JOINED CERAMIC-METAL COMPOSITE SUBSTRATE AND METHOD FOR PRODUCTION THEREOF

Abstract: The present invention provides a joined ceramic-metal composite substrate having a copper sheet (10) directly joined to a ceramic substrate (13) and a method for the production thereof. The composite substrate is characterised by having at least one through hole (12) in the copper sheet (10) which is connected to at least one groove (11) formed at a distance from the edge of the copper sheet (10) on that surface of the copper sheet (10) to be joined to the ceramic substrate (13). The method preferably involves formation of the groove or grooves (11) by plastic deformation.

Description: This invention relates to a joined ceramic-metal composite substrate having a copper sheet directly joined to a ceramic substrate and a method for the production thereof. In recent years, DBC (Direct Bonded Copper) substrates have been developed for ceramic circuit boards which are intended for substrates for ceramic circuit boards which are intended for substrates in transistor modules, for example. They are obtained by disposing a copper sheet at a stated position on a ceramic substrate and directly joining the sheet and the substrate by heating. The heating is carried out at a temperature not exceeding the melting point of copper (1,083 °C) and exceeding the eutectic point of copper and oxygen (1,065 °C). The copper sheet is later formed into conductor circuits. In the DBC substrate, the ceramic substrates are heavily warped or deformed during the application of heat. Consequently, gas emanating from the ceramic substrates or copper sheets is entrapped in the interfaces between the ceramic substrates and copper sheets, and the copper sheets sustain fine blisters in portions thereof, or portions of insufficient union are produced in the composites. When these blisters grow to a size exceeding a certain level, they create a problem in that the DBC substrates will not permit silicon semiconductor chips to be easily mounted thereon and consequently the yield of the products is poor. There is another problem in that even when the chips can be mounted, the chips have poor adhesion and suffer from inferior thermal conductivity. Jochym (USP 4 409 278) has disclosed a directly joined metal-substrate composite which has venting channels between the contiguous surfaces of the metal sheet and the substrate. This construction evidently prevents the occurrence of blisters in the interface. However, it was found by the present inventors that even if this kind of construction is used in such a composite substrate, its does not often provide highly satisfactory thermal conductivity. This is because such construction permits the etching liquid and liquid material such as soldering flux to enter into the grooves in the mounting process, and such liquid prevents the interface between the copper sheet and the ceramic substrate from having good adhesion. The grooves themselves or the flux-filled grooves both reduce the thermal conductivity at the interface. This is a severe problem because thermal conductivity is important for such substrates to effectively dissipate heat from the silicon chips to be mounted thereon. We acknowledge the disclosure in GB-A-2099742 of a composite ceramic-metal substrate in which through-holes and grooves are provided for venting gases during bonding: this does not solve the problem of the grooves filling with flux. This invention has been provided for the solution of the above problem. An object of this invention is to provide a joined ceramic-metal composite substrate which can be produced in high yield substantially without the occurrence of blisters at the interface. Another object of this invention is to provide a joined ceramic-metal composite substrate enjoying highly satisfactory thermal conductivity and enabling subsequent treatments such as the mounting of a chip thereon to be carried out without any noteworthy trouble. To be more specific, in one aspect, this invention is directed to a joined ceramic-metal composite substrate comprising a ceramic substrate having opposite surfaces and a copper sheet having a face directly joined to one of the surfaces of the ceramic substrate, at least one hole through the copper sheet, and at least one groove on the face of the copper sheet, the hole communicating with the groove and the face including a peripheral border free from grooves. In another aspect, the invention provides a corresponding method for producing a ceramic circuit substrate, as defined in claim 9. Forming the grooves in accordance with the present invention can prevent the etching liquid and liquid material such as soldering flux from entering into the grooves in the mounting process, if the through hole is covered by resin. Having discovered the problem of entry of liquids into the grooves, it was apparent that the ends of the grooves could have been closed, e.g. using resin, prior to subsequent processing. The present invention, however, provides an arrangement which is surprisingly beneficial in terms of unexpected improvements in processing speed and cost advantage. Forming the grooves in accordance with this invention also, of course, retains the benefit of and even improves upon the advantage of avoiding the formation of blisters at the interface between the components to be joined. The gas entrapped in the interface is vented via the grooves connected to the through hole. Embodiments of the invention will now be described by way of example only and with reference to the accompanying drawings, in which:- Fig. 1 is a sectional view of a copper sheet with a metal mold having a V-shaped projection for forming the grooves. Fig. 2 is a sectional view of a copper sheet with grooves formed by etching. Fig. 3 is a perspective illustration showing a roller forming the grooves. Fig. 4A is a plan view showing one side