LIQUID CRYSTAL DISPLAY DEVICE AND METHOD OF MANUFACTURING SUCH A DISPLAY DEVICE

Abstract: Liquid crystal display devices having very small cell thicknesses are obtained by means of underetching techniques. Via etching holes (17, 29, 31) an auxiliary layer (27) between a supporting plate (2) and a cover plate (14) is removed. Dependent on the technique used spacers (18) are formed at the area of the etching holes or in between the etching holes. The device obtained has a uniform thickness over large surfaces.

Description: The invention relates to a liquid crystal display device comprising a liquid crystalline medium between a supporting plate and a cover plate at least one of which is transparent and each of which is at least provided with a layer comprising a conducting material and, if necessary, a layer of protective material on the side of the liquid crystalline medium and a plurality of spacers arranged between such plates. The invention also relates to a method of manufacturing such a display device. The said display devices are used, for example, in colour television or in (colour) monitors for data display and in, for example, display devices in dashboards, etc., but they may also be used as light switches in optical equipment or other optical applications. In addition such devices are increasingly being used in projection television. The supporting plate and the cover plate are generally in the form of two glass substrates on which electrodes (metal patterns) are provided. These substrates have a given thickness to render them mechanically robust, which is necessary because these plates are pressed against each other while often simultaneously applying subatmospheric pressure after spacers have been provided between the plates. Usually fibres or spheres of the desired dimensions which are deposited in advance on one of the plates are chosen for the spacers. Since a certain spread occurs in the diameter of these fibres or spheres, there will be a local spread in the thickness of the liquid crystal layer. This spread is even increased by unevennesses in the supporting plate and/or the cover plate owing to the presence of metal tracks and electronic switching elements such as diodes and transistors. A surface unevenness of the order of 0.5 µm is no exception. Notably at smaller cell thicknesses (2 to 3 µm) this variation will play a considerable role. A liquid crystal display device in which a partial solution to this problem is proposed, is known from WO-A-8 605 283. After completion of a supporting plate the spacers are defined by coating the plate with a uniform layer of a polyimide layer whereafter the spacers are formed photolithographically from this layer. A second supporting plate or cover plate is subsequently provided on the spacers. Various problems occur in such a manufacturing method. In the first place the two supporting plates must be correctly positioned with respect to each other. Moreover, a decreasing cell thickness makes it increasingly difficult to fill the devices from their side with liquid crystal material. In this method it also appears that there is still a variation in the thickness of the liquid crystal layer which may be up to 10% or more of the total layer thickness. For a large part these differences in thickness are caused by the fact that unevennesses in the one supporting plate are not compensated by a design in the other supporting plate which is, as it were, a replica. It is an object of the invention to provide a liquid crystal display device in which these problems are largely solved and in which the variation in thickness is at most 4%, notably in thin liquid crystal layers. In addition the invention has for its object to provide a plurality of methods of manufacturing such a device in a small number of process steps. A first liquid crystal display device according to the invention is therefore characterized in that the cover plate has a plurality of openings and in that each of said spacers is present between the plates of substantially equal distances from a number of the openings. A second liquid crystal display device according to the invention is characterized in that the cover plate has a plurality of openings and in that each of said spacers is arranged at the position of an opening in the cover plate. The spacers are now formed, for example, by the conducting material extending as far as the supporting plate or by insulating material such as, for example, cured photoresist provided at the area of the opening. The invention is based on the recognition that the cover plate and the supporting plate can be formed in such a manner that they constitute each other's replica, whilst such structures can be realised in a technological easy manner by means of underetching techniques in which the various openings are used as etching holes. In this respect it is to be noted that the use of underetching techniques for manufacturing display devices is known per se from German Offenlegungsschrift 26,41,283. According to the invention it is possible to manufacture devices with a very small layer thickness (0.1-3 µm) having thickness variations of less than 4%. Such a device is very suitable, for example, for display media whose