FERROELECTRIC LIQUID CRYSTAL COMPOSITIONS

Abstract: A ferroelectric liquid crystal comprises (i) one or more chiral compounds of the formula: (in which R¹ and R² are each a straight or branched alkyl, alkoxy, alkoxyalkoxy, alkoxycarbonyl, alkanoyl or alkanoyloxy group containing up to 18 carbon atoms and at least one of R¹ and R² has an asymmetric carbon atom in the alkyl chain moiety thereof); and (ii) one or more chiral compounds having a spontaneous polarization value of 40 nC/cm² or more.

Description: This invention relates to ferroelectric crystal materials. More particularly it relates to a ferroelectric liquid crystal composition comprising one or more phenylpyrimidine chiral compound(s) and one or more chiral compound(s) having a very large spontaneous polarization value and having high-speed response properties, and to light switching element using the same. Liquid crystal compounds have been widely used as materials for display elements, but most such liquid crystal elements are those having a TN display mode and as liquid crystal materials, those of the nematic phase have been used. Since the TN display mode is non-emissive, it does not tire the eyes, the power consumption is very small, etc. On the other hand, it has the drawbacks that the response is slow, the visual sensation-dependency is inferior, etc. Thus attention has recently been turned towards making the best use of the mode's specific feature as a flat display, and in particular, high-speed response properties and the width of visual sensation have been sought. In order to meet such requirements it has been attempted to improve liquid crystal materials therefor. However, as compared with other emissive displays (for example, electroluminescence display, plasma display, etc.), TN display mode is still considerably different from emissive display modes in the aspects of response time and width of visual sensation. In order to make the best use of the specific features of liquid crystal display elements such as non-emissive mode, small power consumption, etc. and yet to secure response properties matching those of emissive displays it is necessary to develop a novel liquid crystal display mode in place of TN display mode. Thus, it has been proposed to use a display mode utilizing the light switching phenomenon of ferroelectric liquid crystals [N A Clark and S T Lagerwall, Appl. Phys. Lett., Vol. 36, p. 899 (1980)]. The presence of ferroelectric liquid crystals was first upheld by R B Meyer et al first time [see J. Phys. Vol. 38, p. 69 (1975)]. The liquid crystals have a chiral smectic C phase, chiral smectic I phase, chiral smectic F phase, chiral smectic G phase or chiral smectic H phase (hereinafter abbreviated to SC* phase, SI* phase, SG* phase or SH* phase, respectively). Among these chiral smectic phases, the SC* phase has now been particularly noted. As display modes utilizing the switching phenomenon of the SC* phase, two modes may be considered. One of them is a birefrigence mode using two polarizers and the other is a guest-host mode using a dichroic dyestuff. Specific features of these display modes include the following: (1) response time is very short; (2) there are memory properties; and (3) the visual sensation-dependency is small. The display modes have a possibility of high density display and are very attractive as display elements. A number of specific features have been required for ferroelectric liquid crystal materials used for practical ferroelectric liquid crystal elements, but at present there is no single compound satisfying all the requirements; thus it is necessary to use ferroelectric liquid crystal compositions obtained by mixing liquid crystal compounds together or by mixing non-liquid crystal compounds therewith. Further, ferroelectric liquid crystal compositions are obtained not only from ferroelectric liquid crystal compounds, but also when compounds or compositions exhibiting achiral smectic C, F, G, H, I phase or the like (hereinafter abbreviated to SC phase or the like) as base substances are mixed with at least one compound exhibiting ferroelectric liquid crystal phase, ferroelectric liquid crystal compositions are obtained as a whole (see Japanese laid-open patent application No 195187/1986). Further, when compounds or compositions exhibiting an SC phase or the like, are mixed, as base substances, with at least one compound which is optically active but which exhibits no ferroelectric liquid crystal phase, ferroelectric liquid crystal compositions are obtained as a whole [see Mol. Cryst. Liq. Cryst. 