HDPE FILMS WITH DIFFERENTIAL BIAXIAL ORIENTATION

Abstract: High density polyethylene films, preferably containing blends of HDPE resins or microcrystalline wax, are oriented to a deformation ratio of about 2 in the machine direction and about six or more in the transverse direction to give films having good dead-fold and water vapor transmission characteristics making them highly suited for packaging, particularly for dry foods when coated with or coextruded with a heat sealable layer, e.g. an ionomer.

Description: Blown films of high density polyethylene having an ethylene-vinyl acetate heat sealable coating are used for food packaging. Such films must, however, have a thickness of about 0.05 mm (two mils) to meet the water vapor transmission (WVTR) requirements for packaging material suitable for dry foods such as cereals. Moreover, blown HDPE films do not exhibit the dead-fold properties desirable in food packages particularly of the bag-in-box type. This invention seeks to provide HDPE film wherein good WVTR properties can be achieved with film of about 0.025 mm (one mil) thickness and wherein the film also has dead-fold characteristics which make it well suited for packaging of foods in bag-in-box operations conducted on vertical form, fill and seal (VFFS) machinery. Accordingly, this invention provides biaxially oriented high density polyethylene film comprising at least 50 weight percent of a high density polyethylene having a density of 0.96 or higher (HDPE) and which has a deformation ratio from 1.25:1 to 2:1 in the machine direction, and from 6:1 to 12:1 in the transverse direction. It is preferred that the deformation ratio in the transverse direction is at least 4 times greater than the deformation ratio in the machine direction. As used herein, "HDPE" means high density polyethylene having a density of 0.96 or higher. Such films have reduced WVTR, improved dead-fold, and other physical properties which are markedly better than those of blown high density polyethylene films. When provided with a heat-seal layer by coextrusion, or by coating, the films are particularly suited for use in packaging, especially of dry foodstuffs. The differential biaxially oriented films of this invention are prepared using a major proportion of HDPE. The film can be composed exclusively of a single HDPE resin, a mixture of HDPE resins, or of HDPE containing a minor proportion up to 10 weight percent microcrystalline wax. The mixture of HDPE resins gives better processing characteristics. Films made with either a blend of HDPE resins or with microcrystalline wax reduce splittiness of the film which manifests itself as the tendency of the film to break in the transverse direction during operation on vertical form, fill and seal (VFFS) machinery. The blends, of HDPE polymers may advantageously comprise (i) a major proportion of a first HDPE having a melt index from 0.5 to 2.0, preferably from 0.6 to 1.2, and (ii) a second HDPE having a melt index different from that of the first HDPE. Preferably, (ii) has a melt index from 0.1 to 0.5. Terblends have been found particularly desirable. Suitable terblends generally comprise 50 to 98 weight percent, preferably 84 to 96 weight percent of HDPE having a melt index of greater than 0.5 to 2.0; 1 to 25 weight percent, preferably 3 to 8 weight percent of HDPE having a melt index of 0.1 to 0.5; and 1 to 25 weight percent, preferably 3 to 8 weight percent, of HDPE having a melt index of greater than 2 to about 8. Preferably, the second and third HDPE polymers which are minor components are present in approximately equal amounts. It is highly desirable that the differential biaxially oriented HDPE films of this invention be provided, on at least one side thereof, with a heat sealable layer. The heat sealable layer can be applied in known manner to the HDPE; for example, by coating or coextrusion before orientation or by coating the HDPE after one or both of the biaxial orientation operations. The heat sealable layer can be any of the conventional material used for this purpose in conjunction with polyolefin films particularly polyethylene films. For example