operation is based on liquid crystal effects occurring at a small thickness such as, for example, zero-order birefringence (ECB effect; Electrically Controlled Birefringence) or for ferroelectric display media. Due to the small thickness of the cell the relaxation time will also be shorter when using other liquid crystalline materials (for example, twisted nematic) so that cells filled with such materials can be driven more rapidly. An additional advantage is that the openings for underetching can also be used for filling the cells. Due to the decreasing cell thickness the viscous resistance considerably increases when filling the cells from the side, which leads to unacceptably long filling times. The device according to the invention has a plurality of filling openings in the cover plate so that filling is effected even more rapidly. In a preferred embodiment silicon is chosen as a material for the supporting plate in which then the control electronics can be realised. In a first method of manufacturing a display device according to the invention the greater part of the intermediate layer is removed by means of underetching via openings in the cover plate and the remaining parts of the intermediate layer are left as spacers. In a further method depressions which are at least partly filled up with insulating material are provided in the intermediate layer. The invention will now be described in greater detail by way of example with reference to the accompanying drawings in which Fig. 1 is a diagrammatic plan view of a display device according to the invention, Fig. 2 is a diagrammatic cross-section taken on the line II-II in Fig. 1; Fig. 3 is a diagrammatic plan view of another display device according to the invention; Fig. 4 is a diagrammatic cross-section taken on the line IV-IV in Fig. 3; Fig. 5 is a diagrammatic plan view of yet another display device according to the invention; Fig. 6 is a diagrammatic cross-section taken on the line VI-VI in Fig. 5 at different manufacturing stages; Fig. 7 shows diagrammatically a further embodiment of a display device according to the invention and Fig. 8 is a diagrammatic cross-section taken on the line VIII-VIII in Fig. 7. The Figures are diagrammatic and not to scale, and corresponding elements usually have the same reference numerals. Fig. 1 is a plan view and Fig. 2 is a cross-section taken on the line II-II in Fig. 1 of a liquid crystal display device 1 according to the invention. This embodiment comprises a silicon supporting plate 2 in which semiconductor circuits are realised, in this embodiment by means of MOS transistors 3. The MOS transistors 3, which operate as switches, are located at the area of crossing of line electrodes 4 and column electrodes 5. In the switched-on state they connect the column electrodes 5 to picture electrodes 6. To this end the source and drain zones 7, 8 of the MOS transistors are connected to the column electrodes 5 and the picture electrodes 6, respectively, whilst the line electrodes 4 control the switch-on and switch-off states of the transistors 3 via gate electrodes 9 which are separated by a thin gate oxide 10 from the channel region between the source and drain zones 7, 8. Outside the channel region the semiconductor body constituting the supporting plate 2 is coated with an insulating layer 11 of, for example, silicon oxide, and is provided with contact holes 12 for contacting the source and drain zones 7, 8. The assembly of transistors and electrodes is coated with a protective layer 13 which, if necessary, may also serve as an orientation layer for a liquid crystal to be used. The device also comprises a cover plate 14 composed of a protective layer 15 of aluminium oxide and a layer 16 of transparent conducting material, for example, indium tin oxide. According to the invention the layer 16 has at least one opening 17. In this embodiment the cover plate 14 has a plurality of openings 17 which are provided in the double layer 15, 16, whilst the device is also provided with spacers 18, in this embodiment of magnesium oxide. Furthermore the space between the supporting plate 2 and the cover plate 14 is filled with liquid crystal material, in this embodiment a homeotropic liquid having a negative dielectric anisotropy, for example, ZLI 3160 of the firm of Merck, but other materials are alternatively possible. Finally the device is provided with a second cover plate 20, but this is not strictly necessary to keep the liquid crystalline material in the cell. In fact it has been found that the cell thus formed is rapidly filled via the openings 17 with the liquid crystal material due to a strong capillary action and which subsequently stays there. The second cover plate 20, which may rest on cover plate 14 directly or via supporting members, having an airgap, is therefore only used to protect the device from dirt rather than to keep the liquid within the cell and it may also serve as a support for a colour filter 21. The cover plate 20 may itself form a colour filter which can be provided at approximately 10 µm from the cell so that there is substantially no parallax. The distance between the supporting plate 2 and the cover plate 14 is approximately 1 µm in this embodiment, with