89, 327 (1982)]. In summary, it is seen that by mixing at least one optically active compound with a base substance, it is possible to provide a ferroelectric liquid crystal composition, irrespective of whether the optically active compound exhibits a ferroelectric liquid crystal phase. At present, a number of specific features have been required for ferroelectric liquid crystal materials, and the following have been particularly required: (1) the SC* phase is exhibited within a broad temperature range including room temperature (at least 0°C to 50°C); and (2) the response time is 100 µsec or less. At present, however, a ferroelectric liquid crystal material (liquid crystal composition) which satisfies all of such conditions has not yet been obtained. For example, Japanese laid-open patent application 291679/1986 and PCT Application No WO86/06401 disclose a ferroelectric liquid crystal composition obtained by mixing an achiral compound, a 5-alkyl-2-(4-alkoxyphenyl) - pyrimidine, with an optically active compound, which composition exhibits SC* phase within a broad temperature range including room temperature. Further, the former document discloses that when a ferroelectric smectic liquid crystal material comprising the above pyrimidine derivative as a base Sm mixture is used, it is possible to shorten the response time of light switching elements. Further, Japanese laid open patent application No 291679/1986 discloses that a ferroelectric liquid crystal material consisting of a 5-alkyl-2-(4' - alkylbiphenylyl-4) pyrimidine and an optically active compound also exhibits an SC* phase over a broad temperature range including room temperature and is effective for improving the response properties. However, liquid crystal compositions disclosed in Japanese application 291679/1986 and PCT application No WO86/06401, have response times of 300 to 500 µsec; hence they are hardly suitable for practical use. Japanese laid-open patent applications 260564/1985, 22072/1986, 93170/1986, etc. disclose that optically active phenylpyrimidine compounds exhibit an SC* phase within a broad temperature range in the vicinity of room temperature and also have superior response properties, but for example, 5-n-octyl-2-[4-(6-methyloctyloxy) phenyl]pyrimidine has a temperature range for the SC* phase of 15°C-49°C and a response time of 600 µsec; hence it is practically impossible to use this compound alone. Japanese laid-open patent application No 129169/1986 discloses an example of a composition using the above-mentioned optically active phenylpyrimidine compound, but for example, in Test example 1 thereof, the ferroelectric liquid crystal composition has a temperature range for the SC* phase of 2°C to 40°C and a response time of 180 µsec at 30°C; thus this composition is also not practical. The response time of current ferroelectric liquid crystal materials is still long and hence not on a practical level so that further improvement in response properties is desirable. A first object of the present invention is to provide a ferroelectric liquid crystal composition exhibiting an SC* phase within a broad temperature range including room temperature and also having high-speed response properties. A second object is to provide a light switching element using the above-mentioned liquid crystal composition and exhibiting high-speed response properties. We have found that when chiral compounds are combined together, as described below, there is obtained a ferroelectric liquid crystal composition exhibiting SC* phase within a broad temperature range including room temperature and also having high-speed response properties. According to the invention there is provided a ferroelectric liquid crystal composition comprising (i) chiral compounds of the formula. (in which R¹ and R² are each a straight or branched alkyl, alkoxy, alkoxyalkoxy, alkoxycarbonyl, alkanoyl or alkanoyloxy group containing up to 18 carbon atoms and at least one of R¹ and R² has an asymmetric carbon atom in the alkyl chain moiety thereof); and (ii) one or more chiral compounds, as hereinafter defined, having a polariization value of 40 nC/cm² or more. The chiral compound of formula (A) is preferably a compound of the formulae: (in which R³ is a straight or branched alkyl or alkoxy group containing up to 18 carbon atoms; n is 0 or an integer of 1 to 8; and * indicates an asymmetric carbon atom); (in which R³, n and * have the meanings defined above and l is 0 or 1); (in which R³ and * have the meanings defined above and k is an integer from 1 to 8); (in which R³ n and * have the meanings defined above); (in which R³ n and * have the meaning defined above); and (in which R³ and * have the meanings defined above and R⁴ is a straight or branched alkyl or alkoxyd group containing from 2 to 8 carbon atoms). The chiral compounds having a spontaneous polarization value of 40 nC/cm² or more are compounds of the formulae: (in which R³ and * have the meanings as defined above and X is a hydrogen or fluorine atom or a cyano group); (in which the groups R³ have the meanings defined above and may be the same or different and * has the meaning defined above); (in which R³ and * have the meanings defined above and R⁵ is a straight or branched alkyl group containing from 2 to 18 carbon atoms or a straight or branched alkoxy group containing from 1 to 18 carbon atoms); (in which the groups R³ and * are as defined above for the compound of formula VIII); (in which R³, R⁵ and * have the meanings defined above); (in which the groups R³ and * have the meanings defined above for the compound of formula VIII); (in which R³, R⁵ and * have the meanings defined above); (in which R³ and * have the meanings defined