ethylene-vinyl acetate copolymers or ethylene-methacrylic acid salt ionomers (available from DuPont as "Surlyn") can be used. Films in which the heat sealable layer is a ethylene-methacrylic acid salt ionomer have been found to be particularly useful in preparing films which are suitable for VFFS applications. The heat sealable layer can comprise the heat sealable resin as such or can include small amounts of other materials. For example, the relatively costly Surlyn ionomer can be mixed with small amounts of less costly materials such as low density polyethylene. The HDPE films of this invention can include other polymer layers in addition to, or instead of, the heat seal layer; for example, polymers having desirable barrier properties for gases such as oxygen. The degree of orientation of the HDPE films is an important aspect of this invention inasmuch as the proper degree of orientation provides desirable physical properties, good WVTR characteristics and dead-fold. For example, it has been determined that the films of this invention having a thickness of 0.025 to 0.030 mm (1.0 to 1.2 mils) will have acceptable WVTR (g-mil/100 in² - 24 hr - 1 atm) of less than about 0.28 whereas a somewhat heavier gauge (1.5 times thicker or more) is needed in a blown HDPE film. The benefits of reduced WVTR are due to the improvements obtained by biaxial orientation as well as the improvements due to the ability to use higher density HDPE polymers in the cast extrusion process of this invention than is possible in blown film extrusion. Lower density HDPE polymers are generally required in blown film extrusion because the higher density resins (density greater than about 0.957) are not processable in the blown film process in a practical commercial manner. Although higher density HDPE resin having a density of 0.957 or greater can be made directly into thin films by cast extrusion, problems of curling, uniformity, flatness and high WVTR remain as obstacles. Accordingly, thin HDPE films of about 0.020 to 0.038 mm (0.8 to 1.5 mils) having the best balance of properties, particularly for VFFS applications, are obtained in the differential biaxially oriented films of this invention prepared from films having a cast gauge of 0.30 to 0.51 mm (12 to 20 mils) which are reduced to the desired gauge by orientation. The films are produced and oriented in the conventional manner. When a heat sealable layer is present on one side of the HDPE film cast extrustion is generally accomplished using a multi-roll stack system having three or more rolls. The rolls on the HDPE side are advantageously maintained at about 65°C and the heat seal sides at a temperature of about 20°C. In the usual manner the film is heated to its orientation temperature and first subjected to MD orientation between two sets of nip rolls the second rotating at a greater speed than the first in an amount equal to the desired draw ratio. Then the film is TD oriented by heating and subjecting it to transverse stretching in a tenter frame. Typically MD orientation is conducted at 60° to 120°C and TD orientation at 110° to 145°C. This invention also includes the use of a film as herein described in the packaging of foodstuffs. The HDPE films of this invention can be produced with excellent quality at caster speeds of up to about 110 fpm corresponding to line speeds of 0.59 m/s (140 fpm) at 1.25 times MD orientation. The invention is illustrated by the following Examples in which all parts are by weight unless otherwise specified. EXAMPLES 1 AND 2 Two layer biaxially oriented films having a 0.025 mm (1 mil) final thickness were prepared by coextruding a primary HDPE layer comprising 95% of the film thickness and a Surlyn 1652 (ethylene-methacrylic acid copolymer salt ionomer from DuPont) layer comprising 5% of the film thickness. The films were prepared in a three roll stack System with the roll temperatures for the HDPE side at 65°C and 20°C for the Surlyn side. The films were then oriented 1.4 times in the MD at about 115°C and 10 times in the TD direction at 115-140°C in a tenterframe. The HDPE Example 1 was PE-5849 (density 0.96, melt index 1.0, from