of the metal-ceramic composite substrate of one embodiment of this invention. Fig. 4B is a plan view showing the opposite side of the metal-ceramic composite substrate in Fig. 4A. Fig. 4C is a cross section taken along line x-x of Fig. 4A. Fig. 5A is a plan view showing one surface of the substrate of another embodiment of this invention. Fig. 5B is a plan view showing the opposite surface the substrate in Fig. 5A. Reference will now be made in detail to the present preferred embodiments of the invention, examples of which are illustrated in the accompanying drawings. In accordance with the invention, the joined ceramic-metal composite substrate comprises a ceramic substrate and a copper sheet joined to at least one surface of the substrate. The copper sheet has at least one groove on the surface thereof. At least one through hole is formed to be connected to each groove in the copper sheet. This through hole works as a gas vent hole, making it possible to prevent the bonded portion from swelling. The through hole should have a diameter of the order of about 0.2mm to 1.0mm and should be formed in a place where it will not interfere with mounting. This through hole can be formed by etching or by any known mechanical method. The grooves preferably should be formed in a large number and in parallel. These grooves should have a width in the range of about 0.01 to 3mm, preferably 0.5 to 1mm, and a maximum depth of 0.1mm or one half of the thickness of the copper sheet whichever is less. Preferably, the depth is between 0.02mm and 0.08mm. These grooves should be separated by a fixed pitch, i.e. the distance between the center lines of the adjacent grooves, falling in the range of 1 to 25mm. The areas in which no grooves are formed on the copper sheet preferably define a border of at least about 1mm from each edge of the copper sheet. The grooves may be formed in the copper circuit substrate by any of the methods described hereinbelow. (1) As shown in Fig. 1, a metal mold 1 has projections 2 thereon. Pressing with the metal mold 1 is effected with the depth of grooves adjusted according to the thickness of a stopper 3, thereby forming grooves 5 to a prescribed depth in a copper member 4. (2) As shown in Fig. 2, a masking film 6 is formed on both sides of a copper member 4. A portion 6a corresponds to a desired groove forming position on one side of the member 4. The masking film in the portion 6a is removed. Then the copper member 4 is etched to form grooves 5. (3) As shown in Fig. 3, a pressure roll 7 has projections 8 on its outer periphery. A copper member 4 is rolled between roll and a rider roll 9 to form grooves 5. In the above methods (1) through (3) : method (1) can form the grooves to a prescribed depth even if the copper member varies in thickness,because the depth of grooves is adjusted by the stopper; method (2) is suitable for the production of a prototype and small quantities of samples because it does not need a metal mold and other facilities; and method (3) is suitable to form the grooves collectively by using a strip material as the copper member. It is preferred to form the grooves using method (1) or (3) because this involves formation of the grooves through plastic deformation. Such grooves are to some extent flattened out or "erased" by the heat used during the course of joining the copper and the ceramics. At the time that the copper sheet having the grooves formed thereon is joined to the ceramic substrate, the oxygen evolved from the copper sheet finds its way out through these grooves. At the same time, the grooves produced through plastic deformation "recover" and to some extent eventually flatten out as a result of the intense heat used during the course of the joining. As a result, the gap between the ceramic substrate and the copper sheet decreases. For this reason, the ceramic-copper composite substrate produced by the above methods (1) and (3) has a higher thermal conductivity than one produced by the above method (2). These methods are selectively used according to their characteristics. The grooves also may be formed to run radially from the through hole. The copper sheet to be used is preferably made of oxygen-free copper or tough pitch copper having an oxygen content in the range of 100 to 2000ppm, preferably 200 to 500ppm. The practical thickness of the copper sheet is in the range of 0.03 to 0.5mm. The ceramics substrates used in this invention includes those made from alumina, beryllia and other oxide based sintered ceramics, and aluminum nitride, silicon nitride, titanium nitride, silicon carbide, and other non-oxide based sintered ceramics. When a non-oxide based ceramic substrate is used, the bonding faces are preferably subject to an oxidizing treatment in advance. To preclude the occurrence of blisters, the warp possibly inflicted on the ceramic substrate is desired to be not more than 20µm/50mm. To obtain this range, it is desirable that the ceramic substrate be given a special polishing and then a whet horning in advance of the bonding. Union of the ceramic substrate to the copper sheet is carried out, for example, as follows. The copper sheet is disposed at a specified position on the ceramic substrate. The components, as held in the superposed state, are heated in a non-oxidizing atmosphere (or, when the copper sheet is made of oxygen-free copper, in an oxidizing atmosphere containing a very small amount of oxygen) at a temperature in a range of 1,065 to 1,083 °C, and preferably 1,070 to 1,075 °C. Suitably, the heating time is in a range of 2 to 30 minutes. After the heating thus conducted, the composite is cooled to complete the joined ceramic-metal composite. Example (1) Now, one embodiment of this invention will be described below. As shown in Fig. 4A and 4C, the front surface of a copper circuit board 10 bonded to a ceramic substrate 13 has a large number of