above); and (in which R³ and * have the meanings defined above). The ferroelectric liquid crystal composition contains probably 20 to 80% by weight of the chiral components of formula (A), from 5 to 50% by weight of the chiral compound having a spontaneous polarization value of 40 nC/cm² or more, based on the weight of the composition. The invention also provides a light switching element using a ferroelectric liquid crystal composition as defined above. Specific examples of the phenylpyrimidine compounds formula (A) are the known compounds formulae (A-I) to (A-VI) (eg see Japanese laid-open patent applications Nos 260564/1985, 22072/1986, 93170/1986, 200973/1986, 215371/1986, 129170/1986, etc). Such compounds are characterised in that they have not so large spontaneous polarization values, but low viscosities and a tendency to exhibit and SC* phase in the vicinity of room temperature; hence they are useful compounds as base liquid crystals and by combining a plurality thereof, it is possible to form base SC* mixtures. In the ferroelectric liquid crystal compositions of the invention, it is preferred to use compounds of formulae (A-I) to A-VI), but even in the case of compounds not expressed by the formulae (A-I) to (A-VI), if such compounds are optically active compounds having a phenylpyrimidine core as defined by the formula (A), it is possible to use the compounds as a component of the liquid crystal composition of the present invention, within a range of quantity in which the specific features of the liquid crystal composition of the present invention are not damaged. Representation examples of compounds expressed by the formula (A) and having an SC* phase are as follows: DETAILED DESCRIPTION OF THE INVENTION Concrete examples of the phenylpyrimidine compounds expressed by the formula wherein R¹ and R² each represent a linear or branched chain alkyl group, alkoxy group, alkoxyalkoxy group, alkoxycarbonyl group, alkanoyl group or alkanoyloxy group each of 1 to 18 carbon atoms and at least one of R¹ and R² has an asymmetric carbon atom in the alkyl chain moiety of these groups, and used in the present invention, are known compounds expressed by the above formulas (A-I) to (A-VI) (e.g. see Japanese patent application laid-open Nos. Sho 60-260564/1985, Sho 61-22072/1986, Sho 61-93170/1986, Sho 61-200973/1986, Sho 61-215372/1986, Sho 61-129170/1986, etc.). Compounds of such formulas are characterized in that they have not so large spontaneous polarization values, but low viscosities and a tendency of exhibiting SC* phase in the vicinity of room temperature; hence they are useful compounds as base liquid crystals and by combining a plurality thereof, it is possible to form base SC* mixtures. In the ferroelectric liquid crystal composition aimed in the present invention, it is preferred to use compounds expressed by the above formulas (A-I) to (A-VI), but even in the case of compounds not expressed by the formulas (A-I) to (A-VI), if such compounds are optically active compounds having a phenylpyrimidine core expressed by the formula (A), it is possible to use the compounds as a component of the liquid crystal composition of the present invention, within a range of quantity in which the specific features of the liquid crystal composition of the present invention are not damaged. Representative examples of compounds expressed by the formula (A) and having SC* phase are as follows: As the optically active phenylpyrimidine compounds expressed by the formula (A) and used as a component of the ferroelectric liquid crystal composition aimed in the present invention, the above-mentioned compounds having SC* phase are preferred, but even in the case of compounds exhibiting no SC* phase, it is possible to use the compounds in a limited quantity within a range in which the SC* phase temperature range of the resulting base SC* mixture is not notably narrowed. On the other hand, concrete examples of the compounds having a spontaneous polarization value of 40 nC/cm² or more and used in the present invention are compounds expressed by the above formulas (VII) to (XV) which compounds have been previously applied for patent by the present inventors and already laid-open (see e.g. Japanese patent application laid-open No. Sho 60-43/1985, etc.) or previously applied for patent by the present inventors but not yet laid open (e.g. Japanese patent application Nos. Sho 61-133269/1986, Sho 62-049796/1987, Sho 62-103977/1987, Sho 62-67097/1987, Sho 61-192516/1986, etc.). Since a specific feature of these compounds consists in a very large spontaneous polarization value (40 nC/cm² - 300 nC/cm²), the compounds play an important role of exhibiting high-speed response properties in the ferroelectric liquid crystal composition aimed in the present invention. In the ferroelectric liquid crystal composition aimed in the present invention, compounds expressed by the formulas (VII) to (XV) are preferred, but even in the case of compounds other than the above, if the compounds have a spontaneous polarization value of 40 nC/cm² or more, it is possible to use the compounds as a component of the ferroelectric