a tolerance of less than 2%. An advantage of such a small thickness is the shorter relaxation time of a plurality of liquid crystal effects which are inversely proportional to the square value of the thickness. Consequently fast switch-off times are possible. The device shown is used in the reflection mode. For incident radiation 23 with a wavelength λ₀ the polariser 33 has a direction of polarisation which extends at an angle of 45° to the direction of orientation which is introduced, for example, via the protective layer 13 into the liquid crystal when the cell receives a given voltage V directing the molecules parallel to the wall of the cell (region 22a). With the chosen dimension and liquid this region then functions as a 0.5 λ plate for radiation 23a at a wavelength of λ₀ so that the direction of polarisation is rotated through 90° and the radiation 23a is passed on by an analyser 34 whose direction of polarisation is rotated through 90° with respect to that of the polariser 33. At voltage 0 (region 22b) the beam 23b is extinguished by the homeotropic liquid after it has been polarised. If desired, grey tints can be realised by applying intermediate voltages. The device of Figs. 1, 2 may be manufactured as follows. The starting material is a supporting plate 2, in this embodiment a silicon substrate in which MOS transistors 3 for drive purposes and further peripheral electronics are integrated. The picture electrodes 6 have a dimension of, for example, 50 x 50 (µm)² so that the total dimension (including peripheral electronics) is approximately 6 x 6 cm² in a display device with 1000 x 1000 elements. Since in this example a device operating in the reflection mode is concerned, the picture electrodes 6 are formed with reflective material (for example aluminium). If desired, the line and column electrodes 4, 5 may also be made of polycrystalline silicon. The substrate including electronics and electrodes is subsequently coated with a protective layer 13 by means of a homogeneous deposition technique. This dielectric protective layer 13 of SiO₂ has a thickness of approximately 0.1 µm. If necessary, the free surface 24 of the layer 13 is treated (for example, by rubbing with velvet) in order to give the adjacent liquid crystal molecules a preferred direction at a later stage. A layer of magnesium oxide (MgO) is then vapour-deposited at approximately 250°C by means of homogeneous deposition techniques. The layer has a thickness of approximately 1.1 µm and its surface microscopically follows the surface of the supporting plate 1 including transistors, electrodes and protective layer 13. It appears that also for very large surfaces such a layer can be provided in thicknesses of 0.1 µm with an accuracy of 4%. The thickness d of 1.1 µm is determined by the wavelength used and the liquid crystal material via the formula in which d is chosen to be slightly larger in practice. In the present example ZLI 3160 (Merck) is chosen as a liquid crystal material. In this case it holds that Δn is 0.13, whilst λ ₀ is chosen to be 550 nm. The following layers are successively vapour-deposited on the layer of magnesium oxide at approximately 300°C: an approximately 0.2 µm thick layer 15 of aluminium oxide (Al₂O₃) which functions as a dielectric in the ultimate device and in addition provides extra mechanical strength; an approximately 0.15 µm thick layer of indium tin oxide for the conducting layer 16. If desired, the free surface of the layer of magnesium oxide may be subjected to an orienting surface treatment before providing the layers 15, 16. In fact it has been found that the preferred direction obtained by rubbing or another method is taken over by the material 15 which is deposited on this surface. In this case the previous direction of orientation can be followed in order to reinforce the preferred adjustment through the entire liquid crystal layer; alternatively a different direction of orientation can be chosen in order to given the liquid crystal molecules a desired twist. In the case of a single preferred direction it appears that one surface treatment is sufficient for thin layers of liquid crystal material. Subsequently the locations of the circular openings 17 with a diameter of 2 µm are defined by means of photolithographic techniques. The openings 17 in the layers 15, 16 are obtained by etching the indium tin oxide of the layer 16 at the location of openings in the photoresist for 90 seconds at 45°C in a bath containing 250 ml of HCL (36%), 30 g of FeCl₃,25 ml of HNO₃ (65%), 250 ml of H₂O and by subsequently removing the exposed aluminium oxide 15 in a 5% HF solution for 45 seconds at room temperature. The greater part of the magnesium oxide intermediate layer is removed by means of underetching via the openings 17 which are now provided in the layers 15, 16. This is effected, for example, in a 5% H₂SO₄ solution at 35°C in approximately 75 seconds. As a result of the underetching treatment only the spacers 18 are left at regular distances from one another. Since the intermediate layer can be provided very accurately in a given thickness, the distance between substrate 1 and cover plate 15, 16 is substantially constant. The elements 18 are at a mutual distance of