V-shaped grooves 11 formed in parallel with each other, at a width of 100 µm and depth of 30 µm - except for a 1mm border around the edge of each copper sheet. These V-shaped grooves 11 are connected to a through hole 12 having a diameter of about 0.5mm. As shown in Figs. 4B and 4C, the back surface of the circuit board 10 bonded to the ceramic substrate 13 is also formed with V-shaped grooves 11 and a through hole 12 in the same manner. The copper circuit board 10 is directly bonded to the ceramic substrate 13. Such a ceramic circuit substrate is produced for example by the method described below. First, a metal mold 1 having V-shaped projections 2 (as shown in Fig. 1) was prepared. The depth of the V-shaped grooves was adjusted with a stopper 3. Then a press molding was effected to form a large number of V-shaped grooves 5 having a width of 100 µm and a depth of 30 µm - except for a 1mm border around the edge of the prescribed circuit pattern of the copper member 4. Then, a punching die was used to cut the copper member 4 into a prescribed shape and to form a through hole at the same time, thereby forming the copper circuit board 10 shown in Fig. 4. Next, the surface of the copper circuit board 10 in which the V-shaped grooves 11 were formed was disposed in contact with ceramic substrate 13. The components were bonded together by heating in an atmosphere of nitrogen gas at a temperature of 1070°C for about 10 minutes. When the appearance of the ceramic circuit substrate thus obtained was inspected, very little swelling was observed and the surface ratio was equivalent to 2% or below. No entrance of the liquid material into the V-shaped grooves was observed during the subsequent production process. Comparative example (1) For comparison, a comparative example (1) was conducted. A composite was used which had neither a through hole in the copper sheet nor a border free of grooves around the edge of the copper sheet. The grooves of this comparative example are formed by etching. When the appearance of the ceramic circuit substrate thus obtained was inspected, swelling caused the surface ratio to be only about 4%. Thus, high yield of product was obtained. However, the thermal conductivity of this product was unacceptably low. This was because the etching liquid and soldering flux had entered the grooves during the mounting process, and such liquids produce poor adhesion and thermal conductivity in the interface between the copper sheet and the ceramic substrate. Comparative example (2) A comparative example (2) was conducted in which neither a through hole nor grooves were made the copper sheet. The occurrence of swelling in this example was equivalent to a surface ratio of about 10%. Example (2) As shown in Fig.5A and Fig.5B, another sample was made wherein the grooves were formed to run radially from the through hole. This example produced substantially the same result as that of example 1. The present invention has been described with respect to specific embodiments. However, other embodiments based on the principles of the present invention will be readily apparent to those of ordinary skill in the art. Such embodiments are intended to be covered by the appended claims.

Claims: A joined ceramic-metal composite substrate comprising a ceramic substrate (13) having opposite surfaces and a copper sheet (10) having a face directly joined to one of the surfaces of the ceramic substrate (13) with at least one groove (11) on the said face of the copper sheet (10), characterised by at least one hole (12) through the copper sheet (10), the hole (12) being in communication with the groove (11) and the face including a peripheral border free from grooves (11). A joined ceramic-metal composite substrate as claimed in claim 1, wherein the through hole (12) is cylindrical and has a diameter in the range of 0.2mm to 1mm. A joined ceramic-metal composite substrate as claimed in claim 1 or claim 2, wherein the groove or grooves (11) terminate at least 1mm from the periphery of the said face. A joined ceramic-metal composite substrate as claimed in any preceding claim, wherein the groove or grooves (11) have a width in a range of 0.01mm to 3mm and preferably in a range of 0.5mm to 1mm. A joined ceramic-metal composite substrate as claimed in any preceding claim, wherein the groove or grooves (11) have a maximum depth of the lesser of 0.1mm and one half of the thickness of the copper sheet (10) and preferably the maximum depth being in a range of 0.02mm to 0.08m. A joined ceramic-metal composite substrate as claimed in any preceding claim, wherein the said groove (11) is one of a plurality of parallel grooves (11) on the said face of the copper sheet (10). A joined ceramic-metal composite substrate as claimed in claim 6, wherein the distance between the center lines of the adjacent grooves (11) is in a range of 1mm to 25mm. A joined ceramic-metal composite substrate as claimed in any preceding claim, wherein the said groove (11) is one of a plurality of grooves (11) extending radially from the hole (12) on the said face of the copper sheet (10). A method for producing a ceramic circuit substrate comprising forming at least one groove (11) on a face of a copper circuit board (10) of prescribed shape; ; forming at least one hole (12) through the board (10) and in communication with the groove (11); and subsequently heat bonding the face of the board (10) to a ceramic substrate (13); characterized by leaving a peripheral groove-free border surrounding the face. A method as claimed in claim 9, characterised by forming the or each groove by plastic deformation.

Inventors: KOMORITA, HIROSHI C/O PATENT DIVISION, MATSUMURA, KAZUO C/O PATENT DIVISION, MIZUNOYA, NOBUYUKI C/O PATENT DIVISION, TANAKA, TADASHI C/O PATENT DIVISION
Applicants: KABUSHIKI KAISHA TOSHIBA
Application year: 1988
Main classification: C04B37
IPC codes: H05K3, C04B37