liquid crystal composition aimed in the present invention, within a range of quantity in which the specific features of the composition are not damaged. Representative examples of the compounds having a spontaneous polarization value of 40 nC/cm² or more are as follows: The compound having a spontaneous polarization value of 40 nC/cm² or more and used as a component of the ferroelectric liquid crystal composition aimed in the present invention is preferred to be those having SC* phase, but even in the case of compounds exhibiting no SC* phase, it is possible to use the compounds in a limited quantity within a range in which the SC* phase temperature range of the ferroelectric liquid crystal composition aimed in the present invention is not notably narrowed. As described above, the ferroelectric liquid crystal composition of the present invention is achieved by combining optically active phenylpyrimidine compound(s) expressed by the formula (A) with chiral compound(s) having a spontaneous polarization value of 40 nC/cm² or more, but other chiral compounds as shown below, for adjusting the helical pitch may be used within a range of quantity in which the object of the present invention is not damaged: The present invention is based upon a finding that when optically active phenylpyrimidine compound(s) expressed by the formula (A) are combined with chiral compound(s) having a very large spontaneous polarization value, superior specific features are exhibited. The phenylpyrimidine chiral compounds expressed by the formulas (A-I) to (A-VI) have a not so large spontaneous polarization value (1 nC/cm² to 5 nC/cm²), but exhibit SC* phase in the vicinity of room temperature and also have a low viscosity; hence the compounds play a role of a base SC* compound in the ferroelectric liquid crystal composition aimed in the present invention and constitute a motive force by which SC* phase is exhibited within a broad temperature range including room temperature. Representative compounds and their phase transition points are shown in Table 1. As apparent from Table 1, compounds A, G, H and I have very low melting temperatures, whereas compounds B, C, D, E and F have high upper limit temperatures of SC* phase; hence when these compounds A to I are combined, base SC* compositions exhibiting SC* phase within a broad temperature range including room temperature are obtained. Using compounds, A, D, E, F and I in Table 1, the following base SC* composition A was prepared: Composition A The phase transition points of this composition were as follows: As seen from the foregoing, when compounds expressed by the formulas (A-I) to (A-VI) are combined, base SC* compositions exhibiting SC* phase within a broad temperature range including the vicinity of room temperature are obtained. Further, the response time of the above composition A was 350 µsec at an electric field intensity of 5 V/µm and 25°C. The SC* phase temperature range is practical, but the response time is still late; hence even taking the prior art into account, it is regarded impossible to obtain a practical ferroelectric liquid crystal composition only from phenylpyrimidine compounds expressed by the formula (A). Using this base SC* composition A and a chiral compound J expressed by the formula (VII) and having a very large spontaneous polarization value (150 nC/cm² ( T-Tc = 30°C )), the following ferroelectric liquid crystal composition B was prepared: Composition B Composition A (base SC* composition) 80 wt.% and The phase transition points of this composition were as follows: Further, its response time was 80 µsec at 25°C, its spontaneous polarization value was 30 nC/cm² and its tilt angle was 22°. Further, using the following known achiral phenylpyrimidine compounds, the following base SC composition C was prepared: Composition C The phase transition points of this composition C was as follows: Using this base SC composition C and the above-mentioned chiral compound J, the following ferroelectric liquid crystal composition D was prepared: Composition D The phase transition points of this composition were as follows: Further, its response time was 195 µsec at 25°C, its spontaneous polarization value was 5 nC/cm² and its tilt angle was 23° . As seen from comparison of the composition B with composition D, the ferroelectric liquid crystal composition consisting of phenylpyrimidine chiral compounds expressed by the formula (A) and used in the present invention has a broader SC* phase temperature range than that of the ferroelectric liquid crystal composition consisting of achiral phenylpyrimidine compounds, and also has superior response properties to those of the latter. In other words, it has been found by the present inventors for the first time that optically active phenylpyrimidine compounds are superior in the specific features as the base liquid crystals to phenylpyrimidine compounds which have most excellent specific features among achiral SC compounds (see e.g. Japanese patent application laid-open No. Sho 61-291679/1986) (the specific features consisting in a broad SC* phase temperature range and an effect of making the