approximately 50 µm from one another so that the layer can be considered to be substantially rigid. After rinsing in distilled water, acetone (for removing the photoresist) and, for example, hexane the cell is filled with liquid crystal material 19. This is done, for example, by providing a thin layer of the liquid crystal material on the cover plate and due to the relatively large capillary forces the cells will be filled rapidly. The superfluous liquid crystal material is removed and the device is provided with a second cover plate 20 of glass or synthetic material foil. This plate only serves as a protection to external influences. The openings 17 need not be closed; in fact it has been found that the said capillary forces are sufficient to prevent the liquid crystal material from flowing back. After the colour filter 21 is provided by means of conventional techniques the device of Fig. 1, 2 is completed. An advantage of the method described is that only one alignment step is required, namely for defining the openings 17 (via the photoresist). In addition very thin cell thicknesses are possible (from 0.1 µm) with a great homogeneity over large surfaces. The thin cell thicknesses notably provide attractive use of effects based on zero-order birefringence (ECB) and of ferroelectric liquid crystals. In the embodiment shown such an effect was used in the reflection mode with a silicon substrate as a supporting plate. This leads to a high yield in the switching elements to be used and provides the possibility of using the various advantages of IC techniques such as "redundancy". Fig. 3 is a plan view and Fig. 4 is a cross-section taken on the line IV-IV in Fig. 3 of an optical switch 25 whose structure is substantially identical to the device of Figs. 1, 2. The supporting plate 2 is now made of glass and one continuous electrode 6 of indium tin oxide is provided on this plate. In this embodiment underetching is continued until a separate cell 22 which is separated from the other cells 22 is associated with each openings 17. Due to the position of the openings 17 (to be compared with a close poched layer) it is achieved that the surface of the cells 22 fills substantially the entire surface of the device (approximately 90%). The device can be made transparent or non-transparent via voltages at the electrodes 6, 16. Otherwise the reference numerals have the same significance as those in Figs. 1, 2. If necessary, the device may be provided with one or more polarisers. In this case (transparent cell) the cover plate may also function as a polariser. The metallisation layers 6, 16 may also be in the form of columns and rows by dividing the indium tin oxide electrodes into a crossbar system with pixels at the area of the crossings. The layer 15 of Al₂O₃ then provides additional robustuess. Such a device is very suitable for multiplex devices. Fig. 5 is a plan view of a part of a slightly different display device according to the invention whilst Fig. 6 shows the device during different stages of manufacture, taken on the line VI-VI in Fig. 5. In this case a display device 1 is shown which is operated in the transmission mode. Lower electrodes 26 and drive elements not shown, for example, transistors realised in amorphous or polycrystalline silicon are provided on a transparent supporting plate 2 whereafter the assembly is coated with a protective layer 13 in which, if necessary, a preferred direction for the liquid crystal is provided. Subsequently a layer 27 of magnesium oxide with an accurately defined thickness following the topology of the subjacent plate on a microscopic scale is provided on this assembly. A photoresist layer 28 is provided and patterned thereon by means of photolithographic techniques. With this pattern as a mask openings 29 having dimensions of for example 2 x 2 µm² are etched in the subjacent layer 27. Subsequently the protective layer 15 and the layer of conducting material 16 are provided by means of oblique vapour deposition, indicated by arrows 30 in Fig. 6b, in these openings and on the remaining part of the layer 27. With a suitably chosen vapour deposition angle (approximately 45°) and dimensions of the openings 29, the double layer 14 extends in the openings 29 as far as the coating 13 of the lower supporting plate and constitutes spacers 18 in situ. This may be effected at the area of a lower electrode 26 (opening 29′) but alternatively between the lower electrodes. In the first-mentioned case the protective layer 13 may, if necessary, in advance be removed locally in order to obtain through-connections between lower electrodes 26 and upper electrodes 16. The layer 27 can now be removed again via the openings 29, 29′. This etching step is no longer critical as in the previous embodiments, because the spacers 18 are resistant to the etchant. The openings 29 have otherwise the same functions as the openings 17 in Figs. 1, 2. After a cleaning step the cell can be filled with liquid crystal material whereafter a second cover plate and one or more polarisers are provided. In yet another method of manufacturing a device according to the invention and as shown in Figures 7 and 8 the supporting plate 2 is successively provided with electrodes 