DuPont). In the Example 2, 90% by weight of PE-5849 was blended with 5% by weight of PE-5925 (density 0.96, melt index 0.45, from DuPont) and 5% by weight of PE-7835 (density 0.96, melt index 3.0, from Dupont). The film of Example 2 exhibited a crimp seal range and a hot tack range of 80-120°C, and performed well on the VFFS packaging machine while the Example 1 performed unacceptably having excessive TD splittiness. The physical properties of the films however, are comparable and are summarized in Table 1. Example 1 Example 2 Tensile MD 6 (41 Pa) 6 (41 Pa) (psi x 10³) TD 16 (110 Pa) 20 (138 Pa) Modulus MD 365 (2.5 kPa) 380 (2.6 kPa) (psi x 10³) TD 490 (3.4 kPa) 570 (3.9 kPa) Stiffness MD 17 20 (grams) TD 21 24 Tear Strength MD 89 (3500 g/mm) 63 (2500 g/mm) (g/mil) TD 4 (160 g/mm) 5 (200 g/mm) WVTR (g-mil/100 in²/24 hr at 1 atm 101 kPa) 0.23 (0.091 g-mm/m²/24hr) 0.24 (0.095 g-mm/m²/24hr) EXAMPLES 3 - 4 In a manner similar to that of Example 1, the film of Example 3 was prepared and compared to the film in which the HDPE layer contained 4% by weight of microcrystalline wax (Example 4). The film of Example 3 had a crimp-seal range and hot-tack 105-120°C but exhibited numerous TD splits on the VFFS machine, making it unacceptable for this purpose. The film of Example 4 had a crimp-seal and hot-tack range 90-120°0 with no splitting. The physical properties of the films are summarized in Table 2. Example 3 Example 4 Tensile MD 5 (34 Pa) 5 (34 Pa) (psi x 10³) TD 37 (255 Pa) 35 (241 Pa) Modulus MD 330 (2300 Pa) 340 (2300 Pa) (psi x 10³) TD 740 (5100 Pa) 730 (5000 Pa) Stiffness MD 19 19 (grams) TD 32 31 Tear Strength MD 50 (2000 g/mm) 44 (1800 g/mm) (g/mil) TD 2 (80 g/mm) 2 (80 g/mm) WVTR (g-mil/100 in²/24 hr at 1 atm) 0.24 (0.095 g-mm/m²/24hr) 0.24 (0.095 g-mm/m²/24hr)

Claims: A biaxially oriented high density polyethylene film comprising at least 50 weight percent of a high density polyethylene having a density of 0.96 or higher (HDPE) and which has a deformation ratio from 1.25:1 to 2:1 in the machine direction, and from 6:1 to 12:1 in the transverse direction. A film according to claim 1 wherein the deformation ratio in the transverse direction is at least 4 times greater than the deformation ratio in the machine direction. A film according to claim 1 or 2 which comprises (i) a major proportion of a first HDPE having a melt index from 0.5 to 2.0 and (ii) a second HDPE having a melt index different from that of the first HDPE. A film according to claim 3 wherein (i) has a melt index from 0.6 to 1.2. A film according to claim 3 or 4 wherein (ii) has a melt index from 0.1 to 0.5. A film according to any of claims 3 to 5 which also comprises (iii) a third HDPE having a melt index from 2.0 to 8. A film according to any of claims 3 to 6 wherein (i) comprises from 50 to 98 weight percent of the film polymeric material. A film according to any of claims 3 to 7 wherein (ii) comprises from 1 to 25 weight percent of the film polymeric material. A film according to any of claims 6 to 8 wherein (iii) comprises from 1 to 25 weight percent of the film polymeric material. A film according to any of claims 6 to 9 wherein (i) comprises at least 84 weight percent and (ii) and (iii) each comprise from 3 to 8 weight percent of the film polymeric material. A film according to claim 1 or 2 wherein the HDPE consists essentially of a single resin. A film according to claim 1 or 2 which comprises up to 10 weight percent of microcrystalline wax. A film according to any preceeding claim and having a heat sealable layer on at least one side thereof. A film according to claim 13 wherein the heat sealable layer comprises an ionomer. A film according to claim 13 wherein the heat sealable layer comprises ethylene-vinyl acetate copolymer. A film according to any of claims 13 to 15 wherein the heat sealable ionomer layer which is coextruded on one surface of said HDPE film. The use of a film according to any preceeding claim in the packaging of foodstuffs.

Inventors: LU, PANG-CHIA
Applicants: MOBIL OIL CORPORATION
Application year: 1988
Main classification: C08J5
IPC codes: C08L23, B29C55, C08J5, B32B27, B29L7, B29L9, B29K23