response properties faster). In general, among the spontaneous polarization value (abbreviated to Ps), the viscosity (abbreviated to η) and the response time (abbreviated to τ) of ferroelectric liquid crystal materials, there is the following relationship: wherein E refers to the intensity of an electric field impressed to a liquid crystal cell, and a compound having a low viscosity and also a large spontaneous polarization value is desired. Using the above equation, the viscosities of the above mentioned ferroelectric liquid crystal compositions B and D were calculated. As a result, the viscosity of the composition B was 1.2 poise and that of the composition D was 0.5 poise. Since the kinds and concentrations of these chiral compounds are both the same, the difference between the above viscosities may be considered to correspond to the difference between the base liquid crystals. With regard to the viscosity, viscosities of achiral phenylpyrimidine compounds are considerably lower than those of chiral phenylpyrimidine compounds, but chiral phenylpyrimidine compounds have an effect of greatly increasing the spontaneous polarization value and this effect apparently offsets the drawback of the higher viscosity thereof. Thus, in a summary view, chiral phenylpyrimidine compounds may be said to be superior as base liquid crystals to achiral phenylpyrimidine compounds. The optically active phenylpyrimidine compounds expressed by the formula (A) play a role as base SC* compounds; hence the concentration range of the chiral compounds expressed by the formula (A) is preferred to be 80% by weight or less. Further, the viscosity of the ferroelectric liquid crystal compositions is affected not only by the base liquid crystal compounds, but also by the chiralizing agents having a large spontaneous polarization value. In general, the viscosities of compounds having an ester bond at the center thereof as in the case of the above-mentioned compound J are higher than the viscosities of compounds of directly bonded rings type expressed by the above formulas (VIII) to (XIII). Thus, now if the average value of viscosities of ferroelectric liquid crystal compositions is presumed to be in the range of 0.8 to 1.0 poise, then a spontaneous polarization value of at least 16 to 20 nC/cm² is required for obtaining a response time of 100 µsec in the case of an electric field intensity of 5V/µm. The spontaneous polarization values of the optically active phenylpyrimidine compounds expressed by the formula (A) are not so large (1 to 5 nC/cm²), and in order to form base SC* compositions, a compound having a small spontaneous polarization value but having a broad SC* phase temperature region (such as compounds expressed by the formulas (A-I) to (A-III)) should be used; thus the spontaneous polarization value of the base SC* composition of the present invention is nearly 0 nC/cm². Further, the concentration of the compound having a large spontaneous polarization value used is preferred to be 50% by weight or less, taking into consideration the SC* phase temperature range, helical pitch length, tilt angle, etc. Thus, in order to make the response time of the ferroelectric liquid crystal composition 100 µsec or less (i.e. in order to make the spontaneous polarization value 16 nC/cm² or more), a chiral compound having a spontaneous polarization value of at least 32 nC/cm² in 50% by weight or less is required. In the case of a chiral compound having a largest spontaneous polarization value, the concentration range of the chiral compound used may be 50% by weight or less. Thus, as the chiral compound having a large spontaneous polarization value in the ferroelectric liquid crystal composition aimed in the present invention, a compound having a spontaneous polarization value of 40 nC/cm² or more can be said to be useful, taking the concentration thereof used into consideration. As apparent from the foregoing, a chiral compound having a spontaneous polarization value of 40 nC/cm² or more plays an important role for exhibiting high-speed response properties in the ferroelectric liquid crystal composition aimed in the present invention. Representative examples of the compound having a large spontaneous polarization value and their spontaneous polarization values are shown in Table 2. The present invention will be described in more detail by way of Examples, but it should not be construed to be limited thereto. Further, the spontaneous polarization value (Ps) was measured according to Sawyer-Tower method and the helical pitch (P) was sought by using a cell of 200 µm thick subjected to homogeneous alignment and directly measuring the distances between dechiralization lines corresponding to the helical pitch under a polarizing microscope. The tilt angle (ϑ) was sought by impressing an electric field sufficiently higher than the critical electric field to a cell subjected to homogeneous alignment to thereby extinguish the helical structure, followed by inverting the polarity and measuring the resulting moved angle (corresponding to 2ϑ) at extinction site under crossed nicols. The response time was sought by filling