on the surface of said elastic layer (4, 14). A method according to any one of claims 14 to 19, wherein said filler material is removed by sand blasting on the surface of said elastic layer (4, 14). A method of fixing an unfixed image on an image supporting member, the method comprising the step of passing the image supporting member between two rotatable members so that said rotatable members apply pressure to the image supporting member, characterised in that at least one of said rotatable members is an image fixing rotatable member as claimed in any one of claims 1 to 10, or in that at least one of said rotatable members is manufactured by the method as claimed in any one of claims 14 to 21. A method according to claim 22, wherein said at least one of said rotatable members contacts the unfixed image. A method according to claim 22 or 23, wherein said at least one of said rotatable members is heated by a heating source for fusing the unfixed image. Use of an image fixing rotatable member as claimed in any one of claims 1 to 10, or as manufactured by a method as claimed in any one of claims 14 to 21 for applying pressure to an unfixed image on an image supporting member to fix the image.

Inventors: SAKANE ISAMU, SAKURAI MASAAKI, SASAME HIROSHI, YOSHIDA YASUMI, SAKANE,ISAMU, SAKURAI, MASAAKI, SASAME, HIROSHI, YOSHIDA, YASUMI
Applicants: CANON KK, IST KK, CANON KABUSHIKI KAISHA, KABUSHIKI KAISHA I.S.T.
Application year: 1988
Main classification: G03G15
IPC codes: B29C59, B29C70, B29C67, B29C37, G03G15