6, a protective layer 13 and a layer 27 of MgO which in its turn is coated with a protective layer 15 and a layer 16 of indium tin oxide. Openings or slots 31 with dimensions of, for example, 2 x 6 µm² are provided in the layers 15, 16 and subsequently in the layer 27 by means of photolithographic techniques; the MgO of the layer 27 may be slightly underetched in this case. Subsequently the photoresist layer is removed and photoresist is provided again which also fills the slots 31. This photoresist is exposed with a mask 32 so that after development the spacers 18 consisting of cured photoresist (at 200°C) are left. These partly fill the openings 31 so that accesses for the etchant (and at a later stage the liquid crystal material) are obtained again. The invention is of course not limited to the embodiments shown but several variations are possible within the scope of the invention. For example, in Figs. 7, 8 the mask 32 may be formed in such a manner that the opening 31b is entirely filled with photoresist and hence with a spacer 18. In this case the layer 28 can be removed via a second opening 31a, which opening is temporarily coated with an auxiliary mask during underetching of the layer 27 so that the opening 31a is not transferred in the layer 27. In the latter example an inorganic material can be used instead of photoresist for forming the elements 18 therefrom. In addition the spacers 18, notably in the devices of Figs. 5, 6 and Figs. 7, 8 may extend along the edge of an upper electrode. In a device which is operated in the reflection mode the cover plate may alternatively be made opaque and the supporting plate may be made transparent to radiation.

Claims: A liquid crystal display device (1) comprising a liquid crystalline medium (19) between a supporting plate (2) and a cover plate (14) at least one of which is transparent and each of which is at least provided with a layer (6,9,16) comprising a conducting material and, if necessary, a layer (13,15) of protective material on the side of the liquid crystalline medium and a plurality of spacers (18) arranged between said plates (14,29), characterized in that the cover plate (14) has a plurality of openings (17) and in that each of said spacers (18) is present between the plates (2,14) at substantially equal distances from a number of the openings (17). A liquid crystal display device (1) comprising a liquid crystalline medium (19) between a supporting plate (2) and a cover plate (14) at least one of which is transparent and each of which is at least provided with a layer (6,9,16) comprising a conducting, material and, if necessary, a layer (13,15) of protective material on the side of the liquid crystalline medium and a plurality of spacers (18) arranged between said plates (14,29), characterized in that the cover plate (14) has a plurality of openings (17) and in that each of said spacers (18) is arranged at the position of an opening (17) in the cover plate (14). A liquid crystal display device as claimed in Claim 2 characterized in that said spacers (18) consist of conductive material of the cover plate (14) which extends as far as the supporting plate (2) at the position of each of said openings (17) in the cover plate (14). A liquid crystal display device as claimed in Claim 2, characterized in that the spacer (18) comprises cured photoresist. A liquid crystal display device as claimed in Claim 2 or 3, characterized in that the opening (18) is present along at least a part of the edge of an electrode formed from the conducting material (16) of the cover plate (14). A liquid crystal display device as claimed in any one of the preceding Claims, characterized in that the conducting material of the supporting plate and cover plate are realized as strip-shaped rows and columns such that pixels are present at the area of the crossings of the rows and columns. A liquid crystal display device as claimed in Claim 3, characterized in that the device comprises at least one electrically conducting through-connection between the conducting material of the supporting plate and that of the cover plate. A liquid crystal display device as claimed in any one of the preceding Claims, characterized in that the supporting plate (2) comprises silicon. A method of manufacturing a liquid crystal display device as claimed in Claim 1, in which a major part of an intermediate layer (27) between a cover plate (14) and a supporting plate (2) each comprising a layer (6, 9, 16) of conducting material and a layer of protective material (13, 15) is removed, by underetching via openings (17) in the cover plate (14) and the remaining parts of the intermediate layer are left as spacers (18). A method of manufacturing a liquid crystal display device as claimed in Claim 2 or 3, in which an intermediate layer (27) between a cover plate (14) and a supporting plate (2) each comprising a layer (6, 9, 16, 26) of conducting material is at least partly removed, so that depressions (29, 31) which are at least partly filled with insulating material are provided in the intermediate layer.

Inventors: TE VELDE, TIES SIEBOLT
Applicants: N.V. PHILIPS' GLOEILAMPENFABRIEKEN
Application year: 1988
Main classification: G02F1
IPC codes: G02F1, H04N5, H04N9