the respective compositions in a cell provided with electrodes and having a distance between the electrodes of 2 µm, followed by impressing a square wave of a V pp (impressed voltage (peak to peak)) of 20 V and 100 Hz and measuring change in the intensity of transmitted light. In addition, Examples include a composition containing a chiral compound for elongating the helical pitch of SC* phase besides a chiral compound expressed by the formula (A) and a chiral compound having a large spontaneous polarization value, but to contain such a chiral substance does not damage the specific features of the ferroelectric liquid crystal composition aimed in the present invention and hence raises no problem. Examples 1 to 5 The respective proportions of Examples 1 to 5 of the ferroelectric liquid crystal compositions of the present invention are shown in Table 3 and the characteristic values of the compositions are shown in Table 4. In addition, the respective proportions in Table 3 refer to % by weight. Example 6 The ferroelectric liquid crystal composition prepared in Example 3 was filled in a cell provided with transparent electrodes each having PVA as an aligning agent coated to subject the surface to parallel aligning treatment and having a cell gap of 2 µm, followed by placing the resulting liquid crystal cell between two polarizers arranged at crossed nicol state and impressing a low frequency alternating current of 0.5 Hz and 20 V. As a result, a clear switching operation having a very good contrast (1 : 20) was observed and a liquid crystal display element having a response time as very fast as 25 µsec at 25°C was obtained. Example 7 To the ferroelectric liquid crystal composition prepared in Example 5 was added an anthraquinone dyestuff D-16 (tradename of product made by BDH Company) expressed by the formula in 3% by weight to prepare a guest-host mode composition. The composition was filled in a cell treated in the same manner as in Example 6 and having a cell gap of 8 µm, followed by arranging a polarizer so that the polarization surface could be parallel to molecular axis and impressing a low frequency alternating current of 0.5 Hz and 40 V. As a result, a clear switching operation having a very good contrast (1 : 10) was observed, and a color liquid crystal display element having a response time as very fast as 80 µsec at 25°C was obtained.

Claims: A ferroelectric liquid crystal composition comprising (i) one or more chiral compounds of the formula: (in which R¹ and R² are each a straight or branched alkyl, alkoxy, alkoxyalkoxy, alkoxycarbonyl, alkanoyl or alkanoyloxy group containing up to 18 carbon atoms and at least one of R¹ and R² has an asymmetric carbon atom in the alkyl chain moiety thereof); and (ii) one or more chiral compounds having a spontaneous polarization value of 40 nC/cm² or more and being selected from compounds of the formula: (in which R³ and * have the meanings defined in claim 2 and X is a hydrogen or fluorine atom or a cyano group); (in which the groups R³ have the meanings defined above and may be the same or different and * has the meaning defined above); (in which R³ and X have the meanings defined above and R⁵ is a straight or branched alkyl group containing from 2 to 18 carbon atoms or a straight or branched alkoxy group containing from 1 to 18 carbon atoms); (in which the groups R³ and * are as defined above for the compound of formula VIII); (in which R³, R⁵ and * have the meanings defined above); (in which the groups R³ and * have the meanings defined above for the compound of formula VIII); (in which R³, R⁵ and * have the meanings defined above); (in which R³ and * have the meanings defined above), and (in which R³ and * have the meanings defined above). A composition as claimed in claim 1 in which the chiral compound of formula (A) is a compound of the formulae: (in which R³ is a straight or branched alkyl or alkoxy group containing up to 18 carbon atoms; n is 0 or an integer of 1 to 8; and * indicates an asymmetric carbon atom); (in which R³, n and * have the meanings defined above and ℓ is 0 or 1); (in which R³ and * have the meanings defined above and k is an integer of from 1 to 8); (in which R³, n and * have the meanings defined above); (in which R³, n and * have the meanings defined above); or (in which R³ and * have the meanings defined above and R⁴ is a straight or branched alkyl or alkoxy group containing from 2 to 8 carbon atoms). A composition as claimed in claim 1 or claim 2 containing from 20 to 80% by weight of the chiral components of formula (A) and from 5 to 50% by weight of the chiral compound having a spontaneous polarization value of 40 nC/cm² or more. A composition as claimed in any one of the preceding claims also containing a component C which is a compound of the formula:- A light switching element using a ferroelectric liquid crystal composition as claimed in any one of the preceding claims.

Inventors: FURUKAWA, KENJI, ICHIHASHI, MITSUYOSHI, KIKUCHI, MAKOTO, TAKESHITA, FUSAYUKI, TERASHIMA, KANETSUGU
Applicants: CHISSO CORPORATION
Application year: 1988
Main classification: C09K19
IPC codes: G02F1, C09K19